Sample records for metal period number

  1. Period of K system generator of pseudorandom numbers

    E-Print Network [OSTI]

    Akopov, N Z; Floratos, Emmanuel G; Savvidy, G K

    1996-01-01T23:59:59.000Z

    We analyze the structure of the periodic trajectories of the matrix generator of pseudorandom numbers which has been proposed earlier. The structure of the periodic trajectories becomes more transparent when the rational sublattice coincides with the Galois field GF[p]. We are able to compute the period of the trajectories as a function of p and the dimension of the matrix d.

  2. Period of K System Generator of Pseudorandom Numbers

    E-Print Network [OSTI]

    N. Z. Akopov; G. G. Athanasiu; E. G. Floratos; G. K. Savvidy

    1996-02-09T23:59:59.000Z

    We analyze the structure of the periodic trajectories of the matrix generator of pseudorandom numbers which has been proposed earlier. The structure of the periodic trajectories becomes more transparent when the rational sublattice coincides with the Galois field $GF[p]$. We are able to compute the period of the trajectories as a function of $p$ and the dimension of the matrix $d$.

  3. Detection and discrimination of the periodicity of prime numbers by discrete Fourier transform

    E-Print Network [OSTI]

    Levente Csoka

    2015-01-27T23:59:59.000Z

    A novel representation of a quasi-periodic modified von Mangoldt function L(n) on prime numbers and its decomposition into Fourier series has been investigated. We focus on some particular quantities characterizing the modified von Mangoldt function. The results indicate that prime number progression can be decomposed into periodic sequences. The main approach is to decompose it into sin or cosine function. Basically, it is applied to extract hidden periodicities in seemingly quasi periodic prime function. Numerical evidences were provided to confirm the periodic distribution of primes.

  4. Periodic Metallic Nanostructures as Plasmonic Chemical Sensors Chiara Valsecchi and Alexandre G. Brolo*

    E-Print Network [OSTI]

    Brolo, Alexandre G.

    ;evaluation as chemical sensors and a brief comparison of the pPeriodic Metallic Nanostructures as Plasmonic Chemical Sensors Chiara Valsecchi and Alexandre G generation of low- cost and efficient chemical sensors and biosensors. The extensive variety

  5. Rotation numbers of invariant manifolds around unstable periodic orbits for the diamagnetic Kepler problem

    E-Print Network [OSTI]

    Zuo-Bing Wu

    2008-03-17T23:59:59.000Z

    In this paper, a method to construct topological template in terms of symbolic dynamics for the diamagnetic Kepler problem is proposed. To confirm the topological template, rotation numbers of invariant manifolds around unstable periodic orbits in a phase space are taken as an object of comparison. The rotation numbers are determined from the definition and connected with symbolic sequences encoding the periodic orbits in a reduced Poincar\\'e section. Only symbolic codes with inverse ordering in the forward mapping can contribute to the rotation of invariant manifolds around the periodic orbits. By using symbolic ordering, the reduced Poincar\\'e section is constricted along stable manifolds and a topological template, which preserves the ordering of forward sequences and can be used to extract the rotation numbers, is established. The rotation numbers computed from the topological template are the same as those computed from their original definition.

  6. Differential and Integral Equations Volume...., Number....., pp. N-SPECIES COMPETITION IN A PERIODIC CHEMOSTAT

    E-Print Network [OSTI]

    Wolkowicz, Gail S. K.

    , the single-species growth model, has a threshold between global extinction and uniform persistenceDifferential and Integral Equations Volume...., Number....., pp. N-SPECIES COMPETITION is proved and then applied to models of single-species growth and n-species competition in a periodically

  7. Thermal emission and design in one-dimensional periodic metallic photonic crystal slabs David L. C. Chan, Marin Soljaci, and J. D. Joannopoulos

    E-Print Network [OSTI]

    Soljaèiæ, Marin

    Thermal emission and design in one-dimensional periodic metallic photonic crystal slabs David L. C phenomena that drive thermal emission in one-dimensional periodic metallic photonic crystals, emphasizing of how the emissive properties of these systems can be tailored to our needs. DOI: 10.1103/PhysRevE.74

  8. Local field enhancement on metallic periodic surface structures produced by femtosecond laser pulses

    SciTech Connect (OSTI)

    Ionin, Andrei A; Kudryashov, Sergei I; Ligachev, A E; Makarov, Sergei V; Mel'nik, N N; Rudenko, A A; Seleznev, L V; Sinitsyn, D V; Khmelnitskii, R A [P N Lebedev Physics Institute, Russian Academy of Sciences, Moscow (Russian Federation)

    2013-04-30T23:59:59.000Z

    Periodic surface structures on aluminium are produced by femtosecond laser pulses for efficient excitation of surface electromagnetic waves using a strong objective (NA = 0.5). The local electromagnetic field enhancement on the structures is measured using the technique of surface-enhanced Raman scattering from pyridine molecules. (extreme light fields and their applications)

  9. Metals and Ceramics Division progress report for period ending September 30, 1991

    SciTech Connect (OSTI)

    Not Available

    1992-03-01T23:59:59.000Z

    This report provides a brief overview of the activities and accomplishments of the Metals and Ceramics (M C) Division during fiscal year (FY) 1991. The division is organized to provide technical support, primarily in the area of high-temperature materials, for the various technologies being developed by the US Department of Energy (DOE). Activities span the range from basic research (through applied research and engineering development) to industrial interactions (through cooperative research and a strong technology transfer program). The division is organized in functional groups that encompass nearly all of the disciplines needed to develop and to apply materials in high-temperature applications. Sections I through 5 describe the different functional groups; Sect. 6 provides an alternative view of the division in terms of the major programs, most of which cross group lines; and Sect. 7 summarizes external interactions including cooperative research and development programs, educational activities, and technology transfer functions. Appendices describe the organizational structure, note personnel changes, present honors and awards received by division members, and contain listings of publications completed and presentations made at technical meetings.

  10. Metals and Ceramics Division progress report for period ending September 30, 1991

    SciTech Connect (OSTI)

    Not Available

    1992-03-01T23:59:59.000Z

    This report provides a brief overview of the activities and accomplishments of the Metals and Ceramics (M&C) Division during fiscal year (FY) 1991. The division is organized to provide technical support, primarily in the area of high-temperature materials, for the various technologies being developed by the US Department of Energy (DOE). Activities span the range from basic research (through applied research and engineering development) to industrial interactions (through cooperative research and a strong technology transfer program). The division is organized in functional groups that encompass nearly all of the disciplines needed to develop and to apply materials in high-temperature applications. Sections I through 5 describe the different functional groups; Sect. 6 provides an alternative view of the division in terms of the major programs, most of which cross group lines; and Sect. 7 summarizes external interactions including cooperative research and development programs, educational activities, and technology transfer functions. Appendices describe the organizational structure, note personnel changes, present honors and awards received by division members, and contain listings of publications completed and presentations made at technical meetings.

  11. Metals and Ceramics Division progress report for period ending December 31, 1993

    SciTech Connect (OSTI)

    Craig, D.F.; Bradley, R.A.; Weir, J.R. Jr.

    1994-07-01T23:59:59.000Z

    This report provides an overview of activities and accomplishsments of the division from October 1992 through December 1993; the division is organized to provide technical support, mainly in the area of high-temperature materials, for technologies being developed by DOE. Activities span the range from basic research to industrial interactions (cooperative research and technology transfer). Sections 1-5 describe the different functional groups (engineering materials, high-temperature materials, materials science, ceramics, nuclear fuel materials). Sect. 6 provides an alternative view of the division in terms of the major programs, most of which cross group lines. Sect. 7 summarizes external interactions including cooperative R and D programs and technology transfer functions. Finally, Sect. 8 briefly describes the division`s involvement in educational activities. Several organizational changes were effected during this period.

  12. Simple formula for the interspaces of periodic grating structures self-organized on metal surfaces by femtosecond laser ablation

    SciTech Connect (OSTI)

    Hashida, Masaki; Ikuta, Yoshinobu; Miyasaka, Yasuhiro; Tokita, Shigeki; Sakabe, Shuji [ARCBS, Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan and Department of Physics, Graduate School of Science, Kyoto University, Kitashirakawa, Sakyo, Kyoto 606-8502 (Japan)] [ARCBS, Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan and Department of Physics, Graduate School of Science, Kyoto University, Kitashirakawa, Sakyo, Kyoto 606-8502 (Japan)

    2013-04-29T23:59:59.000Z

    Self-organized grating structures formed on Mo and Ti metal surfaces irradiated with femtosecond laser pulses at wavelengths of 800 and 400 nm are investigated by electron microscopy. We observe the formation of the self-organized grating structures on the metals irradiated with 400-nm laser pulses at low laser fluence in narrow fluence ranges. The interspaces of the grating structure depend on the wavelength and fluence of the laser. We find that the dependence of the grating interspaces on laser fluence can be explained by a simple formula for induction of a surface-plasma wave through the parametric decay of laser light.

  13. Ultraviolet GaN photodetectors on Si via oxide buffer heterostructures with integrated short period oxide-based distributed Bragg reflectors and leakage suppressing metal-oxide-semiconductor contacts

    SciTech Connect (OSTI)

    Szyszka, A., E-mail: szyszka@ihp-microelectronics.com, E-mail: adam.szyszka@pwr.wroc.pl [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany); Faculty of Microsystem Electronics and Photonics, Wroclaw University of Technology, Janiszewskiego 11/17, 50-372 Wroclaw (Poland); Lupina, L.; Lupina, G.; Schubert, M. A.; Zaumseil, P. [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany); Haeberlen, M.; Storck, P.; Thapa, S. B. [Siltronic, Hanns-Seidel-Platz 4, 81737 München (Germany); Schroeder, T. [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany); BTU Cottbus-Senftenberg, Konrad-Zuse-Strasse 1, 03046 Cottbus (Germany)

    2014-08-28T23:59:59.000Z

    Based on a novel double step oxide buffer heterostructure approach for GaN integration on Si, we present an optimized Metal-Semiconductor-Metal (MSM)-based Ultraviolet (UV) GaN photodetector system with integrated short-period (oxide/Si) Distributed Bragg Reflector (DBR) and leakage suppressing Metal-Oxide-Semiconductor (MOS) electrode contacts. In terms of structural properties, it is demonstrated by in-situ reflection high energy electron diffraction and transmission electron microscopy-energy dispersive x-ray studies that the DBR heterostructure layers grow with high thickness homogeneity and sharp interface structures sufficient for UV applications; only minor Si diffusion into the Y{sub 2}O{sub 3} films is detected under the applied thermal growth budget. As revealed by comparative high resolution x-ray diffraction studies on GaN/oxide buffer/Si systems with and without DBR systems, the final GaN layer structure quality is not significantly influenced by the growth of the integrated DBR heterostructure. In terms of optoelectronic properties, it is demonstrated that—with respect to the basic GaN/oxide/Si system without DBR—the insertion of (a) the DBR heterostructures and (b) dark current suppressing MOS contacts enhances the photoresponsivity below the GaN band-gap related UV cut-off energy by almost up to two orders of magnitude. Given the in-situ oxide passivation capability of grown GaN surfaces and the one order of magnitude lower number of superlattice layers in case of higher refractive index contrast (oxide/Si) systems with respect to classical III-N DBR superlattices, virtual GaN substrates on Si via functional oxide buffer systems are thus a promising robust approach for future GaN-based UV detector technologies.

  14. Statistical Time-Resolved Spectroscopy: A higher fraction of short-period binaries for metal-rich F-type dwarfs in SDSS

    E-Print Network [OSTI]

    Hettinger, T; Strader, J; Bickerton, S J; Beers, T C

    2015-01-01T23:59:59.000Z

    Stellar multiplicity lies at the heart of many problems in modern astrophysics, including the physics of star formation, the observational properties of unresolved stellar populations, and the rates of interacting binaries such as cataclysmic variables, X-ray binaries, and Type Ia supernovae. However, little is known about the stellar multiplicity of field stars in the Milky Way, in particular about the differences in the multiplicity characteristics between metal-rich disk stars and metal-poor halo stars. In this study we perform a statistical analysis of ~15,000 F-type dwarf stars in the Milky Way through time-resolved spectroscopy with the sub-exposures archived in the Sloan Digital Sky Survey. We obtain absolute radial velocity measurements through template cross-correlation of individual sub-exposures with temporal baselines varying from minutes to years. These sparsely sampled radial velocity curves are analyzed using Markov chain Monte Carlo techniques to constrain the very short-period binary fraction...

  15. Method For Characterizing Residual Stress In Metals

    DOE Patents [OSTI]

    Jacobson, Loren A. (Santa Fe, NM); Michel, David J. (Alexandria, VA); Wyatt, Jeffrey R. (Burke, VA)

    2002-12-03T23:59:59.000Z

    A method is provided for measuring the residual stress in metals. The method includes the steps of drilling one or more holes in a metal workpiece to a preselected depth and mounting one or more acoustic sensors on the metal workpiece and connecting the sensors to an electronic detecting and recording device. A liquid metal capable of penetrating into the metal workpiece placed at the bottom of the hole or holes. A recording is made over a period of time (typically within about two hours) of the magnitude and number of noise events which occur as the liquid metal penetrates into the metal workpiece. The magnitude and number of noise events are then correlated to the internal stress in the region of the workpiece at the bottom of the hole.

  16. Metallization for Self Aligned Technology: Cooperative Research and Development Final Report, CRADA Number CRD-08-295

    SciTech Connect (OSTI)

    Ginley, D.

    2012-04-01T23:59:59.000Z

    In this CRADA NREL will modify/develop metallization inks that are compatible with 1366 Technologies technology. Various methods of deposition will be used to apply the inks to the textured silicon substrates. The goal of the project is to minimize the contact resistance while maximizing the cell efficiency.

  17. Measurement of the solar neutrino capture rate with gallium metal. III. Results for the 2002-2007 data-taking period

    SciTech Connect (OSTI)

    Abdurashitov, J. N.; Gavrin, V. N.; Gorbachev, V. V.; Gurkina, P. P.; Ibragimova, T. V.; Kalikhov, A. V.; Khairnasov, N. G.; Knodel, T. V.; Mirmov, I. N.; Shikhin, A. A.; Veretenkin, E. P.; Yants, V. E.; Zatsepin, G. T.; Bowles, T. J.; Elliott, S. R.; Teasdale, W. A.; Nico, J. S.; Cleveland, B. T.; Wilkerson, J. F. [Institute for Nuclear Research, Russian Academy of Sciences, RU-117312 Moscow (Russian Federation); Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); National Institute of Standards and Technology, Stop 8461, Gaithersburg, Maryland 20899 (United States); University of Washington, Seattle, Washington 98195 (United States)

    2009-07-15T23:59:59.000Z

    The Russian-American experiment SAGE began to measure the solar neutrino capture rate with a target of gallium metal in December 1989. Measurements have continued with only a few brief interruptions since that time. In this article we present the experimental improvements in SAGE since its last published data summary in December 2001. Assuming the solar neutrino production rate was constant during the period of data collection, combined analysis of 168 extractions through December 2007 gives a capture rate of solar neutrinos with energy more than 233 keV of 65.4{sub -3.0}{sup +3.1} (stat) {sub -2.8}{sup +2.6} (syst) SNU. The weighted average of the results of all three Ga solar neutrino experiments, SAGE, Gallex, and GNO, is now 66.1{+-}3.1 SNU, where statistical and systematic uncertainties have been combined in quadrature. During the recent period of data collection a new test of SAGE was made with a reactor-produced {sup 37}Ar neutrino source. The ratio of observed to calculated rates in this experiment, combined with the measured rates in the three prior {sup 51}Cr neutrino-source experiments with Ga, is 0.87{+-}0.05. A probable explanation for this low result is that the cross section for neutrino capture by the two lowest-lying excited states in {sup 71}Ge has been overestimated. If we assume these cross sections are zero, then the standard solar model including neutrino oscillations predicts a total capture rate in Ga in the range of 63 SNU to 66 SNU with an uncertainty of about 4%, in good agreement with experiment. We derive the current value of the neutrino flux produced in the Sun by the proton-proton fusion reaction to be {phi}{sub pp}{sup {center_dot}}=(6.0{+-}0.8)x10{sup 10}/(cm{sup 2} s), which agrees well with the pp flux predicted by the standard solar model. Finally, we make several tests and show that the data are consistent with the assumption that the solar neutrino production rate is constant in time.

  18. Measurement of the solar neutrino capture rate with gallium metal. III: Results for the 2002--2007 data-taking period

    E-Print Network [OSTI]

    SAGE Collaboration; J. N. Abdurashitov; V. N. Gavrin; V. V. Gorbachev; P. P. Gurkina; T. V. Ibragimova; A. V. Kalikhov; N. G. Khairnasov; T. V. Knodel; I. N. Mirmov; A. A. Shikhin; E. P. Veretenkin; V. E. Yants; G. T. Zatsepin; T. J. Bowles; S. R. Elliott; W. A. Teasdale; J. S. Nico; B. T. Cleveland; J. F. Wilkerson

    2009-08-10T23:59:59.000Z

    The Russian-American experiment SAGE began to measure the solar neutrino capture rate with a target of gallium metal in Dec. 1989. Measurements have continued with only a few brief interruptions since that time. We give here the experimental improvements in SAGE since its last published data summary in Dec. 2001. Assuming the solar neutrino production rate was constant during the period of data collection, combined analysis of 168 extractions through Dec. 2007 gives a capture rate of solar neutrinos with energy more than 233 keV of 65.4 (+3.1)(-3.0) (stat) (+2.6)(-2.8) (syst) SNU. The weighted average of the results of all three Ga solar neutrino experiments, SAGE, Gallex, and GNO, is now 66.1 +/- 3.1 SNU, where statistical and systematic uncertainties have been combined in quadrature. During the recent period of data collection a new test of SAGE was made with a reactor-produced 37Ar neutrino source. The ratio of observed to calculated rates in this experiment, combined with the measured rates in the three prior 51Cr neutrino-source experiments with Ga, is 0.87 +/- 0.05. A probable explanation for this low result is that the cross section for neutrino capture by the two lowest-lying excited states in 71Ge has been overestimated. If we assume these cross sections are zero, then the standard solar model including neutrino oscillations predicts a total capture rate in Ga in the range of 63-66 SNU with an uncertainty of about 4%, in good agreement with experiment. We derive the current value of the neutrino flux produced in the Sun by the proton-proton fusion reaction to be (6.0 +/- 0.8) x 10^(10)/(cm^2 s), which agrees well with the pp flux predicted by the standard solar model. Finally, we show that the data are consistent with the assumption that the solar neutrino production rate is constant in time.

  19. Metallic Inks for Solar Cells: Cooperative Research and Development Final Report, CRADA Number CRD-10-370

    SciTech Connect (OSTI)

    van Hest, M.

    2013-04-01T23:59:59.000Z

    This document describes the statement of work for National Renewable Energy Laboratory (NREL) as a subcontractor for Applied Nanotech, Inc. (ANI) for the Phase II SBIR contract with the Department of Energy to build silicon solar cells using non-contact printed, nanoparticle-based metallic inks. The conductive inks are based upon ANI's proprietary method for nanoparticle dispersion. The primary inks under development are aluminum for silicon solar cell back plane contacts and copper for top interdigitated contacts. The current direction of silicon solar cell technology is to use thinner silicon wafers. The reduction in wafer thickness reduces overall material usage and can increase efficiency. These thin silicon wafers are often very brittle and normal methods used for conductive feed line application, such as screen-printing, are detrimental. The Phase II program will be focused on materials development for metallic inks that can be applied to a silicon solar cell using non-contact methods. Uniform BSF (Back Surface Field) formation will be obtained by optimizing ink formulation and curing conditions to improve cell efficiency.

  20. Carbon-enhanced metal-poor stars: a window on AGB nucleosynthesis and binary evolution. I. Detailed analysis of 15 binary stars with known orbital periods

    E-Print Network [OSTI]

    Abate, C; Karakas, A I; Izzard, R G

    2015-01-01T23:59:59.000Z

    AGB stars are responsible for producing a variety of elements, including carbon, nitrogen, and the heavy elements produced in the slow neutron-capture process ($s$-elements). There are many uncertainties involved in modelling the evolution and nucleosynthesis of AGB stars, and this is especially the case at low metallicity, where most of the stars with high enough masses to enter the AGB have evolved to become white dwarfs and can no longer be observed. The stellar population in the Galactic halo is of low mass ($\\lesssim 0.85M_{\\odot}$) and only a few observed stars have evolved beyond the first giant branch. However, we have evidence that low-metallicity AGB stars in binary systems have interacted with their low-mass secondary companions in the past. The aim of this work is to investigate AGB nucleosynthesis at low metallicity by studying the surface abundances of chemically peculiar very metal-poor stars of the halo observed in binary systems. To this end we select a sample of 15 carbon- and $s$-element-en...

  1. Fourier series and periodicity

    E-Print Network [OSTI]

    Donal F. Connon

    2014-12-07T23:59:59.000Z

    A large number of the classical texts dealing with Fourier series more or less state that the hypothesis of periodicity is required for pointwise convergence. In this paper, we highlight the fact that this condition is not necessary.

  2. A National Assistance Extension Program for Metal Casting: a foundation industry. Final report for the period February 16, 1994 through May 15, 1997

    SciTech Connect (OSTI)

    NONE

    1997-09-01T23:59:59.000Z

    The TRP award was proposed as an umbrella project to build infrastructure and extract lessons about providing extension-enabling services to the metal casting industry through the national network of Manufacturing Technology Center`s (MTC`s). It targeted four discrete task areas required for the MCC to service the contemplated needs of industry, and in which the MCC had secured substantial involvement of partner organizations. Task areas identified included Counter-Gravitational Casting, Synchronous Manufacturing, Technology Deployment, and Facility and Laboratory Improvements. Each of the task areas includes specific subtasks which are described.

  3. Mo Year Report Period: EIA ID NUMBER:

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells, Wisconsin:DeploymentSite Name:24,High824 2.839 2.8352.747 2.759 2.699Mo

  4. Magnetic metallic multilayers

    SciTech Connect (OSTI)

    Hood, R.Q.

    1994-04-01T23:59:59.000Z

    Utilizing self-consistent Hartree-Fock calculations, several aspects of multilayers and interfaces are explored: enhancement and reduction of the local magnetic moments, magnetic coupling at the interfaces, magnetic arrangements within each film and among non-neighboring films, global symmetry of the systems, frustration, orientation of the various moments with respect to an outside applied field, and magnetic-field induced transitions. Magnetoresistance of ferromagnetic-normal-metal multilayers is found by solving the Boltzmann equation. Results explain the giant negative magnetoresistance encountered in these systems when an initial antiparallel arrangement is changed into a parallel configuration by an external magnetic field. The calculation depends on (1) geometric parameters (thicknesses of layers), (2) intrinsic metal parameters (number of conduction electrons, magnetization, and effective masses in layers), (3) bulk sample properties (conductivity relaxation times), (4) interface scattering properties (diffuse scattering versus potential scattering at the interfaces, and (5) outer surface scattering properties (specular versus diffuse surface scattering). It is found that a large negative magnetoresistance requires considerable asymmetry in interface scattering for the two spin orientations. Features of the interfaces that may produce an asymmetrical spin-dependent scattering are studied: varying interfacial geometric random roughness with no lateral coherence, correlated (quasi-periodic) roughness, and varying chemical composition of the interfaces. The interplay between these aspects of the interfaces may enhance or suppress the magnetoresistance, depending on whether it increases or decreases the asymmetry in the spin-dependent scattering of the conduction electrons.

  5. VOLUME 86, NUMBER 23 P H Y S I C A L R E V I E W L E T T E R S 4 JUNE 2001 Light-Induced Metal-Insulator Transition in a Switchable Mirror

    E-Print Network [OSTI]

    Wijngaarden, Rinke J.

    possibility to tune yttrium hydride through the T 0 metal-insulator transition. Conductivity and Hall

  6. Stabilization of Electrocatalytic Metal Nanoparticles at Metal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electrocatalytic Metal Nanoparticles at Metal-Metal Oxide-Graphene Triple Junction Points. Stabilization of Electrocatalytic Metal Nanoparticles at Metal-Metal Oxide-Graphene...

  7. Water Research Consortium U.S. Department of Energy Grant Award Number DE-FG02-05ER64132 Final Technical Report For Period Beginning: 15 September 2005 And Ending: 31 December 2009 Report Date: 16 March 2010

    SciTech Connect (OSTI)

    Steven R. Billingsley

    2010-03-18T23:59:59.000Z

    This report summarizes the activities of the INRA Water Research Consortium (IWRC) for the period beginning September 15, 2005 and ending December 16, 2010. This report compares accomplishments to project objectives, documents the activities associated with this project, and lists products developed during the course of the project. The Water Resources Research Needs Assessment team received funding from the Inland Northwest Research Alliance Water Resources Steering Committee to facilitate a structured needs assessment process that could provide a basis for future targeted research efforts to improve regional water resources management in the Inland Northwest region. The original INRA proposal specifically mentions the need to conduct a detailed assessment of the information and research needs of policy makers and water user groups during a period of increasing competition for scarce water supplies. A particular focus of this assessment would be to understand what types of research might facilitate water resource management during periods of drought. The specific goals of the Needs Assessment project were to: (1) Quickly ascertain the perceptions of diverse stakeholders in this region; (2) Condense this complex information into a format that can be shared with the INRA scientific panel, and (3) Develop of a realistic set of research needs & priorities that can shape future INRA-funded research activities.

  8. Metal aminoboranes

    DOE Patents [OSTI]

    Burrell, Anthony K.; Davis, Benjamin J.; Thorn, David L.; Gordon, John C.; Baker, R. Thomas; Semelsberger, Troy Allen; Tumas, William; Diyabalanage, Himashinie Vichalya; Shrestha, Roshan P.

    2010-05-11T23:59:59.000Z

    Metal aminoboranes of the formula M(NH2BH3)n have been synthesized. Metal aminoboranes are hydrogen storage materials. Metal aminoboranes are also precursors for synthesizing other metal aminoboranes. Metal aminoboranes can be dehydrogenated to form hydrogen and a reaction product. The reaction product can react with hydrogen to form a hydrogen storage material. Metal aminoboranes can be included in a kit.

  9. Storm Water Analytical Period

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Protection Obeying Environmental Laws Individual Permit Storm Water Analytical Period Storm Water Analytical Period The Individual Permit authorizes the discharge of storm...

  10. Student Job Review Questionnaire / Periodic Survey

    E-Print Network [OSTI]

    Amin, S. Massoud

    Student Job Review Questionnaire / Periodic Survey FOR OHR USE ONLY No Change Date Received JRQ Number Notice Number Job Family Title Job Family Number New Pay Rate/Range Certifiable Yes No Effective Date Approved for Notice Letter Date Notice Mailed Job Review Questionnaire (JRQ) (Student Request

  11. Thermodynamics and kinetics of ceramic/metal interfacial interactions

    E-Print Network [OSTI]

    Arróyave, Raymundo, 1975-

    2004-01-01T23:59:59.000Z

    Ceramic/metal interfaces occur in a great number of important applications, such as ceramic/metal composites, microelectronics packaging, ceramic/metal seals, and so forth. Understanding the formation and evolution of such ...

  12. Metal inks

    DOE Patents [OSTI]

    Ginley, David S; Curtis, Calvin J; Miedaner, Alex; van Hest, Marinus Franciscus Antonius Maria; Kaydanova, Tatiana

    2014-02-04T23:59:59.000Z

    Self-reducing metal inks and systems and methods for producing and using the same are disclosed. In an exemplary embodiment, a method may comprise selecting metal-organic (MO) precursor, selecting a reducing agent, and dissolving the MO precursor and the reducing agent in an organic solvent to produce a metal ink that remains in a liquid phase at room temperature. Metal inks, including self-reducing and fire-through metal inks, are also disclosed, as are various applications of the metal inks.

  13. Permanent Home Number: Residential Number

    E-Print Network [OSTI]

    Viglas, Anastasios

    Permanent Home Number: Residential Number: Mobile: Please update my contact details. Signature nominated correspondence address as indicated below. Permanent Home Adress Residential Address Other Address (Must not be a PO Box) Residential Address (Must not be a PO Box) Other - Postal/Optional Address

  14. UNIT NUMBER:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    193 UNIT NUMBER: 197 UNIT NAME: CONCRETE RUBBLE PILE (30) REGULATORY STATUS: AOC LOCATION: Outside plant security fence, north of the plant on Big Bayou Creek on private property....

  15. Silicone metalization

    DOE Patents [OSTI]

    Maghribi, Mariam N. (Livermore, CA); Krulevitch, Peter (Pleasanton, CA); Hamilton, Julie (Tracy, CA)

    2008-12-09T23:59:59.000Z

    A system for providing metal features on silicone comprising providing a silicone layer on a matrix and providing a metal layer on the silicone layer. An electronic apparatus can be produced by the system. The electronic apparatus comprises a silicone body and metal features on the silicone body that provide an electronic device.

  16. Supported molten-metal catalysts

    DOE Patents [OSTI]

    Datta, Ravindra (Iowa City, IA); Singh, Ajeet (Iowa City, IA); Halasz, Istvan (Iowa City, IA); Serban, Manuela (Iowa City, IA)

    2001-01-01T23:59:59.000Z

    An entirely new class of catalysts called supported molten-metal catalysts, SMMC, which can replace some of the existing precious metal catalysts used in the production of fuels, commodity chemicals, and fine chemicals, as well as in combating pollution. SMMC are based on supporting ultra-thin films or micro-droplets of the relatively low-melting (<600.degree. C.), inexpensive, and abundant metals and semimetals from groups 1, 12, 13, 14, 15 and 16, of the periodic table, or their alloys and intermetallic compounds, on porous refractory supports, much like supported microcrystallites of the traditional solid metal catalysts. It thus provides orders of magnitude higher surface area than is obtainable in conventional reactors containing molten metals in pool form and also avoids corrosion. These have so far been the chief stumbling blocks in the application of molten metal catalysts.

  17. Heat transfer at the mold-metal interface in permanent mold casting of aluminum alloys project. Annual project status report for the period October 1, 1997 to September 30, 1998

    SciTech Connect (OSTI)

    Pehlke, R.D.; Hao, S.W.

    1998-09-30T23:59:59.000Z

    In the first year of this three-year project, substantial progress has been achieved. This project on heat transfer coefficients in metal permanent mold casting is being conducted in three areas. They are the theoretical study at the University of Michigan, the experimental investigations of squeeze casting and semi-solid casting at CMI-Tech Center, and the experimental investigation of low pressure permanent mold casting at Amcast Automotive. U-M did an initial geometry which was defined for ProCAST to solve, and then a geometry half the size was defined and solved using the same boundary conditions. A conceptual mold geometry was examined and is represented as an axisymmetric element.Furthermore, the influences of the localized heat transfer coefficients on the casting process were carefully studied. The HTC Evaluator has been proposed and initially developed by the U-M team. The Reference and the Database Modules of the HTC Evaluator have been developed, and extensively tested. A series of technical barriers have been cited and potential solutions have been surveyed. At the CMI-Tech Center, the Kistler direct cavity pressure measurement system has been purchased and tested. The calibrations has been evaluated. The probe is capable of sensing a light finger pressure. The experimental mold has been designed and modified. The experimental mold has been designed and modified. The first experiment is scheduled for October 14, 1998. The geometry of the experimental hockey-puck casting has been given to the U-M team for numerical analysis.

  18. Change Number

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWPSuccessAlamos LaboratoryCertified Reference6-02-01Change Number

  19. Periodic subsystem density-functional theory

    SciTech Connect (OSTI)

    Genova, Alessandro; Pavanello, Michele, E-mail: m.pavanello@rutgers.edu [Department of Chemistry, Rutgers University, Newark, New Jersey 07102 (United States); Ceresoli, Davide [Department of Chemistry, Rutgers University, Newark, New Jersey 07102 (United States); CNR-ISTM, Institute of Molecular Sciences and Technologies, Milano (Italy)

    2014-11-07T23:59:59.000Z

    By partitioning the electron density into subsystem contributions, the Frozen Density Embedding (FDE) formulation of subsystem Density Functional Theory (DFT) has recently emerged as a powerful tool for reducing the computational scaling of Kohn–Sham DFT. To date, however, FDE has been employed to molecular systems only. Periodic systems, such as metals, semiconductors, and other crystalline solids have been outside the applicability of FDE, mostly because of the lack of a periodic FDE implementation. To fill this gap, in this work we aim at extending FDE to treat subsystems of molecular and periodic character. This goal is achieved by a dual approach. On one side, the development of a theoretical framework for periodic subsystem DFT. On the other, the realization of the method into a parallel computer code. We find that periodic FDE is capable of reproducing total electron densities and (to a lesser extent) also interaction energies of molecular systems weakly interacting with metallic surfaces. In the pilot calculations considered, we find that FDE fails in those cases where there is appreciable density overlap between the subsystems. Conversely, we find FDE to be in semiquantitative agreement with Kohn–Sham DFT when the inter-subsystem density overlap is low. We also conclude that to make FDE a suitable method for describing molecular adsorption at surfaces, kinetic energy density functionals that go beyond the GGA level must be employed.

  20. Genealogy of periodic trajectories

    SciTech Connect (OSTI)

    de Adguiar, M.A.M.; Maldta, C.P.; de Passos, E.J.V.

    1986-05-20T23:59:59.000Z

    The periodic solutions of non-integrable classical Hamiltonian systems with two degrees of freedom are numerically investigated. Curves of periodic families are given in plots of energy vs. period. Results are presented for this Hamiltonian: H = 1/2(p/sub x//sup 2/ + p/sub y//sup 2/) + 1/2 x/sup 2/ + 3/2 y/sup 2/ - x/sup 2/y + 1/12 x/sup 4/. Properties of the families of curves are pointed out. (LEW)

  1. Metal oxide films on metal

    DOE Patents [OSTI]

    Wu, Xin D. (Los Alamos, NM); Tiwari, Prabhat (Los Alamos, NM)

    1995-01-01T23:59:59.000Z

    A structure including a thin film of a conductive alkaline earth metal oxide selected from the group consisting of strontium ruthenium trioxide, calcium ruthenium trioxide, barium ruthenium trioxide, lanthanum-strontium cobalt oxide or mixed alkaline earth ruthenium trioxides thereof upon a thin film of a noble metal such as platinum is provided.

  2. Three regimes of extrasolar planets inferred from host star metallicities

    E-Print Network [OSTI]

    Buchhave, Lars A; Latham, David W; Sasselov, Dimitar; Cochran, William D; Endl, Michael; Isaacson, Howard; Juncher, Diana; Marcy, Geoffrey W

    2014-01-01T23:59:59.000Z

    Approximately half of the extrasolar planets (exoplanets) with radii less than four Earth radii are in orbits with short periods. Despite their sheer abundance, the compositions of such planets are largely unknown. The available evidence suggests that they range in composition from small, high-density rocky planets to low-density planets consisting of rocky cores surrounded by thick hydrogen and helium gas envelopes. Understanding the transition from the gaseous planets to Earth-like rocky worlds is important to estimate the number of potentially habitable planets in our Galaxy and provide constraints on planet formation theories. Here we report the abundances of heavy elements (that is, the metallicities) of more than 400 stars hosting 600 exoplanet candidates, and find that the exoplanets can be categorized into three populations defined by statistically distinct (~ 4.5{\\sigma}) metallicity regions. We interpret these regions as reflecting the formation regimes of terrestrial-like planets (radii less than 1...

  3. Metals 2000

    SciTech Connect (OSTI)

    Allison, S.W.; Rogers, L.C.; Slaughter, G. [Oak Ridge National Lab., TN (United States); Boensch, F.D. [6025 Oak Hill Lane, Centerville, OH (United States); Claus, R.O.; de Vries, M. [Virginia Polytechnic Inst. and State Univ., Blacksburg, VA (United States)

    1993-05-01T23:59:59.000Z

    This strategic planning exercise identified and characterized new and emerging advanced metallic technologies in the context of the drastic changes in global politics and decreasing fiscal resources. In consideration of a hierarchy of technology thrusts stated by various Department of Defense (DOD) spokesmen, and the need to find new and creative ways to acquire and organize programs within an evolving Wright Laboratory, five major candidate programs identified are: C-17 Flap, Transport Fuselage, Mach 5 Aircraft, 4.Fighter Structures, and 5. Missile Structures. These results were formed by extensive discussion with selected major contractors and other experts, and a survey of advanced metallic structure materials. Candidate structural applications with detailed metal structure descriptions bracket a wide variety of uses which warrant consideration for the suggested programs. An analysis on implementing smart skins and structures concepts is given from a metal structures perspective.

  4. Dendritic metal nanostructures

    DOE Patents [OSTI]

    Shelnutt, John A. (Tijeras, NM); Song, Yujiang (Albuquerque, NM); Pereira, Eulalia F. (Vila Nova de Gaia, PT); Medforth, Craig J. (Winters, CA)

    2010-08-31T23:59:59.000Z

    Dendritic metal nanostructures made using a surfactant structure template, a metal salt, and electron donor species.

  5. Quarterly Construction Status Report Period Ending: June 30, 2013

    E-Print Network [OSTI]

    Alpay, S. Pamir

    Quarterly Construction Status Report Period Ending: June 30, 2013 Storrs and Regional Campuses University of Connecticut Health Center Quarterly Construction Status Report for Period Ending: June 30, 2013 #12;Quarterly Construction Status Report Period Ending: June 30, 2013 Project Number Project Index

  6. Quarterly Construction Status Report Period Ending: March 31, 2014

    E-Print Network [OSTI]

    Alpay, S. Pamir

    Quarterly Construction Status Report Period Ending: March 31, 2014 Storrs and Regional Campuses University of Connecticut Health Center Quarterly Construction Status Report for Period Ending: March 31, 2014 #12;Quarterly Construction Status Report Period Ending: March 31, 2014 Project Number Project

  7. Method of nitriding refractory metal articles

    DOE Patents [OSTI]

    Tiegs, Terry N. (Lenoir City, TN); Holcombe, Cressie E. (Knoxville, TN); Dykes, Norman L. (Oak Ridge, TN); Omatete, Ogbemi O. (Lagos, NG); Young, Albert C. (Flushing, NY)

    1994-01-01T23:59:59.000Z

    A method of nitriding a refractory-nitride forming metal or metalloid articles and composite articles. A consolidated metal or metalloid article or composite is placed inside a microwave oven and nitrogen containing gas is introduced into the microwave oven. The metal or metalloid article or composite is heated to a temperature sufficient to react the metal or metalloid with the nitrogen by applying a microwave energy within the microwave oven. The metal or metalloid article or composite is maintained at that temperature for a period of time sufficient to convert the article of metal or metalloid or composite to an article or composite of refractory nitride. In addition, a method of applying a coating, such as a coating of an oxide, a carbide, or a carbo-nitride, to an article of metal or metalloid by microwave heating.

  8. clock period selection method slack minimization criteria

    E-Print Network [OSTI]

    California at Irvine, University of

    An optimal clock period selection method based on slack minimization criteria En­Shou Chang Daniel the effect of clock slack on the performance of designs and present an algorithm to find a slack]: allocation, scheduling and binding. The purpose of alloca­ tion is to determine the number of resources

  9. Metal Hydrides

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(FactDepartment3311, 3312), OctoberMay 18-19,DepartmentEnergyMetalMetal

  10. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing...

  11. Elastic tail propulsion at low Reynolds number

    E-Print Network [OSTI]

    Yu, Tony S. (Tony Sheung)

    2007-01-01T23:59:59.000Z

    A simple way to generate propulsion at low Reynolds number is to periodically oscillate a passive flexible filament. Here we present a macroscopic experimental investigation of such a propulsive mechanism. A robotic swimmer ...

  12. Trends in Aqueous Hydration Across the 4f Period Assessed by Reliable Computational Methods

    SciTech Connect (OSTI)

    Kuta, Jadwiga; Clark, Aurora E.

    2010-09-06T23:59:59.000Z

    The geometric and electronic structures, as well as the thermodynamic properties of trivalent lanthanide hydrates {Ln(H?O)?,? ³? and Ln(H?O)?,?(H?O)??,?? ³?, Ln = La – Lu} have been examined using unrestricted density functional theory (UDFT), unrestricted M€oller-Plesset perturbation theory (UMP2), and multiconfigurational self-consistent field methods (MCSCF). While Ln-hydrates with 2-5 unpaired f-electrons have some multiconfigurational character, the correlation energy lies within 5-7 kcal/mol across the period and for varying coordination numbers. As such DFT yields structural parameters and thermodynamic data quite close to experimental values. Both UDFT and UMP2 predict free energies of water addition to the Ln(H?O)? ³? species to become less favorable across the period; however, it is a non-linear function of the surface charge density of the ion. UDFT further predicts that the symmetry of the metal-water bond lengths is sensitive to the specific f-electron configuration, presumably because of repulsive interactions between filled f-orbitals and water lone-pairs. Within the Ln(H?O)?,?(H?O)??,?? ³?clusters, interactions between solvation shells overrides this orbital effect, increasing the accuracy of the geometric parameters and calculated vibrational frequencies. Calculated atomic charges indicate that the water ligands each donate 0.1 to 0.2 electrons to the Ln(III) metals, with increasing electron donation across the period. Significant polarization and charge transfer between solvation shells is also observed. The relationship between empirical effective charges and calculated atomic charges is discussed with suggestions for reconciling the trends across the period.

  13. Metalization of lipid vesicles via electroless plating

    SciTech Connect (OSTI)

    Ferrar, W.T.; O'Brien, D.F.; Warshawsky, A.; Voycheck, C.L.

    1988-01-06T23:59:59.000Z

    The encapsulation of metallic particles and metallic oxides within lipid vesicles has recently been of interest for applications such as catalysis, water splitting, and magnetic control of spin coupling. In this communication the authors introduce the concept and practice of the deposition of metal on vesicles by using electroless plating techniques. Coordination of low valent transition metals to organic functional groups on the surface of the bilayer membrane provides a means of binding metal atoms to vesicles. Chemical reduction produced zero valent atoms which serve as sites for further metal deposition by the chemical reduction techniques of electroless plating. Specifically, this procedure involved the binding of a small amount of tetrachloropalladate to the vesicle bilayer, reduction of the palladium(II) to palladium(0), followed by the deposition of much larger amounts of metal from an electroless plating solution. Electroless plating solutions were used for the deposition of palladium, nickel, cobalt, or copper metal onto the catalytic palladium centers. Since the metallic particles were associated with the vesicles, colloids were formed that were stable in water for much longer periods than the control metal particles formed in water alone. If the vesicles were composed in part of unsaturated lipids, with the olefinic groups on the hydrocarbon chains, the initial evidence suggests the transition metal was directed into the bilayer, rather than staying on the surface.

  14. Approximating Metal-Insulator Transitions

    E-Print Network [OSTI]

    C. Danieli; K. Rayanov; B. Pavlov; G. Martin; S. Flach

    2014-05-06T23:59:59.000Z

    We consider quantum wave propagation in one-dimensional quasiperiodic lattices. We propose an iterative construction of quasiperiodic potentials from sequences of potentials with increasing spatial period. At each finite iteration step the eigenstates reflect the properties of the limiting quasiperiodic potential properties up to a controlled maximum system size. We then observe approximate metal-insulator transitions (MIT) at the finite iteration steps. We also report evidence on mobility edges which are at variance to the celebrated Aubry-Andre model. The dynamics near the MIT shows a critical slowing down of the ballistic group velocity in the metallic phase similar to the divergence of the localization length in the insulating phase.

  15. Polarization dependence of the temporal response of metal-semiconductor-metal photodetectors

    E-Print Network [OSTI]

    Van Driel, Henry M.

    of MSM-PD effi- ciency when the electrode period ( ) is comparable to the wavelength of the incident-semiconductor-metal photodetector temporal response is shown to be significant, and largest for devices with electrode periods less insensitive devices require special electrode patterning7 or . When used as a polarization analyzer/ detector

  16. Total Estimated Contract Cost: Performance Period Total Fee Paid

    Office of Environmental Management (EM)

    FY2011 FY2012 Fee Information Minimum Fee Maximum Fee September 2014 Contract Number: Cost Plus Incentive Fee Contractor: 3,260,603,765 Contract Period: EM Contractor Fee Site:...

  17. Total Estimated Contract Cost: Performance Period Total Fee Paid

    Office of Environmental Management (EM)

    Wastren-EnergX Mission Support LLC Contract Number: DE-CI0000004 Contract Type: Cost Plus Award Fee 128,879,762 Contract Period: December 2009 - July 2015 Fee Information...

  18. Total Estimated Contract Cost: Performance Period Total Fee Paid

    Office of Environmental Management (EM)

    - September 2015 September 2014 Contractor: Contract Number: Contract Type: Idaho Treatment Group LLC DE-EM0001467 Cost Plus Award Fee Fee Information 444,161,295 Contract Period:...

  19. Total Estimated Contract Cost: Performance Period Total Fee Paid

    Office of Environmental Management (EM)

    Number: Contract Type: Contract Period: 0 Minimum Fee Maximum Fee Washington River Protection Solutions LLC DE-AC27-08RV14800 Cost Plus Award Fee 5,553,789,617 Fee Information...

  20. Total Estimated Contract Cost: Performance Period Total Fee Paid

    Office of Environmental Management (EM)

    & Wilcox Conversion Services, LLC Contract Number: DE-AC30-11CC40015 Contract Type: Cost Plus Award Fee Fee Available 4,324,912 408,822,369 Contract Period: December 2010 -...

  1. PERIODIC WAVELET TRANSFORMS AND PERIODICITY JOHN J. BENEDETTO AND G

    E-Print Network [OSTI]

    Benedetto, John J.

    PERIODIC WAVELET TRANSFORMS AND PERIODICITY DETECTION JOHN J. BENEDETTO #3; AND G  OTZ E. PFANDER y Key words. Continuous wavelet transform, epileptic seizure prediction, periodicity detection algorithm, optimal generalized Haar wavelets, wavelet frames on Z. AMS subject classi#12;cations. 42C99, 42C

  2. Method for preparing hydride configurations and reactive metal surfaces

    DOE Patents [OSTI]

    Silver, Gary L. (Centerville, OH)

    1988-08-16T23:59:59.000Z

    A method for preparing highly hydrogen-reactive surfaces on metals which normally require substantial heating, high pressures, or an extended induction period, which involves pretreatment of said surfaces with either a non-oxidizing acid or hydrogen gas to form a hydrogen-bearing coating on said surfaces, and subsequently heating said coated metal in the absence of moisture and oxygen for a period sufficient to decompose said coating and cooling said metal to room temperature. Surfaces so treated will react almost instantaneously with hydrogen gas at room temperature and low pressure. The method is particularly applicable to uranium, thorium, and lanthanide metals.

  3. Extracting metals directly from metal oxides

    DOE Patents [OSTI]

    Wai, C.M.; Smart, N.G.; Phelps, C.

    1997-02-25T23:59:59.000Z

    A method of extracting metals directly from metal oxides by exposing the oxide to a supercritical fluid solvent containing a chelating agent is described. Preferably, the metal is an actinide or a lanthanide. More preferably, the metal is uranium, thorium or plutonium. The chelating agent forms chelates that are soluble in the supercritical fluid, thereby allowing direct removal of the metal from the metal oxide. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of {beta}-diketones, halogenated {beta}-diketones, phosphinic acids, halogenated phosphinic acids, carboxylic acids, halogenated carboxylic acids, and mixtures thereof. In especially preferred embodiments, at least one of the chelating agents is fluorinated. The method provides an environmentally benign process for removing metals from metal oxides without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the metal recovered, to provide an economic, efficient process. 4 figs.

  4. Extracting metals directly from metal oxides

    DOE Patents [OSTI]

    Wai, Chien M. (Moscow, ID); Smart, Neil G. (Moscow, ID); Phelps, Cindy (Moscow, ID)

    1997-01-01T23:59:59.000Z

    A method of extracting metals directly from metal oxides by exposing the oxide to a supercritical fluid solvent containing a chelating agent is described. Preferably, the metal is an actinide or a lanthanide. More preferably, the metal is uranium, thorium or plutonium. The chelating agent forms chelates that are soluble in the supercritical fluid, thereby allowing direct removal of the metal from the metal oxide. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of .beta.-diketones, halogenated .beta.-diketones, phosphinic acids, halogenated phosphinic acids, carboxylic acids, halogenated carboxylic acids, and mixtures thereof. In especially preferred embodiments, at least one of the chelating agents is fluorinated. The method provides an environmentally benign process for removing metals from metal oxides without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the metal recovered, to provide an economic, efficient process.

  5. Removal of metal ions from aqueous solution

    DOE Patents [OSTI]

    Jackson, Paul J. (both Los Alamos, NM); Delhaize, Emmanuel (both Los Alamos, NM); Robinson, Nigel J. (Durham, GB2); Unkefer, Clifford J. (Los Alamos, NM); Furlong, Clement (Seattle, WA)

    1990-11-13T23:59:59.000Z

    A method of removing heavy metals from aqueous solution, a composition of matter used in effecting said removal, and apparatus used in effecting said removal. One or more of the polypeptides, poly (.gamma.-glutamylcysteinyl)glycines, is immobilized on an inert material in particulate form. Upon contact with an aqueous solution containing heavy metals, the polypeptides sequester the metals, removing them from the solution. There is selectivity of poly (.gamma.-glutamylcysteinyl)glycines having a particular number of monomer repeat unit for particular metals. The polypeptides are easily regenerated by contact with a small amount of an organic acid, so that they can be used again to remove heayv metals from solution. This also results in the removal of the metals from the column in a concentrated form.

  6. Removal of metal ions from aqueous solution

    DOE Patents [OSTI]

    Jackson, Paul J. (Los Alamos, NM); Delhaize, Emmanuel (Los Alamos, NM); Robinson, Nigel J. (Durham, GB2); Unkefer, Clifford J. (Los Alamos, NM); Furlong, Clement (Seattle, WA)

    1990-01-01T23:59:59.000Z

    A method of removing heavy metals from aqueous solution, a composition of matter used in effecting said removal, and apparatus used in effecting said removal. One or more of the polypeptides, poly (.gamma.-glutamylcysteinyl)glycines, is immobilized on an inert material in particulate form. Upon contact with an aqueous solution containing heavy metals, the polypeptides sequester the metals, removing them from the solution. There is selectivity of poly (.gamma.-glutamylcysteinyl)glycines having a particular number of monomer repeat units for particular metals. The polypeptides are easily regenerated by contact with a small amount of an organic acid, so that they can be used again to remove heavy metals from solution. This also results in the removal of the metals from the column in a concentrated form.

  7. RARE-EARTH METALS--1997 61.1 RARE-EARTH METALS

    E-Print Network [OSTI]

    RARE-EARTH METALS--1997 61.1 RARE-EARTH METALS By James B. Hedrick The rare earths are a relatively million, to thulium and lutetium, the least abundant rare-earth elements at about 0.5 parts per million. Scandium, atomic number 21, is the lightest rare-earth element. It is the 31st most abundant element

  8. INEL metal recycle radioactive scrap metal survey report

    SciTech Connect (OSTI)

    Funk, D.M.

    1994-09-01T23:59:59.000Z

    DOE requested that inventory and characterization of radioactive scrap metal (RSM) be conducted across the DOE complex. Past studies have estimated the metal available from unsubstantiated sources. In meetings held in FY-1993, with seven DOE sites represented and several DOE-HQ personnel present, INEL personnel discovered that these numbers were not reliable and that large stockpiles did not exist. INEL proposed doing in-field measurements to ascertain the amount of RSM actually available. This information was necessary to determine the economic viability of recycling and to identify feed stock that could be used to produce containers for radioactive waste. This inventory measured the amount of RSM available at the selected DOE sites. Information gathered included radionuclide content and chemical form, general radiation field, alloy type, and mass of metal.

  9. Lithium metal oxide electrodes for lithium batteries

    DOE Patents [OSTI]

    Thackeray, Michael M. (Naperville, IL); Kim, Jeom-Soo (Naperville, IL); Johnson, Christopher S. (Naperville, IL)

    2008-01-01T23:59:59.000Z

    An uncycled electrode for a non-aqueous lithium electrochemical cell including a lithium metal oxide having the formula Li.sub.(2+2x)/(2+x)M'.sub.2x/(2+x)M.sub.(2-2x)/(2+x)O.sub.2-.delta., in which 0.ltoreq.x<1 and .delta. is less than 0.2, and in which M is a non-lithium metal ion with an average trivalent oxidation state selected from two or more of the first row transition metals or lighter metal elements in the periodic table, and M' is one or more ions with an average tetravalent oxidation state selected from the first and second row transition metal elements and Sn. Methods of preconditioning the electrodes are disclosed as are electrochemical cells and batteries containing the electrodes.

  10. CV evolution: AM Her binaries and the period gap

    E-Print Network [OSTI]

    R. F. Webbink; D. T. Wickramasinghe

    2002-04-19T23:59:59.000Z

    AM Her variables -- synchronised magnetic cataclysmic variables (CVs) -- exhibit a different period distribution from other CVs across the period gap. We show that non-AM Her systems may infiltrate the longer-period end of the period gap if they are metal-deficient, but that the position and width of the gap in orbital period is otherwise insensitive to other binary parameters (excepting the normalisation of the braking rate). In AM Her binaries, magnetic braking is reduced as the wind from the secondary star may be trapped within the magnetosphere of the white dwarf primary. This reduced braking fills the period gap from its short-period end as the dipole magnetic moment of the white dwarf increases. The consistency of these models with the observed distribution of CVs, both AM Her and non-AM Her type, provides compelling evidence supporting magnetic braking as the agent of angular momentum loss among long-period CVs, and its disruption as the explanation of the 2 - 3 hour period gap among nonmagnetic CVs.

  11. Metal-phosphate binders

    DOE Patents [OSTI]

    Howe, Beth Ann [Lewistown, IL; Chaps-Cabrera, Jesus Guadalupe [Coahuila, MX

    2009-05-12T23:59:59.000Z

    A metal-phosphate binder is provided. The binder may include an aqueous phosphoric acid solution, a metal-cation donor including a metal other than aluminum, an aluminum-cation donor, and a non-carbohydrate electron donor.

  12. Joining of parts via magnetic heating of metal aluminum powders

    DOE Patents [OSTI]

    Baker, Ian

    2013-05-21T23:59:59.000Z

    A method of joining at least two parts includes steps of dispersing a joining material comprising a multi-phase magnetic metal-aluminum powder at an interface between the at least two parts to be joined and applying an alternating magnetic field (AMF). The AMF has a magnetic field strength and frequency suitable for inducing magnetic hysteresis losses in the metal-aluminum powder and is applied for a period that raises temperature of the metal-aluminum powder to an exothermic transformation temperature. At the exothermic transformation temperature, the metal-aluminum powder melts and resolidifies as a metal aluminide solid having a non-magnetic configuration.

  13. Method of producing solution-derived metal oxide thin films

    DOE Patents [OSTI]

    Boyle, Timothy J. (Albuquerque, NM); Ingersoll, David (Albuquerque, NM)

    2000-01-01T23:59:59.000Z

    A method of preparing metal oxide thin films by a solution method. A .beta.-metal .beta.-diketonate or carboxylate compound, where the metal is selected from groups 8, 9, 10, 11, and 12 of the Periodic Table, is solubilized in a strong Lewis base to form a homogeneous solution. This precursor solution forms within minutes and can be deposited on a substrate in a single layer or a multiple layers to form a metal oxide thin film. The substrate with the deposited thin film is heated to change the film from an amorphous phase to a ceramic metal oxide and cooled.

  14. Metal Hydrides - Science Needs

    Broader source: Energy.gov (indexed) [DOE]

    with traditions in metal hydride research Metal and Ceramic Sciences Condensed Matter Physics Materials Chemistry Chemical and Biological Sciences Located on campus of Tier...

  15. Fluorescence in nonlocal dissipative periodic structures

    E-Print Network [OSTI]

    Francesco Intravaia; Kurt Busch

    2015-02-24T23:59:59.000Z

    We present an approach for the description of fluorescence from optically active material embedded in layered periodic structures. Based on an exact electromagnetic Green's tensor analysis, we determine the radiative properties of emitters such as the local photonic density of states, Lamb shifts, line widths etc. for a finite or infinite sequence of thin alternating plasmonic and dielectric layers. In the effective medium limit, these systems may exhibit hyperbolic dispersion relations so that the large wave-vector characteristics of all constituents and processes become relevant. These include the finite thickness of the layers, the nonlocal properties of the constituent metals, and local-field corrections associated with an emitter's dielectric environment. In particular, we show that the corresponding effects are non-additive and lead to considerable modifications of an emitter's luminescence properties.

  16. Hyper Space Complex Number

    E-Print Network [OSTI]

    Shanguang Tan

    2007-04-23T23:59:59.000Z

    A new kind of numbers called Hyper Space Complex Numbers and its algebras are defined and proved. It is with good properties as the classic Complex Numbers, such as expressed in coordinates, triangular and exponent forms and following the associative and commutative laws of addition and multiplication. So the classic Complex Number is developed from in complex plane with two dimensions to in complex space with N dimensions and the number system is enlarged also.

  17. High concentrations of trace metals in oysters from the Patuxent River, Maryland

    SciTech Connect (OSTI)

    Riedel, G.; Sanders, J.; Abbe, G. [Academy of Natural Sciences, St. Leonard, MD (United States). Benedict Estuarine Research Center

    1995-12-31T23:59:59.000Z

    Oyster (Crassostrea virginica) populations from the Patuxent River have been analyzed for trace metals by a number of organizations over at least the past 19 years. During that period, high concentrations of Cu (200--500 {micro}g/g dry weight), Cd (3--7 {micro}g/g) and Ag (2--8 /{micro}g/g) have been found in oysters from the oyster bars furthest up river. In particular, Cd values in oysters from this region have had concentrations approaching or exceeding current FDA warning levels throughout the period. In previous studies it was suggested that a coal-burning power plant located in that region, Chalk Point Steam Electric Station, was responsible for the copper enrichment due to the corrosion of Cu/Ni alloy condenser tubes. However, a monthly survey of trace elements in the nearby oyster populations from 1986 to the present showed only a small decline in copper concentrations after the plant switched from Cu/Ni to Ti alloy condenser tubes in 1987. Other potential sources for trace metals in the region include municipal and industrial discharges, atmospheric deposition, and biocides (anti-fouling paint in particular). The very rapid rise in trace element concentrations in oysters with position up river, and the lack of such a response by another local bivalve, the hooked mussel (Ischadium recurvum), suggests that a physiological effect of low salinity stress on oysters may be in part responsible for the high concentrations of trace metals in oysters in this region.

  18. Heavy metal biosensor

    SciTech Connect (OSTI)

    Hillson, Nathan J; Shapiro, Lucille; Hu, Ping; Andersen, Gary L

    2014-04-15T23:59:59.000Z

    Compositions and methods are provided for detection of certain heavy metals using bacterial whole cell biosensors.

  19. Representing Periodic Functions by Fourier

    E-Print Network [OSTI]

    Vickers, James

    Representing Periodic Functions by Fourier Series 23.2 Introduction In this Section we show how, then the Fourier series expansion takes the form: f(t) = a0 2 + n=1 (an cos nt + bn sin nt) Our main purpose here Fourier coefficients of a function of period 2 calculate Fourier coefficients of a function of general

  20. Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons

    DOE Patents [OSTI]

    Gordon, John Howard

    2014-09-09T23:59:59.000Z

    A method of upgrading an oil feedstock by removing heteroatoms and/or one or more heavy metals from the oil feedstock composition. This method reacts the oil feedstock with an alkali metal and an upgradant hydrocarbon. The alkali metal reacts with a portion of the heteroatoms and/or one or more heavy metals to form an inorganic phase separable from the organic oil feedstock material. The upgradant hydrocarbon bonds to the oil feedstock material and increases the number of carbon atoms in the product. This increase in the number of carbon atoms of the product increases the energy value of the resulting oil feedstock.

  1. A Liquid Metal PMI/PFC Initiative ! R. Maingi, on behalf of

    E-Print Network [OSTI]

    A Liquid Metal PMI/PFC Initiative ! R. Maingi, on behalf of a Liquid Metal PFC Working Group FESAC a number of challenges; focal area of worldwide PMI program 3 · Accepted heat flux exhaust limit for W is 5

  2. Application of quantum theory of electrons to the mechanical and thermal properties of metals 

    E-Print Network [OSTI]

    Peng, Hwan-Wu

    The first successful application of quantum mechanics to the problem of metallic cohesion was made by Wigner and Seitz (1938) They appoximated sodium metal by a number of isolated spheres of equal atomic volume and integrated, ...

  3. Method of boronizing transition metal surfaces

    DOE Patents [OSTI]

    Koyama, Koichiro; Shimotake, Hiroshi.

    1983-08-16T23:59:59.000Z

    A method is presented for preparing a boride layer on a transition metal substrate for use in corrosive environments or as a harden surface in machine applications. This method is particularly useful in treating current collectors for use within a high temperature and corrosive electrochemical cell environment. A melt of a alkali metal boride tetrafluoride salt including such as KF to lower its melting point is prepared including a dissolved boron containing material, for instance NiB, MnB[sub 2], or CrB[sub 2]. A transition metal to be coated is immersed in the melt at a temperature of no more than 700 C and a surface boride layer of that transition metal is formed within a period of about 24 hours on the substrate surface. 4 figs.

  4. Method of boronizing transition metal surfaces

    DOE Patents [OSTI]

    Koyama, Koichiro (Hyogo, JP); Shimotake, Hiroshi (Hinsdale, IL)

    1983-01-01T23:59:59.000Z

    A method is presented for preparing a boride layer on a transition metal substrate for use in corrosive environments or as a harden surface in machine applications. This method is particularly useful in treating current collectors for use within a high temperature and corrosive electrochemical cell environment. A melt of a alkali metal boride tetrafluoride salt including such as KF to lower its melting point is prepared including a dissolved boron containing material, for instance NiB, MnB.sub.2, or CrB.sub.2. A transition metal to be coated is immersed in the melt at a temperature of no more than 700.degree. C. and a surface boride layer of that transition metal is formed within a period of about 24 hours on the substrate surface.

  5. Mechanics of planar periodic microstructures

    E-Print Network [OSTI]

    Prange, Sharon M. (Sharon Marie)

    2007-01-01T23:59:59.000Z

    The deformation of two-dimensional periodically patterned elastomeric sheets has been shown to trigger interesting pattern changes that are both repeatable and predictable (Bertoldi et al., 2007). Here, both square and ...

  6. Metal-Air Batteries

    SciTech Connect (OSTI)

    Zhang, Jiguang; Bruce, Peter G.; Zhang, Gregory

    2011-08-01T23:59:59.000Z

    Metal-air batteries have much higher specific energies than most currently available primary and rechargeable batteries. Recent advances in electrode materials and electrolytes, as well as new designs on metal-air batteries, have attracted intensive effort in recent years, especially in the development of lithium-air batteries. The general principle in metal-air batteries will be reviewed in this chapter. The materials, preparation methods, and performances of metal-air batteries will be discussed. Two main metal-air batteries, Zn-air and Li-air batteries will be discussed in detail. Other type of metal-air batteries will also be described.

  7. On the Mass-Period Correlation of the Extrasolar Planets

    E-Print Network [OSTI]

    Shay Zucker; Tsevi Mazeh

    2002-02-22T23:59:59.000Z

    We report on a possible correlation between the masses and periods of the extrasolar planets, manifested as a paucity of massive planets with short orbital periods. Monte-Carlo simulations show the effect is significant, and is not solely due to an observational selection effect. We also show the effect is stronger than the one already implied by published models that assumed independent power-law distributions for the masses and periods of the extrasolar planets. Planets found in binary stellar systems may have an opposite correlation. The difference is highly significant despite the small number of planets in binary systems. We discuss the paucity of short-period massive planets in terms of some theories for the close-in giant planets. Almost all models can account for the deficit of massive planets with short periods, in particular the model that assumes migration driven by a planet-disk interaction, if the planet masses do not scale with their disk masses.

  8. Metal phthalocyanine catalysts

    DOE Patents [OSTI]

    Ellis, Jr., Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA)

    1994-01-01T23:59:59.000Z

    As a new composition of matter, alkali metal or ammonium or tetraalkylammonium diazidoperfluorophthalocyanatoferrate. Other embodiments of the invention comprise compositions wherein the metal of the coordination complex is cobalt, manganese and chromium.

  9. Liquid Metal Transformers

    E-Print Network [OSTI]

    Sheng, Lei; Liu, Jing

    2014-01-01T23:59:59.000Z

    The room temperature liquid metal is quickly emerging as an important functional material in a variety of areas like chip cooling, 3D printing or printed electronics etc. With diverse capabilities in electrical, thermal and flowing behaviors, such fluid owns many intriguing properties that had never been anticipated before. Here, we show a group of unconventional phenomena occurring on the liquid metal objects. Through applying electrical field on the liquid metals immersed in water, a series of complex transformation behaviors such as self-assembling of a sheet of liquid metal film into a single sphere, quick mergences of separate metal droplets, controlled self-rotation and planar locomotion of liquid metal objects can be realized. Meanwhile, it was also found that two accompanying water vortexes were induced and reliably swirled near the rotating liquid metal sphere. Further, effects of the shape, size, voltage, orientation and geometries of the electrodes to control the liquid metal transformers were clar...

  10. About the logic of the prime number distribution

    E-Print Network [OSTI]

    Harry K. Hahn

    2008-01-28T23:59:59.000Z

    There are two basic number sequences which play a major role in the prime number distribution. The first Number Sequence SQ1 contains all prime numbers of the form 6n+5 and the second Number Sequence SQ2 contains all prime numbers of the form 6n+1. All existing prime numbers seem to be contained in these two number sequences, except of the prime numbers 2 and 3. Riemanns Zeta Function also seems to indicate, that there is a logical connection between the mentioned number sequences and the distribution of prime numbers. This connection is indicated by lines in the diagram of the Zeta Function, which are formed by the points s where the Zeta Function is real. Another key role in the distribution of the prime numbers plays the number 5 and its periodic occurrence in the two number sequences SQ1 and SQ2. All non-prime numbers in SQ1 and SQ2 are caused by recurrences of these two number sequences with increasing wave-lengths in themselves, in a similar fashion as Overtones (harmonics) or Undertones derive from a fundamental frequency. On the contrary prime numbers represent spots in these two basic Number Sequences SQ1 and SQ2 where there is no interference caused by these recurring number sequences. The distribution of the non-prime numbers and prime numbers can be described in a graphical way with a -Wave Model- (or Interference Model) -- see Table 2.

  11. Multispecies weighted Hurwitz numbers

    E-Print Network [OSTI]

    Harnad, J

    2015-01-01T23:59:59.000Z

    The construction of hypergeometric 2D Toda $\\tau$-functions as generating functions for weighted Hurwitz numbers is extended to multispecies families. Both the enumerative geometrical significance of multispecies weighted Hurwitz numbers as weighted enumerations of branched coverings of the Riemann sphere and their combinatorial significance in terms of weighted paths in the Cayley graph of $S_n$ are derived. The particular case of multispecies quantum weighted Hurwitz numbers is studied in detail.

  12. Curvature and Tachibana numbers

    SciTech Connect (OSTI)

    Stepanov, Sergey E [Finance Academy under the Government of the Russian Federation, Moscow (Russian Federation)

    2011-07-31T23:59:59.000Z

    The aim of this paper is to define the rth Tachibana number t{sub r} of an n-dimensional compact oriented Riemannian manifold as the dimension of the space of conformally Killing r-forms, for r=1,2,...,n-1. We also describe properties of these numbers, by analogy with properties of the Betti numbers b{sub r} of a compact oriented Riemannian manifold. Bibliography: 25 titles.

  13. Durable metallized polymer mirror

    DOE Patents [OSTI]

    Schissel, Paul O. (Golden, CO); Kennedy, Cheryl E. (Lafayette, CO); Jorgensen, Gary J. (Pine, CO); Shinton, Yvonne D. (Northglenn, CO); Goggin, Rita M. (Englewood, CO)

    1994-01-01T23:59:59.000Z

    A metallized polymer mirror construction having improved durability against delamination and tunneling, comprising: an outer layer of polymeric material; a metal oxide layer underlying the outer layer of polymeric material; a silver reflective layer underneath the metal oxide layer; and a layer of adhesive attaching the silver layer to a substrate.

  14. PHYTOEXTRACTION OF HEAVY METALS

    E-Print Network [OSTI]

    Blouin-Demers, Gabriel

    Plants Chelating agents Pb hyperaccumulation Effects of pH on metal extraction Disposal options contaminants from soils Contaminants must be in harvestable portions of the plant (Wongkongkatep et al. 2003) Chelating Agents: desorb heavy metals from soil matrix and form water-soluble metal complexes (Shen et al

  15. Durable metallized polymer mirror

    DOE Patents [OSTI]

    Schissel, P.O.; Kennedy, C.E.; Jorgensen, G.J.; Shinton, Y.D.; Goggin, R.M.

    1994-11-01T23:59:59.000Z

    A metallized polymer mirror construction is disclosed having improved durability against delamination and tunneling, comprising: an outer layer of polymeric material; a metal oxide layer underlying the outer layer of polymeric material; a silver reflective layer underneath the metal oxide layer; and a layer of adhesive attaching the silver layer to a substrate. 6 figs.

  16. Ligand Intermediates in Metal-Catalyzed Reactions

    SciTech Connect (OSTI)

    Gladysz, John A.

    1999-07-31T23:59:59.000Z

    The longest-running goal of this project has been the synthesis, isolation, and physical chemical characterization of homogeneous transition metal complexes containing ligand types believed to be intermediates in the metal-catalyzed conversion of CO/H{sub 2}, CO{sub 2}, CH{sub 4}, and similar raw materials to organic fuels, feedstocks, etc. In the current project period, complexes that contain unusual new types of C{sub x}(carbide) and C{sub x}O{sub y} (carbon oxide) ligands have been emphasized. A new program in homogeneous fluorous phase catalysis has been launched as described in the final report.

  17. Definitions Numbered Space

    E-Print Network [OSTI]

    Behmer, Spencer T.

    Definitions · Numbered Space ­ a single space marked with a number and reserved for a single permit 24/7 · Unnumbered Space ­ a space which can be used by any customer allowed to park in that lot. High Low Average Question 4: If I buy a staff permit for an UNNUMBERED* space in a non-gated surface

  18. Liquid Metal Transformers

    E-Print Network [OSTI]

    Lei Sheng; Jie Zhang; Jing Liu

    2014-01-30T23:59:59.000Z

    The room temperature liquid metal is quickly emerging as an important functional material in a variety of areas like chip cooling, 3D printing or printed electronics etc. With diverse capabilities in electrical, thermal and flowing behaviors, such fluid owns many intriguing properties that had never been anticipated before. Here, we show a group of unconventional phenomena occurring on the liquid metal objects. Through applying electrical field on the liquid metals immersed in water, a series of complex transformation behaviors such as self-assembling of a sheet of liquid metal film into a single sphere, quick mergences of separate metal droplets, controlled self-rotation and planar locomotion of liquid metal objects can be realized. Meanwhile, it was also found that two accompanying water vortexes were induced and reliably swirled near the rotating liquid metal sphere. Further, effects of the shape, size, voltage, orientation and geometries of the electrodes to control the liquid metal transformers were clarified. Such events are hard to achieve otherwise on rigid metal or conventional liquid spheres. This finding has both fundamental and practical significances which suggest a generalized way of making smart soft machine, collecting discrete metal fluids, as well as flexibly manipulating liquid metal objects including accompanying devices.

  19. Lithium metal oxide electrodes for lithium batteries

    DOE Patents [OSTI]

    Thackeray, Michael M.; Johnson, Christopher S.; Amine, Khalil; Kang, Sun-Ho

    2010-06-08T23:59:59.000Z

    An uncycled preconditioned electrode for a non-aqueous lithium electrochemical cell including a lithium metal oxide having the formula xLi.sub.2-yH.sub.yO.xM'O.sub.2.(1-x)Li.sub.1-zH.sub.zMO.sub.2 in which 0metal ion with an average trivalent oxidation state selected from two or more of the first row transition metals or lighter metal elements in the periodic table, and M' is one or more ions with an average tetravalent oxidation state selected from the first and second row transition metal elements and Sn. The xLi.sub.2-yH.sub.y.xM'O.sub.2.(1-x)Li.sub.1-zH.sub.zMO.sub.2 material is prepared by preconditioning a precursor lithium metal oxide (i.e., xLi.sub.2M'O.sub.3.(1-x)LiMO.sub.2) with a proton-containing medium with a pH<7.0 containing an inorganic acid. Methods of preparing the electrodes are disclosed, as are electrochemical cells and batteries containing the electrodes.

  20. Experimental Investigations of Elastic Tail Propulsion At Low Reynolds Number

    E-Print Network [OSTI]

    Yu, Tony S.

    2007-05-04T23:59:59.000Z

    A simple way to generate propulsion at low Reynolds number is to periodically oscillate a passive flexible filament. Here we present a macroscopic experimental investigation of such a propulsive mechanism. A robotic swimmer ...

  1. Extraction process for removing metallic impurities from alkalide metals

    DOE Patents [OSTI]

    Royer, Lamar T. (Knoxville, TN)

    1988-01-01T23:59:59.000Z

    A development is described for removing metallic impurities from alkali metals by employing an extraction process wherein the metallic impurities are extracted from a molten alkali metal into molten lithium metal due to the immiscibility of the alkali metals in lithium and the miscibility of the metallic contaminants or impurities in the lithium. The purified alkali metal may be readily separated from the contaminant-containing lithium metal by simple decanting due to the differences in densities and melting temperatures of the alkali metals as compared to lithium.

  2. Total Estimated Contract Cost: Performance Period Total Fee Paid

    Office of Environmental Management (EM)

    Fee Paid 127,390,991 Contract Number: Fee Available Contract Period: Contract Type: Cost Plus Award Fee 4,104,318,749 28,500,000 31,597,837 0 39,171,018 32,871,600 EM...

  3. Periodic table for topological insulators and superconductors

    E-Print Network [OSTI]

    Alexei Kitaev

    2009-01-20T23:59:59.000Z

    Gapped phases of noninteracting fermions, with and without charge conservation and time-reversal symmetry, are classified using Bott periodicity. The symmetry and spatial dimension determines a general universality class, which corresponds to one of the 2 types of complex and 8 types of real Clifford algebras. The phases within a given class are further characterized by a topological invariant, an element of some Abelian group that can be 0, Z, or Z_2. The interface between two infinite phases with different topological numbers must carry some gapless mode. Topological properties of finite systems are described in terms of K-homology. This classification is robust with respect to disorder, provided electron states near the Fermi energy are absent or localized. In some cases (e.g., integer quantum Hall systems) the K-theoretic classification is stable to interactions, but a counterexample is also given.

  4. Metal Matrix Microencapsulated (M3) fuel neutronics performance in PWRs

    SciTech Connect (OSTI)

    Fratoni, Massimiliano [Pennsylvania State University] [Pennsylvania State University; Terrani, Kurt A [ORNL] [ORNL

    2012-01-01T23:59:59.000Z

    Metal Matrix Microencapsulated (M3) fuel consists of TRISO or BISO coated fuel particles directly dispersed in a matrix of zirconium metal to form a solid rod (Fig. 1). In this integral fuel concept the cladding tube and the failure mechanisms associated with it have been eliminated. In this manner pellet-clad-interactions (PCI), thin tube failure due to oxidation and hydriding, and tube pressurization and burst will be absent. M3 fuel, given the high stiffness of the integral rod design, could as well improve grid-to-rod wear behavior. Overall M3 fuel, compared to existing fuel designs, is expected to provide greatly improved operational performance. Multiple barriers to fission product release (ceramic coating layers in the coated fuel particle and te metal matrix) and the high thermal conductivity zirconium alloy metal matrix contribute to the enhancement in fuel behavior. The discontinuous nature of fissile material encapsulated in coated particles provides additional assistance; for instance if the M3 fuel rod is snapped into multiple pieces, only the limited number of fuel particles at the failure cross section are susceptible to release fission products. This is in contrast to the conventional oxide fuel where the presence of a small opening in the cladding provides the pathway for release of the entire inventory of fission products from the fuel rod. While conventional metal fuels (e.g. U-Zr and U-Mo) are typically expected to experience large swelling under irradiation due to the high degree of damage from fission fragments and introduction of fission gas into the lattice, this is not the case for M3 fuels. The fissile portion of the fuel is contained within the coated particle where enough room is available to accommodate fission gases and kernel swelling. The zirconium metal matrix will not be exposed to fission products and its swelling is known to be very limited when exposed solely to neutrons. Under design basis RIA and LOCA, fuel performance will be superior to the conventional oxide fuel since PCMI and rod burst, respectively, have been mitigated. Under beyond design basis accident scenarios where the fuel is exposed to high temperature steam for prolonged periods, larger inventory of zirconium metal in the core could negatively affect the accident progression. A thin steam resistant layer (e.g. alumina forming alloy steel), integrated into the solid rod during fabrication by co-extrusion or hot-isostatic-pressing, offers the potential to provide additional fuel protection from steam interaction: blanketing under a range of boiling regimes and under severe accident conditions up to high temperatures well beyond what is currently possible in the conventional fuel. A crucial aspect to the viability of M3 fuel in light water reactors is the reduced heavy metal load compared to standard pellet fuel. This study evaluated the design requirements to operate a Pressurized Water Reactor (PWR) with M3 fuel in order to obtain fuel cycle length, reactivity coefficients, and power peaking factors comparable to that of standard fuel.

  5. Down hole periodic seismic generator

    DOE Patents [OSTI]

    Hardee, Harry C. (Albuquerque, NM); Hills, Richard G. (Las Cruces, NM); Striker, Richard P. (Albuquerque, NM)

    1989-01-01T23:59:59.000Z

    A down hole periodic seismic generator system for transmitting variable frequency, predominantly shear-wave vibration into earth strata surrounding a borehole. The system comprises a unitary housing operably connected to a well head by support and electrical cabling and contains clamping apparatus for selectively clamping the housing to the walls of the borehole. The system further comprises a variable speed pneumatic oscillator and a self-contained pneumatic reservoir for producing a frequency-swept seismic output over a discrete frequency range.

  6. Advanced downhole periodic seismic generator

    DOE Patents [OSTI]

    Hardee, Harry C. (Albuquerque, NM); Hills, Richard G. (Las Cruces, NM); Striker, Richard P. (Albuquerque, NM)

    1991-07-16T23:59:59.000Z

    An advanced downhole periodic seismic generator system for transmitting variable frequency, predominantly shear-wave vibration into earth strata surrounding a borehole. The system comprises a unitary housing operably connected to a well head by support and electrical cabling and contains clamping apparatus for selectively clamping the housing to the walls of the borehole. The system further comprises a variable speed pneumatic oscillator and a self-contained pneumatic reservoir for producing a frequency-swept seismic output over a discrete frequency range.

  7. Solubility Behavior and Phase Stability of Transition Metal Oxides in Alkaline Hydrothermal Environments

    SciTech Connect (OSTI)

    S.E. Ziemniak

    2000-05-18T23:59:59.000Z

    The solubility behavior of transition metal oxides in high temperature water is interpreted by recognizing three types of chemical reaction equilibria: metal oxide hydration/dehydration, metal oxide dissolution and metal ion hydroxocomplex formation. The equilibria are quantified using thermodynamic concepts and the thermochemical properties of the metal oxides/ions representative of the most common constituents of construction metal alloys, i.e., element shaving atomic numbers between Z = 22 (Ti) and Z = 30 (Zn), are summarized on the basis of metal oxide solubility studies conducted in the laboratory. Particular attention is devoted to the uncharged metal ion hydrocomplex, M{sup Z}(OH){sub Z}(aq), since its thermochemical properties define minimum solubilities of the metal oxide at a given temperature. Experimentally-extracted values of standard partial molal entropy (S{sup 0}) for the transition metal ion neutral hydroxocomplex are shown to be influenced by ligand field stabilization energies and complex symmetry.

  8. Reactor process using metal oxide ceramic membranes

    DOE Patents [OSTI]

    Anderson, M.A.

    1994-05-03T23:59:59.000Z

    A reaction vessel for use in photoelectrochemical reactions includes as its reactive surface a metal oxide porous ceramic membrane of a catalytic metal such as titanium. The reaction vessel includes a light source and a counter electrode. A provision for applying an electrical bias between the membrane and the counter electrode permits the Fermi levels of potential reaction to be favored so that certain reactions may be favored in the vessel. The electrical biasing is also useful for the cleaning of the catalytic membrane. Also disclosed is a method regenerating a porous metal oxide ceramic membrane used in a photoelectrochemical catalytic process by periodically removing the reactants and regenerating the membrane using a variety of chemical, thermal, and electrical techniques. 2 figures.

  9. Planar resonant periodic orbits in Kuiper belt dynamics

    E-Print Network [OSTI]

    George Voyatzis; Thomas Kotoulas

    2005-02-28T23:59:59.000Z

    In the framework of the planar restricted three body problem we study a considerable number of resonances associated to the Kuiper Belt dynamics and located between 30 and 48 a.u. Our study is based on the computation of resonant periodic orbits and their stability. Stable periodic orbits are surrounded by regular librations in phase space and in such domains the capture of trans-Neptunian object is possible. All the periodic orbits found are symmetric and there is evidence for the existence of asymmetric ones only in few cases. In the present work first, second and third order resonances are under consideration. In the planar circular case we found that most of the periodic orbits are stable. The families of periodic orbits are temporarily interrupted by collisions but they continue up to relatively large values of the Jacobi constant and highly eccentric regular motion exists for all cases. In the elliptic problem and for a particular eccentricity value of the primary bodies the periodic orbits are isolated. The corresponding families, where they belong to, bifurcate from specific periodic orbits of the circular problem and seem to continue up to the rectilinear problem. Both stable and unstable orbits are obtained for each case. In the elliptic problem the unstable orbits found are associated with narrow chaotic domains in phase space. The evolution of the orbits, which are located in such chaotic domains, seems to be practically regular and bounded for long time intervals.

  10. Metal atomization spray nozzle

    DOE Patents [OSTI]

    Huxford, T.J.

    1993-11-16T23:59:59.000Z

    A spray nozzle for a magnetohydrodynamic atomization apparatus has a feed passage for molten metal and a pair of spray electrodes mounted in the feed passage. The electrodes, diverging surfaces which define a nozzle throat and diverge at an acute angle from the throat. Current passes through molten metal when fed through the throat which creates the Lorentz force necessary to provide atomization of the molten metal. 6 figures.

  11. Report number codes

    SciTech Connect (OSTI)

    Nelson, R.N. (ed.)

    1985-05-01T23:59:59.000Z

    This publication lists all report number codes processed by the Office of Scientific and Technical Information. The report codes are substantially based on the American National Standards Institute, Standard Technical Report Number (STRN)-Format and Creation Z39.23-1983. The Standard Technical Report Number (STRN) provides one of the primary methods of identifying a specific technical report. The STRN consists of two parts: The report code and the sequential number. The report code identifies the issuing organization, a specific program, or a type of document. The sequential number, which is assigned in sequence by each report issuing entity, is not included in this publication. Part I of this compilation is alphabetized by report codes followed by issuing installations. Part II lists the issuing organization followed by the assigned report code(s). In both Parts I and II, the names of issuing organizations appear for the most part in the form used at the time the reports were issued. However, for some of the more prolific installations which have had name changes, all entries have been merged under the current name.

  12. Metallomics of two microorganisms relevant to heavy metal bioremediation reveal fundamental differences in metal assimilation and utilization

    SciTech Connect (OSTI)

    Lancaster, Andrew [University of Georgia, Athens, GA] [University of Georgia, Athens, GA; Menon, Angeli [University of Georgia, Athens, GA] [University of Georgia, Athens, GA; Scott, Israel [University of Georgia, Athens, GA] [University of Georgia, Athens, GA; Poole, Farris [University of Georgia, Athens, GA] [University of Georgia, Athens, GA; Vaccaro, Brian [University of Georgia, Athens, GA] [University of Georgia, Athens, GA; Thorgersen, Michael P [ORNL] [ORNL; Geller, Jil [Lawrence Berkeley National Laboratory (LBNL)] [Lawrence Berkeley National Laboratory (LBNL); Hazen, Terry C [ORNL] [ORNL; Hurt, Jr., Richard Ashley [ORNL; Brown, Steven D [ORNL] [ORNL; Elias, Dwayne A [ORNL] [ORNL; Adams, Michael W. W. [University of Georgia, Athens, GA] [University of Georgia, Athens, GA

    2014-01-01T23:59:59.000Z

    Although as many as half of all proteins are thought to require a metal cofactor, the metalloproteomes of microorganisms remain relatively unexplored. Microorganisms from different environments are likely to vary greatly in the metals that they assimilate, not just among the metals with well-characterized roles but also those lacking any known function. Herein we investigated the metal utilization of two microorganisms that were isolated from very similar environments and are of interest because of potential roles in the immobilization of heavy metals, such as uranium and chromium. The metals assimilated and their concentrations in the cytoplasm of Desulfovibrio vulgaris strain Hildenborough (DvH) and Enterobacter cloacae strain Hanford (EcH) varied dramatically, with a larger number of metals present in Enterobacter. For example, a total of 9 and 19 metals were assimilated into their cytoplasmic fractions, respectively, and DvH did not assimilate significant amounts of zinc or copper whereas EcH assimilated both. However, bioinformatic analysis of their genome sequences revealed a comparable number of predicted metalloproteins, 813 in DvH and 953 in EcH. These allowed some rationalization of the types of metal assimilated in some cases (Fe, Cu, Mo, W, V) but not in others (Zn, Nd, Ce, Pr, Dy, Hf and Th). It was also shown that U binds an unknown soluble protein in EcH but this incorporation was the result of extracellular U binding to cytoplasmic components after cell lysis.

  13. Method for adhesion of metal films to ceramics

    DOE Patents [OSTI]

    Lowndes, D.H.; Pedraza, A.J.; DeSilva, M.J.; Kumar, R.A.

    1997-12-30T23:59:59.000Z

    Methods for making strongly bonded metal-ceramic materials are disclosed. The methods include irradiating a portion of the surface of the ceramic material with a pulsed ultraviolet laser having an energy density sufficient to effect activation of the irradiated surface of the ceramic material so that adhesion of metals subsequently deposited onto the irradiated surface is substantially increased. Advantages of the invention include (i) the need for only a small number of laser pulses at relatively low focused energy density, (ii) a smoother substrate surface, (iii) activation of the laser-treated surface which provides a chemical bond between the surface and a metal deposited thereon, (iv) only low temperature annealing is required to produce the strong metal-ceramic bond; (v) the ability to obtain strong adhesion between ceramic materials and oxidation resistant metals; (vi) ability to store the laser treated ceramic materials for later deposition of metals thereon. 7 figs.

  14. Method for adhesion of metal films to ceramics

    DOE Patents [OSTI]

    Lowndes, Douglas H. (Knoxville, TN); Pedraza, Anthony J. (Oak Ridge, TN); DeSilva, Melvin J. (Ithaca, NY); Kumar, Rajagopalan A. (Knoxville, TN)

    1997-01-01T23:59:59.000Z

    Methods for making strongly bonded metal-ceramic materials. The methods include irradiating a portion of the surface of the ceramic material with a pulsed ultraviolet laser having an energy density sufficient to effect activation of the irradiated surface of the ceramic material so that adhesion of metals subsequently deposited onto the irradiated surface is substantially increased. Advantages of the invention include (i) the need for only a small number of laser pulses at relatively low focused energy density, (ii) a smoother substrate surface, (iii) activation of the laser-treated surface which provides a chemical bond between the surface and a metal deposited thereon, (iv) only low temperature annealing is required to produce the strong metal-ceramic bond; (v) the ability to obtain strong adhesion between ceramic materials and oxidation resistant metals; (vi) ability to store the laser treated ceramic materials for later deposition of metals thereon.

  15. A number of organizations,

    E-Print Network [OSTI]

    installed solar electric systems on a number of the city's buildings, including the Chicago Center for Green Technology shown here. CityofChicago Aggregated Purchasing--A Clean Energy Strategy SOLAR TODAY Aggregated Purchasing--A Clean Energy Strategy by Lori A. Bird and Edward A. Holt #12;November/December 2002 35 Power

  16. ALARA notes, Number 8

    SciTech Connect (OSTI)

    Khan, T.A.; Baum, J.W.; Beckman, M.C. [eds.] [eds.

    1993-10-01T23:59:59.000Z

    This document contains information dealing with the lessons learned from the experience of nuclear plants. In this issue the authors tried to avoid the `tyranny` of numbers and concentrated on the main lessons learned. Topics include: filtration devices for air pollution abatement, crack repair and inspection, and remote handling equipment.

  17. Heavy Metal Humor: Reconsidering Carnival in Heavy Metal Culture

    E-Print Network [OSTI]

    Powell, Gary Botts

    2013-06-05T23:59:59.000Z

    This thesis considers Bakhtin?s carnivalesque theory by analyzing comedic rhetoric performed by two comedic metal bands. Through the theories of Johan Huizinga and Mikhail Bakhtin, Chapter I: I Play Metal argues that heavy metal culture is a modern...

  18. Regular simplex and periodic billiard orbit

    E-Print Network [OSTI]

    Bedaride, Nicolas

    2011-01-01T23:59:59.000Z

    We consider billiard inside regular simplex of $\\mathbb{R}^n$. We show the existence of two periodic trajectories. One of period $n+1$ which passes one time by each face and one of period $2n$ which passes $n$ times through one face and one time through each other face. In both cases we obtain exact coordinates for the periodic points.

  19. Transition Metal Dopants Essential for Producing Ferromagnetism...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Metal Dopants Essential for Producing Ferromagnetism in Metal Oxide Nanoparticles. Transition Metal Dopants Essential for Producing Ferromagnetism in Metal Oxide Nanoparticles....

  20. Method for producing nanostructured metal-oxides

    DOE Patents [OSTI]

    Tillotson, Thomas M.; Simpson, Randall L.; Hrubesh, Lawrence W.; Gash, Alexander

    2006-01-17T23:59:59.000Z

    A synthetic route for producing nanostructure metal-oxide-based materials using sol-gel processing. This procedure employs the use of stable and inexpensive hydrated-metal inorganic salts and environmentally friendly solvents such as water and ethanol. The synthesis involves the dissolution of the metal salt in a solvent followed by the addition of a proton scavenger, which induces gel formation in a timely manner. Both critical point (supercritical extraction) and atmospheric (low temperature evaporation) drying may be employed to produce monolithic aerogels and xerogels, respectively. Using this method synthesis of metal-oxide nanostructured materials have been carried out using inorganic salts, such as of Fe3+, Cr3+, Al3+, Ga3+, In3+, Hf4+, Sn4+, Zr4+, Nb5+, W6+, Pr3+, Er3+, Nd3+, Ce3+, U3+ and Y3+. The process is general and nanostructured metal-oxides from the following elements of the periodic table can be made: Groups 2 through 13, part of Group 14 (germanium, tin, lead), part of Group 15 (antimony, bismuth), part of Group 16 (polonium), and the lanthanides and actinides. The sol-gel processing allows for the addition of insoluble materials (e.g., metals or polymers) to the viscous sol, just before gelation, to produce a uniformly distributed nanocomposites upon gelation. As an example, energetic nanocomposites of FexOy gel with distributed Al metal are readily made. The compositions are stable, safe, and can be readily ignited to thermitic reaction.

  1. Metal roofing Shingle roofing

    E-Print Network [OSTI]

    Hutcheon, James M.

    Metal roofing panel Shingle roofing Water & ice barrier Thermal Barrier Plywood Student: Arpit between the roof and the attic. · Apply modifications to traditional roofing assembly and roofing roof with only a water barrier between the plywood and the roofing panels. Metal roofing panel Shingle

  2. Porous metallic bodies

    DOE Patents [OSTI]

    Landingham, R.L.

    1984-03-13T23:59:59.000Z

    Porous metallic bodies having a substantially uniform pore size of less than about 200 microns and a density of less than about 25 percent theoretical, as well as the method for making them, are disclosed. Group IIA, IIIB, IVB, VB, and rare earth metal hydrides a

  3. Surface Signature of Flow Past a Sphere at Moderate Reynolds Numbers

    E-Print Network [OSTI]

    Shao, Qi

    2014-04-29T23:59:59.000Z

    . The flow shows a planar symmetric pattern with vortex shedding. When Reynolds number increases to 500, the flow becomes more chaotic and loses its planar symmetry. At Reynolds number of 500, highly organized periodic surface signatures appear on the shear...

  4. Surface Signature of Flow Past a Sphere at Moderate Reynolds Numbers 

    E-Print Network [OSTI]

    Shao, Qi

    2014-04-29T23:59:59.000Z

    The incompressible viscous flow past a sphere is investigated numerically at moderate Reynolds numbers. Periodic vortex shedding happens at these Reynolds numbers. The primary objective is to identify the surface signature when the wake reaches...

  5. Production of magnesium metal

    DOE Patents [OSTI]

    Blencoe, James G. (Harriman, TN) [Harriman, TN; Anovitz, Lawrence M. (Knoxville, TN) [Knoxville, TN; Palmer, Donald A. (Oliver Springs, TN) [Oliver Springs, TN; Beard, James S. (Martinsville, VA) [Martinsville, VA

    2010-02-23T23:59:59.000Z

    A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention further relates to a process for production of magnesium metal or a magnesium compound where an external source of carbon dioxide is not used in any of the reactions of the process. The invention also relates to the magnesium metal produced by the processes described herein.

  6. Metal-Insulating-Semi-Incorporation of Silicon Nanoparticles into

    E-Print Network [OSTI]

    Foundation Research Experience for Undergraduates under grant number DMR-1063150, Renewable Energy Materials Research Science and Engineering Center under grant number DMR-0820518 and the Department of Energy SunMetal-Insulating-Semi- Conductor Incorporation of Silicon Nanoparticles into Silicon Based Solar

  7. Report Period: EIA ID NUMBER: Appendix A: Mailing Address: Appendix B:

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) - HouseholdshortEIA-782A andS FRecord U.S.

  8. Report Period: EIA ID NUMBER: Instructions: (e.g., Street Address, Bldg, Floor, Suite)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) - HouseholdshortEIA-782A andS FRecord U.S.Report

  9. Preparation of uniform nanoparticles of ultra-high purity metal oxides, mixed metal oxides, metals, and metal alloys

    DOE Patents [OSTI]

    Woodfield, Brian F.; Liu, Shengfeng; Boerio-Goates, Juliana; Liu, Qingyuan; Smith, Stacey Janel

    2012-07-03T23:59:59.000Z

    In preferred embodiments, metal nanoparticles, mixed-metal (alloy) nanoparticles, metal oxide nanoparticles and mixed-metal oxide nanoparticles are provided. According to embodiments, the nanoparticles may possess narrow size distributions and high purities. In certain preferred embodiments, methods of preparing metal nanoparticles, mixed-metal nanoparticles, metal oxide nanoparticles and mixed-metal nanoparticles are provided. These methods may provide tight control of particle size, size distribution, and oxidation state. Other preferred embodiments relate to a precursor material that may be used to form nanoparticles. In addition, products prepared from such nanoparticles are disclosed.

  10. Liquid metal electric pump

    DOE Patents [OSTI]

    Abbin, J.P.; Andraka, C.E.; Lukens, L.L.; Moreno, J.B.

    1992-01-14T23:59:59.000Z

    An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other. 3 figs.

  11. Actinide metal processing

    DOE Patents [OSTI]

    Sauer, N.N.; Watkin, J.G.

    1992-03-24T23:59:59.000Z

    A process for converting an actinide metal such as thorium, uranium, or plutonium to an actinide oxide material by admixing the actinide metal in an aqueous medium with a hypochlorite as an oxidizing agent for sufficient time to form the actinide oxide material and recovering the actinide oxide material is described together with a low temperature process for preparing an actinide oxide nitrate such as uranyl nitrate. Additionally, a composition of matter comprising the reaction product of uranium metal and sodium hypochlorite is provided, the reaction product being an essentially insoluble uranium oxide material suitable for disposal or long term storage.

  12. Actinide metal processing

    DOE Patents [OSTI]

    Sauer, Nancy N. (Los Alamos, NM); Watkin, John G. (Los Alamos, NM)

    1992-01-01T23:59:59.000Z

    A process of converting an actinide metal such as thorium, uranium, or plnium to an actinide oxide material by admixing the actinide metal in an aqueous medium with a hypochlorite as an oxidizing agent for sufficient time to form the actinide oxide material and recovering the actinide oxide material is provided together with a low temperature process of preparing an actinide oxide nitrate such as uranyl nitrte. Additionally, a composition of matter comprising the reaction product of uranium metal and sodium hypochlorite is provided, the reaction product being an essentially insoluble uranium oxide material suitable for disposal or long term storage.

  13. Transition Metal Switchable Mirror

    ScienceCinema (OSTI)

    None

    2010-01-08T23:59:59.000Z

    The switchable-mirrors technology was developed by Tom Richardson and Jonathan Slack of Berkeley Lab's Environmental Energy Technologies Division. By using transition metals rather than the rare earth metals used in the first metal-hydride switchable mirrors, Richardson and Slack were able to lower the cost and simplify the manufacturing process. Energy performance is improved as well, because the new windows can reflect or transmit both visible and infrared light. Besides windows for offices and homes, possible applications include automobile sunroofs, signs and displays, aircraft windows, and spacecraft.

  14. Transition Metal Switchable Mirror

    ScienceCinema (OSTI)

    None

    2013-05-29T23:59:59.000Z

    The switchable-mirrors technology was developed by Tom Richardson and Jonathan Slack of Berkeley Lab's Environmental Energy Technologies Division. By using transition metals rather than the rare earth metals used in the first metal-hydride switchable mirrors, Richardson and Slack were able to lower the cost and simplify the manufacturing process. Energy performance is improved as well, because the new windows can reflect or transmit both visible and infrared light. Besides windows for offices and homes, possible applications include automobile sunroofs, signs and displays, aircraft windows, and spacecraft. More information at: http://windows.lbl.gov/materials/chromogenics/default.htm

  15. Transition Metal Switchable Mirror

    SciTech Connect (OSTI)

    None

    2009-01-01T23:59:59.000Z

    The switchable-mirrors technology was developed by Tom Richardson and Jonathan Slack of Berkeley Lab's Environmental Energy Technologies Division. By using transition metals rather than the rare earth metals used in the first metal-hydride switchable mirrors, Richardson and Slack were able to lower the cost and simplify the manufacturing process. Energy performance is improved as well, because the new windows can reflect or transmit both visible and infrared light. Besides windows for offices and homes, possible applications include automobile sunroofs, signs and displays, aircraft windows, and spacecraft. More information at: http://windows.lbl.gov/materials/chromogenics/default.htm

  16. Transition Metal Switchable Mirror

    SciTech Connect (OSTI)

    2009-08-21T23:59:59.000Z

    The switchable-mirrors technology was developed by Tom Richardson and Jonathan Slack of Berkeley Lab's Environmental Energy Technologies Division. By using transition metals rather than the rare earth metals used in the first metal-hydride switchable mirrors, Richardson and Slack were able to lower the cost and simplify the manufacturing process. Energy performance is improved as well, because the new windows can reflect or transmit both visible and infrared light. Besides windows for offices and homes, possible applications include automobile sunroofs, signs and displays, aircraft windows, and spacecraft.

  17. Liquid metal electric pump

    DOE Patents [OSTI]

    Abbin, Joseph P. (Albuquerque, NM); Andraka, Charles E. (Albuquerque, NM); Lukens, Laurance L. (Albuquerque, NM); Moreno, James B. (Albuquerque, NM)

    1992-01-01T23:59:59.000Z

    An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other.

  18. Periodic Discrete Energy for Long-Range Potentials

    E-Print Network [OSTI]

    D. P. Hardin; E. B. Saff; Brian Simanek

    2014-12-11T23:59:59.000Z

    We consider periodic energy problems in Euclidean space with a special emphasis on long-range potentials that cannot be defined through the usual infinite sum. One of our main results builds on more recent developments of Ewald summation to define the periodic energy corresponding to a large class of long-range potentials. Two particularly interesting examples are the logarithmic potential and the Riesz potential when the Riesz parameter is smaller than the dimension of the space. For these examples, we use analytic continuation methods to provide concise formulas for the periodic kernel in terms of the Epstein Hurwitz Zeta function. We apply our energy definition to deduce several properties of the minimal energy including the asymptotic order of growth and the distribution of points in energy minimizing configurations as the number of points becomes large. We conclude with some detailed calculations in the case of one dimension, which shows the utility of this approach.

  19. Nonlinear resonance of superconductor/normal metal structures to microwaves E. Kandelaki,1 A. F. Volkov,1,2 K. B. Efetov,1 and V. T. Petrashov3

    E-Print Network [OSTI]

    Sheldon, Nathan D.

    Nonlinear resonance of superconductor/normal metal structures to microwaves E. Kandelaki,1 A. F.024502 PACS number s : 74.45. c, 74.50. r, 85.25.Dq, 03.67.Lx I. INTRODUCTION Superconductor/normal metal S conductance G=dj/dV of a normal metal wire in a superconductor/ normal metal heterostructure with a cross

  20. NSR Key Number Retrieval

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated CodesTransparency VisitSilver Toyota PriusNSR Key Number Retrieval Pease

  1. Lithium metal reduction of plutonium oxide to produce plutonium metal

    DOE Patents [OSTI]

    Coops, Melvin S. (Livermore, CA)

    1992-01-01T23:59:59.000Z

    A method is described for the chemical reduction of plutonium oxides to plutonium metal by the use of pure lithium metal. Lithium metal is used to reduce plutonium oxide to alpha plutonium metal (alpha-Pu). The lithium oxide by-product is reclaimed by sublimation and converted to the chloride salt, and after electrolysis, is removed as lithium metal. Zinc may be used as a solvent metal to improve thermodynamics of the reduction reaction at lower temperatures. Lithium metal reduction enables plutonium oxide reduction without the production of huge quantities of CaO--CaCl.sub.2 residues normally produced in conventional direct oxide reduction processes.

  2. Divalent metal nanoparticles

    E-Print Network [OSTI]

    DeVries, Gretchen Anne

    2008-01-01T23:59:59.000Z

    Metal nanoparticles hold promise for many scientific and technological applications, such as chemical and biological sensors, vehicles for drug delivery, and subdiffraction limit waveguides. To fabricate such devices, a ...

  3. Production of magnesium metal

    DOE Patents [OSTI]

    Blencoe, James G. (Harriman, TN); Anovitz, Lawrence M. (Knoxville, TN); Palmer, Donald A. (Oliver Springs, TN); Beard, James S. (Martinsville, VA)

    2012-04-10T23:59:59.000Z

    A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention also relates to the magnesium metal produced by the processes described herein.

  4. Functionalized Silicone Nanospheres: Synthesis, Transition Metal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Functionalized Silicone Nanospheres: Synthesis, Transition Metal Immobilization, and Catalytic Applications. Functionalized Silicone Nanospheres: Synthesis, Transition Metal...

  5. Grant Application Package CFDA Number

    E-Print Network [OSTI]

    Talley, Lynne D.

    Grant Application Package CFDA Number: Opportunity Title: Offering Agency: Agency Contact: Opportunity Open Date: Opportunity Close Date: CFDA Description: Opportunity Number: Competition ID

  6. Preparation and use of crystalline bis-monoorganic phosphonate and phosphate salts of tetravalent metals

    DOE Patents [OSTI]

    Maya, L.

    1980-06-26T23:59:59.000Z

    A method of preparing and using the crystalline organic derivatives of the tetravalent metal phosphates and phosphonates provides for the contacting of an aqueous solution of a metal nitrate, with a solution of an organophosphorus acid for a period of time at room temperature that is sufficient for the formation of a metal phosphate product, and thereafter recovering said product. According to the invention, the product of the disclosed process is used in effecting analytical separations, such as ion exchange and chromatography.

  7. Molten metal reactors

    DOE Patents [OSTI]

    Bingham, Dennis N; Klingler, Kerry M; Turner, Terry D; Wilding, Bruce M

    2013-11-05T23:59:59.000Z

    A molten metal reactor for converting a carbon material and steam into a gas comprising hydrogen, carbon monoxide, and carbon dioxide is disclosed. The reactor includes an interior crucible having a portion contained within an exterior crucible. The interior crucible includes an inlet and an outlet; the outlet leads to the exterior crucible and may comprise a diffuser. The exterior crucible may contain a molten alkaline metal compound. Contained between the exterior crucible and the interior crucible is at least one baffle.

  8. ICCM Conference, San Diego, CA July 14-18, 2003 Metallic Coil-Polymer Braid Composites

    E-Print Network [OSTI]

    Nemat-Nasser, Sia

    14th ICCM Conference, San Diego, CA July 14-18, 2003 Metallic Coil-Polymer Braid Composites: II properties and chirality effects, entitled "Metallic Coil-Polymer Braid Composites: I. Numerical Modeling of periodic arrays of conductive coils into composite materials. Such designs are analogous to fiber

  9. Grant Title: KNOWLEDGE DISSEMINATION CONFERENCE GRANTS PROGRAM ANNOUNCEMENT Funding Opportunity Number: CFDA Number(s) -93.243; Funding Opportunity Number -OA-08-002.

    E-Print Network [OSTI]

    Farritor, Shane

    Number: CFDA Number(s) - 93.243; Funding Opportunity Number - OA-08-002. Agency/Department: Department

  10. Electron-Transport in La100-Xalx Metallic Glasses

    E-Print Network [OSTI]

    DELGADO, R.; ARMBRUSTER, H.; Naugle, Donald G.; TSAI, CL; JOHNSON, WL; WILLIAMS, A.

    1986-01-01T23:59:59.000Z

    of an understanding of electron transport in liquid and amorphous transition-metal alloys. The recent review article by Naugle' discusses the most popular scattering mechanisms which have been proposed to ex- plain the systematic trends in the transport... coefficients. Gallagher and Greig had noted that the sign of the ther- mopower for a large number of amorphous transition metal alloys could be explained in terms of the Mott s d- model in which the sign of the thermopower should be the same...

  11. Sounding Number Dr. Rachel Hall

    E-Print Network [OSTI]

    Hall, Rachel W.

    searching for "drum modes vibration" and "chladni plates." (Chladni plates are lat square metal plates-generated animations. Chladni plate experiment and Chladni patterns published by John Tyndall in 1869. From the UCLA

  12. Turbulent transport phenomena in a channel with periodic rib turbulators

    SciTech Connect (OSTI)

    Liou, T.M.; Hwang, J.J.; Chen, S.H. (National Tsing Hua University, Hsinchu (Taiwan))

    1992-09-01T23:59:59.000Z

    Periodic fully developed turbulent flow in a 2D channel with rib turbulators on two opposite walls has been studied numerically and experimentally. In numerical predictions, an algebraic Reynolds stress turbulence model is adopted, and a smoothed hybrid central/skew upstream difference scheme is developed. In experiments, the laser-Doppler velocimetry and laser holographic interferometry are employed to measure the local flow and heat transfer characteristics. The results are obtained with the ratio of pitch to rib height 5, 10, 15, and 20, for Reynolds number of 3.3 x 10 exp 4 and are presented in terms of the reattachment length, mean velocity and turbulent kinetic energy profiles, isotherm patterns, and distributions of local pressure recovery and Nusselt number. A detailed comparison with experimental data shows that the present calculations have an improvement over the previous work in the prediction of periodic ribbed-wall flow and heat transfer. In addition, regions susceptible to hot spots are identified by examining the distributions of the local Nusselt number. Furthermore, the enhancement of mean Nusselt number is documented in terms of relative contributions of the increased turbulence intensity and surface area provided by the ribs. 32 refs.

  13. Method for forming metal contacts

    DOE Patents [OSTI]

    Reddington, Erik; Sutter, Thomas C; Bu, Lujia; Cannon, Alexandra; Habas, Susan E; Curtis, Calvin J; Miedaner, Alexander; Ginley, David S; Van Hest, Marinus Franciscus Antonius Maria

    2013-09-17T23:59:59.000Z

    Methods of forming metal contacts with metal inks in the manufacture of photovoltaic devices are disclosed. The metal inks are selectively deposited on semiconductor coatings by inkjet and aerosol apparatus. The composite is heated to selective temperatures where the metal inks burn through the coating to form an electrical contact with the semiconductor. Metal layers are then deposited on the electrical contacts by light induced or light assisted plating.

  14. A highly specific test for periodicity

    E-Print Network [OSTI]

    Ansmann, Gerrit

    2015-01-01T23:59:59.000Z

    We present a method that allows to distinguish between nearly periodic and strictly periodic time series. To this purpose, we employ a conservative criterion for periodicity, namely that the time series can be interpolated by a periodic function whose local extrema are also present in the time series. Our method is intended for the analysis of time series generated by deterministic dynamical systems, where it can help telling periodic dynamics from chaotic or transient ones. We empirically investigate our method's performance and compare it to an approach based on marker events (or Poincar\\'e sections). We demonstrate that our method is capable of detecting small deviations from periodicity and outperforms the marker-event-based approach in typical situations. Our method requires no adjustment of parameters to the individual time series, yields the period length with a precision that exceeds the sampling rate, and its run time grows asymptotically linear with the length of the time series.

  15. High-Temperature Zirconia Oxygen Sensor with Sealed Metal/Metal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference...

  16. Cooperative accumulation of coherent undulator radiation emitted from periodic electron bunches

    SciTech Connect (OSTI)

    Seo, Y. H. [Department of Electrophysics, Kwangwoon University, Seoul 139-701 (Korea, Republic of)

    2013-01-15T23:59:59.000Z

    Cavity build-up of coherent undulator synchrotron radiation emitted by periodic electron bunches is investigated. At the optimal off-grazing resonance, the bunch slippage relative to the radiation pulse introduces an initial transient period during which radiation accumulates cooperatively as if it is emitted by a single bunch. The power growth during the period is quadratic to the number of bunches. The number of cooperative bunches is {approx}2 Script-Small-L {sub s}{sup 2}, where Script-Small-L {sub s} denotes the slippage length in units of the resonant wavelength.

  17. Texas Rice, Volume V, Number 3

    E-Print Network [OSTI]

    . If it remains unused for extended periods of time, like 3 years, the land be- comes useless for rice farming. Moreover, industry representatives are dwindling. Farm machines, the John Deere stores, they are disap- pearing. Each year, older farmers quit or retire...Texas A&M University System Agricultural Research and Extension Center Beaumont, Texas May 2005 Volume V Number 3 Texas Rice The following is an excerpt of a speech delivered to the U.S. House of Representatives, April 28, 2005...

  18. Method of nitriding, carburizing, or oxidizing refractory metal articles using microwaves

    DOE Patents [OSTI]

    Holcombe, Cressie E. (Knoxville, TN); Dykes, Norman L. (Oak Ridge, TN); Tiegs, Terry N. (Lenoir City, TN)

    1992-01-01T23:59:59.000Z

    A method of nitriding an article of refractory-nitride-forming metal or metalloids. A consolidated metal or metalloid article is placed inside a microwave oven and nitrogen containing gas is introduced into the microwave oven. The metal or metalloid article is heated to a temperature sufficient to react the metal or metalloid with the nitrogen by applying a microwave energy within the microwave oven. The metal or metalloid article is maintained at that temperature for a period of time sufficient to convert the article of metal or metalloid to an article of refractory nitride. in addition, a method of applying a coating, such as a coating of an oxide, a carbide, or a carbo-nitride, to an article of metal or metalloid by microwave heating.

  19. Seismic isolation of two dimensional periodic foundations

    SciTech Connect (OSTI)

    Yan, Y.; Mo, Y. L., E-mail: yilungmo@central.uh.edu [University of Houston, Houston, Texas 77004 (United States); Laskar, A. [Indian Institute of Technology Bombay, Powai, Mumbai (India); Cheng, Z.; Shi, Z. [Beijing Jiaotong University, Beijing (China); Menq, F. [University of Texas, Austin, Texas 78712 (United States); Tang, Y. [Argonne National Laboratory, Argonne, Illinois 60439 (United States)

    2014-07-28T23:59:59.000Z

    Phononic crystal is now used to control acoustic waves. When the crystal goes to a larger scale, it is called periodic structure. The band gaps of the periodic structure can be reduced to range from 0.5?Hz to 50?Hz. Therefore, the periodic structure has potential applications in seismic wave reflection. In civil engineering, the periodic structure can be served as the foundation of upper structure. This type of foundation consisting of periodic structure is called periodic foundation. When the frequency of seismic waves falls into the band gaps of the periodic foundation, the seismic wave can be blocked. Field experiments of a scaled two dimensional (2D) periodic foundation with an upper structure were conducted to verify the band gap effects. Test results showed the 2D periodic foundation can effectively reduce the response of the upper structure for excitations with frequencies within the frequency band gaps. When the experimental and the finite element analysis results are compared, they agree well with each other, indicating that 2D periodic foundation is a feasible way of reducing seismic vibrations.

  20. The concrete theory of numbers: initial numbers and wonderful properties of numbers repunit

    E-Print Network [OSTI]

    Boris V. Tarasov

    2007-04-07T23:59:59.000Z

    In this work initial numbers and repunit numbers have been studied. All numbers have been considered in a decimal notation. The problem of simplicity of initial numbers has been studied. Interesting properties of numbers repunit are proved: $gcd(R_a, R_b) = R_{gcd(a,b)}$; $R_{ab}/(R_aR_b)$ is an integer only if $gcd(a,b) = 1$, where $a\\geq1$, $b\\geq1$ are integers. Dividers of numbers repunit, are researched by a degree of prime number.

  1. Nitrided Metallic Bipolar Plates

    SciTech Connect (OSTI)

    Brady, Michael P [ORNL; Tortorelli, Peter F [ORNL; Pihl, Josh A [ORNL; Toops, Todd J [ORNL; More, Karren Leslie [ORNL; Meyer III, Harry M [ORNL; Vitek, John Michael [ORNL; Wang, Heli [National Renewable Energy Laboratory (NREL); Turner, John [National Renewable Energy Laboratory (NREL); Wilson, Mahlon [Los Alamos National Laboratory (LANL); Garzon, Fernando [Los Alamos National Laboratory (LANL); Rockward, Tommy [Los Alamos National Laboratory (LANL); Connors, Dan [GenCell Corp; Rakowski, Jim [Allegheny Ludlum; Gervasio, Don [Arizona State University

    2008-01-01T23:59:59.000Z

    The objectives are: (1) Develop and optimize stainless steel alloys amenable to formation of a protective Cr-nitride surface by gas nitridation, at a sufficiently low cost to meet DOE targets and with sufficient ductility to permit manufacture by stamping. (2) Demonstrate capability of nitridation to yield high-quality stainless steel bipolar plates from thin stamped alloy foils (no significant stamped foil warping or embrittlement). (3) Demonstrate single-cell fuel cell performance of stamped and nitrided alloy foils equivalent to that of machined graphite plates of the same flow-field design ({approx}750-1,000 h, cyclic conditions, to include quantification of metal ion contamination of the membrane electrode assembly [MEA] and contact resistance increase attributable to the bipolar plates). (4) Demonstrate potential for adoption in automotive fuel cell stacks. Thin stamped metallic bipolar plates offer the potential for (1) significantly lower cost than currently-used machined graphite bipolar plates, (2) reduced weight/volume, and (3) better performance and amenability to high volume manufacture than developmental polymer/carbon fiber and graphite composite bipolar plates. However, most metals exhibit inadequate corrosion resistance in proton exchange membrane fuel cell (PEMFC) environments. This behavior leads to high electrical resistance due to the formation of surface oxides and/or contamination of the MEA by metallic ions, both of which can significantly degrade fuel cell performance. Metal nitrides offer electrical conductivities up to an order of magnitude greater than that of graphite and are highly corrosion resistant. Unfortunately, most conventional coating methods (for metal nitrides) are too expensive for PEMFC stack commercialization or tend to leave pinhole defects, which result in accelerated local corrosion and unacceptable performance.

  2. Metallic coating of microspheres

    SciTech Connect (OSTI)

    Meyer, S.F.

    1980-08-15T23:59:59.000Z

    Extremely smooth, uniform metal coatings of micrometer thicknesses on microscopic glass spheres (microspheres) are often needed as targets for inertial confinement fusion (ICF) experiments. The first part of this paper reviews those methods used successfully to provide metal coated microspheres for ICF targets, including magnetron sputtering, electro- and electroless plating, and chemical vapor pyrolysis. The second part of this paper discusses some of the critical aspects of magnetron sputter coating of microspheres, including substrate requirements, the sticking of microspheres during coating (preventing a uniform coating), and the difficulties in growing the desired dense, smooth, uniform microstructure on continuously moving spherical substrates.

  3. Hard metal composition

    DOE Patents [OSTI]

    Sheinberg, Haskell (Los Alamos, NM)

    1986-01-01T23:59:59.000Z

    A composition of matter having a Rockwell A hardness of at least 85 is formed from a precursor mixture comprising between 3 and 10 weight percent boron carbide and the remainder a metal mixture comprising from 70 to 90 percent tungsten or molybdenum, with the remainder of the metal mixture comprising nickel and iron or a mixture thereof. The composition has a relatively low density of between 7 to 14 g/cc. The precursor is preferably hot pressed to yield a composition having greater than 100% of theoretical density.

  4. Hard metal composition

    DOE Patents [OSTI]

    Sheinberg, H.

    1983-07-26T23:59:59.000Z

    A composition of matter having a Rockwell A hardness of at least 85 is formed from a precursor mixture comprising between 3 and 10 wt % boron carbide and the remainder a metal mixture comprising from 70 to 90% tungsten or molybdenum, with the remainder of the metal mixture comprising nickel and iron or a mixture thereof. The composition has a relatively low density of between 7 and 14 g/cc. The precursor is preferably hot pressed to yield a composition having greater than 100% of theoretical density.

  5. Metal alloy identifier

    DOE Patents [OSTI]

    Riley, William D. (Avondale, MD); Brown, Jr., Robert D. (Avondale, MD)

    1987-01-01T23:59:59.000Z

    To identify the composition of a metal alloy, sparks generated from the alloy are optically observed and spectrographically analyzed. The spectrographic data, in the form of a full-spectrum plot of intensity versus wavelength, provide the "signature" of the metal alloy. This signature can be compared with similar plots for alloys of known composition to establish the unknown composition by a positive match with a known alloy. An alternative method is to form intensity ratios for pairs of predetermined wavelengths within the observed spectrum and to then compare the values of such ratios with similar values for known alloy compositions, thereby to positively identify the unknown alloy composition.

  6. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengthening a solidSynthesisAppliancesTrending: Metal Oxo Bonds Print Metal

  7. Corrosion of Metal Inclusions In Bulk Vitrification Waste Packages

    SciTech Connect (OSTI)

    Bacon, Diana H.; Pierce, Eric M.; Wellman, Dawn M.; Strachan, Denis M.; Josephson, Gary B.

    2006-07-31T23:59:59.000Z

    The primary purpose of the work reported here is to analyze the potential effect of the release of technetium (Tc) from metal inclusions in bulk vitrification waste packages once they are placed in the Integrated Disposal Facility (IDF). As part of the strategy for immobilizing waste from the underground tanks at Hanford, selected wastes will be immobilized using bulk vitrification. During analyses of the glass produced in engineering-scale tests, metal inclusions were found in the glass product. This report contains the results from experiments designed to quantify the corrosion rates of metal inclusions found in the glass product from AMEC Test ES-32B and simulations designed to compare the rate of Tc release from the metal inclusions to the release of Tc from glass produced with the bulk vitrification process. In the simulations, the Tc in the metal inclusions was assumed to be released congruently during metal corrosion as soluble TcO4-. The experimental results and modeling calculations show that the metal corrosion rate will, under all conceivable conditions at the IDF, be dominated by the presence of the passivating layer and corrosion products on the metal particles. As a result, the release of Tc from the metal particles at the surfaces of fractures in the glass releases at a rate similar to the Tc present as a soluble salt. The release of the remaining Tc in the metal is controlled by the dissolution of the glass matrix. To summarize, the release of 99Tc from the BV glass within precipitated Fe is directly proportional to the diameter of the Fe particles and to the amount of precipitated Fe. However, the main contribution to the Tc release from the iron particles is over the same time period as the release of the soluble Tc salt. For the base case used in this study (0.48 mass% of 0.5 mm diameter metal particles homogeneously distributed in the BV glass), the release of 99Tc from the metal is approximately the same as the release from 0.3 mass% soluble Tc salt in the castable refractory block and it is released over the same time period as the salt. Therefore, to limit the impact of precipitated Fe on the release of 99Tc, both the amount of precipitated Fe in the BV glass and the diameter of these particles should be minimized.

  8. Wick for metal vapor laser

    DOE Patents [OSTI]

    Duncan, David B. (Livermore, CA)

    1992-01-01T23:59:59.000Z

    An improved wick for a metal vapor laser is made of a refractory metal cylinder, preferably molybdenum or tungsten for a copper laser, which provides the wicking surface. Alternately, the inside surface of the ceramic laser tube can be metalized to form the wicking surface. Capillary action is enhanced by using wire screen, porous foam metal, or grooved surfaces. Graphite or carbon, in the form of chunks, strips, fibers or particles, is placed on the inside surface of the wick to reduce water, reduce metal oxides and form metal carbides.

  9. Optimized Periodic Control of Chaotic Systems

    E-Print Network [OSTI]

    Robert Mettin; Thomas Kurz

    1995-05-09T23:59:59.000Z

    In this work, we demonstrate the open-loop control of chaotic systems by means of optimized periodic signals. The use of such signals enables us to reduce control power significantly in comparison to simple harmonic perturbations. It is found that the stabilized periodic dynamics can be changed by small, specific alterations of the control signal. Thus, low power switching between different periodic states can be achieved without feedback. The robustness of the proposed control method against noise is discussed.

  10. Method for the preparation of metal colloids in inverse micelles and product preferred by the method

    DOE Patents [OSTI]

    Wilcoxon, Jess P. (Albuquerque, NM)

    1992-01-01T23:59:59.000Z

    A method is provided for preparing catalytic elemental metal colloidal particles (e.g. gold, palladium, silver, rhodium, iridium, nickel, iron, platinum, molybdenum) or colloidal alloy particles (silver/iridium or platinum/gold). A homogeneous inverse micelle solution of a metal salt is first formed in a metal-salt solvent comprised of a surfactant (e.g. a nonionic or cationic surfactant) and an organic solvent. The size and number of inverse micelles is controlled by the proportions of the surfactant and the solvent. Then, the metal salt is reduced (by chemical reduction or by a pulsed or continuous wave UV laser) to colloidal particles of elemental metal. After their formation, the colloidal metal particles can be stabilized by reaction with materials that permanently add surface stabilizing groups to the surface of the colloidal metal particles. The sizes of the colloidal elemental metal particles and their size distribution is determined by the size and number of the inverse micelles. A second salt can be added with further reduction to form the colloidal alloy particles. After the colloidal elemental metal particles are formed, the homogeneous solution distributes to two phases, one phase rich in colloidal elemental metal particles and the other phase rich in surfactant. The colloidal elemental metal particles from one phase can be dried to form a powder useful as a catalyst. Surfactant can be recovered and recycled from the phase rich in surfactant.

  11. Pricing Conspicuous Consumption Products in Recession Periods ...

    E-Print Network [OSTI]

    2012-09-26T23:59:59.000Z

    cally used in chemical engineering, e.g., to avoid irreversible reactions in ... Our basic problem is based on an economic setting with a recession period followed.

  12. Lithium Metal Anodes for Rechargeable Batteries. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Metal Anodes for Rechargeable Batteries. Lithium Metal Anodes for Rechargeable Batteries. Abstract: Rechargeable lithium metal batteries have much higher energy density than those...

  13. Metal hydrides as electrode/catalyst materials for oxygen evolution/reduction in electrochemical devices

    DOE Patents [OSTI]

    Bugga, Ratnakumar V. (Arcadia, CA); Halpert, Gerald (Pasadena, CA); Fultz, Brent (Pasadena, CA); Witham, Charles K. (Pasadena, CA); Bowman, Robert C. (La Mesa, CA); Hightower, Adrian (Whittier, CA)

    1997-01-01T23:59:59.000Z

    An at least ternary metal alloy of the formula, AB.sub.(5-Y)X(.sub.y), is claimed. In this formula, A is selected from the rare earth elements, B is selected from the elements of groups 8, 9, and 10 of the periodic table of the elements, and X includes at least one of the following: antimony, arsenic, and bismuth. Ternary or higher-order substitutions, to the base AB.sub.5 alloys, that form strong kinetic interactions with the predominant metals in the base metal hydride are used to form metal alloys with high structural integrity after multiple cycles of hydrogen sorption.

  14. Material Safety Data Sheet Revision Number: 003.2 Issue date: 11/17/2011

    E-Print Network [OSTI]

    Rollins, Andrew M.

    : LOCTITE® ANTI-SEIZE STICK COPPER IDH number: 504468 Product type: Lubricant Item number: 37616 Region Potential Health Effects Inhalation: Inhalation of copper fumes may result in metal fume fever. Symptoms 7782-42-5 10 - 30 Mineral oil light naphthenic hydrotreat.

  15. Data Compression with Prime Numbers

    E-Print Network [OSTI]

    Gordon Chalmers

    2005-11-16T23:59:59.000Z

    A compression algorithm is presented that uses the set of prime numbers. Sequences of numbers are correlated with the prime numbers, and labeled with the integers. The algorithm can be iterated on data sets, generating factors of doubles on the compression.

  16. Metallicity and Quasar Outflows

    E-Print Network [OSTI]

    Wang, Huiyuan; Yuan, Weimin; Wang, Tinggui

    2012-01-01T23:59:59.000Z

    Correlations are investigated of the outflow strength of quasars, as measured by the blueshift and asymmetry index (BAI) of the CIV line (Wang et al. 2011), with intensities and ratios of broad emission lines, based on composite quasar spectra built from the Sloan Digital Sky Survey. We find that most of the line ratios of other ions to CIV prominently increases with BAI. These behaviors can be well understood in the context of increasing metallicity with BAI. The strength of dominant coolant, CIV line, decreases and weak collisionally excited lines increase with gas metallicity as a result of the competition between different line coolants. Using SiIV+OIV]/CIV as an indicator of gas metallicity, we present, for the first time, a strong correlation between the metallicitiy and the outflow strength of quasars over a wide range of 1.7 to 6.9 times solar abundance. Our result implies that the metallicity plays an important role in the formation of quasar outflows, likely via affecting outflow acceleration. This ...

  17. Ductile transplutonium metal alloys

    DOE Patents [OSTI]

    Conner, W.V.

    1981-10-09T23:59:59.000Z

    Alloys of Ce with transplutonium metals such as Am, Cm, Bk and Cf have properties making them highly suitable as souces of the transplutonium element, e.g., for use in radiation detector technology or as radiation sources. The alloys are ductile, homogeneous, easy to prepare and have a fairly high density.

  18. Speed of Sound in metal Speed of Sound in metal

    E-Print Network [OSTI]

    Yu, Jaehoon

    the metal rod and metal bar. 2. Acquire a metal bar or rod and measure its mass. Use the meter stick and measure and record the length in meters. Use the vernier calipers and measure the other dimensionBar Select the Smart Tool. Position the Smart tool so that the vertical line bisects the pulse. The (x

  19. Method of producing adherent metal oxide coatings on metallic surfaces

    DOE Patents [OSTI]

    Lane, Michael H. (Clifton Park, NY); Varrin, Jr., Robert D. (McLean, VA)

    2001-01-01T23:59:59.000Z

    Provided is a process of producing an adherent synthetic corrosion product (sludge) coating on metallic surfaces. The method involves a chemical reaction between a dry solid powder mixture of at least one reactive metal oxide with orthophosphoric acid to produce a coating in which the particles are bound together and the matrix is adherent to the metallic surface.

  20. Calixarene supported transition metal clusters 

    E-Print Network [OSTI]

    Taylor, Stephanie Merac

    2013-06-29T23:59:59.000Z

    This thesis describes a series of calix[n]arene polynuclear transition metal and lanthanide complexes. Calix[4]arenes possess lower-rim polyphenolic pockets that are ideal for the complexation of various transition metal ...

  1. Broadband solar absorption enhancement via periodic

    E-Print Network [OSTI]

    Province, 230009, P. R. China. Solution processed colloidal quantum dot (CQD) solar cells have greatBroadband solar absorption enhancement via periodic nanostructuring of electrodes Michael M. Adachi demonstrate a bottom- illuminated periodic nanostructured CQD solar cell that enhances broadband absorption

  2. Metallurgy Department Progress Report for the Period

    E-Print Network [OSTI]

    Dlcfc^ooWS imsm "-"' Metallurgy Department Progress Report for the Period 1 January to 31 December 1962 (Uw National Laboratory, DK-4000 Roskilde, Denmark July 1963 #12;Risø-R-486 METALLURGY DEPARTMENT PROGRESS REPORT FOR THE PERIOD 1 JANUARY TO 31 DECEMBER 1982 Abstract. The activities of the Metallurgy

  3. ON THE DIVISIBILITY BY 2 OF THE STIRLING NUMBERS OF THE SECOND KIND T. Lengyel

    E-Print Network [OSTI]

    Lengyel, Tamás

    ON THE DIVISIBILITY BY 2 OF THE STIRLING NUMBERS OF THE SECOND KIND characterize the divisibility by 2 of the Stirling number * *of the second kind, S(n, k), where n. (Here the independence follows from the periodicity of the Stirling numbers mod* *ulo any prime power

  4. ON THE DIVISIBILITY BY 2 OF THE STIRLING NUMBERS OF THE SECOND KIND

    E-Print Network [OSTI]

    Lengyel, Tamás

    ON THE DIVISIBILITY BY 2 OF THE STIRLING NUMBERS OF THE SECOND KIND T* Lengyel Occidental College characterize the divisibility by 2 of the Stirling numbers of the second kind, S(n, k), where n independence follows from the periodicity of the Stirling numbers modulo any prime power.) For k > 5

  5. Electroless metal plating of plastics

    DOE Patents [OSTI]

    Krause, Lawrence J. (Chicago, IL)

    1984-01-01T23:59:59.000Z

    Process for plating main group metals on aromatic polymers is carried out by the use of a nonaqueous solution of a salt of an alkali metal in a positive valence state and a main group metal in a negative valence state with contact between the solution and polymer providing a redox reaction causing the deposition of the main group metal and the reduction of the polymer. Products from the process exhibit useful decorative and electrical properties.

  6. Electroless metal plating of plastics

    DOE Patents [OSTI]

    Krause, L.J.

    1982-09-20T23:59:59.000Z

    Process for plating main group metals on aromatic polymers is carried out by the use of a nonaqueous solution of a salt of an alkali metal in a positive valence state and a main group metal in a negative valence state with contact between the solution and polymer providing a redox reaction causing the deposition of the main group metal and the reduction of the polymer. Products from the process exhibit useful decorative and electrical properties.

  7. Electroless metal plating of plastics

    DOE Patents [OSTI]

    Krause, Lawrence J. (Chicago, IL)

    1986-01-01T23:59:59.000Z

    Process for plating main group metals on aromatic polymers is carried out by the use of a nonaqueous solution of a salt of an alkali metal in a positive valence state and a main group metal in a negative valence state with contact between the solution and polymer providing a redox reaction causing the deposition of the main group metal and the reduction of the polymer. Products from the process exhibit useful decorative and electrical properties.

  8. Upgrading platform using alkali metals

    DOE Patents [OSTI]

    Gordon, John Howard

    2014-09-09T23:59:59.000Z

    A process for removing sulfur, nitrogen or metals from an oil feedstock (such as heavy oil, bitumen, shale oil, etc.) The method involves reacting the oil feedstock with an alkali metal and a radical capping substance. The alkali metal reacts with the metal, sulfur or nitrogen content to form one or more inorganic products and the radical capping substance reacts with the carbon and hydrogen content to form a hydrocarbon phase. The inorganic products may then be separated out from the hydrocarbon phase.

  9. Methods of recovering alkali metals

    DOE Patents [OSTI]

    Krumhansl, James L; Rigali, Mark J

    2014-03-04T23:59:59.000Z

    Approaches for alkali metal extraction, sequestration and recovery are described. For example, a method of recovering alkali metals includes providing a CST or CST-like (e.g., small pore zeolite) material. The alkali metal species is scavenged from the liquid mixture by the CST or CST-like material. The alkali metal species is extracted from the CST or CST-like material.

  10. Y-12 Development Organization technical progress report: Part 3 -- Metal processing, period ending March 1, 1994

    SciTech Connect (OSTI)

    Northcutt, W.G. Jr. [comp.

    1994-05-26T23:59:59.000Z

    As part of the effort to downsize its uranium processing facilities, the Y-12 Plant has supported an investigation to identify extraction solvents that would both work efficiently in centrifugal contactors and be disposed of easily. Various organic ethers, hydroxy ethers, ether ketones, acids, amides, and diketones were studied for their ability to extract uranyl nitrate from aqueous solutions. Although many of these solvents were obtained commercially, others had to be synthesized in-house. The authors found a large range of extraction coefficients for these solvents. Because of steric hindrance or some other factor, certain ethers performed poorly. On the other hand, various mono- and diethers of tetrahydrofurfuryl alcohol exhibited excellent extraction and stripping coefficients for uranyl nitrate, justifying purchase of a pilot plant batch of one of this family of solvents. Likewise, the authors determined the extraction coefficient for one of the two amides synthesized in-house to be quite high.

  11. Metals and Ceramics Division progress report for period ending December 31, 1992

    SciTech Connect (OSTI)

    Craig, D.F.; Weir, J.R. Jr.

    1993-04-01T23:59:59.000Z

    This report provides a brief overview of the activities and accomplishments of the division, whose purpose is to provide technical support, primarily in the area of high-temperature materials, for the various technologies being developed by US DOE. Activities range from basic research to industrial research and technology transfer. The division (and the report) is divided into the following: Engineering materials, high-temperature materials, materials science, ceramics, nuclear fuel materials, program activities, collaborative research facilities and technology transfer, and educational programs.

  12. Y-12 Development Division technical progress report. Part 3, Metal processing period ending December 1, 1992

    SciTech Connect (OSTI)

    Northcutt, W.G. Jr. [comp.

    1993-01-26T23:59:59.000Z

    Type 1020 mild steel, IF-steel{reg_sign}(registered trademark of Armco Steel Corporation, Middletown, Ohio), and TI-Namel were exposed in molten lithium hydride (LiH) at 800C for cumulative times approaching 300 h. Mild steel decarburized at an extreme rate with the affected area exhibiting tremendous grain growth. In contrast, IF-steels{reg_sign} and TI-Namel do not experience decarburization or grain growth during identical exposures to LiH. All three steels experience net weight gains during extended exposure, and the data suggest that lithium penetration into the steel is the primary source of weight gain.

  13. Photonic band structures of periodic arrays of pores in a metallic host

    E-Print Network [OSTI]

    Stroud, David

    . Scherer, O. Painter, B. D'Urso, R. Lee, and A. Yariv, "InGaAsP photonic band gap crystal membrane mi Crystal Waveguides," Phys. Rev. Lett. 77, 3787­3790 (1996). 6. O. Painter, R. K. Lee, A. Scherer, A. Yariv Spontaneous Emission in Solid-State Physics and Electronics," Phys. Rev. Lett. 58, 2059­2062 (1987). 4. A

  14. Metals and Ceramics Division progress report for period ending June 30, 1985

    SciTech Connect (OSTI)

    Not Available

    1986-01-01T23:59:59.000Z

    This progress report is divided into: engineering materials, high-temperature materials, materials science, program activities, and collaborative research facilities. Very little hard data is presented. The appendices include listings of seminars, publications, and conference papers. (DLC)

  15. Neighboring Interactions in a Periodic Plasmonic Material for Solar-Thermal Energy Conversion

    E-Print Network [OSTI]

    Musho, Terence D; Coppens, Zackary J

    2015-01-01T23:59:59.000Z

    A periodic plasmonic meta-material was studied using finite-difference time domain (FDTD) method to investigate the influence of neighboring particles on the near unity optical absorptivity. The meta-material was constructed as a silver nanoparticle (20-90nm) situated above an alumina (Al$_2$O$_3$) dielectric environment. A full parametric sweep of the particle width and the dielectric thickness was conducted. Computational results identified several resonances between the metal-dielectric and metal-air that have potential to broadening the response through stacked geometry. A significant coupled resonance between the metal-dielectric resonance and a cavity resonance between particles was capture as a function of dielectric thickness. This coupled resonance was not evident below dielectric thicknesses of 40nm and above cavity widths of 20nm. Additionally, a noticeable propagating surface plasmon polariton resonance was predicted when the particle width was half the unit cell length.

  16. Fabrication of metallic glass structures

    DOE Patents [OSTI]

    Cline, C.F.

    1983-10-20T23:59:59.000Z

    Amorphous metal powders or ribbons are fabricated into solid shapes of appreciable thickness by the application of compaction energy. The temperature regime wherein the amorphous metal deforms by viscous flow is measured. The metal powders or ribbons are compacted within the temperature regime.

  17. Integrated decontamination process for metals

    DOE Patents [OSTI]

    Snyder, Thomas S. (Oakmont, PA); Whitlow, Graham A. (Murrysville, PA)

    1991-01-01T23:59:59.000Z

    An integrated process for decontamination of metals, particularly metals that are used in the nuclear energy industry contaminated with radioactive material. The process combines the processes of electrorefining and melt refining to purify metals that can be decontaminated using either electrorefining or melt refining processes.

  18. Liquid Metal Fast Breeder Reactors: a bibliography

    SciTech Connect (OSTI)

    Raleigh, H.D. (ed.) [ed.

    1980-11-01T23:59:59.000Z

    This bibliography includes 5465 selected citations on LMFBR development. The citations were compiled from the DOE Energy Data Base covering the period January 1978 (EDB File No. 78R1087) through August 1980 (EDB File No. 80C79142). The references are to reports from the Department of Energy and its contractors, reports from other government or private organizations, and journal articles, books, conference papers, and monographs from US originators. Report citations are arranged alphanumerically by report number; nonreport literature citations are arranged chronologically. Corporate, Personal Author, Subject, and Report Number Indexes are provided in Volume 2.

  19. Liquid Metal Fast Breeder Reactors: a bibliography

    SciTech Connect (OSTI)

    Raleigh, H.D. (ed.) [ed.

    1980-11-01T23:59:59.000Z

    This bibliogralphy includes 5465 selected citations on LMFBR development. The citations were compiled from the DOE Energy Data Base covering the period January 1978 (EDB File No. 78R1087) through August 1980 (EDB File No. 80C79142). The references are to reports from the Department of Energy and its contractors, reports from other government or private organizations, and journal articles, books, conference papers, and monographs from US originators. Report citations are arranged alphanumerically by report number; nonreport literature citations are arranged chronologically. Corporate, Personal Author, Subject, and Report Number Indexes are provided in Volume 2.

  20. Transverse commensurability effect for vortices on periodic pinning arrays

    SciTech Connect (OSTI)

    Reichhardt, Charles [Los Alamos National Laboratory; Reichhardt, Cynthia J [Los Alamos National Laboratory

    2008-01-01T23:59:59.000Z

    Using computer simulations, we demonstrate a type of commensurability that occurs for vortices moving longitudinally through periodic pinning arrays in the presence of an additional transverse driving force. As a function of vortex density, there is a series of broad maxima in the transverse critical depinning force that do not fall at the matching fields where the number of vortices equals an integer multiple of the number of pinning sites. The commensurability effects are associated with dynamical states in which evenly spaced structures consisting of one or more moving rows of vortices form between rows of pinning sites. Remarkably, the critical transverse depinning force can be more than an order of magnitude larger than the longitudinal depinning force.

  1. Using Acid Number as a Leading Indicator of Refrigeration and Air Conditioning System Performance

    SciTech Connect (OSTI)

    Dennis Cartlidge; Hans Schellhase

    2003-07-31T23:59:59.000Z

    This report summarizes a literature review to assess the acidity characteristics of the older mineral oil and newer polyolester (POE) refrigeration systems as well as to evaluate acid measuring techniques used in other non-aqueous systems which may be applicable for refrigeration systems. Failure in the older chlorofluorocarbon/hydrochlorofluorocarbon (CFC/HCFC) / mineral oil systems was primarily due to thermal degradation of the refrigerant which resulted in the formation of hydrochloric and hydrofluoric acids. These are strong mineral acids, which can, over time, severely corrode the system metals and lead to the formation of copper plating on iron surfaces. The oil lubricants used in the older systems were relatively stable and were not prone to hydrolytic degradation due to the low solubility of water in oil. The refrigerants in the newer hydrofluorocarbon (HFC)/POE systems are much more thermally stable than the older CFC/HCFC refrigerants and mineral acid formation is negligible. However, acidity is produced in the new systems by hydrolytic decomposition of the POE lubricants with water to produce the parent organic acids and alcohols used to prepare the POE. The individual acids can therefore vary but they are generally C5 to C9 carboxylic acids. Organic acids are much weaker and far less corrosive to metals than the mineral acids from the older systems but they can, over long time periods, react with metals to form carboxylic metal salts. The salts tend to accumulate in narrow areas such as capillary tubes, particularly if residual hydrocarbon processing chemicals are present in the system, which can lead to plugging. The rate of acid production from POEs varies on a number of factors including chemical structure, moisture levels, temperature, acid concentration and metals. The hydrolysis rate of reaction can be reduced by using driers to reduce the free water concentration and by using scavenging chemicals which react with the system acids. Total acid number (TAN), which includes both mineral acids and organic acids, is therefore a useful indicator which can be used to monitor the condition of the system in order to perform remedial maintenance, when required, to prevent system failure. The critical TAN value is the acid level at which remedial action should be taken to prevent the onset of rapid acid formation which can result in system failure. The level of 0.05 mg KOH/g of oil was established for CFC/mineral oil systems based on analysis of 700 used lubricants from operating systems and failed units. There is no consensus within the refrigeration industry as to the critical TAN value for HFC/POE systems, however, the value will be higher than the CFC/mineral oil systems critical TAN value because of the much weaker organic acids produced from POE. A similar study of used POE lubricants should be performed to establish a critical TAN limit for POE systems. Titrimetric analysis per ASTM procedures is the most commonly used method to determine TAN values in lubricants in the refrigeration industry and other industries dealing with lubricating oils. For field measurements, acid test kits are often used since they provide rapid, semi-quantitative TAN results.

  2. Automated Immobilized Metal Affinity Chromatography System for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Immobilized Metal Affinity Chromatography System for Enrichment of Escherichia coli Phosphoproteome. Automated Immobilized Metal Affinity Chromatography System for Enrichment of...

  3. Industrially challenging separations via adsorption in metal-organic frameworks : a computational exploration 

    E-Print Network [OSTI]

    Lennox, Matthew James

    2015-06-29T23:59:59.000Z

    In recent years, metal-organic frameworks (MOFs) have been identified as promising adsorbents in a number of industrially relevant, yet challenging, separations, including the removal of propane from propane/propylene ...

  4. Spray casting of metallic preforms

    DOE Patents [OSTI]

    Flinn, John E. (Idaho Falls, ID); Burch, Joseph V. (Shelley, ID); Sears, James W. (Niskayuna, NY)

    2000-01-01T23:59:59.000Z

    A metal alloy is melted in a crucible and ejected from the bottom of the crucible as a descending stream of molten metal. The descending stream is impacted with a plurality of primary inert gas jets surrounding the molten metal stream to produce a plume of atomized molten metal droplets. An inert gas is blown onto a lower portion of the plume with a plurality of auxiliary inert gas jets to deflect the plume into a more restricted pattern of high droplet density, thereby substantially eliminating unwanted overspray and resulting wasted material. The plume is projected onto a moving substrate to form a monolithic metallic product having generally parallel sides.

  5. Functional Metal Phosphonates

    E-Print Network [OSTI]

    Perry, Houston Phillipp

    2012-02-14T23:59:59.000Z

    ......................................................... 39 12 Zr6 prepared at 205 ?C with HF as a solubilizing agent ................................ 43 13 Layered structure of Zn(O3PC6H4CN)(H2O) and Mn(O3PC6H4CN)(H2O) viewed along the c-axis. The coordinating water molecules are between... acid groups form hydrogen-bonded pairs in in Zn(O3PC6H4CO2H)(H2O) and Mn(O3PC6H4CO2H)(H2O). ..................... 55 15 Inorganic layered structure common to divalent metal phosphonates. Octahedral metal ions are coordinated by five phosphonate...

  6. FLUIDIC: Metal Air Recharged

    ScienceCinema (OSTI)

    Friesen, Cody

    2014-04-02T23:59:59.000Z

    Fluidic, with the help of ARPA-E funding, has developed and deployed the world's first proven high cycle life metal air battery. Metal air technology, often used in smaller scale devices like hearing aids, has the lowest cost per electron of any rechargeable battery storage in existence. Deploying these batteries for grid reliability is competitive with pumped hydro installations while having the advantages of a small footprint. Fluidic's battery technology allows utilities and other end users to store intermittent energy generated from solar and wind, as well as maintain reliable electrical delivery during power outages. The batteries are manufactured in the US and currently deployed to customers in emerging markets for cell tower reliability. As they continue to add customers, they've gained experience and real world data that will soon be leveraged for US grid reliability.

  7. FLUIDIC: Metal Air Recharged

    SciTech Connect (OSTI)

    Friesen, Cody

    2014-03-07T23:59:59.000Z

    Fluidic, with the help of ARPA-E funding, has developed and deployed the world's first proven high cycle life metal air battery. Metal air technology, often used in smaller scale devices like hearing aids, has the lowest cost per electron of any rechargeable battery storage in existence. Deploying these batteries for grid reliability is competitive with pumped hydro installations while having the advantages of a small footprint. Fluidic's battery technology allows utilities and other end users to store intermittent energy generated from solar and wind, as well as maintain reliable electrical delivery during power outages. The batteries are manufactured in the US and currently deployed to customers in emerging markets for cell tower reliability. As they continue to add customers, they've gained experience and real world data that will soon be leveraged for US grid reliability.

  8. Metal enrichment processes

    E-Print Network [OSTI]

    S. Schindler; A. Diaferio

    2008-01-07T23:59:59.000Z

    There are many processes that can transport gas from the galaxies to their environment and enrich the environment in this way with metals. These metal enrichment processes have a large influence on the evolution of both the galaxies and their environment. Various processes can contribute to the gas transfer: ram-pressure stripping, galactic winds, AGN outflows, galaxy-galaxy interactions and others. We review their observational evidence, corresponding simulations, their efficiencies, and their time scales as far as they are known to date. It seems that all processes can contribute to the enrichment. There is not a single process that always dominates the enrichment, because the efficiencies of the processes vary strongly with galaxy and environmental properties.

  9. Large Scale Periodicity in Redshift Distribution

    E-Print Network [OSTI]

    K. Bajan; M. Biernacka; P. Flin; W. Godlowski; V. Pervushin; A. Zorin

    2004-08-30T23:59:59.000Z

    We review the previous studies of galaxies and quasar redshifts discretisation. We present also the investigations of the large scale periodicity, detected by pencil--beam observations, which revealed 128 (1/h) Mpc period, afterwards confirmed with supercluster studies. We present the theoretical possibility of obtaining such a periodicity using a toy-model. We solved the Kepler problem, i.e. the equation of motion of a particle with null energy moving in the uniform, expanding Universe, decribed by FLRW metrics. It is possible to obtain theoretically the separation between large scale structures similar to the observed one.

  10. Variable-Period Undulators For Synchrotron Radiation

    DOE Patents [OSTI]

    Shenoy, Gopal (Naperville, IL); Lewellen, John (Plainfield, IL); Shu, Deming (Darien, IL); Vinokurov, Nikolai (Novosibirsk, RU)

    2005-02-22T23:59:59.000Z

    A new and improved undulator design is provided that enables a variable period length for the production of synchrotron radiation from both medium-energy and high-energy storage rings. The variable period length is achieved using a staggered array of pole pieces made up of high permeability material, permanent magnet material, or an electromagnetic structure. The pole pieces are separated by a variable width space. The sum of the variable width space and the pole width would therefore define the period of the undulator. Features and advantages of the invention include broad photon energy tunability, constant power operation and constant brilliance operation.

  11. DEVELOPMENT OF RASASASTRA IN MEDIEVAL PERIOD*

    E-Print Network [OSTI]

    Harishankar Sharma

    1984-01-01T23:59:59.000Z

    ABSTRACT: The paper deals with the historical development of Rasasastra in Medieval period. Knowledge of Rasa has been in existence from the time immemorial. Exploration of natural resources for the benefit of human beings is the object of this therapy. It is a medical science recognized during vedic periods for the betterment of even Devas. Medieval period can be treated as a golden age for the development of this science. Looking at its aim and objects, methodology and therapeutics, it was recognized as a medical science with an independent philosophical background in 14 th century, by Madhavacharya in his Sarva Darsana Samgraha.

  12. Waste site reclamation with recovery of radionuclides and metals

    DOE Patents [OSTI]

    Francis, Arokiasamy J. (Middle Island, NY); Dodge, Cleveland J. (Wading River, NY)

    1994-01-01T23:59:59.000Z

    A method for decontaminating radionuclides and other toxic metal-contaminate The U.S. government has certain rights in this invention pursuant to Contract Number DE-AC02-76CH00016 between the U.S. Department of Energy and Associated Universities, Inc.

  13. Waste site reclamation with recovery of radionuclides and metals

    DOE Patents [OSTI]

    Francis, A.J.; Dodge, C.J.

    1994-03-08T23:59:59.000Z

    A method for decontaminating radionuclides and other toxic metal-contaminate The U.S. government has certain rights in this invention pursuant to Contract Number DE-AC02-76CH00016 between the U.S. Department of Energy and Associated Universities, Inc.

  14. MSE 445 Corrosion of Metals -Syllabus Carl Altstetter ,

    E-Print Network [OSTI]

    Weaver, John H.

    MSE 445 Corrosion of Metals - Syllabus Carl Altstetter , 302 MSEB, 217-333-4985 Topic Page Numbers I. Introduction 1 - 39 a) costs of corrosion b) types of corrosion c) corrosion rates) batteries b) fuel cells V. Electrochemical Corrosion a) mixed potential 86-108 b) Evans diagram c) effect

  15. Corrosion protective coating for metallic materials

    DOE Patents [OSTI]

    Buchheit, Rudolph G. (Albuquerque, NM); Martinez, Michael A. (Albuquerque, NM)

    1998-01-01T23:59:59.000Z

    Corrosion protective coatings for metallic materials, particularly aluminum and aluminum alloys, produced with simple, low-cost equipment and materials other than toxic metals or metal salts, or metal cyanides. The metallic material is cleaned, degreased, and deoxidized, the surface is converted to a substantially alkaline condition, and the surface is chemically sealed with inorganic metal compounds.

  16. Corrosion protective coating for metallic materials

    DOE Patents [OSTI]

    Buchheit, R.G.; Martinez, M.A.

    1998-05-26T23:59:59.000Z

    Corrosion protective coatings for metallic materials, particularly aluminum and aluminum alloys, produced with simple, low-cost equipment and materials other than toxic metals or metal salts, or metal cyanides is disclosed. The metallic material is cleaned, degreased, and deoxidized, the surface is converted to a substantially alkaline condition, and the surface is chemically sealed with inorganic metal compounds. 1 fig.

  17. Hydrothermal alkali metal recovery process

    DOE Patents [OSTI]

    Wolfs, Denise Y. (Houston, TX); Clavenna, Le Roy R. (Baytown, TX); Eakman, James M. (Houston, TX); Kalina, Theodore (Morris Plains, NJ)

    1980-01-01T23:59:59.000Z

    In a coal gasification operation or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein solid particles containing alkali metal residues are produced, alkali metal constituents are recovered from the particles by treating them with a calcium or magnesium-containing compound in the presence of water at a temperature between about 250.degree. F. and about 700.degree. F. and in the presence of an added base to establish a pH during the treatment step that is higher than would otherwise be possible without the addition of the base. During the treating process the relatively high pH facilitates the conversion of water-insoluble alkali metal compounds in the alkali metal residues into water-soluble alkali metal constituents. The resultant aqueous solution containing water-soluble alkali metal constituents is then separated from the residue solids, which consist of the treated particles and any insoluble materials formed during the treatment step, and recycled to the gasification process where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst. Preferably, the base that is added during the treatment step is an alkali metal hydroxide obtained by water washing the residue solids produced during the treatment step.

  18. Performance testing of multi-metal continuous emissions monitors

    SciTech Connect (OSTI)

    Haas, W.J. [Ames Lab., IA (United States); French, N.B. [Sky+, Inc. (United States); Brown, C.H. [Oak Ridge National Lab., TN (United States); Burns, D.B. [Westinghouse Savannah River Co., Aiken, SC (United States); Lemieux, P.M.; Ryan, J.V. [National Risk Management Research Lab., Research Triangle Park, NC (United States); Priebe, S.J. [Idaho National Engineering and Environmental Lab., Idaho Falls, ID (United States); Waterland, L.R. [Acurex Environmental Corp. (United States)

    1997-11-17T23:59:59.000Z

    Three prototype multi-metals continuous emissions monitors (CEMs) were tested in April 1996 at the Rotary Kiln Incinerator Simulator facility at the US Environmental Protection Agency (EPA) National Risk Management Research Laboratory, Research Triangle Park, North Carolina. The CEM instruments were: Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES); Laser Induced Breakdown Spectrometry-Atomic Emission Spectroscopy (LIBS); and Laser Spark Spectrometry, another LIBS instrument. The three CEMs were tested simultaneously during test periods in which low, medium, and high concentration levels of seven toxic metals -- antimony, arsenic, beryllium, cadmium, chromium, lead, and mercury -- were maintained under carefully controlled conditions. Two methods were used to introduce the test metals into the flue gas: (1) solution atomization, introducing metal-containing aerosol directly into the secondary combustion burner, and (2) injection of fly ash particulates. The testing addressed four measures of CEM performance: relative accuracy (RA), calibration drift, zero drift, and response time. These were accomplished by comparing the toxic metal analyte concentrations reported by the CEMs to the concentrations measured using the EPA reference method (RM) for the same analytes. Overall, the test results showed the prototype nature of the test CEMs and the clear need for further development. None of the CEMs tested consistently achieved RA values of 20% or less as required by the EPA draft performance specification. Instrument size reduction and automation will also likely need additional attention before multi-metal CEMs systems become commercially available for service as envisioned by regulators and citizens.

  19. PERIODIC WAVELET TRANSFORMS AND PERIODICITY JOHN J. BENEDETTO AND GOTZ E. PFANDER

    E-Print Network [OSTI]

    Pfander, Götz

    PERIODIC WAVELET TRANSFORMS AND PERIODICITY DETECTION JOHN J. BENEDETTO AND G¨OTZ E. PFANDER Key words. Continuous wavelet transform, epileptic seizure prediction, periodicity detection algorithm, optimal generalized Haar wavelets, wavelet frames on Z. AMS subject classifications. 42C99, 42C40

  20. Single-machine scheduling with periodic and exible periodic maintenance to minimize maximum tardiness

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    periods often appear in industry due to a machine breakdown (stochastic) or preventive maintenance of machine unavailability. However, in some cases (e.g. preventive maintenance), the maintenance of a machineSingle-machine scheduling with periodic and exible periodic maintenance to minimize maximum

  1. Reduction of Metal Oxide to Metal using Ionic Liquids

    SciTech Connect (OSTI)

    Dr. Ramana Reddy

    2012-04-12T23:59:59.000Z

    A novel pathway for the high efficiency production of metal from metal oxide means of electrolysis in ionic liquids at low temperature was investigated. The main emphasis was to eliminate the use of carbon and high temperature application in the reduction of metal oxides to metals. The emphasis of this research was to produce metals such as Zn, and Pb that are normally produced by the application of very high temperatures. The reduction of zinc oxide to zinc and lead oxide to lead were investigated. This study involved three steps in accomplishing the final goal of reduction of metal oxide to metal using ionic liquids: 1) Dissolution of metal oxide in an ionic liquid, 2) Determination of reduction potential using cyclic voltammetry (CV) and 3) Reduction of the dissolved metal oxide. Ionic liquids provide additional advantage by offering a wide potential range for the deposition. In each and every step of the process, more than one process variable has been examined. Experimental results for electrochemical extraction of Zn from ZnO and Pb from PbO using eutectic mixtures of Urea ((NH2)2CO) and Choline chloride (HOC2H4N(CH3)3+Cl-) or (ChCl) in a molar ratio 2:1, varying voltage and temperatures were carried out. Fourier Transform Infra-Red (FTIR) spectroscopy studies of ionic liquids with and without metal oxide additions were conducted. FTIR and induction coupled plasma spectroscopy (ICPS) was used in the characterization of the metal oxide dissolved ionic liquid. Electrochemical experiments were conducted using EG&G potentiostat/galvanostat with three electrode cell systems. Cyclic voltammetry was used in the determination of reduction potentials for the deposition of metals. Chronoamperometric experiments were carried out in the potential range of -0.6V to -1.9V for lead and -1.4V to -1.9V for zinc. The deposits were characterized using XRD and SEM-EDS for phase, morphological and elemental analysis. The results showed that pure metal was deposited on the cathode. Successful extraction of metal from metal oxide dissolved in Urea/ChCl (2:1) was accomplished. The current efficiencies were relatively high in both the metal deposition processes with current efficiency greater than 86% for lead and 95% for zinc. This technology will advance the metal oxide reduction process by increasing the process efficiency and also eliminate the production of CO2 which makes this an environmentally benign technology for metal extraction.

  2. Compendium of Experimental Cetane Numbers

    SciTech Connect (OSTI)

    Yanowitz, J.; Ratcliff, M. A.; McCormick, R. L.; Taylor, J. D.; Murphy, M. J.

    2014-08-01T23:59:59.000Z

    This report is an updated version of the 2004 Compendium of Experimental Cetane Number Data and presents a compilation of measured cetane numbers for pure chemical compounds. It includes all available single compound cetane number data found in the scientific literature up until March 2014 as well as a number of unpublished values, most measured over the past decade at the National Renewable Energy Laboratory. This Compendium contains cetane values for 389 pure compounds, including 189 hydrocarbons and 201 oxygenates. More than 250 individual measurements are new to this version of the Compendium. For many compounds, numerous measurements are included, often collected by different researchers using different methods. Cetane number is a relative ranking of a fuel's autoignition characteristics for use in compression ignition engines; it is based on the amount of time between fuel injection and ignition, also known as ignition delay. The cetane number is typically measured either in a single-cylinder engine or a constant volume combustion chamber. Values in the previous Compendium derived from octane numbers have been removed, and replaced with a brief analysis of the correlation between cetane numbers and octane numbers. The discussion on the accuracy and precision of the most commonly used methods for measuring cetane has been expanded and the data has been annotated extensively to provide additional information that will help the reader judge the relative reliability of individual results.

  3. Radiation Induced Nanocrystal Formation in Metallic Glasses 

    E-Print Network [OSTI]

    Carter, Jesse

    2010-01-14T23:59:59.000Z

    simple system consisting of only two elements, several intermetallic compounds can exist, each with their own crystal structure (face-centered cubic, body-centered, etc), and the system gets much more complicated when the number of constituents... of Alloys and Compounds, Vol 431, Q.S. Zhang, W. Zhang, G.Q. Xie, K.S. Nakayama, H. Kimura and A. Inoue, Formation of bulk metallic glass in situ composites in Cu50Zr45Ti5 alloy, Pages 236-240, Copyright 2007, with permission from Elsevier. 16 Fig. 9...

  4. Ferromagnetic Coupling of Mononuclear Fe Centers in a Self-Assembled Metal-Organic Network on Au(111)

    E-Print Network [OSTI]

    Kuch, Wolfgang

    Grenoble, France 3 Center for Supramolecular Interactions, Freie Universita¨t Berlin, Arnimallee 14, 14195.37.Ef, 75.30.Et, 78.70.Dm As the size of a magnetic material decreases, the stabil- ity-symmetry metal-organic structures and periodic networks [9­11]. In bulk metal-organic materials, the organic

  5. Impact of Motor Failures on Payback Periods

    E-Print Network [OSTI]

    Cheek, K. F.; Pillay, P.; Dudley, K. J.

    This paper uses MotorMaster and Vaughen's Complete Price Guide to determine payback periods for different motor failure scenarios. Some scenarios considered are rewinds, reconditions, and replacement of bearings. Prices for these repairs...

  6. Enforcement Policy Statement: Compliance Period for Regional...

    Broader source: Energy.gov (indexed) [DOE]

    Compliance Period for Regional Standards Applicable to Central Air Conditioners April 24, 2014 On June 27, 2011, the U.S. Department of Energy (DOE) published in the Federal...

  7. Analytical homogenization method for periodic composite materials

    E-Print Network [OSTI]

    Chen, Ying

    We present an easy-to-implement technique for determining the effective properties of composite materials with periodic microstructures, as well as the field distributions in them. Our method is based on the transformation ...

  8. Spatial Periodic Forcing Can Displace Patterns It Is Intended to Control

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mau, Yair; Hagberg, Aric; Meron, Ehud

    2012-07-01T23:59:59.000Z

    Spatial periodic forcing of pattern-forming systems is an important, but lightly studied, method of controlling patterns. It can be used to control the amplitude and wave number of one-dimensional periodic patterns, to stabilize unstable patterns, and to induce them below instability onset. We show that, although in one spatial dimension the forcing acts to reinforce the patterns, in two dimensions it acts to destabilize or displace them by inducing two-dimensional rectangular and oblique patterns.

  9. Number

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA groupTuba City, Arizona, DisposalFourthN V O 1 8 7 +New York, New

  10. The periodicity of the eta Carinae events

    E-Print Network [OSTI]

    A. Damineli; M. F. Corcoran; D. J. Hillier; O. Stahl; R. S. Levenhagen; N. V. Leister; J. H. Groh; M. Teodoro; J. F. Albacete Colombo; F. Gonzalez; J. Arias; H. Levato; M. Grosso; N. Morrell; R. Gamen; G. Wallerstein; V. Niemela

    2007-11-27T23:59:59.000Z

    Extensive spectral observations of eta Carinae over the last cycle, and particularly around the 2003.5 low excitation event, have been obtained. The variability of both narrow and broad lines, when combined with data taken from two earlier cycles, reveal a common and well defined period. We have combined the cycle lengths derived from the many lines in the optical spectrum with those from broad-band X-rays, optical and near-infrared observations, and obtained a period length of 2022.7+-1.3 d. Spectroscopic data collected during the last 60 years yield an average period of 2020+-4 d, consistent with the present day period. The period cannot have changed by more than $\\Delta$P/P=0.0007 since 1948. This confirms the previous claims of a true, stable periodicity, and gives strong support to the binary scenario. We have used the disappearance of the narrow component of HeI 6678 to define the epoch of the Cycle 11 minimum, T_0=JD 2,452,819.8. The next event is predicted to occur on 2009 January 11 (+-2 days). The dates for the start of the minimum in other spectral features and broad-bands is very close to this date, and have well determined time delays from the HeI epoch.

  11. Brookhaven National Laboratory Number: Revision

    E-Print Network [OSTI]

    Ohta, Shigemi

    Brookhaven National Laboratory Number: Revision: PS-ESH-0057 01 Effective: Page 1 of 9 06 Chris Weilandics Signature on file Department ES&H Approval printed name Signature Date Lori Stiegler Signature on file #12;Number: PS-ESH-0057 Revision: 01 Effective: 06/08/12 Page 2 of 9 The only official

  12. ASTROBIOLOGY Volume 2, Number 4, 2002

    E-Print Network [OSTI]

    - phiphilic molecules are thought to be products of Fischer­Tropsch reactions catalyzed by metal or mineral

  13. Durability of Metallic Interconnects and Protective Coatings

    SciTech Connect (OSTI)

    Yang, Zhenguo; Stevenson, Jeffry W.

    2009-12-15T23:59:59.000Z

    To build up a useful voltage, a number of solid oxide fuel cells (SOFCs) are electrically connected into series in a stack via interconnects, which are placed between adjacent cells. In addition to functioning as a bi-polar electrical connector, the interconnect also acts as a separator plate that separates the fuel at the anode side of one cell from the air at the cathode side on an adjacent cell. During SOFC operation at the high temperatures, the interconnects are thus simultaneously exposed to the oxidizing air at one side and a reducing fuel that can be either hydrogen or hydrocarbon at the other. Besides, they are in contact with adjacent components, such as electrodes or electrical contacts, seals, etc. With steady reduction in SOFC operating temperatures into the low or intermediate range 600-850oC, oxidation resistant alloys are often used to construct interconnects. However, the metallic interconnects may degrade via interactions at their interfaces with surrounding environments or adjacent components, potentially affecting the stability and performance of interconnects and the SOFC stacks. Thus protection layers are applied to metallic interconnects that also intend to mitigate or prevent chromium migration into cells and the cell poisoning. This chapter provides a comprehensive review of materials for metallic interconnects, their degradation and coating protection.

  14. Metastable Metal Hydrides for Hydrogen Storage

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Graetz, Jason

    2012-01-01T23:59:59.000Z

    The possibility of using hydrogen as a reliable energy carrier for both stationary and mobile applications has gained renewed interest in recent years due to improvements in high temperature fuel cells and a reduction in hydrogen production costs. However, a number of challenges remain and new media are needed that are capable of safely storing hydrogen with high gravimetric and volumetric densities. Metal hydrides and complex metal hydrides offer some hope of overcoming these challenges; however, many of the high capacity “reversible” hydrides exhibit a large endothermic decomposition enthalpy making it difficult to release the hydrogen at low temperatures. Onmore »the other hand, the metastable hydrides are characterized by a low reaction enthalpy and a decomposition reaction that is thermodynamically favorable under ambient conditions. The rapid, low temperature hydrogen evolution rates that can be achieved with these materials offer much promise for mobile PEM fuel cell applications. However, a critical challenge exists to develop new methods to regenerate these hydrides directly from the reactants and hydrogen gas. This spotlight paper presents an overview of some of the metastable metal hydrides for hydrogen storage and a few new approaches being investigated to address the key challenges associated with these materials.« less

  15. Measuring the rotation period distribution of field M-dwarfs with Kepler

    E-Print Network [OSTI]

    McQuillan, Amy; Mazeh, Tsevi

    2013-01-01T23:59:59.000Z

    We have analysed 10 months of public data from the Kepler space mission to measure rotation periods of main-sequence stars with masses between 0.3 and 0.55 M_sun. To derive the rotational period we introduce the autocorrelation function and show that it is robust against phase and amplitude modulation and residual instrumental systematics. Of the 2483 stars examined, we detected rotation periods in 1570 (63.2%), representing an increase of a factor ~ 30 in the number of rotation period determination for field M-dwarfs. The periods range from 0.37-69.7 days, with amplitudes ranging from 1.0-140.8 mmags. The rotation period distribution is clearly bimodal, with peaks at ~ 19 and ~ 33 days, hinting at two distinct waves of star formation, a hypothesis that is supported by the fact that slower rotators tend to have larger proper motions. The two peaks of the rotation period distribution form two distinct sequences in period-temperature space, with the period decreasing with increasing temperature, reminiscent of ...

  16. Specific-Heat of the Organic Metal Bis(tetrathiotetracene) Tri-Iodide from 20-K to 100-K, the Vicinity of the Metal-Nonmetal Phase-Transition

    E-Print Network [OSTI]

    CORT, B.; Naugle, Donald G.

    1981-01-01T23:59:59.000Z

    selenium ana- log, the transition-metal complex KCP, ' and tetrathiofulvalenium-thiocyanate [TTF(SCN) 0588] and its selenium analog' which are similar to the organic metal studied in this work. That the metallic state is stabilized by impurities...PHYSICAL REVIEW B VOLUME 24, NUMBER 7 1 OCTOBER 1981 Specific heat of the organic metal bis(tetrathiotetracene) tri-iodide from 20 to 100 K, the vicinity of the metal-nonmetal phase transition B. Cort' and D. G. Naugle Department of Physics...

  17. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in2,EHSS A-Z Site Map OrganizationFAQTrending: Metal Oxo

  18. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in2,EHSS A-Z Site Map OrganizationFAQTrending: Metal

  19. METALS DESIGN HANDBOOK DISCLAIMER

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem Not Found Item Not Found TheHot electron dynamics in807 DE899 06 Revision 0 METALS

  20. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengthening a solidSynthesisAppliancesTrending: Metal Oxo Bonds Print

  1. Metal coupled emission process

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(FactDepartment3311, 3312), OctoberMayEnergy Metal Organic Heat Carrierscom,

  2. Multiple metals predict prolactin and thyrotropin (TSH) levels in men

    SciTech Connect (OSTI)

    Meeker, John D., E-mail: meekerj@umich.edu [Department of Environmental Health Sciences, University of Michigan School of Public Health, 6635 SPH Tower, 109 S. Observatory St., Ann Arbor, MI 48109 (United States); Rossano, Mary G. [Department of Animal and Food Sciences, University of Kentucky, Lexington, KY (United States)] [Department of Animal and Food Sciences, University of Kentucky, Lexington, KY (United States); Protas, Bridget [Department of Epidemiology, Michigan State University, East Lansing, MI (United States)] [Department of Epidemiology, Michigan State University, East Lansing, MI (United States); Diamond, Michael P.; Puscheck, Elizabeth [Department of Obstetrics and Gynecology, Wayne State University, Detroit, MI (United States)] [Department of Obstetrics and Gynecology, Wayne State University, Detroit, MI (United States); Daly, Douglas [Grand Rapids Fertility and IVF, Grand Rapids, MI (United States)] [Grand Rapids Fertility and IVF, Grand Rapids, MI (United States); Paneth, Nigel [Department of Obstetrics and Gynecology, Michigan State University, East Lansing, MI (United States)] [Department of Obstetrics and Gynecology, Michigan State University, East Lansing, MI (United States); Wirth, Julia J. [Department of Epidemiology, Michigan State University, East Lansing, MI (United States) [Department of Epidemiology, Michigan State University, East Lansing, MI (United States); Department of Obstetrics and Gynecology, Michigan State University, East Lansing, MI (United States)

    2009-10-15T23:59:59.000Z

    Exposure to a number of metals can affect neuroendocrine and thyroid signaling, which can result in adverse effects on development, behavior, metabolism, reproduction, and other functions. The present study assessed the relationship between metal concentrations in blood and serum prolactin (PRL) and thyrotropin (TSH) levels, markers of dopaminergic, and thyroid function, respectively, among men participating in a study of environmental influences on male reproductive health. Blood samples from 219 men were analyzed for concentrations of 11 metals and serum levels of PRL and TSH. In multiple linear regression models adjusted for age, BMI and smoking, PRL was inversely associated with arsenic, cadmium, copper, lead, manganese, molybdenum, and zinc, but positively associated with chromium. Several of these associations (Cd, Pb, Mo) are consistent with limited studies in humans or animals, and a number of the relationships (Cr, Cu, Pb, Mo) remained when additionally considering multiple metals in the model. Lead and copper were associated with non-monotonic decrease in TSH, while arsenic was associated with a dose-dependent increase in TSH. For arsenic these findings were consistent with recent experimental studies where arsenic inhibited enzymes involved in thyroid hormone synthesis and signaling. More research is needed for a better understanding of the role of metals in neuroendocrine and thyroid function and related health implications.

  3. Formation of in-volume nanogratings with sub-100 nm periods in glass by femtosecond laser irradiation

    E-Print Network [OSTI]

    Liao, Yang; Cui, Yun; Qiao, Lingling; Bellouard, Yves; Sugioka, Koji; Cheng, Ya

    2015-01-01T23:59:59.000Z

    We present direct experimental observation of the morphological evolution during the formation of nanogratings with sub-100-nm periods with the increasing number of pulses. Theoretical simulation shows that the constructive interference of the scattering light from original nanoplanes will create an intensity maximum located between the two adjacent nanoplanes, resulting in shortening of the nanograting period by half. The proposed mechanism enables explaining the formation of nanogratings with periods beyond that predicted by the nanoplasmonic model.

  4. Modification of Thermal Emission via Metallic Photonic Crystals

    SciTech Connect (OSTI)

    Norris, David J.; Stein, Andreas; George, Steven M.

    2012-07-30T23:59:59.000Z

    Photonic crystals are materials that are periodically structured on an optical length scale. It was previously demonstrated that the glow, or thermal emission, of tungsten photonic crystals that have a specific structure - known as the 'woodpile structure' - could be modified to reduce the amount of infrared radiation from the material. This ability has implications for improving the efficiency of thermal emission sources and for thermophotovoltaic devices. The study of this effect had been limited because the fabrication of metallic woodpile structures had previously required a complex fabrication process. In this project we pursued several approaches to simplify the fabrication of metallic photonic crystals that are useful for modification of thermal emission. First, we used the self-assembly of micrometer-scale spheres into colloidal crystals known as synthetic opals. These opals can then be infiltrated with a metal and the spheres removed to obtain a structure, known as an inverse opal, in which a three-dimensional array of bubbles is embedded in a film. Second, we used direct laser writing, in which the focus of an infrared laser is moved through a thin film of photoresist to form lines by multiphoton polymerization. Proper layering of such lines can lead to a scaffold with the woodpile structure, which can be coated with a refractory metal. Third, we explored a completely new approach to modified thermal emission - thin metal foils that contain a simple periodic surface pattern, as shown in Fig. 1. When such a foil is heated, surface plasmons are excited that propagate along the metal interface. If these waves strike the pattern, they can be converted into thermal emission with specific properties.

  5. Metal to ceramic sealed joint

    DOE Patents [OSTI]

    Lasecki, John V. (Livonia, MI); Novak, Robert F. (Farmington Hills, MI); McBride, James R. (Ypsilanti, MI)

    1991-01-01T23:59:59.000Z

    A metal to ceramic sealed joint which can withstand wide variations in temperature and maintain a good seal is provided for use in a device adapted to withstand thermal cycling from about 20 to about 1000 degrees C. The sealed joint includes a metal member, a ceramic member having an end portion, and an active metal braze forming a joint to seal the metal member to the ceramic member. The joint is positioned remote from the end portion of the ceramic member to avoid stresses at the ends or edges of the ceramic member. The sealed joint is particularly suited for use to form sealed metal to ceramic joints in a thermoelectric generator such as a sodium heat engine where a solid ceramic electrolyte is joined to metal parts in the system.

  6. Metal to ceramic sealed joint

    DOE Patents [OSTI]

    Lasecki, J.V.; Novak, R.F.; McBride, J.R.

    1991-08-27T23:59:59.000Z

    A metal to ceramic sealed joint which can withstand wide variations in temperature and maintain a good seal is provided for use in a device adapted to withstand thermal cycling from about 20 to about 1000 degrees C. The sealed joint includes a metal member, a ceramic member having an end portion, and an active metal braze forming a joint to seal the metal member to the ceramic member. The joint is positioned remote from the end portion of the ceramic member to avoid stresses at the ends or edges of the ceramic member. The sealed joint is particularly suited for use to form sealed metal to ceramic joints in a thermoelectric generator such as a sodium heat engine where a solid ceramic electrolyte is joined to metal parts in the system. 11 figures.

  7. Metals removal from spent salts

    DOE Patents [OSTI]

    Hsu, Peter C. (Pleasanton, CA); Von Holtz, Erica H. (Livermore, CA); Hipple, David L. (Livermore, CA); Summers, Leslie J. (Livermore, CA); Brummond, William A. (Livermore, CA); Adamson, Martyn G. (Danville, CA)

    2002-01-01T23:59:59.000Z

    A method and apparatus for removing metal contaminants from the spent salt of a molten salt oxidation (MSO) reactor is described. Spent salt is removed from the reactor and analyzed to determine the contaminants present and the carbonate concentration. The salt is dissolved in water, and one or more reagents may be added to precipitate the metal oxide and/or the metal as either metal oxide, metal hydroxide, or as a salt. The precipitated materials are filtered, dried and packaged for disposal as waste or can be immobilized as ceramic pellets. More than about 90% of the metals and mineral residues (ashes) present are removed by filtration. After filtration, salt solutions having a carbonate concentration >20% can be spray-dried and returned to the reactor for re-use. Salt solutions containing a carbonate concentration <20% require further clean-up using an ion exchange column, which yields salt solutions that contain less than 1.0 ppm of contaminants.

  8. Method for preparing porous metal hydride compacts

    DOE Patents [OSTI]

    Ron, M.; Gruen, D.M.; Mendelsohn, M.H.; Sheft, I.

    1980-01-21T23:59:59.000Z

    A method for preparing porous metallic-matrix hydride compacts which can be repeatedly hydrided and dehydrided without disintegration. A mixture of a finely divided metal hydride and a finely divided matrix metal is contacted with a poison which prevents the metal hydride from dehydriding at room temperature and atmospheric pressure. The mixture of matrix metal and poisoned metal hydride is then compacted under pressure at room temperature to form porous metallic-matrix hydride compacts.

  9. Method for preparing porous metal hydride compacts

    DOE Patents [OSTI]

    Ron, Moshe (Haifa, IL); Gruen, Dieter M. (Downers Grove, IL); Mendelsohn, Marshall H. (Woodridge, IL); Sheft, Irving (Oak Park, IL)

    1981-01-01T23:59:59.000Z

    A method for preparing porous metallic-matrix hydride compacts which can be repeatedly hydrided and dehydrided without disintegration. A mixture of a finely divided metal hydride and a finely divided matrix metal is contacted with a poison which prevents the metal hydride from dehydriding at room temperature and atmospheric pressure. The mixture of matrix metal and poisoned metal hydride is then compacted under pressure at room temperature to form porous metallic-matrix hydride compacts.

  10. Kepler and the long-period variables

    SciTech Connect (OSTI)

    Hartig, Erich; Lebzelter, Thomas [University of Vienna, Department of Astrophysics, Türkenschanzstrasse 17, A-1180 Vienna (Austria); Cash, Jennifer [Department of Biological and Physical Sciences, South Carolina State University, P.O. Box 7024, Orangeburg, SC 29117 (United States); Hinkle, Kenneth H.; Mighell, Kenneth J. [National Optical Astronomy Observatories, P.O. Box 26732, Tucson, AZ 85726 (United States); Walter, Donald K., E-mail: erich.hartig@univie.ac.at, E-mail: thomas.lebzelter@univie.ac.at, E-mail: jcash@physics.scsu.edu, E-mail: hinkle@noao.edu, E-mail: mighell@noao.edu, E-mail: dkw@physics.scsu.edu [Department of Biological and Physical Sciences, South Carolina State University, P.O. Box 7296, Orangeburg, SC 29117 (United States)

    2014-12-01T23:59:59.000Z

    High-precision Kepler photometry is used to explore the details of asymptotic giant branch (AGB) light curves. Since AGB variability has a typical timescale on the order of a year, we discuss at length the removal of long-term trends and quarterly changes in Kepler data. Photometry for a small sample of nine semi-regular (SR) AGB stars is examined using a 30 minute cadence over a period of 45 months. While undergoing long-period variations of many magnitudes, the light curves are shown to be smooth at the millimagnitude level over much shorter time intervals. No flares or other rapid events were detected on a sub-day timescale. The shortest AGB period detected is on the order of 100 days. All the SR variables in our sample are shown to have multiple modes. This is always the first overtone, typically combined with the fundamental. A second common characteristic of SR variables is shown to be the simultaneous excitation of multiple closely separated periods for the same overtone mode. Approximately half the sample had a much longer variation in the light curve, likely a long secondary period (LSP). The light curves were all well represented by a combination of sinusoids. However, the properties of the sinusoids are time variable, with irregular variations present at low levels. No non-radial pulsations were detected. It is argued that the LSP variation seen in many SR variables is intrinsic to the star and linked to multiple mode pulsation.

  11. Oxidation catalysts comprising metal exchanged hexaaluminate wherein the metal is Sr, Pd, La, and/or Mn

    DOE Patents [OSTI]

    Wickham, David (Boulder, CO); Cook, Ronald (Lakewood, CO)

    2008-10-28T23:59:59.000Z

    The present invention provides metal-exchanged hexaaluminate catalysts that exhibit good catalytic activity and/or stability at high temperatures for extended periods with retention of activity as combustion catalysts, and more generally as oxidation catalysts, that make them eminently suitable for use in methane combustion, particularly for use in natural gas fired gas turbines. The hexaaluminate catalysts of this invention are of particular interest for methane combustion processes for minimization of the generation of undesired levels (less than about 10 ppm) of NOx species. Metal exchanged hexaaluminate oxidation catalysts are also useful for oxidation of volatile organic compounds (VOC), particularly hydrocarbons. Metal exchanged hexaaluminate oxidation catalysts are further useful for partial oxidation, particularly at high temperatures, of reduced species, particularly hydrocarbons (alkanes and alkenes).

  12. Metal-ceramic joint assembly

    DOE Patents [OSTI]

    Li, Jian (New Milford, CT)

    2002-01-01T23:59:59.000Z

    A metal-ceramic joint assembly in which a brazing alloy is situated between metallic and ceramic members. The metallic member is either an aluminum-containing stainless steel, a high chromium-content ferritic stainless steel or an iron nickel alloy with a corrosion protection coating. The brazing alloy, in turn, is either an Au-based or Ni-based alloy with a brazing temperature in the range of 9500 to 1200.degree. C.

  13. Corrosion-resistant metal surfaces

    DOE Patents [OSTI]

    Sugama, Toshifumi (Wading River, NY)

    2009-03-24T23:59:59.000Z

    The present invention relates to metal surfaces having thereon an ultrathin (e.g., less than ten nanometer thickness) corrosion-resistant film, thereby rendering the metal surfaces corrosion-resistant. The corrosion-resistant film includes an at least partially crosslinked amido-functionalized silanol component in combination with rare-earth metal oxide nanoparticles. The invention also relates to methods for producing such corrosion-resistant films.

  14. Metal deposition using seed layers

    DOE Patents [OSTI]

    Feng, Hsein-Ping; Chen, Gang; Bo, Yu; Ren, Zhifeng; Chen, Shuo; Poudel, Bed

    2013-11-12T23:59:59.000Z

    Methods of forming a conductive metal layers on substrates are disclosed which employ a seed layer to enhance bonding, especially to smooth, low-roughness or hydrophobic substrates. In one aspect of the invention, the seed layer can be formed by applying nanoparticles onto a surface of the substrate; and the metallization is achieved by electroplating an electrically conducting metal onto the seed layer, whereby the nanoparticles serve as nucleation sites for metal deposition. In another approach, the seed layer can be formed by a self-assembling linker material, such as a sulfur-containing silane material.

  15. ``Towards Strange Metallic Holography'

    SciTech Connect (OSTI)

    Hartnoll, Sean A.; /Harvard U., Phys. Dept. /Santa Barbara, KITP /UC, Santa Barbara; Polchinski, Joseph; Silverstein, Eva; /Santa Barbara, KITP /UC, Santa Barbara; Tong, David; /Cambridge U., DAMTP /Santa Barbara, KITP /UC, Santa Barbara

    2010-08-26T23:59:59.000Z

    We initiate a holographic model building approach to 'strange metallic' phenomenology. Our model couples a neutral Lifshitz-invariant quantum critical theory, dual to a bulk gravitational background, to a finite density of gapped probe charge carriers, dually described by D-branes. In the physical regime of temperature much lower than the charge density and gap, we exhibit anomalous scalings of the temperature and frequency dependent conductivity. Choosing the dynamical critical exponent z appropriately we can match the non-Fermi liquid scalings, such as linear resistivity, observed in strange metal regimes. As part of our investigation we outline three distinct string theory realizations of Lifshitz geometries: from F theory, from polarized branes, and from a gravitating charged Fermi gas. We also identify general features of renormalization group flow in Lifshitz theories, such as the appearance of relevant charge-charge interactions when z {ge} 2. We outline a program to extend this model building approach to other anomalous observables of interest such as the Hall conductivity.

  16. Clean Metal Casting

    SciTech Connect (OSTI)

    Makhlouf M. Makhlouf; Diran Apelian

    2002-02-05T23:59:59.000Z

    The objective of this project is to develop a technology for clean metal processing that is capable of consistently providing a metal cleanliness level that is fit for a given application. The program has five tasks: Development of melt cleanliness assessment technology, development of melt contamination avoidance technology, development of high temperature phase separation technology, establishment of a correlation between the level of melt cleanliness and as cast mechanical properties, and transfer of technology to the industrial sector. Within the context of the first task, WPI has developed a standardized Reduced Pressure Test that has been endorsed by AFS as a recommended practice. In addition, within the context of task1, WPI has developed a melt cleanliness sensor based on the principles of electromagnetic separation. An industrial partner is commercializing the sensor. Within the context of the second task, WPI has developed environmentally friendly fluxes that do not contain fluorine. Within the context of the third task, WPI modeled the process of rotary degassing and verified the model predictions with experimental data. This model may be used to optimize the performance of industrial rotary degassers. Within the context of the fourth task, WPI has correlated the level of melt cleanliness at various foundries, including a sand casting foundry, a permanent mold casting foundry, and a die casting foundry, to the casting process and the resultant mechanical properties. This is useful in tailoring the melt cleansing operations at foundries to the particular casting process and the desired properties of cast components.

  17. Departmental Business Instrument Numbering System

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2000-12-05T23:59:59.000Z

    To prescribe procedures for assigning identifying numbers to all Department of Energy (DOE), including the National Nuclear Security Administration, business instruments. Cancels DOE 1331.2B. Canceled by DOE O 540.1A.

  18. Departmental Business Instrument Numbering System

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2005-01-27T23:59:59.000Z

    The Order prescribes the procedures for assigning identifying numbers to all Department of Energy (DOE) and National Nuclear Security Administration (NNSA) business instruments. Cancels DOE O 540.1. Canceled by DOE O 540.1B.

  19. The Jacobi-Stirling Numbers

    E-Print Network [OSTI]

    Andrews, George E; Gawronski, Wolfgang; Littlejohn, Lance L

    2011-01-01T23:59:59.000Z

    The Jacobi-Stirling numbers were discovered as a result of a problem involving the spectral theory of powers of the classical second-order Jacobi differential expression. Specifically, these numbers are the coefficients of integral composite powers of the Jacobi expression in Lagrangian symmetric form. Quite remarkably, they share many properties with the classical Stirling numbers of the second kind which, as shown in LW, are the coefficients of integral powers of the Laguerre differential expression. In this paper, we establish several properties of the Jacobi-Stirling numbers and its companions including combinatorial interpretations thereby extending and supplementing known contributions to the literature of Andrews-Littlejohn, Andrews-Gawronski-Littlejohn, Egge, Gelineau-Zeng, and Mongelli.

  20. In situ remediation process using divalent metal cations

    DOE Patents [OSTI]

    Brady, Patrick V.; Khandaker, Nadim R.; Krumhansl, James L.; Teter, David M.

    2004-12-14T23:59:59.000Z

    An in situ process for treating ambient solid materials (e.g., soils, aquifer solids, sludges) by adding one or more divalent metal cations to the ambient solid material. The added divalent metal cations, such as Cu.sup.2+ or Zn.sup.2+, combine with metal oxide/hydroxides (e.g., ferric oxide/hydroxide or aluminum oxide/hydroxide) already present in the ambient solid material to form an effective sorbent material having a large number of positively-charged surface complexes that binds and immobilizes anionic contaminant species (e.g., arsenic or chromate). Divalent metal cations can be added, for example, by injecting an aqueous solution of CuSO.sub.4 into an aquifer contaminated with arsenic or chromate. Also, sludges can be stabilized against leaching of anionic contaminants through the addition of divalent metal cations. Also, an inexpensive sorbent material can be easily formed by mixing divalent metal cations with soil that has been removed from the ground.

  1. Thermo-quantum diffusion in periodic potentials

    E-Print Network [OSTI]

    R. Tsekov

    2012-01-18T23:59:59.000Z

    Quantum Brownian motion in a periodic cosine potential is studied and a simple estimate of the tunneling effect is obtained in the frames of a quasi-equilibrium semiclassical approach. It is shown that the latter is applicable for heavy particles but electrons cannot be described properly since the quantum effects dominate over the thermal ones. The purely quantum electron diffusion is investigated at zero temperature and demonstrates that electrons do not obey the classical Einstein law of Brownian motion in the field of periodic potentials, since the dispersion of the wave packet increases logarithmically in time.

  2. Microfabrication of freestanding metal structures released from graphite substrates.

    SciTech Connect (OSTI)

    Makarova, O. V.; Tang, C.-M.; Mancini, D. C.; Moldovan, N.; Divan, R.; Ryding, D. G.; Lee, R. H.

    2002-02-22T23:59:59.000Z

    A sacrificial layer is usually used to release electroformed microstructures. Because of the chemistry applied to the sacrificial layer, only a limited number of metals can be used for electroforming. A novel method to fabricate freestanding electroformed copper structures is presented. A graphite substrate allows the release of the metal part, by abrasive removal of the graphite after electroforming. Results on fabrication of high-aspect-ratio freestanding copper grids are presented; these can be used as x-ray collimator in medical imaging to reduce scattered radiation. This process has potential application to the fabrication of injection molds and microparts on pick-and-place carriers for microelectromechanical systems (MEMS).

  3. Unanticipated potential cancer risk near metal recycling facilities

    SciTech Connect (OSTI)

    Raun, Loren, E-mail: raun@rice.edu [Department of Statistics, MS 138, Rice University, P.O. Box 1892, Houston, TX 77251-1892 (United States)] [Department of Statistics, MS 138, Rice University, P.O. Box 1892, Houston, TX 77251-1892 (United States); Pepple, Karl, E-mail: pepple.karl@epa.gov [State and Local Programs Group, Air Quality Policy Division, Office of Air Quality Planning and Standards, Policy, Analysis, and Communications Staff, Mail Drop C404-03, U.S. EPA, Research Triangle Park, NC 27711 (United States)] [State and Local Programs Group, Air Quality Policy Division, Office of Air Quality Planning and Standards, Policy, Analysis, and Communications Staff, Mail Drop C404-03, U.S. EPA, Research Triangle Park, NC 27711 (United States); Hoyt, Daniel, E-mail: hoyt.daniel@epa.gov [Air Surveillance Section, US EPA, Region 6, 6EN-AS, 1445 Ross Avenue, Dallas, TX 75202-2733 (United States)] [Air Surveillance Section, US EPA, Region 6, 6EN-AS, 1445 Ross Avenue, Dallas, TX 75202-2733 (United States); Richner, Donald, E-mail: Donald.Richner@houstontx.gov [Houston Department of Health and Human Services, Bureau of Pollution Control and Prevention, 7411 Park Place Blvd., Houston, TX 77087 (United States)] [Houston Department of Health and Human Services, Bureau of Pollution Control and Prevention, 7411 Park Place Blvd., Houston, TX 77087 (United States); Blanco, Arturo, E-mail: arturo.blanco@houstontx.gov [Pollution Control and Prevention, Environmental Health Division, Houston Department of Health and Human Services, 7411 Park Place Blvd., Houston, TX 77087 (United States)] [Pollution Control and Prevention, Environmental Health Division, Houston Department of Health and Human Services, 7411 Park Place Blvd., Houston, TX 77087 (United States); Li, Jiao, E-mail: jiao.li@rice.edu [Wiess School of Natural Science, Rice University, 6100 Main St., Houston, TX 77005 (United States)] [Wiess School of Natural Science, Rice University, 6100 Main St., Houston, TX 77005 (United States)

    2013-07-15T23:59:59.000Z

    Metal recycling is an important growing industry. Prior to this study, area sources consisting of metal recycling facilities fell in a category of limited regulatory scrutiny because of assumed low levels of annual emissions. Initiating with community complaints of nuisance from smoke, dust and odor, the Houston Department of Health and Human Services (HDHHS) began a monitoring program outside metal recycler facilities and found metal particulates in outdoor ambient air at levels which could pose a carcinogenic human health risk. In a study of five similar metal recycler facilities which used a torch cutting process, air downwind and outside the facility was sampled for eight hours between 6 and 10 times each over 18 months using a mobile laboratory. Ten background locations were also sampled. Iron, manganese, copper, chromium, nickel, lead, cobalt, cadmium and mercury were detected downwind of the metal recyclers at frequencies ranging from 100% of the time for iron to 2% of the time for mercury. Of these metals, chromium, nickel, lead, cobalt, cadmium and mercury were not detected in any sample in the background. Two pairs of samples were analyzed for total chromium and hexavalent chromium to establish a ratio of the fraction of hexavalent chromium in total chromium. This fraction was used to estimate hexavalent chromium at all locations. The carcinogenic risk posed to a residential receptor from metal particulate matter concentrations in the ambient air attributed to the metal recyclers was estimated from each of the five facilities in an effort to rank the importance of this source and inform the need for further investigation. The total risk from these area sources ranged from an increased cancer risk of 1 in 1,000,000 to 6 in 10,000 using the 95th upper confidence limit of the mean of the carcinogenic metal particulate matter concentration, assuming the point of the exposure is the sample location for a residential receptor after accounting for wind direction and the number of shifts that could operate a year. Further study is warranted to better understand the metal air pollution levels in the community and if necessary, to evaluate the feasibility of emission controls and identify operational improvements and best management practices for this industry. This research adds two new aspects to the literature: identification of types and magnitude of metal particulate matter air pollutants associated with a previously unrecognized area source, metal recyclers and their potential risk to health. -- Highlights: • Air monitoring study in response to community complaints found metal contamination. • Metal recyclers found to potentially pose cancer from metal particulates • Chromium, nickel, cobalt and cadmium samples were detected in five metal recyclers. • These metals were not detected in background air samples. • Estimated increased cancer risk ranges from 1 in 1,000,000 to 8 in 10,000.

  4. Metal sulfide initiators for metal oxide sorbent regeneration

    DOE Patents [OSTI]

    Turk, B.S.; Gupta, R.P.

    1999-06-22T23:59:59.000Z

    A process of regenerating a sulfided sorbent is provided. According to the process of the invention, a substantial portion of the energy necessary to initiate the regeneration reaction is provided by the combustion of a particulate metal sulfide additive. In using the particulate metal sulfide additive, the oxygen-containing gas used to regenerate the sulfided sorbent can be fed to the regeneration zone without heating or at a lower temperature than used in conventional processes wherein the regeneration reaction is initiated only by heating the oxygen-containing gas. The particulate metal sulfide additive is preferably an inexpensive mineral ore such as iron pyrite which does not adversely affect the regeneration or corresponding desulfurization reactions. The invention further includes a sorbent composition comprising the particulate metal sulfide additive in admixture with an active metal oxide sorbent capable of removing one or more sulfur compounds from a sulfur-containing gas stream. 1 fig.

  5. 5. Wavelengths and periods of field motions

    E-Print Network [OSTI]

    Finlay, Christopher

    . Using a technique based on the Radon transform [2], we determined the amount of power propagating5. Wavelengths and periods of field motions 2D frequency-wavenumber (FK) power spectra were of the large scale magnetic field at the surface of the core. Here we deconstruct such a model (gufm1

  6. Utility Building Analysis Billing Period: NOV -2013

    E-Print Network [OSTI]

    Ciocan-Fontanine, Ionut

    ELECTRICITY Consumption MUNICIPAL WATER Consumption 8 CCF STEAM Consumption CHILLED WATER Consumption GAS Building Analysis Billing Period: NOV - 2013 032 JACKSON HALL: 150,393 Square Feet ELECTRICITY Consumption,550 Square Feet ELECTRICITY Consumption 114,185 KWHRS MUNICIPAL WATER Consumption 1,423 CCF STEAM Consumption

  7. Quantum transport calculations using periodic boundaryconditions

    SciTech Connect (OSTI)

    Wang, Lin-Wang

    2004-06-15T23:59:59.000Z

    An efficient new method is presented to calculate the quantum transports using periodic boundary conditions. This method allows the use of conventional ground state ab initio programs without big changes. The computational effort is only a few times of a normal groundstate calculations, thus is makes accurate quantum transport calculations for large systems possible.

  8. Creating bulk nanocrystalline metal.

    SciTech Connect (OSTI)

    Fredenburg, D. Anthony (Georgia Institute of Technology, Atlanta, GA); Saldana, Christopher J. (Purdue University, West Lafayette, IN); Gill, David D.; Hall, Aaron Christopher; Roemer, Timothy John (Ktech Corporation, Albuquerque, NM); Vogler, Tracy John; Yang, Pin

    2008-10-01T23:59:59.000Z

    Nanocrystalline and nanostructured materials offer unique microstructure-dependent properties that are superior to coarse-grained materials. These materials have been shown to have very high hardness, strength, and wear resistance. However, most current methods of producing nanostructured materials in weapons-relevant materials create powdered metal that must be consolidated into bulk form to be useful. Conventional consolidation methods are not appropriate due to the need to maintain the nanocrystalline structure. This research investigated new ways of creating nanocrystalline material, new methods of consolidating nanocrystalline material, and an analysis of these different methods of creation and consolidation to evaluate their applicability to mesoscale weapons applications where part features are often under 100 {micro}m wide and the material's microstructure must be very small to give homogeneous properties across the feature.

  9. Expanding hollow metal rings

    DOE Patents [OSTI]

    Peacock, Harold B. (Evans, GA); Imrich, Kenneth J. (Grovetown, GA)

    2009-03-17T23:59:59.000Z

    A sealing device that may expand more planar dimensions due to internal thermal expansion of a filler material. The sealing material is of a composition such that when desired environment temperatures and internal actuating pressures are reached, the sealing materials undergoes a permanent deformation. For metallic compounds, this permanent deformation occurs when the material enters the plastic deformation phase. Polymers, and other materials, may be using a sealing mechanism depending on the temperatures and corrosivity of the use. Internal pressures are generated by either rapid thermal expansion or material phase change and may include either liquid or solid to gas phase change, or in the gaseous state with significant pressure generation in accordance with the gas laws. Sealing material thickness and material composition may be used to selectively control geometric expansion of the seal such that expansion is limited to a specific facing and or geometric plane.

  10. Metal-carbon nanostructures

    SciTech Connect (OSTI)

    Puretzky, A.A.; Hettich, R.L.; Jin, Changming; Haufler, R.E.; Compton, R.N. [Oak Ridge National Lab., TN (United States); Tuinman, A.A. [Tennessee Univ., Knoxville, TN (United States). Dept. of Chemistry

    1993-12-31T23:59:59.000Z

    Ultrafine particles formed by XeCl laser photolysis of M(CO){sub 6}, M = V, Cr, Mo, and W, have been analyzed by Fourier transform mass spectrometry and other techniques. Novel metal carbide clusters, (MoC{sub 4}){sub n}, n = 1 {minus} 4 and (WC{sub 4}){sub m}, m = 1 {minus} 8, were detected and studied. The material produced by photolysis of V(CO){sub 6} shows a series of vanadium-oxygen clusters, V{sub x}O{sub 2x+2}, x = 2 {minus} 10. No clusters of any type were detected in the photolysis product of Cr(CO){sub 6}. Structures based on the experimental evidence are proposed and discussed in light of their chemical reactivity.

  11. Nanostructured metal-polyaniline composites

    SciTech Connect (OSTI)

    Wang, Hsing-Lin (Los Alamos, NM); Li, Wenguang (Elgin, IL); Bailey, James A. (Los Alamos, NM); Gao, Yuan (Brewer, ME)

    2010-08-31T23:59:59.000Z

    Metal-polyaniline (PANI) composites are provided together with a process of preparing such composites by an electrodeless process. The metal of the composite can have nanoscale structural features and the composites can be used in applications such as catalysis for hydrogenation reactions and for analytical detection methods employing SERS.

  12. Metal recovery from porous materials

    DOE Patents [OSTI]

    Sturcken, E.F.

    1991-01-01T23:59:59.000Z

    The present invention relates to recovery of metals. More specifically, the present invention relates to the recovery of plutonium and other metals from porous materials using microwaves. The United States Government has rights in this invention pursuant to Contract No. DE-AC09-89SR18035 between the US Department of Energy and Westinghouse Savannah River Company.

  13. Synthesis metal nanoparticle

    DOE Patents [OSTI]

    Bunge, Scott D.; Boyle, Timothy J.

    2005-08-16T23:59:59.000Z

    A method for providing an anhydrous route for the synthesis of amine capped coinage-metal (copper, silver, and gold) nanoparticles (NPs) using the coinage-metal mesityl (mesityl=C.sub.6 H.sub.2 (CH.sub.3).sub.3 -2,4,6) derivatives. In this method, a solution of (Cu(C.sub.6 H.sub.2 (CH.sub.3).sub.3).sub.5, (Ag(C.sub.6 H.sub.2 (CH.sub.3).sub.3).sub.4, or (Au(C.sub.6 H.sub.2 (CH.sub.3).sub.3).sub.5 is dissolved in a coordinating solvent, such as a primary, secondary, or tertiary amine; primary, secondary, or tertiary phosphine, or alkyl thiol, to produce a mesityl precursor solution. This solution is subsequently injected into an organic solvent that is heated to a temperature greater than approximately 100.degree. C. After washing with an organic solvent, such as an alcohol (including methanol, ethanol, propanol, and higher molecular-weight alcohols), oxide free coinage NP are prepared that could be extracted with a solvent, such as an aromatic solvent (including, for example, toluene, benzene, and pyridine) or an alkane (including, for example, pentane, hexane, and heptane). Characterization by UV-Vis spectroscopy and transmission electron microscopy showed that the NPs were approximately 9.2.+-.2.3 nm in size for Cu.degree., (no surface oxide present), approximately 8.5.+-.1.1 nm Ag.degree. spheres, and approximately 8-80 nm for Au.degree..

  14. Semiclassical Estimates of Electromagnetic Casimir Self-Energies of Spherical and Cylindrical Metallic Shells

    E-Print Network [OSTI]

    Martin Schaden

    2010-06-16T23:59:59.000Z

    The leading semiclassical estimates of the electromagnetic Casimir stresses on a spherical and a cylindrical metallic shell are within 1% of the field theoretical values. The electromagnetic Casimir energy for both geometries is given by two decoupled massless scalars that satisfy conformally covariant boundary conditions. Surface contributions vanish for smooth metallic boundaries and the finite electromagnetic Casimir energy in leading semiclassical approximation is due to quadratic fluctuations about periodic rays in the interior of the cavity only. Semiclassically the non-vanishing Casimir energy of a metallic cylindrical shell is almost entirely due to Fresnel diffraction.

  15. Process for making surfactant capped metal oxide nanocrystals, and products produced by the process

    DOE Patents [OSTI]

    Alivisatos, A. Paul; Rockenberger, Joerg

    2006-01-10T23:59:59.000Z

    Disclosed is a process for making surfactant capped nanocrystals of metal oxides which are dispersable in organic solvents. The process comprises decomposing a metal cupferron complex of the formula MXCupX, wherein M is a metal, and Cup is a N-substituted N-Nitroso hydroxylamine, in the presence of a coordinating surfactant, the reaction being conducted at a temperature ranging from about 150 to about 400.degree. C., for a period of time sufficient to complete the reaction. Also disclosed are compounds made by the process.

  16. Elsevier Journal Specific Embargo Periods 2013 Journal Name Issn Embargo Period

    E-Print Network [OSTI]

    Ayala-Rincón, Mauricio

    Elsevier Journal Specific Embargo Periods 2013 Journal Name Issn Embargo Period ACADEMIC PEDIATRICS 18762859 12 ACADEMIC RADIOLOGY 10766332 12 ACC CARDIOSOURCE REVIEW JOURNAL 15568571 12 ACCIDENT ANALYSIS 18759637 24 AEROSPACE SCIENCE AND TECHNOLOGY 12709638 24 AESTHETIC SURGERY JOURNAL 1090820X 12 AESTHETISCHE

  17. Alleviation of fermi-level pinning effect at metal/germanium interface by the insertion of graphene layers

    SciTech Connect (OSTI)

    Baek, Seung-heon Chris; Seo, Yu-Jin; Oh, Joong Gun; Albert Park, Min Gyu; Bong, Jae Hoon; Yoon, Seong Jun; Lee, Seok-Hee, E-mail: seokheelee@ee.kaist.ac.kr [Department of Electrical Engineering, Korea Advanced Institute of Science and Technology (KAIST), 291 Daehak-ro, Yuseong-gu, Daejeon 305-701 (Korea, Republic of); Seo, Minsu; Park, Seung-young [Division of Materials Science, Korea Basic Science Institute (KBSI), 169-148 Daehak-ro, Yuseong-gu, Daejeon 305-333 (Korea, Republic of); Park, Byong-Guk [Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology (KAIST), 291 Daehak-ro, Yuseong-gu, Daejeon 305-701 (Korea, Republic of)

    2014-08-18T23:59:59.000Z

    In this paper, we report the alleviation of the Fermi-level pinning on metal/n-germanium (Ge) contact by the insertion of multiple layers of single-layer graphene (SLG) at the metal/n-Ge interface. A decrease in the Schottky barrier height with an increase in the number of inserted SLG layers was observed, which supports the contention that Fermi-level pinning at metal/n-Ge contact originates from the metal-induced gap states at the metal/n-Ge interface. The modulation of Schottky barrier height by varying the number of inserted SLG layers (m) can bring about the use of Ge as the next-generation complementary metal-oxide-semiconductor material. Furthermore, the inserted SLG layers can be used as the tunnel barrier for spin injection into Ge substrate for spin-based transistors.

  18. Method for preparing metal powder, device for preparing metal powder, method for processing spent nuclear fuel

    DOE Patents [OSTI]

    Park, Jong-Hee (Clarendon Hills, IL)

    2011-11-29T23:59:59.000Z

    A method for producing metal powder is provided the comprising supplying a molten bath containing a reducing agent, contacting a metal oxide with the molten bath for a time and at a temperature sufficient to reduce the metal in the metal oxide to elemental metal and produce free oxygen; and isolating the elemental metal from the molten bath.

  19. Pressure-Induced Electronic Phase Transitions Transition Metal Oxides and Rare Earth Metals

    E-Print Network [OSTI]

    Islam, M. Saif

    Pressure-Induced Electronic Phase Transitions in Transition Metal Oxides and Rare Earth Metals Metal Oxides and Rare Earth Metals by Brian Ross Maddox Electron correlation can affect profound changes transition in a transition metal monoxide. iv #12;The lanthanides (the 4f metals also known as rare-earths

  20. Modeling the glass forming ability of metals

    E-Print Network [OSTI]

    Cheney, Justin Lee

    2007-01-01T23:59:59.000Z

    compositions without rare earth metals in the Fe-Cr-Mo-C-B-Wsmall percentages of rare earth metals as the oxide formingmore, often containing rare earth metals, are among the best

  1. Superconducting ``metals'' and ``insulators'' Smitha Vishveshwara

    E-Print Network [OSTI]

    Superconducting ``metals'' and ``insulators'' Smitha Vishveshwara Department of Physics, University to the distinction between normal metals and insulators: the superconducting ``metal'' with delocalized qua- siparticle excitations and the superconducting ``insulator'' with localized quasiparticles. We describe

  2. Report/Product Number(s) DOE/ER/64701 DOE Award/Contract Number(s)

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem Not Found Item Not Foundenhancer activity than FINAL Report/Product Number(s)

  3. A Radio SETI Campaign for microsec-sec Periodic Signals

    E-Print Network [OSTI]

    Harp, G R; Astorga, Alfredo; Arbunich, Jack; Hightower, Kristin; Meitzner, Seth; Barott, W C; Nolan, Michael C; Messerschmitt, D G; Vakoch, Douglas A; Shostak, Seth; Tarter, J C

    2015-01-01T23:59:59.000Z

    We report a novel radio autocorrelation (AC) search for extraterrestrial intelligence (SETI). For selected frequencies across the terrestrial microwave window (1-10 GHz) observations were conducted at the Allen Telescope Array to identify artificial non-sinusoidal periodic signals with radio bandwidths greater than 1 kHz, which are capable of carrying substantial messages with symbol-rates from 10-10e6 Hz. Out of 243 observations, about half (101) were directed toward sources with known continuum flux greater than 1 Jy (quasars, pulsars, supernova remnants and masers), based on the hypothesis that they might harbor heretofore undiscovered natural or artificial, repetitive, phase or frequency modulation. The rest of the targets were mostly toward exoplanet stars and similarly interesting targets from the standpoint of SETI. This campaign rules out several previously untested hypotheses relating to the number of artificially modulated "natural" sources. Since we are using a phase sensitive detector, these obser...

  4. Periodic forcing of a 555-IC based hysteretic oscillator

    E-Print Network [OSTI]

    Moises Santillan

    2014-08-12T23:59:59.000Z

    In this work we designed and developed a master-slave electronic oscillatory system (based on the 555-timer IC working in the astable mode), and investigated its dynamic behavior regarding synchronization. For that purpose we measured the circulation number corresponding to the phase-locking rhythm achieved in a large set of values of the normalized forcing period (NFP) and of the coupling strength between the master and the slave oscillators. In particular we were interested in the system behavior in the strong-coupling limit, because such problem has not been extensively studied from an experimental perspective. Our results indicate the existence of a degenerate codimension-2 bifurcation point at NFP=1:2, where all the phase-locking regions converge in the very strong coupling limit. These findings were corroborated by a mathematical model we developed to that end.

  5. Cosmic metal production and the mean metallicity of the Universe

    E-Print Network [OSTI]

    F. Calura; F. Matteucci

    2004-03-08T23:59:59.000Z

    By means of detailed chemo-photometric models for elliptical, spiral and irregular galaxies, we evaluate the cosmic history of the production of chemical elements as well as the metal mass density of the present-day universe. We then calculate the mean metal abundances for galaxies of different morphological types, along with the average metallicity of galactic matter in the universe (stars, gas and intergalactic medium). For the average metallicity of galaxies in the local universe, we find Z_gal= 0.0175, i.e. close to the solar value. We find the main metal production in spheroids (ellipticals and bulges) to occur at very early times, implying an early peak in the metal production and a subsequent decrease. On the other hand, the metal production in spirals and irregulars is always increasing with time. We perform a self-consistent census of the baryons and metals in the local universe finding that, while the vast majority of the baryons lies outside galaxies in the inter-galactic medium (IGM), 52 % of the metals (with the exception of the Fe-peak elements) is locked up in stars and in the interstellar medium. We estimate indirectly the amount of baryons which resides in the IGM and we derive its mean Fe abundance, finding a value of X_Fe,IGM=0.05 X_Fe,sun. We believe that this estimate is uncertain by a factor of 2, owing to the normalization of the local luminosity function. This means that the Fe abundance of 0.3 solar inferred from X-ray observations of the hot intra-cluster medium (ICM) is higher than the average Fe abundance of the inter-galactic gas in the field.

  6. Method of coating metal surfaces to form protective metal coating thereon

    DOE Patents [OSTI]

    Krikorian, Oscar H. (Danville, CA); Curtis, Paul G. (Tracy, CA)

    1992-01-01T23:59:59.000Z

    A process is disclosed for forming a protective metal coating on a metal surface using a flux consisting of an alkali metal fluoride, an alkaline earth metal fluoride, an alkali metal fluoaluminate, an alkali metal fluosilicate, and mixtures thereof. The flux, in particulate form, is mixed with particles of a metal coating material which may comprise aluminum, chromium, mixtures thereof, and alloys containing at least 50 wt. % aluminum and the particulate mixture is applied to the metal surface in a single step, followed by heating the coated metal surface to a temperature sufficient to cause the metal coating material to react with the metal surface to form a protective reaction product in the form of a metal coating bonded to the metal surface. The metal surface which reacts with the metal coating material to form the protective coating may comprise Fe, Co, Ni, Ti, V, Cr, Mn, Zr, Nb, Mo, Tc, Hf, Ta, W, Re and alloys thereof.

  7. Method of coating metal surfaces to form protective metal coating thereon

    DOE Patents [OSTI]

    Krikorian, O.H.; Curtis, P.G.

    1992-03-31T23:59:59.000Z

    A process is disclosed for forming a protective metal coating on a metal surface using a flux consisting of an alkali metal fluoride, an alkaline earth metal fluoride, an alkali metal fluoaluminate, an alkali metal fluosilicate, and mixtures thereof. The flux, in particulate form, is mixed with particles of a metal coating material which may comprise aluminum, chromium, mixtures thereof, and alloys containing at least 50 wt. % aluminum and the particulate mixture is applied to the metal surface in a single step, followed by heating the coated metal surface to a temperature sufficient to cause the metal coating material to react with the metal surface to form a protective reaction product in the form of a metal coating bonded to the metal surface. The metal surface which reacts with the metal coating material to form the protective coating may comprise Fe, Co, Ni, Ti, V, Cr, Mn, Zr, Nb, Mo, Tc, Hf, Ta, W, Re and alloys thereof. 1 figure.

  8. Catalysis using hydrous metal oxide ion exchangers

    DOE Patents [OSTI]

    Dosch, R.G.; Stephens, H.P.; Stohl, F.V.

    1983-07-21T23:59:59.000Z

    In a process which is catalyzed by a catalyst comprising an active metal on a carrier, said metal being active as a catalyst for the process, an improvement is provided wherein the catalyst is a hydrous, alkali metal or alkaline earth metal titanate, zirconate, niobate or tantalate wherein alkali or alkaline earth metal cations have been exchanged with a catalytically effective amount of cations of said metal.

  9. Hydrogen Storage in Metal-Organic Frameworks

    SciTech Connect (OSTI)

    Omar M. Yaghi

    2012-04-26T23:59:59.000Z

    Conventional storage of large amounts of hydrogen in its molecular form is difficult and expensive because it requires employing either extremely high pressure gas or very low temperature liquid. Because of the importance of hydrogen as a fuel, the DOE has set system targets for hydrogen storage of gravimetric (5.5 wt%) and volumetric (40 g L-1) densities to be achieved by 2015. Given that these are system goals, a practical material will need to have higher capacity when the weight of the tank and associated cooling or regeneration system is considered. The size and weight of these components will vary substantially depending on whether the material operates by a chemisorption or physisorption mechanism. In the latter case, metal-organic frameworks (MOFs) have recently been identified as promising adsorbents for hydrogen storage, although little data is available for their sorption behavior. This grant was focused on the study of MOFs with these specific objectives. (1) To examine the effects of functionalization, catenation, and variation of the metal oxide and organic linkers on the low-pressure hydrogen adsorption properties of MOFs. (2) To develop a strategy for producing MOFs with high surface area and porosity to reduce the dead space and increase the hydrogen storage capacity per unit volume. (3) To functionalize MOFs by post synthetic functionalization with metals to improve the adsorption enthalpy of hydrogen for the room temperature hydrogen storage. This effort demonstrated the importance of open metal sites to improve the adsorption enthalpy by the systematic study, and this is also the origin of the new strategy, which termed isoreticular functionalization and metalation. However, a large pore volume is still a prerequisite feature. Based on our principle to design highly porous MOFs, guest-free MOFs with ultrahigh porosity have been experimentally synthesized. MOF-210, whose BET surface area is 6240 m2 g-1 (the highest among porous solids), takes up 15 wt% of total H2 uptake at 80 bar and 77 K. More importantly, the total H2 uptake by MOF-210 was 2.7 wt% at 80 bar and 298 K, which is the highest number reported for physisorptive materials.

  10. Enhancing H[subscript 2] Uptake by 'Close-Packing' Alignment of Open Copper Sites in Metal-Organic Frameworks

    SciTech Connect (OSTI)

    Wang, Xi-Sen; Ma, Shengqian; Forster, Paul M.; Yuan, Daqiang; Eckert, Juergen; López, Joseph J.; Murphy, Brandon J.; Parise, John B.; Zhou, Hong-Cai (TAM); (SBU); (UCSB)

    2010-10-15T23:59:59.000Z

    Inspired by close-packing of spheres, to strengthen the framework-H{sub 2} interaction in MOFs (metal-organic frameworks), a strategy is devised to increase the number of nearest neighboring open metal sites ofe ach H{sub 2}-hosting cage, and to align the open metal sites toward the H{sub 2} molecules. Two MOF polymorphs were made, one exhibiting a record high hydrogen uptake of 3.0 wt% at 1 bar and 77 k.

  11. Chaotic Transport in Planar Periodic Vortical Flows

    E-Print Network [OSTI]

    Taehoon Ahn; Seunghwan Kim

    1993-09-24T23:59:59.000Z

    We have studied a chaotic transport in a two-dimensional periodic vortical flow under a time-dependent perturbation with period T where the global diffusion occurs along the stochastic web. By using the Melnikov method we construct the separatrix map describing the approximate dynamics near the saddle separatrices. Focusing on the small T, the width of the stochastic layer is calculated analytically by using the residue criterion and the diffusion constant by using the random phase assumption and correlated random walks. The analytical results are in good agreements with the results of two different types of numerical simulations by integrations of the Hamilton's equation of motion and by iterations of the separatrix map, which establishes the validity of the use of the separatrix map.

  12. On Normal Numbers Veronica Becher

    E-Print Network [OSTI]

    Figueira, Santiago

    ends with all zeros; hence, q is not simply normal to base b. 3/23 #12;The problem is still open Theorem (Borel 1909) Almost all real numbers are absolutely normal. Problem (Borel 1909) Give an example transducers. Huffman 1959 calls them lossless compressors. A direct proof of the above theorem Becher

  13. Brookhaven National Laboratory Number: Revision

    E-Print Network [OSTI]

    Ohta, Shigemi

    NATIONAL LABORATORY LASER CONTROLLED AREA STANDARD OPERATING PROCEDURE (SOP) This document defines OPERATIONS Operation Maintenance Service Specific Operation (specify) #12;Number: PS-ESH-0083 Revision: 01 the safety management program for the laser system(s) listed below. All American National Standard Institute

  14. Periodic-Orbit Theory of Level Correlations

    E-Print Network [OSTI]

    Stefan Heusler; Sebastian Müller; Alexander Altland; Petr Braun; Fritz Haake

    2006-10-20T23:59:59.000Z

    We present a semiclassical explanation of the so-called Bohigas-Giannoni-Schmit conjecture which asserts universality of spectral fluctuations in chaotic dynamics. We work with a generating function whose semiclassical limit is determined by quadruplets of sets of periodic orbits. The asymptotic expansions of both the non-oscillatory and the oscillatory part of the universal spectral correlator are obtained. Borel summation of the series reproduces the exact correlator of random-matrix theory.

  15. Heterogeneous Catalysis on Atomically Dispersed Supported Metals...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Catalysis on Atomically Dispersed Supported Metals: CO2 Reduction on Multifunctional Pd Catalysts. Heterogeneous Catalysis on Atomically Dispersed Supported Metals: CO2 Reduction...

  16. Recommendation 221: Recommendation Regarding Recycling of Metals...

    Office of Environmental Management (EM)

    221: Recommendation Regarding Recycling of Metals and Materials Recommendation 221: Recommendation Regarding Recycling of Metals and Materials In addition to the DOE making a final...

  17. Engineering Metal Impurities in Multicrystalline Silicon Solar...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Engineering Metal Impurities in Multicrystalline Silicon Solar Cells Print Transition metals are one of the main culprits in degrading the efficiency of multicrystalline solar...

  18. Formation of metal oxides by cathodic arc deposition

    SciTech Connect (OSTI)

    Anders, S.; Anders, A.; Rubin, M.; Wang, Z.; Raoux, S.; Kong, F.; Brown, I.G.

    1995-03-01T23:59:59.000Z

    Metal oxide thin films are of interest for a number of applications. Cathodic arc deposition, an established, industrially applied technique for formation of nitrides (e.g. TiN), can also be used for metal oxide thin film formation. A cathodic arc plasma source with desired cathode material is operated in an oxygen atmosphere, and metal oxides of various stoichiometric composition can be formed on different substrates. We report here on a series of experiments on metal oxide formation by cathodic arc deposition for different applications. Black copper oxide has been deposited on ALS components to increase the radiative heat transfer between the parts. Various metal oxides such as tungsten oxide, niobium oxide, nickel oxide and vanadium oxide have been deposited on ITO glass to form electrochromic films for window applications. Tantalum oxide films are of interest for replacing polymer electrolytes. Optical waveguide structures can be formed by refractive index variation using oxide multilayers. We have synthesized multilayers of Al{sub 2}O{sub 3}/Y{sub 2}O{sub 3}/AI{sub 2}O{sub 3}/Si as possible basic structures for passive optoelectronic integrated circuits, and Al{sub 2-x}Er{sub x}O{sub 3} thin films with a variable Er concentration which is a potential component layer for the production of active optoelectronic integrated devices such as amplifiers or lasers at a wavelength of 1.53 {mu}m. Aluminum and chromium oxide films have been deposited on a number of substrates to impart improved corrosion resistance at high temperature. Titanium sub-oxides which are electrically conductive and corrosion resistant and stable in a number of aggressive environments have been deposited on various substrates. These sub-oxides are of great interest for use in electrochemical cells.

  19. Policy Flash 2013-41 Contracts Periods of Performance Exceeding...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    41 Contracts Periods of Performance Exceeding 5 Years Policy Flash 2013-41 Contracts Periods of Performance Exceeding 5 Years Attached is Policy Flash 2013-41 Contracts Periods of...

  20. Quasi-periodic Fibonacci and periodic one-dimensional hypersonic phononic crystals of porous silicon: Experiment and simulation

    SciTech Connect (OSTI)

    Aliev, Gazi N., E-mail: g.aliev@bath.ac.uk; Goller, Bernhard [Department of Physics, University of Bath, Bath BA2 7AY (United Kingdom)

    2014-09-07T23:59:59.000Z

    A one-dimensional Fibonacci phononic crystal and a distributed Bragg reflector were constructed from porous silicon. The structures had the same number of layers and similar acoustic impedance mismatch, and were electrochemically etched in highly boron doped silicon wafers. The thickness of the individual layers in the stacks was approximately 2??m. Both types of hypersonic band gap structure were studied by direct measurement of the transmittance of longitudinal acoustic waves in the 0.1–2.6?GHz range. Acoustic band gaps deeper than 50?dB were detected in both structures. The experimental results were compared with model calculations employing the transfer matrix method. The acoustic properties of periodic and quasi-periodic structures in which half-wave retarding bi-layers do not consist of two quarter-wave retarding layers are discussed. The strong correlation between width and depth of gaps in the transmission spectra is demonstrated. The dominant mechanisms of acoustic losses in porous multilayer structures are discussed. The elastic constants remain proportional over our range of porosity, and hence, the Grüneisen parameter is constant. This simplifies the expression for the porosity dependence of the Akhiezer damping.

  1. Heavy Metal Humor: Reconsidering Carnival in Heavy Metal Culture 

    E-Print Network [OSTI]

    Powell, Gary Botts

    2013-06-05T23:59:59.000Z

    the majority of the land and maintained a social hierarchy that created a vast wealth disparity between the peasants and the church and upper classes. The Church?s feudal ownership of the land meant that it had power over the peasants, limiting social... manifest itself in metal culture. It may further 16 be suggested that the socio-economic climate from which metal culture developed has analogous threads to 16th century French feudal society. While feudalism and capitalism differ, both French...

  2. Quinary metallic glass alloys

    DOE Patents [OSTI]

    Lin, Xianghong (Pasadena, CA); Johnson, William L. (Pasadena, CA)

    1998-01-01T23:59:59.000Z

    At least quinary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10.sup.3 K/s. Such alloys comprise zirconium and/or hafnium in the range of 45 to 65 atomic percent, titanium and/or niobium in the range of 4 to 7.5 atomic percent, and aluminum and/or zinc in the range of 5 to 15 atomic percent. The balance of the alloy compositions comprise copper, iron, and cobalt and/or nickel. The composition is constrained such that the atomic percentage of iron is less than 10 percent. Further, the ratio of copper to nickel and/or cobalt is in the range of from 1:2 to 2:1. The alloy composition formula is: (Zr,Hf).sub.a (Al,Zn).sub.b (Ti,Nb).sub.c (Cu.sub.x Fe.sub.y (Ni,Co).sub.z).sub.d wherein the constraints upon the formula are: a ranges from 45 to 65 atomic percent, b ranges from 5 to 15 atomic percent, c ranges from 4 to 7.5 atomic percent, d comprises the balance, d.multidot.y is less than 10 atomic percent, and x/z ranges from 0.5 to 2.

  3. Quinary metallic glass alloys

    DOE Patents [OSTI]

    Lin, X.; Johnson, W.L.

    1998-04-07T23:59:59.000Z

    At least quinary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10{sup 3}K/s. Such alloys comprise zirconium and/or hafnium in the range of 45 to 65 atomic percent, titanium and/or niobium in the range of 4 to 7.5 atomic percent, and aluminum and/or zinc in the range of 5 to 15 atomic percent. The balance of the alloy compositions comprise copper, iron, and cobalt and/or nickel. The composition is constrained such that the atomic percentage of iron is less than 10 percent. Further, the ratio of copper to nickel and/or cobalt is in the range of from 1:2 to 2:1. The alloy composition formula is: (Zr,Hf){sub a}(Al,Zn){sub b}(Ti,Nb){sub c}(Cu{sub x}Fe{sub y}(Ni,Co){sub z}){sub d} wherein the constraints upon the formula are: a ranges from 45 to 65 atomic percent, b ranges from 5 to 15 atomic percent, c ranges from 4 to 7.5 atomic percent, d comprises the balance, d{hor_ellipsis}y is less than 10 atomic percent, and x/z ranges from 0.5 to 2.

  4. Layer-by-Layer Fabrication of Oriented Porous Thin Films Based on Porphyrin-Containing Metal-Organic Frameworks

    E-Print Network [OSTI]

    with number of growth cycles. Polarization excitation and fluorescence measurements indicate, Papanikolas et al. have reported on the fabrication and energy migration dynamics of metal for its exploitation for the preparation of molecular devices.19 Example materials include HKUST-1

  5. Formation of laser-induced periodic surface structures on niobium by femtosecond laser irradiation

    SciTech Connect (OSTI)

    Pan, A.; Dias, A.; Gomez-Aranzadi, M.; Olaizola, S. M. [CIC microGUNE, Goiru Kalea 9 Polo Innovación Garaia, 20500 Arrasate-Mondragón (Spain); CEIT-IK4 and Tecnun, University of Navarra, Manuel Lardizábal 15, 20018 San Sebastián (Spain); Rodriguez, A. [CIC microGUNE, Goiru Kalea 9 Polo Innovación Garaia, 20500 Arrasate-Mondragón (Spain)

    2014-05-07T23:59:59.000Z

    The surface morphology of a Niobium sample, irradiated in air by a femtosecond laser with a wavelength of 800?nm and pulse duration of 100 fs, was examined. The period of the micro/nanostructures, parallel and perpendicularly oriented to the linearly polarized fs-laser beam, was studied by means of 2D Fast Fourier Transform analysis. The observed Laser-Induced Periodic Surface Structures (LIPSS) were classified as Low Spatial Frequency LIPSS (periods about 600?nm) and High Spatial Frequency LIPSS, showing a periodicity around 300?nm, both of them perpendicularly oriented to the polarization of the incident laser wave. Moreover, parallel high spatial frequency LIPSS were observed with periods around 100?nm located at the peripheral areas of the laser fingerprint and overwritten on the perpendicular periodic gratings. The results indicate that this method of micro/nanostructuring allows controlling the Niobium grating period by the number of pulses applied, so the scan speed and not the fluence is the key parameter of control. A discussion on the mechanism of the surface topology evolution was also introduced.

  6. SEXUAL SIGNALING IN PERIODICAL CICADAS, MAGICICADA SPP. (HEMIPTERA: CICADIDAE)

    E-Print Network [OSTI]

    Simon, Chris

    SEXUAL SIGNALING IN PERIODICAL CICADAS, MAGICICADA SPP. (HEMIPTERA: CICADIDAE) by JOHN R. COOLEY1 behavior of periodical cicadas (Insecta: Hemiptera: Magicicada spp.) has been considered enigmatic because

  7. Use of impure inert gases in the controlled heating and cooling of mixed conducting metal oxide materials

    DOE Patents [OSTI]

    Carolan, Michael Francis (Allentown, PA); Bernhart, John Charles (Fleetwood, PA)

    2012-08-21T23:59:59.000Z

    Method for processing an article comprising mixed conducting metal oxide material. The method comprises contacting the article with an oxygen-containing gas and either reducing the temperature of the oxygen-containing gas during a cooling period or increasing the temperature of the oxygen-containing gas during a heating period; during the cooling period, reducing the oxygen activity in the oxygen-containing gas during at least a portion of the cooling period and increasing the rate at which the temperature of the oxygen-containing gas is reduced during at least a portion of the cooling period; and during the heating period, increasing the oxygen activity in the oxygen-containing gas during at least a portion of the heating period and decreasing the rate at which the temperature of the oxygen-containing gas is increased during at least a portion of the heating period.

  8. Maine Natural Gas Number of Commercial Consumers (Number of Elements)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40 Buildingto China (Million Cubic Feet) 3 0 07,755,432Commercial Consumers (Number

  9. Minnesota Natural Gas Number of Commercial Consumers (Number of Elements)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40 Buildingto China (Million Cubic Feet)Commercial Consumers (Number of Elements)

  10. Minnesota Natural Gas Number of Industrial Consumers (Number of Elements)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40 Buildingto China (Million Cubic Feet)Commercial Consumers (Number of

  11. Kansas Natural Gas Number of Residential Consumers (Number of Elements)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at1,066,688ElectricityLessAprilResidential Consumers (Number of

  12. Tennessee Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5 Tables July 1996 Energy Information Administration Office ofthroughYear Jan FebDecadeDecade217523,552.1Residential Consumers (Number

  13. Wisconsin Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5 Tables July 1996 Energy Information Administration Office ofthroughYear JanYearFuel5,266 6,090Industrial Consumers (Number

  14. Vermont Natural Gas Number of Commercial Consumers (Number of Elements)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40 Buildingto17 34 44Year Jan FebIncreasesCommercial Consumers (Number of Elements)

  15. Vermont Natural Gas Number of Industrial Consumers (Number of Elements)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40 Buildingto17 34 44Year Jan FebIncreasesCommercial Consumers (Number of

  16. Georgia Natural Gas Number of Industrial Consumers (Number of Elements)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,12803 Table A1.GasYear JanPriceIndustrial Consumers (Number of

  17. Metal-Organic Heat Carrier Nanofluids

    SciTech Connect (OSTI)

    McGrail, B. Peter; Thallapally, Praveen K.; Blanchard, Jeremy; Nune, Satish K.; Jenks, Jeromy WJ; Dang, Liem X.

    2013-09-01T23:59:59.000Z

    Nanofluids, dispersions of metal or oxide nanoparticles in a base working fluid, are being intensively studied due to improvements they offer in thermal properties of the working fluid. However, these benefits have been erratically demonstrated and proven impacts on thermal conductivity are modest and well described from long-established effective medium theory. In this paper, we describe a new class of metal-organic heat carrier (MOHC) nanofluid that offers potential for a larger performance boost in thermal vapor-liquid compression cycles. MOHCs are nanophase porous coordination solids designed to reversibly uptake the working fluid molecules in which the MOHCs are suspended. Additional heat can be extracted in a heat exchanger or solar collector from the endothermic enthalpy of desorption, which is then released as the nanofluid transits through a power generating device such as a turboexpander. Calculations for an R123 MOHC nanofluid indicated potential for up to 15% increase in power output. Capillary tube experiments show that liquid-vapor transitions occur without nanoparticle deposition on the tube walls provided entrance Reynolds number exceeds approximately 100.

  18. High-Pressure Thermodynamic Properties of f-electron Metals, Transition Metal Oxides, and Half-Metallic Magnets

    SciTech Connect (OSTI)

    Richard T. Scalettar; Warren E. Pickett

    2005-08-02T23:59:59.000Z

    This project involves research into the thermodynamic properties of f-electron metals, transition metal oxides, and half-metallic magnets at high pressure. These materials are ones in which the changing importance of electron-electron interactions as the distance between atoms is varied can tune the system through phase transitions from localized to delocalized electrons, from screened to unscreened magnetic moments, and from normal metal to one in which only a single spin specie can conduct. Three main thrusts are being pursued: (i) Mott transitions in transition metal oxides, (ii) magnetism in half-metallic compounds, and (iii) large volume-collapse transitions in f-band metals.

  19. Metal-sensing layer-semiconductor and metal-sensing layer-metal heterostructure gas sensors

    SciTech Connect (OSTI)

    O'Leary, M.; Li, Zheng; Fonash, S.J.

    1987-01-01T23:59:59.000Z

    Extremely sensitive gas sensors can be fabricated using heterostructures of the form metal-sensing layer-semiconductor or metal-sensing layer-metal. These structures are heterostructure diodes which have the barrier controlling transport at least partially located in the sensing layer. In the presence of the gas species to be detected, the electrical properties of the sensing layer evolve, resulting in a modification of the barrier to electric current transport and, hence, resulting in detection due to changes in the current-voltage characteristics of the device. This type of sensor structure is demonstrated using the Pd/Ti-O/sub x/Ti heterostructure hydrogen detector.

  20. Down-hole periodic seismic generator

    DOE Patents [OSTI]

    Hardee, H.C.; Hills, R.G.; Striker, R.P.

    1982-10-28T23:59:59.000Z

    A down hole periodic seismic generator system is disclosed for transmitting variable frequency, predominantly shear-wave vibration into earth strata surrounding a borehole. The system comprises a unitary housing operably connected to a well head by support and electrical cabling and contains clamping apparatus for selectively clamping the housing to the walls of the borehole. The system further comprises a variable speed pneumatic oscillator and a self-contained pneumatic reservoir for producing a frequency-swept seismic output over a discrete frequency range.

  1. Almost Periodic Measures and Meyer Sets

    E-Print Network [OSTI]

    Nicolae Strungaru

    2015-01-05T23:59:59.000Z

    In the first part, we construct a cut and project scheme from a family $\\{P_\\varepsilon\\}$ of sets verifying four conditions. We use this construction to characterize weighted Dirac combs defined by cut and project schemes and by continuous functions on the internal groups in terms of almost periodicity. We are also able to characterise those weighted Dirac combs for which the internal function is compactly supported. Lastly, using the same cut and project construction for $\\varepsilon$-dual sets, we are able to characterise Meyer sets in $\\sigma$-compact locally compact Abelian groups.

  2. Property:TimePeriod | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag Jump to:ID8/OrganizationTechProbSolutions Jump to: navigation,TimePeriod Jump to:

  3. A comparison of graphene, superconductors and metals as conductors for metamaterials and plasmonics

    SciTech Connect (OSTI)

    Tassin, Philippe; Koschny, Thomas; Kafesaki, Maria; Soukoulis, Costas

    2012-03-30T23:59:59.000Z

    Recent advancements in metamaterials and plasmonics have promised a number of exciting applications, in particular at terahertz and optical frequencies. Unfortunately, the noble metals used in these photonic structures are not particularly good conductors at high frequencies, resulting in significant dissipative loss. Here, we address the question of what is a good conductor for metamaterials and plasmonics. For resonant metamaterials, we develop a figure-of-merit for conductors that allows for a straightforward classification of conducting materials according to the resulting dissipative loss in the metamaterial. Application of our method predicts that graphene and high-T{sub c} superconductors are not viable alternatives for metals in metamaterials. We also provide an overview of a number of transition metals, alkali metals and transparent conducting oxides. For plasmonic systems, we predict that graphene and high-T{sub c} superconductors cannot outperform gold as a platform for surface plasmon polaritons, because graphene has a smaller propagation length-to-wavelength ratio.

  4. Titanium metal: extraction to application

    SciTech Connect (OSTI)

    Gambogi, Joseph (USGS, Reston, VA); Gerdemann, Stephen J.

    2002-09-01T23:59:59.000Z

    In 1998, approximately 57,000 tons of titanium metal was consumed in the form of mill products (1). Only about 5% of the 4 million tons of titanium minerals consumed each year is used to produce titanium metal, with the remainder primarily used to produce titanium dioxide pigment. Titanium metal production is primarily based on the direct chlorination of rutile to produce titanium tetrachloride, which is then reduced to metal using the Kroll magnesium reduction process. The use of titanium is tied to its high strength-to-weight ratio and corrosion resistance. Aerospace is the largest application for titanium. In this paper, we discuss all aspects of the titanium industry from ore deposits through extraction to present and future applications. The methods of both primary (mining of ore, extraction, and purification) and secondary (forming and machining) operations will be analyzed. The chemical and physical properties of titanium metal will be briefly examined. Present and future applications for titanium will be discussed. Finally, the economics of titanium metal production also are analyzed as well as the advantages and disadvantages of various alternative extraction methods.

  5. Metal sponge for cryosorption pumping applications

    DOE Patents [OSTI]

    Myneni, G.R.; Kneisel, P.

    1995-12-26T23:59:59.000Z

    A system has been developed for adsorbing gases at high vacuum in a closed area. The system utilizes large surface clean anodized metal surfaces at low temperatures to adsorb the gases. The large surface clean anodized metal is referred to as a metal sponge. The metal sponge generates or maintains the high vacuum by increasing the available active cryosorbing surface area. 4 figs.

  6. Metal salt catalysts for enhancing hydrogen spillover

    DOE Patents [OSTI]

    Yang, Ralph T; Wang, Yuhe

    2013-04-23T23:59:59.000Z

    A composition for hydrogen storage includes a receptor, a hydrogen dissociating metal doped on the receptor, and a metal salt doped on the receptor. The hydrogen dissociating metal is configured to spill over hydrogen to the receptor, and the metal salt is configured to increase a rate of the spill over of the hydrogen to the receptor.

  7. Horizontal electromagnetic casting of thin metal sheets

    DOE Patents [OSTI]

    Hull, John R. (Hinsdale, IL); Lari, Robert J. (Aurora, IL); Praeg, Walter F. (Palos Park, IL); Turner, Larry R. (Naperville, IL)

    1987-01-01T23:59:59.000Z

    Thin metal sheets are cast by magnetically suspending molten metal deposited within a ferromagnetic yoke and between AC conducting coils and linearly displacing the magnetically levitated liquid metal while it is being cooled to form a solid metal sheet. Magnetic flux increases as the molten metal sheet moves downward and decreases as the molten metal sheet moves upward to stabilize the sheet and maintain it in equilibrium as it is linearly displaced and solidified by cooling gases. A conducting shield is electrically coupled to the molten metal sheet by means of either metal sheet engaging rollers or brushes on the solidified metal, and by means of an electrode in the vessel containing the molten metal thereby providing a return path for the eddy currents induced in the metal sheet by the AC coil generated magnetic flux. Variation in the geometry of the conducting shield allows the magnetic flux between the metal sheet and the conducting shield to be varied and the thickness in surface quality of the metal sheet to be controlled. Side guards provide lateral containment for the molten metal sheet and stabilize and shape the magnetic field while a leader sheet having electromagnetic characteristics similar to those of the metal sheet is used to start the casting process and precedes the molten metal sheet through the magnet and forms a continuous sheet therewith. The magnet may be either U-shaped with a single racetrack coil or may be rectangular with a pair of facing bedstead coils.

  8. Horizontal electromagnetic casting of thin metal sheets

    DOE Patents [OSTI]

    Hull, John R. (Hinsdale, IL); Lari, Robert J. (Aurora, IL); Praeg, Walter F. (Palos Park, IL); Turner, Larry R. (Naperville, IL)

    1988-01-01T23:59:59.000Z

    Thin metal sheets are cast by magnetically suspending molten metal deposited within a ferromagnetic yoke and between AC conducting coils and linearly displacing the magnetically levitated liquid metal while it is being cooled to form a solid metal sheet. Magnetic flux increases as the molten metal sheet moves downward and decreases as the molten metal sheet moves upward to stabilize the sheet and maintain it in equilibrium as it is linearly displaced and solidified by cooling gases. A conducting shield is electrically coupled to the molten metal sheet by means of either metal sheet engaging rollers or brushes on the solidified metal, and by means of an electrode in the vessel containing the molten metal thereby providing a return path for the eddy currents induced in the metal sheet by the AC coil generated magnetic flux. Variation in the geometry of the conducting shield allows the magnetic flux between the metal sheet and the conducting shield to be varied and the thickness in surface quality of the metal sheet to be controlled. Side guards provide lateral containment for the molten metal sheet and stabilize and shape the magnetic field while a leader sheet having electromagnetic characteristics similar to those of the metal sheet is used to start the casting process and precedes the molten metal sheet through the magnet and forms a continuous sheet therewith. The magnet may be either U-shaped with a single racetrack coil or may be rectangular with a pair of facing bedstead coils.

  9. Maskless laser writing of microscopic metallic interconnects

    DOE Patents [OSTI]

    Maya, L.

    1995-10-17T23:59:59.000Z

    A method of forming a metal pattern on a substrate is disclosed. The method includes depositing an insulative nitride film on a substrate and irradiating a laser beam onto the nitride film, thus decomposing the metal nitride into a metal constituent and a gaseous constituent, the metal constituent remaining in the nitride film as a conductive pattern. 4 figs.

  10. Maskless laser writing of microscopic metallic interconnects

    DOE Patents [OSTI]

    Maya, Leon (Oak Ridge, TN)

    1995-01-01T23:59:59.000Z

    A method of forming a metal pattern on a substrate. The method includes depositing an insulative nitride film on a substrate and irradiating a laser beam onto the nitride film, thus decomposing the metal nitride into a metal constituent and a gaseous constituent, the metal constituent remaining in the nitride film as a conductive pattern.

  11. Dispersion enhanced metal/zeolite catalysts

    DOE Patents [OSTI]

    Sachtler, W.M.H.; Tzou, M.S.; Jiang, H.J.

    1987-03-31T23:59:59.000Z

    Dispersion stabilized zeolite supported metal catalysts are provided as bimetallic catalyst combinations. The catalyst metal is in a reduced zero valent form while the dispersion stabilizer metal is in an unreduced ionic form. Representative catalysts are prepared from platinum or nickel as the catalyst metal and iron or chromium dispersion stabilizer.

  12. TRANSITION DE MOTT METAL-INSULATOR TRANSITIONS

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    TRANSITION DE MOTT METAL-INSULATOR TRANSITIONS IN TRANSITION METAL OXIDES by D. B. McWHAN, A. MENTH oxydes de metaux de transition on observe une transition d'isolant a metal puis de metal a isolant de type Mott lorsque l'on augmentelenombre d'electrons d. Danslesysthe(V1-~Cr~)203une transition de Mott

  13. Metal nanoparticles as a conductive catalyst

    DOE Patents [OSTI]

    Coker, Eric N. (Albuquerque, NM)

    2010-08-03T23:59:59.000Z

    A metal nanocluster composite material for use as a conductive catalyst. The metal nanocluster composite material has metal nanoclusters on a carbon substrate formed within a porous zeolitic material, forming stable metal nanoclusters with a size distribution between 0.6-10 nm and, more particularly, nanoclusters with a size distribution in a range as low as 0.6-0.9 nm.

  14. Metal oxide nanostructures with hierarchical morphology

    DOE Patents [OSTI]

    Ren, Zhifeng (Newton, MA); Lao, Jing Yu (Saline, MI); Banerjee, Debasish (Ann Arbor, MI)

    2007-11-13T23:59:59.000Z

    The present invention relates generally to metal oxide materials with varied symmetrical nanostructure morphologies. In particular, the present invention provides metal oxide materials comprising one or more metallic oxides with three-dimensionally ordered nanostructural morphologies, including hierarchical morphologies. The present invention also provides methods for producing such metal oxide materials.

  15. Metal sponge for cryosorption pumping applications

    DOE Patents [OSTI]

    Myneni, Ganapati R. (Yorktown, VA); Kneisel, Peter (Williamsburg, VA)

    1995-01-01T23:59:59.000Z

    A system has been developed for adsorbing gases at high vacuum in a closed area. The system utilizes large surface clean anodized metal surfaces at low temperatures to adsorb the gases. The large surface clean anodized metal is referred to as a metal sponge. The metal sponge generates or maintains the high vacuum by increasing the available active cryosorbing surface area.

  16. Molten metal injector system and method

    DOE Patents [OSTI]

    Meyer, Thomas N. (Murrysville, PA); Kinosz, Michael J. (Apollo, PA); Bigler, Nicolas (Morin Heights, CA); Arnaud, Guy (Riviere-Beaudette, CA)

    2003-04-01T23:59:59.000Z

    Disclosed is a molten metal injector system including a holder furnace, a casting mold supported above the holder furnace, and a molten metal injector supported from a bottom side of the mold. The holder furnace contains a supply of molten metal having a metal oxide film surface. The bottom side of the mold faces the holder furnace. The mold defines a mold cavity for receiving the molten metal from the holder furnace. The injector projects into the holder furnace and is in fluid communication with the mold cavity. The injector includes a piston positioned within a piston cavity defined by a cylinder for pumping the molten metal upward from the holder furnace and injecting the molten metal into the mold cavity under pressure. The piston and cylinder are at least partially submerged in the molten metal when the holder furnace contains the molten metal. The cylinder further includes a molten metal intake for receiving the molten metal into the piston cavity. The molten metal intake is located below the metal oxide film surface of the molten metal when the holder furnace contains the molten metal. A method of injecting molten metal into a mold cavity of a casting mold is also disclosed.

  17. Anaerobic microbial remobilization of coprecipitated metals

    DOE Patents [OSTI]

    Francis, A.J.; Dodge, C.J.

    1994-10-11T23:59:59.000Z

    A process is provided for solubilizing coprecipitated metals. Metals in waste streams are concentrated by treatment with an iron oxide coprecipitating agent. The coprecipitated metals are solubilized by contacting the coprecipitate with a bacterial culture of a Clostridium species ATCC 53464. The remobilized metals can then be recovered and recycled. 4 figs.

  18. Periodic Cluster Mutations and Related Integrable Maps

    E-Print Network [OSTI]

    Allan P Fordy

    2014-03-31T23:59:59.000Z

    One of the remarkable properties of cluster algebras is that any cluster, obtained from a sequence of mutations from an initial cluster, can be written as a Laurent polynomial in the initial cluster (known as the "Laurent phenomenon"). There are many nonlinear recurrences which exhibit the Laurent phenomenon and thus unexpectedly generate integer sequences. The mutation of a typical quiver will not generate a recurrence, but rather an erratic sequence of exchange relations. How do we "design" a quiver which gives rise to a given recurrence? A key role is played by the concept of "periodic cluster mutation", introduced in 2009. Each recurrence corresponds to a finite dimensional map. In the context of cluster mutations, these are called "cluster maps". What properties do cluster maps have? Are they integrable in some standard sense? In this review I describe how integrable maps arise in the context of cluster mutations. I first explain the concept of "periodic cluster mutation", giving some classification results. I then give a review of what is meant by an integrable map and apply this to cluster maps. Two classes of integrable maps are related to interesting monodromy problems, which generate interesting Poisson algebras of functions, used to prove complete integrability and a linearisation. A connections to the Hirota-Miwa equation is explained.

  19. Bridged transition-metal complexes and uses thereof for hydrogen separation, storage and hydrogenation

    DOE Patents [OSTI]

    Lilga, M.A.; Hallen, R.T.

    1990-08-28T23:59:59.000Z

    The present invention constitutes a class of organometallic complexes which reversibly react with hydrogen to form dihydrides and processes by which these compounds can be utilized. The class includes bimetallic complexes in which two cyclopentadienyl rings are bridged together and also separately [pi]-bonded to two transition metal atoms. The transition metals are believed to bond with the hydrogen in forming the dihydride. Transition metals such as Fe, Mn or Co may be employed in the complexes although Cr constitutes the preferred metal. A multiple number of ancillary ligands such as CO are bonded to the metal atoms in the complexes. Alkyl groups and the like may be substituted on the cyclopentadienyl rings. These organometallic compounds may be used in absorption/desorption systems and in facilitated transport membrane systems for storing and separating out H[sub 2] from mixed gas streams such as the producer gas from coal gasification processes. 3 figs.

  20. Bridged transition-metal complexes and uses thereof for hydrogen separation, storage and hydrogenation

    DOE Patents [OSTI]

    Lilga, Michael A. (Richland, WA); Hallen, Richard T. (Richland, WA)

    1991-01-01T23:59:59.000Z

    The present invention constitutes a class of organometallic complexes which reversibly react with hydrogen to form dihydrides and processes by which these compounds can be utilized. The class includes bimetallic complexes in which two cyclopentadienyl rings are bridged together and also separately .pi.-bonded to two transition metal atoms. The transition metals are believed to bond with the hydrogen in forming the dihydride. Transition metals such as Fe, Mn or Co may be employed in the complexes although Cr constitutes the preferred metal. A multiple number of ancilliary ligands such as CO are bonded to the metal atoms in the complexes. Alkyl groups and the like may be substituted on the cyclopentadienyl rings. These organometallic compounds may be used in absorption/desorption systems and in facilitated transport membrane systems for storing and separating out H.sub.2 from mixed gas streams such as the product gas from coal gasification processes.

  1. Bridged transition-metal complexes and uses thereof for hydrogen separation, storage and hydrogenation

    DOE Patents [OSTI]

    Lilga, M.A.; Hallen, R.T.

    1991-10-15T23:59:59.000Z

    The present invention constitutes a class of organometallic complexes which reversibly react with hydrogen to form dihydrides and processes by which these compounds can be utilized. The class includes bimetallic complexes in which two cyclopentadienyl rings are bridged together and also separately [pi]-bonded to two transition metal atoms. The transition metals are believed to bond with the hydrogen in forming the dihydride. Transition metals such as Fe, Mn or Co may be employed in the complexes although Cr constitutes the preferred metal. A multiple number of ancillary ligands such as CO are bonded to the metal atoms in the complexes. Alkyl groups and the like may be substituted on the cyclopentadienyl rings. These organometallic compounds may be used in absorption/desorption systems and in facilitated transport membrane systems for storing and separating out H[sub 2] from mixed gas streams such as the product gas from coal gasification processes. 3 figures.

  2. Bridged transition-metal complexes and uses thereof for hydrogen separation, storage and hydrogenation

    DOE Patents [OSTI]

    Lilga, Michael A. (Richland, WA); Hallen, Richard T. (Richland, WA)

    1990-01-01T23:59:59.000Z

    The present invention constitutes a class of organometallic complexes which reversibly react with hydrogen to form dihydrides and processes by which these compounds can be utilized. The class includes bimetallic complexes in which two cyclopentadienyl rings are bridged together and also separately .pi.-bonded to two transition metal atoms. The transition metals are believed to bond with the hydrogen in forming the dihydride. Transition metals such as Fe, Mn or Co may be employed in the complexes although Cr constitutes the preferred metal. A multiple number of ancilliary ligands such as CO are bonded to the metal atoms in the complexes. Alkyl groups and the like may be substituted on the cyclopentadienyl rings. These organometallic compounds may be used in absorption/desorption systems and in facilitated transport membrane systems for storing and separating out H.sub.2 from mixed gas streams such as the produce gas from coal gasification processes.

  3. Valence, coordination number, and PAV cells in metallic rare earth compounds F. L. Carter

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    that the effective radius of the rare earth atoms is surprisingly variable and may even be anisotropic in some SmCo5], is indicated not only by the prediction [4] of the unstability of the SmCo5 structure [9], but even to the likely nature of one of the SmCo5-type distortions. For the first time this paper demonstrated

  4. Vibration-Induced Kondo Tunneling through Metal-Organic Complexes with Even Electron Occupation Number

    E-Print Network [OSTI]

    - neling Hamiltonian H Hmol Hres Htun: (1) Here Hmol includes the 3d electron levels in a ligand field of the cage electrons, the molecular orbitals of these ligands, as well as interactions within the 3d shell with tunneling electrons (vibration assisted tunneling) [8­13] and modulation of the tunnel barriers (shuttling

  5. Stopband optimised E-plane filters with multiple metal inserts of variable number

    E-Print Network [OSTI]

    Bornemann, Jens

    element Prof. F. Arndt, Dr.-Ing., Sen.Mem.I.E.E.E., D. Heckmann, Dipl.-lng., H. Semmerow, Dipl.-lng., J

  6. Criteria for Preparing and Packaging Plutonium Metals and Oxides for Long-Term Storage

    SciTech Connect (OSTI)

    NONE

    1994-12-01T23:59:59.000Z

    This Standard provides criteria for packaging of plutonium metals and stabilized oxides for storage periods of at least 50 years. To meet the criteria, plutonium-bearing materials must be in stable forms and be packaged in containers designed to maintain their integrity both under normal storage conditions and during anticipated handling accidents.

  7. Limit Distribution of Averages over Unstable Periodic Orbits Forming Chaotic Attractor

    E-Print Network [OSTI]

    Denis S. Goldobin

    2012-08-08T23:59:59.000Z

    We address the question of representativeness of a single long unstable periodic orbit for properties of the chaotic attractor it is embedded in. Y. Saiki and M. Yamada [Phys. Rev. E 79, 015201(R) (2009)] have recently suggested the hypothesis that there exist a limit distribution of averages over unstable periodic orbits with given number of loops, N, which is not a Dirac delta-function for infinitely long orbits. In this paper we show that the limit distribution is actually a delta-function and standard deviations decay as 1/sqrt(N) for large enough N.

  8. Equilibrium quasi-periodic configurations with resonant frequencies in quasi-periodic media I: perturbative expansions

    E-Print Network [OSTI]

    Xifeng Su; Lei Zhang; Rafael de la Llave

    2015-03-11T23:59:59.000Z

    We consider 1-D quasi-periodic Frenkel-Kontorova models (describing, for example, deposition of materials in a quasi-periodic substratum). We study the existence of equilibria whose frequency (i.e. the inverse of the density of deposited material) is resonant with the frequencies of the substratum. We study perturbation theory for small potential. We show that there are perturbative expansions to all orders for the quasi-periodic equilibria with resonant frequencies. Under very general conditions, we show that there are at least two such perturbative expansions for equilibria for small values of the parameter. We also develop a dynamical interpretation of the equilibria in these quasi-periodic media. We show that the dynamical system has very unusual properties. Using these, we obtain results on the Lyapunov exponents of the resonant quasi-periodic solutions. In a companion paper, we develop a rather unusual KAM theory (requiring new considerations) which establishes that the perturbative expansions converge when the perturbing potentials satisfy a one-dimensional constraint.

  9. Method of bonding metals to ceramics

    DOE Patents [OSTI]

    Maroni, V.A.

    1991-04-23T23:59:59.000Z

    A ceramic or glass having a thin layer of silver, gold or alloys thereof at the surface thereof is disclosed. A first metal is bonded to the thin layer and a second metal is bonded to the first metal. The first metal is selected from the class consisting of In, Ga, Sn, Bi, Zn, Cd, Pb, Tl and alloys thereof, and the second metal is selected from the class consisting of Cu, Al, Pb, Au and alloys thereof. 3 figures.

  10. Coated metal articles and method of making

    DOE Patents [OSTI]

    Boller, Ernest R. (Van Buren Township, IN); Eubank, Lowell D. (Wilmington, DE)

    2004-07-06T23:59:59.000Z

    The method of protectively coating metallic uranium which comprises dipping the metallic uranium in a molten alloy comprising about 20-75% of copper and about 80-25% of tin, dipping the coated uranium promptly into molten tin, withdrawing it from the molten tin and removing excess molten metal, thereupon dipping it into a molten metal bath comprising aluminum until it is coated with this metal, then promptly withdrawing it from the bath.

  11. Coated Metal Articles and Method of Making

    DOE Patents [OSTI]

    Boller, Ernest R.; Eubank, Lowell D.

    2004-07-06T23:59:59.000Z

    The method of protectively coating metallic uranium which comprises dipping the metallic uranium in a molten alloy comprising about 20-75% of copper and about 80-25% of tin, dipping the coated uranium promptly into molten tin, withdrawing it from the molten tin and removing excess molten metal, thereupon dipping it into a molten metal bath comprising aluminum until it is coated with this metal, then promptly withdrawing it from the bath.

  12. Infrared transparent frequency selective surface based on metallic meshes

    SciTech Connect (OSTI)

    Yu, Miao [Key Laboratory of Optical System Advanced Manufacturing Technology, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun, 130033 (China) [Key Laboratory of Optical System Advanced Manufacturing Technology, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun, 130033 (China); University of Chinese Academy of Sciences, Beijing, 100049 (China); Xu, Nianxi; Liu, Hai; Gao, Jinsong, E-mail: gaojs@ciomp.ac.cn [Key Laboratory of Optical System Advanced Manufacturing Technology, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun, 130033 (China)] [Key Laboratory of Optical System Advanced Manufacturing Technology, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun, 130033 (China)

    2014-02-15T23:59:59.000Z

    This paper presents an infrared transparent frequency selective surface (ITFSS) based on metallic meshes. In this ITFSS structure, periodic cross-slot units are integrated on square metallic meshes empowered by coating and UV-lithography. A matching condition is proposed to avoid the distortion of units. Experimental results show that this ITFSS possesses a good transmittance of 80% in the infrared band of 3–5 ?m, and also a stable band-pass behavior at the resonance frequency of 36.4 GHz with transmittance of ?0.56 dB. Theoretical simulations about the ITFSS diffractive characteristics and frequency responses are also investigated. The novel ITFSS will attract renewed interest and be exploited for applications in various fields.

  13. Particle Number & Particulate Mass Emissions Measurements on...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Number & Particulate Mass Emissions Measurements on a 'Euro VI' Heavy-duty Engine using the PMP Methodologies Particle Number & Particulate Mass Emissions Measurements on a 'Euro...

  14. Quasi-Periodic Oscillations from Magnetorotational Turbulence

    E-Print Network [OSTI]

    Phil Arras; Omer Blaes; Neal J. Turner

    2006-02-13T23:59:59.000Z

    Quasi-periodic oscillations (QPOs) in the X-ray lightcurves of accreting neutron star and black hole binaries have been widely interpreted as being due to standing wave modes in accretion disks. These disks are thought to be highly turbulent due to the magnetorotational instability (MRI). We study wave excitation by MRI turbulence in the shearing box geometry. We demonstrate that axisymmetric sound waves and radial epicyclic motions driven by MRI turbulence give rise to narrow, distinct peaks in the temporal power spectrum. Inertial waves, on the other hand, do not give rise to distinct peaks which rise significantly above the continuum noise spectrum set by MRI turbulence, even when the fluid motions are projected onto the eigenfunctions of the modes. This is a serious problem for QPO models based on inertial waves.

  15. Periodic Arrays of M2-Branes

    E-Print Network [OSTI]

    Imtak Jeon; Neil Lambert; Paul Richmond

    2012-11-29T23:59:59.000Z

    We consider periodic arrays of M2-branes in the ABJM model in the spirit of a circle compactification to D2-branes in type IIA string theory. The result is a curious formulation of three-dimensional maximally supersymmetric Yang-Mills theory in terms of fermions, seven transverse scalars, a non-dynamical gauge field and an additional scalar `dual gluon'. Upon further T-duality on a transverse torus we obtain a non-manifest-Lorentz-invariant description of five-dimensional maximally supersymmetric Yang-Mills. Here the additional scalar field can be thought of as the components of a two-form along the torus. This action can be viewed as an M-theory description of M5-branes on ${\\mathbb T}^3$.

  16. Steady periodic gravity waves with surface tension

    E-Print Network [OSTI]

    Samuel Walsh

    2009-11-06T23:59:59.000Z

    In this paper we consider two-dimensional, stratified, steady water waves propagating over an impermeable flat bed and with a free surface. The motion is assumed to be driven by capillarity (that is, surface tension) on the surface and a gravitational force acting on the body of the fluid. We prove the existence of global continua of classical solutions that are periodic and traveling. This is accomplished by first constructing a 1-parameter family of laminar flow solutions, $\\mathcal{T}$, then applying bifurcation theory methods to obtain local curves of small amplitude solutions branching from $\\mathcal{T}$ at an eigenvalue of the linearized problem. Each solution curve is then continued globally by means of a degree theoretic theorem in the spirit of Rabinowitz. Finally, we complement the degree theoretic picture by proving an alternate global bifurcation theorem via the analytic continuation method of Dancer.

  17. Periodically multilayered planar optical concentrator for photovoltaic solar cells Manuel E. Solano, Muhammad Faryad, Peter B. Monk, Thomas E. Mallouk, and Akhlesh Lakhtakia

    E-Print Network [OSTI]

    Periodically multilayered planar optical concentrator for photovoltaic solar cells Manuel E. Solano performance of amorphous silicon solar cells via scattering from surface plasmon polaritons in nearby metallic concentrator for photovoltaic solar cells Manuel E. Solano,1 Muhammad Faryad,2 Peter B. Monk,1 Thomas E

  18. Zone refining of plutonium metal

    SciTech Connect (OSTI)

    Blau, M.S.

    1994-08-01T23:59:59.000Z

    The zone refining process was applied to Pu metal containing known amounts of impurities. Rod specimens of plutonium metal were melted into and contained in tantalum boats, each of which was passed horizontally through a three-turn, high-frequency coil in such a manner as to cause a narrow molten zone to pass through the Pu metal rod 10 times. The impurity elements Co, Cr, Fe, Ni, Np, U were found to move in the same direction as the molten zone as predicted by binary phase diagrams. The elements Al, Am, and Ga moved in the opposite direction of the molten zone as predicted by binary phase diagrams. As the impurity alloy was zone refined, {delta}-phase plutonium metal crystals were produced. The first few zone refining passes were more effective than each later pass because an oxide layer formed on the rod surface. There was no clear evidence of better impurity movement at the slower zone refining speed. Also, constant or variable coil power appeared to have no effect on impurity movement during a single run (10 passes). This experiment was the first step to developing a zone refining process for plutonium metal.

  19. Random number stride in Monte Carlo calculations

    SciTech Connect (OSTI)

    Hendricks, J.S.

    1990-01-01T23:59:59.000Z

    Monte Carlo radiation transport codes use a sequence of pseudorandom numbers to sample from probability distributions. A common practice is to start each source particle a predetermined number of random numbers up the pseudorandom number sequence. This number of random numbers skipped between each source particles the random number stride, S. Consequently, the jth source particle always starts with the j{center dot}Sth random number providing correlated sampling'' between similar calculations. A new machine-portable random number generator has been written for the Monte Carlo radiation transport code MCNP providing user's control of the random number stride. First the new MCNP random number generator algorithm will be described and then the effects of varying the stride will be presented. 2 refs., 1 fig.

  20. LaNi{sub 5}-based metal hydride electrode in Ni-MH rechargeable cells

    DOE Patents [OSTI]

    Bugga, R.V.; Fultz, B.; Bowman, R.; Surampudi, S.R.; Witham, C.K.; Hightower, A.

    1999-03-30T23:59:59.000Z

    An at least ternary metal alloy of the formula AB{sub (Z-Y)}X{sub (Y)} is disclosed. In this formula, A is selected from the rare earth elements, B is selected from the elements of Groups 8, 9, and 10 of the Periodic Table of the Elements, and X includes at least one of the following: antimony, arsenic, germanium, tin or bismuth. Z is greater than or equal to 4.8 and less than or equal to 6.0. Y is greater than 0 and less than 1. Ternary or higher-order substitutions to the base AB{sub 5} alloys that form strong kinetic interactions with the predominant metals in the base metal hydride are used to form metal alloys with high structural integrity after multiple cycles of hydrogen sorption. 16 figs.

  1. Novel method for the prediction of an interface bonding species at alumina/metal interfaces

    SciTech Connect (OSTI)

    Yoshitake, Michiko, E-mail: yoshitake.michiko@nims.go.jp; Yagyu, Shinjiro [National Institute for Materials Science, 3-13, Sakura, Tsukuba 305-0003 (Japan); Chikyow, Toyohiro [National Institute for Materials Science, 1-1, Namiki, Tsukuba 305-0044 (Japan)

    2014-03-15T23:59:59.000Z

    Interface bonding between alumina and various metals is discussed from the viewpoint of chemical thermodynamics. A method to predict the interface bonding species at an alumina/metal interface under equilibrium conditions is proposed by using the concept of chemical equilibrium for interface termination. The originality of this method is in the way a simple estimation of the interface binding energy, which is generally applicable to most metals, is developed. The effectiveness of this method is confirmed by careful examination of the experimental results. Comparison of the predicted and experimentally observed interface terminations reveals that the proposed method agrees well with the reported results. The method uses only basic quantities of pure elements and the formation enthalpy of oxides. Therefore, it can be applied to most metals in the periodic table and is useful for screening materials in the quest to develop interfaces with particular functions.

  2. Methods for reducing the loss of metal in a metal vapor laser

    DOE Patents [OSTI]

    Duncan, David B. (Auburn, CA); Alger, Terry W. (Tracy, CA)

    1990-01-01T23:59:59.000Z

    Methods are provided for reducing loss of metal from a metal vapor laser by collecting metal present outside the hot zone of the laser and introducing or confining it in the hot zone.

  3. Device Independent Random Number Generation

    E-Print Network [OSTI]

    Mataj Pivoluska; Martin Plesch

    2015-02-23T23:59:59.000Z

    Randomness is an invaluable resource in today's life with a broad use reaching from numerical simulations through randomized algorithms to cryptography. However, on the classical level no true randomness is available and even the use of simple quantum devices in a prepare-measure setting suffers from lack of stability and controllability. This gave rise to a group of quantum protocols that provide randomness certified by classical statistical tests -- Device Independent Quantum Random Number Generators. In this paper we review the most relevant results in this field, which allow the production of almost perfect randomness with help of quantum devices, supplemented with an arbitrary weak source of additional randomness. This is in fact the best one could hope for to achieve, as with no starting randomness (corresponding to no free will in a different concept) even a quantum world would have a fully deterministic description.

  4. Hydrogen atom in crossed electric and magnetic fields: Phase space topology and torus quantization via periodic orbits

    E-Print Network [OSTI]

    Stephan Gekle; Jörg Main; Thomas Bartsch; T. Uzer

    2006-10-02T23:59:59.000Z

    A hierarchical ordering is demonstrated for the periodic orbits in a strongly coupled multidimensional Hamiltonian system, namely the hydrogen atom in crossed electric and magnetic fields. It mirrors the hierarchy of broken resonant tori and thereby allows one to characterize the periodic orbits by a set of winding numbers. With this knowledge, we construct the action variables as functions of the frequency ratios and carry out a semiclassical torus quantization. The semiclassical energy levels thus obtained agree well with exact quantum calculations.

  5. Recycling of rare earth metals from rare earth-transition metal alloy scrap by liquid metal extraction

    DOE Patents [OSTI]

    Ellis, T.W.; Schmidt, F.A.

    1995-08-01T23:59:59.000Z

    A method is described for treating rare earth metal-bearing scrap, waste or other material (e.g. Nd--Fe--B or Dy--Tb--Fe scrap) to recover the rare earth metal comprising melting the rare earth metal-bearing material, melting a Group IIA metal extractant, such as Mg, Ca, or Ba, in which the rare earth is soluble in the molten state, and contacting the melted material and melted extractant at a temperature and for a time effective to extract the rare earth from the melted material into the melted extractant. The rare earth metal is separated from the extractant metal by vacuum sublimation or distillation. 2 figs.

  6. Recycling of rare earth metals from rare earth-transition metal alloy scrap by liquid metal extraction

    DOE Patents [OSTI]

    Ellis, Timothy W. (Ames, IA); Schmidt, Frederick A. (Ames, IA)

    1995-08-01T23:59:59.000Z

    Method of treating rare earth metal-bearing scrap, waste or other material (e.g. Nd--Fe--B or Dy--Tb--Fe scrap) to recover the rare earth metal comprising melting the rare earth metal-bearing material, melting a Group IIA metal extractant, such as Mg, Ca, or Ba, in which the rare earth is soluble in the molten state, and contacting the melted material and melted extractant at a temperature and for a time effective to extract the rare earth from the melted material into the melted extractant. The rare earth metal is separated from the extractant metal by vacuum sublimation or distillation.

  7. Thin films of mixed metal compounds

    DOE Patents [OSTI]

    Mickelsen, R.A.; Chen, W.S.

    1985-06-11T23:59:59.000Z

    Disclosed is a thin film heterojunction solar cell, said heterojunction comprising a p-type I-III-IV[sub 2] chalcopyrite substrate and an overlying layer of an n-type ternary mixed metal compound wherein said ternary mixed metal compound is applied to said substrate by introducing the vapor of a first metal compound to a vessel containing said substrate from a first vapor source while simultaneously introducing a vapor of a second metal compound from a second vapor source of said vessel, said first and second metals comprising the metal components of said mixed metal compound; independently controlling the vaporization rate of said first and second vapor sources; reducing the mean free path between vapor particles in said vessel, said gas being present in an amount sufficient to induce homogeneity of said vapor mixture; and depositing said mixed metal compound on said substrate in the form of a uniform composition polycrystalline mixed metal compound. 5 figs.

  8. Metal volatilization and separation during incineration

    SciTech Connect (OSTI)

    Ho, T.C.; Chu, H.W.; Hopper, J.R. (Lamar Univ., Beaumont, TX (United States). Dept. of Chemical Engineering)

    1993-01-01T23:59:59.000Z

    The US Environmental Protection Agency (US EPA) has reported that metals can account for almost all of the identified risks from a thermal treatment process. Fundamental research leading to better understanding of their behavior and improved control of their emissions is greatly needed. This paper reports studies on metal volatilization and separation during incineration. Metal volatilization studies were carried out in two separate experiments. In the first experiment, the dynamic volatilization characteristics of various metals during the combustion of metal-containing wood pellets were investigated in a high-temperature electric furnace. In addition to uncontrolled volatilization, the potential of employing chemical additives to bind metals and prevent them from volatilizing during combustion was also investigated. The second experiment involved the investigation of metal volatilization characteristics during the thermal treatment of metal-contaminated clay in a fluidized bed unit. The metal species tested in both experiments were compounds of lead and cadmium. Metal capture/separation studies were also carried out in two separate experiments. The first involved the use of sorbents in the combustion chamber to capture metals during the fluidized bed incineration of metal-containing wood pellets. The second experiments, however, employed sorbents to absorb metal vapors in a fluidized-bed waste-heat boiler. The objective of both the experiments is to characterize the metal absorption efficiency associated with the processes.

  9. U.S. Department of Energy National Center of Excellence for Metals Recycle

    SciTech Connect (OSTI)

    Adams, V.; Bennett, M.; Bishop, L. [Dept. of Energy, Oak Ridge, TN (United States)] [and others

    1998-05-01T23:59:59.000Z

    The US Department of Energy (DOE) National Center of Excellence for Metals Recycle has recently been established. The vision of this new program is to develop a DOE culture that promotes pollution prevention by considering the recycle and reuse of metal as the first and primary disposition option and burial as a last option. The Center of Excellence takes the approach that unrestricted release of metal is the first priority because it is the most cost-effective disposition pathway. Where this is not appropriate, restricted release, beneficial reuse, and stockpile of ingots are considered. Current recycling activities include the sale of 40,000 tons of scrap metal from the East Tennessee Technology Park (formerly K-25 Plant) K-770 scrap yard, K-1064 surplus equipment and machinery, 7,000 PCB-contaminated drums, 12,000 tons of metal from the Y-l2 scrap yard, and 1,000 metal pallets. In addition, the Center of Excellence is developing a toolbox for project teams that will contain a number of specific tools to facilitate metals recycle. This Internet-based toolbox will include primers, computer programs, and case studies designed to help sites to perform life cycle analysis, perform ALARA (As Low As is Reasonably Achievable) analysis for radiation exposures, provide pollution prevention information and documentation, and produce independent government estimates. The use of these tools is described for two current activities: disposition of scrap metal in the Y-12 scrapyard, and disposition of PCB-contaminated drums.

  10. Cadmium, copper, and lead in soils and garden produce near a metal smelter at Flin Flon, Manitoba

    SciTech Connect (OSTI)

    Pip, E. (Univ. of Winnipeg, Manitoba (Canada))

    1991-05-01T23:59:59.000Z

    Towns in the vicinity of base metal smelters are subject to contamination from atmospheric fallout containing heavy metals. Many smelters have been in operation for decades, and have resulted in substantial accumulation of metals in the surrounding soils. Metal contamination of edible vegetation near mines and smelters has been the source of health concerns in a number of countries. One smelter that has operated for more than half a century is located at Flin Flon, Manitoba. Many Flin Flon residents utilize home vegetable gardens year after year. However little is known regarding heavy metal contamination of locally grown garden produce. Since food can contribute as much as 90% of total body uptake of metals it is important to identify any sources which may account for the disproportionate share. The objective of the present study was to examine concentrations of cadmium, copper and lead in soils and garden produce in the vicinity of the Flin Flon smelter.

  11. Metallization and insulization during impact

    SciTech Connect (OSTI)

    Gilman, J.J.

    1992-10-01T23:59:59.000Z

    It is pointed out that the large strains produced by hypervelocity impacts can be expected to produce dramatic changes in the chemical bonding (electronic structures) of materials. This will change the mechanical behavior towards increased ductility when a semiconductor is compressed until it becomes metallic; and towards increased brittleness when a transition metal is expanded so as to localize its d-band electrons. Both isotropic compression (expansion) and shear strains can cause these transformations. Critical deformation criteria are given based on the observed cubic to tetragonal transformations in compressed semiconductors.

  12. Laser photodeposition of refractory metals

    SciTech Connect (OSTI)

    Solanki, R.; Boyer, P.K.; Mahan, J.E.; Collins, G.J.

    1981-04-01T23:59:59.000Z

    We report the deposition of the refractory metals chromium, molybdenum, and tungsten through the laser-induced gas-phase photolysis of their respective hexacarbonyls. A copper, hollow cathode laser was used at ultraviolet wavelengths matched to peaks in the absorption spectra of the carbonyl molecules. Localized room-temperature metal deposition was achieved by focusing the beam into a cell containing the carbonyl gas and helium as a buffer. No major differences were noted for deposition on a polished silicon wafer, a thermally oxidized silicon wafer, and a quartz flat.

  13. Photobiomolecular metallic particles and films

    DOE Patents [OSTI]

    Hu, Zhong-Cheng

    2003-05-06T23:59:59.000Z

    The method of the invention is based on the unique electron-carrying function of a photocatalytic unit such as the photosynthesis system I (PSI) reaction center of the protein-chlorophyll complex isolated from chloroplasts. The method employs a photo-biomolecular metal deposition technique for precisely controlled nucleation and growth of metallic clusters/particles, e.g., platinum, palladium, and their alloys, etc., as well as for thin-film formation above the surface of a solid substrate. The photochemically mediated technique offers numerous advantages over traditional deposition methods including quantitative atom deposition control, high energy efficiency, and mild operating condition requirements.

  14. Thermal barrier and overlay coating systems comprising composite metal/metal oxide bond coating layers

    DOE Patents [OSTI]

    Goedjen, John G. (Oviedo, FL); Sabol, Stephen M. (Orlando, FL); Sloan, Kelly M. (Longwood, FL); Vance, Steven J. (Orlando, FL)

    2001-01-01T23:59:59.000Z

    The present invention generally describes multilayer coating systems comprising a composite metal/metal oxide bond coat layer. The coating systems may be used in gas turbines.

  15. Metal oxide and metal fluoride nanostructures and methods of making same

    DOE Patents [OSTI]

    Wong, Stanislaus S. (Stony Brook, NY); Mao, Yuanbing (Los Angeles, CA)

    2009-08-18T23:59:59.000Z

    The present invention includes pure single-crystalline metal oxide and metal fluoride nanostructures, and methods of making same. These nanostructures include nanorods and nanoarrays.

  16. THE METALLICITY DEPENDENCE OF THE CEPHEID P – L RELATION IN M101

    SciTech Connect (OSTI)

    Mager, Violet A.; Madore, Barry F.; Freedman, Wendy L., E-mail: mager@susqu.edu, E-mail: barry@obs.carnegiescience.edu, E-mail: wendy@obs.carnegiescience.edu [Carnegie Observatories, 813 Santa Barbara Street, Pasadena, CA 91101 (United States)

    2013-11-01T23:59:59.000Z

    The impact of metallicity on the Cepheid period-luminosity (P – L) relation is investigated using Hubble Space Telescope Advanced Camera for Surveys V and I images of M101. Variations in the reddening-free Wesenheit parameter (W), which is employed as a proxy for luminosity, are examined as a function of the radial distance from the center of M101 (and thus metallicity). We determine that there is no dependence of the slope on metallicity. However, the intercept is found to depend on metallicity by ?{sub VI} = –0.33 ± 0.12 mag dex{sup –1} and ?{sub VI} = –0.71 ± 0.17 mag dex{sup –1} using 2? and 3? rejection criteria, respectively. Sigma-clipping impacts the derived metallicity dependence, and the 2? criterion applied likely mitigates blending, particularly in the crowded inner regions of M101. A metallicity-corrected distance for M101 is obtained from 619 Cepheids (? = 28.96 ± 0.11), a result that agrees with the recently determined SN Ia distance. The metallicity effects described can be bypassed by working at near and mid-infrared wavelengths (e.g., the Carnegie Hubble Program)

  17. The History of Metals and Ceramics Division

    SciTech Connect (OSTI)

    Craig, D.F.

    1999-01-01T23:59:59.000Z

    The division was formed in 1946 at the suggestion of Dr. Eugene P. Wigner to attack the problem of the distortion of graphite in the early reactors due to exposure to reactor neutrons, and the consequent radiation damage. It was called the Metallurgy Division and assembled the metallurgical and solid state physics activities of the time which were not directly related to nuclear weapons production. William A. Johnson, a Westinghouse employee, was named Division Director in 1946. In 1949 he was replaced by John H Frye Jr. when the Division consisted of 45 people. He was director during most of what is called the Reactor Project Years until 1973 and his retirement. During this period the Division evolved into three organizational areas: basic research, applied research in nuclear reactor materials, and reactor programs directly related to a specific reactor(s) being designed or built. The Division (Metals and Ceramics) consisted of 204 staff members in 1973 when James R. Weir, Jr., became Director. This was the period of the oil embargo, the formation of the Energy Research and Development Administration (ERDA) by combining the Atomic Energy Commission (AEC) with the Office of Coal Research, and subsequent formation of the Department of Energy (DOE). The diversification process continued when James O. Stiegler became Director in 1984, partially as a result of the pressure of legislation encouraging the national laboratories to work with U.S. industries on their problems. During that time the Division staff grew from 265 to 330. Douglas F. Craig became Director in 1992.

  18. On q-deformed Stirling numbers

    E-Print Network [OSTI]

    Yilmaz Simsek

    2007-11-03T23:59:59.000Z

    The purpose of this article is to introduce q-deformed Stirling numbers of the first and second kinds. Relations between these numbers, Riemann zeta function and q-Bernoulli numbers of higher order are given. Some relations related to the classical Stirling numbers and Bernoulli numbers of higher order are found. By using derivative operator to the generating function of the q-deformed Stirling numbers of the second kinds, a new function is defined which interpolates the q-deformed Stirling numbers of the second kinds at negative integers. The recurrence relations of the Stirling numbers of the first and second kind are given. In addition, relation between q-deformed Stirling numbers and q-Bell numbers is obtained.

  19. Composite Metal-hydrogen Electrodes for Metal-Hydrogen Batteries

    SciTech Connect (OSTI)

    Ruckman, M W; Wiesmann, H; Strongin, M; Young, K; Fetcenko, M

    1997-04-01T23:59:59.000Z

    The purpose of this project is to develop and conduct a feasibility study of metallic thin films (multilayered and alloy composition) produced by advanced sputtering techniques for use as anodes in Ni-metal hydrogen batteries. The anodes could be incorporated in thin film solid state Ni-metal hydrogen batteries that would be deposited as distinct anode, electrolyte and cathode layers in thin film devices. The materials could also be incorporated in secondary consumer batteries (i.e. type AF(4/3 or 4/5)) which use electrodes in the form of tapes. The project was based on pioneering studies of hydrogen uptake by ultra-thin Pd-capped metal-hydrogen ratios exceeding and fast hydrogen charging and Nb films, these studies suggested that materials with those of commercially available metal hydride materials discharging kinetics could be produced. The project initially concentrated on gas phase and electrochemical studies of Pd-capped niobium films in laboratory-scale NiMH cells. This extended the pioneering work to the wet electrochemical environment of NiMH batteries and exploited advanced synchrotron radiation techniques not available during the earlier work to conduct in-situ studies of such materials during hydrogen charging and discharging. Although batteries with fast charging kinetics and hydrogen-metal ratios approaching unity could be fabricated, it was found that oxidation, cracking and corrosion in aqueous solutions made pure Nb films-and multiiayers poor candidates for battery application. The project emphasis shifted to alloy films based on known elemental materials used for NiMH batteries. Although commercial NiMH anode materials contain many metals, it was found that 0.24 µm thick sputtered Zr-Ni films cycled at least 50 times with charging efficiencies exceeding 95% and [H]/[M] ratios of 0.7-1.0. Multilayered or thicker Zr-Ni films could be candidates for a thin film NiMH battery that may have practical applications as an integrated power source for modern electronic devices.

  20. Method for producing metal oxide nanoparticles

    DOE Patents [OSTI]

    Phillips, Jonathan (Santa Fe, NM); Mendoza, Daniel (Santa Fe, NM); Chen, Chun-Ku (Albuquerque, NM)

    2008-04-15T23:59:59.000Z

    Method for producing metal oxide nanoparticles. The method includes generating an aerosol of solid metallic microparticles, generating plasma with a plasma hot zone at a temperature sufficiently high to vaporize the microparticles into metal vapor, and directing the aerosol into the hot zone of the plasma. The microparticles vaporize in the hot zone into metal vapor. The metal vapor is directed away from the hot zone and into the cooler plasma afterglow where it oxidizes, cools and condenses to form solid metal oxide nanoparticles.

  1. Metal Cooling in Simulations of Cosmic Structure Formation

    E-Print Network [OSTI]

    Britton D. Smith; Steinn Sigurdsson; Tom Abel

    2008-01-03T23:59:59.000Z

    The addition of metals to any gas can significantly alter its evolution by increasing the rate of radiative cooling. In star-forming environments, enhanced cooling can potentially lead to fragmentation and the formation of low-mass stars, where metal-free gas-clouds have been shown not to fragment. Adding metal cooling to numerical simulations has traditionally required a choice between speed and accuracy. We introduce a method that uses the sophisticated chemical network of the photoionization software, Cloudy, to include radiative cooling from a complete set of metals up to atomic number 30 (Zn) that can be used with large-scale three-dimensional hydrodynamic simulations. Our method is valid over an extremely large temperature range (10 K 10^-4 Zsun, regions of density and temperature exist where gas is both thermally unstable and has a cooling time less than its dynamical time. We identify these doubly unstable regions as the most inducive to fragmentation. At high redshifts, the CMB inhibits efficient cooling at low temperatures and, thus, reduces the size of the doubly unstable regions, making fragmentation more difficult.

  2. Periodic relativity: basic framework of the theory

    E-Print Network [OSTI]

    Vikram H. Zaveri

    2014-11-25T23:59:59.000Z

    An alternative gravity theory is proposed which does not rely on Riemannian geometry and geodesic trajectories. The theory named periodic relativity (PR) does not use the weak field approximation and allows every two body system to deviate differently from the flat Minkowski metric. PR differs from general relativity (GR) in predictions of the proper time intervals of distant objects. PR proposes a definite connection between the proper time interval of an object and gravitational frequency shift of its constituent particles as the object travels through the gravitational field. PR is based on the dynamic weak equivalence principle which equates the gravitational mass with the relativistic mass. PR provides very accurate solutions for the Pioneer anomaly and the rotation curves of galaxies outside the framework of general relativity. PR satisfies Einstein's field equations with respect to the three major GR tests within the solar system and with respect to the derivation of Friedmann equation in cosmology. This article defines the underlying framework of the theory.

  3. DO PERIODICITIES IN EXTINCTION-WITH POSSIBLE ASTRONOMICAL CONNECTIONS-SURVIVE A REVISION OF THE GEOLOGICAL TIMESCALE?

    SciTech Connect (OSTI)

    Melott, Adrian L. [Department of Physics and Astronomy, University of Kansas, Lawrence, KS 66045 (United States); Bambach, Richard K. [Department of Paleobiology, National Museum of Natural History, Smithsonian Institution, P.O. Box 37012, MRC 121, Washington, DC 20013-7012 (United States)

    2013-08-10T23:59:59.000Z

    A major revision of the geological timescale was published in 2012. We re-examine our past finding of a 27 Myr periodicity in marine extinction rates by re-assigning dates to the extinction data used previously. We find that the spectral power in this period is somewhat increased, and persists at a narrow bandwidth, which supports our previous contention that the Nemesis hypothesis is untenable as an explanation for the periodicity that was first noted by Raup and Sepkoski in the 1980s. We enumerate a number of problems in a recent study comparing extinction rates with time series models.

  4. Verification Challenges at Low Numbers

    SciTech Connect (OSTI)

    Benz, Jacob M.; Booker, Paul M.; McDonald, Benjamin S.

    2013-06-01T23:59:59.000Z

    Many papers have dealt with the political difficulties and ramifications of deep nuclear arms reductions, and the issues of “Going to Zero”. Political issues include extended deterrence, conventional weapons, ballistic missile defense, and regional and geo-political security issues. At each step on the road to low numbers, the verification required to ensure compliance of all parties will increase significantly. Looking post New START, the next step will likely include warhead limits in the neighborhood of 1000 . Further reductions will include stepping stones at1000 warheads, 100’s of warheads, and then 10’s of warheads before final elimination could be considered of the last few remaining warheads and weapons. This paper will focus on these three threshold reduction levels, 1000, 100’s, 10’s. For each, the issues and challenges will be discussed, potential solutions will be identified, and the verification technologies and chain of custody measures that address these solutions will be surveyed. It is important to note that many of the issues that need to be addressed have no current solution. In these cases, the paper will explore new or novel technologies that could be applied. These technologies will draw from the research and development that is ongoing throughout the national laboratory complex, and will look at technologies utilized in other areas of industry for their application to arms control verification.

  5. Heat-Pipe Development for Advanced Energy Transport Concepts Final Report Covering the Period January 1999 through September 2001

    SciTech Connect (OSTI)

    R.S.Reid; J.F.Sena; A.L.Martinez

    2002-10-01T23:59:59.000Z

    This report summarizes work in the Heat-pipe Technology Development for the Advanced Energy Transport Concepts program for the period January 1999 through September 2001. A gas-loaded molybdenum-sodium heat pipe was built to demonstrate the active pressure-control principle applied to a refractory metal heat pipe. Other work during the period included the development of processing procedures for and fabrication and testing of three types of sodium heat pipes using Haynes 230, MA 754, and MA 956 wall materials to assess the compatibility of these materials with sodium. Also during this period, tests were executed to measure the response of a sodium heat pipe to the penetration of water.

  6. SciTech Connect: Metal-Organic Framework Templated Inorganic...

    Office of Scientific and Technical Information (OSTI)

    Metal-Organic Framework Templated Inorganic Sorbents for Rapid and Efficient Extraction of Heavy Metals Citation Details In-Document Search Title: Metal-Organic Framework Templated...

  7. Cobalt discovery replaces precious metals as industrial catalyst

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    develop alternatives to the precious metal catalysts by using relatively inexpensive, earth-abundant metals. The chemical complexities of the more common metals have made this...

  8. CEQ Extends Comment Period on Revised Draft Guidance on Consideration...

    Broader source: Energy.gov (indexed) [DOE]

    comment period on its revised draft guidance on consideration of greenhouse gas (GHG) emissions and the effects of climate change in NEPA reviews. The comment period now ends on...

  9. Transition Period High Water Marks - May 2009.indd

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the Contract High Water Mark (CHWM) contracts in May 2009, BPA is publishing initial Transition Period High Water Marks (THWMs) and Above-Rate-Period High Water Mark (Above-RHWM)...

  10. Orbital stability of periodic waves for the nonlinear Schrodinger equation

    E-Print Network [OSTI]

    Gallay, Thierry

    Orbital stability of periodic waves for the nonlinear SchrË?odinger equation Thierry Gallay Institut: Thierry Gallay, Thierry.Gallay@ujf­grenoble.fr Keywords: Nonlinear SchrË?odinger equation, periodic waves

  11. Orbital stability of periodic waves for the nonlinear Schrodinger equation

    E-Print Network [OSTI]

    Orbital stability of periodic waves for the nonlinear Schr¨odinger equation Thierry Gallay Institut: Thierry Gallay, Thierry.Gallay@ujf-grenoble.fr Keywords: Nonlinear Schr¨odinger equation, periodic waves

  12. Orbital stability of periodic waves for the nonlinear Schrodinger equation

    E-Print Network [OSTI]

    Boyer, Edmond

    Orbital stability of periodic waves for the nonlinear Schr¨odinger equation Thierry Gallay Institut: Thierry Gallay, Thierry.Gallay@ujf-grenoble.fr Keywords: Nonlinear Schr¨odinger equation, periodic waves

  13. Corrosion resistant metallic bipolar plate

    DOE Patents [OSTI]

    Brady, Michael P. (Oak Ridge, TN); Schneibel, Joachim H. (Knoxville, TN); Pint, Bruce A. (Knoxville, TN); Maziasz, Philip J. (Oak Ridge, TN)

    2007-05-01T23:59:59.000Z

    A corrosion resistant, electrically conductive component such as a bipolar plate for a PEM fuel cell includes 20 55% Cr, balance base metal such as Ni, Fe, or Co, the component having thereon a substantially external, continuous layer of chromium nitride.

  14. Transition metal sulfide loaded catalyst

    DOE Patents [OSTI]

    Maroni, V.A.; Iton, L.E.; Pasterczyk, J.W.; Winterer, M.; Krause, T.R.

    1994-04-26T23:59:59.000Z

    A zeolite-based catalyst is described for activation and conversion of methane. A zeolite support includes a transition metal (Mo, Cr or W) sulfide disposed within the micropores of the zeolite. The catalyst allows activation and conversion of methane to C[sub 2]+ hydrocarbons in a reducing atmosphere, thereby avoiding formation of oxides of carbon.

  15. Material accountancy for metallic fuel pin casting

    SciTech Connect (OSTI)

    Bucher, R.G.; Orechwa, Y.; Beitel, J.C.

    1995-08-01T23:59:59.000Z

    The operation of the Fuel Conditioning Facility (FCF) is based on the electrometallurgical processing of spent metallic reactor fuel. The pin casting operation, although only one of several operations in FCF, was the first to be on-line. As such, it has served to demonstrate the material accountancy system in many of its facets. This paper details, for the operation of the pin casting process with depleted uranium, the interaction between the mass tracking system (MTG) and some of the ancillary computer codes which generate pertinent information for operations and material accountancy. It is necessary to distinguish between two types of material balance calculations -- closeout for operations and material accountancy for safeguards. The two have much in common, for example, the mass tracking system database and the calculation of an inventory difference, but, in general, are not congruent with regard to balance period and balance spatial domain. Moreover, the objective, assessment, and reporting requirements of the calculated inventory difference are very different in the two cases.

  16. Free electron properties of metals under ultrafast laser-induced electron-phonon nonequilibrium: a first-principles study

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Free electron properties of metals under ultrafast laser-induced electron-phonon nonequilibrium modelled based on the free electron classical theory, the free electron number is a key parameter. However or delocalized electronic states, temperature dependent free electron numbers are evaluated for a series

  17. Focusing-to-defocusing crossover in nonlinear periodic structures

    E-Print Network [OSTI]

    Focusing-to-defocusing crossover in nonlinear periodic structures Francis H. Bennet,* Inés A. Amuli

  18. Grant Title: INNOVATIVE TECHNOLOGY EXPERIENCES FOR STUDENTS AND TEACHERS (ITEST) Funding Opportunity Number: NSF 12-597. CFDA Number(s): 47.076.

    E-Print Network [OSTI]

    Farritor, Shane

    Opportunity Number: NSF 12-597. CFDA Number(s): 47.076. Agency/Department: National Science Foundation

  19. Gas adsorption on metal-organic frameworks

    DOE Patents [OSTI]

    Willis, Richard R. (Cary, IL); Low, John J. (Schaumburg, IL), Faheem, Syed A. (Huntley, IL); Benin, Annabelle I. (Oak Forest, IL); Snurr, Randall Q. (Evanston, IL); Yazaydin, Ahmet Ozgur (Evanston, IL)

    2012-07-24T23:59:59.000Z

    The present invention involves the use of certain metal organic frameworks that have been treated with water or another metal titrant in the storage of carbon dioxide. The capacity of these frameworks is significantly increased through this treatment.

  20. Postsynthetic modification of metal-organic frameworks

    E-Print Network [OSTI]

    Tanabe, Kristine Kimie

    2011-01-01T23:59:59.000Z

    S. M. "Tuning Hydrogen Sorption Properties of Metal-OrganicS. M. "Tuning Hydrogen Sorption Properties of Metal-OrganicA summary of hydrogen sorption properties of three distinct

  1. Aspects of the mechanics of metallic glasses

    E-Print Network [OSTI]

    Henann, David Lee

    2011-01-01T23:59:59.000Z

    Metallic glasses are amorphous materials that possess unique mechanical properties, such as high tensile strengths and good fracture toughnesses. Also, since they are amorphous, metallic glasses exhibit a glass transition, ...

  2. NANO - "Green" metal oxides ... | ornl.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    "Green" metal oxides ... Water and nano-sized particles isolated from trees, plants and algae are the ingredients of a new recipe for low-cost metal oxides that are widely used in...

  3. CORROSION OF METALS IN OIL SHALE ENVIRONMENTS

    E-Print Network [OSTI]

    Bellman Jr., R.

    2012-01-01T23:59:59.000Z

    CORROSION OF METALS IN OIL SHALE ENVIRONMENTS A. Levy and R.of Metals in In-Situ Oil Shale Retorts," NACE Corrosion 80,Corrosion of Oil Shale Retort Component Materials," LBL-

  4. Metal salen catalyzed production of polytrimethylene carbonate

    E-Print Network [OSTI]

    Ganguly, Poulomi

    2009-06-02T23:59:59.000Z

    of Lewis acidic metal salen complexes (Al & Sn), as catalysts for this process. This was followed by the utilization of metal salen complexes of biometals as catalysts for the synthesis of these biodegradable polymers, as well as for the copolymerization...

  5. CORROSION OF METALS IN OIL SHALE ENVIRONMENTS

    E-Print Network [OSTI]

    Bellman Jr., R.

    2012-01-01T23:59:59.000Z

    CORROSION OF METALS IN OIL SHALE ENVIRONMENTS A. Levy and R.of Metals in In-Situ Oil Shale Retorts," NACE Corrosion 80,Elevated Temperature Corrosion of Oil Shale Retort Component

  6. Steady periodic waves bifurcating for fixed-depth rotational flows

    E-Print Network [OSTI]

    consider steady periodic water waves for rotational flows with a specified fixed-depth over a flat bed. We the existence of steady periodic water waves for rotational flows with a specified fixed depth over a flat bedSteady periodic waves bifurcating for fixed-depth rotational flows David Henry School

  7. Periodically poled silicon Nick K. Hon,a

    E-Print Network [OSTI]

    Jalali. Bahram

    as quasi-phase matching. Periodically poled silicon PePSi adds the periodic poling capability to silicon to be harnessed for devices based on second-order nonlinear effects. As an example of the utility of the PePSi is in effect, periodically poled silicon PePSi , a new technology for efficient second-order nonlinear

  8. Jitter-Approximation Tradeoff for Periodic Scheduling Zvika Brakerski

    E-Print Network [OSTI]

    Patt-Shamir, Boaz

    Jitter-Approximation Tradeoff for Periodic Scheduling Zvika Brakerski Dept. of Electrical the average period of a job in the schedule is blown up w.r.t. its requested period, and the jitter ratio with low jitter ratio allow the mobile devices to save power by hav- ing their receivers switched off

  9. Period-luminosity and period-luminosity-colour relations for Mira variables at maximum light

    E-Print Network [OSTI]

    S. M. Kanbur; M. A. Hendry; D. Clarke

    1997-04-14T23:59:59.000Z

    In this paper we confirm the existence of period-luminosity (PL) and period-luminosity-colour (PLC) relations at maximum light for O and C Mira variables in the LMC. We demonstrate that in the J and H bands the maximum light PL relations have a significantly smaller dispersion than their counterparts at mean light, while the K band and bolometric PL relations have a dispersion comparable to that at mean light. In the J, H and K bands the fitted PL relations for the O Miras are found to have smaller dispersion than those for the C Miras, at both mean and maximum light, while the converse is true for the relations based on bolometric magnitudes. The inclusion of a non-zero log period term is found to be highly significant in all cases except that of the C Miras in the J band, for which the data are found to be consistent with having constant absolute magnitude. This suggests the possibility of employing C Miras as standard candles. We suggest both a theoretical justification for the existence of Mira PL relations at maximum light and a possible explanation of why these relations should have a smaller dispersion than at mean light. The existence of such maximum light relations offers the possibility of extending the range and improving the accuracy of the Mira distance scale to Galactic globular clusters and to other galaxies.

  10. A KECK HIRES DOPPLER SEARCH FOR PLANETS ORBITING METAL-POOR DWARFS. II. ON THE FREQUENCY OF GIANT PLANETS IN THE METAL-POOR REGIME

    SciTech Connect (OSTI)

    Sozzetti, Alessandro; Torres, Guillermo; Latham, David W.; Stefanik, Robert P.; Korzennik, Sylvain G. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Boss, Alan P. [Department of Terrestrial Magnetism, Carnegie Institution of Washington, 5241 Broad Branch Road, NW, Washington, DC 20015 (United States); Carney, Bruce W. [Department of Physics and Astronomy, University of North Carolina at Chapel Hill, Chapel Hill, NC 27599 (United States); Laird, John B. [Department of Physics and Astronomy, Bowling Green State University, Bowling Green, OH 43403 (United States)], E-mail: asozzett@cfa.harvard.edu, E-mail: gtorres@cfa.harvard.edu, E-mail: dlatham@cfa.harvard.edu, E-mail: skorzennik@cfa.harvard.edu, E-mail: rstefanik@cfa.harvard.edu, E-mail: boss@dtm.ciw.edu, E-mail: bruce@physics.unc.edu, E-mail: laird@bgsu.edu

    2009-05-20T23:59:59.000Z

    We present an analysis of three years of precision radial velocity (RV) measurements of 160 metal-poor stars observed with HIRES on the Keck 1 telescope. We report on variability and long-term velocity trends for each star in our sample. We identify several long-term, low-amplitude RV variables worthy of followup with direct imaging techniques. We place lower limits on the detectable companion mass as a function of orbital period. Our survey would have detected, with a 99.5% confidence level, over 95% of all companions on low-eccentricity orbits with velocity semiamplitude K {approx}> 100 m s{sup -1}, or M{sub p} sin i {approx}> 3.0 M {sub J}(P/yr){sup (1/3)}, for orbital periods P {approx}< 3 yr. None of the stars in our sample exhibits RV variations compatible with the presence of Jovian planets with periods shorter than the survey duration. The resulting average frequency of gas giants orbiting metal-poor dwarfs with -2.0{approx}<[Fe/H]{approx}<-0.6 is f{sub p} < 0.67% (at the 1{sigma} confidence level). We examine the implications of this null result in the context of the observed correlation between the rate of occurrence of giant planets and the metallicity of their main-sequence solar-type stellar hosts. By combining our data set with the Fischer and Valenti (2005) uniform sample, we confirm that the likelihood of a star to harbor a planet more massive than Jupiter within 2 AU is a steeply rising function of the host's metallicity. However, the data for stars with -1.0{approx}<[Fe/H]{approx}<0.0 are compatible, in a statistical sense, with a constant occurrence rate f{sub p} {approx_equal} 1%. Our results can usefully inform theoretical studies of the process of giant-planet formation across two orders of magnitude in metallicity.

  11. Prime number generation and factor elimination

    E-Print Network [OSTI]

    Vineet Kumar

    2014-10-06T23:59:59.000Z

    We have presented a multivariate polynomial function termed as factor elimination function,by which, we can generate prime numbers. This function's mapping behavior can explain the irregularities in the occurrence of prime numbers on the number line. Generally the different categories of prime numbers found till date, satisfy the form of this function. We present some absolute and probabilistic conditions for the primality of the number generated by this method. This function is capable of leading to highly efficient algorithms for generating prime numbers.

  12. Europium Isotopic Abundances in Very Metal-poor Stars

    E-Print Network [OSTI]

    Christopher Sneden; John J. Cowan; James E. Lawler; Scott Burles; Timothy C. Beers; George M. Fuller

    2002-01-28T23:59:59.000Z

    Europium isotopic abundance fractions are reported for the very metal-poor, neutron-capture-rich giant stars CS 22892-052, HD 115444, and BD +17 3248. The abundance fractions, derived from analysis of several strong Eu II lines appearing in high-resolution spectra of these stars, are in excellent agreement with each other and with their values in the Solar System: fraction(\\iso{Eu}{151}) ~= fraction(\\iso{Eu}{153}) ~= 0.5. Detailed abundance studies of very metal-poor stars have previously shown that the total elemental abundances of stable atoms with atomic numbers z >= 56 typically match very closely those of a scaled solar-system r-process abundance distribution. The present results for the first time extend this agreement to the isotopic level.

  13. Preparation of metal-triazolate frameworks

    DOE Patents [OSTI]

    Yaghi, Omar M; Uribe-Romo, Fernando J; Gandara-Barragan, Felipe; Britt, David K

    2014-10-07T23:59:59.000Z

    The disclosure provides for novel metal-triazolate frameworks, methods of use thereof, and devices comprising the frameworks thereof.

  14. Spectroscopic studies of metal growth on oxides

    E-Print Network [OSTI]

    Luo, Kai

    2000-01-01T23:59:59.000Z

    : Chemistry SPECTROSCOPIC STUDIES OF METAL GROWTH ON OXIDES A Thesis by KAI LUO Submitted to Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE Approved as to style a d content by: avid W. Goodman.... , Jilin University, P. R. China Chair of Advisory Committee: Dr, David W. Goodman Metal/oxide chemistry and metal cluster growth on oxides are fundamental to our understanding of the catalytic activity and selectivity of metal catalysts, thus...

  15. Sintering and ripening resistant noble metal nanostructures

    DOE Patents [OSTI]

    van Swol, Frank B; Song, Yujiang; Shelnutt, John A; Miller, James E; Challa, Sivakumar R

    2013-09-24T23:59:59.000Z

    Durable porous metal nanostructures comprising thin metal nanosheets that are metastable under some conditions that commonly produce rapid reduction in surface area due to sintering and/or Ostwald ripening. The invention further comprises the method for making such durable porous metal nanostructures. Durable, high-surface area nanostructures result from the formation of persistent durable holes or pores in metal nanosheets formed from dendritic nanosheets.

  16. Analysis of electromagnetic scattering by nearly periodic structures: an LDRD report.

    SciTech Connect (OSTI)

    Johnson, William Arthur; Warne, Larry Kevin; Jorgenson, Roy Eberhardt; Wilton, Donald R. (University of Houston, Houston, TX); Basilio, Lorena I.; Peters, David William; Capolino, F. (University of Houston, Houston, TX)

    2006-10-01T23:59:59.000Z

    In this LDRD we examine techniques to analyze the electromagnetic scattering from structures that are nearly periodic. Nearly periodic could mean that one of the structure's unit cells is different from all the others--a defect. It could also mean that the structure is truncated, or butted up against another periodic structure to form a seam. Straightforward electromagnetic analysis of these nearly periodic structures requires us to grid the entire structure, which would overwhelm today's computers and the computers in the foreseeable future. In this report we will examine various approximations that allow us to continue to exploit some aspects of the structure's periodicity and thereby reduce the number of unknowns required for analysis. We will use the Green's Function Interpolation with a Fast Fourier Transform (GIFFT) to examine isolated defects both in the form of a source dipole over a meta-material slab and as a rotated dipole in a finite array of dipoles. We will look at the numerically exact solution of a one-dimensional seam. In order to solve a two-dimensional seam, we formulate an efficient way to calculate the Green's function of a 1d array of point sources. We next formulate ways of calculating the far-field due to a seam and due to array truncation based on both array theory and high-frequency asymptotic methods. We compare the high-frequency and GIFFT results. Finally, we use GIFFT to solve a simple, two-dimensional seam problem.

  17. subcollector Schottky collector contact & interconnect metals

    E-Print Network [OSTI]

    Rodwell, Mark J. W.

    base collector depletion layer subcollector ohmic metal (a) base collector depletion layer Schottky metal base emitter collector collector We emitter base emitter emitter We Wc Wc (b) Schottky collector contact & interconnect metals Emitter & collector Ohmics undoped collector depletion layer base N

  18. Process for making transition metal nitride whiskers

    DOE Patents [OSTI]

    Bamberger, Carlos E. (Oak Ridge, TN)

    1989-01-01T23:59:59.000Z

    A process for making metal nitrides, particularly titanium nitride whiskers, using a cyanide salt as a reducing agent for a metal compound in the presence of an alkali metal oxide. Sodium cyanide, various titanates and titanium oxide mixed with sodium oxide react to provide titanium nitride whiskers that can be used as reinforcement to ceramic composites.

  19. Process for making transition metal nitride whiskers

    DOE Patents [OSTI]

    Bamberger, C.E.

    1988-04-12T23:59:59.000Z

    A process for making metal nitrides, particularly titanium nitride whiskers, using a cyanide salt as a reducing agent for a metal compound in the presence of an alkali metal oxide. Sodium cyanide, various titanates and titanium oxide mixed with sodium oxide react to provide titanium nitride whiskers that can be used as reinforcement to ceramic composites. 1 fig., 1 tab.

  20. Imestigation ol" Maenons in Rare Earth Metals

    E-Print Network [OSTI]

    Imestigation ol" Maenons in Rare Earth Metals b\\ Inelastic Neutron Scattering tL Bjerrum Moiler #12;BLANK PAGE #12;Riso Report No. 178 Investigation of Magnons in Rare Earth Metals by Inelastic NeutronN LANGF h. a. dec. #12;Contents Page PREFACE 7 I. INTRODUCTION *> 1. Magnetism of Rare Earth Metals 10 2

  1. Method for decontamination of radioactive metal surfaces

    DOE Patents [OSTI]

    Bray, L.A.

    1996-08-13T23:59:59.000Z

    Disclosed is a method for removing radioactive contaminants from metal surfaces by applying steam containing an inorganic acid and cerium IV. Cerium IV is applied to contaminated metal surfaces by introducing cerium IV in solution into a steam spray directed at contaminated metal surfaces. Cerium IV solution is converted to an essentially atomized or vapor phase by the steam.

  2. Plasticity of Metal Nanowires Christopher R. Weinberger

    E-Print Network [OSTI]

    Cai, Wei

    Plasticity of Metal Nanowires Christopher R. Weinberger Sandia National Laboratories, Albuquerque-4040 (Dated: November 24, 2011) Abstract The mechanisms of plasticity in metal naowires with diameters below 100 nm are reviewed. At these length scales, plasticity in face-centered-cubic metals subjected

  3. Method for decontamination of radioactive metal surfaces

    DOE Patents [OSTI]

    Bray, Lane A. (Richland, WA)

    1996-01-01T23:59:59.000Z

    Disclosed is a method for removing radioactive contaminants from metal surfaces by applying steam containing an inorganic acid and cerium IV. Cerium IV is applied to contaminated metal surfaces by introducing cerium IV in solution into a steam spray directed at contaminated metal surfaces. Cerium IV solution is converted to an essentially atomized or vapor phase by the steam.

  4. Spectroscopic investigation of metal-RNA interactions

    E-Print Network [OSTI]

    Vogt, Matthew John

    2005-02-17T23:59:59.000Z

    Metal-RNA interactions are important to neutralize the negative charge and aid in correctly folding the RNA. Spectroscopically active metal ions, especially Mn2+, have been used to probe the type of interaction the metal has with RNA. In previous...

  5. Starbursts and their contribution to metal enrichment

    E-Print Network [OSTI]

    Kunth Daniel

    2007-04-28T23:59:59.000Z

    I review the properties of starburst galaxies, compare the properties of the local ones with more distant starburts and examine their role in the metal enrichment of the interstellar medium and the intergalactic-intracluster medium. Metallicity is not an arrow of time and contrary to current belief metal rich galaxies can also be found at high redshift.

  6. Carbon star populations in systems with different metallicities: statistics in Local Group galaxies

    E-Print Network [OSTI]

    M. Mouhcine; A. Lancon

    2002-09-03T23:59:59.000Z

    We present evolutionary population synthesis models for the study of the cool and luminous intermediate age stellar populations in resolved galaxies with particular emphasis on carbon star populations. We study the effects of the star formation history, the age and the metallicity on the populations of intermediate mass stars. In the case of instantaneous bursts, we confirm that lower metallicity results in higher contribution of carbon stars to the total star number, and in higher number ratios of carbon stars to late-type M stars. Chemically consistent models are used to study the effect of the star formation history on the relations between carbon star population properties and global parameters of the parent galaxy (age, metallicity). Our models are able to account, for the first time, for those correlations, as observed in the galaxies of the Local Group. For stellar populations older than 1 Gyr, the properties of carbon star populations are linked to the current metallicity in a way that is quite independent of the star formation scenario. The number of carbon stars to late-type M stars forms a metallicity sequence along which stellar populations with very different star formation histories are found (Abridged).

  7. Adsorption of Chromium (VI) by metal hydroxide sludge from the metal finishing

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Adsorption of Chromium (VI) by metal hydroxide sludge from the metal finishing Loïc Perrin Ecole sludge (MHS) during the treatment of their liquid effluents charged with heavy metals. Generally, a small part of these sludge is valorized because of their important metal fickleness. Consequently

  8. Slag Metal Reactions in Binary CaF2-Metal Oxide Welding Fluxes

    E-Print Network [OSTI]

    Eagar, Thomas W.

    ) Slag Metal Reactions in Binary CaF2-Metal Oxide Welding Fluxes Some otherwise chemically stable fluxes may decompose into suboxides in the presence of welding arcs, thereby providing higher levels of 0 2 in weld metal than those oxides which do not form suboxides ABSTRACT. The stability of metal

  9. Transition metal oxide improves overall efficiency and maintains performance with inexpensive metals.

    E-Print Network [OSTI]

    Transition metal oxide improves overall efficiency and maintains performance with inexpensive that inserting a transition metal oxide (TMO) between the lead sulfide (PbS) quantum dot (QD) layer and the metal-Yu Chen; Octavi E. Semonin; Arthur J. Nozik; Randy J. Ellingson; Matthew C. Beard."n-Type Transition Metal

  10. METAL-NON METAL TRANSITIONS /N RARE EARTH COMPOUNDS. EXPERIMENT AND THEORK /.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    METAL-NON METAL TRANSITIONS /N RARE EARTH COMPOUNDS. EXPERIMENT AND THEORK /. VALENCE INSTABILITIES, superconductivity, electron-phonon and band theory, to name a few. 2. Properties of normal rare earth metals. - Before discussing rare earth valence instabilities, three relevant general features of rare earth metals

  11. Stochastic chemical enrichment in metal-poor systems I. Theory

    E-Print Network [OSTI]

    T. Karlsson

    2005-04-27T23:59:59.000Z

    A stochastic model of the chemical enrichment of metal-poor systems by core-collapse (Type II) supernovae is presented, allowing for large-scale mixing of the enriched material by turbulent motions and cloud collisions in the interstellar medium. Infall of pristine material is taken into account by following the evolution of the gas density in the medium. Analytical expressions were derived for the number of stars enriched by a given number of supernovae, as well as for the amount of mass with which the ejected material from a supernova is mixed before being locked up in a subsequently formed star. It is shown that for reasonable values of the gas density (~0.1 cm-3) and of the supernova rate (~0.25 kpc-3 Myr-1) of the Galactic halo, the resulting metallicity distributions of the extreme Population II stars show a distinct cut-off at [Fe/H] ~= -4. In fact, by assuming no low-mass Population III stars were able to form out of the primordial interstellar medium, the derived fraction of stars below [Fe/H] = -4 is in agreement with observations. Moreover, the probability is high that even the most metal-poor stars observed to date have been enriched by several contributing supernovae. This partly explains the relatively small star-to-star scatter in many chemical-abundance ratios for stars down to [Fe/H] = -4, as recently found in several observational studies. Contribution from the thermonuclear (Type Ia) supernovae is found to be negligible over almost the entire extremely metal-poor regime. (***abridged***)

  12. Electrophilic Metal Alkyl Chemistry in New Ligand Environments

    SciTech Connect (OSTI)

    Jordan, Richard F. [University of Chicago] University of Chicago

    2013-06-30T23:59:59.000Z

    The goals of this project were to design new electrophilic metal alkyl complexes and to exploit these systems in fundamental studies of olefin polymerization and other important and new catalytic reactions. A key target reaction is insertion copolymerization of olefins and polar CH2=CHX vinyl monomers such as vinyl halides and vinyl ethers. During the period covered by this report we (i) investigated the properties of ortho-alkoxy-arylphosphine ligands in Ni-based olefin polymerization catalysts, (ii) studied the synthesis of double-end-capped polyethylene using group 4 metal catalysts that contain tris-pyrazolylborate ligands, (iii) explored the ethylene insertion reactivity of group 4 metal tris-pyrazolyl-borate complexes, (iv) showed that (?-diimine)PdMe{sup +} species undergo multiple insertion of silyl vinyl ethers, (v) synthesized and explored the reactivity of base-free Ni benzyl complexes that contain ortho-phosphino-arene sulfonate ligands, (vi) established the mechanism of the reaction of vinyl chloride with (?-diimine)PdMe{sup +} catalysts, (vii) explored the role of cationic polymerization and insertion chemistry in the reactions of vinyl ethers with (?-diimine)PdMe{sup +} species, (viii) discovered a new class of self-assembled tetranuclear Pd catalysts that produce high molecular weight linear polyethylene and copolymerize ethylene and vinyl fluoride, and (ix) developed model systems that enabled investigation of cis-trans isomerization of {phosphine-sulfonate}Pd(II) complexes.

  13. Changes in worldwide demand for metals (final). Open File report

    SciTech Connect (OSTI)

    Faucett, J.G.; Chmelynski, H.J.

    1986-08-01T23:59:59.000Z

    Worldwide demand for metals was analyzed to identify the important factors that explain differences in the level of demand among world countries. The per capita demand for steel, aluminum, copper, and total nonferrous metals was investigated for 40 to 50 countries over a 22-year period. These countries have been further grouped into four world regions for purposes of making generalizations about the importance of these factors for countries in different stages of development and with dissimilar levels of per capita gross domestic product (GDP). Intercountry and intertemporal differences are explained largely by differences in per capita GDP and changes over time in per capita GDP, oil real prices, and to a lesser extent, metal real prices. The trend in world consumption is dramatically different in the last decade than the previous one. In 1962-73, per capita consumption increased in all areas and consumption intensity (consumption divided by (GDP) increased in most areas). In 1973-84, per capita consumption fell in most areas and intensity fell dramatically, except in developing nations.

  14. Final Report: Metal Perhydrides for Hydrogen Storage

    SciTech Connect (OSTI)

    Hwang, J-Y.; Shi, S.; Hackney, S.; Swenson, D.; Hu, Y.

    2011-07-26T23:59:59.000Z

    Hydrogen is a promising energy source for the future economy due to its environmental friendliness. One of the important obstacles for the utilization of hydrogen as a fuel source for applications such as fuel cells is the storage of hydrogen. In the infrastructure of the expected hydrogen economy, hydrogen storage is one of the key enabling technologies. Although hydrogen possesses the highest gravimetric energy content (142 KJ/g) of all fuels, its volumetric energy density (8 MJ/L) is very low. It is desired to increase the volumetric energy density of hydrogen in a system to satisfy various applications. Research on hydrogen storage has been pursed for many years. Various storage technologies, including liquefaction, compression, metal hydride, chemical hydride, and adsorption, have been examined. Liquefaction and high pressure compression are not desired due to concerns related to complicated devices, high energy cost and safety. Metal hydrides and chemical hydrides have high gravimetric and volumetric energy densities but encounter issues because high temperature is required for the release of hydrogen, due to the strong bonding of hydrogen in the compounds. Reversibility of hydrogen loading and unloading is another concern. Adsorption of hydrogen on high surface area sorbents such as activated carbon and organic metal frameworks does not have the reversibility problem. But on the other hand, the weak force (primarily the van der Waals force) between hydrogen and the sorbent yields a very small amount of adsorption capacity at ambient temperature. Significant storage capacity can only be achieved at low temperatures such as 77K. The use of liquid nitrogen in a hydrogen storage system is not practical. Perhydrides are proposed as novel hydrogen storage materials that may overcome barriers slowing advances to a hydrogen fuel economy. In conventional hydrides, e.g. metal hydrides, the number of hydrogen atoms equals the total valence of the metal ions. One LiH molecule contains one hydrogen atom because the valence of a Li ion is +1. One MgH2 molecule contains two hydrogen atoms because the valence of a Mg ion is +2. In metal perhydrides, a molecule could contain more hydrogen atoms than expected based on the metal valance, i.e. LiH1+n and MgH2+n (n is equal to or greater than 1). When n is sufficiently high, there will be plenty of hydrogen storage capacity to meet future requirements. The existence of hydrogen clusters, Hn+ (n = 5, 7, 9, 11, 13, 15) and transition metal ion-hydrogen clusters, M+(H2)n (n = 1-6), such as Sc(H2)n+, Co(H2)n+, etc., have assisted the development of this concept. Clusters are not stable species. However, their existence stimulates our approach on using electric charges to enhance the hydrogen adsorption in a hydrogen storage system in this study. The experimental and modeling work to verify it are reported here. Experimental work included the generation of cold hydrogen plasma through a microwave approach, synthesis of sorbent materials, design and construction of lab devices, and the determination of hydrogen adsorption capacities on various sorbent materials under various electric field potentials and various temperatures. The results consistently show that electric potential enhances the adsorption of hydrogen on sorbents. NiO, MgO, activated carbon, MOF, and MOF and platinum coated activated carbon are some of the materials studied. Enhancements up to a few hundred percents have been found. In general, the enhancement increases with the electrical potential, the pressure applied, and the temperature lowered. Theoretical modeling of the hydrogen adsorption on the sorbents under the electric potential has been investigated with the density functional theory (DFT) approach. It was found that the interaction energy between hydrogen and sorbent is increased remarkably when an electric field is applied. This increase of binding energy offers a potential solution for DOE when looking for a compromise between chemisorption and physisorption for hydrogen storage. Bonding of chemisorption is too

  15. Periodic eigendecomposition and its application to Kuramoto-Sivashinsky system

    E-Print Network [OSTI]

    Xiong Ding; Predrag Cvitanovi?

    2014-06-18T23:59:59.000Z

    Periodic eigendecomposition algorithm for calculating eigenvectors of a periodic product of a sequence of matrices, an extension of the periodic Schur decomposition, is formulated and compared with the recently proposed covariant vectors algorithms. In contrast to those, periodic eigendecomposition requires no power iteration and is capable of determining not only the real eigenvectors, but also the complex eigenvector pairs. Its effectiveness, and in particular its ability to resolve eigenvalues whose magnitude differs by hundreds of orders, is demonstrated by applying the algorithm to computation of the full linear stability spectrum of periodic solutions of Kuramoto-Sivashinsky system.

  16. Turing's normal numbers: towards randomness Veronica Becher

    E-Print Network [OSTI]

    presumably in 1938 Alan Turing gave an algorithm that produces real numbers normal to every integer base- putable normal numbers, and this result should be attributed to Alan Turing. His manuscript entitled "A

  17. Convection, granulation and period jitter in classical Cepheids

    E-Print Network [OSTI]

    Neilson, Hilding R

    2014-01-01T23:59:59.000Z

    Analyses of recent observations of the sole classical Cepheid in the Kepler field, V1154 Cygni, found random changes of about 30 minutes in the pulsation period. These period changes challenge standard theories of pulsation and evolution because the period change is non-secular, and explaining this period jitter is necessary for understanding stellar evolution and the role of Cepheids as precise standard candles. We suggest that convection and convective hot spots can explain the observed period jitter. Convective hot spots alter the timing of flux maximum and minimum in the Cepheid light curve, hence change the measured pulsation period. We present a model of random hot spots that generate a localized flux excess that perturbs the Cepheid light curve and consequently the pulsation period which is consistent with the observed jitter. This result demonstrates how important understanding convection is for modeling Cepheid stellar structure and evolution, how convection determines the red edge of the instability...

  18. High speed optical quantum random number generation

    E-Print Network [OSTI]

    Weinfurter, Harald

    .3351 (2009). 6. I. Reidler, Y. Aviad, M. Rosenbluh, and I. Kanter, "Ultrahigh-speed random number generation

  19. (Data in thousand metric tons of silicon content unless otherwise noted) Domestic Production and Use: Estimated value of silicon metal and alloys (excluding semiconductor-grade silicon)

    E-Print Network [OSTI]

    metal: Brazil, 37%; South Africa, 25%; Canada, 14%; Norway, 6%; and other, 18%. Total: Brazil, 20%; China, 16%; South Africa, 13%; Canada, 12%; and other, 39%. Tariff: Item Number Normal Trade Relations energy costs. Demand for silicon metal comes primarily from the aluminum and chemical industries

  20. First-principles prediction of redox potentials in transition-metal compounds with LDA+U Department of Physics, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA

    E-Print Network [OSTI]

    Ceder, Gerbrand

    , such as those at which lithium intercalates in transition metal compounds. We argue that this inaccuracy this approach, the experimental lithium intercalation voltages of a number of transition metal compounds corrosion, fuel cells and rechargeable Li batteries, and the ability to study these processes from first

  1. Reactive trace metals in the stratified central North Pacific

    SciTech Connect (OSTI)

    Bruland, K.W. (Univ. of California, Santa Cruz, CA (United States)); Orians, K.J. (Univ. of British Columbia, Vancouver (Canada)); Cowen, J.P. (Univ. of Hawaii, Manoa, HI (United States))

    1994-08-01T23:59:59.000Z

    Vertical concentration profiles of the dissolved and suspended particulate phases were determined for a suite of reactive trace metals, Al, Fe, Mn, Zn, and Cd, during summertime at a station in the center of the North Pacific gyre. During summer the euphotic zone becomes stratified, forming a shallow (0-25 m), oligotrophic, mixed layer overlying a subsurface (25-140 m), strongly-stratified region. The physical, biological, and chemical structure within the euphotic zone during this period enhanced the effect of atmospheric inputs of Al, Fe, and Mn on mixed layer concentrations. For example, the concentration of dissolved Fe in the surface mixed layer was eighteen times that observed at a depth of 100 m. The observed aeolian signature of these metals matched that predicted from estimates of atmospheric input during the period between the onset of stratification and sampling. The distributions of suspended particulate Al, Fe, and Mn all exhibited minima in the euphotic zone and increased with depth into the main thermocline. Particulate Al and Fe were then uniform with depth below 1000 m before increasing in the near bottom nepheloid layer. Average particulate phase concentrations in intermediate and deep waters of the central North Pacific were 1.0, 0.31, and 0.055 nmol[center dot]kg[sup [minus]1] for Al, Fe, and Mn, respectively. The distribution of particulate Cd exhibited a maximum within the subsurface euphotic zone. Particulate zinc also exhibited a surface maximum, albeit a smaller one. Concentrations of particulate Zn and Cd in intermediate and deep waters were 17 and 0.2 pmol[center dot]kg[sup [minus]1]. Substantial interbasin differences in particulate trace metals occur. Concentrations of suspended particulate Al, Fe, and Mn were three to four times lower in the central North Pacific than recently reported for the central North Atlantic gyre, consistent with differences in atmospheric input to these two regions.

  2. Clar number of catacondensed benzenoid hydrocarbons

    E-Print Network [OSTI]

    Klavzar, Sandi

    Clar number of catacondensed benzenoid hydrocarbons Sandi KlavŸzar a,# , Petra Ÿ Zigert a , Ivan hydrocarbon: CL is equal to the minimum number of straight lines required to intersect all hexagons theory; Clar formula; Clar number; Resonance graph; Benzenoid hydrocarbons 1. Introduction Within

  3. Removal of Heavy Metals from Aqueous Systems with Thiol Functionalized...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heavy Metals from Aqueous Systems with Thiol Functionalized Superparamagnetic Nanoparticles. Removal of Heavy Metals from Aqueous Systems with Thiol Functionalized...

  4. BIG METALS, SMALL LIGANDS: CHARACTERIZATION OF THE 15-COORDINATE COMPLEX THORIUM AMINODIBORANATE [Th(H3BN(CH3)2BH3)4

    E-Print Network [OSTI]

    Girolami, Gregory S.

    BIG METALS, SMALL LIGANDS: CHARACTERIZATION OF THE 15- COORDINATE COMPLEX THORIUM AMINODIBORANATE aminodiboranate ligands coordinate to the thorium center. The Werner coordination number of 15 in the solid state

  5. Liquid metal Flow Meter - Final Report

    SciTech Connect (OSTI)

    Andersen, C.; Hoogendoom, S.; Hudson, B.; Prince, J.; Teichert, K.; Wood, J.; Chase, K.

    2007-01-30T23:59:59.000Z

    Measuring the flow of liquid metal presents serious challenges. Current commercially-available flow meters use ultrasonic, electromagnetic, and other technologies to measure flow, but are inadequate for liquid metal flow measurement because of the high temperatures required by most liquid metals. As a result of the reactivity and high temperatures of most liquid metals, corrosion and leakage become very serious safety concerns. The purpose of this project is to develop a flow meter for Lockheed Martin that measures the flow rate of molten metal in a conduit.

  6. CVD of refractory amorphous metal alloys

    SciTech Connect (OSTI)

    Tenhover, M. [The Carborundum Co., Niagara Falls, NY (United States). Technology Div.

    1995-08-01T23:59:59.000Z

    In this work, a novel process is described for the fabrication of multi-metallic amorphous metal alloy coatings using a chemical vapor deposition (CVD) technique. Of special interest in this work are amorphous metal alloys containing Mo and/or Cr which have high crystallization temperatures and readily available low decomposition temperature metal-bearing precursors. The conditions for amorphous alloy formation via CVD are described as well as the chemical properties of these materials. High temperature, aqueous corrosion tests have shown these materials (especially those containing Cr) are among the most corrosion resistant metal alloys known.

  7. Directly susceptible, noncarbon metal ceramic composite crucible

    DOE Patents [OSTI]

    Holcombe, Jr., Cressie E. (Farragut, TN); Kiggans, Jr., James O. (Oak Ridge, TN); Morrow, S. Marvin (Kingston, TN); Rexford, Donald (Pattersonville, NY)

    1999-01-01T23:59:59.000Z

    A sintered metal ceramic crucible suitable for high temperature induction melting of reactive metals without appreciable carbon or silicon contamination of the melt. The crucible comprises a cast matrix of a thermally conductive ceramic material; a perforated metal sleeve, which serves as a susceptor for induction heating of the crucible, embedded within the ceramic cast matrix; and a thermal-shock-absorber barrier interposed between the metal sleeve and the ceramic cast matrix to allow for differential thermal expansions between the matrix and the metal sleeve and to act as a thermal-shock-absorber which moderates the effects of rapid changes of sleeve temperature on the matrix.

  8. Direct electrochemical reduction of metal-oxides

    DOE Patents [OSTI]

    Redey, Laszlo I. (Downers Grove, IL); Gourishankar, Karthick (Downers Grove, IL)

    2003-01-01T23:59:59.000Z

    A method of controlling the direct electrolytic reduction of a metal oxide or mixtures of metal oxides to the corresponding metal or metals. A non-consumable anode and a cathode and a salt electrolyte with a first reference electrode near the non-consumable anode and a second reference electrode near the cathode are used. Oxygen gas is produced and removed from the cell. The anode potential is compared to the first reference electrode to prevent anode dissolution and gas evolution other than oxygen, and the cathode potential is compared to the second reference electrode to prevent production of reductant metal from ions in the electrolyte.

  9. Synthesis of transition metal carbonitrides

    DOE Patents [OSTI]

    Munir, Zuhair A. R. (Davis, CA); Eslamloo-Grami, Maryam (Davis, CA)

    1994-01-01T23:59:59.000Z

    Transition metal carbonitrides (in particular, titanium carbonitride, TiC.sub.0.5 N.sub.0.5) are synthesized by a self-propagating reaction between the metal (e.g., titanium) and carbon in a nitrogen atmosphere. Complete conversion to the carbonitride phase is achieved with the addition of TiN as diluent and with a nitrogen pressure .gtoreq.0.6 MPa. Thermodynamic phase-stability calculations and experimental characterizations of quenched samples provided revealed that the mechanism of formation of the carbonitride is a two-step process. The first step involves the formation of the nonstoichiometric carbide, TiC.sub.0.5, and is followed by the formation of the product by the incorporation of nitrogen in the defect-structure carbide.

  10. Amorphous metal alloy and composite

    DOE Patents [OSTI]

    Wang, Rong (Richland, WA); Merz, Martin D. (Richland, WA)

    1985-01-01T23:59:59.000Z

    Amorphous metal alloys of the iron-chromium and nickel-chromium type have excellent corrosion resistance and high temperature stability and are suitable for use as a protective coating on less corrosion resistant substrates. The alloys are stabilized in the amorphous state by one or more elements of titanium, zirconium, hafnium, niobium, tantalum, molybdenum, and tungsten. The alloy is preferably prepared by sputter deposition.

  11. Metal resistance sequences and transgenic plants

    DOE Patents [OSTI]

    Meagher, Richard Brian (Athens, GA); Summers, Anne O. (Athens, GA); Rugh, Clayton L. (Athens, GA)

    1999-10-12T23:59:59.000Z

    The present invention provides nucleic acid sequences encoding a metal ion resistance protein, which are expressible in plant cells. The metal resistance protein provides for the enzymatic reduction of metal ions including but not limited to divalent Cu, divalent mercury, trivalent gold, divalent cadmium, lead ions and monovalent silver ions. Transgenic plants which express these coding sequences exhibit increased resistance to metal ions in the environment as compared with plants which have not been so genetically modified. Transgenic plants with improved resistance to organometals including alkylmercury compounds, among others, are provided by the further inclusion of plant-expressible organometal lyase coding sequences, as specifically exemplified by the plant-expressible merB coding sequence. Furthermore, these transgenic plants which have been genetically modified to express the metal resistance coding sequences of the present invention can participate in the bioremediation of metal contamination via the enzymatic reduction of metal ions. Transgenic plants resistant to organometals can further mediate remediation of organic metal compounds, for example, alkylmetal compounds including but not limited to methyl mercury, methyl lead compounds, methyl cadmium and methyl arsenic compounds, in the environment by causing the freeing of mercuric or other metal ions and the reduction of the ionic mercury or other metal ions to the less toxic elemental mercury or other metals.

  12. Submicron patterned metal hole etching

    DOE Patents [OSTI]

    McCarthy, Anthony M. (Menlo Park, CA); Contolini, Robert J. (Lake Oswego, OR); Liberman, Vladimir (Needham, MA); Morse, Jeffrey (Martinez, CA)

    2000-01-01T23:59:59.000Z

    A wet chemical process for etching submicron patterned holes in thin metal layers using electrochemical etching with the aid of a wetting agent. In this process, the processed wafer to be etched is immersed in a wetting agent, such as methanol, for a few seconds prior to inserting the processed wafer into an electrochemical etching setup, with the wafer maintained horizontal during transfer to maintain a film of methanol covering the patterned areas. The electrochemical etching setup includes a tube which seals the edges of the wafer preventing loss of the methanol. An electrolyte composed of 4:1 water: sulfuric is poured into the tube and the electrolyte replaces the wetting agent in the patterned holes. A working electrode is attached to a metal layer of the wafer, with reference and counter electrodes inserted in the electrolyte with all electrodes connected to a potentiostat. A single pulse on the counter electrode, such as a 100 ms pulse at +10.2 volts, is used to excite the electrochemical circuit and perform the etch. The process produces uniform etching of the patterned holes in the metal layers, such as chromium and molybdenum of the wafer without adversely effecting the patterned mask.

  13. Induction slag reduction process for purifying metals

    DOE Patents [OSTI]

    Traut, Davis E. (Corvallis, OR); Fisher, II, George T. (Albany, OR); Hansen, Dennis A. (Corvallis, OR)

    1991-01-01T23:59:59.000Z

    A continuous method is provided for purifying and recovering transition metals such as neodymium and zirconium that become reactive at temperatures above about 500.degree. C. that comprises the steps of contacting the metal ore with an appropriate fluorinating agent such as an alkaline earth metal fluosilicate to form a fluometallic compound, and reducing the fluometallic compound with a suitable alkaline earth or alkali metal compound under molten conditions, such as provided in an induction slag metal furnace. The method of the invention is advantageous in that it is simpler and less expensive than methods used previously to recover pure metals, and it may be employed with a wide range of transition metals that were reactive with enclosures used in the prior art methods and were hard to obtain in uncontaminated form.

  14. Methods of selectively incorporating metals onto substrates

    DOE Patents [OSTI]

    Ernst; Richard D. (Salt Lake City, UT), Eyring; Edward M. (Salt Lake City, UT), Turpin; Gregory C. (Salt Lake City, UT), Dunn; Brian C. (Salt Lake City, UT)

    2008-09-30T23:59:59.000Z

    A method for forming multi-metallic sites on a substrate is disclosed and described. A substrate including active groups such as hydroxyl can be reacted with a pretarget metal complex. The target metal attached to the active group can then be reacted with a secondary metal complex such that an oxidation-reduction (redox) reaction occurs to form a multi-metallic species. The substrate can be a highly porous material such as aerogels, xerogels, zeolites, and similar materials. Additional metal complexes can be reacted to increase catalyst loading or control co-catalyst content. The resulting compounds can be oxidized to form oxides or reduced to form metals in the ground state which are suitable for practical use.

  15. SEQUESTRATION OF METALS IN ACTIVE CAP MATERIALS: A LABORATORY AND NUMERICAL EVALUATION

    SciTech Connect (OSTI)

    Dixon, K.; Knox, A.

    2012-02-13T23:59:59.000Z

    Active capping involves the use of capping materials that react with sediment contaminants to reduce their toxicity or bioavailability. Although several amendments have been proposed for use in active capping systems, little is known about their long-term ability to sequester metals. Recent research has shown that the active amendment apatite has potential application for metals contaminated sediments. The focus of this study was to evaluate the effectiveness of apatite in the sequestration of metal contaminants through the use of short-term laboratory column studies in conjunction with predictive, numerical modeling. A breakthrough column study was conducted using North Carolina apatite as the active amendment. Under saturated conditions, a spike solution containing elemental As, Cd, Co, Se, Pb, Zn, and a non-reactive tracer was injected into the column. A sand column was tested under similar conditions as a control. Effluent water samples were periodically collected from each column for chemical analysis. Relative to the non-reactive tracer, the breakthrough of each metal was substantially delayed by the apatite. Furthermore, breakthrough of each metal was substantially delayed by the apatite compared to the sand column. Finally, a simple 1-D, numerical model was created to qualitatively predict the long-term performance of apatite based on the findings from the column study. The results of the modeling showed that apatite could delay the breakthrough of some metals for hundreds of years under typical groundwater flow velocities.

  16. ON THE DIVISIBILITY BY 2 OF THE STIRLING NUMBERS OF THE SECOND KIND Occidental College, 1600 Campus Road, Los Angeles, CA 90041

    E-Print Network [OSTI]

    Lengyel, Tamás

    ON THE DIVISIBILITY BY 2 OF THE STIRLING NUMBERS OF THE SECOND KIND T. Lengyel Occidental College characterize the divisibilityby 2 of the Stirling number of the second kind, Sn;k; where n is a su ciently high follows from the periodicity of the Stirling numbers modulo any prime power. For k 5, the function Lk can

  17. ON THE DIVISIBILITY BY 2 OF THE STIRLING NUMBERS OF THE SECOND KIND Occidental College, 1600 Campus Road, Los Angeles, CA 90041

    E-Print Network [OSTI]

    Lengyel, Tamás

    ON THE DIVISIBILITY BY 2 OF THE STIRLING NUMBERS OF THE SECOND KIND T. Lengyel Occidental College characterize the divisibility by 2 of the Stirling number of the second kind, S(n; k); where n, independently from n: (Here the independence follows from the periodicity of the Stirling numbers modulo any

  18. Method of inducing surface ensembles on a metal catalyst

    DOE Patents [OSTI]

    Miller, S.S.

    1987-10-02T23:59:59.000Z

    A method of inducing surface ensembles on a transition metal catalyst used in the conversion of a reactant gas or gas mixture, such as carbon monoxide and hydrogen into hydrocarbons (the Fischer-Tropsch reaction) is disclosed which comprises adding a Lewis base to the syngas (CO + H/sub 2/) mixture before reaction takes place. The formation of surface ensembles in this manner restricts the number and types of reaction pathways which will be utilized, thus greatly narrowing the product distribution and maximizing the efficiency of the Fischer-Tropsch reaction. Similarly, amines may also be produced by the conversion of reactant gas or gases, such as nitrogen, hydrogen, or hydrocarbon constituents.

  19. Method of inducing surface ensembles on a metal catalyst

    DOE Patents [OSTI]

    Miller, Steven S. (Morgantown, WV)

    1989-01-01T23:59:59.000Z

    A method of inducing surface ensembles on a transition metal catalyst used in the conversion of a reactant gas or gas mixture, such as carbon monoxide and hydrogen into hydrocarbons (the Fischer-Tropsch reaction) is disclosed which comprises adding a Lewis base to the syngas (CO+H.sub.2) mixture before reaction takes place. The formation of surface ensembles in this manner restricts the number and types of reaction pathways which will be utilized, thus greatly narrowing the product distribution and maximizing the efficiency of the Fischer-Tropsch reaction. Similarly, amines may also be produced by the conversion of reactant gas or gases, such as nitrogen, hydrogen, or hydrocarbon constituents.

  20. Inhalation carcinogenicity study with nickel metal powder in Wistar rats

    SciTech Connect (OSTI)

    Oller, Adriana R. [NiPERA, 2605 Meridian Parkway, Suite 200, Durham, NC 27713 (United States)], E-mail: aoller@nipera.org; Kirkpatrick, Daniel T.; Radovsky, Ann [WIL Research Laboratories, LLC, 1407 George Road, Ashland, OH 44805 8946 (United States); Bates, Hudson K. [NiPERA, 2605 Meridian Parkway, Suite 200, Durham, NC 27713 (United States)

    2008-12-01T23:59:59.000Z

    Epidemiological studies of nickel refinery workers have demonstrated an association between increased respiratory cancer risk and exposure to certain nickel compounds (later confirmed in animal studies). However, the lack of an association found in epidemiological analyses for nickel metal remained unconfirmed for lack of robust animal inhalation studies. In the present study, Wistar rats were exposed by whole-body inhalation to 0, 0.1, 0.4, and 1.0 mg Ni/m{sup 3} nickel metal powder (MMAD = 1.8 {mu}m, GSD = 2.4 {mu}m) for 6 h/day, 5 days/week for up to 24 months. A subsequent six-month period without exposures preceded the final euthanasia. High mortality among rats exposed to 1.0 mg Ni/m{sup 3} nickel metal resulted in the earlier termination of exposures in this group. The exposure level of 0.4 mg Ni/m{sup 3} was established as the MTD for the study. Lung alterations associated with nickel metal exposure included alveolar proteinosis, alveolar histiocytosis, chronic inflammation, and bronchiolar-alveolar hyperplasia. No increased incidence of neoplasm of the respiratory tract was observed. Adrenal gland pheochromocytomas (benign and malignant) in males and combined cortical adenomas/carcinomas in females were induced in a dose-dependent manner by the nickel metal exposure. The incidence of pheochromocytomas was statistically increased in the 0.4 mg Ni/m{sup 3} male group. Pheochromocytomas appear to be secondary to the lung toxicity associated with the exposure rather than being related to a direct nickel effect on the adrenal glands. The incidence of cortical tumors among 0.4 mg Ni/m{sup 3} females, although statistically higher compared to the concurrent controls, falls within the historical control range; therefore, in the present study, this tumor is of uncertain relationship to nickel metal exposure. The lack of respiratory tumors in the present animal study is consistent with the findings of the epidemiological studies.

  1. The Periodic Table as a Part of the Periodic Table of Chemical Compounds

    E-Print Network [OSTI]

    Labushev, Mikhail M

    2011-01-01T23:59:59.000Z

    The numbers of natural chemical elements, minerals, inorganic and organic chemical compounds are determined by 1, 2, 3 and 4-combinations of a set 95 and are respectively equal to 95, 4,465, 138,415 and 3,183,545. To explain these relations it is suggested the concept of information coefficient of proportionality as mathematical generalization of the proportionality coefficient for any set of positive numbers. It is suggested a hypothesis that the unimodal distributions of the sets of information coefficients of proportionality for atomic weights of chemical elements of minerals and chemical compounds correspond to unimodal distributions of the above sets for combination of 2, 3 and 4 atomic weights of 95 natural chemical elements. The expected values of symmetrized distributions of information coefficients of proportionality sets for atomic weights of minerals and chemical compounds are proposed to be used to define chemical compounds, like atomic weights define chemical elements. Variational series of the e...

  2. Metal carbonyl-hydrosilane reactions and hydrosilation catalysis. Final report for period May 1, 1995 - August 14, 1999

    SciTech Connect (OSTI)

    Cutler, Alan R.

    2001-04-14T23:59:59.000Z

    Manganese carbonyl complexes serve as hydrosilation precatalysts for selectively transforming a carbonyl group into a doxy methylene or a fully reduced methylene group. Substrates of interest include (1) aldehydes, ketones, carboxylic acids, silyl esters, and esters, and (2) their organometallic acyl counterparts. Two types of manganese precatalysts have been reported: (a) alkyl and acyl complexes (L)(CO){sub 4}MnR [L = CO, PPh{sub 3}; R = COCH{sub 3}, COPh, CH{sub 3}] and (b) halides (CO){sub 5}MnX and [(CO){sub 4}MnX]{sub 2} (X = Br, I). The former promote hydrosilation and deoxygenation catalysis; the latter promote dehydrogenative silation of alcohols and carboxylic acids as well as hydrosilation and deoxygenation of some metallocarboxylic acid derivatives. In every case studied, these Mn precatalysts are far more reactive or selective than traditional Rh(l) precatalysts. The reaction chemistry of the above and other Mn alkyl complexes with hydrosilanes was studied in order to probe catalysis mechanism(s). Thus, Mn(CO){sub 5} methyl, benzyl, acetyl, and benzoyl (4 p-substituents) complexes reacted with hydrosilines by four different mechanisms, which were established. A noteworthy development was that the methyl and benzoyl complexes gave moderate yields of a new ({eta}{sup 2}-Si-H) silane adduct (CO){sub 4}Mn(SiMe{sub 2}Ph)(H-SiMe{sub 2}Ph), which is stable in the presence of excess silane. This silane adduct promotes all three catalytic reactions; its extraordinary activity and potential selectivity are under study.

  3. Tip sheet: Expanded Library of Congress Call Number Classification system Call Number Subject Matter

    E-Print Network [OSTI]

    Kambhampati, Patanjali

    Tip sheet: Expanded Library of Congress Call Number Classification system Call Number Subject R: Medicine T: Technology U: Military Science Z: Bibliography. Library Science. Information

  4. Mesoscopic superconductivity in ultrasmall metallic grains

    SciTech Connect (OSTI)

    Alhassid, Y. [Center for Theoretical Physics, Sloane Physics Laboratory, Yale University, New Haven, CT 06520 (United States); Nesterov, K. N. [Center for Theoretical Physics, Sloane Physics Laboratory, Yale University, New Haven, CT 06520 (United States); CEA, INAC-SPSMS, F-38000 Grenoble (France)

    2014-10-15T23:59:59.000Z

    A nano-scale metallic grain (nanoparticle) with irregular boundaries in which the single-particle dynamics are chaotic is a zero-dimensional system described by the so-called universal Hamiltonian in the limit of a large number of electrons. The interaction part of this Hamiltonian includes a superconducting pairing term and a ferromagnetic exchange term. Spin-orbit scattering breaks spin symmetry and suppresses the exchange interaction term. Of particular interest is the fluctuation-dominated regime, typical of the smallest grains in the experiments, in which the bulk pairing gap is comparable to or smaller than the single-particle mean-level spacing, and the Bardeen-Cooper-Schrieffer (BCS) mean-field theory of superconductivity is no longer valid. Here we study the crossover between the BCS and fluctuation-dominated regimes in two limits. In the absence of spin-orbit scattering, the pairing and exchange interaction terms compete with each other. We describe the signatures of this competition in thermodynamic observables, the heat capacity and spin susceptibility. In the presence of strong spin-orbit scattering, the exchange interaction term can be ignored. We discuss how the magnetic-field response of discrete energy levels in such a nanoparticle is affected by pairing correlations. We identify signatures of pairing correlations in this response, which are detectable even in the fluctuation-dominated regime.

  5. Method and apparatus for dissociating metals from metal compounds extracted into supercritical fluids

    DOE Patents [OSTI]

    Wai, Chien M. (Moscow, ID); Hunt, Fred H. (Moscow, ID); Smart, Neil G. (Workington, GB); Lin, Yuehe (Richland, WA)

    2000-01-01T23:59:59.000Z

    A method for dissociating metal-ligand complexes in a supercritical fluid by treating the metal-ligand complex with heat and/or reducing or oxidizing agents is described. Once the metal-ligand complex is dissociated, the resulting metal and/or metal oxide form fine particles of substantially uniform size. In preferred embodiments, the solvent is supercritical carbon dioxide and the ligand is a .beta.-diketone such as hexafluoroacetylacetone or dibutyldiacetate. In other preferred embodiments, the metals in the metal-ligand complex are copper, silver, gold, tungsten, titanium, tantalum, tin, or mixtures thereof. In preferred embodiments, the reducing agent is hydrogen. The method provides an efficient process for dissociating metal-ligand complexes and produces easily-collected metal particles free from hydrocarbon solvent impurities. The ligand and the supercritical fluid can be regenerated to provide an economic, efficient process.

  6. Developments in Bioremediation of Soils and Sediments Pollutedwith Metals and Radionuclides: 2. Field Research on Bioremediation of Metals and Radionuclides

    SciTech Connect (OSTI)

    Hazen, Terry C.; Tabak, Henry H.

    2007-03-15T23:59:59.000Z

    Bioremediation of metals and radionuclides has had manyfield tests, demonstrations, and full-scale implementations in recentyears. Field research in this area has occurred for many different metalsand radionuclides using a wide array of strategies. These strategies canbe generally characterized in six major categories: biotransformation,bioaccumulation/bisorption, biodegradation of chelators, volatilization,treatment trains, and natural attenuation. For all field applicationsthere are a number of critical biogeochemical issues that most beaddressed for the successful field application. Monitoring andcharacterization parameters that are enabling to bioremediation of metalsand radionuclides are presented here. For each of the strategies a casestudy is presented to demonstrate a field application that uses thisstrategy.

  7. Sumitomo Metal Industries Ltd Sumitomo Metals | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty Edit with formSoutheastern IL ElecStrategicStories HomeSumco Techxiv CorporationMetal

  8. Chemical and Mineralogical Characterization of Arsenic, Lead, Chromium, and Cadmium in a Metal-contaminated Histosol

    SciTech Connect (OSTI)

    Gao, X.; Schulze, D

    2010-01-01T23:59:59.000Z

    The chemical and mineralogical forms of As, Pb, Cr, and Cd were studied in a metal-contaminated organic soil (Histosol) that received runoff and seepage water from a site that was once occupied by a lead smelter. Soil samples were collected from different depth intervals during both wet and dry seasons and analyzed using bulk powder X-ray diffraction (XRD), synchrotron-based micro X-ray diffraction ({mu}-XRD), and micro X-ray fluorescence ({mu}-SXRF) spectroscopy. There was a clear pattern of mineral distribution with depth that indicated the presence of an intense redox gradient. The oxidized reddish brown surface layer (0-10 cm) was dominated by goethite ({alpha}-FeOOH) and poorly crystalline akaganeite ({beta}-FeOOH). Lead and arsenic were highly associated with these Fe oxides, possibly by forming inner-sphere surface complexes. Gypsum (CaSO{sub 4} {center_dot} 2H{sub 2}O) was abundant in the layer as well, particularly for samples collected during dry periods. Fe(II)-containing minerals, such as magnetite (Fe{sub 3}O{sub 4}) and siderite (FeCO{sub 3}), were identified in the intermediate layers (10-30 cm) where the reductive dissolution of Fe(III) oxides occurred. A number of high-temperature minerals, such as mullite (3Al{sub 2}O{sub 3} {center_dot} 2Si{sub 2}O), corundum ({alpha}-Al{sub 2}O{sub 3}), hematite ({alpha}-Fe{sub 2}O{sub 3}), and wustite (FeO) were identified in the subsurface and they probably formed as a result of a burning event. Several sulfide minerals were identified in the most reduced layers at depths > 30 cm. They included realgar (AsS), alacranite (As{sub 4}S{sub 4}), galena (PbS), and sphalerite (Zn, Fe{sup 2+})S, and a series of Fe sulfides, including greigite (Fe{sup 2+}Fe{sub 2}{sup 3+} S{sub 4}), pyrrhotite (Fe{sub 1-x}S), mackinawite (FeS), marcasite (FeS{sub 2}), and pyrite (FeS{sub 2}). Most of these minerals occurred as almost pure phases in sub-millimeter aggregates and appeared to be secondary phases that had precipitated from solution. Despite the elevated levels of Cd in the soil, no specific Cd phases were identified. The complex mineralogy has important implications for risk assessment and the design of in-situ remediation strategies for this and similar metal-contaminated sites.

  9. U.S. Department of Energy National Center of Excellence for Metals Recycle

    SciTech Connect (OSTI)

    Adams, V.; Bennett, M.; Bishop, L. [Dept. of Energy, Oak Ridge, TN (United States)] [and others

    1998-06-01T23:59:59.000Z

    The US Department of Energy (DOE) National Center of Excellence for Metals Recycle has recently been established. The vision of this new program is to develop a DOE culture that promotes pollution prevention by considering the recycle and reuse of metal as the first and primary disposition option and burial as a last option. The Center of Excellence takes the approach that unrestricted release of metal is the first priority because it is the most cost-effective disposition pathway. Where this is not appropriate, restricted release, beneficial reuse, and stockpile of ingots are considered. The Center has gotten off to a fast start. Current recycling activities include the sale of 40,000 tons of scrap metal from the East Tennessee Technology Park (formerly K-25 Plant) K-770 scrap yard, K-1064 surplus equipment and machinery, 7,000 PCB-contaminated drums, 12,000 tons of metal from the Y-12 scrap yard, and 1,000 metal pallets. In addition, the Center of Excellence is developing a toolbox for project teams that will contain a number of specific tools to facilitate metals recycle. This Internet-based toolbox will include primers, computer software, and case studies designed to help sites to perform life cycle analysis, perform ALARA (As Low As is Reasonably Achievable) analysis for radiation exposures, produce pollution prevention information and documentation, manage their materials inventory, produce independent government estimates, and implement sale/service contracts. The use of these tools is described for two current activities: disposition of scrap metal in the Y-12 scrap yard, and disposition of PCB-contaminated drums. Members of the Center look forward to working with all DOE sites, regulatory authorities, the private sector, and other stakeholders to achieve the metals recycle goals.

  10. Green's function analysis of periodic structures in computational electromagnetics

    E-Print Network [OSTI]

    Van Orden, Derek

    2011-01-01T23:59:59.000Z

    the two-dimensional periodic Green's function," IEEE Trans.evaluation of the Green's function for the Helmholtzrepresentations of certain Green's functions," J. Comp.

  11. EIS-0250: Notice of Public Comment Period Extension and Additional...

    Broader source: Energy.gov (indexed) [DOE]

    Period Extension and Additional Public Meeting Geologic Repository for the Disposal of Spent Nuclear Fuel and High-Level Radioactive Waste at Yucca Mountain, Nye County, NV...

  12. Uranium Leasing Program Draft PEIS Public Comment Period Extended...

    Broader source: Energy.gov (indexed) [DOE]

    Uranium Leasing Program Draft PEIS Public Comment Period Extended to May 31, 2013 Draft ULPEIS comment extension community notification041813 (3).pdf More Documents & Publications...

  13. Multilevel interference lithography--fabricating sub-wavelength periodic nanostructures

    E-Print Network [OSTI]

    Chang, Chih-Hao, 1980-

    2008-01-01T23:59:59.000Z

    Periodic nanostructures have many exciting applications, including high-energy spectroscopy, patterned magnetic media, photonic crystals, and templates for self-assembly. Interference lithography (IL) is an attractive ...

  14. Extension of Comment Period on the Draft Integrated, Interagency...

    Energy Savers [EERE]

    Extension of Comment Period on the Draft Integrated, Interagency Pre-Application (IIP) Process for Electric Transmission Projects Requiring Federal Authorizations Extension of...

  15. Methods of producing adsorption media including a metal oxide

    DOE Patents [OSTI]

    Mann, Nicholas R; Tranter, Troy J

    2014-03-04T23:59:59.000Z

    Methods of producing a metal oxide are disclosed. The method comprises dissolving a metal salt in a reaction solvent to form a metal salt/reaction solvent solution. The metal salt is converted to a metal oxide and a caustic solution is added to the metal oxide/reaction solvent solution to adjust the pH of the metal oxide/reaction solvent solution to less than approximately 7.0. The metal oxide is precipitated and recovered. A method of producing adsorption media including the metal oxide is also disclosed, as is a precursor of an active component including particles of a metal oxide.

  16. TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

    SciTech Connect (OSTI)

    James T. Cobb, Jr.; Ronald D. Neufeld; Jana Agostini

    1999-05-10T23:59:59.000Z

    This fourteenth quarterly report describes work done during the fourteenth three-month period of the University of Pittsburgh's project on the ''Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.'' This report describes the activities of the project team during the reporting period. The principal work has focused upon new laboratory evaluation of samples from Phase 1, discussions with MAX Environmental Technologies, Inc., on the field work of Phase 2, preparing presentations, and making and responding to two outside contacts.

  17. Periodic orbit analysis of a system with continuous symmetry - a tutorial

    E-Print Network [OSTI]

    Nazmi Burak Budanur; Daniel Borrero-Echeverry; Predrag Cvitanovi?

    2015-02-06T23:59:59.000Z

    Dynamical systems with translational or rotational symmetry arise frequently in studies of spatially extended physical systems, such as Navier-Stokes flows on periodic domains. In these cases, it is natural to express the state of the fluid in terms of a Fourier series truncated to a finite number of modes. Here, we study a 4-dimensional two-mode SO(2)-equivariant model of this type, the smallest possible truncation that retains the symmetry but is high-dimensional enough to allow for chaotic dynamics. A crucial step in the analysis of such a system is symmetry reduction. We use the model to illustrate different symmetry-reduction techniques. Its relative equilibria are conveniently determined by rewriting the dynamics in terms of a symmetry-invariant polynomial basis. However, for the analysis of its chaotic dynamics, the `method of slices', which is applicable to very high-dimensional problems, is preferable. We show that a Poincar\\'e section taken on the `slice' can be used to further reduce this flow to what is for all practical purposes a unimodal map. This enables us to systematically determine all relative periodic orbits and their symbolic dynamics up to any desired period. We then present cycle averaging formulas adequate for systems with continuous symmetry and use them to compute dynamical averages using relative periodic orbits. The convergence of such computations is discussed.

  18. Induction furnace testing of the durability of prototype crucibles in a molten metal environment

    SciTech Connect (OSTI)

    Jablonski, Paul D.

    2005-09-01T23:59:59.000Z

    Engineered ceramic crucibles are commonly used to contain molten metal. Besides high temperature stability, other desired crucible characteristics include thermal shock resistance, minimal reaction with the molten metal and resistance to attack from the base metal oxide formed during melting. When used in an induction furnace, they can be employed as a “semi-permanent” crucible incorporating a dry ram backup and a ceramic cap. This report covers several 250-lb single melt crucible tests in an air melt induction furnace. These tests consisted of melting a charge of 17-4PH stainless steel, holding the charge molten for two hours before pouring off the heat and then subsequently sectioning the crucible to review the extent of erosion, penetration and other physical characteristics. Selected temperature readings were made throughout each melt. Chemistry samples were also taken from each heat periodically throughout the hold. The manganese level was observed to affect the rate of chromium loss in a non-linear fashion.

  19. Integrated DWPF Melter System (IDMS) campaign report: The first two noble metals operations

    SciTech Connect (OSTI)

    Hutson, N.D.; Zamecnik, J.R.; Smith, M.E.; Miller, D.H.; Ritter, J.A.

    1991-06-06T23:59:59.000Z

    The Integrated DWPF Melter System (IDMS) is designed and constructed to provide an engineering-scale representation of the DWPF melter and its associated feed preparation and off-gas systems. The facility is the first pilot-scale melter system capable of processing mercury, and flowsheet levels of halides and noble metals. In order to characterize the processing of noble metals (Pd, Rh, Ru, and Ag) on a large scale, the IDMS will be operated batchstyle for at least nine feed preparation cycles. The first two of these operations are complete. The major observation to date occurred during the second run when significant amounts of hydrogen were evolved during the feed preparation cycle. The runs were conducted between June 7, 1990 and March 8, 1991. This time period included nearly six months of ``fix-up`` time when forced air purges were installed on the SRAT MFT and other feed preparation vessels to allow continued noble metals experimentation.

  20. Relativistic theory of tidal Love numbers

    E-Print Network [OSTI]

    Taylor Binnington; Eric Poisson

    2009-09-16T23:59:59.000Z

    In Newtonian gravitational theory, a tidal Love number relates the mass multipole moment created by tidal forces on a spherical body to the applied tidal field. The Love number is dimensionless, and it encodes information about the body's internal structure. We present a relativistic theory of Love numbers, which applies to compact bodies with strong internal gravities; the theory extends and completes a recent work by Flanagan and Hinderer, which revealed that the tidal Love number of a neutron star can be measured by Earth-based gravitational-wave detectors. We consider a spherical body deformed by an external tidal field, and provide precise and meaningful definitions for electric-type and magnetic-type Love numbers; and these are computed for polytropic equations of state. The theory applies to black holes as well, and we find that the relativistic Love numbers of a nonrotating black hole are all zero.

  1. Genome-Assisted Analysis of Dissimilatory Metal-Reducing Bacteria

    SciTech Connect (OSTI)

    Fredrickson, Jim K.; Romine, Margaret F.

    2005-06-01T23:59:59.000Z

    Whole genome sequence for Shewanella oneidensis and Geobacter sulfurreducens has provided numerous new biological insights into the function of these model dissimilatory metal-reducing bacteria. Many of the discoveries, including the identification of a high number of c-type cytochromes in both organisms, have been the result of comparative genomic analyses including several that were experimentally confirmed. Genome sequence has also aided the identification of genes important for the reduction of metal ions and other electron acceptors utilized by these organisms during anaerobic growth by facilitating the identification of genes disrupted by random insertions. Technologies for assaying global expression patterns for genes (mRNA) and proteins have also been enabled by the availability of genome sequence but their application has been limited mainly to the analysis of the role of global regulatory genes and to identifying genes expressed or repressed in response to specific electron acceptors. It is anticipated that details regarding the mechanisms of metal ion respiration, and metabolism in general, will eventually be revealed by comprehensive, systems-level analyses enabled by functional genomic analyses.

  2. Metallicity at the explosion sites of interacting transients

    E-Print Network [OSTI]

    Taddia, F; Fremling, C; Pastorello, A; Leloudas, G; Fransson, C; Nyholm, A; Stritzinger, M D; Ergon, M; Roy, R; Migotto, K

    2015-01-01T23:59:59.000Z

    Context. Some circumstellar-interacting (CSI) supernovae (SNe) are produced by the explosions of massive stars that have lost mass shortly before the SN explosion. There is evidence that the precursors of some SNe IIn were luminous blue variable (LBV) stars. For a small number of CSI SNe, outbursts have been observed before the SN explosion. Eruptive events of massive stars are named as SN impostors (SN IMs) and whether they herald a forthcoming SN or not is still unclear. The large variety of observational properties of CSI SNe suggests the existence of other progenitors, such as red supergiant (RSG) stars with superwinds. Furthermore, the role of metallicity in the mass loss of CSI SN progenitors is still largely unexplored. Aims. Our goal is to gain insight on the nature of the progenitor stars of CSI SNe by studying their environments, in particular the metallicity at their locations. Methods. We obtain metallicity measurements at the location of 60 transients (including SNe IIn, SNe Ibn, and SN IMs), via...

  3. Carbon-enhanced metal-poor stars in dwarf galaxies

    E-Print Network [OSTI]

    Salvadori, Stefania; Tolstoy, Eline

    2015-01-01T23:59:59.000Z

    We investigate the frequency and origin of carbon-enhanced metal-poor (CEMP) stars in Local Group dwarf galaxies by means of a statistical, data-calibrated cosmological model for the hierarchical build-up of the Milky Way and its dwarf satellites. The model self-consistently explains the variation with dwarf galaxy luminosity of the observed: i) frequency and [Fe/H] range of CEMP stars; ii) metallicity distribution functions; iii) star formation histories. We show that if primordial faint supernovae dominated the early metal enrichment, then CEMP-no stars enriched by the first stellar generations should be present in all dwarf galaxies, with similar number of stars and CEMP fractions at [Fe/H]$10^{7}L_{\\odot}$. We present model predictions for the low Fe-tail and CEMP fraction of stars in dwarf galaxies, with particular emphasis on the Sculptor dSph, that can be used to shed light on the properties of the first stars.

  4. SPECTROPHOTOMETRIC INDICES AND METAL CONTENT OF GALACTIC GLOBULAR CLUSTERS

    E-Print Network [OSTI]

    S. Covino; S. Galletti; L. E. Pasinetti

    1995-03-06T23:59:59.000Z

    Spectrophotometric indices for $18$ Galactic globular clusters, obtained from CCD observations and careful reductions, were used to determine reliable calibrations on metallicity $[Fe/H]$. The indices were measured in the bandpasses adopted by Burnstein et al. (\\cite{BFGK84}). Adding other observations of Burnstein et al. (\\cite{BFGK84}) we obtained our results from an homogeneous sample of indices for $26$ globular clusters. Relations with indices defined by other Authors and with metallicity photometric indices or parameters were also computed. In each case the relations are quite satisfactory. Observational data were compared with synthetic indices derived from Buzzoni's (\\cite{B89}) models and detailed discussions were performed for $Mg_2$, $Fe_{52}$, and $H_\\beta$. The observational points seem to be systematically shifted with respect to the fiducial lines traced by the models. The scenario confirms that a certain degree of oxygen enhancement would be necessary to obtain a better agreement between observed data and theoretical predictions. This enhancement, however, removes some of the disagreement, but not all of it. The dependence of the observed $Fe_{52}$ and $H_\\beta$ indices on the metal content for different HB morphologies was considered. Finally, some results were also discussed from a statistical point of view. A principal component analysis was applied to the index sample to study the number of independent parameters necessary to reproduce the observations. The whole index set is completely consistent with a one-parameter family.

  5. Pollution prevention and water conservation in metals finishing operations

    SciTech Connect (OSTI)

    O`Shaughnessy, J.; Clark, W. [Worcester Polytechnic Inst., MA (United States); Lizotte, R.P. Jr.; Mikutel, D. [Texas Instruments Inc., Attleboro, MA (United States)

    1996-11-01T23:59:59.000Z

    Attleboro, Massachusetts is the headquarters of the Materials and Controls Group of Texas Instruments Incorporated (Texas Instruments). In support of their activities, Texas Instruments operates a number of metal finishing and electroplating processes. The water supply and the wastewater treatment requirements are supplied throughout the facility from a central location. Water supply quality requirements varies with each manufacturing operation. As a result, manufacturing operations are classified as either high level or a lower water quality. The facility has two methods of wastewater treatment and disposal. The first method involves hydroxide and sulfide metals precipitation prior to discharge to a surface water. The second method involves metals precipitation, filtration, and discharge via sewer to the Attleboro WTF. The facility is limited to a maximum wastewater discharge of 460,000 gallons per day to surface water under the existing National Pollution Discharge Elimination System (NPDES) permit. There is also a hydraulic flow restriction on pretreated wastewater that is discharged to the Attleboro WTF. Both of these restrictions combined with increased production could cause the facility to reach the treatment capacity. The net effect is that wastewater discharge problems are becoming restrictive to the company`s growth. This paper reviews Texas Instruments efforts to overcome these restrictions through pollution prevention and reuse practices rather than expansion of end of pipe treatment methods.

  6. Predicting landfalling hurricane numbers from basin hurricane numbers: basic statistical analysis

    E-Print Network [OSTI]

    Laepple, T; Penzer, J; Bellone, E; Nzerem, K; Laepple, Thomas; Jewson, Stephen; Penzer, Jeremy; Bellone, Enrica; Nzerem, Kechi

    2007-01-01T23:59:59.000Z

    One possible method for predicting landfalling hurricane numbers is to first predict the number of hurricanes in the basin and then convert that prediction to a prediction of landfalling hurricane numbers using an estimated proportion. Should this work better than just predicting landfalling hurricane numbers directly? We perform a basic statistical analysis of this question in the context of a simple abstract model.

  7. Polymer quenched prealloyed metal powder

    DOE Patents [OSTI]

    Hajaligol, Mohammad R. (Midlothian, VA); Fleischhauer, Grier (Midlothian, VA); German, Randall M. (State College, PA)

    2001-01-01T23:59:59.000Z

    A powder metallurgical process of preparing a sheet from a powder having an intermetallic alloy composition such as an iron, nickel or titanium aluminide. The sheet can be manufactured into electrical resistance heating elements having improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The iron aluminide has an entirely ferritic microstructure which is free of austenite and can include, in weight %, 4 to 32% Al, and optional additions such as .ltoreq.1% Cr, .gtoreq.0.05% Zr .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Ni, .ltoreq.0.75% C, .ltoreq.0.1% B, .ltoreq.1% submicron oxide particles and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, and/or .ltoreq.3 % Cu. The process includes forming a non-densified metal sheet by consolidating a powder having an intermetallic alloy composition such as by roll compaction, tape casting or plasma spraying, forming a cold rolled sheet by cold rolling the non-densified metal sheet so as to increase the density and reduce the thickness thereof and annealing the cold rolled sheet. The powder can be a water, polymer or gas atomized powder which is subjecting to sieving and/or blending with a binder prior to the consolidation step. After the consolidation step, the sheet can be partially sintered. The cold rolling and/or annealing steps can be repeated to achieve the desired sheet thickness and properties. The annealing can be carried out in a vacuum furnace with a vacuum or inert atmosphere. During final annealing, the cold rolled sheet recrystallizes to an average grain size of about 10 to 30 .mu.m. Final stress relief annealing can be carried out in the B2 phase temperature range.

  8. REFINED BOUNDS ON THE NUMBER OF CONNECTED ...

    E-Print Network [OSTI]

    2011-04-06T23:59:59.000Z

    Apr 6, 2011 ... Smith inequality (see Theorem 2.5) a bound on the number of semi- ... then using Smith inequality, have been used before in several different ...

  9. Harmonic resolution as a holographic quantum number

    E-Print Network [OSTI]

    Bousso, Raphael

    2009-01-01T23:59:59.000Z

    LBNL- 57239 Harmonic resolution as a holographic quantumhep-th/0310223 UCB-PTH-03/26 Harmonic resolution as aquantum number, the harmonic resolution K. The Bekenstein

  10. On Conformal Field Theory and Number Theory

    E-Print Network [OSTI]

    Huang, An

    2011-01-01T23:59:59.000Z

    Frontiers in Number Theory, Physics, and Ge- ometry II. (Witten, Quantum Field Theory, Crassmannians, and AlgebraicJ. Polchinski, String Theory, Vol. 1, Cambridge Univ.

  11. Clamshell closure for metal drum

    DOE Patents [OSTI]

    Blanton, Paul S

    2014-09-30T23:59:59.000Z

    Closure ring to retain a lid in contact with a metal drum in central C-section conforming to the contact area between a lid and the rim of a drum and further having a radially inwardly directed flange and a vertically downwardly directed flange attached to the opposite ends of the C-section. The additional flanges reinforce the top of the drum by reducing deformation when the drum is dropped and maintain the lid in contact with the drum. The invention is particularly valuable in transportation and storage of fissile material.

  12. Metal recovery from porous materials

    DOE Patents [OSTI]

    Sturcken, Edward F. (P.O. Box 900, Isle of Palms, SC 29451)

    1992-01-01T23:59:59.000Z

    A method for recovering plutonium and other metals from materials by leaching comprising the steps of incinerating the materials to form a porous matrix as the residue of incineration, immersing the matrix into acid in a microwave-transparent pressure vessel, sealing the pressure vessel, and applying microwaves so that the temperature and the pressure in the pressure vessel increase. The acid for recovering plutonium can be a mixture of HBF.sub.4 and HNO.sub.3 and preferably the pressure is increased to at least 100 PSI and the temperature to at least 200.degree. C. The porous material can be pulverized before immersion to further increase the leach rate.

  13. Metal-Ion-Mediated Reactions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHighand Retrievals from aRod EggertMercuryAdvancedMetal-Ion-Mediated

  14. Rapid Freeform Sheet Metal Forming

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOrigin of ContaminationHubs+18, 2012 Qualified11 Connecticut2 of 3)theDieselFreeform Sheet Metal

  15. Method of preparing silicon carbide particles dispersed in an electrolytic bath for composite electroplating of metals

    DOE Patents [OSTI]

    Peng, Yu-Min (Hsinchu, TW); Wang, Jih-Wen (Hsinchu, TW); Liue, Chun-Ying (Tau-Yung, TW); Yeh, Shinn-Horng (Kaohsiung, TW)

    1994-01-01T23:59:59.000Z

    A method for preparing silicon carbide particles dispersed in an electrolytic bath for composite electroplating of metals includes the steps of washing the silicon carbide particles with an organic solvent; washing the silicon carbide particles with an inorganic acid; grinding the silicon carbide particles; and heating the silicon carbide particles in a nickel-containing solution at a boiling temperature for a predetermined period of time.

  16. Electronic Structure of Transition Metal Clusters and Actinide Complexes and Their Reactivity

    SciTech Connect (OSTI)

    Balasubramanian, K

    2008-10-06T23:59:59.000Z

    Our research in this area since October 2007 has resulted in seven completed publications and more papers of the completed work are in progress. Our work during this period principally focused on actinide complexes with secondary emphasis on spectroscopic properties and electronic structure of metal complexes. As the publications are available online with all of the details of the results, tables and figures, we are providing here only a brief summary of major highlights, in each of the categories.

  17. Contour forming of metals by laser peening

    DOE Patents [OSTI]

    Hackel, Lloyd (Livermore, CA); Harris, Fritz (Rocklin, CA)

    2002-01-01T23:59:59.000Z

    A method and apparatus are provided for forming shapes and contours in metal sections by generating laser induced compressive stress on the surface of the metal workpiece. The laser process can generate deep compressive stresses to shape even thick components without inducing unwanted tensile stress at the metal surface. The precision of the laser-induced stress enables exact prediction and subsequent contouring of parts. A light beam of 10 to 100 J/pulse is imaged to create an energy fluence of 60 to 200 J/cm.sup.2 on an absorptive layer applied over a metal surface. A tamping layer of water is flowed over the absorptive layer. The absorption of laser light causes a plasma to form and consequently creates a shock wave that induces a deep residual compressive stress into the metal. The metal responds to this residual stress by bending.

  18. Nanostructured metal foams: synthesis and applications

    SciTech Connect (OSTI)

    Luther, Erik P [Los Alamos National Laboratory; Tappan, Bryce [Los Alamos National Laboratory; Mueller, Alex [Los Alamos National Laboratory; Mihaila, Bogdan [Los Alamos National Laboratory; Volz, Heather [Los Alamos National Laboratory; Cardenas, Andreas [Los Alamos National Laboratory; Papin, Pallas [Los Alamos National Laboratory; Veauthier, Jackie [Los Alamos National Laboratory; Stan, Marius [Los Alamos National Laboratory

    2009-01-01T23:59:59.000Z

    Fabrication of monolithic metallic nanoporous materials is difficult using conventional methodology. Here they report a relatively simple method of synthesizing monolithic, ultralow density, nanostructured metal foams utilizing self-propagating combustion synthesis of novel metal complexes containing high nitrogen energetic ligands. Nanostructured metal foams are formed in a post flame-front dynamic assembly with densities as low as 0.011 g/cc and surface areas as high as 270 m{sup 2}/g. They have produced metal foams via this method of titanium, iron, cobalt, nickel, zirconium, copper, palladium, silver, hafnium, platinum and gold. Microstructural features vary as a function of composition and process parameters. Applications for the metal foams are discussed including hydrogen absorption in palladium foams. A model for the sorption kinetics of hydrogen in the foams is presented.

  19. Irradiation behavior of metallic fast reactor fuels

    SciTech Connect (OSTI)

    Pahl, R.G.; Porter, D.L.; Crawford, D.C.; Walters, L.C.

    1991-01-01T23:59:59.000Z

    Metallic fuels were the first fuels chosen for liquid metal cooled fast reactors (LMR's). In the late 1960's world-wide interest turned toward ceramic LMR fuels before the full potential of metallic fuel was realized. However, during the 1970's the performance limitations of metallic fuel were resolved in order to achieve a high plant factor at the Argonne National Laboratory's Experimental Breeder Reactor II. The 1980's spawned renewed interest in metallic fuel when the Integral Fast Reactor (IFR) concept emerged at Argonne National Laboratory. A fuel performance demonstration program was put into place to obtain the data needed for the eventual licensing of metallic fuel. This paper will summarize the results of the irradiation program carried out since 1985.

  20. Phase-locked rhythms in periodically stimulated heart cell aggregates

    E-Print Network [OSTI]

    Glass, Leon

    Phase-locked rhythms in periodically stimulated heart cell aggregates MICHAEL R. GUEVARA, ALVIN GUEVARA,MICHAEL R., ALVIN SHRIER,ANDLEONGLASS. Phase-locked rhythms in periodically stimulated heart cell, THE SINOATRIAL NODE acts as the pace- maker of the heart. As a result of the orderly spread of excitation