National Library of Energy BETA

Sample records for metals aluminum al

  1. Boron-carbide-aluminum and boron-carbide-reactive metal cermets. [B/sub 4/C-Al

    DOE Patents [OSTI]

    Halverson, D.C.; Pyzik, A.J.; Aksay, I.A.

    1985-05-06

    Hard, tough, lighweight boron-carbide-reactive metal composites, particularly boron-carbide-aluminum composites, are produced. These composites have compositions with a plurality of phases. A method is provided, including the steps of wetting and reacting the starting materials, by which the microstructures in the resulting composites can be controllably selected. Starting compositions, reaction temperatures, reaction times, and reaction atmospheres are parameters for controlling the process and resulting compositions. The ceramic phases are homogeneously distributed in the metal phases and adhesive forces at ceramic-metal interfaces are maximized. An initial consolidated step is used to achieve fully dense composites. Microstructures of boron-carbide-aluminum cermets have been produced with modules of rupture exceeding 110 ksi and fracture toughness exceeding 12 ksi..sqrt..in. These composites and methods can be used to form a variety of structural elements.

  2. Investigation on Aluminum-Based Amorphous Metallic Glass as New Anode Material in Lithium Ion Batteries

    E-Print Network [OSTI]

    Meng, Shirley Y.

    Aluminum based amorphous metallic glass powders were produced and tested as the anode materials for the lithium ion rechargeable batteries. Ground Al??Ni₁?La₁? was found to have a ...

  3. Influence of Aluminum Content on Grain Refinement and Strength of AZ31 Magnesium GTA Weld Metal

    SciTech Connect (OSTI)

    Babu, N. Kishore [Singapore Institute of Manufacturing Technology; Cross, Carl E. [Los Alamos National Laboratory

    2012-06-28

    The goal is to characterize the effect of Al content on AZ31 weld metal, the grain size and strength, and examine role of Al on grain refinement. The approach is to systematically vary the aluminum content of AZ31 weld metal, Measure average grain size in weld metal, and Measure cross-weld tensile properties and hardness. Conclusions are that: (1) increased Al content in AZ31 weld metal results in grain refinement Reason: higher undercooling during solidification; (2) weld metal grain refinement resulted in increased strength & hardness Reason: grain boundary strengthening; and (3) weld metal strength can be raised to wrought base metal levels.

  4. Joining of parts via magnetic heating of metal aluminum powders

    SciTech Connect (OSTI)

    Baker, Ian

    2013-05-21

    A method of joining at least two parts includes steps of dispersing a joining material comprising a multi-phase magnetic metal-aluminum powder at an interface between the at least two parts to be joined and applying an alternating magnetic field (AMF). The AMF has a magnetic field strength and frequency suitable for inducing magnetic hysteresis losses in the metal-aluminum powder and is applied for a period that raises temperature of the metal-aluminum powder to an exothermic transformation temperature. At the exothermic transformation temperature, the metal-aluminum powder melts and resolidifies as a metal aluminide solid having a non-magnetic configuration.

  5. The melting behavior of lutetium aluminum perovskite LuAlO3

    E-Print Network [OSTI]

    Klimm, Detlef

    2009-01-01

    DTA measurements with mixtures of aluminum oxide and lutetium oxide around the 1:1 perovskite composition were performed up to 1970 deg. C. A peak with onset 1901 deg. C was due to the melting of the eutectic Lu4Al2O9 (monoclinic phase) and LuAlO3 (perovskite). Neither peritectic melting of the perovskite nor its decomposition in the solid phase could be resolved experimentally. The maximum of the eutectic peak size near x=0.44, on the Lu-rich side of the perovskite, leads to the conclusion that LuAlO3 melts peritectically at ca. 1907 deg. C as proposed by Wu, Pelton, J. Alloys Compd. 179 (1992) 259. Under strongly reducing conditions (oxygen partial pressure <10^{-13} bar) aluminum(III) oxide can be reduced to suboxides or even Al metal. It is shown that under such conditions a new phase field with liquid Al can appear.

  6. Recovery of aluminum and other metal values from fly ash

    DOE Patents [OSTI]

    McDowell, William J. (Oak Ridge, TN); Seeley, Forest G. (Oak Ridge, TN)

    1981-01-01

    The invention described herein relates to a method for improving the acid leachability of aluminum and other metal values found in fly ash which comprises sintering the fly ash, prior to acid leaching, with a calcium sulfate-containing composition at a temperature at which the calcium sulfate is retained in said composition during sintering and for a time sufficient to quantitatively convert the aluminum in said fly ash into an acid-leachable form.

  7. Inert anode containing base metal and noble metal useful for the electrolytic production of aluminum

    DOE Patents [OSTI]

    Ray, Siba P. (Murrysville, PA); Liu, Xinghua (Monroeville, PA)

    2000-01-01

    An inert anode for production of metals such as aluminum is disclosed. The inert anode comprises a base metal selected from Cu and Ag, and at least one noble metal selected from Ag, Pd, Pt, Au, Rh, Ru, Ir and Os. The inert anode may optionally be formed of sintered particles having interior portions containing more base metal than noble metal and exterior portions containing more noble metal than base metal. In a preferred embodiment, the base metal comprises Cu, and the noble metal comprises Ag, Pd or a combination thereof.

  8. Kinetic energy distributions of sputtered neutral aluminum clusters: Al--Al{sub 6}

    SciTech Connect (OSTI)

    Coon, S.R.; Calaway, W.F.; Pellin, M.J.; Curlee, G.A.; White, J.M.

    1992-12-01

    Neutral aluminum clusters sputtered from polycrystalline aluminum were analyzed by laser postionization time-of-flight (TOF) mass spectrometry. The kinetic energy distributions of Al through Al{sub 6} were measured by a neutrals time-of-flight technique. The interpretation of laser postionization TOF data to extract velocity and energy distributions is presented. The aluminum cluster distributions are qualitatively similar to previous copper cluster distribution measurements from our laboratory. In contrast to the steep high energy tails predicted by the single- or multiple- collision models, the measured cluster distributions have high energy power law dependences in the range of E{sup {minus}3} to E{sup {minus}4.5}. Correlated collision models may explain the substantial abundance of energetic clusters that are observed in these experiments. Possible influences of cluster fragmentation on the distributions are discussed.

  9. Kinetic energy distributions of sputtered neutral aluminum clusters: Al--Al[sub 6

    SciTech Connect (OSTI)

    Coon, S.R.; Calaway, W.F.; Pellin, M.J. ); Curlee, G.A. . Dept. of Physics); White, J.M. . Dept. of Chemistry and Biochemistry)

    1992-01-01

    Neutral aluminum clusters sputtered from polycrystalline aluminum were analyzed by laser postionization time-of-flight (TOF) mass spectrometry. The kinetic energy distributions of Al through Al[sub 6] were measured by a neutrals time-of-flight technique. The interpretation of laser postionization TOF data to extract velocity and energy distributions is presented. The aluminum cluster distributions are qualitatively similar to previous copper cluster distribution measurements from our laboratory. In contrast to the steep high energy tails predicted by the single- or multiple- collision models, the measured cluster distributions have high energy power law dependences in the range of E[sup [minus]3] to E[sup [minus]4.5]. Correlated collision models may explain the substantial abundance of energetic clusters that are observed in these experiments. Possible influences of cluster fragmentation on the distributions are discussed.

  10. Energy Conservation Design Features of the ARCO Metals Logan County Aluminum Process Complex 

    E-Print Network [OSTI]

    Speer, J. A.

    1983-01-01

    ARCO Metals Company (Formerly Anaconda Aluminum Company) is proceeding as scheduled with the construction of a $400 Million aluminum processing complex in Logan County, Kentucky. When the initial construction phase is ...

  11. Metal Compression Forming of aluminum alloys and metal matrix composites

    SciTech Connect (OSTI)

    Viswanathan, S.; Ren, W.; Porter, W.D.; Brinkman, C.R.; Sabau, A.S.; Purgert, R.M.

    2000-02-01

    Metal Compression Forming (MCF) is a variant of the squeeze casting process, in which molten metal is allowed to solidify under pressure in order to close porosity and form a sound part. However, the MCF process applies pressure on the entire mold face, thereby directing pressure on all regions of the casting and producing a uniformly sound part. The process is capable of producing parts with properties close to those of forgings, while retaining the near net shape, complexity in geometry, and relatively low cost of the casting process.

  12. Aluminum/alkaline earth metal composites and method for producing

    DOE Patents [OSTI]

    Russell, Alan M; Anderson, Iver E; Kim, Hyong J; Freichs, Andrew E

    2014-02-11

    A composite is provided having an electrically conducting Al matrix and elongated filaments comprising Ca and/or Sr and/or Ba disposed in the matrix and extending along a longitudinal axis of the composite. The filaments initially comprise Ca and/or Sr and/or Ba metal or allow and then may be reacted with the Al matrix to form a strengthening intermetallic compound comprising Al and Ca and/or Sr and/or Ba. The composite is useful as a long-distance, high voltage power transmission conductor.

  13. Aluminum reference electrode

    DOE Patents [OSTI]

    Sadoway, Donald R. (Belmont, MA)

    1988-01-01

    A stable reference electrode for use in monitoring and controlling the process of electrolytic reduction of a metal. In the case of Hall cell reduction of aluminum, the reference electrode comprises a pool of molten aluminum and a solution of molten cryolite, Na.sub.3 AlF.sub.6, wherein the electrical connection to the molten aluminum does not contact the highly corrosive molten salt solution. This is accomplished by altering the density of either the aluminum (decreasing the density) or the electrolyte (increasing the density) so that the aluminum floats on top of the molten salt solution.

  14. Aluminum reference electrode

    DOE Patents [OSTI]

    Sadoway, D.R.

    1988-08-16

    A stable reference electrode is described for use in monitoring and controlling the process of electrolytic reduction of a metal. In the case of Hall cell reduction of aluminum, the reference electrode comprises a pool of molten aluminum and a solution of molten cryolite, Na[sub 3]AlF[sub 6], wherein the electrical connection to the molten aluminum does not contact the highly corrosive molten salt solution. This is accomplished by altering the density of either the aluminum (decreasing the density) or the electrolyte (increasing the density) so that the aluminum floats on top of the molten salt solution. 1 fig.

  15. Development of an electronic device quality aluminum antimonide (AlSb) semiconductor for solar cell applications

    DOE Patents [OSTI]

    Sherohman, John W; Yee, Jick Hong; Combs, III, Arthur W

    2014-11-11

    Electronic device quality Aluminum Antimonide (AlSb)-based single crystals produced by controlled atmospheric annealing are utilized in various configurations for solar cell applications. Like that of a GaAs-based solar cell devices, the AlSb-based solar cell devices as disclosed herein provides direct conversion of solar energy to electrical power.

  16. Shear properties on aluminum metal foams prepared by the melt route

    SciTech Connect (OSTI)

    Saenz, E. [UTRC GmbH, Aachen (Germany). Technologiezentrum; Baranda, P.S. [UTRC, S.L., Minano (Spain); Bonhomme, J. [ITMA, Coruno-Llanera (Spain). Parque Tecnologico de Asturias

    1998-12-31

    The shear modulus and shear strength of AlSi7Mg Aluminum foam with 15% (vol) of 13 {micro}m SiC particles were determined through shear testing. A foam slab with a density of 0.31 g/cm3 was supplied by Hydro Aluminium. Four samples were tested according to ASTM C 273-61. The specimens were bonded to steel load plates. The relative displacement of the plates was measured using two extensometers. In order to evaluate the effect of the cell size distribution on shear properties, cell size and material distribution analyses were carried out for the metal foam slab in areas close to those from which the shear specimens were extracted. A fast failure was observed after the maximum shear load. The failure in the samples were located in the central section of the slab mainly because the lower density was located there.

  17. In situ metal-organic chemical vapor deposition atomic-layer deposition of aluminum oxide on GaAs using trimethyaluminum

    E-Print Network [OSTI]

    In situ metal-organic chemical vapor deposition atomic-layer deposition of aluminum oxide on Ga 26 June 2008; published online 21 July 2008 In situ atomic-layer deposition ALD of Al2O3 on p­4 Recently, many ex situ methods such as atomic-layer deposition ALD of high-k on GaAs have achieved success

  18. Aluminum sulfate (alum; Al2 O) is used as a

    E-Print Network [OSTI]

    Sparks, Donald L.

    forms (phytic acid, polyphosphates, and monoesters) in alum- and non-alum­amended poultry litter. When increases. Overall, alum-amended litters exhibited higher proportions of Al-bound P species and phytic acid: inositol phosphates, sugar phosphates, nucleic acids, and phospholipids (Bar- nett, 1994a;Toor et al., 2006

  19. Method of making AlInSb by metal-organic chemical vapor deposition

    DOE Patents [OSTI]

    Biefeld, Robert M. (Albuquerque, NM); Allerman, Andrew A. (Albuquerque, NM); Baucom, Kevin C. (Albuquerque, NM)

    2000-01-01

    A method for producing aluminum-indium-antimony materials by metal-organic chemical vapor deposition (MOCVD). This invention provides a method of producing Al.sub.X In.sub.1-x Sb crystalline materials by MOCVD wherein an Al source material, an In source material and an Sb source material are supplied as a gas to a heated substrate in a chamber, said Al source material, In source material, and Sb source material decomposing at least partially below 525.degree. C. to produce Al.sub.x In.sub.1-x Sb crystalline materials wherein x is greater than 0.002 and less than one.

  20. Synthesis of nanocrystalline aluminum matrix composites reinforced with in situ devitrified Al-Ni-La amorphous particles

    E-Print Network [OSTI]

    Zhang, Zhihui H; Han, B Q; Witkin, D; Ajdelsztajn, L; Laverna, E J

    2006-01-01

    metals, RE = rare earth metals) alloys [4] provides a newwith Al and Ni, the rare earth metal La, however, has the

  1. Process for the fabrication of aluminum metallized pyrolytic graphite sputtering targets

    DOE Patents [OSTI]

    Makowiecki, Daniel M. (Livermore, CA); Ramsey, Philip B. (Livermore, CA); Juntz, Robert S. (Hayward, CA)

    1995-01-01

    An improved method for fabricating pyrolytic graphite sputtering targets with superior heat transfer ability, longer life, and maximum energy transmission. Anisotropic pyrolytic graphite is contoured and/or segmented to match the erosion profile of the sputter target and then oriented such that the graphite's high thermal conductivity planes are in maximum contact with a thermally conductive metal backing. The graphite contact surface is metallized, using high rate physical vapor deposition (HRPVD), with an aluminum coating and the thermally conductive metal backing is joined to the metallized graphite target by one of four low-temperature bonding methods; liquid-metal casting, powder metallurgy compaction, eutectic brazing, and laser welding.

  2. Evolution of microstructure and crystalline texture in aluminum sheet metal subjected to high strain rate biaxial deformation

    E-Print Network [OSTI]

    Feitler, Isaac Benjamin

    2005-01-01

    Electrohydraulic forming was used to biaxially stretch commercial Aluminum 5052 sheet metal workpieces at a high strain rate. Annealed and unannealed workpieces were formed. Specimens were taken from unformed metal and ...

  3. Boron-carbide-aluminum and boron-carbide-reactive metal cermets

    DOE Patents [OSTI]

    Halverson, Danny C. (Manteca, CA); Pyzik, Aleksander J. (Seattle, WA); Aksay, Ilhan A. (Seattle, WA)

    1986-01-01

    Hard, tough, lightweight boron-carbide-reactive metal composites, particularly boron-carbide-aluminum composites, are produced. These composites have compositions with a plurality of phases. A method is provided, including the steps of wetting and reacting the starting materials, by which the microstructures in the resulting composites can be controllably selected. Starting compositions, reaction temperatures, reaction times, and reaction atmospheres are parameters for controlling the process and resulting compositions. The ceramic phases are homogeneously distributed in the metal phases and adhesive forces at ceramic-metal interfaces are maximized. An initial consolidation step is used to achieve fully dense composites. Microstructures of boron-carbide-aluminum cermets have been produced with modulus of rupture exceeding 110 ksi and fracture toughness exceeding 12 ksi.sqroot.in. These composites and methods can be used to form a variety of structural elements.

  4. High-nitrogen-metal complexes as burning-rate modifiers for the aluminum-water propellant system

    SciTech Connect (OSTI)

    Tappan, Bryce C; Mason, Benjamin A

    2009-01-01

    The reactions of electropositive metals, such as aluminum, with water have long been utilized in explosive and propellant formulations, but until recently this has mostly been limited to the water formed as a product gas from the decomposition of another energetic system . Recently, however, with the increased availability of nano-particulate materials, the direct reaction of nano-aluminum (nAl) with water as an oxidizer has been investigated as a propellant system due to high reaction temperatures and the production of hydrogen as the primary gaseous species. This system could be useful for intra-planetary travel where non-terrestrial water is harvested for the oxidizer. Here we present the study of nAl, mixed at a stoichiometric ratio with water ({Phi} = 1) with the highly water soluble metal complexes of bis(tetrazolato)amine (BTA) added at 5, 15,30 and 50 wt% in the case of FeBTA and 5 and 15 wt% in the case of NiBTA and CoBTA. The basic structure of the BTA complexes is shown below where M = Fe, Ni or Co, and x = 3 for Fe and Co and x = 2 for Ni. The particle size of nAl studied was primarily 38 nm with various studies with the particle size of 80 nm. The FeBT A at a loading of 15 wt% gave the highest burning rate enhancement (4.6x at {approx}6.8 MPa), while retaining a low pressure exponent (0.21 compared to 0.24 for nA/H{sub 2}O). At 15 wt% the Ni and Co increased the burning rate, but also increased the pressure exponents. The burning rate of the FeBTA modified material with 80 nm Al decreased as the weight percent of FeBTA was increased, which also tracked decrease in the calculated specific impulse of the mixtures.

  5. Comprehensive study and design of scaled metal/high-k/Ge gate stacks with ultrathin aluminum oxide interlayers

    SciTech Connect (OSTI)

    Asahara, Ryohei; Hideshima, Iori; Oka, Hiroshi; Minoura, Yuya; Hosoi, Takuji Shimura, Takayoshi; Watanabe, Heiji; Ogawa, Shingo; Yoshigoe, Akitaka; Teraoka, Yuden

    2015-06-08

    Advanced metal/high-k/Ge gate stacks with a sub-nm equivalent oxide thickness (EOT) and improved interface properties were demonstrated by controlling interface reactions using ultrathin aluminum oxide (AlO{sub x}) interlayers. A step-by-step in situ procedure by deposition of AlO{sub x} and hafnium oxide (HfO{sub x}) layers on Ge and subsequent plasma oxidation was conducted to fabricate Pt/HfO{sub 2}/AlO{sub x}/GeO{sub x}/Ge stacked structures. Comprehensive study by means of physical and electrical characterizations revealed distinct impacts of AlO{sub x} interlayers, plasma oxidation, and metal electrodes serving as capping layers on EOT scaling, improved interface quality, and thermal stability of the stacks. Aggressive EOT scaling down to 0.56?nm and very low interface state density of 2.4?×?10{sup 11?}cm{sup ?2}eV{sup ?1} with a sub-nm EOT and sufficient thermal stability were achieved by systematic process optimization.

  6. Al-Ca and Al-Fe metal-metal composite strength, conductivity, and microstructure relationships

    SciTech Connect (OSTI)

    Kim, Hyong June

    2011-12-01

    Deformation processed metal-metal composites (DMMC’s) are composites formed by mechanical working (i.e., rolling, swaging, or wire drawing) of two-phase, ductile metal mixtures. Since both the matrix and reinforcing phase are ductile metals, the composites can be heavily deformed to reduce the thickness and spacing of the two phases. Recent studies have shown that heavily drawn DMMCs can achieve anomalously high strength and outstanding combinations of strength and conductivity. In this study, Al-Fe wire composite with 0.07, 0.1, and 0.2 volume fractions of Fe filaments and Al-Ca wire composite with 0.03, 0.06, and 0.09 volume fractions of Ca filaments were produced in situ, and their mechanical properties were measured as a function of deformation true strain. The Al-Fe composites displayed limited deformation of the Fe phase even at high true strains, resulting in little strengthening effect in those composites. Al-9vol%Ca wire was deformed to a deformation true strain of 13.76. The resulting Ca second-phase filaments were deformed to thicknesses on the order of one micrometer. The ultimate tensile strength increased exponentially with increasing deformation true strain, reaching a value of 197 MPa at a true strain of 13.76. This value is 2.5 times higher than the value predicted by the rule of mixtures. A quantitative relationship between UTS and deformation true strain was determined. X-ray diffraction data on transformation of Al + Ca microstructures to Al + various Al-Ca intermetallic compounds were obtained at the Advanced Photon Source at Argonne National Laboratory. Electrical conductivity was measured over a range of true strains and post-deformation heat treatment schedules.

  7. Method using selected carbons to react with Al2O and Al vapors in the carbothermic production of aluminum

    DOE Patents [OSTI]

    Fruehan, Richard J.; Li, Yun; Carkin, Gerald

    2005-02-01

    In a method for recovering Al from an off-gas (3,4) produced during carbothermic reduction of aluminum utilizing at least one smelter (1,2), the off-gas (3,4) is directed to an enclosed reactor (5) which is fed a supply of wood charcoal (7) having a porosity of from about 50 vol. % to 85 vol. % and an average pore diameter of from about 0.05 .mu.m to about 2.00 .mu.m, where the wood charcoal (7) contacts the off-gas (3,4) to produce at least Al.sub.4 C.sub.3 (6), which is passed back to the smelter (1,2).

  8. Process for the fabrication of aluminum metallized pyrolytic graphite sputtering targets

    DOE Patents [OSTI]

    Makowiecki, D.M.; Ramsey, P.B.; Juntz, R.S.

    1995-07-04

    An improved method is disclosed for fabricating pyrolytic graphite sputtering targets with superior heat transfer ability, longer life, and maximum energy transmission. Anisotropic pyrolytic graphite is contoured and/or segmented to match the erosion profile of the sputter target and then oriented such that the graphite`s high thermal conductivity planes are in maximum contact with a thermally conductive metal backing. The graphite contact surface is metallized, using high rate physical vapor deposition (HRPVD), with an aluminum coating and the thermally conductive metal backing is joined to the metallized graphite target by one of four low-temperature bonding methods; liquid-metal casting, powder metallurgy compaction, eutectic brazing, and laser welding. 11 figs.

  9. Study of metallic powder behavior in very low pressure plasma spraying (VLPPS) — Application to the manufacturing of titanium–aluminum coatings

    SciTech Connect (OSTI)

    Vautherin, B.; Planche, M.-P.; Montavon, G.; Lapostolle, F.; Quet, A.; Bianchi, L.

    2015-08-28

    In this study, metallic materials made of aluminum and titanium were manufactured implementing very low pressure plasma spraying (VLPPS). Aluminum was selected at first as a demonstrative material due to its rather low vaporization enthalpy (i.e., 381.9 kJ·mol?¹). Developments were then carried out with titanium which exhibits a higher vaporization enthalpy (i.e., 563.6 kJ·mol?¹). Optical emission spectroscopy (OES) was implemented to analyze the behavior of each solid precursor (metallic powders) when it is injected into the plasma jet under very low pressure (i.e., in the 150 Pa range). Besides, aluminum, titanium and titanium–aluminum coatings were deposited in the same conditions implementing a stick-cathode plasma torch operated at 50 kW, maximum power. Coating phase compositions were identified by X-Ray Diffraction (XRD). Coating elementary compositions were quantified by Glow Discharge Optical Emission Spectroscopy (GDOES) and Energy Dispersive Spectroscopy (EDS) analyses. The coating structures were observed by Scanning Electron Microscopy (SEM). The coating void content was determined by Ultra-Small Angle X-ray Scattering (USAXS). The coatings exhibit a two-scale structure corresponding to condensed vapors (smaller scale) and solidified areas (larger scale). Titanium–aluminum sprayed coatings, with various Ti/Al atomic ratios, are constituted of three phases: metastable ?-Ti, Al and metastable ??-Ti?Al. This latter is formed at elevated temperature in the plasma flow, before being condensed. Its rather small fraction, impeded by the rather small amount of vaporized Ti, does not allow modifying however the coating hardness.

  10. Li.sub.2 O-Al.sub.2 O.sub.3 -SiO.sub.2 glass ceramic-aluminum containing austenitic stainless steel composite body and a method of producing the same

    DOE Patents [OSTI]

    Cassidy, Roger T. (Monroe, OH)

    1990-05-01

    The present invention relates to a hermetically sealed Li.sub.2 O-Al.sub.2 O.sub.3 -SiO.sub.2 glass ceramic-aluminum containing stainless steel composite body and a method of producing the body. The composite body includes an oxide interfacial region between the glass ceramic and metal, wherein the interfacial region consists essentially of an Al.sub.2 O.sub.3 layer. The interfacial Al.sub.2 O.sub.3 region includes constituents of both the metal and glass ceramic.

  11. The influence of metallic particle size on the mechanical properties of PTFE-Al-W powder composites

    E-Print Network [OSTI]

    J. Cai; V. F. Nesterenko; K. S. Vecchio; E. B. Herbold; D. J. Benson; F. Jiang; J. W. Addiss; S. M. Walley; W. G. Proud

    2007-09-13

    The dynamic mechanical properties of reactive materials (e.g., high density mixtures of polytetraflouroethylene (PTFE), aluminum (Al) and tungsten (W) powders) can be tailored by changing the morphology of the particles and porosity. Cold isostatically pressed PTFE-Al-W powder composites with fine metallic particles and a higher porosity exhibited higher ultimate compressive strength than less porous composites having equivalent mass ratios with coarse W particles. The mesoscale force chains between the fine metallic particles are responsible for this unusual phenomenon. We observed macrocracks below the critical failure strain for the matrix and a competition between densification and fracture in some porous samples in dynamic tests.

  12. First-principles investigations of Ni3Al(111) and NiAl(110) surfaces at metal dusting conditions

    SciTech Connect (OSTI)

    Saadi, Souheil

    2011-03-01

    We investigate the structure and surface composition of the {gamma}{prime}-Ni{sub 3}Al(111) and {beta}-NiAl(110) alloy surfaces at conditions relevant for metal dusting corrosion related to catalytic steam reforming of natural gas. In regular service as protective coatings, nickel-aluminum alloys are protected by an oxide scale, but in case of oxide scale spallation, the alloy surface may be directly exposed to the reactive gas environment and vulnerable to metal dusting. By means of density functional theory and thermochemical calculations for both the Ni{sub 3}Al and NiAl surfaces, the conditions under which CO and OH adsorption is to be expected and under which it is inhibited, are mapped out. Because CO and OH are regarded as precursors for nucleating graphite or oxide on the surfaces, phase diagrams for the surfaces provide a simple description of their stability. Specifically, this study shows how the CO and OH coverages depend on the steam to carbon ratio (S/C) in the gas and thereby provide a ranking of the carbon limits on the different surface phases.

  13. Influence of Alloy and Solidification Parameters on Grain Refinement in Aluminum Weld Metal due to Inoculation

    SciTech Connect (OSTI)

    Schempp, Philipp [BAM, Germany; Tang, Z. [BIAS, Germany; Cross, Carl E. [Los Alamos National Laboratory; Seefeld, T. [BIAS, Germany; Pittner, A. [BAM, Germany; Rethmeier, M. [BAM, Germany

    2012-06-28

    The goals are: (1) Establish how much Ti/B grain refiner is need to completely refine aluminum weld metal for different alloys and different welding conditions; (2) Characterize how alloy composition and solidification parameters affect weld metal grain refinement; and (3) Apply relevant theory to understand observed behavior. Conclusions are: (1) additions of Ti/B grain refiner to weld metal in Alloys 1050, 5083, and 6082 resulted in significant grain refinement; (2) grain refinement was more effective in GTAW than LBW, resulting in finer grains at lower Ti content - reason is limited time available for equiaxed grain growth in LBW (inability to occlude columnar grain growth); (3) welding travel speed did not markedly affect grain size within GTAW and LBW clusters; and (4) application of Hunt CET analysis showed experimental G to be on the order of the critical G{sub CET}; G{sub CET} was consistently higher for GTAW than for LBW.

  14. Metallic Reinforcement of Direct Squeeze Die Casting Aluminum Alloys for Improved Strength and Fracture Resistance

    SciTech Connect (OSTI)

    D. Schwam: J.F. Wallace: Y. Zhu: J.W. Ki

    2004-10-01

    The utilization of aluminum die casting as enclosures where internal equipment is rotating inside of the casting and could fracture requires a strong housing to restrain the fractured parts. A typical example would be a supercharger. In case of a failure, unless adequately contained, fractured parts could injure people operating the equipment. A number of potential reinforcement materials were investigated. The initial work was conducted in sand molds to create experimental conditions that promote prolonged contact of the reinforcing material with molten aluminum. Bonding of Aluminum bronze, Cast iron, and Ni-resist inserts with various electroplated coatings and surface treatments were analyzed. Also toughening of A354 aluminum cast alloy by steel and stainless steel wire mesh with various conditions was analyzed. A practical approach to reinforcement of die cast aluminum components is to use a reinforcing steel preform. Such performs can be fabricated from steel wire mesh or perforated metal sheet by stamping or deep drawing. A hemispherical, dome shaped casting was selected in this investigation. A deep drawing die was used to fabricate the reinforcing performs. The tendency of aluminum cast enclosures to fracture could be significantly reduced by installing a wire mesh of austenitic stainless steel or a punched austenitic stainless steel sheet within the casting. The use of reinforcements made of austenitic stainless steel wire mesh or punched austenitic stainless steel sheet provided marked improvement in reducing the fragmentation of the casting. The best strengthening was obtained with austenitic stainless steel wire and with a punched stainless steel sheet without annealing this material. Somewhat lower results were obtained with the annealed punched stainless steel sheet. When the annealed 1020 steel wire mesh was used, the results were only slightly improved because of the lower mechanical properties of this unalloyed steel. The lowest results were obtained with unreinforced 356 aluminum casting. Good strength can be obtained with a sound die casting without any defects produced by squeeze casting. The use of higher pressure to produce the squeeze casting has been shown to increase the strength of a hemispherical dome casting. This dome shape casting has been produced both with and without reinforcement and tested to determine its pressure resistance under internal pressure of water. Only a slight improvement in strength could be determined because of water leaks at the seal between hemispherical dome and its flat supporting side. However, when the ability of the casting was tested under the compressive force of a plunger, the strengthening effect of wire mesh or sheet was evident. Higher loads to failure were obtained because of the reinforcement of the stainless steel wire and punched sheet. Rather than a sudden failure occurring, the reinforcement of the stainless steel wire or the punched hard stainless steel sheet held the material together and prevented any loss of the fractured casting to the surroundings. Unalloyed steel did not have the required strength or mechanical properties to increase the properties of the casting.

  15. New ionic liquids based on complexation of dipropylsulfide and AlCl3 for electrochodeposition of aluminum

    SciTech Connect (OSTI)

    Fang, Youxing; Jiang, Xueguang; Dai, Sheng; Sun, Xiao-Guang

    2015-01-01

    A new kind of ionic liquid based on complexation of dipropyl sulfide (DPS) and AlCl3 has been prepared. The equivalent concentration of AlCl3 in the ionic liquid is as high as 2.3 M. More importantly, it is highly fluidic and exhibits an ambient ionic conductivity of 1.25 x 10-4 S cm-1. This new ionic liquid can be successfully used as an electrolyte for electrodeposition of aluminum.

  16. Energy-Saving Melting and Revert Reduction Technology (E-SMARRT): Development of Elevated Temperature Aluminum Metal Matrix Composite (MMC) Alloy and Its Processing Technology

    SciTech Connect (OSTI)

    Weiss, David C.; Gegal, Gerald A.

    2014-04-15

    The objective of this project was to provide a production capable cast aluminum metal matrix composite (MMC) alloy with an operating temperature capability of 250-300°C. Important industrial sectors as well as the military now seek lightweight aluminum alloy castings that can operate in temperature ranges of 250-300°C. Current needs in this temperature range are being satisfied by the use of titanium alloy castings. These have the desired strength properties but the end components are heavier and significantly more costly. Also, the energy requirements for production of titanium alloy castings are significantly higher than those required for production of aluminum alloys and aluminum alloy castings.

  17. Diagnostic of the self-healing of metallized polypropylene film by modeling of the broadening emission lines of aluminum emitted by plasma discharge

    SciTech Connect (OSTI)

    Tortai, J.-H.; Bonifaci, N.; Denat, A.; Trassy, C.

    2005-03-01

    Metallized-film capacitors have the property, even under high continuous voltage, to self-heal i.e., to clear a defect in the dielectric. The self-healing process is a consequence of a transient arc discharge. It has been previously shown that during the discharge, due to Joule effect, the metal is vaporized until the arc extinguishes. The discharge duration has been found to be inversely proportional to the mechanical pressure applied on the layers of metallized films making up a capacitor. The aim of this study is to understand the physical processes involved in this spontaneous extinction of the arc discharge. Emission spectroscopy has been used to provide information about the physical properties (temperatures, electronic and neutral particles densities, etc.) of the plasma induces by a self-healing. An analysis, based on the broadenings and shifts of Al atomic lines, of the experimental light spectra obtained has shown that the self-healing process leads to the generation, from the vaporized metal, of a high-density and relatively weakly ionized aluminum plasma. The plasma density increases with the pressure applied on the film layers and, consequently, the density power needed to extend the plasma zone increases as well and the arc discharge goes out faster as experimentally observed.

  18. Enhancement of heat and mass transfer in metal hydride beds with the addition of Al plates

    E-Print Network [OSTI]

    Guo, Zhixiong "James"

    in the hydriding process with the addition of internal aluminum plates. The two-dimensional equations governing during the absorption/desorption process in the metal hydride beds. The main factors governing the metal hydride matrix and kinetics of the hydrogen sorption processes, etc. By ne- glecting the hydrogen

  19. Interfacial Microstructure Formed by Reactive Metal Penetration of Al into Mullite

    SciTech Connect (OSTI)

    Du, T.B.; Ewsuk, K.G.; Fahrenholtz, W.G.; Loehman, R.E.; Lu, P.

    1999-04-27

    Microstructure in the reaction interface between molten Al and dense mullite have been studied by transmission electron microscopy to provide insight into mechanisms for forming ceramic-metal composites by reactive metal penetration. The reactions, which have the overall stoichiometry, 3Al#iz01~ + (8+ x)A1 + 13 AlzO~ + xA1 + 6Si, were carried out at temperatures of 900, 1100, and 1200oC for 5 minutes and 60 minutes, and 1400oC for 15 minutes. Observed phases generally were those given in the above reaction, although their proportions and interracial rnicrostructures differed strongly with reaction temperature. After reaction at 900oC, a thin Al layer separated unreacted mullite from the cx-AlzO~ and Al reaction products. No Si phase was found near the reaction front. After 5 minutes at 1100"C, the nxtction front contained Si, ct-A120~, and an aluminum oxide phase with a high concentration of Si. After 60 minutes at 11O(YC many of the cx-A120g particles were needle-shaped with a preferred orientation. After reaction at 1200oC, the reaction front contained a high density of Si particles that formed a continuous layer over many of the mullite grains. The sample reacted at 140VC for 15 minutes had a dense ct-A120J reaction layer less than 2~m thick. Some isolated Si particles were present between the a-AlzO~ layer and the unreacted mullite. Using previously measured reaction kinetics data, the observed temperature dependence of the interracial microstructure have been modeled as three sequential steps, each one of which is rate-limiting in a different temperature range.

  20. Aluminum electroplating on steel from a fused bromide electrolyte

    SciTech Connect (OSTI)

    Prabhat K. Tripathy; Laura A. Wurth; Eric J. Dufek; Toni Y. Gutknecht; Natalie J. Gese; Paula Hahn; Steven M. Frank; Guy L. Frederickson; J. Stephen Herring

    2014-08-01

    A quaternary bromide bath (LiBr–KBr–CsBr–AlBr3) was used to electro-coat aluminum on steel substrates. The electrolytewas prepared by the addition of AlBr3 into the eutectic LiBr–KBr–CsBr melt. A smooth, thick, adherent and shiny aluminum coating could be obtained with 80 wt.% AlBr3 in the ternary melt. The SEM photographs of the coated surfaces suggest the formation of thick and dense coatings with good aluminum coverage. Both salt immersion and open circuit potential measurement suggested that the coatings did display a good corrosionresistance behavior. Annealing of the coated surfaces, prior to corrosion tests, suggested the robustness of the metallic aluminum coating in preventing the corrosion of the steel surfaces. Studies also indicated that the quaternary bromide plating bath can potentially provide a better aluminumcoating on both ferrous and non-ferrous metals, including complex surfaces/geometries.

  1. Low coverage spontaneous etching and hyperthermal desorption of aluminum chlorides from Cl2 Al,,111...

    E-Print Network [OSTI]

    Kummel, Andrew C.

    thermal desorption translational energy for AlCl3 . Cl2 sticking probability measurements and AlxCly etch the processes involved in both the thermal and ion-assisted etching of Al 111 by Cl2 .9 Spontaneous high products actually exit the surface at hyperthermal velocities which correspond to 2­30 times thermal energy

  2. Aluminum nanoscale order in amorphous Al92Sm8 measured by fluctuation electron microscopy

    E-Print Network [OSTI]

    Khare, Sanjay V.

    of Illinois--Urbana Champaign, Urbana, Illinois 61801 S. V. Khareb Department of Materials Science and Engineering, University of Illinois--Urbana Champaign, Urbana, Illinois 61801 Received 15 December 2004,3 Devitrification of Al92Sm8 amorphized by de- formation does not proceed by primary Al crystallization.3 When

  3. Electrometallurgical treatment of aluminum-based fuels.

    SciTech Connect (OSTI)

    Willit, J. L.

    1998-07-29

    We have successfully demonstrated aluminum electrorefining from a U-Al-Si alloy that simulates spent aluminum-based reactor fuel. The aluminum product contains less than 200 ppm uranium. All the results obtained have been in agreement with predictions based on equilibrium thermodynamics. We have also demonstrated the need for adequate stirring to achieve a low-uranium product. Most of the other process steps have been demonstrated in other programs. These include uranium electrorefining, transuranic fission product scrubbing, fission product oxidation, and product consolidation by melting. Future work will focus on the extraction of active metal and rare earth fission products by a molten flux salt and scale-up of the aluminum electrorefining.

  4. Synthesis and structural characterization of a new aluminum oxycarbonitride, Al{sub 5}(O, C, N){sub 4}

    SciTech Connect (OSTI)

    Inuzuka, Haruya; Kaga, Motoaki; Urushihara, Daisuke; Nakano, Hiromi; Asaka, Toru; Fukuda, Koichiro

    2010-11-15

    A new aluminum oxycarbonitride, Al{sub 5}(O{sub x}C{sub y}N{sub 4-x-y}) (x{approx}1.4 and y{approx}2.1), has been synthesized and characterized by X-ray powder diffraction, transmission electron microscopy and electron energy loss spectroscopy (EELS). The title compound was found to be hexagonal with space group P6{sub 3}/mmc, Z=2, and unit-cell dimensions a=0.328455(6) nm, c=2.15998(3) nm and V=0.201805(6) nm{sup 3}. The atom ratios O:C:N were determined by EELS. The final structural model, which is isomorphous with that of (Al{sub 4.4}Si{sub 0.6})(O{sub 1.0}C{sub 3.0}), showed the positional disordering of one of the three types of Al sites. The maximum-entropy method-based pattern fitting (MPF) method was used to confirm the validity of the split-atom model, in which conventional structure bias caused by assuming intensity partitioning was minimized. The reliability indices calculated from the MPF were R{sub wp}=6.94% (S=1.22), R{sub p}=5.34%, R{sub B}=1.35% and R{sub F}=0.76%. The crystal was an inversion twin. Each twin-related individual was isostructural with Al{sub 5}C{sub 3}N (space group P6{sub 3}mc, Z=2). - Graphical abstract: A new oxycarbonitride discovered in the Al-O-C-N system, Al{sub 5}(O{sub 1.4}C{sub 2.1}N{sub 0.5}). The crystal is an inversion twin, and hence the structure is represented by a split-atom model. The three-dimensional electron density distributions are determined by the maximum-entropy methods-based pattern fitting, being consistent with the disordered structural model. Display Omitted

  5. Corrosion of graphite/aluminum metal-matrix composites. Technical report, 1 Mar-31 Dec 90

    SciTech Connect (OSTI)

    Buonanno, M.A.; Latanision, R.M.; Hihara, L.H.; Chiang, J.F.

    1991-02-01

    Several commercial G/Al MMCs have been studied by potentiodynamic polarization in deaerated 0.5 M Na{sub 2}SO{sub 4}. The results have been compared with those which were predicted by the mixed electrode theory. The results indicate that processing conditions, especially the cooling rate, had a strong influence on the corrosion behavior of the G/Al MMCs. Large scale G/Al model MMCs were fabricated at MIT in order to study the corrosion behavior of G/Al galvanic couples with the scanning potential microprobe (SPM). Preliminary results indicate that coating graphite with discontinuous alumina did not reduce the corrosion rate of the G/Al galvanic couple. Ion implanting the surface of G/Al model MMCs with zinc, a cathodic inhibitor, did reduce the corrosion G/Al galvanic couple; however, the protection was incomplete.

  6. INLINE HIGH-RATE THERMAL EVAPORATION OF ALUMINUM FOR NOVEL INDUSTRIAL SOLAR CELL METALLIZATION

    E-Print Network [OSTI]

    in the food industry. For the metallization of solar cells Schott Solar AG used a batch evaporation system, seven vacuum chambers and an unloading area and may be used either in a continuous or in an oscillating

  7. Image Reconstruction of a Metal Fill Industrial Process Using Genetic Programming Alaa Al-Afeef

    E-Print Network [OSTI]

    Fernandez, Thomas

    the characteristic of the molten metal in Lost Foam Casting (LFC) process [12], [13] and many others. B. ECT SensorImage Reconstruction of a Metal Fill Industrial Process Using Genetic Programming Alaa Al-field and Ill-condition characteristic of ECT. The basic idea of the ECT for image re- construction for a metal

  8. Formulation and method for preparing gels comprising hydrous aluminum oxide

    SciTech Connect (OSTI)

    Collins, Jack L.

    2014-06-17

    Formulations useful for preparing hydrous aluminum oxide gels contain a metal salt including aluminum, an organic base, and a complexing agent. Methods for preparing gels containing hydrous aluminum oxide include heating a formulation to a temperature sufficient to induce gel formation, where the formulation contains a metal salt including aluminum, an organic base, and a complexing agent.

  9. Crystal structure, characterization and thermoelectric properties of the type-I clathrate Ba{sub 8-y}Sr{sub y}Al{sub 14}Si{sub 32} (0.6{<=}y{<=}1.3) prepared by aluminum flux

    SciTech Connect (OSTI)

    Roudebush, John H.; Toberer, Eric S.; Hope, Hakon; Jeffrey Snyder, G.; Kauzlarich, Susan M.

    2011-05-15

    The title compound was prepared as single crystals using an aluminum flux technique. Single crystal and powder X-ray diffraction indicate that this composition crystallizes in the clathrate type-I structure, space group Pm3-bar n. Electron microprobe characterization indicates the composition to be Ba{sub 8-y}Sr{sub y}Al{sub 14.2(2)}Si{sub 31.8(2)} (0.77Al content fixed at the microprobe value (12 K data: R{sub 1}=0.0233, wR{sub 2}=0.0441) on a crystal of compositions Ba. The Sr atom preferentially occupies the 2a position; mixed Al/Si occupancy was found on all framework sites. These refinements are consistent with a fully occupied framework and nearly fully occupied cation guest sites as found by microprobe analysis. Temperature dependent electrical resistivity and thermal conductivity have been measured from room temperature to 1200 K on a hot-pressed pellet. Electrical resistivity reveals metallic behavior. The negative Seebeck coefficient indicates transport processes dominated by electrons as carriers. Thermal conductivity is between 22 and 25 mW/cm K. The sample shows n-type conductivity with a maximum figure of merit, zT of 0.3 at 1200 K. A single parabolic band model predicts a five-fold increase in zT at 800 K if carrier concentration is lowered. -- Graphical abstract: The inorganic type-I clathrate phase with nominal composition Ba{sub 7}Sr{sub 1}Al{sub 14}Si{sub 32} has been prepared by Al flux. Single crystal diffraction at 90 and 12 K reveal that the framework is fully occupied with the cation sites nearly fully occupied. The lattice thermal conductivity is low thereby suggesting further optimization of the carrier concentration will lead to a high zT. Display Omitted Highlights: {yields} Ba{sub 7}Sr{sub 1}Al{sub 14}Si{sub 32} is a light element phase ideal for thermoelectric power generation. {yields} Ba{sub 7}Sr{sub 1}Al{sub 14}Si{sub 32} is a high melting point cubic structure ideal for efficient power generation. {yields} The framework is fully occupied with the cation sites nearly fully occupied. {yields} Further optimization of the carrier concentration is expected to lead to a high zT.

  10. Technology maturation project on optimization of sheet metal forming of aluminum for use in transportation systems: Final project report

    SciTech Connect (OSTI)

    Johnson, K.I.; Smith, M.T.; Lavender, C.A.; Khalell, M.A.

    1994-10-01

    Using aluminum instead of steel in transportation systems could dramatically reduce the weight of vehicles--an effective way of decreasing energy consumption and emissions. The current cost of SMF aluminum alloys (about $4 per pound) and the relatively long forming times of current materials are serious drawbacks to the widespread use of SMF in industry. The interdependence of materials testing and model development is critical to optimizing SMF since the current process is conducted in a heated, pressurized die where direct measurement of critical SMF parameters is extremely difficult. Numerical models provide a means of tracking the forming process, allowing the applied gas pressure to be adjusted to maintain the optimum SMF behavior throughout the forming process. Thus, models can help produce the optimum SMF component in the least amount of time. The Pacific Northwest Laboratory is integrating SMF model development with research in improved aluminum alloys for SMF. The objectives of this research are: develop and characterize competitively priced aluminum alloys for SMF applications in industry; improve numerical models to accurately predict the optimum forming cycle for reduced forming time and improved quality; verify alloy performance and model accuracy with forming tests conducted in PNL`s Superplastic Forming User Facility. The activities performed in this technology maturation project represent a critical first step in achieving these objectives through cooperative research among industry, PNL, and universities.

  11. Nondestructive detection of an undesirable metallic phase, T.sub.1, during processing of aluminum-lithium alloys

    DOE Patents [OSTI]

    Buck, Otto (Ames, IA); Bracci, David J. (Maryland Heights, MO); Jiles, David C. (Ames, IA); Brasche, Lisa J. H. (Nevada, IA); Shield, Jeffrey E. (Ames, IA); Chumbley, Leonard S. (Ames, IA)

    1990-08-07

    A method is disclosed for detecting the T.sub.1 phase in aluminum-lithium alloys through simultaneous measurement of conductivity and hardness. In employing eddy current to measure conductivity, when the eddy current decreases with aging of the alloy, while the hardness of the material continues to increase, the presence of the T.sub.1 phase may be detected.

  12. Membrane Purification Cell for Aluminum Recycling

    SciTech Connect (OSTI)

    David DeYoung; James Wiswall; Cong Wang

    2011-11-29

    Recycling mixed aluminum scrap usually requires adding primary aluminum to the scrap stream as a diluent to reduce the concentration of non-aluminum constituents used in aluminum alloys. Since primary aluminum production requires approximately 10 times more energy than melting scrap, the bulk of the energy and carbon dioxide emissions for recycling are associated with using primary aluminum as a diluent. Eliminating the need for using primary aluminum as a diluent would dramatically reduce energy requirements, decrease carbon dioxide emissions, and increase scrap utilization in recycling. Electrorefining can be used to extract pure aluminum from mixed scrap. Some example applications include producing primary grade aluminum from specific scrap streams such as consumer packaging and mixed alloy saw chips, and recycling multi-alloy products such as brazing sheet. Electrorefining can also be used to extract valuable alloying elements such as Li from Al-Li mixed scrap. This project was aimed at developing an electrorefining process for purifying aluminum to reduce energy consumption and emissions by 75% compared to conventional technology. An electrolytic molten aluminum purification process, utilizing a horizontal membrane cell anode, was designed, constructed, operated and validated. The electrorefining technology could also be used to produce ultra-high purity aluminum for advanced materials applications. The technical objectives for this project were to: - Validate the membrane cell concept with a lab-scale electrorefining cell; - Determine if previously identified voltage increase issue for chloride electrolytes holds for a fluoride-based electrolyte system; - Assess the probability that voltage change issues can be solved; and - Conduct a market and economic analysis to assess commercial feasibility. The process was tested using three different binary alloy compositions (Al-2.0 wt.% Cu, Al-4.7 wt.% Si, Al-0.6 wt.% Fe) and a brazing sheet scrap composition (Al-2.8 wt.% Si-0.7 wt.% Fe-0.8 wt.% Mn),. Purification factors (defined as the initial impurity concentration divided by the final impurity concentration) of greater than 20 were achieved for silicon, iron, copper, and manganese. Cell performance was measured using its current and voltage characteristics and composition analysis of the anode, cathode, and electrolytes. The various cells were autopsied as part of the study. Three electrolyte systems tested were: LiCl-10 wt. % AlCl3, LiCl-10 wt. % AlCl3-5 wt.% AlF3 and LiF-10 wt.% AlF3. An extended four-day run with the LiCl-10 wt.% AlCl3-5 wt.% AlF3 electrolyte system was stable for the entire duration of the experiment, running at energy requirements about one third of the Hoopes and the conventional Hall-Heroult process. Three different anode membranes were investigated with respect to their purification performance and survivability: a woven graphite cloth with 0.05 cm nominal thickness & > 90 % porosity, a drilled rigid membrane with nominal porosity of 33%, and another drilled rigid graphite membrane with increased thickness. The latter rigid drilled graphite was selected as the most promising membrane design. The economic viability of the membrane cell to purify scrap is sensitive to primary & scrap aluminum prices, and the cost of electricity. In particular, it is sensitive to the differential between scrap and primary aluminum price which is highly variable and dependent on the scrap source. In order to be economically viable, any scrap post-processing technology in the U.S. market must have a total operating cost well below the scrap price differential of $0.20-$0.40 per lb to the London Metal Exchange (LME), a margin of 65%-85% of the LME price. The cost to operate the membrane cell is estimated to be < $0.24/lb of purified aluminum. The energy cost is estimated to be $0.05/lb of purified aluminum with the remaining costs being repair and maintenance, electrolyte, labor, taxes and depreciation. The bench-scale work on membrane purification cell process has demonstrated technological advantages and subs

  13. Short-range order of low-coverage Ti/Al,,111...: Implications for hydrogen storage in complex metal hydrides

    E-Print Network [OSTI]

    Ciobanu, Cristian

    Short-range order of low-coverage Ti/Al,,111...: Implications for hydrogen storage in complex metal-coverage Ti atoms on Al 111 as a model surface system for transition metal doped alanate hydrogen storage the dissociative chemisorption of hydrogen in Ti-doped alanate storage materials. © 2007 American Institute

  14. Magnetic properties of transition metal doped AlN nanosheet: First-principle studies

    SciTech Connect (OSTI)

    Shi, Changmin; Qin, Hongwei Zhang, Yongjia; Hu, Jifan; Ju, Lin

    2014-02-07

    We carry out our first-principles calculations within density functional theory to study the 3d transition metal (TM) doped AlN nanosheets. The calculated results indicate that a stoichiometric AlN nanosheet is graphene-like structure and nonmagnetic. The TM impurities can induce magnetic moments, localized mainly on the 3d TM atoms and neighboring N atoms. Our calculated results of TM-doped nanosheet systems indicate a strong interaction between 3d orbit of TM atom and the 2p orbit of N atoms. In addition, the Mn- and Ni-doped AlN nanosheet with half-metal characters seems to be good candidates for spintronic applications. When substituting two Al atoms, the relative energies of the states between ferromagnetic and antiferromagnetic coupling are investigated sufficiently. The exchange coupling of Co- and Ni-doped AlN nanosheets exhibits a transformation with different distances of two TM atoms and that of Cr-, Mn-, and Fe-doped AlN nanosheets is not changed.

  15. ITP Aluminum: Aluminum Industry Vision: Sustainable Solutions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Aluminum Industry Vision: Sustainable Solutions for a Dynamic World ITP Aluminum: Aluminum Industry Vision: Sustainable Solutions for a Dynamic World alumvision.pdf More Documents...

  16. Production of anhydrous aluminum chloride composition

    DOE Patents [OSTI]

    Vandergrift, G.F. III; Krumpelt, M.; Horwitz, E.P.

    1981-10-08

    A process is described for producing an anhydrous aluminum chloride composition from a water-based aluminous material such as a slurry of aluminum hydroxide in a multistage extraction process in which the aluminum ion is first extracted into an organic liquid containing an acidic extractant and then extracted from the organic phase into an alkali metal chloride or chlorides to form a melt containing a mixture of chlorides of alkali metal and aluminum. In the process, the organic liquid may be recycled. In addition, the process advantageously includes an electrolysis cell for producing metallic aluminum and the alkali metal chloride or chlorides may be recycled for extraction of the aluminum from the organic phase.

  17. High resistivity aluminum antimonide radiation detector

    DOE Patents [OSTI]

    Sherohman, John W. (Livermore, CA); Coombs, III, Arthur W. (Patterson, CA); Yee, Jick H. (Livermore, CA)

    2007-12-18

    Bulk Aluminum Antimonide (AlSb)-based single crystal materials have been prepared for use as ambient (room) temperature X-ray and Gamma-ray radiation detection.

  18. High resistivity aluminum antimonide radiation detector

    DOE Patents [OSTI]

    Sherohman, John W.; Coombs, III, Arthur W.; Yee, Jick H.

    2005-05-03

    Bulk Aluminum Antimonide (AlSb)-based single crystal materials have been prepared for use as ambient (room) temperature X-ray and Gamma-ray radiation detection.

  19. Co-Al mixed metal oxides/carbon nanotubes nanocomposite prepared via a precursor route and enhanced catalytic property

    SciTech Connect (OSTI)

    Fan Guoli; Wang Hui; Xiang Xu; Li Feng

    2013-01-15

    The present work reported the synthesis of Co-Al mixed metal oxides/carbon nanotubes (CoAl-MMO/CNT) nanocomposite from Co-Al layered double hydroxide/CNTs composite precursor (CoAl-LDH/CNT). The materials were characterized by powder X-ray diffraction (XRD), transmission electron microscopy (TEM), low temperature nitrogen adsorption-desorption experiments, thermogravimetric and differential thermal analyses (TG-DTA), Raman spectra and X-ray photoelectron spectroscopy (XPS). The results revealed that in CoAl-MMO/CNT nanocomposite, the nanoparticles of cobalt oxide (CoO) and Co-containing spinel-type complex metal oxides could be well-dispersed on the surface of CNTs, thus forming the heterostructure of CoAl-MMO and CNTs. Furthermore, as-synthesized CoAl-MMO/CNT nanocomposite was utilized as additives for catalytic thermal decomposition of ammonium perchlorate (AP). Compared to those for pure AP and CoAl-MMO, the peak temperature of AP decomposition for CoAl-MMO/CNT was significantly decreased, which is attributed to the novel heterostructure and synergistic effect of multi-component metal oxides of nanocomposite. - Graphical abstract: Hybrid Co-Al mixed metal oxides/carbon nanotubes nanocomposite showed the enhanced catalytic activity in the thermal decomposition of ammonium perchlorate, as compared to carbon nanotubes and pure Co-Al mixed metal oxides. Highlights: Black-Right-Pointing-Pointer Co-Al mixed metal oxides/carbon nanotubes nanocomposite was synthesized. Black-Right-Pointing-Pointer Co-Al mixed metal oxides consisted of cobalt oxide and Co-containing spinels. Black-Right-Pointing-Pointer Nanocomposite exhibited excellent catalytic activity for the decomposition of AP. Black-Right-Pointing-Pointer The superior catalytic property is related to novel heterostructure and composition.

  20. Development of metallization for GaAs and AlGaAs concentrator solar cells

    SciTech Connect (OSTI)

    Tobin, S.P.

    1987-04-01

    A three-layer metallization system was developed for high temperature stability on GaAs and AlGaAs solar cells. The layers are a Pt ohmic contact metal that forms thermally stable compounds with GaAs, a TiN diffusion barrier, and a gold conductor. The solar cell structure was also designed for contact stability, with the key component being a heavily doped GaAs cap layer. Reactively sputtered TiN was found to act as an excellent barrier when deposited under the proper conditions. The conditions were carefully optimized for low resistivity and low stress in the films. A low but nonzero substrate bias during sputtering was found to be important. Solar cells with sputtered metallizations of Pt/TiN/Ti/Pt/Au were found to be thermally stable up to 500/sup 0/C for 15 minutes in vacuum. At 600/sup 0/C there was catastrophic degradation of the cells due to dissociation of uncapped GaAs surfaces. Below this temperature the metallization performed as designed. The Pt and GaAs layers reacted to form a stable PtGa compound layer that gave low contact resistance. There was no penetration of Au or GaAs through the barrier layer. These results are a very encouraging first step leading to stable, reliable GaAs and AlGaAs concentrator cells.

  1. Regeneration of aluminum hydride

    DOE Patents [OSTI]

    Graetz, Jason Allan (Mastic, NY); Reilly, James J. (Bellport, NY)

    2009-04-21

    The present invention provides methods and materials for the formation of hydrogen storage alanes, AlH.sub.x, where x is greater than 0 and less than or equal to 6 at reduced H.sub.2 pressures and temperatures. The methods rely upon reduction of the change in free energy of the reaction between aluminum and molecular H.sub.2. The change in free energy is reduced by lowering the entropy change during the reaction by providing aluminum in a state of high entropy, by increasing the magnitude of the change in enthalpy of the reaction or combinations thereof.

  2. Regeneration of aluminum hydride

    DOE Patents [OSTI]

    Graetz, Jason Allan; Reilly, James J; Wegrzyn, James E

    2012-09-18

    The present invention provides methods and materials for the formation of hydrogen storage alanes, AlH.sub.x, where x is greater than 0 and less than or equal to 6 at reduced H.sub.2 pressures and temperatures. The methods rely upon reduction of the change in free energy of the reaction between aluminum and molecular H.sub.2. The change in free energy is reduced by lowering the entropy change during the reaction by providing aluminum in a state of high entropy, and by increasing the magnitude of the change in enthalpy of the reaction or combinations thereof.

  3. Activated aluminum hydride hydrogen storage compositions and uses thereof

    DOE Patents [OSTI]

    Sandrock, Gary (Ringwood, NJ); Reilly, James (Bellport, NY); Graetz, Jason (Mastic, NY); Wegrzyn, James E. (Brookhaven, NY)

    2010-11-23

    In one aspect, the invention relates to activated aluminum hydride hydrogen storage compositions containing aluminum hydride in the presence of, or absence of, hydrogen desorption stimulants. The invention particularly relates to such compositions having one or more hydrogen desorption stimulants selected from metal hydrides and metal aluminum hydrides. In another aspect, the invention relates to methods for generating hydrogen from such hydrogen storage compositions.

  4. Characterization of Mg/Al butt joints welded by gas tungsten arc filling with Zn–29.5Al–0.5Ti filler metal

    SciTech Connect (OSTI)

    Liu, Fei; Wang, Hongyang; Liu, Liming, E-mail: liulm@dlut.edu.cn

    2014-04-01

    The multivariate alloying design of a welding joint is used in the Mg to Al welding process. A Zn–29.5Al–0.5Ti alloy is added as filler metal in gas tungsten arc welding of Mg and Al alloy joint based on the analysis of Al and Mg alloy characteristics. The tensile strength, microstructure, and phase constitution of the weld seam are analyzed. The formation of brittle and hard Mg–Al intermetallic compounds is avoided because of the effects of Zn, Al, and Ti. The average tensile strength of the joint is 148 MPa. Al{sub 3}Ti is first precipitated and functions as the nucleus of heterogeneous nucleation during solidification. Moreover, the precipitated Al–MgZn{sub 2} hypoeutectic phase exhibited a feather-like structure, which enhances the property of the Mg–Al dissimilar joint. - Highlights: • Mg alloy AZ31B and Al alloy 6061 are butt welded by fusion welding. • The effect of Ti in filler metal is investigated. • The formation of Mg–Al intermetallic compounds is avoided.

  5. Rechargeable Aluminum-Ion Batteries

    SciTech Connect (OSTI)

    Paranthaman, Mariappan Parans [ORNL; Liu, Hansan [ORNL; Sun, Xiao-Guang [ORNL; Dai, Sheng [ORNL; Brown, Gilbert M [ORNL

    2015-01-01

    This chapter reports on the development of rechargeable aluminum-ion batteries. A possible concept of rechargeable aluminum/aluminum-ion battery based on low-cost, earth-abundant Al anode, ionic liquid EMImCl:AlCl3 (1-ethyl-3-methyl imidazolium chloroaluminate) electrolytes and MnO2 cathode has been proposed. Al anode has been reported to show good reversibility in acid melts. However, due to the problems in demonstrating the reversibility in cathodes, alternate battery cathodes and battery concepts have also been presented. New ionic liquid electrolytes for reversible Al dissolution and deposition are needed in the future for replacing corrosive EMImCl:AlCl3 electrolytes.

  6. Extraction of trace metals from fly ash

    DOE Patents [OSTI]

    Blander, Milton (Palos Park, IL); Wai, Chien M. (Moscow, ID); Nagy, Zoltan (Woodridge, IL)

    1984-01-01

    A process for recovering silver, gallium and/or other trace metals from a fine grained industrial fly ash associated with a process for producing phosphorous, the fly ash having a silicate base and containing surface deposits of the trace metals as oxides, chlorides or the like, with the process being carried out by contacting the fly ash with AlCl.sub.3 in an alkali halide melt to react the trace metals with the AlCl.sub.3 to form compositions soluble in the melt and a residue containing the silicate and aluminum oxide or other aluminum precipitate, and separating the desired trace metal or metals from the melt by electrolysis or other separation techniques.

  7. Extraction of trace metals from fly ash

    DOE Patents [OSTI]

    Blander, M.; Wai, C.M.; Nagy, Z.

    1983-08-15

    A process is described for recovering silver, gallium and/or other trace metals from a fine grained industrial fly ash associated with a process for producing phosphorous. The fly ash has a silicate base and contains surface deposits of the trace metals as oxides, chlorides or the like. The process is carried out by contacting the fly ash with AlCl/sub 3/ in an alkali halide melt to react the trace metals with the AlCl/sub 3/ to form compositions soluble in the melt and a residue containing the silicate and aluminum oxide or other aluminum precipitate, and separating the desired trace metal or metals from the melt by electrolysis or other separation techniques.

  8. Electrical characterization of native-oxide InAlPGaAs metal-oxide-semiconductor heterostructures using

    E-Print Network [OSTI]

    Electrical characterization of native-oxide InAlPÕGaAs metal-oxide-semiconductor heterostructures 8 December 2003; accepted 20 January 2004 InAIP native oxide/GaAs metal-oxide-semiconductor MOS of Schottky gates can lead to excessive gate leakage current and also restrict the forward gate bias to only

  9. Overview of Aluminum

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Aluminum Overview of Aluminum Overview of Aluminum Session Coordinator: Mark T. Smith Pacific Northwest National Laboratory VT Merit Review 2008 February 28, 2008 2 Overview of...

  10. Critical magnetic fields of superconducting aluminum-substituted Ba{sub 8}Si{sub 42}Al{sub 4} clathrate

    SciTech Connect (OSTI)

    Li, Yang Garcia, Jose; Lu, Kejie; Shafiq, Basir; Franco, Giovanni; Lu, Junqiang; Rong, Bo; Chen, Ning; Liu, Yang; Liu, Lihua; Song, Bensheng; Wei, Yuping; Johnson, Shardai S.; Luo, Zhiping; Feng, Zhaosheng

    2015-06-07

    In recent years, efforts have been made to explore the superconductivity of clathrates containing crystalline frameworks of group-IV elements. The superconducting silicon clathrate is unusual in that the structure is dominated by strong sp{sup 3} covalent bonds between silicon atoms, rather than the metallic bonding that is more typical of traditional superconductors. This paper reports on critical magnetic fields of superconducting Al-substituted silicon clathrates, which were investigated by transport, ac susceptibility, and dc magnetization measurements in magnetic fields up to 90 kOe. For the sample Ba{sub 8}Si{sub 42}Al{sub 4}, the critical magnetic fields were measured to be H{sub C1}?=?40.2?Oe and H{sub C2}?=?66.4 kOe. The London penetration depth of 4360?Å and the coherence length 70?Å were obtained, whereas the estimated Ginzburg–Landau parameter of ??=?62 revealed that Ba{sub 8}Si{sub 42}Al{sub 4} is a strong type-II superconductor.

  11. ''Heat Transfer at the Mold-Metal Interface in Permanent Mold Casting of Aluminum Alloys'' Final Project Report

    SciTech Connect (OSTI)

    Professor R. D. Pehlke, Principal Investigator, Dr. John M. Cookson, Dr. Shouwei Hao, Dr. Prasad Krishna, Kevin T. Bilkey

    2001-12-14

    This project on heat transfer coefficients in metal permanent mold casting has been conducted in three areas. They are the theoretical study at the University of Michigan, the experimental investigation of squeeze casting at CMI-Tech Center (Now Hayes-Lemmerz Technical Center) and the experimental investigation of low pressure permanent mold casting at Amcast Automotive.

  12. Understanding composite explosive energetics: 3, Reactive flow modeling of aluminum reaction kinetics in PETN and TNT

    SciTech Connect (OSTI)

    Tao, W.C.; Tarver, C.M.; Ornellas, D.L.

    1991-12-06

    Using Fabry-Perot interferometry techniques, we have determined that early time rate of energy release from detonating PETN and TNT explosives filled with 5 and 10 wt % of either 5 {mu}m of 18 {mu}m spherical aluminum (Al) particles. From the measured particle velocity data, we are able to infer the reaction rate of aluminum with the detonation products, and calculate the extent of reaction 1--3 {mu}s after the detonation. We observed that a substantional portion of the aluminum metal in all of the PETN and TNE formulations reacted within the timeframe of the one-dimensional experiment. In the PETN formulation filed with 5 wt % of 5 {mu}m aluminum, all of the metal reacted within 1.5 {mu}s, resulting in an increase of 22% in energy compared to pure PETN. A reactive-flow hydrodynamic model based on the Zeldovich-von Neumann-Doring (ZND) description of the reaction zone and subsequent reaction produce expansion (Taylor wave) is used to interpret the reaction rate of the aluminum particles with detonation product gases. The diffusion-controlled reaction mechanism for aluminum and the global kinetic parameters used in the model have been found to be consistent for all the PETN and TNT formulations.

  13. Single-crystalline aluminum film for ultraviolet plasmonic nanolasers

    E-Print Network [OSTI]

    Chou, Bo-Tsun; Wu, Yen-Mo; Chung, Yi-Chen; Hsueh, Wei-Jen; Lin, Shih-Wei; Lu, Tien-Chang; Lin, Tzy-Rong; Lin, Sheng-Di

    2015-01-01

    Plasmonic devices have advanced significantly in the past decade. Being one of the most intriguing devices, plamonic nanolasers plays an important role in biomedicine, chemical sensor, information technology, and optical integrated circuits. However, nanoscale plasmonic devices, particularly in ultraviolet regime, are extremely sensitive to metal and interface quality, which renders the development of ultraviolet plasmonics. Here, by addressing the material issues, we demonstrate a low threshold, high characteristic temperature metal-oxide-semiconductor ZnO nanolaser working at room temperature. The template for ZnO nanowires consists of a flat single-crystalline aluminum film grown by molecular beam epitaxy and an ultra-smooth Al2O3 spacer layer prepared by atomic layer deposition. By effectively reducing surface plasmon scattering loss and metal intrinsic absorption loss, the high-quality metal film and sharp interfaces between layers boost the device performance. Our work paves the way for future applicati...

  14. Production of anhydrous aluminum chloride composition and process for electrolysis thereof

    DOE Patents [OSTI]

    Vandegrift, George F. (Bolingbrook, Naperville, IL); Krumpelt, Michael (Naperville, IL); Horwitz, E. Philip (Hinsdale, IL)

    1983-01-01

    A process for producing an anhydrous aluminum chloride composition from a water-based aluminous material such as a slurry of aluminum hydroxide in a multistage extraction process in which the aluminum ion is first extracted into an organic liquid containing an acidic extractant and then extracted from the organic phase into an alkali metal chloride or chlorides to form a melt containing a mixture of chlorides of alkali metal and aluminum. In the process, the organic liquid may be recycled. In addition, the process advantageously includes an electrolysis cell for producing metallic aluminum and the alkali metal chloride or chlorides may be recycled for extraction of the aluminum from the organic phase.

  15. Method of forming aluminum oxynitride material and bodies formed by such methods

    DOE Patents [OSTI]

    Bakas, Michael P. (Ammon, ID) [Ammon, ID; Lillo, Thomas M. (Idaho Falls, ID) [Idaho Falls, ID; Chu, Henry S. (Idaho Falls, ID) [Idaho Falls, ID

    2010-11-16

    Methods of forming aluminum oxynitride (AlON) materials include sintering green bodies comprising aluminum orthophosphate or another sacrificial material therein. Such green bodies may comprise aluminum, oxygen, and nitrogen in addition to the aluminum orthophosphate. For example, the green bodies may include a mixture of aluminum oxide, aluminum nitride, and aluminum orthophosphate or another sacrificial material. Additional methods of forming aluminum oxynitride (AlON) materials include sintering a green body including a sacrificial material therein, using the sacrificial material to form pores in the green body during sintering, and infiltrating the pores formed in the green body with a liquid infiltrant during sintering. Bodies are formed using such methods.

  16. Investigation of abrasion in Al–MgO metal matrix composites

    SciTech Connect (OSTI)

    Muharr em Pul; Çalin, Recep; Gül, Ferhat

    2014-12-15

    In this study, the effects of reinforcement volume fractions on abrasive wear behavior were examined in Al–MgO reinforced metal matrix composites of 5%, 10% and 15% reinforcement – volume ratios produced by melt-stirring. Abrasive wear tests were carried out by 60, 80 and 100 mesh sized Al{sub 2}O{sub 3} abrasive papers and pin-on-disc wear test apparatus under 10, 20 and 30 N loads at 0.2 m/s sliding speed. The mechanical properties such as hardness and fracture strength were determined. Subsequent to the wear tests, the microstructures of worn surfaces were examined by scanning electron microscope analyses. While increased MgO reinforcement volume fraction in the composite resulted increased hardness, fracture strength was determined to decrease. Additionally, it was found that increased MgO reinforcement volume fraction in the composite was accompanied with increased wear loss and porosity as well as reinforcement – volume ratio was identified to be significant determinants of abrasive wear behavior.

  17. Erroneous Wave Functions of Ciuchi et al for Collective Modes in Neutron Production on Metallic Hydride Cathodes

    E-Print Network [OSTI]

    A. Widom; Y. N. Srivastava; L. Larsen

    2012-10-17

    There is a recent comment (Ciuchi et al., 2012) concerning the theory of collective many body effects on the neutron production rates in a chemical battery cathode. Ciuchi et al employ an inverse beta decay expression that contains a two body amplitude. Only one electron and one proton may exist in the Ciuchi et al model initial state wave function. A flaw in their reasoning is that one cannot in reality describe collective many body correlations with only a two particle wave function. One needs very many particles to describe collective effects. In the model wave functions of Ciuchi et al there are no metallic hydrides, there are no cathodes and there are no chemical batteries. Employing a wave function with only one electron and one proton is inadequate for describing collective metallic hydride surface quantum plasma physics in cathodes accurately.

  18. Analysis of AlN/AlGaN/GaN metal-insulator-semiconductor structure by using capacitance-frequency-temperature mapping

    SciTech Connect (OSTI)

    Shih, Hong-An; Kudo, Masahiro; Suzuki, Toshi-kazu [Center for Nano Materials and Technology, Japan Advanced Institute of Science and Technology (JAIST), 1-1 Asahidai, Nomi, Ishikawa 923-1292 (Japan)

    2012-07-23

    AlN/AlGaN/GaN metal-insulator-semiconductor (MIS) structure is analyzed by using capacitance-frequency-temperature (C-f-T) mapping. Applying sputtering-deposited AlN, we attained AlN/AlGaN/GaN MIS heterostructure field-effect transistors with much suppressed gate leakage currents, but exhibiting frequency dispersion in C-V characteristics owing to high-density AlN/AlGaN interface states. In order to investigate the interface states deteriorating the device performance, we measured temperature-dependent frequency dispersion in the C-V characteristics. As a result, we obtained C-f-T mapping, whose analysis gives the activation energies of electron trapping, namely the interface state energy levels, for a wide range of the gate biases. This analysis method is auxiliary to the conventional conductance method, serving as a valuable tool for characterization of wide-bandgap devices with deep interface states. From the analysis, we can directly evaluate the gate-control efficiency of the devices.

  19. Spectroscopy of jet-cooled AlMn and trends in the electronic structure of the 3d transition metal aluminides

    E-Print Network [OSTI]

    Morse, Michael D.

    Spectroscopy of jet-cooled AlMn and trends in the electronic structure of the 3d transition metal, Utah 84112 (Received 9 May 1994; accepted 28 June 1994) Jet-cooled diatomic AlMn has been

  20. Identity of Passive Film Formed on Aluminum in Li-ion Battery Electrolytes with LiPF6

    E-Print Network [OSTI]

    Zhang, Xueyuan; Devine, T.M.

    2008-01-01

    Influence Formation of AlF 3 Passive Film on Aluminum in Li-Identity of Passive Film Formed on Aluminum in Li-ionEngineering Abstract The passive film that forms on aluminum

  1. Microstructure evolution of Al/Mg butt joints welded by gas tungsten arc with Zn filler metal

    SciTech Connect (OSTI)

    Liu Fei; Zhang Zhaodong; Liu Liming, E-mail: liulm@dlut.edu.cn

    2012-07-15

    Based on the idea of alloying welding seam, Gas tungsten arc welding method with pure Zn filler metal was chosen to join Mg alloy and Al alloy. The microstructures, phases, element distribution and fracture morphology of welding seams were examined. The results indicate that there was a transitional zone in the width of 80-100 {mu}m between the Mg alloy substrate and fusion zone. The fusion zone was mainly composed of MgZn{sub 2}, Zn-based solid solution and Al-based solid solution. The welding seam presented distinct morphology in different location owning to the quite high cooling rate of the molten pool. The addition of Zn metal could prevent the formation of Mg-Al intermetallics and form the alloyed welding seam during welding. Therefore, the tensile strengths of joints have been significantly improved compared with those of gas tungsten arc welded joints without Zn metal added. Highlights: Black-Right-Pointing-Pointer Mg alloy AZ31B and Al alloy 6061 are welded successfully. Black-Right-Pointing-Pointer Zinc wire is employed as a filler metal to form the alloyed welding seam. Black-Right-Pointing-Pointer An alloyed welding seam is benefit for improving of the joint tensile strength.

  2. Thermoelectric properties of lattice-matched AlInN alloy grown by metal organic chemical vapor deposition

    E-Print Network [OSTI]

    Gilchrist, James F.

    Thermoelectric properties of lattice-matched AlInN alloy grown by metal organic chemical vapor Seebeck coefficient and resistance measurement system for thermoelectric materials in the thin disk geometry Rev. Sci. Instrum. 83, 025101 (2012) High-temperature thermoelectric properties of Cu1­xInTe2

  3. Aluminum-detoxifying compounds in roots of Eucalyptus camaldulensis

    E-Print Network [OSTI]

    Tahara, Ko; Hashida, Koh; Ohara, Seiji; Kojima, Katsumi; Shinohara, Kenji

    2009-01-01

    tips of Melaleuca and Eucalyptus species. J For Res. 2005;in aluminum resistance of Eucalyptus camaldulensis andplants (Kochian et al. 2004). Eucalyptus camaldulensis is a

  4. High Waste Loading Glass Formulations for Hanford High-Aluminum...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    mixtures of aluminum (Al), chromium (Cr), bismuth (Bi), iron (Fe), phosphorous (P), zirconium (Zr), and sulfur (S) compounds as waste-limiting components. Glass compositions for...

  5. For cermet inert anode containing oxide and metal phases useful for the electrolytic production of metals

    DOE Patents [OSTI]

    Ray, Siba P. (Murrysville, PA); Liu, Xinghua (Monroeville, PA); Weirauch, Douglas A. (Murrysville, PA)

    2002-01-01

    A cermet inert anode for the electrolytic production of metals such as aluminum is disclosed. The inert anode comprises a ceramic phase including an oxide of Ni, Fe and M, where M is at least one metal selected from Zn, Co, Al, Li, Cu, Ti, V, Cr, Zr, Nb, Ta, W, Mo, Hf and rare earths, preferably Zn and/or Co. Preferred ceramic compositions comprise Fe.sub.2 O.sub.3, NiO and ZnO or CoO. The cermet inert anode also comprises a metal phase such as Cu, Ag, Pd, Pt, Au, Rh, Ru, Ir and/or Os. A preferred metal phase comprises Cu and Ag. The cermet inert anodes may be used in electrolytic reduction cells for the production of commercial purity aluminum as well as other metals.

  6. System and process for aluminization of metal-containing substrates

    DOE Patents [OSTI]

    Chou, Yeong-Shyung; Stevenson, Jeffry W

    2015-11-03

    A system and method are detailed for aluminizing surfaces of metallic substrates, parts, and components with a protective alumina layer in-situ. Aluminum (Al) foil sandwiched between the metallic components and a refractory material when heated in an oxidizing gas under a compression load at a selected temperature forms the protective alumina coating on the surface of the metallic components. The alumina coating minimizes evaporation of volatile metals from the metallic substrates, parts, and components in assembled devices during operation at high temperature that can degrade performance.

  7. Corrosion protective coating for metallic materials

    DOE Patents [OSTI]

    Buchheit, R.G.; Martinez, M.A.

    1998-05-26

    Corrosion protective coatings for metallic materials, particularly aluminum and aluminum alloys, produced with simple, low-cost equipment and materials other than toxic metals or metal salts, or metal cyanides is disclosed. The metallic material is cleaned, degreased, and deoxidized, the surface is converted to a substantially alkaline condition, and the surface is chemically sealed with inorganic metal compounds. 1 fig.

  8. Amorphous Al-transition Metal Alloys as Anode Material for Lithium Ion Battery

    E-Print Network [OSTI]

    Wang, C.Y.

    Al based alloy powders (Al??Ni?Y?Co?Fe?) are produced by spray atomization method. High energy ball milling is done to modify the surface topology and particle size for better electrochemical performance. X ray diffraction ...

  9. ITP Aluminum: Aluminum Industry Roadmap for the Automotive Market...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Aluminum Industry Roadmap for the Automotive Market (May 1999) ITP Aluminum: Aluminum Industry Roadmap for the Automotive Market (May 1999) autoroadmap.pdf More Documents &...

  10. TiN coated aluminum electrodes for DC high voltage electron guns

    SciTech Connect (OSTI)

    Mamun, Md Abdullah A.; Elmustafa, Abdelmageed A.; Taus, Rhys; Forman, Eric; Poelker, Matthew

    2015-05-15

    Preparing electrodes made of metals like stainless steel, for use inside DC high voltage electron guns, is a labor-intensive and time-consuming process. In this paper, the authors report the exceptional high voltage performance of aluminum electrodes coated with hard titanium nitride (TiN). The aluminum electrodes were comparatively easy to manufacture and required only hours of mechanical polishing using silicon carbide paper, prior to coating with TiN by a commercial vendor. The high voltage performance of three TiN-coated aluminum electrodes, before and after gas conditioning with helium, was compared to that of bare aluminum electrodes, and electrodes manufactured from titanium alloy (Ti-6Al-4V). Following gas conditioning, each TiN-coated aluminum electrode reached ?225?kV bias voltage while generating less than 100?pA of field emission (<10?pA) using a 40?mm cathode/anode gap, corresponding to field strength of 13.7?MV/m. Smaller gaps were studied to evaluate electrode performance at higher field strength with the best performing TiN-coated aluminum electrode reaching ?22.5 MV/m with field emission less than 100?pA. These results were comparable to those obtained from our best-performing electrodes manufactured from stainless steel, titanium alloy and niobium, as reported in references cited below. The TiN coating provided a very smooth surface and with mechanical properties of the coating (hardness and modulus) superior to those of stainless steel, titanium-alloy, and niobium electrodes. These features likely contributed to the improved high voltage performance of the TiN-coated aluminum electrodes.

  11. Low-aluminum-content iron-aluminum alloys

    SciTech Connect (OSTI)

    Sikka, V.K.; Baldwin, R.H.; Howell, C.R.

    1993-07-01

    The low room-temperature ductility Fe{sub 3}Al-based alloys is associated with their environmental embrittlement. Reducing the aluminum level from 29 to 16 at % has been found to be an effective method in essentially eliminating the environmental-embrittlement effect and increasing the room-temperature ductility value to over 25%. This paper will present data on alloy compositions, melting, casting and processing methods, and mechanical properties. Plans for future work on these alloys will also be described.

  12. Electromigration in metal interconnects is the most pernicious failure mechanism in semiconductor integrated circuits (ICs). Early electromigration investigations were primarily focused on aluminum interconnects for

    E-Print Network [OSTI]

    Electromigration in metal interconnects is the most pernicious failure mechanism in semiconductor interconnects for silicon-based ICs. An alternative metallization compatible with gallium arsenide (Ga at higher current densities and elevated temperatures. Gold-based metallization was implemented on Ga

  13. Development Program for Natural Aging Aluminum Casting Alloys

    SciTech Connect (OSTI)

    Dr. Geoffrey K. Sigworth

    2004-05-14

    A number of 7xx aluminum casting alloys are based on the ternary Al-Zn-Mg system. These alloys age naturally to high strength at room temperature. A high temperature solution and aging treatment is not required. Consequently, these alloys have the potential to deliver properties nearly equivalent to conventional A356-T6 (Al-Si-Mg) castings, with a significant cost saving. An energy savings is also possible. In spite of these advantages, the 7xx casting alloys are seldom used, primarily because of their reputation for poor castibility. This paper describes the results obtained in a DOE-funded research study of these alloys, which is part of the DOE-OIT ''Cast Metals Industries of the Future'' Program. Suggestions for possible commercial use are also given.

  14. July/August 20056 Casting aluminum

    E-Print Network [OSTI]

    Colton, Jonathan S.

    July/August 20056 Bob Rapp Casting aluminum Lay people unfamiliar with metallurgical processing to cast Al commercially. Perhaps I can interest the reader with a summary of this important process. I refer to casting large Al shapes suitable for rolling, forging, pressing, extruding, or drawing to make

  15. Joining aluminum to titanium alloy by friction stir lap welding with cutting pin

    SciTech Connect (OSTI)

    Wei, Yanni [State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi'an 710072 (China) [State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi'an 710072 (China); Shaanxi Key Laboratory of Friction Welding Technologies, Northwestern Polytechnical University, Xi'an 710072 (China); Li, Jinglong, E-mail: lijinglg@nwpu.edu.cn [Shaanxi Key Laboratory of Friction Welding Technologies, Northwestern Polytechnical University, Xi'an 710072 (China)] [Shaanxi Key Laboratory of Friction Welding Technologies, Northwestern Polytechnical University, Xi'an 710072 (China); Xiong, Jiangtao [State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi'an 710072 (China) [State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi'an 710072 (China); Shaanxi Key Laboratory of Friction Welding Technologies, Northwestern Polytechnical University, Xi'an 710072 (China); Huang, Fu; Zhang, Fusheng; Raza, Syed Hamid [Shaanxi Key Laboratory of Friction Welding Technologies, Northwestern Polytechnical University, Xi'an 710072 (China)] [Shaanxi Key Laboratory of Friction Welding Technologies, Northwestern Polytechnical University, Xi'an 710072 (China)

    2012-09-15

    Aluminum 1060 and titanium alloy Ti-6Al-4V plates were lap joined by friction stir welding. A cutting pin of rotary burr made of tungsten carbide was employed. The microstructures of the joining interface were observed by scanning electron microscopy. Joint strength was evaluated by a tensile shear test. During the welding process, the surface layer of the titanium plate was cut off by the pin, and intensively mixed with aluminum situated on the titanium plate. The microstructures analysis showed that a visible swirl-like mixed region existed at the interface. In this region, the Al metal, Ti metal and the mixed layer of them were all presented. The ultimate tensile shear strength of joint reached 100% of 1060Al that underwent thermal cycle provided by the shoulder. - Highlights: Black-Right-Pointing-Pointer FSW with cutting pin was successfully employed to form Al/Ti lap joint. Black-Right-Pointing-Pointer Swirl-like structures formed due to mechanical mixing were found at the interface. Black-Right-Pointing-Pointer High-strength joints fractured at Al suffered thermal cycle were produced.

  16. Galvanic corrosion of aluminum-matrix composites. Technical report No. 2, 1 Mar-31 Dec 90

    SciTech Connect (OSTI)

    Hihara, L.H.; Latanision, R.M.

    1991-02-01

    Galvanic-corrosion rates of Al-matrix composites were high in aerated chloride-containing solutions. Oxygen reduction was found to be the primary cathodic reaction. Aluminum corroded by pitting. The type of noble constituent (i.e., graphite, SiC, or TiB{sub 2}) also affected galvanic-corrosion rates. For example, results indicated that the galvanic-corrosion rate of Al should be about 30 times greater when coupled to graphite than when coupled to SiC or TiB{sub 2}. In dearated solutions, galvanic corrosion was negligible even if chlorides were present. The galvanic-corrosion rates were determined using the zero-resistance ammeter technique and from potentiodynamic polarization diagrams of ultrapure Al, 6061-T6 Al, graphite fiber, SiC, TiB2, and a commercial graphite fiber/6061-T6 Al metal-matrix composite.

  17. A Heterobimetallic Complex With an Unsupported Uranium(III)-Aluminum(I) Bond: (CpSiMe3)3U-AlCp* (Cp* = C5Me5)

    E-Print Network [OSTI]

    Minasian, Stefan

    2009-01-01

    of the ? HOMO-4 (BPW91). The Cp ligand contributions wereI) Bond: (CpSiMe 3 ) 3 U–AlCp* (Cp* = C 5 Me 5 ) Stefan G.uncommon, consisting of Cp 3 U– SnPh 3 , and several

  18. Epitaxial growth of aligned AlGalnN nanowires by metal-organic chemical vapor deposition

    DOE Patents [OSTI]

    Han, Jung (Woodbridge, CT); Su, Jie (New Haven, CT)

    2008-08-05

    Highly ordered and aligned epitaxy of III-Nitride nanowires is demonstrated in this work. <1010> M-axis is identified as a preferential nanowire growth direction through a detailed study of GaN/AlN trunk/branch nanostructures by transmission electron microscopy. Crystallographic selectivity can be used to achieve spatial and orientational control of nanowire growth. Vertically aligned (Al)GaN nanowires are prepared on M-plane AlN substrates. Horizontally ordered nanowires, extending from the M-plane sidewalls of GaN hexagonal mesas or islands demonstrate new opportunities for self-aligned nanowire devices, interconnects, and networks.

  19. Aqueous recovery of actinides from aluminum alloys

    SciTech Connect (OSTI)

    Gray, J.H.; Chostner, D.F.; Gray, L.W.

    1989-01-01

    Early in the 1980's, a joint Rocky Flats/Savannah River program was established to recover actinides from scraps and residues generated during Rocky Flats purification operations. The initial program involved pyrochemical treatment of Molten Salt Extraction (MSE) chloride salts and Electrorefining (ER) anode heel metal to form aluminum alloys suitable for aqueous processing at Savannah River. Recently Rocky Flats has expressed interest in expanding the aluminum alloy program to include treatment of chloride salt residues from a modified Molten Salt Extraction process and from the Electrorefining purification operations. Samples of the current aluminum alloy buttons were prepared at Rocky Flats and sent to Savannah River Laboratory for flowsheet development and characterization of the alloys. A summary of the scrub alloy-anode heel alloy program will be presented along with recent results from aqueous dissolution studies of the new aluminum alloys. 2 figs., 4 tabs.

  20. Electrodeposition of magnesium and magnesium/aluminum alloys

    DOE Patents [OSTI]

    Mayer, A.

    1988-01-21

    Electrolytes and plating solutions for use in processes for electroplating and electroforming pure magnesium and alloys of aluminum and magnesium and also electrodeposition processes. An electrolyte of this invention is comprised of an alkali metal fluoride or a quaternary ammonium halide, dimethyl magnesium and/or diethyl magnesium, and triethyl aluminum and/or triisobutyl aluminum. An electrolyte may be dissolved in an aromatic hydrocarbon solvent to form a plating solution. The proportions of the component compounds in the electrolyte are varied to produce essentially pure magnesium or magnesium/aluminum alloys having varying selected compositions.

  1. Electrodeposition of magnesium and magnesium/aluminum alloys

    DOE Patents [OSTI]

    Mayer, Anton (Los Alamos, NM)

    1988-01-01

    Electrolytes and plating solutions for use in processes for electroplating and electroforming pure magnesium and alloys of aluminum and magnesium and also electrodeposition processes. An electrolyte of this invention is comprised of an alkali metal fluoride or a quaternary ammonium halide, dimethyl magnesium and/or diethyl magnesium, and triethyl aluminum and/or triisobutyl aluminum. An electrolyte may be dissolved in an aromatic hydrocarbon solvent to form a plating solution. The proportions of the component compounds in the electrolyte are varied to produce essentially pure magnesium or magnesium/aluminum alloys having varying selected compositions.

  2. The design of a power system using treated aluminum fuel

    E-Print Network [OSTI]

    Slocum, Jonathan (Jonathan T.)

    2015-01-01

    Aluminum is the most abundant metal in the Earth's crust and a highly sought after fuel source due to its extreme energy density. It has the ability to produce large quantities of hydrogen and heat when reacted with water ...

  3. Iron and aluminum interaction with amyloid-beta peptides associated with Alzheimer’s disease

    SciTech Connect (OSTI)

    Drochioiu, Gabi; Ion, Laura; Murariu, Manuela; Habasescu, Laura

    2014-10-06

    An elevation in the concentration of heavy metal ions in Alzheimer’s disease (AD) brain has been demonstrated in many studies. A? precipitation and toxicity in AD brains seem to be caused by abnormal interactions with neocortical metal ions, especially iron, copper, zinc, and aluminum [1–3]. There is increasing evidence that iron and aluminum ions are involved in the mechanisms that underlie the neurodegenerative diseases [4,5]. However, evidence was brought to demonstrate that some A? fragments, at physiological pH, are not able to form binary complexes with Fe(III) ions of sufficient stability to compete with metal hydroxide precipitation [6]. On the contrary, multiple metal ions are known to interact with A? peptides [7]. Consequently, we investigated here the interaction of Fe(II/III) and Al(III) ions with some amyloid-? peptides and fragments that results in peptide aggregation and fibrillation [8,9]. Infrared spectroscopy, atomic force microscopy, scanning electron microscopy, electrophoresis and mass spectrometry demonstrated conformational changes of peptides in the presence of such metals.

  4. Fluxing agent for metal cast joining

    DOE Patents [OSTI]

    Gunkel, Ronald W. (Lower Burrell, PA); Podey, Larry L. (Greensburg, PA); Meyer, Thomas N. (Murrysville, PA)

    2002-11-05

    A method of joining an aluminum cast member to an aluminum component. The method includes the steps of coating a surface of an aluminum component with flux comprising cesium fluoride, placing the flux coated component in a mold, filling the mold with molten aluminum alloy, and allowing the molten aluminum alloy to solidify thereby joining a cast member to the aluminum component. The flux preferably includes aluminum fluoride and alumina. A particularly preferred flux includes about 60 wt. % CsF, about 30 wt. % AlF.sub.3, and about 10 wt. % Al.sub.2 O.sub.3.

  5. ITP Aluminum: Aluminum Industry Technology Roadmap

    Office of Energy Efficiency and Renewable Energy (EERE)

    In 2002, the industry created this updated Aluminum Industry Technology Roadmap to define the specific research and development priorities, performance targets, and milestones required to achieve the set vision.

  6. Synthesis and structural characterization of Al{sub 7}C{sub 3}N{sub 3}-homeotypic aluminum silicon oxycarbonitride, (Al{sub 7-x}Si{sub x})(O{sub y}C{sub z}N{sub 6-y-z}) (x{approx}1.2, y{approx}1.0 and z{approx}3.5)

    SciTech Connect (OSTI)

    Urushihara, Daisuke; Kaga, Motoaki; Asaka, Toru; Nakano, Hiromi; Fukuda, Koichiro

    2011-08-15

    A new aluminum silicon oxycarbonitride, (Al{sub 5.8}Si{sub 1.2})(O{sub 1.0}C{sub 3.5}N{sub 1.5}), has been synthesized and characterized by X-ray powder diffraction (XRPD), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDX) and electron energy loss spectroscopy (EELS). The title compound is hexagonal with space group P6{sub 3}/mmc and unit-cell dimensions a=0.322508(4) nm, c=3.17193(4) nm and V=0.285717(6) nm{sup 3}. The atom ratios of Al:Si and those of O:C:N were, respectively, determined by EDX and EELS. The initial structural model was successfully derived from the XRPD data by the direct methods and further refined by the Rietveld method. The crystal is most probably composed of four types of domains with nearly the same fraction, each of which is isotypic to Al{sub 7}C{sub 3}N{sub 3} with space group P6{sub 3}mc. The existence of another new oxycarbonitride (Al{sub 6.6}Si{sub 1.4})(O{sub 0.7}C{sub 4.3}N{sub 2.0}), which must be homeotypic to Al{sub 8}C{sub 3}N{sub 4}, has been also demonstrated by XRPD and TEM. - Graphical abstract: A new oxycarbonitride discovered in the Al-Si-O-C-N system, (Al{sub 7-x}Si{sub x})(O{sub y}C{sub z}N{sub 6-y-z}) (x{approx}1.2, y{approx}1.0 and z{approx}3.5). The crystal is composed of four types of domains (I, II, III and IV), and hence the structure is represented by a split-atom model. Individual crystal structures can be regarded as layered structures, which consist of A-type [(Al, Si){sub 4}(O, C, N){sub 4}] unit layers and B-type [(Al, Si)(O, C, N){sub 2}] single layers. Highlights: > (Al{sub 5.8}Si{sub 1.2})(O{sub 1.0}C{sub 3.5}N{sub 1.5}) as a new aluminum silicon oxycarbonitride. > Crystal structure is determined and represented by a split-atom model. > Existence of another new oxycarbonitride (Al{sub 6.6}Si{sub 1.4})(O{sub 0.7}C{sub 4.3}N{sub 2.0}) is demonstrated. > Both new materials are formed by oxidation and nitridation of (Al, Si){sub 6}(O, C){sub 5}.

  7. Optical reflection from the Bragg lattice of AsSb metal nanoinclusions in an AlGaAs matrix

    SciTech Connect (OSTI)

    Ushanov, V. I.; Chaldyshev, V. V., E-mail: chald.gvg@mail.ioffe.ru [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation); Preobrazhenskii, V. V.; Putyato, M. A.; Semyagin, B. R. [Russian Academy of Sciences, Institute of Semiconductor Physics, Siberian Branch (Russian Federation)] [Russian Academy of Sciences, Institute of Semiconductor Physics, Siberian Branch (Russian Federation)

    2013-08-15

    The optical properties of metal-semiconductor metamaterials based on an AlGaAs matrix are studied. The specific feature of these materials is that there are As and AsSb nanoinclusion arrays which modify the dielectric properties of the material. These nanoinclusions are randomly arranged in the medium or form a Bragg structure with a reflectance peak at a wavelength close to 750 nm, corresponding to the transparency region of the matrix. The reflectance spectra are studied for s- and p-polarized light at different angles of incidence. It is shown that (i) As nanoinclusion arrays only slightly influence the optical properties of the medium in the wavelength range 700-900 nm, (ii) chaotic AsSb nanoinclusion arrays cause strong scattering of light, and (iii) the spatial periodicity in the arrangement of AsSb nanoinclusions is responsible for Bragg resonance in the optical reflection.

  8. Energy Saving Melting and Revert Reduction Technology (Energy-SMARRT): Light Metals Permanent Mold Casting

    SciTech Connect (OSTI)

    Fasoyinu, Yemi

    2014-03-31

    Current vehicles use mostly ferrous components for structural applications. It is possible to reduce the weight of the vehicle by substituting these parts with those made from light metals such as aluminum and magnesium. Many alloys and manufacturing processes can be used to produce these light metal components and casting is known to be most economical. One of the high integrity casting processes is permanent mold casting which is the focus of this research report. Many aluminum alloy castings used in automotive applications are produced by the sand casting process. Also, aluminum-silicon (Al-Si) alloys are the most widely used alloy systems for automotive applications. It is possible that by using high strength aluminum alloys based on an aluminum-copper (Al-Cu) system and permanent mold casting, the performance of these components can be enhanced significantly. This will also help to further reduce the weight. However, many technological obstacles need to be overcome before using these alloys in automotive applications in an economical way. There is very limited information in the open literature on gravity and low-pressure permanent mold casting of high strength aluminum alloys. This report summarizes the results and issues encountered during the casting trials of high strength aluminum alloy 206.0 (Al-Cu alloy) and moderate strength alloy 535.0 (Al-Mg alloy). Five engineering components were cast by gravity tilt-pour or low pressure permanent mold casting processes at CanmetMATERIALS (CMAT) and two production foundries. The results of the casting trials show that high integrity engineering components can be produced successfully from both alloys if specific processing parameters are used. It was shown that a combination of melt processing and mold temperature is necessary for the elimination of hot tears in both alloys.

  9. EFFECT OF GRAIN SIZE ON THE ACOUSTIC EMISSION GENERATED DURING PLASTIC DEFORMATION OF ALUMINUM

    E-Print Network [OSTI]

    Baram, J.

    2013-01-01

    EMISSION GENERATED DURING PLASTIC DEFORMATION OF ALUMINUMEMISSION GENERATED DURING PLASTIC DEFORMATION OF ALUMINUM J.Al 1100 samples during plastic deformation were analyzed

  10. Development of damped metal-matrix composites for advanced structural applications. Technical report

    SciTech Connect (OSTI)

    Updike, C.A.; Bhagat, R.B.

    1990-04-01

    The development of damped metal matrix composite structures for advanced applications has been investigated by the use of two different approaches: (1) the development of metal matrix composites with high intrinsic damping compared to that of the matrix material, and (2) the development of coated metal matrix composites with high structural damping compared to that of the composite substrates. The two different approaches are analyzed in terms of their potential for improved damping and feasibility for structural applications. Damping was measured by the transverse vibration of free-free beams using the bandwidth technique by a laser vibrometer under ambient conditions. The damping measurements were made over a wide range of frequencies (.7 kHz to 25.6 kHz) at low strain amplitudes (10 to the -10 power to 10 to the -7 power). Materials investigated for their tensile stiffness, strength, and damping performance include mechanically alloyed (MA) Aluminum-Magnesium, SiC(p)/Aluminum-Copper (MA), SiC(p)/AL, AL2O3(p)/AL, SiC(W)/AL, planar random Gr/AL, unidirectional Gr/AL and unidirectional SiC(Nicalon)/AL composites. The effects of coatings of high damping metals (nitinol and incramute) on 6061-T6 AL and AL2O3(p)/AL substrates have also been studied. The AL-Mg (MA), SiC(p)/AL (MA), SiC(W)/AL and th AL2O3(p)/AL composites show no significant improvement in damping compared with that of the 6061-T6 AL.

  11. Synthesis and structural characterization of Al{sub 4}Si{sub 2}C{sub 5}-homeotypic aluminum silicon oxycarbide, (Al{sub 6-x}Si{sub x})(O{sub y}C{sub 5-y}) (x{approx}0.8 and y{approx}1.6)

    SciTech Connect (OSTI)

    Kaga, Motoaki; Urushihara, Daisuke; Iwata, Tomoyuki; Sugiura, Keita [Department of Environmental and Materials Engineering, Nagoya Institute of Technology, Nagoya 466-8555 (Japan); Nakano, Hiromi [Cooperative Research Facility Center, Toyohashi University of Technology, Toyohashi 441-8580 (Japan); Fukuda, Koichiro, E-mail: fukuda.koichiro@nitech.ac.j [Department of Environmental and Materials Engineering, Nagoya Institute of Technology, Nagoya 466-8555 (Japan)

    2010-09-15

    We have prepared a new layered oxycarbide, [Al{sub 5.25(5)}Si{sub 0.75(5)}][O{sub 1.60(7)}C{sub 3.40(7)}], by isothermal heating of (Al{sub 4.4}Si{sub 0.6})(O{sub 1.0}C{sub 3.0}) at 2273 K near the carbon-carbon monoxide buffer. The crystal structure was characterized using X-ray powder diffraction, transmission electron microscopy and energy dispersive X-ray spectroscopy (EDX). The title compound is trigonal with space group R3m (centrosymmetric), Z=3, and hexagonal cell dimensions a=0.32464(2) nm, c=4.00527(14) nm and V=0.36556(3) nm{sup 3}. The atom ratios Al:Si were determined by EDX, and the initial structural model was derived by the direct methods. The final structural model showed the positional disordering of one of the three types of Al/Si sites. The reliability indices were R{sub wp}=4.45% (S=1.30), R{sub p}=3.48%, R{sub B}=2.27% and R{sub F}=1.25%. The crystal is composed of three types of domains with nearly the same fraction, one of which has the crystal structure of space group R3-bar m. The crystal structure of the remaining two domains, which are related by pseudo-symmetry inversion, is noncentrosymmetric with space group R3m. - Graphical Abstract: A new aluminum silicon oxycarbide, (Al{sub 6-x}Si{sub x})(O{sub y}C{sub 5-y}) (x{approx}0.8 and y{approx}1.6). The crystal is composed of three types of domains (I, II and III), and hence the structure is represented by a split-atom model. Individual crystal structures can be regarded as layered structures, which consist of A-type [(Al,Si){sub 4}(O,C){sub 4}] unit layers and B-type [(Al,Si)(O,C){sub 2}] single layers.

  12. In-situ P/M Al/(ZrB{sub 2} + Al{sub 2}O{sub 3}) MMCs: Processing, microstructure and mechanical characterization[Powder Metallurgy, Metal Matrix Composites

    SciTech Connect (OSTI)

    Feng, C.F.; Froyen, L.

    1999-12-10

    In-situ metal matrix composites (MMCs) offer significant advantages over conventional MMCs from both a technical and an economic standpoint. In this paper, an in-situ MMC, i.e., Al/(10 vol.% Zr2B + 9.2 vol.% Al{sub 2}O{sub 3}), is produced starting from Al + ZrO{sub 2} + B by reactive sintering and subsequently densified by hot-pressing. The formation mechanism of ZrB{sub 2} and Al{sub 2}O{sub 3} in Al matrix is studied by XRD, thermal analysis and microstructural characterization. Reaction kinetics are also investigated based on the results of the reaction mechanism. The properties are evaluated in terms of microstructural characterization, Young's modulus and bending tests. The in-situ processing involves four intermediate steps and the transitional phases are AlB{sub 2}, Zr(O, B){sub 2} and (Zr, Al)(B, O){sub 2}. Regarding the reaction kinetics, conversion fraction vs time relationships have been established for the last three intermediate steps.

  13. Degassing of Aluminum Alloys Using Ultrasonic Vibration

    SciTech Connect (OSTI)

    Meek, T. T.; Han, Q.; Xu, H.

    2006-06-01

    The research was intended to lead to a better fundamental understanding of the effect of ultrasonic energy on the degassing of liquid metals and to develop practical approaches for the ultrasonic degassing of alloys. The goals of the project described here were to evaluate core principles, establish a quantitative basis for the ultrasonic degassing of aluminum alloy melts, and demonstrate the application of ultrsaonic processing during ingot casting and foundry shape casting.

  14. Aluminum ion batteries: electrolytes and cathodes

    E-Print Network [OSTI]

    Reed, Luke

    2015-01-01

    Anodes for Aluminum-Air Batteries. J. Electrochem. Soc.Anodes for Aluminum-Air Batteries. J. Electrochem. Soc.ALLOYS FOR ALUMINUM AIR BATTERIES. J. Electrochem. Soc.

  15. Adhesion evaluation of TiN and (Ti, Al)N coatings on titanium 6Al-4V

    SciTech Connect (OSTI)

    James, R.D.; Gruss, K.A.; Horie, Y.; Davis, R.F.; Paisley, D.L.; Parthasarthi, S.; Tittmann, B.R.

    1996-12-31

    The metallic components of gas turbine engines are continually subjected to hostile atmospheres. Nitride coatings improve the performance of the metallic compressor blades in these engines. To assess the adhesion of nitride coatings on metals, titanium 6% aluminum 4% vanadium substrates were coated with titanium nitride (TiN) using both cathodic arc and electron beam evaporation. Titanium aluminum nitride ((Ti, Al)N) was also deposited using cathodic arc evaporation. The interfaces of the coated samples were loaded in tension using a high speed shock wave which caused spallation either at the interface, in the coating or in the metal. Scanning acoustic microscopy analysis of the spalled samples detected delaminations at the interface in the samples deposited by cathodic arc evaporation. DYNA2D modeling of plate impact spallation experiments revealed the tensile adhesion strength for TiN deposited by both techniques was {approx} 2.0 GPa. The tensile adhesion strength for (Ti, Al)N was less than 1.5 GPa.

  16. DEFLECTION MEASUREMENTS OF 25 mm ALUMINUM COLLARS

    E-Print Network [OSTI]

    Peters, C.

    2010-01-01

    DEFLECTION MEASUREMENTS OF 25 mm ALUMINUM COLLARS· C. PetersDEFLECTION MEASUREMENTS OF 25 mm ALUMINUM COLLARS" C. Peters

  17. ITP Aluminum: Inert Anodes Roadmap

    Broader source: Energy.gov [DOE]

    Aluminum is one of the most versatile materials available today that can meet the demanding requirements of tomorrow's products.

  18. ALUMINUM AND CHROMIUM LEACHING WORKSHOP WHITEPAPER

    SciTech Connect (OSTI)

    McCabe, D; Jeff Pike, J; Bill Wilmarth, B

    2007-04-25

    A workshop was held on January 23-24, 2007 to discuss the status of processes to leach constituents from High Level Waste (HLW) sludges at the Hanford and Savannah River Sites. The objective of the workshop was to examine the needs and requirements for the HLW flowsheet for each site, discuss the status of knowledge of the leaching processes, communicate the research plans, and identify opportunities for synergy to address knowledge gaps. The purpose of leaching of non-radioactive constituents from the sludge waste is to reduce the burden of material that must be vitrified in the HLW melter systems, resulting in reduced HLW glass waste volume, reduced disposal costs, shorter process schedules, and higher facility throughput rates. The leaching process is estimated to reduce the operating life cycle of SRS by seven years and decrease the number of HLW canisters to be disposed in the Repository by 1000 [Gillam et al., 2006]. Comparably at Hanford, the aluminum and chromium leaching processes are estimated to reduce the operating life cycle of the Waste Treatment Plant by 20 years and decrease the number of canisters to the Repository by 15,000-30,000 [Gilbert, 2007]. These leaching processes will save the Department of Energy (DOE) billions of dollars in clean up and disposal costs. The primary constituents targeted for removal by leaching are aluminum and chromium. It is desirable to have some aluminum in glass to improve its durability; however, too much aluminum can increase the sludge viscosity, glass viscosity, and reduce overall process throughput. Chromium leaching is necessary to prevent formation of crystalline compounds in the glass, but is only needed at Hanford because of differences in the sludge waste chemistry at the two sites. Improving glass formulations to increase tolerance of aluminum and chromium is another approach to decrease HLW glass volume. It is likely that an optimum condition can be found by both performing leaching and improving formulations. Disposal of the resulting aluminum and chromium-rich streams are different at the two sites, with vitrification into Low Activity Waste (LAW) glass at Hanford, and solidification in Saltstone at SRS. Prior to disposal, the leachate solutions must be treated to remove radionuclides, resulting in increased operating costs and extended facility processing schedules. Interim storage of leachate can also add costs and delay tank closure. Recent projections at Hanford indicate that up to 40,000 metric tons of sodium would be needed to dissolve the aluminum and maintain it in solution, which nearly doubles the amount of sodium in the entire current waste tank inventory. This underscores the dramatic impact that the aluminum leaching can have on the entire system. A comprehensive view of leaching and the downstream impacts must therefore be considered prior to implementation. Many laboratory scale tests for aluminum and chromium dissolution have been run on Hanford wastes, with samples from 46 tanks tested. Three samples from SRS tanks have been tested, out of seven tanks containing high aluminum sludge. One full-scale aluminum dissolution was successfully performed on waste at SRS in 1982, but generated a very large quantity of liquid waste ({approx}3,000,000 gallons). No large-scale tests have been done on Hanford wastes. Although the data to date give a generally positive indication that aluminum dissolution will work, many issues remain, predominantly because of variable waste compositions and changes in process conditions, downstream processing, or storage limitations. Better approaches are needed to deal with the waste volumes and limitations on disposal methods. To develop a better approach requires a more extensive understanding of the kinetics of dissolution, as well as the factors that effect rates, effectiveness, and secondary species. Models of the dissolution rate that have been developed are useful, but suffer from limitations on applicable compositional ranges, mineral phases, and particle properties that are difficult to measure. The experimental

  19. Gas-tungsten arc welding of aluminum alloys

    DOE Patents [OSTI]

    Frye, L.D.

    1982-03-25

    The present invention is directed to a gas-tungsten arc welding method for joining together structures formed of aluminum alloy with these structures disposed contiguously to a heat-damagable substrate of a metal dissimilar to the aluminum alloy. The method of the present invention is practiced by diamond machining the fay surfaces of the aluminum alloy structures to profice a mirror finish thereon having a surface roughness in the order of about one microinch. The fay surface are aligned and heated sufficiently by the tungsten electrode to fuse the aluminum alloy continguous to the fay surfaces to effect the weld joint. The heat input used to provide an oxide-free weld is significantly less than that required if the fay surfaces were prepared by using conventional chemical and mechanical practices.

  20. Non-LTE Abundances of Magnesium, Aluminum and Sulfur in OB Stars Near the Solar Circle

    E-Print Network [OSTI]

    S. Daflon; K. Cunha; V. V. Smith; K. Butler

    2002-12-09

    Non-LTE abundances of magnesium, aluminum and sulfur are derived for a sample of 23 low-v \\sin i stars belonging to six northern OB associations of the Galactic disk within 1 kpc of the Sun. The abundances are obtained from the fitting of synthetic line profiles to high resolution spectra. A comparison of our results with HII region abundances indicates good agreement for sulfur while the cepheid abundances are higher. The derived abundances of Mg show good overlap with the cepheid results. The aluminum abundances for OB stars are significantly below the cepheid values. But, the OB star results show a dependence with effective temperature and need further investigation. The high Al abundances in the cepheids could be the result of mixing. A discussion of the oxygen abundance in objects near the solar circle suggests that the current mean galactic oxygen abundance in this region is 8.6-8.7 and in agreement with the recently revised oxygen abundance in the solar photosphere. Meaningful comparisons of the absolute S, Al and Mg abundances in OB stars with the Sun must await a reinvestigation of these elements, as well as the meteoritic reference element Si, with 3D hydrodynamical model atmospheres for the Sun. No abundance gradients are found within the limited range in galactocentric distances in the present study. Such variations would be expected only if there were large metallicity gradients in the disk.

  1. Relaxation and critical strain for maximum In incorporation in AlInGaN on GaN grown by metal organic vapour phase epitaxy

    SciTech Connect (OSTI)

    Reuters, Benjamin; Finken, M.; Wille, A.; Kalisch, H.; Vescan, A.; Hollaender, B.; Heuken, M.

    2012-11-01

    Quaternary AlInGaN layers were grown on conventional GaN buffer layers on sapphire by metal organic vapour phase epitaxy at different surface temperatures and different reactor pressures with constant precursor flow conditions. A wide range in compositions within 30-62% Al, 5-29% In, and 23-53% Ga was covered, which leads to different strain states from high tensile to high compressive. From high-resolution x-ray diffraction and Rutherford backscattering spectrometry, we determined the compositions, strain states, and crystal quality of the AlInGaN layers. Atomic force microscopy measurements were performed to characterize the surface morphology. A critical strain value for maximum In incorporation near the AlInGaN/GaN interface is presented. For compressively strained layers, In incorporation is limited at the interface as residual strain cannot exceed an empirical critical value of about 1.1%. Relaxation occurs at about 15 nm thickness accompanied by strong In pulling. Tensile strained layers can be grown pseudomorphically up to 70 nm at a strain state of 0.96%. A model for relaxation in compressively strained AlInGaN with virtual discrete sub-layers, which illustrates the gradually changing lattice constant during stress reduction is presented.

  2. Ni/metal hydride secondary element

    DOE Patents [OSTI]

    Bauerlein, Peter

    2005-04-19

    A Ni/metal hydride secondary element having a positive nickel hydroxide electrode, a negative electrode having a hydrogen storage alloy, and an alkaline electrolyte, the positive electrode, provided with a three-dimensional metallic conductive structure, also contains an aluminum compound which is soluble in the electrolyte, in addition to nickel hydroxide and cobalt oxide. The aluminum compound is aluminum hydroxide and/or aluminum oxide, and the mass of the aluminum compound which is present in the positive bulk material mixture is 0.1 to 2% by weight relative to the mass of the nickel hydroxide which is present. In combination with aluminum hydroxide or aluminum oxide, the positive electrode further contains lanthanoid oxidic compounds Y.sub.2 O.sub.3, La.sub.2 O.sub.3 and Ca(OH).sub.2, as well as mixtures of these compounds.

  3. Wetting of Sodium on ??-Al2O3/YSZ Composites for Low Temperature Planar Sodium-Metal Halide Batteries

    SciTech Connect (OSTI)

    Reed, David M.; Coffey, Greg W.; Mast, Eric S.; Canfield, Nathan L.; Mansurov, Jirgal; Lu, Xiaochuan; Sprenkle, Vincent L.

    2013-04-01

    Wetting of Na on B”-Al2O3/YSZ composites was investigated using the sessile drop technique. The effects of moisture and surface preparation were studied at low temperatures. Electrical conductivity of Na/B”-Al2O3-YSZ/Na cells was also investigated at low temperatures and correlated to the wetting behavior. The use of planar B”-Al2O3 substrates at low temperature with low cost polymeric seals is realized due to improved wetting at low temperature and conductivity values consistent with the literature.

  4. Screening Methods to Develop Alfalfa Germplasms Tolerant of Acid, Aluminum Toxic Soils

    E-Print Network [OSTI]

    Parrott, Wayne

    Screening Methods to Develop Alfalfa Germplasms Tolerant of Acid, Aluminum Toxic Soils M. Dall'Agnol, J. H. Bouton,* and W. A. Parrott ABSTRACT Soil acidity and aluminum (Al)toxicity are major problems different screening methods for selection of acid soil tolerant alfalfa germplasms in the greenhouse during

  5. Chemical Preparation of Aluminum Borate Whiskers I. Erkin GNENLI and A. Cneyt TAS

    E-Print Network [OSTI]

    Tas, A. Cuneyt

    of Metallurgical and Materials Engineering, Middle East Technical University, Ankara 06531, Turkey Aluminum borate Aluminum sulphate (Al2(SO4)3.18H2O, 99.9%, Riedel de-Haen, Seelze, Germany), boric acid (H3BO3: 99.9%, Riedel de-Haen, Germany) and potassium sulphate (K2SO4: 99.9%, Merck, Darmstadt, Germany) were accurately

  6. A scanning Kelvin probe analysis of aluminum and aluminum alloys

    SciTech Connect (OSTI)

    Hansen, D.C.; Grecsek, G.E.; Roberts, R.O.

    1999-07-01

    A scanning Kelvin probe was used to determine a correlation between work function measurements in air and corrosion potential measurements in solution of pure metals. Test panels of AA2024-T3 treated with various surface preparations and primer/coatings were also analyzed using this technique. Filiform corrosion was observed on a scribed panel that had been exposed to a humid environment, whereas on a non-scribed and non-exposed test panel, holidays in the coating were observed and clearly defined. Work function (wf) analysis yielded more noble values for areas within the scribe mark and more active values were observed for areas adjacent to the scribe mark where delamination of the coating and filiform corrosion was observed. The tips of corrosion filaments were found to be anodic in relation to the body of the filament, with areas of activity extending away from the filaments themselves. Measurements made on an aircraft access panel resulted in the detection of a potential gradient within the repair area. These results indicate that the scanning Kelvin probe is a useful non-destructive technique for the detection of delamination and disbanding of coatings, coating anomalies and corrosion susceptibility of coatings on aluminum aircraft alloys.

  7. Spray-formed tooling and aluminum strip

    SciTech Connect (OSTI)

    McHugh, K.M.

    1995-11-01

    Spray forming is an advanced materials processing technology that converts a bulk liquid metal to a near-net-shape solid by depositing atomized droplets onto a suitably shaped substrate. By combining rapid solidification processing with product shape control, spray forming can reduce manufacturing costs while improving product quality. De Laval nozzles offer an alternative method to the more conventional spray nozzle designs. Two applications are described: high-volume production of aluminum alloy strip, and the production of specialized tooling, such as injection molds and dies, for rapid prototyping.

  8. Laser welding of annealed Zr55Cu30Ni5Al10 bulk metallic glass B. Chen a,b

    E-Print Network [OSTI]

    Li, Mo

    welded specimen plates with no obvious welding defects in the joints and high welding speed may lead, it becomes increasingly difficult to form complex structures because of the high flow stress in the mold shaping of BMG parts with complex shapes and geometry. In addition, it is difficult to produce metal molds

  9. DETERMINATION OF IN-VITRO LUNG SOLUBILITY AND INTAKE-TO-DOSE CONVERSION FACTOR FOR TRITIATED LANTHANUM NICKEL ALUMINUM ALLOY

    SciTech Connect (OSTI)

    Farfan, E.; Labone, T.; Staack, G.; Cheng, Y.; Zhou, Y.; Varallo, T.

    2011-11-11

    A sample of tritiated lanthanum nickel aluminum alloy (LaNi4.25Al0.75 or LANA.75) similar to that used at the Savannah River Site Tritium Facilities was analyzed to estimate the particle size distribution of this metal tritide powder and the rate, at which this material dissolves in the human respiratory tract after it is inhaled. This information is used to calculate the committed effective dose received by a worker after inhaling the material. These doses, which were calculated using the same methodology given in the DOE Tritium Handbook, are presented as inhalation intake-to-dose conversion factors (DCF). The DCF for this metal tritide is less than the DCF for tritiated water and radiation worker bioassay programs designed for tritiated water are adequate to monitor for intakes of this material.

  10. Hydrogen storage in sodium aluminum hydride.

    SciTech Connect (OSTI)

    Ozolins, Vidvuds; Herberg, J.L.; McCarty, Kevin F.; Maxwell, Robert S.; Stumpf, Roland Rudolph; Majzoub, Eric H.

    2005-11-01

    Sodium aluminum hydride, NaAlH{sub 4}, has been studied for use as a hydrogen storage material. The effect of Ti, as a few mol. % dopant in the system to increase kinetics of hydrogen sorption, is studied with respect to changes in lattice structure of the crystal. No Ti substitution is found in the crystal lattice. Electronic structure calculations indicate that the NaAlH{sub 4} and Na{sub 3}AlH{sub 6} structures are complex-ionic hydrides with Na{sup +} cations and AlH{sub 4}{sup -} and AlH{sub 6}{sup 3-} anions, respectively. Compound formation studies indicate the primary Ti-compound formed when doping the material at 33 at. % is TiAl{sub 3} , and likely Ti-Al compounds at lower doping rates. A general study of sorption kinetics of NaAlH{sub 4}, when doped with a variety of Ti-halide compounds, indicates a uniform response with the kinetics similar for all dopants. NMR multiple quantum studies of solution-doped samples indicate solvent interaction with the doped alanate. Raman spectroscopy was used to study the lattice dynamics of NaAlH{sub 4}, and illustrated the molecular ionic nature of the lattice as a separation of vibrational modes between the AlH{sub 4}{sup -} anion-modes and lattice-modes. In-situ Raman measurements indicate a stable AlH{sub 4}{sup -} anion that is stable at the melting temperature of NaAlH{sub 4}, indicating that Ti-dopants must affect the Al-H bond strength.

  11. Aluminum processing energy benchmark report

    SciTech Connect (OSTI)

    None, None

    2007-02-01

    Substantial energy efficiency gains have been made in the aluminum industry over the past forty years, resulting in a 58 percent decrease in energy utilization.

  12. Directly correlated transmission electron microscopy and atom probe tomography of grain boundary oxidation in a Ni-Al binary alloy exposed to high-temperature water.

    SciTech Connect (OSTI)

    Schreiber, Daniel K.; Olszta, Matthew J.; Bruemmer, Stephen M.

    2013-10-30

    Intergranular oxidation of a Ni-4Al alloy exposed to hydrogenated, high-temperature water was characterized using directly correlated transmission electron microscopy and atom probe tomography. These combined analyses revealed that discrete, well-separated oxides (NiAl2O4) precipitated along grain boundaries in the metal. Aluminum was depleted from the grain boundary between oxides and also from one side of the boundary as a result of grain boundary migration. The discrete oxide morphology, disconnected from the continuous surface oxidation, suggests intergranular solid-state internal oxidation of Al. Keywords: oxidation; grain boundaries; nickel alloys; atom probe tomography; transmission electron microscopy (TEM)

  13. Half-Metallicity and Efficient Spin Injection in AlN=GaN:Cr (0001) Heterostructure J. E. Medvedeva,1

    E-Print Network [OSTI]

    Medvedeva, Julia E.

    V, so that the conduction electrons can tunnel into the semiconductor material with 100% spin, Australia 3 Chemical and Materials Engineering Department, Arizona State University, Tempe, Arizona 85287 of the structural, electronic, and magnetic properties of Cr-doped AlN=GaN (0001) heterostructures reveal

  14. Angular-dependent interatomic potential for the aluminum-hydrogen system F. Apostol* and Y. Mishin

    E-Print Network [OSTI]

    Mishin, Yuri

    , an aluminum oxide layer protects the underlying Al alloy from the environment. But in the presence of me- chanical stresses, the oxide layer can develop microscopic cracks exposing the alloy surface. Water

  15. Production of aluminum-26

    DOE Patents [OSTI]

    Steinkruger, Fred J. (Los Alamos, NM); Phillips, Dennis R. (Los Alamos, NM)

    1991-01-01

    A method of producing Al-26 from potassium chloride by exposing it to a proton beam in order to break potassium and chlorine atoms into smaller pieces, which include Al-26. The Al-26 is isolated from the potassium chloride and other substances produced by the beam by means of extraction and ion exchange.

  16. Synthesis of AlN/Al Polycrystals along with Al Nanoparticles Using Thermal Plasma Route

    SciTech Connect (OSTI)

    Kanhe, Nilesh S.; Nawale, A. B.; Kulkarni, N. V.; Bhoraskar, S. V.; Mathe, V. L.; Das, A. K.

    2011-07-15

    This paper for the first time reports the (200) oriented growth of hexagonal Aluminum nitride crystals during synthesis of aluminum nanoparticles in dc transferred arc thermal plasma reactor by gas phase condensation in nitrogen plasma. The structural and morphological study of as synthesized AlN crystal and aluminium nanoparticles was done by using the x-ray diffraction method, scanning electron microscopy and transmission electron microscopy.

  17. Reactions of aluminum with uranium fluorides and oxyfluorides

    SciTech Connect (OSTI)

    Leitnaker, J.M.; Nichols, R.W.; Lankford, B.S. [Martin Marietta Energy Systems, Inc., Oak Ridge, TN (United States)

    1991-12-31

    Every 30 to 40 million operating hours a destructive reaction is observed in one of the {approximately}4000 large compressors that move UF{sub 6} through the gaseous diffusion plants. Despite its infrequency, such a reaction can be costly in terms of equipment and time. Laboratory experiments reveal that the presence of moderate pressures of UF{sub 6} actually cools heated aluminum, although thermodynamic calculations indicate the potential for a 3000-4000{degrees}C temperature rise. Within a narrow and rather low (<100 torr; 1 torr = 133.322 Pa) pressure range, however, the aluminum is seen to react with sufficient heat release to soften an alumina boat. Three things must occur in order for aluminum to react vigorously with either UF{sub 6} or UO{sub 2}F{sub 2}. 1. An initiating source of heat must be provided. In the compressors, this source can be friction, permitted by disruption of the balance of the large rotating part or by creep of the aluminum during a high-temperature treatment. In the absence of this heat source, compressors have operated for 40 years in UF{sub 6} without significant reaction. 2. The film protecting the aluminum must be breached. Melting (of UF{sub 5} at 620 K or aluminum at 930 K) can cause such a breach in laboratory experiments. In contrast, holding Al samples in UF{sub 6} at 870 K for several hours produces only moderate reaction. Rubbing in the cascade can undoubtedly breach the protective film. 3. Reaction products must not build up and smother the reaction. While uranium products tend to dissolve or dissipate in molten aluminum, AIF{sub 3} shows a remarkable tendency to surround and hence protect even molten aluminum. Hence the initial temperature rise must be rapid and sufficient to move reactants into a temperature region in which products are removed from the reaction site.

  18. LIFE CYCLE INVENTORY ANALYSIS IN THE PRODUCTION OF METALS USED IN PHOTOVOLTAICS.

    SciTech Connect (OSTI)

    FTHENAKIS,V.M.; KIM, H.C.; WANG, W.

    2007-03-30

    Material flows and emissions in all the stages of production of zinc, copper, aluminum, cadmium, indium, germanium, gallium, selenium, tellurium, and molybdenum were investigated. These metals are used selectively in the manufacture of solar cells, and emission and energy factors in their production are used in the Life Cycle Analysis (LCA) of photovoltaics. Significant changes have occurred in the production and associated emissions for these metals over the last 10 years, which are not described in the LCA databases. Furthermore, emission and energy factors for several of the by-products of the base metal production were lacking. This report aims in updating the life-cycle inventories associated with the production of the base metals (Zn, Cu, Al, Mo) and in defining the emission and energy allocations for the minor metals (Cd, In, Ge, Se, Te and Ga) used in photovoltaics.

  19. Ultrahigh-Efficiency Aluminum Production Cells

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ultrahigh-Efficiency Aluminum Production Cells Saving Energy and Reducing Carbon Emissions with Cell Redesign and Novel Electrolytes This project will develop a multipolar aluminum...

  20. Aluminum-Alkaline Metal-Metal Composite Conductor - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O O D S TAPropane Texas LawCasefor SolarAlumina

  1. Aluminum-Alkaline Metal-Metal Composite Conductor - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O O D S TAPropane Texas LawCasefor SolarAluminaPortal

  2. Thermochemistry of Aluminum Species for Combustion Modeling from Ab Initio Molecular Orbital Calculations

    E-Print Network [OSTI]

    Swihart, Mark T.

    to be present during combustion of aluminum particles. The computed enthalpies of formation at 298.15 K agree thermochemical data are also presented for several species never studied experimentally, including AlH2, AlH3, Al methods observed in other systems, the calculated enthalpies of formation would be expected to be accurate

  3. Carbonaceous cathode with enhanced wettability for aluminum production

    DOE Patents [OSTI]

    Keller, Rudolf; Gatty, David G.; Barca, Brian J.

    2003-09-09

    A method of preparing carbonaceous blocks or bodies for use in a cathode in an electrolytic cell for producing aluminum wherein the cell contains an electrolyte and has molten aluminum contacting the cathode, the cathode having improved wettability with molten aluminum. The method comprises the steps of providing a carbonaceous block and a boron oxide containing melt. The carbonaceous block is immersed in the melt and pressure is applied to the melt to impregnate the melt into pores in the block. Thereafter, the carbonaceous block is withdrawn from the melt, the block having boron oxide containing melt intruded into pores therein, the boron oxide capable of reacting with a source of titanium or zirconium or like metal to form titanium or zirconium diboride during heatup or operation of said cell.

  4. SILICON SURFACE PASSIVATION BY ULTRATHIN Al2O3 FILMS AND Al2O3/SiNx STACKS

    E-Print Network [OSTI]

    by thermal as well as by plasma-assisted atomic layer deposition (ALD) are very well suited for the effec, aluminum oxide (Al2O3) grown by atomic layer deposition (ALD) has been identified as a di- electric Ohrberg 1, 31860 Emmerthal, Germany ABSTRACT We show that aluminum oxide (Al2O3) layers depo- sited

  5. Spray Rolling Aluminum Strip

    SciTech Connect (OSTI)

    Lavernia, E.J.; Delplanque, J-P; McHugh, K.M.

    2006-05-10

    Spray forming is a competitive low-cost alternative to ingot metallurgy for manufacturing ferrous and non-ferrous alloy shapes. It produces materials with a reduced number of processing steps, while maintaining materials properties, with the possibility of near-net-shape manufacturing. However, there are several hurdles to large-scale commercial adoption of spray forming: 1) ensuring strip is consistently flat, 2) eliminating porosity, particularly at the deposit/substrate interface, and 3) improving material yield. Through this program, a new strip/sheet casting process, termed spray rolling, has been developed, which is an innovative manufacturing technique to produce aluminum net-shape products. Spray rolling combines the benefits of twin-roll casting and conventional spray forming, showing a promising potential to overcome the above hurdles associated with spray forming. Spray rolling requires less energy and generates less scrap than conventional processes and, consequently, enables the development of materials with lower environmental impacts in both processing and final products. Spray Rolling was developed as a collaborative project between the University of California-Davis, the Colorado School of Mines, the Idaho National Engineering and Environmental Laboratory, and an industry team. The following objectives of this project were achieved: (1) Demonstration of the feasibility of the spray rolling process at the bench-scale level and evaluation of the materials properties of spray rolled aluminum strip alloys; and (2) Demonstration of 2X scalability of the process and documentation of technical hurdles to further scale up and initiate technology transfer to industry for eventual commercialization of the process.

  6. Aluminum reduction cell electrode

    DOE Patents [OSTI]

    Goodnow, W.H.; Payne, J.R.

    1982-09-14

    The invention is directed to cathode modules comprised of refractory hard metal materials, such as TiB[sub 2], for an electrolytic cell for the reduction of alumina wherein the modules may be installed and replaced during operation of the cell and wherein the structure of the cathode modules is such that the refractory hard metal materials are not subjected to externally applied forces or rigid constraints. 9 figs.

  7. Chemical Hydrogen Storage Using Polyhedral Borane Anions and Aluminum-Ammonia-Borane Complexes

    SciTech Connect (OSTI)

    Hawthorne, M. Frederick; Jalisatgi, Satish S.; Safronov, Alexander V.; Lee, Han Beak; Wu, Jianguo

    2010-10-01

    Phase 1. Hydrolysis of borohydride compounds offer the potential for significant hydrogen storage capacity, but most work to date has focused on one particular anion, BH4-, which requires high pH for stability. Other borohydride compounds, in particular polyhedral borane anions offer comparable hydrogen storage capacity without requiring high pH media and their long term thermal and hydrolytic stability coupled with non-toxic nature make them a very attractive alternative to NaBH4. The University of Missouri project provided the overall program focal point for the investigation of catalytic hydrolysis of polyhedral borane anions for hydrogen release. Due to their inherent stability, a transition metal catalyst was necessary for the hydrolysis of polyhedral borane anions. Transition metal ions such as cobalt, nickel, palladium and rhodium were investigated for their catalytic activity in the hydrolysis of nido-KB11H14, closo-K2B10H10, and closo-K2B12H12. The rate of hydrolysis follows first-order kinetics with respect to the concentration of the polyhedral borane anion and surface area of the rhodium catalyst. The rate of hydrolysis depends upon a) choice of polyhedral borane anion, c) concentration of polyhedral borane anion, d) surface area of the rhodium catalyst and e) temperature of the reaction. In all cases the yield of hydrogen was 100% which corresponds to ~7 wt% of hydrogen (based on material wt%). Phase 2. The phase 2 of program at the University of Missouri was focused upon developing aluminum ammonia-boranes (Al-AB) as chemical hydrogen storage materials, specifically their synthesis and studies of their dehydrogenation. The ammonia borane molecule (AB) is a demonstrated source of chemically stored hydrogen (19.6 wt%) which meets DOE performance parameters except for its regeneration from spent AB and elemental hydrogen. The presence of an aluminum center bonded to multiple AB residues might combine the efficiency of AB dehydrogenation with an aluminum mediated hydrogenation process leading to reversibility. The Al-AB complexes have comparable hydrogen capacity with other M-AB and have potential to meet DOE’s 2010 and 2015 targets for system wt%.

  8. In situ growth of ZrO{sub 2}–Al{sub 2}O{sub 3} nano-crystalline ceramic coatings via micro arc oxidation of aluminum substrates

    SciTech Connect (OSTI)

    Shoaei-Rad, V.; Bayati, M.R.; Zargar, H.R.; Javadpour, J.; Golestani-Fard, F.; Center of Excellence for Advanced Materials, Iran University of Science and Technology, P.O. Box 16845-195, Tehran

    2012-06-15

    Highlights: ? ZrO{sub 2}–Al{sub 2}O{sub 3} layers were fabricated by MAO process. ? A formation mechanism was also proposed. ? Effect of voltage and electrolyte composition on layers properties was studied. -- Abstract: Micro arc oxidation technique was employed to grow zirconia–alumina porous layers. Considering XPS, XRD, and EDX results, the layers mainly consisted of ?-Al{sub 2}O{sub 3}, ?-Al{sub 2}O{sub 3}, monoclinic ZrO{sub 2}, tetragonal ZrO{sub 2}. Fractions of these phases were observed to change based on the fabrication conditions. Zirconia phases formed not only on the surface, but also in the layers depth. Increasing the voltage as well as utilizing thicker electrolytes resulted in higher zirconium concentration. The average crystalline size of the ZrO{sub 2} and the Al{sub 2}O{sub 3} phases was determined as about 57 and 75 nm. AFM studies revealed that the surface roughness increased with voltage and electrolyte concentration. Morphological evaluations, performed by SEM, showed that the microstructure of the layers strongly depended on the synthesis conditions. The layers revealed a porous structure with a pores size of 40–300 nm. Microcracks were observed to appear when the electrolyte concentration and the applied voltage increased. Finally, a formation mechanism was put forward with emphasis on the chemical and the electrochemical foundations.

  9. TiN coated aluminum electrodes for DC high voltage electron guns

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mamun, Md Abdullah A.; Elmustafa, Abdelmageed A.; Taus, Rhys; Forman, Eric; Poelker, Matthew

    2015-05-01

    Preparing electrodes made of metals like stainless steel, for use inside DC high voltage electron guns, is a labor-intensive and time-consuming process. In this paper, the authors report the exceptional high voltage performance of aluminum electrodes coated with hard titanium nitride (TiN). The aluminum electrodes were comparatively easy to manufacture and required only hours of mechanical polishing using silicon carbide paper, prior to coating with TiN by a commercial vendor. The high voltage performance of three TiN-coated aluminum electrodes, before and after gas conditioning with helium, was compared to that of bare aluminum electrodes, and electrodes manufactured from titanium alloymore »(Ti-6AI-4V). Following gas conditioning, each TiN-coated aluminum electrode reached -225 kV bias voltage while generating less than 100 pA of field emission (« less

  10. Processing of Silver-Implanted Aluminum Nitride for Energy Harvesting Devices

    E-Print Network [OSTI]

    Alleyne, Fatima

    2013-01-01

    literature for Au, rare earth metals (Eu, Er, Tm), Fe, andimplanted AlN, 122 rare-earth (RE) metals (europium (Eu),

  11. Ionic Current Mapping Techniques and Applications to Aluminum-Copper Corrosion

    SciTech Connect (OSTI)

    Isaacs, H. S.; Jeffcoate, C. S.; Missert, N. A.; Barbour, J. C.

    1999-10-17

    Measurements have been made of the aluminum/metal galvanic couple. A wide range of geometries were investigated varying the areas of anodic and cathodic surfaces and employing specially designed galvanic cells with crevices. In situ ionic current density mapping was used to monitor galvanic corrosion and currents flowing between separated metals was measured.

  12. Salt-soda sinter process for recovering aluminum from fly ash

    DOE Patents [OSTI]

    McDowell, William J. (Oak Ridge, TN); Seeley, Forest G. (Oak Ridge, TN)

    1981-01-01

    A method for recovering aluminum values from fly ash comprises sintering the fly ash with a mixture of NaCl and Na.sub.2 CO.sub.3 to a temperature in the range 700.degree.-900.degree. C. for a period of time sufficient to convert greater than 90% of the aluminum content of the fly ash into an acid-soluble fraction and then contacting the thus-treated fraction with an aqueous solution of nitric or sulfuric acid to effect dissolution of aluminum and other metal values in said solution.

  13. A combined capacitance-voltage and hard x-ray photoelectron spectroscopy characterisation of metal/Al{sub 2}O{sub 3}/In{sub 0.53}Ga{sub 0.47}As capacitor structures

    SciTech Connect (OSTI)

    Lin, Jun; Povey, Ian M.; Hurley, Paul K.; Walsh, Lee; Hughes, Greg; Woicik, Joseph C.; O'Regan, Terrance P.

    2014-07-14

    Capacitance-Voltage (C-V) characterization and hard x-ray photoelectron spectroscopy (HAXPES) measurements have been used to study metal/Al{sub 2}O{sub 3}/In{sub 0.53}Ga{sub 0.47}As capacitor structures with high (Ni) and low (Al) work function metals. The HAXPES measurements observe a band bending occurring prior to metal deposition, which is attributed to a combination of fixed oxide charges and interface states of donor-type. Following metal deposition, the Fermi level positions at the Al{sub 2}O{sub 3}/In{sub 0.53}Ga{sub 0.47}As interface move towards the expected direction as observed from HAXPES measurements. The In{sub 0.53}Ga{sub 0.47}As surface Fermi level positions determined from both the C-V analysis at zero gate bias and HAXPES measurements are in reasonable agreement. The results are consistent with the presence of electrically active interface states at the Al{sub 2}O{sub 3}/In{sub 0.53}Ga{sub 0.47}As interface and suggest an interface state density increasing towards the In{sub 0.53}Ga{sub 0.47}As valence band edge.

  14. PHYTOEXTRACTION OF HEAVY METALS

    E-Print Network [OSTI]

    Blouin-Demers, Gabriel

    Plants Chelating agents Pb hyperaccumulation Effects of pH on metal extraction Disposal options contaminants from soils Contaminants must be in harvestable portions of the plant (Wongkongkatep et al. 2003) Chelating Agents: desorb heavy metals from soil matrix and form water-soluble metal complexes (Shen et al

  15. Aluminum reduction cell electrode

    DOE Patents [OSTI]

    Payne, J.R.

    1983-09-20

    The invention is directed to an anode-cathode structure for an electrolytic cell for the reduction of alumina wherein the structure is comprised of a carbon anode assembly which straddles a wedge-shaped refractory hard metal cathode assembly having steeply sloped cathodic surfaces, each cathodic surface being paired in essentially parallel planar relationship with an anode surface. The anode-cathode structure not only takes into account the structural weakness of refractory hard metal materials but also permits the changing of the RHM assembly during operation of the cell. Further, the anode-cathode structure enhances the removal of anode gas from the interpolar gap between the anode and cathode surfaces. 10 figs.

  16. Coated Metal Articles and Method of Making

    DOE Patents [OSTI]

    Boller, Ernest R.; Eubank, Lowell D.

    2004-07-06

    The method of protectively coating metallic uranium which comprises dipping the metallic uranium in a molten alloy comprising about 20-75% of copper and about 80-25% of tin, dipping the coated uranium promptly into molten tin, withdrawing it from the molten tin and removing excess molten metal, thereupon dipping it into a molten metal bath comprising aluminum until it is coated with this metal, then promptly withdrawing it from the bath.

  17. Coated metal articles and method of making

    DOE Patents [OSTI]

    Boller, Ernest R. (Van Buren Township, IN); Eubank, Lowell D. (Wilmington, DE)

    2004-07-06

    The method of protectively coating metallic uranium which comprises dipping the metallic uranium in a molten alloy comprising about 20-75% of copper and about 80-25% of tin, dipping the coated uranium promptly into molten tin, withdrawing it from the molten tin and removing excess molten metal, thereupon dipping it into a molten metal bath comprising aluminum until it is coated with this metal, then promptly withdrawing it from the bath.

  18. Quinary metallic glass alloys

    DOE Patents [OSTI]

    Lin, X.; Johnson, W.L.

    1998-04-07

    At least quinary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10{sup 3}K/s. Such alloys comprise zirconium and/or hafnium in the range of 45 to 65 atomic percent, titanium and/or niobium in the range of 4 to 7.5 atomic percent, and aluminum and/or zinc in the range of 5 to 15 atomic percent. The balance of the alloy compositions comprise copper, iron, and cobalt and/or nickel. The composition is constrained such that the atomic percentage of iron is less than 10 percent. Further, the ratio of copper to nickel and/or cobalt is in the range of from 1:2 to 2:1. The alloy composition formula is: (Zr,Hf){sub a}(Al,Zn){sub b}(Ti,Nb){sub c}(Cu{sub x}Fe{sub y}(Ni,Co){sub z}){sub d} wherein the constraints upon the formula are: a ranges from 45 to 65 atomic percent, b ranges from 5 to 15 atomic percent, c ranges from 4 to 7.5 atomic percent, d comprises the balance, d{hor_ellipsis}y is less than 10 atomic percent, and x/z ranges from 0.5 to 2.

  19. Quinary metallic glass alloys

    DOE Patents [OSTI]

    Lin, Xianghong (Pasadena, CA); Johnson, William L. (Pasadena, CA)

    1998-01-01

    At least quinary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10.sup.3 K/s. Such alloys comprise zirconium and/or hafnium in the range of 45 to 65 atomic percent, titanium and/or niobium in the range of 4 to 7.5 atomic percent, and aluminum and/or zinc in the range of 5 to 15 atomic percent. The balance of the alloy compositions comprise copper, iron, and cobalt and/or nickel. The composition is constrained such that the atomic percentage of iron is less than 10 percent. Further, the ratio of copper to nickel and/or cobalt is in the range of from 1:2 to 2:1. The alloy composition formula is: (Zr,Hf).sub.a (Al,Zn).sub.b (Ti,Nb).sub.c (Cu.sub.x Fe.sub.y (Ni,Co).sub.z).sub.d wherein the constraints upon the formula are: a ranges from 45 to 65 atomic percent, b ranges from 5 to 15 atomic percent, c ranges from 4 to 7.5 atomic percent, d comprises the balance, d.multidot.y is less than 10 atomic percent, and x/z ranges from 0.5 to 2.

  20. Responses of soil microbial and nematode communities to aluminum toxicity in vegetated oil-shale-waste lands

    E-Print Network [OSTI]

    Neher, Deborah A.

    Responses of soil microbial and nematode communities to aluminum toxicity in vegetated oil-shale and total Al concentrations showed a significant decrease after planting S. cumini plantation onto the shale

  1. ON THE PURPORTED FISCHER-TROPSCH ALKYLATION OF BENZENE: THE REACTION OF BENZENE WITH ALUMINUM TRICHLORIDE REVISITED

    E-Print Network [OSTI]

    Benner, Linda S.

    2014-01-01

    of AlC1 3 in boiling benzene. (8) M. Siskin and J. Porcelli,ON THE PURPORTED FISCHER-TROPSCH ALKYLATION OF BENZENE: THEREACTION OF BENZENE WITH ALUMINUM TRICHLORIDE REVISITED

  2. PRECIPITATION HARDENING IN ALUMINUM ALLOY 6022 W.F. Miao and D.E. Laughlin

    E-Print Network [OSTI]

    Laughlin, David E.

    PRECIPITATION HARDENING IN ALUMINUM ALLOY 6022 W.F. Miao and D.E. Laughlin Department of Materials on a precipitation hardening process. The precipitation sequence in the Al-Mg-Si alloys is generally accepted [1-shaped precipitates (circular cross sections) along 100 Al, having a hexagonal crystal structure with a 0.705 nm and c

  3. Metal-ceramic joint assembly

    DOE Patents [OSTI]

    Li, Jian (New Milford, CT)

    2002-01-01

    A metal-ceramic joint assembly in which a brazing alloy is situated between metallic and ceramic members. The metallic member is either an aluminum-containing stainless steel, a high chromium-content ferritic stainless steel or an iron nickel alloy with a corrosion protection coating. The brazing alloy, in turn, is either an Au-based or Ni-based alloy with a brazing temperature in the range of 9500 to 1200.degree. C.

  4. Titanium Matrix Composite Tooling Material for Aluminum Die Castings

    Broader source: Energy.gov [DOE]

    In aluminum die-casting, molten aluminum is forced under high pressure into a die cavity. First a "shot" of molten aluminum is ladled into a shot sleeve and the shot of molten aluminum is forced by...

  5. Electrolytic Cell For Production Of Aluminum From Alumina

    DOE Patents [OSTI]

    Bradford, Donald R (Underwood, WA); Barnett, Robert J. (Goldendale, WA); Mezner, Michael B. (Sandy, OR)

    2004-11-02

    An electrolytic cell for producing aluminum from alumina having a reservoir for collecting molten aluminum remote from the electrolysis.

  6. Micro Joining of Aluminum Graphite Composites 

    E-Print Network [OSTI]

    Velamati, Manasa

    2012-07-16

    Advanced aluminum graphite composites have unique thermal properties due to opposing coefficients of thermal expansion of aluminum and graphite. The thermal and mechanical properties of such composites are anisotropic due ...

  7. Current technologies and trends of aluminum design

    E-Print Network [OSTI]

    Chen, Michael, 1981-

    2004-01-01

    A literature review of current aluminum technology in the building and construction industry was carried out. Aluminum is an ideal material for building in corrosive environments and for building structures where small ...

  8. Aluminum-carbon composite electrode

    DOE Patents [OSTI]

    Farahmandi, C.J.; Dispennette, J.M.

    1998-07-07

    A high performance double layer capacitor having an electric double layer formed in the interface between activated carbon and an electrolyte is disclosed. The high performance double layer capacitor includes a pair of aluminum impregnated carbon composite electrodes having an evenly distributed and continuous path of aluminum impregnated within an activated carbon fiber preform saturated with a high performance electrolytic solution. The high performance double layer capacitor is capable of delivering at least 5 Wh/kg of useful energy at power ratings of at least 600 W/kg. 3 figs.

  9. Aluminum-carbon composite electrode

    DOE Patents [OSTI]

    Farahmandi, C. Joseph (Auburn, AL); Dispennette, John M. (Auburn, AL)

    1998-07-07

    A high performance double layer capacitor having an electric double layer formed in the interface between activated carbon and an electrolyte is disclosed. The high performance double layer capacitor includes a pair of aluminum impregnated carbon composite electrodes having an evenly distributed and continuous path of aluminum impregnated within an activated carbon fiber preform saturated with a high performance electrolytic solution. The high performance double layer capacitor is capable of delivering at least 5 Wh/kg of useful energy at power ratings of at least 600 W/kg.

  10. UNCORRECTEDPROOF Please cite this article in press as: M. Grujicic et al., Selection of the spraying technologies for over-coating of metal-stampings

    E-Print Network [OSTI]

    Grujicic, Mica

    of the spraying technologies for over-coating of metal-stampings with thermo-plastics for use in direct) xxx­xxx Selection of the spraying technologies for over-coating of metal-stampings with thermo The suitability of various polymer-powder spraying technologies for coating of metal-stampings used in polymer

  11. Improved Irradiation Performance of Uranium-Molybdenum/Aluminum Dispersion Fuel by Silicon Addition in Aluminum

    SciTech Connect (OSTI)

    Yeon Soo Kim; G. L. Hofman; A. B. Robinson; D. M. Wachs

    2013-10-01

    Uranium-molybdenum fuel particle dispersion in aluminum is a form of fuel under development for conversion of high-power research and test reactors from highly enriched to low-enriched uranium in the U.S. Global Threat Reduction Initiative program (also known as the Reduced Enrichment for Research and Test Reactors program). Extensive irradiation tests have been conducted to find a solution for problems caused by interaction layer growth and pore formation between U-Mo and Al. Adding a small amount of Si (up to [approximately]5 wt%) in the Al matrix was one of the proposed remedies. The effect of silicon addition in the Al matrix was examined using irradiation test results by comparing side-by-side samples with different Si additions. Interaction layer growth was progressively reduced with increasing Si addition to the matrix Al, up to 4.8 wt%. The Si addition also appeared to delay pore formation and growth between the U-Mo and Al.

  12. Large magnetic entropy change and adiabatic temperature rise of a Gd{sub 55}Al{sub 20}Co{sub 20}Ni{sub 5} bulk metallic glass

    SciTech Connect (OSTI)

    Xia, L., E-mail: xialei@shu.edu.cn [Key Laboratory for Microstructure and Institute of Materials, Shanghai University, Shanghai 200072 (China); Department of Industrial and Systems Engineering, The Hong Kong Polytechnic University, Hung Hom (Hong Kong); Tang, M. B. [Shanghai Institute of Ceramics, Chinese Academy of Science, Shanghai 200050 (China); Chan, K. C. [Department of Industrial and Systems Engineering, The Hong Kong Polytechnic University, Hung Hom (Hong Kong); Dong, Y. D. [Key Laboratory for Microstructure and Institute of Materials, Shanghai University, Shanghai 200072 (China)

    2014-06-14

    Gd{sub 55}Al{sub 20}Co{sub 20}Ni{sub 5} bulk metallic glass (BMG) was synthesized by minor Ni substitution for Co in the Gd{sub 55}Al{sub 20}Co{sub 25} BMG in which excellent glass forming ability (GFA) and magneto-caloric effect were reported previously. The Gd{sub 55}Al{sub 20}Ni{sub 20}Co{sub 5} amorphous rod has a similar GFA to the Gd{sub 55}Al{sub 20}Co{sub 25} BMG but exhibits better magnetic properties. The peak value of magnetic entropy change (??S{sub m}{sup peak}) of the Gd{sub 55}Al{sub 20}Co{sub 20}Ni{sub 5} BMG is 9.8 Jkg{sup ?1} K{sup ?1}. The field dependence of ??S{sub m}{sup peak} follows a ??S{sub m}{sup peak}?H{sup 0.85} relationship. The adiabatic temperature rise of the rod is 4.74?K under 5 T and is larger than of other BMGs previously reported. The improved magnetic properties were supposed to be induced by the enhanced interaction between 4f electron in the rare-earth and 3d electron in the transition metal elements by means of a minor Ni substitution for Co.

  13. Metal pad instabilities in liquid metal batteries

    E-Print Network [OSTI]

    Zikanov, Oleg

    2015-01-01

    A mechanical analogy is used to analyze the interaction between the magnetic field, electric current and deformation of interfaces in liquid metal batteries. It is found that, during charging or discharging, a sufficiently large battery is prone to instabilities of two types. One is similar to the metal pad instability known for aluminum reduction cells. Another type is new. It is related to the destabilizing effect of the Lorentz force formed by the azimuthal magnetic field induced by the base current and the current perturbations caused by the local variations of the thickness of the electrolyte layer.

  14. An investigation of aluminum titanate-spinel composites behavior in radiation

    SciTech Connect (OSTI)

    Cevikbas, G.; Tugrul, A. B.; Boyraz, T.; Buyuk, B.; Onen, U.

    2015-03-30

    In the present work, the radiation attenuation properties of Aluminum titanate (Al{sub 2}TiO{sub 5})-Spinel (MgAl{sub 2}O{sub 4}) ceramics composites were investigated. Al{sub 2}TiO{sub 5}-MgAl{sub 2}O{sub 4} ceramics composites which have different Al{sub 2}TiO{sub 5} percentages (0%, 5% and 10%) were produced and performed against gamma sources. Cs-137 and Co-60 were used as gamma radiation sources. Transmission technique was used in the experiments. The linear and mass attenuation coefficients of the samples were carried out for gamma radiation sources. The experimental results were compared with the theoretical mass attenuation coefficients which were calculated by using XCOM computer code. Increasing Al{sub 2}TiO{sub 5} percentage in the Aluminum titanate/ Spinel ceramics composites causes the higher linear and mass attenuation coefficients of the composites against Cs-137 and Co-60 gamma radioisotopes. Therefore Also theoretical mass attenuation coefficients are compatible with the experimental results. In conclusion, increasing the Aluminum titanate ratio in the Al{sub 2}TiO{sub 5}-MgAl{sub 2}O{sub 4} ceramics composites increases the gamma shielding property of the Al{sub 2}TiO{sub 5}-MgAl{sub 2}O{sub 4} ceramics for nuclear shielding applications.

  15. HIGH ALUMINUM HLW GLASSES FOR HANFORDS WTP

    SciTech Connect (OSTI)

    KRUGER AA; JOSEPH I; BOWMAN BW; GAN H; KOT W; MATLACK KS; PEGG IL

    2009-08-19

    The world's largest radioactive waste vitrification facility is now under construction at the United State Department of Energy's (DOE's) Hanford site. The Hanford Tank Waste Treatment and Immobilization Plant (WTP) is designed to treat nearly 53 million gallons of mixed hazardous and radioactive waste now residing in 177 underground storage tanks. This multi-decade processing campaign will be one of the most complex ever undertaken because of the wide chemical and physical variability of the waste compositions generated during the cold war era that are stored at Hanford. The DOE Office of River Protection (ORP) has initiated a program to improve the long-term operating efficiency of the WTP vitrification plants with the objective of reducing the overall cost of tank waste treatment and disposal and shortening the duration of plant operations. Due to the size, complexity and duration of the WTP mission, the lifecycle operating and waste disposal costs are substantial. As a result, gains in High Level Waste (HLW) and Low Activity Waste (LAW) waste loadings, as well as increases in glass production rate, which can reduce mission duration and glass volumes for disposal, can yield substantial overall cost savings. EnergySolutions and its long-term research partner, the Vitreous State Laboratory (VSL) of the Catholic University of America, have been involved in a multi-year ORP program directed at optimizing various aspects of the HLW and LAW vitrification flow sheets. A number of Hanford HLW streams contain high concentrations of aluminum, which is challenging with respect to both waste loading and processing rate. Therefore, a key focus area of the ORP vitrification process optimization program at EnergySolutions and VSL has been development of HLW glass compositions that can accommodate high Al{sub 2}O{sub 3} concentrations while maintaining high processing rates in the Joule Heated Ceramic Melters (JHCMs) used for waste vitrification at the WTP. This paper, reviews the achievements of this program with emphasis on the recent enhancements in Al{sub 2}O{sub 3} loadings in HLW glass and its processing characteristics. Glass formulation development included crucible-scale preparation and characterization of glass samples to assess compliance with all melt processing and product quality requirements, followed by small-scale screening tests to estimate processing rates. These results were used to down-select formulations for subsequent engineering-scale melter testing. Finally, further testing was performed on the DM1200 vitrification system installed at VSL, which is a one-third scale (1.20 m{sup 2}) pilot melter for the WTP HLW melters and which is fitted with a fully prototypical off-gas treatment system. These tests employed glass formulations with high waste loadings and Al{sub 2}O{sub 3} contents of {approx}25 wt%, which represents a near-doubling of the present WTP baseline maximum Al{sub 2}O{sub 3} loading. In addition, these formulations were processed successfully at glass production rates that exceeded the present requirements for WTP HLW vitrification by up to 88%. The higher aluminum loading in the HLW glass has an added benefit in that the aluminum leaching requirements in pretreatment are reduced, thus allowing less sodium addition in pretreatment, which in turn reduces the amount of LAW glass to be produced at the WTP. The impact of the results from this ORP program in reducing the overall cost and schedule for the Hanford waste treatment mission will be discussed.

  16. Low-Cost Direct Bonded Aluminum (DBA) Substrates

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for mass production and that produces high adhesive strength of the ceramic-metal interfaces. Consider the fabrication and use of low-cost AlN as a potential (and...

  17. Amorphous Metallic Glass as New High Power and Energy Density Anodes For Lithium Ion Rechargeable Batteries

    E-Print Network [OSTI]

    Meng, Shirley Y.

    We have investigated the use of aluminum based amorphous metallic glass as the anode in lithium ion rechargeable batteries. Amorphous metallic glasses have no long-range ordered microstructure; the atoms are less closely ...

  18. Synthesis and structural characterization of Al{sub 4}SiC{sub 4}-homeotypic aluminum silicon oxycarbide, [Al{sub 4.4}Si{sub 0.6}][O{sub 1.0}C{sub 2.0}]C

    SciTech Connect (OSTI)

    Kaga, Motoaki; Iwata, Tomoyuki [Department of Environmental and Materials Engineering, Nagoya Institute of Technology, Nagoya 466-8555 (Japan); Nakano, Hiromi [Cooperative Research Facility Center, Toyohashi University of Technology, Toyohashi 441-8580 (Japan); Fukuda, Koichiro, E-mail: fukuda.koichiro@nitech.ac.j [Department of Environmental and Materials Engineering, Nagoya Institute of Technology, Nagoya 466-8555 (Japan)

    2010-03-15

    A new quaternary layered oxycarbide, [Al{sub 4.39(5)}Si{sub 0.61(5)}]{sub S}IGMA{sub 5}[O{sub 1.00(2)}C{sub 2.00(2)}]{sub S}IGMA{sub 3}C, has been synthesized and characterized by X-ray powder diffraction, transmission electron microscopy and energy dispersive X-ray spectroscopy (EDX). The title compound was found to be hexagonal with space group P6{sub 3}/mmc, Z=2, and unit-cell dimensions a=0.32783(1) nm, c=2.16674(7) nm and V=0.20167(1) nm{sup 3}. The atom ratios Al:Si were determined by EDX, and the initial structural model was derived by the direct methods. The final structural model showed the positional disordering of one of the three types of Al/Si sites. The maximum-entropy methods-based pattern fitting (MPF) method was used to confirm the validity of the split-atom model, in which conventional structure bias caused by assuming intensity partitioning was minimized. The reliability indices calculated from the MPF were R{sub wp}=3.73% (S=1.20), R{sub p}=2.94%, R{sub B}=1.04% and R{sub F}=0.81%. The crystal was an inversion twin. Each twin-related individual was isostructural with Al{sub 4}SiC{sub 4} (space group P6{sub 3}mc, Z=2). - Graphical abstract: A new oxycarbide discovered in the Al-Si-O-C system, Al{sub 4}SiC{sub 4}-homeotypic [Al{sub 4.4}Si{sub 0.6}][O{sub 1.0}C{sub 2.0}]C. The crystal is an inversion twin, and hence the structure is represented by a split-atom model. The three-dimensional electron density distributions are determined by the maximum-entropy methods-based pattern fitting, being consistent with the disordered structural model.

  19. Simulation of Particle Size Effect on Dynamic Properties and Fracture of PTFE-W-Al Composites

    E-Print Network [OSTI]

    E. B. Herbold; J. Cai; D. J. Benson; V. F. Nesterenko

    2007-08-09

    Recent investigations of the dynamic compressive strength of cold isostatically pressed composites of polytetrafluoroethylene (PTFE), tungsten (W) and aluminum (Al) powders show significant differences depending on the size of metallic particles. The addition of W increases the density and overall strength of the sample. To investigate relatively large deformations multi-material Eulerian and arbitrary Lagrangian-Eulerian methods, which have the ability to efficiently handle the formation of free surfaces, were used. The calculations indicate that the increased strength of the sample with fine metallic particles is due to the formation of force chains under dynamic loading. This phenomenon occurs even at larger porosity of the PTFE matrix in comparison with samples with larger particle size of W and higher density of the PTFE matrix.

  20. Electronic circuits having NiAl and Ni.sub.3 Al substrates

    DOE Patents [OSTI]

    Deevi, Seetharama C. (Midlothian, VA); Sikka, Vinod K. (Oak Ridge, TN)

    1999-01-01

    An electronic circuit component having improved mechanical properties and thermal conductivity comprises NiAl and/or Ni.sub.3 Al, upon which an alumina layer is formed prior to applying the conductive elements. Additional layers of copper-aluminum alloy or copper further improve mechanical strength and thermal conductivity.

  1. (Polyfluoroaryl) fluoroanions of aluminum, gallium, and indium of enhanced utility, uses thereof, and products based thereon

    DOE Patents [OSTI]

    Marks, Tobin J. (Evanston, IL); Chen, You-Xian (Midland, MI)

    2001-01-01

    The (polyfluoroaryl)fluoroanions of aluminum, gallium, and indium are novel weakly coordinating anions which are highly fluorinated. (Polyfluoroaryl)fluoroanions of one such type contain at least one ring substituent other than fluorine. These (polyfluoroaryl)fluoroanions of aluminum, gallium, and indium have greater solubility in organic solvents, or have a coordinative ability essentially equal to or less than that of the corresponding (polyfluoroaryl)fluoroanion of aluminum, gallium, or indium in which the substituent is replaced by fluorine. Another type of new (polyfluoroaryl)fluoroanion of aluminum, gallium, and indium have 1-3 perfluorinated fused ring groups and 2-0 perfluorophenyl groups. When used as a cocatalyst in the formation of novel catalytic complexes with d- or f-block metal compounds having at least one leaving group such as a methyl group, these anions, because of their weak coordination to the metal center, do not interfere in the ethylene polymerization process, while affecting the propylene process favorably, if highly isotactic polypropylene is desired. Thus, the (polyfluoroaryl)fluoroanions of aluminum, gallium, and indium of this invention are useful in various polymerization processes such as are described.

  2. (Polyfluoroaryl) fluoroanions of aluminum, gallium, and indium of enhanced utility, uses thereof, and products based thereon

    DOE Patents [OSTI]

    Marks, Tobin J. (Evanston, IL); Chen, You-Xian (Midland, MI)

    2002-01-01

    The (polyfluoroaryl)fluoroanions of aluminum, gallium, and indium are novel weakly coordinating anions which are highly fluorinated. (Polyfluoroaryl)fluoroanions of one such type contain at least one ring substituent other than fluorine. These (polyfluoroaryl)fluoroanions of aluminum, gallium, and indium have greater solubility in organic solvents, or have a coordinative ability essentially equal to or less than that of the corresponding (polyfluoroaryl)fluoroanion of aluminum, gallium, or indium in which the substituent is replaced by fluorine. Another type of new (polyfluoroaryl)fluoroanion of aluminum, gallium, and indium have 1-3 perfluorinated fused ring groups and 2-0 perfluorophenyl groups. When used as a cocatalyst in the formation of novel catalytic complexes with d- or f-block metal compounds having at least one leaving group such as a methyl group, these anions, because of their weak coordination to the metal center, do not interfere in the ethylene polymerization process, while affecting the propylene process favorably, if highly isotactic polypropylene is desired. Thus, the (polyfluoroaryl)fluoroanions of aluminum, gallium, and indium of this invention are useful in various polymerization processes such as are described.

  3. Creep of pure aluminum at cryogenic temperatures 

    E-Print Network [OSTI]

    McDonald, Lacy Clark

    1989-01-01

    are capable of producing stea. dy-state fields greater than 15 Tesla while conventional magnets are only capable of about 3 Tesla, . The second advantage is that superconducting magnets create very homogeneous fields. This is particularly important..., the resistivity of 99. 99% pure aluminum is lower than that of oxygen free high conductivity (OFHC) copper. 2. As magnetic field increases above about 6 Tesla, , copper continues to increase in resistivity whereas aluminum becomes saturated, i. e. , aluminum...

  4. Formation of metal oxides by cathodic arc deposition

    SciTech Connect (OSTI)

    Anders, S.; Anders, A.; Rubin, M.; Wang, Z.; Raoux, S.; Kong, F.; Brown, I.G.

    1995-03-01

    Metal oxide thin films are of interest for a number of applications. Cathodic arc deposition, an established, industrially applied technique for formation of nitrides (e.g. TiN), can also be used for metal oxide thin film formation. A cathodic arc plasma source with desired cathode material is operated in an oxygen atmosphere, and metal oxides of various stoichiometric composition can be formed on different substrates. We report here on a series of experiments on metal oxide formation by cathodic arc deposition for different applications. Black copper oxide has been deposited on ALS components to increase the radiative heat transfer between the parts. Various metal oxides such as tungsten oxide, niobium oxide, nickel oxide and vanadium oxide have been deposited on ITO glass to form electrochromic films for window applications. Tantalum oxide films are of interest for replacing polymer electrolytes. Optical waveguide structures can be formed by refractive index variation using oxide multilayers. We have synthesized multilayers of Al{sub 2}O{sub 3}/Y{sub 2}O{sub 3}/AI{sub 2}O{sub 3}/Si as possible basic structures for passive optoelectronic integrated circuits, and Al{sub 2-x}Er{sub x}O{sub 3} thin films with a variable Er concentration which is a potential component layer for the production of active optoelectronic integrated devices such as amplifiers or lasers at a wavelength of 1.53 {mu}m. Aluminum and chromium oxide films have been deposited on a number of substrates to impart improved corrosion resistance at high temperature. Titanium sub-oxides which are electrically conductive and corrosion resistant and stable in a number of aggressive environments have been deposited on various substrates. These sub-oxides are of great interest for use in electrochemical cells.

  5. Aluminum ion batteries: electrolytes and cathodes

    E-Print Network [OSTI]

    Reed, Luke

    2015-01-01

    Activators of Aluminum Electrochemistry in Organic Media. J.I. ; Neff, V. D. Electrochemistry of Polynuclear Transitionaluminum ion based electrochemistry. Closer investigation

  6. "Making Stuff Smarter" Shape-Memory Material: Metals &

    E-Print Network [OSTI]

    Tsymbal, Evgeny Y.

    ·glass ·cloth ·wood #12;Conductor ­ ·copper ·aluminum ·steel ·any metal insulator conductor Any material straight (1) As the alloy cools and enters the low temperature phase, called martensite, the cubic

  7. Structure of stagnated plasma in aluminum wire array Z pinches

    SciTech Connect (OSTI)

    Hall, G. N.; Pikuz, S. A.; Shelkovenko, T. A.; Bland, S. N.; Lebedev, S. V.; Ampleford, D. J.; Palmer, J. B. A.; Bott, S. C.; Rapley, J.; Chittenden, J. P.; Apruzese, J. P.

    2006-08-15

    Experiments with aluminum wire array Z pinches have been carried out on the mega-ampere generator for plasma implosion experiments (MAGPIE) at Imperial College London [I. H. Mitchell et al., Rev. Sci. Instrum. 67, 1533 (1996)]. It has been shown that in these arrays, there are two intense sources of radiation during stagnation; Al XII line emission from a precursor-sized object, and both continuum and Al XIII radiation from bright spots of either significantly higher temperature or density randomly distributed around this object so as to produce a hollow emission profile. Spatially resolved spectra produced by spherically bent crystals were recorded, both time-integrated and time-resolved, and were used to show that these two sources of radiation peak at the same time.

  8. Interfacial charging phenomena of aluminum (hydr)oxides

    SciTech Connect (OSTI)

    Hiemstra, T.; Yong, H.; Van Riemsdijk, W.H.

    1999-08-31

    The interfacial charging of Al(OH){sub 3} (gibbsite and bayerite) and Al{sub 2}O{sub 3} has been studied. For Al(OH){sub 3} it can be shown that the very strong variation in charging behavior for different preparations is related to the relative presence of differently reacting crystal planes. The edge faces of the hexagonal gibbsite crystals are proton reactive over the whole pH range, in contrast to the 001 plane, which is mainly uncharged below pH = 10. On this 001 face only doubly coordinated surface groups are found, in contrast to the edges which also have singly coordinated surface groups. The results are fully in agreement with the predictions of the Multi site complexation (MUSIC) model. The proton adsorption, electrolyte ion adsorption, and shift of the IEP of gibbsite and aluminum oxide have been modeled simultaneously. For gibbsite, the ion pair formation of Na is larger than that of Cl, as is evidenced by modeling the experimentally observed upward shift on the IEP and charge reversal at high electrolyte concentrations. All these experimental results can be satisfactorily modeled with the MUSIC model, including the experimental surface potential of aluminum oxide (ISFET).

  9. ATOMIC-LAYER-DEPOSITED ALUMINUM OXIDE FOR THE SURFACE PASSIVATION OF HIGH-EFFICIENCY SILICON SOLAR CELLS

    E-Print Network [OSTI]

    ATOMIC-LAYER-DEPOSITED ALUMINUM OXIDE FOR THE SURFACE PASSIVATION OF HIGH-EFFICIENCY SILICON SOLAR- contacted rear being either passivated by atomic-layer- deposited Al2O3 or by stacks consisting-Si passivation to thermal processes. ATOMIC-LAYER-DEPOSITED Al2O3 Recently, it was shown that thin films

  10. SPALLING FAILURE OF A THERMAL BARRIER COATING ASSOCIATED WITH ALUMINUM DEPLETION

    E-Print Network [OSTI]

    Clarke, David R.

    SPALLING FAILURE OF A THERMAL BARRIER COATING ASSOCIATED WITH ALUMINUM DEPLETION IN THE BOND-COAT EÐA plasma-sprayed thermal barrier coating is observed to spall after oxidation at 11218C from a CoNiCrAlY bond-coated superalloy at the interface between the thermally grown oxide (TGO) and the zir- conia

  11. The problem of intermixing of metals possessing no mutual solubility upon explosion welding (Cu-Ta, Fe-Ag, Al-Ta)

    SciTech Connect (OSTI)

    Greenberg, B.A., E-mail: bella@imp.uran.ru [Institute of Metal Physics, Ural Branch, Russian Academy of Sciences, S. Kovalevskoi str. 18, Ekaterinburg, 620990 (Russian Federation); Ivanov, M.A. [Kurdyumov Institute of Metal Physics, National Academy of Sciences of Ukraine, Vernadskogo blvd. 36, Kiev, 03680 (Ukraine)] [Kurdyumov Institute of Metal Physics, National Academy of Sciences of Ukraine, Vernadskogo blvd. 36, Kiev, 03680 (Ukraine); Rybin, V.V. [State Polytechnical University, Politekhnicheskaya str. 29, St. Petersburg, 195251 (Russian Federation)] [State Polytechnical University, Politekhnicheskaya str. 29, St. Petersburg, 195251 (Russian Federation); Elkina, O.A.; Antonova, O.V.; Patselov, A.M.; Inozemtsev, A.V.; Plotnikov, A.V.; Volkova, A.Yu. [Institute of Metal Physics, Ural Branch, Russian Academy of Sciences, S. Kovalevskoi str. 18, Ekaterinburg, 620990 (Russian Federation)] [Institute of Metal Physics, Ural Branch, Russian Academy of Sciences, S. Kovalevskoi str. 18, Ekaterinburg, 620990 (Russian Federation); Besshaposhnikov, Yu.P. [OJSC Ural Chemical Machine Building Plant, Khibinogorskii Lane 33, Ekaterinburg, 620010 (Russian Federation)] [OJSC Ural Chemical Machine Building Plant, Khibinogorskii Lane 33, Ekaterinburg, 620010 (Russian Federation)

    2013-01-15

    On the basis of the results obtained for joints of dissimilar metals such as copper-tantalum and iron-silver, the reason of immiscible suspensions mixing upon explosion welding has been cleared out. It has been found that the interface (plain or wavy) is not smooth and contains inhomogeneities, namely, cusps and local melting zones. The role of granulating fragmentation providing partitioning of initial materials as a main channel of input energy dissipation has been revealed. It has been shown that in joints of metals possessing normal solubility the local melting zones are true solutions, but if metals possess no mutual solubility the local melting zones are colloidal solutions. Realization of either emulsion or suspension variant takes place. The results can be used in the development of new joints of metals possessing no mutual solubility. - Highlights: Black-Right-Pointing-Pointer Immiscible pairs Ta/Cu and Fe/Ag are welded successfully by explosive welding. Black-Right-Pointing-Pointer Fragmentation provides for partitioning as the main energy dissipation channel. Black-Right-Pointing-Pointer Immiscible metals form colloidal solid solutions during solidification. Black-Right-Pointing-Pointer Melting and boiling temperatures ratio determines the colloidal solution type. Black-Right-Pointing-Pointer Local melting zones being in suspension form enhance welds hardening.

  12. Effects of ductile phase volume fraction on the mechanical properties of Ti-Al?Ti metal-intermetallic laminate (MIL) composites

    E-Print Network [OSTI]

    Price, Richard David

    2010-01-01

    ductile behavior, and so should have had the highest fracture toughness.fracture toughness of 31.65MPa?m, indicating primarily ductilefracture toughness decreased steadily with decreasing Al volume fraction, indicating a reduction of ductile

  13. Advanced manufacturing by spray forming: Aluminum strip and microelectromechanical systems

    SciTech Connect (OSTI)

    McHugh, K.M.

    1994-12-31

    Spray forming is an advanced materials processing technology that converts a bulk liquid metal to a near-net-shape solid by depositing atomized droplets onto a suitably shaped substrate. By combining rapid solidification processing with product shape control, spray forming can reduce manufacturing costs while improving product quality. INEL is developing a unique spray-forming method based on de Laval (converging/diverging) nozzle designs to produce near-net-shape solids and coatings of metals, polymers, and composite materials. Properties of the spray-formed material are tailored by controlling the characteristics of the spray plume and substrate. Two examples are described: high-volume production of aluminum alloy strip, and the replication of micron-scale features in micropatterned polymers during the production of microelectromechanical systems.

  14. MECS 2006 - Alumina and Aluminum | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    documents Manufacturing Energy and Carbon Footprint Alumina and Aluminum More Documents & Publications Alumina and Aluminum (2010 MECS) MECS 2006 - Cement MECS 2006 - Glass...

  15. Commonwealth Aluminum: Manufacturer Conducts Plant-Wide Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Costs by Increasing Energy Efficiency in Process Heating Systems ITP Aluminum: Aluminum Industry Roadmap for the Automotive Market (May 1999) Improving Process Heating System...

  16. Rechargeable Aluminum Batteries with Conducting Polymers as Active...

    Office of Scientific and Technical Information (OSTI)

    Rechargeable Aluminum Batteries with Conducting Polymers as Active Cathode Materials. Citation Details In-Document Search Title: Rechargeable Aluminum Batteries with Conducting...

  17. Improved dual flow aluminum hydrogen peroxide battery

    SciTech Connect (OSTI)

    Marsh, C.; Licht, S.L.; Matthews, D.

    1993-11-30

    A novel dual flow battery configuration is provided comprising an aqueous hydrogen peroxide catholyte, an aqueous anolyte, a porous solid electrocatalyst capable of reducing said hydrogen peroxide and separating said anolyte, and an aluminum anode positioned within said anolyte. Separation of catholyte and anolyte chambers prevents hydrogen peroxide poisoning of the aluminum anode.

  18. Gating of Permanent Molds for ALuminum Casting

    SciTech Connect (OSTI)

    David Schwam; John F. Wallace; Tom Engle; Qingming Chang

    2004-03-30

    This report summarizes a two-year project, DE-FC07-01ID13983 that concerns the gating of aluminum castings in permanent molds. The main goal of the project is to improve the quality of aluminum castings produced in permanent molds. The approach taken was determine how the vertical type gating systems used for permanent mold castings can be designed to fill the mold cavity with a minimum of damage to the quality of the resulting casting. It is evident that somewhat different systems are preferred for different shapes and sizes of aluminum castings. The main problems caused by improper gating are entrained aluminum oxide films and entrapped gas. The project highlights the characteristic features of gating systems used in permanent mold aluminum foundries and recommends gating procedures designed to avoid common defects. The study also provides direct evidence on the filling pattern and heat flow behavior in permanent mold castings.

  19. Process for production of a metal hydride

    DOE Patents [OSTI]

    Allen, Nathan Tait; Butterick, III, Robert; Chin, Arthur Achhing; Millar, Dean Michael; Molzahn, David Craig

    2014-08-12

    A process for production of a metal hydride compound MH.sub.x, wherein x is one or two and M is an alkali metal, Be or Mg. The process comprises combining a compound of formula (R.sup.1O).sub.xM with aluminum, hydrogen and at least one metal selected from among titanium, zirconium, hafnium, niobium, vanadium, tantalum and iron to produce a compound of formula MH.sub.x. R.sup.1 is phenyl or phenyl substituted by at least one alkyl or alkoxy group. A mole ratio of aluminum to (R.sup.1O).sub.xM is from 0.1:1 to 1:1. The catalyst is present at a level of at least 200 ppm based on weight of aluminum.

  20. Metal-templated assembly of protein cages

    E-Print Network [OSTI]

    Huard, Dustin Johnathen Edward

    2012-01-01

    Chapter 2. Generation of Metal-Responsive HuHF Buildingprotein interactions through metal coordination: Assembly ofSalgado, E.N. , et al. , Metal-mediated self-assembly of

  1. Preliminary study of the electrolysis of aluminum sulfide in molten salts

    SciTech Connect (OSTI)

    Minh, N.Q.; Loutfy, R.O.; Yao, N.P.

    1983-02-01

    A preliminary laboratory-scale study of the electrolysis of aluminum sulfide in molten salts investigated the (1) solubility of Al/sub 2/S/sub 3/ in molten salts, (2) electrochemical behavior of Al/sub 2/S/sub 3/, and (3) electrolysis of Al/sub 2/S/sub 3/ with the determination of current efficiency as a function of current density. The solubility measurements show that MgCl/sub 2/-NaCl-KCl eutectic electrolyte at 1023 K can dissolve up to 3.3 mol % sulfide. The molar ratio of sulfur to aluminum in the eutectic is about one, which suggests that some sulfur remains undissolved, probably in the form of MgS. The experimental data and thermodynamic calculations suggest that Al/sub 2/S/sub 3/ dissolves in the eutectic to form AlS/sup +/ species in solution. Addition of AlCl/sub 3/ to the eutectic enhances the solubility of Al/sub 2/S/sub 3/; the solubility increases with increasing AlCl/sub 3/ concentration. The electrode reaction mechanism for the electrolysis of Al/sub 2/S/sub 3/ was elucidated by using linear sweep voltammetry. The cathodic reduction of aluminum-ion-containing species to aluminum proceeds by a reversible, diffusion-controlled, three-electron reaction. The anodic reaction involves the two-electron discharge of sulfide-ion-containing species, followed by the fast dimerization of sulfur atoms to S/sub 2/. Electrolysis experiments show that Al/sub 2/S/sub 3/ dissolved in molten MgCl/sub 2/-NaCl-KCl eutectic or in eutectic containing AlCl/sub 3/ can be electrolyzed to produce aluminum and sulfur. In the eutectic at 1023 K, the electrolysis can be conducted up to about 300 mA/cm/sup 2/ for the saturation solubility of Al/sub 2/S/sub 3/. Although these preliminary results are promising, additional studies are needed to elucidate many critical operating parameters before the technical potential of the electrolysis can be accurately assessed. 20 figures, 18 tables.

  2. Characterization of the plastic strain theory for predicting hot cracking during welding in aluminum alloys 

    E-Print Network [OSTI]

    Walters, Douglas Frederick

    1970-01-01

    , PRESENTATION OF DATA. 12 1. Simulated Weld Data. 2. Photomicrographs 12 19 DISCUSSION OF RESULTS, . 29 VI CONCLUSIONS AND RECOMMENDATIONS I REFERENCES. 38 39 VITA. 40 LIST OF TABLES Table Page Properties of Aluminum Alloys. Test Results for 7075... able 4 presents the data associated with the 5086 alloy. Table Nx 5 presents the test data for 5052 alloy. Table 6 presents test data 13 Table 1. Properties of Aluminum Alloys Al loy 7075 Composition w 0 Mg ? 2. 5 Cu ? 1. 5 Cr ? 0. 3 Zn ? 5...

  3. TiN coated aluminum electrodes for DC high voltage electron guns

    SciTech Connect (OSTI)

    Mamun, Md Abdullah A.; Elmustafa, Abdelmageed A.; Taus, Rhys; Forman, Eric; Poelker, Matthew

    2015-05-01

    Preparing electrodes made of metals like stainless steel, for use inside DC high voltage electron guns, is a labor-intensive and time-consuming process. In this paper, the authors report the exceptional high voltage performance of aluminum electrodes coated with hard titanium nitride (TiN). The aluminum electrodes were comparatively easy to manufacture and required only hours of mechanical polishing using silicon carbide paper, prior to coating with TiN by a commercial vendor. The high voltage performance of three TiN-coated aluminum electrodes, before and after gas conditioning with helium, was compared to that of bare aluminum electrodes, and electrodes manufactured from titanium alloy (Ti-6AI-4V). Following gas conditioning, each TiN-coated aluminum electrode reached -225 kV bias voltage while generating less than 100 pA of field emission (<10 pA) using a 40 mm cathode/anode gap, corresponding to field strength of 13.7 MV/m. Smaller gaps were studied to evaluate electrode performance at higher field strength with the best performing TiN-coated aluminum electrode reaching ~22.5 MV/m with field emission less than 100 pA. These results were comparable to those obtained from our best-performing electrodes manufactured from stainless steel, titanium alloy and niobium, as reported in references cited below. The TiN coating provided a very smooth surface and with mechanical properties of the coating (hardness and modulus) superior to those of stainless steel, titanium-alloy, and niobium electrodes. These features likely contributed to the improved high voltage performance of the TiN-coated aluminum electrodes.

  4. Metastable phases in mechanically alloyed aluminum germanium powders

    SciTech Connect (OSTI)

    Yvon, P.J.; Schwarz, R.B.

    1993-03-01

    Aluminum and germanium form a simple eutectic system with no stable intermetallic phase, and limited mutual solubility. We report the formation of a metastable rhombohedral,{gamma}{sub 1} phase by mechanically alloying aluminum and germanium powders. This phase, which appears for compositions between 20 and 50 at. % germanium, has also been observed in rapidly quenched alloys, but there is disagreement as to its composition. By measuring the heat of crystallization as a function of composition, we determined the composition of the {gamma}{sub 1} phase to be Al{sub 70}Ge{sub 30}. We also produced Al{sub 70}Ge{sub 30} by arc melting the pure elements, followed by splat-quenching at a cooling rate in the range of 10{sup 8} K s{sup {minus}1}. This method produced two metastable phases, one of which was found to be the {gamma}{sub 1} phase obtained by mechanical alloying. The other was a monoclinic phase reported earlier in the literature as {gamma}{sub 2}.

  5. Method of manufacturing a niobium-aluminum-germanium superconductive material

    DOE Patents [OSTI]

    Wang, John L. (San Francisco, CA); Pickus, Milton R. (Oakland, CA); Douglas, Kent E. (Redondo Beach, CA)

    1980-01-01

    A method for manufacturing flexible Nb.sub.3 (Al,Ge) multifilamentary superconductive material in which a sintered porous niobium compact is infiltrated with an aluminum-germanium alloy and thereafter deformed and heat treated in a series of steps at different successively higher temperatures preferably below 1000.degree. C. to produce filaments composed of Nb.sub.3 (Al,G3) within the compact. By avoiding temperatures in excess of 1000.degree. C. during the heat treatment, cladding material such as copper can be applied to facilitate a deformation step preceding the heat treatment and can remain in place through the heat treatment to also serve as a temperature stabilizer for supeconductive material produced. Further, these lower heat treatment temperatures favor formation of filaments with reduced grain size and, hence with more grain boundaries which in turn increase the current-carrying capacity of the superconductive material.

  6. Cathode for aluminum producing electrolytic cell

    DOE Patents [OSTI]

    Brown, Craig W.

    2004-04-13

    A method of producing aluminum in an electrolytic cell comprising the steps of providing an anode in a cell, preferably a non-reactive anode, and also providing a cathode in the cell, the cathode comprised of a base material having low electrical conductivity reactive with molten aluminum to provide a highly electrically conductive layer on the base material. Electric current is passed from the anode to the cathode and alumina is reduced and aluminum is deposited at the cathode. The cathode base material is selected from boron carbide, and zirconium oxide.

  7. Inhibition of Aluminum Oxyhydroxide Precipitation with Citric Acid

    E-Print Network [OSTI]

    Aksay, Ilhan A.

    /mol) hydroxide-to-aluminum ratios. Conversely, citric acid also colloidally stabilizes particles in aqueous particles in high pH suspension.7 Past work by our group dealt with the stabilization of aluminum oxide suspensions of aluminum-containing particles. Solutions of aluminum chloride, with and without citric acid

  8. ALUMINUM--2001 6.1 By Patricia A. Plunkert

    E-Print Network [OSTI]

    ALUMINUM--2001 6.1 ALUMINUM By Patricia A. Plunkert Domestic survey data and tables were prepared, international data coordinator. In 2001, 11 domestic companies operated 23 primary aluminum reduction plants consumption in 2001. The recycling rate for aluminum UBCs decreased to 55.4%, compared with 62.1% in 2000

  9. Cost and energy consumption estimates for the aluminum-air battery anode fuel cycle

    SciTech Connect (OSTI)

    Humphreys, K.K.; Brown, D.R.

    1990-01-01

    At the request of DOE's Office of Energy Storage and Distribution (OESD), Pacific Northwest Laboratory (PNL) conducted a study to generate estimates of the energy use and costs associated with the aluminum anode fuel cycle of the aluminum-air (Al-air) battery. The results of this analysis indicate that the cost and energy consumption characteristics of the mechanically rechargeable Al-air battery system are not as attractive as some other electrically rechargeable electric vehicle battery systems being developed by OESD. However, there are distinct advantages to mechanically rechargeable batteries, which may make the Al-air battery (or other mechanically rechargeable batteries) attractive for other uses, such as stand-alone applications. Fuel cells, such as the proton exchange membrane (PEM), and advanced secondary batteries may be better suited to electric vehicle applications. 26 refs., 3 figs., 25 tabs.

  10. High Methane Storage Capacity in Aluminum Metal-Organic Frameworks |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid you notHeat Pumps Heat Pumps An error occurred. Try| Center for

  11. From micro- to nano-scale molding of metals : size effect during molding of single crystal Al with rectangular strip punches.

    SciTech Connect (OSTI)

    Chen, K.; Meng, W. J.; Mei, F.; Hiller, J.; Miller, D. J. (Materials Science Division); (Louisiana State Univ.); (Enervana Tech. LLC)

    2011-02-01

    A single crystal Al specimen was molded at room temperature with long, rectangular, strip diamond punches. Quantitative molding response curves were obtained at a series of punch widths, ranging from 5 {micro}m to 550 nm. A significant size effect was observed, manifesting itself in terms of significantly increasing characteristic molding pressure as the punch width decreases to 1.5 {micro}m and below. A detailed comparison of the present strip punch molding results was made with Berkovich pyramidal indentation on the same single crystal Al specimen. The comparison reveals distinctly different dependence of the characteristic pressure on corresponding characteristic length. The present results show the feasibility of micro-/nano-scale compression molding as a micro-/nano-fabrication technique, and offer an experimental test case for size-dependent plasticity theories.

  12. ITP Aluminum: Aluminum Industry Vision: Sustainable Solutions for a Dynamic World

    Office of Energy Efficiency and Renewable Energy (EERE)

    The Aluminum Vision is intended to stimulate a wide variety of R&D activities to accelerate technology development throughout industry.

  13. UV Curable Coatings in Aluminum Can Production 

    E-Print Network [OSTI]

    Donhowe, E. T.

    1994-01-01

    based coatings. The Coors Brewing Company Can Manufacturing Plant has been utilizing this technology in full scale aluminum can production since 1975, and therefore has had the opportunity to evaluate practical operations of the UV technology...

  14. Aluminum ion batteries: electrolytes and cathodes

    E-Print Network [OSTI]

    Reed, Luke

    2015-01-01

    W. Sea Water Activated Aluminium-Air Cell. Electrochim. ActaADVANCES IN ALUMINUM - AIR SALT-WATER BATTERIES. Abstr. Pap.liquid has been shown to be air and water stable and allowed

  15. Aluminum ion batteries: electrolytes and cathodes

    E-Print Network [OSTI]

    Reed, Luke

    2015-01-01

    Benign Electrochemical Energy Storage and Conversion DevicesN. J. Aluminum as Anode for Energy Storage and Conversion: Awith other forms of energy storage. In light of this, there

  16. Thin-film solar cell fabricated on a flexible metallic substrate

    DOE Patents [OSTI]

    Tuttle, John R.; Noufi, Rommel; Hasoon, Falah S.

    2006-05-30

    A thin-film solar cell (10) is provided. The thin-film solar cell (10) comprises a flexible metallic substrate (12) having a first surface and a second surface. A back metal contact layer (16) is deposited on the first surface of the flexible metallic substrate (12). A semiconductor absorber layer (14) is deposited on the back metal contact. A photoactive film deposited on the semiconductor absorber layer (14) forms a heterojunction structure and a grid contact (24) deposited on the heterjunction structure. The flexible metal substrate (12) can be constructed of either aluminium or stainless steel. Furthermore, a method of constructing a solar cell is provided. The method comprises providing an aluminum substrate (12), depositing a semiconductor absorber layer (14) on the aluminum substrate (12), and insulating the aluminum substrate (12) from the semiconductor absorber layer (14) to inhibit reaction between the aluminum substrate (12) and the semiconductor absorber layer (14).

  17. Thin-Film Solar Cell Fabricated on a Flexible Metallic Substrate

    DOE Patents [OSTI]

    Tuttle, J. R.; Noufi, R.; Hasoon, F. S.

    2006-05-30

    A thin-film solar cell (10) is provided. The thin-film solar cell (10) comprises a flexible metallic substrate (12) having a first surface and a second surface. A back metal contact layer (16) is deposited on the first surface of the flexible metallic substrate (12). A semiconductor absorber layer (14) is deposited on the back metal contact. A photoactive film deposited on the semiconductor absorber layer (14) forms a heterojunction structure and a grid contact (24) deposited on the heterjunction structure. The flexible metal substrate (12) can be constructed of either aluminium or stainless steel. Furthermore, a method of constructing a solar cell is provided. The method comprises providing an aluminum substrate (12), depositing a semiconductor absorber layer (14) on the aluminum substrate (12), and insulating the aluminum substrate (12) from the semiconductor absorber layer (14) to inhibit reaction between the aluminum substrate (12) and the semiconductor absorber layer (14).

  18. Anomalous deformation twinning in fcc metals at high temperatures Tanushree Sinha and Yashashree Kulkarnia)

    E-Print Network [OSTI]

    Kulkarni, Yashashree

    of nanotwinned metals, especially at high temperatures. Recent studies by Shute et al.18 and Saldana et al.19

  19. Surface chemical reaction of laser ablated aluminum sample for detonation initiation

    SciTech Connect (OSTI)

    Kim, Chang-hwan; Yoh, Jack J. [School of Mechanical and Aerospace Engineering, Seoul National University, 599 Kwanakro, Kwanakgu, Seoul, Korea 151-742 (Korea, Republic of)

    2011-05-01

    We explore the evolution of metal plasma generated by high laser irradiances and its effect on the surrounding air by using shadowgraph images after laser pulse termination; hence the formation of laser supported detonation and combustion processes has been investigated. The essence of the paper is in observing initiation of chemical reaction between ablated aluminum plasma and oxygen from air by inducing high power laser pulse (>1000 mJ/pulse) and conduct a quantitative comparison of chemically reactive laser initiated waves with the classical detonation of exploding aluminum (dust) cloud in air. Findings in this work may lead to a new method of initiating detonation from metal sample in its bulk form without the need of mixing nano-particles with oxygen for initiation.

  20. (Data in thousand metric tons of silicon content unless otherwise noted) Domestic Production and Use: Estimated value of silicon alloys and metal produced in the United States in 2011

    E-Print Network [OSTI]

    and aluminum alloys and the chemical industry. The semiconductor and solar industries, which manufacture chips%; and other, 4%. Silicon metal: Brazil, 39%; South Africa, 22%; Canada, 13%; Australia, 10%; and other, 16 secondary aluminum production--the primary materials source for aluminum-silicon alloys--was projected

  1. Laser removal of Aluminum links for applications in wafer scale integrated circuits 

    E-Print Network [OSTI]

    Parikh, Harshavadan B.

    1987-01-01

    predesigned redundancy on it. One method to invoke this redundancy uses links which may be broken after the manufacture of the circuit is complete. In this work, a focused Nd:YAG laser beam is used to break the connections or links when Aluminum is used... required for discretionary wiring proved inadequate for a production environment. [2] Pad Relocation Technique: Hughes aircraft Company improved the method suggested by TI by developing a pad relocation technique requiring a single discretionary metal...

  2. Measurement of quasiparticle transport in aluminum films using tungsten transition-edge sensors

    SciTech Connect (OSTI)

    Yen, J. J. Shank, B.; Cabrera, B.; Moffatt, R.; Redl, P.; Young, B. A.; Tortorici, E. C.; Brink, P. L.; Cherry, M.; Tomada, A.; Kreikebaum, J. M.

    2014-10-20

    We report on experimental studies of phonon sensors which utilize quasiparticle diffusion in thin aluminum films connected to tungsten transition-edge-sensors (TESs) operated at 35 mK. We show that basic TES physics and a simple physical model of the overlap region between the W and Al films in our devices enables us to accurately reproduce the experimentally observed pulse shapes from x-rays absorbed in the Al films. We further estimate quasiparticle loss in Al films using a simple diffusion equation approach. These studies allow the design of phonon sensors with improved performance.

  3. Low Temperature Aluminum Dissolution Of Sludge Waste

    SciTech Connect (OSTI)

    Keefer, M.T.; Hamm, B.A.; Pike, J.A. [Washington Savannah River Company, Aiken, SC (United States)

    2008-07-01

    High Level Waste (HLW) at the Savannah River Site (SRS) is currently stored in aging underground storage tanks. This waste is a complex mixture of insoluble solids, referred to as sludge, and soluble salts. Continued long-term storage of these radioactive wastes poses an environmental risk. The sludge is currently being stabilized in the Defense Waste Processing Facility (DWPF) through a vitrification process immobilizing the waste in a borosilicate glass matrix for long-term storage in a federal repository. Without additional treatment, the existing volume of sludge would produce nearly 8000 canisters of vitrified waste. Aluminum compounds, along with other non-radioactive components, represent a significant portion of the sludge mass currently planned for vitrification processing in DWPF. Removing the aluminum from the waste stream reduces the volume of sludge requiring vitrification and improves production rates. Treating the sludge with a concentrated sodium hydroxide (caustic) solution at elevated temperatures (>90 deg. C) to remove aluminum is part of an overall sludge mass reduction effort to reduce the number of vitrified canisters, shorten the life cycle for the HLW system, and reduce the risk associated with the long term storage of radioactive wastes at SRS. A projected reduction of nearly 900 canisters will be achieved by performing aluminum dissolution on six targeted sludge batches; however, a project to develop and install equipment will not be ready for operation until 2013. The associated upgrades necessary to implement a high temperature process in existing facilities are costly and present many technical challenges. Efforts to better understand the characteristics of the sludge mass and dissolution kinetics are warranted to overcome these challenges. Opportunities to further reduce the amount of vitrified waste and increase production rates should also be pursued. Sludge staged in Tank 51 as the next sludge batch for feed to DWPF consisted primarily of radioactive wastes containing a very high aluminum concentration. Based on initial laboratory testing and previous sludge characterization, aluminum in this sludge could be dissolved at low temperature (no more than 65 deg. C) in a concentrated caustic solution. The amount of aluminum predicted to dissolve under these conditions ranged from 25% to 80%. An opportunity existed to remove a significant amount of aluminum prior to vitrification in DWPF and increase the level of understanding of the effects of caustic dissolution of aluminum at lower temperatures. This paper presents the results of a real waste laboratory demonstration and full-scale implementation of a low temperature aluminum dissolution process which should be considered as a viable means to reduce radioactive sludge mass and reduce the amount of waste to be vitrified. (authors)

  4. (Polyfluoroaryl)fluoroanions of aluminum, gallium, and indium of enhanced utility, uses thereof, and products based thereon

    DOE Patents [OSTI]

    Marks, Tobin J. (Evanston, IL); Chen, You-Xian (Midland, MI)

    2001-01-01

    The (polyfluoroaryl)fluoroanions of aluminum, gallium, and indium are novel weakly coordinating anions which are are highly fluorinated. (Polyfluoroaryl)fluoroanions of one such type contain at least one ring substituent other than fluorine. These (polyfluoroaryl)fluoroanions of aluminum, gallium, and indium have greater solubility in organic solvents, or have a coordinative ability essentially equal to or less than that of the corresponding (polyfluoroaryl)fluoroanion of aluminum, gallium, or indium in which the substituent is replaced by fluorine. Another type of new (polyfluoroaryl)fluoroanion of aluminum, gallium, and indium have 1-3 perfluorinated fused ring groups and 2-0 perfluorophenyl groups. When used as a cocatalyst in the formation of novel catalytic complexes with d- or f-block metal compounds having at least one leaving group such as a methyl group, these anions, because of their weak coordination to the metal center, do not interefere in the ethylene polymerization process, while affecting the the propylene process favorably, if highly isotactic polypropylene is desired. Thus, the (polyfluoroaryl)fluoroanions of aluminum, gallium, and indium of this invention are useful in various polymerization processes such as are described.

  5. Aluminum oxyhydroxide based separator/electrolyte and battery system, and a method of making the same

    DOE Patents [OSTI]

    Gerald, II; Rex E. (Brookfield, IL); Klingler, Robert J. (Glenview, IL); Rathke, Jerome W. (Homer Glen, IL)

    2011-02-15

    The instant invention relates a solid-state electrochemical cell and a novel separator/electrolyte incorporated therein. The invented electrochemical cell generally comprising: a unique metal oxyhydroxide based (i.e. AlOOH) separator/electrolyte membrane sandwiched between a first electrode and a second electrode. The novel separator/electrolyte comprises a nanoparticulate metal oxyhydroxide, preferably AlOOH and a salt which are mixed and then pressed together to form a monolithic metal oxyhydroxide-salt membrane.

  6. TEST RESULTS FROM GAMMA IRRADIATION OF ALUMINUM OXYHYDROXIDES

    SciTech Connect (OSTI)

    Fisher, D.; Westbrook, M.; Sindelar, R.

    2012-02-01

    Hydrated metal oxides or oxyhydroxides boehmite and gibbsite that can form on spent aluminum-clad nuclear fuel assemblies during in-core and post-discharge wet storage were exposed as granular powders to gamma irradiation in a {sup 60}Co irradiator in closed laboratory test vessels with air and with argon as separate cover gases. The results show that boehmite readily evolves hydrogen with exposure up to a dose of 1.8 x 10{sup 8} rad, the maximum tested, in both a full-dried and moist condition of the powder, whereas only a very small measurable quantity of hydrogen was generated from the granular powder of gibbsite. Specific information on the test setup, sample characteristics, sample preparation, irradiation, and gas analysis are described.

  7. Radiation and bias switch-induced charge dynamics in Al{sub 2}O{sub 3}-based metal-oxide-semiconductor structures

    SciTech Connect (OSTI)

    Sambuco Salomone, L. Kasulin, A.; Carbonetto, S. H.; Garcia-Inza, M. A.; Redin, E. G.; Berbeglia, F.; Lipovetzky, J.; Faigón, A.; Campabadal, F.

    2014-11-07

    Charge trapping dynamics induced by exposition to ?-ray ({sup 60}Co) radiation and bias switching in MOS capacitors with atomic layer deposited Al{sub 2}O{sub 3} as insulating layer was studied. Electrical characterization prior to irradiation showed voltage instabilities due to electron tunneling between the substrate and preexisting defects inside the dielectric layer. Real-time capacitance-voltage (C-V) measurements during irradiation showed two distinct regimes: For short times, the response is strongly bias dependent and linear with log(t), consistent with electron trapping/detrapping; for long times, the voltage shift is dominated by the radiation-induced hole capture being always negative and linear with dose. A simple model that takes into account these two phenomena can successfully reproduce the observed results.

  8. Polarization properties of real aluminum mirrors; I. Influence of the aluminum oxide layer

    E-Print Network [OSTI]

    van Harten, G; Keller, C U

    2009-01-01

    In polarimetry it is important to characterize the polarization properties of the instrument itself to disentangle real astrophysical signals from instrumental effects. This article deals with the accurate measurement and modeling of the polarization properties of real aluminum mirrors, as used in astronomical telescopes. Main goals are the characterization of the aluminum oxide layer thickness at different times after evaporation and its influence on the polarization properties of the mirror. The full polarization properties of an aluminum mirror are measured with Mueller matrix ellipsometry at different incidence angles and wavelengths. The best fit of theoretical Mueller matrices to all measurements simultaneously is obtained by taking into account a model of bulk aluminum with a thin aluminum oxide film on top of it. Full Mueller matrix measurements of a mirror are obtained with an absolute accuracy of ~1% after calibration. The determined layer thicknesses indicate logarithmic growth in the first few hou...

  9. Desorption and sublimation kinetics for fluorinated aluminum nitride surfaces

    SciTech Connect (OSTI)

    King, Sean W., E-mail: sean.king@intel.com; Davis, Robert F. [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); Nemanich, Robert J. [Department of Physics, North Carolina State University, Raleigh, North Carolina 27695 (United States)

    2014-09-01

    The adsorption and desorption of halogen and other gaseous species from surfaces is a key fundamental process for both wet chemical and dry plasma etch and clean processes utilized in nanoelectronic fabrication processes. Therefore, to increase the fundamental understanding of these processes with regard to aluminum nitride (AlN) surfaces, temperature programmed desorption (TPD) and x-ray photoelectron spectroscopy (XPS) have been utilized to investigate the desorption kinetics of water (H{sub 2}O), fluorine (F{sub 2}), hydrogen (H{sub 2}), hydrogen fluoride (HF), and other related species from aluminum nitride thin film surfaces treated with an aqueous solution of buffered hydrogen fluoride (BHF) diluted in methanol (CH{sub 3}OH). Pre-TPD XPS measurements of the CH{sub 3}OH:BHF treated AlN surfaces showed the presence of a variety of Al-F, N-F, Al-O, Al-OH, C-H, and C-O surfaces species in addition to Al-N bonding from the AlN thin film. The primary species observed desorbing from these same surfaces during TPD measurements included H{sub 2}, H{sub 2}O, HF, F{sub 2}, and CH{sub 3}OH with some evidence for nitrogen (N{sub 2}) and ammonia (NH{sub 3}) desorption as well. For H{sub 2}O, two desorption peaks with second order kinetics were observed at 195 and 460?°C with activation energies (E{sub d}) of 51?±?3 and 87?±?5?kJ/mol, respectively. Desorption of HF similarly exhibited second order kinetics with a peak temperature of 475?°C and E{sub d} of 110?±?5?kJ/mol. The TPD spectra for F{sub 2} exhibited two peaks at 485 and 585?°C with second order kinetics and E{sub d} of 62?±?3 and 270?±?10?kJ/mol, respectively. These values are in excellent agreement with previous E{sub d} measurements for desorption of H{sub 2}O from SiO{sub 2} and AlF{sub x} from AlN surfaces, respectively. The F{sub 2} desorption is therefore attributed to fragmentation of AlF{sub x} species in the mass spectrometer ionizer. H{sub 2} desorption exhibited an additional high temperature peak at 910?°C with E{sub d}?=?370?±?10?kJ/mol that is consistent with both the dehydrogenation of surface AlOH species and H{sub 2} assisted sublimation of AlN. Similarly, N{sub 2} exhibited a similar higher temperature desorption peak with E{sub d}?=?535?±?40?kJ/mol that is consistent with the activation energy for direct sublimation of AlN.

  10. Radiation tolerance of piezoelectric bulk single-crystal aluminum nitride

    SciTech Connect (OSTI)

    David A. Parks; Bernhard R. Tittmann

    2014-07-01

    For practical use in harsh radiation environments, we pose selection criteria for piezoelectric materials for nondestructive evaluation (NDE) and material characterization. Using these criteria, piezoelectric aluminum nitride is shown to be an excellent candidate. The results of tests on an aluminumnitride-based transducer operating in a nuclear reactor are also presented. We demonstrate the tolerance of single-crystal piezoelectric aluminum nitride after fast and thermal neutron fluences of 1.85 × 1018 neutron/cm2 and 5.8 × 1018 neutron/cm2, respectively, and a gamma dose of 26.8 MGy. The radiation hardness of AlN is most evident from the unaltered piezoelectric coefficient d33, which measured 5.5 pC/N after a fast and thermal neutron exposure in a nuclear reactor core for over 120 MWh, in agreement with the published literature value. The results offer potential for improving reactor safety and furthering the understanding of radiation effects on materials by enabling structural health monitoring and NDE in spite of the high levels of radiation and high temperatures, which are known to destroy typical commercial ultrasonic transducers.

  11. Method for electrochemical decontamination of radioactive metal

    DOE Patents [OSTI]

    Ekechukwu, Amy A. (Augusta, GA)

    2008-06-10

    A decontamination method for stripping radionuclides from the surface of stainless steel or aluminum material comprising the steps of contacting the metal with a moderately acidic carbonate/bicarbonate electrolyte solution containing sodium or potassium ions and thereafter electrolytically removing the radionuclides from the surface of the metal whereby radionuclides are caused to be stripped off of the material without corrosion or etching of the material surface.

  12. New Opportunities for Metals Extraction and Waste Treatment by Electrochemical Processing in Molten Salts

    E-Print Network [OSTI]

    Sadoway, Donald R.

    2001-01-01

    Molten salt electrolysis is a proven technology for the extraction of metals -- all the world's primary aluminum is produced in this manner. The unique properties of molten salts also make them

  13. Investigation of zinc oxide doped with metal impurities for use as thin film conductive phosphors 

    E-Print Network [OSTI]

    Evatt, Steven R.

    1994-01-01

    in which metal dopants were introduced in ZnO. This survey has revealed tungsten doped ZnO to be a previously unreported brilliant blue phosphor with high resistivity. Additional experiments indicated aluminum could be introduced in conjunction...

  14. Method for gas bubble and void control and removal from metals

    DOE Patents [OSTI]

    Van Siclen, Clinton D. (Idaho Falls, ID); Wright, Richard N. (Idaho Falls, ID)

    1996-01-01

    A method for enhancing the diffusion of gas bubbles or voids attached to impurity precipitates, and biasing their direction of migration out of the host metal (or metal alloy) by applying a temperature gradient across the host metal (or metal alloy). In the preferred embodiment of the present invention, the impurity metal is insoluble in the host metal and has a melting point lower than the melting point of the host material. Also, preferably the impurity metal is lead or indium and the host metal is aluminum or a metal alloy.

  15. Method for gas bubble and void control and removal from metals

    DOE Patents [OSTI]

    Siclen, C.D. Van; Wright, R.N.

    1996-02-06

    A method is described for enhancing the diffusion of gas bubbles or voids attached to impurity precipitates, and biasing their direction of migration out of the host metal (or metal alloy) by applying a temperature gradient across the host metal (or metal alloy). In the preferred embodiment of the present invention, the impurity metal is insoluble in the host metal and has a melting point lower than the melting point of the host material. Also, preferably the impurity metal is lead or indium and the host metal is aluminum or a metal alloy. 2 figs.

  16. Behavior of Aluminum, Arsenic, and Vanadium during the Neutralization of Red Mud Leachate by HCl, Gypsum, or Seawater

    E-Print Network [OSTI]

    Burke, Ian

    Behavior of Aluminum, Arsenic, and Vanadium during the Neutralization of Red Mud Leachate by HCl ABSTRACT: Red mud leachate (pH 13) collected from Ajka, Hungary is neutralized to via surface adsorption of As onto the Al oxyhydroxides. Gypsum addition to red mud leachate results

  17. Refining of solid ferrous scrap intermingled with copper by using molten aluminum

    SciTech Connect (OSTI)

    Iwase, M. [Kyoto Univ. (Japan). Dept. of Energy Science and Engineering

    1996-12-31

    A new approach for the removal of copper from solid ferrous scrap has been proposed by the present authors. With this process, solid ferrous scrap intermingled with pure copper is brought into contact with molten aluminum, which dissolved copper preferentially, and is recovered as {l_brace}Al + Cu{r_brace} alloys. After a duration of 30 minutes at temperatures between 963 K and 1,223 K, steel scrap is removed from the bath, resulting in being free of copper contamination.

  18. Quench-age method for the fabrication of niobium-aluminum superconductors

    DOE Patents [OSTI]

    Pickus, Milton R. (Oakland, CA); Ciardella, Robert L. (Cardiff, CA)

    1978-01-01

    A flexible Nb.sub.3 Al superconducting wire is fabricated from a niobium-aluminum composite wire by heating to form a solid solution which is retained at room temperature as a metastable solid solution by quenching. The metastable solid solution is then transformed to the stable superconducting A-15 phase by low temperature aging. The transformation induced by aging can be controlled to yield either a multifilamentary or a solid A-15 core surrounded by ductile niobium.

  19. Joining of highly aluminum-doped lanthanum strontium manganese oxide with tetragonal zirconia by plastic deformation

    E-Print Network [OSTI]

    Dutta, Prabir K.

    Joining of highly aluminum-doped lanthanum strontium manganese oxide with tetragonal zirconia0.20Al0.9Mn0.1O3 (LSAM), was joined to stabilized tetragonal zirconia polymorph YTZP (ZrO2)0.97(Y2O3-stabilized zirconia (YSZ) is a solid electrolyte used in high-temperature devices such as fuel cells and oxygen

  20. Structure and properties of a rapidly solidified dispersion strengthened aluminum-iron-vanadium-silicon alloy 

    E-Print Network [OSTI]

    Little, Stafford Dean

    1991-01-01

    of the requirements for the degree of MASTER OF SCIENCE December 1991 Major Subject: Mechanical Engineering STRUCTURE AND PROPERTIES OF A RAPIDLY SOLIDIFIED DISPERSION STRENGTHENED ALUMINUM-IRON-VANADIUM-SILICON ALLOY A Thesis by STAFFORD DEAN LITTLE Approved... Al-Fe-V-Si alloys II Three Component PUCOT Equations III Four Component PUCOT Equations 16 16 IV Melt Spinning Variables 19 V Young's Modulus Determined by PUCOT 27 VI Tensile Test Data VII Microhardness Measurements at Room Temperature 29...

  1. Laser assisted high entropy alloy coating on aluminum: Microstructural evolution

    SciTech Connect (OSTI)

    Katakam, Shravana; Joshi, Sameehan S.; Mridha, Sanghita; Mukherjee, Sundeep; Dahotre, Narendra B.

    2014-09-14

    High entropy alloy (Al-Fe-Co-Cr-Ni) coatings were synthesized using laser surface engineering on aluminum substrate. Electron diffraction analysis confirmed the formation of solid solution of body centered cubic high entropy alloy phase along with phases with long range periodic structures within the coating. Evolution of such type of microstructure was a result of kinetics associated with laser process, which generates higher temperatures and rapid cooling resulting in retention of high entropy alloy phase followed by reheating and/or annealing in subsequent passes of the laser track giving rise to partial decomposition. The partial decomposition resulted in formation of precipitates having layered morphology with a mixture of high entropy alloy rich phases, compounds, and long range ordered phases.

  2. Aluminum phosphate ceramics for waste storage

    SciTech Connect (OSTI)

    Wagh, Arun; Maloney, Martin D

    2014-06-03

    The present disclosure describes solid waste forms and methods of processing waste. In one particular implementation, the invention provides a method of processing waste that may be particularly suitable for processing hazardous waste. In this method, a waste component is combined with an aluminum oxide and an acidic phosphate component in a slurry. A molar ratio of aluminum to phosphorus in the slurry is greater than one. Water in the slurry may be evaporated while mixing the slurry at a temperature of about 140-200.degree. C. The mixed slurry may be allowed to cure into a solid waste form. This solid waste form includes an anhydrous aluminum phosphate with at least a residual portion of the waste component bound therein.

  3. Roll Casting of Aluminum Alloy Clad Strip

    SciTech Connect (OSTI)

    Nakamura, R.; Tsuge, H. [Graduate School of Osaka Institute of Technology (Japan); Haga, T. [Osaka Institute of Technology, 5-16-1 Omiya Asahiku Osaka city 535-8585 (Japan); Watari, H. [Tokyo Institute of Technology, 4259 Nagatsuda Midoriku Yokohama city 226-8502 (Japan); Kumai, S. [Gunma University, 1-5-1 tenjin cho Kiryu city 376-8515 (Japan)

    2011-01-17

    Casting of aluminum alloy three layers of clad strip was tried using the two sets of twin roll casters, and effects of the casting parameters on the cladding conditions were investigated. One twin roll caster was mounted on the other twin roll caster. Base strip was 8079 aluminum alloy and overlay strips were 6022 aluminum alloy. Effects of roll-load of upper and lower casters and melt temperature of the lower caster were investigated. When the roll-load of the upper and lower caster was large enough, the overlay strip could be solidified and be connected. The overlay strip could be connected when the melt of the overlay strip cast by the lower caster was low enough. Sound three layers of clad strip could be cast by proper conditions.

  4. Development of epitaxial AlxSc1-xN for artificially structured metal/semiconductor superlattice metamaterials

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sands, Timothy D.; Stach, Eric A.; Saha, Bivas; Saber, Sammy; Naik, Gururaj V.; Boltasseva, Alexandra; Kvam, Eric P.

    2015-02-01

    Epitaxial nitride rocksalt metal/semiconductor superlattices are emerging as a novel class of artificially structured materials that have generated significant interest in recent years for their potential application in plasmonic and thermoelectric devices. Though most nitride metals are rocksalt, nitride semiconductors in general have hexagonal crystal structure. We report rocksalt aluminum scandium nitride (Al,Sc)N alloys as the semiconducting component in epitaxial rocksalt metal/semiconductor superlattices. The AlxSc1-xN alloys when deposited directly on MgO substrates are stabilized in a homogeneous rocksalt (single) phase when x more »the rocksalt phase has been extended to x xSc1-xN alloys show moderate direct bandgap bowing with a bowing parameter, B = 1.41 ± 0.19 eV. The direct bandgap of metastable rocksalt AlN is extrapolated to be 4.70 ± 0.20 eV. The tunable lattice parameter, bandgap, dielectric permittivity, and electronic properties of rocksalt AlxSc1-xN alloys enable high quality epitaxial rocksalt metal/AlxSc1-xN superlattices with a wide range of accessible metamaterials properties.« less

  5. Temperature threshold for nanorod structuring of metal and oxide films grown by glancing angle deposition

    SciTech Connect (OSTI)

    Deniz, Derya; Lad, Robert J.

    2011-01-15

    Thin films of tin (Sn), aluminum (Al), gold (Au), ruthenium (Ru), tungsten (W), ruthenium dioxide (RuO{sub 2}), tin dioxide (SnO{sub 2}), and tungsten trioxide (WO{sub 3}) were grown by glancing angle deposition (GLAD) to determine the nanostructuring temperature threshold, {Theta}{sub T}, above which adatom surface diffusion becomes large enough such that nanorod morphology is no longer formed during growth. The threshold was found to be lower in metals compared to oxides. Films were grown using both dc and pulsed dc magnetron sputtering with continuous substrate rotation over the temperature range from 291 to 866 K. Film morphologies, structures, and compositions were characterized by high resolution scanning electron microscopy, x-ray diffraction, and x-ray photoelectron spectroscopy. Films were also grown in a conventional configuration for comparison. For elemental metals, nanorod structuring occurs for films with melting points higher than that of Al (933 K) when grown at room temperature with a rotation rate of {approx}5 rpm, corresponding to a value of {Theta}{sub T}{approx_equal}0.33{+-}0.01. For the oxide films, a value of {Theta}{sub T}{approx_equal}0.5 was found, above which GLAD nanorod structuring does not occur. The existence of a nanostructuring temperature threshold in both metal and oxide GLAD films can be attributed to greater adatom mobilities as temperature is increased resulting in nonkinetically limited film nucleation and growth processes.

  6. Reaction of Aluminum with Water to Produce Hydrogen - 2010 Update

    Fuel Cell Technologies Publication and Product Library (EERE)

    A Study of Issues Related to the Use of Aluminum for On-Board Vehicular Hydrogen Storage The purpose of this White Paper is to describe and evaluate the potential of aluminum-water reactions for the

  7. Energy Challenges and Conservation Achievements in the Aluminum Industry 

    E-Print Network [OSTI]

    Sheldon, A. C.

    1979-01-01

    Energy is a vital resource in the production of aluminum. It is economically essential that producers use it efficiently. The aluminum industry developed historically in an economy of energy surplus or abundance. It has responded to energy...

  8. Strategies for aluminum recycling : insights from material system optimization

    E-Print Network [OSTI]

    Li, Preston Pui-Chuen

    2005-01-01

    The dramatic increase in aluminum consumption over the past decades necessitates a societal effort to recycle and reuse these materials to promote true sustainability and energy savings in aluminum production. However, the ...

  9. Reaction of Aluminum with Water to Produce Hydrogen: A Study...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Produce Hydrogen: A Study of Issues Related to the Use of Aluminum for On-Board Vehicular Hydrogen Storage. Version 2, 2010. Reaction of Aluminum with Water to Produce Hydrogen: A...

  10. Aluminum plasmonic metamaterials for structural color printing

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cheng, Fei; Gao, Jie; Stan, Liliana; Rosenmann, Daniel; Czaplewski, David; Yang, Xiaodong

    2015-05-26

    We report a structural color printing platform based on aluminum plasmonic metamaterials supporting near perfect light absorption and narrow-band spectral response tunable across the visible spectrum to realize high-resolution, angle-insensitive color printing with high color purity and saturation. Additionally, the fabricated metamaterials can be protected by a transparent polymer thin layer for ambient use with further improved color performance. The demonstrated structural color printing with aluminum plasmonic metamaterials offers great potential for relevant applications such as security marking and information storage.

  11. Optimization of Squeeze Casting for Aluminum Alloy Parts

    SciTech Connect (OSTI)

    David Schwam; John F. Wallace; Qingming Chang; Yulong Zhu

    2002-07-30

    This study was initiated with the installation of a new production size UBE 350 Ton VSC Squeeze Casting system in the Metal Casting Laboratory at Case Western University. A Lindberg 75k W electrical melting furnace was installed alongside. The challenge of installation and operation of such industrial-size equipment in an academic environment was met successfully. Subsequently, a Sterling oil die heater and a Visi-Track shot monitoring system were added. A significant number of inserts were designed and fabricated over the span of the project, primarily for squeeze casting different configurations of test bars and plates. A spiral ''ribbon insert'' for evaluation of molten metal fluidity was also fabricated. These inserts were used to generate a broad range of processing conditions and determine their effect on the quality of the squeeze cast parts. This investigation has studied the influence of the various casting variables on the quality of indirect squeeze castings primarily of aluminum alloys. The variables studied include gating design, fill time and fill patter, metal pressure and die temperature variations. The quality of the die casting was assessed by an analysis of both their surface condition and internal soundness. The primary metal tested was an aluminum 356 alloy. In addition to determining the effect of these casting variables on casting quality as measured by a flat plate die of various thickness, a number of test bar inserts with different gating designs have been inserted in the squeeze casting machine. The mechanical properties of these test bars produced under different squeeze casting conditions were measured and reported. The investigation of the resulting properties also included an analysis of the microstructure of the squeeze castings and the effect of the various structural constituents on the resulting properties. The main conclusions from this investigation are as follows: The ingate size and shape are very important since it must remain open until the casting is solidified and pressure is maintained on the solidifying casting. Fanned gates, particularly on the smaller section castings avoid jetting effects at the ingate end. The fan type ingate helps accomplish a rapid fill without high velocities. The molten metal has to fill the cavity before localized solidification occurs. This is best accomplished with a larger ingate to attain rapid filling without excessive velocity or jetting that occurs at high metal velocities. Straight gates are prone to case jetting of the metal stream even a low velocities. Fanned gates allow use of higher fill velocity without excessive jetting. A higher metal pressure provides a more complete fill of the die including improved compensation for solidification shrinkage. With the proper filling pattern, ingates, overflows and die temperature for a given die, very good tensile properties can be attained in squeeze casting. In general, the smaller squeeze castings require higher die temperatures. Computer models using the UES Procast and MagmaSoft finite element software can, after suitable adjustments, predict the flow pattern in the die cavity.

  12. Aluminum across the Americas: Caribbean Mobilities and Transnational American Studies

    E-Print Network [OSTI]

    Sheller, Mimi

    2013-01-01

    zinc, bauxite, and the hydroelectric power needed to smeltthe Afobaka hydroelectric dam to power an aluminum smelter

  13. The corrosion of aluminum in boric acid solutions 

    E-Print Network [OSTI]

    Bass, Henry Kinsolving

    1956-01-01

    An investigation of the corrosion of aluminum in boric acid solutions was made. The total immersion, continuous agitation method of testing was used. Commercially pure aluminum and two aluminum alloys were exposed to various concentrations of boric acid...THE CORROSION OF ALUMINUM IN BORIC ACID SOLUTIONS A Thesis By HENRI KINSOLVING BASS, JR. Submitted to the Graduate School of the Agricultural and Mechanical College oi' Texas' in partial fulfillment of the requirements for the degree...

  14. Method And Reactor For Production Of Aluminum By Carbothermic Reduction Of Alumina

    DOE Patents [OSTI]

    Aune, Jan Arthur (Ytre Enebakk, NO); Johansen, Kai (Kristiansand, NO)

    2004-10-19

    A hollow partition wall is employed to feed carbon material to an underflow of a carbothermic reduction furnace used to make aluminum. The partition wall divides a low temperature reaction zone where aluminum oxide is reacted with carbon to form aluminum carbide and a high temperature reaction zone where the aluminum carbide and remaining aluminum oxide are reacted to form aluminum and carbon monoxide.

  15. ALUMINUM--1999 5.1 By Patricia A. Plunkert

    E-Print Network [OSTI]

    ALUMINUM--1999 5.1 ALUMINUM By Patricia A. Plunkert Domestic survey data and tables were prepared, international data coordinator. In 1999, 12 domestic companies operated 23 primary aluminum reduction plants beverage can (UBC) scrap accounted for more than one-half of the reported old scrap consumption in 1999

  16. Evaluation of precipitates used in strainer head loss testing : Part II. precipitates by in-situ aluminum alloy corrosion.

    SciTech Connect (OSTI)

    Bahn, C.; Kasza, K. E.; Shack, W. J.; Natesan, K. (Nuclear Engineering Division)

    2011-05-01

    Vertical loop head loss tests were performed with 6061 and 1100 aluminum (Al) alloy plates immersed in borated solution at pH = 9.3 at room temperature and 60 C. The results suggest that the potential for corrosion of an Al alloy to result in increased head loss across a glass fiber bed may depend on its microstructure, i.e., the size distribution and number density of intermetallic particles that are present in Al matrix and FeSiAl ternary compounds, as well as its Al release rate. Per unit mass of Al removed from solution, the WCAP-16530 aluminum hydroxide (Al(OH){sub 3}) surrogate was more effective in increasing head loss than the Al(OH)3 precipitates formed in situ by corrosion of Al alloy. However, in choosing a representative amount of surrogate for plant specific testing, consideration should be given to the potential for additional head losses due to intermetallic particles and the apparent reduction in the effective solubility of Al(OH){sub 3} when intermetallic particles are present.

  17. Commonwealth Aluminum: Manufacturer Conducts Plant-Wide Energy Assessments at Two Aluminum Sheet Production Operations

    Broader source: Energy.gov [DOE]

    This case study describes how Commonwealth Industries (now Aleris Rolled Products) conducted plant-wide energy assessments at its aluminum sheet rolling mills in Lewisport, Kentucky, and Uhrichsville, Ohio, to improve process and energy efficiency.

  18. Metal Oxide Nanostructured Materials for Optical and Energy Applications

    E-Print Network [OSTI]

    Moore, Michael Christopher

    2013-01-01

    of a Stack of Two Metal Micromeshes. The Journal of Physicalals 3, 601 (2004). M. T. Hill et al. Lasing in metal-insulator-metal sub-wavelength plasmonic waveguides. Optics

  19. Effect of electron collecting metal oxide layer in normal and inverted structure polymer solar cells

    SciTech Connect (OSTI)

    Ng, A.; Liu, X.; Sun, Y. C.; Djuriši?, A. B. [Department of Physics, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. (China); Ng, A. M. C. [Department of Physics, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China and Nanostructure Institute for Energy and Environmental Research, Division of Physical Sciences, South University of Science and Technology of China, Shenzhen (China); Chan, W. K. [Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P. R. (China)

    2013-12-04

    We performed a systematic study of the effect of electron collecting metal oxide layer on the performance of P3HT: PCBM solar cells. Zinc oxide (ZnO) or titanium dioxide (TiO{sub 2}) buffer layers were prepared by either e-beam evaporation or solution processing method. We also compared the photovoltaic performance of inserting the buffer layer between indium tin oxide (ITO) and the polymer layer for the inverted structure (ITO/ ZnO or TiO{sub 2}/P3HT:PCBM/V{sub 2}O{sub 5}/Au) as well as inserting the buffers layers between the polymer and the aluminum electrode for the conventional structure (ITO/V{sub 2}O{sub 5}/P3HT:PCBM/ZnO or TiO{sub 2}/Al). The results are shown in detail.

  20. FLOWSHEET FOR ALUMINUM REMOVAL FROM SLUDGE BATCH 6

    SciTech Connect (OSTI)

    Pike, J; Jeffrey Gillam, J

    2008-12-17

    Samples of Tank 12 sludge slurry show a substantially larger fraction of aluminum than originally identified in sludge batch planning. The Liquid Waste Organization (LWO) plans to formulate Sludge Batch 6 (SB6) with about one half of the sludge slurry in Tank 12 and one half of the sludge slurry in Tank 4. LWO identified aluminum dissolution as a method to mitigate the effect of having about 50% more solids in High Level Waste (HLW) sludge than previously planned. Previous aluminum dissolution performed in a HLW tank in 1982 was performed at approximately 85 C for 5 days and dissolved nearly 80% of the aluminum in the sludge slurry. In 2008, LWO successfully dissolved 64% of the aluminum at approximately 60 C in 46 days with minimal tank modifications and using only slurry pumps as a heat source. This report establishes the technical basis and flowsheet for performing an aluminum removal process in Tank 51 for SB6 that incorporates the lessons learned from previous aluminum dissolution evolutions. For SB6, aluminum dissolution process temperature will be held at a minimum of 65 C for at least 24 days, but as long as practical or until as much as 80% of the aluminum is dissolved. As planned, an aluminum removal process can reduce the aluminum in SB6 from about 84,500 kg to as little as 17,900 kg with a corresponding reduction of total insoluble solids in the batch from 246,000 kg to 131,000 kg. The extent of the reduction may be limited by the time available to maintain Tank 51 at dissolution temperature. The range of dissolution in four weeks based on the known variability in dissolution kinetics can range from 44 to more than 80%. At 44% of the aluminum dissolved, the mass reduction is approximately 1/2 of the mass noted above, i.e., 33,300 kg of aluminum instead of 66,600 kg. Planning to reach 80% of the aluminum dissolved should allow a maximum of 81 days for dissolution and reduce the allowance if test data shows faster kinetics. 47,800 kg of the dissolved aluminum will be stored in Tank 8 and 21,000 kg will be stored in saltcake via evaporation. Up to 77% of the total aluminum planned for SB6 may be removed via aluminum dissolution. Storage of the aluminum-laden supernate in Tank 8 will require routine evaluation of the free hydroxide concentration in order to maintain aluminum in solution. Periodic evaluation will be established on concurrent frequency with corrosion program samples as previously established for aluminum-laden supernate from SB5 that is stored in Tank 11.

  1. Beryllium Adsorption at Transition Aluminas: Implications for Environmental Science and Oxidation of Aluminum Alloys

    SciTech Connect (OSTI)

    Sergey N. Rashkeev; Michael V. Glazoff

    2010-08-01

    It is demonstrated that?gamma- and?eta- aluminas (transition Al2O3 polytypes with defect spinel structure) can effectively capture beryllium atoms. Although the bulk crystal structures of these two oxides are characterized only by slight differences in cation vacancy distributions, the interaction of Be with the two polytypes are different. For gamma- Al2O3, the Be adsorption energy is high (~ 5 eV per atom), and all Be atoms are captured and trapped at the surface - all attempts to move Be in the subsurface region result in its expulsion back to the surface. On the other hand, for ?eta- alumina Be atoms can be captured both at the surface and in octahedrally-coordinated subsurface cation vacancies. This result implies that both alumina oxides could be successfully used for Be capture out of wastewater streams related to industrial processes of aluminum and alumina production. Also, the surface adsorption mechanism of Be at?gamma- Al2O3 explains why very small additions of Be (of the order of several ppm) to Al-Mg and Al-Mg-Si casting and wrought alloys prevent run-away oxidation of these materials in molten state, as well as ingot cracking. We also discuss possibilities to use other additives (e.g., Ca and Sr) yielding the same protective effect for aluminum alloys but which are less toxic than beryllium.

  2. Dimensionally stable metallic hydride composition

    DOE Patents [OSTI]

    Heung, Leung K. (Aiken, SC)

    1994-01-01

    A stable, metallic hydride composition and a process for making such a composition. The composition comprises a uniformly blended mixture of a metal hydride, kieselguhr, and a ballast metal, all in the form of particles. The composition is made by subjecting a metal hydride to one or more hydrogen absorption/desorption cycles to disintegrate the hydride particles to less than approximately 100 microns in size. The particles are partly oxidized, then blended with the ballast metal and the kieselguhr to form a uniform mixture. The mixture is compressed into pellets and calcined. Preferably, the mixture includes approximately 10 vol. % or more kieselguhr and approximately 50 vol. % or more ballast. Metal hydrides that can be used in the composition include Zr, Ti, V, Nb, Pd, as well as binary, tertiary, and more complex alloys of La, Al, Cu, Ti, Co, Ni, Fe, Zr, Mg, Ca, Mn, and mixtures and other combinations thereof. Ballast metals include Al, Cu and Ni.

  3. Process of electrolysis and fractional crystallization for aluminum purification

    DOE Patents [OSTI]

    Dawless, R.K.; Bowman, K.A.; Mazgaj, R.M.; Cochran, C.N.

    1983-10-25

    A method is described for purifying aluminum that contains impurities, the method including the step of introducing such aluminum containing impurities to a charging and melting chamber located in an electrolytic cell of the type having a porous diaphragm permeable by the electrolyte of the cell and impermeable to molten aluminum. The method includes further the steps of supplying impure aluminum from the chamber to the anode area of the cell and electrolytically transferring aluminum from the anode area to the cathode through the diaphragm while leaving impurities in the anode area, thereby purifying the aluminum introduced into the chamber. The method includes the further steps of collecting the purified aluminum at the cathode, and lowering the level of impurities concentrated in the anode area by subjecting molten aluminum and impurities in said chamber to a fractional crystallization treatment wherein eutectic-type impurities crystallize and precipitate out of the aluminum. The eutectic impurities that have crystallized are physically removed from the chamber. The aluminum in the chamber is now suited for further purification as provided in the above step of electrolytically transferring aluminum through the diaphragm. 2 figs.

  4. Production of sodium-22 from proton irradiated aluminum

    DOE Patents [OSTI]

    Taylor, Wayne A. (Los Alamos, NM); Heaton, Richard C. (Los Alamos, NM); Jamriska, David J. (Los Alamos, NM)

    1996-01-01

    A process for selective separation of sodium-22 from a proton irradiated minum target including dissolving a proton irradiated aluminum target in hydrochloric acid to form a first solution including aluminum ions and sodium ions, separating a portion of the aluminum ions from the first solution by crystallization of an aluminum salt, contacting the remaining first solution with an anion exchange resin whereby ions selected from the group consisting of iron and copper are selectively absorbed by the anion exchange resin while aluminum ions and sodium ions remain in solution, contacting the solution with an cation exchange resin whereby aluminum ions and sodium ions are adsorbed by the cation exchange resin, and, contacting the cation exchange resin with an acid solution capable of selectively separating the adsorbed sodium ions from the cation exchange resin while aluminum ions remain adsorbed on the cation exchange resin is disclosed.

  5. Issues for conversion coating of aluminum alloys with hydrotalcite

    SciTech Connect (OSTI)

    Drewien, C.A.; Buchheit, R.G.

    1993-12-01

    Hydrotalcite coatings on aluminum alloys are being developed for corrosion protection of aluminum in aggressive saline environments. Coating bath composition, surface pretreatment, and alloying elements in aluminum all influence the performance of these coatings during salt spray testing. The coating bath, comprised of lithium carbonate, requires aging by dissolution of aluminum into the bath in order to grow corrosion resistant coatings. Coatings formed in non- aged baths do not perform well in salt spray testing. The alloying elements in aluminum alloys, especially copper, influence the coating growth and formation leading to thin coatings. The effect of the alloy elements is to limit the supply of aluminum to the coating/electrolyte interface and hinder growth of hydrotalcite upon aluminum alloys.

  6. Microstructural Development in Al-Si Powder During Rapid Solidification

    SciTech Connect (OSTI)

    Amber Lynn Genau

    2004-12-19

    Powder metallurgy has become an increasingly important form of metal processing because of its ability to produce materials with superior mechanical properties. These properties are due in part to the unique and often desirable microstructures which arise as a result of the extreme levels of undercooling achieved, especially in the finest size powder, and the subsequent rapid solidification which occurs. A better understanding of the fundamental processes of nucleation and growth is required to further exploit the potential of rapid solidification processing. Aluminum-silicon, an alloy of significant industrial importance, was chosen as a model for simple eutectic systems displaying an unfaceted/faceted interface and skewed coupled eutectic growth zone, Al-Si powder produced by high pressure gas atomization was studied to determine the relationship between microstructure and alloy composition as a function of powder size and atomization gas. Critical experimental measurements of hypereutectic (Si-rich) compositions were used to determine undercooling and interface velocity, based on the theoretical models which are available. Solidification conditions were analyzed as a function of particle diameter and distance from nucleation site. A revised microstructural map is proposed which allows the prediction of particle morphology based on temperature and composition. It is hoped that this work, by providing enhanced understanding of the processes which govern the development of the solidification morphology of gas atomized powder, will eventually allow for better control of processing conditions so that particle microstructures can be optimized for specific applications.

  7. Characterization of isotropic solids with nonlinear surface acoustic wave pulses Al. A. Kolomenskii and H. A. Schuessler

    E-Print Network [OSTI]

    Schuessler, Hans

    Characterization of isotropic solids with nonlinear surface acoustic wave pulses Al. A. Kolomenskii acoustic wave SAW pulses in two isotropic materials, polycrystalline aluminum and synthetic fused silica Studies of nonlinear properties of surface acoustic waves SAW's recently attracted substantial interest

  8. Methods of forming aluminum oxynitride-comprising bodies, including methods of forming a sheet of transparent armor

    DOE Patents [OSTI]

    Chu, Henry Shiu-Hung [Idaho Falls, ID; Lillo, Thomas Martin [Idaho Falls, ID

    2008-12-02

    The invention includes methods of forming an aluminum oxynitride-comprising body. For example, a mixture is formed which comprises A:B:C in a respective molar ratio in the range of 9:3.6-6.2:0.1-1.1, where "A" is Al.sub.2O.sub.3, "B" is AlN, and "C" is a total of one or more of B.sub.2O.sub.3, SiO.sub.2, Si--Al--O--N, and TiO.sub.2. The mixture is sintered at a temperature of at least 1,600.degree. C. at a pressure of no greater than 500 psia effective to form an aluminum oxynitride-comprising body which is at least internally transparent and has at least 99% maximum theoretical density.

  9. Process for production of an aluminum hydride compound

    SciTech Connect (OSTI)

    Allen, Nathan Tait; Butterick, III, Robert; Chin, Arthur Achhing; Miller, Dean Michael; Molzahn, David Craig

    2013-08-06

    A compound of formula M(AlH.sub.3OR.sup.1).sub.y, wherein R.sup.1 is phenyl substituted by at least one of: (i) an alkoxy group having from one to six carbon atoms; and (ii) an alkyl group having from three to twelve carbon atoms; wherein M is an alkali metal, Be or Mg; and y is one or two.

  10. Transmissive metallic contact for amorphous silicon solar cells

    DOE Patents [OSTI]

    Madan, A.

    1984-11-29

    A transmissive metallic contact for amorphous silicon semiconductors includes a thin layer of metal, such as aluminum or other low work function metal, coated on the amorphous silicon with an antireflective layer coated on the metal. A transparent substrate, such as glass, is positioned on the light reflective layer. The metallic layer is preferably thin enough to transmit at least 50% of light incident thereon, yet thick enough to conduct electricity. The antireflection layer is preferably a transparent material that has a refractive index in the range of 1.8 to 2.2 and is approximately 550A to 600A thick.

  11. A New Environmentally Friendly AL/ZR-Based Clay Stabilizer 

    E-Print Network [OSTI]

    El-Monier, Ilham Abdallah

    2013-01-18

    tests showed that this new chemical was effective, and unlike previous Al-based and Zr-based stabilizers (hydroxy aluminum and zirconium oxychloride solutions), it did not dissolve in acids and worked very well up to 300oF. Stabilizer A proved...

  12. Effects of plastic constraint on the cyclic and static fatigue behavior of metal/ceramic layered structures

    E-Print Network [OSTI]

    Ritchie, Robert

    Effects of plastic constraint on the cyclic and static fatigue behavior of metal/ceramic layered of metal/ceramic layered structures is examined under cyclic and static loading conditions. Crack-crack growth; Stress-corrosion cracking; Plastic constraint; Alumina; Aluminum 1. Introduction Metal/ceramic

  13. Aluminum-doped Zinc Oxide Nanoink

    Energy Innovation Portal (Marketing Summaries) [EERE]

    2014-08-15

    Scientists at Berkeley Lab have developed a method for fabricating conductive aluminum-doped zinc oxide (AZO) nanocrystals that provide a lower cost, less toxic, earth-abundant alternative to the widely used transparent conductive oxide (TCO) indium tin oxide while offering comparable optical and electronic properties. TCOs are used in devices such as flat screen displays, photovoltaic cells, photochromic windows, chemical sensors, and biosensors....

  14. Experimental superplastic characterization of advanced aluminum alloys 

    E-Print Network [OSTI]

    Kopp, Christopher Carl

    1991-01-01

    categories. The first category is experimental SPF testing procedures at a constant crosshead velocity without an applied hydrostatic pressure, where SPF test data does not accurately measure the superplastic . properties of the alloy under study... recrystallization and cavitation in the alloy. This research involves the design and development of a test system to characterize the SPF properties of advanced aluminum alloys. The system in this study is constructed around an Instron testing machine, high...

  15. On the dissolution of iridium by aluminum.

    SciTech Connect (OSTI)

    Hewson, John C.

    2009-08-01

    The potential for liquid aluminum to dissolve an iridium solid is examined. Substantial uncertainties exist in material properties, and the available data for the iridium solubility and iridium diffusivity are discussed. The dissolution rate is expressed in terms of the regression velocity of the solid iridium when exposed to the solvent (aluminum). The temperature has the strongest influence in the dissolution rate. This dependence comes primarily from the solubility of iridium in aluminum and secondarily from the temperature dependence of the diffusion coefficient. This dissolution mass flux is geometry dependent and results are provided for simplified geometries at constant temperatures. For situations where there is negligible convective flow, simple time-dependent diffusion solutions are provided. Correlations for mass transfer are also given for natural convection and forced convection. These estimates suggest that dissolution of iridium can be significant for temperatures well below the melting temperature of iridium, but the uncertainties in actual rates are large because of uncertainties in the physical parameters and in the details of the relevant geometries.

  16. Combustion of Shock-Dispersed Flake Aluminum - High-Speed Visualization

    SciTech Connect (OSTI)

    Neuwald, P; Reichenbach, H; Kuhl, A

    2006-06-19

    Charges of 0.5 g PETN were used to disperse 1 g of flake aluminum in a rectangular test chamber of 4 liter inner volume and inner dimensions of approximately 10 cm x 10 cm x 40 cm. The subsequent combustion of the flake aluminum with the ambient air in the chamber gave rise to a highly luminous flame. The evolution of the luminous region was studied by means of high-speed cinematography. The high-speed camera is responsive to a broad spectral range in the visible and near infra-red. For a number of tests this response range was narrowed down by means of a band-pass filter with a center wavelength of 488 nm and a half-width of 23 nm. The corresponding images were expected to have a stronger temperature dependence than images obtained without the filter, thus providing better capability to highlight hot-spots. Emission in the range of the pass-band of the filter can be due to continuous thermal radiation from hot Al and Al{sub 2}O{sub 3} particles or to molecular band emission from gaseous AlO. A time-resolving spectrometer was improvised to inspect this topic. The results suggest that AlO emission occurs, but that the continuous spectrum is the dominating effect in our experiments.

  17. Method of bonding metals to ceramics

    DOE Patents [OSTI]

    Maroni, V.A.

    1991-04-23

    A ceramic or glass having a thin layer of silver, gold or alloys thereof at the surface thereof is disclosed. A first metal is bonded to the thin layer and a second metal is bonded to the first metal. The first metal is selected from the class consisting of In, Ga, Sn, Bi, Zn, Cd, Pb, Tl and alloys thereof, and the second metal is selected from the class consisting of Cu, Al, Pb, Au and alloys thereof. 3 figures.

  18. Method of bonding metals to ceramics

    DOE Patents [OSTI]

    Maroni, Victor A. (Naperville, IL)

    1991-01-01

    A ceramic or glass having a thin layer of silver, gold or alloys thereof at the surface thereof. A first metal is bonded to the thin layer and a second metal is bonded to the first metal. The first metal is selected from the class consisting of In, Ga, Sn, Bi, Zn, Cd, Pb, Tl and alloys thereof, and the second metal is selected from the class consisting of Cu, Al, Pb, An and alloys thereof.

  19. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS in a novel way to observe the behavior of electrons during technologically important chemical reactions in metal oxide electrocatalysts. What they learned has upended...

  20. Metal binding in an aluminum based metal-organic framework for carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid you notHeatMaRIEdioxide capture | Center for Gas SeparationsRelevant to

  1. Method For Making Electronic Circuits Having Nial And Ni3al Substrates

    DOE Patents [OSTI]

    Deevi, Seetharama C. (Midlothian, VA); Sikka, Vinod K. (Oak Ridge, TN)

    2001-01-30

    A method for making electronic circuit component having improved mechanical properties and thermal conductivity comprises steps of providing NiAl and/or Ni.sub.3 Al, and forming an alumina layer thereupon prior to applying the conductive elements. Additional layers of copper-aluminum alloy or copper further improve mechanical strength and thermal conductivity.

  2. Metal aminoboranes

    DOE Patents [OSTI]

    Burrell, Anthony K.; Davis, Benjamin J.; Thorn, David L.; Gordon, John C.; Baker, R. Thomas; Semelsberger, Troy Allen; Tumas, William; Diyabalanage, Himashinie Vichalya Kaviraj; Shrestha, Roshan P.

    2010-05-11

    Metal aminoboranes of the formula M(NH.sub.2BH.sub.3).sub.n have been synthesized. Metal aminoboranes are hydrogen storage materials. Metal aminoboranes are also precursors for synthesizing other metal aminoboranes. Metal aminoboranes can be dehydrogenated to form hydrogen and a reaction product. The reaction product can react with hydrogen to form a hydrogen storage material. Metal aminoboranes can be included in a kit.

  3. Aluminum oxyhydroxide based separator/electrolyte and battery system, and a method making the same

    DOE Patents [OSTI]

    Gerald, II, Rex E. (Brookfield, IL); Klingler, Robert J. (Glenview, IL); Rathke, Jerome W. (Homer Glen, IL)

    2011-03-08

    The instant invention relates a solid-state electrochemical cell and a novel separator/electrolyte incorporated therein. A preferred embodiment of the invented electrochemical cell generally comprises a unique metal oxyhydroxide based (i.e. AlOOH) separator/electrolyte membrane sandwiched between a first electrode and a second electrode. A preferred novel separator/electrolyte comprises a nanoparticulate metal oxyhydroxide, preferably AlOOH and a salt which are mixed and then pressed together to form a monolithic metal oxyhydroxide-salt membrane.

  4. Amorphous silicon enhanced metal-insulator-semiconductor contacts for silicon solar cells

    SciTech Connect (OSTI)

    Bullock, J. Cuevas, A.; Yan, D.; Demaurex, B.; Hessler-Wyser, A.; De Wolf, S.

    2014-10-28

    Carrier recombination at the metal-semiconductor contacts has become a significant obstacle to the further advancement of high-efficiency diffused-junction silicon solar cells. This paper provides the proof-of-concept of a procedure to reduce contact recombination by means of enhanced metal-insulator-semiconductor (MIS) structures. Lightly diffused n{sup +} and p{sup +} surfaces are passivated with SiO{sub 2}/a-Si:H and Al{sub 2}O{sub 3}/a-Si:H stacks, respectively, before the MIS contacts are formed by a thermally activated alloying process between the a-Si:H layer and an overlying aluminum film. Transmission/scanning transmission electron microscopy (TEM/STEM) and energy dispersive x-ray spectroscopy are used to ascertain the nature of the alloy. Idealized solar cell simulations reveal that MIS(n{sup +}) contacts, with SiO{sub 2} thicknesses of ?1.55?nm, achieve the best carrier-selectivity producing a contact resistivity ?{sub c} of ?3 m? cm{sup 2} and a recombination current density J{sub 0c} of ?40 fA/cm{sup 2}. These characteristics are shown to be stable at temperatures up to 350?°C. The MIS(p{sup +}) contacts fail to achieve equivalent results both in terms of thermal stability and contact characteristics but may still offer advantages over directly metallized contacts in terms of manufacturing simplicity.

  5. Fracture of welded aluminum thin-walled structures

    E-Print Network [OSTI]

    Zheng, Li, Ph. D. Massachusetts Institute of Technology

    2006-01-01

    A comprehensive methodology was developed in the thesis for damage prediction of welded aluminum thin-walled structures, which includes material modeling, calibration, numerical simulation and experimental verification. ...

  6. Energy and Environmental Profile of the Aluminum Industry

    SciTech Connect (OSTI)

    Margolis, Nancy

    1997-07-01

    This detailed report (PDF 2.5 MB) benchmarks the energy and environmental characteristics of the key technologies used in the major processes of the aluminum industry.

  7. Aluminum-stabilized Nb/sub 3/Sn superconductor

    DOE Patents [OSTI]

    Scanlan, R.M.

    1984-02-10

    This patent discloses an aluminum-stabilized Nb/sub 3/Sn superconductor and process for producing same, utilizing ultrapure aluminum. Ductile components are co-drawn with aluminum to produce a conductor suitable for winding magnets. After winding, the conductor is heated to convert it to the brittle Nb/sub 3/Sn superconductor phase, using a temperature high enough to perform the transformation but still below the melting point of the aluminum. This results in reaction of substantially all of the niobium, while providing stabilization and react-in-place features which are beneficial in the fabrication of magnets utilizing superconducting materials.

  8. Five Ways Aluminum Foil Is Advancing Science | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    SLAC National Accelerator Laboratory uses massive quantities of aluminum foil to perform "bake out" of their equipment. In a typical bake out, the equipment is blanketed in foil,...

  9. Aluminum-stabilized Nb[sub 3]Sn superconductor

    DOE Patents [OSTI]

    Scanlan, R.M.

    1988-05-10

    Disclosed are an aluminum-stabilized Nb[sub 3]Sn superconductor and process for producing same, utilizing ultrapure aluminum. Ductile components are co-drawn with aluminum to produce a conductor suitable for winding magnets. After winding, the conductor is heated to convert it to the brittle Nb[sub 3]Sn superconductor phase, using a temperature high enough to perform the transformation but still below the melting point of the aluminum. This results in reaction of substantially all of the niobium, while providing stabilization and react-in-place features which are beneficial in the fabrication of magnets utilizing superconducting materials. 4 figs.

  10. Microsoft PowerPoint - Aluminum Concentrations in Storm Water...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    guarantee its technical correctness. Title: Solid and Dissolved Phase Aluminum in Storm Water Runoff on the Pajarito Plateau, Poster, Individual Permit for Storm Water, NPDES...

  11. MATHEMATICAL MODELING OF THE LITHIUM-ALUMINUM, IRON SULFIDE BATTERY

    E-Print Network [OSTI]

    Pollard, Richard

    2012-01-01

    and J. Newman, Proc. Syrup. Battery Design and Optimization,123, 1364 (1976). Symp, Battery Design and Optimization, S.~ALUMINUM, IRON SULFIDE BATTERY Contents ACKNOWLEDGEMENTS

  12. An aluminum resist substrate for microfabrication by LIGA.

    SciTech Connect (OSTI)

    Kelly, James J.; Boehme, Dale R.; Hauck, Cheryl A. (Lawrence Berkeley National Laboratory, Berkeley, CA); Yang, Chu-Yeu Peter; Hunter, Luke L.; Griffiths, Stewart K.; McLean, Dorrance E.; Aigeldinger, Georg; Hekmaty, Michelle A.; Hachman, John T.; Losey, Matthew W.; Skala, Dawn M.; Korellis, John S.; Friedmann, Thomas Aquinas (Sandia National Laboratories, Albuquerque, NM); Yang, Nancy Y. C.; Lu, Wei-Yang

    2005-04-01

    Resist substrates used in the LIGA process must provide high initial bond strength between the substrate and resist, little degradation of the bond strength during x-ray exposure, acceptable undercut rates during development, and a surface enabling good electrodeposition of metals. Additionally, they should produce little fluorescence radiation and give small secondary doses in bright regions of the resist at the substrate interface. To develop a new substrate satisfying all these requirements, we have investigated secondary resist doses due to electrons and fluorescence, resist adhesion before exposure, loss of fine features during extended development, and the nucleation and adhesion of electrodeposits for various substrate materials. The result of these studies is a new anodized aluminum substrate and accompanying methods for resist bonding and electrodeposition. We demonstrate successful use of this substrate through all process steps and establish its capabilities via the fabrication of isolated resist features down to 6 {micro}m, feature aspect ratios up to 280 and electroformed nickel structures at heights of 190 to 1400 {micro}m. The minimum mask absorber thickness required for this new substrate ranges from 7 to 15 {micro}m depending on the resist thickness.

  13. ALS Visitors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.TheoryTuesday, August 10, 20102016 NewsUsers' Executive Committee ALS Users'ALS

  14. Precipitation of aluminum nitride in a high strength maraging steel with low nitrogen content

    SciTech Connect (OSTI)

    Jeanmaire, G.; Dehmas, M.; Redjaïmia, A.; Puech, S.; Fribourg, G.

    2014-12-15

    In the present work, aluminum nitride (AlN) precipitation was investigated in a X23NiCoCrMoAl13-6-3 maraging steel with low nitrogen content (wt.% N = 5.5 ppm). A reliable and robust automatic method by scanning electron microscopy observations coupled with energy dispersive X-ray spectroscopy was developed for the quantification of AlN precipitates. The first stage was to identify the solvus temperature and to develop a heat treatment able to dissolve the AlN precipitates. The experimental determination of equilibrium conditions and solvus temperature show good agreement with ThermoCalc® simulation. Then, from this AlN-free state, the cooling rate, isothermal holding time and temperature were the subject of an intensive investigation in the austenite region of this maraging steel. In spite of the high temperatures used during heat treatments, the growth kinetic of the largest AlN precipitates (> 1 ?m) is slow. The cooling rate has a major effect on the size and the number density of AlN due to a higher driving force for nucleation at low temperatures. At last, quenching prior to isothermal annealing at high temperatures leads to fine and dense AlN precipitation, resulting from the martensite to austenite transformation. Experimental results will be discussed and compared with kinetic data obtained with the mobility database MobFe2 implemented in Dictra® software. - Highlights: • Slow dissolution kinetic of AlN precipitates due to both their large size and small chemical driving force • Significant effects of cooling rate prior isothermal heat treatment, holding time and temperature on AlN precipitation • Size of AlN precipitates can be reduced by quenching prior isothermal holding. • Fine precipitation of AlN related to the ? ? ? transformation.

  15. A plane stress anisotropic plastic flow theory for orthotropic sheet metals

    E-Print Network [OSTI]

    Tong, Wei

    A plane stress anisotropic plastic flow theory for orthotropic sheet metals Wei Tong * Department for describing the anisotropic plastic flow of ortho- tropic polycrystalline aluminum sheet metals under plane anisotropic material functions to specify a flow potential, an associated flow rule of plastic strain rates

  16. Metalized Polyethylene Mulch to Reduce Incidence of Huanglongbing and Improve Growth of New Citrus Plantings

    E-Print Network [OSTI]

    Ma, Lena

    7.14 P Metalized Polyethylene Mulch to Reduce Incidence of Huanglongbing and Improve Growth of New and Education Center Polyethylene mulch was evaluated for deterring colonization by Asian citrus psyllid (ACP growth of young citrus. UV reflective low density polyethylene mulch metalized with aluminum, low density

  17. Lithium aluminum/iron sulfide battery having lithium aluminum and silicon as negative electrode

    DOE Patents [OSTI]

    Gilbert, Marian (Flossmoor, IL); Kaun, Thomas D. (New Lenox, IL)

    1984-01-01

    A method of making a negative electrode, the electrode made thereby and a secondary electrochemical cell using the electrode. Silicon powder is mixed with powdered electroactive material, such as the lithium-aluminum eutectic, to provide an improved electrode and cell.

  18. Nanotube Fabrication byNanotube Fabrication by Anodic Aluminum Oxide,Anodic Aluminum Oxide,

    E-Print Network [OSTI]

    Rubloff, Gary W.

    Self--Aligned Processing,Aligned Processing, and Atomic Layerand Atomic Layerand Atomic Layerand Atomic Layer Deposition synthesis by atomic layer deposition (ALD) Significance Realizing nanotechnology benefits requires new combined anodic aluminum oxide (AAO) nanostructures with atomic layer deposition (ALD) to fabricate

  19. Ordered binary oxide films of V{sub 2}O{sub 3}(0001) on Al{sub 2}O{sub 3}

    SciTech Connect (OSTI)

    Guo, Q.; Kim, D.Y.; Street, S.C.; Goodman, D.W.

    1999-07-01

    Ordered binary oxide films of vanadium oxide have been prepared on an aluminum oxide film supported on Mo(110) under ultrahigh vacuum conditions and characterized by various surface analytical techniques. Auger electron spectroscopy, low energy electron diffraction, high-resolution electron loss spectroscopy, x-ray photoelectron spectroscopy and ion scattering spectroscopy indicate that the vanadia films grow epitaxially on the Al{sub 2}O{sub 3}/Mo(110) surface as V{sub 2}O{sub 3}(0001). The results of electronic structural measurements show an increase in the energy of the a{sub 1g} level in the 3{ital d} band at low temperatures, which is a possible explanation for the metal-to-insulator transition in V{sub 2}O{sub 3}. {copyright} {ital 1999 American Vacuum Society.}

  20. Economic and environmental evaluation of end-of-life aerospace aluminum options using optimization methods

    E-Print Network [OSTI]

    Chen, Emily, S.B. Massachusetts Institute of Technology

    2008-01-01

    The benefits of recycling have long been understood and the conspicuous energy savings of secondary aluminum production have caused aluminum recycling to increase. Obsolete aircraft are a valuable source of aluminum scrap ...

  1. MECHANICAL TEST RESULTS ON DIPOLE MODEL C-l 25 mm ALUMINUM COLLARS

    E-Print Network [OSTI]

    Peters, C.

    2010-01-01

    RESULTS ON DIPOLE MODEL C-1 25 mm ALUMINUM COLLARS C. PetersRESULTS ON DIPOLE MODEL C-I 25 mm ALUMINUM COLLARS· CraigON DIPOLE MODEL C-I 25 mm ALUMINUM COLLARS Craig Peters

  2. 1999 PhotoDisc, Inc. Miraculous metal. Thin sheets of

    E-Print Network [OSTI]

    Adams, Philip W.

    they are chilled to low temperatures. But the 1 November PRL describes a case where superconductivity can arise on the sample's history--like ice that melts at one temperature on warming and then freezes at a different temperature on cooling. These strange properties were observed in thin films of aluminum, a metal whose

  3. Polymerization of phenylacetylene by triethyl aluminum and titanium tetraethoxide

    SciTech Connect (OSTI)

    Chiang, A.C. (Pitney Bowes, Inc., Danbury, CT); Waters, P.F.; Aldridge, M.H.

    1982-07-01

    The polymerization of phenylacetylene to polyphenylacetylene was accomplished with the combined catalysts triethyl aluminum and titanium tetraethoxide. The progress of the reaction was monitored by gas chromatography. The parameters included temperature (-80, 25, 140/sup 0/C), solvent (benzene, chlorobenzene, toluene, cyclohexane, and nitrobenzene), mole ratio of catalysts (Al/Ti; 1.5, 3.0, 4.5, 6.0, and 9.0), aging times of catalysts (2, 10, and 40 min), and order of addition of reagents. Derivatives of polyphenylacetylene were obtained by the acylation of polyphenylacetylene with p-nitrobenzoyl chloride, the sulfonation of polyphenylacetylene with benzenesulfonyl chloride, and the formation of polyphenylacetylene complexes with complexing agents such as bromine, iodine, iodine chloride, boron trifluoride, and ferric chloride. A new phenylacetylene-acetylene product mixture was produced by the polymerization of phenylacetylene and acetylene at 25 and -80/sup 0/C. The electrical conductivity of polyphenylacetylene and its derivatives is in the range of 10/sup -10/ to 10/sup -3/ ..cap omega../sup -1/ cm/sup -1/.

  4. The potential pyrophoricity of BMI-SPEC and aluminum plate spent fuels retrieved from underwater storage

    SciTech Connect (OSTI)

    Ebner, M.A.

    1996-08-01

    Physical/chemical factors in U metal and hydride combustion, particularly pyrophoricity in ambient environment, were evaluated for BMI-SPEC and UAl{sub x} plate fuels. Some metal fuels may be highly reactive (spontaneously igniting in air) due to high specific surface area, high decay heat, or a high U hydride content from corrosion during underwater storage. However, for the BMI-SPEC and the aluminum plate fuels, this reactivity is too low to present a realistic threat of uncontrolled spontaneous combustion at ambient conditions. While residual U hydride is expected in these corroded fuels, the hydride levels are expected to be too low and the configuration too unfavorable to ignite the fuel meat when the fuels are retrieved from the basin and dried. Furthermore the composition and microstructure of the UAl{sub x} fuels further mitigate that risk.

  5. Free-standing Al[subscript x]Ga[subscript 1?x]As heterostructures by gas-phase etching of germanium

    E-Print Network [OSTI]

    Cole, Garrett D.

    We outline a facile fabrication technique for the realization of free-standing Al[subscript x]Ga[subscript 1?x]As heterostructures of arbitrary aluminum content. Utilizing xenon difluoride (XeF[subscript 2]) we rapidly and ...

  6. MATHEMATICAL MODELING OF THE LITHIUM-ALUMINUM, IRON SULFIDE BATTERY. I. GALVONOSTATIC DISCHARGE BEHAVIOR

    E-Print Network [OSTI]

    Pollard, Richard

    2012-01-01

    composition profiles in lithium/sulfur battery analogues hasTHE LITHIUM-ALUMINUM, IRON SULFIDE BATTERY. I. GALVONOSTATICthe Lithium-Aluminum, Iron Sulfide Battery I. Galvanostatic

  7. Surface Preparation of Gallium Nitride for Atomic Layer Deposition of Aluminum Oxide /

    E-Print Network [OSTI]

    Kerr, Amanda J.

    2014-01-01

    Nitride for Atomic Layer Deposition of Aluminum Oxide AForce Microscopy Atomic Layer Deposition Capacitance-VoltageSurfaces for Atomic Layer Deposition of Aluminum Oxide” x

  8. Characteristics of Aluminum Biosorption by Sargassum fluitans Biomass

    E-Print Network [OSTI]

    Volesky, Bohumil

    Characteristics of Aluminum Biosorption by Sargassum fluitans Biomass Hak Sung Lee1, * and Bohumil3A 2B2, Canada Abstract: Biomass of nonliving brown seaweed Sargassum fluitans pretreated.5. There are indications that the biomass hydroxyl groups were involved in sequestering the aluminum in the form

  9. Computer-assisted Rheo-forging Processing of A356 Aluminum Alloys

    SciTech Connect (OSTI)

    Kim, H. H. [Department of Mechanical and Precision Engineering, Pusan National University, Busan 609-735 (Korea, Republic of); Kang, C. G. [School of Mechanical Engineering, Pusan National University, Busan 609-735 (Korea, Republic of)

    2010-06-15

    Die casting process has been used widely for complex automotive products such as the knuckle, arm and etc. Generally, a part fabricated by casting has limited strength due to manufacturing defects by origin such as the dendrite structure and segregation. As an attempt to offer a solution to these problems, forging has been used as an alternative process. However, the forging process provides limited formability for complex shape products. Rheo-forging of metal offers not only superior mechanical strength but also requires significantly lower machine loads than solid forming processes. In order to produce semi-solid materials of the desired microstructure, a stirring process is applied during solidification of A356 aluminum molten state. This paper presents the results of an A356 aluminum alloy sample, which were obtained by experiment and by simulation using DEFORM 3D V6.1. Samples of metal parts were subsequently fabricated by using hydraulic press machinery. In order to compare the influence of loading method, two types of samples were fabricated: (1) samples fabricated under direct loading die sets (2) those fabricated under indirect loading die sets. The formability and defects, which were predicted by FEM simulation, were similar to those of samples used in practice.

  10. Asymmetric Yield Function Based on the Stress Invariants for Pressure Sensitive Metals

    SciTech Connect (OSTI)

    Jeong Wahn Yoon; Yanshan Lou; Jong Hun Yoon; Michael V. Glazoff

    2014-05-01

    A general asymmetric yield function is proposed with dependence on the stress invariants for pressure sensitive metals. The pressure sensitivity of the proposed yield function is consistent with the experimental result of Spitzig and Richmond (1984) for steel and aluminum alloys while the asymmetry of the third invariant is preserved to model strength differential (SD) effect of pressure insensitive materials. The proposed yield function is transformed in the space of the stress triaxaility, the von Mises stress and the normalized invariant to theoretically investigate the possible reason of the SD effect. The proposed plasticity model is further extended to characterize the anisotropic behavior of metals both in tension and compression. The extension of the yield function is realized by introducing two distinct fourth-order linear transformation tensors of the stress tensor for the second and third invariants, respectively. The extended yield function reasonably models the evolution of yield surfaces for a zirconium clock-rolled plate during in-plane and through-thickness compression reported by Plunkett et al. (2007). The extended yield function is also applied to describe the orthotropic behavior of a face-centered cubic metal of AA 2008-T4 and two hexagonal close-packed metals of high-purity-titanium and AZ31 magnesium alloy. The orthotropic behavior predicted by the generalized model is compared with experimental results of these metals. The comparison validates that the proposed yield function provides sufficient predictability on SD effect and anisotropic behavior both in tension and compression. When it is necessary to consider r-value anisotropy, the proposed function is efficient to be used with nonassociated flow plasticity by introducing a separate plastic potential for the consideration of r-values as shown in Stoughton & Yoon (2004, 2009).

  11. Superconducting structure with layers of niobium nitride and aluminum nitride

    DOE Patents [OSTI]

    Murduck, J.M.; Lepetre, Y.J.; Schuller, I.K.; Ketterson, J.B.

    1989-07-04

    A superconducting structure is formed by depositing alternate layers of aluminum nitride and niobium nitride on a substrate. Deposition methods include dc magnetron reactive sputtering, rf magnetron reactive sputtering, thin-film diffusion, chemical vapor deposition, and ion-beam deposition. Structures have been built with layers of niobium nitride and aluminum nitride having thicknesses in a range of 20 to 350 Angstroms. Best results have been achieved with films of niobium nitride deposited to a thickness of approximately 70 Angstroms and aluminum nitride deposited to a thickness of approximately 20 Angstroms. Such films of niobium nitride separated by a single layer of aluminum nitride are useful in forming Josephson junctions. Structures of 30 or more alternating layers of niobium nitride and aluminum nitride are useful when deposited on fixed substrates or flexible strips to form bulk superconductors for carrying electric current. They are also adaptable as voltage-controlled microwave energy sources. 8 figs.

  12. Superconducting structure with layers of niobium nitride and aluminum nitride

    DOE Patents [OSTI]

    Murduck, James M. (Lisle, IL); Lepetre, Yves J. (Lauris, FR); Schuller, Ivan K. (Woodridge, IL); Ketterson, John B. (Evanston, IL)

    1989-01-01

    A superconducting structure is formed by depositing alternate layers of aluminum nitride and niobium nitride on a substrate. Deposition methods include dc magnetron reactive sputtering, rf magnetron reactive sputtering, thin-film diffusion, chemical vapor deposition, and ion-beam deposition. Structures have been built with layers of niobium nitride and aluminum nitride having thicknesses in a range of 20 to 350 Angstroms. Best results have been achieved with films of niobium nitride deposited to a thickness of approximately 70 Angstroms and aluminum nitride deposited to a thickness of approximately 20 Angstroms. Such films of niobium nitride separated by a single layer of aluminum nitride are useful in forming Josephson junctions. Structures of 30 or more alternating layers of niobium nitride and aluminum nitride are useful when deposited on fixed substrates or flexible strips to form bulk superconductors for carrying electric current. They are also adaptable as voltage-controlled microwave energy sources.

  13. AL. I

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and Myers Co -VANaval Ordnance,:n5.5.8GE 1A L L'-AL.

  14. ALS Spectrum

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve4AJ01) (See Energy Level79AJ01)19^ U N I TALSALSSpectroscopyALS

  15. ALS Visitors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.TheoryTuesday, August 10, 20102016 NewsUsers' Executive Committee ALS Users'ALSQuick

  16. ALS Visitors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.TheoryTuesday, August 10, 20102016 NewsUsers' Executive Committee ALS

  17. Industry @ ALS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid you notHeat Pumps Heat Pumpsfacility doe logoInIndustry @ ALS

  18. Reviw Al

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988 1.996 2.003 1990-2016 East CoastReviw Al now ..

  19. Metal inks

    DOE Patents [OSTI]

    Ginley, David S; Curtis, Calvin J; Miedaner, Alex; van Hest, Marinus Franciscus Antonius Maria; Kaydanova, Tatiana

    2014-02-04

    Self-reducing metal inks and systems and methods for producing and using the same are disclosed. In an exemplary embodiment, a method may comprise selecting metal-organic (MO) precursor, selecting a reducing agent, and dissolving the MO precursor and the reducing agent in an organic solvent to produce a metal ink that remains in a liquid phase at room temperature. Metal inks, including self-reducing and fire-through metal inks, are also disclosed, as are various applications of the metal inks.

  20. REPORT ON QUALITATIVE VALIDATION EXPERIMENTS USING LITHIUM-ALUMINUM LAYERED DOUBLE-HYDROXIDES FOR THE REDUCTION OF ALUMINUM FROM THE WASTE TREATMENT PLANT FEEDSTOCK

    SciTech Connect (OSTI)

    HUBER HJ; DUNCAN JB; COOKE GA

    2010-05-11

    A process for removing aluminum from tank waste simulants by adding lithium and precipitating Li-Al-dihydroxide (Lithiumhydrotalcite, [LiAl{sub 2}(OH){sub 6}]{sup +}X{sup -}) has been verified. The tests involved a double-shell tank (DST) simulant and a single-shell tank (SST) simulant. In the case of the DST simulant, the product was the anticipated Li-hydrotalcite. For the SST simulant, the product formed was primarily Li-phosphate. However, adding excess Li to the solution did result in the formation of traces of Li-hydrotalcite. The Li-hydrotalcite from the DST supernate was an easily filterable solid. After four water washes the filter cake was a fluffy white material made of < 100 {micro}m particles made of smaller spheres. These spheres are agglomerates of {approx} 5 {micro}m diameter platelets with < 1 {micro}m thickness. Chemical and mineralogical analyses of the filtrate, filter cake, and wash waters indicate a removal of 90+ wt% of the dissolved Al for the DST simulant. For the SST simulant, the main competing reaction to the formation of lithium hydrotalcite appears to be the formation of lithium phosphate. In case of the DST simulant, phosphorus co-precipitated with the hydrotalcite. This would imply the added benefit of the removal of phosphorus along with aluminum in the pre-treatment part of the waste treatment and immobilization plant (WTP). For this endeavor to be successful, a serious effort toward process parameter optimization is necessary. Among the major issues to be addressed are the dependency of the reaction yield on the solution chemistry, as well as residence times, temperatures, and an understanding of particle growth.

  1. Diode laser welding of aluminum to steel

    SciTech Connect (OSTI)

    Santo, Loredana; Quadrini, Fabrizio; Trovalusci, Federica [University of Rome Tor Vergata, Department of Mechanical Engineering, Via del Politecnico 1, 00133 Rome (Italy)

    2011-05-04

    Laser welding of dissimilar materials was carried out by using a high power diode laser to join aluminum to steel in a butt-joint configuration. During testing, the laser scan rate was changed as well as the laser power: at low values of fluence (i.e. the ratio between laser power and scan rate), poor joining was observed; instead at high values of fluence, an excess in the material melting affected the joint integrity. Between these limiting values, a good aesthetics was obtained; further investigations were carried out by means of tensile tests and SEM analyses. Unfortunately, a brittle behavior was observed for all the joints and a maximum rupture stress about 40 MPa was measured. Apart from the formation of intermeltallic phases, poor mechanical performances also depended on the chosen joining configuration, particularly because of the thickness reduction of the seam in comparison with the base material.

  2. Nickel coated aluminum battery cell tabs

    DOE Patents [OSTI]

    Bucchi, Robert S.; Casoli, Daniel J.; Campbell, Kathleen M.; Nicotina, Joseph

    2014-07-29

    A battery cell tab is described. The battery cell tab is anodized on one end and has a metal coating on the other end. Battery cells and methods of making battery cell tabs are also described.

  3. Aluminum Stabilized NbTi Conductor Test Coil Design, Fabrication, and Test Results

    SciTech Connect (OSTI)

    Andreev, N.; Chlachidze, G.; Evbota, D.; Kashikhin, V.S.; Lamm, M.; Makarov, A.; Tartaglia, M.; Nakamoto, T.; Ogitsu, T.; Tanaka, K.; Yamamoto, A.; /KEK, Tsukuba

    2011-09-01

    A new generation of precision muon conversion experiments is planned at both Fermilab and KEK. These experiments will depend upon a complex set of solenoid magnets for the production, momentum selection and transport of a muon beam to a stopping target, and for tracking detector momentum analysis of candidate conversion electrons from the target. Baseline designs for the production and detector solenoids use NbTi cable that is heavily stabilized by an extruded high RRR aluminum jacket. A U.S.-Japan research collaboration has begun whose goal is to advance the development of optimized Al-NbTi conductors, gain experience with the technology of winding coils from this material, and test the conductor performance as modest length samples become available. For this purpose, a 'conductor test' solenoid with three coils was designed and built at Fermilab. A sample of the RIKEN Al-NbTi conductor from KEK was wound into a 'test' coil; this was sandwiched between two 'field' coils wound from doubled SSC cable, to increase the peak field on the RIKEN test coil. All three solenoid coils were epoxy impregnated, and utilized aluminum outer bandage rings to apply preload to the coils when cold. The design and fabrication details, and results of the magnet quench performance tests are presented and discussed.

  4. Method of bonding metals to ceramics and other materials

    DOE Patents [OSTI]

    Gruen, D.M.; Krauss, A.R.; DeWald, A.P.; Chienping Ju; Rigsbee, J.M.

    1993-01-05

    A composite and method of forming same wherein the composite has a non-metallic portion and an alloy portion wherein the alloy comprises an alkali metal and a metal which is an electrical conductor such as Cu, Ag, Al, Sn or Au and forms an alloy with the alkali metal. A cable of superconductors and composite is also disclosed.

  5. Silicone metalization

    DOE Patents [OSTI]

    Maghribi, Mariam N. (Livermore, CA); Krulevitch, Peter (Pleasanton, CA); Hamilton, Julie (Tracy, CA)

    2008-12-09

    A system for providing metal features on silicone comprising providing a silicone layer on a matrix and providing a metal layer on the silicone layer. An electronic apparatus can be produced by the system. The electronic apparatus comprises a silicone body and metal features on the silicone body that provide an electronic device.

  6. Effects of Soil Property and Soil Amendment on Weathering of Abraded Metallic Pb in Shooting Ranges

    E-Print Network [OSTI]

    Ma, Lena

    is not the metal but a metal oxide, hydroxide or salt (Pourbaix, 1966). Under these conditions the met- al becomes/or a porous film to partially separate the metal from solution (Pourbaix, 1966). In the case of Pb

  7. New Process for Grain Refinement of Aluminum. Final Report

    SciTech Connect (OSTI)

    Dr. Joseph A. Megy

    2000-09-22

    A new method of grain refining aluminum involving in-situ formation of boride nuclei in molten aluminum just prior to casting has been developed in the subject DOE program over the last thirty months by a team consisting of JDC, Inc., Alcoa Technical Center, GRAS, Inc., Touchstone Labs, and GKS Engineering Services. The Manufacturing process to make boron trichloride for grain refining is much simpler than preparing conventional grain refiners, with attendant environmental, capital, and energy savings. The manufacture of boride grain refining nuclei using the fy-Gem process avoids clusters, salt and oxide inclusions that cause quality problems in aluminum today.

  8. Process for strengthening aluminum based ceramics and material

    DOE Patents [OSTI]

    Moorhead, Arthur J. (Knoxville, TN); Kim, Hyoun-Ee (Seoul, KR)

    2000-01-01

    A process for strengthening aluminum based ceramics is provided. A gaseous atmosphere consisting essentially of silicon monoxide gas is formed by exposing a source of silicon to an atmosphere consisting essentially of hydrogen and a sufficient amount of water vapor. The aluminum based ceramic is exposed to the gaseous silicon monoxide atmosphere for a period of time and at a temperature sufficient to produce a continuous, stable silicon-containing film on the surface of the aluminum based ceramic that increases the strength of the ceramic.

  9. Microstructure characterization of the stir zone of submerged friction stir processed aluminum alloy 2219

    SciTech Connect (OSTI)

    Feng, Xiuli, E-mail: feng.97@osu.edu [Welding Engineering Program, Department of Materials Science and Engineering, The Ohio State University, Columbus, OH 43221 (United States); State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China); Liu, Huijie, E-mail: liuhj@hit.edu.cn [State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China); Lippold, John C., E-mail: lippold.1@osu.edu [Welding Engineering Program, Department of Materials Science and Engineering, The Ohio State University, Columbus, OH 43221 (United States)

    2013-08-15

    Aluminum alloy 2219-T6 was friction stir processed using a novel submerged processing technique to facilitate cooling. Processing was conducted at a constant tool traverse speed of 200 mm/min and spindle rotation speeds in the range from 600 to 800 rpm. The microstructural characteristics of the base metal and processed zone, including grain structure and precipitation behavior, were studied using optical microscopy (OM), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Microhardness maps were constructed on polished cross sections of as-processed samples. The effect of tool rotation speed on the microstructure and hardness of the stir zone was investigated. The average grain size of the stir zone was much smaller than that of the base metal, but the hardness was also lower due to the formation of equilibrium ? precipitates from the base metal ?? precipitates. Stir zone hardness was found to decrease with increasing rotation speed (heat input). The effect of processing conditions on strength (hardness) was rationalized based on the competition between grain refinement strengthening and softening due to precipitate overaging. - Highlights: • SZ grain size (? 1 ?m) is reduced by over one order of magnitude relative to the BM. • Hardness in the SZ is lower than that of the precipitation strengthened BM. • Metastable ?? in the base metal transforms to equilibrium ? in the stir zone. • Softening in the SZ results from a decrease of precipitation strengthening.

  10. Size Effect of SiC Particle on Microstructures and Mechanical Properties of SiCp/Al Composites

    E-Print Network [OSTI]

    Qin, Qinghua

    matrix composites reinforced with ceramic particles have some attractive properties such as high strengthCp/Al composites were fabricated using aluminum alloy ZL101 as the matrix material, and SiC particles a composite is stretched, most of external load transfers from soft Al matrix to hard SiCp reinforcement

  11. A second law analysis of thermoelastic damping in elementary metal-matrix composites 

    E-Print Network [OSTI]

    Bishop, Joseph Edward

    1991-01-01

    homogeneous aluminum and homogeneous graphite beam. . . . . . . , . . 50 Figure 13. Phase of the fluctuating temperature, 4, of BVP II as a function of position, for the composite AI-Gr-Al, for four different nondimensional frequencies, and for a thickness... ratio of r = 1. 52 Figure 14. Comparison of the phase of the tluctuating temperature, 4, of BVP II as a function of position for both a homogeneous aluminum and homogeneous graphite beam. . 53 Figure 15. The nyquist plot of the normalized fluctuating...

  12. (Data in thousand metric tons of silicon content unless otherwise noted) Domestic Production and Use: Estimated value of silicon alloys and metal produced in the United States in 2012

    E-Print Network [OSTI]

    and aluminum alloys and the chemical industry. The semiconductor and solar industries, which manufacture chips%; and other, 5%. Silicon metal: Brazil, 41%; South Africa, 20%; Canada, 12%; Australia, 9%; and other, 18 materials source for aluminum-silicon alloys--was projected to increase by 10% in 2012 compared

  13. High Temperature Oxidation Behavior of gamma-Ni+gamma'-Ni3Al Alloys and Coatings Modified with Pt and Reactive Elements

    SciTech Connect (OSTI)

    Nan Mu

    2007-12-01

    Materials for high-pressure turbine blades must be able to operate in the high-temperature gases (above 1000 C) emerging from the combustion chamber. Accordingly, the development of nickel-based superalloys has been constantly motivated by the need to have improved engine efficiency, reliability and service lifetime under the harsh conditions imposed by the turbine environment. However, the melting point of nickel (1455 C) provides a natural ceiling for the temperature capability of nickel-based superalloys. Thus, surface-engineered turbine components with modified diffusion coatings and overlay coatings are used. Theses coatings are capable of forming a compact and adherent oxide scale, which greatly impedes the further transport of reactants between the high-temperature gases and the underlying metal and thus reducing attack by the atmosphere. Typically, these coatings contain {beta}-NiAl as a principal constituent phase in order to have sufficient aluminum content to form an Al{sub 2}O{sub 3} scale at elevated temperatures. The drawbacks to the currently-used {beta}-based coatings, such as phase instabilities, associated stresses induced by such phase instabilities, and extensive coating/substrate interdiffusion, are major motivations in this study to seek next-generation coatings. The high-temperature oxidation resistance of novel Pt + Hf-modified {gamma}-Ni + {gamma}-Ni{sub 3}Al-based alloys and coatings were investigated in this study. Both early-stage and 4-days isothermal oxidation behavior of single-phase {gamma}-Ni and {gamma}{prime}-Ni{sub 3}Al alloys were assessed by examining the weight changes, oxide-scale structures, and elemental concentration profiles through the scales and subsurface alloy regions. It was found that Pt promotes Al{sub 2}O{sub 3} formation by suppressing the NiO growth on both {gamma}-Ni and {gamma}{prime}Ni{sub 3}Al single-phase alloys. This effect increases with increasing Pt content. Moreover, Pt exhibits this effect even at lower temperatures ({approx}970 C) in the very early stage of oxidation. It was also inferred that Pt enhances the diffusive flux of aluminum from the substrate to the scale/alloy interface. Relatively low levels of hafnium addition to Pt-free {gamma}{prime}-Ni{sub 3}Al increased the extent of external NiO formation due to non-protective HfO{sub 2} formation. Accordingly, this effect intensified with increasing Hf content from 0.2 to 0.5 at.%.

  14. An inverted cylindrical sputter magnetron as metal vapor supply for electron cyclotron resonance ion sources

    SciTech Connect (OSTI)

    Weichsel, T., E-mail: tim.weichsel@fep.fraunhofer.de; Hartung, U.; Kopte, T. [Fraunhofer Institute for Electron Beam and Plasma Technology, 01277 Dresden (Germany)] [Fraunhofer Institute for Electron Beam and Plasma Technology, 01277 Dresden (Germany); Zschornack, G. [Institute of Solid State Physics, Dresden University of Technology, 01062 Dresden, Germany and Helmholtz-Zentrum Dresden-Rossendorf e.V., Institute of Ion Beam Physics and Materials Research, Dresden (Germany)] [Institute of Solid State Physics, Dresden University of Technology, 01062 Dresden, Germany and Helmholtz-Zentrum Dresden-Rossendorf e.V., Institute of Ion Beam Physics and Materials Research, Dresden (Germany); Kreller, M.; Silze, A. [DREEBIT GmbH, 01900 Grossroehrsdorf (Germany)] [DREEBIT GmbH, 01900 Grossroehrsdorf (Germany)

    2014-05-15

    An inverted cylindrical sputter magnetron device has been developed. The magnetron is acting as a metal vapor supply for an electron cyclotron resonance (ECR) ion source. FEM simulation of magnetic flux density was used to ensure that there is no critical interaction between both magnetic fields of magnetron and ECR ion source. Spatially resolved double Langmuir probe and optical emission spectroscopy measurements show an increase in electron density by one order of magnitude from 1 × 10{sup 10} cm{sup ?3} to 1 × 10{sup 11} cm{sup ?3}, when the magnetron plasma is exposed to the magnetic mirror field of the ECR ion source. Electron density enhancement is also indicated by magnetron plasma emission photography with a CCD camera. Furthermore, photographs visualize the formation of a localized loss-cone - area, when the magnetron is operated at magnetic mirror field conditions. The inverted cylindrical magnetron supplies a metal atom load rate of R > 1 × 10{sup 18} atoms/s for aluminum, which meets the demand for the production of a milliampere Al{sup +} ion beam.

  15. Ultrafast laser induced periodic sub-wavelength aluminum surface structures and nanoparticles in air and liquids

    SciTech Connect (OSTI)

    Kuladeep, Rajamudili; Dar, Mudasir H.; Rao, D. Narayana, E-mail: dnrsp@uohyd.ac.in, E-mail: dnr-laserlab@yahoo.com [School of Physics, University of Hyderabad, Hyderabad 500046 (India); Deepak, K. L. N. [Department of Physics and Center for Research in Photonics, University of Ottawa, 150 Louis Pasteur, Ottawa K1N6N5, Ontario (Canada)

    2014-09-21

    In this communication, we demonstrate the generation of laser-induced periodic sub-wavelength surface structures (LIPSS) or ripples on a bulk aluminum (Al) and Al nanoparticles (NPs) by femtosecond (fs) laser direct writing technique. Laser irradiation was performed on Al surface at normal incidence in air and by immersing in ethanol (C?H?OH) and water (H?O) using linearly polarized Ti:sapphire fs laser pulses of ~110 fs pulse duration and ~800 nm wavelength. Field emission scanning electron microscope is utilized for imaging surface morphology of laser written structures and it reveals that the spatial periodicity as well as the surface morphology of the LIPSS depends on the surrounding dielectric medium and also on the various laser irradiation parameters. The observed LIPSS have been classified as low spatial frequency LIPSS which are perpendicularly oriented to the laser polarization with a periodicity from 460 to 620 nm and high spatial frequency LIPSS which spectacles a periodicity less than 100 nm with the orientation parallel to the polarization of the incident laser beam. Fabricated colloidal solutions, which contain the Al NPs, were characterized by UV-Vis absorption spectroscopy and transmission electron microscopy (TEM). TEM results reveal the formation of internal cavities in Al NPs both in ethanol and water. Formation mechanism of LIPSS and cavities inside the nanoparticles are discussed in detail.

  16. Filler metal alloy for welding cast nickel aluminide alloys

    DOE Patents [OSTI]

    Santella, Michael L. (Knoxville, TN); Sikka, Vinod K. (Oak Ridge, TN)

    1998-01-01

    A filler metal alloy used as a filler for welding east nickel aluminide alloys contains from about 15 to about 17 wt. % chromium, from about 4 to about 5 wt. % aluminum, equal to or less than about 1.5 wt. % molybdenum, from about 1 to about 4.5 wt. % zirconium, equal to or less than about 0.01 wt. % yttrium, equal to or less than about 0.01 wt. % boron and the balance nickel. The filler metal alloy is made by melting and casting techniques such as are melting the components of the filler metal alloy and east in copper chill molds.

  17. Filler metal alloy for welding cast nickel aluminide alloys

    DOE Patents [OSTI]

    Santella, M.L.; Sikka, V.K.

    1998-03-10

    A filler metal alloy used as a filler for welding cast nickel aluminide alloys contains from about 15 to about 17 wt. % chromium, from about 4 to about 5 wt. % aluminum, equal to or less than about 1.5 wt. % molybdenum, from about 1 to about 4.5 wt. % zirconium, equal to or less than about 0.01 wt. % yttrium, equal to or less than about 0.01 wt. % boron and the balance nickel. The filler metal alloy is made by melting and casting techniques such as are melting the components of the filler metal alloy and cast in copper chill molds. 3 figs.

  18. Primary aluminum production : climate policy, emissions and costs

    E-Print Network [OSTI]

    Harnisch, Jochen.; Sue Wing, Ian.; Jacoby, Henry D.; Prinn, Ronald G.

    Climate policy regarding perfluorocarbons (PFCs) may have a significant influence on investment decisions in the production of primary aluminum. This work demonstrates an integrated analysis of the effectiveness and likely ...

  19. Five Ways Aluminum Foil Is Advancing Science | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    practice for your x-ray laser Have you ever accidentally put aluminum foil in the microwave and turned it on? I imagine that is similar to experiments that researchers use to...

  20. Aluminum Surface Texturing by Means of Laser Interference Metallurgy...

    Office of Scientific and Technical Information (OSTI)

    laser interferometry produced by two beams of a pulsed Nd:YAG laser operating at 10Hz of frequency to clean aluminum surfaces, and meanwhile creating periodic and rough surface...

  1. New, More Efficient Technology for Remelting Aluminum Chips 

    E-Print Network [OSTI]

    Hosek, D.

    1994-01-01

    This project will introduce a new, more efficient technology for remelting the considerable volume of aluminum by 6.5% . Automated conveyors will transport chips from the machining operation to the new remelting operation for recycling. A reduction...

  2. Ames Lab 101: BAM (Boron-Aluminum-Magnesium)

    ScienceCinema (OSTI)

    Bruce Cook

    2013-06-05

    Materials scientist, Bruce Cook, discusses the super hard, low friction, and lubricious alloy know as BAM (Boron-Aluminum-Magnesium). BAM was discovered by Bruce Cook and his team a

  3. Evaluation of heat stress in an aluminum smelter 

    E-Print Network [OSTI]

    Rose, Stacy Rahkell

    1999-01-01

    of heat stress and heat strain was evaluated for the aluminum smelter workers at Alcoa, Rockdale Operations. Personal, environmental, and metabolic factors that contribute to heat-related illnesses were identified. The effectiveness of current...

  4. Consolidation of aluminum 6061 powder by equal channel angular extrusion 

    E-Print Network [OSTI]

    Pearson, John Montgomery

    1997-01-01

    Equal channel angular extrusion is a promising approach to obtaining full density in powder metallurgy applications. This method can impose large effective deformations through uniform shear strain. Aluminum alloy 6061 powder is used as a test...

  5. Aluminum Reactions and Problems in Municipal Solid Waste Landfills

    E-Print Network [OSTI]

    problematic for landfill operations by generating undesirable heat, liquid leachate, and gases reactions. Another source of water in a MSW landfill is leachate recirculation, which is not recommended: Solid wastes; Aluminum; Chemicals; Waste disposal; Landfills. Author keywords: Solid waste; Leachate

  6. The development of a preliminary correlation of data on oxide growth on 6061 aluminum under ANS thermal-hydraulic conditions

    SciTech Connect (OSTI)

    Pawel, R.E.; Yoder, G.L.; West, C.D.; Montgomery, B.H.

    1990-06-01

    The corrosion of aluminum alloy 6061 is being studied in a special test loop facility under the range of thermal-hydraulic conditions appropriate for fuel plate operation in the Advanced Neutron Source (ANS) reactor core. Experimental measurements describing the growth of the boehmite (Al{sub 2}O{sub 3}H{sub 2}O) films on the exposed aluminum surfaces are now available for a range of coolant conditions and heat fluxes, and these results have been analyzed to demonstrate the influence of several important experimental variables. A subset of our data base particularly appropriate to the ANS conditions presently anticipated was used to develop a preliminary correlation based on an empirical oxidation model.

  7. Hysteresis-free high rate reactive sputtering of niobium oxide, tantalum oxide, and aluminum oxide

    SciTech Connect (OSTI)

    Särhammar, Erik, E-mail: erik.sarhammar@angstrom.uu.se; Berg, Sören; Nyberg, Tomas [Department of Solid State Electronics, The Ångström Laboratory, Uppsala University, Box 534, SE-751 21 Uppsala (Sweden)

    2014-07-01

    This work reports on experimental studies of reactive sputtering from targets consisting of a metal and its oxide. The composition of the targets varied from pure metal to pure oxide of Al, Ta, and Nb. This combines features from both the metal target and oxide target in reactive sputtering. If a certain relation between the metal and oxide parts is chosen, it may be possible to obtain a high deposition rate, due to the metal part, and a hysteresis-free process, due to the oxide part. The aim of this work is to quantify the achievable boost in oxide deposition rate from a hysteresis-free process by using a target consisting of segments of a metal and its oxide. Such an increase has been previously demonstrated for Ti using a homogeneous substoichiometric target. The achievable gain in deposition rate depends on transformation mechanisms from oxide to suboxides due to preferential sputtering of oxygen. Such mechanisms are different for different materials and the achievable gain is therefore material dependent. For the investigated materials, the authors have demonstrated oxide deposition rates that are 1.5–10 times higher than what is possible from metal targets in compound mode. However, although the principle is demonstrated for oxides of Al, Ta, and Nb, a similar behavior is expected for most oxides.

  8. Continuous Severe Plastic Deformation Processing of Aluminum Alloys

    SciTech Connect (OSTI)

    Raghavan Srinivasan (PI); Prabir K. Chaudhury; Balakrishna Cherukuri; Qingyou Han; David Swenson; Percy Gros

    2006-06-30

    Metals with grain sizes smaller than 1-micrometer have received much attention in the past decade. These materials have been classified as ultra fine grain (UFG) materials (grain sizes in the range of 100 to 1000-nm) and nano-materials (grain size <100-nm) depending on the grain size. This report addresses the production of bulk UFG metals through the use of severe plastic deformation processing, and their subsequent use as stock material for further thermomechanical processing, such as forging. A number of severe plastic deformation (SPD) methods for producing bulk UFG metals have been developed since the early 1990s. The most promising of these processes for producing large size stock that is suitable for forging is the equal channel angular extrusion or pressing (ECAE/P) process. This process involves introducing large shear strain in the work-piece by pushing it through a die that consists of two channels with the same cross-sectional shape that meet at an angle to each other. Since the cross-sections of the two channels are the same, the extruded product can be re-inserted into the entrance channel and pushed again through the die. Repeated extrusion through the ECAE/P die accumulates sufficient strain to breakdown the microstructure and produce ultra fine grain size. It is well known that metals with very fine grain sizes (< 10-micrometer) have higher strain rate sensitivity and greater elongation to failure at elevated temperature, exhibiting superplastic behavior. However, this superplastic behavior is usually manifest at high temperature (> half the melting temperature on the absolute scale) and very low strain rates (< 0.0001/s). UFG metals have been shown to exhibit superplastic characteristics at lower temperature and higher strain rates, making this phenomenon more practical for manufacturing. This enables part unitization and forging more complex and net shape parts. Laboratory studies have shown that this is particularly true for UFG metals produced by SPD techniques. This combination of properties makes UFG metals produced by SPD very attractive as machining, forging or extrusion stock, both from the point of view of formability as well as energy and cost saving. However, prior to this work there had been no attempt to transfer these potential benefits observed in the laboratory scale to industrial shop floor. The primary reason for this was that the laboratory scale studies had been conducted to develop a scientific understanding of the processes that result in grain refinement during SPD. Samples that had been prepared in the laboratory scale were typically only about 10-mm diameter and 50-mm long (about 0.5-inch diameter and 2-inches long). The thrust of this project was three-fold: (i) to show that the ECAE/P process can be scaled up to produce long samples, i.e., a continuous severe plastic deformation (CSPD) process, (ii) show the process can be scaled up to produce large cross section samples that could be used as forging stock, and (iii) use the large cross-section samples to produce industrial size forgings and demonstrate the potential energy and cost savings that can be realized if SPD processed stock is adopted by the forging industry. Aluminum alloy AA-6061 was chosen to demonstrate the feasibility of the approach used. The CSPD process developed using the principles of chamber-less extrusion and drawing, and was demonstrated using rolling and wire drawing equipment that was available at Oak Ridge National Laboratory. In a parallel effort, ECAE/P dies were developed for producing 100-mm square cross section SPD billets for subsequent forging. This work was carried out at Intercontinental Manufacturing Co. (IMCO), Garland TX. Forging studies conducted with the ECAE/P billets showed that many of the potential benefits of using UFG material can be realized. In particular, the material yield can be increased, and the amount of material that is lost as scrap can be reduced by as much as 50%. Forging temperatures can also be reduced by over 150ºC, resulting in energy savings in the ope

  9. Switching Currents Limited by Single Phase Slips in One-Dimensional Superconducting Al Nanowires

    E-Print Network [OSTI]

    Finkelstein, Gleb

    Switching Currents Limited by Single Phase Slips in One-Dimensional Superconducting Al Nanowires received 10 January 2011; published 21 September 2011) An aluminum nanowire switches from superconducting to normal as the current is increased in an upsweep. The switching current (Is) averaged over upsweeps

  10. Effective hole extraction using MoO{sub x}-Al contact in perovskite CH{sub 3}NH{sub 3}PbI{sub 3} solar cells

    SciTech Connect (OSTI)

    Zhao, Yixin; Nardes, Alexandre M.; Zhu, Kai

    2014-05-26

    We report an 11.4%-efficient perovskite CH{sub 3}NH{sub 3}PbI{sub 3} solar cell using low-cost molybdenum oxide/aluminum (i.e., MoO{sub x}/Al) as an alternative top contact to replace noble/precious metals (e.g., Au or Ag) for extracting photogenerated holes. The device performance of perovskite solar cells using a MoO{sub x}/Al top contact is comparable to that of cells using the standard Ag top contact. Analysis of impedance spectroscopy measurements suggests that using 10-nm-thick MoO{sub x} and Al does not affect charge-recombination properties of perovskite solar cells. Using a thicker (20-nm) MoO{sub x} layer leads to a lower cell performance caused mainly by a reduced fill factor. Our results suggest that MoO{sub x}/Al is promising as a low-cost and effective hole-extraction contact for perovskite solar cells.

  11. Simulation of Turbulent Combustion Fields of Shock-Dispersed Aluminum Using the AMR Code

    SciTech Connect (OSTI)

    Kuhl, A L; Bell, J B; Beckner, V E; Khasainov, B

    2006-11-02

    We present a Model for simulating experiments of combustion in Shock-Dispersed-Fuel (SDF) explosions. The SDF charge consisted of a 0.5-g spherical PETN booster, surrounded by 1-g of fuel powder (flake Aluminum). Detonation of the booster charge creates a high-temperature, high-pressure source (PETN detonation products gases) that both disperses the fuel and heats it. Combustion ensues when the fuel mixes with air. The gas phase is governed by the gas-dynamic conservation laws, while the particle phase obeys the continuum mechanics laws for heterogeneous media. The two phases exchange mass, momentum and energy according to inter-phase interaction terms. The kinetics model used an empirical particle burn relation. The thermodynamic model considers the air, fuel and booster products to be of frozen composition, while the Al combustion products are assumed to be in equilibrium. The thermodynamic states were calculated by the Cheetah code; resulting state points were fit with analytic functions suitable for numerical simulations. Numerical simulations of combustion of an Aluminum SDF charge in a 6.4-liter chamber were performed. Computed pressure histories agree with measurements.

  12. Measurement of irradiation effects in precipitate hardened aluminum using nonlinear ultrasonic principles (in-situ)

    SciTech Connect (OSTI)

    Reinhardt, B. T.; Parks, D. A.; Tittmann, B. R. [Department of Engineering Science and Mechanics, Pennsylvania State University, State College, PA 16804 (United States)

    2012-05-17

    Currently nuclear power plants are reaching the end of their initial design life. Yet, in order to meet the energy demands, twenty year extensions have been granted to many nuclear reactor facilities. These extensions will be ending by the year 2035, leaving a large gap in the available energy supply. In order to extend the life of these facilities it will imperative to develop techniques capable detecting damage in the aging nuclear facilities. However, the high temperature and high neutron flux environment limits the materials available for use in the nuclear reactor. Because of this limitation little NDE based inspection has been implemented in high radiation environments. Yet recent developments in the understanding of Aluminum Nitride (AlN) piezoelectric sensors high temperature and radiation dependent behavior have opened the door for in-situ experimentation. An experiment was designed to monitor the propagation of an ultrasonic wave in a precipitate hardened aluminum specimen while being subjected to radiation at the Pennsylvania State Universities Breazeale Reactor. Measurements of harmonic generation were made up to 1.85x10{sup 18} fluence with significant spectral difference between the pre-irradiated state and the post irradiated state. The connection between micro-structural material changes and harmonic measurements are addressed.

  13. A quantitative determination of the conditions for hot cracking during welding for aluminum alloys 

    E-Print Network [OSTI]

    Steenbergen, James Everett

    1969-01-01

    REFERENCES ~ ~ ~ . ~ 12 23 23 46 55 56 VITA 58 vi LIST OP TABLES Table Page Properties of Aluminum Alloys Test Results for 6061-T6 Aluminum Test Results for 7075-T6 Aluminum Strain Data for 6061-T6 Aluminum Strain Data for 7075-T6 Aluminum 27...' These alloys were selected because of their usage in structural design applications and availability. Test specimens were machined from sheet stock in preparation for generation of the test data. The generation of the experimental test data for the aluminum...

  14. Metal pollution of river Msimbazi, Tanzania

    SciTech Connect (OSTI)

    Ak'habuhaya, J.; Lodenius, M. )

    1988-01-01

    The Misimbazi River in Dar es Salaam is polluted with industrial, urban and agricultural waste waters. A preliminary investigation on the extent of metal pollution (Hg, Cr, Cu, Zn, Fe, Ni, Cd, Mn, Al) was made from samples of sediments and biological indicators. The metal concentrations were in general low, but some of our results indicated industrial pollution.

  15. The formation of iron aluminides on aluminum surface by using a Q-switched Nd:YAG laser

    SciTech Connect (OSTI)

    Bidin, Noriah; Al-Wafi, Yusef A. [Advanced Photonic Science Institute, Faculty of Science, Universiti Teknologi Malaysia, Skudai, 81310, Johor (Malaysia)

    2014-03-05

    The formation and growth of Fe based aluminum diffusion layers at the Fe-Al interface have been investigated to improve the surface hardness. The diffusion of Fe into Al has been accomplished by focusing a Q-switched Nd:YAG laser on the modified surface. The variety of the layer depth is achieved based on the type of heating and quenching media. Microstructural characterization and mechanical properties of the modified surface were carried out via gas discharge spectrometer GDS, X-Ray diffraction (XRD), Scanning electron microscope (SEM), and Vickers Hardness tester. The results indicate that hardness at the interface of Fe-Al layer is increased. The optimum hardness achieved as 93 HV at corresponding critical energy density of 438 Jcm{sup ?2}.

  16. Energy Saving Melting and Revert Reduction Technology (E-SMARRT): Development of Surface Engineered Coating Systems for Aluminum Pressure Die Casting Dies: Towards a 'Smart' Die Coating

    SciTech Connect (OSTI)

    Dr. John J. Moore; Dr. Jianliang Lin,

    2012-07-31

    The main objective of this research program was to design and develop an optimal coating system that extends die life by minimizing premature die failure. In high-pressure aluminum die-casting, the die, core pins and inserts must withstand severe processing conditions. Many of the dies and tools in the industry are being coated to improve wear-resistance and decrease down-time for maintenance. However, thermal fatigue in metal itself can still be a major problem, especially since it often leads to catastrophic failure (i.e. die breakage) as opposed to a wear-based failure (parts begin to go out of tolerance). Tooling costs remain the largest portion of production costs for many of these parts, so the ability prevent catastrophic failures would be transformative for the manufacturing industry.The technology offers energy savings through reduced energy use in the die casting process from several factors, including increased life of the tools and dies, reuse of the dies and die components, reduction/elimination of lubricants, and reduced machine down time, and reduction of Al solder sticking on the die. The use of the optimized die coating system will also reduce environmental wastes and scrap parts. Current (2012) annual energy saving estimates, based on initial dissemination to the casting industry in 2010 and market penetration of 80% by 2020, is 3.1 trillion BTU's/year. The average annual estimate of CO2 reduction per year through 2020 is 0.63 Million Metric Tons of Carbon Equivalent (MM TCE).

  17. REAL TIME ULTRASONIC ALUMINUM SPOT WELD MONITORING SYSTEM

    SciTech Connect (OSTI)

    Regalado, W. Perez; Chertov, A. M.; Maev, R. Gr. [Institute for Diagnostic Imaging Research, Physics Department, University of Windsor, 292 Essex Hall, 401 Sunset Ave. N9B 3P4 Windsor, Ontario (Canada)

    2010-02-22

    Aluminum alloys pose several properties that make them one of the most popular engineering materials: they have excellent corrosion resistance, and high weight-to-strength ratio. Resistance spot welding of aluminum alloys is widely used today but oxide film and aluminum thermal and electrical properties make spot welding a difficult task. Electrode degradation due to pitting, alloying and mushrooming decreases the weld quality and adjustment of parameters like current and force is required. To realize these adjustments and ensure weld quality, a tool to measure weld quality in real time is required. In this paper, a real time ultrasonic non-destructive evaluation system for aluminum spot welds is presented. The system is able to monitor nugget growth while the spot weld is being made. This is achieved by interpreting the echoes of an ultrasound transducer located in one of the welding electrodes. The transducer receives and transmits an ultrasound signal at different times during the welding cycle. Valuable information of the weld quality is embedded in this signal. The system is able to determine the weld nugget diameter by measuring the delays of the ultrasound signals received during the complete welding cycle. The article presents the system performance on aluminum alloy AA6022.

  18. Hermetic aluminum radio frequency interconnection and method for making

    DOE Patents [OSTI]

    Kilgo, Riley D. (Albuquerque, NM); Kovacic, Larry (Albuquerque, NM); Brow, Richard K. (Rolla, MO)

    2000-01-01

    The present invention provides a light-weight, hermetic coaxial radio-frequency (RF) interconnection having an electrically conductive outer housing made of aluminum or an aluminum alloy, a central electrical conductor made of ferrous or non-ferrous material, and a cylinder of dielectric material comprising a low-melting-temperature, high-thermal-expansion aluminophosphate glass composition for hermetically sealing between the aluminum-alloy outer housing and the ferrous or non-ferrous center conductor. The entire RF interconnection assembly is made permanently hermetic by thermally fusing the center conductor, glass, and housing concurrently by bringing the glass to the melt point by way of exposure to an atmospheric temperature sufficient to melt the glass, less than 540.degree. C., but that does not melt the center conductor or the outer aluminum or aluminum alloy housing. The composition of the glass used is controlled to provide a suitable low dielectric constant so that an appropriate electrical characteristic impedance, for example 50 ohms, can be achieved for an electrical interconnection that performs well at high radio frequencies and also provides an interconnection maintaining a relatively small physical size.

  19. Phase III Advanced Anodes and Cathodes Utilized in Energy Efficient Aluminum Production Cells

    SciTech Connect (OSTI)

    R.A. Christini; R.K. Dawless; S.P. Ray; D.A. Weirauch, Jr.

    2001-11-05

    During Phase I of the present program, Alcoa developed a commercial cell concept that has been estimated to save 30% of the energy required for aluminum smelting. Phase ii involved the construction of a pilot facility and operation of two pilots. Phase iii of the Advanced Anodes and Cathodes Program was aimed at bench experiments to permit the resolution of certain questions to be followed by three pilot cells. All of the milestones related to materials, in particular metal purity, were attained with distinct improvements over work in previous phases of the program. NiO additions to the ceramic phase and Ag additions to the Cu metal phase of the cermet improved corrosion resistance sufficiently that the bench scale pencil anodes met the purity milestones. Some excellent metal purity results have been obtained with anodes of the following composition: Further improvements in anode material composition appear to be dependent on a better understanding of oxide solubilities in molten cryolite. For that reason, work was commissioned with an outside consultant to model the MeO - cryolite systems. That work has led to a better understanding of which oxides can be used to substitute into the NiO-Fe2O3 ceramic phase to stabilize the ferrites and reduce their solubility in molten cryolite. An extensive number of vertical plate bench electrolysis cells were run to try to find conditions where high current efficiencies could be attained. TiB2-G plates were very inconsistent and led to poor wetting and drainage. Pure TiB2 did produce good current efficiencies at small overlaps (shadowing) between the anodes and cathodes. This bench work with vertical plate anodes and cathodes reinforced the importance of good cathode wetting to attain high current efficiencies. Because of those conclusions, new wetting work was commissioned and became a major component of the research during the third year of Phase III. While significant progress was made in several areas, much work needs to be done. The anode composition needs further improvements to attain commercial purity targets. At the present corrosion rate, the vertical plate anodes will wear too rapidly leading to a rapidly increasing anode-cathode gap and thermal instabilities in the cell. Cathode wetting as a function of both cathode plate composition and bath composition needs to be better understood to ensure that complete drainage of the molten aluminum off the plates occurs. Metal buildup appears to lead to back reaction and low current efficiencies.

  20. Solder for oxide layer-building metals and alloys

    DOE Patents [OSTI]

    Kronberg, J.W.

    1992-09-15

    A low temperature solder and method for soldering an oxide layer-building metal such as aluminum, titanium, tantalum or stainless steel is disclosed. The composition comprises tin and zinc; germanium as a wetting agent; preferably small amounts of copper and antimony; and a grit, such as silicon carbide. The grit abrades any oxide layer formed on the surface of the metal as the germanium penetrates beneath and loosens the oxide layer to provide good metal-to-metal contact. The germanium comprises less than approximately 10% by weight of the solder composition so that it provides sufficient wetting action but does not result in a melting temperature above approximately 300 C. The method comprises the steps rubbing the solder against the metal surface so the grit in the solder abrades the surface while heating the surface until the solder begins to melt and the germanium penetrates the oxide layer, then brushing aside any oxide layer loosened by the solder.

  1. Solder for oxide layer-building metals and alloys

    DOE Patents [OSTI]

    Kronberg, James W. (108 Independent Blvd., Aiken, SC 29801)

    1992-01-01

    A low temperature solder and method for soldering an oxide layer-building metal such as aluminum, titanium, tantalum or stainless steel. The comosition comprises tin and zinc; germanium as a wetting agent; preferably small amounts of copper and antimony; and a grit, such as silicon carbide. The grit abrades any oxide layer formed on the surface of the metal as the germanium penetrates beneath and loosens the oxide layer to provide good metal-to-metal contact. The germanium comprises less than aproximatley 10% by weight of the solder composition so that it provides sufficient wetting action but does not result in a melting temperature above approximately 300.degree. C. The method comprises the steps rubbing the solder against the metal surface so the grit in the solder abrades the surface while heating the surface until the solder begins to melt and the germanium penetrates the oxide layer, then brushing aside any oxide layer loosened by the solder.

  2. Ceramic-metal composite article and joining method

    DOE Patents [OSTI]

    Kang, Shinhoo (Wayland, MA); Selverian, John H. (Burlington, MA); Kim, Hans J. (Concord, MA); Dunn, Edmund M. (Lexington, MA); Kim, Kyung S. (Barrington, RI)

    1992-01-01

    A ceramic-metal article including a ceramic rod, a metal rod, and a braze joining the ceramic and metal rods at a braze area of a coaxial bore in the metal rod. The bore gradually decreases in diameter, having an inward seat area sized for close sliding fit about the ceramic, a larger brazing area near the joint end, and a void area intermediate the braze and seat areas. The ceramic is seated without brazing in the bore seat area. The side wall between the brazing area and the metal outer surface is about 0.030-0.080 inch. The braze includes an inner braze layer, an outer braze layer, and an interlayer about 0.030-0.090 inch thick. A shoulder between the brazing and void areas supports the interlayer during bonding while preventing bonding between the void area and the ceramic member, leaving a void space between the void area and the ceramic member. A venting orifice extends generally radially through the metal member from the outer surface to the void space. The braze layers are palladium, platinum, gold, silver, copper, nickel, indium, chromium, molybdenum, niobium, iron, aluminum, or alloys thereof. Preferred is a gold-palladium-nickel brazing alloy. The interlayer is nickel, molybdenum, copper, tantalum, tungsten, niobium, aluminum, cobalt, iron, or an alloy thereof.

  3. Ductile Ni[sub 3]Al alloys as bonding agents for ceramic materials

    DOE Patents [OSTI]

    Tiegs, T.N.; McDonald, R.R.

    1990-04-24

    An improved ceramic-metal composite is described comprising a mixture of a ceramic material with a ductile intermetallic alloy, preferably Ni[sub 3]Al. 2 figs.

  4. Ductile Ni.sub.3 Al alloys as bonding agents for ceramic materials in cutting tools

    DOE Patents [OSTI]

    Tiegs, Terry N. (Lenoir City, TN); McDonald, Robert R. (Traverse City, MI)

    1991-01-01

    An improved ceramic-metal composite comprising a mixture of a ceramic material with a ductile intermetallic alloy, preferably Ni.sub.3 Al.

  5. Ductile Ni[sub 3]Al alloys as bonding agents for ceramic materials in cutting tools

    DOE Patents [OSTI]

    Tiegs, T.N.; McDonald, R.R.

    1991-05-14

    An improved ceramic-metal composite comprising a mixture of a ceramic material with a ductile intermetallic alloy, preferably Ni[sub 3]Al is disclosed. 2 figures.

  6. Real time synchrotron X-ray observations of solidification in hypoeutectic Al–Si alloys

    SciTech Connect (OSTI)

    Nogita, Kazuhiro [Nihon Superior Centre for the Manufacture of Electronic Materials, The University of Queensland, Brisbane, QLD 4072 (Australia); School of Mechanical and Mining Engineering, The University of Queensland, Brisbane, QLD 4072 (Australia); Yasuda, Hideyuki [Department of Adaptive Machine Systems, Osaka University, Suita, Osaka, 565-0871 (Japan); Prasad, Arvind [School of Mechanical and Mining Engineering, The University of Queensland, Brisbane, QLD 4072 (Australia); McDonald, Stuart D., E-mail: s.mcdonald1@uq.edu.au [Nihon Superior Centre for the Manufacture of Electronic Materials, The University of Queensland, Brisbane, QLD 4072 (Australia); School of Mechanical and Mining Engineering, The University of Queensland, Brisbane, QLD 4072 (Australia); Nagira, Tomoya; Nakatsuka, Noriaki [Department of Adaptive Machine Systems, Osaka University, Suita, Osaka, 565-0871 (Japan); Uesugi, Kentaro [Japan Synchrotron Radiation Research Institute, SPring-8, Sayo, Hyogo, 679-5198 (Japan); StJohn, David H. [School of Mechanical and Mining Engineering, The University of Queensland, Brisbane, QLD 4072 (Australia)

    2013-11-15

    This paper demonstrates how recent advances in synchrotron technology have allowed for the real-time X-ray imaging of solidification in Al–Si alloys, despite the small difference in atomic number of these elements. The experiments performed at the SPring-8 synchrotron, involved imaging the solidification of Al–1wt.%Si and Al–4wt.%Si alloys under a low-temperature gradient and a cooling rate of around 0.3 °C/s. The nucleation and growth of the primary aluminum grains as well as the onset of eutectic solidification were clearly observed. In the alloys containing Al–4wt.%Si, contrast was sufficient to characterize the nucleation rate and growth velocity of the aluminum grains. The importance of improving observation of solidification in the Al–Si system by increasing the time resolution during critical events is discussed. - Highlights: • A synchrotron technique was used to observe solidification of Al-Si alloys. • Nucleation, coarsening, and the onset of eutectic solidification were observed. • Images captured are suitable for quantitative analysis. • The resolution that was obtained should be possible for most aluminum alloys.

  7. Understanding composite explosive energetics: 4. Reactive flow modeling of aluminum reaction kinetics in PETN and TNT using normalized product equation of state

    SciTech Connect (OSTI)

    Tao, W.C.; Tarver, C.M.; Kury, J.W.; Lee, C.G.; Ornellas, D.L.

    1993-07-01

    Using Fabry-Perot interferometry techniques, we have determined the early time rate of energy release from detonating PETN and TNT explosives filled with 5 to 20 wt % of either 5 {mu}m or 18 {mu}m spherical aluminum with the detonation products, and calculate the extent of reaction at 1--3 {mu}s after the detonation. All of the metal in PETN formulations filled with 5 wt % and 10 wt % of either 5 {mu}m or 18 {mu}m aluminum reacted within 1.5 {mu}s, resulting in an increase of 18--22% in energy compared to pure PETN. For TNT formulations, between 5 to 10 wt % aluminum reacts completely with the same timeframe. A reactive flow hydrodynamic code model based on the Zeldovich-von Neumann-Doring (ZND) description of the reaction zone and subsequent reaction product expansion (Taylor wave) is used to address the reaction rate of the aluminum particles with detonation product gases. The detonation product JWL equation of state is derived from that of pure PETN using a parametric normalization methodology.

  8. Electrolytic production of metals using a resistant anode

    DOE Patents [OSTI]

    Tarcy, G.P.; Gavasto, T.M.; Ray, S.P.

    1986-11-04

    An electrolytic process is described comprising evolving oxygen on an anode in a molten salt, the anode comprising an alloy comprising a first metal and a second metal, both metals forming oxides, the oxide of the first metal being more resistant than the second metal to attack by the molten salt, the oxide of the second metal being more resistant than the first metal to the diffusion of oxygen. The electrode may also be formed of CuAlO[sub 2] and/or Cu[sub 2]O. 2 figs.

  9. COMPILATION OF LABORATORY SCALE ALUMINUM WASH AND LEACH REPORT RESULTS

    SciTech Connect (OSTI)

    HARRINGTON SJ

    2011-01-06

    This report compiles and analyzes all known wash and caustic leach laboratory studies. As further data is produced, this report will be updated. Included are aluminum mineralogical analysis results as well as a summation of the wash and leach procedures and results. Of the 177 underground storage tanks at Hanford, information was only available for five individual double-shell tanks, forty-one individual single-shell tanks (e.g. thirty-nine 100 series and two 200 series tanks), and twelve grouped tank wastes. Seven of the individual single-shell tank studies provided data for the percent of aluminum removal as a function of time for various caustic concentrations and leaching temperatures. It was determined that in most cases increased leaching temperature, caustic concentration, and leaching time leads to increased dissolution of leachable aluminum solids.

  10. Reactive self-heating model of aluminum spherical nanoparticles

    E-Print Network [OSTI]

    Karen S. Martirosyan; Maxim Zyskin

    2012-12-17

    Aluminum-oxygen reaction is important in many highly energetic, high pressure generating systems. Recent experiments with nanostructured thermites suggest that oxidation of aluminum nanoparticles occurs in a few microseconds. Such rapid reaction cannot be explained by a conventional diffusion-based mechanism. We present a rapid oxidation model of a spherical aluminum nanoparticle, using Cabrera-Mott moving boundary mechanism, and taking self-heating into account. In our model, electric potential solves the nonlinear Poisson equation. In contrast with the Coulomb potential, a "double-layer" type solution for the potential and self-heating leads to enhanced oxidation rates. At maximal reaction temperature of 2000 C, our model predicts overall oxidation time scale in microseconds range, in agreement with experimental evidence.

  11. Reactive self-heating model of aluminum spherical nanoparticles

    E-Print Network [OSTI]

    Martirosyan, Karen S

    2012-01-01

    Aluminum-oxygen reaction is important in many highly energetic, high pressure generating systems. Recent experiments with nanostructured thermites suggest that oxidation of aluminum nanoparticles occurs in a few microseconds. Such rapid reaction cannot be explained by a conventional diffusion-based mechanism. We present a rapid oxidation model of a spherical aluminum nanoparticle, using Cabrera-Mott moving boundary mechanism, and taking self-heating into account. In our model, electric potential solves the nonlinear Poisson equation. In contrast with the Coulomb potential, a "double-layer" type solution for the potential and self-heating leads to enhanced oxidation rates. At maximal reaction temperature of 2000 C, our model predicts overall oxidation time scale in microseconds range, in agreement with experimental evidence.

  12. CONTAINMENT ANALYSIS METHODOLOGY FOR TRANSPORT OF BREACHED CLAD ALUMINUM SPENT FUEL

    SciTech Connect (OSTI)

    Vinson, D.

    2010-07-11

    Aluminum-clad, aluminum-based spent nuclear fuel (Al-SNF) from foreign and domestic research reactors (FRR/DRR) is being shipped to the Savannah River Site and placed in interim storage in a water basin. To enter the United States, a cask with loaded fuel must be certified to comply with the requirements in the Title 10 of the U.S. Code of Federal Regulations, Part 71. The requirements include demonstration of containment of the cask with its contents under normal and accident conditions. Many Al-SNF assemblies have suffered corrosion degradation in storage in poor quality water, and many of the fuel assemblies are 'failed' or have through-clad damage. A methodology was developed to evaluate containment of Al-SNF even with severe cladding breaches for transport in standard casks. The containment analysis methodology for Al-SNF is in accordance with the methodology provided in ANSI N14.5 and adopted by the U. S. Nuclear Regulatory Commission in NUREG/CR-6487 to meet the requirements of 10CFR71. The technical bases for the inputs and assumptions are specific to the attributes and characteristics of Al-SNF received from basin and dry storage systems and its subsequent performance under normal and postulated accident shipping conditions. The results of the calculations for a specific case of a cask loaded with breached fuel show that the fuel can be transported in standard shipping casks and maintained within the allowable release rates under normal and accident conditions. A sensitivity analysis has been conducted to evaluate the effects of modifying assumptions and to assess options for fuel at conditions that are not bounded by the present analysis. These options would include one or more of the following: reduce the fuel loading; increase fuel cooling time; reduce the degree of conservatism in the bounding assumptions; or measure the actual leak rate of the cask system. That is, containment analysis for alternative inputs at fuel-specific conditions and at cask-loading-specific conditions could be performed to demonstrate that release is within the allowable leak rates of the cask.

  13. Process of preparing metal parts to be heated by means of infrared radiance

    DOE Patents [OSTI]

    Mayer, Howard Robinson (Cincinnati, OH); Blue, Craig A. (Knoxville, TN)

    2009-06-09

    A method for preparing metal for heating by infrared radiance to enable uniform and consistent heating. The surface of one or more metal parts, such as aluminum or aluminum alloy parts, is treated to alter the surface finish to affect the reflectivity of the surface. The surface reflectivity is evaluated, such as by taking measurements at one or more points on the surface, to determine if a desired reflectivity has been achieved. The treating and measuring are performed until the measuring indicates that the desired reflectivity has been achieved. Once the treating has altered the surface finish to achieve the desired reflectivity, the metal part may then be exposed to infrared radiance to heat the metal part to a desired temperature, and that heating will be substantially consistent throughout by virtue of the desired reflectivity.

  14. On the State of the Art of Metal Interconnects for SOFC Application

    SciTech Connect (OSTI)

    Jablonski@netl.doe.gov

    2011-02-27

    One of the recent developments for Solid Oxide Fuel Cells (SOFC) is oxide component materials capable of operating at lower temperatures such as 700-800C. This lower temperature range has provided for the consideration of metallic interconnects which have several advantages over ceramic interconnects: low cost, ease in manufacturing, and high conductivity. Most metals and alloys will oxidize under both the anode and cathode conditions within an SOFC, thus a chief requirement is that the base metal oxide scale must be electrically conductive since this constitutes the majority of the electrical resistance in a metallic interconnect. Common high temperature alloys form scales that contain chrome, silicon and aluminum oxides among others. Under SOFC operating conditions chrome oxide is a semi-conductor while silicon and aluminum oxides are insulators. In this talk we will review the evolution in candidate alloys and surface modifications which constitute an engineered solution for SOFC interconnect applications.

  15. Fabrication of metal matrix composite by semi-solid powder processing

    SciTech Connect (OSTI)

    Wu, Yufeng

    2012-11-28

    Various metal matrix composites (MMCs) are widely used in the automotive, aerospace and electrical industries due to their capability and flexibility in improving the mechanical, thermal and electrical properties of a component. However, current manufacturing technologies may suffer from insufficient process stability and reliability and inadequate economic efficiency and may not be able to satisfy the increasing demands placed on MMCs. Semi-solid powder processing (SPP), a technology that combines traditional powder metallurgy and semi-solid forming methods, has potential to produce MMCs with low cost and high efficiency. In this work, the analytical study and experimental investigation of SPP on the fabrication of MMCs were explored. An analytical model was developed to understand the deformation mechanism of the powder compact in the semi-solid state. The densification behavior of the Al6061 and SiC powder mixtures was investigated with different liquid fractions and SiC volume fractions. The limits of SPP were analyzed in terms of reinforcement phase loading and its impact on the composite microstructure. To explore adoption of new materials, carbon nanotube (CNT) was investigated as a reinforcing material in aluminum matrix using SPP. The process was successfully modeled for the mono-phase powder (Al6061) compaction and the density and density distribution were predicted. The deformation mechanism at low and high liquid fractions was discussed. In addition, the compaction behavior of the ceramic-metal powder mixture was understood, and the SiC loading limit was identified by parametric study. For the fabrication of CNT reinforced Al6061 composite, the mechanical alloying of Al6061-CNT powders was first investigated. A mathematical model was developed to predict the CNT length change during the mechanical alloying process. The effects of mechanical alloying time and processing temperature during SPP were studied on the mechanical, microstructural and compositional properties of the Al6061-CNT composites. A shear lag model was applied to predict the mechanical property (hardness) of the composite. This work demonstrated the promising potential of SPP in the fabrication of particle/fiber (nanotube) reinforced MMCs.

  16. Influence of argon and oxygen on charge-state-resolved ion energy distributions of filtered aluminum arcs

    E-Print Network [OSTI]

    Rosen, Johanna; Anders, Andre; Mraz, Stanislav; Atiser, Adil; Schneider, Jochen M.

    2006-01-01

    in filtered aluminum vacuum arc plasmas were measured andI. INTRODUCTION Vacuum arc plasma is well known to be highlymeasured for vacuum arc plasmas. Aluminum plasma, for

  17. The Development of ALADIN,an Expert System for Aluminum Alloy Design

    E-Print Network [OSTI]

    Fox, Mark S.

    -Mel- lon Unit,., Pittsburgh, PA, USA 1. Introduction ALADIN (ALuminum Alloy Design INventor) is an expert publications in The- oretical Physics. Dr. Hulthage is working on The Aluminum Alloy Design Inventor (Aladin

  18. Field assessment of an aluminum intensive passenger car

    SciTech Connect (OSTI)

    Cuenca, R.M.

    1994-12-31

    Ford Motor Co. has made a small batch of ``aluminum intensive vehicles`` (AIV), consisting of mid-size cars (Taurus/Sable) with all-aluminum bodies. The first twenty vehicles were made for internal evaluation at Ford, but the second batch of twenty has been placed on the hands of selected independent users, primarily automotive suppliers, for long term field assessment. The mass reduction achieved in the body of an AIV is shown, and compared with an equivalent standard steel body. Argonne obtained one of these vehicles last October; this is an assessment of the fuel consumption and other operational characteristics of this type of car to date.

  19. Electrolytic Cell For Production Of Aluminum Employing Planar Anodes.

    DOE Patents [OSTI]

    Barnett, Robert J. (Goldendale, WA); Mezner, Michael B. (Sandy, OR); Bradford, Donald R (Underwood, WA)

    2004-10-05

    A method of producing aluminum in an electrolytic cell containing alumina dissolved in an electrolyte, the method comprising providing a molten salt electrolyte having alumina dissolved therein in an electrolytic cell. A plurality of anodes and cathodes having planar surfaces are disposed in a generally vertical orientation in the electrolyte, the anodes and cathodes arranged in alternating or interleaving relationship to provide anode planar surfaces disposed opposite cathode planar surfaces, the anode comprised of carbon. Electric current is passed through anodes and through the electrolyte to the cathodes depositing aluminum at the cathodes and forming carbon containing gas at the anodes.

  20. Aluminum Surface Texturing by Means of Laser Interference Metallurgy

    SciTech Connect (OSTI)

    Chen, Jian; Sabau, Adrian S; Jones, Jonaaron F.; Hackett, Alexandra C.; Daniel, Claus; Warren, Charles David

    2015-01-01

    The increasing use of lightweight materials, such as aluminum alloys, in auto body structures requires more effective surface cleaning and texturing techniques to improve the quality of the structural components. The present work introduces a novel surface treatment method using laser interferometry produced by two beams of a pulsed Nd:YAG laser operating at 10Hz of frequency to clean aluminum surfaces, and meanwhile creating periodic and rough surface structures. The influences of beam size, laser fluence, wavelength, and pulse number per spot are investigated. High resolution optical profiler images reveal the change of the peak-to-valley height on the laser-treated surface.

  1. Corrosion-resistant fuel cladding allow for liquid metal fast breeder reactors

    DOE Patents [OSTI]

    Brehm, Jr., William F. (Richland, WA); Colburn, Richard P. (Pasco, WA)

    1982-01-01

    An aluminide coating for a fuel cladding tube for LMFBRs (liquid metal fast breeder reactors) such as those using liquid sodium as a heat transfer agent. The coating comprises a mixture of nickel-aluminum intermetallic phases and presents good corrosion resistance to liquid sodium at temperatures up to 700.degree. C. while additionally presenting a barrier to outward diffusion of .sup.54 Mn.

  2. Predicting the Failure of Ultrasonic Spot Welds by Pull-out from Sheet Metal

    E-Print Network [OSTI]

    Thouless, Michael

    -mode fracture of the base metal, the cohesive parameters for ductile fracture of an aluminum alloy were parameters (characteristic strength and toughness) associated with the shear and normal modes of ductile, cohesive zone, fracture, cohesive strength, toughness. (March 2006) #12;2 1. Introduction Ultrasonic spot

  3. Fracture mechanics analysis of NGV fuel cylinders. Part 2. Metal cylinder liners. Topical report

    SciTech Connect (OSTI)

    Connolly, M.P.; Hudak, S.J.

    1994-03-01

    Metal-lined composite wrapped cylinders for compressed natural gas (CNG) storage onboard natural gas vehicles (NGV`s) offer the advantage of reduced weight over conventional all-metal cylinders. These cylinders, however, can fail as a result of fatigue crack growth in the metal liners, or by degradation and failure of the composite wrap. This report summarizes a fracture mechanics based assessment of fatigue crack growth of the metal liners. The analysis was performed on a full-wrapped aluminum lined cylinder and a hoop-wrapped steel cylinder.

  4. Method for separating contaminants from solution employing an organic-stabilized metal-hydroxy gel

    DOE Patents [OSTI]

    Alexander, Donald H. (212 High Meadows, Richland, WA 99352)

    1996-01-01

    Metals and organics are extracted from solution by co-precipitating them with a gel comprising aluminum hydroxide and a complexing agent such as EDTA. After the gel is processed to remove the metals and organics, it can be recycled for further use by dissolving it in a high-pH solution, leaving no secondary waste stream. A number of alternative complexing agents perform better than EDTA.

  5. Passivation of Aluminum in Lithium-ion Battery Electrolytes with LiBOB

    E-Print Network [OSTI]

    Zhang, Xueyuan; Devine, Thomas M.

    2008-01-01

    of Aluminum in Lithium-ion Battery Electrolytes with LiBOBin commercially available lithium-ion battery electrolytes,

  6. ALS User Meeting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS User Meeting Print web banner ALS User Meeting: October 5-7, 2015 Home Agenda Awards Exhibitors Lodging Posters Registration Transportation Workshops Contact Us User Meeting...

  7. Cermet materials prepared by combustion synthesis and metal infiltration

    DOE Patents [OSTI]

    Holt, Joseph B. (San Jose, CA); Dunmead, Stephen D. (Davis, CA); Halverson, Danny C. (Modesto, CA); Landingham, Richard L. (Livermore, CA)

    1991-01-01

    Ceramic-metal composites (cermets) are made by a combination of self-propagating high temperature combustion synthesis and molten metal infiltration. Solid-gas, solid-solid and solid-liquid reactions of a powder compact produce a porous ceramic body which is infiltrated by molten metal to produce a composite body of higher density. AlN-Al and many other materials can be produced.

  8. Cermet materials prepared by combustion synthesis and metal infiltration

    DOE Patents [OSTI]

    Holt, J.B.; Dunmead, S.D.; Halverson, D.C.; Landingham, R.L.

    1991-01-29

    Ceramic-metal composites (cermets) are made by a combination of self-propagating high temperature combustion synthesis and molten metal infiltration. Solid-gas, solid-solid and solid-liquid reactions of a powder compact produce a porous ceramic body which is infiltrated by molten metal to produce a composite body of higher density. AlN-Al and many other materials can be produced. 6 figures.

  9. Mercury-free dissolution of aluminum-clad fuel in nitric acid

    DOE Patents [OSTI]

    Christian, Jerry D. (Idaho Falls, ID); Anderson, Philip A. (Pocatello, ID)

    1994-01-01

    A mercury-free dissolution process for aluminum involves placing the aluminum in a dissolver vessel in contact with nitric acid-fluoboric acid mixture at an elevated temperature. By maintaining a continuous flow of the acid mixture through the dissolver vessel, an effluent containing aluminum nitrate, nitric acid, fluoboric acid and other dissolved components are removed.

  10. Mercury-free dissolution of aluminum-clad fuel in nitric acid

    DOE Patents [OSTI]

    Christian, J.D.; Anderson, P.A.

    1994-11-15

    A mercury-free dissolution process for aluminum involves placing the aluminum in a dissolver vessel in contact with nitric acid-fluoboric acid mixture at an elevated temperature. By maintaining a continuous flow of the acid mixture through the dissolver vessel, an effluent containing aluminum nitrate, nitric acid, fluoboric acid and other dissolved components are removed. 5 figs.

  11. Textures in Strip-Cast Aluminum Alloys: Their On-Line Monitoring and Quantitative Effects on Formability. Final Technical Report

    SciTech Connect (OSTI)

    Man, Chi-Sing

    2003-07-27

    Aluminum sheets produced by continuous casting (CC) provide energy and economic savings of at least 25 and 14 percent, respectively, over sheets made from conventional direct chill (DC) ingot casting and rolling. As a result of the much simpler production route in continuous casting, however, the formability of CC aluminum alloys is often somewhat inferior to that of their DC counterparts. The mechanical properties of CC alloys can be improved by controlling their microstructure through optimal thermomechanical processing. Suitable annealing is an important means to improve the formability of CC aluminum alloy sheets. Recrystallization of deformed grains occurs during annealing, and it changes the crystallographic texture of the aluminum sheet. Laboratory tests in this project showed that this texture change can be detected by either laser-ultrasound resonance spectroscopy or resonance EMAT (electromagnetic acoustic transducer) spectroscopy, and that monitoring this change allows the degree of recrystallization or the ''recrystallized fraction'' in an annealed sheet to be ascertained. Through a plant trial conducted in May 2002, this project further demonstrated that it is feasible to monitor the recrystallized state of a continuous-cast aluminum sheet in-situ on the production line by using a laser-ultrasound sensor. When used in conjunction with inline annealing, inline monitoring of the recrystallized fraction by laser-ultrasound resonance spectroscopy offers the possibility of feed-back control that helps optimize processing parameters (e.g., annealing temperature), detect production anomalies, ensure product quality, and further reduce production costs of continuous-cast aluminum alloys. Crystallographic texture strongly affects the mechanical anisotropy/formability of metallic sheets. Clarification of the quantitative relationship between texture and anisotropy/formability of an aluminum alloy will render monitoring and control of its texture during the sheet production process even more meaningful. The present project included a study to determine how the anisotropic plastic behavior of a continuous-cast AA 5754 aluminum alloy depends on quantifiable texture coefficients. Formulae which show explicitly the effects of texture on the directional dependence of the q-value (a formability parameter) and of the uniaxial flow stress, respectively, were derived. Measurements made on a batch of as-received AA 5754 hot band and its O-temper counterpart corroborate the validity of these formulae. On the other hand, these measurements also indicate that some microstructure(s) other than texture could play a significant role in the plastic anisotropy of the AA 5754 alloy. For the q-value of a set of O-temper samples of this alloy, the additional microstructure that affects plastic anisotropy was shown to be grain shape. A formula that captures both the effects of crystallographic texture and grain shape on the q-value of the O-temper material was derived. A simple quadratic plastic potential that delivers this q-value formula was written down. Verification of the adequacy of this plastic potential, however, requires further investigations.

  12. BWeb Copy of the Aluminum Chapter from the 1st

    E-Print Network [OSTI]

    Ford, Andrew

    to a cheap source of electric power, typically a large scale hydro-electric facility. With 2,204 pounds industry. It then exploits the power of arrays to develop a model which distinguishes between smelters Falls Power Company. The partnership between large scale aluminum production and power generation

  13. Method to decrease loss of aluminum and magnesium melts

    DOE Patents [OSTI]

    Hryn, John N. (Naperville, IL); Pellin, Michael J. (Naperville, IL); Calaway, Jr., Wallis F. (Woodridge, IL); Moore, Jerry F. (Naperville, IL); Krumdick, Gregory K. (Crete, IL)

    2002-01-01

    A method to minimize oxidation of metal during melting processes is provided, the method comprising placing solid phase metal into a furnace environ-ment, transforming the solid-phase metal into molten metal phase having a molten metal surface, and creating a barrier between the surface and the environment. Also provided is a method for isolating the surface of molten metal from its environment, the method comprising confining the molten metal to a controlled atmos-phere, and imposing a floating substrate between the surface and the atmosphere.

  14. Attenuation of external Bremsstrahlung in metallic absorbers

    SciTech Connect (OSTI)

    Dhaliwal, A.S.; Powar, M.S.; Singh, M. (Punjabi Univ., Physics Dept., Patiala 147002 (IN))

    1990-12-01

    In this paper attenuation of bremsstrahlung from {sup 147}Pm and {sup 170}Tm beta emitters has been studied in aluminum, copper, tin, and lead metallic absorbers. Bremsstrahlung spectra and mass attenuation coefficients for monoenergetic gamma rays are used to calculate theoretical attenuation curves. Magnetic deflection and beta stopping techniques are used to measure the integral bremsstrahlung intensities above 30 keV in different target thicknesses. Comparison of measured and calculated attenuation curves shows a good agreement for various absorbers, thus providing a test of this technique, which may be useful in understanding bremsstrahlung intensity buildup and in the design of optimum shielding for bremsstrahlung sources. It is found that the absorption of bremsstrahlung in metallic absorbers does not obey an exponential law and that absorbers act as energy filters.

  15. NEUTRALIZATIONS OF HIGH ALUMINUM LOW URANIUM USED NUCLEAR FUEL SOLUTIONS CONTAINING GADOLINIUM AS A NEUTRON POISON

    SciTech Connect (OSTI)

    Taylor-Pashow, K.

    2011-06-08

    H-Canyon will begin dissolving High Aluminum - Low Uranium (High Al/Low U) Used Nuclear Fuel (UNF) following approval by DOE which is anticipated in CY2011. High Al/Low U is an aluminum/enriched uranium UNF with small quantities of uranium relative to aluminum. The maximum enrichment level expected is 93% {sup 235}U. The High Al/Low U UNF will be dissolved in H-Canyon in a nitric acid/mercury/gadolinium solution. The resulting solution will be neutralized and transferred to Tank 39H in the Tank Farm. To confirm that the solution generated could be poisoned with Gd, neutralized, and discarded to the Savannah River Site (SRS) high level waste (HLW) system without undue nuclear safety concerns the caustic precipitation of simulant solutions was examined. Experiments were performed with three simulant solutions representative of the H-Canyon estimated concentrations in the final solutions after dissolution. The maximum U, Gd, and Al concentration were selected for testing from the range of solution compositions provided. Simulants were prepared in three different nitric acid concentrations, ranging from 0.5 to 1.5 M. The simulant solutions were neutralized to four different endpoints: (1) just before a solid phase was formed (pH 3.5-4), (2) the point where a solid phase was obtained, (3) 0.8 M free hydroxide, and (4) 1.2 M free hydroxide, using 50 wt % sodium hydroxide (NaOH). The settling behavior of the neutralized solutions was found to be slower compared to previous studies, with settling continuing over a one week period. Due to the high concentration of Al in these solutions, precipitation of solids was observed immediately upon addition of NaOH. Precipitation continued as additional NaOH was added, reaching a point where the mixture becomes almost completely solid due to the large amount of precipitate. As additional NaOH was added, some of the precipitate began to redissolve, and the solutions neutralized to the final two endpoints mixed easily and had expected densities of typical neutralized waste. Based on particle size and scanning electron microscopy analyses, the neutralized solids were found to be homogeneous and less than 20 microns in size. The majority of solids were less than 4 microns in size. Compared to previous studies, a larger percentage of the Gd was found to precipitate in the partially neutralized solutions (at pH 3.5-4). In addition the Gd:U mass ratio was found to be at least 1.0 in all of the solids obtained after partial or full neutralization. The hydrogen to U (H:U) molar ratios for two accident scenarios were also determined. The first was for transient neutralization and agitator failure. Experimentally this scenario was determined by measuring the H:U ratio of the settled solids. The minimum H:U molar ratio for solids from fully neutralized solutions was 388:1. The second accident scenario is for the solids drying out in an unagitiated pump box. Experimentally, this scenario was determined by measuring the H:U molar ratio in centrifuged solids. The minimum H:U atom ratios for centrifuged precipitated solids was 250:1. It was determined previously that a 30:1 H:Pu atom ratio was sufficient for a 1:1 Gd:Pu mass ratio. Assuming a 1:1 equivalence with {sup 239}Pu, the results of these experiments show Gd is a viable poison for neutralizing U/Gd solutions with the tested compositions.

  16. Energy-Saving Melting and Revert Reduction Technology (E-SMARRT): Lost Foam Thin Wall - Feasibility of Producing Lost Foam Castings in Aluminum and Magnesium Based Alloys

    SciTech Connect (OSTI)

    Fasoyinu, Yemi; Griffin, John A.

    2014-03-31

    With the increased emphasis on vehicle weight reduction, production of near-net shape components by lost foam casting will make significant inroad into the next-generation of engineering component designs. The lost foam casting process is a cost effective method for producing complex castings using an expandable polystyrene pattern and un-bonded sand. The use of un-bonded molding media in the lost foam process will impose less constraint on the solidifying casting, making hot tearing less prevalent. This is especially true in Al-Mg and Al-Cu alloy systems that are prone to hot tearing when poured in rigid molds partially due to their long freezing range. Some of the unique advantages of using the lost foam casting process are closer dimensional tolerance, higher casting yield, and the elimination of sand cores and binders. Most of the aluminum alloys poured using the lost foam process are based on the Al-Si system. Very limited research work has been performed with Al-Mg and Al-Cu type alloys. With the increased emphasis on vehicle weight reduction, and given the high-strength-to-weight-ratio of magnesium, significant weight savings can be achieved by casting thin-wall (? 3 mm) engineering components from both aluminum- and magnesium-base alloys.

  17. Optical properties of chromium and neodymium in zirconium-barium-lanthanum-aluminum fluoride glass. Final report, October 1987-September 1988

    SciTech Connect (OSTI)

    Hanson, F.E.; Caspers, H.H.

    1993-08-01

    The optical properties are reported of chromium and neodymium doped in zirconium-barium-lanthanum-aluminum fluoride glass (ZBLA). The fluorescence of Cr(3+) and of co-doped Cr(3+), Nd(3+) glasses is investigated. Fluorescence decay rates of Cr(3+) and Nd(3+) are measured at various temperatures, and the excitation transfer efficiency between Cr(3+) and Nd(3+) is determined. The absorption spectrum of Nd(3+):ZBLA is characterized in terms of the Judd-Ofelt model of crystal field-induced electric-dipole transitions. The three phenomenological intensity parameters for Nd(3+) in ZBLA glass Omega sub 2,4,6, are compared to those obtained for Nd(3+) in Y3Al5Ol2, Gd3S2Al3Ol2, and LHG-8 glass.

  18. Thermodynamics of copper-nickel alloys containing aluminum, silicon, titanium, and chromium relative to their use in ceramic brazing

    SciTech Connect (OSTI)

    Williams, R.O.

    1984-11-01

    By varying the copper-to-nickel ratio the activity coefficients of Al, Si, Ti, and Cr can be varied over a wide range. Thus to a degree one can tailor the behavior of such alloys for usefulness in brazing ceramics. Further, considerable amounts of these active elements can be present while the ability of carbon to reduce the surface oxide film in a high-vacuum system is retained. The critical aluminum concentrations required to prevent the formation of SiO/sub 2/, TiO, or Cr/sub 2/O/sub 3/ by reaction with Al/sub 2/O/sub 3/ are calculated. The simultaneous presence of the four active additions will presumably promote wetting without making the surface deoxidation more difficult.

  19. Composite metal membrane

    DOE Patents [OSTI]

    Peachey, Nathaniel M. (Espanola, NM); Dye, Robert C. (Los Alamos, NM); Snow, Ronny C. (Los Alamos, NM); Birdsell, Stephan A. (Los Alamos, NM)

    1998-01-01

    A composite metal membrane including a first metal layer of Group IVB met or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof is provided together with a process for the recovery of hydrogen from a gaseous mixture including contacting a hydrogen-containing gaseous mixture with a first side of a nonporous composite metal membrane including a first metal of Group IVB metals or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof, and, separating hydrogen from a second side of the nonporous composite metal membrane.

  20. Composite metal membrane

    DOE Patents [OSTI]

    Peachey, N.M.; Dye, R.C.; Snow, R.C.; Birdsell, S.A.

    1998-04-14

    A composite metal membrane including a first metal layer of Group IVB met or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof is provided together with a process for the recovery of hydrogen from a gaseous mixture including contacting a hydrogen-containing gaseous mixture with a first side of a nonporous composite metal membrane including a first metal of Group IVB metals or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof, and, separating hydrogen from a second side of the nonporous composite metal membrane.

  1. Improving properties of Mg with Al–Cu additions

    SciTech Connect (OSTI)

    Rashad, Muhammad; Pan, Fusheng; Asif, Muhammad; Hussain, Shahid; Saleem, Muhammad

    2014-09-15

    The present work reports improvement in tensile properties of the Mg matrix reinforced with micron-sized copper–aluminum particulate hybrids. The Al–Cu particulate hybrids were incorporated into the Mg matrix through powder metallurgy method. The synthesized alloys exhibited homogeneously dispersed Mg{sub 2}Cu particles in the matrix, therefore leading to a 110% increase in yield strength (221 MPa) and a 72% enhancement in ultimate tensile strength (284 MPa) by addition of 1.0 wt.%Al–0.6 wt.%Cu particle hybrids. Optical microscopy, scanning election microscopy, transmission electron microscopy and X-ray diffraction were used to investigate the microstructure and intermetallic phases of the synthesized alloys. - Highlights: • Mg matrix is reinforced with Al–Cu particulate hybrids. • Powder metallurgic method is used to fabricate the alloys. • Tensile strength and ductility were increased simultaneously.

  2. A MODERN INTERPRETATION OF THE BARNEY DIAGRAM FOR ALUMINUM SOLUBILITY IN TANK WASTE

    SciTech Connect (OSTI)

    REYNOLDS JG; REYNOLDS DA

    2009-12-16

    Experimental and modeling studies of aluminum solubility in Hanford tank waste have been developed and refined for many years in efforts to resolve new issues or develop waste treatment flowsheets. The earliest of these studies was conducted by G. Scott Barney, who performed solubility studies in highly concentrated electrolyte solutions to support evaporator campaign flowsheets in the 1970's. The 'Barney Diagram', a term still widely used at Hanford today, suggested gibbsite ({gamma}-Al(OH){sub 3}) was much more soluble in tank waste than in simple sodium hydroxide solutions. These results, which were highly surprising at the time, continue to be applied to new situations where aluminum solubility in tank waste is of interest. Here, we review the history and provide a modern explanation for the large gibbsite solubility observed by Barney, an explanation based on basic research that has been performed and published in the last 30 years. This explanation has both thermodynamic and kinetic aspects. Thermodynamically, saturated salt solutions stabilize soluble aluminate species that are minor components in simple sodium hydroxide solutions. These species are the aluminate dimer and the sodium-aluminate ion-pair. Ion-pairs must be present in the Barney simulants because calculations showed that there was insufficient space between the highly concentrated ions for a water molecule. Thus, most of the ions in the simulants have to be ion-paired. Kinetics likely played a role as well. The simulants were incubated for four to seven days, and more recent data indicate that this was unlikely sufficient time to achieve equilibrium from supersaturation. These results allow us to evaluate applications of the Barney results to current and future tank waste issues or flowsheets.

  3. Atomic layer deposited lithium aluminum oxide: (In)dependency of film properties from pulsing sequence

    SciTech Connect (OSTI)

    Miikkulainen, Ville Nilsen, Ola; Fjellvåg, Helmer; Li, Han; King, Sean W.; Laitinen, Mikko; Sajavaara, Timo

    2015-01-01

    Atomic layer deposition (ALD) holds markedly high potential of becoming the enabling method for achieving the three-dimensional all-solid-state thin-film lithium ion battery (LiB). One of the most crucial components in such a battery is the electrolyte that needs to hold both low electronic conductivity and at least fair lithium ion conductivity being at the same time pinhole free. To obtain these desired properties in an electrolyte film, one necessarily has to have a good control over the elemental composition of the deposited material. The present study reports on the properties of ALD lithium aluminum oxide (Li{sub x}Al{sub y}O{sub z}) thin films. In addition to LiB electrolyte applications, Li{sub x}Al{sub y}O{sub z} is also a candidate low dielectric constant (low-k) etch stop and diffusion barrier material in nanoelectronics applications. The Li{sub x}Al{sub y}O{sub z} films were deposited employing trimethylaluminum-O{sub 3} and lithium tert-butoxide-H{sub 2}O for Al{sub 2}O{sub 3} and Li{sub 2}O/LiOH, respectively. The composition was aimed to be controlled by varying the pulsing ratio of those two binary oxide ALD cycles. The films were characterized by several methods for composition, crystallinity and phase, electrical properties, hardness, porosity, and chemical environment. Regardless of the applied pulsing ratio of Al{sub 2}O{sub 3} and Li{sub 2}O/LiOH, all the studied ALD Li{sub x}Al{sub y}O{sub z} films of 200 and 400 nm in thickness were polycrystalline in the orthorhombic ?-LiAlO{sub 2} phase and also very similar to each other with respect to composition and other studied properties. The results are discussed in the context of both fundamental ALD chemistry and applicability of the films as thin-film LiB electrolytes and low-k etch stop and diffusion barriers.

  4. High Methane Storage Capacity in Aluminum Metal-Organic Frameworks (MOFs)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid you notHeat Pumps Heat Pumps An error occurred. Try| Center for Gas

  5. Reduction of Annealing Times for Energy Conservation in Aluminum

    SciTech Connect (OSTI)

    Anthony D. Rollett; Hasso Weiland; Mohammed Alvi; Abhijit Brahme

    2005-08-31

    Carnegie Mellon University was teamed with the Alcoa Technical Center with support from the US Dept. of Energy (Office of Industrial Technology) and the Pennsylvania Technology Investment Authority (PTIA) to make processing of aluminum less costly and more energy efficient. Researchers in the Department of Materials Science and Engineering have investigated how annealing processes in the early stages of aluminum processing affect the structure and properties of the material. Annealing at high temperatures consumes significant amounts of time and energy. By making detailed measurements of the crystallography and morphology of internal structural changes they have generated new information that will provide a scientific basis for shortening processing times and consuming less energy during annealing.

  6. Influence of insulating coating on aluminum wire explosions

    SciTech Connect (OSTI)

    Li, Yang; Wu, Jian; Sheng, Liang; Zhao, Jizhen; Zhang, Mei; Yuan, Yuan; Peng, Bodong; Li, Xingwen

    2014-10-15

    Single wire explosions are widely used in understanding the early stages of z-pinch experiments. This paper presents a serial of experiments conducted on the pulse power generator with ?1?kA peak current and ?10?ns rising time in Xi'an Jiao Tong University. Polyimide coated aluminum wires and uncoated ones were tested under three different voltages to analyze the effect of insulating coating. Experimental results showed that insulating coating can increase the energy deposition 10%?30% in aluminum wires by delaying the voltage collapse and raising the maximum load resistance. The substantial energy deposition resulted in about 20% faster expansion rates for coated wires. Experimental evidence that plasma channel shunts the current from the wire core was observed by streak camera and schlieren graphs. This paper also briefly discussed the influence of nonuniform coating on the morphology of wire expansion.

  7. Growth and Oxidation of Thin Film Al(2)Cu

    SciTech Connect (OSTI)

    SON,KYUNG-AH; MISSERT,NANCY A.; BARBOUR,J. CHARLES; HREN,J.J.; COPELAND,ROBERT GUILD; MINOR,KENNETH G.

    2000-01-18

    Al{sub 2}Cu thin films ({approx} 382 nm) are fabricated by melting and resolidifying Al/Cu bilayers in the presence of a {micro} 3 nm Al{sub 2}O{sub 3} passivating layer. X-ray Photoelectron Spectroscopy (XPS) measures a 1.0 eV shift of the Cu2p{sub 3/2} peak and a 1.6 eV shift of the valence band relative to metallic Cu upon Al{sub 2}Cu formation. Scanning Electron microscopy (SEM) and Electron Back-Scattered Diffraction (EBSD) show that the Al{sub 2}Cu film is composed of 30-70 {micro}m wide and 10-25 mm long cellular grains with (110) orientation. The atomic composition of the film as estimated by Energy Dispersive Spectroscopy (EDS) is 67 {+-} 2% Al and 33 {+-} 2% Cu. XPS scans of Al{sub 2}O{sub 3}/Al{sub 2}Cu taken before and after air exposure indicate that the upper Al{sub 2}Cu layers undergo further oxidation to Al{sub 2}O{sub 3} even in the presence of {approx} 5 nm Al{sub 2}O{sub 3}. The majority of Cu produced from oxidation is believed to migrate below the Al{sub 2}O{sub 3} layers, based upon the lack of evidence for metallic Cu in the XPS scans. In contrast to Al/Cu passivated with Al{sub 2}O{sub 3}, melting/resolidifying the Al/Cu bilayer without Al{sub 2}O{sub 3} results in phase-segregated dendritic film growth.

  8. Synthesis and Properites of Nanotwinned Silver and Aluminum 

    E-Print Network [OSTI]

    Bufford, Daniel C

    2013-07-31

    Recent studies of fcc metals with dense twins (~10 nm spacing) have revealed impressive mechanical properties, along with improved ductility and electrical conductivity in comparison to nanocrystalline metals with similar ...

  9. Metal Hydrides

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURING OFFICESpecial ReportProposal to changeNovemberEnergyMessage fromMetal

  10. Three series of quaternary rare-earth transition-metal pnictides with CaAl{sub 2}Si{sub 2}-type structures: RECuZnAs{sub 2}, REAgZnP{sub 2}, and REAgZnAs{sub 2}

    SciTech Connect (OSTI)

    Stoyko, Stanislav S.; Ramachandran, Krishna K.; Blanchard, Peter E.R. [Department of Chemistry, University of Alberta, Edmonton, Alberta, Canada T6G 2G2 (Canada); Rosmus, Kimberly A.; Aitken, Jennifer A. [Department of Chemistry and Biochemistry, Duquesne University, Pittsburgh, PA 15282 (United States); Mar, Arthur, E-mail: arthur.mar@ualberta.ca [Department of Chemistry, University of Alberta, Edmonton, Alberta, Canada T6G 2G2 (Canada)

    2014-05-01

    Three series of quaternary rare-earth transition-metal pnictides REMM?Pn{sub 2} (M=Cu, Ag; M?=Zn; Pn=P, As) have been prepared by reaction of the elements at 800 °C, with crystal growth promoted through the addition of iodine. The extent of RE substitution is broad in these series: RECuZnAs{sub 2} (RE=Y, La-Nd, Sm, Gd–Lu), REAgZnP{sub 2} (RE=La–Nd, Sm, Gd–Dy), and REAgZnAs{sub 2} (RE=La-Nd, Sm, Gd-Dy). Powder and single-crystal X-ray diffraction analysis revealed that they adopt the trigonal CaAl{sub 2}Si{sub 2}-type structure (space group P3{sup ¯}m1, Z=1), in which Cu or Ag atoms are disordered with Zn atoms over the unique tetrahedrally coordinated transition-metal site. Magnetic measurements indicated Curie–Weiss behavior for several members of the RECuZnAs{sub 2} and REAgZnP{sub 2} series. Core-line X-ray photoelectron spectra (XPS) collected on some RECuZnAs{sub 2} members corroborate the charge assignment deduced by the Zintl concept for these compounds, (RE{sup 3+})(M{sup 1+})(Zn{sup 2+})(Pn{sup 3?}){sub 2}. Optical diffuse reflectance spectra and valence band XPS spectra established that these compounds are small band-gap semiconductors (up to ?0.8 eV in REAgZnP{sub 2}) or semimetals (RECuZnAs{sub 2}). Band structure calculations also support this electronic structure and indicate that the band gap can be narrowed through appropriate chemical substitution (RE=smaller atoms, M=Cu, and Pn=As). - Graphical abstract: Cu or Ag atoms are disordered with Zn atoms over the tetrahedral site within relatively rigid [M{sub 2}Pn{sub 2}] slabs in three series of quaternary pnictides adopting the CaAl{sub 2}Si{sub 2}-type structure. - Highlights: • Three series (comprising 25 compounds) of pnictides REMM'Pn{sub 2} were prepared. • Cu or Ag atoms are disordered with Zn atoms within relatively rigid [M{sub 2}Pn{sub 2}] slabs. • They are semimetals or small band-gap semiconductors. • RECuZnAs{sub 2} and REAgZnP{sub 2} are generally paramagnetic.

  11. Mechanical properties of Al-Cu alloy-SiC composites

    SciTech Connect (OSTI)

    Anggara, B. S., E-mail: anggorobs1960@yahoo.com [Jurusan Fisika, FMIPA Universitas Negeri Jakarta, Indonesia 13220 and PPS Ilmu Material, Department Fisika, FMIPA, Universitas Indonesia (Indonesia); Handoko, E. [Jurusan Fisika, FMIPA Universitas Negeri Jakarta, 13220 (Indonesia); Soegijono, B. [PPS Ilmu Material, Department Fisika, FMIPA, Universitas Indonesia (Indonesia)

    2014-09-25

    The synthesis of aluminum (Al) alloys, Al-Cu, from mixture 96.2 % Al and 3.8 % Cu has been prepared by melting process at a temperature of 1200°C. The adding 12.5 wt% up to 20 wt% of SiC on Al-Cu alloys samples has been investigated. The structure analyses were examined by X-Ray Diffractometer (XRD) and scanning electron microscope (SEM). Moreover, the morphology of Al-Cu alloys has been seen as structure in micrometer range. The hardness was measured by hardness Vickers method. According to the results, it can be assumed that the 15 wt% of SiC content is prefer content to get better quality of back to back hardness Vickers of Al-Cu alloys.

  12. Isentropic Compression Experiment on Aluminum Using the Z-Accelerator

    SciTech Connect (OSTI)

    Williamson, D.R.; Peterson, R.R.; Blanchard, J.P

    2003-07-15

    The capability of using the Z-Machine at Sandia to perform isentropic compression experiments has been discussed by Hall previously. Pressures exceeding 1.5 Mbar have been launched into materials and the pressure wave can be shaped by varying the load current in Z. In this paper, theoretical results will be presented for an aluminum sample in which we obtain isentropic equations of state (EOS) information.Obtaining the isentropic EOS is necessary in many scientific and technological fields for computer simulations. We will follow the procedure outlined by Reisman to determine the EOS. From these steps, we will determine the theoretical EOS of aluminum using data obtained from BUCKY. We will discuss any variances we have in our results due to the use of two different sets of EOS opacity data.The results presented here were obtained using BUCKY, a 1-D MHD code developed at University of Wisconsin-Madison. BUCKY is a code that simulates high energy density plasmas and target yields for Inertial Confinement Fusion (ICF). BUCKY was originally designed to study target physics and target chamber designs for ICF reactors but can be used to study Isentropic Compression Experiments.We will describe the procedure used to determine the velocity wave profile measurements that leads to determining EOS. From the velocity wave profile we will be able to determine the isentropic compression equations of state of the aluminum sample modeled.

  13. Electrical properties of atomic layer deposited aluminum oxide on gallium nitride

    SciTech Connect (OSTI)

    Esposto, Michele; Krishnamoorthy, Sriram; Nath, Digbijoy N.; Bajaj, Sanyam; Hung, Ting-Hsiang; Rajan, Siddharth

    2011-09-26

    We report on our investigation of the electrical properties of metal/Al{sub 2}O{sub 3}/GaN metal-insulator-semiconductor capacitors. We determined the conduction band offset and interface charge density of the alumina/GaN interface by analyzing the capacitance-voltage characteristics of atomic layer deposited Al{sub 2}O{sub 3} films on GaN substrates. The conduction band offset at the Al{sub 2}O{sub 3}/GaN interface was calculated to be 2.13 eV, in agreement with theoretical predications. A non-zero field of 0.93 MV/cm in the oxide under flat-band conditions in the GaN was inferred, which we attribute to a fixed net positive charge density of magnitude 4.60 x 10{sup 12 }cm{sup -2} at the Al{sub 2}O{sub 3}/GaN interface. We provide hypotheses to explain the origin of this charge by analyzing the energy band line-up.

  14. Supersonic metal plasma impact on a surface: An optical investigation of the pre-surface region

    SciTech Connect (OSTI)

    Fusion Science Group, AFRD; Plasma Applications Group, AFRD; Ni, Pavel A.; Anders, Andre

    2009-12-15

    Aluminum plasma, produced in high vacuum by a pulsed, filtered cathodic arc plasma source, was directed onto a wall where if formed a coating. The accompanying ?optical flare? known from the literature was visually observed, photographed, and spectroscopically investigated with appropriately high temporal (1 ?s) and spatial (100 ?m) resolution. Consistent with other observations using different techniques, it was found that the impact of the fully ionized plasma produces metal neutrals as well as desorbed gases, both of which interact with the incoming plasma. Most effectively are charge exchange collisions between doubly charged aluminum and neutral aluminum, which lead to a reduction of the flow of doubly charged before they reach the wall, and a reduction of neutrals as the move away from the surface. Those plasma-wall interactions are relevant for coating processes as well as for interpreting the plasma properties such as ion charge state distributions.

  15. Susceptibility of Aluminum Alloys to Corrosion in Simulated Fuel Blends Containing Ethanol

    SciTech Connect (OSTI)

    Thomson, Jeffery K; Pawel, Steven J; Wilson, Dane F

    2013-01-01

    The compatibility of aluminum and aluminum alloys with synthetic fuel blends comprised of ethanol and reference fuel C (a 50/50 mix of toluene and iso-octane) was examined as a function of water content and temperature. Commercially pure wrought aluminum and several cast aluminum alloys were observed to be similarly susceptible to substantial corrosion in dry (< 50 ppm water) ethanol. Corrosion rates of all the aluminum materials examined was accelerated by increased temperature and ethanol content in the fuel mixture, but inhibited by increased water content. Pretreatments designed to stabilize passive films on aluminum increased the incubation time for onset of corrosion, suggesting film stability is a significant factor in the mechanism of corrosion.

  16. Impact of Aluminum on Anticipated Corrosion in a Flooded SNF Multi Canister Overpack (MCO)

    SciTech Connect (OSTI)

    DUNCAN, D.R.

    1999-07-06

    Corrosion reactions in a flooded MCO are examined to determine the impact of aluminum corrosion products (from aluminum basket grids and spacers) on bound water estimates and subsequent fuel/environment reactions during storage. The mass and impact of corrosion products were determined to be insignificant, validating the choice of aluminum as an MCO component and confirming expectations that no changes to the Technical Databook or particulate mass or water content are necessary.

  17. Metal filled porous carbon

    DOE Patents [OSTI]

    Gross, Adam F. (Los Angeles, CA); Vajo, John J. (West Hills, CA); Cumberland, Robert W. (Malibu, CA); Liu, Ping (Irvine, CA); Salguero, Tina T. (Encino, CA)

    2011-03-22

    A porous carbon scaffold with a surface and pores, the porous carbon scaffold containing a primary metal and a secondary metal, where the primary metal is a metal that does not wet the surface of the pores of the carbon scaffold but wets the surface of the secondary metal, and the secondary metal is interspersed between the surface of the pores of the carbon scaffold and the primary metal.

  18. Reduction of Carbon Footprint and Energy Efficiency Improvement in Aluminum Production by Use of Novel Wireless Instrumentation Integrated with Mathematical Modeling

    SciTech Connect (OSTI)

    James W. Evans

    2012-04-11

    The work addressed the greenhouse gas emission and electrical energy consumption of the aluminum industry. The objective was to provide a means for reducing both through the application of wireless instrumentation, coupled to mathematical modeling. Worldwide the aluminum industry consumes more electrical energy than all activities in many major countries (e.g. the UK) and emits more greenhouse gasses (e.g. than France). Most of these excesses are in the 'primary production' of aluminum; that is the conversion of aluminum oxide to metal in large electrolytic cells operating at hundreds of thousands of amps. An industry-specific GHG emission has been the focus of the work. The electrolytic cells periodically, but at irregular intervals, experience an upset condition known as an 'anode effect'. During such anode effects the cells emit fluorinated hydrocarbons (PFCs, which have a high global warming potential) at a rate far greater than in normal operation. Therefore curbing anode effects will reduce GHG emissions. Prior work had indicated that the distribution of electrical current within the cell experiences significant shifts in the minutes before an anode effect. The thrust of the present work was to develop technology that could detect and report this early warning of an anode effect so that the control computer could minimize GHG emissions. A system was developed to achieve this goal and, in collaboration with Alcoa, was tested on two cells at an Alcoa plant in Malaga, Washington. The project has also pointed to the possibility of additional improvements that could result from the work. Notable among these is an improvement in efficiency that could result in an increase in cell output at little extra operating cost. Prospects for commercialization have emerged in the form of purchase orders for further installations. The work has demonstrated that a system for monitoring the current of individual anodes in an aluminum cell is practical. Furthermore the system has been installed twice on a smelter in the US without exposing workers to hazards usually associated with running signal wires in aluminum plants. The results display the early warning of an anode effect that potentially can be used to minimize such anode effects with their excessive GHG emissions. They also point to a possible, but substantial, economic benefit that could result in improved current efficiency by anode adjustment based on individual anode current measurements.

  19. Updated Life-Cycle Assessment of Aluminum Production and Semi-fabrication for the GREET Model

    SciTech Connect (OSTI)

    Dai, Qiang; Kelly, Jarod C.; Burnham, Andrew; Elgowainy, Amgad

    2015-09-01

    This report serves as an update for the life-cycle analysis (LCA) of aluminum production based on the most recent data representing the state-of-the-art of the industry in North America. The 2013 Aluminum Association (AA) LCA report on the environmental footprint of semifinished aluminum products in North America provides the basis for the update (The Aluminum Association, 2013). The scope of this study covers primary aluminum production, secondary aluminum production, as well as aluminum semi-fabrication processes including hot rolling, cold rolling, extrusion and shape casting. This report focuses on energy consumptions, material inputs and criteria air pollutant emissions for each process from the cradle-to-gate of aluminum, which starts from bauxite extraction, and ends with manufacturing of semi-fabricated aluminum products. The life-cycle inventory (LCI) tables compiled are to be incorporated into the vehicle cycle model of Argonne National Laboratory’s Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET) Model for the release of its 2015 version.

  20. Investigation of Opportunities for High-Temperature Solar Energy in the Aluminum Industry

    SciTech Connect (OSTI)

    Murray, J.

    2006-05-01

    This report gives the conclusions drawn from a study of the potential application of high-temperature solar process heat for production of aluminum.

  1. Extracting metals directly from metal oxides

    DOE Patents [OSTI]

    Wai, C.M.; Smart, N.G.; Phelps, C.

    1997-02-25

    A method of extracting metals directly from metal oxides by exposing the oxide to a supercritical fluid solvent containing a chelating agent is described. Preferably, the metal is an actinide or a lanthanide. More preferably, the metal is uranium, thorium or plutonium. The chelating agent forms chelates that are soluble in the supercritical fluid, thereby allowing direct removal of the metal from the metal oxide. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of {beta}-diketones, halogenated {beta}-diketones, phosphinic acids, halogenated phosphinic acids, carboxylic acids, halogenated carboxylic acids, and mixtures thereof. In especially preferred embodiments, at least one of the chelating agents is fluorinated. The method provides an environmentally benign process for removing metals from metal oxides without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the metal recovered, to provide an economic, efficient process. 4 figs.

  2. Extracting metals directly from metal oxides

    DOE Patents [OSTI]

    Wai, Chien M. (Moscow, ID); Smart, Neil G. (Moscow, ID); Phelps, Cindy (Moscow, ID)

    1997-01-01

    A method of extracting metals directly from metal oxides by exposing the oxide to a supercritical fluid solvent containing a chelating agent is described. Preferably, the metal is an actinide or a lanthanide. More preferably, the metal is uranium, thorium or plutonium. The chelating agent forms chelates that are soluble in the supercritical fluid, thereby allowing direct removal of the metal from the metal oxide. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of .beta.-diketones, halogenated .beta.-diketones, phosphinic acids, halogenated phosphinic acids, carboxylic acids, halogenated carboxylic acids, and mixtures thereof. In especially preferred embodiments, at least one of the chelating agents is fluorinated. The method provides an environmentally benign process for removing metals from metal oxides without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the metal recovered, to provide an economic, efficient process.

  3. COORDINATION CHEMISTRY OF METAL SURFACES AND METAL COMPLEXES

    E-Print Network [OSTI]

    Muetterties, E.L.

    2013-01-01

    4, 1980 Catalysis~ COORDINATION CHEMISTRY OF METAL SURFACESAND METAL COMPLEXES Earl L. Muetterties December 1979 TWO-10308 COORDINATION CHEt1ISTRY OF METAL SURFACES AND METAL

  4. A differential thermal analysis study of the effect of tramp impurities on the exothermic U sub 3 O sub 8 -Al reactions

    SciTech Connect (OSTI)

    Gray, L.W. (Lawrence Livermore National Lab., CA (USA)); Peacock, H.B. (Savannah River Lab., Aiken, SC (USA))

    1989-12-01

    Differential thermal analysis (DTA) has been used to study the effect of impurities on aluminothermic reactions between commercial type 101 aluminum powder and U{sub 3}O{sub 8} powder. No measurable effect (solid state reactions) was found below 660{degrees}C during differential thermal analysis studies of (1) loose blended powders, (2) blended and compressed powders, (3) blended, heated, and compressed powders, or (4) blended, compressed, and heated compacts containing less than 50,000 ppM impurities from group IA halide salts and group IIA oxides. It was determined that impurities (>5 wt %) of alkali metal chlorides, and alkaline earth oxides, cause minor modifications of the reaction thermograms above 800{degrees}C for molten aluminum metal with U{sub 3}O{sub 8}. It was also determined that attempts to prepare alkali, alkaline earth, and transition metal uranates under conditions via reaction below 660{degrees}C. In similar experiments where Fe{sub 2}O{sub 3} and NiO were substituted for U{sub 3}O{sub 8}, it was determined that NaCl does modify the reactions between aluminum metal and Fe{sub 2}O{sub 3} and between aluminum metal and NiO. With increasing NaCl concentrations, the temperature for initiation of the reaction moves to lower temperatures. At 10 wt % NaCl, the exothermic thermite'' reactions between aluminum and Fe{sub 2}O{sub 3} or NiO begin at approximately 640{degrees}C. 30 refs., 17 figs., 7 tabs.

  5. Constitutive Expression of a High-Affinity Sulfate Transporter in Indian Mustard Affects Metal Tolerance and Accumulation

    E-Print Network [OSTI]

    engineering. Already, transgenic plants with enhanced metal tolerance and accumulation have been created via et al., 1999; Curie et al., 2000; Hirschi et al., 2000). The purpose of this study was to test of heavy metals there is an increased demand for reduced S compounds like GSH and PCs, and genes involved

  6. Oxidation resistant nanocrystalline MCrAl(Y) coatings and methods of forming such coatings

    SciTech Connect (OSTI)

    Cheruvu, Narayana S.; Wei, Ronghua

    2014-07-29

    The present disclosure relates to an oxidation resistant nanocrystalline coating and a method of forming an oxidation resistant nanocrystalline coating. An oxidation resistant coating comprising an MCrAl(Y) alloy may be deposited on a substrate, wherein M, includes iron, nickel, cobalt, or combinations thereof present greater than 50 wt % of the MCrAl(Y) alloy, chromium is present in the range of 15 wt % to 30 wt % of the MCrAl(Y) alloy, aluminum is present in the range of 6 wt % to 12 wt % of the MCrAl(Y) alloy and yttrium, is optionally present in the range of 0.1 wt % to 0.5 wt % of the MCrAl(Y) alloy. In addition, the coating may exhibit a grain size of 200 nm or less as deposited.

  7. FRICTION STIR SPOT WELDING OF 6016 ALUMINUM ALLOY

    SciTech Connect (OSTI)

    Mishra, Rajiv S.; Webb, S.; Freeney, T. A.; Chen, Y. L.; Gayden, X.; Grant, Glenn J.; Herling, Darrell R.

    2007-01-08

    Friction stir spot welding (FSSW) of 6016 aluminum alloy was evaluated with conventional pin tool and new off-center feature tools. The off-center feature tool provides significant control over the joint area. The tool rotation rate was varied between 1000 and 2500 rpm. Maximum failure strength was observed in the tool rotation range of 1200-1500 rpm. The results are interpreted in the context of material flow in the joint and influence of thermal input on microstructural changes. The off-center feature tool concept opens up new possibilities for plunge-type friction stir spot welding.

  8. The Pricing of Electricity to Aluminum Smelters in the Northwest 

    E-Print Network [OSTI]

    Foley, T. J.

    1986-01-01

    prompted Bonneville to search for Innovative pnClng schemes designed to maintain its revenue base Bonneville's proposed strategy Includes tYing the price of electricity it seilS to tne alumlr,u~ smelters to the world price of aluminum. This paper wili... examine Bonneville's proposed pnClng strategy; it will also examine other strategies to reduce uncertainty In the region's future electriC load. BACKGROUND For well over half a century, electrical power has been a cornerstone of the PaCific Northwest...

  9. Standard specification for nuclear-grade aluminum oxide pellets

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2008-01-01

    1.1 This specification applies to pellets of aluminum oxide that may be ultimately used in a reactor core, for example, as filler or spacers within fuel, burnable poison, or control rods. In order to distinguish between the subject pellets and “burnable poison” pellets, it is established that the subject pellets are not intended to be used as neutron-absorbing material. 1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.

  10. Aluminum Bronze Alloys to Improve Furnace Component Life | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of the furnace can result in metal failure from erosion, corrosion, and thermal stress cracking. With AMO support, the Energy Industries of Ohio, Oak Ridge National...

  11. Introduction: Bencubbin-like meteorites (CB) are metal-rich chondritic breccias containing about 60 vol% metallic (Fe,Ni) [1]. Unlike the CBa (Becubbin, Weatherford,

    E-Print Network [OSTI]

    vol% metallic (Fe,Ni) [1]. Unlike the CBa (Becubbin, Weatherford, Gujba) subgroup, the CBb (HH 237 al. [4] found that the Ir/Fe, Pd/Fe and Ni/Fe ratios in unzoned metal grains in the CBa chondrites that the components of CBa and CBb chondrites formed in a giant impact: SO chondrules and unzoned metal in Gujba

  12. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Trending: Metal Oxo Bonds Trending: Metal Oxo Bonds Print Wednesday, 29 May 2013 00:00 Metal oxides are important for scientific and technical applications in a variety of...

  13. Operation of an aluminum-intensive vehicle : report on a six-year project.

    SciTech Connect (OSTI)

    Gaines, L. L.; Cuenca, R. M.

    2002-05-02

    In 1994, Ford produced a small demonstration fleet of Mercury Sables with aluminum bodies. Argonne National Laboratory obtained one of these vehicles on a lease so that Laboratory staff could observe the wear characteristics of the body under normal operating conditions. The vehicle was placed in the transportation pool, parked outdoors, and used by staff members for both local and longer trips. The vehicle performed normally, except for having particularly good acceleration because of its light weight and highpower SHO engine. No significant problems were encountered that related to the Al body or engine. No special driving protocols were observed, but a log was kept of trip lengths and fuel purchases. Fuel economy was observed to be improved, compared with that of a similar conventional steel-bodied vehicle that was available for one year of the lease period. The vehicle was tested on a chassis dynamometer to obtain emissions and fuel economy over the federal test cycle. The impacts of further mass reduction were also simulated. At the end of the lease, the body was in excellent condition, which we documented with a set of detailed photographs before the vehicle was returned to Ford. There were minor imperfections in the painted surface, probably resulting from the omission of an E-coat during the painting process. We also examined three similar conventional vehicles for comparison; these exhibited varying degrees of rust.

  14. Spectroscopic studies of metal growth on oxides 

    E-Print Network [OSTI]

    Luo, Kai

    2000-01-01

    of metal clusters on well-defined oxide surfaces. In this work, the nucleation and growth modes of Ag on TiO?(110)(1x1) and (1x2) surfaces, Ag on ultra-thin Al?O? films, and Au on ultra-thin SiO? films were studied by scanning tunneling microscopy (STM...

  15. Inert anode containing oxides of nickel, iron and zinc useful for the electrolytic production of metals

    DOE Patents [OSTI]

    Ray, Siba P. (Murrysville, PA); Weirauch, Jr., Douglas A. (Murrysville, PA); Liu, Xinghua (Monroeville, PA)

    2002-01-01

    An inert anode for the electrolytic production of metals such as aluminum is disclosed. The inert anode includes a ceramic oxide material preferably made from NiO, Fe.sub.2 O.sub.3 and ZnO. The inert anode composition may comprise the following mole fractions of NiO, Fe.sub.2 O.sub.3 and ZnO: 0.2 to 0.99 NiO; 0.0001 to 0.8 Fe.sub.2 O.sub.3 ; and 0.0001 to 0.3 ZnO. The inert anode may optionally include other oxides and/or at least one metal phase, such as Cu, Ag, Pd, Pt, Au, Rh, Ru, Ir and/or Os. The Ni--Fe--Co--O ceramic material exhibits very low solubility in Hall cell baths used to produce aluminum.

  16. Inert anode containing oxides of nickel iron and cobalt useful for the electrolytic production of metals

    DOE Patents [OSTI]

    Ray, Siba P. (Murrysville, PA); Liu, Xinghua (Monroeville, PA); Weirauch, Jr., Douglas A. (Murrysville, PA)

    2002-01-01

    An inert anode for the electrolytic production of metals such as aluminum is disclosed. The inert anode includes a ceramic oxide material preferably made from NiO, Fe.sub.2 O.sub.3 and CoO. The inert anode composition may comprise the following mole fractions of NiO, Fe.sub.2 O.sub.3 and CoO: 0.15 to 0.99 NiO; 0.0001 to 0.85 Fe.sub.2 O.sub.3 ; and 0.0001 to 0.45 CoO. The inert anode may optionally include other oxides and/or at least one metal phase, such as Cu, Ag, Pd, Pt, Au, Rh, Ru, Ir and/or Os. The Ni--Fe--Co--O ceramic material exhibits very low solubility in Hall cell baths used to produce aluminum.

  17. Electrical and mechanical studies of high purity aluminum single crystals at 4.2 K under cyclic strain 

    E-Print Network [OSTI]

    Zou, Hong

    1995-01-01

    The objective of this research is to investigate the effects of orientation on strain hardening and resistivity degradation in high purity aluminum single crystals resulting from uniaxial cyclic strain at 4.2 K. Aluminum crystals with various...

  18. Life-cycle energy savings potential from aluminum-intensive vehicles

    SciTech Connect (OSTI)

    Stodolsky, F.; Vyas, A.; Cuenca, R.; Gaines, L.

    1995-07-01

    The life-cycle energy and fuel-use impacts of US-produced aluminum-intensive passenger cars and passenger trucks are assessed. The energy analysis includes vehicle fuel consumption, material production energy, and recycling energy. A model that stimulates market dynamics was used to project aluminum-intensive vehicle market shares and national energy savings potential for the period between 2005 and 2030. We conclude that there is a net energy savings with the use of aluminum-intensive vehicles. Manufacturing costs must be reduced to achieve significant market penetration of aluminum-intensive vehicles. The petroleum energy saved from improved fuel efficiency offsets the additional energy needed to manufacture aluminum compared to steel. The energy needed to make aluminum can be reduced further if wrought aluminum is recycled back to wrought aluminum. We find that oil use is displaced by additional use of natural gas and nonfossil energy, but use of coal is lower. Many of the results are not necessarily applicable to vehicles built outside of the United States, but others could be used with caution.

  19. Study of Dislocation Densities Through the Thickness of 7050 Aluminum Cory Parker, David Field

    E-Print Network [OSTI]

    Collins, Gary S.

    Study of Dislocation Densities Through the Thickness of 7050 Aluminum Cory Parker, David Field WSU number DMR-1062898. Introduction 7050 Aluminum is a lightweight, yet strong, alloy primarily used rather difficult due to the presence of a wide range of particles in the substrate. 7050 goes through

  20. Fracture response of externally flawed aluminum cylindrical shells under internal gaseous detonation loading

    E-Print Network [OSTI]

    Barr, Al

    Fracture response of externally flawed aluminum cylindrical shells under internal gaseous. Experiments were performed to observe the fracture behavior of thin- wall and initially-flawed aluminum tubes to different fracture events are analyzed. Keywords: tube fracture, detonation, crack branching, crack curving

  1. Anodic Aluminum Oxide Templated Channel Electrodes via Atomic Layer A. B. F. Martinsona,b

    E-Print Network [OSTI]

    Anodic Aluminum Oxide Templated Channel Electrodes via Atomic Layer Deposition A. B. F. Martinsona of transparent, semiconducting oxides via atomic layer deposition may allow for significantly faster charge aluminum oxide membranes via atomic layer deposition. Introduction Dye sensitized solar cells (DSSCs

  2. Comparative study of the growth of sputtered aluminum oxide films on organic and inorganic substrates

    E-Print Network [OSTI]

    Schreiber, Frank

    coatings as they are used, e.g., in gas-turbine engines [2]. Ultrathin and well-ordered aluminum oxide material aluminum oxide in inorganic and also organic heterostructures. Atomic force microscopy studies such as microelectronics, optics and coating technology. Because of its extraordinary mechanical, electrical, thermal

  3. A thermomechanical study of the effects of mold topography on the solidification of Aluminum alloys

    E-Print Network [OSTI]

    Zabaras, Nicholas J.

    1 A thermomechanical study of the effects of mold topography on the solidification of Aluminum-3801, USA A thermomechanical study of the effects of mold topography on the solidification of Aluminum alloys at early times is provided. The various coupling mechanisms between the solid-shell and mold

  4. Reactive codoping of GaAlInP compound semiconductors

    DOE Patents [OSTI]

    Hanna, Mark Cooper (Boulder, CO); Reedy, Robert (Golden, CO)

    2008-02-12

    A GaAlInP compound semiconductor and a method of producing a GaAlInP compound semiconductor are provided. The apparatus and method comprises a GaAs crystal substrate in a metal organic vapor deposition reactor. Al, Ga, In vapors are prepared by thermally decomposing organometallic compounds. P vapors are prepared by thermally decomposing phospine gas, group II vapors are prepared by thermally decomposing an organometallic group IIA or IIB compound. Group VIB vapors are prepared by thermally decomposing a gaseous compound of group VIB. The Al, Ga, In, P, group II, and group VIB vapors grow a GaAlInP crystal doped with group IIA or IIB and group VIB elements on the substrate wherein the group IIA or IIB and a group VIB vapors produced a codoped GaAlInP compound semiconductor with a group IIA or IIB element serving as a p-type dopant having low group II atomic diffusion.

  5. Process for mitigating corrosion and increasing the conductivity of steel studs in soderberg anodes of aluminum reduction cells

    DOE Patents [OSTI]

    Oden, Laurance L. (Albany, OR); White, Jack C. (Albany, OR); Ramsey, James A. (The Dalles, OR)

    1994-01-01

    A corrosion resistant electrically conductive coating on steel anode studs used in the production of aluminum by electrolysis.

  6. In situ remediation process using divalent metal cations

    DOE Patents [OSTI]

    Brady, Patrick V.; Khandaker, Nadim R.; Krumhansl, James L.; Teter, David M.

    2004-12-14

    An in situ process for treating ambient solid materials (e.g., soils, aquifer solids, sludges) by adding one or more divalent metal cations to the ambient solid material. The added divalent metal cations, such as Cu.sup.2+ or Zn.sup.2+, combine with metal oxide/hydroxides (e.g., ferric oxide/hydroxide or aluminum oxide/hydroxide) already present in the ambient solid material to form an effective sorbent material having a large number of positively-charged surface complexes that binds and immobilizes anionic contaminant species (e.g., arsenic or chromate). Divalent metal cations can be added, for example, by injecting an aqueous solution of CuSO.sub.4 into an aquifer contaminated with arsenic or chromate. Also, sludges can be stabilized against leaching of anionic contaminants through the addition of divalent metal cations. Also, an inexpensive sorbent material can be easily formed by mixing divalent metal cations with soil that has been removed from the ground.

  7. Semiconductor structures having electrically insulating and conducting portions formed from an AlSb-alloy layer

    DOE Patents [OSTI]

    Spahn, Olga B. (Albuquerque, NM); Lear, Kevin L. (Albuquerque, NM)

    1998-01-01

    A semiconductor structure. The semiconductor structure comprises a plurality of semiconductor layers formed on a substrate including at least one layer of a III-V compound semiconductor alloy comprising aluminum (Al) and antimony (Sb), with at least a part of the AlSb-alloy layer being chemically converted by an oxidation process to form superposed electrically insulating and electrically conducting portions. The electrically insulating portion formed from the AlSb-alloy layer comprises an oxide of aluminum (e.g. Al.sub.2 O.sub.3), while the electrically conducting portion comprises Sb. A lateral oxidation process allows formation of the superposed insulating and conducting portions below monocrystalline semiconductor layers for forming many different types of semiconductor structures having particular utility for optoelectronic devices such as light-emitting diodes, edge-emitting lasers, vertical-cavity surface-emitting lasers, photodetectors and optical modulators (waveguide and surface normal), and for electronic devices such as heterojunction bipolar transistors, field-effect transistors and quantum-effect devices. The invention is expected to be particularly useful for forming light-emitting devices for use in the 1.3-1.6 .mu.m wavelength range, with the AlSb-alloy layer acting to define an active region of the device and to effectively channel an electrical current therein for efficient light generation.

  8. Energy Saving Melting and Revert Reduction Technology: Innovative Semi-Solid Metal (SSM) Processing

    SciTech Connect (OSTI)

    Diran Apelian

    2012-08-15

    Semi-solid metal (SSM) processing has emerged as an attractive method for near-net-shape manufacturing due to the distinct advantages it holds over conventional near-net-shape forming technologies. These advantages include lower cycle time, increased die life, reduced porosity, reduced solidification shrinkage, improved mechanical properties, etc. SSM processing techniques can not only produce the complex dimensional details (e.g. thin-walled sections) associated with conventional high-pressure die castings, but also can produce high integrity castings currently attainable only with squeeze and low-pressure permanent mold casting processes. There are two primary semi-solid processing routes, (a) thixocasting and (b) rheocasting. In the thixocasting route, one starts from a non-dendritic solid precursor material that is specially prepared by a primary aluminum manufacturer, using continuous casting methods. Upon reheating this material into the mushy (a.k.a. "two-phase") zone, a thixotropic slurry is formed, which becomes the feed for the casting operation. In the rheocasting route (a.k.a. "slurry-on-demand" or "SoD"), one starts from the liquid state, and the thixotropic slurry is formed directly from the melt via careful thermal management of the system; the slurry is subsequently fed into the die cavity. Of these two routes, rheocasting is favored in that there is no premium added to the billet cost, and the scrap recycling issues are alleviated. The CRP (Trade Marked) is a process where the molten metal flows through a reactor prior to casting. The role of the reactor is to ensure that copious nucleation takes place and that the nuclei are well distributed throughout the system prior to entering the casting cavity. The CRP (Trade Marked) has been successfully applied in hyper-eutectic Al-Si alloys (i.e., 390 alloy) where two liquids of equal or different compositions and temperatures are mixed in the reactor and creating a SSM slurry. The process has been mostly used for hypo-eutectic Al-Si alloys (i.e., 356, 357, etc.) where a single melt passes through the reactor. In addition, the CRP (Trade Marked) was designed to be flexible for thixocasting or rheocasting applications as well as batch or continuous casting. Variable heat extraction rates can be obtained by controlling either the superheat of the melt, the temperature of the channel system, or the temperature of the reactor. This program had four main objectives all of which were focused on a mechanistic understanding of the process in order to be able to scale it up, to develop it into a robust process,and for SSM processing to be commercially used.

  9. In situ fabrication of blue ceramic coatings on wrought Al Alloy 2024 by plasma electrolytic oxidation

    SciTech Connect (OSTI)

    Wang Zhijiang; Nie Xueyuan; Hu, Henry; Hussein, Riyad O.

    2012-03-15

    In situ formation of ceramic coatings on 2024 Al alloy with a blue color was successfully achieved using a plasma electrolytic oxidation process working at atmospheric pressure. This novel blue ceramic coating overcomes the shortcomings of surface treatments resulting from conventional dyeing processes by depositing organic dyes into the porous structure of anodic film, which has poor resistance to abrasion and rapid fading when exposed to sunlight. X-ray diffraction, scanning electron microscopy, and energy dispersive spectroscopy were employed to characterize the microstructure of the blue ceramic coating. The fabricated ceramic coating was composed of CoAl{sub 2}O{sub 4}, {alpha}-Al{sub 2}O{sub 3}, and {gamma}-Al{sub 2}O{sub 3.} By controlling the working parameters, the distribution of the CoAl{sub 2}O{sub 4} phase on the surface can be adjusted, and plays a key role in the appearance of the coating. Electrochemical testing, thermal cycling method, and pin-on-disk sliding wear testing were employed to evaluate corrosion, thermal cycling, and wear resistance of the ceramic coatings. The results indicate that the blue ceramic coating has a similar polarization resistance to that of conventional anodic film and can significantly enhance the corrosion resistance of aluminum alloy. There are no destructive horizontal cracks observed within the blue ceramic coating when subjected to 120 times of thermal cycling, which heats the samples up to 573 K and followed by submersion in water at room temperature for 10 min. Compared with the aluminum substrate as well as a conventional anodic film coated aluminum sample, the wear resistance of the blue ceramic coating coated sample was significantly increased while the coefficient of friction was decreased from 0.34 to 0.14.

  10. Oxidation of Al doped Au clusters: A first principles study

    SciTech Connect (OSTI)

    Rajesh, Chinagandham [RMC, Bhabha Atomic Research Centre, Trombay, Mumbai 400 085 (India); Majumder, Chiranjib [Chemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400 085 (India)

    2009-06-21

    Using first principles method we report the oxidation of Al doped Au clusters. This work is divided into two parts: (i) the equilibrium structures and stability of Al doped Au{sub n-1} clusters (n=2-7,21) and (ii) the interaction of O{sub 2} with stable clusters. The calculations are performed using the plane wave pseudopotential approach under the density functional theory and generalized gradient approximation for the exchange and correlation functional. The optimized geometries of Au{sub n-1}Al clusters indicate that the substitution of Au by Al results an early onset of three-dimensional structures from tetramer onwards. This is different from the results of transition metal doped Au clusters, where the planar conformation of Au clusters retains up to heptamer. The stability of Au{sub n-1}Al clusters has been analyzed based on the binding energy, second difference in energy, and the energy gaps between the highest occupied molecular orbital and lowest unoccupied molecular orbital energy levels. Based on the energetics, the Au{sub 3}Al and Au{sub 5}Al clusters are found to have extraordinary stability. The oxidation mechanism of Al doped Au clusters have been studied by the interaction of O{sub 2} with Al, Au, AuAl, Au{sub 3}Al, and Au{sub 20}Al clusters. It is found that the oxidation of Au{sub n-1}Al clusters undergoes via dissociative mechanism, albeit significant charge transfer from Al to Au. Moreover, the O{sub 2} molecule prefers to attach at the Al site rather than at the Au site.

  11. Sizing and burn time measurements of micron-sized metal powders

    SciTech Connect (OSTI)

    Gill, Robert J.; Mohan, Salil; Dreizin, Edward L. [New Jersey Institute of Technology Newark, New Jersey 07102 (United States)

    2009-06-15

    Detailed ignition and combustion mechanisms are needed to develop optimized propellant and energetic formulations using micron-sized metal powders, such as aluminum. Combustion researchers have traditionally used relatively coarse metal particles to characterize the burn time dependence on particle size. However, measurements of burn times for particles below 10 {mu}m in diameter are still needed for aluminum powders and other metal fuels. The apparatus described here sizes the particles just before the ignition event, providing a direct correlation between individual particle size and its burn time. Two lasers were utilized: a 785 nm laser diode for sizing the particles and a 125 W CO{sub 2} laser for particle ignition. The particles crossed the 785 nm laser beam just before crossing the CO{sub 2} laser beam. The particle size was determined from the amplitude of the scattered 785 nm light pulse. The burn time was determined from the duration of the visible light emission produced from the ignited particle. The in situ measured particle size distributions compared well with the size distributions measured for the same powders by a commercial instrument using low angle laser light scattering. Our measurements with two nominally spherical aluminum powders, suggest that the burn times increase from 0.5 to {approx}2.5 ms as the particle diameters increase from 3 to 8 {mu}m.

  12. Trace metal concentration and fish size: Variation among fish species in a Mediterranean river

    E-Print Network [OSTI]

    García-Berthou, Emili

    Trace metal concentration and fish size: Variation among fish species in a Mediterranean river 29 April 2014 Accepted 12 May 2014 Keywords: Bioaccumulation Heavy metals Llobregat River Mediterranean Cyprinid fish a b s t r a c t Concentration of trace metals (Al, Mn, Fe, Co, Ni, Cu, Zn, Cd, Pb

  13. Heavy metal biosensor

    DOE Patents [OSTI]

    Hillson, Nathan J; Shapiro, Lucille; Hu, Ping; Andersen, Gary L

    2014-04-15

    Compositions and methods are provided for detection of certain heavy metals using bacterial whole cell biosensors.

  14. Influence of hydrogen and hydrogen/methane plasmas on AlN thin films

    SciTech Connect (OSTI)

    Pobedinskas, P. Hardy, A.; Van Bael, M. K.; Haenen, K.; Degutis, G.; Dexters, W.

    2014-02-24

    Polycrystalline aluminum nitride (AlN) thin films are exposed to hydrogen and hydrogen/methane plasmas at different conditions. The latter plays an indispensable role in the subsequent deposition of nanocrystalline diamond thin films on AlN. The changes of AlN properties are investigated by means of Fourier transform infrared (FTIR) and Raman spectroscopies as well as atomic force microscopy. The E{sub 1}(TO) and E{sub 2}{sup 2} phonon mode frequencies blue-shift after the exposure to plasmas. The damping constant of E{sub 1}(TO) phonon, calculated from FTIR transmission spectra using the factorized model of a damped oscillator, and the width of E{sub 2}{sup 2} peak in Raman spectra decrease with increasing substrate temperature till the decomposition of AlN thin film becomes notable. It is proven that these changes are driven by the plasmas as annealing in vacuum does not induce them.

  15. Formability Prediction Of Aluminum Sheet In Automotive Applications

    SciTech Connect (OSTI)

    Leppin, Christian; Daniel, Dominique; Shahani, Ravi; Gese, Helmut; Dell, Harry

    2007-05-17

    In the following paper, a full mechanical characterization of the AA6016 T4 aluminum alloy car body sheet DR100 is presented. A comprehensive experimental program was performed to identify and model the orthotopic elasto-plastic deformation behavior of the material and its fracture characteristics including criteria for localized necking, ductile fracture and shear fracture. The commercial software package MF GenYld + CrachFEM in combination with the explicit finite element code Ls-Dyna is used to validate the quality of the material model with experiments, namely, prediction of the FLD, deep drawing with a cross-shaped punch and finally, analysis of a simplified hemming process using a solid discretization of the problem. The focus is on the correct prediction of the limits of the material in such processes.

  16. AlGaAsSb/GaSb Distributed Bragg Reflectors Grown by Organometallic Vapor Phase Epitaxy

    SciTech Connect (OSTI)

    C.A. Wang; C.J. Vineis; D.R. Calawa

    2002-02-13

    The first AlGaAsSb/GaSb quarter-wave distributed Bragg reflectors grown by metallic vapor phase epitaxy are reported. The peak reflectance is 96% for a 10-period structure.

  17. Porous anodic aluminum oxide scaffolds; formation mechanisms and applications

    E-Print Network [OSTI]

    Oh, Jihun

    2010-01-01

    Nanoporous anodic aluminium oxide (AAO) can be created with pores that self-assemble into ordered configurations. Nanostructured metal oxides have proven to be very useful as scaffolds for growth of nanowires and nanotubes ...

  18. DOE - Office of Legacy Management -- Hunter Douglas Aluminum...

    Office of Legacy Management (LM)

    , California CA.11-1 Evaluation Year: 1995 CA.11-2 Site Operations: Fabricated uranium metal tubing during the late 1950s. CA.11-1 Site Disposition: Eliminated - No Authority -...

  19. Microstructural characterization of superplastic aluminum-lithium alloys 

    E-Print Network [OSTI]

    Balasubramanian, Rajasekaran

    1991-01-01

    . 3 G. B. S. , Accommodation by Grain Boundary Sliding 1. 6. 2. 4 Summary 13 14 15 2. EXPERIMENTAL PROCEDURE 2. 1 Alloy Composition . 2. 2 Processing Details 2. 3 Mechanical Testing 2. 4 Microstructural Evaluation 17 17 17 19 21 2, 4. 1... obtained (& 200%) are small in comparison with the pseudo single phase metallic materials, but they are significant in comparison with structural ceramics ' ' . 1. 3 Mechanics of Superplasticity Superplastic metallic alloys have one property in common...

  20. Aluminum Leaching of ''Archived'' Sludge from Tanks 8F, 11H, and 12H

    SciTech Connect (OSTI)

    FONDEUR, FERNANDOF.

    2004-03-12

    Aluminum can promote formation or dissolution of networks in hydroxide solid solutions. When present in large amounts it will act as a network former increasing both the viscosity and the surface tension of melts. This translates into poor free flow properties that affect pour rate of glass production in the Defense Waste Processing Facility (DWPF). To mitigate this situation, DWPF operations limit the amount of aluminum contained in sludge. This study investigated the leaching of aluminum compounds from archived sludge samples. The conclusions found boehmite present as the predominant aluminum compound in sludge from two tanks. We did not identify an aluminum compound in sludge from the third tank. We did not detect any amorphous aluminum hydroxide in the samples. The amount of goethite measured 4.2 percentage weight while hematite measured 3.7 percentage weight in Tank 11H sludge. The recommended recipe for removing gibbsite in sludge proved inefficient for digesting boehmite, removing less than 50 per cent of the compound within 48 hours. The recipe did remove boehmite when the test ran for 10 days (i.e., 7 more days than the recommended baseline leaching period). Additions of fluoride and phosphate to Tank 12H archived sludge did not improve the aluminum leaching efficiency of the baseline recipe.

  1. MELT RATE ENHANCEMENT FOR HIGH ALUMINUM HLW (HIGH LEVEL WASTE) GLASS FORMULATION FINAL REPORT 08R1360-1

    SciTech Connect (OSTI)

    KRUGER AA; MATLACK KS; KOT W; PEGG IL; JOSEPH I; BARDAKCI T; GAN H; GONG W; CHAUDHURI M

    2010-01-04

    This report describes the development and testing of new glass formulations for high aluminum waste streams that achieve high waste loadings while maintaining high processing rates. The testing was based on the compositions of Hanford High Level Waste (HLW) with limiting concentrations of aluminum specified by the Office of River Protection (ORP). The testing identified glass formulations that optimize waste loading and waste processing rate while meeting all processing and product quality requirements. The work included preparation and characterization of crucible melts and small scale melt rate screening tests. The results were used to select compositions for subsequent testing in a DuraMelter 100 (DM100) system. These tests were used to determine processing rates for the selected formulations as well as to examine the effects of increased glass processing temperature, and the form of aluminum in the waste simulant. Finally, one of the formulations was selected for large-scale confirmatory testing on the HLW Pilot Melter (DM1200), which is a one third scale prototype of the Hanford Tank Waste Treatment and Immobilization Plant (WTP) HLW melter and off-gas treatment system. This work builds on previous work performed at the Vitreous State Laboratory (VSL) for Department of Energy (DOE) to increase waste loading and processing rates for high-iron HLW waste streams as well as previous tests conducted for ORP on the same high-aluminum waste composition used in the present work and other Hanford HLW compositions. The scope of this study was outlined in a Test Plan that was prepared in response to an ORP-supplied statement of work. It is currently estimated that the number of HLW canisters to be produced in the WTP is about 13,500 (equivalent to 40,500 MT glass). This estimate is based upon the inventory of the tank wastes, the anticipated performance of the sludge treatment processes, and current understanding of the capability of the borosilicate glass waste form. The WTP HLW melter design, unlike earlier DOE melter designs, incorporates an active glass bubbler system. The bubblers create active glass pool convection and thereby improve heat transfer and glass melting rate. The WTP HLW melter has a glass surface area of 3.75 m{sup 2} and depth of {approx}1.1 m. The two melters in the HLW facility together are designed to produce up to 7.5 MT of glass per day at 100% availability. Further increases in HLW waste processing rates can potentially be achieved by increasing the melter operating temperature above 1150 C and by increasing the waste loading in the glass product. Increasing the waste loading also has the added benefit of decreasing the number of canisters for storage. The current estimates and glass formulation efforts have been conservative in terms of achievable waste loadings. These formulations have been specified to ensure that the glasses are homogenous, contain essentially no crystalline phases, are processable in joule-heated, ceramic-lined melters and meet WTP Contract terms. The WTP's overall mission will require the immobilization of tank waste compositions that are dominated by mixtures of aluminum (Al), chromium (Cr), bismuth (Bi), iron (Fe), phosphorous (P), zirconium (Zr), and sulfur (S) compounds as waste-limiting components. Glass compositions for these waste mixtures have been developed based upon previous experience and current glass property models. Recently, DOE has initiated a testing program to develop and characterize HLW glasses with higher waste loadings. Results of this work have demonstrated the feasibility of increases in wasteloading from about 25 wt% to 33-50 wt% (based on oxide loading) in the glass depending on the waste stream. It is expected that these higher waste loading glasses will reduce the HLW canister production requirement by about 25% or more.

  2. Comparing Laser Welding Technologies with Friction Stir Welding for Production of Aluminum Tailor-Welded Blanks

    SciTech Connect (OSTI)

    Hovanski, Yuri; Carsley, John; Carlson, Blair; Hartfield-Wunsch, Susan; Pilli, Siva Prasad

    2014-01-15

    A comparison of welding techniques was performed to determine the most effective method for producing aluminum tailor-welded blanks for high volume automotive applications. Aluminum sheet was joined with an emphasis on post weld formability, surface quality and weld speed. Comparative results from several laser based welding techniques along with friction stir welding are presented. The results of this study demonstrate a quantitative comparison of weld methodologies in preparing tailor-welded aluminum stampings for high volume production in the automotive industry. Evaluation of nearly a dozen welding variations ultimately led to down selecting a single process based on post-weld quality and performance.

  3. Enhanced structural color generation in aluminum metamaterials coated with a thin polymer layer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cheng, Fei; Yang, Xiaodong; Rosenmann, Daniel; Stan, Liliana; Czaplewski, David; Gao, Jie

    2015-09-18

    A high-resolution and angle-insensitive structural color generation platform is demonstrated based on triple-layer aluminum-silica-aluminum metamaterials supporting surface plasmon resonances tunable across the entire visible spectrum. The color performances of the fabricated aluminum metamaterials can be strongly enhanced by coating a thin transparent polymer layer on top. The results show that the presence of the polymer layer induces a better impedance matching for the plasmonic resonances to the free space so that strong light absorption can be obtained, leading to the generation of pure colors in cyan, magenta, yellow and black (CMYK) with high color saturation.

  4. Twelve Year Study of Underground Corrosion of Activated Metals

    SciTech Connect (OSTI)

    M. Kay Adler Flitton; Timothy S. Yoder

    2012-03-01

    The subsurface radioactive disposal facility located at the U.S. Department of Energy’s Idaho site contains neutron-activated metals from non-fuel nuclear-reactor-core components. A long-term corrosion study is being conducted to obtain site-specific corrosion rates to support efforts to more accurately estimate the transfer of activated elements in an arid vadose zone environment. The study uses non-radioactive metal coupons representing the prominent neutron-activated material buried at the disposal location, namely, two types of stainless steels, welded stainless steel, welded nickel-chromium steel alloy, zirconium alloy, beryllium, and aluminum. Additionally, carbon steel (the material used in cask disposal liners and other disposal containers) and duplex stainless steel (high-integrity containers) are also included in the study. This paper briefly describes the test program and presents the corrosion rate results through twelve years of underground exposure.

  5. Influence of growth temperature on electrical, optical, and plasmonic properties of aluminum:zinc oxide films grown by radio frequency magnetron sputtering

    SciTech Connect (OSTI)

    Dondapati, Hareesh; Santiago, Kevin; Pradhan, A. K.

    2013-10-14

    We have investigated the responsible mechanism for the observation of metallic conductivity at room temperature and metal-semiconductor transition (MST) at lower temperatures for aluminum-doped zinc oxide (AZO) films. AZO films were grown on glass substrates by radio-frequency magnetron sputtering with varying substrate temperatures (T{sub s}). The films were found to be crystalline with the electrical resistivity close to 1.1 × 10{sup ?3} ? cm and transmittance more than 85% in the visible region. The saturated optical band gap of 3.76 eV was observed for the sample grown at T{sub s} of 400 °C, however, a slight decrease in the bandgap was noticed above 400 °C, which can be explained by Burstein–Moss effect. Temperature dependent resistivity measurements of these highly conducting and transparent films showed a MST at ?110 K. The observed metal-like and metal-semiconductor transitions are explained by taking into account the Mott phase transition and localization effects due to defects. All AZO films demonstrate crossover in permittivity from positive to negative and low loss in the near-infrared region, illustrating its applications for plasmonic metamaterials, including waveguides for near infrared telecommunication region. Based on the results presented in this study, the low electrical resistivity and high optical transmittance of AZO films suggested a possibility for the application in the flexible electronic devices, such as transparent conducting oxide film on LEDs, solar cells, and touch panels.

  6. METAL NANOPARTICLES FUNCTIONALIZED WITH METAL-LIGAND COVALENT BONDS

    E-Print Network [OSTI]

    Kang, Xiongwu

    2012-01-01

    Formation of catalytic metal-molecule contacts. Science,of Organotransition Metal Compounds. Advances inof highly monodisperse metal nanoparticles. Journal of the

  7. Metal halogen electrochemical cell

    SciTech Connect (OSTI)

    Walsh, F.M.

    1986-06-03

    An electrochemical cell is described having a metal anode selected from the group consisting of zinc and cadmium; a bromine cathode; and, an aqueous electrolyte containing a metal bromide, the metal having the same metal as the metal of the anode, the improvement comprising: a bromine complexing agent in the aqueous metal bromide electrolyte consisting solely of a tetraorgano substituted ammonium salt, which salt is soluble of water and forms and substantially water immiscible liquid bromine complex at temperatures in the range of about 10/sup 0/C. to about 60/sup 0/C. and wherein the tetraorgano substituted ammonium salt is selected from asymmetric quaternary ammonium compounds.

  8. Metal-Air Batteries

    SciTech Connect (OSTI)

    Zhang, Jiguang; Bruce, Peter G.; Zhang, Gregory

    2011-08-01

    Metal-air batteries have much higher specific energies than most currently available primary and rechargeable batteries. Recent advances in electrode materials and electrolytes, as well as new designs on metal-air batteries, have attracted intensive effort in recent years, especially in the development of lithium-air batteries. The general principle in metal-air batteries will be reviewed in this chapter. The materials, preparation methods, and performances of metal-air batteries will be discussed. Two main metal-air batteries, Zn-air and Li-air batteries will be discussed in detail. Other type of metal-air batteries will also be described.

  9. Metal organic chemical vapor deposition of 111-v compounds on silicon

    DOE Patents [OSTI]

    Vernon, Stanley M. (Wellesley, MA)

    1986-01-01

    Expitaxial composite comprising thin films of a Group III-V compound semiconductor such as gallium arsenide (GaAs) or gallium aluminum arsenide (GaAlAs) on single crystal silicon substrates are disclosed. Also disclosed is a process for manufacturing, by chemical deposition from the vapor phase, epitaxial composites as above described, and to semiconductor devices based on such epitaxial composites. The composites have particular utility for use in making light sensitive solid state solar cells.

  10. CONTAINMENT EVALUATION OF BREACHED AL-SNF FOR CASK TRANSPORT

    SciTech Connect (OSTI)

    Vinson, D. W.; Sindelar, R. L.; Iyer, N. C.

    2005-11-07

    Aluminum-based spent nuclear fuel (Al-SNF) from foreign and domestic research reactors (FRR/DRR) is being shipped to the Savannah River Site. To enter the U.S., the cask with loaded fuel must be certified to comply with the requirements in the Title 10 of the U.S. Code of Federal Regulations, Part 71. The requirements include demonstration of containment of the cask with its contents under normal and accident conditions. Al-SNF is subject to corrosion degradation in water storage, and many of the fuel assemblies are ''failed'' or have through-clad damage. A methodology has been developed with technical bases to show that Al-SNF with cladding breaches can be directly transported in standard casks and maintained within the allowable release rates. The approach to evaluate the limiting allowable leakage rate, L{sub R}, for a cask with breached Al-SNF for comparison to its test leakage rate could be extended to other nuclear material systems. The approach for containment analysis of Al-SNF follows calculations for commercial spent fuel as provided in NUREG/CR-6487 that adopts ANSI N14.5 as a methodology for containment analysis. The material-specific features and characteristics of damaged Al-SNF (fuel materials, fabrication techniques, microstructure, radionuclide inventory, and vapor corrosion rates) that were derived from literature sources and/or developed in laboratory testing are applied to generate the four containment source terms that yield four separate cask cavity activity densities; namely, those from fines; gaseous fission product species; volatile fission product species; and fuel assembly crud. The activity values, A{sub 2}, are developed per the guidance of 10CFR71. The analysis is performed parametrically to evaluate maximum number of breached assemblies and exposed fuel area for a proposed shipment in a cask with a test leakage rate.

  11. Metal-Ion-Mediated Reactions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Metal-Ion-Mediated Reactions Metal-Ion-Mediated Reactions Print Monday, 19 December 2011 18:29 While mononuclear, polynuclear, and polymeric metal complexes are most often...

  12. Intramolecular electronic communication between dimetal units with multiple metal??al bonds 

    E-Print Network [OSTI]

    Li, Zhong

    2009-05-15

    . For example, [Mo 2 (cis?DAniF) 2 ] 2 (??Cl 4 ) has a large ?E 1/2 value of 540 mV, which corresponds to a comproportionation constant of 1.3 ? 10 9 . Because of the large comproportionation constant, oxidation of the neutral precursor gives a mixed...V/s, and 0.10 M Bu 4 NPF 6 (in CH 2 Cl 2 ) as electrolyte. The EPR spectrum was recorded on a Bruker ESP300 spectrometer and Magnetic susceptibility measurements were performed on a Quantum Design SQUID MPMS?XL magnetometer. Preparation of [Mo 2 (DAniF) 3...

  13. Method for producing nanostructured metal-oxides

    DOE Patents [OSTI]

    Tillotson, Thomas M.; Simpson, Randall L.; Hrubesh, Lawrence W.; Gash, Alexander

    2006-01-17

    A synthetic route for producing nanostructure metal-oxide-based materials using sol-gel processing. This procedure employs the use of stable and inexpensive hydrated-metal inorganic salts and environmentally friendly solvents such as water and ethanol. The synthesis involves the dissolution of the metal salt in a solvent followed by the addition of a proton scavenger, which induces gel formation in a timely manner. Both critical point (supercritical extraction) and atmospheric (low temperature evaporation) drying may be employed to produce monolithic aerogels and xerogels, respectively. Using this method synthesis of metal-oxide nanostructured materials have been carried out using inorganic salts, such as of Fe.sup.3+, Cr.sup.3+, Al.sup.3+, Ga.sup.3+, In.sup.3+, Hf.sup.4+, Sn.sup.4+, Zr.sup.4+, Nb.sup.5+, W.sup.6+, Pr.sup.3+, Er.sup.3+, Nd.sup.3+, Ce.sup.3+, U.sup.3+ and Y.sup.3+. The process is general and nanostructured metal-oxides from the following elements of the periodic table can be made: Groups 2 through 13, part of Group 14 (germanium, tin, lead), part of Group 15 (antimony, bismuth), part of Group 16 (polonium), and the lanthanides and actinides. The sol-gel processing allows for the addition of insoluble materials (e.g., metals or polymers) to the viscous sol, just before gelation, to produce a uniformly distributed nanocomposites upon gelation. As an example, energetic nanocomposites of Fe.sub.xO.sub.y gel with distributed Al metal are readily made. The compositions are stable, safe, and can be readily ignited to thermitic reaction.

  14. Analytical study and cost modeling of secondary aluminum consumption for alloy producers under uncertain demands

    E-Print Network [OSTI]

    Li, Yaoqi

    2008-01-01

    A series of case studies on raw materials inventory strategy for both wrought and cast aluminum alloy productions were conducted under recourse-based modeling framework with the explicit considerations of the demand ...

  15. Design of an aluminum differential housing and driveline components for high performance applications

    E-Print Network [OSTI]

    James, Richard A. (Richard Alexander), 1982-

    2004-01-01

    The purpose of the study was to design a lightweight aluminum differential housing to replace the cast-iron housing used in the Torsen® T-1. The redesigned housing was destined for use in the 2004 MIT Formula SAE vehicle, ...

  16. Fabrication and applications of nanocomposite structures using anodized aluminum oxide membranes

    E-Print Network [OSTI]

    Gapin, Andrew Isaac

    2007-01-01

    effects of this thin oxide layer have led to numerousof an anodized aluminum oxide layer will now be examined.and thickening of the oxide layer. One critical aspect of

  17. The ultra-high lime with aluminum process for removing chloride from recirculating cooling water 

    E-Print Network [OSTI]

    Abdel-wahab, Ahmed Ibraheem Ali

    2004-09-30

    Chloride is a deleterious ionic species in cooling water systems because it is important in promoting corrosion. Chloride can be removed from cooling water by precipitation as calcium chloroaluminate using ultra-high lime with aluminum process (UHLA...

  18. Removal of Chloride from Wastewater by Advanced Softening Process Using Electrochemically Generated Aluminum Hydroxide 

    E-Print Network [OSTI]

    Mustafa, Syed Faisal

    2014-07-23

    solubility. Chloride can be removed from water and wastewater by precipitation as calcium chloroaluminate using advanced softening process. This research was conducted to evaluate chloride removal using electrochemically generated aluminum hydroxide and lime...

  19. Recycling production designs : the value of coordination and flexibility in aluminum recycling operations

    E-Print Network [OSTI]

    Brommer, Tracey H. (Tracey Helenius)

    2013-01-01

    The growing motivation for aluminum recycling has prompted interest in recycling alternative and more challenging secondary materials. The nature of these alternative secondary materials necessitates the development of an ...

  20. Iron-niobium-aluminum alloy having high-temperature corrosion resistance

    DOE Patents [OSTI]

    Hsu, Huey S.

    1988-04-14

    An alloy for use in high temperature sulfur and oxygen containing environments, having aluminum for oxygen resistance, niobium for sulfur resistance and the balance iron, is discussed. 4 figs., 2 tabs.

  1. An in-situ interdiffusion method for harvesting energy from an aluminum-water reaction

    E-Print Network [OSTI]

    Brandeau, Erich John

    2012-01-01

    Autonomous underwater vehicles (AUVs) are indispensable for countless underwater tasks but are currently limited in their range and endurance by the energy density of their battery packs. Aluminum is an ideal energy source ...

  2. Temperature-dependent Urbach tail measurements of lutetium aluminum garnet single crystals

    E-Print Network [OSTI]

    Liberman, Vladimir

    Lutetium aluminum garnet (LuAG) is the most promising candidate for a high-index lens material for use in microlithographic imaging lenses. In the deep ultraviolet spectral range the transmission of high-purity LuAG was ...

  3. Phosphate and Organic Acids as Competing Sorbates on Amorphous Aluminum Oxide. (3791)

    E-Print Network [OSTI]

    Sparks, Donald L.

    Phosphate and Organic Acids as Competing Sorbates on Amorphous Aluminum Oxide. (3791) Authors: K that organics (i.e. oxalic acid), readily present in PL, play in P retention under varying pH conditions

  4. The U5. 0 Undulator for the ALS

    SciTech Connect (OSTI)

    Hoyer, E.; Chin, J.; Halbach, K.; Hassenzahl, W.V.; Humphries, D.; Kincaid, B.; Lancaster, H.; Plate, D.

    1991-05-01

    The U5.0 Undulator, an 89 period, 5 cm period length, 4.6 m long insertion device has been designed and is in fabrication. This undulator will be the first high brightness source, in the 50 to 1500 eV range, for the Advanced Light Source (ALS) and is scheduled for completion in 1992. A modular hybrid configuration utilizing Nd-Fe-B permanent magnet material and vanadium permendur is used that achieves 0.837 Tesla effective peak field. Correction of the vertical field integral is with permanent magnet rotors at the ends. Gap adjustment is with an arrangement of roller screws, chains drives, a gear reduction unit and a stepper motor driven by a closed loop control system. The vacuum chamber design is a two-piece, machined and welded 5083-H321 aluminum construction of 5.1 m length. Magnetic design, subsystem design and fabrication progress are presented. 12 refs., 4 figs., 2 tabs.

  5. Aluminum plasma immersion ion implantation in polymers M. Ueda a,*, I.H. Tan a

    E-Print Network [OSTI]

    by a thin metal oxide layer on the polymerÕs surface. Metal implantation followed by oxidation if a metal oxide layer is formed in the surface. This can be achieved after implan- tation of metallic ions

  6. Experimental and Numerical Studies of Aluminum-Alumina Composites 

    E-Print Network [OSTI]

    Gudlur, Pradeep

    2013-07-22

    The preliminary goal of this study is to determine the effects of processing conditions, compositions and microstructural morphologies of the constituents on the physical and thermo-mechanical properties of alumina (Al_2O_3) ...

  7. Towards electroformed nanostructured aluminum alloys with high strength and ductility

    E-Print Network [OSTI]

    Ruan, Shiyun

    Nanostructured Al–Mn alloys are proposed as high-strength low-density materials, which can be electroformed (i.e., produced electrolytically and removed from the substrate) from ionic liquid. A variety of current waveforms, ...

  8. Synthesis, structural characterization and properties of SrAl{sub 4?x}Ge{sub x}, BaAl{sub 4?x}Ge{sub x}, and EuAl{sub 4?x}Ge{sub x} (x?0.3–0.4)—Rare examples of electron-rich phases with the BaAl{sub 4} structure type

    SciTech Connect (OSTI)

    Zhang, Jiliang; Bobev, Svilen, E-mail: bobev@udel.edu

    2013-09-15

    Three solid solutions with the general formula AEAl{sub 4?x}Ge{sub x} (AE=Eu, Sr, Ba; 0.32(1)?x?0.41(1)) have been synthesized via the aluminum self-flux method, and their crystal structures have been established from powder and single-crystal X-ray diffraction. They are isotypic and crystallize with the well-known BaAl{sub 4} structure type, adopted by the three AEAl{sub 4} end members. In all structures, Ge substitutes Al only at the 4e Wyckoff site. Results from X-rays photoelectron spectroscopy on EuAl{sub 4?x}Ge{sub x} and EuAl{sub 4} indicate that the interactions between the Eu{sup 2+} cations and the polyanionic framework are enhanced in the Ge-doped structure, despite the slightly elevated Fermi level. Magnetic susceptibility measurements confirm the local moment magnetism, expected for the [Xe]4f{sup 7} electronic configuration of Eu{sup 2+} and suggest strong ferromagnetic interactions at cryogenic temperatures. Resistivity data from single-crystalline samples show differences between the title compounds, implying different bonding characteristics despite the close Debye temperatures. A brief discussion on the observed electron count and homogeneity ranges for AEAl{sub 4?x}Ge{sub x} (AE=Eu, Sr, Ba) is also presented. - Graphical abstract: AEAl{sub 4?x}Ge{sub x} (AE=Eu, Sr, Ba; 0.32(1)?x?0.41(1)), three “electron-rich” phases with BaAl{sub 4} structure type have been synthesized and characterized. Display Omitted - Highlights: • Three BaAl{sub 4}-type ternary aluminum germanides have been synthesized with Eu, Sr and Ba. • Eu, Sr and Ba cations have no apparent influence on the solubility of Ge. • The Ge atoms substitute Al on one of two framework sites, thereby strengthening the interactions between the cations and the polyanionic framework.

  9. Liquid Metal Transformers

    E-Print Network [OSTI]

    Sheng, Lei; Liu, Jing

    2014-01-01

    The room temperature liquid metal is quickly emerging as an important functional material in a variety of areas like chip cooling, 3D printing or printed electronics etc. With diverse capabilities in electrical, thermal and flowing behaviors, such fluid owns many intriguing properties that had never been anticipated before. Here, we show a group of unconventional phenomena occurring on the liquid metal objects. Through applying electrical field on the liquid metals immersed in water, a series of complex transformation behaviors such as self-assembling of a sheet of liquid metal film into a single sphere, quick mergences of separate metal droplets, controlled self-rotation and planar locomotion of liquid metal objects can be realized. Meanwhile, it was also found that two accompanying water vortexes were induced and reliably swirled near the rotating liquid metal sphere. Further, effects of the shape, size, voltage, orientation and geometries of the electrodes to control the liquid metal transformers were clar...

  10. Metal phthalocyanine catalysts

    DOE Patents [OSTI]

    Ellis, P.E. Jr.; Lyons, J.E.

    1994-10-11

    A new composition of matter is described which is an alkali metal or ammonium or tetraalkylammonium diazidoperfluorophthalocyanatoferrate. Other embodiments of the invention comprise compositions wherein the metal of the coordination complex is cobalt, manganese and chromium.

  11. Metal phthalocyanine catalysts

    DOE Patents [OSTI]

    Ellis, Jr., Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA)

    1994-01-01

    As a new composition of matter, alkali metal or ammonium or tetraalkylammonium diazidoperfluorophthalocyanatoferrate. Other embodiments of the invention comprise compositions wherein the metal of the coordination complex is cobalt, manganese and chromium.

  12. Precipitation and Deposition of Aluminum-Containing Phases in Tank Wastes

    SciTech Connect (OSTI)

    Daniel M. Dabbs; Ilhan A. Aksay

    2005-01-12

    Aluminum-containing phases compose the bulk of solids precipitating during the processing of radioactive tank wastes. Processes designed to minimize the volume of high-level waste through conversion to glassy phases require transporting waste solutions near-saturated with aluminum-containing species from holding tank to processing center. The uncontrolled precipitation within transfer lines results in clogged pipes and lines and fouled ion exchangers, with the potential to shut down processing operations.

  13. Relative radiant heat absorption characteristics of two types of mirror shields and a polished aluminum shield 

    E-Print Network [OSTI]

    Herron, Steven Douglas

    1973-01-01

    RELATIVE RADIANT HEAT ABSORPTION CHARACTERISTICS OF TWO TYPES OF MIRROR SHIELDS AND A POLISHED ALUMINUM SHIELD A Thesis by STEVEN DOUGLAS HERRON Submitted to the Graduate College of Texas A&M University in partial fulfillment... of the requirement for the degree of MASTER OF SCIENCE August 1973 Major Subject: Industrial Hygiene RELATIVE RADIANT HEAT ABSORPTION CHARACTERISTICS OF TWO TYPES OF MIRROR SHIELDS AND A POLISHED ALUMINUM SHIELD A Thesis by STEVEN DOUGLAS HERRON Approved...

  14. Geometry dependence of crack growth resistance curves in thin sheet aluminum alloys 

    E-Print Network [OSTI]

    Stricklin, Lance Lee

    1988-01-01

    and 7475 aluminum alloys were cut into ~ T, 1T, 2 T compact tension specimens, fatigue precracked, and tested under displacement control at room temperature. The data were reduced using the linear elastic fracture mechanics (LEFM), Irwin plasticity... of specimens before testing; (2) the actual test procedures including data acquisition; (3) the use of several techniques including photoelastic methods for analysis. SPECIMEN PREPARATION The materials tested were a 2090 aluminum-lithium alloy and a 7475...

  15. Electronic structure investigation of the cubic inverse perovskite Sc3AlN

    E-Print Network [OSTI]

    Magnuson, Martin; Höglund, Carina; Abrikosov, Igor A; Birch, Jens; Hultman, Lars; 10.1103/PhysRevB.78.235102

    2011-01-01

    The electronic structure and chemical bonding of the recently discovered inverse perovskite Sc3AlN, in comparison to ScN and Sc metal have been investigated by bulk-sensitive soft x-ray emission spectroscopy. The measured Sc L, N K, Al L1, and Al L2,3 emission spectra are compared with calculated spectra using first principle density-functional theory including dipole transition matrix elements. The main Sc 3d - N 2p and Sc 3d - Al 3p chemical bond regions are identified at -4 eV and -1.4 eV below the Fermi level, respectively. A strongly modified spectral shape of 3s states in the Al L2,3 emission from Sc3AlN in comparison to pure Al metal is found, which reflects the Sc 3d - Al 3p hybridization observed in the Al L1 emission. The differences between the electronic structure of Sc3AlN, ScN, and Sc metal are discussed in relation to the change of the conductivity and elastic properties.

  16. Durable metallized polymer mirror

    DOE Patents [OSTI]

    Schissel, P.O.; Kennedy, C.E.; Jorgensen, G.J.; Shinton, Y.D.; Goggin, R.M.

    1994-11-01

    A metallized polymer mirror construction is disclosed having improved durability against delamination and tunneling, comprising: an outer layer of polymeric material; a metal oxide layer underlying the outer layer of polymeric material; a silver reflective layer underneath the metal oxide layer; and a layer of adhesive attaching the silver layer to a substrate. 6 figs.

  17. Durable metallized polymer mirror

    DOE Patents [OSTI]

    Schissel, Paul O. (Golden, CO); Kennedy, Cheryl E. (Lafayette, CO); Jorgensen, Gary J. (Pine, CO); Shinton, Yvonne D. (Northglenn, CO); Goggin, Rita M. (Englewood, CO)

    1994-01-01

    A metallized polymer mirror construction having improved durability against delamination and tunneling, comprising: an outer layer of polymeric material; a metal oxide layer underlying the outer layer of polymeric material; a silver reflective layer underneath the metal oxide layer; and a layer of adhesive attaching the silver layer to a substrate.

  18. Metal Affinity Chromatography (MAC)

    E-Print Network [OSTI]

    Lebendiker, Mario

    Fractogel® Metal Affinity Chromatography (MAC) Resins and Cartridges Tools for His·Tag® Fusion-MACTM Cartridges #12;2 Novagen · Fractogel Metal Affinity Chromatography (MAC) Resins Ni-MACTM , Co-MACTM and u-MACTM Metal Affinity Chromatography (MAC) Resins and Cartridges HI Ni2+ Ni2+ Ni2+ HISHISHI SHISHISHIS Ni2

  19. Metal roofing Shingle roofing

    E-Print Network [OSTI]

    Hutcheon, James M.

    Metal roofing panel Shingle roofing Water & ice barrier Thermal Barrier Plywood Student: Arpit a cost benefit analysis and choose the most efficient and cost effective modification. Metal or shingle roof with only a water barrier between the plywood and the roofing panels. Metal roofing panel Shingle

  20. FINAL TECHNICAL REPORT Synthetic, Structural and Mechanistic Investigations of Olefin Polymerization Catalyzed by Early Transition Metal Compounds

    SciTech Connect (OSTI)

    Bercaw, John E. [California Institute of Technology

    2014-05-23

    The goal of this project is to develop new catalysts and provide understanding of ligand effects on catalyst composition in order to guide development of superior catalyst systems for polymerization of olefins. Our group is designing and synthesizing new “LX2”,“pincer” type ligands and complexing early transition metals to afford precatalysts. In a collaboration with Hans Brintzinger from the University of Konstanz, we are also examining the structures of the components of catalyst systems obtained from reaction of zirconocene dichlorides with aluminum alkyls and aluminum hydrides. Such systems are currently used commercially to produce polyolefins, but the nature of the active and dormant species as well as the mechanisms of their interconversions are not understood. New information on catalyst design and performance may lead to new types of polymers and/or new chemical transformations between hydrocarbons and transition metal centers, ultimately contributing to the development of catalytic reactions for the production of fuels, commodity and polymeric materials.