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Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Multiferroic Metal Organic Frameworks  

NLE Websites -- All DOE Office Websites (Extended Search)

with the oxygen of the framework. Upon cooling the compounds go under a phase transition, due to the ordering of nitrogen, leading to ferroelectric ordering. They also order...

2

Gas adsorption on metal-organic frameworks  

DOE Patents (OSTI)

The present invention involves the use of certain metal organic frameworks that have been treated with water or another metal titrant in the storage of carbon dioxide. The capacity of these frameworks is significantly increased through this treatment.

Willis, Richard R. (Cary, IL); Low, John J. (Schaumburg, IL), Faheem, Syed A. (Huntley, IL); Benin, Annabelle I. (Oak Forest, IL); Snurr, Randall Q. (Evanston, IL); Yazaydin, Ahmet Ozgur (Evanston, IL)

2012-07-24T23:59:59.000Z

3

Crystallography of metal-organic frameworks  

Science Journals Connector (OSTI)

Recent advances in the crystallography of metal-organic frameworks (MOFs) are reviewed, including crystal growth, structural elucidation, in-situ and non-ambient crystallography.

G?ndara, F.

2014-10-28T23:59:59.000Z

4

Hydrocarbon Separations in Metal–Organic Frameworks  

Science Journals Connector (OSTI)

Given the large differences in the physical properties of methane and C2 hydrocarbons, both size selective effects and metal–hydrocarbon interactions can be tuned to achieve a high selectivity within a metal–organic framework. ... Polycyclic aromatic hydrocarbons, or PAHs, are carcinogenic byproducts of incomplete combustion of organic matter such as fossil fuels. ... data and the heats of adsorption were found to fit well to a small group of mol. ...

Zoey R. Herm; Eric D. Bloch; Jeffrey R. Long

2013-11-22T23:59:59.000Z

5

& MetalOrganic Frameworks Enhancing CO2 Separation Ability of a MetalOrganic Framework  

E-Print Network (OSTI)

that it is a promising material for sequestering CO2 from landfill gas. Introduction Metal­organic frameworks have been considered as promising materials for separating CO2 from landfill gas and industrial flue gas due

Paik Suh, Myunghyun

6

Metal-Organic Frameworks with Precisely Designed Interior for...  

NLE Websites -- All DOE Office Websites (Extended Search)

Metal-Organic Frameworks with Precisely Designed Interior for Carbon Dioxide Capture in the Presence of Water...

7

Stepwise Synthesis of Robust Metal-Organic Frameworks via Postsyntheti...  

NLE Websites -- All DOE Office Websites (Extended Search)

Stepwise Synthesis of Robust Metal-Organic Frameworks via Postsynthetic Metathesis and Oxidation of Metal Nodes in a Single-Crystal to Single-Crystal Transformation Previous Next...

8

Isomerism in Metal–Organic Frameworks: “Framework Isomers”  

Science Journals Connector (OSTI)

His research interest focuses on the controlled formation, and eventual design, of metal–organic frameworks for application in gas storage for clean energy technologies. ... After that, he completed his M.Sc. in Applied Chemistry at New Mexico Highlands University where he worked on X-ray structure determination of low-melting organic materials and their complexes with mercury-organic compounds. ... This was observed upon heating Cd(abdc)bipy-1 under pressure to generate Cd(abdc)bipy-3, and exposing Cd(abdc)bipy-3 to air to reform Cd(abdc)bipy-1. ...

Trevor A. Makal; Andrey A. Yakovenko; Hong-Cai Zhou

2011-06-28T23:59:59.000Z

9

Metal binding in an aluminum based metal-organic framework for...  

NLE Websites -- All DOE Office Websites (Extended Search)

Metal binding in an aluminum based metal-organic framework for carbon dioxide capture Link to article...

10

Metal Organic Framework Research: High Throughput Discovery of Robust Metal Organic Framework for CO2 Capture  

SciTech Connect

IMPACCT Project: LBNL is developing a method for identifying the best metal organic frameworks for use in capturing CO2 from the flue gas of coal-fired power plants. Metal organic frameworks are porous, crystalline compounds that, based on their chemical structure, vary considerably in terms of their capacity to grab hold of passing CO2 molecules and their ability to withstand the harsh conditions found in the gas exhaust of coal-fired power plants. Owing primarily to their high tunability, metal organic frameworks can have an incredibly wide range of different chemical and physical properties, so identifying the best to use for CO2 capture and storage can be a difficult task. LBNL uses high-throughput instrumentation to analyze nearly 100 materials at a time, screening them for the characteristics that optimize their ability to selectively adsorb CO2 from coal exhaust. Their work will identify the most promising frameworks and accelerate their large-scale commercial development to benefit further research into reducing the cost of CO2 capture and storage.

None

2010-08-01T23:59:59.000Z

11

Photochromic Metal-Organic Frameworks: Reversible Control of...  

NLE Websites -- All DOE Office Websites (Extended Search)

Photochromic Metal-Organic Frameworks: Reversible Control of Singlet Oxygen Generation Previous Next List Jihye Park, Dawei Feng, Shuai Yuan and Hong-Cai Zhou, Angew. Chem. Int....

12

Hydrogen Storage in Metal-Organic Frameworks  

SciTech Connect

Conventional storage of large amounts of hydrogen in its molecular form is difficult and expensive because it requires employing either extremely high pressure gas or very low temperature liquid. Because of the importance of hydrogen as a fuel, the DOE has set system targets for hydrogen storage of gravimetric (5.5 wt%) and volumetric (40 g L-1) densities to be achieved by 2015. Given that these are system goals, a practical material will need to have higher capacity when the weight of the tank and associated cooling or regeneration system is considered. The size and weight of these components will vary substantially depending on whether the material operates by a chemisorption or physisorption mechanism. In the latter case, metal-organic frameworks (MOFs) have recently been identified as promising adsorbents for hydrogen storage, although little data is available for their sorption behavior. This grant was focused on the study of MOFs with these specific objectives. (1) To examine the effects of functionalization, catenation, and variation of the metal oxide and organic linkers on the low-pressure hydrogen adsorption properties of MOFs. (2) To develop a strategy for producing MOFs with high surface area and porosity to reduce the dead space and increase the hydrogen storage capacity per unit volume. (3) To functionalize MOFs by post synthetic functionalization with metals to improve the adsorption enthalpy of hydrogen for the room temperature hydrogen storage. This effort demonstrated the importance of open metal sites to improve the adsorption enthalpy by the systematic study, and this is also the origin of the new strategy, which termed isoreticular functionalization and metalation. However, a large pore volume is still a prerequisite feature. Based on our principle to design highly porous MOFs, guest-free MOFs with ultrahigh porosity have been experimentally synthesized. MOF-210, whose BET surface area is 6240 m2 g-1 (the highest among porous solids), takes up 15 wt% of total H2 uptake at 80 bar and 77 K. More importantly, the total H2 uptake by MOF-210 was 2.7 wt% at 80 bar and 298 K, which is the highest number reported for physisorptive materials.

Omar M. Yaghi

2012-04-26T23:59:59.000Z

13

Functional Mesoporous Metal-Organic Frameworks for the Capture...  

NLE Websites -- All DOE Office Websites (Extended Search)

Functional Mesoporous Metal-Organic Frameworks for the Capture of Heavy Metal Ions and Size-Selective Catalysis Previous Next List Qian-Rong Fang, Da-Qian Yuan, Julian Sculley,...

14

Recent advances as materials of functional metal-organic frameworks  

Science Journals Connector (OSTI)

Metal-organic frameworks (MOFs), also known as hybrid inorganic-organic materials, represent an emerging class of materials that have attracted the imagination of solid-state chemists because MOFs combine unprecedented levels of porosity with a range ...

Xiao-Lan Tong; Hai-Lu Lin; Jian-Hua Xin; Fen Liu; Min Li; Xia-Ping Zhu

2013-01-01T23:59:59.000Z

15

Carbon Dioxide Separation with Novel Microporous Metal Organic Frameworks  

NLE Websites -- All DOE Office Websites (Extended Search)

Separation with Separation with Novel Microporous Metal Organic Frameworks Background UOP LLC, the University of Michigan, and Northwestern University are collaborating on a three-year program to develop novel microporous metal organic frameworks (MOFs) suitable for CO 2 capture and separation. MOFs are hybrid organic/inorganic structures in which the organic moiety is readily derivatized. This innovative program is using sophisticated molecular modeling to evaluate the structurally

16

Carbon Dioxide Capture in Metal-Organic Frameworks | Center for...  

NLE Websites -- All DOE Office Websites (Extended Search)

Carbon Dioxide Capture in Metal-Organic Frameworks Previous Next List Kenji Sumida , David L. Rogow , Jarad A. Mason , Thomas M. McDonald , Eric D. Bloch , Zoey R. Herm , Tae-Hyun...

17

A versatile metal-organic framework for carbon dioxide capture...  

NLE Websites -- All DOE Office Websites (Extended Search)

versatile metal-organic framework for carbon dioxide capture and cooperative catalysis Previous Next List Jinhee Park, Jian-Rong Li, Ying-Pin Chen, Jiamei Yu, Andrey A. Yakovenko,...

18

Metal-Organic Frameworks as Adsorbents for Hydrogen Purification...  

NLE Websites -- All DOE Office Websites (Extended Search)

Metal-Organic Frameworks as Adsorbents for Hydrogen Purification and Precombustion Carbon Dioxide Capture Previous Next List Z. R. Herm, J. A. Swisher, B. Smit, R. Krishna, and J....

19

Omar Yaghi on Chemistry and Metal Organic Frameworks  

ScienceCinema (OSTI)

In this edited version of the hour long talk, Omar Yaghi, director of the Molecular Foundry, sat down in conversation with Jeff Miller, head of Public Affairs, on July 11th, 2012 to discuss his fascination with the hidden world of chemistry and his work on Metal Organic Frameworks.

Omar Yaghi

2013-06-24T23:59:59.000Z

20

Carbon Dioxide Separation with Novel Microporous Metal Organic Frameworks  

NLE Websites -- All DOE Office Websites (Extended Search)

David a. Lang David a. Lang Project Manager National Energy Technology Laboratory 626 Cochrans Mill Road P.O. Box 10940 Pittsburgh, PA 15236-0940 412-386-4881 david.lang@netl.doe.doe Richard Willis Principal Investigator UOP LLC 50 East Algonquin Road Des Plaines, IL 60016 847-391-3190 Richard.Willis@uop.com Carbon DioxiDe Separation with novel MiCroporouS Metal organiC FraMeworkS Background UOP LLC, in collaboration with Vanderbilt University and the University of Edinburgh, is working to develop novel microporous metal organic frameworks (MOFs) and an associated process for the removal of CO 2 from coal-fired power plant flue gas. This innovative project will exploit the latest discoveries in an extraordinary class of materials (MOFs) having extremely high adsorption capacities. MOFs have previously exhibited

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Microporous Metal-Organic Frameworks Incorporating 1,4-Benzeneditetrazolate: Syntheses, Structures, and  

E-Print Network (OSTI)

@berkeley.edu Abstract: The potential of tetrazolate-based ligands for forming metal-organic frameworks of utility

22

Stimuli-Responsive Metal Organic Frameworks: Stimuli-Responsive Metal Organic Frameworks for Energy-Efficient Post Combustion Capture  

SciTech Connect

IMPACCT Project: A team led by three professors at Texas A&M is developing a subset of metal organic frameworks that respond to stimuli such as small changes in temperature to trap CO2 and then release it for storage. These frameworks are a promising class of materials for carbon capture applications because their structure and chemistry can be controlled with great precision. Because the changes in temperature required to trap and release CO2 in Texas A&M’s frameworks are much smaller than in other carbon capture approaches, the amount of energy or stimulus that has to be diverted from coal-fired power plants to accomplish this is greatly reduced. The team is working to alter the materials so they bind only with CO2, and are stable enough to withstand the high temperatures found in the chimneys of coal-fired power plants.

None

2010-07-01T23:59:59.000Z

23

Metal-organic frameworks for Xe/Kr separation  

DOE Patents (OSTI)

Metal-organic framework (MOF) materials are provided and are selectively adsorbent to xenon (Xe) over another noble gas such as krypton (Kr) and/or argon (Ar) as a result of having framework voids (pores) sized to this end. MOF materials having pores that are capable of accommodating a Xe atom but have a small enough pore size to receive no more than one Xe atom are desired to preferentially adsorb Xe over Kr in a multi-component (Xe--Kr mixture) adsorption method. The MOF material has 20% or more, preferably 40% or more, of the total pore volume in a pore size range of 0.45-0.75 nm which can selectively adsorb Xe over Kr in a multi-component Xe--Kr mixture over a pressure range of 0.01 to 1.0 MPa.

Ryan, Patrick J.; Farha, Omar K.; Broadbelt, Linda J.; Snurr, Randall Q.; Bae, Youn-Sang

2013-08-27T23:59:59.000Z

24

Metal-organic frameworks for Xe/Kr separation  

DOE Patents (OSTI)

Metal-organic framework (MOF) materials are provided and are selectively adsorbent to xenon (Xe) over another noble gas such as krypton (Kr) and/or argon (Ar) as a result of having framework voids (pores) sized to this end. MOF materials having pores that are capable of accommodating a Xe atom but have a small enough pore size to receive no more than one Xe atom are desired to preferentially adsorb Xe over Kr in a multi-component (Xe--Kr mixture) adsorption method. The MOF material has 20% or more, preferably 40% or more, of the total pore volume in a pore size range of 0.45-0.75 nm which can selectively adsorb Xe over Kr in a multi-component Xe--Kr mixture over a pressure range of 0.01 to 1.0 MPa.

Ryan, Patrick J.; Farha, Omar K.; Broadbelt, Linda J.; Snurr, Randall Q.; Bae, Youn-Sang

2014-07-22T23:59:59.000Z

25

Methods for associating or dissociating guest materials with a metal organic framework, systems for associating or dissociating guest materials within a series of metal organic frameworks, thermal energy transfer assemblies, and methods for transferring thermal energy  

DOE Patents (OSTI)

Methods for releasing associated guest materials from a metal organic framework are provided. Methods for associating guest materials with a metal organic framework are also provided. Methods are provided for selectively associating or dissociating guest materials with a metal organic framework. Systems for associating or dissociating guest materials within a series of metal organic frameworks are provided. Thermal energy transfer assemblies are provided. Methods for transferring thermal energy are also provided.

McGrail, B. Peter; Brown, Daryl R.; Thallapally, Praveen K.

2014-08-05T23:59:59.000Z

26

The Chemistry and Applications of Metal-Organic Frameworks  

Science Journals Connector (OSTI)

...Anson C. E. Powell A. K. , Iron(II) formate [Fe...carbon dioxide capture in an iron-based sodalite-type...IRMOF-3 with a manganese(II) acetylacetonate complex . Chem. Commun. 47...Postsynthetic modifications of iron-carboxylate nanoscale metal-organic...

Hiroyasu Furukawa; Kyle E. Cordova; Michael O’Keeffe; Omar M. Yaghi

2013-08-30T23:59:59.000Z

27

Defining the Proton Topology of the Zr6Based Metal-Organic Framework NU-1000  

E-Print Network (OSTI)

,16-19 heavy metal capture,20,21 sensing,12 ionic conductivity,22 toxic industrial chemical capture,23Defining the Proton Topology of the Zr6Based Metal-Organic Framework NU-1000 Nora Planas,, Joseph E of Science, King Abdulaziz University, Jeddah, Saudi Arabia *S Supporting Information ABSTRACT: Metal

28

Ab-initio Carbon Capture in Open-Site Metal Organic Frameworks...  

NLE Websites -- All DOE Office Websites (Extended Search)

Ab-initio Carbon Capture in Open-Site Metal Organic Frameworks Previous Next List A. Dzubak, L.-C. Lin, J. Kim, J. A. Swisher, R. Poloni, S. N. Maximoff, B. Smit, and L. Gagliardi,...

29

Symmetry-Guided Synthesis of Highly Porous Metal-Organic Frameworks...  

NLE Websites -- All DOE Office Websites (Extended Search)

Symmetry-Guided Synthesis of Highly Porous Metal-Organic Frameworks with Fluorite Topology Previous Next List Muwei Zhang, Ying-Pin Chen, Mathieu Bosch, Thomas Gentle III, Kecheng...

30

Cation exchange at the secondary building units of metal–organic frameworks  

E-Print Network (OSTI)

Cation exchange is an emerging synthetic route for modifying the secondary building units (SBUs) of metal–organic frameworks (MOFs). This technique has been used extensively to enhance the properties of nanocrystals and ...

Brozek, Carl Kavanaugh

31

Neutron powder diffraction of metal-organic frameworks for hydrogen storage  

Science Journals Connector (OSTI)

We review recent structural studies that we have undertaken aimed at elucidating the fundamental properties of metal-organic framework materials and their interactions with hydrogen. We have shown that exposin...

Craig M. Brown; Yun Liu; Dan A. Neumann

2008-10-01T23:59:59.000Z

32

Synthesis and Characterization of Films and Membranes of Metal-Organic Framework (MOF) for Gas Separation Applications  

E-Print Network (OSTI)

Metal-Organic Frameworks (MOFs) are nanoporous framework materials with tunable pore size and functionality, and hence attractive for gas separation membrane applications. Zeolitic Imidazolate Frameworks (ZIFs), a subclass of MOFs, are known...

Shah, Miral Naresh 1987-

2012-12-12T23:59:59.000Z

33

Highly efficient separation of carbon dioxide by a metal-organic framework replete with  

E-Print Network (OSTI)

Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal capture of CO2, which is essential for natural gas purifi- cation and CO2 sequestration, has been reported media. carbon dioxide capture dynamic adsorption reticular chemistry Selective removal of CO2 from

Yaghi, Omar M.

34

Increasing the Stability of Metal-Organic Frameworks | Center...  

NLE Websites -- All DOE Office Websites (Extended Search)

functional groups and unsaturated metal centers have afforded excellent gas sorption and separation ability, catalytic activity, luminescent properties, and more....

35

Methane Storage in Metal-Organic Frameworks: Current Records, Surprise Findings, and Challenges  

E-Print Network (OSTI)

bridging fuel to a low- carbon energy future. Methane delivers roughly twice the energy of coal in terms of the amount of carbon dioxide released. In contrast to coal, methane does so without dissipating mercuryMethane Storage in Metal-Organic Frameworks: Current Records, Surprise Findings, and Challenges

36

Metal-Organic Framework Thin Films Composed of Free-Standing Acicular Nanorods Exhibiting Reversible Electrochromism  

E-Print Network (OSTI)

Reversible Electrochromism Chung-Wei Kung, Timothy Chiaan Wang, Joseph E. Mondloch, David Fairen electrochromic switching between yellow and deep blue by means of a one-electron redox reaction at its pyrene and rapid switching rate. KEYWORDS: electrochromism, metal-organic frameworks, one-dimensional nanorods

37

DOI: 10.1002/adfm.200600944 Microporous MetalOrganic Frameworks with High Gas Sorption  

E-Print Network (OSTI)

DOI: 10.1002/adfm.200600944 Microporous Metal­Organic Frameworks with High Gas Sorption on several different SBUs. They exhibit unique gas sorption behavior and high selectivity for adsorbing: triethylenediamine; DMF: dimethylform- amide) and their argon, hydrogen, and hydrocarbon sorption properties

Li, Jing

38

Theoretical Limits of Hydrogen Storage in Metal-Organic Frameworks: Opportunities and Trade-Offs  

E-Print Network (OSTI)

technologies has highlighted the need for high- density energy storage.1 In the case of fuel cell vehicles (FCVTheoretical Limits of Hydrogen Storage in Metal-Organic Frameworks: Opportunities and Trade predict the hydrogen storage properties of these compounds. Approximately 20 000 candidate compounds were

Cafarella, Michael J.

39

CO2 Removal from Flue Gas Using MIcroporous Metal Organic Frameworks  

NLE Websites -- All DOE Office Websites (Extended Search)

Removal from Flue Gas Using Removal from Flue Gas Using Microporous Metal Organic Frameworks Background The mission of the U.S. Department of Energy's (DOE) Existing Plants, Emissions, & Capture (EPEC) Research & Development (R&D) Program is to develop innovative environmental control technologies to enable full use of the nation's vast coal reserves, while at the same time allowing the current fleet of coal-fired power plants to comply with existing and emerging environmental regulations. The EPEC R&D

40

Metal?organic frameworks for the storage and delivery of biologically active hydrogen sulfide  

SciTech Connect

Hydrogen sulfide is an extremely toxic gas that is also of great interest for biological applications when delivered in the correct amount and at the desired rate. Here we show that the highly porous metal-organic frameworks with the CPO-27 structure can bind the hydrogen sulfide relatively strongly, allowing the storage of the gas for at least several months. Delivered gas is biologically active in preliminary vasodilation studies of porcine arteries, and the structure of the hydrogen sulfide molecules inside the framework has been elucidated using a combination of powder X-ray diffraction and pair distribution function analysis.

Allan, Phoebe K.; Wheatley, Paul S.; Aldous, David; Mohideen, M. Infas; Tang, Chiu; Hriljac, Joseph A.; Megson, Ian L.; Chapman, Karena W.; De Weireld, Guy; Vaesen, Sebastian; Morris, Russell E. (St Andrews)

2012-04-02T23:59:59.000Z

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Published on Web 12/23/2007 Matrix Isolation Chemistry in a Porous Metal-Organic Framework  

E-Print Network (OSTI)

Published on Web 12/23/2007 Matrix Isolation Chemistry in a Porous Metal-Organic Framework, during which time the colorless solid turned dark red, indicating the attachment of Cr(CO)3 units. Upon

42

Improved hydrogen storage capacity by hydrogen spillover and fine structural characterization of MIL-100 metal organic frameworks  

Science Journals Connector (OSTI)

The MIL-100 metal organic framework was synthesized through solvothermal route, modified with Pt-loaded active carbon and H2 adsorption capacity was evaluated. The maximum specific surface area of MIL-100 was obt...

Abhijit Krishna Adhikari; Kuen-Song Lin…

2014-11-01T23:59:59.000Z

43

Selective Hydrogenation of Biomass Based 5-Hydroxymethylfurfural over Catalyst of Palladium Immobilized on Amine-Functionalized Metal–Organic Frameworks  

Science Journals Connector (OSTI)

Selective Hydrogenation of Biomass Based 5-Hydroxymethylfurfural over Catalyst of Palladium Immobilized on Amine-Functionalized Metal–Organic Frameworks ... A catalyst of palladium [Pd/MIL-101(Al)-NH2] supported on amine-functionalized Metal–Organic Frameworks (MOFs) allows selective hydrogenation of biomass-based 5-hydroxymethylfurfural (HMF) to 2,5-dihydroxymethyl-tetrahydrofuran (DHMTHF) with 2,5-dihydroxymethylfuran (DHMF) as an observed “intermediate”. ...

Jinzhu Chen; Ruliang Liu; Yuanyuan Guo; Limin Chen; Hui Gao

2014-12-16T23:59:59.000Z

44

Lithium inclusion in indium metal-organic frameworks showing increased surface area and hydrogen adsorption  

SciTech Connect

Investigation of counterion exchange in two anionic In-Metal-Organic Frameworks (In-MOFs) showed that partial replacement of disordered ammonium cations was achieved through the pre-synthetic addition of LiOH to the reaction mixture. This resulted in a surface area increase of over 1600% in (Li [In(1,3 ? BDC){sub 2}]){sub n} and enhancement of the H{sub 2} uptake of approximately 275% at 80?000 Pa at 77 K. This method resulted in frameworks with permanent lithium content after repeated solvent exchange as confirmed by inductively coupled plasma mass spectrometry. Lithium counterion replacement appears to increase porosity after activation through replacement of bulkier, softer counterions and demonstrates tuning of pore size and properties in MOFs.

Bosch, Mathieu; Zhang, Muwei; Feng, Dawei; Yuan, Shuai; Wang, Xuan [Department of Chemistry, Texas A and M University, College Station, Texas 77842 (United States); Chen, Ying-Pin [Department of Materials Science and Engineering, Texas A and M University, College Station, Texas 77842 (United States); Zhou, Hong-Cai, E-mail: zhou@mail.chem.tamu.edu [Department of Chemistry, Texas A and M University, College Station, Texas 77842 (United States); Department of Materials Science and Engineering, Texas A and M University, College Station, Texas 77842 (United States)

2014-12-01T23:59:59.000Z

45

System and method for generating and/or screening potential metal-organic frameworks  

DOE Patents (OSTI)

A system and method for systematically generating potential metal-organic framework (MOFs) structures given an input library of building blocks is provided herein. One or more material properties of the potential MOFs are evaluated using computational simulations. A range of material properties (surface area, pore volume, pore size distribution, powder x-ray diffraction pattern, methane adsorption capability, and the like) can be estimated, and in doing so, illuminate unidentified structure-property relationships that may only have been recognized by taking a global view of MOF structures. In addition to identifying structure-property relationships, this systematic approach to identify the MOFs of interest is used to identify one or more MOFs that may be useful for high pressure methane storage.

Wilmer, Christopher E; Leaf, Michael; Snurr, Randall Q; Farha, Omar K; Hupp, Joseph T

2014-12-02T23:59:59.000Z

46

Supramolecular structures and metal-organic frameworks based on metal dipyrrin building blocks  

E-Print Network (OSTI)

in organic solvents, but are dichroic red/green solids upongreen blocks were grown by diffusion of pentane into a toluene solution containing the complex. No solvent

Halper, Sara R.

2006-01-01T23:59:59.000Z

47

Design and Synthesis of Novel Porous Metal-Organic Frameworks (MOFs) Toward High Hydrogen Storage Capacity  

SciTech Connect

Statement of Objectives: 1. Synthesize viable porous MOFs for high H2 storage at ambient conditions to be assessed by measuring H2 uptake. 2. Develop a better understanding of the operative interactions of the sorbed H2 with the organic and inorganic constituents of the sorbent MOF by means of inelastic neutron scattering (INS, to characterize the H2-MOF interactions) and computational studies (to interpret the data and predict novel materials suitable for high H2 uptake at moderate temperatures and relatively low pressures). 3. Synergistically combine the outcomes of objectives 1 and 2 to construct a made-to-order inexpensive MOF that is suitable for super H2 storage and meets the DOE targets - 6% H2 per weight (2kWh/kg) by 2010 and 9% H2 per weight (3kWh/kg) by 2015. The ongoing research is a collaborative experimental and computational effort focused on assessing H2 storage and interactions with pre-selected metal-organic frameworks (MOFs) and zeolite-like MOFs (ZMOFs), with the eventual goal of synthesizing made-to-order high H2 storage materials to achieve the DOE targets for mobile applications. We proposed in this funded research to increase the amount of H2 uptake, as well as tune the interactions (i.e. isosteric heats of adsorption), by targeting readily tunable MOFs:

Mohamed, Eddaoudi [USF; Zaworotko, Michael [USF; Space, Brian [USF; Eckert, Juergen [USF

2013-05-08T23:59:59.000Z

48

Facile xenon capture and release at room temperature using a metal-organic framework: a comparison with activated charcoal  

SciTech Connect

Two well known Metal organic frameworks (MOF-5, NiDOBDC) were synthesized and studied for facile xenon capture and separation. Our results indicate the NiDOBDC adsorbs significantly more xenon than MOF-5, releases it more readily than activated carbon, and is more selective for Xe over Kr than activated carbon.

Thallapally, Praveen K.; Grate, Jay W.; Motkuri, Radha K.

2012-01-11T23:59:59.000Z

49

Metal-Organic Frameworks with Precisely Designed Interior for Carbon Dioxide Capture in the Presence of Water  

E-Print Network (OSTI)

Metal-Organic Frameworks with Precisely Designed Interior for Carbon Dioxide Capture preservation of the IRMOF structure. Carbon dioxide capture from combustion sources such as flue gas in power this carbon capture challenge. The preferred method for measuring the efficiency of a given material

Yaghi, Omar M.

50

Porous Metal-Organic Framework with Coordinatively Unsaturated MnII Sites:Sorption Properties for Various Gases  

E-Print Network (OSTI)

Porous Metal-Organic Framework with Coordinatively Unsaturated MnII Sites:Sorption Properties solid [Mn(NDC)]n (2), which contains coordinatively unsaturated MnII sites, reveals remarkable sorption capabilities for N2, H2, CO2, and CH4 gases and exhibits type I sorption behavior indicative of permanent

Paik Suh, Myunghyun

51

Composite Membranes for CO2 Capture: High Performance Metal Organic Frameworks/Polymer Composite Membranes for Carbon Dioxide Capture  

SciTech Connect

IMPACCT Project: A team of six faculty members at Georgia Tech are developing an enhanced membrane by fitting metal organic frameworks, compounds that show great promise for improved carbon capture, into hollow fiber membranes. This new material would be highly efficient at removing CO2 from the flue gas produced at coal-fired power plants. The team is analyzing thousands of metal organic frameworks to identify those that are most suitable for carbon capture based both on their ability to allow coal exhaust to pass easily through them and their ability to select CO2 from that exhaust for capture and storage. The most suitable frameworks would be inserted into the walls of the hollow fiber membranes, making the technology readily scalable due to their high surface area. This composite membrane would be highly stable, withstanding the harsh gas environment found in coal exhaust.

None

2010-07-01T23:59:59.000Z

52

Stress-induced chemical detection using flexible metal-organic frameworks.  

SciTech Connect

In this work we demonstrate the concept of stress-induced chemical detection using metal-organic frameworks (MOFs) by integrating a thin film of the MOF HKUST-1 with a microcantilever surface. The results show that the energy of molecular adsorption, which causes slight distortions in the MOF crystal structure, can be efficiently converted to mechanical energy to create a highly responsive, reversible, and selective sensor. This sensor responds to water, methanol, and ethanol vapors, but yields no response to either N{sub 2} or O{sub 2}. The magnitude of the signal, which is measured by a built-in piezoresistor, is correlated with the concentration and can be fitted to a Langmuir isotherm. Furthermore, we show that the hydration state of the MOF layer can be used to impart selectivity to CO{sub 2}. We also report the first use of surface-enhanced Raman spectroscopy to characterize the structure of a MOF film. We conclude that the synthetic versatility of these nanoporous materials holds great promise for creating recognition chemistries to enable selective detection of a wide range of analytes. A force field model is described that successfully predicts changes in MOF properties and the uptake of gases. This model is used to predict adsorption isotherms for a number of representative compounds, including explosives, nerve agents, volatile organic compounds, and polyaromatic hydrocarbons. The results show that, as a result of relatively large heats of adsorption (> 20 kcal mol{sup -1}) in most cases, we expect an onset of adsorption by MOF as low as 10{sup -6} kPa, suggesting the potential to detect compounds such as RDX at levels as low as 10 ppb at atmospheric pressure.

Allendorf, Mark D.; Hesketh, Peter J. (Georgia Institute of Technology, Atlanta, GA); Gall, Kenneth A. (Georgia Institute of Technology, Atlanta, GA); Choudhury, A. (Georgia Institute of Technology, Atlanta, GA); Pikarsky, J. (Georgia Institute of Technology, Atlanta, GA); Andruszkiewicz, Leanne (Georgia Institute of Technology, Atlanta, GA); Houk, Ronald J. T.; Talin, Albert Alec (National Institute of Standards & Technology, Gaithersburg, MD)

2009-09-01T23:59:59.000Z

53

From Stimuli-Responsive Polymorphic Organic Dye Crystals to Photoluminescent Cationic Open-Framework Metal Phosphate  

Science Journals Connector (OSTI)

Four photoluminescent dye crystals, TPB-n (n = 1–3) and TPCH, have been synthesized in isolation from carbon–carbon coupling of 4,4?-trimethylene-dipyridine (tmdp) in the absence of organic solvent and catalyst via in situ one-pot metal/ligand oxidative-...

Yu-Chuan Chang; Sue-Lein Wang

2012-05-03T23:59:59.000Z

54

Carbon Dioxide Removal from Flue Gas Using Microporous Metal Organic Frameworks  

SciTech Connect

UOP LLC, a Honeywell Company, in collaboration with Professor Douglas LeVan at Vanderbilt University (VU), Professor Adam Matzger at the University of Michigan (UM), Professor Randall Snurr at Northwestern University (NU), and Professor Stefano Brandani at the University of Edinburgh (UE), supported by Honeywell's Specialty Materials business unit and the Electric Power Research Institute (EPRI), have completed a three-year project to develop novel microporous metal organic frameworks (MOFs) and an associated vacuum-pressure swing adsorption (vPSA) process for the removal of CO{sub 2} from coal-fired power plant flue gas. The project leveraged the team's complementary capabilities: UOP's experience in materials development and manufacturing, adsorption process design and process commercialization; LeVan and Brandani's expertise in high-quality adsorption measurements; Matzger's experience in syntheis of MOFs and the organic components associated with MOFs; Snurr's expertise in molecular and other modeling; Honeywell's expertise in the manufacture of organic chemicals; and, EPRI's knowledge of power-generation technology and markets. The project was successful in that a selective CO{sub 2} adsorbent with good thermal stability and reasonable contaminant tolerance was discovered, and a low cost process for flue gas CO{sub 2} capture process ready to be evaluated further at the pilot scale was proposed. The team made significant progress toward the current DOE post-combustion research targets, as defined in a recent FOA issued by NETL: 90% CO{sub 2} removal with no more than a 35% increase in COE. The team discovered that favorable CO{sub 2} adsorption at more realistic flue gas conditions is dominated by one particular MOF structure type, M/DOBDC, where M designates Zn, Co, Ni, or Mg and DOBDC refers to the form of the organic linker in the resultant MOF structure, dioxybenzenedicarboxylate. The structure of the M/DOBDC MOFs consists of infinite-rod secondary building units bound by DOBDC resulting in 1D hexagonal pores about 11 angstroms in diameter. Surface areas range from 800 to 1500 sq m/g for the different MOFs. Mg/DOBDC outperformed all MOF and zeolite materials evaluated to date, with about 25 wt% CO{sub 2} captured by this MOF at flue gas conditions ({approx}0.13 atm CO{sub 2} pressure, 311K). In simulated flue gas without oxygen, the zero-length (ZLC) system was very useful in quickly simulating the effect of long term exposure to impurities on the MOFs. Detailed adsorption studies on MOF pellets have shown that water does not inhibit CO{sub 2} adsorption for MOFs as much as it does for typical zeolites. Moreover, some MOFs retain a substantial CO{sub 2} capacity even with a modest water loading at room temperature. Molecular modeling was a key activity in three areas of our earlier DOE/NETL-sponsored MOF-based research on CC. First, the team was able to effectively simulate CO{sub 2} and other gas adsorption isotherms for more than 20 MOFs, and the knowledge obtained was used to help predict new MOF structures that should be effective for CO{sub 2} adsorption at low pressure. The team also showed that molecular modeling could be utilized to predict the hydrothermal stability of a given MOF. Finally, the team showed that low moisture level exposure actually enhanced the CO{sub 2} adsorption performance of a particular MOF, HKUST-1.

David A Lesch

2010-06-30T23:59:59.000Z

55

A “Ship in a Bottle” Strategy To Load a Hydrophilic Anticancer Drug in Porous Metal Organic Framework Nanoparticles: Efficient Encapsulation, Matrix Stabilization, and Photodelivery  

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A “Ship in a Bottle” Strategy To Load a Hydrophilic Anticancer Drug in Porous Metal Organic Framework Nanoparticles: Efficient Encapsulation, Matrix Stabilization, and Photodelivery ... The attachment of the GO C layers to the spherical cages of MIL-100(Fe) (via coordination between the O groups of GO and the metallic sites of the metal-org. ...

Maria Rosaria di Nunzio; Valentina Agostoni; Boiko Cohen; Ruxandra Gref; Abderrazzak Douhal

2013-12-17T23:59:59.000Z

56

Metal–organic frameworks of the MIL-101 family as heterogeneous single-site catalysts  

Science Journals Connector (OSTI)

...provided the size of pore entrances...contrast to zeolites and mesoporous...substrate conversion and enone...Unlike zeolites and metal-silicates...washed with methanol and dried...figure-6) studies confirmed...air; the conversion is usually...using just small additives...production of ethylene carbonate...titanosilicates and zeolites (Sakakura...synthesis of propylene (table-4...

2012-01-01T23:59:59.000Z

57

Rationally tuned micropores within enantiopure metal-organic frameworks for highly selective separation of acetylene and ethylene  

SciTech Connect

Separation of acetylene and ethylene is an important industrial process because both compounds are essential reagents for a range of chemical products and materials. Current separation approaches include the partial hydrogenation of acetylene into ethylene over a supported Pd catalyst, and the extraction of cracked olefins using an organic solvent; both routes are costly and energy consuming. Adsorption technologies may allow separation, but microporous materials exhibiting highly selective adsorption of C{sub 2}H{sub 2}/C{sub 2}H{sub 4} have not been realized to date. Here, we report the development of tunable microporous enantiopure mixed-metal-organic framework (M'MOF) materials for highly selective separation of C{sub 2}H{sub 2} and C{sub 2}H{sub 4}. The high selectivities achieved suggest the potential application of microporous M'MOFs for practical adsorption-based separation of C{sub 2}H{sub 2}/C{sub 2}H{sub 4}.

Xiang, Sheng-Chang [University of Texas at San Antonio (UTSA); Zhang, Zhangjing [University of Texas at San Antonio (UTSA); Zhao, Cong-Gui [University of Texas at San Antonio (UTSA); Hong, Kunlun [ORNL; Zhao, Xuebo [University of Newcastle upon Tyne; Ding, De-Rong [University of Texas at San Antonio (UTSA); Xie, Ming-Hua [University of Texas, Pan American, Edinburg, TX; Wu, Chuan-De [University of Texas, Pan American, Edinburg, TX; Madhab, Das [University of Texas at San Antonio (UTSA); Gill, Rachel [University of Newcastle upon Tyne; Thomas, K Mark [University of Newcastle upon Tyne; Chen, Banglin [University of Texas at San Antonio (UTSA)

2011-01-01T23:59:59.000Z

58

Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal-Organic Framework mmen-Mg2(dobpdc)  

E-Print Network (OSTI)

Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine- Appended Metal-Organic Framework, stationary sources like coal-fired power plants, carbon capture and sequestration (CCS) has been proposed.4 viable absorbents for carbon capture under the aforementioned conditions, and they are presently used

59

Preparation of metal-triazolate frameworks  

DOE Patents (OSTI)

The disclosure provides for novel metal-triazolate frameworks, methods of use thereof, and devices comprising the frameworks thereof.

Yaghi, Omar M; Uribe-Romo, Fernando J; Gandara-Barragan, Felipe; Britt, David K

2014-10-07T23:59:59.000Z

60

Synthetic Design of New Metal-Organic Framework Materials for Hydrogen Storage - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

9 9 FY 2012 Annual Progress Report DOE Hydrogen and Fuel Cells Program Pingyun Feng (Primary Contact), Qipu Lin, Xiang Zhao Department of Chemistry University of California Riverside, CA 92521 Phone: (951) 827-2042 Email: pingyun.feng@ucr.edu DOE Program Officer: Dr. Michael Sennett Phone: (301) 903-6051 Email: Michael.Sennett@science.doe.gov Objectives Design and * synthesize new metal-organic framework materials using lightweight chemical elements to help improve gravimetric hydrogen storage capacity. Develop new synthetic strategies to generate novel * active binding sites on metal ions and ligands to enhance solid-gas interactions for increased uptake near ambient conditions.

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61

A Biomimetic Approach to Metal-Organic Frameworks with High H2 Uptake - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

0 0 DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report Hong-Cai (Joe) Zhou Dept. of Chem., Texas A&M University P.O. Box 30012 College Station, TX 77842-3012 Phone: (979) 845-4034 Email: zhou@mail.chem.tamu.edu DOE Managers HQ: Ned Stetson Phone: (202) 586-9995 Email: Ned.Stetson@ee.doe.gov GO: Jesse Adams Phone: (720) 356-1421 Email: Jesse.Adams@go.doe.gov Contract Number: DE-FC36-07GO17033 Project Start Date: July 1, 2007 Project End Date: June 30, 2013 Fiscal Year (FY) 2012 Objectives Design, synthesis, and characterization of metal-organic * frameworks (MOFs) with potential anchors for active metal centers introduction. Design, synthesis, and optimization of porous polymer * frameworks (PPNs) with different functionalities. These functionalized MOFs and PPNs demonstrate much *

62

Preparation and Analysis of Cyclodextrin-Based Metal–Organic Frameworks: Laboratory Experiments Adaptable for High School through Advanced Undergraduate Students  

Science Journals Connector (OSTI)

First-Year Undergraduate/General; Second-Year Undergraduate; Upper-Division Undergraduate; Laboratory Instruction; Inorganic Chemistry; High School/Introductory Chemistry; Hands-On Learning/Manipulatives; Materials Science; Crystals/Crystallography; Green Chemistry ... The authors gratefully acknowledge financial support from Wesleyan University and the National Science Foundation CAREER program (award CHE-1352239). ... (a) Furukawa, H.; Cordova, K. E.; O’Keeffe, M.; Yaghi, O. M.The Chemistry and Applications of Metal-Organic Frameworks Science 2013, 341 ( 6149) 974– 986 ...

Merry K. Smith; Samantha R. Angle; Brian H. Northrop

2014-11-06T23:59:59.000Z

63

One-pot synthesis of a metal–organic framework as an anode for Li-ion batteries with improved capacity and cycling stability  

SciTech Connect

Metal–organic framework is a kind of novel electrode materials for lithium ion batteries. Here, a 3D metal–organic framework Co{sub 2}(OH){sub 2}BDC (BDC=1,4-benzenedicarboxylate) was synthesized for the first time by the reaction of Co{sup 2+} with a bio-inspired renewable organic ligand 1,4-benzenedicarboxylic acid through a solvothermal method. As an anode material for lithium ion batteries, this material exhibited an excellent cyclic stability as well as a large reversible capacity of ca. 650 mA h g{sup ?1} at a current density of 50 mA g{sup ?1} after 100 cycles within the voltage range of 0.02–3.0 V, higher than that of other BDC based anode. - Graphical abstract: The PXRD pattern and the cycleability curves (inset) of Co{sub 2}(OH){sub 2}BDC. Display Omitted - Highlights: • Co{sub 2}(OH){sub 2}BDC was synthesized through a one pot solvothermal process. • The solvent had a great effect on the purity of this material. • This material was used as anode material for lithium ion batteries for the first time. • Co{sub 2}(OH){sub 2}BDC showed improved capacity and cycling stability.

Gou, Lei, E-mail: Leigou@chd.edu.cn; Hao, Li-Min; Shi, Yong-Xin; Ma, Shou-Long; Fan, Xiao-Yong; Xu, Lei; Li, Dong-Lin, E-mail: dlli@chd.edu.cn; Wang, Kang

2014-02-15T23:59:59.000Z

64

2D?3D polycatenated and 3D?3D interpenetrated metal–organic frameworks constructed from thiophene-2,5-dicarboxylate and rigid bis(imidazole) ligands  

SciTech Connect

Hydrothermal reactions of rigid 1,4-bis(imidazol-1-yl)benzene (dib) and 1,4-bis(imidazol-1-yl)-2,5-dimethylbenzene (dimb) with deprotonated thiophene-2,5-dicarboxylic acid (H{sub 2}tdc) in the presence of Zn(II) and Cd(II) salts in H{sub 2}O produced three new metal–organic frameworks, namely, [Zn(µ-tdc)(H{sub 2}O)(µ-dib)]{sub n} (1), [Cd(µ-tdc)(H{sub 2}O)(µ-dib)]{sub n} (2), and ([Cd{sub 2}(µ{sub 3}-tdc){sub 2}(µ-dimb){sub 2}]·(H{sub 2}O)){sub n}(3). These MOFs were characterized by FT-IR spectroscopy, elemental, thermal (TG, DTA, DTG and DSC), and single-crystal X-ray diffraction analyses. Isomorphous complexes 1 and 2 reveal polycatenated 2D+2D?3D framework based on an undulated (4,4)-sql layer. Complex 3 exhibits a new 4-fold interpenetrating 3D framework with the point symbol of 6{sup 6}. Molecular simulations were used to assess the potentials of the complexes for H{sub 2} storage application. Moreover, these coordination polymers exhibit blue fluorescent emission bands in the solid state at room temperature. - Graphical abstract: In this study, hydrothermal reactions of rigid 1,4-bis(imidazol-1-yl)benzene (dib) and 1,4-bis(imidazol-1-yl)-2,5-dimethylbenzene (dimb) with deprotonated thiophene-2,5-dicarboxylic acid (H{sub 2}tdc) in the presence of Zn(II) and Cd(II) salts in H{sub 2}O produced three new metal–organic frameworks. Isomorphous complexes 1 and 2 reveal polycatenated 2D+2D?3D framework based on an undulated (4,4)-sql layer. Complex 3 exhibits a new 4-fold interpenetrating 3D framework with the point symbol of 6{sup 6}. Molecular simulations were used to assess the potentials of the complexes for H{sub 2} storage application. These coordination polymers exhibit blue fluorescent emission bands in the solid state at room temperature. Display Omitted - Highlights: • Complexes 1 and 2 display polycatenated 2D+2D?3D framework. • Complex 3 exhibits a new 4-fold interpenetrating 3D framework. • Complex 1 adsorbs the highest amount of H{sub 2} at 100 bar and 298 K. • Complexes display blue fluorescent emission bands.

Erer, Hakan [Department of Chemistry, Faculty of Arts and Sciences, Eski?ehir Osmangazi University, 26480 Eski?ehir (Turkey); Ye?ilel, Okan Zafer, E-mail: yesilel@ogu.edu.tr [Department of Chemistry, Faculty of Arts and Sciences, Eski?ehir Osmangazi University, 26480 Eski?ehir (Turkey); Ar?c?, Mürsel [Department of Chemistry, Faculty of Arts and Sciences, Eski?ehir Osmangazi University, 26480 Eski?ehir (Turkey); Keskin, Seda [Department of Chemical and Biological Engineering, Koç University, ?stanbul (Turkey); Büyükgüngör, Orhan [Department of Physics, Faculty of Arts and Sciences, Ondokuz May?s University, 55139 Samsun (Turkey)

2014-02-15T23:59:59.000Z

65

Magnetism in metal-organic capsules  

SciTech Connect

Nickel and cobalt seamed metal-organic capsules have been isolated and studied using structural, magnetic and computational approaches. Antiferromagnetic exchange in the Ni capsule results from coordination environments enforced by the capsule framework.

Atwood, Jerry L.; Brechin, Euan K; Dalgarno, Scott J.; Inglis, Ross; Jones, Leigh F.; Mossine, Andrew; Paterson, Martin J.; Power, Nicholas P.; Teat, Simon J.

2010-01-07T23:59:59.000Z

66

Photophysical Studies of Ru(II)tris(2,2;#8242;-bipyridine) Confined within a Zn(II)?Trimesic Acid Polyhedral Metal?Organic Framework  

SciTech Connect

The ability to confine photoactive catalysts within metal-organic framework (MOF) materials affords the opportunity to expand the functional diversity of these materials into solar based applications. Here, the confinement of Ru(II)tris(2,2'-bipyridine) (RuBpy) by a MOF material derived from Zn(II) ions and trimesic acid (hereafter, USF2) is examined. Although the encapsulated RuBpy could not be crystallographically resolved within the MOF framework, the photophysical properties of the complex are characteristic of confinement including extended triplet metal-to-ligand ({sup 3}MLCT) lifetime ({tau}{sub ethanol} = 614 ns and {tau}{sub USF2} = 1.2 {micro}s at 25 C) and a slight hypsochromic shift in the steady-state emission spectrum relative to RuBpy in ethanol. The extended lifetime is attributed to a deactivation of a nonradiative {sup 3}dd that is antibonding with respect to the Ru(II)-bipyridine due to a confined molecular environment. These results represent one of the first examples of RuBpy encapsulation and photophysical characterization within a polyhedral MOF material.

Larsen, Randy W.; Wojtas, Lukasz (USF)

2012-10-25T23:59:59.000Z

67

Broadly Hysteretic H2 Adsorption in the Microporous Metal-Organic Framework Co(1,4-benzenedipyrazolate)  

E-Print Network (OSTI)

H2 storage capacity. Recognizing the promise of certain tetrazolate-bridged frameworks for high. This result suggests that the high basicity of pyrazolate relative to tetrazolate imparts increased strength

68

Preparation of metal-catecholate frameworks  

SciTech Connect

The disclosure provides for metal catecholate frameworks, and methods of use thereof, including gas separation, gas storage, catalysis, tunable conductors, supercapacitors, and sensors.

Yaghi, Omar M.; Gandara-Barragan, Felipe; Lu, Zheng; Wan, Shun

2014-06-03T23:59:59.000Z

69

Origin of the exceptional negative thermal expansion in metal-organic framework-5 Zn4O(1,4-benzenedicarboxylate)3  

Science Journals Connector (OSTI)

Metal organic framework-5 (MOF-5) was recently suggested to possess an exceptionally large negative thermal-expansion coefficient. Our direct experimental measurement of the thermal expansion of MOF-5 using neutron powder diffraction, in the temperature range of 4 to 600 K, shows that the linear thermal-expansion coefficient is ??16×10?6?K?1. To understand the origin of this large negative thermal-expansion behavior, we performed first-principles lattice dynamics calculations. The calculated thermal-expansion coefficients within quasiharmonic approximation agree well with the experimental data. We found that almost all low-frequency lattice vibrational modes (below ?23?meV) involve the motion of the benzene rings and the ZnO4 clusters as rigid units and the carboxyl groups as bridges. These so-called “rigid-unit modes” exhibit various degrees of phonon softening (i.e., the vibrational energy decreases with contracting crystal lattice) and thus are directly responsible for the large negative thermal expansion in MOF-5. Initial efforts were made to observe the phonon softening experimentally.

W. Zhou; H. Wu; T. Yildirim; J. R. Simpson; A. R. Hight Walker

2008-08-20T23:59:59.000Z

70

Amorphous Metal–Organic Frameworks  

Science Journals Connector (OSTI)

The tuning of release times of MOF drug delivery vehicles by partial structural collapse may be possible, and aMOFs are often more mechanically robust than crystalline materials, which is of importance for industrial applications. ... Fe3O(BTC)2F·H2O aerogelb ... H(2)-air polymer-electrolyte-membrane fuel cells are electrochemical power generators with potential vehicle propulsion applications. ...

Thomas D. Bennett; Anthony K. Cheetham

2014-04-07T23:59:59.000Z

71

Adsorption and Separation of Light Gases on an Amino-Functionalized Metal–Organic Framework: An Adsorption and In Situ XRD Study  

SciTech Connect

The NH{sub 2}-MIL-53(Al) metal-organic framework was studied for its use in the separation of CO{sub 2} from CH{sub 4}, H{sub 2}, N{sub 2} C{sub 2}H{sub 6} and C{sub 3}H{sub 8} mixtures. Isotherms of methane, ethane, propane, hydrogen, nitrogen, and CO{sub 2} were measured. The atypical shape of these isotherms is attributed to the breathing properties of the material, in which a transition from a very narrow pore form to a narrow pore form and from a narrow pore form to a large pore form occurs, depending on the total pressure and the nature of the adsorbate, as demonstrated by in-situ XRD patterns measured during adsorption. Apart from CO{sub 2}, all tested gases interacted weakly with the adsorbent. As a result, they are excluded from adsorption in the narrow pore form of the material at low pressure. CO{sub 2} interacted much more strongly and was adsorbed in significant amounts at low pressure. This gives the material excellent properties to separate CO{sub 2} from other gases. The separation of CO{sub 2} from methane, nitrogen, hydrogen, or a combination of these gases has been demonstrated by breakthrough experiments using pellets of NH{sub 2}-MIL-53(Al). The effect of total pressure (1-30 bar), gas composition, temperature (303-403 K) and contact time has been examined. In all cases, CO{sub 2} was selectively adsorbed, whereas methane, nitrogen, and hydrogen nearly did not adsorb at all. Regeneration of the adsorbent by thermal treatment, inert purge gas stripping, and pressure swing has been demonstrated. The NH{sub 2}-MIL-53(Al) pellets retained their selectivity and capacity for more than two years.

Couck S.; Stavitski E.; Gobehiya, E.; Kirschhock, C.E.A.; Serra-Crespo, P.; Juan-Alcaniz, J.; Martinez Joaristi, A.; Gascon, J.; Kapteijn, F.; Baron, G. V.; Denayer J.F.M.

2012-02-29T23:59:59.000Z

72

Novel theoretical and experimental approaches for understanding and optimizing hydrogen-sorbent interactions in metal organic framework materials - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

3 3 FY 2012 Annual Progress Report DOE Hydrogen and Fuel Cells Program Yves. J. Chabal (Primary Contact), Jing Li, Timo Thonhauser UT Dallas - Department of Materials Science and Engineering 800 W. Campbell Road, RL 10 Richardson, TX 75080 Phone: (972) 883-5751 Email: chabal@utdallas.edu DOE Program Officer: Dr. Bonnie Gersten Phone: (301) 903-0002 Email: Bonnie.Gersten@science.doe.gov Subcontractors: * Jing Li (Rutgers University) * Timo Thonhauser (Wake Forest University) Objectives Develop a * comprehensive understanding of how small molecules (e.g. H 2 ) bind inside metal organic framework

73

Metal-Organic Heat Carrier Nanofluids. | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

Organic Heat Carrier Nanofluids. Metal-Organic Heat Carrier Nanofluids. Abstract: Nanofluids, dispersions of metal or oxide nanoparticles in a base working fluid, are being...

74

Sorptive extraction using polydimethylsiloxane/metal–organic framework coated stir bars coupled with high performance liquid chromatography-fluorescence detection for the determination of polycyclic aromatic hydrocarbons in environmental water samples  

Science Journals Connector (OSTI)

Abstract In this work, metal–organic frameworks (MOFs, Al-MIL-53-NH2) were synthesized via the hydrothermal method, and novel polydimethylsiloxane/metal–organic framework (PDMS/MOFs, PDMS/Al-MIL-53-NH2)-coated stir bars were prepared by the sol–gel technique. The preparation reproducibility of the PDMS/MOFs-coated stir bar was good, with relative standard deviations (RSDs) ranging from 4.8% to 14.9% (n = 7) within one batch and from 6.2% to 16.9% (n = 6) among different batches. Based on this fact, a new method of PDMS/MOFs-coated stir bar sorptive extraction (SBSE) and ultrasonic-assisted liquid desorption (UALD) coupled with high performance liquid chromatography-fluorescence detection (HPLC-FLD) was developed for the determination of polycyclic aromatic hydrocarbons (PAHs) in environmental water samples. To obtain the best extraction performance for PAHs, several parameters affecting SBSE, such as extraction time, stirring rate, and extraction temperature, were investigated. Under optimal experimental conditions, wide linear ranges and good \\{RSDs\\} (n = 7) were obtained. With enrichment factors (EFs) of 16.1- to 88.9-fold (theoretical EF, 142-fold), the limits of detection (LODs, S/N = 3) of the developed method for the target \\{PAHs\\} were found to be in the range of 0.05–2.94 ng/L. The developed method was successfully applied to the analysis of \\{PAHs\\} in Yangtze River and East Lake water samples.

Cong Hu; Man He; Beibei Chen; Cheng Zhong; Bin Hu

2014-01-01T23:59:59.000Z

75

Microporous Metal Organic Materials for Hydrogen Storage  

SciTech Connect

We have examined a number of Metal Organic Framework Materials for their potential in hydrogen storage applications. Results obtained in this study may, in general, be summarized as follows: (1) We have identified a new family of porous metal organic framework materials with the compositions M (bdc) (ted){sub 0.5}, {l_brace}M = Zn or Co, bdc = biphenyl dicarboxylate and ted = triethylene diamine{r_brace} that adsorb large quantities of hydrogen ({approx}4.6 wt%) at 77 K and a hydrogen pressure of 50 atm. The modeling performed on these materials agree reasonably well with the experimental results. (2) In some instances, such as in Y{sub 2}(sdba){sub 3}, even though the modeling predicted the possibility of hydrogen adsorption (although only small quantities, {approx}1.2 wt%, 77 K, 50 atm. hydrogen), our experiments indicate that the sample does not adsorb any hydrogen. This may be related to the fact that the pores are extremely small or may be attributed to the lack of proper activation process. (3) Some samples such as Zn (tbip) (tbip = 5-tert butyl isophthalate) exhibit hysteresis characteristics in hydrogen sorption between adsorption and desorption runs. Modeling studies on this sample show good agreement with the desorption behavior. It is necessary to conduct additional studies to fully understand this behavior. (4) Molecular simulations have demonstrated the need to enhance the solid-fluid potential of interaction in order to achieve much higher adsorption amounts at room temperature. We speculate that this may be accomplished through incorporation of light transition metals, such as titanium and scandium, into the metal organic framework materials.

S. G. Sankar; Jing Li; Karl Johnson

2008-11-30T23:59:59.000Z

76

Metal-doped organic foam  

DOE Patents (OSTI)

Organic foams having a low density and very small cell size and method for producing same in either a metal-loaded or unloaded (nonmetal loaded) form are described. Metal-doped foams are produced by soaking a polymer gel in an aqueous solution of desired metal salt, soaking the gel successively in a solvent series of decreasing polarity to remove water from the gel and replace it with a solvent of lower polarity with each successive solvent in the series being miscible with the solvents on each side and being saturated with the desired metal salt, and removing the last of the solvents from the gel to produce the desired metal-doped foam having desired density cell size, and metal loading. The unloaded or metal-doped foams can be utilized in a variety of applications requiring low density, small cell size foam. For example, rubidium-doped foam made in accordance with the invention has utility in special applications, such as in x-ray lasers.

Rinde, James A. (Livermore, CA)

1982-01-01T23:59:59.000Z

77

Heavy metals in Antarctic organisms  

SciTech Connect

To evaluate levels of essential (zinc and copper) and non-essential (mercury and cadmium) heavy metals, 34 species of organisms from different areas close to the Antarctic Peninsula were analysed. These included algae, filter-feeders, omnivorous invertebrates and vertebrates. Mercury was not detected, while cadmium was found in the majority of organisms analysed (detection limit was 0.05 ppm for both metals). The highest cadmium concentration was observed in the starfish Odontaster validus. Anthozoans, sipunculids and nudibranchs showed maximum levels of zinc, while the highest copper level was found in the gastropod Trophon brevispira. Mercury and cadmium levels in fishes were below the detection limit. Concentrations of essential and non-essential metals in birds were highest in liver followed by muscle and eggs. Cadmium and mercury levels in muscle of southern elephant seals were above the detection limit, whereas in Antarctic fur seals they were below it. The objective of the study was to gather baseline information for metals in Antarctic Ocean biota that may be needed to detect, measure and monitor future environmental changes. 46 refs., 7 figs., 8 tabs.

Moreno, J.E.A. de; Moreno, V.J. [Universidad Nacional de Mar del Plata (Argentina); Gerpe, M.S.; Vodopivez, C. [Instituto Antartico Argentino, Buenos Aires (Argentina)

1997-02-01T23:59:59.000Z

78

Pore with Gate: Enhancement of the Isosteric Heat of Adsorption of Dihydrogen via Postsynthetic Cation Exchange in Metal?Organic Frameworks  

Science Journals Connector (OSTI)

Three isostructural anionic frameworks {[(Hdma)(H3O)][In2(L1)2]·4DMF·5H2O}? (NOTT-206-solv), {[H2ppz][In2(L2)2]·3.5DMF·5H2O}? (NOTT-200-solv), and {[H2ppz][In2(L3)2]·4DMF·5.5H2O}? (NOTT-208-solv) (dma = dimethylamine; ppz = piperazine) each featuring ...

Sihai Yang; Gregory S. B. Martin; Jeremy J. Titman; Alexander J. Blake; David R. Allan; Neil R. Champness; Martin Schröder

2011-09-07T23:59:59.000Z

79

Magnetism in metal-organic capsules  

E-Print Network (OSTI)

Quantum Spin Chains in Magnetism: Molecules to Materials, J.Magnetism in metal-organic capsules Jerry L. Atwood,* a Euan

Atwood, Jerry L.

2010-01-01T23:59:59.000Z

80

Porous Materials -Metal-Organic Frameworks  

E-Print Network (OSTI)

expected to grow to 68% in 2025 · Hydrogen as energy carrier clean, efficient, and can be derived from domestic resources Renewable (biomass, hydro, wind, solar, and geothermal) Fossil fuels (coal ,natural gas is a critical enabling technology for the acceptance of hydrogen powered vehicles · Storing sufficient hydrogen

Tsymbal, Evgeny Y.

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Computational modeling of metal-organic frameworks  

E-Print Network (OSTI)

Orbital Ibu: Ibuprofen IPA: Isopropyl alcohol IUPAC:and isopropyl alcohol (IPA).63'64 Some of the most-NP) state. During adsorption of IPA, the adsorption of 3 IPA

Sung, Jeffrey Chuen-Fai; Sung, Jeffrey Chuen-Fai

2012-01-01T23:59:59.000Z

82

Postsynthetic modification of metal-organic frameworks  

E-Print Network (OSTI)

Cubic Ångstrøm AA Atomic Absorption acac Acetylacetonate AM157 Table 5- 4. Atomic Absorption (AA) analysis of UMCM-1-NHby TGA, PXRD, atomic absorption (AA) analysis, diffuse

Tanabe, Kristine Kimie

2011-01-01T23:59:59.000Z

83

Metal Organic Framework Adsorbent for Biogas Upgrading  

Science Journals Connector (OSTI)

In this context, this adsorbent can be used for biogas upgrading to produce biomethane and reduce fossil-fuel CO2. ...

Simone Cavenati; Carlos A. Grande; Alírio E. Rodrigues; Christoph Kiener; Ulrich Müller

2008-07-25T23:59:59.000Z

84

A fivefold inter­penetrating diamond­oid three-dimensional metal-organic framework constructed from benzene-1,4-di­acetic acid and flexible triazole derivatives: poly[[(2-benzene-1,4-di­acetato-2O:O){2-1,4-bis­[(1H-1,2,4-triazol-1-yl)methyl]benzene-2N4:N4'}zinc(II)] monohydrate  

Science Journals Connector (OSTI)

The title compound has a fivefold inter­penetrating diamondoid three-dimensional metal-organic framework, with each ZnII centre surrounded by two O-donor atoms from monodentate carboxyl­ate groups belonging to two different benzene-1,4-di­acetate ligands and by two triazole N-donor atoms from two different 1,4-bis­[(1H-1,2,4-triazol-1-yl)methyl]benzene ligands.

Shen, H.

2013-12-14T23:59:59.000Z

85

Energy Transfer on Demand: Photoswitch-Directed Behavior of Metal–Porphyrin Frameworks  

Science Journals Connector (OSTI)

Energy Transfer on Demand: Photoswitch-Directed Behavior of Metal–Porphyrin Frameworks ... were used to est. the ligand strain energies in the and all other topol. ...

Derek E. Williams; Joseph A. Rietman; Josef M. Maier; Rui Tan; Andrew B. Greytak; Mark D. Smith; Jeanette A. Krause; Natalia B. Shustova

2014-08-12T23:59:59.000Z

86

Doctoral Defense "Carbon Dioxide Capture on Elastic Layered Metal-Organic  

E-Print Network (OSTI)

Doctoral Defense "Carbon Dioxide Capture on Elastic Layered Metal-Organic Framework Adsorbents requires drastic modifications to the current energy infrastructure. Thus, carbon capture and sequestration for use as carbon capture adsorbents. Ideal adsorbed solution theory (IAST) estimates of CO2 selectivity

Kamat, Vineet R.

87

Metal-Organic Heat Carrier Nanofluids  

SciTech Connect

Nanofluids, dispersions of metal or oxide nanoparticles in a base working fluid, are being intensively studied due to improvements they offer in thermal properties of the working fluid. However, these benefits have been erratically demonstrated and proven impacts on thermal conductivity are modest and well described from long-established effective medium theory. In this paper, we describe a new class of metal-organic heat carrier (MOHC) nanofluid that offers potential for a larger performance boost in thermal vapor-liquid compression cycles. MOHCs are nanophase porous coordination solids designed to reversibly uptake the working fluid molecules in which the MOHCs are suspended. Additional heat can be extracted in a heat exchanger or solar collector from the endothermic enthalpy of desorption, which is then released as the nanofluid transits through a power generating device such as a turboexpander. Calculations for an R123 MOHC nanofluid indicated potential for up to 15% increase in power output. Capillary tube experiments show that liquid-vapor transitions occur without nanoparticle deposition on the tube walls provided entrance Reynolds number exceeds approximately 100.

McGrail, B. Peter; Thallapally, Praveen K.; Blanchard, Jeremy; Nune, Satish K.; Jenks, Jeromy WJ; Dang, Liem X.

2013-09-01T23:59:59.000Z

88

Development of New Biphasic Metal Organic Working Fluids for...  

Open Energy Info (EERE)

Biphasic Metal Organic Working Fluids for Subcritical Geothermal Systems Geothermal Lab Call Project Jump to: navigation, search Last modified on July 22, 2011. Project Title...

89

High Throughput Combinatorial Screening of Biometic Metal-Organic...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Throughput Combinatorial Screening of Biometic Metal-Organic Materials for Military Hydrogen-Storage Materials (New Joint Miami UNREL DoDDLA Project) (presentation) High...

90

Photochemical deterioration of the organic/metal contacts in organic optoelectronic devices  

SciTech Connect

We study the effect of exposure to light on a wide range of organic/metal contacts that are commonly used in organic optoelectronic devices and found that irradiation by light in the visible and UV range results in a gradual deterioration in their electrical properties. This photo-induced contact degradation reduces both charge injection (i.e., from the metal to the organic layer) and charge extraction (i.e., from the organic layer to the metal). X-ray photoelectron spectroscopy (XPS) measurements reveal detectable changes in the interface characteristics after irradiation, indicating that the photo-degradation is chemical in nature. Changes in XPS characteristics after irradiation suggests a possible reduction in bonds associated with organic-metal complexes. Measurements of interfacial adhesion strength using the four-point flexure technique reveal a decrease in organic/metal adhesion in irradiated samples, consistent with a decrease in metal-organic bond density. The results shed the light on a new material degradation mechanism that appears to have a wide presence in organic/metal interfaces in general, and which likely plays a key role in limiting the stability of various organic optoelectronic devices such as organic light emitting devices, organic solar cells, and organic photo-detectors.

Wang Qi; Williams, Graeme; Aziz, Hany [Department of Electrical and Computer Engineering, University of Waterloo, 200 University Avenue West, Waterloo, Ontario N2L 3G1 (Canada); Tsui Ting [Department of Chemical Engineering, University of Waterloo, 200 University Avenue West, Waterloo, Ontario N2L 3G1 (Canada)

2012-09-15T23:59:59.000Z

91

Design and synthesis of nucleobase-incorporated metal-organic...  

NLE Websites -- All DOE Office Websites (Extended Search)

Design and synthesis of nucleobase-incorporated metal-organic materials Previous Next List Muwei Zhang, Weigang Lu, Jian-Rong Li, Mathieu Bosch, Ying-Pin Chen, Tian-Fu Liu,...

92

Metal-Organic Frameworks with Precisely Designed Interior for...  

NLE Websites -- All DOE Office Websites (Extended Search)

with Precisely Designed Interior for Carbon Dioxide Capture in the Presence of Water Previous Next List Alejandro M. Fracaroli, Hiroyasu Furukawa, Mitsuharu Suzuki, Matthew Dodd,...

93

Screening Metal-Organic Frameworks by Analysis of Transient Breakthrou...  

NLE Websites -- All DOE Office Websites (Extended Search)

of break to highlight some important advantages of MOFs over conventionally used adsorbents such as zeolite NaX. For a given separation duty, such comparisons provide a more...

94

The Chemistry and Applications of Metal-Organic Frameworks  

Science Journals Connector (OSTI)

...j.jcat.2008.05.014 80 Sun C.-Y. Liu S. X. Liang D. D. Shao K. Z. Ren Y. H. Su Z. M. , Highly stable crystalline...Education, Science and Technology (Korea), WCU Program grant NRF R-31-2008-000-10055-0. The Chemistry and Applications...

Hiroyasu Furukawa; Kyle E. Cordova; Michael O’Keeffe; Omar M. Yaghi

2013-08-30T23:59:59.000Z

95

The Chemistry and Applications of Metal-Organic Frameworks  

Science Journals Connector (OSTI)

...6-dimethylphenol . J. Organomet. Chem. 692 , 2014 – 2020 ( 2007 ). 10.1016/j.jorganchem...014 80 Sun C.-Y. Liu S. X. Liang D. D. Shao K. Z. Ren Y. H. Su Z. M. , Highly...Technology (Korea), WCU Program grant NRF R-31-2008-000-10055-0. The Chemistry...

Hiroyasu Furukawa; Kyle E. Cordova; Michael O’Keeffe; Omar M. Yaghi

2013-08-30T23:59:59.000Z

96

Sandia National Laboratories: Sandia Metal-Organic Framework...  

NLE Websites -- All DOE Office Websites (Extended Search)

devices, reconfigurable electronics, and sensors. The work was supported by the DOE SunShot program and Sandia's Laboratory-Directed Research and Development (LDRD) project:...

97

New Design and Synthetic Strategies of Metal-Organic Frameworks  

E-Print Network (OSTI)

measured with Ar at 87K. ........................ 93 Figure 61. H2 gas sorption isotherm of PCN-94. ............................................................. 94 Figure 62. Coverage dependence of the isosteric heats of adsorption calculated from.... ................................................. 34 Figure 16. Coverage dependence of the isosteric heats of adsorption calculated from the isotherms for H2. ......................................................................................... 35 Figure 17. The CO2 isotherm of PCN-91at 273K...

Wei, Zhangwen

2014-04-18T23:59:59.000Z

98

Metal-organic frameworks—New materials for hydrogen storage  

Science Journals Connector (OSTI)

Published data on the physical sorption of hydrogen by new materials with a large specific ... (MOFs), are systematized and analyzed. The hydrogen-accumulating properties of MOFs are compared with ... and nanocar...

V. I. Isaeva; L. M. Kustov

2007-04-01T23:59:59.000Z

99

When Metal Organic Frameworks Turn into One-Dimensional Magnets...  

Office of Science (SC) Website

Energy Sciences Advisory Committee (BESAC) News & Resources Contact Information Basic Energy Sciences U.S. Department of Energy SC-22Germantown Building 1000 Independence...

100

Porous Metal–Organic Frameworks for Heterogeneous Biomimetic Catalysis  

Science Journals Connector (OSTI)

Homogeneous artificial metalloporphyrins can undergo catalytic deactivation via suicidal self-oxidation, which lowers their catalytic activity and sustainability relative to their counterparts in Nature. ... The 3D structure of [Zn2(HCOO)(FeIII(H2O)-TCPP)]·guest (7) is made up of layered network of FeIII-TCPP connected with binuclear Zn2(COO)4 paddle-wheel SBUs, and further linked by formate pillars to homogeneously coordinate with Zn2(COO)4 SBUs (Figure 4a). ... pillar linker DPNI to form a three-dimensional porous structure. ...

Min Zhao; Sha Ou; Chuan-De Wu

2014-02-06T23:59:59.000Z

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Knowledge Management and Clinical Framework for Cross Country Healthcare Organizations.  

E-Print Network (OSTI)

??Healthcare organizations are big source of knowledge creation. Acquiring knowledge, storing and transferring it to others in affective way has its own importance for healthcare… (more)

Saeed., Rizwan

2009-01-01T23:59:59.000Z

102

Development of New Biphasic Metal Organic Working Fluids for Subcritical  

Open Energy Info (EERE)

Biphasic Metal Organic Working Fluids for Subcritical Biphasic Metal Organic Working Fluids for Subcritical Geothermal Systems Geothermal Lab Call Project Jump to: navigation, search Last modified on July 22, 2011. Project Title Development of New Biphasic Metal Organic Working Fluids for Subcritical Geothermal Systems Project Type / Topic 1 Laboratory Call for Submission of Applications for Research, Development and Analysis of Geothermal Technologies Project Type / Topic 2 Working Fluids for Binary Power Plants Project Description In binary-cycle plants the cycle efficiency improves as pumping energy is reduced and from maximizing the enthalpy gain of the working fluid for a given amount of heat extracted from the geothermal source brine. Enthalpy gain of the working fluid in the heat exchanger occurs principally from sensible heat gained while passing through the heat exchanger in the liquid state and from vaporization of the organic working fluid near the exit of the heat exchanger. Additional heat transfer is limited after the vapor phase transition due the low thermal conductivity and heat capacity of the vapor. Also, operating pressures and temperatures are constrained by the bulk phase behavior and thermodynamic properties of the working fluid (boiling point, latent heat of vaporization, density, heat capacity, etc.). The fundamental underlying goal of this project is to overcome the cycle efficiency limitations imposed by the bulk thermodynamic proper-ties of the working fluid by introducing a metal-organic heat carrier (MOHC) into the system.

103

A Multi-layer Framework for Virtual Organizations Creation in Breeding Environment  

E-Print Network (OSTI)

Organizations, VO Breeding Environment, 1. INTRODUCTION In response to global competition, rapid changesA Multi-layer Framework for Virtual Organizations Creation in Breeding Environment Khouloud Boukadi-Ferrand, France 2 Industrial Engineering and Computer Sciences, ENSM, Saint-Etienne, France 3 LIRIS Laboratory

Paris-Sud XI, Université de

104

Method of making metal-doped organic foam products  

DOE Patents (OSTI)

Organic foams having a low density and very small cell size and method for roducing same in either a metal-loaded or unloaded (nonmetal loaded) form are described. Metal-doped foams are produced by soaking a polymer gel in an aqueous solution of desired metal salt, soaking the gel successively in a solvent series of decreasing polarity to remove water from the gel and replace it with a solvent of lower polarity with each successive solvent in the series being miscible with the solvents on each side and being saturated with the desired metal salt, and removing the last of the solvents from the gel to produce the desired metal-doped foam having desired density cell size, and metal loading. The unloaded or metal-doped foams can be utilized in a variety of applications requiring low density, small cell size foam. For example, rubidium-doped foam made in accordance with the invention has utility in special applications, such as in x-ray lasers.

Rinde, James A. (Livermore, CA)

1981-01-01T23:59:59.000Z

105

Use of metal organic fluors for spectral discrimination of neutrons and gammas.  

SciTech Connect

A new method for spectral shape discrimination (SSD) of fast neutrons and gamma rays has been investigated. Gammas interfere with neutron detection, making efficient discrimination necessary for practical applications. Pulse shape discrimination (PSD) in liquid organic scintillators is currently the most effective means of gamma rejection. The hazardous liquids, restrictions on volume, and the need for fast timing are drawbacks to traditional PSD scintillators. In this project we investigated harvesting excited triplet states to increase scintillation yield and provide distinct spectral signatures for gammas and neutrons. Our novel approach relies on metal-organic phosphors to convert a portion of the energy normally lost to the scintillation process into useful luminescence with sub-microsecond lifetimes. The approach enables independent control over delayed luminescence wavelength, intensity, and timing for the first time. We demonstrated that organic scintillators, including plastics, nanoporous framework materials, and oil-based liquids can be engineered for both PSD and SSD.

Allendorf, Mark D.; Doty, F. Patrick; Feng, Patrick L.

2010-09-01T23:59:59.000Z

106

Synthesis, Structure, and Metalation of Two New Highly Porous...  

NLE Websites -- All DOE Office Websites (Extended Search)

Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal-Organic Frameworks Previous Next List William Morris, Boris Volosskiy, Selcuk Demir, Felipe Gndara,...

107

A conceptual framework to understand retailers' logistics1 and transport organization illustrated for groceries' goods2  

E-Print Network (OSTI)

A conceptual framework to understand retailers' logistics1 and transport organization ­ illustrated38 * Corresponding author9 10 11 1 IFSTTAR,12 Production Systems, logistics, Transport Organisation as retailers, through in-house or51 outsourced logistics deliveries to points of sale, have a high share

Paris-Sud XI, Université de

108

Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy  

E-Print Network (OSTI)

, and carbon dioxide. Introduction Carbon dioxide emissions resulting from the burning of fossil fuels 20 metric tons of carbon dioxide per capita are released annually into the atmosphere.1a,b CarbonStorage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks

Yaghi, Omar M.

109

A Neo-Rumsfeldian Framework for the Thermodynamics of Organic Particulate  

NLE Websites -- All DOE Office Websites (Extended Search)

A Neo-Rumsfeldian Framework for the Thermodynamics of Organic Particulate A Neo-Rumsfeldian Framework for the Thermodynamics of Organic Particulate Matter Formation in the Atmosphere: Successes and Challenges Speaker(s): James F. Pankow Date: March 6, 2008 - 12:00pm Location: 90-3122 James F. Pankow. The thermodynamic principles according to which organic particulate matter (OPM) forms in the atmosphere have become well identified because of research progress made since about the mid 1990s. These are, ahem, known knowns. However, many unknowns exist regarding the concentrations and chemical characteristics of the biogenic and anthropogenic compounds present in the atmosphere that are important in OPM formation. In this context, since we know what we need to know more about, these are, well, known unknowns. Other known important unknowns are

110

Salt-Mediated Self-Assembly of Metal Nanoshells into Monolithic Aerogel Frameworks  

Science Journals Connector (OSTI)

Salt-Mediated Self-Assembly of Metal Nanoshells into Monolithic Aerogel Frameworks ... For the salt-mediated self-assembly, concentrated colloidal sols of Au/Ag, Pt/Ag, and Pd/Ag nanoshells were prepared by using either a rotatory evaporation (RE) or centrifuge filtration (CF) technique. ... Once the volume reached the desired value (typically 5–16 mL), the resulting sol was filtered using a 0.22 ?m poly(vinylidene difluoride) (PVDF) membrane filter and transferred to a glass vial for gel-formation studies. ...

Kulugammana G. S. Ranmohotti; Xiaonan Gao; Indika U. Arachchige

2013-08-06T23:59:59.000Z

111

Trace metal contamination of waters, sediments, and organisms of the Swan Lake area of Galveston Bay  

E-Print Network (OSTI)

facility (Gulf Coast Waste Disposal Authority) is located north of the Wah Chang Ditch. Consequently there have been concerns about possible metal contamination in this area. I determined trace metal concentrations in water, sediments, and organisms (oyster...

Park, Junesoo

1995-01-01T23:59:59.000Z

112

New metal-organic nanomaterials synthesized by laser irradiation of organic liquids  

SciTech Connect

A new type of metal-organic composition consisting of clusters of nanoparticles has been synthesised by laser irradiation of metallocene/benzene solutions. The metallocene molecules in this reaction become the source of the metal. Exposure to high-energy femtosecond laser pulses dehydrogenate benzene molecules and initiate the high-temperature high-pressure conditions that results in the synthesis of new materials. Irradiation experiments have been carried out on ferrocene/benzene and on other solutions. With ferrocene the synthesis of a new compound has been confirmed by X-ray powder diffraction as the peaks detected do not correspond to any known substance in the Crystallography Open Database. Theoretical simulation of the periodic structure of this new carbide predicts that it has hexagonal symmetry and a unit cell with a = 3.2A and c =2.8A. The exact structure is still uncertain but may be determined from scanning tunneling microscope (STM) studies.

Kuzmin, Stanislav L.; Wesolowski, Michal J.; Duley, Walter W. [Department of Physics and Astronomy, University of Waterloo, 200 University Avenue West, Waterloo, ON N2L 3G1 (Canada)

2014-03-31T23:59:59.000Z

113

Incorporation of nanovoids into metallic gratings for broadband plasmonic organic solar  

E-Print Network (OSTI)

Incorporation of nanovoids into metallic gratings for broadband plasmonic organic solar cells investigation and optimization of a newly proposed plasmonic organic solar cell geometry based. Kietzke, "Recent advances in organic solar cells," Adv. Optoelectron. 2007, 40285 (2007). 2. P. E. Shaw, A

Park, Namkyoo

114

High Throughput Combinatorial Screening of Biometic Metal-Organic...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

O O OH O HO OH O Co V 3+ Cr 3+ Mn 2+ Fe 2+ Co 2+ Ni 2+ Cu 2+ Ni Pd Pt SBU metal ions bare metal Carboxylate linkers Vibrational Spectroscopy of Hydrogen Raman *H 2 in gas...

115

Trace metal behaviour in riverine sediments: role of organic matter and sulphides Adeline Charriaua  

E-Print Network (OSTI)

1 Trace metal behaviour in riverine sediments: role of organic matter and sulphides Authors Adeline : 10.1016/j.apgeochem.2010.11.005 #12;2 Abstract Three sediment cores were collected in the Scheldt. The speciation and the distribution of trace metals in pore waters and sediment particles were assessed through

Paris-Sud XI, Université de

116

Electrochemical Nanoscale Templating: Laterally Self-Aligned Growth of Organic-Metal Nanostructures  

E-Print Network (OSTI)

, catalysts, solar cells, fuel cells, and molecular electronics.1,2 In addition to the synthesis of 1D, template-assisted strategies allow for both the synthesis and assembly of 1D nanostructures in one pot.3-organization of molecule-assisted metal nanoparticle colloids16 or metal nanopatterning through electrodeposition

Borguet, Eric

117

Transition metal oxides on organic semiconductors Yongbiao Zhao a  

E-Print Network (OSTI)

semiconductors (OSs) structure has been widely used in inverted organic optoelectronic devices, including toward in simplifying the fabrication process of the organic optoelectronic devices. Ã? 2014 Elsevier B], have gained great attention because of their wide applications in optoelectronic devices composed

Demir, Hilmi Volkan

118

A Multi-scale Framework for Thermo-viscoelastic Analysis of Fiber Metal Laminates  

E-Print Network (OSTI)

Fiber Metal Laminates (FML) are hybrid composites with alternate layers of orthotropic fiber reinforced polymers (FRP) and isotropic metal alloys. FML can exhibit a nonlinear thermo-viscoelastic behavior under the influence of external mechanical...

Sawant, Sourabh P.

2010-01-14T23:59:59.000Z

119

Metallic Nanoantennae and their Use in Organic-Polymer Photovoltaics  

Science Journals Connector (OSTI)

Organic photovoltaics, particularly bulk heterojunction devices, have shown...1, 2]. One of the main limitations of these designs is the low charge carrier mobility of the polymer blend. This leads to losses due ...

Eric Peterson; Patrick N. Sisco; Catherine J. Murphy…

2011-03-01T23:59:59.000Z

120

Surfactant biocatalyst for remediation of recalcitrant organics and heavy metals  

DOE Patents (OSTI)

Novel strains of isolated and purified bacteria have been identified which have the ability to degrade petroleum hydrocarbons including a variety of PAHs. Several isolates also exhibit the ability to produce a biosurfactant. The combination of the biosurfactant-producing ability along with the ability to degrade PAHs enhances the efficiency with which PAHs may be degraded. Additionally, the biosurfactant also provides an additional ability to bind heavy metal ions for removal from a soil or aquatic environment.

Brigmon, Robin L. (North Augusta, SC); Story, Sandra (Greenville, SC); Altman; Denis J. (Evans, GA); Berry, Christopher J. (Aiken, SC)

2011-03-29T23:59:59.000Z

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Surfactant biocatalyst for remediation of recalcitrant organics and heavy metals  

DOE Patents (OSTI)

Novel strains of isolated and purified bacteria have been identified which have the ability to degrade petroleum hydrocarbons including a variety of PAHs. Several isolates also exhibit the ability to produce a biosurfactant. The combination of the biosurfactant-producing ability along with the ability to degrade PAHs enhances the efficiency with which PAHs may be degraded. Additionally, the biosurfactant also provides an additional ability to bind heavy metal ions for removal from a soil or aquatic environment.

Brigmon, Robin L. (North Augusta, SC); Story, Sandra (Greenville, SC); Altman, Denis J. (Evans, GA); Berry, Christopher J. (Aiken, SC)

2011-03-15T23:59:59.000Z

122

Surfactant biocatalyst for remediation of recalcitrant organics and heavy metals  

DOE Patents (OSTI)

Novel strains of isolated and purified bacteria have been identified which have the ability to degrade petroleum hydrocarbons including a variety of PAHs. Several isolates also exhibit the ability to produce a biosurfactant. The combination of the biosurfactant-producing ability along with the ability to degrade PAHs enhances the efficiency with which PAHs may be degraded. Additionally, the biosurfactant also provides an additional ability to bind heavy metal ions for removal from a soil or aquatic environment.

Brigmon, Robin L. (North Augusta, SC); Story, Sandra (Greenville, SC); Altman, Denis (Evans, GA); Berry, Christopher J. (Aiken, SC)

2009-01-06T23:59:59.000Z

123

Surfactant biocatalyst for remediation of recalcitrant organics and heavy metals  

DOE Patents (OSTI)

Novel strains of isolated and purified bacteria have been identified which have the ability to degrade petroleum hydrocarbons including a variety of PAHs. Several isolates also exhibit the ability to produce a biosurfactant. The combination of the biosurfactant-producing ability along with the ability to degrade PAHs enhances the efficiency with which PAHs may be degraded. Additionally, the biosurfactant also provides an additional ability to bind heavy metal ions for removal from a soil or aquatic environment.

Brigmon, Robin L. (North Augusta, SC); Story, Sandra (Greenville, SC); Altman, Denis J. (Evans, GA); Berry, Christopher J. (Aiken, SC)

2011-05-03T23:59:59.000Z

124

Metal speciation in landfill leachates with a focus on the influence of organic matter  

SciTech Connect

Highlights: > This study characterises the heavy-metal content in leachates collected from eight landfills in France. > Most of the metals are concentrated in the <30 kDa fraction, while Pb, Cu and Cd are associated with larger particles. > Metal complexation with OM is not sufficient to explain apparent supersaturation of metals with sulphide minerals. - Abstract: This study characterises the heavy-metal content in leachates collected from eight landfills in France. In order to identify heavy metal occurrence in the different size fractions of leachates, a cascade filtration protocol was applied directly in the field, under a nitrogen gas atmosphere to avoid metal oxidation. The results of analyses performed on the leachates suggest that most of the metals are concentrated in the <30 kDa fraction, while lead, copper and cadmium show an association with larger particles. Initial speciation calculations, without considering metal association with organic matter, suggest that leachate concentrations in lead, copper, nickel and zinc are super-saturated with respect to sulphur phases. Speciation calculations that account for metal complexation with organic matter, considered as fulvic acids based on C1(s) NEXAFS spectroscopy, show that this mechanism is not sufficient to explain such deviation from equilibrium conditions. It is therefore hypothesized that the deviation results also from the influence of biological activity on the kinetics of mineral phase precipitation and dissolution, thus providing a dynamic system. The results of chemical analyses of sampled fluids are compared with speciation calculations and some implications for the assessment of metal mobility and natural attenuation in a context of landfill risk assessment are discussed.

Claret, Francis, E-mail: f.claret@brgm.fr [BRGM, 3 avenue C. Guillemin, BP 6009, 45060 Orleans (France); Tournassat, Christophe; Crouzet, Catherine; Gaucher, Eric C. [BRGM, 3 avenue C. Guillemin, BP 6009, 45060 Orleans (France); Schaefer, Thorsten [Karlsruhe Institute of Technology (KIT), Institute for Nuclear Waste Disposal (INE), P.O. Box 3640, 76021 Karlsruhe (Germany); Freie Universitaet Berlin, Institute of Geological Sciences, Department of Earth Sciences, Hydrogeology Group, D-12249 Berlin (Germany); Braibant, Gilles; Guyonnet, Dominique [BRGM, 3 avenue C. Guillemin, BP 6009, 45060 Orleans (France)

2011-09-15T23:59:59.000Z

125

Substrate and environmental controls on microbial assimilation of soil organic carbon: a framework for Earth System Models  

SciTech Connect

Microbial assimilation of soil organic carbon is one of the fundamental processes of global carbon cycling and it determines the magnitude of microbial biomass in soils. Mechanistic understanding of microbial assimilation of soil organic carbon and its controls is important for to improve Earth system models ability to simulate carbon-climate feedbacks. Although microbial assimilation of soil organic carbon is broadly considered to be an important parameter, it really comprises two separate physiological processes: one-time assimilation efficiency and time-dependent microbial maintenance energy. Representing of these two mechanisms is crucial to more accurately simulate carbon cycling in soils. In this study, a simple modeling framework was developed to evaluate the substrate and environmental controls on microbial assimilation of soil organic carbon using a new term: microbial annual active period (the length of microbes remaining active in one year). Substrate quality has a positive effect on microbial assimilation of soil organic carbon: higher substrate quality (lower C:N ratio) leads to higher ratio of microbial carbon to soil organic carbon and vice versa. Increases in microbial annual active period from zero stimulate microbial assimilation of soil organic carbon; however, when microbial annual active period is longer than an optimal threshold, increasing this period decreases microbial biomass. The simulated ratios of soil microbial biomass to soil organic carbon are reasonably consistent with a recently compiled global dataset at the biome-level. The modeling framework of microbial assimilation of soil organic carbon and its controls developed in this study offers an applicable ways to incorporate microbial contributions to the carbon cycling into Earth system models for simulating carbon-climate feedbacks and to explain global patterns of microbial biomass.

Xu, Xiaofeng [ORNL] [ORNL; Schimel, Joshua [University of California, Santa Barbara] [University of California, Santa Barbara; Thornton, Peter E [ORNL] [ORNL; Song, Xia [ORNL] [ORNL; Yuan, Fengming [ORNL] [ORNL; Goswami, Santonu [ORNL] [ORNL

2014-01-01T23:59:59.000Z

126

Towards a more quantitative understanding of the complex interactions between natural organic matter, heavy metals, and goethite.  

E-Print Network (OSTI)

??Dissolved natural organic matter (NOM) and heavy metals are ubiquitous in aqueous and terrestrial systems. Adsorption processes involving mineral surfaces largely control the fate, transport,… (more)

Arthurs, Leilani

2008-01-01T23:59:59.000Z

127

Metal Speciation in Landfill Leachates with a Focus on the Influence of Organic Matter  

SciTech Connect

This study characterizes the heavy-metal content in leachates collected from eight landfills in France. In order to identify heavy metal occurrence in the different size fractions of leachates, a cascade filtration protocol was applied directly in the field, under a nitrogen gas atmosphere to avoid metal oxidation. The results of analyses performed on the leachates suggest that most of the metals are concentrated in the <30 kDa fraction, while lead, copper and cadmium show an association with larger particles. Initial speciation calculations, without considering metal association with organic matter, suggest that leachate concentrations in lead, copper, nickel and zinc are super-saturated with respect to sulphur phases. Speciation calculations that account for metal complexation with organic matter, considered as fulvic acids based on C1(s) NEXAFS spectroscopy, show that this mechanism is not sufficient to explain such deviation from equilibrium conditions. It is therefore hypothesized that the deviation results also from the influence of biological activity on the kinetics of mineral phase precipitation and dissolution, thus providing a dynamic system. The results of chemical analyses of sampled fluids are compared with speciation calculations and some implications for the assessment of metal mobility and natural attenuation in a context of landfill risk assessment are discussed.

F Claret; C Tournassat; C Crouzet; E Gaucher; T Schäfer; G Braibant; D Guyonnet

2011-12-31T23:59:59.000Z

128

A Physically Based Framework for Modelling the Organic Fractionation of Sea Spray Aerosol from Bubble Film Langmuir Equilibria  

SciTech Connect

The presence of a large fraction of organic matter in primary sea spray aerosol (SSA) can strongly affect its cloud condensation nuclei activity and interactions with marine clouds. Global climate models require new parameterizations of the SSA composition in order to improve the representation of these processes. Existing proposals for such a parameterization use remotely-sensed chlorophyll-a concentrations as a proxy for the biogenic contribution to the aerosol. However, both observations and theoretical considerations suggest that existing relationships with chlorophyll-a, derived from observations at only a few locations, may not be representative for all ocean regions. We introduce a novel framework for parameterizing the fractionation of marine organic matter into SSA based on a competitive Langmuir adsorption equilibrium at bubble surfaces. Marine organic matter is partitioned into classes with differing molecular weights, surface excesses, and Langmuir adsorption parameters. The classes include a lipid-like mixture associated with labile dissolved organic carbon (DOC), a polysaccharide-like mixture associated primarily with semi-labile DOC, a protein-like mixture with concentrations intermediate between lipids and polysaccharides, a processed mixture associated with recalcitrant surface DOC, and a deep abyssal humic-like mixture. Box model calculations have been performed for several cases of organic adsorption to illustrate the underlying concepts. We then apply the framework to output from a global marine biogeochemistry model, by partitioning total dissolved organic carbon into several classes of macromolecule. Each class is represented by model compounds with physical and chemical properties based on existing laboratory data. This allows us to globally map the predicted organic mass fraction of the nascent submicron sea spray aerosol. Predicted relationships between chlorophyll-\\textit{a} and organic fraction are similar to existing empirical parameterizations, but can vary between biologically productive and non-productive regions, and seasonally within a given region. Major uncertainties include the bubble film thickness at bursting and the variability of organic surfactant activity in the ocean, which is poorly constrained. In addition, marine colloids and cooperative adsorption of polysaccharides may make important contributions to the aerosol, but are not included here. This organic fractionation framework is an initial step towards a closer linking of ocean biogeochemistry and aerosol chemical composition in Earth system models. Future work should focus on improving constraints on model parameters through new laboratory experiments or through empirical fitting to observed relationships in the real ocean and atmosphere, as well as on atmospheric implications of the variable composition of organic matter in sea spray.

Burrows, Susannah M.; Ogunro, O.; Frossard, Amanda; Russell, Lynn M.; Rasch, Philip J.; Elliott, S.

2014-12-19T23:59:59.000Z

129

Nano-structured Organic-Metal Interface for High Efficiency Organic Solar Cells  

Science Journals Connector (OSTI)

High bimolecular recombination has been identified as a performance limiting parameter in organic solar cells. To counter this issue, we introduce a structured-junction device...

Pandey, Ajay K; Aljada, Muhsen; Velusamy, M; Burn, Paul L; Meredith, Paul

130

High-Capacity Hydrogen Storage in Metal-Free Organic Molecular Crystals  

E-Print Network (OSTI)

High-Capacity Hydrogen Storage in Metal-Free Organic Molecular Crystals Mina Yoon1, 2 and Matthias donor and acceptor molecules as a promising new class of hydrogen storage materials. Using quantum(Tetrathiafulvalene)/TCNQ(7,7,8,8-tetracyanoquinodimethane) become very efficient hydrogen storage media of high gravimetric

131

Microporous Metal Organic Materials: Promising Candidates as Sorbents for Hydrogen Storage  

E-Print Network (OSTI)

Microporous Metal Organic Materials: Promising Candidates as Sorbents for Hydrogen Storage Long Pan coordination structures represent a promising new entry to the field of hydrogen storage materials.2 To fully that effectively store hydrogen are needed for use in fuel cell powered vehicles. Among the various candidate

Li, Jing

132

Surfactant Organic Molecules Restore Magnetism in Metal-Oxide Nanoparticle Surfaces  

E-Print Network (OSTI)

Surfactant Organic Molecules Restore Magnetism in Metal-Oxide Nanoparticle Surfaces Juan Salafranca, Nashville, Tennessee 37235, United States *S Supporting Information ABSTRACT: The properties of magnetic nanoparticles tend to be depressed by the unavoidable presence of a magnetically inactive surface layer. However

Pennycook, Steve

133

Seleno groups control the energy-level alignment between conjugated organic molecules and metals  

SciTech Connect

The charge injection from metallic electrodes into hole transporting layers of organic devices often suffers from deviations from vacuum-level alignment at the interface. Even for weakly interacting cases, Pauli repulsion causes an interface dipole between the metal and conjugated organic molecules (COMs) (so called “push-back” or “cushion” effect), which leads notoriously to an increase of the hole injection barrier. On the other hand, for chalcogenol self assembled monolayers (SAMs) on metal surfaces, chemisorption via the formation of chalcogen-metal bonds is commonly observed. In these cases, the energy-level alignment is governed by chalcogen-derived interface states in the vicinity of the metal Fermi-level. In this work, we present X-ray and ultraviolet photoelectron spectroscopy data that demonstrate that the interfacial energy-level alignment mechanism found for chalcogenol SAMs also applies to seleno-functionalized COMs. This can be exploited to mitigate the push-back effect at metal contacts, notably also when COMs with low ionization energies are employed, permitting exceedingly low hole injection barriers, as shown here for the interfaces of tetraseleno-tetracene with Au(111), Ag(111), and Cu(111)

Niederhausen, Jens; Heimel, Georg; Wilke, Andreas; Rabe, Jürgen P. [Institut für Physik, Humboldt-Universität zu Berlin, 12489 Berlin (Germany)] [Institut für Physik, Humboldt-Universität zu Berlin, 12489 Berlin (Germany); Duhm, Steffen [Graduate School of Advanced Integration Science, Chiba University, Chiba 263-8522 (Japan) [Graduate School of Advanced Integration Science, Chiba University, Chiba 263-8522 (Japan); Institute of Functional Nano and Soft Materials (FUNSOM), Soochow University, Suzhou 215123 (China); Bürker, Christoph; Schreiber, Frank [Institut für Angewandte Physik, Universität Tübingen, 72076 Tübingen (Germany)] [Institut für Angewandte Physik, Universität Tübingen, 72076 Tübingen (Germany); Xin, Qian [Graduate School of Advanced Integration Science, Chiba University, Chiba 263-8522 (Japan) [Graduate School of Advanced Integration Science, Chiba University, Chiba 263-8522 (Japan); School of Physics, Shandong University, 27 Shanda Nanlu, Jinan 250100 (China); Vollmer, Antje [Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, BESSY II, 12489 Berlin (Germany)] [Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, BESSY II, 12489 Berlin (Germany); Kera, Satoshi; Ueno, Nobuo [Graduate School of Advanced Integration Science, Chiba University, Chiba 263-8522 (Japan)] [Graduate School of Advanced Integration Science, Chiba University, Chiba 263-8522 (Japan); Koch, Norbert [Institut für Physik, Humboldt-Universität zu Berlin, 12489 Berlin (Germany) [Institut für Physik, Humboldt-Universität zu Berlin, 12489 Berlin (Germany); Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, BESSY II, 12489 Berlin (Germany)

2014-01-07T23:59:59.000Z

134

Oxygen as a surfactant for Al contact metallization of organic layers  

SciTech Connect

Valence band and spatially resolved x-ray photoemission studies of the Al growth on sexiphenyl films, in both an ultrahigh vacuum (UHV) and in a partial pressure of oxygen, are reported. We show that in an UHV, even for very high coverages, the Al balls up on the organic film and is discontinuous. In contrast, for growth in an oxygen partial pressure, similar to that in standard high-vacuum systems used in organic device production, very thin continuous conducting wetting layers are formed. We suggest that the oxygen acts like a surfactant that allows the high surface free-energy metal to wet low surface free-energy organic films.

Ivanco, J.; Winter, B.; Netzer, F.P.; Ramsey, M.G.; Gregoratti, L.; Kiskinova, M. [Institut fuer Experimentalphysik, Karl-Franzens-Universitaet, Universitaet Platz 5, A-8010 Graz (Austria); Sincrotrone Trieste, Societa Consoirtile p. Azioni, S.S. 14 km 163.5 in Area Science Park, I-34012 Trieste-Basovizza (Italy)

2004-07-26T23:59:59.000Z

135

Water extraction kinetics of metals, arsenic and dissolved organic carbon from industrial contaminated poplar leaves  

Science Journals Connector (OSTI)

Abstract In industrial areas, tree leaves contaminated by metals and metalloids could constitute a secondary source of pollutants. In the present study, water extraction kinetics of inorganic elements (IE: Pb, Zn, Cd, As, Fe and Mn), dissolved organic carbon, pH and biological activity were studied for industrial contaminated poplar leaves. Moreover, the distribution of the IE through the size fractions of the associated top soil was measured. High quantities of Mn, Zn and As and polysaccharides were released in the solution from the strongly contaminated leaves. The kinetic of release varied with time and metal type. The solution pH decreased while dissolved organic contents increased with time after 30 days. Therefore, these contaminated leaves could constitute a source of more available organic metals and metalloids than the initial inorganic process particles. However, the distribution of the IE through the size fractions of the top soil suggested that a great part of the released IE was adsorbed, reducing in consequence their transfers and bioavailability. It's concluded that mobility/bioavailability and speciation of metals and metalloids released from the decomposition of polluted tree leaves depends on soil characteristics, pollutant type and litter composition, with consequences for environmental risk assessment.

Muhammad Shahid; Tiantian Xiong; Maryse Castrec-Rouelle; Tibo Leveque; Camille Dumat

2013-01-01T23:59:59.000Z

136

Separation of Hexane Isomers in a Metal-Organic Framework with Triangular Channels  

Science Journals Connector (OSTI)

...solid upon reaction of Fe(acetylacetonate) 3 and 1,4-benzenedipyrazole...26). Here, octahedral iron(III) centers are linked...one ring bind to different iron atoms. The rigid, nearly planar...The chains of octahedral iron(III) centers form the vertices of these...

Zoey R. Herm; Brian M. Wiers; Jarad A. Mason; Jasper M. van Baten; Matthew R. Hudson; Pawel Zajdel; Craig M. Brown; Norberto Masciocchi; Rajamani Krishna; Jeffrey R. Long

2013-05-24T23:59:59.000Z

137

Metal-organic frameworks with high capacity and selectivity for harmful gases  

E-Print Network (OSTI)

, chlorine, tetrahydrothiophene, benzene, dichloromethane, ethyl- ene oxide, and carbon monoxide. Kinetic

Yaghi, Omar M.

138

Metal-organic frameworks with high capacity and selectivity for harmful gases  

Science Journals Connector (OSTI)

...sulfur dioxide, ammonia, chlorine, tetrahydrothiophene, benzene, dichloromethane, ethylene...dioxide, dichloromethane, and tetrahydrothiophene. We sample a wide range of size, acidity, vapor...001 0.036 0.092 0.190 1.76 Tetrahydrothiophene 0.001 0.007 0.090 <0.001...

David Britt; David Tranchemontagne; Omar M. Yaghi

2008-01-01T23:59:59.000Z

139

Hysteretic Adsorption and Desorption of Hydrogen by Nanoporous Metal-Organic Frameworks  

Science Journals Connector (OSTI)

...Notes 1 “Grand challenge for basic and applied research on hydrogen storage: statement of objectives,” available at www.eere.energy.gov/hydrogenandfuelcells/docs/gc_h2_storage.doc. 2 G. Gundiah , A. Govindaraj, N. Rajalakshmi, K...

Xuebo Zhao; Bo Xiao; Ashleigh J. Fletcher; K. Mark Thomas; Darren Bradshaw; Matthew J. Rosseinsky

2004-11-05T23:59:59.000Z

140

Functionalization of metal-organic frameworks with metalloligands and postsynthetic modification  

E-Print Network (OSTI)

calculated Langmuir surface area of ~3000 m 2 g -1 . 5 TheMoreover, surface areas greater than 3000 m 2 g -1 were

Garibay, Sergio J.

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Metal–organic frameworks of the MIL-101 family as heterogeneous single-site catalysts  

Science Journals Connector (OSTI)

...of hydrocarbons with green oxidants-O2 and tert-butyl...resistance to common solvents and thermal stability...dAcetone was used as solvent. Table 4. Cyclic carbonate...and Y. Ikushima 2008 Solvent-free allylic oxidation...as starting material. Green Chem 5, 497-507...

2012-01-01T23:59:59.000Z

142

Molecular Simulation of Carbon Dioxide Capture on Elastic Layered Metal-Organic Framework Adsorbents.  

E-Print Network (OSTI)

??The likelihood of fossil fuel power plants being targeted for future CO2 emissions regulation creates a motivation for developing an alternative CO2 capture method that… (more)

Tran, Trinh D.

2012-01-01T23:59:59.000Z

143

Enhancement of CO2/N2 selectivity in a metal-organic framework by cavity modification  

E-Print Network (OSTI)

electricity is a major source of CO2 in the atmosphere, but the capture and sequestration of CO2 from flue gas two-thirds), CO2, water vapor, oxygen, and minor components such as carbon monoxide, nitrogen oxides

144

High-Throughput Methodology for Discovery of Metal-Organic Frameworks with a High  

E-Print Network (OSTI)

of California, Berkeley Lily Ackerman and Thomas R. Boussie Symyx Technologies, Inc. #12;A Tetrazolate

145

Metal?Organic Frameworks As Templates for Nanoscale NaAlH4  

Science Journals Connector (OSTI)

Raghunandan K. Bhakta †, Julie L. Herberg ‡, Benjamin Jacobs †, Aaron Highley †, Richard Behrens , Jr.†, Nathan W. Ockwig §, Jeffery A. Greathouse § and Mark D. Allendorf *† ...

Raghunandan K. Bhakta; Julie L. Herberg; Benjamin Jacobs; Aaron Highley; Richard Behrens, Jr.; Nathan W. Ockwig; Jeffery A. Greathouse; Mark D. Allendorf

2009-09-01T23:59:59.000Z

146

Tunable Electrical Conductivity in Metal-Organic Framework Thin-Film Devices  

Science Journals Connector (OSTI)

...Laboratory Directed Research and Development Program at Sandia National Laboratories and the U.S. Department of Energy (DOE) SunShot Program. Sandia is a multiprogram laboratory operated by Sandia Corporation, a Lockheed Martin company, for the U.S...

A. Alec Talin; Andrea Centrone; Alexandra C. Ford; Michael E. Foster; Vitalie Stavila; Paul Haney; R. Adam Kinney; Veronika Szalai; Farid El Gabaly; Heayoung P. Yoon; François Léonard; Mark D. Allendorf

2014-01-03T23:59:59.000Z

147

Energy Transfer from Quantum Dots to Metal-Organic Frameworks for Enhanced Light Harvesting  

E-Print Network (OSTI)

and photosynthesis-like ensembles for solar energy conversion. A few important studies demonstrating the promise applications of MOFs in gas storage,5 sensing,6 chemical separation,7 drug delivery,8 and so on. In addition of MOFs for conversion of solar energy to electrical or chemical energy have been reported previously.9

148

Computational studies of the breathing motion of the metal -organic framework DMOF-1  

E-Print Network (OSTI)

Table 3.7A. Bonds for the IPA force field. Force Const.Table 3.7B. Angles for the IPA force field. Force Const.Table 3.7C. Dihedrals for the IPA force field. Force Const.

Grosch, Jason Scott

2011-01-01T23:59:59.000Z

149

Porous Metal-Organic Frameworks for Energy Storage Applications: Design, Synthesis and Mechanism Studies  

E-Print Network (OSTI)

) channel structure was synthesized. In-situ powder X-ray diffraction studies reveal its interesting phase transitions properties. After removing coordinated solvent at magnesium chains, this MOF can selectively adsorb CO_(2) over N_(2). Secondly...

Liu, Yangyang

2014-05-05T23:59:59.000Z

150

A General Thermolabile Protecting Group Strategy for Organocatalytic Metal?Organic Frameworks  

Science Journals Connector (OSTI)

Scheme 1 outlines how we envisaged the application of this methodology to the surreptitious incorporation into MOFs of proline groups designed to be specific sites for catalysis. ...

David J. Lun; Geoffrey I. N. Waterhouse; Shane G. Telfer

2011-03-28T23:59:59.000Z

151

Generation and Applications of Structure Envelopes for Metal-Organic Frameworks  

E-Print Network (OSTI)

and answers my results would not be what they are. I want thanks Gregory Halder, Karena Chapman and Matthew Suchomel from Argonne National Laboratory for for help with recording the in situ powder X-ray diffraction data on 1-BM, 11-BM and 17-BM beam lines...

Yakovenko, Andrey A.

2013-04-18T23:59:59.000Z

152

Tuning the Hydrophobicity of Zinc Dipyridyl Paddlewheel Metal-Organic Frameworks for Selective Sorption  

E-Print Network (OSTI)

Sorption Mitchell H. Weston, Amelia A. Delaquil, Amy A. Sarjeant, Omar K. Farha,* Joseph T. Hupp,* and Son). The most hydrophobic MOFs exhibited selective sorption of ethanol over water. INTRODUCTION Since on one of the two struts. The resulting materials were found to have selective sorption properties

153

Development of Metal-Organic Framework Thin Films and Membranes for Low-Energy Gas Separation  

E-Print Network (OSTI)

facile control over pore size and physical properties, making MOFs attractive materials for application in gas-separating membranes. A wealth of reports exist discussing the synthesis of MOF structures, however relatively few reports exist discussing MOF...

McCarthy, Michael

2011-08-08T23:59:59.000Z

154

Molecular simulation studies of metal organic frameworks focusing on hydrogen purification   

E-Print Network (OSTI)

The process of purifying hydrogen gas using pressure swing adsorption columns heavily relies on highly efficient adsorbents. Such materials must be able to selectively adsorb a large amount of impurities, and must also ...

Banu, Ana Maria

2014-06-30T23:59:59.000Z

155

The enterprise architecting framework applied to the supply organization of a sourcing management center of excellence  

E-Print Network (OSTI)

The basis to develop this thesis was performed after executing an internship in ABB Inc. The main objective of the study was to design the organization to operate the procurement function at a new manufacturing campus.The ...

Villegas Kavanagh, Leon Felipe

2008-01-01T23:59:59.000Z

156

Design and implementation of a continuous improvement framework for an organic photovoltaic panels manufacturer  

E-Print Network (OSTI)

The MIT MEng Team worked at Konarka Technologies, the world leader organic photovoltaic panels (OPV) manufacturer, on several improvement projects. The concentration was on operations improvement as well as production ...

Colaci, Gregorio

2011-01-01T23:59:59.000Z

157

Life cycle cost study for coated conductor manufacture by metal organic chemical vapor deposition  

SciTech Connect

The purpose of this report is to calculate the cost of producing high temperature superconducting wire by the Metal Organic Chemical Vapor Deposition (MOCVD) process. The technology status is reviewed from the literature and a plant conceptual design is assumed for the cost calculation. The critical issues discussed are the high cost of the metal organic precursors, the material utilization efficiency and the capability of the final product as measured by the critical current density achieved. Capital, operating and material costs are estimated and summed as the basis for calculating the cost per unit length of wire. Sensitivity analyses of key assumptions are examined to determine their effects on the final wire cost. Additionally, the cost of wire on the basis of cost per kiloampere per meter is calculated for operation at lower temperatures than the liquid nitrogen boiling temperature. It is concluded that this process should not be ruled out on the basis of high cost of precursors alone.

Chapman, J.N.

1999-07-13T23:59:59.000Z

158

Impact of Metal and Anion Substitutions on the Hydrogen Storage Properties of MBTT Metal-Organic Frameworks  

E-Print Network (OSTI)

applications is of paramount importance due to the increasing atmospheric levels of CO2 resulting from. For example, although the compression of hydrogen within insulated pressure tanks represents the simplest

159

Wireless Sensing Framework for Long-Term Measurements of Electric Organ Discharge  

E-Print Network (OSTI)

monitoring and visualization of the electric organ discharges (EOD) of a weakly electric fish (Sternopygus of multiple fish residing in separate tanks. Furthermore, the sensing mechanisms used to detect EOD are non-invasive, minimizing side effects on the fishs' natural behavior. Commercial-off-the- shelf (COTS) components are used

Misra, Satyajayant

160

Semitransparent metal or distributed Bragg reflector for wide-viewing-angle organic light-emitting-diode microcavities  

Science Journals Connector (OSTI)

Microcavities for organic light-emitting devices (OLED’s) with a metal mirror on one side and a distributed Bragg reflector (DBR) on the other side have been extensively studied in...

Neyts, Kristiaan; De Visschere, Patrick; Fork, David K; Anderson, Greg B

2000-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Stabilization of Rocky Flats combustible residues contaminated with plutonium metal and organic solvents  

SciTech Connect

This report describes tests on a proposed flowsheet designed to stabilize combustible residues that were generated at the Rocky Flats Environmental Technology Site (RFETS) during the machining of plutonium metal. Combustible residues are essentially laboratory trash contaminated with halogenated organic solvents and plutonium metal. The proposed flowsheet, designed by RFETS, follows a glovebox procedure that includes (1) the sorting and shredding of materials, (2) a low temperature thermal desorption of solvents from the combustible materials, (3) an oxidation of plutonium metal with steam, and (4) packaging of the stabilized residues. The role of Los Alamos National Laboratory (LANL) in this study was to determine parameters for the low temperature thermal desorption and steam oxidation steps. Thermal desorption of carbon tetrachloride (CCl{sub 4}) was examined using a heated air stream on a Rocky Flats combustible residue surrogate contaminated with CCl{sub 4}. Three types of plutonium metal were oxidized with steam in a LANL glovebox to determine the effectiveness of this procedure for residue stabilization. The results from these LANL experiments are used to recommend parameters for the proposed RFETS stabilization flowsheet.

Bowen, S.M.; Cisneros, M.R.; Jacobson, L.L.; Schroeder, N.C.; Ames, R.L.

1998-09-30T23:59:59.000Z

162

Effect of residual gases in high vacuum on the energy-level alignment at noble metal/organic interfaces  

SciTech Connect

The energy-level alignment at metal/organic interfaces has traditionally been studied using ultraviolet photoelectron spectroscopy (UPS) in ultra-high vacuum (UHV). However, since most devices are fabricated in high vacuum (HV), these studies do not accurately reflect the interfaces in real devices. We demonstrate, using UPS measurements of samples prepared in HV and UHV and current-voltage measurements of devices prepared in HV, that the small amounts of residual gases that are adsorbed on the surface of clean Cu, Ag, and Au (i.e., the noble metals) in HV can significantly alter the energy-level alignment at metal/organic interfaces.

Helander, M. G.; Wang, Z. B.; Lu, Z. H.

2011-10-31T23:59:59.000Z

163

Ambient air monitoring for organic compounds, acids, and metals at Los Alamos National Laboratory, January 1991  

SciTech Connect

Los Alamos National Laboratory (LANL) contracted Radian Corporation (Radian) to conduct a short-term, intensive air monitoring program whose goal was to estimate the impact of chemical emissions from LANL on the ambient air environment. A comprehensive emission inventory had identified more than 600 potential air contaminants in LANL's emissions. A subset of specific target chemicals was selected for monitoring: 20 organic vapors, 6 metals and 5 inorganic acid vapors. These were measured at 5 ground level sampling sites around LANL over seven consecutive days in January 1991. The sampling and analytical strategy used a combination of EPA and NIOSH methods modified for ambient air applications.

Williams, C.H. (Radian Corp., Austin, TX (United States)); Eberhart, C.F. (Los Alamos National Lab., NM (United States))

1992-01-01T23:59:59.000Z

164

Ambient air monitoring for organic compounds, acids, and metals at Los Alamos National Laboratory, January 1991  

SciTech Connect

Los Alamos National Laboratory (LANL) contracted Radian Corporation (Radian) to conduct a short-term, intensive air monitoring program whose goal was to estimate the impact of chemical emissions from LANL on the ambient air environment. A comprehensive emission inventory had identified more than 600 potential air contaminants in LANL`s emissions. A subset of specific target chemicals was selected for monitoring: 20 organic vapors, 6 metals and 5 inorganic acid vapors. These were measured at 5 ground level sampling sites around LANL over seven consecutive days in January 1991. The sampling and analytical strategy used a combination of EPA and NIOSH methods modified for ambient air applications.

Williams, C.H. [Radian Corp., Austin, TX (United States); Eberhart, C.F. [Los Alamos National Lab., NM (United States)

1992-10-01T23:59:59.000Z

165

Preparation of functionalized zeolitic frameworks  

DOE Patents (OSTI)

The disclosure provides zeolitic frameworks for gas separation, gas storage, catalysis and sensors. More particularly the disclosure provides zeolitic frameworks (ZIFs). The ZIF of the disclosure comprises any number of transition metals or a homogenous transition metal composition.

Yaghi, Omar M.; Hayashi, Hideki; Banerjee, Rahul; Park, Kyo Sung; Wang, Bo; Cote, Adrien P.

2014-08-19T23:59:59.000Z

166

Self-Assembly and Selective Guest Binding of Three-Dimensional Open-Framework Solids from a Macrocyclic Complex as a Trifunctional Metal  

E-Print Network (OSTI)

Self-Assembly and Selective Guest Binding of Three-Dimensional Open- Framework Solids from by the one-pot template condensation re- action of amine and formaldehyde. From the self-assembly of 1-organic coordination networks having specific network topologies and potentially interesting prop- erties.[1±12] Self-assembly

Paik Suh, Myunghyun

167

Assessing chironomid deformities in field- and laboratory-exposed organisms from organic- and metal-contaminated sediments  

SciTech Connect

Benthic invertebrate samples were collected from three Great Lakes harbors classified as Areas of concern (AOC) and from the Clark Fork River Superfund Site (CFR) in Montana. Contamination consists of organic and inorganic contaminants at the AOC sites and primarily heavy metal tailings and mining wastes in the CFR sites. Samples were collected with a ponar grab sampler from stations in Indiana Harbor, IN (1989, n = 7), the Buffalo River, NY (1989, n = 10), the Saginaw River, MI (1989, n = 7; 1990, n = 7), and the Clark Fork River (1991, n = 13). Compared to literature values for incidence of deformities in uncontaminated sediments, frequency of Chironomid mouthpart deformities was significantly greater at most stations sampled from the AOC sites. In contrast, only a few stations sampled from the CFR sites had significantly greater incidence of mouthpart deformities. Occurrence of mouthpart deformities ranged from 0 to 100% at the stations from the AOC`s and from 0 to 18% at the CFR stations. These mouthpart deformities in Chironomus riparius laboratory exposures to contaminated sediments from all AOC and CFR sites were evaluated and compared to frequencies found in field collected samples. Preliminary analysis indicates that frequency of mouthpart deformities from laboratory exposed chironomids are generally lower than those found in field collected samples.

Canfield, T.J.; Kemble, N.E.; Ingersoll, C.G. [National Biological Survey, Columbia, MO (United States)

1994-12-31T23:59:59.000Z

168

Transition Metal Catalyzed Reactions of Carbohydrates: a Nonoxidative Approach to Oxygenated Organics  

SciTech Connect

There is a critical need for new environmentally friendly processes in the United States chemical industry as legislative and economic pressures push the industry to zero-waste and cradle-to-grave responsibility for the products they produce. Carbohydrates represent a plentiful, renewable resource, which for some processes might economically replace fossil feedstocks. While the conversion of biomass to fuels, is still not generally economical, the selective synthesis of a commodity or fine chemical, however, could compete effectively if appropriate catalytic conversion systems can be found. Oxygenated organics, found in a variety of products such as nylon and polyester, are particularly attractive targets. We believe that with concerted research efforts, homogeneous transition metal catalyzed reactions could play a significant role in bringing about this future green chemistry technology.

Andrews, Mark

1997-01-08T23:59:59.000Z

169

Mechanistic Studies of Charge Injection from Metallic Electrodes into Organic Semiconductors Mediated by Ionic Functionalities: Final Report  

SciTech Connect

Metal-organic semiconductor interfaces are important because of their ubiquitous role in determining the performance of modern electronics such as organic light emitting diodes (OLEDs), fuel cells, batteries, field effect transistors (FETs), and organic solar cells. Interfaces between metal electrodes required for external wiring to the device and underlying organic structures directly affect the charge carrier injection/collection efficiency in organic-based electronic devices primarily due to the mismatch between energy levels in the metal and organic semiconductor. Environmentally stable and cost-effective electrode materials, such as aluminum and gold typically exhibit high potential barriers for charge carriers injection into organic devices leading to increased operational voltages in OLEDs and FETs and reduced charge extraction in photovoltaic devices. This leads to increased power consumption by the device, reduced overall efficiency, and decreased operational lifetime. These factors represent a significant obstacle for development of next generation of cheap and energy-efficient components based on organic semiconductors. It has been noticed that introduction of organic materials with conjugated backbone and ionic pendant groups known as conjugated poly- and oligoelectrolytes (CPEs and COEs), enables one to reduce the potential barriers at the metal-organic interface and achieve more efficient operation of a device, however exact mechanisms of the phenomenon have not been understood. The goal of this project was to delineate the function of organic semiconductors with ionic groups as electron injection layers. The research incorporated a multidisciplinary approach that encompassed the creation of new materials, novel processing techniques, examination of fundamental electronic properties and the incorporation of the resulting knowledgebase into development of novel organic electronic devices with increased efficiency, environmental stability, and reduced cost. During the execution of the project, main efforts were focused on the synthesis of new charge-bearing organic materials, such as CPEs and COEs, and block copolymers with neutral and ionic segments, studies of mechanisms responsible for the charge injection modulation in devices with ionic interlayers, and use of naturally occurring charged molecules for creation of enhanced devices. The studies allowed PIs to demonstrate the usefulness of the proposed approach for the improvement of operational parameters in model OLED and FET systems resulting in increased efficiency, decreased contact resistance, and possibility to use stable metals for fabrication of device electrodes. The successful proof-of-the-principle results potentially promise development of light-weight, low fabrication cost devices which can be used in consumer applications such as displays, solar cells, and printed electronic devices. Fundamental mechanisms responsible for the phenomena observed have been identified thus advancing the fundamental knowledgebase.

Nguyen, Thuc-Quyen [UCSB; Bazan, Guillermo [UCSB; Mikhailovsky, Alexander [UCSB

2014-04-15T23:59:59.000Z

170

DOI: 10.1002/chem.201002135 High Gas Sorption and Metal-Ion Exchange of Microporous MetalOrganic  

E-Print Network (OSTI)

DOI: 10.1002/chem.201002135 High Gas Sorption and Metal-Ion Exchange of Microporous Metal nanoparticles in the MOF.[1,2f,3] Gas sorption properties also depend on pore volume and ligand structures] but sorption properties for other gases have been less well explored.[6] In addition, the tetracarboxylate

Paik Suh, Myunghyun

171

Optical design of transparent metal grids for plasmonic absorption enhancement in ultrathin organic solar cells  

Science Journals Connector (OSTI)

Transparent metal grid combining with plasmonic absorption enhancement is a promising replacement to indium tin oxide thin films. We numerically demonstrate metal grids in one or two...

Kim, Inho; Lee, Taek Seong; Jeong, Doo Seok; Lee, Wook Seong; Kim, Won Mok; Lee, Kyeong-Seok

2013-01-01T23:59:59.000Z

172

Simple Way to Engineer Metal–Semiconductor Interface for Enhanced Performance of Perovskite Organic Lead Iodide Solar Cells  

Science Journals Connector (OSTI)

Simple Way to Engineer Metal–Semiconductor Interface for Enhanced Performance of Perovskite Organic Lead Iodide Solar Cells ... ‡ School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China ... However, ALD technique has the problems of strict working environment like vacuum and high cost precursors. ...

Yuzhuan Xu; Jiangjian Shi; Songtao Lv; Lifeng Zhu; Juan Dong; Huijue Wu; Yin Xiao; Yanhong Luo; Shirong Wang; Dongmei Li; Xianggao Li; Qingbo Meng

2014-04-01T23:59:59.000Z

173

Determining the exchange parameters of spin-1 metal-organic molecular magnets in pulsed magnetic fields  

SciTech Connect

We nave measured the high-field magnetization of a number of Ni-based metal-organic molecular magnets. These materials are self-assembly coordination polymers formed from transition metal ions and organic ligands. The chemistry of the compounds is versatile allowing many structures with different magnetic properties to be formed. These studies follow on from previous measurements of the Cu-based analogues in which we showed it was possible to extract the exchange parameters of low-dimensional magnets using pulsed magnetic fields. In our recent experiments we have investigated the compound (Ni(HF{sub 2})(pyz){sub 2})PF{sub 6}, where pyz = pyrazine, and the Ni-ions are linked in a quasi-two-dimensional (Q2D) square lattice via the pyrazine molecules, with the layers held together by HF{sub 2} ligands. We also investigated Ni(NCS){sub 2}(pyzdo){sub 2}, where pyzdo = pyrazine dioxide. The samples are grown at Eastern Washington University using techniques described elsewhere. Measurements are performed at the pulsed magnetic field laboratory in Los Alamos. The magnetization of powdered samples is determined using a compensated coil magnetometer in a 65 T short pulse magnet. Temperatures as low as 500 mK are achievable using a {sup 3}He cryostat. The main figure shows the magnetization of the spin-1 [Ni(HF{sub 2})(pyz){sub 2}]PF{sub 6} compound at 1.43 K. The magnetization rises slowly at first, achieving a rounded saturation whose midpoint is around 19 T. A small anomaly is also seen in the susceptibility at low fields ({approx}3 T), which might be attributed to a spin-flop transition. In contrast, the spin-1/2 [Cu(HF{sub 2})(pyz){sub 2}]PF{sub 6} measured previously has a saturation magnetization of 35.5 T and a strongly concave form of M(B) below this field. This latter compound was shown to be a good example of a Q2D Heisenberg antiferromagnet with the strong exchange coupling (J{sub 2D} = 12.4 K, J{sub {perpendicular}}/J{sub 2D} {approx} 10{sup -2}) directed along the Cu-pyz-Cu directions. The structure of the two compounds is similar, but in the case of the Cu-compound the Cu-Cu pathways are linear, whereas in the Ni-compound they are kinked. The pulsed-field data combined with information from temperature-dependent susceptibility, muon-spin rotation, electron-spin resonance and ligand-field calculations suggest that, far from being magnetically Q2D, the Ni-compound is fairly one-dimensional with the dominant exchange (J{sub 1D} = 3.1 K and J{sub {perpendicular}}/J{sub 1D} = 0.63) directed along the Ni-FHF-Ni direction. Ni(NCS){sub 2}(pyzdo){sub 2} was also investigated. Previous ultra-high field measurements using the 100 T magnet have shown that this compound has a saturation field close to 80 T. The purpose of the present studies is to map out the phase diagram of this material at mid-range fields. The data are shown in the inset to the figure. This continuing project probes the ability of organic ligands to mediate magnetic exchange, the link between structure, dimensionality and bulk magnetic properties, as well as the role of spin number in quantum magnets. Ultimately the investigations aim to determine to what extent it is possible to produce self-assembly molecular materials with tailor-made magnetic characteristics.

Mcdonald, Ross D [Los Alamos National Laboratory; Singleton, John [Los Alamos National Laboratory; Lancaster, Tom [OXFORD UNIV.; Goddard, Paul [OXFORD UNIV.; Manson, Jamie [EASTERN WASHINGTON UNIV.

2011-01-14T23:59:59.000Z

174

Absorption-Enhanced Organic Photovoltaic By Incorporating Metallic Nano Pyramid Particles  

E-Print Network (OSTI)

Device Physics of Organic Solar Cells," 2011/12/21/ 2011. S.photogeneration in organic solar cells," Chemical reviews,for High Performance Inverted Organic Solar Cells," Advanced

Qasem, Hussamaldeen S.

2014-01-01T23:59:59.000Z

175

Aluminum Nitride Micro-Channels Grown via Metal Organic Vapor Phase Epitaxy for MEMs Applications  

SciTech Connect

Aluminum nitride (AlN) is a promising material for a number of applications due to its temperature and chemical stability. Furthermore, AlN maintains its piezoelectric properties at higher temperatures than more commonly used materials, such as Lead Zirconate Titanate (PZT) [1, 2], making AlN attractive for high temperature micro and nanoelectromechanical (MEMs and NEMs) applications including, but not limited to, high temperature sensors and actuators, micro-channels for fuel cell applications, and micromechanical resonators. This work presents a novel AlN micro-channel fabrication technique using Metal Organic Vapor Phase Epitaxy (MOVPE). AlN easily nucleates on dielectric surfaces due to the large sticking coefficient and short diffusion length of the aluminum species resulting in a high quality polycrystalline growth on typical mask materials, such as silicon dioxide and silicon nitride [3,4]. The fabrication process introduced involves partially masking a substrate with a silicon dioxide striped pattern and then growing AlN via MOVPE simultaneously on the dielectric mask and exposed substrate. A buffered oxide etch is then used to remove the underlying silicon dioxide and leave a free standing AlN micro-channel. The width of the channel has been varied from 5 ìm to 110 ìm and the height of the air gap from 130 nm to 800 nm indicating the stability of the structure. Furthermore, this versatile process has been performed on (111) silicon, c-plane sapphire, and gallium nitride epilayers on sapphire substrates. Reflection High Energy Electron Diffraction (RHEED), Atomic Force Microscopy (AFM), and Raman measurements have been taken on channels grown on each substrate and indicate that the substrate is influencing the growth of the AlN micro-channels on the SiO2 sacrificial layer.

Rodak, L.E.; Kuchibhatla, S.; Famouri, P.; Ting, L.; Korakakis, D.

2008-01-01T23:59:59.000Z

176

Topological Analysis of Metal-Organic Frameworks with Polytopic Linkers and/or Multiple Building Units and the Minimal Transitivity  

E-Print Network (OSTI)

and Octahedral SBUs 1349 3. MOFs with Tetratopic Linkers 1349 3.1. Paddle Wheels and Other Square SBUs Joined by Planar Tetratopic Linkers 1349 3.2. Paddle-Wheel SBUs Joined by Tetrahedral Tetratopic Linkers 1352 3 of the nets of simpler solids, such as diamond or PtS.3-6 This was the so-called "ball and spoke" approach

Yaghi, Omar M.

177

Expanded Sodalite-Type Metal-Organic Frameworks: Increased Stability and H2 Adsorption through Ligand-Directed Catenation  

E-Print Network (OSTI)

The torsion between the central benzene ring and the outer aromatic rings in 1,3,5-tri-p-(tetrazol-5-yl)phenylbenzene (H3TPB- 3tz) and the absence of such strain in 2,4,6-tri-p-(tetrazol-5-yl)- phenyl-s-triazine (H3TPT

178

Strong CO2 Binding in a Water-Stable, Triazolate-Bridged Metal-Organic Framework Functionalized with Ethylenediamine  

E-Print Network (OSTI)

as analogues of known tetrazolate-bridged structures8 with enhanced chemical and thermal stability as a result

179

DOI: 10.1002/chem.200801336 Structure and Charge Control in MetalOrganic Frameworks Based on the  

E-Print Network (OSTI)

· tetrazoles [a] M. Dinca, Prof. J. R. Long Department of Chemistry University of California at Berkeley

180

Size-Selective Lewis Acid Catalysis in a Microporous Metal-Organic Framework with Exposed Mn2+  

E-Print Network (OSTI)

tetrazolate ligands, with a sixth methanol ligand that projects into the pore present only 83% of the time. Site II is bound by just two tetrazolate ligands and accounts for one-ninth of the total manganese

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Obtaining Chiral Metal–Organic Frameworks via a Prochirality Synthetic Strategy with Achiral Ligands Step-by-Step  

Science Journals Connector (OSTI)

Powder X-ray diffraction (PXRD) data were collected on an X‘Pert-ProMPD (Holand) D/max-?A X-ray diffractometer with Cu K? radiation in a flat plate geometry. ... A mixture of compound 1 (0.16 g, 0.5 mmol), Im (0.1 g, 1.5 mmol), and H2O (12 mL) was adjusted to approximately pH 7.5 with dilute en solution and HCl and stirred for 0.5 h and then transferred to and sealed in a 22 mL Teflon-lined stainless steel container, which was heated at 150 °C for 72 h and then cooled to room temperature naturally. ... It is precisely the central location of Cu atom in the unit; thus, if a reaction occurred between Cu and a new ligand with stronger coordination ability, the symmetry of CuN2O4 unit would be destroyed, and a chiral center might be formed. ...

Huan Dong; Hailiang Hu; Yang Liu; Jun Zhong; Guangju Zhang; Fangfang Zhao; Xuhui Sun; Youyong Li; Zhenhui Kang

2014-03-10T23:59:59.000Z

182

Synthesis and Characterization of Iso-Reticular Metal-Organic Frameworks and Their Applications for Gas Separations  

E-Print Network (OSTI)

. .......................................................................................... 77 4-2 Time-evolution of MOF-5 crystal layers on nanoporous anodized aluminum oxide substrates with and without conductive coatings. ...................... 80 4-3 Time-evolution of the XRD patterns of MOF-5 thin films grown on a graphite.... .................................................................................... 114 xiii FIGURE Page 5-12 Permeation of various gas molecules through: (a) ?-alumina support, (b) graphite-coated ?-alumina support, and (c) activated randomly-oriented MOF-5 membrane...

Yoo, Yeonshick

2011-10-21T23:59:59.000Z

183

Coordination-Chemistry Control of Proton Conductivity in the Iconic Metal-Organic Framework Material HKUST-1  

E-Print Network (OSTI)

. As shown below, we find that this approach can increase proton conductivity by close to 2 orders of magnitude. While any of several MOFs featuring open coordination sites3c,14 should be capable constructed from paddlewheel-coordinated (CuII )2 nodes and 1,3,5-benzenetricarboxylate (BTC) linkers15 (Chart

184

High-Throughput Screening of Mg-Functionalized Metal-Organic Frameworks for Hydrogen Storage near Room Temperature  

E-Print Network (OSTI)

The hydrogen storage capabilities of 18,383 porous crystalline structures possessing various degrees of Mg functionalization and diverse physical properties were assessed through combined grand canonical Monte Carlo (GCMC) and quantum mechanical...

Colón, Yamil J.; Fairen-Jimenez, David; Wilmer, Christopher E.; Snurr, Randall Q.

2014-01-01T23:59:59.000Z

185

A highly stable zirconium-based metal-organic framework material with high surface area and gas storage capacities  

E-Print Network (OSTI)

published for Zr-based MOFs. CH4/CO2/H2 adsorption isotherms were measured over a broad range of pressures and temperatures and are in excellent agreement with the computational predictions. The total hydrogen adsorption at 65 bar and 77 K is 0.092 g/g which...

Gutov, Oleksii V.; Bury, Wojciech; Gomez-Gualdron, Diego A.; Krungleviciute, Vaiva; Fairen-Jimenez, David; Sarjeant, Amy A.; Snurr, Randall Q.; Hupp, Joseph T.; Yildirim, Taner; Farha, Omar K.

2014-08-14T23:59:59.000Z

186

Hydrogen Storage in Metal-Organic Frameworks - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

7 7 FY 2012 Annual Progress Report DOE Hydrogen and Fuel Cells Program Jeffrey Long (Primary Contact), Martin Head-Gordon Lawrence Berkeley National Laboratory 1 Cyclotron Road Berkeley, CA 95720 Phone: (510) 642-0860 Email: jrlong@berkeley.edu DOE Managers HQ: Ned Stetson Phone: (202) 586-9995 Email: Ned.Stetson@ee.doe.gov GO: Jesse Adams Phone: (720) 356-1421 Email: Jesse.Adams@go.doe.gov Subcontractors: * National Institute of Standards and Technology, Gaithersburg, MD (Craig Brown) * General Motors Corporation, Warren, MI (Anne Dailly) Project Start Date: April 1, 2012 Project End Date: March 31, 2015 Fiscal Year (FY) 2012 Objectives

187

Design and implementation of a continuous improvement framework, focusing on material and information flow, for the manufacturing of organic photovoltaics  

E-Print Network (OSTI)

Konarka Technologies is an organic photo voltaic solar panel manufacturing startup and is currently in the process of ramping up their production volumes. The MIT team has worked on numerous improvement activities that ...

Gogineni, Susheel Teja

2011-01-01T23:59:59.000Z

188

Radionuclides, Trace Metals, and Organic Compounds in Shells of Native Freshwater Mussels Along the Hanford Reach of the Columbia River: 6000 Years Before Present to Current Times  

SciTech Connect

This report documents concentrations of radionuclides, trace metals, and semivolatile organic compounds measured in shell samples of the western pearl shell mussel collected along the Hanford Reach of the Columbia River.

B. L. Tiller; T. E. Marceau

2006-01-25T23:59:59.000Z

189

Using atmospheric fallout to date organic horizon layers and quantify metal dynamics during decomposition  

E-Print Network (OSTI)

- tribution of geochemical tracers from weapons fallout, air pollution, and a direct 207 Pb application at one by the recent suggestion that metals are mined from deeper horizons and brought into the O horizon via

Heimsath, Arjun M.

190

The Effects of Heavy Metals (other than Mercury) on Marine and Estuarine Organisms  

Science Journals Connector (OSTI)

...of heavy metals is described in terms of their absorption, storage, excretion and regulation when different concentrations are...Industrial Waste Lead toxicity Marine Biology Mollusca drug effects Seawater Sewage Water Pollution Zinc toxicity The Royal Society is collaborating...

1971-01-01T23:59:59.000Z

191

Effect of Metal Nanoparticles on Absorption Enhancement in Organic Solar Cells  

Science Journals Connector (OSTI)

In this study, for increasing absorption of the active layer in bulk heterojunction (BHJ) organic solar cells (OSCs), we used surface Plasmon effect. For showing the results, we...

Rostami, A; Andalibi, Sh

192

Incorporation of nanovoids into metallic gratings for broadband plasmonic organic solar cells  

Science Journals Connector (OSTI)

We present investigation and optimization of a newly proposed plasmonic organic solar cell geometry based on the incorporation of nanovoids into conventional rectangular backplane...

Lee, Sangjun; In, SungJun; Mason, Daniel R; Park, Namkyoo

2013-01-01T23:59:59.000Z

193

Metal-like self-organization of periodic nanostructures on silicon and silicon carbide under femtosecond laser pulses  

SciTech Connect

Periodic structures were generated on Si and SiC surfaces by irradiation with femtosecond laser pulses. Self-organized structures with spatial periodicity of approximately 600?nm appear on silicon and silicon carbide in the laser fluence range just above the ablation threshold and upon irradiation with a large number of pulses. As in the case of metals, the dependence of the spatial periodicity on laser fluence can be explained by the parametric decay of laser light into surface plasma waves. The results show that the proposed model might be universally applicable to any solid state material.

Gemini, Laura [Advanced Research Center for beam Science, Institute for Chemical Research, Kyoto University, 611-0011 Kyoto (Japan); Department of Physics, Graduate School of Science, Kyoto University, 606-85802 Kyoto (Japan); FNSPE, Czech Technical University in Prague, 11519 Prague (Czech Republic); HiLASE Project, Institute of Physics, ASCR, 18221 Prague (Czech Republic); Hashida, Masaki; Shimizu, Masahiro; Miyasaka, Yasuhiro; Inoue, Shunsuke; Tokita, Shigeki; Sakabe, Shuji [Advanced Research Center for beam Science, Institute for Chemical Research, Kyoto University, 611-0011 Kyoto (Japan); Department of Physics, Graduate School of Science, Kyoto University, 606-85802 Kyoto (Japan); Limpouch, Jiri [FNSPE, Czech Technical University in Prague, 11519 Prague (Czech Republic); Mocek, Tomas [HiLASE Project, Institute of Physics, ASCR, 18221 Prague (Czech Republic)

2013-11-21T23:59:59.000Z

194

Pressure dependence of phonons and excitons in InSe films prepared by metal-organic chemical vapor deposition  

Science Journals Connector (OSTI)

The pressure dependence of the Raman spectra of phase-pure InSe thin films prepared by the low-pressure metal-organic chemical vapor deposition technique has been studied using a diamond-anvil high-pressure cell. Enhancement in the intensities of the Raman modes has been observed as a result of pressure-induced “tuning” of the energy of the M1-type hyperbolic exciton in InSe at ?2.54 eV through discrete incident laser photon energies. The pressure coefficients of the phonon modes and of the hyperbolic exciton in InSe have been determined.

In-Hwan Choi and Peter Y. Yu

2003-10-27T23:59:59.000Z

195

The transformation of organic amines by transition metal cluster compounds. Progress report, 1993--1994  

SciTech Connect

In the recent year, the authors extended investigations into insertion reactions by investigating the insertion of dicarboxylate acetylene into the metal-metal bond of Re{sub 2}(CO){sub 9}(NCMe). Secondly, the authors considered the ring opening reactions of the cyclic thioethers: tetrahydrothiophene and thiacyclohexane when complexed to Os{sub 3}(CO){sub 10}(NCMe){sub 2}. In a third effort, various osmium complexes of cyclobutynes were synthesized and the subsequent reactivity probed. Finally, energy storage (via absorption of UV-visible photons) in osmium cluster compounds was investigated.

Adams, R.D.

1994-01-01T23:59:59.000Z

196

Metal speciation in landfill leachates with a focus on the influence of organic matter  

E-Print Network (OSTI)

fractions of leachates, a cascade filtration protocol was applied directly in the field, under a nitrogen gas atmosphere to avoid metal oxidation. The results of analyses performed on the leachates suggest mobility and natural attenuation in a context of landfill risk assessment are discussed. hal-00605888

Paris-Sud XI, Université de

197

Anal. Chem. 1986, 58, 2443-2447 2443 Characterization of Metal-Complex-Containing Organic  

E-Print Network (OSTI)

, Raleigh, North Carolina 27695 The SIMS technique has been successfully applled as an analytkal tool of metal complexes containing Ru, Re, or Zn by chemical bindlng, the SIMS technique was found investigation where secondary ion mass spectrometry (SIMS) is used as an analytical tool for characterization

198

Physiological responses of switchgrass (Panicum virgatum L.) to organic and inorganic amended heavy-metal contaminated chat tailings  

SciTech Connect

Study plots established at the Galena subsite of the Cherokee County Superfund Site in Southeastern Kansas by the US Bureau of Mines in 1990 were examined during the summer of 1996 to determine whether physiological criteria could be used to determine suitability of switchgrass for remediation of heavy-metal contaminated substrates. Switchgrass was chosen because it was the most frequently encountered species on these plots. Treatment plots included a treatment control, an organic residue treatment of 89.6 Mg Ha{sup {minus}1} composted cattle manure, and two inorganic fertilizer treatments recommended for either native grass or grass/legume mixtures. Plant response variables were photosynthetic rate, leaf conductance to water vapor, internal concentration of carbon dioxide in leaves, foliar transpiration rate, leaf water-use-efficiency, predawn leaf xylem water potential, and midday leaf xylem water potential. Predawn and midday xylem water potentials were higher for grass/legume inorganic treatment than for the other inorganic treatments. Leaf conductances were lower for organically treated plots than those plots not organically amended and both photosynthesis and transpiration were lower for organically treated plots. Leaf conductances and transpiration were higher for grass/legume treated plots than for plots lacking inorganic treatment. Water-use-efficiency was higher for native grass inorganically treated plots than for other inorganic treatments.

Youngman, A.L. [Wichita State Univ., KS (United States). Dept. of Biological Sciences

1997-12-31T23:59:59.000Z

199

The transformation of organic amines by transition metal cluster compounds: Progress report  

SciTech Connect

Research during the current award period has covered several related topics which have emerged and grown as a consequence of the various discoveries that have been made during this award period. They have been divided into the following subsections for clarity and emphasis: The activation of tertiary amines by osmium cluster complexes; CH bond activation and ring opening of a nitrogen containing strained ring heterocycle by an osmium cluster complex; Ring opening of cyclic thioethers; cyclooligomerization of Thietanes; Studies of the cyclobutyne ligand; Insertion of an alkynes into metal-metal bonds; and Energy storage in metal clusters. A summary of the results of these studies is given in the following sections of this report. These studies have resulted in 50 scientific publications over the last three years and details of their studies beyond that given in the following sections can be found in those reports. All of these reports are listed in the final section of this report by the author`s names, title and journal citation.

Adams, R.D.

1994-11-01T23:59:59.000Z

200

Case Study of Water-Soluble Metal Containing Organic Constituents of Biomass Burning Aerosol  

SciTech Connect

Natural and prescribed biomass fires are a major source of atmospheric aerosols that can persist in the atmosphere for long periods of time. Biomass burning aerosols (BBA) can be associated with long range transport of water soluble N?, S?, P?, and metal?containing species. In this study, BBA samples were collected using a particle?into?liquid sampler (PILS) from laboratory burns of vegetation collected on military bases in the southeastern and southwestern United States. The samples were then analyzed using high resolution electrospray ionization mass spectrometry (ESI/HR?MS) that enabled accurate mass measurements for hundreds of species with m/z values between 70 and 1000 and assignment of probable elemental formulae. Mg, Al, Ca, Cr, Mn, Fe, Ni, Cu, Zn, and Ba?containing organometallic species were identified. The results suggest that the biomass may have accumulated metal?containing species that were reemitted during biomass burning. Further research into the sources, persistence, and dispersion of metal?containing aerosols as well as their environmental effects is needed.

Chang-Graham, Alexandra L.; Profeta, Luisa Tm; Johnson, Timothy J.; Yokelson, Robert J.; Laskin, Alexander; Laskin, Julia

2011-01-10T23:59:59.000Z

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Metal inks  

DOE Patents (OSTI)

Self-reducing metal inks and systems and methods for producing and using the same are disclosed. In an exemplary embodiment, a method may comprise selecting metal-organic (MO) precursor, selecting a reducing agent, and dissolving the MO precursor and the reducing agent in an organic solvent to produce a metal ink that remains in a liquid phase at room temperature. Metal inks, including self-reducing and fire-through metal inks, are also disclosed, as are various applications of the metal inks.

Ginley, David S; Curtis, Calvin J; Miedaner, Alex; van Hest, Marinus Franciscus Antonius Maria; Kaydanova, Tatiana

2014-02-04T23:59:59.000Z

202

Cognitive decision errors and organization vulnerabilities in nuclear power plant safety management: Modeling using the TOGA meta-theory framework  

SciTech Connect

In the field of nuclear power plant (NPP) safety modeling, the perception of the role of socio-cognitive engineering (SCE) is continuously increasing. Today, the focus is especially on the identification of human and organization decisional errors caused by operators and managers under high-risk conditions, as evident by analyzing reports on nuclear incidents occurred in the past. At present, the engineering and social safety requirements need to enlarge their domain of interest in such a way to include all possible losses generating events that could be the consequences of an abnormal state of a NPP. Socio-cognitive modeling of Integrated Nuclear Safety Management (INSM) using the TOGA meta-theory has been discussed during the ICCAP 2011 Conference. In this paper, more detailed aspects of the cognitive decision-making and its possible human errors and organizational vulnerability are presented. The formal TOGA-based network model for cognitive decision-making enables to indicate and analyze nodes and arcs in which plant operators and managers errors may appear. The TOGA's multi-level IPK (Information, Preferences, Knowledge) model of abstract intelligent agents (AIAs) is applied. In the NPP context, super-safety approach is also discussed, by taking under consideration unexpected events and managing them from a systemic perspective. As the nature of human errors depends on the specific properties of the decision-maker and the decisional context of operation, a classification of decision-making using IPK is suggested. Several types of initial situations of decision-making useful for the diagnosis of NPP operators and managers errors are considered. The developed models can be used as a basis for applications to NPP educational or engineering simulators to be used for training the NPP executive staff. (authors)

Cappelli, M. [UTFISST, ENEA Casaccia, via Anguillarese 301, Rome (Italy); Gadomski, A. M. [ECONA, Centro Interuniversitario Elaborazione Cognitiva Sistemi Naturali e Artificiali, via dei Marsi 47, Rome (Italy); Sepiellis, M. [UTFISST, ENEA Casaccia, via Anguillarese 301, Rome (Italy); Wronikowska, M. W. [UTFISST, ENEA Casaccia, via Anguillarese 301, Rome (Italy); Poznan School of Social Sciences (Poland)

2012-07-01T23:59:59.000Z

203

The growth of CdTe/GaAs heteroepitaxial films by metal–organic chemical vapor deposition  

Science Journals Connector (OSTI)

A process for the growth of CdTe/GaAs heteroepitaxialfilms using metal–organic chemical vapor deposition(MOCVD) has been developed. The initial results of the determination of the deposition mechanism are reported. A pilot production demonstration using experimentally determined operating conditions has been completed. This is the first reported pilot production of CdTe/GaAs using 2 in. diam GaAs substrates in a multiple slice commercially manufactured MOCVD system. The results reported therein demonstrate that MOCVD is a reliable reproducible production worthy process for preparation of CdTe/GaAs heterostructures. These results are applicable to a wide variety of CdTe based device technologies including IR detection fiber optics solar cells and others.

Philip L. Anderson

1986-01-01T23:59:59.000Z

204

Organization  

NLE Websites -- All DOE Office Websites (Extended Search)

Organization Print Organization Print 2012-12 org chart A complete ALS organization chart (June 2013) is available in PDF. Appointed and elected members of advisory panels provide guidance to Berkeley Lab and ALS management in developing the ALS scientific and user programs. ALS Staff Photo staff photo thumb Click on the image to see a recent photo of ALS staff in front of the dome. The photo was taken on May 14, 2013. ALS Management and Advisory Team Steve Kevan, Deputy Division Director, Science Michael J. Banda, Deputy Division Director, Operations Robert W. Schoenlein, Senior Staff Scientist, Next Generation Light Source Initiative Janos Kirz, Scientific Advisor Paul Adams, Division Deputy for Biosciences ALS Scientific, Technical, and User Support Groups Accelerator Physics

205

Preparation of iron oxide thin film by metal organic deposition from Fe(III)-acetylacetonate: a study of photocatalytic properties  

Science Journals Connector (OSTI)

Iron oxide thin films have been deposited over fused quartz substrate by simple metal organic deposition from Fe-(III) acetylacetonate as the organic precursor. The decomposition of Fe-acetylacetonate is characterised by its distinct transition temperatures and thermogravimetric loss rates, which have been measured by thermal gravimetric analysis. As-deposited films were sintered in the temperature range 365–800°C and the structural changes of the iron oxide thin films as they transform into different crystalline phases have been studied by X-ray diffraction, Fourier transform infrared spectroscopy, ultraviolet-visible absorption spectroscopy and scanning electron microscopy techniques. Mainly amorphous ?-Fe2O3 is formed at an annealing temperature of approximately 365–400°C, which transforms to ?-Fe2O3 phase with a further increase (600–800°C) in sintering temperature. The film sintered at 800°C consists of mainly crystalline ?-Fe2O3 phase, which shows photocatalytic degradation of an oxygenated aqueous solution of phenol upon visible light illumination.

Bonamali Pal; Maheshwar Sharon

2000-01-01T23:59:59.000Z

206

Evaluating metalorganic frameworks for post-combustion carbon dioxide capture via temperature swing adsorption  

E-Print Network (OSTI)

Evaluating metal­organic frameworks for post-combustion carbon dioxide capture via temperature.1039/c1ee01720a Broader context The development of an effective carbon dioxide capture system is critical capture via temperature swing adsorption (TSA). Low-pressure single-component CO2 and N2 adsorption

207

Comprehensive study of carbon dioxide adsorption in the metalorganic frameworks M2(dobdc)  

E-Print Network (OSTI)

are historically slow, the need for mitigation of current CO2 emissions using carbon capture and sequestration (CCSComprehensive study of carbon dioxide adsorption in the metal­organic frameworks M2(dobdc) (M ¼ Mg of adsorption in the M2(dobdc)­CO2 adducts. Introduction Currently, 80% of global energy is supplied by carbon

208

Magnetic properties of a metal-organic network Fe,,N3...2,,4,4 -bpy... Tan Yuen and C. L. Lin  

E-Print Network (OSTI)

Magnetic properties of a metal-organic network Fe,,N3...2,,4,4 -bpy... Tan Yuen and C. L. Lin of Chemistry, Rutgers University, Camden, New Jersey 08102 The results of magnetic susceptibility, isothermal magnetization, and heat capacity measurements on a newly discovered iron complex with mixed ligands Fe(N3

Li, Jing

209

Thermal treatment induced change of diluted oxygen doped ZnTe films grown by metal-organic chemical vapor deposition  

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In this paper the authors report the growth of diluted oxygen doped ZnTe films (ZnTe:O) by metal-organic chemical vapor deposition (MOCVD). The effect of a post thermal annealing on the properties of the highly mismatched films has been investigated. It is found that the in-situ doping leads to an effective incorporation of oxygen into ZnTe films with different occupation configurations either on Zn or on Te site. The subsequent annealing process in a vacuum ambient leads to an enhancement of the oxygen incorporation into the ZnTe:O films due to the diffusion of the residual oxygen while the annealing with the same as-grown sample covered on top of the surface (denoted as “face-to-face” annealing in the text) is beneficial to the improvement of the film quality with manifest intermediate band emission at around 1.9?eV as revealed by the low-temperature photoluminescence. This study indicates that the mass-productive MOCVD technique may be suitable for the growth of highly mismatched ZnTe:O films for the application of the intermediate band solar cell.

2014-01-01T23:59:59.000Z

210

Comparative evaluation of several small mammal species as monitors of heavy metals, radionuclides, and selected organic compounds in the environment  

SciTech Connect

The primary purpose of this study was to evaluate which small mammal species are the best monitors of specific environmental contaminants. The evaluation is based on the published literature and on an analysis of small mammals trapped at several sites on the Oak Ridge National Laboratory (ORNL) Reservation in Oak Ridge, Tennessee. Studies on the uptake of heavy metals, radionuclides, and organic chemicals are reviewed in Chapter II to evaluate several small mammal species for their capacity to serve as sentinels for the presence, accumulation, and effects of various contaminants. Where several species were present at a site, a comparative evaluation was made and species are ranked for their capacity to serve as monitors of specific contaminants. Food chain accumulation and food habits of the species are used to establish a relationship with suitability as a biomonitor. Tissue-specific concentration factors were noted in order to establish target tissues. Life histories, habitat, and food habits are reviewed in order to make generalizations concerning the ability of similar taxa to serve as biomonitor. Finally, the usefulness of several small mammal species as monitors of three contaminants -- benzo(a)pyrene, mercury, and strontium-90 -- present on or near the ORNL facilities was investigated. 133 refs., 5 figs., 20 tabs.

Talmage, S.S. (Tennessee Univ., Knoxville, TN (USA) Oak Ridge National Lab., TN (USA)); Walton, B.T. (Oak Ridge National Lab., TN (USA))

1990-08-01T23:59:59.000Z

211

Film Boiling in Presence of a Magnetic Field in Liquid Metals Within Framework of Taylor–Helmholtz Instabilities in Application to Fusion Reactor Project  

Science Journals Connector (OSTI)

Whereas a lot of research has been done on boiling of various fluids [1] including liquid metals [2] not much work exists on Magnetohydrodynamic MHD boiling [3] and although some theoretical aspects of MHD boilin...

F. J. Arias

2010-04-01T23:59:59.000Z

212

A series of novel metal–organic coordination polymers constructed from the new 5-(4-imidazol-1-yl-phenyl)-2H-tetrazole spacer and aromatic carboxylates: Synthesis, crystal structures, and luminescence properties  

SciTech Connect

Using bifunctional organic ligand 5-(4-imidazol-1-yl-phenyl)-2H-tetrazole (HL) and different aromatic carboxylates as secondary ligands, four novel metal-organic coordination polymers, [Zn(L)(1,4-bdc){sub 0.5}] (1), [Zn{sub 1.5}(L)(2,5-pydc)] (2), [Zn(HL)(1,2,4,5-btec){sub 0.5}] (3), and [Cd(HL)(1,2,4,5-btec){sub 0.5}] (4) (1,4-bdc, 1,4-benzenedicarboxylate; 2,5-pydc, 2,5-pyridinedicarboxylate; 1,2,4,5-btec, 1,2,4,5-benzenetetracarboxylate) have been successfully synthesized and analyzed. Compound 1 features the 2D [Zn(L)]{sub n} layers built by ?{sub 3}-L bridging ligands and Zn(II) ions, which are further linked by pillared 1,4-bdc{sup 2?} ligands to form a 2-fold interpenetrating dmc framework. The 3D network of compound 2 can be simplified as a rare 2-nodal (3,6)-connected rtl (rutile) topology. Compound 3 possesses a 2D layer structure which is accomplished by connecting ladder-chains to L ligands. Compound 4 exhibits 2D [Cd(1,2,4,5-btec)] layers with infinite Cd–O–Cd rods and the adjacent 2D networks are further pillared by L with terminal bidentate coordination mode to generate the final 3D structure. The solid-state luminescent studies show that compounds 1–4 display intense fluorescent emissions. - Graphical abstract: Using bifunctional organic ligand 5-(4-imidazol-1-yl-phenyl)-2H-tetrazole (HL) and different aromatic carboxylates as secondary ligands, four novel metal-organic coordination polymers have been obtained. All compounds show good luminescence properties at room temperature. Display Omitted - Highlights: • Four Zn(II)/Cd(II)-MOCPs have been successfully prepared with the rigid bifunctional ligand 5-(4-imidazol -1-yl-phenyl) -2H-tetrazole and different aromatic carboxylates mixed ligands. • Compound 2 is a 2-nodal rtl (rutile) net and compound 4 is a binodal (5, 6)-connected net with yav topology. • Compounds 1-4 display intense fluorescent emissions at room temperature.

Sun, Jiayin [State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (China); Zhang, Daojun, E-mail: zhangdj0410@gmail.com [College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455002 (China); Wang, Li [State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (China); Zhang, Renchun; Wang, Junjie; Zeng, Ying; Zhan, Jinling [College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455002 (China); Xu, Jianing [State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (China); Fan, Yong, E-mail: mrfy@jlu.edu.cn [State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (China)

2013-10-15T23:59:59.000Z

213

MST: Organizations: Organic Materials  

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Adhesive Bonding Adhesive Bonding Composites Encapsulation Materials Characterization Mechanical Testing Molding, Thermoforming, & Compounding Organizations Organic Materials Composite-to-metal adhesive bond Experimental/analytical study of composit-to-metal adhesive bond. The Organic Materials department in the Advanced Manufacturing and Processing Laboratory provides innovative prototype fabrication, full service small lot production, materials technology, processing expertise, and a broad range of organic material characterization and mechanical testing techniques. We encapsulate, we join and bond, we foam, we analyze and image, we build composite structures. We strive to make you, our customers, successful! We partner with you to find the right combination of materials, processing, and fixturing that will result in the highest value

214

Direct measurement of anisotropy of interfacial free energy from grain boundary groove morphology in transparent organic metal analong systems  

SciTech Connect

Both academia and industry alike have paid close attention to the mechanisms of microstructural selection during the solidification process. The forces that give rise to and the principles which rule the natural selection of particular morphologies are important to understanding and controlling new microstructures. Interfacial properties play a very crucial role to the selection of such microstructure formation. In the solidification of a metallic alloy, the solid-liquid interface is highly mobile and responds to very minute changes in the local conditions. At this interface, the driving force must be large enough to drive solute diffusion, maintain local curvature, and overcome the kinetic barrier to move the interface. Therefore, the anisotropy of interfacial free energy with respect to crystallographic orientation is has a significant influence on the solidification of metallic systems. Although it is generally accepted that the solid-liquid interfacial free energy and its associated anisotropy are highly important to the overall selection of morphology, the confident measurement of these particular quantities remains a challenge, and reported values are scarce. Methods for measurement of the interfacial free energy include nucleation experiments and grain boundary groove experiments. The predominant method used to determine anisotropy of interfacial energy has been equilibrium shape measurement. There have been numerous investigations involving grain boundaries at a solid-liquid interface. These studies indicated the GBG could be used to describe various interfacial energy values, which affect solidification. Early studies allowed for an estimate of interfacial energy with respect to the GBG energy, and finally absolute interfacial energy in a constant thermal gradient. These studies however, did not account for the anisotropic nature of the material at the GBG. Since interfacial energy is normally dependent on orientation of the crystallographic plane of the solid with respect to the liquid, a better calculation of interfacial energy was needed. Herring described this orientation dependence, which related the interfacial undercooling to the principle interfacial curvatures. The present study pertains to the measurement of the anisotropy of interfacial energy by comparison of experimental and theoretical GBG geometries in pure succinonitrile (SCN) and pivalic acid (PVA). A quantity of SCN and PVA was distilled and zone refined using a process that is defined in the experimental procedure portion of this paper. Very thin (100 {micro}m) slide assemblies were created and filled with these organic materials. For each system, several grooves were photographed and their shapes were compared with theoretical predictions. The correlation between experiment and theory was quantified and plotted as a function of the anisotropy for each of the GBG's examined, and a maximum correlation corresponded to the anisotropy of interfacial energy which describes that particular rotation of the GBG. The results from several rotations were statistically analyzed to ensure confidence in the measurement of the anisotropy of interfacial energy and, finally, compared to reported values obtained with other techniques.

Rustwick, Bryce A.

2005-08-01T23:59:59.000Z

215

Enhancement of optical absorption in thin-film organic solar cells through the excitation of plasmonic modes in metallic gratings  

E-Print Network (OSTI)

Enhancement of optical absorption in thin-film organic solar cells through the excitation 2010 We theoretically investigate the enhancement of optical absorption in thin-film organic solar.1063/1.3377791 Thin-film organic solar cells OSCs are a promising candidate for low-cost energy conversion.1­6 However

Veronis, Georgios

216

Hydrogen storage in water-stable metalorganic frameworks incorporating 1,3-and 1,4-benzenedipyrazolate  

E-Print Network (OSTI)

stability. Accordingly, we are working to extend our previous metal­tetrazolate framework chemistry3

217

Clustering of metal atoms in organic media. 9. High-activity Ni/MgO catalysts prepared by metal vapor methods. Surface area and particle size effects  

SciTech Connect

A metal vapor method was employed to prepare highly dispersed Ni metal catalysts (solvated metal atom dispersed = SMAD catalyst) supported on MgO. Compared with conventional Ni/MgO compositions, the SMAD catalysts showed much greater activities for all reactions studied (hydrogenolysis of methylcyclopentane, MCP; hydrogenation/hydrogenolysis of toluene, TOL; methanation of carbon monoxide, CO; dehydration of isopropyl alcohol, IPA). These high activities for the SMAD catalysts are attributed to the high surface area of Ni on MgO and the high percentage of this Ni in a zero-valent state (reduction degree). Conventional methods for preparing Ni/MgO catalysts did not yield nearly such favorable surface areas or reduction degrees. Nickel particle size effects were observed during hydrogenolysis studies of MCP and hydrogenation studies of TOL. These phenomena are explained by assuming the size of an active Ni particle to be largest for hydrogenolysis of MCP > hydrogenation of TOL > methanation of CO approx. = dehydrogenation of IPA. 8 figures, 2 tables.

Matsuo, K.; Klabunde, K.J.

1982-02-01T23:59:59.000Z

218

The role of organic carbon, iron, and aluminium oxyhydroxides as trace metal carriers: Comparison between the Trinity River and the Trinity River Estuary (Galveston Bay, Texas)  

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Concentrations of many trace elements in aquatic systems can become enriched due to anthropogenic as well as natural processes. In order to investigate particle enrichment processes from the river through an estuary, the changes in solid phase speciation and particle–water partitioning of a number of trace metals (e.g., Fe, Pb, Cd, Cu, Ni, Zn, Co, V) were evaluated from the Trinity River through Galveston Bay to the Ocean. An established way to detect anthropogenic contamination is by normalization of contaminant concentrations to Fe, Al, and/or organic carbon (OC). Particulate metal (Mn, Co, Ni, Cu, Pb, V, Ni, Zn, Cd) to Fe, Al, and metal to OC ratios were determined in waters of the Trinity River and Galveston Bay, in order to test 1) if the system is contaminated, and 2) whether Fe, Al, or organic carbon act as a master variable for determining metal concentrations. All particulate trace metals from Trinity River were present in ratios to Fe or Al similar to those from drainage basin soils, which were similar to world world-average soil. As expected, concentrations of Fe, Al and OC in particles from both the Trinity River as well as Galveston Bay were strongly correlated, from which one might conclude that Fe can be used as a reference element that is representative for all three of them. However, ratios to Fe of particle-reactive elements, such as Pb, were found to be significantly and positively correlated to the Fe content of particles from Galveston Bay, while nutrient-type elements, such as Cu, Ni, and Cd, were negatively correlated to their Fe content. Interestingly, suspended particles from the Trinity River did not exhibit any such correlations at all and only varied within a very limited range. The reason for such distinctive correlative behavior that distinguishes riverine from estuarine particles is likely caused by internal cycling of these elements within Galveston Bay, and their relationship to OC. Relationships of trace metals to OC revealed that differences in sources and cycling of OC in the estuary significantly altered the soil imprinted particle make-up. Results from selective leaching experiments of suspended particles in Galveston Bay confirmed the selective enrichment and fractionation processes for the different metals.

Liang-Saw Wen; Kent W. Warnken; Peter H. Santschi

2008-01-01T23:59:59.000Z

219

GVis: a scalable visualization framework for genomic data  

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This paper describes a framework we have developed for the visual analysis of large-scale phylogeny hierarchies populated with the genomic data of various organisms. This framework allows the user to quickly browse the phylogeny hierarchy of organisms ...

Jin Hong; Dong Hyun Jeong; Chris D Shaw; William Ribarsky; Mark Borodovsky; Chang Song

2005-06-01T23:59:59.000Z

220

The optimization of interfaces in InAsSb/InGaAs strained-layer superlattices grown by metal-organic chemical vapor deposition  

SciTech Connect

We have prepared InAsSb/InGaAs strained-layer superlattice (SLS) semiconductors by metal-organic chemical vapor deposition (MOCVD) under a variety of conditions. Presence of an InGaAsSb interface layer is indicated by x-ray diffraction patterns. Optimized growth conditions involved the use of low pressure, short purge times, and no reactant flow during the purges. MOCVD was used to prepare an optically pumped, single heterostructure InAsSb/InGaAs SLS/InPSb laser which emitted at 3.9 {mu}m with a maximum operating temperature of approximately 100 K.

Biefeld, R.M.; Baucom, K.C.; Kurtz, S.R.

1993-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

DOI: 10.1002/chem.201200456 Control of Interpenetration and Gas-Sorption Properties of MetalOrganic  

E-Print Network (OSTI)

DOI: 10.1002/chem.201200456 Control of Interpenetration and Gas-Sorption Properties of Metal areas and excellent gas-sorption properties.[1­3] In MOF chemistry, con- trol of the interpenetration is of high importance because the degree of interpenetration significantly affects the gas- sorption

Paik Suh, Myunghyun

222

GTT Framework | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

GTT Framework GTT Framework GTT Framework GTT Framework Strategic Framework The GTT proposes a strategic framework that organizes these activities into three interrelated dimensions (informational, analytical, and physical), representative of the systems nature of the grid. Each of these dimensions have a corresponding strategic focus: The informational dimension aims to improve the visibility of grid conditions. The analytical dimension increases our understanding of the implications of the observed conditions. The physical dimension enhances the flexibility of the grid to respond to that understanding. The logic behind these focus areas is that a modernized grid should be able to "see" an event or condition, "know" what is happening or about to happen, and "do" something appropriate in response - quickly and

224

Mixed-Ligand MetalOrganic Frameworks with Large Pores: Gas Sorption Properties and Single-Crystal-to-Single-Crystal Transformation on Guest  

E-Print Network (OSTI)

storage has been the center of interest because of the needs for an alternative fuel in mobile. The highest H2 gas uptake data reported so far is 7.5 wt% at 77 K and 70 bar in MOF-177,[23] but the best room temperature storage data are far less than 1% (0.62 wt%).[24] The highest CO2 uptake data reported so far

Paik Suh, Myunghyun

225

A Direct White-Light-Emitting Metal?Organic Framework with Tunable Yellow-to-White Photoluminescence by Variation of Excitation Light  

Science Journals Connector (OSTI)

Allendorf, M. D., Bauer, C. A., Bhakta, R. K. and Houk, R. J. T. Chem. ... (a) Pigge, F. C., Burgard, M. D. and Rath, N. P. Cryst. ...

Ming-Sheng Wang; Sheng-Ping Guo; Yan Li; Li-Zhen Cai; Jian-Ping Zou; Gang Xu; Wei-Wei Zhou; Fa-Kun Zheng; Guo-Cong Guo

2009-09-02T23:59:59.000Z

226

Hydrothermal Synthesis and Characterization of a Metal–Organic Framework by Thermogravimetric Analysis, Powder X-ray Diffraction, and Infrared Spectroscopy: An Integrative Inorganic Chemistry Experiment  

Science Journals Connector (OSTI)

Upper-Division Undergraduate; Inorganic Chemistry; Laboratory Instruction; Gravimetric Analysis; Hydrogen Bonding; IR Spectroscopy; Materials Science; Thermal Analysis ...

Johanna L. Crane; Kelly E. Anderson; Samantha G. Conway

2014-10-10T23:59:59.000Z

227

Improving the Power Conversion Efficiency of Ultrathin Organic Solar Cells by Incorporating Plasmonic Effects of Spheroidal Metallic Nanoparticles  

E-Print Network (OSTI)

Improving the Power Conversion Efficiency of Ultrathin Organic Solar Cells by Incorporating be exploited to achieve efficient harvesting of solar energy. Notably, the incorporation of plasmonic effects can allow the light harvesting capability of a solar cell to be maintained even as the thickness

Park, Namkyoo

228

High Throughput Combinatorial Screening of Biometic Metal-Organic Materials for Military Hydrogen-Storage Materials (New Joint Miami U/NREL DoD/DLA Project) (presentation)  

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Miami University/NREL DoD/DLA Project Miami University/NREL DoD/DLA Project High throughput combinatorial screening of biomimetic metal-organic materials for military hydrogen-storage applications Philip Parilla - NREL Joe Zhou, Dan Zhao - Miami U, Ohio Jeff Blackburn, Kevin O'Neill, Lin Simpson, Mike Heben - NREL Outline * Miami/NREL Project - Synthesis (Miami) - High Throughput Characterization (NREL) - Other Characterization * Other High Throughput Activities (NREL) - Parallel Sieverts - Parallel Gravimetric * Final Comments Overview of Miami/NREL Project * Goals - Development of H 2 storage materials based on MOFs, targeting 15 kJ/mole binding energy and high density of H 2 sites - Development of optical-based detection of adsorbed H 2 allowing rapid screening of samples * Approach - Combinatorial MOFs synthesis involving 8

229

InGaAs heterostructure formation in catalyst-free GaAs nanopillars by selective-area metal-organic vapor phase epitaxy  

SciTech Connect

We investigate axial GaAs/InGaAs/GaAs heterostructures embedded in GaAs nanopillars via catalyst-free selective-area metal-organic chemical vapor deposition. Structural characterization by transmission electron microscopy with energy dispersive x-ray spectroscopy (EDS) indicates formation of axial In{sub x}Ga{sub 1-x}As (x{approx}0.20) inserts with thicknesses from 36 to 220 nm with {+-}10% variation and graded Ga:In transitions controlled by In segregation. Using the heterointerfaces as markers, the vertical growth rate is determined to increase linearly during growth. Photoluminescence from 77 to 290 K and EDS suggest the presence of strain in the shortest inserts. This capability to control the formation of axial nanopillar heterostructures is crucial for optimized device integration.

Shapiro, J. N.; Lin, A.; Wong, P. S.; Scofield, A. C.; Tu, C.; Senanayake, P. N.; Mariani, G.; Liang, B. L.; Huffaker, D. L. [Department of Electrical Engineering and California Nano-Systems Institute, University of California at Los Angeles, Los Angeles, California 90095 (United States)

2010-12-13T23:59:59.000Z

230

Optimization of InAsSb/InGaAs strained-layer superlattice growth by metal-organic chemical vapor deposition for use in infrared emitters  

SciTech Connect

We have prepared InAsSb/InGaAs strained-layer superlattices (SLSs) by metal-organic chemical vapor deposition using a variety of growth conditions. Presence of an InGaAsSb interface layer was indicated by x-ray diffraction. This interface effect was minimized by optimizing the purge times, reactant flows, and growth conditions. The optimized growth conditions involved the use of low pressure, short purge times between the growth of the layers, and no reactant flow during the purges. Electron diffraction indicates that CuPt-type compositional ordering occurs in InAs{sub 1{minus}x}Sb{sub x} alloys and SLSs which explains an observed bandgap reduction from previously accepted alloy values.

Biefeld, R.M.; Baucom, K.C.; Follstaedt, D.M.; Kurtz, S.R.

1994-08-01T23:59:59.000Z

231

Removal of organic compounds and trace metals from oil sands process-affected water using zero valent iron enhanced by petroleum coke  

Science Journals Connector (OSTI)

Abstract The oil production generates large volumes of oil sands process-affected water (OSPW), referring to the water that has been in contact with oil sands or released from tailings deposits. There are concerns about the environmental impacts of the release of OSPW because of its toxicity. Zero valent iron alone (ZVI) and in combination with petroleum coke (CZVI) were investigated as environmentally friendly treatment processes for the removal of naphthenic acids (NAs), acid-extractable fraction (AEF), fluorophore organic compounds, and trace metals from OSPW. While the application of 25 g/L ZVI to OSPW resulted in 58.4% removal of \\{NAs\\} in the presence of oxygen, the addition of 25 g petroleum coke (PC) as an electron conductor enhanced the \\{NAs\\} removal up to 90.9%. The increase in ZVI concentration enhanced the removals of NAs, AEF, and fluorophore compounds from OSPW. It was suggested that the electrons generated from the oxidation of ZVI were transferred to oxygen, resulting in the production of hydroxyl radicals and oxidation of NAs. When OSPW was de-oxygenated, the \\{NAs\\} removal decreased to 17.5% and 65.4% during treatment with ZVI and CZVI, respectively. The removal of metals in ZVI samples was similar to that obtained during CZVI treatment. Although an increase in ZVI concentration did not enhance the removal of metals, their concentrations effectively decreased at all ZVI loadings. The Microtox® bioassay with Vibrio fischeri showed a decrease in the toxicity of ZVI- and CZVI-treated OSPW. The results obtained in this study showed that the application of ZVI in combination with PC is a promising technology for OSPW treatment.

Parastoo Pourrezaei; Alla Alpatova; Kambiz Khosravi; Przemys?aw Drzewicz; Yuan Chen; Pamela Chelme-Ayala; Mohamed Gamal El-Din

2014-01-01T23:59:59.000Z

232

Climate Literacy Framework  

NLE Websites -- All DOE Office Websites (Extended Search)

Climate Literacy Framework Print E-mail Climate Literacy Framework Print E-mail A Guide for Individuals and Communities The Essential Principles of Climate Science presents important information for individuals and communities to understand Earth's climate, impacts of climate change, and approaches for adapting and mitigating change. Principles in the guide can serve as discussion starters or launching points for scientific inquiry. The guide can also serve educators who teach climate science as part of their science curricula. Development of the guide began at a workshop sponsored by the National Oceanic and Atmospheric Administration (NOAA) and the American Association for the Advancement of Science (AAAS). Multiple science agencies, non-governmental organizations, and numerous individuals also contributed through extensive review and comment periods. Discussion at the National Science Foundation (NSF) and NOAA-sponsored Atmospheric Sciences and Climate Literacy workshop contributed substantially to the refinement of the document.

233

Hydrogen atom trapping in a self-organized one-dimensional dimer  

SciTech Connect

Metal–organic frameworks (MOFs) have attracted widespread attention owing to their unusual structure and properties produced by their nanospaces. However, many MOFs possess the similar three-dimensional frameworks, limiting their structural variety and operating capacity for hydrogen storage under ambient conditions. Here we report the synthesis and structural characterization of a single-crystal one-dimensional dimer whose structure, operating capacity, and physical mechanism contrast with those of existing MOFs. The hydrogen storage capacity of 2.6 wt.% is comparable to the highest capacity achieved by existing MOFs at room temperature. This exceptional storage capacity is realized by self-organization during crystal growth using a weak base.

Takami, Tsuyoshi, E-mail: takami@phys.sci.osaka-u.ac.jp [Department of Physics, Graduate School of Science, Osaka University, 1-1 Machikaneyama-cho, Toyonaka, Osaka 560-0043 (Japan); Kawamura, Kazushi [Analytical Measurement Room, Graduate School of Science, Osaka University, 1-1 Machikaneyama-cho, Toyonaka, Osaka 560-0043 (Japan)

2014-09-01T23:59:59.000Z

234

Imparting functionality to a metalorganic framework material by controlled nanoparticle  

E-Print Network (OSTI)

Imparting functionality to a metal�organic framework material by controlled nanoparticle by encapsulating various functional species (for example, nanoparticles) within the frameworks. However, despite increasing numbers of reports of nanoparticle/MOF composites, simultaneously to control the size, composition

235

Enterprise Security Planning using Zachman Framework: Designer's Perspective  

E-Print Network (OSTI)

Enterprise Security Planning using Zachman Framework: Designer's Perspective Abstract planning point of view. Index Terms - Enterprise Architecture, Zachman Framework, Enterprise Security security planning. This paper has been organized as follows. Section 2, describes the enterprise

Ertaull, Levent

236

Tuning Reactivity and Electronic Properties through Ligand Reorganization within a Cerium Heterobimetallic Framework  

SciTech Connect

Cerium compounds have played vital roles in organic, inorganic, and materials chemistry due to their reversible redox chemistry between trivalent and tetravalent oxidation states. However, attempts to rationally access molecular cerium complexes in both oxidation states have been frustrated by unpredictable reactivity in cerium(III) oxidation chemistry. Such oxidation reactions are limited by steric saturation at the metal ion, which can result in high energy activation barriers for electron transfer. An alternative approach has been realized using a rare earth/alkali metal/1,1'-BINOLate (REMB) heterobimetallic framework, which uses redox-inactive metals within the secondary coordination sphere to control ligand reorganization. The rational syntheses of functionalized cerium(IV) products and a mechanistic examination of the role of ligand reorganization in cerium(III) oxidation are presented.

Robinson, Jerome R.; Gordon, Zachary; Booth, Corwin H.; Carroll, Patrick J.; Walsh, Patrick J.; Schelter, Eric J.

2014-06-24T23:59:59.000Z

237

Economic Impact Reporting Framework  

E-Print Network (OSTI)

Economic Impact Reporting Framework 2007/08 November 2008 #12;#12;Economic Impact Reporting Framework 2007/08 #12;STFC Economic Impact Reporting Framework 2007/08 Contents: Introduction..............................................................................................................................................2 1: Overall Economic Impacts

238

Economic Impact Reporting Framework  

E-Print Network (OSTI)

Economic Impact Reporting Framework 2008/09 #12;#12;Economic Impact Reporting Framework 2008/09 #12;STFC Economic Impact Reporting Framework 2008/09 Contents: Introduction..............................................................................................................................................2 1: Overall Economic Impacts

239

Reversible photodeposition and dissolution of metal ions  

DOE Patents (OSTI)

A cyclic photocatalytic process for treating waste water containing metal and organic contaminants. In one embodiment of the method, metal ions are photoreduced onto the photocatalyst and the metal concentrated by resolubilization in a smaller volume. In another embodiment of the method, contaminant organics are first oxidized, then metal ions removed by photoreductive deposition. The present invention allows the photocatalyst to be recycled until nearly complete removal of metal ions and organic contaminants is achieved.

Foster, Nancy S. (Boulder, CO); Koval, Carl A. (Golden, CO); Noble, Richard D. (Boulder, CO)

1994-01-01T23:59:59.000Z

240

A Formal Analysis Framework for PLEXIL Gilles Dowek, Cesar Mu~noz, and Corina S. Pasareanu  

E-Print Network (OSTI)

, and stuttering, for different variants of the language. The framework is organized as a stack of abstract

Muñoz, César A.

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Sustainability Framework 1 Queen's University  

E-Print Network (OSTI)

Sustainability Framework 1 Queen's University Sustainability Strategic Framework #12;Sustainability Framework 2 Contents Introduction .................................................................................................................................................. 2 Queen's Sustainability Mission

Abolmaesumi, Purang

242

NETL: IEP – Post-Combustion CO2 Emissions Control - Microporous Metal  

NLE Websites -- All DOE Office Websites (Extended Search)

IEP – Post-Combustion CO2 Emissions Control IEP – Post-Combustion CO2 Emissions Control Microporous Metal Organic Frameworks Project No.: FC26-07NT43092 Examples of several MOFs under investigation Examples of several MOFs under investigation UOP LLC is conducting research for separating carbon dioxide (CO2) using novel microporous metal organic frameworks (MOFs). In the first project, NT42121, UOP partnered with the University of Michigan and Northwestern University to evaluate MOFs in both pre-combustion and post-combustion applications. In the second project, NT43092, UOP is collaborating with Vanderbilt University and the University of Edinburgh, as well as the University of Michigan and Northwestern University, in a more focused effort on MOFs in post-combustion applications. MOFs are an extraordinary

243

Hydrogen Sorption Efficiency of Titanium-Functionalized Mg–BN Framework  

Science Journals Connector (OSTI)

Stavila, V.; Bhakta, R. K.; Alam, T. M.; Majzoub, E. H.; Allendorf, M. D.Reversible Hydrogen Storage by NaAlH4 Confined within a Titanium-Functionalized MOF-74 (Mg) ACS Nano 2012, 6, 9807– 9817 ... Whitehead, G. F. S.; Cross, B.; Carthy, L. V.; Milway, A.; Rath, H.; Fernandez, A.; Heath, S. L.; Muryn, C. A. R.; Pritchard, G.; Teat, S. J.; Timco, G. A.; Winpenny, R. E. P.Rings and Threads as Linkers in Metal-Organic Frameworks and Poly-Rotaxanes Chem. ...

Madhu Samolia; T. J. Dhilip Kumar

2014-04-30T23:59:59.000Z

244

Metal-Ion-Mediated Reactions  

NLE Websites -- All DOE Office Websites (Extended Search)

Metal-Ion-Mediated Reactions Metal-Ion-Mediated Reactions Metal-Ion-Mediated Reactions Print Monday, 19 December 2011 18:29 While mononuclear, polynuclear, and polymeric metal complexes are most often synthesized by the reaction of a metal precursor and a presynthesized organic ligand, it is also possible to generate the ligand in situ from an easily available organic compound. This approach allows the reactivity of the metal ion to activate a proligand, transforming it through an in situ reaction, sometimes providing coordination compounds with ligands not accessible by conventional organic synthesis. The intense interest in the reactivity of coordinated ligands is mainly due to the necessity of interpreting the mechanisms of homogeneous metal-catalyzed processes, in which a substrate is activated upon its coordination to one or more metal sites. A coordinated oxime group contains three active sites (C, N, O) for reactivity.

245

A Highly Symmetric Porous Framework with Multi-intersecting Open Channels  

Science Journals Connector (OSTI)

A Highly Symmetric Porous Framework with Multi-intersecting Open Channels ... 7 One particularly useful family of ligands that has been used to create high-symmetry frameworks contains multicarboxylate functional groups, such as 1,3,5-benzenetricarboxylic acid (H3btc). ... The examples we have known include the sodalite topology with the carbonate ion as a building block, [Cu6(CO3)12{C(NH2)3}8],4-7a a framework with mixed triangular and octahedral building blocks having the pyrite topology, [Zn4O(TCA)2]·(DMF)3(H2O)3(TCA=4,4‘,4‘?‘?tricarboxy triphenylamine),7b a pair of interwoven metal-organic frameworks, Cu3(BTB)2(H2O)3(DMF)9(H2O)2(H3BTB = 4,4‘,4‘?‘-benzene-1,3,5-triyl-tribenzoic acid),7d a framework having the NbO structure type Cu2[o-Br? C6H3(CO2)2]2(H2O)2·(DMF)8(H2O)2,7e and a chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n (TMA = btc). ...

Zheng-Zhong Lin; Fei-Long Jiang; Lian Chen; Cheng-Yang Yue; Da-Qiang Yuan; An-Jian Lan; Mao-Chun Hong

2007-07-28T23:59:59.000Z

246

From Helical Array to Porous Architecture:? Exploring the Use of Side Chains of Amino Acids to Engineer 1D Infinite Coordination Polymeric Chain into Porous Frameworks  

Science Journals Connector (OSTI)

From Helical Array to Porous Architecture:? Exploring the Use of Side Chains of Amino Acids to Engineer 1D Infinite Coordination Polymeric Chain into Porous Frameworks ... State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, 350002, China, and Department of Chemistry and Chemical Engineering, Minjiang University, Fuzhou, 350108, China ... 5 The coordination mode of organic ligands could transform the coordination environment of the metal center, which could direct the linker to connect discrete metal complexes into a specific extended structure. ...

Ben-Yong Lou; Fei-Long Jiang; Ben-Lai Wu; Da-Qiang Yuan; Mao-Chun Hong

2006-02-21T23:59:59.000Z

247

Studies on rejuvenation of spent residue hydroprocessing catalysts by leaching of foulant metals: influence of inorganic salt additives on the leaching efficiency of organic acids  

Science Journals Connector (OSTI)

A comparative study has been made on the efficiency of oxalic, malonic and acetic acids for selective removal of metal foulants (e.g. vanadium) from spent residue hydrotreating catalysts in the presence and ab...

M. Marafi; A. Stanislaus; C. J. Mumford

1993-01-01T23:59:59.000Z

248

Formation and fragmentation of gas-phase ion-molecule complexes of transition-metal ions with organic molecules containing two functional groups  

Science Journals Connector (OSTI)

A mass spectrometer fast atom bombardment source has been used to synthesize, in the gas phase, the ion-molecule complexes of transition-metal ions (Ni+, CO+, Fe+, and Mn+) with ?- or ?-unsaturated alkenenitriles...

Lin-Zhi Chen; Jack M. Miller

1992-05-01T23:59:59.000Z

249

A Stable Open Framework with Wide Open Spaces | Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

Pumping Through the Middle Crust Pumping Through the Middle Crust Looking for Ways to Improve Vaccines Against the Deadly Rotavirus A "Colossal" Magnetic Effect under Pressure Using High Pressure to Reveal Quantum Criticality in an Elemental Antiferromagnet Nano Changes Have Macro Importance for a Key Electronics Material Science Highlights Archives: 2013 | 2012 | 2011 | 2010 2009 | 2008 | 2007 | 2006 2005 | 2004 | 2003 | 2002 2001 | 2000 | 1998 | Subscribe to APS Science Highlights rss feed A Stable Open Framework with Wide Open Spaces AUGUST 11, 2009 Bookmark and Share In this depiction of the structure of PCN-61, a metal-organic framework, copper atoms (blue) sit in "paddlewheel" structures with oxygen (red) and carbon (black) atoms. The paddlewheels link together to form

250

Structural disorder and transformation in crystal growth: direct observation of ring-opening isomerization in a metal-organic solid solution  

Science Journals Connector (OSTI)

The co-crystallization of cyclic and polymeric isomers in the same crystal in varying ratios with the skeleton frameworks packed in a geometrically compatible and energetically similar fashion gives a chance to rationalize ring-opening isomerization in a crystal growth process.

Jiang, J.-J.

2014-08-20T23:59:59.000Z

251

Stabilization of Electrocatalytic Metal Nanoparticles at Metal...  

NLE Websites -- All DOE Office Websites (Extended Search)

Electrocatalytic Metal Nanoparticles at Metal-Metal Oxide-Graphene Triple Junction Points. Stabilization of Electrocatalytic Metal Nanoparticles at Metal-Metal Oxide-Graphene...

252

Photoactivated metal removal  

SciTech Connect

The authors propose the use of photochromic dyes as light activated switches to bind and release metal ions. This process, which can be driven by solar energy, can be used in environmental and industrial processes to remove metals from organic and aqueous solutions. Because the metals can be released from the ligands when irradiated with visible light, regeneration of the ligands and concentration of the metals may be easier than with conventional ion exchange resins. Thus, the process has the potential to be less expensive than currently used metal extraction techniques. In this paper, the authors report on their studies of the metal binding of spirogyran dyes and the hydrolytic stability of these dyes. They have prepared a number of spirogyrans and measured their binding constants for calcium and magnesium. They discuss the relationship of the structure of the dyes to their binding strengths. These studies are necessary towards determining the viability of this technique.

Nimlos, M.R.; Filley, J.; Ibrahim, M.A.; Watt, A.S.; Blake, D.M.

1999-07-01T23:59:59.000Z

253

Carbon Sequestration Rates in Organic Layers of Soils Under the Grey Poplar (Populus x canescens) Stands Impacted by Heavy Metal Pollution  

Science Journals Connector (OSTI)

To describe carbon sequestration processes in organic layers of forest soils ... limit-value method was used to estimate C sequestration rate in poplar litters. A two-year ... using the ignition method. Input of ...

Agnieszka Medy?ska-Juraszek; Leszek Kuchar

2013-01-01T23:59:59.000Z

254

Nuclear Safety Regulatory Framework  

Energy Savers (EERE)

Department of Energy Nuclear Safety Regulatory Framework DOE's Nuclear Safety Enabling Legislation Regulatory Enforcement & Oversight Regulatory Governance Atomic Energy Act 1946...

255

Transition Metal Ions in the Gas Phase  

Science Journals Connector (OSTI)

For several years we have been studying the chemistry of atomic transition metal ions with simple organic molecules. This research was ... examining the consequences of oxidation and reduction of transition metal...

Douglas P. Ridge

1982-01-01T23:59:59.000Z

256

Metal Aminoboranes  

NLE Websites -- All DOE Office Websites (Extended Search)

Metal Aminoboranes Metal Aminoboranes Metal Aminoboranes Metal aminoboranes of the formula M(NH.sub.2BH.sub.3).sub.n have been synthesized. June 25, 2013 Metal Aminoboranes Metal aminoboranes of the formula M(NH.sub.2BH.sub.3).sub.n have been synthesized. Available for thumbnail of Feynman Center (505) 665-9090 Email Metal Aminoboranes Metal aminoboranes of the formula M(NH.sub.2BH.sub.3).sub.n have been synthesized. Metal aminoboranes are hydrogen storage materials. Metal aminoboranes are also precursors for synthesizing other metal aminoboranes. Metal aminoboranes can be dehydrogenated to form hydrogen and a reaction product. The reaction product can react with hydrogen to form a hydrogen storage material. Metal aminoboranes can be included in a kit. U.S. Patent No.: 7,713,506 (DOE S-112,798)

257

A Conceptual Framework for Progressing Towards Sustainability in the  

Open Energy Info (EERE)

A Conceptual Framework for Progressing Towards Sustainability in the A Conceptual Framework for Progressing Towards Sustainability in the Agriculture and Food Sector Jump to: navigation, search Tool Summary LAUNCH TOOL Name: A Conceptual Framework for Progressing Towards Sustainability in the Agriculture and Food Sector Agency/Company /Organization: Food and Agriculture Organization of the United Nations Sector: Land Focus Area: Agriculture Topics: Policies/deployment programs, Pathways analysis Resource Type: Publications Website: www.fao.org/docrep/012/al322e/al322e00.pdf A Conceptual Framework for Progressing Towards Sustainability in the Agriculture and Food Sector Screenshot References: A Conceptual Framework for Progressing Towards Sustainability in the Agriculture and Food Sector[1] Logo: A Conceptual Framework for Progressing Towards Sustainability in the Agriculture and Food Sector

258

A framework for warranty management in industrial assets  

Science Journals Connector (OSTI)

The objective of this paper is to suggest a management framework for a better organization of warranty assistance, using engineering techniques already developed for similar processes and according to a process-based quality management system. Therefore, ... Keywords: After sales, Industrial assets, Reference framework, Warranty management

V. GonzáLez-Prida; A. Crespo MáRquez

2012-12-01T23:59:59.000Z

259

Hydroxyl-decorated graphene systems as candidates for organic metal-free ferroelectrics, multiferroics, and high-performance proton battery cathode materials  

Science Journals Connector (OSTI)

Using a first-principles method we show that graphene based materials, functionalized with hydroxyl groups, constitute a class of multifunctional, lightweight, and nontoxic organic materials with functional properties such as ferroelectricity, multiferroicity, and can be used as proton battery cathode materials. For example, the polarizations of semihydroxylized graphane and graphone, as well as fully hydroxylized graphane, are much higher than any organic ferroelectric materials known to date. Further, hydroxylized graphene nanoribbons with proton vacancies at the end can have much larger dipole moments. They may also be applied as high-capacity cathode materials with a specific capacity that is six times larger than lead-acid batteries and five times that of lithium-ion batteries.

Menghao Wu; J. D. Burton; Evgeny Y. Tsymbal; Xiao Cheng Zeng; Puru Jena

2013-02-19T23:59:59.000Z

260

Global Framework for Climate Risk Exposure | Open Energy Information  

Open Energy Info (EERE)

Framework for Climate Risk Exposure Framework for Climate Risk Exposure Jump to: navigation, search Tool Summary Name: Global Framework for Climate Risk Exposure Agency/Company /Organization: United Nations Environment Programme Topics: Finance, Co-benefits assessment, Market analysis Resource Type: Publications, Guide/manual Website: www.unepfi.org/fileadmin/documents/global_framework.pdf Global Framework for Climate Risk Exposure Screenshot References: Global Framework for Climate Risk Exposure[1] Summary "A group of leading institutional investors from around the world released the Global Framework for Climate Risk Disclosure-a new statement on disclosure that investors expect from companies-in October 2006. Investors require this information in order to analyze a company's business risks and opportunities resulting from climate change, as well as

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

An Investment Framework for Clean Energy and Development | Open Energy  

Open Energy Info (EERE)

An Investment Framework for Clean Energy and Development An Investment Framework for Clean Energy and Development Jump to: navigation, search Tool Summary LAUNCH TOOL Name: An Investment Framework for Clean Energy and Development Agency/Company /Organization: World Bank, International Monetary Fund Sector: Energy Focus Area: Energy Efficiency, Renewable Energy, Solar Topics: Finance, Pathways analysis Resource Type: Guide/manual Website: siteresources.worldbank.org/DEVCOMMINT/Documentation/21046509/DC2006-0 An Investment Framework for Clean Energy and Development Screenshot References: An Investment Framework for Clean Energy and Development[1] Overview "This paper reports on progress in developing an Investment Framework for Clean Energy and Development. The Investment Framework is intended to be a vehicle to accelerate investments to address developing country energy

262

Cybersecurity Framework Development Overview  

E-Print Network (OSTI)

Cybersecurity Framework Development Overview NIST's Role in Implementing Executive Order 13636 "Improving Critical Infrastructure Cybersecurity" #12;Executive Order 13636: Improving Critical Infrastructure Cybersecurity - February 12, 2013 "The cyber threat to critical infrastructure continues to grow

Bentz, Dale P.

263

Cybersecurity Framework Development Overview  

E-Print Network (OSTI)

Cybersecurity Framework Development Overview NIST's Role in Implementing Executive Order 13636 "Improving Critical Infrastructure Cybersecurity" #12;Executive Order 13636: Improving Critical Infrastructure Cybersecurity February 12, 2013 · "The cyber threat to critical infrastructure continues to grow

264

The Partnership Evaluation Framework  

Energy.gov (U.S. Department of Energy (DOE))

U.S. Department of Energy Better Buildings Neighborhood Program: The Partnership Evaluation Framework: How to evaluate a potential partner’s business model and identify areas for collaboration.

265

Theories of phosphorescence in organo-transition metal complexes - from relativistic effects to simple models and design principles for organic light-emitting diodes  

E-Print Network (OSTI)

We review theories of phosphorescence in cyclometalated complexes. We focus primarily on pseudooctahedrally coordinated $t_{2g}^6$ metals (e.g., [Os(II)(bpy)$_3$]$^{2+}$, Ir(III)(ppy)$_3$ and Ir(III)(ptz)$_3$) as, for reasons that are explored in detail, these show particularly strong phosphorescence. We discuss both first principles approaches and semi-empirical models, e.g., ligand field theory. We show that together these provide a clear understanding of the photophysics and in particular the lowest energy triplet excitation, T$_1$. In order to build a good model relativistic effects need to be included. The role of spin-orbit coupling is well-known, but scalar relativistic effects are also large - and are therefore also introduced and discussed. No expertise in special relativity or relativistic quantum mechanics is assumed and a pedagogical introduction to these subjects is given. It is shown that, once both scalar relativistic effects and spin-orbit coupling are included, time dependent density function...

Powell, B J

2015-01-01T23:59:59.000Z

266

Demand Response Valuation Frameworks Paper  

E-Print Network (OSTI)

Framework, Dr. Daniel M. Violette, Summit Blue Consulting,Response Resources by Daniel M. Violette, Rachel Freeman andFramework, Dr. Daniel M. Violette, Summit Blue Consulting,

Heffner, Grayson

2010-01-01T23:59:59.000Z

267

Gas Storage and Diffusion through Nanocages and Windows in Porous Metal–Organic Framework Cu2(2,3,5,6-tetramethylbenzene-1,4-diisophthalate)(H2O)2  

Science Journals Connector (OSTI)

§ Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, Shandong 266101, P. R. ... Chemical Society Reviews (2012), 41 (23), 7761-7779 CODEN: CSRVBR; ISSN:0306-0012. ... A review of the literature ...

Liangjun Li; Jon G. Bell; Sifu Tang; Xiaoxia Lv; Chao Wang; Yanlong Xing; Xuebo Zhao; K. Mark Thomas

2014-07-21T23:59:59.000Z

268

Two novel metal organic frameworks of Sn(II) and Pb(II) with Pyridine-2,6-dicarboxylic Acid and 4,4?-Bipyridine: syntheses, crystal structures and solution studies  

Science Journals Connector (OSTI)

Two novel compounds with formulae [Sn2(pydcH)2(H2O)2O]n, 1, and (4,4?-bpyH2)0.5[Pb(pydc)2(4,4?-bpyH)].4,4?-bpy.4H2O, 2, were obtained from a one-pot reaction between pyridine-2,6-dicarboxylic acid (pydcH2) and 4,...

J. Soleimannejad; H. Aghabozorg; S. Hooshmand…

2010-06-01T23:59:59.000Z

269

Introduction to Framework | Open Energy Information  

Open Energy Info (EERE)

Introduction to Framework Introduction to Framework (Redirected from Introduction to Methodology) Jump to: navigation, search Stage 1 LEDS Home Introduction to Framework Assess current country plans, policies, practices, and capacities Develop_BAU Stage 4: Prioritizing and Planning for Actions Begin execution of implementation plans 1.0. Organizing the LEDS Process 1.1. Institutional Structure for LEDS 1.2. Workplan to Develop the LEDS 1.3. Roles and responsibilities to develop LEDS 2.1. Assess current country plans, policies, practices, and capacities 2.2. Compile lessons learned and good practices from ongoing and previous sustainable development efforts in the country 2.3. Assess public and private sector capacity to support initiatives 2.4. Assess and improve the national GHG inventory and other

270

Introduction to Framework | Open Energy Information  

Open Energy Info (EERE)

Introduction to Framework Introduction to Framework Jump to: navigation, search Stage 1 LEDS Home Introduction to Framework Assess current country plans, policies, practices, and capacities Develop_BAU Stage 4: Prioritizing and Planning for Actions Begin execution of implementation plans 1.0. Organizing the LEDS Process 1.1. Institutional Structure for LEDS 1.2. Workplan to Develop the LEDS 1.3. Roles and responsibilities to develop LEDS 2.1. Assess current country plans, policies, practices, and capacities 2.2. Compile lessons learned and good practices from ongoing and previous sustainable development efforts in the country 2.3. Assess public and private sector capacity to support initiatives 2.4. Assess and improve the national GHG inventory and other economic and resource data as needed for LEDS development

271

Conceptual Framework Presentation, 2006, Slide 1 The Conceptual Framework for  

E-Print Network (OSTI)

Conceptual Framework Presentation, 2006, Slide 1 The Conceptual Framework for Programs that Prepare Professionals Who Work in Schools What - Why - and Why You? #12;Conceptual Framework Presentation, 2006, Slide 2 on and develop your philosophy as a professional. . . WHY YOU? #12;Conceptual Framework Presentation, 2006, Slide

de Lijser, Peter

272

Framework for Physics Computation  

SciTech Connect

The Georgia Tech team has been working in collaboration with ORNL and Rutgers on improved I/O for petascale fusion codes, specifically, to integrate staging methods into the ADIOS framework. As part of this on-going work, we have released the DataTap server as part of the ADIOS release, and we have been working on improving the ‘in situ’ processing capabilities of the ADIOS framework. In particular, we have been moving forward with a design that adds additional metadata to describe the data layout and structure of data that is being moved for I/O purposes, building on the FFS type system developed in our past research

Schwan, Karsten [Georgia Institute of Technology

2012-01-13T23:59:59.000Z

273

Metal Oxides  

Science Journals Connector (OSTI)

Metal oxides are the class of materials having the widest application in gas sensors. This chapter presents information related to the application of various metal oxides in gas sensors designed on different p...

Ghenadii Korotcenkov

2013-01-01T23:59:59.000Z

274

Silicone metalization  

DOE Patents (OSTI)

A system for providing metal features on silicone comprising providing a silicone layer on a matrix and providing a metal layer on the silicone layer. An electronic apparatus can be produced by the system. The electronic apparatus comprises a silicone body and metal features on the silicone body that provide an electronic device.

Maghribi, Mariam N. (Livermore, CA); Krulevitch, Peter (Pleasanton, CA); Hamilton, Julie (Tracy, CA)

2006-12-05T23:59:59.000Z

275

The Framework of Astronomy  

Science Journals Connector (OSTI)

... FOR his inaugural lecture as Perren professor of astronomy in the University of London, which he gave last year at University College, London ... , London, Prof. C. W. Allen chose as his subject "The Framework of Astronomy". At the beginning of this lecture, which has now been published*, Prof. ...

1953-09-12T23:59:59.000Z

276

Semantic resource framework  

Science Journals Connector (OSTI)

The Semantic Resource Framework (SRF) is a multi-level description of the data sources for search computing applications. It responds to the need of having a structured representation of search services, amenable to service exploration, selection, and ... Keywords: ontology, search services, semantic annotation, service description, service repository

Marco Brambilla; Alessandro Campi; Stefano Ceri; Silvia Quarteroni

2011-01-01T23:59:59.000Z

277

Organic Vegetable Organic Vegetable  

E-Print Network (OSTI)

marketed separately from conventionally grown produce in order to be profitably sold. Because of the amount of organic material include compost, Purdue University · Cooperative Extension Service · Knowledge to Go

278

E-Print Network 3.0 - absorbable organic halides Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Collection: Chemistry 64 386 JACKHALPERN VOl. 3 xidative-AdditionReactions of Transition Metal Complexes Summary: peroxide, as well as various organic halides and metal...

279

Sustainable Bioenergy: A Framework for Decision Makers | Open Energy  

Open Energy Info (EERE)

Sustainable Bioenergy: A Framework for Decision Makers Sustainable Bioenergy: A Framework for Decision Makers Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Sustainable Bioenergy: A Framework for Decision Makers Agency/Company /Organization: Food and Agriculture Organization of the United Nations Sector: Energy, Land Focus Area: Renewable Energy, Biomass Topics: Implementation, Policies/deployment programs Resource Type: Guide/manual, Lessons learned/best practices Website: esa.un.org/un-energy/pdf/susdev.Biofuels.FAO.pdf References: Sustainable Bioenergy: A Framework for Decision Makers[1] "In this publication, UN-Energy seeks to structure an approach to the current discussion on bioenergy, it is the contribution of the UN system to the issues that need further attention, analysis and valuation, so that

280

Detection of Heavy Metal Ions Based on Quantum Point Contacts  

E-Print Network (OSTI)

. The ability to detect trace amounts of metal ions is important because of the toxicity of heavy metal ionsDetection of Heavy Metal Ions Based on Quantum Point Contacts Vasanth Rajagopalan, Salah Boussaad on many living organisms and the consequence of heavy metal ions not being biodegradable. To date, heavy

Zhang, Yanchao

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Rwanda-Developing a Strategic Climate Change Framework | Open Energy  

Open Energy Info (EERE)

Rwanda-Developing a Strategic Climate Change Framework Rwanda-Developing a Strategic Climate Change Framework (Redirected from CDKN-Rwanda-Developing a Strategic Climate Change Framework) Jump to: navigation, search Name CDKN-Rwanda-Developing a Strategic Climate Change Framework and Design of a Climate Change and Environmental Fund Agency/Company /Organization Climate and Development Knowledge Network (CDKN), United Kingdom Department for International Development Partner REMA, Government of Rwanda Sector Climate, Energy, Land Topics Background analysis, Low emission development planning, Pathways analysis Website http://cdkn.org/project/a-stra Program Start 2010 Program End 2012 Country Rwanda UN Region Middle Africa References CDKN-Rwanda-Developing a Strategic Climate Change Framework[1] Rwanda's ambitious Green Growth and Climate Resilience Strategy was

282

A software framework for developing measurement applications under variable requirements  

Science Journals Connector (OSTI)

A framework for easily developing software for measurement and test applications under highly and fast-varying requirements is proposed. The framework allows the software quality in terms of flexibility usability and maintainability to be maximized. Furthermore the development effort is reduced and finalized by relieving the test engineer of development details. The framework can be configured for satisfying a large set of measurement applications in a generic field for an industrial test division a test laboratory or a research center. As an experimental case study the design the implementation and the assessment inside the application to a measurement scenario of magnettesting at the European Organization for Nuclear Research is reported.

Pasquale Arpaia; Marco Buzio; Lucio Fiscarelli; Vitaliano Inglese

2012-01-01T23:59:59.000Z

283

Ravi Metallics Ltd | Open Energy Information  

Open Energy Info (EERE)

Metallics Ltd Metallics Ltd Jump to: navigation, search Name Ravi Metallics Ltd. Place Rourkela, Orissa, India Zip 769004 Sector Biomass Product Rourkela-based biomass project developer. References Ravi Metallics Ltd.[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Ravi Metallics Ltd. is a company located in Rourkela, Orissa, India . References ↑ "Ravi Metallics Ltd." Retrieved from "http://en.openei.org/w/index.php?title=Ravi_Metallics_Ltd&oldid=350202" Categories: Clean Energy Organizations Companies Organizations Stubs What links here Related changes Special pages Printable version Permanent link Browse properties 429 Throttled (bot load) Error 429 Throttled (bot load)

284

E-Print Network 3.0 - advantageous metal ion Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Metal Ions and Organic Ligands C H I N G - H U A H... catalyzed by +II transition metal ions exhibiting strong affinities for nitrogen- and oxygen-donor ligands... metal ions...

285

Nuclear Safety Regulatory Framework  

NLE Websites -- All DOE Office Websites (Extended Search)

Department of Energy Department of Energy Nuclear Safety Regulatory Framework DOE's Nuclear Safety Enabling Legislation Regulatory Enforcement & Oversight Regulatory Governance Atomic Energy Act 1946 Atomic Energy Act 1954 Energy Reorganization Act 1974 DOE Act 1977 Authority and responsibility to regulate nuclear safety at DOE facilities 10 CFR 830 10 CFR 835 10 CFR 820 Regulatory Implementation Nuclear Safety Radiological Safety Procedural Rules ISMS-QA; Operating Experience; Metrics and Analysis Cross Cutting DOE Directives & Manuals DOE Standards Central Technical Authorities (CTA) Office of Health, Safety, and Security (HSS) Line Management SSO/ FAC Reps 48 CFR 970 48 CFR 952 Federal Acquisition Regulations External Oversight *Defense Nuclear Facility

286

Threat Analysis Framework | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Threat Analysis Framework The need to protect national critical infrastructure has led to the development of a threat analysis framework. The threat analysis framework can be...

287

Development of a metal hydride electrode waste treatment process  

SciTech Connect

Manufacturing residues of metal hydride electrodes for nickel - metal hydride batteries were chemically processed to recover the metal part and heat treated for the organic part. Chemical recovery yielded Ni-Co alloy after electrolysis of the solution and hydroxides of other metal, mainly rare earths. The organic part, pyrolyzed at 700 C, led to separation between carbon and fluorinated matter. Infrared coupling at the output of the pyrolysis furnace was used to identify the pyrolysis gases.

Bianco, J.C.; Martin, D.; Ansart, F.; Castillo, S.

1999-12-01T23:59:59.000Z

288

Science Organizations  

NLE Websites -- All DOE Office Websites (Extended Search)

Organizations Science Organizations National security depends on science and technology. The United States relies on Los Alamos National Laboratory for the best of both. No place...

289

Vitrification of organics-containing wastes  

DOE Patents (OSTI)

A process for stabilizing organics-containing waste materials and recovery metals therefrom, and a waste glass product made according to the process are described. Vitrification of wastes such as organic ion exchange resins, electronic components and the like can be accomplished by mixing at least one transition metal oxide with the wastes, and, if needed, glass formers to compensate for a shortage of silicates or other glass formers in the wastes. The transition metal oxide increases the rate of oxidation of organic materials in the wastes to improve the composition of the glass-forming mixture: at low temperatures, the oxide catalyzes oxidation of a portion of the organics in the waste; at higher temperatures, the oxide dissolves and the resulting oxygen ions oxidize more of the organics; and at vitrification temperatures, the metal ions conduct oxygen into the melt to oxidize the remaining organics. In addition, the transition metal oxide buffers the redox potential of the glass melt so that metals such as Au, Pt, Ag, and Cu separate form the melt in the metallic state and can be recovered. After the metals are recovered, the remainder of the melt is allowed to cool and may subsequently be disposed of. The product has good leaching resistance and can be disposed of in an ordinary landfill, or, alternatively, used as a filler in materials such as concrete, asphalt, brick and tile.

Bickford, D.F.

1995-01-01T23:59:59.000Z

290

Metal oxide films on metal  

DOE Patents (OSTI)

A structure including a thin film of a conductive alkaline earth metal oxide selected from the group consisting of strontium ruthenium trioxide, calcium ruthenium trioxide, barium ruthenium trioxide, lanthanum-strontium cobalt oxide or mixed alkaline earth ruthenium trioxides thereof upon a thin film of a noble metal such as platinum is provided.

Wu, Xin D. (Los Alamos, NM); Tiwari, Prabhat (Los Alamos, NM)

1995-01-01T23:59:59.000Z

291

Energy Sector Cybersecurity Framework Implementation Guidance  

Energy Savers (EERE)

DRAFT FOR PUBLIC COMMENT SEPTEMBER, 2014 ENERGY SECTOR CYBERSECURITY FRAMEWORK IMPLEMENTATION GUIDANCE Energy Sector Cybersecurity Framework Implementation Guidance Table of...

292

Organization | Department of Energy  

Energy Savers (EERE)

About Us Organization Organization Organization Printable PDF News & Blog CIO Leadership Organization Contact Us...

293

Organization | Department of Energy  

Office of Environmental Management (EM)

About Us Organization Organization Organization News Leadership Organization History Careers Contact Us...

294

Electron transport through a metal-molecule-metal junction  

Science Journals Connector (OSTI)

Molecules of bisthiolterthiophene have been adsorbed on the two facing gold electrodes of a mechanically controllable break junction in order to form metal-molecule(s)-metal junctions. Current-voltage (I-V) characteristics have been recorded at room temperature. Zero bias conductances were measured in the 10–100 nS range and different kinds of nonlinear I-V curves with steplike features were reproducibly obtained. Switching between different kinds of I-V curves could be induced by varying the distance between the two metallic electrodes. The experimental results are discussed within the framework of tunneling transport models explicitly taking into account the discrete nature of the electronic spectrum of the molecule.

C. Kergueris; J.-P. Bourgoin; S. Palacin; D. Esteve; C. Urbina; M. Magoga; C. Joachim

1999-05-15T23:59:59.000Z

295

Metal Toxicity  

Science Journals Connector (OSTI)

Problems posed to plants by metal toxicity in the soils of the world are basically of two kinds. The first kind are of natural origin. These arise either as a consequence of the nature of the parent material f...

T. McNeilly

1994-01-01T23:59:59.000Z

296

Dendritic metal nanostructures  

DOE Patents (OSTI)

Dendritic metal nanostructures made using a surfactant structure template, a metal salt, and electron donor species.

Shelnutt, John A. (Tijeras, NM); Song, Yujiang (Albuquerque, NM); Pereira, Eulalia F. (Vila Nova de Gaia, PT); Medforth, Craig J. (Winters, CA)

2010-08-31T23:59:59.000Z

297

RISK MANAGEMENT FRAMEWORK: HELPING ORGANIZATIONS IMPLEMENT EFFECTIVE INFORMATION SECURITY PROGRAMS  

E-Print Network (OSTI)

organizational managers in making informed decisions regarding the security of their information systems. NIST agencies implementing risk-based planning and management also must consider effectiveness, efficiency for their information and information systems with the gains in capabilities and improved support of organizational

298

An object-oriented framework to organize genomic data  

E-Print Network (OSTI)

APPENDIX M: WEB PRESENTATION LAYER - ContigList.jsp ............................. 147 APPENDIX N: WEB PRESENTATION LAYER - xwork.xml ................................... 148 APPENDIX O: WEB PRESENTATION LAYER - action-servlet... to a Java Servlet which processes it, interacts with a database and produces an HTML-formatted response, or it is given to a JavaServer Pages (JSP) document. Both approaches are often considered inadequate for large projects because they mix...

Wei, Ning

2009-05-15T23:59:59.000Z

299

Vision for 2025: A Framework for Change  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Action Plan for Energy Effi Action Plan for Energy Effi ciency Vision for 2025: A Framework for Change A RESOURCE OF THE NATIONAL ACTION PLAN FOR ENERGY EFFICIENCY NOVEMBER 2008 Letter from the Co-Chairs of the National Action Plan for Energy Effi ciency November 2008 To all, As you know, the National Action Plan for Energy Effi ciency is playing a vital role in advancing the dialogue and the pursuit of energy effi ciency in our homes, buildings, and industries -an important energy resource for the country. With the commitment and leadership from more than 60 diverse organizations nationwide we have made great progress in a short time. We have: * Developed fi ve broad and meaningful recommendations for pursuing cost-effective energy effi ciency. * Brought together more than 100 organizations from 50 states around this common goal to take energy effi

300

Digital forensics investigation framework that incorporate legal issues  

E-Print Network (OSTI)

aspects · Each organization has its own procedures · Technology changes new procedures. #12;Frequently;Presentation Outline 1. Introduction 2. Fundamental principle in digital forensics investigation procedures 3. FORZA framework ­ the link to bind them all 4. Bringing legal aspects into the picture 5. Applying FORZA

Almulhem, Ahmad

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Energy Forecasting Framework and Emissions Consensus Tool (EFFECT) | Open  

Open Energy Info (EERE)

Energy Forecasting Framework and Emissions Consensus Tool (EFFECT) Energy Forecasting Framework and Emissions Consensus Tool (EFFECT) Jump to: navigation, search LEDSGP green logo.png FIND MORE DIA TOOLS This tool is part of the Development Impacts Assessment (DIA) Toolkit from the LEDS Global Partnership. Tool Summary LAUNCH TOOL Name: Energy Forecasting Framework and Emissions Consensus Tool (EFFECT) Agency/Company /Organization: Energy Sector Management Assistance Program of the World Bank Sector: Energy Focus Area: Non-renewable Energy Topics: Baseline projection, Co-benefits assessment, GHG inventory Resource Type: Software/modeling tools User Interface: Spreadsheet Complexity/Ease of Use: Simple Website: www.esmap.org/esmap/EFFECT Cost: Free Equivalent URI: www.esmap.org/esmap/EFFECT Energy Forecasting Framework and Emissions Consensus Tool (EFFECT) Screenshot

302

Rwanda-Developing a Strategic Climate Change Framework | Open Energy  

Open Energy Info (EERE)

Rwanda-Developing a Strategic Climate Change Framework Rwanda-Developing a Strategic Climate Change Framework Jump to: navigation, search Name CDKN-Rwanda-Developing a Strategic Climate Change Framework and Design of a Climate Change and Environmental Fund Agency/Company /Organization Climate and Development Knowledge Network (CDKN), United Kingdom Department for International Development Partner REMA, Government of Rwanda Sector Climate, Energy, Land Topics Background analysis, Low emission development planning, Pathways analysis Website http://cdkn.org/project/a-stra Program Start 2010 Program End 2012 Country Rwanda UN Region Middle Africa References CDKN-Rwanda-Developing a Strategic Climate Change Framework[1] Rwanda's ambitious Green Growth and Climate Resilience Strategy was launched at a UNFCCC side event at CoP17 in Durban. Rwanda joins Korea,

303

Sodium loop framework structural analysis  

SciTech Connect

This document provides the structural analysis of the Sodium Loop framework in a drop condition. The drop is similar to the US Department of Transportation non-bulk, performance-oriented packaging (Packaging Group I) drop test. The drop height evaluated for the Sodium Loop framework is 5.9 ft.

Nguyen, P.M.

1995-06-06T23:59:59.000Z

304

Transportation System Readiness and Resiliency Assessment Framework: Readiness and Assess Resiliency of  

E-Print Network (OSTI)

Transportation System Readiness and Resiliency Assessment Framework: Readiness and Assess Resiliency of Transportation Systems (Infrastructure, Systems, Organization and Services) to Deter, Detect Flows Passenger Flows Supply Chain Efficiency Transportation: Energy Environment Safety Security Vehicle

305

Metalorganic frameworks Gas-Sorption Properties of Cobalt(II)Carborane-Based  

E-Print Network (OSTI)

Metal�organic frameworks Gas-Sorption Properties of Cobalt(II)�Carborane-Based Coordination materials, and nanostructures. Interestingly however, none of these studies address how the gas-sorption

306

Ambient-pressure organic superconductor  

DOE Patents (OSTI)

A new class of organic superconductors having the formula (ET).sub.2 MX.sub.2 wherein ET represents bis(ethylenedithio)-tetrathiafulvalene, M is a metal such as Au, Ag, In, Tl, Rb, Pd and the like and X is a halide. The superconductor (ET).sub.2 AuI.sub.2 exhibits a transition temperature of 5 K which is high for organic superconductors.

Williams, Jack M. (Downers Grove, IL); Wang, Hsien-Hau (Willowbrook, IL); Beno, Mark A. (Woodridge, IL)

1986-01-01T23:59:59.000Z

307

Route to transition metal carbide nanoparticles through cyanamide and metal oxides  

SciTech Connect

We have designed an efficient route to the synthesis of transition metal carbide nanoparticles starting from an organic reagent cyanamide and transition metal oxides. Four technologically important metal carbide nanoparticles such as tungsten carbide, niobium carbide, tantalum carbide and vanadium carbide were synthesized successfully at moderate temperatures. It is found that cyanamide is an efficient carburization reagent and that the metal oxides are completely transmitted into the corresponding carbide nanoparticles. A possible mechanism is proposed to explain the results of the reaction between cyanamide and the metal oxides.

Li, P.G. [Department of Physics, Center for Optoelectronics Materials and Devices, Zhejiang Sci-Tech University, Xiasha College Park, Hangzhou 310018 (China)], E-mail: peigangiphy@yahoo.com.cn; Lei, M.; Tang, W.H. [Department of Physics, Center for Optoelectronics Materials and Devices, Zhejiang Sci-Tech University, Xiasha College Park, Hangzhou 310018 (China)

2008-12-01T23:59:59.000Z

308

Metals Production Requirements for Rapid Photovoltaics Deployment  

E-Print Network (OSTI)

If global photovoltaics (PV) deployment grows rapidly, the required input materials need to be supplied at an increasing rate. In this paper, we quantify the effect of PV deployment levels on the scale of metals production. For example, we find that if cadmium telluride {copper indium gallium diselenide} PV accounts for more than 3% {10%} of electricity generation by 2030, the required growth rates for the production of indium and tellurium would exceed historically-observed production growth rates for a large set of metals. In contrast, even if crystalline silicon PV supplies all electricity in 2030, the required silicon production growth rate would fall within the historical range. More generally, this paper highlights possible constraints to the rate of scaling up metals production for some PV technologies, and outlines an approach to assessing projected metals growth requirements against an ensemble of past growth rates from across the metals production sector. The framework developed in this paper may be...

Kavlak, Goksin; Jaffe, Robert L; Trancik, Jessika E

2015-01-01T23:59:59.000Z

309

REVIEW ARTICLE Heavy Metal Pollutants and Chemical Ecology: Exploring  

E-Print Network (OSTI)

REVIEW ARTICLE Heavy Metal Pollutants and Chemical Ecology: Exploring New Frontiers Robert S. Boyd to be learned about how heavy metal pollution impacts organisms, and that exciting new research frontiers as pollutants (Han et al. 2002), including Cd, Cu, Cr, Hg, Pb, Ni, and Zn. Much research on heavy metal

Boyd, Robert S.

310

Composite metal membrane  

DOE Patents (OSTI)

A composite metal membrane including a first metal layer of Group IVB met or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof is provided together with a process for the recovery of hydrogen from a gaseous mixture including contacting a hydrogen-containing gaseous mixture with a first side of a nonporous composite metal membrane including a first metal of Group IVB metals or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof, and, separating hydrogen from a second side of the nonporous composite metal membrane.

Peachey, Nathaniel M. (Espanola, NM); Dye, Robert C. (Los Alamos, NM); Snow, Ronny C. (Los Alamos, NM); Birdsell, Stephan A. (Los Alamos, NM)

1998-01-01T23:59:59.000Z

311

Composite metal membrane  

DOE Patents (OSTI)

A composite metal membrane including a first metal layer of Group IVB met or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof is provided together with a process for the recovery of hydrogen from a gaseous mixture including contacting a hydrogen-containing gaseous mixture with a first side of a nonporous composite metal membrane including a first metal of Group IVB metals or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof, and, separating hydrogen from a second side of the nonporous composite metal membrane.

Peachey, N.M.; Dye, R.C.; Snow, R.C.; Birdsell, S.A.

1998-04-14T23:59:59.000Z

312

A Formal Framework of AOC  

Science Journals Connector (OSTI)

For an AOC system, autonomous entities and an environment are ... their environment are the force that drives an AOC system to evolve towards certain desired states. ... and have provided a general framework for ...

2005-01-01T23:59:59.000Z

313

Sample Business Plan Framework 3  

Energy.gov (U.S. Department of Energy (DOE))

U.S. Department of Energy Better Buildings Neighborhood Program: Sample Business Plan Framework 1: A program seeking to continue operations in the post-grant period as a not-for-profit (NGO) entity.

314

Sample Business Plan Framework 5  

Energy.gov (U.S. Department of Energy (DOE))

U.S. Department of Energy Better Buildings Neighborhood Program: Sample Business Plan Framework 1: A program seeking to continue operations in the post-grant period as a not-for-profit (NGO) entity.

315

Sample Business Plan Framework 2  

Energy.gov (U.S. Department of Energy (DOE))

U.S. Department of Energy Better Buildings Neighborhood Program: Sample Business Plan Framework 1: A program seeking to continue operations in the post-grant period as a not-for-profit (NGO) entity.

316

Sample Business Plan Framework 1  

Energy.gov (U.S. Department of Energy (DOE))

U.S. Department of Energy Better Buildings Neighborhood Program: Sample Business Plan Framework 1: A program seeking to continue operations in the post-grant period as a not-for-profit (NGO) entity.

317

Decision-Based Design Framework  

Science Journals Connector (OSTI)

With methods for modeling designer preference and customer preference presented in Chaps. 2 and 3, respectively, the decision-based design (DBD) framework and taxonomy is fully developed in this chapter. DBD i...

Wei Chen; Christopher Hoyle; Henk Jan Wassenaar

2013-01-01T23:59:59.000Z

318

Sample Business Plan Framework 4  

Energy.gov (U.S. Department of Energy (DOE))

U.S. Department of Energy Better Buildings Neighborhood Program: Sample Business Plan Framework 1: A program seeking to continue operations in the post-grant period as a not-for-profit (NGO) entity.

319

Geologic Framework Model (GFM2000)  

SciTech Connect

The purpose of this report is to document the geologic framework model, version GFM2000 with regard to input data, modeling methods, assumptions, uncertainties, limitations, and validation of the model results, and the differences between GFM2000 and previous versions. The version number of this model reflects the year during which the model was constructed. This model supersedes the previous model version, documented in Geologic Framework Model (GFM 3.1) (CRWMS M&O 2000 [DIRS 138860]). The geologic framework model represents a three-dimensional interpretation of the geology surrounding the location of the monitored geologic repository for spent nuclear fuel and high-level radioactive waste at Yucca Mountain. The geologic framework model encompasses and is limited to an area of 65 square miles (168 square kilometers) and a volume of 185 cubic miles (771 cubic kilometers). The boundaries of the geologic framework model (shown in Figure 1-1) were chosen to encompass the exploratory boreholes and to provide a geologic framework over the area of interest for hydrologic flow and radionuclide transport modeling through the unsaturated zone (UZ). The upper surface of the model is made up of the surface topography and the depth of the model is constrained by the inferred depth of the Tertiary-Paleozoic unconformity. The geologic framework model was constructed from geologic map and borehole data. Additional information from measured stratigraphic sections, gravity profiles, and seismic profiles was also considered. The intended use of the geologic framework model is to provide a geologic framework over the area of interest consistent with the level of detailed needed for hydrologic flow and radionuclide transport modeling through the UZ and for repository design. The model is limited by the availability of data and relative amount of geologic complexity found in an area. The geologic framework model is inherently limited by scale and content. The grid spacing used in the geologic framework model (200 feet [61 meters]), discussed in Section 6.4.2, limits the size of features that can be resolved by the model but is appropriate for the distribution of data available and its intended use. Uncertainty and limitations are discussed in Section 6.6 and model validation is discussed in Section 7.

T. Vogt

2004-08-26T23:59:59.000Z

320

Metal resistance sequences and transgenic plants  

SciTech Connect

The present invention provides nucleic acid sequences encoding a metal ion resistance protein, which are expressible in plant cells. The metal resistance protein provides for the enzymatic reduction of metal ions including but not limited to divalent Cu, divalent mercury, trivalent gold, divalent cadmium, lead ions and monovalent silver ions. Transgenic plants which express these coding sequences exhibit increased resistance to metal ions in the environment as compared with plants which have not been so genetically modified. Transgenic plants with improved resistance to organometals including alkylmercury compounds, among others, are provided by the further inclusion of plant-expressible organometal lyase coding sequences, as specifically exemplified by the plant-expressible merB coding sequence. Furthermore, these transgenic plants which have been genetically modified to express the metal resistance coding sequences of the present invention can participate in the bioremediation of metal contamination via the enzymatic reduction of metal ions. Transgenic plants resistant to organometals can further mediate remediation of organic metal compounds, for example, alkylmetal compounds including but not limited to methyl mercury, methyl lead compounds, methyl cadmium and methyl arsenic compounds, in the environment by causing the freeing of mercuric or other metal ions and the reduction of the ionic mercury or other metal ions to the less toxic elemental mercury or other metals.

Meagher, Richard Brian (Athens, GA); Summers, Anne O. (Athens, GA); Rugh, Clayton L. (Athens, GA)

1999-10-12T23:59:59.000Z

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Organic Photovoltaics  

Science Journals Connector (OSTI)

Satisfying the world's growing demand for energy is an urgent societal challenge. Organic photovoltaics holds promise as a cost-efficient and environmentally friendly solution.

Kippelen, Bernard

2007-01-01T23:59:59.000Z

322

Method of photocatalytic conversion of C-H organics  

DOE Patents (OSTI)

The present invention is the addition of a semiconductor material and energy to the reaction mixture of organic, acid (for example, trifluoroacetate), and oxygen. A transition metal ion may be added to the reaction mixture. The semiconductor material converts energy to oxidants thereby promoting oxidation of the organic. Alternatively, using metal in combination with exposure to light may be used.

Camaioni, Donald M. (Richland, WA); Lilga, Michael A. (Richland, WA)

1998-01-01T23:59:59.000Z

323

Method of photocatalytic conversion of C-H organics  

DOE Patents (OSTI)

The present invention is the addition of a semiconductor material and energy to the reaction mixture of organic, acid (for example, trifluoroacetate), and oxygen. A transition metal ion may be added to the reaction mixture. The semiconductor material converts energy to oxidants thereby promoting oxidation of the organic. Alternatively, using metal in combination with exposure to light may be used.

Camaioni, D.M.; Lilga, M.A.

1998-01-13T23:59:59.000Z

324

Thermoelectric Activities of European Community within Framework...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

of European Community within Framework Programme 7 and additional activities in Germany Thermoelectric Activities of European Community within Framework Programme 7 and...

325

Energy Sector Cybersecurity Framework Implementation Guidance...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Cybersecurity Framework Implementation Guidance - Notice of Public Comment: Federal Register Notice, Volume 79, No. 177, September 12, 2014 Energy Sector Cybersecurity Framework...

326

Energy 101 Undergraduate Course Framework: Infosheet | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Undergraduate Course Framework: Infosheet Energy 101 Undergraduate Course Framework: Infosheet Energy101infosheet.pdf More Documents & Publications Energy 101 Webinar Energy...

327

Nuclear Safety Regulatory Framework | Department of Energy  

Energy Savers (EERE)

Presentation that outlines the rules, policies and orders that comprise the Department of Energy Nuclear Safety Regulatory Framework. Nuclear Safety Regulatory Framework More...

328

A framework model for grid security  

Science Journals Connector (OSTI)

Computational grids can be considered as tiered objects; following a widespread terminology, cluster grids may be grouped into enterprise grids, that in turn may belong to global grids. Therefore, computing grid security has to be “tiered” too, with the ground level remaining the OS one. In this work, we introduce a sort of unified approach, an overall architectural framework for access control to grid resources, and one that adheres as much as possible to current security principles. Current grid security implementations are viewed in the light of this model, their main drawbacks are described, and we show how our proposal is able to avoid them. We believe that a main strategy could be to adopt both PKI and PMI infrastructures at the grid layer, ensuring that an adequate transfer of authentication and authorization will be made between the Virtual Organization and Resource Provider layers. This can be achieved by extending those features at the OS layer as system applications and services.

G. Laccetti; G. Schmid

2007-01-01T23:59:59.000Z

329

SDS: A Framework for Scientific Data Services  

SciTech Connect

Large-scale scientific applications typically write their data to parallel file systems with organizations designed to achieve fast write speeds. Analysis tasks frequently read the data in a pattern that is different from the write pattern, and therefore experience poor I/O performance. In this paper, we introduce a prototype framework for bridging the performance gap between write and read stages of data access from parallel file systems. We call this framework Scientific Data Services, or SDS for short. This initial implementation of SDS focuses on reorganizing previously written files into data layouts that benefit read patterns, and transparently directs read calls to the reorganized data. SDS follows a client-server architecture. The SDS Server manages partial or full replicas of reorganized datasets and serves SDS Clients' requests for data. The current version of the SDS client library supports HDF5 programming interface for reading data. The client library intercepts HDF5 calls and transparently redirects them to the reorganized data. The SDS client library also provides a querying interface for reading part of the data based on user-specified selective criteria. We describe the design and implementation of the SDS client-server architecture, and evaluate the response time of the SDS Server and the performance benefits of SDS.

Dong, Bin; Byna, Surendra; Wu, Kesheng

2013-10-31T23:59:59.000Z

330

Integrated Global System Modeling Framework | Open Energy Information  

Open Energy Info (EERE)

Integrated Global System Modeling Framework Integrated Global System Modeling Framework Jump to: navigation, search LEDSGP green logo.png FIND MORE DIA TOOLS This tool is part of the Development Impacts Assessment (DIA) Toolkit from the LEDS Global Partnership. Tool Summary LAUNCH TOOL Name: Integrated Global System Modeling Framework Agency/Company /Organization: MIT Joint Program on the Science and Policy of Global Change Sector: Climate, Energy Focus Area: Renewable Energy Phase: Determine Baseline, Evaluate Options Topics: - Macroeconomic Resource Type: Software/modeling tools User Interface: Desktop Application Complexity/Ease of Use: Not Available Website: globalchange.mit.edu/research/IGSM Cost: Free Related Tools Transport Co-benefits Calculator General Equilibrium Modeling Package (GEMPACK)

331

Site transition framework for long-term surveillance and maintenance  

SciTech Connect

This document provides a framework for all U.S. Department of Energy (DOE) facilities and sites where DOE may have anticipated long-term surveillance and maintenance (LTSM) responsibilities. It is a tool to help facilitate a smooth transition from remediation to LTSM, providing a systematic process for affected parties to utilize in analyzing the baseline to understand and manage the actions from EM mission completion through a site’s transition into LTSM. The framework is not meant to provide an exhaustive list of the specific requirement and information that are needed. Sites will have unique considerations that may not be adequately addressed by this tool, and it is anticipated that a team comprised of the transferring and receiving organization will use judgment in utilizing this augmenting with other DOE guidance. However the framework should be followed to the extent possible at each site; and adapted to accommodate unique site-specific requirements, needs, and documents. Since the objective of the tool is facilitate better understanding of the conditions of the site and the actions required for transfer, the transition team utilizing the checklist is expected to consult with management of both the receiving and transferring organization to verify that major concerns are addressed. Ideally, this framework should be used as early in the remediation process as possible. Subsequent applications of the Site Transition Framework (STF) to the site should be conducted periodically and used to verify that all appropriate steps have been or will be taken to close-out the site and that actions by both organization are identified to transfer the site to LTSM. The requirements are provided herein.

none,

2014-04-01T23:59:59.000Z

332

Legal Frameworks for REDD: Design and Implementation at the National Level  

Open Energy Info (EERE)

Legal Frameworks for REDD: Design and Implementation at the National Level Legal Frameworks for REDD: Design and Implementation at the National Level Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Legal Frameworks for REDD: Design and Implementation at the National Level Agency/Company /Organization: International Union for Conservation of Nature Sector: Land Focus Area: Forestry Topics: Implementation Resource Type: Publications Website: data.iucn.org/dbtw-wpd/edocs/EPLP-077.pdf Legal Frameworks for REDD: Design and Implementation at the National Level Screenshot References: Legal Frameworks for REDD: Design and Implementation at the National Level[1] Summary "This publication identifies and analyzes critical issues in the formulation and implementation of national and sub-national legal frameworks for REDD activities. Lessons are drawn from the wealth of

333

Mechanochemical processing for metals and metal alloys  

DOE Patents (OSTI)

A set of processes for preparing metal powders, including metal alloy powders, by ambient temperature reduction of a reducible metal compound by a reactive metal or metal hydride through mechanochemical processing. The reduction process includes milling reactants to induce and complete the reduction reaction. The preferred reducing agents include magnesium and calcium hydride powders. A process of pre-milling magnesium as a reducing agent to increase the activity of the magnesium has been established as one part of the invention.

Froes, Francis H. (Moscow, ID); Eranezhuth, Baburaj G. (Moscow, ID); Prisbrey, Keith (Moscow, ID)

2001-01-01T23:59:59.000Z

334

Programmatic Framework | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Programmatic Framework Programmatic Framework Programmatic Framework PROGRAM FACT SHEETS FUSRAP Nevada Offsites UMTRCA Title I and II PROGRAM TYPES UMTRCA Title I Sites UMTRCA Title II Sites FUSRAP Sites D&D Sites Nevada Offsites CERCLA/RCRA Sites NWPA Section 151 Site Other UMTRCA Title I Disposal and Processing Sites (Regulatory Drivers) For UMTRCA Title I disposal sites managed by LM, DOE becomes a licensee to the U.S. Nuclear Regulatory Commission (NRC). Inspection, reporting, and record-keeping requirements are defined in Title 10 Code of Federal Regulations (CFR) Part 40.27, "General License for Custody and Long-Term Care of Residual Radioactive Material Disposal Sites." The general license for long-term custody is indefinite in duration. Usually, title for the land is assigned to an agency of the Federal government, and the land is

335

Organic geochemistry and organic petrography  

SciTech Connect

The Vermillion Creek coals and shales contain dominantly humic organic matter originating from woody plant tissues except for one shale unit above the coals, which contains hydrogen-rich kerogen that is mostly remains of filamentous algae, of likely lacustrine origin. The coals have two unusual features - very low inertinite content and high sulfur content compared to mined western coals. However, neither of these features points to the limnic setting reported for the Vermillion Creek sequence. The vitrinite reflectance of Vermillion Creek shales is markedly lower than that of the coals and is inversely proportional to the H/C ratio of the shales. Rock-Eval pyrolysis results, analyses of H, C, and N, petrographic observations, isotope composition of organic carbon, and amounts and compositions of the CHCl/sub 3/-extractable organic matter all suggest mixtures of two types of organic matter in the Vermillion Creek coals and clay shales: (1) isotopically heavy, hydrogen-deficient, terrestrial organic matter, as was found in the coals, and (2) isotopically light, hydrogen-rich organic matter similar to that found in one of the clay-shale samples. The different compositions of the Vermillion Creek coal, the unnamed Williams Fork Formation coals, and coals from the Middle Pennsylvanian Marmaton and Cherokee Groups are apparently caused by differences in original plant composition, alteration of organic matter related to different pH conditions of the peat swamps, and slightly different organic maturation levels.

Bostick, N.H.; Hatch, J.R.; Daws, T.A.; Love, A.H.; Lubeck, S.C.M.; Threlkeld, C.N.

1987-01-01T23:59:59.000Z

336

Heavy metal removal and recovery using microorganisms  

SciTech Connect

Microorganisms -- bacteria, fungi, and microalgae -- can accumulate relatively large amounts of toxic heavy metals and radionuclides from the environment. These organisms often exhibit specificity for particular metals. The metal content of microbial biomass can be a substantial fraction of total dry weight with concentration factors (metal in dry biomass to metal in solution) exceeding one million in some cases. Both living and inert (dead) microbial biomass can be used to reduce heavy metal concentrations in contaminated waters to very low levels -- parts per billion and even lower. In many respects (e.g. specificity, residual metal concentrations, accumulation factors, and economics) microbial bioremoval processes can be superior to conventional processes, such as ion exchange and caustic (lime or hydroxide) precipitation for heavy metals removal from waste and contaminated waters. Thus, bioremoval could be developed to contribute to the clean-up of wastes at the Savannah River Site (SRS) and other DOE facilities. However, the potential advantages of bioremoval processes must still be developed into practical operating systems. A detailed review of the literature suggests that appropriate bioremoval processes could be developed for the SRS. There is great variability from one biomass source to another in bioremoval capabilities. Bioremoval is affected by pH, other ions, temperature, and many other factors. The biological (living vs. dead) and physical (immobilized vs. dispersed) characteristics of the biomass also greatly affect metal binding. Even subtle differences in the microbial biomass, such as the conditions under which it was cultivated, can have major effects on heavy metal binding.

Wilde, E.W. (Westinghouse Savannah River Co., Aiken, SC (United States)); Benemann, J.R. (Benemann (J.R.), Pinole, CA (United States))

1991-02-01T23:59:59.000Z

337

Framework for SCADA Security Policy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Framework for SCADA Security Policy Framework for SCADA Security Policy Dominique Kilman Jason Stamp dkilman@sandia.gov jestamp@sandia.gov Sandia National Laboratories Albuquerque, NM 87185-0785 Abstract - Modern automation systems used in infrastruc- ture (including Supervisory Control and Data Acquisition, or SCADA) have myriad security vulnerabilities. Many of these relate directly to inadequate security administration, which precludes truly effective and sustainable security. Adequate security management mandates a clear administrative struc- ture and enforcement hierarchy. The security policy is the root document, with sections covering purpose, scope, posi- tions, responsibilities, references, revision history, enforce- ment, and exceptions for various subjects relevant for system

338

Metagenomic Insights into Evolution of a Heavy Metal-Contaminated Groundwater Microbial Community  

E-Print Network (OSTI)

acetone). Finally, toxic heavy metal stress has resulted inby exporting toxic organics from the cell. (iv) Heavy metalheavy metal ions are relatively simple, typically involving: (a) conversion of the ion to a less toxic

Hemme, Christopher L.

2010-01-01T23:59:59.000Z

339

Human-Centered Fusion Framework  

SciTech Connect

In recent years the benefits of fusing signatures extracted from large amounts of distributed and/or heterogeneous data sources have been largely documented in various problems ranging from biological protein function prediction to cyberspace monitoring. In spite of significant progress in information fusion research, there is still no formal theoretical framework for defining various types of information fusion systems, defining and analyzing relations among such types, and designing information fusion systems using a formal method approach. Consequently, fusion systems are often poorly understood, are less than optimal, and/or do not suit user needs. To start addressing these issues, we outline a formal humancentered fusion framework for reasoning about fusion strategies. Our approach relies on a new taxonomy for fusion strategies, an alternative definition of information fusion in terms of parameterized paths in signature related spaces, an algorithmic formalization of fusion strategies and a library of numeric and dynamic visual tools measuring the impact as well as the impact behavior of fusion strategies. Using a real case of intelligence analysis we demonstrate that the proposed framework enables end users to rapidly 1) develop and implement alternative fusion strategies, 2) understand the impact of each strategy, 3) compare the various strategies, and 4) perform the above steps without having to know the mathematical foundations of the framework. We also demonstrate that the human impact on a fusion system is critical in the sense that small changes in strategies do not necessarily correspond to small changes in results.

Posse, Christian; White, Amanda M.; Beagley, Nathaniel

2007-05-16T23:59:59.000Z

340

UTS Policy Framework: Introduction 11.  

E-Print Network (OSTI)

UTS Policy Framework: user guide Contents Introduction 11. TheroleofpolicywithintheUniversity 12 Policytemplate 64kbWord Directivetemplate 64kbWord Coversheets Coversheet--policies 48kbWord Coversheet--academicpolicies 48kbWord Coversheet--directives 48kbWord Policy Tools PolicyTool1:IssuesLog 60kbWord PolicyTool2

University of Technology, Sydney

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

New approach to the generation of metal-bearing, medium-pore, shape-selective zeolites for Fischer-Tropsch catalysis. Spectroscopic studies of zeolites  

SciTech Connect

Two recent developments in zeolite synthesis and modification were successfully combined to demonstrate a new approach to the generation of metal-bearing, medium-pore, shape-selective zeolites for use as catalysts in Fischer-Tropsch conversions. The steps are: (1) synthesis of an aluminoferrisilicate zeolite having the ZSM-5-type structure; (2) removal of the organic base template incorporated in the channel system during synthesis; (3) formation of a polycyano inclusion compound in the AFS zeolite; and (4) reduction of the inclusion compound by hydrogen at approx. 400/sup 0/C. PAS and EPR spectroscopy have been used to establish that the as-synthesized AFS zeolite contains Fe/sup 3 +/ ions in both framework and non-framework sites. FMR spectroscopy has been used to confirm the formation of the metallic (Fe) and bimetallic (Fe/Ru and Fe/Co) particles as products of the reduction of the inclusion compounds by hydrogen. The application of other spectroscopic techniques in recent studies of cations, complexes, and metal particles in zeolites is reviewed: high-resolution solid-state NMR, nuclear-spin-relaxation studies, FMR, EXAFS, and XANES.

Iton, L.E.; Beal, R.B.; Hodul, D.T.

1983-01-01T23:59:59.000Z

342

Metal-phosphate binders  

DOE Patents (OSTI)

A metal-phosphate binder is provided. The binder may include an aqueous phosphoric acid solution, a metal-cation donor including a metal other than aluminum, an aluminum-cation donor, and a non-carbohydrate electron donor.

Howe, Beth Ann [Lewistown, IL; Chaps-Cabrera, Jesus Guadalupe [Coahuila, MX

2009-05-12T23:59:59.000Z

343

A coupled theory for diffusion of hydrogen and large elastic-plastic deformations of metals  

E-Print Network (OSTI)

A thermodynamically-consistent coupled-theory which accounts for diffusion of hydrogen, trapping of hydrogen, diffusion of heat, and large elastic-plastic deformations of metals is developed. Our theoretical framework ...

Di Leo, Claudio V

2012-01-01T23:59:59.000Z

344

Sewage sludge dewatering using flowing liquid metals  

DOE Patents (OSTI)

A method and apparatus for reducing the moisture content of a moist sewage sludge having a moisture content of about 50% to 80% and formed of small cellular micro-organism bodies having internally confined water is provided. A hot liquid metal is circulated in a circulation loop and the moist sewage sludge is injected in the circulation loop under conditions of temperature and pressure such that the confined water vaporizes and ruptures the cellular bodies. The vapor produced, the dried sludge, and the liquid metal are then separated. Preferably, the moist sewage sludge is injected into the hot liquid metal adjacent the upstream side of a venturi which serves to thoroughly mix the hot liquid metal and the moist sewage sludge. The venturi and the drying zone after the venturi are preferably vertically oriented. The dried sewage sludge recovered is available as a fuel and is preferably used for heating the hot liquid metal.

Carlson, Larry W. (Oswego, IL)

1986-01-01T23:59:59.000Z

345

Microbial transformations of natural organic compounds and radionuclides in subsurface environments  

SciTech Connect

A major national concern in the subsurface disposal of energy wastes is the contamination of ground and surface waters by waste leachates containing radionuclides, toxic metals, and organic compounds. Microorganisms play an important role in the transformation of organic compounds, radionuclides, and toxic metals present in the waste and affect their mobility in subsurface environments. Microbial processes involved in dissolution, mobilization, and immobilization of toxic metals under aerobic and anaerobic conditions are briefly reviewed. Metal complexing agents and several organic acids produced by microbial action affect mobilization of radionuclides and toxic metals in subsurface environments. Information on the persistence of and biodegradation rates of synthetic as well as microbiologically produced complexing agents is scarce but important in determining the mobility of metal organic complexes in subsoils. Several gaps in knowledge in the area of microbial transformation of naturally occurring organics, radionuclides, and toxic metals have been identified, and further basic research has been suggested. 31 refs., 1 fig., 3 tabs.

Francis, A.J.

1985-10-01T23:59:59.000Z

346

Moving towards urban sustainability in Kenya: a framework for integration of environmental, economic, social and governance dimensions  

Science Journals Connector (OSTI)

In the case of slums, weakness resides in all four pillars and results in a downward spiral. Organizations ... improved to restore some balance among the other three pillars by establishing a framework for the so...

Emmanuel Mutisya; Masaru Yarime

2014-04-01T23:59:59.000Z

347

Metal Hydrides - Science Needs  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Storage Grand Challenge Pre-Solicitation Meeting, June 19, 2003 1 Metal Hydrides - Science Needs TRADITIONAL METALLIC HYDRIDES: 1.5 to 2 wt.% H. Well studied. COMPLEX...

348

Probing metal solidification nondestructively  

NLE Websites -- All DOE Office Websites (Extended Search)

Probing metal solidification nondestructively This is the first time that high-energy protons have been used to nondestructively image a large metal sample during melting and...

349

Probing metal solidification nondestructively  

NLE Websites -- All DOE Office Websites (Extended Search)

Probing metal solidification nondestructively This is the first time that high-energy protons have been used to nondestructively image a large metal sample during melting...

350

E-Print Network 3.0 - assess heavy metals Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Submitted to Summary: and organic pollutants that include heavy metals, PAHs, PCBs, dioxins, and furans that have deleterious... environmental effects. For example, sediment...

351

E-Print Network 3.0 - anthropogenic trace metal Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Collection: Geosciences 57 Heavy metal contamination in highway soils. Comparison of Corpus Christi, Texas and Cincinnati, Ohio shows organic matter is key to mobility...

352

Trending: Metal Oxo Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Trending: Metal Oxo Bonds Trending: Metal Oxo Bonds Trending: Metal Oxo Bonds Print Wednesday, 29 May 2013 00:00 Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide variety of important emergent technologies, including industrial catalysis, biomimetic transformations, and artificial photosynthesis. To address this problem, a research team from four national laboratories, three Department of Energy synchrotron user facilities, and the University of Washington has applied spectroscopic and computational analyses to a number of metal oxides, quantifying trends in metal oxo bonding for groups of metals across the periodic table.

353

Demand Response Valuation Frameworks Paper  

E-Print Network (OSTI)

in regions with organized energy markets (day-ahead or real-or bid into day-ahead energy markets then it might gainin capacity and energy markets are significant only in the

Heffner, Grayson

2010-01-01T23:59:59.000Z

354

Process for forming a metal compound coating on a substrate  

DOE Patents (OSTI)

A method of coating a substrate with a thin layer of a metal compound by forming a dispersion of an electrophoretically active organic colloid and a precursor of the metal compound in an electrolytic cell in which the substrate is an electrode. Upon application of an electric potential, the electrode is coated with a mixture of the organic colloid and the precursor to the metal compound, and the coated substrate is then heated in the presence of an atmosphere or vacuum to decompose the organic colloid and form a coating of either a combination of metal compound and carbon, or optionally forming a porous metal compound coating by heating to a temperature high enough to chemically react the carbon.

Sharp, Donald J. (Albuquerque, NM); Vernon, Milton E. (Albuquerque, NM); Wright, Steven A. (Albuquerque, NM)

1991-01-01T23:59:59.000Z

355

Process for forming a metal compound coating on a substrate  

DOE Patents (OSTI)

A method of coating a substrate with a thin layer of a metal compound by forming a dispersion of an electrophoretically active organic colloid and a precursor of the metal compound in an electrolytic cell in which the substrate is an electrode. Upon application of an electric potential, the electrode is coated with a mixture of the organic colloid and the precursor to the metal compound, and the coated substrate is then heated in the presence of an atmosphere or vacuum to decompose the organic colloid and form a coating of either a combination of metal compound and carbon, or optionally forming a porous metal compound coating by heating to a temperature high enough to chemically react the carbon.

Sharp, D.J.; Vernon, M.E.; Wright, S.A.

1988-06-29T23:59:59.000Z

356

Feature identification framework and applications (FIFA)  

E-Print Network (OSTI)

collections that provides a general framework for applications while allowing decisions about the details of document representation and features identification to be deferred to domain specific implementations of that framework. These deferred decisions...

Audenaert, Michael Neal

2006-04-12T23:59:59.000Z

357

A Virtual Environment Framework For Software Engineering  

E-Print Network (OSTI)

A Virtual Environment Framework For Software Engineering Stephen E. Dossick Submitted in partial Environment Framework for Software Engineering Stephen E. Dossick The field of Software Engineering, responsible for mapping project artifacts into virtual environment furnishings, and the CHIME Theme Manager

Kaiser, Gail E.

358

Technology Enhanced Interaction Framework Kewalin Angkananon  

E-Print Network (OSTI)

Technology Enhanced Interaction Framework Kewalin Angkananon ECS University of Southampton interaction framework to help design technology to support communication between people and improve interactions between people, technology and objects, particularly in complex situations. A review of existing

359

Trace analysis of atmospheric organic bases  

E-Print Network (OSTI)

analysis of atmospheric organic bases were investigated; the study included (1) the analysis of submarine charcoal filter bed samples for nitrogen bases and (2) the use of metallic tetraphenylporphines (TPP) as specific adsorbents for atmospheric... gas chromatography (GC) and GC-mass spectrometry (GC-MS). The isolation procedure provided acceptable reproducibi lity in the determination of trace amounts of nitrogen bases in the submarine environment. Several metallic TPP adsorbents were...

Clark, Dwayne C.

2012-06-07T23:59:59.000Z

360

Bottom Up and Country Led: A New Framework for Climate Action | Open Energy  

Open Energy Info (EERE)

Bottom Up and Country Led: A New Framework for Climate Action Bottom Up and Country Led: A New Framework for Climate Action Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Bottom Up and Country Led: A New Framework for Climate Action Agency/Company /Organization: Booz and Company Sector: Energy, Land, Climate Topics: Low emission development planning Resource Type: Publications Website: www.booz.com/global/home/what_we_think/reports_and_white_papers/ic-dis Cost: Free Bottom Up and Country Led: A New Framework for Climate Action Screenshot References: Bottom Up and Country Led: A New Framework for Climate Action[1] "As delegates gather for the Climate Change Conference in Cancun in late 2010, they can benefit from familiarizing themselves with the set of tools available for mitigation and adaptation, as well as how these tools can fit

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Department of Energy Releases Vision & Framework for the U.S. Climate  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Vision & Framework for the U.S. Vision & Framework for the U.S. Climate Change Technology Program Department of Energy Releases Vision & Framework for the U.S. Climate Change Technology Program August 5, 2005 - 2:38pm Addthis WASHINGTON, DC -- In a speech before the Climate Policy Center in Washington, D.C., David Conover, Director of the Department of Energy's Climate Change Technology Program (CCTP), today announced the release of the department's Vision and Framework for Strategy and Planning report on behalf of Secretary of Energy Samuel Bodman. The report provides strategic direction and guidance to the 10 Federal agencies developing new and advanced global climate change technologies. The Vision and Framework document is organized around six complementary goals: (1) reducing emissions from energy use and infrastructure; (2)

362

Shale Gas Development: A Smart Regulation Framework  

Science Journals Connector (OSTI)

Shale Gas Development: A Smart Regulation Framework ... Mandatory reporting of greenhouse gases: Petroleum and natural gas systems; Final rule. ...

Katherine E. Konschnik; Mark K. Boling

2014-02-24T23:59:59.000Z

363

Phase-Transfer Catalysis-Transition Metal Cocatalyzed Reactions  

Science Journals Connector (OSTI)

Transition metals are active catalysts for a variety of organic reactions. Sometimes they are also useful in conjunction with phase-transfer catalysts, particularly when hydroxide anions and other inorganic sp...

Charles M. Starks; Charles L. Liotta; Marc E. Halpern

1994-01-01T23:59:59.000Z

364

A Low Temperature Fully Lithographic Process For Metal–Oxide Field-Effect Transistors  

E-Print Network (OSTI)

We report a low temperature ( ~ 100à °C) lithographic method for fabricating hybrid metal oxide/organic field-effect transistors (FETs) that combine a zinc-indium-oxide (ZIO) semiconductor channel and organic, parylene, ...

Sodini, Charles G.

365

The Offline Software Framework of the Pierre Auger Observatory  

E-Print Network (OSTI)

The Pierre Auger Observatory is designed to unveil the nature and the origins of the highest energy cosmic rays. The large and geographically dispersed collaboration of physicists and the wide-ranging collection of simulation and reconstruction tasks pose some special challenges for the offline analysis software. We have designed and implemented a general purpose framework which allows collaborators to contribute algorithms and sequencing instructions to build up the variety of applications they require. The framework includes machinery to manage these user codes, to organize the abundance of user-contributed configuration files, to facilitate multi-format file handling, and to provide access to event and time-dependent detector information which can reside in various data sources. A number of utilities are also provided, including a novel geometry package which allows manipulation of abstract geometrical objects independent of coordinate system choice. The framework is implemented in C++, and takes advantage of object oriented design and common open source tools, while keeping the user side simple enough for C++ novices to learn in a reasonable time. The distribution system incorporates unit and acceptance testing in order to support rapid development of both the core framework and contributed user code.

S. Argiro; S. L. C. Barroso; J. Gonzalez; L. Nellen; T. Paul; T. A. Porter; L. Prado Jr.; M. Roth; R. Ulrich; D. Veberic

2007-07-11T23:59:59.000Z

366

The Offline Software Framework of the Pierre Auger Observatory  

E-Print Network (OSTI)

The Pierre Auger Observatory is designed to unveil the nature and the origins of the highest energy cosmic rays. The large and geographically dispersed collaboration of physicists and the wide-ranging collection of simulation and reconstruction tasks pose some special challenges for the offline analysis software. We have designed and implemented a general purpose framework which allows collaborators to contribute algorithms and sequencing instructions to build up the variety of applications they require. The framework includes machinery to manage these user codes, to organize the abundance of user-contributed configuration files, to facilitate multi-format file handling, and to provide access to event and time-dependent detector information which can reside in various data sources. A number of utilities are also provided, including a novel geometry package which allows manipulation of abstract geometrical objects independent of coordinate system choice. The framework is implemented in C++, and takes advantage of object oriented design and common open source tools, while keeping the user side simple enough for C++ novices to learn in a reasonable time. The distribution system incorporates unit and acceptance testing in order to support rapid development of both the core framework and contributed user code.

S. Argiro; S. L. C Barroso; J. Gonzalez; L. Nellen; T. Paul; T. A. Porter; L. Prado Jr.; M. Roth; R. Ulrich; D. Veberic

2006-01-01T23:59:59.000Z

367

Ghana-Support for Future National Climate Change Policy Framework | Open  

Open Energy Info (EERE)

Page Page Edit with form History Facebook icon Twitter icon » Ghana-Support for Future National Climate Change Policy Framework Jump to: navigation, search Name CDKN-Ghana-Support for Future National Climate Change Policy Framework Agency/Company /Organization Climate and Development Knowledge Network (CDKN), United Kingdom Department for International Development Partner Energy Research Centre of the Netherlands (ECN), University of Ghana Sector Climate, Energy, Land Topics Background analysis, Low emission development planning, Pathways analysis Website http://cdkn.org/project/assist Program Start 2010 Program End 2011 Country Ghana UN Region Western Africa References CDKN-Ghana-Support for Future National Climate Change Policy Framework[1] Policy brief[2]

368

Framework for Improving Critical Infrastructure Cybersecurity  

E-Print Network (OSTI)

Framework for Improving Critical Infrastructure Cybersecurity Version 1.0 National Institute of Standards and Technology February 12, 2014 #12;February 12, 2014 Cybersecurity Framework Version 1.0 Table............................................................................................................. 20 ii #12;February 12, 2014 Cybersecurity Framework Version 1.0 Executive Summary The national

369

Heavy metal biosensor  

DOE Patents (OSTI)

Compositions and methods are provided for detection of certain heavy metals using bacterial whole cell biosensors.

Hillson, Nathan J; Shapiro, Lucille; Hu, Ping; Andersen, Gary L

2014-04-15T23:59:59.000Z

370

THE COORDINATION CHEMISTRY OF METAL SURFACES  

SciTech Connect

In coordinately unsaturated molecular metal complexes, carbon-hydrogen bonds of the peripheral ligands may, if the stereochemistry allows, closely approach a metal center so as to develop a three-center two-electron bond between the carbon, the hydrogen, and the metal atoms, C-H-M. In some instances, the interaction .is followed by a scission of the C-H bond whereby the metal is effectively oxidized and discrete M-H and M-C {sigma} bonds are forrned. This class of metal-hydrogen-carbon interactions and reactions is shown to be a common phenomenon in metal surface chemistry. Ultra high vacuum studies of nickel and platinum with simple organic molecules like olefins, and arenes are described. These surface chemistry studies were done as a function of surface crystallography and surface composition. The discussion is largely limited to the chemistry of methyl isocyanide, acetonitrile, benzene and toluene. Molecular orbital calculations are presented that support the experimental identification of the importance of C-H-M metal bonding for metal surfaces.

Muetterties, Earl L.

1980-10-01T23:59:59.000Z

371

Using Localized Plasmon Resonances to Enhance Absorption Efficiency in Thin-film Organic Solar Cells  

Science Journals Connector (OSTI)

We propose the use of localized surface plasmon modes excited by square metallic gratings to enhance the optical absorption of thin-film organic solar cells. Broadband absorption...

Le, Khai Q; Abass, Aimi; Maes, Bjorn; Bienstman, Peter; Alu, Andrea

372

Resonant cavity enhanced light harvesting in flexible thin-film organic solar cells  

Science Journals Connector (OSTI)

Dielectric/metal/dielectric (DMD) electrodes have the potential to significantly increase the absorption efficiency and photocurrent in flexible organic solar cells. We demonstrate...

Sergeant, Nicholas P; Niesen, Bjoern; Liu, Albert S; Boman, Lee; Stoessel, Chris; Heremans, Paul; Peumans, Peter; Rand, Barry P; Fan, Shanhui

2013-01-01T23:59:59.000Z

373

The Influence of Residence Time and Organic Acids on the Desorption of Goethite.  

E-Print Network (OSTI)

??The Influence of Residence Time and Organic Acids on the Desorption of Trace Metals from Goethite Leslie James Glover II Committee Chair: M.J. Eick Crop… (more)

Glover II, Leslie James

2000-01-01T23:59:59.000Z

374

Trending: Metal Oxo Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Trending: Metal Oxo Bonds Print Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide variety of important emergent technologies, including industrial catalysis, biomimetic transformations, and artificial photosynthesis. To address this problem, a research team from four national laboratories, three Department of Energy synchrotron user facilities, and the University of Washington has applied spectroscopic and computational analyses to a number of metal oxides, quantifying trends in metal oxo bonding for groups of metals across the periodic table.

375

Trending: Metal Oxo Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Trending: Metal Oxo Bonds Print Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide variety of important emergent technologies, including industrial catalysis, biomimetic transformations, and artificial photosynthesis. To address this problem, a research team from four national laboratories, three Department of Energy synchrotron user facilities, and the University of Washington has applied spectroscopic and computational analyses to a number of metal oxides, quantifying trends in metal oxo bonding for groups of metals across the periodic table.

376

Trending: Metal Oxo Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Trending: Metal Oxo Bonds Print Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide variety of important emergent technologies, including industrial catalysis, biomimetic transformations, and artificial photosynthesis. To address this problem, a research team from four national laboratories, three Department of Energy synchrotron user facilities, and the University of Washington has applied spectroscopic and computational analyses to a number of metal oxides, quantifying trends in metal oxo bonding for groups of metals across the periodic table.

377

Trending: Metal Oxo Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Trending: Metal Oxo Bonds Print Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide variety of important emergent technologies, including industrial catalysis, biomimetic transformations, and artificial photosynthesis. To address this problem, a research team from four national laboratories, three Department of Energy synchrotron user facilities, and the University of Washington has applied spectroscopic and computational analyses to a number of metal oxides, quantifying trends in metal oxo bonding for groups of metals across the periodic table.

378

Method for extracting copper, silver and related metals  

DOE Patents (OSTI)

A process for selectively extracting precious metals such as silver and gold concurrent with copper extraction from aqueous solutions containing the same. The process utilizes tetrathiamacrocycles and high molecular weight organic acids that exhibit a synergistic relationship when complexing with certain metal ions thereby removing them from ore leach solutions.

Moyer, B.A.; McDowell, W.J.

1987-10-23T23:59:59.000Z

379

A Statistical Framework for the Functional Analysis of Metagenomes  

SciTech Connect

Metagenomic studies consider the genetic makeup of microbial communities as a whole, rather than their individual member organisms. The functional and metabolic potential of microbial communities can be analyzed by comparing the relative abundance of gene families in their collective genomic sequences (metagenome) under different conditions. Such comparisons require accurate estimation of gene family frequencies. They present a statistical framework for assessing these frequencies based on the Lander-Waterman theory developed originally for Whole Genome Shotgun (WGS) sequencing projects. They also provide a novel method for assessing the reliability of the estimations which can be used for removing seemingly unreliable measurements. They tested their method on a wide range of datasets, including simulated genomes and real WGS data from sequencing projects of whole genomes. Results suggest that their framework corrects inherent biases in accepted methods and provides a good approximation to the true statistics of gene families in WGS projects.

Sharon, Itai; Pati, Amrita; Markowitz, Victor; Pinter, Ron Y.

2008-10-01T23:59:59.000Z

380

Organics Verification Study for Sinclair and Dyes Inlets, Washington  

SciTech Connect

Sinclair and Dyes Inlets near Bremerton, Washington, are on the State of Washington 1998 303(d) list of impaired waters because of fecal coliform contamination in marine water, metals in sediment and fish tissue, and organics in sediment and fish tissue. Because significant cleanup and source control activities have been conducted in the inlets since the data supporting the 1998 303(d) listings were collected, two verification studies were performed to address the 303(d) segments that were listed for metal and organic contaminants in marine sediment. The Metals Verification Study (MVS) was conducted in 2003; the final report, Metals Verification Study for Sinclair and Dyes Inlets, Washington, was published in March 2004 (Kohn et al. 2004). This report describes the Organics Verification Study that was conducted in 2005. The study approach was similar to the MVS in that many surface sediment samples were screened for the major classes of organic contaminants, and then the screening results and other available data were used to select a subset of samples for quantitative chemical analysis. Because the MVS was designed to obtain representative data on concentrations of contaminants in surface sediment throughout Sinclair Inlet, Dyes Inlet, Port Orchard Passage, and Rich Passage, aliquots of the 160 MVS sediment samples were used in the analysis for the Organics Verification Study. However, unlike metals screening methods, organics screening methods are not specific to individual organic compounds, and are not available for some target organics. Therefore, only the quantitative analytical results were used in the organics verification evaluation. The results of the Organics Verification Study showed that sediment quality outside of Sinclair Inlet is unlikely to be impaired because of organic contaminants. Similar to the results for metals, in Sinclair Inlet, the distribution of residual organic contaminants is generally limited to nearshore areas already within the actively managed Puget Sound Naval Shipyard and Intermediate Maintenance Facility Superfund Site, where further source-control actions and monitoring are under way.

Kohn, Nancy P.; Brandenberger, Jill M.; Niewolny, Laurie A.; Johnston, Robert K.

2006-09-28T23:59:59.000Z

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Synthesis and Properties of Nano Zeolitic Imidazolate Frameworks...  

NLE Websites -- All DOE Office Websites (Extended Search)

Properties of Nano Zeolitic Imidazolate Frameworks. Synthesis and Properties of Nano Zeolitic Imidazolate Frameworks. Abstract: Nano sized zeolitic imidazolate frameworks nZIF-8...

382

Optical design of organic solar cell with hybrid plasmonic system  

Science Journals Connector (OSTI)

We propose a novel optical design of organic solar cell with a hybrid plasmonic system, which comprises a plasmonic cavity coupled with a dielectric core-metal shell nanosphere. From a...

Sha, Wei E I; Choy, Wallace C H; Chen, Yongpin P; Chew, Weng Cho

2011-01-01T23:59:59.000Z

383

New lithium cuprates for the promotion of directed organic transformations  

E-Print Network (OSTI)

The use of bimetallic bases to effect highly stereoselective organic transformations via Directed ortho Metalation (DoM) is an important synthetic tool and requires thorough investigation to maximise efficiency and develop a mechanistic...

Harford, Philip James

2014-10-07T23:59:59.000Z

384

Intermediate connector for stacked organic light emitting devices  

DOE Patents (OSTI)

A device is provided, having an anode, a cathode, and an intermediate connector disposed between the anode and the cathode. A first organic layer including an emissive sublayer is disposed between the anode and the intermediate connector, and a second including an emissive sublayer is disposed between the intermediate connector and the cathode. The intermediate connector includes a first metal having a work function lower than 4.0 eV and a second metal having a work function lower than 5.0 eV. The work function of the first metal is at least 0.5 eV less than the work function of the second metal. The first metal is in contact with a sublayer of the second organic layer that includes a material well adapted to receive holes from a low work function metal.

D'Andrade, Brian

2013-02-12T23:59:59.000Z

385

Emissions of metals, chromium and nickel species, and organics from municipal waste-water-sludge incinerators. Volume 5. Site 7 test report CEMS evaluation. Final report, 1989-91  

SciTech Connect

The U.S. Environmental Protection Agency (EPA) Office of Water Regulations and Standards (OWRS) has recently revised the risk-based sludge regulations under Section 405d of the Clean Water Act. The revised regulations include a provision for monitoring total hydrocarbon (THC) and/or carbon monoxide (CO) emissions as a surrogate for organic emissions measurements. With the assistance of EPA's Risk Reduction Engineering Laboratory (RREL), OWRS has implemented a research program to investigate the relationship of CO and hydrocarbon emissions and the viability of the monitoring systems used to continuously measure these emissions. The test report presents the results obtained at the Site 7 municipal wastewater treatment facility. The CO and THC emission levels showed good agreement during the test program, i.e., increases in CO are accompanied by increases in THC. The actual correlation coefficients ranged from .73-.93 using one-minute averaged data from six test runs. Comparisons of CO and THC values corrected to 7% oxygen levels do not provide the same measure of correlation (r-values from .11 to .83). Possible explanation of the apparent change in agreement is being investigated further. The report presents uncorrected and corrected emission data in both tabular and graphic formats.

Cone, A.L.; Shanklin, S.A.

1992-03-01T23:59:59.000Z

386

Metal-Air Batteries  

SciTech Connect

Metal-air batteries have much higher specific energies than most currently available primary and rechargeable batteries. Recent advances in electrode materials and electrolytes, as well as new designs on metal-air batteries, have attracted intensive effort in recent years, especially in the development of lithium-air batteries. The general principle in metal-air batteries will be reviewed in this chapter. The materials, preparation methods, and performances of metal-air batteries will be discussed. Two main metal-air batteries, Zn-air and Li-air batteries will be discussed in detail. Other type of metal-air batteries will also be described.

Zhang, Jiguang; Bruce, Peter G.; Zhang, Gregory

2011-08-01T23:59:59.000Z

387

LEDS Toolkit and Framework | Open Energy Information  

Open Energy Info (EERE)

LEDS Toolkit and Framework LEDS Toolkit and Framework Jump to: navigation, search Tool Summary LAUNCH TOOL Name: LEDS Toolkit and Methodology Agency/Company /Organization: National Renewable Energy Laboratory Sector: Energy, Land, Water, Climate Topics: Low emission development planning Resource Type: Dataset User Interface: Website, Desktop Application Website: en.openei.org/apps/LEDS/ Cost: Free UN Region: Central Asia, Eastern Asia, South-Eastern Asia, "Pacific" is not in the list of possible values (Eastern Africa, Middle Africa, Northern Africa, Southern Africa, Western Africa, Caribbean, Central America, South America, Northern America, Central Asia, Eastern Asia, Southern Asia, South-Eastern Asia, Western Asia, Eastern Europe, Northern Europe, Southern Europe, Western Europe, Australia and New Zealand, Melanesia, Micronesia, Polynesia, Latin America and the Caribbean) for this property., "Latin America and Caribbean" is not in the list of possible values (Eastern Africa, Middle Africa, Northern Africa, Southern Africa, Western Africa, Caribbean, Central America, South America, Northern America, Central Asia, Eastern Asia, Southern Asia, South-Eastern Asia, Western Asia, Eastern Europe, Northern Europe, Southern Europe, Western Europe, Australia and New Zealand, Melanesia, Micronesia, Polynesia, Latin America and the Caribbean) for this property., "Western Asia & North Africa" is not in the list of possible values (Eastern Africa, Middle Africa, Northern Africa, Southern Africa, Western Africa, Caribbean, Central America, South America, Northern America, Central Asia, Eastern Asia, Southern Asia, South-Eastern Asia, Western Asia, Eastern Europe, Northern Europe, Southern Europe, Western Europe, Australia and New Zealand, Melanesia, Micronesia, Polynesia, Latin America and the Caribbean) for this property., Northern America, "South Asia" is not in the list of possible values (Eastern Africa, Middle Africa, Northern Africa, Southern Africa, Western Africa, Caribbean, Central America, South America, Northern America, Central Asia, Eastern Asia, Southern Asia, South-Eastern Asia, Western Asia, Eastern Europe, Northern Europe, Southern Europe, Western Europe, Australia and New Zealand, Melanesia, Micronesia, Polynesia, Latin America and the Caribbean) for this property., "Sub-Saharan Africa" is not in the list of possible values (Eastern Africa, Middle Africa, Northern Africa, Southern Africa, Western Africa, Caribbean, Central America, South America, Northern America, Central Asia, Eastern Asia, Southern Asia, South-Eastern Asia, Western Asia, Eastern Europe, Northern Europe, Southern Europe, Western Europe, Australia and New Zealand, Melanesia, Micronesia, Polynesia, Latin America and the Caribbean) for this property., "Western & Eastern Europe" is not in the list of possible values (Eastern Africa, Middle Africa, Northern Africa, Southern Africa, Western Africa, Caribbean, Central America, South America, Northern America, Central Asia, Eastern Asia, Southern Asia, South-Eastern Asia, Western Asia, Eastern Europe, Northern Europe, Southern Europe, Western Europe, Australia and New Zealand, Melanesia, Micronesia, Polynesia, Latin America and the Caribbean) for this property.

388

ITL BULLETIN FOR NOVEMBER 2013 ITL RELEASES PRELIMINARY CYBERSECURITY FRAMEWORK  

E-Print Network (OSTI)

ITL BULLETIN FOR NOVEMBER 2013 ITL RELEASES PRELIMINARY CYBERSECURITY FRAMEWORK The Information a Preliminary Cybersecurity Framework for public review and comment. ITL developed the framework based is developing the framework under Executive Order 13636, Improving Critical Infrastructure Cybersecurity, which

389

Synthesis Of Fluorescent Metal Nanoclusters  

NLE Websites -- All DOE Office Websites (Extended Search)

Synthesis Of Fluorescent Metal Nanoclusters Synthesis Of Fluorescent Metal Nanoclusters Fluorescent metal nanoclusters were prepared. Available for thumbnail of Feynman Center...

390

Metal phthalocyanine catalysts  

DOE Patents (OSTI)

As a new composition of matter, alkali metal or ammonium or tetraalkylammonium diazidoperfluorophthalocyanatoferrate. Other embodiments of the invention comprise compositions wherein the metal of the coordination complex is cobalt, manganese and chromium.

Ellis, Jr., Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA)

1994-01-01T23:59:59.000Z

391

Microsoft Word - DOE Framework Final.docx  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Washington, D.C. 20585 Washington, D.C. 20585 Hanford Tank Waste Retrieval, Treatment, and Disposition Framework September 24, 2013 Hanford Tank Waste Retrieval, Treatment, and Disposition Framework ii This page intentionally left blank. Hanford Tank Waste Retrieval, Treatment, and Disposition Framework iii CONTENTS 1. Introduction ............................................................................................................................................. 1 Immobilizing Radioactive Tank Waste at the Office of River Protection .................................................. 1 Current System Design ........................................................................................................................... 2 Addressing Technical Risks and Challenges .......................................................................................... 2

392

Testing of organic acids in engine coolants  

SciTech Connect

The effectiveness of 30 organic acids as inhibitors in engine coolants is reported. Tests include glassware corrosion of coupled and uncoupled metals. FORD galvanostatic and cyclic polarization electrochemistry for aluminum pitting, and reserve alkalinity (RA) measurements. Details of each test are discussed as well as some general conclusions. For example, benzoic acid inhibits coupled metals well but is ineffective on cast iron when uncoupled. In benzoic acid inhibits coupled metals well but is ineffective on cast iron when uncoupled. In general, the organic acids provide little RA when titrated to a pH of 5.5, titration to a pH of 4.5 can result in precipitation of the acid. Trends with respect to acid chain length are reported also.

Weir, T.W. [ARCO Chemical Co., Newtown Square, PA (United States)

1999-08-01T23:59:59.000Z

393

Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons  

DOE Patents (OSTI)

A method of upgrading an oil feedstock by removing heteroatoms and/or one or more heavy metals from the oil feedstock composition. This method reacts the oil feedstock with an alkali metal and an upgradant hydrocarbon. The alkali metal reacts with a portion of the heteroatoms and/or one or more heavy metals to form an inorganic phase separable from the organic oil feedstock material. The upgradant hydrocarbon bonds to the oil feedstock material and increases the number of carbon atoms in the product. This increase in the number of carbon atoms of the product increases the energy value of the resulting oil feedstock.

Gordon, John Howard

2014-09-09T23:59:59.000Z

394

MECS 2006- Fabricated Metals  

Energy.gov (U.S. Department of Energy (DOE))

Manufacturing Energy and Carbon Footprint for Fabricated Metals (NAICS 332) Sector with Total Energy Input, October 2012 (MECS 2006)

395

Site Transition Framework | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

(April 2004) Site Transition Framework More Documents & Publications Process for Transition of Uranium Mill Tailings Radiation Control Act Title II Disposal Sites to the...

396

A Framework for Nonlinear Filtering in MATLAB.  

E-Print Network (OSTI)

?? The object of this thesis is to provide a MATLAB framework for nonlinear filtering in general, and particle filtering in particular. This is done… (more)

Rosén, Jakob

2005-01-01T23:59:59.000Z

397

Energy Sector Cybersecurity Framework Implementation Guidance  

Energy Savers (EERE)

JANUARY 2015 ENERGY SECTOR CYBERSECURITY FRAMEWORK IMPLEMENTATION GUIDANCE U.S. DEPARTMENT OF ENERGY OFFICE OF ELECTRICITY DELIVERY AND ENERGY RELIABILITY Energy Sector...

398

Testing roadmap for generalized agile framework.  

E-Print Network (OSTI)

?? Testing in Agile development frameworks has engaged the concentration of software developers throughout the world. The research regarding this testing is however limited. This… (more)

Chaitanya, Challa

2006-01-01T23:59:59.000Z

399

Draft Energy Sector Cybersecurity Framework Implementation Guidance...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

and Technology (NIST) released a Cybersecurity Framework. DOE has collaborated with private sector stakeholders through the Electricity Subsector Coordinating Council (ESCC)...

400

Gas sensor incorporating a porous framework  

DOE Patents (OSTI)

The disclosure provides sensor for gas sensing including CO.sub.2 gas sensors comprising a porous framework sensing area for binding an analyte gas.

Yaghi, Omar M; Czaja, Alexander U; Wang, Bo; Galatsis, Kosmas; Wang, Kang L; Furukawa, Hiroyasu

2014-05-27T23:59:59.000Z

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Bioenergy Knowledge Discovery Framework Recognized at National...  

Energy Savers (EERE)

Knowledge Discovery Framework (KDF) is bringing together the bioenergy community through Web-based tools, and was presented by Bioenergy KDF team members from Oak Ridge National...

402

A Conceptual Framework for Progressing Towards Sustainability...  

Open Energy Info (EERE)

Progressing Towards Sustainability in the Agriculture and Food Sector Jump to: navigation, search Tool Summary LAUNCH TOOL Name: A Conceptual Framework for Progressing Towards...

403

Deposition of Contiguous Metal Adlayer on Transition Metal Nanostructu...  

NLE Websites -- All DOE Office Websites (Extended Search)

and Abstract Primary Lab Date Application 20100099012 Application 20100099012 Electrocatalyst Synthesized by Depositing a Contiguous Metal Adlayer on Transition Metal...

404

Method for recovering metals from waste  

DOE Patents (OSTI)

A method is described for recovering metals from metals-containing wastes, and vitrifying the remainder of the wastes for disposal. Metals-containing wastes such as circuit boards, cathode ray tubes, vacuum tubes, transistors and so forth, are broken up and placed in a suitable container. The container is heated by microwaves to a first temperature in the range of approximately 300--800 C to combust organic materials in the waste, then heated further to a second temperature in the range of approximately 1,000--1,550 C at which temperature glass formers present in the waste will cause it to melt and vitrify. Low-melting-point metals such as tin and aluminum can be recovered after organics combustion is substantially complete. Metals with higher melting points, such as gold, silver and copper, can be recovered from the solidified product or separated from the waste at their respective melting points. Network former-containing materials can be added at the start of the process to assist vitrification. 2 figs.

Wicks, G.G.; Clark, D.E.; Schulz, R.L.

1998-12-01T23:59:59.000Z

405

Towards an Automatic Metadata Management Framework for Smart Oil Charalampos Chelmis1  

E-Print Network (OSTI)

of the oil exploration process in the oil industry. Our system is capable of annotating models and images. Introduction Oil and gas organizations are in continuous pressure to investigate and employ innovativeTowards an Automatic Metadata Management Framework for Smart Oil Fields Charalampos Chelmis1 , Jing

Prasanna, Viktor K.

406

SERS of molecules that do not adsorb on Ag surfaces: a metalorganic framework-based  

E-Print Network (OSTI)

SERS of molecules that do not adsorb on Ag surfaces: a metal�organic framework, for molecules that weakly adsorb to non-functionalized plasmonic materials, detection by SERS remains a key previously been shown to enhance Raman signals of surface adsorbates by a factor of 107 . Upon exposing

407

In situ tetrazole ligand synthesis leading to a microporous cadmiumorganic framework for selective ion sensingw  

E-Print Network (OSTI)

In situ tetrazole ligand synthesis leading to a microporous cadmium­organic framework for selective published as an Advance Article on the web 28th July 2009 DOI: 10.1039/b907783a In situ tetrazole ligand-methyl-1H-tetrazole)} that exhibits a high-sensitivity sensing function with respect to nitrite in both

Li, Jing

408

Towards a Generic Context-Aware Framework for Self-Adaptation of Service-Oriented Architectures  

E-Print Network (OSTI)

Towards a Generic Context-Aware Framework for Self-Adaptation of Service-Oriented Architectures context-aware frame- work to build self-organizing service-oriented architectures for cloud computing Application (SBA) is a software architecture where the basic element is the service, performing a single

Paris-Sud XI, Université de

409

Lessons Learned in Framework-Based Software Process Improvement Pankaj Jalote  

E-Print Network (OSTI)

frameworks for SPI are the Capability Maturity Model (CMM) for software [18] and ISO9001 [12, 13]. Currently description of an implementation of the CMM in an organization is given in [14]. Though the CMM and ISO have are based on the experience of the author in implementing a CMM-based SPI program in a large software

Jalote, Pankaj

410

Project Information Form Project Title Working toward a policy framework for reducing greenhouse gas  

E-Print Network (OSTI)

Provided (by each agency or organization) US DOT $37,874 Total Project Cost $37,874 Agency ID or ContractProject Information Form Project Title Working toward a policy framework for reducing greenhouse of Research Project This white paper is concerned with a preliminary investigation of the extent to which

California at Davis, University of

411

A Framework to Compare OR Models for Humanitarian Logistics  

Science Journals Connector (OSTI)

Abstract A multitude of OR models – mainly mathematical programs – has been published in relevant journals to support decision-making in the field of humanitarian logistics. Due to the effort that comes with their application, these models are often not adapted by practitioners in humanitarian organizations. Clearly, one part of the effort relates to the comparison process in which the decision-maker has to choose the most appropriate model out of the available OR models. In this contribution, a framework is presented that should help decision-makers in the field of humanitarian logistics to compare available OR models. Three different ways how to compare OR models are introduced: based on the decision they support, based on the decision criteria and metrics they use, and based on their underlying methodology and assumptions. To serve as an illustration, two mathematical programs for the specification of stationary warehouses for relief items are compared with the help of this framework. In the long run, this framework will guide users of a methodological toolkit for humanitarian logistics to the most appropriate OR model for their decision problem. The development of such a methodological toolkit is the overarching goal of this work-in-progress.

Henning Gösling; Jutta Geldermann

2014-01-01T23:59:59.000Z

412

CDKN-Ghana-Support for Future National Climate Change Policy Framework |  

Open Energy Info (EERE)

Support for Future National Climate Change Policy Framework Support for Future National Climate Change Policy Framework Jump to: navigation, search Name CDKN-Ghana-Support for Future National Climate Change Policy Framework Agency/Company /Organization Climate and Development Knowledge Network (CDKN), United Kingdom Department for International Development Partner Energy Research Centre of the Netherlands (ECN), University of Ghana Sector Climate, Energy, Land Topics Background analysis, Low emission development planning, Pathways analysis Website http://cdkn.org/project/assist Program Start 2010 Program End 2011 Country Ghana UN Region Western Africa References CDKN-Ghana-Support for Future National Climate Change Policy Framework[1] Policy brief[2] "CDKN responded to a request by the Government of Ghana to help develop a

413

High Seebeck effects from conducting polymer: Poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) based thin-film device with hybrid metal/polymer/metal architecture  

SciTech Connect

Conductive polymers are of particular interest for thermoelectric applications due to their low thermal conductivity and relatively high electrical conductivity. In this study, commercially available conducting polymer poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) was used in a hybrid metal/polymer/metal thin film design in order to achieve a high Seebeck coefficient with the value of 252lV/k on a relatively low temperature scale. Polymer film thickness was varied in order to investigate its influence on the Seebeck effect. The high Seebeck coefficient indicates that the metal/polymer/metal design can develop a large entropy difference in internal energy of charge carriers between high and low-temperature metal electrodes to develop electrical potential due to charge transport in conducting polymer film through metal/polymer interface. Therefore, the metal/polymer/metal structure presents a new design to combine inorganic metals and organic polymers in thin-film form to develop Seebeck devices

Stanford, Michael G [ORNL; Wang, Hsin [ORNL; Ivanov, Ilia N [ORNL; Hu, Bin [University of Tennessee, Knoxville (UTK)

2012-01-01T23:59:59.000Z

414

Reaction-Forming Method for Producing Near Net-Shape Refractory Metal Carbides  

DOE Patents (OSTI)

A method for reaction forming refractory metal carbides. The method involves the fabrication of a glassy carbon preform by casting an organic, resin-based liquid mixture into a mold and subsequently heat treating it in two steps, which cures and pyrolizes the resin resulting in a porous carbon preform. By varying the amounts of the constituents in the organic, resin-based liquid mixture, control over the density of the carbon preform is obtained. Control of the density and microstructure of the carbon preform allows for determination of the microstructure and properties of the refractory metal carbide material produced. The glassy carbon preform is placed on a bed of refractory metal or refractory metal--silicon alloy. The pieces are heated above the melting point of the metal or alloy. The molten metal wicks inside the porous carbon preform and reacts, forming the refractory metal carbide or refractory metal carbide plus a minor secondary phase.

Palmisiano, Marc N.; Jakubenas, Kevin J.; Baranwal, Rita

2004-07-20T23:59:59.000Z

415

Zn Speciation in the Organic Horizon of a Contaminated Soil by  

E-Print Network (OSTI)

, MS 6-2100, Berkeley, California 94720 Soils that have been acutely contaminated by heavy metals show to metal toxicity (5). Similar organic layers have been reported in many other contaminated sites (6 distinct characteristics, such as colonization by metal-tolerant plant species and topsoil enrichment

416

UNITED NATIONS FRAMEWORK CONVENTION ON CLIMATE CHANGE  

E-Print Network (OSTI)

UNITED NATIONS FRAMEWORK CONVENTION ON CLIMATE CHANGE UNITED NATIONS 1992 FCCC/INFORMAL/84 GE.05-62220 (E) 200705 #12;UNITED NATIONS FRAMEWORK CONVENTION ON CLIMATE CHANGE The Parties to this Convention in predictions of climate change, particularly with regard to the timing, magnitude and regional patterns thereof

Laughlin, Robert B.

417

Cellular Energy Efficiency Evaluation Framework (Invited Paper)  

E-Print Network (OSTI)

Cellular Energy Efficiency Evaluation Framework (Invited Paper) Gunther Auer, Vito Giannini, Istv, the power consumption of the entire system needs to be captured and an appropriate energy efficiency evaluation frameworks are discussed, such that the energy efficiency of the entire network comprising

Stevenson, Paul

418

Extraction process for removing metallic impurities from alkalide metals  

DOE Patents (OSTI)

A development is described for removing metallic impurities from alkali metals by employing an extraction process wherein the metallic impurities are extracted from a molten alkali metal into molten lithium metal due to the immiscibility of the alkali metals in lithium and the miscibility of the metallic contaminants or impurities in the lithium. The purified alkali metal may be readily separated from the contaminant-containing lithium metal by simple decanting due to the differences in densities and melting temperatures of the alkali metals as compared to lithium.

Royer, L.T.

1987-03-20T23:59:59.000Z

419

DOE Hydrogen Analysis Repository: Novel Non-Precious Metal Catalysts  

NLE Websites -- All DOE Office Websites (Extended Search)

Novel Non-Precious Metal Catalysts Novel Non-Precious Metal Catalysts Project Summary Full Title: Novel Non-Precious Metal Catalysts for PEMFC: Catalyst Selection through Molecular Modeling and Durability Studies Project ID: 147 Principal Investigator: Branko Popov Brief Description: The University of South Carolina is synthesizing novel non-precious metal electrocatalysts with similar activity and stability as Pt for oxygen reduction reaction (ORR). Keywords: Catalyst; oxygen reduction; non precious metals; molecular modeling; durability Purpose Develop highly active and stable carbon-based metal-free catalysts and carbon composite catalysts with strong Lewis basicity to facilitate the ORR. Performer Principal Investigator: Branko Popov Organization: University of South Carolina Address: 2C19 Swearingen, Chemical Engineering, 301 Main Street

420

Method and apparatus for the production of metal oxide powder  

DOE Patents (OSTI)

The present invention provides a method for preparing metal oxide powder. A first solution, which is substantially organic, is prepared. A second solution, which is an aqueous solution substantially immiscible in the first solution, is prepared and delivered as drops to the first solution. The drops of the second solution are atomized by a pulsed electric field forming micro-drops of the second solution. Reagents in the first solution diffuse into and react with reactants in the micro-drops of the second solution forming metal hydroxide or oxalate particles. The metal hydroxide or metal oxalate particles are then recovered and dried to produce the metal oxide powder. An apparatus for preparing a metal oxide powder is also disclosed.

Harris, Michael T. (Knoxville, TN); Scott, Timothy C. (Knoxville, TN); Byers, Charles H. (Oak Ridge, TN)

1993-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Method and apparatus for the production of metal oxide powder  

DOE Patents (OSTI)

The present invention provides a method for preparing metal oxide powder. A first solution, which is substantially organic, is prepared. A second solution, which is an aqueous solution substantially immiscible in the first solution, is prepared and delivered as drops to the first solution. The drops of the second solution are atomized by a pulsed electric field forming micro-drops of the second solution. Reagents in the first solution diffuse into and react with reactants in the micro-drops of the second solution forming metal hydroxide or oxalate particles. The metal hydroxide or metal oxalate particles are then recovered and dried to produce the metal oxide powder. An apparatus for preparing a metal oxide powder is also disclosed.

Harris, Michael T. (Knoxville, TN); Scott, Timothy C. (Knoxville, TN); Byers, Charles H. (Oak Ridge, TN)

1992-01-01T23:59:59.000Z

422

Method and apparatus for the production of metal oxide powder  

DOE Patents (OSTI)

The present invention provides a method for preparing metal oxide powder. A first solution, which is substantially organic, is prepared. A second solution, which is an aqueous solution substantially immiscible in the first solution, is prepared and delivered as drops to the first solution. The drops of the second solution are atomized by a pulsed electric field forming micro-drops of the second solution. Reagents in the first solution diffuse into and react with reactants in the micro-drops of the second solution forming metal hydroxide or oxalate particles. The metal hydroxide or metal oxalate particles are then recovered and dried to produce the metal oxide powder. An apparatus for preparing a metal oxide powder is also disclosed. 2 figs.

Harris, M.T.; Scott, T.C.; Byers, C.H.

1992-06-16T23:59:59.000Z

423

Process for the hydrotreatment of heavy hydrocarbons in the presence of reduced metals  

SciTech Connect

A heavy hydrocarbon charge containing sulfur, asphaltenes and/or resins is hydrotreated in the liquid phase at 250/sup 0/-500/sup 0/ C. under a pressure of 20-350 bars in the presence of a catalyst previously obtained by reacting an organic compound of a transition metal with an organic aluminum compound, in a hydrocarbon free of asphaltene and resin. The transition metal organic compound is advantageously an iron, nickel, cobalt, molybdenum, tungsten or vanadium acetylacetonate or carboxylate.

Dinh, C.T.; Desvard, A.; Jacquin, Y.; Martino, G.

1984-03-06T23:59:59.000Z

424

Sumitomo Metal Industries Ltd Sumitomo Metals | Open Energy Information  

Open Energy Info (EERE)

Sumitomo Metal Industries Ltd Sumitomo Metals Sumitomo Metal Industries Ltd Sumitomo Metals Jump to: navigation, search Name Sumitomo Metal Industries Ltd (Sumitomo Metals) Place Osaka-shi, Osaka, Japan Zip 540-0041 Sector Solar Product Engaged in the steel, engineering, and electronics businesses; works on fuel cell component technology and manufactures silicon wafers for the solar sector. References Sumitomo Metal Industries Ltd (Sumitomo Metals)[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Sumitomo Metal Industries Ltd (Sumitomo Metals) is a company located in Osaka-shi, Osaka, Japan . References ↑ "Sumitomo Metal Industries Ltd (Sumitomo Metals)" Retrieved from "http://en.openei.org/w/index.php?title=Sumitomo_Metal_Industries_Ltd_Sumitomo_Metals&oldid=351744"

425

Organic Thin Film Magnet of Nickel-Tetracyanoethylene  

SciTech Connect

Hybrid organic-inorganic materials consisting of a transition metal and an organic compound, TCNE form a unique class of organic magnets denoted by M(TCNE){sub x}(where M = transition metals, and TCNE = tetracyanoethylene). The organic thin film magnet of nickel-tetracyanoethylene, Ni(TCNE){sub x} is deposited on sputtered clean gold substrate using the physical vapor deposition (PVD) technique under ultra high vacuum (UHV) conditions at room temperature. X-ray photoelectron spectroscopy (XPS) has been used to investigate chemical and electronic properties of Ni(TCNE){sub x} film. XPS derived film thickness and stoichiometry are found to be 6 nm and 1:2 ratio between Ni and TCNE resulting Ni(TCNE){sub 2} film, respectively. In addition, XPS results do not show any signature of the presence of pure metallic Ni or Ni-clustering in the Ni(TCNE){sub x} film.

Bhatt, Pramod; Yusuf, S. M. [Solid State Physics Division, Bhabha Atomic Research Centre, Mumbai 400 085 (India)

2011-07-15T23:59:59.000Z

426

STFC Economic Impact Reporting Framework 2009/10 Economic Impact  

E-Print Network (OSTI)

STFC Economic Impact Reporting Framework 2009/10 Economic Impact Reporting Framework 2009/10 #12;STFC Economic Impact Reporting Framework 2009/10 Economic Impact Reporting Framework 2009/10 #12;STFC Economic Impact Reporting Framework 2009/10 1 Contents: Introduction

427

Metal atomization spray nozzle  

DOE Patents (OSTI)

A spray nozzle for a magnetohydrodynamic atomization apparatus has a feed passage for molten metal and a pair of spray electrodes mounted in the feed passage. The electrodes, diverging surfaces which define a nozzle throat and diverge at an acute angle from the throat. Current passes through molten metal when fed through the throat which creates the Lorentz force necessary to provide atomization of the molten metal. 6 figures.

Huxford, T.J.

1993-11-16T23:59:59.000Z

428

ORGANIC CHEMISTRY UCLA Organic Chemistry Faculty  

E-Print Network (OSTI)

ORGANIC CHEMISTRY UCLA Organic Chemistry Faculty perform research in molecular machines, exotic CHEMISTRY FACULTY RESEARCH INTERESTS Anne M. Andrews, Professor-in-Residence: Understanding how areas of interest include cross- coupling reactions, green chemistry, heterocycle synthesis, and natural

Levine, Alex J.

429

Fabricated Metals (2010 MECS)  

Energy.gov (U.S. Department of Energy (DOE))

Manufacturing Energy and Carbon Footprint for Fabricated Metals Sector (NAICS 332) Energy use data source: 2010 EIA MECS (with adjustments) Footprint Last Revised: February 2014

430

EMSL - trace metals  

NLE Websites -- All DOE Office Websites (Extended Search)

trace-metals en Microbial Reductive Transformation of Phyllosilicate Fe(III) and U(VI) in Fluvial Subsurface Sediments. http:www.emsl.pnl.govemslwebpublications...

431

Introducing Metal Atoms to Organic Solar Cell Materials  

E-Print Network (OSTI)

... Advantage! · Light weight! · Flexible! · Printable Disadvantage! · Low power conversion efficiency (PCE)! For Improvement of PCE! Long wavelength absorption! High mobility! Efficient charge separation ó Light h+ e­ #12. et al. Nat. Commun. 2013, 4, 1446. Power conversion efficiency (PCE): 9.2% Ph O OMe Ph O OMe S Hexyl

Katsumoto, Shingo

432

Recent advances in carbon dioxide capture with metal-organic...  

NLE Websites -- All DOE Office Websites (Extended Search)

U. Wang, Hong-Cai Zhou, Greenhouse Gas Sci Technol, 2: 239-259, 2012 DOI: 10.1002ghg.1296 Abstract: Uncontrolled massive release of the primary greenhouse gas carbon...

433

Plasmonic metal nanoparticle enhanced thin film organic solar cells  

Science Journals Connector (OSTI)

A novel plasmonic enhanced OSCs with MNPs located at the interface of PEDOT:PSS anode layer and P3HT:PCBM active layer has been proposed and demonstrated theoretically and...

Qu, Di; Liu, Fang; Huang, Yidong; Xie, Wanlu; Xu, Qi; Aoki, Youichi; Tsujimura, Hiroki; Oku, Yoshiaki

434

Metal oxide/organic interface investigations for photovoltaic devices  

E-Print Network (OSTI)

summarises work I have carried out as a PhD student of the Optoelectronics Group at Cavendish Laboratory of the University of Cambridge since October 2010. I am thankful to the Engineering and Physical Sciences Research Council and the A.G. Leventis... are often used in many other optoelectronic devices such as photovoltaics and light emitting diodes. Sufficiently conducting oxides with the appropriate electron affinities and ionisation potentials, can be employed as charge transport and injection layers...

Pachoumi, Olympia

2014-10-07T23:59:59.000Z

435

Chemistry and Applications of Metal-Organic Materials  

E-Print Network (OSTI)

-Fluorouracil ANG Adsorbed Natural Gas BDC Benzenedicarboxylate BET Brunauer, Emmett and Teller BTC 1,3,5-Benzenetricarboxylate CCS Carbon Capture and Sequestration CNG Compressed Natural Gas DEF Diethyl Formamide DLS Dynamic Light Scattering DMA...-Fluorouracil ANG Adsorbed Natural Gas BDC Benzenedicarboxylate BET Brunauer, Emmett and Teller BTC 1,3,5-Benzenetricarboxylate CCS Carbon Capture and Sequestration CNG Compressed Natural Gas DEF Diethyl Formamide DLS Dynamic Light Scattering DMA...

Zhao, Dan

2012-02-14T23:59:59.000Z

436

Metal Organic Heat Carriers for Enhanced Geothermal Systems  

Energy.gov (U.S. Department of Energy (DOE))

DOE Geothermal Program Peer Review 2010 - Presentation. This project addresses Energy Conversion Barrier N -Inability to lower the temperature conditions under which EGS power generation is commercially viable.

437

Understanding Structure and Bonding of Multilayered Metal-Organic Nanostructures  

E-Print Network (OSTI)

, Victor G. Ruiz, Wissam A. Saidi,§ Tomas Bucko,, Alexandre Tkatchenko, and Egbert Zojer, * Institute

438

Understanding Structure and Bonding of Multilayered Metal–Organic Nanostructures  

Science Journals Connector (OSTI)

David A. Egger †, Victor G. Ruiz ‡, Wissam A. Saidi §, Tomáš Bu?ko ??, Alexandre Tkatchenko ‡, and Egbert Zojer †* ... Wissam A. Saidi ... Wissam A. Saidi ...

David A. Egger; Victor G. Ruiz; Wissam A. Saidi; Tomáš Bu?ko; Alexandre Tkatchenko; Egbert Zojer

2013-01-08T23:59:59.000Z

439

Synthesis models in the VO framework  

E-Print Network (OSTI)

The theory interest group in the International Virtual Observatory Alliance (IVOA) has the goal of ensuring that theoretical data and services are taken into account in the IVOA standards process. In this poster we present some of the efforts carried out by this group to include evolutionary synthesis models in the VO framework. In particular we present the VO tool PGos3, developed by the INAOE (Mexico) and the Spanish Virtual Observatory which includes most of public SSP models in the VO framework (e.g. VOSpec). We also describe the problems related with the inclusion of synthesis models in the VO framework and we try to encourage people to define the way in which synthesis models should be described. This issue has implications not only for the inclusion of synthesis models in the the VO framework but also for a proper usage of synthesis models.

M. Cervino; E. Terlevich; R. Terlevich; C. Rodrigo-Blanco; V. Luridiana; A. Lopez; E. Solano

2007-09-20T23:59:59.000Z

440

A flexible design framework for autonomous mowing  

E-Print Network (OSTI)

This work outlines the creation of a flexible design framework for autonomous mowing to meet changing customer needs and functionality across a spectrum of applications from residential areas to sport complexes. The thesis ...

Kraft, Justin (Justin A.)

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

A global framework for scene gist  

E-Print Network (OSTI)

Human observers are able to rapidly and accurately categorize natural scenes, but the representation mediating this feat is still unknown. Here we propose a framework of rapid scene categorization that does not segment a ...

Greene, Michelle R

2009-01-01T23:59:59.000Z

442

Gas: A Neglected Phase in Remediation of Metals and Radionuclides  

SciTech Connect

The gas phase is generally ignored in remediation of metals and radionuclides because it is assumed that there is no efficient way to exploit it. In the literal sense, all remediations involve the gas phase because this phase is linked to the liquid and solid phases by vapor pressure and thermodynamic relationships. Remediation methods that specifically use the gas phase as a central feature have primarily targeted volatile organic contaminants, not metals and radionuclides. Unlike many organic contaminants, the vapor pressure and Henry's Law constants of metals and radionuclides are not generally conducive to direct air stripping of dissolved contaminants. Nevertheless, the gas phase can play an important role in remediation of inorganic contaminants and provide opportunities for efficient, cost effective remediation. The objective here is to explore ways in which manipulation of the gas phase can be used to facilitate remediation of metals and radionuclides.

Denham, Miles E.; Looney, Brian B

2005-09-28T23:59:59.000Z

443

Silicon metal-semiconductor-metal photodetector  

DOE Patents (OSTI)

Silicon MSM photodiodes sensitive to radiation in the visible to near infrared spectral range are produced by altering the absorption characteristics of crystalline Si by ion implantation. The implantation produces a defected region below the surface of the silicon with the highest concentration of defects at its base which acts to reduce the contribution of charge carriers formed below the defected layer. The charge carriers generated by the radiation in the upper regions of the defected layer are very quickly collected between biased Schottky barrier electrodes which form a metal-semiconductor-metal structure for the photodiode.

Brueck, Steven R. J. (Albuquerque, NM); Myers, David R. (Albuquerque, NM); Sharma, Ashwani K. (Albuquerque, NM)

1997-01-01T23:59:59.000Z

444

Silicon metal-semiconductor-metal photodetector  

DOE Patents (OSTI)

Silicon MSM photodiodes sensitive to radiation in the visible to near infrared spectral range are produced by altering the absorption characteristics of crystalline Si by ion implantation. The implantation produces a defected region below the surface of the silicon with the highest concentration of defects at its base which acts to reduce the contribution of charge carriers formed below the defected layer. The charge carriers generated by the radiation in the upper regions of the defected layer are very quickly collected between biased Schottky barrier electrodes which form a metal-semiconductor-metal structure for the photodiode.

Brueck, Steven R. J. (Albuquerque, NM); Myers, David R. (Albuquerque, NM); Sharma, Ashwani K. (Albuquerque, NM)

1995-01-01T23:59:59.000Z

445

Symmetry reduction of metal phthalocyanines on metals  

Science Journals Connector (OSTI)

The temperature-dependent adsorption behavior of fourfold symmetric metal phthalocyanines (MPcs) on metals with commensurate and incommensurate symmetries was investigated by scanning tunneling microscopy. On the fourfold symmetric Cu(100) surface, planar and fourfold molecular structures in two equivalent orientations were found for MPcs when prepared at room temperature. In addition, two metastable orientations were identified when prepared at low temperature, which can be depopulated upon annealing. MPcs adsorbed on the sixfold symmetric Cu(111) surface showed a disturbed molecular appearance. The symmetry of molecular structures changed from fourfold to twofold, which is discussed in terms of molecule-substrate interaction.

Shih-Hsin Chang; Stefan Kuck; Jens Brede; Leonid Lichtenstein; Germar Hoffmann; Roland Wiesendanger

2008-12-29T23:59:59.000Z

446

PHYTOEXTRACTION OF HEAVY METALS  

E-Print Network (OSTI)

) Type of phytoremediation Cost effective form of environmental remediation (Glass 1999) Chelating Agents: desorb heavy metals from soil matrix and form water-soluble metal complexes (Shen et al -using hyperaccumulator plant biomass to produce a bio-ore for commercial use -Li et al. look at using Ni

Blouin-Demers, Gabriel

447

Metallization of fluid hydrogen  

Science Journals Connector (OSTI)

...P. Tunstall Metallization of fluid hydrogen W. J. Nellis 1 A. A. Louis 2 N...The electrical resistivity of liquid hydrogen has been measured at the high dynamic...which structural changes are paramount. hydrogen|metallization of hydrogen|liquid...

1998-01-01T23:59:59.000Z

448

Electroreflectance in Metals  

Science Journals Connector (OSTI)

Calculations have been made which suggest that the prominent maximum in the electroreflectance spectra of metals observed by Feinleib is not due to modulation of the optical constants of the electrolyte, but to modulation of the optical constants of the metal.

Arnold Prostak and Wilford N. Hansen

1967-08-15T23:59:59.000Z

449

The Organic Rankine Cycle  

Science Journals Connector (OSTI)

Chap. 3 is dedicated to Rankine cycles with organic fluids: the so-called organic Rankine cycles (ORC), which in recent years have ... of the use of...

Costante Mario Invernizzi

2013-01-01T23:59:59.000Z

450

Organization | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Organization Organization The Office of Economic Impact and Diversity is comprised of: The Office of the Director- contact us Office of Minority Business and Economic Development -...

451

INTERPRETING THE RESULTS OF SOIL TESTS FOR HEAVY METALS Vern Grubinger and Don Ross, University of Vermont  

E-Print Network (OSTI)

toxicity of a heavy metal will be affected by soil texture, organic matter, and pH. The health effects1 INTERPRETING THE RESULTS OF SOIL TESTS FOR HEAVY METALS Vern Grubinger and Don Ross, University of Vermont Agricultural soils normally contain low background levels of heavy metals. Contamination from

Hayden, Nancy J.

452

Sedimentation and chronology of heavy metal pollution in Oslo harbor, Norway Aivo Lepland a,*, Thorbjrn J. Andersen b  

E-Print Network (OSTI)

Sedimentation and chronology of heavy metal pollution in Oslo harbor, Norway Aivo Lepland a that pollution by these metals peaked between 1940 and 1970. Dating results indicate that Hg discharges peaked such as heavy metals and organic pollu- tants are typically scavenged by suspended, fine-grained, mineral

Alve, Elisabeth

453

Environmental Pollution (Series B) 9 (1985) 239-254 Heavy Metals in Isopods from the Supra-littoral Zone  

E-Print Network (OSTI)

Environmental Pollution (Series B) 9 (1985) 239-254 Heavy Metals in Isopods from the Supra were very small. The hepatopancreas was the most important storage organ oj'heavy metals and, at all of heavy metals were compared in the tissues oiL. oceanica and in two 'more terrestrial' isopods, Oniscus

Hopkin, Steve

454

Production of magnesium metal  

SciTech Connect

A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention further relates to a process for production of magnesium metal or a magnesium compound where an external source of carbon dioxide is not used in any of the reactions of the process. The invention also relates to the magnesium metal produced by the processes described herein.

Blencoe, James G. (Harriman, TN) [Harriman, TN; Anovitz, Lawrence M. (Knoxville, TN) [Knoxville, TN; Palmer, Donald A. (Oliver Springs, TN) [Oliver Springs, TN; Beard, James S. (Martinsville, VA) [Martinsville, VA

2010-02-23T23:59:59.000Z

455

Deputy Secretary Poneman to Attend International Framework for...  

Office of Environmental Management (EM)

Poneman to Attend International Framework for Nuclear Energy Cooperation Meeting in Jordan Deputy Secretary Poneman to Attend International Framework for Nuclear Energy...

456

Training Framework to Improve the DOE Performance-Based Culture...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Training Framework to Improve the DOE Performance-Based Culture Training Framework to Improve the DOE Performance-Based Culture Guidance Memorandum for implementing the Secretaries...

457

Webcast of the 'Energy 101' Course Framework | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

101 Course Framework."" The Energy 101 framework is part of the Energy 101 initiative, a DOE-led effort to support the creation of a peer reviewed, multidisciplinary,...

458

International Framework for Nuclear Energy Cooperation to Hold...  

Energy Savers (EERE)

Framework for Nuclear Energy Cooperation to Hold Ministerial-Level Meeting Sept. 29 in Warsaw, Poland International Framework for Nuclear Energy Cooperation to Hold...

459

Towards a Framework for National Climate Finance Governance in...  

Open Energy Info (EERE)

Framework for National Climate Finance Governance in Africa Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Towards a Framework for National Climate Finance Governance...

460

Metal-Nonmetal Transition in Metal-Ammonia Solutions  

Science Journals Connector (OSTI)

A review is given of the properties of metal-ammonia solutions together with a summary of the evidence for the existence of a metal-nonmetal transition.

J. C. THOMPSON

1968-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Interaction Between Toxic Metals and Complex Biofilm/Mineral/Solution  

NLE Websites -- All DOE Office Websites (Extended Search)

highlights highlights title by Alexis S. Templeton, Thomas P. Trainor, and Gordon E. Brown, Jr., Stanford University Sorption reactions on particle surfaces can dramatically affect the speciation, cycling and bioavailability of essential micronutrients (i.e. PO43-, Cu, Zn etc.) and toxic metals and metalloids (i.e. Pb, Hg, Se, As) in soils and aquatic environments. Considerable attention has been focused on understanding metal sorption reactions at a molecular/mechanistic level and the effects of metal concentration, pH, ionic strength, and complexing ligands on the ways in which metal ions bind to the surfaces of common mineral phases such as Fe-, Mn- and Al-(hydr)oxides and clays. However, a significant fraction of mineral surfaces in natural environments are extensively colonized by microbial organisms, which can also be potent sorbents for metals due to the large number of reactive functional groups that decorate the cell walls and outer membranes of bacterial surfaces.

462

User satisfaction modeling framework for automotive audio interfaces  

Science Journals Connector (OSTI)

Abstract Currently the research on product satisfaction is evolving to integrate pleasure and delight alongside other, more traditional needs. Pleasure and delight are emotional and hedonic benefits experienced by the user when interacting with the product. Thus, user satisfaction models have to deal with high complexity of product properties that collectively contribute to satisfaction. The formulation of these models has to include not only a proper taxonomy, but also the organization of such properties in categories and their relation to well defined satisfaction dimensions. Successful models would help to find out the most effective technical and design specifications (engineering parameters) that give shape to specific attributes of design, sometimes called “brand feelings”, defined in accordance with the business strategy. The objective of this paper is to present a user satisfaction modeling framework that deals with the complexity of an in-car user interface, namely the audio one. The proposed framework defines three distinct types of product properties: engineering parameters (P), perceived product attributes (A) and satisfaction dimensions (D) and presents a methodology to link the perceived product attributes (A) to satisfaction dimension (D). Relevance to industry Better understanding of the relationships between perceived and formal properties of automotive audio interfaces in order to contribute to better define their technical and design specifications.

José Gaspar; Mihail Fontul; Elsa Henriques; Arlindo Silva

2014-01-01T23:59:59.000Z

463

Assess institutional frameworks for LEDS for land-use sector | Open Energy  

Open Energy Info (EERE)

Assess institutional frameworks for LEDS for land-use sector Assess institutional frameworks for LEDS for land-use sector Jump to: navigation, search Stage 3 LEDS Home Introduction to Framework Assess current country plans, policies, practices, and capacities Develop_BAU Stage 4: Prioritizing and Planning for Actions Begin execution of implementation plans 1.0. Organizing the LEDS Process 1.1. Institutional Structure for LEDS 1.2. Workplan to Develop the LEDS 1.3. Roles and responsibilities to develop LEDS 2.1. Assess current country plans, policies, practices, and capacities 2.2. Compile lessons learned and good practices from ongoing and previous sustainable development efforts in the country 2.3. Assess public and private sector capacity to support initiatives 2.4. Assess and improve the national GHG inventory and other

464

Highlights | Center for Gas SeparationsRelevant to Clean Energy...  

NLE Websites -- All DOE Office Websites (Extended Search)

Link to article Sep 8, 2014 Metal-Organic Frameworks with Precisely Designed Interior for Carbon Dioxide Capture in the Presence of Water Metal-Organic Frameworks with Precisely...

465

Home Page | Center for Gas SeparationsRelevant to Clean Energy...  

NLE Websites -- All DOE Office Websites (Extended Search)

Link to article Sep 8, 2014 Metal-Organic Frameworks with Precisely Designed Interior for Carbon Dioxide Capture in the Presence of Water Metal-Organic Frameworks with Precisely...

466

Transportation Organization and Functions  

Energy.gov (U.S. Department of Energy (DOE))

Office of Packaging and Transportation list of organizations and functions, with a list of acronyms.

467

Liquid metal electric pump  

DOE Patents (OSTI)

An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other. 3 figs.

Abbin, J.P.; Andraka, C.E.; Lukens, L.L.; Moreno, J.B.

1992-01-14T23:59:59.000Z

468

Deformable Organisms and Error Learning for Brain Segmentation  

E-Print Network (OSTI)

Deformable Organisms and Error Learning for Brain Segmentation Gautam Prasad1,2 , Anand A. Joshi3 be easily incorporated into the plan. We validate this framework by creating a plan to locate the brain in 3D magnetic resonance images of the head (skull-stripping). This is important for surgical planning

Boyer, Edmond

469

ANTS: a new Collaborative Learning Framework  

E-Print Network (OSTI)

CSCW and MOO environments have played an important role in CSCL research. These multi-user community-ware frameworks enhance social interactions and shared experience and thus enabling new CSCL research. We however find some limitations in existing platforms: technology limitations and a lack of solid collaborative services. We present ANTS: a collaborative framework that aims to provide a solid foundation for CSCL applications. In one side, the framework is constructed on top of cutting-edge technologies like J2EE (EJB, JSP, Servlets), Notification services (Elvin, JMS) and XML. In the other side, ANTS provides solid CSCW services that make the system robust and extensible. We also present a concrete ANTS extension: JLE, a collaborative learning environment including services like course management, assessment management, collaboration, progress tracking and tutorware.

Pedro García Lopez; Robert Rallo Moya; Merce Gisbert; Antonio Gómez Skarmeta

470

Knowledge Encapsulation Framework for Collaborative Social Modeling  

SciTech Connect

This paper describes the Knowledge Encapsulation Framework (KEF), a suite of tools to enable knowledge inputs (relevant, domain-specific facts) to modeling and simulation projects, as well as other domains that require effective collaborative workspaces for knowledge-based task. This framework can be used to capture evidence (e.g., trusted material such as journal articles and government reports), discover new evidence (covering both trusted and social media), enable discussions surrounding domain-specific topics and provide automatically generated semantic annotations for improved corpus investigation. The current KEF implementation is presented within a wiki environment, providing a simple but powerful collaborative space for team members to review, annotate, discuss and align evidence with their modeling frameworks. The novelty in this approach lies in the combination of automatically tagged and user-vetted resources, which increases user trust in the environment, leading to ease of adoption for the collaborative environment.

Cowell, Andrew J.; Gregory, Michelle L.; Marshall, Eric J.; McGrath, Liam R.

2009-03-24T23:59:59.000Z

471

Multichannel framework for singular quantum mechanics  

SciTech Connect

A multichannel S-matrix framework for singular quantum mechanics (SQM) subsumes the renormalization and self-adjoint extension methods and resolves its boundary-condition ambiguities. In addition to the standard channel accessible to a distant (“asymptotic”) observer, one supplementary channel opens up at each coordinate singularity, where local outgoing and ingoing singularity waves coexist. The channels are linked by a fully unitary S-matrix, which governs all possible scenarios, including cases with an apparent nonunitary behavior as viewed from asymptotic distances. -- Highlights: •A multichannel framework is proposed for singular quantum mechanics and analogues. •The framework unifies several established approaches for singular potentials. •Singular points are treated as new scattering channels. •Nonunitary asymptotic behavior is subsumed in a unitary multichannel S-matrix. •Conformal quantum mechanics and the inverse quartic potential are highlighted.

Camblong, Horacio E., E-mail: camblong@usfca.edu [Department of Physics and Astronomy, University of San Francisco, San Francisco, CA 94117-1080 (United States); Epele, Luis N., E-mail: epele@fisica.unlp.edu.ar [Laboratorio de Física Teórica, Departamento de Física, IFLP, CONICET, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, C.C. 67–1900 La Plata (Argentina); Fanchiotti, Huner, E-mail: huner@fisica.unlp.edu.ar [Laboratorio de Física Teórica, Departamento de Física, IFLP, CONICET, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, C.C. 67–1900 La Plata (Argentina)] [Laboratorio de Física Teórica, Departamento de Física, IFLP, CONICET, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, C.C. 67–1900 La Plata (Argentina); García Canal, Carlos A., E-mail: garcia@fisica.unlp.edu.ar [Laboratorio de Física Teórica, Departamento de Física, IFLP, CONICET, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, C.C. 67–1900 La Plata (Argentina); Ordóñez, Carlos R., E-mail: ordonez@uh.edu [Department of Physics, University of Houston, Houston, TX 77204-5506 (United States)

2014-01-15T23:59:59.000Z

472

Divalent metal nanoparticles  

E-Print Network (OSTI)

Metal nanoparticles hold promise for many scientific and technological applications, such as chemical and biological sensors, vehicles for drug delivery, and subdiffraction limit waveguides. To fabricate such devices, a ...

DeVries, Gretchen Anne

2008-01-01T23:59:59.000Z

473

Nitrided Metallic Bipolar Plates  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

to meet 5000 h automotive durability goal at cost < 5kW Year 1 Goals: Single-cell fuel cell test performance for 25 cm 2 stamped and nitrided metallic bipolar plates...

474

Metal stocks and sustainability  

Science Journals Connector (OSTI)

...dissipated through corrosion and wear, and some enters waste repositories...landfills. Dissipation from wear and corrosion is generally small...dispersion of metals from wear and corrosion is an important...transportation (railroad, marine, aircraft, and aerospace equipment...

R. B. Gordon; M. Bertram; T. E. Graedel

2006-01-01T23:59:59.000Z

475

Oligocyclopentadienyl transition metal complexes  

SciTech Connect

Synthesis, characterization, and reactivity studies of oligocyclopentadienyl transition metal complexes, namely those of fulvalene, tercyclopentadienyl, quatercyclopentadienyl, and pentacyclopentadienyl(cyclopentadienyl) are the subject of this account. Thermal-, photo-, and redox chemistries of homo- and heteropolynuclear complexes are described.

de Azevedo, Cristina G.; Vollhardt, K. Peter C.

2002-01-18T23:59:59.000Z

476

Excitons in Metals  

Science Journals Connector (OSTI)

It is shown that exciton states exist in metals, occurring near the interband threshold in optical absorption and substantially altering the shape and strength of the absorption edge. Their relation to the corresponding donor states is discussed.

G. D. Mahan

1967-03-20T23:59:59.000Z

477

Lithium metal reduction of plutonium oxide to produce plutonium metal  

DOE Patents (OSTI)

A method is described for the chemical reduction of plutonium oxides to plutonium metal by the use of pure lithium metal. Lithium metal is used to reduce plutonium oxide to alpha plutonium metal (alpha-Pu). The lithium oxide by-product is reclaimed by sublimation and converted to the chloride salt, and after electrolysis, is removed as lithium metal. Zinc may be used as a solvent metal to improve thermodynamics of the reduction reaction at lower temperatures. Lithium metal reduction enables plutonium oxide reduction without the production of huge quantities of CaO--CaCl.sub.2 residues normally produced in conventional direct oxide reduction processes.

Coops, Melvin S. (Livermore, CA)

1992-01-01T23:59:59.000Z

478

Metallic glass composition  

DOE Patents (OSTI)

A metallic glass alloy that is either iron-based or nickel-based or based on a mixture of iron and nickel, containing lesser amounts of elements selected from the group boron, silicon carbon and phosphorous to which is added an amount of a ductility enhancing element selected from the group cerium, lanthanum, praseodymium and neodymium sufficient to increase ductility of the metallic glass upon annealing.

Kroeger, Donald M. (Knoxville, TN); Koch, Carl C. (Raleigh, NC)

1986-01-01T23:59:59.000Z

479

Molten metal reactors  

DOE Patents (OSTI)

A molten metal reactor for converting a carbon material and steam into a gas comprising hydrogen, carbon monoxide, and carbon dioxide is disclosed. The reactor includes an interior crucible having a portion contained within an exterior crucible. The interior crucible includes an inlet and an outlet; the outlet leads to the exterior crucible and may comprise a diffuser. The exterior crucible may contain a molten alkaline metal compound. Contained between the exterior crucible and the interior crucible is at least one baffle.

Bingham, Dennis N; Klingler, Kerry M; Turner, Terry D; Wilding, Bruce M

2013-11-05T23:59:59.000Z

480

Building Technologies Office: Residential Furnaces and Boilers Framework  

NLE Websites -- All DOE Office Websites (Extended Search)

Residential Furnaces Residential Furnaces and Boilers Framework Meeting to someone by E-mail Share Building Technologies Office: Residential Furnaces and Boilers Framework Meeting on Facebook Tweet about Building Technologies Office: Residential Furnaces and Boilers Framework Meeting on Twitter Bookmark Building Technologies Office: Residential Furnaces and Boilers Framework Meeting on Google Bookmark Building Technologies Office: Residential Furnaces and Boilers Framework Meeting on Delicious Rank Building Technologies Office: Residential Furnaces and Boilers Framework Meeting on Digg Find More places to share Building Technologies Office: Residential Furnaces and Boilers Framework Meeting on AddThis.com... About Standards & Test Procedures Implementation, Certification & Enforcement

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Functionalized Silicone Nanospheres: Synthesis, Transition Metal...  

NLE Websites -- All DOE Office Websites (Extended Search)

Functionalized Silicone Nanospheres: Synthesis, Transition Metal Immobilization, and Catalytic Applications. Functionalized Silicone Nanospheres: Synthesis, Transition Metal...

482

Metal-oxide-based energetic materials and synthesis thereof  

DOE Patents (OSTI)

A method of preparing energetic metal-oxide-based energetic materials using sol-gel chemistry has been invented. The wet chemical sol-gel processing provides an improvement in both safety and performance. Essentially, a metal-oxide oxidizer skeletal structure is prepared from hydrolyzable metals (metal salts or metal alkoxides) with fuel added to the sol prior to gelation or synthesized within the porosity metal-oxide gel matrix. With metal salt precursors a proton scavenger is used to destabilize the sol and induce gelation. With metal alkoxide precursors standard well-known sol-gel hydrolysis and condensation reactions are used. Drying is done by standard sol-gel practices, either by a slow evaporation of the liquid residing within the pores to produce a high density solid nanocomposite, or by supercritical extraction to produce a lower density, high porous nanocomposite. Other ingredients may be added to this basic nanostructure to change physical and chemical properties, which include organic constituents for binders or gas generators during reactions, burn rate modifiers, or spectral emitters.

Tillotson, Thomas M. (Tracy, CA), Simpson; Randall L. (Livermore, CA); Hrubesh, Lawrence W. (Pleasanton, CA)

2006-01-17T23:59:59.000Z

483

Stability of metallic thin film with free electron model  

SciTech Connect

The stability of metallic thin lms is studied with free electron model, which is popularly known as model of \\particle in a box". A detailed theoretical framework is presented, along with discussion on typical metals, such as Pb, Al, Ag, Na, and Be. This simple model is found to be able to describe well the oscillation pattern of stability for continuous metallic lms. In particular, it yields even-odd oscillations in the stability of Pb(111) lm, consistent with both experimental observation and ab initio results. However, the free electron model is too crude to predict at what thickness the lm is stable. The lm stability is further examined with a model of \\particle in a corrugated box", where a lattice potential is added along the vertical direction of the lm. The e ect of lattice potential is found not substantial.

Wu, Biao [ORNL; Zhang, Zhenyu [ORNL

2008-01-01T23:59:59.000Z

484

Very metal poor Classical Cepheids: variables in IZw18  

E-Print Network (OSTI)

In the framework of an ongoing ACS@HST project (HST program #10586, PI: Aloisi) we have obtained deep multi-color imaging of the very metal-poor Blue Compact Dwarf galaxy IZw18. The data were acquired in time-series fashion to allow the identification of Classical Cepheids (CCs). The main aim of this project is to constrain both the distance and the Star Formation History of the galaxy. However, as a byproduct these data also provide new insights into the properties of CCs at very low metallicities. We have identified 24 candidate CCs in IZw18. New theoretical pulsation models of CCs specifically for the low metallicity of this primordial galaxy (Z=0.0004, Y=0.24) have been computed to interpret our results.

G. Fiorentino; M. Marconi; G. Clementini; I. Musella; A. Aloisi; F. Annibali; R. A. Contreras; M. Tosi

2007-03-27T23:59:59.000Z

485

Mixed crystal organic scintillators  

DOE Patents (OSTI)

A mixed organic crystal according to one embodiment includes a single mixed crystal having two compounds with different bandgap energies, the organic crystal having a physical property of exhibiting a signal response signature for neutrons from a radioactive source, wherein the signal response signature does not include a significantly-delayed luminescence characteristic of neutrons interacting with the organic crystal relative to a luminescence characteristic of gamma rays interacting with the organic crystal. According to one embodiment, an organic crystal includes bibenzyl and stilbene or a stilbene derivative, the organic crystal having a physical property of exhibiting a signal response signature for neutrons from a radioactive source.

Zaitseva, Natalia P; Carman, M Leslie; Glenn, Andrew M; Hamel, Sebastien; Hatarik, Robert; Payne, Stephen A; Stoeffl, Wolfgang

2014-09-16T23:59:59.000Z

486

In-situ x-ray diffraction studies of host-guest properties in nanoporous zinc-triazolate-based framework materials.  

SciTech Connect

Two nanoporous metal-organic framework materials incorporating the exotridentate bridging ligand 3-amino-1,2,4-triazolate (AmTAZ) have been synthesized through variation of secondary bridging anions: [Zn{sub 3}(AmTAZ){sub 3}S](NO{sub 3}) {center_dot} (H{sub 2}O) (1 {center_dot} (H{sub 2}O)) and Zn{sub 7}(AmTAZ){sub 8}(CO{sub 3}){sub 2}(OH){sub 2} {center_dot} 2(EtOH) (2 {center_dot} 2(EtOH); EtOH = ethanol). 1 {center_dot} (H{sub 2}O) crystallizes in the cubic space group I23 and is constructed from triangular Zn{sub 3}S units that are bridged through AmTAZ ligands into a cationic three-dimensional (3D) network with nitrate and water molecules residing in the cavities. 2 {center_dot} 2(EtOH) crystallizes in the monoclinic space group C2/c and shows a complex 3D network constructed from seven crystallographically unique zinc centers bridged by AmTAZ, carbonate, and hydroxide anions. The porous nature of both materials has been explored by thermogravimetric analysis, nitrogen sorption, and in situ synchrotron-based powder X-ray diffraction.

Halder, G. J.; Park, H.; Funk, R. J.; Chapman, K. W.; Engerer, L. K.; Geiser, U.; Schlueter, J. A.

2009-08-01T23:59:59.000Z

487

Enterprise Information Security Management Framework [EISMF  

E-Print Network (OSTI)

There are several technological solutions available in the market to help organizations with information security breach detection and prevention such as intrusion detection and prevention systems, antivirus software, ...

Sharma, Dhirendra, S.M. Massachusetts Institute of Technology

2011-01-01T23:59:59.000Z

488

A framework for nonparametric profile monitoring  

Science Journals Connector (OSTI)

Control charts have been widely used for monitoring the functional relationship between a response variable and some explanatory variable(s) (called profile) in various industrial applications. In this article, we propose an easy-to-implement framework ... Keywords: B-spline, Block bootstrap, Confidence band, Curve depth, Nonparametric profile monitoring

Shih-Chung Chuang; Ying-Chao Hung; Wen-Chi Tsai; Su-Fen Yang

2013-01-01T23:59:59.000Z

489

RESEARCH Open Access Probabilistic framework for opportunistic  

E-Print Network (OSTI)

approaches. Keywords: Cognitive radio networks, Opportunistic spectrum management, Medium access control 1 that the licensed spectrum is underutilized for 15 to 85% of the time depending on the spatial location [1]. ThusRESEARCH Open Access Probabilistic framework for opportunistic spectrum management in cognitive ad

Perkins, Dmitri

490

CSE394: Security Policy Frameworks Scott Stoller  

E-Print Network (OSTI)

, and it can provide good practice in public speaking. Printouts of final versions of all documents (i.eCSE394: Security Policy Frameworks Scott Stoller Project. Version: 18oct2005a. An initial proposal project. I will provide feedback on the proposals (on the topic and the size of the project) within a week

Stoller, Scott

491

Flexible Framework for Building Energy Analysis: Preprint  

SciTech Connect

In the building energy research and advanced practitioner communities, building models are perturbed across large parameter spaces to assess energy and cost performance in the face of programmatic and economic constraints. This paper describes the OpenStudio software framework for performing such analyses.

Hale, E.; Macumber, D.; Weaver, E.; Shekhar, D.

2012-09-01T23:59:59.000Z

492

Free Parameters and Frameworks in Minimal Supersymmetry  

E-Print Network (OSTI)

405 Appendix A Free Parameters and Frameworks in Minimal Supersymmetry It is useful to discuss what the various schemes that exist for reducing the set of free parameters to a manageable number. The information, and so is fixed by experiment. The free parameters consist mainly of the coe#cients of the ``soft

California at Berkeley, University of

493

Free Parameters and Frameworks in Minimal Supersymmetry  

E-Print Network (OSTI)

405 Appendix A Free Parameters and Frameworks in Minimal Supersymmetry It is useful to discuss what the various schemes that exist for reducing the set of free parameters to a manageable number. The information, and so is fixed by experiment. The free parameters consist mainly of the coefficients of the "soft

California at Berkeley, University of

494

APPLYING THE ZACHMAN FRAMEWORK DIMENSIONS TO SUPPORT  

E-Print Network (OSTI)

APPLYING THE ZACHMAN FRAMEWORK DIMENSIONS TO SUPPORT BUSINESS PROCESS MODELING Pedro Sousa123.caetano, jose.tribolet}@inov.pt Business process models assist business and information technology managers with disparate blueprints for the same process and no formal procedures to sort out their relevance. In fact

495

A Homogenized Energy Framework for Ferromagnetic Hysteresis  

E-Print Network (OSTI)

energy relations at the mesoscopic or lattice level based on the assumption that magnetic momentsA Homogenized Energy Framework for Ferromagnetic Hysteresis Ralph C. Smith Marcelo J. Dapino Center or spins are restricted to two orientations. Direct minimization of the Gibbs energy yields local average

496

Alignment vs N framework for active matter  

E-Print Network (OSTI)

/Coffee at 11:15 AM) Seminar Hall, TCIS trivial Commission for Atomic Energy and Alternative propelled particlesAlignment vs N framework for active matter and collective motion Commission for Atomic Energy and Alternative Energies (CEA), Franc The collective properties of self interacting solely via some kind

Shyamasundar, R.K.

497

A Statistical Framework for Spatial Comparative Genomics  

E-Print Network (OSTI)

A Statistical Framework for Spatial Comparative Genomics Rose Hoberman May 2007 CMU-CS-07, or the U.S. Government. #12;Keywords: spatial comparative genomics, comparative genomics, gene clusters, max-gap clusters, gene teams, whole genome duplication, paralogons, synteny, ortholog detection #12

498

Liquid metal thermal electric converter  

DOE Patents (OSTI)

A liquid metal thermal electric converter which converts heat energy to electrical energy. The design of the liquid metal thermal electric converter incorporates a unique configuration which directs the metal fluid pressure to the outside of the tube which results in the structural loads in the tube to be compressive. A liquid metal thermal electric converter refluxing boiler with series connection of tubes and a multiple cell liquid metal thermal electric converter are also provided.

Abbin, Joseph P. (Albuquerque, NM); Andraka, Charles E. (Albuquerque, NM); Lukens, Laurance L. (Albuquerque, NM); Moreno, James B. (Albuquerque, NM)

1989-01-01T23:59:59.000Z

499

trace metals | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

decreased in incubated Hanford sediments with the rate and extent being greater in sediment amended with organic carbon. X-ray absorption spectroscopy of bioreduced sediments...

500

Crystalline Nanoporous Frameworks: a Nanolaboratory for Probing Excitonic Device Concepts.  

SciTech Connect

Electro-optical organic materials hold great promise for the development of high-efficiency devices based on exciton formation and dissociation, such as organic photovoltaics (OPV) and organic light-emitting devices (OLEDs). However, the external quantum efficiency (EQE) of both OPV and OLEDs must be improved to make these technologies economical. Efficiency rolloff in OLEDs and inability to control morphology at key OPV interfaces both reduce EQE. Only by creating materials that allow manipulation and control of the intimate assembly and communication between various nanoscale excitonic components can we hope to first understand and then engineer the system to allow these materials to reach their potential. The aims of this proposal are to: 1) develop a paradigm-changing platform for probing excitonic processes composed of Crystalline Nanoporous Frameworks (CNFs) infiltrated with secondary materials (such as a complimentary semiconductor); 2) use them to probe fundamental aspects of excitonic processes; and 3) create prototype OPVs and OLEDs using infiltrated CNF as active device components. These functional platforms will allow detailed control of key interactions at the nanoscale, overcoming the disorder and limited synthetic control inherent in conventional organic materials. CNFs are revolutionary inorganic-organic hybrid materials boasting unmatched synthetic flexibility that allow tuning of chemical, geometric, electrical, and light absorption/generation properties. For example, bandgap engineering is feasible and polyaromatic linkers provide tunable photon antennae; rigid 1-5 nm pores provide an oriented, intimate host for triplet emitters (to improve light emission in OLEDs) or secondary semiconducting polymers (creating a charge-separation interface in OPV). These atomically engineered, ordered structures will enable critical fundamental questions to be answered concerning charge transport, nanoscale interfaces, and exciton behavior that are inaccessible in disordered systems. Implementing this concept also creates entirely new dimensions for device fabrication that could both improve performance, increase durability, and reduce costs with unprecedented control of over properties. This report summarizes the key results of this project and is divided into sections based on publications that resulted from the work. We begin in Section 2 with an investigation of light harvesting and energy transfer in a MOF infiltrated with donor and acceptor molecules of the type typically used in OPV devices (thiophenes and fullerenes, respectively). The results show that MOFs can provide multiple functions: as a light harvester, as a stabilizer and organizer or the infiltrated molecules, and as a facilitator of energy transfer. Section 3 describes computational design of MOF linker groups to accomplish light harvesting in the visible and facilitate charge separation and transport. The predictions were validated by UV-visible absorption spectroscopy, demonstrating that rational design of MOFs for light-harvesting purposes is feasible. Section 4 extends the infiltration concept discussed in Section to, which we now designate as %22Molecule%40MOF%22 to create an electrically conducting framework. The tailorability and high conductivity of this material are unprecedented, meriting publication in the journal Science and spawning several Technical Advances. Section 5 discusses processes we developed for depositing MOFs as thin films on substrates, a critical enabling technology for fabricating MOF-based electronic devices. Finally, in Section 6 we summarize results showing that a MOF thin film can be used as a sensitizer in a DSSC, demonstrating that MOFs can serve as active layers in excitonic devices. Overall, this project provides several crucial proofs-of- concept that the potential of MOFs for use in optoelectronic devices that we predicted several years ago [ 3 ] can be realized in practice.

Allendorf, Mark D.; Azoulay, Jason; Ford, Alexandra Caroline [Sandia National Laboratories, Albuquerque, NM; Foster, Michael E.; El Gabaly Marquez, Farid; Leonard, Francois Leonard; Leong-Hau, Kirsty; Stavila, Vitalie; Talin, Albert Alec; Wong, Brian M.; Brumbach, Michael T. [Sandia National Laboratories, Albuquerque, NM; Van Gough, D.; Lambert, Timothy N. [Sandia National Laboratories, Albuquerque, NM; Rodriguez, Mark A. [Sandia National Laboratories, Albuquerque, NM; Spoerke, Erik David [Sandia National Laboratories, Albuquerque, NM; Wheeler, David R. [Sandia National Laboratories, Albuquerque, NM; Deaton, Joseph C.; Centrone, Andrea; Haney, Paul; Kinney, R.; Szalai, Veronika; Yoon, Heayoung P.

2014-09-01T23:59:59.000Z