National Library of Energy BETA

Sample records for metals fluid coking

  1. Metal and coke deactivation of resid hydroprocessing catalysts

    SciTech Connect (OSTI)

    Bartholdy, J.; Cooper, B.

    1993-12-31

    It is well established that residuum hydroprocessing catalysts are deactivated by both coke and metals. The traditional approach has been to relate the initial rapid deactivation with coke laydown and subsequent deactivation with deposition of metals from the residuum. This paper presents evidence of coke and metals deactivation throughout the life of the catalyst. By comparing tests made at constant temperature with tests made at constant conversion it is concluded that the extent of coke deactivation in related to the operating temperature. The extent of coke deactivation has further been estimated by regeneration of a fraction of the catalyst bed.

  2. High Operating Temperature Liquid Metal Heat Transfer Fluids...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Operating Temperature Liquid Metal Heat Transfer Fluids High Operating Temperature Liquid Metal Heat Transfer Fluids This fact sheet describes a UCLA-led solar project to ...

  3. Pump for molten metal or other fluid

    DOE Patents [OSTI]

    Horton, James A.; Brown, Donald L.

    1994-01-01

    A pump having no moving parts which can be used to pump high temperature molten metal or other fluids in a vacuum or low pressure environment, and a method for pumping such fluids. The pump combines elements of a bubble pump with a trap which isolates the vacuum or low pressure region from the gas used to create the bubbles. When used in a vacuum the trap prevents the pumping gas from escaping into the isolated region and thereby reducing the quality of the vacuum. The pump includes a channel in which a pumping gas is forced under pressure into a cavity where bubbles are formed. The cavity is in contact with a reservoir which contains the molten metal or other fluid which is to be pumped. The bubbles rise up into a column (or pump tube) carrying the fluid with them. At the top of the column is located a deflector which causes the bubbles to burst and the drops of pumped fluid to fall into a trap. The fluid accumulates in the trap, eventually forcing its way to an outlet. A roughing pump can be used to withdraw the pumping gas from the top of the column and assist with maintaining the vacuum or low pressure environment.

  4. Determination of electrical resistivity of dry coke beds

    SciTech Connect (OSTI)

    Eidem, P.A.; Tangstad, M.; Bakken, J.A.

    2008-02-15

    The electrical resistivity of the coke bed is of great importance when producing FeMn, SiMn, and FeCr in a submerged arc furnace. In these processes, a coke bed is situated below and around the electrode tip and consists of metallurgical coke, slag, gas, and metal droplets. Since the basic mechanisms determining the electrical resistivity of a coke bed is not yet fully understood, this investigation is focused on the resistivity of dry coke beds consisting of different carbonaceous materials, i.e., coke beds containing no slag or metal. A method that reliably compares the electrical bulk resistivity of different metallurgical cokes at 1500{sup o} C to 1600{sup o}C is developed. The apparatus is dimensioned for industrial sized materials, and the electrical resistivity of anthracite, charcoal, petroleum coke, and metallurgical coke has been measured. The resistivity at high temperatures of the Magnitogorsk coke, which has the highest resistivity of the metallurgical cokes investigated, is twice the resistivity of the Corus coke, which has the lowest electrical resistivity. Zdzieszowice and SSAB coke sort in between with decreasing resistivities in the respective order. The electrical resistivity of anthracite, charcoal, and petroleum coke is generally higher than the resistivity of the metallurgical cokes, ranging from about two to about eight times the resistivity of the Corus coke at 1450{sup o}C. The general trend is that the bulk resistivity of carbon materials decreases with increasing temperature and increasing particle size.

  5. Heteroatom incorporated coke for electrochemical cell electrode

    DOE Patents [OSTI]

    Lewis, Irwin Charles (Strongsville, OH); Greinke, Ronald Alfred (Medina, OH)

    1997-01-01

    This invention relates to an electrode for a coke/alkali metal electrochemical cell comprising: (a) calcined coke particles: (i) that contain at least 0.5 weight percent of nitrogen heteroatoms and at least 1.0 weight percent sulfur heteroatoms, and (ii) that have an average particle size from 2 microns to 40 microns with essentially no particles being greater than 50 microns. (b) a binder This invention also relates to a coke/alkali metal electrochemical cell comprising: (a) an electrode as described above, (b) a non-aqueous electrolytic solution comprising an organic aprotic solvent and an electrically conductive salt, and (c) a counterelectrode.

  6. Heteroatom incorporated coke for electrochemical cell electrode

    DOE Patents [OSTI]

    Lewis, I.C.; Greinke, R.A.

    1997-06-17

    This invention relates to an electrode for a coke/alkali metal electrochemical cell comprising: (a) calcined coke particles: (1) that contain at least 0.5 weight percent of nitrogen heteroatoms and at least 1.0 weight percent sulfur heteroatoms, and (2) that have an average particle size from 2 microns to 40 microns with essentially no particles being greater than 50 microns and (b) a binder. This invention also relates to a coke/alkali metal electrochemical cell comprising: (a) an electrode as described above, (b) a non-aqueous electrolytic solution comprising an organic aprotic solvent and an electrically conductive salt, and (c) a counterelectrode. 5 figs.

  7. Method and apparatus for dissociating metals from metal compounds extracted into supercritical fluids

    DOE Patents [OSTI]

    Wai, Chien M.; Hunt, Fred H.; Smart, Neil G.; Lin, Yuehe

    2000-01-01

    A method for dissociating metal-ligand complexes in a supercritical fluid by treating the metal-ligand complex with heat and/or reducing or oxidizing agents is described. Once the metal-ligand complex is dissociated, the resulting metal and/or metal oxide form fine particles of substantially uniform size. In preferred embodiments, the solvent is supercritical carbon dioxide and the ligand is a .beta.-diketone such as hexafluoroacetylacetone or dibutyldiacetate. In other preferred embodiments, the metals in the metal-ligand complex are copper, silver, gold, tungsten, titanium, tantalum, tin, or mixtures thereof. In preferred embodiments, the reducing agent is hydrogen. The method provides an efficient process for dissociating metal-ligand complexes and produces easily-collected metal particles free from hydrocarbon solvent impurities. The ligand and the supercritical fluid can be regenerated to provide an economic, efficient process.

  8. Project Profile: High Operating Temperature Liquid Metal Heat Transfer Fluids

    Broader source: Energy.gov [DOE]

    The University of California, Los Angeles (UCLA), along with partners at the University of California, Berkeley, and Yale University, under the 2012 Multidisciplinary University Research Initiative (MURI): High Operating Temperature (HOT) Fluids funding opportunity, is investigating the use of metal alloys as a heat transfer fluid (HTF) in concentrating solar power (CSP) systems operating at temperatures in excess of 800°C. By allowing higher temperature operation, CSP systems can achieve greater efficiencies and thereby reduce the overall cost of electricity production.

  9. High Operating Temperature Liquid Metal Heat Transfer Fluids

    Broader source: Energy.gov [DOE]

    This fact sheet describes a UCLA-led solar project to investigate high operating temperature liquid metal heat transfer fluids, funded by the SunShot initiative. The project team is using a combination of modeling along with a variety of property measurement and validation studies to demonstrate that the metal alloys identified can meet all the needs of a concentrating solar power plant. A successful candidate fluid would allow for the reduction of the levelized cost of energy by increasing the operating temperature for the CSP plant power cycle, which would increase thermal-to-electric conversion efficiency.

  10. A coke/soot formation model for multiphase reacting flow simulation

    SciTech Connect (OSTI)

    Chang, S.L.; Lottes, S.A.; Petrick, M.; Zhou, C.Q. |

    1997-03-01

    Coke is a by-product in petroleum fluid catalytic cracking (FCC) processes. The concentration of coke in an FCC riser reactor is a critical parameter used to evaluate the riser performance. A coke formation and transport model was developed. It was incorporated into a computational fluid dynamic (CFD) computer code, ICRKFLO, to simulate the coke formation processes in an FCC riser reactor. Based on a similar process, a soot formation model can be derived from the coke formation model and used for diesel combustion processes, where soot is emitted as one of the primary pollutants.

  11. Metal chelate process to remove pollutants from fluids

    DOE Patents [OSTI]

    Chang, S.G.T.

    1994-12-06

    The present invention relates to improved methods using an organic iron chelate to remove pollutants from fluids, such as flue gas. Specifically, the present invention relates to a process to remove NO[sub x] and optionally SO[sub 2] from a fluid using a metal ion (Fe[sup 2+]) chelate wherein the ligand is a dimercapto compound wherein the --SH groups are attached to adjacent carbon atoms (HS--C--C--SH) or (SH--C--CCSH) and contain a polar functional group so that the ligand of DMC chelate is water soluble. Alternatively, the DMC is covalently attached to a water insoluble substrate such as a polymer or resin, e.g., polystyrene. The chelate is regenerated using electroreduction or a chemical additive. The dimercapto compound bonded to a water insoluble substrate is also useful to lower the concentration or remove hazardous metal ions from an aqueous solution. 26 figures.

  12. Metal chelate process to remove pollutants from fluids

    DOE Patents [OSTI]

    Chang, Shih-Ger T.

    1994-01-01

    The present invention relates to improved methods using an organic iron chelate to remove pollutants from fluids, such as flue gas. Specifically, the present invention relates to a process to remove NO.sub.x and optionally SO.sub.2 from a fluid using a metal ion (Fe.sup.2+) chelate wherein the ligand is a dimercapto compound wherein the --SH groups are attached to adjacent carbon atoms (HS--C--C--SH) or (SH--C--CCSH) and contain a polar functional group so that the ligand of DMC chelate is water soluble. Alternatively, the DMC' is covalently attached to a water insoluble substrate such as a polymer or resin, e.g., polystyrene. The chelate is regenerated using electroreduction or a chemical additive. The dimercapto compound bonded to a water insoluble substrate is also useful to lower the concentration or remove hazardous metal ions from an aqueous solution.

  13. Blast furnace coke quality in relation to petroleum coke addition

    SciTech Connect (OSTI)

    Alvarez, R.; Diez, M.A.; Menendez, J.A.; Barriocanal, C.; Pis, J.J.; Sirgado, M.

    1995-12-01

    The incorporation of petroleum coke as an additive in industrial coking coal blends is a practice often used by steel companies. A suitable blast furnace coke produced by replacing part of the coking coal blend with a suitable petroleum coke (addition of 5 to 15%), was made by Great Lakes Carbon Corporation and successfully tested at several blast furnaces. This coke had lower reactivity, less ash and slightly higher sulfur content than coke made without the addition of petroleum coke. In contrast with these results, it has been reported in a BCRA study that additions of petroleum coke to a strong coking coal, above 5 wt%, increased coke reactivity. These differences may be explained on the basis of the coal or blend characteristics to which petroleum coke is added. Petroleum coke addition seems to give better results if the coal/blend has high fluidity. The present situation in Spain is favorable for the use of petroleum coke. So, a study of laboratory and semi-industrial scale was made to assess the possibility of using petroleum coke as an additive to the typical industrial coal blend coked by the Spanish Steel Company, ENSIDESA. The influence of the petroleum coke particle size was also studied to semi-industrial scale.

  14. Dissolution of metal tritides in a simulated lung fluid

    SciTech Connect (OSTI)

    Cheng, Yung-Sung; Dahl, A.R.; Jow, Hong Nian

    1997-10-01

    Metal tritides including titanium tritide (Ti {sup 3}H{sub x}) and erbium tritide (Er {sup 3}H{sub x}) have been used as components of neutron generators. The current understanding of metal tritides and their radiation dosimetry for internal exposure is very limited, and the ICRP Publication 30 does not provide for tritium dosimetry in metal tritide form. However, a few papers in the literature suggest that the solubility of metal tritides could be low. The current radiation protection guidelines for metal tritide particles are based on the assumption that their biological behavior is similar to tritiated water, which could be easily absorbed into body fluid. Therefore, these particles could have relatively short biological half-lives (10 d). If the solubility is low, the biological half-life of metal tritide particles and the dosimetry of an inhalation exposure to these particles could be quite different from tritiated water. This paper describes experiments on the dissolution rate of titanium tritide particles in a simulated lung fluid. Titanium tritide particles with mean sizes of 103 {mu}m (coarse) and 0.95 {mu}m (fine) were used. The results showed that the coarse particles dissolved much more slowly than the fine particles. The long-term dissolution half times were 361 and 33 d for the coarse and fine particles, respectively. Dissolution data of the fine particles were consistent with the diffusion theory. The dissolution half times were longer than the 10-d biological half time for tritiated water in the body. This finding has significant implications for the current health protection guidelines, including annual limits of intakes and derived air concentrations.

  15. Western Canadian coking coals -- Thermal rheology and coking quality

    SciTech Connect (OSTI)

    Leeder, W.R.; Price, J.T.; Gransden, J.F.

    1997-12-31

    Methods of predicting coke strength developed from the thermal rheological properties of Carboniferous coals frequently indicate that Cretaceous coals would not make high quality coke -- yet both types of coals produce coke suitable for the iron blast furnace. This paper will discuss the reasons why Western Canadian coals exhibit lower rheological values and how to predict the strength of coke produced from them.

  16. Petroleum coke as a clean and reliable boiler fuel

    SciTech Connect (OSTI)

    Molen, R.V.

    1994-12-31

    Petroleum coke is the solid residue left over after all valuable liquid and gaseous components have been extracted from crude oil. A typical integrated refinery flowsheet when a coker is used is illustrated. Coking is a process which {open_quotes}removes{close_quotes} excess carbon from the crude in order to obtain a better carbon-to-hydrogen ratio as required by refineries to produce the balance of products presently demanded by the marketplace. Three basic types of cokers exists. The current production from these is shown. Most delayed cokers use a batch operation in which the coke forms a layer on the walls and is usually removed by hydroblasting after processing of the batch. This coke is therefore sized irregularly and must be crushed prior to use. Another form of delayed coking, also a batch process, results in {open_quotes}shot{close_quotes} coke which looks like multi-sized BB`s. Delayed cokes are by far the largest produced cokes. A distant second in production is fluid coke which is produced in a continuous process fluidized bed. The rarely produced flexicoke comes from an entrained bed reactor.

  17. Method for measuring particulate and gaseous metals in a fluid stream, device for measuring particulate and gaseous metals in a fluid stream

    DOE Patents [OSTI]

    Farber, Paul S.; Huang, Hann-Shen

    2001-01-01

    A method for analyzing metal in a fluid is provided comprising maintaining a first portion of a continuous filter media substrate at a temperature coinciding with the phase in which the metal is to be analyzed; contacting the fluid to a first portion of said substrate to retain the metal on the first portion of said substrate; preventing further contact of the fluid to the first portion of substrate; and contacting the fluid to a second portion of said substrate to retain metal on the second portion of the said substrate while simultaneously analyzing the first portion for metal. Also provided is a device for the simultaneous monitoring and analysis of metal in a fluid comprising a continuous filter media substrate; means for maintaining a first portion of said filter media substrate at a temperature coinciding with the phase in which the metal is to be analyzed; a means for contacting the fluid to the first portion of said substrate; a means for preventing further contact of the fluid to the first portion of substrate; a means for contacting the fluid to a second portion of said substrate to retain metal on the second portion of the said substrate; and means for analyzing the first portion for metal.

  18. Processing heavy crudes: advances in fluid and flexicoking technology

    SciTech Connect (OSTI)

    Allan, D.E.; Metrailer, W.J.; King, R.C.; Wiechert, S.

    1981-12-01

    The authors are concerned with Exxon's Fluid and Flexicoking processes which allow the refiner to convert the bottom of the crude barrel to clean products. This article primarily discusses enhancement of liquid yields from both processes and reduction of low-Btu gas from Flexicoking. Also discussed are recent advances in coking technology, which could make these processes more attractive. Flexicoking is an integrated coking/gasification process for upgrading heavy feedstocks. The process converts these feeds to a 99% yield of fuel gas, naphtha, middle distillates, heavy gas oil, and a low-sulfur coke gas. The remaining 1% is petroleum coke containing metals and other ash components present in the feed. 6 refs.

  19. Extraction of metals using supercritical fluid and chelate forming ligand

    DOE Patents [OSTI]

    Wai, C.M.; Laintz, K.E.

    1998-03-24

    A method of extracting metalloid and metal species from a solid or liquid material by exposing the material to a supercritical fluid solvent containing a chelating agent is described. The chelating agent forms chelates that are soluble in the supercritical fluid to allow removal of the species from the material. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is a fluorinated {beta}-diketone. In especially preferred embodiments the extraction solvent is supercritical carbon dioxide, and the chelating agent comprises a fluorinated {beta}-diketone and a trialkyl phosphate, or a fluorinated {beta}-diketone and a trialkylphosphine oxide. Although a trialkyl phosphate can extract lanthanides and actinides from acidic solutions, a binary mixture comprising a fluorinated {beta}-diketone and a trialkyl phosphate or a trialkylphosphine oxide tends to enhance the extraction efficiencies for actinides and lanthanides. The method provides an environmentally benign process for removing contaminants from industrial waste without using acids or biologically harmful solvents. The method is particularly useful for extracting actinides and lanthanides from acidic solutions. The chelate and supercritical fluid can be regenerated, and the contaminant species recovered, to provide an economic, efficient process. 7 figs.

  20. Extraction of metals using supercritical fluid and chelate forming legand

    DOE Patents [OSTI]

    Wai, Chien M.; Laintz, Kenneth E.

    1998-01-01

    A method of extracting metalloid and metal species from a solid or liquid material by exposing the material to a supercritical fluid solvent containing a chelating agent is described. The chelating agent forms chelates that are soluble in the supercritical fluid to allow removal of the species from the material. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is a fluorinated .beta.-diketone. In especially preferred embodiments the extraction solvent is supercritical carbon dioxide, and the chelating agent comprises a fluorinated .beta.-diketone and a trialkyl phosphate, or a fluorinated .beta.-diketone and a trialkylphosphine oxide. Although a trialkyl phosphate can extract lanthanides and actinides from acidic solutions, a binary mixture comprising a fluorinated .beta.-diketone and a trialkyl phosphate or a trialkylphosphine oxide tends to enhance the extraction efficiencies for actinides and lanthanides. The method provides an environmentally benign process for removing contaminants from industrial waste without using acids or biologically harmful solvents. The method is particularly useful for extracting actinides and lanthanides from acidic solutions. The chelate and supercritical fluid can be regenerated, and the contaminant species recovered, to provide an economic, efficient process.

  1. Methods for retarding coke formation during pyrolytic hydrocarbon processing

    SciTech Connect (OSTI)

    Not Available

    1993-06-22

    A method is described for inhibiting the formation and deposition of pyrolytic coke on the heated metal surfaces in contact with a hydrocarbon feedstock which is undergoing pyrolytic processing to produce lower hydrocarbon fractions and said metal surfaces having a temperature of about 1,400 F or higher, consisting essentially of adding to said hydrocarbon feedstock being pyrolytically processed a coke inhibiting amount of hydroquinone.

  2. Integration of stripping of fines slurry in a coking and gasification process

    DOE Patents [OSTI]

    DeGeorge, Charles W.

    1980-01-01

    In an integrated fluid coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a wet scrubbing process and wherein the resulting solids-liquid slurry is stripped to remove acidic gases, the stripped vapors of the stripping zone are sent to the gas cleanup stage of the gasification product gas. The improved stripping integration is particularly useful in the combination coal liquefaction process, fluid coking of bottoms of the coal liquefaction zone and gasification of the product coke.

  3. Coking and gasification process

    DOE Patents [OSTI]

    Billimoria, Rustom M.; Tao, Frank F.

    1986-01-01

    An improved coking process for normally solid carbonaceous materials wherein the yield of liquid product from the coker is increased by adding ammonia or an ammonia precursor to the coker. The invention is particularly useful in a process wherein coal liquefaction bottoms are coked to produce both a liquid and a gaseous product. Broadly, ammonia or an ammonia precursor is added to the coker ranging from about 1 to about 60 weight percent based on normally solid carbonaceous material and is preferably added in an amount from about 2 to about 15 weight percent.

  4. Determination of the effect of different additives in coking blends using a combination of in situ high-temperature {sup 1}H NMR and rheometry

    SciTech Connect (OSTI)

    Miguel C. Diaz; Karen M. Steel; Trevor C. Drage; John W. Patrick; Colin E. Snape

    2005-12-01

    High-temperature {sup 1}H NMR and rheometry measurements were carried out on 4:1 wt/wt blends of a medium volatile bituminous coal with two anthracites, two petroleum cokes, charcoal, wood, a low-temperature coke breeze, tyre crumb, and active carbon to determine the effects on fluidity development to identify the parameters responsible for these effects during pyrolysis and to study possible relationships among the parameters derived from these techniques. Positive, negative, and neutral effects were identified on the concentration of fluid material. Small positive effects (ca. 5-6%) were caused by blending the coal with petroleum cokes. Charcoal, wood, and active carbon all exerted negative effects on concentration (18-27% reduction) and mobility (12-25% reduction in T2) of the fluid phase, which have been associated with the inert character and high surface areas of these additives that adsorb the fluid phase of the coal. One of the anthracites and the low-temperature coke breeze caused deleterious effects to a lesser extent on the concentration (7-12%) and mobility (13-17%) of the fluid material, possibly due to the high concentration of metals in these additives (ca. 11% ash). Despite the high fluid character of tyre crumb at the temperature of maximum fluidity of the coal (73%), the mobility of the fluid phase of the blend was lower than expected. The comparison of {sup 1}H NMR and rheometry results indicated that to account for the variations in minimum complex viscosity for all the blends, both the maximum concentration of fluid phase and the maximum mobility of the fluid material had to be considered. For individual blends, two exponential relationships have been found between the complex viscosity and the concentration of solid phase in both the softening and resolidification stages but the parameters are different for each blend. 30 refs., 8 figs., 5 tabs.

  5. High coking value pitch

    SciTech Connect (OSTI)

    Miller, Douglas J.; Chang, Ching-Feng; Lewis, Irwin C.; Lewis, Richard T.

    2014-06-10

    A high coking value pitch prepared from coal tar distillate and has a low softening point and a high carbon value while containing substantially no quinoline insolubles is disclosed. The pitch can be used as an impregnant or binder for producing carbon and graphite articles.

  6. RESIDUA UPGRADING EFFICIENCY IMPROVEMENT MODELS: WRI COKING INDEXES

    SciTech Connect (OSTI)

    John F. Schabron; Joseph F. Rovani, Jr.; Francis P. Miknis; Thomas F. Turner

    2003-06-01

    Pyrolysis experiments were conducted with three residua at 400 C (752 F) at various residence times. The wt % coke and gaseous products were measured for the product oils. The Western Research Institute (WRI) Coking Indexes were determined for the product oils. Measurements were made using techniques that might correlate with the Coking Indexes. These included spin-echo proton nuclear magnetic resonance spectroscopy, heat capacity measurements at 280 C (536 F), and ultrasonic attenuation. The two immiscible liquid phases that form once coke formation begins were isolated and characterized for a Boscan residuum pyrolyzed at 400 C (752 F) for 55 minutes. These materials were analyzed for elemental composition (CHNS), porphyrins, and metals (Ni,V) content.

  7. Treatment of petroleum cokes to inhibit coke puffing

    SciTech Connect (OSTI)

    Orac, T.H.; Quandt, H.C.; Ball, D.R.

    1992-06-02

    This patent describes apparatus for treating raw petroleum coke particles. It comprises an elongated, cylindrical, calcining kiln having an inlet end and an outlet end; and entrance chamber and a discharge chamber, an elongated, cylindrical, cooler having an inlet end and an outlet end; means defining a retention chamber communicating with the discharge chamber; means defining a hot zone communicating with the retention chamber and the inlet end of the cooler; means for introducing a dry, granulated, puffing inhibitor into the retention chamber in contact with the calcined coke particles; and a coke delivery chamber for collecting the cooled, calcined coke particles at the outlet end of the cooler.

  8. COKEMASTER: Coke plant management system

    SciTech Connect (OSTI)

    Johanning, J.; Reinke, M.

    1996-12-31

    To keep coke utilization in ironmaking as competitive as possible, the potential to improve the economics of coke production has to be utilized. As one measure to meet this need of its customers, Krupp Koppers has expanded its existing ECOTROL computer system for battery heating control to a comprehensive Coke Plant Management System. Increased capacity utilization, lower energy consumption, stabilization of plant operation and ease of operation are the main targets.

  9. Coke from coal and petroleum

    DOE Patents [OSTI]

    Wynne, Jr., Francis E.; Lopez, Jaime; Zaborowsky, Edward J.

    1981-01-01

    A carbonaceous coke is manufactured by the delayed coking of a slurry mixture of from about 10 to about 30 weight percent of caking or non-caking coal and the remainder a petroleum resid blended at below 50.degree. C.

  10. High Operating Temperature Liquid Metal Heat Transfer Fluids (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-12-01

    The University of California, Los Angeles, the University of California, Berkeley, and Yale University is one of the 2012 SunShot CSP R&D awardees for their Multidisciplinary University Research Initiative (MURI): High Operating Temperature (HOT) Fluids. This fact sheet explains the motivation, description, and impact of the project.

  11. Organophosphorus compounds as coke inhibitors during naphtha pyrolysis. Effect of benzyl diethyl phosphite and triphenylphosphine sulfide

    SciTech Connect (OSTI)

    Das, P.; Prasad, S.; Kunztu, D.

    1992-09-01

    This paper reports that significant reduction in the rate of coke formation during naphtha pyrolysis was achieved by adding benzyl diethyl phosphite or triphenylphosphine sulfide to the feed. Although the yield of carbon oxides was reduced, there was no effect of these additives on the hydrocarbon yields. Addition of these organophosphorus compounds significantly reduced the concentration of metals, such as iron, nickel, and chromium, incorporated in the coke. A previously proposed model for coke inhibition due to the formation of a passivating metal-phosphorus complex could satisfactorily correlate the data.

  12. Ultrasound enhanced process for extracting metal species in supercritical fluids

    DOE Patents [OSTI]

    Wai, Chien M.; Enokida, Youichi

    2006-10-31

    Improved methods for the extraction or dissolution of metals, metalloids or their oxides, especially lanthanides, actinides, uranium or their oxides, into supercritical solvents containing an extractant are disclosed. The disclosed embodiments specifically include enhancing the extraction or dissolution efficiency with ultrasound. The present methods allow the direct, efficient dissolution of UO2 or other uranium oxides without generating any waste stream or by-products.

  13. Technologies for Extracting Valuable Metals and Compounds from Geothermal Fluids

    SciTech Connect (OSTI)

    Harrison, Stephen

    2014-04-30

    Executive Summary Simbol Materials studied various methods of extracting valuable minerals from geothermal brines in the Imperial Valley of California, focusing on the extraction of lithium, manganese, zinc and potassium. New methods were explored for managing the potential impact of silica fouling on mineral extraction equipment, and for converting silica management by-products into commercial products.` Studies at the laboratory and bench scale focused on manganese, zinc and potassium extraction and the conversion of silica management by-products into valuable commercial products. The processes for extracting lithium and producing lithium carbonate and lithium hydroxide products were developed at the laboratory scale and scaled up to pilot-scale. Several sorbents designed to extract lithium as lithium chloride from geothermal brine were developed at the laboratory scale and subsequently scaled-up for testing in the lithium extraction pilot plant. Lithium The results of the lithium studies generated the confidence for Simbol to scale its process to commercial operation. The key steps of the process were demonstrated during its development at pilot scale: 1. Silica management. 2. Lithium extraction. 3. Purification. 4. Concentration. 5. Conversion into lithium hydroxide and lithium carbonate products. Results show that greater than 95% of the lithium can be extracted from geothermal brine as lithium chloride, and that the chemical yield in converting lithium chloride to lithium hydroxide and lithium carbonate products is greater than 90%. The product purity produced from the process is consistent with battery grade lithium carbonate and lithium hydroxide. Manganese and zinc Processes for the extraction of zinc and manganese from geothermal brine were developed. It was shown that they could be converted into zinc metal and electrolytic manganese dioxide after purification. These processes were evaluated for their economic potential, and at the present time Simbol

  14. Clean Production of Coke from Carbonaceous Fines

    SciTech Connect (OSTI)

    Craig N. Eatough

    2004-11-16

    In order to produce steel (a necessary commodity in developed nations) using conventional technologies, you must have metallurgical coke. Current coke-making technology pyrolyzes high-quality coking coals in a slot oven, but prime coking coals are becoming more expensive and slot ovens are being shut-down because of age and environmental problems. The United States typically imports about 4 million tons of coke per year, but because of a world-wide coke scarcity, metallurgical coke costs have risen from about $77 per tonne to more than $225. This coke shortage is a long-term challenge driving up the price of steel and is forcing steel makers to search for alternatives. Combustion Resources (CR) has developed a technology to produce metallurgical coke from alternative feedstocks in an environmentally clean manner. The purpose of the current project was to refine material and process requirements in order to achieve improved economic benefits and to expand upon prior work on the proposed technology through successful prototype testing of coke products. The ultimate objective of this project is commercialization of the proposed technology. During this project period, CR developed coke from over thirty different formulations that meet the strength and reactivity requirements for use as metallurgical coke. The technology has been termed CR Clean Coke because it utilizes waste materials as feedstocks and is produced in a continuous process where pollutant emissions can be significantly reduced compared to current practice. The proposed feed material and operating costs for a CR Clean Coke plant are significantly less than conventional coke plants. Even the capital costs for the proposed coke plant are about half that of current plants. The remaining barrier for CR Clean Coke to overcome prior to commercialization is full-scale testing in a blast furnace. These tests will require a significant quantity of product (tens of thousands of tons) necessitating the construction

  15. Extraction of metals and/or metalloids from acidic media using supercritical fluids and salts

    DOE Patents [OSTI]

    Wai, Chien M.; Smart, Neil G.; Lin, Yuehe

    1998-01-01

    A method of extracting metalloid and metal species from a solid or liquid material by exposing the material to a fluid solvent, particularly supercritical carbon dioxide, containing a chelating agent is described. The chelating agent forms chelates that are soluble in the fluid to allow removal of the species from the material. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent comprises a trialkyl phosphate, a triaryl phosphate, a trialkylphosphine oxide, a triarylphosphine oxide, or mixtures thereof. The method provides an environmentally benign process for removing contaminants from industrial waste. The method is particularly useful for extracting actinides from acidic solutions, and the process can be aided by the addition of nitrate salts. The chelate and supercritical fluid can be regenerated, and the contaminant species recovered, to provide an economic, efficient process.

  16. Extraction of metals and/or metalloids from acidic media using supercritical fluids and salts

    DOE Patents [OSTI]

    Wai, C.M.; Smart, N.G.; Lin, Y.

    1998-06-23

    A method is described for extracting metalloid and metal species from a solid or liquid material by exposing the material to a fluid solvent, particularly supercritical carbon dioxide, containing a chelating agent. The chelating agent forms chelates that are soluble in the fluid to allow removal of the species from the material. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent comprises a trialkyl phosphate, a triaryl phosphate, a trialkylphosphine oxide, a triarylphosphine oxide, or mixtures thereof. The method provides an environmentally benign process for removing contaminants from industrial waste. The method is particularly useful for extracting actinides from acidic solutions, and the process can be aided by the addition of nitrate salts. The chelate and supercritical fluid can be regenerated, and the contaminant species recovered, to provide an economic, efficient process. 7 figs.

  17. Coke gasification: the influence and behavior of inherent catalytic mineral matter

    SciTech Connect (OSTI)

    Mihaela Grigore; Richard Sakurovs; David French; Veena Sahajwalla

    2009-04-15

    Gasification of coke contributes to its degradation in the blast furnace. In this study, the effect of gasification on the inherent catalytic minerals in cokes and their reciprocal influence on gasification are investigated. The catalytic mineral phases identified in the cokes used in this study were metallic iron, iron sulfides, and iron oxides. Metallic iron and pyrrhotite were rapidly oxidized during gasification to iron oxide. The catalysts had a strong influence on the apparent rates at the initial stages of reaction. As gasification proceeds, their effect on the reaction rate diminishes as a result of reducing the surface contact between catalyst and carbon matrix because of carbon consumption around the catalyst particles; with extended burnout the reactivity of the coke becomes increasingly dependent on surface area. The reaction rate in the initial stages was also influenced by the particle size of the catalytic minerals; for a given catalytic iron level, the cokes whose catalytic minerals were more finely dispersed had a higher apparent reaction rate than cokes containing larger catalytic particles. Iron, sodium, and potassium in the amorphous phase did not appear to affect the reaction rate. 40 refs., 16 figs., 6 tabs.

  18. Mathematical modeling of clearance between wall of coke oven and coke cake

    SciTech Connect (OSTI)

    Nushiro, K.; Matsui, T.; Hanaoka, K.; Igawa, K.; Sorimachi, K.

    1995-12-01

    A mathematical model was developed for estimating the clearance between the wall of the coke oven and the coke cake. The prediction model is based on the balance between the contractile force and the coking pressure. A clearance forms when the contractile force exceeds the coking pressure in this model. The contractile force is calculated in consideration of the visco-elastic behavior of the thermal shrinkage of the coke. The coking pressure is calculated considering the generation and dispersion of gas in the melting layer. The relaxation time off coke used in this model was obtained with a dilatometer under the load application. The clearance was measured by the laser sensor, and the internal gas pressure was measured in a test oven. The clearance calculated during the coking process were in good agreement with the experimental results, which supported the validity of the mathematical model.

  19. Inhibition of coke formation in pyrolysis furnaces

    SciTech Connect (OSTI)

    Tong, Y.; Poindexter, M.K.; Rowe, C.T.

    1995-12-31

    Coke formation in pyrolysis furnaces, which thermally convert hydrocarbons to ethylene as well as other useful products, adversely affects product yields, causes furnace down time for coke removal, and shortens furnace coil life. A phosphorus-based chemical treatment program was developed to inhibit the coke formation. The anticoking performance of the phosphorus-based treatment program was studied using a bench scale coking rate measurement apparatus. The programs`s influence on coke morphology and reactor surface was addressed using SEM/EDX surface characterization techniques. For comparison, similar studies were carried out with sulfur-containing species which are conventionally used in industrial practice as furnace additives. The present work demonstrated that the phosphorus-based treatment program provided an efficient and durable surface passivation against coke formation.

  20. Coke cake behavior under compressive forces

    SciTech Connect (OSTI)

    Watakabe, S.; Takeda, T.; Itaya, H.; Suginobe, H.

    1997-12-31

    The deformation of the coke cake and load on the side wall during pushing were studied using an electric furnace equipped with a movable wall. Coke cake was found to deform in three stages under compressive forces. The coke cake was shortened in the pushing direction in the cake deformation stage, and load was generated on the side walls in the high wall load stage. Secondary cracks in the coke cake were found to prevent load transmission on the wall. The maximum load transmission rate was controlled by adjusting the maximum fluidity and mean reflectance of the blended coal.

  1. Collector main replacement at Indianapolis Coke

    SciTech Connect (OSTI)

    Sickle, R.R. Van

    1997-12-31

    Indianapolis Coke is a merchant coke producer, supplying both foundry and blast furnace coke to the industry. The facility has three coke batteries: two 3 meter batteries, one Wilputte four divided and one Koppers Becker. Both batteries are underjet batteries and are producing 100% foundry coke at a net coking time of 30.6 hours. This paper deals with the No. 1 coke battery, which is a 72 oven, gun fired, 5 meter Still battery. No. 1 battery produces both foundry and blast furnace coke at a net coking rate of 25.4 hours. No. 1 battery was commissioned in 1979. The battery is equipped with a double collector main. Although many renovations have been completed to the battery, oven machinery and heating system, to date no major construction projects have taken place. Deterioration of the collector main was caused in part from elevated levels of chlorides in the flushing liquor, and temperature fluctuations within the collector main. The repair procedures are discussed.

  2. Method for separating metal chelates from other materials based on solubilities in supercritical fluids

    DOE Patents [OSTI]

    Wai, Chien M.; Smart, Neil G.; Phelps, Cindy

    2001-01-01

    A method for separating a desired metal or metalloi from impurities using a supercritical extraction process based on solubility differences between the components, as well as the ability to vary the solvent power of the supercritical fluid, is described. The use of adduct-forming agents, such as phosphorous-containing ligands, to separate metal or metalloid chelates in such processes is further disclosed. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of .beta.-diketones; phosphine oxides, such as trialkylphosphine oxides, triarylphosphine oxides and alkylarylphosphine oxides; phosphinic acids; carboxylic acids; phosphates, such as trialkylphosphates, triarylphosphates and alkylarylphosphates; crown ethers; dithiocarbamates; phosphine sulfides; phosphorothioic acids; thiophosphinic acids; halogenated analogs of these chelating agents; and mixtures of these chelating agents. In especially preferred embodiments, at least one of the chelating agents is fluorinated.

  3. Coke County, Texas: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Zone Subtype B. Places in Coke County, Texas Blackwell, Texas Bronte, Texas Robert Lee, Texas Retrieved from "http:en.openei.orgwindex.php?titleCokeCounty,Texas&oldid...

  4. Simulation of industrial coking -- Phase 1

    SciTech Connect (OSTI)

    Todoschuk, T.W.; Price, J.T.; Gransden, J.F.

    1997-12-31

    Two statistically designed experimental programs using an Appalachian and a Western Canadian coal blend were run in CANMET`s 460mm (18 inch) movable wall oven. Factors included coal grind, moisture, oil addition, carbonization rate and final coke temperature. Coke quality parameters including CSR, coal charge characteristics and pressure generation were analyzed.

  5. Coke oven gas injection to blast furnaces

    SciTech Connect (OSTI)

    Maddalena, F.L.; Terza, R.R.; Sobek, T.F.; Myklebust, K.L.

    1995-12-01

    U.S. Steel has three major facilities remaining in Pennsylvania`s Mon Valley near Pittsburgh. The Clairton Coke Works operates 12 batteries which produce 4.7 million tons of coke annually. The Edgar Thomson Works in Braddock is a 2.7 million ton per year steel plant. Irvin Works in Dravosburg has a hot strip mill and a range of finishing facilities. The coke works produces 120 mmscfd of coke oven gas in excess of the battery heating requirements. This surplus gas is used primarily in steel re-heating furnaces and for boiler fuel to produce steam for plant use. In conjunction with blast furnace gas, it is also used for power generation of up to 90 MW. However, matching the consumption with the production of gas has proved to be difficult. Consequently, surplus gas has been flared at rates of up to 50 mmscfd, totaling 400 mmscf in several months. By 1993, several changes in key conditions provided the impetus to install equipment to inject coke oven gas into the blast furnaces. This paper describes the planning and implementation of a project to replace natural gas in the furnaces with coke oven gas. It involved replacement of 7 miles of pipeline between the coking plants and the blast furnaces, equipment capable of compressing coke oven gas from 10 to 50 psig, and installation of electrical and control systems to deliver gas as demanded.

  6. Factors affecting coking pressures in tall coke ovens

    SciTech Connect (OSTI)

    Grimley, J.J.; Radley, C.E.

    1995-12-01

    The detrimental effects of excessive coking pressures, resulting in the permanent deformation of coke oven walls, have been recognized for many years. Considerable research has been undertaken worldwide in attempts to define the limits within which a plant may safely operate and to quantify the factors which influence these pressures. Few full scale techniques are available for assessing the potential of a coal blend for causing wall damage. Inference of dangerous swelling pressures may be made however by the measurement of the peak gas pressure which is generated as the plastic layers meet and coalesce at the center of the oven. This pressure is referred to in this report as the carbonizing pressure. At the Dawes Lane cokemaking plant of British Steel`s Scunthorpe Works, a large database has been compiled over several years from the regulator measurement of this pressure. This data has been statistically analyzed to provide a mathematical model for predicting the carbonizing pressure from the properties of the component coals, the results of this analysis are presented in this report.

  7. Rheology of petroleum coke-water slurry

    SciTech Connect (OSTI)

    Prasad, M.; Mall, B.K.; Mukherjee, A.; Basu, S.K.; Verma, S.K.; Narasimhan, K.S.

    1998-07-01

    This paper reports the results of the studies carried out on the optimization of particle size distribution, the rheological characteristics and stability of highly loaded petroleum coke-water slurry using three additives. The solids loading achieved in the slurries were in the range of 65% to 75.6% depending on the additives used. Slurry viscosity varied between 267 to 424 mPas at 128 s{sup {minus}} shear rate. The petroleum coke-water slurries exhibited pseudoplastic characteristics with yield tending towards Bingham plastic as the solids loading progressively increased. The effect of addition of petroleum coke to the extent of 25% in coal-water slurry prepared from low ash Ledo coal of Makum field in Assam was also examined. The slurry containing coal-petroleum coke blend showed better stability, having shelf life of 7 days as compared to 5 days in the case of petroleum coke-water slurry.

  8. Coke formation in visbreaking process

    SciTech Connect (OSTI)

    Yan, T.Y. )

    1987-04-01

    Visbreaking is a mild cracking process primarily used to reduce residual oil viscosity and thus decrease the amount of cutter stock required for blending to heavy fuels specification. It can also be used to produce incremental quantities of gasoline, middle distillates and catalytic cracker feeds. This process was widely used in the 1930s and 1940s and became obsolete until a few years ago. When the need for increased conversion of residues to light products became desirable, visbreaking offered economic advantages to many refining schemes - especially in Western Europe. Between 1978-1981, Exxon brought on stream seven visbreakers ranging from 1900 to 9100 tons/SD capacity. In January 1983, the world-wide visbreaking capacity was over 2 MM B/SD. The visbreaking process and its application in refinery operations have been well described. In general, the process economics improve as the process severity is increased but it is limited by coke formation in the process. For this reason, they have studied the kinetics of coke formation in the visbreaking process.

  9. New additive retards coke formation in ethylene furnace tubes

    SciTech Connect (OSTI)

    Not Available

    1994-05-09

    Adding relatively small amounts of a new additive to the feed stream of a steam cracker can inhibit coke formation on the metal surfaces of processing equipment and increase furnace run time. The additive comprises a variable mixture of four to six inorganic salts in aqueous solution. The components of the additive mixture can be varied, as needed, for processing heavy feed materials such as heavy naphtha and gas oil. The process was first tested at a Korean petrochemical plant and is now operating successfully at a commercial facility in Russia. The results of the Korean trial are presented here.

  10. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Michael Volk; Keith Wisecarver

    2003-09-26

    Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world

  11. Mozambique becomes a major coking coal exporter?

    SciTech Connect (OSTI)

    Ruffini, A.

    2008-06-15

    In addition to its potential role as a major international supplier of coking coal, Mozambique will also become a major source of power generation for southern Africa. 3 figs.

  12. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Michael Volk; Keith Wisecarver

    2004-09-26

    Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world

  13. The waste water free coke plant

    SciTech Connect (OSTI)

    Schuepphaus, K.; Brink, N.

    1995-12-01

    Apart from coke which is the actual valuable material a coke oven plant also produces a substantial volume of waste water. These effluent water streams are burdened with organic components (e.g. phenols) and inorganic salts (e.g. NH{sub 4}Cl); due to the concentration of the constituents contained therein these effluent waters must be subjected to a specific treatment before they can be introduced into public waters. For some years a lot of separation tasks have been solved successfully by applying the membrane technology. It was especially the growing number of membrane facilities for cleaning of landfill leakage water whose composition can in fact be compared with that of coking plant waste waters (organic constituents, high salt fright, ammonium compounds) which gave Thyssen Still Otto Anlagentechnik the idea for developing a process for coke plant effluent treatment which contains the membrane technology as an essential component.

  14. Demand for superpremium needle cokes on upswing

    SciTech Connect (OSTI)

    Acciarri, J.A.; Stockman, G.H. )

    1989-12-01

    The authors discuss how recent supply shortages of super-premium quality needle cokes, plus the expectation of increased shortfalls in the future, indicate that refiners should consider upgrading their operations to fill these demands. Calcined, super-premium needle cokes are currently selling for as much as $550/metric ton, fob producer, and increasing demand will continue the upward push of the past year. Needle coke, in its calcined form, is the major raw material in the manufacture of graphite electrodes. Used in steelmaking, graphite electrodes are the electrical conductors that supply the heat source, through arcing electrode column tips, to electric arc steel furnaces. Needle coke is commercially available in three grades - super premium, premium, and intermediate. Super premium is used to produce electrodes for the most severe electric arc furnace steelmaking applications, premium for electrodes destined to less severe operations, and intermediate for even less critical needs.

  15. Oil coking propensity under hydroprocessing conditions

    SciTech Connect (OSTI)

    Kriz, J.F. )

    1991-01-01

    If the processability of heavy or residual oil is assessed in terms of conversion to distillate oils, the tendency to form carbonaceous (coke) deposits in the reactor would impose limits on the operating conditions, since any significant coke accumulation on a continuing basis would be prohibitive. Experimentally, one can evaluate the feedstock coking propensity in a bench-scale reactor for a set of typical hydroprocessing conditions by varying the temperature near the threshold of coking. For a number of different feedstocks examined by this method, an empirical function can be found correlating the coking propensity with some of the characteristic properties determined by routine analyses. The present approach used a combination of physical and chemical properties including density and contents of Conradson Carbon residue, pentane and toluene insolubles, fraction of high-boiling pitch, and carbon, hydrogen, nitrogen, sulfur and ash. Feedstocks were chosen to cover a wide but practical range of properties to establish their impact on the coking propensity. Although these relationships apply to thermal hydroprocessing, the role of catalysts is also indicated.

  16. Unmanned operation of the coke guides at Hoogovens IJmuiden Coke Plant 1

    SciTech Connect (OSTI)

    Vos, D.; Mannes, N.; Poppema, B.

    1995-12-01

    Due to the bad condition of batteries and many ovens under repair, Hoogovens was forced to partially repair and rebuild the Coke plant No. 1. The production of coke at Coke plant No. 1 is realized in 3 production blocks subdivided in 6 batteries. Besides a renovated installation, all coke oven machines were renewed. A total of five identical machine sets are available. Each consists of a pusher machine, larry car, coke guide and quench car with diesel locomotive. A complete automated control system was implemented. The main objectives were a highly regular coking and pushing process, automated traveling and positioning and a centrally coordinated interlocking of machine functions. On each operational machine however an operator performed the supervisory control of the automated machine functions. After years of good experience with the automated system, economical reasons urged further personnel reduction from 1994 on. Totally 375 people were involved, including the maintenance department. To reduce the occupation at coke plant No. 1, the coke guide was the first machine to be fully automated because of the isolated and uncomfortable working place.

  17. Radial-directed fluid-pressure-loaded all-metal-sealed gate valve

    DOE Patents [OSTI]

    Batzer, Thomas H.

    1992-01-01

    A large diameter gate valve uses a radially directed fluid pressure loaded all metal seal formed by engaging and disengaging a fixed and a moveable seal element. The fixed element is formed of a circular flange which contains a pressure chamber with a deformable wall, and is mounted to the valve body. The moving seal element contains an annular recess which mates with the circular flange, and is carried on a moveable sub-frame which moves on a frame fixed in the valve body. The valve opening defines an axis in a first direction, and the sub-frame moves through the valve body in a second direction which is substantially perpendicular to the first direction. The sub-frame and moveable seal element move in the second direction until the moveable element reaches a stop mounted in the valve body at which position the moveable element is aligned with but spaced apart from the fixed element. As the sub-frame continues to move in the second direction, the moveable element is forced to move toward and engage the fixed element. The pressure chamber in the flange is then pressurized to complete the seal.

  18. The correlation between reactivity and ash mineralogy of coke

    SciTech Connect (OSTI)

    Kerkkonen, O.; Mattila, E.; Heiniemi, R.

    1996-12-31

    Rautaruukki is a modern integrated Finnish steel works having a production of 2.4 mil. t/year of flat products. The total fuel consumption of the two blast furnaces in 1994 was 435 kg/t HM. Coke used was 345 kg/t HM and oil injection was 90 kg/t HM. The coking plant was taken in to operation in 1987 and is the only one in Finland, which means that the coking tradition is very short. Coke production is 0.9 mil. t/year. The coking blends include 70--80% medium volatile coals having a wide range of total dilatation. From time to time disturbances in the operation of the blast furnaces have occurred in spite of the fact that the reactivity of the coke used has remained constant or even decreased. It was thought necessary to investigate the factors affecting coke reactivity, in order to better understand the results of the reactivity test. This paper deals with carbonization tests done in a 7 kg test oven using nine individual coals having volatile-matter contents of 17--36% (dry) and seven blends made from these coals. Coke reactivity with CO{sub 2} at 1100 C (CRI) and coke strength after reaction (CSR) were determined using the test developed by the Nippon Steel Corporation. The influence of coke carbon form, porosity and especially ash mineralogy on the coke reactivity were examined. The effects of some additives; petroleum coke (pet coke), the spillage material from the coke ovens and oxidized coal, on coke quality were also studied. Typical inorganic minerals found in coals were added to one of the high volatile coals, which was then coked to determine the affect of the minerals on the properties of the coke produced.

  19. Rheology of petroleum coke-water slurry

    SciTech Connect (OSTI)

    Prasad, M.; Mall, B.K.; Mukherjee, A.

    1998-04-01

    This paper reports the results of the studies carried out on the optimization of particle size distribution, the theological characteristics and stability of highly loaded petroleum coke-water slurry using three additives. The solids loading achieved in the slurries were in the range of 65% to 75.6% depending on the additives used. Slurry viscosity varied between 267 to 424 mPas at 128 s{sup -1} shear rate. The petroleum coke-water slurries exhibited pseudoplastic characteristics with yield tending towards Bingham plastic as the solids loading progressively increased.

  20. Petroleum coke: A viable fuel for power generation

    SciTech Connect (OSTI)

    Dymond, R.E.

    1995-09-01

    As the power generation industry struggles to meet the seemingly divergent goals of reduced emissions and increased electricity demand during the 1990s, petroleum coke`s use as a low cost BTU source should be seriously considered. Since this material is produced at petroleum refineries-thus affected by variables unfamiliar to most power generators-industry participants often do not understand what forces drive coke markets. This article will address these forces and provide some insight about petroleum coke`s future as a viable fuel for power generation.

  1. Petroleum coke: A viable fuel for power generation

    SciTech Connect (OSTI)

    Dymond, R.E.

    1994-12-31

    As the power generation industry struggles to meet the seemingly divergent goals of reduced emissions and increased electricity demand during the 1990s, petroleum coke`s use as a low cost BTU source should be seriously considered. since this material is produced at petroleum refineries - thus affected by variables unfamiliar to most power generators - industry participants often do not understand what forces drive coke markets. This article will address these forces and provide some insight about petroleum coke`s future as a viable fuel for power generation.

  2. Reducing dust emissions at OAO Alchevskkoks coke battery 10A

    SciTech Connect (OSTI)

    T.F. Trembach; E.N. Lanina

    2009-07-15

    Coke battery 10A with rammed batch is under construction at OAO Alchevskkoks. The design documentation developed by Giprokoks includes measures for reducing dust emissions to the atmosphere. Aspiration systems with dry dust trapping are employed in the new components of coke battery 10A and in the existing coke-sorting equipment. Two-stage purification of dusty air in cyclones and bag filters is employed for the coke-sorting equipment. This system considerably reduces coke-dust emissions to the atmosphere.

  3. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Michael Volk Jr; Keith Wisecarver

    2005-10-01

    Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world

  4. Residuum conversion using hydroprocessing with delayed coking

    SciTech Connect (OSTI)

    Wilson, J.R.

    1985-01-01

    Chevron's Pascagoula Resid Conversion Project utilizes a combination of hydroprocessing and delayed coking. In conjunction with existing process units, this conversion capacity gives the Pascagoula Refinery flexibility to meet the light product demands while processing heavier and lower valued crude oils. Design concepts and considerations into the final process selection are discussed.

  5. RESIDUA UPGRADING EFFICIENCY IMPROVEMENT MODELS: COKE FORMATION PREDICTABILITY MAPS

    SciTech Connect (OSTI)

    John F. Schabron; A. Troy Pauli; Joseph F. Rovani Jr.

    2002-05-01

    The dispersed particle solution model of petroleum residua structure was used to develop predictors for pyrolytic coke formation. Coking Indexes were developed in prior years that measure how near a pyrolysis system is to coke formation during the coke formation induction period. These have been demonstrated to be universally applicable for residua regardless of the source of the material. Coking onset is coincidental with the destruction of the ordered structure and the formation of a multiphase system. The amount of coke initially formed appears to be a function of the free solvent volume of the original residua. In the current work, three-dimensional coke make predictability maps were developed at 400 C, 450 C, and 500 C (752 F, 842 F, and 932 F). These relate residence time and free solvent volume to the amount of coke formed at a particular pyrolysis temperature. Activation energies for two apparent types of zero-order coke formation reactions were estimated. The results provide a new tool for ranking residua, gauging proximity to coke formation, and predicting initial coke make tendencies.

  6. REDUCING POWER PRODUCTION COSTS BY UTILIZING PETROLEUM COKE

    SciTech Connect (OSTI)

    Kevin C. Galbreath; Donald L. Toman; Christopher J. Zygarlicke

    1999-09-01

    Petroleum coke, a byproduct of the petroleum-refining process, is an attractive primary or supplemental fuel for power production primarily because of a progressive and predictable increase in the production volumes of petroleum coke (1, 2). Petroleum coke is most commonly blended with coal in proportions suitable to meet sulfur emission compliance. Petroleum coke is generally less reactive than coal; therefore, the cofiring of petroleum coke with coal typically improves ignition, flame stability, and carbon loss relative to the combustion of petroleum coke alone. Although petroleum coke is a desirable fuel for producing relatively inexpensive electrical power, concerns about the effects of petroleum coke blending on combustion and pollution control processes exist in the coal-fired utility industry (3). The Energy & Environmental Research Center (EERC) completed a 2-year technical assessment of petroleum coke as a supplemental fuel. A survey questionnaire was sent to seven electric utility companies that are currently cofiring coal and petroleum coke in an effort to solicit specific suggestions on research needs and fuel selections. An example of the letter and survey questionnaire is presented in Appendix A. Interest was expressed by most utilities in evaluating the effects of petroleum coke blending on grindability, combustion reactivity, fouling, slagging, and fly ash emissions control. Unexpectedly, concern over corrosion was not expressed by the utilities contacted. Although all seven utilities responded to the question, only two utilities, Northern States Power Company (NSP) and Ameren, sent fuels to the EERC for evaluation. Both utilities sent subbituminous coals from the Power River Basin and petroleum shot coke samples. Petroleum shot coke is produced unintentionally during operational upsets in the petroleum refining process. This report evaluates the effects of petroleum shot coke blending on grindability, fuel reactivity, fouling/slagging, and

  7. REDUCING POWER PRODUCTION COSTS BY UTILIZING PETROLEUM COKE

    SciTech Connect (OSTI)

    1998-09-01

    A Powder River Basin subbituminous coal from the North Antelope mine and a petroleum shot coke were received from Northern States Power Company (NSP) for testing the effects of parent fuel properties on coal-coke blend grindability and evaluating the utility of petroleum coke blending as a strategy for improving electrostatic precipitator (ESP) particulate collection efficiency. Petroleum cokes are generally harder than coals, as indicated by Hardgrove grindability tests. Therefore, the weaker coal component may concentrate in the finer size fractions during the pulverizing of coal-coke blends. The possibility of a coal-coke size fractionation effect is being investigated because it may adversely affect combustion performance. Although the blending of petroleum coke with coal may adversely affect combustion performance, it may enhance ESP particulate collection efficiency. Petroleum cokes contain much higher concentrations of V relative to coals. Consequently, coke blending can significantly increase the V content of fly ash resulting from coal-coke combustion. Pentavalent vanadium oxide (V{sub 2}O{sub 5}) is a known catalyst for transforming gaseous sulfur dioxide (SO{sub 2}[g]) to gaseous sulfur trioxide (SO{sub 3}[g]). The presence of SO{sub 3}(g) strongly affects fly ash resistivity and, thus, ESP performance.

  8. Comparative evaluation of rejuvenation of spent residue hydroprocessing catalysts in the decoked (oxide) and coked (sulfided) forms

    SciTech Connect (OSTI)

    Stanislaus, A.; Marafi, M.; Absi-Halabi, M.

    1993-12-31

    Two routes were used to rejuvenate spent residue hydroprocessing catalyst by leaching foulant metals. In the first, the deoiled spent catalyst containing coke and deposited metals in the sulfide form was chemically treated to remove the metal foulants. In the second, the deoiled spent catalyst was decoked by controlled combustion of coke and the resultant coke free catalyst containing the metals in the oxide form was subjected to leaching. Oxalic acid, a chelating agent, that can form soluble metal complexes was used for metal leaching in both routes. The influence of adding an oxidizing agent such as H{sub 2}O{sub 2} to oxalic acid on the leaching efficiency was also examined in both routes. The spent and treated catalysts were characterized and the improvements in surface area pore volume and HDS activity of the catalysts as a result of leaching in different routes compared. The selectivity for leaching of the major metal foulant (vanadium) was better, and activity recovery was higher for the catalyst rejuvenated by metal leaching prior to decoking.

  9. Model based control of a coke battery

    SciTech Connect (OSTI)

    Stone, P.M.; Srour, J.M.; Zulli, P.; Cunningham, R.; Hockings, K.

    1997-12-31

    This paper describes a model-based strategy for coke battery control at BHP Steel`s operations in Pt Kembla, Australia. The strategy uses several models describing the battery thermal and coking behavior. A prototype controller has been installed on the Pt Kembla No. 6 Battery (PK6CO). In trials, the new controller has been well accepted by operators and has resulted in a clear improvement in battery thermal stability, with a halving of the standard deviation of average battery temperature. Along with other improvements to that battery`s operations, this implementation has contributed to a 10% decrease in specific battery energy consumption. A number of enhancements to the low level control systems on that battery are currently being undertaken in order to realize further benefits.

  10. Dynamic compression of dense oxide (Gd3Ga5O12) from 0.4 to 2.6 TPa: Universal Hugoniot of fluid metals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ozaki, N.; Nellis, W. J.; Mashimo, T.; Ramzan, M.; Ahuja, R.; Kaewmaraya, T.; Kimura, T.; Knudson, M.; Miyanishi, K.; Sakawa, Y.; et al

    2016-05-19

    Materials at high pressures and temperatures are of great current interest for warm dense matter physics, planetary sciences, and inertial fusion energy research. Shock-compression equation-of-state data and optical reflectivities of the fluid dense oxide, Gd3Ga5O12 (GGG), were measured at extremely high pressures up to 2.6 TPa (26 Mbar) generated by high-power laser irradiation and magnetically-driven hypervelocity impacts. Above 0.75 TPa, the GGG Hugoniot data approach/reach a universal linear line of fluid metals, and the optical reflectivity most likely reaches a constant value indicating that GGG undergoes a crossover from fluid semiconductor to poor metal with minimum metallic conductivity (MMC). Thesemore » results suggest that most fluid compounds, e.g., strong planetary oxides, reach a common state on the universal Hugoniot of fluid metals (UHFM) with MMC at sufficiently extreme pressures and temperatures. Lastly, the systematic behaviors of warm dense fluid would be useful benchmarks for developing theoretical equation-of-state and transport models in the warm dense matter regime in determining computational predictions.« less

  11. Cyanide treatment options in coke plants

    SciTech Connect (OSTI)

    Minak, H.P.; Lepke, P.

    1997-12-31

    The paper discusses the formation of cyanides in coke oven gas and describes and compares waste processing options. These include desulfurization by aqueous ammonia solution, desulfurization using potash solution, desulfurization in oxide boxes, decomposition of NH{sub 3} and HCN for gas scrubbing. Waste water treatment methods include chemical oxidation, precipitation, ion exchange, reverse osmosis, and biological treatment. It is concluded that biological treatment is the most economical process, safe in operation and requires a minimum of manpower.

  12. Improvement of coke quality by utilization of hydrogenation residue

    SciTech Connect (OSTI)

    Meckel, J.F. ); Wairegi, T. )

    1993-01-01

    Hydrogenation residue is the product left over when petroleum residue feedstocks (or coal) are treated by, e.g. the Veba Combi Cracking (VCC) process. Many tests in semitechnical and full-sized coke ovens were carried out with hydrogenation residue (HR) as an additive in coking coal blends for the production of blast furnace coke or foundry coke. The results of the investigations reported in this paper demonstrate that HR is a very promising alternative for enlarging the coking coal basis compared to other processes or the use of other additives. The application of HR on an industrial scale did not indicate any negative impact on the handling of the hydrogenation residue or on the operation of the coke oven battery.

  13. Petroleum-derived additive reduces coke on hydrotreating catalyst

    SciTech Connect (OSTI)

    Not Available

    1993-12-27

    Upgrading heavy oils is becoming increasingly important as the world crude slate gets heavier and demand for light products increases. But most upgrading processes must contend with problems related to coke formation during hydrotreating. Three researchers have found that materials having high radical-scavenging ability can reduce coke formation when applied to hydrotreating heavy oils. And these materials can be produced from heavy petroleum fractions. The paper discusses coke formation, the research program, and the pilot plant.

  14. Development of an Advanced Combined Heat and Power (CHP) System Utilizing Off-Gas from Coke Calcination

    Broader source: Energy.gov [DOE]

    Coke calcination is a process that involves the heating of green petroleum coke in order to remove volatile material and purify the coke for further processing. Calcined coke is vital to the...

  15. Development and Testing of the Advanced CHP System Utilizing the Off-Gas from the Innovative Green Coke Calcining Process in Fluidized Bed

    SciTech Connect (OSTI)

    Chudnovsky, Yaroslav; Kozlov, Aleksandr

    2013-08-15

    Green petroleum coke (GPC) is an oil refining byproduct that can be used directly as a solid fuel or as a feedstock for the production of calcined petroleum coke. GPC contains a high amount of volatiles and sulfur. During the calcination process, the GPC is heated to remove the volatiles and sulfur to produce purified calcined coke, which is used in the production of graphite, electrodes, metal carburizers, and other carbon products. Currently, more than 80% of calcined coke is produced in rotary kilns or rotary hearth furnaces. These technologies provide partial heat utilization of the calcined coke to increase efficiency of the calcination process, but they also share some operating disadvantages. However, coke calcination in an electrothermal fluidized bed (EFB) opens up a number of potential benefits for the production enhancement, while reducing the capital and operating costs. The increased usage of heavy crude oil in recent years has resulted in higher sulfur content in green coke produced by oil refinery process, which requires a significant increase in the calcinations temperature and in residence time. The calorific value of the process off-gas is quite substantial and can be effectively utilized as an “opportunity fuel” for combined heat and power (CHP) production to complement the energy demand. Heat recovered from the product cooling can also contribute to the overall economics of the calcination process. Preliminary estimates indicated the decrease in energy consumption by 35-50% as well as a proportional decrease in greenhouse gas emissions. As such, the efficiency improvement of the coke calcinations systems is attracting close attention of the researchers and engineers throughout the world. The developed technology is intended to accomplish the following objectives: - Reduce the energy and carbon intensity of the calcined coke production process. - Increase utilization of opportunity fuels such as industrial waste off-gas from the novel

  16. Nippon Coke and Engineering Sumitomo Corp JV | Open Energy Information

    Open Energy Info (EERE)

    navigation, search Name: Nippon Coke and Engineering & Sumitomo Corp JV Place: Tokyo, Japan Zip: 135-6007 Product: Japan-based natural graphite base anode materials joint...

  17. Reducing power production costs by utilizing petroleum coke. Annual report

    SciTech Connect (OSTI)

    Galbreath, K.C.

    1998-07-01

    A Powder River Basin subbituminous coal from the North Antelope mine and a petroleum shot coke were received from Northern States Power Company (NSP) for testing the effects of parent fuel properties on coal-coke blend grindability and evaluating the utility of petroleum coke blending as a strategy for improving electrostatic precipitator (ESP) particulate collection efficiency. Petroleum cokes are generally harder than coals, as indicated by Hardgrove grindability tests. Therefore, the weaker coal component may concentrate in the finer size fractions during the pulverizing of coal-coke blends. The possibility of a coal-coke size fractionation effect is being investigated because it may adversely affect combustion performance, it may enhance ESP particulate collection efficiency. Petroleum cokes contain much higher concentrations of V relative to coals. Consequently, coke blending can significantly increase the V content of fly ash resulting from coal-coke combustion. Pentavalent vanadium oxide (V{sub 2}O{sub 5}) is a known catalyst for transforming gaseous sulfur dioxide (SO{sub 2}[g]) to gaseous sulfur trioxide (SO{sub 3}[g]). The presence of SO{sub 3}(g) strongly affects fly ash resistivity and, thus, ESP performance.

  18. Petroleum coke supply: present problems and future prospects

    SciTech Connect (OSTI)

    Brandt, H.H.

    1982-08-01

    Since the 1973 OPEC oil embargo, the coke market's strength has gradually shifted, for the most part, from the buyer to the seller. This general assessment is subject to localized exceptions and temporary reversals (such as the present market weakness due to the low level of primary aluminum production). However, there are two major factors which will influence the trend toward higher coke prices for anode use by aluminum producers: decreasing supplies of high-quality coke, and revised marketing strategies of coke producers.

  19. Lime addition to heavy crude oils prior to coking

    SciTech Connect (OSTI)

    Kessick, M. A.; George, Z. M.; Schneider, L. G.

    1985-06-04

    The sulphur emissive capability, on combustion, of coke which is formed during upgrading of sulphur-containing heavy crude oils, including oil sands bitumen, or residua is decreased by the addition of slaked lime or calcium oxide to the heavy crude oil prior to coking. The presence of the slaked lime or calcium oxide leads to an increased yield of liquid distillates at coking temperatures of about 450/sup 0/ to about 500/sup 0/ C. Ash remaining after combustion of the coke may be leached to recover nickel and vanadium values therefrom.

  20. Coupling scales for modelling heavy metal vaporization from municipal solid waste incineration in a fluid bed by CFD

    SciTech Connect (OSTI)

    Soria, José; Gauthier, Daniel; Flamant, Gilles; Rodriguez, Rosa; Mazza, Germán

    2015-09-15

    Highlights: • A CFD two-scale model is formulated to simulate heavy metal vaporization from waste incineration in fluidized beds. • MSW particle is modelled with the macroscopic particle model. • Influence of bed dynamics on HM vaporization is included. • CFD predicted results agree well with experimental data reported in literature. • This approach may be helpful for fluidized bed reactor modelling purposes. - Abstract: Municipal Solid Waste Incineration (MSWI) in fluidized bed is a very interesting technology mainly due to high combustion efficiency, great flexibility for treating several types of waste fuels and reduction in pollutants emitted with the flue gas. However, there is a great concern with respect to the fate of heavy metals (HM) contained in MSW and their environmental impact. In this study, a coupled two-scale CFD model was developed for MSWI in a bubbling fluidized bed. It presents an original scheme that combines a single particle model and a global fluidized bed model in order to represent the HM vaporization during MSW combustion. Two of the most representative HM (Cd and Pb) with bed temperatures ranging between 923 and 1073 K have been considered. This new approach uses ANSYS FLUENT 14.0 as the modelling platform for the simulations along with a complete set of self-developed user-defined functions (UDFs). The simulation results are compared to the experimental data obtained previously by the research group in a lab-scale fluid bed incinerator. The comparison indicates that the proposed CFD model predicts well the evolution of the HM release for the bed temperatures analyzed. It shows that both bed temperature and bed dynamics have influence on the HM vaporization rate. It can be concluded that CFD is a rigorous tool that provides valuable information about HM vaporization and that the original two-scale simulation scheme adopted allows to better represent the actual particle behavior in a fluid bed incinerator.

  1. VACASULF operation at Citizens Gas and Coke Utility

    SciTech Connect (OSTI)

    Currey, J.H.

    1995-12-01

    Citizens Gas and Coke Utility is a Public Charitable Trust which operates as the Department of Utilities of the City of Indianapolis, Indiana. Indianapolis Coke, the trade name for the Manufacturing Division of the Utility, operates a by-products coke plant in Indianapolis, Indiana. The facility produces both foundry and blast furnace coke. Surplus Coke Oven gas, generated by the process, is mixed with Natural Gas for sale to industrial and residential customers. In anticipation of regulatory developments, beginning in 1990, Indianapolis Coke undertook the task to develop an alternate Coke Oven Gas desulfurization technology for its facility. The new system was intended to perform primary desulfurization of the gas, dramatically extending the oxide bed life, thus reducing disposal liabilities. Citizens Gas chose the VACASULF technology for its primary desulfurization system. VACASULF requires a single purchased material, Potassium Hydroxide (KOH). The KOH reacts with Carbon Dioxide in the coke Oven Gas to form Potassium Carbonate (potash) which in turn absorbs the Hydrogen Sulfide. The rich solution releases the absorbed sulfide under strong vacuum in the desorber column. Operating costs are reduced through utilization of an inherent heat source which is transferred indirectly via attendant reboilers. The Hydrogen Sulfide is transported by the vacuum pumps to the Claus Kiln and Reactor for combustion, reaction, and elemental Sulfur recovery. Regenerated potash solution is returned to the Scrubber.

  2. System to acquire and monitor operating machinery positions for horizontal coke oven batteries

    SciTech Connect (OSTI)

    Bierbaum, D.; Teschner, W.

    1980-02-26

    In a horizontal coke oven battery with at least one coke receiving device movable along one longitudinal side of the battery and at least one coke driving device movable along an opposite longitudinal side of the battery, an apparatus is disclosed for determining the relative position of the coke receiving device with respect to the coke driving device and for activating the coke driving device when its position corresponds with that of the coke receiving device. A first wheel is mounted on the coke receiving device for rotation with the movement of the coke receiving device, a first angle encoder is connected to the first wheel for producing a first signal corresponding to the location of the first wheel and the position of the coke receiving device along the coke oven, and an input storage in the form of a magnetic disc is connected to the first angle encoder for recording and storing the signal. A second wheel is mounted on the coke driving device for rotation with the movement of the coke driving device and a second angle encoder is connected thereto for producing a second signal which corresponds to the rotation of the second wheel and the position of the coke driving device along the coke oven. A comparator is connected to the second signal encoder for receiving the second signal and a data link is provided between the comparator and the input storage of the coke receiving device so that the first signal from the coke receiving device can be impressed on the comparator. An activator is connected to the comparator for activating the coke driving device when the first signal corresponds to the second signal indicating a corresponding positional relationship between the coke receiving device and the coke driving device.

  3. Table 21. U.S. Coke Imports

    U.S. Energy Information Administration (EIA) Indexed Site

    1. U.S. Coke Imports (short tons) Year to Date Continent and Country of Origin January - March 2016 October - December 2015 January - March 2015 2016 2015 Percent Change North America Total 2,763 52,115 2,035 2,763 2,035 35.8 Canada 2,763 52,115 2,035 2,763 2,035 35.8 Europe Total 1,056 1,156 14 1,056 14 NM Austria - 3 - - - - France - 23 - - - - Germany, Federal Republic of - - 11 - 11 - Italy 1,043 976 - 1,043 - - Spain - 141 - - - - United Kingdom 13 13 3 13 3 333.3 Asia Total 457 326 954 457

  4. New process to avoid emissions: Constant pressure in coke ovens

    SciTech Connect (OSTI)

    Giertz, J.; Huhn, F.; Hofherr, K.

    1995-12-01

    A chamber pressure regulation (PROven), especially effective in regard to emission control problems of coke ovens is introduced for the first time. Because of the partial vacuum in the collecting main system, it is possible to keep the oven`s raw gas pressure constant on a low level over the full coking time. The individual pressure control for each chamber is assured directly as a function of the oven pressure by an immersion system controlling the flow resistance of the collecting main valve. The latter is a fixed-position design (system name ``FixCup``). By doing away with the interdependence of collecting main pressure and chamber pressure, a parameter seen as a coking constant could not be made variable. This opens a new way to reduce coke oven emissions and simultaneously to prevent the ovens from damage caused by air ingress into the oven.

  5. The evaluation of the Nippon Steel Corporation reactivity and post-reaction-strength test for coke

    SciTech Connect (OSTI)

    Not Available

    1980-12-01

    A systematic investigation was made of the factors influencing the reactivity of coke, including test temperature, coke structural properties, mineral inclusions and additives, and the inert content of the charge.

  6. Table 7.8 Coke Overview, 1949-2011 (Thousand Short Tons)

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Sources: * 1949-1975Bureau of Mines, Minerals Yearbook, "Coke and Coal Chemicals" chapter. * 1976-1980U.S. Energy Information Administration (EIA), Energy Data Report, Coke and ...

  7. New packing in absorption systems for trapping benzene from coke-oven gas

    SciTech Connect (OSTI)

    V.V. Grabko; V.M. Li; T.A. Shevchenko; M.A. Solov'ev

    2009-07-15

    The efficiency of benzene removal from coke-oven gas in absorption units OAO Alchevskkoks with new packing is assessed.

  8. Study on rheological characteristics of petroleum coke residual oil slurry

    SciTech Connect (OSTI)

    Shou Weiyi; Xu Xiaoming; Cao Xinyu

    1997-07-01

    We have embarked on a program to develop petroleum coke residual oil slurry (POS) as an alternative fuel for existing oil-fired boilers. The industrial application of petroleum coke residual oil slurry requires full knowledge of its flow behavior. This paper will present the results of an experimental investigation undertaken to study the Theological properties using a rotating viscometer at shear rate up to 996 s{sup -1}. The effects of temperature, concentration, particle size distribution and additives are also investigated. The experiments show that petroleum coke residual oil slurry exhibits pseudoplastic behavior, which has favorable viscosity property under a certain condition and has broad prospect to be applied on oil-fired boilers.

  9. Problems of organizing zero-effluent production in coking plants

    SciTech Connect (OSTI)

    Maiskii, S.V.; Kagasov, V.M.

    1981-01-01

    The basic method of protecting the environment against pollution by coking plants in the future must be the organization of zero-waste production cycles. Problems associated with the elimination of effluent are considered. In the majority of plants at present, the phenolic effluent formed during coal carbonization and chemical product processing is completely utilized within the plant as a coke quenching medium (the average rate of phenolic effluent formation is 0.4 m/sup 3//ton of dry charge, which equals the irrecoverable water losses in coke quenching operations). However, the increasing adoption of dry coke cooling is inevitably associated with increasing volumes of surplus effluent which cannot be disposed of in coke quenching towers. As a result of experiments it was concluded that: 1. The utilization of phenolic effluent in closed-cycle watercooling systems does not entirely solve the effluent disposal problem. The volume of surplus effluent depends on the volume originally formed, the rate of consuming water in circulation and the time of year. In order to dispose of surplus effluent, wet quenching must be retained for a proportion of the coke produced. 2. The greatest hazards in utilizing phenolic effluent in closed-cycle watercooling systems are corrosion and the build-up of suspended solids. The water must be filtered and biochemically purified before it is fed into the closed-cycle watercooling systems. The total ammonia content after purification should not exceed 100 to 150 mg/l. 3. Stormwater and thawed snow can be used in closed-cycle water supply systems after purification. 4. The realization of zero-effluent conditions in existing plants will require modifications to the existing water supply systems.

  10. Metalworking and machining fluids

    DOE Patents [OSTI]

    Erdemir, Ali; Sykora, Frank; Dorbeck, Mark

    2010-10-12

    Improved boron-based metal working and machining fluids. Boric acid and boron-based additives that, when mixed with certain carrier fluids, such as water, cellulose and/or cellulose derivatives, polyhydric alcohol, polyalkylene glycol, polyvinyl alcohol, starch, dextrin, in solid and/or solvated forms result in improved metalworking and machining of metallic work pieces. Fluids manufactured with boric acid or boron-based additives effectively reduce friction, prevent galling and severe wear problems on cutting and forming tools.

  11. Table 38. Coal Stocks at Coke Plants by Census Division

    Gasoline and Diesel Fuel Update (EIA)

    Coal Stocks at Coke Plants by Census Division (thousand short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2014 Table 38. Coal Stocks at Coke Plants by Census Division (thousand short tons) U.S. Energy Information Administration | Quarterly Coal Report, April - June 2014 Census Division June 30, 2014 March 31, 2014 June 30, 2013 Percent Change (June 30) 2014 versus 2013 Middle Atlantic 547 544 857 -36.2 East North Central 1,130 963 1,313 -13.9 South

  12. A coke oven model including thermal decomposition kinetics of tar

    SciTech Connect (OSTI)

    Munekane, Fuminori; Yamaguchi, Yukio; Tanioka, Seiichi

    1997-12-31

    A new one-dimensional coke oven model has been developed for simulating the amount and the characteristics of by-products such as tar and gas as well as coke. This model consists of both heat transfer and chemical kinetics including thermal decomposition of coal and tar. The chemical kinetics constants are obtained by estimation based on the results of experiments conducted to investigate the thermal decomposition of both coal and tar. The calculation results using the new model are in good agreement with experimental ones.

  13. Formation of coke from heavy crude oils in the presence of calcium carbonate

    SciTech Connect (OSTI)

    Kessick, M. A.; George, Z. M.; Schneider, L. G.

    1985-06-04

    The sulphur emissive capability, on combustion, of coke which is formed during upgrading of sulphur-containing heavy crude oils, including oil sands bitumen, and residua, is decreased by the addition of calcium carbonate, preferably in the form of limestone, to the heavy crude oil prior to coking. The presence of the limestone leads to an increased yield of liquid distillates from the coking process under preferred coking conditions. Ash remaining after combustion of the coke may be leached to recover nickel and vanadium values therefrom.

  14. Process for converting coal into liquid fuel and metallurgical coke

    DOE Patents [OSTI]

    Wolfe, Richard A.; Im, Chang J.; Wright, Robert E.

    1994-01-01

    A method of recovering coal liquids and producing metallurgical coke utilizes low ash, low sulfur coal as a parent for a coal char formed by pyrolysis with a volatile content of less than 8%. The char is briquetted and heated in an inert gas over a prescribed heat history to yield a high strength briquette with less than 2% volatile content.

  15. Use of a scale model for coke oven charging practice development

    SciTech Connect (OSTI)

    Case, E.R.; Pendergras, S.T.

    1982-01-01

    A 1/8 scale model coke oven was designed and built for use as a tool to improve coke oven charging practice. Major goals of the program were to increase coke oven productivity and decrease charging emissions. The material used to simulate coal in the model was chosen on the basis of angle of repose. the proper choice of media to simulate the coke oven charge, under a given set of operating conditions, was essential to obtain correspondence between the model and the production oven. Oven profiles were very similar after individual larry car hoppers were dropped and after leveling. Improved coke oven charging practices developed with the coke oven model, in combination with close control by operating personnel, have resulted in increased coke oven charge weights of over 1.0 ton/oven without increased charging emissions.

  16. Integrated coke, asphalt and jet fuel production process and apparatus

    DOE Patents [OSTI]

    Shang, Jer Y.

    1991-01-01

    A process and apparatus for the production of coke, asphalt and jet fuel m a feed of fossil fuels containing volatile carbon compounds therein is disclosed. The process includes the steps of pyrolyzing the feed in an entrained bed pyrolyzing means, separating the volatile pyrolysis products from the solid pyrolysis products removing at least one coke from the solid pyrolysis products, fractionating the volatile pyrolysis products to produce an overhead stream and a bottom stream which is useful as asphalt for road pavement, condensing the overhead stream to produce a condensed liquid fraction and a noncondensable, gaseous fraction, and removing water from the condensed liquid fraction to produce a jet fuel-containing product. The disclosed apparatus is useful for practicing the foregoing process. the process provides a useful method of mass producing and jet fuels from materials such as coal, oil shale and tar sands.

  17. An overview of crisis management in the coke industry

    SciTech Connect (OSTI)

    Saunders, D.A.

    1995-12-01

    Members of the American Coke and Coal Chemicals Institute (ACCCI), as responsible corporate citizens, have embraced the concepts of crisis management and progress down the various paths of planning and preparation, monitoring, media communications, community outreach, emergency response, and recovery. Many of the concepts outlined here reflect elements of crisis management guidelines developed by the Chemical Manufacturers Association (CMA). At a coke plant, crises can take the form of fires, chemical releases, labor strikes, feedstock supply disruptions, and excessive snowfall, just to name a few. The CMA defines a crisis as: ``an unplanned event that has the potential to significantly impact a company`s operability or credibility, or to pose a significant environment, economic or legal liability``; and crisis management as: ``those activities undertaken to anticipate or prevent, prepare for, respond to and recover from any incident that has the potential to greatly affect the way a company conducts its business.

  18. Development of advanced technology of coke oven gas drainage treatment

    SciTech Connect (OSTI)

    Higashi, Tadayuki; Yamaguchi, Akikazu; Ikai, Kyozou; Kamiyama, Hisarou; Muto, Hiroshi

    1996-12-31

    In April 1994, commercial-scale application of ozone oxidation to ammonia liquor (which is primarily the water condensing from coke oven gas) to reduce its chemical oxygen demand (COD) was started at the Nagoya Works of Nippon Steel Corporation. This paper deals with the results of technical studies on the optimization of process operating conditions and the enlargement of equipment size and the operating purification system.

  19. Low-coke rate operation under high PCI at Kobe No. 3 BF

    SciTech Connect (OSTI)

    Matsuo, Tadasu; Kanazuka, Yasuo; Hoshino, Koichi; Yoshida, Yasuo; Kitayama, Syuji; Ishiwaki, Shiro

    1997-12-31

    Kobe No. 3 blast furnace (BF) suffered tremendous damage when the Great Hanshin-Awaji Earthquake rocked the area on January 17, 1995. However, working as quickly as possible to dig out of the burden and rehabilitate various facilities, the company managed to restart the No. 3 BF on April 2. After the restart, which went smoothly, production was shifted into the low coke rate operation which was being promoted before the disaster. In October, 1995, only seven months after the restart, the nation record of 296 kg/t low coke rate could be achieved. Subsequently, in January, 1996, coke rate reached 290 kg/t and the low coke rate operation was renewed. Since that time the same level of coke rate has been maintained. The paper discusses how low coke rate operation was achieved.

  20. How to implement a quality program in a coking plant. The AHMSA experience

    SciTech Connect (OSTI)

    Reyes M, M.A.; Perez, J.L.; Garza, C. de la; Morales, M.

    1995-12-01

    AHMSA (Altos Hornos de Mexico) is the largest integrated Steel Plant in Mexico, with its 3.1 MMMT of Liquid Steel production program for 1995. AHMSA operates two coke plants which began operations in 1955 and 1976. Total coke monthly production capacity amounts to as much as 106,000 Metric Tons (MT). The coke plants working philosophy was discussed and established in 1986 as part of the Quality Improvement Program, where its ultimate goal is to give the best possible coke quality to its main client--the blast furnaces. With this goal in mind, a planned joint effort with their own coal mines was initiated. This paper deals with the implementation process of the Quality Program, and the results of this commitment at the coal mines, coke plants and blast furnaces. The coke quality improvement is shown since 1985 to 1994, as well as the impact on the blast furnace operation.

  1. On the utilization of coking plant surface runoff

    SciTech Connect (OSTI)

    Evzel'man, I.B.; Kagasov, V.M.; Maiskii, S.V.; Pimenov, I.V.; Rod'kin, S.P.; Ushakov, E.B.

    1983-01-01

    Surface runoff from the industrial sites of coking plants in the East and Center of the USSR is usually diverted into a storm sewer in a mixture with the conditionally pure water. General data on the contamination of this mixture (industrial stormwater) and the snow cover at a number of coking plants in this region are tabulated. Our data on the quality of industrial stormwater show that schemes for utilization of surface runoff must include pretreatment to remove suspended matter and oils. For example, the oil concentration in melt water is 2-10 times greater than the concentration in industrial phenol-containing effluent (2). When the biochemical facilities receive surface runoff containing up to 40 g/l suspended solids, which occurs in periods of snowmelt, without treatment to remove these solids, there are difficulties with the discharge of tar from the secondary sedimenters of the biochemical treatment plant. An analysis of the literature materials (3-9) showed that the maximum allowable concentration of suspended solids in make-up water for the closed-cycle heat exchange water cooling system should apparently not exceed 25 mg/l. The level of this parameter in the make-up water of these systems at coke plants requires correction.

  2. The new Kaiserstuhl coking plant: The heating system -- Design, construction and initial operating experience

    SciTech Connect (OSTI)

    Strunk, J.

    1996-12-31

    At the end of 1992 the new coke plant Kaiserstuhl in Dortmund/Germany with presently the largest coke ovens world-wide started its production operation in close linkage to the Krupp-Hoesch Metallurgical Works after about 35 months construction time. This plant incorporating comprehensive equipment geared to improve environmental protection is also considered as the most modern coke plant of the world. The heating-system and first results of operation will be presented.

  3. Heating control methodology in coke oven battery at Rourkela Steel Plant

    SciTech Connect (OSTI)

    Bandyopadhyay, S.S.; Parthasarathy, L.; Gupta, A.; Bose, P.R.; Mishra, U.

    1996-12-31

    A methodology of heating control was evolved incorporating temperature data generated through infra-red sensor at quenching station and thermocouples specially installed in the gooseneck of coke oven battery No. 3 of RSP. Average temperature of the red-hot coke as pushed helps in diagnosis of the abnormal ovens and in setting the targeted battery temperature. A concept of coke readiness factor (Q) was introduced which on optimization resulted in lowering the specific heat consumption by 30 KCal/Kg.

  4. Operational improvements at Jewell Coal and Coke Company`s non-recovery ovens

    SciTech Connect (OSTI)

    Ellis, C.E.; Pruitt, C.W.

    1995-12-01

    Operational improvements at Jewell Coal and Coke Company over the past five years includes safety and environmental concerns, product quality, equipment availability, manpower utilization, and productivity. These improvements with Jewell`s unique process has allowed Jewell Coal and Coke Company to be a consistent, high quality coke producer. The paper briefly explains Jewell`s unique ovens, their operating mode, improved process control, their maintenance management program, and their increase in productivity.

  5. Using Coke Oven Gas in a Blast Furnace Saves Over $6 Million Annually at a Steel Mill (U.S. Steel Edgar Thompson Plant)

    SciTech Connect (OSTI)

    2000-12-01

    Like most steel companies, U.S. Steel (USS) had been using coke oven gas (COG), a by-product of coke manufacturing, as a fuel in their coke ovens, boilers, and reheat furnaces.

  6. Resonant excitation of coupled Rayleigh waves in a short and narrow fluid channel clad between two identical metal plates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    García-Chocano, Victor M.; López-Rios, Tomás; Krokhin, Arkadii; Sanchez-Dehesa, Jose

    2011-12-23

    Transmission of ultrasonic waves through a slit between two water immersed brass plates is studied for sub-wavelength plate thicknesses and slit apertures. Extraordinary high absorption is observed at discrete frequencies corresponding to resonant excitation of Rayleigh waves on the both sides of the channel. The coupling of the Rayleigh waves occurs through the fluid and the corresponding contribution to the dispersion has been theoretically derived and also experimentally confirmed. Symmetric and anti-symmetric modes are predicted but only the symmetric mode resonances have been observed. It follows from the dispersion equation that the coupled Rayleigh waves cannot be excited in amore » channel with apertures less than the critical one. The calculated critical aperture is in a good agreement with the measured acoustic spectra. These findings could be applied to design a broadband absorptive metamaterial.« less

  7. Mechanistic insights of ethanol steam reforming over Ni-CeOx(111): The importance of hydroxyl groups for suppressing coke formation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Zongyuan; Senanayake, Sanjaya D.; Duchon, Tomas; Wang, Huanru; Peterson, Erik W.; Zhou, Yinghui; Luo, Si; Zhou, Jing; Matolin, Vladimir; Stacchiola, Dario J.; et al

    2015-07-10

    We have studied the reaction of ethanol and water over NiCeO2-x(111) model surfaces to elucidate the mechanistic steps associated with the ethanol steam reforming (ESR) reaction. Our results provide insights about the importance of hydroxyl groups to the ESR reaction over Ni-based catalysts. Systematically, we have investigated the reaction of ethanol on NiCeO2-x(111) at varying Ce? concentrations (CeO1.82.0) with absence/presence of water using a combination of soft X-ray photoelectron spectroscopy (sXPS) and temperature-programmed desorption (TPD). Consistent with previous reports, upon annealing, metallic Ni formed on reduced ceria while NiO was the main component on fully oxidized ceria. Ni? is themoreactive phase leading to both the CC and CH cleavage of ethanol but is also responsible for carbon accumulation or coking. We have identified a Ni?C phase that formed prior to the formation of coke. At temperatures above 600K, the lattice oxygen from ceria and the hydroxyl groups from water interact cooperatively in the removal of coke, likely through a strong metalsupport interaction between nickel and ceria that facilitates oxygen transfer.less

  8. Fluid extraction

    DOE Patents [OSTI]

    Wai, Chien M.; Laintz, Kenneth E.

    1999-01-01

    A method of extracting metalloid and metal species from a solid or liquid material by exposing the material to a supercritical fluid solvent containing a chelating agent is described. The chelating agent forms chelates that are soluble in the supercritical fluid to allow removal of the species from the material. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is a fluorinated .beta.-diketone. In especially preferred embodiments the extraction solvent is supercritical carbon dioxide, and the chelating agent comprises a fluorinated .beta.-diketone and a trialkyl phosphate, or a fluorinated .beta.-diketone and a trialkylphosphine oxide. Although a trialkyl phosphate can extract lanthanides and actinides from acidic solutions, a binary mixture comprising a fluorinated .beta.-diketone and a trialkyl phosphate or a trialkylphosphine oxide tends to enhance the extraction efficiencies for actinides and lanthanides. The method provides an environmentally benign process for removing contaminants from industrial waste without using acids or biologically harmful solvents. The method is particularly useful for extracting actinides and lanthanides from acidic solutions. The chelate and supercritical fluid can be regenerated, and the contaminant species recovered, to provide an economic, efficient process.

  9. Fluid pumping apparatus

    DOE Patents [OSTI]

    West, Phillip B.

    2006-01-17

    A method and apparatus suitable for coupling seismic or other downhole sensors to a borehole wall in high temperature and pressure environments. In one embodiment, one or more metal bellows mounted to a sensor module are inflated to clamp the sensor module within the borehole and couple an associated seismic sensor to a borehole wall. Once the sensing operation is complete, the bellows are deflated and the sensor module is unclamped by deflation of the metal bellows. In a further embodiment, a magnetic drive pump in a pump module is used to supply fluid pressure for inflating the metal bellows using borehole fluid or fluid from a reservoir. The pump includes a magnetic drive motor configured with a rotor assembly to be exposed to borehole fluid pressure including a rotatable armature for driving an impeller and an associated coil under control of electronics isolated from borehole pressure.

  10. Use of selective oxidation of petroleum residue for production of low-sulfur coke

    SciTech Connect (OSTI)

    Hairudinov, I.R.; Kul`chitskaya, O.V.; Imashev, U.B.

    1995-12-10

    The chemical nature of liquid-phase oxidation of sulfurous petroleum residues by cumene hydroperoxide was studied by a tracer technique. Sulfur compounds are selectively oxidized in the presence of catalytic additives of molybdenum salts. Desulfurization of distillate products and coke during coking of preoxidized raw materials was revealed.

  11. Teamwork in planning and carrying out the first inspection of the coke dry quenching (CDQ) plant of the Kaiserstuhl Coking Facility

    SciTech Connect (OSTI)

    Burchardt, G.

    1996-12-31

    The coke plant Kaiserstuhl operates a coke dry quenching (CDQ) plant with a downstream installed waste heat boiler to satisfy statutory pollution control rules and requirements. This CDQ which went on stream in March 1993 cools the whole coke production output from the Kaiserstuhl coke plant in counterflow to an inert cooling gas. This brief overview on the whole CDQ plant should elucidate the complex of problems posed when trying to make an exact plant revision plan. After all it was impossible to evaluate or to assess all the interior process technology relevant components during the planning stage as the plant was in operation. The revision data for the first interior check was determined and fixed by the statutory rule for steam boilers and pressure vessels. The relevant terms for this check are mandatorily prescribed. In liaison with the testing agency (RW TUEV) the date for the first revision was fixed for April 1995, that means two years after the first commissioning.

  12. Mechanistic Insights of Ethanol Steam Reforming over Ni–CeO x (111): The Importance of Hydroxyl Groups for Suppressing Coke Formation

    SciTech Connect (OSTI)

    Liu, Zongyuan; Duchoň, Tomáš; Wang, Huanru; Peterson, Erik W.; Zhou, Yinghui; Luo, Si; Zhou, Jing; Matolín, Vladimir; Stacchiola, Dario J.; Rodriguez, José A.; Senanayake, Sanjaya D.

    2015-07-30

    We have studied the reaction of ethanol and water over Ni–CeO2-x(111) model surfaces to elucidate the mechanistic steps associated with the ethanol steam reforming (ESR) reaction. Our results provide insights about the importance of hydroxyl groups to the ESR reaction over Ni-based catalysts. Systematically, we have investigated the reaction of ethanol on Ni–CeO2-x(111) at varying Ce³⁺ concentrations (CeO1.8–2.0) with absence/presence of water using a combination of soft X-ray photoelectron spectroscopy (sXPS) and temperature-programmed desorption (TPD). Consistent with previous reports, upon annealing, metallic Ni formed on reduced ceria while NiO was the main component on fully oxidized ceria. Ni⁰ is the active phase leading to both the C–C and C–H cleavage of ethanol but is also responsible for carbon accumulation or coking. We have identified a Ni₃C phase that formed prior to the formation of coke. At temperatures above 600K, the lattice oxygen from ceria and the hydroxyl groups from water interact cooperatively in the removal of coke, likely through a strong metal–support interaction between nickel and ceria that facilitates oxygen transfer.

  13. Mechanistic Insights of Ethanol Steam Reforming over Ni–CeO x (111): The Importance of Hydroxyl Groups for Suppressing Coke Formation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Zongyuan; Duchoň, Tomáš; Wang, Huanru; Peterson, Erik W.; Zhou, Yinghui; Luo, Si; Zhou, Jing; Matolín, Vladimir; Stacchiola, Dario J.; Rodriguez, José A.; et al

    2015-07-30

    We have studied the reaction of ethanol and water over Ni–CeO2-x(111) model surfaces to elucidate the mechanistic steps associated with the ethanol steam reforming (ESR) reaction. Our results provide insights about the importance of hydroxyl groups to the ESR reaction over Ni-based catalysts. Systematically, we have investigated the reaction of ethanol on Ni–CeO2-x(111) at varying Ce³⁺ concentrations (CeO1.8–2.0) with absence/presence of water using a combination of soft X-ray photoelectron spectroscopy (sXPS) and temperature-programmed desorption (TPD). Consistent with previous reports, upon annealing, metallic Ni formed on reduced ceria while NiO was the main component on fully oxidized ceria. Ni⁰ is themore » active phase leading to both the C–C and C–H cleavage of ethanol but is also responsible for carbon accumulation or coking. We have identified a Ni₃C phase that formed prior to the formation of coke. At temperatures above 600K, the lattice oxygen from ceria and the hydroxyl groups from water interact cooperatively in the removal of coke, likely through a strong metal–support interaction between nickel and ceria that facilitates oxygen transfer.« less

  14. Ammonia removal process upgrade to the Acme Steel Coke Plant

    SciTech Connect (OSTI)

    Harris, J.L.

    1995-12-01

    The need to upgrade the ammonia removal process at the Acme Steel Coke Plant developed with the installation of the benzene NESHAP (National Emission Standard for Hazardous Air Pollutants) equipment, specifically the replacement of the final cooler. At Acme Steel it was decided to replace the existing open cooling tower type final cooler with a closed loop direct spray tar/water final cooler. This new cooler has greatly reduced the emissions of benzene, ammonia, hydrogen sulfide and hydrogen cyanide to the atmosphere, bringing them into environmental compliance. At the time of its installation it was not fully recognized as to the effect this would have on the coke oven gas composition. In the late seventies the decision had been made at Acme Steel to stop the production of ammonia sulfate salt crystals. The direction chosen was to make a liquid ammonia sulfate solution. This product was used as a pickle liquor at first and then as a liquid fertilizer as more markets were developed. In the fall of 1986 the ammonia still was brought on line. The vapors generated from the operation of the stripping still are directed to the inlet of the ammonia absorber. At that point in time it was decided that an improvement to the cyclical ammonia removal process was needed. The improvements made were minimal yet allowed the circulation of solution through the ammonia absorber on a continuous basis. The paper describes the original batch process and the modifications made which allowed continuous removal.

  15. Laser ultrasonic furnace tube coke monitor. Quarterly technical progress report No. 1, May 1--August 1, 1998

    SciTech Connect (OSTI)

    1998-08-15

    The overall aim of the project is to demonstrate the performance and practical use of a laser ultrasonic probe for measuring the thickness of coke deposits located within the high temperature tubes of a thermal cracking furnace. This aim will be met by constructing an optical probe that will be tested using simulated coke deposits that are positioned inside of a bench-scale furnace. Successful development of the optical coke detector will provide industry with the only available method for on-line measurement of coke deposits. The optical coke detector will have numerous uses in the refining and petrochemical sectors including monitoring of visbreakers, hydrotreaters, delayed coking units, vacuum tower heaters, and various other heavy oil heating applications where coke formation is a problem. The coke detector will particularly benefit the olefins industry where high temperature thermal crackers are used to produce ethylene, propylene, butylene and other important olefin intermediates. The ethylene industry requires development of an on-line method for gauging the thickness of coke deposits in cracking furnaces because the current lack of detailed knowledge of coke deposition profiles introduces the single greatest uncertainty in the simulation and control of modern cracking furnaces. The laser ultrasonic coke detector will provide operators with valuable new information allowing them to better optimize the decoking turnaround schedule and therefore maximize production capacity.

  16. Development of automatic operation system for coke oven machines at Yawata Works of Nippon Steel Corporation

    SciTech Connect (OSTI)

    Matsunaga, Masao; Uematsu, Hiroshi; Nakagawa, Yoji; Ishiharaguchi, Yuji

    1995-12-01

    The coke plant is a working environment involving heavy dust emissions, high heat and demanding physical labor. The labor-saving operation of the coke plant is an essential issue from the standpoints of not only improvement in working environment, but also reduction in fixed cost by enhancement of labor productivity. Under these circumstances, Nippon Steel has implemented the automation of coke oven machines. The first automatic operation system for coke oven machinery entered service at Oita Works in 1992, followed by the second system at the No. 5 coke oven battery of the coke plant at Yawata Works. The Yawata automatic operation system is characterized by the installation of coke oven machinery to push as many as 140 ovens per day within a short cycle time, such as a preliminary ascension pipe cap opening car and cycle time simulator by the manned operation of the pusher, which is advantageous from the standpoint of investment efficiency, and by the monitoring of other oven machines by the pusher. These measures helped to reduce the manpower requirement to 2 persons per shift from 4 persons per shift. The system entered commercial operation in March, 1994 and has been smoothly working with an average total automatic rate of 97%. Results from the startup to recent operation of the system are reported below.

  17. Gas treatment and by-products recovery of Thailand`s first coke plant

    SciTech Connect (OSTI)

    Diemer, P.E.; Seyfferth, W.

    1997-12-31

    Coke is needed in the blast furnace as the main fuel and chemical reactant and the main product of a coke plant. The second main product of the coke plant is coke oven gas. During treatment of the coke oven gas some coal chemicals like tar, ammonia, sulphur and benzole can be recovered as by-products. Since the market prices for these by-products are rather low and often erratic it does not in most cases justify the investment to recover these products. This is the reason why modern gas treatment plants only remove those impurities from the crude gas which must be removed for technical and environmental reasons. The cleaned gas, however, is a very valuable product as it replaces natural gas in steel work furnaces and can be used by other consumers. The surplus can be combusted in the boiler of a power plant. A good example for an optimal plant layout is the new coke oven facility of Thai Special Steel Industry (TSSI) in Rayong. The paper describes the TSSI`s coke oven gas treatment plant.

  18. Extracting metals directly from metal oxides

    DOE Patents [OSTI]

    Wai, C.M.; Smart, N.G.; Phelps, C.

    1997-02-25

    A method of extracting metals directly from metal oxides by exposing the oxide to a supercritical fluid solvent containing a chelating agent is described. Preferably, the metal is an actinide or a lanthanide. More preferably, the metal is uranium, thorium or plutonium. The chelating agent forms chelates that are soluble in the supercritical fluid, thereby allowing direct removal of the metal from the metal oxide. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of {beta}-diketones, halogenated {beta}-diketones, phosphinic acids, halogenated phosphinic acids, carboxylic acids, halogenated carboxylic acids, and mixtures thereof. In especially preferred embodiments, at least one of the chelating agents is fluorinated. The method provides an environmentally benign process for removing metals from metal oxides without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the metal recovered, to provide an economic, efficient process. 4 figs.

  19. Extracting metals directly from metal oxides

    DOE Patents [OSTI]

    Wai, Chien M.; Smart, Neil G.; Phelps, Cindy

    1997-01-01

    A method of extracting metals directly from metal oxides by exposing the oxide to a supercritical fluid solvent containing a chelating agent is described. Preferably, the metal is an actinide or a lanthanide. More preferably, the metal is uranium, thorium or plutonium. The chelating agent forms chelates that are soluble in the supercritical fluid, thereby allowing direct removal of the metal from the metal oxide. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of .beta.-diketones, halogenated .beta.-diketones, phosphinic acids, halogenated phosphinic acids, carboxylic acids, halogenated carboxylic acids, and mixtures thereof. In especially preferred embodiments, at least one of the chelating agents is fluorinated. The method provides an environmentally benign process for removing metals from metal oxides without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the metal recovered, to provide an economic, efficient process.

  20. Glass-coating and cleaning system to prevent carbon deposition on coke oven walls

    SciTech Connect (OSTI)

    Takahira, Takuya; Ando, Takeshi; Kasaoka, Shizuki; Yamauchi, Yutaka

    1997-12-31

    The new technology for protecting the coking chamber bricks from damage by hard-pushing is described. The technology consists of the glass coating on the wall bricks and a wall cleaner to blow deposited carbon. For the glass coating, a specially developed glaze is sprayed onto the wall bricks by a spraying device developed to completely spray one coking chamber in a few minutes. The wall cleaner is installed on a pusher ram in the facility to automatically blow air at a sonic speed during coke pushing. The life of the glazed layer is estimated to be over two years.

  1. Role of hydrogen in blast furnaces to improve productivity and decrease coke consumption

    SciTech Connect (OSTI)

    Agarwal, J.C.; Brown, F.C.; Chin, D.L.; Stevens, G.; Clark, R.; Smith, D.

    1995-12-01

    The hydrogen contained in blast furnace gases exerts a variety of physical, thermochemical, and kinetic effects as the gases pass through the various zones. The hydrogen is derived from two sources: (1) the dissociation of moisture in the blast air (ambient and injected with hot blast), and (2) the release from partial combustion of supplemental fuels (including moisture in atomizing water, steam, or transport air, if any). With each atom of oxygen (or carbon), the molar amounts of hydrogen released are more than six times higher for natural gas than for coal, and two times higher for natural gas than for oil. Injection of natural gas in a blast furnace is not a new process. Small amounts of natural gas--about 50--80 lb or 1,100--1,700 SCF/ton of hot metal--have been injected in many of the North American blast furnaces since the early 1960s, with excellent operating results. What is new, however, is a batter understanding of how natural gas reacts in the blast furnace and how natural gas and appropriate quantities of oxygen can be used to increase the driving rate or combustion rate of carbon (coke) in the blast furnace without causing hanging furnace and operating problems. The paper discusses the factors limiting blast furnace productivity and how H{sub 2} and O{sub 2} can increase productivity.

  2. Table 22. Average Price of U.S. Coke Imports

    U.S. Energy Information Administration (EIA) Indexed Site

    2. Average Price of U.S. Coke Imports (dollars per short ton) Year to Date Continent and Country of Origin January - March 2016 October - December 2015 January - March 2015 2016 2015 Percent Change North America Total 181.85 113.11 213.82 181.85 213.82 -15.0 Canada 181.85 113.11 213.82 181.85 213.82 -15.0 Europe Total 270.94 416.80 770.50 270.94 770.50 -64.8 Austria - 1,788.00 - - - - France - 1,110.35 - - - - Germany, Federal Republic of - - 206.27 - 206.27 - Italy 265.37 300.11 - 265.37 - -

  3. Multiphase fluid characterization system

    DOE Patents [OSTI]

    Sinha, Dipen N.

    2014-09-02

    A measurement system and method for permitting multiple independent measurements of several physical parameters of multiphase fluids flowing through pipes are described. Multiple acoustic transducers are placed in acoustic communication with or attached to the outside surface of a section of existing spool (metal pipe), typically less than 3 feet in length, for noninvasive measurements. Sound speed, sound attenuation, fluid density, fluid flow, container wall resonance characteristics, and Doppler measurements for gas volume fraction may be measured simultaneously by the system. Temperature measurements are made using a temperature sensor for oil-cut correction.

  4. Supercritical fluid extraction

    DOE Patents [OSTI]

    Wai, Chien M.; Laintz, Kenneth

    1994-01-01

    A method of extracting metalloid and metal species from a solid or liquid material by exposing the material to a supercritical fluid solvent containing a chelating agent. The chelating agent forms chelates that are soluble in the supercritical fluid to allow removal of the species from the material. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is a fluorinated or lipophilic crown ether or fluorinated dithiocarbamate. The method provides an environmentally benign process for removing contaminants from industrial waste without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the contaminant species recovered, to provide an economic, efficient process.

  5. An investigation of the properties of pitch coke modified by chemically active additives

    SciTech Connect (OSTI)

    Kulakov, V.V.; Fedeneva, E.N.; Neproshin, E.I.

    1984-01-01

    The results of an investigation are presented of the influence of chemically active additives on the yield and properties of coke from hard-coal pitch. A comparison has been made of the efficacy of the influence of these additives.

  6. Fascinating Fluids

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fascinating Fluids Fascinating Fluids From liquids to gases, we take on this most fascinating compound with hands-on activities for children and adults alike. We are made of fluids, mostly water, arguably the most interesting compound in the universe. Think About This Liquids Fluids are amazing. Fluids flow. Liquids have variable shapes but almost constant volumes. Gases Gases take the shape of their containers and can be squeezed and stretched relatively easily. Sand What is fine sand? It is a

  7. Cryogenic fractionator gas as stripping gas of fines slurry in a coking and gasification process

    DOE Patents [OSTI]

    DeGeorge, Charles W.

    1981-01-01

    In an integrated coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a scrubbing process and wherein the resulting solids-liquid slurry is stripped with a stripping gas to remove acidic gases, at least a portion of the stripping gas comprises a gas comprising hydrogen, nitrogen and methane separated from the coker products.

  8. The Videofil probe, a novel instrument to extend the coke oven service life

    SciTech Connect (OSTI)

    Gaillet, J.P.; Isler, D.

    1997-12-31

    To prolong the service life of coke oven batteries, the Centre de Pyrolyse de Marienau developed the Videofil probe, a novel instrument to conduct diagnoses and to help repair operations of coke ovens. The Videofil probe is a flexible non-water-cooled endoscope which is used to locate flue wall damage and estimate its importance, to define the oven zones to repair and guide the repair work and to control the quality of the repair work and its durability.

  9. Development of an Advanced Combined Heat and Power (CHP) System Utilizing Off-Gas from Coke Calcination

    SciTech Connect (OSTI)

    2009-02-01

    This factsheet describes a research project whose goal is to reduce the energy and carbon intensity of the calcined coke production process.

  10. Application of process safety management to the coke industry

    SciTech Connect (OSTI)

    Mentzer, W.P. (USX Corp., Clairton, PA (United States))

    1994-09-01

    OSHA's Process Safety Management (PSM) standard went into effect on May 26, 1992. Explosions at various industrial facilities that claimed the lives of workers over the past several years were the catalyst for the new federal regulations. The new PSM standard deals with 130 specific chemicals along with flammable liquids and gases used at nearly 25,000 worksites. The performance-based PSM standard consists of 14 elements that establish goals and describe basic program elements to fulfill these goals. The PSM standard requires employers to conduct a process hazard analysis to examine potential problems and determine what preventative measures should be taken. Key elements include employee training, written operating procedures, safety reviews and maintenance requirements to insure the mechanical integrity of critical components. The presentation will cover the evolution of OSHA's PSM standard, the requirements of the 14 elements in the PSM standard and discuss the significant achievements in the development and implementation of the PSM process at US Steel's Clairton coke plant.

  11. Effect of coal and coke qualities on blast furnace injection and productivity at Taranto

    SciTech Connect (OSTI)

    Salvatore, E.; Calcagni, M.; Eichinger, F.; Rafi, M.

    1995-12-01

    Injection rates at Taranto blast furnaces Nos. 2 and 4, for more than 16 months, was maintained above 175 kg/thm. Monthly average injection rate for two months stabilized above 190 kg/thm. This performance was possible due to the very high combined availabilities of Taranto blast furnaces and the KST injection system. Based upon this experience the quantitative relationships between coke/coal and blast furnace operational parameters were studied and are shown graphically. During this period due to coke quality changes, injection rate had to be reduced. The effect of using coke breeze in coke/ferrous charge as well as coal blend was also evaluated. Permeability of the furnace was found to be directly affected by O{sub 2} enrichment level, while at a high PCI rate no correlation between actual change in coke quality and permeability could be established. The future of PCI technology lies in better understanding of relationships between material specifications and blast furnace parameters of which permeability is of prime importance.

  12. Automatic coke oven heating control system at Burns Harbor for normal and repair operation

    SciTech Connect (OSTI)

    Battle, E.T.; Chen, K.L.

    1997-12-31

    An automatic heating control system for coke oven batteries was developed in 1985 for the Burns Harbor No. 1 battery and reported in the 1989 Ironmaking Conference Proceedings. The original system was designed to maintain a target coke temperature at a given production level under normal operating conditions. Since 1989, enhancements have been made to this control system so that it can also control the battery heating when the battery is under repair. The new control system has improved heating control capability because it adjusts the heat input to the battery in response to anticipated changes in the production schedule. During a recent repair of this 82 oven battery, the pushing schedule changed from 102 ovens/day to 88 ovens/day, then back to 102 ovens/day, then to 107 ovens/day. During this repair, the control system was able to maintain the coke temperature average standard deviation at 44 F, with a maximum 75 F.

  13. Light oil yield improvement project at Granite City Division Coke/By-Product Plant

    SciTech Connect (OSTI)

    Holloran, R.A.

    1995-12-01

    Light oil removal from coke oven gas is a process that has long been proven and utilized throughout many North American Coke/By-Products Plants. The procedures, processes, and equipment requirements to maximize light oil recovery at the Granite City By-Products Plant will be discussed. The Light Oil Yield Improvement Project initially began in July, 1993 and was well into the final phase by February, 1994. Problem solving techniques, along with utilizing proven theoretical recovery standards were applied in this project. Process equipment improvements and implementation of Operator/Maintenance Standard Practices resulted in an average yield increase of 0.4 Gals./NTDC by the end of 1993.

  14. Process for producing fluid fuel from coal

    DOE Patents [OSTI]

    Hyde, Richard W.; Reber, Stephen A.; Schutte, August H.; Nadkarni, Ravindra M.

    1977-01-01

    Process for producing fluid fuel from coal. Moisture-free coal in particulate form is slurried with a hydrogen-donor solvent and the heated slurry is charged into a drum wherein the pressure is so regulated as to maintain a portion of the solvent in liquid form. During extraction of the hydrocarbons from the coal, additional solvent is added to agitate the drum mass and keep it up to temperature. Subsequently, the pressure is released to vaporize the solvent and at least a portion of the hydrocarbons extracted. The temperature of the mass in the drum is then raised under conditions required to crack the hydrocarbons in the drum and to produce, after subsequent stripping, a solid coke residue. The hydrocarbon products are removed and fractionated into several cuts, one of which is hydrotreated to form the required hydrogen-donor solvent while other fractions can be hydrotreated or hydrocracked to produce a synthetic crude product. The heaviest fraction can be used to produce ash-free coke especially adapted for hydrogen manufacture. The process can be made self-sufficient in hydrogen and furnishes as a by-product a solid carbonaceous material with a useful heating value.

  15. Who lives near coke plants and oil refineries An exploration of the environmental inequity hypothesis

    SciTech Connect (OSTI)

    Graham, J.D.; Beaulieu, N.D.; Sussman, D.; Sadowitz, M.; Li, Y.C. )

    1999-04-01

    Facility-specific information on pollution was obtained for 36 coke plants and 46 oil refineries in the US and matched with information on populations surrounding these 82 facilities. These data were analyzed to determine whether environmental inequities were present, whether they were more economic or racial in nature, and whether the racial composition of nearby communities has changed significantly since plants began operations. The Census tracts near coke plants have a disproportionate share of poor and nonwhite residents. Multivariate analyses suggest that existing inequities are primarily economic in nature. The findings for oil refineries are not strongly supportive of the environmental inequity hypothesis. Rank ordering of facilities by race, poverty, and pollution produces limited (although not consistent) evidence that the more risky facilities tend to be operating in communities with above-median proportions of nonwhite residents (near coke plants) and Hispanic residents (near oil refineries). Over time, the radical makeup of many communities near facilities has changed significantly, particularly in the case of coke plants sited in the early 1900s. Further risk-oriented studies of multiple manufacturing facilities in various industrial sectors of the economy are recommended.

  16. Innovative coke oven gas cleaning system for retrofit applications. Volume 1, Public design report

    SciTech Connect (OSTI)

    Not Available

    1994-05-24

    This Public Design Report provides, in a single document, available nonproprietary design -information for the ``Innovative Coke Oven Gas Cleaning System for Retrofit Applications`` Demonstration Project at Bethlehem Steel Corporation`s Sparrows Point, Maryland coke oven by-product facilities. This project demonstrates, for the first time in the United States, the feasibility of integrating four commercially available technologies (processes) for cleaning coke oven gas. The four technologies are: Secondary Gas Cooling, Hydrogen Sulfide and Ammonia Removal, Hydrogen Sulfide and Ammonia Recovery, and Ammonia Destruction and Sulfur Recovery. In addition to the design aspects, the history of the project and the role of the US Department of,Energy are briefly discussed. Actual plant capital and projected operating costs are also presented. An overview of the integration (retrofit) of the processes into the existing plant is presented and is followed by detailed non-proprietary descriptions of the four technologies and their overall effect on reducing the emissions of ammonia, sulfur, and other pollutants from coke oven gas. Narrative process descriptions, simplified process flow diagrams, input/output stream data, operating conditions, catalyst and chemical requirements, and utility requirements are given for each unit. Plant startup provisions, environmental considerations and control monitoring, and safety considerations are also addressed for each process.

  17. Coal flow aids reduce coke plant operating costs and improve production rates

    SciTech Connect (OSTI)

    Bedard, R.A.; Bradacs, D.J.; Kluck, R.W.; Roe, D.C.; Ventresca, B.P.

    2005-06-01

    Chemical coal flow aids can provide many benefits to coke plants, including improved production rates, reduced maintenance and lower cleaning costs. This article discusses the mechanisms by which coal flow aids function and analyzes several successful case histories. 2 refs., 10 figs., 1 tab.

  18. DOE MURI: Hig-Operating Temperature Heat Transfer Fluids for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Operating Temperature Liquid Metal Heat Transfer Fluids - FY13 Q2 High Operating Temperature Heat Transfer Fluids for Solar Thermal Power Generation FY13 Q1 Corrosion in Very ...

  19. Agglutination of single catalyst particles during fluid catalytic cracking as observed by X-ray nanotomography

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Meirer, F.; Kalirai, S.; Weker, J. Nelson; Liu, Y.; Andrews, J. C.; Weckhuysen, B. M.

    2015-04-14

    Metal accumulation at the catalyst particle surface plays a role in particle agglutination during fluid catalytic cracking.

  20. Torrefaction reduction of coke formation on catalysts used in esterification and cracking of biofuels from pyrolysed lignocellulosic feedstocks

    SciTech Connect (OSTI)

    Kastner, James R; Mani, Sudhagar; Hilten, Roger; Das, Keshav C

    2015-11-04

    A bio-oil production process involving torrefaction pretreatment, catalytic esterification, pyrolysis, and secondary catalytic processing significantly reduces yields of reactor char, catalyst coke, and catalyst tar relative to the best-case conditions using non-torrefied feedstock. The reduction in coke as a result of torrefaction was 28.5% relative to the respective control for slow pyrolysis bio-oil upgrading. In fast pyrolysis bio-oil processing, the greatest reduction in coke was 34.9%. Torrefaction at 275.degree. C. reduced levels of acid products including acetic acid and formic acid in the bio-oil, which reduced catalyst coking and increased catalyst effectiveness and aromatic hydrocarbon yields in the upgraded oils. The process of bio-oil generation further comprises a catalytic esterification of acids and aldehydes to generate such as ethyl levulinate from lignified biomass feedstock.

  1. Mineral Recovery from Geothermal Fluids | Open Energy Information

    Open Energy Info (EERE)

    Metals and Compounds from Geothermal Fluids California Simbol Mining Corp. Recovery Act: Enhanced Geothermal Systems Component Research and DevelopmentAnalysis Albuquerque, NM,...

  2. Reactive flash volatilization of fluid fuels

    DOE Patents [OSTI]

    Schmidt, Lanny D.; Dauenhauer, Paul J.; Dreyer, Bradon J.; Salge, James R.

    2013-01-08

    The invention provides methods for the production of synthesis gas. More particularly, various embodiments of the invention relate to systems and methods for volatilizing fluid fuel to produce synthesis gas by using a metal catalyst on a solid support matrix.

  3. Recycling of rubber tires in electric arc furnace steelmaking: simultaneous combustion of metallurgical coke and rubber tyres blends

    SciTech Connect (OSTI)

    Magdalena Zaharia; Veena Sahajwalla; Byong-Chul Kim; Rita Khanna; N. Saha-Chaudhury; Paul O'Kane; Jonathan Dicker; Catherine Skidmore; David Knights

    2009-05-15

    The present study investigates the effect of addition of waste rubber tires on the combustion behavior of its blends with coke for carbon injection in electric arc furnace steelmaking. Waste rubber tires were mixed in different proportions with metallurgical coke (MC) (10:90, 20:80, 30:70) for combustion and pyrolysis at 1473 K in a drop tube furnace (DTF) and thermogravimetric analyzer (TGA), respectively. Under experimental conditions most of the rubber blends indicated higher combustion efficiencies compared to those of the constituent coke. In the early stage of combustion the weight loss rate of the blends is much faster compared to that of the raw coke due to the higher volatile yield of rubber. The presence of rubber in the blends may have had an impact upon the structure during the release and combustion of their high volatile matter (VM) and hence increased char burnout. Measurements of micropore surface area and bulk density of the chars collected after combustion support the higher combustion efficiency of the blends in comparison to coke alone. The surface morphology of the 30% rubber blend revealed pores in the residual char that might be attributed to volatile evolution during high temperature reaction in oxygen atmosphere. Physical properties and VM appear to have a major effect upon the measured combustion efficiency of rubber blends. The study demonstrates that waste rubber tires can be successfully co-injected with metallurgical coke in electric arc furnace steelmaking process to provide additional energy from combustion. 44 refs., 11 figs., 2 tabs.

  4. Nanoparticle enhanced ionic liquid heat transfer fluids

    DOE Patents [OSTI]

    Fox, Elise B.; Visser, Ann E.; Bridges, Nicholas J.; Gray, Joshua R.; Garcia-Diaz, Brenda L.

    2014-08-12

    A heat transfer fluid created from nanoparticles that are dispersed into an ionic liquid is provided. Small volumes of nanoparticles are created from e.g., metals or metal oxides and/or alloys of such materials are dispersed into ionic liquids to create a heat transfer fluid. The nanoparticles can be dispersed directly into the ionic liquid during nanoparticle formation or the nanoparticles can be formed and then, in a subsequent step, dispersed into the ionic liquid using e.g., agitation.

  5. High-strength insulating castable used behind coke-oven buckstays and jambs

    SciTech Connect (OSTI)

    Sich, G. Jr. ); Gladfelder, L.A. . Iron and Steel Monolithics); Cox, F.S.

    1993-10-01

    Conventional pumpable, clay-based grouting materials used behind the armor/jamb systems were inadequate. Open brick joints caused reduced end flue temperatures which resulted in improper coking with reduced yields and coke quality, as well as difficulties in controlling door emissions. Based on criteria established by an Armco task force, a unique commercial product supplied by North American Refractories was located that had the potential of meeting these requirements. A laboratory trial casting program was undertaken by Armco that verified the potential of this castable refractory. Development programs by Armco and North American Refractories were established to optimize the properties of the refractory. Actual oven repairs have demonstrated that the castable developed meets all requirements for successful performance. These include: absence of castable failures; nonspalling; repairable through ceramic welding; and acceptable flowability.

  6. Coke oven doors: Historical methods of emission control and evaluation of current designs

    SciTech Connect (OSTI)

    Pettrey, J.O.; Greene, D.E. )

    1993-01-01

    The containment of oven door leakage has presented challenges to coke producers for many years as the requirements of environmental regulatory agencies have become increasingly stringent. A description and evaluation of past door modifications, leakage control methodologies and luting practices on Armco Steel Company, L.P.'s Ashland No. 4 Battery is detailed to provide a background for recent work, and to expand the industry's technology base. The strict door leakage standards of the 1990 amendments to the USA Clean Air Act has prompted additional technical studies. Both a joint Armco committee's evaluation of successful systems world wide and test door installations at Ashland were incorporated to determine compliance strategy. The eventual installation of Ikio Model II coke oven doors, along with modifications to ancillary equipment, has resulted in door leakage rates approaching zero. Associated methods, problems, results and evaluations are discussed.

  7. Air pollution from a large steel factory: polycyclic aromatic hydrocarbon emissions from coke-oven batteries

    SciTech Connect (OSTI)

    Lorenzo Liberti; Michele Notarnicola; Roberto Primerano; Paolo Zannetti

    2006-03-15

    A systematic investigation of solid and gaseous atmospheric emissions from some coke-oven batteries of one of Europe's largest integrated steel factory (Taranto, Italy) has been carried out. These emissions, predominantly diffuse, originate from oven leakages, as well as from cyclic operations of coal loading and coke unloading. In air monitoring samples, polycyclic aromatic hydrocarbons (PAHs) were consistently detected at concentrations largely exceeding threshold limit values. By means of PAHs speciation profile and benzo-(a)pyrene (BaP) equivalent dispersion modeling from diffuse sources, the study indicated that serious health risks exist not only in working areas, but also in a densely populated residential district near the factory. 30 refs., 5 figs., 3 tabs.

  8. A mathematical model for the estimation of flue temperature in a coke oven

    SciTech Connect (OSTI)

    Choi, K.I.; Kim, S.Y.; Suo, J.S.; Hur, N.S.; Kang, I.S.; Lee, W.J.

    1997-12-31

    The coke plants at the Kwangyang works has adopted an Automatic Battery Control (ABC) system which consists of four main parts, battery heating control, underfiring heat and waste gas oxygen control, pushing and charging schedule and Autotherm-S that measures heating wall temperature during pushing. The measured heating wall temperature is used for calculating Mean Battery Temperature (MBT) which is average temperature of flues for a battery, but the Autotherm-S system can not provide the flue temperatures of an oven. This work attempted to develop mathematical models for the estimation of the flue temperature using the measured heating wall temperature and to examine fitness of the mathematical model for the coke plant operation by analysis of raw gas temperature at the stand pipe. Through this work it is possible to reflect heating wall temperature in calculating MBT for battery heating control without the interruption caused by a maintenance break.

  9. Incorporation of deuterium in coke formed on an acetylene hydrogenation catalyst

    SciTech Connect (OSTI)

    Larsson, M.; Jansson, J.; Asplund, S.

    1996-09-01

    In selective hydrogenation of acetylene in excess ethylene, considerable amounts of coke or {open_quotes}green oils{close_quotes} are formed and accumulate on the catalyst. A fraction of the acetylene undergoes oligomerization reactions producing C{sub 4}`s and larger hydrocarbons. Compounds larger than C{sub 8} are retained on the catalysts surface or as a condensed phase in the pore system. The reaction mechanism is largely unknown but several authors have postulated that oligomerization occurs through dissociatively adsorbed acetylene (2), i.e., C{sub 2}H(ads) and C{sub 2}(ads). In this paper a novel method of studying the coke formation on a catalyst is introduced. Deuterium is incorporated in the coke during hydrogenation of acetylene, and during temperature-programmed oxidation (TPO) experiments the deuterium content is analyzed. The objective is to shed some light on the mechanism for oligomer formation in this system. The catalyst, Pd/{alpha}-Al{sub 2}O{sub 3}, was prepared by the impregnation of {alpha}-alumina (Sued-Chemie) with a solution of Pd(NO{sub 3}){sub 2} in 30% HNO{sub 3}. 8 refs., 4 figs.

  10. Health-hazard evaluation report No. HETA-88-377-2120, Armco Coke Oven, Ashland Kentucky

    SciTech Connect (OSTI)

    Kinnes, G.M.; Fleeger, A.K.; Baron, S.L.

    1991-06-01

    In response to a request from the Oil, Chemical and Atomic Workers International Union, a study was made of possible hazardous working conditions at ARMCO Coke Oven (SIC-3312), Ashland, Kentucky. The facility produces about 1,000,000 tons of coke annually. Of the approximately 400 total employees at the coke oven site, 55 work in the by products area. Air quality sampling results indicated overexposure to both benzene (71432) and coal tar pitch volatiles (CTPVs). Airborne levels of benzene ranged as high as 117 parts per million (ppm) with three of 17 samples being above the OSHA limit of 1ppm. Airborne concentrations of CTPVs ranged as high as 0.38mg/cu m with two of six readings being above OSHA limit of 0.2mg/cu m. Several polynuclear aromatic hydrocarbons were also detected. The authors conclude that by products area workers are potentially overexposed to carcinogens, including benzene, CTPVs, and polynuclear aromatic hydrocarbons. An epidemiologic study is considered unlikely to yield meaningful information at this time, due to the small number of workers and the short follow up period. The authors recommend specific measures for reducing potential employee exposures, including an environmental sampling program, a preventive maintenance program, improved housekeeping procedures, and reducing exposure in operators' booths.

  11. Hot metal Si control at Kwangyang blast furnaces

    SciTech Connect (OSTI)

    Hur, N.S.; Cho, B.R.; Kim, G.Y.; Choi, J.S.; Kim, B.H.

    1995-12-01

    Studies of Si transfer in blast furnaces have shown that the Si level in pig iron is influenced more by the reaction of silicon oxide gas generation in the raceway than the chemical reaction between hot metal and slag at the drop zone. Specifications require a Si content of pig iron below 0.15% at the Kwangyang Works, but the use of soft coking coal in the blend for coke ovens, high pulverized coal injection rate into the blast furnace, and the application of lower grade iron ore has resulted in the need to develop methods to control Si in hot metal. In this paper, the results of in furnace Si control and the desiliconization skills at the casthouse floor are described.

  12. Liquid metal thermal electric converter

    DOE Patents [OSTI]

    Abbin, Joseph P.; Andraka, Charles E.; Lukens, Laurance L.; Moreno, James B.

    1989-01-01

    A liquid metal thermal electric converter which converts heat energy to electrical energy. The design of the liquid metal thermal electric converter incorporates a unique configuration which directs the metal fluid pressure to the outside of the tube which results in the structural loads in the tube to be compressive. A liquid metal thermal electric converter refluxing boiler with series connection of tubes and a multiple cell liquid metal thermal electric converter are also provided.

  13. Relational contracting and the law and economics of vertical integration: a study of the economics of petroleum coking, processing, and consumption

    SciTech Connect (OSTI)

    Erickson, J.R.

    1981-01-01

    The basis for this study was an antitrust suit brought by the Federal Trade Commission against the Great Lakes Carbon Corp., a processor and reseller of green petroleum coke, and eight petroleum refiners. The respondents in this case were accused of using long-term contracts to foreclose the markets for both green and processed petroleum coke. Chapter 1 develops a theory of exchange and the contracts governing exchange. Chapter 2 describes the petroleum-coke industry and the nature of green coke exchange. It explains the reasons for the highly concentrated structure of the green-coke market in terms of the technology of petroleum-coke production and consumption and the physical and byproduct nature of petroleum coke. Chapter 3 takes a large number of green-coke contracts and breaks them down into their various relevant provisions. These provisions are then grouped according to their purpose and the characteristics of the firms employing them and shows that differences between the contracts can be explained by differences in the risks to firms of engaging in green coke exchange. Chapter 4 discusses the implications of vertical restrictions from the point of view of relational contracting using the data adduced in Chapter 3.

  14. Fluid casting of particle-based articles

    DOE Patents [OSTI]

    Menchhofer, P.

    1995-03-28

    A method is disclosed for the production of articles made of a particle-based material; e.g., ceramics and sintered metals. In accordance with one aspect of the invention, a thermally settable slurry containing a relatively high concentration of the particles is introduced into an immiscible, heated fluid. The slurry sets hardens into a shape determined by the physical characteristics of the fluid and the manner of introduction of the slurry into the fluid. For example, the slurry is pulse injected into the fluid to provide spherical articles. The hardened spheres may then be sintered to consolidate the particles and provide a high density product. 1 figure.

  15. Fluid casting of particle-based articles

    DOE Patents [OSTI]

    Menchhofer, Paul

    1995-01-01

    A method for the production of articles made of a particle-based material; e.g., ceramics and sintered metals. In accordance with one aspect of the invention, a thermally settable slurry containing a relatively high concentration of the particles is introduced into an immiscible, heated fluid. The slurry sets or hardens into a shape determined by the physical characteristics of the fluid and the manner of introduction of the slurry into the fluid. For example, the slurry is pulse injected into the fluid to provide spherical articles. The hardened spheres may then be sintered to consolidate the particles and provide a high density product.

  16. Proposal of a novel multifunctional energy system for cogeneration of coke, hydrogen, and power - article no. 052001

    SciTech Connect (OSTI)

    Jin, H.G.; Sun, S.; Han, W.; Gao, L.

    2009-09-15

    This paper proposes a novel multifunctional energy system (MES), which cogenerates coke, hydrogen, and power, through the use of coal and coke oven gas (COG). In this system, a new type of coke oven, firing coal instead of COG as heating resource for coking, is adopted. The COG rich in H{sub 2} is sent to a pressure swing adsorption (PSA) unit to separate about 80% of hydrogen first, and then the PSA purge gas is fed to a combined cycle as fuel. The new system combines the chemical processes and power generation system, along with the integration of chemical conversion and thermal energy utilization. In this manner, both the chemical energy of fuel and thermal energy can be used more effectively. With the same inputs of fuel and the same output of coking heat, the new system can produce about 65% more hydrogen than that of individual systems. As a result, the thermal efficiency of the new system is about 70%, and the exergy efficiency is about 66%. Compared with individual systems, the primary energy saving ratio can reach as high as 12.5%. Based on the graphical exergy analyses, we disclose that the integration of synthetic utilization of COG and coal plays a significant role in decreasing the exergy destruction of the MES system. The promising results obtained may lead to a clean coal technology that will utilize COG and coal more efficiently and economically.

  17. Effects of fluid dynamics on cleaning efficacy of supercritical fluids

    SciTech Connect (OSTI)

    Phelps, M.R.; Willcox, W.A.; Silva, L.J.; Butner, R.S.

    1993-03-01

    Pacific Northwest Laboratory (PNL) and Boeing Aerospace Company are developing a process to clean metal parts using a supercritical solvent. This work is part of an effort to address issues inhibiting the rapid commercialization of Supercritical Fluid Parts Cleaning (SFPC). PNL assembled a SFPC test stand to observe the relationship between the fluid dynamics of the system and the mass transfer of a contaminant from the surface of a contaminated metal coupon into the bulk fluid. The bench-scale test stand consists of a ``Berty`` autoclave modified for these tests and supporting hardware to achieve supercritical fluids parts cleaning. Three separate sets of tests were conducted using supercritical carbon dioxide. For the first two tests, a single stainless steel coupon was cleaned with organic solvents to remove surface residue, doped with a single contaminant, and then cleaned in the SFPC test stand. Contaminants studied were Dow Corning 200 fluid (dimethylpolysiloxane) and Castle/Sybron X-448 High-temperature Oil (a polybutane/mineral oil mixture). A set of 5-minute cleaning runs was conducted for each dopant at various autoclave impeller speeds. Test results from the first two sets of experiments indicate that precision cleaning for difficult-to-remove contaminants can be dramatically improved by introducing and increasing turbulence within the system. Metal coupons that had been previously doped with aircraft oil were used in a third set of tests. The coupons were placed in the SFPC test stand and subjected to different temperatures, pressures, and run times at a constant impeller speed. The cleanliness of each part was measured by Optically Stimulated Electron Emission. The third set of tests show that levels of cleanliness attained with supercritical carbon dioxide compare favorably with solvent and aqueous cleaning levels.

  18. Effects of fluid dynamics on cleaning efficacy of supercritical fluids

    SciTech Connect (OSTI)

    Phelps, M.R.; Willcox, W.A.; Silva, L.J.; Butner, R.S.

    1993-03-01

    Pacific Northwest Laboratory (PNL) and Boeing Aerospace Company are developing a process to clean metal parts using a supercritical solvent. This work is part of an effort to address issues inhibiting the rapid commercialization of Supercritical Fluid Parts Cleaning (SFPC). PNL assembled a SFPC test stand to observe the relationship between the fluid dynamics of the system and the mass transfer of a contaminant from the surface of a contaminated metal coupon into the bulk fluid. The bench-scale test stand consists of a Berty'' autoclave modified for these tests and supporting hardware to achieve supercritical fluids parts cleaning. Three separate sets of tests were conducted using supercritical carbon dioxide. For the first two tests, a single stainless steel coupon was cleaned with organic solvents to remove surface residue, doped with a single contaminant, and then cleaned in the SFPC test stand. Contaminants studied were Dow Corning 200 fluid (dimethylpolysiloxane) and Castle/Sybron X-448 High-temperature Oil (a polybutane/mineral oil mixture). A set of 5-minute cleaning runs was conducted for each dopant at various autoclave impeller speeds. Test results from the first two sets of experiments indicate that precision cleaning for difficult-to-remove contaminants can be dramatically improved by introducing and increasing turbulence within the system. Metal coupons that had been previously doped with aircraft oil were used in a third set of tests. The coupons were placed in the SFPC test stand and subjected to different temperatures, pressures, and run times at a constant impeller speed. The cleanliness of each part was measured by Optically Stimulated Electron Emission. The third set of tests show that levels of cleanliness attained with supercritical carbon dioxide compare favorably with solvent and aqueous cleaning levels.

  19. Coke oven gas treatment and by-product plant of Magnitogorsk Integrated Iron and Steel Works

    SciTech Connect (OSTI)

    Egorov, V.N.; Anikin, G.J.; Gross, M.

    1995-12-01

    Magnitogorsk Integrated Iron and Steel Works, Russia, decided to erect a new coke oven gas treatment and by-product plant to replace the existing obsolete units and to improve the environmental conditions of the area. The paper deals with the technological concept and the design requirements. Commissioning is scheduled at the beginning of 1996. The paper describes H{sub 2}S and NH{sub 3} removal, sulfur recovery and ammonia destruction, primary gas cooling and electrostatic tar precipitation, and the distributed control system that will be installed.

  20. Improved wastewater treatment at Wheeling-Pittsburgh Steel Corporations`s Steubenville East Coke Plant

    SciTech Connect (OSTI)

    Goshe, A.J.; Nodianos, M.J.

    1995-12-01

    Wheeling-Pittsburgh Steel Corporation recently improved its wastewater treatment at it`s by-products coke plant. This has led to greatly improved effluent quality. Excess ammonia liquor, along with wastewater from the light oil recovery plant, desulfurization facility, and coal pile runoff, must be treated prior to being discharged into the Ohio River. This is accomplished using a biological wastewater treatment plant to remove 99.99% of the organic contaminants and ammonia. Biologically treated, clarified wastewater is now polished in the newly constructed tertiary treatment plant.

  1. Specialized Materials and Fluids and Power Plants | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Specialized Materials and Fluids and Power Plants Specialized Materials and Fluids and Power Plants Below are the project presentations and respective peer review results for Specialized Materials and Fluids and Power Plants. Evaluate Thermal Spray Coatings as a Pressure Seal, Joseph A. Henfling, Sandia National Laboratories Technologies for Extracting Valuable Metals and Compounds from Geothermal Fluids, Dr. Stephen Harrison, Simbol Mining Corp. Chemical Energy Carriers (CEC) for the

  2. Method of winning aluminum metal from aluminous ore

    DOE Patents [OSTI]

    Loutfy, Raouf O.; Keller, Rudolf; Yao, Neng-Ping

    1981-01-01

    Aluminous ore such as bauxite containing alumina is blended with coke or other suitable form of carbon and reacted with sulfur gas at an elevated temperature. For handling, the ore and coke can be extruded into conveniently sized pellets. The reaction with sulfur gas produces molten aluminum sulfide which is separated from residual solid reactants and impurities. The aluminum sulfide is further increased in temperature to cause its decomposition or sublimation, yielding aluminum subsulfide liquid (AlS) and sulfur gas that is recycled. The aluminum monosulfide is then cooled to below its disproportionation temperature to again form molten aluminum sulfide and aluminum metal. A liquid-liquid or liquid-solid separation, depending on the separation temperature, provides product aluminum and aluminum sulfide for recycle to the disproportionation step.

  3. Method of winning aluminum metal from aluminous ore

    DOE Patents [OSTI]

    Loutfy, R.O.; Keller, R.; Yao, N.P.

    Aluminous ore such as bauxite containing alumina is blended with coke or other suitable form of carbon and reacted with sulfur gas at an elevated temperature. For handling, the ore and coke can be extruded into conveniently sized pellets. The reaction with sulfur gas produces molten aluminum sulfide which is separated from residual solid reactants and impurities. The aluminum sulfide is further increased in temperature to cause its decomposition or sublimation, yielding aluminum subsulfide liquid (A1S) and sulfur gas that is recycled. The aluminum monosulfide is then cooled to below its disproportionation temperature to again form molten aluminum sulfide and aluminum metal. A liquid-liquid or liquid-solid separation, depending on the separation temperature, provides product aluminum and aluminum sulfide for recycle to the disproportionation step.

  4. Fluid sampling tool

    DOE Patents [OSTI]

    Garcia, Anthony R.; Johnston, Roger G.; Martinez, Ronald K.

    2000-01-01

    A fluid-sampling tool for obtaining a fluid sample from a container. When used in combination with a rotatable drill, the tool bores a hole into a container wall, withdraws a fluid sample from the container, and seals the borehole. The tool collects fluid sample without exposing the operator or the environment to the fluid or to wall shavings from the container.

  5. Cracking of simulated oil refinery off-gas over a coal char, petroleum coke, and quartz

    SciTech Connect (OSTI)

    Yuan Zhang; Jin-hu Wu; Dong-ke Zhang

    2008-03-15

    The cracking of oil refinery off-gas, simulated with a gas mixture containing methane (51%), ethylene (21.4%), ethane (21.1%), and propane (6.5%), over a coal char, petroleum coke, and quartz, respectively, has been studied in a fixed bed reactor. The experiments were performed at temperatures between 850 and 1000{sup o}C and at atmospheric pressure. The results show that the conversions of all species considered increased with increasing temperature. Ethane and propane completely decomposed over all three bed materials in the temperature range investigated. However, the higher initial conversion rates of methane and ethylene cracking at all temperatures were observed only over the coal char and not on the petroleum coke and quartz, indicating a significant catalytic effect of the coal char on methane and ethylene cracking. Methane and ethylene conversions decreased with reaction time due to deactivation of the coal char by carbon deposition on the char surface and, in the later stage of a cracking experiment, became negative, suggesting that methane and ethylene had been formed during the cracking of ethane and propane. 16 refs., 13 figs., 2 tabs.

  6. Fluid Inclusion Gas Analysis

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Dilley, Lorie

    Fluid inclusion gas analysis for wells in various geothermal areas. Analyses used in developing fluid inclusion stratigraphy for wells and defining fluids across the geothermal fields. Each sample has mass spectrum counts for 180 chemical species.

  7. Fluid Inclusion Gas Analysis

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Dilley, Lorie

    2013-01-01

    Fluid inclusion gas analysis for wells in various geothermal areas. Analyses used in developing fluid inclusion stratigraphy for wells and defining fluids across the geothermal fields. Each sample has mass spectrum counts for 180 chemical species.

  8. Petroleum Coke

    Gasoline and Diesel Fuel Update (EIA)

    Proved Reserves (Billion Cubic Feet) Pennsylvania Shale Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 96 88 3,790 2010's 10,708 23,581 32,681 44,325 56,210 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 11/19/2015 Next Release Date: 12/31/2016 Referring Pages: Shale Natural Gas Proved Reserves as of Dec. 31 Pennsylvania Shale Gas

  9. Process for regenerating a spent resid hydroprocessing catalyst using a Group IV metal

    SciTech Connect (OSTI)

    Clark, F.T.; Springman, M.C.

    1993-08-03

    A method is described for regenerating a contaminant metal-containing, resid hydroprocessing molecular sieve-free catalyst for use with an ebullated bed reaction process wherein said catalyst contains a pore volume of pores having a diameter greater than 1200 Angstroms of at least 0.05 cc/gm, comprising the steps of: (a) partially decoking said catalyst in an initial coke-burning step wherein said catalyst is contacted with an oxygen-containing gas at a temperature ranging from about 400 F to about 700 F; (b) incorporating a Group IV metal onto said partially decoked catalyst such that the partially decoked catalyst contains about 0.1 to about 20.0 wt % of said Group IV metal calculated as the oxide and based on the fresh weight of said catalyst; and (c) decoking said partially decoked, Group IV metal-containing catalyst in a final coke-burning step wherein said catalyst is contacted with an oxygen-containing gas at a temperature ranging from about 600 F to about 1,400 F, thereby removing a substantial amount of said coke, wherein the loss on attrition of said resid hydroprocessing molecular sieve-free catalyst after step (c) is less than 9 weight percent fines per day calculated based on a regeneration temperature of 1,000 F.

  10. Serpentine metal gasket

    DOE Patents [OSTI]

    Rothgeb, Timothy Moore; Reece, Charles Edwin

    2009-06-02

    A metallic seal or gasket for use in the joining of cryogenic fluid conduits, the seal or gasket having a generally planar and serpentine periphery defining a central aperture. According to a preferred embodiment, the periphery has at least two opposing elongated serpentine sides and two opposing arcuate ends joining the opposing elongated serpentine sides and is of a hexagonal cross-section.

  11. Fluid transport container

    DOE Patents [OSTI]

    DeRoos, Bradley G.; Downing, Jr., John P.; Neal, Michael P.

    1995-01-01

    An improved fluid container for the transport, collection, and dispensing of a sample fluid that maintains the fluid integrity relative to the conditions of the location at which it is taken. More specifically, the invention is a fluid sample transport container that utilizes a fitment for both penetrating and sealing a storage container under controlled conditions. Additionally, the invention allows for the periodic withdrawal of portions of the sample fluid without contamination or intermixing from the environment surrounding the sample container.

  12. Fluid transport container

    DOE Patents [OSTI]

    DeRoos, B.G.; Downing, J.P. Jr.; Neal, M.P.

    1995-11-14

    An improved fluid container for the transport, collection, and dispensing of a sample fluid that maintains the fluid integrity relative to the conditions of the location at which it is taken. More specifically, the invention is a fluid sample transport container that utilizes a fitting for both penetrating and sealing a storage container under controlled conditions. Additionally, the invention allows for the periodic withdrawal of portions of the sample fluid without contamination or intermixing from the environment surrounding the sample container. 13 figs.

  13. Computational Fluid Dynamics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    scour-tracc-cfd TRACC RESEARCH Computational Fluid Dynamics Computational Structural Mechanics Transportation Systems Modeling Computational Fluid Dynamics Overview of CFD: Video Clip with Audio Computational fluid dynamics (CFD) research uses mathematical and computational models of flowing fluids to describe and predict fluid response in problems of interest, such as the flow of air around a moving vehicle or the flow of water and sediment in a river. Coupled with appropriate and prototypical

  14. Immobilized fluid membranes for gas separation (Patent) | DOEPatents

    Office of Scientific and Technical Information (OSTI)

    In one example, the immobilized membrane includes a porous metallic host matrix and an immobilized liquid fluid (such as a silicone oil) that is immobilized within one or more ...

  15. Coke oven air and water pollution. (Latest citations from the EI Compendex*Plus database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1994-09-01

    The bibliography contains citations concerning coke oven pollution. Monitoring, sampling, analyzing, transport properties, and control of emissions and effluents are cited in this compilation from worldwide journals. Pollutants described are sulfur dioxide, hydrogen sulfide, ammonia, phenols, benzopyrene, particulates, and other trace elements and compounds. Process and equipment modifications, such as pipeline charging, wet and dry quenching, retrofitting, and oven leakage preventives are included. (Contains a minimum of 200 citations and includes a subject term index and title list.)

  16. GEOTHERMAL FLUID PROPENE AND PROPANE: INDICATORS OF FLUID | Open...

    Open Energy Info (EERE)

    FLUID PROPENE AND PROPANE: INDICATORS OF FLUID Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Proceedings: GEOTHERMAL FLUID PROPENE AND PROPANE:...

  17. Environmentally safe fluid extractor

    DOE Patents [OSTI]

    Sungaila, Zenon F.

    1993-07-06

    An environmentally safe fluid extraction device for use in mobile laboratory and industrial settings comprising a pump, compressor, valving system, waste recovery tank, fluid tank, and a exhaust filtering system.

  18. Electric fluid pump

    DOE Patents [OSTI]

    Van Dam, Jeremy Daniel; Turnquist, Norman Arnold; Raminosoa, Tsarafidy; Shah, Manoj Ramprasad; Shen, Xiaochun

    2015-09-29

    An electric machine is presented. The electric machine includes a hollow rotor; and a stator disposed within the hollow rotor, the stator defining a flow channel. The hollow rotor includes a first end portion defining a fluid inlet, a second end portion defining a fluid outlet; the fluid inlet, the fluid outlet, and the flow channel of the stator being configured to allow passage of a fluid from the fluid inlet to the fluid outlet via the flow channel; and wherein the hollow rotor is characterized by a largest cross-sectional area of hollow rotor, and wherein the flow channel is characterized by a smallest cross-sectional area of the flow channel, wherein the smallest cross-sectional area of the flow channel is at least about 25% of the largest cross-sectional area of the hollow rotor. An electric fluid pump and a power generation system are also presented.

  19. Environmentally safe fluid extractor

    DOE Patents [OSTI]

    Sungaila, Zenon F.

    1993-01-01

    An environmentally safe fluid extraction device for use in mobile laboratory and industrial settings comprising a pump, compressor, valving system, waste recovery tank, fluid tank, and a exhaust filtering system.

  20. Fluid sampling tool

    DOE Patents [OSTI]

    Johnston, Roger G.; Garcia, Anthony R. E.; Martinez, Ronald K.

    2001-09-25

    The invention includes a rotatable tool for collecting fluid through the wall of a container. The tool includes a fluid collection section with a cylindrical shank having an end portion for drilling a hole in the container wall when the tool is rotated, and a threaded portion for tapping the hole in the container wall. A passageway in the shank in communication with at least one radial inlet hole in the drilling end and an opening at the end of the shank is adapted to receive fluid from the container. The tool also includes a cylindrical chamber affixed to the end of the shank opposite to the drilling portion thereof for receiving and storing fluid passing through the passageway. The tool also includes a flexible, deformable gasket that provides a fluid-tight chamber to confine kerf generated during the drilling and tapping of the hole. The invention also includes a fluid extractor section for extracting fluid samples from the fluid collecting section.

  1. Fluid force transducer

    DOE Patents [OSTI]

    Jendrzejczyk, Joseph A.

    1982-01-01

    An electrical fluid force transducer for measuring the magnitude and direction of fluid forces caused by lateral fluid flow, includes a movable sleeve which is deflectable in response to the movement of fluid, and a rod fixed to the sleeve to translate forces applied to the sleeve to strain gauges attached to the rod, the strain gauges being connected in a bridge circuit arrangement enabling generation of a signal output indicative of the magnitude and direction of the force applied to the sleeve.

  2. Methods for fluid separations, and devices capable of separating fluids

    DOE Patents [OSTI]

    TeGrotenhuis, Ward E [Kennewick, WA; Stenkamp, Victoria S [Richland, WA

    2006-05-30

    Wick-Containing apparatus capable of separating fluids and methods of separating fluids using wicks are disclosed.

  3. Methods for fluid separations, and devices capable of separating fluids

    DOE Patents [OSTI]

    TeGrotenhuis, Ward E.; Stenkamp, Victoria S.

    2007-09-25

    Wick-Containing apparatus capable of separating fluids and methods of separating fluids using wicks are disclosed.

  4. Effects of HyperCoal addition on coke strength and thermoplasticity of coal blends

    SciTech Connect (OSTI)

    Toshimasa Takanohashi; Takahiro Shishido; Ikuo Saito

    2008-05-15

    Ashless coal, also known as HyperCoal (HPC), was produced by thermal extraction of three coals of different ranks (Gregory caking coal, Warkworth steam coal, and Pasir subbituminous coal) with 1-methylnaphthalene (1-MN) at 360, 380, and 400{sup o}C. The effects of blending these HPCs into standard coal blends were investigated. Blending HPCs as 5-10% of a standard blend (Kouryusho:Goonyella:K9) enhanced the thermoplasticity over a wide temperature range. For blends made with the Pasir-HPC, produced from a noncaking coal, increasing the extraction temperature from 360 to 400{sup o}C increased the thermoplasticity significantly. Blends containing Warkworth-HPC, produced from a slightly caking coal, had a higher tensile strength than the standard blend in semicoke strength tests. The addition of 10% Pasir-HPC, extracted at 400{sup o}C, increased the tensile strength of the semicokes to the same degree as those made with Gregory-HPC. Furthermore, all HPC blends had a higher tensile strength and smaller weight loss during carbonization. These results suggest that the HPC became integrated into the coke matrix, interacting strongly with the other raw coals. 14 refs., 11 figs., 1 tab.

  5. Spinning fluids reactor

    DOE Patents [OSTI]

    Miller, Jan D; Hupka, Jan; Aranowski, Robert

    2012-11-20

    A spinning fluids reactor, includes a reactor body (24) having a circular cross-section and a fluid contactor screen (26) within the reactor body (24). The fluid contactor screen (26) having a plurality of apertures and a circular cross-section concentric with the reactor body (24) for a length thus forming an inner volume (28) bound by the fluid contactor screen (26) and an outer volume (30) bound by the reactor body (24) and the fluid contactor screen (26). A primary inlet (20) can be operatively connected to the reactor body (24) and can be configured to produce flow-through first spinning flow of a first fluid within the inner volume (28). A secondary inlet (22) can similarly be operatively connected to the reactor body (24) and can be configured to produce a second flow of a second fluid within the outer volume (30) which is optionally spinning.

  6. Fluid cooled electrical assembly

    DOE Patents [OSTI]

    Rinehart, Lawrence E.; Romero, Guillermo L.

    2007-02-06

    A heat producing, fluid cooled assembly that includes a housing made of liquid-impermeable material, which defines a fluid inlet and a fluid outlet and an opening. Also included is an electrical package having a set of semiconductor electrical devices supported on a substrate and the second major surface is a heat sink adapted to express heat generated from the electrical apparatus and wherein the second major surface defines a rim that is fit to the opening. Further, the housing is constructed so that as fluid travels from the fluid inlet to the fluid outlet it is constrained to flow past the opening thereby placing the fluid in contact with the heat sink.

  7. Fiber optic fluid detector

    DOE Patents [OSTI]

    Angel, S. Michael

    1989-01-01

    Particular gases or liquids are detected with a fiber optic element (11, 11a to 11j) having a cladding or coating of a material (23, 23a to 23j) which absorbs the fluid or fluids and which exhibits a change of an optical property, such as index of refraction, light transmissiveness or fluoresence emission, for example, in response to absorption of the fluid. The fluid is sensed by directing light into the fiber optic element and detecting changes in the light, such as exit angle changes for example, that result from the changed optical property of the coating material. The fluid detector (24, 24a to 24j) may be used for such purposes as sensing toxic or explosive gases in the atmosphere, measuring ground water contamination or monitoring fluid flows in industrial processes, among other uses.

  8. Fiber optic fluid detector

    DOE Patents [OSTI]

    Angel, S.M.

    1987-02-27

    Particular gases or liquids are detected with a fiber optic element having a cladding or coating of a material which absorbs the fluid or fluids and which exhibits a change of an optical property, such as index of refraction, light transmissiveness or fluoresence emission, for example, in response to absorption of the fluid. The fluid is sensed by directing light into the fiber optic element and detecting changes in the light, such as exit angle changes for example, that result from the changed optical property of the coating material. The fluid detector may be used for such purposes as sensing toxic or explosive gases in the atmosphere, measuring ground water contamination or monitoring fluid flows in industrial processes, among other uses. 10 figs.

  9. Microwave fluid flow meter

    DOE Patents [OSTI]

    Billeter, Thomas R.; Philipp, Lee D.; Schemmel, Richard R.

    1976-01-01

    A microwave fluid flow meter is described utilizing two spaced microwave sensors positioned along a fluid flow path. Each sensor includes a microwave cavity having a frequency of resonance dependent upon the static pressure of the fluid at the sensor locations. The resonant response of each cavity with respect to a variation in pressure of the monitored fluid is represented by a corresponding electrical output which can be calibrated into a direct pressure reading. The pressure drop between sensor locations is then correlated as a measure of fluid velocity. In the preferred embodiment the individual sensor cavities are strategically positioned outside the path of fluid flow and are designed to resonate in two distinct frequency modes yielding a measure of temperature as well as pressure. The temperature response can then be used in correcting for pressure responses of the microwave cavity encountered due to temperature fluctuations.

  10. Electrorheological fluids and methods

    DOE Patents [OSTI]

    Green, Peter F.; McIntyre, Ernest C.

    2015-06-02

    Electrorheological fluids and methods include changes in liquid-like materials that can flow like milk and subsequently form solid-like structures under applied electric fields; e.g., about 1 kV/mm. Such fluids can be used in various ways as smart suspensions, including uses in automotive, defense, and civil engineering applications. Electrorheological fluids and methods include one or more polar molecule substituted polyhedral silsesquioxanes (e.g., sulfonated polyhedral silsesquioxanes) and one or more oils (e.g., silicone oil), where the fluid can be subjected to an electric field.

  11. Method and apparatus for back-extracting metal chelates

    DOE Patents [OSTI]

    Wai, C.M.; Smart, N.G.; Lin, Y.

    1998-08-11

    A method is described for extracting metal and metalloid species from a solid or liquid substrate using a supercritical fluid solvent containing one or more chelating agents followed by back-extracting the metal and metalloid species from the metal and metalloid chelates formed thereby. The back-extraction acidic solution is performed utilizing an acidic solution. Upon sufficient exposure of the metal and metalloid chelates to the acidic solution, the metal and metalloid species are released from the chelates into the acid solution, while the chelating agent remains in the supercritical fluid solvent. The chelating agent is thereby regenerated and the metal and metalloid species recovered. 3 figs.

  12. Method and apparatus for back-extracting metal chelates

    DOE Patents [OSTI]

    Wai, Chien M.; Smart, Neil G.; Lin, Yuehe

    1998-01-01

    A method of extracting metal and metalloid species from a solid or liquid substrate using a supercritical fluid solvent containing one or more chelating agents followed by back-extracting the metal and metalloid species from the metal and metalloid chelates formed thereby. The back-extraction acidic solution is performed utilizing an acidic solution. Upon sufficient exposure of the metal and metalloid chelates to the acidic solution, the metal and metalloid species are released from the chelates into the acid solution, while the chelating agent remains in the supercritical fluid solvent. The chelating agent is thereby regenerated and the metal and metalloid species recovered.

  13. Metal aminoboranes

    DOE Patents [OSTI]

    Burrell, Anthony K.; Davis, Benjamin J.; Thorn, David L.; Gordon, John C.; Baker, R. Thomas; Semelsberger, Troy Allen; Tumas, William; Diyabalanage, Himashinie Vichalya Kaviraj; Shrestha, Roshan P.

    2010-05-11

    Metal aminoboranes of the formula M(NH.sub.2BH.sub.3).sub.n have been synthesized. Metal aminoboranes are hydrogen storage materials. Metal aminoboranes are also precursors for synthesizing other metal aminoboranes. Metal aminoboranes can be dehydrogenated to form hydrogen and a reaction product. The reaction product can react with hydrogen to form a hydrogen storage material. Metal aminoboranes can be included in a kit.

  14. FLUID CONTROLLING MEANS

    DOE Patents [OSTI]

    Pouliot, H.N.

    1960-11-01

    A device is described for releasing fluid from a container and delivering it to an outlet conduit. An explosive squib moves a piston so as to cut a wall section from the conduit and to punch a hole in the container, whereby a fluid may pass from the container into the conduit. A deformable sleeve retains the piston in its final position.

  15. Fluid delivery control system

    DOE Patents [OSTI]

    Hoff, Brian D.; Johnson, Kris William; Algrain, Marcelo C.; Akasam, Sivaprasad

    2006-06-06

    A method of controlling the delivery of fluid to an engine includes receiving a fuel flow rate signal. An electric pump is arranged to deliver fluid to the engine. The speed of the electric pump is controlled based on the fuel flow rate signal.

  16. Geothermal Produced Fluids: Characteristics, Treatment Technologies, and Management Options

    SciTech Connect (OSTI)

    Finster, Molly; Clark, Corrie; Schroeder, Jenna; Martino, Louis

    2015-10-01

    Geothermal power plants use geothermal fluids as a resource and create waste residuals as part of the power generation process. Both the geofluid resource and the waste stream are considered produced fluids. The chemical and physical nature of produced fluids can have a major impact on the geothermal power industry and can influence the feasibility of geothermal power development, exploration approaches, power plant design, operating practices, and the reuse or disposal of residuals. In general, produced fluids include anything that comes out of a geothermal field and that subsequently must be managed on the surface. These fluids vary greatly depending on the geothermal reservoir being harnessed, power plant design, and the life cycle stage in which the fluid exists, but generally include water and fluids used to drill geothermal wells, fluids used to stimulate wells in enhanced geothermal systems, and makeup and/or cooling water used during operation of a geothermal power plant. Additional geothermal-related produced fluids include many substances that are similar to waste streams from the oil and gas industry, such as scale, flash tank solids, precipitated solids from brine treatment, hydrogen sulfide, and cooling-tower-related waste. This review paper aims to provide baseline knowledge on specific technologies and technology areas associated with geothermal power production. Specifically, this research focused on the management techniques related to fluids produced and used during the operational stage of a geothermal power plant; the vast majority of which are employed in the generation of electricity. The general characteristics of produced fluids are discussed. Constituents of interest that tend to drive the selection of treatment technologies are described, including total dissolved solids, noncondensable gases, scale and corrosion, silicon dioxide, metal sulfides, calcium carbonate, corrosion, metals, and naturally occurring radioactive material. Management

  17. FLUID SELECTING APPARATUS

    DOE Patents [OSTI]

    Stinson, W.J.

    1958-09-16

    A valve designed to selectively sample fluids from a number of sources is described. The valve comprises a rotatable operating lever connected through a bellows seal to a rotatable assembly containing a needle valve, bearings, and a rotational lock. The needle valve is connected through a flexible tube to the sample fluid outlet. By rotating the lever the needle valve is placed over . one of several fluid sources and locked in position so that the fluid is traasferred through the flexible tubing and outlet to a remote sampling system. The fluids from the nonselected sources are exhausted to a waste line. This valve constitutes a simple, dependable means of selecting a sample from one of several scurces.

  18. Fluid blade disablement tool

    DOE Patents [OSTI]

    Jakaboski, Juan-Carlos; Hughs, Chance G.; Todd, Steven N.

    2012-01-10

    A fluid blade disablement (FBD) tool that forms both a focused fluid projectile that resembles a blade, which can provide precision penetration of a barrier wall, and a broad fluid projectile that functions substantially like a hammer, which can produce general disruption of structures behind the barrier wall. Embodiments of the FBD tool comprise a container capable of holding fluid, an explosive assembly which is positioned within the container and which comprises an explosive holder and explosive, and a means for detonating. The container has a concavity on the side adjacent to the exposed surface of the explosive. The position of the concavity relative to the explosive and its construction of materials with thicknesses that facilitate inversion and/or rupture of the concavity wall enable the formation of a sharp and coherent blade of fluid advancing ahead of the detonation gases.

  19. Technologies for Extracting Valuable Metals and Compounds from Geothermal

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fluids | Department of Energy Technologies for Extracting Valuable Metals and Compounds from Geothermal Fluids Technologies for Extracting Valuable Metals and Compounds from Geothermal Fluids DOE Geothermal Peer Review 2010 - Presentation. Project objectives: Demonstrate geothermal mineral extraction; Demonstrate technical and economic feasibility; Produce products for market development; Generate operational data and scale up data so a commercial scale plant can be designed and built.

  20. Fluid sampling tool

    DOE Patents [OSTI]

    Garcia, Anthony R.; Johnston, Roger G.; Martinez, Ronald K.

    1999-05-25

    A fluid sampling tool for sampling fluid from a container. The tool has a fluid collecting portion which is drilled into the container wall, thereby affixing it to the wall. The tool may have a fluid extracting section which withdraws fluid collected by the fluid collecting section. The fluid collecting section has a fluted shank with an end configured to drill a hole into a container wall. The shank has a threaded portion for tapping the borehole. The shank is threadably engaged to a cylindrical housing having an inner axial passageway sealed at one end by a septum. A flexible member having a cylindrical portion and a bulbous portion is provided. The housing can be slid into an inner axial passageway in the cylindrical portion and sealed to the flexible member. The bulbous portion has an outer lip defining an opening. The housing is clamped into the chuck of a drill, the lip of the bulbous section is pressed against a container wall until the shank touches the wall, and the user operates the drill. Wall shavings (kerf) are confined in a chamber formed in the bulbous section as it folds when the shank advances inside the container. After sufficient advancement of the shank, an o-ring makes a seal with the container wall.

  1. Fluid sampling tool

    DOE Patents [OSTI]

    Garcia, A.R.; Johnston, R.G.; Martinez, R.K.

    1999-05-25

    A fluid sampling tool is described for sampling fluid from a container. The tool has a fluid collecting portion which is drilled into the container wall, thereby affixing it to the wall. The tool may have a fluid extracting section which withdraws fluid collected by the fluid collecting section. The fluid collecting section has a fluted shank with an end configured to drill a hole into a container wall. The shank has a threaded portion for tapping the borehole. The shank is threadably engaged to a cylindrical housing having an inner axial passageway sealed at one end by a septum. A flexible member having a cylindrical portion and a bulbous portion is provided. The housing can be slid into an inner axial passageway in the cylindrical portion and sealed to the flexible member. The bulbous portion has an outer lip defining an opening. The housing is clamped into the chuck of a drill, the lip of the bulbous section is pressed against a container wall until the shank touches the wall, and the user operates the drill. Wall shavings (kerf) are confined in a chamber formed in the bulbous section as it folds when the shank advances inside the container. After sufficient advancement of the shank, an o-ring makes a seal with the container wall. 6 figs.

  2. Dispersion modeling of polycyclic aromatic hydrocarbons from combustion of biomass and fossil fuels and production of coke in Tianjin, China

    SciTech Connect (OSTI)

    Shu Tao; Xinrong Li; Yu Yang; Raymond M. Coveney, Jr.; Xiaoxia Lu; Haitao Chen; Weiran Shen

    2006-08-01

    A USEPA procedure, ISCLT3 (Industrial Source Complex Long-Term), was applied to model the spatial distribution of polycyclic aromatic hydrocarbons (PAHs) emitted from various sources including coal, petroleum, natural gas, and biomass into the atmosphere of Tianjin, China. Benzo(a)pyrene equivalent concentrations (BaPeq) were calculated for risk assessment. Model results were provisionally validated for concentrations and profiles based on the observed data at two monitoring stations. The dominant emission sources in the area were domestic coal combustion, coke production, and biomass burning. Mainly because of the difference in the emission heights, the contributions of various sources to the average concentrations at receptors differ from proportions emitted. The shares of domestic coal increased from {approximately} 43% at the sources to 56% at the receptors, while the contributions of coking industry decreased from {approximately} 23% at the sources to 7% at the receptors. The spatial distributions of gaseous and particulate PAHs were similar, with higher concentrations occurring within urban districts because of domestic coal combustion. With relatively smaller contributions, the other minor sources had limited influences on the overall spatial distribution. The calculated average BaPeq value in air was 2.54 {+-} 2.87 ng/m{sup 3} on an annual basis. Although only 2.3% of the area in Tianjin exceeded the national standard of 10 ng/m{sup 3}, 41% of the entire population lives within this area. 37 refs., 9 figs.

  3. Development of materials resistant to metal dusting degradation.

    SciTech Connect (OSTI)

    Natesan, K.; Zeng, Z.; Nuclear Engineering Division

    2007-12-07

    The deposition of carbon from carbonaceous gaseous environments is prevalent in many chemical and petrochemical processes such as, hydrogen-, ammonia-, and methanol-reforming systems, syngas production systems, and iron-ore reduction plants. One of the major consequences of carbon deposition is the degradation of structural materials by a phenomenon known as ''metal dusting''. There are two major issues of importance in metal dusting. First is formation of coke and subsequent deposition of coke on metallic structural components. Second is the initiation and subsequent propagation of metal dusting degradation of the structural alloy. In the past, we reported on the mechanism for metal dusting of Fe- and Ni-base alloys. In this report, we present metal dusting data on both Fe- and Ni-base alloys after exposure in high and atmospheric pressure environments that simulate the gas chemistry in operating hydrogen reformers. We have also measured the progression of pits by measuring the depth as a function of exposure time for a variety of Fe- and Ni-base structural alloys. We have clearly established the role of transport of iron in forming a non-protective spinel phase in the initiation process and presence of carbon transfer channels in the oxide scale for the continued propagation of pits, by nano-beam X-ray analysis using the advance photon source (APS), Raman scattering, and SEM/EDX analysis. In this report, we have developed correlations between weight loss and pit progression rates and evaluated the effects of carbon activity, system pressure, and alloy chemistry, on weight loss and pit propagation. To develop pit propagation data for the alloys without incurring substantial time for the initiation of pits, especially for the Ni-base alloys that exhibit incubation times of thousands of hours, a pre-pitting method has been developed. The pre-pitted alloys exhibited pit propagation rates similar to those of materials tested without pre-pitting. We have also developed

  4. EXPERIMENTAL LIQUID METAL FUEL REACTOR

    DOE Patents [OSTI]

    Happell, J.J.; Thomas, G.R.; Denise, R.P.; Bunts, J.L. Jr.

    1962-01-23

    A liquid metal fuel nuclear fission reactor is designed in which the fissionable material is dissolved or suspended in a liquid metal moderator and coolant. The liquid suspension flows into a chamber in which a critical amount of fissionable material is obtained. The fluid leaves the chamber and the heat of fission is extracted for power or other utilization. The improvement is in the support arrangement for a segrnented graphite core to permit dif ferential thermal expansion, effective sealing between main and blanket liquid metal flows, and avoidance of excessive stress development in the graphite segments. (AEC)

  5. Molten metal injector system and method

    DOE Patents [OSTI]

    Meyer, Thomas N.; Kinosz, Michael J.; Bigler, Nicolas; Arnaud, Guy

    2003-04-01

    Disclosed is a molten metal injector system including a holder furnace, a casting mold supported above the holder furnace, and a molten metal injector supported from a bottom side of the mold. The holder furnace contains a supply of molten metal having a metal oxide film surface. The bottom side of the mold faces the holder furnace. The mold defines a mold cavity for receiving the molten metal from the holder furnace. The injector projects into the holder furnace and is in fluid communication with the mold cavity. The injector includes a piston positioned within a piston cavity defined by a cylinder for pumping the molten metal upward from the holder furnace and injecting the molten metal into the mold cavity under pressure. The piston and cylinder are at least partially submerged in the molten metal when the holder furnace contains the molten metal. The cylinder further includes a molten metal intake for receiving the molten metal into the piston cavity. The molten metal intake is located below the metal oxide film surface of the molten metal when the holder furnace contains the molten metal. A method of injecting molten metal into a mold cavity of a casting mold is also disclosed.

  6. FLUID PRESSURE AND CAM OPERATED VACUUM VALVE

    DOE Patents [OSTI]

    Batzer, T.H.

    1963-11-26

    An ultra-high vacuum valve that is bakable, reusable, and capable of being quickly opened and closed is described. A translationally movable valve gate having an annular ridge is adapted to contact an annular soft metal gasket disposed at the valve seat such that the soft metal gasket extends beyond the annular ridge on all sides. The valve gate is closed, by first laterally aligning the valve gate with the valve seat and then bringing the valve gate and valve seat into seating contact by the translational movement of a ramp-like wedging means that engages similar ramp-like stractures at the base of the valve gate to force the valve gate into essentially pressureless contact with the annular soft metal gasket. This gasket is then pressurized from beneath by a fluid thereby effecting a vacuura tight seal between the gasket and the ridge. (AEC)

  7. Basic fluid system trainer

    DOE Patents [OSTI]

    Semans, Joseph P.; Johnson, Peter G.; LeBoeuf, Jr., Robert F.; Kromka, Joseph A.; Goron, Ronald H.; Hay, George D.

    1993-01-01

    A trainer, mounted and housed within a mobile console, is used to teach and reinforce fluid principles to students. The system trainer has two centrifugal pumps, each driven by a corresponding two-speed electric motor. The motors are controlled by motor controllers for operating the pumps to circulate the fluid stored within a supply tank through a closed system. The pumps may be connected in series or in parallel. A number of valves are also included within the system to effect different flow paths for the fluid. In addition, temperature and pressure sensing instruments are installed throughout the closed system for measuring the characteristics of the fluid, as it passes through the different valves and pumps. These measurements are indicated on a front panel mounted to the console, as a teaching aid, to allow the students to observe the characteristics of the system.

  8. Valve for fluid control

    DOE Patents [OSTI]

    Oborny, Michael C.; Paul, Phillip H.; Hencken, Kenneth R.; Frye-Mason, Gregory C.; Manginell, Ronald P.

    2001-01-01

    A valve for controlling fluid flows. This valve, which includes both an actuation device and a valve body provides: the ability to incorporate both the actuation device and valve into a unitary structure that can be placed onto a microchip, the ability to generate higher actuation pressures and thus control higher fluid pressures than conventional microvalves, and a device that draws only microwatts of power. An electrokinetic pump that converts electric potential to hydraulic force is used to operate, or actuate, the valve.

  9. Computational Fluid Dynamics (CFD) Modeling for High Rate Pulverized Coal Injection (PCI) into the Blast Furnace

    SciTech Connect (OSTI)

    Dr. Chenn Zhou

    2008-10-15

    Pulverized coal injection (PCI) into the blast furnace (BF) has been recognized as an effective way to decrease the coke and total energy consumption along with minimization of environmental impacts. However, increasing the amount of coal injected into the BF is currently limited by the lack of knowledge of some issues related to the process. It is therefore important to understand the complex physical and chemical phenomena in the PCI process. Due to the difficulty in attaining trus BF measurements, Computational fluid dynamics (CFD) modeling has been identified as a useful technology to provide such knowledge. CFD simulation is powerful for providing detailed information on flow properties and performing parametric studies for process design and optimization. In this project, comprehensive 3-D CFD models have been developed to simulate the PCI process under actual furnace conditions. These models provide raceway size and flow property distributions. The results have provided guidance for optimizing the PCI process.

  10. Metal inks

    DOE Patents [OSTI]

    Ginley, David S; Curtis, Calvin J; Miedaner, Alex; van Hest, Marinus Franciscus Antonius Maria; Kaydanova, Tatiana

    2014-02-04

    Self-reducing metal inks and systems and methods for producing and using the same are disclosed. In an exemplary embodiment, a method may comprise selecting metal-organic (MO) precursor, selecting a reducing agent, and dissolving the MO precursor and the reducing agent in an organic solvent to produce a metal ink that remains in a liquid phase at room temperature. Metal inks, including self-reducing and fire-through metal inks, are also disclosed, as are various applications of the metal inks.

  11. Microscale fluid transport using optically controlled marangoni effect

    DOE Patents [OSTI]

    Thundat, Thomas G; Passian, Ali; Farahi, Rubye H

    2011-05-10

    Low energy light illumination and either a doped semiconductor surface or a surface-plasmon supporting surface are used in combination for manipulating a fluid on the surface in the absence of any applied electric fields or flow channels. Precise control of fluid flow is achieved by applying focused or tightly collimated low energy light to the surface-fluid interface. In the first embodiment, with an appropriate dopant level in the semiconductor substrate, optically excited charge carriers are made to move to the surface when illuminated. In a second embodiment, with a thin-film noble metal surface on a dispersive substrate, optically excited surface plasmons are created for fluid manipulation. This electrode-less optical control of the Marangoni effect provides re-configurable manipulations of fluid flow, thereby paving the way for reprogrammable microfluidic devices.

  12. Encapsulated Nanoparticle Synthesis and Characterization for Improved Storage Fluids: Preprint

    SciTech Connect (OSTI)

    Glatzmaier, G. C.; Pradhan, S.; Kang, J.; Curtis, C.; Blake, D.

    2010-10-01

    Nanoparticles are typically composed of 50--500 atoms and exhibit properties that are significantly different from the properties of larger, macroscale particles that have the same composition. The addition of these particles to traditional fluids may improve the fluids' thermophysical properties. As an example, the addition of a nanoparticle or set of nanoparticles to a storage fluid may double its heat capacity. This increase in heat capacity would allow a sensible thermal energy storage system to store the same amount of thermal energy in half the amount of storage fluid. The benefit is lower costs for the storage fluid and the storage tanks, resulting in lower-cost electricity. The goal of this long-term research is to create a new class of fluids that enable concentrating solar power plants to operate with greater efficiency and lower electricity costs. Initial research on this topic developed molecular dynamic models that predicted the energy states and transition temperatures for these particles. Recent research has extended the modeling work, along with initiating the synthesis and characterization of bare metal nanoparticles and metal nanoparticles that are encapsulated with inert silica coatings. These particles possess properties that make them excellent candidates for enhancing the heat capacity of storage fluids.

  13. Metal/ceramic composites with high hydrogen permeability

    DOE Patents [OSTI]

    Dorris, Stephen E.; Lee, Tae H.; Balachandran, Uthamalingam

    2003-05-27

    A membrane for separating hydrogen from fluids is provided comprising a sintered homogenous mixture of a ceramic composition and a metal. The metal may be palladium, niobium, tantalum, vanadium, or zirconium or a binary mixture of palladium with another metal such as niobium, silver, tantalum, vanadium, or zirconium.

  14. Development and installation of a high strength insulating castable for use behind buckstays and jambs of a 6-meter coke battery

    SciTech Connect (OSTI)

    Cox, F.S. ); Sich, G. ); Gladfelder, L.

    1993-01-01

    The 6-meter coke oven batteries at Armco Steel Company, L.P.'s Middletown Works experienced stand pipe base failure and numerous door fires with the original hammer-type double knife edge door design. These events resulted in deformation of the battery buckstay, armoring, tie rod, and jamb system. In 1983, these issues were addressed by releasing the jamb from the interlocking armor, replacing the jamb casting, and strengthening the buckstays in place through minimum capital expenditures. End flue refractory condition at that time was good, and little movement was measured. The 1983 repairs did not eliminate heating wall movement, and the heating wall refractories gradually deteriorated. The end flues required special maintenance attention. Broken brickwork from the refractory shapes surrounding the coke side inspection port inside the end flues blocked air ports and gas nozzles. Open brick joints between the nose brick allowed gas and heat to escape the flue toward the buckstays and jambs. This heat loss deformed jambs and reduced end flue temperatures. Jamb movement resulted in partial loss of contact between the top of the jambs and the lintel area above the jambs, resulting in some loss of brick above the jamb area. Improper coking of the coal charge at the end flues reduced yield and affected coke quality. Door emissions and pushing emissions became more difficult to control. A task group explored several strategies for solving these refractory problems. The strategies that were investigated varied widely in scope and cost. One low cost alternative explored (and the one eventually adopted) was to repair the coke side of the batteries. The scope of the repair included three components. Install a new jamb; Reseal the lintel area above the jamb with a castable refractory; and Reseal the area between the end flue and the buckstay/armor/jamb system with a castable refractory. This paper describes the project.

  15. Method for absorbing an ion from a fluid

    DOE Patents [OSTI]

    Gao, Huizhen; Wang, Yifeng; Bryan, Charles R.

    2007-07-03

    A method for absorbing an ion from a fluid by using dispersing an organic acid into an anion surfactant solution, mixing in a divalent-metal containing compound and a trivalent-metal containing compound and calcining the resulting solid layered double hydroxide product to form an absorbent material and then contacting the absorbent material with an aqueous solution of cations or anions to be absorbed.

  16. METAL PHTHALOCYANINES

    DOE Patents [OSTI]

    Frigerio, N.A.

    1962-03-27

    A process is given for preparing heavy metal phthalocyanines, sulfonated or not. The process comprises mixing an inorganic metal salt with dimethyl formamide or methyl sulfoxide; separating the metal complex formed from the solution; mixing the complex with an equimolar amount of sodium, potassium, lithium, magnesium, or beryllium sulfonated or unsulfonated phthalocyanine whereby heavy-metal phthalocyanine crystals are formed; and separating the crystals from the solution. Uranyl, thorium, lead, hafnium, and lanthanide rare earth phthalocyanines can be produced by the process. (AEC)

  17. Boiler using combustible fluid

    DOE Patents [OSTI]

    Baumgartner, H.; Meier, J.G.

    1974-07-03

    A fluid fuel boiler is described comprising a combustion chamber, a cover on the combustion chamber having an opening for introducing a combustion-supporting gaseous fluid through said openings, means to impart rotation to the gaseous fluid about an axis of the combustion chamber, a burner for introducing a fluid fuel into the chamber mixed with the gaseous fluid for combustion thereof, the cover having a generally frustro-conical configuration diverging from the opening toward the interior of the chamber at an angle of between 15/sup 0/ and 55/sup 0/; means defining said combustion chamber having means defining a plurality of axial hot gas flow paths from a downstream portion of the combustion chamber to flow hot gases into an upstream portion of the combustion chamber, and means for diverting some of the hot gas flow along paths in a direction circumferentially of the combustion chamber, with the latter paths being immersed in the water flow path thereby to improve heat transfer and terminating in a gas outlet, the combustion chamber comprising at least one modular element, joined axially to the frustro-conical cover and coaxial therewith. The modular element comprises an inner ring and means of defining the circumferential, radial, and spiral flow paths of the hot gases.

  18. Fluid driven reciprocating apparatus

    DOE Patents [OSTI]

    Whitehead, J.C.

    1997-04-01

    An apparatus is described comprising a pair of fluid driven pump assemblies in a back-to-back configuration to yield a bi-directional pump. Each of the pump assemblies includes a piston or diaphragm which divides a chamber therein to define a power section and a pumping section. An intake-exhaust valve is connected to each of the power sections of the pump chambers, and function to direct fluid, such as compressed air, into the power section and exhaust fluid therefrom. At least one of the pistons or diaphragms is connected by a rod assembly which is constructed to define a signal valve, whereby the intake-exhaust valve of one pump assembly is controlled by the position or location of the piston or diaphragm in the other pump assembly through the operation of the rod assembly signal valve. Each of the pumping sections of the pump assemblies are provided with intake and exhaust valves to enable filling of the pumping section with fluid and discharging fluid therefrom when a desired pressure has been reached. 13 figs.

  19. Fluid driven recipricating apparatus

    DOE Patents [OSTI]

    Whitehead, John C.

    1997-01-01

    An apparatus comprising a pair of fluid driven pump assemblies in a back-to-back configuration to yield a bi-directional pump. Each of the pump assemblies includes a piston or diaphragm which divides a chamber therein to define a power section and a pumping section. An intake-exhaust valve is connected to each of the power sections of the pump chambers, and function to direct fluid, such as compressed air, into the power section and exhaust fluid therefrom. At least one of the pistons or diaphragms is connected by a rod assembly which is constructed to define a signal valve, whereby the intake-exhaust valve of one pump assembly is controlled by the position or location of the piston or diaphragm in the other pump assembly through the operation of the rod assembly signal valve. Each of the pumping sections of the pump assemblies are provided with intake and exhaust valves to enable filling of the pumping section with fluid and discharging fluid therefrom when a desired pressure has been reached.

  20. Fluorescent fluid interface position sensor

    DOE Patents [OSTI]

    Weiss, Jonathan D.

    2004-02-17

    A new fluid interface position sensor has been developed, which is capable of optically determining the location of an interface between an upper fluid and a lower fluid, the upper fluid having a larger refractive index than a lower fluid. The sensor functions by measurement, of fluorescence excited by an optical pump beam which is confined within a fluorescent waveguide where that waveguide is in optical contact with the lower fluid, but escapes from the fluorescent waveguide where that waveguide is in optical contact with the upper fluid.

  1. Silicone metalization

    DOE Patents [OSTI]

    Maghribi, Mariam N.; Krulevitch, Peter; Hamilton, Julie

    2006-12-05

    A system for providing metal features on silicone comprising providing a silicone layer on a matrix and providing a metal layer on the silicone layer. An electronic apparatus can be produced by the system. The electronic apparatus comprises a silicone body and metal features on the silicone body that provide an electronic device.

  2. Silicone metalization

    DOE Patents [OSTI]

    Maghribi, Mariam N.; Krulevitch, Peter; Hamilton, Julie

    2008-12-09

    A system for providing metal features on silicone comprising providing a silicone layer on a matrix and providing a metal layer on the silicone layer. An electronic apparatus can be produced by the system. The electronic apparatus comprises a silicone body and metal features on the silicone body that provide an electronic device.

  3. Fluid lubricated bearing construction

    DOE Patents [OSTI]

    Dunning, John R.; Boorse, Henry A.; Boeker, Gilbert F.

    1976-01-01

    1. A fluid lubricated thrust bearing assembly comprising, in combination, a first bearing member having a plain bearing surface, a second bearing member having a bearing surface confronting the bearing surface of said first bearing member and provided with at least one spiral groove extending inwardly from the periphery of said second bearing member, one of said bearing members having an axial fluid-tight well, a source of fluid lubricant adjacent to the periphery of said second bearing member, and means for relatively rotating said bearing members to cause said lubricant to be drawn through said groove and to flow between said bearing surfaces, whereby a sufficient pressure is built up between said bearing surfaces and in said well to tend to separate said bearing surfaces.

  4. Universal fluid droplet ejector

    DOE Patents [OSTI]

    Lee, E.R.; Perl, M.L.

    1999-08-24

    A droplet generator comprises a fluid reservoir having a side wall made of glass or quartz, and an end cap made from a silicon plate. The end cap contains a micromachined aperture through which the fluid is ejected. The side wall is thermally fused to the end cap, and no adhesive is necessary. This means that the fluid only comes into contact with the side wall and the end cap, both of which are chemically inert. Amplitudes of drive pulses received by reservoir determine the horizontal displacements of droplets relative to the ejection aperture. The drive pulses are varied such that the dropper generates a two-dimensional array of vertically-falling droplets. Vertical and horizontal inter-droplet spacings may be varied in real time. Applications include droplet analysis experiments such as Millikan fractional charge searches and aerosol characterization, as well as material deposition applications. 8 figs.

  5. Universal fluid droplet ejector

    DOE Patents [OSTI]

    Lee, Eric R.; Perl, Martin L.

    1999-08-24

    A droplet generator comprises a fluid reservoir having a side wall made of glass or quartz, and an end cap made from a silicon plate. The end cap contains a micromachined aperture through which the fluid is ejected. The side wall is thermally fused to the end cap, and no adhesive is necessary. This means that the fluid only comes into contact with the side wall and the end cap, both of which are chemically inert. Amplitudes of drive pulses received by reservoir determine the horizontal displacements of droplets relative to the ejection aperture. The drive pulses are varied such that the dropper generates a two-dimensional array of vertically-falling droplets. Vertical and horizontal interdroplet spacings may be varied in real time. Applications include droplet analysis experiments such as Millikan fractional charge searches and aerosol characterization, as well as material deposition applications.

  6. Completion and workover fluid

    SciTech Connect (OSTI)

    Block, J.

    1985-09-17

    An aqueous completion or workover fluid for oil or gas wells having at least two solid components. One component is a hydroxy containing aluminum compound represented by the formula AlO(OH).xH/sub 2/O. The second component is a fluid loss control agent which can be either a cross-linked polyvinyl alcohol or a cross-linked hydroxyalkyl cellulose reaction product. An acid soluble weighting agent can be added for wells having higher down hole pressures. Examples of the weighting agents include iron carbonates, iron oxides, calcium carbonates, dolomite, sodium or calcium chloride, zinc bromide and calcium bromide. After use, the fluid can be displaced from the well with acid, e.g. 15% HCl, and the cake previously deposited on the bore-hole wall is dissolved by the acid so that no damaging residue remains.

  7. Hazardous fluid leak detector

    DOE Patents [OSTI]

    Gray, Harold E.; McLaurin, Felder M.; Ortiz, Monico; Huth, William A.

    1996-01-01

    A device or system for monitoring for the presence of leaks from a hazardous fluid is disclosed which uses two electrodes immersed in deionized water. A gas is passed through an enclosed space in which a hazardous fluid is contained. Any fumes, vapors, etc. escaping from the containment of the hazardous fluid in the enclosed space are entrained in the gas passing through the enclosed space and transported to a closed vessel containing deionized water and two electrodes partially immersed in the deionized water. The electrodes are connected in series with a power source and a signal, whereby when a sufficient number of ions enter the water from the gas being bubbled through it (indicative of a leak), the water will begin to conduct, thereby allowing current to flow through the water from one electrode to the other electrode to complete the circuit and activate the signal.

  8. Fluid extraction using carbon dioxide and organophosphorus chelating agents

    DOE Patents [OSTI]

    Smart, N.G.; Wai, C.M.; Lin, Y.; Kwang, Y.H.

    1998-11-24

    Methods for extracting metalloid and metal species from a solid or liquid material by exposing the material to a fluid solvent, particularly supercritical CO{sub 2}, and a chelating agent are described. The chelating agent forms a chelate with the species, the chelate being soluble in the fluid to allow removal of the species from the material. In preferred embodiments the extraction solvent is supercritical CO{sub 2} and the chelating agent comprises an organophosphorous chelating agent, particularly sulfur-containing organophosphorous chelating agents, including mixtures of chelating agents. Examples of chelating agents include monothiophosphinic acid, di-thiophosphinic acid, phosphine sulfite, phosphorothioic acid, and mixtures thereof. The method provides an environmentally benign process for removing metal and metalloids from industrial waste solutions, particularly acidic solutions. Both the chelate and the supercritical fluid can be regenerated and the contaminant species recovered to provide an economic, efficient process. 1 fig.

  9. Fluid extraction using carbon dioxide and organophosphorus chelating agents

    DOE Patents [OSTI]

    Smart, Neil G.; Wai, Chien M.; Lin, Yuehe; Kwang, Yak Hwa

    1998-01-01

    Methods for extracting metalloid and metal species from a solid or liquid material by exposing the material to a fluid solvent, particularly supercritical CO.sub.2, and a chelating agent are described. The chelating agent forms a chelate with the species, the chelate being soluble in the fluid to allow removal of the species from the material. In preferred embodiments the extraction solvent is supercritical CO.sub.2 and the chelating agent comprises an organophosphorous chelating agent, particularly sulfur-containing organophosphorous chelating agents, including mixtures of chelating agents. Examples of chelating agents include monothiophosphinic acid, di-thiophosphinic acid, phosphine sulfite, phosphorothioic acid, and mixtures thereof. The method provides an environmentally benign process for removing metal and metalloids from industrial waste solutions, particularly acidic solutions. Both the chelate and the supercritical fluid can be regenerated and the contaminant species recovered to provide an economic, efficient process.

  10. Ultrasonic fluid densitometry and densitometer

    DOE Patents [OSTI]

    Greenwood, M.S.; Lail, J.C.

    1998-01-13

    The present invention is an ultrasonic fluid densitometer that uses a material wedge having an acoustic impedance that is near the acoustic impedance of the fluid, specifically less than a factor of 11 greater than the acoustic impedance of the fluid. The invention also includes a wedge having at least two transducers for transmitting and receiving ultrasonic signals internally reflected within the material wedge. Density of a fluid is determined by immersing the wedge into the fluid and measuring reflection of ultrasound at the wedge-fluid interface. 6 figs.

  11. Ultrasonic fluid densitometry and densitometer

    DOE Patents [OSTI]

    Greenwood, Margaret S.; Lail, Jason C.

    1998-01-01

    The present invention is an ultrasonic fluid densitometer that uses a material wedge having an acoustic impedance that is near the acoustic impedance of the fluid, specifically less than a factor of 11 greater than the acoustic impedance of the fluid. The invention also includes a wedge having at least two transducers for transmitting and receiving ultrasonic signals internally reflected within the material wedge. Density of a fluid is determined by immersing the wedge into the fluid and measuring reflection of ultrasound at the wedge-fluid interface.

  12. Pressurized tundish for controlling a continuous flow of molten metal

    DOE Patents [OSTI]

    Lewis, T.W.; Hamill, P.E. Jr.; Ozgu, M.R.; Padfield, R.C.; Rego, D.N.; Brita, G.P.

    1990-07-24

    A pressurized tundish for controlling a continuous flow of molten metal is characterized by having a pair of principal compartments, one being essentially unpressurized and receiving molten metal introduced thereto, and the other being adapted for maintaining a controlled gaseous pressure over the surface of the fluid metal therein, whereby, by controlling the pressure within the pressurized chamber, metal exiting from the tundish is made to flow continually and at a controlled rate. 1 fig.

  13. Pressurized tundish for controlling a continuous flow of molten metal

    DOE Patents [OSTI]

    Lewis, Thomas W.; Hamill, Jr., Paul E.; Ozgu, Mustafa R.; Padfield, Ralph C.; Rego, Donovan N.; Brita, Guido P.

    1990-01-01

    A pressurized tundish for controlling a continous flow of molten metal characterized by having a pair of principal compartments, one being essentially unpressurized and receiving molten metal introduced thereto, and the other being adapted for maintaining a controlled gaseous pressure over the surface of the fluid metal therein, whereby, by controlling the pressure within the pressurized chamber, metal exiting from the tundish is made to flow continually and at a controlled rate.

  14. Fluid processing device and method

    DOE Patents [OSTI]

    Whyatt, Greg A. (West Richland, WA); Davis, James M. (Richland, WA)

    2006-02-07

    A fluid processing unit having first and second interleaved flow paths in a cross flow configuration is disclosed. The first flow paths are substantially longer than the second flow paths such that the pressure drop in the second flow paths can be maintained at a relatively low level and temperature variations across the second flow paths are reduced. One or more of the flow paths can be microchannels. When used as a vaporizer and/or superheater, the longer first flow paths include an upstream liquid flow portion and a downstream vapor flow portion of enlarged cross sectional area. A substantial pressure drop is maintained through the upstream liquid flow portion for which one or more tortuous flow channels can be utilized. The unit is a thin panel, having a width substantially less its length or height, and is manufactured together with other thin units in a bonded stack of thin metal sheets. The individual units are then separated from the stack after bonding.

  15. Immobilized fluid membranes for gas separation

    DOE Patents [OSTI]

    Liu, Wei; Canfield, Nathan L; Zhang, Jian; Li, Xiaohong Shari; Zhang, Jiguang

    2014-03-18

    Provided herein are immobilized liquid membranes for gas separation, methods of preparing such membranes and uses thereof. In one example, the immobilized membrane includes a porous metallic host matrix and an immobilized liquid fluid (such as a silicone oil) that is immobilized within one or more pores included within the porous metallic host matrix. The immobilized liquid membrane is capable of selective permeation of one type of molecule (such as oxygen) over another type of molecule (such as water). In some examples, the selective membrane is incorporated into a device to supply oxygen from ambient air to the device for electrochemical reactions, and at the same time, to block water penetration and electrolyte loss from the device.

  16. METHOD OF CLEANING METAL SURFACES

    DOE Patents [OSTI]

    Winkler, H.W.; Morfitt, J.W.; Little, T.H.

    1959-05-19

    Cleaning fluids for removing deposits from metal surfaces are described. The cleaning agents of the invention consist of aqueous nitric acid and an amhydrous nitrate salt of a metal which is lower in the electromotive series than the element of the deposit to be removed. In general, the salt content of thc cleaning agents ranged from 10 to 90%, preferably from 10 to 40% by weight; and the balance of the composition comprises nitric acid of any strength from extremely dilute up to concentrated strength.

  17. Magnetically stimulated fluid flow patterns

    SciTech Connect (OSTI)

    Martin, Jim; Solis, Kyle

    2014-03-06

    Sandia National Laboratories' Jim Martin and Kyle Solis explain research on the effects of magnetic fields on fluid flows and how they stimulate vigorous flows. Fluid flow is a necessary phenomenon in everything from reactors to cooling engines in cars.

  18. Magnetically stimulated fluid flow patterns

    ScienceCinema (OSTI)

    Martin, Jim; Solis, Kyle

    2014-08-06

    Sandia National Laboratories' Jim Martin and Kyle Solis explain research on the effects of magnetic fields on fluid flows and how they stimulate vigorous flows. Fluid flow is a necessary phenomenon in everything from reactors to cooling engines in cars.

  19. Microchannel crossflow fluid heat exchanger and method for its fabrication

    DOE Patents [OSTI]

    Swift, G.W.; Migliori, A.; Wheatley, J.C.

    1982-08-31

    A microchannel crossflow fluid heat exchanger and a method for its fabrication are disclosed. The heat exchanger is formed from a stack of thin metal sheets which are bonded together. The stack consists of alternating slotted and unslotted sheets. Each of the slotted sheets includes multiple parallel slots which form fluid flow channels when sandwiched between the unslotted sheets. Successive slotted sheets in the stack are rotated ninety degrees with respect to one another so as to form two sets of orthogonally extending fluid flow channels which are arranged in a crossflow configuration. The heat exchanger has a high surface to volume ratio, a small dead volume, a high heat transfer coefficient, and is suitable for use with fluids under high pressures. The heat exchanger has particular application in a Stirling engine that utilizes a liquid as the working substance.

  20. Supercritical fluid carbon dioxide cleaning of plutonium parts

    SciTech Connect (OSTI)

    Hale, S.J.

    1991-12-31

    Supercritical fluid carbon dioxide is under investigation in this work for use as a cleaning solvent for the final cleaning of plutonium parts. These parts must be free of organic residue to avoid corrosion in the stockpile. Initial studies on stainless steel and full-scale mock-up parts indicate that the oils of interest are easily and adequately cleaned from the metal surfaces with supercritical fluid carbon dioxide. Results from compatibility studies show that undesirable oxidation or other surface reactions are not occurring during exposure of plutonium to the supercritical fluid. Cleaning studies indicate that the oils of interest are removed from the plutonium surface under relatively mild conditions. These studies indicate that supercritical fluid carbon dioxide is a very promising cleaning medium for this application.

  1. Microchannel crossflow fluid heat exchanger and method for its fabrication

    DOE Patents [OSTI]

    Swift, G.W.; Migliori, A.; Wheatley, J.C.

    1985-05-14

    A microchannel crossflow fluid heat exchanger and a method for its fabrication are disclosed. The heat exchanger is formed from a stack of thin metal sheets which are bonded together. The stack consists of alternating slotted and unslotted sheets. Each of the slotted sheets includes multiple parallel slots which form fluid flow channels when sandwiched between the unslotted sheets. Successive slotted sheets in the stack are rotated ninety degrees with respect to one another so as to form two sets of orthogonally extending fluid flow channels which are arranged in a crossflow configuration. The heat exchanger has a high surface to volume ratio, a small dead volume, a high heat transfer coefficient, and is suitable for use with fluids under high pressures. The heat exchanger has particular application in a Stirling engine that utilizes a liquid as the working substance. 9 figs.

  2. Microchannel crossflow fluid heat exchanger and method for its fabrication

    DOE Patents [OSTI]

    Swift, Gregory W.; Migliori, Albert; Wheatley, John C.

    1985-01-01

    A microchannel crossflow fluid heat exchanger and a method for its fabrication are disclosed. The heat exchanger is formed from a stack of thin metal sheets which are bonded together. The stack consists of alternating slotted and unslotted sheets. Each of the slotted sheets includes multiple parallel slots which form fluid flow channels when sandwiched between the unslotted sheets. Successive slotted sheets in the stack are rotated ninety degrees with respect to one another so as to form two sets of orthogonally extending fluid flow channels which are arranged in a crossflow configuration. The heat exchanger has a high surface to volume ratio, a small dead volume, a high heat transfer coefficient, and is suitable for use with fluids under high pressures. The heat exchanger has particular application in a Stirling engine that utilizes a liquid as the working substance.

  3. Production of MHD fluid

    DOE Patents [OSTI]

    Lacey, James J.; Kurtzrock, Roy C.; Bienstock, Daniel

    1976-08-24

    A hot gaseous fluid of low ash content, suitable for use in open-cycle MHD (magnetohydrodynamic) power generation, is produced by means of a three-stage process comprising (1) partial combustion of a fossil fuel to produce a hot gaseous product comprising CO.sub.2 CO, and H.sub.2 O, (2) reformation of the gaseous product from stage (1) by means of a fluidized char bed, whereby CO.sub.2 and H.sub.2 O are converted to CO and H.sub.2, and (3) combustion of CO and H.sub.2 from stage (2) to produce a low ash-content fluid (flue gas) comprising CO.sub.2 and H.sub.2 O and having a temperature of about 4000.degree. to 5000.degree.F.

  4. Oscillating fluid power generator

    DOE Patents [OSTI]

    Morris, David C

    2014-02-25

    A system and method for harvesting the kinetic energy of a fluid flow for power generation with a vertically oriented, aerodynamic wing structure comprising one or more airfoil elements pivotably attached to a mast. When activated by the moving fluid stream, the wing structure oscillates back and forth, generating lift first in one direction then in the opposite direction. This oscillating movement is converted to unidirectional rotational movement in order to provide motive power to an electricity generator. Unlike other oscillating devices, this device is designed to harvest the maximum aerodynamic lift forces available for a given oscillation cycle. Because the system is not subjected to the same intense forces and stresses as turbine systems, it can be constructed less expensively, reducing the cost of electricity generation. The system can be grouped in more compact clusters, be less evident in the landscape, and present reduced risk to avian species.

  5. Drilling fluid filter

    DOE Patents [OSTI]

    Hall, David R.; Fox, Joe; Garner, Kory

    2007-01-23

    A drilling fluid filter for placement within a bore wall of a tubular drill string component comprises a perforated receptacle with an open end and a closed end. A hanger for engagement with the bore wall is mounted at the open end of the perforated receptacle. A mandrel is adjacent and attached to the open end of the perforated receptacle. A linkage connects the mandrel to the hanger. The linkage may be selected from the group consisting of struts, articulated struts and cams. The mandrel operates on the hanger through the linkage to engage and disengage the drilling fluid filter from the tubular drill string component. The mandrel may have a stationary portion comprising a first attachment to the open end of the perforated receptacle and a telescoping adjustable portion comprising a second attachment to the linkage. The mandrel may also comprise a top-hole interface for top-hole equipment.

  6. ,,,,,,"Coal Components",,,"Coke",,,"Electricity Components",,,,,,,,,,,,,,"Natural Gas Components",,,"Steam Components"

    U.S. Energy Information Administration (EIA) Indexed Site

    Relative Standard Errors for Table 7.1;" " Unit: Percents." ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,"Selected Wood and Other Biomass Components" ,,,,,,"Coal Components",,,"Coke",,,"Electricity Components",,,,,,,,,,,,,,"Natural Gas Components",,,"Steam Components" " "," ",,,,,,,,,,,,,"Total",,,,,,,,,,,,,,,,,,,,,,,"Wood Residues",,,," " " "," ","

  7. Liquid metal pump for nuclear reactors

    DOE Patents [OSTI]

    Allen, H.G.; Maloney, J.R.

    1975-10-01

    A pump for use in pumping high temperature liquids at high pressures, particularly liquid metals used to cool nuclear reactors is described. It is of the type in which the rotor is submerged in a sump but is fed by an inlet duct which bypasses the sump. A chamber, kept full of fluid, surrounds the pump casing into which fluid is bled from the pump discharge and from which fluid is fed to the rotor bearings and hence to the sump. This equalizes pressure inside and outside the pump casing and reduces or eliminates the thermal shock to the bearings and sump tank.

  8. Supercritical fluid reverse micelle separation

    DOE Patents [OSTI]

    Fulton, John L.; Smith, Richard D.

    1993-01-01

    A method of separating solute material from a polar fluid in a first polar fluid phase is provided. The method comprises combining a polar fluid, a second fluid that is a gas at standard temperature and pressure and has a critical density, and a surfactant. The solute material is dissolved in the polar fluid to define the first polar fluid phase. The combined polar and second fluids, surfactant, and solute material dissolved in the polar fluid is maintained under near critical or supercritical temperature and pressure conditions such that the density of the second fluid exceeds the critical density thereof. In this way, a reverse micelle system defining a reverse micelle solvent is formed which comprises a continuous phase in the second fluid and a plurality of reverse micelles dispersed in the continuous phase. The solute material is dissolved in the polar fluid and is in chemical equilibrium with the reverse micelles. The first polar fluid phase and the continuous phase are immiscible. The reverse micelles each comprise a dynamic aggregate of surfactant molecules surrounding a core of the polar fluid. The reverse micelle solvent has a polar fluid-to-surfactant molar ratio W, which can vary over a range having a maximum ratio W.sub.o that determines the maximum size of the reverse micelles. The maximum ratio W.sub.o of the reverse micelle solvent is then varied, and the solute material from the first polar fluid phase is transported into the reverse micelles in the continuous phase at an extraction efficiency determined by the critical or supercritical conditions.

  9. Supercritical fluid reverse micelle separation

    DOE Patents [OSTI]

    Fulton, J.L.; Smith, R.D.

    1993-11-30

    A method of separating solute material from a polar fluid in a first polar fluid phase is provided. The method comprises combining a polar fluid, a second fluid that is a gas at standard temperature and pressure and has a critical density, and a surfactant. The solute material is dissolved in the polar fluid to define the first polar fluid phase. The combined polar and second fluids, surfactant, and solute material dissolved in the polar fluid is maintained under near critical or supercritical temperature and pressure conditions such that the density of the second fluid exceeds the critical density thereof. In this way, a reverse micelle system defining a reverse micelle solvent is formed which comprises a continuous phase in the second fluid and a plurality of reverse micelles dispersed in the continuous phase. The solute material is dissolved in the polar fluid and is in chemical equilibrium with the reverse micelles. The first polar fluid phase and the continuous phase are immiscible. The reverse micelles each comprise a dynamic aggregate of surfactant molecules surrounding a core of the polar fluid. The reverse micelle solvent has a polar fluid-to-surfactant molar ratio W, which can vary over a range having a maximum ratio W[sub o] that determines the maximum size of the reverse micelles. The maximum ratio W[sub o] of the reverse micelle solvent is then varied, and the solute material from the first polar fluid phase is transported into the reverse micelles in the continuous phase at an extraction efficiency determined by the critical or supercritical conditions. 27 figures.

  10. Recirculating Molten Metal Supply System And Method

    DOE Patents [OSTI]

    Kinosz, Michael J.; Meyer, Thomas N.

    2003-07-01

    The melter furnace includes a heating chamber (16), a pump chamber (18), a degassing chamber (20), and a filter chamber (22). The pump chamber (18) is located adjacent the heating chamber (16) and houses a molten metal pump (30). The degassing chamber (20) is located adjacent and in fluid communication with the pump chamber (18), and houses a degassing mechanism (36). The filter chamber (22) is located adjacent and in fluid communication with the degassing chamber (20). The filter chamber (22) includes a molten metal filter (38). The melter furnace (12) is used to supply molten metal to an externally located holder furnace (14), which then recirculates molten metal back to the melter furnace (12).

  11. Fluid bed material transfer method

    DOE Patents [OSTI]

    Pinske, Jr., Edward E.

    1994-01-01

    A fluidized bed apparatus comprising a pair of separated fluid bed enclosures, each enclosing a fluid bed carried on an air distributor plate supplied with fluidizing air from below the plate. At least one equalizing duct extending through sidewalls of both fluid bed enclosures and flexibly engaged therewith to communicate the fluid beds with each other. The equalizing duct being surrounded by insulation which is in turn encased by an outer duct having expansion means and being fixed between the sidewalls of the fluid bed enclosures.

  12. Heat transfer fluids containing nanoparticles

    DOE Patents [OSTI]

    Singh, Dileep; Routbort, Jules; Routbort, A.J.; Yu, Wenhua; Timofeeva, Elena; Smith, David S.; France, David M.

    2016-05-17

    A nanofluid of a base heat transfer fluid and a plurality of ceramic nanoparticles suspended throughout the base heat transfer fluid applicable to commercial and industrial heat transfer applications. The nanofluid is stable, non-reactive and exhibits enhanced heat transfer properties relative to the base heat transfer fluid, with only minimal increases in pumping power required relative to the base heat transfer fluid. In a particular embodiment, the plurality of ceramic nanoparticles comprise silicon carbide and the base heat transfer fluid comprises water and water and ethylene glycol mixtures.

  13. Metal oxide films on metal

    DOE Patents [OSTI]

    Wu, Xin D. (Los Alamos, NM); Tiwari, Prabhat (Los Alamos, NM)

    1995-01-01

    A structure including a thin film of a conductive alkaline earth metal oxide selected from the group consisting of strontium ruthenium trioxide, calcium ruthenium trioxide, barium ruthenium trioxide, lanthanum-strontium cobalt oxide or mixed alkaline earth ruthenium trioxides thereof upon a thin film of a noble metal such as platinum is provided.

  14. Reduction of COD in leachate from a hazardous waste landfill adjacent to a coke-making facility

    SciTech Connect (OSTI)

    Banerjee, K.; O`Toole, T.J.

    1995-12-01

    A hazardous waste landfill adjacent to a coke manufacturing facility was in operation between July 1990 and December 1991. A system was constructed to collect and treat the leachate from the landfill prior to discharge to the river. Occasionally, the discharge from the treatment facility exceeded the permit limitations for Chemical Oxygen Demand (COD), Biochemical Oxygen Demand (BOD), and Total Organic Carbon (TOC). The objectives of this study were to determine treatment methods which would enable compliance with the applicable discharge limits; to establish the desired operating conditions of the process; and to investigate the effect of various parameters such as pH, catalyst dosage, and reaction time on the COD destruction efficiency. The characteristics of the landfill leachate in question were significantly variable in terms of chemical composition. A review of the influent quality data suggests that the COD concentration ranges between 80 and 390 mg/l. The oxidation processes using Fenton`s reagent or a combination of UV/hydrogen peroxide/catalyst are capable of reducing the COD concentration of the leachate below the discharge limitation of 35 mg/l. The estimated capital cost associated with the Fenton`s reagent process is approximately $525,000, and the annual operating and maintenance cost is $560,000. The estimated capital cost for the UV/hydrogen peroxide/catalyst treatment system is $565,000. The annual operating and maintenance cost of this process would be approximately $430,000.

  15. A review of the global emissions, transport and effects of heavy metals in the environment

    SciTech Connect (OSTI)

    Friedman, J.R.; Ashton, W.B.; Rapoport, R.D.

    1993-06-01

    The purpose of this report is to describe the current state of knowledge regarding the sources and quantities of heavy metal emissions, their transport and fate, their potential health and environmental effects, and strategies to control them. The approach is to review the literature on this topic and to consult with experts in the field. Ongoing research activities and research needs are discussed. Estimates of global anthropogenic and natural emissions indicate that anthropogenic emissions are responsible for most of the heavy metals released into the atmosphere and that industrial activities have had a significant impact on the global cycling of trace metals. The largest anthropogenic sources of trace metals are coal combustion and the nonferrous metal industry. Atmospheric deposition is an important pathway by which trace metals enter the environment. Atmospheric deposition varies according to the solubility of the element and the length of time it resides in the atmosphere. Evidence suggests that deposition is influenced by other chemicals in the atmosphere, such as ozone and sulfur dioxide. Trace metals also enter the environment through leaching. Existing emissions-control technologies such as electrostatic precipitators, baghouses, and scrubbers are designed to remove other particulates from the flue gas of coal-fired power plants and are only partially effective at removing heavy metals. Emerging technologies such as flue gas desulfurization, lignite coke, and fluidized bed combustion could further reduce emissions. 108 refs.

  16. Acoustic concentration of particles in fluid flow

    DOE Patents [OSTI]

    Ward, Michael D.; Kaduchak, Gregory

    2010-11-23

    An apparatus for acoustic concentration of particles in a fluid flow includes a substantially acoustically transparent membrane and a vibration generator that define a fluid flow path therebetween. The fluid flow path is in fluid communication with a fluid source and a fluid outlet and the vibration generator is disposed adjacent the fluid flow path and is capable of producing an acoustic field in the fluid flow path. The acoustic field produces at least one pressure minima in the fluid flow path at a predetermined location within the fluid flow path and forces predetermined particles in the fluid flow path to the at least one pressure minima.

  17. Development of New Biphasic Metal Organic Working Fluids for...

    Open Energy Info (EERE)

    Additional heat transfer is limited after the vapor phase transition due the low thermal conductivity and heat capacity of the vapor. Also, operating pressures and...

  18. Methodologies for Reservoir Characterization Using Fluid Inclusion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Methodologies for Reservoir Characterization Using Fluid Inclusion Gas Chemistry Methodologies for Reservoir Characterization Using Fluid Inclusion Gas Chemistry Methodologies for ...

  19. Apparatus for gas-metal arc deposition

    DOE Patents [OSTI]

    Buhrmaster, Carol L.; Clark, Denis E.; Smartt, Herschel B.

    1991-01-01

    Apparatus for gas-metal arc deposition of metal, metal alloys, and metal matrix composites. The apparatus contains an arc chamber for confining a D.C. electrical arc discharge, the arc chamber containing an outlet orifice in fluid communication with a deposition chamber having a deposition opening in alignment with the orifice for depositing metal droplets on a coatable substrate. Metal wire is passed continuously into the arc chamber in alignment with the orifice. Electric arcing between the metal wire anode and the orifice cathode produces droplets of molten metal from the wire which pass through the orifice and into the deposition chamber for coating a substrate exposed at the deposition opening. When producing metal matrix composites, a suspenion of particulates in an inert gas enters the deposition chamber via a plurality of feed openings below and around the orifice so that reinforcing particulates join the metal droplets to produce a uniform mixture which then coats the exposed substrate with a uniform metal matrix composite.

  20. Method for gas-metal arc deposition

    DOE Patents [OSTI]

    Buhrmaster, Carol L.; Clark, Denis E.; Smartt, Herschel B.

    1990-01-01

    Method and apparatus for gas-metal arc deposition of metal, metal alloys, and metal matrix composites. The apparatus contains an arc chamber for confining a D.C. electrical arc discharge, the arc chamber containing an outlet orifice in fluid communication with a deposition chamber having a deposition opening in alignment wiht the orifice for depositing metal droplets on a coatable substrate. Metal wire is passed continuously into the arc chamber in alignment with the orifice. Electric arcing between the metal wire anode and the orifice cathode produces droplets of molten metal from the wire which pass through the orifice and into the deposition chamber for coating a substrate exposed at the deposition opening. When producing metal matrix composites, a suspension of particulates in an inert gas enters the deposition chamber via a plurality of feed openings below and around the orifice so that reinforcing particulates join the metal droplets to produce a uniform mixture which then coats the exposed substrate with a uniform metal matrix composite.

  1. Method for gas-metal arc deposition

    DOE Patents [OSTI]

    Buhrmaster, C.L.; Clark, D.E.; Smartt, H.B.

    1990-11-13

    Method and apparatus for gas-metal arc deposition of metal, metal alloys, and metal matrix composites are disclosed. The apparatus contains an arc chamber for confining a D.C. electrical arc discharge, the arc chamber containing an outlet orifice in fluid communication with a deposition chamber having a deposition opening in alignment with the orifice for depositing metal droplets on a coatable substrate. Metal wire is passed continuously into the arc chamber in alignment with the orifice. Electric arcing between the metal wire anode and the orifice cathode produces droplets of molten metal from the wire which pass through the orifice and into the deposition chamber for coating a substrate exposed at the deposition opening. When producing metal matrix composites, a suspension of particulates in an inert gas enters the deposition chamber via a plurality of feed openings below and around the orifice so that reinforcing particulates join the metal droplets to produce a uniform mixture which then coats the exposed substrate with a uniform metal matrix composite. 1 fig.

  2. Metals 2000

    SciTech Connect (OSTI)

    Allison, S.W.; Rogers, L.C.; Slaughter, G.; Boensch, F.D.; Claus, R.O.; de Vries, M.

    1993-05-01

    This strategic planning exercise identified and characterized new and emerging advanced metallic technologies in the context of the drastic changes in global politics and decreasing fiscal resources. In consideration of a hierarchy of technology thrusts stated by various Department of Defense (DOD) spokesmen, and the need to find new and creative ways to acquire and organize programs within an evolving Wright Laboratory, five major candidate programs identified are: C-17 Flap, Transport Fuselage, Mach 5 Aircraft, 4.Fighter Structures, and 5. Missile Structures. These results were formed by extensive discussion with selected major contractors and other experts, and a survey of advanced metallic structure materials. Candidate structural applications with detailed metal structure descriptions bracket a wide variety of uses which warrant consideration for the suggested programs. An analysis on implementing smart skins and structures concepts is given from a metal structures perspective.

  3. Fluid injection microvalve

    DOE Patents [OSTI]

    Renzi, Ronald F.

    2005-11-22

    A microvalve for extracting small volume samples into analytical devices, e.g., high pressure liquid chromatography (HPLC) column, includes: a first body having a first interior surface and two or more outlet ports at the first interior surface that are in fluid communication with two or more first channels; a second body having a second interior surface and two or more inlet ports at the second interior surface that are in fluid communication with two or more second channels wherein the outlet ports of the first body are coaxial with the corresponding inlet ports of the second body such that there are at least two sets of coaxial port outlets and port inlets; a plate member, which has a substantially planar first mating surface and a substantially planar second mating surface, that is slidably positioned between the first interior surface and the second interior surface wherein the plate member has at least one aperture that traverses the height of the plate member, and wherein the aperture can be positioned to be coaxial with any of the at least two sets of coaxial port outlets and port inlets; and means for securing the first surface of the first body against the first mating surface and for securing the second surface of the second body against the second mating surface.

  4. Borehole Fluid Conductivity Model

    Energy Science and Technology Software Center (OSTI)

    2004-03-15

    Dynamic wellbore electrical conductivity logs provide a valuable means to determine the flow characteristics of fractures intersectin a wellbore, in order to study the hydrologic behavior of fractured rocks. To expedite the analysis of log data, a computer program called BORE II has been deveoloped that considers multiple inflow or outflow points along the wellbore, including the case of horizontal flow across the wellbore, BORE II calculates the evolution of fluid electrical conducivity (FEC) profilesmorein a wellbore or wellbore section, which may be pumped at a low rate, and compares model results to log data in a variety of ways. FEC variations may arise from inflow under natural-state conditions or due to tracer injected in a neighboring well (interference tests). BORE II has an interactive, graphical user interface and runs on a personal computer under the Windows operating system. BORE II is a modification and extension of older codes called BORE and BOREXT, which considered inflow points only. Finite difference solution of the one-dimensional advection-diffusion equation with explicit time stepping; feed points treated as prescribed-mass sources or sinks; assume quadratic relationship between fluid electrical conductivity and ion consentration. Graphical user interface; interactive modification of model parameters and graphical display of model results and filed data in a variety of ways. Can examine horizontal flow or arbitarily complicated combination of upflow, downflow, and horizontal flow. Feed point flow rate and/or concentration may vary in time.less

  5. Fluid lubricated bearing assembly

    DOE Patents [OSTI]

    Boorse, Henry A.; Boeker, Gilbert F.; Menke, John R.

    1976-01-01

    1. A support for a loaded rotatable shaft comprising in combination on a housing having a fluid-tight cavity encasing an end portion of said shaft, a thrust bearing near the open end of said cavity for supporting the axial thrust of said shaft, said thrust bearing comprising a thrust plate mounted in said housing and a thrust collar mounted on said shaft, said thrust plate having a central opening the peripheral portion of which is hermetically sealed to said housing at the open end of said cavity, and means for supplying a fluid lubricant to said thrust bearing, said thrust bearing having a lubricant-conducting path connecting said lubricant supplying means with the space between said thrust plate and collar intermediate the peripheries thereof, the surfaces of said plate and collar being constructed and arranged to inhibit radial flow of lubricant and, on rotation of said thrust collar, to draw lubricant through said path between the bearing surfaces and to increase the pressure therebetween and in said cavity and thereby exert a supporting force on said end portion of said shaft.

  6. Metal Hydrides

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Metal Hydrides Theodore Motyka Savannah River National Laboratory Metal Hydride System Architect Jose-Miguel Pasini, & Bart van Hassel UTRC Claudio Corgnale & Bruce Hardy SRNL Kevin Simmons and Mark Weimar PNNL Darsh Kumar GM, Matthew Thornton NREL, Kevin Drost OSU DOE Materials-Based Hydrogen Storage Summit Defining Pathways for Onboard Automotive Applications 2 Outline * Background and MH History * MH HSECoE Results * Material Operating Requirements * Modeling and Analyses * BOP and

  7. Trace element and isotope geochemistry of geothermal fluids, East Rift Zone, Kilauea, Hawaii

    SciTech Connect (OSTI)

    West, H.B.; Delanoy, G.A.; Thomas, D.M. . Hawaii Inst. of Geophysics); Gerlach, D.C. ); Chen, B.; Takahashi, P.; Thomas, D.M. Evans and Associates, Redwood City, CA )

    1992-01-01

    A research program has been undertaken in an effort to better characterize the composition and the precipitation characteristic of the geothermal fluids produced by the HGP-A geothermal well located on the Kilauea East Rift Zone on the Island of Hawaii. The results of these studies have shown that the chemical composition of the fluids changed over the production life of the well and that the fluids produced were the result of mixing of at least two, and possibly three, source fluids. These source fluids were recognized as: a sea water composition modified by high temperature water-rock reactions; meteoric recharge; and a hydrothermal fluid that had been equilibrated with high temperature reservoir rocks and magmatic volatiles. Although the major alkali and halide elements show clearly increasing trends with time, only a few of the trace transition metals show a similar trend. The rare earth elements, were typically found at low concentrations and appeared to be highly variable with time. Studies of the precipitation characteristics of silica showed that amorphous silica deposition rates were highly sensitive to fluid pH and that increases in fluid pH above about 8.5 could flocculate more than 80% of the suspended colloidal silica in excess of its solubility. Addition of transition metal salts were also found to enhance the recovery fractions of silica from solution. The amorphous silica precipitate was also found to strongly scavenge the alkaline earth and transition metal ions naturally present in the brines; mild acid treatments were shown to be capable of removing substantial fractions of the scavenged metals from the silica flocs yielding a moderately pure gelatinous by-product. Further work on the silica precipitation process is recommended to improve our ability to control silica scaling from high temperature geothermal fluids or to recover a marketable silica by-product from these fluids prior to reinjection.

  8. Use of a polishing scrubber with a fluid bed boiler

    SciTech Connect (OSTI)

    Toher, J.G.

    1996-12-31

    Once viewed as {open_quotes}competitive{close_quotes} technologies, the circulating dry scrubber (CDS){reg_sign} and circulating fluid bed (CFB) boiler are being used together to achieve enhanced performance with lower overall costs. The need to understand the synergy between these two technologies is driven by deregulation of the power industry and the 1990 Clean Air Act Amendments. Deregulation of power production in the US has spurred the growth of Independent Power Producers (IPP) who are responding to Industry`s demand for lower cost fuels, and close attention to annual operating costs. Utilities have to provide {open_quotes}open{close_quotes} access to their transmission lines allowing various IPP`s to connect with the end user. Industrial users can now choose from one of several sources of electricity with prices per kilowatt hour that are much lower than what they are currently being charged. The race is on to reduce power production costs and fuel can be the key in many cases. IPP`s and industry are banding together in very logical ways that can benefit both. Industry`s byproducts with heating value can be sold {open_quotes}over the fence{close_quotes} to an IPP who provides the industry with low cost steam and or electricity in return. However, many alternative lower cost fuels also have a higher emissions potential for criteria pollutants such a SO{sub 2}, NO{sub X}, particulate, or other emissions such as VOC`s and mercury which are more recently receiving attention. Cost effective management of these environmental issues must be an integral part of the project planning process. Three such cases are examined that involve the use of CFB`s with the CDS{reg_sign} as a polishing scrubber for SO{sub 2}. The first two cases involve repowering of existing facilities with petroleum coke as the fuel. The last case involves a new facility powered with low sulfur coal.

  9. Dendritic metal nanostructures

    DOE Patents [OSTI]

    Shelnutt, John A.; Song, Yujiang; Pereira, Eulalia F.; Medforth, Craig J.

    2010-08-31

    Dendritic metal nanostructures made using a surfactant structure template, a metal salt, and electron donor species.

  10. Liquid metal cooling of synchrotron optics

    SciTech Connect (OSTI)

    Smither, R.K.

    1992-09-01

    The installation of insertion devices at existing synchrotron facilities around the world has stimulated the development of new ways to cool the optical elements in the associated x-ray beamlines. Argonne has been a leader in the development of liquid metal cooling for high heat load x-ray optics for the next generation of synchrotron facilities. The high thermal conductivity, high volume specific heat, low kinematic viscosity, and large working temperature range make liquid metals a very efficient heat transfer fluid. A wide range of liquid metals were considered in the initial phase of this work. The most promising liquid metal cooling fluid identified to date is liquid gallium, which appears to have all the desired properties and the fewest number of undesired features of the liquid metals examined. Besides the special features of liquid metals that make them good heat transfer fluids, the very low vapor pressure over a large working temperature range make liquid gallium an ideal cooling fluid for use in a high vacuum environment. A leak of the liquid gallium into the high vacuum and even into very high vacuum areas will not result in any detectable vapor pressure and may even improve the vacuum environment as the liquid gallium combines with any water vapor or oxygen present in the system. The practical use of a liquid metal for cooling silicon crystals and other high heat load applications depends on having a convenient and efficient delivery system. The requirements for a typical cooling system for a silicon crystal used in a monochromator are pumping speeds of 2 to 5 gpm (120 cc per sec to 600 cc per sec) at pressures up to 100 psi.

  11. Electromagnetic augmentation for casting of thin metal sheets

    DOE Patents [OSTI]

    Hull, J.R.

    1987-10-28

    Thin metal sheets are cast by magnetically levitating molten metal deposited in a model within a ferromagnetic yoke and between AC conducting coils and linearly displacing the magnetically levitated liquid metal while it is being cooled by the water-cooled walls of the mold to form a solid metal sheet. A conducting shield is electrically coupled to the molten metal sheet to provide a return path for eddy currents induced in the metal sheet by the current in the AC conducting coils. In another embodiment, a DC conducting coil is coupled to the metal sheet for providing a direct current therein which interacts with the magnetic field to levitate the moving metal sheet. Levitation of the metal sheet in both molten and solid forms reduces its contact pressure with the mold walls while maintaining sufficient engagement therebetween to permit efficient conductive cooling by the mold through which a coolant fluid may be circulated. 8 figs.

  12. Ultrasonic fluid quality sensor system

    DOE Patents [OSTI]

    Gomm, Tyler J.; Kraft, Nancy C.; Phelps, Larry D.; Taylor, Steven C.

    2002-10-08

    A system for determining the composition of a multiple-component fluid and for determining linear flow comprising at least one sing-around circuit that determines the velocity of a signal in the multiple-component fluid and that is correlatable to a database for the multiple-component fluid. A system for determining flow uses two of the inventive circuits, one of which is set at an angle that is not perpendicular to the direction of flow.

  13. Ultrasonic Fluid Quality Sensor System

    DOE Patents [OSTI]

    Gomm, Tyler J.; Kraft, Nancy C.; Phelps, Larry D.; Taylor, Steven C.

    2003-10-21

    A system for determining the composition of a multiple-component fluid and for determining linear flow comprising at least one sing-around circuit that determines the velocity of a signal in the multiple-component fluid and that is correlatable to a database for the multiple-component fluid. A system for determining flow uses two of the inventive circuits, one of which is set at an angle that is not perpendicular to the direction of flow.

  14. FLUID CONTACTOR APPARATUS

    DOE Patents [OSTI]

    Spence, R.; Streeton, R.J.W.

    1956-04-17

    The fluid contactor apparatus comprises a cylindrical column mounted co- axially and adapted to rotate within a cylindrical vessel, for the purpose of extracting a solute from am aqueous solution by means of an organic solvent. The column is particularly designed to control the vortex pattern so as to reduce the height of the vortices while, at the same time, the width of the annular radius in the radial direction between the vessel and column is less than half the radius of the column. A plurality of thin annular fins are spaced apart along the rotor approximately twice the radial dimension of the column such that two contrarotating substantially circular vortices are contained within each pair of fins as the column is rotated.

  15. Supercritical fluid reverse micelle systems

    DOE Patents [OSTI]

    Fulton, John L.; Smith, Richard D.

    1992-01-01

    of 1 ) United States Patent 5,158,704 Fulton ,   et al. October 27, 1992 Supercritical fluid reverse micelle systems

  16. Fluid relief and check valve

    DOE Patents [OSTI]

    Blaedel, K.L.; Lord, S.C.; Murray, I.

    1986-07-17

    A passive fluid pressure relief and check valve allows the relief pressure to be slaved to a reference pressure independently of the exhaust pressure. The pressure relief valve is embodied by a submerged vent line in a sealing fluid, the relief pressure being a function of the submerged depth. A check valve is embodied by a vertical column of fluid (the maximum back pressure being a function of the height of the column of fluid). The pressure is vented into an exhaust system which keeps the exhaust out of the area providing the reference pressure.

  17. In vitro dissolution of metal tritides

    SciTech Connect (OSTI)

    Cheng, Yung-Sung; Jow, Hong-Nian; Dahl, A.R.

    1994-11-01

    Metal tritides including titanium, zirconium, and erbium tritide have been used as components of neutron generators. These compounds can be released to the air as aerosols during fabrication, assembling, and testing of components or in accidental or fugitive releases, and as a result, workers may inhale them. Our understanding of metal tritides and their radiation dosimetry for internal exposure is very limited. Current radiation protection guidelines for metal tritide particles are based on the assumption that their biological behavior is similar to tritiated water which could be easily absorbed into body fluid, and, therefore, has a relatively short biological half-life (10 d). However, a few papers in the literature suggest that the solubility of metal tritide could be low. If this is true, the biological half-life of metal tritide particles and the dosimetry of inhalation exposure to these particles could be quite different from tritiated water, and this would have significant implications in the current health protection guidelines. The purpose of this study was to investigate the dissolution behavior of metal tritide particles in simulated biological fluids and in rats. Data from these studies will provide information with which to estimate the dosimetry of inhaled metal tritides. A dosimetric model can then be used as the technical basis for setting health protection limits, including annual limits on intake and derived air concentrations for DOE facilities.

  18. Metal hydrides

    SciTech Connect (OSTI)

    Carnes, J.R.; Kherani, N.P.

    1987-11-01

    Metal hydride information is not available for most hydrides in a consolidated quick-reference source. This report's objective is to fill the need for such a document providing basic thermodynamic data for as many metal hydrides as possible. We conduced a computerized library search to access as many sources as possible and screened each source for such thermodynamic data as pressure-temperature graphs, van't Hoff curves, and impurity effects. We included any other relevant information and commented on it. A primary concern to be investigated in the future is the behavior of metal tritides. This would be important in the area of emergency tritium cleanup systems. The hydride graphs are useful, however, as tritides may be expected in most cases to behave similarly and at least follow trends of their respective hydrides. 42 refs., 40 figs., 5 tabs.

  19. Two-fluid Hydrodynamic Model for Fluid-Flow Simulation in Fluid-Solids Systems

    Energy Science and Technology Software Center (OSTI)

    1994-06-20

    FLUFIX is a two-dimensional , transient, Eulerian, and finite-difference program, based on a two-fluid hydrodynamic model, for fluid flow simulation in fluid-solids systems. The software is written in a modular form using the Implicit Multi-Field (IMF) numerical technique. Quantities computed are the spatial distribution of solids loading, gas and solids velocities, pressure, and temperatures. Predicted are bubble formation, bed frequencies, and solids recirculation. Applications include bubbling and circulating atmospheric and pressurized fluidized bed reactors, combustors,more » gasifiers, and FCC (Fluid Catalytic Cracker) reactors.« less

  20. Corrosion of materials in absorption heating and refrigeration fluids

    SciTech Connect (OSTI)

    Griess, J.C.; DeVan, J.H.; Perez Blanco, H.

    1985-06-01

    The corrosion of metals and alloys in absorption refrigeration fluids has received little attention except for the behavior of steel and copper alloys in aqueous lithium bromide solutions. This report presents results of short-term corrosion tests on several materials in lithium bromide solutions as well as in other fluids of potential interest in advanced absorption machines. All materials tested had extremely high resistance to organic fluids, but in the aqueous systems some of the materials underwent localized attack. Type 304 stainless steel had acceptable corrosion resistance in most environments, but it underwent stress corrosion cracking in oxygen- or chromate-containing lithium bromide and even in the unstressed condition was subject to intergranular attack in hot concentrated caustic solutions. 10 refs., 2 figs., 4 tabs.

  1. Fluid jet electric discharge source

    DOE Patents [OSTI]

    Bender, Howard A.

    2006-04-25

    A fluid jet or filament source and a pair of coaxial high voltage electrodes, in combination, comprise an electrical discharge system to produce radiation and, in particular, EUV radiation. The fluid jet source is composed of at least two serially connected reservoirs, a first reservoir into which a fluid, that can be either a liquid or a gas, can be fed at some pressure higher than atmospheric and a second reservoir maintained at a lower pressure than the first. The fluid is allowed to expand through an aperture into a high vacuum region between a pair of coaxial electrodes. This second expansion produces a narrow well-directed fluid jet whose size is dependent on the size and configuration of the apertures and the pressure used in the reservoir. At some time during the flow of the fluid filament, a high voltage pulse is applied to the electrodes to excite the fluid to form a plasma which provides the desired radiation; the wavelength of the radiation being determined by the composition of the fluid.

  2. Effective perfect fluids in cosmology

    SciTech Connect (OSTI)

    Ballesteros, Guillermo; Bellazzini, Brando E-mail: brando.bellazzini@pd.infn.it

    2013-04-01

    We describe the cosmological dynamics of perfect fluids within the framework of effective field theories. The effective action is a derivative expansion whose terms are selected by the symmetry requirements on the relevant long-distance degrees of freedom, which are identified with comoving coordinates. The perfect fluid is defined by requiring invariance of the action under internal volume-preserving diffeomorphisms and general covariance. At lowest order in derivatives, the dynamics is encoded in a single function of the entropy density that characterizes the properties of the fluid, such as the equation of state and the speed of sound. This framework allows a neat simultaneous description of fluid and metric perturbations. Longitudinal fluid perturbations are closely related to the adiabatic modes, while the transverse modes mix with vector metric perturbations as a consequence of vorticity conservation. This formalism features a large flexibility which can be of practical use for higher order perturbation theory and cosmological parameter estimation.

  3. Acoustic sand detector for fluid flowstreams

    DOE Patents [OSTI]

    Beattie, Alan G. (Corrales, NM); Bohon, W. Mark (Frisco, TX)

    1993-01-01

    The particle volume and particle mass production rate of particulate solids entrained in fluid flowstreams such as formation sand or fracture proppant entrained in oil and gas production flowstreams is determined by a system having a metal probe interposed in a flow conduit for transmitting acoustic emissions created by particles impacting the probe to a sensor and signal processing circuit which produces discrete signals related to the impact of each of the particles striking the probe. The volume or mass flow rate of particulates is determined from making an initial particle size distribution and particle energy distribution and comparing the initial energy distribution and/or the initial size distribution with values related to the impact energies of a predetermined number of recorded impacts. The comparison is also used to recalibrate the system to compensate for changes in flow velocity.

  4. METAL COMPOSITIONS

    DOE Patents [OSTI]

    Seybolt, A.U.

    1959-02-01

    Alloys of uranium which are strong, hard, and machinable are presented, These alloys of uranium contain bctween 0.1 to 5.0% by weight of at least one noble metal such as rhodium, palladium, and gold. The alloys may be heat treated to obtain a product with iniproved tensile and compression strengths,

  5. Fluid flow monitoring device

    DOE Patents [OSTI]

    McKay, M.D.; Sweeney, C.E.; Spangler, B.S. Jr.

    1993-11-30

    A flow meter and temperature measuring device are described comprising a tube with a body centered therein for restricting flow and a sleeve at the upper end of the tube to carry several channels formed longitudinally in the sleeve to the appropriate axial location where they penetrate the tube to allow pressure measurements and temperature measurements with thermocouples. The high pressure measurement is made using a channel penetrating the tube away from the body and the low pressure measurement is made at a location at the widest part of the body. An end plug seals the end of the device and holes at its upper end allow fluid to pass from the interior of the tube into a plenum. The channels are made by cutting grooves in the sleeve, the grooves widened at the surface of the sleeve and then a strip of sleeve material is welded to the grooves closing the channels. Preferably the sleeve is packed with powdered graphite before cutting the grooves and welding the strips. 7 figures.

  6. Fluid sampling system

    DOE Patents [OSTI]

    Houck, Edward D.

    1994-01-01

    An fluid sampling system allows sampling of radioactive liquid without spillage. A feed tank is connected to a liquid transfer jet powered by a pumping chamber pressurized by compressed air. The liquid is pumped upwardly into a sampling jet of a venturi design having a lumen with an inlet, an outlet, a constricted middle portion, and a port located above the constricted middle portion. The liquid is passed under pressure through the constricted portion causing its velocity to increase and its pressure to decreased, thereby preventing liquid from escaping. A septum sealing the port can be pierced by a two pointed hollow needle leading into a sample bottle also sealed by a pierceable septum affixed to one end. The bottle is evacuated by flow through the sample jet, cyclic variation in the sampler jet pressure periodically leaves the evacuated bottle with lower pressure than that of the port, thus causing solution to pass into the bottle. The remaining solution in the system is returned to the feed tank via a holding tank.

  7. Fluid sampling system

    DOE Patents [OSTI]

    Houck, E.D.

    1994-10-11

    An fluid sampling system allows sampling of radioactive liquid without spillage. A feed tank is connected to a liquid transfer jet powered by a pumping chamber pressurized by compressed air. The liquid is pumped upwardly into a sampling jet of a venturi design having a lumen with an inlet, an outlet, a constricted middle portion, and a port located above the constricted middle portion. The liquid is passed under pressure through the constricted portion causing its velocity to increase and its pressure to be decreased, thereby preventing liquid from escaping. A septum sealing the port can be pierced by a two pointed hollow needle leading into a sample bottle also sealed by a pierceable septum affixed to one end. The bottle is evacuated by flow through the sample jet, cyclic variation in the sampler jet pressure periodically leaves the evacuated bottle with lower pressure than that of the port, thus causing solution to pass into the bottle. The remaining solution in the system is returned to the feed tank via a holding tank. 4 figs.

  8. Incompressible Viscous Fluid Dynamics

    Energy Science and Technology Software Center (OSTI)

    1992-02-13

    NACHOS2 is a finite element program designed for the analysis of two-dimensional, incompressible viscous fluid flow problems. The basic flows considered may be isothermal, nonisothermal, or may involve other physical processes, such as mass transport. Both steady and transient flows may be analyzed. The class of problems treated are those described by the two-dimensional (plane or axisymmetric) incompressible form of the Navier-Stokes equations. An energy transport equation is included in the formulation for problems inmore » which heat transfer effects are important. Two auxiliary transport equations can be added to describe other physical processes,e.g. mass transfer, chemical reactions. Among the specific types of flow problems treated are: isothermal flow; forced, free, or mixed convection; conjugate heat transfer; flow in saturated porous media with or without heat transfer; and inelastic, non-Newtonian flows with or without heat transfer. Other problem classes are possible depending on the specific definitions applied to the auxiliary transport equations.« less

  9. Incompressible Viscous Fluid Dynamics

    Energy Science and Technology Software Center (OSTI)

    1992-02-13

    NACHOS2 is a finite element program designed for the analysis of two-dimensional, incompressible viscous fluid flow problems. The basic flows considered may be isothermal, nonisothermal, or may involve other physical processes, such as mass transport. Both steady and transient flows may be analyzed. The class of problems treated are those described by the two-dimensional (plane or axisymmetric) incompressible form of the Navier-Stokes equations. An energy transport equation is included in the formulation for problems inmore »which heat transfer effects are important. Two auxiliary transport equations can be added to describe other physical processes,e.g. mass transfer, chemical reactions. Among the specific types of flow problems treated are: isothermal flow; forced, free, or mixed convection; conjugate heat transfer; flow in saturated porous media with or without heat transfer; and inelastic, non-Newtonian flows with or without heat transfer. Other problem classes are possible depending on the specific definitions applied to the auxiliary transport equations.« less

  10. Fluid flow monitoring device

    DOE Patents [OSTI]

    McKay, Mark D.; Sweeney, Chad E.; Spangler, Jr., B. Samuel

    1993-01-01

    A flow meter and temperature measuring device comprising a tube with a body centered therein for restricting flow and a sleeve at the upper end of the tube to carry several channels formed longitudinally in the sleeve to the appropriate axial location where they penetrate the tube to allow pressure measurements and temperature measurements with thermocouples. The high pressure measurement is made using a channel penetrating the tube away from the body and the low pressure measurement is made at a location at the widest part of the body. An end plug seals the end of the device and holes at its upper end allow fluid to pass from the interior of the tube into a plenum. The channels are made by cutting grooves in the sleeve, the grooves widened at the surface of the sleeve and then a strip of sleeve material is welded to the grooves closing the channels. Preferably the sleeve is packed with powdered graphite before cutting the grooves and welding the strips.

  11. Computational Fluid Dynamics Library

    Energy Science and Technology Software Center (OSTI)

    2005-03-04

    CFDLib05 is the Los Alamos Computational Fluid Dynamics LIBrary. This is a collection of hydrocodes using a common data structure and a common numerical method, for problems ranging from single-field, incompressible flow, to multi-species, multi-field, compressible flow. The data structure is multi-block, with a so-called structured grid in each block. The numerical method is a Finite-Volume scheme employing a state vector that is fully cell-centered. This means that the integral form of the conservation lawsmore » is solved on the physical domain that is represented by a mesh of control volumes. The typical control volume is an arbitrary quadrilateral in 2D and an arbitrary hexahedron in 3D. The Finite-Volume scheme is for time-unsteady flow and remains well coupled by means of time and space centered fluxes; if a steady state solution is required, the problem is integrated forward in time until the user is satisfied that the state is stationary.« less

  12. Composite metal membrane

    DOE Patents [OSTI]

    Peachey, Nathaniel M.; Dye, Robert C.; Snow, Ronny C.; Birdsell, Stephan A.

    1998-01-01

    A composite metal membrane including a first metal layer of Group IVB met or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof is provided together with a process for the recovery of hydrogen from a gaseous mixture including contacting a hydrogen-containing gaseous mixture with a first side of a nonporous composite metal membrane including a first metal of Group IVB metals or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof, and, separating hydrogen from a second side of the nonporous composite metal membrane.

  13. Composite metal membrane

    DOE Patents [OSTI]

    Peachey, N.M.; Dye, R.C.; Snow, R.C.; Birdsell, S.A.

    1998-04-14

    A composite metal membrane including a first metal layer of Group IVB met or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof is provided together with a process for the recovery of hydrogen from a gaseous mixture including contacting a hydrogen-containing gaseous mixture with a first side of a nonporous composite metal membrane including a first metal of Group IVB metals or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof, and, separating hydrogen from a second side of the nonporous composite metal membrane.

  14. Fluid Flow Phenomena during Welding

    SciTech Connect (OSTI)

    Zhang, Wei

    2011-01-01

    MOLTEN WELD POOLS are dynamic. Liquid in the weld pool in acted on by several strong forces, which can result in high-velocity fluid motion. Fluid flow velocities exceeding 1 m/s (3.3 ft/s) have been observed in gas tungsten arc (GTA) welds under ordinary welding conditions, and higher velocities have been measured in submerged arc welds. Fluid flow is important because it affects weld shape and is related to the formation of a variety of weld defects. Moving liquid transports heat and often dominates heat transport in the weld pool. Because heat transport by mass flow depends on the direction and speed of fluid motion, weld pool shape can differ dramatically from that predicted by conductive heat flow. Temperature gradients are also altered by fluid flow, which can affect weld microstructure. A number of defects in GTA welds have been attributed to fluid flow or changes in fluid flow, including lack of penetration, top bead roughness, humped beads, finger penetration, and undercutting. Instabilities in the liquid film around the keyhole in electron beam and laser welds are responsible for the uneven penetration (spiking) characteristic of these types of welds.

  15. High-density fluid compositions

    SciTech Connect (OSTI)

    Sanders, D.C.

    1981-09-29

    Clear, high-density fluids suitable for use as well completion, packing, and perforation media comprise aqueous solutions of zinc bromide and calcium bromide having densities lying in the range of about 14.5 up to about 18.0 pounds per gallon and measured PH's lying in the range of about 3.5 up to about 6.0. Optionally, such fluids may also comprise calcium chloride and/or a soluble film-forming amine-based corrosion inhibitor. Such fluids under conditions of ordinary use exhibit low corrosion rates and have crystallization points lying well below the range of temperatures under which they are used.

  16. Particle sorter comprising a fluid displacer in a closed-loop fluid circuit

    DOE Patents [OSTI]

    Perroud, Thomas D.; Patel, Kamlesh D.; Renzi, Ronald F.

    2012-04-24

    Disclosed herein are methods and devices utilizing a fluid displacer in a closed-loop fluid circuit.

  17. Fluid-filled bomb-disrupting apparatus and method

    DOE Patents [OSTI]

    Cherry, Christopher R.

    2001-01-01

    An apparatus and method for disarming improvised bombs are disclosed. The apparatus comprises a fluid-filled bottle or container made of plastic or another soft material which contains a fixed or adjustable, preferably sheet explosive. The charge is fired centrally at its apex and can be adjusted to propel a fluid projectile that is broad or narrow, depending upon how it is set up. In one embodiment, the sheet explosive is adjustable so as to correlate the performance of the fluid projectile to the disarming needs for the improvised explosive device (IED). Common materials such as plastic water bottles or larger containers can be used, with the sheet explosive or other explosive material configured in a general chevron-shape to target the projectile toward the target. In another embodiment, a thin disk of metal is conformably mounted with the exterior of the container and radially aligned with the direction of fire of the fluid projectile. Depending on the configuration and the amount of explosive and fluid used, a projectile is fired at the target that has sufficient energy to penetrate rigid enclosures from fairly long stand-off and yet is focused enough to be targeted to specific portions of the IED for disablement.

  18. Standardization of Thermo-Fluid Modeling in Modelica.Fluid

    SciTech Connect (OSTI)

    Franke, Rudiger; Casella, Francesco; Sielemann, Michael; Proelss, Katrin; Otter, Martin; Wetter, Michael

    2009-09-01

    This article discusses the Modelica.Fluid library that has been included in the Modelica Standard Library 3.1. Modelica.Fluid provides interfaces and basic components for the device-oriented modeling of onedimensional thermo-fluid flow in networks containing vessels, pipes, fluid machines, valves and fittings. A unique feature of Modelica.Fluid is that the component equations and the media models as well as pressure loss and heat transfer correlations are decoupled from each other. All components are implemented such that they can be used for media from the Modelica.Media library. This means that an incompressible or compressible medium, a single or a multiple substance medium with one or more phases might be used with one and the same model as long as the modeling assumptions made hold. Furthermore, trace substances are supported. Modeling assumptions can be configured globally in an outer System object. This covers in particular the initialization, uni- or bi-directional flow, and dynamic or steady-state formulation of mass, energy, and momentum balance. All assumptions can be locally refined for every component. While Modelica.Fluid contains a reasonable set of component models, the goal of the library is not to provide a comprehensive set of models, but rather to provide interfaces and best practices for the treatment of issues such as connector design and implementation of energy, mass and momentum balances. Applications from various domains are presented.

  19. State-of-the-art review of computational fluid dynamics modeling for fluid-solids systems

    SciTech Connect (OSTI)

    Lyczkowski, R.W.; Bouillard, J.X.; Ding, J.; Chang, S.L.; Burge, S.W.

    1994-05-12

    As the result of 15 years of research (50 staff years of effort) Argonne National Laboratory (ANL), through its involvement in fluidized-bed combustion, magnetohydrodynamics, and a variety of environmental programs, has produced extensive computational fluid dynamics (CFD) software and models to predict the multiphase hydrodynamic and reactive behavior of fluid-solids motions and interactions in complex fluidized-bed reactors (FBRS) and slurry systems. This has resulted in the FLUFIX, IRF, and SLUFIX computer programs. These programs are based on fluid-solids hydrodynamic models and can predict information important to the designer of atmospheric or pressurized bubbling and circulating FBR, fluid catalytic cracking (FCC) and slurry units to guarantee optimum efficiency with minimum release of pollutants into the environment. This latter issue will become of paramount importance with the enactment of the Clean Air Act Amendment (CAAA) of 1995. Solids motion is also the key to understanding erosion processes. Erosion rates in FBRs and pneumatic and slurry components are computed by ANL`s EROSION code to predict the potential metal wastage of FBR walls, intervals, feed distributors, and cyclones. Only the FLUFIX and IRF codes will be reviewed in the paper together with highlights of the validations because of length limitations. It is envisioned that one day, these codes with user-friendly pre and post-processor software and tailored for massively parallel multiprocessor shared memory computational platforms will be used by industry and researchers to assist in reducing and/or eliminating the environmental and economic barriers which limit full consideration of coal, shale and biomass as energy sources, to retain energy security, and to remediate waste and ecological problems.

  20. The handbook of fluid dynamics

    SciTech Connect (OSTI)

    Johnson, R.W.

    1998-07-01

    This book provides professionals in the field of fluid dynamics with a comprehensive guide and resource. The book balances three traditional areas of fluid mechanics--theoretical, computational, and experimental--and expounds on basic science and engineering techniques. Each chapter introduces a topic, discusses the primary issues related to this subject, outlines approaches taken by experts, and supplies references for further information. Topics discussed include: (1) basic engineering fluid dynamics; (2) classical fluid dynamics; (3) turbulence modeling; (4) reacting flows; (5) multiphase flows; (6) flow and porous media; (7) high Reynolds number asymptotic theories; (8) finite difference method; (9) finite volume method; (10) finite element methods; (11) spectral element methods for incompressible flows; (12) experimental methods, such as hot-wire anemometry, laser-Doppler velocimetry, and flow visualization; and (13) applications, such as axial-flow compressor and fan aerodynamics, turbomachinery, airfoils and wings, atmospheric flows, and mesoscale oceanic flows.

  1. Fluid Dynamics with Free Surfaces

    Energy Science and Technology Software Center (OSTI)

    1992-02-01

    RIPPLE is a two-dimensional, transient, free surface incompressible fluid dynamics program. It allows multiple free surfaces with surface tension and wall adhesion forces and has a partial cell treatment which allows curved boundaries and interior obstacles.

  2. Fluid Inclusion Analysis | Open Energy Information

    Open Energy Info (EERE)

    Geothermal Area (2004) Coso Geothermal Area 2004 2004 GEOTHERMAL FLUID PROPENE AND PROPANE: INDICATORS OF FLUID GEOLOGY AND MINERAL PARAGENESIS STUDY WITHIN THE COSO-EGS...

  3. Variable flexure-based fluid filter

    DOE Patents [OSTI]

    Brown, Steve B.; Colston, Jr., Billy W.; Marshall, Graham; Wolcott, Duane

    2007-03-13

    An apparatus and method for filtering particles from a fluid comprises a fluid inlet, a fluid outlet, a variable size passage between the fluid inlet and the fluid outlet, and means for adjusting the size of the variable size passage for filtering the particles from the fluid. An inlet fluid flow stream is introduced to a fixture with a variable size passage. The size of the variable size passage is set so that the fluid passes through the variable size passage but the particles do not pass through the variable size passage.

  4. Nonequilibrium molecular dynamics simulations of confined fluids...

    Office of Scientific and Technical Information (OSTI)

    A nonequilibrium molecular dynamics (MD) ... in a single simulation upon compression, whereas fluid molecules in the bulk ... for weak fluid -- wall interactions. ...

  5. Insertable fluid flow passage bridgepiece and method

    DOE Patents [OSTI]

    Jones, Daniel O.

    2000-01-01

    A fluid flow passage bridgepiece for insertion into an open-face fluid flow channel of a fluid flow plate is provided. The bridgepiece provides a sealed passage from a columnar fluid flow manifold to the flow channel, thereby preventing undesirable leakage into and out of the columnar fluid flow manifold. When deployed in the various fluid flow plates that are used in a Proton Exchange Membrane (PEM) fuel cell, bridgepieces of this invention prevent mixing of reactant gases, leakage of coolant or humidification water, and occlusion of the fluid flow channel by gasket material. The invention also provides a fluid flow plate assembly including an insertable bridgepiece, a fluid flow plate adapted for use with an insertable bridgepiece, and a method of manufacturing a fluid flow plate with an insertable fluid flow passage bridgepiece.

  6. DOE MURI: Hig-Operating Temperature Heat Transfer Fluids for CSD

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applications | Department of Energy DOE MURI: Hig-Operating Temperature Heat Transfer Fluids for CSD Applications DOE MURI: Hig-Operating Temperature Heat Transfer Fluids for CSD Applications This presentation was delivered at the SunShot Concentrating Solar Power (CSP) Program Review 2013, held April 23-25, 2013 near Phoenix, Arizona. csp_review_meeting_042513_ju.pdf (3.41 MB) More Documents & Publications High Operating Temperature Liquid Metal Heat Transfer Fluids - FY13 Q2 High

  7. Metal dusting

    SciTech Connect (OSTI)

    Edited by K. Natesan

    2004-01-01

    This workshop was held soon after the September 11th incident under a climate of sorrow and uncertainty among the people of the world, in particular the Workshop participants and their host organizations. With considerable help from the partiicpants, the Workshop was conducted as planed and we had excellent participation in spite of the circumstances. A good fraction of the attendees in the Workshop were from abroad and from several industries, indicating the importance and relevance of the subject for the chemical process industry. Degradation of structural metallic alloys by metal dusting has been an issue for over 40 years in the chemical, petrochemical, syngas, and iron ore reduction plants. However, the fundamental scientific reasons for the degradation of complex alloys in high carbon activity environments are not clear. one of the major parameters of importance is the variation in gas chemistry in both the laboratory experiments and in the plant-service environments. the industry has questioned the applicability of the laboratory test data, obtained in low steam environments, in assessment and life prediction for the materials in plant service where the environments contain 25-35% steam. Several other variables such as system pressure, gas flow velocity, incubation time, alloy chemistry, surface finish, and weldments, were also identified in the literature as to having an effect on the initiatino and propagation of metal dusting attack. It is the purpose of this Workshop to establish a forum in which the researchers from scientific and industrial laboratories, alloy manufacturers, end users, and research and development sponsors can exchange information, discuss different points of view, prioritize the issues, and to elaborate on the trends in industry for the future. We believe that we accomplished these goals successfully and sincerely thank the participants for their contributions.

  8. Computer modeling of electromagnetic fields and fluid flows for edge containment in continuous casting

    SciTech Connect (OSTI)

    Chang, F.C.; Hull, J.R.; Wang, Y.H.; Blazek, K.E.

    1996-02-01

    A computer model was developed to predict eddy currents and fluid flows in molten steel. The model was verified by comparing predictions with experimental results of liquid-metal containment and fluid flow in electromagnetic (EM) edge dams (EMDs) designed at Inland Steel for twin-roll casting. The model can optimize the EMD design so it is suitable for application, and minimize expensive, time-consuming full-scale testing. Numerical simulation was performed by coupling a three-dimensional (3-D) finite-element EM code (ELEKTRA) and a 3-D finite-difference fluids code (CaPS-EM) to solve heat transfer, fluid flow, and turbulence transport in a casting process that involves EM fields. ELEKTRA is able to predict the eddy- current distribution and the electromagnetic forces in complex geometries. CaPS-EM is capable of modeling fluid flows with free surfaces. Results of the numerical simulation compared well with measurements obtained from a static test.

  9. Polymers for metal extractions in carbon dioxide

    DOE Patents [OSTI]

    DeSimone, Joseph M.; Tumas, William; Powell, Kimberly R.; McCleskey, T. Mark; Romack, Timothy J.; McClain, James B.; Birnbaum, Eva R.

    2001-01-01

    A composition useful for the extraction of metals and metalloids comprises (a) carbon dioxide fluid (preferably liquid or supercritical carbon dioxide); and (b) a polymer in the carbon dioxide, the polymer having bound thereto a ligand that binds the metal or metalloid; with the ligand bound to the polymer at a plurality of locations along the chain length thereof (i.e., a plurality of ligands are bound at a plurality of locations along the chain length of the polymer). The polymer is preferably a copolymer, and the polymer is preferably a fluoropolymer such as a fluoroacrylate polymer. The extraction method comprises the steps of contacting a first composition containing a metal or metalloid to be extracted with a second composition, the second composition being as described above; and then extracting the metal or metalloid from the first composition into the second composition.

  10. Composite metal foil and ceramic fabric materials

    DOE Patents [OSTI]

    Webb, Brent J.; Antoniak, Zen I.; Prater, John T.; DeSteese, John G.

    1992-01-01

    The invention comprises new materials useful in a wide variety of terrestrial and space applications. In one aspect, the invention comprises a flexible cloth-like material comprising a layer of flexible woven ceramic fabric bonded with a layer of metallic foil. In another aspect, the invention includes a flexible fluid impermeable barrier comprising a flexible woven ceramic fabric layer having metal wire woven therein. A metallic foil layer is incontinuously welded to the woven metal wire. In yet another aspect, the invention includes a material comprising a layer of flexible woven ceramic fabric bonded with a layer of an organic polymer. In still another aspect, the invention includes a rigid fabric structure comprising a flexible woven ceramic fabric and a resinous support material which has been hardened as the direct result of exposure to ultraviolet light. Inventive methods for producing such material are also disclosed.

  11. Composite metal foil and ceramic fabric materials

    DOE Patents [OSTI]

    Webb, B.J.; Antoniak, Z.I.; Prater, J.T.; DeSteese, J.G.

    1992-03-24

    The invention comprises new materials useful in a wide variety of terrestrial and space applications. In one aspect, the invention comprises a flexible cloth-like material comprising a layer of flexible woven ceramic fabric bonded with a layer of metallic foil. In another aspect, the invention includes a flexible fluid impermeable barrier comprising a flexible woven ceramic fabric layer having metal wire woven therein. A metallic foil layer is incontinuously welded to the woven metal wire. In yet another aspect, the invention includes a material comprising a layer of flexible woven ceramic fabric bonded with a layer of an organic polymer. In still another aspect, the invention includes a rigid fabric structure comprising a flexible woven ceramic fabric and a resinous support material which has been hardened as the direct result of exposure to ultraviolet light. Inventive methods for producing such material are also disclosed. 11 figs.

  12. Mechanochemical processing for metals and metal alloys

    DOE Patents [OSTI]

    Froes, Francis H.; Eranezhuth, Baburaj G.; Prisbrey, Keith

    2001-01-01

    A set of processes for preparing metal powders, including metal alloy powders, by ambient temperature reduction of a reducible metal compound by a reactive metal or metal hydride through mechanochemical processing. The reduction process includes milling reactants to induce and complete the reduction reaction. The preferred reducing agents include magnesium and calcium hydride powders. A process of pre-milling magnesium as a reducing agent to increase the activity of the magnesium has been established as one part of the invention.

  13. Pitch-catch only ultrasonic fluid densitometer

    DOE Patents [OSTI]

    Greenwood, M.S.; Harris, R.V.

    1999-03-23

    The present invention is an ultrasonic fluid densitometer that uses a material wedge and pitch-catch only ultrasonic transducers for transmitting and receiving ultrasonic signals internally reflected within the material wedge. Density of a fluid is determined by immersing the wedge into the fluid and measuring reflection of ultrasound at the wedge-fluid interface. 6 figs.

  14. Fluid Imaging of Enhanced Geothermal Systems

    Broader source: Energy.gov [DOE]

    Project objectives: Attempting to Image EGS Fracture & Fluid Networks; Employing joint Geophysical Imaging Technologies.

  15. Pitch-catch only ultrasonic fluid densitometer

    DOE Patents [OSTI]

    Greenwood, Margaret S.; Harris, Robert V.

    1999-01-01

    The present invention is an ultrasonic fluid densitometer that uses a material wedge and pitch-catch only ultrasonic transducers for transmitting and receiving ultrasonic signals internally reflected within the material wedge. Density of a fluid is determined by immersing the wedge into the fluid and measuring reflection of ultrasound at the wedge-fluid interface.

  16. Ultracentrifuge for separating fluid mixtures

    DOE Patents [OSTI]

    Lowry, Ralph A.

    1976-01-01

    1. A centrifuge for the separation of fluid mixtures having light and heavy fractions comprising a cylindrical rotor, disc type end-plugs closing the ends of the rotor, means for mounting said rotor for rotation about its cylindrical axis, a housing member enclosing the rotor, a vacuum chamber in said housing about the central portion of the rotor, a collection chamber at each end of the housing, the innermost side of which is substantially formed by the outer face of the end-plug, means for preventing flow of the fluid from the collection chambers to said vacuum chamber, at least one of said end-plugs having a plurality of holes therethrough communicating between the collection chamber adjacent thereto and the inside of the rotor to induce countercurrent flow of the fluid in the centrifuge, means for feeding fluid to be processed into the centrifuge, means communicating with the collection chambers to extract the light and heavy separated fractions of the fluid, and means for rotating the rotor.

  17. DEVELOPMENT OF NEW DRILLING FLUIDS

    SciTech Connect (OSTI)

    David B. Burnett

    2003-08-01

    The goal of the project has been to develop new types of drill-in fluids (DIFs) and completion fluids (CFs) for use in natural gas reservoirs. Phase 1 of the project was a 24-month study to develop the concept of advanced type of fluids usable in well completions. Phase 1 tested this concept and created a kinetic mathematical model to accurately track the fluid's behavior under downhole conditions. Phase 2 includes tests of the new materials and practices. Work includes the preparation of new materials and the deployment of the new fluids and new practices to the field. The project addresses the special problem of formation damage issues related to the use of CFs and DIFs in open hole horizontal well completions. The concept of a ''removable filtercake'' has, as its basis, a mechanism to initiate or trigger the removal process. Our approach to developing such a mechanism is to identify the components of the filtercake and measure the change in the characteristics of these components when certain cleanup (filtercake removal) techniques are employed.

  18. Metal filled porous carbon

    DOE Patents [OSTI]

    Gross, Adam F.; Vajo, John J.; Cumberland, Robert W.; Liu, Ping; Salguero, Tina T.

    2011-03-22

    A porous carbon scaffold with a surface and pores, the porous carbon scaffold containing a primary metal and a secondary metal, where the primary metal is a metal that does not wet the surface of the pores of the carbon scaffold but wets the surface of the secondary metal, and the secondary metal is interspersed between the surface of the pores of the carbon scaffold and the primary metal.

  19. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Trending: Metal Oxo Bonds Trending: Metal Oxo Bonds Print Wednesday, 29 May 2013 00:00 Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides

  20. Mixing in a liquid metal electrode

    SciTech Connect (OSTI)

    Kelley, DH; Sadoway, DR

    2014-05-01

    Fluid mixing has first-order importance for many engineering problems in mass transport, including design and optimization of liquid-phase energy storage devices. Liquid metal batteries are currently being commercialized as a promising and economically viable technology for large-scale energy storage on worldwide electrical grids. But because these batteries are entirely liquid, fluid flow and instabilities may affect battery robustness and performance. Here we present estimates of flow magnitude and ultrasound measurements of the flow in a realistic liquid metal electrode. We find that flow does substantially affect mass transport by altering the electrode mixing time. Above a critical electrical current density, the convective flow organizes and gains speed, which promotes transport and would yield improved battery efficiency. (C) 2014 AIP Publishing LLC.

  1. Apparatus And Method For Producing Single Crystal Metallic Objects

    DOE Patents [OSTI]

    Huang, Shyh-Chin; Gigliotti, Jr., Michael Francis X.; Rutkowski, Stephen Francis; Petterson, Roger John; Svec, Paul Steven

    2006-03-14

    A mold is provided for enabling casting of single crystal metallic articles including a part-defining cavity, a sorter passage positioned vertically beneath and in fluid communication with the part-defining cavity, and a seed cavity positioned vertically beneath and in fluid communication with the sorter passage. The sorter passage includes a shape suitable for encouraging a single crystal structure in solidifying molten metal. Additionally, a portion of the mold between the sorter passage and the part-defining cavity includes a notch for facilitating breakage of a cast article proximate the notch during thermal stress build-up, so as to prevent mold breakage or the inclusion of part defects.

  2. Fluid-solid contact vessel having fluid distributors therein

    DOE Patents [OSTI]

    Jones, Jr., John B.

    1980-09-09

    Rectangularly-shaped fluid distributors for large diameter, vertical vessels include reinforcers for high heat operation, vertical sides with gas distributing orifices and overhanging, sloped roofs. Devices are provided for cleaning the orifices from a buildup of solid deposits resulting from the reactions in the vessel.

  3. Well completion and servicing fluid

    SciTech Connect (OSTI)

    Grimsley, R.L.

    1990-09-25

    This patent describes a well completion servicing fluid for controlling formation pressure during completion or servicing of a well. It comprises: an aqueous solution of calcium chloride, a solid weighing agent suspended in the solution and being selected from the group consisting of zinc, zinc oxide, and mixtures thereof; and a viscosifier dissolved in the solution in an amount effective to suspend the weighing agent. The fluid has a density of greater than 15 pounds per gallon and being substantially free of bromide ions and being substantially free of solid material which is not soluble in hydrochloric acid.

  4. Transport coefficients of gluonic fluid

    SciTech Connect (OSTI)

    Das, Santosh K.; Alam, Jan-e

    2011-06-01

    The shear ({eta}) and bulk ({zeta}) viscous coefficients have been evaluated for a gluonic fluid. The elastic, gg{yields}gg and the inelastic, number nonconserving, gg{yields}ggg processes have been considered as the dominant perturbative processes in evaluating the viscous coefficients to entropy density (s) ratios. Recently the processes: gg{yields}ggg has been revisited and a correction to the widely used Gunion-Bertsch (GB) formula has been obtained. The {eta} and {zeta} have been evaluated for gluonic fluid with the formula recently derived. At large {alpha}{sub s} the value of {eta}/s approaches its lower bound, {approx}1/4{pi}.

  5. Wellbottom fluid implosion treatment system

    SciTech Connect (OSTI)

    Brieger, Emmet F.

    2001-01-01

    A system for inducing implosion shock forces on perforation traversing earth formations with fluid pressure where an implosion tool is selected relative to a shut in well pressure and a tubing pressure to have a large and small area piston relationship in a well tool so that at a predetermined tubing pressure the pistons move a sufficient distance to open an implosion valve which permits a sudden release of well fluid pressure into the tubing string and produces an implosion force on the perforations. A pressure gauge on the well tool records tubing pressure and well pressure as a function of time.

  6. Electromagnetic augmentation for casting of thin metal sheets

    DOE Patents [OSTI]

    Hull, John R.

    1989-01-01

    Thin metal sheets are cast by magnetically levitating molten metal deposited in a mold within a ferromagnetic yoke and between AC conducting coils and linearly displacing the magnetically levitated liquid metal while it is being cooled by the water-cooled walls of the mold to form a solid metal sheet. A conducting shield is electrically coupled to the molten metal sheet to provide a return path for eddy currents induced in the metal sheet by the current in the AC conducting coils. In another embodiment, a DC conducting coil is coupled to the metal sheet for providing a direct current therein which interacts with the magnetic field to levitate the moving metal sheet. Levitation of the metal sheet in both molten and solid forms reduces its contact pressure with the mold walls while maintaining sufficient engagement therebetween to permit efficient conductive cooling by the mold through which a coolant fluid may be circulated. The magnetic fields associated with the currents in the aforementioned coils levitate the molten metal sheet while the mold provides for its lateral and vertical confinement. A leader sheet having electromagnetic characteristics similar to those of the molten metal sheet is used to start the casing process and precedes the molten metal sheet through the yoke/coil arrangement and mold and forms a continuous sheet therewith. The yoke/coil arrangement may be either U-shaped with a single racetrack coil or may be rectangular with a pair of spaced, facing bedstead coils.

  7. Indirect passive cooling system for liquid metal cooled nuclear reactors

    DOE Patents [OSTI]

    Hunsbedt, Anstein; Boardman, Charles E.

    1990-01-01

    A liquid metal cooled nuclear reactor having a passive cooling system for removing residual heat resulting from fuel decay during reactor shutdown. The passive cooling system comprises a plurality of partitions surrounding the reactor vessel in spaced apart relation forming intermediate areas for circulating heat transferring fluid which remove and carry away heat from the reactor vessel. The passive cooling system includes a closed primary fluid circuit through the partitions surrounding the reactor vessel and a partially adjoining secondary open fluid circuit for carrying transferred heat out into the atmosphere.

  8. Passive cooling safety system for liquid metal cooled nuclear reactors

    DOE Patents [OSTI]

    Hunsbedt, Anstein; Boardman, Charles E.; Hui, Marvin M.; Berglund, Robert C.

    1991-01-01

    A liquid metal cooled nuclear reactor having a passive cooling system for removing residual heat resulting from fuel decay during reactor shutdown. The passive cooling system comprises a plurality of partitions surrounding the reactor vessel in spaced apart relation forming intermediate areas for circulating heat transferring fluid which remove and carry away heat from the reactor vessel. The passive cooling system includes a closed primary fluid circuit through the partitions surrounding the reactor vessel and a partially adjoining secondary open fluid circuit for carrying transferred heat out into the atmosphere.

  9. Seal for fluid forming tools

    DOE Patents [OSTI]

    Golovashchenko, Sergey Fedorovich; Bonnen, John Joseph Francis

    2012-03-20

    An electro-hydraulic forming tool for forming a sheet metal blank in a one-sided die has first and second rigid rings that engage opposite sides of a sheet metal blank. The rigid rings are contained within slots on a die portion and a hydraulic force applicator portion of the forming tool. The seals are either resiliently biased by an elastomeric member or inherently resiliently biased into contact with the blank.

  10. General Transient Fluid Flow Algorithm

    Energy Science and Technology Software Center (OSTI)

    1992-03-12

    SALE2D calculates two-dimensional fluid flows at all speeds, from the incompressible limit to highly supersonic. An implicit treatment of the pressure calculation similar to that in the Implicit Continuous-fluid Eulerian (ICE) technique provides this flow speed flexibility. In addition, the computing mesh may move with the fluid in a typical Lagrangian fashion, be held fixed in an Eulerian manner, or move in some arbitrarily specified way to provide a continuous rezoning capability. This latitude resultsmore » from use of an Arbitrary Lagrangian-Eulerian (ALE) treatment of the mesh. The partial differential equations solved are the Navier-Stokes equations and the mass and internal energy equations. The fluid pressure is determined from an equation of state and supplemented with an artificial viscous pressure for the computation of shock waves. The computing mesh consists of a two-dimensional network of quadrilateral cells for either cylindrical or Cartesian coordinates, and a variety of user-selectable boundary conditions are provided in the program.« less

  11. Directed flow fluid rinse trough

    DOE Patents [OSTI]

    Kempka, S.N.; Walters, R.N.

    1996-07-02

    Novel rinse troughs accomplish thorough uniform rinsing. The tanks are suitable for one or more essentially planar items having substantially the same shape. The troughs ensure that each surface is rinsed uniformly. The new troughs also require less rinse fluid to accomplish a thorough rinse than prior art troughs. 9 figs.

  12. Directed flow fluid rinse trough

    DOE Patents [OSTI]

    Kempka, Steven N.; Walters, Robert N.

    1996-01-01

    Novel rinse troughs accomplish thorough uniform rinsing. The tanks are suitable for one or more essentially planar items having substantially the same shape. The troughs ensure that each surface is rinsed uniformly. The new troughs also require less rinse fluid to accomplish a thorough rinse than prior art troughs.

  13. Metal-phosphate binders

    DOE Patents [OSTI]

    Howe, Beth Ann [Lewistown, IL; Chaps-Cabrera, Jesus Guadalupe [Coahuila, MX

    2009-05-12

    A metal-phosphate binder is provided. The binder may include an aqueous phosphoric acid solution, a metal-cation donor including a metal other than aluminum, an aluminum-cation donor, and a non-carbohydrate electron donor.

  14. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide

  15. Role of metal-support interactions on the activity of Pt and Rh catalysts for reforming methane and butane.

    SciTech Connect (OSTI)

    Rossignol, C.; Krause, T.; Krumpelt, M.

    2002-01-11

    For residential fuel cell systems, reforming of natural gas is one option being considered for providing the H{sub 2} necessary for the fuel cell to operate. Industrially, natural gas is reformed using Ni-based catalysts supported on an alumina substrate, which has been modified to inhibit coke formation. At Argonne National Laboratory, we have developed a new family of catalysts derived from solid oxide fuel cell technology for reforming hydrocarbon fuels to generate H{sub 2}. These catalysts consist of a transition metal supported on an oxide-ion-conducting substrate, such as ceria, that has been doped with a small amount of a non-reducible element, such as gadolinium, samarium, or zirconium. Unlike alumina, the oxide-ion-conducting substrate has been shown to induce strong metal-support interactions. Metal-support interactions are known to play an important role in influencing the catalytic activity of many metals supported on oxide supports. Based on results from temperature-programmed reduction/oxidation and kinetic reaction studies, this paper discusses the role of the metal and the substrate in the metal-support interactions, and how these interactions influence the activity and the selectivity of the catalyst in reforming methane and butane to hydrogen for use in fuel cell power systems.

  16. Heat Transfer in Complex Fluids

    SciTech Connect (OSTI)

    Mehrdad Massoudi

    2012-01-01

    Amongst the most important constitutive relations in Mechanics, when characterizing the behavior of complex materials, one can identify the stress tensor T, the heat flux vector q (related to heat conduction) and the radiant heating (related to the radiation term in the energy equation). Of course, the expression 'complex materials' is not new. In fact, at least since the publication of the paper by Rivlin & Ericksen (1955), who discussed fluids of complexity (Truesdell & Noll, 1992), to the recently published books (Deshpande et al., 2010), the term complex fluids refers in general to fluid-like materials whose response, namely the stress tensor, is 'non-linear' in some fashion. This non-linearity can manifest itself in variety of forms such as memory effects, yield stress, creep or relaxation, normal-stress differences, etc. The emphasis in this chapter, while focusing on the constitutive modeling of complex fluids, is on granular materials (such as coal) and non-linear fluids (such as coal-slurries). One of the main areas of interest in energy related processes, such as power plants, atomization, alternative fuels, etc., is the use of slurries, specifically coal-water or coal-oil slurries, as the primary fuel. Some studies indicate that the viscosity of coal-water mixtures depends not only on the volume fraction of solids, and the mean size and the size distribution of the coal, but also on the shear rate, since the slurry behaves as shear-rate dependent fluid. There are also studies which indicate that preheating the fuel results in better performance, and as a result of such heating, the viscosity changes. Constitutive modeling of these non-linear fluids, commonly referred to as non-Newtonian fluids, has received much attention. Most of the naturally occurring and synthetic fluids are non-linear fluids, for example, polymer melts, suspensions, blood, coal-water slurries, drilling fluids, mud, etc. It should be noted that sometimes these fluids show Newtonian

  17. Compressor bleed cooling fluid feed system

    SciTech Connect (OSTI)

    Donahoo, Eric E; Ross, Christopher W

    2014-11-25

    A compressor bleed cooling fluid feed system for a turbine engine for directing cooling fluids from a compressor to a turbine airfoil cooling system to supply cooling fluids to one or more airfoils of a rotor assembly is disclosed. The compressor bleed cooling fluid feed system may enable cooling fluids to be exhausted from a compressor exhaust plenum through a downstream compressor bleed collection chamber and into the turbine airfoil cooling system. As such, the suction created in the compressor exhaust plenum mitigates boundary layer growth along the inner surface while providing flow of cooling fluids to the turbine airfoils.

  18. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the...

  19. REFRACTORY METAL TUBE DRAWING

    DOE Patents [OSTI]

    Bean, C.H.; Karasek, F.J.

    1963-01-29

    A lubricant for drawing Zr and other refractory metals is described. Metallic Cu powder is added to a solution of acrylic resin in chlorinated hydrocarbon solvent. (AEC)

  20. Two-phase alkali-metal experiments in reduced gravity

    SciTech Connect (OSTI)

    Antoniak, Z.I.

    1986-06-01

    Future space missions envision the use of large nuclear reactors utilizing either a single or a two-phase alkali-metal working fluid. The design and analysis of such reactors require state-of-the-art computer codes that can properly treat alkali-metal flow and heat transfer in a reduced-gravity environment. A literature search of relevant experiments in reduced gravity is reported on here, and reveals a paucity of data for such correlations. The few ongoing experiments in reduced gravity are noted. General plans are put forth for the reduced-gravity experiments which will have to be performed, at NASA facilities, with benign fluids. A similar situation exists regarding two-phase alkali-metal flow and heat transfer, even in normal gravity. Existing data are conflicting and indequate for the task of modeling a space reactor using a two-phase alkali-metal coolant. The major features of past experiments are described here. Data from the reduced-gravity experiments with innocuous fluids are to be combined with normal gravity data from the two-phase alkali-metal experiments. Analyses undertaken here give every expectation that the correlations developed from this data base will provide a valid representation of alkali-metal heat transfer and pressure drop in reduced gravity.

  1. Silica recovery and control in Hawaiian geothermal fluids. Final report

    SciTech Connect (OSTI)

    Thomas, D.M.

    1992-06-01

    A series of experiments was performed to investigate methods of controlling silica in waste geothermal brines produced at the HGP-A Generator Facility. Laboratory testing has shown that the rate of polymerization of silica in the geothermal fluids is highly pH dependent. At brine pH values in excess of 8.5 the suspension of silica polymers flocculated and rapidly precipitated a gelatinous silica mass. Optimum flocculation and precipitation rates were achieved at pH values in the range of 10.5 to 11.5. The addition of transition metal salts to the geothermal fluids similarly increased the rate of polymerization as well as the degree of precipitation of the silica polymer from suspension. A series of experiments performed on the recovered silica solids demonstrated that methanol extraction of the water in the gels followed by critical point drying yielded surface areas in excess of 300 M{sup 2}/g and that treatment of the dried solids with 2 N HCl removed most of the adsorbed impurities in the recovered product. A series of experiments tested the response of the waste brines to mixing with steam condensate and non-condensable gases.The results demonstrated that the addition of condensate and NCG greatly increased the stability of the silica in the geothermal brines. They also indicated that the process could reduce the potential for plugging of reinjection wells receiving waste geothermal fluids from commercial geothermal facilities in Hawaii. Conceptual designs were proposed to apply the gas re-combination approach to the disposal of geothermal waste fluids having a range of chemical compositions. Finally, these designs were applied to the geothermal fluid compositions found at Cerro Prieto, Ahuachapan, and Salton Sea.

  2. Silica recovery and control in Hawaiian geothermal fluids

    SciTech Connect (OSTI)

    Thomas, D.M.

    1992-06-01

    A series of experiments was performed to investigate methods of controlling silica in waste geothermal brines produced at the HGP-A Generator Facility. Laboratory testing has shown that the rate of polymerization of silica in the geothermal fluids is highly pH dependent. At brine pH values in excess of 8.5 the suspension of silica polymers flocculated and rapidly precipitated a gelatinous silica mass. Optimum flocculation and precipitation rates were achieved at pH values in the range of 10.5 to 11.5. The addition of transition metal salts to the geothermal fluids similarly increased the rate of polymerization as well as the degree of precipitation of the silica polymer from suspension. A series of experiments performed on the recovered silica solids demonstrated that methanol extraction of the water in the gels followed by critical point drying yielded surface areas in excess of 300 M{sup 2}/g and that treatment of the dried solids with 2 N HCl removed most of the adsorbed impurities in the recovered product. A series of experiments tested the response of the waste brines to mixing with steam condensate and non-condensable gases.The results demonstrated that the addition of condensate and NCG greatly increased the stability of the silica in the geothermal brines. They also indicated that the process could reduce the potential for plugging of reinjection wells receiving waste geothermal fluids from commercial geothermal facilities in Hawaii. Conceptual designs were proposed to apply the gas re-combination approach to the disposal of geothermal waste fluids having a range of chemical compositions. Finally, these designs were applied to the geothermal fluid compositions found at Cerro Prieto, Ahuachapan, and Salton Sea.

  3. Fluid sampling system for a nuclear reactor

    DOE Patents [OSTI]

    Lau, L.K.; Alper, N.I.

    1994-11-22

    A system of extracting fluid samples, either liquid or gas, from the interior of a nuclear reactor containment utilizes a jet pump. To extract the sample fluid, a nonradioactive motive fluid is forced through the inlet and discharge ports of a jet pump located outside the containment, creating a suction that draws the sample fluid from the containment through a sample conduit connected to the pump suction port. The mixture of motive fluid and sample fluid is discharged through a return conduit to the interior of the containment. The jet pump and means for removing a portion of the sample fluid from the sample conduit can be located in a shielded sample grab station located next to the containment. A non-nuclear grade active pump can be located outside the grab sampling station and the containment to pump the nonradioactive motive fluid through the jet pump. 1 fig.

  4. Fluid sampling system for a nuclear reactor

    DOE Patents [OSTI]

    Lau, Louis K.; Alper, Naum I.

    1994-01-01

    A system of extracting fluid samples, either liquid or gas, from the interior of a nuclear reactor containment utilizes a jet pump. To extract the sample fluid, a nonradioactive motive fluid is forced through the inlet and discharge ports of a jet pump located outside the containment, creating a suction that draws the sample fluid from the containment through a sample conduit connected to the pump suction port. The mixture of motive fluid and sample fluid is discharged through a return conduit to the interior of the containment. The jet pump and means for removing a portion of the sample fluid from the sample conduit can be located in a shielded sample grab station located next to the containment. A non-nuclear grade active pump can be located outside the grab sampling station and the containment to pump the nonradioactive motive fluid through the jet pump.

  5. Aqueous cutting fluid for machining fissionable materials

    DOE Patents [OSTI]

    Duerksen, Walter K.; Googin, John M.; Napier, Jr., Bradley

    1984-01-01

    The present invention is directed to a cutting fluid for machining fissionable material. The cutting fluid is formed of glycol, water and boron compound in an adequate concentration for effective neutron attenuation so as to inhibit criticality incidents during machining.

  6. Apparatus for unloading pressurized fluid

    DOE Patents [OSTI]

    Rehberger, Kevin M.

    1994-01-01

    An apparatus for unloading fluid, preferably pressurized gas, from containers in a controlled manner that protects the immediate area from exposure to the container contents. The device consists of an unloading housing, which is enclosed within at least one protective structure, for receiving the dispensed contents of the steel container, and a laser light source, located external to the protective structure, for opening the steel container instantaneously. The neck or stem of the fluid container is placed within the sealed interior environment of the unloading housing. The laser light passes through both the protective structure and the unloading housing to instantaneously pierce a small hole within the stem of the container. Both the protective structure and the unloading housing are specially designed to allow laser light passage without compromising the light's energy level. Also, the unloading housing allows controlled flow of the gas once it has been dispensed from the container. The external light source permits remote operation of the unloading device.

  7. Ultrasonic fluid densitometer for process control

    DOE Patents [OSTI]

    Greenwood, Margaret S.

    2000-01-01

    The present invention is an ultrasonic fluid densitometer that uses at least one pair of transducers for transmitting and receiving ultrasonic signals internally reflected within a material wedge. A temperature sensor is provided to monitor the temperature of the wedge material. Density of a fluid is determined by immersing the wedge into the fluid and measuring reflection of ultrasound at the wedge-fluid interface and comparing a transducer voltage and wedge material temperature to a tabulation as a function of density.

  8. METAL PRODUCTION AND CASTING

    DOE Patents [OSTI]

    Magel, T.T.

    1958-03-01

    This patent covers a method and apparatus for collecting the molten metal produced by high temperature metal salt reduction. It consists essentially of subjecting the reaction vessel to centrifugal force in order to force the liberatcd molten metal into a coherent molten mass, and allowing it to solidify there. The apparatus is particularly suitable for use with small quantities of rare metals.

  9. Heavy metal biosensor

    DOE Patents [OSTI]

    Hillson, Nathan J; Shapiro, Lucille; Hu, Ping; Andersen, Gary L

    2014-04-15

    Compositions and methods are provided for detection of certain heavy metals using bacterial whole cell biosensors.

  10. Ceramic to metal seal

    DOE Patents [OSTI]

    Snow, Gary S.; Wilcox, Paul D.

    1976-01-01

    Providing a high strength, hermetic ceramic to metal seal by essentially heating a wire-like metal gasket and a ceramic member, which have been chemically cleaned, while simultaneously deforming from about 50 to 95 percent the metal gasket against the ceramic member at a temperature of about 30 to 75 percent of the melting temperature of the metal gasket.

  11. Amorphous metal composites

    DOE Patents [OSTI]

    Byrne, Martin A. (Troy, NY); Lupinski, John H. (Scotia, NY)

    1984-01-01

    An improved amorphous metal composite and process of making the composite. The amorphous metal composite comprises amorphous metal (e.g. iron) and a low molecular weight thermosetting polymer binder. The process comprises placing an amorphous metal in particulate form and a thermosetting polymer binder powder into a container, mixing these materials, and applying heat and pressure to convert the mixture into an amorphous metal composite.

  12. Reservoir compartmentalization assessed with fluid compositional data

    SciTech Connect (OSTI)

    Smalley, P.C.; England, W.A. . Alliance R D Centre)

    1994-08-01

    Fluid composition is a valuable addition to the battery of static'' data available during reservoir appraisal that can be used to predict the dynamic behavior of the reservoir later in field life. This is because fluid data are not truly static; natural fluid mixing is a dynamic process that occurs over a long (geologic) time scale. Oil compositional differences, especially those that parallel changes in density, should be mixed rapidly by convection; their preservation indicates barriers to fluid flow. Water variations, now measurable on conventional core samples by use of residual salt analysis (RSA), help identify barriers to vertical fluid flow in oil and water legs.

  13. Metal-Organic Heat Carrier Nanofluids

    SciTech Connect (OSTI)

    McGrail, B. Peter; Thallapally, Praveen K.; Blanchard, Jeremy; Nune, Satish K.; Jenks, Jeromy WJ; Dang, Liem X.

    2013-09-01

    Nanofluids, dispersions of metal or oxide nanoparticles in a base working fluid, are being intensively studied due to improvements they offer in thermal properties of the working fluid. However, these benefits have been erratically demonstrated and proven impacts on thermal conductivity are modest and well described from long-established effective medium theory. In this paper, we describe a new class of metal-organic heat carrier (MOHC) nanofluid that offers potential for a larger performance boost in thermal vapor-liquid compression cycles. MOHCs are nanophase porous coordination solids designed to reversibly uptake the working fluid molecules in which the MOHCs are suspended. Additional heat can be extracted in a heat exchanger or solar collector from the endothermic enthalpy of desorption, which is then released as the nanofluid transits through a power generating device such as a turboexpander. Calculations for an R123 MOHC nanofluid indicated potential for up to 15% increase in power output. Capillary tube experiments show that liquid-vapor transitions occur without nanoparticle deposition on the tube walls provided entrance Reynolds number exceeds approximately 100.

  14. Transient Wellbore Fluid Flow Model

    Energy Science and Technology Software Center (OSTI)

    1982-04-06

    WELBORE is a code to solve transient, one-dimensional two-phase or single-phase non-isothermal fluid flow in a wellbore. The primary thermodynamic variables used in solving the equations are the pressure and specific energy. An equation of state subroutine provides the density, quality, and temperature. The heat loss out of the wellbore is calculated by solving a radial diffusion equation for the temperature changes outside the bore. The calculation is done at each node point in themore » wellbore.« less

  15. Immersible solar heater for fluids

    DOE Patents [OSTI]

    Kronberg, James W.

    1995-01-01

    An immersible solar heater comprising a light-absorbing panel attached to a frame for absorbing heat energy from the light and transferring the absorbed heat energy directly to the fluid in which the heater is immersed. The heater can be used to heat a swimming pool, for example, and is held in position and at a preselected angle by a system of floats, weights and tethers so that the panel can operate efficiently. A skid can be used in one embodiment to prevent lateral movement of the heater along the bottom of the pool. Alternative embodiments include different arrangements of the weights, floats and tethers and methods for making the heater.

  16. Fluid cooled vehicle drive module

    DOE Patents [OSTI]

    Beihoff, Bruce C.; Radosevich, Lawrence D.; Meyer, Andreas A.; Gollhardt, Neil; Kannenberg, Daniel G.

    2005-11-15

    An electric vehicle drive includes a support may receive one or more power electronic circuits. The support may aid in removing heat from the circuits through fluid circulating through the support. The support, in conjunction with other packaging features may form a shield from both external EM/RFI and from interference generated by operation of the power electronic circuits. Features may be provided to permit and enhance connection of the circuitry to external circuitry, such as improved terminal configurations. Modular units may be assembled that may be coupled to electronic circuitry via plug-in arrangements or through interface with a backplane or similar mounting and interconnecting structures.

  17. Polymer filtration systems for dilute metal ion recovery

    SciTech Connect (OSTI)

    Smith, B.F.; Robison, T.W.; Jarvinen, G.D.

    1998-12-01

    Scientists at Los Alamos National Laboratory have developed a metal recovery system that meets the global treatment demands for all kinds of industrial and metal-processing streams. The Polymer Filtration (PF) System--a process that is easily operated and robust--offers metal-finishing businesses a convenient and inexpensive way to recover and recycle metal ions in-house, thus reducing materials costs, waste removal costs, and industrial liability. As a valuable economic and environmental asset, the PF System has been named a winner of a 1995 R and D 100 Award. These awards are presented annually by R and D Magazine to the one hundred most significant technical innovations of the year. The PF System is based on the use of water-soluble metal-binding polymers and on advanced ultrafiltration membranes. Customers for this technology will receive new soluble polymers, especially formulated for their waste stream, and the complete PF processing unit: a reaction reservoir, pumps, plumbing, controls, and the advanced ultrafiltration membranes, all in a skid mounted frame. Metal-bearing waste water is treated in the reaction reservoir, where the polymer binds with the metal ions under balanced acid/base conditions. The reservoir fluid is then pumped through the ultrafiltration system--a cartridge packed with ultrafiltration membranes shaped in hollow fibers. As the fluid travels inside the fiber, water and other small molecules--simple salts such as calcium and sodium, for example--pass through the porous membrane walls of the fibers and are discharged through the outlet as permeate. The polymer-bound metal, which is too large to pass through the pores, is both purified and concentrated inside the hollow fibers and is returned to the fluid reservoir for further waste water treatment.

  18. Metal halogen electrochemical cell

    SciTech Connect (OSTI)

    Walsh, F.M.

    1986-06-03

    An electrochemical cell is described having a metal anode selected from the group consisting of zinc and cadmium; a bromine cathode; and, an aqueous electrolyte containing a metal bromide, the metal having the same metal as the metal of the anode, the improvement comprising: a bromine complexing agent in the aqueous metal bromide electrolyte consisting solely of a tetraorgano substituted ammonium salt, which salt is soluble of water and forms and substantially water immiscible liquid bromine complex at temperatures in the range of about 10/sup 0/C. to about 60/sup 0/C. and wherein the tetraorgano substituted ammonium salt is selected from asymmetric quaternary ammonium compounds.

  19. Alkali metal nitrate purification

    DOE Patents [OSTI]

    Fiorucci, Louis C. (Hamden, CT); Morgan, Michael J. (Guilford, CT)

    1986-02-04

    A process is disclosed for removing contaminants from impure alkali metal nitrates containing them. The process comprises heating the impure alkali metal nitrates in solution form or molten form at a temperature and for a time sufficient to effect precipitation of solid impurities and separating the solid impurities from the resulting purified alkali metal nitrates. The resulting purified alkali metal nitrates in solution form may be heated to evaporate water therefrom to produce purified molten alkali metal nitrates suitable for use as a heat transfer medium. If desired, the purified molten form may be granulated and cooled to form discrete solid particles of purified alkali metal nitrates.

  20. Metal-Air Batteries

    SciTech Connect (OSTI)

    Zhang, Jiguang; Bruce, Peter G.; Zhang, Gregory

    2011-08-01

    Metal-air batteries have much higher specific energies than most currently available primary and rechargeable batteries. Recent advances in electrode materials and electrolytes, as well as new designs on metal-air batteries, have attracted intensive effort in recent years, especially in the development of lithium-air batteries. The general principle in metal-air batteries will be reviewed in this chapter. The materials, preparation methods, and performances of metal-air batteries will be discussed. Two main metal-air batteries, Zn-air and Li-air batteries will be discussed in detail. Other type of metal-air batteries will also be described.

  1. Nanoparticle Assemblies at Fluid Interfaces

    SciTech Connect (OSTI)

    Russell, Thomas P.

    2015-03-10

    A systematic study of the structure and dynamics of nanoparticles (NP) and NP-surfactants was performed. The ligands attached to both the NPs and NP-surfactants dictate the manner in which the nanoscopic materials assemble at fluid interfaces. Studies have shown that a single layer of the nanoscpic materials form at the interface to reduce the interactions between the two immiscible fluids. The shape of the NP is, also, important, where for spherical particles, a disordered, liquid-like monolayer forms, and, for nanorods, ordered domains at the interface is found and, if the monolayers are compressed, the orientation of the nanorods with respect to the interface can change. By associating end-functionalized polymers to the NPs assembled at the interface, NP-surfactants are formed that increase the energetic gain in segregating each NP at the interface which allows the NP-surfactants to jam at the interface when compressed. This has opened the possibility of structuring the two liquids by freezing in shape changes of the liquids.

  2. Apparatus for unloading pressurized fluid

    DOE Patents [OSTI]

    Rehberger, K.M.

    1994-01-04

    An apparatus is described for unloading fluid, preferably pressurized gas, from containers in a controlled manner that protects the immediate area from exposure to the container contents. The device consists of an unloading housing, which is enclosed within at least one protective structure, for receiving the dispensed contents of the steel container, and a laser light source, located external to the protective structure, for opening the steel container instantaneously. The neck or stem of the fluid container is placed within the sealed interior environment of the unloading housing. The laser light passes through both the protective structure and the unloading housing to instantaneously pierce a small hole within the stem of the container. Both the protective structure and the unloading housing are specially designed to allow laser light passage without compromising the light's energy level. Also, the unloading housing allows controlled flow of the gas once it has been dispensed from the container. The external light source permits remote operation of the unloading device. 2 figures.

  3. Hydrostatic bearings for a turbine fluid flow metering device

    DOE Patents [OSTI]

    Fincke, J.R.

    1982-05-04

    A rotor assembly fluid metering device has been improved by development of a hydrostatic bearing fluid system which provides bearing fluid at a common pressure to rotor assembly bearing surfaces. The bearing fluid distribution system produces a uniform film of fluid between bearing surfaces and allows rapid replacement of bearing fluid between bearing surfaces, thereby minimizing bearing wear and corrosion. 3 figs.

  4. Hydrostatic bearings for a turbine fluid flow metering device

    DOE Patents [OSTI]

    Fincke, James R.

    1982-01-01

    A rotor assembly fluid metering device has been improved by development of a hydrostatic bearing fluid system which provides bearing fluid at a common pressure to rotor assembly bearing surfaces. The bearing fluid distribution system produces a uniform film of fluid between bearing surfaces and allows rapid replacement of bearing fluid between bearing surfaces, thereby minimizing bearing wear and corrosion.

  5. Ceramic pressure housing with metal endcaps

    DOE Patents [OSTI]

    Downing, J.P. Jr.; DeRoos, B.G.; Hackman, D.J.

    1995-06-27

    A housing is disclosed for the containment of instrumentation in a high pressure fluid environment that consists of a metallic endcap and ceramic cylinder bonded together. The improvement comprises a structure which results in the improved sealing of said housing as the fluid pressure increases. The cylindrical ceramic tube and endcap are dimensioned such that mechanical failure does not occur when exposed to the desired external operating pressures which includes up to 36,000 feet of water. The housing is designed to withstand the external operating pressures without being subject to mechanical failure or excessive deformation which results in the loss of pressure housing integrity via cracking or deformation of the ceramic tube, deformation of the endcap, or from failure of the bonding agent. 9 figs.

  6. Ceramic pressure housing with metal endcaps

    DOE Patents [OSTI]

    Downing, Jr., John P. (Port Townsand, WA); DeRoos, Bradley G. (Worthington, OH); Hackman, Donald J. (Columbus, OH)

    1995-01-01

    A housing for the containment of instrumentation in a high pressure fluid environment that consists of a metallic endcap and ceramic cylinder bonded together. The improvement comprises a structure which results in the improved sealing of said housing as the fluid pressure increases. The cylindrical ceramic tube and endcap are dimensioned such that mechanical failure does not occur when exposed to the desired external operating pressures which includes up to 36,000 feet of water. The housing is designed to withstand the external operating pressures without being subject to mechanical failure or excessive deformation which results in the loss of pressure housing integrity via cracking or deformation of the ceramic tube, deformation of the endcap, or from failure of the bonding agent.

  7. Metal to semiconductor transition in metallic transition metal dichalcogenides

    SciTech Connect (OSTI)

    Li, Yan; Kang, Jun; Li, Jingbo; Tongay, Sefaattin; Wu, Junqiao; Yue, Qu

    2013-11-07

    We report on tuning the electronic and magnetic properties of metallic transition metal dichalcogenides (mTMDCs) by 2D to 1D size confinement. The stability of the mTMDC monolayers and nanoribbons is demonstrated by the larger binding energy compared to the experimentally available semiconducting TMDCs. The 2D MX{sub 2} (M?=?Nb, Ta; X?=?S, Se) monolayers are non-ferromagnetic metals and mechanically softer compared to their semiconducting TMDCs counterparts. Interestingly, mTMDCs undergo metal-to-semiconductor transition when the ribbon width approaches to ?13? and ?7? for zigzag and armchair edge terminations, respectively; then these ribbons convert back to metal when the ribbon widths further decrease. Zigzag terminated nanoribbons are ferromagnetic semiconductors, and their magnetic properties can also be tuned by hydrogen edge passivation, whereas the armchair nanoribbons are non-ferromagnetic semiconductors. Our results display that the mTMDCs offer a broad range of physical properties spanning from metallic to semiconducting and non-ferromagnetic to ferromagnetic that is ideal for applications where stable narrow bandgap semiconductors with different magnetic properties are desired.

  8. Nitrided Metallic Bipolar Plates

    SciTech Connect (OSTI)

    Brady, Michael P; Toops, Todd J; Tortorelli, Peter F; More, Karren Leslie; Meyer III, Harry M; Pihl, Josh A; Wang, Heli; Turner, John; Garzon, Fernando; Rockward, Tommy; Gervasio, Don; Rakowski, Jim; EstevezGenCell, Francisco

    2010-01-01

    Effort devoted to scale up and demonstration of thin stamped metallic bipolar plates. Overall goal is to demonstrate potential for metallic bipolar plates to meet 5000 h automotive durability goal at a cost of less than $5/kW.

  9. Metal phthalocyanine catalysts

    DOE Patents [OSTI]

    Ellis, Jr., Paul E.; Lyons, James E.

    1994-01-01

    As a new composition of matter, alkali metal or ammonium or tetraalkylammonium diazidoperfluorophthalocyanatoferrate. Other embodiments of the invention comprise compositions wherein the metal of the coordination complex is cobalt, manganese and chromium.

  10. Metal phthalocyanine catalysts

    DOE Patents [OSTI]

    Ellis, P.E. Jr.; Lyons, J.E.

    1994-10-11

    A new composition of matter is described which is an alkali metal or ammonium or tetraalkylammonium diazidoperfluorophthalocyanatoferrate. Other embodiments of the invention comprise compositions wherein the metal of the coordination complex is cobalt, manganese and chromium.

  11. Casting Apparatus Including A Gas Driven Molten Metal Injector And Method

    DOE Patents [OSTI]

    Meyer, Thomas N.

    2004-06-01

    The casting apparatus (50) includes a holding vessel (10) for containing a supply of molten metal (12) and a casting mold (52) located above the holding vessel (10) and having a casting cavity (54). A molten metal injector (14) extends into the holding vessel (10) and is at least partially immersed in the molten metal (12) in the holding vessel (10). The molten metal injector (14) is in fluid communication with the casting cavity (54). The molten metal injector (14) has an injector body (16) defining an inlet opening (24) for receiving molten metal into the injector body (16). A gas pressurization source (38) is in fluid communication with the injector body (16) for cyclically pressurizing the injector body (16) and inducing molten metal to flow from the injector body (16) to the casting cavity (54). An inlet valve (42) is located in the inlet opening (24) in the injector body (16) for filling molten metal into the injector body (16). The inlet valve (42) is configured to prevent outflow of molten metal from the injector body (16) during pressurization and permit inflow of molten metal into the injector body (16) after pressurization. The inlet valve (42) has an inlet valve actuator (44) located above the surface of the supply of molten metal (12) and is operatively connected to the inlet valve (42) for operating the inlet valve (42) between open and closed positions.

  12. MECS 2006- Fabricated Metals

    Broader source: Energy.gov [DOE]

    Manufacturing Energy and Carbon Footprint for Fabricated Metals (NAICS 332) Sector with Total Energy Input, October 2012 (MECS 2006)

  13. Split driveshaft pump for hazardous fluids

    DOE Patents [OSTI]

    Evans, II, Thomas P.; Purohit, Jwalit J.; Fazio, John M.

    1995-01-01

    A pump having a split driveshaft for use in pumping hazardous fluids wherein only one driveshaft becomes contaminated by the fluid while the second remains isolated from the fluid. The pump has a first portion and a second portion. The first portion contains a pump motor, the first driveshaft, a support pedestal, and vapor barriers and seals. The second portion contains a second, self-lubricating driveshaft and an impeller. The first and second driveshafts are connected together by a releasable coupling. A shield and a slinger deployed below the coupling prevent fluid from the second portion from reaching the first portion. In operation, only the second assembly comes into contact with the fluid being pumped, so the risk of contamination of the first portion by the hazardous fluid is reduced. The first assembly can be removed for repairs or routine maintenance by decoupling the first and second driveshafts and disconnecting the motor from the casing.

  14. Multiple source/multiple target fluid transfer apparatus

    DOE Patents [OSTI]

    Turner, Terry D.

    1997-01-01

    A fluid transfer apparatus includes: a) a plurality of orifices for connection with fluid sources; b) a plurality of orifices for connection with fluid targets; c) a set of fluid source conduits and fluid target conduits associated with the orifices; d) a pump fluidically interposed between the source and target conduits to transfer fluid therebetween; e) a purge gas conduit in fluid communication with the fluid source conduits, fluid target conduits and pump to receive and pass a purge gas under pressure; f) a solvent conduit in fluid communication with the fluid source conduits, fluid target conduits and pump to receive and pass solvent, the solvent conduit including a solvent valve; g) pump control means for controlling operation of the pump; h) purge gas valve control means for controlling operation of the purge gas valve to selectively impart flow of purge gas to the fluid source conduits, fluid target conduits and pump; i) solvent valve control means for controlling operation of the solvent valve to selectively impart flow of solvent to the fluid source conduits, fluid target conduits and pump; and j) source and target valve control means for controlling operation of the fluid source conduit valves and the fluid target conduit valves to selectively impart passage of fluid between a selected one of the fluid source conduits and a selected one of the fluid target conduits through the pump and to enable passage of solvent or purge gas through selected fluid source conduits and selected fluid target conduits.

  15. Multiple source/multiple target fluid transfer apparatus

    DOE Patents [OSTI]

    Turner, T.D.

    1997-08-26

    A fluid transfer apparatus includes: (a) a plurality of orifices for connection with fluid sources; (b) a plurality of orifices for connection with fluid targets; (c) a set of fluid source conduits and fluid target conduits associated with the orifices; (d) a pump fluidically interposed between the source and target conduits to transfer fluid there between; (e) a purge gas conduit in fluid communication with the fluid source conduits, fluid target conduits and pump to receive and pass a purge gas under pressure; (f) a solvent conduit in fluid communication with the fluid source conduits, fluid target conduits and pump to receive and pass solvent, the solvent conduit including a solvent valve; (g) pump control means for controlling operation of the pump; (h) purge gas valve control means for controlling operation of the purge gas valve to selectively impart flow of purge gas to the fluid source conduits, fluid target conduits and pump; (i) solvent valve control means for controlling operation of the solvent valve to selectively impart flow of solvent to the fluid source conduits, fluid target conduits and pump; and (j) source and target valve control means for controlling operation of the fluid source conduit valves and the fluid target conduit valves to selectively impart passage of fluid between a selected one of the fluid source conduits and a selected one of the fluid target conduits through the pump and to enable passage of solvent or purge gas through selected fluid source conduits and selected fluid target conduits. 6 figs.

  16. Durable metallized polymer mirror

    DOE Patents [OSTI]

    Schissel, P.O.; Kennedy, C.E.; Jorgensen, G.J.; Shinton, Y.D.; Goggin, R.M.

    1994-11-01

    A metallized polymer mirror construction is disclosed having improved durability against delamination and tunneling, comprising: an outer layer of polymeric material; a metal oxide layer underlying the outer layer of polymeric material; a silver reflective layer underneath the metal oxide layer; and a layer of adhesive attaching the silver layer to a substrate. 6 figs.

  17. Durable metallized polymer mirror

    DOE Patents [OSTI]

    Schissel, Paul O.; Kennedy, Cheryl E.; Jorgensen, Gary J.; Shinton, Yvonne D.; Goggin, Rita M.

    1994-01-01

    A metallized polymer mirror construction having improved durability against delamination and tunneling, comprising: an outer layer of polymeric material; a metal oxide layer underlying the outer layer of polymeric material; a silver reflective layer underneath the metal oxide layer; and a layer of adhesive attaching the silver layer to a substrate.

  18. Fluid control structures in microfluidic devices

    DOE Patents [OSTI]

    Mathies, Richard A.; Grover, William H.; Skelley, Alison; Lagally, Eric; Liu, Chung N.

    2008-11-04

    Methods and apparatus for implementing microfluidic analysis devices are provided. A monolithic elastomer membrane associated with an integrated pneumatic manifold allows the placement and actuation of a variety of fluid control structures, such as structures for pumping, isolating, mixing, routing, merging, splitting, preparing, and storing volumes of fluid. The fluid control structures can be used to implement a variety of sample introduction, preparation, processing, and storage techniques.

  19. Vibratory pumping of a free fluid stream

    DOE Patents [OSTI]

    Merrigan, Michael A.; Woloshun, Keith A.

    1990-01-01

    A vibratory fluid pump having a force generator for generating asymmetric periodic waves or oscillations connected to one end of one or more fluid conveyance means, such as filaments. The opposite ends of the filaments are connected to springs. Fluid introduced onto the filaments will traverse along the filaments according to the magnitude of the positive and negative excursions of the periodic waves or oscillations, and can be recovered from the filaments.

  20. Vibratory pumping of a free fluid stream

    DOE Patents [OSTI]

    Merrigan, M.A.; Woloshun, K.A.

    1990-11-13

    A vibratory fluid pump is described having a force generator for generating asymmetric periodic waves or oscillations connected to one end of one or more fluid conveyance means, such as filaments. The opposite ends of the filaments are connected to springs. Fluid introduced onto the filaments will traverse along the filaments according to the magnitude of the positive and negative excursions of the periodic waves or oscillations, and can be recovered from the filaments. 3 figs.

  1. Value for controlling flow of cryogenic fluid

    DOE Patents [OSTI]

    Knapp, Philip A.

    1996-01-01

    A valve is provided for accurately controlling the flow of cryogenic fluids such as liquid nitrogen. The valve comprises a combination of disc and needle valves affixed to a valve stem in such a manner that the disc and needle are free to rotate about the stem, but are constrained in lateral and vertical movements. This arrangement provides accurate and precise fluid flow control and positive fluid isolation.

  2. Conductivity measurements on H2O-bearing CO2-rich fluids

    SciTech Connect (OSTI)

    Capobianco, Ryan [Virginia Polytechnic Institute and State University; Gruszkiewicz, Miroslaw {Mirek} S [ORNL; Bodnar, Robert [Virginia Polytechnic Institute and State University; Rimstidt, J. Donald [Virginia Polytechnic Institute and State University

    2015-01-01

    Recent studies report rapid corrosion of metals and carbonation of minerals in contact with carbon dioxide containing trace amounts of dissolved water. One explanation for this behavior is that addition of small amounts of H2O to CO2 leads to significant ionization within the fluid, thus promoting reactions at the fluid-solid interface analogous to corrosion associated with aqueous fluids. The extent of ionization in the bulk CO2 fluid was determined using a flow-through conductivity cell capable of detecting very low conductivities. Experiments were conducted from 298 to 473 K and 7.39 to 20 MPa with H2O concentrations up to ~1600 ppmw (xH2O 3.9 10-3), corresponding to the H2O solubility limit in liquid CO2 at ambient temperature. All solutions showed conductivities <10 nS/cm, indicating that the solutions were essentially ion-free. This observation suggests that the observed corrosion and carbonation reactions are not the result of ionization in CO2-rich bulk phase, but does not preclude ionization in the fluid at the fluid-solid interface.

  3. Conductivity measurements on H2O-bearing CO2-rich fluids

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Capobianco, Ryan M.; Miroslaw S. Gruszkiewicz; Bodnar, Robert J.; Rimstidt, J. Donald

    2014-09-10

    Recent studies report rapid corrosion of metals and carbonation of minerals in contact with carbon dioxide containing trace amounts of dissolved water. One explanation for this behavior is that addition of small amounts of H2O to CO2 leads to significant ionization within the fluid, thus promoting reactions at the fluid-solid interface analogous to corrosion associated with aqueous fluids. The extent of ionization in the bulk CO2 fluid was determined using a flow-through conductivity cell capable of detecting very low conductivities. Experiments were conducted from 298 to 473 K and 7.39 to 20 MPa with H2O concentrations up to ~1600 ppmwmore » (xH2O ≈ 3.9 x 10-3), corresponding to the H2O solubility limit in liquid CO2 at ambient temperature. All solutions showed conductivities <10 nS/cm, indicating that the solutions were essentially ion-free. Furthermore, this observation suggests that the observed corrosion and carbonation reactions are not the result of ionization in CO2-rich bulk phase, but does not preclude ionization in the fluid at the fluid-solid interface.« less

  4. Pressurized-fluid-operated engine

    SciTech Connect (OSTI)

    Holleyman, J.E.

    1990-01-30

    This patent describes a pressurized-fluid-operated reciprocating engine for providing output power by use of a pressurized gas that expands within the engine without combustion. It comprises: an engine block having a plurality of cylinders within which respective pistons are reciprocatable to provide a rotary power output; gas inlet means connected with the engine block for introducing a pressurized gas into the respective cylinders in a predetermined, timed relationship to provide a smooth power output from the engine; gas outlet means connected with the engine block for conveying exhaust gas from the respective cylinders after the gas expanded to move the pistons within the cylinders; and recirculation means extending between the inlet means and the outlet means for recirculation a predetermined quantity of exhaust gas. The recirculation means including ejector means for drawing exhaust gas into the recirculation means.

  5. Immersible solar heater for fluids

    DOE Patents [OSTI]

    Kronberg, J.W.

    1995-07-11

    An immersible solar heater is described comprising a light-absorbing panel attached to a frame for absorbing heat energy from the light and transferring the absorbed heat energy directly to the fluid in which the heater is immersed. The heater can be used to heat a swimming pool, for example, and is held in position and at a preselected angle by a system of floats, weights and tethers so that the panel can operate efficiently. A skid can be used in one embodiment to prevent lateral movement of the heater along the bottom of the pool. Alternative embodiments include different arrangements of the weights, floats and tethers and methods for making the heater. 11 figs.

  6. Immersible solar heater for fluids

    DOE Patents [OSTI]

    Hazen, T.C.; Fliermans, C.B.

    1994-01-01

    An immersible solar heater is described comprising a light-absorbing panel attached to a frame for absorbing heat energy from the light and transferring the absorbed heat energy directly to the fluid in which the heater is immersed. The heater can be used to heat a swimming pool, for example, and is held in position and at a preselected angle by a system of floats, weights and tethers so that the panel can operate efficiently. A skid can be used in one embodiment to prevent lateral movement of the heater along the bottom of the pool. Alternative embodiments include different arrangements of the weights, floats and tethers and methods for making the heater.

  7. DISPLAYING AND INTERPRETING FLUID INCLUSION STRATIGRAPHY ANALYSES...

    Open Energy Info (EERE)

    DISPLAYING AND INTERPRETING FLUID INCLUSION STRATIGRAPHY ANALYSES ON MUDLOG GRAPHS Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Proceedings:...

  8. Nano Particles - Supercritical Fluid Process - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solar Photovoltaic Solar Photovoltaic Find More Like This Return to Search Nano Particles ... Applications and Industries Nano particles, supercritical fluid, photovoltaic devices, ...

  9. Gas powered fluid gun with recoil mitigation

    DOE Patents [OSTI]

    Grubelich, Mark C; Yonas, Gerold

    2013-11-12

    A gas powered fluid gun for propelling a stream or slug of a fluid at high velocity toward a target. Recoil mitigation is provided that reduces or eliminates the associated recoil forces, with minimal or no backwash. By launching a quantity of water in the opposite direction, net momentum forces are reduced or eliminated. Examples of recoil mitigation devices include a cone for making a conical fluid sheet, a device forming multiple impinging streams of fluid, a cavitating venturi, one or more spinning vanes, or an annular tangential entry/exit.

  10. Gas powered fluid gun with recoil mitigation

    DOE Patents [OSTI]

    Grubelich, Mark C.; Yonas, Gerold

    2016-03-01

    A gas powered fluid gun for propelling a stream or slug of a fluid at high velocity toward a target. Recoil mitigation is provided that reduces or eliminates the associated recoil forces, with minimal or no backwash. By launching a quantity of water in the opposite direction, net momentum forces are reduced or eliminated. Examples of recoil mitigation devices include a cone for making a conical fluid sheet, a device forming multiple impinging streams of fluid, a cavitating venturi, one or more spinning vanes, or an annular tangential entry/exit.

  11. Preparation, Injection and Combustion of Supercritical Fluids...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Volatility of Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection Evaluation of Biodiesel Fuels from Supercritical Fluid Processing with the Advanced Distillation ...

  12. Heat Transfer Fluids Containing Nanoparticles | Argonne National...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heat Transfer Fluids Containing Nanoparticles Technology available for licensing: A stable, nonreactive nanofluid that exhibits enhanced heat transfer properties with only a minimal ...

  13. Fluid Submersible Sensing Device - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Technology Publications: PDF Document Publication WO2010151470A1.pdf (476 KB) Technology Marketing Summary The present invention relates to a fluid submersible sensing device and,...

  14. Coupled Fluid Energy Solute Transport

    Energy Science and Technology Software Center (OSTI)

    1992-02-13

    CFEST is a Coupled Fluid, Energy, and Solute Transport code for the study of a multilayered, nonisothermal ground-water system. It can model discontinuous as well as continuous layers, time-dependent and constant source/sinks, and transient as well as steady-state flow. The finite element method is used for analyzing isothermal and nonisothermal events in a confined aquifer system. Only single-phase Darcian flow is considered. In the Cartesian coordinate system, flow in a horizontal plane, in a verticalmore » plane, or in a fully three-dimensional region can be simulated. An option also exists for the axisymmetric analysis of a vertical cross section. The code employs bilinear quadrilateral elements in all two dimensional analyses and trilinear quadrilateral solid elements in three dimensional simulations. The CFEST finite element formulation can approximate discontinuities, major breaks in slope or thickness, and fault zones in individual hydrogeologic units. The code accounts for heterogeneity in aquifer permeability and porosity and accommodates anisotropy (collinear with the Cartesian coordinates). The variation in the hydraulic properties is described on a layer-by-layer basis for the different hydrogeologic units. Initial conditions can be prescribed hydraulic head or pressure, temperature, or concentration. CFEST can be used to support site, repository, and waste package subsystem assessments. Some specific applications are regional hydrologic characterization; simulation of coupled transport of fluid, heat, and salinity in the repository region; consequence assessment due to natural disruption or human intrusion scenarios in the repository region; flow paths and travel-time estimates for transport of radionuclides; and interpretation of well and tracer tests.« less

  15. Electrolytic purification of metals

    DOE Patents [OSTI]

    Bowman, Kenneth A.

    1980-01-01

    A method of electrolytically separating metal from impurities comprises providing the metal and impurities in a molten state in a container having a porous membrane therein, the membrane having a thickness in the range of about 0.01 to 0.1 inch, being capable of containing the molten metal in the container, and being permeable by a molten electrolyte. The metal is electrolytically transferred through the membrane to a cathode in the presence of the electrolyte for purposes of separating or removing impurities from the metal.

  16. Conditions for fluid separations in microchannels, capillary-driven fluid separations, and laminated devices capable of separating fluids

    DOE Patents [OSTI]

    TeGrotenhuis, Ward E.; Stenkamp, Victoria S.

    2008-03-18

    Methods of separating fluids using capillary forces and/or improved conditions for are disclosed. The improved methods may include control of the ratio of gas and liquid Reynolds numbers relative to the Suratman number. Also disclosed are wick-containing, laminated devices that are capable of separating fluids.

  17. Conditions for fluid separations in microchannels, capillary-driven fluid separations, and laminated devices capable of separating fluids

    DOE Patents [OSTI]

    TeGrotenhuis, Ward E [Kennewick, WA; Stenkamp, Victoria S [Richland, WA

    2005-04-05

    Methods of separating fluids using capillary forces and/or improved conditions for are disclosed. The improved methods may include control of the ratio of gas and liquid Reynolds numbers relative to the Suratman number. Also disclosed are wick-containing, laminated devices that are capable of separating fluids.

  18. Method and apparatus for ion sequestration and a nanostructured metal phosphate

    DOE Patents [OSTI]

    Mattigod, Shas V.; Fryxell, Glen E.; Li, Xiaohong; Parker, Kent E.; Wellman, Dawn M.

    2010-04-06

    A nanostructured substance, a process for sequestration of ionic waste, and an ion-sequestration apparatus are disclosed in the specification. The nanostructured substance can comprise a Lewis acid transition metal bound to a phosphate, wherein the phosphate comprises a primary structural component of the substance and the Lewis acid transition metal is a reducing agent. The nanostructured substance has a Brunner-Emmet-Teller (BET) surface area greater than or equal to approximately 100 m.sup.2/g, and a distribution coefficient for an analyte, K.sub.d, greater than or equal to approximately 5000 ml/g. The process can comprise contacting a fluid and a nanostructured metal phosphate. The apparatus can comprise a vessel and a nanostructured metal phosphate. The vessel defines a volume wherein a fluid contacts the nanostructured metal phosphate.

  19. System and method for filling a plurality of isolated vehicle fluid circuits through a common fluid fill port

    DOE Patents [OSTI]

    Sullivan, Scott C; Fansler, Douglas

    2014-10-14

    A vehicle having multiple isolated fluid circuits configured to be filled through a common fill port includes a first fluid circuit disposed within the vehicle, the first fluid circuit having a first fill port, a second fluid circuit disposed within the vehicle, and a conduit defining a fluid passageway between the first fluid circuit and second fluid circuit, the conduit including a valve. The valve is configured such that the first and second fluid circuits are fluidly coupled via the passageway when the valve is open, and are fluidly isolated when the valve is closed.

  20. Hydrostatic bearings for a turbine fluid flow metering device

    DOE Patents [OSTI]

    Fincke, J.R.

    1980-05-02

    A rotor assembly fluid metering device has been improved by development of a hydrostatic bearing fluid system which provides bearing fluid at a common pressure to rotor assembly bearing surfaces. The bearing fluid distribution system produces a uniform film of fluid distribution system produces a uniform film of fluid between bearing surfaces and allows rapid replacement of bearing fluid between bearing surfaces, thereby minimizing bearing wear and corrosion.

  1. Fluid dynamic effects on precision cleaning with supercritical fluids

    SciTech Connect (OSTI)

    Phelps, M.R.; Hogan, M.O.; Silva, L.J.

    1994-06-01

    Pacific Northwest Laboratory staff have assembled a small supercritical fluids parts cleaning test stand to characterize how system dynamics affect the efficacy of precision cleaning with supercritical carbon dioxide. A soiled stainless steel coupon, loaded into a ``Berty`` autoclave, was used to investigate how changes in system turbulence and solvent temperature influenced the removal of test dopants. A pulsed laser beam through a fiber optic was used to investigate real-time contaminant removal. Test data show that cleaning efficiency is a function of system agitation, solvent density, and temperature. These data also show that high levels of cleaning efficiency can generally be achieved with high levels of system agitation at relatively low solvent densities and temperatures. Agitation levels, temperatures, and densities needed for optimal cleaning are largely contaminant dependent. Using proper system conditions, the levels of cleanliness achieved with supercritical carbon dioxide compare favorably with conventional precision cleaning methods. Additional research is currently being conducted to generalize the relationship between cleaning performance and parameters such as contaminant solubilities, mass transfer rates, and solvent agitation. These correlations can be used to optimize cleaning performance, system design, and time and energy consumption for particular parts cleaning applications.

  2. Extraction process for removing metallic impurities from alkalide metals

    DOE Patents [OSTI]

    Royer, L.T.

    1987-03-20

    A development is described for removing metallic impurities from alkali metals by employing an extraction process wherein the metallic impurities are extracted from a molten alkali metal into molten lithium metal due to the immiscibility of the alkali metals in lithium and the miscibility of the metallic contaminants or impurities in the lithium. The purified alkali metal may be readily separated from the contaminant-containing lithium metal by simple decanting due to the differences in densities and melting temperatures of the alkali metals as compared to lithium.

  3. Review - basic research needs in fluid mechanics

    SciTech Connect (OSTI)

    Jones, O.C. Jr.; Kreith, F.; White, F.M.

    1981-12-01

    A small segment of the engineering community was surveyed to obtain their judgement regarding the long-range needs for basic research in fluid mechanics. It is the purpose of this paper to provide a summary of a more detailed report, which identifies basic research needed in fluid mechanics. 12 refs.

  4. Foam vessel for cryogenic fluid storage

    DOE Patents [OSTI]

    Spear, Jonathan D

    2011-07-05

    Cryogenic storage and separator vessels made of polyolefin foams are disclosed, as are methods of storing and separating cryogenic fluids and fluid mixtures using these vessels. In one embodiment, the polyolefin foams may be cross-linked, closed-cell polyethylene foams with a density of from about 2 pounds per cubic foot to a density of about 4 pounds per cubic foot.

  5. Fluid permeability measurement system and method

    DOE Patents [OSTI]

    Hallman, Jr., Russell Louis; Renner, Michael John

    2008-02-05

    A system for measuring the permeance of a material. The permeability of the material may also be derived. The system provides a liquid or high concentration fluid bath on one side of a material test sample, and a gas flow across the opposing side of the material test sample. The mass flow rate of permeated fluid as a fraction of the combined mass flow rate of gas and permeated fluid is used to calculate the permeance of the material. The material test sample may be a sheet, a tube, or a solid shape. Operational test conditions may be varied, including concentration of the fluid, temperature of the fluid, strain profile of the material test sample, and differential pressure across the material test sample.

  6. Systems, compositions, and methods for fluid purification

    SciTech Connect (OSTI)

    Ho, W.S. Winston; Verweij, Hendrik; Shqau, Krenar; Ramasubranian, Kartik

    2015-12-22

    Disclosed herein are membranes comprising a substrate, a support layer, and a selective layer. In some embodiments the membrane may further comprise a permeable layer. Methods of forming membranes are also disclosed comprising forming a support layer on a substrate, removing adsorbed species from the support layer, preparing a solution containing inorganic materials of a selective layer, contacting the support layer with the solution, drying the membrane, and exposing the membrane to rapid thermal processing. Also disclosed are methods of fluid purification comprising providing a membrane having a feed side and a permeable side, passing a fluid mixture across the feed side of the membrane, providing a driving force for transmembrane permeation, removing from the permeate side a permeate stream enriched in a purified fluid, and withdrawing from the feed side a fluid that is depleted in a purified fluid.

  7. Extreme pressure fluid sample transfer pump

    DOE Patents [OSTI]

    Halverson, Justin E.; Bowman, Wilfred W.

    1990-01-01

    A transfer pump for samples of fluids at very low or very high pressures comprising a cylinder having a piston sealed with an O-ring, the piston defining forward and back chambers, an inlet and exit port and valve arrangement for the fluid to enter and leave the forward chamber, and a port and valve arrangement in the back chamber for adjusting the pressure across the piston so that the pressure differential across the piston is essentially zero and approximately equal to the pressure of the fluid so that the O-ring seals against leakage of the fluid and the piston can be easily moved, regardless of the pressure of the fluid. The piston may be actuated by a means external to the cylinder with a piston rod extending through a hole in the cylinder sealed with a bellows attached to the piston head and the interior of the back chamber.

  8. A scintillator purification plant and fluid handling system for SNO+

    SciTech Connect (OSTI)

    Ford, Richard J.

    2015-08-17

    A large capacity purification plant and fluid handling system has been constructed for the SNO+ neutrino and double-beta decay experiment, located 6800 feet underground at SNOLAB, Canada. SNO+ is a refurbishment of the SNO detector to fill the acrylic vessel with liquid scintillator based on Linear Alkylbenzene (LAB) and 2 g/L PPO, and also has a phase to load natural tellurium into the scintillator for a double-beta decay experiment with {sup 130}Te. The plant includes processes multi-stage dual-stream distillation, column water extraction, steam stripping, and functionalized silica gel adsorption columns. The plant also includes systems for preparing the scintillator with PPO and metal-loading the scintillator for double-beta decay exposure. We review the basis of design, the purification principles, specifications for the plant, and the construction and installations. The construction and commissioning status is updated.

  9. Surging fluids downhole in an earth borehole

    SciTech Connect (OSTI)

    Wesson, D.S.; Edwards, A.G.; George, F.R.; George, K.R.; Brieger, E.F.

    1987-04-21

    An annulus pressure responsive surge tool is described for use in a conduit string in a well bore having fluid filling the annulus between the conduit string and the well bore. The annulus pressure responsive surge tool comprises; a housing having a bore therethrough, a first aperture therein to allow communication of the fluid from the exterior of the housing to the bore therethrough, and a second aperture therein to allow communication of the fluid from the exterior of the housing to the bore therethrough; a frangible closure member retained within the bore of the housing sealingly closing the same from fluid therethrough; a first annular piston slidable within a portion of the bore of the housing having, in turn, a bore therethrough, a portion of the exterior of the first annular piston sealingly engaging a portion of the bore of the housing to form a chamber containing a compressible fluid under pressure therein at a pressure less than the pressure of the fluid in the annulus. A portion of the first annular piston is in fluid communication through the first aperture in the housing with the fluid in the annulus; a second annular piston slidable within a portion of the bore of the housing having, in turn, a bore therethrough, a portion of the second annular piston abutting a portion of the first piston, a portion of the second annular piston sealingly engaging a portion of the bore of the housing, and a portion of the second annular piston in fluid communication through the second aperture in the housing with the fluid in the annulus; and first releasable locking means retained within a portion of the bore in the housing having a portion thereof releasably retaining the first piston in a first position in the bore in the housing.

  10. Metal binding proteins, recombinant host cells and methods

    DOE Patents [OSTI]

    Summers, Anne O.; Caguiat, Jonathan J.

    2004-06-15

    The present disclosure provides artificial heavy metal binding proteins termed chelons by the inventors. These chelons bind cadmium and/or mercuric ions with relatively high affinity. Also disclosed are coding sequences, recombinant DNA molecules and recombinant host cells comprising those recombinant DNA molecules for expression of the chelon proteins. In the recombinant host cells or transgenic plants, the chelons can be used to bind heavy metals taken up from contaminated soil, groundwater or irrigation water and to concentrate and sequester those ions. Recombinant enteric bacteria can be used within the gastrointestinal tracts of animals or humans exposed to toxic metal ions such as mercury and/or cadmium, where the chelon recombinantly expressed in chosen in accordance with the ion to be rededicated. Alternatively, the chelons can be immobilized to solid supports to bind and concentrate heavy metals from a contaminated aqueous medium including biological fluids.

  11. "End Use","for Electricity(a)","Fuel Oil","Diesel Fuel(b)","Natural Gas(c)","NGL(d)","Coke and Breeze)"

    U.S. Energy Information Administration (EIA) Indexed Site

    8 Relative Standard Errors for Table 5.8;" " Unit: Percents." ,,,"Distillate" ,,,"Fuel Oil",,,"Coal" ,"Net Demand","Residual","and",,"LPG and","(excluding Coal" "End Use","for Electricity(a)","Fuel Oil","Diesel Fuel(b)","Natural Gas(c)","NGL(d)","Coke and Breeze

  12. FORMING PROTECTIVE FILMS ON METAL

    DOE Patents [OSTI]

    Gurinsky, D.H.; Kammerer, O.F.; Sadofsky, J.; Weeks, J.R.

    1958-12-16

    Methods are described of inhibiting the corrosion of ferrous metal by contact with heavy liquid metals such as bismuth and gallium at temperatures above 500 icient laborato C generally by bringing nltrogen and either the metal zirconium, hafnium, or titanium into reactlve contact with the ferrous metal to form a thin adherent layer of the nitride of the metal and thereafter maintaining a fractional percentage of the metal absorbed in the heavy liquid metal in contact with the ferrous metal container. The general purpose for uslng such high boiling liquid metals in ferrous contalners would be as heat transfer agents in liquid-metal-fueled nuclear reactors.

  13. Heat exchanger with intermediate evaporating and condensing fluid

    DOE Patents [OSTI]

    Fraas, Arthur P.

    1978-01-01

    A shell and tube-type heat exchanger, such as a liquid sodium-operated steam generator for use in nuclear reactors, comprises a shell containing a primary fluid tube bundle, a secondary fluid tube bundle at higher elevation, and an intermediate fluid vaporizing at the surface of the primary fluid tubes and condensing at the surface of the secondary fluid tubes.

  14. Light metal production

    DOE Patents [OSTI]

    Fan, Qinbai

    2016-04-19

    An electrochemical process for the production of light metals, particularly aluminum. Such a process involves contacting a light metal source material with an inorganic acid to form a solution containing the light metal ions in high concentration. The solution is fed to an electrochemical reactor assembly having an anode side containing an anode and a cathode side containing a cathode, with anode side and the cathode side separated by a bipolar membrane, with the solution being fed to the anode side. Light metal ions are electrochemically transferred through the bipolar membrane to the cathode side. The process further involves reducing the light metal ions to light metal powder. An associated processing system is also provided.

  15. Magnetic separation of micro-spheres from viscous biological fluids.

    SciTech Connect (OSTI)

    Chen, H.; Kaminski, M. D.; Xianqiao, L.; Caviness, P.; Torno, M.; Rosengart, A. J.; Dhar, P.; Chemical Engineering; Univ. of Chicago Pritzker School of Medicine; Illinois Inst. of Tech.

    2007-02-21

    A magnetically based detoxification system is being developed as a therapeutic tool for selective and rapid removal of biohazards, i.e. chemicals and radioactive substances, from human blood. One of the key components of this system is a portable magnetic separator capable of separating polymer-based magnetic nano/micro-spheres from arterial blood flow in an ex vivo unit. The magnetic separator consists of an array of alternating and parallel capillary tubing and magnetizable wires, which is exposed to an applied magnetic field created by two parallel permanent magnets such that the magnetic field is perpendicular to both the wires and the fluid flow. In this paper, the performance of this separator was evaluated via preliminary in vitro flow experiments using a separator unit consisting of single capillary glass tubing and two metal wires. Pure water, ethylene glycol-water solution (v:v = 39:61 and v:v = 49:51) and human whole blood were used as the fluids. The results showed that when the viscosity increased from 1.0 cp to 3.0 cp, the capture efficiency (CE) decreased from 90% to 56%. However, it is still feasible to obtain >90% CE in blood flow if the separator design is optimized to create higher magnetic gradients and magnetic fields in the separation area.

  16. Metal atomization spray nozzle

    DOE Patents [OSTI]

    Huxford, T.J.

    1993-11-16

    A spray nozzle for a magnetohydrodynamic atomization apparatus has a feed passage for molten metal and a pair of spray electrodes mounted in the feed passage. The electrodes, diverging surfaces which define a nozzle throat and diverge at an acute angle from the throat. Current passes through molten metal when fed through the throat which creates the Lorentz force necessary to provide atomization of the molten metal. 6 figures.

  17. Metal atomization spray nozzle

    DOE Patents [OSTI]

    Huxford, Theodore J.

    1993-01-01

    A spray nozzle for a magnetohydrodynamic atomization apparatus has a feed passage for molten metal and a pair of spray electrodes mounted in the feed passage. The electrodes, diverging surfaces which define a nozzle throat and diverge at an acute angle from the throat. Current passes through molten metal when fed through the throat which creates the Lorentz force necessary to provide atomization of the molten metal.

  18. Metal atom oxidation laser

    DOE Patents [OSTI]

    Jensen, R.J.; Rice, W.W.; Beattie, W.H.

    1975-10-28

    A chemical laser which operates by formation of metal or carbon atoms and reaction of such atoms with a gaseous oxidizer in an optical resonant cavity is described. The lasing species are diatomic or polyatomic in nature and are readily produced by exchange or other abstraction reactions between the metal or carbon atoms and the oxidizer. The lasing molecules may be metal or carbon monohalides or monoxides. (auth)

  19. Metal atom oxidation laser

    DOE Patents [OSTI]

    Jensen, R.J.; Rice, W.W.; Beattie, W.H.

    1975-10-28

    A chemical laser which operates by formation of metal or carbon atoms and reaction of such atoms with a gaseous oxidizer in an optical resonant cavity is described. The lasing species are diatomic or polyatomic in nature and are readily produced by exchange or other abstraction reactions between the metal or carbon atoms and the oxidizer. The lasing molecules may be metal or carbon monohalides or monoxides.

  20. Supported metal alloy catalysts

    DOE Patents [OSTI]

    Barrera, Joseph; Smith, David C.

    2000-01-01

    A process of preparing a Group IV, V, or VI metal carbonitride including reacting a Group IV, V, or VI metal amide complex with ammonia to obtain an intermediate product; and, heating the intermediate product to temperatures and for times sufficient to form a Group IV, V, or VI metal carbonitride is provided together with the product of the process and a process of reforming an n-alkane by use of the product.

  1. Closed cell metal foam method

    DOE Patents [OSTI]

    Patten, James W.

    1978-01-01

    Foamed metals and metal alloys which have a closed cellular structure are prepared by heating a metal body containing entrapped inert gas uniformly distributed throughout to a temperature above the melting point of the metal and maintaining the body at this temperature a period of time sufficient to permit the entrapped gas to expand, forming individual cells within the molten metal, thus expanding and foaming the molten metal. After cell formation has reached the desired amount, the foamed molten metal body is cooled to below the melting temperature of the metal. The void area or density of the foamed metal is controlled by predetermining the amount of inert gas entrapped in the metal body and by the period of time the metal body is maintained in the molten state. This method is useful for preparing foamed metals and metal alloys from any metal or other material of which a body containing entrapped inert gas can be prepared.

  2. Dissolution rate and radiation dosimetry of metal tritides

    SciTech Connect (OSTI)

    Jow, Hong-Nian; Cheng, Yung-Sung

    1993-06-01

    Metal tritides including titanium tritide (Ti{sup 3}H{sub x}) and erbium tritide (Er{sup 3}H{sub x}) have been used as components of neutron generators. These compounds can be released to the air as aerosols during fabrication, assembling and testing of components or in accidental or fugitive releases. As a result, workers could be exposed to these compounds by inhalation. A joint research project between SNL and ITRI (Inhalation Toxicology Research Institute) was initiated last fall to investigate the solubility of metal tritides, retention and translocation of inhaled particles and internal dosimetry of metal tritides. The current understanding of metal tritides and their radiation dosimetry for internal exposure are very limited. There is no provision in the ICRP-30 for tritium dosimetry in metal tritide form. However, a few papers in the literature suggested that the solubility of metal tritide could be low. The current radiation protection guidelines for metal tritide particles are based on the assumption that the biological behavior is similar to tritiated water which behaves like body fluid with a relative short biological half life (10 days). If the solubility of metal tritide is low, the biological half life of metal tritide particles and the dosimetry of inhalation exposure to these particles could be quite different from tritiated water. This would have major implications in current radiation protection guidelines for metal tritides Including annual limits of intakes and derived air concentrations. The preliminary results of metal tritide dissolution study at ITRI indicate that the solubility of titanium tritide is low. The outlines of the project, the preliminary results and future work will be discussed in presentation.

  3. Probing metal solidification nondestructively

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    provide the insight needed to control the microstructure of metals and lead to advanced manufacturing processes to produce materials with desired properties. Los Alamos...

  4. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in both in technological and biological processes that are often governed by careful control over the physical and chemical properties of metal-oxygen bonds. For example,...

  5. Method of producing homogeneous mixed metal oxides and metal-metal oxide mixtures

    DOE Patents [OSTI]

    Quinby, Thomas C.

    1978-01-01

    Metal powders, metal oxide powders, and mixtures thereof of controlled particle size are provided by reacting an aqueous solution containing dissolved metal values with excess urea. Upon heating, urea reacts with water from the solution leaving a molten urea solution containing the metal values. The molten urea solution is heated to above about 180.degree. C. whereupon metal values precipitate homogeneously as a powder. The powder is reduced to metal or calcined to form oxide particles. One or more metal oxides in a mixture can be selectively reduced to produce metal particles or a mixture of metal and metal oxide particles.

  6. CO2-fluxing collapses metal mobility in magmatic vapour

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    van Hinsberg, V. J.; Berlo, K.; Migdisov, A. A.; Williams-Jones, A. E.

    2016-05-18

    Magmatic systems host many types of ore deposits, including world-class deposits of copper and gold. Magmas are commonly an important source of metals and ore-forming fluids in these systems. In many magmatic-hydrothermal systems, low-density aqueous fluids, or vapours, are significant metal carriers. Such vapours are water-dominated shallowly, but fluxing of CO2-rich vapour exsolved from deeper magma is now recognised as ubiquitous during open-system magma degassing. Furthermore, we show that such CO2-fluxing leads to a sharp drop in element solubility, up to a factor of 10,000 for Cu, and thereby provides a highly efficient, but as yet unrecognised mechanism for metalmore » deposition.« less

  7. Hamiltonian description of the ideal fluid

    SciTech Connect (OSTI)

    Morrison, P.J.

    1994-01-01

    Fluid mechanics is examined from a Hamiltonian perspective. The Hamiltonian point of view provides a unifying framework; by understanding the Hamiltonian perspective, one knows in advance (within bounds) what answers to expect and what kinds of procedures can be performed. The material is organized into five lectures, on the following topics: rudiments of few-degree-of-freedom Hamiltonian systems illustrated by passive advection in two-dimensional fluids; functional differentiation, two action principles of mechanics, and the action principle and canonical Hamiltonian description of the ideal fluid; noncanonical Hamiltonian dynamics with examples; tutorial on Lie groups and algebras, reduction-realization, and Clebsch variables; and stability and Hamiltonian systems.

  8. Geothermal energy production with supercritical fluids

    DOE Patents [OSTI]

    Brown, Donald W.

    2003-12-30

    There has been invented a method for producing geothermal energy using supercritical fluids for creation of the underground reservoir, production of the geothermal energy, and for heat transport. Underground reservoirs are created by pumping a supercritical fluid such as carbon dioxide into a formation to fracture the rock. Once the reservoir is formed, the same supercritical fluid is allowed to heat up and expand, then is pumped out of the reservoir to transfer the heat to a surface power generating plant or other application.

  9. Apparatus and method for fluid analysis

    DOE Patents [OSTI]

    Wilson, Bary W.; Peters, Timothy J.; Shepard, Chester L.; Reeves, James H.

    2004-11-02

    The present invention is an apparatus and method for analyzing a fluid used in a machine or in an industrial process line. The apparatus has at least one meter placed proximate the machine or process line and in contact with the machine or process fluid for measuring at least one parameter related to the fluid. The at least one parameter is a standard laboratory analysis parameter. The at least one meter includes but is not limited to viscometer, element meter, optical meter, particulate meter, and combinations thereof.

  10. Apparatus And Method For Fluid Analysis

    DOE Patents [OSTI]

    Wilson, Bary W.; Peters, Timothy J.; Shepard, Chester L.; Reeves, James H.

    2003-05-13

    The present invention is an apparatus and method for analyzing a fluid used in a machine or in an industrial process line. The apparatus has at least one meter placed proximate the machine or process line and in contact with the machine or process fluid for measuring at least one parameter related to the fluid. The at least one parameter is a standard laboratory analysis parameter. The at least one meter includes but is not limited to viscometer, element meter, optical meter, particulate meter, and combinations thereof.

  11. Creating fluid injectivity in tar sands formations

    DOE Patents [OSTI]

    Stegemeier, George Leo; Beer, Gary Lee; Zhang, Etuan

    2012-06-05

    Methods for treating a tar sands formation are described herein. Methods for treating a tar sands may include heating a portion of a hydrocarbon layer in the formation from one or more heaters located in the portion. The heat may be controlled to increase the permeability of at least part of the portion to create an injection zone in the portion with an average permeability sufficient to allow injection of a fluid through the injection zone. A drive fluid and/or an oxidizing fluid may be provided into the injection zone. At least some hydrocarbons including mobilized hydrocarbons are produced from the portion.

  12. Creating fluid injectivity in tar sands formations

    DOE Patents [OSTI]

    Stegemeier, George Leo; Beer, Gary Lee; Zhang, Etuan

    2010-06-08

    Methods for treating a tar sands formation are described herein. Methods for treating a tar sands may include heating a portion of a hydrocarbon layer in the formation from one or more heaters located in the portion. The heat may be controlled to increase the permeability of at least part of the portion to create an injection zone in the portion with an average permeability sufficient to allow injection of a fluid through the injection zone. A drive fluid and/or an oxidizing fluid may be provided into the injection zone. At least some hydrocarbons are produced from the portion.

  13. Fluid properties determine flow line blockage potential

    SciTech Connect (OSTI)

    Hunt, A.

    1996-07-15

    A thorough understanding of fluid properties helps in determining the potential of hydrates, paraffins, or asphaltenes to block subsea flow lines. Thermal, chemical, and mechanical methods are the main ways for preventing deposition. Already in both the North Sea and the Gulf of Mexico, blockages have led to significant losses in production and reserves recovery. This first article in a two-part series discusses thermal and chemical methods in overcoming fluid behavior problems caused by hydrate and other fluid constituents in subsea multiphase flow. The paper discusses subsea production, possible problems, nucleation, growth, deposition, preventing deposition, hydrate predictions, multiphase flow, and hydrate inhibition.

  14. Silicon metal-semiconductor-metal photodetector

    DOE Patents [OSTI]

    Brueck, Steven R. J.; Myers, David R.; Sharma, Ashwani K.

    1997-01-01

    Silicon MSM photodiodes sensitive to radiation in the visible to near infrared spectral range are produced by altering the absorption characteristics of crystalline Si by ion implantation. The implantation produces a defected region below the surface of the silicon with the highest concentration of defects at its base which acts to reduce the contribution of charge carriers formed below the defected layer. The charge carriers generated by the radiation in the upper regions of the defected layer are very quickly collected between biased Schottky barrier electrodes which form a metal-semiconductor-metal structure for the photodiode.

  15. Silicon metal-semiconductor-metal photodetector

    DOE Patents [OSTI]

    Brueck, Steven R. J.; Myers, David R.; Sharma, Ashwani K.

    1995-01-01

    Silicon MSM photodiodes sensitive to radiation in the visible to near infrared spectral range are produced by altering the absorption characteristics of crystalline Si by ion implantation. The implantation produces a defected region below the surface of the silicon with the highest concentration of defects at its base which acts to reduce the contribution of charge carriers formed below the defected layer. The charge carriers generated by the radiation in the upper regions of the defected layer are very quickly collected between biased Schottky barrier electrodes which form a metal-semiconductor-metal structure for the photodiode.

  16. PRECISION CLEANING OF SEMICONDUCTOR SURFACES USING CARBON DIOXIDE-BASED FLUIDS

    SciTech Connect (OSTI)

    J. RUBIN; L. SIVILS; A. BUSNAINA

    1999-07-01

    The Los Alamos National Laboratory, on behalf of the Hewlett-Packard Company, is conducting tests of a closed-loop CO{sub 2}-based supercritical fluid process, known as Supercritical CO{sub 2} Resist Remover (SCORR). We have shown that this treatment process is effective in removing hard-baked, ion-implanted photoresists, and appears to be fully compatible with metallization systems. We are now performing experiments on production wafers to assess not only photoresist removal, but also residual surface contamination due to particulate and trace metals. Dense-phase (liquid or supercritical) CO{sub 2}, since it is non-polar, acts like an organic solvent and therefore has an inherently high volubility for organic compounds such as oils and greases. Also, dense CO{sub 2} has a low-viscosity and a low dielectric constant. Finally, CO{sub 2} in the liquid and supercritical fluid states can solubilize metal completing agents and surfactants. This combination of properties has interesting implications for the removal not only of organic films, but also trace metals and inorganic particulate. In this paper we discuss the possibility of using CO{sub 2} as a precision-cleaning solvent, with particular emphasis on semiconductor surfaces.

  17. Fluid Inclusion Analysis At Coso Geothermal Area (2004) | Open...

    Open Energy Info (EERE)

    DOE-funding Unknown Exploration Basis 1) To determine if analyses of fluid propene and propane species in fluid inclusions can be used to interpret fluid type, history, or process....

  18. Thermal Storage and Advanced Heat Transfer Fluids (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2010-08-01

    Fact sheet describing NREL CSP Program capabilities in the area of thermal storage and advanced heat transfer fluids: measuring thermophysical properties, measuring fluid flow and heat transfer, and simulating flow of thermal energy and fluid.

  19. Volume Comparison

    Gasoline and Diesel Fuel Update (EIA)

    Day) Process: Vacuum Distillation Thermal Cracking Thermal Cracking: Coking Thermal Cracking: Delayed Coking Thermal Cracking: Fluid Coking Thermal Cracking: Visbreaking Thermal Cracking: Other/Gas Oil Thermal Cracking: Coking (Barrels/Calendar Day) Catalytic Cracking Fresh Feed Catalytic Cracking Fresh Feed (Barrels/Calendar Day) Catalytic Cracking Recycled Feed Catalytic Hydrocracking Catalytic Hydrocracking: Distillate Catalytic Hydrocracking: Gas Oil Catalytic Hydrocracking: Residual Fuel

  20. Mapping Metals Incorporation of a Single Catalyst Particle Using Element

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Specific X-ray Nanotomography | Stanford Synchrotron Radiation Lightsource Mapping Metals Incorporation of a Single Catalyst Particle Using Element Specific X-ray Nanotomography Tuesday, March 31, 2015 Fluid catalytic cracking (FCC) is the refining process for converting large and/or heavy molecules of oil feedstock into smaller and lighter hydrocarbons, such as gasoline. The workhorse of the FCC process is a tiny catalyst particle of 50-150 µm diameter that consists of a complex mixture of

  1. Correlating Spatial Heterogeneities in Porosity and Permeability with Metal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Poisoning within an Individual Catalyst Particle using X-ray Microscopy | Stanford Synchrotron Radiation Lightsource Correlating Spatial Heterogeneities in Porosity and Permeability with Metal Poisoning within an Individual Catalyst Particle using X-ray Microscopy Wednesday, August 21, 2013 - 1:30pm SLAC, Conference Room 137-226 Presented by Darius Morris, Stanford Synchrotron Radiation Lightsource Fluid catalytic cracking (FCC) is a refining process for converting large and/or heavy

  2. Porous metallic bodies

    DOE Patents [OSTI]

    Landingham, R.L.

    1984-03-13

    Porous metallic bodies having a substantially uniform pore size of less than about 200 microns and a density of less than about 25 percent theoretical, as well as the method for making them, are disclosed. Group IIA, IIIB, IVB, VB, and rare earth metal hydrides a

  3. METAL SURFACE TREATMENT

    DOE Patents [OSTI]

    Eubank, L.D.

    1958-08-12

    Improved flux baths are described for use in conjunction with hot dipped coatings for uranium. The flux bath consists of molten alkali metal, or alkaline earth metal halides. One preferred embodiment comprises a bath containing molten KCl, NaCl, and LiCl in proportions approximating the triple eutectic.

  4. Metallic nanowire networks

    DOE Patents [OSTI]

    Song, Yujiang; Shelnutt, John A.

    2012-11-06

    A metallic nanowire network synthesized using chemical reduction of a metal ion source by a reducing agent in the presence of a soft template comprising a tubular inverse micellar network. The network of interconnected polycrystalline nanowires has a very high surface-area/volume ratio, which makes it highly suitable for use in catalytic applications.

  5. PRODUCTION OF PLUTONIUM METAL

    DOE Patents [OSTI]

    Lyon, W.L.; Moore, R.H.

    1961-01-17

    A process is given for producing plutonium metal by the reduction of plutonium chloride, dissolved in alkali metal chloride plus or minus aluminum chloride, with magnesium or a magnesium-aluminum alloy at between 700 and 800 deg C and separating the plutonium or plutonium-aluminum alloy formed from the salt.

  6. Method and apparatus for fluid dispersion

    DOE Patents [OSTI]

    Stone, Howard A.; Anna, Shelley L.; Bontoux, Nathalie; Link, Darren R.; Weitz, David A.; Gitlin, Irina; Kumacheva, Eugenia; Garstecki, Piotr; Diluzio, Willow; Whitesides, George M.

    2010-05-04

    A microfluidic method and device for focusing and/or forming discontinuous sections of similar or dissimilar size in a fluid is provided. The device can be fabricated simply from readily-available, inexpensive material using simple techniques.

  7. Method and apparatus for fluid dispersion

    DOE Patents [OSTI]

    Stone, Howard A; Anna, Shelley L; Bontoux, Nathalie; Link, Darren Roy; Weitz, David A; Gitlin, Irina; Kumacheva, Eugenia; Garstecki, Piotr; Diluzio, Willow R; Whitesides, George M

    2015-03-24

    A microfluidic method and device for focusing and/or forming discontinuous sections of similar or dissimilar size in a fluid is provided. The device can be fabricated simply from readily-available, inexpensive material using simple techniques.

  8. Method and apparatus for fluid dispersion

    DOE Patents [OSTI]

    Stone, Howard A.; Anna, Shelley L.; Bontoux, Nathalie; Link, Darren Roy; Weitz, David A.; Gitlin, Irina; Kumacheva, Eugenia; Garstecki, Piotr; Diluzio, Willow R.; Whitesides, George M.

    2012-12-25

    A microfluidic method and device for focusing and/or forming discontinuous sections of similar or dissimilar size in a fluid is provided. The device can be fabricated simply from readily-available, inexpensive material using simple techniques.

  9. Clay-based geothermal drilling fluids

    SciTech Connect (OSTI)

    Guven, N.; Carney, L.L.; Lee, L.J.; Bernhard, R.P.

    1982-11-01

    The rheological properties of fluids based on fibrous clays such as sepiolite and attapulgite have been systematically examined under conditions similar to those of geothermal wells, i.e. at elevated temperatures and pressures in environments with concentrated brines. Attapulgite- and sepiolite-based fluids have been autoclaved at temperatures in the range from 70 to 800/sup 0/F with the addition of chlorides and hydroxides of Na, K, Ca, and Mg. The rheological properties (apparent and plastic viscosity, fluid loss, gel strength, yield point, and cake thickness) of the autoclaved fluids have been studied and correlated with the chemical and physical changes that occur in the clay minerals during the autoclaving process.

  10. On the fluid mechanics of fires

    SciTech Connect (OSTI)

    TIESZEN,SHELDON R.

    2000-02-29

    Fluid mechanics research related to fire is reviewed with focus on canonical flows, multiphysics coupling aspects, experimental and numerical techniques. Fire is a low-speed, chemically-reacting, flow in which buoyancy plans an important role. Fire research has focused on two canonical flows, the reacting boundary-layer and the reacting free plume. There is rich, multi-lateral, bi-directional, coupling among fluid mechanics and scalar transport, combustion, and radiation. There is only a limited experimental fluid-mechanics database for fire due to measurement difficulties in the harsh environment, and the focus within the fire community on thermal/chemical consequences. Increasingly, computational fluid dynamics techniques are being used to provide engineering guidance on thermal/chemical consequences and to study fire phenomenology.

  11. Controlled in-situ dissolution of an alkali metal

    DOE Patents [OSTI]

    Jones, Jeffrey Donald; Dooley, Kirk John; Tolman, David Donald

    2012-09-11

    A method for the controllable dissolution of one or more alkali metals from a vessel containing a one or more alkali metals and/or one or more partially passivated alkali metals. The vessel preferably comprising a sodium, NaK or other alkali metal-cooled nuclear reactor that has been used. The alkali metal, preferably sodium, potassium or a combination thereof, in the vessel is exposed to a treatment liquid, preferably an acidic liquid, more preferably citric acid. Preferably, the treatment liquid is maintained in continuous motion relative to any surface of unreacted alkali metal with which the treatment liquid is in contact. The treatment liquid is preferably pumped into the vessel containing the one or more alkali metals and the resulting fluid is extracted and optionally further processed. Preferably, the resulting off-gases are processed by an off-gas treatment system and the resulting liquids are processed by a liquid disposal system. In one preferred embodiment, an inert gas is pumped into the vessel along with the treatment liquid.

  12. Dissolution rate and radiation dosimetry of metal tritides

    SciTech Connect (OSTI)

    Cheng, Y.

    1993-12-31

    Metal tritides including titanium tritide (Ti{sup 3}H{sub x}) and erbium tritide (Er{sup 3}H{sub x}) have been used as components of neutron generators. These compounds can be released to the air as aerosols during fabrication, assembling, and testing of components or in accidental or fugitive releases; as a result, workers may be exposed to these compounds by inhalation. A joint research project between Sandia National Laboratories and the Inhalation Toxicology Research Institute was initiated to investigate the solubility of metal tritide particles, to determine retention and translocation of inhaled particles in animals, and to develop an internal dosimetry model. The current understanding of metal tritides and their radiation dosimetry for internal exposure is very limited. The ICRP Report 30 does not provide for tritium dosimetry in metal tritide form. The current radiation protection guidelines for metal tritide particles are based on the assumption that the biological behavior is similar to tritiated water which could be easily absorbed into body fluid, and therefore, a relatively short biological half life (10 days). If the solubility is low, the biological half life of metal tritide particles and the dosimetry of inhalation exposure to these particles could be quite different from tritiated water. This would have significant implications in the current health protection guidelines including annual limits of intakes and derived air concentrations. The preliminary results of our metal tritide dissolution study indicated that the solubility of titanium tritide is low.

  13. Dissolution rate and radiation dosimetry of metal tritides

    SciTech Connect (OSTI)

    Cheng, Y.

    1993-12-31

    Metal tritides including titanium tritide (Ti {sup 3}H{sub x}) and erbium tritide (Er {sup 3}H{sub x}) have been used as components of neutron generators. These compounds can be released to the air as aerosols during fabrication, assembling, and testing of components or in accidental or fugitive releases; as a result, workers may be exposed to these compounds by inhalation. A joint research project between Sandia National Laboratories and the Inhalation Toxicology Research Institute was initiated last fall to investigate the solubility of metal tritide particles, to determine retention and translocation of inhaled particles in animals, and to develop an internal dosimetry model. The current understanding of metal tritides and their radiation dosimetry for dosimetry in metal tritide form. However, a few papers in the literature suggest that the solubility of metal tritide could be low. The current radiation protection guidelines for metal tritide particles are based on the assumption that the biological behavior is similar to tritiated water which could be easily absorbed into body fluid, and therefore, a relatively short biological half life (10 days). If the solubility is low, exposure to these particles could be quite different from tritiated water. This would have significant implications in the current health protection guidelines including annual limits of intakes and derived air concentrations. The preliminary results of our metal tritide dissolution study indicated that the solubility of titanium tritide is low.

  14. Production of magnesium metal

    DOE Patents [OSTI]

    Blencoe, James G. [Harriman, TN; Anovitz, Lawrence M. [Knoxville, TN; Palmer, Donald A. [Oliver Springs, TN; Beard, James S. [Martinsville, VA

    2010-02-23

    A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention further relates to a process for production of magnesium metal or a magnesium compound where an external source of carbon dioxide is not used in any of the reactions of the process. The invention also relates to the magnesium metal produced by the processes described herein.

  15. Metallization of electronic insulators

    DOE Patents [OSTI]

    Gottesfeld, Shimshon (Los Alamos, NM); Uribe, Francisco A. (Los Alamos, NM)

    1994-01-01

    An electroplated element is formed to include an insulating substrate, a conducting polymer polymerized in situ on the substrate, and a metal layer deposited on the conducting polymer. In one application a circuit board is formed by polymerizing pyrrole on an epoxy-fiberglass substrate in a single step process and then electrodepositing a metal over the resulting polypyrrole polymer. No chemical deposition of the metal is required prior to electroplating and the resulting layer of substrate-polymer-metal has excellent adhesion characteristics. The metal deposition is surprisingly smooth and uniform over the relatively high resistance film of polypyrrole. A continuous manufacturing process is obtained by filtering the solution between successive substrates to remove polymer formed in the solution, by maintaining the solution oxidizing potential within selected limits, and by adding a strong oxidant, such as KMnO.sub.4 at periodic intervals to maintain a low sheet resistivity in the resulting conducting polymer film.

  16. Modeling fluid flow in deformation bands with stabilized localization...

    Office of Scientific and Technical Information (OSTI)

    Modeling fluid flow in deformation bands with stabilized localization mixed finite elements. Citation Details In-Document Search Title: Modeling fluid flow in deformation bands...

  17. Tailored Working Fluids for Enhanced Binary Geothermal Power...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tailored Working Fluids for Enhanced Binary Geothermal Power Plants Tailored Working Fluids for Enhanced Binary Geothermal Power Plants DOE Geothermal Program Peer Review 2010 - ...

  18. High-potential Working Fluids for Next Generation Binary Cycle...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-potential Working Fluids for Next Generation Binary Cycle Geothermal Power Plants High-potential Working Fluids for Next Generation Binary Cycle Geothermal Power Plants DOE ...

  19. Fracture Propagation, Fluid Flow, and Geomechanics of Water-Based...

    Office of Scientific and Technical Information (OSTI)

    Conference: Fracture Propagation, Fluid Flow, and Geomechanics of Water-Based Hydraulic ... Title: Fracture Propagation, Fluid Flow, and Geomechanics of Water-Based Hydraulic ...

  20. Computational Fluid Dynamics Modeling of Diesel Engine Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Computational Fluid Dynamics Modeling of Diesel Engine Combustion and Emissions Computational Fluid Dynamics Modeling of Diesel Engine Combustion and Emissions 2005 Diesel Engine ...

  1. Category:Fluid Lab Analysis | Open Energy Information

    Open Energy Info (EERE)

    Fluid Lab Analysis Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermalpower.jpg Looking for the Fluid Lab Analysis page? For detailed information on exploration...

  2. Volatiles in hydrothermal fluids- A mass spectrometric study...

    Open Energy Info (EERE)

    Volatiles in hydrothermal fluids- A mass spectrometric study of fluid inclusions from active geothermal systems Jump to: navigation, search OpenEI Reference LibraryAdd to library...

  3. Temperature distribution and fluid flow in an enclosure with...

    Office of Scientific and Technical Information (OSTI)

    Temperature distribution and fluid flow in an enclosure with localized heating and cooling Citation Details In-Document Search Title: Temperature distribution and fluid flow in an ...

  4. Fracture Propagation, Fluid Flow, and Geomechanics of Water-Based...

    Office of Scientific and Technical Information (OSTI)

    Conference: Fracture Propagation, Fluid Flow, and Geomechanics of Water-Based Hydraulic ... Citation Details In-Document Search Title: Fracture Propagation, Fluid Flow, and ...

  5. Controlling Subsurface Fractures and Fluid Flow: A Basic Research...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Controlling Subsurface Fractures and Fluid Flow: A Basic Research Agenda Controlling Subsurface Fractures and Fluid Flow: A Basic Research Agenda PDF icon BES Report Controlling ...

  6. Application of Neutron Imaging and Scattering to Fluid Flow and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Application of Neutron Imaging and Scattering to Fluid Flow and Fracture in EGS Environments Application of Neutron Imaging and Scattering to Fluid Flow and Fracture in EGS ...

  7. International Collaborations on Fluid Flows in Fractured Crystalline...

    Office of Scientific and Technical Information (OSTI)

    International Collaborations on Fluid Flows in Fractured Crystalline Rocks: FY14 Progress Report. Citation Details In-Document Search Title: International Collaborations on Fluid ...

  8. Electric Power Generation from Coproduced Fluids from Oil and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electric Power Generation from Coproduced Fluids from Oil and Gas Wells Principal ... Electric Power Generation from Coproduced Fluids from Oil and Gas Wells 3 | US DOE ...

  9. Microfluidics: Kinetics of Hybridized DNA With Fluid Flow Variations...

    Office of Scientific and Technical Information (OSTI)

    Microfluidics: Kinetics of Hybridized DNA With Fluid Flow Variations. Citation Details In-Document Search Title: Microfluidics: Kinetics of Hybridized DNA With Fluid Flow ...

  10. Evaluation of Biodiesel Fuels from Supercritical Fluid Processing...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biodiesel Fuels from Supercritical Fluid Processing with the Advanced Distillation Curve Method Evaluation of Biodiesel Fuels from Supercritical Fluid Processing with the Advanced ...

  11. Modeling Fluid Flow in Natural Systems, Model Validation and...

    Energy Savers [EERE]

    Modeling Fluid Flow in Natural Systems, Model Validation and Demonstration Modeling Fluid Flow in Natural Systems, Model Validation and Demonstration Clay and granitic units are ...

  12. Molten salt heat transfer fluids and thermal storage technology...

    Office of Scientific and Technical Information (OSTI)

    Molten salt heat transfer fluids and thermal storage technology. Citation Details In-Document Search Title: Molten salt heat transfer fluids and thermal storage technology. No ...

  13. Development of Molten-Salt Heat Trasfer Fluid Technology for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Development of Molten-Salt Heat Trasfer Fluid Technology for Parabolic Trough Solar Power Plants Development of Molten-Salt Heat Trasfer Fluid Technology for Parabolic Trough Solar ...

  14. Property:FluidMechanicsMeasurement | Open Energy Information

    Open Energy Info (EERE)

    Property Name FluidMechanicsMeasurement Property Type String Description MHK Fluid Mechanics Measurement Categories Used in FormTemplate MHKSensor Allows Values Differential...

  15. Electric Power Generation from Coproduced Fluids from Oil and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electric Power Generation from Coproduced Fluids from Oil and Gas Wells Electric Power Generation from Coproduced Fluids from Oil and Gas Wells The primary objective of this ...

  16. ITP Chemicals: Technology Roadmap for Computational Fluid Dynamics...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fluid Dynamics, January 1999 ITP Chemicals: Technology Roadmap for Computational Fluid Dynamics, January 1999 cfdroadmap.pdf (323.09 KB) More Documents & Publications 3-D ...

  17. Collapsible sheath fluid reservoirs for flow cytometers

    DOE Patents [OSTI]

    Mark, Graham A. (Los Alamos, NM)

    2000-01-01

    The present invention is a container in the form of a single housing for holding fluid, including a first collapsible reservoir having a first valve. The first reservoir initially contains a volume of fluid. The container also includes a second reservoir, initially empty (or substantially empty), expandable to a second volume. The second reservoir has a second valve. As the volume of said first reservoir decreases, the volume of the second reservoir proportionally increases.

  18. Control system for fluid heated steam generator

    DOE Patents [OSTI]

    Boland, J.F.; Koenig, J.F.

    1984-05-29

    A control system for controlling the location of the nucleate-boiling region in a fluid heated steam generator comprises means for measuring the temperature gradient (change in temperature per unit length) of the heating fluid along the steam generator; means for determining a control variable in accordance with a predetermined function of temperature gradients and for generating a control signal in response thereto; and means for adjusting the feedwater flow rate in accordance with the control signal.

  19. Control system for fluid heated steam generator

    DOE Patents [OSTI]

    Boland, James F.; Koenig, John F.

    1985-01-01

    A control system for controlling the location of the nucleate-boiling region in a fluid heated steam generator comprises means for measuring the temperature gradient (change in temperature per unit length) of the heating fluid along the steam generator; means for determining a control variable in accordance with a predetermined function of temperature gradients and for generating a control signal in response thereto; and means for adjusting the feedwater flow rate in accordance with the control signal.

  20. MEANS FOR VISUALIZING FLUID FLOW PATTERNS

    DOE Patents [OSTI]

    Lynch, F.E.; Palmer, L.D.; Poppendick, H.F.; Winn, G.M.

    1961-05-16

    An apparatus is given for determining both the absolute and relative velocities of a phosphorescent fluid flowing through a transparent conduit. The apparatus includes a source for exciting a narrow trsnsverse band of the fluid to phosphorescence, detecting means such as a camera located downstream from the exciting source to record the shape of the phosphorescent band as it passes, and a timer to measure the time elapsed between operation of the exciting source and operation of the camera.

  1. computational-fluid-dynamics-student-thesis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fluid Dynamics Student Thesis Abstract DEVELOPMENT OF A THREE-DIMENSIONAL SCOURING METHODOLOGY AND ITS IMPLEMENTATION IN A COMMERCIAL CFD CODE FOR OPEN CHANNEL FLOW OVER A FLOODED BRIDGE DECK The Computational Fluid Dynamics staff at TRACC is supporting three students from Northern Illinois University who are working for a Masters degree. The CFD staff is directing the thesis research and working with them on three projects: (1) a three-dimensional scour computation methodology for pressure flow

  2. Computational fluid dynamics improves liner cementing operation

    SciTech Connect (OSTI)

    Barton, N.A.; Archer, G.L. ); Seymour, D.A. )

    1994-09-26

    The use of computational fluid dynamics (CFD), an analytical tool for studying fluid mechanics, helped plan the successful cementing of a critical liner in a North Sea extended reach well. The results from CFD analysis increased the confidence in the primary cementing of the liner. CFD modeling was used to quantify the effects of increasing the displacement rate and of rotating the liner on the mud flow distribution in the annulus around the liner.

  3. Fluid Interface Reactions, Structures and Transport

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Perspectives Nonlinear optical approaches for elucidating interfacial fluid and sorbed species structures and dynamics pdf Structural and Dynamic Properties of Room Temperature Ionic Liquids Confined within Hierarchical Porous Materials pdf Structure and Dynamics of Electrical Double Layer Using Integrated Scanning Probe Microscopy and Molecular Simulations pdf Effects of Nano-Confinement on the Fluid Interfacial Structure, Dynamics and Thermodynamic behavior pdf Molecular Insights into

  4. Fluid Interface Reactions, Structures and Transport

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Overview (Summary Slides) Scientific Objectives: The unique properties of the FSI emerge from a complex interplay of short- and long-range forces and reactions among the molecular fluid components, solutes and substrates. Potential gradients (chemical, electrical, etc.) can be highly non-linear at the angstrom to nanometer scale. The finite size, shape, directional bonding, charge distribution and polarizability of solvent and solute fluid components are convoluted with their ability to

  5. High-Energy-Density Plasmas, Fluids

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High-Energy-Density Plasmas, Fluids High-Energy-Density Plasmas, Fluids National security depends on science and technology. The United States relies on Los Alamos National Laboratory for the best of both. No place on Earth pursues a broader array of world-class scientific endeavors. TRIDENT target chamber Sasi Palaniyappan, right, and Rahul Shah left inside a target chamber where the TRIDENT short pulse laser is aimed at a very thin diamond- foil target, a fraction of a micrometer thick. The

  6. Fluid driven torsional dipole seismic source

    DOE Patents [OSTI]

    Hardee, Harry C.

    1991-01-01

    A compressible fluid powered oscillating downhole seismic source device capable of periodically generating uncontaminated horizontally-propagated, shear waves is provided. A compressible fluid generated oscillation is created within the device which imparts an oscillation to a housing when the device is installed in a housing such as the cylinder off an existing downhole tool, thereby a torsional seismic source is established. Horizontal waves are transferred to the surrounding bore hole medium through downhole clamping.

  7. Water as a thermoacoustic working fluid

    SciTech Connect (OSTI)

    Swift, G.W.

    1988-01-01

    This short report, addressed only to the thermoacoustic cognoscenti, discusses thermodynamic and transport properties of water with emphasis on water's virtues as a thermoacoustic working fluid. Short-stack-approximation calculations are presented, showing that water is a good working fluid. A very rough design for a sound source using water is also presented as a starting point for discussing the merits and difficulties of this technology. 4 figs.

  8. Stirling engine with air working fluid

    DOE Patents [OSTI]

    Corey, John A.

    1985-01-01

    A Stirling engine capable of utilizing air as a working fluid which includes a compact heat exchange module which includes heating tube units, regenerator and cooler positioned about the combustion chamber. This arrangement has the purpose and effect of allowing the construction of an efficient, high-speed, high power-density engine without the use of difficult to seal light gases as working fluids.

  9. Structural cooling fluid tube for supporting a turbine component and supplying cooling fluid to transition section

    SciTech Connect (OSTI)

    Charron, Richard; Pierce, Daniel

    2015-08-11

    A shaft cover support for a gas turbine engine is disclosed. The shaft cover support not only provides enhanced support to a shaft cover of the gas turbine engine, but also includes a cooling fluid chamber for passing fluids from a rotor air cooling supply conduit to an inner ring cooling manifold. Furthermore, the shaft cover support may include a cooling shield supply extending from the cooling fluid chamber between the radially outward inlet and the radially inward outlet on the radially extending region and in fluid communication with the cooling fluid chamber for providing cooling fluids to a transition section. The shaft cover support may also provide additional stiffness and reduce interference of the flow from the compressor. In addition, the shaft cover support accommodates a transition section extending between compressor and turbine sections of the gas turbine engine.

  10. Hydrodynamic 'memory' of binary fluid mixtures

    SciTech Connect (OSTI)

    Kalashnik, M. V.; Ingel, L. Kh.

    2006-07-15

    A theoretical analysis is presented of hydrostatic adjustment in a two-component fluid system, such as seawater stratified with respect to temperature and salinity. Both linear approximation and nonlinear problem are investigated. It is shown that scenarios of relaxation to a hydrostatically balanced state in binary fluid mixtures may substantially differ from hydrostatic adjustment in fluids that can be stratified only with respect to temperature. In particular, inviscid two-component fluids have 'memory': a horizontally nonuniform disturbance in the initial temperature or salinity distribution does not vanish even at the final stage, transforming into a persistent thermohaline 'trace.' Despite stability of density stratification and convective stability of the fluid system by all known criteria, an initial temperature disturbance may not decay and may even increase in amplitude. Moreover, its sign may change (depending on the relative contributions of temperature and salinity to stable background density stratification). Hydrostatic adjustment may involve development of discontinuous distributions from smooth initial temperature or concentration distributions. These properties of two-component fluids explain, in particular, the occurrence of persistent horizontally or vertically nonuniform temperature and salinity distributions in the ocean, including discontinuous ones.

  11. High gliding fluid power generation system with fluid component separation and multiple condensers

    SciTech Connect (OSTI)

    Mahmoud, Ahmad M; Lee, Jaeseon; Radcliff, Thomas D

    2014-10-14

    An example power generation system includes a vapor generator, a turbine, a separator and a pump. In the separator, the multiple components of the working fluid are separated from each other and sent to separate condensers. Each of the separate condensers is configured for condensing a single component of the working fluid. Once each of the components condense back into a liquid form they are recombined and exhausted to a pump that in turn drives the working fluid back to the vapor generator.

  12. Synthesis of metal silicide at metal/silicon oxide interface...

    Office of Scientific and Technical Information (OSTI)

    Synthesis of metal silicide at metalsilicon oxide interface by electronic excitation Citation Details In-Document Search Title: Synthesis of metal silicide at metalsilicon oxide ...

  13. Synthesis of Metal-Metal Oxide Catalysts and Electrocatalysts...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Synthesis of Metal-Metal Oxide Catalysts and Electrocatalysts Brookhaven National Laboratory Contact BNL About This Technology Publications: PDF Document Publication...

  14. Work Functions of the transition Metals and Metal Silicides ...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Work Functions of the transition Metals and Metal Silicides Citation Details In-Document Search ... Publication Date: 1999-02-15 OSTI Identifier: 3597 Report ...

  15. Biosensor and chemical sensor probes for calcium and other metal ions

    DOE Patents [OSTI]

    Vo-Dinh, Tuan; Viallet, Pierre

    1996-01-01

    The present invention relates to chemical sensor and biosensor probes for measuring low concentration of metals and metal ions in complex samples such as biological fluids, living cells, and environmental samples. More particularly the present invention relates to a gel-based Indo-1 and Fura-2 chemical sensor probes for the measurement of low concentrations of calcium, cadmium, magnesium and the like. Also disclosed is a detector device using the sensors of the present invention.

  16. Metal Aminoboranes - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Materials Advanced Materials Find More Like This Return to Search Metal Aminoboranes Los Alamos National Laboratory Contact LANL About This Technology Technology Marketing Summary Metal aminoboranes of the formula M(NH.sub.2BH.sub.3).sub.n have been synthesized. Metal aminoboranes are hydrogen storage materials. Metal aminoboranes are also precursors for synthesizing other metal aminoboranes. Metal aminoboranes can be dehydrogenated to form hydrogen and a reaction product. The reaction

  17. Method for producing metallic microparticles

    DOE Patents [OSTI]

    Phillips, Jonathan; Perry, William L.; Kroenke, William J.

    2004-06-29

    Method for producing metallic particles. The method converts metallic nanoparticles into larger, spherical metallic particles. An aerosol of solid metallic nanoparticles and a non-oxidizing plasma having a portion sufficiently hot to melt the nanoparticles are generated. The aerosol is directed into the plasma where the metallic nanoparticles melt, collide, join, and spheroidize. The molten spherical metallic particles are directed away from the plasma and enter the afterglow where they cool and solidify.

  18. Method for producing metallic nanoparticles

    DOE Patents [OSTI]

    Phillips, Jonathan; Perry, William L.; Kroenke, William J.

    2004-02-10

    Method for producing metallic nanoparticles. The method includes generating an aerosol of solid metallic microparticles, generating non-oxidizing plasma with a plasma hot zone at a temperature sufficiently high to vaporize the microparticles into metal vapor, and directing the aerosol into the hot zone of the plasma. The microparticles vaporize in the hot zone to metal vapor. The metal vapor is directed away from the hot zone and to the plasma afterglow where it cools and condenses to form solid metallic nanoparticles.

  19. Precious Metals | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Precious Metals General Information: The Materials Handling group provides Precious Metals receiving and documentation (PM's) for research programs funded by the Department of Energy (DOE). Precious metals are obtained from the DOE's Business Center for Precious Metals Sales and Recovery (BCPMSR). The return of scrap and excess precious metals to the BCPMSR is also provided by this group. Metals under this control are: GOLD - SILVER - PLATINUM - RHODIUM - PALLADIUM - IRIDIUM - OSMIUM - RUTHENIUM

  20. Metal nanodisks using bicellar templates

    DOE Patents [OSTI]

    Song, Yujiang; Shelnutt, John A

    2013-12-03

    Metallic nanodisks and a method of making them. The metallic nanodisks are wheel-shaped structures that that provide large surface areas for catalytic applications. The metallic nanodisks are grown within bicelles (disk-like micelles) that template the growth of the metal in the form of approximately circular dendritic sheets. The zero-valent metal forming the nanodisks is formed by reduction of a metal ion using a suitable electron donor species.