National Library of Energy BETA

Sample records for metal-based durables agricultural

  1. Durability

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    WP3 Durability : tasks & leaders T3.6 Work package coordination Gaz de France T3.2 Transmission pipelines; testing of steels TNO T3.1 State of the art Gaz de France T3.3 ...

  2. Agricultural

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Utility Resources News & Events Expand News & Events Skip navigation links Smart Grid Demand Response Agricultural Residential Demand Response Commercial & Industrial Demand...

  3. Low Cost, Durable Seal

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    UTC Power Corporation February 14, 2007 This presentation does not contain any proprietary or confidential information 1 LOW COST, DURABLE SEAL Outline * Project Objective * ...

  4. Durable metallized polymer mirror

    DOE Patents [OSTI]

    Schissel, P.O.; Kennedy, C.E.; Jorgensen, G.J.; Shinton, Y.D.; Goggin, R.M.

    1994-11-01

    A metallized polymer mirror construction is disclosed having improved durability against delamination and tunneling, comprising: an outer layer of polymeric material; a metal oxide layer underlying the outer layer of polymeric material; a silver reflective layer underneath the metal oxide layer; and a layer of adhesive attaching the silver layer to a substrate. 6 figs.

  5. Durable metallized polymer mirror

    DOE Patents [OSTI]

    Schissel, Paul O.; Kennedy, Cheryl E.; Jorgensen, Gary J.; Shinton, Yvonne D.; Goggin, Rita M.

    1994-01-01

    A metallized polymer mirror construction having improved durability against delamination and tunneling, comprising: an outer layer of polymeric material; a metal oxide layer underlying the outer layer of polymeric material; a silver reflective layer underneath the metal oxide layer; and a layer of adhesive attaching the silver layer to a substrate.

  6. Low Cost, Durable Seal

    SciTech Connect (OSTI)

    Roberts, George; Parsons, Jason; Friedman, Jake

    2010-12-17

    Seal durability is critical to achieving the 2010 DOE operational life goals for both stationary and transportation PEM fuel cell stacks. The seal material must be chemically and mechanically stable in an environment consisting of aggressive operating temperatures, humidified gases, and acidic membranes. The seal must also be producible at low cost. Currentlyused seal materials do not meet all these requirements. This project developed and demonstrated a high consistency hydrocarbon rubber seal material that was able to meet the DOE technical and cost targets. Significant emphasis was placed on characterization of the material and full scale molding demonstrations.

  7. A Heteroepitaxial Perovskite Metal-Base Transistor

    SciTech Connect (OSTI)

    Yajima, T.; Hikita, Y.; Hwang, H.Y.; ,

    2011-08-11

    'More than Moore' captures a concept for overcoming limitations in silicon electronics by incorporating new functionalities in the constituent materials. Perovskite oxides are candidates because of their vast array of physical properties in a common structure. They also enable new electronic devices based on strongly-correlated electrons. The field effect transistor and its derivatives have been the principal oxide devices investigated thus far, but another option is available in a different geometry: if the current is perpendicular to the interface, the strong internal electric fields generated at back-to-back heterojunctions can be used for oxide electronics, analogous to bipolar transistors. Here we demonstrate a perovskite heteroepitaxial metal-base transistor operating at room temperature, enabled by interface dipole engineering. Analysis of many devices quantifies the evolution from hot-electron to permeable-base behaviour. This device provides a platform for incorporating the exotic ground states of perovskite oxides, as well as novel electronic phases at their interfaces.

  8. Durable Fuel Cell Membrane Electrode Assembly (MEA)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Durable Fuel Cell Membrane Electrode Assembly (MEA) Durable Fuel Cell Membrane Electrode Assembly (MEA) A revolutionary method of building a membrane electrode assembly (MEA) for...

  9. PEM fuel cell durability studies

    SciTech Connect (OSTI)

    Borup, Rodney L; Davey, John R; Ofstad, Axel B; Xu, Hui

    2008-01-01

    The durability of polymer electrolyte membrane (PEM) fuel cells is a major barrier to the commercialization for stationary and transportation power applications. For transportation applications, the durability target for fuel cell power systems is a 5,000 hour lifespan and able to function over a range of vehicle operating conditions (-40{sup o} to +40{sup o}C). However, durability is difficult to quantify and improve because of the quantity and duration of testing required, and also because the fuel cell stack contains many components, for which the degradation mechanisms, component interactions and effects of operating conditions are not fully understood. These requirements have led to the development of accelerated testing protocols for PEM fuel cells. The need for accelerated testing methodology is exemplified by the times required for standard testing to reach their required targets: automotive 5,000 hrs = {approx} 7 months; stationary systems 40,000 hrs = {approx} 4.6 years. As new materials continue to be developed, the need for relevant accelerated testing increases. In this investigation, we examine the durability of various cell components, examine the effect of transportation operating conditions (potential cycling, variable RH, shut-down/start-up, freeze/thaw) and evaluate durability by accelerated durability protocols. PEM fuel cell durability testing is performed on single cells, with tests being conducted with steady-state conditions and with dynamic conditions using power cycling to simulate a vehicle drive cycle. Component and single-cell characterization during and after testing was conducted to identify changes in material properties and related failure mechanisms. Accelerated-testing experiments were applied to further examine material degradation.

  10. Rational Design of Artificial Metal-Based Enzymes | Center for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rational Design of Artificial Metal-Based Enzymes 17 Mar 2014 Giovanna Ghirlanda is one of ... of Subtask 3 with an objective to design and optimize artificial catalysts for ...

  11. Durable silver coating for mirrors

    DOE Patents [OSTI]

    Wolfe, Jesse D.; Thomas, Norman L.

    2000-01-01

    A durable multilayer mirror includes reflective layers of aluminum and silver and has high reflectance over a broad spectral range from ultraviolet to visible to infrared. An adhesion layer of a nickel and/or chromium alloy or nitride is deposited on an aluminum surface, and a thin layer of silver is then deposited on the adhesion layer. The silver layer is protected by a passivation layer of a nickel and/or chromium alloy or nitride and by one or more durability layers made of metal oxides and typically a first layer of metal nitride. The durability layers may include a composite silicon aluminum nitride and an oxinitride transition layer to improve bonding between nitride and oxide layers.

  12. Low Cost Durable Seal | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cost Durable Seal Low Cost Durable Seal Part of a 100 million fuel cell award announced by DOE Secretary Bodman on Oct. 25, 2006. PDF icon 4utc.pdf More Documents & Publications ...

  13. Low Cost, Durable Seal | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low Cost, Durable Seal Low Cost, Durable Seal This presentation, which focuses on low cost, durable seals, was given by George Roberts of UTC Power at a February 2007 meeting on new fuel cell projects. new_fc_roberts_utc.pdf (823.45 KB) More Documents & Publications Improved AST's Based on Real World FCV Data Low Cost Durable Seal Breakout Group 3: Water Management

  14. Compositional threshold for Nuclear Waste Glass Durability

    SciTech Connect (OSTI)

    Kruger, Albert A.; Farooqi, Rahmatullah; Hrma, Pavel R.

    2013-04-24

    Within the composition space of glasses, a distinct threshold appears to exist that separates "good" glasses, i.e., those which are sufficiently durable, from "bad" glasses of a low durability. The objective of our research is to clarify the origin of this threshold by exploring the relationship between glass composition, glass structure and chemical durability around the threshold region.

  15. Extremely durable biofouling-resistant metallic surfaces based...

    Office of Scientific and Technical Information (OSTI)

    Accepted Manuscript: Extremely durable biofouling-resistant metallic surfaces based on electrodeposited nanoporous tungstite films on steel Title: Extremely durable ...

  16. Durability

    Broader source: Energy.gov [DOE]

    Presentation by 06-Alliat to DOE Hydrogen Pipeline R&D Project Review Meeting held January 5-6, 2005 at Oak Ridge National Laboratory in Oak Ridge, Tennessee.

  17. Agriculture Sector

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Commercial Industrial Federal Agriculture SIS Variable Frequency Drives Irrigation Pump Testing Irrigation Hardware Upgrades LESA Agricultural Marketing Toolkit BPA's...

  18. Durability Improvements Through Degradation Mechanism Studies

    SciTech Connect (OSTI)

    Borup, Rodney L.; Mukundan, Rangachary; Spernjak, Dusan; Baker, Andrew M.; Lujan, Roger W.; Langlois, David Alan; Ahluwalia, Rajesh; Papadia, D. D.; Weber, Adam Z.; Kusoglu, Ahmet; Shi, Shouwnen; More, K. L.; Grot, Steve

    2015-08-03

    The durability of polymer electrolyte membrane (PEM) fuel cells is a major barrier to the commercialization of these systems for stationary and transportation power applications. By investigating cell component degradation modes and defining the fundamental degradation mechanisms of components and component interactions, new materials can be designed to improve durability. To achieve a deeper understanding of PEM fuel cell durability and component degradation mechanisms, we utilize a multi-institutional and multi-disciplinary team with significant experience investigating these phenomena.

  19. Optically transparent and environmentally durable superhydrophobic...

    Office of Scientific and Technical Information (OSTI)

    nanoparticles Citation Details In-Document Search Title: Optically transparent and environmentally durable superhydrophobic coating based on functionalized SiO2 nanoparticles ...

  20. Enhanced durability transparent superhydrophobic anti-soiling...

    Office of Scientific and Technical Information (OSTI)

    Title: Enhanced durability transparent superhydrophobic anti-soiling coatings for CSP applications Authors: Polyzos, Georgios 1 ; Schaeffer, Daniel A 1 ; Smith, Barton Barton ...

  1. DOE Durability Working Group December 2014 Meeting Agenda | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy December 2014 Meeting Agenda DOE Durability Working Group December 2014 Meeting Agenda Agenda for the DOE Durability Working Group Meeting held December 16, 2014, in Lemont, Illinois. DOE Durability Working Group December 2014 Meeting Agenda (33.15 KB) More Documents & Publications DOE Durability Working Group May 2015 Meeting Agenda DOE Durability Working Group June 2014 Meeting Agenda DOE Durability Working Group May 2012

  2. DOE Durability Working Group February 2013 Meeting Agenda | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy February 2013 Meeting Agenda DOE Durability Working Group February 2013 Meeting Agenda Meeting agenda from the February 2013 Durability Working Group Meeting sponsored by the U.S. Department of Energy (DOE) Fuel Cell Technologies Office. durability_working_group_agenda_feb_2013.pdf (15.04 KB) More Documents & Publications DOE Durability Working Group May 2012 Meeting Agenda DOE Durability Working Group December 2014 Meeting Agenda DOE Durability Working Group May 2011

  3. DOE Durability Working Group October 2010 Meeting Minutes | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 0 Meeting Minutes DOE Durability Working Group October 2010 Meeting Minutes Minutes of DOE-EERE Durability Working Group Meeting, October 10, 2010, sponsored by the DOE Fuel Cell Technologies Program. durability_working_group_minutes_oct_2010.pdf (35.11 KB) More Documents & Publications DOE Durability Working Group May 2011 Meeting Agenda DOE Durability Working Group October 2011 Meeting Notes Durability Improvements Through Degradation Mechanism Studies

  4. DOE Durability Working Group October 2012 Meeting Agenda | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 2 Meeting Agenda DOE Durability Working Group October 2012 Meeting Agenda Meeting agenda from the Fall 2012 Durability Working Group Meeting sponsored by the U.S. Department of Energy (DOE) Fuel Cell Technologies Program. durability_working_group_agenda_oct_2012.pdf (16.28 KB) More Documents & Publications DOE Durability Working Group October 2010 Meeting Minutes DOE Durability Working Group May 2012 Meeting Agenda DOE Durability Working Group February 2013

  5. Effects of Impurities on Fuel Cell Performance and Durability...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    clemson.pdf More Documents & Publications Effects of Impurities on Fuel Cell Performance and Durability Effects of Impurities on Fuel Cell Performance and Durability Effects of ...

  6. Effects of Impurities on Fuel Cell Performance and Durability...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Effects of Impurities on Fuel Cell Performance and Durability Effects of Impurities on Fuel Cell Performance and Durability Highly Dispersed Alloy ...

  7. Effects of Impurities on Fuel Cell Performance and Durability...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    lanl.pdf More Documents & Publications Effects of Impurities on Fuel Cell Performance and Durability Effects of Impurities on Fuel Cell Performance and Durability Advanced Cathode ...

  8. Integration of Advanced Materials and Interfaces for Durable...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Materials and Interfaces for Durable Thermoelectric Automobile Exhaust Waste Heat Harvesting Devices Integration of Advanced Materials and Interfaces for Durable ...

  9. DOE Zero Energy Ready Home: Durable Energy Builders, Houston...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE Zero Energy Ready Home: Durable Energy Builders, Houston, Texas DOE Zero Energy Ready Home: Durable Energy Builders, Houston, Texas This DOE Zero Energy Ready Home features...

  10. New MEA Materials for Improved DMFC Performance, Durability and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    MEA Materials for Improved DMFC Performance, Durability and Cost New MEA Materials for Improved DMFC Performance, Durability and Cost Presented at the Department of Energy Fuel ...

  11. Highly Dispersed Alloy Catalyst for Durability

    SciTech Connect (OSTI)

    Vivek S. Murthi , Elise Izzo, Wu Bi, Sandra Guerrero and Lesia Protsailo

    2013-01-08

    Achieving DOE's stated 5000-hr durability goal for light-duty vehicles by 2015 will require MEAs with characteristics that are beyond the current state of the art. Significant effort was placed on developing advanced durable cathode catalysts to arrive at the best possible electrode for high performance and durability, as well as developing manufacturing processes that yield significant cost benefit. Accordingly, the overall goal of this project was to develop and construct advanced MEAs that will improve performance and durability while reducing the cost of PEMFC stacks. The project, led by UTC Power, focused on developing new catalysts/supports and integrating them with existing materials (membranes and gas diffusion layers (GDLs)) using state-of-the-art fabrication methods capable of meeting the durability requirements essential for automotive applications. Specifically, the project work aimed to lower platinum group metals (PGM) loading while increasing performance and durability. Appropriate catalysts and MEA configuration were down-selected that protects the membrane, and the layers were tailored to optimize the movements of reactants and product water through the cell to maximize performance while maintaining durability.

  12. DOE Durability Working Group May 2015 Meeting

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE Durability Working Group Meeting Thursday, May 28, 2015, 2:00 pm to 6:00 pm Argonne National Laboratory 9700 S. Cass Avenue, Lemont, IL Energy Sciences Building, Building 241, Room A323 2:00 pm Arrive and get settled. (Substantial refreshments available, i.e., not dinner, but enough to get you by until after 6 pm). 2:05 pm Welcome and introductory comments Debbie Myers (Argonne), Rod Borup (LANL), Donna Ho (DOE), Co-chairs of Durability Working Group 2:10 pm Discussion of Durability

  13. DOE Durability Working Group Meeting Agenda

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE Durability Working Group Meeting Monday, June 16, 2014, 9:00 am to 12:00 pm Washington Marriott Wardman Park 2660 Woodley Road NW Washington, D.C. 8:30 am Continental "breakfast": breakfast breads, coffee, and tea 9:00 am Joint Durability and Catalysis Working Groups Meeting (Delaware A Room) Welcome and introductory comments Debbie Myers (Argonne), Rod Borup (LANL), Donna Ho (DOE), Piotr Zelenay (LANL), and Nancy Garland (DOE) co-chairs of Durability and Catalysis Working Groups

  14. Method of determining glass durability

    DOE Patents [OSTI]

    Jantzen, Carol Maryanne; Pickett, John Butler; Brown, Kevin George; Edwards, Thomas Barry

    1998-01-01

    A process for determining one or more leachate concentrations of one or more components of a glass composition in an aqueous solution of the glass composition by identifying the components of the glass composition, including associated oxides, determining a preliminary glass dissolution estimator, .DELTA.G.sub.p, based upon the free energies of hydration for the component reactant species, determining an accelerated glass dissolution function, .DELTA.G.sub.a, based upon the free energy associated with weak acid dissociation, .DELTA.G.sub.a.sup.WA, and accelerated matrix dissolution at high pH, .DELTA.G.sub.a.sup.SB associated with solution strong base formation, and determining a final hydration free energy, .DELTA.G.sub.f. This final hydration free energy is then used to determine leachate concentrations for elements of interest using a regression analysis and the formula log.sub.10 (N C.sub.i (g/L))=a.sub.i +b.sub.i .DELTA.G.sub.f. The present invention also includes a method to determine whether a particular glass to be produced will be homogeneous or phase separated. The present invention is also directed to methods of monitoring and controlling processes for making glass using these determinations to modify the feedstock materials until a desired glass durability and homogeneity is obtained.

  15. Method of determining glass durability

    DOE Patents [OSTI]

    Jantzen, C.M.; Pickett, J.B.; Brown, K.G.; Edwards, T.B.

    1998-12-08

    A process is described for determining one or more leachate concentrations of one or more components of a glass composition in an aqueous solution of the glass composition by identifying the components of the glass composition, including associated oxides, determining a preliminary glass dissolution estimator, {Delta}G{sub p}, based upon the free energies of hydration for the component reactant species, determining an accelerated glass dissolution function, {Delta}G{sub a}, based upon the free energy associated with weak acid dissociation, {Delta}G{sub a}{sup WA}, and accelerated matrix dissolution at high pH, {Delta}G{sub a}{sup SB} associated with solution strong base formation, and determining a final hydration free energy, {Delta}G{sub f}. This final hydration free energy is then used to determine leachate concentrations for elements of interest using a regression analysis and the formula log{sub 10}(N C{sub i}(g/L))=a{sub i} + b{sub i}{Delta}G{sub f}. The present invention also includes a method to determine whether a particular glass to be produced will be homogeneous or phase separated. The present invention is also directed to methods of monitoring and controlling processes for making glass using these determinations to modify the feedstock materials until a desired glass durability and homogeneity is obtained. 4 figs.

  16. Durable, Low Cost, Improved Fuel Cell Membranes

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    z To develop a low cost (vs. perfluorosulfonated ionomers), durable membrane. z To develop a membrane capable at 80C at low relative humidity (25-50%). z To develop a ...

  17. DOE Durability Working Group June 2014 Meeting Agenda | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy June 2014 Meeting Agenda DOE Durability Working Group June 2014 Meeting Agenda Agenda for the DOE Durability Working Group Meeting held June 16, 2014, in Washington, D.C., in conjunction with the DOE Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting. Durability Working Group June 2014 Meeting Agenda (28.67 KB) More Documents & Publications DOE Durability Working Group December 2014 Meeting Agenda DOE Durability Working Group May 2015 Meeting Agend

  18. DOE Durability Working Group October 2011 Meeting Notes | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 1 Meeting Notes DOE Durability Working Group October 2011 Meeting Notes Meeting notes from the Fall 2011 Durability Working Group (DWG) Meeting sponsored by the U.S. Department of Energy (DOE) Fuel Cell Technologies Program. Notes also include a summary of progress on action items from the Spring 2011 DWG meeting. durability_working_group_minutes_oct_2011.pdf (54.58 KB) More Documents & Publications DOE Durability Working Group October 2010 Meeting Minutes DOE Durability Working

  19. Highly Dispersed Alloy Cathode Catalyst for Durability

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    HIGHLY DISPERSED ALLOY CATHODE CATALYST FOR DURABILITY T. D. Jarvi UTC Power Corporation This presentation does not contain any proprietary or confidential information HIGHLY DISPERSED ALLOY CATALYST Objectives of project Characteristic DOE 2010 Target Pt group metal Total Content 0.50 g/kW rated Pt group metal Total Loading 0.30 mg PGM/cm 2 Durability with cycling <80 o C; >80 o C 5000 h; 2000 h Electrochemical Area Loss < 40 % Mass Activity at 900 mV RHE (IR-Free) 0.44 A/mg Pt

  20. PERFORMANCE AND DURABILITY OF THE PSA PEUGEOT CITROEN'S DPF SYSTEM...

    Office of Scientific and Technical Information (OSTI)

    PERFORMANCE AND DURABILITY OF THE PSA PEUGEOT CITROEN'S DPF SYSTEM ON A TAXI FLEET IN THE PARIS AREA Citation Details In-Document Search Title: PERFORMANCE AND DURABILITY OF THE ...

  1. Effects of Impurities of Fuel Cell Performance and Durability | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy of Fuel Cell Performance and Durability Effects of Impurities of Fuel Cell Performance and Durability This presentation, which focuses on fuel cell performance and durability, was given by Trent Molter of the University of Connecticut at a February 2007 meeting on new fuel cell projects. new_fc_molter_uconn.pdf (680.96 KB) More Documents & Publications The Effect of Airborne Contaminants on Fuel Cell Performance & Durability Effects of Impurities on Fuel Cell Performance

  2. Minutes from Durability Working Group Kick-off meeting

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Minutes from Durability Working Group (DWG) Kick-off Meeting 6/9/10 Contaminants Discussion on effect of air and system contaminants on performance and durability, initiated by S. Blanchet (Nuvera) Question of extent of impurity work in six newly-awarded durability projects represented at this meeting. None of the projects are specifically looking at the effect of system and air impurities on long- term performance degradation. New Argonne durability project does include task on effect of

  3. DOE Durability Working Group May 2015 Meeting Agenda | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5 Meeting Agenda DOE Durability Working Group May 2015 Meeting Agenda Agenda for the DOE Durability Working Group Meeting held May 28, 2015, in Lemont, Illinois. DOE Durability Working Group May 2015 Meeting Agenda (22.11 KB) More Documents & Publications DOE Durability Working Group December 2014 Meeting Agenda DOE Durability Working Group June 2014 Meeting Agenda DOE Durability Working Group May

  4. Intermediate Ethanol Blends Catalyst Durability Program

    SciTech Connect (OSTI)

    West, Brian H; Sluder, Scott; Knoll, Keith; Orban, John; Feng, Jingyu

    2012-02-01

    In the summer of 2007, the U.S. Department of Energy (DOE) initiated a test program to evaluate the potential impacts of intermediate ethanol blends (also known as mid-level blends) on legacy vehicles and other engines. The purpose of the test program was to develop information important to assessing the viability of using intermediate blends as a contributor to meeting national goals for the use of renewable fuels. Through a wide range of experimental activities, DOE is evaluating the effects of E15 and E20 - gasoline blended with 15% and 20% ethanol - on tailpipe and evaporative emissions, catalyst and engine durability, vehicle driveability, engine operability, and vehicle and engine materials. This report provides the results of the catalyst durability study, a substantial part of the overall test program. Results from additional projects will be reported separately. The principal purpose of the catalyst durability study was to investigate the effects of adding up to 20% ethanol to gasoline on the durability of catalysts and other aspects of the emissions control systems of vehicles. Section 1 provides further information about the purpose and context of the study. Section 2 describes the experimental approach for the test program, including vehicle selection, aging and emissions test cycle, fuel selection, and data handling and analysis. Section 3 summarizes the effects of the ethanol blends on emissions and fuel economy of the test vehicles. Section 4 summarizes notable unscheduled maintenance and testing issues experienced during the program. The appendixes provide additional detail about the statistical models used in the analysis, detailed statistical analyses, and detailed vehicle specifications.

  5. (Durability of building materials and components)

    SciTech Connect (OSTI)

    Naus, D.J.

    1990-11-27

    The traveler participated in the fourth meeting of RILEM 100-TSL, Techniques for Service Life Prediction,'' and The Fifth International Conference on Durability of Building Materials and Components.'' In addition, the traveler met with staff members at Taywood Engineering Ltd., Electricite de France, and AEA Technology. The meeting pertained to performance of concrete materials in nuclear power plant structures, time variation of concrete material properties, methods for evaluating concrete structures, and modeling to predict the effects of degradation factors on concrete materials. As many of the concrete structures in general civil engineering applications as well as nuclear power plant applications in Europe are aging, there is increasing emphasis on assessing the durability of these structures. Information was provided of direct application to the Structural Aging Program which would not have been available without these visits. Of equal, or possibly more importance, was the individual contacts established at the organizations visited. Each organization was extremely interested in both the approach and scope of the Structural Aging Program and requested that they be informed of progress. The initial steps were taken to cooperate with several of these researchers and this should help the Structural Aging Program keep abreast of related European activities. In summary, information obtained during this trip will benefit the ongoing Structural Aging Program by informing Oak Ridge National Laboratory (ORNL) of the extensive European research programs addressing the durability of concrete structures, and also by forming and strengthening acquaintances with counterparts in other countries, thus enhancing the basis for possible international cooperation.

  6. Vehicle Technologies Office Merit Review 2014: Metal-Based High Capacity Li-Ion Anodes

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation given by Binghamton University-SUNY at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about metal-based high...

  7. Effects of Impurities on Fuel Cell Performance and Durability | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy on Fuel Cell Performance and Durability Effects of Impurities on Fuel Cell Performance and Durability This presentation, which focuses on fuel cell performance and durability, was given by James Goodwin of Clemson Univeristy at a February 2007 meeting on new fuel cell projects. new_fc_goodwin_clemson.pdf (322.34 KB) More Documents & Publications Acid Doped Membranes for High Temperature PEMFC Biogas Impurities and Cleanup for Fuel Cells Integration of Non-Traditional Membranes

  8. Development of Alternative and Durable High Performance Cathode Supporst

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for PEM Fuel Cells | Department of Energy Alternative and Durable High Performance Cathode Supporst for PEM Fuel Cells Development of Alternative and Durable High Performance Cathode Supporst for PEM Fuel Cells Part of a $100 million fuel cell award announced by DOE Secretary Bodman on Oct. 25, 2006. 3_pnnl.pdf (21.99 KB) More Documents & Publications Development of Alternative and Durable High Performance Cathode Supports for PEM Fuel Cells Fuel Cell Kickoff Meeting Agenda 2015 Pathways

  9. Membrane Durability in PEM Fuel Cells: Chemical Degradation | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Durability in PEM Fuel Cells: Chemical Degradation Membrane Durability in PEM Fuel Cells: Chemical Degradation Presentation at the 2008 High Temperature Membrane Working Group Meeting held June 9, 2008, in Washington, DC motupally_htmwg_2008.pdf (962.33 KB) More Documents & Publications Highly Dispersed Alloy Cathode Catalyst for Durability Fundamental Study of the Mechanical Strength Degradation Mechanisms of PFSA Membranes and MEAs New Membranes for PEM Fuel Cells

  10. Membrane Performance and Durability Overview for Automotive Fuel Cell

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applications | Department of Energy Performance and Durability Overview for Automotive Fuel Cell Applications Membrane Performance and Durability Overview for Automotive Fuel Cell Applications Presented by Tom Greszler of General Motors at the High Temperature Membrane Working Group Meeting, San Francisco, September 14, 2006. htmwg_greszler.pdf (502.69 KB) More Documents & Publications High Temperature Membrane Working Group, Minutes of Meeting on September 14, 2006 Some durability

  11. Project Profile: Cleanable and Hardcoat Coatings for Increased Durability

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Silvered Polymeric Mirrors | Department of Energy Cleanable and Hardcoat Coatings for Increased Durability of Silvered Polymeric Mirrors Project Profile: Cleanable and Hardcoat Coatings for Increased Durability of Silvered Polymeric Mirrors 3M logo 3M, under the CSP R&D FOA, is developing optical coatings for solar mirrors that are durable, easily maintained, and more cost-effective. Approach Diagram of the most successful coatings identified by the research team based on the mix of

  12. X-Ray Microcomputed Tomography for the Durability Characterization...

    Office of Scientific and Technical Information (OSTI)

    Conference: X-Ray Microcomputed Tomography for the Durability Characterization of Limestone Aggregate Citation Details In-Document Search Title: X-Ray Microcomputed Tomography for...

  13. Durable Low Cost Improved Fuel Cell Membranes | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications Durable, Low Cost, Improved Fuel Cell Membranes Novel Materials for High Efficiency Direct ...

  14. Membrane Performance and Durability Overview for Automotive Fuel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Membrane Performance and Durability Overview for Automotive Fuel Cell Applications Presented by Tom Greszler of General Motors at the High Temperature Membrane Working Group ...

  15. PERFORMANCE AND DURABILITY OF THE PSA PEUGEOT CITROEN'S DPF SYSTEM...

    Office of Scientific and Technical Information (OSTI)

    Conference: PERFORMANCE AND DURABILITY OF THE PSA PEUGEOT CITROEN'S DPF SYSTEM ON A TAXI FLEET IN THE PARIS AREA Citation Details In-Document Search Title: PERFORMANCE AND ...

  16. Critical Performance and Durability Parameters of an Integrated...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    used to Meet Tier II Emission Standards Critical Performance and Durability Parameters of an Integrated Aftertreatment System used to Meet Tier II Emission Standards Poster ...

  17. Biofuels Impact on DPF Durability | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Vehicle Technologies Office Merit Review 2014: Biofuel Impacts on Aftertreatment Devices (Agreement ID:26463) Project ID:18519 Biofuels Impact on DPF Durability Vehicle ...

  18. Development of Alternative and Durable High Performance Cathode...

    Broader source: Energy.gov (indexed) [DOE]

    Development of Alternative and Durable High Performance Cathode Supporst for PEM Fuel Cells Fuel Cell Kickoff Meeting Agenda Energy Storage Systems 2012 Peer Review Presentations - ...

  19. Combined hydrophobicity and mechanical durability through surface nanoengineering

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Elliott, Paul R.; Stagon, Stephen P.; Huang, Hanchen; Furrer, David U.; Burlatsky, Sergei F.; Filburn, Thomas P.

    2015-04-08

    This paper reports combined hydrophobicity and mechanical durability through the nanoscale engineering of surfaces in the form of nanorod-polymer composites. Specifically, the hydrophobicity derives from nanoscale features of mechanically hard ZnO nanorods and the mechanical durability derives from the composite structure of a hard ZnO nanorod core and soft polymer shell. Experimental characterization correlates the morphology of the nanoengineered surfaces with the combined hydrophobicity and mechanical durability, and reveals the responsible mechanisms. Such surfaces may find use in applications, such as boat hulls, that benefit from hydrophobicity and require mechanical durability.

  20. DOE Durability Working Group February 2013 Meeting Agenda

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE Durability Working Group (DWG) Meeting Agenda Thursday, February 28, 2013 Crystal City Marriott Crystal City, VA 8:30 am Welcome and introductory comments Debbie Myers ...

  1. Hot vibration durability of ceramic preconverters

    SciTech Connect (OSTI)

    Locker, R.J.; Schad, M.J.; Sawyer, C.B.

    1995-12-31

    The advent of thermally durable catalyst technologies has created the opportunity to move catalytic converters closer to the engine, providing a potential solution for cold start emissions. Close-coupled positioning exposes the converter to higher exhaust gas temperatures than experienced in underbody applications, permitting earlier catalyst light-off. The proximity of the converter to the engine will result in increased exposure to the vibrational energy created by combustion processes as well as intake and exhaust valve dynamics. This study investigated the thermo-mechanical challenges of mounting a ceramic substrate under severe conditions. In some instances ceramic substrates have been overlooked for application in the more demanding close-coupled environment. It will be shown that ceramic substrates mounted with standard intumescent mats survive under the most severe hot vibration testing conditions in the industry. Hot vibration testing is a very expensive activity. Therefore, testing a statistically significant sample population is not cost effective. Additional testing techniques were employed in this study to quantify hot vibration performance. These tests show promise in predicting hot vibration durability.

  2. CHP Fuel Cell Durability Demonstration - Final Report

    SciTech Connect (OSTI)

    Petrecky, James; Ashley, Christopher J

    2014-07-21

    Plug Power has managed a demonstration project that has tested multiple units of its high-temperature, PEM fuel cell system in micro-combined heat and power (μ-CHP) applications in California. The specific objective of the demonstration project was to substantiate the durability of GenSys Blue, and, thereby, verify its technology and commercial readiness for the marketplace. In the demonstration project, Plug Power, in partnership with the National Fuel Cell Research Center (NFCRC) at the University of California, Irvine (UCI), and Sempra, will execute two major tasks: • Task 1: Internal durability/reliability fleet testing. Six GenSys Blue units will be built and will undergo an internal test regimen to estimate failure rates. This task was modified to include 3 GenSys Blue units installed in a lab at UCI. • Task 2: External customer testing. Combined heat and power units will be installed and tested in real-world residential and/or light commercial end user locations in California.

  3. Bivalent metal-based MIL-53 analogues: Synthesis, properties and application

    SciTech Connect (OSTI)

    Liu, Yongxin; Liu, Dan; Wang, Cheng

    2015-03-15

    Trivalent metal-based MIL-53 (Al{sup 3+}, Cr{sup 3+}, Fe{sup 3+}, In{sup 3+}) compounds are interesting metal–organic frameworks (MOFs) with breathing effect and are promising gas sorption materials. Replacing bridging μ{sub 2}-OH group by neutral ligands such as pyridine N-oxide and its derivatives (PNOs), the trivalent metal-based MIL-53 analogous structures could be extended to bivalent metal systems. The introduction of PNOs and bivalent metal elements endows the frameworks with new structural features and physical and chemical properties. This minireview summarizes the recent development of bivalent metal-based MIL-53 analogues (Mn{sup 2+}, Co{sup 2+}, Ni{sup 2+}), typically, focusing on the synthetic strategies and potential applications based on our own works and literatures. We present the synthetic strategy to achieve structures evolution from single-ligand-walled to double-ligand-walled channel. Properties and application of these new materials in a wide range of potential areas are discussed including thermal stability, gas adsorption, magnetism and liquid-phase separation. Promising directions of this research field are also highlighted. - Graphical abstract: The recent development of bivalent metal-based MIL-53 analogues (Mn{sup 2+}, Co{sup 2+}, Ni{sup 2+}) on their synthetic strategies, properties and potential applications was reviewed. - Highlights: • Structure features of bivalent metal-based MIL-53 analogues are illustrated. • Important properties and application are presented. • Host–guest interactions are main impetus for liquid-phase separation. • Promising directions of bivalent metal-based MIL-53 analogues are highlighted.

  4. Durability of waste glass flax fiber reinforced mortar

    SciTech Connect (OSTI)

    Aly, M.; Hashmi, M. S. J.; Olabi, A. G.; Messeiry, M.

    2011-01-17

    The main concern for natural fibre reinforced mortar composites is the durability of the fibres in the alkaline environment of cement. The composites may undergo a reduction in strength as a result of weakening of the fibres by a combination of alkali attack and fibre mineralisation. In order to enhance the durability of natural fiber reinforced cement composites several approaches have been studied including fiber impregnation, sealing of the matrix pore system and reduction of matrix alkalinity through the use of pozzolanic materials. In this study waste glass powder was used as a pozzolanic additive to improve the durability performance of flax fiber reinforced mortar (FFRM). The durability of the FFRM was studied by determining the effects of ageing in water and exposure to wetting and drying cycles; on the microstructures and flexural behaviour of the composites. The mortar tests demonstrated that the waste glass powder has significant effect on improving the durability of FFRM.

  5. Lightweight, durable lead-acid batteries

    SciTech Connect (OSTI)

    Lara-Curzio, Edgar; An, Ke; Kiggans, Jr., James O.; Dudney, Nancy J.; Contescu, Cristian I.; Baker, Frederick S.; Armstrong, Beth L.

    2011-09-13

    A lightweight, durable lead-acid battery is disclosed. Alternative electrode materials and configurations are used to reduce weight, to increase material utilization and to extend service life. The electrode can include a current collector having a buffer layer in contact with the current collector and an electrochemically active material in contact with the buffer layer. In one form, the buffer layer includes a carbide, and the current collector includes carbon fibers having the buffer layer. The buffer layer can include a carbide and/or a noble metal selected from of gold, silver, tantalum, platinum, palladium and rhodium. When the electrode is to be used in a lead-acid battery, the electrochemically active material is selected from metallic lead (for a negative electrode) or lead peroxide (for a positive electrode).

  6. Lightweight, durable lead-acid batteries

    DOE Patents [OSTI]

    Lara-Curzio, Edgar; An, Ke; Kiggans, Jr., James O; Dudney, Nancy J; Contescu, Cristian I; Baker, Frederick S; Armstrong, Beth L

    2013-05-21

    A lightweight, durable lead-acid battery is disclosed. Alternative electrode materials and configurations are used to reduce weight, to increase material utilization and to extend service life. The electrode can include a current collector having a buffer layer in contact with the current collector and an electrochemically active material in contact with the buffer layer. In one form, the buffer layer includes a carbide, and the current collector includes carbon fibers having the buffer layer. The buffer layer can include a carbide and/or a noble metal selected from of gold, silver, tantalum, platinum, palladium and rhodium. When the electrode is to be used in a lead-acid battery, the electrochemically active material is selected from metallic lead (for a negative electrode) or lead peroxide (for a positive electrode).

  7. Outdoor durability of radiation-cured coatings

    SciTech Connect (OSTI)

    Holman, R.; Kennedy, R.

    1997-12-31

    Radiation cured coatings are used almost exclusively on products which have little or no exposure to moisture or the weather; inks, furniture varnishes, floor varnishes and coatings for electronic components. However there is considerable interest in being able to use this technology in exterior environments as a substitute for solvent-borne coatings. A 3-year study examining the possible reasons for the poor durability of radiation curable coatings showed that the resistance of the monomers and oligomers to hydrogen abstraction was crucially important, and the water permeability of the cured coating influenced the long-term adhesion performance. The project concluded that with the appropriate combination of curing technology and monomer/oligomer selection, the prospects of UV curable coatings for outdoor exposure are very encouraging.

  8. Quantification of ceramic preconverter hot vibration durability

    SciTech Connect (OSTI)

    Locker, R.J.; Sawyer, C.B.; Schad, M.J.

    1996-09-01

    The hot vibration durability of ceramic preconverters was examined in this study. Two preconverter designs were investigated. A Generation 1 design, utilizing 4,070 g/m{sup 2} intumescent mat, was examined at 900 C/75g. A Generation 2 design, possessing 6,200 g/m{sup 2} intumescent mat and insulated end cones, was evaluated at 1,050 C/75g. Three consecutive Generation 1 samples passed 900 C/75g exposures of 100 hours. Three Generation 2 preconverters tested at 1,050 C/75g similarly passed 100 hour exposures. The residual shear strength of each preconverter tested in hot vibration was measured to quantify durability. Hot push shear evaluations were performed to obtain the residual shear strength. Following 900 C/75g hot vibration exposures, the Generation 1 samples possessed an average residual shear strength of 450 kPa. Generation 2 samples, tested at 1,050 C/75g retained an average mat shear strength of 61 kPa. A minimum calculated shear strength of 15 kPa is required. An alternative thermal aging technique was applied to new sets of Generation 1 and 2 specimens. These samples did not experience mechanical vibration. Results of hot push shear measurements on these components indicated that the residual shear strengths were similar to those obtained for specimens exposed to hot vibration. These results indicated that the thermal conditions were the primary cause of Mat deterioration in hot vibration. The supplemental test methods investigated in this study represent an economical and quantitative alternative to hot vibration testing.

  9. DOE Durability Working Group May 2012 Meeting Agenda | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 Meeting Agenda DOE Durability Working Group May 2012 Meeting Agenda Meeting agenda from the Spring 2012 Durability Working Group Meeting sponsored by the U.S. Department of Energy (DOE) Fuel Cell Technologies Program. durability_working_group_agenda_may_2012.pdf (19.95 KB) More Documents & Publications DOE Durability Working Group October 2011 Meeting Notes DOE Durability Working Group February 2013 Meeting Agenda DOE Durability Working Group October

  10. Function Specific Analysis of the Thermal Durability of Cu-Zeolite...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Function Specific Analysis of the Thermal Durability of Cu-Zeolite SCR Catalyst Function Specific Analysis of the Thermal Durability of Cu-Zeolite SCR Catalyst Presentation given ...

  11. Fuel Cell Measurements of Performance and Durability of Non-PGM...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    FUEL CELL MEASUREMENTS OF PERFORMANCE AND DURABILITY OF NON-PGM ORR ELECTROCATALYSTS DOE DURABILITY WORKING GROUP 2011 CELL AND ELECTRODES Fuel cell: The surface area of the ...

  12. DOE Durability Working Group December 2014 Meeting Agenda

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE Durability Working Group Meeting Tuesday, December 16, 2014, 9:00 am to 4:00 pm Argonne National Laboratory Energy Sciences Building, Building 241, Room A323 Lemont, IL 8:45 am Arrive and get settled. 9:00 am Welcome and introductory comments Debbie Myers (Argonne), Rod Borup (LANL), Donna Ho (DOE), Co-chairs of Durability Working Group 9:05 am Summary presentation of durability needs from 2013and 2014 workshops Donna Ho (DOE) Summary of new results and discussion of missing component-level

  13. Development of Alternative and Durable High Performance Cathode...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Supporst for PEM Fuel Cells Development of Alternative and Durable High Performance Cathode Supporst for PEM Fuel Cells Part of a 100 million fuel cell award announced by DOE ...

  14. Durable Fuel Cell Membrane Electrode Assembly (MEA) - Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Durable Fuel Cell Membrane Electrode Assembly (MEA) Los Alamos National Laboratory Contact ... The pt loading was 0.2 and 0.4 mgcm2. Technology Marketing SummaryThe membrane electrode ...

  15. An empirical modeling approach to high sodium glass durability

    SciTech Connect (OSTI)

    Shine, E.P.; Sadler, A.L.K. [Westinghouse Savannah River Company, Aiken, SC (United States)

    1996-12-31

    Empirical mixture models have been developed for chemical durability of high sodium borosilicate glass. The response of boron to a seven-day Product Consistency Test (PCT) was chosen as the measure of durability. The objective of the model development was to support the proposed vitrification of Hanford low-level waste (LLW), the bulk of which is primarily sodium oxide. A full first-order model and a second order model were developed from a database of high-sodium borosilicate glasses. First-order models proved to be satisfactory in a qualitative sense, but root mean squared errors were fairly large for quantitative predictive purposes. The results imply that mechanistic models relating durability to composition should include higher order compositional interactions; a second-order model yielded much improved statistics. The modeling results also suggest that calcium, which is considered a network modifier yet is also regarded as a glass {open_quotes}stiffener{close_quotes}, may improve durability.

  16. Biofuels Impact on DPF Durability | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    and Peer Evaluation pm040lance2011p.pdf (637.35 KB) More Documents & Publications Biofuels Impact on DPF Durability DPF Performance with Biodiesel Blends Non-Petroleum-Based ...

  17. Durable Zinc Oxide-Based Regenerable Sorbents for Desulfurization...

    Office of Scientific and Technical Information (OSTI)

    in a Fixed-Bed Reactor Citation Details In-Document Search Title: Durable Zinc Oxide-Based Regenerable Sorbents for Desulfurization of Syngas in a Fixed-Bed Reactor You are ...

  18. DOE Durability Working Group May 2012 Meeting Agenda

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE Durability Working Group (DWG) Monday, May 14, 2012, 8:00-10:00 am Gateway Salon I, Crystal Gateway Marriott Crystal City, VA Meeting Agenda 8:00 am Welcome and introductory ...

  19. DOE Durability Working Group May 2011 Meeting Agenda

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE Durability Working Group Wednesday, May 11, 2011, 7:00-10:00 pm Marriott Crystal Gateway "Salon V" (Ballroom Level) Meeting Agenda 7:00 pm Welcome and introductory comments ...

  20. Impact of Biodiesel Metals on the Performance and Durability...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Metals on the Performance and Durability of DOC and DPF Technologies Impact of Biodiesel ... and the Role of the DOC Impact of Biodiesel-Based Na on the Selective Catalytic ...

  1. Performance and durability of PSA Peugeot Citroen's DPF System...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DPF System on a Taxi Fleet in the Paris Area Performance and durability of PSA Peugeot Citroen's DPF System on a Taxi Fleet in the Paris Area 2003 DEER Conference ...

  2. Highly Dispersed Alloy Cathode Catalyst for Durability | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Dispersed Alloy Cathode Catalyst for Durability Highly Dispersed Alloy Cathode Catalyst for Durability This presentation, which focuses on alloy cathode catalysts, was given by T. D. Jarvi of UTC Power at a February 2007 meeting on new fuel cell projects. new_fc_jarvi_utc.pdf (576 KB) More Documents & Publications PEM Fuel Cell Technology, Key Research Needs and Approaches (Presentation) PBI-Phosphoric Acid Based Membrane Electrode Assemblies: Status Update Development of

  3. Future Engine Fluids Technologies: Durable, Fuel-Efficient, and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emissions-Friendly | Department of Energy Engine Fluids Technologies: Durable, Fuel-Efficient, and Emissions-Friendly Future Engine Fluids Technologies: Durable, Fuel-Efficient, and Emissions-Friendly 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters 2005_deer_bardasz.pdf (561.21 KB) More Documents & Publications Controlled Experiments on the Effects of Lubricant/Additive (Low-Ash, Ashless) Characteristics on DPF Degradation Diesel Particulate Filters:

  4. Durable, Low Cost, Improved Fuel Cell Membranes | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Durable, Low Cost, Improved Fuel Cell Membranes Durable, Low Cost, Improved Fuel Cell Membranes This presentation, which focuses on fuel cell membranes, was given by Michel Foure of Arkema at a meeting on new fuel cell projects in February 2007. new_fc_foure_arkema.pdf (168.93 KB) More Documents & Publications Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications Novel Materials for High Efficiency Direct Methanol Fuel Cells High Temperature Membrane Working

  5. Critical Performance and Durability Parameters of an Integrated

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Aftertreatment System used to Meet Tier II Emission Standards | Department of Energy Critical Performance and Durability Parameters of an Integrated Aftertreatment System used to Meet Tier II Emission Standards Critical Performance and Durability Parameters of an Integrated Aftertreatment System used to Meet Tier II Emission Standards Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by

  6. PV Module Intraconnect Thermomechanical Durability Damage Prediction Model

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Module Intraconnect Thermomechanical Durability Damage Prediction Model PV Module Intraconnect Thermomechanical Durability Damage Prediction Model Presented at the PV Module Reliability Workshop, February 26 - 27 2013, Golden, Colorado pvmrw13_ps2_dow_gaston.pdf (1.26 MB) More Documents & Publications FY2015 Status Report: CIRFT Testing of High-Burnup Used Nuclear Fuel Rods from Pressurized Water Reactor and BWR Environments 2014 Propulsion Materials R&D Annual

  7. The properties of metal-based nanoparticle catalysts will be calculated

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with unprecedented accuracy using massively parallel first-principles calculations. These calculations will provide fundamentally new insights into the electronic structure and b | Argonne Leadership Computing Facility The properties of metal-based nanoparticle catalysts will be calculated with unprecedented accuracy using massively parallel first-principles calculations. These calculations will provide fundamentally new insights into the electronic structure and b PI Name: Jeffrey Greeley

  8. Durability of Polymeric Encapsulation Materials in a PMMA/glass Concentrator Photovoltaic System

    SciTech Connect (OSTI)

    Miller, David; Kempe, Michael; Muller, Matthew; Gray, Matthew; Araki, Kenji; Kurtz, Sarah

    2014-04-08

    Durability of Polymeric Polymeric Encapsulation Encapsulation Materials for a PMMA/glass Concentrator Photovoltaic System

  9. DOE Durability Working Group June 2010 Kick-Off Meeting Minutes |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 0 Kick-Off Meeting Minutes DOE Durability Working Group June 2010 Kick-Off Meeting Minutes Minutes from Durability Working Group June 2010 Kick-off meeting sponsored by DOE Fuel Cell Technologies Program. durability_working_group_minutes_june_2010.pdf (33.66 KB) More Documents & Publications DOE Durability Working Group February 2013 Meeting Agenda Advanced Cathode Catalysts DOE Durability Working Group June 2014

  10. DOE Durability Working Group May 2011 Meeting Agenda | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    May 2011 Meeting Agenda DOE Durability Working Group May 2011 Meeting Agenda Meeting agenda from the Spring 2011 Durability Working Group Meeting sponsored by the U.S. Department of Energy (DOE) Fuel Cell Technologies Program. durability_working_group_agenda_may_2011.pdf (24.2 KB) More Documents & Publications DOE Durability Working Group October 2010 Meeting Minutes DOE Durability Working Group October 2011 Meeting Notes

  11. Agricultural Bio-Fueled Generation of Electricity and Development of Durable and Efficent NOx Reduction

    SciTech Connect (OSTI)

    Boyd, Rodney

    2007-08-08

    The objective of this project was to define the scope and cost of a technology research and development program that will demonstrate the feasibility of using an off-the-shelf, unmodified, large bore diesel powered generator in a grid-connected application, utilizing various blends of BioDiesel as fuel. Furthermore, the objective of project was to develop an emissions control device that uses a catalytic process and BioDiesel (without the presence of Ammonia or Urea)to reduce NOx and other pollutants present in a reciprocating engine exhaust stream with the goal of redefining the highest emission reduction efficiencies possible for a diesel reciprocating generator. Process: Caterpillar Power Generation adapted an off-the-shelf Diesel Generator to run on BioDiesel and various Petroleum Diesel/BioDiesel blends. EmeraChem developed and installed an exhaust gas cleanup system to reduce NOx, SOx, volatile organics, and particulates. The system design and function was optimized for emissions reduction with results in the 90-95% range;

  12. DURABILITY TESTING OF FLUIDIZED BED STEAM REFORMER (FBSR) WASTE FORMS

    SciTech Connect (OSTI)

    Jantzen, C

    2006-01-06

    Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of high sodium aqueous radioactive wastes. The addition of clay and a catalyst as co-reactants converts high sodium aqueous low activity wastes (LAW) such as those existing at the Hanford and Idaho DOE sites to a granular ''mineralized'' waste form that may be made into a monolith form if necessary. Simulant Hanford and Idaho high sodium wastes were processed in a pilot scale FBSR at Science Applications International Corporation (SAIC) Science and Technology Applications Research (STAR) facility in Idaho Falls, ID. Granular mineral waste forms were made from (1) a basic Hanford Envelope A low-activity waste (LAW) simulant and (2) an acidic INL simulant commonly referred to as sodium-bearing waste (SBW). The FBSR waste forms were characterized and the durability tested via ASTM C1285 (Product Consistency Test), the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP), and the Single Pass Flow Through (SPFT) test. The durability of the FBSR waste form products was tested in order to compare the measured durability to previous FBSR waste form testing on Hanford Envelope C waste forms that were made by THOR Treatment Technologies (TTT) and to compare the FBSR durability to vitreous LAW waste forms, specifically the Hanford low activity waste (LAW) glass known as the Low-activity Reference Material (LRM). The durability of the FBSR waste form is comparable to that of the LRM glass for the test responses studied.

  13. Integrated Design and Rapid Development of Refractory Metal Based Alloys for Fossil Energy Applications

    SciTech Connect (OSTI)

    Dogan, O.N.; King, P.E.; Gao, M.C.

    2008-07-01

    One common barrier in the development of new technologies for future energy generating systems is insufficiency of existing materials at high temperatures (>1150oC) and aggressive atmospheres (e.g., steam, oxygen, CO2). To overcome this barrier, integrated design methodology will be applied to the development of refractory metal based alloys. The integrated design utilizes the multi-scale computational methods to design materials for requirements of processing and performance. This report summarizes the integrated design approach to the alloy development and project accomplishments in FY 2008.

  14. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1989-05-02

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  15. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1988-11-14

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  16. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1989-03-06

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  17. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1988-08-19

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  18. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Baltich, L.K.; Berggren, M.H.

    1987-05-18

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  19. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Baltich, L.K.; Berggren, M.H.

    1987-08-28

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  20. DOE-EERE Durability Working Group Meeting Notes

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE-EERE Durability Working Group (DWG) Meeting Thursday, October 13, 2011 Boston, MA Meeting Notes D. Myers and R. Borup Meeting Agenda 6:30 pm Welcome and introductory comments Debbie Myers (Argonne) and Rod Borup (Los Alamos) - co-chairs 6:40-7:45 pm Descriptions and summaries of results of modeling efforts in durability projects Dane Morgan, University of Wisconsin-Madison Srikanth Arisetty, ANL Adam Weber, LBNL Shanna Knights, Ballard Sergei Burlatsky, UTC Power Jean St-Pierre, University

  1. Pt-Co/C Catalysts: PEMFC Performance and Durability

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pt-Co/C Catalysts: PEMFC Performance and Durability Prasanna Mani, Harmeet Chhina, Emily Hopkins and Wendy Lee Slides presented by James Waldecker of Ford to the DOE Catalysis Working Group Meeting on June 16, 2014 Why are we looking at Pt-Co/C catalysts for PEM Fuel Cells even after so many years since the introduction? What trade offs in Pt-Co alloy characteristics can yield better performance and durability than Pt/C? - Pt:Co atomic ratio - Particle size - Metal loading What causes the

  2. Durability-based design criteria for an automotive structural composite

    SciTech Connect (OSTI)

    Corum, J.M.; Battiste, R.L.; Brinkman, C.R.; Ren, W.; Ruggles, M.B.; Yahr, G.T.

    1998-11-01

    Before composite structures can be widely used in automotive applications, their long-term durability must be assured. The Durability of Lightweight Composite Structures Project at Oak Ridge National Laboratory was established by the US Department of Energy to help provide that assurance. The project is closely coordinated with the Automotive Composites Consortium. The experimentally-based, durability-driven design criteria described in this paper are the result of the initial project thrust. The criteria address a single reference composite, which is an SRIM (Structural Reaction Injection Molded) polyurethane, reinforced with continuous strand, swirl-mat E-glass fibers. The durability issues addressed include the effects of cyclic and sustained loadings, temperature, automotive fluid environments, and low-energy impacts (e.g., tool drops and roadway kickups) on strength, stiffness, and deformation. The criteria provide design analysis guidance, a multiaxial strength criterion, time-independent and time-dependent allowable stresses, rules for cyclic loading, and damage tolerance design guidance. Environmental degradation factors and the degrading effects of prior loadings are included. Efforts are currently underway to validate the criteria by application to a second random-glass-fiber composite. Carbon-fiber composites are also being addressed.

  3. Request for Information: Photovoltaic Reliability and Durability Research and Development

    Office of Energy Efficiency and Renewable Energy (EERE)

    The United States Department of Energy (DOE) – Office of Energy Efficiency and Renewable Energy (EERE) seeks feedback from industry, academia, research laboratories, government agencies, and other stakeholders on issues related to solar photovoltaic (PV) reliability and durability research and development.

  4. DOE Durability Working Group June 2010 Kick-Off Meeting Minutes...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    0 Kick-Off Meeting Minutes DOE Durability Working Group June 2010 Kick-Off Meeting Minutes Minutes from Durability Working Group June 2010 Kick-off meeting sponsored by DOE Fuel ...

  5. Fuel Cell Measurements of Performance and Durability of Non-PGM ORR Electrocatalysts

    Broader source: Energy.gov [DOE]

    Fuel cell testing protocol developed by the DOE Durability Working Group in 2011 for measuring performance and durability of non-platinum group metal (PGM) oxygen reduction reaction (ORR) electrocatalysts.

  6. Rotating Disk-Electrode Aqueous Electrolyte Accelerated Stress Tests for PGM Electrocatalyst/Support Durability Evaluation

    Broader source: Energy.gov [DOE]

    Rotating disk-electrode aqueous electrolyte accelerated stress test protocols developed by the DOE Durability Working Group for platinum group metal (PGM) electrocatalyst/support durability evaluation, October 4, 2011.

  7. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Berggren, M.H.; Jha, M.C.

    1989-10-01

    AMAX Research Development Center (AMAX R D) investigated methods for enhancing the reactivity and durability of zinc ferrite desulfurization sorbents. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For this program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such as size, strength, and specific surface area during 10 cycles of sulfidation and oxidation. Two base case sorbents, a spherical pellet and a cylindrical extrude used in related METC-sponsored projects, were used to provide a basis for the aimed enhancement in durability and reactivity. Sorbent performance was judged on the basis of physical properties, single particle kinetic studies based on thermogravimetric (TGA) techniques, and multicycle bench-scale testing of sorbents. A sorbent grading system was utilized to quantify the characteristics of the new sorbents prepared during the program. Significant enhancements in both reactivity and durability were achieved for the spherical pellet shape over the base case formulation. Overall improvements to reactivity and durability were also made to the cylindrical extrude shape. The primary variables which were investigated during the program included iron oxide type, zinc oxide:iron oxide ratio, inorganic binder concentration, organic binder concentration, and induration conditions. The effects of some variables were small or inconclusive. Based on TGA studies and bench-scale tests, induration conditions were found to be very significant.

  8. USDA Agricultural Conservation Easement Program

    Broader source: Energy.gov [DOE]

    The U.S. Department of Agriculture's (USDA's) Agricultural Conservation Easement Program (ACEP) provides financial and technical assistance to help conserve agricultural lands, wetlands, and their related benefits.

  9. Method for improving the durability of ion insertion materials

    DOE Patents [OSTI]

    Lee, Se-Hee; Tracy, C. Edwin; Cheong, Hyeonsik M.

    2002-01-01

    The invention provides a method of protecting an ion insertion material from the degradative effects of a liquid or gel-type electrolyte material by disposing a protective, solid ion conducting, electrically insulating, layer between the ion insertion layer and the liquid or gel-type electrolyte material. The invention further provides liquid or gel-type electrochemical cells having improved durability having a pair of electrodes, a pair of ion insertion layers sandwiched between the pair of electrodes, a pair of solid ion conducting layers sandwiched between the ion insertion layers, and a liquid or gel-type electrolyte material disposed between the solid ion conducting layers, where the solid ion conducting layer minimizes or prevents degradation of the faces of the ion insertion materials facing the liquid or gel-type electrolyte material. Electrochemical cells of this invention having increased durability include secondary lithium batteries and electrochromic devices.

  10. Moisture Durability with Vapor-Permeable Insulating Sheathing

    SciTech Connect (OSTI)

    Lepage, R.; Lstiburek, J.

    2013-09-01

    Exterior sheathing insulation is an effective strategy in increasing the overall R-value of wall assemblies; other benefits include decreasing the effects of thermal bridging and increasing the moisture durability of the built assembly. Vapor-permeable exterior insulation, such as mineral board or expanded polystyrene foam, are one such product that may be used to achieve these benefits. However, uncertainty exists on the effects of inward driven moisture and the interaction of increased sheathing temperatures on the moisture durability of the edifice. To address these concerns, Building Science Corporation (BSC) conducted a series of hygrothermal models for cities representing a range of different climate zones. This report describes the research project, key research questions, and the procedures utilized to analyse the problems.

  11. High Performance and Durable Low PGM Cathode Catalysts

    SciTech Connect (OSTI)

    Wang, Yong; Liu, Jun; Shao, Yuyan; Cheng, Yingwen; Borup, Rodney L.; Rockward, Tommy; Brosha, Eric Lanich

    2015-08-17

    There is a strong need to decrease the amount of Pt electrocatalyst used in fuel cells and increase its durability for transportation application. Conventional strategies include Pt nanocrystals and Pt alloy with well-controlled structures, durable carbon support, non-carbon support, etc. We have developed the so-called “metal-metal oxide-carbon” triple junction concept to stabilize Pt and protect carbon from corrosion. It also improved the activity of Pt. The good performance was not achieved in fuel cell test mainly because of the transport issue due to the use of 2D graphene. In this project, our main goal is to demonstrate the concept in fuel cell device test using 3D porous graphene as support so that the transport issue could be addressed.

  12. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1987-10-27

    AMAX Research Development Center (AMAX R D) has been investigating methods for improving the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hog coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. The reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point in a bench-scale fixed-bed reactor. The durability may be defined as the ability of the sorbent to maintain its reactivity and other important physical characteristics such as size, strength, and specific surface area during 10 cycles of sulfidation and regeneration. Two base case sorbents, spherical pellets and cylindrical extrudes used in related METC sponsored projects, are being used to provide a basis for the comparison of physical characteristics and chemical reactivity.

  13. Durable zinc ferrite sorbent pellets for hot coal gas desulfurization

    DOE Patents [OSTI]

    Jha, Mahesh C.; Blandon, Antonio E.; Hepworth, Malcolm T.

    1988-01-01

    Durable, porous sulfur sorbents useful in removing hydrogen sulfide from hot coal gas are prepared by water pelletizing a mixture of fine zinc oxide and fine iron oxide with inorganic and organic binders and small amounts of activators such as sodium carbonate and molybdenite; the pellets are dried and then indurated at a high temperature, e.g., 1800.degree. C., for a time sufficient to produce crush-resistant pellets.

  14. DOE-EERE Durability Working Group Meeting, October 10, 2010

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE-EERE Durability Working Group Meeting October 10, 2010 Agenda 6 pm Welcome and introductory comments Debbie Myers (Argonne) and Rod Borup (Los Alamos) - co-chairs 6:15 pm Overview of electrocatalyst and support degradation mechanisms Sarah Ball, Johnson Matthey Fuel Cells 6:45 pm Discussion/presentations by project PIs/representatives (5-10 minutes each) * Overview of electrocatalyst and support degradation aspects of projects * Protocols/testing procedures/diagnostics used to resolve the

  15. Hollow Nanoparticles as Active and Durable Catalysts - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Hollow Nanoparticles as Active and Durable Catalysts Brookhaven National Laboratory Contact BNL About This Technology <p> Performance characteristics of the hollow nanoparticle catalysts for the oxygen-reduction reaction</p> Performance characteristics of the hollow nanoparticle catalysts for the oxygen-reduction reaction Technology Marketing Summary Platinum is an excellent catalyst for many reactions. However, it is also very expensive. The catalytic activity per gram of

  16. Agricultural Marketing Toolkit

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Agricultural-Marketing-Toolkit Sign In About | Careers | Contact | Investors | bpa.gov Search Policy & Reporting Expand Policy & Reporting EE Sectors Expand EE Sectors...

  17. Durability of Polymeric Encapsulation Materials for Concentrating Photovoltaic Systems (Poster)

    SciTech Connect (OSTI)

    Miller, D. C.; Kempe, M. D.; Araki, K.; Kennedy, C. E.; Kurtz, S. R.

    2011-02-01

    Polymeric encapsulation materials are typically used in concentrating photovoltaic (CPV) modules to protect the cell from the field environment. Because it is physically located adjacent to the cell, the encapsulation is exposed to a high optical flux, often including light in the ultraviolet (UV) and infrared (IR) wavelengths. The durability of encapsulants used in CPV modules is critical to the technology, but is presently not well understood. This work seeks to identify the appropriate material types, field-induced failure mechanisms, and factors of influence (if possible) of polymeric encapsulation. These results will ultimately be weighed against those of future qualification and accelerated life test procedures.

  18. Chemically durable phosphate glasses and a method for their preparation

    DOE Patents [OSTI]

    Day, D.E.; Wilder, J.A. Jr.

    The chemical durability of alkali phosphate glasses is improved by incorporation of up to 23 weight percent of nitrogen. A typical phosphate glass contains: 10 to 60 mole % of Li/sub 2/O, Na/sub 2/O or K/sub 2/O; 5 to 40 mole % of BaO or CaO; 0 to 1 to 10 mole % of Al/sub 2/O/sub 3/; and 40 to 70 mole % of P/sub 2/O/sub 5/. Nitrides, such as AlN, are the favored additives.

  19. Durable silver thin film coating for diffraction gratings

    DOE Patents [OSTI]

    Wolfe, Jesse D.; Britten, Jerald A.; Komashko, Aleksey M.

    2006-05-30

    A durable silver film thin film coated non-planar optical element has been developed to replace Gold as a material for fabricating such devices. Such a coating and resultant optical element has an increased efficiency and is resistant to tarnishing, can be easily stripped and re-deposited without modifying underlying grating structure, improves the throughput and power loading of short pulse compressor designs for ultra-fast laser systems, and can be utilized in variety of optical and spectrophotometric systems, particularly high-end spectrometers that require maximized efficiency.

  20. Durable zinc oxide-containing sorbents for coal gas desulfurization

    DOE Patents [OSTI]

    Siriwardane, Ranjani V.

    1996-01-01

    Durable zinc-oxide containing sorbent pellets for removing hydrogen sulfide from a gas stream at an elevated temperature are made up to contain titania as a diluent, high-surface-area silica gel, and a binder. These materials are mixed, moistened, and formed into pellets, which are then dried and calcined. The resulting pellets undergo repeated cycles of sulfidation and regeneration without loss of reactivity and without mechanical degradation. Regeneration of the pellets is carried out by contacting the bed with an oxidizing gas mixture.

  1. New MEA Materials for Improved DMFC Performance, Durability and Cost

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    MEA Materials for Improved DMFC Performance, Durability and Cost Kick-Off Meeting PolyFuel Friday, August 21, 2009 Philip Cox Vice President, Product Development This presentation does not contain any proprietary, confidential, or otherwise restricted information Project Overview and Partners * Two and half years - Target: November 2009 through May 2012 - Project not yet started * Budget - Total: $3,116,971; DOE: $2,493,577 - Year 1 - $ 1,610,241 DOE: $ 322,048 - Year 2 - $ 1,506,730 DOE $

  2. DOE Durability Working Group October 2012 Meeting Agenda

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE Durability Working Group October 7, 2012 Meeting Agenda Hilton Hawaiian Village, Honolulu, HI 8:00 am Welcome and introductory comments Debbie Myers (Argonne), Rod Borup (Los Alamos) - co-chairs Nancy Garland (DOE) 8:10 am Dan Hussey, "Neutron Imaging of Fuel Cells at NIST" 8:35 am Discussion/presentations by project PIs/representatives (5 minutes each)  Overview/summary of major conclusions from projects thus far  Ballard, LANL-Borup, Argonne, LANL-Mukund, NREL, HNEI, 3M

  3. PEM Fuel Cell Freeze Durability and Cold Start Project

    SciTech Connect (OSTI)

    Patterson, T.; O'Neill, Jonathan

    2008-01-02

    UTC has taken advantage of the unique water management opportunities inherent in micro-porous bipolar-plates to improve the cold-start performance of its polymer electrolyte fuel cells (PEFC). Diagnostic experiments were used to determine the limiting factors in micro-porous plate PEFC freeze performance and the causes of any performance decay. Alternative cell materials were evaluated for their freeze performance. Freeze-thaw cycling was also performed to determine micro-porous plate PEFC survivability. Data from these experiments has formed the basis for continuing development of advanced materials capable of supporting DOE's cold-start and durability objectives.

  4. The Effect of Airborne Contaminants on Fuel Cell Performance & Durability |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy The Effect of Airborne Contaminants on Fuel Cell Performance & Durability The Effect of Airborne Contaminants on Fuel Cell Performance & Durability Presented at the Department of Energy Fuel Cell Projects Kickoff Meeting, September 1 - October 1, 2009 rocheleau_uhawaii_kickoff.pdf (340.84 KB) More Documents & Publications Supporting a Hawaii Hydrogen Economy Effects of Impurities of Fuel Cell Performance and Durability Effect of System and Air Contaminants on

  5. State-of-the-art Fuel Cell Voltage Durability Status: 2015 Composite Data Products

    SciTech Connect (OSTI)

    Kurtz, Jennfier; Dinh, Huyen; Ainscough, Chris; Saur, Genevieve

    2015-05-01

    This publication includes 14 composite data products (CDPs) produced in 2015 for fuel cell technology status, focusing on state-of-the-art fuel cell voltage durability.

  6. Durable silver mirror with ultra-violet thru far infra-red reflection

    DOE Patents [OSTI]

    Wolfe, Jesse D.

    2010-11-23

    A durable highly reflective silver mirror characterized by high reflectance in a broad spectral range of about 300 nm in the UV to the far infrared (.about.10000 nm), as well as exceptional environmental durability. A high absorptivity metal underlayer is used which prevents the formation of a galvanic cell with a silver layer while increasing the reflectance of the silver layer. Environmentally durable overcoat layers are provided to enhance mechanical and chemical durability and protect the silver layer from corrosion and tarnishing, for use in a wide variety of surroundings or climates, including harsh or extreme environments.

  7. Building a Durable and Energy Efficient Home in Post-Katrina New Orleans

    SciTech Connect (OSTI)

    Peter Baker

    2008-07-08

    This report examines designing homes with key sustainability concepts, durability, and energy efficiency that can provide insurance to people in the event of a hurricane.

  8. Fuel Cell Measurements of Performance and Durability of Non-PGM...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Cell Measurements of Performance and Durability of Non-PGM ORR Electrocatalysts (60.39 KB) More Documents & Publications Catalysis Working Group Meeting: June 2014 Catalysis ...

  9. The Development and On-Road Performance and Durability of the...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Development and On-Road Performance and Durability of the Four-Way Emission Control SCRTTM System 2003 DEER Conference Presentation: Johnson Matthey plc, Cummins Inc. ...

  10. Urea SCR Durability Assessment for Tier 2 Light-Duty Truck

    Broader source: Energy.gov [DOE]

    Summarizes progress toward development of a durable urea SCR system to meet Tier 2 Bin 5 on 3780 lb light truck

  11. Regeneration and Durability of Advanced Zinc Ferrite Sorbent for Hot Coal Gas Desulfurization

    SciTech Connect (OSTI)

    Shirai, H.; Kobayashi, M.; Nunokawa, M.; Noda, N.

    2002-09-19

    In this study, we investigate the regeneration characteristics, desulfurization performance after regeneration and the durability of zinc ferrite sorbent in the desulfurization/regeneration cycles.

  12. Enhanced durability of desulfurization sorbents for fluidized-bed applications

    SciTech Connect (OSTI)

    Gupta, R.P.; Gangwal, S.K.

    1991-06-01

    Advanced integrated gasification combined cycle (IGCC) power systems require the development of high-temperature desulfurization sorbents capable of removing hydrogen sulfide from coal gasifier down to very low levels. The objective of this investigation was to identify and demonstrate methods for enhancing the long-term chemical reactivity and mechanical strength of zinc ferrite, a leading regenerable sorbent, for fluidized-bed applications. Fluidized sorbent beds offer significant potential in IGCC systems because of their ability to control the highly exothermic regeneration involved. However, fluidized beds require a durable, attrition-resistant sorbent in the 100--300 {mu}m size range. A bench-scale high-temperature, high- pressure (HTHP) fluidized-bed reactor (7.6-cm I.D.) system capable of operating up to 24 atm and 800{degree}C was designed, built and tested. A total of 175 sulfidation-regeneration cycles were carried out using KRW-type coal gas with various zinc ferrite formulations. A number of sorbent manufacturing techniques including spray drying, impregnation, crushing and screening, and granulation were investigated. While fluidizable sorbents prepared by crushing durable pellets and screening had acceptable sulfur capacity, they underwent excessive attrition during multicycle testing. The sorbent formulations prepared by a proprietary technique were found to have excellent attrition resistance and acceptable chemical reactivity during multicycle testing. However, zinc ferrite was found to be limited to 550{degree}C, beyond which excessive sorbent weakening due to chemical transformations, e.g., iron oxide reduction, was observed.

  13. On the Existence of Our Metals-Based Civilization: I. Phase Space Analysis

    SciTech Connect (OSTI)

    D.D. Macdonald

    2005-06-22

    than are equilibrium thermodynamic diagrams. Thus, KSDs more accurately account for the limits of passivity in highly acidic systems, where acid depassivation occurs, and at high potentials, where transition to the transpassive state may occur in some systems. In any event, phase space analysis of the PDM permits specification of the conditions over which reactive metals will remain passive in contact with aqueous systems and hence of the conditions that must be met for the existence of our metals-based civilization.

  14. Kentucky Department of Agriculture

    Broader source: Energy.gov [DOE]

    At the August 7, 2008 quarterly joint Web conference of DOE's Biomass and Clean Cities programs, Wilbur Frye (Office of Consumer & Environmental Protection, Kentucky Department of Agriculture) described Biofuel Quality Testing in Kentucky.

  15. Durability Testing of Fluidized Bed Steam Reforming Products

    SciTech Connect (OSTI)

    JANTZEN, CAROL M.; PAREIZS, JOHN M.; LORIER, TROY H.; MARRA, JAMES C.

    2005-07-01

    Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of radioactive wastes but especially aqueous high sodium wastes at the Hanford site, at the Idaho National Laboratory (INL), and at the Savannah River Site (SRS). The FBSR technology converts organic compounds to CO{sub 2} and H{sub 2}O, converts nitrate/nitrite species to N{sub 2}, and produces a solid residue through reactions with superheated steam, the fluidizing media. If clay is added during processing a ''mineralized'' granular waste form can be produced. The mineral components of the waste form are primarily Na-Al-Si (NAS) feldspathoid minerals with cage-like and ring structures and iron bearing spinel minerals. The cage and ring structured minerals atomically bond radionuclides like Tc{sup 99} and Cs{sup 137} and anions such as SO{sub 4}, I, F, and Cl. The spinel minerals appear to stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Durability testing of the FBSR products was performed using ASTM C1285 (Product Consistency Test) and the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP). The FBSR mineral products (bed and fines) evaluated in this study were found to be two orders of magnitude more durable than the Hanford Low Activity Waste (LAW) glass requirement of 2 g/m{sup 2} release of Na{sup +}. The PCT responses for the FBSR samples tested were consistent with results from previous FBSR Hanford LAW product testing. Differences in the response can be explained by the minerals formed and their effects on PCT leachate chemistry.

  16. Moisture Durability Assessment of Selected Well-insulated Wall Assemblies

    SciTech Connect (OSTI)

    Pallin, Simon B.; Boudreaux, Philip R.; Kehrer, Manfred; Hun, Diana E.; Jackson, Roderick K.; Desjarlais, Andre Omer

    2015-12-01

    This report presents the results from studying the hygrothermal performance of two well-insulated wall assemblies, both complying with and exceeding international building codes (IECC 2015 2014, IRC 2015). The hygrothermal performance of walls is affected by a large number of influential parameters (e.g., outdoor and indoor climates, workmanship, material properties). This study was based on a probabilistic risk assessment in which a number of these influential parameters were simulated with their natural variability. The purpose of this approach was to generate simulation results based on laboratory chamber measurements that represent a variety of performances and thus better mimic realistic conditions. In total, laboratory measurements and 6,000 simulations were completed for five different US climate zones. A mold growth indicator (MGI) was used to estimate the risk of mold which potentially can cause moisture durability problems in the selected wall assemblies. Analyzing the possible impact on the indoor climate due to mold was not part of this study. The following conclusions can be reached from analyzing the simulation results. In a hot-humid climate, a higher R-value increases the importance of the airtightness because interior wall materials are at lower temperatures. In a cold climate, indoor humidity levels increase with increased airtightness. Air leakage must be considered in a hygrothermal risk assessment, since air efficiently brings moisture into buildings from either the interior or exterior environment. The sensitivity analysis of this study identifies mitigation strategies. Again, it is important to remark that MGI is an indicator of mold, not an indicator of indoor air quality and that mold is the most conservative indicator for moisture durability issues.

  17. Effect of glass composition on waste form durability: A critical review

    SciTech Connect (OSTI)

    Ellison, A.J.G.; Mazer, J.J.; Ebert, W.L.

    1994-11-01

    This report reviews literature concerning the relationship between the composition and durability of silicate glasses, particularly glasses proposed for immobilization of radioactive waste. Standard procedures used to perform durability tests are reviewed. It is shown that tests in which a low-surface area sample is brought into contact with a very large volume of solution provide the most accurate measure of the intrinsic durability of a glass composition, whereas high-surface area/low-solution volume tests are a better measure of the response of a glass to changes in solution chemistry induced by a buildup of glass corrosion products. The structural chemistry of silicate and borosilicate glasses is reviewed to identify those components with the strongest cation-anion bonds. A number of examples are discussed in which two or more cations engage in mutual bonding interactions that result in minima or maxima in the rheologic and thermodynamic properties of the glasses at or near particular optimal compositions. It is shown that in simple glass-forming systems such interactions generally enhance the durability of glasses. Moreover, it is shown that experimental results obtained for simple systems can be used to account for durability rankings of much more complex waste glass compositions. Models that purport to predict the rate of corrosion of glasses in short-term durability tests are evaluated using a database of short-term durability test results for a large set of glass compositions. The predictions of these models correlate with the measured durabilities of the glasses when considered in large groupings, but no model evaluated in this review provides accurate estimates of durability for individual glass compositions. Use of these models in long-term durability models is discussed. 230 refs.

  18. Agricultural Equipment Technology Conference

    Broader source: Energy.gov [DOE]

    The 20th Agricultural Equipment Technology Conference will be held Feb. 8–10, 2016, in Louisville, Kentucky. The conference will bring together professionals and experts in the agricultural and biological engineering fields. Bioenergy Technologies Office (BETO) Terrestrial Feedstocks Technology Manager Sam Tagore will be in attendance. Mr. Tagore will moderate a technical session titled “Ash Reduction Strategies for Improving Biomass Feedstock Quality.” The session will include presentations by researchers from Idaho National Laboratory and Oak Ridge National Laboratory supporting BETO, as well as from university and industry.

  19. FC-PAD: Fuel Cell Consortium for Performance and Durability | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy FC-PAD: Fuel Cell Consortium for Performance and Durability FC-PAD: Fuel Cell Consortium for Performance and Durability Illustration of the research consortia model showing a 'National Laboratory Core Team' as the central role with three sub-groups of University &amp; Non-Profit, Industry, and National Lab contributing to the core. The Fuel Cell Consortium for Performance and Durability (FC-PAD) will aid in the understanding of-and lead to significant improvements in-fuel cell

  20. Superhydrophobic durable coating based on UV-photoreactive silica nanoparticles

    SciTech Connect (OSTI)

    Nahum, T.; Dodiuk, H.; Dotan, A.; Kenig, S.; Lellouche, J. P.

    2015-05-22

    Superhydrophobic surfaces with contact angle (CA) >150 and sliding angle (SA) <10 have been aroused curiosity over the years due to their various applications. Superhydrophobicity can be obtained tailoring the chemistry and the roughness of the surface, mimicking the Lotus flower. Most superhydrophobic surfaces based on secondary bonding lose their roughness in harsh conditions and are unsuitable for practical applications. Photoreactive SiO{sub 2} nanoparticles (NPs) based on benzophenone (BP) can be a very effective tool for formation of reactive species that function as a molecular bridge by covalent bonding between the NP and any polymer matrix with C-C and C-H bonds. The present work focused on thermoset radiation curing urethane acrylate. Upon UV irradiation reactive excited nπ* triplet benzophenone species are formed and react through hydrogen abstraction to form ketyl radicals which interact with a radicals from the UV irradiated polymer matrix to yield covalent bonding. Roughness was achieved by dipping the substrate in SiO{sub 2}@BPs NPs dispersion followed by irradiation. Fluoroalkylsilane was used to obtain hydrophobic top layer. AFM nano manipulation was used to verify the immobilization of NPs. Evaluation of durability was made using air flow at 300 km/hr. Preliminary results indicate the formation of super hydrophobic surfaces (CA>150 and SA<10) with improved stability.

  1. Durable pd-based alloy and hydrogen generation membrane thereof

    DOE Patents [OSTI]

    Benn, Raymond C.; Opalka, Susanne M.; Vanderspurt, Thomas Henry

    2010-02-02

    A durable Pd-based alloy is used for a H.sub.2-selective membrane in a hydrogen generator, as in the fuel processor of a fuel cell plant. The Pd-based alloy includes Cu as a binary element, and further includes "X", where "X" comprises at least one metal from group "M" that is BCC and acts to stabilize the .beta. BCC phase for stability during operating temperatures. The metal from group "M" is selected from the group consisting of Fe, Cr, Nb, Ta, V, Mo, and W, with Nb and Ta being most preferred. "X" may further comprise at least one metal from a group "N" that is non-BCC, preferably FCC, that enhances other properties of the membrane, such as ductility. The metal from group "N" is selected from the group consisting of Ag, Au, Re, Ru, Rh, Y, Ce, Ni, Ir, Pt, Co, La and In. The at. % of Pd in the binary Pd--Cu alloy ranges from about 35 at. % to about 55 at. %, and the at. % of "X" in the higher order alloy, based on said binary alloy, is in the range of about 1 at. % to about 15 at. %. The metals are selected according to a novel process.

  2. Durability of Polymeric Encapsulation Materials for Concentrating Photovoltaic Systems (Presentation)

    SciTech Connect (OSTI)

    Miller, D. C.; Muller, M.; Kempe, M. D.; Araki, K.; Kennedy, C. E.; Kurtz, S. R.

    2012-03-01

    Many concentrating photovoltaic (CPV) systems use a polymeric encapsulant to couple and optical component and/or coverglass to the cell. In that location, the encapsulation improves the transmission of concentrated optical flux through interface(s), while protecting the cell from the environment. The durability of encapsulation materials, however, is not well established relative to the desired service life of 30 years. Therefore, we have initiated a screen test to identify the field-induced failure modes for a variety of popular PV encapsulation materials. An existing CPV module (with no PV cells present) was modified to accommodate encapsulation specimens. The module (where nominal concentration of solar flux is 500x for the domed-Fresnel design) has been mounted on a tracker in Golden, CO (elevation 1.79 km). Initial results are reported here for 18 months cumulative exposure, including the hottest and coldest months of the past year. Characteristics observed at intervals during that time include: visual appearance, direct and hemispherical transmittance, and mass. Degradation may be assessed from subsequent analysis (including yellowness index and cut-on frequency) relative to the ambient conditions present during field exposure. The fluorescence signature observed of all the silicone specimens is examined here, including possible factors of causation -- the platinum catalyst used in the addition cured materials as well as the primer used to promote adhesion to the quartz substrate and superstrate.

  3. Durable Airtightness in Single-Family Dwellings - Field Measurementsand Analysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chan, Wanyu R.; Walker, Iain S.; Sherman, Max H.

    2015-06-01

    Here, durability of the building envelope is important to new homes that are increasingly built with improved levels of airtightness. It is also important to weatherized homes such that energy savings from retrofit measures, such as air sealing, are persistent. This paper presents a comparison of air leakage measurements collected in November 2013 through March 2014, with two sets of prior data collected between 2001-2003 from 17 new homes located near Atlanta, GA, and 17 homes near Boise, ID that were weatherized in 2007- 2008. The purpose of the comparison is to determine if there are changes to the airtightnessmore » of building envelopes over time. The air leakage increased in all but one of the new homes, with a mean increase of about 25%. The weatherized homes also showed an increase in the mean air leakage (12%). A regression analysis was performed to describe the relationship between prior and current measurements in terms of normalized leakage (NL). The best estimate of the ageing factor predicts a 15% increase in NL over ten years. Further analysis using ResDB data (LBNL’s Residential Diagnostic Database) showed the expected changes in air leakage if ageing were modelled. These results imply the need to examine the causes of increased leakage and methods to avoid them. This increase in leakage with time should be accounted for in long-term population-wide energy savings estimates, such as those used in ratings or energy savings programs.« less

  4. New MEA Materials for Improved DMFC Performance, Durability and Cost

    SciTech Connect (OSTI)

    Fletcher, James H.; Campbell, Joseph L.; Cox, Philip; Harrington, William J.

    2013-09-16

    Abstract Project Title: New MEA Materials for Improved DMFC Performance, Durability and Cost The University of North Florida (UNF)--with project partners the University of Florida, Northeastern University, and Johnson Matthey--has recently completed the Department of Energy (DOE) project entitled “New MEA Materials for Improved DMFC Performance, Durability and Cost”. The primary objective of the project was to advance portable fuel cell MEA technology towards the commercial targets as laid out in the DOE R&D roadmap by developing a passive water recovery MEA (membrane electrode assembly). Developers at the University of North Florida identified water management components as an insurmountable barrier to achieving the required system size and weight necessary to achieve the energy density requirements of small portable power applications. UNF developed an innovative “passive water recovery” MEA for direct methanol fuel cells (DMFC) which provides a path to system simplification and optimization. The passive water recovery MEA incorporates a hydrophobic, porous, barrier layer within the cathode electrode, so that capillary pressure forces the water produced at the cathode through holes in the membrane and back to the anode. By directly transferring the water from the cathode to the anode, the balance of plant is very much simplified and the need for heavy, bulky water recovery components is eliminated. At the heart of the passive water recovery MEA is the UNF DM-1 membrane that utilizes a hydrocarbon structure to optimize performance in a DMFC system. The membrane has inherent performance advantages, such as a low methanol crossover (high overall efficiency), while maintaining a high proton conductivity (good electrochemical efficiency) when compared to perfluorinated sulfonic acid membranes such as Nafion. Critically, the membrane provides an extremely low electro-osmotic drag coefficient of approximately one water molecule per proton (versus the 2-3 for

  5. A New Approach in Urea Dosing to Improve Performance and Durability...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Approach in Urea Dosing to Improve Performance and Durability of SCR Systems for the Use in Off-Road Applications to Fulfill Tier 4 Final A New Approach in Urea Dosing to Improve ...

  6. Sulfur tolerant highly durable CO.sub.2 sorbents (Patent) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Sulfur tolerant highly durable CO.sub.2 sorbents A sorbent for the capture of carbon dioxide from a gas stream is provided, the sorbent ...

  7. State-of-the-Art Fuel Cell Voltage Durability Status: Spring 2013 Composite Data Products

    SciTech Connect (OSTI)

    Kurtz, J.; Sprik, S.; Saur, G.; Peters, M.; Post, M.; Ainscough, C.

    2013-05-01

    This presentation from the U.S. Department of Energy's National Renewable Energy Laboratory includes composite data products (CDPs) produced in 2013 for state-of-the-art fuel cell voltage durability status.

  8. The Development and On-Road Performance and Durability of the Four-Way

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emission Control SCRTTM System | Department of Energy The Development and On-Road Performance and Durability of the Four-Way Emission Control SCRTTM System The Development and On-Road Performance and Durability of the Four-Way Emission Control SCRTTM System 2003 DEER Conference Presentation: Johnson Matthey plc, Cummins Inc. 2003_deer_walker.pdf (535.28 KB) More Documents & Publications SCRT Technology for Retrofit of Heavy-Duty Diesel Applications Update on Diesel Exhaust Emission

  9. Development of a Durable Low-Temperature Urea-SCR Catalyst for CIDI Engines

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Durable Low-Temperature Urea-SCR Catalyst for CIDI Engines Development of a Durable Low-Temperature Urea-SCR Catalyst for CIDI Engines 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Sandia National Laboratories 2004_deer_pena.pdf (298.19 KB) More Documents & Publications Experimental and Modelling Study of the Effect of Diffusional Limitations on the NH3 SCR Activity Vehicle Technologies Office Merit Review 2016: Innovative SCR Materials and

  10. Analysis of the Durability of PEM FC Membrane Electrode Assemblies in

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Automotive Applications | Department of Energy the Durability of PEM FC Membrane Electrode Assemblies in Automotive Applications Analysis of the Durability of PEM FC Membrane Electrode Assemblies in Automotive Applications These slides were presented at the 2010 New Fuel Cell Projects Meeting on September 28, 2010. 10_dupont_perry.pdf (204.87 KB) More Documents & Publications DOE Fuel Cell Pre-Solicitation Workshop - Breakout Group 2: MEAs, Components, and Integration Membranes and MEAs

  11. Impact of Biodiesel on the Near-term Performance and Long-term Durability

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Advanced Aftertreatment Systems | Department of Energy on the Near-term Performance and Long-term Durability of Advanced Aftertreatment Systems Impact of Biodiesel on the Near-term Performance and Long-term Durability of Advanced Aftertreatment Systems Compare SCR catalyst performance with ULSD and Soy B20 through engine testing deer09_williams.pdf (1.02 MB) More Documents & Publications Vehicle Technologies Office Merit Review 2014: Biofuel Impacts on Aftertreatment Devices

  12. Enhanced durability of desulfurization sorbents for fluidized-bed applications

    SciTech Connect (OSTI)

    Gupta, R.P.; Gangwal, S.K.

    1992-11-01

    To extend the operating temperature range and further improve the durability of fluidizable sorbents, zinc titanate, another leading regenerable sorbent, was selected for development in the later part of this project. A number of zinc titanate formulations were prepared in the 50 to 300 [mu]m range using granulation and spray drying methods. Important sorbent preparation variables investigated included zinc to titanium ratio, binder type, binder amount, and various chemical additives such as cobalt and molybdenum. A number of sorbents selected on the basis of screening tests were subjected to bench-scale testing for 10 cycles at high temperature, high pressure (HTHP) conditions using the reactor system designed and constructed during the base program. This reactor system is capable of operation either as a 2.0 in. or 3.0 in. I.D. bubbling bed and is rated up to 20 atm operation at 871[degrees]C. Bench-scale testing variables included sorbent type, temperature (550 to 750[degrees]C), gas type (KRW or Texaco gasifier gas), steam content of coal gas, and fluidizing gas velocity (6 to 15 cm/s). The sorbents prepared by spray drying showed poor performance in terms of attrition resistance and chemical reactivity. On the other hand, the granulation method proved to be very successful. For example, a highly attrition-resistant zinc titanate formulation, ZT-4, prepared by granulation exhibited virtually no zinc loss and demonstrated a constant high reactivity and sulfur capacity over 10 cycles, i.e., approximately a 60 percent capacity utilization, with Texaco gas at 750[degrees]C, 15 cm/s fluidizing velocity and 15 atm pressure. The commercial potential of the granulation method for zinc titanate manufacture was demonstrated by preparing two 80 lb batches of sorbent with zinc to titanium mol ratios of 0.8 and 1.5.

  13. Enhanced durability of desulfurization sorbents for fluidized-bed applications

    SciTech Connect (OSTI)

    Gupta, R.P.; Gangwal, S.K.

    1992-11-01

    To extend the operating temperature range and further improve the durability of fluidizable sorbents, zinc titanate, another leading regenerable sorbent, was selected for development in the later part of this project. A number of zinc titanate formulations were prepared in the 50 to 300 {mu}m range using granulation and spray drying methods. Important sorbent preparation variables investigated included zinc to titanium ratio, binder type, binder amount, and various chemical additives such as cobalt and molybdenum. A number of sorbents selected on the basis of screening tests were subjected to bench-scale testing for 10 cycles at high temperature, high pressure (HTHP) conditions using the reactor system designed and constructed during the base program. This reactor system is capable of operation either as a 2.0 in. or 3.0 in. I.D. bubbling bed and is rated up to 20 atm operation at 871{degrees}C. Bench-scale testing variables included sorbent type, temperature (550 to 750{degrees}C), gas type (KRW or Texaco gasifier gas), steam content of coal gas, and fluidizing gas velocity (6 to 15 cm/s). The sorbents prepared by spray drying showed poor performance in terms of attrition resistance and chemical reactivity. On the other hand, the granulation method proved to be very successful. For example, a highly attrition-resistant zinc titanate formulation, ZT-4, prepared by granulation exhibited virtually no zinc loss and demonstrated a constant high reactivity and sulfur capacity over 10 cycles, i.e., approximately a 60 percent capacity utilization, with Texaco gas at 750{degrees}C, 15 cm/s fluidizing velocity and 15 atm pressure. The commercial potential of the granulation method for zinc titanate manufacture was demonstrated by preparing two 80 lb batches of sorbent with zinc to titanium mol ratios of 0.8 and 1.5.

  14. Study on durability for thermal cycle of planar SOFC

    SciTech Connect (OSTI)

    Ando, Motoo; Nakata, Kei-ichi; Wakayama, Sin-ichi

    1996-12-31

    TONEN CORPORATION has developed planar type SOFC since 1986. We demonstrated the output of 1.3 kW in 1991 and 5.1 kW in 1995. Simultaneously we have studied how to raise electric efficiency and reliability utilizing hydrogen and propane as fuel. Durability for thermal cycle is one of the most important problems of planar SOFC to make it more practical. The planar type SOFC is made up of separator, zirconia electrolyte and glass sealant. The thermal expansion of these components are expected to be the same value, however, they still possess small differences. In this situation, a thermal cycle causes a thermal stress due to the difference of the cell components and is often followed by a rupture in cell components, therefore, the analysis of the thermal stress should give us much useful information. The thermal cycle process consists of a heating up and cooling down procedure. Zirconia electrolyte is not bonded to the separator under the condition of the initial heating up procedure, and glass sealant becomes soft or melts and glass seals spaces between the zirconia and separator. The glass sealant becomes harder with the cooling down procedure. Moreover, zirconia is tightly bonded with separator below a temperature which is defined as a constraint temperature and thermal stress also occurs. This indicates that the heating up process relaxes the thermal stress and the cooling down increases it. In this paper, we simulated dependence of the stress on the sealing configuration, thermal expansion of sealant and constraint temperature of sealant glass. Furthermore, we presented SOFC electrical properties after a thermal cycle.

  15. Sustainable Agriculture Network | Open Energy Information

    Open Energy Info (EERE)

    Agriculture Network Jump to: navigation, search Logo: Sustainable Agriculture Network Name: Sustainable Agriculture Network Website: clima.sanstandards.org References: Sustainable...

  16. NREL Determines Better Testing Methods for Photovoltaic Module Durability (Fact Sheet), NREL Highlights, Research & Development

    SciTech Connect (OSTI)

    Not Available

    2011-11-01

    NREL discoveries will enable manufacturers to produce more robust photovoltaic modules. Over the past decade, some photovoltaic (PV) modules have experienced power losses because of the system voltage stress that modules experience in fielded arrays. This is partly because qualification tests and standards do not adequately evaluate the durability of modules that undergo the long-term effects of high voltage. Scientists at the National Renewable Energy Laboratory (NREL) tried various testing methods and stress levels to demonstrate module durability to system voltage potential-induced degradation (PID) mechanisms. The results of these accelerated tests, along with outdoor testing, were used to estimate the acceleration factors needed to more accurately evaluate the durability of modules to system voltage stress. NREL was able to determine stress factors, levels, and methods for testing based on the stresses experienced by modules in the field. These results, in combination with those in the literature, suggest that constant stress with humidity and system voltage is more damaging than stress applied intermittently or with periods of recovery comprising hot and dry conditions or alternating bias in between. NREL has determined some module constructions to be extremely durable to PID. These findings will help the manufacturers of PV materials and components produce more durable products that better satisfy their customers. NREL determined that there is rapid degradation of some PV modules under system voltage stress and evaluated degradation rates in the field to develop more accurate accelerated testing methods. PV module manufacturers will be better able to choose robust materials and durable designs and guarantee sturdier, longer-lasting products. As PV modules become more durable, and thus more efficient over the long term, the risks and the cost of PV power will be reduced.

  17. Measurement of Exterior Foundation Insulation to Assess Durability in Energy-Saving Performance

    SciTech Connect (OSTI)

    Kehrer, Manfred; Christian, Jeff

    2012-04-01

    The foundation of a house is a sometimes ignored component of the building because of its low visibility. It is increasingly evident, however, that attention to good foundation design and construction significantly benefits the homeowner and the builder by mitigating future problems. Good foundation design and construction practice involves not only insulating to save energy but also providing effective structural design as well as moisture, termite, and radon control techniques as appropriate. Energy efficiency in housing is augmented by use of exterior slab and basement insulation, but high moisture content in the insulation material has led to concerns about its durability. The activity under this task was to extract six different exterior insulation systems that were characterized at installation and have been in the ground for 9 months to 15 years. R-value and moisture content were measured and inspections conducted for evidence of termite intrusion or deterioration. Based on the results, the durability of the various systems has been documented and assessments made of which systems appear to be best practice. Heat flux and temperature measurement data had been archived for some of the exterior insulation tests, thereby providing a unique opportunity to assess energy-saving performance and durability over the long term. The results show that the durability of foundation insulation systems depends on insulation type as well as on foundation type and local boundary conditions, the latter of which may have a marked influence on the durability of energy-saving performance.

  18. Chemical durability of soda-lime-aluminosilicate glass for radioactive waste vitrification

    SciTech Connect (OSTI)

    Eppler, F.H.; Yim, M.S. [North Carolina State Univ., Raleigh, NC (United States)

    1998-09-01

    Vitrification has been identified as one of the most viable waste treatment alternatives for nuclear waste disposal. Currently, the most popular glass compositions being selected for vitrification are the borosilicate family of glasses. Another popular type that has been around in glass industry is the soda-lime-silicate variety, which has often been characterized as the least durable and a poor candidate for radioactive waste vitrification. By replacing the boron constituent with a cheaper substitute, such as silica, the cost of vitrification processing can be reduced. At the same time, addition of network intermediates such as Al{sub 2}O{sub 3} to the glass composition increases the environmental durability of the glass. The objective of this study is to examine the ability of the soda-lime-aluminosilicate glass as an alternative vitrification tool for the disposal of radioactive waste and to investigate the sensitivity of product chemical durability to variations in composition.

  19. Durability-Based Design Guide for an Automotive Structural Composite: Part 2. Background Data and Models

    SciTech Connect (OSTI)

    Corum, J.M.; Battiste, R.L.; Brinkman, C.R.; Ren, W.; Ruggles, M.B.; Weitsman, Y.J.; Yahr, G.T.

    1998-02-01

    This background report is a companion to the document entitled ''Durability-Based Design Criteria for an Automotive Structural Composite: Part 1. Design Rules'' (ORNL-6930). The rules and the supporting material characterization and modeling efforts described here are the result of a U.S. Department of Energy Advanced Automotive Materials project entitled ''Durability of Lightweight Composite Structures.'' The overall goal of the project is to develop experimentally based, durability-driven design guidelines for automotive structural composites. The project is closely coordinated with the Automotive Composites Consortium (ACC). The initial reference material addressed by the rules and this background report was chosen and supplied by ACC. The material is a structural reaction injection-molded isocyanurate (urethane), reinforced with continuous-strand, swirl-mat, E-glass fibers. This report consists of 16 position papers, each summarizing the observations and results of a key area of investigation carried out to provide the basis for the durability-based design guide. The durability issues addressed include the effects of cyclic and sustained loadings, temperature, automotive fluids, vibrations, and low-energy impacts (e.g., tool drops and roadway kickups) on deformation, strength, and stiffness. The position papers cover these durability issues. Topics include (1) tensile, compressive, shear, and flexural properties; (2) creep and creep rupture; (3) cyclic fatigue; (4) the effects of temperature, environment, and prior loadings; (5) a multiaxial strength criterion; (6) impact damage and damage tolerance design; (7) stress concentrations; (8) a damage-based predictive model for time-dependent deformations; (9) confirmatory subscale component tests; and (10) damage development and growth observations.

  20. Chemical durability and degradation mechanisms of HT9 based alloy waste forms with variable Zr content

    SciTech Connect (OSTI)

    Olson, L. N.

    2015-10-30

    In Corrosion studies were undertaken on alloy waste forms that can result from advanced electrometallurgical processing techniques to better classify their durability and degradation mechanisms. The waste forms were based on the RAW3-(URe) composition, consisting primarily of HT9 steel and other elemental additions to simulate nuclear fuel reprocessing byproducts. The solution conditions of the corrosion studies were taken from an electrochemical testing protocol, and meant to simulate conditions in a repository. The alloys durability was examined in alkaline and acidic brines.

  1. Stay-Clean and Durable White Elastomeric Roof Coatings | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Stay-Clean and Durable White Elastomeric Roof Coatings Stay-Clean and Durable White Elastomeric Roof Coatings Lead Performer: Lawrence Berkeley National Laboratory - Berkeley, CA Partner: Dow Chemical - Midland, MI DOE Funding: $570,000 Cost Share: $449,000 Project Term: 10/1/2011 - 9/30/2014 Project Objective This project is developing stay-clean white elastomeric roof coatings (ERCs) with a three-year aged solar reflectance (SR) of at least 0.75 and a service life of 15 years or

  2. Method and apparatus for increasing the durability and yield of thin film photovoltaic devices

    DOE Patents [OSTI]

    Phillips, James E.; Lasswell, Patrick G.

    1987-01-01

    Thin film photovoltaic cells having a pair of semiconductor layers between an opaque and a transparent electrical contact are manufactured in a method which includes the step of scanning one of the semiconductor layers to determine the location of any possible shorting defect. Upon the detection of such defect, the defect is eliminated to increase the durability and yield of the photovoltaic device.

  3. Oxidation of platinum nickel nanowires to improve durability of oxygen-reducing electrocatalysts

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Alia, Shaun M.; Pylypenko, Svitlana; Dameron, Arrelaine; Neyerlin, Kenneth C.; Kocha, Shyam S.; Pivovar, Bryan S.

    2016-01-12

    In this study, the impact of heat treating platinum-coated nickel (Pt-Ni) nanowires in oxygen is examined to determine the effect on oxygen reduction (ORR) activity and durability. Pt-Ni nanowires exhibit promising ORR mass activities (3 times greater than Pt nanoparticles, 1.5 times greater than U.S. Department of Energy target) both before and after potential cycling for all but the highest annealing temperatures explored. The annealing of Pt-Ni nanowires in oxygen with increasing temperature is found to reduce surface area and ORR activity in comparison to the untreated material, but also reduces activity losses following durability testing. Following potential cycling, unannealedmore » Pt-Ni nanowires show significant losses in surface area (23%) and specific activity (18%) while Pt-Ni nanowires annealed at 200°C show modest increases in surface area (2%) and specific activity (6%) after potential cycling. Increasing annealing temperatures also show a clear trend of decreasing Ni dissolution rates. While oxygen annealing has shown the ability to improve durability of Pt-Ni nanowires, significant Ni dissolution was observed in all samples and suggests oxide passivation while showing promise for improved durability, when employed by itself is insufficient to prevent all contamination concerns involving Ni dissolution.« less

  4. Extremely durable biofouling-resistant metallic surfaces based on electrodeposited nanoporous tungstite films on steel

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tesler, Alexander B.; Kim, Philseok; Kolle, Stefan; Howell, Caitlin; Ahanotu, Onye; Aizenberg, Joanna

    2015-10-20

    Formation of unwanted deposits on steels during their interaction with liquids is an inherent problem that often leads to corrosion, biofouling and results in reduction in durability and function. Here we report a new route to form anti-fouling steel surfaces by electrodeposition of nanoporous tungsten oxide (TO) films. TO-modified steels are as mechanically durable as bare steel and highly tolerant to compressive and tensile stresses due to chemical bonding to the substrate and island-like morphology. When inherently superhydrophilic TO coatings are converted to superhydrophobic, they remain non-wetting even after impingement with yttria-stabilized-zirconia particles, or exposure to ultraviolet light and extrememore » temperatures. Upon lubrication, these surfaces display omniphobicity against highly contaminating media retaining hitherto unseen mechanical durability. Furthermore, to illustrate the applicability of such a durable coating in biofouling conditions, we modified naval construction steels and surgical instruments and demonstrated significantly reduced marine algal film adhesion, Escherichia coli attachment and blood staining.« less

  5. Extremely durable biofouling-resistant metallic surfaces based on electrodeposited nanoporous tungstite films on steel

    SciTech Connect (OSTI)

    Tesler, Alexander B.; Kim, Philseok; Kolle, Stefan; Howell, Caitlin; Ahanotu, Onye; Aizenberg, Joanna

    2015-10-20

    Formation of unwanted deposits on steels during their interaction with liquids is an inherent problem that often leads to corrosion, biofouling and results in reduction in durability and function. Here we report a new route to form anti-fouling steel surfaces by electrodeposition of nanoporous tungsten oxide (TO) films. TO-modified steels are as mechanically durable as bare steel and highly tolerant to compressive and tensile stresses due to chemical bonding to the substrate and island-like morphology. When inherently superhydrophilic TO coatings are converted to superhydrophobic, they remain non-wetting even after impingement with yttria-stabilized-zirconia particles, or exposure to ultraviolet light and extreme temperatures. Upon lubrication, these surfaces display omniphobicity against highly contaminating media retaining hitherto unseen mechanical durability. Furthermore, to illustrate the applicability of such a durable coating in biofouling conditions, we modified naval construction steels and surgical instruments and demonstrated significantly reduced marine algal film adhesion, Escherichia coli attachment and blood staining.

  6. Multiplex detection of agricultural pathogens

    SciTech Connect (OSTI)

    Siezak, Thomas R.; Gardner, Shea; Torres, Clinton; Vitalis, Elizabeth; Lenhoff, Raymond J.

    2013-01-15

    Described are kits and methods useful for detection of agricultural pathogens in a sample. Genomic sequence information from agricultural pathogens was analyzed to identify signature sequences, e.g., polynucleotide sequences useful for confirming the presence or absence of a pathogen in a sample. Primer and probe sets were designed and optimized for use in a PCR based, multiplexed Luminex assay and/or an array assay to successfully identify the presence or absence of pathogens in a sample.

  7. Multiplex detection of agricultural pathogens

    DOE Patents [OSTI]

    McBride, Mary Teresa; Slezak, Thomas Richard; Messenger, Sharon Lee

    2010-09-14

    Described are kits and methods useful for detection of seven agricultural pathogens (BPSV; BHV; BVD; FMDV; BTV; SVD; and VESV) in a sample. Genomic sequence information from 7 agricultural pathogens was analyzed to identify signature sequences, e.g., polynucleotide sequences useful for confirming the presence or absence of a pathogen in a sample. Primer and probe sets were designed and optimized for use in a PCR based, multiplexed Luminex assay to successfully identify the presence or absence of pathogens in a sample.

  8. LEDSGP/sector/Agriculture | Open Energy Information

    Open Energy Info (EERE)

    LEDSGPsectorAgriculture < LEDSGP(Redirected from Agriculture Work Space) Redirect page Jump to: navigation, search REDIRECT LEDSGPsectorAFOLU Retrieved from "http:...

  9. Oregon Department of Agriculture | Open Energy Information

    Open Energy Info (EERE)

    Agriculture Jump to: navigation, search Name: Oregon Department of Agriculture Address: 635 Capitol St NE Place: Salem, Oregon Zip: 97301 Phone Number: 503-986-4550 Website:...

  10. Wyoming Department of Agriculture | Open Energy Information

    Open Energy Info (EERE)

    Agriculture Jump to: navigation, search Name: Wyoming Department of Agriculture Address: 2219 Carey Avenue Place: Cheyenne, Wyoming Zip: 82002 Phone Number: 307-777-7321 Website:...

  11. Energy Secretary Chu, Agriculture Secretary Vilsack Announce...

    Energy Savers [EERE]

    Chu, Agriculture Secretary Vilsack Announce 6.3 million for Biofuels Research Energy Secretary Chu, Agriculture Secretary Vilsack Announce 6.3 million for Biofuels Research July ...

  12. Durable regenerable sorbent pellets for removal of hydrogen sulfide coal gas

    DOE Patents [OSTI]

    Siriwardane, Ranjani V.

    1999-01-01

    Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form, usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

  13. Durable regenerable sorbent pellets for removal of hydrogen sulfide from coal gas

    DOE Patents [OSTI]

    Siriwardane, Ranjani V.

    1997-01-01

    Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

  14. Durable regenerable sorbent pellets for removal of hydrogen sulfide from coal gas

    DOE Patents [OSTI]

    Siriwardane, R.V.

    1999-02-02

    Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form, usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

  15. Durable regenerable sorbent pellets for removal of hydrogen sulfide from coal gas

    DOE Patents [OSTI]

    Siriwardane, R.V.

    1997-12-30

    Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

  16. The Corrosion of PEM Fuel Cell Catalyst Supports and Its Implications for Developing Durable Catalysts

    SciTech Connect (OSTI)

    Shao, Yuyan; Wang, Jun; Kou, Rong; Engelhard, Mark H.; Liu, Jun; Wang, Yong; Lin, Yuehe

    2009-01-03

    Studying the corrosion behavior of catalyst support materials is of great significance for understanding the degradation of PEM fuel cell performance and developing durable catalysts. The oxidation of Vulcan carbon black (the most widely-used catalyst support for PEM fuel cells) was investigated using various electrochemical stressing methods (fixed-potential holding vs. potential step cycling), among which the potential step cycling was considered to mimic more closely the real drive cycle operation of vehicle PEM fuel cells. The oxidation of carbon was accelerated under potential step conditions as compared with the fixed-potential holding condition. Increasing potential step frequency or decreasing the lower potential limit in the potential step can further accelerate the corrosion of carbon. The accelerated corrosion of carbon black was attributed to the cycle of consumption/regeneration of some easily oxidized species. These findings are being employed to develop a test protocol for fast screening durable catalyst support.

  17. New tests for characterizing the durability of a ceramic catalytic converter package

    SciTech Connect (OSTI)

    Reddy, K.P.; Helfinstine, J.D.; Gulati, S.T.

    1996-09-01

    New test methods were developed to characterize the high temperature durability of intumescent mats that are used to mount ceramic catalyst supports in stainless steel cans. The key attribute of these tests is the use of an electric resistance heating method to maintain a temperature gradient through the thickness of the mat when a cyclic or constant shear stress is applied to the mat interface. These tests are simple to perform and do not require expensive equipment or highly skilled operators. Using these new test methods, the durability of ceramic preconverters mounted with 4,070 gm/m{sup 2} intumescent mat was studied. The results of these tests indicate that a preconverter package with 4070 gm/m{sup 2} intumescent mat can perform satisfactorily in the close-coupled application where temperatures exceed 900 C. The mat performance can be quantified in terms of applied stress and test temperature by utilizing the experimental methods described in the present study.

  18. Durability and reliability of solar domestic hot water heaters: Survey results. Final report, Part 1

    SciTech Connect (OSTI)

    Ramirez-Vargas, R.; Whitfield, K.; Hicks, B.; Wood, B.D.

    1998-03-01

    An unresolved barrier for consumer acceptance of SDWH systems is the perception that they are unreliable and that their service life is significantly less than that claimed by the manufacturers/dealers. A comprehensive survey was developed to identify and define the relevant durability and reliability issues that affect the long term performance of SDWH systems. The survey was directed towards installers and service contractors with significant field experience.

  19. Durability-Based Design Criteria for a Chopped-Glass-Fiber Automotive Structural Composite

    SciTech Connect (OSTI)

    Battiste, R.L.; Corum, J.M.; Ren, W.; Ruggles, M.B.

    1999-11-01

    This report provides recommended durability-based design criteria for a chopped-glass-fiber reinforced polymeric composite for automotive structural applications. The criteria closely follow the framework of an earlier criteria document for a continuous-strand-mat (CSM) glass-fiber reference composite. Together these design criteria demonstrate a framework that can be adapted for future random-glass-fiber composites for automotive structural applications.

  20. Durability-Based Design Properties of Reference Crossply Carbon-Fiber Composite

    SciTech Connect (OSTI)

    Corum, J.M.

    2001-04-16

    This report provides recommended durability-based design properties and criteria for a crossply carbon-fiber composite for possible automotive structural applications. Although the composite utilized aerospace-grade carbon-fiber reinforcement, it was made by a rapid-molding process suitable for high-volume automotive use. The material is the first in a planned progression of candidate composites to be characterized as part of an Oak Ridge National Laboratory project entitled Durability of Carbon-Fiber Composites. The overall goal of the project, which is sponsored by the U.S. Department of Energy's Office of Advanced Automotive Technologies and is closely coordinated with the Advanced Composites Consortium, is to develop durability-driven design data and criteria to assure the long-term integrity of carbon-fiber-based composite systems for automotive structural applications. The composite addressed in this report is a ({+-}45{degree})3S crossply consisting of continuous Thornel T300 fibers in a Baydur 420 IMR urethane matrix. This composite is highly anisotropic with two dominant fiber orientations--0/90{degree} and {+-}45{degree}. Properties and models were developed for both orientations. This document is in two parts. Part 1 provides design data and correlations, while Part 2 provides the underlying experimental data and models. The durability issues addressed include the effects of short-time, cyclic, and sustained loadings; temperature; fluid environments; and low-energy impacts (e.g., tool drops and kickups of roadway debris) on deformation, strength, and stiffness. Guidance for design analysis, time-independent and time-dependent allowable stresses, rules for cyclic loadings, and damage-tolerance design guidance are provided.

  1. Method and apparatus for increasing the durability and yield of thin film photovoltaic devices

    DOE Patents [OSTI]

    Phillips, J.E.; Lasswell, P.G.

    1987-02-03

    Thin film photovoltaic cells having a pair of semiconductor layers between an opaque and a transparent electrical contact are manufactured in a method which includes the step of scanning one of the semiconductor layers to determine the location of any possible shorting defect. Upon the detection of such defect, the defect is eliminated to increase the durability and yield of the photovoltaic device. 10 figs.

  2. Durability-Based Design Criteria for a Quasi-Isotropic Carbon-Fiber Automotive Composite

    SciTech Connect (OSTI)

    Corum, J.M.

    2002-04-17

    This report provides recommended durability-based design properties and criteria for a quasi-isotropic carbon-fiber composite for possible automotive structural applications. The composite, which was made by a rapid molding process suitable for high-volume automotive applications, consisted of continuous Thornel T300 fibers (6K tow) in a Baydur 420 IMR urethane matrix. The reinforcement was in the form of four {+-}45{sup o} stitch-bonded mats in the following layup: [0/90{sup o}/{+-}45{sup o}]{sub S}. This material is the second in a progression of three candidate thermoset composites to be characterized and modeled as part of an Oak Ridge National Laboratory project entitled Durability of Carbon-Fiber Composites. The overall goal of the project, which is sponsored by the U.S. Department of Energy's Office of Advanced Automotive Technologies and is closely coordinated with the industry Automotive Composites Consortium, is to develop durability-driven design data and criteria to assure the long-term integrity of carbon-fiber-based composite systems for large automotive structural components. This document is in two parts. Part I provides the design criteria, and Part 2 provides the underlying experimental data and models. The durability issues addressed include the effects on deformation, strength, and stiffness of cyclic and sustained loads, operating temperature, automotive fluid environments, and low-energy impacts (e.g., tool drops and kickups of roadway debris). Guidance is provided for design analysis, time-dependent allowable stresses, rules for cyclic loadings, and damage tolerance design guidance, including the effects of holes. Chapter 6 provides a brief summary of the design criteria.

  3. Analysis of the Durability of PEM FC Membrane Electrode Assemblies in Automotive Applications

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    g y Analysis of the Durability of PEM FC Membrane Electrode Assemblies in Automotive Applications Through the Fundamental Understanding of Membrane and MEA Degradation Pathways DE-EE0003772 2010 DOE Hydrogen Program Fuel Cell Project Kick-Off Randal L. Perry E.I. duPont de Nemours September 28 2010 September 28, 2010 This presentation does not contain any proprietary, confidential, or otherwise restricted information" 2 Overview Timeline (tentative) Start date: Oct 1 2010 Start date: Oct 1,

  4. Durability of Poly(Methyl Methacrylate) Lenses Used in Concentrating Photovoltaic Technology (Revised) (Presentation)

    SciTech Connect (OSTI)

    Miller, D. C.; Carloni, J. D.; Pankow, J. W.; Gjersing, E. L.; To, B.; Packard, C. E.; Kennedy, C. E.; Kurtz, S. R.

    2012-01-01

    Concentrating photovoltaic (CPV) technology recently gained interest based on its expected low levelized cost of electricity, high efficiency, and scalability. Many CPV systems employ Fresnel lenses composed of poly(methyl methacrylate) (PMMA) to obtain a high optical flux density on the cell. The optical and mechanical durability of these lenses, however, is not well established relative to the desired surface life of 30 years. Our research aims to quantify the expected lifetime of PMMA in key market locations (FL, AZ, and CO).

  5. Method of immobilizing weapons plutonium to provide a durable, disposable waste product

    DOE Patents [OSTI]

    Ewing, Rodney C.; Lutze, Werner; Weber, William J.

    1996-01-01

    A method of atomic scale fixation and immobilization of plutonium to provide a durable waste product. Plutonium is provided in the form of either PuO.sub.2 or Pu(NO.sub.3).sub.4 and is mixed with and SiO.sub.2. The resulting mixture is cold pressed and then heated under pressure to form (Zr,Pu)SiO.sub.4 as the waste product.

  6. Primer on Durability of Nuclear Power Plant Reinforced Concrete Structures - A Review of Pertinent Factors

    SciTech Connect (OSTI)

    Naus, Dan J

    2007-02-01

    The objective of this study was to provide a primer on the environmental effects that can affect the durability of nuclear power plant concrete structures. As concrete ages, changes in its properties will occur as a result of continuing microstructural changes (i.e., slow hydration, crystallization of amorphous constituents, and reactions between cement paste and aggregates), as well as environmental influences. These changes do not have to be detrimental to the point that concrete will not be able to meet its performance requirements. Concrete, however, can suffer undesirable changes with time because of improper specifications, a violation of specifications, or adverse performance of its cement paste matrix or aggregate constituents under either physical or chemical attack. Contained in this report is a discussion on concrete durability and the relationship between durability and performance, a review of the historical perspective related to concrete and longevity, a description of the basic materials that comprise reinforced concrete, and information on the environmental factors that can affect the performance of nuclear power plant concrete structures. Commentary is provided on the importance of an aging management program.

  7. Volvo Penta 4.3 GL E15 Emissions and Durability Test

    SciTech Connect (OSTI)

    Zoubul, G.; Cahoon, M.; Kolb, R.

    2011-10-01

    A new Volvo Penta carbureted 4.3 GL engine underwent emissions and dynamometer durability testing from break-in to expected end of life using an accelerated ICOMIA marine emissions cycle and E15 fuel. Only ethanol content was controlled. All aging used splash-blended E15 fuel. Exhaust emissions, exhaust gas temperature, torque, power, barometric pressure, air temperature, and fuel flow were measured at five intervals using site-blended E15 aging fuel and certification fuel (E0). The durability test cycle showed no noticeable impact on mechanical durability or engine power. Emissions performance degraded beyond the certification limit for this engine family, mostly occurring by 28% of expected life. Such degradation is inconsistent with prior experience. Comparisons showed that E15 resulted in lower CO and HC, but increased NOX, as expected for non-feedback-controlled carbureted engines with increased oxygen in the fuel. Fuel consumption also increased with E15 compared with E0. Throughout testing, poor starting characteristics were exhibited on E15 fuel for hot re-start and cold-start. Cranking time to start and smooth idle was roughly doubled compared with typical E0 operation. The carburetor was factory-set for lean operation to ensure emissions compliance. Test protocols did not include carburetor adjustment to account for increased oxygen in the E15 fuel.

  8. Vehicle Technologies Office Merit Review 2014: Durability of Diesel Particulate Filters (Agreement ID:10461) Project ID:18519

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation given by Oak Ridge National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about durability of...

  9. Agricultural

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Appendix E.) J. Jennings. ERC Environmental and Energy Services, Co. ERCEPO-49. (190) Empirical Impact Evaluation of the Energy Savings Resulting From BPA's Stage II Irrigation...

  10. Shotcrete durability

    SciTech Connect (OSTI)

    Palermo, G.; Sardinha, V.L.A.; Coutinho, P.T.

    1995-12-31

    This paper defends the use of shotcrete as a permanent structure based on scientific, technological and practical reasons. Special attention is given to the topic of lining design in tunnels and stations excavated in soil by the NATM method.

  11. Mathias Agricultural Energy Efficiency Grant program

    Broader source: Energy.gov [DOE]

    Mathias Agriculture Energy Efficiency program offered by the Maryland Energy Administration (MEA) provides grants to farms and businesses in agricultural sector to offset 50% of the cost of energ...

  12. Randolph EMC- Agricultural Efficient Lighting Rebate Program

    Broader source: Energy.gov [DOE]

    Agricultural members of Randolph EMC (REMC) who upgrade to energy-efficientCFL bulbs in agricultural facilities are eligible for an incentive to help cover the initial cost of installation. The...

  13. Building, Testing, and Post Test Analysis of Durability Heat Pipe No.6

    SciTech Connect (OSTI)

    MOSS, TIMOTHY A.

    2002-03-01

    The Solar Thermal Program at Sandia supports work developing dish/Stirling systems to convert solar energy into electricity. Heat pipe technology is ideal for transferring the energy of concentrated sunlight from the parabolic dish concentrators to the Stirling engine heat tubes. Heat pipes can absorb the solar energy at non-uniform flux distributions and release this energy to the Stirling engine heater tubes at a very uniform flux distribution thus decoupling the design of the engine heater head from the solar absorber. The most important part of a heat pipe is the wick, which transports the sodium over the heated surface area. Bench scale heat pipes were designed and built to more economically, both in time and money, test different wicks and cleaning procedures. This report covers the building, testing, and post-test analysis of the sixth in a series of bench scale heat pipes. Durability heat pipe No.6 was built and tested to determine the effects of a high temperature bakeout, 950 C, on wick corrosion during long-term operation. Previous tests showed high levels of corrosion with low temperature bakeouts (650-700 C). Durability heat pipe No.5 had a high temperature bakeout and reflux cleaning and showed low levels of wick corrosion after long-term operation. After testing durability heat pipe No.6 for 5,003 hours at an operating temperature of 750 C, it showed low levels of wick corrosion. This test shows a high temperature bakeout alone will significantly reduce wick corrosion without the need for costly and time consuming reflux cleaning.

  14. Industrial and Agricultural Production Efficiency Program | Department...

    Broader source: Energy.gov (indexed) [DOE]

    food processing, cold storage, agricultural, greenhouses, irrigation districts, and waterwastewater treatment. Standard prescriptive incentives include lighting, green motor...

  15. Agricultural Research Service (ARS) Research Participation Program -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Managed by ORAU Agricultural Research Service (ARS) Research Participation Program Home About USDA ARS About ORISE Current Research Opportunities Site Map Contact ORISE Facebook Twitter Applicants Welcome to the Agricultural Research Service (ARS) Research Participation Program The Agricultural Research Service (ARS) Research Participation Program will serve as the next step in the educational and professional development of scientists and engineers interested in agricultural related

  16. Chemically durable nitrogen containing phosphate glasses useful for sealing to metals

    DOE Patents [OSTI]

    Day, Delbert E.; Wilder, Jr., James A.

    1984-01-01

    The chemical durability of alkali phosphate glasses is improved by incorporation of up to 23 weight percent of nitrogen. A typical phosphate glass contains: 10 to 60 mole % of Li.sub.2 O, Na.sub.2 O or K.sub.2 O; 5-40 mole % of BaO or CAO; 0-1 to 10 mole % of Al.sub.2 O.sub.3 ; and 40-70 mole % of P.sub.2 O.sub.5. Nitrides, such as AlN, are the favored additives.

  17. Electronic Durability of Flexible Transparent Films from Type-Specific Single-Wall Carbon Nanotubes

    SciTech Connect (OSTI)

    Harris, J; Iyer, S; Bernhardt, A; Huh, JY; Hudson, S; Fagan, J; Hobbie, E.

    2011-12-11

    The coupling between mechanical flexibility and electronic performance is evaluated for thin films of metallic and semiconducting single-wall carbon nanotubes (SWCNTs) deposited on compliant supports. Percolated networks of type-purified SWCNTs are assembled as thin conducting coatings on elastic polymer substrates, and the sheet resistance is measured as a function of compression and cyclic strain through impedance spectroscopy. The wrinkling topography, microstructure and transparency of the films are independently characterized using optical microscopy, electron microscopy, and optical absorption spectroscopy. Thin films made from metallic SWCNTs show better durability as flexible transparent conductive coatings, which we attribute to a combination of superior mechanical performance and higher interfacial conductivity.

  18. DOE Zero Energy Ready Home Case Study 2014: Durable Energy Builders, Houston, TX

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Durable Energy Builders Houston, TX DOE ZERO ENERGY READY HOME(tm) CASE STUDY The U.S. Department of Energy invites home builders across the country to meet the extraordinary levels of excellence and quality specified in DOE's Zero Energy Ready Home program (formerly known as Challenge Home). Every DOE Zero Energy Ready Home starts with ENERGY STAR Certified Homes Version 3.0 for an energy-efficient home built on a solid foundation of building science research. Advanced technologies are designed

  19. California Department of Food and Agriculture | Open Energy Informatio...

    Open Energy Info (EERE)

    Agriculture Jump to: navigation, search Logo: California Department of Food and Agriculture Name: California Department of Food and Agriculture Abbreviation: CDFA Address: 1220 N...

  20. Extended Durability Testing of an External Fuel Processor for a Solid Oxide Fuel Cell (SOFC)

    SciTech Connect (OSTI)

    Mark Perna; Anant Upadhyayula; Mark Scotto

    2012-11-05

    Durability testing was performed on an external fuel processor (EFP) for a solid oxide fuel cell (SOFC) power plant. The EFP enables the SOFC to reach high system efficiency (electrical efficiency up to 60%) using pipeline natural gas and eliminates the need for large quantities of bottled gases. LG Fuel Cell Systems Inc. (formerly known as Rolls-Royce Fuel Cell Systems (US) Inc.) (LGFCS) is developing natural gas-fired SOFC power plants for stationary power applications. These power plants will greatly benefit the public by reducing the cost of electricity while reducing the amount of gaseous emissions of carbon dioxide, sulfur oxides, and nitrogen oxides compared to conventional power plants. The EFP uses pipeline natural gas and air to provide all the gas streams required by the SOFC power plant; specifically those needed for start-up, normal operation, and shutdown. It includes a natural gas desulfurizer, a synthesis-gas generator and a start-gas generator. The research in this project demonstrated that the EFP could meet its performance and durability targets. The data generated helped assess the impact of long-term operation on system performance and system hardware. The research also showed the negative impact of ambient weather (both hot and cold conditions) on system operation and performance.

  1. The Network of Excellence 'Knowledge-based Multicomponent Materials for Durable and Safe Performance'

    SciTech Connect (OSTI)

    Moreno, Arnaldo

    2008-02-15

    The Network of Excellence 'Knowledge-based Multicomponent Materials for Durable and Safe Performance' (KMM-NoE) consists of 36 institutional partners from 10 countries representing leading European research institutes and university departments (25), small and medium enterprises, SMEs (5) and large industry (7) in the field of knowledge-based multicomponent materials (KMM), more specifically in intermetallics, metal-ceramic composites, functionally graded materials and thin layers. The main goal of the KMM-NoE (currently funded by the European Commission) is to mobilise and concentrate the fragmented scientific potential in the KMM field to create a durable and efficient organism capable of developing leading-edge research while spreading the accumulated knowledge outside the Network and enhancing the technological skills of the related industries. The long-term strategic goal of the KMM-NoE is to establish a self-supporting pan-European institution in the field of knowledge-based multicomponent materials--KMM Virtual Institute (KMM-VIN). It will combine industry oriented research with educational and training activities. The KMM Virtual Institute will be founded on three main pillars: KMM European Competence Centre, KMM Integrated Post-Graduate School, KMM Mobility Programme. The KMM-NoE is coordinated by the Institute of Fundamental Technological Research (IPPT) of the Polish Academy of Sciences, Warsaw, Poland.

  2. ADVANCED COMPOSITE WIND TURBINE BLADE DESIGN BASED ON DURABILITY AND DAMAGE TOLERANCE

    SciTech Connect (OSTI)

    Galib Abumeri; Frank Abdi

    2012-02-16

    The objective of the program was to demonstrate and verify Certification-by-Analysis (CBA) capability for wind turbine blades made from advanced lightweight composite materials. The approach integrated durability and damage tolerance analysis with robust design and virtual testing capabilities to deliver superior, durable, low weight, low cost, long life, and reliable wind blade design. The GENOA durability and life prediction software suite was be used as the primary simulation tool. First, a micromechanics-based computational approach was used to assess the durability of composite laminates with ply drop features commonly used in wind turbine applications. Ply drops occur in composite joints and closures of wind turbine blades to reduce skin thicknesses along the blade span. They increase localized stress concentration, which may cause premature delamination failure in composite and reduced fatigue service life. Durability and damage tolerance (D&DT) were evaluated utilizing a multi-scale micro-macro progressive failure analysis (PFA) technique. PFA is finite element based and is capable of detecting all stages of material damage including initiation and propagation of delamination. It assesses multiple failure criteria and includes the effects of manufacturing anomalies (i.e., void, fiber waviness). Two different approaches have been used within PFA. The first approach is Virtual Crack Closure Technique (VCCT) PFA while the second one is strength-based. Constituent stiffness and strength properties for glass and carbon based material systems were reverse engineered for use in D&DT evaluation of coupons with ply drops under static loading. Lamina and laminate properties calculated using manufacturing and composite architecture details matched closely published test data. Similarly, resin properties were determined for fatigue life calculation. The simulation not only reproduced static strength and fatigue life as observed in the test, it also showed composite

  3. Liquidus temperature and chemical durability of selected glasses to immobilize rare earth oxides waste

    SciTech Connect (OSTI)

    Mohd Fadzil, Syazwani Binti; Hrma, Pavel R.; Schweiger, Michael J.; Riley, Brian J.

    2015-06-30

    Pyroprocessing is a reprocessing method for managing and reusing used nuclear fuel (UNF) by dissolving it in an electrorefiner with a molten alkali or alkaline earth chloride salt mixture while avoiding wet reprocessing. Pyroprocessing UNF with a LiCl-KCl eutectic salt releases the fission products from the fuel and generates a variety of metallic and salt-based species, including rare earth (RE) chlorides. If the RE-chlorides are converted to oxides, borosilicate glass is a prime candidate for their immobilization because of its durability and ability to dissolve almost any RE waste component into the matrix at high loadings. Crystallization that occurs in waste glasses as the waste loading increases may complicate glass processing and affect the product quality. This work compares three types of borosilicate glasses in terms of liquidus temperature (TL): the International Simple Glass designed by the International Working Group, sodium borosilicate glass developed by Korea Hydro and Nuclear Power, and the lanthanide aluminoborosilicate (LABS) glass established in the United States. The LABS glass allows the highest waste loadings (over 50 mass% RE2O3) while possessing an acceptable chemical durability.

  4. Effect of Stainless Steel Can/Glass-Ceramic Interaction Layer on Aqueous Durability

    SciTech Connect (OSTI)

    McGlinn, Peter J.; Zhang, Yingjie; Li, Huijun; Payne, Timothy E.

    2007-07-01

    Calcined high-level radioactive waste (HLW) stored at the Idaho National Laboratory (INL) will eventually be immobilised in a suitable wasteform before disposal. A tailored glass-ceramic wasteform, produced by hot isostatic pressing (HIPing) in stainless steel (SS) cans, has been developed at the Australian Nuclear Science and Technology Organisation (ANSTO) as a cost-saving alternative to glass which would improve waste loading and density, and reduce waste volume. We have studied the SS/wasteform interactions under HIPing conditions to understand whether such interactions would have any detrimental effect on long-term wasteform stability. This has been demonstrated by carrying out aqueous durability tests, under near-neutral and alkaline conditions, on the wasteform at the interaction layer, and on the wasteform distal to this reaction edge. Reaction during HIPing resulted in verifiable Cr diffusion from the can wall into the wasteform, yet without any detectable detrimental impact on the HIP can or the aqueous durability of the wasteform. (authors)

  5. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Quarterly technical progress report 8, July--September 1988

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1988-11-14

    AMAX Research & Development Center (AMAX R&D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  6. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Quarterly technical progress report 9, October--December 1988

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1989-03-06

    AMAX Research & Development Center (AMAX R&D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  7. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Quarterly technical progress report No. 3, April--June 1987

    SciTech Connect (OSTI)

    Jha, M.C.; Baltich, L.K.; Berggren, M.H.

    1987-08-28

    AMAX Research & Development Center (AMAX R&D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  8. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Quarterly technical progress report 2, January--March 1987

    SciTech Connect (OSTI)

    Jha, M.C.; Baltich, L.K.; Berggren, M.H.

    1987-05-18

    AMAX Research & Development Center (AMAX R&D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  9. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Volume 1, Bench-scale testing and analysis

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1989-05-02

    AMAX Research & Development Center (AMAX R&D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  10. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Quarterly technical progress report 7, April--June 1988

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1988-08-19

    AMAX Research & Development Center (AMAX R&D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  11. Durability of Low Platinum Fuel Cells Operating at High Power Density

    SciTech Connect (OSTI)

    Polevaya, Olga; Blanchet, Scott; Ahluwalia, Rajesh; Borup, Rod; Mukundan, Rangachary

    2014-03-19

    Understanding and improving the durability of cost-competitive fuel cell stacks is imperative to successful deployment of the technology. Stacks will need to operate well beyond today’s state-of-the-art rated power density with very low platinum loading in order to achieve the cost targets set forth by DOE ($15/kW) and ultimately be competitive with incumbent technologies. An accelerated cost-reduction path presented by Nuvera focused on substantially increasing power density to address non-PGM material costs as well as platinum. The study developed a practical understanding of the degradation mechanisms impacting durability of fuel cells with low platinum loading (≤0.2mg/cm2) operating at high power density (≥1.0W/cm2) and worked out approaches for improving the durability of low-loaded, high-power stack designs. Of specific interest is the impact of combining low platinum loading with high power density operation, as this offers the best chance of achieving long-term cost targets. A design-of-experiments approach was utilized to reveal and quantify the sensitivity of durability-critical material properties to high current density at two levels of platinum loading (the more conventional 0.45 mgPt.cm–1 and the much lower 0.2 mgPt.cm–2) across several cell architectures. We studied the relevance of selected component accelerated stress tests (AST) to fuel cell operation in power producing mode. New stress tests (NST) were designed to investigate the sensitivity to the addition of electrical current on the ASTs, along with combined humidity and load cycles and, eventually, relate to the combined city/highway drive cycle. Changes in the cathode electrochemical surface area (ECSA) and average oxygen partial pressure on the catalyst layer with aging under AST and NST protocols were compared based on the number of completed cycles. Studies showed elevated sensitivity of Pt growth to the potential limits and the initial particle size distribution. The ECSA loss

  12. E-Area Vault Concrete Material Property And Vault Durability/Degradation Projection Recommendations

    SciTech Connect (OSTI)

    Phifer, M. A.

    2014-03-11

    Subsequent to the 2008 E-Area Low-Level Waste Facility (ELLWF) Performance Assessment (PA) (WSRC 2008), two additional E-Area vault concrete property testing programs have been conducted (Dixon and Phifer 2010 and SIMCO 2011a) and two additional E-Area vault concrete durability modeling projections have been made (Langton 2009 and SIMCO 2012). All the information/data from these reports has been evaluated and consolidated herein by the Savannah River National Laboratory (SRNL) at the request of Solid Waste Management (SWM) to produce E-Area vault concrete hydraulic and physical property data and vault durability/degradation projection recommendations that are adequately justified for use within associated Special Analyses (SAs) and future PA updates. The Low Activity Waste (LAW) and Intermediate Level (IL) Vaults structural degradation predictions produced by Carey 2006 and Peregoy 2006, respectively, which were used as the basis for the 2008 ELLWF PA, remain valid based upon the results of the E-Area vault concrete durability simulations reported by Langton 2009 and those reported by SIMCO 2012. Therefore revised structural degradation predictions are not required so long as the mean thickness of the closure cap overlying the vaults is no greater than that assumed within Carey 2006 and Peregoy 2006. For the LAW Vault structural degradation prediction (Carey 2006), the mean thickness of the overlying closure cap was taken as nine feet. For the IL Vault structural degradation prediction (Peregoy 2006), the mean thickness of the overlying closure cap was taken as eight feet. The mean closure cap thicknesses as described here for both E-Area Vaults will be included as a key input and assumption (I&A) in the next revision to the closure plan for the ELLWF (Phifer et al. 2009). In addition, it has been identified as new input to the PA model to be assessed in the ongoing update to the new PA Information UDQE (Flach 2013). Once the UDQE is approved, the SWM Key I

  13. Global Climate Change and Agriculture

    SciTech Connect (OSTI)

    Izaurralde, Roberto C.

    2009-01-01

    The Fourth Assessment Report of the Intergovernmental Panel on Climate Change released in 2007 significantly increased our confidence about the role that humans play in forcing climate change. There is now a high degree of confidence that the (a) current atmospheric concentrations of carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O) far exceed those of the pre-industrial era, (b) global increases in CO2 arise mainly from fossil fuel use and land use change while those of CH4 and N2O originate primarily from agricultural activities, and (c) the net effect of human activities since 1750 has led to a warming of the lower layers of the atmosphere, with an increased radiative forcing of 1.6 W m-2. Depending on the scenario of human population growth and global development, mean global temperatures could rise between 1.8 and 4.0 C by the end of the 21st century.

  14. ORISE: Multiple research appointments available through Agricultural

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Service Postdoctoral Research Program Multiple research appointments available through Agricultural Research Service Postdoctoral Research Program Selected candidates participate in USDA research for one to four years FOR IMMEDIATE RELEASE March 26, 2014 FY14-23 OAK RIDGE, Tenn.-ORAU and the U.S. Department of Agriculture are currently seeking recent doctoral degree recipients for various appointments in the Agricultural Research Service Postdoctoral Research Program. The ARS is the

  15. The Future of Biofuels an Agricultural Perspective

    U.S. Energy Information Administration (EIA) Indexed Site

    Biofuels An Agricultural Perspective Beth J. Calabotta Monsanto Company POPULATION GROWING AT 1.1% EACH YEAR Source: UN Population Division, Monsanto analysis INCOMES GROWING AT 3.5% PER YEAR... $5 BILLION PER DAY Source: IHS Global Insight, Agriculture Division, Monsanto analysis FOOD DEMAND GROWING AT ~1.75% EACH YEAR Source: IHS Global Insights, Agriculture Division, Monsanto analysis WATER DEMAND IS GROWING AT ~2% PER YEAR Source: McKinsey Resource Revolution 2011, Monsanto Analysis ENERGY

  16. Durable Media for Long-Term Preservation of Geological Repository Records

    SciTech Connect (OSTI)

    Aoki, K.; Fujii, N.; Kageyama, H.; Yoshimura, K.; Ohuchi, J.; Tsuboya, T.

    2008-07-01

    Durability of selected hard materials as information preserving media has been studied, leading to some promising results. Several engraving experiments on the selected materials confirmed that characters and patterns can be expressed along with shading and gradation. Engraving experiments on durable artificial materials were carried out by applying laser technologies. By selecting appropriate materials and engraving methods, characters and patterns can be expressed along with shading and gradation. These technologies can be applied to not only documentary records but also to markers and monuments. Among the materials, silicon carbide, which has strong resistance against heat wear and chemical impacts, corrosion resistance and wear resistance, showed satisfactory results in terms of accuracy. Thus, it is expected to be a promising material for the long-term record preservation. With respect to the density of characters in written records in the case of dot printing, it was estimated that, with 2-point characters, information totaling 6 to 8 pages of A-4 size can be engraved on a 10 cm x 10 cm plate. When a document that has 500 pages of A4 size paper is engraved on sintered silicon carbide plates, the total volume of recording media is evaluated as follows: - Size of plate: 10 cm x 10 cm; - Size of character to be engraved: 2-points ({approx} 0.7 mm; of readable size by naked eye or using a magnifying glass); - Number of pages of original document to be engraved on a plate: 8; - Number of pages of original document to be engraved on both sides of a plate: 16; - Number of plates needed for a series of document package: 500 / 16 = 32; - The thickness of a plate: 1 mm; - The total thickness of recording media: 32 mm; - Bulk of recording media preserving 500 pages of document: 10 cm x 10 cm x 32 cm. The examination has shown the possibility of long-term preservation of documentation records as a permanent system. A further examination is suggested concerning the

  17. Factors affecting the microstructural stability and durability of thermal barrier coatings fabricated by air plasma spraying

    SciTech Connect (OSTI)

    Helminiak, M. A.; Yanar, N. M.; Pettit, F. S.; Taylor, T. A.; Meier, G. H.

    2012-10-01

    The high-temperature behavior of high-purity, low-density (HP-LD) air plasma sprayed (APS) thermal barrier coatings (TBCs) with NiCoCrAlY bond coats deposited by argon-shrouded plasma spraying is described. The high purity yttria-stabilized zirconia resulted in top coats which are highly resistant to sintering and transformation from the metastable tetragonal phase to the equilibrium mixture of monoclinic and cubic phases. The thermal conductivity of the as-processed TBC is low but increases during high temperature exposure even before densification occurs. The porous topcoat microstructure also resulted in good spallation resistance during thermal cycling. The actual failure mechanisms of the APS coatings were found to depend on topcoat thickness, topcoat density, and the thermal cycle frequency. The failure mechanisms are described and the durability of the HP-LD coatings is compared with that of state-of-the-art electron beam physical vapor deposition TBCs.

  18. Effects of extreme pressure additive chemistry on rolling element bearing surface durability

    SciTech Connect (OSTI)

    Evans, Ryan D.; Nixon, H. P.; Darragh, Craig V.; Howe, Jane Y; Coffey, Dorothy W

    2007-01-01

    Lubricant additives have been known to affect rolling element bearing surface durability for many years. Tapered roller bearings were used in fatigue testing of lubricants formulated with gear oil type additive systems. These systems have sulfur- and phosphoruscontaining compounds used for gear protection as well as bearing lubrication. Several variations of a commercially available base additive formulation were tested having modified sulfur components. The variations represent a range of ''active'' extreme pressure (EP) chemistries. The bearing fatigue test results were compared with respect to EP formulation and test conditions. Inner ring near-surface material in selected test bearings was evaluated on two scales: the micrometer scale using optical metallography and the nanometer scale using transmission electron microscopy (TEM). Focused-ion beam (FIB) techniques were used for TEM specimen preparation. Imaging and chemical analysis of the bearing samples revealed near-surface material and tribofilm characteristics. These results are discussed with respect to the relative fatigue lives.

  19. Durable Airtightness in Single-Family Dwellings: Field Measurements and Analysis

    SciTech Connect (OSTI)

    Chan, Wanyu; Walker, Iain; Sherman, Max

    2015-06-01

    Durability of the building envelope is important to new homes that are increasingly built with improved levels of airtightness. It is also important to weatherized homes such that energy savings from retrofit measures, such as air sealing, are persistent. This paper presents a comparison of air leakage measurements collected in November 2013 through March 2014, with two sets of prior data collected between 2001-2003 from 17 new homes located near Atlanta, GA, and 17 homes near Boise, ID that were weatherized in 2007-2008. The purpose of the comparison is to determine if there are changes to the airtightness of building envelopes over time. The air leakage increased in all but one of the new homes, with a mean increase of about 25%. A regression analysis was performed to describe the relationship between prior and current measurements in terms of normalized leakage (NL).

  20. Spray-on anti-soiling coatings that exhibit high transparency and mechanical durability

    SciTech Connect (OSTI)

    Schaeffer, Daniel A; Polyzos, Georgios; Smith, Barton; Lee, Dominic F; Rajic, Slobodan; Datskos, Panos G; Hunter, Scott Robert

    2014-01-01

    A superhydrophobic (SH) surface has many characteristics, one of which is its self-cleaning, anti-soiling functionality, that are desirable across various industries. A transparent, self-cleaning surface utilizes the right combination of surface chemistry and roughness that force water droplets to form high water contact angles (CA). This in turn allows droplets to easily roll off and pick up dirt and debris across the surface. In theory this is simple but in practice this can be very difficult as superhydrophobicity and optical transparency are competitive. We have developed a simple, spray-on coating based on functionalized SiO2 nanoparticles that can easily be applied to surfaces whose application requires high transparency including, but not limited to, optical sensors, photovoltaics, sights, and lenses. In addition, these coatings exhibit practical mechanical and environmental durability that allow prolonged use of the coatings in harsh environments.

  1. Consultative Group on International Agricultural Research (CGIAR...

    Open Energy Info (EERE)

    academia, and the private sector. The 15 Research Centers generate and disseminate knowledge, technologies, and policies for agricultural development through the CGIAR...

  2. Agricultural Lighting and Equipment Rebate Program

    Broader source: Energy.gov [DOE]

    In Vermont, agricultural operations are eligible for prescriptive and customized incentives for equipment proven to help make farms more efficient. Prescriptive rebates are available for lighting...

  3. WINDExchange: Agricultural and Rural Resources and Tools

    Wind Powering America (EERE)

    Rural Communities Printable Version Bookmark and Share Wind for Homeowners, Farmers, & Businesses Resources & Tools Agricultural and Rural Resources and Tools This page lists...

  4. Consultative Group on International Agricultural Research | Open...

    Open Energy Info (EERE)

    reduce poverty and hunger, improve human health and nutrition, and enhance ecosystem resilience through high-quality international agricultural research, partnershp and...

  5. OTEC- Agricultural Energy Efficiency Rebate Programs

    Office of Energy Efficiency and Renewable Energy (EERE)

    Oregon Trail Electric Consumers Cooperative (OTEC) offers programs to agricultural customers.  Interested customers should contact a local OTEC office.

  6. Farmers Electric Cooperative - Residential/Agricultural Energy...

    Broader source: Energy.gov (indexed) [DOE]

    Residential Agricultural Savings Category Solar Photovoltaics Wind (All) Geothermal Heat Pumps Water Heaters Lighting Heat Pumps CaulkingWeather-stripping Building Insulation...

  7. Durability of metals from archaeological objects, metal meteorites, and native metals

    SciTech Connect (OSTI)

    Johnson, A.B. Jr.; Francis, B.

    1980-01-01

    Metal durability is an important consideration in the multi-barrier nuclear waste storage concept. This study summarizes the ancient metals, the environments, and factors which appear to have contributed to metal longevity. Archaeological and radiochemical dating suggest that human use of metals began in the period 6000 to 7000 BC. Gold is clearly the most durable, but many objects fashioned from silver, copper, bronze, iron, lead, and tin have survived for several thousand years. Dry environments, such as tombs, appear to be optimum for metal preservation, but some metals have survived in shipwrecks for over a thousand years. The metal meteorites are Fe-base alloys with 5 to 60 wt% Ni and minor amounts of Co, I, and S. Some meteoritic masses with ages estimated to be 5,000 to 20,000 years have weathered very little, while other masses from the same meteorites are in advanced stages of weathering. Native metals are natural metallic ores. Approximately five million tonnes were mined from native copper deposits in Michigan. Copper masses from the Michigan deposits were transported by the Pleistocene glaciers. Areas on the copper surfaces which appear to represent glacial abrasion show minimal corrosion. Dry cooling tower technology has demonstrated that in pollution-free moist environments, metals fare better at temperatures above than below the dewpoint. Thus, in moderate temperature regimes, elevated temperatures may be useful rather than detrimental for exposures of metal to air. In liquid environments, relatively complex radiolysis reactions can occur, particularly where multiple species are present. A dry environment largely obviates radiolysis effects.

  8. Impact of Biodiesel Impurities on the Performance and Durability of DOC, DPF and SCR Technologies

    SciTech Connect (OSTI)

    Williams, A.; McCormick, R.; Luecke, J.; Brezny, R.; Geisselmann, A.; Voss, K.; Hallstrom, K.; Leustek, M.; Parsons, J.; Abi-Akar, H.

    2011-06-01

    It is estimated that operating continuously on a B20 fuel containing the current allowable ASTM specification limits for metal impurities in biodiesel could result in a doubling of ash exposure relative to lube-oil derived ash. The purpose of this study was to determine if a fuel containing metals at the ASTM limits could cause adverse impacts on the performance and durability of diesel emission control systems. An accelerated durability test method was developed to determine the potential impact of these biodiesel impurities. The test program included engine testing with multiple DPF substrate types as well as DOC and SCR catalysts. The results showed no significant degradation in the thermo-mechanical properties of cordierite, aluminum titanate, or silicon carbide DPFs after exposure to 150,000 mile equivalent biodiesel ash and thermal aging. However, exposure of a cordierite DPF to 435,000 mile equivalent aging resulted in a 69% decrease in the thermal shock resistance parameter. It is estimated that the additional ash from 150,000 miles of biodiesel use would also result in a moderate increases in exhaust backpressure for a DPF. A decrease in DOC activity was seen after exposure to 150,000 mile equivalent aging, resulting in higher HC slip and a reduction in NO{sub 2} formation. The metal-zeolite SCR catalyst experienced a slight loss in activity after exposure to 435,000 mile equivalent aging. This catalyst, placed downstream of the DPF, showed a 5% reduction in overall NOx conversion activity over the HDDT test cycle.

  9. Strength and durability properties of core lithologies from coal-bearing Tyonek formation, Cook Inlet region, Alaska

    SciTech Connect (OSTI)

    Odum, J.K.

    1985-04-01

    The Tyonek Formation (late Oligocene to middle Miocene) is a nonmarine unit of sandstone, siltstone, and claystone that contains large quantities of strippable subbituminous coal and lignite. The geotechnical properties, determined by field and laboratory tests on core from the Capps and Chuitna coalfields, dictate the equipment needs for excavation, determination of pit slope angle for mine planning, and durability of excavated spoil to weathering degradation. Point-load strength index tests are rapid and inexpensive field tests approximating the tensile and unconfined compressive strength of rock types. These tests, combined with laboratory uniaxial compression tests, were used to rank the formation lithologies in order of decreasing strength: coal (2670 psi), carbonaceous claystone (835 psi), siltstone (435 psi), claystone (375 psi), and sandstone (145 psi). Except for coal, the lithologies range in hardness from soft soil to soft rock. Laboratory slake durability index tests, which measure the deterioration potential of rock masses as a result of cyclic wetting and drying, were used to rank lithologies in order of decreasing durability: claystone (49%), carbonaceous claystone (46%), siltstone (40%), and sandstone (20%). The cored Tyonek lithologies are noncarbonate, and their strength and durability increase with decreasing grain size and increasing clay-particle content. Compressional wave velocity, combined with point-load data, indicates that most of the rocks could be removed by bull-dozers with ripping blades or by scrapers and shovels. However, coal (with rare exceptions, the strongest lithology tested) would require blasting before removal.

  10. Long-term durability testing of ceramic cross-flow filter. Final report, September 29, 1987--December 31, 1992

    SciTech Connect (OSTI)

    Lippert, T.E.; Smeltzer, E.E.; Alvin, M.A.; Bachovchin, D.M.

    1993-08-01

    Long term durability testing of the cross flow filter is described. Two high temperature, high pressure test facilities were built and operated. The facilities were designed to simulate dirty gas environments typical of Pressurized Fluidized Bed Combustion (PFBC) and coal gasification. Details of the design and operation of the test facilities and filter testing results are described.

  11. The effect of chemical composition on the PCT durability of mixed waste glasses from wastewater treatment sludges

    SciTech Connect (OSTI)

    Resce, J.L.; Ragsdale, R.G.; Overcamp, T.J.; Bickford, D.F.; Cicero, C.A.

    1995-01-25

    An experimental program has been designed to examine the chemical durability of glass compositions derived from the vitrification of simulated wastewater treatment sludges. These sludges represent the majority of low-level mixed wastes currently in need of treatment by the US DOE. The major oxides in these model glasses included SiO{sub 2}, Al{sub 2}O{sub 3}, B{sub 2}O{sub 3}, Na{sub 2}O, CaO and Fe{sub 2}O{sub 3}. In addition, three minor oxides, BaO, NiO, and PbO, were added as hazardous metals. The major oxides were each varied at two levels resulting in 32 experimental glasses. The chemical durability was measured by the 7-Day Product Consistency Test (PCT). The normalized sodium release rates (NRR{sub Na}) of these glasses ranged from 0.01 to 4.99 g/m{sup 2}. The molar ratio of the glass-former to glass-modifier (F/M) was found to have the greatest effect on PCT durability. Glass-formers included SiO{sub 2}, Al{sub 2}O{sub 3}, and B{sub 2}O{sub 3}, while Na{sub 2}O, CaO, BaO, NiO, and PbO were glass-modifiers. As this ratio increased from 0.75 to 2.0, NRR{sub Na} was found to decrease between one and two orders of magnitude. Another important effect on NRR{sub Na} was the Na{sub 2}O/CaO ratio. As this ratio increased from 0.5 to 2.0, NRR{sub Na} increased up to two orders of magnitude for the glasses with the low F/M ratio but almost no effect was observed for the glasses with the high F/M ratio. Increasing the iron oxide content from 2 to 18 mole% was found to decrease NRR{sub Na} one order of magnitude for the glasses with low F/M but iron had little effect on the glasses with the high F/M ratio. The durability also increased when 10 mole percent Al{sub 2}O{sub 3} was included in low iron oxide glasses but no effect was observed with the high iron glasses. The addition of B{sub 2}O{sub 3} had little effect on durability. The effects of other composition parameters on durability are discussed as well.

  12. Durability of Poly(Methyl Methacrylate) Lenses Used in Concentrating Photovoltaic Modules: Preprint

    SciTech Connect (OSTI)

    Miller, D. C.; Gedvilas, L. M.; To, B.; Kennedy, C. E.; Kurtz, S. R.

    2010-08-01

    Concentrating photovoltaic (CPV) technology has recently gained interest based on their expected low levelized cost of electricity, high efficiency, and scalability. Many CPV systems use Fresnel lenses made of poly(methyl methacrylate)(PMMA) to obtain a high optical flux density. The optical and mechanical durability of such components, however, are not well established relative to the desired service life of 30 years. Specific reliability issues may include: reduced optical transmittance, discoloration, hazing, surface erosion, embrittlement, crack growth, physical aging, shape setting (warpage), and soiling. The initial results for contemporary lens- and material-specimens aged cumulatively to 6 months are presented. The study here uses an environmental chamber equipped with a xenon-arc lamp to age specimens at least 8x the nominal field rate. A broad range in the affected characteristics (including optical transmittance, yellowness index, mass loss, and contact angle) has been observed to date, depending on the formulation of PMMA used. The most affected specimens are further examined in terms of their visual appearance, surface roughness (examined via atomic force microscopy), and molecular structure (via Fourier transform infrared spectroscopy).

  13. Durability of double-shell slurry feed grouts: FY-90 results

    SciTech Connect (OSTI)

    Lokken, R.O.; Martin, P.F.C.

    1992-12-01

    Plans for disposal of the low-level fraction of selected double-shell tank wastes at Hanford include grouting. Grout disposal is the process of mixing low-level liquid waste with cementitious powders and pumping the slurry to near-surface, underground concrete vaults; hydration results in the formation of a solid product that binds/encapsulates the radioactive/hazardous constituents. In this durability program, previous studies have indicated a strong impact from curing temperature/time on strength and leach resistance of DSSF grouts. The current studies were expanded to determine whether these impacts could be attributed to other factors, such as dry blend composition and waste concentration. Major conclusions: grouts from dry blends with 40 wt% limestone had lower strengths; compressive strengths and leach resistance decreased with increased curing temperature/time; leach resistance increased for grouts prepared with dilute DSSF; nitrate leach resistance increased with high slag/cement ratios, dilute DSSF, and low curing temperatures; amount of drainable liquids for grouts using diluted DSSF was lowest when slag content was high; the 2 most significant factors affecting grout properties were the slag/cement ratio and waste dilution (slag-waste reactions appear to dominate the properties of DSSF grouts).

  14. Final Report - Durable Catalysts for Fuel Cell Protection during Transient Conditions

    SciTech Connect (OSTI)

    Atanasoski, Radoslav; van der Vliet, Dennis; Cullen, David; Atanasoska, Ljiljana

    2015-01-26

    The objective of this project was to develop catalysts that will enable proton exchange membranes (PEM) fuel cell systems to weather the damaging conditions in the fuel cell at voltages beyond the thermodynamic stability of water during the transient periods of start-up/shut-down and fuel starvation. Such catalysts are required to make it possible for the fuel cell to satisfy the 2015 DOE targets for performance and durability. The project addressed a key issue of importance for successful transition of PEM fuel cell technology from development to pre-commercial phase. This issue is the failure of the catalyst and the other thermodynamically unstable membrane electrode assembly (MEA) components during start-up/shut-down and local fuel starvation at the anode, commonly referred to as transient conditions. During these periods the electrodes can reach potentials higher than the usual 1.23V upper limit during normal operation. The most logical way to minimize the damage from such transient events is to minimize the potential seen by the electrodes. At lower positive potentials, increased stability of the catalysts themselves and reduced degradation of the other MEA components is expected.

  15. Impact of Biodiesel Impurities on the Performance and Durability of DOC, DPF and SCR Technologies: Preprint

    SciTech Connect (OSTI)

    Williams, A.; McCormick, R.; Luecke, J.; Brezny, R.; Geisselmann, A.; Voss, K.; Hallstrom, K.; Leustek, M.; Parsons, J.; Abi-Akar, H.

    2011-04-01

    An accelerated durability test method determined the potential impact of biodiesel ash impurities, including engine testing with multiple diesel particulate filter substrate types, as well as diesel oxidation catalyst and selective catalyst reduction catalysts. The results showed no significant degradation in the thermo-mechanical properties of a DPF after exposure to 150,000-mile equivalent biodiesel ash and thermal aging. However, exposure to 435,000-mile equivalent aging resulted in a 69% decrease in thermal shock resistance. A decrease in DOC activity was seen after exposure to 150,000-mile equivalent aging, resulting in higher hydrocarbon slip and a reduction in NO2 formation. The SCR catalyst experienced a slight loss in activity after exposure to 435,000-mile equivalent aging. The SCR catalyst, placed downstream of the DPF and exposed to B20 exhaust suffered a 5% reduction in overall NOx conversion activity over the HDDT test cycle. It is estimated that the additional ash from 150,000 miles of biodiesel use would also result in a moderate increases in exhaust backpressure for a DPF. The results of this study suggest that long-term operation with B20 at the current specification limits for alkali and alkaline earth metal impurities will adversely impact the performance of DOC, DPF and SCR systems.

  16. Vanadium redox flow battery efficiency and durability studies of sulfonated Diels Alder poly(phenylene)s

    SciTech Connect (OSTI)

    Fujimoto, Cy H.; Kim, Soowhan; Stains, Ronald; Wei, Xiaoliang; Li, Liyu; Yang, Zhenguo

    2012-07-01

    Sulfonated Diels Alder poly(phenylene) (SDAPP) was examined for vanadium redox flow battery (VRFB) use. The ion exchange capacity (IEC) was varied from 1.4, 1.6 and 2.0 meq/g in order to tune the proton conductivity and vanadium permeability. Coulombic efficiencies between 92 to 99% were observed, depending on IEC (lower IEC, higher coulombic efficiencies). In all cases the SDAPP displayed comparable energy efficiencies (88 - 90%) to Nafion 117 (88%) at 50mA/cm2. Membrane durability also was dependent on IEC; SDAPP with the highest IEC lasted slightly over 50 cycles while SDAPP with the lowest IEC lasted over 400 cycles and testing was discontinued only due to time constraints. Accelerated vanadium lifetime studies were initialed with SDAPP, by soaking films in a 0.1 M V5+ and 5.0 M total SO4-2 solution. The rate of degradation was also proportional with IEC; the 2 meq/g sample dissolved within 376 hours, the 1.6 meq/g sample dissolved after 860 hours, while the 1.4 meq/g sample broke apart after 1527 hours.

  17. Optical performance and durability of solar reflectors protected by an alumina coating

    SciTech Connect (OSTI)

    Kennedy, C.E.; Smilgys, R.V.; Kirkpatrick, D.A.; Ross, J.S.

    1996-07-01

    Solar thermal electric power systems use large solar reflectors to concentrate sunlight to generate electricity. The economic viability of these systems depends on developing a durable, low-cost reflector. The goals for such a reflector are specular reflectance above 90% for at least 10 years under outdoor service conditions and a large-volume manufacturing cost of less than $10.8/m{sup 2} ($1.00/ft{sup 2}). Currently, the best candidate materials for solar reflectors are silver-coated, low-iron glass and silvered polymer films. Polymer reflectors are lighter in weight, offer greater system design flexibility, and have the potential for lower cost than glass reflectors. A promising low-cost reflector consists of a silvered polymer protected by an optically transparent alumina coating. The coating is deposited by an ion-beam-assisted physical vapor deposition (IBAD) technique. Samples of this reflector have maintained high optical performance in accelerated testing at the National Renewable Energy Laboratory for more than 3000 hours. Solar reflectors produced using this technique may represent an opportunity to bring solar power generation to reality.

  18. Palladium–platinum core-shell icosahedra with substantially enhanced activity and durability towards oxygen reduction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Xue; Choi, Sang-Il; Roling, Luke T.; Luo, Ming; Ma, Cheng; Zhang, Lei; Chi, Miaofang; Liu, Jingyue; Xie, Zhaoxiong; Herron, Jeffrey A.; et al

    2015-07-02

    Conformal deposition of platinum as ultrathin shells on facet-controlled palladium nanocrystals offers a great opportunity to enhance the catalytic performance while reducing its loading. Here we report such a system based on palladium icosahedra. Owing to lateral confinement imposed by twin boundaries and thus vertical relaxation only, the platinum overlayers evolve into a corrugated structure under compressive strain. For the core-shell nanocrystals with an average of 2.7 platinum overlayers, their specific and platinum mass activities towards oxygen reduction are enhanced by eight- and sevenfold, respectively, relative to a commercial catalyst. Density functional theory calculations indicate that the enhancement can bemore » attributed to the weakened binding of hydroxyl to the compressed platinum surface supported on palladium. After 10,000 testing cycles, the mass activity of the core-shell nanocrystals is still four times higher than the commercial catalyst. Ultimately, these results demonstrate an effective approach to the development of electrocatalysts with greatly enhanced activity and durability.« less

  19. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Quarterly technical progress report 4, July--September 1987

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1987-10-27

    AMAX Research & Development Center (AMAX R&D) has been investigating methods for improving the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hog coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. The reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point in a bench-scale fixed-bed reactor. The durability may be defined as the ability of the sorbent to maintain its reactivity and other important physical characteristics such as size, strength, and specific surface area during 10 cycles of sulfidation and regeneration. Two base case sorbents, spherical pellets and cylindrical extrudes used in related METC sponsored projects, are being used to provide a basis for the comparison of physical characteristics and chemical reactivity.

  20. Impact of process conditions on the density and durability of wheat, oat, canola, and barley straw briquettes

    SciTech Connect (OSTI)

    Tumuluru, J. S.; Tabil, L. G.; Song, Y.; Iroba, K. L.; Meda, V.

    2014-10-01

    The present study is to understand the impact of process conditions on the quality attributes of wheat oat, barley, and canola straw briquettes. Analysis of variance indicated that briquette moisture content and initial density immediately after compaction and final density after 2 weeks of storage are strong functions of feedstock moisture content and compression pressure, whereas durability rating is influenced by die temperature and feedstock moisture content. Briquettes produced at a low feedstock moisture content of 9 % (w.b.) yielded maximum densities >700 kg/m3 for wheat, oat, canola, and barley straws. Lower feedstock moisture content of <10 % (w.b.) and higher die temperatures >110 C and compression pressure >10 MPa minimized the briquette moisture content and maximized densities and durability rating based on surface plots observations. Optimal process conditions indicated that a low feedstock moisture content of about 9 % (w.b.), high die temperature of 120130 C, medium-to-large hammer mill screen sizes of about 24 to 31.75 mm, and low to high compression pressures of 7.5 to 12.5 MPa minimized briquette moisture content to <8 % (w.b.) and maximized density to >700 kg/m3. Durability rating >90 % is achievable at higher die temperatures of >123 C, lower to medium feedstock moisture contents of 9 to 12 % (w.b.), low to high compression pressures of 7.5 to 12.5 MPa, and large hammer mill screen size of 31.75 mm, except for canola where a lower compression pressure of 7.5 to 8.5 MPa and a smaller hammer mill screen size of 19 mm for oat maximized the durability rating values.

  1. Impact of process conditions on the density and durability of wheat, oat, canola, and barley straw briquettes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tumuluru, J. S.; Tabil, L. G.; Song, Y.; Iroba, K. L.; Meda, V.

    2014-10-01

    The present study is to understand the impact of process conditions on the quality attributes of wheat oat, barley, and canola straw briquettes. Analysis of variance indicated that briquette moisture content and initial density immediately after compaction and final density after 2 weeks of storage are strong functions of feedstock moisture content and compression pressure, whereas durability rating is influenced by die temperature and feedstock moisture content. Briquettes produced at a low feedstock moisture content of 9 % (w.b.) yielded maximum densities >700 kg/m3 for wheat, oat, canola, and barley straws. Lower feedstock moisture content of <10 % (w.b.) andmore » higher die temperatures >110 °C and compression pressure >10 MPa minimized the briquette moisture content and maximized densities and durability rating based on surface plots observations. Optimal process conditions indicated that a low feedstock moisture content of about 9 % (w.b.), high die temperature of 120–130 °C, medium-to-large hammer mill screen sizes of about 24 to 31.75 mm, and low to high compression pressures of 7.5 to 12.5 MPa minimized briquette moisture content to <8 % (w.b.) and maximized density to >700 kg/m3. Durability rating >90 % is achievable at higher die temperatures of >123 °C, lower to medium feedstock moisture contents of 9 to 12 % (w.b.), low to high compression pressures of 7.5 to 12.5 MPa, and large hammer mill screen size of 31.75 mm, except for canola where a lower compression pressure of 7.5 to 8.5 MPa and a smaller hammer mill screen size of 19 mm for oat maximized the durability rating values.« less

  2. Effect of process variables on the density and durability of the pellets made from high moisture corn stover

    SciTech Connect (OSTI)

    Jaya Shankar Tumuluru

    2014-03-01

    A flat die pellet mill was used to understand the effect of high levels of feedstock moisture content in the range of 28–38% (w.b.), with die rotational speeds of 40–60 Hz, and preheating temperatures of 30–110 °C on the pelleting characteristics of 4.8 mm screen size ground corn stover using an 8 mm pellet die. The physical properties of the pelletised biomass studied are: (a) pellet moisture content, (b) unit, bulk and tapped density, and (c) durability. Pelletisation experiments were conducted based on central composite design. Analysis of variance (ANOVA) indicated that feedstock moisture content influenced all of the physical properties at P < 0.001. Pellet moisture content decreased with increase in preheating temperature to about 110 °C and decreasing the feedstock moisture content to about 28% (w.b.). Response surface models developed for quality attributes with respect to process variables has adequately described the process with coefficient of determination (R2) values of >0.88. The other pellet quality attributes such as unit, bulk, tapped density, were maximised at feedstock moisture content of 30–33% (w.b.), die speeds of >50 Hz and preheating temperature of >90 °C. In case of durability a medium moisture content of 33–34% (w.b.) and preheating temperatures of >70 °C and higher die speeds >50 Hz resulted in high durable pellets. It can be concluded from the present study that feedstock moisture content, followed by preheating, and die rotational speed are the interacting process variables influencing pellet moisture content, unit, bulk and tapped density and durability.

  3. Press Conference Call Tomorrow: Agriculture Secretary Vilsack...

    Office of Environmental Management (EM)

    to Reduce U.S. Oil Dependence Press Conference Call Tomorrow: Agriculture Secretary Vilsack and Energy Secretary Chu to Discuss Efforts to Reduce U.S. Oil Dependence May 4, ...

  4. Sustainable Energy Utility (SEU)- Agricultural Loan Program

    Broader source: Energy.gov [DOE]

    Delaware Sustainable Energy Utility (DESEU) offers customized loans for agricultural customer as a part of DESEU’s revolving loan program. Program applications are accepted on a rolling basis, and...

  5. Geothermal Food Processors Agricultural Drying Low Temperature...

    Open Energy Info (EERE)

    Processors is an Agricultural Drying low temperature direct use geothermal facility in Brady Hot Springs E of Fernley, Nevada. This article is a stub. You can help OpenEI by...

  6. Renewable Agricultural Energy | Open Energy Information

    Open Energy Info (EERE)

    Sector: Renewable Energy Product: Renewable Agricultural Energy plans to bring five ethanol plants on line by the end of 2009 with a combined annual capacity of at least 1.89bn...

  7. ORISE: Multiple research appointments available through Agricultural...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    RELEASE March 26, 2014 FY14-23 OAK RIDGE, Tenn.-ORAU and the U.S. Department of Agriculture are currently seeking recent doctoral degree recipients for various appointments in...

  8. Rural Cooperative Geothermal Development Electric & Agriculture |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Rural Cooperative Geothermal Development Electric & Agriculture Rural Cooperative Geothermal Development Electric & Agriculture DOE 2010 Geothermal Program Peer Review; Low Temperature Demonstration Projects low_silveria_rural_electric_coop.pdf (557.69 KB) More Documents & Publications Southwest Alaska Regional Geothermal Energy Project District Wide Geothermal Heating Conversion Blaine County School District Novel Energy Conversion Equipment for Low

  9. FGD gypsum's place in American agriculture

    SciTech Connect (OSTI)

    Haynes, C.

    2007-07-01

    Surface cracks and soil clumps form when saline-sodic, high-clay soil dries out. Treatment with FGD gypsum and irrigation water flowing into these cracks leaches salts until the aggregates swell and the cracks close up. The article describes research projects to develop agricultural uses of FGD gypsum from coal-fired power plants that have been conducted by university researchers and USDA-Agricultural Research Service scientists.

  10. Royal Agricultural and Horticultural Society of South Australia...

    Open Energy Info (EERE)

    Agricultural and Horticultural Society of South Australia Jump to: navigation, search Name: Royal Agricultural and Horticultural Society of South Australia Place: South Australia,...