National Library of Energy BETA

Sample records for metal halide replacing

  1. Electrolytic systems and methods for making metal halides and refining metals

    DOE Patents [OSTI]

    Holland, Justin M.; Cecala, David M.

    2015-05-26

    Disclosed are electrochemical cells and methods for producing a halide of a non-alkali metal and for electrorefining the halide. The systems typically involve an electrochemical cell having a cathode structure configured for dissolving a hydrogen halide that forms the halide into a molten salt of the halogen and an alkali metal. Typically a direct current voltage is applied across the cathode and an anode that is fabricated with the non-alkali metal such that the halide of the non-alkali metal is formed adjacent the anode. Electrorefining cells and methods involve applying a direct current voltage across the anode where the halide of the non-alkali metal is formed and the cathode where the non-alkali metal is electro-deposited. In a representative embodiment the halogen is chlorine, the alkali metal is lithium and the non-alkali metal is uranium.

  2. Metal Halide Surface Treatment of Quantum Dots - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Materials Advanced Materials Find More Like This Return to Search Metal Halide Surface Treatment of Quantum Dots National Renewable Energy Laboratory Contact NREL About This Technology Technology Marketing Summary Quantum dot (QD) solids are a solution-processed, composite thin film semiconductor system that is being developed for optoelectronics (display technology, solid state lighting, next generation photovoltaics, photodetector application, etc.). For photovoltaics, in addition to

  3. Thermal battery. [solid metal halide electrolytes with enhanced electrical conductance after a phase transition

    DOE Patents [OSTI]

    Carlsten, R.W.; Nissen, D.A.

    1973-03-06

    The patent describes an improved thermal battery whose novel design eliminates various disadvantages of previous such devices. Its major features include a halide cathode, a solid metal halide electrolyte which has a substantially greater electrical conductance after a phase transition at some temperature, and a means for heating its electrochemical cells to activation temperature.

  4. Metal-halide perovskites for photovoltaic and light-emitting devices* |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MIT-Harvard Center for Excitonics Metal-halide perovskites for photovoltaic and light-emitting devices* September 15, 2015 at 4:30 pm/36-428 Sam Stranks Massachusetts Institute of Technology stranks.02 Metal halide perovskites are exotic hybrid crystalline materials developed out of curiosity. Unexpectedly, solar cells incorporating these perovskites are rapidly emerging as serious contenders to rival the leading photovoltaic technologies. Power conversion efficiencies have jumped from 3% to

  5. New Energy Efficiency Standards for Metal Halide Lamp Fixtures to Save on

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Bills and Reduce Carbon Pollution | Department of Energy Metal Halide Lamp Fixtures to Save on Energy Bills and Reduce Carbon Pollution New Energy Efficiency Standards for Metal Halide Lamp Fixtures to Save on Energy Bills and Reduce Carbon Pollution January 30, 2014 - 9:30am Addthis News Media Contact (202) 586-4940 WASHINGTON - As part of the Energy Department's efforts to develop efficiency standards that cut carbon pollution and save money by saving energy, U.S. Energy Secretary

  6. Method for hydrocracking a heavy polynuclear hydrocarbonaceous feedstock in the presence of a molten metal halide catalyst

    DOE Patents [OSTI]

    Gorin, Everett (San Rafael, CA)

    1981-01-01

    A method for hydrocracking a heavy polynuclear hydrocarbonaceous feedstock to produce lighter hydrocarbon fuels by contacting the feedstock with hydrogen in the presence of a molten metal halide catalyst, the method comprising: mixing the feedstock with a heavy naphtha fraction which has an initial boiling point from about 100.degree. to about 160.degree. C. with a boiling point difference between the initial boiling point and the final boiling point of no more than about 50.degree. C. to produce a mixture; thereafter contacting the mixture with partially spent molten metal halide and hydrogen under temperature and pressure conditions so that the temperature is near the critical temperature of the heavy naphtha fraction; separating at least a portion of the heavy naphtha fraction and lighter hydrocarbon fuels from the partially spent molten metal halide, unreacted feedstock and reaction products; thereafter contacting the partially spent molten metal halide, unreacted feedstock and reaction products with hydrogen and fresh molten metal halide in a hydrocracking zone to produce additional lighter hydrocarbon fuels and separating at least a major portion of the lighter hydrocarbon fuels from the spent molten metal halide.

  7. Metal halide solid-state surface treatment for nanocrystal materials

    DOE Patents [OSTI]

    Luther, Joseph M.; Crisp, Ryan; Beard, Matthew C.

    2016-04-26

    Methods of treating nanocrystal and/or quantum dot devices are described. The methods include contacting the nanocrystals and/or quantum dots with a solution including metal ions and halogen ions, such that the solution displaces native ligands present on the surface of the nanocrystals and/or quantum dots via ligand exchange.

  8. Evaluation of Metal Halide, Plasma, and LED Lighting Technologies for a Hydrogen Fuel Cell Mobile Light (H 2 LT)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Miller, L. B.; Donohoe, S. P.; Jones, M. H.; White, W. A.; Klebanoff, L. E.; Velinsky, S. A.

    2015-04-22

    This article reports on the testing and comparison of a prototype hydrogen fuel cell light tower (H2LT) and a conventional diesel-powered metal halide light trailer for use in road maintenance and construction activities. The prototype was originally outfitted with plasma lights and then with light-emitting diode (LED) luminaires. Light output and distribution, lighting energy efficiency (i.e., efficacy), power source thermal efficiency, and fuel costs are compared. The metal halide luminaires have 2.2 and 3.1 times more light output than the plasma and LED luminaires, respectively, but they require more power/lumen to provide that output. The LED luminaires have 1.6 timesmore » better light efficacy than either the metal halide or plasma luminaires. The light uniformity ratios produced by the plasma and LED towers are acceptable. The fuel cell thermal efficiency at the power required to operate the plasma lights is 48%, significantly higher than the diesel generator efficiency of 23% when operating the metal halide lights. Due to the increased efficiency of the fuel cell and the LED lighting, the fuel cost per lumen-hour of the H2LT is 62% of the metal halide diesel light tower assuming a kilogram of hydrogen is twice the cost of a gallon of diesel fuel.« less

  9. Alkaline and alkaline earth metal phosphate halides and phosphors

    DOE Patents [OSTI]

    Lyons, Robert Joseph; Setlur, Anant Achyut; Cleaver, Robert John

    2012-11-13

    Compounds, phosphor materials and apparatus related to nacaphite family of materials are presented. Potassium and rubidium based nacaphite family compounds and phosphors designed by doping divalent rare earth elements in the sites of alkaline earth metals in the nacaphite material families are descried. An apparatus comprising the phosphors based on the nacaphite family materials are presented herein. The compounds presented is of formula A.sub.2B.sub.1-yR.sub.yPO.sub.4X where the elements A, B, R, X and suffix y are defined such that A is potassium, rubidium, or a combination of potassium and rubidium and B is calcium, strontium, barium, or a combination of any of calcium, strontium and barium. X is fluorine, chlorine, or a combination of fluorine and chlorine, R is europium, samarium, ytterbium, or a combination of any of europium, samarium, and ytterbium, and y ranges from 0 to about 0.1.

  10. Cobalt discovery replaces precious metals as industrial catalyst

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cobalt Discovery Replaces Precious Metals Cobalt discovery replaces precious metals as industrial catalyst Cobalt holds promise as an industrial catalyst with potential applications in such energy-related technologies such as production of biofuels and reduction of carbon dioxide. November 26, 2012 The artwork depicts the substitution of cobalt for precious metals in catalysis as a variation on the ancient alchemical theme of transmuting base metals into precious ones. The artwork depicts the

  11. Cobalt discovery replaces precious metals as industrial catalyst

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cobalt Discovery Replaces Precious Metals Cobalt discovery replaces precious metals as industrial catalyst Cobalt holds promise as an industrial catalyst with potential applications in such energy-related technologies such as production of biofuels and reduction of carbon dioxide. November 26, 2012 The artwork depicts the substitution of cobalt for precious metals in catalysis as a variation on the ancient alchemical theme of transmuting base metals into precious ones. The artwork depicts the

  12. Transition metal ion-assisted photochemical generation of alkyl halides and hydrocarbons from carboxylic acids

    SciTech Connect (OSTI)

    Carraher, Jack; Pestovsky, Oleg; Bakac, Andreja

    2012-03-14

    Near-UV photolysis of aqueous solutions of propionic acid and aqueous Fe3+ in the absence of oxygen generates a mixture of hydrocarbons (ethane, ethylene and butane), carbon dioxide, and Fe2+. The reaction becomes mildly catalytic (about five turnovers) in the presence of oxygen which converts a portion of alkyl radicals to oxidizing intermediates that reoxidize Fe2+. The photochemistry in the presence of halide ions (X? = Cl?, Br?) generates ethyl halides via halogen atom abstraction from FeXn3?n by ethyl radicals. Near-quantitative yields of C2H5X are obtained at ?0.05 M X?. Competition experiments with Co(NH3)5Br2+ provided kinetic data for the reaction of ethyl radicals with FeCl2+ (k = (4.0 0.5) 106 M?1 s?1) and with FeBr2+ (k = (3.0 0.5) 107 M?1 s?1). Photochemical decarboxylation of propionic acid in the presence of Cu2+ generates ethylene and Cu+. Longer-chain acids also yield alpha olefins as exclusive products. These reactions become catalytic under constant purge with oxygen which plays a dual role. It reoxidizes Cu+ to Cu2+, and removes gaseous olefins to prevent accumulation of Cu+(olefin) complexes and depletion of Cu2+. The results underscore the profound effect that the choice of metal ions, the medium, and reaction conditions exert on the photochemistry of carboxylic acids.

  13. Evaluation of Metal Halide, Plasma, and LED Lighting Technologies for a Hydrogen Fuel Cell Mobile Light (H 2 LT)

    SciTech Connect (OSTI)

    Miller, L. B.; Donohoe, S. P.; Jones, M. H.; White, W. A.; Klebanoff, L. E.; Velinsky, S. A.

    2015-04-22

    This article reports on the testing and comparison of a prototype hydrogen fuel cell light tower (H2LT) and a conventional diesel-powered metal halide light trailer for use in road maintenance and construction activities. The prototype was originally outfitted with plasma lights and then with light-emitting diode (LED) luminaires. Light output and distribution, lighting energy efficiency (i.e., efficacy), power source thermal efficiency, and fuel costs are compared. The metal halide luminaires have 2.2 and 3.1 times more light output than the plasma and LED luminaires, respectively, but they require more power/lumen to provide that output. The LED luminaires have 1.6 times better light efficacy than either the metal halide or plasma luminaires. The light uniformity ratios produced by the plasma and LED towers are acceptable. The fuel cell thermal efficiency at the power required to operate the plasma lights is 48%, significantly higher than the diesel generator efficiency of 23% when operating the metal halide lights. Due to the increased efficiency of the fuel cell and the LED lighting, the fuel cost per lumen-hour of the H2LT is 62% of the metal halide diesel light tower assuming a kilogram of hydrogen is twice the cost of a gallon of diesel fuel.

  14. Replacing precious metals with carbide catalysts for hydrogenation reactions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ruijun, Hou; Chen, Jingguang G.; Chang, Kuan; Wang, Tiefeng

    2015-03-03

    Molybdenum carbide (Mo₂C and Ni/Mo₂C) catalysts were compared with Pd/SiO₂ for the hydrogenation of several diene molecules, 1,3- butadiene, 1,3- and 1,4-cyclohexadiene (CHD). Compared to Pd/SiO₂, Mo₂C showed similar hydrogenation rate for 1,3-butadiene and 1,3-CHD and even higher rate for 1,4-CHD, but with significant deactivation rate for 1,3-CHD hydrogenation. However, the hydrogenation activity of Mo₂C could be completely regenerated by H₂ treatment at 723 K for the three molecules. The Ni modified Mo₂C catalysts retained similar activity for 1,3-butadiene hydrogenation with significantly enhanced selectivity for 1-butene production. The 1-butene selectivity increased with increasing Ni loading below 15%. Among the Nimore » modified Mo₂C catalysts, 8.6%Ni/Mo₂C showed the highest selectivity to 1-butene, which was even higher selectivity than that over Pd/SiO₂. Compared to Pd/SiO₂, both Mo₂C and Ni/Mo₂C showed combined advantages in hydrogenation activity and catalyst cost reduction, demonstrating the potential to use less expensive carbide catalysts to replace precious metals for hydrogenation reactions.« less

  15. Replacing precious metals with carbide catalysts for hydrogenation reactions

    SciTech Connect (OSTI)

    Ruijun, Hou; Chen, Jingguang G.; Chang, Kuan; Wang, Tiefeng

    2015-03-03

    Molybdenum carbide (Mo?C and Ni/Mo?C) catalysts were compared with Pd/SiO? for the hydrogenation of several diene molecules, 1,3- butadiene, 1,3- and 1,4-cyclohexadiene (CHD). Compared to Pd/SiO?, Mo?C showed similar hydrogenation rate for 1,3-butadiene and 1,3-CHD and even higher rate for 1,4-CHD, but with significant deactivation rate for 1,3-CHD hydrogenation. However, the hydrogenation activity of Mo?C could be completely regenerated by H? treatment at 723 K for the three molecules. The Ni modified Mo?C catalysts retained similar activity for 1,3-butadiene hydrogenation with significantly enhanced selectivity for 1-butene production. The 1-butene selectivity increased with increasing Ni loading below 15%. Among the Ni modified Mo?C catalysts, 8.6%Ni/Mo?C showed the highest selectivity to 1-butene, which was even higher selectivity than that over Pd/SiO?. Compared to Pd/SiO?, both Mo?C and Ni/Mo?C showed combined advantages in hydrogenation activity and catalyst cost reduction, demonstrating the potential to use less expensive carbide catalysts to replace precious metals for hydrogenation reactions.

  16. Lutetium gadolinium halide scintillators

    DOE Patents [OSTI]

    Shah, Kanai S.; Higgins, William M; Van Loef, Edgar V; Glodo, Jaroslaw

    2010-07-13

    Lutetium gadolinium halide scintillators, devices and methods, including a composition having the formula Lu.sub.xGd.sub.(1-x)Halide and a dopant.

  17. Cobalt discovery replaces precious metals as industrial catalyst

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alchemical theme of transmuting base metals into precious ones. Contact Nancy Ambrosiano Communications Office (505) 699-1149 Email Catalysts are also integral to thousands of...

  18. An opposite view data replacement approach for reducing artifacts due to metallic dental objects

    SciTech Connect (OSTI)

    Yazdi, Mehran; Lari, Meghdad Asadi; Bernier, Gaston; Beaulieu, Luc

    2011-04-15

    Purpose: To present a conceptually new method for metal artifact reduction (MAR) that can be used on patients with multiple objects within the scan plane that are also of small sized along the longitudinal (scanning) direction, such as dental fillings. Methods: The proposed algorithm, named opposite view replacement, achieves MAR by first detecting the projection data affected by metal objects and then replacing the affected projections by the corresponding opposite view projections, which are not affected by metal objects. The authors also applied a fading process to avoid producing any discontinuities in the boundary of the affected projection areas in the sinogram. A skull phantom with and without a variety of dental metal inserts was made to extract the performance metric of the algorithm. A head and neck case, typical of IMRT planning, was also tested. Results: The reconstructed CT images based on this new replacement scheme show a significant improvement in image quality for patients with metallic dental objects compared to the MAR algorithms based on the interpolation scheme. For the phantom, the authors showed that the artifact reduction algorithm can efficiently recover the CT numbers in the area next to the metallic objects. Conclusions: The authors presented a new and efficient method for artifact reduction due to multiple small metallic objects. The obtained results from phantoms and clinical cases fully validate the proposed approach.

  19. Process and composition for drying of gaseous hydrogen halides

    DOE Patents [OSTI]

    Tom, Glenn M.; Brown, Duncan W.

    1989-08-01

    A process for drying a gaseous hydrogen halide of the formula HX, wherein X is selected from the group consisting of bromine, chlorine, fluorine, and iodine, to remove water impurity therefrom, comprising: contacting the water impurity-containing gaseous hydrogen halide with a scavenger including a support having associated therewith one or more members of the group consisting of: (a) an active scavenging moiety selected from one or more members of the group consisting of: (i) metal halide compounds dispersed in the support, of the formula MX.sub.y ; and (ii) metal halide pendant functional groups of the formula -MX.sub.y-1 covalently bonded to the support, wherein M is a y-valent metal, and y is an integer whose value is from 1 to 3; (b) corresponding partially or fully alkylated compounds and/or pendant functional groups, of the metal halide compounds and/or pendant functional groups of (a); wherein the alkylated compounds and/or pendant functional groups, when present, are reactive with the gaseous hydrogen halide to form the corresponding halide compounds and/or pendant functional groups of (a); and M being selected such that the heat of formation, .DELTA.H.sub.f of its hydrated halide, MX.sub.y.(H.sub.2 O).sub.n, is governed by the relationship: .DELTA.H.sub.f .gtoreq.n.times.10.1 kilocalories/mole of such hydrated halide compound wherein n is the number of water molecules bound to the metal halide in the metal halide hydrate. Also disclosed is an appertaining scavenger composition and a contacting apparatus wherein the scavenger is deployed in a bed for contacting with the water impurity-containing gaseous hydrogen halide.

  20. Oxidation of hydrogen halides to elemental halogens

    DOE Patents [OSTI]

    Rohrmann, Charles A. (Kennewick, WA); Fullam, Harold T. (Richland, WA)

    1985-01-01

    A process for oxidizing hydrogen halides having substantially no sulfur impurities by means of a catalytically active molten salt is disclosed. A mixture of the subject hydrogen halide and an oxygen bearing gas is contacted with a molten salt containing an oxidizing catalyst and alkali metal normal sulfates and pyrosulfates to produce an effluent gas stream rich in the elemental halogen and substantially free of sulfur oxide gases.

  1. Actinide halide complexes

    DOE Patents [OSTI]

    Avens, Larry R.; Zwick, Bill D.; Sattelberger, Alfred P.; Clark, David L.; Watkin, John G.

    1992-01-01

    A compound of the formula MX.sub.n L.sub.m wherein M is a metal atom selected from the group consisting of thorium, plutonium, neptunium or americium, X is a halide atom, n is an integer selected from the group of three or four, L is a coordinating ligand selected from the group consisting of aprotic Lewis bases having an oxygen-, nitrogen-, sulfur-, or phosphorus-donor, and m is an integer selected from the group of three or four for monodentate ligands or is the integer two for bidentate ligands, where the sum of n+m equals seven or eight for monodentate ligands or five or six for bidentate ligands, a compound of the formula MX.sub.n wherein M, X, and n are as previously defined, and a process of preparing such actinide metal compounds including admixing the actinide metal in an aprotic Lewis base as a coordinating solvent in the presence of a halogen-containing oxidant, are provided.

  2. Actinide halide complexes

    DOE Patents [OSTI]

    Avens, L.R.; Zwick, B.D.; Sattelberger, A.P.; Clark, D.L.; Watkin, J.G.

    1992-11-24

    A compound is described of the formula MX[sub n]L[sub m] wherein M is a metal atom selected from the group consisting of thorium, plutonium, neptunium or americium, X is a halide atom, n is an integer selected from the group of three or four, L is a coordinating ligand selected from the group consisting of aprotic Lewis bases having an oxygen-, nitrogen-, sulfur-, or phosphorus-donor, and m is an integer selected from the group of three or four for monodentate ligands or is the integer two for bidentate ligands, where the sum of n+m equals seven or eight for monodentate ligands or five or six for bidentate ligands. A compound of the formula MX[sub n] wherein M, X, and n are as previously defined, and a process of preparing such actinide metal compounds are described including admixing the actinide metal in an aprotic Lewis base as a coordinating solvent in the presence of a halogen-containing oxidant.

  3. APPARATUS FOR THE PRODUCTION OF LITHIUM METAL

    DOE Patents [OSTI]

    Baker, P.S.; Duncan, F.R.; Greene, H.B.

    1961-08-22

    Methods and apparatus for the production of high-purity lithium from lithium halides are described. The apparatus is provided for continuously contacting a molten lithium halide with molten barium, thereby forming lithium metal and a barium halide, establishing separate layers of these reaction products and unreacted barium and lithium halide, and continuously withdrawing lithium and barium halide from the reaction zone. (AEC)

  4. Halide and Oxy-Halide Eutectic Systems for High-Performance,...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Halide and Oxy-Halide Eutectic Systems for High-Performance, High-Temperature Heat Transfer Fluids Halide and Oxy-Halide Eutectic Systems for High-Performance, High-Temperature...

  5. PREPARATION OF HALIDES OF PLUTONIUM

    DOE Patents [OSTI]

    Garner, C.S.; Johns, I.B.

    1958-09-01

    A dry chemical method is described for preparing plutonium halides, which consists in contacting plutonyl nitrate with dry gaseous HCl or HF at an elevated temperature. The addition to the reaction gas of a small quantity of an oxidizing gas or a reducing gas will cause formation of the tetra- or tri-halide of plutonium as desired.

  6. Process for oxidation of hydrogen halides to elemental halogens

    DOE Patents [OSTI]

    Lyke, Stephen E.

    1992-01-01

    An improved process for generating an elemental halogen selected from chlorine, bromine or iodine, from a corresponding hydrogen halide by absorbing a molten salt mixture, which includes sulfur, alkali metals and oxygen with a sulfur to metal molar ratio between 0.9 and 1.1 and includes a dissolved oxygen compound capable of reacting with hydrogen halide to produce elemental halogen, into a porous, relatively inert substrate to produce a substrate-supported salt mixture. Thereafter, the substrate-supported salt mixture is contacted (stage 1) with a hydrogen halide while maintaining the substrate-supported salt mixture during the contacting at an elevated temperature sufficient to sustain a reaction between the oxygen compound and the hydrogen halide to produce a gaseous elemental halogen product. This is followed by purging the substrate-supported salt mixture with steam (stage 2) thereby recovering any unreacted hydrogen halide and additional elemental halogen for recycle to stage 1. The dissolved oxygen compound is regenerated in a high temperature (stage 3) and an optical intermediate temperature stage (stage 4) by contacting the substrate-supported salt mixture with a gas containing oxygen whereby the dissolved oxygen compound in the substrate-supported salt mixture is regenerated by being oxidized to a higher valence state.

  7. sup 3 P Hg, Cd, and Zn photosensitized chemistry of vinyl halides in krypton matrix

    SciTech Connect (OSTI)

    Cartland, H.E.; Pimentel, G.C. )

    1990-01-25

    The reaction of group IIB metals in the {sup 3}P state with vinyl fluoride, chloride, and bromide is studied in krypton matrix. The primary process in all cases is hydrogen halide elimination to form a hydrogen halide/acetylene hydrogen-bonded complex. Insertion of metal atoms into C-Cl and C-Br bonds, but not into C-H and C-F bonds, is also observed. The insertion photochemistry can be explained by a mechanism which requires that the process occur on a triplet surface with the vinyl halide in the planar ground-state conformation.

  8. Project Profile: Halide and Oxy-Halide Eutectic Systems forHigh...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Project Profile: Halide and Oxy-Halide Eutectic Systems for High-Performance, High-Temperature Heat Transfer Fluids Logos from The University of Arizona, Arizona State University, ...

  9. Vitrification of IFR and MSBR halide salt reprocessing wastes

    SciTech Connect (OSTI)

    Siemer, D.D.

    2013-07-01

    Both of the genuinely sustainable (breeder) nuclear fuel cycles (IFR - Integral Fast Reactor - and MSBR - Molten Salt Breeder Reactor -) studied by the USA's national laboratories would generate high level reprocessing waste (HLRW) streams consisting of a relatively small amount ( about 4 mole %) of fission product halide (chloride or fluoride) salts in a matrix comprised primarily (about 95 mole %) of non radioactive alkali metal halide salts. Because leach resistant glasses cannot accommodate much of any of the halides, most of the treatment scenarios previously envisioned for such HLRW have assumed a monolithic waste form comprised of a synthetic analog of an insoluble crystalline halide mineral. In practice, this translates to making a 'substituted' sodalite ('Ceramic Waste Form') of the IFR's chloride salt-based wastes and fluoroapatite of the MSBR's fluoride salt-based wastes. This paper discusses my experimental studies of an alternative waste management scenario for both fuel cycles that would separate/recycle the waste's halide and immobilize everything else in iron phosphate (Fe-P) glass. It will describe both how the work was done and what its results indicate about how a treatment process for both of those wastes should be implemented (fluoride and chloride behave differently). In either case, this scenario's primary advantages include much higher waste loadings, much lower overall cost, and the generation of a product (glass) that is more consistent with current waste management practices. (author)

  10. Preparation of cerium halide solvate complexes

    DOE Patents [OSTI]

    Vasudevan, Kalyan V; Smith, Nickolaus A; Gordon, John C; McKigney, Edward A; Muenchaussen, Ross E

    2013-08-06

    Crystals of a solvated cerium(III) halide solvate complex resulted from a process of forming a paste of a cerium(III) halide in an ionic liquid, adding a solvent to the paste, removing any undissolved solid, and then cooling the liquid phase. Diffusing a solvent vapor into the liquid phase also resulted in crystals of a solvated cerium(III) halide complex.

  11. Synthesis of metal-metal oxide catalysts and electrocatalysts using a metal cation adsorption/reduction and adatom replacement by more noble ones

    DOE Patents [OSTI]

    Adzic, Radoslav; Vukmirovic, Miomir; Sasaki, Kotaro

    2010-04-27

    The invention relates to platinum-metal oxide composite particles and their use as electrocatalysts in oxygen-reducing cathodes and fuel cells. The invention particularly relates to methods for preventing the oxidation of the platinum electrocatalyst in the cathodes of fuel cells by use of these platinum-metal oxide composite particles. The invention additionally relates to methods for producing electrical energy by supplying such a fuel cell with an oxidant, such as oxygen, and a fuel source, such as hydrogen. The invention also relates to methods of making the metal-metal oxide composites.

  12. RARE-EARTH METAL FISSION PRODUCTS FROM LIQUID U-Bi

    DOE Patents [OSTI]

    Wiswall, R.H.

    1960-05-10

    Fission product metals can be removed from solution in liquid bismuth without removal of an appreciable quantity of uranium by contacting the liquid metal solution with fused halides, as for example, the halides of sodium, potassium, and lithium and by adding to the contacted phases a quantity of a halide which is unstable relative to the halides of the fission products, a specific unstable halide being MgCl/sub 3/.

  13. Development of Halide and Oxy-Halides for Isotopic Separations

    SciTech Connect (OSTI)

    Leigh R. Martin; Aaron T. Johnson; Jana Pfeiffer; Martha R. Finck

    2014-10-01

    The goal of this project was to synthesize a volatile form of Np for introduction into mass spectrometers at INL. Volatile solids of the 5f elements are typically those of the halides (e.g. UF6), however fluorine is highly corrosive to the sensitive internal components of the mass separator, and the other volatile halides exist as several different stable isotopes in nature. However, iodide is both mono-isotopic and volatile, and as such presents an avenue for creation of a form of Np suitable for introduction into the mass separator. To accomplish this goal, the technical work in the project sought to establish a novel synthetic route for the conversion NpO2+ (dissolved in nitric acid) to NpI3 and NpI4.

  14. PROCESSING OF URANIUM-METAL-CONTAINING FUEL ELEMENTS

    DOE Patents [OSTI]

    Moore, R.H.

    1962-10-01

    A process is given for recovering uranium from neutronbombarded uranium- aluminum alloys. The alloy is dissolved in an aluminum halide--alkali metal halide mixture in which the halide is a mixture of chloride and bromide, the aluminum halide is present in about stoichiometric quantity as to uranium and fission products and the alkali metal halide in a predominant quantity; the uranium- and electropositive fission-products-containing salt phase is separated from the electronegative-containing metal phase; more aluminum halide is added to the salt phase to obtain equimolarity as to the alkali metal halide; adding an excess of aluminum metal whereby uranium metal is formed and alloyed with the excess aluminum; and separating the uranium-aluminum alloy from the fission- productscontaining salt phase. (AEC)

  15. Lanthanide doped strontium barium mixed halide scintillators

    DOE Patents [OSTI]

    Gundiah, Gautam; Bizarri, Gregory; Hanrahan, Stephen M; Bourret-Courchesne, Edith; Derenzo, Stephen E

    2013-07-16

    The present invention provides for a composition comprising an inorganic scintillator comprising a lanthanide-doped strontium barium mixed halide useful for detecting nuclear material.

  16. Diamond films treated with alkali-halides

    DOE Patents [OSTI]

    Anderson, David F.; Kwan, Simon W.

    1997-01-01

    A secondary electron emitter is provided and includes a substrate with a diamond film, the diamond film is treated or coated with an alkali-halide.

  17. Diamond films treated with alkali-halides

    DOE Patents [OSTI]

    Anderson, D.F.; Kwan, S.W.

    1997-04-08

    A secondary electron emitter is provided and includes a substrate with a diamond film, the diamond film is treated or coated with an alkali-halide. 5 figs.

  18. Lanthanide doped strontium barium mixed halide scintillators

    DOE Patents [OSTI]

    Gundiah, Gautam; Bizarri, Gregory A.; Hanrahan, Stephen M.; Bourret-Courchesne, Edith D.; Derenzo, Stephen E.

    2016-03-15

    The present invention provides for a composition comprising an inorganic scintillator comprising a lanthanide-doped strontium barium mixed halide useful for detecting nuclear material.

  19. DEPOSITION OF METAL ON NONMETAL FILAMENT

    DOE Patents [OSTI]

    Magel, T.T.

    1959-02-10

    A method is described for purifying metallic uranium by passing a halogen vapor continuously over the impure uranium to form uranium halide vapor and immediately passing the halide vapor into contact with a nonmetallic refractory surface which is at a temperature above the melting point of uranium metal. The halide is decomposed at the heated surface depositing molten metal, which collects and falls into a receiver below.

  20. Metal Halide Lamp Ballasts and Fixtures

    Broader source: Energy.gov [DOE]

    The Department of Energy (DOE) develops standardized data templates for reporting the results of tests conducted in accordance with current DOE test procedures. Templates may be used by third-party laboratories under contract with DOE that conduct testing in support of ENERGY STAR® verification, DOE rulemakings, and enforcement of the federal energy conservation standards.

  1. Hygroscopicity Evaluation of Halide Scintillators

    SciTech Connect (OSTI)

    Zhuravleva, M; Stand, L; Wei, H; Hobbs, C. L.; Boatner, Lynn A; Ramey, Joanne Oxendine; Burger, Arnold; Rowe, E; Bhattacharya, P.; Tupitsyn, E; Melcher, Charles L

    2014-01-01

    A collaborative study of relative hygroscopicity of anhydrous halide scintillators grown at various laboratories is presented. We have developed a technique to evaluate moisture sensitivity of both raw materials and grown crystals, in which the moisture absorption rate is measured using a gravimetric analysis. Degradation of the scintillation performance was investigated by recording gamma-ray spectra and monitoring the photopeak position, count rate and energy resolution. The accompanying physical degradation of the samples exposed to ambient atmosphere was photographically recorded as well. The results were compared with ben

  2. Enhanced Quantum Efficiency From Hybrid Cesium Halide/Copper Photocathode

    SciTech Connect (OSTI)

    Kong, Lingmei; Joly, Alan G.; Droubay, Timothy C.; Gong, Yu; Hess, Wayne P.

    2014-04-28

    The quantum efficiency of Cu is found to increase dramatically when coated by a CsI film and then irradiated by a UV laser. Over three orders of magnitude quantum efficiency enhancement at 266 nm is observed in CsI/Cu(100), indicating potential application in future photocathode devices. Upon laser irradiation, a large work function reduction to a value less than 2 eV is also observed, significantly greater than for similarly treated CsBr/Cu(100). The initial QE enhancement, prior to laser irradiation, is attributed to interface interaction, surface cleanliness and the intrinsic properties of the Cs halide film. Further QE enhancement following activation is attributed to formation of inter-band states and Cs metal accumulation at the interface induced by laser irradiation.

  3. Method for dry etching of transition metals

    DOE Patents [OSTI]

    Ashby, C.I.H.; Baca, A.G.; Esherick, P.; Parmeter, J.E.; Rieger, D.J.; Shul, R.J.

    1998-09-29

    A method for dry etching of transition metals is disclosed. The method for dry etching of a transition metal (or a transition metal alloy such as a silicide) on a substrate comprises providing at least one nitrogen- or phosphorus-containing {pi}-acceptor ligand in proximity to the transition metal, and etching the transition metal to form a volatile transition metal/{pi}-acceptor ligand complex. The dry etching may be performed in a plasma etching system such as a reactive ion etching (RIE) system, a downstream plasma etching system (i.e. a plasma afterglow), a chemically-assisted ion beam etching (CAIBE) system or the like. The dry etching may also be performed by generating the {pi}-acceptor ligands directly from a ligand source gas (e.g. nitrosyl ligands generated from nitric oxide), or from contact with energized particles such as photons, electrons, ions, atoms, or molecules. In some preferred embodiments of the present invention, an intermediary reactant species such as carbonyl or a halide ligand is used for an initial chemical reaction with the transition metal, with the intermediary reactant species being replaced at least in part by the {pi}-acceptor ligand for forming the volatile transition metal/{pi}-acceptor ligand complex.

  4. Method for dry etching of transition metals

    DOE Patents [OSTI]

    Ashby, Carol I. H.; Baca, Albert G.; Esherick, Peter; Parmeter, John E.; Rieger, Dennis J.; Shul, Randy J.

    1998-01-01

    A method for dry etching of transition metals. The method for dry etching of a transition metal (or a transition metal alloy such as a silicide) on a substrate comprises providing at least one nitrogen- or phosphorous-containing .pi.-acceptor ligand in proximity to the transition metal, and etching the transition metal to form a volatile transition metal/.pi.-acceptor ligand complex. The dry etching may be performed in a plasma etching system such as a reactive ion etching (RIE) system, a downstream plasma etching system (i.e. a plasma afterglow), a chemically-assisted ion beam etching (CAIBE) system or the like. The dry etching may also be performed by generating the .pi.-acceptor ligands directly from a ligand source gas (e.g. nitrosyl ligands generated from nitric oxide), or from contact with energized particles such as photons, electrons, ions, atoms, or molecules. In some preferred embodiments of the present invention, an intermediary reactant species such as carbonyl or a halide ligand is used for an initial chemical reaction with the transition metal, with the intermediary reactant species being replaced at least in part by the .pi.-acceptor ligand for forming the volatile transition metal/.pi.-acceptor ligand complex.

  5. Lanthanide-halide based humidity indicators

    DOE Patents [OSTI]

    Beitz, James V.; Williams, Clayton W.

    2008-01-01

    The present invention discloses a lanthanide-halide based humidity indicator and method of producing such indicator. The color of the present invention indicates the humidity of an atmosphere to which it is exposed. For example, impregnating an adsorbent support such as silica gel with an aqueous solution of the europium-containing reagent solution described herein, and dehydrating the support to dryness forms a substance with a yellow color. When this substance is exposed to a humid atmosphere the water vapor from the air is adsorbed into the coating on the pore surface of the silica gel. As the water content of the coating increases, the visual color of the coated silica gel changes from yellow to white. The color change is due to the water combining with the lanthanide-halide complex on the pores of the gel.

  6. METAL SURFACE TREATMENT

    DOE Patents [OSTI]

    Eubank, L.D.

    1958-08-12

    Improved flux baths are described for use in conjunction with hot dipped coatings for uranium. The flux bath consists of molten alkali metal, or alkaline earth metal halides. One preferred embodiment comprises a bath containing molten KCl, NaCl, and LiCl in proportions approximating the triple eutectic.

  7. Lasing in robust cesium lead halide perovskite nanowires (Journal...

    Office of Scientific and Technical Information (OSTI)

    Title: Lasing in robust cesium lead halide perovskite nanowires Authors: Eaton, Samuel W. ; Lai, Minliang ; Gibson, Natalie A. ; Wong, Andrew B. ; Dou, Letian ; Ma, Jie ; Wang, ...

  8. Lanthanide doped strontium-barium cesium halide scintillators

    DOE Patents [OSTI]

    Bizarri, Gregory; Bourret-Courchesne, Edith; Derenzo, Stephen E.; Borade, Ramesh B.; Gundiah, Gautam; Yan, Zewu; Hanrahan, Stephen M.; Chaudhry, Anurag; Canning, Andrew

    2015-06-09

    The present invention provides for a composition comprising an inorganic scintillator comprising an optionally lanthanide-doped strontium-barium, optionally cesium, halide, useful for detecting nuclear material.

  9. The Electrolytic Production of Metallic Uranium

    DOE Patents [OSTI]

    Rosen, R.

    1950-08-22

    This patent covers a process for producing metallic uranium by electrolyzing uranium tetrafluoride at an elevated temperature in a fused bath consisting essentially of mixed alkali and alkaline earth halides.

  10. Reversible and irreversible ion migration processes in lead halide

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    perovskites for photovoltaics | MIT-Harvard Center for Excitonics Reversible and irreversible ion migration processes in lead halide perovskites for photovoltaics March 9, 2016 at 4:30 PM/36-462 Eric Hoke Stanford University, Draper Laboratory hoke-eric Lead hybrid perovskites are a promising family of photovoltaic absorber materials that have achieved power conversion efficiencies of over 20%. Lead halide perovskites are ionic materials with a low lattice energy which are unusual properties

  11. Explosive composition with group VIII metal nitroso halide getter

    DOE Patents [OSTI]

    Walker, F.E.; Wasley, R.J.

    1982-06-22

    An improved explosive composition is disclosed and comprises a major portion of an explosive having a detonation velocity between about 1,500 and 10,000 meters per second and a minor amount of a getter additive comprising a non-explosive compound or mixture of non-explosive compounds capable of chemically reacting with free radicals or ions under shock initiation conditions of 2,000 calories/cm[sup 2] or less of energy fluence.

  12. Explosive composition with group VIII metal nitroso halide getter

    DOE Patents [OSTI]

    Walker, Franklin E.; Wasley, Richard J.

    1982-01-01

    An improved explosive composition is disclosed and comprises a major portion of an explosive having a detonation velocity between about 1,500 and 10,000 meters per second and a minor amount of a getter additive comprising a non-explosive compound or mixture of non-explosive compounds capable of chemically reacting with free radicals or ions under shock initiation conditions of 2,000 calories/cm.sup.2 or less of energy fluence.

  13. New Energy Efficiency Standards for Metal Halide Lamp Fixtures...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    WASHINGTON - As part of the Energy Department's efforts to develop efficiency standards that cut carbon pollution and save money by saving energy, U.S. Energy Secretary Ernest ...

  14. Project Profile: Halide and Oxy-Halide Eutectic Systems for High-Performance, High-Temperature Heat Transfer Fluids

    Broader source: Energy.gov [DOE]

    The University of Arizona along with partners at Arizona State University and Georgia Institute of Technology, under the 2012 Multidisciplinary University Research Initiative (MURI): High Operating Temperature (HOT) Fluids funding opportunity, is investigating the use of halide salts with oxy-halide additives as a heat transfer fluid (HTF) in concentrating solar power (CSP) systems operating at temperatures greater than 800°C. By allowing higher temperature operation, CSP systems can achieve greater efficiencies and thereby reduce the overall system cost.

  15. Method of coating graphite tubes with refractory metal carbides

    DOE Patents [OSTI]

    Wohlberg, C.

    1973-12-11

    A method of coating graphite tubes with a refractory metal carbide is described. An alkali halide is reacted with a metallic oxide, the metallic portion being selected from the IVth or Vth group of the Periodic Table, the resulting salt reacting in turn with the carbon to give the desired refractory metal carbide coating. (Official Gazette)

  16. Lattice dynamics in perovskite halides CsSn X 3 with X = I ,...

    Office of Scientific and Technical Information (OSTI)

    Lattice dynamics in perovskite halides CsSn X 3 with X I , Br , Cl Citation Details In-Document Search Title: Lattice dynamics in perovskite halides CsSn X 3 with X I , Br , Cl ...

  17. Regeneration of zinc halide catalyst used in the hydrocracking of polynuclear hydrocarbons

    DOE Patents [OSTI]

    Gorin, Everett

    1978-01-01

    Improved recovery of spent molten zinc halide hydro-cracking catalyst is achieved in the oxidative vapor phase regeneration thereof by selective treatment of the zinc oxide carried over by the effluent vapors from the regeneration zone with hydrogen halide gas under conditions favoring the reaction of the zinc oxide with the hydrogen halide, whereby regenerated zinc halide is recovered in a solids-free state with little loss of zinc values.

  18. Replacement of Lighting Fixtures with LED Energy Efficient Lights at the Parking Facility, Milwaukee, Wisconsin

    SciTech Connect (OSTI)

    David Brien

    2012-06-21

    The Forest County Potawatomi Community (FCPC or Tribe) owns a six-story parking facility adjacent to its Potawatomi Bingo Casino (the Casino) in Milwaukee, Wisconsin, as well as a valet parking facility under the Casino (collectively, the Parking Facility). The Parking Facility contained 205-watt metal halide-type lights that, for security reasons, operated 24 hours per day, 7 days per week. Starting on August 30, 2010, the Tribe replaced these fixtures with 1,760 state-of-the-art, energy efficient 55-Watt LED lights. This project resulted in an immediate average reduction in monthly peak demand of 238 kW over the fourth quarter of 2010. The average reduction in monthly peak demand from October 1 through December 31, 2010 translates into a forecast annual electrical energy reduction of approximately 1,995,000 kWh or 47.3% of the pre-project demand. This project was technically effective, economically feasible, and beneficial to the public not only in terms of long term energy efficiency and associated emissions reductions, but also in the short-term jobs provided for the S.E. Wisconsin region. The project was implemented, from approval by U.S. Department of Energy (DOE) to completion, in less than 6 months. The project utilized off-the-shelf proven technologies that were fabricated locally and installed by local trade contractors.

  19. Energy Replacement Generation Tax Exemption

    Broader source: Energy.gov [DOE]

    Under the Energy Replacement Generation Tax Exemption, the following facilities are exempt from the replacement tax:

  20. Method for providing adhesion to a metal surface

    DOE Patents [OSTI]

    Harrah, Larry A.; Allred, Ronald E.; Wilson, Jr., Kennard V.

    1992-01-01

    A process for treating metal surfaces to obtain improved susceptibility to bonding with adhesive compositions is disclosed. A metal surface is oxidized with a halogen to form a monolayer of halide ions on the surface. The halide ions are then exchanged with azide ions to form an azide monolayer on the metal surface. Upon contact of the treated surface with an adhesive composition, the azide layer may be thermally or photochemically decomposed to form active nitrene species, which react to bond the adhesive composition to the metal surface.

  1. Method for providing adhesion to a metal surface

    DOE Patents [OSTI]

    Harrah, L.A.; Allred, R.E.; Wilson, K.V. Jr.

    1992-02-18

    A process for treating metal surfaces to obtain improved susceptibility to bonding with adhesive compositions is disclosed. A metal surface is oxidized with a halogen to form a monolayer of halide ions on the surface. The halide ions are then exchanged with azide ions to form an azide monolayer on the metal surface. Upon contact of the treated surface with an adhesive composition, the azide layer may be thermally or photochemically decomposed to form active nitrene species, which react to bond the adhesive composition to the metal surface.

  2. Radiation Source Replacement Workshop

    SciTech Connect (OSTI)

    Griffin, Jeffrey W.; Moran, Traci L.; Bond, Leonard J.

    2010-12-01

    This report summarizes a Radiation Source Replacement Workshop in Houston Texas on October 27-28, 2010, which provided a forum for industry and researchers to exchange information and to discuss the issues relating to replacement of AmBe, and potentially other isotope sources used in well logging.

  3. Dissecting ion-specific dielectric spectra of sodium-halide solutions...

    Office of Scientific and Technical Information (OSTI)

    water and ionic contributions Citation Details In-Document Search Title: Dissecting ion-specific dielectric spectra of sodium-halide solutions into solvation water and ...

  4. Halide and Oxy-Halide Eutectic Systems for High-Performance, High-Temperature Heat Transfer Fluids

    Broader source: Energy.gov [DOE]

    This fact sheet details a SunShot-funded solar project led by the University of Arizona to using ab initio computational modeling along with rapid material screening methods to identify halide salt mixtures with a melting point below 250°C that are stable at temperatures well above 800°C. This research has the potential to help concentrating solar power systems achieve greater efficiencies and reduce overall costs.

  5. SEPARATION OF METAL SALTS BY ADSORPTION

    DOE Patents [OSTI]

    Gruen, D.M.

    1959-01-20

    It has been found that certain metal salts, particularly the halides of iron, cobalt, nickel, and the actinide metals, arc readily absorbed on aluminum oxide, while certain other salts, particularly rare earth metal halides, are not so absorbed. Use is made of this discovery to separate uranium from the rare earths. The metal salts are first dissolved in a molten mixture of alkali metal nitrates, e.g., the eutectic mixture of lithium nitrate and potassium nitrate, and then the molten salt solution is contacted with alumina, either by slurrying or by passing the salt solution through an absorption tower. The process is particularly valuable for the separation of actinides from lanthanum-group rare earths.

  6. Impact of the organic halide salt on final perovskite composition for photovoltaic applications

    SciTech Connect (OSTI)

    Moore, David T.; Sai, Hiroaki; Wee Tan, Kwan; Estroff, Lara A.; Wiesner, Ulrich

    2014-08-01

    The methylammonium lead halide perovskites have shown significant promise as a low-cost, second generation, photovoltaic material. Despite recent advances, however, there are still a number of fundamental aspects of their formation as well as their physical and electronic behavior that are not well understood. In this letter we explore the mechanism by which these materials crystallize by testing the outcome of each of the reagent halide salts. We find that components of both salts, lead halide and methylammonium halide, are relatively mobile and can be readily exchanged during the crystallization process when the reaction is carried out in solution or in the solid state. We exploit this fact by showing that the perovskite structure is formed even when the lead salt's anion is a non-halide, leading to lower annealing temperature and time requirements for film formation. Studies into these behaviors may ultimately lead to improved processing conditions for photovoltaic films.

  7. Fundamental studies and new applications of hybrid lead halide perovskites*

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | MIT-Harvard Center for Excitonics Fundamental studies and new applications of hybrid lead halide perovskites* November 10, 2015 at 4:30pm/Duboc Room: 4-331 Riccardo Comin University of Toronto comin-1 In recent years light-harvesting devices based on a new class of organometallic lead iodide perovskites (CH3NH3PbI3) were demonstrated to exhibit power conversion efficiencies beyond 20%, rapidly approaching the performance of commercial silicon-based modules. Besides photovoltaics, important

  8. ARRANGEMENT FOR REPLACING FILTERS

    DOE Patents [OSTI]

    Blomgren, R.A.; Bohlin, N.J.C.

    1957-08-27

    An improved filtered air exhaust system which may be continually operated during the replacement of the filters without the escape of unfiltered air is described. This is accomplished by hermetically sealing the box like filter containers in a rectangular tunnel with neoprene covered sponge rubber sealing rings coated with a silicone impregnated pneumatic grease. The tunnel through which the filters are pushed is normal to the exhaust air duct. A number of unused filters are in line behind the filters in use, and are moved by a hydraulic ram so that a fresh filter is positioned in the air duct. The used filter is pushed into a waiting receptacle and is suitably disposed. This device permits a rapid and safe replacement of a radiation contaminated filter without interruption to the normal flow of exhaust air.

  9. Replacing Lightbulbs and Ballasts | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lighting Replacing Lightbulbs and Ballasts Replacing Lightbulbs and Ballasts Replace frequently used bulbs with more energy efficient options to save money and energy. Replace...

  10. Resistivity measurements of halide-salt/MgO separators for thermal cells

    SciTech Connect (OSTI)

    Redey, L.; McParland, M. ); Guidotti, R. )

    1990-01-01

    Resistivities of 20 compositions of halide-salt/MgO mixtures (various selections and percentages of LiF, LiCl, LiBr, KCl, KBr, CsBr, and MgO) to be used in Li-alloy/metal sulfide cells have been measured at temperatures between the melting point of a particular mixture and 500{degrees}C. The resistivities were determined with cold-pressed electrolyte-binder pellets by using a special cell and DC measuring technique. Temperature, salt composition, and MgO content were found to have a strong influence on resistivity. These factors are listed in decreasing order of the magnitude of the effect. The fabrication density (porosity) of the pellet also has some effect on resistivity. These measured resistivities provide a data base to select optimum compositions of electrolyte-binder pellets for LiSi/FeS{sub 2} thermal batteries and to calculate area-specific resistances of these components for battery modeling and optimization. 5 refs., 7 figs.

  11. Heavy oil upgrading using halide catalysts in a bubbling microautoclave

    SciTech Connect (OSTI)

    Chakma, A.; Chornet, E.; Overend, R.P.; Dawson, W. )

    1988-01-01

    Athabasca bitumen has been treated with halide catalysts under a continuous flow of H{sub 2} in a 15 ml microautoclave. The H{sub 2} was bubbled through the liquid using a microporous steel grid. ZnCl{sub 2}, CuCl and ZnCl{sub 2}/CuCl mixtures, with and without tetralin, were used as catalysts. The experimental conditions were: 13.8 MPa operating pressure, 1 liter STP/min as H{sub 2} flow rate, 425-450 C and 30 min as reaction temperature and time, respectively. ZnCl{sub 2} has been found effective for converting asphaltenes into maltenes while lowering the coke formation with respect to the uncatalyzed reaction. The addition of tetralin to the reaction mixture minimized coke and gas formation.

  12. Heavy oil upgrading using halide catalysts in a bubbling microautoclave

    SciTech Connect (OSTI)

    Chakma, A.; Chornet, E.; Overend, R.P. ); Dawson, W. )

    1988-06-01

    Athabasca bitumen with halide catalysts has been treated under a continuous flow of H/sub 2/ in a 15 mL microautoclave. The H/sub 2/ was bubbled through the liquid using a microporous steel grid. ZnCl/sub 2/, CuCl and ZnCl/sub 2//CuCl mixtures, with and without tetralin, were used as catalysts. The experimental conditions were: 13.8 MPa operating pressure, 1 L/sub STP/min/ as H/sub 2/ flowrate, 425 - 450/sup 0/C and 30 min as reaction temperature and time respectively. ZnCl/sub 2/ has been found effective for converting asphaltenes into maltenes while lowering the coke formation with respect to the uncatalyzed reaction. The addition of tetralin to the reaction mixture minimized coke and gas formation.

  13. Power Plant Replacement Study

    SciTech Connect (OSTI)

    Reed, Gary

    2010-09-30

    This report represents the final report for the Eastern Illinois University power plant replacement study. It contains all related documentation from consideration of possible solutions to the final recommended option. Included are the economic justifications associated with the chosen solution along with application for environmental permitting for the selected project for construction. This final report will summarize the results of execution of an EPC (energy performance contract) investment grade audit (IGA) which lead to an energy services agreement (ESA). The project includes scope of work to design and install energy conservation measures which are guaranteed by the contractor to be self-funding over its twenty year contract duration. The cost recovery is derived from systems performance improvements leading to energy savings. The prime focus of this EPC effort is to provide a replacement solution for Eastern Illinois University’s aging and failing circa 1925 central steam production plant. Twenty-three ECMs were considered viable whose net impact will provide sufficient savings to successfully support the overall project objectives.

  14. Power Plant Replacement Study

    SciTech Connect (OSTI)

    Reed, Gary

    2010-09-30

    This report represents the final report for the Eastern Illinois University power plant replacement study. It contains all related documentation from consideration of possible solutions to the final recommended option. Included are the economic justifications associated with the chosen solution along with application for environmental permitting for the selected project for construction. This final report will summarize the results of execution of an EPC (energy performance contract) investment grade audit (IGA) which lead to an energy services agreement (ESA). The project includes scope of work to design and install energy conservation measures which are guaranteed by the contractor to be self-funding over its twenty year contract duration. The cost recovery is derived from systems performance improvements leading to energy savings. The prime focus of this EPC effort is to provide a replacement solution for Eastern Illinois Universitys aging and failing circa 1925 central steam production plant. Twenty-three ECMs were considered viable whose net impact will provide sufficient savings to successfully support the overall project objectives.

  15. Power Plant Replacement Study

    SciTech Connect (OSTI)

    Reed, Gary

    2010-09-30

    This report represents the final report for the Eastern Illinois University power plant replacement study. It contains all related documentation from consideration of possible solutions to the final recommended option. Included are the economic justifications associated with the chosen solution along with application for environmental permitting for the selected project for construction. This final report will summarize the results of execution of an EPC (energy performance contract) investment grade audit (IGA) which lead to an energy services agreement (ESA). The project includes scope of work to design and install energy conservation measures which are guaranteed by the contractor to be self-funding over its twenty year contract duration. The cost recovery is derived from systems performance improvements leading to energy savings. The prime focus of this EPC effort is to provide a replacement solution for Eastern Illinois University's aging and failing circa 1925 central steam production plant. Twenty-three ECMs were considered viable whose net impact will provide sufficient savings to successfully support the overall project objectives.

  16. Power Plant Replacement Study

    SciTech Connect (OSTI)

    Reed, Gary

    2010-09-30

    This report represents the final report for the Eastern Illinois University power plant replacement study. It contains all related documentation from consideration of possible solutions to the final recommended option. Included are the economic justifications associated with the chosen solution along with application for environmental permitting for the selected project for construction. This final report will summarize the results of execution of an EPC (energy performance contract) investment grade audit (IGA) which lead to an energy services agreement (ESA). The project includes scope of work to design and install energy conservation measures which are guaranteed by the contractor to be self?funding over its twenty year contract duration. The cost recovery is derived from systems performance improvements leading to energy savings. The prime focus of this EPC effort is to provide a replacement solution for Eastern Illinois Universitys aging and failing circa 1925 central steam production plant. Twenty?three ECMs were considered viable whose net impact will provide sufficient savings to successfully support the overall project objectives.

  17. METHOD OF MAKING ALLOYS OF SECOND RARE EARTH SERIES METALS

    DOE Patents [OSTI]

    Baker, R.D.; Hayward, B.R.

    1963-01-01

    >This invention relates to a process for alloying the second rare earth series metals with Mo, Nb, or Zr. A halide of the rare earth metal is mixed with about 1 to 20 at.% of an oxide of Mo, Nb, or Zr. Iodine and an alkali or alkaline earth metal are added, and the resulting mixture is heated in an inert atmosphere to 350 deg C. (AEC)

  18. Liquid-Metal Electrode to Enable Ultra-Low Temperature Sodium-Beta Alumina Batteries for Renewable Energy Storage

    SciTech Connect (OSTI)

    Lu, Xiaochuan; Li, Guosheng; Kim, Jin Yong; Mei, Donghai; Lemmon, John P.; Sprenkle, Vincent L.; Liu, Jun

    2014-08-01

    Metal electrodes have a high capacity for energy storage but have found limited applications in batteries because of dendrite formation and other problems. In this paper, we report a new alloying strategy that can significantly reduce the melting temperature and improve wetting with the electrolyte to allow the use of liquid metal as anode in sodium-beta alumina batteries (NBBs) at much lower temperatures (e.g., 95 to 175°C). Commercial NBBs such as sodium-sulfur (Na-S) battery and sodium-metal halide (ZEBRA) batteries typically operate at relatively high temperatures (e.g., 300-350°C) due to poor wettability of sodium on the surface of β"-Al2O3. Our combined experimental and computational studies suggest that Na-Cs alloy can replace pure sodium as the anode material, which provides a significant improvement in wettability, particularly at lower temperatures (i.e., <200°C). Single cells with the Na-Cs alloy anode exhibit excellent cycling life over those with pure sodium anode at 175 and 150°C. The cells can even operate at 95°C, which is below the melting temperature of pure sodium. These results demonstrate that NBB can be operated at ultra lower temperatures with successfully solving the wetting issue. This work also suggests a new strategy to use liquid metal as the electrode materials for advanced batteries that can avoid the intrinsic safety issues associated with dendrite formation on the anode.

  19. Methods for synthesizing alane without the formation of adducts and free of halides

    DOE Patents [OSTI]

    Zidan, Ragaiy; Knight, Douglas A; Dinh, Long V

    2013-02-19

    A process is provided to synthesize an alane without the formation of alane adducts as a precursor. The resulting product is a crystallized .alpha.-alane and is a highly stable product and is free of halides.

  20. DOE Publishes GATEWAY Report on Exterior Lighting at Princeton...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Using LED luminaires that operated night and day to replace 252 metal halide parking garage luminaires that only operated after dark showed that the inherent controllability of ...

  1. DOE Publishes GATEWAY Report on Exterior Lighting at Princeton...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and day to replace 252 metal halide parking garage luminaires that only operated after dark showed that the inherent controllability of LEDs provides opportunities for multiple...

  2. EECBG Success Story: North Carolina Playing Fields Score Brighter...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    at Mecklenburg Park. | Photo courtesy of Michael Jaycocks Energy efficient metal halide lighting is replacing the outdated lighting system at Mecklenburg Park. | Photo courtesy ...

  3. Dissecting ion-specific dielectric spectra of sodium-halide solutions into

    Office of Scientific and Technical Information (OSTI)

    solvation water and ionic contributions (Journal Article) | SciTech Connect Dissecting ion-specific dielectric spectra of sodium-halide solutions into solvation water and ionic contributions Citation Details In-Document Search Title: Dissecting ion-specific dielectric spectra of sodium-halide solutions into solvation water and ionic contributions Using extensive equilibrium molecular dynamics simulations we determine the dielectric spectra of aqueous solutions of NaF, NaCl, NaBr, and NaI.

  4. UV-visible spectroscopy of macrocyclic alkyl, nitrosyl and halide complexes of cobalt and rhodium. Experiment and calculation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hull, Emily A.; West, Aaron C.; Pestovsky, Oleg; Kristian, Kathleen E.; Ellern, Arkady; Dunne, James F.; Carraher, Jack M.; Bakac, Andreja; Windus, Theresa L.

    2015-01-22

    In this paper, transition metal complexes (NH3)5CoX2+ (X = CH3, Cl) and L(H2O)MX2+, where M = Rh or Co, X = CH3, NO, or Cl, and L is a macrocyclic N4 ligand are examined by both experiment and computation to better understand their electronic spectra and associated photochemistry. Specifically, irradiation into weak visible bands of nitrosyl and alkyl complexes (NH3)5CoCH32+ and L(H2O)MIIIX2+ (X = CH3 or NO) leads to photohomolysis that generates the divalent metal complex and ˙CH3 or ˙NO, respectively. On the other hand, when X = halide or NO2, visible light photolysis leads to dissociation of X– and/ormore » cis/trans isomerization. Computations show that visible bands for alkyl and nitrosyl complexes involve transitions from M–X bonding orbitals and/or metal d orbitals to M–X antibonding orbitals. In contrast, complexes with X = Cl or NO2 exhibit only d–d bands in the visible, so that homolytic cleavage of the M–X bond requires UV photolysis. UV-Vis spectra are not significantly dependent on the structure of the equatorial ligands, as shown by similar spectral features for (NH3)5CoCH32+ and L1(H2O)CoCH32+.« less

  5. WIPP Workers Perform Filter Replacement

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    December 10, 2015 WIPP Workers Perform Filter Replacement As recovery operations at the Waste Isolation Pilot Plant continue, increased work activity in the underground results in higher levels of airborne salt dust, increasing the frequency with which filters are replaced. Last week, workers performed a filter replacement on WIPP's Underground Ventilation System. WIPP's ventilation system has two filter units. Each unit has 84 separate filters arranges in four layers- moderate efficiency

  6. Virent is Replacing Crude Oil

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Virent 2014 Virent is Replacing Crude Oil. Biomass 2014 July 30, 2014 Randy D. Cortright, ... Plants Partners & Investors Converting plant-based feedstocks to fuels and chemicals 75 ...

  7. Replacement Cost of Domestic Crude

    Energy Science and Technology Software Center (OSTI)

    1994-12-01

    The DEEPWATER model forecasts the replacement cost of domestic crude oil for 13 offshore regions in the lower 48 states. The replacement cost of domestic crude oil is the constant or levelized selling price that will recover the full expense of exploration, development, and productions with a reasonable return on capital.

  8. FUSED SALT METHOD FOR COATING URANIUM WITH A METAL

    DOE Patents [OSTI]

    Eubank, L.D.

    1959-02-01

    A method is presented for coating uranium with a less active metal such as Cr, Ni, or Cu comprising immersing the U in a substantially anhydrous molten solution of a halide of these less active metals in a ternary chloride composition which consists of selected percentages of KCl, NaCl and another chloride such as LiCl or CaCl/sub 2/.

  9. Electronic band structure trends of perovskite halides: Beyond Pb and Sn to

    Office of Scientific and Technical Information (OSTI)

    Ge and Si (Journal Article) | DOE PAGES Electronic band structure trends of perovskite halides: Beyond Pb and Sn to Ge and Si This content will become publicly available on May 23, 2017 « Prev Next » Title: Electronic band structure trends of perovskite halides: Beyond Pb and Sn to Ge and Si Authors: Huang, Ling-yi ; Lambrecht, Walter R. L. Publication Date: 2016-05-23 OSTI Identifier: 1254217 Grant/Contract Number: SC0008933 Type: Publisher's Accepted Manuscript Journal Name: Physical

  10. Lattice dynamics in perovskite halides CsSn X 3 with X = I , Br , Cl

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | DOE PAGES Lattice dynamics in perovskite halides CsSn X 3 with X = I , Br , Cl « Prev Next » Title: Lattice dynamics in perovskite halides CsSn X 3 with X = I , Br , Cl Authors: Huang, Ling-yi ; Lambrecht, Walter R. L. Publication Date: 2014-11-05 OSTI Identifier: 1180124 Grant/Contract Number: ER 46874-SC0008933 Type: Publisher's Accepted Manuscript Journal Name: Physical Review B Additional Journal Information: Journal Volume: 90; Journal Issue: 19; Journal ID: ISSN

  11. Electronic band structure trends of perovskite halides: Beyond Pb and Sn to

    Office of Scientific and Technical Information (OSTI)

    Ge and Si (Journal Article) | SciTech Connect Electronic band structure trends of perovskite halides: Beyond Pb and Sn to Ge and Si Citation Details In-Document Search This content will become publicly available on May 23, 2017 Title: Electronic band structure trends of perovskite halides: Beyond Pb and Sn to Ge and Si Authors: Huang, Ling-yi ; Lambrecht, Walter R. L. Publication Date: 2016-05-23 OSTI Identifier: 1254217 Grant/Contract Number: SC0008933 Type: Publisher's Accepted Manuscript

  12. Shape Evolution and Single Particle Luminescence of Organometal Halide Perovskite Nanocrystals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhu, Feng; Men, Long; Guo, Yijun; Zhu, Qiaochu; Bhattacharjee, Ujjal; Goodwin, Peter M.; Petrich, Jacob W.; Smith, Emily A.; Vela, Javier

    2015-02-09

    Organometallic halide perovskites CH3NH3PbX3 (X = I, Br, Cl) have quickly become one of the most promising semiconductors for solar cells, with photovoltaics made of these materials reaching power conversion efficiencies of near 20%. Improving our ability to harness the full potential of organometal halide perovskites will require more controllable syntheses that permit a detailed understanding of their fundamental chemistry and photophysics. In our manuscript, we systematically synthesize CH3NH3PbX3 (X = I, Br) nanocrystals with different morphologies (dots, rods, plates or sheets) by using different solvents and capping ligands. CH3NH3PbX3 nanowires and nanorods capped with octylammonium halides show relatively highermore » photoluminescence (PL) quantum yields and long PL lifetimes. CH3NH3PbI3 nanowires monitored at the single particle level show shape-correlated PL emission across whole particles, with little photobleaching observed and very few off periods. Our work highlights the potential of low-dimensional organometal halide perovskite semiconductors in constructing new porous and nanostructured solar cell architectures, as well as in applying these materials to other fields such as light-emitting devices and single particle imaging and tracking.« less

  13. Shape Evolution and Single Particle Luminescence of Organometal Halide Perovskite Nanocrystals

    SciTech Connect (OSTI)

    Zhu, Feng; Men, Long; Guo, Yijun; Zhu, Qiaochu; Bhattacharjee, Ujjal; Goodwin, Peter M.; Petrich, Jacob W.; Smith, Emily A.; Vela, Javier

    2015-02-09

    Organometallic halide perovskites CH3NH3PbX3 (X = I, Br, Cl) have quickly become one of the most promising semiconductors for solar cells, with photovoltaics made of these materials reaching power conversion efficiencies of near 20%. Improving our ability to harness the full potential of organometal halide perovskites will require more controllable syntheses that permit a detailed understanding of their fundamental chemistry and photophysics. In our manuscript, we systematically synthesize CH3NH3PbX3 (X = I, Br) nanocrystals with different morphologies (dots, rods, plates or sheets) by using different solvents and capping ligands. CH3NH3PbX3 nanowires and nanorods capped with octylammonium halides show relatively higher photoluminescence (PL) quantum yields and long PL lifetimes. CH3NH3PbI3 nanowires monitored at the single particle level show shape-correlated PL emission across whole particles, with little photobleaching observed and very few off periods. Our work highlights the potential of low-dimensional organometal halide perovskite semiconductors in constructing new porous and nanostructured solar cell architectures, as well as in applying these materials to other fields such as light-emitting devices and single particle imaging and tracking.

  14. THE EFFECTS OF HALIDE MODIFIERS ON THE SORPTION KINETICS OF THE LI-MG-N-H SYSTEM

    SciTech Connect (OSTI)

    Anton, D.; Gray, J.; Price, C.; Lascola, R.

    2011-07-20

    The effects of different transition metal halides (TiCl{sub 3}, VCl{sub 3}, ScCl{sub 3} and NiCl{sub 2}) on the sorption properties of the 1:1 molar ratio of LiNH{sub 2} to MgH{sub 2} are investigated. The modified mixtures were found to contain LiNH{sub 2}, MgH{sub 2} and LiCl. TGA results showed that the hydrogen desorption temperature was reduced with the modifier addition in this order: TiCl{sub 3} > ScCl{sub 3} > VCl{sub 3} > NiCL{sub 2}. Ammonia release was not significantly reduced resulting in a weight loss greater than the theoretical hydrogen storage capacity of the material. The isothermal sorption kinetics of the modified systems showed little improvement after the first dehydrogenation cycle over the unmodified system but showed drastic improvement in rehydrogenation cycles. X-ray diffraction and Raman spectroscopy identified the cycled material to be composed of LiH, MgH{sub 2}, Mg(NH{sub 2}){sub 2} and Mg{sub 3}N{sub 2}.

  15. Do You Have Windows That Need Replacing?

    Broader source: Energy.gov [DOE]

    Do you have windows that need replacing, too? Do you have any plans to replace them with newer, more efficient windows?

  16. Extraction of trace metals from fly ash

    DOE Patents [OSTI]

    Blander, Milton; Wai, Chien M.; Nagy, Zoltan

    1984-01-01

    A process for recovering silver, gallium and/or other trace metals from a fine grained industrial fly ash associated with a process for producing phosphorous, the fly ash having a silicate base and containing surface deposits of the trace metals as oxides, chlorides or the like, with the process being carried out by contacting the fly ash with AlCl.sub.3 in an alkali halide melt to react the trace metals with the AlCl.sub.3 to form compositions soluble in the melt and a residue containing the silicate and aluminum oxide or other aluminum precipitate, and separating the desired trace metal or metals from the melt by electrolysis or other separation techniques.

  17. Extraction of trace metals from fly ash

    DOE Patents [OSTI]

    Blander, M.; Wai, C.M.; Nagy, Z.

    1983-08-15

    A process is described for recovering silver, gallium and/or other trace metals from a fine grained industrial fly ash associated with a process for producing phosphorous. The fly ash has a silicate base and contains surface deposits of the trace metals as oxides, chlorides or the like. The process is carried out by contacting the fly ash with AlCl/sub 3/ in an alkali halide melt to react the trace metals with the AlCl/sub 3/ to form compositions soluble in the melt and a residue containing the silicate and aluminum oxide or other aluminum precipitate, and separating the desired trace metal or metals from the melt by electrolysis or other separation techniques.

  18. NREL Investigates Critical Properties of Perovskite Halides Solar Cells (Fact Sheet), NREL Highlights in Science, NREL (National Renewable Energy Laboratory)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Results give insight on a novel, promising class of photoactive materials for solar conversion applications. Organometallic halide perovskites (e.g., CH 3 NH 3 PbI 3 ) are a novel class of light- absorbing materials that have demon- strated exceptional progress in solar cell performance. But despite rapid progress in device performance, under- standing the structural and electronic properties of halide perovskites is just in its infancy-and obtaining information on charge diffusion length is

  19. Modifications to Replacement Costs System

    SciTech Connect (OSTI)

    Godec, M. [ICF Resources, Inc., Fairfax, VA (United States)

    1989-05-18

    The purpose of this memorandum is to document the improvements and modifications made to the Replacement Costs of Crude Oil (REPCO) Supply Analysis System. While some of this work was performed under our previous support contract to DOE/ASFE, we are presenting all modifications and improvements are presented here for completeness. The memo primarily documents revisions made to the Lower-48 Onshore Model. Revisions and modifications made to other components and models in the REPCO system which are documented elsewhere are only highlighted in this memo. Generally, the modifications made to the Lower-48 Onshore Model reflect changes that have occurred in domestic drilling, oil field costs, and reserves since 1982, the date of the most recent available data used for the original Replacement Costs report, published in 1985.

  20. Investigation into Nanostructured Lanthanum Halides and CeBr{sub 3} for Nuclear Radiation Detection

    SciTech Connect (OSTI)

    Guss, P., Guise, R., Mukhopadhyay, S., Yuan, D.

    2011-06-22

    This slide-show presents work on radiation detection with nanostructured lanthanum halides and CeBr{sub 3}. The goal is to extend the gamma energy response on both low and high-energy regimes by demonstrating the ability to detect low-energy x-rays and relatively high-energy activation prompt gamma rays simultaneously using the nano-structured lanthanum bromide, lanthanum fluoride, cerium bromide, or other nanocrystal material. Homogeneous and nano structure cases are compared.

  1. Lanthanum halide scintillators for time-of-flight 3-D pet

    DOE Patents [OSTI]

    Karp, Joel S.; Surti, Suleman

    2008-06-03

    A Lanthanum Halide scintillator (for example LaCl.sub.3 and LaBr.sub.3) with fast decay time and good timing resolution, as well as high light output and good energy resolution, is used in the design of a PET scanner. The PET scanner includes a cavity for accepting a patient and a plurality of PET detector modules arranged in an approximately cylindrical configuration about the cavity. Each PET detector includes a Lanthanum Halide scintillator having a plurality of Lanthanum Halide crystals, a light guide, and a plurality of photomultiplier tubes arranged respectively peripherally around the cavity. The good timing resolution enables a time-of-flight (TOF) PET scanner to be developed that exhibits a reduction in noise propagation during image reconstruction and a gain in the signal-to-noise ratio. Such a PET scanner includes a time stamp circuit that records the time of receipt of gamma rays by respective PET detectors and provides timing data outputs that are provided to a processor that, in turn, calculates time-of-flight (TOF) of gamma rays through a patient in the cavity and uses the TOF of gamma rays in the reconstruction of images of the patient.

  2. Preferential Eu Site Occupation and Its Consequences in the Ternary Luminescent HalidesAB2I5:Eu2+(A=Li–Cs;B=Sr, Ba)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fang, C.  M.; Biswas, Koushik

    2015-07-22

    Several rare-earth-doped, heavy-metal halides have recently been identified as potential next-generation luminescent materials with high efficiency at low cost. AB2I5:Eu2+ (A=Li–Cs; B=Sr, Ba) is one such family of halides. Its members, such as CsBa2I5:Eu2+ and KSr2I5:Eu2+, are currently being investigated as high-performance scintillators with improved sensitivity, light yield, and energy resolution less than 3% at 662 keV. Within the AB2I5 family, our first-principles-based calculations reveal two remarkably different trends in Eu site occupation. The substitutional Eu ions occupy both eightfold-coordinated B1(VIII) and the sevenfold-coordinated B2(VII) sites in the Sr-containing compounds. However, in the Ba-containing crystals, Eu ions strongly prefer themore » B2(VII)sites. This random versus preferential distribution of Eu affects their electronic properties. The calculations also suggest that in the Ba-containing compounds one can expect the formation of Eu-rich domains. These results provide atomistic insight into recent experimental observations about the concentration and temperature effects in Eu-doped CsBa2I5. We discuss the implications of our results with respect to luminescent properties and applications. We also hypothesize Sr, Ba-mixed quaternary iodides ABaVIIISrVIII5:Eu as scintillators having enhanced homogeneity and electronic properties.« less

  3. Preferential Eu Site Occupation and Its Consequences in the Ternary Luminescent HalidesAB2I5:Eu2+(A=Li–Cs;B=Sr, Ba)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fang, C.  M.; Biswas, Koushik

    2015-07-22

    Several rare-earth-doped, heavy-metal halides have recently been identified as potential next-generation luminescent materials with high efficiency at low cost. AB2I5:Eu2+ (A=Li–Cs; B=Sr, Ba) is one such family of halides. Its members, such as CsBa2I5:Eu2+ and KSr2I5:Eu2+, are currently being investigated as high-performance scintillators with improved sensitivity, light yield, and energy resolution less than 3% at 662 keV. Within the AB2I5 family, our first-principles-based calculations reveal two remarkably different trends in Eu site occupation. The substitutional Eu ions occupy both eightfold-coordinated B1(VIII) and the sevenfold-coordinated B2(VII) sites in the Sr-containing compounds. However, in the Ba-containing crystals, Eu ions strongly prefer themore »B2(VII)sites. This random versus preferential distribution of Eu affects their electronic properties. The calculations also suggest that in the Ba-containing compounds one can expect the formation of Eu-rich domains. These results provide atomistic insight into recent experimental observations about the concentration and temperature effects in Eu-doped CsBa2I5. We discuss the implications of our results with respect to luminescent properties and applications. We also hypothesize Sr, Ba-mixed quaternary iodides ABaVIIISrVIII5:Eu as scintillators having enhanced homogeneity and electronic properties.« less

  4. Cobalt discovery replaces precious metals as industrial catalyst

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    biofuels, and the reduction of carbon dioxide. It also has implications for organic chemistry, where hydrogenation is a commonly practiced catalytic reaction that produces...

  5. Cobalt discovery replaces precious metals as industrial catalyst

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    process biomass to fuel June, 19 2013 - Improved methods for breaking down cellulose nanofibers are central to cost-effective biofuel production. A high-resolution microscopic...

  6. B Plant process piping replacement feasibility study

    SciTech Connect (OSTI)

    Howden, G.F.

    1996-02-07

    Reports on the feasibility of replacing existing embedded process piping with new more corrosion resistant piping between cells and between cells and a hot pipe trench of a Hanford Site style canyon facility. Provides concepts for replacement piping installation, and use of robotics to replace the use of the canyon crane as the primary means of performing/supporting facility modifications (eg, cell lining, pipe replacement, equipment reinstallation) and operational maintenenace.

  7. Advances in the growth of alkaline-earth halide single crystals for scintillator detectors

    SciTech Connect (OSTI)

    Boatner, Lynn A; Ramey, Joanne Oxendine; Kolopus, James A; Neal, John S; Cherepy, Nerine; Payne, Stephen A.; Beck, P; Burger, Arnold; Rowe, E; Bhattacharya, P.

    2014-01-01

    Alkaline-earth scintillators such as strontium iodide and other alkaline-earth halides activated with divalent europium represent some of the most efficient and highest energy resolution scintillators for use as gamma-ray detectors in a wide range of applications. These applications include the areas of nuclear nonproliferation, homeland security, the detection of undeclared nuclear material, nuclear physics and materials science, medical diagnostics, space physics, high energy physics, and radiation monitoring systems for first responders, police, and fire/rescue personnel. Recent advances in the growth of large single crystals of these scintillator materials hold the promise of higher crystal yields and significantly lower detector production costs. In the present work, we describe new processing protocols that, when combined with our molten salt filtration methods, have led to advances in achieving a significant reduction of cracking effects during the growth of single crystals of SrI2:Eu2+. In particular, we have found that extended pumping on the molten crystal-growth charge under vacuum for time periods extending up to 48 hours is generally beneficial in compensating for variations in the alkaline-earth halide purity and stoichiometry of the materials as initially supplied by commercial sources. These melt-pumping and processing techniques are now being applied to the purification of CaI2:Eu2+ and some mixed-anion europium-doped alkaline-earth halides prior to single-crystal growth by means of the vertical Bridgman technique. The results of initial studies of the effects of aliovalent doping of SrI2:Eu2+ on the scintillation characteristics of this material are also described.

  8. Method of removal of heavy metal from molten salt in IFR fuel pyroprocessing

    DOE Patents [OSTI]

    Gay, Eddie C.

    1995-01-01

    An electrochemical method of separating heavy metal values from a radioactive molten salt including Li halide at temperatures of about 500.degree. C. The method comprises positioning a solid Li--Cd alloy anode in the molten salt containing the heavy metal values, positioning a Cd-containing cathode or a solid cathode positioned above a catch crucible in the molten salt to recover the heavy metal values, establishing a voltage drop between the anode and the cathode to deposit material at the cathode to reduce the concentration of heavy metals in the salt, and controlling the deposition rate at the cathode by controlling the current between the anode and cathode.

  9. Calcium manganate: A promising candidate as buffer layer for hybrid halide perovskite photovoltaic-thermoelectric systems

    SciTech Connect (OSTI)

    Zhao, Pengjun; Wang, Hongguang; Kong, Wenwen; Xu, Jinbao Wang, Lei; Ren, Wei; Bian, Liang; Chang, Aimin

    2014-11-21

    We have systematically studied the feasibility of CaMnO{sub 3} thin film, an n-type perovskite, to be utilized as the buffer layer for hybrid halide perovskite photovoltaic-thermoelectric device. Locations of the conduction band and the valence band, spontaneous polarization performance, and optical properties were investigated. Results indicate the energy band of CaMnO{sub 3} can match up well with that of CH{sub 3}NH{sub 3}PbI{sub 3} on separating electron-hole pairs. In addition, the consistent polarization angle helps enlarge the open circuit voltage of the composite system. Besides, CaMnO{sub 3} film shows large absorption coefficient and low extinction coefficient under visible irradiation, demonstrating high carrier concentration, which is beneficial to the current density. More importantly, benign thermoelectric properties enable CaMnO{sub 3} film to assimilate phonon vibration from CH{sub 3}NH3PbI{sub 3}. All the above features lead to a bright future of CaMnO{sub 3} film, which can be a promising candidate as a buffer layer for hybrid halide perovskite photovoltaic-thermoelectric systems.

  10. Retail Replacement Lamps | Department of Energy

    Energy Savers [EERE]

    CALiPER Testing » Application Reports » Retail Replacement Lamps Retail Replacement Lamps Annual CALiPER testing of A19, G25, candelabra, night light, MR16/PAR16, PAR20, and PAR30 replacement lamps - purchased directly from store shelves - offers insights on performance trends from year to year. The report findings offer valuable insights for manufacturers and retailers alike. Retail Lamps Study 3 (48 pages, February 2014) Retail Lamps Study 3.1: Dimming, Flicker, and Power Quality

  11. Grand Coulee & Hungry Horse SCADA Replacement

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    extensive maintenance and repairs. The turbine hubs on these units have experienced chronic oil leaks. The history of problems led to a decision to replace the turbine runners...

  12. Ni Clusterbank Replacement Project | Argonne Leadership Computing...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ni Clusterbank Replacement Project Event Sponsor: Argonne Leadership Computing Facility Seminar Start Date: Oct 20 2015 - 12:00pm BuildingRoom: Building 241Room D173...

  13. Electronic-type vacuum gauges with replaceable elements

    DOE Patents [OSTI]

    Edwards, Jr., David (7 Brown's La., Bellport, NY 11713)

    1984-01-01

    In electronic devices for measuring pressures in vacuum systems, the metal elements which undergo thermal deterioration are made readily replaceable by making them parts of a simple plug-in unit. Thus, in ionization gauges, the filament and grid or electron collector are mounted on the novel plug-in unit. In thermocouple pressure gauges, the heater and attached thermocouple are mounted on the plug-in unit. Plug-in units have been designed to function, alternatively, as ionization gauge and as thermocouple gauge, thus providing new gauges capable of measuring broader pressure ranges than is possible with either an ionization gauge or a thermocouple gauge.

  14. Electronic-type vacuum gauges with replaceable elements

    DOE Patents [OSTI]

    Edwards, D. Jr.

    1984-09-18

    In electronic devices for measuring pressures in vacuum systems, the metal elements which undergo thermal deterioration are made readily replaceable by making them parts of a simple plug-in unit. Thus, in ionization gauges, the filament and grid or electron collector are mounted on the novel plug-in unit. In thermocouple pressure gauges, the heater and attached thermocouple are mounted on the plug-in unit. Plug-in units have been designed to function, alternatively, as ionization gauge and as thermocouple gauge, thus providing new gauges capable of measuring broader pressure ranges than is possible with either an ionization gauge or a thermocouple gauge. 5 figs.

  15. Ambient-temperature superconductor symetrical metal-dihalide bis-(ethylenedithio)-tetrathiafulvalene compounds

    DOE Patents [OSTI]

    Williams, Jack M.; Wang, Hsien-Hau; Beno, Mark A.

    1987-01-01

    A new class of organic superconductors having the formula (ET).sub.2 MX.sub.2 wherein ET represents bis(ethylenedithio)-tetrathiafulvalene, M is a metal such as Au, Ag, In, Tl, Rb, Pd and the like and X is a halide. The superconductor (ET).sub.2 AuI.sub.2 exhibits a transition temperature of 5 K. which is high for organic superconductors.

  16. Ion Segregation and Deliquescence of Alkali Halide Nanocrystals on SiO2

    SciTech Connect (OSTI)

    Arima, Kenta; Jiang, Peng; Lin, Deng-Sung; Verdaguer, Albert; Salmeron, Miquel

    2009-08-11

    The adsorption of water on alkali halide (KBr, KCl, KF, NaCl) nanocrystals on SiO{sub 2} and their deliquescence was investigated as a function of relative humidity (RH) from 8% to near saturation by scanning polarization force microscopy. At low humidity, water adsorption solvates ions at the surface of the crystals and increases their mobility. This results in a large increase in the dielectric constant, which is manifested in an increase in the electrostatic force and in an increase in the apparent height of the nanocrystals. Above 58% RH, the diffusion of ions leads to Ostwald ripening, where larger nanocrystals grow at the expense of the smaller ones. At the deliquescence point, droplets were formed. For KBr, KCl, and NaCl, the droplets exhibit a negative surface potential relative to the surrounding region, which is indicative of the preferential segregation of anions to the air/solution interface.

  17. Replacement solvents for use in chemical synthesis

    DOE Patents [OSTI]

    Molnar, Linda K.; Hatton, T. Alan; Buchwald, Stephen L.

    2001-05-15

    Replacement solvents for use in chemical synthesis include polymer-immobilized solvents having a flexible polymer backbone and a plurality of pendant groups attached onto the polymer backbone, the pendant groups comprising a flexible linking unit bound to the polymer backbone and to a terminal solvating moiety. The polymer-immobilized solvent may be dissolved in a benign medium. Replacement solvents for chemical reactions for which tetrahydrofuran or diethyl may be a solvent include substituted tetrahydrofurfuryl ethers and substituted tetrahydro-3-furan ethers. The replacement solvents may be readily recovered from the reaction train using conventional methods.

  18. Conceptual Design Plan SM-43 Replacement Project

    SciTech Connect (OSTI)

    University of California, Los Alamos National Laboratory, SCC Project Office

    2000-11-01

    The Los Alamos National Laboratory Conceptual Design Plan for the SM-43 Replacement Project outlines plans for replacing the SM-43 Administration Building. Topics include the reasons that replacement is considered a necessity; the roles of the various project sponsors; and descriptions of the proposed site and facilities. Also covered in this proposal is preliminary information on the project schedule, cost estimates, acquisition strategy, risk assessment, NEPA strategy, safety strategy, and safeguards and security. Spreadsheets provide further detail on space requirements, project schedules, and cost estimates.

  19. DOE Publishes GATEWAY Report on High-Luminous-Flux LED Lighting in a High-Temperature Environment

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy has released a GATEWAY report on a trial demonstration in which the incumbent quartz metal halide (QMH) area lighting was replaced with LED at three pole locations...

  20. Positive-electrode current collector for liquid-metal cells

    DOE Patents [OSTI]

    Shimotake, H.; Bartholme, L.G.

    1982-09-27

    A current collector for the positive electrode of an electrochemical cell with a positive electrode including a sulfide. The cell also has a negative electrode and a molten salt electrolyte including halides of a metal selected from the alkali metals and the alkaline earth metals in contact with both the positive and negative electrodes. The current collector has a base metal of copper, silver, gold, aluminum or alloys thereof with a coating thereon of iron, nickel, chromium or alloys thereof. The current collector when subjected to cell voltage forms a sulfur-containing compound on the surface thereby substantially protecting the current collector from further attack by sulfur ions during cell operation. Both electroless and electrolytic processes may be used to deposit coatings.

  1. Positive electrode current collector for liquid metal cells

    DOE Patents [OSTI]

    Shimotake, Hiroshi; Bartholme, Louis G.

    1984-01-01

    A current collector for the positive electrode of an electrochemical cell with a positive electrode including a sulfide. The cell also has a negative electrode and a molten salt electrolyte including halides of a metal selected from the alkali metals and the alkaline earth metals in contact with both the positive and negative electrodes. The current collector has a base metal of copper, silver, gold, aluminum or alloys thereof with a coating thereon of iron, nickel, chromium or alloys thereof. The current collector when subjected to cell voltage forms a sulfur-containing compound on the surface thereby substantially protecting the current collector from further attack by sulfur ions during cell operation. Both electroless and electrolytic processes may be used to deposit coatings.

  2. Grand Coulee & Hungry Horse SCADA Replacement

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Gates Replacement This project is part of the Third Powerplant overhaul at Grand Coulee Dam. The full overhaul effort involves a mechanical overhaul of units G19 - G24. The...

  3. Marin County- Wood Stove Replacement Rebate Program

    Broader source: Energy.gov [DOE]

    Homes in the San Geronimo Valley (Forest Knolls, Lagunitas, San Geronimo, and Woodacre) can receive a rebate of $1,500 for the removal and replacement of non-certified wood burning appliances with...

  4. Calcium looping process for high purity hydrogen production integrated with capture of carbon dioxide, sulfur and halides

    DOE Patents [OSTI]

    Ramkumar, Shwetha; Fan, Liang-Shih

    2015-11-04

    A process for producing hydrogen comprising the steps of: (i) gasifying a fuel into a raw synthesis gas comprising CO, hydrogen, steam, sulfur and halide contaminants in the form of H.sub.2S, COS, and HX, wherein X is a halide; (ii) passing the raw synthesis gas through a water gas shift reactor (WGSR) into which CaO and steam are injected, the CaO reacting with the shifted gas to remove CO.sub.2, sulfur and halides in a solid-phase calcium-containing product comprising CaCO.sub.3, CaS and CaX.sub.2; (iii) separating the solid-phase calcium-containing product from an enriched gaseous hydrogen product; and (iv) regenerating the CaO by calcining the solid-phase calcium-containing product at a condition selected from the group consisting of: in the presence of steam, in the presence of CO.sub.2, in the presence of synthesis gas, in the presence of H.sub.2 and O.sub.2, under partial vacuum, and combinations thereof.

  5. Calcium looping process for high purity hydrogen production integrated with capture of carbon dioxide, sulfur and halides

    DOE Patents [OSTI]

    Ramkumar, Shwetha; Fan, Liang-Shih

    2013-07-30

    A process for producing hydrogen comprising the steps of: (i) gasifying a fuel into a raw synthesis gas comprising CO, hydrogen, steam, sulfur and halide contaminants in the form of H.sub.2S, COS, and HX, wherein X is a halide; (ii) passing the raw synthesis gas through a water gas shift reactor (WGSR) into which CaO and steam are injected, the CaO reacting with the shifted gas to remove CO.sub.2, sulfur and halides in a solid-phase calcium-containing product comprising CaCO.sub.3, CaS and CaX.sub.2; (iii) separating the solid-phase calcium-containing product from an enriched gaseous hydrogen product; and (iv) regenerating the CaO by calcining the solid-phase calcium-containing product at a condition selected from the group consisting of: in the presence of steam, in the presence of CO.sub.2, in the presence of synthesis gas, in the presence of H.sub.2 and O.sub.2, under partial vacuum, and combinations thereof.

  6. Silver-halide/organic-composite structures: Toward materials with multiple photographic functionalities

    SciTech Connect (OSTI)

    Bringley, Joseph F. . E-mail: joseph.bringley@kodak.com; Rajeswaran, Manju; Olson, Leif P.; Liebert, Nancy M.

    2005-10-15

    We report the synthesis and structure of the novel silver-halide-based organic-inorganic hybrids Ag{sub 2}Br{sub 6}(PPD){sub 2}, Ag{sub 2}Br{sub 6}(CD-2){sub 2}.H{sub 2}O, Ag{sub 2}Br{sub 4}(TMBD), and Ag{sub 2}I{sub 6}(CD-2){sub 2}.H{sub 2}O. 1,4-phenylenediammonium hexabromodiargentate(I) [Ag{sub 2}Br{sub 6}(PPD){sub 2}] crystals are monoclinic (P2{sub 1}/n), with unit-cell dimensions, a=10.1915(3)A, b=7.7562(2)A, c=12.4340(5)A and {beta}=93.109(1){sup o}. N,N-diethyl-2-methyl-1,4-benzenediammonium hexabromodiargentate(I) monohydrate [Ag{sub 2}Br{sub 6}(CD-2){sub 2}.H{sub 2}O] crystals are monoclinic (space group P2{sub 1}/c) with a=10.8434(2)A, b=11.4293(2)A, c=14.3729(1)A, and {beta}=96.153(1){sup o}. N,N,N',N'-tetramethyl-1,4-benzenediammonium tetrabromodiargentate(I) [Ag{sub 2}Br{sub 4}(TMBD)] crystals are orthorhombic (space group Pbcn) with a=17.0030(6)A, b=6.6163(2)A, and c=15.9762(6)A. N,N-diethyl-2-methyl-1,4-benzenediammonium hexaiododiargentate(I) monohydrate, [Ag{sub 2}I{sub 6}(CD-2){sub 2}.H{sub 2}O], are monoclinic (C2/c), with unit-cell dimensions, a=21.4691(4)A, b=12.1411(2)A, c=14.3102(2)A, and {beta}=98.657(1){sup o}. The novel structures are members of a class of silver-halide-based organic-inorganic hybrids based upon the assembly of [Ag{sub a}X{sub b}]{sup n-} clusters and protonated organoamines in aqueous mineral acids. The clusters display short intracluster Ag-Ag distances, and computational methods are used to evaluate intracluster Ag-Ag bonding. The diverse stoichiometries and cluster connectivities observed suggest a rich compositional and structural chemistry based upon the general assembly method. We have extended the methodology to include a silver-halide-organoamonium chemistry in which the organic moiety is chosen to serve a specific photographic function and demonstrate the first examples of such materials. The methodology allows for the direct assembly of [Ag{sub a}X{sub b}]{sup n-} clusters with commercial photographic color developer molecules, and we show that development is repressed but can later be 'switched on' in a unique photographic scheme. The photographic properties of Ag{sub 2}Br{sub 6}(PPD){sub 2} are examined and show an extremely facile development rate owing to the fact that the developer molecules are within molecular proximity to the clusters. As a result of their molecular nature, we anticipate that such materials could enable conventional or completely new imaging technologies with very fast image access rates and very high resolution.

  7. Nanostructured Lanthanum Halides and CeBr3 for Nuclear Radiation and Detection

    SciTech Connect (OSTI)

    Paul Guss, Sanjoy Mukhopadhyay, Ron Guise, Ding Yuan

    2010-06-09

    Scintillator materials are used to detect, and in some cases identify, gamma rays. Higher performance scintillators are expensive, hard to manufacture, fragile, and sometimes require liquid nitrogen or cooling engines. But whereas lower-quality scintillators are cheap, easy to manufacture, and more rugged, their performance is lower. At issue: can the desirable qualities of high-and low-performance scintillators be combined to achieve better performance at lower cost? Preliminary experiments show that a LaF{sub 3}:Ce oleic acid-based nanocomposite exhibits a photopeak when exposed to {sup 137}Cs source gamma-radiation. The chemical synthesis of the cerium-doped lanthanum halide nanoparticles are scalable and large quantities of material can be produced at a time, unlike typical crystal growth processes such as the Bridgeman process. Using a polymer composite (Figure 1), produced by LANL, initial measurements of the unloaded and 8% LaF{sub 3}:Ce-loaded sample have been made using {sup 137}Cs sources. Figure 2 shows an energy spectrum acquired for CeF{sub 3}. The lighter plot is the measured polymer-only spectrum and the black plot is the spectrum from the nanocomposite scintillator. As the development of this material continues, the energy resolution is expected to improve and the photopeak-to-Compton ratio will become greater at higher loadings. These measurements show the expected Compton edge in the polymer-only sample, and the Compton edge and photo-peak expected in the nanophosphor composites that LANL has produced. Using a porous VYCORR with CdSe/ZnS core shell quantum dots, Letant has demonstrated that he has obtained signatures of the 241Am photopeak with energy resolution as good at NaI (Figure 3). We begin with the fact that CeBr{sub 3} crystals do not have a self-activity component as strong as the lanthanum halides. The radioactive 0.090% {sup 138}La component of lanthanum leads to significant self-activity, which will be a problem for very large detector volumes. Yet a significant strength of the nanostructure detector concept is the ability to create extremely large detector volumes by mixing nanoparticles into a transparent matrix. This would argue for use of nanoparticles other than lanthanum halides. Nanocomposites are easy to prepare; it is much less costly to use nanocomposites than to grow large whole crystals of these materials. The material can be fabricated at an industrial scale, further reducing cost. This material potentially offers the performance of $300/cc material (e.g., lanthanum bromide) at a cost of $1/cc. Because the material acts as a plastic, it is rugged and flexible, and can be made in large sheets, increasing the sensitivity of a detector using it. It would operate at ambient temperatures. Very large volumes of detector may be produced at greatly reduced cost, enhancing the non-proliferation posture of the nation for the same dollar value.

  8. Nashville Gas treads carefully to replace pipe

    SciTech Connect (OSTI)

    1997-06-01

    The private gas utility, Nashville Gas, was responsible for replacing damaged or inadequate 2- and 4-inch steel gas lines beneath Music City, USA. The line replacements required either size for size or upsizing. The first choice was directional drilling, which was quickly determined to be unpractical because of rocky soil conditions. The second option was open trenching. Undoubtedly, trenching would mean having to contend with angry residents and tourists, since gas lines ran beneath yards, mature trees, sidewalks, roadways, and railways. In addition to the negative social factors, trenching would require additional funds for substantial landscaping and pavement replacement. It at all possible, a no-dig alternative was desired. Nashville Gas found Grundomat piercing tools which create a bore, then pushes pipe back through it. These same tools can simultaneously pull in pipe. These tools were customized for the Nashville project.

  9. Wetting of Sodium on ??-Al2O3/YSZ Composites for Low Temperature Planar Sodium-Metal Halide Batteries

    SciTech Connect (OSTI)

    Reed, David M.; Coffey, Greg W.; Mast, Eric S.; Canfield, Nathan L.; Mansurov, Jirgal; Lu, Xiaochuan; Sprenkle, Vincent L.

    2013-04-01

    Wetting of Na on B-Al2O3/YSZ composites was investigated using the sessile drop technique. The effects of moisture and surface preparation were studied at low temperatures. Electrical conductivity of Na/B-Al2O3-YSZ/Na cells was also investigated at low temperatures and correlated to the wetting behavior. The use of planar B-Al2O3 substrates at low temperature with low cost polymeric seals is realized due to improved wetting at low temperature and conductivity values consistent with the literature.

  10. Valve assembly having remotely replaceable bearings

    DOE Patents [OSTI]

    Johnson, Evan R.; Tanner, David E.

    1980-01-01

    A valve assembly having remotely replaceable bearings is disclosed wherein a valve disc is supported within a flow duct for rotation about a pair of axially aligned bearings, one of which is carried by a spindle received within a diametral bore in the valve disc, and the other of which is carried by a bearing support block releasably mounted on the duct circumferentially of an annular collar on the valve disc coaxial with its diametrical bore. The spindle and bearing support block are adapted for remote removal to facilitate servicing or replacement of the valve disc support bearings.

  11. Supported molten-metal catalysts

    DOE Patents [OSTI]

    Datta, Ravindra; Singh, Ajeet; Halasz, Istvan; Serban, Manuela

    2001-01-01

    An entirely new class of catalysts called supported molten-metal catalysts, SMMC, which can replace some of the existing precious metal catalysts used in the production of fuels, commodity chemicals, and fine chemicals, as well as in combating pollution. SMMC are based on supporting ultra-thin films or micro-droplets of the relatively low-melting (<600.degree. C.), inexpensive, and abundant metals and semimetals from groups 1, 12, 13, 14, 15 and 16, of the periodic table, or their alloys and intermetallic compounds, on porous refractory supports, much like supported microcrystallites of the traditional solid metal catalysts. It thus provides orders of magnitude higher surface area than is obtainable in conventional reactors containing molten metals in pool form and also avoids corrosion. These have so far been the chief stumbling blocks in the application of molten metal catalysts.

  12. Evaluation Prompts ENERGY STAR Program to Replace Web Tool, Saving...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Prompts ENERGY STAR Program to Replace Web Tool, Saving 90 Percent of Annual Costs A ... program managers decided to drop the web tool, eventually replacing it with a ...

  13. Applications of molecular replacement to G protein-coupled receptors...

    Office of Scientific and Technical Information (OSTI)

    Applications of molecular replacement to G protein-coupled receptors Citation Details In-Document Search Title: Applications of molecular replacement to G protein-coupled receptors ...

  14. WPN 00-5: Approval of Replacement Refrigerators and Electric...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Provides states with the approval to include refrigerator and electric water heater replacements as an allowable measure. PDF icon WPN 00-5: Approval of Replacement Refrigerators ...

  15. Molecular replacement and model-building using distant homology...

    Office of Scientific and Technical Information (OSTI)

    Molecular replacement and model-building using distant homology models as templates Citation Details In-Document Search Title: Molecular replacement and model-building using...

  16. Replacement-2-A Wholesale Power Rate Schedule | Department of...

    Office of Environmental Management (EM)

    2-A Wholesale Power Rate Schedule Replacement-2-A Wholesale Power Rate Schedule Area: Replacement Energy System: Kerr-Philpott This rate schedule shall be available to public...

  17. Avoiding a Train Wreck: Replacing Old Coal Plants with Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Avoiding a Train Wreck: Replacing Old Coal Plants with Energy Efficiency, August 2011 Avoiding a Train Wreck: Replacing Old Coal Plants with Energy Efficiency, August 2011 This ...

  18. Virent is Replacing Crude Oil | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Virent is Replacing Crude Oil Virent is Replacing Crude Oil Breakout Session 2A-Conversion Technologies II: Bio-Oils, Sugar Intermediates, Precursors, Distributed Models, and ...

  19. Radiation-induced defects in GaN bulk grown by halide vapor phase epitaxy

    SciTech Connect (OSTI)

    Duc, Tran Thien; Pozina, Galia; Son, Nguyen Tien; Janzn, Erik; Hemmingsson, Carl; Ohshima, Takeshi

    2014-09-08

    Defects induced by electron irradiation in thick free-standing GaN layers grown by halide vapor phase epitaxy were studied by deep level transient spectroscopy. In as-grown materials, six electron traps, labeled D2 (E{sub C}0.24?eV), D3 (E{sub C}0.60?eV), D4 (E{sub C}0.69?eV), D5 (E{sub C}0.96?eV), D7 (E{sub C}1.19?eV), and D8, were observed. After 2?MeV electron irradiation at a fluence of 1??10{sup 14?}cm{sup ?2}, three deep electron traps, labeled D1 (E{sub C}0.12?eV), D5I (E{sub C}0.89?eV), and D6 (E{sub C}1.14?eV), were detected. The trap D1 has previously been reported and considered as being related to the nitrogen vacancy. From the annealing behavior and a high introduction rate, the D5I and D6 centers are suggested to be related to primary intrinsic defects.

  20. The nature of free-carrier transport in organometal halide perovskites

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hakamata, Tomoya; Shimamura, Kohei; Shimojo, Fuyuki; Kalia, Rajiv K.; Nakano, Aiichiro; Vashishta, Priya

    2016-01-19

    Organometal halide perovskites are attracting great attention as promising material for solar cells because of their high power conversion efficiency. The high performance has been attributed to the existence of free charge carriers and their large diffusion lengths, but the nature of carrier transport at the atomistic level remains elusive. Here, nonadiabatic quantum molecular dynamics simulations elucidate the mechanisms underlying the excellent free-carrier transport in CH3NH3PbI3. Pb and I sublattices act as disjunct pathways for rapid and balanced transport of photoexcited electrons and holes, respectively, while minimizing efficiency-degrading charge recombination. On the other hand, CH3NH3 sublattice quickly screens out electrostaticmore » electron-hole attraction to generate free carriers within 1 ps. Together this nano-architecture lets photoexcited electrons and holes dissociate instantaneously and travel far away to be harvested before dissipated as heat. As a result, this work provides much needed structure-property relationships and time-resolved information that potentially lead to rational design of efficient solar cells.« less

  1. Measure Guideline: Window Repair, Rehabilitation, and Replacement

    SciTech Connect (OSTI)

    Baker, P.

    2012-12-01

    This measure guideline provides information and guidance on rehabilitating, retrofitting, and replacing existing window assemblies in residential construction. The intent is to provide information regarding means and methods to improve the energy and comfort performance of existing wood window assemblies in a way that takes into consideration component durability, in-service operation, and long term performance of the strategies.

  2. A Guide to AC Motor Repair and Replacement

    SciTech Connect (OSTI)

    2004-03-01

    This booklet provides helpful information for making informed repair or replace decisions for electric motors.

  3. Metal aminoboranes

    DOE Patents [OSTI]

    Burrell, Anthony K.; Davis, Benjamin J.; Thorn, David L.; Gordon, John C.; Baker, R. Thomas; Semelsberger, Troy Allen; Tumas, William; Diyabalanage, Himashinie Vichalya Kaviraj; Shrestha, Roshan P.

    2010-05-11

    Metal aminoboranes of the formula M(NH.sub.2BH.sub.3).sub.n have been synthesized. Metal aminoboranes are hydrogen storage materials. Metal aminoboranes are also precursors for synthesizing other metal aminoboranes. Metal aminoboranes can be dehydrogenated to form hydrogen and a reaction product. The reaction product can react with hydrogen to form a hydrogen storage material. Metal aminoboranes can be included in a kit.

  4. Metal Hydrides

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Metal Hydrides Theodore Motyka Savannah River National Laboratory Metal Hydride System Architect Jose-Miguel Pasini, & Bart van Hassel UTRC Claudio Corgnale & Bruce Hardy SRNL ...

  5. Kinetics of ion-ion mutual neutralization: Halide anions with polyatomic cations

    SciTech Connect (OSTI)

    Shuman, Nicholas S.; Wiens, Justin P.; Miller, Thomas M.; Viggiano, Albert A.

    2014-06-14

    The binary mutual neutralization (MN) of a series of 17 cations (O{sub 2}{sup +}, NO{sup +}, NO{sub 2}{sup +}, CO{sup +}, CO{sub 2}{sup +}, Cl{sup +}, Cl{sub 2}{sup +}, SO{sub 2}{sup +}, CF{sub 3}{sup +}, C{sub 2}F{sub 5}{sup +}, NH{sub 3}{sup +}, H{sub 3}{sup +}, D{sub 3}{sup +}, H{sub 2}O{sup +}, H{sub 3}O{sup +}, ArH{sup +}, ArD{sup +}) with 3 halide anions (Cl{sup −}, Br{sup −}, I{sup −}) has been investigated in a flowing afterglow-Langmuir probe apparatus using the variable electron and neutral density attachment mass spectrometry technique. The MN rate constants of atom-atom reactions are dominated by the chemical nature of the system (i.e., the specific locations of curve crossings). As the number of atoms in the system increases, the MN rate constants become dominated instead by the physical nature of the system (e.g., the relative velocity of the reactants). For systems involving 4 or more atoms, the 300 K MN rate constants are well described by 2.7 × 10{sup −7} μ{sup −0.5}, where the reduced mass is in Da and the resulting rate constants in cm{sup 3} s{sup −1}. An upper limit to the MN rate constants appears well described by the complex potential model described by Hickman assuming a cross-section to neutralization of 11 000 Å{sup 2} at 300 K, equivalent to 3.5 × 10{sup −7} μ{sup −0.5}.

  6. Photoinduced electron transfer double fragmentation. An oxygen-mediated radical chain process in the cofragmentation of aminopinacol donors with organic halides

    SciTech Connect (OSTI)

    Chen, L.; Farahat, M.S.; Gan, H.; Whitten, D.G.; Farid, S. |

    1995-06-14

    We reprot an investigation in which excited states of amino pinacols 1-3 are reacted with the halides CCl{sub 4}, benzyl bromide, and p-cyanobenzyl bromide. Interesting results from this study include the finding that low-to-moderate quantum efficiencies for reaction are observed when the reactions are carried out under degassed conditions, indicating that the halide radical anions must survive long enough within the initial ion pair formed in the quenching step to undergo considerable return electron transfer. More strikingly we find that for certain pinacol-halide combinations reaction in aerared solutions leads to much higher efficiencies, which can be attributed to a chain reaction involving oxygen capture of a primary radical product. 25 refs., 1 fig., 1 tab.

  7. Europium-activated phosphors containing oxides of rare-earth and group-IIIB metals and method of making the same

    DOE Patents [OSTI]

    Comanzo, Holly Ann; Setlur, Anant Achyut; Srivastava, Alok Mani; Manivannan, Venkatesan

    2004-07-13

    Europium-activated phosphors comprise oxides of at least a rare-earth metal selected from the group consisting of gadolinium, yttrium, lanthanum, and combinations thereof and at least a Group-IIIB metal selected from the group consisting of aluminum, gallium, indium, and combinations thereof. A method for making such phosphors comprises adding at least a halide of at least one of the selected Group-IIIB metals in a starting mixture. The method further comprises firing the starting mixture in an oxygen-containing atmosphere. The phosphors produced by such a method exhibit improved absorption in the UV wavelength range and improved quantum efficiency.

  8. Europium-activated phosphors containing oxides of rare-earth and group-IIIB metals and method of making the same

    DOE Patents [OSTI]

    Comanzo, Holly Ann; Setlur, Anant Achyut; Srivastava, Alok Mani

    2006-04-04

    Europium-activated phosphors comprise oxides of at least a rare-earth metal selected from the group consisting of gadolinium, yttrium, lanthanum, and combinations thereof and at least a Group-IIIB metal selected from the group consisting of aluminum, gallium, indium, and combinations thereof. A method for making such phosphors comprises adding at least a halide of at least one of the selected Group-IIIB metals in a starting mixture. The method further comprises firing the starting mixture in an oxygen-containing atmosphere. The phosphors produced by such a method exhibit improved absorption in the UV wavelength range and improved quantum efficiency.

  9. Replaces DOE F 5120.2

    Energy Savers [EERE]

    700.2 (09-93) Replaces DOE F 5120.2 (02-90) edition may be used 1. INITIATOR: NAME & SIGNATURE ORGANIZATION CODE TELEPHONE NO. 2. PROJECT TITLE: 3. RESPONSIBLE ASSISTANT SECRETARY: 4. RESPONSIBLE OPERATIONS OFFICE: 5. M&O CONTRACTOR NAME: 6. WORK AUTHORIZATION NO.: FUNDS HEREBY AUTHORIZED 7. REVISION: B&R No. $000 13. WORK AUTHORIZED: (Brief description, schedule, results or products and reporting requirements, and any shifting of funds permitted within the work authorization): U.S.

  10. Metal inks

    DOE Patents [OSTI]

    Ginley, David S; Curtis, Calvin J; Miedaner, Alex; van Hest, Marinus Franciscus Antonius Maria; Kaydanova, Tatiana

    2014-02-04

    Self-reducing metal inks and systems and methods for producing and using the same are disclosed. In an exemplary embodiment, a method may comprise selecting metal-organic (MO) precursor, selecting a reducing agent, and dissolving the MO precursor and the reducing agent in an organic solvent to produce a metal ink that remains in a liquid phase at room temperature. Metal inks, including self-reducing and fire-through metal inks, are also disclosed, as are various applications of the metal inks.

  11. Evaluation Prompts ENERGY STAR Program to Replace Web Tool, Saving...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Prompts ENERGY STAR Program to Replace Web Tool, Saving 90 Percent of Annual Costs Evaluation Prompts ENERGY STAR Program to Replace Web Tool, Saving 90 Percent of Annual Costs ...

  12. California: SQAMD Replaces Drayage Trucks with CNG | Department...

    Energy Savers [EERE]

    California: SQAMD Replaces Drayage Trucks with CNG California: SQAMD Replaces Drayage Trucks with CNG November 6, 2013 - 12:00am Addthis In 2008, the South Coast Air Quality ...

  13. Method of removal of heavy metal from molten salt in IFR fuel pyroprocessing

    DOE Patents [OSTI]

    Gay, E.C.

    1995-10-03

    An electrochemical method is described for separating heavy metal values from a radioactive molten salt including Li halide at temperatures of about 500 C. The method comprises positioning a solid Li--Cd alloy anode in the molten salt containing the heavy metal values, positioning a Cd-containing cathode or a solid cathode positioned above a catch crucible in the molten salt to recover the heavy metal values, establishing a voltage drop between the anode and the cathode to deposit material at the cathode to reduce the concentration of heavy metals in the salt, and controlling the deposition rate at the cathode by controlling the current between the anode and cathode. 3 figs.

  14. Text-Alternative Version: LED Replacements for Linear Fluorescent Lamps

    Broader source: Energy.gov [DOE]

    Below is the text-alternative version of the "LED Replacements for Linear Fluorescent Lamps" webcast, held June 20, 2011.

  15. Silicone metalization

    DOE Patents [OSTI]

    Maghribi, Mariam N.; Krulevitch, Peter; Hamilton, Julie

    2008-12-09

    A system for providing metal features on silicone comprising providing a silicone layer on a matrix and providing a metal layer on the silicone layer. An electronic apparatus can be produced by the system. The electronic apparatus comprises a silicone body and metal features on the silicone body that provide an electronic device.

  16. Silicone metalization

    DOE Patents [OSTI]

    Maghribi, Mariam N.; Krulevitch, Peter; Hamilton, Julie

    2006-12-05

    A system for providing metal features on silicone comprising providing a silicone layer on a matrix and providing a metal layer on the silicone layer. An electronic apparatus can be produced by the system. The electronic apparatus comprises a silicone body and metal features on the silicone body that provide an electronic device.

  17. Metal-doped organic foam

    DOE Patents [OSTI]

    Rinde, James A.

    1982-01-01

    Organic foams having a low density and very small cell size and method for producing same in either a metal-loaded or unloaded (nonmetal loaded) form are described. Metal-doped foams are produced by soaking a polymer gel in an aqueous solution of desired metal salt, soaking the gel successively in a solvent series of decreasing polarity to remove water from the gel and replace it with a solvent of lower polarity with each successive solvent in the series being miscible with the solvents on each side and being saturated with the desired metal salt, and removing the last of the solvents from the gel to produce the desired metal-doped foam having desired density cell size, and metal loading. The unloaded or metal-doped foams can be utilized in a variety of applications requiring low density, small cell size foam. For example, rubidium-doped foam made in accordance with the invention has utility in special applications, such as in x-ray lasers.

  18. Alternatives to proposed replacement production reactors

    SciTech Connect (OSTI)

    Cullingford, H.S.

    1981-06-01

    To insure adequate supplies of plutonium and tritium for defense purposes, an independent evaluation was made by Los Alamos National Laboratory of the numerous alternatives to the proposed replacement production reactors (RPR). This effort concentrated on the defense fuel cycle operation and its technical implications in identifying the principal alternatives for the 1990s. The primary options were identified as (1) existing commercial reactors, (2) existing and planned government-owned facilities (not now used for defense materials production), and (3) other RPRs (not yet proposed) such as CANDU or CANDU-type heavy-water reactors (HWR) for both plutonium and tritium production. The evaluation considered features and differences of various options that could influence choice of RPR alternatives. Barring a change in the US approach to civilian and defense fuel cycles and precluding existing commercial reactors at government-owned sites, the most significant alternatives were identified as a CANDU-type HWR at Savannah River Plant (SRP) site or the Three Mile Island commercial reactor with reprocessing capability at Barnwell Nuclear Fuel Plant and at SRP.

  19. LED Replacements for Linear Fluorescent Lamps Webcast | Department of

    Energy Savers [EERE]

    Energy Replacements for Linear Fluorescent Lamps Webcast LED Replacements for Linear Fluorescent Lamps Webcast In this June 20, 2011 webcast on LED products marketed as replacements for linear fluorescent lamps, Jason Tuenge of the Pacific Northwest National Laboratory (PNNL) discussed current Lighting Facts-listed products as well as products evaluated in the latest CALiPER reports. Eric Richman, also of PNNL, reported on a recently completed GATEWAY demonstration project, in which LED and

  20. Building America Technology Solutions for New and Existing Homes: Replacing

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Resistance Heating with Mini-Split Heat Pumps | Department of Energy Replacing Resistance Heating with Mini-Split Heat Pumps Building America Technology Solutions for New and Existing Homes: Replacing Resistance Heating with Mini-Split Heat Pumps In this project, the Advanced Residential Integrated Solutions team investigated the suitability of mini-split heat pumps for multifamily retrofits. PDF icon Replacing Resistance Heating with Mini-Split Heat Pumps More Documents & Publications

  1. Replacement-1 Wholesale Power Rate Schedule | Department of Energy

    Energy Savers [EERE]

    Replacement-1 Wholesale Power Rate Schedule Replacement-1 Wholesale Power Rate Schedule Area: Replacement Energy System: Georgia-Alabama-South Carolina This rate schedule shall be available to public bodies and cooperatives (any one of whom is hereinafter called the Customer) in Georgia, Alabama, Mississippi, Florida, South Carolina, or North Carolina to whom power is provided pursuant to contracts between the Government and the Customer. This rate schedule shall be applicable to the sale at

  2. Optical amplifier operating at 1.3 microns useful for telecommunications and based on dysprosium-doped metal chloride host materials

    DOE Patents [OSTI]

    Page, Ralph H.; Schaffers, Kathleen I.; Payne, Stephen A.; Krupke, William F.; Beach, Raymond J.

    1997-01-01

    Dysprosium-doped metal chloride materials offer laser properties advantageous for use as optical amplifiers in the 1.3 .mu.m telecommunications fiber optic network. The upper laser level is characterized by a millisecond lifetime, the host material possesses a moderately low refractive index, and the gain peak occurs near 1.31 .mu.m. Related halide materials, including bromides and iodides, are also useful. The Dy.sup.3+ -doped metal chlorides can be pumped with laser diodes and yield 1.3 .mu.m signal gain levels significantly beyond those currently available.

  3. Optical amplifier operating at 1.3 microns useful for telecommunications and based on dysprosium-doped metal chloride host materials

    DOE Patents [OSTI]

    Page, R.H.; Schaffers, K.I.; Payne, S.A.; Krupke, W.F.; Beach, R.J.

    1997-12-02

    Dysprosium-doped metal chloride materials offer laser properties advantageous for use as optical amplifiers in the 1.3 {micro}m telecommunications fiber optic network. The upper laser level is characterized by a millisecond lifetime, the host material possesses a moderately low refractive index, and the gain peak occurs near 1.31 {micro}m. Related halide materials, including bromides and iodides, are also useful. The Dy{sup 3+}-doped metal chlorides can be pumped with laser diodes and yield 1.3 {micro}m signal gain levels significantly beyond those currently available. 9 figs.

  4. QUENCHING AND PARTITIONING PROCESS DEVELOPMENT TO REPLACE HOT...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    OF HIGH STRENGTH AUTOMOTIVE STEEL QUENCHING AND PARTITIONING PROCESS DEVELOPMENT TO REPLACE HOT STAMPING OF HIGH STRENGTH AUTOMOTIVE STEEL Colorado School of Mines - Golden, ...

  5. Quenching and Partitioning Process Development to Replace Hot...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Quenching and Partitioning Process Development to Replace Hot Stamping of High-Strength Automotive Steel Novel Steel Heat Treatment Process to Produce Third Generation AHSS ...

  6. Trim or Replace Impellers on Oversized Pumps | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    tip sheet discusses the reasoning behind trimming or replacing impellers on oversized pumps and describes how it works to improve pumping system efficiency. PUMPING SYSTEMS TIP ...

  7. LED T8 Replacement Lamps | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    PDF icon LED T8 Replacement Lamps (April 2010) More Documents & Publications Emerging Lighting Technology General Service LED Lamps Guiding Market Introduction of High-Performance ...

  8. New Feedstocks and Replacement Fuels - Future Energy for Mobility...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuels - Future Energy for Mobility New Feedstocks and Replacement Fuels - Future Energy for Mobility Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. ...

  9. Jordan Malheur Resource Area Jonesboro Diversion Dam Replacement...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The proposed replacement would help improve fish passage and facilitate continued ... the existing diversion dam to help improve fish passage and facilitate continued ...

  10. EA-1994: Malheur Resource Area Jonesboro Diversion Dam Replacement...

    Broader source: Energy.gov (indexed) [DOE]

    Burns Paiute Tribe for replacement of an existing diversion dam and installation of a fish passage structure. BPA's proposed action was to fund the project. PUBLIC COMMENT...

  11. "Green" Replacement for Industrial Applications of Polar Organic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search "Green" Replacement for Industrial Applications ... The lower volatility can lead to more energy intensive separation of the solvent; however, ...

  12. Magnesium Replacement of Aluminum Cast Components in a Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    to Effect Cost-Effective Mass Reduction Magnesium Replacement of Aluminum Cast Components in a Production V6 Engine to Effect Cost-Effective Mass Reduction Presentation given ...

  13. Replace Fossil Fuels, Final Technical Report Roberts, William...

    Office of Scientific and Technical Information (OSTI)

    Crude Glycerol as Cost-Effective Fuel for Combined Heat and Power to Replace Fossil Fuels, Final Technical Report Roberts, William L 09 BIOMASS FUELS biofuels, glycerin, glycerol,...

  14. Replacing an Oversized and Underloaded Electric Motor | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon Replacing an Oversized and Underloaded Electric Motor (September 1996) More Documents & Publications MotorMaster+ User Manual Buying an Energy-Efficient Electric Motor ...

  15. Window Replacement, Rehabilitation, & Repair Guides- Building America Top Innovation

    Broader source: Energy.gov [DOE]

    Building America team Building Science Corporation guides contractors through several options for repairing or replacing old windows to improve air sealing and thermal performance.

  16. Trim or Replace Impellers on Oversized Pumps

    SciTech Connect (OSTI)

    Not Available

    2006-09-01

    One in a series of tip sheets to help manufacturers optimize their industrial pumping systems. As a result of conservative engineering practices, pumps are often substantially larger than they need to be for an industrial plant's process requirements. Centrifugal pumps can often be oversized because of ''rounding up'', trying to accommodate gradual increases in pipe surface roughness and flow resistance over time, or anticipating future plant capacity expansions. In addition, the plant's pumping requirements might not have been clearly defined during the design phase. Because of this conservative approach, pumps can have operating points completely different from their design points. The pump head is often less than expected, while the flow rate is greater. This can cause cavitation and waste energy as the flow rate typically must be regulated with bypass or throttle control. Oversized and throttled pumps that produce excess pressure are excellent candidates for impeller replacement or ''trimming'', to save energy and reduce costs. Trimming involves machining the impeller to reduce its diameter. Trimming should be limited to about 75% of a pump's maximum impeller diameter, because excessive trimming can result in a mismatched impeller and casing. As the impeller diameter decreases, added clearance between the impeller and the fixed pump casing increases internal flow recirculation, causes head loss, and lowers pumping efficiency. For manufacturing standardization purposes, pump casings and shafts are designed to accommodate impellers in a range of sizes. Many pump manufacturers provide pump performance curves that indicate how various models will perform with different impeller diameters or trims. The impeller should not be trimmed any smaller than the minimum diameter shown on the curve. Net positive suction head requirements (NPSHR) usually decrease at lower flow rates and can increase at the higher end of the pump head curve. The NPSHR at a given flow rate will normally be greater with a smaller impeller, but engineers should consult with the pump manufacturer to determine variations in NPSHR before trimming the impeller. Manufacturers can often provide trim correction charts based on historical test data.

  17. Process for forming epitaxial perovskite thin film layers using halide precursors

    DOE Patents [OSTI]

    Clem, Paul G.; Rodriguez, Mark A.; Voigt, James A.; Ashley, Carol S.

    2001-01-01

    A process for forming an epitaxial perovskite-phase thin film on a substrate. This thin film can act as a buffer layer between a Ni substrate and a YBa.sub.2 Cu.sub.3 O.sub.7-x superconductor layer. The process utilizes alkali or alkaline metal acetates dissolved in halogenated organic acid along with titanium isopropoxide to dip or spin-coat the substrate which is then heated to about 700.degree. C. in an inert gas atmosphere to form the epitaxial film on the substrate. The YBCO superconductor can then be deposited on the layer formed by this invention.

  18. Metal oxide films on metal

    DOE Patents [OSTI]

    Wu, Xin D. (Los Alamos, NM); Tiwari, Prabhat (Los Alamos, NM)

    1995-01-01

    A structure including a thin film of a conductive alkaline earth metal oxide selected from the group consisting of strontium ruthenium trioxide, calcium ruthenium trioxide, barium ruthenium trioxide, lanthanum-strontium cobalt oxide or mixed alkaline earth ruthenium trioxides thereof upon a thin film of a noble metal such as platinum is provided.

  19. Enhanced open voltage of BiFeO{sub 3} polycrystalline film by surface modification of organolead halide perovskite

    SciTech Connect (OSTI)

    Zhao, Pengjun; Bian, Liang; Xu, Jinbao Chang, Aimin; Wang, Lei

    2014-07-07

    Inorganic-organolead halide perovskite CH{sub 3}NH{sub 3}PbI{sub 3} modified BiFeO{sub 3} polycrystalline film has been established. The composite photoelectrode presents much larger open voltage and several magnitudes superior photoelectric conversion performance in comparison to the ordinary BiFeO{sub 3} polycrystalline film. The I-V curve shows that the short-circuit current (J{sub sc}) is 1.74?mAcm{sup ?2} and open-circuit voltage (V{sub oc}) is 1.62?V, the device's photon to current efficiency is over 1%. The large open voltage and high photovoltaic efficiency is believed to attributed to the spontaneous polarization of composite perovskite induced by BiFeO{sub 3} lattice and modified reduced work function of the modified BiFeO{sub 3} surface. Our results clearly show that the present BiFeO{sub 3}-CH{sub 3}NH{sub 3}PbI{sub 3} planar device is capable to generate a large voltage in macro scale under visible light, leading an approach to further applications on photodetectors and optoelectronic switch.

  20. Resonance Raman and far-infrared studies of isotopically disordered and mixed-halide halogen-bridged platinum chain solids

    SciTech Connect (OSTI)

    Love, S.P.; Worl, L.A.; Donohoe, R.J.; Huckett, S.C.; Saxena, A.; Huang, X.Z.; Bishop, A.R.; Swanson, B.I.

    1992-12-31

    The MX chain solids [Pt(en){sub 2}][Pt(en){sub 2}X{sub 2}](CIO{sub 4}){sub 4}, (en = C{sub 2}H{sub 8}N{sub 2} and X=Cl, Br), referred to as ``PtX,`` are used to explore some of the surprising spectral consequences of disorder in 1-D systems, first for pure PtCl, where the disorder arises from randomly distributed Cl isotopes, then for the more drastic case of the mixed-halide materials PtCl{sub 1minusx}Br{sub x}. Lattice dynamics and Peierls-Hubbard modelling are used to analyze the observed spectral behavior. In both cases, the complex structure seen in the Raman and IR spectra is found to arise from strongly localized vibrational modes residing on chain segments, defined by sequences of Cl isotopes for PtCl, and by sequences of Cl and Br for PtCl{sub 1minusx}Br{sub x}. 4 figs, 8 refs.

  1. Dendritic metal nanostructures

    DOE Patents [OSTI]

    Shelnutt, John A.; Song, Yujiang; Pereira, Eulalia F.; Medforth, Craig J.

    2010-08-31

    Dendritic metal nanostructures made using a surfactant structure template, a metal salt, and electron donor species.

  2. Replacing 16 mm film cameras with high definition digital cameras

    SciTech Connect (OSTI)

    Balch, K.S.

    1995-12-31

    For many years 16 mm film cameras have been used in severe environments. These film cameras are used on Hy-G automotive sleds, airborne gun cameras, range tracking and other hazardous environments. The companies and government agencies using these cameras are in need of replacing them with a more cost effective solution. Film-based cameras still produce the best resolving capability, however, film development time, chemical disposal, recurring media cost, and faster digital analysis are factors influencing the desire for a 16 mm film camera replacement. This paper will describe a new camera from Kodak that has been designed to replace 16 mm high speed film cameras.

  3. REQUEST FOR LOST/STOLEN BADGE REPLACEMENT | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    REQUEST FOR LOST/STOLEN BADGE REPLACEMENT REQUEST FOR LOST/STOLEN BADGE REPLACEMENT Form documents the circumstances surrounding the loss of the security badge, i.e., the date the badge was Iost/stolen, location where the badge may have been Iost/stolen, attempts to find the lost badge, etc. PDF icon REQUEST FOR LOST/STOLEN BADGE REPLACEMENT More Documents & Publications DOE HQ F 473.1 (fillable pdf) DOE F 5639.2 DOE F 5634.1

  4. Pacific Power - FinAnswer Express | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    35 Pulse Start Metal Halide Fixtures: 60 Pulse Start Metal Halide Ballast: 20 Induction Fixtures: 125unit LED Screw InRecessed Downlight: 10 LED OutdoorRoadway...

  5. Reminder: Y-12 Public Warning Siren System being replaced, tested...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    located around the Oak Ridge area is being replaced this month with a test of the new system on Sept. 26. The vendor, American Signal, will be testing the sirens Sept. 26...

  6. Replace Pressure-Reducing Valves with Backpressure Turbogenerators

    SciTech Connect (OSTI)

    Not Available

    2006-01-01

    This revised ITP steam tip sheet on replacing pressure-reducing valves provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  7. EA-0923: Winnett School District Boiler Replacement Project, Winnett, Montana

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of the proposal to replace the Winnett School District complex's existing oil-fired heating system with a new coal-fired heating system with funds...

  8. Ultrasound image guided acetabular implant orientation during total hip replacement

    DOE Patents [OSTI]

    Chang, John; Haddad, Waleed; Kluiwstra, Jan-Ulco; Matthews, Dennis; Trauner, Kenneth

    2003-08-19

    A system for assisting in precise location of the acetabular implant during total hip replacement. The system uses ultrasound imaging for guiding the placement and orientation of the implant.

  9. Washington State Department of Ecology: Replacement Wells Requiring...

    Open Energy Info (EERE)

    Ecology: Replacement Wells Requiring a Water Right Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- OtherOther: Washington State Department of...

  10. Laboratory Evaluation of LED T8 Replacement Lamp Products

    SciTech Connect (OSTI)

    Richman, Eric E.; Kinzey, Bruce R.; Miller, Naomi J.

    2011-05-23

    A report on a lab setting analysis involving LED lamps intended to directly replace T8 fluorescent lamps (4') showing light output, power, and economic comparisons with other fluorescent options.

  11. Replace Pressure-Reducing Valves with Backpressure Turbogenerators...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    This tip sheet on replacing pressure-reducing valves provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies. STEAM TIP SHEET ...

  12. Dry halide method for separating the components of spent nuclear fuels

    DOE Patents [OSTI]

    Christian, Jerry Dale; Thomas, Thomas Russell; Kessinger, Glen F.

    1998-01-01

    The invention is a nonaqueous, single method for processing multiple spent nuclear fuel types by separating the fission- and transuranic products from the nonradioactive and fissile uranium product. The invention has four major operations: exposing the spent fuels to chlorine gas at temperatures preferably greater than 1200.degree. C. to form volatile metal chlorides; removal of the fission product chlorides, transuranic product chlorides, and any nickel chloride and chromium chloride in a molten salt scrubber at approximately 400.degree. C.; fractional condensation of the remaining volatile chlorides at temperatures ranging from 164.degree. C. to 2.degree. C.; and regeneration and recovery of the transferred spent molten salt by vacuum distillation. The residual fission products, transuranic products, and nickel- and chromium chlorides are converted to fluorides or oxides for vitrification. The method offers the significant advantages of a single, compact process that is applicable to most of the diverse nuclear fuels, minimizes secondary wastes, segregates fissile uranium from the high level wastes to resolve potential criticality concerns, segregates nonradioactive wastes from the high level wastes for volume reduction, and produces a common waste form glass or glass-ceramic.

  13. Dry halide method for separating the components of spent nuclear fuels

    DOE Patents [OSTI]

    Christian, J.D.; Thomas, T.R.; Kessinger, G.F.

    1998-06-30

    The invention is a nonaqueous, single method for processing multiple spent nuclear fuel types by separating the fission and transuranic products from the nonradioactive and fissile uranium product. The invention has four major operations: exposing the spent fuels to chlorine gas at temperatures preferably greater than 1200 C to form volatile metal chlorides; removal of the fission product chlorides, transuranic product chlorides, and any nickel chloride and chromium chloride in a molten salt scrubber at approximately 400 C; fractional condensation of the remaining volatile chlorides at temperatures ranging from 164 to 2 C; and regeneration and recovery of the transferred spent molten salt by vacuum distillation. The residual fission products, transuranic products, and nickel- and chromium chlorides are converted to fluorides or oxides for vitrification. The method offers the significant advantages of a single, compact process that is applicable to most of the diverse nuclear fuels, minimizes secondary wastes, segregates fissile uranium from the high level wastes to resolve potential criticality concerns, segregates nonradioactive wastes from the high level wastes for volume reduction, and produces a common waste form glass or glass-ceramic. 3 figs.

  14. Exploring the speed and performance of molecular replacement with AMPLE

    Office of Scientific and Technical Information (OSTI)

    using QUARK ab initio protein models (Journal Article) | SciTech Connect Exploring the speed and performance of molecular replacement with AMPLE using QUARK ab initio protein models Citation Details In-Document Search Title: Exploring the speed and performance of molecular replacement with AMPLE using QUARK ab initio protein models Two ab initio modelling programs solve complementary sets of targets, enhancing the success of AMPLE with small proteins. AMPLE clusters and truncates ab initio

  15. Biomass 2011: Replace the Whole Barrel, Supply the Whole Market |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 1: Replace the Whole Barrel, Supply the Whole Market Biomass 2011: Replace the Whole Barrel, Supply the Whole Market The New Horizons of Bioenergy Biomass 2011 July 26-27, 2011 Gaylord National Resort and Convention Center 201 Waterfront Street National Harbor, MD 20745 Thank you to everyone who attended and participated to help make Biomass 2011 a remarkable success. More than 600 speakers, moderators, sponsors, exhibitors, and attendees were able to listen to

  16. Metal hydrides

    SciTech Connect (OSTI)

    Carnes, J.R.; Kherani, N.P.

    1987-11-01

    Metal hydride information is not available for most hydrides in a consolidated quick-reference source. This report's objective is to fill the need for such a document providing basic thermodynamic data for as many metal hydrides as possible. We conduced a computerized library search to access as many sources as possible and screened each source for such thermodynamic data as pressure-temperature graphs, van't Hoff curves, and impurity effects. We included any other relevant information and commented on it. A primary concern to be investigated in the future is the behavior of metal tritides. This would be important in the area of emergency tritium cleanup systems. The hydride graphs are useful, however, as tritides may be expected in most cases to behave similarly and at least follow trends of their respective hydrides. 42 refs., 40 figs., 5 tabs.

  17. METAL COMPOSITIONS

    DOE Patents [OSTI]

    Seybolt, A.U.

    1959-02-01

    Alloys of uranium which are strong, hard, and machinable are presented, These alloys of uranium contain bctween 0.1 to 5.0% by weight of at least one noble metal such as rhodium, palladium, and gold. The alloys may be heat treated to obtain a product with iniproved tensile and compression strengths,

  18. Comparison of small photon beams measured using radiochromic and silver-halide films in solid water phantoms

    SciTech Connect (OSTI)

    Zeidan, Omar A.; Li, Jonathan G.; Low, Daniel A.; Dempsey, James F.

    2004-10-01

    In this study, we compared the dosimetric properties of four of the most commonly used films for megavoltage photon-beam dosimetry when irradiated under identical conditions by small multileaf-collimator (MLC) defined beamlets. Two silver-halide films (SHFs), Kodak XV2 and EDR2, and two radiochromic films (RCFs), Gafchromic HS and MD55-2, were irradiated by MLC-defined 1x1 cm{sup 2} beamlets from a Varian 2100 C/D linac equipped with a 120-leaf MLC. The beamlets were delivered with the accelerator gantry set laterally (90 deg. rotation) upon a solid-water compression film phantom at 100 cm source-to-surface distance which was positioned with the films parallel to the beam axis. Beamlets were delivered at central axis, 5.0 cm, and 10.5 cm off-axis for both leaf-end and leaf-side defined beamlets. The film dosimetry was performed using a quantitative optical density (OD) imaging system that was validated in a previous study. No significant differences between SHF and RCF measurements were observed in percentage depth doses, horizontal depth profiles, or two-dimension spatial isodose distributions in both the central axis and off-axis measurements. We found that regardless of the type of film used, RCF or SHF, a consistent data set for small beam dose modeling was generated. Previous validation studies based on the use of RCF and OD imaging system would indicate that all film produce an accurate result for small beam characterization.

  19. Liquid ash corrosion, remaining life estimation and superheater/reheater replacement strategy in coal fired boilers

    SciTech Connect (OSTI)

    Alice, J.A.; Janiszewski, J.A.

    1985-01-01

    The liquid ash corrosion of superheater and reheater tubing in coal fired boilers is commonly accepted to be caused by the action of liquid sodium and potassium iron trisulfates Na/sub 3/Fe(SO/sub 4/) and K/sub 3/Fe(SO/sub 4/)/sub 3/. These species melt at temperatures between 1030/sup 0/F and 1160/sup 0/F (555-625/sup 0/C) depending on the relative amounts of sodium and potassium. Rapid tube wastage begins when the tube metal temperature reaches the trisulfate melting point. The key to improved availability in fossil boilers is to identify and replace, during a planned outage, tubes which are likely to fail before the next planned outage. The authors have developed a computerized method for estimating the remaining life of superheater/reheater tubes based on accelerated liquid ash corrosion. The scheme of analysis employs the following logic: (1) measurement of tube wastage from several removed samples, (2) estimation of tube metal temperature from I.D. scale thickness and thermocouple data, (3) estimation of trisulfate melting point from chemical analysis of the ash deposit and (4) using the computer model to calculate remaining life as a function of tube wastage rate metal temperature. The practical application of this strategy is presented for a coal fired boiler in the GPU system.

  20. Composite metal membrane

    DOE Patents [OSTI]

    Peachey, N.M.; Dye, R.C.; Snow, R.C.; Birdsell, S.A.

    1998-04-14

    A composite metal membrane including a first metal layer of Group IVB met or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof is provided together with a process for the recovery of hydrogen from a gaseous mixture including contacting a hydrogen-containing gaseous mixture with a first side of a nonporous composite metal membrane including a first metal of Group IVB metals or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof, and, separating hydrogen from a second side of the nonporous composite metal membrane.

  1. Composite metal membrane

    DOE Patents [OSTI]

    Peachey, Nathaniel M.; Dye, Robert C.; Snow, Ronny C.; Birdsell, Stephan A.

    1998-01-01

    A composite metal membrane including a first metal layer of Group IVB met or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof is provided together with a process for the recovery of hydrogen from a gaseous mixture including contacting a hydrogen-containing gaseous mixture with a first side of a nonporous composite metal membrane including a first metal of Group IVB metals or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof, and, separating hydrogen from a second side of the nonporous composite metal membrane.

  2. Magnetic Transitions in Iron Porphyrin Halides by Inelastic Neutron Scattering and Ab-initio Studies of Zero-Field Splittings

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stavretis, Shelby E.; Atanasov, Mihail; Podlesnyak, Andrey A.; Hunter, Seth C.; Neese, Frank; Xue, Zi-Ling

    2015-10-02

    Zero-field splitting (ZFS) parameters of nondeuterated metalloporphyrins [Fe(TPP)X] (X = F, Br, I; H2TPP = tetraphenylporphyrin) are determined by inelastic neutron scattering (INS). The ZFS values are D = 4.49(9) cm–1 for tetragonal polycrystalline [Fe(TPP)F], and D = 8.8(2) cm–1, E = 0.1(2) cm–1 and D = 13.4(6) cm–1, E = 0.3(6) cm–1 for monoclinic polycrystalline [Fe(TPP)Br] and [Fe(TPP)I], respectively. Along with our recent report of the ZFS value of D = 6.33(8) cm–1 for tetragonal polycrystalline [Fe(TPP)Cl], these data provide a rare, complete determination of ZFS parameters in a metalloporphyrin halide series. The electronic structure of [Fe(TPP)X] (X =more » F, Cl, Br, I) has been studied by multireference ab initio methods: the complete active space self-consistent field (CASSCF) and the N-electron valence perturbation theory (NEVPT2) with the aim of exploring the origin of the large and positive zero-field splitting D of the 6A1 ground state. D was calculated from wave functions of the electronic multiplets spanned by the d5 configuration of Fe(III) along with spin–orbit coupling accounted for by quasi degenerate perturbation theory. Results reproduce trends of D from inelastic neutron scattering data increasing in the order from F, Cl, Br, to I. A mapping of energy eigenvalues and eigenfunctions of the S = 3/2 excited states on ligand field theory was used to characterize the σ- and π-antibonding effects decreasing from F to I. This is in agreement with similar results deduced from ab initio calculations on CrX63- complexes and also with the spectrochemical series showing a decrease of the ligand field in the same directions. A correlation is found between the increase of D and decrease of the π- and σ-antibonding energies eλX (λ = σ, π) in the series from X = F to I. Analysis of this correlation using second-order perturbation theory expressions in terms of angular overlap parameters rationalizes the experimentally deduced trend. Furthermore, D parameters from CASSCF and NEVPT2 results have been calibrated against those from the INS data, yielding a predictive power of these approaches. Methods to improve the quantitative agreement between ab initio calculated and experimental D and spectroscopic transitions for high-spin Fe(III) complexes are proposed.« less

  3. Metal dusting

    SciTech Connect (OSTI)

    Edited by K. Natesan

    2004-01-01

    This workshop was held soon after the September 11th incident under a climate of sorrow and uncertainty among the people of the world, in particular the Workshop participants and their host organizations. With considerable help from the partiicpants, the Workshop was conducted as planed and we had excellent participation in spite of the circumstances. A good fraction of the attendees in the Workshop were from abroad and from several industries, indicating the importance and relevance of the subject for the chemical process industry. Degradation of structural metallic alloys by metal dusting has been an issue for over 40 years in the chemical, petrochemical, syngas, and iron ore reduction plants. However, the fundamental scientific reasons for the degradation of complex alloys in high carbon activity environments are not clear. one of the major parameters of importance is the variation in gas chemistry in both the laboratory experiments and in the plant-service environments. the industry has questioned the applicability of the laboratory test data, obtained in low steam environments, in assessment and life prediction for the materials in plant service where the environments contain 25-35% steam. Several other variables such as system pressure, gas flow velocity, incubation time, alloy chemistry, surface finish, and weldments, were also identified in the literature as to having an effect on the initiatino and propagation of metal dusting attack. It is the purpose of this Workshop to establish a forum in which the researchers from scientific and industrial laboratories, alloy manufacturers, end users, and research and development sponsors can exchange information, discuss different points of view, prioritize the issues, and to elaborate on the trends in industry for the future. We believe that we accomplished these goals successfully and sincerely thank the participants for their contributions.

  4. Replacing the whole barrel of oil with plants and microbes

    ScienceCinema (OSTI)

    Simmons, Blake

    2014-06-24

    In this May 13, 2013 talk, Blake Simmons discusses how scientists are exploring how plants and microbes can be used to replace many of the everyday goods we use that are derived from petroleum. To watch the entire entire Science at the Theater event, in which seven of our scientists present BIG ideas in eight minutes each.

  5. Measure Guideline. Wood Window Repair, Rehabilitation, and Replacement

    SciTech Connect (OSTI)

    Baker, P.; Eng, P.

    2012-12-01

    This measure guideline provides information and guidance on rehabilitating, retrofitting, and replacing existing window assemblies in residential construction. The intent is to provide information regarding means and methods to improve the energy and comfort performance of existing wood window assemblies in a way that takes into consideration component durability, in-service operation, and long term performance of the strategies.

  6. Selection and Implementation of a Replacement Cutting Tool Selection Application

    SciTech Connect (OSTI)

    Rice, Gordon

    2008-10-06

    A new commercial cutting tool software package replaced an internally created legacy system. This report describes the issues that surfaced during the migration and installation of the commercial package and the solutions employed. The primary issues discussed are restructuring the data between two drastically different database schemas and the creation of individual component graphics.

  7. HVAC & Building Management Control System Energy Efficiency Replacements

    SciTech Connect (OSTI)

    Hernandez, Adriana

    2012-09-21

    The project objective was the replacement of an aging, un-repairable HVAC system which has grown inefficient and a huge energy consumer with low energy and efficient HVAC units, and installation of energy efficient building control technologies at City's YMCA Community Center.

  8. Replacing the whole barrel of oil with plants and microbes

    SciTech Connect (OSTI)

    Simmons, Blake

    2013-05-29

    In this May 13, 2013 talk, Blake Simmons discusses how scientists are exploring how plants and microbes can be used to replace many of the everyday goods we use that are derived from petroleum. To watch the entire entire Science at the Theater event, in which seven of our scientists present BIG ideas in eight minutes each.

  9. Replacement of alloy 800H superheated steam line

    SciTech Connect (OSTI)

    Barbier, R.A.; Bullock, J.W. [Sterling Chemicals, Texas City, TX (United States)

    1996-07-01

    Sterling Chemicals utilizes alloy 800HT (UNS N08811) piping for superheated steam service in its styrene dehydrogenation unit. An engineering project to replace these lines was recently completed. Material acquisition, shop fabrication, inspection requirements, and field erection will be highlighted in this paper.

  10. CALiPER Exploratory Study Retail Replacement Lamps – 2011

    SciTech Connect (OSTI)

    2012-04-02

    In 2010, CALiPER conducted a study on LED replacement lamps found in retail stores. The results were less than satisfactory, and many products were classified as being unlikely to meet consumer expectations. In November 2011, CALiPER purchased a new sample of products for a follow-up study, with the intent of characterizing the progress of this essential market segment.

  11. CALiPER Special Summary Report: Retail Replacement Lamp Testing

    SciTech Connect (OSTI)

    2011-04-01

    CALiPER testing has evaluated many products for commercial lighting markets and found some excellent performers. However, many of these are not available on the retail market. This special testing was undertaken to identify and test solid-state lighting (SSL) replacement lamp products that are available to the general public through retail stores and websites.

  12. ARP/wARP and molecular replacement: the next generation

    SciTech Connect (OSTI)

    Cohen, Serge X. Ben Jelloul, Marouane; Long, Fei; Vagin, Alexei; Knipscheer, Puck; Lebbink, Joyce; Sixma, Titia K.; Lamzin, Victor S.; Murshudov, Garib N.; Perrakis, Anastassis

    2008-01-01

    A systematic test shows how ARP/wARP deals with automated model building for structures that have been solved by molecular replacement. A description of protocols in the flex-wARP control system and studies of two specific cases are also presented. Automatic iterative model (re-)building, as implemented in ARP/wARP and its new control system flex-wARP, is particularly well suited to follow structure solution by molecular replacement. More than 100 molecular-replacement solutions automatically solved by the BALBES software were submitted to three standard protocols in flex-wARP and the results were compared with final models from the PDB. Standard metrics were gathered in a systematic way and enabled the drawing of statistical conclusions on the advantages of each protocol. Based on this analysis, an empirical estimator was proposed that predicts how good the final model produced by flex-wARP is likely to be based on the experimental data and the quality of the molecular-replacement solution. To introduce the differences between the three flex-wARP protocols (keeping the complete search model, converting it to atomic coordinates but ignoring atom identities or using the electron-density map calculated from the molecular-replacement solution), two examples are also discussed in detail, focusing on the evolution of the models during iterative rebuilding. This highlights the diversity of paths that the flex-wARP control system can employ to reach a nearly complete and accurate model while actually starting from the same initial information.

  13. Mechanochemical processing for metals and metal alloys

    DOE Patents [OSTI]

    Froes, Francis H.; Eranezhuth, Baburaj G.; Prisbrey, Keith

    2001-01-01

    A set of processes for preparing metal powders, including metal alloy powders, by ambient temperature reduction of a reducible metal compound by a reactive metal or metal hydride through mechanochemical processing. The reduction process includes milling reactants to induce and complete the reduction reaction. The preferred reducing agents include magnesium and calcium hydride powders. A process of pre-milling magnesium as a reducing agent to increase the activity of the magnesium has been established as one part of the invention.

  14. Submicron patterned metal hole etching

    DOE Patents [OSTI]

    McCarthy, Anthony M.; Contolini, Robert J.; Liberman, Vladimir; Morse, Jeffrey

    2000-01-01

    A wet chemical process for etching submicron patterned holes in thin metal layers using electrochemical etching with the aid of a wetting agent. In this process, the processed wafer to be etched is immersed in a wetting agent, such as methanol, for a few seconds prior to inserting the processed wafer into an electrochemical etching setup, with the wafer maintained horizontal during transfer to maintain a film of methanol covering the patterned areas. The electrochemical etching setup includes a tube which seals the edges of the wafer preventing loss of the methanol. An electrolyte composed of 4:1 water: sulfuric is poured into the tube and the electrolyte replaces the wetting agent in the patterned holes. A working electrode is attached to a metal layer of the wafer, with reference and counter electrodes inserted in the electrolyte with all electrodes connected to a potentiostat. A single pulse on the counter electrode, such as a 100 ms pulse at +10.2 volts, is used to excite the electrochemical circuit and perform the etch. The process produces uniform etching of the patterned holes in the metal layers, such as chromium and molybdenum of the wafer without adversely effecting the patterned mask.

  15. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Trending: Metal Oxo Bonds Trending: Metal Oxo Bonds Print Wednesday, 29 May 2013 00:00 Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides

  16. Metal filled porous carbon

    DOE Patents [OSTI]

    Gross, Adam F.; Vajo, John J.; Cumberland, Robert W.; Liu, Ping; Salguero, Tina T.

    2011-03-22

    A porous carbon scaffold with a surface and pores, the porous carbon scaffold containing a primary metal and a secondary metal, where the primary metal is a metal that does not wet the surface of the pores of the carbon scaffold but wets the surface of the secondary metal, and the secondary metal is interspersed between the surface of the pores of the carbon scaffold and the primary metal.

  17. Extracting metals directly from metal oxides

    DOE Patents [OSTI]

    Wai, Chien M.; Smart, Neil G.; Phelps, Cindy

    1997-01-01

    A method of extracting metals directly from metal oxides by exposing the oxide to a supercritical fluid solvent containing a chelating agent is described. Preferably, the metal is an actinide or a lanthanide. More preferably, the metal is uranium, thorium or plutonium. The chelating agent forms chelates that are soluble in the supercritical fluid, thereby allowing direct removal of the metal from the metal oxide. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of .beta.-diketones, halogenated .beta.-diketones, phosphinic acids, halogenated phosphinic acids, carboxylic acids, halogenated carboxylic acids, and mixtures thereof. In especially preferred embodiments, at least one of the chelating agents is fluorinated. The method provides an environmentally benign process for removing metals from metal oxides without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the metal recovered, to provide an economic, efficient process.

  18. Extracting metals directly from metal oxides

    DOE Patents [OSTI]

    Wai, C.M.; Smart, N.G.; Phelps, C.

    1997-02-25

    A method of extracting metals directly from metal oxides by exposing the oxide to a supercritical fluid solvent containing a chelating agent is described. Preferably, the metal is an actinide or a lanthanide. More preferably, the metal is uranium, thorium or plutonium. The chelating agent forms chelates that are soluble in the supercritical fluid, thereby allowing direct removal of the metal from the metal oxide. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of {beta}-diketones, halogenated {beta}-diketones, phosphinic acids, halogenated phosphinic acids, carboxylic acids, halogenated carboxylic acids, and mixtures thereof. In especially preferred embodiments, at least one of the chelating agents is fluorinated. The method provides an environmentally benign process for removing metals from metal oxides without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the metal recovered, to provide an economic, efficient process. 4 figs.

  19. Measure Guideline: Air Conditioner Diagnostics, Maintenance, and Replacement

    SciTech Connect (OSTI)

    Springer, D.; Dakin, B.

    2013-03-01

    This guideline responds to the need for an efficient means of identifying, diagnosing, and repairing faults in air conditioning systems in existing homes that are undergoing energy upgrades. Inadequate airflow due to constricted ducts or undersized filters, improper refrigerant charge, and other system defects can be corrected at a fraction of the cost of equipment replacement and can yield significant savings. The guideline presents a two-step approach to diagnostics and repair.

  20. Measure Guideline. Air Conditioner Diagnostics, Maintenance, and Replacement

    SciTech Connect (OSTI)

    Springer, David; Dakin, Bill

    2013-03-01

    This guideline responds to the need for an efficient means of identifying, diagnosing, and repairing faults in air conditioning systems in existing homes that are undergoing energy upgrades. Inadequate airflow due to constricted ducts or undersized filters, improper refrigerant charge, and other system defects can be corrected at a fraction of the cost of equipment replacement and can yield significant savings. The guideline presents a two-step approach to diagnostics and repair.

  1. OSRAM SYLVANIA Develops High-Efficiency LED Troffer Replacement

    Broader source: Energy.gov [DOE]

    With the help of DOE funding, OSRAM SYLVANIA is developing a high-efficiency LED 2'x2' troffer replacement that is expected to be commercially available in the spring of 2012 and to be cost-competitive with existing troffers of that size. It is projected to have a light output of up to 4,000 lumens, an efficacy of more than 100 lm/W, and a CCT of 3500K.

  2. Magnetic Nanoparticle Capilary Flow as a Replacement for Lateral Flow

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chromatography - Energy Innovation Portal Magnetic Nanoparticle Capilary Flow as a Replacement for Lateral Flow Chromatography Colorado School of Mines Contact CSM About This Technology Technology Marketing SummaryThis invention looks at method to detect targeted analytes. DescriptionThe method most often used now is Lateral Flow Chromatography (LFC) which has many drawbacks including: the need for extensive optimization, sensitivity, specificity, lack of quantitative data and extensive

  3. Polypeptide having an amino acid replaced with N-benzylglycine

    DOE Patents [OSTI]

    Mitchell, Alexander R.; Young, Janis D.

    1996-01-01

    The present invention relates to one or more polypeptides having useful biological activity in a mammal, which comprise: a polypeptide related to bradykinin of four to ten amino acid residues wherein one or more specific amino acids in the polypeptide chain are replaced with achiral N-benzylglycine. These polypeptide analogues have useful potent agonist or antagonist pharmacological properties depending upon the structure. A preferred polypeptide is (N-benzylglycine.sup.7)-bradykinin.

  4. Metal-phosphate binders

    DOE Patents [OSTI]

    Howe, Beth Ann [Lewistown, IL; Chaps-Cabrera, Jesus Guadalupe [Coahuila, MX

    2009-05-12

    A metal-phosphate binder is provided. The binder may include an aqueous phosphoric acid solution, a metal-cation donor including a metal other than aluminum, an aluminum-cation donor, and a non-carbohydrate electron donor.

  5. Demonstration Assessment of Light-Emitting Diode (LED) Post-Top Lighting at Central Park in New York City

    SciTech Connect (OSTI)

    Myer, Michael; Goettel, Russell T.; Kinzey, Bruce R.

    2012-09-30

    A review of five post-top light-emitting diode (LED) pedestrian luminaires installed in New York City's Central Park for possible replacement to the existing metal halide post-top luminaire. This report reviews the energy savings potential and lighting delivered by the LED post-top luminaires.

  6. GATEWAY Demonstrations: Trial Demonstration of Area Lighting Retrofit, Yuma Border Patrol, Yuma, Arizona

    SciTech Connect (OSTI)

    Wilkerson, A. M.; McCullough, J. J.

    2014-12-31

    Along the Yuma Sector Border Patrol Area in Yuma, Arizona, the GATEWAY program conducted a trial demonstration in which the incumbent quartz metal halide area lighting was replaced with LED at three pole locations at the Yuma Sector Border Patrol Area in Yuma, Arizona. The retrofit was documented to better understand LED technology performance in high-temperature environments.

  7. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide

  8. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide

  9. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide

  10. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide

  11. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide

  12. REFRACTORY METAL TUBE DRAWING

    DOE Patents [OSTI]

    Bean, C.H.; Karasek, F.J.

    1963-01-29

    A lubricant for drawing Zr and other refractory metals is described. Metallic Cu powder is added to a solution of acrylic resin in chlorinated hydrocarbon solvent. (AEC)

  13. Method and making group IIB metal - telluride films and solar cells

    DOE Patents [OSTI]

    Basol, Bulent M.; Kapur, Vijay K.

    1990-08-21

    A technique is disclosed forming thin films (13) of group IIB metal-telluride, such as Cd.sub.x Zn.sub.1-x Te (0.ltoreq.x.ltoreq.1), on a substrate (10) which comprises depositing Te (18) and at least one of the elements (19) of Cd, Zn, and Hg onto a substrate and then heating the elements to form the telluride. A technique is also provided for doping this material by chemically forming a thin layer of a dopant on the surface of the unreacted elements and then heating the elements along with the layer of dopant. A method is disclosed of fabricating a thin film photovoltaic cell which comprises depositing Te and at least one of the elements of Cd, Zn, and Hg onto a substrate which contains on its surface a semiconductor film (12) and then heating the elements in the presence of a halide of the Group IIB metals, causing the formation of solar cell grade Group IIB metal-telluride film and also causing the formation of a rectifying junction, in situ, between the semiconductor film on the substrate and the Group IIB metal-telluride layer which has been formed.

  14. Polymer filtration: An emerging technology for selective metals recovery

    SciTech Connect (OSTI)

    Smith, B.F.; Robison, T.W.; Cournoyer, M.E.

    1995-12-31

    A new technology is under development to selectively recover regulated metal ions from electroplating rinse waters. The electroplating metal ions are recovered in a concentrated form with the appropriate counter ions ready for return to the original electroplating bath. The technology is based on the use of specially designed water-soluble polymers that selectively bind with the metal ions in the rinse bath. The polymers have such a large molecular weight that they can be physically separated using available ultrafiltration technology. The advantages of this technology are high metal selectivity with no sludge formation, rapid processing, low energy, low capital costs, and small size. We have tested and demonstrated the recovery of zinc and nickel (a new alloy electroplating bath designed to replace cadmium) from rinse waters. The metal-ion concentrate was returned to the original electroplating bath. Applications of this technology include waste treatment for textile, paint and dye production, chemical manufacturing, and nuclear reactor and reprocessing operations.

  15. Heavy metal biosensor

    DOE Patents [OSTI]

    Hillson, Nathan J; Shapiro, Lucille; Hu, Ping; Andersen, Gary L

    2014-04-15

    Compositions and methods are provided for detection of certain heavy metals using bacterial whole cell biosensors.

  16. METAL PRODUCTION AND CASTING

    DOE Patents [OSTI]

    Magel, T.T.

    1958-03-01

    This patent covers a method and apparatus for collecting the molten metal produced by high temperature metal salt reduction. It consists essentially of subjecting the reaction vessel to centrifugal force in order to force the liberatcd molten metal into a coherent molten mass, and allowing it to solidify there. The apparatus is particularly suitable for use with small quantities of rare metals.

  17. Ceramic to metal seal

    DOE Patents [OSTI]

    Snow, Gary S.; Wilcox, Paul D.

    1976-01-01

    Providing a high strength, hermetic ceramic to metal seal by essentially heating a wire-like metal gasket and a ceramic member, which have been chemically cleaned, while simultaneously deforming from about 50 to 95 percent the metal gasket against the ceramic member at a temperature of about 30 to 75 percent of the melting temperature of the metal gasket.

  18. Nuclear criticality safety assessment of the proposed CFC replacement coolants

    SciTech Connect (OSTI)

    Jordan, W.C.; Dyer, H.R.

    1993-12-01

    The neutron multiplication characteristics of refrigerant-114 (R-114) and proposed replacement coolants perfluorobutane (C{sub 4}F{sub 10}) and cycloperfluorobutane C{sub 4}F{sub 8}) have been compared by evaluating the infinite media multiplication factors of UF{sub 6}/H/coolant systems and by replacement calculations considering a 10-MW freezer/sublimer. The results of these comparisons demonstrate that R-114 is a neutron absorber, due to its chlorine content, and that the alternative fluorocarbon coolants are neutron moderators. Estimates of critical spherical geometries considering mixtures of UF{sub 6}/HF/C{sub 4}F{sub 10} indicate that the flourocarbon-moderated systems are large compared with water-moderated systems. The freezer/sublimer calculations indicate that the alternative coolants are more reactive than R-114, but that the reactivity remains significantly below the condition of water in the tubes, which was a limiting condition. Based on these results, the alternative coolants appear to be acceptable; however, several follow-up tasks have been recommended, and additional evaluation will be required on an individual equipment basis.

  19. Operational Readiness Review: Savannah River Replacement Tritium Facility

    SciTech Connect (OSTI)

    Not Available

    1993-02-01

    The Operational Readiness Review (ORR) is one of several activities to be completed prior to introducing tritium into the Replacement Tritium Facility (RTF) at the Savannah River Site (SRS). The Secretary of Energy will rely in part on the results of this ORR in deciding whether the startup criteria for RTF have been met. The RTF is a new underground facility built to safely service the remaining nuclear weapons stockpile. At RTF, tritium will be unloaded from old components, purified and enriched, and loaded into new or reclaimed reservoirs. The RTF will replace an aging facility at SRS that has processed tritium for more than 35 years. RTF has completed construction and is undergoing facility startup testing. The final stages of this testing will require the introduction of limited amounts of tritium. The US Department of Energy (DOE) ORR was conducted January 19 to February 4, 1993, in accordance with an ORR review plan which was developed considering previous readiness reviews. The plan also considered the Defense Nuclear Facilities Safety Board (DNFSB) Recommendations 90-4 and 92-6, and the judgements of experienced senior experts. The review covered three major areas: (1) Plant and Equipment Readiness, (2) Personnel Readiness, and (3) Management Systems. The ORR Team was comprised of approximately 30 members consisting of a Team Leader, Senior Safety Experts, and Technical Experts. The ORR objectives and criteria were based on DOE Orders, industry standards, Institute of Nuclear Power Operations guidelines, recommendations of external oversight groups, and experience of the team members.

  20. How do I know if my RTUs are Efficient? When do I Replace or...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    How do I know if my RTUs are Efficient? When do I Replace or Retrofit them? How do I know if my RTUs are Efficient? When do I Replace or Retrofit them? December 2, 2015 - 3:05pm ...

  1. Webinar: The L Prize-Winning LED A19 Replacement-What Commercial...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The L Prize-Winning LED A19 Replacement-What Commercial Building OwnersOperators Can Expect in 2012 Webinar: The L Prize-Winning LED A19 Replacement-What Commercial Building ...

  2. Amorphous metal composites

    DOE Patents [OSTI]

    Byrne, Martin A. (Troy, NY); Lupinski, John H. (Scotia, NY)

    1984-01-01

    An improved amorphous metal composite and process of making the composite. The amorphous metal composite comprises amorphous metal (e.g. iron) and a low molecular weight thermosetting polymer binder. The process comprises placing an amorphous metal in particulate form and a thermosetting polymer binder powder into a container, mixing these materials, and applying heat and pressure to convert the mixture into an amorphous metal composite.

  3. Molecular metal-Oxo catalysts for generating hydrogen from water

    DOE Patents [OSTI]

    Long, Jeffrey R; Chang, Christopher J; Karunadasa, Hemamala I

    2015-02-24

    A composition of matter suitable for the generation of hydrogen from water is described, the positively charged cation of the composition having the general formula [(PY5W.sub.2)MO].sup.2+, wherein PY5W.sub.2 is (NC.sub.5XYZ)(NC.sub.5H.sub.4).sub.4C.sub.2W.sub.2, M is a transition metal, and W, X, Y, and Z can be H, R, a halide, CF.sub.3, or SiR.sub.3, where R can be an alkyl or aryl group. The two accompanying counter anions, in one embodiment, can be selected from the following Cl.sup.-, I.sup.-, PF.sub.6.sup.-, and CF.sub.3SO.sub.3.sup.-. In embodiments of the invention, water, such as tap water containing electrolyte or straight sea water can be subject to an electric potential of between 1.0 V and 1.4 V relative to the standard hydrogen electrode, which at pH 7 corresponds to an overpotential of 0.6 to 1.0 V, with the result being, among other things, the generation of hydrogen with an optimal turnover frequency of ca. 1.5 million mol H.sub.2/mol catalyst per h.

  4. CALiPER Benchmark Report: Performance of Halogen Incandescent MR16 Lamps and LED Replacement

    SciTech Connect (OSTI)

    Paget, M. L.; Lingard, R. D.; Myer, M. A.

    2008-11-01

    This benchmark report addresses the halogen MR16 lamp and its commercially available light-emitting diode (LED) replacements.

  5. DEVELOPMENT OF REMOTE HANFORD CONNECTOR GASKET REPLACEMENT TOOLING FOR DWPF

    SciTech Connect (OSTI)

    Krementz, D.; Coughlin, Jeffrey

    2009-05-05

    The Defense Waste Processing Facility (DWPF) requested the Savannah River National Laboratory (SRNL) to develop tooling and equipment to remotely replace gaskets in mechanical Hanford connectors to reduce personnel radiation exposure as compared to the current hands-on method. It is also expected that radiation levels will continually increase with future waste streams. The equipment is operated in the Remote Equipment Decontamination Cell (REDC), which is equipped with compressed air, two master-slave manipulators (MSM's) and an electro-mechanical manipulator (EMM) arm for operation of the remote tools. The REDC does not provide access to electrical power, so the equipment must be manually or pneumatically operated. The MSM's have a load limit at full extension of ten pounds, which limited the weight of the installation tool. In order to remotely replace Hanford connector gaskets several operations must be performed remotely, these include: removal of the spent gasket and retaining ring (retaining ring is also called snap ring), loading the new snap ring and gasket into the installation tool and installation of the new gasket into the Hanford connector. SRNL developed and tested tools that successfully perform all of the necessary tasks. Removal of snap rings from horizontal and vertical connectors is performed by separate air actuated retaining ring removal tools and is manipulated in the cell by the MSM. In order install a new gasket, the snap ring loader is used to load a new snap ring into a groove in the gasket installation tool. A new gasket is placed on the installation tool and retained by custom springs. An MSM lifts the installation tool and presses the mounted gasket against the connector block. Once the installation tool is in position, the gasket and snap ring are installed onto the connector by pneumatic actuation. All of the tools are located on a custom work table with a pneumatic valve station that directs compressed air to the desired tool and vents the tools as needed. Extensive testing of tooling operation was performed in the DWPF manipulator repair shop. This testing allowed the operators to gain confidence before the equipment was exposed to radioactive contamination. The testing also led to multiple design improvements. On July 17 and 29, 2008 the Remote Gasket Replacement Tooling was successfully demonstrated in the REDC at the DWPF of The Savannah River Site.

  6. Evaluation of radioactive scrap metal recycling

    SciTech Connect (OSTI)

    Nieves, L.A.; Chen, S.Y.; Kohout, E.J.; Nabelssi, B.; Tilbrook, R.W.; Wilson, S.E.

    1995-12-01

    This report evaluates the human health risks and environmental and socio-political impacts of options for recycling radioactive scrap metal (RSM) or disposing of and replacing it. Argonne National Laboratory (ANL) is assisting the US Department of Energy (DOE), Office of Environmental Restoration and Waste Management, Oak Ridge Programs Division, in assessing the implications of RSM management alternatives. This study is intended to support the DOE contribution to a study of metal recycling being conducted by the Task Group on Recycling and Reuse of the Organization for Economic Cooperation and Development. The focus is on evaluating the justification for the practice of recycling RSM, and the case of iron and steel scrap is used as an example in assessing the impacts. To conduct the evaluation, a considerable set of data was compiled and developed. Much of this information is included in this document to provide a source book of information.

  7. Formation of Pd/Au Nanostructures from Pd Nanowires via Galvanic Replacement Reaction

    SciTech Connect (OSTI)

    Teng,X.; Wang, Q.; Liu, P.; Han, W.; Frenkel, A.; Wen, W.; Marinkovic, N.; Hanson, J.; Rodriguez, J.

    2008-01-01

    Bimetallic nanostructures with non-random metal atoms distribution are very important for various applications. To synthesize such structures via benign wet chemistry approach remains challenging. This paper reports a synthesis of a Au/Pd alloy nanostructure through the galvanic replacement reaction between Pd ultrathin nanowires (2.4 {+-} 0.2 nm in width, over 30 nm in length) and AuCl3 in toluene. Both morphological and structural changes were monitored during the reaction up to 10 h. Continuous changes of chemical composition and crystalline structure from Pd nanowires to Pd68Au32 and Pd45Au55 alloys, and to Au nanoparticles were observed. More interestingly, by using combined techniques such as high-resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), energy dispersive X-ray spectrometry (EDS), UV-vis absorption, and extended X-ray absorption fine structure (EXAFS) spectroscopy, we found the formation of Pd68Au32 non-random alloy with Au-rich core and Pd-rich shell, and random Pd45Au55 alloy with uniformly mixed Pd and Au atom inside the nanoparticles, respectively. Density functional theory (DFT) calculations indicated that alkylamine will strongly stabilize Pd to the surface, resulting in diffusion of Au atoms into the core region to form a non-random alloy. We believe such benign synthetic techniques can also enable the large scale preparation of various types of non-random alloys for several technically important catalysis applications.

  8. Use of Brazilian sugarcane bagasse ash in concrete as sand replacement

    SciTech Connect (OSTI)

    Sales, Almir; Lima, Sofia Araujo

    2010-06-15

    Sugarcane today plays a major role in the worldwide economy, and Brazil is the leading producer of sugar and alcohol, which are important international commodities. The production process generates bagasse as a waste, which is used as fuel to stoke boilers that produce steam for electricity cogeneration. The final product of this burning is residual sugarcane bagasse ash (SBA), which is normally used as fertilizer in sugarcane plantations. Ash stands out among agroindustrial wastes because it results from energy generating processes. Many types of ash do not have hydraulic or pozzolanic reactivity, but can be used in civil construction as inert materials. The present study used ash collected from four sugar mills in the region of Sao Carlos, SP, Brazil, which is one of the world's largest producers of sugarcane. The ash samples were subjected to chemical characterization, sieve analysis, determination of specific gravity, X-ray diffraction, scanning electron microscopy, and solubilization and leaching tests. Mortars and concretes with SBA as sand replacement were produced and tests were carried out: compressive strength, tensile strength and elastic modulus. The results indicated that the SBA samples presented physical properties similar to those of natural sand. Several heavy metals were found in the SBA samples, indicating the need to restrict its use as a fertilizer. The mortars produced with SBA in place of sand showed better mechanical results than the reference samples. SBA can be used as a partial substitute of sand in concretes made with cement slag-modified Portland cement.

  9. Alkali metal nitrate purification

    DOE Patents [OSTI]

    Fiorucci, Louis C. (Hamden, CT); Morgan, Michael J. (Guilford, CT)

    1986-02-04

    A process is disclosed for removing contaminants from impure alkali metal nitrates containing them. The process comprises heating the impure alkali metal nitrates in solution form or molten form at a temperature and for a time sufficient to effect precipitation of solid impurities and separating the solid impurities from the resulting purified alkali metal nitrates. The resulting purified alkali metal nitrates in solution form may be heated to evaporate water therefrom to produce purified molten alkali metal nitrates suitable for use as a heat transfer medium. If desired, the purified molten form may be granulated and cooled to form discrete solid particles of purified alkali metal nitrates.

  10. Metal halogen electrochemical cell

    SciTech Connect (OSTI)

    Walsh, F.M.

    1986-06-03

    An electrochemical cell is described having a metal anode selected from the group consisting of zinc and cadmium; a bromine cathode; and, an aqueous electrolyte containing a metal bromide, the metal having the same metal as the metal of the anode, the improvement comprising: a bromine complexing agent in the aqueous metal bromide electrolyte consisting solely of a tetraorgano substituted ammonium salt, which salt is soluble of water and forms and substantially water immiscible liquid bromine complex at temperatures in the range of about 10/sup 0/C. to about 60/sup 0/C. and wherein the tetraorgano substituted ammonium salt is selected from asymmetric quaternary ammonium compounds.

  11. Metal-Air Batteries

    SciTech Connect (OSTI)

    Zhang, Jiguang; Bruce, Peter G.; Zhang, Gregory

    2011-08-01

    Metal-air batteries have much higher specific energies than most currently available primary and rechargeable batteries. Recent advances in electrode materials and electrolytes, as well as new designs on metal-air batteries, have attracted intensive effort in recent years, especially in the development of lithium-air batteries. The general principle in metal-air batteries will be reviewed in this chapter. The materials, preparation methods, and performances of metal-air batteries will be discussed. Two main metal-air batteries, Zn-air and Li-air batteries will be discussed in detail. Other type of metal-air batteries will also be described.

  12. Preferential Eu Site Occupation and Its Consequences in the Ternary Luminescent HalidesAB2I5:Eu2+(A=LiCs;B=Sr, Ba)

    SciTech Connect (OSTI)

    Fang, C.  M.; Biswas, Koushik

    2015-07-22

    Several rare-earth-doped, heavy-metal halides have recently been identified as potential next-generation luminescent materials with high efficiency at low cost. AB2I5:Eu2+ (A=Li–Cs; B=Sr, Ba) is one such family of halides. Its members, such as CsBa2I5:Eu2+ and KSr2I5:Eu2+, are currently being investigated as high-performance scintillators with improved sensitivity, light yield, and energy resolution less than 3% at 662 keV. Within the AB2I5 family, our first-principles-based calculations reveal two remarkably different trends in Eu site occupation. The substitutional Eu ions occupy both eightfold-coordinated B1(VIII) and the sevenfold-coordinated B2(VII) sites in the Sr-containing compounds. However, in the Ba-containing crystals, Eu ions strongly prefer the B2(VII)sites. This random versus preferential distribution of Eu affects their electronic properties. The calculations also suggest that in the Ba-containing compounds one can expect the formation of Eu-rich domains. These results provide atomistic insight into recent experimental observations about the concentration and temperature effects in Eu-doped CsBa2I5. We discuss the implications of our results with respect to luminescent properties and applications. We also hypothesize Sr, Ba-mixed quaternary iodides ABaVIIISrVIII5:Eu as scintillators having enhanced homogeneity and electronic properties.

  13. Metal to semiconductor transition in metallic transition metal dichalcogenides

    SciTech Connect (OSTI)

    Li, Yan; Kang, Jun; Li, Jingbo; Tongay, Sefaattin; Wu, Junqiao; Yue, Qu

    2013-11-07

    We report on tuning the electronic and magnetic properties of metallic transition metal dichalcogenides (mTMDCs) by 2D to 1D size confinement. The stability of the mTMDC monolayers and nanoribbons is demonstrated by the larger binding energy compared to the experimentally available semiconducting TMDCs. The 2D MX{sub 2} (M?=?Nb, Ta; X?=?S, Se) monolayers are non-ferromagnetic metals and mechanically softer compared to their semiconducting TMDCs counterparts. Interestingly, mTMDCs undergo metal-to-semiconductor transition when the ribbon width approaches to ?13? and ?7? for zigzag and armchair edge terminations, respectively; then these ribbons convert back to metal when the ribbon widths further decrease. Zigzag terminated nanoribbons are ferromagnetic semiconductors, and their magnetic properties can also be tuned by hydrogen edge passivation, whereas the armchair nanoribbons are non-ferromagnetic semiconductors. Our results display that the mTMDCs offer a broad range of physical properties spanning from metallic to semiconducting and non-ferromagnetic to ferromagnetic that is ideal for applications where stable narrow bandgap semiconductors with different magnetic properties are desired.

  14. Metal phthalocyanine catalysts

    DOE Patents [OSTI]

    Ellis, Jr., Paul E.; Lyons, James E.

    1994-01-01

    As a new composition of matter, alkali metal or ammonium or tetraalkylammonium diazidoperfluorophthalocyanatoferrate. Other embodiments of the invention comprise compositions wherein the metal of the coordination complex is cobalt, manganese and chromium.

  15. Nitrided Metallic Bipolar Plates

    SciTech Connect (OSTI)

    Brady, Michael P; Toops, Todd J; Tortorelli, Peter F; More, Karren Leslie; Meyer III, Harry M; Pihl, Josh A; Wang, Heli; Turner, John; Garzon, Fernando; Rockward, Tommy; Gervasio, Don; Rakowski, Jim; EstevezGenCell, Francisco

    2010-01-01

    Effort devoted to scale up and demonstration of thin stamped metallic bipolar plates. Overall goal is to demonstrate potential for metallic bipolar plates to meet 5000 h automotive durability goal at a cost of less than $5/kW.

  16. Metal phthalocyanine catalysts

    DOE Patents [OSTI]

    Ellis, P.E. Jr.; Lyons, J.E.

    1994-10-11

    A new composition of matter is described which is an alkali metal or ammonium or tetraalkylammonium diazidoperfluorophthalocyanatoferrate. Other embodiments of the invention comprise compositions wherein the metal of the coordination complex is cobalt, manganese and chromium.

  17. CRC Handbook of Electrical Resistivitives of Binary Metallic Alloys

    SciTech Connect (OSTI)

    Schroder, K.

    1983-01-01

    Material design engineers often require a tabulation of physical properties in order to select the appropriate material for use, while developmental engineers need to be aware of basic principles and systemic trends that can be utilized as a guide for developing future materials and alloys. The trade-off in conductivity that results when metals are replaced by alloys for strength and stability purposes becomes an important consideration for both types of engineers. This handbook presents an extensive, updated and comprehensive compilation of the electrical resistivities of metallic alloys.

  18. Tube Bank C - metal wastage: status report, August 1983

    SciTech Connect (OSTI)

    Not Available

    1984-01-01

    The Experimental Pressurised Fluidized Bed Combustion Facility at Grimethorpe, South Yorkshire, UK incorporates an in-bed tube bank. During the operation of the facility between June and September 1982, an unexpectedly high degree of metal wastage occurred from the external surfaces of this tube bank. Measures were taken to reduce the rate of metal wastage and extend the life of the tube bank, which was subsequently replaced in July 1983 after a total operating period of 1222 hours of coal burning. Using small-scale fluidized bed cold models, experimental investigations were carried out to determine measures to reduce the metal wastage. The results indicated that metal wastage would be reduced by the following changes: a reduction in the fluidizing velocity; the attachment of studs or axial fins to the tubes; a reduction in the height of the space between the distributor plate and the bottom of the tube bank; and the elimination, where possible of any large gaps within the tube bank. Such changes have been incorporated into the design of the replacement tube bank. This has now been installed and has experienced significantly less metal wastage. 9 references, 6 tables, 34 figures.

  19. Durable metallized polymer mirror

    DOE Patents [OSTI]

    Schissel, P.O.; Kennedy, C.E.; Jorgensen, G.J.; Shinton, Y.D.; Goggin, R.M.

    1994-11-01

    A metallized polymer mirror construction is disclosed having improved durability against delamination and tunneling, comprising: an outer layer of polymeric material; a metal oxide layer underlying the outer layer of polymeric material; a silver reflective layer underneath the metal oxide layer; and a layer of adhesive attaching the silver layer to a substrate. 6 figs.

  20. Durable metallized polymer mirror

    DOE Patents [OSTI]

    Schissel, Paul O.; Kennedy, Cheryl E.; Jorgensen, Gary J.; Shinton, Yvonne D.; Goggin, Rita M.

    1994-01-01

    A metallized polymer mirror construction having improved durability against delamination and tunneling, comprising: an outer layer of polymeric material; a metal oxide layer underlying the outer layer of polymeric material; a silver reflective layer underneath the metal oxide layer; and a layer of adhesive attaching the silver layer to a substrate.

  1. Formation of lithium fluoride/metal nanocomposites for energy storage through solid state reduction of metal fluorides

    SciTech Connect (OSTI)

    Amatucci, GG; Pereira, N; Badway, F; Sina, M; Cosandey, F; Ruotolo, M; Cao, C

    2011-12-01

    In order to utilize high energy metal fluoride electrode materials as direct replacement electrode materials for lithium ion batteries in the future, a methodology to prelithiate the cathode or anode must be developed. Herein, we introduce the use of a solid state Li(3)N route to achieve the lithiation and mechanoreduction of metal fluoride based nanocomposites. The resulting prelithiation was found to be effective with the formation of xLiF:Me structures of very fine nanodimensions analogous to what is found by electrochemical lithiation. Physical and electrochemical properties of these nanocomposites for the bismuth and iron lithium fluoride systems are reported. (C) 2011 Elsevier B.V. All rights reserved.

  2. ITP Metal Casting: Implementation of Metal Casting Best Practices |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Implementation of Metal Casting Best Practices ITP Metal Casting: Implementation of Metal Casting Best Practices PDF icon implementation_final.pdf More Documents & Publications ITP Metal Casting: Advanced Melting Technologies: Energy Saving Concepts and Opportunities for the Metal Casting Industry ITP Metal Casting: Energy Use in Selected Metalcasting Facilities - 2003 ITP Metal Casting: Energy and Environmental Profile of the U.S. Metal casting

  3. New York Power Authority/New York City Housing Authority refrigerator replacement program, first program year evaluation. Final report

    SciTech Connect (OSTI)

    Kinney, L.F.; Lewis, G.; Pratt, R.G.; Miller, J.

    1997-08-01

    Acting as an energy services provider, the New York Power Authority (NYPA) has initiated a long-term project through which 20,000 refrigerators per year will be replaced with the most energy-efficient units possible in apartments managed by the New York City Housing Authority (NYCHA). Using bulk purchasing as an incentive to appliance manufacturers to produce energy-efficient refrigerators suitable for use in apartments, replaced in the first year of the program, which ended in December 1996. These units, kWh per year. Savings were determined by field testing and laboratory testing of 220 existing refrigerators and 56 newly-installed units. In the next program year, a 15.0-cubic-foot Maytag refrigerator, newly-designed in response to bulk purchasing incentives, is being installed. The new unit has a label rating of 437 kWh per year, 31 percent better than 1993 energy standards. Old refrigerators removed from apartments are {open_quotes}demanufactured{close_quotes} in an environmentally-appropriate way and both metals and refrigerants are recovered for reuse.

  4. Kinetics and mechanism of the outer-sphere oxidation of metal carbonyl anions with coordination complexes containing chloride

    SciTech Connect (OSTI)

    Lai, C.K.; Corraine, M.S.; Atwood, J.D.

    1992-02-01

    Reactions of metal carbonyl anions, CpFe(CO){sub 2}{sup -}, Re(CO){sub 5}{sup -}, Mn(CO){sub 5}{sup -}, CpMo(CO){sub 3}{sup -}, CpCr(CO){sub 3}{sup -}, and Co(CO){sub 4}{sup -}, with CrCl{sub 3}{center_dot}3S (S = THF, CH{sub 3}CN) and reactions of Mn(CO){sub 5}{sup -} and Re(CO){sub 5}{sup -} with [Co(o-phen){sub 2}Cl{sub 2}]CIO{sub 4} are reported. Net oxidation/reduction chemistry is observed with formation of metal carbonyl dimers and CrCl{sub 2}{center_dot}4S or Co(o-phen){sub 2}Cl{sub 2}. Metal carbonyl halides are also observed and shown to arise from a secondary reaction of the metal carbonyl dimer with the oxidant. The products and rates are most consistent with outer-sphere electron-transfer reactions. Reactions of CpFe(CO){sub 2}{sup -} with CpFe(CO){sub 2}X (X = Cl, Br, I) are also reported. The rate dependence on X is very small and in the order expected for nucleophilic substitution. 21 refs. 1 fig., 4 tabs.

  5. LED Replacement Lamps: Current Performance and the Latest on ENERGY STAR®

    Energy Savers [EERE]

    | Department of Energy Replacement Lamps: Current Performance and the Latest on ENERGY STAR® LED Replacement Lamps: Current Performance and the Latest on ENERGY STAR® This May 19, 2009 webcast summarized CALiPER's recent benchmark testing of common omnidirectional incandescent lamps (e.g., A-lamps), and provided an update on ENERGY STAR criteria for LED integral replacement lamps - currently in its second draft. Robert Lingard of Pacific Northwest National Laboratory (PNNL) gave an

  6. Evaluation Prompts ENERGY STAR Program to Replace Web Tool, Saving 90

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Percent of Annual Costs | Department of Energy Prompts ENERGY STAR Program to Replace Web Tool, Saving 90 Percent of Annual Costs Evaluation Prompts ENERGY STAR Program to Replace Web Tool, Saving 90 Percent of Annual Costs This document, from the U.S. Environmental Protection Agency's ENERGY STAR Residential Program, is part of the Case Study Series, highlighting how "Evaluation Prompts ENERGY STAR Program to Replace Web Tool, Saving 90 Percent of Annual Costs." PDF icon ENERGY

  7. KP-Replacement-2-B Wholesale Power Rate Schedule | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Replacement-2-B Wholesale Power Rate Schedule KP-Replacement-2-B Wholesale Power Rate Schedule Area: Replacement Energy System: Kerr-Philpott This rate schedule shall be available to public bodies and cooperatives (any one of whom is hereinafter called the Customer) in North Carolina and Virginia to whom power is provided pursuant to contracts between the Government and the customer from the John H. Kerr and Philpott Projects (or Kerr-Philpott System). This rate schedule shall be applicable to

  8. Replacing the Whole BarrelTo Reduce U.S. Dependence on Oil | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Replacing the Whole BarrelTo Reduce U.S. Dependence on Oil Replacing the Whole BarrelTo Reduce U.S. Dependence on Oil Converting domestic biomass into affordable fuels, products, and power supports our national strategy to diversify energy resources and reduce dependence on imported oil. PDF icon replacing_barrel_overview.pdf More Documents & Publications Thermochemical Conversion: Using Heat and Catalysis to Make Biofuels and Bioproducts Bioenergy Technologies Office Conversion

  9. Extraction process for removing metallic impurities from alkalide metals

    DOE Patents [OSTI]

    Royer, L.T.

    1987-03-20

    A development is described for removing metallic impurities from alkali metals by employing an extraction process wherein the metallic impurities are extracted from a molten alkali metal into molten lithium metal due to the immiscibility of the alkali metals in lithium and the miscibility of the metallic contaminants or impurities in the lithium. The purified alkali metal may be readily separated from the contaminant-containing lithium metal by simple decanting due to the differences in densities and melting temperatures of the alkali metals as compared to lithium.

  10. Replacement of lead-loaded glovebox glove with attenuation medium that are not RCRA-hazardous metals

    SciTech Connect (OSTI)

    Cournoyer, Michael E; George, Gerald L; Dodge, Robert L; Chunglo, Steve

    2010-01-01

    Programmatic operations at the Los Alamos National Laboratory Plutonium Facility (TA-55) involve working with various amounts of plutonium and other highly toxic, alpha-emitting materials. The spread of radiological contamination on surfaces, airborne contamination, and excursions of contaminants into the operator's breathing zone are prevented through the use of a variety of gloveboxes (the glovebox, coupled with an adequate negative pressure gradient, provides primary confinement). Radiation shielding is commonly used to protect the glovebox worker from unintentional direct and secondary radiation exposure, while working with plutonium-238 and plutonium-239. In these environments, low-energy photons, i.e., those less than 250 keY, are encountered. Shielding glove box gloves are traditionally composed of lead-based materials, but these are now considered hazardous waste. This has prompted the development of new, nonhazardous- shielding gJovebox gloves. No studies, however, have investigated the effectiveness of these new glovebox gloves. We examined both leaded and nonhazardous- shielding glovebox gloves and compared their attenuation effectiveness over the energy range of interest at TA-55. All measurements are referenced to lead sheets, allowing direct comparisons to the common industry standard of 0.1 mm lead equivalent material. The attenuation properties of both types of glovebox gloves vary with energy, making it difficult for manufacturers to claim lead equivalency across the entire energy range used at TA-55. The positions of materials' photon energy absorption edges, which are particularly important to improved attenuation performance, depending upon the choice of radiation energy range, are discussed. This effort contributes to the Los Alamos National Laboratory Continuous Improvement Program by improving the efficiency, cost effectiveness, and formality of glovebox operations.

  11. METHOD FOR THE REDUCTION OF URANIUM COMPOUNDS

    DOE Patents [OSTI]

    Cooke, W.H.; Crawford, J.W.C.

    1959-05-12

    An improved technique of preparing massive metallic uranium by the reaction at elevated temperature between an excess of alkali in alkaline earth metal and a uranium halide, such ss uranium tetrafluoride is presented. The improvement comprises employing a reducing atmosphere of hydrogen or the like, such as coal gas, in the vessel during the reduction stage and then replacing the reducing atmosphere with argon gas prior to cooling to ambient temperature.

  12. Fact #568: April 27, 2009 For Modern Cars, Replacing an Air Filter...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Performance but Not Fuel Economy Fact 568: April 27, 2009 For Modern Cars, Replacing an Air Filter Will Improve Performance but Not Fuel Economy A February 2009 study ...

  13. Building America Top Innovations 2013 Profile – Window Replacement, Rehabilitation, & Repair Guide

    SciTech Connect (OSTI)

    none,

    2013-09-01

    In this Top Innovation profile, Building Science Corporation guides contractors through several options for repairing or replacing old windows to improve air sealing and thermal performance.

  14. Feasibility/alternatives study for the planned replacement of Nuclear Material Safeguards System (NMSS)

    SciTech Connect (OSTI)

    McBride, K.C.; Russell, V.K.

    1994-10-04

    This document is a study which describes the NMSS replacement alternatives and provides recommended solutions. It also describes a NMSS Paradox prototype.

  15. Text-Alternative Version: LED Replacement Lamps: Current Performance and the Latest on ENERGY STAR®

    Broader source: Energy.gov [DOE]

    Below is the text-alternative version of the LED Replacement Lamps: Current Performance and the Latest on ENERGY STAR® webcast.

  16. CALiPER Benchmark Report: Performance of Incandescent A Type and Decorative Lamps and LED Replacements

    SciTech Connect (OSTI)

    Lingard, R. D.; Myer, M. A.; Paget, M. L.

    2008-11-01

    This benchmark report addresses common omnidirectional incandescent lamps - A-type and small decorative, candelabra-type lamps - and their commercially available light-emitting diode (LED) replacements.

  17. Is it Cost-Effective to Replace Old Eddy-Current Drives? - Motor Tip Sheet #12

    SciTech Connect (OSTI)

    2008-07-01

    New pulse-width-modulated (PWM) adjustable speed drives (ASDs) may be cost-effective replacements for aging or maintenance-intensive eddy-current drives.

  18. Method of making metal-doped organic foam products

    DOE Patents [OSTI]

    Rinde, James A.

    1981-01-01

    Organic foams having a low density and very small cell size and method for roducing same in either a metal-loaded or unloaded (nonmetal loaded) form are described. Metal-doped foams are produced by soaking a polymer gel in an aqueous solution of desired metal salt, soaking the gel successively in a solvent series of decreasing polarity to remove water from the gel and replace it with a solvent of lower polarity with each successive solvent in the series being miscible with the solvents on each side and being saturated with the desired metal salt, and removing the last of the solvents from the gel to produce the desired metal-doped foam having desired density cell size, and metal loading. The unloaded or metal-doped foams can be utilized in a variety of applications requiring low density, small cell size foam. For example, rubidium-doped foam made in accordance with the invention has utility in special applications, such as in x-ray lasers.

  19. FORMING PROTECTIVE FILMS ON METAL

    DOE Patents [OSTI]

    Gurinsky, D.H.; Kammerer, O.F.; Sadofsky, J.; Weeks, J.R.

    1958-12-16

    Methods are described of inhibiting the corrosion of ferrous metal by contact with heavy liquid metals such as bismuth and gallium at temperatures above 500 icient laborato C generally by bringing nltrogen and either the metal zirconium, hafnium, or titanium into reactlve contact with the ferrous metal to form a thin adherent layer of the nitride of the metal and thereafter maintaining a fractional percentage of the metal absorbed in the heavy liquid metal in contact with the ferrous metal container. The general purpose for uslng such high boiling liquid metals in ferrous contalners would be as heat transfer agents in liquid-metal-fueled nuclear reactors.

  20. Light metal production

    DOE Patents [OSTI]

    Fan, Qinbai

    2016-04-19

    An electrochemical process for the production of light metals, particularly aluminum. Such a process involves contacting a light metal source material with an inorganic acid to form a solution containing the light metal ions in high concentration. The solution is fed to an electrochemical reactor assembly having an anode side containing an anode and a cathode side containing a cathode, with anode side and the cathode side separated by a bipolar membrane, with the solution being fed to the anode side. Light metal ions are electrochemically transferred through the bipolar membrane to the cathode side. The process further involves reducing the light metal ions to light metal powder. An associated processing system is also provided.

  1. Metal atomization spray nozzle

    DOE Patents [OSTI]

    Huxford, Theodore J.

    1993-01-01

    A spray nozzle for a magnetohydrodynamic atomization apparatus has a feed passage for molten metal and a pair of spray electrodes mounted in the feed passage. The electrodes, diverging surfaces which define a nozzle throat and diverge at an acute angle from the throat. Current passes through molten metal when fed through the throat which creates the Lorentz force necessary to provide atomization of the molten metal.

  2. Metal atomization spray nozzle

    DOE Patents [OSTI]

    Huxford, T.J.

    1993-11-16

    A spray nozzle for a magnetohydrodynamic atomization apparatus has a feed passage for molten metal and a pair of spray electrodes mounted in the feed passage. The electrodes, diverging surfaces which define a nozzle throat and diverge at an acute angle from the throat. Current passes through molten metal when fed through the throat which creates the Lorentz force necessary to provide atomization of the molten metal. 6 figures.

  3. Metal atom oxidation laser

    DOE Patents [OSTI]

    Jensen, R.J.; Rice, W.W.; Beattie, W.H.

    1975-10-28

    A chemical laser which operates by formation of metal or carbon atoms and reaction of such atoms with a gaseous oxidizer in an optical resonant cavity is described. The lasing species are diatomic or polyatomic in nature and are readily produced by exchange or other abstraction reactions between the metal or carbon atoms and the oxidizer. The lasing molecules may be metal or carbon monohalides or monoxides. (auth)

  4. Metal atom oxidation laser

    DOE Patents [OSTI]

    Jensen, R.J.; Rice, W.W.; Beattie, W.H.

    1975-10-28

    A chemical laser which operates by formation of metal or carbon atoms and reaction of such atoms with a gaseous oxidizer in an optical resonant cavity is described. The lasing species are diatomic or polyatomic in nature and are readily produced by exchange or other abstraction reactions between the metal or carbon atoms and the oxidizer. The lasing molecules may be metal or carbon monohalides or monoxides.

  5. Probing metal solidification nondestructively

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Probing metal solidification nondestructively Probing metal solidification nondestructively This is the first time that high-energy protons have been used to nondestructively image a large metal sample during melting and solidification. April 11, 2014 An x-ray image of a 200 micron thick aluminum-14 atomic percent copper alloy during directional solidification, highlighting the growth of an aluminum-rich branched structure (dendrite) and the advancing solid-liquid (planar) interface. The

  6. Supported metal alloy catalysts

    DOE Patents [OSTI]

    Barrera, Joseph; Smith, David C.

    2000-01-01

    A process of preparing a Group IV, V, or VI metal carbonitride including reacting a Group IV, V, or VI metal amide complex with ammonia to obtain an intermediate product; and, heating the intermediate product to temperatures and for times sufficient to form a Group IV, V, or VI metal carbonitride is provided together with the product of the process and a process of reforming an n-alkane by use of the product.

  7. Closed cell metal foam method

    DOE Patents [OSTI]

    Patten, James W.

    1978-01-01

    Foamed metals and metal alloys which have a closed cellular structure are prepared by heating a metal body containing entrapped inert gas uniformly distributed throughout to a temperature above the melting point of the metal and maintaining the body at this temperature a period of time sufficient to permit the entrapped gas to expand, forming individual cells within the molten metal, thus expanding and foaming the molten metal. After cell formation has reached the desired amount, the foamed molten metal body is cooled to below the melting temperature of the metal. The void area or density of the foamed metal is controlled by predetermining the amount of inert gas entrapped in the metal body and by the period of time the metal body is maintained in the molten state. This method is useful for preparing foamed metals and metal alloys from any metal or other material of which a body containing entrapped inert gas can be prepared.

  8. Nitrided Metallic Bipolar Plates

    Broader source: Energy.gov [DOE]

    This presentation, which focuses on nitrided metallic bipolar plates, was given by M. P. Brady of ORNL at a February 2007 meeting on new fuel cell projects.

  9. Method of producing homogeneous mixed metal oxides and metal-metal oxide mixtures

    DOE Patents [OSTI]

    Quinby, Thomas C.

    1978-01-01

    Metal powders, metal oxide powders, and mixtures thereof of controlled particle size are provided by reacting an aqueous solution containing dissolved metal values with excess urea. Upon heating, urea reacts with water from the solution leaving a molten urea solution containing the metal values. The molten urea solution is heated to above about 180.degree. C. whereupon metal values precipitate homogeneously as a powder. The powder is reduced to metal or calcined to form oxide particles. One or more metal oxides in a mixture can be selectively reduced to produce metal particles or a mixture of metal and metal oxide particles.

  10. Test report for K Basin MK I lid removal and replacement system

    SciTech Connect (OSTI)

    Omberg, R.P.; Roe, N.R.

    1996-08-21

    This report provides the results of acceptance testing of sampling equipment for use in the Hanford K Basin. The equipment, MK I Lid Removal/Replacement Tools, were designed to remove/replace MK I Spent Fuel Canister lids so that other equipment may be used to sample the canister contents. The tools were determined to be acceptable for their intended use.

  11. Silicon metal-semiconductor-metal photodetector

    DOE Patents [OSTI]

    Brueck, Steven R. J.; Myers, David R.; Sharma, Ashwani K.

    1995-01-01

    Silicon MSM photodiodes sensitive to radiation in the visible to near infrared spectral range are produced by altering the absorption characteristics of crystalline Si by ion implantation. The implantation produces a defected region below the surface of the silicon with the highest concentration of defects at its base which acts to reduce the contribution of charge carriers formed below the defected layer. The charge carriers generated by the radiation in the upper regions of the defected layer are very quickly collected between biased Schottky barrier electrodes which form a metal-semiconductor-metal structure for the photodiode.

  12. Silicon metal-semiconductor-metal photodetector

    DOE Patents [OSTI]

    Brueck, Steven R. J.; Myers, David R.; Sharma, Ashwani K.

    1997-01-01

    Silicon MSM photodiodes sensitive to radiation in the visible to near infrared spectral range are produced by altering the absorption characteristics of crystalline Si by ion implantation. The implantation produces a defected region below the surface of the silicon with the highest concentration of defects at its base which acts to reduce the contribution of charge carriers formed below the defected layer. The charge carriers generated by the radiation in the upper regions of the defected layer are very quickly collected between biased Schottky barrier electrodes which form a metal-semiconductor-metal structure for the photodiode.

  13. DEVELOPMENT OF A NON-NOBLE METAL HYDROGEN PURIFICATION SYSTEM

    SciTech Connect (OSTI)

    Korinko, P; Kyle Brinkman, K; Thad Adams, T; George Rawls, G

    2008-11-25

    Development of advanced hydrogen separation membranes in support of hydrogen production processes such as coal gasification and as front end gas purifiers for fuel cell based system is paramount to the successful implementation of a national hydrogen economy. Current generation metallic hydrogen separation membranes are based on Pd-alloys. Although the technology has proven successful, at issue is the high cost of palladium. Evaluation of non-noble metal based dense metallic separation membranes is currently receiving national and international attention. The focus of the reported work was to develop a scaled reactor with a VNi-Ti alloy membrane to replace a production Pd-alloy tube-type purification/diffuser system.

  14. PRODUCTION OF PLUTONIUM METAL

    DOE Patents [OSTI]

    Lyon, W.L.; Moore, R.H.

    1961-01-17

    A process is given for producing plutonium metal by the reduction of plutonium chloride, dissolved in alkali metal chloride plus or minus aluminum chloride, with magnesium or a magnesium-aluminum alloy at between 700 and 800 deg C and separating the plutonium or plutonium-aluminum alloy formed from the salt.

  15. Porous metallic bodies

    DOE Patents [OSTI]

    Landingham, R.L.

    1984-03-13

    Porous metallic bodies having a substantially uniform pore size of less than about 200 microns and a density of less than about 25 percent theoretical, as well as the method for making them, are disclosed. Group IIA, IIIB, IVB, VB, and rare earth metal hydrides a

  16. Production of magnesium metal

    DOE Patents [OSTI]

    Blencoe, James G. [Harriman, TN; Anovitz, Lawrence M. [Knoxville, TN; Palmer, Donald A. [Oliver Springs, TN; Beard, James S. [Martinsville, VA

    2010-02-23

    A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention further relates to a process for production of magnesium metal or a magnesium compound where an external source of carbon dioxide is not used in any of the reactions of the process. The invention also relates to the magnesium metal produced by the processes described herein.

  17. Metallization of electronic insulators

    DOE Patents [OSTI]

    Gottesfeld, Shimshon (Los Alamos, NM); Uribe, Francisco A. (Los Alamos, NM)

    1994-01-01

    An electroplated element is formed to include an insulating substrate, a conducting polymer polymerized in situ on the substrate, and a metal layer deposited on the conducting polymer. In one application a circuit board is formed by polymerizing pyrrole on an epoxy-fiberglass substrate in a single step process and then electrodepositing a metal over the resulting polypyrrole polymer. No chemical deposition of the metal is required prior to electroplating and the resulting layer of substrate-polymer-metal has excellent adhesion characteristics. The metal deposition is surprisingly smooth and uniform over the relatively high resistance film of polypyrrole. A continuous manufacturing process is obtained by filtering the solution between successive substrates to remove polymer formed in the solution, by maintaining the solution oxidizing potential within selected limits, and by adding a strong oxidant, such as KMnO.sub.4 at periodic intervals to maintain a low sheet resistivity in the resulting conducting polymer film.

  18. A survey of repair practices for nuclear power plant containment metallic pressure boundaries

    SciTech Connect (OSTI)

    Oland, C.B.; Naus, D.J.

    1998-05-01

    The Nuclear Regulatory Commission has initiated a program at the Oak Ridge National Laboratory to provide assistance in their assessment of the effects of potential degradation on the structural integrity and leaktightness of metal containment vessels and steel liners of concrete containments in nuclear power plants. One of the program objectives is to identify repair practices for restoring metallic containment pressure boundary components that have been damaged or degraded in service. This report presents issues associated with inservice condition assessments and continued service evaluations and identifies the rules and requirements for the repair and replacement of nonconforming containment pressure boundary components by welding or metal removal. Discussion topics include base and welding materials, welding procedure and performance qualifications, inspection techniques, testing methods, acceptance criteria, and documentation requirements necessary for making acceptable repairs and replacements so that the plant can be returned to a safe operating condition.

  19. Synthesis of Metal-Metal Oxide Catalysts and Electrocatalysts...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Synthesis of Metal-Metal Oxide Catalysts and Electrocatalysts Brookhaven National Laboratory Contact BNL About This Technology Publications: PDF Document Publication...

  20. Metal nanodisks using bicellar templates

    DOE Patents [OSTI]

    Song, Yujiang; Shelnutt, John A

    2013-12-03

    Metallic nanodisks and a method of making them. The metallic nanodisks are wheel-shaped structures that that provide large surface areas for catalytic applications. The metallic nanodisks are grown within bicelles (disk-like micelles) that template the growth of the metal in the form of approximately circular dendritic sheets. The zero-valent metal forming the nanodisks is formed by reduction of a metal ion using a suitable electron donor species.

  1. Metal Aminoboranes - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Materials Advanced Materials Find More Like This Return to Search Metal Aminoboranes Los Alamos National Laboratory Contact LANL About This Technology Technology Marketing Summary Metal aminoboranes of the formula M(NH.sub.2BH.sub.3).sub.n have been synthesized. Metal aminoboranes are hydrogen storage materials. Metal aminoboranes are also precursors for synthesizing other metal aminoboranes. Metal aminoboranes can be dehydrogenated to form hydrogen and a reaction product. The reaction

  2. Precious Metals | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Precious Metals General Information: The Materials Handling group provides Precious Metals receiving and documentation (PM's) for research programs funded by the Department of Energy (DOE). Precious metals are obtained from the DOE's Business Center for Precious Metals Sales and Recovery (BCPMSR). The return of scrap and excess precious metals to the BCPMSR is also provided by this group. Metals under this control are: GOLD - SILVER - PLATINUM - RHODIUM - PALLADIUM - IRIDIUM - OSMIUM - RUTHENIUM

  3. Method for producing metallic nanoparticles

    DOE Patents [OSTI]

    Phillips, Jonathan; Perry, William L.; Kroenke, William J.

    2004-02-10

    Method for producing metallic nanoparticles. The method includes generating an aerosol of solid metallic microparticles, generating non-oxidizing plasma with a plasma hot zone at a temperature sufficiently high to vaporize the microparticles into metal vapor, and directing the aerosol into the hot zone of the plasma. The microparticles vaporize in the hot zone to metal vapor. The metal vapor is directed away from the hot zone and to the plasma afterglow where it cools and condenses to form solid metallic nanoparticles.

  4. Method for producing metallic microparticles

    DOE Patents [OSTI]

    Phillips, Jonathan; Perry, William L.; Kroenke, William J.

    2004-06-29

    Method for producing metallic particles. The method converts metallic nanoparticles into larger, spherical metallic particles. An aerosol of solid metallic nanoparticles and a non-oxidizing plasma having a portion sufficiently hot to melt the nanoparticles are generated. The aerosol is directed into the plasma where the metallic nanoparticles melt, collide, join, and spheroidize. The molten spherical metallic particles are directed away from the plasma and enter the afterglow where they cool and solidify.

  5. Agents for replacement of NAD+/NADH system in enzymatic reactions

    DOE Patents [OSTI]

    Fish, Richard H.; Kerr, John B.; Lo, Christine H.

    2004-04-06

    Novel agents acting as co-factors for replacement of NAD(P).sup.+ /NAD(P)H co-enzyme systems in enzymatic oxido-reductive reactions. Agents mimicking the action of NAD(P).sup.+ /NAD(P)H system in enzymatic oxidation/reduction of substrates into reduced or oxidized products. A method for selection and preparation of the mimicking agents for replacement of NAD(P).sup.+ /NAD(P)H system and a device comprising co-factors for replacement of NAD(P).sup.+ /NAD(P)H system.

  6. EERE Success Story-California: SQAMD Replaces Drayage Trucks with CNG |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy SQAMD Replaces Drayage Trucks with CNG EERE Success Story-California: SQAMD Replaces Drayage Trucks with CNG November 6, 2013 - 12:00am Addthis In 2008, the South Coast Air Quality Management District (AQMD) Heavy-Duty Natural Gas Drayage Truck Replacement Program started to address a significant need to reduce diesel emissions and associated public health risks from goods movement at the Ports of Los Angeles and Long Beach. In 2010, the two ports processed goods worth

  7. Transition Metal Switchable Mirror

    ScienceCinema (OSTI)

    None

    2010-01-08

    The switchable-mirrors technology was developed by Tom Richardson and Jonathan Slack of Berkeley Lab's Environmental Energy Technologies Division. By using transition metals rather than the rare earth metals used in the first metal-hydride switchable mirrors, Richardson and Slack were able to lower the cost and simplify the manufacturing process. Energy performance is improved as well, because the new windows can reflect or transmit both visible and infrared light. Besides windows for offices and homes, possible applications include automobile sunroofs, signs and displays, aircraft windows, and spacecraft.

  8. Transition Metal Switchable Mirror

    ScienceCinema (OSTI)

    None

    2013-05-29

    The switchable-mirrors technology was developed by Tom Richardson and Jonathan Slack of Berkeley Lab's Environmental Energy Technologies Division. By using transition metals rather than the rare earth metals used in the first metal-hydride switchable mirrors, Richardson and Slack were able to lower the cost and simplify the manufacturing process. Energy performance is improved as well, because the new windows can reflect or transmit both visible and infrared light. Besides windows for offices and homes, possible applications include automobile sunroofs, signs and displays, aircraft windows, and spacecraft. More information at: http://windows.lbl.gov/materials/chromogenics/default.htm

  9. Actinide metal processing

    DOE Patents [OSTI]

    Sauer, Nancy N. (Los Alamos, NM); Watkin, John G. (Los Alamos, NM)

    1992-01-01

    A process of converting an actinide metal such as thorium, uranium, or plnium to an actinide oxide material by admixing the actinide metal in an aqueous medium with a hypochlorite as an oxidizing agent for sufficient time to form the actinide oxide material and recovering the actinide oxide material is provided together with a low temperature process of preparing an actinide oxide nitrate such as uranyl nitrte. Additionally, a composition of matter comprising the reaction product of uranium metal and sodium hypochlorite is provided, the reaction product being an essentially insoluble uranium oxide material suitable for disposal or long term storage.

  10. Liquid metal electric pump

    DOE Patents [OSTI]

    Abbin, J.P.; Andraka, C.E.; Lukens, L.L.; Moreno, J.B.

    1992-01-14

    An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other. 3 figs.

  11. Liquid metal electric pump

    DOE Patents [OSTI]

    Abbin, Joseph P.; Andraka, Charles E.; Lukens, Laurance L.; Moreno, James B.

    1992-01-01

    An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other.

  12. Actinide metal processing

    DOE Patents [OSTI]

    Sauer, N.N.; Watkin, J.G.

    1992-03-24

    A process for converting an actinide metal such as thorium, uranium, or plutonium to an actinide oxide material by admixing the actinide metal in an aqueous medium with a hypochlorite as an oxidizing agent for sufficient time to form the actinide oxide material and recovering the actinide oxide material is described together with a low temperature process for preparing an actinide oxide nitrate such as uranyl nitrate. Additionally, a composition of matter comprising the reaction product of uranium metal and sodium hypochlorite is provided, the reaction product being an essentially insoluble uranium oxide material suitable for disposal or long term storage.

  13. EXELFS of Metallic Glasses

    SciTech Connect (OSTI)

    Ito, Y.; Alamgir, F.M.; Schwarz, R.B.; Jain, H.; Williams, D.B.

    1999-11-30

    The feasibility of using extended energy-loss fine structure (EXELFS) obtained from {approximately}1 nm regions of metallic glasses to study their short-range order has been examined. Ionization edges of the metallic glasses in the electron energy-loss spectrum (EELS) have been obtained from PdNiP bulk metallic glass and Ni{sub 2}P polycrystalline powder in a transmission electron microscope. The complexity of EXELFS analysis of L- and M-ionization edges of heavy elements (Z>22, i.e. Ni and Pd) is addressed by theoretical calculations using an ab initio computer code, and its results are compared with the experimental data.

  14. Preparation of uniform nanoparticles of ultra-high purity metal oxides, mixed metal oxides, metals, and metal alloys

    DOE Patents [OSTI]

    Woodfield, Brian F.; Liu, Shengfeng; Boerio-Goates, Juliana; Liu, Qingyuan; Smith, Stacey Janel

    2012-07-03

    In preferred embodiments, metal nanoparticles, mixed-metal (alloy) nanoparticles, metal oxide nanoparticles and mixed-metal oxide nanoparticles are provided. According to embodiments, the nanoparticles may possess narrow size distributions and high purities. In certain preferred embodiments, methods of preparing metal nanoparticles, mixed-metal nanoparticles, metal oxide nanoparticles and mixed-metal nanoparticles are provided. These methods may provide tight control of particle size, size distribution, and oxidation state. Other preferred embodiments relate to a precursor material that may be used to form nanoparticles. In addition, products prepared from such nanoparticles are disclosed.

  15. Electrodes synthesized from carbon nanostructures coated with a smooth and conformal metal adlayer

    DOE Patents [OSTI]

    Adzic, Radoslav; Harris, Alexander

    2014-04-15

    High-surface-area carbon nanostructures coated with a smooth and conformal submonolayer-to-multilayer thin metal films and their method of manufacture are described. The preferred manufacturing process involves the initial oxidation of the carbon nanostructures followed by a surface preparation process involving immersion in a solution with the desired pH to create negative surface dipoles. The nanostructures are subsequently immersed in an alkaline solution containing a suitable quantity of non-noble metal ions which adsorb at surface reaction sites. The metal ions are then reduced via chemical or electrical means. The nanostructures are exposed to a solution containing a salt of one or more noble metals which replace adsorbed non-noble surface metal atoms by galvanic displacement. The process can be controlled and repeated to obtain a desired film coverage. The resulting coated nanostructures may be used, for example, as high-performance electrodes in supercapacitors, batteries, or other electric storage devices.

  16. Oligocyclopentadienyl transition metal complexes

    SciTech Connect (OSTI)

    de Azevedo, Cristina G.; Vollhardt, K. Peter C.

    2002-01-18

    Synthesis, characterization, and reactivity studies of oligocyclopentadienyl transition metal complexes, namely those of fulvalene, tercyclopentadienyl, quatercyclopentadienyl, and pentacyclopentadienyl(cyclopentadienyl) are the subject of this account. Thermal-, photo-, and redox chemistries of homo- and heteropolynuclear complexes are described.

  17. Metal Hydride Storage Materials

    Broader source: Energy.gov [DOE]

    The Fuel Cell Technologies Office's (FCTO's) metal hydride storage materials research focuses on improving the volumetric and gravimetric capacities, hydrogen adsorption/desorption kinetics, cycle life, and reaction thermodynamics of potential material candidates.

  18. Production of magnesium metal

    DOE Patents [OSTI]

    Blencoe, James G.; Anovitz, Lawrence M.; Palmer, Donald A.; Beard, James S.

    2012-04-10

    A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention also relates to the magnesium metal produced by the processes described herein.

  19. Molten metal reactors

    DOE Patents [OSTI]

    Bingham, Dennis N; Klingler, Kerry M; Turner, Terry D; Wilding, Bruce M

    2013-11-05

    A molten metal reactor for converting a carbon material and steam into a gas comprising hydrogen, carbon monoxide, and carbon dioxide is disclosed. The reactor includes an interior crucible having a portion contained within an exterior crucible. The interior crucible includes an inlet and an outlet; the outlet leads to the exterior crucible and may comprise a diffuser. The exterior crucible may contain a molten alkaline metal compound. Contained between the exterior crucible and the interior crucible is at least one baffle.

  20. Replace Pressure-Reducing Valves with Backpressure Turbogenerators - Steam Tip Sheet #20

    SciTech Connect (OSTI)

    2012-01-01

    This revised AMO steam tip sheet on replacing pressure-reducing valves provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  1. Replacing the Whole BarrelTo Reduce U.S. Dependence on Oil

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Replacing the Whole Barrel To Reduce U.S. Dependence on Oil July 2013 Biofuels are ... We've got to develop every source of American energy-not just oil and gas, but wind power ...

  2. Is it Cost-Effective to Replace Old Eddy-Current Drives?

    Broader source: Energy.gov [DOE]

    New pulse-width-modulated (PWM) adjustable speed drives (ASDs) may be cost-effective replacements for aging or maintenance-intensive eddy-current drives. This tip sheet provides suggested actions and example energy savings calculations.

  3. Is it Cost-Effective to Replace Old Eddy-Current Drives?

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Drives? Electronic pulse-width-modulated (PWM) variable frequency drives (VFD) may be ... life; the proposed replacement is a PWM VFD. The fan operates for 8,000 hours per ...

  4. Replaces DOE F 3530.1 5. HOW LONG IN PRESENT POSITION GRADE

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (07-95) Replaces DOE F 3530.1 5. HOW LONG IN PRESENT POSITION GRADE 6. DATE NEXT REGULAR STEP INCREASE IS DUE: 7. LIST ANY AWARDS OR QUALITY INCREASES RECEIVED IN LAST 5 YEARS...

  5. PREPARATION OF URANIUM-ALUMINUM ALLOYS

    DOE Patents [OSTI]

    Moore, R.H.

    1962-09-01

    A process is given for preparing uranium--aluminum alloys from a solution of uranium halide in an about equimolar molten alkali metal halide-- aluminum halide mixture and excess aluminum. The uranium halide is reduced and the uranium is alloyed with the excess aluminum. The alloy and salt are separated from each other. (AEC)

  6. CU-Replacement-3 Wholesale Power Rate Schedule | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Replacement-3 Wholesale Power Rate Schedule CU-Replacement-3 Wholesale Power Rate Schedule Area: Virginia, North Carolina, Tennessee, Georgia, Alabama, Mississippi, Kentucky, southern Illinois System: CU This rate schedule shall be available to public bodies and cooperatives ( any one of whom is hereinafter called the Customer) in Virginia, North Carolina, Tennessee, Georgia, Alabama, Mississippi, Kentucky and southern Illinois to whom power is provided pursuant to contracts between the

  7. Molecular replacement and model-building using distant homology models as

    Office of Scientific and Technical Information (OSTI)

    templates (Technical Report) | SciTech Connect Molecular replacement and model-building using distant homology models as templates Citation Details In-Document Search Title: Molecular replacement and model-building using distant homology models as templates Authors: Terwilliger, Thomas C. [1] + Show Author Affiliations Los Alamos National Laboratory [Los Alamos National Laboratory Publication Date: 2013-11-26 OSTI Identifier: 1107986 Report Number(s): LA-UR-13-29025 DOE Contract Number:

  8. The Radioactive Liquid Waste Treatment Facility Replacement Project at Los Alamos National Laboratory

    Energy Savers [EERE]

    Radioactive Liquid Waste Treatment Facility Replacement Project at Los Alamos National Laboratory OAS-L-13-15 September 2013 Department of Energy Washington, DC 20585 September 26, 2013 MEMORANDUM FOR THE ASSOCIATE ADMINISTRATOR FOR ACQUISITION AND PROJECT MANAGEMENT MANAGER LOS ALAMOS FIELD OFFICE FROM: David Sedillo Western Audits Division Office of Inspector General SUBJECT: INFORMATION: Audit Report on "The Radioactive Liquid Waste Treatment Facility Replacement Project at Los Alamos

  9. Building America Top Innovations 2013 Profile … Window Replacement, Rehabilitation, & Repair Guide

    Energy Savers [EERE]

    Window Replacement, Rehabilitation, & Repair Guide TOP INNOVATOR: BSC Old single-glazed windows have such low thermal resistance that their effect on the overall thermal resistance of the walls can be staggering. Building America recommends several ways to improve the performance of existing windows at varying price points. Owners of older homes who want to improve their homes' efficiency often conclude that window replacement is a necessary first step. They are right that windows can be a

  10. Avoiding a Train Wreck: Replacing Old Coal Plants with Energy Efficiency,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    August 2011 | Department of Energy Avoiding a Train Wreck: Replacing Old Coal Plants with Energy Efficiency, August 2011 Avoiding a Train Wreck: Replacing Old Coal Plants with Energy Efficiency, August 2011 This paper discusses the so-called "coal train wreck" which may afford an opportunity to modernize our electric utility regulations to reflect a new century of different economic and energy markets, creating opportunities for the utility industry to define a new path to

  11. Lithium metal reduction of plutonium oxide to produce plutonium metal

    DOE Patents [OSTI]

    Coops, Melvin S.

    1992-01-01

    A method is described for the chemical reduction of plutonium oxides to plutonium metal by the use of pure lithium metal. Lithium metal is used to reduce plutonium oxide to alpha plutonium metal (alpha-Pu). The lithium oxide by-product is reclaimed by sublimation and converted to the chloride salt, and after electrolysis, is removed as lithium metal. Zinc may be used as a solvent metal to improve thermodynamics of the reduction reaction at lower temperatures. Lithium metal reduction enables plutonium oxide reduction without the production of huge quantities of CaO--CaCl.sub.2 residues normally produced in conventional direct oxide reduction processes.

  12. Pacific Power - FinAnswer Express | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Cathode: 5 CFLs: 5 Ceramic Metal Halide: 35 Pulse Start Metal Halide: 20 - 60 Induction: 125 LEDs: 10 - 100 Lighting Controls: 15 - 75 LED Exit Signs: 15 LED Signs:...

  13. Better Buildings Alliance, adidas Case Study: adidas Saves Energy and Costs with Planned RTU Replacement Program (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2014-09-01

    Case study describing how adidas implemented a best practice of a planned replacement program for its RTUs.

  14. Electrochemical nitridation of metal surfaces

    DOE Patents [OSTI]

    Wang, Heli; Turner, John A.

    2015-06-30

    Electrochemical nitridation of metals and the produced metals are disclosed. An exemplary method of electrochemical nitridation of metals comprises providing an electrochemical solution at low temperature. The method also comprises providing a three-electrode potentiostat system. The method also comprises stabilizing the three-electrode potentiostat system at open circuit potential. The method also comprises applying a cathodic potential to a metal.

  15. AIR PASSIVATION OF METAL HYDRIDE BEDS FOR WASTE DISPOSAL

    SciTech Connect (OSTI)

    Klein, J; R. H. Hsu, R

    2007-07-02

    Metal hydride beds offer compact, safe storage of tritium. After metal hydride beds have reached the end of their useful life, the beds will replaced with new beds and the old beds prepared for disposal. One acceptance criteria for hydride bed waste disposal is that the material inside the bed not be pyrophoric. To determine the pyrophoric nature of spent metal hydride beds, controlled air ingress tests were performed. A simple gas handling manifold fitted with pressure transducers and a calibrated volume were used to introduce controlled quantities of air into a metal hydride bed and the bed temperature rise monitored for reactivity with the air. A desorbed, 4.4 kg titanium prototype hydride storage vessel (HSV) produced a 4.4 C internal temperature rise upon the first air exposure cycle and a 0.1 C temperature rise upon a second air exposure. A total of 346 scc air was consumed by the bed (0.08 scc per gram Ti). A desorbed, 9.66 kg LaNi{sub 4.25}Al{sub 0.75} prototype storage bed experienced larger temperature rises over successive cycles of air ingress and evacuation. The cycles were performed over a period of days with the bed effectively passivated after the 12th cycle. Nine to ten STP-L of air reacted with the bed producing both oxidized metal and water.

  16. Thermally tolerant multilayer metal membrane

    DOE Patents [OSTI]

    Dye, Robert C. (Los Alamos, NM); Snow, Ronny C. (Los Alamos, NM)

    2001-01-01

    A composite metal membrane including a first metal layer of a Group IVB or Group VB metal sandwiched between two layers of a Group VIIIB metal selected from the group consisting of palladium, platinum, nickel, rhodium, iridium, cobalt, and alloys thereof, and a non-continuous layer of a metal chalcogenide upon one layer of the Group VIIIB metal is disclosed together with a process for the recovery of hydrogen from a gaseous mixture using such a composite membrane and a process for forming such a composite metal membrane.

  17. PROCESS FOR PRODUCING URANIUM HALIDES

    DOE Patents [OSTI]

    Murphree, E.V.

    1957-10-29

    A process amd associated apparatus for producing UF/sub 4/ from U/sub 3/ O/sub 8/ by a fluidized'' technique are reported. The U/sub 3/O/sub 8/ is first reduced to UO/sub 2/ by reaction with hydrogen, and the lower oxide of uranium is then reacted with gaseous HF to produce UF/sub 4/. In each case the reactant gas is used, alone or in combination with inert gases, to fluidize'' the finely divided reactant solid. The complete setup of the plant equipment including bins, reactor and the associated piping and valving, is described. An auxiliary fluorination reactor allows for the direct production of UF/sub 6/ from UF/sub 4/ and fluorine gas, or if desired, UF/sub 4/ may be collected as the product.

  18. Method for forming metal contacts

    DOE Patents [OSTI]

    Reddington, Erik; Sutter, Thomas C; Bu, Lujia; Cannon, Alexandra; Habas, Susan E; Curtis, Calvin J; Miedaner, Alexander; Ginley, David S; Van Hest, Marinus Franciscus Antonius Maria

    2013-09-17

    Methods of forming metal contacts with metal inks in the manufacture of photovoltaic devices are disclosed. The metal inks are selectively deposited on semiconductor coatings by inkjet and aerosol apparatus. The composite is heated to selective temperatures where the metal inks burn through the coating to form an electrical contact with the semiconductor. Metal layers are then deposited on the electrical contacts by light induced or light assisted plating.

  19. Peroxotitanates for Biodelivery of Metals

    SciTech Connect (OSTI)

    Hobbs, David; Elvington, M.

    2009-02-11

    Metal-based drugs are largely undeveloped in pharmacology. One limiting factor is the systemic toxicity of metal-based compounds. A solid-phase, sequestratable delivery agent for local delivery of metals could reduce systemic toxicity, facilitating new drug development in this nascent area. Amorphous peroxotitanates (APT) are ion exchange materials with high affinity for several heavy metal ions, and have been proposed to deliver or sequester metal ions in biological contexts. In the current study, we tested a hypothesis that APT are able to deliver metals or metal compounds to cells. We exposed fibroblasts (L929) or monocytes (THP1) to metal-APT materials for 72 h in vitro, then measured cellular mitochondrial activity (SDH-MTT method) to assess the biological impact of the metal-APT materials vs. metals or APT alone. APT alone did not significantly affect cellular mitochondrial activity, but all metal-APT materials suppressed the mitochondrial activity of fibroblasts (by 30-65% of controls). The concentration of metal-APT materials required to suppress cellular mitochondrial activity was below that required for metals alone, suggesting that simple extracellular release of the metals from the metal-APT materials was not the primary mechanism of mitochondrial suppression. In contrast to fibroblasts, no metal-APT material had a measurable effect on THP1 monocyte mitochondrial activity, despite potent suppression by metals alone. This latter result suggested that 'biodelivery' by metal-APT materials may be cell type-specific. Therefore, it appears that APT are plausible solid phase delivery agents of metals or metal compounds to some types of cells for potential therapeutic effect.

  20. Liquid metal thermal electric converter

    DOE Patents [OSTI]

    Abbin, Joseph P.; Andraka, Charles E.; Lukens, Laurance L.; Moreno, James B.

    1989-01-01

    A liquid metal thermal electric converter which converts heat energy to electrical energy. The design of the liquid metal thermal electric converter incorporates a unique configuration which directs the metal fluid pressure to the outside of the tube which results in the structural loads in the tube to be compressive. A liquid metal thermal electric converter refluxing boiler with series connection of tubes and a multiple cell liquid metal thermal electric converter are also provided.

  1. Alkali metal ionization detector

    DOE Patents [OSTI]

    Bauerle, James E.; Reed, William H.; Berkey, Edgar

    1978-01-01

    Variations in the conventional filament and collector electrodes of an alkali metal ionization detector, including the substitution of helical electrode configurations for either the conventional wire filament or flat plate collector; or, the substitution of a plurality of discrete filament electrodes providing an in situ capability for transferring from an operationally defective filament electrode to a previously unused filament electrode without removing the alkali metal ionization detector from the monitored environment. In particular, the helical collector arrangement which is coaxially disposed about the filament electrode, i.e. the thermal ionizer, provides an improved collection of positive ions developed by the filament electrode. The helical filament design, on the other hand, provides the advantage of an increased surface area for ionization of alkali metal-bearing species in a monitored gas environment as well as providing a relatively strong electric field for collecting the ions at the collector electrode about which the helical filament electrode is coaxially positioned. Alternatively, both the filament and collector electrodes can be helical. Furthermore, the operation of the conventional alkali metal ionization detector as a leak detector can be simplified as to cost and complexity, by operating the detector at a reduced collector potential while maintaining the sensitivity of the alkali metal ionization detector adequate for the relatively low concentration of alkali vapor and aerosol typically encountered in leak detection applications.

  2. 10 CFR 830 Major Modification Determination for Emergency Firewater Injection System Replacement

    SciTech Connect (OSTI)

    Noel Duckwitz

    2011-05-01

    The continued safe and reliable operation of the ATR is critical to the Department of Energy (DOE) Office of Nuclear Energy (NE) mission. While ATR is safely fulfilling current mission requirements, a variety of aging and obsolescence issues challenge ATR engineering and maintenance personnel’s capability to sustain ATR over the long term. First documented in a series of independent assessments, beginning with an OA Environmental Safety and Health Assessment conducted in 2003, the issues were validated in a detailed Material Condition Assessment (MCA) conducted as a part of the ATR Life Extension Program in 2007.Accordingly, near term replacement of aging and obsolescent original ATR equipment has become important to ensure ATR capability in support of NE’s long term national missions. To that end, a mission needs statement has been prepared for a non-major system acquisition which is comprised of three interdependent sub-projects. The first project will replace the existent diesel-electrical bus (E-3), switchgear, and the fifty year old antiquated marine diesels with commercial power that is backed with safety-related emergency diesel generators (EDGs), switchgear, and uninterruptible power supply. The second project will replace the four, obsolete, original primary coolant pumps and motors. The third project, the subject of this major modification determination, will replace the current emergency firewater injection system (EFIS). The replacement water injection system will function as the primary emergency water injection system with the EFIS being retained as a defense-in-depth backup. Completion of this and the two other age-related projects (replacement of the ATR diesel bus (E-3) and switchgear and replacement of the existent aged primary coolant pumps and motors) will resolve major age-related operational issues plus make a significant contribution in sustaining the ATR safety and reliability profile. The major modification criteria evaluation of the project pre-conceptual design identified several issues that lead to the conclusion that the project is a major modification.

  3. METAL RESISTIVITY MEASURING DEVICE

    DOE Patents [OSTI]

    Renken, J. Jr.; Myers, R.G.

    1960-12-20

    An eddy current device is offered for detecting discontinuities in metal samples. Alternate short and long duration pulses are inductively applied to a metal sample via the outer coil of a probe. The long pulses give a resultant signal from the metal sample responsive to probe-tosample spacing and discontinuities within the sample and the shont pulses give a resultant signal responsive only to probe -to-sample spacing. The inner coil of the probe detects the two resultant signals and transmits them to a separation network where the two signals are separated. The two separated signals are then transmitted to a compensation network where the detected signals due to the short pulses are used to compensate for variations due to probe-to-sample spacing contained in the detected signals from the long pulses. Thus, a resultant signal is obtained responsive to discontinuities within the sample and independent of probe-to- sample spacing.

  4. Method for locating metallic nitride inclusions in metallic alloy ingots

    DOE Patents [OSTI]

    White, Jack C.; Traut, Davis E.; Oden, Laurance L.; Schmitt, Roman A.

    1992-01-01

    A method of determining the location and history of metallic nitride and/or oxynitride inclusions in metallic melts. The method includes the steps of labeling metallic nitride and/or oxynitride inclusions by making a coreduced metallic-hafnium sponge from a mixture of hafnium chloride and the chloride of a metal, reducing the mixed chlorides with magnesium, nitriding the hafnium-labeled metallic-hafnium sponge, and seeding the sponge to be melted with hafnium-labeled nitride inclusions. The ingots are neutron activated and the hafnium is located by radiometric means. Hafnium possesses exactly the proper metallurgical and radiochemical properties for this use.

  5. Hard metal composition

    DOE Patents [OSTI]

    Sheinberg, Haskell (Los Alamos, NM)

    1986-01-01

    A composition of matter having a Rockwell A hardness of at least 85 is formed from a precursor mixture comprising between 3 and 10 weight percent boron carbide and the remainder a metal mixture comprising from 70 to 90 percent tungsten or molybdenum, with the remainder of the metal mixture comprising nickel and iron or a mixture thereof. The composition has a relatively low density of between 7 to 14 g/cc. The precursor is preferably hot pressed to yield a composition having greater than 100% of theoretical density.

  6. Hard metal composition

    DOE Patents [OSTI]

    Sheinberg, H.

    1983-07-26

    A composition of matter having a Rockwell A hardness of at least 85 is formed from a precursor mixture comprising between 3 and 10 wt % boron carbide and the remainder a metal mixture comprising from 70 to 90% tungsten or molybdenum, with the remainder of the metal mixture comprising nickel and iron or a mixture thereof. The composition has a relatively low density of between 7 and 14 g/cc. The precursor is preferably hot pressed to yield a composition having greater than 100% of theoretical density.

  7. Liquid metal pump

    DOE Patents [OSTI]

    Pennell, William E.

    1982-01-01

    The liquid metal pump comprises floating seal rings and attachment of the pump diffuser to the pump bowl for isolating structural deflections from the pump shaft bearings. The seal rings also eliminate precision machining on large assemblies by eliminating the need for a close tolerance fit between the mounting surfaces of the pump and the seals. The liquid metal pump also comprises a shaft support structure that is isolated from the pump housing for better preservation of alignment of shaft bearings. The shaft support structure also allows for complete removal of pump internals for inspection and repair.

  8. Metal alloy identifier

    DOE Patents [OSTI]

    Riley, William D. (Avondale, MD); Brown, Jr., Robert D. (Avondale, MD)

    1987-01-01

    To identify the composition of a metal alloy, sparks generated from the alloy are optically observed and spectrographically analyzed. The spectrographic data, in the form of a full-spectrum plot of intensity versus wavelength, provide the "signature" of the metal alloy. This signature can be compared with similar plots for alloys of known composition to establish the unknown composition by a positive match with a known alloy. An alternative method is to form intensity ratios for pairs of predetermined wavelengths within the observed spectrum and to then compare the values of such ratios with similar values for known alloy compositions, thereby to positively identify the unknown alloy composition.

  9. Metallic carbon materials

    DOE Patents [OSTI]

    Cohen, Marvin Lou; Crespi, Vincent Henry; Louie, Steven Gwon Sheng; Zettl, Alexander Karlwalter

    1999-01-01

    Novel metallic forms of planar carbon are described, as well as methods of designing and making them. Nonhexagonal arrangements of carbon are introduced into a graphite carbon network essentially without destroying the planar structure. Specifically a form of carbon comprising primarily pentagons and heptagons, and having a large density of states at the Fermi level is described. Other arrangements of pentagons and heptagons that include some hexagons, and structures incorporating squares and octagons are additionally disclosed. Reducing the bond angle symmetry associated with a hexagonal arrangement of carbons increases the likelihood that the carbon material will have a metallic electron structure.

  10. GATEWAY Demonstrations: LED System Performance in a Trial Installation--One Year Later, Yuma Border Patrol, Yuma, Arizona

    SciTech Connect (OSTI)

    Wilkerson, A. M.; Davis, R. G.

    2015-04-01

    Along the Yuma Sector Border Patrol Area in Yuma, Arizona, the GATEWAY program conducted a trial demonstration in which the incumbent quartz metal halide area lighting was replaced with LED at three pole locations at the Yuma Sector Border Patrol Area in Yuma, Arizona. The retrofit was documented to better understand LED technology performance in high-temperature environments. This report follows the GATEWAY Yuma Phase 1.0 Report and reflects LED system results documented one year after the demonstration began.

  11. SSL Demonstration: Area Lighting, Yuma Sector Border Patrol Area, AZ

    SciTech Connect (OSTI)

    2015-05-28

    Along the Yuma Sector Border Patrol Area in Yuma, Arizona, the GATEWAY program conducted a trial demonstration in which the incumbent quartz metal halide area lighting was replaced with LED at three pole locations at the Yuma Sector Border Patrol Area in Yuma, Arizona. The retrofit was documented to better understand LED technology performance in high-temperature environments. This document is a summary brief of the Phase 1.0 and 1.1 reports previously published on this demonstration.

  12. Wick for metal vapor laser

    DOE Patents [OSTI]

    Duncan, David B. (Livermore, CA)

    1992-01-01

    An improved wick for a metal vapor laser is made of a refractory metal cylinder, preferably molybdenum or tungsten for a copper laser, which provides the wicking surface. Alternately, the inside surface of the ceramic laser tube can be metalized to form the wicking surface. Capillary action is enhanced by using wire screen, porous foam metal, or grooved surfaces. Graphite or carbon, in the form of chunks, strips, fibers or particles, is placed on the inside surface of the wick to reduce water, reduce metal oxides and form metal carbides.

  13. Lithium inclusion in indium metal-organic frameworks showing increased surface area and hydrogen adsorption

    SciTech Connect (OSTI)

    Bosch, Mathieu; Zhang, Muwei; Feng, Dawei; Yuan, Shuai; Wang, Xuan; Chen, Ying-Pin; Zhou, Hong-Cai

    2014-12-01

    Investigation of counterion exchange in two anionic In-Metal-Organic Frameworks (In-MOFs) showed that partial replacement of disordered ammonium cations was achieved through the pre-synthetic addition of LiOH to the reaction mixture. This resulted in a surface area increase of over 1600% in (Li [In(1,3 − BDC){sub 2}]){sub n} and enhancement of the H{sub 2} uptake of approximately 275% at 80 000 Pa at 77 K. This method resulted in frameworks with permanent lithium content after repeated solvent exchange as confirmed by inductively coupled plasma mass spectrometry. Lithium counterion replacement appears to increase porosity after activation through replacement of bulkier, softer counterions and demonstrates tuning of pore size and properties in MOFs.

  14. Metal Insertion in a Microporous Metal-Organic Framework Lined...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Metal Insertion in a Microporous Metal-Organic Framework Lined with 2,2 '-Bipyridine Previous Next List E. D. Bloch, D. Britt, C. Lee, C. J. Doonan, F. J. Uribe-Romo, H. Furukawa,...

  15. STRIPPING METAL COATINGS

    DOE Patents [OSTI]

    Siefen, H.T.; Campbell, J.M.

    1959-02-01

    A method is described for removing aluminumuranium-silicon alloy bonded to metallic U comprising subjecting the Al-U -Si alloy to treatment with hot concentrated HNO/sun 3/ to partially dissolve and embrittle the alloy and shot- blasting the embrittled alloy to loosen it from the U.

  16. Metal working lubricant compositions

    SciTech Connect (OSTI)

    Andress, H.J.; Davis, R.H.; Schick, J.W.

    1981-08-11

    A lubricant concentrate for use in metal processing comprises a sulfur compound such as a sulfurized olefin or sulfurized mineral oil and an ester prepared from a fatty acid having 12 to 40 carbon atoms or the dimer thereof or a polyalkenylsuccinic acid or anhydride and a hydroxyl-containing amine.

  17. Serpentine metal gasket

    DOE Patents [OSTI]

    Rothgeb, Timothy Moore; Reece, Charles Edwin

    2009-06-02

    A metallic seal or gasket for use in the joining of cryogenic fluid conduits, the seal or gasket having a generally planar and serpentine periphery defining a central aperture. According to a preferred embodiment, the periphery has at least two opposing elongated serpentine sides and two opposing arcuate ends joining the opposing elongated serpentine sides and is of a hexagonal cross-section.

  18. Metal halogen electrochemical cell

    DOE Patents [OSTI]

    Bellows, Richard J. (Hampton, NJ); Kantner, Edward (E. Brunswick, NJ)

    1988-08-23

    It has now been discovered that reduction in the coulombic efficiency of metal halogen cells can be minimized if the microporous separator employed in such cells is selected from one which is preferably wet by the aqueous electrolyte and is not wet substantially by the cathodic halogen.

  19. Ductile transplutonium metal alloys

    DOE Patents [OSTI]

    Conner, W.V.

    1981-10-09

    Alloys of Ce with transplutonium metals such as Am, Cm, Bk and Cf have properties making them highly suitable as souces of the transplutonium element, e.g., for use in radiation detector technology or as radiation sources. The alloys are ductile, homogeneous, easy to prepare and have a fairly high density.

  20. Ductile transplutonium metal alloys

    DOE Patents [OSTI]

    Conner, William V.

    1983-01-01

    Alloys of Ce with transplutonium metals such as Am, Cm, Bk and Cf have properties making them highly suitable as sources of the transplutonium element, e.g., for use in radiation detector technology or as radiation sources. The alloys are ductile, homogeneous, easy to prepare and have a fairly high density.

  1. Study: Algae Could Replace 17% of U.S. Oil Imports | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Study: Algae Could Replace 17% of U.S. Oil Imports Study: Algae Could Replace 17% of U.S. Oil Imports April 13, 2011 - 6:30pm Addthis Algae samples back at the NREL lab, ready to be analyzed and run through the Fluorescent-Activated Cell Sorter, or FACS, which separates the cells. | Credit: NREL Staff Photographer Dennis Schroeder. Algae samples back at the NREL lab, ready to be analyzed and run through the Fluorescent-Activated Cell Sorter, or FACS, which separates the cells. | Credit: NREL

  2. The How's and Why's of Replacing the Whole Barrel | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The How's and Why's of Replacing the Whole Barrel The How's and Why's of Replacing the Whole Barrel October 19, 2011 - 4:09pm Addthis A 42-U.S. gallon barrel of crude oil yields about 45 gallons of petroleum products. Source: Energy Information Administration, “Oil: Crude Oil and Petroleum Products Explained” and Annual Energy Outlook 2009 (Updated February 2010). A 42-U.S. gallon barrel of crude oil yields about 45 gallons of petroleum products. Source: Energy Information

  3. Monitoring Galvanic Replacement of Ag Nanoparticles by Pd using Low Dose In

    Office of Scientific and Technical Information (OSTI)

    Situ Liquid S/TEM. (Conference) | SciTech Connect Conference: Monitoring Galvanic Replacement of Ag Nanoparticles by Pd using Low Dose In Situ Liquid S/TEM. Citation Details In-Document Search Title: Monitoring Galvanic Replacement of Ag Nanoparticles by Pd using Low Dose In Situ Liquid S/TEM. Abstract not provided. Authors: Jungjohann, Katherine Leigh Publication Date: 2013-08-01 OSTI Identifier: 1106551 Report Number(s): SAND2013-6522C 465022 DOE Contract Number: AC04-94AL85000 Resource

  4. Reminder: Y-12 Public Warning Siren System being replaced, tested | Y-12

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Security Complex Reminder: Y-12 Public ... Reminder: Y-12 Public Warning Siren System being replaced, tested Posted: September 25, 2012 - 12:55pm The Y-12 Public Warning Siren System (PWSS) located around the Oak Ridge area is being replaced this month with a test of the new system on Sept. 26. The vendor, American Signal, will be testing the sirens Sept. 26 between 10 a.m. and 2 p.m. They may sound sirens multiple times during this window, and they probably will sound each siren

  5. Method of producing adherent metal oxide coatings on metallic surfaces

    DOE Patents [OSTI]

    Lane, Michael H. (Clifton Park, NY); Varrin, Jr., Robert D. (McLean, VA)

    2001-01-01

    Provided is a process of producing an adherent synthetic corrosion product (sludge) coating on metallic surfaces. The method involves a chemical reaction between a dry solid powder mixture of at least one reactive metal oxide with orthophosphoric acid to produce a coating in which the particles are bound together and the matrix is adherent to the metallic surface.

  6. Purification of alkali metal nitrates

    DOE Patents [OSTI]

    Fiorucci, Louis C.; Gregory, Kevin M.

    1985-05-14

    A process is disclosed for removing heavy metal contaminants from impure alkali metal nitrates containing them. The process comprises mixing the impure nitrates with sufficient water to form a concentrated aqueous solution of the impure nitrates, adjusting the pH of the resulting solution to within the range of between about 2 and about 7, adding sufficient reducing agent to react with heavy metal contaminants within said solution, adjusting the pH of the solution containing reducing agent to effect precipitation of heavy metal impurities and separating the solid impurities from the resulting purified aqueous solution of alkali metal nitrates. The resulting purified solution of alkali metal nitrates may be heated to evaporate water therefrom to produce purified molten alkali metal nitrate suitable for use as a heat transfer medium. If desired, the purified molten form may be granulated and cooled to form discrete solid particles of alkali metal nitrates.

  7. Upgrading platform using alkali metals

    SciTech Connect (OSTI)

    Gordon, John Howard

    2014-09-09

    A process for removing sulfur, nitrogen or metals from an oil feedstock (such as heavy oil, bitumen, shale oil, etc.) The method involves reacting the oil feedstock with an alkali metal and a radical capping substance. The alkali metal reacts with the metal, sulfur or nitrogen content to form one or more inorganic products and the radical capping substance reacts with the carbon and hydrogen content to form a hydrocarbon phase. The inorganic products may then be separated out from the hydrocarbon phase.

  8. SURFACE TREATMENT OF METALLIC URANIUM

    DOE Patents [OSTI]

    Gray, A.G.; Schweikher, E.W.

    1958-05-27

    The treatment of metallic uranium to provide a surface to which adherent electroplates can be applied is described. Metallic uranium is subjected to an etchant treatment in aqueous concentrated hydrochloric acid, and the etched metal is then treated to dissolve the resulting black oxide and/or chloride film without destroying the etched metal surface. The oxide or chloride removal is effected by means of moderately concentrated nitric acid in 3 to 20 seconds.

  9. Electroless metal plating of plastics

    DOE Patents [OSTI]

    Krause, Lawrence J.

    1984-01-01

    Process for plating main group metals on aromatic polymers is carried out by the use of a nonaqueous solution of a salt of an alkali metal in a positive valence state and a main group metal in a negative valence state with contact between the solution and polymer providing a redox reaction causing the deposition of the main group metal and the reduction of the polymer. Products from the process exhibit useful decorative and electrical properties.

  10. Electroless metal plating of plastics

    DOE Patents [OSTI]

    Krause, Lawrence J.

    1986-01-01

    Process for plating main group metals on aromatic polymers is carried out by the use of a nonaqueous solution of a salt of an alkali metal in a positive valence state and a main group metal in a negative valence state with contact between the solution and polymer providing a redox reaction causing the deposition of the main group metal and the reduction of the polymer. Products from the process exhibit useful decorative and electrical properties.

  11. Electroless metal plating of plastics

    DOE Patents [OSTI]

    Krause, L.J.

    1982-09-20

    Process for plating main group metals on aromatic polymers is carried out by the use of a nonaqueous solution of a salt of an alkali metal in a positive valence state and a main group metal in a negative valence state with contact between the solution and polymer providing a redox reaction causing the deposition of the main group metal and the reduction of the polymer. Products from the process exhibit useful decorative and electrical properties.

  12. Methods of recovering alkali metals

    DOE Patents [OSTI]

    Krumhansl, James L; Rigali, Mark J

    2014-03-04

    Approaches for alkali metal extraction, sequestration and recovery are described. For example, a method of recovering alkali metals includes providing a CST or CST-like (e.g., small pore zeolite) material. The alkali metal species is scavenged from the liquid mixture by the CST or CST-like material. The alkali metal species is extracted from the CST or CST-like material.

  13. Passive cooling system for top entry liquid metal cooled nuclear reactors

    DOE Patents [OSTI]

    Boardman, Charles E.; Hunsbedt, Anstein; Hui, Marvin M.

    1992-01-01

    A liquid metal cooled nuclear fission reactor plant having a top entry loop joined satellite assembly with a passive auxiliary safety cooling system for removing residual heat resulting from fuel decay during shutdown, or heat produced during a mishap. This satellite type reactor plant is enhanced by a backup or secondary passive safety cooling system which augments the primary passive auxiliary cooling system when in operation, and replaces the primary cooling system when rendered inoperative.

  14. Passive cooling system for liquid metal cooled nuclear reactors with backup coolant flow path

    DOE Patents [OSTI]

    Hunsbedt, Anstein; Boardman, Charles E.

    1993-01-01

    A liquid metal cooled nuclear fission reactor plant having a passive auxiliary safety cooling system for removing residual heat resulting from fuel decay during reactor shutdown, or heat produced during a mishap. This reactor plant is enhanced by a backup or secondary passive safety cooling system which augments the primary passive auxiliary cooling system when in operation, and replaces the primary system when rendered inoperable.

  15. Inert electrode containing metal oxides, copper and noble metal

    DOE Patents [OSTI]

    Ray, Siba P.; Woods, Robert W.; Dawless, Robert K.; Hosler, Robert B.

    2000-01-01

    A cermet composite material is made by treating at an elevated temperature a mixture comprising a compound of iron and a compound of at least one other metal, together with an alloy or mixture of copper and a noble metal. The alloy or mixture preferably comprises particles having an interior portion containing more copper than noble metal and an exterior portion containing more noble metal than copper. The noble metal is preferably silver. The cermet composite material preferably includes alloy phase portions and a ceramic phase portion. At least part of the ceramic phase portion preferably has a spinel structure.

  16. Inert electrode containing metal oxides, copper and noble metal

    DOE Patents [OSTI]

    Ray, Siba P.; Woods, Robert W.; Dawless, Robert K.; Hosler, Robert B.

    2001-01-01

    A cermet composite material is made by treating at an elevated temperature a mixture comprising a compound of iron and a compound of at least one other metal, together with an alloy or mixture of copper and a noble metal. The alloy or mixture preferably comprises particles having an interior portion containing more copper than noble metal and an exterior portion containing more noble metal than copper. The noble metal is preferably silver. The cermet composite material preferably includes alloy phase portions and a ceramic phase portion. At least part of the ceramic phase portion preferably has a spinel structure.

  17. Metals processing control by counting molten metal droplets

    DOE Patents [OSTI]

    Schlienger, Eric; Robertson, Joanna M.; Melgaard, David; Shelmidine, Gregory J.; Van Den Avyle, James A.

    2000-01-01

    Apparatus and method for controlling metals processing (e.g., ESR) by melting a metal ingot and counting molten metal droplets during melting. An approximate amount of metal in each droplet is determined, and a melt rate is computed therefrom. Impedance of the melting circuit is monitored, such as by calculating by root mean square a voltage and current of the circuit and dividing the calculated current into the calculated voltage. Analysis of the impedance signal is performed to look for a trace characteristic of formation of a molten metal droplet, such as by examining skew rate, curvature, or a higher moment.

  18. Integrated decontamination process for metals

    DOE Patents [OSTI]

    Snyder, Thomas S.; Whitlow, Graham A.

    1991-01-01

    An integrated process for decontamination of metals, particularly metals that are used in the nuclear energy industry contaminated with radioactive material. The process combines the processes of electrorefining and melt refining to purify metals that can be decontaminated using either electrorefining or melt refining processes.

  19. Fabrication of metallic glass structures

    DOE Patents [OSTI]

    Cline, C.F.

    1983-10-20

    Amorphous metal powders or ribbons are fabricated into solid shapes of appreciable thickness by the application of compaction energy. The temperature regime wherein the amorphous metal deforms by viscous flow is measured. The metal powders or ribbons are compacted within the temperature regime.

  20. FLUIDIC: Metal Air Recharged

    ScienceCinema (OSTI)

    Friesen, Cody

    2014-04-02

    Fluidic, with the help of ARPA-E funding, has developed and deployed the world's first proven high cycle life metal air battery. Metal air technology, often used in smaller scale devices like hearing aids, has the lowest cost per electron of any rechargeable battery storage in existence. Deploying these batteries for grid reliability is competitive with pumped hydro installations while having the advantages of a small footprint. Fluidic's battery technology allows utilities and other end users to store intermittent energy generated from solar and wind, as well as maintain reliable electrical delivery during power outages. The batteries are manufactured in the US and currently deployed to customers in emerging markets for cell tower reliability. As they continue to add customers, they've gained experience and real world data that will soon be leveraged for US grid reliability.

  1. FLUIDIC: Metal Air Recharged

    SciTech Connect (OSTI)

    Friesen, Cody

    2014-03-07

    Fluidic, with the help of ARPA-E funding, has developed and deployed the world's first proven high cycle life metal air battery. Metal air technology, often used in smaller scale devices like hearing aids, has the lowest cost per electron of any rechargeable battery storage in existence. Deploying these batteries for grid reliability is competitive with pumped hydro installations while having the advantages of a small footprint. Fluidic's battery technology allows utilities and other end users to store intermittent energy generated from solar and wind, as well as maintain reliable electrical delivery during power outages. The batteries are manufactured in the US and currently deployed to customers in emerging markets for cell tower reliability. As they continue to add customers, they've gained experience and real world data that will soon be leveraged for US grid reliability.

  2. Fabrication of metal shells

    SciTech Connect (OSTI)

    O'Holleran, T.P.; Henderson, T.M.; Downs, R.L.; Nolen, R.L.

    1980-01-01

    Small hollow metal spheres are needed as targets for particle-beam fusion experiments and as the inner fuel container for multi-shell targets. For the multishell application, shells fabricated of materials with high atomic numbers, e.g., gold, are of particular interest because they may effectively reduce preheating of the fuel. Because the shells must also contain the fuel mixture (deuterium and tritium) at high pressures, high strength materials, e.g., iron, are also of considerable interest. With the objective of proof of principle we have investigated several techniques of fabricating shells of metal or materials containing large fractions of high atomic number elements. These techniques, our experimental results and their evaluation are presented.

  3. Conformationally constrained farnesoid X receptor (FXR) agonists: Heteroaryl replacements of the naphthalene

    SciTech Connect (OSTI)

    Bass, Jonathan Y.; Caravella, Justin A.; Chen, Lihong; Creech, Katrina L.; Deaton, David N.; Madauss, Kevin P.; Marr, Harry B.; McFadyen, Robert B.; Miller, Aaron B.; Mills, Wendy Y.; Navas, III, Frank; Parks, Derek J.; Smalley, Jr., Terrence L.; Spearing, Paul K.; Todd, Dan; Williams, Shawn P.; Wisely, G. Bruce

    2014-08-13

    To improve on the drug properties of GSK8062 1b, a series of heteroaryl bicyclic naphthalene replacements were prepared. The quinoline 1c was an equipotent FXR agonist with improved drug developability parameters relative to 1b. In addition, analog 1c lowered body weight gain and serum glucose in a DIO mouse model of diabetes.

  4. The feasibility of replacing or upgrading utility distribution transformers during routine maintenance

    SciTech Connect (OSTI)

    Barnes, P.R.; Van Dyke, J.W.; McConnell, B.W.; Cohn, S.M.; Purucker, S.L.

    1995-04-01

    It is estimated that electric utilities use about 40 million distribution transformers in supplying electricity to customers in the United States. Although utility distribution transformers collectively have a high average efficiency, they account for approximately 61 billion kWh of the 229 billion kWh of energy lost annually in the delivery of electricity. Distribution transformers are being replaced over time by new, more efficient, lower-loss units during routine utility maintenance of power distribution systems. Maintenance is typically not performed on units in service. However, units removed from service with appreciable remaining life are often refurbished and returned to stock. Distribution transformers may be removed from service for many reasons, including failure, over- or underloading, or line upgrades such as voltage changes or rerouting. When distribution transformers are removed from service, a decision must be made whether to dispose of the transformer and purchase a lower-loss replacement or to refurbish the transformer and return it to stock for future use. This report contains findings and recommendations on replacing utility distribution transformers during routine maintenance, which is required by section 124(c) of the Energy Policy Act of 1992. The objectives of the study are to evaluate the practicability, cost-effectiveness, and potential energy savings of replacing or upgrading existing transformers during routine utility maintenance and to develop recommendations on was to achieve the potential energy savings.

  5. EA-1994: Malheur Resource Area Jonesboro Diversion Dam Replacement Project, Malheur County, Oregon

    Broader source: Energy.gov [DOE]

    The Bureau of Land Management, with the Bonneville Power Administration (BPA) as a cooperating agency, prepared an EA that assesses the potential environmental impacts of the proposed authorization of a right of way to the Burns Paiute Tribe for replacement of an existing diversion dam and installation of a fish passage structure. BPA’s proposed action was to fund the project

  6. Measure Guideline. Replacing Single-Speed Pool Pumps with Variable Speed Pumps for Energy Savings

    SciTech Connect (OSTI)

    Hunt, A.; Easley, S.

    2012-05-01

    This measure guideline evaluates potential energy savings by replacing traditional single-speed pool pumps with variable speed pool pumps, and provides a basic cost comparison between continued uses of traditional pumps verses new pumps. A simple step-by-step process for inspecting the pool area and installing a new pool pump follows.

  7. Measure Guideline: Replacing Single-Speed Pool Pumps with Variable Speed Pumps for Energy Savings

    SciTech Connect (OSTI)

    Hunt, A.; Easley, S.

    2012-05-01

    The report evaluates potential energy savings by replacing traditional single-speed pool pumps with variable speed pool pumps, and provide a basic cost comparison between continued uses of traditional pumps verses new pumps. A simple step-by-step process for inspecting the pool area and installing a new pool pump follows.

  8. METAL COATING BATHS

    DOE Patents [OSTI]

    Robinson, J.W.

    1958-08-26

    A method is presented for restoring the effectiveness of bronze coating baths used for hot dip coating of uranium. Such baths, containing a high proportion of copper, lose their ability to wet uranium surfaces after a period of use. The ability of such a bath to wet uranium can be restored by adding a small amount of metallic aluminum to the bath, and skimming the resultant hard alloy from the surface.

  9. Amorphous metal alloy

    DOE Patents [OSTI]

    Wang, R.; Merz, M.D.

    1980-04-09

    Amorphous metal alloys of the iron-chromium and nickel-chromium type have excellent corrosion resistance and high temperature stability and are suitable for use as a protective coating on less corrosion resistant substrates. The alloys are stabilized in the amorphous state by one or more elements of titanium, zirconium, hafnium, niobium, tantalum, molybdenum, and tungsten. The alloy is preferably prepared by sputter deposition.

  10. Spray casting of metallic preforms

    DOE Patents [OSTI]

    Flinn, John E.; Burch, Joseph V.; Sears, James W.

    2000-01-01

    A metal alloy is melted in a crucible and ejected from the bottom of the crucible as a descending stream of molten metal. The descending stream is impacted with a plurality of primary inert gas jets surrounding the molten metal stream to produce a plume of atomized molten metal droplets. An inert gas is blown onto a lower portion of the plume with a plurality of auxiliary inert gas jets to deflect the plume into a more restricted pattern of high droplet density, thereby substantially eliminating unwanted overspray and resulting wasted material. The plume is projected onto a moving substrate to form a monolithic metallic product having generally parallel sides.

  11. Promoting plumbing fixture and fitting replacement: Recommendations and review for state and local water resource authorities

    SciTech Connect (OSTI)

    Dunham, C.; Lutz, J.D.; Pickle, S.J.

    1995-06-01

    Lawrence Berkeley National Laboratory (LBNL) has prepared this report to facilitate compliance with the requirements of Section 123 of the Energy Policy Act of 1992 (EPACT). Section 123 requires the Department of Energy to issue recommendations for establishing state and local incentive programs to encourage acceleration of voluntary consumer replacement of existing water closets, urinals, showerheads and faucets with water-saving products meeting EPACT standards. The authors recommend that state and local authorities working together and also with utilities: (A) investigate the cost-effectiveness of voluntary replacement of plumbing fixtures and fittings as an effective component of a water efficiency incentive program; (B) allow utilities to distribute the costs of water saving products by billing at pre-installation rates until devices have been paid for; (C) encourage decreased water usage by establishing rate structures such as increasing block rates or seasonal pricing; (D) add additional incentive to rebate programs by making the rebates untaxable income. (E) require municipalities or utilities to exhaust every reasonable method of water conservation before applying for permits to construct water supply or water treatment systems; (F) require high-efficiency toilets, urinals, showerheads, and faucets in new construction and changing plumbing codes to incorporate different pipe sizing needs; and (G) and mandate installation of meters to correctly measure water consumption. Following the introduction, a general overview of these recommendations is presented. Each recommendation is discussed briefly. After determining the cost-effectiveness of a plumbing replacement program (or plumbing replacement aspect of a larger program) states can encourage replacement of toilets, urinals, showerheads, and faucets in a number of ways. This report lists both legislative and economic measures that can be implemented on the state level that impact local programs.

  12. Hydrothermal alkali metal recovery process

    DOE Patents [OSTI]

    Wolfs, Denise Y.; Clavenna, Le Roy R.; Eakman, James M.; Kalina, Theodore

    1980-01-01

    In a coal gasification operation or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein solid particles containing alkali metal residues are produced, alkali metal constituents are recovered from the particles by treating them with a calcium or magnesium-containing compound in the presence of water at a temperature between about 250.degree. F. and about 700.degree. F. and in the presence of an added base to establish a pH during the treatment step that is higher than would otherwise be possible without the addition of the base. During the treating process the relatively high pH facilitates the conversion of water-insoluble alkali metal compounds in the alkali metal residues into water-soluble alkali metal constituents. The resultant aqueous solution containing water-soluble alkali metal constituents is then separated from the residue solids, which consist of the treated particles and any insoluble materials formed during the treatment step, and recycled to the gasification process where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst. Preferably, the base that is added during the treatment step is an alkali metal hydroxide obtained by water washing the residue solids produced during the treatment step.

  13. Dimensionally stable metallic hydride composition

    DOE Patents [OSTI]

    Heung, Leung K.

    1994-01-01

    A stable, metallic hydride composition and a process for making such a composition. The composition comprises a uniformly blended mixture of a metal hydride, kieselguhr, and a ballast metal, all in the form of particles. The composition is made by subjecting a metal hydride to one or more hydrogen absorption/desorption cycles to disintegrate the hydride particles to less than approximately 100 microns in size. The particles are partly oxidized, then blended with the ballast metal and the kieselguhr to form a uniform mixture. The mixture is compressed into pellets and calcined. Preferably, the mixture includes approximately 10 vol. % or more kieselguhr and approximately 50 vol. % or more ballast. Metal hydrides that can be used in the composition include Zr, Ti, V, Nb, Pd, as well as binary, tertiary, and more complex alloys of La, Al, Cu, Ti, Co, Ni, Fe, Zr, Mg, Ca, Mn, and mixtures and other combinations thereof. Ballast metals include Al, Cu and Ni.

  14. Reduction of Metal Oxide to Metal using Ionic Liquids

    SciTech Connect (OSTI)

    Dr. Ramana Reddy

    2012-04-12

    A novel pathway for the high efficiency production of metal from metal oxide means of electrolysis in ionic liquids at low temperature was investigated. The main emphasis was to eliminate the use of carbon and high temperature application in the reduction of metal oxides to metals. The emphasis of this research was to produce metals such as Zn, and Pb that are normally produced by the application of very high temperatures. The reduction of zinc oxide to zinc and lead oxide to lead were investigated. This study involved three steps in accomplishing the final goal of reduction of metal oxide to metal using ionic liquids: 1) Dissolution of metal oxide in an ionic liquid, 2) Determination of reduction potential using cyclic voltammetry (CV) and 3) Reduction of the dissolved metal oxide. Ionic liquids provide additional advantage by offering a wide potential range for the deposition. In each and every step of the process, more than one process variable has been examined. Experimental results for electrochemical extraction of Zn from ZnO and Pb from PbO using eutectic mixtures of Urea ((NH2)2CO) and Choline chloride (HOC2H4N(CH3)3+Cl-) or (ChCl) in a molar ratio 2:1, varying voltage and temperatures were carried out. Fourier Transform Infra-Red (FTIR) spectroscopy studies of ionic liquids with and without metal oxide additions were conducted. FTIR and induction coupled plasma spectroscopy (ICPS) was used in the characterization of the metal oxide dissolved ionic liquid. Electrochemical experiments were conducted using EG&G potentiostat/galvanostat with three electrode cell systems. Cyclic voltammetry was used in the determination of reduction potentials for the deposition of metals. Chronoamperometric experiments were carried out in the potential range of -0.6V to -1.9V for lead and -1.4V to -1.9V for zinc. The deposits were characterized using XRD and SEM-EDS for phase, morphological and elemental analysis. The results showed that pure metal was deposited on the cathode. Successful extraction of metal from metal oxide dissolved in Urea/ChCl (2:1) was accomplished. The current efficiencies were relatively high in both the metal deposition processes with current efficiency greater than 86% for lead and 95% for zinc. This technology will advance the metal oxide reduction process by increasing the process efficiency and also eliminate the production of CO2 which makes this an environmentally benign technology for metal extraction.

  15. Corrosion protective coating for metallic materials

    DOE Patents [OSTI]

    Buchheit, R.G.; Martinez, M.A.

    1998-05-26

    Corrosion protective coatings for metallic materials, particularly aluminum and aluminum alloys, produced with simple, low-cost equipment and materials other than toxic metals or metal salts, or metal cyanides is disclosed. The metallic material is cleaned, degreased, and deoxidized, the surface is converted to a substantially alkaline condition, and the surface is chemically sealed with inorganic metal compounds. 1 fig.

  16. Corrosion protective coating for metallic materials

    DOE Patents [OSTI]

    Buchheit, Rudolph G.; Martinez, Michael A.

    1998-01-01

    Corrosion protective coatings for metallic materials, particularly aluminum and aluminum alloys, produced with simple, low-cost equipment and materials other than toxic metals or metal salts, or metal cyanides. The metallic material is cleaned, degreased, and deoxidized, the surface is converted to a substantially alkaline condition, and the surface is chemically sealed with inorganic metal compounds.

  17. 10 CFR 830 Major Modification Determination for the ATR Diesel Bus (E-3) and Switchgear Replacement

    SciTech Connect (OSTI)

    Noel Duckwtiz

    2011-05-01

    Near term replacement of aging and obsolescent original ATR equipment has become important to ensure ATR capability in support of NE’s long term national missions. To that end, a mission needs statement has been prepared for a non-major system acquisition which is comprised of three interdependent subprojects. The first project, subject of this determination, will replace the existent diesel-electrical bus (E-3) and associated switchgear. More specifically, INL proposes transitioning ATR to 100% commercial power with appropriate emergency backup to include: • Provide commercial power as the normal source of power to the ATR loads currently supplied by diesel-electric power. • Provide backup power to the critical ATR loads in the event of a loss of commercial power. • Replace obsolescent critical ATR power distribution equipment, e.g., switchgear, transformers, motor control centers, distribution panels. Completion of this and two other age-related projects (primary coolant pump and motor replacement and emergency firewater injection system replacement) will resolve major age related operational issues plus make a significant contribution in sustaining the ATR safety and reliability profile. The major modification criteria evaluation of the project pre-conceptual design identified several issues make the project a major modification: 1. Evaluation Criteria #2 (Footprint change). The addition of a new PC-4 structure to the ATR Facility to house safety-related SSCs requires careful attention to maintaining adherence to applicable engineering and nuclear safety design criteria (e.g., structural qualification, fire suppression) to ensure no adverse impacts to the safety-related functions of the housed equipment. 2. Evaluation Criteria #3 (Change of existing process). The change to the strategy for providing continuous reliable power to the safety-related emergency coolant pumps requires careful attention and analysis to ensure it meets a project primary object to maintain or reduce CDF and does not negatively affect the efficacy of the currently approved strategy. 3. Evaluation Criteria #5 (Create the need for new or revised safety SSCs). The change to the strategy for providing continuous reliable power to the safety-related emergency coolant pumps, based on the pre-conceptual design, will require the addition of two quick start diesel generators, their associated power coordination/distribution controls, and a UPS to the list of safety-related SSCs. Similarly to item 1 above, the addition of these active SSCs to the list of safety-related SSCs and replacement of the E-3 bus requires careful attention to maintaining adherence to applicable engineering and nuclear safety design criteria (e.g., seismic qualification, isolation of redundant trains from common fault failures) to ensure no adverse impacts to the safety-related functions.

  18. Metal-doped organic foam and method of making same. [Patent application

    DOE Patents [OSTI]

    Rinde, J.A.

    Organic foams having a low density and very small cell size and method for producing same in either a metal-loaded or unloaded (nonmetal loaded) form are described. Metal-doped foams are produced by soaking a polymer gel in an aqueous solution of desired metal salt, soaking the gel successively in a solvent series of decreasing polarity to remove water from the gel and replace it with a solvent of lower polarity with each successive solvent in the series being miscible with the solvents on each side and being saturated with the desired metal salt, and removing the last of the solvents from the gel to produce the desired metal-doped foam having desired density cell size, and metal loading. The unloaded or metal-doped foams can be utilized in a variety of applications requiring low density, small cell size foam. For example, rubidium-doped foam made in accordance with the invention has utility in special applications, such as in x-ray lasers.

  19. Metal nanoparticle inks

    DOE Patents [OSTI]

    Lewis, Jennifer A.; Ahn, Bok Yeop; Duoss, Eric B.

    2011-04-12

    Stabilized silver particles comprise particles comprising silver, a short-chain capping agent adsorbed on the particles, and a long-chain capping agent adsorbed on the particles. The short-chain capping agent is a first anionic polyelectrolyte having a molecular weight (Mw) of at most 10,000, and the long-chain capping agent is a second anionic polyelectrolyte having a molecular weight (Mw) of at least 25,000. The stabilized silver particles have a solid loading of metallic silver of at least 50 wt %.

  20. Sumitomo Metal Industries Ltd Sumitomo Metals | Open Energy Informatio...

    Open Energy Info (EERE)

    Industries Ltd (Sumitomo Metals) Place: Osaka-shi, Osaka, Japan Zip: 540-0041 Sector: Solar Product: Engaged in the steel, engineering, and electronics businesses; works on...

  1. Construction and operation of replacement hazardous waste handling facility at Lawrence Berkeley Laboratory. Environmental Assessment

    SciTech Connect (OSTI)

    Not Available

    1992-09-01

    The US Department of Energy (DOE) has prepared an environmental assessment (EA), DOE/EA-0423, for the construction and operation of a replacement hazardous waste handling facility (HWHF) and decontamination of the existing HWHF at Lawrence Berkeley Laboratory (LBL), Berkeley, California. The proposed facility would replace several older buildings and cargo containers currently being used for waste handling activities and consolidate the LBL`s existing waste handling activities in one location. The nature of the waste handling activities and the waste volume and characteristics would not change as a result of construction of the new facility. Based on the analysis in the EA, DOE has determined that the proposed action would not constitute a major Federal action significantly affecting the quality of the human environment within the meaning of the National Environmental Policy Act (NEPA) of 1969, 42 USC. 4321 et seq. Therefore, an environmental impact statement is not required.

  2. Compliant mechanism road bicycle brake: a rigid-body replacement case study

    SciTech Connect (OSTI)

    Olsen, Brian M; Howell, Larry L; Magleby, Spencer P

    2011-01-19

    The design of high-performance bicycle brakes is complicated by the competing design objectives of increased performance and low weight. But this challenge also provides a good case study to demonstrate the design of compliant mechanisms to replace current rigid-link mechanisms. This paper briefly reviews current road brake designs, demonstrates the use of rigid-body replacement synthesis to design a compliant mechanism, and illustrates the combination of compliant mechanism design tools. The resulting concept was generated from the modified dual-pivot brake design and is a partially compliant mechanism where one pin has the dual role of a joint and a mounting pin. The pseudo-rigid-body model, finite element analysis, and optimization algorithms are used to generate design dimensions, and designs are considered for both titanium and E-glass flexures. The resulting design has the potential of reducing the part count and overall weight while maintaining a performance similar to the benchmark.

  3. Clean Metal Casting

    SciTech Connect (OSTI)

    Makhlouf M. Makhlouf; Diran Apelian

    2002-02-05

    The objective of this project is to develop a technology for clean metal processing that is capable of consistently providing a metal cleanliness level that is fit for a given application. The program has five tasks: Development of melt cleanliness assessment technology, development of melt contamination avoidance technology, development of high temperature phase separation technology, establishment of a correlation between the level of melt cleanliness and as cast mechanical properties, and transfer of technology to the industrial sector. Within the context of the first task, WPI has developed a standardized Reduced Pressure Test that has been endorsed by AFS as a recommended practice. In addition, within the context of task1, WPI has developed a melt cleanliness sensor based on the principles of electromagnetic separation. An industrial partner is commercializing the sensor. Within the context of the second task, WPI has developed environmentally friendly fluxes that do not contain fluorine. Within the context of the third task, WPI modeled the process of rotary degassing and verified the model predictions with experimental data. This model may be used to optimize the performance of industrial rotary degassers. Within the context of the fourth task, WPI has correlated the level of melt cleanliness at various foundries, including a sand casting foundry, a permanent mold casting foundry, and a die casting foundry, to the casting process and the resultant mechanical properties. This is useful in tailoring the melt cleansing operations at foundries to the particular casting process and the desired properties of cast components.

  4. Metals removal from spent salts

    DOE Patents [OSTI]

    Hsu, Peter C.; Von Holtz, Erica H.; Hipple, David L.; Summers, Leslie J.; Brummond, William A.; Adamson, Martyn G.

    2002-01-01

    A method and apparatus for removing metal contaminants from the spent salt of a molten salt oxidation (MSO) reactor is described. Spent salt is removed from the reactor and analyzed to determine the contaminants present and the carbonate concentration. The salt is dissolved in water, and one or more reagents may be added to precipitate the metal oxide and/or the metal as either metal oxide, metal hydroxide, or as a salt. The precipitated materials are filtered, dried and packaged for disposal as waste or can be immobilized as ceramic pellets. More than about 90% of the metals and mineral residues (ashes) present are removed by filtration. After filtration, salt solutions having a carbonate concentration >20% can be spray-dried and returned to the reactor for re-use. Salt solutions containing a carbonate concentration <20% require further clean-up using an ion exchange column, which yields salt solutions that contain less than 1.0 ppm of contaminants.

  5. Metal to ceramic sealed joint

    DOE Patents [OSTI]

    Lasecki, J.V.; Novak, R.F.; McBride, J.R.

    1991-08-27

    A metal to ceramic sealed joint which can withstand wide variations in temperature and maintain a good seal is provided for use in a device adapted to withstand thermal cycling from about 20 to about 1000 degrees C. The sealed joint includes a metal member, a ceramic member having an end portion, and an active metal braze forming a joint to seal the metal member to the ceramic member. The joint is positioned remote from the end portion of the ceramic member to avoid stresses at the ends or edges of the ceramic member. The sealed joint is particularly suited for use to form sealed metal to ceramic joints in a thermoelectric generator such as a sodium heat engine where a solid ceramic electrolyte is joined to metal parts in the system. 11 figures.

  6. Metal to ceramic sealed joint

    DOE Patents [OSTI]

    Lasecki, John V.; Novak, Robert F.; McBride, James R.

    1991-01-01

    A metal to ceramic sealed joint which can withstand wide variations in temperature and maintain a good seal is provided for use in a device adapted to withstand thermal cycling from about 20 to about 1000 degrees C. The sealed joint includes a metal member, a ceramic member having an end portion, and an active metal braze forming a joint to seal the metal member to the ceramic member. The joint is positioned remote from the end portion of the ceramic member to avoid stresses at the ends or edges of the ceramic member. The sealed joint is particularly suited for use to form sealed metal to ceramic joints in a thermoelectric generator such as a sodium heat engine where a solid ceramic electrolyte is joined to metal parts in the system.

  7. Degenerate doping of metallic anodes

    SciTech Connect (OSTI)

    Friesen, Cody A; Zeller, Robert A; Johnson, Paul B; Switzer, Elise E

    2015-05-12

    Embodiments of the invention relate to an electrochemical cell comprising: (i) a fuel electrode comprising a metal fuel, (ii) a positive electrode, (iii) an ionically conductive medium, and (iv) a dopant; the electrodes being operable in a discharge mode wherein the metal fuel is oxidized at the fuel electrode and the dopant increases the conductivity of the metal fuel oxidation product. In an embodiment, the oxidation product comprises an oxide of the metal fuel which is doped degenerately. In an embodiment, the positive electrode is an air electrode that absorbs gaseous oxygen, wherein during discharge mode, oxygen is reduced at the air electrode. Embodiments of the invention also relate to methods of producing an electrode comprising a metal and a doped metal oxidation product.

  8. Magnesium Replacement of Aluminum Cast Components in a Production V6 Engine

    Broader source: Energy.gov (indexed) [DOE]

    to Effect Cost-Effective Mass Reduction | Department of Energy Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon deer10_powell.pdf More Documents & Publications Magnesium Powertrain Cast Components FY 2009 Progress Report for Lightweighting Materials - 3. Automotive Metals - Cast FY 2008 Progress Report for Lightweighting Materials - 3. Automotive Metals-Cast

  9. Replace V-Belts with Notched or Synchronous Belt Drives | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy V-Belts with Notched or Synchronous Belt Drives Replace V-Belts with Notched or Synchronous Belt Drives Belt drives provide flexibility in the positioning of the motor relative to the load. Pulleys (sheaves) of varying diameters allow the speed of the driven equipment to be increased or decreased relative to the motor speed. A properly designed belt power-transmission system offers high efficiency and low noise, requires no lubrication, and presents low maintenance requirements.

  10. 5-Carbon Alcohols for Drop-in Gasoline Replacement - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Vehicles and Fuels Vehicles and Fuels Biomass and Biofuels Biomass and Biofuels Find More Like This Return to Search 5-Carbon Alcohols for Drop-in Gasoline Replacement Lawrence Berkeley National Laboratory Contact LBL About This Technology Technology Marketing SummaryJay Keasling and Howard Chou of Berkeley Lab and the Joint BioEnergy Institute (JBEI) have invented a fermentation process to produce 5-carbon alcohols from genetically modified E. coli host cells regardless of the

  11. A Safer Replacement for Highly Flammable Liquids Currently Used in Li-ion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Batteries | U.S. DOE Office of Science (SC) A Safer Replacement for Highly Flammable Liquids Currently Used in Li-ion Batteries Small Business Innovation Research (SBIR) and Small Business Technology Transfer (STTR) SBIR/STTR Home About Funding Opportunity Announcements (FOAs) Applicant and Awardee Resources Commercialization Assistance Other Resources Awards SBIR/STTR Highlights Reporting Fraud Contact Information Small Business Innovation Research and Small Business Technology Transfer

  12. Bio-based ethylene able to replace petroleum as a feedstock - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Early Stage R&D Early Stage R&D Biomass and Biofuels Biomass and Biofuels Find More Like This Return to Search Bio-based ethylene able to replace petroleum as a feedstock National Renewable Energy Laboratory Contact NREL About This Technology Publications: PDF Document Publication Photosynthetic Conversion of CO2 to Fuels and Chemicals using Cyanobacteria - Accelerating Innovation Webinar Presentation (989 KB) Technology Marketing Summary Ethylene is the most

  13. Technology Solutions Case Study: Replacement of Variable-Speed Motors for Furnaces

    SciTech Connect (OSTI)

    2013-02-01

    In conjunction with the New York State Energy Research and Development Authority (NYSERDA) and Proctor Engineering Group, Ltd. (PEG), the Consortium for Advanced Residential Buildings (CARB) evaluated the Concept 3 replacement motors for residential furnaces in eight homes in Syracuse, NY. These brushless, permanent magnet (BPM) motors can use much less electricity than their PSC (permanent split capacitor) predecessors. This evaluation focuses on existing homes in the heating-dominated climate of upstate New York with the goals of characterizing field performance and cost-effectiveness. The results of this study are intended to be useful to home performance contractors, HVAC contractors, and home efficiency program stakeholders. Tests and monitoring was performed both before and after fan motors were replaced. Average fan power reductions were approximately 126 Watts during heating and 220 Watts during cooling operation. Over the course of entire heating and cooling seasons, these translated into average electric energy savings of 163 kWh, with average cost savings of $20 per year. Homes where the fan was used outside of heating and cooling mode saved an additional $42 per year on average. Results indicate that BPM replacement motors will be most cost-effective in HVAC systems with longer run times and relatively low duct static pressures. More dramatic savings are possible if occupants use the fan-only setting when there is no thermal load.

  14. Corrosion-resistant metal surfaces

    DOE Patents [OSTI]

    Sugama, Toshifumi (Wading River, NY)

    2009-03-24

    The present invention relates to metal surfaces having thereon an ultrathin (e.g., less than ten nanometer thickness) corrosion-resistant film, thereby rendering the metal surfaces corrosion-resistant. The corrosion-resistant film includes an at least partially crosslinked amido-functionalized silanol component in combination with rare-earth metal oxide nanoparticles. The invention also relates to methods for producing such corrosion-resistant films.

  15. Metal-ceramic joint assembly

    DOE Patents [OSTI]

    Li, Jian (New Milford, CT)

    2002-01-01

    A metal-ceramic joint assembly in which a brazing alloy is situated between metallic and ceramic members. The metallic member is either an aluminum-containing stainless steel, a high chromium-content ferritic stainless steel or an iron nickel alloy with a corrosion protection coating. The brazing alloy, in turn, is either an Au-based or Ni-based alloy with a brazing temperature in the range of 9500 to 1200.degree. C.

  16. Electronic structure of metallic glasses

    SciTech Connect (OSTI)

    Oelhafen, P.; Lapka, R.; Gubler, U.; Krieg, J.; DasGupta, A.; Guentherodt, H.J.; Mizoguchi, T.; Hague, C.; Kuebler, J.; Nagel, S.R.

    1981-01-01

    This paper is organized in six sections and deals with (1) the glassy transition metal alloys, their d-band structure, the d-band shifts on alloying and their relation to the alloy heat of formation (..delta..H) and the glass forming ability, (2) the glass to crystal phase transition viewed by valence band spectroscopy, (3) band structure calculations, (4) metallic glasses prepared by laser glazing, (5) glassy normal metal alloys, and (6) glassy hydrides.

  17. SOLDERING OF ALUMINUM BASE METALS

    DOE Patents [OSTI]

    Erickson, G.F.

    1958-02-25

    This patent deals with the soldering of aluminum to metals of different types, such as copper, brass, and iron. This is accomplished by heating the aluminum metal to be soldered to slightly above 30 deg C, rubbing a small amount of metallic gallium into the part of the surface to be soldered, whereby an aluminum--gallium alloy forms on the surface, and then heating the aluminum piece to the melting point of lead--tin soft solder, applying lead--tin soft solder to this alloyed surface, and combining the aluminum with the other metal to which it is to be soldered.

  18. Properties of aged metal tritides

    SciTech Connect (OSTI)

    McConville, G.T,; Menke, D.A.; West, D.S.; Woods, C.M.

    1994-06-22

    The interaction of tritium with metals is made complex by two phenomena. The first is that the beta decay in the metal produces {sup 3}He. The helium moves to form bubbles. This report shows that growth of the bubbles produces a two-stage swelling of the metal that comes first from the appearance of the helium and second from the relaxation of the lattice disorder. The second phenomena is the steady state ion and free radical concentration in the tritium over gas that interacts with impurities on the metal surface. This report shows that the reaction rates are much faster than for normal hydrogen cleaning.

  19. Metal-Ion-Mediated Reactions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Researchers from Patras (Greece), Nicosia (Cyprus), Karlsruhe (Germany), Zaragoza (Spain), and the ALS at Berkeley Lab have studied metal-ion-mediated reactions of...

  20. Metal Buildings M&V

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Best practices are adopted as standard * FY18-...: Industry standards revised Approach ... Cost versus Best Value * Energy codesstandards * Many metal buildings are ...

  1. Metal deposition using seed layers

    DOE Patents [OSTI]

    Feng, Hsein-Ping; Chen, Gang; Bo, Yu; Ren, Zhifeng; Chen, Shuo; Poudel, Bed

    2013-11-12

    Methods of forming a conductive metal layers on substrates are disclosed which employ a seed layer to enhance bonding, especially to smooth, low-roughness or hydrophobic substrates. In one aspect of the invention, the seed layer can be formed by applying nanoparticles onto a surface of the substrate; and the metallization is achieved by electroplating an electrically conducting metal onto the seed layer, whereby the nanoparticles serve as nucleation sites for metal deposition. In another approach, the seed layer can be formed by a self-assembling linker material, such as a sulfur-containing silane material.

  2. Alkali metal ion battery with bimetallic electrode

    DOE Patents [OSTI]

    Boysen, Dane A; Bradwell, David J; Jiang, Kai; Kim, Hojong; Ortiz, Luis A; Sadoway, Donald R; Tomaszowska, Alina A; Wei, Weifeng; Wang, Kangli

    2015-04-07

    Electrochemical cells having molten electrodes having an alkali metal provide receipt and delivery of power by transporting atoms of the alkali metal between electrode environments of disparate chemical potentials through an electrochemical pathway comprising a salt of the alkali metal. The chemical potential of the alkali metal is decreased when combined with one or more non-alkali metals, thus producing a voltage between an electrode comprising the molten the alkali metal and the electrode comprising the combined alkali/non-alkali metals.

  3. Catalytic production of metal carbonyls from metal oxides

    DOE Patents [OSTI]

    Sapienza, Richard S.; Slegeir, William A.; Foran, Michael T.

    1984-01-01

    This invention relates to the formation of metal carbonyls from metal oxides and specially the formation of molybdenum carbonyl and iron carbonyl from their respective oxides. Copper is used here in admixed form or used in chemically combined form as copper molybdate. The copper/metal oxide combination or combined copper is utilized with a solvent, such as toluene and subjected to carbon monoxide pressure of 25 atmospheres or greater at about 150.degree.-260.degree. C. The reducing metal copper is employed in catalytic concentrations or combined concentrations as CuMoO.sub.4 and both hydrogen and water present serve as promoters. It has been found that the yields by this process have been salutary and that additionally the catalytic metal may be reused in the process to good effect.

  4. Catalytic production of metal carbonyls from metal oxides

    DOE Patents [OSTI]

    Sapienza, R.S.; Slegeir, W.A.; Foran, M.T.

    1984-01-06

    This invention relates to the formation of metal carbonyls from metal oxides and specially the formation of molybdenum carbonyl and iron carbonyl from their respective oxides. Copper is used here in admixed form or used in chemically combined form as copper molybdate. The copper/metal oxide combination or combined copper is utilized with a solvent, such as toluene and subjected to carbon monoxide pressure of 25 atmospheres or greater at about 150 to 260/sup 0/C. The reducing metal copper is employed in catalytic concentrations or combined concentrations as CuMoO/sub 4/ and both hydrogen and water present serve as promoters. It has been found that the yields by this process have been salutary and that additionally the catalytic metal may be reused in the process to good effect. 3 tables.

  5. Metal sulfide initiators for metal oxide sorbent regeneration

    DOE Patents [OSTI]

    Turk, Brian S.; Gupta, Raghubir P.

    2001-01-01

    A process of regenerating a sulfided sorbent is provided. According to the process of the invention, a substantial portion of the energy necessary to initiate the regeneration reaction is provided by the combustion of a particulate metal sulfide additive. In using the particulate metal sulfide additive, the oxygen-containing gas used to regenerate the sulfided sorbent can be fed to the regeneration zone without heating or at a lower temperature than used in conventional processes wherein the regeneration reaction is initiated only by heating the oxygen-containing gas. The particulate metal sulfide additive is preferably an inexpensive mineral ore such as iron pyrite which does not adversely affect the regeneration or corresponding desulfurization reactions. The invention further includes a sorbent composition comprising the particulate metal sulfide additive in admixture with an active metal oxide sorbent capable of removing one or more sulfur compounds from a sulfur-containing gas stream.

  6. Metal sulfide initiators for metal oxide sorbent regeneration

    DOE Patents [OSTI]

    Turk, B.S.; Gupta, R.P.

    1999-06-22

    A process of regenerating a sulfided sorbent is provided. According to the process of the invention, a substantial portion of the energy necessary to initiate the regeneration reaction is provided by the combustion of a particulate metal sulfide additive. In using the particulate metal sulfide additive, the oxygen-containing gas used to regenerate the sulfided sorbent can be fed to the regeneration zone without heating or at a lower temperature than used in conventional processes wherein the regeneration reaction is initiated only by heating the oxygen-containing gas. The particulate metal sulfide additive is preferably an inexpensive mineral ore such as iron pyrite which does not adversely affect the regeneration or corresponding desulfurization reactions. The invention further includes a sorbent composition comprising the particulate metal sulfide additive in admixture with an active metal oxide sorbent capable of removing one or more sulfur compounds from a sulfur-containing gas stream. 1 fig.

  7. Metal sulfide initiators for metal oxide sorbent regeneration

    DOE Patents [OSTI]

    Turk, Brian S.; Gupta, Raghubir P.

    1999-01-01

    A process of regenerating a sulfided sorbent is provided. According to the process of the invention, a substantial portion of the energy necessary to initiate the regeneration reaction is provided by the combustion of a particulate metal sulfide additive. In using the particulate metal sulfide additive, the oxygen-containing gas used to regenerate the sulfided sorbent can be fed to the regeneration zone without heating or at a lower temperature than used in conventional processes wherein the regeneration reaction is initiated only by heating the oxygen-containing. The particulate metal sulfide additive is preferably an inexpensive mineral ore such as iron pyrite which does not adversely affect the regeneration or corresponding desulfurization reactions. The invention further includes a sorbent composition comprising the particulate metal sulfide additive in admixture with an active metal oxide sorbent capable of removing one or more sulfur compounds from a sulfur-containing gas stream.

  8. Heavy metal movement in metal-contaminated soil profiles

    SciTech Connect (OSTI)

    Li, Zhenbin; Shuman, L.M.

    1996-10-01

    Heavy metal movement in soil profiles is a major environmental concern because even slow transport through the soil may eventually lead to deterioration of groundwater quality. In this study, three metal-contaminated soil (Fuquay, Dothan, and Clarendon) were selected from cropland were a high-metal flue dust had been applied annually for 6 years to raise soil pH, with application ending 4 years before sampling. One uncontaminated soil (Tifton) from the same physiographic area was also sampled as a control. Soil samples were collected in 15-cm increments from the surface to 105 cm in depth. Total contents of Zn, Cd, and Pb in the soils samples were determined. To better understand metal movement in relation to metal fractions in the soil profile, soil samples were also extracted sequentially for exchangeable (EXC), organic matter (OM), Mn oxide (MNO), amorphous Fe oxide (AFEO), crystalline Fe oxide (CFEO), and residual (RES) fractions. 35 refs., 6 figs., 2 tabs.

  9. Creating bulk nanocrystalline metal.

    SciTech Connect (OSTI)

    Fredenburg, D. Anthony; Saldana, Christopher J.; Gill, David D.; Hall, Aaron Christopher; Roemer, Timothy John; Vogler, Tracy John; Yang, Pin

    2008-10-01

    Nanocrystalline and nanostructured materials offer unique microstructure-dependent properties that are superior to coarse-grained materials. These materials have been shown to have very high hardness, strength, and wear resistance. However, most current methods of producing nanostructured materials in weapons-relevant materials create powdered metal that must be consolidated into bulk form to be useful. Conventional consolidation methods are not appropriate due to the need to maintain the nanocrystalline structure. This research investigated new ways of creating nanocrystalline material, new methods of consolidating nanocrystalline material, and an analysis of these different methods of creation and consolidation to evaluate their applicability to mesoscale weapons applications where part features are often under 100 {micro}m wide and the material's microstructure must be very small to give homogeneous properties across the feature.

  10. Expanding hollow metal rings

    DOE Patents [OSTI]

    Peacock, Harold B.; Imrich, Kenneth J.

    2009-03-17

    A sealing device that may expand more planar dimensions due to internal thermal expansion of a filler material. The sealing material is of a composition such that when desired environment temperatures and internal actuating pressures are reached, the sealing materials undergoes a permanent deformation. For metallic compounds, this permanent deformation occurs when the material enters the plastic deformation phase. Polymers, and other materials, may be using a sealing mechanism depending on the temperatures and corrosivity of the use. Internal pressures are generated by either rapid thermal expansion or material phase change and may include either liquid or solid to gas phase change, or in the gaseous state with significant pressure generation in accordance with the gas laws. Sealing material thickness and material composition may be used to selectively control geometric expansion of the seal such that expansion is limited to a specific facing and or geometric plane.

  11. METAL EXTRACTION PROCESS

    DOE Patents [OSTI]

    Lewis, G.W. Jr.; Rhodes, D.E.

    1957-11-01

    An improved method for extracting uranium from aqueous solutions by solvent extraction is presented. A difficulty encountered in solvent extraction operations using an organic extractant (e.g., tributyl phosphate dissolved in kerosene or carbon tetrachloride) is that emulsions sometimes form, and phase separation is difficult or impossible. This difficulty is overcome by dissolving the organic extractant in a molten wax which is a solid at operating temperatures. After cooling, the wax which now contains the extractant, is broken into small particles (preferably flakes) and this wax complex'' is used to contact the uranium bearing solutions and extract the metal therefrom. Microcrystalline petroleum wax and certain ethylene polymers have been found suitable for this purpose.

  12. Metal tritides helium emission

    SciTech Connect (OSTI)

    Beavis, L.C.

    1980-02-01

    Over the past several years, we have been measuring the release of helium from metal tritides (primarily erbium tritide). We find that qualitatively all tritides of interest to us behave the same. When they are first formed, the helium is released at a low rate that appears to be related to the amount of surface area which has access to the outside of the material (either film or bulk). For example, erbium tritide films initially release about 0.3% of the helium generated. Most tritide films emit helium at about this rate initially. At some later time, which depends upon the amount of helium generated, the parent occluding element and the degree of tritium saturation of the dihydride phase the helium emission changes to a new mode in which it is released at approximately the rate at which it is generated (for example, we measure this value to be approx. = .31 He/Er for ErT/sub 1/./sub 9/ films). If erbium ditritide is saturated beyond 1.9 T/Er, the critical helium/metal ratio decreases. For example, in bulk powders ErT/sub 2/./sub 15/ reaches critical release concentration at approx. = 0.03. Moderate elevation of temperature above room temperature has little impact on the helium release rate. It appears that the process may have approx. = 2 kcal/mol activation energy. The first helium formed is well bound. As the tritide ages, the helium is found in higher energy sites. Similar but less extensive measurements on scandium, titanium, and zirconium tritides are also described. Finally, the thermal desorption of erbium tritides of various ages from 50 days to 3154 days is discussed. Significant helium is desorbed along with the tritium in all but the youngest samples during thermodesorption.

  13. Synthesis metal nanoparticle

    DOE Patents [OSTI]

    Bunge, Scott D.; Boyle, Timothy J.

    2005-08-16

    A method for providing an anhydrous route for the synthesis of amine capped coinage-metal (copper, silver, and gold) nanoparticles (NPs) using the coinage-metal mesityl (mesityl=C.sub.6 H.sub.2 (CH.sub.3).sub.3 -2,4,6) derivatives. In this method, a solution of (Cu(C.sub.6 H.sub.2 (CH.sub.3).sub.3).sub.5, (Ag(C.sub.6 H.sub.2 (CH.sub.3).sub.3).sub.4, or (Au(C.sub.6 H.sub.2 (CH.sub.3).sub.3).sub.5 is dissolved in a coordinating solvent, such as a primary, secondary, or tertiary amine; primary, secondary, or tertiary phosphine, or alkyl thiol, to produce a mesityl precursor solution. This solution is subsequently injected into an organic solvent that is heated to a temperature greater than approximately 100.degree. C. After washing with an organic solvent, such as an alcohol (including methanol, ethanol, propanol, and higher molecular-weight alcohols), oxide free coinage NP are prepared that could be extracted with a solvent, such as an aromatic solvent (including, for example, toluene, benzene, and pyridine) or an alkane (including, for example, pentane, hexane, and heptane). Characterization by UV-Vis spectroscopy and transmission electron microscopy showed that the NPs were approximately 9.2.+-.2.3 nm in size for Cu.degree., (no surface oxide present), approximately 8.5.+-.1.1 nm Ag.degree. spheres, and approximately 8-80 nm for Au.degree..

  14. Liquid metal thermoacoustic engine

    SciTech Connect (OSTI)

    Swift, G.W.; Migliori, A.; Wheatley, J.C.

    1986-01-01

    We are studying a liquid metal thermoacoustic engine both theoretically and experimentally. This type of engine promises to produce large quantities of electrical energy from heat at modest efficiency with no moving parts. A sound wave is usually thought of as consisting of pressure oscillations, but always attendant to the pressure oscillation are temperature oscillations. The combination produces a rich variety of ''thermoacoustic'' effects. These effects are usually so small that they are never noticed in everyday life; nevertheless under the right circumstances they can be harnessed to produce powerful heat engines, heat pumps, and refrigerators. In our liquid metal thermoacoustic engine, heat flow from a high temperature source to a low temperature sink generates a high-amplitude standing acoustic wave in liquid sodium. This acoustic power is converted to electric power by a simple magnetohydrodynamic effect at the acoustic oscillation frequency. We have developed a detailed thermoacoustic theory applicable to this engine, and find that a reasonably designed liquid sodium engine operating between 700/sup 0/C and 100/sup 0/C should generate about 60 W/cm/sup 2/ of acoustic power at about 1/3 of Carnot's efficiency. Construction of a 3000 W-thermal laboratory model engine has just been completed, and we have exciting preliminary experimental results as of the time of preparation of this manuscript showing, basically, that the engine works. We have also designed and built a 1 kHz liquid sodium magnetohydrodynamic generator and have extensive measurements on it. It is now very well characterized both experimentally and theoretically. The first generator of its kind, it already converts acoustic power to electric power with 40% efficiency. 16 refs., 5 figs.

  15. Nanostructured metal-polyaniline composites

    DOE Patents [OSTI]

    Wang, Hsing-Lin; Li, Wenguang; Bailey, James A.; Gao, Yuan

    2010-08-31

    Metal-polyaniline (PANI) composites are provided together with a process of preparing such composites by an electrodeless process. The metal of the composite can have nanoscale structural features and the composites can be used in applications such as catalysis for hydrogenation reactions and for analytical detection methods employing SERS.

  16. Metal recovery from porous materials

    DOE Patents [OSTI]

    Sturcken, E.F.

    1991-01-01

    The present invention relates to recovery of metals. More specifically, the present invention relates to the recovery of plutonium and other metals from porous materials using microwaves. The United States Government has rights in this invention pursuant to Contract No. DE-AC09-89SR18035 between the US Department of Energy and Westinghouse Savannah River Company.

  17. PROCESS OF RECOVERING ALKALI METALS

    DOE Patents [OSTI]

    Wolkoff, J.

    1961-08-15

    A process is described of recovering alkali metal vapor by sorption on activated alumina, activated carbon, dehydrated zeolite, activated magnesia, or Fuller's earth preheated above the vaporization temperature of the alkali metal and subsequent desorption by heating the solvent under vacuum. (AEC)

  18. MECS 2006 - Fabricated Metals | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fabricated Metals MECS 2006 - Fabricated Metals Manufacturing Energy and Carbon Footprint for Fabricated Metals (NAICS 332) Sector with Total Energy Input, October 2012 (MECS 2006) All available footprints and supporting documents Manufacturing Energy and Carbon Footprint PDF icon Fabricated Metals More Documents & Publications Fabricated Metals (2010 MECS) MECS 2006 - Cement MECS 2006 - Glass

  19. Thin film hydrous metal oxide catalysts

    DOE Patents [OSTI]

    Dosch, Robert G. (Albuquerque, NM); Stephens, Howard P. (Albuquerque, NM)

    1995-01-01

    Thin film (<100 nm) hydrous metal oxide catalysts are prepared by 1) synthesis of a hydrous metal oxide, 2) deposition of the hydrous metal oxide upon an inert support surface, 3) ion exchange with catalytically active metals, and 4) activating the hydrous metal oxide catalysts.

  20. 10 CFR 830 Major Modification Determination for Replacement of ATR Primary Coolant Pumps and Motors

    SciTech Connect (OSTI)

    Noel Duckwitz

    2011-05-01

    The continued safe and reliable operation of the ATR is critical to the Department of Energy (DOE) Office of Nuclear Energy (NE) mission. While ATR is safely fulfilling current mission requirements, a variety of aging and obsolescence issues challenge ATR engineering and maintenance personnel’s capability to sustain ATR over the long term. First documented in a series of independent assessments, beginning with an OA Environmental Safety and Health Assessment conducted in 2003, the issues were validated in a detailed Material Condition Assessment (MCA) conducted as a part of the ATR Life Extension Program in 2007.Accordingly, near term replacement of aging and obsolescent original ATR equipment has become important to ensure ATR capability in support of NE’s long term national missions. To that end, a mission needs statement has been prepared for a non-major system acquisition which is comprised of three interdependent subprojects. The first project will replace the existent diesel-electrical bus (E-3), switchgear, and the 50-year-old obsolescent marine diesels with commercial power that is backed with safety related emergency diesel generators, switchgear, and uninterruptible power supply (UPS). The second project, the subject of this major modification determination, will replace the four, obsolete, original primary coolant pumps (PCPs) and motors. Completion of this and the two other age-related projects (replacement of the ATR diesel bus [E-3] and switchgear and replacement of the existent emergency firewater injection system) will resolve major age-related operational issues plus make a significant contribution in sustaining the ATR safety and reliability profile. The major modification criteria evaluation of the project pre-conceptual design identified several issues that lead to the conclusion that the project is a major modification: 1. Evaluation Criteria #3 (Change of existing process). The proposed strategy for equipping the replacement PCPs with VFDs and having the PCPs also function as ECPs will require significant safety basis changes requiring DOE approval. 2. Evaluation Criteria #4 (Use of new technology). The use of VFD and VFD “pump catcher” technology for the PCPs is not currently in use and has not been previously formally reviewed/approved by DOE for ATR. It is noted that VFD technology has several decades of commercial use and experience. However, the ATR probabilistic risk assessment will have to be updated, reflecting the changes for supplying ECP flows including VFD reliability, to confirm that the proposed activity maintains or reduces the CDF for the ATR. 3. Evaluation Criteria #5 (Create the need for new or revised safety SSCs). It is expected that the proposed activity will result in a revised list of safety-related SSCs. Specifically, as currently proposed, the existing ECPs will be deleted from the list. The PCPs and their associated components, picking up the ECP function, will be classified as safety-related active Seismic Category I.

  1. 10 CFR 830 Major Modification Determination for Advanced Test Reactor RDAS and LPCIS Replacement

    SciTech Connect (OSTI)

    David E. Korns

    2012-05-01

    The replacement of the ATR Control Complex's obsolete computer based Reactor Data Acquisition System (RDAS) and its safety-related Lobe Power Calculation and Indication System (LPCIS) software application is vitally important to ensure the ATR remains available to support this national mission. The RDAS supports safe operation of the reactor by providing 'real-time' plant status information (indications and alarms) for use by the reactor operators via the Console Display System (CDS). The RDAS is a computer support system that acquires analog and digital information from various reactor and reactor support systems. The RDAS information is used to display quadrant and lobe powers via a display interface more user friendly than that provided by the recorders and the Control Room upright panels. RDAS provides input to the Nuclear Engineering ATR Surveillance Data System (ASUDAS) for fuel burn-up analysis and the production of cycle data for experiment sponsors and the generation of the Core Safety Assurance Package (CSAP). RDAS also archives and provides for retrieval of historical plant data which may be used for event reconstruction, data analysis, training and safety analysis. The RDAS, LPCIS and ASUDAS need to be replaced with state-of-the-art technology in order to eliminate problems of aged computer systems, and difficulty in obtaining software upgrades, spare parts, and technical support. The major modification criteria evaluation of the project design did not lead to the conclusion that the project is a major modification. The negative major modification determination is driven by the fact that the project requires a one-for-one equivalent replacement of existing systems that protects and maintains functional and operational requirements as credited in the safety basis.

  2. Analysis of disposition alternatives for radioactively contaminated scrap metal

    SciTech Connect (OSTI)

    Nieves, L.A.; Chen, S.Y.; Kohout, E.J.; Nabelssi, B.; Tilbrook, R.W.; Wilson, S.E.

    1997-01-01

    Millions of tonnes of slightly radioactive, scrap iron and steel, stainless steel, and copper are likely to become available as nuclear and other facilities and equipment are withdrawn from service. Disposition of this material is an international policy issue under consideration currently. The major alternatives for managing this material are to either develop a regulatory process for decontamination and recycling that will safeguard human health or to dispose of the scrap and replace the metal stocks. To evaluate the alternatives, we estimate quantities of scrap arising from nuclear power plant decommissioning, evaluate potential price impacts of recycling on regional markets, and assess the health and environmental impacts of the management alternatives. We conclude that decontaminating and recycling the scrap is the superior alternative.

  3. Thermodynamic aspects of dehydrogenation reactions on noble metal surfaces

    SciTech Connect (OSTI)

    Svane, K. L. Hammer, B.

    2014-11-07

    The reaction free energy for dehydrogenation of phenol, aniline, thiophenol, benzoic acid, and 1,4-benzenediol on the close packed copper, silver, and gold surfaces has been studied by density functional theory calculations. Dehydrogenation of thiophenol is found to be favourable on all three surfaces while aniline does not dehydrogenate on any of them. For phenol, benzenediol and benzoic acid dehydrogenation is favourable on copper and silver only, following the general trend of an increasing reaction free energy when going form gold to silver to copper. This trend can be correlated with the changes in bond lengths within the molecule upon dehydrogenation. While copper is able to replace hydrogen, leaving small changes in the bond lengths of the aromatic ring, the metal-molecule bond is weaker for silver and gold, resulting in a partial loss of aromaticity. This difference in bond strength leads to pronounced differences in adsorption geometries upon multiple dehydrogenations.

  4. Lumen Maintenance Testing of the Philips 60-Watt Replacement Lamp L Prize Entry

    SciTech Connect (OSTI)

    Gordon, Kelly L.; Hafen, Ryan P.; Hathaway, John E.; McCullough, Jeffrey J.

    2012-09-01

    This paper describes testing conducted to evaluate the Philips' L Prize award winning 60-watt LED replacement product's ability to meet the lifetime/lumen maintenance requirement of the competition, which was: "having 70 percent of the lumen value under subparagraph (A) [producing a luminous flux greater than 900 lumens] exceeding 25,000 hours under typical conditions expected in residential use." A custom test apparatus was designed and constructed for this testing and a statistical approach was developed for use in evaluating the test results. This will be the only publicly available, third-party data set of long-term LED product operation.

  5. ANALYSIS OF DOSE RATES DURING REPLACEMENT OF MANIPULATORS IN THE FFTF INTERIM EXAMINATION & MAINTENANCE (IEM) CELL

    SciTech Connect (OSTI)

    NELSON, J.V.

    2002-01-23

    Replacement of a master-slave manipulator in the Interim Examination and Maintenance Cell at the Fast Flux Test Facility was carried out in August 2001. This operation created a 178-mm opening in the thick concrete wall of the hot cell. To aid in radiological work planning, dose rates outside the penetration in the wall were predicted using MCNP{trademark} photon transport calculations. The predicted dose rate was 7.7 mrem/h, which was reasonably close to the value of 10.4 mrem/h inferred from measurements.

  6. Working with SRNL - Our Facilities - Metal Hydride Laboratories

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Metal Hydride Laboratories Working with SRNL Our Facilities - Metal Hydride Laboratories The Metal Hydride Laboratories are used for research and development on metal hydride absorption and desorption performance

  7. Method for preparing metal powder, device for preparing metal powder, method for processing spent nuclear fuel

    DOE Patents [OSTI]

    Park, Jong-Hee (Clarendon Hills, IL)

    2011-11-29

    A method for producing metal powder is provided the comprising supplying a molten bath containing a reducing agent, contacting a metal oxide with the molten bath for a time and at a temperature sufficient to reduce the metal in the metal oxide to elemental metal and produce free oxygen; and isolating the elemental metal from the molten bath.

  8. 3-D Metals | Open Energy Information

    Open Energy Info (EERE)

    Metals Jump to: navigation, search Name 3-D Metals Facility 3-D Metals Sector Wind energy Facility Type Small Scale Wind Facility Status In Service Location Valley City OH...

  9. Method for controlled hydrogen charging of metals

    DOE Patents [OSTI]

    Cheng, Bo-Ching (Fremont, CA); Adamson, Ronald B. (Fremont, CA)

    1984-05-29

    A method for controlling hydrogen charging of hydride forming metals through a window of a superimposed layer of a non-hydriding metal overlying the portion of the hydride forming metals to be charged.

  10. Metal-Air Battery - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search Metal-Air Battery Battelle Memorial Institute Contact ... The open electrochemical cells may function as metal-air batteries.Benefits Metal-air ...

  11. Quinary metallic glass alloys

    DOE Patents [OSTI]

    Lin, Xianghong; Johnson, William L.

    1998-01-01

    At least quinary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10.sup.3 K/s. Such alloys comprise zirconium and/or hafnium in the range of 45 to 65 atomic percent, titanium and/or niobium in the range of 4 to 7.5 atomic percent, and aluminum and/or zinc in the range of 5 to 15 atomic percent. The balance of the alloy compositions comprise copper, iron, and cobalt and/or nickel. The composition is constrained such that the atomic percentage of iron is less than 10 percent. Further, the ratio of copper to nickel and/or cobalt is in the range of from 1:2 to 2:1. The alloy composition formula is: (Zr,Hf).sub.a (Al,Zn).sub.b (Ti,Nb).sub.c (Cu.sub.x Fe.sub.y (Ni,Co).sub.z).sub.d wherein the constraints upon the formula are: a ranges from 45 to 65 atomic percent, b ranges from 5 to 15 atomic percent, c ranges from 4 to 7.5 atomic percent, d comprises the balance, d.multidot.y is less than 10 atomic percent, and x/z ranges from 0.5 to 2.

  12. Quinary metallic glass alloys

    DOE Patents [OSTI]

    Lin, X.; Johnson, W.L.

    1998-04-07

    At least quinary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10{sup 3}K/s. Such alloys comprise zirconium and/or hafnium in the range of 45 to 65 atomic percent, titanium and/or niobium in the range of 4 to 7.5 atomic percent, and aluminum and/or zinc in the range of 5 to 15 atomic percent. The balance of the alloy compositions comprise copper, iron, and cobalt and/or nickel. The composition is constrained such that the atomic percentage of iron is less than 10 percent. Further, the ratio of copper to nickel and/or cobalt is in the range of from 1:2 to 2:1. The alloy composition formula is: (Zr,Hf){sub a}(Al,Zn){sub b}(Ti,Nb){sub c}(Cu{sub x}Fe{sub y}(Ni,Co){sub z}){sub d} wherein the constraints upon the formula are: a ranges from 45 to 65 atomic percent, b ranges from 5 to 15 atomic percent, c ranges from 4 to 7.5 atomic percent, d comprises the balance, d{hor_ellipsis}y is less than 10 atomic percent, and x/z ranges from 0.5 to 2.

  13. Catalysis using hydrous metal oxide ion exchangers

    DOE Patents [OSTI]

    Dosch, R.G.; Stephens, H.P.; Stohl, F.V.

    1983-07-21

    In a process which is catalyzed by a catalyst comprising an active metal on a carrier, said metal being active as a catalyst for the process, an improvement is provided wherein the catalyst is a hydrous, alkali metal or alkaline earth metal titanate, zirconate, niobate or tantalate wherein alkali or alkaline earth metal cations have been exchanged with a catalytically effective amount of cations of said metal.

  14. Catalysis using hydrous metal oxide ion exchanges

    DOE Patents [OSTI]

    Dosch, Robert G.; Stephens, Howard P.; Stohl, Frances V.

    1985-01-01

    In a process which is catalyzed by a catalyst comprising an active metal on a carrier, said metal being active as a catalyst for the process, an improvement is provided wherein the catalyst is a hydrous, alkali metal or alkaline earth metal titanate, zirconate, niobate or tantalate wherein alkali or alkaline earth metal cations have been exchanged with a catalytically effective amount of cations of said metal.

  15. Method of coating metal surfaces to form protective metal coating thereon

    DOE Patents [OSTI]

    Krikorian, Oscar H.; Curtis, Paul G.

    1992-01-01

    A process is disclosed for forming a protective metal coating on a metal surface using a flux consisting of an alkali metal fluoride, an alkaline earth metal fluoride, an alkali metal fluoaluminate, an alkali metal fluosilicate, and mixtures thereof. The flux, in particulate form, is mixed with particles of a metal coating material which may comprise aluminum, chromium, mixtures thereof, and alloys containing at least 50 wt. % aluminum and the particulate mixture is applied to the metal surface in a single step, followed by heating the coated metal surface to a temperature sufficient to cause the metal coating material to react with the metal surface to form a protective reaction product in the form of a metal coating bonded to the metal surface. The metal surface which reacts with the metal coating material to form the protective coating may comprise Fe, Co, Ni, Ti, V, Cr, Mn, Zr, Nb, Mo, Tc, Hf, Ta, W, Re and alloys thereof.

  16. Method of coating metal surfaces to form protective metal coating thereon

    DOE Patents [OSTI]

    Krikorian, O.H.; Curtis, P.G.

    1992-03-31

    A process is disclosed for forming a protective metal coating on a metal surface using a flux consisting of an alkali metal fluoride, an alkaline earth metal fluoride, an alkali metal fluoaluminate, an alkali metal fluosilicate, and mixtures thereof. The flux, in particulate form, is mixed with particles of a metal coating material which may comprise aluminum, chromium, mixtures thereof, and alloys containing at least 50 wt. % aluminum and the particulate mixture is applied to the metal surface in a single step, followed by heating the coated metal surface to a temperature sufficient to cause the metal coating material to react with the metal surface to form a protective reaction product in the form of a metal coating bonded to the metal surface. The metal surface which reacts with the metal coating material to form the protective coating may comprise Fe, Co, Ni, Ti, V, Cr, Mn, Zr, Nb, Mo, Tc, Hf, Ta, W, Re and alloys thereof. 1 figure.

  17. Replace Pressure-Reducing Valves with Backpressure Turbogenerators (International Fact Sheet), Energy Tips-Steam, Steam Tip Sheet #20c

    SciTech Connect (OSTI)

    Not Available

    2010-10-01

    This English/Chinese ITP steam tip sheet on replacing pressure-reducing valves provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  18. Light metal explosives and propellants

    DOE Patents [OSTI]

    Wood, Lowell L.; Ishikawa, Muriel Y.; Nuckolls, John H.; Pagoria, Phillip F.; Viecelli, James A.

    2005-04-05

    Disclosed herein are light metal explosives, pyrotechnics and propellants (LME&Ps) comprising a light metal component such as Li, B, Be or their hydrides or intermetallic compounds and alloys containing them and an oxidizer component containing a classic explosive, such as CL-20, or a non-explosive oxidizer, such as lithium perchlorate, or combinations thereof. LME&P formulations may have light metal particles and oxidizer particles ranging in size from 0.01 .mu.m to 1000 .mu.m.

  19. Aluminum-Alkaline Metal-Metal Composite Conductor - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Electricity Transmission Electricity Transmission Advanced Materials Advanced Materials Find More Like This Return to Search Aluminum-Alkaline Metal-Metal Composite Conductor Ames Laboratory Contact AMES About This Technology Technology Marketing Summary Researchers have developed a high strength, lightweight aluminum wire for high-voltage power transmission with reduced electrical resistance for overhead electrical lines. High-voltage electric power transmission cables based on pure

  20. Metal Hydride Hydrogen Storage Research and Development

    Broader source: Energy.gov [DOE]

    DOE's research on complex metal hydrides targets the development of advanced metal hydride materials including light-weight complex hydrides, destabilized binary hydrides, intermetallic hydrides,...

  1. Metal-bonded graphite foam composites

    DOE Patents [OSTI]

    Menchhofer, Paul A; Klett, James W

    2015-04-28

    A metal-bonded graphite foam composite includes a ductile metal continuous phase and a dispersed phase that includes graphite foam particles.

  2. Rotational Electrophoresis of Striped Metallic Microrods (Journal...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Rotational Electrophoresis of Striped Metallic Microrods Citation Details In-Document Search Title: Rotational Electrophoresis of Striped Metallic Microrods ...

  3. Computationally Optimized Homogenization Heat Treatment of Metal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Return to Search Computationally Optimized Homogenization Heat Treatment of Metal Alloys ... PDF Document Publication Computationally Optimized Homogenization Heat Treatment of Metal ...

  4. Controlled Metal Photodeposition - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    semiconductor-metal hybrid heterostructures High yields of site-selective nanoparticles Simple, scalable method for metal photodeposition Applications and Industries The...

  5. Metallic Membrane Materials Development for Hydrogen Production...

    Office of Scientific and Technical Information (OSTI)

    Metallic Membrane Materials Development for Hydrogen Production from Coal Derived Syngas Citation Details In-Document Search Title: Metallic Membrane Materials Development for...

  6. Replacement of chlorofluorocarbons (CFCs) at the DOE Gaseous Diffusion Plants: An assessment of global impacts

    SciTech Connect (OSTI)

    Socolof, M.L.; Saylor, R.E.; McCold, L.N.

    1994-12-31

    The US Department of Energy (DOE) operates two uranium enrichment plants. Together, the two plants maintain an inventory of approximately 14 million pounds of a chlorofluorocarbon (CFC), dichlorote-trafluoroethane (CFC-114) as a coolant. Annual operational CFC-114 losses total over 500,000 pounds. In February, 1992, President Bush announced that the US would terminate manufacture and importation of Class 1 ozone depleting substances (including CFC-114) by the end of 1995. To comply with this requirement DOE has considered introducing a replacement coolant by the end of 1995. Two perfluorocarbons (PFCs) - namely, octofluoro-cyclobutane and decafluorobutane - are presently the only known coolants that could meet safety requirements. They would not contribute to stratospheric ozone depletion but contribute to global warming. The paper describes an analysis of the potential global impacts of the proposed replacement of CFC-114 with a PFC. A problem with analyses of global warming and ozone depletion impacts is that even large sources of compounds that contribute to these effects contribute only very small fractions of the total effect. The authors take the position that significant effects to global warming and ozone depletion have already occurred, and that any additional contribution to these effects are contributions to cumulatively significant adverse effects on the environment. The paper describes four alternatives and the extent to which each would contribute to global warming and ozone depletion.

  7. Should a coal-fired power plant be replaced or retrofitted?

    SciTech Connect (OSTI)

    Dalia Patino-Echeverri; Benoit Morel; Jay Apt; Chao Chen

    2007-12-15

    In a cap-and-trade system, a power plant operator can choose to operate while paying for the necessary emissions allowances, retrofit emissions controls to the plant, or replace the unit with a new plant. Allowance prices are uncertain, as are the timing and stringency of requirements for control of mercury and carbon emissions. We model the evolution of allowance prices for SO{sub 2}, NOx, Hg, and CO{sub 2} using geometric Brownian motion with drift, volatility, and jumps, and use an options-based analysis to find the value of the alternatives. In the absence of a carbon price, only if the owners have a planning horizon longer than 30 years would they replace a conventional coal-fired plant with a high-performance unit such as a supercritical plant; otherwise, they would install SO{sub 2} and NOx controls on the existing unit. An expectation that the CO{sub 2} price will reach $50/t in 2020 makes the installation of an IGCC with carbon capture and sequestration attractive today, even for planning horizons as short as 20 years. A carbon price below $40/t is unlikely to produce investments in carbon capture for electric power. 1 ref., 5 figs., 2 tabs.

  8. The History of Metals and Ceramics Division

    SciTech Connect (OSTI)

    Craig, D.F.

    1999-01-01

    The division was formed in 1946 at the suggestion of Dr. Eugene P. Wigner to attack the problem of the distortion of graphite in the early reactors due to exposure to reactor neutrons, and the consequent radiation damage. It was called the Metallurgy Division and assembled the metallurgical and solid state physics activities of the time which were not directly related to nuclear weapons production. William A. Johnson, a Westinghouse employee, was named Division Director in 1946. In 1949 he was replaced by John H Frye Jr. when the Division consisted of 45 people. He was director during most of what is called the Reactor Project Years until 1973 and his retirement. During this period the Division evolved into three organizational areas: basic research, applied research in nuclear reactor materials, and reactor programs directly related to a specific reactor(s) being designed or built. The Division (Metals and Ceramics) consisted of 204 staff members in 1973 when James R. Weir, Jr., became Director. This was the period of the oil embargo, the formation of the Energy Research and Development Administration (ERDA) by combining the Atomic Energy Commission (AEC) with the Office of Coal Research, and subsequent formation of the Department of Energy (DOE). The diversification process continued when James O. Stiegler became Director in 1984, partially as a result of the pressure of legislation encouraging the national laboratories to work with U.S. industries on their problems. During that time the Division staff grew from 265 to 330. Douglas F. Craig became Director in 1992.

  9. Low leakage Ru-strontium titanate-Ru metal-insulator-metal capacitors for sub-20 nm technology node in dynamic random access memory

    SciTech Connect (OSTI)

    Popovici, M. Swerts, J.; Redolfi, A.; Kaczer, B.; Aoulaiche, M.; Radu, I.; Clima, S.; Everaert, J.-L.; Van Elshocht, S.; Jurczak, M.

    2014-02-24

    Improved metal-insulator-metal capacitor (MIMCAP) stacks with strontium titanate (STO) as dielectric sandwiched between Ru as top and bottom electrode are shown. The Ru/STO/Ru stack demonstrates clearly its potential to reach sub-20 nm technology nodes for dynamic random access memory. Downscaling of the equivalent oxide thickness, leakage current density (J{sub g}) of the MIMCAPs, and physical thickness of the STO have been realized by control of the Sr/Ti ratio and grain size using a heterogeneous TiO{sub 2}/STO based nanolaminate stack deposition and a two-step crystallization anneal. Replacement of TiN with Ru as both top and bottom electrodes reduces the amount of electrically active defects and is essential to achieve a low leakage current in the MIM capacitor.

  10. Method of producing metallic materials

    DOE Patents [OSTI]

    Branagan, Daniel J.

    2004-02-10

    The invention includes a method of producing a hard metallic material by forming a mixture containing at least 55% iron and at least one of B, C, Si and P. The mixture is formed into an alloy and cooled to form a metallic material having a hardness greater than about 9.2 GPa. The invention includes a method of forming a wire by combining a metal strip and a powder. The strip and the powder are rolled to form a wire containing at least 55% iron and from 2-7 additional elements including at least one of C, Si and B. The invention also includes a method of forming a hardened surface on a substrate by processing a solid mass to form a powder, applying the powder to a surface to form a layer containing metallic glass, and converting the glass to a crystalline material having a nanocrystalline grain size.

  11. Nanostructured Metal Oxide Anodes (Presentation)

    SciTech Connect (OSTI)

    Dillon, A. C.; Riley, L. A.; Lee, S.-H.; Kim, Y.-H.; Ban, C.; Gillaspie, D. T.; Pesaran, A.

    2009-05-01

    This summarizes NREL's FY09 battery materials research activity in developing metal oxide nanostructured anodes to enable high-energy, durable and affordable li-ion batteries for HEVs and PHEVs.

  12. Time domain electromagnetic metal detectors

    SciTech Connect (OSTI)

    Hoekstra, P.

    1996-04-01

    This presentation focuses on illustrating by case histories the range of applications and limitations of time domain electromagnetic (TDEM) systems for buried metal detection. Advantages claimed for TDEM metal detectors are: independent of instrument response (Geonics EM61) to surrounding soil and rock type; simple anomaly shape; mitigation of interference by ambient electromagnetic noise; and responsive to both ferrous and non-ferrous metallic targets. The data in all case histories to be presented were acquired with the Geonics EM61 TDEM system. Case histories are a test bed site on Molokai, Hawaii; Fort Monroe, Virginia; and USDOE, Rocky Flats Plant. The present limitations of this technology are: discrimination capabilities in terms of type of ordnance, and depth of burial is limited, and ability of resolving targets with small metallic ambient needs to be improved.

  13. Mutual neutralization of atomic rare-gas cations (Ne{sup +}, Ar{sup +}, Kr{sup +}, Xe{sup +}) with atomic halide anions (Cl{sup −}, Br{sup −}, I{sup −})

    SciTech Connect (OSTI)

    Shuman, Nicholas S.; Miller, Thomas M.; Viggiano, Albert A.; Johnsen, Rainer

    2014-01-28

    We report thermal rate coefficients for 12 reactions of rare gas cations (Ne{sup +}, Ar{sup +}, Kr{sup +}, Xe{sup +}) with halide anions (Cl{sup −}, Br{sup −}, I{sup −}), comprising both mutual neutralization (MN) and transfer ionization. No rate coefficients have been previously reported for these reactions; however, the development of the Variable Electron and Neutral Density Attachment Mass Spectrometry technique makes it possible to measure the difference of the rate coefficients for pairs of parallel reactions in a Flowing Afterglow-Langmuir Probe apparatus. Measurements of 18 such combinations of competing reaction pairs yield an over-determined data set from which a consistent set of rate coefficients of the 12 MN reactions can be deduced. Unlike rate coefficients of MN reactions involving at least one polyatomic ion, which vary by at most a factor of ∼3, those of the atom-atom reactions vary by at least a factor 60 depending on the species. It is found that the rate coefficients involving light rare-gas ions are larger than those for the heavier rare-gas ions, but the opposite trend is observed in the progression from Cl{sup −} to I{sup −}. The largest rate coefficient is 6.5 × 10{sup −8} cm{sup 3} s{sup −1} for Ne{sup +} with I{sup −}. Rate coefficients for Ar{sup +}, Kr{sup +}, and Xe{sup +} reacting with Br{sub 2}{sup −} are also reported.

  14. ARM: Millimeter Wave Cloud Radar (MMCR), replaces mmcrcal and mmcrmoments datastreams following C-40 processor upgrade of 2003.09.09

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Karen Johnson; Nitin Bharadwaj

    1990-01-01

    Millimeter Wave Cloud Radar (MMCR), replaces mmcrcal and mmcrmoments datastreams following C-40 processor upgrade of 2003.09.09

  15. METHOD OF DISSOLVING URANIUM METAL

    DOE Patents [OSTI]

    Slotin, L.A.

    1958-02-18

    This patent relates to an economicai means of dissolving metallic uranium. It has been found that the addition of a small amount of perchloric acid to the concentrated nitric acid in which the uranium is being dissolved greatly shortens the time necessary for dissolution of the metal. Thus the use of about 1 or 2 percent of perchioric acid based on the weight of the nitric acid used, reduces the time of dissolution of uranium by a factor of about 100.

  16. LIQUID METAL COMPOSITIONS CONTAINING URANIUM

    DOE Patents [OSTI]

    Teitel, R.J.

    1959-04-21

    Liquid metal compositions containing a solid uranium compound dispersed therein is described. Uranium combines with tin to form the intermetallic compound USn/sub 3/. It has been found that this compound may be incorporated into a liquid bath containing bismuth and lead-bismuth components, if a relatively small percentage of tin is also included in the bath. The composition has a low thermal neutron cross section which makes it suitable for use in a liquid metal fueled nuclear reactor.

  17. PRETREATING URANIUM FOR METAL PLATING

    DOE Patents [OSTI]

    Wehrmann, R.F.

    1961-05-01

    A process is given for anodically treating the surface of uranium articles, prior to metal plating. The metal is electrolyzed in an aqueous solution of about 10% polycarboxylic acid, preferably oxalic acid, from 1 to 5% by weight of glycerine and from 1 to 5% by weight of hydrochloric acid at from 20 to 75 deg C for from 30 seconds to 15 minutes. A current density of from 60 to 100 amperes per square foot is used.

  18. Metal detector technology data base

    SciTech Connect (OSTI)

    Porter, L.K.; Gallo, L.R.; Murray, D.W.

    1990-08-01

    The tests described in this report were conducted to obtain information on the effects target characteristics have on portal type metal detector response. A second purpose of the tests was to determine the effect of detector type and settings on the detection of the targets. Although in some cases comparison performance of different types and makes of metal detectors is found herein, that is not the primary purpose of the report. Further, because of the many variables that affect metal detector performance, the information presented can be used only in a general way. The results of these tests can show general trends in metal detection, but do little for making accurate predictions as to metal detector response to a target with a complex shape such as a handgun. The shape of an object and its specific metal content (both type and treatment) can have a significant influence on detection. Thus it should not be surprising that levels of detection for a small 100g stainless steel handgun are considerably different than for detection of the 100g stainless steel right circular cylinder that was used in these tests. 7 figs., 1 tab.

  19. Titanium metal: extraction to application

    SciTech Connect (OSTI)

    Gambogi, Joseph; Gerdemann, Stephen J.

    2002-09-01

    In 1998, approximately 57,000 tons of titanium metal was consumed in the form of mill products (1). Only about 5% of the 4 million tons of titanium minerals consumed each year is used to produce titanium metal, with the remainder primarily used to produce titanium dioxide pigment. Titanium metal production is primarily based on the direct chlorination of rutile to produce titanium tetrachloride, which is then reduced to metal using the Kroll magnesium reduction process. The use of titanium is tied to its high strength-to-weight ratio and corrosion resistance. Aerospace is the largest application for titanium. In this paper, we discuss all aspects of the titanium industry from ore deposits through extraction to present and future applications. The methods of both primary (mining of ore, extraction, and purification) and secondary (forming and machining) operations will be analyzed. The chemical and physical properties of titanium metal will be briefly examined. Present and future applications for titanium will be discussed. Finally, the economics of titanium metal production also are analyzed as well as the advantages and disadvantages of various alternative extraction methods.

  20. ITP Metal Casting: A Vision for the U.S. Metal Casting Industry: 2002 and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Beyond | Department of Energy A Vision for the U.S. Metal Casting Industry: 2002 and Beyond ITP Metal Casting: A Vision for the U.S. Metal Casting Industry: 2002 and Beyond PDF icon mcvision.pdf More Documents & Publications ITP Metal Casting: Metalcasting Industry Technology Roadmap ITP Metal Casting: Implementation of Metal Casting Best Practices ITP Metal Casting: Energy Use in Selected Metalcasting Facilities - 2003

  1. Replacing Resistance Heating with Mini-Split Heat Pumps, Sharon, Connecticut (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2014-05-01

    Mini-split heat pumps can provide space heating and cooling in many climates and are relatively affordable. These and other features make them potentially suitable for retrofitting into multifamily buildings in cold climates to replace electric resistance heating or other outmoded heating systems. This report investigates the suitability of mini-split heat pumps for multifamily retrofits. Various technical and regulatory barriers are discussed and modeling was performed to compare long-term costs of substituting mini-splits for a variety of other heating and cooling options. A number of utility programs have retrofit mini-splits in both single family and multifamily residences. Two such multifamily programs are discussed in detail.

  2. Standard Measurement & Verification Plan for Lighting Equipment Retrofit or Replacement Projects

    SciTech Connect (OSTI)

    Richman, Eric E.

    2009-11-04

    This document provides a framework for a standard Measurement and Verification (M&V) plan for lighting projects. It was developed to support cost-effective retrofits (partial and complete replacements) of lighting systems and is intended to provide a foundation for an M&V plan for a lighting retrofit utilizing a "best practice" approach, and to provide guidance to site owners, contractors, and other involved organizations on what is essential for a robust M&V plan for lighting projects. This document provides examples of appropriate elements of an M&V plan, including the calculation of expected energy savings. The standard M&V plan, as provided, also allows for consistent comparison with other similar lighting projects. Although intended for lighting retrofit applications, M&V plans developed per this framework document may also be used for other non-lighting technology retrofits and new installations.

  3. Anaerobic microbial remobilization of coprecipitated metals

    DOE Patents [OSTI]

    Francis, A.J.; Dodge, C.J.

    1994-10-11

    A process is provided for solubilizing coprecipitated metals. Metals in waste streams are concentrated by treatment with an iron oxide coprecipitating agent. The coprecipitated metals are solubilized by contacting the coprecipitate with a bacterial culture of a Clostridium species ATCC 53464. The remobilized metals can then be recovered and recycled. 4 figs.

  4. Anaerobic microbial remobilization of coprecipitated metals

    DOE Patents [OSTI]

    Francis, Arokiasamy J.; Dodge, Cleveland J.

    1994-10-11

    A process is provided for solubilizing coprecipitated metals. Metals in wastestreams are concentrated by treatment with an iron oxide coprecipitating agent. The coprecipitated metals are solubilized by contacting the coprecipitate with a bacterial culture of a Clostridium species ATCC 53464. The remobilized metals can then be recovered and recycled.

  5. Metal salt catalysts for enhancing hydrogen spillover

    DOE Patents [OSTI]

    Yang, Ralph T; Wang, Yuhe

    2013-04-23

    A composition for hydrogen storage includes a receptor, a hydrogen dissociating metal doped on the receptor, and a metal salt doped on the receptor. The hydrogen dissociating metal is configured to spill over hydrogen to the receptor, and the metal salt is configured to increase a rate of the spill over of the hydrogen to the receptor.

  6. Dispersion enhanced metal/zeolite catalysts

    DOE Patents [OSTI]

    Sachtler, W.M.H.; Tzou, M.S.; Jiang, H.J.

    1987-03-31

    Dispersion stabilized zeolite supported metal catalysts are provided as bimetallic catalyst combinations. The catalyst metal is in a reduced zero valent form while the dispersion stabilizer metal is in an unreduced ionic form. Representative catalysts are prepared from platinum or nickel as the catalyst metal and iron or chromium dispersion stabilizer.

  7. Horizontal electromagnetic casting of thin metal sheets

    DOE Patents [OSTI]

    Hull, John R.; Lari, Robert J.; Praeg, Walter F.; Turner, Larry R.

    1988-01-01

    Thin metal sheets are cast by magnetically suspending molten metal deposited within a ferromagnetic yoke and between AC conducting coils and linearly displacing the magnetically levitated liquid metal while it is being cooled to form a solid metal sheet. Magnetic flux increases as the molten metal sheet moves downward and decreases as the molten metal sheet moves upward to stabilize the sheet and maintain it in equilibrium as it is linearly displaced and solidified by cooling gases. A conducting shield is electrically coupled to the molten metal sheet by means of either metal sheet engaging rollers or brushes on the solidified metal, and by means of an electrode in the vessel containing the molten metal thereby providing a return path for the eddy currents induced in the metal sheet by the AC coil generated magnetic flux. Variation in the geometry of the conducting shield allows the magnetic flux between the metal sheet and the conducting shield to be varied and the thickness in surface quality of the metal sheet to be controlled. Side guards provide lateral containment for the molten metal sheet and stabilize and shape the magnetic field while a leader sheet having electromagnetic characteristics similar to those of the metal sheet is used to start the casting process and precedes the molten metal sheet through the magnet and forms a continuous sheet therewith. The magnet may be either U-shaped with a single racetrack coil or may be rectangular with a pair of facing bedstead coils.

  8. Horizontal electromagnetic casting of thin metal sheets

    DOE Patents [OSTI]

    Hull, John R.; Lari, Robert J.; Praeg, Walter F.; Turner, Larry R.

    1987-01-01

    Thin metal sheets are cast by magnetically suspending molten metal deposited within a ferromagnetic yoke and between AC conducting coils and linearly displacing the magnetically levitated liquid metal while it is being cooled to form a solid metal sheet. Magnetic flux increases as the molten metal sheet moves downward and decreases as the molten metal sheet moves upward to stabilize the sheet and maintain it in equilibrium as it is linearly displaced and solidified by cooling gases. A conducting shield is electrically coupled to the molten metal sheet by means of either metal sheet engaging rollers or brushes on the solidified metal, and by means of an electrode in the vessel containing the molten metal thereby providing a return path for the eddy currents induced in the metal sheet by the AC coil generated magnetic flux. Variation in the geometry of the conducting shield allows the magnetic flux between the metal sheet and the conducting shield to be varied and the thickness in surface quality of the metal sheet to be controlled. Side guards provide lateral containment for the molten metal sheet and stabilize and shape the magnetic field while a leader sheet having electromagnetic characteristics similar to those of the metal sheet is used to start the casting process and precedes the molten metal sheet through the magnet and forms a continuous sheet therewith. The magnet may be either U-shaped with a single racetrack coil or may be rectangular with a pair of facing bedstead coils.

  9. Molten metal injector system and method

    DOE Patents [OSTI]

    Meyer, Thomas N.; Kinosz, Michael J.; Bigler, Nicolas; Arnaud, Guy

    2003-04-01

    Disclosed is a molten metal injector system including a holder furnace, a casting mold supported above the holder furnace, and a molten metal injector supported from a bottom side of the mold. The holder furnace contains a supply of molten metal having a metal oxide film surface. The bottom side of the mold faces the holder furnace. The mold defines a mold cavity for receiving the molten metal from the holder furnace. The injector projects into the holder furnace and is in fluid communication with the mold cavity. The injector includes a piston positioned within a piston cavity defined by a cylinder for pumping the molten metal upward from the holder furnace and injecting the molten metal into the mold cavity under pressure. The piston and cylinder are at least partially submerged in the molten metal when the holder furnace contains the molten metal. The cylinder further includes a molten metal intake for receiving the molten metal into the piston cavity. The molten metal intake is located below the metal oxide film surface of the molten metal when the holder furnace contains the molten metal. A method of injecting molten metal into a mold cavity of a casting mold is also disclosed.

  10. Metal nanoparticles as a conductive catalyst

    DOE Patents [OSTI]

    Coker, Eric N.

    2010-08-03

    A metal nanocluster composite material for use as a conductive catalyst. The metal nanocluster composite material has metal nanoclusters on a carbon substrate formed within a porous zeolitic material, forming stable metal nanoclusters with a size distribution between 0.6-10 nm and, more particularly, nanoclusters with a size distribution in a range as low as 0.6-0.9 nm.

  11. Metal oxide nanostructures with hierarchical morphology

    DOE Patents [OSTI]

    Ren, Zhifeng; Lao, Jing Yu; Banerjee, Debasish

    2007-11-13

    The present invention relates generally to metal oxide materials with varied symmetrical nanostructure morphologies. In particular, the present invention provides metal oxide materials comprising one or more metallic oxides with three-dimensionally ordered nanostructural morphologies, including hierarchical morphologies. The present invention also provides methods for producing such metal oxide materials.

  12. Maskless laser writing of microscopic metallic interconnects

    DOE Patents [OSTI]

    Maya, Leon

    1995-01-01

    A method of forming a metal pattern on a substrate. The method includes depositing an insulative nitride film on a substrate and irradiating a laser beam onto the nitride film, thus decomposing the metal nitride into a metal constituent and a gaseous constituent, the metal constituent remaining in the nitride film as a conductive pattern.

  13. Maskless laser writing of microscopic metallic interconnects

    DOE Patents [OSTI]

    Maya, L.

    1995-10-17

    A method of forming a metal pattern on a substrate is disclosed. The method includes depositing an insulative nitride film on a substrate and irradiating a laser beam onto the nitride film, thus decomposing the metal nitride into a metal constituent and a gaseous constituent, the metal constituent remaining in the nitride film as a conductive pattern. 4 figs.

  14. Dispersion enhanced metal/zeolite catalysts

    DOE Patents [OSTI]

    Sachtler, Wolfgang M. H.; Tzou, Ming-Shin; Jiang, Hui-Jong

    1987-01-01

    Dispersion stabilized zeolite supported metal catalysts are provided as bimetallic catalyst combinations. The catalyst metal is in a reduced zero valent form while the dispersion stabilizer metal is in an unreduced ionic form. Representative catalysts are prepared from platinum or nickel as the catalyst metal and iron or chromium dispersion stabilizer.

  15. Metal sponge for cryosorption pumping applications

    DOE Patents [OSTI]

    Myneni, G.R.; Kneisel, P.

    1995-12-26

    A system has been developed for adsorbing gases at high vacuum in a closed area. The system utilizes large surface clean anodized metal surfaces at low temperatures to adsorb the gases. The large surface clean anodized metal is referred to as a metal sponge. The metal sponge generates or maintains the high vacuum by increasing the available active cryosorbing surface area. 4 figs.

  16. Metal sponge for cryosorption pumping applications

    DOE Patents [OSTI]

    Myneni, Ganapati R.; Kneisel, Peter

    1995-01-01

    A system has been developed for adsorbing gases at high vacuum in a closed area. The system utilizes large surface clean anodized metal surfaces at low temperatures to adsorb the gases. The large surface clean anodized metal is referred to as a metal sponge. The metal sponge generates or maintains the high vacuum by increasing the available active cryosorbing surface area.

  17. Lessons learned from reheater replacements TVA Gallatin Fossil Plant units 1 and 2

    SciTech Connect (OSTI)

    Chang, P.S.; Stangarone, R.J.

    1996-07-01

    Gallatin Units 1 and 2 have experienced a long history of problems in the reheat front inlet platens and front outlet pendants. Cracks were discovered at lug welds on the reheat inlet platen assemblies after six years of operation. During the next ten years cracking at lugs continued to be a problem in both the inlet platen and front outlet assemblies. Solutions included changing tube material and spacing, and redesigning lugs. None of the solutions were successful. In 1980, a fuel switch to washed coal was made to reduce boiler slagging. Within two years of the fuel change, liquid phase corrosion began to attack the tubes. The corrosion became severe and elements were replaced at seven year intervals. During this time, EPRI sought utilities with boilers experiencing liquid phase corrosion to test new corrosion resistant materials. Gallatin Unit 2 was selected as one of the test units. Probes containing a number of different alloys were inserted into the furnace and subjected to the corrosion attacks. After a five year study, HR3C was selected as the alloy from which to build a complete set of elements for further testing. Reheat assemblies were manufactured from HR3C and installed in Unit 2 and Unit 1 Shortly after Unit 1 returned to service, swages between the front pendant and inlet platen elements failed by brittle fracture due to the cold swaging operation used in fabrication. Cracks were discovered after two years of operation at the tube to lug welds and the new elements were experiencing the same liquid phase corrosion as in the past. The attempt to resolve the liquid phase corrosion problem in Gallatin Units 1 and 2 pendant reheater revealed that past replacements did not address the root cause of the problems. HR3C is a relatively brittle material and manufacturers used traditional methods to design and fabricate the elements. Inadequate fabrication and erection procedures have led to several in-service problems not associated with liquid phase corrosion.

  18. Generation of highly N-type, defect passivated transition metal oxides using plasma fluorine insertion

    DOE Patents [OSTI]

    Baker, L. Robert; Seo, Hyungtak; Hervier, Antoine; Somorjai, Gabor A.

    2016-04-12

    A new composition of matter is disclosed wherein oxygen vacancies in a semiconducting transition metal oxide such as titanium dioxide are filled with a halogen such as Fluorine, whereby the conductivity of the composition is greatly enhanced, while at the same time the chemical stability of the composition is greatly improved. Stoichiometric titanium dioxide having less than 3 % oxygen vacancies is subject to fluorine insertion such that oxygen vacancies are filled, limited amounts of fluorine replace additional oxygen atoms and fluorine interstitially inserts into the body of the TiO.sub.2 composition.

  19. Inert anode containing base metal and noble metal useful for the electrolytic production of aluminum

    DOE Patents [OSTI]

    Ray, Siba P.; Liu, Xinghua

    2000-01-01

    An inert anode for production of metals such as aluminum is disclosed. The inert anode comprises a base metal selected from Cu and Ag, and at least one noble metal selected from Ag, Pd, Pt, Au, Rh, Ru, Ir and Os. The inert anode may optionally be formed of sintered particles having interior portions containing more base metal than noble metal and exterior portions containing more noble metal than base metal. In a preferred embodiment, the base metal comprises Cu, and the noble metal comprises Ag, Pd or a combination thereof.

  20. Fabricated Metals (2010 MECS) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fabricated Metals (2010 MECS) Fabricated Metals (2010 MECS) Manufacturing Energy and Carbon Footprint for Fabricated Metals Sector (NAICS 332) Energy use data source: 2010 EIA MECS (with adjustments) Footprint Last Revised: February 2014 View footprints for other sectors here. Manufacturing Energy and Carbon Footprint PDF icon Fabricated Metals More Documents & Publications MECS 2006 - Fabricated Metals Cement (2010 MECS) Glass and Glass Products (2010 MECS) Manufacturing Energy Sankey