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they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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1

Gas adsorption on metal-organic frameworks  

SciTech Connect

The present invention involves the use of certain metal organic frameworks that have been treated with water or another metal titrant in the storage of carbon dioxide. The capacity of these frameworks is significantly increased through this treatment.

Willis, Richard R. (Cary, IL); Low, John J. (Schaumburg, IL), Faheem, Syed A. (Huntley, IL); Benin, Annabelle I. (Oak Forest, IL); Snurr, Randall Q. (Evanston, IL); Yazaydin, Ahmet Ozgur (Evanston, IL)

2012-07-24T23:59:59.000Z

2

Metal Organic Frameworks for Clean Energy Applications  

Science Conference Proceedings (OSTI)

Symposium, Materials Issues in Nuclear Waste Management in the 21st Century. Presentation Title, Metal Organic Frameworks for Clean Energy Applications.

3

Metal Organic Framework Research: High Throughput Discovery of Robust Metal Organic Framework for CO2 Capture  

Science Conference Proceedings (OSTI)

IMPACCT Project: LBNL is developing a method for identifying the best metal organic frameworks for use in capturing CO2 from the flue gas of coal-fired power plants. Metal organic frameworks are porous, crystalline compounds that, based on their chemical structure, vary considerably in terms of their capacity to grab hold of passing CO2 molecules and their ability to withstand the harsh conditions found in the gas exhaust of coal-fired power plants. Owing primarily to their high tunability, metal organic frameworks can have an incredibly wide range of different chemical and physical properties, so identifying the best to use for CO2 capture and storage can be a difficult task. LBNL uses high-throughput instrumentation to analyze nearly 100 materials at a time, screening them for the characteristics that optimize their ability to selectively adsorb CO2 from coal exhaust. Their work will identify the most promising frameworks and accelerate their large-scale commercial development to benefit further research into reducing the cost of CO2 capture and storage.

None

2010-08-01T23:59:59.000Z

4

Hydrogen Storage in Metal-Organic Frameworks  

DOE Green Energy (OSTI)

Conventional storage of large amounts of hydrogen in its molecular form is difficult and expensive because it requires employing either extremely high pressure gas or very low temperature liquid. Because of the importance of hydrogen as a fuel, the DOE has set system targets for hydrogen storage of gravimetric (5.5 wt%) and volumetric (40 g L-1) densities to be achieved by 2015. Given that these are system goals, a practical material will need to have higher capacity when the weight of the tank and associated cooling or regeneration system is considered. The size and weight of these components will vary substantially depending on whether the material operates by a chemisorption or physisorption mechanism. In the latter case, metal-organic frameworks (MOFs) have recently been identified as promising adsorbents for hydrogen storage, although little data is available for their sorption behavior. This grant was focused on the study of MOFs with these specific objectives. (1) To examine the effects of functionalization, catenation, and variation of the metal oxide and organic linkers on the low-pressure hydrogen adsorption properties of MOFs. (2) To develop a strategy for producing MOFs with high surface area and porosity to reduce the dead space and increase the hydrogen storage capacity per unit volume. (3) To functionalize MOFs by post synthetic functionalization with metals to improve the adsorption enthalpy of hydrogen for the room temperature hydrogen storage. This effort demonstrated the importance of open metal sites to improve the adsorption enthalpy by the systematic study, and this is also the origin of the new strategy, which termed isoreticular functionalization and metalation. However, a large pore volume is still a prerequisite feature. Based on our principle to design highly porous MOFs, guest-free MOFs with ultrahigh porosity have been experimentally synthesized. MOF-210, whose BET surface area is 6240 m2 g-1 (the highest among porous solids), takes up 15 wt% of total H2 uptake at 80 bar and 77 K. More importantly, the total H2 uptake by MOF-210 was 2.7 wt% at 80 bar and 298 K, which is the highest number reported for physisorptive materials.

Omar M. Yaghi

2012-04-26T23:59:59.000Z

5

Recent advances as materials of functional metal-organic frameworks  

Science Conference Proceedings (OSTI)

Metal-organic frameworks (MOFs), also known as hybrid inorganic-organic materials, represent an emerging class of materials that have attracted the imagination of solid-state chemists because MOFs combine unprecedented levels of porosity with a range ...

Xiao-Lan Tong, Hai-Lu Lin, Jian-Hua Xin, Fen Liu, Min Li, Xia-Ping Zhu

2013-01-01T23:59:59.000Z

6

Carbon Dioxide Separation with Novel Microporous Metal Organic Frameworks  

NLE Websites -- All DOE Office Websites (Extended Search)

Separation with Separation with Novel Microporous Metal Organic Frameworks Background UOP LLC, the University of Michigan, and Northwestern University are collaborating on a three-year program to develop novel microporous metal organic frameworks (MOFs) suitable for CO 2 capture and separation. MOFs are hybrid organic/inorganic structures in which the organic moiety is readily derivatized. This innovative program is using sophisticated molecular modeling to evaluate the structurally

7

Metal-Organic Frameworks for Highly Selective Separations  

Science Conference Proceedings (OSTI)

This grant was focused on the study of metal-organic frameworks with these specific objectives. (1) To examine the use of MOFs with well-defined open metal sites for binding of gases and small organics. (2) To develop a strategy for producing MOFs that combine large pore size with high surface area for their use in gas adsorption and separation of polycyclic organic compounds. (3) To functionalize MOFs for the storage of inert gases such as methane. A brief outline of our progress towards these objectives is presented here as it forms part of the basis for the ideas to be developed under the present proposal.

Omar M. Yaghi

2009-09-28T23:59:59.000Z

8

Carbon Dioxide Separation with Novel Microporous Metal Organic Frameworks  

NLE Websites -- All DOE Office Websites (Extended Search)

David a. Lang David a. Lang Project Manager National Energy Technology Laboratory 626 Cochrans Mill Road P.O. Box 10940 Pittsburgh, PA 15236-0940 412-386-4881 david.lang@netl.doe.doe Richard Willis Principal Investigator UOP LLC 50 East Algonquin Road Des Plaines, IL 60016 847-391-3190 Richard.Willis@uop.com Carbon DioxiDe Separation with novel MiCroporouS Metal organiC FraMeworkS Background UOP LLC, in collaboration with Vanderbilt University and the University of Edinburgh, is working to develop novel microporous metal organic frameworks (MOFs) and an associated process for the removal of CO 2 from coal-fired power plant flue gas. This innovative project will exploit the latest discoveries in an extraordinary class of materials (MOFs) having extremely high adsorption capacities. MOFs have previously exhibited

9

Stimuli-Responsive Metal Organic Frameworks: Stimuli-Responsive Metal Organic Frameworks for Energy-Efficient Post Combustion Capture  

Science Conference Proceedings (OSTI)

IMPACCT Project: A team led by three professors at Texas A&M is developing a subset of metal organic frameworks that respond to stimuli such as small changes in temperature to trap CO2 and then release it for storage. These frameworks are a promising class of materials for carbon capture applications because their structure and chemistry can be controlled with great precision. Because the changes in temperature required to trap and release CO2 in Texas A&M’s frameworks are much smaller than in other carbon capture approaches, the amount of energy or stimulus that has to be diverted from coal-fired power plants to accomplish this is greatly reduced. The team is working to alter the materials so they bind only with CO2, and are stable enough to withstand the high temperatures found in the chimneys of coal-fired power plants.

None

2010-07-01T23:59:59.000Z

10

Carbon Dioxide Separation with Novel Microporous Metal Organic Frameworks  

SciTech Connect

The goal of this program was to develop a low cost novel sorbent to remove carbon dioxide from flue gas and gasification streams in electric utilities. Porous materials named metal-organic frameworks (MOFs) were found to have good capacity and selectivity for the capture of carbon dioxide. Several materials from the initial set of reference MOFs showed extremely high CO{sub 2} adsorption capacities and very desirable linear isotherm shapes. Sample preparation occurred at a high level, with a new family of materials suitable for intellectual property protection prepared and characterized. Raman spectroscopy was shown to be useful for the facile characterization of MOF materials during adsorption and especially, desorption. Further, the development of a Raman spectroscopic-based method of determining binary adsorption isotherms was initiated. It was discovered that a stronger base functionality will need to be added to MOF linkers in order to enhance CO{sub 2} selectivity over other gases via a chemisorption mechanism. A concentrated effort was expended on being able to accurately predict CO{sub 2} selectivities and on the calculation of predicted MOF surface area values from first principles. A method of modeling hydrolysis on MOF materials that correlates with experimental data was developed and refined. Complimentary experimental data were recorded via utilization of a combinatorial chemistry heat treatment unit and high-throughput X-ray diffractometer. The three main Deliverables for the project, namely (a) a MOF for pre-combustion (e.g., IGCC) CO{sub 2} capture, (b) a MOF for post-combustion (flue gas) CO{sub 2} capture, and (c) an assessment of commercial potential for a MOF in the IGCC application, were completed. The key properties for MOFs to work in this application - high CO{sub 2} capacity, good adsorption/desorption rates, high adsorption selectivity for CO{sub 2} over other gases such as methane and nitrogen, high stability to contaminants, namely moisture, and easy regenerability, were all addressed during this program. As predicted at the start of the program, MOFs have high potential for CO{sub 2} capture in the IGCC and flue gas applications.

Richard Willis; Annabelle Benin; John Low; Ganesh Venimadhavan; Syed Faheem; David Lesch; Adam Matzger; Randy Snurr

2008-02-04T23:59:59.000Z

11

Tetratopic phenyl compounds, related metal-organic framework materials and post-assembly elaboration  

DOE Patents (OSTI)

Disclosed are tetratopic carboxylic acid phenyl for use in metal-organic framework compounds. These compounds are useful in catalysis, gas storage, sensing, biological imaging, drug delivery and gas adsorption separation.

Farha, Omar K; Hupp, Joseph T

2013-06-25T23:59:59.000Z

12

Tetratopic phenyl compounds, related metal-organic framework materials and post-assembly elaboration  

DOE Patents (OSTI)

Disclosed are tetratopic carboxylic acid phenyl for use in metal-organic framework compounds. These compounds are useful in catalysis, gas storage, sensing, biological imaging, drug delivery and gas adsorption separation.

Farha, Omar K.; Hupp, Joseph T.

2012-09-11T23:59:59.000Z

13

Stepwise adsorption in a mesoporous metal?organic framework: experimental and computational analysis  

SciTech Connect

Stepwise adsorption in a metal-organic framework with both micro- and meso-pores is caused by adsorbates first filling the micropores, then adsorbing along the mesopore walls, and finally filling the mesopores.

Yuan, Daqiang; Getman, Rachel B.; Wei, Zhangwen; Snurr, Randall Q.; Zhou, Hong-Cai (TAM)

2012-04-02T23:59:59.000Z

14

Impact of Metal and Anion Substitutions on the Hydrogen Storage Properties of MBTT Metal-Organic Frameworks  

E-Print Network (OSTI)

of Energy (DoE) system performance targets for mobile hydrogen storage systems,3 which specify minimumImpact of Metal and Anion Substitutions on the Hydrogen Storage Properties of MBTT Metal-organic frameworks are a class of materials being vigorously investigated for mobile hydrogen storage applications

15

Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal?Organic Frameworks  

SciTech Connect

Three new metal-organic frameworks [MOF-525, Zr{sub 6}O{sub 4}(OH){sub 4}(TCPP-H{sub 2}){sub 3}; MOF-535, Zr{sub 6}O{sub 4}(OH){sub 4}(XF){sub 3}; MOF-545, Zr{sub 6}O{sub 8}(H{sub 2}O){sub 8}(TCPP-H{sub 2}){sub 2}, where porphyrin H{sub 4}-TCPP-H{sub 2} = (C{sub 48}H{sub 24}O{sub 8}N{sub 4}) and cruciform H{sub 4}-XF = (C{sub 42}O{sub 8}H{sub 22})] based on two new topologies, ftw and csq, have been synthesized and structurally characterized. MOF-525 and -535 are composed of Zr{sub 6}O{sub 4}(OH){sub 4} cuboctahedral units linked by either porphyrin (MOF-525) or cruciform (MOF-535). Another zirconium-containing unit, Zr{sub 6}O{sub 8}(H{sub 2}O){sub 8}, is linked by porphyrin to give the MOF-545 structure. The structure of MOF-525 was obtained by analysis of powder X-ray diffraction data. The structures of MOF-535 and -545 were resolved from synchrotron single-crystal data. MOF-525, -535, and -545 have Brunauer-Emmett-Teller surface areas of 2620, 1120, and 2260 m{sup 2}/g, respectively. In addition to their large surface areas, both porphyrin-containing MOFs are exceptionally chemically stable, maintaining their structures under aqueous and organic conditions. MOF-525 and -545 were metalated with iron(III) and copper(II) to yield the metalated analogues without losing their high surface area and chemical stability.

Morris, William; Volosskiy, Boris; Demir, Selcuk; Gándara, Felipe; McGrier, Psaras L.; Furukawa, Hiroyasu; Cascio, Duilio; Stoddart, J. Fraser; Yaghi, Omar M. (UCLA); (NWU)

2012-10-24T23:59:59.000Z

16

Hydrogen Storage in a Microporous Metal-Organic Framework with Exposed Mn2+ Coordination Sites  

E-Print Network (OSTI)

Hydrogen Storage in a Microporous Metal-Organic Framework with Exposed Mn2+ Coordination Sites and 90 bar, which at 60 g H2/L provides a storage density 85% of that of liquid hydrogen. The material-358. (2) EERE: Hydrogen, Fuel Cells, & Infrastructure Technologies Program Homepage, www.eere.energy

17

Metal?organic frameworks for the storage and delivery of biologically active hydrogen sulfide  

SciTech Connect

Hydrogen sulfide is an extremely toxic gas that is also of great interest for biological applications when delivered in the correct amount and at the desired rate. Here we show that the highly porous metal-organic frameworks with the CPO-27 structure can bind the hydrogen sulfide relatively strongly, allowing the storage of the gas for at least several months. Delivered gas is biologically active in preliminary vasodilation studies of porcine arteries, and the structure of the hydrogen sulfide molecules inside the framework has been elucidated using a combination of powder X-ray diffraction and pair distribution function analysis.

Allan, Phoebe K.; Wheatley, Paul S.; Aldous, David; Mohideen, M. Infas; Tang, Chiu; Hriljac, Joseph A.; Megson, Ian L.; Chapman, Karena W.; De Weireld, Guy; Vaesen, Sebastian; Morris, Russell E. (St Andrews)

2012-04-02T23:59:59.000Z

18

Template-Free Synthesis of Hierarchical Porous Metal-Organic Frameworks  

Science Conference Proceedings (OSTI)

A template-free synthesis of a hierarchical microporous-mesoporous metal-organic framework (MOF) of Zn(II)-2,5-dihydroxy-1,4-benzenedicarboxylate, namely Zn-MOF-74, is reported. The surface morphology and porosity of the bimodal materials can be modified by etching the pore walls with the synthesis solvent under different reaction times and different solvents. This template-free strategy allows for the preparation of stable frameworks with mesopores exceeding 15 nm, which was previously unattained by the synthesis of MOFs by ligand exten-sion method.

Yue, Yanfeng [ORNL; Qiao, Zhen-an [University of Tennessee, Knoxville (UTK); Fulvio, Pasquale F [ORNL; Dai, Sheng [ORNL; Binder, Andrew J [ORNL; Tian, Chengcheng [ORNL; Nelson, Kimberly M [ORNL; Zhu, Xiang [ORNL

2013-01-01T23:59:59.000Z

19

CO2 Removal from Flue Gas Using MIcroporous Metal Organic Frameworks  

NLE Websites -- All DOE Office Websites (Extended Search)

Removal from Flue Gas Using Removal from Flue Gas Using Microporous Metal Organic Frameworks Background The mission of the U.S. Department of Energy's (DOE) Existing Plants, Emissions, & Capture (EPEC) Research & Development (R&D) Program is to develop innovative environmental control technologies to enable full use of the nation's vast coal reserves, while at the same time allowing the current fleet of coal-fired power plants to comply with existing and emerging environmental regulations. The EPEC R&D

20

Anionic Gallium-Based Metal;#8722;Organic Framework and Its Sorption and Ion-Exchange Properties  

SciTech Connect

A gallium-based metal-organic framework Ga{sub 6}(C{sub 9}H{sub 3}O{sub 6}){sub 8} {center_dot} (C{sub 2}H{sub 8}N){sub 6}(C{sub 3}H{sub 7}NO){sub 3}(H{sub 2}O){sub 26} [1, Ga{sub 6}(1,3,5-BTC){sub 8} {center_dot} 6DMA {center_dot} 3DMF {center_dot} 26H{sub 2}O], GaMOF-1; BTC = benzenetricarboxylate/trimesic acid and DMA = dimethylamine, with space group I{bar 4}3d, a = 19.611(1) {angstrom}, and V = 7953.4(6) {angstrom}{sup 3}, was synthesized using solvothermal techniques and characterized by synchrotron-based X-ray microcrystal diffraction. Compound 1 contains isolated gallium tetrahedra connected by the organic linker (BTC) forming a 3,4-connected anionic porous network. Disordered positively charged ions and solvent molecules are present in the pore, compensating for the negative charge of the framework. These positively charged molecules could be exchanged with alkali-metal ions, as is evident by an ICP-MS study. The H{sub 2} storage capacity of the parent framework is moderate with a H{sub 2} storage capacity of {approx}0.5 wt % at 77 K and 1 atm.

Banerjee, Debasis; Kim, Sun Jin; Wu, Haohan; Xu, Wenqian; Borkowski, Lauren A.; Li, Jing; Parise, John B. (Kwangju); (Rutgers); (SBU)

2012-04-30T23:59:59.000Z

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Metal-organic and zeolite imidazolate frameworks (MOFs and ZIFs) for highly selective separations  

SciTech Connect

Metal-organic and zeolite imidazolate frameworks (MOFs and ZIFs) have been investigated for the realization as separation media with high selectivity. These structures are held together with strong bonds, making them architecturally, chemically, and thermally stable. Therefore, employing well designed building units, it is possible to discover promising materials for gas and vapor separation. This grant was focused on the study of MOFs and ZIFs with these specific objectives: (i) to develop a strategy for producing MOFs and ZIFs that combine high surface areas with active sites for their use in gas adsorption and separation of small organic compounds, (ii) to introduce active sites in the framework by a post-synthetic modification and metalation of MOFs and ZIFs, and (iii) to design and synthesize MOFs with extremely high surface areas and large pore volumes to accommodate large amounts of guest molecules. By the systematic study, this effort demonstrated how to introduce active functional groups in the frameworks, and this is also the origin of a new strategy, which is termed isoreticular functionalization and metalation. However, a large pore volume is still a prerequisite feature. One of the solutions to overcome this challenge is an isoreticular expansion of a MOF�������¢����������������s structure. With triangular organic linker and square building units, we demonstrated that MOF-399 has a unit cell volume 17 times larger than that of the first reported material isoreticular to it, and it has the highest porosity (94%) and lowest density (0.126 g cm-3) of any MOF reported to date. MOFs are not just low density materials; the guest-free form of MOF-210 demonstrates an ultrahigh porosity, whose BET surface area was estimated to be 6240 m2 g-1 by N2 adsorption measurements.

Omar M. Yaghi

2012-09-17T23:59:59.000Z

22

Switching Kr/Xe Selectivity with Temperature in a Metal-Organic Framework  

Science Conference Proceedings (OSTI)

Krypton (Kr) and xenon (Xe) adsorption on two partially fluorinated metal-organic frameworks (FMOFCu and FMOFZn) with different cavity size and topologies were reported. FMOFCu shows an inversion in sorption selectivity toward Kr at temperatures below 0 C while FMOFZn does not. The 1D microtubes packed along the (101) direction connected through small bottleneck windows in FMOFCu appear to be the reason for this peculiar behavior. The FMOFCu shows an estimated Kr/Xe selectivity of 36 at 0.1 bar.

Fernandez, Carlos A.; Liu, Jian; Thallapally, Praveen K.; Strachan, Denis M.

2012-05-16T23:59:59.000Z

23

Molecular mechanism of hydrocarbons binding to the metal–organic framework  

SciTech Connect

The adsorption and diffusivity of methane, ethane, n-butane, n-hexane and cyclohexane in a metal organic framework (MOF) with the organic linker tetrakis[4-(carboxyphenyl)oxamethyl]methane, the metal salt, Zn2+, and organic pillar, 4,4’-bipyridin was studied using molecular dynamics simulations. For the n-alkanes, the longer the chain, the lower the free energy of adsorption, which was attributed to a greater number of contacts between the alkane and MOF. Cyclohexane had a slightly higher adsorption free energy than n-hexane. Furthermore, for cyclo- and n-hexane, there were no significant differences in adsorption free energies between systems with low to moderate loadings. The diffusivity of the n-alkanes was found to strongly depend on chain length with slower diffusion for longer chains. Cyclohexane had no effective diffusion, suggesting that the selectivity the MOF has towards n-hexane over cyclohexane is the result of kinetics instead of energetics. This work was supported by the U.S. Department of Energy's (DOE) Office of Basic Energy Sciences, Chemical Sciences program. The Pacific Northwest National Laboratory is operated by Battelle for DOE.

Sun, Xiuquan; Wick, Collin D.; Thallapally, Praveen K.; McGrail, B. Peter; Dang, Liem X.

2011-01-07T23:59:59.000Z

24

Development of Metal-Organic Framework Thin Films and Membranes for Low-Energy Gas Separation  

E-Print Network (OSTI)

Metal-organic frameworks (MOFs) are hybrid organic-inorganic micro- or mesoporous materials that exhibit regular crystalline lattices with rigid pore structures. Chemical functionalization of the organic linkers in the structures of MOFs affords facile control over pore size and physical properties, making MOFs attractive materials for application in gas-separating membranes. A wealth of reports exist discussing the synthesis of MOF structures, however relatively few reports exist discussing MOF membranes. This disparity owes to challenges associated with fabricating films of hybrid materials, including poor substrate-film interactions, moisture sensitivity, and thermal instability. Since even nanometer scale cracks and defects can affect the performance of a membrane for gas separation, these challenges are particularly acute for MOF membranes. The focus of this work is the development of novel methods for MOF film and membrane fabrication with a view to overcoming these challenges. The MOF film production methods discussed herein include in situ synthesis using ligand-modified or metal-modified supports and rapid thermal deposition (RTD).

McCarthy, Michael

2011-05-01T23:59:59.000Z

25

Collaborative Triple Framework Interpenetration and Immobilization of Open Metal Sites within a Microporous Mixed Metal-Organic Framework for Highly Selective Gas Adsorption  

Science Conference Proceedings (OSTI)

A three-dimensional triply interpenetrated mixed metal-organic framework, Zn{sub 2}(BBA){sub 2}(CuPyen) {center_dot} G{sub x} (M'MOF-20; BBA = biphenyl-4,4'-dicarboxylate; G = guest solvent molecules), of primitive cubic net was obtained through the solvothermal reaction of Zn(NO{sub 3}){sub 2}, biphenyl-4,4'-dicarboxylic acid, and the salen precursor Cu(PyenH{sub 2})(NO{sub 3}){sub 2} by a metallo-ligand approach. The triple framework interpenetration has stabilized the framework in which the activated M'MOF-20a displays type-I N{sub 2} gas sorption behavior with a Langmuir surface area of 62 m{sup 2} g{sup -1}. The narrow pores of about 3.9 {angstrom} and the open metal sites on the pore surfaces within M'MOF-20a collaboratively induce its highly selective C{sub 2}H{sub 2}/CH{sub 4} and CO{sub 2}/CH{sub 4} gas separation at ambient temperature.

Zhang, Zhangjing [University of Texas at San Antonio (UTSA); Xiang, Sheng-Chang [University of Texas at San Antonio (UTSA); Hong, Kunlun [ORNL; Das, Madhab [University of Texas at San Antonio (UTSA); Arman, Hadi [University of Texas at San Antonio (UTSA); Garcia, Maya [University of Texas, Pan American, Edinburg, TX; Mondal, Jalal [University of Texas, Pan American, Edinburg, TX; Chen, Banglin [University of Texas at San Antonio (UTSA)

2012-01-01T23:59:59.000Z

26

Sulfation of metal-organic framework: Opportunities for acid catalysis and proton conductivity  

Science Conference Proceedings (OSTI)

A new post-functionalization method for metal-organic frameworks (MOFs) has been developed to introduce acidity for catalysis. Upon treatment with a mixture of triflic anhydride and sulfuric acid, chemically stable MOF structures MIL-101(Cr) and MIL-53(Al) can be sulfated, resulting in a Broensted sulfoxy acid group attached to up to 50% of the aromatic terephthalate linkers of the structure. The sulfated samples have been extensively characterized by solid-state NMR, XANES, and FTIR spectroscopy. The functionalized acidic frameworks show catalytic activity similar to that of acidic polymers like Nafion{reg_sign} display in the esterification of n-butanol with acetic acid (TOF {approx} 1 min{sup -1} {at} 343 K). Water adsorbs strongly up to 4 molecules per sulfoxy acid group, and an additional 2 molecules are taken up at lower temperatures in the 1-D pore channels of S-MIL-53(Al). The high water content and Broensted acidity provide the structure S-MIL-53(Al) a high proton conductivity up to moderate temperatures.

Goesten, M.G.; Stavitski, E.; Juan-Alcaniz, J.; Ramos-Fernandez, E.V.; Sai Sankar Gupta, K.B.; van Bekkum, H.; Gascon, J. and Kapteijn, F.

2011-05-24T23:59:59.000Z

27

Interpenetrating metal-organic frameworks formed by self-assembly of tetrahedral and octahedral building blocks  

Science Conference Proceedings (OSTI)

To investigate the relationship between topological types and molecular building blocks (MBBs), we have designed and synthesized a series of three-dimensional (3D) interpenetrating metal-organic frameworks based on different polygons or polyhedra under hydrothermal conditions, namely [Cd(bpib){sub 0.5}(L{sup 1})] (1), [Cd(bpib){sub 0.5}(L{sup 2})].H{sub 2}O (2), [Cd(bpib){sub 0.5}(L{sup 3})] (3) and [Cd(bib){sub 0.5}(L{sup 1})] (4), where bpib=1,4-bis(2-(pyridin-2-yl)-1H-imidazol-1-yl)butane, bib=1,4-bis(1H-imidazol-1-yl)butane, H{sub 2}L{sup 1}=4-(4-carboxybenzyloxy)benzoic acid, H{sub 2}L{sup 2}=4,4'-(ethane-1,2-diylbis(oxy))dibenzoic acid and H{sub 2}L{sup 3}=4,4'-(1,4-phenylenebis(methylene))bis(oxy)dibenzoic acid, respectively. Their structures have been determined by single crystal X-ray diffraction analyses and further characterized by elemental analyses, IR spectra, and thermogravimetric (TG) analyses. Compounds 1-3 display alpha-Po topological nets with different degrees of interpenetration based on the similar octahedral [Cd{sub 2}(-COO){sub 4}] building blocks. Compound 4 is a six-fold interpenetrating diamondoid net based on tetrahedral MBBs. By careful inspection of these structures, we find that various carboxylic ligands and N-donor ligands with different coordination modes and conformations, and metal centers with different geometries are important for the formation of the different MBBs. It is believed that different topological types lie on different MBBs with various polygons or polyhedra. Such as four- and six-connected topologies are formed by tetrahedral and octahedral building blocks. In addition, with the increase of carboxylic ligands' length, the degrees of interpenetration have been changed in the alpha-Po topological nets. And the luminescent properties of these compounds have been investigated in detail. - Graphical abstract: A series of three-dimensional interpenetrating metal-organic frameworks based on different polygons or polyhedra has been synthesized. The crystal structures and topological analysis of these compounds, along with a systematic investigation of the relationship between topological types and molecular building blocks, will be discussed.

Lu Yongming; Lan Yaqian; Xu Yanhong [Institute of Functional Material Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun 130024 (China); Su Zhongmin, E-mail: zmsu@nenu.edu.c [Institute of Functional Material Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun 130024 (China); Li Shunli, E-mail: lishunli@yahoo.c [Institute of Functional Material Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun 130024 (China); Zang Hongying; Xu Guangjuan [Institute of Functional Material Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun 130024 (China)

2009-11-15T23:59:59.000Z

28

Facile xenon capture and release at room temperature using a metal-organic framework: a comparison with activated charcoal  

SciTech Connect

Two well known Metal organic frameworks (MOF-5, NiDOBDC) were synthesized and studied for facile xenon capture and separation. Our results indicate the NiDOBDC adsorbs significantly more xenon than MOF-5, releases it more readily than activated carbon, and is more selective for Xe over Kr than activated carbon.

Thallapally, Praveen K.; Grate, Jay W.; Motkuri, Radha K.

2012-01-11T23:59:59.000Z

29

Generation and Applications of Structure Envelopes for Metal-Organic Frameworks  

E-Print Network (OSTI)

Synthesis of polycrystalline, vs. single-crystalline porous materials, such as metal-organic frameworks (MOFs), is usually beneficial due to shorter synthetic time and higher yields. However, the structural characterization of these materials by X-ray powder diffraction can be complicated. Even more difficult, is to track structural changes of MOFs by in situ experiments. Hence, we designed several successful techniques for the structural investigation of porous MOFs. These methods utilize the Structure Envelope (SE) density maps. SEs are surfaces which describing the pore system with the framework. It was shown that these maps can be easily generated from the structure factors of a few (1 to 10) of the most intense low index reflections. Application of SE in Charge Flipping calculations shortens and simplifies structure determination of MOF materials. This method provides excellent MOF models which can be used as a good starting point for their refinement. However, the most interesting results have been found by using Difference Envelope Density (DED) analysis. DED plots are made by taking the difference between observed and calculated SE densities. This allows us to study guest related issues of MOFs such as, location of guest molecules in the pores, tracking activation of MOFs and gas loading, etc. We also have shown that, DED created from routine powder diffraction patterns might provide very important information about MOF structure itself. In fact DED can be used for study of interpenetration, substituents locations and effects conformational changes in the MOF ligands. Generation and analysis of SEs and DEDs are easy and straightforward. It provides the information needed to explain major deviations in structure-property relationship in MOFs. In our opinion, this method might become one of the important and routine techniques for MOFs structural analysis.

Yakovenko, Andrey A.

2013-05-01T23:59:59.000Z

30

Composite Membranes for CO2 Capture: High Performance Metal Organic Frameworks/Polymer Composite Membranes for Carbon Dioxide Capture  

Science Conference Proceedings (OSTI)

IMPACCT Project: A team of six faculty members at Georgia Tech are developing an enhanced membrane by fitting metal organic frameworks, compounds that show great promise for improved carbon capture, into hollow fiber membranes. This new material would be highly efficient at removing CO2 from the flue gas produced at coal-fired power plants. The team is analyzing thousands of metal organic frameworks to identify those that are most suitable for carbon capture based both on their ability to allow coal exhaust to pass easily through them and their ability to select CO2 from that exhaust for capture and storage. The most suitable frameworks would be inserted into the walls of the hollow fiber membranes, making the technology readily scalable due to their high surface area. This composite membrane would be highly stable, withstanding the harsh gas environment found in coal exhaust.

None

2010-07-01T23:59:59.000Z

31

Stress-induced chemical detection using flexible metal-organic frameworks.  

DOE Green Energy (OSTI)

In this work we demonstrate the concept of stress-induced chemical detection using metal-organic frameworks (MOFs) by integrating a thin film of the MOF HKUST-1 with a microcantilever surface. The results show that the energy of molecular adsorption, which causes slight distortions in the MOF crystal structure, can be efficiently converted to mechanical energy to create a highly responsive, reversible, and selective sensor. This sensor responds to water, methanol, and ethanol vapors, but yields no response to either N{sub 2} or O{sub 2}. The magnitude of the signal, which is measured by a built-in piezoresistor, is correlated with the concentration and can be fitted to a Langmuir isotherm. Furthermore, we show that the hydration state of the MOF layer can be used to impart selectivity to CO{sub 2}. We also report the first use of surface-enhanced Raman spectroscopy to characterize the structure of a MOF film. We conclude that the synthetic versatility of these nanoporous materials holds great promise for creating recognition chemistries to enable selective detection of a wide range of analytes. A force field model is described that successfully predicts changes in MOF properties and the uptake of gases. This model is used to predict adsorption isotherms for a number of representative compounds, including explosives, nerve agents, volatile organic compounds, and polyaromatic hydrocarbons. The results show that, as a result of relatively large heats of adsorption (> 20 kcal mol{sup -1}) in most cases, we expect an onset of adsorption by MOF as low as 10{sup -6} kPa, suggesting the potential to detect compounds such as RDX at levels as low as 10 ppb at atmospheric pressure.

Allendorf, Mark D.; Hesketh, Peter J. (Georgia Institute of Technology, Atlanta, GA); Gall, Kenneth A. (Georgia Institute of Technology, Atlanta, GA); Choudhury, A. (Georgia Institute of Technology, Atlanta, GA); Pikarsky, J. (Georgia Institute of Technology, Atlanta, GA); Andruszkiewicz, Leanne (Georgia Institute of Technology, Atlanta, GA); Houk, Ronald J. T.; Talin, Albert Alec (National Institute of Standards & Technology, Gaithersburg, MD)

2009-09-01T23:59:59.000Z

32

Structure-property relationship of metal-organic frameworks (MOFs) and physisorbed off-gas radionuclides.  

Science Conference Proceedings (OSTI)

We report on the host-guest interactions between metal-organic frameworks (MOFs) with various profiles and highly polarizable molecules (iodine), with emphasis on identifying preferential sorption sites in these systems. Radioactive iodine 129I, along with other volatile radionuclides (3H, 14C, Xe and Kr), represents a relevant component in the off-gas resulted during nuclear fuel reprocessing. Due to its very long half-life, 15.7 x 106 years, and potential health risks in humans, its efficient capture and long-term storage is of great importance. The leading iodine capture technology to date is based on trapping iodine in silver-exchanged mordenite. Our interests are directed towards improving existent capturing technologies, along with developing novel materials and alternative waste forms. Herein we report the first study that systematically monitors iodine loading onto MOFs, an emerging new class of porous solid-state materials. In this context, MOFs are of particular interest as: (i) they serve as ideal high capacity storage media, (ii) they hold potential for the selective adsorption from complex streams, due to their high versatility and tunability. This work highlights studies on both newly developed in our lab, and known highly porous MOFs that all possess distinct characteristics (specific surface area, pore volume, pore size, and dimension of the window access to the pore). The materials were loaded to saturation, where elemental iodine was introduced from solution, as well as from vapor phase. Uptakes in the range of {approx}125-150 wt% I2 sorbed were achieved, indicating that these materials outperform all other solid adsorbents to date in terms of overall capacity. Additionally, the loaded materials can be efficiently encapsulated in stable waste forms, including as low temperature sintering glasses. Ongoing studies are focused on gathering qualitative information with respect to localizing the physisorbed iodine molecules within the frameworks: X-ray single-crystal analyses, in conjunction with high pressure differential pair distribution function (d-PDF) studies aimed to identify preferential sites in the pores, and improve MOFs robustness. Furthermore, durability studies on the iodine loaded MOFs and subsequent waste forms include thermal analyses, SEM/EDS elemental mapping, and leach-durability testing. We anticipate for this in-depth analysis to further aid the design of advanced materials, capable to address major hallmarks: safe capture, stability and durability over extended timeframes.

Nenoff, Tina Maria; Chupas, Peter J. (Argonne National Laboratory); Garino, Terry J.; Rodriguez, Mark Andrew; Chapman, Karena W. (Argonne National Laboratory); Sava, Dorina Florentina

2010-11-01T23:59:59.000Z

33

Computational Evaluation of Metal-Organic Frameworks for CO2 Capture  

E-Print Network (OSTI)

Metal-organic frameworks (MOFs), a new class of porous solids comprised of metal-containing nodes linked by organic ligands, have become promising materials for gas separations. In particular, their flexible chemistry makes them attractive for CO2 capture from flue gas streams in post-combustion plants. Although numerous efforts have been exerted on the investigation of MOFs for CO2 capture, the exploration of the effects from coexisting components present in very dilute proportions in flue gases is limited because of the experimental difficulty to determine the coadsorption of CO2 with trace components. In this regard, molecular simulations show superiority. In this study, molecular simulations are used to estimate the in?uence of impurities: water, O2, and SO2 on post-combustion CO2 capture in MOFs. Firstly, two MOFs with coordinatively unsaturated metal sites (CUMs), HKUST-1 and Mg-MOF-74 are explored. Increase of CO2 adsorption is observed for hydrated HKUST-1; on the contrary, the opposite water adsorption behavior is observed in hydrated Mg-MOF-74, leading to decrease of CO2 adsorption. Further, water effects on CO2 capture in M-HKUST1 (M = Mg, Zn, Co, Ni) are evaluated to test whether comparing the binding energy could be a general method to evaluate water effects in MOFs with CUMs. It is found that the method works well for Zn-, Co-, and Ni-HKUST1 but partially for Mg-HKUST1. In addition, the effects of O2 and SO2 on CO2 capture in MOFs are also investigated for the first time, showing that the effects of O2 may be negligible but SO2 has negative effects in the CO2 capture process in HKUST-1 systems. Secondly, the influences of water on CO2 capture in three UiO-66 MOFs with functional groups, –NH2, –OH and –Br are explored, respectively. For UiO-66-NH2 and -OH, the presence of water lowers CO2 adsorption significantly; in contrast, water shows much smaller effects in UiO-66-Br. Moreover, the presence of SO2 decreases water adsorption but enhances CO2 uptakes slightly in both UiO-66-NH2 and -Br. Finally, the effects of impurities on CO2 capture in a MOF with suitable pore size (PCN-200) are analyzed. The adsorption of both CO2 and N2 decrease substantially even with 1% water present in the mixture. In addition, the presence of low SO2 does not show obvious effect in PCN-200. However, a lower CO2 adsorption is observed for a mixture with a high SO2 content. In collaboration with experimental groups, the performances of three new MOFs in CO2 capture are evaluated using molecular simulations. The computational results demonstrate the feasibility of precisely designing single-molecule traps (SMT) for CO2 capture. Also, a multi-functional MOF with micro-porosity, open Cu2+ sites and amine groups has also proved computationally the selective adsorption of CO2 over CH4 and N2. Last, we demonstrate that charge separation is an effective strategy for improving CO2 capture in MOFs.

Yu, Jiamei

2013-05-01T23:59:59.000Z

34

Tuning the Gate Opening Pressure of Metal Organic Frameworks (MOFs) for the Selective Separation of Hydro-carbons  

E-Print Network (OSTI)

Separation of hydrocarbons is one of the most energy demanding processes. The need to develop materials for the selective adsorption of hydrocarbons, under reasonable conditions, is therefore of paramount importance. This work unveils unexpected hydrocarbon selectivity in a flexible Metal Organic Framework (MOF), based on differences in their gate opening pressure. We show selectivity dependence on both chain length and specific framework-gas interaction. Combining Raman spectroscopy and theoretical van der Waals Density Functional (vdW-DF) calculations, the separation mechanisms governing this unexpected gate opening behavior are revealed.

Nijem, Nour; Canepa, Pieremanuele; Marti, Anne; Balkus,, Kenneth J; Thonhauser, T; Li, Jing; Chabal, Yves J; 10.1021/ja305754f

2012-01-01T23:59:59.000Z

35

Carbon Dioxide Removal from Flue Gas Using Microporous Metal Organic Frameworks  

SciTech Connect

UOP LLC, a Honeywell Company, in collaboration with Professor Douglas LeVan at Vanderbilt University (VU), Professor Adam Matzger at the University of Michigan (UM), Professor Randall Snurr at Northwestern University (NU), and Professor Stefano Brandani at the University of Edinburgh (UE), supported by Honeywell's Specialty Materials business unit and the Electric Power Research Institute (EPRI), have completed a three-year project to develop novel microporous metal organic frameworks (MOFs) and an associated vacuum-pressure swing adsorption (vPSA) process for the removal of CO{sub 2} from coal-fired power plant flue gas. The project leveraged the team's complementary capabilities: UOP's experience in materials development and manufacturing, adsorption process design and process commercialization; LeVan and Brandani's expertise in high-quality adsorption measurements; Matzger's experience in syntheis of MOFs and the organic components associated with MOFs; Snurr's expertise in molecular and other modeling; Honeywell's expertise in the manufacture of organic chemicals; and, EPRI's knowledge of power-generation technology and markets. The project was successful in that a selective CO{sub 2} adsorbent with good thermal stability and reasonable contaminant tolerance was discovered, and a low cost process for flue gas CO{sub 2} capture process ready to be evaluated further at the pilot scale was proposed. The team made significant progress toward the current DOE post-combustion research targets, as defined in a recent FOA issued by NETL: 90% CO{sub 2} removal with no more than a 35% increase in COE. The team discovered that favorable CO{sub 2} adsorption at more realistic flue gas conditions is dominated by one particular MOF structure type, M/DOBDC, where M designates Zn, Co, Ni, or Mg and DOBDC refers to the form of the organic linker in the resultant MOF structure, dioxybenzenedicarboxylate. The structure of the M/DOBDC MOFs consists of infinite-rod secondary building units bound by DOBDC resulting in 1D hexagonal pores about 11 angstroms in diameter. Surface areas range from 800 to 1500 sq m/g for the different MOFs. Mg/DOBDC outperformed all MOF and zeolite materials evaluated to date, with about 25 wt% CO{sub 2} captured by this MOF at flue gas conditions ({approx}0.13 atm CO{sub 2} pressure, 311K). In simulated flue gas without oxygen, the zero-length (ZLC) system was very useful in quickly simulating the effect of long term exposure to impurities on the MOFs. Detailed adsorption studies on MOF pellets have shown that water does not inhibit CO{sub 2} adsorption for MOFs as much as it does for typical zeolites. Moreover, some MOFs retain a substantial CO{sub 2} capacity even with a modest water loading at room temperature. Molecular modeling was a key activity in three areas of our earlier DOE/NETL-sponsored MOF-based research on CC. First, the team was able to effectively simulate CO{sub 2} and other gas adsorption isotherms for more than 20 MOFs, and the knowledge obtained was used to help predict new MOF structures that should be effective for CO{sub 2} adsorption at low pressure. The team also showed that molecular modeling could be utilized to predict the hydrothermal stability of a given MOF. Finally, the team showed that low moisture level exposure actually enhanced the CO{sub 2} adsorption performance of a particular MOF, HKUST-1.

David A Lesch

2010-06-30T23:59:59.000Z

36

Selective CO2 Capture from Flue Gas Using Metal-Organic Frameworks?A Fixed Bed Study  

SciTech Connect

It is important to capture carbon dioxide from flue gas which is considered to be the main reason to cause global warming. CO2/N2 separation by novel adsorbents is a promising method to reduce CO2 emission but effect of water and CO2/N2 selectivity is critical to apply the adsorbents into practical applications. A very well known, Metal Organic Framework, NiDOBDC (Ni-MOF-74 or CPO-27-Ni) was synthesized through a solvothermal reaction and the sample (500 to 800 microns) was used in a fixed bed CO2/N2 breakthrough study with and without H2O. The Ni/DOBDC pellet has a high CO2 capacity of 3.74 mol/kg at 0.15 bar and a high CO2/N2 selectivity of 38, which is much higher than those of reported MOFs and zeolites under dry condition. Trace amount of water can impact CO2 adsorption capacity as well as CO2/N2 selectivity for the Ni/DOBDC. However, Ni/DOBDC can retain a significant CO2 capacity and CO2/N2 selectivity at 0.15 bar CO2 with 3% RH water. These results indicate a promising future to use the Ni/DOBDC in CO2 capture from flue gas.

Liu, Jian; Tian, Jian; Thallapally, Praveen K.; McGrail, B. Peter

2012-05-03T23:59:59.000Z

37

Pendant Functional Groups in Metal-Organic Frameworks - Effects on Crystal Structure, Stability, and Gas Sorption Properties  

E-Print Network (OSTI)

The primary goal of this research concerns the synthesis and characterization of metal-organic frameworks (MOFs) grafted with pendant alkyl substituents to enhance stability and gas sorption properties for use in clean-energy related technologies. Initially, the focus of this work was on the synthesis and comparison of two isostructural MOFs built upon octahedral secondary building blocks; one with no alkyl substituents, and its dimethyl-substituted counterpart. The dimethyl-substituents are observed to enhance the stability of the framework, resulting in high Langmuir surface area (4859 m2 g-1) and hydrogen uptake capacity at 77 K and 1 bar (2.6 wt%). In the second section, the length of pendant alkoxy substituents in semi-flexible MOFs was evaluated through the synthesis and characterization of two isostructural MOFs, one with dimethoxy (PCN-38) and one with diethoxy pendant groups (PCN-39). While PCN-38 exhibited moderate surface area and hydrogen uptake capacities, PCN-39 underwent structural change upon activation leading to a redistribution of pore sizes and selective adsorption of hydrogen over larger gases. This structural transformation is believed to originate from optimal space filling of the pendant groups. In the third section, a series of NbO-type MOFs were synthesized with dimethoxy, diethoxy, dipropoxy, and dihexyloxy substituents and the relationship between chain length and framework stability identified. Increasing chain length was observed to increase moisture stability of the MOFs, resulting in a superhydrophobic material in the case of the dihexyloxy derivative. Thermal stability, however, decreased with increasing chain length, as evidenced from in situ synchrotron powder X-ray diffraction measurements (PXRD). This is in contrast to data obtained from thermogravimetric analysis and shows that the standard use of thermogravimetric analysis, which measures combustion temperatures, may not always provide an accurate description of the thermal stability of MOFs. The role of pendant groups in gas adsorption processes was evaluated through identification of side chains and guest species in the pores of MOFs through in situ synchrotron PXRD measurements. In summary, three separate isostructural series of MOFs with various pendant groups have been discussed in this dissertation, with the roles of those pendant groups toward crystal structure, stability, and gas sorption properties analyzed.

Makal, Trevor Arnold

2013-05-01T23:59:59.000Z

38

Synthesis and Characterization of Films and Membranes of Metal-Organic Framework (MOF) for Gas Separation Applications  

E-Print Network (OSTI)

Metal-Organic Frameworks (MOFs) are nanoporous framework materials with tunable pore size and functionality, and hence attractive for gas separation membrane applications. Zeolitic Imidazolate Frameworks (ZIFs), a subclass of MOFs, are known for their high thermal and chemical stability. ZIF-8 has demonstrated potential to kinetically separate propane/propene in powder and membrane form. ZIF-8 membranes propane-propene separation performance is superior in comparison to polymer, mixed matrix and carbon membranes. The overarching theme of my research is to address challenges that hinder fabrication of MOF membranes on a commercial scale and in a reproducible and scalable manner. 1. Current approaches, are specific to a given ZIF, a general synthesis route is not available. Use of multiple steps for surface modification or seeding causes reproducibility and scalability issues. 2. Conventional fabrication techniques are batch processes, thereby limiting their commercialization. Here we demonstrate two new approaches that can potentially address these challenges. First, we report one step in situ synthesis of ZIF-8 membranes on more commonly used porous ?-alumina supports. By incorporating sodium formate in the in situ growth solution, well intergrown ZIF-8 membranes were synthesized on unmodified supports. The mechanism by which sodium formate promotes heterogeneous nucleation was investigated. Sodium formate reacts with zinc source to form zinc oxide layer, which in turn promotes heterogeneous nucleation. Sodium formate promotes heterogeneous nucleation in other ZIF systems as well, leading to ZIF-7, Zn(Im)2 (ZIF-61 analogue), ZIF-90, and SIM-1 films. Thus one step in situ growth using sodium formate provides a simplified, reproducible and potentially general route for ZIF film fabrication. One step in situ route, although advantageous; is still conventional in nature and batch process with long synthesis time. This limits commercialization, due to scalability and manufacturing cost issues. Taking advantage of coordination chemistry of MOFs and using temperature as driving force, continuous well-intergrown membranes of HKUST-1 and ZIF-8 in relatively short time (15 min) using Rapid Thermal Deposition (RTD). With minimum precursor consumption and simplified synthesis protocol, RTD provides potential for a continuous, scalable, reproducible and commercializable route for MOF membrane fabrication. RTD-prepared MOF membranes show improved separation performances, indicating improved microstructure

Shah, Miral 1987-

2012-12-01T23:59:59.000Z

39

Gas Adsorption and Permeance with Metal Organic ...  

Science Conference Proceedings (OSTI)

... Page 4. ? Metal Organic Frameworks (MOFs) ? Zeolitic Imidazolate ... 1 2 2,1 P P = ? nRT A nRT PV = ? = ? • 7 coupled equations, 9 unknowns ...

2010-09-03T23:59:59.000Z

40

Synthetic Design of New Metal-Organic Framework Materials for Hydrogen Storage - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

9 9 FY 2012 Annual Progress Report DOE Hydrogen and Fuel Cells Program Pingyun Feng (Primary Contact), Qipu Lin, Xiang Zhao Department of Chemistry University of California Riverside, CA 92521 Phone: (951) 827-2042 Email: pingyun.feng@ucr.edu DOE Program Officer: Dr. Michael Sennett Phone: (301) 903-6051 Email: Michael.Sennett@science.doe.gov Objectives Design and * synthesize new metal-organic framework materials using lightweight chemical elements to help improve gravimetric hydrogen storage capacity. Develop new synthetic strategies to generate novel * active binding sites on metal ions and ligands to enhance solid-gas interactions for increased uptake near ambient conditions.

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41

A Biomimetic Approach to Metal-Organic Frameworks with High H2 Uptake - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

0 0 DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report Hong-Cai (Joe) Zhou Dept. of Chem., Texas A&M University P.O. Box 30012 College Station, TX 77842-3012 Phone: (979) 845-4034 Email: zhou@mail.chem.tamu.edu DOE Managers HQ: Ned Stetson Phone: (202) 586-9995 Email: Ned.Stetson@ee.doe.gov GO: Jesse Adams Phone: (720) 356-1421 Email: Jesse.Adams@go.doe.gov Contract Number: DE-FC36-07GO17033 Project Start Date: July 1, 2007 Project End Date: June 30, 2013 Fiscal Year (FY) 2012 Objectives Design, synthesis, and characterization of metal-organic * frameworks (MOFs) with potential anchors for active metal centers introduction. Design, synthesis, and optimization of porous polymer * frameworks (PPNs) with different functionalities. These functionalized MOFs and PPNs demonstrate much *

42

A two-fold interpenetrating 3D metal-organic framework material constructed from helical chains linked via 4,4'-H{sub 2}bpz fragments  

SciTech Connect

A 3-connected dia-f-type metal-organic framework compound {l_brace}[Ag(L){sub 3/2}H{sub 2}PO{sub 4}]{r_brace}{sub n} (1) has been synthesized by self-assembly of 4,4'-H{sub 2}bpz (L=4,4'-H{sub 2}bpz=3,3',5,5'-tetramethyl-4,4'-bipyrazole) and Ag{sub 4}P{sub 2}O{sub 7} under hydrothermal conditions. It crystallizes in the tetragonal space group I4{sub 1}/acd with a=21.406(4) A, b=21.406(4) A, c=36.298(8) A, Z=32. X-ray single-crystal diffraction reveals that 1 has a three-dimensional framework with an unprecedented alternate left- and right-handed helices structure, featuring a non-uniform two-fold interpenetrated (4.14{sup 2}) net. Photoluminescent investigation reveals that the title compound displays interesting emissions in a wide region, which shows that the title compound may be a good potential candidate as a photoelectric material. - Graphical abstract: A 3-connected dia-f-type metal-organic framework compound [Ag(4,4'-bpz){sub 3/2}H{sub 2}PO{sub 4}] shows unprecedented alternating left- and right-handed helices structure, featuring a non-uniform two-fold interpenetrated (4.14{sup 2}) net.

Xie Yiming [State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 35002 (China); College of Materials Science and Engineering, Huaqiao University, the Key Laboratory for Functional Materials of Fujian Higher Education, Quanzhou, Fujian 362021 (China); Zhao Zhenguo; Wu Xiaoyuan; Zhang Qisheng; Chen Lijuan; Wang Fei; Chen Shanci [State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 35002 (China); Lu Canzhong [State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 35002 (China)], E-mail: czlu@fjirsm.ac.cn

2008-12-15T23:59:59.000Z

43

A Highly Porous and Robust (3,3,4)-Connected Metal?Organic Framework Assembled with a 90° Bridging-Angle Embedded Octacarboxylate Ligand  

SciTech Connect

A dicopper(II)-paddle-wheel-based metal-organic framework (PCN-80, see picture) with a rare (3,3,4)-connected topology has been synthesized by using a unique octatopic ligand featuring 90{sup o} bridging-angle dicarboxylate moieties. PCN-80 has Brunauer-Emmett-Teller (BET) and Langmuir surface areas of 3850 and 4150 m{sup 2}g{sup -1}, respectively. It exhibits high gas-uptake capacity for H{sub 2} and large adsorption selectivity of CO{sub 2} over N{sub 2}.

Lu, Weigang; Yuan, Daqiang; Makal, Trevor A.; Li, Jian-Rong; Zhou, Hong-Cai (TAM)

2012-03-15T23:59:59.000Z

44

Photophysical Studies of Ru(II)tris(2,2;#8242;-bipyridine) Confined within a Zn(II)?Trimesic Acid Polyhedral Metal?Organic Framework  

Science Conference Proceedings (OSTI)

The ability to confine photoactive catalysts within metal-organic framework (MOF) materials affords the opportunity to expand the functional diversity of these materials into solar based applications. Here, the confinement of Ru(II)tris(2,2'-bipyridine) (RuBpy) by a MOF material derived from Zn(II) ions and trimesic acid (hereafter, USF2) is examined. Although the encapsulated RuBpy could not be crystallographically resolved within the MOF framework, the photophysical properties of the complex are characteristic of confinement including extended triplet metal-to-ligand ({sup 3}MLCT) lifetime ({tau}{sub ethanol} = 614 ns and {tau}{sub USF2} = 1.2 {micro}s at 25 C) and a slight hypsochromic shift in the steady-state emission spectrum relative to RuBpy in ethanol. The extended lifetime is attributed to a deactivation of a nonradiative {sup 3}dd that is antibonding with respect to the Ru(II)-bipyridine due to a confined molecular environment. These results represent one of the first examples of RuBpy encapsulation and photophysical characterization within a polyhedral MOF material.

Larsen, Randy W.; Wojtas, Lukasz (USF)

2012-10-25T23:59:59.000Z

45

Adsorption and Separation of Light Gases on an Amino-Functionalized Metal–Organic Framework: An Adsorption and In Situ XRD Study  

Science Conference Proceedings (OSTI)

The NH{sub 2}-MIL-53(Al) metal-organic framework was studied for its use in the separation of CO{sub 2} from CH{sub 4}, H{sub 2}, N{sub 2} C{sub 2}H{sub 6} and C{sub 3}H{sub 8} mixtures. Isotherms of methane, ethane, propane, hydrogen, nitrogen, and CO{sub 2} were measured. The atypical shape of these isotherms is attributed to the breathing properties of the material, in which a transition from a very narrow pore form to a narrow pore form and from a narrow pore form to a large pore form occurs, depending on the total pressure and the nature of the adsorbate, as demonstrated by in-situ XRD patterns measured during adsorption. Apart from CO{sub 2}, all tested gases interacted weakly with the adsorbent. As a result, they are excluded from adsorption in the narrow pore form of the material at low pressure. CO{sub 2} interacted much more strongly and was adsorbed in significant amounts at low pressure. This gives the material excellent properties to separate CO{sub 2} from other gases. The separation of CO{sub 2} from methane, nitrogen, hydrogen, or a combination of these gases has been demonstrated by breakthrough experiments using pellets of NH{sub 2}-MIL-53(Al). The effect of total pressure (1-30 bar), gas composition, temperature (303-403 K) and contact time has been examined. In all cases, CO{sub 2} was selectively adsorbed, whereas methane, nitrogen, and hydrogen nearly did not adsorb at all. Regeneration of the adsorbent by thermal treatment, inert purge gas stripping, and pressure swing has been demonstrated. The NH{sub 2}-MIL-53(Al) pellets retained their selectivity and capacity for more than two years.

Couck S.; Stavitski E.; Gobehiya, E.; Kirschhock, C.E.A.; Serra-Crespo, P.; Juan-Alcaniz, J.; Martinez Joaristi, A.; Gascon, J.; Kapteijn, F.; Baron, G. V.; Denayer J.F.M.

2012-02-29T23:59:59.000Z

46

Interplay of Metalloligand and Organic Ligand to Tune Micropores within Isostructural Mixed-Metal Organic Frameworks (M MOFs) for Their Highly Selective Separation of Chiral and Achiral Small Molecules  

SciTech Connect

Four porous isostructural mixed-metal-organic frameworks (M'MOFs) have been synthesized and structurally characterized. The pores within these M'MOFs are systematically tuned by the interplay of both the metalloligands and organic ligands which have enabled us not only to direct their highly selective separation of chiral alcohols 1-phenylethanol (PEA), 2-butanol (BUT), and 2-pentanol (2-PEN) with the highest ee up to 82.4% but also to lead highly selective separation of achiral C{sub 2}H{sub 2}/C{sub 2}H{sub 4} separation. The potential application of these M'MOFs for the fixed bed pressure swing adsorption (PSA) separation of C{sub 2}H{sub 2}/C{sub 2}H{sub 4} has been further examined and compared by the transient breakthrough simulations in which the purity requirement of 40 ppm in the outlet gas can be readily fulfilled by the fixed bed M'MOF-4a adsorber at ambient conditions.

Madhab, Das [University of Texas at San Antonio (UTSA); He, Yabing [University of Texas at San Antonio (UTSA); Kim, Jaheon [Soongsil University, Korea; Guo, Qunsheng [University of Texas at San Antonio (UTSA); Zhao, Cong-Gui [University of Texas at San Antonio (UTSA); Hong, Kunlun [ORNL; Xiang, Sheng-Chang [University of Texas at San Antonio (UTSA); Zhang, Zhangjing [University of Texas at San Antonio (UTSA); Thomas, K Mark [University of Newcastle upon Tyne; Krishna, Rajamani [Universitate Amsterdam; Chen, Banglin [University of Texas at San Antonio (UTSA)

2012-01-01T23:59:59.000Z

47

Mixed-Matric Membranes for CO2 and H2 Gas Separations Using Metal-Organic Framework and Mesoporus Hybrid Silicas  

Science Conference Proceedings (OSTI)

In this work, we have investigated the separation performance of polymer-based mixed-matrix membranes containing metal-organic frameworks and mesoporous hybrid silicas. The MOF/Matrimid{reg_sign} and MOP-18/Matrimid{reg_sign} membranes exhibited improved dispersion and mechanical strength that allowed high additive loadings with reduced aggregation, as is the case of the 80 wt% MOP-18/Matrimid{reg_sign} and the 80% (w/w) Cu-MOF/Matrimid{reg_sign} membranes. Membranes with up to 60% (w/w) ZIF-8 content exhibited similar mechanical strength and improved dispersion. The H{sub 2}/CO{sub 2} separation properties of MOF/Matrimid{reg_sign} mixed-matrix membranes was improved by either keeping the selectivity constant and increasing the permeability (MOF-5, Cu-MOF) or by improving both selectivity and permeability (ZIF-8). In the case of MOF-5/Matrimid{reg_sign} mixed-matrix membranes, the H{sub 2}/CO{sub 2} selectivity was kept at 2.6 and the H{sub 2} permeability increased from 24.4 to 53.8 Barrers. For the Cu-MOF/Matrimid{reg_sign} mixed-matrix membranes, the H{sub 2}/CO{sub 2} selectivity was kept at 2.05 and the H{sub 2} permeability increased from 17.1 to 158 Barrers. These two materials introduced porosity and uniform paths that enhanced the gas transport in the membranes. When ZIF-8/Matrimid{reg_sign} mixed-matrix membranes were studied, the H{sub 2}/CO{sub 2} selectivity increased from 2.9 to 4.4 and the permeability of H{sub 2} increased from 26.5 to 35.8 Barrers. The increased H{sub 2}/CO{sub 2} selectivity in ZIF-8/Matrimid{reg_sign} membranes was explained by the sieving effect introduced by the ZIF-8 crystals (pore window 0.34 nm) that restricted the transport of molecules larger than H{sub 2}. Materials with microporous and/or mesoporous cavities like carbon aerogel composites with zeolite A and zeolite Y, and membranes containing mesoporous ZSM-5 showed sieving effects for small molecules (e.g. H{sub 2} and CO{sub 2}), however, the membranes were most selective for CO{sub 2} due to the strong interaction of the zeolites with CO{sub 2}. For example, at 30 wt% ZSM-5 loading, the CO{sub 2}/CH{sub 4} selectivity increased from 34.7 (Matrimid{reg_sign}) to 56.4. The large increase in selectivity was the result of the increase in CO{sub 2} permeability from 7.3 (Matrimid{reg_sign}) to 14.6 Barrers. At 30 wt% ZSM-5 loading, the H{sub 2}/CH{sub 4} separation was also improved from 83.3 (Matrimid{reg_sign}) to 136.7 with an increase in H{sub 2} permeability from 17.5 (Matrimid{reg_sign}) to 35.3 Barrers. The 10% carbon aerogel-zeolite A and -zeolite Y composite/Matrimid{reg_sign} membranes exhibited an increase in the CO{sub 2}/CH{sub 4} separation from 34.7 to 71.5 (zeolite A composite) and to 57.4 (zeolite Y composite); in addition, the membrane exhibited an increase in the CO{sub 2}/N{sub 2} separation from 33.1 to 50 (zeolite A composite) and to 49.4 (zeolite Y composite), indicating that these type of materials have affinity for CO{sub 2}. The inclusion of mesoporosity enhanced the dispersion of the additive allowing loadings of up to 30% (w/w) without the formation of non-selective voids.

Inga Musselman; Kenneth Balkus, Jr.; John Ferraris

2009-01-07T23:59:59.000Z

48

Novel theoretical and experimental approaches for understanding and optimizing hydrogen-sorbent interactions in metal organic framework materials - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

3 3 FY 2012 Annual Progress Report DOE Hydrogen and Fuel Cells Program Yves. J. Chabal (Primary Contact), Jing Li, Timo Thonhauser UT Dallas - Department of Materials Science and Engineering 800 W. Campbell Road, RL 10 Richardson, TX 75080 Phone: (972) 883-5751 Email: chabal@utdallas.edu DOE Program Officer: Dr. Bonnie Gersten Phone: (301) 903-0002 Email: Bonnie.Gersten@science.doe.gov Subcontractors: * Jing Li (Rutgers University) * Timo Thonhauser (Wake Forest University) Objectives Develop a * comprehensive understanding of how small molecules (e.g. H 2 ) bind inside metal organic framework

49

Microporous Metal Organic Materials for Hydrogen Storage  

DOE Green Energy (OSTI)

We have examined a number of Metal Organic Framework Materials for their potential in hydrogen storage applications. Results obtained in this study may, in general, be summarized as follows: (1) We have identified a new family of porous metal organic framework materials with the compositions M (bdc) (ted){sub 0.5}, {l_brace}M = Zn or Co, bdc = biphenyl dicarboxylate and ted = triethylene diamine{r_brace} that adsorb large quantities of hydrogen ({approx}4.6 wt%) at 77 K and a hydrogen pressure of 50 atm. The modeling performed on these materials agree reasonably well with the experimental results. (2) In some instances, such as in Y{sub 2}(sdba){sub 3}, even though the modeling predicted the possibility of hydrogen adsorption (although only small quantities, {approx}1.2 wt%, 77 K, 50 atm. hydrogen), our experiments indicate that the sample does not adsorb any hydrogen. This may be related to the fact that the pores are extremely small or may be attributed to the lack of proper activation process. (3) Some samples such as Zn (tbip) (tbip = 5-tert butyl isophthalate) exhibit hysteresis characteristics in hydrogen sorption between adsorption and desorption runs. Modeling studies on this sample show good agreement with the desorption behavior. It is necessary to conduct additional studies to fully understand this behavior. (4) Molecular simulations have demonstrated the need to enhance the solid-fluid potential of interaction in order to achieve much higher adsorption amounts at room temperature. We speculate that this may be accomplished through incorporation of light transition metals, such as titanium and scandium, into the metal organic framework materials.

S. G. Sankar; Jing Li; Karl Johnson

2008-11-30T23:59:59.000Z

50

Organic metal neutron detector  

DOE Patents (OSTI)

A device for detection of neutrons comprises: as an active neutron sensing element, a conductive organic polymer having an electrical conductivity and a cross-section for said neutrons whereby a detectable change in said conductivity is caused by impingement of said neutrons on the conductive organic polymer which is responsive to a property of said polymer which is altered by impingement of said neutrons on the polymer; and means for associating a change in said alterable property with the presence of neutrons at the location of said device.

Butler, M.A.; Ginley, D.S.

1984-11-21T23:59:59.000Z

51

Characterizing Hydrogen Storage Media: Understanding the Interior Pore Structure of a Cu3BTC2 Metal-Organic Framework Infiltrated with NaAlH4  

DOE Green Energy (OSTI)

Preliminary results support the nano-confinement of sodium alanate within the pores of a Cu{sub 3}BTC{sub 2} MOF substrate. Increased {sup 1}H and {sup 27}Al NMR T{sub 1} relaxation rates indicate a close proximity of infiltrated sodium alante to the paramagnetic Cu{sup 2+} ions on the BTC paddlewheel units. This is in support of the theory that an interaction due to the electronegative framework with the sodium alanate facilitates thermodynamically-favorable hydrogen adsorption and desorption. Further studies can elucidate the local electronic environment of the sodium ions, further supporting a charge-transfer mechanism as the driving force for thermodynamically-favorable hydrogen adsorption and desorption.

Kirmiz, A; Bhakta, R K; Allendorf, M D; Majzoub, E H; Behrens, R; Herberg, J

2010-04-15T23:59:59.000Z

52

A Neo-Rumsfeldian Framework for the Thermodynamics of Organic...  

NLE Websites -- All DOE Office Websites (Extended Search)

Neo-Rumsfeldian Framework for the Thermodynamics of Organic Particulate Matter Formation in the Atmosphere: Successes and Challenges Speaker(s): James F. Pankow Date: March 6, 2008...

53

Postsynthetic modification of metal-organic frameworks  

E-Print Network (OSTI)

ca. Calculated CAT Catechol CDCl 3 Deuterated chloroformacid (CAT-BDC, CAT = catechol, 5) were selected as thebe consistent with known Fe 3+ catechol complexes (Figure 6-

Tanabe, Kristine Kimie

2011-01-01T23:59:59.000Z

54

Method of stripping metals from organic solvents  

DOE Patents (OSTI)

A new method to strip metals from organic solvents in a manner that allows for the recycle of the stripping agent. The method utilizes carbonate solutions of organic amines with complexants, in low concentrations, to strip metals from organic solvents. The method allows for the distillation and reuse of organic amines. The concentrated metal/complexant fraction from distillation is more amenable to immobilization than solutions resulting from current practice.

Todd, Terry A. (Aberdeen, ID); Law, Jack D. (Pocatello, ID); Herbst, R. Scott (Idaho Falls, ID); Romanovskiy, Valeriy N. (St. Petersburg, RU); Smirnov, Igor V. (St.-Petersburg, RU); Babain, Vasily A. (St-Petersburg, RU); Esimantovski, Vyatcheslav M. (St-Petersburg, RU)

2009-02-24T23:59:59.000Z

55

A framework for formal modeling and analysis of organizations  

Science Conference Proceedings (OSTI)

A new, formal, role-based, framework for modeling and analyzing both real world and artificial organizations is introduced. It exploits static and dynamic properties of the organizational model and includes the (frequently ignored) environment. The transition ... Keywords: Analysis, Computational, Logic-based, Modeling, Organization model, Simulation, Verification

Catholijn M. Jonker; Alexei Sharpanskykh; Jan Treur; Pinar Yolum

2007-08-01T23:59:59.000Z

56

Chemistry and Applications of Metal-Organic Materials  

E-Print Network (OSTI)

Developing the synthetic control required for the intentional 3-D arrangement of atoms remains a holy grail in crystal engineering and materials chemistry. The explosive development of metal-organic materials in recent decades has shed light on the above problem. Their properties can be tuned by varying the organic and/or inorganic building units. In addition, their crystallinity makes it possible to determine their structures via the X-ray diffraction method. This dissertation will focus on the chemistry and applications of two kinds of metal-organic materials, namely, metal-organic frameworks (MOFs) and metal-organic polyhedra (MOP). MOFs are coordination polymers. Their permanent porosity makes them a good “gas sponge”. In the first section, an isoreticular series of MOFs with dendritic hexacarboxylate ligands has been synthesized and characterized structurally. One of the MOFs in this series, PCN-68, has a Langmuir surface area as high as 6033 m2 g-1. The MOFs also possess excellent gas (H2, CH4, and CO2) adsorption capacity. In the second section, a NbO-type MOF, PCN-46, was constructed based on a polyyne-coupled di-isophthalate linker formed in situ. Its lasting porosity was confirmed by N2 adsorption isotherm, and its H2, CH4 and CO2 adsorption capacity was examined at 77 K and 298 K over a wide pressure range (0-110 bar). Unlike MOFs, MOP are discrete porous coordination nanocages. In the third section, a MOP covered with bulky triisopropylsilyl group was synthesized, which exhibits a thermosensitive gate opening property. This material demonstrates a molecular sieving effect at a certain temperature range, which could be used for gas separation purpose. In the last section, a MOP covered with alkyne group was synthesized through kinetic control. The postsynthetic modification via click reaction with azide-terminated polyethylene glycol turned them into metallomicelles, which showed controlled release of an anticancer drug 5-fluorouracil. In summary, two kinds of metal-organic materials have been discussed in this dissertation, with the applications in gas storage, gas separation, and drug delivery. These findings greatly enrich the chemistry and applications of metal-organic materials.

Zhao, Dan

2010-12-01T23:59:59.000Z

57

Metal-doped organic gels and method thereof  

DOE Patents (OSTI)

Disclosed herein is a sol-gel polymerization process for synthesizing metal-doped organic gels. The process polymerizes metal salts of hydroxylated benzenes or hydroxylated benzene derivatives with alkyl or aryl aldehydes to form metal-doped, wet, organic gels. The gels can then be dried by supercritical solvent extraction to form metal-doped aerogels or by evaporation to form metal-doped xerogels. The aerogels and xerogels can then be pyrolyzed.

Satcher, Jr., Joe H. (Patterson, CA); Baumann, Theodore F. (Tracy, CA)

2007-10-23T23:59:59.000Z

58

Gas Adsorption in Metal Organic Frameworks : an experiment ...  

Science Conference Proceedings (OSTI)

... Liquefied natural gas (LNG) must be cooled to –162 oC. LNG requires only 30 percent of the space of CNG to store the same amount of energy. ...

2009-09-15T23:59:59.000Z

59

Gas Adsorption in Metal Organic Frameworks: an experiment ...  

Science Conference Proceedings (OSTI)

... In this type of instrument (figure 3) bursts of monochromatic neutrons ... source is cleaned of high energy neutron and gamma ray contamination using ...

2007-05-31T23:59:59.000Z

60

Selected Metal Organic Framework and Molecular Sieve Materials ...  

Science Conference Proceedings (OSTI)

Symposium, Materials for CO2 Capture and Conversion ... Abstract Scope, Reduction of CO2 emissions from coal-burning power plants using ...

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Available Technologies: Modified Metal Organic Framework (MOF) as ...  

APPLICATIONS OF TECHNOLOGY: Lithium-ion batteries for electric vehicles and consumer electronics ; ADVANTAGES: Safer; Reduces battery weight; Improved conductivity

62

Improved Design of Metal-Organic Framework Family for Efficient ...  

Science Conference Proceedings (OSTI)

Microstructural Evolution of SnS Thin Films Grown by Electrodeposition · Morphology Engineering of 1D, 2D and 3D TiO2 Nanostructures and Their Application ...

63

Argonne scientists squeeze more out of metal-organic framework...  

NLE Websites -- All DOE Office Websites (Extended Search)

a diamond anvil cell next to collaborating scientists Peter Chupas and Gregory Halder. Argonne scientist Karena Chapman holds a diamond anvil cell next to collaborating scientists...

64

Development of New Biphasic Metal Organic Working Fluids for Subcritical  

Open Energy Info (EERE)

Biphasic Metal Organic Working Fluids for Subcritical Biphasic Metal Organic Working Fluids for Subcritical Geothermal Systems Geothermal Lab Call Project Jump to: navigation, search Last modified on July 22, 2011. Project Title Development of New Biphasic Metal Organic Working Fluids for Subcritical Geothermal Systems Project Type / Topic 1 Laboratory Call for Submission of Applications for Research, Development and Analysis of Geothermal Technologies Project Type / Topic 2 Working Fluids for Binary Power Plants Project Description In binary-cycle plants the cycle efficiency improves as pumping energy is reduced and from maximizing the enthalpy gain of the working fluid for a given amount of heat extracted from the geothermal source brine. Enthalpy gain of the working fluid in the heat exchanger occurs principally from sensible heat gained while passing through the heat exchanger in the liquid state and from vaporization of the organic working fluid near the exit of the heat exchanger. Additional heat transfer is limited after the vapor phase transition due the low thermal conductivity and heat capacity of the vapor. Also, operating pressures and temperatures are constrained by the bulk phase behavior and thermodynamic properties of the working fluid (boiling point, latent heat of vaporization, density, heat capacity, etc.). The fundamental underlying goal of this project is to overcome the cycle efficiency limitations imposed by the bulk thermodynamic proper-ties of the working fluid by introducing a metal-organic heat carrier (MOHC) into the system.

65

Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy  

E-Print Network (OSTI)

Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks projects aimed at using hydrogen as a clean fuel for automobiles and producing clean energy by designing achieve higher storage capacities for hydrogen, (1) (a) Leaf, D.; Verolmec, H. J. H.; Hunt, W. F., Jr. En

Yaghi, Omar M.

66

Short-Term Metal/Organic Interface Stability Investigations of Organic Photovoltaic Devices: Preprint  

DOE Green Energy (OSTI)

This paper addresses one source of degradation in OPV devices: the metal/organic interface. The basic approach was to study the completed device stability vs. the stability of the organic film itself as shown in subsequent devices fabricated from the films.

Reese, M. O.; Morfa, A. J.; White, M. S.; Kopidakis, N.; Shaheen, S. E.; Rumbles, G.; Ginley, D. S.

2008-05-01T23:59:59.000Z

67

A Neo-Rumsfeldian Framework for the Thermodynamics of Organic Particulate  

NLE Websites -- All DOE Office Websites (Extended Search)

A Neo-Rumsfeldian Framework for the Thermodynamics of Organic Particulate A Neo-Rumsfeldian Framework for the Thermodynamics of Organic Particulate Matter Formation in the Atmosphere: Successes and Challenges Speaker(s): James F. Pankow Date: March 6, 2008 - 12:00pm Location: 90-3122 James F. Pankow. The thermodynamic principles according to which organic particulate matter (OPM) forms in the atmosphere have become well identified because of research progress made since about the mid 1990s. These are, ahem, known knowns. However, many unknowns exist regarding the concentrations and chemical characteristics of the biogenic and anthropogenic compounds present in the atmosphere that are important in OPM formation. In this context, since we know what we need to know more about, these are, well, known unknowns. Other known important unknowns are

68

Use of metal organic fluors for spectral discrimination of neutrons and gammas.  

Science Conference Proceedings (OSTI)

A new method for spectral shape discrimination (SSD) of fast neutrons and gamma rays has been investigated. Gammas interfere with neutron detection, making efficient discrimination necessary for practical applications. Pulse shape discrimination (PSD) in liquid organic scintillators is currently the most effective means of gamma rejection. The hazardous liquids, restrictions on volume, and the need for fast timing are drawbacks to traditional PSD scintillators. In this project we investigated harvesting excited triplet states to increase scintillation yield and provide distinct spectral signatures for gammas and neutrons. Our novel approach relies on metal-organic phosphors to convert a portion of the energy normally lost to the scintillation process into useful luminescence with sub-microsecond lifetimes. The approach enables independent control over delayed luminescence wavelength, intensity, and timing for the first time. We demonstrated that organic scintillators, including plastics, nanoporous framework materials, and oil-based liquids can be engineered for both PSD and SSD.

Allendorf, Mark D.; Doty, F. Patrick; Feng, Patrick L.

2010-09-01T23:59:59.000Z

69

Composites for removing metals and volatile organic compounds and method thereof  

DOE Patents (OSTI)

Functionalized hydrophobic aerogel/solid support structure composites have been developed to remove metals and organic compounds from aqueous and vapor media. The targeted metals and organics are removed by passing the aqueous or vapor phase through the composite which can be in molded, granular, or powder form. The composites adsorb the metals and the organics leaving a purified aqueous or vapor stream. The species-specific adsorption occurs through specific functionalization of the aerogels tailored towards specific metals and/or organics. After adsorption, the composites can be disposed of or the targeted metals and/or organics can be reclaimed or removed and the composites recycled.

Coronado, Paul R. (Livermore, CA); Coleman, Sabre J. (Oakland, CA); Reynolds, John G. (San Ramon, CA)

2006-12-12T23:59:59.000Z

70

Vapor-Phase Metalation by Atomic Layer Deposition in a Metal-Organic Framework  

E-Print Network (OSTI)

encompass deposition onto micro- and nanopowders14 and coating of nanoparticle films15 as well as aerogel coating of porous materials that exhibit ultrahigh-aspect ratios.12,13 To date, some striking examples

71

Thin films by metal-organic precursor plasma spray  

Science Conference Proceedings (OSTI)

While most plasma spray routes to coatings utilize solids as the precursor feedstock, metal-organic precursor plasma spray (MOPPS) is an area that the authors have investigated recently as a novel route to thin film materials. Very thin films are possible via MOPPS and the technology offers the possibility of forming graded structures by metering the liquid feed. The current work employs metal-organic compounds that are liquids at standard temperature-pressure conditions. In addition, these complexes contain chemical functionality that allows straightforward thermolytic transformation to targeted phases of interest. Toward that end, aluminum 3,5-heptanedionate (Al(hd){sub 3}), triethylsilane (HSi(C{sub 2}H{sub 5}){sub 3} or HSiEt{sub 3}), and titanium tetrakisdiethylamide (Ti(N(C{sub 2}H{sub 5}){sub 2}){sub 4} or Ti(NEt{sub 2}){sub 4}) were employed as precursors to aluminum oxide, silicon carbide, and titanium nitride, respectively. In all instances, the liquids contain metal-heteroatom bonds envisioned to provide atomic concentrations of the appropriate reagents at the film growth surface, thus promoting phase formation (e.g., Si-C bond in triethylsilane, Ti-N bond in titanium amide, etc.). Films were deposited using a Sulzer Metco TriplexPro-200 plasma spray system under various experimental conditions using design of experiment principles. Film compositions were analyzed by glazing incidence x-ray diffraction and elemental determination by x-ray spectroscopy. MOPPS films from HSiEt{sub 3} showed the formation of SiC phase but Al(hd){sub 3}-derived films were amorphous. The Ti(NEt{sub 2}){sub 4} precursor gave MOPPS films that appear to consist of nanosized splats of TiOCN with spheres of TiO{sub 2} anatase. While all films in this study suffered from poor adhesion, it is anticipated that the use of heated substrates will aid in the formation of dense, adherent films.

Schulz, Douglas L.; Sailer, Robert A.; Payne, Scott; Leach, James; Molz, Ronald J. [North Dakota State University, Fargo, North Dakota 58108-6050 (United States); Sulzer Metco (United States) Inc., Westbury, New York 11590-2724 (United States)

2009-07-15T23:59:59.000Z

72

A framework for organizing the space of decision problems with application to solving subjective, context-dependent problems  

Science Conference Proceedings (OSTI)

Developing Decision Support Systems (DSS) is a difficult task, prone to errors and susceptible to colossal failures. In order to alleviate this difficulty and its consequences, we propose a framework for organizing the space of decision problems based ... Keywords: Case-based reasoning, Clustering, Decision problems characteristics, Influence knowledge graph, Software development

Yoram Reich; Adi Kapeliuk

2005-11-01T23:59:59.000Z

73

Using atmospheric fallout to date organic horizon layers and quantify metal dynamics during decomposition  

E-Print Network (OSTI)

Using atmospheric fallout to date organic horizon layers and quantify metal dynamics during- tribution of geochemical tracers from weapons fallout, air pollution, and a direct 207 Pb application at one

Heimsath, Arjun M.

74

Metal-Containing Organic and Carbon Aerogels for Hydrogen Storage  

SciTech Connect

This document and the accompanying manuscript summarize the technical accomplishments of our one-year LDRD-ER effort. Hydrogen storage and hydrogen fuel cells are important components of the 2003 Hydrogen Fuel Initiative focused on the reduction of America's dependence on oil. To compete with oil as an energy source, however, one must be able to transport and utilize hydrogen at or above the target set by DOE (6 wt.% H{sub 2}) for the transportation sector. Other than liquid hydrogen, current technology falls well short of this DOE target. As a result, a variety of materials have recently been investigated to address this issue. Carbon nanostructures have received significant attention as hydrogen storage materials due to their low molecular weight, tunable microporosity and high specific surface areas. For example, the National Renewable Energy Laboratory (NREL) achieved 5 to 10 wt.% H{sub 2} storage using metal-doped carbon nanotubes. That study showed that the intimate mix of metal nanoparticles with graphitic carbon resulted in the unanticipated hydrogen adsorption at near ambient conditions. The focus of our LDRD effort was the investigation of metal-doped carbon aerogels (MDCAs) as hydrogen storage materials. In addition to their low mass densities, continuous porosities and high surface areas, these materials are promising candidates for hydrogen storage because MDCAs contain a nanometric mix of metal nanoparticles and graphitic nanostructures. For FY04, our goals were to: (1) prepare a variety of metal-doped CAs (where the metal is cobalt, nickel or iron) at different densities and carbonization temperatures, (2) characterize the microstructure of these materials and (3) initiate hydrogen adsorption/desorption studies to determine H2 storage properties of these materials. Since the start of this effort, we have successfully prepared and characterized Ni- and Co-doped carbon aerogels at different densities and carbonization temperatures. The bulk of this work is described in the attached manuscript entitled 'Formation of Carbon Nanostructures in Cobalt- and Nickel- Doped Carbon Aerogels'. This one-year effort has lead to our incorporation into the DOE Carbon-based Hydrogen Storage Center of Excellence at NREL, with funding from DOE's Energy Efficiency and Renewable Energy (EERE) Program starting in FY05.

Satcher, Jr., J H; Baumann, T F; Herberg, J L

2005-01-10T23:59:59.000Z

75

Metal speciation in landfill leachates with a focus on the influence of organic matter  

SciTech Connect

Highlights: > This study characterises the heavy-metal content in leachates collected from eight landfills in France. > Most of the metals are concentrated in the <30 kDa fraction, while Pb, Cu and Cd are associated with larger particles. > Metal complexation with OM is not sufficient to explain apparent supersaturation of metals with sulphide minerals. - Abstract: This study characterises the heavy-metal content in leachates collected from eight landfills in France. In order to identify heavy metal occurrence in the different size fractions of leachates, a cascade filtration protocol was applied directly in the field, under a nitrogen gas atmosphere to avoid metal oxidation. The results of analyses performed on the leachates suggest that most of the metals are concentrated in the <30 kDa fraction, while lead, copper and cadmium show an association with larger particles. Initial speciation calculations, without considering metal association with organic matter, suggest that leachate concentrations in lead, copper, nickel and zinc are super-saturated with respect to sulphur phases. Speciation calculations that account for metal complexation with organic matter, considered as fulvic acids based on C1(s) NEXAFS spectroscopy, show that this mechanism is not sufficient to explain such deviation from equilibrium conditions. It is therefore hypothesized that the deviation results also from the influence of biological activity on the kinetics of mineral phase precipitation and dissolution, thus providing a dynamic system. The results of chemical analyses of sampled fluids are compared with speciation calculations and some implications for the assessment of metal mobility and natural attenuation in a context of landfill risk assessment are discussed.

Claret, Francis, E-mail: f.claret@brgm.fr [BRGM, 3 avenue C. Guillemin, BP 6009, 45060 Orleans (France); Tournassat, Christophe; Crouzet, Catherine; Gaucher, Eric C. [BRGM, 3 avenue C. Guillemin, BP 6009, 45060 Orleans (France); Schaefer, Thorsten [Karlsruhe Institute of Technology (KIT), Institute for Nuclear Waste Disposal (INE), P.O. Box 3640, 76021 Karlsruhe (Germany); Freie Universitaet Berlin, Institute of Geological Sciences, Department of Earth Sciences, Hydrogeology Group, D-12249 Berlin (Germany); Braibant, Gilles; Guyonnet, Dominique [BRGM, 3 avenue C. Guillemin, BP 6009, 45060 Orleans (France)

2011-09-15T23:59:59.000Z

76

Trace metal contamination of waters, sediments, and organisms of the Swan Lake area of Galveston Bay  

E-Print Network (OSTI)

Swan Lake is a sub-bay of the Galveston Bay system. The area received runoff from a tin smelter via the Wah Chang Ditch which ran through it in the past but the ditch is now cut off by a hurricane protection levee. An industrial waste disposal facility (Gulf Coast Waste Disposal Authority) is located north of the Wah Chang Ditch. Consequently there have been concerns about possible metal contamination in this area. I determined trace metal concentrations in water, sediments, and organisms (oyster, mussel, snail, crab, fish, shrimp, and spartina) in the area. Sediments and organisms were analyzed for total Ag, Al, As, Cd, Cu, Fe, Hg, Mn, Ni, Pb, Se, Sn, and Zn. Water samples were analyzed for Cd, Cu, Fe, Mn, and Sn. The variabilities and geographic trends in sediment trace metals indicated that waste disposal and airborne inputs from facilities located at the Tex Tin site were likely sources for metal pollution found in the sediments. Sediments in the study area showed elevated trace metals relative to Galveston Bay and other Texas bay sediments. Three different samplings of the Wah Chang Ditch showed no temporal patterns in metal distribution in the sediments. Lead especially was uniformly high on the three different trips, respectively averaging 1250 (Trip 1), 893 (Trip H), and 1350 ppm (Trip V). Metal enrichments at depth in the sediment column indicated that the Swan Lake area has recently received less input of metal contaminated sediment than in the past. Anthropogenic inputs did not greatly influence the natural concentrations of Fe, Al, and Ni in sediments either in the past or at present. Most organisms showed very small spatial variations. However, the oysters in Swan Lake are enriched in most metals relative to Galveston Bay and other U. S. Gulf of Mexico oysters. The mussels in this study do not reflect the unusually elevated environmental metal concentration in the sediments from which they were taken. Iron and Pb concentrations in oysters seemed to be directly related to sediment concentrations at each location. Oysters show higher concentrations in most metals than those in mussels. The Zn level was II 3 times higher in oysters. For organisms collected from the Swan Lake area trace metal concentrations were generally in the order oysters > snail > crab > shrimp > fish. Metal concentrations in Wah Chang Ditch water were very elevated relative to those of the Brazos River and Galveston Bay and closely reflect those in sediments of the Wah Chang Ditch.

Park, Junesoo

1995-01-01T23:59:59.000Z

77

Carbon Dioxide Adsorption by Metal Organic Frameworks (Synthesis, Testing and Modeling).  

E-Print Network (OSTI)

??It is essential to capture carbon dioxide from flue gas because it is considered one of the main causes of global warming. Several materials and… (more)

Sabouni, Rana

2013-01-01T23:59:59.000Z

78

Multistep N2 Breathing in the Metal-Organic Framework Co(1,4-benzenedipyrazolate)  

E-Print Network (OSTI)

and in harmony with recent numerical simulations [20]. There is a surprise, however. Numerical [6., Thermochim. Acta, 238 (1994) 277. See also Modu- lated DSC, document TA210, T.A. Instruments, Inc., New

79

Homochiral 3D Metal-Organic Frameworks from Chiral 1D Rods: 6 – Way Helical Packing  

Science Conference Proceedings (OSTI)

The chiral 3D MOFs resulted from the packing of chiral 1D SBBs were studied. It was demonstrated that the final packing pattern is dependent on the dimension of SBB's. In addition, we were able to identify a new plywood-like network from ligand 2H2 exhibiting an unprecedented six-way chiral helical packing motif, which can be added on the list of invariant rod packings.

Shin, Sung M.; Moon, Dohyun; Jeong, Kyung S.; Kim, Jaheon; Thallapally, Praveen K.; Jeong, Nakcheol

2011-07-20T23:59:59.000Z

80

Computational study of hydrocarbon adsorption in metal-organic framework Ni2(dhtp)  

SciTech Connect

Molecular dynamic simulations were carried out to study the sorption, structural properties, and diffusivities of n-hexane and cyclohexane adsorbed in Ni2(dhtp). The results indicated strong interactions between the alkanes and the host material. The free energy perturbation method was employed to investigate the adsorption free energies of methane, ethane, n-butane, n-hexane and cyclohexane. For linear alkanes, the free energy lowered as the length of the carbon chain increased. Also, the adsorption of n-hexane was preferred over cyclohexane, due to its ability to rearrange its structure to maximize contacts with the host. Furthermore, due to the large pore size of Ni2(dhtp), higher loadings of alkanes did not significantly affect the alkane structure, and enhanced the free energy of adsorption for subsequent alkanes being loaded. According to our studies, Ni2(dhtp) has a very promising potential for adsorption and storage of alkanes. This work was supported by the US Department of Energy Basic Energy Sciences' Chemical Sciences, Geosciences & Biosciences Division. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

Sun, Xiuquan; Wick, Collin D.; Thallapally, Praveen K.; McGrail, B. Peter; Dang, Liem X.

2011-03-31T23:59:59.000Z

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Role of natural organic matter in governing the bioavailability of toxic metals to american oysters  

E-Print Network (OSTI)

Colloidal macromolecular organic matter (COM), which makes up a large portion of the bulk dissolved organic matter (DOM) in marine environments, has the capability to modify the bioavailability of potentially toxic metals to aquatic organisms. In order to better understand the bioavailability of some of these metals to estuarine bivalves, American Oysters (Crassostrea virginica) were exposed to different types of natural colloidal (COM) and model (alginic acid, carrageenan, and latex particles) organic biopolymers, tagged with gamma-emitting radioactive metal ions (110mAg, 109Cd, 57Co, 51Cr, 59Fe, 203Hg and 65Zn) or 14C (to sugar OH groups). Natural COM was obtained from Galveston Bay water by 0.5µm filtration, followed by cross-flow ultrafiltration, using a 1kDa ultrafilter, diafiltration and freeze-drying. COM and DOM model compounds were used in the bioavailability experiments at 2 ppm concentrations. Separate 16-hour experiments using varying sizes of latex particles assessed the lowest size of colloids that can be filtered from the water. Results showed that filter-feeding bivalves could efficiently remove particles as small as 0.04µm (40nm) in diameter, with removal halftimes of 2.5 to 5.5 hours, equivalent to filtration rates of about 50±15 ml/hour, or about 3 L d-1 g-1, which are typical values for these oysters. Results of the 20-hour bioavailability experiments demonstrated that oysters could effectively filter metals bound to COM, with the metals bound to alginic acid COM being removed at the highest rates from the water. However, the metals bound to alginic acid were not found in oyster meat in the highest amounts: it was the metals associated with the carrageenan COM. The 14C labeled biopolymer data also showed alginic acid to be removed from the water at the highest rate and, contrary to the metals, was also present in the meat in the greatest amounts. Thus, while previous experiments suggested that the quantity (i.e., concentration) of natural organic matter is important for metal bioavailability, it was shown here that the �quality�, i.e., the type of natural organic matter, is also a factor for controlling bioavailability, removal and incorporation rates of metals to oysters.

Haye, Jennifer Marcelle

2005-05-01T23:59:59.000Z

82

The enterprise architecting framework applied to the supply organization of a sourcing management center of excellence  

E-Print Network (OSTI)

The basis to develop this thesis was performed after executing an internship in ABB Inc. The main objective of the study was to design the organization to operate the procurement function at a new manufacturing campus.The ...

Villegas Kavanagh, Leon Felipe

2008-01-01T23:59:59.000Z

83

Impact of Post-Synthesis Modification of Nanoporous Organic Frameworks on Selective Carbon Dioxide Capture.  

E-Print Network (OSTI)

??Porous organic polymers containing nitrogen-rich building units are among the most promising materials for selective CO2 capture and separation applications that impact the environment and… (more)

?slamo?lu, Timur

2013-01-01T23:59:59.000Z

84

Metal Speciation in Landfill Leachates with a Focus on the Influence of Organic Matter  

SciTech Connect

This study characterizes the heavy-metal content in leachates collected from eight landfills in France. In order to identify heavy metal occurrence in the different size fractions of leachates, a cascade filtration protocol was applied directly in the field, under a nitrogen gas atmosphere to avoid metal oxidation. The results of analyses performed on the leachates suggest that most of the metals are concentrated in the <30 kDa fraction, while lead, copper and cadmium show an association with larger particles. Initial speciation calculations, without considering metal association with organic matter, suggest that leachate concentrations in lead, copper, nickel and zinc are super-saturated with respect to sulphur phases. Speciation calculations that account for metal complexation with organic matter, considered as fulvic acids based on C1(s) NEXAFS spectroscopy, show that this mechanism is not sufficient to explain such deviation from equilibrium conditions. It is therefore hypothesized that the deviation results also from the influence of biological activity on the kinetics of mineral phase precipitation and dissolution, thus providing a dynamic system. The results of chemical analyses of sampled fluids are compared with speciation calculations and some implications for the assessment of metal mobility and natural attenuation in a context of landfill risk assessment are discussed.

F Claret; C Tournassat; C Crouzet; E Gaucher; T Schäfer; G Braibant; D Guyonnet

2011-12-31T23:59:59.000Z

85

Anthraquinone with Tailored Structure for Nonaqueous Metal-Organic Redox Flow Battery  

Science Conference Proceedings (OSTI)

A nonaqueous, hybrid metal-organic redox flow battery based on tailored anthraquinone structure is demonstrated to have an energy efficiency of {approx}82% and a specific discharge energy density similar to aqueous redox flow batteries, which is due to the significantly improved solubility of anthraquinone in supporting electrolytes.

Wang, Wei; Xu, Wu; Cosimbescu, Lelia; Choi, Daiwon; Li, Liyu; Yang, Zhenguo

2012-06-08T23:59:59.000Z

86

Surface functionalization of metal?organic polyhedron for homogeneous cyclopropanation catalysis  

Science Conference Proceedings (OSTI)

A super-paddlewheel (comprised of two paddlewheels) metal-organic polyhedron (MOP) containing surface hydroxyl groups was synthesized and characterized. Condensation reactions with linear alkyl anhydrides lead to new MOPs with enhanced solubility. As a result, the surface-modified MOP 4 was demonstrated as a homogeneous Lewis-acid catalyst.

Lu, Weigang; Yuan, Daqiang; Yakovenko, Andrey; Zhou, Hong-Cai (TAM)

2012-03-13T23:59:59.000Z

87

Metal-organic scintillator crystals for X-ray, gamma ray, and neutron detection  

DOE Patents (OSTI)

New metal-organic materials are useful as scintillators and have the chemical formula LX.sub.3(CH.sub.3OH).sub.4 where L is Y, Sc, or a lanthanide element, and X is a halogen element. An example of the scintillator materials is CeCl.sub.3(CH.sub.3OH).sub.4.

Boatner, Lynn A (Oak Ridge, TN); Kolopus, James A. (Clinton, TN); Neal, John S (Knoxville, TN); Ramey, Joanne Oxendine (Knoxville, TN); Wisniewski, Dariusz J (Torun, PL)

2012-01-03T23:59:59.000Z

88

Effect Of Solid Phase Organic Substrate Characteristics On Sulfate Reducer Activity And Metal Removal  

E-Print Network (OSTI)

Abstract. This paper is a progress report on studies whose objectives are to determine methods of analysis that will rate metal sorption and sulfate reduction activity of organic materials for use in passive treatment systems (PTS). Substrates tested include agricultural residues (alfalfa pellets, sugar beat pulp pellets, brewery waste, corncobs, and walnut hulls), inoculums (dairy manure and wetland inoculum), and a variety woods (maple, oak, pine, poplar, and walnut). Characteristics targeted include moisture, organic and nutrient content; water, ethanol and acid soluble and insoluble fractions and metal sorption capacity. The short-term and long-term effects of organic substrate characteristics on metal removal and sulfate reduction rate are being evaluated in batch and column experiments receiving mine water. These data are not presented in this paper but will be included in the oral presentation. Measured values of moisture and organic content ranged from 5.5 to 65 % and 7.4 to 95 % relative to raw sample weights, respectively. The water-soluble fractions and protein content ranged from 0 to 32 % and 2 to 23 % relative to dried samples, respectively. Low concentration zinc sorption studies were described well by Freundlich isotherms. Using a wider range of concentrations, manganese sorption to substrates was more closely modeled by Langmuir isotherms. The highest manganese sorption was observed for manure, corncobs, walnut hulls and wetland inoculum (8-13 mg Mn / gram substrate at an equilibrium concentration (Ce) = 50 mg/L Mn). Corncobs and walnut hulls can be included in substrate specifications to target manganese removal. Moisture and organic content are important parameters in the specification of organic substrates as a significant portion of the raw organic substrate weight can be inorganic. A high soluble fraction should correlate with a rapid startup of SRB activity and thus is an important element in substrate specification. All substrates have some capacity for metal sorption and their quantification is essential for use in PTS.

J. Seyler; L. Figueroa; D. Ahmann; T. R. Wildeman; M. Robustelli

2003-01-01T23:59:59.000Z

89

Preparation of functionalized zeolitic frameworks  

DOE Patents (OSTI)

The disclosure provides zeolitic frameworks for gas separation, gas storage, catalysis and sensors. More particularly the disclosure provides zeolitic frameworks (ZIFs). The ZIF of the disclosure comprises any number of transition metals or a homogenous transition metal composition.

Yaghi, Omar M; Hayashi, Hideki; Banerjee, Rahul; Park, Kyo Sung; Wang, Bo; Cote, Adrien P

2012-11-20T23:59:59.000Z

90

Preparation of functionalized zeolitic frameworks  

DOE Patents (OSTI)

The disclosure provides zeolitic frameworks for gas separation, gas storage, catalysis and sensors. More particularly the disclosure provides zeolitic frameworks (ZIFs). The ZIF of the disclosure comprises any number of transition metals or a homogenous transition metal composition.

Yaghi, Omar M; Furukawa, Hiroyasu; Wang, Bo

2013-07-09T23:59:59.000Z

91

Characteristics of Gd2-xLaxO3 high-k films by metal-organic chemical vapor deposition  

Science Conference Proceedings (OSTI)

Gd"2"-"xLa"xO"3 high-k films were deposited on (100) Si substrates by low-pressure metal-organic chemical vapor deposition (MOCVD). The metal-organic precursors we used were Gd and La @b-diketonates. The structure, band gap, composition and electrical ... Keywords: Gd2-xLaxO3, High- k, MOCVD

Liu-Ying Huang; Ai-Dong Li; Ying-Ying Fu; Wen-Qi Zhang; Xiao-Jie Liu; Di Wu

2012-06-01T23:59:59.000Z

92

Method of making AlInSb by metal-organic chemical vapor deposition  

DOE Patents (OSTI)

A method for producing aluminum-indium-antimony materials by metal-organic chemical vapor deposition (MOCVD). This invention provides a method of producing Al.sub.X In.sub.1-x Sb crystalline materials by MOCVD wherein an Al source material, an In source material and an Sb source material are supplied as a gas to a heated substrate in a chamber, said Al source material, In source material, and Sb source material decomposing at least partially below 525.degree. C. to produce Al.sub.x In.sub.1-x Sb crystalline materials wherein x is greater than 0.002 and less than one.

Biefeld, Robert M. (Albuquerque, NM); Allerman, Andrew A. (Albuquerque, NM); Baucom, Kevin C. (Albuquerque, NM)

2000-01-01T23:59:59.000Z

93

Watershed Mercury Loading Framework  

Science Conference Proceedings (OSTI)

This report explains and illustrates a simplified stochastic framework, the Watershed Mercury Loading Framework, for organizing and framing site-specific knowledge and information on mercury loading to waterbodies. The framework permits explicit treatment of data uncertainties. This report will be useful to EPRI members, state and federal regulatory agencies, and watershed stakeholders concerned with mercury-related human and ecological health risk.

2003-05-23T23:59:59.000Z

94

Transition Metal Catalyzed Reactions of Carbohydrates: a Nonoxidative Approach to Oxygenated Organics  

DOE Green Energy (OSTI)

There is a critical need for new environmentally friendly processes in the United States chemical industry as legislative and economic pressures push the industry to zero-waste and cradle-to-grave responsibility for the products they produce. Carbohydrates represent a plentiful, renewable resource, which for some processes might economically replace fossil feedstocks. While the conversion of biomass to fuels, is still not generally economical, the selective synthesis of a commodity or fine chemical, however, could compete effectively if appropriate catalytic conversion systems can be found. Oxygenated organics, found in a variety of products such as nylon and polyester, are particularly attractive targets. We believe that with concerted research efforts, homogeneous transition metal catalyzed reactions could play a significant role in bringing about this future green chemistry technology.

Andrews, Mark

1997-01-08T23:59:59.000Z

95

Heavy metals and toxic organic pollutants in MSW-composts: Research results on phytoavailability, bioavailability, fate, etc  

Science Conference Proceedings (OSTI)

The paper is a review and interpretation of research which has been conducted to determine the fate, transport, and potential effects of heavy metals and toxic organic compounds in Municipal Solid Waste (MSW)-composts and sewage sludges. Evaluation of research findings identified a number of pathways by which these contaminants can be transferred from MSW-compost or compost-amended soils to humans, livestock, or wildlife. The pathways consider direct ingestion of compost or compost-amended soil by livestock and children, plant uptake by food or feed crops, and exposure to dust, vapor, and water to which metals and organics have migrated.

Ryan, J.A.; Chaney, R.L.

1994-01-01T23:59:59.000Z

96

Charge-transfer interfaces between metal and redox arylamine molecular films: As probed with anode interfacial engineering approach in single-layer organic diodes  

E-Print Network (OSTI)

We investigate the charge-transfer interfaces between metal and redox arylamine molecular films through studying the current-voltage characteristics of single-layer organic diodes with the aid of anode interfacial engineering method. The diode turn-on voltage is shown to be highly sensitive to the arylamine/metal charge-transfer interfaces and thus can serve as a probe in detecting such organic/metal interfaces. We show that the diode electrical performance could be tuned through engineering the arylamine/metal interfaces via controlling the factors of anode work function, arylamine substitute groups, and active layer surface morphology etc. The conduction mechanism of the diodes is shown to be injection limited, which could be well described with Richardson-Schottky thermonic emission model. Our work may provide some insight into the use of single-layer organic diode and interfacial engineering method to rapidly probe the organic/metal and even organic/organic charge-transfer interfaces.

J. C. Li; S. C. Blackstock; G. J. Szulczewski

2005-08-19T23:59:59.000Z

97

Hydrogen Storage in Metal-Organic Frameworks - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

7 7 FY 2012 Annual Progress Report DOE Hydrogen and Fuel Cells Program Jeffrey Long (Primary Contact), Martin Head-Gordon Lawrence Berkeley National Laboratory 1 Cyclotron Road Berkeley, CA 95720 Phone: (510) 642-0860 Email: jrlong@berkeley.edu DOE Managers HQ: Ned Stetson Phone: (202) 586-9995 Email: Ned.Stetson@ee.doe.gov GO: Jesse Adams Phone: (720) 356-1421 Email: Jesse.Adams@go.doe.gov Subcontractors: * National Institute of Standards and Technology, Gaithersburg, MD (Craig Brown) * General Motors Corporation, Warren, MI (Anne Dailly) Project Start Date: April 1, 2012 Project End Date: March 31, 2015 Fiscal Year (FY) 2012 Objectives

98

Hydrocarbon Separations in Metal-Organic Frameworks Zoey R. Herm, Eric D. Bloch, and Jeffrey R. Long*  

E-Print Network (OSTI)

such as methane/ethane separations and more esoteric separations have already been investigated to a considerable

99

Low temperature metal-organic chemical vapor deposition growth processes for high-efficiency solar cells  

DOE Green Energy (OSTI)

This report describes the results of a program to develop a more complete understanding of the physical and chemical processes involved in low-temperature growth of III-V compounds by metal-organic chemical vapor deposition (MOCVD) and to develop a low-temperature process that is suitable for the growth of high-efficiency solar cells. The program was structured to develop a better understanding of the chemical reactions involved in MOCVD growth, to develop a model of the processes occurring in the gas phase, to understand the physical kinetics and reactions operative on the surface of the growing crystal, and to develop an understanding of the means by which these processes may be altered to reduce the temperature of growth and the utilization of toxic hydrides. The basic approach was to develop the required information about the chemical and physical kinetics operative in the gas phase and on the surface by the direct physical measurement of the processes whenever possible. The program included five tasks: (1) MOCVD growth process characterization, (2) photoenhanced MOCVD studies, (3) materials characterization, (4) device fabrication and characterization, and (5) photovoltaic training. Most of the goals of the program were met and significant progress was made in defining an approach that would allow both high throughput and high uniformity growth of compound semiconductors at low temperatures. The technical activity was focused on determining the rates of thermal decomposition of trimethyl gallium, exploring alternate arsenic sources for use MOCVD, and empirical studies of atomic layer epitaxy as an approach.

Dapkus, P.D. (University of Southern California, Los Angeles, CA (United States))

1993-02-01T23:59:59.000Z

100

Distributed Resource Integration Framework  

Science Conference Proceedings (OSTI)

This report defines a framework for assessing current issues and considerations associated with the deployment and operation of distributed resources. The framework is a guide that can assist utility personnel, distributed resource owners, and other stakeholders in planning integration projects and in relating different integration projects to one another. The framework provides a structured organization of the various elements associated with distributed resource integration, including regulatory, busin...

2009-12-23T23:59:59.000Z

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Magnetic properties of a metal-organic antiferromagnet Mn,,hfipbb...py,,H2O...0.5  

E-Print Network (OSTI)

crystallographically independent Mn atoms Mn1 and Mn2 exist in this structure, and an alternate connection ­Mn1­ Mn2­Mn are discovered. Here we report the synthesis, structure, and magnetic properties of a metal-organic coordination 0.195, 0.5 mmol , py 2 ml , and H2O 5 ml was sealed in a Teflon-lined acid digestion bomb and heated

Li, Jing

102

Making frameworks work: a project retrospective  

Science Conference Proceedings (OSTI)

Various issues make framework development harder than regular development. Building product lines and frameworks requires increased coordination and communication between stakeholders and across the organization. The difficulty of building the right ... Keywords: experience report, object-oriented frameworks, product lines

Marwan Abi-Antoun

2007-10-01T23:59:59.000Z

103

Cybersecurity Framework  

Science Conference Proceedings (OSTI)

... the Executive Order “Improving Critical Infrastructure Cybersecurity” has directed NIST to work with stakeholders to develop a voluntary framework ...

2013-08-30T23:59:59.000Z

104

Metal dissolution kinetics in organic solvents using rotating ring-disc voltammetry. Final report  

DOE Green Energy (OSTI)

The effect of a two-phased liquid system - composed of geothermal brine and an organic heat transfer fluid - on the stability of materials used in the energy conversion system was investigated. The principle organic liquids used were isobutane and isopentane. The effects of relative fluid velocity on the corrosion behavior of representative construction materials, austenitic stainless steels, nickel, and copper alloy were determined using an autoclave incorporating a rotating ring-disc electrode. 2 refs., 20 figs. (ACR)

Not Available

1985-01-01T23:59:59.000Z

105

New organic synthetic metals derived from BEDT-TTF, Ni(dsit) sub 2 and BEDO-TTF  

SciTech Connect

Three strategies have been employed by us to synthesize new organic synthetic metals and superconductors. On the basis of structure-property correlations derived for the {beta}-(BEDT-TTF){sub 2}X salts, new charge transfer salts of BEDT-TTF with large, polarizable anions have been synthesized. The occurrence of molecular dimers has been engineered into salts of the new organic acceptor molecule, Ni(dsit){sub 2} (bis (4,5 -diselenolate -1,3-dithiole-2-thione) nickelate), to synthesize salts with acceptor packing similar to the donor packing in {kappa}-(BEDT-TTF){sub 2}Cu(SCN){sub 2}. Finally, two charge transfer salts of bis(ethylenedioxy)tetrathiafulvalene, BEDO-TTF, namely (BEDO-TTF){sub 2}AuBr{sub 2} and (BEDO-TTF){sub 2}AuI{sub 2} have been synthesized. The AuBr{sub 2}{sup -} salt, the first BEDO-TTF salt to be structurally characterized, is semiconducting below 263 K, while the AuI{sub 2}{sup -} salt shows metallic conductivity to low temperatures. 10 refs., 3 figs.

Beno, M.A.; Kini, A.M.; Geiser, U.; Wang, H.H.; Carlson, K.D.; Williams, J.M.

1989-01-01T23:59:59.000Z

106

Case Study of Water-Soluble Metal Containing Organic Constituents of Biomass Burning Aerosol  

DOE Green Energy (OSTI)

Natural and prescribed biomass fires are a major source of atmospheric aerosols that can persist in the atmosphere for long periods of time. Biomass burning aerosols (BBA) can be associated with long range transport of water soluble N?, S?, P?, and metal?containing species. In this study, BBA samples were collected using a particle?into?liquid sampler (PILS) from laboratory burns of vegetation collected on military bases in the southeastern and southwestern United States. The samples were then analyzed using high resolution electrospray ionization mass spectrometry (ESI/HR?MS) that enabled accurate mass measurements for hundreds of species with m/z values between 70 and 1000 and assignment of probable elemental formulae. Mg, Al, Ca, Cr, Mn, Fe, Ni, Cu, Zn, and Ba?containing organometallic species were identified. The results suggest that the biomass may have accumulated metal?containing species that were reemitted during biomass burning. Further research into the sources, persistence, and dispersion of metal?containing aerosols as well as their environmental effects is needed.

Chang-Graham, Alexandra L.; Profeta, Luisa Tm; Johnson, Timothy J.; Yokelson, Robert J.; Laskin, Alexander; Laskin, Julia

2011-01-10T23:59:59.000Z

107

Structure-property correlations in the design of organic metals and superconductors: An overview  

SciTech Connect

Molecular structure and, more importantly, molecular packing in organic superconducting salts (TMTSF){sub 2}X, {beta}-(BEDT-TTF){sub 2}X and {kappa}-(BEDT-TTF){sub 2}X will be examined in the context of deducing structure-property correlations in these systems. Such an approach has been instrumental in the discovery of superconductivity at 10.4 K in {kappa}-(BEDT-TTF){sub 2}Cu(NCS){sub 2}, and it will continue to serve as an important tool in the rational design of new organic superconductors with even higher superconducting transition temperatures.

Kini, A.M.; Beno, M.A.; Carlson, K.D.; Ferraro, J.R.; Geiser, U.; Schultz, A.J.; Wang, H.H.; Williams, J.M.

1989-01-01T23:59:59.000Z

108

ZnO light-emitting diode grown by plasma-assisted metal organic chemical vapor deposition  

SciTech Connect

We report a breakthrough in fabricating ZnO homojunction light-emitting diode by metal organic chemical vapor deposition. Using NO plasma, we are able to grow p-type ZnO thin films on n-type bulk ZnO substrates. The as-grown films on glass substrates show hole concentration of 10{sup 16}-10{sup 17} cm{sup -3} and mobility of 1-10 cm{sup 2} V{sup -1} s{sup -1}. Room-temperature photoluminescence spectra reveal nitrogen-related emissions. A typical ZnO homojunction shows rectifying behavior with a turn-on voltage of about 2.3 V. Electroluminescence at room temperature has been demonstrated with band-to-band emission at I=40 mA and defect-related emissions in the blue-yellow spectrum range.

Xu, W.Z.; Ye, Z.Z.; Zeng, Y.J.; Zhu, L.P.; Zhao, B.H.; Jiang, L.; Lu, J.G.; He, H.P.; Zhang, S.B. [State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027 (China); National Renewable Energy Laboratory, Golden, Colorado 80401 (United States)

2006-04-24T23:59:59.000Z

109

Organization  

NLE Websites -- All DOE Office Websites (Extended Search)

Organization Print Organization Print 2012-12 org chart A complete ALS organization chart (June 2013) is available in PDF. Appointed and elected members of advisory panels provide guidance to Berkeley Lab and ALS management in developing the ALS scientific and user programs. ALS Staff Photo staff photo thumb Click on the image to see a recent photo of ALS staff in front of the dome. The photo was taken on May 14, 2013. ALS Management and Advisory Team Steve Kevan, Deputy Division Director, Science Michael J. Banda, Deputy Division Director, Operations Robert W. Schoenlein, Senior Staff Scientist, Next Generation Light Source Initiative Janos Kirz, Scientific Advisor Paul Adams, Division Deputy for Biosciences ALS Scientific, Technical, and User Support Groups Accelerator Physics

110

Two-dimensional magnetic quantum oscillations observed in an organic metal  

Science Conference Proceedings (OSTI)

The de Haas-van Alphen (dHvA) signal of the organic superconductor {beta}{double_prime}-(BEDT-TTF){sub 2}SF{sub 5}CH{sub 2}CF{sub 2}SO{sub 3} shows an inverse-sawtooth wave form which proves the existence of an ideal two-dimensional (2D) Fermi surface. The dHvA wave shape can almost perfectly be described by a 2D theory assuming a constant chemical potential. This either implies the existence of the predicted quasi-one-dimensional band with an exceptionally large density of states or the chemical potential may be pinned due to localized states near the Fermi energy.

Hagel, J.; Wanka, S.; Wosnitza, J.; Balthes, E.; Schlueter, J. A.; Kini, A. M.; Geiser, U.; Mohtasham, J.; Winter, R. W.; Gard, G. L.

2000-07-24T23:59:59.000Z

111

Conceptual Framework  

Science Conference Proceedings (OSTI)

...in the Presence of Corrosion, Oct 1998 (Corfu, Greece), North Atlantic Treaty Organization Research and

112

An examination of reliability critical items in liquid metal reactors: An analysis by the Centralized Reliability Data Organization (CREDO)  

SciTech Connect

The Centralized Reliability Data Organization (CREDO) is the largest repository of liquid metal reactor (LMR) component reliability data in the world. It is jointly sponsored by the US Department of Energy (DOE) and the Power Reactor and Nuclear Fuel Development Corporation (PNC) of Japan. The CREDO data base contains information on a population of more than 21,000 components and approximately 1300 event records. A conservative estimation is that the total component operating hours is approaching 3.5 billion hours. Because data gathering for CREDO concentrates on event (failure) information, the work reported here focuses on the reliability information contained in CREDO and the development of reliability critical items lists. That is, components are ranked in prioritized lists from worst to best performers from a reliability standpoint. For the data contained in the CREDO data base, FFTF and JOYO show reliability growth; EBR-II reveals a slight unreliability growth for those components tracked by CREDO. However, tabulations of events which cause reactor shutdowns decrease with time at each site.

Humphrys, B.L.; Haire, M.J.; Koger, K.H.; Manneschmidt, J.F.; Setoguchi, K.; Nakai, R.; Okubo, Y.

1987-01-01T23:59:59.000Z

113

GTT Framework | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

GTT Framework GTT Framework GTT Framework GTT Framework Strategic Framework The GTT proposes a strategic framework that organizes these activities into three interrelated dimensions (informational, analytical, and physical), representative of the systems nature of the grid. Each of these dimensions have a corresponding strategic focus: The informational dimension aims to improve the visibility of grid conditions. The analytical dimension increases our understanding of the implications of the observed conditions. The physical dimension enhances the flexibility of the grid to respond to that understanding. The logic behind these focus areas is that a modernized grid should be able to "see" an event or condition, "know" what is happening or about to happen, and "do" something appropriate in response - quickly and

114

Crypto Key Management Framework  

Science Conference Proceedings (OSTI)

... A Framework for Designing Cryptographic Key Management Systems ... A Framework for Designing Cryptographic Key Management Systems ...

2013-08-13T23:59:59.000Z

115

Refractory Metals 2011  

Science Conference Proceedings (OSTI)

Aug 2, 2010 ... TMS Structural Materials Division TMS: Refractory Metals Committee. Organizer( s), Omer Dogan, DOE National Energy Technology Laboratory

116

Hydrogen-Defect Interactions in the Framework of the Defactant ...  

Science Conference Proceedings (OSTI)

Symposium, Multiscale Approaches to Hydrogen-assisted Degradation of Metals. Presentation Title, Hydrogen-Defect Interactions in the Framework of the ...

117

Journal of Light Emitting Diodes Vol 2 N0 1, April 2010 1 Abstract--In metal organic vapor phase epitaxy we developed  

E-Print Network (OSTI)

Journal of Light Emitting Diodes Vol 2 N0 1, April 2010 1 Abstract-- In metal organic vapor phase epitaxy we developed GaInN/GaN quantum well material suitable for 500 ­ 580 nm light emitting diodes at longer wavelengths. Index Terms-- a-plane GaN, GaInN, Green light emitting diode, m-plane GaN I

Wetzel, Christian M.

118

Climate Literacy Framework  

NLE Websites -- All DOE Office Websites (Extended Search)

Climate Literacy Framework Print E-mail Climate Literacy Framework Print E-mail A Guide for Individuals and Communities The Essential Principles of Climate Science presents important information for individuals and communities to understand Earth's climate, impacts of climate change, and approaches for adapting and mitigating change. Principles in the guide can serve as discussion starters or launching points for scientific inquiry. The guide can also serve educators who teach climate science as part of their science curricula. Development of the guide began at a workshop sponsored by the National Oceanic and Atmospheric Administration (NOAA) and the American Association for the Advancement of Science (AAAS). Multiple science agencies, non-governmental organizations, and numerous individuals also contributed through extensive review and comment periods. Discussion at the National Science Foundation (NSF) and NOAA-sponsored Atmospheric Sciences and Climate Literacy workshop contributed substantially to the refinement of the document.

119

Exceptional H2 Saturation Uptake in Microporous Metal-Organic Frameworks Antek G. Wong-Foy, Adam J. Matzger,* and Omar M. Yaghi*,  

E-Print Network (OSTI)

it requires employing either extremely high pressures as a gas or very low temperatures as a liquid.1, a practical material will need to have higher capacity when the weight of the tank and associated cooling materials were calculated from the adsorption branches of the N2 isotherms obtained at 77 K

Yaghi, Omar M.

120

MST: Organizations: Organic Materials  

NLE Websites -- All DOE Office Websites (Extended Search)

Adhesive Bonding Adhesive Bonding Composites Encapsulation Materials Characterization Mechanical Testing Molding, Thermoforming, & Compounding Organizations Organic Materials Composite-to-metal adhesive bond Experimental/analytical study of composit-to-metal adhesive bond. The Organic Materials department in the Advanced Manufacturing and Processing Laboratory provides innovative prototype fabrication, full service small lot production, materials technology, processing expertise, and a broad range of organic material characterization and mechanical testing techniques. We encapsulate, we join and bond, we foam, we analyze and image, we build composite structures. We strive to make you, our customers, successful! We partner with you to find the right combination of materials, processing, and fixturing that will result in the highest value

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

IRF: Information Retrieval Framework  

Science Conference Proceedings (OSTI)

is a freely available object-oriented framework for information retrieval (IR) applications. A framework is software which ...

122

Recycling Metals Using the MOCVD Process  

Science Conference Proceedings (OSTI)

Aug 1, 2000 ... Secondly, the volatile metal organic compound is purified by fractional distillation. Thirdly, the purified metal organic compound is decomposed ...

123

Nonferrous Metals Society of China  

Science Conference Proceedings (OSTI)

The Nonferrous Metals Society of China (NFSoc) is a technological organization of scientists and technologists engaged in the nonferrous metals industry.

124

The geography of strategy : an exploration of alternative frameworks for transportation infrastructure strategy development  

E-Print Network (OSTI)

This thesis introduces the notion of a strategy development framework for transportation infrastructure systems. A strategy development framework has several dimensions: the organizations that own.infrastructure, the ...

Dunn, Travis P

2010-01-01T23:59:59.000Z

125

NIST Cybersecurity Framework - DRAFT Framework Glossary  

Science Conference Proceedings (OSTI)

DRAFT - Framework Glossary Term Draft Definition Category The logical subdivision of a function; one or more categories comprise a function. ...

2013-06-28T23:59:59.000Z

126

Effects of metallic absorption and the corrugated layer on the optical extraction efficiency of organic light-emitting diodes  

E-Print Network (OSTI)

The absorption of a metallic cathode in OLEDs is analyzed by using FDTD calculation. As the light propagates parallel to the layer, the intensity of Ez polarization decreases rapidly. The intensity at 2.0 um from the dipole is less than a quarter of that at 0.5 um. The strong absorption by a cathode can be a critical factor when considering the increase of optical extraction by means of bending the optical layers. The calculation indicates that the corrugation of layers helps the guided light escape the guiding layer, but also increases the absorption into a metallic cathode. The final optical output power of the corrugated OLED can be smaller than that of the flat OLED. On the contrary, the corrugated structure with a non-absorptive cathode increases the optical extraction by nearly two times.

Lee, Baek-Woon

2011-01-01T23:59:59.000Z

127

Nanotube Reinforced Metal Matrix Composites II  

Science Conference Proceedings (OSTI)

Symposium, Nanotube Reinforced Metal Matrix Composites II. Sponsorship, MS&T Organization. Organizer(s), Indrajit Charit, University of Idaho Sudipta Seal  ...

128

A Scalable Framework for Cyber Attack Discovery and Situational...  

NLE Websites -- All DOE Office Websites (Extended Search)

Scalable Framework for Cyber Attack Discovery and Situational Understanding (SITU) May 15, 2013 Problem Statement: Cyber attacks cost commercial and governmental organizations vast...

129

High Throughput Combinatorial Screening of Biometic Metal-Organic Materials for Military Hydrogen-Storage Materials (New Joint Miami U/NREL DoD/DLA Project) (presentation)  

NLE Websites -- All DOE Office Websites (Extended Search)

Miami University/NREL DoD/DLA Project Miami University/NREL DoD/DLA Project High throughput combinatorial screening of biomimetic metal-organic materials for military hydrogen-storage applications Philip Parilla - NREL Joe Zhou, Dan Zhao - Miami U, Ohio Jeff Blackburn, Kevin O'Neill, Lin Simpson, Mike Heben - NREL Outline * Miami/NREL Project - Synthesis (Miami) - High Throughput Characterization (NREL) - Other Characterization * Other High Throughput Activities (NREL) - Parallel Sieverts - Parallel Gravimetric * Final Comments Overview of Miami/NREL Project * Goals - Development of H 2 storage materials based on MOFs, targeting 15 kJ/mole binding energy and high density of H 2 sites - Development of optical-based detection of adsorbed H 2 allowing rapid screening of samples * Approach - Combinatorial MOFs synthesis involving 8

130

Synthesis and Characterization of Porous Metal Phosphonates  

E-Print Network (OSTI)

This dissertation focuses on the challenge of developing porous metal arylphosphonates with both high crystallinity and functional porosity by using different synthetic approaches. Metal phosphonates are an extensive class of materials based upon extended inorganic-organic architectures such as chains, layers and three-dimensional networks. Metal phosphonates generally favor extended inorganic architectures leading to pillared materials with no porosity. We found that the use of template molecules, type of ligand and choice of metal ions could be used to deviate from the pillared structure. Many of these structures had interesting properties that were explored. The results can be divided into three areas: We developed non-pillared monovalent metal phosphonates by investigating both the role of water and template molecules in the solvothermal synthesis. The role of water in solvothermal reactions was found to have a profound influence on the structure of monovalent metal phosphonates and the structures could be tailored from zero/one-dimensional to two-dimensional. Non-pillared structures could be synthesized by using template molecules. For a zinc phosphonate, we converted a layered structure into a three-dimensional framework by using small template molecules in the solvothermal reaction. The compound exhibited reversible dehydration behavior. The change in the framework structure and guest positions was monitored during this process. Two different ligands were used in the development of porous aluminum phosphonates. One series exhibited reversible dehydration behavior, which had a dramatic influence on permanent porosity of the material. The stability of the dehydrated phase is a result of the geometry of the aluminum atom, which in some cases has coordinatively unsaturated metal sites. The second series was developed with ion exchange applications in mind therefore the pore environment was tailored to favor ion exchange processes. The most important aspect is that these compounds exhibit high selectivity for Th^(4+) ions. In total 28 new compounds were prepared, and their utility and structures clarified.

Kinnibrugh, Tiffany Lewis

2013-08-01T23:59:59.000Z

131

MOD silver metallization for photovoltaics. Quarterly technical report, December 1, 1983-February 29, 1984. [Metallo-organic decomposition  

DOE Green Energy (OSTI)

It was determined that pyrolysis products can produce dark surface films on MOD silver conductors. Improving the purity of all ink ingredients helped this problem. It was established that the existence and nature of the surface film is influenced by the rate of air flow during firing and by the heating rate in the 70 to 225/sup 0/C range, but these processing parameters have not as yet been optimized. Low temperature solvent removal was determined to be of prime importance in obtaining good adhesion between the MOD films and the substrate. For inks developed to date, 15 to 30 minutes at 60 to 70/sup 0/C was required. It was also determined that the adhesion is influenced by the air flow rate during firing, the heating rate in the 100 to 250/sup 0/C range, and the maximum firing temperature. Results during the first 3 months of effort on this project have demonstrated that it is essential to use generic compounds, and that the compounds must be prepared from high purity raw materials. It was also established that the quality and properties of the MOD silver films are intimately dependent on the time-temperature processing. All of the results obtained to date still indicate that MOD silver shows great promise for low temperature metallization of photovoltaic cells.

Vest, G.M.; Vest, R.W.

1984-03-20T23:59:59.000Z

132

[(CH3)4N][(C5H5NH)0.8((CH3)3NH)0.2]U2Si9O23F4 (USH-8): An Organically Templated Open-Framework Uranium Silicate  

E-Print Network (OSTI)

-Framework Uranium Silicate Xiqu Wang, Jin Huang, and Allan J. Jacobson* Department of Chemistry, Uni pyramids we obtained also a number of open-framework uranium silicates.18,19 These new compounds were-framework uranium fluorosilicate [(CH3)4N][(C5H5NH)0.8((CH3)3NH)0.2]U2Si9O23F4 (USH- 8) that has been synthesized

Wang, Xiqu

133

Organic oxalate as leachant and precipitant for the recovery of valuable metals from spent lithium-ion batteries  

Science Conference Proceedings (OSTI)

Graphical abstract: Display Omitted Highlights: Black-Right-Pointing-Pointer Vacuum pyrolysis as a pretreatment was used to separate cathode material from aluminum foils. Black-Right-Pointing-Pointer Cobalt and lithium can be leached using oxalate while cobalt can be directly precipitated as cobalt oxalate. Black-Right-Pointing-Pointer Cobalt and lithium can be separated efficiently from each other only in the oxalate leaching process. Black-Right-Pointing-Pointer High reaction efficiency of LiCoO{sub 2} was obtained with oxalate. - Abstract: Spent lithium-ion batteries containing lots of strategic resources such as cobalt and lithium are considered as an attractive secondary resource. In this work, an environmentally compatible process based on vacuum pyrolysis, oxalate leaching and precipitation is applied to recover cobalt and lithium from spent lithium-ion batteries. Oxalate is introduced as leaching reagent meanwhile as precipitant which leaches and precipitates cobalt from LiCoO{sub 2} and CoO directly as CoC{sub 2}O{sub 4}{center_dot}2H{sub 2}O with 1.0 M oxalate solution at 80 Degree-Sign C and solid/liquid ratio of 50 g L{sup -1} for 120 min. The reaction efficiency of more than 98% of LiCoO{sub 2} can be achieved and cobalt and lithium can also be separated efficiently during the hydrometallurgical process. The combined process is simple and adequate for the recovery of valuable metals from spent lithium-ion batteries.

Sun Liang [College of Chemistry and Chemical Engineering, Central South University, Changsha 410083 (China); Key Laboratory of Resources Chemistry of Nonferrous Metals, Central South University, Ministry of Education of the People's Republic of China (China); Qiu Keqiang, E-mail: qiuwhs@sohu.com [College of Chemistry and Chemical Engineering, Central South University, Changsha 410083 (China); Key Laboratory of Resources Chemistry of Nonferrous Metals, Central South University, Ministry of Education of the People's Republic of China (China)

2012-08-15T23:59:59.000Z

134

Vibronic states in organic semiconductors based on non-metal naphthalocyanine. Detection of heterocyclic phthalocyanine compounds in a flexible dielectric matrix  

Science Conference Proceedings (OSTI)

The vibronic properties of semiconductor structures based on non-metal naphthalocyanine molecules are studied using IR and Raman spectroscopy methods. New absorption lines in the transmission spectra of such materials are detected and identified. Three transmission lines are observed in the range 2830-3028 cm{sup -1}, which characterize carbon-hydrogen bonds of peripheral molecular groups. Their spectral positions are 2959, 2906, and 2866 cm{sup -1}. It is detected that the phthalocyanine ring can also exhibit its specific vibronic properties in the Raman spectra at 767, 717, and 679 cm{sup -1}. The naphthalocyanine molecule in the organic dielectric matrix of microfibers is described using IR spectroscopy. It is shown that the set of vibrations characterizing the isoindol group, pyrrole ring, naphtha group, and C-H bonds, allows an accurate enough description of the vibronic states of the naphthalocyanine complex in complex heterostructures to be made. The spectral range with fundamental modes, characterizing a naphthalocyanine semiconductor in a heterostructure, is 600-1600 cm{sup -1}. A comparison of the compositions of complex systems with a similar heterostructure containing lutetium diphthalocyanine demonstrated few errors.

Belogorokhov, I. A., E-mail: jugqwerty@mail.ru [State Research and Project Institute of Rare-Metal Industry GIREDMET (Russian Federation); Tikhonov, E. V. [Moscow State University (Russian Federation); Dronov, M. A. [Russian Academy of Sciences, Prokhorov General Physics Institute (Russian Federation); Belogorokhova, L. I. [Moscow State University (Russian Federation); Ryabchikov, Yu. V. [Russian Academy of Sciences, Lebedev Physical Institute (Russian Federation); Tomilova, L. G.; Khokhlov, D. R. [Moscow State University (Russian Federation)

2012-01-15T23:59:59.000Z

135

As-grown deep-level defects in n-GaN grown by metal-organic chemical vapor deposition on freestanding GaN  

SciTech Connect

Traps of energy levels E{sub c}-0.26 and E{sub c}-0.61 eV have been identified as as-grown traps in n-GaN grown by metal-organic chemical vapor deposition by using deep level transient spectroscopy of the Schottky contacts fabricated by resistive evaporation. The additional traps of E{sub c}-0.13 and E{sub c}-0.65 eV have been observed in samples whose contacts are deposited by electron-beam evaporation. An increase in concentration of the E{sub c}-0.13 and E{sub c}-0.65 eV traps when approaching the interface between the contact and the GaN film supports our argument that these traps are induced by electron-beam irradiation. Conversely, the depth profiles of as-grown traps show different profiles between several samples with increased or uniform distribution in the near surface below 50 nm. Similar profiles are observed in GaN grown on a sapphire substrate. We conclude that the growth process causes these large concentrations of as-grown traps in the near-surface region. It is speculated that the finishing step in the growth process should be an essential issue in the investigation of the surface state of GaN.

Chen Shang; Ishikawa, Kenji; Hori, Masaru [Nagoya University, Chikusa, Nagoya 464-8603 (Japan); Honda, Unhi; Shibata, Tatsunari; Matsumura, Toshiya; Tokuda, Yutaka [Aichi Institute of Technology, Yakusa, Toyota 470-0392 (Japan); Ueda, Hiroyuki; Uesugi, Tsutomu; Kachi, Tetsu [Toyota Central R and D Laboratories, Inc., Yokomichi, Nagakute 480-1192 (Japan)

2012-09-01T23:59:59.000Z

136

Low temperature metal-organic chemical vapor deposition growth processes for high-efficiency solar cells. Final technical report, 1 September 1985--30 November 1989  

DOE Green Energy (OSTI)

This report describes the results of a program to develop a more complete understanding of the physical and chemical processes involved in low-temperature growth of III-V compounds by metal-organic chemical vapor deposition (MOCVD) and to develop a low-temperature process that is suitable for the growth of high-efficiency solar cells. The program was structured to develop a better understanding of the chemical reactions involved in MOCVD growth, to develop a model of the processes occurring in the gas phase, to understand the physical kinetics and reactions operative on the surface of the growing crystal, and to develop an understanding of the means by which these processes may be altered to reduce the temperature of growth and the utilization of toxic hydrides. The basic approach was to develop the required information about the chemical and physical kinetics operative in the gas phase and on the surface by the direct physical measurement of the processes whenever possible. The program included five tasks: (1) MOCVD growth process characterization, (2) photoenhanced MOCVD studies, (3) materials characterization, (4) device fabrication and characterization, and (5) photovoltaic training. Most of the goals of the program were met and significant progress was made in defining an approach that would allow both high throughput and high uniformity growth of compound semiconductors at low temperatures. The technical activity was focused on determining the rates of thermal decomposition of trimethyl gallium, exploring alternate arsenic sources for use MOCVD, and empirical studies of atomic layer epitaxy as an approach.

Dapkus, P.D. [University of Southern California, Los Angeles, CA (United States)

1993-02-01T23:59:59.000Z

137

Relaxation and critical strain for maximum In incorporation in AlInGaN on GaN grown by metal organic vapour phase epitaxy  

Science Conference Proceedings (OSTI)

Quaternary AlInGaN layers were grown on conventional GaN buffer layers on sapphire by metal organic vapour phase epitaxy at different surface temperatures and different reactor pressures with constant precursor flow conditions. A wide range in compositions within 30-62% Al, 5-29% In, and 23-53% Ga was covered, which leads to different strain states from high tensile to high compressive. From high-resolution x-ray diffraction and Rutherford backscattering spectrometry, we determined the compositions, strain states, and crystal quality of the AlInGaN layers. Atomic force microscopy measurements were performed to characterize the surface morphology. A critical strain value for maximum In incorporation near the AlInGaN/GaN interface is presented. For compressively strained layers, In incorporation is limited at the interface as residual strain cannot exceed an empirical critical value of about 1.1%. Relaxation occurs at about 15 nm thickness accompanied by strong In pulling. Tensile strained layers can be grown pseudomorphically up to 70 nm at a strain state of 0.96%. A model for relaxation in compressively strained AlInGaN with virtual discrete sub-layers, which illustrates the gradually changing lattice constant during stress reduction is presented.

Reuters, Benjamin; Finken, M.; Wille, A.; Kalisch, H.; Vescan, A. [RWTH Aachen University, GaN Device Technology, Sommerfeldstrasse 24, 52074 Aachen (Germany); Juelich Aachen Research Alliance, JARA-FIT, Wilhelm-Johnen-Strasse, 52428 Juelich (Germany); Hollaender, B. [Juelich Aachen Research Alliance, JARA-FIT, Wilhelm-Johnen-Strasse, 52428 Juelich (Germany); Forschungszentrum Juelich GmbH, PGI9-IT, 52425 Juelich (Germany); Heuken, M. [RWTH Aachen University, GaN Device Technology, Sommerfeldstrasse 24, 52074 Aachen (Germany); AIXTRON SE, Kaiserstr. 98, 52134 Herzogenrath (Germany)

2012-11-01T23:59:59.000Z

138

A Stable Open Framework with Wide Open Spaces | Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

Pumping Through the Middle Crust Pumping Through the Middle Crust Looking for Ways to Improve Vaccines Against the Deadly Rotavirus A "Colossal" Magnetic Effect under Pressure Using High Pressure to Reveal Quantum Criticality in an Elemental Antiferromagnet Nano Changes Have Macro Importance for a Key Electronics Material Science Highlights Archives: 2013 | 2012 | 2011 | 2010 2009 | 2008 | 2007 | 2006 2005 | 2004 | 2003 | 2002 2001 | 2000 | 1998 | Subscribe to APS Science Highlights rss feed A Stable Open Framework with Wide Open Spaces AUGUST 11, 2009 Bookmark and Share In this depiction of the structure of PCN-61, a metal-organic framework, copper atoms (blue) sit in "paddlewheel" structures with oxygen (red) and carbon (black) atoms. The paddlewheels link together to form

139

IBRD Operational Decision Framework  

SciTech Connect

The IBRD Operational Decision Framework in this document is an expansion of an emerging general risk management framework under development by an interagency working group. It provides the level of detail necessary to develop a general Consequence Management Guidance Document for biological contamination remediation and restoration. It is the intent of this document to support both wide area and individual site remediation and restoration activities. This product was initiated as a portion of the IBRD Task 1 Systems Analysis to aid in identification of wide area remediation and restoration shortcomings and gaps. The draft interagency general risk management framework was used as the basis for the analysis. The initial Task 1 analysis document expanded the draft interagency framework to a higher level of resolution, building on both the logic structure and the accompanying text explanations. It was then employed in a qualitative manner to identify responsible agencies, data requirements, tool requirements, and current capabilities for each decision and task. This resulted in identifying shortcomings and gaps needing resolution. Several meetings of a joint LLNL/SNL working group reviewed and approved the initial content of this analysis. At the conclusion of Task 1, work continued on the expanded framework to generate this Operational Decision Framework which is consistent with the existing interagency general risk management framework. A large LLNL task group met repeatedly over a three-month period to develop the expanded framework, coordinate the framework with the biological remediation checklist, and synchronize the logic with the Consequence Management Plan table of contents. The expanded framework was briefed at a large table top exercise reviewing the interagency risk management framework. This exercise had representation from major US metropolitan areas as well as national agencies. This product received positive comments from the participants. Upon completion of the Operational Decision Framework, another joint LLNL/SNL working group conducted a day-long review. Identified modifications were made to the document, resulting in the included product.

Greenwalt, R; Hibbard, W; Raber, E; Carlsen, T; Folks, K; MacQueen, D; Mancieri, S; Bunt, T; Richards, J; Hirabayashi-Dethier, J

2010-11-12T23:59:59.000Z

140

NIST Cyber Security Framework  

Science Conference Proceedings (OSTI)

Page 1. NIST Cyber Security Framework ISA-62443-2-1 :2009 ISA-62443-2-1 (Ed. 2, D2E8 ... Page 2. Security NIST Cyber ...

2013-12-13T23:59:59.000Z

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

NETL: IEP – Post-Combustion CO2 Emissions Control - Microporous Metal  

NLE Websites -- All DOE Office Websites (Extended Search)

IEP – Post-Combustion CO2 Emissions Control IEP – Post-Combustion CO2 Emissions Control Microporous Metal Organic Frameworks Project No.: FC26-07NT43092 Examples of several MOFs under investigation Examples of several MOFs under investigation UOP LLC is conducting research for separating carbon dioxide (CO2) using novel microporous metal organic frameworks (MOFs). In the first project, NT42121, UOP partnered with the University of Michigan and Northwestern University to evaluate MOFs in both pre-combustion and post-combustion applications. In the second project, NT43092, UOP is collaborating with Vanderbilt University and the University of Edinburgh, as well as the University of Michigan and Northwestern University, in a more focused effort on MOFs in post-combustion applications. MOFs are an extraordinary

142

METAL ORGANIC VAPOR PHASE EPITAXY  

Science Conference Proceedings (OSTI)

Jun 4, 2004 ... used to texture the surface of a Light Emitting Diode (LED) structure, enhancing light extraction by a factor of 2 to 3 times. This paper will.

143

Cascaded refactoring for framework  

Science Conference Proceedings (OSTI)

Refactoring of source code has been studied as a preliminary step in the evolution of object-oriented software. We extend the concept of refactoring to the whole range of models used to describe a framework in our methodology: feature model, use case ... Keywords: architecture, design pattern, domain analysis, evolution, feature model, framework, hotspot, refactoring, role, use case

Greg Butler; Lugang Xu

2001-05-01T23:59:59.000Z

144

Reversible photodeposition and dissolution of metal ions  

DOE Patents (OSTI)

A cyclic photocatalytic process for treating waste water containing metal and organic contaminants. In one embodiment of the method, metal ions are photoreduced onto the photocatalyst and the metal concentrated by resolubilization in a smaller volume. In another embodiment of the method, contaminant organics are first oxidized, then metal ions removed by photoreductive deposition. The present invention allows the photocatalyst to be recycled until nearly complete removal of metal ions and organic contaminants is achieved.

Foster, Nancy S. (Boulder, CO); Koval, Carl A. (Golden, CO); Noble, Richard D. (Boulder, CO)

1994-01-01T23:59:59.000Z

145

Computational Design of Metal Ion Sequestering Agents  

SciTech Connect

Organic ligands that exhibit a high degree of metal ion recognition are essential precursors for developing separation processes and sensors for metal ions. Since the beginning of the nuclear era, much research has focused on discovering ligands that target specific radionuclides. Members of the Group 1A and 2A cations (e.g., Cs, Sr, Ra) and the f-block metals (actinides and lanthanides) are of primary concern to DOE. Although there has been some success in identifying ligand architectures that exhibit a degree of metal ion recognition, the ability to control binding affinity and selectivity remains a significant challenge. The traditional approach for discovering such ligands has involved lengthy programs of organic synthesis and testing that, in the absence of reliable methods for screening compounds before synthesis, have resulted in much wasted research effort. This project seeks to enhance and strengthen the traditional approach through computer-aided design of new and improved host molecules. Accurate electronic structure calculations are coupled with experimental data to provide fundamental information about ligand structure and the nature of metal-donor group interactions (design criteria). This fundamental information then is used in a molecular mechanics model (MM) that helps us rapidly screen proposed ligand architectures and select the best members from a set of potential candidates. By using combinatorial methods, molecule building software has been developed that generates large numbers of candidate architectures for a given set of donor groups. The specific goals of this project are: • further understand the structural and energetic aspects of individual donor group- metal ion interactions and incorporate this information within the MM framework • further develop and evaluate approaches for correlating ligand structure with reactivity toward metal ions, in other words, screening capability • use molecule structure building software to generate large numbers of candidate ligand architectures for given sets of donor groups • screen candidates and identify ligand architectures that will exhibit enhanced metal ion recognition. These new capabilities are being applied to ligand systems identified under other DOEsponsored projects where studies have suggested that modifying existing architectures will lead to dramatic enhancements in metal ion binding affinity and selectivity. With this in mind, we are collaborating with Professors R. T. Paine (University of New Mexico), K. N. Raymond (University of California, Berkeley), and J. E. Hutchison (University of Oregon), and Dr. B. A. Moyer (Oak Ridge National Laboratory) to obtain experimental validation of the predicted new ligand structures. Successful completion of this study will yield molecular-level insight into the role that ligand architecture plays in controlling metal ion complexation and will provide a computational approach to ligand design.

Hay, Benjamin P.; Rapko, Brian M.

2005-06-15T23:59:59.000Z

146

Metal Aminoboranes  

Metal aminoboranes of the formula M(NH.sub.2BH.sub.3).sub.n have been synthesized. Metal aminoboranes are hydrogen storage materials. Metal aminoboranes are also precursors for synthesizing other metal aminoboranes. Metal aminoboranes can be ...

147

A Clustering-Driven LDAP Framework  

Science Conference Proceedings (OSTI)

LDAP directories have proliferated as the appropriate storage framework for various and heterogeneous data sources, operating under a wide range of applications and services. Due to the increased amount and heterogeneity of the LDAP data, there is a ... Keywords: DIT organization, LDAP services, clustering, merging criteria, query and retrieval engine

Vassiliki Koutsonikola; Athena Vakali

2011-07-01T23:59:59.000Z

148

A Conceptual Framework for Progressing Towards Sustainability in the  

Open Energy Info (EERE)

A Conceptual Framework for Progressing Towards Sustainability in the A Conceptual Framework for Progressing Towards Sustainability in the Agriculture and Food Sector Jump to: navigation, search Tool Summary LAUNCH TOOL Name: A Conceptual Framework for Progressing Towards Sustainability in the Agriculture and Food Sector Agency/Company /Organization: Food and Agriculture Organization of the United Nations Sector: Land Focus Area: Agriculture Topics: Policies/deployment programs, Pathways analysis Resource Type: Publications Website: www.fao.org/docrep/012/al322e/al322e00.pdf A Conceptual Framework for Progressing Towards Sustainability in the Agriculture and Food Sector Screenshot References: A Conceptual Framework for Progressing Towards Sustainability in the Agriculture and Food Sector[1] Logo: A Conceptual Framework for Progressing Towards Sustainability in the Agriculture and Food Sector

149

Realm Specific IP: Framework  

Science Conference Proceedings (OSTI)

This document examines the general framework of Realm Specific IP (RSIP). RSIP is intended as a alternative to NAT in which the end- to-end integrity of packets is maintained. We focus on implementation issues, deployment scenarios, and interaction ...

M. Borella; J. Lo; D. Grabelsky; G. Montenegro

2001-10-01T23:59:59.000Z

150

Grammatical framework web service  

Science Conference Proceedings (OSTI)

We present a web service for natural language parsing, prediction, generation, and translation using grammars in Portable Grammar Format (PGF), the target format of the Grammatical Framework (GF) grammar compiler. The web service implementation is open ...

Björn Bringert; Krasimir Angelov; Aarne Ranta

2009-04-01T23:59:59.000Z

151

Metal-Ion-Mediated Reactions  

NLE Websites -- All DOE Office Websites (Extended Search)

Metal-Ion-Mediated Reactions Metal-Ion-Mediated Reactions Metal-Ion-Mediated Reactions Print Monday, 19 December 2011 18:29 While mononuclear, polynuclear, and polymeric metal complexes are most often synthesized by the reaction of a metal precursor and a presynthesized organic ligand, it is also possible to generate the ligand in situ from an easily available organic compound. This approach allows the reactivity of the metal ion to activate a proligand, transforming it through an in situ reaction, sometimes providing coordination compounds with ligands not accessible by conventional organic synthesis. The intense interest in the reactivity of coordinated ligands is mainly due to the necessity of interpreting the mechanisms of homogeneous metal-catalyzed processes, in which a substrate is activated upon its coordination to one or more metal sites. A coordinated oxime group contains three active sites (C, N, O) for reactivity.

152

New Planning Framework  

Science Conference Proceedings (OSTI)

This report describes an investigation into how various regulatory, economic, and technical changes are likely to affect the framework for transmission planning. It begins with an overview of the Existing Planning Framework, structured along the lines of five key aspects that encompass the purview, role, and responsibilities of transmission planning. The report then explores seven scenarios (future states) of transformative change in the electricity industryranging from the greater penetration of wind ge...

2010-12-22T23:59:59.000Z

153

A new 3D nickel(II) framework composed of large rings: Ionothermal synthesis and crystal structure  

SciTech Connect

Ionothermal reaction between Ni{sup 2+} and 1,3,5-benzentricarboxylic acid (H{sub 3}BTC) with [AMI]Cl (AMI=1-amyl-3-methylimidazolium) as the reaction medium produced a novel 3D mixed-ligand metal-organic framework [AMI][Ni{sub 3}(BTC){sub 2}(OAc)(MI){sub 3}] (1) (MI=1-methylimidazole) with [AMI]{sup +} incorporated in the framework. The framework is formed by connecting 2D planes, made up of 32- and 48-membered rings, through 1D chains composed of 32-membered rings. The two BTC{sup 3-} ligands in 1 show the same connectivity mode with two bidentate and one {mu}{sub 2} bridging carboxylic groups. This is a new connectivity mode to the already existing 17 in the Ni-BTC system. The role of MI and [AMI]Cl in the structure formation is discussed. - Graphical Abstract: A novel 3D framework [AMI][Ni{sub 3}(BTC){sub 2}(OAc)(MI){sub 3}] is obtained in ionothermal system with [AMI]{sup +} incorporating in the cavities as structure directing template and BTC{sup 3-} showing a new coordination fashion. The 3D framework is constructed by 2D layers linked with 1D double chains. The title compound has the middle thermal stability at ca. 280 deg. C.

Xu Ling [Department of Chemistry, BK-21 School of Chemical Materials Sciences, Sungkyunkwan University, Suwon 440-746 (Korea, Republic of); Choi, Eun-Young [Institute of Basic Science, Sungkyunkwan University, Suwon 440-746 (Korea, Republic of); Kwon, Young-Uk [Department of Chemistry, BK-21 School of Chemical Materials Sciences, Sungkyunkwan University, Suwon 440-746 (Korea, Republic of); Institute of Basic Science, Sungkyunkwan University, Suwon 440-746 (Korea, Republic of); SKKU Advanced Institute of Nanotechnology, Sungkyunkwan University, Suwon 440-746 (Korea, Republic of)], E-mail: ywkwon@skku.edu

2008-11-15T23:59:59.000Z

154

Organizational images : towards a model of organizations  

E-Print Network (OSTI)

This study develops a general theoretical framework for the analysis of organizational behavior by focusing on the notion that organizations develop unique information-processing frameworks, which it labels "organizational ...

Krishnan, Neel

2012-01-01T23:59:59.000Z

155

An Investment Framework for Clean Energy and Development | Open Energy  

Open Energy Info (EERE)

An Investment Framework for Clean Energy and Development An Investment Framework for Clean Energy and Development Jump to: navigation, search Tool Summary LAUNCH TOOL Name: An Investment Framework for Clean Energy and Development Agency/Company /Organization: World Bank, International Monetary Fund Sector: Energy Focus Area: Energy Efficiency, Renewable Energy, Solar Topics: Finance, Pathways analysis Resource Type: Guide/manual Website: siteresources.worldbank.org/DEVCOMMINT/Documentation/21046509/DC2006-0 An Investment Framework for Clean Energy and Development Screenshot References: An Investment Framework for Clean Energy and Development[1] Overview "This paper reports on progress in developing an Investment Framework for Clean Energy and Development. The Investment Framework is intended to be a vehicle to accelerate investments to address developing country energy

156

Global Framework for Climate Risk Exposure | Open Energy Information  

Open Energy Info (EERE)

Framework for Climate Risk Exposure Framework for Climate Risk Exposure Jump to: navigation, search Tool Summary Name: Global Framework for Climate Risk Exposure Agency/Company /Organization: United Nations Environment Programme Topics: Finance, Co-benefits assessment, Market analysis Resource Type: Publications, Guide/manual Website: www.unepfi.org/fileadmin/documents/global_framework.pdf Global Framework for Climate Risk Exposure Screenshot References: Global Framework for Climate Risk Exposure[1] Summary "A group of leading institutional investors from around the world released the Global Framework for Climate Risk Disclosure-a new statement on disclosure that investors expect from companies-in October 2006. Investors require this information in order to analyze a company's business risks and opportunities resulting from climate change, as well as

157

A framework for warranty management in industrial assets  

Science Conference Proceedings (OSTI)

The objective of this paper is to suggest a management framework for a better organization of warranty assistance, using engineering techniques already developed for similar processes and according to a process-based quality management system. Therefore, ... Keywords: After sales, Industrial assets, Reference framework, Warranty management

V. GonzáLez-Prida; A. Crespo MáRquez

2012-12-01T23:59:59.000Z

158

Metrology For Organic Monolayers On Cobalt Surfaces  

Science Conference Proceedings (OSTI)

... used in: magnetic recording/storage, catalysis, batteries ... Molecule-metal electrode interface crucial ... formation between organic materials and the ...

2013-03-29T23:59:59.000Z

159

Introduction to Framework | Open Energy Information  

Open Energy Info (EERE)

Introduction to Framework Introduction to Framework Jump to: navigation, search Stage 1 LEDS Home Introduction to Framework Assess current country plans, policies, practices, and capacities Develop_BAU Stage 4: Prioritizing and Planning for Actions Begin execution of implementation plans 1.0. Organizing the LEDS Process 1.1. Institutional Structure for LEDS 1.2. Workplan to Develop the LEDS 1.3. Roles and responsibilities to develop LEDS 2.1. Assess current country plans, policies, practices, and capacities 2.2. Compile lessons learned and good practices from ongoing and previous sustainable development efforts in the country 2.3. Assess public and private sector capacity to support initiatives 2.4. Assess and improve the national GHG inventory and other economic and resource data as needed for LEDS development

160

Introduction to Framework | Open Energy Information  

Open Energy Info (EERE)

Introduction to Framework Introduction to Framework (Redirected from Introduction to Methodology) Jump to: navigation, search Stage 1 LEDS Home Introduction to Framework Assess current country plans, policies, practices, and capacities Develop_BAU Stage 4: Prioritizing and Planning for Actions Begin execution of implementation plans 1.0. Organizing the LEDS Process 1.1. Institutional Structure for LEDS 1.2. Workplan to Develop the LEDS 1.3. Roles and responsibilities to develop LEDS 2.1. Assess current country plans, policies, practices, and capacities 2.2. Compile lessons learned and good practices from ongoing and previous sustainable development efforts in the country 2.3. Assess public and private sector capacity to support initiatives 2.4. Assess and improve the national GHG inventory and other

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Knowledge transfer frameworks  

Science Conference Proceedings (OSTI)

While theories abound concerning knowledge transfer in organisations, little empirical work has been undertaken to assess any possible relationship between repositories of knowledge and those responsible for the use of knowledge. This paper develops ... Keywords: hybrid approach, knowledge administration, knowledge management, knowledge storage, knowledge transfer framework

Sajjad M Jasimuddin; Nigel Connell; Jonathan H Klein

2012-05-01T23:59:59.000Z

162

Metal Aminoboranes  

NLE Websites -- All DOE Office Websites (Extended Search)

Metal Aminoboranes Metal Aminoboranes Metal Aminoboranes Metal aminoboranes of the formula M(NH.sub.2BH.sub.3).sub.n have been synthesized. June 25, 2013 Metal Aminoboranes Metal aminoboranes of the formula M(NH.sub.2BH.sub.3).sub.n have been synthesized. Available for thumbnail of Feynman Center (505) 665-9090 Email Metal Aminoboranes Metal aminoboranes of the formula M(NH.sub.2BH.sub.3).sub.n have been synthesized. Metal aminoboranes are hydrogen storage materials. Metal aminoboranes are also precursors for synthesizing other metal aminoboranes. Metal aminoboranes can be dehydrogenated to form hydrogen and a reaction product. The reaction product can react with hydrogen to form a hydrogen storage material. Metal aminoboranes can be included in a kit. U.S. Patent No.: 7,713,506 (DOE S-112,798)

163

Automatically locating framework extension examples  

Science Conference Proceedings (OSTI)

Using and extending a framework is a challenging task whose difficulty is exacerbated by the poor documentation that generally comes with the framework. Even in the presence of documentation, developers often desire implementation examples for concrete ...

Barthélémy Dagenais; Harold Ossher

2008-11-01T23:59:59.000Z

164

Nuclear Safety Regulatory Framework  

NLE Websites -- All DOE Office Websites (Extended Search)

Department of Energy Department of Energy Nuclear Safety Regulatory Framework DOE's Nuclear Safety Enabling Legislation Regulatory Enforcement & Oversight Regulatory Governance Atomic Energy Act 1946 Atomic Energy Act 1954 Energy Reorganization Act 1974 DOE Act 1977 Authority and responsibility to regulate nuclear safety at DOE facilities 10 CFR 830 10 CFR 835 10 CFR 820 Regulatory Implementation Nuclear Safety Radiological Safety Procedural Rules ISMS-QA; Operating Experience; Metrics and Analysis Cross Cutting DOE Directives & Manuals DOE Standards Central Technical Authorities (CTA) Office of Health, Safety, and Security (HSS) Line Management SSO/ FAC Reps 48 CFR 970 48 CFR 952 Federal Acquisition Regulations External Oversight *Defense Nuclear Facility

165

Sustainable Bioenergy: A Framework for Decision Makers | Open Energy  

Open Energy Info (EERE)

Sustainable Bioenergy: A Framework for Decision Makers Sustainable Bioenergy: A Framework for Decision Makers Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Sustainable Bioenergy: A Framework for Decision Makers Agency/Company /Organization: Food and Agriculture Organization of the United Nations Sector: Energy, Land Focus Area: Renewable Energy, Biomass Topics: Implementation, Policies/deployment programs Resource Type: Guide/manual, Lessons learned/best practices Website: esa.un.org/un-energy/pdf/susdev.Biofuels.FAO.pdf References: Sustainable Bioenergy: A Framework for Decision Makers[1] "In this publication, UN-Energy seeks to structure an approach to the current discussion on bioenergy, it is the contribution of the UN system to the issues that need further attention, analysis and valuation, so that

166

Threat Analysis Framework | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Threat Analysis Framework The need to protect national critical infrastructure has led to the development of a threat analysis framework. The threat analysis framework can be...

167

Rwanda-Developing a Strategic Climate Change Framework | Open Energy  

Open Energy Info (EERE)

Rwanda-Developing a Strategic Climate Change Framework Rwanda-Developing a Strategic Climate Change Framework (Redirected from CDKN-Rwanda-Developing a Strategic Climate Change Framework) Jump to: navigation, search Name CDKN-Rwanda-Developing a Strategic Climate Change Framework and Design of a Climate Change and Environmental Fund Agency/Company /Organization Climate and Development Knowledge Network (CDKN), United Kingdom Department for International Development Partner REMA, Government of Rwanda Sector Climate, Energy, Land Topics Background analysis, Low emission development planning, Pathways analysis Website http://cdkn.org/project/a-stra Program Start 2010 Program End 2012 Country Rwanda UN Region Middle Africa References CDKN-Rwanda-Developing a Strategic Climate Change Framework[1] Rwanda's ambitious Green Growth and Climate Resilience Strategy was

168

Innovation in Processing of Light Metals for Transportation Industries  

Science Conference Proceedings (OSTI)

Symposium, Innovation in Processing of Light Metals for Transportation Industries: A Symposium in Honor of C. Ravi Ravindran. Sponsorship. Organizer(

169

Study of Metal Contamination in CMOS Image Sensors by Dark ...  

Science Conference Proceedings (OSTI)

Accelerated Light Induced Degradation, ALID, for Monitoring of Defects in PV Silicon .... Small Molecule/Metal Phthalocyanine Based Organic Photovoltaics.

170

M.: An Ontology-Based Framework for Representing Organizational Knowledge  

E-Print Network (OSTI)

Abstract: This paper describes an ontology-based organizational knowledge representation framework focused on the specification of a two kinds of ontologies: the top level ontology containing concepts characterizing the typical organizational background and COKE ontologies representing so called core organizational knowledge entities. The framework constitutes an abstract representation of organizational knowledge providing a semantic support for designing knowledge management infrastructure able to interoperate with systems already existing in an organization. Moreover, the annotation of COKE w.r.t. the top level ontology allowed by the framework facilitates their semi-automatic handling, retrieval and evolution monitoring.

Andrea Gualtieri; Massimo Ruffolo

2005-01-01T23:59:59.000Z

171

Metal decontamination for waste minimization using liquid metal refining technology  

Science Conference Proceedings (OSTI)

The current Department of Energy Mixed Waste Treatment Project flowsheet indicates that no conventional technology, other than surface decontamination, exists for metal processing. Current Department of Energy guidelines require retrievable storage of all metallic wastes containing transuranic elements above a certain concentration. This project is in support of the National Mixed Low Level Waste Treatment Program. Because of the high cost of disposal, it is important to develop an effective decontamination and volume reduction method for low-level contaminated metals. It is important to be able to decontaminate complex shapes where surfaces are hidden or inaccessible to surface decontamination processes and destruction of organic contamination. These goals can be achieved by adapting commercial metal refining processes to handle radioactive and organic contaminated metal. The radioactive components are concentrated in the slag, which is subsequently vitrified; hazardous organics are destroyed by the intense heat of the bath. The metal, after having been melted and purified, could be recycled for use within the DOE complex. In this project, we evaluated current state-of-the-art technologies for metal refining, with special reference to the removal of radioactive contaminants and the destruction of hazardous organics. This evaluation was based on literature reports, industrial experience, plant visits, thermodynamic calculations, and engineering aspects of the various processes. The key issues addressed included radioactive partitioning between the metal and slag phases, minimization of secondary wastes, operability of the process subject to widely varying feed chemistry, and the ability to seal the candidate process to prevent the release of hazardous species.

Joyce, E.L. Jr.; Lally, B. [Los Alamos National Lab., NM (United States); Ozturk, B.; Fruehan, R.J. [Carnegie-Mellon Univ., Pittsburgh, PA (United States). Dept. of Materials Science and Engineering

1993-09-01T23:59:59.000Z

172

Complex Structure Forewarning System Framework  

This invention is a novel predictive framework to control the in-service health of structures or equipment by ... Oak Ridge National Laboratory Rm ...

173

Framework forensic examination computer systems.  

E-Print Network (OSTI)

??This thesis discusses the features and requirements of a computationally intelligent computer forensic system. By introducing a novel concept, "Case-Relevance", a computationally intelligent forensic framework… (more)

Gong, Ruibin.

2008-01-01T23:59:59.000Z

174

Second Cybersecurity Infrastructure Framework Workshop ...  

Science Conference Proceedings (OSTI)

... framework to reduce cybersecurity risks for critical infrastructure from May 29 ... industry experts in all sectors—such as energy, finance, transportation ...

2013-05-01T23:59:59.000Z

175

Development framework components as commonplaces  

Science Conference Proceedings (OSTI)

This paper examines the practice of using front-end web development frameworks and associated plug-ins to develop web application interfaces and suggests returning to a rhetorical foundation for determining the propriety of code use and vetting of an ... Keywords: code libraries, commonplaces, design, development frameworks, extreme usability, front-end development, rhetoric, topoi, user interfaces

Tom Lindsley

2012-10-01T23:59:59.000Z

176

Light Metals  

Science Conference Proceedings (OSTI)

Alternative processes; Anode design and operation; Cell fundamentals and ... Hot-rolling technologies; Deformation of materials; Primary metal production.

177

Vision for 2025: A Framework for Change  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Action Plan for Energy Effi Action Plan for Energy Effi ciency Vision for 2025: A Framework for Change A RESOURCE OF THE NATIONAL ACTION PLAN FOR ENERGY EFFICIENCY NOVEMBER 2008 Letter from the Co-Chairs of the National Action Plan for Energy Effi ciency November 2008 To all, As you know, the National Action Plan for Energy Effi ciency is playing a vital role in advancing the dialogue and the pursuit of energy effi ciency in our homes, buildings, and industries -an important energy resource for the country. With the commitment and leadership from more than 60 diverse organizations nationwide we have made great progress in a short time. We have: * Developed fi ve broad and meaningful recommendations for pursuing cost-effective energy effi ciency. * Brought together more than 100 organizations from 50 states around this common goal to take energy effi

178

Rwanda-Developing a Strategic Climate Change Framework | Open Energy  

Open Energy Info (EERE)

Rwanda-Developing a Strategic Climate Change Framework Rwanda-Developing a Strategic Climate Change Framework Jump to: navigation, search Name CDKN-Rwanda-Developing a Strategic Climate Change Framework and Design of a Climate Change and Environmental Fund Agency/Company /Organization Climate and Development Knowledge Network (CDKN), United Kingdom Department for International Development Partner REMA, Government of Rwanda Sector Climate, Energy, Land Topics Background analysis, Low emission development planning, Pathways analysis Website http://cdkn.org/project/a-stra Program Start 2010 Program End 2012 Country Rwanda UN Region Middle Africa References CDKN-Rwanda-Developing a Strategic Climate Change Framework[1] Rwanda's ambitious Green Growth and Climate Resilience Strategy was launched at a UNFCCC side event at CoP17 in Durban. Rwanda joins Korea,

179

Energy Forecasting Framework and Emissions Consensus Tool (EFFECT) | Open  

Open Energy Info (EERE)

Energy Forecasting Framework and Emissions Consensus Tool (EFFECT) Energy Forecasting Framework and Emissions Consensus Tool (EFFECT) Jump to: navigation, search LEDSGP green logo.png FIND MORE DIA TOOLS This tool is part of the Development Impacts Assessment (DIA) Toolkit from the LEDS Global Partnership. Tool Summary LAUNCH TOOL Name: Energy Forecasting Framework and Emissions Consensus Tool (EFFECT) Agency/Company /Organization: Energy Sector Management Assistance Program of the World Bank Sector: Energy Focus Area: Non-renewable Energy Topics: Baseline projection, Co-benefits assessment, GHG inventory Resource Type: Software/modeling tools User Interface: Spreadsheet Complexity/Ease of Use: Simple Website: www.esmap.org/esmap/EFFECT Cost: Free Equivalent URI: www.esmap.org/esmap/EFFECT Energy Forecasting Framework and Emissions Consensus Tool (EFFECT) Screenshot

180

Lithium-based inorganic-organic framework materials  

E-Print Network (OSTI)

and thermodynamic conditions can be used to control their phase behaviour, and the main structural factors affecting their relative energies were found to be density and hydrogen bonding. Three crystal structures topologically identical to lithium succinate, Li2(C... and the training and advice I have received, particularly Mary Vickers and Andrew Moss in the X-ray laboratory, Robert Cornell in the polymer lab, Ken Thorn and his team in the workshop, Simon Griggs in the SEM room, Dave Duke, Nathan Cliff and Les Allen...

Yeung, Hamish Hei-Man

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Safer, Denser Acetylene Storage in an Organic Framework  

Science Conference Proceedings (OSTI)

... be of use to the chemical industry in the future. ... substantial savings in acetylene transportation costs,” says ... renders it difficult to transport: It becomes ...

2010-12-29T23:59:59.000Z

182

The FRESCO Framework: An Overview  

E-Print Network (OSTI)

The dynamic composition of existing services into new services is at the core of service-oriented computing. The objective of FRESCO (Foundational Research on Service Composition) is to develop a framework that service providers can use in order to model, develop, and execute composite services. The FRESCO framework will include conceptual tools, such as models for service composition and aggregation. The framework will also include technology elements, such as an integrated development environment and specific components of the infrastructure for service execution. A methodology will be given for the use of the FRESCO framework in the development of composite service solutions. In this paper, we describe the main aspects of the approach to service composition adopted in FRESCO. 1.

Giacomo Piccinelli; Christian Zirpins; Winfried Lamersdorf

2003-01-01T23:59:59.000Z

183

UC SECURITY FRAMEWORK 2011 -2012  

E-Print Network (OSTI)

1 UC SECURITY FRAMEWORK 2011 - 2012 #12;2 Contents Background..................................................................................................................................4 About UC Security & Campus Community Support .................................................................5 Security Service Authority and Relationship with NZ Police and Emergency Services ...........5

Hickman, Mark

184

Precious Metals  

Science Conference Proceedings (OSTI)

"Advances in the Extractive Metallurgy of Selected Rare and Precious Metals" ( 1991 Review of Extractive Metallurgy), J.E. Hoffmann, April 1991, pp. 18-23.

185

A Conceptual Framework for Progressing Towards Sustainability...  

Open Energy Info (EERE)

Conceptual Framework for Progressing Towards Sustainability in the Agriculture and Food Sector Jump to: navigation, search Logo: A Conceptual Framework for Progressing Towards...

186

Treatment of organic waste  

DOE Patents (OSTI)

An organic waste containing at least one element selected from the group consisting of strontium, cesium, iodine and ruthenium is treated to achieve a substantial reduction in the volume of the waste and provide for fixation of the selected element in an inert salt. The method of treatment comprises introducing the organic waste and a source of oxygen into a molten salt bath maintained at an elevated temperature to produce solid and gaseous reaction products. The gaseous reaction products comprise carbon dioxide and water vapor, and the solid reaction products comprise the inorganic ash constituents of the organic waste and the selected element which is retained in the molten salt. The molten salt bath comprises one or more alkali metal carbonates, and may optionally include from 1 to about 25 wt.% of an alkali metal sulfate.

Grantham, LeRoy F. (Calabasas, CA)

1979-01-01T23:59:59.000Z

187

Transportation System Readiness and Resiliency Assessment Framework: Readiness and Assess Resiliency of  

E-Print Network (OSTI)

Transportation System Readiness and Resiliency Assessment Framework: Readiness and Assess Resiliency of Transportation Systems (Infrastructure, Systems, Organization and Services) to Deter, Detect Flows Passenger Flows Supply Chain Efficiency Transportation: Energy Environment Safety Security Vehicle

188

Knowledge organization : Beichuan Middle School architecture design  

E-Print Network (OSTI)

This Thesis is comprised of two interrelated parts: the first part attempts to incorporate Design and Methodology into the framework of Knowledge Organization, tries to refine/ redefine the workflow, and establishes a ...

Song, Kanda

2009-01-01T23:59:59.000Z

189

Ravi Metallics Ltd | Open Energy Information  

Open Energy Info (EERE)

Metallics Ltd Metallics Ltd Jump to: navigation, search Name Ravi Metallics Ltd. Place Rourkela, Orissa, India Zip 769004 Sector Biomass Product Rourkela-based biomass project developer. References Ravi Metallics Ltd.[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Ravi Metallics Ltd. is a company located in Rourkela, Orissa, India . References ↑ "Ravi Metallics Ltd." Retrieved from "http://en.openei.org/w/index.php?title=Ravi_Metallics_Ltd&oldid=350202" Categories: Clean Energy Organizations Companies Organizations Stubs What links here Related changes Special pages Printable version Permanent link Browse properties 429 Throttled (bot load) Error 429 Throttled (bot load)

190

Metal Organic Clathrates for Carbon Dioxide Removal  

removal from coal-fired power plant flue gas streams.  Modified variations of the materials can be used in a variety of other fields as well, ...

191

Magnetism in metal-organic capsules  

E-Print Network (OSTI)

environment for Ni (with two catechol 25 and one pyridinepyramidal Ni centre with two catechol ligands and one axial

Atwood, Jerry L.

2010-01-01T23:59:59.000Z

192

Programmatic Framework | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Programmatic Framework Programmatic Framework Programmatic Framework PROGRAM FACT SHEETS FUSRAP Nevada Offsites UMTRCA Title I and II PROGRAM TYPES UMTRCA Title I Sites UMTRCA Title II Sites FUSRAP Sites D&D Sites Nevada Offsites CERCLA/RCRA Sites NWPA Section 151 Site Other UMTRCA Title I Disposal and Processing Sites (Regulatory Drivers) For UMTRCA Title I disposal sites managed by LM, DOE becomes a licensee to the U.S. Nuclear Regulatory Commission (NRC). Inspection, reporting, and record-keeping requirements are defined in Title 10 Code of Federal Regulations (CFR) Part 40.27, "General License for Custody and Long-Term Care of Residual Radioactive Material Disposal Sites." The general license for long-term custody is indefinite in duration. Usually, title for the land is assigned to an agency of the Federal government, and the land is

193

Framework for SCADA Security Policy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Framework for SCADA Security Policy Framework for SCADA Security Policy Dominique Kilman Jason Stamp dkilman@sandia.gov jestamp@sandia.gov Sandia National Laboratories Albuquerque, NM 87185-0785 Abstract - Modern automation systems used in infrastruc- ture (including Supervisory Control and Data Acquisition, or SCADA) have myriad security vulnerabilities. Many of these relate directly to inadequate security administration, which precludes truly effective and sustainable security. Adequate security management mandates a clear administrative struc- ture and enforcement hierarchy. The security policy is the root document, with sections covering purpose, scope, posi- tions, responsibilities, references, revision history, enforce- ment, and exceptions for various subjects relevant for system

194

A Framework for Bioelectronics: Discovery and Innovation  

Science Conference Proceedings (OSTI)

A Framework for Bioelectronics: Discovery and Innovation. There is an opportunity for dramatically increased synergy between ...

2013-06-25T23:59:59.000Z

195

The Observational?Inductive Framework for Science  

Science Conference Proceedings (OSTI)

A new observational?inductive framework for science is emerging due to recent developments in sensors

Timothy E. Eastman

2006-01-01T23:59:59.000Z

196

NIST Prototypes Framework for Evaluating Sustainability ...  

Science Conference Proceedings (OSTI)

NIST Prototypes Framework for Evaluating Sustainability Standards. ... Whatever the drivers, businesses are boosting their sustainability efforts. ...

2011-10-26T23:59:59.000Z

197

Integrated Global System Modeling Framework | Open Energy Information  

Open Energy Info (EERE)

Integrated Global System Modeling Framework Integrated Global System Modeling Framework Jump to: navigation, search LEDSGP green logo.png FIND MORE DIA TOOLS This tool is part of the Development Impacts Assessment (DIA) Toolkit from the LEDS Global Partnership. Tool Summary LAUNCH TOOL Name: Integrated Global System Modeling Framework Agency/Company /Organization: MIT Joint Program on the Science and Policy of Global Change Sector: Climate, Energy Focus Area: Renewable Energy Phase: Determine Baseline, Evaluate Options Topics: - Macroeconomic Resource Type: Software/modeling tools User Interface: Desktop Application Complexity/Ease of Use: Not Available Website: globalchange.mit.edu/research/IGSM Cost: Free Related Tools Transport Co-benefits Calculator General Equilibrium Modeling Package (GEMPACK)

198

The Offline Software Framework of the Pierre Auger Observatory  

E-Print Network (OSTI)

The Pierre Auger Observatory is designed to unveil the nature and the origins of the highest energy cosmic rays. The large and geographically dispersed collaboration of physicists and the wide-ranging collection of simulation and reconstruction tasks pose some special challenges for the offline analysis software. We have designed and implemented a general purpose framework which allows collaborators to contribute algorithms and sequencing instructions to build up the variety of applications they require. The framework includes machinery to manage these user codes, to organize the abundance of user-contributed configuration files, to facilitate multi-format file handling, and to provide access to event and time-dependent detector information which can reside in various data sources. A number of utilities are also provided, including a novel geometry package which allows manipulation of abstract geometrical objects independent of coordinate system choice. The framework is implemented in C++, and takes advantage...

Argiro, S; González, J; Nellen, L; Paul, T; Porter, T A; Prado, L; Roth, M; Ulrich, R; Veberic, D

2007-01-01T23:59:59.000Z

199

The Offline Software Framework of the Pierre Auger Observatory  

E-Print Network (OSTI)

The Pierre Auger Observatory is designed to unveil the nature and the origins of the highest energy cosmic rays. The large and geographically dispersed collaboration of physicists and the wide-ranging collection of simulation and reconstruction tasks pose some special challenges for the offline analysis software. We have designed and implemented a general purpose framework which allows collaborators to contribute algorithms and sequencing instructions to build up the variety of applications they require. The framework includes machinery to manage these user codes, to organize the abundance of user-contributed configuration files, to facilitate multi-format file handling, and to provide access to event and time-dependent detector information which can reside in various data sources. A number of utilities are also provided, including a novel geometry package which allows manipulation of abstract geometrical objects independent of coordinate system choice. The framework is implemented in C++, and takes advantage...

Argiro, S; González, J; Nellen, L; Paul, T; Porter, T A; Roth, M; Ulrich, R; Veberic, D

2005-01-01T23:59:59.000Z

200

A Framework for Proof Systems  

Science Conference Proceedings (OSTI)

Linear logic can be used as a meta-logic to specify a range of object-level proof systems. In particular, we show that by providing different polarizations within a focused proof system for linear logic, one can account for natural ... Keywords: Focusing, Linear logic, Logical framework, Meta-logic

Vivek Nigam; Dale Miller

2010-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Developing a Regional Recovery Framework  

Science Conference Proceedings (OSTI)

Abstract A biological attack would present an unprecedented challenge for local, state, and federal agencies; the military; the private sector; and individuals on many fronts ranging from vaccination and treatment to prioritization of cleanup actions to waste disposal. To prepare the Seattle region to recover from a biological attack, the Seattle Urban Area Security Initiative (UASI) partners collaborated with military and federal agencies to develop a Regional Recovery Framework for a Biological Attack in the Seattle Urban Area. The goal was to reduce the time and resources required to recover and restore wide urban areas, military installations, and other critical infrastructure following a biological incident by providing a coordinated systems approach. Based on discussions in small workshops, tabletop exercises, and interviews with emergency response agency staff, the partners identified concepts of operation for various areas to address critical issues the region will face as recovery progresses. Key to this recovery is the recovery of the economy. Although the Framework is specific to a catastrophic, wide-area biological attack using anthrax, it was designed to be flexible and scalable so it could also serve as the recovery framework for an all-hazards approach. The Framework also served to coalesce policy questions that must be addressed for long-term recovery. These questions cover such areas as safety and health, security, financial management, waste management, legal issues, and economic development.

Lesperance, Ann M.; Olson, Jarrod; Stein, Steven L.; Clark, Rebecca; Kelly, Heather; Sheline, Jim; Tietje, Grant; Williamson, Mark; Woodcock, Jody

2011-09-01T23:59:59.000Z

202

Autonomic load-testing framework  

Science Conference Proceedings (OSTI)

In this paper, we present a method for performance testing of transactional systems. The methods models the system under test, finds the software and hardware bottlenecks and generate the workloads that saturate them. The framework is autonomic, the ... Keywords: autonomic system, performance models, performance testing, stress testing

Cornel Barna; Marin Litoiu; Hamoun Ghanbari

2011-06-01T23:59:59.000Z

203

A framework for linguistic modelling  

Science Conference Proceedings (OSTI)

A new framework for linguistic reasoning is proposed based on a random set model of the degree of appropriateness of a label. Labels are assumed to be chosen from a finite predefined set of labels and the set of appropriate labels for a value is defined ... Keywords: Bayesian inference, fuzzy labels, label semantics, linguistic constraints, random sets

Jonathan Lawry

2004-05-01T23:59:59.000Z

204

Interoperability Context-Setting Framework  

SciTech Connect

As the deployment of automation technology advances, it touches upon many areas of our corporate and personal lives. A trend is emerging where systems are growing to the extent that integration is taking place with other systems to provide even greater capabilities more efficiently and effectively. GridWise™ provides a vision for this type of integration as it applies to the electric system. Imagine a time in the not too distant future when homeowners can offer the management of their electricity demand to participate in a more efficient and environmentally friendly operation of the electric power grid. They will do this using technology that acts on their behalf in response to information from other components of the electric system. This technology will recognize their preferences to parameters such as comfort and the price of energy to form responses that optimize the local need to a signal that satisfies a higher-level need in the grid. For example, consider a particularly hot day with air stagnation in an area with a significant dependence on wind generation. To manage the forecasted peak electricity demand, the bulk system operator issues a critical peak price warning. Their automation systems alert electric service providers who distribute electricity from the wholesale electricity system to consumers. In response, the electric service providers use their automation systems to inform consumers of impending price increases for electricity. This information is passed to an energy management system at the premises, which acts on the homeowner’s behalf, to adjust the electricity usage of the onsite equipment (which might include generation from such sources as a fuel cell). The objective of such a system is to honor the agreement with the electricity service provider and reduce the homeowner’s bill while keeping the occupants as comfortable as possible. This will include actions such as moving the thermostat on the heating, ventilation, and air-conditioning (HVAC) unit up several degrees. The resulting load reduction becomes part of an aggregated response from the electricity service provider to the bulk system operator who is now in a better position to manage total system load with available generation. Looking across the electric system, from generating plants, to transmission substations, to the distribution system, to factories, office parks, and buildings, automation is growing, and the opportunities for unleashing new value propositions are exciting. How can we facilitate this change and do so in a way that ensures the reliability of electric resources for the wellbeing of our economy and security? The GridWise Architecture Council (GWAC) mission is to enable interoperability among the many entities that interact with the electric power system. A good definition of interoperability is, “The capability of two or more networks, systems, devices, applications, or components to exchange information between them and to use the information so exchanged.” As a step in the direction of enabling interoperability, the GWAC proposes a context-setting framework to organize concepts and terminology so that interoperability issues can be identified and debated, improvements to address issues articulated, and actions prioritized and coordinated across the electric power community.

Widergren, Steven E.; Hardin, Dave; Ambrosio, Ron; Drummond, R.; Gunther, E.; Gilchrist, Grant; Cohen, David

2007-01-31T23:59:59.000Z

205

Legal Frameworks for REDD: Design and Implementation at the National Level  

Open Energy Info (EERE)

Legal Frameworks for REDD: Design and Implementation at the National Level Legal Frameworks for REDD: Design and Implementation at the National Level Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Legal Frameworks for REDD: Design and Implementation at the National Level Agency/Company /Organization: International Union for Conservation of Nature Sector: Land Focus Area: Forestry Topics: Implementation Resource Type: Publications Website: data.iucn.org/dbtw-wpd/edocs/EPLP-077.pdf Legal Frameworks for REDD: Design and Implementation at the National Level Screenshot References: Legal Frameworks for REDD: Design and Implementation at the National Level[1] Summary "This publication identifies and analyzes critical issues in the formulation and implementation of national and sub-national legal frameworks for REDD activities. Lessons are drawn from the wealth of

206

Vitrification of organics-containing wastes  

DOE Patents (OSTI)

A process for stabilizing organics-containing waste materials and recovery metals therefrom, and a waste glass product made according to the process are described. Vitrification of wastes such as organic ion exchange resins, electronic components and the like can be accomplished by mixing at least one transition metal oxide with the wastes, and, if needed, glass formers to compensate for a shortage of silicates or other glass formers in the wastes. The transition metal oxide increases the rate of oxidation of organic materials in the wastes to improve the composition of the glass-forming mixture: at low temperatures, the oxide catalyzes oxidation of a portion of the organics in the waste; at higher temperatures, the oxide dissolves and the resulting oxygen ions oxidize more of the organics; and at vitrification temperatures, the metal ions conduct oxygen into the melt to oxidize the remaining organics. In addition, the transition metal oxide buffers the redox potential of the glass melt so that metals such as Au, Pt, Ag, and Cu separate form the melt in the metallic state and can be recovered. After the metals are recovered, the remainder of the melt is allowed to cool and may subsequently be disposed of. The product has good leaching resistance and can be disposed of in an ordinary landfill, or, alternatively, used as a filler in materials such as concrete, asphalt, brick and tile.

Bickford, D.F.

1995-01-01T23:59:59.000Z

207

Vitrification of organics-containing wastes  

DOE Patents (OSTI)

A process is described for stabilizing organics-containing waste materials and recovering metals therefrom, and a waste glass product made according to the process is also disclosed. Vitrification of wastes such as organic ion exchange resins, electronic components and the like can be accomplished by mixing at least one transition metal oxide with the wastes, and, if needed, glass formers to compensate for a shortage of silicates or other glass formers in the wastes. The transition metal oxide increases the rate of oxidation of organic materials in the wastes to improve the composition of the glass-forming mixture: at low temperatures, the oxide catalyzes oxidation of a portion of the organics in the waste; at higher temperatures, the oxide dissolves and the resulting oxygen ions oxidize more of the organics; and at vitrification temperatures, the metal ions conduct oxygen into the melt to oxidize the remaining organics. In addition, the transition metal oxide buffers the redox potential of the glass melt so that metals such as Au, Pt, Ag, and Cu separate from the melt in the metallic state and can be recovered. After the metals are recovered, the remainder of the melt is allowed to cool and may subsequently be disposed of. The product has good leaching resistance and can be disposed of in an ordinary landfill, or, alternatively, used as a filler in materials such as concrete, asphalt, brick and tile. 1 fig.

Bickford, D.F.

1997-09-02T23:59:59.000Z

208

Recipients: 2006 Light Metals Division JOM Best Paper Award  

Science Conference Proceedings (OSTI)

STAFF DIRECTORY ... activities has clearly facilitated the Society's capability to serve its light metals-oriented members and their supporting organizations.

209

Organization Chart  

NLE Websites -- All DOE Office Websites (Extended Search)

and Mission Organization Staff - Organization Chart About Us Bob Cottingham, 865-241-0554 Computational Biology and Bioinformatics Meghan Drake 865-241-8288 Michael...

210

Science Organizations  

NLE Websites -- All DOE Office Websites (Extended Search)

Organizations Science Organizations National security depends on science and technology. The United States relies on Los Alamos National Laboratory for the best of both. No place...

211

A Framework for Green Computing  

Science Conference Proceedings (OSTI)

Many organizations attempt to implement Green ICT. Some adopt a deliberate and holistic policy, but most approach it piecemeal. The formal definition and approach to implementing Green ICT remains elusive, because most organizations are unable to properly ... Keywords: Benchmarking, Green Computing, Green ICT, IT, Implementation

Graeme Philipson

2011-01-01T23:59:59.000Z

212

A General Framework for Convective Trigger Functions  

Science Conference Proceedings (OSTI)

A general framework for the trigger function used in convective parameterization routines in mesoscale models is proposed. The framework is based on the diagnosis of the accessibility of potential buoyant energy. Specifically, the trigger ...

Robert F. Rogers; J. M. Fritsch

1996-11-01T23:59:59.000Z

213

Toward a Systematic Framework for Deploying Synchrophasors  

E-Print Network (OSTI)

Toward a Systematic Framework for Deploying Synchrophasors and their Utilization for Improving for Deploying Synchrophasors and their Utilization for Improving Performance of Future Electric Energy Systems a Systematic Framework for Deploying Synchrophasors and their Utilization for Improving Performance of Future

214

Metis: a thin-client application framework  

Science Conference Proceedings (OSTI)

This paper introduces a thin-client programming model and then presents an object-oriented framework for developing applications using the model. The programming model and the framework have evolved from interactions with developers and users of commercial ...

Deborra J. Zukowski; Apratim Purakayastha; Ajay Mohindra; Murthy Devarakonda

1997-06-01T23:59:59.000Z

215

A General Framework for Forecast Verification  

Science Conference Proceedings (OSTI)

A general framework for forecast verification based on the joint distribution of forecasts and observations is described. For further elaboration of the framework, two factorizations of the joint distribution are investigated: 1) the calibration-...

Allan H. Murphy; Robert L. Winkler

1987-07-01T23:59:59.000Z

216

DRAFT Outline - Preliminary Framework to Reduce Cyber ...  

Science Conference Proceedings (OSTI)

Page 1. 1 DRAFT Outline - Preliminary Framework to Reduce Cyber Risks to Critical Infrastructure, July 1, 2013 NOTES ...

2013-07-02T23:59:59.000Z

217

Developing a Framework to Improve Critical Infrastructure ...  

Science Conference Proceedings (OSTI)

... To that end any risk framework ... financial, telecommunications, transportation, energy, chemical, information ... heating and cooling, physical security ...

2013-04-08T23:59:59.000Z

218

DOE Competency Framework | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

managers, and supervisors. DOE Competency Framework More Documents & Publications Federal Employee Training Desk Reference DOE Competency Dictionary DOE General Competencies...

219

Comparison of Novel Microstructure Quantification Frameworks for ...  

Science Conference Proceedings (OSTI)

Bayesian inference of grain boundary properties from heterogeneous data · Comparison of Novel Microstructure Quantification Frameworks for Visualization,  ...

220

A framework for knowledge-based team training  

E-Print Network (OSTI)

Teamwork is crucial to many disciplines, from activities such as organized sports to economic and military organizations. Team training is difficult and as yet there are few automated tools to assist in the training task. As with the training of individuals, effective training depends upon practice and proper training protocols. In this research, we defined a team training framework for constructing team training systems in domains involving command and control teams. This team training framework provides an underlying model of teamwork and programming interfaces to provide services that ease the construction of team training systems. Also, the framework enables experimentation with training protocols and coaching to be conducted more readily, as team training systems incorporating new protocols or coaching capabilities can be more easily built. For this framework (called CAST-ITT) we developed an underlying intelligent agent architecture known as CAST (Collaborative Agents Simulating Teamwork). CAST provides the underlying model of teamwork and agents to simulate virtual team members. CAST-ITT (Intelligent Team Trainer) uses CAST to also monitor trainees, and support performance assessment and coaching for the purposes of evaluating the performance of a trainee as a member of a team. CAST includes a language for describing teamwork called MALLET (Multi-Agent Logic Language for Encoding Teamwork). MALLET allows us to codify the behaviors of team members (both as virtual agents and as trainees) for use by CAST. In demonstrating CAST-ITT through an implemented team training system called TWP-DDD we have shown that a team training system can be built that uses the framework (CAST-ITT) and has good performance and can be used for achieving real world training objectives.

Miller, Michael Scott

2006-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Thermostat Metals  

Science Conference Proceedings (OSTI)

...A thermostat metal is a composite material (usually in the form of sheet or strip) that consists of two or more materials bonded together, of which one can be a nonmetal. Because the materials bonded together to form the composite differ in

222

METAL COMPOSITIONS  

DOE Patents (OSTI)

Alloys of uranium which are strong, hard, and machinable are presented, These alloys of uranium contain bctween 0.1 to 5.0% by weight of at least one noble metal such as rhodium, palladium, and gold. The alloys may be heat treated to obtain a product with iniproved tensile and compression strengths,

Seybolt, A.U.

1959-02-01T23:59:59.000Z

223

The CloudBrowser web application framework  

Science Conference Proceedings (OSTI)

CloudBrowser is a web application framework that supports the development of rich Internet applications whose entire user interface and application logic resides on the server, while all client/server communication is provided by the framework. CloudBrowser ... Keywords: ajax, cloud applications, paas, remote display, server-centric, web application framework

Brian McDaniel; Godmar Back

2012-10-01T23:59:59.000Z

224

Organization | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

About Us Organization Organization Leadership Organization History Careers Contact Us Organization...

225

Functional Metal Phosphonates  

E-Print Network (OSTI)

The primary goal of the work described in this dissertation was the incorporation of functionality into metal phosphonates. This was done in one of several ways. The first involved using phosphonate ligands that had covalently attached organic functional groups. In some cases, these ligands undergo reactions during the solvothermal syntheses which can impart new chemical reactivity. Another method used to introduce functionality was to partially or completely substitute metal atoms within phosphonate clusters to create materials which may have interesting magnetic properties. By controlling the way these clusters pack in the solids, their magnetic properties may be able to be augmented. The final method used to impart functionality to metal phosphonates was the incorporation of N-donor and bulky aryl groups into the phosphonate ligands. These influences caused structural variations which exposed potentially active sites within the materials, including both Lewis acidic and basic sites, as well as Bronsted acid sites. The first strategy was employed in the design of tetravalent metal phosphonates which have covalently incorporated bipyridine moieties. The materials are porous so that the bipyridine sites can chelate Pd atoms from solution, which can then be reduced to stable nanoparticles trapped within the phosphonate matrix. This approach was also used in the synthesis of surface-functionalized divalent metal phosphonates which exhibit interesting amine uptake properties. Solvent and cation substitution effects were used to control the packing and connectivity of phosphonate-based clusters. The selective substitution of metal atoms within the clusters may lead to interesting magnetic materials. In other work, N-donor and bulky phosphonates were used to influence the structure of several SnII phosphonates, which resulted in the discovery of a new layered structure type. The effect of the Sn-N interaction on the structures is investigated, and found to have significant effects on the structural units formed and how they pack in the solid state. The work presented herein represents only a small fraction of the rich chemistry of metal phosphonates. Creative researchers will continue to push boundaries and find new and interesting applications for phosphonate-based materials.

Perry, Houston Phillipp

2011-12-01T23:59:59.000Z

226

METAL EXTRACTION PROCESS  

DOE Patents (OSTI)

An improved method for extracting uranium from aqueous solutions by solvent extraction is presented. A difficulty encountered in solvent extraction operations using an organic extractant (e.g., tributyl phosphate dissolved in kerosene or carbon tetrachloride) is that emulsions sometimes form, and phase separation is difficult or impossible. This difficulty is overcome by dissolving the organic extractant in a molten wax which is a solid at operating temperatures. After cooling, the wax which now contains the extractant, is broken into small particles (preferably flakes) and this wax complex'' is used to contact the uranium bearing solutions and extract the metal therefrom. Microcrystalline petroleum wax and certain ethylene polymers have been found suitable for this purpose.

Lewis, G.W. Jr.; Rhodes, D.E.

1957-11-01T23:59:59.000Z

227

The Offline Software Framework of the Pierre Auger Observatory  

E-Print Network (OSTI)

The Pierre Auger Observatory is designed to unveil the nature and the origins of the highest energy cosmic rays. The large and geographically dispersed collaboration of physicists and the wide-ranging collection of simulation and reconstruction tasks pose some special challenges for the offline analysis software. We have designed and implemented a general purpose framework which allows collaborators to contribute algorithms and sequencing instructions to build up the variety of applications they require. The framework includes machinery to manage these user codes, to organize the abundance of user-contributed configuration files, to facilitate multi-format file handling, and to provide access to event and time-dependent detector information which can reside in various data sources. A number of utilities are also provided, including a novel geometry package which allows manipulation of abstract geometrical objects independent of coordinate system choice. The framework is implemented in C++, and takes advantage of object oriented design and common open source tools, while keeping the user side simple enough for C++ novices to learn in a reasonable time. The distribution system incorporates unit and acceptance testing in order to support rapid development of both the core framework and contributed user code.

S. Argiro; S. L. C. Barroso; J. Gonzalez; L. Nellen; T. Paul; T. A. Porter; L. Prado Jr.; M. Roth; R. Ulrich; D. Veberic

2007-07-11T23:59:59.000Z

228

The Offline Software Framework of the Pierre Auger Observatory  

E-Print Network (OSTI)

The Pierre Auger Observatory is designed to unveil the nature and the origins of the highest energy cosmic rays. The large and geographically dispersed collaboration of physicists and the wide-ranging collection of simulation and reconstruction tasks pose some special challenges for the offline analysis software. We have designed and implemented a general purpose framework which allows collaborators to contribute algorithms and sequencing instructions to build up the variety of applications they require. The framework includes machinery to manage these user codes, to organize the abundance of user-contributed configuration files, to facilitate multi-format file handling, and to provide access to event and time-dependent detector information which can reside in various data sources. A number of utilities are also provided, including a novel geometry package which allows manipulation of abstract geometrical objects independent of coordinate system choice. The framework is implemented in C++, and takes advantage of object oriented design and common open source tools, while keeping the user side simple enough for C++ novices to learn in a reasonable time. The distribution system incorporates unit and acceptance testing in order to support rapid development of both the core framework and contributed user code.

S. Argiro; S. L. C Barroso; J. Gonzalez; L. Nellen; T. Paul; T. A. Porter; L. Prado Jr.; M. Roth; R. Ulrich; D. Veberic

2006-01-01T23:59:59.000Z

229

The offline software framework of the Pierre Auger Observatory  

SciTech Connect

The Pierre Auger Observatory is designed to unveil the nature and origin of the highest energy cosmic rays through the analysis of extensive air showers. The large and geographically dispersed collaboration of physicists and the wide-ranging collection of simulation and reconstruction tasks pose some special challenges for the offline analysis software. They have designed and implemented a general purpose framework which allows Auger collaborators to contribute algorithms and configuration instructions to build up the variety of applications they require. The framework includes machinery to manage these user codes, to organize the abundance of user-contributed configuration files, to facilitate multi-format file handling, and to provide access to event and time-dependent detector information residing in many data sources. A number of utilities are also provided, including a novel geometry package allowing manipulation of abstract geometrical objects independent of coordinate system choice. The framework is implemented in C++ and takes advantage of object oriented design and common open source tools, while keeping the user-side simple enough for C++ novices to learn in a reasonable time. The distribution system incorporates unit and acceptance testing in order to support rapid development of both the core framework and the contributed user codes.

Argiro, S.; Barroso, S.L.C.; Dagoret-Campagne, S.; Gonzalez, Javier G.; Nellen, L.; Paul, T.; Porter, T.; Prado, L., Jr.; Roth, M.; Ulrich, R.; Veberic, D.

2005-08-01T23:59:59.000Z

230

NIST Organization  

Science Conference Proceedings (OSTI)

... What We Do; Organization Chart; Budget Information; Office of the Director; Laboratories & Major Programs; Locations; Staff Directory; Working With ...

2013-02-19T23:59:59.000Z

231

Symposium Organizer  

Science Conference Proceedings (OSTI)

Volunteer Training Module. March 2013. 1. Your Professional Partner for Career Advancement. Symposium Organizer. Online Training Module. March 2013 ...

232

Specific complexation of metal oxo cations  

DOE Patents (OSTI)

The present invention relates to novel chelating agents for high molecular weight polyvalent metal oxo cations. Specifically, an improved chelating agent and an improved process of chelation is described to recognize specifically metal oxo cations using organic chelating agents that have a functional group to supply donor groups for metal coordination while simultaneously providing a different group to intramolecularly interact with the oxygen of the oxo group. More precisely, the invention relates to tripodal amine carboxylates useful to sequester uranyl and related metal oxo cations in aqueous solution, and is especially suitable for recovering such oxo cations from dilute aqueous solutions, e.g. seawater, mine runoff, processing waste streams, etc.

Raymond, K.N.; Franczyk, T.S.

1990-12-17T23:59:59.000Z

233

Bottom Up and Country Led: A New Framework for Climate Action | Open Energy  

Open Energy Info (EERE)

Bottom Up and Country Led: A New Framework for Climate Action Bottom Up and Country Led: A New Framework for Climate Action Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Bottom Up and Country Led: A New Framework for Climate Action Agency/Company /Organization: Booz and Company Sector: Energy, Land, Climate Topics: Low emission development planning Resource Type: Publications Website: www.booz.com/global/home/what_we_think/reports_and_white_papers/ic-dis Cost: Free Bottom Up and Country Led: A New Framework for Climate Action Screenshot References: Bottom Up and Country Led: A New Framework for Climate Action[1] "As delegates gather for the Climate Change Conference in Cancun in late 2010, they can benefit from familiarizing themselves with the set of tools available for mitigation and adaptation, as well as how these tools can fit

234

Department of Energy Releases Vision & Framework for the U.S. Climate  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Vision & Framework for the U.S. Vision & Framework for the U.S. Climate Change Technology Program Department of Energy Releases Vision & Framework for the U.S. Climate Change Technology Program August 5, 2005 - 2:38pm Addthis WASHINGTON, DC -- In a speech before the Climate Policy Center in Washington, D.C., David Conover, Director of the Department of Energy's Climate Change Technology Program (CCTP), today announced the release of the department's Vision and Framework for Strategy and Planning report on behalf of Secretary of Energy Samuel Bodman. The report provides strategic direction and guidance to the 10 Federal agencies developing new and advanced global climate change technologies. The Vision and Framework document is organized around six complementary goals: (1) reducing emissions from energy use and infrastructure; (2)

235

Energy Conservation in Metals  

Science Conference Proceedings (OSTI)

About this Symposium. Meeting, 2010 TMS Annual Meeting & Exhibition. Symposium, Energy Conservation in Metals. Sponsorship, The Minerals, Metals and ...

236

Ambient-pressure organic superconductor  

DOE Patents (OSTI)

A new class of organic superconductors having the formula (ET).sub.2 MX.sub.2 wherein ET represents bis(ethylenedithio)-tetrathiafulvalene, M is a metal such as Au, Ag, In, Tl, Rb, Pd and the like and X is a halide. The superconductor (ET).sub.2 AuI.sub.2 exhibits a transition temperature of 5 K which is high for organic superconductors.

Williams, Jack M. (Downers Grove, IL); Wang, Hsien-Hau (Willowbrook, IL); Beno, Mark A. (Woodridge, IL)

1986-01-01T23:59:59.000Z

237

Metal resistance sequences and transgenic plants  

DOE Patents (OSTI)

The present invention provides nucleic acid sequences encoding a metal ion resistance protein, which are expressible in plant cells. The metal resistance protein provides for the enzymatic reduction of metal ions including but not limited to divalent Cu, divalent mercury, trivalent gold, divalent cadmium, lead ions and monovalent silver ions. Transgenic plants which express these coding sequences exhibit increased resistance to metal ions in the environment as compared with plants which have not been so genetically modified. Transgenic plants with improved resistance to organometals including alkylmercury compounds, among others, are provided by the further inclusion of plant-expressible organometal lyase coding sequences, as specifically exemplified by the plant-expressible merB coding sequence. Furthermore, these transgenic plants which have been genetically modified to express the metal resistance coding sequences of the present invention can participate in the bioremediation of metal contamination via the enzymatic reduction of metal ions. Transgenic plants resistant to organometals can further mediate remediation of organic metal compounds, for example, alkylmetal compounds including but not limited to methyl mercury, methyl lead compounds, methyl cadmium and methyl arsenic compounds, in the environment by causing the freeing of mercuric or other metal ions and the reduction of the ionic mercury or other metal ions to the less toxic elemental mercury or other metals.

Meagher, Richard Brian (Athens, GA); Summers, Anne O. (Athens, GA); Rugh, Clayton L. (Athens, GA)

1999-10-12T23:59:59.000Z

238

Ghana-Support for Future National Climate Change Policy Framework | Open  

Open Energy Info (EERE)

Page Page Edit with form History Facebook icon Twitter icon » Ghana-Support for Future National Climate Change Policy Framework Jump to: navigation, search Name CDKN-Ghana-Support for Future National Climate Change Policy Framework Agency/Company /Organization Climate and Development Knowledge Network (CDKN), United Kingdom Department for International Development Partner Energy Research Centre of the Netherlands (ECN), University of Ghana Sector Climate, Energy, Land Topics Background analysis, Low emission development planning, Pathways analysis Website http://cdkn.org/project/assist Program Start 2010 Program End 2011 Country Ghana UN Region Western Africa References CDKN-Ghana-Support for Future National Climate Change Policy Framework[1] Policy brief[2]

239

Catalyzed Nano-Framework Stablized High Density Reversible Hydrogen Storage Systems  

Science Conference Proceedings (OSTI)

A wide range of high capacity on-board rechargeable material candidates have exhibited non-ideal behavior related to irreversible hydrogen discharge / recharge behavior, and kinetic instability or retardation. This project addresses these issues by incorporating solvated and other forms of complex metal hydrides, with an emphasis on borohydrides, into nano-scale frameworks of low density, high surface area skeleton materials to stabilize, catalyze, and control desorption product formation associated with such complex metal hydrides. A variety of framework chemistries and hydride / framework combinations were investigated to make a relatively broad assessment of the method'Â?s potential. In this project, the hydride / framework interactions were tuned to decrease desorption temperatures for highly stable compounds or increase desorption temperatures for unstable high capacity compounds, and to influence desorption product formation for improved reversibility. First principle modeling was used to explore heterogeneous catalysis of hydride reversibility by modeling H{sub 2} dissociation, hydrogen migration, and rehydrogenation. Atomic modeling also demonstrated enhanced NaTi(BH{sub 4}){sub 4} stabilization at nano-framework surfaces modified with multi-functional agents. Amine multi-functional agents were found to have more balanced interactions with nano-framework and hydride clusters than other functional groups investigated. Experimentation demonstrated that incorporation of Ca(BH{sub 4}){sub 2} and Mg(BH{sub 4}){sub 2} in aerogels enhanced hydride desorption kinetics. Carbon aerogels were identified as the most suitable nano-frameworks for hydride kinetic enhancement and high hydride loading. High loading of NaTi(BH{sub 4}){sub 4} ligand complex in SiO{sub 2} aerogel was achieved and hydride stability was improved with the aerogel. Although improvements of desorption kinetics was observed, the incorporation of Ca(BH{sub 4}){sub 2} and Mg(BH{sub 4}){sub 2} in nano-frameworks did not improve their H{sub 2} absorption due to the formation of stable alkaline earth B12H12 intermediates upon rehydrogenation. This project primarily investigated the effect of nano-framework surface chemistry on hydride properties, while the effect of pore size is the focus area of other efforts (e.g., HRL, Sandia National Laboratories (SNL) etc.) within the Metal Hydride Center of Excellence (MHCoE). The projects were complementary in gaining an overall understanding of the influence of nano-frameworks on hydride behavior.

Xia Tang , Susanne M. Opalka , Daniel A. Mosher, Bruce L. Laube, Ronald J. Brown, Thomas H. Vanderspurt, Sarah Arsenault, Robert Wu, Jamie Strickler, Ewa. Ronnebro, Tim. Boyle and Joseph Cordaro

2010-06-30T23:59:59.000Z

240

Removal of metal ions from aqueous solution  

DOE Patents (OSTI)

A method of removing heavy metals from aqueous solution, a composition of matter used in effecting said removal, and apparatus used in effecting said removal. One or more of the polypeptides, poly ({gamma}-glutamylcysteinyl)glycines, is immobilized on an inert material in particulate form. Upon contact with an aqueous solution containing heavy metals, the polypeptides sequester the metals, removing them from the solution. There is selectivity of poly ({gamma}-glutamylcysteinyl)glycines having a particular number of monomer repeat units for particular metals. The polypeptides are easily regenerated by contact with a small amount of an organic acid, so that they can be used again to remove heavy metals from solution. This also results in the removal of the metals from the column in a concentrated form.

Jackson, P.J.; Delhaize, E.; Robinson, N.J.; Unkefer, C.J.; Furlong, C.

1988-08-26T23:59:59.000Z

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Removal of metal ions from aqueous solution  

DOE Patents (OSTI)

A method of removing heavy metals from aqueous solution, a composition of matter used in effecting said removal, and apparatus used in effecting said removal. One or more of the polypeptides, poly (.gamma.-glutamylcysteinyl)glycines, is immobilized on an inert material in particulate form. Upon contact with an aqueous solution containing heavy metals, the polypeptides sequester the metals, removing them from the solution. There is selectivity of poly (.gamma.-glutamylcysteinyl)glycines having a particular number of monomer repeat units for particular metals. The polypeptides are easily regenerated by contact with a small amount of an organic acid, so that they can be used again to remove heavy metals from solution. This also results in the removal of the metals from the column in a concentrated form.

Jackson, Paul J. (Los Alamos, NM); Delhaize, Emmanuel (Los Alamos, NM); Robinson, Nigel J. (Durham, GB2); Unkefer, Clifford J. (Los Alamos, NM); Furlong, Clement (Seattle, WA)

1990-01-01T23:59:59.000Z

242

Removal of metal ions from aqueous solution  

DOE Patents (OSTI)

A method of removing heavy metals from aqueous solution, a composition of matter used in effecting said removal, and apparatus used in effecting said removal. One or more of the polypeptides, poly (.gamma.-glutamylcysteinyl)glycines, is immobilized on an inert material in particulate form. Upon contact with an aqueous solution containing heavy metals, the polypeptides sequester the metals, removing them from the solution. There is selectivity of poly (.gamma.-glutamylcysteinyl)glycines having a particular number of monomer repeat unit for particular metals. The polypeptides are easily regenerated by contact with a small amount of an organic acid, so that they can be used again to remove heayv metals from solution. This also results in the removal of the metals from the column in a concentrated form.

Jackson, Paul J. (both Los Alamos, NM); Delhaize, Emmanuel (both Los Alamos, NM); Robinson, Nigel J. (Durham, GB2); Unkefer, Clifford J. (Los Alamos, NM); Furlong, Clement (Seattle, WA)

1990-11-13T23:59:59.000Z

243

Mechanochemical processing for metals and metal alloys  

DOE Patents (OSTI)

A set of processes for preparing metal powders, including metal alloy powders, by ambient temperature reduction of a reducible metal compound by a reactive metal or metal hydride through mechanochemical processing. The reduction process includes milling reactants to induce and complete the reduction reaction. The preferred reducing agents include magnesium and calcium hydride powders. A process of pre-milling magnesium as a reducing agent to increase the activity of the magnesium has been established as one part of the invention.

Froes, Francis H. (Moscow, ID); Eranezhuth, Baburaj G. (Moscow, ID); Prisbrey, Keith (Moscow, ID)

2001-01-01T23:59:59.000Z

244

Developing a Regulatory Framework for Extended Storage and Transportat...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Storage and Transportation Developing a Regulatory Framework for Extended Storage and Transportation Outline: Current Regulatory Framework Future Regulatory Needs Technical...

245

Modeling the mechanical behavior of amorphous metals by shear transformation zone dynamics  

E-Print Network (OSTI)

A new mesoscale modeling technique for the thermo-mechanical behavior of amorphous metals is proposed. The modeling framework considers the shear transformation zone (STZ) as the fundamental unit of deformation, and ...

Homer, Eric Richards, 1980-

2010-01-01T23:59:59.000Z

246

Microsoft Word - DOE Framework Final.docx  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Washington, D.C. 20585 Washington, D.C. 20585 Hanford Tank Waste Retrieval, Treatment, and Disposition Framework September 24, 2013 Hanford Tank Waste Retrieval, Treatment, and Disposition Framework ii This page intentionally left blank. Hanford Tank Waste Retrieval, Treatment, and Disposition Framework iii CONTENTS 1. Introduction ............................................................................................................................................. 1 Immobilizing Radioactive Tank Waste at the Office of River Protection .................................................. 1 Current System Design ........................................................................................................................... 2 Addressing Technical Risks and Challenges .......................................................................................... 2

247

LEDS Toolkit and Framework | Open Energy Information  

Open Energy Info (EERE)

LEDS Toolkit and Framework LEDS Toolkit and Framework Jump to: navigation, search Tool Summary LAUNCH TOOL Name: LEDS Toolkit and Methodology Agency/Company /Organization: National Renewable Energy Laboratory Sector: Energy, Land, Water, Climate Topics: Low emission development planning Resource Type: Dataset User Interface: Website, Desktop Application Website: en.openei.org/apps/LEDS/ Cost: Free UN Region: Central Asia, Eastern Asia, South-Eastern Asia, "Pacific" is not in the list of possible values (Eastern Africa, Middle Africa, Northern Africa, Southern Africa, Western Africa, Caribbean, Central America, South America, Northern America, Central Asia, Eastern Asia, Southern Asia, South-Eastern Asia, Western Asia, Eastern Europe, Northern Europe, Southern Europe, Western Europe, Australia and New Zealand, Melanesia, Micronesia, Polynesia, Latin America and the Caribbean) for this property., "Latin America and Caribbean" is not in the list of possible values (Eastern Africa, Middle Africa, Northern Africa, Southern Africa, Western Africa, Caribbean, Central America, South America, Northern America, Central Asia, Eastern Asia, Southern Asia, South-Eastern Asia, Western Asia, Eastern Europe, Northern Europe, Southern Europe, Western Europe, Australia and New Zealand, Melanesia, Micronesia, Polynesia, Latin America and the Caribbean) for this property., "Western Asia & North Africa" is not in the list of possible values (Eastern Africa, Middle Africa, Northern Africa, Southern Africa, Western Africa, Caribbean, Central America, South America, Northern America, Central Asia, Eastern Asia, Southern Asia, South-Eastern Asia, Western Asia, Eastern Europe, Northern Europe, Southern Europe, Western Europe, Australia and New Zealand, Melanesia, Micronesia, Polynesia, Latin America and the Caribbean) for this property., Northern America, "South Asia" is not in the list of possible values (Eastern Africa, Middle Africa, Northern Africa, Southern Africa, Western Africa, Caribbean, Central America, South America, Northern America, Central Asia, Eastern Asia, Southern Asia, South-Eastern Asia, Western Asia, Eastern Europe, Northern Europe, Southern Europe, Western Europe, Australia and New Zealand, Melanesia, Micronesia, Polynesia, Latin America and the Caribbean) for this property., "Sub-Saharan Africa" is not in the list of possible values (Eastern Africa, Middle Africa, Northern Africa, Southern Africa, Western Africa, Caribbean, Central America, South America, Northern America, Central Asia, Eastern Asia, Southern Asia, South-Eastern Asia, Western Asia, Eastern Europe, Northern Europe, Southern Europe, Western Europe, Australia and New Zealand, Melanesia, Micronesia, Polynesia, Latin America and the Caribbean) for this property., "Western & Eastern Europe" is not in the list of possible values (Eastern Africa, Middle Africa, Northern Africa, Southern Africa, Western Africa, Caribbean, Central America, South America, Northern America, Central Asia, Eastern Asia, Southern Asia, South-Eastern Asia, Western Asia, Eastern Europe, Northern Europe, Southern Europe, Western Europe, Australia and New Zealand, Melanesia, Micronesia, Polynesia, Latin America and the Caribbean) for this property.

248

Building Energy Transparency: A Framework for Implementing.....  

NLE Websites -- All DOE Office Websites (Extended Search)

Energy Transparency: A Framework for Implementing... Energy Rating & Disclosure Policy Secondary menu About us Press room Contact Us Portfolio Manager Login Facility owners and...

249

California Evaluation Framework | Building Energy Codes Program  

NLE Websites -- All DOE Office Websites (Extended Search)

those studies. bpCaliforniaEvaluationFramework.pdf Document Details Affiliation: California Public Utilities Commission and the Project Advisory Group Focus: Adoption...

250

Gas sensor incorporating a porous framework  

DOE Patents (OSTI)

The disclosure provides sensor for gas sensing including CO.sub.2 gas sensors comprising a porous framework sensing area for binding an analyte gas.

Yaghi, Omar M.; Czaja, Alexander U.; Wang, Bo; Furukawa, Hiroyasu; Galatsis, Kosmas; Wang, Kang L.

2013-07-09T23:59:59.000Z

251

Enterprise Risk Management (ERM) Framework for Directives  

Directives, Delegations, and Requirements

Explains the new ERM framework for developing, revising, and reviewing directives. This memo directs the Office of Management to institutionalize ERM into the ...

2012-07-09T23:59:59.000Z

252

Organization Chart  

NLE Websites -- All DOE Office Websites (Extended Search)

spacer spacer spacer About DOE Organization News Contact Us Search Search Go spacer U.S. Department of Energy header image Science & Technology Energy Sources Energy Efficiency...

253

Method of photocatalytic conversion of C-H organics  

DOE Patents (OSTI)

The present invention is the addition of a semiconductor material and energy to the reaction mixture of organic, acid (for example, trifluoroacetate), and oxygen. A transition metal ion may be added to the reaction mixture. The semiconductor material converts energy to oxidants thereby promoting oxidation of the organic. Alternatively, using metal in combination with exposure to light may be used.

Camaioni, Donald M. (Richland, WA); Lilga, Michael A. (Richland, WA)

1998-01-01T23:59:59.000Z

254

ALU NIST Cybersecurity Framework Comments FINAL  

Science Conference Proceedings (OSTI)

... Examples of “controls” would be battery backup ... an organization's systems from their start through their end of life. An organization ...

2013-04-09T23:59:59.000Z

255

Extracting metals directly from metal oxides  

DOE Patents (OSTI)

A method of extracting metals directly from metal oxides by exposing the oxide to a supercritical fluid solvent containing a chelating agent is described. Preferably, the metal is an actinide or a lanthanide. More preferably, the metal is uranium, thorium or plutonium. The chelating agent forms chelates that are soluble in the supercritical fluid, thereby allowing direct removal of the metal from the metal oxide. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of .beta.-diketones, halogenated .beta.-diketones, phosphinic acids, halogenated phosphinic acids, carboxylic acids, halogenated carboxylic acids, and mixtures thereof. In especially preferred embodiments, at least one of the chelating agents is fluorinated. The method provides an environmentally benign process for removing metals from metal oxides without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the metal recovered, to provide an economic, efficient process.

Wai, Chien M. (Moscow, ID); Smart, Neil G. (Moscow, ID); Phelps, Cindy (Moscow, ID)

1997-01-01T23:59:59.000Z

256

Extracting metals directly from metal oxides  

DOE Patents (OSTI)

A method of extracting metals directly from metal oxides by exposing the oxide to a supercritical fluid solvent containing a chelating agent is described. Preferably, the metal is an actinide or a lanthanide. More preferably, the metal is uranium, thorium or plutonium. The chelating agent forms chelates that are soluble in the supercritical fluid, thereby allowing direct removal of the metal from the metal oxide. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of {beta}-diketones, halogenated {beta}-diketones, phosphinic acids, halogenated phosphinic acids, carboxylic acids, halogenated carboxylic acids, and mixtures thereof. In especially preferred embodiments, at least one of the chelating agents is fluorinated. The method provides an environmentally benign process for removing metals from metal oxides without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the metal recovered, to provide an economic, efficient process. 4 figs.

Wai, C.M.; Smart, N.G.; Phelps, C.

1997-02-25T23:59:59.000Z

257

Demand Response Valuation Frameworks Paper  

Science Conference Proceedings (OSTI)

While there is general agreement that demand response (DR) is a valued component in a utility resource plan, there is a lack of consensus regarding how to value DR. Establishing the value of DR is a prerequisite to determining how much and what types of DR should be implemented, to which customers DR should be targeted, and a key determinant that drives the development of economically viable DR consumer technology. Most approaches for quantifying the value of DR focus on changes in utility system revenue requirements based on resource plans with and without DR. This ''utility centric'' approach does not assign any value to DR impacts that lower energy and capacity prices, improve reliability, lower system and network operating costs, produce better air quality, and provide improved customer choice and control. Proper valuation of these benefits requires a different basis for monetization. The review concludes that no single methodology today adequately captures the wide range of benefits and value potentially attributed to DR. To provide a more comprehensive valuation approach, current methods such as the Standard Practice Method (SPM) will most likely have to be supplemented with one or more alternative benefit-valuation approaches. This report provides an updated perspective on the DR valuation framework. It includes an introduction and four chapters that address the key elements of demand response valuation, a comprehensive literature review, and specific research recommendations.

Heffner, Grayson

2009-02-01T23:59:59.000Z

258

From patterns to frameworks to parallel programs  

Science Conference Proceedings (OSTI)

Object-oriented programming, design patterns, and frameworks are abstraction techniques that have been used to reduce the complexity of sequential programming. This paper describes our approach of applying these three techniques to the more difficult ... Keywords: design patterns, object-oriented frameworks, parallel programming systems

S. MacDonald; J. Anvik; S. Bromling; J. Schaeffer; D. Szafron; K. Tan

2002-12-01T23:59:59.000Z

259

Framework Oriented Approach to Eco-Tourism  

Science Conference Proceedings (OSTI)

This paper discusses an approach for eco-tourism. The paper also addresses the cost-benefit analysis of different parameters which can help in designing a framework. The principles of eco tourism emphasizes on the win-win situation for both the Commercial ... Keywords: Cost-Benefit Analysis, Eco-Tourism, Framework for Eco-Tourism, Green Technology, Stakeholders Issues

Sanjay Mohapatra, Tripti Naswa

2013-01-01T23:59:59.000Z

260

Reference framework for E-participation projects  

Science Conference Proceedings (OSTI)

Accommodating the various requirements from distinct perspectives in e-participation calls for a holistic engineering approach for e-participation systems analysis and design. This paper presents research results towards a reference framework for e-participation ... Keywords: E-participation, reference framework, reference model

Sabrina Scherer; Maria A. Wimmer

2011-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Control and Navigation Framework for Quadrotor Helicopters  

Science Conference Proceedings (OSTI)

This paper presents the development of a nonlinear quadrotor simulation framework together with a nonlinear controller. The quadrotor stabilization and navigation problems are tackled using a nested loops control architecture. A nonlinear Backstepping ... Keywords: Backstepping, Gazebo, Navigation, Nonlinear control, Open dynamics engine, Quadrotor, Simulation framework

Amr Nagaty; Sajad Saeedi; Carl Thibault; Mae Seto; Howard Li

2013-04-01T23:59:59.000Z

262

A Risk Minimization Framework for Information Retrieval  

E-Print Network (OSTI)

A Risk Minimization Framework for Information Retrieval ChengXiang Zhai a John Lafferty b Carnegie Mellon University Abstract This paper presents a probabilistic information retrieval framework of decades of research in information retrieval, many different information retrieval models have been

Lafferty, John

263

A Risk Minimization Framework for Information Retrieval  

E-Print Network (OSTI)

A Risk Minimization Framework for Information Retrieval ChengXiang Zhai a John Lafferty b a University Abstract This paper presents a probabilistic information retrieval framework in which in information retrieval, many different information retrieval models have been proposed and studied. While

Lafferty, John

264

Cellular Energy Efficiency Evaluation Framework (Invited Paper)  

E-Print Network (OSTI)

Cellular Energy Efficiency Evaluation Framework (Invited Paper) Gunther Auer, Vito Giannini, Istv, the power consumption of the entire system needs to be captured and an appropriate energy efficiency evaluation frameworks are discussed, such that the energy efficiency of the entire network comprising

Stevenson, Paul

265

Computational Design of Metal Ion Sequestering Agents  

SciTech Connect

Organic ligands that exhibit a high degree of metal ion recognition are essential precursors for developing separation processes and sensors for metal ions. Since the beginning of the nuclear era, much research has focused on discovering ligands that target specific radionuclides. Members of the Group 1A and 2A cations (e.g., Cs, Sr, Ra) and the f-block metals (actinides and lanthanides) are of primary concern to DOE. Although there has been some success in identifying ligand architectures that exhibit a degree of metal ion recognition, the ability to control binding affinity and selectivity remains a significant challenge. The traditional approach for discovering such ligands has involved lengthy programs of organic synthesis and testing that, in the absence of reliable methods for screening compounds before synthesis, have resulted in much wasted research effort.

Hay, Benjamin P.; Rapko, Brian M.

2005-06-15T23:59:59.000Z

266

Computational Design of Metal Ion Sequestering Agents  

SciTech Connect

Organic ligands that exhibit a high degree of metal ion recognition are essential precursors for developing separation processes and sensors for metal ions. Since the beginning of the nuclear era, much research has focused on discovering ligands that target specific radionuclides. Members of the Group 1A and 2A cations (e.g., Cs, Sr, Ra) and the f-block metals (actinides and lanthanides) are of primary concern to DOE. Although there has been some success in identifying ligand architectures that exhibit a degree of metal ion recognition, the ability to control binding affinity and selectivity remains a significant challenge. The traditional approach for discovering such ligands has involved lengthy programs of organic synthesis and testing that, in the absence of reliable methods for screening compounds before synthesis, have resulted in much wasted research effort.

Hay, Benjamin P.; Rapko, Brian M.

2006-06-01T23:59:59.000Z

267

A Calcium Coordination Framework Having Permanent Porosity and High CO2/N2 Selectivity  

SciTech Connect

A thermally stable, microporous calcium coordination network shows a reversible 5.75 wt % CO{sub 2} uptake at 273 K and 1 atm pressure, with an enthalpy of interaction of {approx}31 kJ/mol and a CO{sub 2}/N{sub 2} selectivity over 45 under ideal flue gas conditions. The absence of open metal sites in the activated material suggests a different mechanism for selectivity and high interaction energy compared to those for frameworks with open metal sites.

Banerjee D.; Parise J.; Zhang, Z.; Plonka, A.M.; Li, J.

2012-03-15T23:59:59.000Z

268

CASTING SLIPS FOR FABRICATION OF REFRACTORY METAL WARE  

DOE Patents (OSTI)

A composition is given for slip casting tungsten metal. The composition consists essentially of tungsten metal with an average particle size of 0.9 micron, an organic vehicle such as methyl chloroform, o-xylene, n-butyl acetate, isobutyl acetate, and 1, 1, 2, 2-tetrachlorethane, and a suspending agent such as ethyl cellulose, with the approximate ratio of said vehicle to the tungsten metal being 12 cc of a solution containing from 5 to about 20 grams of said ethyl cellulose in 400 cc of said organic vehicle per 100 grams of metal. (AEC)

Stoddard, S.D.; Nuckolls, D.E.; Cowan, R.E.

1962-09-01T23:59:59.000Z

269

Metallic Glass II  

Science Conference Proceedings (OSTI)

Aug 8, 2013 ... Application of Metallic Glass for High Performance Si Solar Cell: ... of the metallic glasses during heating is dependent on the thermal stability of ...

270

Light Metals 2010  

Science Conference Proceedings (OSTI)

Feb 1, 2010 ... Softcover book: Light Metals 2008 Volume 2: Aluminum Reduction. Hardcover book and CD-ROM: Light Metals 2009 ...

271

Bulk Metallic Glasses IX  

Science Conference Proceedings (OSTI)

... of elements to form metallic-glass alloys] have resulted in the required cooling rate ... Bauschinger Effect in Metallic Glass Nanowires under Cyclic Loading.

272

Bulk Metallic Glasses XI  

Science Conference Proceedings (OSTI)

Jul 15, 2013 ... A Bulk Metallic Glass with Record-breaking Damage Tolerance ... Oxidation on the Surface Characteristics of Zr-based Bulk Metallic Glasses.

273

Principal Metals Online  

Science Conference Proceedings (OSTI)

Topic Title: WEB RESOURCE: Principal Metals Online Topic Summary: Principal Metals inventory database. Created On: 2/9/2007 5:41 AM, Topic View:.

274

Refractory Metals Committee  

Science Conference Proceedings (OSTI)

The Refractory Metals Committee is part of the Structural Materials Division. Our Mission: Includes all technical aspects of the science of refractory metals and ...

275

CDKN-Ghana-Support for Future National Climate Change Policy Framework |  

Open Energy Info (EERE)

Support for Future National Climate Change Policy Framework Support for Future National Climate Change Policy Framework Jump to: navigation, search Name CDKN-Ghana-Support for Future National Climate Change Policy Framework Agency/Company /Organization Climate and Development Knowledge Network (CDKN), United Kingdom Department for International Development Partner Energy Research Centre of the Netherlands (ECN), University of Ghana Sector Climate, Energy, Land Topics Background analysis, Low emission development planning, Pathways analysis Website http://cdkn.org/project/assist Program Start 2010 Program End 2011 Country Ghana UN Region Western Africa References CDKN-Ghana-Support for Future National Climate Change Policy Framework[1] Policy brief[2] "CDKN responded to a request by the Government of Ghana to help develop a

276

Electronic, Thermal and Structural Properties of Graphene Oxide Frameworks  

Science Conference Proceedings (OSTI)

We report a theoretical study of the electronic, thermal, and structural properties of a series of graphene oxide frameworks (GOFs) using first-principles calculations based on density functional theory. The molecular structure of GOFs is systematically studied by varying the nature and concentration of linear boronic acid pillars and the thermal stability is assessed using ab initio molecular dynamics. The results demonstrate that GOFs are thermally stable up to 550 K and that electronic properties, such as their band gap, can be modified controllably by an appropriate choice of pillaring unit and pillar concentration. The tunability of the electronic structure using non-chemical means, e.g., mechanical strain, is also quantified. Overall, this class of materials is predicted to offer highly tunable materials electronic properties ranging from metallic to semiconducting.

Zhu, Pan [Rensselaer Polytechnic Institute (RPI); Sumpter, Bobby G [ORNL; Meunier, V. [Rensselaer Polytechnic Institute (RPI)

2013-01-01T23:59:59.000Z

277

Materials Built from Ultra-Light Elements. Final Scientific/Technical Report  

DOE Green Energy (OSTI)

applications including gas storage and separation and catalysis. These include lithium-based metal-organic frameworks, magnesium-based metal-organic frameworks, and high gas uptake in porous frameworks with high density of open donor sites.

Feng, Pingyun

2014-01-10T23:59:59.000Z

278

Incorporation of noble metals into aerogels  

DOE Patents (OSTI)

Aerogels or xerogels containing atomically dispersed noble metals for applications such as environmental remediation are disclosed. New noble metal precursors, such as Pt--Si or Pd(Si--P){sub 2}, have been created to bridge the incompatibility between noble metals and oxygen, followed by their incorporation into the aerogel or xerogel through sol-gel chemistry and processing. Applications include oxidation of hydrocarbons and reduction of nitrogen oxide species, complete oxidation of volatile organic carbon species, oxidative membranes for photocatalysis and partial oxidation for synthetic applications.

Hair, L.M.; Sanner, R.D.; Coronado, P.R.

1998-12-22T23:59:59.000Z

279

Incorporation of noble metals into aerogels  

DOE Patents (OSTI)

Aerogels or xerogels containing atomically dispersed noble metals for applications such environmental remediation. New noble metal precursors, such as Pt--Si or Pd(Si--P).sub.2, have been created to bridge the incompatibility between noble metals and oxygen, followed by their incorporation into the aerogel or xerogel through sol-gel chemistry and processing. Applications include oxidation of hydrocarbons and reduction of nitrogen oxide species, complete oxidation of volatile organic carbon species, oxidative membranes for photocatalysis and partial oxidation for synthetic applications.

Hair, Lucy M. (Livermore, CA); Sanner, Robert D. (Livermore, CA); Coronado, Paul R. (Livermore, CA)

1998-01-01T23:59:59.000Z

280

Trending: Metal Oxo Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Trending: Metal Oxo Bonds Trending: Metal Oxo Bonds Trending: Metal Oxo Bonds Print Wednesday, 29 May 2013 00:00 Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide variety of important emergent technologies, including industrial catalysis, biomimetic transformations, and artificial photosynthesis. To address this problem, a research team from four national laboratories, three Department of Energy synchrotron user facilities, and the University of Washington has applied spectroscopic and computational analyses to a number of metal oxides, quantifying trends in metal oxo bonding for groups of metals across the periodic table.

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Towards an Automatic Metadata Management Framework for Smart Oil Charalampos Chelmis1  

E-Print Network (OSTI)

of the oil exploration process in the oil industry. Our system is capable of annotating models and images. Introduction Oil and gas organizations are in continuous pressure to investigate and employ innovativeTowards an Automatic Metadata Management Framework for Smart Oil Fields Charalampos Chelmis1 , Jing

Prasanna, Viktor K.

282

IDebug: An Advanced Debugging Framework for Java  

E-Print Network (OSTI)

IDebug, the Infospheres debugging framework, is an advanced debugging framework for Java. This framework provides the standard core debugging and specification constructs such as assertions, debug levels and categories, stack traces, and specialized exceptions. Debugging functionality can be fine-tuned to a per-thread and/or a per-class basis, debugging contexts can be stored to and recovered from persistent storage, and several aspects of the debugging run-time are configurable at the meta-level. Additionally, the framework is designed for extensibility. Planned improvements include support for debugging distributed object systems via currying call stacks across virtual machine contexts and debug information logging with a variety of networking media including unicast, multicast, RMI, distributed events, and JavaSpaces. Finally, we are adding support for debugging mobile agent systems by providing mobile debug logs. 1 Introduction Programming technologies have evolved greatly over th...

Joseph R. Kiniry

1998-01-01T23:59:59.000Z

283

A proposed open cognitive architecture framework  

Science Conference Proceedings (OSTI)

This paper describes a proposed general-purpose cognitive architecture known as the Open Cognitive Architecture Framework (OpenCAF) capable of representing complex intelligent behavior for a variety of applications. This new cognitive architecture ...

Jeffrey S. Steinman; Craig N. Lammers; Maria E. Valinski

2009-12-01T23:59:59.000Z

284

Aranea: web framework construction and integration kit  

Science Conference Proceedings (OSTI)

Currently there exist dozens of web controller frameworks that are incompatible, but at the same time have large portions of overlapping functionality that is implemented over and over again. Web programmers are facing limitations on code reuse, application ...

Oleg Mürk; Jevgeni Kabanov

2006-08-01T23:59:59.000Z

285

A framework for technology forecasting and visualization  

E-Print Network (OSTI)

This paper presents a novel framework for supporting the development of well-informed research policies and plans. The proposed methodology is based on the use of bibliometrics; i.e., analysis is conducted using information ...

Woon, Wei Lee

286

A Framework for Technology Forecasting and Visualization  

E-Print Network (OSTI)

This paper presents a novel framework for supporting the development of well-informed research policies and plans. The proposed methodology is based on the use of bibliometrics; i.e., analysis is conducted using information ...

Woon, Wei Lee

287

A Bayesian Framework for Multimodel Regression  

Science Conference Proceedings (OSTI)

This paper presents a framework based on Bayesian regression and constrained least squares methods for incorporating prior beliefs in a linear regression problem. Prior beliefs are essential in regression theory when the number of predictors is ...

Timothy DelSole

2007-06-01T23:59:59.000Z

288

Netgauge: a network performance measurement framework  

Science Conference Proceedings (OSTI)

This paper introduces Netgauge, an extensible open-source framework for implementing network benchmarks. The structure of Netgauge abstracts and explicitly separates communication patterns from communication modules. As a result of this separation of ...

Torsten Hoefler; Torsten Mehlan; Andrew Lumsdaine; Wolfgang Rehm

2007-09-01T23:59:59.000Z

289

A hierarchical systems knowledge representation framework  

E-Print Network (OSTI)

We present the design and implementation of a framework for storing and analysing knowledge about engineering systems. The hierarchical entity-relation-attribute model is useful for large data sets, in which it can abstract ...

Sylvester, Igor Andrade

2007-01-01T23:59:59.000Z

290

Flexible Residential Smart Grid Simulation Framework  

E-Print Network (OSTI)

Different scheduling and coordination algorithms controlling household appliances’ operations can potentially lead to energy consumption reduction and/or load balancing in conjunction with different electricity pricing methods used in smart grid programs. In order to easily implement different algorithms and evaluate their efficiency against other ideas, a flexible simulation framework is desirable in both research and business fields. However, such a platform is currently lacking or underdeveloped. In this thesis, we provide a simulation framework to focus on demand side residential energy consumption coordination in response to different pricing methods. This simulation framework, equipped with an appliance consumption library using realistic values, aims to closely represent the average usage of different types of appliances. The simulation results of traditional usage yield close matching values compared to surveyed real life consumption records. Several sample coordination algorithms, pricing schemes, and communication scenarios are also implemented to illustrate the use of the simulation framework.

Wang Xiang; Thomas Kunz; Marc St-hilaire; Wang Xiang

2013-01-01T23:59:59.000Z

291

A flexible design framework for autonomous mowing  

E-Print Network (OSTI)

This work outlines the creation of a flexible design framework for autonomous mowing to meet changing customer needs and functionality across a spectrum of applications from residential areas to sport complexes. The thesis ...

Kraft, Justin (Justin A.)

2011-01-01T23:59:59.000Z

292

Precious Metals Conversion Information  

Science Conference Proceedings (OSTI)

Precious Metals Conversion Information. The Office of Weights and Measures (OWM) has prepared a Conversion Factors ...

2012-11-21T23:59:59.000Z

293

Corrosion of valve metals  

DOE Green Energy (OSTI)

A general survey related to the corrosion of valve metals or film-forming metals. The way these metals corrode with some general examples is described. Valve metals form relatively perfect oxide films with little breakdown or leakage when anodized. (FS)

Draley, J.E.

1976-01-01T23:59:59.000Z

294

METAL PRODUCTION AND CASTING  

DOE Patents (OSTI)

This patent covers a method and apparatus for collecting the molten metal produced by high temperature metal salt reduction. It consists essentially of subjecting the reaction vessel to centrifugal force in order to force the liberatcd molten metal into a coherent molten mass, and allowing it to solidify there. The apparatus is particularly suitable for use with small quantities of rare metals.

Magel, T.T.

1958-03-01T23:59:59.000Z

295

Ceramic to metal seal  

DOE Patents (OSTI)

Providing a high strength, hermetic ceramic to metal seal by essentially heating a wire-like metal gasket and a ceramic member, which have been chemically cleaned, while simultaneously deforming from about 50 to 95 percent the metal gasket against the ceramic member at a temperature of about 30 to 75 percent of the melting temperature of the metal gasket.

Snow, Gary S. (Albuquerque, NM); Wilcox, Paul D. (Albuquerque, NM)

1976-01-01T23:59:59.000Z

296

Shiva: An astronomical data analysis framework  

SciTech Connect

A key online and off-line software component of the Sloan Digital Sky Survey (SDSS) is Shiva. Shiva provides a readily extendible framework upon which the SDSS data reduction pipeline software is built. In this paper we present an introduction to the Shiva data analysis framework. We briefly discuss the features and the inherent prototyping and rapid development capabilities that make Shiva an integral part in the on-going development of SDSS software.

Sergey, G.; Berman, E.; Huang, C.H.; Kent, S.; Newberg, H; Nicinski, T.; Petravick, D; Stoughton, C. [Fermi National Accelerator Lab., Batavia, IL (United States); Lupton, R. [Princeton Univ., NJ (United States). Dept. of Astronomy

1995-12-01T23:59:59.000Z

297

Trending: Metal Oxo Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Trending: Metal Oxo Bonds Print Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide variety of important emergent technologies, including industrial catalysis, biomimetic transformations, and artificial photosynthesis. To address this problem, a research team from four national laboratories, three Department of Energy synchrotron user facilities, and the University of Washington has applied spectroscopic and computational analyses to a number of metal oxides, quantifying trends in metal oxo bonding for groups of metals across the periodic table.

298

Trending: Metal Oxo Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Trending: Metal Oxo Bonds Print Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide variety of important emergent technologies, including industrial catalysis, biomimetic transformations, and artificial photosynthesis. To address this problem, a research team from four national laboratories, three Department of Energy synchrotron user facilities, and the University of Washington has applied spectroscopic and computational analyses to a number of metal oxides, quantifying trends in metal oxo bonding for groups of metals across the periodic table.

299

Trending: Metal Oxo Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Trending: Metal Oxo Bonds Print Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide variety of important emergent technologies, including industrial catalysis, biomimetic transformations, and artificial photosynthesis. To address this problem, a research team from four national laboratories, three Department of Energy synchrotron user facilities, and the University of Washington has applied spectroscopic and computational analyses to a number of metal oxides, quantifying trends in metal oxo bonding for groups of metals across the periodic table.

300

Trending: Metal Oxo Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Trending: Metal Oxo Bonds Print Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide variety of important emergent technologies, including industrial catalysis, biomimetic transformations, and artificial photosynthesis. To address this problem, a research team from four national laboratories, three Department of Energy synchrotron user facilities, and the University of Washington has applied spectroscopic and computational analyses to a number of metal oxides, quantifying trends in metal oxo bonding for groups of metals across the periodic table.

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Solution synthesis of mixed-metal chalcogenide nanoparticles and spray deposition of precursor films  

DOE Patents (OSTI)

A colloidal suspension comprising metal chalcogenide nanoparticles and a volatile capping agent. The colloidal suspension is made by reacting a metal salt with a chalcogenide salt in an organic solvent to precipitate a metal chalcogenide, recovering the metal chalcogenide, and admixing the metal chalcogenide with a volatile capping agent. The colloidal suspension is spray deposited onto a substrate to produce a semiconductor precursor film which is substantially free of impurities.

Schulz, Douglas L. (Denver, CO); Curtis, Calvin J. (Lakewood, CO); Ginley, David S. (Evergreen, CO)

2000-01-01T23:59:59.000Z

302

Final Report: Metal Perhydrides for Hydrogen Storage  

DOE Green Energy (OSTI)

Hydrogen is a promising energy source for the future economy due to its environmental friendliness. One of the important obstacles for the utilization of hydrogen as a fuel source for applications such as fuel cells is the storage of hydrogen. In the infrastructure of the expected hydrogen economy, hydrogen storage is one of the key enabling technologies. Although hydrogen possesses the highest gravimetric energy content (142 KJ/g) of all fuels, its volumetric energy density (8 MJ/L) is very low. It is desired to increase the volumetric energy density of hydrogen in a system to satisfy various applications. Research on hydrogen storage has been pursed for many years. Various storage technologies, including liquefaction, compression, metal hydride, chemical hydride, and adsorption, have been examined. Liquefaction and high pressure compression are not desired due to concerns related to complicated devices, high energy cost and safety. Metal hydrides and chemical hydrides have high gravimetric and volumetric energy densities but encounter issues because high temperature is required for the release of hydrogen, due to the strong bonding of hydrogen in the compounds. Reversibility of hydrogen loading and unloading is another concern. Adsorption of hydrogen on high surface area sorbents such as activated carbon and organic metal frameworks does not have the reversibility problem. But on the other hand, the weak force (primarily the van der Waals force) between hydrogen and the sorbent yields a very small amount of adsorption capacity at ambient temperature. Significant storage capacity can only be achieved at low temperatures such as 77K. The use of liquid nitrogen in a hydrogen storage system is not practical. Perhydrides are proposed as novel hydrogen storage materials that may overcome barriers slowing advances to a hydrogen fuel economy. In conventional hydrides, e.g. metal hydrides, the number of hydrogen atoms equals the total valence of the metal ions. One LiH molecule contains one hydrogen atom because the valence of a Li ion is +1. One MgH2 molecule contains two hydrogen atoms because the valence of a Mg ion is +2. In metal perhydrides, a molecule could contain more hydrogen atoms than expected based on the metal valance, i.e. LiH1+n and MgH2+n (n is equal to or greater than 1). When n is sufficiently high, there will be plenty of hydrogen storage capacity to meet future requirements. The existence of hydrogen clusters, Hn+ (n = 5, 7, 9, 11, 13, 15) and transition metal ion-hydrogen clusters, M+(H2)n (n = 1-6), such as Sc(H2)n+, Co(H2)n+, etc., have assisted the development of this concept. Clusters are not stable species. However, their existence stimulates our approach on using electric charges to enhance the hydrogen adsorption in a hydrogen storage system in this study. The experimental and modeling work to verify it are reported here. Experimental work included the generation of cold hydrogen plasma through a microwave approach, synthesis of sorbent materials, design and construction of lab devices, and the determination of hydrogen adsorption capacities on various sorbent materials under various electric field potentials and various temperatures. The results consistently show that electric potential enhances the adsorption of hydrogen on sorbents. NiO, MgO, activated carbon, MOF, and MOF and platinum coated activated carbon are some of the materials studied. Enhancements up to a few hundred percents have been found. In general, the enhancement increases with the electrical potential, the pressure applied, and the temperature lowered. Theoretical modeling of the hydrogen adsorption on the sorbents under the electric potential has been investigated with the density functional theory (DFT) approach. It was found that the interaction energy between hydrogen and sorbent is increased remarkably when an electric field is applied. This increase of binding energy offers a potential solution for DOE when looking for a compromise between chemisorption and physisorption for hydrogen storage. Bonding of chemisorption is too

Hwang, J-Y.; Shi, S.; Hackney, S.; Swenson, D.; Hu, Y.

2011-07-26T23:59:59.000Z

303

Organic solvent topical report  

Science Conference Proceedings (OSTI)

This report provides the basis for closing the organic solvent safety issue. Sufficient information is presented to conclude that risk posed by an organic solvent fire is within risk evaluation guidelines. This report updates information contained in Analysis of Consequences of Postulated Solvent Fires in Hanford Site Waste Tanks. WHC-SD-WM-CN-032. Rev. 0A (Cowley et al. 1996). However, this document will not replace Cowley et al (1996) as the primary reference for the Basis for Interim Operation (BIO) until the recently submitted BIO amendment (Hanson 1999) is approved by the US Department of Energy. This conclusion depends on the use of controls for preventing vehicle fuel fires and for limiting the use of flame cutting in areas where hot metal can fall on the waste surface.The required controls are given in the Tank Waste Remediation System Technical Safety Requirements (Noorani 1997b). This is a significant change from the conclusions presented in Revision 0 of this report. Revision 0 of this calcnote concluded that some organic solvent fire scenarios exceeded risk evaluation guidelines, even with controls imposed.

COWLEY, W.L.

1999-05-13T23:59:59.000Z

304

Framework for Certification of Fish Propagation, Protection and Monitoring Facilities. Final Report.  

DOE Green Energy (OSTI)

A conceptual framework for certification of fish production and monitoring facilities including software templates to expedite implementation of the framework are presented. The framework is based on well established and widely utilized project management techniques. The implementation templates are overlays for Microsoft Professional Office software products: Excel, Word, and Project. Use of the software templates requires Microsoft Professional Office. The certification framework integrates two classical project management processes with a third process for facility certification. These processes are: (1) organization and definition of the project, (2) acquisition and organization of project documentation, and (3) facility certification. The certification process consists of systematic review of the production processes and the characteristics of the produced product. The criteria for certification review are the plans and specifications for the products and production processes that guided development of the facility. The facility is certified when the production processes are operating as designed and the product produced meets specifications. Within this framework, certification is a performance based process, not dissimilar from that practiced in many professions and required for many process, or a product meets professional/industry standards of performance. In the case of fish production facilities, the certifying authority may be diffuse, consisting of many entities acting through a process such as NEPA. A cornerstone of certification is accountability, over the long term, for the operation and products of a facility. This is particularly important for fish production facilities where the overall goal of the facility may require decades to accomplish.

Carlson, Thomas J.; Costello, Ronald J.

1997-06-01T23:59:59.000Z

305

International Framework for Nuclear Energy Cooperation to Hold...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Framework for Nuclear Energy Cooperation to Hold Ministerial-Level Meeting Sept. 29 in Warsaw, Poland International Framework for Nuclear Energy Cooperation to Hold...

306

A Framework for Comparative Assessments of Energy Efficiency...  

NLE Websites -- All DOE Office Websites (Extended Search)

A Framework for Comparative Assessments of Energy Efficiency Policy Measures Title A Framework for Comparative Assessments of Energy Efficiency Policy Measures Publication Type...

307

A Methodological Framework for Comparative Assessments of Equipment...  

NLE Websites -- All DOE Office Websites (Extended Search)

Methodological Framework for Comparative Assessments of Equipment Energy Efficiency Policy Measures Title A Methodological Framework for Comparative Assessments of Equipment Energy...

308

Deputy Secretary Poneman to Attend International Framework for...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

to Attend International Framework for Nuclear Energy Cooperation Meeting in Jordan Deputy Secretary Poneman to Attend International Framework for Nuclear Energy Cooperation Meeting...

309

A Statistical Pattern Analysis Framework for Rooftop Unit Diagnostics  

NLE Websites -- All DOE Office Websites (Extended Search)

A Statistical Pattern Analysis Framework for Rooftop Unit Diagnostics Title A Statistical Pattern Analysis Framework for Rooftop Unit Diagnostics Publication Type Journal Article...

310

Online Monitoring Technical Basis and Analysis Framework for...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Online Monitoring Technical Basis and Analysis Framework for Emergency Diesel Generators-Interim Report for FY 2013 Online Monitoring Technical Basis and Analysis Framework for...

311

Security Framework for Control System Data Classification and...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Framework for Control System Data Classification and Protection Security Framework for Control System Data Classification and Protection This document presents a data...

312

3rd Cybersecurity Framework Workshop - July 10-12 2013 ...  

Science Conference Proceedings (OSTI)

... Cybersecurity Framework, July 1, 2013 The purpose of this document is to define the overall Framework and provide guidance on its usage. ...

2013-07-19T23:59:59.000Z

313

A Systems Framework for Assessing Plumbing Products-Related Water...  

NLE Websites -- All DOE Office Websites (Extended Search)

A Systems Framework for Assessing Plumbing Products-Related Water Conservation Title A Systems Framework for Assessing Plumbing Products-Related Water Conservation Publication Type...

314

Recovery Act: Smart Grid Interoperability Standards and Framework...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Act: Smart Grid Interoperability Standards and Framework Recovery Act: Smart Grid Interoperability Standards and Framework Congressional Testimony Recovery Act Recovery Act...

315

Dynamic modelling of metals - Time scales and target loads  

Science Conference Proceedings (OSTI)

Over the past decade steady-state methods have been developed to assess critical loads of metals avoiding long-term risks in view of food quality and eco-toxicological effects on organisms in soils and surface waters. However, dynamic models are needed ... Keywords: Critical loads, Delay times, Dynamic modelling, Metals, Scenario analysis, Target loads

Maximilian Posch; Wim de Vries

2009-01-01T23:59:59.000Z

316

Method for extracting copper, silver and related metals  

DOE Patents (OSTI)

A process for selectively extracting precious metals such as silver and gold concurrent with copper extraction from aqueous solutions containing the same. The process utilizes tetrathiamacrocycles and high molecular weight organic acids that exhibit a synergistic relationship when complexing with certain metal ions thereby removing them from ore leach solutions.

Moyer, B.A.; McDowell, W.J.

1987-10-23T23:59:59.000Z

317

Molecular structures on crystalline metallic surfaces - From STM images to molecular electronics  

Science Conference Proceedings (OSTI)

We present results from scanning tunneling microscopy obtained for organic molecules - coronene and different phthalocyanine derivatives - adsorbed on crystalline metallic substrates under UHV conditions. Molecular structures resolved till to submolecular ... Keywords: Molecular electronics, Nanoscale structures, Organic molecules, Scanning tunneling microscopy

M. Hietschold; M. Lackinger; S. Griessl; W. M. Heckl; T. G. Gopakumar; G. W. Flynn

2005-12-01T23:59:59.000Z

318

A Low Temperature Fully Lithographic Process For Metal–Oxide Field-Effect Transistors  

E-Print Network (OSTI)

We report a low temperature ( ~ 100à °C) lithographic method for fabricating hybrid metal oxide/organic field-effect transistors (FETs) that combine a zinc-indium-oxide (ZIO) semiconductor channel and organic, parylene, ...

Sodini, Charles G.

319

Metal-Air Batteries  

Science Conference Proceedings (OSTI)

Metal-air batteries have much higher specific energies than most currently available primary and rechargeable batteries. Recent advances in electrode materials and electrolytes, as well as new designs on metal-air batteries, have attracted intensive effort in recent years, especially in the development of lithium-air batteries. The general principle in metal-air batteries will be reviewed in this chapter. The materials, preparation methods, and performances of metal-air batteries will be discussed. Two main metal-air batteries, Zn-air and Li-air batteries will be discussed in detail. Other type of metal-air batteries will also be described.

Zhang, Jiguang; Bruce, Peter G.; Zhang, Gregory

2011-08-01T23:59:59.000Z

320

Alkali metal nitrate purification  

DOE Patents (OSTI)

A process is disclosed for removing contaminants from impure alkali metal nitrates containing them. The process comprises heating the impure alkali metal nitrates in solution form or molten form at a temperature and for a time sufficient to effect precipitation of solid impurities and separating the solid impurities from the resulting purified alkali metal nitrates. The resulting purified alkali metal nitrates in solution form may be heated to evaporate water therefrom to produce purified molten alkali metal nitrates suitable for use as a heat transfer medium. If desired, the purified molten form may be granulated and cooled to form discrete solid particles of purified alkali metal nitrates.

Fiorucci, Louis C. (Hamden, CT); Morgan, Michael J. (Guilford, CT)

1986-02-04T23:59:59.000Z

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

U.S. Nuclear Regulatory Commission Extremely Low Probability of Rupture pilot study : xLPR framework model user's guide.  

Science Conference Proceedings (OSTI)

For the U.S. Nuclear Regulatory Commission (NRC) Extremely Low Probability of Rupture (xLPR) pilot study, Sandia National Laboratories (SNL) was tasked to develop and evaluate a probabilistic framework using a commercial software package for Version 1.0 of the xLPR Code. Version 1.0 of the xLPR code is focused assessing the probability of rupture due to primary water stress corrosion cracking in dissimilar metal welds in pressurizer surge nozzles. Future versions of this framework will expand the capabilities to other cracking mechanisms, and other piping systems for both pressurized water reactors and boiling water reactors. The goal of the pilot study project is to plan the xLPR framework transition from Version 1.0 to Version 2.0; hence the initial Version 1.0 framework and code development will be used to define the requirements for Version 2.0. The software documented in this report has been developed and tested solely for this purpose. This framework and demonstration problem will be used to evaluate the commercial software's capabilities and applicability for use in creating the final version of the xLPR framework. This report details the design, system requirements, and the steps necessary to use the commercial-code based xLPR framework developed by SNL.

Kalinich, Donald A.; Sallaberry, Cedric M.; Mattie, Patrick D.

2010-12-01T23:59:59.000Z

322

A project management focused framework for assuring quality work processes  

Science Conference Proceedings (OSTI)

Federal Manufacturing & Technologies/New Mexico (FM&T/NM) of AlliedSignal is an organization of approximately 300 associates providing operations support, engineering, and other technical services for DOE, New Mexico`s National Laboratories, etc. Work performed is primarily project-oriented and ranges from executing a major long-term contract for retrofitting and maintaining a large fleet of escort vehicles to creating a single, small, prototype electronic device for measuring radiation in a unique environment. FM&T/NM is functionally organized and operates in a classic matrix format with functional departments providing personnel with technical expertise, necessary physical resources, and administrative support to several project-based groups. Like most matrix-based organizations that provide support to diverse customers, FM&T/NM has encountered problems that occur when a group of project managers is expected to work together in using and scheduling a shared set of limited resources for the good of the organization as a whole. The framework for managing projects that we present focuses on developing, understanding, and managing the relationships between the functional organization structure, the system of work processes, and the management of projects. FM&T/NM retains its functional structure which primarily assigns personnel to work processes. The evolving role of the process leader focuses primarily on designing, managing, and improving the process, and the interactions among the subprocesses. The project manager is responsible for (1) translating customer requirements into product specifications, (2) determining the sequence of activities needed to meet project goals, (3) scheduling the required work processes, (4) monitoring project progress, (5) providing liaison between the customer and process leaders, and (6) having the desired product and/or service delivered to a satisfied customer in a timely manner.

Gamsby, S.O.; Mize, J.D. [Allied Signal, Inc., Albuquerque, NM (United States). Federal Mfg. and Technologies; Reid, R.A. [New Mexico Univ., Albuquerque, NM (United States)

1996-10-01T23:59:59.000Z

323

A Probabilistic Framework for Discriminative Dictionary Learning  

E-Print Network (OSTI)

In this paper, we address the problem of discriminative dictionary learning (DDL), where sparse linear representation and classification are combined in a probabilistic framework. As such, a single discriminative dictionary and linear binary classifiers are learned jointly. By encoding sparse representation and discriminative classification models in a MAP setting, we propose a general optimization framework that allows for a data-driven tradeoff between faithful representation and accurate classification. As opposed to previous work, our learning methodology is capable of incorporating a diverse family of classification cost functions (including those used in popular boosting methods), while avoiding the need for involved optimization techniques. We show that DDL can be solved by a sequence of updates that make use of well-known and well-studied sparse coding and dictionary learning algorithms from the literature. To validate our DDL framework, we apply it to digit classification and face recognition and tes...

Ghanem, Bernard

2011-01-01T23:59:59.000Z

324

Complete Security Framework for Wireless Sensor Networks  

E-Print Network (OSTI)

Security concern for a Sensor Networks and level of security desired may differ according to application specific needs where the sensor networks are deployed. Till now, most of the security solutions proposed for sensor networks are layer wise i.e a particular solution is applicable to single layer itself. So, to integrate them all is a new research challenge. In this paper we took up the challenge and have proposed an integrated comprehensive security framework that will provide security services for all services of sensor network. We have added one extra component i.e. Intelligent Security Agent (ISA) to assess level of security and cross layer interactions. This framework has many components like Intrusion Detection System, Trust Framework, Key Management scheme and Link layer communication protocol. We have also tested it on three different application scenarios in Castalia and Omnet++ simulator.

Sharma, Kalpana; Kuldeep,

2009-01-01T23:59:59.000Z

325

A Bayesian Framework for Combining Valuation Estimates  

E-Print Network (OSTI)

Obtaining more accurate equity value estimates is the starting point for stock selection, value-based indexing in a noisy market, and beating benchmark indices through tactical style rotation. Unfortunately, discounted cash flow, method of comparables, and fundamental analysis typically yield discrepant valuation estimates. Moreover, the valuation estimates typically disagree with market price. Can one form a superior valuation estimate by averaging over the individual estimates, including market price? This article suggests a Bayesian framework for combining two or more estimates into a superior valuation estimate. The framework justifies the common practice of averaging over several estimates to arrive at a final point estimate.

Kenton K. Yee

2007-07-24T23:59:59.000Z

326

A planning framework for transferring building energy technologies: Executive Summary  

Science Conference Proceedings (OSTI)

Accelerating the adoption of new and existing cost-effective technologies has significant potential to reduce the energy consumed in US buildings. This report summarizes some of the key results of an interlaboratory technology transfer planning effort in support of the US Department of Energy's Office of Building Technologies (the full report is published under SERI number TP-260-3729). A guiding assumption for planning was that OBT's R D program should forge linkages with existing programs whose goals involved enhancing energy efficiency in buildings. An ad hoc Technology Transfer Advisory Group reviewed the existing analysis and technology transfer program, brainstormed technology transfer approaches, interviewed DOE program managers, identified applicable research results, and developed a framework that management could use in deciding on the best investments of technology transfer resources. Representatives of 22 organizations were interviewed on their views of the potential for transferring energy efficiency technologies through active linking with OBT. The report describes in summary these programs and interview results; outlines OBT tools, technologies, and practices to be transferred; defines OBT audiences; identifies technology transfer functions and presents a framework devised using functions and audiences; presents some example technology transfer activities; and summarizes the Advisory Group's recommendations.

Farhar, B C; Brown, M A; Mohler, B L; Wilde, M; Abel, F H

1990-08-01T23:59:59.000Z

327

A planning framework for transferring building energy technologies  

SciTech Connect

Accelerating the adoption of new and existing cost-effective technologies has significant potential to reduce the energy consumed in US buildings. This report presents key results of an interlaboratory technology transfer planning effort in support of the US Department of Energy's Office of Building Technologies (OBT). A guiding assumption for planning was that OBT's R D program should forge linkages with existing programs whose goals involved enhancing energy efficiency in buildings. An ad hoc Technology Transfer Advisory Group reviewed the existing analysis and technology transfer program, brainstormed technology transfer approaches, interviewed DOE program managers, identified applicable research results, and developed a framework that management could use in deciding on the best investments of technology transfer resources. Representatives of 22 organizations were interviewed on their views of the potential for transferring energy efficiency technologies through active linking with OBT. The report describes these programs and interview results; outlines OBT tools, technologies, and practices to be transferred; defines OBT audiences; identifies technology transfer functions and presents a framework devised using functions and audiences; presents some 60 example technology transfer activities; and documents the Advisory Group's recommendations. 37 refs., 3 figs., 12 tabs.

Farhar, B C; Brown, M A; Mohler, B L; Wilde, M; Abel, F H

1990-07-01T23:59:59.000Z

328

A framework for evaluation of technology transfer programs. Volume 2  

Science Conference Proceedings (OSTI)

The objective of this volume is to describe a framework with which DOE can develop a program specific methodology to evaluate it`s technology transfer efforts. This approach could also be applied to an integrated private sector technology transfer organization. Several benefits will be realized from the application of this work. While the immediate effect will be to assist program managers in evaluating and improving program performance, the ultimate benefits will accrue to the producing industry, the states, and the nation in the form of sustained or increased domestic oil production. This benefit depends also, of course, on the effectiveness of the technology being transferred. The managers of the Technology Transfer program, and the larger federal oil and gas R&D programs, will be provided with a means to design and assess the effectiveness of program efforts as they are developed, tested and performed. The framework allows deficiencies in critical aspects of the program to be quickly identified, allowing for timely corrections and improvements. The actual process of developing the evaluation also gives the staff of the Oil R&D Program or Technology Transfer subprogram the opportunity to become oriented to the overall program goals. The structure and focus imposed by the evaluation paradigm will guide program staff in selecting activities which are consistent with achieving the goals of the overall R&D program.

Not Available

1993-07-01T23:59:59.000Z

329

Evaluation Framework and Tools for Distributed Energy Resources  

E-Print Network (OSTI)

Glossary Executive Summary Introduction Total Societal Impact Framework i iii v vii Effects of Distributed Energy

Gumerman, Etan Z.; Bharvirkar, Ranjit R.; LaCommare, Kristina Hamachi; Marnay, Chris

2003-01-01T23:59:59.000Z

330

Frameworks for model-driven development of web applications  

Science Conference Proceedings (OSTI)

This paper describes model driven development of dynamic web application using a few different frameworks. Those are the following open source Java frameworks: Modelibra, ModelibraWicket and Wicket. Modelibra is a domain model framework. ModelibraWicket ... Keywords: application development, framework, model, web component

Vensada Okanovi?; Dzenana Donko; Tadej Mateljan

2010-11-01T23:59:59.000Z

331

Bulk Metallic Glasses X  

Science Conference Proceedings (OSTI)

Jul 31, 2012 ... Aerospace and Spacecraft Applications for Bulk Metallic Glasses and Matrix Composites · Air Oxidation of a Binary Cu64.5Zr35.5 Bulk Metallic ...

332

Bulk Metallic Glasses VII  

Science Conference Proceedings (OSTI)

Sponsorship, The Minerals, Metals and Materials Society ... Air-Oxidation of a ( Zr55Cu30Al10Ni5)98Er2 Bulk Metallic Glass at 350-500oc · Anelastic ...

333

Metal phthalocyanine catalysts  

DOE Patents (OSTI)

As a new composition of matter, alkali metal or ammonium or tetraalkylammonium diazidoperfluorophthalocyanatoferrate. Other embodiments of the invention comprise compositions wherein the metal of the coordination complex is cobalt, manganese and chromium.

Ellis, Jr., Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA)

1994-01-01T23:59:59.000Z

334

Metal phthalocyanine catalysts  

DOE Patents (OSTI)

A new composition of matter is described which is an alkali metal or ammonium or tetraalkylammonium diazidoperfluorophthalocyanatoferrate. Other embodiments of the invention comprise compositions wherein the metal of the coordination complex is cobalt, manganese and chromium.

Ellis, P.E. Jr.; Lyons, J.E.

1994-10-11T23:59:59.000Z

335

Intermediate connector for stacked organic light emitting devices  

DOE Patents (OSTI)

A device is provided, having an anode, a cathode, and an intermediate connector disposed between the anode and the cathode. A first organic layer including an emissive sublayer is disposed between the anode and the intermediate connector, and a second including an emissive sublayer is disposed between the intermediate connector and the cathode. The intermediate connector includes a first metal having a work function lower than 4.0 eV and a second metal having a work function lower than 5.0 eV. The work function of the first metal is at least 0.5 eV less than the work function of the second metal. The first metal is in contact with a sublayer of the second organic layer that includes a material well adapted to receive holes from a low work function metal.

D& #x27; Andrade, Brian

2013-02-12T23:59:59.000Z

336

Precision metal rulers  

Science Conference Proceedings (OSTI)

... precision metal rulers. Our customers include state bureaus of Weights and Measures and departments of Agriculture. We also ...

2011-10-28T23:59:59.000Z

337

Fasteners & Metals Program  

Science Conference Proceedings (OSTI)

Directory of Accredited Laboratories. Fasteners & Metals Program. The Fastener Quality Act (FQA), Public Law 101-592, was ...

2013-11-08T23:59:59.000Z

338

TMS Light Metals Publication  

Science Conference Proceedings (OSTI)

The following instructions should be used when submitting a manuscript for any TMS Light Metals proceedings volume. INTRODUCTION. Orientation to ...

339

Building Technologies Office: Residential Furnaces and Boilers Framework  

NLE Websites -- All DOE Office Websites (Extended Search)

Residential Furnaces Residential Furnaces and Boilers Framework Meeting to someone by E-mail Share Building Technologies Office: Residential Furnaces and Boilers Framework Meeting on Facebook Tweet about Building Technologies Office: Residential Furnaces and Boilers Framework Meeting on Twitter Bookmark Building Technologies Office: Residential Furnaces and Boilers Framework Meeting on Google Bookmark Building Technologies Office: Residential Furnaces and Boilers Framework Meeting on Delicious Rank Building Technologies Office: Residential Furnaces and Boilers Framework Meeting on Digg Find More places to share Building Technologies Office: Residential Furnaces and Boilers Framework Meeting on AddThis.com... About Standards & Test Procedures Implementation, Certification & Enforcement

340

Applicant Organization: | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Applicant Organization: Applicant Organization: Applicant Organization: More Documents & Publications BlueFire Ethanol, Inc. Applicant Organization: Applicant Organization:...

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

PRODUCTION OF METALS  

DOE Patents (OSTI)

A process is described producing metallic thorium, titanium, zirconium, or hafnium from the fluoride. In the process, the fluoride is reduced with alkali or alkaline earth metal and a booster compound (e.g. iodine or a decomposable oxysalt) in a sealed bomb at superatmospheric pressure and a temperature above the melting point of the metal to be produced.

Spedding, F.H.; Wilhelm, H.A.; Keller, W.H.

1961-09-19T23:59:59.000Z

342

Durable metallized polymer mirror  

DOE Patents (OSTI)

A metallized polymer mirror construction is disclosed having improved durability against delamination and tunneling, comprising: an outer layer of polymeric material; a metal oxide layer underlying the outer layer of polymeric material; a silver reflective layer underneath the metal oxide layer; and a layer of adhesive attaching the silver layer to a substrate. 6 figs.

Schissel, P.O.; Kennedy, C.E.; Jorgensen, G.J.; Shinton, Y.D.; Goggin, R.M.

1994-11-01T23:59:59.000Z

343

Assess institutional frameworks for LEDS for land-use sector | Open Energy  

Open Energy Info (EERE)

Assess institutional frameworks for LEDS for land-use sector Assess institutional frameworks for LEDS for land-use sector Jump to: navigation, search Stage 3 LEDS Home Introduction to Framework Assess current country plans, policies, practices, and capacities Develop_BAU Stage 4: Prioritizing and Planning for Actions Begin execution of implementation plans 1.0. Organizing the LEDS Process 1.1. Institutional Structure for LEDS 1.2. Workplan to Develop the LEDS 1.3. Roles and responsibilities to develop LEDS 2.1. Assess current country plans, policies, practices, and capacities 2.2. Compile lessons learned and good practices from ongoing and previous sustainable development efforts in the country 2.3. Assess public and private sector capacity to support initiatives 2.4. Assess and improve the national GHG inventory and other

344

The Non-Organic Theory of the Genesis of Petroleum  

E-Print Network (OSTI)

Recent advances in interdisciplinary fields as diverse as astrophysics, cosmogeophysics, nuclear geology, etc. have led to interesting developments in the non-organic theory of the genesis of petroleum. This theory, which holds that petroleum is of an abiogenic primordial origin, provides an explanation for certain features of petroleum geology that are hard to explain within the standard organic framework. If the non-organic theory is correct, then hydrocarbon reserves would be enormous and almost inexhaustable.

Abbas, S

1996-01-01T23:59:59.000Z

345

A compiler framework for speculative optimizations  

Science Conference Proceedings (OSTI)

Speculative execution, such as control speculation or data speculation, is an effective way to improve program performance. Using edge/path profile information or simple heuristic rules, existing compiler frameworks can adequately incorporate and exploit ... Keywords: Data speculation, partial redundancy elimination, register promotion, speculative SSA form, speculative weak update

Jin Lin; Tong Chen; Wei-Chung Hsu; Pen-Chung Yew; Roy Dz-Ching Ju; Tin-Fook Ngai; Sun Chan

2004-09-01T23:59:59.000Z

346

A Framework for Historic Bridge Preservation  

E-Print Network (OSTI)

In an inevitably occurring process, bridges possessing historic, artistic, and engineering significance deteriorate and must be maintained and rehabilitated in order to be kept in service. Ideally, all potentially significant bridges would be properly preserved and continue to beautify and bring character to their surroundings for years to come. However, funding is currently limited for transportation projects in general, and even more so for historic bridge preservation, which some may consider less critical in comparison to other transportation needs. Because of this limitation on resources, it is important that bridge-owning agencies use proper planning and management strategies in order to make the best use of available funding. This thesis presents a framework designed to assist agencies in this process. The framework is devised specifically for TxDOT for use in Tarrant County, Texas, but can be used as a model for agencies anywhere with some modifications to fit the inventory under evaluation. Included in the framework are a methodology for prioritization of bridges within an inventory, guidance on financial and legal procedures, identification of potential funding sources, summary and review of condition assessment practices and bridge mitigation strategies, a template for individual bridge preservation plans, and a framework for resource allocation within a bridge inventory. It can be concluded from this research that early detection of defects, preventive maintenance, condition assessment beyond routine inspection, adjustment of evaluation methodology, and use of engineering judgment when using numerical evaluation methods are critical components of proper management of historic bridges.

Puls, Eric Mark

2013-08-01T23:59:59.000Z

347

Privacy, Technology, and Aging: A Proposed Framework  

E-Print Network (OSTI)

the development, adoption, and use of home-based ubiquitous technologies for older adults. We began with a five, adoption, and use of home-based ubiquitous technologies are highly contextual, individualized and aging can inform the development of a privacy framework for home-based technologies that can contribute

Camp, L. Jean

348

A Framework for Measuring Supercomputer Productivity  

Science Conference Proceedings (OSTI)

We propose a framework for measuring the productivity of high performance computing (HPC) systems, based on common economic definitions of productivity and on utility theory. We discuss how these definitions can capture essential aspects of HPC systems, ... Keywords: High-performance computing, Productivity, benchmarks, performance metrics

Marc Snir; David A. Bader

2004-11-01T23:59:59.000Z

349

Flexible Framework for Building Energy Analysis: Preprint  

SciTech Connect

In the building energy research and advanced practitioner communities, building models are perturbed across large parameter spaces to assess energy and cost performance in the face of programmatic and economic constraints. This paper describes the OpenStudio software framework for performing such analyses.

Hale, E.; Macumber, D.; Weaver, E.; Shekhar, D.

2012-09-01T23:59:59.000Z

350

An autonomic routing framework for sensor networks  

Science Conference Proceedings (OSTI)

Current routing services for sensor networks are often designed for specific applications and network conditions, thus have difficulty in adapting to application and network dynamics. This paper proposes an autonomic framework to promote the adaptivity ... Keywords: Autonomic routing, Feature functions, Monitoring policies, Sensor networks

Yu He; Cauligi S. Raghavendra; Steven Berson; Robert Braden

2006-04-01T23:59:59.000Z

351

GCspy: an adaptable heap visualisation framework  

Science Conference Proceedings (OSTI)

GCspy is an architectural framework for the collection, transmission, storage and replay of memory management behaviour. It makes new contributions to the understanding of the dynamic memory behaviour of programming languages (and especially object-oriented ... Keywords: Java, garbage collection, language implementation, memory management, visualisation of objects

Tony Printezis; Richard Jones

2002-11-01T23:59:59.000Z

352

A framework for schema matcher composition  

Science Conference Proceedings (OSTI)

Enterprise schemas tend to be different, which is the key issue when the seamless communication between systems is of utmost importance. One solution could be the development of standards which then could be enforced, however, vendors seem to be reluctant ... Keywords: algorithm analysis, framework definition, optimization, performance improvement, schema matching

Balazs Villanyi; Peter Martinek; Bela Szikora

2010-10-01T23:59:59.000Z

353

Free Parameters and Frameworks in Minimal Supersymmetry  

E-Print Network (OSTI)

405 Appendix A Free Parameters and Frameworks in Minimal Supersymmetry It is useful to discuss what the various schemes that exist for reducing the set of free parameters to a manageable number. The information, and so is fixed by experiment. The free parameters consist mainly of the coefficients of the "soft

354

Free Parameters and Frameworks in Minimal Supersymmetry  

E-Print Network (OSTI)

405 Appendix A Free Parameters and Frameworks in Minimal Supersymmetry It is useful to discuss what the various schemes that exist for reducing the set of free parameters to a manageable number. The information, and so is fixed by experiment. The free parameters consist mainly of the coe#cients of the ``soft

355

Compiler implementation in a formal logical framework  

Science Conference Proceedings (OSTI)

The task of designing and implementing a compiler can be a difficult and error-prone process. In this paper, we present a new approach based on the use of higher-order abstract syntax and term rewriting in a logical framework. All program transformations, ... Keywords: formal compiler, higher-order abstract syntax, logical programming environment

Jason Hickey; Aleksey Nogin; Adam Granicz

2003-08-01T23:59:59.000Z

356

CZT: a framework for Z tools  

Science Conference Proceedings (OSTI)

The Community Z Tools (CZT) project is an open-source Java framework for building formal methods tools for Z and Z dialects. It also includes a set of tools for parsing, typechecking, transforming and printing standard Z specifications in LATEX, Unicode ...

Petra Malik; Mark Utting

2005-04-01T23:59:59.000Z

357

A general implementation framework for tabled CLP  

Science Conference Proceedings (OSTI)

This paper describes a framework to combine tabling evaluation and constraint logic programming (TCLP). While this combination has been studied previously from a theoretical point of view and some implementations exist, they either suffer from a lack ... Keywords: constraint logic programming, implementation, performance, tabling

Pablo Chico de Guzmán; Manuel Carro; Manuel V. Hermenegildo; Peter Stuckey

2012-05-01T23:59:59.000Z

358

A national public healthcare framework using grid  

Science Conference Proceedings (OSTI)

This paper presents a framework for public healthcare by making a grid over public infrastructure such as Internet. It clearly illustrates the need and viability of such grids. The paper gives in details the technology required behind building such global ... Keywords: DICOM, HL7, SAN, component, grid, healthcare, national, security, state, taluka

Rekha Singhal

2010-09-01T23:59:59.000Z

359

Semantic Sensor Net: an extensible framework  

Science Conference Proceedings (OSTI)

Existing approaches for sensor networks suffer from a number of serious drawbacks, including assumption of homogeneous sensor nodes, application-dependency, engineering-orientation, and lack of interoperability. To overcome these drawbacks, we ... Keywords: architecture, data processing, dynamic tagging, framework, semantic information, semantic sensor net, semantics, sensor networks

Lionel M. Ni; Yanmin Zhu; Jian Ma; Qiong Luo; Yunhao Liu; S. C. Cheung; Qiang Yang; Minglu Li; Min-you Wu

2009-04-01T23:59:59.000Z

360

SYNFORMPeople, Trends and Views in Synthetic Organic Chemistry Direct Conversion of Arylamines  

E-Print Network (OSTI)

the organic molecules which are essential components of drugs, materials, agrochemicals, and all the organic SYNSTORY, Jianbo Wang (P. R. of China) elaborates on his recent metal-free conversion of arylamines

Wang, Jianbo

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Silica Embedded Metal Hydrides  

DOE Green Energy (OSTI)

A method to produce silica embedded metal hydride was developed. The product is a composite in which metal hydride particles are embedded in a matrix of silica. The silica matrix is highly porous. Hydrogen gas can easily reach the embedded metal hydride particles. The pores are small so that the metal hydride particles cannot leave the matrix. The porous matrix also protects the metal hydride particles from larger and reactive molecules such as oxygen, since the larger gas molecules cannot pass through the small pores easily. Tests show that granules of this composite can absorb hydrogen readily and withstand many cycles without making fines.

Heung, L.K. [Westinghouse Savannah River Company, AIKEN, SC (United States); Wicks, G.G.

1998-08-01T23:59:59.000Z

362

Method for recovering metals from waste  

DOE Patents (OSTI)

A method for recovering metals from metals-containing wastes, and vitrifying the remainder of the wastes for disposal. Metals-containing wastes such as circuit boards, cathode ray tubes, vacuum tubes, transistors and so forth, are broken up and placed in a suitable container. The container is heated by microwaves to a first temperature in the range of approximately 300-800.degree. C. to combust organic materials in the waste, then heated further to a second temperature in the range of approximately 1,000-1,550.degree. C. at which temperature glass formers present in the waste will cause it to melt and vitrify. Low-melting-point metals such as tin and aluminum can be recovered after organics combustion is substantially complete. Metals with higher melting points, such as gold, silver and copper, can be recovered from the solidified product or separated from the waste at their respective melting points. Network former-containing materials can be added at the start of the process to assist vitrification.

Wicks, George G. (North Augusta, SC); Clark, David E. (Gainesville, FL); Schulz, Rebecca L. (Gainesville, FL)

2000-01-01T23:59:59.000Z

363

Method for recovering metals from waste  

DOE Patents (OSTI)

A method is described for recovering metals from metals-containing wastes, and vitrifying the remainder of the wastes for disposal. Metals-containing wastes such as circuit boards, cathode ray tubes, vacuum tubes, transistors and so forth, are broken up and placed in a suitable container. The container is heated by microwaves to a first temperature in the range of approximately 300--800 C to combust organic materials in the waste, then heated further to a second temperature in the range of approximately 1,000--1,550 C at which temperature glass formers present in the waste will cause it to melt and vitrify. Low-melting-point metals such as tin and aluminum can be recovered after organics combustion is substantially complete. Metals with higher melting points, such as gold, silver and copper, can be recovered from the solidified product or separated from the waste at their respective melting points. Network former-containing materials can be added at the start of the process to assist vitrification. 2 figs.

Wicks, G.G.; Clark, D.E.; Schulz, R.L.

1998-12-01T23:59:59.000Z

364

Method for recovering metals from waste  

DOE Patents (OSTI)

A method for recovering metals from metals-containing wastes, and vitrifying the remainder of the wastes for disposal. Metals-containing wastes such as circuit boards, cathode ray tubes, vacuum tubes, transistors and so forth, are broken up and placed in a suitable container. The container is heated by microwaves to a first temperature in the range of approximately 300.degree.-800.degree. C. to combust organic materials in the waste, then heated further to a second temperature in the range of approximately 1,000.degree.-1,550.degree. C. at which temperature glass formers present in the waste will cause it to melt and vitrify. Low-melting-point metals such as tin and aluminum can be recovered after organics combustion is substantially complete. Metals with higher melting points, such as gold, silver and copper, can be recovered from the solidified product or separated from the waste at their respective melting points. Network former-containing materials can be added at the start of the process to assist vitrification.

Wicks, George G. (North Augusta, SC); Clark, David E. (Gainesville, FL); Schulz, Rebecca L. (Gainesville, FL)

1998-01-01T23:59:59.000Z

365

Extraction process for removing metallic impurities from alkalide metals  

DOE Patents (OSTI)

A development is described for removing metallic impurities from alkali metals by employing an extraction process wherein the metallic impurities are extracted from a molten alkali metal into molten lithium metal due to the immiscibility of the alkali metals in lithium and the miscibility of the metallic contaminants or impurities in the lithium. The purified alkali metal may be readily separated from the contaminant-containing lithium metal by simple decanting due to the differences in densities and melting temperatures of the alkali metals as compared to lithium.

Royer, Lamar T. (Knoxville, TN)

1988-01-01T23:59:59.000Z

366

Extraction process for removing metallic impurities from alkalide metals  

DOE Patents (OSTI)

A development is described for removing metallic impurities from alkali metals by employing an extraction process wherein the metallic impurities are extracted from a molten alkali metal into molten lithium metal due to the immiscibility of the alkali metals in lithium and the miscibility of the metallic contaminants or impurities in the lithium. The purified alkali metal may be readily separated from the contaminant-containing lithium metal by simple decanting due to the differences in densities and melting temperatures of the alkali metals as compared to lithium.

Royer, L.T.

1987-03-20T23:59:59.000Z

367

Structure-Directing Roles and Interactions of Fluoride and Organocations with Siliceous Zeolite Frameworks  

SciTech Connect

Interactions of fluoride anions and organocations with crystalline silicate frameworks are shown to depend subtly on the architectures of the organic species, which significantly influence the crystalline structures that result. One- and two-dimensional (2D) {sup 1}H, {sup 19}F, and {sup 29}Si nuclear magnetic resonance (NMR) spectroscopy measurements establish distinct intermolecular interactions among F{sup -} anions, imidazolium structure-directing agents (SDA{sup +}), and crystalline silicate frameworks for as-synthesized siliceous zeolites ITW and MTT. Different types and positions of hydrophobic alkyl ligands on the imidazolium SDA{sup +} species under otherwise identical zeolite synthesis compositions and conditions lead to significantly different interactions between the F{sup -} and SDA{sup +} ions and the respective silicate frameworks. For as-synthesized zeolite ITW, F{sup -} anions are established to reside in the double-four-ring (D4R) cages and interact strongly and selectively with D4R silicate framework sites, as manifested by their strong {sup 19}F{sup 29}Si dipolar couplings. By comparison, for as-synthesized zeolite MTT, F{sup -} anions reside within the 10-ring channels and interact relatively weakly with the silicate framework as ion pairs with the SDA{sup +} ions. Such differences manifest the importance of interactions between the imidazolium and F{sup -} ions, which account for their structure-directing influences on the topologies of the resulting silicate frameworks. Furthermore, 2D {sup 29}Si{l_brace}{sup 29}Si{r_brace} double-quantum NMR measurements establish {sup 29}Si-O-{sup 29}Si site connectivities within the as-synthesized zeolites ITW and MTT that, in conjunction with synchrotron X-ray diffraction analyses, establish insights on complicated order and disorder within their framework structures.

Shayib, Ramzy M.; George, Nathan C.; Seshadri, Ram; Burton, Allen W.; Zones, Stacey I.; Chmelka, Bradley F. (UCSB); (Chevron ETC)

2012-02-06T23:59:59.000Z

368

Characterization of a New Family of Metal Transport Proteins  

SciTech Connect

Soils at many DOE sites are contaminated with metals and radionuclides. Such soils obviously pose a risk to human and animal health. Unlike organic wastes, which can be metabolized, metals are immutable and cannot be degraded into harmless constituents. Phytoremediation, the use of plants to remove toxic materials from soil and water, may prove to be an environmentally friendly and cost effective solution for cleaning up metal contaminated sites. The success of phytoremediation will rely on the availability of plants that absorb, translocate, and tolerate the contaminating metals. However, before we can engineer such plants, we need more basic information on how plants acquire metals. An important long term goal of our research program is to understand how metals such as zinc, cadmium and iron are transported across membranes. Our research is focused on a new family of metal transporters, which we have identified through combined studies in the yeast Saccharomyces cerevisiae and in the model plant Arabidopsis thaliana. We have identified a family of 24 presumptive metal transport genes in a variety of organisms including yeast, trypanosomes, plants, nematodes, and humans. This family, which we have designated the ''ZIP'' genes, provides a rich source of material with which to undertake studies on metal transport in eukar

Guerinot, Mary Lou; Eide, David

1999-06-01T23:59:59.000Z

369

Destruction of organic wastes with molten oxidizers  

DOE Patents (OSTI)

A process for destruction of biologically hazardous organic chemical wastes by using liquefied strongly oxidizing inorganic salts, such as the alkali metal nitrates, at high temperatures and atmospheric pressure, to yield inorganic salts, carbon dioxide, and water. The oxidizing salts are regenerated and recycled.

Bradshaw, R.W.; Holmes, J.T.; Tyner, C.E.

1990-12-31T23:59:59.000Z

370

Destruction of organic wastes with molten oxidizers  

DOE Patents (OSTI)

A process for destruction of biologically hazardous organic chemical wastes by using liquefied strongly oxidizing inorganic salts, such as the alkali metal nitrates, at high temperatures and atmospheric pressure, to yield inorganic salts, carbon dioxide, and water. The oxidizing salts are regenerated and recycled.

Bradshaw, R.W.; Holmes, J.T.; Tyner, C.E.

1990-01-01T23:59:59.000Z

371

Reaction-Forming Method for Producing Near Net-Shape Refractory Metal Carbides  

DOE Patents (OSTI)

A method for reaction forming refractory metal carbides. The method involves the fabrication of a glassy carbon preform by casting an organic, resin-based liquid mixture into a mold and subsequently heat treating it in two steps, which cures and pyrolizes the resin resulting in a porous carbon preform. By varying the amounts of the constituents in the organic, resin-based liquid mixture, control over the density of the carbon preform is obtained. Control of the density and microstructure of the carbon preform allows for determination of the microstructure and properties of the refractory metal carbide material produced. The glassy carbon preform is placed on a bed of refractory metal or refractory metal--silicon alloy. The pieces are heated above the melting point of the metal or alloy. The molten metal wicks inside the porous carbon preform and reacts, forming the refractory metal carbide or refractory metal carbide plus a minor secondary phase.

Palmisiano, Marc N.; Jakubenas, Kevin J.; Baranwal, Rita

2004-07-20T23:59:59.000Z

372

Ligand Intermediates in Metal-Catalyzed Reactions  

DOE Green Energy (OSTI)

The longest-running goal of this project has been the synthesis, isolation, and physical chemical characterization of homogeneous transition metal complexes containing ligand types believed to be intermediates in the metal-catalyzed conversion of CO/H{sub 2}, CO{sub 2}, CH{sub 4}, and similar raw materials to organic fuels, feedstocks, etc. In the current project period, complexes that contain unusual new types of C{sub x}(carbide) and C{sub x}O{sub y} (carbon oxide) ligands have been emphasized. A new program in homogeneous fluorous phase catalysis has been launched as described in the final report.

Gladysz, John A.

1999-07-31T23:59:59.000Z

373

Sumitomo Metal Industries Ltd Sumitomo Metals | Open Energy Information  

Open Energy Info (EERE)

Sumitomo Metal Industries Ltd Sumitomo Metals Sumitomo Metal Industries Ltd Sumitomo Metals Jump to: navigation, search Name Sumitomo Metal Industries Ltd (Sumitomo Metals) Place Osaka-shi, Osaka, Japan Zip 540-0041 Sector Solar Product Engaged in the steel, engineering, and electronics businesses; works on fuel cell component technology and manufactures silicon wafers for the solar sector. References Sumitomo Metal Industries Ltd (Sumitomo Metals)[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Sumitomo Metal Industries Ltd (Sumitomo Metals) is a company located in Osaka-shi, Osaka, Japan . References ↑ "Sumitomo Metal Industries Ltd (Sumitomo Metals)" Retrieved from "http://en.openei.org/w/index.php?title=Sumitomo_Metal_Industries_Ltd_Sumitomo_Metals&oldid=351744"

374

Reading Comprehension - Organs and Organ Systems  

NLE Websites -- All DOE Office Websites (Extended Search)

together in a group make up an organ system. Examples of organ systems are cats and dogs the circulatory system and the respiratory system the stomacular system and...

375

Evolution of Organic Aerosols in the Atmosphere.  

SciTech Connect

Organic aerosol (OA) particles affect climate forcing and human health, but their sources and evolution remain poorly characterized. We present a unifying model framework that describes the atmospheric evolution of OA and is constrained and motivated by new, high time resolution, experimental characterizations of their composition, volatility, and oxidation state. OA and OA-precursor gases evolve by becoming increasingly oxidized, less volatile, and more hygroscopic, leading to the formation of large amounts of oxygenated organic aerosol (OOA) mass that has comparable concentrations to sulfate aerosol over the Northern Hemisphere. Our new model framework captures the dynamic aging behavior observed in the atmosphere and the laboratory and can serve as a basis for improving parameterizations in regional and global models.

Jimenez, J. L.; Canagaratna, M. R.; Donahue, N. M.; Prevot, A. S. H.; Zhang, Qi; Kroll, Jesse H.; DeCarlo, Peter F.; Allan, James D.; Coe, H.; Ng, N. L.; Aiken, Allison; Docherty, Kenneth S.; Ulbrich, Ingrid M.; Grieshop, A. P.; Robinson, A. L.; Duplissy, J.; Smith, J. D.; Wilson, K. R.; Lanz, V. A.; Hueglin, C.; Sun, Y. L.; Tian, J.; Laaksonen, A.; Raatikainen, T.; Rautiainen, J.; Vaattovaara, P.; Ehn, M.; Kulmala, M.; Tomlinson, Jason M.; Collins, Donald R.; Cubison, Michael J.; Dunlea, E. J.; Huffman, John A.; Onasch, Timothy B.; Alfarra, M. R.; Williams, Paul I.; Bower, K.; Kondo, Yutaka; Schneider, J.; Drewnick, F.; Borrmann, S.; Weimer, S.; Demerjian, K.; Salcedo, D.; Cottrell, L.; Griffin, Robert; Takami, A.; Miyoshi, T.; Hatakeyama, S.; Shimono, A.; Sun, J. Y.; Zhang, Y. M.; Dzepina, K.; Kimmel, Joel; Sueper, D.; Jayne, J. T.; Herndon, Scott C.; Trimborn, Achim; Williams, L. R.; Wood, Ezra C.; Middlebrook, A. M.; Kolb, C. E.; Baltensperger, Urs; Worsnop, Douglas R.

2009-12-11T23:59:59.000Z

376

FORMING PROTECTIVE FILMS ON METAL  

DOE Patents (OSTI)

Methods are described of inhibiting the corrosion of ferrous metal by contact with heavy liquid metals such as bismuth and gallium at temperatures above 500 icient laborato C generally by bringing nltrogen and either the metal zirconium, hafnium, or titanium into reactlve contact with the ferrous metal to form a thin adherent layer of the nitride of the metal and thereafter maintaining a fractional percentage of the metal absorbed in the heavy liquid metal in contact with the ferrous metal container. The general purpose for uslng such high boiling liquid metals in ferrous contalners would be as heat transfer agents in liquid-metal-fueled nuclear reactors.

Gurinsky, D.H.; Kammerer, O.F.; Sadofsky, J.; Weeks, J.R.

1958-12-16T23:59:59.000Z

377

Enterprise Information Security Management Framework [EISMF  

E-Print Network (OSTI)

There are several technological solutions available in the market to help organizations with information security breach detection and prevention such as intrusion detection and prevention systems, antivirus software, ...

Sharma, Dhirendra, S.M. Massachusetts Institute of Technology

2011-01-01T23:59:59.000Z

378

CIM-EARTH : Framework and case study.  

SciTech Connect

General equilibrium models have been used for decades to obtain insights into the economic implications of policies and decisions. Despite successes, however, these economic models have substantive limitations. Many of these limitations are due to computational and methodological constraints that can be overcome by leveraging recent advances in computer architecture, numerical methods, and economics research. Motivated by these considerations, we are developing a new modeling framework: the Community Integrated Model of Economic and Resource Trajectories for Humankind (CIM-EARTH). In this paper, we describe the key features of the CIM-EARTH framework and initial implementation, detail the model instance we use for studying the impacts of a carbon tax on international trade and the sensitivity of these impacts to assumptions on the rate of change in energy efficiency and labor productivity, and present results on the extent to which carbon leakage limits global reductions in emissions for some policy scenarios.

Elliott, J.; Foster, I.; Judd, K.; Moyer, E.; Munson, T.; Univ. of Chicago

2010-01-01T23:59:59.000Z

379

A Strategic Framework for SMR Deployment  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

A Strategic Framework for SMR Deployment February 24, 2012 Introduction A strategy for the successful deployment of small modular reactors (SMRs) must consider what the goals of deployment would entail, the challenges to achieving these goals and the approach to overcome those challenges. This paper will attempt to offer a framework for addressing these important issues at the outset of the program. The deployment of SMRs will be realized by private power companies making the decision to purchase and operate SMRs from private vendors. The government role is to set national priorities for clean energy and national security and create incentives to achieve them. The policy tools the government may choose to use to advance this technology in support of these national objectives will evolve as SMRs advance

380

A framework for modeling rail transport vulnerability  

Science Conference Proceedings (OSTI)

Railroads represent one of the most efficient methods of long-haul transport for bulk commodities, from coal to agricultural products. Over the past fifty years, the rail network has contracted while tonnage has increased. Service, geographically, has been abandoned along short haul routes and increased along major long haul routes, resulting in a network that is more streamlined. The current rail network may be very vulnerable to disruptions, like the failure of a trestle. This paper proposes a framework to model rail network vulnerability and gives an application of this modeling framework in analyzing rail network vulnerability for the State of Washington. It concludes with a number of policy related issues that need to be addressed in order to identify, plan, and mitigate the risks associated with the sudden loss of a bridge or trestle.

Peterson, Steven K [ORNL; Church, Richard L. [University of California, Santa Barbara

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

FRAMEWORK FOR AGENT-BASED ROLE DELEGATION  

E-Print Network (OSTI)

This paper describes a framework for addressing the administration of role delegation introduced in the wellknown role-based access control model (RBAC). More specifically, this paper describes how a third party, called an agent, can administer the delegation of roles on behalf of a user who is a member of a certain role and wishes to delegate his role to another user who belongs to another role. Furthermore, this paper describes a framework of reference to systematically address the diverse manifestations of the agent-based delegation, such as Role participant agent, Non-role participant agent, Static, and Dynamic types of delegation and introduces an agent-based delegation model that illustrates delegation based on non-role participant delegation.

Ezedin Barka; Ravi Sandhu

2007-01-01T23:59:59.000Z

382

DOE Hydrogen Analysis Repository: Novel Non-Precious Metal Catalysts  

NLE Websites -- All DOE Office Websites (Extended Search)

Novel Non-Precious Metal Catalysts Novel Non-Precious Metal Catalysts Project Summary Full Title: Novel Non-Precious Metal Catalysts for PEMFC: Catalyst Selection through Molecular Modeling and Durability Studies Project ID: 147 Principal Investigator: Branko Popov Brief Description: The University of South Carolina is synthesizing novel non-precious metal electrocatalysts with similar activity and stability as Pt for oxygen reduction reaction (ORR). Keywords: Catalyst; oxygen reduction; non precious metals; molecular modeling; durability Purpose Develop highly active and stable carbon-based metal-free catalysts and carbon composite catalysts with strong Lewis basicity to facilitate the ORR. Performer Principal Investigator: Branko Popov Organization: University of South Carolina Address: 2C19 Swearingen, Chemical Engineering, 301 Main Street

383

Tri-State Demand Response Framework  

Science Conference Proceedings (OSTI)

This report provides the results of a demand response framework development project of Tri-State Generation and Transmission, a wholesale provider to a number of rural electric associations in the Rocky Mountain west. Tri-State has developed an assortment of planned demand response and energy shaping products and services designed to both shave peak and shift consumption to off-peak hours. The applications, networks, and devices that will be needed to support these needs will involve many ...

2013-03-28T23:59:59.000Z

384

An Optimization Framework for Driver Feedback Systems  

SciTech Connect

Modern vehicles have sophisticated electronic control units that can control engine operation with discretion to balance fuel economy, emissions, and power. These control units are designed for specific driving conditions (e.g., different speed profiles for highway and city driving). However, individual driving styles are different and rarely match the specific driving conditions for which the units were designed. In the research reported here, we investigate driving-style factors that have a major impact on fuel economy and construct an optimization framework to optimize individual driving styles with respect to these driving factors. In this context, we construct a set of polynomial metamodels to reflect the responses produced in fuel economy by changing the driving factors. Then, we compare the optimized driving styles to the original driving styles and evaluate the effectiveness of the optimization framework. Finally, we use this proposed framework to develop a real-time feedback system, including visual instructions, to enable drivers to alter their driving styles in response to actual driving conditions to improve fuel efficiency.

Malikopoulos, Andreas [ORNL; Aguilar, Juan P. [Georgia Institute of Technology

2013-01-01T23:59:59.000Z

385

Constructibility review process framework for transportation facilities  

E-Print Network (OSTI)

Constructibility is the optimum use of construction knowledge and experience in planning, design, procurement, and field operations in order to achieve overall project objectives ("Constructibility: a primer" 1986). This Thesis presents a framework for implementing constructibility to the transportation industry. The challenge of applying such a process to the transportation industry is the contracting strategy predominantly used: the design/bid/build strategy. In such a contracting environment construction is performed as a completely separate phase. Changes in key players occur once the project is awarded to the contractor. Contractors have little or no opportunity to provide input to planners and designers. The framework developed in this research consists of performing a series of constructibility functions during specific project development phases. Constructibility functions such as forming project teams, storing and retrieving constructibility lessons learned, and providing construction feedback to designers make the project development process more efficient. The computer technique used to build the Constructibility Review Process Framework is the IDEFO modeling technique. The technique is used for modeling functions in a process (decisions, actions, and activities) and the relationship between the functions (Mayer). The model was developed after a thorough investigation of the critical issues facing the state transportation agencies, and an understanding of the current environment these agencies operate in.

Liman, Majed

1995-01-01T23:59:59.000Z

386

Metal atomization spray nozzle  

DOE Patents (OSTI)

A spray nozzle for a magnetohydrodynamic atomization apparatus has a feed passage for molten metal and a pair of spray electrodes mounted in the feed passage. The electrodes, diverging surfaces which define a nozzle throat and diverge at an acute angle from the throat. Current passes through molten metal when fed through the throat which creates the Lorentz force necessary to provide atomization of the molten metal.

Huxford, Theodore J. (Harriman, TN)

1993-01-01T23:59:59.000Z

387

Metal atom oxidation laser  

DOE Patents (OSTI)

A chemical laser which operates by formation of metal or carbon atoms and reaction of such atoms with a gaseous oxidizer in an optical resonant cavity is described. The lasing species are diatomic or polyatomic in nature and are readily produced by exchange or other abstraction reactions between the metal or carbon atoms and the oxidizer. The lasing molecules may be metal or carbon monohalides or monoxides. (auth)

Jensen, R.J.; Rice, W.W.; Beattie, W.H.

1975-10-28T23:59:59.000Z

388

Metal atom oxidation laser  

DOE Patents (OSTI)

A chemical laser which operates by formation of metal or carbon atoms and reaction of such atoms with a gaseous oxidizer in an optical resonant cavity is described. The lasing species are diatomic or polyatomic in nature and are readily produced by exchange or other abstraction reactions between the metal or carbon atoms and the oxidizer. The lasing molecules may be metal or carbon monohalides or monoxides.

Jensen, R.J.; Rice, W.W.; Beattie, W.H.

1975-10-28T23:59:59.000Z

389

Supported metal alloy catalysts  

DOE Patents (OSTI)

A process of preparing a Group IV, V, or VI metal carbonitride including reacting a Group IV, V, or VI metal amide complex with ammonia to obtain an intermediate product; and, heating the intermediate product to temperatures and for times sufficient to form a Group IV, V, or VI metal carbonitride is provided together with the product of the process and a process of reforming an n-alkane by use of the product.

Barrera, Joseph (Albuquerque, NM); Smith, David C. (Santa Clara, CA)

2000-01-01T23:59:59.000Z

390

Metal atomization spray nozzle  

DOE Patents (OSTI)

A spray nozzle for a magnetohydrodynamic atomization apparatus has a feed passage for molten metal and a pair of spray electrodes mounted in the feed passage. The electrodes, diverging surfaces which define a nozzle throat and diverge at an acute angle from the throat. Current passes through molten metal when fed through the throat which creates the Lorentz force necessary to provide atomization of the molten metal. 6 figures.

Huxford, T.J.

1993-11-16T23:59:59.000Z

391

Characterization of Light Metals  

Science Conference Proceedings (OSTI)

Mar 15, 2012 ... Characterization of Grit Blasted Metallic Biomaterials by ... The grit blasting, a surface improvement treatment is used to enhance mechanical ...

392

ELECTRON WELDING OF METALS  

SciTech Connect

The advantages and disadvantages of the electron welding of metals are briefly reviewed. Typical apparatuses used for electron welding are described. (J.S.R)

Stohr, J.-A.

1958-03-01T23:59:59.000Z

393

Metal Matrix Composites - TMS  

Science Conference Proceedings (OSTI)

METAL- MATRIX COMPOSITES UNDER MULTI- AXIAL LOADINGS: M. V. S. Ravisankar ... including the values of the stress exponent and the activation energy.

394

A decision making framework for cruise ship design  

E-Print Network (OSTI)

This thesis develops a new decision making framework for initial cruise ship design. Through review of effectiveness analysis and multi-criteria decision making, a uniform philosophy is created to articulate a framework ...

Katsoufis, George P. (George Paraskevas)

2006-01-01T23:59:59.000Z

395

A linux kernel cryptographic framework: decoupling cryptographic keys from applications  

Science Conference Proceedings (OSTI)

This paper describes a cryptographic service framework for the Linux kernel. The framework enables user-space applications to perform operations with cryptographic keys, while at the same time ensuring that applications cannot directly access or extract ...

Nikos Mavrogiannopoulos; Miloslav Trma?; Bart Preneel

2012-03-01T23:59:59.000Z

396

Improving Building Performance at Urban Scale with a Framework...  

NLE Websites -- All DOE Office Websites (Extended Search)

Improving Building Performance at Urban Scale with a Framework for Real-time Data Sharing Title Improving Building Performance at Urban Scale with a Framework for Real-time Data...

397

A UI-Driven lightweight framework for developing web applications  

Science Conference Proceedings (OSTI)

Due to the increasing complexity of Web applications, systematic processes and supporting tools are required for the development of Web applications. In this paper, we propose a UI-driven lightweight framework for building Web applications. This framework ...

Keeyoull Lee; Sanghyun Park; Chunwoo Lee; Woosung Jung; Wookjin Lee; Byungjeong Lee; Heechern Kim; Chisu Wu

2005-07-01T23:59:59.000Z

398

The cactus framework and toolkit: design and applications  

Science Conference Proceedings (OSTI)

We describe Cactus, a framework for building a variety of computing applications in science and engineering, including astrophysics, relativity and chemical engineering.We first motivate by example the need for such frameworks to support multi-platform, ...

Tom Goodale; Gabrielle Allen; Gerd Lanfermann; Joan Massó; Thomas Radke; Edward Seidel; John Shalf

2002-06-01T23:59:59.000Z

399

An Information Systems Design Framework for Facilitating TQM Implementation  

Science Conference Proceedings (OSTI)

This paper provides a framework for information systems IS design for TQM implementation. The framework consists of three main phases. In the first, TQM implementation tasks are established. These tasks include identifying customer satisfaction variables ...

Nazim U. Ahmed; Ramarathnam Ravichandran

1999-10-01T23:59:59.000Z

400

Renewable Energy Project Development and Finance Framework: The...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Development and Finance Framework: The Five-Step Process Webinar Renewable Energy Project Development and Finance Framework: The Five-Step Process Webinar March 26, 2014 5:45PM MDT...

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

A framework for sustainable buildings : an application to China  

E-Print Network (OSTI)

A framework has been established to discuss the different topics of Sustainability in the context of buildings. The framework includes the dimensions of time and space and the dimensions of ecology, society, and economy. ...

Ospelt, Christoph, 1970-

1999-01-01T23:59:59.000Z

402

Site Transition Framework for Long-Term Surveillance and Maintenance  

Energy.gov (U.S. Department of Energy (DOE))

The Site Transition Framework (STF) provides a framework for all U.S. Department of Energy (DOE) facilities and sites where DOE may have anticipated long-term surveillance and maintenance (LTS&...

403

Drive-access transit : a regional analytical framework  

E-Print Network (OSTI)

A framework for analyzing drive-access transit at a regional level is developed in this research. This framework is intended primarily for in-house use by regional transit agencies, yet has implications for the regional ...

Sorensen, James B

2005-01-01T23:59:59.000Z

404

Enhancement of Watershed Analysis Risk Management Framework (WARMF) for Mercury Watershed Management and Total Maximum Daily Loads (TMDLs)  

Science Conference Proceedings (OSTI)

This report documents the enhancement of EPRI's Watershed Analysis Risk Management Framework (WARMF) to enable it to simulate the biogeochemical cycling and fish accumulation of mercury in the environment. This report should be of value to the power sector, industry, environmental organizations, government, and public agencies concerned about environmental mercury.

2006-03-13T23:59:59.000Z

405

MALEF: Framework for distributed machine learning and data mining  

Science Conference Proceedings (OSTI)

Growing importance of distributed data mining techniques has recently attracted attention of researchers in multiagent domain. In this paper we present a novel framework MultiAgent Learning Framework (MALEF) designed for both the agent-based ... Keywords: MAS, agent-based systems, architectures, data mining, distributed machine learning, market-based approaches, multi-agent systems, multiagent learning frameworks, unsupervised clustering

Jan Tozicka; Michael Rovatsos; Michal Pechoucek; Stepan Urban

2008-02-01T23:59:59.000Z

406

Security Requirements Engineering: A Framework for Representation and Analysis  

E-Print Network (OSTI)

Security Requirements Engineering: A Framework for Representation and Analysis Charles B. Haley Abstract--This paper presents a framework for security requirements elicitation and analysis. The framework is based on constructing a context for the system, representing security requirements as constraints

Haley, Charles B.

407

Porous metallic bodies  

DOE Patents (OSTI)

Porous metallic bodies having a substantially uniform pore size of less than about 200 microns and a density of less than about 25 percent theoretical, as well as the method for making them, are disclosed. Group IIA, IIIB, IVB, VB, and rare earth metal hydrides a

Landingham, R.L.

1984-03-13T23:59:59.000Z

408

Explosion metal welding  

SciTech Connect

Process parameters pertaining to welding similar and dissimilar metals using explosives are reviewed. The discussion centers on the interrelationship of physical parameters which play a part in achieving desirable metallurgical results. Present activities in explosion metal welding at LASL are presented and shown how they related to the interests of the ERDA community.

Popoff, A.A.

1976-01-01T23:59:59.000Z

409

Clean Metal Spray Forming  

Science Conference Proceedings (OSTI)

controlled transfer of liquid metal from the ESR pool to the spray forming system is performed using a ... heating to maintain superheat and avoid freezing of the liquid metal as it flows through the funnel. ... As is the case with all similar cross-.

410

PRODUCTION OF PLUTONIUM METAL  

DOE Patents (OSTI)

A process is given for producing plutonium metal by the reduction of plutonium chloride, dissolved in alkali metal chloride plus or minus aluminum chloride, with magnesium or a magnesium-aluminum alloy at between 700 and 800 deg C and separating the plutonium or plutonium-aluminum alloy formed from the salt.

Lyon, W.L.; Moore, R.H.

1961-01-17T23:59:59.000Z

411

Liquid metal hydrogen barriers  

DOE Patents (OSTI)

Hydrogen barriers which comprise liquid metals in which the solubility of hydrogen is low and which have good thermal conductivities at operating temperatures of interest. Such barriers are useful in nuclear fuel elements containing a metal hydride moderator which has a substantial hydrogen dissociation pressure at reactor operating temperatures.

Grover, George M. (Los Alamos, NM); Frank, Thurman G. (Los Alamos, NM); Keddy, Edward S. (Los Alamos, NM)

1976-01-01T23:59:59.000Z

412

Making Sustainable Decisions Using The KONVERGENCE Framework  

Science Conference Proceedings (OSTI)

Hundreds of contaminated facilities and sites must be cleaned up. ''Cleanup'' includes decommissioning, environmental restoration, and waste management. Cleanup can be complex, expensive, risky, and time-consuming. Decisions are often controversial, can stall or be blocked, and are sometimes re-done--some before implementation, some decades later. Making and keeping decisions with long time horizons involves special difficulties and requires new approaches. Our project goal is to make cleanup decisions easier to make, implement, keep, and sustain. By sustainability, we mean decisions that work better over the entire time-period-from when a decision is made, through implementation, to its end point. That is, alternatives that can be kept ''as is'' or adapted as circumstances change. Increased attention to sustainability and adaptability may decrease resistance to making and implementing decisions. Our KONVERGENCE framework addresses these challenges. The framework is based on a mental model that states: where Knowledge, Values, and Resources converge (the K, V, R in KONVERGENCE), you will find a sustainable decision. We define these areas or universes as follows: (1) Knowledge: what is known about the problem and possible solutions? (2) Values: what is important to those affected by the decision? (3) Resources: what is available to implement possible solutions or improve knowledge? This mental model helps analyze and visualize what is happening as decisions are made and kept. Why is there disagreement? Is there movement toward konvergence? Is a past decision drifting out of konvergence? The framework includes strategic improvements, i.e., expand the spectrum of alternatives to include adaptable alternatives and decision networks. It includes tactical process improvements derived from experience, values, and relevant literature. This paper includes diagnosis and medication (suggested path forward) for intractable cases.

Piet, S. J.; Gibson, P. L.; Joe, J. C.; Kerr, T. A.; Nitschke, R. L.; Dakins, M. E.

2003-02-25T23:59:59.000Z

413

About the 12th International Conference on Metal Organic Vapor ...  

Science Conference Proceedings (OSTI)

... phosphide based materials; Gallium arsenide based materials; High brightness LEDs and solid state lighting; Growth of device structures: LEDs, laser diodes, ...

414

Metal Organic Vapor Phase Epitaxy ICMOVPE-XV  

Science Conference Proceedings (OSTI)

Growth of Energy Technology (solid state lighting, PV, Thermoelectrics, etc) ..... treatment prices when booked in advance for the attendees and guests of.

415

Solvent-Assisted Mechanochemical Synthesis of the Metal–Organic ...  

Science Conference Proceedings (OSTI)

Anode Materials for Reprocessing of Spent Nuclear Fuel ... Computational Design and Synthesis of Intermetallic Clathrates for Energy Storage and Recovery.

416

About the 12th International Conference on Metal Organic Vapor ...  

Science Conference Proceedings (OSTI)

Limos can be arranged. Shuttle service is available. Or you can rent a car - you may be surprised to find that our rental rates and packages are generally lower ...

417

Ninth International Conference on Metal Organic Vapor Phase ...  

Science Conference Proceedings (OSTI)

Hertz Rent-a-Car System has been selected as the Official Car Rental Company for the ICMOVPE IX. Special rates are being offered and will be honored up to ...

418

About the Ninth International Conference on Metal Organic Vapor ...  

Science Conference Proceedings (OSTI)

... Dept. of Chemical Engineering, Building 66-566, 25 Ames Street, Cambridge, ... Packard Laboratories; Jerry Olson, National Renewable Energy Laboratory; ...

419

Development of New Biphasic Metal Organic Working Fluids for...  

Open Energy Info (EERE)

extracted from the geothermal source brine. Enthalpy gain of the working fluid in the heat exchanger occurs principally from sensible heat gained while passing through the heat...

420

Ninth International Conference on Metal Organic Vapor Phase ...  

Science Conference Proceedings (OSTI)

Free sample copies of III-Vs Review and information on the Advanced ... on the market an innovative surface contamination analysis with the powerful TOF SIMS ... NIMTEC, located in Chandler, AZ, is a subsidiary of Japan Energy that sells ...

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Removal of Xenon and Krypton from Air Using Metal Organic ...  

Science Conference Proceedings (OSTI)

... two gases is cryogenic distillation which is an energy-intensive process. ... Determining Thermal Conductivity of Simulated Feed for High Level Waste Glass.

422

Production of magnesium metal  

DOE Patents (OSTI)

A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention further relates to a process for production of magnesium metal or a magnesium compound where an external source of carbon dioxide is not used in any of the reactions of the process. The invention also relates to the magnesium metal produced by the processes described herein.

Blencoe, James G. (Harriman, TN); Anovitz, Lawrence M. (Knoxville, TN); Palmer, Donald A. (Oliver Springs, TN); Beard, James S. (Martinsville, VA)

2010-02-23T23:59:59.000Z

423

Strategic planning for MIS: a conceptual framework  

Science Conference Proceedings (OSTI)

Increasingly, Management Information Services (MIS) divisions within organizations are becoming more centrally involved in the mainstream of corporate activities. MIS projects are becoming more complex and expensive; are affecting more aspects of the ...

Ephraim R. McLean; John V. Soden

1976-06-01T23:59:59.000Z

424

ATLAS Tags Web Service calls Athena via Athenaeum Framework  

E-Print Network (OSTI)

High Energy Physics experiments start using a Web Service style application to access functionality of their main frameworks. Those frameworks, however, are not ready to be executed in a standard Web Service environment as frameworks are too complex, monolithic and use non-standard and non-portable technologies. ATLAS Tag Browser is one of those Web Service. To provide the possibility to extract full ATLAS events from the standard Web Service, we need to access to full ATLAS offline framework - Athena. As Athena cannot run directly within any Web Service, the client server approach has been chosen. Web Service calls Athena remotely over XML-RPC connection using Athenaeum framework.

Hrivnac, J; The ATLAS collaboration

2011-01-01T23:59:59.000Z

425

A Generic Framework for Network Forensics  

E-Print Network (OSTI)

Internet is the most powerful medium as on date, facilitating varied services to numerous users. It has also become the environment for cyber warfare where attacks of many types (financial, ideological, revenge) are being launched. The e-commerce transactions being carried out online are of major interest to cybercriminals. The Internet needs to be protected from these attacks and an appropriate response has to be generated to handle them to reduce the impact. Network forensics is the science that deals with capture, recording, and analysis of network traffic for investigative purpose and incident response. There are many tools which assist in capturing data transferred over the networks so that an attack or the malicious intent of the intrusions may be investigated. This paper presents a generic framework for network forensic analysis by specifically identifying the steps connected only to network forensics from the already proposed models for digital investigation. Each of the phases in the framework is elucidated. A comparison of the proposed model is done with the existing models for digital investigation. Research challenges in various phases of the model are approached with specific reference to network forensics.

Emmanuel S. Pilli; R. C. Joshi; Rajdeep Niyogi

2010-01-01T23:59:59.000Z

426

Perspectives on Dam Removal: York Creek Dam and the Water Framework Directive  

E-Print Network (OSTI)

Figure 4. Water Framework Directive decision-making processand the Water Framework Directive LA 222 UC Berkeley May 16Dam and the Water Framework Directive Justin Lawrence, Josh

Lawrence, Justin E; Pollak, Josh D; Richmond, Sarah F

2008-01-01T23:59:59.000Z

427

Reservoir Management in Mediterranean Climates through the European Water Framework Directive  

E-Print Network (OSTI)

the EuropeanWater Framework Directive? ” Elsevier Cabecinha,Under the Water Framework Directive. Conacher, A.J. , Sala,The EU Water Framework Directive: measures and implications.

O'Reilly, Clare; Silberblatt, Rafael

2009-01-01T23:59:59.000Z

428

Business Center for Precious Metals  

NLE Websites -- All DOE Office Websites (Extended Search)

Department of Energy Business Center for Precious Metals Department of Energy Business Center for Precious Metals Becky Eddy National Nuclear Security Administration Y-12 Site...

429

Metal RIE 1: Unaxis 790  

Science Conference Proceedings (OSTI)

... Scientific Opportunities / Applications: Physical milling of most metals; Anisotropic etching of metal films; Anisotropic etching of SiO 2 and SiN x. ...

2013-04-23T23:59:59.000Z

430

Wild-Inspired Intrusion Detection System Framework for High Speed Networks f|p IDS Framework  

Science Conference Proceedings (OSTI)

While the rise of the Internet and the high speed networks made information easier to acquire, faster to exchange and more flexible to share, it also made the cybernetic attacks and crimes easier to perform, more accurate to hit the target victim and ... Keywords: Cybernetic Attacks, Framework, High Speed Network, Intrusion Detection, Monitoring

Hassen Sallay; Mohsen Rouached; Adel Ammar; Ouissem Ben Fredj; Khalid Al-Shalfan; Majdi Ben Saad

2011-10-01T23:59:59.000Z

431

Actinide metal processing  

DOE Patents (OSTI)

A process for converting an actinide metal such as thorium, uranium, or plutonium to an actinide oxide material by admixing the actinide metal in an aqueous medium with a hypochlorite as an oxidizing agent for sufficient time to form the actinide oxide material and recovering the actinide oxide material is described together with a low temperature process for preparing an actinide oxide nitrate such as uranyl nitrate. Additionally, a composition of matter comprising the reaction product of uranium metal and sodium hypochlorite is provided, the reaction product being an essentially insoluble uranium oxide material suitable for disposal or long term storage.

Sauer, N.N.; Watkin, J.G.

1992-03-24T23:59:59.000Z

432

Actinide metal processing  

DOE Patents (OSTI)

This invention is comprised of a process of converting an actinide metal such as thorium, uranium, or plutonium to an actinide oxide material by admixing the actinide metal in an aqueous medium with a hypochlorite as an oxidizing agent for sufficient time to form the actinide oxide material and recovering the actinide oxide material is provided together with a low temperature process of preparing an actinide oxide nitrate such as uranyl nitrate. Additionally, a composition of matter comprising the reaction product of uranium metal and sodium hypochlorite is provided, the reaction product being an essentially insoluble uranium oxide material suitable for disposal or long term storage.

Sauer, N.N.; Watkin, J.G.

1991-04-05T23:59:59.000Z

433

Liquid metal electric pump  

DOE Patents (OSTI)

An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other. 3 figs.

Abbin, J.P.; Andraka, C.E.; Lukens, L.L.; Moreno, J.B.

1992-01-14T23:59:59.000Z

434

Charged Metallic Clusters  

Science Conference Proceedings (OSTI)

Usually in Nuclear Physics the minimum of the liquid drop model (LDM) energy occurs at a mass asymmetry which is different from the minimum of shell correction. Charged metallic clusters are ideal emitters of singly ionized trimers because both LDM and shell correction are reaching a minimum for the same mass asymmetry corresponding to the emission of a charged particle with two delocalized electrons. Maximum dissociation energy (Q-value) is obtained for metallic clusters with high surface tension and low Wigner-Seitz radius (transition metals). The Q-values for spheroidal shapes are much larger than for hemispheroids.

Poenaru, D. N.; Gherghescu, R. A. [Horia Hulubei National Institute of Physics and Nuclear Engineering (IFIN-HH), Bucharest-Magurele (Romania); Frankfurt Institute for Advanced Studies, Johann Wolfgang Goethe University, Frankfurt am Main (Germany); Solov'yov, A. V.; Greiner, W. [Frankfurt Institute for Advanced Studies, Johann Wolfgang Goethe University, Frankfurt am Main (Germany)

2009-12-03T23:59:59.000Z

435

Interaction Between Toxic Metals and Complex Biofilm/Mineral/Solution  

NLE Websites -- All DOE Office Websites (Extended Search)

highlights highlights title by Alexis S. Templeton, Thomas P. Trainor, and Gordon E. Brown, Jr., Stanford University Sorption reactions on particle surfaces can dramatically affect the speciation, cycling and bioavailability of essential micronutrients (i.e. PO43-, Cu, Zn etc.) and toxic metals and metalloids (i.e. Pb, Hg, Se, As) in soils and aquatic environments. Considerable attention has been focused on understanding metal sorption reactions at a molecular/mechanistic level and the effects of metal concentration, pH, ionic strength, and complexing ligands on the ways in which metal ions bind to the surfaces of common mineral phases such as Fe-, Mn- and Al-(hydr)oxides and clays. However, a significant fraction of mineral surfaces in natural environments are extensively colonized by microbial organisms, which can also be potent sorbents for metals due to the large number of reactive functional groups that decorate the cell walls and outer membranes of bacterial surfaces.

436

Dr. Yun Liu's Openings  

Science Conference Proceedings (OSTI)

... for many applications such as gas sequestration, energy storage ... media including metal-organic frameworks (MOFs), activated carbon, porous silica ...

2011-12-05T23:59:59.000Z

437

Multi-Physics Functional Design of HeteroFoaM Nanomaterials for ...  

Science Conference Proceedings (OSTI)

Hierarchical Microporous Materials: Rational and Designable Heterogeneous Catalysts for Renewable Energy · Improved Design of Metal-Organic Framework

438

Hierarchical Template of Porous Carbon for Multifunctional ...  

Science Conference Proceedings (OSTI)

Hierarchical Template of Porous Carbon for Multifunctional Applications · Interstitial Hydride ... Structurally Dynamic Metal Organic Frameworks for CO2 Capture.

439

Method for hydrogen production and metal winning, and a catalyst/cocatalyst composition useful therefor  

DOE Patents (OSTI)

A catalyst/cocatalyst/organics composition of matter is useful in electrolytically producing hydrogen or electrowinning metals. Use of the catalyst/cocatalyst/organics composition causes the anode potential and the energy required for the reaction to decrease. An electrolyte, including the catalyst/cocatalyst composition, and a reaction medium composition further including organic material are also described.

Dhooge, Patrick M. (Corrales, NM)

1987-10-13T23:59:59.000Z

440

Making Sustainable Decisions Using the KONVERGENCE Framework  

SciTech Connect

Hundreds of contaminated facilities and sites must be cleaned up. “Cleanup” includes decommissioning, environmental restoration, and waste management. Cleanup can be complex, expensive, risky, and time-consuming. Decisions are often controversial, can stall or be blocked, and are sometimes re-done - some before implementation, some decades later. Making and keeping decisions with long time horizons involves special difficulties and requires new approaches, including: • New ways (mental model) to analyze and visualize the problem, • Awareness of the option to shift strategy or reframe from a single decision to an adaptable network of decisions, and • Improved tactical processes that account for several challenges. These include the following: • Stakeholder values are a more fundamental basis for decision making and keeping than “meeting regulations.” • Late-entry players and future generations will question decisions. • People may resist making “irreversible” decisions. • People need “compelling reasons” to take action in the face of uncertainties. Our project goal is to make cleanup decisions easier to make, implement, keep, and sustain. By sustainability, we mean decisions that work better over the entire time-period—from when a decision is made, through implementation, to its end point. That is, alternatives that can be kept “as is” or adapted as circumstances change. Increased attention to sustainability and adaptability may decrease resistance to making and implementing decisions. Our KONVERGENCE framework addresses these challenges. The framework is based on a mental model that states: where Knowledge, Values, and Resources converge (the K, V, R in KONVERGENCE), you will find a sustainable decision. We define these areas or universes as follows: • Knowledge: what is known about the problem and possible solutions? • Values: what is important to those affected by the decision? • Resources: what is available to implement possible solutions or improve knowledge? This mental model helps analyze and visualize what is happening as decisions are made and kept. Why is there disagreement? Is there movement toward konvergence? Is a past decision drifting out of konvergence? The framework includes strategic improvements, i.e., expand the spectrum of alternatives to include adaptable alternatives and decision networks. It includes tactical process improvements derived from experience, values, and relevant literature. This paper includes diagnosis and medication (suggested path forward) for intractable cases.

Piet, Steven James; Gibson, Patrick Lavern; Joe, Jeffrey Clark; Kerr, Thomas A; Nitschke, Robert Leon; Dakins, Maxine Ellen

2003-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

ADLIB: A simple database framework for beamline codes  

SciTech Connect

There are many well developed codes available for beamline design and analysis. A significant fraction of each of these codes is devoted to processing its own unique input language for describing the problem. None of these large, complex, and powerful codes does everything. Adding a new bit of specialized physics can be a difficult task whose successful completion makes the code even larger and more complex. This paper describes an attempt to move in the opposite direction, toward a family of small, simple, single purpose physics and utility modules, linked by an open, portable, public domain database framework. These small specialized physics codes begin with the beamline parameters already loaded in the database, and accessible via the handful of subroutines that constitute ADLIB. Such codes are easier to write, and inherently organized in a manner suitable for incorporation in model based control system algorithms. Examples include programs for analyzing beamline misalignment sensitivities, for simulating and fitting beam steering data, and for translating among MARYLIE, TRANSPORT, and TRACE3D formats.

Mottershead, C.T.

1993-01-01T23:59:59.000Z

442

ADLIB: A simple database framework for beamline codes  

SciTech Connect

There are many well developed codes available for beamline design and analysis. A significant fraction of each of these codes is devoted to processing its own unique input language for describing the problem. None of these large, complex, and powerful codes does everything. Adding a new bit of specialized physics can be a difficult task whose successful completion makes the code even larger and more complex. This paper describes an attempt to move in the opposite direction, toward a family of small, simple, single purpose physics and utility modules, linked by an open, portable, public domain database framework. These small specialized physics codes begin with the beamline parameters already loaded in the database, and accessible via the handful of subroutines that constitute ADLIB. Such codes are easier to write, and inherently organized in a manner suitable for incorporation in model based control system algorithms. Examples include programs for analyzing beamline misalignment sensitivities, for simulating and fitting beam steering data, and for translating among MARYLIE, TRANSPORT, and TRACE3D formats.

Mottershead, C.T.

1993-03-01T23:59:59.000Z

443

Self-organization in multi-agent systems  

Science Conference Proceedings (OSTI)

This paper is the synthesis of joint work realised in a technical forum group within the AgentLink III NoE framework, which elaborated on issues concerning self-organization and emergence in multi-agent systems (MAS). The work concluded on a common definition ...

Giovanna Di Marzo Serugendo; Marie-Pierre Gleizes; Anthony Karageorgos

2005-06-01T23:59:59.000Z

444

An Interactive Simulation Framework for Burning Objects  

E-Print Network (OSTI)

We present a simulation framework to integrate several aspects of the combustion and burning process in a unified and modular manner. A simple three gas flame model is used to simulate a combustion process, while air motion is simulated as a single moving fluid. Solid objects inside the simulation domain can catch fire and start burning. Heat information is transferred from the fluid simulator to a solid simulator, while the solid simulator injects fuel into the fluid simulation. We also present a simple yet effective method for modeling of object decomposition under combustion using level set methods. The interaction between modules is presented as well as a discussion of fluid-solid coupling. All simulation modules run together at interactive rates, enabling the user to tweak the simulation parameters and setup for desired behavior 1. 1

Zeki Melek; John Keyser

2005-01-01T23:59:59.000Z

445

Divalent metal nanoparticles  

E-Print Network (OSTI)

Metal nanoparticles hold promise for many scientific and technological applications, such as chemical and biological sensors, vehicles for drug delivery, and subdiffraction limit waveguides. To fabricate such devices, a ...

DeVries, Gretchen Anne

2008-01-01T23:59:59.000Z

446

Controlled Metal Photodeposition  

A reliable syntheses of semiconductor-metal heterostructure has been developed to enable application of materials in catalytic, magnetic, and opto-electronic devices, and Iowa State University, The Ames Laboratory's Contractor, is looking for ...

447

Production of magnesium metal  

DOE Patents (OSTI)

A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention also relates to the magnesium metal produced by the processes described herein.

Blencoe, James G. (Harriman, TN); Anovitz, Lawrence M. (Knoxville, TN); Palmer, Donald A. (Oliver Springs, TN); Beard, James S. (Martinsville, VA)

2012-04-10T23:59:59.000Z

448

Metal Matrix Composites II  

Science Conference Proceedings (OSTI)

Oct 29, 2013... of Al-AC8H/Al2O3p Metal Matrix Composites Produced by Stir Casting Route: Anne Zulfia1; Maman Ajiriyanto1; 1University of Indonesia

449

General Light Metals  

Science Conference Proceedings (OSTI)

Mar 3, 2011 ... A detailed literature survey indicates that vacuum sintering is able to produce ... In recent years, there is a high demand for light-weight metals foams. ... Each powder mixture's composition is determined by response surface ...

450

Adsorption Mechanism and Uptake of Methane in Covalent Organic Frameworks: Theory and Experiment  

E-Print Network (OSTI)

pollutants by combustion and evaporation, including nitrogen oxides, sulfur oxide, carbon monoxide-burning characteristics.2 Moreover, the huge reserves of natural gas (NG) (>95% CH4, with some ethane, nitrogen, higher be liquefied at room temperature, increasing the cost of its transportation.3 Attempts to overcome

Yaghi, Omar M.

451

Engineering Systems Matrix: An organizing framework for modeling large-scale complex systems  

E-Print Network (OSTI)

The scope and complexity of engineered systems are ever-increasing as burgeoning global markets, unprecedented technological capabilities, rising consumer expectations, and ever-changing social requirements present difficult ...

Bartolomei, Jason E.

452

A framework for benchmarking land models  

SciTech Connect

Land models, which have been developed by the modeling community in the past few decades to predict future states of ecosystems and climate, have to be critically evaluated for their performance skills of simulating ecosystem responses and feedback to climate change. Benchmarking is an emerging procedure to measure performance of models against a set of defined standards. This paper proposes a benchmarking framework for evaluation of land model performances and, meanwhile, highlights major challenges at this infant stage of benchmark analysis. The framework includes (1) targeted aspects of model performance to be evaluated, (2) a set of benchmarks as defined references to test model performance, (3) metrics to measure and compare performance skills among models so as to identify model strengths and deficiencies, and (4) model improvement. Land models are required to simulate exchange of water, energy, carbon and sometimes other trace gases between the atmosphere and land surface, and should be evaluated for their simulations of biophysical processes, biogeochemical cycles, and vegetation dynamics in response to climate change across broad temporal and spatial scales. Thus, one major challenge is to select and define a limited number of benchmarks to effectively evaluate land model performance. The second challenge is to develop metrics of measuring mismatches between models and benchmarks. The metrics may include (1) a priori thresholds of acceptable model performance and (2) a scoring system to combine data model mismatches for various processes at different temporal and spatial scales. The benchmark analyses should identify clues of weak model performance to guide future development, thus enabling improved predictions of future states of ecosystems and climate. The near-future research effort should be on development of a set of widely acceptable benchmarks that can be used to objectively, effectively, and reliably evaluate fundamental properties of land models to improve their prediction performance skills.

Luo, Yiqi [University of Oklahoma; Randerson, James T. [University of California, Irvine; Hoffman, Forrest [ORNL; Norby, Richard J [ORNL

2012-01-01T23:59:59.000Z

453

A framework for benchmarking land models  

SciTech Connect

Land models, which have been developed by the modeling community in the past few decades to predict future states of ecosystems and climate, have to be critically evaluated for their performance skills of simulating ecosystem responses and feedback to climate change. Benchmarking is an emerging procedure to measure performance of models against a set of defined standards. This paper proposes a benchmarking framework for evaluation of land model performances and, meanwhile, highlights major challenges at this infant stage of benchmark analysis. The framework includes (1) targeted aspects of model performance to be evaluated, (2) a set of benchmarks as defined references to test model performance, (3) metrics to measure and compare performance skills among models so as to identify model strengths and deficiencies, and (4) model improvement. Land models are required to simulate exchange of water, energy, carbon and sometimes other trace gases between the atmosphere and land surface, and should be evaluated for their simulations of biophysical processes, biogeochemical cycles, and vegetation dynamics in response to climate change across broad temporal and spatial scales. Thus, one major challenge is to select and define a limited number of benchmarks to effectively evaluate land model performance. The second challenge is to develop metrics of measuring mismatches between models and benchmarks. The metrics may include (1) a priori thresholds of acceptable model performance and (2) a scoring system to combine data–model mismatches for various processes at different temporal and spatial scales. The benchmark analyses should identify clues of weak model performance to guide future development, thus enabling improved predictions of future states of ecosystems and climate. The near-future research effort should be on development of a set of widely acceptable benchmarks that can be used to objectively, effectively, and reliably evaluate fundamental properties of land models to improve their prediction performance skills.

Luo, Yiqi; Randerson, J.; Abramowitz, G.; Bacour, C.; Blyth, E.; Carvalhais, N.; Ciais, Philippe; Dalmonech, D.; Fisher, J.B.; Fisher, R.; Friedlingstein, P.; Hibbard, Kathleen A.; Hoffman, F. M.; Huntzinger, Deborah; Jones, C.; Koven, C.; Lawrence, David M.; Li, D.J.; Mahecha, M.; Niu, S.L.; Norby, Richard J.; Piao, S.L.; Qi, X.; Peylin, P.; Prentice, I.C.; Riley, William; Reichstein, M.; Schwalm, C.; Wang, Y.; Xia, J. Y.; Zaehle, S.; Zhou, X. H.

2012-10-09T23:59:59.000Z

454

IRRADIATION METHOD OF CONVERTING ORGANIC COMPOUNDS  

DOE Patents (OSTI)

A method is given for changing the distribution of organic compounds from that produced by the irradiation of bulk alkane hydrocarbons. This method consists of depositing an alkane hydrocarbon on the surface of a substrate material and irradiating with gamma radiation at a dose rate of more than 100,000 rads. The substrate material may be a metal, metal salts, metal oxides, or carbons having a surface area in excess of 1 m/sup 2//g. The hydrocarbons are deposited in layers of from 0.1 to 10 monolayers on the surfaces of these substrates and irradiated. The product yields are found to vary from those which result from the irradiation of bulk hydrocarbons in that there is an increase in the quantity of branched hydrocarbons.

Allen, A.O.; Caffrey, J.M. Jr.

1960-10-11T23:59:59.000Z

455

Lithium metal reduction of plutonium oxide to produce plutonium metal  

DOE Patents (OSTI)

A method is described for the chemical reduction of plutonium oxides to plutonium metal by the use of pure lithium metal. Lithium metal is used to reduce plutonium oxide to alpha plutonium metal (alpha-Pu). The lithium oxide by-product is reclaimed by sublimation and converted to the chloride salt, and after electrolysis, is removed as lithium metal. Zinc may be used as a solvent metal to improve thermodynamics of the reduction reaction at lower temperatures. Lithium metal reduction enables plutonium oxide reduction without the production of huge quantities of CaO--CaCl.sub.2 residues normally produced in conventional direct oxide reduction processes.

Coops, Melvin S. (Livermore, CA)

1992-01-01T23:59:59.000Z

456

Molten metal reactors  

SciTech Connect

A molten metal reactor for converting a carbon material and steam into a gas comprising hydrogen, carbon monoxide, and carbon dioxide is disclosed. The reactor includes an interior crucible having a portion contained within an exterior crucible. The interior crucible includes an inlet and an outlet; the outlet leads to the exterior crucible and may comprise a diffuser. The exterior crucible may contain a molten alkaline metal compound. Contained between the exterior crucible and the interior crucible is at least one baffle.

Bingham, Dennis N; Klingler, Kerry M; Turner, Terry D; Wilding, Bruce M

2013-11-05T23:59:59.000Z

457

Policy Framework for a 21st Century: Enabling our Secure Energy Future  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Framework Framework for a 21 st Century Grid Enabling Our Secure Energy Future Background: ARRA investments in Grid Modernization * $4.5 billion in federal money * $5.5 billion match from utilities and industry * 99 Smart Grid Investment Grants * 42 demonstration grants * 52 workforce training grants 2 National Science and Technology Council (NSTC) Subcommittee on Smart Grid * 11 Agency task force * Co-chaired by: - Patricia Hoffman, Assistant Secretary, DOE Office of Electricity Reliability and Deliverability - George Arnold, National Coordinator for Smart Grid Interoperability, NIST * Met with over 100 organizations including states, utilities, technology firms, and consumer advocates * Drew on three Requests for Information 1 1 Information and RFI comments: http://www.oe.energy.gov/Smart%20Grid%20Request%20f

458

Organization | Department of Energy  

NLE Websites -- All DOE Office Websites (Extended Search)

Organization Leadership Organization Contact Us The Office of Economic Impact and Diversity is comprised of six offices: The Office of the Director- contact us Office of...

459

SSRL Users' Organization Ballot  

NLE Websites -- All DOE Office Websites (Extended Search)

2003 SSRL Users' Organization Executive Committee (SSRLUO-EC) Ballot The SSRL Users' Organization Executive Committee represents the scientific user community to the SSRL...

460

A scalable framework for distributed ontologies  

Science Conference Proceedings (OSTI)

In large-scale Peer-to-Peer (P2P) systems, information is usually generated decentralized. An architecture that enables applications to have a unified view on various information sources is currently attracting enormous attention. For building that architecture, ... Keywords: grid computing, semantic web, virtual organization

Ngot Phu Bui; Young-Tack Park; TaeChoong Chung

2008-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Symposium Organizer Information  

Science Conference Proceedings (OSTI)

National Metal and Materials Technology Center 114 Thailand Science Park Pahol Yothen Rd Klong Luard, 12120. Thailand Telephone: 011-66-2-5646500

462

ATLAS Tags Web Service calls Athena via Athenaeum Framework  

E-Print Network (OSTI)

High Energy Physics experiments start using a Web Service style application to access functionality of their main frameworks. Those frameworks, however, are not ready to be executed in a standard Web Service environment as frameworks are too complex, monolithic and use non-standard and non-portable technologies. ATLAS Tag Browser is one of those Web Service. To provide the possibility to extract full ATLAS events from the standard Web Service, we need to access to full ATLAS offline framework - Athena. As Athena cannot run directly within any Web Service, the client server approach has been chosen. Web Service calls Athena remotely over XML-RPC connection using Athenaeum framework. The paper will discuss integration of Athenaeum framework with ATLAS Tag database service, its distributed deployment, monitoring and performance.

Hrivnac, J; The ATLAS collaboration

2010-01-01T23:59:59.000Z

463

Decision Framework for Evaluating Advanced Nuclear Fuel Cycle Options  

Science Conference Proceedings (OSTI)

EPRI is working to develop tools to support long-term strategic planning for research, development, and demonstration (RD&D) of advanced nuclear fuel cycle technologies for electricity generation. The development of a decision framework to help guide the eventual deployment of advanced nuclear technologies represents a key component of this effort. This interim report describes the structure of a prototypical EPRI decision framework and illustrates how that framework can be applied to assess nuclear fuel...

2011-12-13T23:59:59.000Z

464

Optimization Online - A New Framework for Combining Global and ...  

E-Print Network (OSTI)

Jul 29, 2013 ... exxonmobil.com). Abstract: We propose a new framework for the optimization of computationally expensive black box problems, where neither ...

465

Risk assessment framework for geologic carbon sequestration sites  

E-Print Network (OSTI)

Framework for geologic carbon sequestration risk assessment,for geologic carbon sequestration risk assessment, Energyfor Geologic Carbon Sequestration, Int. J. of Greenhouse Gas

Oldenburg, C.

2010-01-01T23:59:59.000Z

466

Microstructure Sensitive Design Framework for Elastic-Plastic Multi ...  

Science Conference Proceedings (OSTI)

Abstract Scope, In this study, a microstructure sensitive design (MSD) framework for elastic-plastic ... Elastic Deformation Mechanics of Cellulose Nanocrystals.

467

A software framework for simulation-based scientific investigations .  

E-Print Network (OSTI)

??This thesis provides a design and development of a software architecture and programming framework that enables domain-oriented scientific investigations to be more easily developed and… (more)

Salman, Adnan M., 1965-

2010-01-01T23:59:59.000Z

468

EV Everywhere Battery Workshop: Preliminary Target-Setting Framework  

NLE Websites -- All DOE Office Websites (Extended Search)

Battery Workshop: Preliminary Target-Setting Framework Jacob Ward, Vehicle Technologies Senior Analyst July 26, 2012 Doubletree-Rosemont, Chicago, IL For this Analysis, Three "EV "...

469

Modeling Framework and Associated Simulation Tools for the ...  

Science Conference Proceedings (OSTI)

A modeling framework and the associated simulation tools are presented. It allows the ... Thermochemical Degradation Mechanisms of SiC/BN/SiC Composites.

470

Step 3. Identify the Appropriate Adoption Process and Framework...  

NLE Websites -- All DOE Office Websites (Extended Search)

3. Identify the Appropriate Adoption Process and Framework Description Once the code support infrastructure has established clear, measurable goals for a new energy code or update,...

471

NETL: News Release - State Regulatory Framework Will Most Likely...  

NLE Websites -- All DOE Office Websites (Extended Search)

February 1, 2011 State Regulatory Framework Will Most Likely Result in Robust CO2 Pipeline System, New Study Says Analysis Funded by NETL May Help Speed Commercialization of...

472

Stochastic Optimal Control Framework for Natural Gas Network...  

NLE Websites -- All DOE Office Websites (Extended Search)

Stochastic Optimal Control Framework for Natural Gas Network Operations Event Sponsor: Mathematics and Computing Science - LANS Seminar Start Date: Nov 20 2013 - 3:00pm Building...

473

The CO2 Adsorption in Zeolitic Imidazolate Framework 7  

Science Conference Proceedings (OSTI)

Author(s), Pu Zhao, Giulio Lampronti, Gareth Lloyd, Simon Redfern. On-Site Speaker (Planned), Pu Zhao. Abstract Scope, Zeolitic Imidazolate Framework 7 ...

474

Enterprise performance measurement system : metric design framework and tools  

E-Print Network (OSTI)

Existing metric selection methodologies and performance measurement frameworks provide practicing managers with good checklists and tools to evaluate and design their enterprise performance measurement systems (EPMS) and ...

Teo, Kai Siang

2013-01-01T23:59:59.000Z

475

Multi-scale, Multi-physics Optimization Framework for Additively ...  

Science Conference Proceedings (OSTI)

On-Site Speaker (Planned), Tahany El-Wardany. Abstract Scope, This paper proposes an optimization framework that enables the integration of multi-scale ...

476

Framework for Reducing Cyber Risks to Critical Infrastructure  

Science Conference Proceedings (OSTI)

... Policies and standards are published on an ... Law enforcement and the Federal Bureau of ... Duke Energy comments for Developing a Framework to ...

2013-04-08T23:59:59.000Z

477

Using the Victorian Curriculum and Standards Framework in music education.  

E-Print Network (OSTI)

??This research examined the usefulness of the Victorian Curriculum and Standards Framework as the basis for school music education in Victoria. Interviews with experienced primary… (more)

Blyth, Andrew

2004-01-01T23:59:59.000Z

478

Recency Of Faulting And Neotechtonic Framework In The Dixie Valley...  

Open Energy Info (EERE)

Recency Of Faulting And Neotechtonic Framework In The Dixie Valley Geothermal Field And Other Geothermal Fields Of The Basin And Range Jump to: navigation, search GEOTHERMAL...

479

Addressing college readiness through a positive deviance framework.  

E-Print Network (OSTI)

??This exploratory study utilized a positive deviance theoretical framework to unveil the challenges faced by students preparing for college, as well as the strategies used… (more)

Rainey, Christie A.

2012-01-01T23:59:59.000Z

480

Cybersecurity Framework Workshop - May 29-31 2013  

Science Conference Proceedings (OSTI)

... Online: https://www.starwoodmeeting.com/Book/sei13. Phone: 412-261-2000 Ask for the Cybersecurity Framework Workshop rate. ...

2013-06-10T23:59:59.000Z

Note: This page contains sample records for the topic "metal organic frameworks" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

A Framework for the Optimization of Integrated Energy Systems...  

Open Energy Info (EERE)

A Framework for the Optimization of Integrated Energy Systems(Jain and Alleyne 2012) Home > Groups > Energy Systems Integration Qinsun's picture Submitted by Qinsun(35) Member 15...

482

An Analytical Framework for Long Term Policy for Commercial Deployment...  

Open Energy Info (EERE)

An Analytical Framework for Long Term Policy for Commercial Deployment and Innovation in Carbon Capture and Sequestration Technology in the United States Jump to: navigation,...

483

A Bayesian Network Framework for Relational Shape Matching  

E-Print Network (OSTI)

entropy maximization for Bayesian belief propagation. In T.problem. Essentially, the Bayesian network searches for theof the relational shape matching Bayesian network framework.

Anand Rangarajan; James Coughlan; Alan L. Yuille

2011-01-01T23:59:59.000Z

484

A Framework for Studying the Environmental Impact of Biofuel Policies.  

E-Print Network (OSTI)

??In this thesis I present a new framework for investigating the environmental im- pact of and optimal policies for biofuel production. The model captures the… (more)

Størkersen, Thea Charlotte

2012-01-01T23:59:59.000Z

485

Method for forming metal contacts  

DOE Patents (OSTI)

Methods of forming metal contacts with metal inks in the manufacture of photovoltaic devices are disclosed. The metal inks are selectively deposited on semiconductor coatings by inkjet and aerosol apparatus. The composite is heated to selective temperatures where the metal inks burn through the coating to form an electrical contact with the semiconductor. Metal layers are then deposited on the electrical contacts by light induced or light assisted plating.

Reddington, Erik; Sutter, Thomas C; Bu, Lujia; Cannon, Alexandra; Habas, Susan E; Curtis, Calvin J; Miedaner, Alexander; Ginley, David S; Van Hest, Marinus Franciscus Antonius Maria

2013-09-17T23:59:59.000Z

486

Liquid metal thermal electric converter  

DOE Patents (OSTI)

A liquid metal thermal electric converter which converts heat energy to electrical energy. The design of the liquid metal thermal electric converter incorporates a unique configuration which directs the metal fluid pressure to the outside of the tube which results in the structural loads in the tube to be compressive. A liquid metal thermal electric converter refluxing boiler with series connection of tubes and a multiple cell liquid metal thermal electric converter are also provided.

Abbin, Joseph P. (Albuquerque, NM); Andraka, Charles E. (Albuquerque, NM); Lukens, Laurance L. (Albuquerque, NM); Moreno, James B. (Albuquerque, NM)

1989-01-01T23:59:59.000Z

487

Organic Electronics: Organic thin-film magnetometers  

SciTech Connect

Magnetometry usually requires large probes and bulky instrumentation. Organic diodes have now been used in small probes that can measure moderate magnetic fields with 10 ppm precision.

Shinar, Joseph

2012-07-24T23:59:59.000Z

488

Standards Development Organization Overview  

Science Conference Proceedings (OSTI)

... Standards Organizations NFPA (National Fire Protection Association) ... Fire News – Annual directory – NFPA Buyer's Guide ... Headquarters ...

2010-04-28T23:59:59.000Z

489

Transportation Organization and Functions  

Energy.gov (U.S. Department of Energy (DOE))

Office of Packaging and Transportation list of organizations and functions, with a list of acronyms.

490

TREC Organization User Agreement  

Science Conference Proceedings (OSTI)

Organization Application to use the TREC Information- Retrieval Text Research Collections. The _____ ...

491

INEL metal recycle annual report, FY-94  

SciTech Connect

In 1992, the mission of the Idaho Chemical Processing Plant was changed from reprocessing of spent nuclear fuels to development of technologies for conditioning of spent nuclear fuels and other high-level wastes for disposal in a geologic repository. In addition, the Department of Energy (DOE) directed Idaho National Engineering Laboratory (INEL) to develop a program plan addressing the management of radioactive contaminated scrap metal (RSM) within the DOE complex. Based on discussions with the EM-30 organization, the INEL Metal Recycle program plan was developed to address all issues of RSM management. Major options considered for RSM management were engineered interim storage, land disposal as low-level waste, and beneficial reuse/recycle. From its inception, the Metal Recycle program has emphasized avoidance of storage and disposal costs through beneficial reuse of RSM. The Metal Recycle program plan includes three major activities: Site-by-site inventory of RSM resources; validation of technologies for conversion of RSM to usable products; and identification of parties prepared to participate in development of a RSM recycle business.

Bechtold, T.E. [ed.

1994-09-01T23:59:59.000Z

492

Evaporative printing of organic materials and metals and development of organic memories  

E-Print Network (OSTI)

The advantages of directed printing make it the ideal fabrication tool for the ubiquitous electronic technologies of the future. However, direct printing techniques such as ink-jet technology, are currently limited to ...

Kang, Sung Hoon, 1974-

2004-01-01T23:59:59.000Z

493

Quantum corrected spherical collapse: A phenomenological framework  

SciTech Connect

A phenomenological framework is presented for incorporating quantum gravity motivated corrections into the dynamics of spherically symmetric collapse. The effective equations are derived from a variational principle that guarantees energy conservation and the existence of a Birkhoff theorem. The gravitational potential can be chosen as a function of the areal radius to yield specific nonsingular static spherically symmetric solutions that generically have two horizon