National Library of Energy BETA

Sample records for metal hydride number

  1. Metal Hydrides

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Metal Hydrides Theodore Motyka Savannah River National Laboratory Metal Hydride System Architect Jose-Miguel Pasini, & Bart van Hassel UTRC Claudio Corgnale & Bruce Hardy SRNL ...

  2. Metal hydrides

    SciTech Connect (OSTI)

    Carnes, J.R.; Kherani, N.P.

    1987-11-01

    Metal hydride information is not available for most hydrides in a consolidated quick-reference source. This report's objective is to fill the need for such a document providing basic thermodynamic data for as many metal hydrides as possible. We conduced a computerized library search to access as many sources as possible and screened each source for such thermodynamic data as pressure-temperature graphs, van't Hoff curves, and impurity effects. We included any other relevant information and commented on it. A primary concern to be investigated in the future is the behavior of metal tritides. This would be important in the area of emergency tritium cleanup systems. The hydride graphs are useful, however, as tritides may be expected in most cases to behave similarly and at least follow trends of their respective hydrides. 42 refs., 40 figs., 5 tabs.

  3. Metal Hydride Hydrogen Storage Research and Development

    Broader source: Energy.gov [DOE]

    DOE's research on complex metal hydrides targets the development of advanced metal hydride materials including light-weight complex hydrides, destabilized binary hydrides, intermetallic hydrides,...

  4. Working with SRNL - Our Facilities - Metal Hydride Laboratories

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Metal Hydride Laboratories Working with SRNL Our Facilities - Metal Hydride Laboratories The Metal Hydride Laboratories are used for research and development on metal hydride...

  5. Dimensionally stable metallic hydride composition

    DOE Patents [OSTI]

    Heung, Leung K. (Aiken, SC)

    1994-01-01

    A stable, metallic hydride composition and a process for making such a composition. The composition comprises a uniformly blended mixture of a metal hydride, kieselguhr, and a ballast metal, all in the form of particles. The composition is made by subjecting a metal hydride to one or more hydrogen absorption/desorption cycles to disintegrate the hydride particles to less than approximately 100 microns in size. The particles are partly oxidized, then blended with the ballast metal and the kieselguhr to form a uniform mixture. The mixture is compressed into pellets and calcined. Preferably, the mixture includes approximately 10 vol. % or more kieselguhr and approximately 50 vol. % or more ballast. Metal hydrides that can be used in the composition include Zr, Ti, V, Nb, Pd, as well as binary, tertiary, and more complex alloys of La, Al, Cu, Ti, Co, Ni, Fe, Zr, Mg, Ca, Mn, and mixtures and other combinations thereof. Ballast metals include Al, Cu and Ni.

  6. Metal Hydride Storage Materials | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Storage » Metal Hydride Storage Materials Metal Hydride Storage Materials The Fuel Cell Technologies Office's (FCTO's) metal hydride storage materials research focuses on improving the volumetric and gravimetric capacities, hydrogen adsorption/desorption kinetics, cycle life, and reaction thermodynamics of potential material candidates. Technical Overview Figure shows pressure composition isotherms and van't Hoff traces for metal hydride materials. Metal hydrides (MHx) are the most

  7. Metastable Metal Hydrides for Hydrogen Storage

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Graetz, Jason

    2012-01-01

    The possibility of using hydrogen as a reliable energy carrier for both stationary and mobile applications has gained renewed interest in recent years due to improvements in high temperature fuel cells and a reduction in hydrogen production costs. However, a number of challenges remain and new media are needed that are capable of safely storing hydrogen with high gravimetric and volumetric densities. Metal hydrides and complex metal hydrides offer some hope of overcoming these challenges; however, many of the high capacity “reversible” hydrides exhibit a large endothermic decomposition enthalpy making it difficult to release the hydrogen at low temperatures. Onmore » the other hand, the metastable hydrides are characterized by a low reaction enthalpy and a decomposition reaction that is thermodynamically favorable under ambient conditions. The rapid, low temperature hydrogen evolution rates that can be achieved with these materials offer much promise for mobile PEM fuel cell applications. However, a critical challenge exists to develop new methods to regenerate these hydrides directly from the reactants and hydrogen gas. This spotlight paper presents an overview of some of the metastable metal hydrides for hydrogen storage and a few new approaches being investigated to address the key challenges associated with these materials.« less

  8. Project Profile: Engineering a Novel High Temperature Metal Hydride...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Project Profile: Engineering a Novel High Temperature Metal Hydride Thermochemical Storage Project Profile: Engineering a Novel High Temperature Metal Hydride Thermochemical Storage ...

  9. Disposal of tritium-exposed metal hydrides

    SciTech Connect (OSTI)

    Nobile, A.; Motyka, T.

    1991-01-01

    A plan has been established for disposal of tritium-exposed metal hydrides used in Savannah River Site (SRS) tritium production or Materials Test Facility (MTF) R D operations. The recommended plan assumes that the first tritium-exposed metal hydrides will be disposed of after startup of the Solid Waste Disposal Facility (SWDF) Expansion Project in 1992, and thus the plan is consistent with the new disposal requiremkents that will be in effect for the SWDF Expansion Project. Process beds containing tritium-exposed metal hydride powder will be disposed of without removal of the powder from the bed; however, disposal of tritium-exposed metal hydride powder that has been removed from its process vessel is also addressed.

  10. Disposal of tritium-exposed metal hydrides

    SciTech Connect (OSTI)

    Nobile, A.; Motyka, T.

    1991-12-31

    A plan has been established for disposal of tritium-exposed metal hydrides used in Savannah River Site (SRS) tritium production or Materials Test Facility (MTF) R&D operations. The recommended plan assumes that the first tritium-exposed metal hydrides will be disposed of after startup of the Solid Waste Disposal Facility (SWDF) Expansion Project in 1992, and thus the plan is consistent with the new disposal requiremkents that will be in effect for the SWDF Expansion Project. Process beds containing tritium-exposed metal hydride powder will be disposed of without removal of the powder from the bed; however, disposal of tritium-exposed metal hydride powder that has been removed from its process vessel is also addressed.

  11. Liquid suspensions of reversible metal hydrides

    DOE Patents [OSTI]

    Reilly, J.J.; Grohse, E.W.; Winsche, W.E.

    1983-12-08

    The reversibility of the process M + x/2 H/sub 2/ ..-->.. MH/sub x/, where M is a metal hydride former that forms a hydride MH/sub x/ in the presence of H/sub 2/, generally used to store and recall H/sub 2/, is found to proceed under a liquid, thereby to reduce contamination, provide better temperature control and provide in situ mobility of the reactants. Thus, a slurry of particles of a metal hydride former with an inert solvent is subjected to temperature and pressure controlled atmosphere containing H/sub 2/, to store hydrogen (at high pressures) and to release (at low pressures) previously stored hydrogen. The direction of the flow of the H/sub 2/ through the liquid is dependent upon the H/sub 2/ pressure in the gas phase at a given temperature. When the former is above the equilibrium absorption pressure of the respective hydride the reaction proceeds to the right, i.e., the metal hydride is formed and hydrogen is stored in the solid particle. When the H/sub 2/ pressure in the gas phase is below the equilibrium dissociation pressure of the respective hydride the reaction proceeds to the left, the metal hydride is decomposed and hydrogen is released into the gas phase.

  12. Low density metal hydride foams

    DOE Patents [OSTI]

    Maienschein, Jon L. (Oakland, CA); Barry, Patrick E. (Pleasant Hill, CA)

    1991-01-01

    Disclosed is a low density foam having a porosity of from 0 to 98% and a density less than about 0.67 gm/cc, prepared by heating a mixture of powered lithium hydride and beryllium hydride in an inert atmosphere at a temperature ranging from about 455 to about 490 K for a period of time sufficient to cause foaming of said mixture, and cooling the foam thus produced. Also disclosed is the process of making the foam.

  13. Metal hydride fuel storage and method thereof

    DOE Patents [OSTI]

    Morse, Jeffrey D [Martinez, CA; Jankowski, Alan F [Livermore, CA; Yu, Conrad [Antioch, CA

    2009-05-05

    Disclosed herein is a metal hydride fuel storage cartridge having integrated resistive heaters that can be used in conjunction with fuel cells such as MEMS-based fuel cells. The cartridge is fabricated using micromachining methods and thin/thick film materials synthesis techniques.

  14. Metal hydride fuel storage and method thereof

    DOE Patents [OSTI]

    Morse, Jeffrey D. (Martinez, CA); Jankowski, Alan F. (Livermore, CA); Yu, Conrad (Antioch, CA)

    2006-10-17

    Disclosed herein is a metal hydride fuel storage cartridge having integrated resistive heaters that can be used in conjunction with fuel cells such as MEMS-based fuel cells. The cartridge is fabricated using micromachining methods and thin/thick film materials synthesis techniques.

  15. METAL HYDRIDE HYDROGEN COMPRESSORS: A REVIEW

    SciTech Connect (OSTI)

    Bowman Jr, Robert C; Yartys, Dr. Volodymyr A.; Lototskyy, Dr. Michael V; Pollet, Dr. B.G.

    2014-01-01

    Metal hydride (MH) thermal sorption compression is an efficient and reliable method allowing a conversion of energy from heat into a compressed hydrogen gas. The most important component of such a thermal engine the metal hydride material itself should possess several material features in order to achieve an efficient performance in the hydrogen compression. Apart from the hydrogen storage characteristics important for every solid H storage material (e.g. gravimetric and volumetric efficiency of H storage, hydrogen sorption kinetics and effective thermal conductivity), the thermodynamics of the metal-hydrogen systems is of primary importance resulting in a temperature dependence of the absorption/desorption pressures). Several specific features should be optimized to govern the performance of the MH-compressors including synchronisation of the pressure plateaus for multi-stage compressors, reduction of slope of the isotherms and hysteresis, increase of cycling stability and life time, together with challenges in system design associated with volume expansion of the metal matrix during the hydrogenation. The present review summarises numerous papers and patent literature dealing with MH hydrogen compression technology. The review considers (a) fundamental aspects of materials development with a focus on structure and phase equilibria in the metal-hydrogen systems suitable for the hydrogen compression; and (b) applied aspects, including their consideration from the applied thermodynamic viewpoint, system design features and performances of the metal hydride compressors and major applications.

  16. DOE Metal Hydride Center of Excellence

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Metal Hydride Center of Excellence - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management

  17. Steps to Commercialization: Nickel Metal Hydride Batteries | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Steps to Commercialization: Nickel Metal Hydride Batteries Steps to Commercialization: Nickel Metal Hydride Batteries October 17, 2011 - 10:42am Addthis Steps to Commercialization: Nickel Metal Hydride Batteries Matthew Loveless Matthew Loveless Data Integration Specialist, Office of Public Affairs How does it work? Through licensing and collaborative work, Energy Department-sponsored research can yield great economic benefits and help bring important new products to market. The

  18. Metal Hydride Thermal Storage: Reversible Metal Hydride Thermal Storage for High-Temperature Power Generation Systems

    SciTech Connect (OSTI)

    2011-12-05

    HEATS Project: PNNL is developing a thermal energy storage system based on a Reversible Metal Hydride Thermochemical (RMHT) system, which uses metal hydride as a heat storage material. Heat storage materials are critical to the energy storage process. In solar thermal storage systems, heat can be stored in these materials during the day and released at nightwhen the sun is not outto drive a turbine and produce electricity. In nuclear storage systems, heat can be stored in these materials at night and released to produce electricity during daytime peak-demand hours. PNNLs metal hydride material can reversibly store heat as hydrogen cycles in and out of the material. In a RHMT system, metal hydrides remain stable in high temperatures (600- 800C). A high-temperature tank in PNNLs storage system releases heat as hydrogen is absorbed, and a low-temperature tank stores the heat until it is needed. The low-cost material and simplicity of PNNLs thermal energy storage system is expected to keep costs down. The system has the potential to significantly increase energy density.

  19. Metal hydride fuel storage and method thereof

    DOE Patents [OSTI]

    Morse, Jeffrey D. (Martinez, CA); Jankowski, Alan F. (Livermore, CA); Yu, Conrad (Antioch, CA)

    2010-08-10

    An apparatus having a first substrate having (1) a cavity, (2) one or more resistive heaters, and (3) one or more coatings forming a diffusion barrier to hydrogen; a second substrate having (1) an outlet valve comprising a pressure relief structure and (2) one or more coatings forming a diffusion barrier to hydrogen, wherein said second substrate is coupled to said first substrate forming a sealed volume in said cavity; a metal hydride material contained within said cavity; and a gas distribution system formed by coupling a microfluidic interconnect to said pressure relief structure. Additional apparatuses and methods are also disclosed.

  20. Process for production of a metal hydride

    DOE Patents [OSTI]

    Allen, Nathan Tait; Butterick, III, Robert; Chin, Arthur Achhing; Millar, Dean Michael; Molzahn, David Craig

    2014-08-12

    A process for production of a metal hydride compound MH.sub.x, wherein x is one or two and M is an alkali metal, Be or Mg. The process comprises combining a compound of formula (R.sup.1O).sub.xM with aluminum, hydrogen and at least one metal selected from among titanium, zirconium, hafnium, niobium, vanadium, tantalum and iron to produce a compound of formula MH.sub.x. R.sup.1 is phenyl or phenyl substituted by at least one alkyl or alkoxy group. A mole ratio of aluminum to (R.sup.1O).sub.xM is from 0.1:1 to 1:1. The catalyst is present at a level of at least 200 ppm based on weight of aluminum.

  1. Project Profile: Engineering a Novel High Temperature Metal Hydride

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermochemical Storage | Department of Energy Project Profile: Engineering a Novel High Temperature Metal Hydride Thermochemical Storage Project Profile: Engineering a Novel High Temperature Metal Hydride Thermochemical Storage PNNL Logo Pacific Northwest National Lab (PNNL), through the Concentrating Solar Power: Efficiently Leveraging Equilibrium Mechanisms for Engineering New Thermochemical Storage (CSP: ELEMENTS) funding program, is developing a concept for high energy density

  2. Ni/metal hydride secondary element

    DOE Patents [OSTI]

    Bauerlein, Peter

    2005-04-19

    A Ni/metal hydride secondary element having a positive nickel hydroxide electrode, a negative electrode having a hydrogen storage alloy, and an alkaline electrolyte, the positive electrode, provided with a three-dimensional metallic conductive structure, also contains an aluminum compound which is soluble in the electrolyte, in addition to nickel hydroxide and cobalt oxide. The aluminum compound is aluminum hydroxide and/or aluminum oxide, and the mass of the aluminum compound which is present in the positive bulk material mixture is 0.1 to 2% by weight relative to the mass of the nickel hydroxide which is present. In combination with aluminum hydroxide or aluminum oxide, the positive electrode further contains lanthanoid oxidic compounds Y.sub.2 O.sub.3, La.sub.2 O.sub.3 and Ca(OH).sub.2, as well as mixtures of these compounds.

  3. Recent advances in metal hydrides for clean energy applications

    SciTech Connect (OSTI)

    Ronnebro, Ewa; Majzoub, Eric H.

    2013-06-01

    Metal hydrides are a fascinating class of materials that can be utilized for a surprising variety of clean energy applications, including smart solar collectors, smart windows, sensors, thermal energy storage, and batteries, in addition to their traditional application for hydrogen storage. Over the past decade, research on metal hydrides for hydrogen storage increased due to global governmental incentives and an increased focus on hydrogen storage research for polymer electrolyte membrane fuel cell operation. Tremendous progress has been made in so-called complex metal hydrides for hydrogen storage applications with the discovery of many new hydrides containing covalently bound complex anions. Many of these materials have applications beyond hydrogen storage and are being investigated for lithium-ion battery separator and anode materials. In this issue of MRS Bulletin , we present the state of the art of key evolving metal-hydride-based clean energy technologies with an outlook toward future needs.

  4. Porous metal hydride composite and preparation and uses thereof

    DOE Patents [OSTI]

    Steyert, W.A.; Olsen, C.E.

    1980-03-12

    A composite formed from large pieces of aggregate formed from (1) metal hydride (or hydride-former) powder and (2) either metal powder or plastic powder or both is prepared. The composite has large macroscopic interconnected pores (much larger than the sizes of the powders which are used) and will have a very fast heat transfer rate and low windage loss. It will be useful, for example, in heat engines, hydrogen storage devices, and refrigerator components which depend for their utility upon both a fast rate of hydriding and dehydriding. Additionally, a method of preparing the composite and a method of increasing the rates of hydriding and dehydriding of metal hydrides are also given.

  5. Porous metal hydride composite and preparation and uses thereof

    DOE Patents [OSTI]

    Steyert, William A. (Los Alamos, NM); Olsen, Clayton E. (Los Alamos, NM)

    1982-01-01

    A composite formed from large pieces of aggregate formed from (1) metal hydride (or hydride-former) powder and (2) either metal powder or plastic powder or both is prepared. The composite has large macroscopic interconnected pores (much larger than the sizes of the powders which are used) and will have a very fast heat transfer rate and low windage loss. It will be useful, for example, in heat engines, hydrogen storage devices, and refrigerator components which depend for their utility upon both a fast rate of hydriding and dehydriding. Additionally, a method of preparing the composite and a method of increasing the rates of hydriding and dehydriding of metal hydrides are also given.

  6. Metal Hydrides for High-Temperature Power Generation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ronnebro, Ewa; Whyatt, Greg A.; Powell, Michael R.; Westman, Matthew P.; Zheng, Feng; Fang, Zhigang Zak

    2015-08-10

    Metal hydrides can be utilized for hydrogen storage and for thermal energy storage (TES) applications. By using TES with solar technologies, heat can be stored from sun energy to be used later which enables continuous power generation. We are developing a TES technology based on a dual-bed metal hydride system, which has a high-temperature (HT) metal hydride operating reversibly at 600-800°C to generate heat as well as a low-temperature (LT) hydride near room temperature that is used for hydrogen storage during sun hours until there is a need to produce electricity, such as during night time, a cloudy day, ormore » during peak hours. We proceeded from selecting a high-energy density, low-cost HT-hydride based on performance characterization on gram size samples, to scale-up to kilogram quantities and design, fabrication and testing of a 1.5kWh, 200kWh/m3 bench-scale TES prototype based on a HT-bed of titanium hydride and a hydrogen gas storage instead of a LT-hydride. COMSOL Multiphysics was used to make performance predictions for cylindrical hydride beds with varying diameters and thermal conductivities. Based on experimental and modeling results, a bench-scale prototype was designed and fabricated and we successfully showed feasibility to meet or exceed all performance targets.« less

  7. Metal Hydrides for High-Temperature Power Generation

    SciTech Connect (OSTI)

    Ronnebro, Ewa; Whyatt, Greg A.; Powell, Michael R.; Westman, Matthew P.; Zheng, Feng; Fang, Zhigang Zak

    2015-08-10

    Metal hydrides can be utilized for hydrogen storage and for thermal energy storage (TES) applications. By using TES with solar technologies, heat can be stored from sun energy to be used later which enables continuous power generation. We are developing a TES technology based on a dual-bed metal hydride system, which has a high-temperature (HT) metal hydride operating reversibly at 600-800°C to generate heat as well as a low-temperature (LT) hydride near room temperature that is used for hydrogen storage during sun hours until there is a need to produce electricity, such as during night time, a cloudy day, or during peak hours. We proceeded from selecting a high-energy density, low-cost HT-hydride based on performance characterization on gram size samples, to scale-up to kilogram quantities and design, fabrication and testing of a 1.5kWh, 200kWh/m3 bench-scale TES prototype based on a HT-bed of titanium hydride and a hydrogen gas storage instead of a LT-hydride. COMSOL Multiphysics was used to make performance predictions for cylindrical hydride beds with varying diameters and thermal conductivities. Based on experimental and modeling results, a bench-scale prototype was designed and fabricated and we successfully showed feasibility to meet or exceed all performance targets.

  8. Hydridable material for the negative electrode in a nickel-metal hydride storage battery

    DOE Patents [OSTI]

    Knosp, Bernard (Neuilly-sur-Seine, FR); Bouet, Jacques (Paris, FR); Jordy, Christian (Dourdan, FR); Mimoun, Michel (Neuilly-sur-Marne, FR); Gicquel, Daniel (Lanorville, FR)

    1997-01-01

    A monophase hydridable material for the negative electrode of a nickel-metal hydride storage battery with a "Lave's phase" structure of hexagonal C14 type (MgZn.sub.2) has the general formula: Zr.sub.1-x Ti.sub.x Ni.sub.a Mn.sub.b Al.sub.c Co.sub.d V.sub.e where ##EQU1##

  9. Method for preparing hydride configurations and reactive metal surfaces

    DOE Patents [OSTI]

    Silver, G.L.

    1984-05-18

    A method for preparing reactive metal surfaces, particularly uranium surfaces is disclosed, whereby the metal is immediately reactive to hydrogen gas at room temperature and low pressure. The metal surfaces are first pretreated by exposure to an acid which forms an adherent hydride-bearing composition on the metal surface. Subsequent heating of the pretreated metal at a temperature sufficient to decompose the hydride coating in vacuum or inert gas renders the metal surface instantaneously reactive to hydrogen gas at room temperature and low pressure.

  10. AIR PASSIVATION OF METAL HYDRIDE BEDS FOR WASTE DISPOSAL

    SciTech Connect (OSTI)

    Klein, J; R. H. Hsu, R

    2007-07-02

    Metal hydride beds offer compact, safe storage of tritium. After metal hydride beds have reached the end of their useful life, the beds will replaced with new beds and the old beds prepared for disposal. One acceptance criteria for hydride bed waste disposal is that the material inside the bed not be pyrophoric. To determine the pyrophoric nature of spent metal hydride beds, controlled air ingress tests were performed. A simple gas handling manifold fitted with pressure transducers and a calibrated volume were used to introduce controlled quantities of air into a metal hydride bed and the bed temperature rise monitored for reactivity with the air. A desorbed, 4.4 kg titanium prototype hydride storage vessel (HSV) produced a 4.4 C internal temperature rise upon the first air exposure cycle and a 0.1 C temperature rise upon a second air exposure. A total of 346 scc air was consumed by the bed (0.08 scc per gram Ti). A desorbed, 9.66 kg LaNi{sub 4.25}Al{sub 0.75} prototype storage bed experienced larger temperature rises over successive cycles of air ingress and evacuation. The cycles were performed over a period of days with the bed effectively passivated after the 12th cycle. Nine to ten STP-L of air reacted with the bed producing both oxidized metal and water.

  11. Influence of uranium hydride oxidation on uranium metal behaviour

    SciTech Connect (OSTI)

    Patel, N.; Hambley, D.; Clarke, S.A.; Simpson, K.

    2013-07-01

    This work addresses concerns that the rapid, exothermic oxidation of active uranium hydride in air could stimulate an exothermic reaction (burning) involving any adjacent uranium metal, so as to increase the potential hazard arising from a hydride reaction. The effect of the thermal reaction of active uranium hydride, especially in contact with uranium metal, does not increase in proportion with hydride mass, particularly when considering large quantities of hydride. Whether uranium metal continues to burn in the long term is a function of the uranium metal and its surroundings. The source of the initial heat input to the uranium, if sufficient to cause ignition, is not important. Sustained burning of uranium requires the rate of heat generation to be sufficient to offset the total rate of heat loss so as to maintain an elevated temperature. For dense uranium, this is very difficult to achieve in naturally occurring circumstances. Areas of the uranium surface can lose heat but not generate heat. Heat can be lost by conduction, through contact with other materials, and by convection and radiation, e.g. from areas where the uranium surface is covered with a layer of oxidised material, such as burned-out hydride or from fuel cladding. These rates of heat loss are highly significant in relation to the rate of heat generation by sustained oxidation of uranium in air. Finite volume modelling has been used to examine the behaviour of a magnesium-clad uranium metal fuel element within a bottle surrounded by other un-bottled fuel elements. In the event that the bottle is breached, suddenly, in air, it can be concluded that the bulk uranium metal oxidation reaction will not reach a self-sustaining level and the mass of uranium oxidised will likely to be small in relation to mass of uranium hydride oxidised. (authors)

  12. Composite Materials for Hazard Mitigation of Reactive Metal Hydrides.

    SciTech Connect (OSTI)

    Pratt, Joseph William; Cordaro, Joseph Gabriel; Sartor, George B.; Dedrick, Daniel E.; Reeder, Craig L.

    2012-02-01

    In an attempt to mitigate the hazards associated with storing large quantities of reactive metal hydrides, polymer composite materials were synthesized and tested under simulated usage and accident conditions. The composites were made by polymerizing vinyl monomers using free-radical polymerization chemistry, in the presence of the metal hydride. Composites with vinyl-containing siloxane oligomers were also polymerized with and without added styrene and divinyl benzene. Hydrogen capacity measurements revealed that addition of the polymer to the metal hydride reduced the inherent hydrogen storage capacity of the material. The composites were found to be initially effective at reducing the amount of heat released during oxidation. However, upon cycling the composites, the mitigating behavior was lost. While the polymer composites we investigated have mitigating potential and are physically robust, they undergo a chemical change upon cycling that makes them subsequently ineffective at mitigating heat release upon oxidation of the metal hydride. Acknowledgements The authors would like to thank the following people who participated in this project: Ned Stetson (U.S. Department of Energy) for sponsorship and support of the project. Ken Stewart (Sandia) for building the flow-through calorimeter and cycling test stations. Isidro Ruvalcaba, Jr. (Sandia) for qualitative experiments on the interaction of sodium alanate with water. Terry Johnson (Sandia) for sharing his expertise and knowledge of metal hydrides, and sodium alanate in particular. Marcina Moreno (Sandia) for programmatic assistance. John Khalil (United Technologies Research Corp) for insight into the hazards of reactive metal hydrides and real-world accident scenario experiments. Summary In an attempt to mitigate and/or manage hazards associated with storing bulk quantities of reactive metal hydrides, polymer composite materials (a mixture of a mitigating polymer and a metal hydride) were synthesized and tested under simulated usage and accident conditions. Mitigating the hazards associated with reactive metal hydrides during an accident while finding a way to keep the original capability of the active material intact during normal use has been the focus of this work. These composites were made by polymerizing vinyl monomers using free-radical polymerization chemistry, in the presence of the metal hydride, in this case a prepared sodium alanate (chosen as a representative reactive metal hydride). It was found that the polymerization of styrene and divinyl benzene could be initiated using AIBN in toluene at 70 degC. The resulting composite materials can be either hard or brittle solids depending on the cross-linking density. Thermal decomposition of these styrene-based composite materials is lower than neat polystyrene indicating that the chemical nature of the polymer is affected by the formation of the composite. The char-forming nature of cross-linked polystyrene is low and therefore, not an ideal polymer for hazard mitigation. To obtain composite materials containing a polymer with higher char-forming potential, siloxane-based monomers were investigated. Four vinyl-containing siloxane oligomers were polymerized with and without added styrene and divinyl benzene. Like the styrene materials, these composite materials exhibited thermal decomposition behavior significantly different than the neat polymers. Specifically, the thermal decomposition temperature was shifted approximately 100 degC lower than the neat polymer signifying a major chemical change to the polymer network. Thermal analysis of the cycled samples was performed on the siloxane-based composite materials. It was found that after 30 cycles the siloxane-containing polymer composite material has similar TGA/DSC-MS traces as the virgin composite material indicating that the polymer is physically intact upon cycling. Hydrogen capacity measurements revealed that addition of the polymer to the metal hydride in the form of a composite material reduced the inherent hydrogen storage capacity of the material. This

  13. Ab-initio study of transition metal hydrides

    SciTech Connect (OSTI)

    Sharma, Ramesh; Shukla, Seema Dwivedi, Shalini Sharma, Yamini

    2014-04-24

    We have performed ab initio self consistent calculations based on Full potential linearized augmented plane wave (FP-LAPW) method to investigate the optical and thermal properties of yttrium hydrides. From the band structure and density of states, the optical absorption spectra and specific heats have been calculated. The band structure of Yttrium metal changes dramatically due to hybridization of Y sp orbitals with H s orbitals and there is a net charge transfer from metal to hydrogen site. The electrical resistivity and specific heats of yttrium hydrides are lowered but the thermal conductivity is slightly enhanced due to increase in scattering from hydrogen sites.

  14. Process of forming a sol-gel/metal hydride composite

    DOE Patents [OSTI]

    Congdon, James W. (Aiken, SC)

    2009-03-17

    An external gelation process is described which produces granules of metal hydride particles contained within a sol-gel matrix. The resulting granules are dimensionally stable and are useful for applications such as hydrogen separation and hydrogen purification. An additional coating technique for strengthening the granules is also provided.

  15. Cascades for hydrogen isotope separation using metal hydrides

    SciTech Connect (OSTI)

    Hill, F.B.; Grzetic, V.

    1982-01-01

    Designs are presented for continuous countercurrent hydrogen isotope separation cascades based on the use of metal hydrides. The cascades are made up of pressure swing adsorption (PSA) or temperature swing adsorption (TSA) stages. The designs were evolved from consideration of previously conducted studies of the separation performance of four types of PSA and TSA processes.

  16. Designation of Sites for Remedial Action - Metal Hydrides, Beverly,

    Office of Legacy Management (LM)

    T: Designation of Sites for Remedial Action - Metal Hydrides, Beverly, MA; Bridgeport Brass, Adrian, MI and Seymour, Chicago, IL CT; National Guard Armory, 0: Joe LaGrone, Manager Oak Ridge Operations Office Based on the attached radiological survey data (Attachments 1 through 3) and an appropriate authority review, the following properties are being authorized for remedial action. It should be noted that the attached survey data are for designation purposes only and that Bechtel National, Inc.

  17. Diffusional exchange of isotopes in a metal hydride sphere.

    SciTech Connect (OSTI)

    Wolfer, Wilhelm G.; Hamilton, John C.; James, Scott Carlton

    2011-04-01

    This report describes the Spherical Particle Exchange Model (SPEM), which simulates exchange of one hydrogen isotope by another hydrogen isotope in a spherical metal hydride particle. This is one of the fundamental physical processes during isotope exchange in a bed of spherical metal particles and is thus one of the key components in any comprehensive physics-based model of exchange. There are two important physical processes in the model. One is the entropy of mixing between the two isotopes; the entropy of mixing is increased by having both isotopes randomly placed at interstitial sites on the lattice and thus impedes the exchange process. The other physical process is the elastic interaction between isotope atoms on the lattice. The elastic interaction is the cause for {beta}-phase formation and is independent of the isotope species. In this report the coupled diffusion equations for two isotopes in the {beta}-phase hydride are solved. A key concept is that the diffusion of one isotope depends not only on its concentration gradient, but also on the concentration gradient of the other isotope. Diffusion rate constants and the chemical potentials for deuterium and hydrogen in the {beta}-phase hydride are reviewed because these quantities are essential for an accurate model of the diffusion process. Finally, a summary of some of the predictions from the SPEM model are provided.

  18. Project Profile: Low-Cost Metal Hydride Thermal Energy Storage System |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Metal Hydride Thermal Energy Storage System Project Profile: Low-Cost Metal Hydride Thermal Energy Storage System Savannah River National Laboratory logo The Savannah River National Laboratory (SRNL), under the National Laboratory R&D competitive funding opportunity, is collaborating with Curtin University (CU) to evaluate new metal hydride materials for thermal energy storage (TES) that meet the SunShot cost and performance targets for TES systems. Approach

  19. Mathematical modeling of the nickel/metal hydride battery system

    SciTech Connect (OSTI)

    Paxton, B K

    1995-09-01

    A group of compounds referred to as metal hydrides, when used as electrode materials, is a less toxic alternative to the cadmium hydroxide electrode found in nickel/cadmium secondary battery systems. For this and other reasons, the nickel/metal hydride battery system is becoming a popular rechargeable battery for electric vehicle and consumer electronics applications. A model of this battery system is presented. Specifically the metal hydride material, LaNi{sub 5}H{sub 6}, is chosen for investigation due to the wealth of information available in the literature on this compound. The model results are compared to experiments found in the literature. Fundamental analyses as well as engineering optimizations are performed from the results of the battery model. In order to examine diffusion limitations in the nickel oxide electrode, a ``pseudo 2-D model`` is developed. This model allows for the theoretical examination of the effects of a diffusion coefficient that is a function of the state of charge of the active material. It is found using present data from the literature that diffusion in the solid phase is usually not an important limitation in the nickel oxide electrode. This finding is contrary to the conclusions reached by other authors. Although diffusion in the nickel oxide active material is treated rigorously with the pseudo 2-D model, a general methodology is presented for determining the best constant diffusion coefficient to use in a standard one-dimensional battery model. The diffusion coefficients determined by this method are shown to be able to partially capture the behavior that results from a diffusion coefficient that varies with the state of charge of the active material.

  20. ACCEPTABILITY ENVELOPE FOR METAL HYDRIDE-BASED HYDROGEN STORAGE SYSTEMS

    SciTech Connect (OSTI)

    Hardy, B.; Corgnale, C.; Tamburello, D.; Garrison, S.; Anton, D.

    2011-07-18

    The design and evaluation of media based hydrogen storage systems requires the use of detailed numerical models and experimental studies, with significant amount of time and monetary investment. Thus a scoping tool, referred to as the Acceptability Envelope, was developed to screen preliminary candidate media and storage vessel designs, identifying the range of chemical, physical and geometrical parameters for the coupled media and storage vessel system that allow it to meet performance targets. The model which underpins the analysis allows simplifying the storage system, thus resulting in one input-one output scheme, by grouping of selected quantities. Two cases have been analyzed and results are presented here. In the first application the DOE technical targets (Year 2010, Year 2015 and Ultimate) are used to determine the range of parameters required for the metal hydride media and storage vessel. In the second case the most promising metal hydrides available are compared, highlighting the potential of storage systems, utilizing them, to achieve 40% of the 2010 DOE technical target. Results show that systems based on Li-Mg media have the best potential to attain these performance targets.

  1. Uranium metal reactions with hydrogen and water vapour and the reactivity of the uranium hydride produced

    SciTech Connect (OSTI)

    Godfrey, H.; Broan, C.; Goddard, D.; Hodge, N.; Woodhouse, G.; Diggle, A.; Orr, R.

    2013-07-01

    Within the nuclear industry, metallic uranium has been used as a fuel. If this metal is stored in a hydrogen rich environment then the uranium metal can react with the hydrogen to form uranium hydride which can be pyrophoric when exposed to air. The UK National Nuclear Laboratory has been carrying out a programme of research for Sellafield Limited to investigate the conditions required for the formation and persistence of uranium hydride and the reactivity of the material formed. The experimental results presented here have described new results characterising uranium hydride formed from bulk uranium at 50 and 160 C. degrees and measurements of the hydrolysis kinetics of these materials in liquid water. It has been shown that there is an increase in the proportion of alpha-uranium hydride in material formed at lower temperatures and that there is an increase in the rate of reaction with water of uranium hydride formed at lower temperatures. This may at least in part be attributable to a difference in the reaction rate between alpha and beta-uranium hydride. A striking observation is the strong dependence of the hydrolysis reaction rate on the temperature of preparation of the uranium hydride. For example, the reaction rate of uranium hydride prepared at 50 C. degrees was over ten times higher than that prepared at 160 C. degrees at 20% extent of reaction. The decrease in reaction rate with the extent of reaction also depended on the temperature of uranium hydride preparation.

  2. Hydrogen storage material and process using graphite additive with metal-doped complex hydrides

    DOE Patents [OSTI]

    Zidan, Ragaiy (Aiken, SC); Ritter, James A. (Lexington, SC); Ebner, Armin D. (Lexington, SC); Wang, Jun (Columbia, SC); Holland, Charles E. (Cayce, SC)

    2008-06-10

    A hydrogen storage material having improved hydrogen absorbtion and desorption kinetics is provided by adding graphite to a complex hydride such as a metal-doped alanate, i.e., NaAlH.sub.4. The incorporation of graphite into the complex hydride significantly enhances the rate of hydrogen absorbtion and desorption and lowers the desorption temperature needed to release stored hydrogen.

  3. Final report for the DOE Metal Hydride Center of Excellence.

    SciTech Connect (OSTI)

    Keller, Jay O.; Klebanoff, Leonard E.

    2012-01-01

    This report summarizes the R&D activities within the U.S. Department of Energy Metal Hydride Center of Excellence (MHCoE) from March 2005 to June 2010. The purpose of the MHCoE has been to conduct highly collaborative and multi-disciplinary applied R&D to develop new reversible hydrogen storage materials that meet or exceed DOE 2010 and 2015 system goals for hydrogen storage materials. The MHCoE combines three broad areas: mechanisms and modeling (which provide a theoretically driven basis for pursuing new materials), materials development (in which new materials are synthesized and characterized) and system design and engineering (which allow these new materials to be realized as practical automotive hydrogen storage systems). This Final Report summarizes the organization and execution of the 5-year research program to develop practical hydrogen storage materials for light duty vehicles. Major results from the MHCoE are summarized, along with suggestions for future research areas.

  4. Advanced Metal-Hydrides-Based Thermal Battery: A New Generation of High Density Thermal Battery Based on Advanced Metal Hydrides

    SciTech Connect (OSTI)

    2011-12-01

    HEATS Project: The University of Utah is developing a compact hot-and-cold thermal battery using advanced metal hydrides that could offer efficient climate control system for EVs. The teams innovative designs of heating and cooling systems for EVs with high energy density, low-cost thermal batteries could significantly reduce the weight and eliminate the space constraint in automobiles. The thermal battery can be charged by plugging it into an electrical outlet while charging the electric battery and it produces heat and cold through a heat exchanger when discharging. The ultimate goal of the project is a climate-controlling thermal battery that can last up to 5,000 charge and discharge cycles while substantially increasing the driving range of EVs, thus reducing the drain on electric batteries.

  5. Final Report for the DOE Metal Hydride Center of Excellence | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Metal Hydride Center of Excellence Final Report for the DOE Metal Hydride Center of Excellence This technical report describes the activities carried out, key accomplishments, and recommendations from the DOE's Chemical Hydrogen Storage Center of Excellence, led by Los Alamos National Laboratory with Pacific Northwest National Laboratory from 2005 through 2010. The center's focus was the development of advanced chemical hydrogen storage materials that had the potential to meet the

  6. Synthesis and characterization of metal hydride electrodes. Interim report

    SciTech Connect (OSTI)

    McBreen, J.; Reilly, J.J.

    1995-10-01

    The objective of this project is to elucidate the compositional and structural parameters that affect the thermodynamics, kinetics and stability of alloy hydride electrodes and to use this information in the development of new high capacity long life hydride electrodes for rechargeable batteries. The work focuses on the development of AB{sub 5} alloys and the application of in situ methods, at NSLS, such as x-ray absorption (XAS), to elucidate the role of the alloying elements in hydrogen storage and corrosion inhibition. The most significant results to date are: The decay of electrode capacity on cycling was directly related to alloy corrosion. The rate of corrosion depended in part on both the alloy composition and the partial molar volume of hydrogen, V{sub H}. The corrosion rate depended on the composition of the A component in AB{sub 5} (LaNi{sub 5} type) alloys. Partial substitution of La with Ce in AB{sub 5} alloys substantially inhibits electrode corrosion on cycling. Recent results indicate that Co also greatly inhibits electrode corrosion, possibly by minimizing V{sub H}. The AB{sub 5} alloys investigated included LaNi{sub 5}, ternary alloys (e.g. LaN{sub 4.8}Sn{sub 0.2} and La{sub 0.8}Ce{sub 0.2}Ni{sub 5}), alloys with various substitutions for both La and Ni (e.g. La{sub 0.8}Ce{sub 0.2}Ni{sub 4.8}Sn{sub 0.2}) and mischmetal (Mm) alloys of the type normally used in batteries, such as MmB{sub 5} (B = Ni{sub 3.55}Mn{sub 0.4}A1{sub 0.3}Co{sub 0.75}). A major effort was devoted to the effects of La substitution in the A component. Both in situ and ex situ XAS measurements are used to study the electronic effects that occur on the addition of various metal substitutions and on the ingress of hydrogen.

  7. Materials Down-selection Decisions Made within the DOE Metal Hydride Center of Excellence (MHCoE) - September-October 2007

    Fuel Cell Technologies Publication and Product Library (EERE)

    Reports on which hydrogen storage materials offer potential for further research as decided by DOE's Metal Hydride Center of Excellence.

  8. Materials Down-selection Decisions Made within the DOE Metal Hydride Center of Excellence (MHCoE) - September-October 2007

    SciTech Connect (OSTI)

    Klebanoff, Lennie

    2007-09-01

    Reports on which hydrogen storage materials offer potential for further research as decided by DOE's Metal Hydride Center of Excellence.

  9. Method and composition in which metal hydride particles are embedded in a silica network

    DOE Patents [OSTI]

    Heung, Leung K. (Aiken, SC)

    1999-01-01

    A silica embedded metal hydride composition and a method for making such a composition. The composition is made via the following process: A quantity of fumed silica is blended with water to make a paste. After adding metal hydride particles, the paste is dried to form a solid. According to one embodiment of the invention, the solid is ground into granules for use of the product in hydrogen storage. Alternatively, the paste can be molded into plates or cylinders and then dried for use of the product as a hydrogen filter. Where mechanical strength is required, the paste can be impregnated in a porous substrate or wire network.

  10. First Principles Studies of Phase Stability and Reaction Dynamics in Complex Metal Hydrides

    SciTech Connect (OSTI)

    Chou, Mei-Yin

    2014-09-29

    Complex metal hydrides are believed to be one of the most promising materials for developing hydrogen storage systems that can operate under desirable conditions. At the same time, these are also a class of materials that exhibit intriguing properties. We have used state-of-the-art computational techniques to study the fundamental properties of these materials.

  11. Metal hydrides as electrode/catalyst materials for oxygen evolution/reduction in electrochemical devices

    DOE Patents [OSTI]

    Bugga, Ratnakumar V. (Arcadia, CA); Halpert, Gerald (Pasadena, CA); Fultz, Brent (Pasadena, CA); Witham, Charles K. (Pasadena, CA); Bowman, Robert C. (La Mesa, CA); Hightower, Adrian (Whittier, CA)

    1997-01-01

    An at least ternary metal alloy of the formula, AB.sub.(5-Y)X(.sub.y), is claimed. In this formula, A is selected from the rare earth elements, B is selected from the elements of groups 8, 9, and 10 of the periodic table of the elements, and X includes at least one of the following: antimony, arsenic, and bismuth. Ternary or higher-order substitutions, to the base AB.sub.5 alloys, that form strong kinetic interactions with the predominant metals in the base metal hydride are used to form metal alloys with high structural integrity after multiple cycles of hydrogen sorption.

  12. Effect of delivery condition on desorption rate of ZrCo metal hydride bed for fusion fuel cycle

    SciTech Connect (OSTI)

    Kang, H.G.; Yun, S.H.; Chung, D.; Oh, Y.H.; Chang, M.H.; Cho, S.; Chung, H.; Song, K.M.

    2015-03-15

    For the safety of fusion fuel cycle, hydrogen isotope gases including tritium are stored as metal hydride form. To satisfy fueling requirement of fusion machine, rapid delivery from metal hydride bed is one of major factors for the development of tritium storage and delivery system. Desorption from metal hydride depends on the operation scenario by pressure and temperature control of the bed. The effect of operation scenario and pump performance on desorption rate of metal hydride bed was experimentally investigated using ZrCo bed. The results showed that the condition of pre-heating scenario before actual delivery of gas affected the delivery performance. Different pumps were connected to desorption line from bed and the effect of pump capacity on desorption rate were also found to be significant. (authors)

  13. In-bed accountability of tritium in production scale metal hydride storage beds

    SciTech Connect (OSTI)

    Klein, J.E.

    1995-10-01

    An `in-bed accountability` (IBA) flowing gas calorimetric measurement method has been developed and implemented to eliminate the need to remove tritium from production scale metal hydride storage beds for inventory measurement purposes. Six-point tritium IBA calibration curves have been completed for two, 390 gram tritium metal hydride storage beds. The calibration curves for the two tritium beds are similar to those obtained from the `cold` test program. Tritium inventory errors at the 95 percent confidence level ranged from {+-} 7.3 to 8.6 grams for the cold test results compared to {+-} 4.2 to 7.5 grams obtained for the two tritium calibrated beds. 5 refs., 4 figs., 1 tab.

  14. In-bed measurement of tritium loading in process metal hydride beds

    SciTech Connect (OSTI)

    Nobile, A.

    1988-01-01

    The Replacement Tritium Facility at Savannah River Plant will make extensive use of metal hydride technology for the storage, pumping, isotopic separation, and compression of hydrogen isotopes. Two options were considered for routine accountability of tritium stored in metal hydride beds. One option was to use standard P-V-T-mass spectrometry techniques after desorption of storage beds to tanks of known volume. The second option was to develop a technique for direct measurement of bed loading. It was thought that such a technique would be more rapid and would account for heel, although some accuracy would be lost.The static nitrogen and flowing nitrogen methods were considered for this option. The flowing nitrogen method was eventually selected because it was insensitive to bed physical properties and isotopic gas composition, as well as being more accurate and easier to automate.

  15. Method for preparing hydride configurations and reactive metal surfaces

    DOE Patents [OSTI]

    Silver, Gary L. (Centerville, OH)

    1988-08-16

    A method for preparing highly hydrogen-reactive surfaces on metals which normally require substantial heating, high pressures, or an extended induction period, which involves pretreatment of said surfaces with either a non-oxidizing acid or hydrogen gas to form a hydrogen-bearing coating on said surfaces, and subsequently heating said coated metal in the absence of moisture and oxygen for a period sufficient to decompose said coating and cooling said metal to room temperature. Surfaces so treated will react almost instantaneously with hydrogen gas at room temperature and low pressure. The method is particularly applicable to uranium, thorium, and lanthanide metals.

  16. Applications of nuclear reaction analysis to metal hydride film characterization at the GEND 200 KeV accelerator facility

    SciTech Connect (OSTI)

    Malbrough, D.J.; Becker, R.H.

    1985-01-01

    Nuclear reaction analysis (NRA) is a quantitative analytical technique that usually involves the use of MeV ion beams and resonant nuclear reactions to non-destructively probe materials for elemental content and depth profiles. Low energy, non-resonant nuclear reactions can also be exploited for NRA and procedures have been developed for using the GEND 200-KeV accelerator to characterize neutron generator components by that technique. The procedures involve the detection and analysis of fusion reaction products generated by the interactions of deuteron beams with light elements in metal hydride films. A description of the accelerator system is presented along with some of the unique NRA procedures that have recently been developed for its use. The system is used to measure neutron output efficiencies of metal deuterides and tritides by the associated particle technique (APT) and accurate neutron yield measurements have been made for a number of materials for which data was formerly not available.

  17. OPTIMIZATION OF INTERNAL HEAT EXCHANGERS FOR HYDROGEN STORAGE TANKS UTILIZING METAL HYDRIDES

    SciTech Connect (OSTI)

    Garrison, S.; Tamburello, D.; Hardy, B.; Anton, D.; Gorbounov, M.; Cognale, C.; van Hassel, B.; Mosher, D.

    2011-07-14

    Two detailed, unit-cell models, a transverse fin design and a longitudinal fin design, of a combined hydride bed and heat exchanger are developed in COMSOL{reg_sign} Multiphysics incorporating and accounting for heat transfer and reaction kinetic limitations. MatLab{reg_sign} scripts for autonomous model generation are developed and incorporated into (1) a grid-based and (2) a systematic optimization routine based on the Nelder-Mead downhill simplex method to determine the geometrical parameters that lead to the optimal structure for each fin design that maximizes the hydrogen stored within the hydride. The optimal designs for both the transverse and longitudinal fin designs point toward closely-spaced, small cooling fluid tubes. Under the hydrogen feed conditions studied (50 bar), a 25 times improvement or better in the hydrogen storage kinetics will be required to simultaneously meet the Department of Energy technical targets for gravimetric capacity and fill time. These models and methodology can be rapidly applied to other hydrogen storage materials, such as other metal hydrides or to cryoadsorbents, in future work.

  18. LaNi{sub 5}-based metal hydride electrode in Ni-MH rechargeable cells

    DOE Patents [OSTI]

    Bugga, R.V.; Fultz, B.; Bowman, R.; Surampudi, S.R.; Witham, C.K.; Hightower, A.

    1999-03-30

    An at least ternary metal alloy of the formula AB{sub (Z-Y)}X{sub (Y)} is disclosed. In this formula, A is selected from the rare earth elements, B is selected from the elements of Groups 8, 9, and 10 of the Periodic Table of the Elements, and X includes at least one of the following: antimony, arsenic, germanium, tin or bismuth. Z is greater than or equal to 4.8 and less than or equal to 6.0. Y is greater than 0 and less than 1. Ternary or higher-order substitutions to the base AB{sub 5} alloys that form strong kinetic interactions with the predominant metals in the base metal hydride are used to form metal alloys with high structural integrity after multiple cycles of hydrogen sorption. 16 figs.

  19. Non-stoichiometric AB5 alloys for metal hydride electrodes

    DOE Patents [OSTI]

    Reilly, James J. (Bellport, NY); Adzic, Gordana D. (Setauket, NY); Johnson, John R. (Calverton, NY); Vogt, Thomas (Cold Spring Harbor, NY); McBreen, James (Bellport, NY)

    2001-01-01

    The present invention provides a non-stoichiometric alloy comprising a composition having the formula AB.sub.5+X an atomic ratio wherein A is selected from the group consisting of the rare earth metals, yttrium, mischmetal, or a combination thereof; B is nickel and tin, or nickel and tin and at least a third element selected from the group consisting of the elements in group IVA of the periodic table, aluminum, manganese, iron, cobalt, copper, antimony or a combination thereof; X is greater than 0 and less than or equal to about 2.0; and wherein at least one substituted A site is occupied by at least one of the B elements. An electrode incorporating said alloy and an electrochemical cell incorporating said electrode are also described.

  20. First-Principles Modeling of Hydrogen Storage in Metal Hydride Systems

    SciTech Connect (OSTI)

    J. Karl Johnson

    2011-05-20

    The objective of this project is to complement experimental efforts of MHoCE partners by using state-of-the-art theory and modeling to study the structure, thermodynamics, and kinetics of hydrogen storage materials. Specific goals include prediction of the heats of formation and other thermodynamic properties of alloys from first principles methods, identification of new alloys that can be tested experimentally, calculation of surface and energetic properties of nanoparticles, and calculation of kinetics involved with hydrogenation and dehydrogenation processes. Discovery of new metal hydrides with enhanced properties compared with existing materials is a critical need for the Metal Hydride Center of Excellence. New materials discovery can be aided by the use of first principles (ab initio) computational modeling in two ways: (1) The properties, including mechanisms, of existing materials can be better elucidated through a combined modeling/experimental approach. (2) The thermodynamic properties of novel materials that have not been made can, in many cases, be quickly screened with ab initio methods. We have used state-of-the-art computational techniques to explore millions of possible reaction conditions consisting of different element spaces, compositions, and temperatures. We have identified potentially promising single- and multi-step reactions that can be explored experimentally.

  1. Heat exchanger selection and design analyses for metal hydride heat pump systems

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mazzucco, Andrea; Voskuilen, Tyler G.; Waters, Essene L.; Pourpoint, Timothee L.; Rokni, Masoud

    2016-01-29

    This paper presents a design analysis for the development of highly efficient heat exchangers within stationary metal hydride heat pumps. The design constraints and selected performance criteria are applied to three representative heat exchangers. The proposed thermal model can be applied to select the most efficient heat exchanger design and provides outcomes generally valid in a pre-design stage. Heat transfer effectiveness is the principal performance parameter guiding the selection analysis, the results of which appear to be mildly (up to 13%) affected by the specific Nusselt correlation used. The thermo-physical properties of the heat transfer medium and geometrical parameters aremore » varied in the sensitivity analysis, suggesting that the length of independent tubes is the physical parameter that influences the performance of the heat exchangers the most. The practical operative regions for each heat exchanger are identified by finding the conditions over which the heat removal from the solid bed enables a complete and continuous hydriding reaction. The most efficient solution is a design example that achieves the target effectiveness of 95%.« less

  2. Executive Summaries for the Hydrogen Storage Materials Center of Excellence - Chemical Hydrogen Storage CoE, Hydrogen Sorption CoE, and Metal Hydride CoE

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Executive Summaries for the Hydrogen Storage Materials Centers of Excellence Chemical Hydrogen Storage CoE, Hydrogen Sorption CoE, and Metal Hydride CoE Period of Performance: 2005-2010 Fuel Cell Technologies Program Office of Energy Efficiency and Renewable Energy U. S. Department of Energy April 2012 2 3 Primary Authors: Chemical Hydrogen Storage (CHSCoE): Kevin Ott, Los Alamos National Laboratory Hydrogen Sorption (HSCoE): Lin Simpson, National Renewable Energy Laboratory Metal Hydride

  3. Hydrogen, lithium, and lithium hydride production

    DOE Patents [OSTI]

    Brown, Sam W; Spencer, Larry S; Phillips, Michael R; Powell, G. Louis; Campbell, Peggy J

    2014-03-25

    A method of producing high purity lithium metal is provided, where gaseous-phase lithium metal is extracted from lithium hydride and condensed to form solid high purity lithium metal. The high purity lithium metal may be hydrided to provide high purity lithium hydride.

  4. Discovery of Novel Complex Metal Hydrides for Hydrogen Storage through Molecular Modeling and Combinatorial Methods

    SciTech Connect (OSTI)

    Lesch, David A; Adriaan Sachtler, J.W. J.; Low, John J; Jensen, Craig M; Ozolins, Vidvuds; Siegel, Don

    2011-02-14

    UOP LLC, a Honeywell Company, Ford Motor Company, and Striatus, Inc., collaborated with Professor Craig Jensen of the University of Hawaii and Professor Vidvuds Ozolins of University of California, Los Angeles on a multi-year cost-shared program to discover novel complex metal hydrides for hydrogen storage. This innovative program combined sophisticated molecular modeling with high throughput combinatorial experiments to maximize the probability of identifying commercially relevant, economical hydrogen storage materials with broad application. A set of tools was developed to pursue the medium throughput (MT) and high throughput (HT) combinatorial exploratory investigation of novel complex metal hydrides for hydrogen storage. The assay programs consisted of monitoring hydrogen evolution as a function of temperature. This project also incorporated theoretical methods to help select candidate materials families for testing. The Virtual High Throughput Screening served as a virtual laboratory, calculating structures and their properties. First Principles calculations were applied to various systems to examine hydrogen storage reaction pathways and the associated thermodynamics. The experimental program began with the validation of the MT assay tool with NaAlH4/0.02 mole Ti, the state of the art hydrogen storage system given by decomposition of sodium alanate to sodium hydride, aluminum metal, and hydrogen. Once certified, a combinatorial 21-point study of the NaAlH4 ?? LiAlH4 ??Mg(AlH4)2 phase diagram was investigated with the MT assay. Stability proved to be a problem as many of the materials decomposed during synthesis, altering the expected assay results. This resulted in repeating the entire experiment with a mild milling approach, which only temporarily increased capacity. NaAlH4 was the best performer in both studies and no new mixed alanates were observed, a result consistent with the VHTS. Powder XRD suggested that the reverse reaction, the regeneration of the alanate from alkali hydride, Al and hydrogen, was hampering reversibility. The reverse reaction was then studied for the same phase diagram, starting with LiH, NaH, and MgH2, and Al. The study was extended to phase diagrams including KH and CaH2 as well. The observed hydrogen storage capacity in the Al hexahydrides was less than 4 wt. %, well short of DOE targets. The HT assay came on line and after certification with studies on NaAlH4, was first applied to the LiNH2 - LiBH4 - MgH2 phase diagram. The 60-point study elucidated trends within the system locating an optimum material of 0.6 LiNH2 ?? 0.3 MgH2 ?? 0.1 LiBH4 that stored about 4 wt. % H2 reversibly and operated below 220 °C. Also present was the phase Li4(NH2)3BH4, which had been discovered in the LiNH2 -LiBH4 system. This new ternary formulation performed much better than the well-known 2 LiNH2 ?? MgH2 system by 50 °C in the HT assay. The Li4(NH2)3BH4 is a low melting ionic liquid under our test conditions and facilitates the phase transformations required in the hydrogen storage reaction, which no longer relies on a higher energy solid state reaction pathway. Further study showed that the 0.6 LiNH2 ?? 0.3 MgH2 ?? 0.1 LiBH4 formulation was very stable with respect to ammonia and diborane desorption, the observed desorption was from hydrogen. This result could not have been anticipated and was made possible by the efficiency of HT combinatorial methods. Investigation of the analogous LiNH2 ?? LiBH4 ?? CaH2 phase diagram revealed new reversible hydrogen storage materials 0.625 LiBH4 + 0.375 CaH2 and 0.375 LiNH2 + 0.25 LiBH4 + 0.375 CaH2 operating at 1 wt. % reversible hydrogen below 175 °C. Powder x-ray diffraction revealed a new structure for the spent materials which had not been previously observed. While the storage capacity was not impressive, an important aspect is that it boron appears to participate in a low temperature reversible reaction. The last major area of study also focused

  5. LaNi.sub.5 is-based metal hydride electrode in Ni-MH rechargeable cells

    DOE Patents [OSTI]

    Bugga, Ratnakumar V. (Arcadia, CA); Fultz, Brent (Pasadena, CA); Bowman, Robert (La Mesa, CA); Surampudi, Subra Rao (Glendora, CA); Witham, Charles K. (Pasadena, CA); Hightower, Adrian (Pasadena, CA)

    1999-01-01

    An at least ternary metal alloy of the formula AB.sub.(Z-Y) X.sub.(Y) is disclosed. In this formula, A is selected from the rare earth elements, B is selected from the elements of Groups 8, 9, and 10 of the Periodic Table of the Elements, and X includes at least one of the following: antimony, arsenic, germanium, tin or bismuth. Z is greater than or equal to 4.8 and less than or equal to 6.0. Y is greater than 0 and less than 1. Ternary or higher-order substitutions to the base AB.sub.5 alloys that form strong kinetic interactions with the predominant metals in the base metal hydride are used to form metal alloys with high structural integrity after multiple cycles of hydrogen sorption.

  6. Gas atomization processing of tin and silicon modified LaNi{sub 5} for nickel-metal hydride battery applications

    SciTech Connect (OSTI)

    Ting, J.

    1999-02-12

    Numerous researchers have studied the relevant material properties of so-called AB{sub 5} alloys for battery applications. These studies involved LaNi{sub 5} substituted alloys which were prepared using conventional cast and crush alloying techniques. While valuable to the understanding of metal hydride effects, the previous work nearly ignored the potential for alternative direct powder production methods, like high pressure gas atomization (HPGA). Thus, there is a need to understand the relationship between gas atomization processes, powder particle solidification phases, and hydrogen absorption properties of ultra fine (< 25 {micro}m) atomized powders with high surface area for enhanced battery performance. Concurrently, development of a gas atomization nozzle that is more efficient than all current designs is needed to increase the yield of ultrafine AB{sub 5} alloy powder for further processing advantage. Gas atomization processing of the AB{sub 5} alloys was demonstrated to be effective in producing ultrafine spherical powders that were resilient to hydrogen cycling for the benefit of improving corrosion resistance in battery application. These ultrafine powders benefited from the rapid solidification process by having refined solute segregation in the microstructure of the gas atomized powders which enabled a rapid anneal treatment of the powders. The author has demonstrated the ability to produce high yields of ultrafine powder efficiently and cost effectively, using the new HPGA-III technology. Thus, the potential benefits of processing AB{sub 5} alloys using the new HPGA technology could reduce manufacturing cost of nickel-metal hydride powder. In the near future, the manufacture of AB{sub 5} alloy powders could become a continuous and rapid production process. The economic benefit of an improved AB{sub 5} production process may thereby encourage the use of nickel-metal hydride rechargeable batteries in electrical vehicle applications in the foreseeable future.

  7. Activated aluminum hydride hydrogen storage compositions and uses thereof

    DOE Patents [OSTI]

    Sandrock, Gary (Ringwood, NJ); Reilly, James (Bellport, NY); Graetz, Jason (Mastic, NY); Wegrzyn, James E. (Brookhaven, NY)

    2010-11-23

    In one aspect, the invention relates to activated aluminum hydride hydrogen storage compositions containing aluminum hydride in the presence of, or absence of, hydrogen desorption stimulants. The invention particularly relates to such compositions having one or more hydrogen desorption stimulants selected from metal hydrides and metal aluminum hydrides. In another aspect, the invention relates to methods for generating hydrogen from such hydrogen storage compositions.

  8. Hydride compressor

    DOE Patents [OSTI]

    Powell, James R. (Wading River, NY); Salzano, Francis J. (Patchogue, NY)

    1978-01-01

    Method of producing high energy pressurized gas working fluid power from a low energy, low temperature heat source, wherein the compression energy is gained by using the low energy heat source to desorb hydrogen gas from a metal hydride bed and the desorbed hydrogen for producing power is recycled to the bed, where it is re-adsorbed, with the recycling being powered by the low energy heat source. In one embodiment, the adsorption-desorption cycle provides a chemical compressor that is powered by the low energy heat source, and the compressor is connected to a regenerative gas turbine having a high energy, high temperature heat source with the recycling being powered by the low energy heat source.

  9. Executive Summaries for the Hydrogen Storage Materials Center of Excellence- Chemical Hydrogen Storage CoE, Hydrogen Sorption CoE, and Metal Hydride CoE

    Broader source: Energy.gov [DOE]

    This report contains the executive summaries of the final technical reports from the three Hydrogen Storage Centers of Excellence that operated from 2005 through 2010 to develop advanced hydrogen storage materials in the areas of Chemical Hydrogen Storage Materials, Hydrogen Sorbents, and Reversible Metal Hydrides.

  10. Final Report: DE- FC36-05GO15063, Fundamental Studies of Advanced High-Capacity, Reversible Metal Hydrides

    SciTech Connect (OSTI)

    Jensen, Craig; McGrady, Sean; Severa, Godwin; Eliseo, Jennifer; Chong, Marina

    2015-02-08

    The project was component of the US DOE, Metal Hydride Center of Excellence (MHCoE). The Sandia National Laboratory led center was established to conduct highly collaborative and multi-disciplinary applied R&D to develop new reversible hydrogen storage materials that meet or exceed DOE/FreedomCAR 2010 and 2015 system targets for hydrogen storage materials. Our approach entailed a wide variety of activities ranging from synthesis, characterization, and evaluation of new candidate hydrogen storage materials; screening of catalysts for high capacity materials requiring kinetics enhancement; development of low temperature methods for nano-confinement of hydrides and determining its effects on the kinetics and thermodynamics of hydrides; and development of novel processes for the direct re-hydrogenation of materials. These efforts have resulted in several advancements the development of hydrogen storage materials. We have greatly extended the fundamental knowledge about the highly promising hydrogen storage carrier, alane (AlH?), by carrying out the first crystal structure determinations and the first determination of the heats of dehydrogenation of ?AlH? and ?-AlD?. A low-temperature homogenous organometallic approach to incorporation of Al and Mg based hydrides into carbon aerogels has been developed that that allows high loadings without degradation of the nano-porous scaffold. Nano-confinement was found to significantly improve the dehydrogenation kinetics but not effect the enthalpy of dehydrogenation. We conceived, characterized, and synthesized a novel class of potential hydrogen storage materials, bimetallic borohydrides. These novel compounds were found to have many favorable properties including release of significant amounts of hydrogen at moderate temperatures (75-190C). However, in situ IR studies in tandem with thermal gravimetric analysis have shown that about 0.5 equivalents of diborane are released during the dehydrogenation making re-hydrogenation effectively impossible and precluding these compounds from further consideration as hydrogen storage materials. The hydrogen cycling of >11 wt % between MgB? to Mg(BH?)? was achieved but required very forcing conditions. Under moderate conditions (dehydrogenation 200C; re-hydrogenation 250C, 120 atm H2), Mg(BH?)? undergoes reversible dehydrogenation to Mg(B3H8)2. Although the 2.5 wt% cycling capacity does not meet current on-board storage targets, this result provides first example of direct hydrogen cycling of a borohydride under moderate conditions and demonstrates the plausibility of finding mild, PEM fuel cell relevant conditions for the high capacity, reversible dehydrogenation of borohydrides. A method was developed for the room temperature, direct hydrogenation of Ti-doped LiH/Al in liquefied dimethyl ether under 100 atm of H?. The process has been optimized such that Ti-doped LiAlH? is obtained in >95% yield. The WTT energy efficiency our direct synthesis process has been estimated to approach the 60% U.S. DOE target. Thus our simplification of the hydrogenation half-cycle may provide the key to harnessing the long-recognized potential of this lightweight, high capacity material as a practical hydrogen carrier. Finally, we have gained insight into the fundamental basis of the enhanced hydrogen cycling kinetics of Ti-doped NaAlH? through studies by solid state H NMR, anelastic spectroscopy; muon spin rotation; and positron annihilation.

  11. Hydride compositions

    DOE Patents [OSTI]

    Lee, Myung, W.

    1994-01-01

    Disclosed are a composition for use in storing hydrogen and a method for making the composition. The composition comprises a mixture of two or more hydrides, each hydride having a different series of hydrogen sorption isotherms that contribute to the overall isotherms of the mixture. The hydrides are chosen so that the isotherms of the mixture have regions wherein the H equilibrium pressure increases with increasing hydrogen, preferably linearly. The isotherms of the mixture can be adjusted by selecting hydrides with different isotherms and by varying the amounts of the individual hydrides, or both. Preferably, the mixture is made up of hydrides that have isotherms with substantially flat plateaus and in nearly equimolar amounts. The composition is activated by degassing, exposing to H, and then heating below the softening temperature of any of the constituents. When the composition is used to store hydrogen, its hydrogen content can be found simply by measuring P{sub H}{sub 2} and determining H/M from the isothermic function of the composition.

  12. Hydride compositions

    DOE Patents [OSTI]

    Lee, Myung W.

    1995-01-01

    A composition for use in storing hydrogen, and a method for making the composition. The composition comprises a mixture of two or more hydrides, each hydride having a different series of hydrogen sorption isotherms that contribute to the overall isotherms of the mixture. The hydrides are chosen so that the isotherms of the mixture have regions wherein the hydrogen equilibrium pressure increases with increasing hydrogen, preferably linearly. The isotherms of the mixture can be adjusted by selecting hydrides with different isotherms and by varying the amounts of the individual hydrides, or both. Preferably, the mixture is made up of hydrides that have isotherms with substantially flat plateaus and in nearly equimolar amounts. The composition is activated by degassing, exposing to hydrogen and then heating at a temperature below the softening temperature of any of the. constituents so that their chemical and structural integrity is preserved. When the composition is used to store hydrogen, its hydrogen content can be found simply by measuring P.sub.H.sbsb.2 and determining H/M from the isothermic function of the composition.

  13. Metal hydride differential scanning calorimetry as an approach to compositional determination of mixtures of hydrogen isotopologues and helium

    SciTech Connect (OSTI)

    Robinson, David B.; Luo, Weifang; Cai, Trevor Y.; Stewart, Kenneth D.

    2015-09-26

    Gaseous mixtures of diatomic hydrogen isotopologues and helium are often encountered in the nuclear energy industry and in analytical chemistry. Compositions of stored mixtures can vary due to interactions with storage and handling materials. When tritium is present, it decays to form ions and helium-3, both of which can lead to further compositional variation. Monitoring of composition is typically achieved by mass spectrometry, a method that is bulky and energy-intensive. Mass spectrometers disperse sample material through vacuum pumps, which is especially troublesome if tritium is present. Moreover, our ultimate goal is to create a compact, fast, low-power sensor that can determine composition with minimal gas consumption and waste generation, as a complement to mass spectrometry that can be instantiated more widely. We propose calorimetry of metal hydrides as an approach to this, due to the strong isotope effect on gas absorption, and demonstrate the sensitivity of measured heat flow to atomic composition of the gas. Peak shifts are discernible when mole fractions change by at least 1%. A mass flow restriction results in a unique dependence of the measurement on helium concentration. We present a mathematical model as a first step toward prediction of the peak shapes and positions. The model includes a useful method to compute estimates of phase diagrams for palladium in the presence of arbitrary mixtures of hydrogen isotopologues. As a result, we expect that this approach can be used to deduce unknown atomic compositions from measured calorimetric data over a useful range of partial pressures of each component.

  14. Metal hydride differential scanning calorimetry as an approach to compositional determination of mixtures of hydrogen isotopologues and helium

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Robinson, David B.; Luo, Weifang; Cai, Trevor Y.; Stewart, Kenneth D.

    2015-09-26

    Gaseous mixtures of diatomic hydrogen isotopologues and helium are often encountered in the nuclear energy industry and in analytical chemistry. Compositions of stored mixtures can vary due to interactions with storage and handling materials. When tritium is present, it decays to form ions and helium-3, both of which can lead to further compositional variation. Monitoring of composition is typically achieved by mass spectrometry, a method that is bulky and energy-intensive. Mass spectrometers disperse sample material through vacuum pumps, which is especially troublesome if tritium is present. Moreover, our ultimate goal is to create a compact, fast, low-power sensor that canmore » determine composition with minimal gas consumption and waste generation, as a complement to mass spectrometry that can be instantiated more widely. We propose calorimetry of metal hydrides as an approach to this, due to the strong isotope effect on gas absorption, and demonstrate the sensitivity of measured heat flow to atomic composition of the gas. Peak shifts are discernible when mole fractions change by at least 1%. A mass flow restriction results in a unique dependence of the measurement on helium concentration. We present a mathematical model as a first step toward prediction of the peak shapes and positions. The model includes a useful method to compute estimates of phase diagrams for palladium in the presence of arbitrary mixtures of hydrogen isotopologues. As a result, we expect that this approach can be used to deduce unknown atomic compositions from measured calorimetric data over a useful range of partial pressures of each component.« less

  15. Direct synthesis of catalyzed hydride compounds

    DOE Patents [OSTI]

    Gross, Karl J.; Majzoub, Eric

    2004-09-21

    A method is disclosed for directly preparing alkali metal aluminum hydrides such as NaAlH.sub.4 and Na.sub.3 AlH.sub.6 from either the alkali metal or its hydride, and aluminum. The hydride thus prepared is doped with a small portion of a transition metal catalyst compound, such as TiCl.sub.3, TiF.sub.3, or a mixture of these materials, in order to render them reversibly hydridable. The process provides for mechanically mixing the dry reagents under an inert atmosphere followed by charging the mixed materials with high pressure hydrogen while heating the mixture to about 125.degree. C. The method is relatively simple and inexpensive and provides reversible hydride compounds which are free of the usual contamination introduced by prior art wet chemical methods.

  16. Metal Hydrides- Science Needs

    Broader source: Energy.gov [DOE]

    Presentation from the Hydrogen Storage Pre-Solicitation Meeting held June 19, 2003 in Washington, DC.

  17. Method for controlled hydrogen charging of metals

    DOE Patents [OSTI]

    Cheng, Bo-Ching (Fremont, CA); Adamson, Ronald B. (Fremont, CA)

    1984-05-29

    A method for controlling hydrogen charging of hydride forming metals through a window of a superimposed layer of a non-hydriding metal overlying the portion of the hydride forming metals to be charged.

  18. Complex hydrides for hydrogen storage

    DOE Patents [OSTI]

    Zidan, Ragaiy

    2006-08-22

    A hydrogen storage material and process of forming the material is provided in which complex hydrides are combined under conditions of elevated temperatures and/or elevated temperature and pressure with a titanium metal such as titanium butoxide. The resulting fused product exhibits hydrogen desorption kinetics having a first hydrogen release point which occurs at normal atmospheres and at a temperature between 50.degree. C. and 90.degree. C.

  19. High capacity stabilized complex hydrides for hydrogen storage

    DOE Patents [OSTI]

    Zidan, Ragaiy; Mohtadi, Rana F; Fewox, Christopher; Sivasubramanian, Premkumar

    2014-11-11

    Complex hydrides based on Al(BH.sub.4).sub.3 are stabilized by the presence of one or more additional metal elements or organic adducts to provide high capacity hydrogen storage material.

  20. Zirconium hydride containing explosive composition

    DOE Patents [OSTI]

    Walker, Franklin E. (18 Shadow Oak Rd., Danville, CA 94526); Wasley, Richard J. (4290 Colgate Way, Livermore, CA 94550)

    1981-01-01

    An improved explosive composition is disclosed and comprises a major portion of an explosive having a detonation velocity between about 1500 and 10,000 meters per second and a minor amount of a donor additive comprising a non-explosive compound or mixture of non-explosive compounds which when subjected to an energy fluence of 1000 calories/cm.sup.2 or less is capable of releasing free radicals each having a molecular weight between 1 and 120. Exemplary donor additives are dibasic acids, polyamines and metal hydrides.

  1. Hydrogen Storage Properties of New Hydrogen-Rich BH3NH3-Metal Hydride (TiH2, ZrH2, MgH2, and/or CaH2) Composite Systems

    SciTech Connect (OSTI)

    Choi, Young Joon; Xu, Yimin; Shaw, Wendy J.; Ronnebro, Ewa

    2012-04-19

    Ammonia borane (AB = NH3BH3) is one of the most attractive materials for chemical hydrogen storage due to its high hydrogen contents of 19.6 wt.%, however, impurity levels of borazine, ammonia and diborane in conjunction with foaming and exothermic hydrogen release calls for finding ways to mitigate the decomposition reactions. In this paper we present a solution by mixing AB with metal hydrides (TiH2, ZrH2, MgH2 and CaH2) which have endothermic hydrogen release in order to control the heat release and impurity levels from AB upon decomposition. The composite materials were prepared by mechanical ball milling, and their H2 release properties were characterized by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The formation of volatile products from decomposition side reactions, such as borazine (N3B3H6) was determined by mass spectrometry (MS). Sieverts type pressure-composition-temperature (PCT) gas-solid reaction instrument was adopted to observe the kinetics of the H2 release reactions of the combined systems and neat AB. In situ 11B MAS-NMR revealed a destabilized decomposition pathway. We found that by adding specific metal hydrides to AB we can eliminate the impurities and mitigate the heat release.

  2. Phase I. Lanthanum-based Start Materials for Hydride Batteries

    SciTech Connect (OSTI)

    Gschneidner, K. A.; Schmidt, F. A.; Frerichs, A. E.; Ament, K. A.

    2013-08-20

    The purpose of Phase I of this work is to focus on developing a La-based start material for making nickel-metal (lanthanum)-hydride batteries based on our carbothermic-silicon process. The goal is to develop a protocol for the manufacture of (La1-xRx)(Ni1-yMy)(Siz), where R is a rare earth metal and M is a non-rare earth metal, to be utilized as the negative electrode in nickel-metal hydride (NiMH) rechargeable batteries.

  3. Results of NDE Technique Evaluation of Clad Hydrides

    SciTech Connect (OSTI)

    Dennis C. Kunerth

    2014-09-01

    This report fulfills the M4 milestone, M4FT-14IN0805023, Results of NDE Technique Evaluation of Clad Hydrides, under Work Package Number FT-14IN080502. During service, zirconium alloy fuel cladding will degrade via corrosion/oxidation. Hydrogen, a byproduct of the oxidation process, will be absorbed into the cladding and eventually form hydrides due to low hydrogen solubility limits. The hydride phase is detrimental to the mechanical properties of the cladding and therefore it is important to be able to detect and characterize the presence of this constituent within the cladding. Presently, hydrides are evaluated using destructive examination. If nondestructive evaluation techniques can be used to detect and characterize the hydrides, the potential exists to significantly increase test sample coverage while reducing evaluation time and cost. To demonstrate the viability this approach, an initial evaluation of eddy current and ultrasonic techniques were performed to demonstrate the basic ability to these techniques to detect hydrides or their effects on the microstructure. Conventional continuous wave eddy current techniques were applied to zirconium based cladding test samples thermally processed with hydrogen gas to promote the absorption of hydrogen and subsequent formation of hydrides. The results of the evaluation demonstrate that eddy current inspection approaches have the potential to detect both the physical damage induced by hydrides, e.g. blisters and cracking, as well as the combined effects of absorbed hydrogen and hydride precipitates on the electrical properties of the zirconium alloy. Similarly, measurements of ultrasonic wave velocities indicate changes in the elastic properties resulting from the combined effects of absorbed hydrogen and hydride precipitates as well as changes in geometry in regions of severe degradation. However, for both approaches, the signal responses intended to make the desired measurement incorporate a number of contributing parameters. These contributing factors need to be recognized and a means to control them or separate their contributions will be required to obtain the desired information.

  4. Boron hydride polymer coated substrates

    DOE Patents [OSTI]

    Pearson, R.K.; Bystroff, R.I.; Miller, D.E.

    1986-08-27

    A method is disclosed for coating a substrate with a uniformly smooth layer of a boron hydride polymer. The method comprises providing a reaction chamber which contains the substrate and the boron hydride plasma. A boron hydride feed stock is introduced into the chamber simultaneously with the generation of a plasma discharge within the chamber. A boron hydride plasma of ions, electrons and free radicals which is generated by the plasma discharge interacts to form a uniformly smooth boron hydride polymer which is deposited on the substrate.

  5. Boron hydride polymer coated substrates

    DOE Patents [OSTI]

    Pearson, Richard K. (Pleasanton, CA); Bystroff, Roman I. (Livermore, CA); Miller, Dale E. (Livermore, CA)

    1987-01-01

    A method is disclosed for coating a substrate with a uniformly smooth layer of a boron hydride polymer. The method comprises providing a reaction chamber which contains the substrate and the boron hydride plasma. A boron hydride feed stock is introduced into the chamber simultaneously with the generation of a plasma discharge within the chamber. A boron hydride plasma of ions, electrons and free radicals which is generated by the plasma discharge interacts to form a uniformly smooth boron hydride polymer which is deposited on the substrate.

  6. Chemical Hydride Slurry for Hydrogen Production and Storage

    SciTech Connect (OSTI)

    McClaine, Andrew W.

    2008-09-30

    The purpose of this project was to investigate and evaluate the attractiveness of using a magnesium chemical hydride slurry as a hydrogen storage, delivery, and production medium for automobiles. To fully evaluate the potential for magnesium hydride slurry to act as a carrier of hydrogen, potential slurry compositions, potential hydrogen release techniques, and the processes (and their costs) that will be used to recycle the byproducts back to a high hydrogen content slurry were evaluated. A 75% MgH2 slurry was demonstrated, which was just short of the 76% goal. This slurry is pumpable and storable for months at a time at room temperature and pressure conditions and it has the consistency of paint. Two techniques were demonstrated for reacting the slurry with water to release hydrogen. The first technique was a continuous mixing process that was tested for several hours at a time and demonstrated operation without external heat addition. Further work will be required to reduce this design to a reliable, robust system. The second technique was a semi-continuous process. It was demonstrated on a 2 kWh scale. This system operated continuously and reliably for hours at a time, including starts and stops. This process could be readily reduced to practice for commercial applications. The processes and costs associated with recycling the byproducts of the water/slurry reaction were also evaluated. This included recovering and recycling the oils of the slurry, reforming the magnesium hydroxide and magnesium oxide byproduct to magnesium metal, hydriding the magnesium metal with hydrogen to form magnesium hydride, and preparing the slurry. We found that the SOM process, under development by Boston University, offers the lowest cost alternative for producing and recycling the slurry. Using the H2A framework, a total cost of production, delivery, and distribution of $4.50/kg of hydrogen delivered or $4.50/gge was determined. Experiments performed at Boston University have demonstrated the technical viability of the process and have provided data for the cost analyses that have been performed. We also concluded that a carbothermic process could also produce magnesium at acceptable costs. The use of slurry as a medium to carry chemical hydrides has been shown during this project to offer significant advantages for storing, delivering, and distributing hydrogen: Magnesium hydride slurry is stable for months and pumpable. The oils of the slurry minimize the contact of oxygen and moisture in the air with the metal hydride in the slurry. Thus reactive chemicals, such as lithium hydride, can be handled safely in the air when encased in the oils of the slurry. Though magnesium hydride offers an additional safety feature of not reacting readily with water at room temperatures, it does react readily with water at temperatures above the boiling point of water. Thus when hydrogen is needed, the slurry and water are heated until the reaction begins, then the reaction energy provides heat for more slurry and water to be heated. The reaction system can be relatively small and light and the slurry can be stored in conventional liquid fuel tanks. When transported and stored, the conventional liquid fuel infrastructure can be used. The particular metal hydride of interest in this project, magnesium hydride, forms benign byproducts, magnesium hydroxide (Milk of Magnesia) and magnesium oxide. We have estimated that a magnesium hydride slurry system (including the mixer device and tanks) could meet the DOE 2010 energy density goals. ? During the investigation of hydriding techniques, we learned that magnesium hydride in a slurry can also be cycled in a rechargeable fashion. Thus, magnesium hydride slurry can act either as a chemical hydride storage medium or as a rechargeable hydride storage system. Hydrogen can be stored and delivered and then stored again thus significantly reducing the cost of storing and delivering hydrogen. Further evaluation and development of this concept will be performed as follow-on work under a

  7. Number

    Office of Legacy Management (LM)

    ' , /v-i 2 -i 3 -A, This dow'at consists ~f--~-_,_~~~p.~,::, Number -------of.-&--copies, 1 Series.,-a-,-. ! 1 THE UNIVERSITY OF ROCHESTER 1; r-.' L INTRAMURALCORRESPONDENCE i"ks' 3 2.. September 25, 1947 Memo.tor Dr. A. H, Dovdy . From: Dr. H. E, Stokinger Be: Trip Report - Mayvood Chemical Works A trip vas made Nednesday, August 24th vith Messrs. Robert W ilson and George Sprague to the Mayvood Chemical F!orks, Mayvood, New Jersey one of 2 plants in the U.S.A. engaged in the

  8. Mechanochemical processing for metals and metal alloys

    DOE Patents [OSTI]

    Froes, Francis H. (Moscow, ID); Eranezhuth, Baburaj G. (Moscow, ID); Prisbrey, Keith (Moscow, ID)

    2001-01-01

    A set of processes for preparing metal powders, including metal alloy powders, by ambient temperature reduction of a reducible metal compound by a reactive metal or metal hydride through mechanochemical processing. The reduction process includes milling reactants to induce and complete the reduction reaction. The preferred reducing agents include magnesium and calcium hydride powders. A process of pre-milling magnesium as a reducing agent to increase the activity of the magnesium has been established as one part of the invention.

  9. Optimization of Hydride Rim Formation in Unirradiated Zr 4 Cladding

    SciTech Connect (OSTI)

    Shimskey, Rick W.; Hanson, Brady D.; MacFarlan, Paul J.

    2013-09-30

    The purpose of this work is to build on the results reported in the M2 milestone M2FT 13PN0805051, document number FCRD-USED-2013-000151 (Hanson, 2013). In that work, it was demonstrated that unirradiated samples of zircaloy-4 cladding could be pre-hydrided at temperatures below 400C in pure hydrogen gas and that the growth of hydrides on the surface could be controlled by changing the surface condition of the samples and form a desired hydride rim on the outside diameter of the cladding. The work performed at Pacific Northwest National Laboratory since the issuing of the M2 milestone has focused its efforts to optimize the formation of a hydride rim on available zircaloy-4 cladding samples by controlling temperature variation and gas flow control during pre-hydriding treatments. Surface conditioning of the outside surface was also examined as a variable. The results of test indicate that much of the variability in the hydride thickness is due to temperature variation occurring in the furnaces as well as how hydrogen gas flows across the sample surface. Efforts to examine other alloys, gas concentrations, and different surface conditioning plan to be pursed in the next FY as more cladding samples become available

  10. Erbium hydride decomposition kinetics.

    SciTech Connect (OSTI)

    Ferrizz, Robert Matthew

    2006-11-01

    Thermal desorption spectroscopy (TDS) is used to study the decomposition kinetics of erbium hydride thin films. The TDS results presented in this report are analyzed quantitatively using Redhead's method to yield kinetic parameters (E{sub A} {approx} 54.2 kcal/mol), which are then utilized to predict hydrogen outgassing in vacuum for a variety of thermal treatments. Interestingly, it was found that the activation energy for desorption can vary by more than 7 kcal/mol (0.30 eV) for seemingly similar samples. In addition, small amounts of less-stable hydrogen were observed for all erbium dihydride films. A detailed explanation of several approaches for analyzing thermal desorption spectra to obtain kinetic information is included as an appendix.

  11. Hydrogen isotopic exchange over palladium metal

    SciTech Connect (OSTI)

    Carstens, D.H.W.; Encinias, P.D.

    1990-01-01

    We have recently developed the laser-Raman technique as a means of unambiguously measuring the partial pressures of all possible hydrogen isotopes in the gas phase. Using this technique we have investigated the hydrogen-deuterium exchange in a number of metals. This report presents detailed data for isotopic exchange in the palladium hydride system over the temperature range 26{degree}C to -100{degree}C at a pressure of 7 atm. First order kinetic rate constants and activation energies are summarized for the forward (hydride to deuteride) and reverse (deuteride to hydride) exchange processes. In addition, we have found that small amounts (100 ppm) of impurities in the exchange gases considerably slow the exchange kinetics with the effect increasing down the series CH{sub 4}, CO{sub 2}, H{sub 2}O, and CO. 9 refs., 4 figs., 1 tab.

  12. Microstructure, Phase Formation, and Stress of Reactively-Deposited Metal

    Office of Scientific and Technical Information (OSTI)

    Hydride Thin Films (Technical Report) | SciTech Connect Microstructure, Phase Formation, and Stress of Reactively-Deposited Metal Hydride Thin Films Citation Details In-Document Search Title: Microstructure, Phase Formation, and Stress of Reactively-Deposited Metal Hydride Thin Films This document summarizes research of reactively deposited metal hydride thin films and their properties. Reactive deposition processes are of interest, because desired stoichiometric phases are created in a

  13. Hydride Rim Formation in Unirradiated Zircaloy

    Office of Energy Efficiency and Renewable Energy (EERE)

    The purpose of this work is to develop the means of pre-hydriding unirradiated Zircaloy cladding such that a high concentration, or rim, of hydrides is formed at the cladding outside diameter.

  14. Method of producing a chemical hydride

    DOE Patents [OSTI]

    Klingler, Kerry M.; Zollinger, William T.; Wilding, Bruce M.; Bingham, Dennis N.; Wendt, Kraig M.

    2007-11-13

    A method of producing a chemical hydride is described and which includes selecting a composition having chemical bonds and which is capable of forming a chemical hydride; providing a source of a hydrocarbon; and reacting the composition with the source of the hydrocarbon to generate a chemical hydride.

  15. Photogeneration of Hydride Donors and Their Use Toward CO2 Reduction

    SciTech Connect (OSTI)

    Fujita,E.; Muckerman, J.T.; Polyansky, D.E.

    2009-06-07

    Despite substantial effort, no one has succeeded in efficiently producing methanol from CO2 using homogeneous photocatalytic systems. We are pursuing reaction schemes based on a sequence of hydride-ion transfers to carry out stepwise reduction of CO2 to methanol. We are using hydride-ion transfer from photoproduced C-H bonds in metal complexes with bio-inspired ligands (i.e., NADH-like ligands) that are known to store one proton and two electrons.

  16. Complex Hydride Compounds with Enhanced Hydrogen Storage Capacity

    SciTech Connect (OSTI)

    Mosher, Daniel A.; Opalka, Susanne M.; Tang, Xia; Laube, Bruce L.; Brown, Ronald J.; Vanderspurt, Thomas H.; Arsenault, Sarah; Wu, Robert; Strickler, Jamie; Anton, Donald L.; Zidan, Ragaiy; Berseth, Polly

    2008-02-18

    The United Technologies Research Center (UTRC), in collaboration with major partners Albemarle Corporation (Albemarle) and the Savannah River National Laboratory (SRNL), conducted research to discover new hydride materials for the storage of hydrogen having on-board reversibility and a target gravimetric capacity of ? 7.5 weight percent (wt %). When integrated into a system with a reasonable efficiency of 60% (mass of hydride / total mass), this target material would produce a system gravimetric capacity of ? 4.5 wt %, consistent with the DOE 2007 target. The approach established for the project combined first principles modeling (FPM - UTRC) with multiple synthesis methods: Solid State Processing (SSP - UTRC), Solution Based Processing (SBP - Albemarle) and Molten State Processing (MSP - SRNL). In the search for novel compounds, each of these methods has advantages and disadvantages; by combining them, the potential for success was increased. During the project, UTRC refined its FPM framework which includes ground state (0 Kelvin) structural determinations, elevated temperature thermodynamic predictions and thermodynamic / phase diagram calculations. This modeling was used both to precede synthesis in a virtual search for new compounds and after initial synthesis to examine reaction details and options for modifications including co-reactant additions. The SSP synthesis method involved high energy ball milling which was simple, efficient for small batches and has proven effective for other storage material compositions. The SBP method produced very homogeneous chemical reactions, some of which cannot be performed via solid state routes, and would be the preferred approach for large scale production. The MSP technique is similar to the SSP method, but involves higher temperature and hydrogen pressure conditions to achieve greater species mobility. During the initial phases of the project, the focus was on higher order alanate complexes in the phase space between alkaline metal hydrides (AmH), Alkaline earth metal hydrides (AeH2), alane (AlH3), transition metal (Tm) hydrides (TmHz, where z=1-3) and molecular hydrogen (H2). The effort started first with variations of known alanates and subsequently extended the search to unknown compounds. In this stage, the FPM techniques were developed and validated on known alanate materials such as NaAlH4 and Na2LiAlH6. The coupled predictive methodologies were used to survey over 200 proposed phases in six quaternary spaces, formed from various combinations of Na, Li Mg and/or Ti with Al and H. A wide range of alanate compounds was examined using SSP having additions of Ti, Cr, Co, Ni and Fe. A number of compositions and reaction paths were identified having H weight fractions up to 5.6 wt %, but none meeting the 7.5 wt%H reversible goal. Similarly, MSP of alanates produced a number of interesting compounds and general conclusions regarding reaction behavior of mixtures during processing, but no alanate based candidates meeting the 7.5 wt% goal. A novel alanate, LiMg(AlH4)3, was synthesized using SBP that demonstrated a 7.0 wt% capacity with a desorption temperature of 150C. The deuteride form was synthesized and characterized by the Institute for Energy (IFE) in Norway to determine its crystalline structure for related FPM studies. However, the reaction exhibited exothermicity and therefore was not reversible under acceptable hydrogen gas pressures for on-board recharging. After the extensive studies of alanates, the material class of emphasis was shifted to borohydrides. Through SBP, several ligand-stabilized Mg(BH4)2 complexes were synthesized. The Mg(BH4)2*2NH3 complex was found to change behavior with slightly different synthesis conditions and/or aging. One of the two mechanisms was an amine-borane (NH3BH3) like dissociation reaction which released up to 16 wt %H and more conservatively 9 wt%H when not including H2 released from the NH3. From FPM, the stability of the Mg(BH4)2*2NH3 compound was found to increase with the inclusion of NH3 groups in the inner-Mg coordination

  17. A new phase in palladium hydride technology

    SciTech Connect (OSTI)

    Walters, R.T.

    1991-12-31

    Two plateaux are observed in both the absorption and desorption isotherms of palladium hydride. For the absorption isotherm, a change in plateau pressure is observed at a hydrogen-to-metal (H/M) ratio of about 0.35 for all temperatures studied. For the desorption isotherm, the change in plateau pressure appears to be a function of temperature, ranging from an H/M ratio of 0.18 at 80{degrees}C to 0.3 at 140{degrees}C. These data are interpreted as being experimentally observed boundaries to an equilibrium phase line located in the miscibility gap of the palladium/hydrogen phase diagram. This new phase does not appear to be a stoichiometric compounds, but rather its composition seems to vary with temperature. 6 refs., 4 figs.

  18. A new phase in palladium hydride technology

    SciTech Connect (OSTI)

    Walters, R.T.

    1991-01-01

    Two plateaux are observed in both the absorption and desorption isotherms of palladium hydride. For the absorption isotherm, a change in plateau pressure is observed at a hydrogen-to-metal (H/M) ratio of about 0.35 for all temperatures studied. For the desorption isotherm, the change in plateau pressure appears to be a function of temperature, ranging from an H/M ratio of 0.18 at 80{degrees}C to 0.3 at 140{degrees}C. These data are interpreted as being experimentally observed boundaries to an equilibrium phase line located in the miscibility gap of the palladium/hydrogen phase diagram. This new phase does not appear to be a stoichiometric compounds, but rather its composition seems to vary with temperature. 6 refs., 4 figs.

  19. The Hydriding Kinetics of Organic Hydrogen Getters

    SciTech Connect (OSTI)

    Powell, G. L.

    2002-02-11

    The aging of hermetically sealed systems is often accompanied by the gradual production of hydrogen gas that is a result of the decay of environmental gases and the degradation of organic materials. In particular, the oxygen, water, hydrogen ''equilibrium'' is affected by the removal of oxygen due the oxidation of metals and organic materials. This shift of the above ''equilibrium'' towards the formation of hydrogen gas, particularly in crevices, may eventually reach an explosive level of hydrogen gas or degrade metals by hydriding them. The latter process is generally delayed until the oxidizing species are significantly reduced. Organic hydrogen getters introduced by Allied Signal Aerospace Company, Kansas City Division have proven to be a very effective means of preventing hydrogen gas accumulation in sealed containers. These getters are relatively unaffected by air and environmental gases. They can be packaged in a variety of ways to fit particular needs such as porous pellets, fine or coarse [gravel] powder, or loaded into silicone rubber. The hydrogen gettering reactions are extremely irreversible since the hydrogen gas is converted into an organic hydrocarbon. These getters are based on the palladium-catalyzed hydrogenation of triple bonds to double and then single bonds in aromatic aryl compounds. DEB (1,4 bis (phenyl ethynyl) benzene) typically mixed with 25% by weight carbon with palladium (1% by weight of carbon) is one of the newest and best of these organic hydrogen getters. The reaction mechanisms are complex involving solid state reaction with a heterogeneous catalyst leading to the many intermediates, including mixed alkyl and aryl hydrocarbons with the possibilities of many isomers. The reaction kinetics mechanisms are also strongly influenced by the form in which they are packaged. For example, the hydriding rates for pellets and gravel have a strong dependence on reaction extent (i.e., DEB reduction) and a kinetic order in pressure of 0.76. Silicone rubber based DEB getters hydride at a much lower rate, have little dependence on reaction extent, have a higher kinetic order in pressure (0.87), and have a lower activation energy. The kinetics of the reaction as a function of hydrogen pressure, stoichiometry, and temperature for hydrogen and deuterium near ambient temperature (0 to 75 C) for pressures near or below 100 Pa over a wide range (in some cases, the complete) hydrogenation range are presented along with multi-dimensional rate models.

  20. Steps to Commercialization: Nickel Metal Hydride Batteries |...

    Broader source: Energy.gov (indexed) [DOE]

    funds cutting-edge research on a broad range of topics ranging from advanced battery construction to the modeling of industrial processes and supercomputer simulation of...

  1. Vanadium hydride deuterium-tritium generator

    DOE Patents [OSTI]

    Christensen, L.D.

    1980-03-13

    A pressure controlled vanadium hydride gas generator was designed to provide deuterium-tritium gas in a series of pressure increments. A high pressure chamber filled with vanadium-deuterium-tritium hydride is surrounded by a heater which controls the hydride temperature. The heater is actuated by a power controller which responds to the difference signal between the actual pressure signal and a programmed pressure signal.

  2. CRADA (AL-C-2009-02) Final Report: Phase I. Lanthanum-based Start Materials for Hydride Batteries

    SciTech Connect (OSTI)

    Gschneidner, Jr., Karl; Schmidt, Frederick; Frerichs, A.E.; Ament, Katherine A.

    2013-05-01

    The purpose of Phase I of this work is to focus on developing a La-based start material for making nickel-metal (lanthanum)-hydride batteries based on our carbothermic-silicon process. The goal is to develop a protocol for the manufacture of (La{sub 1-x}R{sub x})(Ni{sub 1-y}M{sub y})(Si{sub z}), where R is a rare earth metal and M is a non-rare earth metal, to be utilized as the negative electrode in nickel-metal hydride (NiMH) rechargeable batteries.

  3. Investigation of Cracked Lithium Hydride Reactor Vessels

    SciTech Connect (OSTI)

    bird, e.l.; mustaleski, t.m.

    1999-06-01

    Visual examination of lithium hydride reactor vessels revealed cracks that were adjacent to welds, most of which were circumferentially located in the bottom portion of the vessels. Sections were cut from the vessels containing these cracks and examined by use of the metallograph, scanning electron microscope, and microprobe to determine the cause of cracking. Most of the cracks originated on the outer surface just outside the weld fusion line in the base material and propagated along grain boundaries. Crack depths of those examined sections ranged from {approximately}300 to 500 {micro}m. Other cracks were reported to have reached a maximum depth of 1/8 in. The primary cause of cracking was the creation of high tensile stresses associated with the differences in the coefficients of thermal expansion between the filler metal and the base metal during operation of the vessel in a thermally cyclic environment. This failure mechanism could be described as creep-type fatigue, whereby crack propagation may have been aided by the presence of brittle chromium carbides along the grain boundaries, which indicates a slightly sensitized microstructure.

  4. Hydrogen-storing hydride complexes

    DOE Patents [OSTI]

    Srinivasan, Sesha S.; Niemann, Michael U.; Goswami, D. Yogi; Stefanakos, Elias K.

    2012-04-10

    A ternary hydrogen storage system having a constant stoichiometric molar ratio of LiNH.sub.2:MgH.sub.2:LiBH.sub.4 of 2:1:1. It was found that the incorporation of MgH.sub.2 particles of approximately 10 nm to 20 nm exhibit a lower initial hydrogen release temperature of 150.degree. C. Furthermore, it is observed that the particle size of LiBNH quaternary hydride has a significant effect on the hydrogen sorption concentration with an optimum size of 28 nm. The as-synthesized hydrides exhibit two main hydrogen release temperatures, one around 160.degree. C. and the other around 300.degree. C., with the main hydrogen release temperature reduced from 310.degree. C. to 270.degree. C., while hydrogen is first reversibly released at temperatures as low as 150.degree. C. with a total hydrogen capacity of 6 wt. % to 8 wt. %. Detailed thermal, capacity, structural and microstructural properties have been demonstrated and correlated with the activation energies of these materials.

  5. Titanium tritide radioisotope heat source development : palladium-coated titanium hydriding kinetics and tritium loading tests.

    SciTech Connect (OSTI)

    Van Blarigan, Peter; Shugard, Andrew D.; Walters, R. Tom

    2012-01-01

    We have found that a 180 nm palladium coating enables titanium to be loaded with hydrogen isotopes without the typical 400-500 C vacuum activation step. The hydriding kinetics of Pd coated Ti can be described by the Mintz-Bloch adherent film model, where the rate of hydrogen absorption is controlled by diffusion through an adherent metal-hydride layer. Hydriding rate constants of Pd coated and vacuum activated Ti were found to be very similar. In addition, deuterium/tritium loading experiments were done on stacks of Pd coated Ti foil in a representative-size radioisotope heat source vessel. The experiments demonstrated that such a vessel could be loaded completely, at temperatures below 300 C, in less than 10 hours, using existing department-of-energy tritium handling infrastructure.

  6. Method for converting uranium oxides to uranium metal

    DOE Patents [OSTI]

    Duerksen, Walter K. (Norris, TN)

    1988-01-01

    A process is described for converting scrap and waste uranium oxide to uranium metal. The uranium oxide is sequentially reduced with a suitable reducing agent to a mixture of uranium metal and oxide products. The uranium metal is then converted to uranium hydride and the uranium hydride-containing mixture is then cooled to a temperature less than -100.degree. C. in an inert liquid which renders the uranium hydride ferromagnetic. The uranium hydride is then magnetically separated from the cooled mixture. The separated uranium hydride is readily converted to uranium metal by heating in an inert atmosphere. This process is environmentally acceptable and eliminates the use of hydrogen fluoride as well as the explosive conditions encountered in the previously employed bomb-reduction processes utilized for converting uranium oxides to uranium metal.

  7. Empirical and physics based mathematical models of uranium hydride decomposition kinetics with quantified uncertainties.

    SciTech Connect (OSTI)

    Salloum, Maher N.; Gharagozloo, Patricia E.

    2013-10-01

    Metal particle beds have recently become a major technique for hydrogen storage. In order to extract hydrogen from such beds, it is crucial to understand the decomposition kinetics of the metal hydride. We are interested in obtaining a a better understanding of the uranium hydride (UH3) decomposition kinetics. We first developed an empirical model by fitting data compiled from different experimental studies in the literature and quantified the uncertainty resulting from the scattered data. We found that the decomposition time range predicted by the obtained kinetics was in a good agreement with published experimental results. Secondly, we developed a physics based mathematical model to simulate the rate of hydrogen diffusion in a hydride particle during the decomposition. We used this model to simulate the decomposition of the particles for temperatures ranging from 300K to 1000K while propagating parametric uncertainty and evaluated the kinetics from the results. We compared the kinetics parameters derived from the empirical and physics based models and found that the uncertainty in the kinetics predicted by the physics based model covers the scattered experimental data. Finally, we used the physics-based kinetics parameters to simulate the effects of boundary resistances and powder morphological changes during decomposition in a continuum level model. We found that the species change within the bed occurring during the decomposition accelerates the hydrogen flow by increasing the bed permeability, while the pressure buildup and the thermal barrier forming at the wall significantly impede the hydrogen extraction.

  8. Activated Aluminum Hydride Hydrogen Storage Compositions - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Startup America Startup America Hydrogen and Fuel Cell Hydrogen and Fuel Cell Find More Like This Return to Search Activated Aluminum Hydride Hydrogen Storage Compositions Brookhaven National Laboratory Contact BNL About This Technology Publications: PDF Document Publication Alane for Hydrogen Storage and Delivery - Accelerating Innovation Webinar Presentation - June 2012 (7,079 KB) <p> Schematic representation of &nbsp;mechanical alloying reaction during ball

  9. High Resolution Neutron Radiography and Tomography of Hydrided Zircaloy-4 Cladding Materials

    SciTech Connect (OSTI)

    Smith, Tyler S; Bilheux, Hassina Z; Ray, Holly B; Bilheux, Jean-Christophe; Yan, Yong

    2015-01-01

    Neutron radiography for hydrogen analysis was performed with several Zircaloy-4 cladding samples with controlled hydrogen concentrations up to 1100 ppm. Hydrogen charging was performed in a process tube that was heated to facilitate hydrogen absorption by the metal. A correlation between the hydrogen concentration in the hydrided tubes and the neutron intensity was established, by which hydrogen content can be determined precisely in a small area (55 m x 55 m). Radiography analysis was also performed to evaluate the heating rate and its correlation with the hydrogen distribution through hydrided materials. In addition to radiography analysis, tomography experiments were performed on Zircaloy-4 tube samples to study the local hydrogen distribution. Through tomography analysis a 3D reconstruction of the tube was evaluated in which an uneven hydrogen distribution in the circumferential direction can be observed.

  10. Neutron Irradiation of Hydrided Cladding Material in HFIR Summary...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (HFIR). Irradiation of the capsules was conducted for post-irradiation examination (PIE) metallography. PDF icon Neutron Irradiation of Hydrided Cladding Material in HFIR...

  11. Documentation of Hybrid Hydride Model for Incorporation into...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    This report documents the development, demonstration and validation of a mesoscale, microstructural evolution model for simulation of zirconium hydride d-ZrH1.5 precipitation in ...

  12. Complex Hydrides-A New Frontier for Future Energy Applications...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    physics and chemistry of complex hydrides, X-ray diffraction (XRD), high-resolution solid-state nuclear magnetic resonance (NMR), electron microscopy, and first-principles...

  13. Method of making crack-free zirconium hydride

    DOE Patents [OSTI]

    Sullivan, Richard W. (Denver, CO)

    1980-01-01

    Crack-free hydrides of zirconium and zirconium-uranium alloys are produced by alloying the zirconium or zirconium-uranium alloy with beryllium, or nickel, or beryllium and scandium, or nickel and scandium, or beryllium and nickel, or beryllium, nickel and scandium and thereafter hydriding.

  14. Highly Concentrated Palladium Hydrides/Deuterides; Theory

    SciTech Connect (OSTI)

    Papaconstantopoulos, Dimitrios

    2013-11-26

    Accomplishments are reported in these areas: tight-binding molecular dynamics study of palladium; First-principles calculations and tight-binding molecular dynamics simulations of the palladium-hydrogen system; tight-binding studies of bulk properties and hydrogen vacancies in KBH{sub 4}; tight-binding study of boron structures; development of angular dependent potentials for Pd-H; and density functional and tight-binding calculations for the light-hydrides NaAlH4 and NaBH4

  15. In-Bed Accountability Development for a Passively Cooled, Electrically Heated Hydride (PACE) Bed

    SciTech Connect (OSTI)

    Klein, J.E.

    2005-07-15

    A nominal 1500 STP-L PAssively Cooled, Electrically heated hydride (PACE) Bed has been developed for implementation into a new Savannah River Site tritium project. The 1.2 meter (four-foot) long process vessel contains on internal 'U-tube' for tritium In-Bed Accountability (IBA) measurements. IBA will be performed on six, 12.6 kg production metal hydride storage beds.IBA tests were done on a prototype bed using electric heaters to simulate the radiolytic decay of tritium. Tests had gas flows from 10 to 100 SLPM through the U-tube or 100 SLPM through the bed's vacuum jacket. IBA inventory measurement errors at the 95% confidence level were calculated using the correlation of IBA gas temperature rise, or (hydride) bed temperature rise above ambient temperature, versus simulated tritium inventory.Prototype bed IBA inventory errors at 100 SLPM were the largest for gas flows through the vacuum jacket: 15.2 grams for the bed temperature rise and 11.5 grams for the gas temperature rise. For a 100 SLPM U-tube flow, the inventory error was 2.5 grams using bed temperature rise and 1.6 grams using gas temperature rise. For 50 to 100 SLPM U-tube flows, the IBA gas temperature rise inventory errors were nominally one to two grams that increased above four grams for flows less than 50 SLPM. For 50 to 100 SLPM U-tube flows, the IBA bed temperature rise inventory errors were greater than the gas temperature rise errors, but similar errors were found for both methods at gas flows of 20, 30, and 40 SLPM.Electric heater IBA tests were done for six production hydride beds using a 45 SLPM U-tube gas flow. Of the duplicate runs performed on these beds, five of the six beds produced IBA inventory errors of approximately three grams: consistent with results obtained in the laboratory prototype tests.

  16. In-Bed Accountability Development for a Passively Cooled, Electrically Heated Hydride (PACE) Bed

    SciTech Connect (OSTI)

    KLEIN, JAMES

    2004-10-12

    A nominal 1500 STP-L PAssively Cooled, Electrically heated hydride (PACE) Bed has been developed for implementation into a new Savannah River Site tritium project. The 1.2 meter (four-foot) long process vessel contains an internal ''U-tube'' for tritium In-Bed Accountability (IBA) measurements. IBA will be performed on six, 12.6 kg production metal hydride storage beds. IBA tests were done on a prototype bed using electric heaters to simulate the radiolytic decay of tritium. Tests had gas flows from 10 to 100 SLPM through the U-tube or 100 SLPM through the bed's vacuum jacket. IBA inventory measurement errors at the 95 percent confidence level were calculated using the correlation of IBA gas temperature rise, or (hydride) bed temperature rise above ambient temperature, versus simulated tritium inventory. Prototype bed IBA inventory errors at 100 SLPM were the largest for gas flows through the vacuum jacket: 15.2 grams for the bed temperature rise and 11.5 grams for the gas temperature rise. For a 100 SLPM U-tube flow, the inventory error was 2.5 grams using bed temperature rise and 1.6 grams using gas temperature rise. For 50 to 100 SLPM U-tube flows, the IBA gas temperature rise inventory errors were nominally one to two grams that increased above four grams for flows less than 50 SLPM. For 50 to 100 SLPM U-tube flows, the IBA bed temperature rise inventory errors were greater than the gas temperature rise errors, but similar errors were found for both methods at gas flows of 20, 30, and 40 SLPM. Electric heater IBA tests were done for six production hydride beds using a 45 SLPM U-tube gas flow. Of the duplicate runs performed on these beds, five of the six beds produced IBA inventory errors of approximately three grams: consistent with results obtained in the laboratory prototype tests.

  17. Metallic Inks for Solar Cells: Cooperative Research and Development Final Report, CRADA Number CRD-10-370

    SciTech Connect (OSTI)

    van Hest, M.

    2013-04-01

    This document describes the statement of work for National Renewable Energy Laboratory (NREL) as a subcontractor for Applied Nanotech, Inc. (ANI) for the Phase II SBIR contract with the Department of Energy to build silicon solar cells using non-contact printed, nanoparticle-based metallic inks. The conductive inks are based upon ANI's proprietary method for nanoparticle dispersion. The primary inks under development are aluminum for silicon solar cell back plane contacts and copper for top interdigitated contacts. The current direction of silicon solar cell technology is to use thinner silicon wafers. The reduction in wafer thickness reduces overall material usage and can increase efficiency. These thin silicon wafers are often very brittle and normal methods used for conductive feed line application, such as screen-printing, are detrimental. The Phase II program will be focused on materials development for metallic inks that can be applied to a silicon solar cell using non-contact methods. Uniform BSF (Back Surface Field) formation will be obtained by optimizing ink formulation and curing conditions to improve cell efficiency.

  18. Electronic structure and crystal phase stability of palladium hydrides

    SciTech Connect (OSTI)

    Houari, Abdesalem; Matar, Samir F.; Eyert, Volker

    2014-11-07

    The results of electronic structure calculations for a variety of palladium hydrides are presented. The calculations are based on density functional theory and used different local and semilocal approximations. The thermodynamic stability of all structures as well as the electronic and chemical bonding properties are addressed. For the monohydride, taking into account the zero-point energy is important to identify the octahedral Pd-H arrangement with its larger voids and, hence, softer hydrogen vibrational modes as favorable over the tetrahedral arrangement as found in the zincblende and wurtzite structures. Stabilization of the rocksalt structure is due to strong bonding of the 4d and 1s orbitals, which form a characteristic split-off band separated from the main d-band group. Increased filling of the formerly pure d states of the metal causes strong reduction of the density of states at the Fermi energy, which undermines possible long-range ferromagnetic order otherwise favored by strong magnetovolume effects. For the dihydride, octahedral Pd-H arrangement as realized, e.g., in the pyrite structure turns out to be unstable against tetrahedral arrangement as found in the fluorite structure. Yet, from both heat of formation and chemical bonding considerations, the dihydride turns out to be less favorable than the monohydride. Finally, the vacancy ordered defect phase Pd{sub 3}H{sub 4} follows the general trend of favoring the octahedral arrangement of the rocksalt structure for Pd:H ratios less or equal to one.

  19. Isotope exchange kinetics in metal hydrides I : TPLUG model.

    SciTech Connect (OSTI)

    Larson, Rich; James, Scott Carlton; Nilson, Robert H.

    2011-05-01

    A one-dimensional isobaric reactor model is used to simulate hydrogen isotope exchange processes taking place during flow through a powdered palladium bed. This simple model is designed to serve primarily as a platform for the initial development of detailed chemical mechanisms that can then be refined with the aid of more complex reactor descriptions. The one-dimensional model is based on the Sandia in-house code TPLUG, which solves a transient set of governing equations including an overall mass balance for the gas phase, material balances for all of the gas-phase and surface species, and an ideal gas equation of state. An energy equation can also be solved if thermodynamic properties for all of the species involved are known. The code is coupled with the Chemkin package to facilitate the incorporation of arbitrary multistep reaction mechanisms into the simulations. This capability is used here to test and optimize a basic mechanism describing the surface chemistry at or near the interface between the gas phase and a palladium particle. The mechanism includes reversible dissociative adsorptions of the three gas-phase species on the particle surface as well as atomic migrations between the surface and the bulk. The migration steps are more general than those used previously in that they do not require simultaneous movement of two atoms in opposite directions; this makes possible the creation and destruction of bulk vacancies and thus allows the model to account for variations in the bulk stoichiometry with isotopic composition. The optimization code APPSPACK is used to adjust the mass-action rate constants so as to achieve the best possible fit to a given set of experimental data, subject to a set of rigorous thermodynamic constraints. When data for nearly isothermal and isobaric deuterium-to-hydrogen (D {yields} H) and hydrogen-to-deuterium (H {yields} D) exchanges are fitted simultaneously, results for the former are excellent, while those for the latter show pronounced deviations at long times. These discrepancies can be overcome by postulating the presence of a surface poison such as carbon monoxide, but this explanation is highly speculative. When the method is applied to D {yields} H exchanges intentionally poisoned by known amounts of CO, the fitting results are noticeably degraded from those for the nominally CO-free system but are still tolerable. When TPLUG is used to simulate a blowdown-type experiment, which is characterized by large and rapid changes in both pressure and temperature, discrepancies are even more apparent. Thus, it can be concluded that the best use of TPLUG is not in simulating realistic exchange scenarios, but in extracting preliminary estimates for the kinetic parameters from experiments in which variations in temperature and pressure are intentionally minimized.

  20. Reversible Metal Hydride Thermal Energy Storage for High Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    This presentation was delivered at the SunShot Concentrating Solar Power (CSP) Program Review 2013, held April 23-25, 2013 near Phoenix, Arizona. PDF icon cspreviewmeeting042313...

  1. Proposed Virtual Center for Excellence for Metal Hydride Development

    Broader source: Energy.gov [DOE]

    Presentation from the Hydrogen Storage Pre-Solicitation Meeting held June 19, 2003 in Washington, DC.

  2. Final Report for the DOE Metal Hydride Center of Excellence

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... on Future High-Priority R&D Directions ... Figure 1. Sandia MHCoE Management Team (L-R): Director ... Physical Review B, Journal of the American Chemical ...

  3. Electronic structure of metallic glasses

    SciTech Connect (OSTI)

    Oelhafen, P.; Lapka, R.; Gubler, U.; Krieg, J.; DasGupta, A.; Guentherodt, H.J.; Mizoguchi, T.; Hague, C.; Kuebler, J.; Nagel, S.R.

    1981-01-01

    This paper is organized in six sections and deals with (1) the glassy transition metal alloys, their d-band structure, the d-band shifts on alloying and their relation to the alloy heat of formation (..delta..H) and the glass forming ability, (2) the glass to crystal phase transition viewed by valence band spectroscopy, (3) band structure calculations, (4) metallic glasses prepared by laser glazing, (5) glassy normal metal alloys, and (6) glassy hydrides.

  4. Hydrogen storage in sodium aluminum hydride.

    SciTech Connect (OSTI)

    Ozolins, Vidvuds; Herberg, J.L.; McCarty, Kevin F.; Maxwell, Robert S.; Stumpf, Roland Rudolph; Majzoub, Eric H.

    2005-11-01

    Sodium aluminum hydride, NaAlH{sub 4}, has been studied for use as a hydrogen storage material. The effect of Ti, as a few mol. % dopant in the system to increase kinetics of hydrogen sorption, is studied with respect to changes in lattice structure of the crystal. No Ti substitution is found in the crystal lattice. Electronic structure calculations indicate that the NaAlH{sub 4} and Na{sub 3}AlH{sub 6} structures are complex-ionic hydrides with Na{sup +} cations and AlH{sub 4}{sup -} and AlH{sub 6}{sup 3-} anions, respectively. Compound formation studies indicate the primary Ti-compound formed when doping the material at 33 at. % is TiAl{sub 3} , and likely Ti-Al compounds at lower doping rates. A general study of sorption kinetics of NaAlH{sub 4}, when doped with a variety of Ti-halide compounds, indicates a uniform response with the kinetics similar for all dopants. NMR multiple quantum studies of solution-doped samples indicate solvent interaction with the doped alanate. Raman spectroscopy was used to study the lattice dynamics of NaAlH{sub 4}, and illustrated the molecular ionic nature of the lattice as a separation of vibrational modes between the AlH{sub 4}{sup -} anion-modes and lattice-modes. In-situ Raman measurements indicate a stable AlH{sub 4}{sup -} anion that is stable at the melting temperature of NaAlH{sub 4}, indicating that Ti-dopants must affect the Al-H bond strength.

  5. Two plateaux for palladium hydride and the effect of helium from tritium decay on the desorption plateau pressure for palladium tritide

    SciTech Connect (OSTI)

    Walters, R.T.; Lee, M.W. )

    1991-10-01

    Two plateaux are observed in the desorption isotherm for palladium hydride: a lower plateau pressure for a hydrogen/metal atom ratio (H/M) less than about 0.3 and a slightly higher plateau pressure for H/M greater than about 0.3. This higher pressure corresponds to the reported pressure for palladium hydride. These observations were made for a large surface area palladium powder exposed to both protium and tritium. Helium buildup form tritium decay decreases the lower plateau pressure but does not affect the observations for H/M greater than about 0.3. In this paper, a multiple-energy hydrogen site occupancy model is proposed to explain qualitatively both the dual plateau and the helium effect in palladium hydride.

  6. Production of Hydrogen by Electrocatalysis: Making the H-H Bond by Combining Protons and Hydrides

    SciTech Connect (OSTI)

    Bullock, R. Morris; Appel, Aaron M.; Helm, Monte L.

    2014-03-25

    Generation of hydrogen by reduction of two protons by two electrons can be catalysed by molecular electrocatalysts. Determination of the thermodynamic driving force for elimination of H2 from molecular complexes is important for the rational design of molecular electrocatalysts, and allows the design of metal complexes of abundant, inexpensive metals rather than precious metals (“Cheap Metals for Noble Tasks”). The rate of H2 evolution can be dramatically accelerated by incorporating pendant amines into diphosphine ligands. These pendant amines in the second coordination sphere function as protons relays, accelerating intramolecular and intermolecular proton transfer reactions. The thermodynamics of hydride transfer from metal hydrides and the acidity of protonated pendant amines (pKa of N-H) contribute to the thermodynamics of elimination of H2; both of the hydricity and acidity can be systematically varied by changing the substituents on the ligands. A series of Ni(II) electrocatalysts with pendant amines have been developed. In addition to the thermochemical considerations, the catalytic rate is strongly influenced by the ability to deliver protons to the correct location of the pendant amine. Protonation of the amine endo to the metal leads to the N-H being positioned appropriately to favor rapid heterocoupling with the M-H. Designing ligands that include proton relays that are properly positioned and thermodynamically tuned is a key principle for molecular electrocatalysts for H2 production as well as for other multi-proton, multi-electron reactions important for energy conversions. The research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for DOE.

  7. Effects of outgassing of loader chamber walls on hydriding of...

    Office of Scientific and Technical Information (OSTI)

    gas pressure. Complete process data for (1) a copper-(1.83 wt. %)beryllium wet hydrogen fired passivated (600 C-1 h) externally heated pipe hydriding chamber are reported....

  8. Method of selective reduction of polyhalosilanes with alkyltin hydrides

    DOE Patents [OSTI]

    Sharp, Kenneth G.; D'Errico, John J.

    1989-01-01

    The invention relates to the selective and stepwise reduction of polyhalosilanes by reacting at room temperature or below with alkyltin hydrides without the use of free radical intermediates. Alkyltin hydrides selectively and stepwise reduce the Si--Br, Si--Cl, or Si--I bonds while leaving intact any Si--F bonds. When two or more different halogens are present on the polyhalosilane, the halogen with the highest atomic weight is preferentially reduced.

  9. Method of selective reduction of halodisilanes with alkyltin hydrides

    DOE Patents [OSTI]

    D'Errico, John J.; Sharp, Kenneth G.

    1989-01-01

    The invention relates to the selective and sequential reduction of halodisilanes by reacting these compounds at room temperature or below with trialkyltin hydrides or dialkyltin dihydrides without the use of free radical intermediates. The alkyltin hydrides selectively and sequentially reduce the Si-Cl, Si-Br or Si-I bonds while leaving intact the Si-Si and Si-F bonds present.

  10. Transition Metal Switchable Mirror

    ScienceCinema (OSTI)

    None

    2013-05-29

    The switchable-mirrors technology was developed by Tom Richardson and Jonathan Slack of Berkeley Lab's Environmental Energy Technologies Division. By using transition metals rather than the rare earth metals used in the first metal-hydride switchable mirrors, Richardson and Slack were able to lower the cost and simplify the manufacturing process. Energy performance is improved as well, because the new windows can reflect or transmit both visible and infrared light. Besides windows for offices and homes, possible applications include automobile sunroofs, signs and displays, aircraft windows, and spacecraft. More information at: http://windows.lbl.gov/materials/chromogenics/default.htm

  11. Transition Metal Switchable Mirror

    ScienceCinema (OSTI)

    None

    2010-01-08

    The switchable-mirrors technology was developed by Tom Richardson and Jonathan Slack of Berkeley Lab's Environmental Energy Technologies Division. By using transition metals rather than the rare earth metals used in the first metal-hydride switchable mirrors, Richardson and Slack were able to lower the cost and simplify the manufacturing process. Energy performance is improved as well, because the new windows can reflect or transmit both visible and infrared light. Besides windows for offices and homes, possible applications include automobile sunroofs, signs and displays, aircraft windows, and spacecraft.

  12. THE EFFECT OF 3HE ON LOW PRESSURE HYDRIDE ABSORPTION MEASUREMENTS WITH TRITIUM

    SciTech Connect (OSTI)

    Staack, G.; Klein, J.

    2011-01-20

    Absorption isotherm data exists for a wide variety of hydrogen-metal systems. When working with high purity gases, appropriately sized equipment, and hydrides with equilibrium pressures above several hundred Pa, data collection is relatively straightforward. Special consideration must be given to experiments involving low equilibrium pressure hydrides, as even sub-ppm levels of gas impurities can generate partial pressures many times greater than the equilibrium pressures to be measured. Tritium absorption experiments are further complicated by the continuous generation of helium-3. The time required to transfer and absorb a known quantity of tritium onto a sample ultimately limits the minimum pressure range that can be studied using the standard technique. Equations are presented which show the pressure of helium-3 in a sample cell based on the amount of tritium to be absorbed, the sample cell volume and temperature, and the decay time of tritium. Sample calculations for zirconium show that at 300 C, the estimated helium-3 pressure in the cell will be equal to the hydrogen absorption pressure after only milliseconds of tritium decay. An alternate method is presented that permits the collection of equilibrium data at pressures orders of magnitude lower than possible using a direct approach.

  13. THERMAL ENHANCEMENT CARTRIDGE HEATER MODIFIED TECH MOD TRITIUM HYDRIDE BED DEVELOPMENT PART I DESIGN AND FABRICATION

    SciTech Connect (OSTI)

    Klein, J.; Estochen, E.

    2014-03-06

    The Savannah River Site (SRS) tritium facilities have used 1{sup st} generation (Gen1) LaNi{sub 4.25}Al{sub 0.75} (LANA0.75) metal hydride storage beds for tritium absorption, storage, and desorption. The Gen1 design utilizes hot and cold nitrogen supplies to thermally cycle these beds. Second and 3{sup rd} generation (Gen2 and Gen3) storage bed designs include heat conducting foam and divider plates to spatially fix the hydride within the bed. For thermal cycling, the Gen2 and Gen 3 beds utilize internal electric heaters and glovebox atmosphere flow over the bed inside the bed external jacket for cooling. The currently installed Gen1 beds require replacement due to tritium aging effects on the LANA0.75 material, and cannot be replaced with Gen2 or Gen3 beds due to different designs of these beds. At the end of service life, Gen1 bed desorption efficiencies are limited by the upper temperature of hot nitrogen supply. To increase end-of-life desorption efficiency, the Gen1 bed design was modified, and a Thermal Enhancement Cartridge Heater Modified (TECH Mod) bed was developed. Internal electric cartridge heaters in the new design to improve end-of-life desorption, and also permit in-bed tritium accountability (IBA) calibration measurements to be made without the use of process tritium. Additional enhancements implemented into the TECH Mod design are also discussed.

  14. A Novel Zr-1Nb Alloy and a New Look at Hydriding

    SciTech Connect (OSTI)

    Robert D. Mariani; James I. Cole; Assel Aitkaliyeva

    2013-09-01

    A novel Zr-1Nb has begun development based on a working model that takes into account the hydrogen permeabilities for zirconium and niobium metals. The beta-Nb secondary phase particles (SPPs) in Zr-1Nb are believed to promote more rapid hydrogen dynamics in the alloy in comparison to other zirconium alloys. Furthermore, some hydrogen release is expected at the lower temperatures corresponding to outages when the partial pressure of H2 in the coolant is less. These characteristics lessen the negative synergism between corrosion and hydriding that is otherwise observed in cladding alloys without niobium. In accord with the working model, development of nanoscale precursors was initiated to enhance the performance of existing Zr-1Nb alloys. Their characteristics and properties can be compared to oxide-dispersion strengthened alloys, and material additions have been proposed to zirconium-based LWR cladding to guard further against hydriding and to fix the size of the SPPs for microstructure stability enhancements. A preparative route is being investigated that does not require mechanical alloying, and 10 nanometer molybdenum particles have been prepared which are part of the nanoscale precursors. If successful, the approach has implications for long term dry storage of used fuel and for new routes to nanoferritic and ODS alloys.

  15. Facile synthesis of Ba1-xKxFe?As? superconductors via hydride route

    SciTech Connect (OSTI)

    Zaikina, Julia V. [Univ. of California at Davis, Davis, CA (United States); Batuk, Maria [Univ. of Antwerp, Antwerp (Belgium); Abakumov, Artem M. [Univ. of Antwerp, Antwerp (Belgium); Navrotsky, Alexandra [Univ. of California at Davis, Davis, CA (United States); Kauzlarich, Susan M. [Univ. of California at Davis, Davis, CA (United States)

    2014-12-03

    We have developed a fast, easy, and scalable synthesis method for Ba1-xKxFe?As? (0 ? x ? 1) superconductors using hydrides BaH? and KH as a source of barium and potassium metals. Synthesis from hydrides provides better mixing and easier handling of the starting materials, consequently leading to faster reactions and/or lower synthesis temperatures. The reducing atmosphere provided by the evolved hydrogen facilitates preparation of oxygen-free powders. By a combination of methods we have shown that Ba1-xKxFe?As? obtained via hydride route has the same characteristics as when it is prepared by traditional solid-state synthesis. Refinement from synchrotron powder X-ray diffraction data confirms a linear dependence of unit cell parameters upon K content as well as the tetragonal to orthorhombic transition at low temperatures for compositions with x < 0.2. Magnetic measurements revealed dome-like dependence of superconducting transition temperature Tc upon K content with a maximum of 38 K for x close to 0.4. Electron diffraction and high-resolution high-angle annular dark-field scanning transmission electron microscopy indicates an absence of Ba/K ordering, while local inhomogeneity in the Ba/K distribution takes place at a scale of several angstroms along [110] crystallographic direction.

  16. Final Report: Metal Perhydrides for Hydrogen Storage

    SciTech Connect (OSTI)

    Hwang, J-Y.; Shi, S.; Hackney, S.; Swenson, D.; Hu, Y.

    2011-07-26

    Hydrogen is a promising energy source for the future economy due to its environmental friendliness. One of the important obstacles for the utilization of hydrogen as a fuel source for applications such as fuel cells is the storage of hydrogen. In the infrastructure of the expected hydrogen economy, hydrogen storage is one of the key enabling technologies. Although hydrogen possesses the highest gravimetric energy content (142 KJ/g) of all fuels, its volumetric energy density (8 MJ/L) is very low. It is desired to increase the volumetric energy density of hydrogen in a system to satisfy various applications. Research on hydrogen storage has been pursed for many years. Various storage technologies, including liquefaction, compression, metal hydride, chemical hydride, and adsorption, have been examined. Liquefaction and high pressure compression are not desired due to concerns related to complicated devices, high energy cost and safety. Metal hydrides and chemical hydrides have high gravimetric and volumetric energy densities but encounter issues because high temperature is required for the release of hydrogen, due to the strong bonding of hydrogen in the compounds. Reversibility of hydrogen loading and unloading is another concern. Adsorption of hydrogen on high surface area sorbents such as activated carbon and organic metal frameworks does not have the reversibility problem. But on the other hand, the weak force (primarily the van der Waals force) between hydrogen and the sorbent yields a very small amount of adsorption capacity at ambient temperature. Significant storage capacity can only be achieved at low temperatures such as 77K. The use of liquid nitrogen in a hydrogen storage system is not practical. Perhydrides are proposed as novel hydrogen storage materials that may overcome barriers slowing advances to a hydrogen fuel economy. In conventional hydrides, e.g. metal hydrides, the number of hydrogen atoms equals the total valence of the metal ions. One LiH molecule contains one hydrogen atom because the valence of a Li ion is +1. One MgH2 molecule contains two hydrogen atoms because the valence of a Mg ion is +2. In metal perhydrides, a molecule could contain more hydrogen atoms than expected based on the metal valance, i.e. LiH1+n and MgH2+n (n is equal to or greater than 1). When n is sufficiently high, there will be plenty of hydrogen storage capacity to meet future requirements. The existence of hydrogen clusters, Hn+ (n = 5, 7, 9, 11, 13, 15) and transition metal ion-hydrogen clusters, M+(H2)n (n = 1-6), such as Sc(H2)n+, Co(H2)n+, etc., have assisted the development of this concept. Clusters are not stable species. However, their existence stimulates our approach on using electric charges to enhance the hydrogen adsorption in a hydrogen storage system in this study. The experimental and modeling work to verify it are reported here. Experimental work included the generation of cold hydrogen plasma through a microwave approach, synthesis of sorbent materials, design and construction of lab devices, and the determination of hydrogen adsorption capacities on various sorbent materials under various electric field potentials and various temperatures. The results consistently show that electric potential enhances the adsorption of hydrogen on sorbents. NiO, MgO, activated carbon, MOF, and MOF and platinum coated activated carbon are some of the materials studied. Enhancements up to a few hundred percents have been found. In general, the enhancement increases with the electrical potential, the pressure applied, and the temperature lowered. Theoretical modeling of the hydrogen adsorption on the sorbents under the electric potential has been investigated with the density functional theory (DFT) approach. It was found that the interaction energy between hydrogen and sorbent is increased remarkably when an electric field is applied. This increase of binding energy offers a potential solution for DOE when looking for a compromise between chemisorption and physisorption for hydrogen storage. Bonding of chemisorption is too

  17. Plasma deposition of amorphous metal alloys

    DOE Patents [OSTI]

    Hays, Auda K. (Albuquerque, NM)

    1986-01-01

    Amorphous metal alloy coatings are plasma-deposited by dissociation of vapors of organometallic compounds and metalloid hydrides in the presence of a reducing gas, using a glow discharge. Tetracarbonylnickel, phosphine, and hydrogen constitute a typical reaction mixture of the invention, yielding a NiPC alloy.

  18. Light metal explosives and propellants

    DOE Patents [OSTI]

    Wood, Lowell L.; Ishikawa, Muriel Y.; Nuckolls, John H.; Pagoria, Phillip F.; Viecelli, James A.

    2005-04-05

    Disclosed herein are light metal explosives, pyrotechnics and propellants (LME&Ps) comprising a light metal component such as Li, B, Be or their hydrides or intermetallic compounds and alloys containing them and an oxidizer component containing a classic explosive, such as CL-20, or a non-explosive oxidizer, such as lithium perchlorate, or combinations thereof. LME&P formulations may have light metal particles and oxidizer particles ranging in size from 0.01 .mu.m to 1000 .mu.m.

  19. FEASIBILITY OF RECYCLING PLUTONIUM AND MINOR ACTINIDES IN LIGHT WATER REACTORS USING HYDRIDE FUEL

    SciTech Connect (OSTI)

    Greenspan, Ehud; Todreas, Neil; Taiwo, Temitope

    2009-03-10

    The objective of this DOE NERI program sponsored project was to assess the feasibility of improving the plutonium (Pu) and minor actinide (MA) recycling capabilities of pressurized water reactors (PWRs) by using hydride instead of oxide fuels. There are four general parts to this assessment: 1) Identifying promising hydride fuel assembly designs for recycling Pu and MAs in PWRs 2) Performing a comprehensive systems analysis that compares the fuel cycle characteristics of Pu and MA recycling in PWRs using the promising hydride fuel assembly designs identified in Part 1 versus using oxide fuel assembly designs 3) Conducting a safety analysis to assess the likelihood of licensing hydride fuel assembly designs 4) Assessing the compatibility of hydride fuel with cladding materials and water under typical PWR operating conditions Hydride fuel was found to offer promising transmutation characteristics and is recommended for further examination as a possible preferred option for recycling plutonium in PWRs.

  20. The Role of Impurities in the Complex Hydrides

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Impurities in the Complex Hydrides Eric H. Majzoub Center for Nanoscience Department of Physics University of Missouri - St. Louis Acknowledgements UMSL Xianfeng Liu, David Peaslee, Tim Mason, Dongxue Zhao, Gang Wang, Chris Carr, Waruni Jayawardana, Alyssa McFarlane, Henry Hamper, Hua Ning SNL Vitalie Stavila, Mark Allendorf, Lennie Klebanoff * Department of Energy EERE * Boeing * NASA Space grant Consortium 2 Objectives and Overview I. Fundamental Limitations - density of hydrogen and

  1. Documentation of Hybrid Hydride Model for Incorporation into Moose-Bison

    Office of Environmental Management (EM)

    and Validation Strategy | Department of Energy Documentation of Hybrid Hydride Model for Incorporation into Moose-Bison and Validation Strategy Documentation of Hybrid Hydride Model for Incorporation into Moose-Bison and Validation Strategy This report documents the development, demonstration and validation of a mesoscale, microstructural evolution model for simulation of zirconium hydride d-ZrH1.5 precipitation in the cladding of used nuclear fuels that may occur during long-term dry

  2. Advances in Design of the Next Generation Hydride Bed | Department of

    Office of Environmental Management (EM)

    Energy Design of the Next Generation Hydride Bed Advances in Design of the Next Generation Hydride Bed Presentation from the 32nd Tritium Focus Group Meeting held in Germantown, Maryland on April 23-25, 2013. PDF icon Advances in Design of the Next Generation Hydride Bed More Documents & Publications Tritium Aging Studies of LaNi4.15Al0.85 (LANA.85) Determination of In-Vitro Lung Solubility and Intake-To-Dose Conversion Factors for Tritiated LaNi4.25Al0.75 Hydride Safe Disposition of

  3. Combined on-board hydride slurry storage and reactor system and process for hydrogen-powered vehicles and devices

    DOE Patents [OSTI]

    Brooks, Kriston P; Holladay, Jamelyn D; Simmons, Kevin L; Herling, Darrell R

    2014-11-18

    An on-board hydride storage system and process are described. The system includes a slurry storage system that includes a slurry reactor and a variable concentration slurry. In one preferred configuration, the storage system stores a slurry containing a hydride storage material in a carrier fluid at a first concentration of hydride solids. The slurry reactor receives the slurry containing a second concentration of the hydride storage material and releases hydrogen as a fuel to hydrogen-power devices and vehicles.

  4. Chemical Hydrides for Hydrogen Storage in Fuel Cell Applications

    SciTech Connect (OSTI)

    Devarakonda, Maruthi N.; Brooks, Kriston P.; Ronnebro, Ewa; Rassat, Scot D.; Holladay, Jamelyn D.

    2012-04-16

    Due to its high hydrogen storage capacity (up to 19.6% by weight for the release of 2.5 molar equivalents of hydrogen gas) and its stability under typical ambient conditions, ammonia borane (AB) is a promising material for chemical hydrogen storage for fuel cell applications in transportation sector. Several systems models for chemical hydride materials such as solid AB, liquid AB and alane were developed and evaluated at PNNL to determine an optimal configuration that would meet the 2010 and future DOE targets for hydrogen storage. This paper presents an overview of those systems models and discusses the simulation results for various transient drive cycle scenarios.

  5. Electrochemical process and production of novel complex hydrides

    DOE Patents [OSTI]

    Zidan, Ragaiy

    2013-06-25

    A process of using an electrochemical cell to generate aluminum hydride (AlH.sub.3) is provided. The electrolytic cell uses a polar solvent to solubilize NaAlH.sub.4. The resulting electrochemical process results in the formation of AlH.sub.3. The AlH.sub.3 can be recovered and used as a source of hydrogen for the automotive industry. The resulting spent aluminum can be regenerated into NaAlH.sub.4 as part of a closed loop process of AlH.sub.3 generation.

  6. Microstructure and hydriding studies of AB/sub 5/ hydrogen storage compounds. Final report

    SciTech Connect (OSTI)

    Goodell, P.D.; Sandrock, G.D.; Huston, E.L.

    1980-01-01

    New data on the microstructure, pressure-composition-temperature, and absorption/desorption kinetics of AB/sub 5/ metal hydrides are presented. The most significant result to emerge from the investigation is that many of the AB/sub 5/ metal hydrides, especially the LaNi/sub 5/ related materials, show instantaneous absorption and desorption response in proportion to the amount of cooling or heating which is provided. Eight categories of materials were studied: reference alloys (LaNi/sub 5/, LaNi/sub 4/ /sub 9/Al/sub 0/ /sub 1/, LaNi/sub 3/Co/sub 2/); Ni second phase particles (LaNi/sub 5/ /sub 67/, LaNi/sub 7/, LaNi/sub 11/ /sub 3/); eutectoid microstructure (SmCo/sub 5/); other second phases (LaNi/sub 3/ /sub 8/Fe/sub 1/ /sub 2/, LaNi/sub 3/ /sub 5/Cr/sub 1/ /sub 5/, LaNi/sub 4/Cr, LaNi/sub 4/Si; LaNi/sub 4/Sn, MNi/sub 4/Sn, MNi/sub 4/ /sub 3/Al/sub 0/ /sub 7/); substitutional elements (LaNi/sub 4/Cu, LaNi/sub 4/ /sub 5/Pd/sub 0/ /sub 5/, LaNi/sub 4/ /sub 7/Sn/sub 0/ /sub 3/, LaNi/sub 4/ /sub 8/C/sub 0/ /sub 2/, MNi/sub 4/ /sub 3/Mn/sub 0/ /sub 7/); surface active elements (LaNi/sub 4/ /sub 8/B/sub 0/ /sub 2/, LaNi/sub 4/ /sub 9/S/sub 0/ /sub 1/, LaNi/sub 4/ /sub 9/Se/sub 0/ /sub 1/); large diameter atom substitutions (Mg/sub 0/ /sub 1/La/sub 0/ /sub 9/Ni/sub 5/, Ca/sub 0/ /sub 2/La/sub 0/ /sub 8/Ni/sub 5/, Sr/sub 0/ /sub 2/La/sub 0/ /sub 8/Ni/sub 5/, Ba/sub 0/ /sub 2/La/sub 0/ /sub 8/Ni/sub 5/); other compositions (LaNi/sub 3/); and Pd plating (electroless plated samples and mechanically alloyed specimens).

  7. Steric Effect for Proton, Hydrogen-Atom, andHydride Transfer Reactions with Geometric Isomers of NADH-Model Ruthenium Complexes

    SciTech Connect (OSTI)

    Fujita E.; Cohen, B.W.; Polyansky, D.E.; Achord, P.; Cabelli, D.; Muckerman, J.T.; Tanaka, K.; Thummel, R.P.; Zong, R.

    2012-01-01

    Two isomers, [Ru(1)]{sup 2+} (Ru = Ru(bpy){sub 2}, bpy = 2,2{prime}-bipyridine, 1 = 2-(pyrid-2{prime}-yl)-1-azaacridine) and [Ru(2)]{sup 2+} (2 = 3-(pyrid-2{prime}-yl)-4-azaacridine), are bio-inspired model compounds containing the nicotinamide functionality and can serve as precursors for the photogeneration of C-H hydrides for studying reactions pertinent to the photochemical reduction of metal-C{sub 1} complexes and/or carbon dioxide. While it has been shown that the structural differences between the azaacridine ligands of [Ru(1)]{sup 2+} and [Ru(2)]{sup 2+} have a significant effect on the mechanism of formation of the hydride donors, [Ru(1HH)]{sup 2+} and [Ru(2HH)]{sup 2+}, in aqueous solution, we describe the steric implications for proton, net-hydrogen-atom and net-hydride transfer reactions in this work. Protonation of [Ru(2{sup {sm_bullet}-})]{sup +} in aprotic and even protic media is slow compared to that of [Ru(1{sup {sm_bullet}-})]{sup +}. The net hydrogen-atom transfer between *[Ru(1)]{sup 2+} and hydroquinone (H{sub 2}Q) proceeds by one-step EPT, rather than stepwise electron-proton transfer. Such a reaction was not observed for *[Ru(2)]{sup 2+} because the non-coordinated N atom is not easily available for an interaction with H{sub 2}Q. Finally, the rate of the net hydride ion transfer from [Ru(1HH)]{sup 2+} to [Ph{sub 3}C]{sup +} is significantly slower than that of [Ru(2HH)]{sup 2+} owing to steric congestion at the donor site.

  8. Method of generating hydrogen-storing hydride complexes

    DOE Patents [OSTI]

    Srinivasan, Sesha S; Niemann, Michael U; Goswami, D. Yogi; Stefanakos, Elias K

    2013-05-14

    A ternary hydrogen storage system having a constant stoichiometric molar ratio of LiNH.sub.2:MgH.sub.2:LiBH.sub.4 of 2:1:1. It was found that the incorporation of MgH.sub.2 particles of approximately 10 nm to 20 nm exhibit a lower initial hydrogen release temperature of 150.degree. C. Furthermore, it is observed that the particle size of LiBNH quaternary hydride has a significant effect on the hydrogen sorption concentration with an optimum size of 28 nm. The as-synthesized hydrides exhibit two main hydrogen release temperatures, one around 160.degree. C. and the other around 300.degree. C., with the main hydrogen release temperature reduced from 310.degree. C. to 270.degree. C., while hydrogen is first reversibly released at temperatures as low as 150.degree. C. with a total hydrogen capacity of 6 wt. % to 8 wt. %. Detailed thermal, capacity, structural and microstructural properties have been demonstrated and correlated with the activation energies of these materials.

  9. Request Number:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3023307 Name: Madeleine Brown Organization: nJa Address: --- -------- -------- -- Country: Phone Number: United States Fax Number: n/a E-mail: --- -------- --------_._------ --- Reasonably Describe Records Description: Please send me a copy of the emails and records relating to the decision to allow the underage son of Bill Gates to tour Hanford in June 2010. Please also send the emails and records that justify the Department of Energy to prevent other minors from visiting B Reactor. Optional

  10. Request Number:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1074438 Name: Gayle Cooper Organization: nla Address: _ Country: United States Phone Number: Fax Number: nla E-mail: . ~===--------- Reasonably Describe Records Description: Information pertaining to the Department of Energy's cost estimate for reinstating pension benefit service years to the Enterprise Company (ENCO) employees who are active plan participants in the Hanford Site Pension Plan. This cost estimate was an outcome of the DOE's Worker Town Hall Meetings held on September 17-18, 2009.

  11. Reduction of metal oxides through mechanochemical processing

    DOE Patents [OSTI]

    Froes, Francis H. (Moscow, ID); Eranezhuth, Baburaj G. (Moscow, ID); Senkov, Oleg N. (Moscow, ID)

    2000-01-01

    The low temperature reduction of a metal oxide using mechanochemical processing techniques. The reduction reactions are induced mechanically by milling the reactants. In one embodiment of the invention, titanium oxide TiO.sub.2 is milled with CaH.sub.2 to produce TiH.sub.2. Low temperature heat treating, in the range of 400.degree. C. to 700.degree. C., can be used to remove the hydrogen in the titanium hydride.

  12. Neutron Irradiation of Hydrided Cladding Material in HFIR Summary of Initial Activities

    Broader source: Energy.gov [DOE]

    Irradiation is known to have a significant impact on the properties and performance of Zircaloy cladding and structural materials (material degradation processes, e.g., effects of hydriding).  This...

  13. First-principles calculations of niobium hydride formation in superconducting radio-frequency cavities

    SciTech Connect (OSTI)

    Ford, Denise C.; Cooley, Lance D.; Seidman, David N.

    2013-09-01

    Niobium hydride is suspected to be a major contributor to degradation of the quality factor of niobium superconducting radio-frequency (SRF) cavities. In this study, we connect the fundamental properties of hydrogen in niobium to SRF cavity performance and processing. We modeled several of the niobium hydride phases relevant to SRF cavities and present their thermodynamic, electronic, and geometric properties determined from calculations based on density-functional theory. We find that the absorption of hydrogen from the gas phase into niobium is exothermic and hydrogen becomes somewhat anionic. The absorption of hydrogen by niobium lattice vacancies is strongly preferred over absorption into interstitial sites. A single vacancy can accommodate six hydrogen atoms in the symmetrically equivalent lowest-energy sites and additional hydrogen in the nearby interstitial sites affected by the strain field: this indicates that a vacancy can serve as a nucleation center for hydride phase formation. Small hydride precipitates may then occur near lattice vacancies upon cooling. Vacancy clusters and extended defects should also be enriched in hydrogen, potentially resulting in extended hydride phase regions upon cooling. We also assess the phase changes in the niobium-hydrogen system based on charge transfer between niobium and hydrogen, the strain field associated with interstitial hydrogen, and the geometry of the hydride phases. The results of this study stress the importance of not only the hydrogen content in niobium, but also the recovery state of niobium for the performance of SRF cavities.

  14. Documentation of Hybrid Hydride Model for Incorporation into Moose-Bison and Validation Strategy.

    SciTech Connect (OSTI)

    Weck, Philippe F; Tikare, Veena; Schultz, Peter Andrew; Clark, B; Mitchell, J; Glazoff, Michael V.; Homer, Eric R.

    2014-10-01

    This report documents the development, demonstration and validation of a mesoscale, microstructural evolution model for simulation of zirconium hydride ?-ZrH{sub 1.5} precipitation in the cladding of used nuclear fuels that may occur during long-term dry storage. While the Zr-based claddings are manufactured free of any hydrogen, they absorb hydrogen during service, in the reactor by a process commonly termed hydrogen pick-up. The precipitation and growth of zirconium hydrides during dry storage is one of the most likely fuel rod integrity failure mechanisms either by embrittlement or delayed hydride cracking of the cladding (Hanson et al., 2011). While the phenomenon is well documented and identified as a potential key failure mechanism during long-term dry storage (Birk et al., 2012 and NUREG/CR-7116), the ability to actually predict the formation of hydrides is poor. The model being documented in this work is a computational capability for the prediction of hydride formation in different claddings of used nuclear fuels. This work supports the Used Fuel Disposition Research and Development Campaign in assessing the structural engineering performance of the cladding during and after long-term dry storage. In this work, a model to numerically simulate hydride precipitation at the microstructural scale, in a wide variety of Zr-based claddings, under dry-storage conditions is being developed. It will be used to aid in the evaluation of the mechanical integrity of used fuel rods during dry storage and transportation by providing the structural conditions from the microstructural scale to the continuum scale to engineering component scale models to predict if the used fuel rods will perform without failure under normal and off-normal conditions. The microstructure, especially, the hydride structure is thought to be a primary determinant of cladding failure, thus this component of UFDs storage and transportation analysis program is critical. The model development, application and validation of the model are documented and the limitations of the current model are discussed. The model has been shown to simulate hydride precipitation in Zircaloy-4 cladding with correct morphology, thermodynamics and kinetics. An unexpected insight obtained from simulations hydride formation in Zircaloy-4 is that small (sub-micron) precipitates need to order themselves to form the larger hydrides typically described as radially-reoriented precipitates. A limitation of this model is that it does not currently solve the stress state that forms dynamically in the precipitate or matrix surrounding the precipitate. A method to overcome the limitations is suggested and described in detail. The necessary experiments to provide key materials physics and to validate the model are also recommended.

  15. The affect of erbium hydride on the conversion efficience to accelerated protons from ultra-shsort pulse laser irradiated foils

    SciTech Connect (OSTI)

    Offermann, D

    2008-09-04

    This thesis work explores, experimentally, the potential gains in the conversion efficiency from ultra-intense laser light to proton beams using erbium hydride coatings. For years, it has been known that contaminants at the rear surface of an ultra-intense laser irradiated thin foil will be accelerated to multi-MeV. Inertial Confinement Fusion fast ignition using proton beams as the igniter source requires of about 10{sup 16} protons with an average energy of about 3MeV. This is far more than the 10{sup 12} protons available in the contaminant layer. Target designs must include some form of a hydrogen rich coating that can be made thick enough to support the beam requirements of fast ignition. Work with computer simulations of thin foils suggest the atomic mass of the non-hydrogen atoms in the surface layer has a strong affect on the conversion efficiency to protons. For example, the 167amu erbium atoms will take less energy away from the proton beam than a coating using carbon with a mass of 12amu. A pure hydrogen coating would be ideal, but technologically is not feasible at this time. In the experiments performed for my thesis, ErH{sub 3} coatings on 5 {micro}m gold foils are compared with typical contaminants which are approximately equivalent to CH{sub 1.7}. It will be shown that there was a factor of 1.25 {+-} 0.19 improvement in the conversion efficiency for protons above 3MeV using erbium hydride using the Callisto laser. Callisto is a 10J per pulse, 800nm wavelength laser with a pulse duration of 200fs and can be focused to a peak intensity of about 5 x 10{sup 19}W/cm{sup 2}. The total number of protons from either target type was on the order of 10{sup 10}. Furthermore, the same experiment was performed on the Titan laser, which has a 500fs pulse duration, 150J of energy and can be focused to about 3 x 10{sup 20} W/cm{sup 2}. In this experiment 10{sup 12} protons were seen from both erbium hydride and contaminants on 14 {micro} m gold foils. Significant improvements were also observed but possibly because of the depletion of hydrogen in the contaminant layer case.

  16. Thermal Release of 3He from Tritium Aged LaNi4.25Al0.75 Hydride

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Staack, Gregory C.; Crowder, Mark L.; Klein, James E.

    2015-02-01

    Recently, the demand for He-3 has increased dramatically due to widespread use in nuclear nonproliferation, cryogenic, and medical applications. Essentially all of the world’s supply of He-3 is created by the radiolytic decay of tritium. The Savannah River Site Tritium Facilities (SRS-TF) utilizes LANA.75 in the tritium process to store hydrogen isotopes. The vast majority of He-3 “born” from tritium stored in LANA.75 is trapped in the hydride metal matrix. The SRS-TF has multiple LANA.75 tritium storage beds that have been retired from service with significant quantities of He-3 trapped in the metal. To support He-3 recovery, the Savannah Rivermore » National Laboratory (SRNL) conducted thermogravimetric analysis coupled with mass spectrometry (TGA-MS) on a tritium aged LANA.75 sample. TGA-MS testing was performed in an argon environment. Prior to testing, the sample was isotopically exchanged with deuterium to reduce residual tritium and passivated with air to alleviate pyrophoric concerns associated with handling the material outside of an inert glovebox. Analyses indicated that gas release from this sample was bimodal, with peaks near 220 and 490°C. The first peak consisted of both He-3 and residual hydrogen isotopes, the second was primarily He-3. The bulk of the gas was released by 600 °C« less

  17. White Paper Summary of 2nd ASTM International Workshop on Hydrides in Zirconium Alloy Cladding

    SciTech Connect (OSTI)

    Sindelar, R.; Louthan, M.; PNNL, B.

    2015-05-29

    This white paper recommends that ASTM International develop standards to address the potential impact of hydrides on the long term performance of irradiated zirconium alloys. The need for such standards was apparent during the 2nd ASTM International Workshop on Hydrides in Zirconium Alloy Cladding and Assembly Components, sponsored by ASTM International Committee C26.13 and held on June 10-12, 2014, in Jackson, Wyoming. The potentially adverse impacts of hydrogen and hydrides on the long term performance of irradiated zirconium-alloy cladding on used fuel were shown to depend on multiple factors such as alloy chemistry and processing, irradiation and post irradiation history, residual and applied stresses and stress states, and the service environment. These factors determine the hydrogen content and hydride morphology in the alloy, which, in turn, influence the response of the alloy to the thermo-mechanical conditions imposed (and anticipated) during storage, transport and disposal of used nuclear fuel. Workshop presentations and discussions showed that although hydrogen/hydride induced degradation of zirconium alloys may be of concern, the potential for occurrence and the extent of anticipated degradation vary throughout the nuclear industry because of the variations in hydrogen content, hydride morphology, alloy chemistry and irradiation conditions. The tools and techniques used to characterize hydrides and hydride morphologies and their impacts on material performance also vary. Such variations make site-to-site comparisons of test results and observations difficult. There is no consensus that a single material or system characteristic (e.g., reactor type, burnup, hydrogen content, end-of life stress, alloy type, drying temperature, etc.) is an effective predictor of material response during long term storage or of performance after long term storage. Multi-variable correlations made for one alloy may not represent the behavior of another alloy exposed to identical conditions and the material responses to thermo-mechanical exposures will be different depending on the materials and systems used. The discussions at the workshop showed several gaps in the standardization of processes and techniques necessary to assess the long term performance of irradiated zirconium alloy cladding during dry storage and transport. The development of, and adherence to, standards to help bridge these gaps will strengthen the technical basis for long term storage and post-storage operations, provide consistency across the nuclear industry, maximize the value of most observations, and enhance the understanding of behavioral differences among alloys. The need for, and potential benefits of, developing the recommended standards are illustrated in the various sections of this report.

  18. Method of production of pure hydrogen near room temperature from aluminum-based hydride materials

    DOE Patents [OSTI]

    Pecharsky, Vitalij K.; Balema, Viktor P.

    2004-08-10

    The present invention provides a cost-effective method of producing pure hydrogen gas from hydride-based solid materials. The hydride-based solid material is mechanically processed in the presence of a catalyst to obtain pure gaseous hydrogen. Unlike previous methods, hydrogen may be obtained from the solid material without heating, and without the addition of a solvent during processing. The described method of hydrogen production is useful for energy conversion and production technologies that consume pure gaseous hydrogen as a fuel.

  19. Low-Cost Metal Hydride TES Systems- FY13 Q3

    Broader source: Energy.gov [DOE]

    This document summarizes the progress of this SRNL project, funded by SunShot, for the third quarter of fiscal year 2013.

  20. Low-Cost Metal Hydride TES Systems- FY13 Q1

    Broader source: Energy.gov [DOE]

    This document summarizes the progress for this Savannah Reiver National Laboratory project, funded by SunShot, for the first quarter of fiscal year 2013.

  1. Low-Cost Metal Hydride Thermal Energy Storage System- FY13 Q2

    Broader source: Energy.gov [DOE]

    This document summarizes the progress of this SRNL project, funded by SunShot, for the second quarter of fiscal year 2013.

  2. Lawrence Livermore National Laboratory Proposal to Participate in the Carbon and Metal Hydride Virtual Centers

    Broader source: Energy.gov [DOE]

    Presentation from the Hydrogen Storage Pre-Solicitation Meeting held June 19, 2003 in Washington, DC.

  3. Method Of Charging Maintenance-Free Nickel Metal Hydride Storage Cells

    DOE Patents [OSTI]

    Berlureau, Thierry; Liska, Jean-Louis

    1999-11-16

    A method of charging an industrial maintenance-free Ni-MH storage cell, the method comprising in combination a first stage at a constant current I.sub.1 lying in the range I.sub.c /10 to I.sub.c /2, and a second stage at a constant current I.sub.2 lying in the range I.sub.c /50 to I.sub.c /10, the changeover from the first stage to the second stage taking place when the time derivative of the temperature reaches a threshold value which varies as a function of the temperature at the time of the changeover.

  4. Reversible Metal Hydride Thermal Energy Storage for High Temperature Power Generation Systems

    Broader source: Energy.gov [DOE]

    This presentation was delivered at the SunShot Concentrating Solar Power (CSP) Program Review 2013, held April 23–25, 2013 near Phoenix, Arizona.

  5. Formation of amorphous metal alloys by chemical vapor deposition

    DOE Patents [OSTI]

    Mullendore, A.W.

    1988-03-18

    Amorphous alloys are deposited by a process of thermal dissociation of mixtures of organometallic compounds and metalloid hydrides,e.g., transition metal carbonyl, such as nickel carbonyl and diborane. Various sizes and shapes of deposits can be achieved, including near-net-shape free standing articles, multilayer deposits, and the like. Manipulation or absence of a magnetic field affects the nature and the structure of the deposit. 1 fig.

  6. Formation of amorphous metal alloys by chemical vapor deposition

    DOE Patents [OSTI]

    Mullendore, Arthur W.

    1990-01-01

    Amorphous alloys are deposited by a process of thermal dissociation of mixtures or organometallic compounds and metalloid hydrides, e.g., transition metal carbonyl such as nickel carbonyl, and diborane. Various sizes and shapes of deposits can be achieved, including near-net-shape free standing articles, multilayer deposits, and the like. Manipulation or absence of a magnetic field affects the nature and the structure of the deposit.

  7. Model for the Prediction of the Hydriding Thermodynamics of Pd-Rh-Co Ternary Alloys

    SciTech Connect (OSTI)

    Teter, D.F.; Thoma, D.J.

    1999-03-01

    A dilute solution model (with respect to the substitutional alloying elements) has been developed, which accurately predicts the hydride formation and decomposition thermodynamics and the storage capacities of dilute ternary Pd-Rh-Co alloys. The effect of varying the rhodium and cobalt compositions on the thermodynamics of hydride formation and decomposition and hydrogen capacity of several palladium-rhodium-cobalt ternary alloys has been investigated using pressure-composition (PC) isotherms. Alloying in the dilute regime (<10 at.%) causes the enthalpy for hydride formation to linearly decrease with increasing alloying content. Cobalt has a stronger effect on the reduction in enthalpy than rhodium for equivalent alloying amounts. Also, cobalt reduces the hydrogen storage capacity with increasing alloying content. The plateau thermodynamics are strongly linked to the lattice parameters of the alloys. A near-linear dependence of the enthalpy of hydride formation on the lattice parameter was observed for both the binary Pd-Rh and Pd-Co alloys, as well as for the ternary Pd-Rh-Co alloys. The Pd-5Rh-3Co (at. %) alloy was found to have similar plateau thermodynamics as a Pd-10Rh alloy, however, this ternary alloy had a diminished hydrogen storage capacity relative to Pd-10Rh.

  8. Internal hydriding in irradiated defected Zircaloy fuel rods: A review (LWBR Development Program)

    SciTech Connect (OSTI)

    Clayton, J C

    1987-10-01

    Although not a problem in recent commercial power reactors, including the Shippingport Light Water Breeder Reactor, internal hydriding of Zircaloy cladding was a persistent cause of gross cladding failures during the 1960s. It occurred in the fuel rods of water-cooled nuclear power reactors that had a small cladding defect. This report summarizes the experimental findings, causes, mechanisms, and methods of minimizing internal hydriding in defected Zircaloy-clad fuel rods. Irradiation test data on the different types of defected fuel rods, intentionally fabricated defected and in-pile operationally defected rods, are compared. Significant factors affecting internal hydriding in defected Zircaloy-clad fuel rods (defect hole size, internal and external sources of hydrogen, Zircaloy cladding surface properties, nickel alloy contamination of Zircaloy, the effect of heat flux and fluence) are discussed. Pertinent in-pile and out-of-pile test results from Bettis and other laboratories are used as a data base in constructing a qualitative model which explains hydrogen generation and distribution in Zircaloy cladding of defected water-cooled reactor fuel rods. Techniques for minimizing internal hydride failures in Zircaloy-clad fuel rods are evaluated.

  9. Draft of M2 Report on Integration of the Hybrid Hydride Model into INL's MBM Framework for Review

    SciTech Connect (OSTI)

    Tikare, Veena; Weck, Philippe F.; Schultz, Peter A.; Clark, Blythe; Glazoff, Michael; Homer, Eric

    2014-07-01

    This report documents the development, demonstration and validation of a mesoscale, microstructural evolution model for simulation of zirconium hydride {delta}-ZrH{sub 1.5} precipitation in the cladding of used nuclear fuels that may occur during long-term dry storage. While the Zr-based claddings are manufactured free of any hydrogen, they absorb hydrogen during service, in the reactor by a process commonly termed ‘hydrogen pick-up’. The precipitation and growth of zirconium hydrides during dry storage is one of the most likely fuel rod integrity failure mechanisms either by embrittlement or delayed hydride cracking of the cladding. While the phenomenon is well documented and identified as a potential key failure mechanism during long-term dry storage (NUREG/CR-7116), the ability to actually predict the formation of hydrides is poor. The model being documented in this work is a computational capability for the prediction of hydride formation in different claddings of used nuclear fuels. This work supports the Used Fuel Disposition Research and Development Campaign in assessing the structural engineering performance of the cladding during and after long-term dry storage. This document demonstrates a basic hydride precipitation model that is built on a recently developed hybrid Potts-phase field model that combines elements of Potts-Monte Carlo and the phase-field models. The model capabilities are demonstrated along with the incorporation of the starting microstructure, thermodynamics of the Zr-H system and the hydride formation mechanism.

  10. Effect of Gaseous Impurities on Long-Term Thermal Cycling and Aging Properties of Complex Hydrides for Hydrogen Storage

    SciTech Connect (OSTI)

    Chandra, Dhanesh; Lamb, Joshua; Chien, Wen-Ming; Talekar, Anjali; and Pal, Narendra.

    2011-03-28

    This program was dedicated to understanding the effect of impurities on Long-Term Thermal Cycling and aging properties of Complex Hydrides for Hydrogen Storage. At the start of the program we found reversibility between Li2NH+LiH  LiH+LiNH2 (yielding ~5.8 wt.%H capacity). Then we tested the effect of impurity in H2 gas by pressure cycling at 255oC; first with industrial gas containing ppm levels of O2 and H2O as major impurities. Both these impurities had a significant impact on the reversibility and decreased the capacity by 2.65 wt.%H. Further increase in number of cycles from 500 to 1100 showed only a 0.2 wt%H more weight loss, showing some capacity is still maintained after a significant number of cycles. The loss of capacity is attributed to the formation of ~55 wt% LiH and ~30% Li2O, as major contaminant phases, along with the hydride Li2NH phase; suggesting loss of nitrogen during cycling. The effect of 100 ppm H2O in H2 also showed a decrease of ~2.5 wt.%H (after 560 cycles), and 100ppm O2 in H2; a loss of ~4.1 wt.%. Methane impurity (100 ppm, 100cycles), showed a very small capacity loss of 0.9 wt.%H under similar conditions. However, when Li3N was pressure cycled with 100ppmN2-H2 there were beneficial effects were observed (255oC); the reversible capacity increased to 8.4wt.%H after 853 cycles. Furthermore, with 20 mol.%N2-H2 capacity increased to ~10 wt.%H after 516 cycles. We attribute this enhancement to the reaction of nitrogen with liquid lithium during cycling as the Gibbs free energy of formation of Li3N (Go = -98.7 kJ/mol) is more negative than that of LiH (Go = -50.3 kJ/mol). We propose that the mitigation of hydrogen capacity losses is due to the destabilization of the LiH phase that tends to accumulate during cycling. Also more Li2NH phase was found in the cycled product. Mixed Alanates (3LiNH2:Li3AlH6) showed that 7 wt% hydrogen desorbed under dynamic vacuum. Equilibrium experiments (maximum 12 bar H2) showed up to 4wt% hydrogen reversibly stored in the material after the first desorption. The activation energy was found to be 51 kJ/mol, as compared to 81 kJ/mol for pure lithium alanate. It is proposed that based on the data obtained and CALPHAD modeling that the improvement in cycling is due to the formation of pure lithium (liquid at 255oC), which is able to react with nitrogen specifically forming Li3N. The presence of nitrogen in the 80/20 molar mixtures in a hydride bed along with hydrogen causes Li to form Li3N rather than LiH, and subsequently regenerates the Li2NH phase and yields a ~10 wt.%H reversibly.

  11. Model for Simulation of Hydride Precipitation in Zr-Based Used Fuel Claddings: A Status Report on Current Model Capabilities

    Broader source: Energy.gov [DOE]

    The report demonstrates a meso-scale, microstructural evolution model for simulation of zirconium hydride precipitation in the cladding of used fuels during long-term dry-storage.

  12. Process for production of an aluminum hydride compound

    DOE Patents [OSTI]

    Allen, Nathan Tait; Butterick, III, Robert; Chin, Arthur Achhing; Miller, Dean Michael; Molzahn, David Craig

    2013-08-06

    A compound of formula M(AlH.sub.3OR.sup.1).sub.y, wherein R.sup.1 is phenyl substituted by at least one of: (i) an alkoxy group having from one to six carbon atoms; and (ii) an alkyl group having from three to twelve carbon atoms; wherein M is an alkali metal, Be or Mg; and y is one or two.

  13. The influence of surface morphology and oxide microstructure on the nucleation and growth of uranium hydride on alpha uranium

    SciTech Connect (OSTI)

    Hanrahan, R.J. Jr.; Hawley, M.E.; Brown, G.W.

    1998-12-31

    While the bulk kinetics of the uranium-hydrogen reaction are well understood, the mechanisms underlying the initial nucleation of uranium hydride on uranium remain controversial. In this study, the authors have employed environmental cell optical microscopy, Scanning Electron Microscopy (SEM) and Atomic Force Microscopy, (AFM) in an attempt to relate the structure of the surface and the microstructure of the substrate with the susceptibility and site of hydride nucleation. Samples have been investigated with varying grain size, inclusion (carbide) concentration, and thermal history. There is a clear correlation to heat treatment immediately prior to hydrogen exposure. Susceptibility to hydride formation also appears to be related to impurities in the uranium. The oxidized surface is very complex, exhibiting wide variations in thickness and topography between samples, between grains in the same sample, and within individual grains. It is, however, very difficult to relate this fine scale variability to the relatively sparse hydride initiation sites. Therefore, the surface oxide layer itself does not appear to control the sites where hydride attack is initiated, although it must play a role in the induction period prior to hydride initiation.

  14. Fast, Quantitative, and Nondestructive Evaluation on Hydrided LWR Fuel Cladding by Small Angle Incoherent Neutron Scattering of Hydrogen

    SciTech Connect (OSTI)

    Yan, Yong; Qian, Shuo; Littrell, Ken; Parish, Chad M; Plummer, Lee K

    2015-01-01

    A non-destructive neutron scattering method to precisely measure the uptake of hydrogen and the distribution of hydride precipitates in light water reactor (LWR) fuel cladding was developed. Zircaloy-4 cladding used in commercial LWRs was used to produce hydrided specimens. The hydriding apparatus consists of a closed stainless steel vessel that contains Zr alloy specimens and hydrogen gas. Following hydrogen charging, the hydrogen content of the hydrided specimens was measured using the vacuum hot extraction method, by which the samples with desired hydrogen concentration were selected for the neutron study. Optical microscopy shows that our hydriding procedure results in uniform distribution of circumferential hydrides across the wall. Small angle neutron incoherent scattering was performed in the High Flux Isotope Reactor at Oak Ridge National Laboratory. Our study demonstrates that the hydrogen in commercial Zircaloy-4 cladding can be measured very accurately in minutes by this nondestructive method over a wide range of hydrogen concentrations from a very small amount ( 20 ppm) to over 1000 ppm. The hydrogen distribution in a tube sample was obtained by scaling the neutron scattering rate with a factor determined by a calibration process using standard, destructive direct chemical analysis methods on the specimens. This scale factor can be used in future tests with unknown hydrogen concentrations, thus providing a nondestructive method for absolute hydrogen concentration determination.

  15. Method to predict relative hydriding within a group of zirconium alloys under nuclear irradiation

    DOE Patents [OSTI]

    Johnson, A.B. Jr.; Levy, I.S.; Trimble, D.J.; Lanning, D.D.; Gerber, F.S.

    1990-04-10

    An out-of-reactor method for screening to predict relative in-reactor hydriding behavior of zirconium-based materials is disclosed. Samples of zirconium-based materials having different compositions and/or fabrication methods are autoclaved in a relatively concentrated (0.3 to 1.0M) aqueous lithium hydroxide solution at constant temperatures within the water reactor coolant temperature range (280 to 316 C). Samples tested by this out-of-reactor procedure, when compared on the basis of the ratio of hydrogen weight gain to oxide weight gain, accurately predict the relative rate of hydriding for the same materials when subject to in-reactor (irradiated) corrosion. 1 figure.

  16. Synthesis, NMR spectra, and structure of rhodium hydride complexes with Rh-Sn bonds

    SciTech Connect (OSTI)

    Krut'ko, B.P.; Permin, A.B.; Petrosyan, V.S.; Reutov, O.A.

    1985-06-20

    The authors study the hydride complexes using Sn 119 and H 1 NMR spectroscopy. The spectra were taken in a pulse mode on a Varian FT-80A spectrometer equipped with a wideband system at 29.66 and 79.54 MHz. The Sn 119 and H 1 NMR spectral parameters for a solution of the complex (Bu/sub 4/N)/sub 3/ (HRh(SnCl/sub 3/)/sub 5/) in CD/sub 3/CN are shown, the spectra show that the (HRh(SnCl/sub 3/)/sub 5/)/sup 3 -/ anion has octahedral structure with four equatorial and one axial Rh-Sn bonds. New rhodium hydride complexes with general formula (R/sub 4/N)/sub 3/(HRh(SnCl/sub 3/)/sub 5/) were synthesized.

  17. Number | Open Energy Information

    Open Energy Info (EERE)

    Property:NumOfPlants Property:NumProdWells Property:NumRepWells Property:Number of Color Cameras Property:Number of Devices Deployed Property:Number of Plants included in...

  18. Titanium Metal Powder Production by the Plasma Quench Process

    SciTech Connect (OSTI)

    R. A. Cordes; A. Donaldson

    2000-09-01

    The goals of this project included the scale-up of the titanium hydride production process to a production rate of 50 kg/hr at a purity level of 99+%. This goal was to be achieved by incrementally increasing the production capability of a series of reactor systems. This methodic approach was designed to allow Idaho Titanium Technologies to systematically address the engineering issues associated with plasma system performance, and powder collection system design and performance. With quality powder available, actual fabrication with the titanium hydride was to be pursued. Finally, with a successful titanium production system in place, the production of titanium aluminide was to be pursued by the simultaneously injection of titanium and aluminum precursors into the reactor system. Some significant accomplishments of the project are: A unique and revolutionary torch/reactor capable of withstanding temperatures up to 5000 C with high thermal efficiency has been operated. The dissociation of titanium tetrachloride into titanium powder and HC1 has been demonstrated, and a one-megawatt reactor potentially capable of producing 100 pounds per hour has been built, but not yet operated at the powder level. The removal of residual subchlorides and adsorbed HC1 and the sintering of powder to form solid bodies have been demonstrated. The production system has been operated at production rates up to 40 pounds per hour. Subsequent to the end of the project, Idaho Titanium Technologies demonstrated that titanium hydride powder can indeed be sintered into solid titanium metal at 1500 C without sintering aids.

  19. Mechanistic study of the isotopic-exchange reaction between gaseous hydrogen and palladium hydride powder

    SciTech Connect (OSTI)

    Outka, D.A.; Foltz, G.W. (Sandia National Labs., Livermore, CA (USA))

    1991-07-01

    A detailed mechanism for the isotopic-exchange reaction between gaseous hydrogen and solid palladium hydride is developed which extends previous model for this reaction by specifically including surface reactions. The modeling indicates that there are two surface-related processes that contribute to the overall rate of exchange: the desorption of hydrogen from the surface and the exchange between surface hydrogen and bulk hydrogen. This conclusion is based upon measurements examining the effect of small concentrations of carbon monoxide were helpful in elucidating the mechanism. Carbon monoxide reversibly inhibits certain steps in the exchange; this slows the overall rate of exchange and changes the distribution of products from the reactor.

  20. Method and apparatus for storing hydrogen isotopes. [stored as uranium hydride in a block of copper

    DOE Patents [OSTI]

    McMullen, J.W.; Wheeler, M.G.; Cullingford, H.S.; Sherman, R.H.

    1982-08-10

    An improved method and apparatus for storing isotopes of hydrogen (especially tritium) are provided. The hydrogen gas is stored as hydrides of material (for example uranium) within boreholes in a block of copper. The mass of the block is critically important to the operation, as is the selection of copper, because no cooling pipes are used. Because no cooling pipes are used, there can be no failure due to cooling pipes. And because copper is used instead of stainless steel, a significantly higher temperature can be reached before the eutectic formation of uranium with copper occurs, (the eutectic of uranium with the iron in stainless steel forms at a significantly lower temperature).

  1. NSR Key Number Retrieval

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NSR Key Number Retrieval Pease enter key in the box Submit

  2. DOE/ID-Number

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... if all metal cladding were to react (5) Minimal H reaction rate Power uprates 3411 MWt - ... This results in a minimal impact on facility design for the later stages; the main impact ...

  3. Rapid hydrogen gas generation using reactive thermal decomposition of uranium hydride.

    SciTech Connect (OSTI)

    Kanouff, Michael P.; Van Blarigan, Peter; Robinson, David B.; Shugard, Andrew D.; Gharagozloo, Patricia E.; Buffleben, George M.; James, Scott Carlton; Mills, Bernice E.

    2011-09-01

    Oxygen gas injection has been studied as one method for rapidly generating hydrogen gas from a uranium hydride storage system. Small scale reactors, 2.9 g UH{sub 3}, were used to study the process experimentally. Complimentary numerical simulations were used to better characterize and understand the strongly coupled chemical and thermal transport processes controlling hydrogen gas liberation. The results indicate that UH{sub 3} and O{sub 2} are sufficiently reactive to enable a well designed system to release gram quantities of hydrogen in {approx} 2 seconds over a broad temperature range. The major system-design challenge appears to be heat management. In addition to the oxidation tests, H/D isotope exchange experiments were performed. The rate limiting step in the overall gas-to-particle exchange process was found to be hydrogen diffusion in the {approx}0.5 {mu}m hydride particles. The experiments generated a set of high quality experimental data; from which effective intra-particle diffusion coefficients can be inferred.

  4. EXPERIMENTAL RESULTS FOR THE ISOTOPIC EXCHANGE OF A 1600 LITER TITANIUM HYDRIDE STORAGE VESSEL

    SciTech Connect (OSTI)

    Klein, J.

    2010-12-14

    Titanium is used as a low pressure tritium storage material. The absorption/desorption rates and temperature rise during air passivation have been reported previously for a 4400 gram prototype titanium hydride storage vessel (HSV). A desorption limit of roughly 0.25 Q/M was obtained when heating to 700 C which represents a significant residual tritium process vessel inventory. To prepare an HSV for disposal, batchwise isotopic exchange has been proposed to reduce the tritium content to acceptable levels. A prototype HSV was loaded with deuterium and exchanged with protium to determine the effectiveness of a batch-wise isotopic exchange process. A total of seven exchange cycles were performed. Gas samples were taken nominally at the beginning, middle, and end of each desorption cycle. Sample analyses showed the isotopic exchange process does not follow the standard dilution model commonly reported. Samples taken at the start of the desorption process were lower in deuterium (the gas to be removed) than those taken later in the desorption cycle. The results are explained in terms of incomplete mixing of the exchange gas in the low pressure hydride.

  5. Verification and Validation Strategy for Implementation of Hybrid Potts-Phase Field Hydride Modeling Capability in MBM

    SciTech Connect (OSTI)

    Jason D. Hales; Veena Tikare

    2014-04-01

    The Used Fuel Disposition (UFD) program has initiated a project to develop a hydride formation modeling tool using a hybrid Pottsphase field approach. The Potts model is incorporated in the SPPARKS code from Sandia National Laboratories. The phase field model is provided through MARMOT from Idaho National Laboratory.

  6. Half metallic materials and their properties (Book) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Book: Half metallic materials and their properties Citation Details In-Document Search ... OSTI Identifier: 1130002 Report Number(s): LLNL-BOOK-424888 DOE Contract Number: ...

  7. Metal aminoboranes

    DOE Patents [OSTI]

    Burrell, Anthony K.; Davis, Benjamin J.; Thorn, David L.; Gordon, John C.; Baker, R. Thomas; Semelsberger, Troy Allen; Tumas, William; Diyabalanage, Himashinie Vichalya Kaviraj; Shrestha, Roshan P.

    2010-05-11

    Metal aminoboranes of the formula M(NH.sub.2BH.sub.3).sub.n have been synthesized. Metal aminoboranes are hydrogen storage materials. Metal aminoboranes are also precursors for synthesizing other metal aminoboranes. Metal aminoboranes can be dehydrogenated to form hydrogen and a reaction product. The reaction product can react with hydrogen to form a hydrogen storage material. Metal aminoboranes can be included in a kit.

  8. A technique for synthesizing metal tritide standards

    SciTech Connect (OSTI)

    Bach, H. T.; Allen, T. H.; Hill, D. D.; Martinez, P. T.; Schwarz, R. B.; Paglieri, S. N.; Wermer, J. R.

    2008-07-15

    Before surplus plutonium pits can be decommissioned and converted into metal oxides to be used as reactor fuels, residual tritium must be reduced to an acceptable level. We have developed two analytical methods involving melting and acid dissolution, combined with liquid scintillation counting as a quantitative and sensitive technique for measuring residual tritium in Pu metal. The detection limit, linearity, and reproducibility of these analytical methods must be validated with a series of metal tritide standards. Since there are no commercially available metal tritide standards, we have developed a technique for their synthesis. The synthesis of these low-level metal tritide standards is accomplished by charging cerium powder with a known amount of tritium to form a master cerium tritide alloy and then by aliquoting from this master alloy and diluting with pure cerium powder to form a series of standards with different tritium concentrations. The major difficulty in synthesizing these standards is that the samples contain extremely low levels of tritium, which span over three decades of concentrations. The synthesis technique and initial data obtained for cerium hydride samples will be presented. (authors)

  9. Metal Matrix Microencapsulated (M3) fuel neutronics performance in PWRs

    SciTech Connect (OSTI)

    Fratoni, Massimiliano; Terrani, Kurt A

    2012-01-01

    Metal Matrix Microencapsulated (M3) fuel consists of TRISO or BISO coated fuel particles directly dispersed in a matrix of zirconium metal to form a solid rod (Fig. 1). In this integral fuel concept the cladding tube and the failure mechanisms associated with it have been eliminated. In this manner pellet-clad-interactions (PCI), thin tube failure due to oxidation and hydriding, and tube pressurization and burst will be absent. M3 fuel, given the high stiffness of the integral rod design, could as well improve grid-to-rod wear behavior. Overall M3 fuel, compared to existing fuel designs, is expected to provide greatly improved operational performance. Multiple barriers to fission product release (ceramic coating layers in the coated fuel particle and te metal matrix) and the high thermal conductivity zirconium alloy metal matrix contribute to the enhancement in fuel behavior. The discontinuous nature of fissile material encapsulated in coated particles provides additional assistance; for instance if the M3 fuel rod is snapped into multiple pieces, only the limited number of fuel particles at the failure cross section are susceptible to release fission products. This is in contrast to the conventional oxide fuel where the presence of a small opening in the cladding provides the pathway for release of the entire inventory of fission products from the fuel rod. While conventional metal fuels (e.g. U-Zr and U-Mo) are typically expected to experience large swelling under irradiation due to the high degree of damage from fission fragments and introduction of fission gas into the lattice, this is not the case for M3 fuels. The fissile portion of the fuel is contained within the coated particle where enough room is available to accommodate fission gases and kernel swelling. The zirconium metal matrix will not be exposed to fission products and its swelling is known to be very limited when exposed solely to neutrons. Under design basis RIA and LOCA, fuel performance will be superior to the conventional oxide fuel since PCMI and rod burst, respectively, have been mitigated. Under beyond design basis accident scenarios where the fuel is exposed to high temperature steam for prolonged periods, larger inventory of zirconium metal in the core could negatively affect the accident progression. A thin steam resistant layer (e.g. alumina forming alloy steel), integrated into the solid rod during fabrication by co-extrusion or hot-isostatic-pressing, offers the potential to provide additional fuel protection from steam interaction: blanketing under a range of boiling regimes and under severe accident conditions up to high temperatures well beyond what is currently possible in the conventional fuel. A crucial aspect to the viability of M3 fuel in light water reactors is the reduced heavy metal load compared to standard pellet fuel. This study evaluated the design requirements to operate a Pressurized Water Reactor (PWR) with M3 fuel in order to obtain fuel cycle length, reactivity coefficients, and power peaking factors comparable to that of standard fuel.

  10. RF sputtering for controlling dihydride and monohydride bond densities in amorphous silicon hydride

    DOE Patents [OSTI]

    Jeffery, F.R.; Shanks, H.R.

    1980-08-26

    A process is described for controlling the dihydride and monohydride bond densities in hydrogenated amorphous silicone produced by reactive rf sputtering of an amorphous silicon target. There is provided a chamber with an amorphous silicon target and a substrate therein with the substrate and the target positioned such that when rf power is applied to the target the substrate is in contact with the sputtering plasma produced thereby. Hydrogen and argon are fed to the chamber and the pressure is reduced in the chamber to a value sufficient to maintain a sputtering plasma therein, and then rf power is applied to the silicon target to provide a power density in the range of from about 7 watts per square inch to about 22 watts per square inch to sputter an amorphous solicone hydride onto the substrate, the dihydride bond density decreasing with an increase in the rf power density. Substantially pure monohydride films may be produced.

  11. Hydride vapor phase GaN films with reduced density of residual electrons and deep traps

    SciTech Connect (OSTI)

    Polyakov, A. Y.; Smirnov, N. B.; Govorkov, A. V.; Yugova, T. G.; Cox, H.; Helava, H.; Makarov, Yu.; Usikov, A. S.

    2014-05-14

    Electrical properties and deep electron and hole traps spectra are compared for undoped n-GaN films grown by hydride vapor phase epitaxy (HVPE) in the regular process (standard HVPE samples) and in HVPE process optimized for decreasing the concentration of residual donor impurities (improved HVPE samples). It is shown that the residual donor density can be reduced by optimization from ?10{sup 17}?cm{sup ?3} to (25)??10{sup 14}?cm{sup ?3}. The density of deep hole traps and deep electron traps decreases with decreased donor density, so that the concentration of deep hole traps in the improved samples is reduced to ?5??10{sup 13}?cm{sup ?3} versus 2.9??10{sup 16}?cm{sup ?3} in the standard samples, with a similar decrease in the electron traps concentration.

  12. Method to predict relative hydriding within a group of zirconium alloys under nuclear irradiation

    DOE Patents [OSTI]

    Johnson, Jr., A. Burtron (Richland, WA); Levy, Ira S. (Kennewick, WA); Trimble, Dennis J. (Kennewick, WA); Lanning, Donald D. (Kennewick, WA); Gerber, Franna S. (Richland, WA)

    1990-01-01

    An out-of-reactor method for screening to predict relative in-reactor hydriding behavior of zirconium-bsed materials is disclosed. Samples of zirconium-based materials having different composition and/or fabrication are autoclaved in a relatively concentrated (0.3 to 1.0M) aqueous lithium hydroxide solution at constant temperatures within the water reactor coolant temperature range (280.degree. to 316.degree. C.). Samples tested by this out-of-reactor procedure, when compared on the basis of the ratio of hydrogen weight gain to oxide weight gain, accurately predict the relative rate of hyriding for the same materials when subject to in-reactor (irradiated) corrision.

  13. Big Numbers | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Big Numbers May 16, 2011 This article has some numbers in it. In principle, numbers are just language, like English or Japanese. Nevertheless, it is true that not everyone is comfortable or facile with numbers and may be turned off by too many of them. To those people, I apologize that this article pays less attention to maximizing the readership than some I do. But sometimes it's just appropriate to indulge one's self, so here goes. When we discuss the performance of some piece of equipment, we

  14. Anisotropic Azimuthal Power and Temperature distribution on FuelRod. Impact on Hydride Distribution

    SciTech Connect (OSTI)

    Motta, Arthur; Ivanov, Kostadin; Arramova, Maria; Hales, Jason

    2015-04-29

    The degradation of the zirconium cladding may limit nuclear fuel performance. In the high temperature environment of a reactor, the zirconium in the cladding corrodes, releasing hydrogen in the process. Some of this hydrogen is absorbed by the cladding in a highly inhomogeneous manner. The distribution of the absorbed hydrogen is extremely sensitive to temperature and stress concentration gradients. The absorbed hydrogen tends to concentrate near lower temperatures. This hydrogen absorption and hydride formation can cause cladding failure. This project set out to improve the hydrogen distribution prediction capabilities of the BISON fuel performance code. The project was split into two primary sections, first was the use of a high fidelity multi-physics coupling to accurately predict temperature gradients as a function of r, ? , and z, and the second was to use experimental data to create an analytical hydrogen precipitation model. The Penn State version of thermal hydraulics code COBRA-TF (CTF) was successfully coupled to the DeCART neutronics code. This coupled system was verified by testing and validated by comparison to FRAPCON data. The hydrogen diffusion and precipitation experiments successfully calculated the heat of transport and precipitation rate constant values to be used within the hydrogen model in BISON. These values can only be determined experimentally. These values were successfully implemented in precipitation, diffusion and dissolution kernels that were implemented in the BISON code. The coupled output was fed into BISON models and the hydrogen and hydride distributions behaved as expected. Simulations were conducted in the radial, axial and azimuthal directions to showcase the full capabilities of the hydrogen model.

  15. The anti-perovskite type hydride InPd{sub 3}H{sub 0.89}

    SciTech Connect (OSTI)

    Kohlmann, H.; Skripov, A.V.; Soloninin, A.V.; Udovic, T.J.

    2010-10-15

    Hydrogenation of tetragonal InPd{sub 3} in the ZrAl{sub 3} type structure (four-fold ccp superstructure) yields a hydride with a cubic AuCu{sub 3} type structure (one-fold ccp superstructure). Deuterium can be located by neutron powder diffraction in octahedral voids surrounded exclusively by palladium, [Pd{sub 6}], which are 88.5(6)% occupied in a statistical manner. The resulting deuteride InPd{sub 3}D{sub 0.89} thus crystallizes in a cubic anti-perovskite type structure (space group Pm3-bar m (no. 221), a=402.25(1) pm at 299(2) K). The Pd-D distance of 201.13(1) pm is typical for interstitial hydrides with palladium. Inelastic neutron scattering on the hydride InPd{sub 3}H{sub 0.89}, which shows a spectrum similar to that of binary palladium hydride, confirms the cubic site symmetry of hydrogen in [Pd{sub 6}] interstices. This is also confirmed by the absence of any quadrupole splitting in the {sup 2}D-NMR signal of the deuteride. {sup 1}H NMR spectra of InPd{sub 3}H{sub 0.89} do not show any motional narrowing. Values found for the H jump rate {tau}{sup -1} in InPd{sub 3}H{sub 0.89} remain below 10{sup 6} s{sup -1} in the studied temperature range 28-360 K, indicating a small hydrogen mobility in InPd{sub 3}H{sub 0.8} as compared with binary palladium hydride, PdH{sub {<=}1}. This can be attributed to the large spatial separation of the [Pd{sub 6}] sites. - Graphical abstract: Hydrogen induces a rearrangement in InPd{sub 3} from a ZrAl{sub 3} type structure to a cubic AuCu{sub 3} type structure, thus forming an anti-perovskite type hydride InPd{sub 3}H{sub 0.89}.

  16. Numerical comparison of hydrogen desorption behaviors of metal hydride beds based on uranium and on zirconium-cobalt

    SciTech Connect (OSTI)

    Kyoung, S.; Yoo, H.; Ju, H.

    2015-03-15

    In this paper, the hydrogen delivery capabilities of uranium (U) and zirconium-cobalt (ZrCo) are compared quantitatively in order to find the optimum getter materials for tritium storage. A three-dimensional hydrogen desorption model is applied to two identically designed cylindrical beds with the different materials, and hydrogen desorption simulations are then conducted. The simulation results show superior hydrogen delivery performance and easier thermal management capability for the U bed. This detailed analysis of the hydrogen desorption behaviors of beds with U and ZrCo will help to identify the optimal bed material, bed design, and operating conditions for the storage and delivery system in ITER. (authors)

  17. Metal inks

    DOE Patents [OSTI]

    Ginley, David S; Curtis, Calvin J; Miedaner, Alex; van Hest, Marinus Franciscus Antonius Maria; Kaydanova, Tatiana

    2014-02-04

    Self-reducing metal inks and systems and methods for producing and using the same are disclosed. In an exemplary embodiment, a method may comprise selecting metal-organic (MO) precursor, selecting a reducing agent, and dissolving the MO precursor and the reducing agent in an organic solvent to produce a metal ink that remains in a liquid phase at room temperature. Metal inks, including self-reducing and fire-through metal inks, are also disclosed, as are various applications of the metal inks.

  18. Sub-Nanostructured Non Transition Metal Complex Grids for Hydrogen Storage

    SciTech Connect (OSTI)

    Dr. Orhan Talu; Dr. Surendra N. Tewari

    2007-10-27

    This project involved growing sub-nanostructured metal grids to increase dynamic hydrogen storage capacity of metal hydride systems. The nano particles of any material have unique properties unlike its bulk form. Nano-structuring metal hydride materials can result in: {sm_bullet}Increased hydrogen molecule dissociation rate, {sm_bullet} Increased hydrogen atom transport rate, {sm_bullet} Decreased decrepitation caused by cycling, {sm_bullet} Increased energy transfer in the metal matrix, {sm_bullet} Possible additional contribution by physical adsorption, and {sm_bullet} Possible additional contribution by quantum effects The project succeeded in making nano-structured palladium using electrochemical growth in templates including zeolites, mesoporous silica, polycarbonate films and anodized alumina. Other metals were used to fine-tune the synthesis procedures. Palladium was chosen to demonstrate the effects of nano-structuring since its bulk hydrogen storage capacity and kinetics are well known. Reduced project funding was not sufficient for complete characterization of these materials for hydrogen storage application. The project team intends to seek further funding in the future to complete the characterization of these materials for hydrogen storage.

  19. Report number codes

    SciTech Connect (OSTI)

    Nelson, R.N.

    1985-05-01

    This publication lists all report number codes processed by the Office of Scientific and Technical Information. The report codes are substantially based on the American National Standards Institute, Standard Technical Report Number (STRN)-Format and Creation Z39.23-1983. The Standard Technical Report Number (STRN) provides one of the primary methods of identifying a specific technical report. The STRN consists of two parts: The report code and the sequential number. The report code identifies the issuing organization, a specific program, or a type of document. The sequential number, which is assigned in sequence by each report issuing entity, is not included in this publication. Part I of this compilation is alphabetized by report codes followed by issuing installations. Part II lists the issuing organization followed by the assigned report code(s). In both Parts I and II, the names of issuing organizations appear for the most part in the form used at the time the reports were issued. However, for some of the more prolific installations which have had name changes, all entries have been merged under the current name.

  20. Silicone metalization

    DOE Patents [OSTI]

    Maghribi, Mariam N. (Livermore, CA); Krulevitch, Peter (Pleasanton, CA); Hamilton, Julie (Tracy, CA)

    2008-12-09

    A system for providing metal features on silicone comprising providing a silicone layer on a matrix and providing a metal layer on the silicone layer. An electronic apparatus can be produced by the system. The electronic apparatus comprises a silicone body and metal features on the silicone body that provide an electronic device.

  1. Silicone metalization

    DOE Patents [OSTI]

    Maghribi, Mariam N. (Livermore, CA); Krulevitch, Peter (Pleasanton, CA); Hamilton, Julie (Tracy, CA)

    2006-12-05

    A system for providing metal features on silicone comprising providing a silicone layer on a matrix and providing a metal layer on the silicone layer. An electronic apparatus can be produced by the system. The electronic apparatus comprises a silicone body and metal features on the silicone body that provide an electronic device.

  2. Modeling of temporal behavior of isotopic exchange between gaseous hydrogen and palladium hydride power

    SciTech Connect (OSTI)

    Melius, C F; Foltz, G W

    1987-01-01

    A parametric rate-equation model is described which depicts the time dependent behavior of the isotopic exchange process occurring between the solid and gas phases in gaseous hydrogen (deuterium) flows through packed-powder palladium deuteride (hydride) beds. The exchange mechanism is assumed to be rate-limited by processes taking place on the surface of the powder. The fundamental kinetic parameter of the model is the isotopic exchange probability, p, which is the probability that an isotopic exchange event occurs during a collision of a gas phase atom with the surface. Isotope effects between the gas and solid phases are explicitly included in terms of the isotope separation factor, ..cap alpha... Results of the model are compared with recent experimental measurements of isotope exchange in the ..beta..-phase hydrogen/palladium system and, using a literature value of ..cap alpha.. = 2.4, a good description of the experimental data is obtained for p approx. 10/sup -7/. In view of the importance of the isotope effects in the hydrogen/palladium system and the range of ..cap alpha.. values reported for the ..beta..-phase in the literature, the sensitivity of the model results to a variation in the value of ..cap alpha.. is examined.

  3. Studies of isotopic exchange between gaseous hydrogen and palladium hydride powder

    SciTech Connect (OSTI)

    Foltz, G.W.; Melius, C.F.

    1987-12-01

    A gas flow apparatus has been constructed and used to study the isotopic exchange reaction occurring between the solid and gas phases in hydrogen (deuterium) gas flows directed through packed-powder beds of ..beta..-phase palladium deuteride (hydride). Spontaneous Raman light scattering is employed to obtain a real-time analysis of the isotopic composition of the gas (H/sub 2/, D/sub 2/, HD) exiting from the bed. A parametric rate-equation model is described which depicts the time-dependent behavior of the isotopic exchange process. The exchange mechanism is assumed to be rate-limited by processes occurring on the surface of the powder. The fundamental kinetic parameter of the model is the isotopic exchange probability, p, which is the probability that an isotopic exchange event occurs during a collision of a gas-phase atom with the surface. Isotope effects between the gas and solid phases are explicitly included in terms of the isotope separation factor, ..cap alpha... Results of the model are compared with the experimental measurements and, using a literature value of ..cap alpha.. = 2.4, good agreement is obtained for p approx. = 10/sup -7/. In view of the importance of the isotope effects in the hydrogen/palladium system and the range of a values reported for the ..beta..-phase in the literature, the sensitivity of the model results to a variation in the value of ..cap alpha.. is examined.

  4. TRITIUM IN-BED ACCOUNTABILITY FOR A PASSIVELY COOLED, ELECTRICALLY HEATED HYDRIDE BED

    SciTech Connect (OSTI)

    Klein, J.; Foster, P.

    2011-01-21

    A PAssively Cooled, Electrically heated hydride (PACE) Bed has been deployed into tritium service in the Savannah River Site (SRS) Tritium Facilities. The bed design, absorption and desorption performance, and cold (non-radioactive) in-bed accountability (IBA) results have been reported previously. Six PACE Beds were fitted with instrumentation to perform the steady-state, flowing gas calorimetric inventory method. An IBA inventory calibration curve, flowing gas temperature rise ({Delta}T) versus simulated or actual tritium loading, was generated for each bed. Results for non-radioactive ('cold') tests using the internal electric heaters and tritium calibration results are presented. Changes in vacuum jacket pressure significantly impact measured IBA {Delta}T values. Higher jacket pressures produce lower IBA {Delta}T values which underestimate bed tritium inventories. The exhaust pressure of the IBA gas flow through the bed's U-tube has little influence on measured IBA {Delta}T values, but larger gas flows reduce the time to reach steady-state conditions and produce smaller tritium measurement uncertainties.

  5. Modeling and Simulation for Used Nuclear Fuel Loading and Effect of Hydriding during Transportation

    SciTech Connect (OSTI)

    Chakraborty, Pritam; Sabharwall, Piyush; Spears, Robert Edward; Coleman, Justin Leigh

    2015-09-30

    The United States nuclear contribution to the net energy production mix is approximately 20% per year. Meeting the demand every year adds to the spent nuclear fuel (SNF) inventory. The commercial nuclear fleet consists mainly of light water reactors (pressurized water reactors [PWRs] and boiling water reactors), with estimation of approximately 140,000 maximum transmission units (MTUs) of spent nuclear discharged from the operating reactor fleet [1]. The current average discharge burnup for PWRs is approximately 48 gigawatt-days (GWd)/MTU and for boiling water reactors is approximately 43 gigawatt-days GWd/MTU [2, 3], with a potential increase in the burnup looking into the future, which will lead to higher decay heat and potential changes in cladding thickness, higher hydrogen content in the cladding with increase in production of the fission gas, and hydride effect. Current fuels research and development examines various cladding materials such as ZIRLOTM and M5, and the accident-tolerant fuel program mainly focuses on other novel cladding materials such as SiC and FeCrAl as potential cladding materials for future.

  6. Atomic-Scale Chemical, Physical and Electronic Properties of the Subsurface Hydride of Palladium

    SciTech Connect (OSTI)

    Weiss, Paul

    2014-01-20

    We employed low-temperature, extreme-high vacuum scanning tunneling microscopy (STM) to investigate the roles of subsurface hydride (H) and deuteride (D) in the surface reconstruction and surface reactivity of Pd{110}. Specifically, we gained the ability to tailor the surface structure of Pd{110} both by preparation method and by deposition of deuterium from the gas phase. We observed thiophene at low coverage on Pd{110} to determine its adsorption orientation and electronic structure through scanning tunneling spectroscopy (STS) namely, conductance spectroscopy and differential conductance imaging. We developed the methods necessary to coadsorb D adatoms with thiophene molecules, and to induce the reaction of individual molecules with predefined subsurface H or D features. In the case of Pd{110}, we found a much more pronounced effect from subsurface D, as it is influenced by the surface directionality. These experiments facilitate an understanding of the role of surface and subsurface H and D in heterogeneous catalytic processes, specifically in the hydrodesulfuization (HDS) of thiophene, an important and ubiquitous component found to be detrimental to petroleum refining.

  7. Document Details Document Number

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Document Details Document Number Date of Document Document Title/Description [Links below to each document] D195066340 Not listed. N/A REVISIONS IN STRATIGRAPHIC NOMENCLATURE OF COLUMBIA RIVER BASALT GROUP D196000240 Not listed. N/A EPA DENIAL OF LINER LEACHATE COLLECTION SYSTEM REQUIREMENTS D196005916 Not listed. N/A LATE CENOZOIC STRATIGRAPHY AND TECTONIC EVOLUTION WITHIN SUBSIDING BASIN SOUTH CENTRAL WASHINGTON D196025993 RHO-BWI-ST-14 N/A SUPRABASALT SEDIMENTS OF COLD CREEK SYNCLINE AREA

  8. Molybdenum Hydride and Dihydride Complexes Bearing Diphosphine Ligands with a Pendant Amine: Formation of Complexes With Bound Amines

    SciTech Connect (OSTI)

    Zhang, Shaoguang; Bullock, R. Morris

    2015-07-06

    CpMo(CO)(PNP)H complexes (PNP = (R2PCH2)2NMe, R = Et or Ph) were synthesized by displacement of two CO ligands of CpMo(CO)3H by the PNP ligand; these complexes were characterized by IR and variable temperature 1H and 31P NMR spectroscopy. CpMo(CO)(PNP)H complexes are formed as mixture of cis and trans-isomers. Both cis-CpMo(CO)(PEtNMePEt)H and trans-CpMo(CO)(PPhNMePPh)H were analyzed by single crystal X-ray diffraction. Electrochemical oxidation of CpMo(CO)(PEtNMePEt)H and CpMo(CO)(PPhNMePPh)H in CH3CN are both irreversible at slow scan rates and quasi-reversible at higher scan rates, with E1/2 = -0.36 V (vs. Cp2Fe+/0) for CpMo(CO)(PEtNMePEt)H and E1/2 = -0.18 V for CpMo(CO)(PPhNMePPh)H. Hydride abstraction from CpMo(CO)(PNP)H with [Ph3C]+[A]- (A = B(C6F5)4 or BArF4; [ArF = 3,5-bis(trifluoromethyl)phenyl]) afforded “tuck-in” [CpMo(CO)(κ3-PNP)]+ complexes that feature the amine bound to the metal. Displacement of the κ3 Mo-N bond by CD3CN gives [CpMo(CO)(PNP)(CD3CN)]+. The kinetics of this reaction were studied by NMR spectroscopy, providing the activation parameters ΔH‡ = 22.1 kcal/mol, ΔS‡ = 1.89 cal/(mol·K), Ea = 22.7 kcal/mol. Protonation of CpMo(CO)(PEtNMePEt)H affords [CpMo(CO)(κ2-PEtNMePEt)(H)2]+ as a Mo dihydride complex, which loses H2 to generate [CpMo(CO)(κ3-PEtNMePEt)]+ at room temperature. CpMo(CO)(dppp)H (dppp = 1,2-bis(diphenylphosphino)propane) was studied as a Mo diphosphine analogue without a pendant amine, and the product of protonation of this complex gives [CpMo(CO)(dppp)(H)2]+. Our results show that the pendant amine has a strong driving force to form stable “tuck-in” [CpMo(CO)(κ3-PNP)]+ complexes, and also promotes hydrogen elimination from [CpMo(CO)(PNP)(H)2]+ complexes by formation of Mo-N dative bond. We thank the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences and Biosciences for support. Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy. We thank Monte Helm, Elliott Hulley and Deanna Miller for help on the crystallography, and Ming Fang for assistance on the electrochemical experiments.

  9. First Principles Contributions to the Thermodynamic Assessment of Solid

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    State Metal Hydride and Complex Hydride Phases | Department of Energy First Principles Contributions to the Thermodynamic Assessment of Solid State Metal Hydride and Complex Hydride Phases First Principles Contributions to the Thermodynamic Assessment of Solid State Metal Hydride and Complex Hydride Phases Presentation on the Thermodynamic Assessment of Solid State Metal Hydride and Complex Hydride Phases given at the DOE Theory Focus Session on Hydrogen Storage Materials on May 18, 2006.

  10. Particle size effect of hydride formation and surface hydrogen absorption of nanosized palladium catalysts : L{sub 3} edge vs K edge x-ray absorption spectroscopy.

    SciTech Connect (OSTI)

    Tew, M. W.; Miller, J. T.; van Bokhoven, J. A.

    2009-08-01

    The particle size effect on the formation of palladium hydride and on surface hydrogen adsorption was studied at room temperature using in situ X-ray absorption spectroscopy at the Pd K and L{sub 3} edges. Hydride formation was indirectly observed by lattice expansion in Pd K edge XANES spectra and by EXAFS analysis. Hydride formation was directly detected in the L{sub 3} edge spectra. A characteristic spectral feature caused by the formation of a Pd-H antibonding state showed strong particle size dependence. The L{sub 3} edge spectra were reproduced using full multiple scattering analysis and density of state calculations, and the contributions of bulk absorbed and surface hydrogen to the XANES spectra could be distinguished. The ratio of hydrogen on the surface versus that in the bulk increased with decreasing particle size, and smaller particles dissolved less hydrogen.

  11. A coupled transport and solid mechanics formulation with improved reaction kinetics parameters for modeling oxidation and decomposition in a uranium hydride bed.

    SciTech Connect (OSTI)

    Salloum, Maher N.; Shugard, Andrew D.; Kanouff, Michael P.; Gharagozloo, Patricia E.

    2013-03-01

    Modeling of reacting flows in porous media has become particularly important with the increased interest in hydrogen solid-storage beds. An advanced type of storage bed has been proposed that utilizes oxidation of uranium hydride to heat and decompose the hydride, releasing the hydrogen. To reduce the cost and time required to develop these systems experimentally, a valid computational model is required that simulates the reaction of uranium hydride and oxygen gas in a hydrogen storage bed using multiphysics finite element modeling. This SAND report discusses the advancements made in FY12 (since our last SAND report SAND2011-6939) to the model developed as a part of an ASC-P&EM project to address the shortcomings of the previous model. The model considers chemical reactions, heat transport, and mass transport within a hydride bed. Previously, the time-varying permeability and porosity were considered uniform. This led to discrepancies between the simulated results and experimental measurements. In this work, the effects of non-uniform changes in permeability and porosity due to phase and thermal expansion are accounted for. These expansions result in mechanical stresses that lead to bed deformation. To describe this, a simplified solid mechanics model for the local variation of permeability and porosity as a function of the local bed deformation is developed. By using this solid mechanics model, the agreement between our reacting bed model and the experimental data is improved. Additionally, more accurate uranium hydride oxidation kinetics parameters are obtained by fitting the experimental results from a pure uranium hydride oxidation measurement to the ones obtained from the coupled transport-solid mechanics model. Finally, the coupled transport-solid mechanics model governing equations and boundary conditions are summarized and recommendations are made for further development of ARIA and other Sandia codes in order for them to sufficiently implement the model.

  12. Metal oxide films on metal

    DOE Patents [OSTI]

    Wu, Xin D. (Los Alamos, NM); Tiwari, Prabhat (Los Alamos, NM)

    1995-01-01

    A structure including a thin film of a conductive alkaline earth metal oxide selected from the group consisting of strontium ruthenium trioxide, calcium ruthenium trioxide, barium ruthenium trioxide, lanthanum-strontium cobalt oxide or mixed alkaline earth ruthenium trioxides thereof upon a thin film of a noble metal such as platinum is provided.

  13. Texas Natural Gas Number of Residential Consumers (Number of...

    Gasoline and Diesel Fuel Update (EIA)

    Residential Consumers (Number of Elements) Texas Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

  14. Texas Natural Gas Number of Commercial Consumers (Number of Elements...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Commercial Consumers (Number of Elements) Texas Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

  15. Connecticut Natural Gas Number of Commercial Consumers (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Connecticut Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

  16. Connecticut Natural Gas Number of Residential Consumers (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Connecticut Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6...

  17. North Carolina Natural Gas Number of Commercial Consumers (Number...

    Gasoline and Diesel Fuel Update (EIA)

    Commercial Consumers (Number of Elements) North Carolina Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6...

  18. New York Natural Gas Number of Commercial Consumers (Number of...

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) New York Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

  19. New York Natural Gas Number of Residential Consumers (Number...

    Gasoline and Diesel Fuel Update (EIA)

    Residential Consumers (Number of Elements) New York Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

  20. Indiana Natural Gas Number of Industrial Consumers (Number of...

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Indiana Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

  1. Fabrication of metal shells

    SciTech Connect (OSTI)

    O'Holleran, T.P.; Henderson, T.M.; Downs, R.L.; Nolen, R.L.

    1980-01-01

    Small hollow metal spheres are needed as targets for particle-beam fusion experiments and as the inner fuel container for multi-shell targets. For the multishell application, shells fabricated of materials with high atomic numbers, e.g., gold, are of particular interest because they may effectively reduce preheating of the fuel. Because the shells must also contain the fuel mixture (deuterium and tritium) at high pressures, high strength materials, e.g., iron, are also of considerable interest. With the objective of proof of principle we have investigated several techniques of fabricating shells of metal or materials containing large fractions of high atomic number elements. These techniques, our experimental results and their evaluation are presented.

  2. Review of consequences of uranium hydride formation in N-Reactor fuel elements stored in the K-Basins

    SciTech Connect (OSTI)

    Weber, J.W.

    1994-09-28

    The 105-K Basins on the Hanford site are used to store uranium fuel elements and assemblies irradiated in and discharged from N Reactor. The storage cylinders in KW Basin are known to have some broken N reactor fuel elements in which the exposed uranium is slowly reacting chemically with water in the cylinder. The products of these reactions are uranium oxide, hydrogen, and potentially some uranium hydride. The purpose of this report is to document the results f the latest review of potential, but highly unlikely accidents postulated to occur as closed cylinders containing N reactor fuel assemblies are opened under water in the KW basin and as a fuel assembly is raised from the basin in a shipping cask for transportation to the 327 Building for examination as part of the SNF Characterization Program. The postulated accidents reviews in this report are considered to bound all potential releases of radioactivity and hydrogen. These postulated accidents are: (1) opening and refill of a cylinder containing significant amounts of hydrogen and uranium hydride; and (2) draining of the single element can be used to keep the fuel element submerged in water after the cask containing the can and element is lifted from the KW Basin. Analysis shows the release of radioactivity to the site boundary is significantly less than that allowed by the K Basin Safety Evaluation. Analysis further shows there would be no damage to the K Basin structure nor would there be injury to personnel for credible events.

  3. Dendritic metal nanostructures

    DOE Patents [OSTI]

    Shelnutt, John A. (Tijeras, NM); Song, Yujiang (Albuquerque, NM); Pereira, Eulalia F. (Vila Nova de Gaia, PT); Medforth, Craig J. (Winters, CA)

    2010-08-31

    Dendritic metal nanostructures made using a surfactant structure template, a metal salt, and electron donor species.

  4. Method For Characterizing Residual Stress In Metals

    DOE Patents [OSTI]

    Jacobson, Loren A. (Santa Fe, NM); Michel, David J. (Alexandria, VA); Wyatt, Jeffrey R. (Burke, VA)

    2002-12-03

    A method is provided for measuring the residual stress in metals. The method includes the steps of drilling one or more holes in a metal workpiece to a preselected depth and mounting one or more acoustic sensors on the metal workpiece and connecting the sensors to an electronic detecting and recording device. A liquid metal capable of penetrating into the metal workpiece placed at the bottom of the hole or holes. A recording is made over a period of time (typically within about two hours) of the magnitude and number of noise events which occur as the liquid metal penetrates into the metal workpiece. The magnitude and number of noise events are then correlated to the internal stress in the region of the workpiece at the bottom of the hole.

  5. Calorimetric study of the palladium hydride and deuteride systems. Preliminary report

    SciTech Connect (OSTI)

    Wagner, J.E.

    1985-08-12

    Pressure differential scanning calorimetry was applied to a study of the hydrogenation of palladium metal. The effects of hydrogen and deuterium absorption by palladium metal, the effects of isotope exchanges, and hydrogen and deuterium pressure changes which affect the stoichiometry of PdH/sub x/ and PdD/sub x/ are presented in some detail by this experimental technique. It is emphasized that a pressure differential scanning calorimeter is a quick and convenient experimental means for assessing hydrogen absorption properties of hydrogen storage materials. 13 refs., 4 figs., 1 tab.

  6. MULTIDIMENSIONAL CHEMICAL MODELING OF YOUNG STELLAR OBJECTS. III. THE INFLUENCE OF GEOMETRY ON THE ABUNDANCE AND EXCITATION OF DIATOMIC HYDRIDES

    SciTech Connect (OSTI)

    Bruderer, S.; Benz, A. O.; Staeuber, P.; Doty, S. D.

    2010-09-10

    The Herschel Space Observatory enables observations in the far-infrared at high spectral and spatial resolution. A particular class of molecules will be directly observable: light diatomic hydrides and their ions (CH, OH, SH, NH, CH{sup +}, OH{sup +}, SH{sup +}, NH{sup +}). These simple constituents are important both for the chemical evolution of the region and as tracers of high-energy radiation. If outflows of a forming star erode cavities in the envelope, protostellar far-UV (FUV; 6 < E{sub {gamma}} < 13.6 eV) radiation may escape through such low-density regions. Depending on the shape of the cavity, the FUV radiation then irradiates the quiescent envelope in the walls along the outflow. The chemical composition in these outflow walls is altered by photoreactions and heating via FUV photons in a manner similar to photo-dominated regions. In this work, we study the effect of cavity shapes, outflow density, and of a disk with the two-dimensional chemical model of a high-mass young stellar object introduced in the second paper in this series. The model has been extended with a self-consistent calculation of the dust temperature and a multi-zone escape probability method for the calculation of the molecular excitation and the prediction of line fluxes. We find that the shape of the cavity is particularly important in the innermost part of the envelope, where the dust temperatures are high enough ({approx}>100 K) for water ice to evaporate. If the cavity shape allows FUV radiation to penetrate this hot-core region, the abundance of FUV-destroyed species (e.g., water) is decreased. On larger scales, the shape of the cavity is less important for the chemistry in the outflow wall. In particular, diatomic hydrides and their ions CH{sup +}, OH{sup +}, and NH{sup +} are enhanced by many orders of magnitude in the outflow walls due to the combination of high gas temperatures and rapid photodissociation of more saturated species. The enhancement of these diatomic hydrides is sufficient for a detection using the HIFI and PACS instruments on board Herschel. The effect of X-ray ionization on the chemistry is found to be small, due to the much larger luminosity in FUV bands compared to X-rays.

  7. METAL COMPOSITIONS

    DOE Patents [OSTI]

    Seybolt, A.U.

    1959-02-01

    Alloys of uranium which are strong, hard, and machinable are presented, These alloys of uranium contain bctween 0.1 to 5.0% by weight of at least one noble metal such as rhodium, palladium, and gold. The alloys may be heat treated to obtain a product with iniproved tensile and compression strengths,

  8. Composite metal membrane

    DOE Patents [OSTI]

    Peachey, N.M.; Dye, R.C.; Snow, R.C.; Birdsell, S.A.

    1998-04-14

    A composite metal membrane including a first metal layer of Group IVB met or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof is provided together with a process for the recovery of hydrogen from a gaseous mixture including contacting a hydrogen-containing gaseous mixture with a first side of a nonporous composite metal membrane including a first metal of Group IVB metals or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof, and, separating hydrogen from a second side of the nonporous composite metal membrane.

  9. Composite metal membrane

    DOE Patents [OSTI]

    Peachey, Nathaniel M. (Espanola, NM); Dye, Robert C. (Los Alamos, NM); Snow, Ronny C. (Los Alamos, NM); Birdsell, Stephan A. (Los Alamos, NM)

    1998-01-01

    A composite metal membrane including a first metal layer of Group IVB met or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof is provided together with a process for the recovery of hydrogen from a gaseous mixture including contacting a hydrogen-containing gaseous mixture with a first side of a nonporous composite metal membrane including a first metal of Group IVB metals or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof, and, separating hydrogen from a second side of the nonporous composite metal membrane.

  10. Alaska Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Alaska Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 10 11 8 1990's 8 8 10 11 11 9 202 7 7 9 2000's 9 8 9 9 10 12 11 11 6 3 2010's 3 5 3 3 1 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next Release Date: 3/31/2016 Referring Pages: Number of Natural Gas

  11. Hawaii Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Hawaii Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 27 26 29 2000's 28 28 29 29 29 28 26 27 27 25 2010's 24 24 22 22 23 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next Release Date: 3/31/2016 Referring Pages: Number of Natural Gas Industrial

  12. Transition metal-free olefin polymerization catalyst

    DOE Patents [OSTI]

    Sen, Ayusman (State College, PA); Wojcinski, II, Louis M. (State College, PA); Liu, Shengsheng (State College, PA)

    2001-01-01

    Ethylene and/or propylene are polymerized to form high molecular weight, linear polymers by contacting ethylene and/or propylene monomer, in the presence of an inert reaction medium, with a catalyst system which consists essentially of (1) an aluminum alkyl component, such as trimethylaluminum, triethylaluminum, triisobutylaluminum, tri-n-octylaluminum and diethylaluminum hydride and (2) a Lewis acid or Lewis acid derivative component, such as B (C.sub.6 F.sub.5).sub.3, [(CH.sub.3).sub.2 N (H) (C.sub.6 H.sub.5)].sup.+ [B (C.sub.6 F.sub.5)4].sup.-, [(C.sub.2 H.sub.5).sub.3 NH].sup.+ [B C.sub.6 F.sub.5).sub.4 ],.sup.-, [C(C.sub.6 F.sub.5).sub.3 ].sup.+ [B(C.sub.6 F.sub.5).sub.4 ].sup.-, (C.sub.2 H.sub.5).sub.2 Al(OCH.sub.3), (C.sub.2 H.sub.5).sub.2 Al(2,6-di-t-butyl-4-methylphenoxide), (C.sub.2 H.sub.5)Al(2,6 -di-t-butylphenoxide).sub.2, (C.sub.2 H.sub.5).sub.2 Al(2,6-di-t-butylphonoxide) , 2,6 -di-t-butylphenol.multidot.methylaluminoxane or an alkylaluminoxane, and which may be completely free any transition metal component(s).

  13. Gas-Phase Reactions of Doubly Charged Lanthanide Cations with Alkanes and Alkenes. Trends in Metal(2+) Reactivity

    SciTech Connect (OSTI)

    Gibson, John K.; Marcalo, Joaquim; Santos, Marta; Pires de Matos, Antonio; Haire, Richard G.

    2008-12-08

    The gas-phase reactivity of doubly-charged lanthanide cations, Ln2+ (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu), with alkanes (methane, ethane, propane, n-butane) and alkenes (ethene, propene, 1-butene) was studied by Fourier transform ion cyclotron resonance mass spectrometry. The reaction products consisted of different combinations of doubly-charged organometallic ions?adducts or species formed via metal-ion-induced hydrogen, dihydrogen, alkyl, or alkane eliminations from the hydrocarbons?and singly-charged ions that resulted from electron, hydride, or methide transfers from the hydrocarbons to the metal ions. The only lanthanide cations capable of activating the hydrocarbons to form doubly-charged organometallic ions were La2+, Ce2+, Gd2+, and Tb2+, which have ground-state or low-lying d1 electronic configurations. Lu2+, with an accessible d1 electronic configuration but a rather high electron affinity, reacted only through transfer channels. The remaining Ln2+ reacted via transfer channels or adduct formation. The different accessibilities of d1 electronic configurations and the range of electron affinities of the Ln2+ cations allowed for a detailed analysis of the trends for metal(2+) reactivity and the conditions for occurrence of bond activation, adduct formation, and electron, hydride, and methide transfers.

  14. Total Number of Operable Refineries

    U.S. Energy Information Administration (EIA) Indexed Site

    Data Series: Total Number of Operable Refineries Number of Operating Refineries Number of Idle Refineries Atmospheric Crude Oil Distillation Operable Capacity (B/CD) Atmospheric Crude Oil Distillation Operating Capacity (B/CD) Atmospheric Crude Oil Distillation Idle Capacity (B/CD) Atmospheric Crude Oil Distillation Operable Capacity (B/SD) Atmospheric Crude Oil Distillation Operating Capacity (B/SD) Atmospheric Crude Oil Distillation Idle Capacity (B/SD) Vacuum Distillation Downstream Charge

  15. Compendium of Experimental Cetane Numbers

    SciTech Connect (OSTI)

    Yanowitz, J.; Ratcliff, M. A.; McCormick, R. L.; Taylor, J. D.; Murphy, M. J.

    2014-08-01

    This report is an updated version of the 2004 Compendium of Experimental Cetane Number Data and presents a compilation of measured cetane numbers for pure chemical compounds. It includes all available single compound cetane number data found in the scientific literature up until March 2014 as well as a number of unpublished values, most measured over the past decade at the National Renewable Energy Laboratory. This Compendium contains cetane values for 389 pure compounds, including 189 hydrocarbons and 201 oxygenates. More than 250 individual measurements are new to this version of the Compendium. For many compounds, numerous measurements are included, often collected by different researchers using different methods. Cetane number is a relative ranking of a fuel's autoignition characteristics for use in compression ignition engines; it is based on the amount of time between fuel injection and ignition, also known as ignition delay. The cetane number is typically measured either in a single-cylinder engine or a constant volume combustion chamber. Values in the previous Compendium derived from octane numbers have been removed, and replaced with a brief analysis of the correlation between cetane numbers and octane numbers. The discussion on the accuracy and precision of the most commonly used methods for measuring cetane has been expanded and the data has been annotated extensively to provide additional information that will help the reader judge the relative reliability of individual results.

  16. Arizona Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Arizona Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 358 344 354 1990's 526 532 532 526 519 530 534 480 514 555 2000's 526 504 488 450 414 425 439 395 383 390 2010's 368 371 379 383 386 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next Release Date:

  17. Montana Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Montana Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 435 435 428 1990's 457 452 459 462 453 463 466 462 454 397 2000's 71 73 439 412 593 716 711 693 693 396 2010's 384 381 372 372 369 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next Release Date:

  18. Nevada Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Nevada Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 93 98 100 1990's 100 113 114 117 119 120 121 93 93 109 2000's 90 90 96 97 179 192 207 220 189 192 2010's 184 177 177 195 218 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next Release Date: 3/31/2016

  19. New Hampshire Natural Gas Number of Industrial Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Industrial Consumers (Number of Elements) New Hampshire Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 153 295 376 1990's 364 361 344 334 324 332 367 385 389 417 2000's 432 331 437 550 305 397 421 578 5,298 155 2010's 306 362 466 403 326 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016

  20. North Dakota Natural Gas Number of Industrial Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Industrial Consumers (Number of Elements) North Dakota Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 138 148 151 1990's 165 170 171 174 186 189 206 216 404 226 2000's 192 203 223 234 241 239 241 253 271 279 2010's 307 259 260 266 269 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016

  1. Rhode Island Natural Gas Number of Industrial Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Industrial Consumers (Number of Elements) Rhode Island Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 1,158 1,152 1,122 1990's 1,135 1,107 1,096 1,066 1,064 359 363 336 325 302 2000's 317 283 54 236 223 223 245 256 243 260 2010's 249 245 248 271 266 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release

  2. South Dakota Natural Gas Number of Industrial Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Industrial Consumers (Number of Elements) South Dakota Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 261 267 270 1990's 275 283 319 355 381 396 444 481 464 445 2000's 416 402 533 526 475 542 528 548 598 598 2010's 580 556 574 566 575 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016

  3. Utah Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Utah Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 551 627 550 1990's 1,508 631 783 345 252 713 923 3,379 3,597 3,625 2000's 3,576 3,535 949 924 312 191 274 278 313 293 2010's 293 286 302 323 328 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next Release

  4. Vermont Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Vermont Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 22 21 14 1990's 15 13 18 20 24 23 27 30 36 37 2000's 38 36 38 41 43 41 35 37 35 36 2010's 38 36 38 13 13 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next Release Date: 3/31/2016 Referring Pages:

  5. Delaware Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Delaware Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 241 233 235 1990's 240 243 248 249 252 253 250 265 257 264 2000's 297 316 182 184 186 179 170 185 165 112 2010's 114 129 134 138 141 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next Release Date:

  6. Florida Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Florida Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 575 552 460 1990's 452 377 388 433 481 515 517 561 574 573 2000's 520 518 451 421 398 432 475 467 449 607 2010's 581 630 507 528 520 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next Release Date:

  7. Idaho Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Idaho Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 219 132 64 1990's 62 65 66 75 144 167 183 189 203 200 2000's 217 198 194 191 196 195 192 188 199 187 2010's 184 178 179 183 189 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next Release Date: 3/31/2016

  8. Maine Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Maine Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 73 73 74 1990's 80 81 80 66 89 74 87 81 110 108 2000's 178 233 66 65 69 69 73 76 82 85 2010's 94 102 108 120 126 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next Release Date: 3/31/2016 Referring

  9. West Virginia Natural Gas Number of Industrial Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Industrial Consumers (Number of Elements) West Virginia Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 463 208 211 1990's 182 198 159 197 191 192 182 173 217 147 2000's 207 213 184 142 137 145 155 114 109 101 2010's 102 94 97 95 92 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next

  10. Wyoming Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Wyoming Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 190 200 230 1990's 284 228 244 194 135 126 170 194 317 314 2000's 308 295 877 179 121 127 133 133 155 130 2010's 120 123 127 132 131 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next Release Date:

  11. Metal dusting

    SciTech Connect (OSTI)

    Edited by K. Natesan

    2004-01-01

    This workshop was held soon after the September 11th incident under a climate of sorrow and uncertainty among the people of the world, in particular the Workshop participants and their host organizations. With considerable help from the partiicpants, the Workshop was conducted as planed and we had excellent participation in spite of the circumstances. A good fraction of the attendees in the Workshop were from abroad and from several industries, indicating the importance and relevance of the subject for the chemical process industry. Degradation of structural metallic alloys by metal dusting has been an issue for over 40 years in the chemical, petrochemical, syngas, and iron ore reduction plants. However, the fundamental scientific reasons for the degradation of complex alloys in high carbon activity environments are not clear. one of the major parameters of importance is the variation in gas chemistry in both the laboratory experiments and in the plant-service environments. the industry has questioned the applicability of the laboratory test data, obtained in low steam environments, in assessment and life prediction for the materials in plant service where the environments contain 25-35% steam. Several other variables such as system pressure, gas flow velocity, incubation time, alloy chemistry, surface finish, and weldments, were also identified in the literature as to having an effect on the initiatino and propagation of metal dusting attack. It is the purpose of this Workshop to establish a forum in which the researchers from scientific and industrial laboratories, alloy manufacturers, end users, and research and development sponsors can exchange information, discuss different points of view, prioritize the issues, and to elaborate on the trends in industry for the future. We believe that we accomplished these goals successfully and sincerely thank the participants for their contributions.

  12. Departmental Business Instrument Numbering System

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2000-12-05

    To prescribe procedures for assigning identifying numbers to all Department of Energy (DOE), including the National Nuclear Security Administration, business instruments. Cancels DOE 1331.2B. Canceled by DOE O 540.1A.

  13. Departmental Business Instrument Numbering System

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2005-01-27

    The Order prescribes the procedures for assigning identifying numbers to all Department of Energy (DOE) and National Nuclear Security Administration (NNSA) business instruments. Cancels DOE O 540.1. Canceled by DOE O 540.1B.

  14. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Trending: Metal Oxo Bonds Trending: Metal Oxo Bonds Print Wednesday, 29 May 2013 00:00 Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides

  15. Metal filled porous carbon

    DOE Patents [OSTI]

    Gross, Adam F. (Los Angeles, CA); Vajo, John J. (West Hills, CA); Cumberland, Robert W. (Malibu, CA); Liu, Ping (Irvine, CA); Salguero, Tina T. (Encino, CA)

    2011-03-22

    A porous carbon scaffold with a surface and pores, the porous carbon scaffold containing a primary metal and a secondary metal, where the primary metal is a metal that does not wet the surface of the pores of the carbon scaffold but wets the surface of the secondary metal, and the secondary metal is interspersed between the surface of the pores of the carbon scaffold and the primary metal.

  16. Document ID Number: RL-721

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ---------------------------------------------------------- Document ID Number: RL-721 REV 4 NEPA REVIEW SCREENING FORM DOE/CX-00066 I. Project Title: Nesting Bird Deterrent Study at the 241-C Tank Farm CX B3.8, "Outdoor Terrestrial Ecological and Environmental Research" II. Project Description and Location (including Time Period over which proposed action will occur and Project Dimensions - e.g., acres displaced/disturbed, excavation length/depth, area/location/number of buildings,

  17. Alabama Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Alabama Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 53 54,306 55,400 56,822 1990's 56,903 57,265 58,068 57,827 60,320 60,902 62,064 65,919 76,467 64,185 2000's 66,193 65,794 65,788 65,297 65,223 65,294 66,337 65,879 65,313 67,674 2010's 68,163 67,696 67,252 67,136 67,806 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to

  18. Alabama Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Alabama Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2 2,313 2,293 2,380 1990's 2,431 2,523 2,509 2,458 2,477 2,491 2,512 2,496 2,464 2,620 2000's 2,792 2,781 2,730 2,743 2,799 2,787 2,735 2,704 2,757 3,057 2010's 3,039 2,988 3,045 3,143 3,244 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  19. Alabama Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Alabama Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 656 662,217 668,432 683,528 1990's 686,149 700,195 711,043 730,114 744,394 751,890 766,322 781,711 788,464 775,311 2000's 805,689 807,770 806,389 809,754 806,660 809,454 808,801 796,476 792,236 785,005 2010's 778,985 772,892 767,396 765,957 769,418 - = No Data Reported; -- = Not Applicable; NA = Not

  20. Alaska Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Alaska Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 11 11,484 11,649 11,806 1990's 11,921 12,071 12,204 12,359 12,475 12,584 12,732 12,945 13,176 13,409 2000's 13,711 14,002 14,342 14,502 13,999 14,120 14,384 13,408 12,764 13,215 2010's 12,998 13,027 13,133 13,246 13,399 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to

  1. Alaska Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Alaska Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 66 67,648 68,612 69,540 1990's 70,808 72,565 74,268 75,842 77,670 79,474 81,348 83,596 86,243 88,924 2000's 91,297 93,896 97,077 100,404 104,360 108,401 112,269 115,500 119,039 120,124 2010's 121,166 121,736 122,983 124,411 126,416 - = No Data Reported; -- = Not Applicable; NA = Not Available; W =

  2. Arizona Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Arizona Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 46 46,702 46,636 46,776 1990's 47,292 53,982 47,781 47,678 48,568 49,145 49,693 50,115 51,712 53,022 2000's 54,056 54,724 56,260 56,082 56,186 56,572 57,091 57,169 57,586 57,191 2010's 56,676 56,547 56,532 56,585 56,649 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to

  3. Arizona Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Arizona Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 545 567,962 564,195 572,461 1990's 586,866 642,659 604,899 610,337 635,335 661,192 689,597 724,911 764,167 802,469 2000's 846,016 884,789 925,927 957,442 993,885 1,042,662 1,088,574 1,119,266 1,128,264 1,130,047 2010's 1,138,448 1,146,286 1,157,688 1,172,003 1,186,794 - = No Data Reported; -- = Not

  4. Arkansas Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Arkansas Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 60 60,355 61,630 61,848 1990's 61,530 61,731 62,221 62,952 63,821 65,490 67,293 68,413 69,974 71,389 2000's 72,933 71,875 71,530 71,016 70,655 69,990 69,475 69,495 69,144 69,043 2010's 67,987 67,815 68,765 68,791 69,011 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to

  5. Arkansas Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Arkansas Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 1 1,410 1,151 1,412 1990's 1,396 1,367 1,319 1,364 1,417 1,366 1,488 1,336 1,300 1,393 2000's 1,414 1,122 1,407 1,269 1,223 1,120 1,120 1,055 1,104 1,025 2010's 1,079 1,133 990 1,020 1,009 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  6. Arkansas Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Arkansas Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 475 480,839 485,112 491,110 1990's 488,850 495,148 504,722 513,466 521,176 531,182 539,952 544,460 550,017 554,121 2000's 560,055 552,716 553,192 553,211 554,844 555,861 555,905 557,966 556,746 557,355 2010's 549,970 551,795 549,959 549,764 549,034 - = No Data Reported; -- = Not Applicable; NA =

  7. Massachusetts Natural Gas Number of Commercial Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Commercial Consumers (Number of Elements) Massachusetts Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 84,636 93,005 92,252 1990's 85,775 88,746 85,873 102,187 92,744 104,453 105,889 107,926 108,832 113,177 2000's 117,993 120,984 122,447 123,006 125,107 120,167 126,713 128,965 242,693 153,826 2010's 144,487 138,225 142,825 144,246 139,556 - = No Data Reported; -- = Not Applicable;

  8. Massachusetts Natural Gas Number of Industrial Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Industrial Consumers (Number of Elements) Massachusetts Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 5,626 7,199 13,057 1990's 6,539 5,006 8,723 7,283 8,019 10,447 10,952 11,058 11,245 8,027 2000's 8,794 9,750 9,090 11,272 10,949 12,019 12,456 12,678 36,928 19,208 2010's 12,751 10,721 10,840 11,063 10,946 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld

  9. Massachusetts Natural Gas Number of Residential Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Residential Consumers (Number of Elements) Massachusetts Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 1,082,777 1,100,635 1,114,920 1990's 1,118,429 1,127,536 1,137,911 1,155,443 1,179,869 1,180,860 1,188,317 1,204,494 1,212,486 1,232,887 2000's 1,278,781 1,283,008 1,295,952 1,324,715 1,306,142 1,297,508 1,348,848 1,361,470 1,236,480 1,370,353 2010's 1,389,592 1,408,314 1,447,947

  10. Michigan Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Michigan Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 178,469 185,961 191,474 1990's 195,766 198,890 201,561 204,453 207,629 211,817 214,843 222,726 224,506 227,159 2000's 230,558 225,109 247,818 246,123 246,991 253,415 254,923 253,139 252,382 252,017 2010's 249,309 249,456 249,994 250,994 253,127 - = No Data Reported; -- = Not Applicable; NA = Not

  11. Michigan Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Michigan Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 10,885 11,117 11,452 1990's 11,500 11,446 11,460 11,425 11,308 11,454 11,848 12,233 11,888 14,527 2000's 11,384 11,210 10,468 10,378 10,088 10,049 9,885 9,728 10,563 18,186 2010's 9,332 9,088 8,833 8,497 8,156 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  12. Michigan Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Michigan Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2,452,554 2,491,149 2,531,304 1990's 2,573,570 2,609,561 2,640,579 2,677,085 2,717,683 2,767,190 2,812,876 2,859,483 2,903,698 2,949,628 2000's 2,999,737 3,011,205 3,110,743 3,140,021 3,161,370 3,187,583 3,193,920 3,188,152 3,172,623 3,169,026 2010's 3,152,468 3,153,895 3,161,033 3,180,349

  13. Minnesota Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Minnesota Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 88,789 90,256 92,916 1990's 95,474 97,388 99,707 93,062 102,857 103,874 105,531 108,686 110,986 114,127 2000's 116,529 119,007 121,751 123,123 125,133 126,310 129,149 128,367 130,847 131,801 2010's 132,163 132,938 134,394 135,557 136,382 - = No Data Reported; -- = Not Applicable; NA = Not Available;

  14. Minnesota Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Minnesota Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2,585 2,670 2,638 1990's 2,574 2,486 2,515 2,477 2,592 2,531 2,564 2,233 2,188 2,267 2000's 2,025 1,996 2,029 2,074 2,040 1,432 1,257 1,146 1,131 2,039 2010's 2,106 1,770 1,793 1,870 1,878 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  15. Minnesota Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Minnesota Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 872,148 894,380 911,001 1990's 946,107 970,941 998,201 1,074,631 1,049,263 1,080,009 1,103,709 1,134,019 1,161,423 1,190,190 2000's 1,222,397 1,249,748 1,282,751 1,308,143 1,338,061 1,364,237 1,401,362 1,401,623 1,413,162 1,423,703 2010's 1,429,681 1,436,063 1,445,824 1,459,134 1,472,663 - = No

  16. Mississippi Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Mississippi Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 43,362 44,170 44,253 1990's 43,184 43,693 44,313 45,310 43,803 45,444 46,029 47,311 45,345 47,620 2000's 50,913 51,109 50,468 50,928 54,027 54,936 55,741 56,155 55,291 50,713 2010's 50,537 50,636 50,689 50,153 50,238 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to

  17. Mississippi Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Mississippi Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 1,312 1,263 1,282 1990's 1,317 1,314 1,327 1,324 1,313 1,298 1,241 1,199 1,165 1,246 2000's 1,199 1,214 1,083 1,161 996 1,205 1,181 1,346 1,132 1,141 2010's 980 982 936 933 943 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company

  18. Mississippi Natural Gas Number of Residential Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Residential Consumers (Number of Elements) Mississippi Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 370,094 372,238 376,353 1990's 382,251 386,264 392,155 398,472 405,312 415,123 418,442 423,397 415,673 426,352 2000's 434,501 438,069 435,146 438,861 445,212 445,856 437,669 445,043 443,025 437,715 2010's 436,840 442,479 442,840 445,589 444,423 - = No Data Reported; -- = Not

  19. Missouri Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Missouri Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 96,711 97,939 99,721 1990's 105,164 117,675 125,174 125,571 132,378 130,318 133,445 135,553 135,417 133,464 2000's 133,969 135,968 137,924 140,057 141,258 142,148 143,632 142,965 141,529 140,633 2010's 138,670 138,214 144,906 142,495 143,024 - = No Data Reported; -- = Not Applicable; NA = Not

  20. Missouri Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Missouri Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2,832 2,880 3,063 1990's 3,140 3,096 2,989 3,040 3,115 3,033 3,408 3,097 3,151 3,152 2000's 3,094 3,085 2,935 3,115 3,600 3,545 3,548 3,511 3,514 3,573 2010's 3,541 3,307 3,692 3,538 3,497 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  1. Missouri Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Missouri Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 1,180,546 1,194,985 1,208,523 1990's 1,213,305 1,211,342 1,220,203 1,225,921 1,281,007 1,259,102 1,275,465 1,293,032 1,307,563 1,311,865 2000's 1,324,282 1,326,160 1,340,726 1,343,614 1,346,773 1,348,743 1,353,892 1,354,173 1,352,015 1,348,781 2010's 1,348,549 1,342,920 1,389,910 1,357,740

  2. Montana Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Montana Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 21,382 22,246 22,219 1990's 23,331 23,185 23,610 24,373 25,349 26,329 26,374 27,457 28,065 28,424 2000's 29,215 29,429 30,250 30,814 31,357 31,304 31,817 32,472 33,008 33,731 2010's 34,002 34,305 34,504 34,909 35,205 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  3. Montana Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Montana Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 167,883 171,785 171,156 1990's 174,384 177,726 182,641 188,879 194,357 203,435 205,199 209,806 218,851 222,114 2000's 224,784 226,171 229,015 232,839 236,511 240,554 245,883 247,035 253,122 255,472 2010's 257,322 259,046 259,957 262,122 265,849 - = No Data Reported; -- = Not Applicable; NA = Not

  4. Nebraska Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Nebraska Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 60,707 61,365 60,377 1990's 60,405 60,947 61,319 60,599 62,045 61,275 61,117 51,661 63,819 53,943 2000's 55,194 55,692 56,560 55,999 57,087 57,389 56,548 55,761 58,160 56,454 2010's 56,246 56,553 56,608 58,005 57,191 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  5. Nebraska Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Nebraska Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 675 684 702 1990's 712 718 696 718 766 2,432 2,234 11,553 10,673 10,342 2000's 10,161 10,504 9,156 9,022 8,463 7,973 7,697 7,668 11,627 7,863 2010's 7,912 7,955 8,160 8,495 8,791 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company

  6. Nevada Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Nevada Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 18,294 18,921 19,924 1990's 20,694 22,124 22,799 23,207 24,521 25,593 26,613 27,629 29,030 30,521 2000's 31,789 32,782 33,877 34,590 35,792 37,093 38,546 40,128 41,098 41,303 2010's 40,801 40,944 41,192 41,710 42,338 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  7. Nevada Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Nevada Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 213,422 219,981 236,237 1990's 256,119 283,307 295,714 305,099 336,353 364,112 393,783 426,221 458,737 490,029 2000's 520,233 550,850 580,319 610,756 648,551 688,058 726,772 750,570 758,315 760,391 2010's 764,435 772,880 782,759 794,150 808,970 - = No Data Reported; -- = Not Applicable; NA = Not

  8. New Hampshire Natural Gas Number of Commercial Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Commercial Consumers (Number of Elements) New Hampshire Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 8,831 9,159 10,237 1990's 10,521 11,088 11,383 11,726 12,240 12,450 12,755 13,225 13,512 13,932 2000's 14,219 15,068 15,130 15,047 15,429 16,266 16,139 16,150 41,332 16,937 2010's 16,645 17,186 17,758 17,298 17,421 - = No Data Reported; -- = Not Applicable; NA = Not Available; W =

  9. New Hampshire Natural Gas Number of Residential Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Residential Consumers (Number of Elements) New Hampshire Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 60,078 61,969 64,059 1990's 65,310 67,991 69,356 70,938 72,656 74,232 75,175 77,092 78,786 80,958 2000's 82,813 84,760 87,147 88,170 88,600 94,473 94,600 94,963 67,945 96,924 2010's 95,361 97,400 99,738 98,715 99,146 - = No Data Reported; -- = Not Applicable; NA = Not Available;

  10. North Carolina Natural Gas Number of Industrial Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Industrial Consumers (Number of Elements) North Carolina Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 3,236 3,196 3,381 1990's 2,802 3,506 3,119 2,664 3,401 3,652 3,973 5,375 6,228 5,672 2000's 5,288 2,962 3,200 3,101 3,021 2,891 2,701 2,991 2,984 2,384 2010's 2,457 2,468 2,525 2,567 2,596 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  11. North Carolina Natural Gas Number of Residential Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Residential Consumers (Number of Elements) North Carolina Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 435,826 472,928 492,821 1990's 520,140 539,321 575,096 607,388 652,307 678,147 699,159 740,013 777,805 815,908 2000's 858,004 891,227 905,816 953,732 948,283 992,906 1,022,430 1,063,871 1,095,362 1,102,001 2010's 1,115,532 1,128,963 1,142,947 1,161,398 1,183,152 - = No Data

  12. North Dakota Natural Gas Number of Commercial Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Commercial Consumers (Number of Elements) North Dakota Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 11,905 12,104 12,454 1990's 12,742 12,082 12,353 12,650 12,944 13,399 13,789 14,099 14,422 15,050 2000's 15,531 15,740 16,093 16,202 16,443 16,518 16,848 17,013 17,284 17,632 2010's 17,823 18,421 19,089 19,855 20,687 - = No Data Reported; -- = Not Applicable; NA = Not Available; W =

  13. North Dakota Natural Gas Number of Residential Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Residential Consumers (Number of Elements) North Dakota Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 83,517 84,059 84,643 1990's 85,646 87,880 89,522 91,237 93,398 95,818 97,761 98,326 101,930 104,051 2000's 105,660 106,758 108,716 110,048 112,206 114,152 116,615 118,100 120,056 122,065 2010's 123,585 125,392 130,044 133,975 137,972 - = No Data Reported; -- = Not Applicable; NA =

  14. Ohio Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Ohio Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 213,601 219,257 225,347 1990's 233,075 236,519 237,861 240,684 245,190 250,223 259,663 254,991 258,076 266,102 2000's 269,561 269,327 271,160 271,203 272,445 277,767 270,552 272,555 272,899 270,596 2010's 268,346 268,647 267,793 269,081 269,758 - = No Data Reported; -- = Not Applicable; NA = Not

  15. Ohio Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Ohio Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 7,929 8,163 8,356 1990's 8,301 8,479 8,573 8,678 8,655 8,650 8,672 7,779 8,112 8,136 2000's 8,267 8,515 8,111 8,098 7,899 8,328 6,929 6,858 6,806 6,712 2010's 6,571 6,482 6,381 6,554 6,526 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  16. Ohio Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Ohio Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2,648,972 2,678,838 2,714,839 1990's 2,766,912 2,801,716 2,826,713 2,867,959 2,921,536 2,967,375 2,994,891 3,041,948 3,050,960 3,111,108 2000's 3,178,840 3,195,584 3,208,466 3,225,908 3,250,068 3,272,307 3,263,062 3,273,791 3,262,716 3,253,184 2010's 3,240,619 3,236,160 3,244,274 3,271,074 3,283,869 -

  17. Oklahoma Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Oklahoma Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 87,824 86,666 86,172 1990's 85,790 86,744 87,120 88,181 87,494 88,358 89,852 90,284 89,711 80,986 2000's 80,558 79,045 80,029 79,733 79,512 78,726 78,745 93,991 94,247 94,314 2010's 92,430 93,903 94,537 95,385 96,004 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  18. Oklahoma Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Oklahoma Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2,772 2,689 2,877 1990's 2,889 2,840 2,859 2,912 2,853 2,845 2,843 2,531 3,295 3,040 2000's 2,821 3,403 3,438 3,367 3,283 2,855 2,811 2,822 2,920 2,618 2010's 2,731 2,733 2,872 2,958 3,063 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  19. Oklahoma Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Oklahoma Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 809,171 805,107 806,875 1990's 814,296 824,172 832,677 842,130 845,448 856,604 866,531 872,454 877,236 867,922 2000's 859,951 868,314 875,338 876,420 875,271 880,403 879,589 920,616 923,650 924,745 2010's 914,869 922,240 927,346 931,981 937,237 - = No Data Reported; -- = Not Applicable; NA = Not

  20. Oregon Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Oregon Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 40,967 41,998 43,997 1990's 47,175 55,374 50,251 51,910 53,700 55,409 57,613 60,419 63,085 65,034 2000's 66,893 68,098 69,150 74,515 71,762 73,520 74,683 80,998 76,868 76,893 2010's 77,370 77,822 78,237 79,276 80,480 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  1. Oregon Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Oregon Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 676 1,034 738 1990's 699 787 740 696 765 791 799 704 695 718 2000's 717 821 842 926 907 1,118 1,060 1,136 1,075 1,051 2010's 1,053 1,066 1,076 1,085 1,099 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016

  2. Oregon Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Oregon Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 280,670 288,066 302,156 1990's 326,177 376,166 354,256 371,151 391,845 411,465 433,638 456,960 477,796 502,000 2000's 523,952 542,799 563,744 625,398 595,495 626,685 647,635 664,455 674,421 675,582 2010's 682,737 688,681 693,507 700,211 707,010 - = No Data Reported; -- = Not Applicable; NA = Not

  3. Pennsylvania Natural Gas Number of Commercial Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Commercial Consumers (Number of Elements) Pennsylvania Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 166,901 172,615 178,545 1990's 186,772 191,103 193,863 198,299 206,812 209,245 214,340 215,057 216,519 223,732 2000's 228,037 225,911 226,957 227,708 231,051 233,132 231,540 234,597 233,462 233,334 2010's 233,751 233,588 235,049 237,922 239,681 - = No Data Reported; -- = Not

  4. Pennsylvania Natural Gas Number of Industrial Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Industrial Consumers (Number of Elements) Pennsylvania Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 6,089 6,070 6,023 1990's 6,238 6,344 6,496 6,407 6,388 6,328 6,441 6,492 6,736 7,080 2000's 6,330 6,159 5,880 5,577 5,726 5,577 5,241 4,868 4,772 4,745 2010's 4,624 5,007 5,066 5,024 5,084 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  5. Pennsylvania Natural Gas Number of Residential Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Residential Consumers (Number of Elements) Pennsylvania Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2,237,877 2,271,801 2,291,242 1990's 2,311,795 2,333,377 2,363,575 2,386,249 2,393,053 2,413,715 2,431,909 2,452,524 2,493,639 2,486,704 2000's 2,519,794 2,542,724 2,559,024 2,572,584 2,591,458 2,600,574 2,605,782 2,620,755 2,631,340 2,635,886 2010's 2,646,211 2,667,392 2,678,547

  6. Rhode Island Natural Gas Number of Commercial Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Commercial Consumers (Number of Elements) Rhode Island Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 15,128 16,096 16,924 1990's 17,765 18,430 18,607 21,178 21,208 21,472 21,664 21,862 22,136 22,254 2000's 22,592 22,815 23,364 23,270 22,994 23,082 23,150 23,007 23,010 22,988 2010's 23,049 23,177 23,359 23,742 23,934 - = No Data Reported; -- = Not Applicable; NA = Not Available; W =

  7. Rhode Island Natural Gas Number of Residential Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Residential Consumers (Number of Elements) Rhode Island Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 180,656 185,861 190,796 1990's 195,100 196,438 197,926 198,563 200,959 202,947 204,259 212,777 208,208 211,097 2000's 214,474 216,781 219,769 221,141 223,669 224,320 225,027 223,589 224,103 224,846 2010's 225,204 225,828 228,487 231,763 233,786 - = No Data Reported; -- = Not

  8. South Carolina Natural Gas Number of Commercial Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Commercial Consumers (Number of Elements) South Carolina Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 35,414 37,075 38,856 1990's 39,904 39,999 40,968 42,191 45,487 47,293 48,650 50,817 52,237 53,436 2000's 54,794 55,257 55,608 55,909 56,049 56,974 57,452 57,544 56,317 55,850 2010's 55,853 55,846 55,908 55,997 56,172 - = No Data Reported; -- = Not Applicable; NA = Not Available; W

  9. South Carolina Natural Gas Number of Industrial Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Industrial Consumers (Number of Elements) South Carolina Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 1,256 1,273 1,307 1990's 1,384 1,400 1,568 1,625 1,928 1,802 1,759 1,764 1,728 1,768 2000's 1,715 1,702 1,563 1,574 1,528 1,535 1,528 1,472 1,426 1,358 2010's 1,325 1,329 1,435 1,452 1,426 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  10. South Carolina Natural Gas Number of Residential Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Residential Consumers (Number of Elements) South Carolina Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 302,321 313,831 327,527 1990's 339,486 344,763 357,818 370,411 416,773 412,259 426,088 443,093 460,141 473,799 2000's 489,340 501,161 508,686 516,362 527,008 541,523 554,953 570,213 561,196 565,774 2010's 570,797 576,594 583,633 593,286 604,743 - = No Data Reported; -- = Not

  11. South Dakota Natural Gas Number of Commercial Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Commercial Consumers (Number of Elements) South Dakota Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 12,480 12,438 12,771 1990's 13,443 13,692 14,133 16,523 15,539 16,285 16,880 17,432 17,972 18,453 2000's 19,100 19,378 19,794 20,070 20,457 20,771 21,149 21,502 21,819 22,071 2010's 22,267 22,570 22,955 23,214 23,591 - = No Data Reported; -- = Not Applicable; NA = Not Available; W =

  12. South Dakota Natural Gas Number of Residential Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Residential Consumers (Number of Elements) South Dakota Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 101,468 102,084 103,538 1990's 105,436 107,846 110,291 128,029 119,544 124,152 127,269 130,307 133,095 136,789 2000's 142,075 144,310 147,356 150,725 148,105 157,457 160,481 163,458 165,694 168,096 2010's 169,838 170,877 173,856 176,204 179,042 - = No Data Reported; -- = Not

  13. Tennessee Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Tennessee Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 77,104 81,159 84,040 1990's 88,753 89,863 91,999 94,860 97,943 101,561 103,867 105,925 109,772 112,978 2000's 115,691 118,561 120,130 131,916 125,042 124,755 126,970 126,324 128,007 127,704 2010's 127,914 128,969 130,139 131,091 131,001 - = No Data Reported; -- = Not Applicable; NA = Not Available;

  14. Tennessee Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Tennessee Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2,206 2,151 2,555 1990's 2,361 2,369 2,425 2,512 2,440 2,393 2,306 2,382 5,149 2,159 2000's 2,386 2,704 2,657 2,755 2,738 2,498 2,545 2,656 2,650 2,717 2010's 2,702 2,729 2,679 2,581 2,595 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  15. Tennessee Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Tennessee Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 534,882 565,856 599,042 1990's 627,031 661,105 696,140 733,363 768,421 804,724 841,232 867,793 905,757 937,896 2000's 969,537 993,363 1,009,225 1,022,628 1,037,429 1,049,307 1,063,328 1,071,756 1,084,102 1,083,573 2010's 1,085,387 1,089,009 1,084,726 1,094,122 1,106,681 - = No Data Reported; -- =

  16. Texas Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Texas Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 4,852 4,427 13,383 1990's 13,659 13,770 5,481 5,823 5,222 9,043 8,796 5,339 5,318 5,655 2000's 11,613 10,047 9,143 9,015 9,359 9,136 8,664 11,063 5,568 8,581 2010's 8,779 8,713 8,953 8,525 8,406 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  17. Utah Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Utah Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 31,329 32,637 32,966 1990's 34,697 35,627 36,145 37,816 39,183 40,101 40,107 40,689 42,054 43,861 2000's 47,201 47,477 50,202 51,063 51,503 55,174 55,821 57,741 59,502 60,781 2010's 61,976 62,885 63,383 64,114 65,134 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  18. Utah Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Utah Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 414,020 418,569 432,377 1990's 453,023 455,649 467,664 484,438 503,583 523,622 562,343 567,786 588,364 609,603 2000's 641,111 657,728 660,677 678,833 701,255 743,761 754,554 778,644 794,880 810,442 2010's 821,525 830,219 840,687 854,389 869,052 - = No Data Reported; -- = Not Applicable; NA = Not

  19. Vermont Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Vermont Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2,447 2,698 2,768 1990's 2,949 3,154 3,198 3,314 3,512 3,649 3,790 3,928 4,034 4,219 2000's 4,316 4,416 4,516 4,602 4,684 4,781 4,861 4,925 4,980 5,085 2010's 5,137 5,256 5,535 5,441 5,589 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  20. Vermont Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Vermont Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 15,553 16,616 16,920 1990's 18,300 19,879 20,468 21,553 22,546 23,523 24,383 25,539 26,664 27,931 2000's 28,532 29,463 30,108 30,856 31,971 33,015 34,081 34,937 35,929 37,242 2010's 38,047 38,839 39,917 41,152 42,231 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to

  1. Virginia Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Virginia Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 54,071 54,892 61,012 1990's 63,751 67,997 69,629 70,161 72,188 74,690 77,284 78,986 77,220 80,500 2000's 84,646 84,839 86,328 87,202 87,919 90,577 91,481 93,015 94,219 95,704 2010's 95,401 96,086 96,503 97,499 98,741 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  2. Virginia Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Virginia Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 877 895 895 1990's 929 1,156 1,101 2,706 2,740 2,812 2,822 2,391 2,469 2,984 2000's 1,749 1,261 1,526 1,517 1,217 1,402 1,256 1,271 1,205 1,126 2010's 1,059 1,103 1,132 1,132 1,123 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company

  3. Virginia Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Virginia Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 550,318 573,731 601,906 1990's 622,883 651,203 664,500 690,061 721,495 753,003 789,985 812,866 847,938 893,887 2000's 907,855 941,582 982,521 996,564 1,029,389 1,066,302 1,085,509 1,101,863 1,113,016 1,124,717 2010's 1,133,103 1,145,049 1,155,636 1,170,161 1,183,894 - = No Data Reported; -- = Not

  4. Washington Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Washington Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 51,365 56,487 55,231 1990's 58,148 60,887 63,391 65,810 68,118 70,781 73,708 75,550 77,770 80,995 2000's 83,189 84,628 85,286 87,082 93,559 92,417 93,628 95,615 97,799 98,965 2010's 99,231 99,674 100,038 100,939 101,730 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to

  5. Washington Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Washington Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 3,355 3,564 3,365 1990's 3,428 3,495 3,490 3,448 3,586 3,544 3,587 3,748 3,848 4,040 2000's 4,007 3,898 3,928 3,775 3,992 3,489 3,428 3,630 3,483 3,428 2010's 3,372 3,353 3,338 3,320 3,355 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  6. Washington Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Washington Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 392,469 413,008 425,624 1990's 458,013 492,189 528,913 565,475 604,315 638,603 673,357 702,701 737,208 779,104 2000's 813,319 841,617 861,943 895,800 926,510 966,199 997,728 1,025,171 1,047,319 1,059,239 2010's 1,067,979 1,079,277 1,088,762 1,102,318 1,118,193 - = No Data Reported; -- = Not

  7. California Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) California Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 413 404,507 407,435 410,231 1990's 415,073 421,278 412,467 411,648 411,140 411,535 408,294 406,803 588,224 416,791 2000's 413,003 416,036 420,690 431,795 432,367 434,899 442,052 446,267 447,160 441,806 2010's 439,572 440,990 442,708 444,342 443,115 - = No Data Reported; -- = Not Applicable; NA =

  8. California Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) California Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 31 44,764 44,680 46,243 1990's 46,048 44,865 40,528 42,748 38,750 38,457 36,613 35,830 36,235 36,435 2000's 35,391 34,893 33,725 34,617 41,487 40,226 38,637 39,134 39,591 38,746 2010's 38,006 37,575 37,686 37,996 37,548 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to

  9. California Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) California Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 7,626 7,904,858 8,113,034 8,313,776 1990's 8,497,848 8,634,774 8,680,613 8,726,187 8,790,733 8,865,541 8,969,308 9,060,473 9,181,928 9,331,206 2000's 9,370,797 9,603,122 9,726,642 9,803,311 9,957,412 10,124,433 10,329,224 10,439,220 10,515,162 10,510,950 2010's 10,542,584 10,625,190 10,681,916

  10. Colorado Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Colorado Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 108 109,770 110,769 112,004 1990's 112,661 113,945 114,898 115,924 115,994 118,502 121,221 123,580 125,178 129,041 2000's 131,613 134,393 136,489 138,621 138,543 137,513 139,746 141,420 144,719 145,624 2010's 145,460 145,837 145,960 150,145 150,235 - = No Data Reported; -- = Not Applicable; NA = Not

  11. Colorado Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Colorado Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 1 896 923 976 1990's 1,018 1,074 1,108 1,032 1,176 1,528 2,099 2,923 3,349 4,727 2000's 4,994 4,729 4,337 4,054 4,175 4,318 4,472 4,592 4,816 5,084 2010's 6,232 6,529 6,906 7,293 7,823 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  12. Colorado Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Colorado Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 925 942,571 955,810 970,512 1990's 983,592 1,002,154 1,022,542 1,044,699 1,073,308 1,108,899 1,147,743 1,183,978 1,223,433 1,265,032 2000's 1,315,619 1,365,413 1,412,923 1,453,974 1,496,876 1,524,813 1,558,911 1,583,945 1,606,602 1,622,434 2010's 1,634,587 1,645,716 1,659,808 1,672,312 1,690,581 -

  13. Connecticut Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Connecticut Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2 2,709 2,818 2,908 1990's 3,061 2,921 2,923 2,952 3,754 3,705 3,435 3,459 3,441 3,465 2000's 3,683 3,881 3,716 3,625 3,470 3,437 3,393 3,317 3,196 3,138 2010's 3,063 3,062 3,148 4,454 4,217 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of

  14. Delaware Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Delaware Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 6 6,180 6,566 7,074 1990's 7,485 7,895 8,173 8,409 8,721 9,133 9,518 9,807 10,081 10,441 2000's 9,639 11,075 11,463 11,682 11,921 12,070 12,345 12,576 12,703 12,839 2010's 12,861 12,931 12,997 13,163 13,352 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  15. Delaware Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Delaware Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 81 82,829 84,328 86,428 1990's 88,894 91,467 94,027 96,914 100,431 103,531 106,548 109,400 112,507 115,961 2000's 117,845 122,829 126,418 129,870 133,197 137,115 141,276 145,010 147,541 149,006 2010's 150,458 152,005 153,307 155,627 158,502 - = No Data Reported; -- = Not Applicable; NA = Not

  16. Florida Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Florida Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 41 42,376 43,178 43,802 1990's 43,674 45,012 45,123 47,344 47,851 46,459 47,578 48,251 46,778 50,052 2000's 50,888 53,118 53,794 55,121 55,324 55,479 55,259 57,320 58,125 59,549 2010's 60,854 61,582 63,477 64,772 67,460 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to

  17. Florida Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Florida Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 442 444,848 446,690 452,544 1990's 457,648 467,221 471,863 484,816 497,777 512,365 521,674 532,790 542,770 556,628 2000's 571,972 590,221 603,690 617,373 639,014 656,069 673,122 682,996 679,265 674,090 2010's 675,551 679,199 686,994 694,210 703,535 - = No Data Reported; -- = Not Applicable; NA = Not

  18. Georgia Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Georgia Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 94 98,809 102,277 106,690 1990's 108,295 109,659 111,423 114,889 117,980 120,122 123,200 123,367 126,050 225,020 2000's 128,275 130,373 128,233 129,867 128,923 128,389 127,843 127,832 126,804 127,347 2010's 124,759 123,454 121,243 126,060 122,573 - = No Data Reported; -- = Not Applicable; NA = Not

  19. Georgia Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Georgia Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 3 3,034 3,144 3,079 1990's 3,153 3,124 3,186 3,302 3,277 3,261 3,310 3,310 3,262 5,580 2000's 3,294 3,330 3,219 3,326 3,161 3,543 3,053 2,913 2,890 2,254 2010's 2,174 2,184 2,112 2,242 2,481 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  20. Georgia Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Georgia Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 1,190 1,237,201 1,275,128 1,308,972 1990's 1,334,935 1,363,723 1,396,860 1,430,626 1,460,141 1,495,992 1,538,458 1,553,948 1,659,730 1,732,865 2000's 1,680,749 1,737,850 1,735,063 1,747,017 1,752,346 1,773,121 1,726,239 1,793,650 1,791,256 1,744,934 2010's 1,740,587 1,740,006 1,739,543 1,805,425

  1. Hawaii Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Hawaii Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2,896 2,852 2,842 1990's 2,837 2,786 2,793 3,222 2,805 2,825 2,823 2,783 2,761 2,763 2000's 2,768 2,777 2,781 2,804 2,578 2,572 2,548 2,547 2,540 2,535 2010's 2,551 2,560 2,545 2,627 2,789 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  2. Hawaii Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Hawaii Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 28,502 28,761 28,970 1990's 29,137 29,701 29,805 29,984 30,614 30,492 31,017 30,990 30,918 30,708 2000's 30,751 30,794 30,731 30,473 26,255 26,219 25,982 25,899 25,632 25,466 2010's 25,389 25,305 25,184 26,374 28,919 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  3. Idaho Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Idaho Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 17,482 18,454 18,813 1990's 19,452 20,328 21,145 21,989 22,999 24,150 25,271 26,436 27,697 28,923 2000's 30,018 30,789 31,547 32,274 33,104 33,362 33,625 33,767 37,320 38,245 2010's 38,506 38,912 39,202 39,722 40,229 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  4. Idaho Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Idaho Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 104,824 111,532 113,898 1990's 113,954 126,282 136,121 148,582 162,971 175,320 187,756 200,165 213,786 227,807 2000's 240,399 251,004 261,219 274,481 288,380 301,357 316,915 323,114 336,191 342,277 2010's 346,602 350,871 353,963 359,889 367,394 - = No Data Reported; -- = Not Applicable; NA = Not

  5. Illinois Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Illinois Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 241,367 278,473 252,791 1990's 257,851 261,107 263,988 268,104 262,308 264,756 265,007 268,841 271,585 274,919 2000's 279,179 278,506 279,838 281,877 273,967 276,763 300,606 296,465 298,418 294,226 2010's 291,395 293,213 297,523 282,743 294,391 - = No Data Reported; -- = Not Applicable; NA = Not

  6. Illinois Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Illinois Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 19,460 20,015 25,161 1990's 25,991 26,489 27,178 27,807 25,788 25,929 29,493 28,472 28,063 27,605 2000's 27,348 27,421 27,477 26,698 29,187 29,887 26,109 24,000 23,737 23,857 2010's 25,043 23,722 23,390 23,804 23,829 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  7. Illinois Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Illinois Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 3,170,364 3,180,199 3,248,117 1990's 3,287,091 3,320,285 3,354,679 3,388,983 3,418,052 3,452,975 3,494,545 3,521,707 3,556,736 3,594,071 2000's 3,631,762 3,670,693 3,688,281 3,702,308 3,754,132 3,975,961 3,812,121 3,845,441 3,869,308 3,839,438 2010's 3,842,206 3,855,942 3,878,806 3,838,120

  8. Indiana Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Indiana Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 116,571 119,458 122,803 1990's 124,919 128,223 129,973 131,925 134,336 137,162 139,097 140,515 141,307 145,631 2000's 148,411 148,830 150,092 151,586 151,943 159,649 154,322 155,885 157,223 155,615 2010's 156,557 161,293 158,213 158,965 159,596 - = No Data Reported; -- = Not Applicable; NA = Not

  9. Indiana Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Indiana Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 1,250,476 1,275,401 1,306,747 1990's 1,327,772 1,358,640 1,377,023 1,402,770 1,438,483 1,463,640 1,489,647 1,509,142 1,531,914 1,570,253 2000's 1,604,456 1,613,373 1,657,640 1,644,715 1,588,738 1,707,195 1,661,186 1,677,857 1,678,158 1,662,663 2010's 1,669,026 1,707,148 1,673,132 1,681,841 1,693,267

  10. Iowa Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Iowa Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 80,797 81,294 82,549 1990's 83,047 84,387 85,325 86,452 86,918 88,585 89,663 90,643 91,300 92,306 2000's 93,836 95,485 96,496 96,712 97,274 97,767 97,823 97,979 98,144 98,416 2010's 98,396 98,541 99,113 99,017 99,182 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  11. Iowa Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Iowa Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2,033 1,937 1,895 1990's 1,883 1,866 1,835 1,903 1,957 1,957 2,066 1,839 1,862 1,797 2000's 1,831 1,830 1,855 1,791 1,746 1,744 1,670 1,651 1,652 1,626 2010's 1,528 1,465 1,469 1,491 1,572 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  12. Iowa Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Iowa Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 690,532 689,655 701,687 1990's 706,842 716,088 729,081 740,722 750,678 760,848 771,109 780,746 790,162 799,015 2000's 812,323 818,313 824,218 832,230 839,415 850,095 858,915 865,553 872,980 875,781 2010's 879,713 883,733 892,123 895,414 900,420 - = No Data Reported; -- = Not Applicable; NA = Not

  13. Kansas Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Kansas Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 82,934 83,810 85,143 1990's 85,539 86,874 86,840 87,735 86,457 88,163 89,168 85,018 89,654 86,003 2000's 87,007 86,592 87,397 88,030 86,640 85,634 85,686 85,376 84,703 84,715 2010's 84,446 84,874 84,673 84,969 85,867 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  14. Kansas Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Kansas Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 4,440 4,314 4,366 1990's 4,357 3,445 3,296 4,369 3,560 3,079 2,988 7,014 10,706 5,861 2000's 8,833 9,341 9,891 9,295 8,955 8,300 8,152 8,327 8,098 7,793 2010's 7,664 7,954 7,970 7,877 7,429 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  15. Kansas Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Kansas Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 725,676 733,101 731,792 1990's 747,081 753,839 762,545 777,658 773,357 797,524 804,213 811,975 841,843 824,803 2000's 833,662 836,486 843,353 850,464 855,272 856,761 862,203 858,304 853,125 855,454 2010's 853,842 854,730 854,800 858,572 861,092 - = No Data Reported; -- = Not Applicable; NA = Not

  16. Kentucky Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Kentucky Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 63,024 63,971 65,041 1990's 67,086 68,461 69,466 71,998 73,562 74,521 76,079 77,693 80,147 80,283 2000's 81,588 81,795 82,757 84,110 84,493 85,243 85,236 85,210 84,985 83,862 2010's 84,707 84,977 85,129 85,999 85,318 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  17. Kentucky Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Kentucky Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 1,391 1,436 1,443 1990's 1,544 1,587 1,608 1,585 1,621 1,630 1,633 1,698 1,864 1,813 2000's 1,801 1,701 1,785 1,695 1,672 1,698 1,658 1,599 1,585 1,715 2010's 1,742 1,705 1,720 1,767 1,780 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  18. Kentucky Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Kentucky Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 596,320 606,106 614,058 1990's 624,477 633,942 644,281 654,664 668,774 685,481 696,989 713,509 726,960 735,371 2000's 744,816 749,106 756,234 763,290 767,022 770,080 770,171 771,047 753,531 754,761 2010's 758,129 759,584 757,790 761,575 760,131 - = No Data Reported; -- = Not Applicable; NA = Not

  19. Louisiana Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Louisiana Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 67,382 66,472 64,114 1990's 62,770 61,574 61,030 62,055 62,184 62,930 62,101 62,270 63,029 62,911 2000's 62,710 62,241 62,247 63,512 60,580 58,409 57,097 57,127 57,066 58,396 2010's 58,562 58,749 63,381 59,147 58,611 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to

  20. Louisiana Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Louisiana Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 1,617 1,503 1,531 1990's 1,504 1,469 1,452 1,592 1,737 1,383 1,444 1,406 1,380 1,397 2000's 1,318 1,440 1,357 1,291 1,460 1,086 962 945 988 954 2010's 942 920 963 916 883 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data.

  1. Maine Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Maine Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 3,435 3,731 3,986 1990's 4,250 4,455 4,838 4,979 5,297 5,819 6,414 6,606 6,662 6,582 2000's 6,954 6,936 7,375 7,517 7,687 8,178 8,168 8,334 8,491 8,815 2010's 9,084 9,681 10,179 11,415 11,810 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  2. Maine Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Maine Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 12,134 11,933 11,902 1990's 12,000 12,424 13,766 13,880 14,104 14,917 14,982 15,221 15,646 15,247 2000's 17,111 17,302 17,921 18,385 18,707 18,633 18,824 18,921 19,571 20,806 2010's 21,142 22,461 23,555 24,765 27,047 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  3. Maryland Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Maryland Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 51,252 53,045 54,740 1990's 55,576 61,878 62,858 63,767 64,698 66,094 69,991 69,056 67,850 69,301 2000's 70,671 70,691 71,824 72,076 72,809 73,780 74,584 74,856 75,053 75,771 2010's 75,192 75,788 75,799 77,117 77,846 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  4. Maryland Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Maryland Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 5,222 5,397 5,570 1990's 5,646 520 514 496 516 481 430 479 1,472 536 2000's 329 795 1,434 1,361 1,354 1,325 1,340 1,333 1,225 1,234 2010's 1,255 1,226 1,163 1,173 1,179 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release

  5. Maryland Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Maryland Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 755,294 760,754 767,219 1990's 774,707 782,373 894,677 807,204 824,137 841,772 871,012 890,195 901,455 939,029 2000's 941,384 959,772 978,319 987,863 1,009,455 1,024,955 1,040,941 1,053,948 1,057,521 1,067,807 2010's 1,071,566 1,077,168 1,078,978 1,099,272 1,101,292 - = No Data Reported; -- = Not

  6. West Virginia Natural Gas Number of Commercial Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Commercial Consumers (Number of Elements) West Virginia Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 31,283 33,192 33,880 1990's 32,785 32,755 33,289 33,611 33,756 36,144 33,837 33,970 35,362 35,483 2000's 41,949 35,607 35,016 35,160 34,932 36,635 34,748 34,161 34,275 34,044 2010's 34,063 34,041 34,078 34,283 34,339 - = No Data Reported; -- = Not Applicable; NA = Not Available; W

  7. West Virginia Natural Gas Number of Residential Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Residential Consumers (Number of Elements) West Virginia Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 351,024 349,765 349,347 1990's 349,673 350,489 352,463 352,997 352,929 353,629 358,049 362,432 359,783 362,292 2000's 360,471 363,126 361,171 359,919 358,027 374,301 353,292 347,433 347,368 343,837 2010's 344,131 342,069 340,256 340,102 338,652 - = No Data Reported; -- = Not

  8. Wisconsin Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Wisconsin Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 96,760 99,157 102,492 1990's 106,043 109,616 112,761 115,961 119,788 125,539 129,146 131,238 134,651 135,829 2000's 140,370 144,050 149,774 150,128 151,907 155,109 159,074 160,614 163,026 163,843 2010's 164,173 165,002 165,657 166,845 167,901 - = No Data Reported; -- = Not Applicable; NA = Not

  9. Wisconsin Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Wisconsin Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 7,411 7,218 7,307 1990's 7,154 7,194 7,396 7,979 7,342 6,454 5,861 8,346 9,158 9,756 2000's 9,630 9,864 9,648 10,138 10,190 8,484 5,707 5,999 5,969 6,396 2010's 6,413 6,376 6,581 6,677 7,000 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  10. Wisconsin Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Wisconsin Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 1,054,347 1,072,585 1,097,514 1990's 1,123,557 1,151,939 1,182,834 1,220,500 1,253,333 1,291,424 1,324,570 1,361,348 1,390,068 1,426,909 2000's 1,458,959 1,484,536 1,514,700 1,541,455 1,569,719 1,592,621 1,611,772 1,632,200 1,646,644 1,656,614 2010's 1,663,583 1,671,834 1,681,001 1,692,891

  11. Wyoming Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Wyoming Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 15,342 15,093 14,012 1990's 13,767 14,931 15,064 15,315 15,348 15,580 17,036 15,907 16,171 16,317 2000's 16,366 16,027 16,170 17,164 17,490 17,904 18,016 18,062 19,286 19,843 2010's 19,977 20,146 20,387 20,617 20,894 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  12. Wyoming Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Wyoming Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 113,175 112,126 113,129 1990's 113,598 113,463 114,793 116,027 117,385 119,544 131,910 125,740 127,324 127,750 2000's 129,274 129,897 133,445 135,441 137,434 140,013 142,385 143,644 152,439 153,062 2010's 153,852 155,181 157,226 158,889 160,896 - = No Data Reported; -- = Not Applicable; NA = Not

  13. Extracting metals directly from metal oxides

    DOE Patents [OSTI]

    Wai, C.M.; Smart, N.G.; Phelps, C.

    1997-02-25

    A method of extracting metals directly from metal oxides by exposing the oxide to a supercritical fluid solvent containing a chelating agent is described. Preferably, the metal is an actinide or a lanthanide. More preferably, the metal is uranium, thorium or plutonium. The chelating agent forms chelates that are soluble in the supercritical fluid, thereby allowing direct removal of the metal from the metal oxide. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of {beta}-diketones, halogenated {beta}-diketones, phosphinic acids, halogenated phosphinic acids, carboxylic acids, halogenated carboxylic acids, and mixtures thereof. In especially preferred embodiments, at least one of the chelating agents is fluorinated. The method provides an environmentally benign process for removing metals from metal oxides without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the metal recovered, to provide an economic, efficient process. 4 figs.

  14. Extracting metals directly from metal oxides

    DOE Patents [OSTI]

    Wai, Chien M.; Smart, Neil G.; Phelps, Cindy

    1997-01-01

    A method of extracting metals directly from metal oxides by exposing the oxide to a supercritical fluid solvent containing a chelating agent is described. Preferably, the metal is an actinide or a lanthanide. More preferably, the metal is uranium, thorium or plutonium. The chelating agent forms chelates that are soluble in the supercritical fluid, thereby allowing direct removal of the metal from the metal oxide. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of .beta.-diketones, halogenated .beta.-diketones, phosphinic acids, halogenated phosphinic acids, carboxylic acids, halogenated carboxylic acids, and mixtures thereof. In especially preferred embodiments, at least one of the chelating agents is fluorinated. The method provides an environmentally benign process for removing metals from metal oxides without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the metal recovered, to provide an economic, efficient process.

  15. The role of destabilization of palladium hydride on the hydrogen uptake of Pd-containing activated carbons

    SciTech Connect (OSTI)

    Bhat, Vinay V; Contescu, Cristian I; Gallego, Nidia C

    2009-01-01

    This paper reports on differences in stability of Pd hydride phases in palladium particles with various degrees of contact with microporous carbon supports. A sample containing Pd embedded in activated carbon fiber (Pd-ACF; 2 wt% Pd) was compared with commercial Pd nanoparticles deposited on microporous activated carbon (Pd-catalyst, 3 wt% Pd) and with support-free nanocrystalline palladium (Pd-black). The morphology of materials was characterized by electron microscopy, and the phase transformations were analyzed over a large range of hydrogen partial pressures (0.003 - 10 bar) and at several temperatures using in-situ X-ray diffraction. The results were verified with volumetric hydrogen uptake measurements. Results indicate that higher degree of Pd-carbon contacts for Pd particles embedded in a microporous carbon matrix induce efficient pumping of hydrogen out of -PdHx. It was also found that thermal cleaning of carbon surface groups prior to exposure to hydrogen further enhances the hydrogen pumping power of the microporous carbon support. In brief, this study highlights that the stability of -PdHx phase supported on carbon depends on the degree of contact between Pd-carbon and the nature of the carbon surface.

  16. OPERATION OF A TRITIUM GLOVEBOX CLEAN-UP SYSTEM USING ZIRCONIUM MANGANESE IRON AND ZIRCONIUM TWO IRON METAL GETTERS

    SciTech Connect (OSTI)

    E. LARSON; K. COOK

    2000-08-01

    A metal hydride-based tritium clean-up system has been successfully operated for more than four years on an 11 m{sup 3} helium/nitrogen glovebox which was used for handling metal tritide powders. The clean-up system consists of two beds: (1) a Zr-Mn-Fe (in a 10% by weight Al binder, SAES ST909) bed operating at 675 C followed by (2) a Zr{sub 2}Fe (SAES ST198) bed operating at 250 C. The Zr-Mn-Fe bed serves to condition the gas stream by cracking hydrogenous impurities (such as H{sub 2}O and hydrocarbons) and absorbing oxygen and carbon. The Zr{sub 2}Fe bed absorbs the hydrogen isotopes from the flowing stream by forming a solid hydride compound. These beds contain 3 kilograms of Zr{sub 2}Fe and have been loaded routinely with 230-250 STP liters of hydrogen isotopes in earlier trials. The Zr-Mn-Fe alloy exhibits an anomaly during activation, namely an exotherm upon initial exposure to nitrogen. The purpose of this work is to better understand this reaction. Nitrogen absorption studies were done in order to quantify the nitrogen taken up by the getter and to characterize the reaction kinetics. In addition, ST909 phases before and after the reaction were studied with x-ray diffraction.

  17. Removal of metal ions from aqueous solution

    DOE Patents [OSTI]

    Jackson, Paul J. (both Los Alamos, NM); Delhaize, Emmanuel (both Los Alamos, NM); Robinson, Nigel J. (Durham, GB2); Unkefer, Clifford J. (Los Alamos, NM); Furlong, Clement (Seattle, WA)

    1990-11-13

    A method of removing heavy metals from aqueous solution, a composition of matter used in effecting said removal, and apparatus used in effecting said removal. One or more of the polypeptides, poly (.gamma.-glutamylcysteinyl)glycines, is immobilized on an inert material in particulate form. Upon contact with an aqueous solution containing heavy metals, the polypeptides sequester the metals, removing them from the solution. There is selectivity of poly (.gamma.-glutamylcysteinyl)glycines having a particular number of monomer repeat unit for particular metals. The polypeptides are easily regenerated by contact with a small amount of an organic acid, so that they can be used again to remove heayv metals from solution. This also results in the removal of the metals from the column in a concentrated form.

  18. Removal of metal ions from aqueous solution

    DOE Patents [OSTI]

    Jackson, Paul J. (Los Alamos, NM); Delhaize, Emmanuel (Los Alamos, NM); Robinson, Nigel J. (Durham, GB2); Unkefer, Clifford J. (Los Alamos, NM); Furlong, Clement (Seattle, WA)

    1990-01-01

    A method of removing heavy metals from aqueous solution, a composition of matter used in effecting said removal, and apparatus used in effecting said removal. One or more of the polypeptides, poly (.gamma.-glutamylcysteinyl)glycines, is immobilized on an inert material in particulate form. Upon contact with an aqueous solution containing heavy metals, the polypeptides sequester the metals, removing them from the solution. There is selectivity of poly (.gamma.-glutamylcysteinyl)glycines having a particular number of monomer repeat units for particular metals. The polypeptides are easily regenerated by contact with a small amount of an organic acid, so that they can be used again to remove heavy metals from solution. This also results in the removal of the metals from the column in a concentrated form.

  19. Metal-phosphate binders

    DOE Patents [OSTI]

    Howe, Beth Ann [Lewistown, IL; Chaps-Cabrera, Jesus Guadalupe [Coahuila, MX

    2009-05-12

    A metal-phosphate binder is provided. The binder may include an aqueous phosphoric acid solution, a metal-cation donor including a metal other than aluminum, an aluminum-cation donor, and a non-carbohydrate electron donor.

  20. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide

  1. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the...

  2. Final Report for DOE Project Number: DE-FG02-05ER46241

    SciTech Connect (OSTI)

    Gang Chen; Mildred S. Dresselhaus; Costas P. Grigoropoulos; Samuel S. Mao; Xiaodong Xiang; Taofang Zeng

    2010-03-15

    Hydrogen storage is the most challenging task for the hydrogen economy. We established a multidisciplinary research program for high throughput combinatorial synthesis and characterization of novel nanoporous and metastable complex hydrides, coupled to fundamental material studies including electronic, structural and kinetic transport modeling, and pump-probe experiments. Our research is based the concept of hybrid nanostructures that store hydrogen by a combination of chemi- and physorption: atomic hydrogen is stored in metastable hydrides while molecule hydrogen is stored in the nanometer pores of the hydrides. Metastable nanostructured hydride has been achieved by introducing structural and compositional disorders through high throughput elemental substitution/doping, catalyst addition, and nonequilibrium processing. Fast screening compatible with the combinatorial synthesis was achieved by combining X-ray structural characterization with the development of a laser-based microbalance. Manufacturing of nanoporous metahydrides that are identified as promising by the combinatorial synthesis has been explored along with the materials search.

  3. Heavy metal biosensor

    DOE Patents [OSTI]

    Hillson, Nathan J; Shapiro, Lucille; Hu, Ping; Andersen, Gary L

    2014-04-15

    Compositions and methods are provided for detection of certain heavy metals using bacterial whole cell biosensors.

  4. Amorphous metal composites

    DOE Patents [OSTI]

    Byrne, Martin A. (Troy, NY); Lupinski, John H. (Scotia, NY)

    1984-01-01

    An improved amorphous metal composite and process of making the composite. The amorphous metal composite comprises amorphous metal (e.g. iron) and a low molecular weight thermosetting polymer binder. The process comprises placing an amorphous metal in particulate form and a thermosetting polymer binder powder into a container, mixing these materials, and applying heat and pressure to convert the mixture into an amorphous metal composite.

  5. Guest-Induced Electrical Conductivity in Metal-Organic Frameworks.

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Conference: Guest-Induced Electrical Conductivity in Metal-Organic Frameworks. Citation Details In-Document Search Title: Guest-Induced Electrical Conductivity in Metal-Organic Frameworks. Abstract not provided. Authors: Allendorf, Mark D. ; Talin, Albert Alec ; Leonard, Francois Leonard ; Stavila, Vitalie ; Foster, Michael E. Publication Date: 2014-09-01 OSTI Identifier: 1241681 Report Number(s): SAND2014-18118PE 537742 DOE Contract Number: AC04-94AL85000

  6. Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons

    DOE Patents [OSTI]

    Gordon, John Howard

    2014-09-09

    A method of upgrading an oil feedstock by removing heteroatoms and/or one or more heavy metals from the oil feedstock composition. This method reacts the oil feedstock with an alkali metal and an upgradant hydrocarbon. The alkali metal reacts with a portion of the heteroatoms and/or one or more heavy metals to form an inorganic phase separable from the organic oil feedstock material. The upgradant hydrocarbon bonds to the oil feedstock material and increases the number of carbon atoms in the product. This increase in the number of carbon atoms of the product increases the energy value of the resulting oil feedstock.

  7. Verification Challenges at Low Numbers

    SciTech Connect (OSTI)

    Benz, Jacob M.; Booker, Paul M.; McDonald, Benjamin S.

    2013-06-01

    Many papers have dealt with the political difficulties and ramifications of deep nuclear arms reductions, and the issues of “Going to Zero”. Political issues include extended deterrence, conventional weapons, ballistic missile defense, and regional and geo-political security issues. At each step on the road to low numbers, the verification required to ensure compliance of all parties will increase significantly. Looking post New START, the next step will likely include warhead limits in the neighborhood of 1000 . Further reductions will include stepping stones at1000 warheads, 100’s of warheads, and then 10’s of warheads before final elimination could be considered of the last few remaining warheads and weapons. This paper will focus on these three threshold reduction levels, 1000, 100’s, 10’s. For each, the issues and challenges will be discussed, potential solutions will be identified, and the verification technologies and chain of custody measures that address these solutions will be surveyed. It is important to note that many of the issues that need to be addressed have no current solution. In these cases, the paper will explore new or novel technologies that could be applied. These technologies will draw from the research and development that is ongoing throughout the national laboratory complex, and will look at technologies utilized in other areas of industry for their application to arms control verification.

  8. Highly chemoselective palladium-catalyzed conjugate reduction of. cap alpha. ,. beta. -unsaturated carbonyl compounds with silicon hydrides and zinc chloride cocatalyst

    SciTech Connect (OSTI)

    Keinan, E.; Greenspoon, N.

    1986-11-12

    A three-component system comprised of a soluble palladium catalyst, hydridosilane, and zinc chloride is capable of efficient conjugate reduction of ..cap alpha..,..beta..-unsaturated ketones and aldehydes. The optimal set of conditions includes diphenylsilane as the most effective hydride donor, any soluble palladium complex in either the O or II oxidation state, when it is stabilized by phosphine ligands, and ZnCl/sub 2/ as the best Lewis acid cocatalyst. The reaction is very general with respect to a broad range of unsaturated ketones and aldehydes, and it is highly selective for these Michael acceptors, as reduction of ..cap alpha..,..beta..-unsaturated carboxylic acid derivatives is very sluggish under these conditions. When dideuteriodiphenylsilane is used to reduce unsaturated ketones, deuterium is stereoselectivity introduced at the less-hindered fact of the substrate and regioselectively at the ..beta..-position. Conversely, when reductions are carried out in the presence of traces of D/sub 2/O, deuterium incorporation occurs at the ..cap alpha..-position. On the basis of deuterium-incorporation experiments and /sup 1/H NMR studies a catalytic cycle is postulated in which the first step involves reversible coordination of the palladium complex to the electron-deficient olefin and oxidative addition of silicon hydride to form a hydridopalladium olefin complex.

  9. Metal halogen electrochemical cell

    SciTech Connect (OSTI)

    Walsh, F.M.

    1986-06-03

    An electrochemical cell is described having a metal anode selected from the group consisting of zinc and cadmium; a bromine cathode; and, an aqueous electrolyte containing a metal bromide, the metal having the same metal as the metal of the anode, the improvement comprising: a bromine complexing agent in the aqueous metal bromide electrolyte consisting solely of a tetraorgano substituted ammonium salt, which salt is soluble of water and forms and substantially water immiscible liquid bromine complex at temperatures in the range of about 10/sup 0/C. to about 60/sup 0/C. and wherein the tetraorgano substituted ammonium salt is selected from asymmetric quaternary ammonium compounds.

  10. Alkali metal nitrate purification

    DOE Patents [OSTI]

    Fiorucci, Louis C. (Hamden, CT); Morgan, Michael J. (Guilford, CT)

    1986-02-04

    A process is disclosed for removing contaminants from impure alkali metal nitrates containing them. The process comprises heating the impure alkali metal nitrates in solution form or molten form at a temperature and for a time sufficient to effect precipitation of solid impurities and separating the solid impurities from the resulting purified alkali metal nitrates. The resulting purified alkali metal nitrates in solution form may be heated to evaporate water therefrom to produce purified molten alkali metal nitrates suitable for use as a heat transfer medium. If desired, the purified molten form may be granulated and cooled to form discrete solid particles of purified alkali metal nitrates.

  11. Electrochemical Oxidation of H? Catalyzed by Ruthenium Hydride Complexes Bearing P?N? Ligands With Pendant Amines as Proton Relays

    SciTech Connect (OSTI)

    Liu, Tianbiao L.; Rakowski DuBois, Mary; DuBois, Daniel L.; Bullock, R. Morris

    2014-01-01

    Two Ru hydride complexes (Cp*Ru(PPh?NBn?)H, (1-H) and Cp*Ru(PtBu?NBn?)H, (2-H) supported by cyclic PR?NR'? ligands (Cp* = n?-C?Me?; 1,5-diaza-3,7-diphosphacyclooctane, where R = Ph or tBu and R' = Bn) have been synthesized and fully characterized. Both complexes are demonstrated to be electrocatalysts for oxidation of H? (1 atm, 22 C) in the presence of external base, DBU (1,8-diazabicyclo[5.4.0]undec-7-ene). The turnover frequency of 2-H is 1.2 s-1, with an overpotential at Ecat/2 of 0.45 V, while catalysis by 1-H has a turnover frequency of 0.6 s-1 and an overpotential of 0.6 V at Ecat/2. Addition of H?O facilitates oxidation of H? by 2-H and increases its turnover frequency to 1.9 s-1 while , H?O slows down the catalysis by 1-H. The different effects of H?O for 1-H and 2-H are ascribed to different binding affinities of H?O to the Ru center of the corresponding unsaturated species, [Cp*Ru(PPh?NBn?)]+ and [Cp*Ru(PPh?NBn?)]+. In addition, studies of Cp*Ru(dmpm)H (where dmpm = bis(dimethylphosphino)methane), a control complex lacking pendent amines in its diphosphine ligand, confirms the critical roles of the pendent amines of P?N? ligands for oxidation of H?. We thank the U.S. Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences and Biosciences, for supporting initial parts of the work. Current work is supported by the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy.

  12. Metal to semiconductor transition in metallic transition metal dichalcogenides

    SciTech Connect (OSTI)

    Li, Yan; Kang, Jun; Li, Jingbo; Tongay, Sefaattin; Wu, Junqiao; Yue, Qu

    2013-11-07

    We report on tuning the electronic and magnetic properties of metallic transition metal dichalcogenides (mTMDCs) by 2D to 1D size confinement. The stability of the mTMDC monolayers and nanoribbons is demonstrated by the larger binding energy compared to the experimentally available semiconducting TMDCs. The 2D MX{sub 2} (M?=?Nb, Ta; X?=?S, Se) monolayers are non-ferromagnetic metals and mechanically softer compared to their semiconducting TMDCs counterparts. Interestingly, mTMDCs undergo metal-to-semiconductor transition when the ribbon width approaches to ?13? and ?7? for zigzag and armchair edge terminations, respectively; then these ribbons convert back to metal when the ribbon widths further decrease. Zigzag terminated nanoribbons are ferromagnetic semiconductors, and their magnetic properties can also be tuned by hydrogen edge passivation, whereas the armchair nanoribbons are non-ferromagnetic semiconductors. Our results display that the mTMDCs offer a broad range of physical properties spanning from metallic to semiconducting and non-ferromagnetic to ferromagnetic that is ideal for applications where stable narrow bandgap semiconductors with different magnetic properties are desired.

  13. Metal phthalocyanine catalysts

    DOE Patents [OSTI]

    Ellis, P.E. Jr.; Lyons, J.E.

    1994-10-11

    A new composition of matter is described which is an alkali metal or ammonium or tetraalkylammonium diazidoperfluorophthalocyanatoferrate. Other embodiments of the invention comprise compositions wherein the metal of the coordination complex is cobalt, manganese and chromium.

  14. Metal phthalocyanine catalysts

    DOE Patents [OSTI]

    Ellis, Jr., Paul E.; Lyons, James E.

    1994-01-01

    As a new composition of matter, alkali metal or ammonium or tetraalkylammonium diazidoperfluorophthalocyanatoferrate. Other embodiments of the invention comprise compositions wherein the metal of the coordination complex is cobalt, manganese and chromium.

  15. Nitrided Metallic Bipolar Plates

    SciTech Connect (OSTI)

    Brady, Michael P; Toops, Todd J; Tortorelli, Peter F; More, Karren Leslie; Meyer III, Harry M; Pihl, Josh A; Wang, Heli; Turner, John; Garzon, Fernando; Rockward, Tommy; Gervasio, Don; Rakowski, Jim; EstevezGenCell, Francisco

    2010-01-01

    Effort devoted to scale up and demonstration of thin stamped metallic bipolar plates. Overall goal is to demonstrate potential for metallic bipolar plates to meet 5000 h automotive durability goal at a cost of less than $5/kW.

  16. Durable metallized polymer mirror

    DOE Patents [OSTI]

    Schissel, Paul O. (Golden, CO); Kennedy, Cheryl E. (Lafayette, CO); Jorgensen, Gary J. (Pine, CO); Shinton, Yvonne D. (Northglenn, CO); Goggin, Rita M. (Englewood, CO)

    1994-01-01

    A metallized polymer mirror construction having improved durability against delamination and tunneling, comprising: an outer layer of polymeric material; a metal oxide layer underlying the outer layer of polymeric material; a silver reflective layer underneath the metal oxide layer; and a layer of adhesive attaching the silver layer to a substrate.

  17. Durable metallized polymer mirror

    DOE Patents [OSTI]

    Schissel, P.O.; Kennedy, C.E.; Jorgensen, G.J.; Shinton, Y.D.; Goggin, R.M.

    1994-11-01

    A metallized polymer mirror construction is disclosed having improved durability against delamination and tunneling, comprising: an outer layer of polymeric material; a metal oxide layer underlying the outer layer of polymeric material; a silver reflective layer underneath the metal oxide layer; and a layer of adhesive attaching the silver layer to a substrate. 6 figs.

  18. Reversible hydrogen storage materials

    DOE Patents [OSTI]

    Ritter, James A. (Lexington, SC); Wang, Tao (Columbia, SC); Ebner, Armin D. (Lexington, SC); Holland, Charles E. (Cayce, SC)

    2012-04-10

    In accordance with the present disclosure, a process for synthesis of a complex hydride material for hydrogen storage is provided. The process includes mixing a borohydride with at least one additive agent and at least one catalyst and heating the mixture at a temperature of less than about 600.degree. C. and a pressure of H.sub.2 gas to form a complex hydride material. The complex hydride material comprises MAl.sub.xB.sub.yH.sub.z, wherein M is an alkali metal or group IIA metal, Al is the element aluminum, x is any number from 0 to 1, B is the element boron, y is a number from 0 to 13, and z is a number from 4 to 57 with the additive agent and catalyst still being present. The complex hydride material is capable of cyclic dehydrogenation and rehydrogenation and has a hydrogen capacity of at least about 4 weight percent.

  19. ITP Metal Casting: Implementation of Metal Casting Best Practices |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Implementation of Metal Casting Best Practices ITP Metal Casting: Implementation of Metal Casting Best Practices PDF icon implementation_final.pdf More Documents & Publications ITP Metal Casting: Advanced Melting Technologies: Energy Saving Concepts and Opportunities for the Metal Casting Industry ITP Metal Casting: Energy Use in Selected Metalcasting Facilities - 2003 ITP Metal Casting: Energy and Environmental Profile of the U.S. Metal casting

  20. California's Efforts for Advancing Ultrafine Particle Number...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efforts for Advancing Ultrafine Particle Number Measurements for Clean Diesel Exhaust California's Efforts for Advancing Ultrafine Particle Number Measurements for Clean Diesel...

  1. Identification of Export Control Classification Number - ITER

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Identification of Export Control Classification Number - ITER (April 2012) As the "Shipper of Record" please provide the appropriate Export Control Classification Number (ECCN) for...

  2. The effect of hydriding on the physical structure of palladium and on the release of contained tritium

    SciTech Connect (OSTI)

    Storms, E.; Talcott-Storms, C. (Nuclear Materials Technology, and Material Science and Technology Divisions Los Alamos National Laboratory, MS C348, Los Alamos, New Mexico 87545 (United States))

    1991-05-10

    When Pd gains or loses hydrogen or deuterium, the lattice expands or contracts causing a change in physical dimension. Under certain conditions, there is an additional expansion that is largely irreversible. Repeated gain and loss of hydrogen caused this excess volume to steadily increase. After all dissolved hydrogen has been removed, the diameter of a rod is found to have increased and the length to have decreased. These changes suggest the creation of micropores and/or dislocations within the metal. Such changes in the ennvironment with Pd metal can alter the local D/Pd ratio, affect the diffusion of impurities and, perhaps, affect the Fleischmann-Pons Effect.

  3. Synthesis of main group, rare-earth, and d{sup 0} metal complexes containing beta-hydrogen

    SciTech Connect (OSTI)

    Yan, Ka King

    2013-05-02

    A series of organometallic compounds containing the tris(dimethylsilyl)methyl ligand are described. The potassium carbanions KC(SiHMe{sub 2}){sub 3} and KC(SiHMe{sub 2}){sub 3}TMEDA are synthesized by deprotonation of the hydrocarbon HC(SiHMe{sub 2}){sub 3} with potassium benzyl. KC(SiHMe{sub 2}){sub 3}TMEDA crystallizes as a dimer with two types of three-center-two-electron KH- Si interactions. Homoleptic Ln(III) tris(silylalkyl) complexes containing ?-SiH groups M{C(SiHMe{sub 2}){sub 3}}{sub 3} (Ln = Y, Lu, La) are synthesized from salt elimination of the corresponding lanthanide halide and 3 equiv. of KC(SiHMe{sub 2}){sub 3}. The related reactions with Sc yield bis(silylalkyl) ate-complexes containing either LiCl or KCl. The divalent calcium and ytterbium compounds M{C(SiHMe{sub 2}){sub 3}}{sub 2}L (M = Ca, Yb; L = THF{sub 2} or TMEDA) are prepared from MI{sub 2} and 2 equiv of KC(SiHMe{sub 2}){sub 3}. The compounds M{C(SiHMe{sub 2}){sub 3}}{sub 2}L (M = Ca, Yb; L = THF{sub 2} or TMEDA) and La{C(SiHMe{sub 2}){sub 3}}{sub 3} react with 1 equiv of B(C{sub 6}F{sub 5}){sub 3} to give 1,3- disilacyclobutane {Me2Si-C(SiHMe2)2}2 and MC(SiHMe2)3HB(C6F5)3L, and La{C(SiHMe{sub 2}){sub 3}}{sub 2}HB(C{sub 6}F{sub 5}){sub 3}, respectively. The corresponding reactions of Ln{C(SiHMe{sub 2}){sub 3}}{sub 3} (Ln = Y, Lu) give the ?-SiH abstraction product [{(Me{sub 2}HSi){sub 3}C}{sub 2}LnC(SiHMe{sub 2}){sub 2}SiMe{sub 2}][HB(C{sub 6}F{sub 5}){sub 3}] (Ln = Y, Lu), but the silene remains associated with the Y or Lu center. The abstraction reactions of M{C(SiHMe{sub 2}){sub 3}}{sub 2}L (M = Ca, Yb; L = THF{sub 2 }or TMEDA) and Ln{C(SiHMe{sub 2}){sub 3}}{sub 3} (Ln = Y, Lu, La) and 2 equiv of B(C{sub 6}F{sub 5}){sub 3} give the expected dicationic M{HB(C{sub 6}F{sub 5}){sub 3}}{sub 2}L (M = Ca, Yb; L = THF{sub 2} or TMEDA) and dicationic mono(silylalkyl) LnC(SiHMe{sub 2}){sub 3}{HB(C{sub 6}F{sub 5}){sub 3}}{sub 2} (Ln = Y, Lu, La), respectively. Salt metathesis reactions of Cp{sub 2}(NR{sub 2})ZrX (X = Cl, I, OTf; R = t-Bu, SiHMe{sub 2}) and lithium hydrosilazide ultimately afford hydride products Cp{sub 2}(NR{sub 2})ZrH that suggest unusual ?-hydrogen elimination processes. A likely intermediate in one of these reactions, Cp{sub 2}Zr[N(SiHMe{sub 2})t-Bu][N(SiHMe{sub 2}){sub 2}], is isolated under controlled synthetic conditions. Addition of alkali metal salts to this zirconium hydrosilazide compound produces the corresponding zirconium hydride. However as conditions are varied, a number of other pathways are also accessible, including C-H/Si-H dehydrocoupling, ?-abstraction of a CH, and ?-abstraction of a SiH. Our observations suggest that the conversion of (hydrosilazido)zirconocene to zirconium hydride does not follow the classical four-center ?- elimination mechanism. Elimination and abstraction reactions dominate the chemistry of ligands containing ?- hydrogen. In contrast, Cp{sub 2}Zr{N(SiHMe{sub 2}){sub 2}}H and Cp{sub 2}Zr{N(SiHMe{sub 2}){sub 2}}Me undergo selective ?-CH bond activation to yield the azasilazirconacycle Cp{sub 2Zr}{?{sup 2}-N(SiHMe{sub 2})SiHMeCH{sub 2}}, even though there are reactive ?-hydrogen available for abstraction. The ?-SiH groups in metallacycle provide access to new pathways for sixteen-electron zirconium alkyl compounds, in which Cp{sub 2}Zr{?{sup 2}-N(SiHMe{sub 2})SiHMeCH{sub 2}} undergoes a rare ?-bond metathesis reaction with ethylene. The resulting vinyl intermediate undergoes ?-hydrogen abstraction to reform ethylene and a silanimine zirconium species that reacts with ethylene to give a metallacyclopentane as the isolated product. The pendent ?-SiH in metallocycle also reacts with paraformaldehyde through an uncatalyzed hydrosilylation to form an exocyclic methoxysilyl moiety, while the zirconium-carbon bond in metallocycle is surprisingly inert toward formaldehyde. Still, the Zr-C moiety in metallocycle is available for chemistry, and it interacts with the carbon monoxide and strong electrophile B(C{sub 6}F{sub 5}){sub 3} to provide Cp{sub 2}Zr[?{sup 2}- OC(=CH{sub 2})SiMeHN(SiHMe

  4. PNNL Chemical Hydride Capabilities

    Broader source: Energy.gov [DOE]

    Presentation from the Hydrogen Storage Pre-Solicitation Meeting held June 19, 2003 in Washington, DC.

  5. Regeneration of aluminum hydride

    DOE Patents [OSTI]

    Graetz, Jason Allan; Reilly, James J; Wegrzyn, James E

    2012-09-18

    The present invention provides methods and materials for the formation of hydrogen storage alanes, AlH.sub.x, where x is greater than 0 and less than or equal to 6 at reduced H.sub.2 pressures and temperatures. The methods rely upon reduction of the change in free energy of the reaction between aluminum and molecular H.sub.2. The change in free energy is reduced by lowering the entropy change during the reaction by providing aluminum in a state of high entropy, and by increasing the magnitude of the change in enthalpy of the reaction or combinations thereof.

  6. Regeneration of aluminum hydride

    DOE Patents [OSTI]

    Graetz, Jason Allan (Mastic, NY); Reilly, James J. (Bellport, NY)

    2009-04-21

    The present invention provides methods and materials for the formation of hydrogen storage alanes, AlH.sub.x, where x is greater than 0 and less than or equal to 6 at reduced H.sub.2 pressures and temperatures. The methods rely upon reduction of the change in free energy of the reaction between aluminum and molecular H.sub.2. The change in free energy is reduced by lowering the entropy change during the reaction by providing aluminum in a state of high entropy, by increasing the magnitude of the change in enthalpy of the reaction or combinations thereof.

  7. Extraction process for removing metallic impurities from alkalide metals

    DOE Patents [OSTI]

    Royer, L.T.

    1987-03-20

    A development is described for removing metallic impurities from alkali metals by employing an extraction process wherein the metallic impurities are extracted from a molten alkali metal into molten lithium metal due to the immiscibility of the alkali metals in lithium and the miscibility of the metallic contaminants or impurities in the lithium. The purified alkali metal may be readily separated from the contaminant-containing lithium metal by simple decanting due to the differences in densities and melting temperatures of the alkali metals as compared to lithium.

  8. Treatability study Number PDC-1-O-T. Final report

    SciTech Connect (OSTI)

    1998-04-22

    Los Alamos National Laboratory provided treatability study samples from four waste streams, designated Stream {number_sign}1, Stream {number_sign}3, Stream {number_sign}6, and Stream {number_sign}7. Stream {number_sign}1 consisted of one 55-gallon drum of personal protective equipment (PPE), rags, and neutralizing agent (bicarbonate) generated during the cleanup of a sodium dichromate solution spill. Stream {number_sign}3 was one 55-gallon drum of paper, rags, lab utensils, tools, and tape from the decontamination of a glovebox. The sample of Stream {number_sign}6 was packaged in three 30-gallon drums and a 100 ft{sup 3} wooden box. It consisted of plastic sheeting, PPE, and paper generated from the cleanup of mock explosive (barium nitrate) from depleted uranium parts. Stream {number_sign}7 was scrap metal (copper, stainless and carbon steel joined with silver solder) from the disassembly of gas manifolds. The objective of the treatability study is to determine: (1) whether the Perma-Fix stabilization/solidification process can treat the waste sample to meet Land Disposal Restrictions and the Waste Acceptance Criteria for LANL Technical Area 54, Area G, and (2) optimum loading and resulting weight and volume of finished waste form. The stabilized waste was mixed into grout that had been poured into a lined drum. After each original container of waste was processed, the liner was closed and a new liner was placed in the same drum on top of the previous closed liner. This allowed an overall reduction in waste volume but kept waste segregated to minimize the amount of rework in case analytical results indicated any batch did not meet treatment standards. Samples of treated waste from each waste stream were analyzed by Perma-Fix Analytical Services to get a preliminary approximation of TCLP metals. Splits of these samples were sent to American Environmental Network`s mixed waste analytical lab in Cary, NC for confirmation analysis. Results were all below applicable limits.

  9. Environmental effects on noble-gas hydrides: HXeBr, HXeCCH, and HXeH in noble-gas and molecular matrices

    SciTech Connect (OSTI)

    Tsuge, Masashi E-mail: leonid.khriachtchev@helsinki.fi; Lignell, Antti; Rsnen, Markku; Khriachtchev, Leonid E-mail: leonid.khriachtchev@helsinki.fi

    2013-11-28

    Noble-gas hydrides HNgY (Ng is a noble-gas atom and Y is an electronegative group) are sensitive probes of local environment due to their relatively weak bonding and large dipole moments. We experimentally studied HXeBr in Ar, Kr, and N{sub 2} matrices, HXeCCH in Ne and N{sub 2} matrices, and HXeH in an N{sub 2} matrix. These are the first observations of noble-gas hydrides in an N{sub 2} matrix. An N{sub 2} matrix strongly increases the HXe stretching frequency of HXeBr and HXeCCH with respect to a Ne matrix, which is presumably due to a strong interaction between the HNgY dipole moment and quadrupole moments of the surrounding lattice N{sub 2} molecules. The spectral shift of HXeBr in an N{sub 2} matrix is similar to that in a CO{sub 2} matrix, which is a rather unexpected result because the quadrupole moment of CO{sub 2} is about three times as large as that of N{sub 2}. The HXe stretching frequencies of HXeBr and HXeCCH in noble-gas matrices show a trend of ?(Ne) < ?(Xe) < ?(Kr) < ?(Ar), which is a non-monotonous function of the dielectric constants of the noble-gas solids. The MP2(full) calculations of HXeBr and HXeCCH with the polarizable continuum model as well as the CCSD(T) calculations of the HXeBrNg and HXeCCHNg (Ng = Ne, Ar, Kr, and Xe) complexes cannot fully explain the experimental observations. It is concluded that more sophisticated computational models should be used to describe these experimental findings.

  10. Probing the surface structure of divalent transition metals using surface

    Office of Scientific and Technical Information (OSTI)

    specific solid-state NMR spectroscopy (Journal Article) | SciTech Connect Probing the surface structure of divalent transition metals using surface specific solid-state NMR spectroscopy Citation Details In-Document Search Title: Probing the surface structure of divalent transition metals using surface specific solid-state NMR spectroscopy Authors: Mason, H E ; Harley, S J ; Maxwell, R S ; Carroll, S A Publication Date: 2011-12-07 OSTI Identifier: 1107317 Report Number(s): LLNL-JRNL-520237

  11. Determining thermochemical properties of halogenated metals: On enabling

    Office of Scientific and Technical Information (OSTI)

    the rapid assessment of agent defeat formulations (Technical Report) | SciTech Connect Technical Report: Determining thermochemical properties of halogenated metals: On enabling the rapid assessment of agent defeat formulations Citation Details In-Document Search Title: Determining thermochemical properties of halogenated metals: On enabling the rapid assessment of agent defeat formulations Authors: M.Zaug, J ; Bastea, S Publication Date: 2014-06-25 OSTI Identifier: 1149562 Report Number(s):

  12. Temperature Dependence of Dynamic Deformation in FCC Metals, Aluminum and

    Office of Scientific and Technical Information (OSTI)

    Invar (Conference) | SciTech Connect Conference: Temperature Dependence of Dynamic Deformation in FCC Metals, Aluminum and Invar Citation Details In-Document Search Title: Temperature Dependence of Dynamic Deformation in FCC Metals, Aluminum and Invar Authors: Chen, L ; Swift, D C ; Austin, R A ; Florando, J N ; Hawreliak, J ; Lazicki, A ; Saculla, M D ; Eakins, D ; Bernier, J V ; Kumar, M Publication Date: 2015-09-23 OSTI Identifier: 1239232 Report Number(s): LLNL-PROC-679036 DOE Contract

  13. Metal atom oxidation laser

    DOE Patents [OSTI]

    Jensen, R.J.; Rice, W.W.; Beattie, W.H.

    1975-10-28

    A chemical laser which operates by formation of metal or carbon atoms and reaction of such atoms with a gaseous oxidizer in an optical resonant cavity is described. The lasing species are diatomic or polyatomic in nature and are readily produced by exchange or other abstraction reactions between the metal or carbon atoms and the oxidizer. The lasing molecules may be metal or carbon monohalides or monoxides. (auth)

  14. Metal atom oxidation laser

    DOE Patents [OSTI]

    Jensen, R.J.; Rice, W.W.; Beattie, W.H.

    1975-10-28

    A chemical laser which operates by formation of metal or carbon atoms and reaction of such atoms with a gaseous oxidizer in an optical resonant cavity is described. The lasing species are diatomic or polyatomic in nature and are readily produced by exchange or other abstraction reactions between the metal or carbon atoms and the oxidizer. The lasing molecules may be metal or carbon monohalides or monoxides.

  15. Metal atomization spray nozzle

    DOE Patents [OSTI]

    Huxford, Theodore J. (Harriman, TN)

    1993-01-01

    A spray nozzle for a magnetohydrodynamic atomization apparatus has a feed passage for molten metal and a pair of spray electrodes mounted in the feed passage. The electrodes, diverging surfaces which define a nozzle throat and diverge at an acute angle from the throat. Current passes through molten metal when fed through the throat which creates the Lorentz force necessary to provide atomization of the molten metal.

  16. Metal atomization spray nozzle

    DOE Patents [OSTI]

    Huxford, T.J.

    1993-11-16

    A spray nozzle for a magnetohydrodynamic atomization apparatus has a feed passage for molten metal and a pair of spray electrodes mounted in the feed passage. The electrodes, diverging surfaces which define a nozzle throat and diverge at an acute angle from the throat. Current passes through molten metal when fed through the throat which creates the Lorentz force necessary to provide atomization of the molten metal. 6 figures.

  17. Supported metal alloy catalysts

    DOE Patents [OSTI]

    Barrera, Joseph; Smith, David C.

    2000-01-01

    A process of preparing a Group IV, V, or VI metal carbonitride including reacting a Group IV, V, or VI metal amide complex with ammonia to obtain an intermediate product; and, heating the intermediate product to temperatures and for times sufficient to form a Group IV, V, or VI metal carbonitride is provided together with the product of the process and a process of reforming an n-alkane by use of the product.

  18. Probing metal solidification nondestructively

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    provide the insight needed to control the microstructure of metals and lead to advanced manufacturing processes to produce materials with desired properties. Los Alamos...

  19. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in both in technological and biological processes that are often governed by careful control over the physical and chemical properties of metal-oxygen bonds. For example,...

  20. Nitrided Metallic Bipolar Plates

    Broader source: Energy.gov [DOE]

    This presentation, which focuses on nitrided metallic bipolar plates, was given by M. P. Brady of ORNL at a February 2007 meeting on new fuel cell projects.

  1. Climate Zone Number 5 | Open Energy Information

    Open Energy Info (EERE)

    Climate Zone Number 5 Jump to: navigation, search A type of climate defined in the ASHRAE 169-2006 standard. Climate Zone Number 5 is defined as Cool- Humid(5A) with IP Units 5400...

  2. Silicon metal-semiconductor-metal photodetector

    DOE Patents [OSTI]

    Brueck, Steven R. J. (Albuquerque, NM); Myers, David R. (Albuquerque, NM); Sharma, Ashwani K. (Albuquerque, NM)

    1997-01-01

    Silicon MSM photodiodes sensitive to radiation in the visible to near infrared spectral range are produced by altering the absorption characteristics of crystalline Si by ion implantation. The implantation produces a defected region below the surface of the silicon with the highest concentration of defects at its base which acts to reduce the contribution of charge carriers formed below the defected layer. The charge carriers generated by the radiation in the upper regions of the defected layer are very quickly collected between biased Schottky barrier electrodes which form a metal-semiconductor-metal structure for the photodiode.

  3. Silicon metal-semiconductor-metal photodetector

    DOE Patents [OSTI]

    Brueck, Steven R. J. (Albuquerque, NM); Myers, David R. (Albuquerque, NM); Sharma, Ashwani K. (Albuquerque, NM)

    1995-01-01

    Silicon MSM photodiodes sensitive to radiation in the visible to near infrared spectral range are produced by altering the absorption characteristics of crystalline Si by ion implantation. The implantation produces a defected region below the surface of the silicon with the highest concentration of defects at its base which acts to reduce the contribution of charge carriers formed below the defected layer. The charge carriers generated by the radiation in the upper regions of the defected layer are very quickly collected between biased Schottky barrier electrodes which form a metal-semiconductor-metal structure for the photodiode.

  4. PRODUCTION OF PLUTONIUM METAL

    DOE Patents [OSTI]

    Lyon, W.L.; Moore, R.H.

    1961-01-17

    A process is given for producing plutonium metal by the reduction of plutonium chloride, dissolved in alkali metal chloride plus or minus aluminum chloride, with magnesium or a magnesium-aluminum alloy at between 700 and 800 deg C and separating the plutonium or plutonium-aluminum alloy formed from the salt.

  5. Production of magnesium metal

    DOE Patents [OSTI]

    Blencoe, James G. (Harriman, TN) [Harriman, TN; Anovitz, Lawrence M. (Knoxville, TN) [Knoxville, TN; Palmer, Donald A. (Oliver Springs, TN) [Oliver Springs, TN; Beard, James S. (Martinsville, VA) [Martinsville, VA

    2010-02-23

    A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention further relates to a process for production of magnesium metal or a magnesium compound where an external source of carbon dioxide is not used in any of the reactions of the process. The invention also relates to the magnesium metal produced by the processes described herein.

  6. Metallization of electronic insulators

    DOE Patents [OSTI]

    Gottesfeld, Shimshon (Los Alamos, NM); Uribe, Francisco A. (Los Alamos, NM)

    1994-01-01

    An electroplated element is formed to include an insulating substrate, a conducting polymer polymerized in situ on the substrate, and a metal layer deposited on the conducting polymer. In one application a circuit board is formed by polymerizing pyrrole on an epoxy-fiberglass substrate in a single step process and then electrodepositing a metal over the resulting polypyrrole polymer. No chemical deposition of the metal is required prior to electroplating and the resulting layer of substrate-polymer-metal has excellent adhesion characteristics. The metal deposition is surprisingly smooth and uniform over the relatively high resistance film of polypyrrole. A continuous manufacturing process is obtained by filtering the solution between successive substrates to remove polymer formed in the solution, by maintaining the solution oxidizing potential within selected limits, and by adding a strong oxidant, such as KMnO.sub.4 at periodic intervals to maintain a low sheet resistivity in the resulting conducting polymer film.

  7. Computational Design of Metal Ion Sequestering Agents

    SciTech Connect (OSTI)

    Hay, Benjamin P.; Rapko, Brian M.

    2005-06-15

    Organic ligands that exhibit a high degree of metal ion recognition are essential precursors for developing separation processes and sensors for metal ions. Since the beginning of the nuclear era, much research has focused on discovering ligands that target specific radionuclides. Members of the Group 1A and 2A cations (e.g., Cs, Sr, Ra) and the f-block metals (actinides and lanthanides) are of primary concern to DOE. Although there has been some success in identifying ligand architectures that exhibit a degree of metal ion recognition, the ability to control binding affinity and selectivity remains a significant challenge. The traditional approach for discovering such ligands has involved lengthy programs of organic synthesis and testing that, in the absence of reliable methods for screening compounds before synthesis, have resulted in much wasted research effort. This project seeks to enhance and strengthen the traditional approach through computer-aided design of new and improved host molecules. Accurate electronic structure calculations are coupled with experimental data to provide fundamental information about ligand structure and the nature of metal-donor group interactions (design criteria). This fundamental information then is used in a molecular mechanics model (MM) that helps us rapidly screen proposed ligand architectures and select the best members from a set of potential candidates. By using combinatorial methods, molecule building software has been developed that generates large numbers of candidate architectures for a given set of donor groups. The specific goals of this project are: further understand the structural and energetic aspects of individual donor group- metal ion interactions and incorporate this information within the MM framework further develop and evaluate approaches for correlating ligand structure with reactivity toward metal ions, in other words, screening capability use molecule structure building software to generate large numbers of candidate ligand architectures for given sets of donor groups screen candidates and identify ligand architectures that will exhibit enhanced metal ion recognition. These new capabilities are being applied to ligand systems identified under other DOEsponsored projects where studies have suggested that modifying existing architectures will lead to dramatic enhancements in metal ion binding affinity and selectivity. With this in mind, we are collaborating with Professors R. T. Paine (University of New Mexico), K. N. Raymond (University of California, Berkeley), and J. E. Hutchison (University of Oregon), and Dr. B. A. Moyer (Oak Ridge National Laboratory) to obtain experimental validation of the predicted new ligand structures. Successful completion of this study will yield molecular-level insight into the role that ligand architecture plays in controlling metal ion complexation and will provide a computational approach to ligand design.

  8. Method for adhesion of metal films to ceramics

    DOE Patents [OSTI]

    Lowndes, D.H.; Pedraza, A.J.; DeSilva, M.J.; Kumar, R.A.

    1997-12-30

    Methods for making strongly bonded metal-ceramic materials are disclosed. The methods include irradiating a portion of the surface of the ceramic material with a pulsed ultraviolet laser having an energy density sufficient to effect activation of the irradiated surface of the ceramic material so that adhesion of metals subsequently deposited onto the irradiated surface is substantially increased. Advantages of the invention include (i) the need for only a small number of laser pulses at relatively low focused energy density, (ii) a smoother substrate surface, (iii) activation of the laser-treated surface which provides a chemical bond between the surface and a metal deposited thereon, (iv) only low temperature annealing is required to produce the strong metal-ceramic bond; (v) the ability to obtain strong adhesion between ceramic materials and oxidation resistant metals; (vi) ability to store the laser treated ceramic materials for later deposition of metals thereon. 7 figs.

  9. Method for adhesion of metal films to ceramics

    DOE Patents [OSTI]

    Lowndes, Douglas H.; Pedraza, Anthony J.; DeSilva, Melvin J.; Kumar, Rajagopalan A.

    1997-01-01

    Methods for making strongly bonded metal-ceramic materials. The methods include irradiating a portion of the surface of the ceramic material with a pulsed ultraviolet laser having an energy density sufficient to effect activation of the irradiated surface of the ceramic material so that adhesion of metals subsequently deposited onto the irradiated surface is substantially increased. Advantages of the invention include (i) the need for only a small number of laser pulses at relatively low focused energy density, (ii) a smoother substrate surface, (iii) activation of the laser-treated surface which provides a chemical bond between the surface and a metal deposited thereon, (iv) only low temperature annealing is required to produce the strong metal-ceramic bond; (v) the ability to obtain strong adhesion between ceramic materials and oxidation resistant metals; (vi) ability to store the laser treated ceramic materials for later deposition of metals thereon.

  10. Synthesis of Metal-Metal Oxide Catalysts and Electrocatalysts...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Synthesis of Metal-Metal Oxide Catalysts and Electrocatalysts Brookhaven National Laboratory Contact BNL About This Technology Publications: PDF Document Publication...

  11. Control of Metal Nanocrystal Size Reveals Metal-Support Interface Role for Ceria Catalysts

    SciTech Connect (OSTI)

    Cargnello, M; Doan-Nguyen, VVT; Gordon, TR; Diaz, RE; Stach, EA; Gorte, RJ; Fornasiero, P; Murray, CB

    2013-08-15

    Interactions between ceria (CeO2) and supported metals greatly enhance rates for a number of important reactions. However, direct relationships between structure and function in these catalysts have been difficult to extract because the samples studied either were heterogeneous or were model systems dissimilar to working catalysts. We report rate measurements on samples in which the length of the ceria-metal interface was tailored by the use of monodisperse nickel, palladium, and platinum nanocrystals. We found that carbon monoxide oxidation in ceria-based catalysts is greatly enhanced at the ceria-metal interface sites for a range of group VIII metal catalysts, clarifying the pivotal role played by the support.

  12. Alabama Natural Gas Number of Gas and Gas Condensate Wells (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Alabama Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  13. Ohio Natural Gas Number of Gas and Gas Condensate Wells (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Ohio Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  14. Wyoming Natural Gas Number of Gas and Gas Condensate Wells (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Wyoming Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  15. Texas Natural Gas Number of Gas and Gas Condensate Wells (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Texas Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  16. Indiana Natural Gas Number of Gas and Gas Condensate Wells (Number...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas and Gas Condensate Wells (Number of Elements) Indiana Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  17. Alaska Natural Gas Number of Gas and Gas Condensate Wells (Number...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas and Gas Condensate Wells (Number of Elements) Alaska Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  18. Oregon Natural Gas Number of Gas and Gas Condensate Wells (Number...

    Gasoline and Diesel Fuel Update (EIA)

    Gas and Gas Condensate Wells (Number of Elements) Oregon Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  19. U.S. Natural Gas Number of Gas and Gas Condensate Wells (Number...

    Gasoline and Diesel Fuel Update (EIA)

    Gas and Gas Condensate Wells (Number of Elements) U.S. Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  20. Nevada Natural Gas Number of Gas and Gas Condensate Wells (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Nevada Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  1. Utah Natural Gas Number of Gas and Gas Condensate Wells (Number...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas and Gas Condensate Wells (Number of Elements) Utah Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  2. ARM - Measurement - Cloud particle number concentration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    number concentration ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Cloud particle number concentration The total number of cloud particles present in any given volume of air. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available

  3. Precious Metals | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Precious Metals General Information: The Materials Handling group provides Precious Metals receiving and documentation (PM's) for research programs funded by the Department of Energy (DOE). Precious metals are obtained from the DOE's Business Center for Precious Metals Sales and Recovery (BCPMSR). The return of scrap and excess precious metals to the BCPMSR is also provided by this group. Metals under this control are: GOLD - SILVER - PLATINUM - RHODIUM - PALLADIUM - IRIDIUM - OSMIUM - RUTHENIUM

  4. Metal nanodisks using bicellar templates

    DOE Patents [OSTI]

    Song, Yujiang; Shelnutt, John A

    2013-12-03

    Metallic nanodisks and a method of making them. The metallic nanodisks are wheel-shaped structures that that provide large surface areas for catalytic applications. The metallic nanodisks are grown within bicelles (disk-like micelles) that template the growth of the metal in the form of approximately circular dendritic sheets. The zero-valent metal forming the nanodisks is formed by reduction of a metal ion using a suitable electron donor species.

  5. Rapid Freeform Sheet Metal Forming

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Freeform Sheet Metal ADVANCED MANUFACTURING OFFICE Rapid Freeform Sheet Metal Forming Technology Development and System Verification of Innovative Forming Process for Rapid Prototyping. The automotive, aerospace, and appliance industries use sheet metal forming processes that deform an initially fat sheet of metal into a fnal three-dimensional shape. A traditional sheet metal stamping process utilizes a set of dies under mechanical force generated by a press to deform the metal sheet. The

  6. Metal Aminoboranes - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Materials Advanced Materials Find More Like This Return to Search Metal Aminoboranes Los Alamos National Laboratory Contact LANL About This Technology Technology Marketing Summary Metal aminoboranes of the formula M(NH.sub.2BH.sub.3).sub.n have been synthesized. Metal aminoboranes are hydrogen storage materials. Metal aminoboranes are also precursors for synthesizing other metal aminoboranes. Metal aminoboranes can be dehydrogenated to form hydrogen and a reaction product. The reaction

  7. Method for producing metallic microparticles

    DOE Patents [OSTI]

    Phillips, Jonathan; Perry, William L.; Kroenke, William J.

    2004-06-29

    Method for producing metallic particles. The method converts metallic nanoparticles into larger, spherical metallic particles. An aerosol of solid metallic nanoparticles and a non-oxidizing plasma having a portion sufficiently hot to melt the nanoparticles are generated. The aerosol is directed into the plasma where the metallic nanoparticles melt, collide, join, and spheroidize. The molten spherical metallic particles are directed away from the plasma and enter the afterglow where they cool and solidify.

  8. Method for producing metallic nanoparticles

    DOE Patents [OSTI]

    Phillips, Jonathan; Perry, William L.; Kroenke, William J.

    2004-02-10

    Method for producing metallic nanoparticles. The method includes generating an aerosol of solid metallic microparticles, generating non-oxidizing plasma with a plasma hot zone at a temperature sufficiently high to vaporize the microparticles into metal vapor, and directing the aerosol into the hot zone of the plasma. The microparticles vaporize in the hot zone to metal vapor. The metal vapor is directed away from the hot zone and to the plasma afterglow where it cools and condenses to form solid metallic nanoparticles.

  9. Calculating Atomic Number Densities for Uranium

    Energy Science and Technology Software Center (OSTI)

    1993-01-01

    Provides method to calculate atomic number densities of selected uranium compounds and hydrogenous moderators for use in nuclear criticality safety analyses at gaseous diffusion uranium enrichment facilities.

  10. OMB Control Number: 1910-5165

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    damages assessed under Contract Work Hours and Safety Standards Act: Page 1 OMB Control Number: 1910-5165 Expires: 04302015 SEMI-ANNUAL DAVIS-BACON ENFORCEMENT REPORT...

  11. Actinide metal processing

    DOE Patents [OSTI]

    Sauer, Nancy N. (Los Alamos, NM); Watkin, John G. (Los Alamos, NM)

    1992-01-01

    A process of converting an actinide metal such as thorium, uranium, or plnium to an actinide oxide material by admixing the actinide metal in an aqueous medium with a hypochlorite as an oxidizing agent for sufficient time to form the actinide oxide material and recovering the actinide oxide material is provided together with a low temperature process of preparing an actinide oxide nitrate such as uranyl nitrte. Additionally, a composition of matter comprising the reaction product of uranium metal and sodium hypochlorite is provided, the reaction product being an essentially insoluble uranium oxide material suitable for disposal or long term storage.

  12. EXELFS of Metallic Glasses

    SciTech Connect (OSTI)

    Ito, Y.; Alamgir, F.M.; Schwarz, R.B.; Jain, H.; Williams, D.B.

    1999-11-30

    The feasibility of using extended energy-loss fine structure (EXELFS) obtained from {approximately}1 nm regions of metallic glasses to study their short-range order has been examined. Ionization edges of the metallic glasses in the electron energy-loss spectrum (EELS) have been obtained from PdNiP bulk metallic glass and Ni{sub 2}P polycrystalline powder in a transmission electron microscope. The complexity of EXELFS analysis of L- and M-ionization edges of heavy elements (Z>22, i.e. Ni and Pd) is addressed by theoretical calculations using an ab initio computer code, and its results are compared with the experimental data.

  13. Liquid metal electric pump

    DOE Patents [OSTI]

    Abbin, Joseph P. (Albuquerque, NM); Andraka, Charles E. (Albuquerque, NM); Lukens, Laurance L. (Albuquerque, NM); Moreno, James B. (Albuquerque, NM)

    1992-01-01

    An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other.

  14. Liquid metal electric pump

    DOE Patents [OSTI]

    Abbin, J.P.; Andraka, C.E.; Lukens, L.L.; Moreno, J.B.

    1992-01-14

    An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other. 3 figs.

  15. Actinide metal processing

    DOE Patents [OSTI]

    Sauer, N.N.; Watkin, J.G.

    1992-03-24

    A process for converting an actinide metal such as thorium, uranium, or plutonium to an actinide oxide material by admixing the actinide metal in an aqueous medium with a hypochlorite as an oxidizing agent for sufficient time to form the actinide oxide material and recovering the actinide oxide material is described together with a low temperature process for preparing an actinide oxide nitrate such as uranyl nitrate. Additionally, a composition of matter comprising the reaction product of uranium metal and sodium hypochlorite is provided, the reaction product being an essentially insoluble uranium oxide material suitable for disposal or long term storage.

  16. Preparation of uniform nanoparticles of ultra-high purity metal oxides, mixed metal oxides, metals, and metal alloys

    DOE Patents [OSTI]

    Woodfield, Brian F.; Liu, Shengfeng; Boerio-Goates, Juliana; Liu, Qingyuan; Smith, Stacey Janel

    2012-07-03

    In preferred embodiments, metal nanoparticles, mixed-metal (alloy) nanoparticles, metal oxide nanoparticles and mixed-metal oxide nanoparticles are provided. According to embodiments, the nanoparticles may possess narrow size distributions and high purities. In certain preferred embodiments, methods of preparing metal nanoparticles, mixed-metal nanoparticles, metal oxide nanoparticles and mixed-metal nanoparticles are provided. These methods may provide tight control of particle size, size distribution, and oxidation state. Other preferred embodiments relate to a precursor material that may be used to form nanoparticles. In addition, products prepared from such nanoparticles are disclosed.

  17. Time dependent deformation of metals at room temperature. (Conference) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Time dependent deformation of metals at room temperature. Citation Details In-Document Search Title: Time dependent deformation of metals at room temperature. Abstract not provided. Authors: Deibler, Lisa Anne ; Boyce, Brad Lee ; Puskar, Joseph D. Publication Date: 2013-08-01 OSTI Identifier: 1107903 Report Number(s): SAND2013-7101C 470009 DOE Contract Number: AC04-94AL85000 Resource Type: Conference Resource Relation: Conference: JOWOG 28 Main Meeting held September 9-12,

  18. Low Mach Number Models in Computational Astrophysics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ann Almgren Low Mach Number Models in Computational Astrophysics February 4, 2014 Ann Almgren. Berkeley Lab Downloads Almgren-nug2014.pdf | Adobe Acrobat PDF file Low Mach Number Models in Computational Astrophysics - Ann Almgren, Berkeley Lab Last edited: 2016-02-01 08:06:52

  19. Production of magnesium metal

    DOE Patents [OSTI]

    Blencoe, James G. (Harriman, TN); Anovitz, Lawrence M. (Knoxville, TN); Palmer, Donald A. (Oliver Springs, TN); Beard, James S. (Martinsville, VA)

    2012-04-10

    A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention also relates to the magnesium metal produced by the processes described herein.

  20. METALS DESIGN HANDBOOK DISCLAIMER

    Office of Scientific and Technical Information (OSTI)

    Metals Design Handbook Dear Andy : Enclosed f o r your useinformation is DOE-HTGR-88106, ... * 0 I ELECTRiCAL CLASSIFICATION 7 SUE F 0 - INTI NA I NA I NA I APPROVAL PREPARED ...

  1. Oligocyclopentadienyl transition metal complexes

    SciTech Connect (OSTI)

    de Azevedo, Cristina G.; Vollhardt, K. Peter C.

    2002-01-18

    Synthesis, characterization, and reactivity studies of oligocyclopentadienyl transition metal complexes, namely those of fulvalene, tercyclopentadienyl, quatercyclopentadienyl, and pentacyclopentadienyl(cyclopentadienyl) are the subject of this account. Thermal-, photo-, and redox chemistries of homo- and heteropolynuclear complexes are described.

  2. Compendium of Experimental Cetane Number Data

    SciTech Connect (OSTI)

    Murphy, M. J.; Taylor, J. D.; McCormick, R. L.

    2004-09-01

    In this report, we present a compilation of reported cetane numbers for pure chemical compounds. The compiled database contains cetane values for 299 pure compounds, including 156 hydrocarbons and 143 oxygenates. Cetane number is a relative ranking of fuels based on the amount of time between fuel injection and ignition. The cetane number is typically measured either in a combustion bomb or in a single-cylinder research engine. This report includes cetane values from several different measurement techniques - each of which has associated uncertainties. Additionally, many of the reported values are determined by measuring blending cetane numbers, which introduces significant error. In many cases, the measurement technique is not reported nor is there any discussion about the purity of the compounds. Nonetheless, the data in this report represent the best pure compound cetane number values available from the literature as of August 2004.

  3. Hydrogen storage materials and method of making by dry homogenation

    DOE Patents [OSTI]

    Jensen, Craig M. (Kailua, HI); Zidan, Ragaiy A. (Honolulu, HI)

    2002-01-01

    Dry homogenized metal hydrides, in particular aluminum hydride compounds, as a material for reversible hydrogen storage is provided. The reversible hydrogen storage material comprises a dry homogenized material having transition metal catalytic sites on a metal aluminum hydride compound, or mixtures of metal aluminum hydride compounds. A method of making such reversible hydrogen storage materials by dry doping is also provided and comprises the steps of dry homogenizing metal hydrides by mechanical mixing, such as be crushing or ball milling a powder, of a metal aluminum hydride with a transition metal catalyst. In another aspect of the invention, a method of powering a vehicle apparatus with the reversible hydrogen storage material is provided.

  4. Molten metal reactors

    DOE Patents [OSTI]

    Bingham, Dennis N; Klingler, Kerry M; Turner, Terry D; Wilding, Bruce M

    2013-11-05

    A molten metal reactor for converting a carbon material and steam into a gas comprising hydrogen, carbon monoxide, and carbon dioxide is disclosed. The reactor includes an interior crucible having a portion contained within an exterior crucible. The interior crucible includes an inlet and an outlet; the outlet leads to the exterior crucible and may comprise a diffuser. The exterior crucible may contain a molten alkaline metal compound. Contained between the exterior crucible and the interior crucible is at least one baffle.

  5. Lithium metal reduction of plutonium oxide to produce plutonium metal

    DOE Patents [OSTI]

    Coops, Melvin S. (Livermore, CA)

    1992-01-01

    A method is described for the chemical reduction of plutonium oxides to plutonium metal by the use of pure lithium metal. Lithium metal is used to reduce plutonium oxide to alpha plutonium metal (alpha-Pu). The lithium oxide by-product is reclaimed by sublimation and converted to the chloride salt, and after electrolysis, is removed as lithium metal. Zinc may be used as a solvent metal to improve thermodynamics of the reduction reaction at lower temperatures. Lithium metal reduction enables plutonium oxide reduction without the production of huge quantities of CaO--CaCl.sub.2 residues normally produced in conventional direct oxide reduction processes.

  6. Helium nano-bubble evolution in aging metal tritides.

    SciTech Connect (OSTI)

    Cowgill, Donald F.

    2004-05-01

    A continuum-scale, evolutionary model of helium (He) nano-bubble nucleation, growth and He release for aging bulk metal tritides is presented which accounts for major features of the experimental database. Bubble nucleation, modeled as self-trapping of interstitially diffusing He atoms, is found to occur during the first few days following tritium introduction into the metal and is sensitive to the He diffusivity and pairing energy. An effective helium diffusivity of 0.3 x 10{sup -16} cm{sup 2}/s at 300 K is required to generate the average bubble density of 5x 1017 bubbles/cm3 observed by transmission electron microscopy (TEM). Early bubble growth by dislocation loop punching with a l/radius bubble pressure dependence produces good agreement with He atomic volumes and bubble pressures determined from swelling data, nuclear magnetic resonance (NMR) measurements, and hydride pressure-composition-temperature (PCT) shifts. The model predicts that later in life neighboring bubble interactions may first lower the loop punching pressure through cooperative stress effects, then raise the pressure by partial blocking of loops. It also accounts for the shape of the bubble spacing distribution obtained from NMR data. This distribution is found to remain fixed with age, justifying the separation of nucleation and growth phases, providing a sensitive test of the growth formulation, and indicating that further significant bubble nucleation does not occur throughout life. Helium generated within the escape depth of surfaces and surface-connected porosity produces the low-level early helium release. Accelerated or rapid release is modeled as inter-bubble fracture using an average ligament stress criterion. Good agreement is found between the predicted onset of fracture and the observed He-metal ratio (HeM) for rapid He release from bulk palladium tritide. An examination of how inter-bubble fracture varies over the bubble spacing distribution shows that the critical Hem will be lower for thin films or small particle material. It is concluded that control of He retention can be accomplished through control of bubble nucleation.

  7. Cooling system for continuous metal casting machines

    DOE Patents [OSTI]

    Draper, R.; Sumpman, W.C.; Baker, R.J.; Williams, R.S.

    1988-06-07

    A continuous metal caster cooling system is provided in which water is supplied in jets from a large number of small nozzles against the inner surface of rim at a temperature and with sufficient pressure that the velocity of the jets is sufficiently high that the mode of heat transfer is substantially by forced convection, the liquid being returned from the cooling chambers through return pipes distributed interstitially among the nozzles. 9 figs.

  8. Cooling system for continuous metal casting machines

    DOE Patents [OSTI]

    Draper, Robert (Churchill Boro, PA); Sumpman, Wayne C. (North Huntingdon, PA); Baker, Robert J. (Wilkins Township, Allegheny County, PA); Williams, Robert S. (Plum Borough, PA)

    1988-01-01

    A continuous metal caster cooling system is provided in which water is supplied in jets from a large number of small nozzles 19 against the inner surface of rim 13 at a temperature and with sufficient pressure that the velocity of the jets is sufficiently high that the mode of heat transfer is substantially by forced convection, the liquid being returned from the cooling chambers 30 through return pipes 25 distributed interstitially among the nozzles.

  9. Electrochemical nitridation of metal surfaces

    DOE Patents [OSTI]

    Wang, Heli; Turner, John A.

    2015-06-30

    Electrochemical nitridation of metals and the produced metals are disclosed. An exemplary method of electrochemical nitridation of metals comprises providing an electrochemical solution at low temperature. The method also comprises providing a three-electrode potentiostat system. The method also comprises stabilizing the three-electrode potentiostat system at open circuit potential. The method also comprises applying a cathodic potential to a metal.

  10. Thermally tolerant multilayer metal membrane

    DOE Patents [OSTI]

    Dye, Robert C. (Los Alamos, NM); Snow, Ronny C. (Los Alamos, NM)

    2001-01-01

    A composite metal membrane including a first metal layer of a Group IVB or Group VB metal sandwiched between two layers of a Group VIIIB metal selected from the group consisting of palladium, platinum, nickel, rhodium, iridium, cobalt, and alloys thereof, and a non-continuous layer of a metal chalcogenide upon one layer of the Group VIIIB metal is disclosed together with a process for the recovery of hydrogen from a gaseous mixture using such a composite membrane and a process for forming such a composite metal membrane.

  11. Particle Number & Particulate Mass Emissions Measurements on...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    on a 'Euro VI' Heavy-duty Engine using the PMP Methodologies Particle Number & Particulate Mass Emissions Measurements on a 'Euro VI' Heavy-duty Engine using the PMP ...

  12. Identification of Export Control Classification Number - ITER

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Identification of Export Control Classification Number - ITER (April 2012) As the "Shipper of Record" please provide the appropriate Export Control Classification Number (ECCN) for the products (equipment, components and/or materials) and if applicable the nonproprietary associated installation/maintenance documentation that will be shipped from the United States to the ITER International Organization in Cadarache, France or to ITER Members worldwide on behalf of the Company. In rare

  13. Stockpile Stewardship Quarterly Volume 1, Number 4

    National Nuclear Security Administration (NNSA)

    1, Number 4 * February 2012 Message from the Assistant Deputy Administrator for Stockpile Stewardship, Chris Deeney Defense Programs Stockpile Stewardship in Action Volume 1, Number 4 Inside this Issue 2 Applying Advanced Simulation Models to Neutron Tube Ion Extraction 3 Advanced Optical Cavities for Subcritical and Hydrodynamic Experiments 5 Progress Toward Ignition on the National Ignition Facility 7 Commissioning URSA Minor: The First LTD-Based Accelerator for Radiography 8 Publication

  14. Peroxotitanates for Biodelivery of Metals

    SciTech Connect (OSTI)

    Hobbs, David; Elvington, M.

    2009-02-11

    Metal-based drugs are largely undeveloped in pharmacology. One limiting factor is the systemic toxicity of metal-based compounds. A solid-phase, sequestratable delivery agent for local delivery of metals could reduce systemic toxicity, facilitating new drug development in this nascent area. Amorphous peroxotitanates (APT) are ion exchange materials with high affinity for several heavy metal ions, and have been proposed to deliver or sequester metal ions in biological contexts. In the current study, we tested a hypothesis that APT are able to deliver metals or metal compounds to cells. We exposed fibroblasts (L929) or monocytes (THP1) to metal-APT materials for 72 h in vitro, then measured cellular mitochondrial activity (SDH-MTT method) to assess the biological impact of the metal-APT materials vs. metals or APT alone. APT alone did not significantly affect cellular mitochondrial activity, but all metal-APT materials suppressed the mitochondrial activity of fibroblasts (by 30-65% of controls). The concentration of metal-APT materials required to suppress cellular mitochondrial activity was below that required for metals alone, suggesting that simple extracellular release of the metals from the metal-APT materials was not the primary mechanism of mitochondrial suppression. In contrast to fibroblasts, no metal-APT material had a measurable effect on THP1 monocyte mitochondrial activity, despite potent suppression by metals alone. This latter result suggested that 'biodelivery' by metal-APT materials may be cell type-specific. Therefore, it appears that APT are plausible solid phase delivery agents of metals or metal compounds to some types of cells for potential therapeutic effect.

  15. Method for forming metal contacts

    DOE Patents [OSTI]

    Reddington, Erik; Sutter, Thomas C; Bu, Lujia; Cannon, Alexandra; Habas, Susan E; Curtis, Calvin J; Miedaner, Alexander; Ginley, David S; Van Hest, Marinus Franciscus Antonius Maria

    2013-09-17

    Methods of forming metal contacts with metal inks in the manufacture of photovoltaic devices are disclosed. The metal inks are selectively deposited on semiconductor coatings by inkjet and aerosol apparatus. The composite is heated to selective temperatures where the metal inks burn through the coating to form an electrical contact with the semiconductor. Metal layers are then deposited on the electrical contacts by light induced or light assisted plating.

  16. Liquid metal thermal electric converter

    DOE Patents [OSTI]

    Abbin, Joseph P. (Albuquerque, NM); Andraka, Charles E. (Albuquerque, NM); Lukens, Laurance L. (Albuquerque, NM); Moreno, James B. (Albuquerque, NM)

    1989-01-01

    A liquid metal thermal electric converter which converts heat energy to electrical energy. The design of the liquid metal thermal electric converter incorporates a unique configuration which directs the metal fluid pressure to the outside of the tube which results in the structural loads in the tube to be compressive. A liquid metal thermal electric converter refluxing boiler with series connection of tubes and a multiple cell liquid metal thermal electric converter are also provided.

  17. Alkali metal ionization detector

    DOE Patents [OSTI]

    Bauerle, James E. (Plum Borough, PA); Reed, William H. (Monroeville, PA); Berkey, Edgar (Murrysville, PA)

    1978-01-01

    Variations in the conventional filament and collector electrodes of an alkali metal ionization detector, including the substitution of helical electrode configurations for either the conventional wire filament or flat plate collector; or, the substitution of a plurality of discrete filament electrodes providing an in situ capability for transferring from an operationally defective filament electrode to a previously unused filament electrode without removing the alkali metal ionization detector from the monitored environment. In particular, the helical collector arrangement which is coaxially disposed about the filament electrode, i.e. the thermal ionizer, provides an improved collection of positive ions developed by the filament electrode. The helical filament design, on the other hand, provides the advantage of an increased surface area for ionization of alkali metal-bearing species in a monitored gas environment as well as providing a relatively strong electric field for collecting the ions at the collector electrode about which the helical filament electrode is coaxially positioned. Alternatively, both the filament and collector electrodes can be helical. Furthermore, the operation of the conventional alkali metal ionization detector as a leak detector can be simplified as to cost and complexity, by operating the detector at a reduced collector potential while maintaining the sensitivity of the alkali metal ionization detector adequate for the relatively low concentration of alkali vapor and aerosol typically encountered in leak detection applications.

  18. The Evaluation of Lithium Hydride for Use in a Space Nuclear Reactor Shield, Including a Historical Perspective

    SciTech Connect (OSTI)

    D. Poeth

    2005-12-09

    LiH was one of the five primary shield materials the NRPCT intended to develop (along with beryllium, boron carbide, tungsten, and water) for potential Prometheus application. It was also anticipated that {sup 10}B metal would be investigated for feasibility at a low level of effort. LiH historically has been selected as a low mass, neutron absorption material for space shields (Systems for Nuclear Auxiliary Power (SNAP), Topaz, SP-100). Initial NRPCT investigations did not produce convincing evidence that LiH was desirable or feasible for a Prometheus mission due to material property issues (primarily swelling and hydrogen cover gas containment), and related thermal design complexity. Furthermore, if mass limits allowed, an option to avoid use of LiH was being contemplated to lower development costs and associated risks. However, LiH remains theoretically the most efficient neutron shield material per unit mass, and, with sufficient testing and development, could be an optimal material choice for future flights.

  19. Nonlocal effective medium analysis in symmetric metal-dielectric multilayer

    Office of Scientific and Technical Information (OSTI)

    metamaterials (Journal Article) | SciTech Connect Nonlocal effective medium analysis in symmetric metal-dielectric multilayer metamaterials Citation Details In-Document Search This content will become publicly available on May 26, 2016 Title: Nonlocal effective medium analysis in symmetric metal-dielectric multilayer metamaterials Authors: Sun, Lei ; Li, Zhigang ; Luk, Ting S. ; Yang, Xiaodong ; Gao, Jie Publication Date: 2015-05-27 OSTI Identifier: 1183224 Grant/Contract Number:

  20. Ubiquity of linear resistivity at intermediate temperature in bad metals

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | DOE PAGES Ubiquity of linear resistivity at intermediate temperature in bad metals Title: Ubiquity of linear resistivity at intermediate temperature in bad metals Authors: Boyd, G. R. ; Zlatić, V. ; Freericks, J. K. Publication Date: 2015-02-20 OSTI Identifier: 1181226 Grant/Contract Number: SC0007091; FG02-08ER46542 Type: Publisher's Accepted Manuscript Journal Name: Physical Review B Additional Journal Information: Journal Volume: 91; Journal Issue: 7; Journal ID: ISSN

  1. Multi-resolution modeling of the dynamic loading of metal matrix

    Office of Scientific and Technical Information (OSTI)

    composites. (Conference) | SciTech Connect Multi-resolution modeling of the dynamic loading of metal matrix composites. Citation Details In-Document Search Title: Multi-resolution modeling of the dynamic loading of metal matrix composites. Abstract not provided. Authors: Dingreville, Remi Philippe Michel ; Voth, Thomas Eugene ; Robbins, Joshua Publication Date: 2013-10-01 OSTI Identifier: 1115648 Report Number(s): SAND2013-9199C 479945 DOE Contract Number: AC04-94AL85000 Resource Type:

  2. Atomic-Layer Deposition on Noble Metal Powders. (Conference) | SciTech

    Office of Scientific and Technical Information (OSTI)

    Connect Atomic-Layer Deposition on Noble Metal Powders. Citation Details In-Document Search Title: Atomic-Layer Deposition on Noble Metal Powders. Abstract not provided. Authors: Robinson, David ; Cappillino, Patrick. ; Salloum, Maher N. ; Sugar, Joshua Daniel ; El Gabaly Marquez, Farid ; Sheridan, Leah B. ; Jagannathan, Kaushik ; Benson, David M. ; Stickney, John L. Publication Date: 2014-10-01 OSTI Identifier: 1241747 Report Number(s): SAND2014-18364PE 537921 DOE Contract Number:

  3. Spillover-Assisted Hydrogen Evolution at Si-based Metal-Oxide-Semiconductor

    Office of Scientific and Technical Information (OSTI)

    Photoelectrodes. (Journal Article) | SciTech Connect Spillover-Assisted Hydrogen Evolution at Si-based Metal-Oxide-Semiconductor Photoelectrodes. Citation Details In-Document Search Title: Spillover-Assisted Hydrogen Evolution at Si-based Metal-Oxide-Semiconductor Photoelectrodes. Authors: Talin, Albert Alec ; Esposito, Daniel V. ; Levin, Igor ; Moffat, Thomas P. Publication Date: 2012-12-01 OSTI Identifier: 1063415 Report Number(s): SAND2012-10868J DOE Contract Number: AC04-94AL85000

  4. Method for locating metallic nitride inclusions in metallic alloy ingots

    DOE Patents [OSTI]

    White, Jack C. (Albany, OR); Traut, Davis E. (Corvallis, OR); Oden, Laurance L. (Albany, OR); Schmitt, Roman A. (Corvallis, OR)

    1992-01-01

    A method of determining the location and history of metallic nitride and/or oxynitride inclusions in metallic melts. The method includes the steps of labeling metallic nitride and/or oxynitride inclusions by making a coreduced metallic-hafnium sponge from a mixture of hafnium chloride and the chloride of a metal, reducing the mixed chlorides with magnesium, nitriding the hafnium-labeled metallic-hafnium sponge, and seeding the sponge to be melted with hafnium-labeled nitride inclusions. The ingots are neutron activated and the hafnium is located by radiometric means. Hafnium possesses exactly the proper metallurgical and radiochemical properties for this use.

  5. High-Temperature Zirconia Oxygen Sensor with Sealed Metal/Metal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference ...

  6. Hard metal composition

    DOE Patents [OSTI]

    Sheinberg, H.

    1983-07-26

    A composition of matter having a Rockwell A hardness of at least 85 is formed from a precursor mixture comprising between 3 and 10 wt % boron carbide and the remainder a metal mixture comprising from 70 to 90% tungsten or molybdenum, with the remainder of the metal mixture comprising nickel and iron or a mixture thereof. The composition has a relatively low density of between 7 and 14 g/cc. The precursor is preferably hot pressed to yield a composition having greater than 100% of theoretical density.

  7. Metallic carbon materials

    DOE Patents [OSTI]

    Cohen, Marvin Lou (Berkeley, CA); Crespi, Vincent Henry (Darien, IL); Louie, Steven Gwon Sheng (Berkeley, CA); Zettl, Alexander Karlwalter (Kensington, CA)

    1999-01-01

    Novel metallic forms of planar carbon are described, as well as methods of designing and making them. Nonhexagonal arrangements of carbon are introduced into a graphite carbon network essentially without destroying the planar structure. Specifically a form of carbon comprising primarily pentagons and heptagons, and having a large density of states at the Fermi level is described. Other arrangements of pentagons and heptagons that include some hexagons, and structures incorporating squares and octagons are additionally disclosed. Reducing the bond angle symmetry associated with a hexagonal arrangement of carbons increases the likelihood that the carbon material will have a metallic electron structure.

  8. Metal alloy identifier

    DOE Patents [OSTI]

    Riley, William D. (Avondale, MD); Brown, Jr., Robert D. (Avondale, MD)

    1987-01-01

    To identify the composition of a metal alloy, sparks generated from the alloy are optically observed and spectrographically analyzed. The spectrographic data, in the form of a full-spectrum plot of intensity versus wavelength, provide the "signature" of the metal alloy. This signature can be compared with similar plots for alloys of known composition to establish the unknown composition by a positive match with a known alloy. An alternative method is to form intensity ratios for pairs of predetermined wavelengths within the observed spectrum and to then compare the values of such ratios with similar values for known alloy compositions, thereby to positively identify the unknown alloy composition.

  9. Hard metal composition

    DOE Patents [OSTI]

    Sheinberg, Haskell (Los Alamos, NM)

    1986-01-01

    A composition of matter having a Rockwell A hardness of at least 85 is formed from a precursor mixture comprising between 3 and 10 weight percent boron carbide and the remainder a metal mixture comprising from 70 to 90 percent tungsten or molybdenum, with the remainder of the metal mixture comprising nickel and iron or a mixture thereof. The composition has a relatively low density of between 7 to 14 g/cc. The precursor is preferably hot pressed to yield a composition having greater than 100% of theoretical density.

  10. Probing lepton number violation on three frontiers

    SciTech Connect (OSTI)

    Deppisch, Frank F. [Department of Physics and Astronomy, University College London (United Kingdom)

    2013-12-30

    Neutrinoless double beta decay constitutes the main probe for lepton number violation at low energies, motivated by the expected Majorana nature of the light but massive neutrinos. On the other hand, the theoretical interpretation of the (non-)observation of this process is not straightforward as the Majorana neutrinos can destructively interfere in their contribution and many other New Physics mechanisms can additionally mediate the process. We here highlight the potential of combining neutrinoless double beta decay with searches for Tritium decay, cosmological observations and LHC physics to improve the quantitative insight into the neutrino properties and to unravel potential sources of lepton number violation.

  11. Battling bird flu by the numbers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Battling bird flu by the numbers Battling bird flu by the numbers Lab theorists have developed a mathematical tool that could help health experts and crisis managers determine in real time whether an emerging infectious disease such as avian influenza H5N1 is poised to spread globally. May 27, 2008 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience,

  12. WIPP Documents - All documents by number

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Note: Documents that do not have document numbers are not included in this listing. Large file size alert This symbol means the document may be a large file size. All documents by number Common document prefixes DOE/CAO DOE/TRU DOE/CBFO DOE/WIPP DOE/EA NM DOE/EIS Other DOE/CAO Back to top DOE/CAO 95-1095, Oct. 1995 Remote Handled Transuranic Waste Study This study was conducted to satisfy the requirements defined by the WIPP Land Withdrawal Act and considered by DOE to be a prudent exercise in

  13. Wick for metal vapor laser

    DOE Patents [OSTI]

    Duncan, David B. (Livermore, CA)

    1992-01-01

    An improved wick for a metal vapor laser is made of a refractory metal cylinder, preferably molybdenum or tungsten for a copper laser, which provides the wicking surface. Alternately, the inside surface of the ceramic laser tube can be metalized to form the wicking surface. Capillary action is enhanced by using wire screen, porous foam metal, or grooved surfaces. Graphite or carbon, in the form of chunks, strips, fibers or particles, is placed on the inside surface of the wick to reduce water, reduce metal oxides and form metal carbides.

  14. Ductile transplutonium metal alloys

    DOE Patents [OSTI]

    Conner, W.V.

    1981-10-09

    Alloys of Ce with transplutonium metals such as Am, Cm, Bk and Cf have properties making them highly suitable as souces of the transplutonium element, e.g., for use in radiation detector technology or as radiation sources. The alloys are ductile, homogeneous, easy to prepare and have a fairly high density.

  15. Metal working lubricant compositions

    SciTech Connect (OSTI)

    Andress, H.J.; Davis, R.H.; Schick, J.W.

    1981-08-11

    A lubricant concentrate for use in metal processing comprises a sulfur compound such as a sulfurized olefin or sulfurized mineral oil and an ester prepared from a fatty acid having 12 to 40 carbon atoms or the dimer thereof or a polyalkenylsuccinic acid or anhydride and a hydroxyl-containing amine.

  16. Metal halogen electrochemical cell

    DOE Patents [OSTI]

    Bellows, Richard J. (Hampton, NJ); Kantner, Edward (E. Brunswick, NJ)

    1988-08-23

    It has now been discovered that reduction in the coulombic efficiency of metal halogen cells can be minimized if the microporous separator employed in such cells is selected from one which is preferably wet by the aqueous electrolyte and is not wet substantially by the cathodic halogen.

  17. Serpentine metal gasket

    DOE Patents [OSTI]

    Rothgeb, Timothy Moore; Reece, Charles Edwin

    2009-06-02

    A metallic seal or gasket for use in the joining of cryogenic fluid conduits, the seal or gasket having a generally planar and serpentine periphery defining a central aperture. According to a preferred embodiment, the periphery has at least two opposing elongated serpentine sides and two opposing arcuate ends joining the opposing elongated serpentine sides and is of a hexagonal cross-section.

  18. The 17 GHz active region number

    SciTech Connect (OSTI)

    Selhorst, C. L.; Pacini, A. A.; Costa, J. E. R.; Gimnez de Castro, C. G.; Valio, A.; Shibasaki, K.

    2014-08-01

    We report the statistics of the number of active regions (NAR) observed at 17 GHz with the Nobeyama Radioheliograph between 1992, near the maximum of cycle 22, and 2013, which also includes the maximum of cycle 24, and we compare with other activity indexes. We find that NAR minima are shorter than those of the sunspot number (SSN) and radio flux at 10.7 cm (F10.7). This shorter NAR minima could reflect the presence of active regions generated by faint magnetic fields or spotless regions, which were a considerable fraction of the counted active regions. The ratio between the solar radio indexes F10.7/NAR shows a similar reduction during the two minima analyzed, which contrasts with the increase of the ratio of both radio indexes in relation to the SSN during the minimum of cycle 23-24. These results indicate that the radio indexes are more sensitive to weaker magnetic fields than those necessary to form sunspots, of the order of 1500 G. The analysis of the monthly averages of the active region brightness temperatures shows that its long-term variation mimics the solar cycle; however, due to the gyro-resonance emission, a great number of intense spikes are observed in the maximum temperature study. The decrease in the number of these spikes is also evident during the current cycle 24, a consequence of the sunspot magnetic field weakening in the last few years.

  19. Pennsylvania Number of Natural Gas Consumers

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    1998-2014 Average Consumption per Consumer (Thousand Cubic Ft.) 618 606 604 540 627 666 1967-2014 Industrial Number of Consumers 4,745 4,624 5,007 5,066 5,024 5,084 1987-2014...

  20. The New Element Curium (Atomic Number 96)

    DOE R&D Accomplishments [OSTI]

    Seaborg, G. T.; James, R. A.; Ghiorso, A.

    1948-00-00

    Two isotopes of the element with atomic number 96 have been produced by the helium-ion bombardment of plutonium. The name curium, symbol Cm, is proposed for element 96. The chemical experiments indicate that the most stable oxidation state of curium is the III state.