National Library of Energy BETA

Sample records for metal halide light

  1. Evaluation of Metal Halide, Plasma, and LED Lighting Technologies for a Hydrogen Fuel Cell Mobile Light (H 2 LT)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Miller, L. B.; Donohoe, S. P.; Jones, M. H.; White, W. A.; Klebanoff, L. E.; Velinsky, S. A.

    2015-04-22

    This article reports on the testing and comparison of a prototype hydrogen fuel cell light tower (H2LT) and a conventional diesel-powered metal halide light trailer for use in road maintenance and construction activities. The prototype was originally outfitted with plasma lights and then with light-emitting diode (LED) luminaires. Light output and distribution, lighting energy efficiency (i.e., efficacy), power source thermal efficiency, and fuel costs are compared. The metal halide luminaires have 2.2 and 3.1 times more light output than the plasma and LED luminaires, respectively, but they require more power/lumen to provide that output. The LED luminaires have 1.6 timesmore »better light efficacy than either the metal halide or plasma luminaires. The light uniformity ratios produced by the plasma and LED towers are acceptable. The fuel cell thermal efficiency at the power required to operate the plasma lights is 48%, significantly higher than the diesel generator efficiency of 23% when operating the metal halide lights. Due to the increased efficiency of the fuel cell and the LED lighting, the fuel cost per lumen-hour of the H2LT is 62% of the metal halide diesel light tower assuming a kilogram of hydrogen is twice the cost of a gallon of diesel fuel.« less

  2. Evaluation of Metal Halide, Plasma, and LED Lighting Technologies for a Hydrogen Fuel Cell Mobile Light (H 2 LT)

    SciTech Connect (OSTI)

    Miller, L. B.; Donohoe, S. P.; Jones, M. H.; White, W. A.; Klebanoff, L. E.; Velinsky, S. A.

    2015-04-22

    This article reports on the testing and comparison of a prototype hydrogen fuel cell light tower (H2LT) and a conventional diesel-powered metal halide light trailer for use in road maintenance and construction activities. The prototype was originally outfitted with plasma lights and then with light-emitting diode (LED) luminaires. Light output and distribution, lighting energy efficiency (i.e., efficacy), power source thermal efficiency, and fuel costs are compared. The metal halide luminaires have 2.2 and 3.1 times more light output than the plasma and LED luminaires, respectively, but they require more power/lumen to provide that output. The LED luminaires have 1.6 times better light efficacy than either the metal halide or plasma luminaires. The light uniformity ratios produced by the plasma and LED towers are acceptable. The fuel cell thermal efficiency at the power required to operate the plasma lights is 48%, significantly higher than the diesel generator efficiency of 23% when operating the metal halide lights. Due to the increased efficiency of the fuel cell and the LED lighting, the fuel cost per lumen-hour of the H2LT is 62% of the metal halide diesel light tower assuming a kilogram of hydrogen is twice the cost of a gallon of diesel fuel.

  3. New Energy Efficiency Standards for Metal Halide Lamp Fixtures...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Metal Halide Lamp Fixtures to Save on Energy Bills and Reduce Carbon Pollution New Energy Efficiency Standards for Metal Halide Lamp Fixtures to Save on Energy Bills and Reduce...

  4. Bright Light-Emitting Diodes based on Organometal Halide Perovskite

    E-Print Network [OSTI]

    Tan, Zhi-Kuang; Moghaddam, Reza Saberi; Lai, May Ling; Docampo, Pablo; Higler, Ruben; Deschler, Felix; Price, Michael; Sadhanala, Aditya; Pazos, Luis M.; Credgington, Dan; Hanusch, Fabian; Bein, Thomas; Snaith, Henry J.; Friend, Richard H.

    2014-08-03

    temperature and high vacuum processes, rendering them uneconomical for use in large area displays. Here, we report high brightness light-emitting diodes based on solution-processed organometal halide perovskites. We demonstrate electroluminescence in the near...

  5. Electrolytic systems and methods for making metal halides and refining metals

    DOE Patents [OSTI]

    Holland, Justin M.; Cecala, David M.

    2015-05-26

    Disclosed are electrochemical cells and methods for producing a halide of a non-alkali metal and for electrorefining the halide. The systems typically involve an electrochemical cell having a cathode structure configured for dissolving a hydrogen halide that forms the halide into a molten salt of the halogen and an alkali metal. Typically a direct current voltage is applied across the cathode and an anode that is fabricated with the non-alkali metal such that the halide of the non-alkali metal is formed adjacent the anode. Electrorefining cells and methods involve applying a direct current voltage across the anode where the halide of the non-alkali metal is formed and the cathode where the non-alkali metal is electro-deposited. In a representative embodiment the halogen is chlorine, the alkali metal is lithium and the non-alkali metal is uranium.

  6. Metal Halide Surface Treatment of Quantum Dots - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on dark matter ByMentor-ProtegeFrom the Director HereMetal

  7. Method for hydrocracking a heavy polynuclear hydrocarbonaceous feedstock in the presence of a molten metal halide catalyst

    DOE Patents [OSTI]

    Gorin, Everett (San Rafael, CA)

    1981-01-01

    A method for hydrocracking a heavy polynuclear hydrocarbonaceous feedstock to produce lighter hydrocarbon fuels by contacting the feedstock with hydrogen in the presence of a molten metal halide catalyst, the method comprising: mixing the feedstock with a heavy naphtha fraction which has an initial boiling point from about 100.degree. to about 160.degree. C. with a boiling point difference between the initial boiling point and the final boiling point of no more than about 50.degree. C. to produce a mixture; thereafter contacting the mixture with partially spent molten metal halide and hydrogen under temperature and pressure conditions so that the temperature is near the critical temperature of the heavy naphtha fraction; separating at least a portion of the heavy naphtha fraction and lighter hydrocarbon fuels from the partially spent molten metal halide, unreacted feedstock and reaction products; thereafter contacting the partially spent molten metal halide, unreacted feedstock and reaction products with hydrogen and fresh molten metal halide in a hydrocracking zone to produce additional lighter hydrocarbon fuels and separating at least a major portion of the lighter hydrocarbon fuels from the spent molten metal halide.

  8. Metal Halide Lamp Ballasts and Fixtures | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i nAand DOE Safetyof EnergyPresentation:DaisStatesEMCHIEF HUMANAtMetal

  9. Alkaline and alkaline earth metal phosphate halides and phosphors

    DOE Patents [OSTI]

    Lyons, Robert Joseph; Setlur, Anant Achyut; Cleaver, Robert John

    2012-11-13

    Compounds, phosphor materials and apparatus related to nacaphite family of materials are presented. Potassium and rubidium based nacaphite family compounds and phosphors designed by doping divalent rare earth elements in the sites of alkaline earth metals in the nacaphite material families are descried. An apparatus comprising the phosphors based on the nacaphite family materials are presented herein. The compounds presented is of formula A.sub.2B.sub.1-yR.sub.yPO.sub.4X where the elements A, B, R, X and suffix y are defined such that A is potassium, rubidium, or a combination of potassium and rubidium and B is calcium, strontium, barium, or a combination of any of calcium, strontium and barium. X is fluorine, chlorine, or a combination of fluorine and chlorine, R is europium, samarium, ytterbium, or a combination of any of europium, samarium, and ytterbium, and y ranges from 0 to about 0.1.

  10. Technical Feasibility Assessment of LED Roadway Lighting on the...

    Office of Scientific and Technical Information (OSTI)

    Technical Feasibility Assessment of LED Roadway Lighting on the Golden Gate Bridge Tuenge, Jason R. LED; induction; ceramic metal halide; plasma; roadway lighting; Golden Gate...

  11. Transition metal ion-assisted photochemical generation of alkyl halides and hydrocarbons from carboxylic acids

    SciTech Connect (OSTI)

    Carraher, Jack; Pestovsky, Oleg; Bakac, Andreja

    2012-03-14

    Near-UV photolysis of aqueous solutions of propionic acid and aqueous Fe3+ in the absence of oxygen generates a mixture of hydrocarbons (ethane, ethylene and butane), carbon dioxide, and Fe2+. The reaction becomes mildly catalytic (about five turnovers) in the presence of oxygen which converts a portion of alkyl radicals to oxidizing intermediates that reoxidize Fe2+. The photochemistry in the presence of halide ions (X? = Cl?, Br?) generates ethyl halides via halogen atom abstraction from FeXn3?n by ethyl radicals. Near-quantitative yields of C2H5X are obtained at ?0.05 M X?. Competition experiments with Co(NH3)5Br2+ provided kinetic data for the reaction of ethyl radicals with FeCl2+ (k = (4.0 ± 0.5) × 106 M?1 s?1) and with FeBr2+ (k = (3.0 ± 0.5) × 107 M?1 s?1). Photochemical decarboxylation of propionic acid in the presence of Cu2+ generates ethylene and Cu+. Longer-chain acids also yield alpha olefins as exclusive products. These reactions become catalytic under constant purge with oxygen which plays a dual role. It reoxidizes Cu+ to Cu2+, and removes gaseous olefins to prevent accumulation of Cu+(olefin) complexes and depletion of Cu2+. The results underscore the profound effect that the choice of metal ions, the medium, and reaction conditions exert on the photochemistry of carboxylic acids.

  12. Spatial and time-dependent distribution of plasma parameters in the metal-halide arc lamp

    E-Print Network [OSTI]

    Khakhaev, A; Ekimov, K; Soloviev, A; Khakhaev, Anatoly; Luizova, Lidia; Ekimov, Konstantin; Soloviev, Alexey

    2004-01-01

    It was shown by several authors that closed high pressure arc a.c. discharge in mercury vapors with addition of metal halide cannot be described in frames of the local thermodynamic equilibrium (LTE) model. However some plasma parameters (electron and high lying excited states densities as well as Hg metastable levels densities) are assumed to be in equilibrium with electron temperature and these assumptions are applied in plasma diagnostics. To verify these supposition the method of local plasma spectroscopy based on spatial and temporal distribution of spectral line profiles was developed. The experimental set up is based on diffraction spectrometer with large aperture, spatial scanning device and photodetector, which allows to carry out the measurements in chosen phases of current period. The software for data acquisition and processing is based on LabVIEW system. The original method of joint data processing was applied to data arrays containing spatial, spectral and temporal distribution of a source surfa...

  13. Metal-halide perovskites for photovoltaic and light-emitting...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    are exotic hybrid crystalline materials developed out of curiosity. Unexpectedly, solar cells incorporating these perovskites are rapidly emerging as serious contenders to rival...

  14. Light metal explosives and propellants

    DOE Patents [OSTI]

    Wood, Lowell L.; Ishikawa, Muriel Y.; Nuckolls, John H.; Pagoria, Phillip F.; Viecelli, James A.

    2005-04-05

    Disclosed herein are light metal explosives, pyrotechnics and propellants (LME&Ps) comprising a light metal component such as Li, B, Be or their hydrides or intermetallic compounds and alloys containing them and an oxidizer component containing a classic explosive, such as CL-20, or a non-explosive oxidizer, such as lithium perchlorate, or combinations thereof. LME&P formulations may have light metal particles and oxidizer particles ranging in size from 0.01 .mu.m to 1000 .mu.m.

  15. Optical emission spectroscopy of metal-halide lamps: Radially resolved atomic state distribution functions of Dy and Hg

    SciTech Connect (OSTI)

    Nimalasuriya, T.; Flikweert, A.J.; Stoffels, W.W.; Haverlag, M.; Mullen, J.J.A.M. van der; Pupat, N.B.M. [Department of Applied Physics, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (Netherlands); Ecole Nationale Superieure de Chimie de Paris, 11 Rue Pierre et Marie Curie, 75005 Paris (France)

    2006-03-01

    Absolute line intensity measurements are performed on a metal-halide lamp. Several transitions of atomic and ionic Dy and atomic Hg are measured at different radial positions from which we obtain absolute atomic and ionic Dy intensity profiles. From these profiles we construct the radially resolved atomic state distribution function (ASDF) of the atomic and ionic Dy and the atomic Hg. From these ASDFs several quantities are determined as functions of radial position, such as the (excitation) temperature, the ion ratio Hg{sup +}/Dy{sup +}, the electron density, the ground state, and the total density of Dy atoms and ions. Moreover, these ASDFs give us insight about the departure from equilibrium. The measurements show a hollow density profile for the atoms and the ionization of atoms in the center. In the outer parts of the lamp molecules dominate.

  16. Energy - LEDs to light UT arena | ornl.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to 85 percent more efficient than conventional arena metal halide lights. The light-emitting diode fixtures developed by Oak Ridge-based LED North America incorporate an Oak...

  17. Lutetium gadolinium halide scintillators

    DOE Patents [OSTI]

    Shah, Kanai S. (Newton, MA); Higgins, William M (Westborough, MA); Van Loef, Edgar V (Allston, MA); Glodo, Jaroslaw (Allston, MA)

    2010-07-13

    Lutetium gadolinium halide scintillators, devices and methods, including a composition having the formula Lu.sub.xGd.sub.(1-x)Halide and a dopant.

  18. Reliability Tools for Resonance Inspection of Light Metal Castings...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tools for Resonance Inspection of Light Metal Castings Reliability Tools for Resonance Inspection of Light Metal Castings 2012 DOE Hydrogen and Fuel Cells Program and Vehicle...

  19. Emission of Visible Light by Hot Dense Metals

    E-Print Network [OSTI]

    More, R.M.

    2010-01-01

    HIFAN 1761 EMISSION OF VISIBLE LIGHT BY HOT DENSE METALS ByDE-AC52-07NA27344. HI FAN Emission of Visible Light by HotABSTRACT We consider the emission of visible light by hot

  20. Actinide halide complexes

    DOE Patents [OSTI]

    Avens, Larry R. (Los Alamos, NM); Zwick, Bill D. (Santa Fe, NM); Sattelberger, Alfred P. (Los Alamos, NM); Clark, David L. (Los Alamos, NM); Watkin, John G. (Los Alamos, NM)

    1992-01-01

    A compound of the formula MX.sub.n L.sub.m wherein M is a metal atom selected from the group consisting of thorium, plutonium, neptunium or americium, X is a halide atom, n is an integer selected from the group of three or four, L is a coordinating ligand selected from the group consisting of aprotic Lewis bases having an oxygen-, nitrogen-, sulfur-, or phosphorus-donor, and m is an integer selected from the group of three or four for monodentate ligands or is the integer two for bidentate ligands, where the sum of n+m equals seven or eight for monodentate ligands or five or six for bidentate ligands, a compound of the formula MX.sub.n wherein M, X, and n are as previously defined, and a process of preparing such actinide metal compounds including admixing the actinide metal in an aprotic Lewis base as a coordinating solvent in the presence of a halogen-containing oxidant, are provided.

  1. Actinide halide complexes

    DOE Patents [OSTI]

    Avens, L.R.; Zwick, B.D.; Sattelberger, A.P.; Clark, D.L.; Watkin, J.G.

    1992-11-24

    A compound is described of the formula MX[sub n]L[sub m] wherein M is a metal atom selected from the group consisting of thorium, plutonium, neptunium or americium, X is a halide atom, n is an integer selected from the group of three or four, L is a coordinating ligand selected from the group consisting of aprotic Lewis bases having an oxygen-, nitrogen-, sulfur-, or phosphorus-donor, and m is an integer selected from the group of three or four for monodentate ligands or is the integer two for bidentate ligands, where the sum of n+m equals seven or eight for monodentate ligands or five or six for bidentate ligands. A compound of the formula MX[sub n] wherein M, X, and n are as previously defined, and a process of preparing such actinide metal compounds are described including admixing the actinide metal in an aprotic Lewis base as a coordinating solvent in the presence of a halogen-containing oxidant.

  2. ONDES DE SPIN MAGNETISM IN THE LIGHT RARE EARTH 'METALS

    E-Print Network [OSTI]

    Boyer, Edmond

    ONDES DE SPIN MAGNETISM IN THE LIGHT RARE EARTH 'METALS A. R. MACKINTOSH H. C. Mrsted Institute terres rares Ikgeres. Abstract. -The magnetic properties of the light rare earth metals are reviewed the last decade, the magnetism of the heavy rare earth metals is now rather well understood. The magnetic

  3. 190 IEEE TRANSACTIONS ON PLASMA SCIENCE, VOL. 30, NO. 1, FEBRUARY 2002 Gap Closure in a Cold Metal Halide Lamp

    E-Print Network [OSTI]

    Kushner, Mark

    190 IEEE TRANSACTIONS ON PLASMA SCIENCE, VOL. 30, NO. 1, FEBRUARY 2002 Gap Closure in a Cold Metal lamp has been investigated using a two-dimensional, plasma transport model. Im- ages are presented are found to be important during gap closure. Index Terms--Arc discharges, avalanche breakdown, glow dis

  4. Bloch states, universality in light transport through a perforated metal

    E-Print Network [OSTI]

    Gevorkian, Zh S; Cuevas, Emilio

    2015-01-01

    Light transport in a metal with hole arrays is considered.Analytical expressions for a normal incident lights transmission coefficient in a metallic system with periodic, isolated and disordered holes are obtained and analyzed. Special attention is paid to the phenomenon of an extraordinary transmittance. It was proven that a sufficient condition for such extraordinary behavior is a long-range order in the dielectric permittivity profile. Based on the extended Bloch states model a ladder structure and universal behavior for a transmission spectra is predicted. The resonance wavelength of a transmission spectra is found for the Kronig-Penney model. The role of surface plasmons is discussed.

  5. sup 3 P Hg, Cd, and Zn photosensitized chemistry of vinyl halides in krypton matrix

    SciTech Connect (OSTI)

    Cartland, H.E.; Pimentel, G.C. )

    1990-01-25

    The reaction of group IIB metals in the {sup 3}P state with vinyl fluoride, chloride, and bromide is studied in krypton matrix. The primary process in all cases is hydrogen halide elimination to form a hydrogen halide/acetylene hydrogen-bonded complex. Insertion of metal atoms into C-Cl and C-Br bonds, but not into C-H and C-F bonds, is also observed. The insertion photochemistry can be explained by a mechanism which requires that the process occur on a triplet surface with the vinyl halide in the planar ground-state conformation.

  6. Vitrification of IFR and MSBR halide salt reprocessing wastes

    SciTech Connect (OSTI)

    Siemer, D.D.

    2013-07-01

    Both of the genuinely sustainable (breeder) nuclear fuel cycles (IFR - Integral Fast Reactor - and MSBR - Molten Salt Breeder Reactor -) studied by the USA's national laboratories would generate high level reprocessing waste (HLRW) streams consisting of a relatively small amount ( about 4 mole %) of fission product halide (chloride or fluoride) salts in a matrix comprised primarily (about 95 mole %) of non radioactive alkali metal halide salts. Because leach resistant glasses cannot accommodate much of any of the halides, most of the treatment scenarios previously envisioned for such HLRW have assumed a monolithic waste form comprised of a synthetic analog of an insoluble crystalline halide mineral. In practice, this translates to making a 'substituted' sodalite ('Ceramic Waste Form') of the IFR's chloride salt-based wastes and fluoroapatite of the MSBR's fluoride salt-based wastes. This paper discusses my experimental studies of an alternative waste management scenario for both fuel cycles that would separate/recycle the waste's halide and immobilize everything else in iron phosphate (Fe-P) glass. It will describe both how the work was done and what its results indicate about how a treatment process for both of those wastes should be implemented (fluoride and chloride behave differently). In either case, this scenario's primary advantages include much higher waste loadings, much lower overall cost, and the generation of a product (glass) that is more consistent with current waste management practices. (author)

  7. GATEWAY Demonstrations: Trial Demonstration of Area Lighting Retrofit, Yuma Border Patrol, Yuma, Arizona

    SciTech Connect (OSTI)

    Wilkerson, A. M.; McCullough, J. J.

    2014-12-31

    Along the Yuma Sector Border Patrol Area in Yuma, Arizona, the GATEWAY program conducted a trial demonstration in which the incumbent quartz metal halide area lighting was replaced with LED at three pole locations at the Yuma Sector Border Patrol Area in Yuma, Arizona. The retrofit was documented to better understand LED technology performance in high-temperature environments.

  8. Enhanced Performance in Fluorene-Free Organometal Halide Perovskite Light Emitting Diodes using Tunable, Low Electron-Affinity Oxide Electron-Injectors

    E-Print Network [OSTI]

    Hoye, Robert L. Z.; Chua, Matthew R.; Musselman, Kevin P.; Li, Guangru; Lai, May-Ling; Tan, Zhi-Kuang; Greenham, Neil C.; MacManus-Driscoll, Judith L.; Friend, Richard H.; Credgington, Dan

    2015-01-09

    pyrolysis, which is the common method for producing metal oxides in hybrid LEDs, requires deposition temperatures >350 °C. This renders it incompatible with fl exible polymer substrates or direct deposi- tion onto perovskites. [ 3,18,19 ] In this work, we...

  9. Preparation of cerium halide solvate complexes

    DOE Patents [OSTI]

    Vasudevan, Kalyan V; Smith, Nickolaus A; Gordon, John C; McKigney, Edward A; Muenchaussen, Ross E

    2013-08-06

    Crystals of a solvated cerium(III) halide solvate complex resulted from a process of forming a paste of a cerium(III) halide in an ionic liquid, adding a solvent to the paste, removing any undissolved solid, and then cooling the liquid phase. Diffusing a solvent vapor into the liquid phase also resulted in crystals of a solvated cerium(III) halide complex.

  10. High Photoluminescence E?ciency and Optically Pumped Lasing in Solution-Processed Mixed Halide Perovskite Semiconductors

    E-Print Network [OSTI]

    Deschler, Felix; Price, Michael; Pathak, Sandeep; Klintberg, Lina E.; Jarausch, David-Dominik; Higler, Ruben; Hu?ttner, Sven; Leijtens, Tomas; Stranks, Samuel D.; Snaith, Henry J.; Atatu?re, Mete; Phillips, Richard T.; Friend, Richard H.

    2014-03-24

    The study of the photo-physical properties of organic-metallic lead-halide perovskites, which demonstrate excellent photovoltaic performance in devices with electron- and hole-accepting layers, helps to understand their charge photo...

  11. Dialing in color with rare earth metals: facile photoluminescent production of true white light

    E-Print Network [OSTI]

    Tew, Gregory N.

    Dialing in color with rare earth metals: facile photoluminescent production of true white light of lanthanide ions which is the focus of this report. Rare earth metal complexes have relatively good Combining polymeric architectures with metal ions produces hybrid materials with extremely rich properties

  12. Development of Halide and Oxy-Halides for Isotopic Separations

    SciTech Connect (OSTI)

    Leigh R. Martin; Aaron T. Johnson; Jana Pfeiffer; Martha R. Finck

    2014-10-01

    The goal of this project was to synthesize a volatile form of Np for introduction into mass spectrometers at INL. Volatile solids of the 5f elements are typically those of the halides (e.g. UF6), however fluorine is highly corrosive to the sensitive internal components of the mass separator, and the other volatile halides exist as several different stable isotopes in nature. However, iodide is both mono-isotopic and volatile, and as such presents an avenue for creation of a form of Np suitable for introduction into the mass separator. To accomplish this goal, the technical work in the project sought to establish a novel synthetic route for the conversion NpO2+ (dissolved in nitric acid) to NpI3 and NpI4.

  13. Comparative study of metal or oxide capped indiumtin oxide anodes for organic light-emitting diodes

    E-Print Network [OSTI]

    of Physics. DOI: 10.1063/1.1556184 I. INTRODUCTION Organic light-emitting diodes OLEDs 1 are challengingComparative study of metal or oxide capped indium­tin oxide anodes for organic light as anodes in organic light-emitting diodes based on N,N -diphenyl-N,N bis 3-methyl-phenyl-1,1 -biphenyl-4

  14. Diamond films treated with alkali-halides

    DOE Patents [OSTI]

    Anderson, D.F.; Kwan, S.W.

    1997-04-08

    A secondary electron emitter is provided and includes a substrate with a diamond film, the diamond film is treated or coated with an alkali-halide. 5 figs.

  15. Lanthanide doped strontium barium mixed halide scintillators

    DOE Patents [OSTI]

    Gundiah, Gautam; Bizarri, Gregory; Hanrahan, Stephen M; Bourret-Courchesne, Edith; Derenzo, Stephen E

    2013-07-16

    The present invention provides for a composition comprising an inorganic scintillator comprising a lanthanide-doped strontium barium mixed halide useful for detecting nuclear material.

  16. Hygroscopicity Evaluation of Halide Scintillators

    SciTech Connect (OSTI)

    Zhuravleva, M; Stand, L; Wei, H; Hobbs, C. L.; Boatner, Lynn A; Ramey, Joanne Oxendine; Burger, Arnold; Rowe, E; Bhattacharya, P.; Tupitsyn, E; Melcher, Charles L

    2014-01-01

    A collaborative study of relative hygroscopicity of anhydrous halide scintillators grown at various laboratories is presented. We have developed a technique to evaluate moisture sensitivity of both raw materials and grown crystals, in which the moisture absorption rate is measured using a gravimetric analysis. Degradation of the scintillation performance was investigated by recording gamma-ray spectra and monitoring the photopeak position, count rate and energy resolution. The accompanying physical degradation of the samples exposed to ambient atmosphere was photographically recorded as well. The results were compared with ben

  17. Halide and Oxy-Halide Eutectic Systems for High-Performance,...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    computational modeling along with rapid material screening methods to identify halide salt mixtures with a melting point below 250C that are stable at temperatures well above...

  18. Metal-black scattering centers to enhance light harvesting by thin-film solar cells

    E-Print Network [OSTI]

    Peale, Robert E.

    Metal-black scattering centers to enhance light harvesting by thin-film solar cells Deep Panjwania as scattering centers to increase the effective optical thickness of thin-film solar cells. The particular type. Gold-black was deposited on commercial thin-film solar cells using a thermal evaporator in nitrogen

  19. Spectral light separator based on deep-subwavelength resonant apertures in a metallic film

    SciTech Connect (OSTI)

    Büyükalp, Yasin; Catrysse, Peter B. Shin, Wonseok; Fan, Shanhui

    2014-07-07

    We propose to funnel, select, and collect light spectrally by exploiting the unique properties of deep-subwavelength resonant apertures in a metallic film. In our approach, each aperture has an electromagnetic cross section that is much larger than its physical size while the frequency of the collected light is controlled by its height through the Fabry-Pérot resonance mechanism. The electromagnetic crosstalk between apertures remains low despite physical separations in the deep-subwavelength range. The resulting device enables an extremely efficient, subwavelength way to decompose light into its spectral components without the loss of photons and spatial coregistration errors. As a specific example, we show a subwavelength-size structure with three deep-subwavelength slits in a metallic film designed to operate in the mid-wave infrared range between 3 and 5.5??m.

  20. Preferential Eu Site Occupation and Its Consequences in the Ternary Luminescent HalidesAB2I5:Eu2+(A=Li–Cs;B=Sr, Ba)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fang, C.? M.; Biswas, Koushik

    2015-07-22

    Several rare-earth-doped, heavy-metal halides have recently been identified as potential next-generation luminescent materials with high efficiency at low cost. AB2I5:Eu2+ (A=Li–Cs; B=Sr, Ba) is one such family of halides. Its members, such as CsBa2I5:Eu2+ and KSr2I5:Eu2+, are currently being investigated as high-performance scintillators with improved sensitivity, light yield, and energy resolution less than 3% at 662 keV. Within the AB2I5 family, our first-principles-based calculations reveal two remarkably different trends in Eu site occupation. The substitutional Eu ions occupy both eightfold-coordinated B1(VIII) and the sevenfold-coordinated B2(VII) sites in the Sr-containing compounds. However, in the Ba-containing crystals, Eu ions strongly prefer themore »B2(VII)sites. This random versus preferential distribution of Eu affects their electronic properties. The calculations also suggest that in the Ba-containing compounds one can expect the formation of Eu-rich domains. These results provide atomistic insight into recent experimental observations about the concentration and temperature effects in Eu-doped CsBa2I5. We discuss the implications of our results with respect to luminescent properties and applications. We also hypothesize Sr, Ba-mixed quaternary iodides ABaVIIISrVIII5:Eu as scintillators having enhanced homogeneity and electronic properties.« less

  1. Design of Optical Metamaterial Mirror with Metallic Nanoparticles for Broadband Light Absorption in Graphene Optoelectronic Devices

    E-Print Network [OSTI]

    Lee, Seungwoo

    2015-01-01

    A general metallic mirror (i.e., a flat metallic surface) has been a popular optical component that can contribute broadband light absorption to thin-film optoelectronic devices; nonetheless, such electric mirror with a reversal of reflection phase inevitably causes the problem of minimized electric field near at the mirror surface (maximized electric field at one quarter of wavelength from mirror). This problem becomes more elucidated, when the deep-subwavelength-scaled two-dimensional (2D) material (e.g., graphene and molybdenum disulfide) is implemented into optoelectronic device as an active channel layer. The purpose of this work was to conceive the idea for using a charge storage layer (spherical Au nanoparticles (AuNPs), embedded into dielectric matrix) of the floating-gate graphene photodetector as a magnetic mirror, which allows the device to harness the increase in broadband light absorption. In particular, we systematically examined whether the versatile assembly of spherical AuNP monolayer within ...

  2. Project title: A preparatory study of a new ultra-light metallic sheet material

    E-Print Network [OSTI]

    Sheet The Challenge The development of an ultra-light metallic sheet material has the potential to support highly desirable combinations of properties (including low areal density, high beam stiffness, good corrosion resistance, attractive thermal... . Working Together The project, originally proposed by Volvo, was initiated as a 12-month venture in 2001 and funded by CMI. To oversee the invention and production of this revolutionary material Prof Bill Clyne from the Department of Materials Science...

  3. Nanostructure of Metallic Particles in Light Water Reactor Used Nuclear Fuel

    SciTech Connect (OSTI)

    Buck, Edgar C.; Mausolf, Edward J.; Mcnamara, Bruce K.; Soderquist, Chuck Z.; Schwantes, Jon M.

    2015-03-11

    The extraordinary nano-structure of metallic particles in light water reactor fuels points to possible high reactivity through increased surface area and a high concentration of high energy defect sites. We have analyzed the metallic epsilon particles from a high burn-up fuel from a boiling water reactor using transmission electron microscopy and have observed a much finer nanostructure in these particles than has been reported previously. The individual round particles that varying in size between ~20 and ~50 nm appear to consist of individual crystallites on the order of 2-3 nm in diameter. It is likely that in-reactor irradiation induce displacement cascades results in the formation of the nano-structure. The composition of these metallic phases is variable yet the structure of the material is consistent with the hexagonal close packed structure of epsilon-ruthenium. These findings suggest that unusual catalytic behavior of these materials might be expected, particularly under accident conditions.

  4. Shape Evolution and Single Particle Luminescence of Organometal Halide Perovskite Nanocrystals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhu, Feng; Men, Long; Guo, Yijun; Zhu, Qiaochu; Bhattacharjee, Ujjal; Goodwin, Peter M.; Petrich, Jacob W.; Smith, Emily A.; Vela, Javier

    2015-02-09

    Organometallic halide perovskites CH3NH3PbX3 (X = I, Br, Cl) have quickly become one of the most promising semiconductors for solar cells, with photovoltaics made of these materials reaching power conversion efficiencies of near 20%. Improving our ability to harness the full potential of organometal halide perovskites will require more controllable syntheses that permit a detailed understanding of their fundamental chemistry and photophysics. In our manuscript, we systematically synthesize CH3NH3PbX3 (X = I, Br) nanocrystals with different morphologies (dots, rods, plates or sheets) by using different solvents and capping ligands. CH3NH3PbX3 nanowires and nanorods capped with octylammonium halides show relatively highermore »photoluminescence (PL) quantum yields and long PL lifetimes. CH3NH3PbI3 nanowires monitored at the single particle level show shape-correlated PL emission across whole particles, with little photobleaching observed and very few off periods. Our work highlights the potential of low-dimensional organometal halide perovskite semiconductors in constructing new porous and nanostructured solar cell architectures, as well as in applying these materials to other fields such as light-emitting devices and single particle imaging and tracking.« less

  5. Enhanced Quantum Efficiency From Hybrid Cesium Halide/Copper Photocathode

    SciTech Connect (OSTI)

    Kong, Lingmei; Joly, Alan G.; Droubay, Timothy C.; Gong, Yu; Hess, Wayne P.

    2014-04-28

    The quantum efficiency of Cu is found to increase dramatically when coated by a CsI film and then irradiated by a UV laser. Over three orders of magnitude quantum efficiency enhancement at 266 nm is observed in CsI/Cu(100), indicating potential application in future photocathode devices. Upon laser irradiation, a large work function reduction to a value less than 2 eV is also observed, significantly greater than for similarly treated CsBr/Cu(100). The initial QE enhancement, prior to laser irradiation, is attributed to interface interaction, surface cleanliness and the intrinsic properties of the Cs halide film. Further QE enhancement following activation is attributed to formation of inter-band states and Cs metal accumulation at the interface induced by laser irradiation.

  6. J. Am. Chem. SOC.1991, 113,9575-9585 9575 Mixed Aggregation of Lithium Enolates and Lithium Halides

    E-Print Network [OSTI]

    Collum, David B.

    J. Am. Chem. SOC.1991, 113,9575-9585 9575 Mixed Aggregation of Lithium Enolates and Lithium Halides with Lithium 2,2,6,6-Tetramethylpiperidide(LiTMP) Patricia L. Hall, James H. Gilchrist, Aidan T. Harrison]-lithiumdi-tert-butylamide and conformationally locked [6Li]-lithium2,2,4,6,6-pentamethylpiperidide shed further light

  7. High lumen compact fluorescents boost light output in new fixtures

    SciTech Connect (OSTI)

    1992-12-31

    Some compact fluorescent lamps aren`t so compact. General Electric (GE), OSRAM, and Philips have been expanding offerings in longer, more powerful, hard wired CFLs that generate enough light to serve applications once limited to conventional fluorescents and metal halide systems. All three of these manufacturers have for some time offered 18- to 40-watt high-output CFLs, which use a fluorescent tube doubled back on itself to produce a lot of light in a compact source. Now GE has introduced an even larger, more powerful 50-watt unit, and OSRAM is soon to follow suit with a 55-watt lamp. These new entries to the field of turbocharged CFLs can provide general lighting at ceiling heights of 12 feet or more as well as indirect lighting, floodlighting, and wall washing. They are such a concentrated source of light that they can provide the desired illumination using fewer lamps and fixtures than would be needed with competing sources.

  8. Lanthanide-halide based humidity indicators

    DOE Patents [OSTI]

    Beitz, James V. (Hinsdale, IL); Williams, Clayton W. (Chicago, IL)

    2008-01-01

    The present invention discloses a lanthanide-halide based humidity indicator and method of producing such indicator. The color of the present invention indicates the humidity of an atmosphere to which it is exposed. For example, impregnating an adsorbent support such as silica gel with an aqueous solution of the europium-containing reagent solution described herein, and dehydrating the support to dryness forms a substance with a yellow color. When this substance is exposed to a humid atmosphere the water vapor from the air is adsorbed into the coating on the pore surface of the silica gel. As the water content of the coating increases, the visual color of the coated silica gel changes from yellow to white. The color change is due to the water combining with the lanthanide-halide complex on the pores of the gel.

  9. Lanthanum halide scintillators for time-of-flight 3-D pet

    DOE Patents [OSTI]

    Karp, Joel S. (Glenside, PA); Surti, Suleman (Philadelphia, PA)

    2008-06-03

    A Lanthanum Halide scintillator (for example LaCl.sub.3 and LaBr.sub.3) with fast decay time and good timing resolution, as well as high light output and good energy resolution, is used in the design of a PET scanner. The PET scanner includes a cavity for accepting a patient and a plurality of PET detector modules arranged in an approximately cylindrical configuration about the cavity. Each PET detector includes a Lanthanum Halide scintillator having a plurality of Lanthanum Halide crystals, a light guide, and a plurality of photomultiplier tubes arranged respectively peripherally around the cavity. The good timing resolution enables a time-of-flight (TOF) PET scanner to be developed that exhibits a reduction in noise propagation during image reconstruction and a gain in the signal-to-noise ratio. Such a PET scanner includes a time stamp circuit that records the time of receipt of gamma rays by respective PET detectors and provides timing data outputs that are provided to a processor that, in turn, calculates time-of-flight (TOF) of gamma rays through a patient in the cavity and uses the TOF of gamma rays in the reconstruction of images of the patient.

  10. Trial Demonstration of Area Lighting Retrofit: Yuma Border Patrol, Yuma Arizona

    SciTech Connect (OSTI)

    Wilkerson, Andrea M.; McCullough, Jeffrey J.

    2014-12-30

    The Yuma Sector Border Patrol Area is a high flux lighting application in a high temperature environment, presenting a formidable challenge for light-emitting diodes (LEDs). This retrofit is an Energy Savings Performance Contract ENABLE project under the U.S. Department of Energy (DOE) Federal Energy Management Program. If high flux LED technology performs well in a region with high ambient temperature and solar radiation, it can perform well in most outdoor environments. The design process for the Yuma retrofit has already provided valuable knowledge to CBP and DOE. The LED lighting system selected for the retrofit is expected to reduce energy consumption 69% compared to the incumbent quartz metal halide (QMH) lighting system. If the LED lighting system is installed, GATEWAY will continue to document and disseminate information regarding the installation and long-term performance so that others may also gain valuable knowledge from the Yuma Sector Border Patrol Area lighting retrofit.

  11. Visible-light-induced instability in amorphous metal-oxide based TFTs for transparent electronics

    SciTech Connect (OSTI)

    Ha, Tae-Jun

    2014-10-15

    We investigate the origin of visible-light-induced instability in amorphous metal-oxide based thin film transistors (oxide-TFTs) for transparent electronics by exploring the shift in threshold voltage (V{sub th}). A large hysteresis window in amorphous indium-gallium-zinc-oxide (a-IGZO) TFTs possessing large optical band-gap (?3 eV) was observed in a visible-light illuminated condition whereas no hysteresis window was shown in a dark measuring condition. We also report the instability caused by photo irradiation and prolonged gate bias stress in oxide-TFTs. Larger V{sub th} shift was observed after photo-induced stress combined with a negative gate bias than the sum of that after only illumination stress and only negative gate bias stress. Such results can be explained by trapped charges at the interface of semiconductor/dielectric and/or in the gate dielectric which play a role in a screen effect on the electric field applied by gate voltage, for which we propose that the localized-states-assisted transitions by visible-light absorption can be responsible.

  12. On the surface morphology of thin alkali halide photocathode "lms

    E-Print Network [OSTI]

    On the surface morphology of thin alkali halide photocathode "lms T. Boutboul *, A. Breskin , R-91128 Palaiseau Cedex, France Abstract Thin alkali halide "lms are currently used as transmissive UVI and CsBr "lms was investigated by means of a scanning electron microscope, to which the samples were

  13. Coupling mid-infrared light from a photonic crystal waveguide to metallic transmission lines

    SciTech Connect (OSTI)

    Blanco-Redondo, Andrea E-mail: r.hillenbrand@nanogune.eu; Dpto. Electronica y Telecom., E.T.S. Ingeniería Bilbao, UPV Sarriugarte, Paulo; Garcia-Adeva, Angel; Zubia, Joseba; IKERBASQUE, Basque Foundation for Science, 48011 Bilbao, Bizkaia

    2014-01-06

    We propose and theoretically study a hybrid structure consisting of a photonic crystal waveguide (PhC-wg) and a two-wire metallic transmission line (TL), engineered for efficient transfer of mid-infrared (mid-IR) light between them. An efficiency of 32% is obtained for the coupling from the transverse magnetic (TM) photonic mode to the symmetric mode of the TL, with a predicted intensity enhancement factor of 53 at the transmission line surface. The strong coupling is explained by the small phase velocity mismatch and sufficient spatial overlapping between the modes. This hybrid structure could find applications in highly integrated mid-IR photonic-plasmonic devices for biological and gas sensing, among others.

  14. Energy Saving Melting and Revert Reduction Technology (Energy-SMARRT): Light Metals Permanent Mold Casting

    SciTech Connect (OSTI)

    Fasoyinu, Yemi

    2014-03-31

    Current vehicles use mostly ferrous components for structural applications. It is possible to reduce the weight of the vehicle by substituting these parts with those made from light metals such as aluminum and magnesium. Many alloys and manufacturing processes can be used to produce these light metal components and casting is known to be most economical. One of the high integrity casting processes is permanent mold casting which is the focus of this research report. Many aluminum alloy castings used in automotive applications are produced by the sand casting process. Also, aluminum-silicon (Al-Si) alloys are the most widely used alloy systems for automotive applications. It is possible that by using high strength aluminum alloys based on an aluminum-copper (Al-Cu) system and permanent mold casting, the performance of these components can be enhanced significantly. This will also help to further reduce the weight. However, many technological obstacles need to be overcome before using these alloys in automotive applications in an economical way. There is very limited information in the open literature on gravity and low-pressure permanent mold casting of high strength aluminum alloys. This report summarizes the results and issues encountered during the casting trials of high strength aluminum alloy 206.0 (Al-Cu alloy) and moderate strength alloy 535.0 (Al-Mg alloy). Five engineering components were cast by gravity tilt-pour or low pressure permanent mold casting processes at CanmetMATERIALS (CMAT) and two production foundries. The results of the casting trials show that high integrity engineering components can be produced successfully from both alloys if specific processing parameters are used. It was shown that a combination of melt processing and mold temperature is necessary for the elimination of hot tears in both alloys.

  15. Cross-coupling reactions of unactivated alkyl halides

    E-Print Network [OSTI]

    Zhou, Jianrong (Jianrong Steve)

    2005-01-01

    My graduate research at MIT has been focused on the development of palladium- or nickel-catalyzed cross-coupling reactions using unactivated alkyl electrophiles (e.g., halides and sulfonates). Although aryl and alkenyl ...

  16. Assessing Global Terrestrial Sources of Methyl Halides - Ozone Regulating Gases 

    E-Print Network [OSTI]

    Gancarczyk, Maciej

    2010-11-24

    Methyl bromide (CH3Br) and methyl chloride (CH3Cl) play significant roles in the depletion of the stratospheric ozone layer. The vast portion of methyl halide sources and sinks sources and sinks are natural in origin. The ...

  17. Efficient Light-Emitting Diodes Based on Nanocrystalline Perovskite in a Dielectric Polymer Matrix

    E-Print Network [OSTI]

    Li, Guangru; Tan, Zhi-Kuang; Di, Dawei; Lai, May Ling; Jiang, Lang; Lim, Jonathan Hua-Wei; Friend, Richard H.; Greenham, Neil C.

    2015-02-24

    Electroluminescence in light-emitting devices relies on the encounter and radiative recombination of electrons and holes in the emissive layer. In organometal halide perovskite light-emitting diodes, poor film formation creates electrical shunting...

  18. Highly stable and high power efficiency tandem organic light-emitting diodes with transition metal oxide-based charge generation layers

    E-Print Network [OSTI]

    Demir, Hilmi Volkan

    efficiency improvement Transition metal oxide a b s t r a c t Tandem organic light-emitting diodes (OLEDs. Ó 2015 Elsevier B.V. All rights reserved. 1. Introduction Organic light-emitting diodes (OLEDs) [1 displays and lighting panels. However, before mass production of OLEDs for the consumer market can start

  19. New Energy Efficiency Standards for Metal Halide Lamp Fixtures...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Department's efforts to develop efficiency standards that cut carbon pollution and save money by saving energy, U.S. Energy Secretary Ernest Moniz today announced that the...

  20. Regeneration of zinc halide catalyst used in the hydrocracking of polynuclear hydrocarbons

    DOE Patents [OSTI]

    Gorin, Everett (San Rafael, CA)

    1978-01-01

    Improved recovery of spent molten zinc halide hydro-cracking catalyst is achieved in the oxidative vapor phase regeneration thereof by selective treatment of the zinc oxide carried over by the effluent vapors from the regeneration zone with hydrogen halide gas under conditions favoring the reaction of the zinc oxide with the hydrogen halide, whereby regenerated zinc halide is recovered in a solids-free state with little loss of zinc values.

  1. Metal Optics Based nanoLEDs: In Search of a Fast, Efficient, Nanoscale Light Emitter

    E-Print Network [OSTI]

    Eggleston, Michael Scott

    2015-01-01

    on Lasers and Electro- Optics (Optical Society of America,M. C. Wu, "Subwavelength metal-optic semiconductor nanopatchand V. Gill, "Fiber optic communication technologies: What’s

  2. Deep-Subwavelength Focusing and Steering of Light in an Aperiodic Metallic Waveguide Array Lieven Verslegers,* Peter B. Catrysse, Zongfu Yu, and Shanhui Fan

    E-Print Network [OSTI]

    Fan, Shanhui

    Deep-Subwavelength Focusing and Steering of Light in an Aperiodic Metallic Waveguide Array Lieven deep- subwavelength modes [14], provides important new oppor- tunities for manipulating light the side and achieve deep- subwavelength confinement [11]. In this Letter, we consider an aperiodic

  3. Method for providing adhesion to a metal surface

    DOE Patents [OSTI]

    Harrah, L.A.; Allred, R.E.; Wilson, K.V. Jr.

    1992-02-18

    A process for treating metal surfaces to obtain improved susceptibility to bonding with adhesive compositions is disclosed. A metal surface is oxidized with a halogen to form a monolayer of halide ions on the surface. The halide ions are then exchanged with azide ions to form an azide monolayer on the metal surface. Upon contact of the treated surface with an adhesive composition, the azide layer may be thermally or photochemically decomposed to form active nitrene species, which react to bond the adhesive composition to the metal surface.

  4. Method for providing adhesion to a metal surface

    DOE Patents [OSTI]

    Harrah, Larry A. (Albuquerque, NM); Allred, Ronald E. (Albuquerque, NM); Wilson, Jr., Kennard V. (Albuquerque, NM)

    1992-01-01

    A process for treating metal surfaces to obtain improved susceptibility to bonding with adhesive compositions is disclosed. A metal surface is oxidized with a halogen to form a monolayer of halide ions on the surface. The halide ions are then exchanged with azide ions to form an azide monolayer on the metal surface. Upon contact of the treated surface with an adhesive composition, the azide layer may be thermally or photochemically decomposed to form active nitrene species, which react to bond the adhesive composition to the metal surface.

  5. Journal of Light Emitting Diodes Vol 2 N0 1, April 2010 1 Abstract--In metal organic vapor phase epitaxy we developed

    E-Print Network [OSTI]

    Wetzel, Christian M.

    Journal of Light Emitting Diodes Vol 2 N0 1, April 2010 1 Abstract-- In metal organic vapor phase epitaxy we developed GaInN/GaN quantum well material suitable for 500 ­ 580 nm light emitting diodes at longer wavelengths. Index Terms-- a-plane GaN, GaInN, Green light emitting diode, m-plane GaN I

  6. Metal Optics Based nanoLEDs: In Search of a Fast, Efficient, Nanoscale Light Emitter

    E-Print Network [OSTI]

    Eggleston, Michael Scott

    2015-01-01

    G. Beausoleil, "Design of an efficient light-emitting diodethe Optical Excitation Efficiency of a Single Self-AssembledS. Nakagawa, "Energy-efficient 1060nm optical link operating

  7. White-light emission from mixing blue and red-emitting metal complexes

    E-Print Network [OSTI]

    Tew, Gregory N.

    that the efficiency of the blending phosphorescent dyes has been increased when blended with polymers since component to obtain the emitted color.38,39 Among these, the single layer technique is attractive due, due to differential aging of different components.41 . Renewed interest in metal­ligand complexes

  8. Two dimensional metallic photonic crystals for light trapping and anti-reflective coatings in thermophotovoltaic applications

    SciTech Connect (OSTI)

    Shemelya, Corey; DeMeo, Dante F.; Vandervelde, Thomas E. [The Renewable Energy and Applied Photonics Laboratories, Electrical and Computer Engineering, Tufts University, Medford, Massachusetts 02155 (United States)

    2014-01-13

    We report the development of a front-side contact design for thermophotovoltaics that utilizes metallic photonic crystals (PhCs). While this front-side grid replacement covers more surface area of the semiconductor, a higher percentage of photons is shown to be converted to usable power in the photodiode. This leads to a 30% increase in the short-circuit current of the gallium antimonide thermophotovoltaic cell.

  9. Lighting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACTThousand CubicResourcelogo and-E C H N13,CenterCenterLighting Sign In

  10. The dynamic behavior of thin-film ionic transition metal complex-based light-emitting electrochemical cells

    SciTech Connect (OSTI)

    Meier, Sebastian B., E-mail: sebastian.meier@belectric.com, E-mail: wiebke.sarfert@siemens.com [Department of Materials Science VI: Materials for Electronics and Energy Technology, Friedrich-Alexander-University of Erlangen-Nuremberg, 91058 Erlangen (Germany); Siemens AG, Corporate Technology, CT RTC MAT IEC-DE, 91058 Erlangen (Germany); Hartmann, David; Sarfert, Wiebke, E-mail: sebastian.meier@belectric.com, E-mail: wiebke.sarfert@siemens.com [Siemens AG, Corporate Technology, CT RTC MAT IEC-DE, 91058 Erlangen (Germany); Winnacker, Albrecht [Department of Materials Science VI: Materials for Electronics and Energy Technology, Friedrich-Alexander-University of Erlangen-Nuremberg, 91058 Erlangen (Germany)

    2014-09-14

    Light-emitting electrochemical cells (LECs) have received increasing attention during recent years due to their simple architecture, based on solely air-stabile materials, and ease of manufacture in ambient atmosphere, using solution-based technologies. The LEC's active layer offers semiconducting, luminescent as well as ionic functionality resulting in device physical processes fundamentally different as compared with organic light-emitting diodes. During operation, electrical double layers (EDLs) form at the electrode interfaces as a consequence of ion accumulation and electrochemical doping sets in leading to the in situ development of a light-emitting p-i-n junction. In this paper, we comment on the use of impedance spectroscopy in combination with complex nonlinear squares fitting to derive key information about the latter events in thin-film ionic transition metal complex-based light-emitting electrochemical cells based on the model compound bis-2-phenylpyridine 6-phenyl-2,2´-bipyridine iridium(III) hexafluoridophosphate ([Ir(ppy)?(pbpy)][PF?]). At operating voltages below the bandgap potential of the ionic complex used, we obtain the dielectric constant of the active layer, the conductivity of mobile ions, the transference numbers of electrons and ions, and the thickness of the EDLs, whereas the transient thickness of the p-i-n junction is determined at voltages above the bandgap potential. Most importantly, we find that charge transport is dominated by the ions when carrier injection from the electrodes is prohibited, that ion movement is limited by the presence of transverse internal interfaces and that the width of the intrinsic region constitutes almost 60% of the total active layer thickness in steady state at a low operating voltage.

  11. ZnO light-emitting diode grown by plasma-assisted metal organic chemical vapor deposition

    SciTech Connect (OSTI)

    Xu, W.Z.; Ye, Z.Z.; Zeng, Y.J.; Zhu, L.P.; Zhao, B.H.; Jiang, L.; Lu, J.G.; He, H.P.; Zhang, S.B. [State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027 (China); National Renewable Energy Laboratory, Golden, Colorado 80401 (United States)

    2006-04-24

    We report a breakthrough in fabricating ZnO homojunction light-emitting diode by metal organic chemical vapor deposition. Using NO plasma, we are able to grow p-type ZnO thin films on n-type bulk ZnO substrates. The as-grown films on glass substrates show hole concentration of 10{sup 16}-10{sup 17} cm{sup -3} and mobility of 1-10 cm{sup 2} V{sup -1} s{sup -1}. Room-temperature photoluminescence spectra reveal nitrogen-related emissions. A typical ZnO homojunction shows rectifying behavior with a turn-on voltage of about 2.3 V. Electroluminescence at room temperature has been demonstrated with band-to-band emission at I=40 mA and defect-related emissions in the blue-yellow spectrum range.

  12. Impact of Fuel Metal Impurities on the Durability of a Light-Duty Diesel Aftertreatment System

    SciTech Connect (OSTI)

    Williams, A.; Burton, J.; McCormick, R. L.; Toops, T.; Wereszczak, A. A.; Fox, E. E.; Lance, M. J.; Cavataio, G.; Dobson, D.; Warner, J.; Brezny, R.; Nguyen, K.; Brookshear, D. W.

    2013-04-01

    Alkali and alkaline earth metal impurities found in diesel fuels are potential poisons for diesel exhaust catalysts. A set of diesel engine production exhaust systems was aged to 150,000 miles. These exhaust systems included a diesel oxidation catalyst, selective catalytic reduction (SCR) catalyst, and diesel particulate filter (DPF). Four separate exhaust systems were aged, each with a different fuel: ultralow sulfur diesel containing no measureable metals, B20 (a common biodiesel blend) containing sodium, B20 containing potassium, and B20 containing calcium, which were selected to simulate the maximum allowable levels in B100 according to ASTM D6751. Analysis included Federal Test Procedure emissions testing, bench-flow reactor testing of catalyst cores, electron probe microanalysis (EPMA), and measurement of thermo-mechanical properties of the DPFs. EPMA imaging found that the sodium and potassium penetrated into the washcoat, while calcium remained on the surface. Bench-flow reactor experiments were used to measure the standard nitrogen oxide (NOx) conversion, ammonia storage, and ammonia oxidation for each of the aged SCR catalysts. Vehicle emissions tests were conducted with each of the aged catalyst systems using a chassis dynamometer. The vehicle successfully passed the 0.2 gram/mile NOx emission standard with each of the four aged exhaust systems.

  13. Investigation of Heat Transfer at the Mold/Metal Interface in Permanent Mold Casting of Light Alloys

    SciTech Connect (OSTI)

    Robert D. Pehlke; John T. Berry

    2005-12-16

    Accurate modeling of the metal casting process prior to creating a mold design demands reliable knowledge of the interfacial heat transfer coefficient at the mold metal interface as a function of both time and location. The phenomena concerned with the gap forming between the mold and the solidifying metal are complex but need to be understood before any modeling is attempted. The presence of mold coatings further complicates the situation. A commercial casting was chosen and studied in a gravity permanent mold casting process. The metal/mold interfacial heat transfer coefficient (IHTC) was the focus of the research. A simple, direct method has been used to evaluate the IHTC. Both the simulation and experiments have shown that a reasonably good estimate of the heat transfer coefficient could be made in the case studied. It has been found that there is a good agreement between experiments and simulations in the temperature profiles during the solidification process, given that the primary mechanism of heat transfer across the gap in permanent mold casting of light alloys is by conduction across the gap. The procedure utilized to determine the interfacial heat transfer coefficient can be applied to other casting processes. A recently completed project involving The University of Michigan and Mississippi State University, together with several industrial partners, which was supported by the USDOE through the Cast Metals Coalition, examined a number of cases of thermal contact. In an investigation which gave special consideration to the techniques of measurement, several mold coatings were employed and results presented as a function of time. Realistic conditions of coating thickness and type together with an appropriate combination of mold preheat and metal pouring temperature were strictly maintained throughout the investigation. Temperature sensors, in particular thermocouples, play an important part in validating the predictions of solidification models. Cooling curve information, as well as temperature gradient history both in the solidifying metal and within the mold are invariably required to be validated. This validation depends upon the response of the sensor concerned, but also on its own effect upon the thermal environment. A joint university/industry team has completed an investigation of the invasive effects of thermocouples upon temperature history in permanent molds determining the degree of uncertainty associated with placement and indicating how the time-temperature history may be recovered. In addition to its relevance to the all important study of thermal contact of the casting with metallic molds, the observations also impact the determination of heat flux and interfacial heat transfer coefficients. In these respects the study represents the first of its kind that has tackled the problem in depth for permanent mold castings. An important ramification of this investigation has been the errors likely to be encountered in mold temperature measurement with thin section aluminum castings, especially with respect to the plans for thermocouple placement. A comparison between the degree of uncertainty experienced in sand molds compared with that found in permanent molds reveals that the associated problems have a lesser impact. These conclusions and the related recommendations have been disseminated to industry and the technical community through project reports and publications.

  14. Scattered Light Interference from a Single Metal Nanoparticle and Its Mirror Image Sang-Kee Eah,, Heinrich M. Jaeger,, Norbert F. Scherer,,| Gary P. Wiederrecht, and

    E-Print Network [OSTI]

    Scherer, Norbert F.

    as an efficient way to transport energy on a small length scale.11 Small metal nano- particles are also being distance measurement with 10 nm resolution through this nonintrusive far field interferometry. Spontaneous energy levels. Changing the photonic mode density near a light emitter by placing it near a mirror

  15. Impact of the organic halide salt on final perovskite composition for photovoltaic applications

    SciTech Connect (OSTI)

    Moore, David T.; Sai, Hiroaki; Wee Tan, Kwan; Estroff, Lara A.; Wiesner, Ulrich

    2014-08-01

    The methylammonium lead halide perovskites have shown significant promise as a low-cost, second generation, photovoltaic material. Despite recent advances, however, there are still a number of fundamental aspects of their formation as well as their physical and electronic behavior that are not well understood. In this letter we explore the mechanism by which these materials crystallize by testing the outcome of each of the reagent halide salts. We find that components of both salts, lead halide and methylammonium halide, are relatively mobile and can be readily exchanged during the crystallization process when the reaction is carried out in solution or in the solid state. We exploit this fact by showing that the perovskite structure is formed even when the lead salt's anion is a non-halide, leading to lower annealing temperature and time requirements for film formation. Studies into these behaviors may ultimately lead to improved processing conditions for photovoltaic films.

  16. WASP-36b: A NEW TRANSITING PLANET AROUND A METAL-POOR G-DWARF, AND AN INVESTIGATION INTO ANALYSES BASED ON A SINGLE TRANSIT LIGHT CURVE

    SciTech Connect (OSTI)

    Smith, A. M. S.; Anderson, D. R.; Hellier, C.; Maxted, P. F. L.; Smalley, B.; Southworth, J.; Collier Cameron, A.; Gillon, M.; Jehin, E.; Lendl, M.; Queloz, D.; Triaud, A. H. M. J.; Pepe, F.; Segransan, D.; Udry, S.; West, R. G.; Barros, S. C. C.; Pollacco, D.; Street, R. A.

    2012-04-15

    We report the discovery, from WASP and CORALIE, of a transiting exoplanet in a 1.54 day orbit. The host star, WASP-36, is a magnitude V = 12.7, metal-poor G2 dwarf (T{sub eff} = 5959 {+-} 134 K), with [Fe/H] =-0.26 {+-} 0.10. We determine the planet to have mass and radius, respectively, 2.30 {+-} 0.07 and 1.28 {+-} 0.03 times that of Jupiter. We have eight partial or complete transit light curves, from four different observatories, which allow us to investigate the potential effects on the fitted system parameters of using only a single light curve. We find that the solutions obtained by analyzing each of these light curves independently are consistent with our global fit to all the data, despite the apparent presence of correlated noise in at least two of the light curves.

  17. Role of surface profiles in surface plasmon-polariton-mediated emission of light through a thin metal film

    E-Print Network [OSTI]

    Exeter, University of

    such as organic light-emitting diodes. 1. Introduction The field of organic light-emitting diodes (OLEDs, several research laboratories have begun to explore top-emitting OLEDs where light is emitted through of topical concern [5, 6]. Light is produced in OLEDs when excitons formed by the injection of opposite

  18. Replacement of Lighting Fixtures with LED Energy Efficient Lights at the Parking Facility, Milwaukee, Wisconsin

    SciTech Connect (OSTI)

    David Brien

    2012-06-21

    The Forest County Potawatomi Community (FCPC or Tribe) owns a six-story parking facility adjacent to its Potawatomi Bingo Casino (the Casino) in Milwaukee, Wisconsin, as well as a valet parking facility under the Casino (collectively, the Parking Facility). The Parking Facility contained 205-watt metal halide-type lights that, for security reasons, operated 24 hours per day, 7 days per week. Starting on August 30, 2010, the Tribe replaced these fixtures with 1,760 state-of-the-art, energy efficient 55-Watt LED lights. This project resulted in an immediate average reduction in monthly peak demand of 238 kW over the fourth quarter of 2010. The average reduction in monthly peak demand from October 1 through December 31, 2010 translates into a forecast annual electrical energy reduction of approximately 1,995,000 kWh or 47.3% of the pre-project demand. This project was technically effective, economically feasible, and beneficial to the public not only in terms of long term energy efficiency and associated emissions reductions, but also in the short-term jobs provided for the S.E. Wisconsin region. The project was implemented, from approval by U.S. Department of Energy (DOE) to completion, in less than 6 months. The project utilized off-the-shelf proven technologies that were fabricated locally and installed by local trade contractors.

  19. Surface plasmon dispersion engineering via double-metallic AU/AG layers for nitride light-emitting diodes

    DOE Patents [OSTI]

    Tansu, Nelson; Zhao, Hongping; Zhang, Jing; Liu, Guangyu

    2014-04-01

    A double-metallic deposition process is used whereby adjacent layers of different metals are deposited on a substrate. The surface plasmon frequency of a base layer of a first metal is tuned by the surface plasmon frequency of a second layer of a second metal formed thereon. The amount of tuning is dependent upon the thickness of the metallic layers, and thus tuning can be achieved by varying the thicknesses of one or both of the metallic layers. In a preferred embodiment directed to enhanced LED technology in the green spectrum regime, a double-metallic Au/Ag layer comprising a base layer of gold (Au) followed by a second layer of silver (Ag) formed thereon is deposited on top of InGaN/GaN quantum wells (QWs) on a sapphire/GaN substrate.

  20. Two-photon pumped lead halide perovskite nanowire lasers

    E-Print Network [OSTI]

    Gu, Zhiyuan; Sun, Wenzhao; Li, Jinakai; Liu, Shuai; Song, Qinghai; Xiao, Shumin

    2015-01-01

    Solution-processed lead halide perovskites have shown very bright future in both solar cells and microlasers. Very recently, the nonlinearity of perovskites started to attract considerable research attention. Second harmonic generation and two-photon absorption have been successfully demonstrated. However, the nonlinearity based perovskite devices such as micro- & nano- lasers are still absent. Here we demonstrate the two-photon pumped nanolasers from perovskite nanowires. The CH3NH3PbBr3 perovskite nanowires were synthesized with one-step solution self-assembly method and dispersed on glass substrate. Under the optical excitation at 800 nm, two-photon pumped lasing actions with periodic peaks have been successfully observed at around 546 nm. The obtained quality (Q) factors of two-photon pumped nanolasers are around 960, and the corresponding thresholds are about 674?J=cm2. Both the Q factors and thresholds are comparable to conventional whispering gallery modes in two-dimensional polygon microplates. Ou...

  1. Negishi Coupling of Secondary Alkylzinc Halides with Aryl Bromides and Chlorides

    E-Print Network [OSTI]

    Han, Chong

    An efficient palladium-catalyzed process has been developed for Negishi coupling of secondary alkylzinc halides with a wide range of aryl bromides and activated aryl chlorides. A palladium catalyst composed of a new ...

  2. Size-dependent Photon Emission from Organometal Halide Perovskite Nanocrystals Embedded in an Organic Matrix

    E-Print Network [OSTI]

    Di, Dawei; Musselman, Kevin P.; Li, Guangru; Sadhanala, Aditya; Ievskaya, Yulia; Song, Qilei; Tan, Zhi-Kuang; Lai, May Ling; MacManus-Driscoll, Judith L.; Greenham, Neil C.; Friend, Richard H.

    2015-01-14

    In recent years, organometal halide perovskite materials have attracted significant research interest in the field of optoelectronics. Here we introduce a simple and low temperature route for the formation of self-assembled perovskite nanocrystals...

  3. Methods for synthesizing alane without the formation of adducts and free of halides

    DOE Patents [OSTI]

    Zidan, Ragaiy; Knight, Douglas A; Dinh, Long V

    2013-02-19

    A process is provided to synthesize an alane without the formation of alane adducts as a precursor. The resulting product is a crystallized .alpha.-alane and is a highly stable product and is free of halides.

  4. A Solid-State 199Hg NMR Study of Mercury Halides

    E-Print Network [OSTI]

    Taylor, Robert E; Bai, Shi; Dybowski, Cecil

    2011-01-01

    550 (1998), 89-99. [25] R. E. Taylor, C. T. Carver, R. E.7 (1997), 333-336. [33] R. E. Taylor, Concepts Magn. Reson.Study of Mercury Halides R. E. Taylor 1 *, Shi Bai 2 , and

  5. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    Technical Feasibility Assessment of LED Roadway Lighting on the Golden Gate Bridge Tuenge Jason R LED induction ceramic metal halide plasma roadway lighting Golden Gate Bridge LED...

  6. Potential Environmental Impacts from the Metals in Incandescent, Compact Fluorescent Lamp (CFL), and Light-Emitting Diode (LED)

    E-Print Network [OSTI]

    Short, Daniel

    Potential Environmental Impacts from the Metals in Incandescent, Compact Fluorescent Lamp (CFL, previous studies have investigated various environmental impacts from incandescent, CFL, and LED bulbs. There is uncertainty about the potential environmental impacts of these components and whether special provisions must

  7. A mechanistic study of aryl halide reactions with lithium aluminum hydride 

    E-Print Network [OSTI]

    Chung, Fu-Fan

    1980-01-01

    A M:"CHA~JISTIC STUDv OF ARYL HALID RHAC IC~JS ' ITH LITHIUM ALUM 'J"M HYDRIDE A Thesis FU-FAJJ CHUI'JG Submitted to the Graduate College of Texas ARM University in nartial fulfillment of the reauirement for the degree of MASTER OF SCI- JC... August Jo80 Major Subject: Chemistry A MECHANISTIC STUDY OF ARYL HALIDE REACTIONS 1'IITH LITHIUM ALUMINUM HYDRIDE A Thesis by FU-FAN CHUNG Approved as to style and content by; (Chairman of Co ittee) (Member) , . 7 1 (Member) (Member) i (Head...

  8. Light-induced hysteresis and recovery behaviors in photochemically activated solution-processed metal-oxide thin-film transistors

    SciTech Connect (OSTI)

    Jo, Jeong-Wan; Park, Sung Kyu E-mail: skpark@cau.ac.kr; Kim, Yong-Hoon E-mail: skpark@cau.ac.kr

    2014-07-28

    In this report, photo-induced hysteresis, threshold voltage (V{sub T}) shift, and recovery behaviors in photochemically activated solution-processed indium-gallium-zinc oxide (IGZO) thin-film transistors (TFTs) are investigated. It was observed that a white light illumination caused negative V{sub T} shift along with creation of clockwise hysteresis in electrical characteristics which can be attributed to photo-generated doubly ionized oxygen vacancies at the semiconductor/gate dielectric interface. More importantly, the photochemically activated IGZO TFTs showed much reduced overall V{sub T} shift compared to thermally annealed TFTs. Reduced number of donor-like interface states creation under light illumination and more facile neutralization of ionized oxygen vacancies by electron capture under positive gate potential are claimed to be the origin of the less V{sub T} shift in photochemically activated TFTs.

  9. THE ORIGINS OF LIGHT AND HEAVY R-PROCESS ELEMENTS IDENTIFIED BY CHEMICAL TAGGING OF METAL-POOR STARS

    SciTech Connect (OSTI)

    Tsujimoto, Takuji; Shigeyama, Toshikazu

    2014-11-01

    Growing interests in neutron star (NS) mergers as the origin of r-process elements have sprouted since the discovery of evidence for the ejection of these elements from a short-duration ?-ray burst. The hypothesis of a NS merger origin is reinforced by a theoretical update of nucleosynthesis in NS mergers successful in yielding r-process nuclides with A > 130. On the other hand, whether the origin of light r-process elements are associated with nucleosynthesis in NS merger events remains unclear. We find a signature of nucleosynthesis in NS mergers from peculiar chemical abundances of stars belonging to the Galactic globular cluster M15. This finding combined with the recent nucleosynthesis results implies a potential diversity of nucleosynthesis in NS mergers. Based on these considerations, we are successful in the interpretation of an observed correlation between [light r-process/Eu] and [Eu/Fe] among Galactic halo stars and accordingly narrow down the role of supernova nucleosynthesis in the r-process production site. We conclude that the tight correlation by a large fraction of halo stars is attributable to the fact that core-collapse supernovae produce light r-process elements while heavy r-process elements such as Eu and Ba are produced by NS mergers. On the other hand, stars in the outlier, composed of r-enhanced stars ([Eu/Fe] ? +1) such as CS22892-052, were exclusively enriched by matter ejected by a subclass of NS mergers that is inclined to be massive and consist of both light and heavy r-process nuclides.

  10. Enhancement of Raman Light Scattering in Dye-Labeled Rat Glioma Cells by Langmuir-Blodgett CNT-Bundles Arranged on Metal-Containing Conducting Polymer Film

    E-Print Network [OSTI]

    Egorov, A S; Grushevskaya, H V; Krot, V I; Krylova, N G; Lipnevich, I V; Orekhovskaya, T I; Shulitsky, B G

    2015-01-01

    We have fabricated layered nanocomposite consisting of a nanoporous anodic alumina sublayer (AOA), an ultrathin metal-containing polymer Langmuir-Blodgett (LB) film coating AOA, and multi-walled carbon nanotube (MCNT) - bundles which are arranged on the LB-film. MCNTs were preliminarily chemically modified by carboxyl groups and functionalized by stearic acid. We have experimentally observed an enhancement of Raman light scattering on surface plasmons in the LB-monolayers. This enhancement is due to charge and energy transfer. We demonstrate that propidium iodide (PI) fluorescence is quenched by the MCNT-bundles. A method of two-dimensional system imaging based on the MCNT-enhanced Raman spectroscopy has been proposed. This method has been applied to visualize focal adhesion sites on membranes of living PI-labeled rat glioma cells.

  11. The origins of light and heavy r-process elements identified by chemical tagging of metal-poor stars

    E-Print Network [OSTI]

    Tsujimoto, Takuji

    2014-01-01

    Growing interests in neutron star (NS) mergers as the origin of r-process elements have sprouted since the discovery of evidence for the ejection of these elements from a short-duration gamma-ray burst. The hypothesis of a NS merger origin is reinforced by a theoretical update of nucleosynthesis in NS mergers successful in yielding r-process nuclides with A>130. On the other hand, whether the origin of light r-process elements are associated with nucleosynthesis in NS merger events remains unclear. We find a signature of nucleosynthesis in NS mergers from peculiar chemical abundances of stars belonging to the Galactic globular cluster M15. This finding combined with the recent nucleosynthesis results implies a potential diversity of nucleosynthesis in NS mergers. Based on these considerations, we are successful in the interpretation of an observed correlation between [light r-process/Eu] and [Eu/Fe] among Galactic halo stars and accordingly narrow down the role of supernova nucleosynthesis in the r-process pr...

  12. Palladium-catalyzed reaction of allyl halides with a-diazocarbonyl Shufeng Chen and Jianbo Wang*

    E-Print Network [OSTI]

    Wang, Jianbo

    Palladium-catalyzed reaction of allyl halides with a-diazocarbonyl compoundsw Shufeng Chen-Allylic palladium complexes are important intermediates in palladium-catalyzed reactions.1 The p-allylic palladium,3-dicarbonyl compounds.2 In connection to our recent interest in the palladium-catalyzed reaction of diazo

  13. A VIBRATIONAL SPECTROSCOPIC STUDY OF AQUEOUS HYDROGEN HALIDE SOLUTIONS: APPLICATION TO ATMOSPHERIC AEROSOL CHEMISTRY

    E-Print Network [OSTI]

    Heterogeneous reactions on the surfaces of atmospheric aerosols play an important role in atmospheric chemistryA VIBRATIONAL SPECTROSCOPIC STUDY OF AQUEOUS HYDROGEN HALIDE SOLUTIONS: APPLICATION TO ATMOSPHERIC AEROSOL CHEMISTRY A Thesis Presented in Partial Fulfillment of the Requirements for the Degree Master

  14. Preferential Eu Site Occupation and Its Consequences in the Ternary Luminescent HalidesAB2I5:Eu2+(A=LiCs;B=Sr, Ba)

    SciTech Connect (OSTI)

    Fang, C.? M.; Biswas, Koushik

    2015-07-22

    Several rare-earth-doped, heavy-metal halides have recently been identified as potential next-generation luminescent materials with high efficiency at low cost. AB2I5:Eu2+ (A=Li–Cs; B=Sr, Ba) is one such family of halides. Its members, such as CsBa2I5:Eu2+ and KSr2I5:Eu2+, are currently being investigated as high-performance scintillators with improved sensitivity, light yield, and energy resolution less than 3% at 662 keV. Within the AB2I5 family, our first-principles-based calculations reveal two remarkably different trends in Eu site occupation. The substitutional Eu ions occupy both eightfold-coordinated B1(VIII) and the sevenfold-coordinated B2(VII) sites in the Sr-containing compounds. However, in the Ba-containing crystals, Eu ions strongly prefer the B2(VII)sites. This random versus preferential distribution of Eu affects their electronic properties. The calculations also suggest that in the Ba-containing compounds one can expect the formation of Eu-rich domains. These results provide atomistic insight into recent experimental observations about the concentration and temperature effects in Eu-doped CsBa2I5. We discuss the implications of our results with respect to luminescent properties and applications. We also hypothesize Sr, Ba-mixed quaternary iodides ABaVIIISrVIII5:Eu as scintillators having enhanced homogeneity and electronic properties.

  15. Extraction of trace metals from fly ash

    DOE Patents [OSTI]

    Blander, Milton (Palos Park, IL); Wai, Chien M. (Moscow, ID); Nagy, Zoltan (Woodridge, IL)

    1984-01-01

    A process for recovering silver, gallium and/or other trace metals from a fine grained industrial fly ash associated with a process for producing phosphorous, the fly ash having a silicate base and containing surface deposits of the trace metals as oxides, chlorides or the like, with the process being carried out by contacting the fly ash with AlCl.sub.3 in an alkali halide melt to react the trace metals with the AlCl.sub.3 to form compositions soluble in the melt and a residue containing the silicate and aluminum oxide or other aluminum precipitate, and separating the desired trace metal or metals from the melt by electrolysis or other separation techniques.

  16. Extraction of trace metals from fly ash

    DOE Patents [OSTI]

    Blander, M.; Wai, C.M.; Nagy, Z.

    1983-08-15

    A process is described for recovering silver, gallium and/or other trace metals from a fine grained industrial fly ash associated with a process for producing phosphorous. The fly ash has a silicate base and contains surface deposits of the trace metals as oxides, chlorides or the like. The process is carried out by contacting the fly ash with AlCl/sub 3/ in an alkali halide melt to react the trace metals with the AlCl/sub 3/ to form compositions soluble in the melt and a residue containing the silicate and aluminum oxide or other aluminum precipitate, and separating the desired trace metal or metals from the melt by electrolysis or other separation techniques.

  17. Electroluminescence from Organometallic Lead Halide Perovskite - Conjugated Polymer Diodes

    E-Print Network [OSTI]

    Sadhanala, Aditya; Kumar, Abhishek; Pathak, Sandeep; Rao, Akshay; Steiner, Ullrich; Greenham, Neil C.; Snaith, Henry J.; Friend, Richard H.

    2015-02-19

    Organometallic lead perovskite-based solar cells can be converted to light-emitting diodes by engineering the current density. Diodes are fabricated with adjacent perovskite and conjugated polymer layers using orthogonal solvents. Under forward bias...

  18. EECBG Success Story: Grant Improves Comfort for Nevada City's...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    depot. There was just one problem: it was built before central heating or air-conditioning. Learn more. Addthis Related Articles Metal halide light fixtures at Pompey Park...

  19. New Energy Efficiency Standards for Metal Halide Lamp Fixtures to Save on

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on DeliciousMathematicsEnergyInterested Parties -DepartmentAvailable for Public Comment (March 2012) |NewEnergy Bills

  20. Enhanced open voltage of BiFeO{sub 3} polycrystalline film by surface modification of organolead halide perovskite

    SciTech Connect (OSTI)

    Zhao, Pengjun; Bian, Liang; Xu, Jinbao Chang, Aimin; Wang, Lei

    2014-07-07

    Inorganic-organolead halide perovskite CH{sub 3}NH{sub 3}PbI{sub 3} modified BiFeO{sub 3} polycrystalline film has been established. The composite photoelectrode presents much larger open voltage and several magnitudes superior photoelectric conversion performance in comparison to the ordinary BiFeO{sub 3} polycrystalline film. The I-V curve shows that the short-circuit current (J{sub sc}) is 1.74?mA·cm{sup ?2} and open-circuit voltage (V{sub oc}) is 1.62?V, the device's photon to current efficiency is over 1%. The large open voltage and high photovoltaic efficiency is believed to attributed to the spontaneous polarization of composite perovskite induced by BiFeO{sub 3} lattice and modified reduced work function of the modified BiFeO{sub 3} surface. Our results clearly show that the present BiFeO{sub 3}-CH{sub 3}NH{sub 3}PbI{sub 3} planar device is capable to generate a large voltage in macro scale under visible light, leading an approach to further applications on photodetectors and optoelectronic switch.

  1. Ligand-Controlled Palladium-Catalyzed Regiodivergent Suzuki–Miyaura Cross-Coupling of Allylboronates and Aryl Halides

    E-Print Network [OSTI]

    Yang, Yang

    An orthogonal set of catalyst systems has been developed for the Suzuki–Miyaura coupling of 3,3-disubstituted and 3-monosubstituted allylboronates with (hetero)aryl halides. These methods allow for the highly selective ...

  2. Palladium-Catalyzed Hydroxylation of Aryl and Heteroaryl Halides Enabled by the Use of a Palladacycle Precatalyst

    E-Print Network [OSTI]

    Cheung, Chi Wai

    A method for the hydroxylation of aryl and heteroaryl halides, promoted by a catalyst based on a biarylphosphine ligand tBuBrettPhos (L5) and its corresponding palladium precatalyst (1), is described. The reactions allow ...

  3. Method for forming metal contacts

    DOE Patents [OSTI]

    Reddington, Erik; Sutter, Thomas C; Bu, Lujia; Cannon, Alexandra; Habas, Susan E; Curtis, Calvin J; Miedaner, Alexander; Ginley, David S; Van Hest, Marinus Franciscus Antonius Maria

    2013-09-17

    Methods of forming metal contacts with metal inks in the manufacture of photovoltaic devices are disclosed. The metal inks are selectively deposited on semiconductor coatings by inkjet and aerosol apparatus. The composite is heated to selective temperatures where the metal inks burn through the coating to form an electrical contact with the semiconductor. Metal layers are then deposited on the electrical contacts by light induced or light assisted plating.

  4. Controlled Synthesis of Organic/Inorganic van de Waals Solid for Tunable Light-matter Interactions

    E-Print Network [OSTI]

    Niu, Lin; Cong, Chunxiao; Wu, Chunyang; Wu, Di; Chang, Tay-Rong; Wang, Hong; Zeng, Qingsheng; Zhou, Jiadong; Wang, Xingli; Fu, Wei; Yu, Peng; Fu, Qundong; Zhang, Zhuhua; Yakobson, Boris I; Tay, Beng Kang; Jeng, Horng-Tay; Lin, Hsin; Sum, Tze Chien; Jin, Chuanhong; He, Haiyong; Yu, Ting; Liu, Zheng

    2015-01-01

    Van de Waals (vdW) solids, as a new type of artificial materials that consisting of alternative layers bonded by weak interactions, have shed light on fantastic optoelectronic devices. As a result, a large variety of shining vdW devices have been engineered via layer-by-layer stacking of two-dimensional materials, although shadowed by the difficulties of fabrication. Alternatively, direct growth of vdW solids have been proved a scalable and swift way towards vdW solids, reflected by the successful synthesis of graphene/h-BN and transition metal dichalcogenides (TMDs) vertical heterostructures from controlled vapor deposition. Enlightened by it, with a three-step deposition and reaction, we realize high-quality organic and inorganic vdW solids, using methylammonium lead halide as the organic part (organic perovskite) and 2D monolayers inorganic as counterpart. Being a perfect light absorbent, the electrons and holes generated in organic perovskite couple with its inorganic 2D companions, and behave dramaticall...

  5. Metal Hydride Hydrogen Storage Research and Development

    Broader source: Energy.gov [DOE]

    DOE's research on complex metal hydrides targets the development of advanced metal hydride materials including light-weight complex hydrides, destabilized binary hydrides, intermetallic hydrides,...

  6. Investigation into Nanostructured Lanthanum Halides and CeBr{sub 3} for Nuclear Radiation Detection

    SciTech Connect (OSTI)

    Guss, P., Guise, R., Mukhopadhyay, S., Yuan, D.

    2011-06-22

    This slide-show presents work on radiation detection with nanostructured lanthanum halides and CeBr{sub 3}. The goal is to extend the gamma energy response on both low and high-energy regimes by demonstrating the ability to detect low-energy x-rays and relatively high-energy activation prompt gamma rays simultaneously using the nano-structured lanthanum bromide, lanthanum fluoride, cerium bromide, or other nanocrystal material. Homogeneous and nano structure cases are compared.

  7. Reactions of stannylamines and anionic main group metal halides : : a mild route to novel main group metal-nitrogen compounds

    E-Print Network [OSTI]

    Wilson, Robert James

    2013-01-01

    Rodriguez-Monge, L. ; Taylor, R. ; van de Streek, J. ; Wood,Rodriguez-Monge, L. ; Taylor, R. ; van de Streek, J. ; Wood,Rodriguez-Monge, L. ; Taylor, R. ; van de Streek, J. ; Wood,

  8. Light Metals Permanent Mold Casting

    SciTech Connect (OSTI)

    None

    2004-11-01

    The research will develop the gravity and/or low-pressure permanent-mold casting processes with sand or permanent-mold cores for aluminum and magnesium based alloys.

  9. Halide-Dependent Electronic Structure of Organolead Perovskite Andrei Buin, Riccardo Comin, Jixian Xu, Alexander H. Ip, and Edward H. Sargent*

    E-Print Network [OSTI]

    Sargent, Edward H. "Ted"

    Halide-Dependent Electronic Structure of Organolead Perovskite Materials Andrei Buin, Riccardo Engineering, University of Toronto, Toronto, Ontario, Canada M5S 3G4 ABSTRACT: Organometal halide perovskites perovskite-based photovoltaic technology. In addition to this, the performance of perovskite-based devices

  10. Fabrication of large-volume, low-cost ceramic lanthanum halide scintillators for gamma ray detection : final report for DHS/DNDO/TRDD project TA-01-SL01.

    SciTech Connect (OSTI)

    Boyle, Timothy J.; Ottley, Leigh Anna M.; Yang, Pin; Chen, Ching-Fong; Sanchez, Margaret R.; Bell, Nelson Simmons

    2008-10-01

    This project uses advanced ceramic processes to fabricate large, optical-quality, polycrystalline lanthanum halide scintillators to replace small single crystals produced by the conventional Bridgman growth method. The new approach not only removes the size constraint imposed by the growth method, but also offers the potential advantages of both reducing manufacturing cost and increasing production rate. The project goal is to fabricate dense lanthanum halide ceramics with a preferred crystal orientation by applying texture engineering and solid-state conversion to reduce the thermal mechanical stress in the ceramic and minimize scintillation light scattering at grain boundaries. Ultimately, this method could deliver the sought-after high sensitivity and <3% energy resolution at 662 keV of lanthanum halide scintillators and unleash their full potential for advanced gamma ray detection, enabling rapid identification of radioactive materials in a variety of practical applications. This report documents processing details from powder synthesis, seed particle growth, to final densification and texture development of cerium doped lanthanum bromide (LaBr{sub 3}:Ce{sup +3}) ceramics. This investigation demonstrated that: (1) A rapid, flexible, cost efficient synthesis method of anhydrous lanthanum halides and their solid solutions was developed. Several batches of ultrafine LaBr{sub 3}:Ce{sup +3} powder, free of oxyhalide, were produced by a rigorously controlled process. (2) Micron size ({approx} 5 {micro}m), platelet shape LaBr{sub 3} seed particles of high purity can be synthesized by a vapor phase transport process. (3) High aspect-ratio seed particles can be effectively aligned in the shear direction in the ceramic matrix, using a rotational shear-forming process. (4) Small size, highly translucent LaBr{sub 3} (0.25-inch diameter, 0.08-inch thick) samples were successfully fabricated by the equal channel angular consolidation process. (5) Large size, high density, translucent LaBr{sub 3} ceramics samples (3-inch diameter, > 1/8-inch thick) were fabricated by hot pressing, demonstrating the superior manufacturability of the ceramic approach over single crystal growth methods in terms of size capability and cost. (6) Despite all these advances, evidence has shown that LaBr{sub 3} is thermally unstable at temperatures required for the densification process. This is particularly true for material near the surface where lattice defects and color centers can be created as bromine becomes volatile at high temperatures. Consequently, after densification these samples made using chemically prepared ultrafine powders turned black. An additional thermal treatment in a flowing bromine condition proved able to reduce the darkness of the surface layer for these densified samples. These observations demonstrated that although finer ceramic powders are desirable for densification due to a stronger driving force from their large surface areas, the same desirable factor can lead to lattice defects and color centers when these powders are densified at higher temperatures where material near the surface becomes thermally unstable.

  11. Band gaps and structural properties of graphene halides and their derivates: A hybrid functional study with localized orbital basis sets

    E-Print Network [OSTI]

    Karlický, František; Otyepka, Michal; 10.1063/1.4736998

    2012-01-01

    DFT calculations of the electronic structure of graphane and stoichiometrically halogenated graphene derivatives (fluorographene and other analogous graphene halides) show (i) localized orbital basis sets can be successfully and effectively used for such 2D materials; (ii) several functionals predict that the band gap of graphane is greater than that of fluorographene, whereas HSE06 gives the opposite trend; (iii) HSE06 functional predicts quite good values of band gaps w.r.t benchmark theoretical and experimental data; (iv) the zero band gap of graphene is opened by hydrogenation and halogenation and strongly depends on the chemical composition of mixed graphene halides; (v) the stability of graphene halides decreases sharply with increasing size of the halogen atom - fluorographene is stable, whereas graphene iodide spontaneously decomposes. In terms of band gap and stability, the C2FBr, and C2HBr derivatives seem to be promising materials, e.g., for (opto)electronics applications, because their band gaps a...

  12. Advances in the growth of alkaline-earth halide single crystals for scintillator detectors

    SciTech Connect (OSTI)

    Boatner, Lynn A; Ramey, Joanne Oxendine; Kolopus, James A; Neal, John S; Cherepy, Nerine; Payne, Stephen A.; Beck, P; Burger, Arnold; Rowe, E; Bhattacharya, P.

    2014-01-01

    Alkaline-earth scintillators such as strontium iodide and other alkaline-earth halides activated with divalent europium represent some of the most efficient and highest energy resolution scintillators for use as gamma-ray detectors in a wide range of applications. These applications include the areas of nuclear nonproliferation, homeland security, the detection of undeclared nuclear material, nuclear physics and materials science, medical diagnostics, space physics, high energy physics, and radiation monitoring systems for first responders, police, and fire/rescue personnel. Recent advances in the growth of large single crystals of these scintillator materials hold the promise of higher crystal yields and significantly lower detector production costs. In the present work, we describe new processing protocols that, when combined with our molten salt filtration methods, have led to advances in achieving a significant reduction of cracking effects during the growth of single crystals of SrI2:Eu2+. In particular, we have found that extended pumping on the molten crystal-growth charge under vacuum for time periods extending up to 48 hours is generally beneficial in compensating for variations in the alkaline-earth halide purity and stoichiometry of the materials as initially supplied by commercial sources. These melt-pumping and processing techniques are now being applied to the purification of CaI2:Eu2+ and some mixed-anion europium-doped alkaline-earth halides prior to single-crystal growth by means of the vertical Bridgman technique. The results of initial studies of the effects of aliovalent doping of SrI2:Eu2+ on the scintillation characteristics of this material are also described.

  13. Calcium manganate: A promising candidate as buffer layer for hybrid halide perovskite photovoltaic-thermoelectric systems

    SciTech Connect (OSTI)

    Zhao, Pengjun; Wang, Hongguang; Kong, Wenwen; Xu, Jinbao Wang, Lei; Ren, Wei; Bian, Liang; Chang, Aimin

    2014-11-21

    We have systematically studied the feasibility of CaMnO{sub 3} thin film, an n-type perovskite, to be utilized as the buffer layer for hybrid halide perovskite photovoltaic-thermoelectric device. Locations of the conduction band and the valence band, spontaneous polarization performance, and optical properties were investigated. Results indicate the energy band of CaMnO{sub 3} can match up well with that of CH{sub 3}NH{sub 3}PbI{sub 3} on separating electron-hole pairs. In addition, the consistent polarization angle helps enlarge the open circuit voltage of the composite system. Besides, CaMnO{sub 3} film shows large absorption coefficient and low extinction coefficient under visible irradiation, demonstrating high carrier concentration, which is beneficial to the current density. More importantly, benign thermoelectric properties enable CaMnO{sub 3} film to assimilate phonon vibration from CH{sub 3}NH3PbI{sub 3}. All the above features lead to a bright future of CaMnO{sub 3} film, which can be a promising candidate as a buffer layer for hybrid halide perovskite photovoltaic-thermoelectric systems.

  14. Ambient-temperature superconductor symetrical metal-dihalide bis-(ethylenedithio)-tetrathiafulvalene compounds

    DOE Patents [OSTI]

    Williams, Jack M. (Downers Grove, IL); Wang, Hsien-Hau (Willowbrook, IL); Beno, Mark A. (Woodridge, IL)

    1987-01-01

    A new class of organic superconductors having the formula (ET).sub.2 MX.sub.2 wherein ET represents bis(ethylenedithio)-tetrathiafulvalene, M is a metal such as Au, Ag, In, Tl, Rb, Pd and the like and X is a halide. The superconductor (ET).sub.2 AuI.sub.2 exhibits a transition temperature of 5 K. which is high for organic superconductors.

  15. Nickel-catalyzed cross-couplings of unactivated secondary and tertiary alkyl halides and photoinduced copper-mediated asymmetric C-N cross-couplings

    E-Print Network [OSTI]

    Zultanski, Susan L. (Susan Lyn)

    2013-01-01

    Chapter 1 describes the development of two nickel-catalyzed Suzuki cross-coupling methodologies that employ alkyl halides as electrophiles. In Section 1.1, asymmetric [gamma]-alkylation relative to a carbonyl group is ...

  16. Light-Light Scattering

    E-Print Network [OSTI]

    Naohiro Kanda

    2011-06-03

    For a long time, it is believed that the light by light scattering is described properly by the Lagrangian density obtained by Heisenberg and Euler. Here, we present a new calculation which is based on the modern field theory technique. It is found that the light-light scattering is completely different from the old expression. The reason is basically due to the unphysical condition (gauge condition) which was employed by the QED calcualtion of Karplus and Neumann. The correct cross section of light-light scattering at low energy of $(\\frac{\\omega}{m} \\ll 1)$ can be written as $ \\displaystyle{\\frac{d\\sigma}{d\\Omega}=\\frac{1}{(6\\pi)^2}\\frac{\\alpha^4} {(2\\omega)^2}(3+2\\cos^2\\theta +\\cos^4\\theta)}$.

  17. Highly efficient light management for perovskite solar cells

    E-Print Network [OSTI]

    Wang, Dong-Lin; Hou, Guo-Jiao; Zhu, Zhen-Gang; Yan, Qing-Bo; Su, Gang

    2015-01-01

    Organic-inorganic halide perovskite solar cells have enormous potential to impact the existing photovoltaic industry. As realizing a higher conversion efficiency of the solar cell is still the most crucial task, a great number of schemes were proposed to minimize the carrier loss by optimizing the electrical properties of the perovskite solar cells. Here, we focus on another significant aspect that is to minimize the light loss by optimizing the light management to gain a high efficiency for perovskite solar cells. In our scheme, the slotted and inverted prism structured SiO2 layers are adopted to trap more light into the solar cells, and a better transparent conducting oxide layer is employed to reduce the parasitic absorption. For such an implementation, the efficiency and the serviceable angle of the perovskite solar cell can be promoted impressively. This proposal would shed new light on developing the high-performance perovskite solar cells.

  18. Calcium looping process for high purity hydrogen production integrated with capture of carbon dioxide, sulfur and halides

    DOE Patents [OSTI]

    Ramkumar, Shwetha; Fan, Liang-Shih

    2013-07-30

    A process for producing hydrogen comprising the steps of: (i) gasifying a fuel into a raw synthesis gas comprising CO, hydrogen, steam, sulfur and halide contaminants in the form of H.sub.2S, COS, and HX, wherein X is a halide; (ii) passing the raw synthesis gas through a water gas shift reactor (WGSR) into which CaO and steam are injected, the CaO reacting with the shifted gas to remove CO.sub.2, sulfur and halides in a solid-phase calcium-containing product comprising CaCO.sub.3, CaS and CaX.sub.2; (iii) separating the solid-phase calcium-containing product from an enriched gaseous hydrogen product; and (iv) regenerating the CaO by calcining the solid-phase calcium-containing product at a condition selected from the group consisting of: in the presence of steam, in the presence of CO.sub.2, in the presence of synthesis gas, in the presence of H.sub.2 and O.sub.2, under partial vacuum, and combinations thereof.

  19. Nanostructured Lanthanum Halides and CeBr3 for Nuclear Radiation and Detection

    SciTech Connect (OSTI)

    Paul Guss, Sanjoy Mukhopadhyay, Ron Guise, Ding Yuan

    2010-06-09

    Scintillator materials are used to detect, and in some cases identify, gamma rays. Higher performance scintillators are expensive, hard to manufacture, fragile, and sometimes require liquid nitrogen or cooling engines. But whereas lower-quality scintillators are cheap, easy to manufacture, and more rugged, their performance is lower. At issue: can the desirable qualities of high-and low-performance scintillators be combined to achieve better performance at lower cost? Preliminary experiments show that a LaF{sub 3}:Ce oleic acid-based nanocomposite exhibits a photopeak when exposed to {sup 137}Cs source gamma-radiation. The chemical synthesis of the cerium-doped lanthanum halide nanoparticles are scalable and large quantities of material can be produced at a time, unlike typical crystal growth processes such as the Bridgeman process. Using a polymer composite (Figure 1), produced by LANL, initial measurements of the unloaded and 8% LaF{sub 3}:Ce-loaded sample have been made using {sup 137}Cs sources. Figure 2 shows an energy spectrum acquired for CeF{sub 3}. The lighter plot is the measured polymer-only spectrum and the black plot is the spectrum from the nanocomposite scintillator. As the development of this material continues, the energy resolution is expected to improve and the photopeak-to-Compton ratio will become greater at higher loadings. These measurements show the expected Compton edge in the polymer-only sample, and the Compton edge and photo-peak expected in the nanophosphor composites that LANL has produced. Using a porous VYCORR with CdSe/ZnS core shell quantum dots, Letant has demonstrated that he has obtained signatures of the 241Am photopeak with energy resolution as good at NaI (Figure 3). We begin with the fact that CeBr{sub 3} crystals do not have a self-activity component as strong as the lanthanum halides. The radioactive 0.090% {sup 138}La component of lanthanum leads to significant self-activity, which will be a problem for very large detector volumes. Yet a significant strength of the nanostructure detector concept is the ability to create extremely large detector volumes by mixing nanoparticles into a transparent matrix. This would argue for use of nanoparticles other than lanthanum halides. Nanocomposites are easy to prepare; it is much less costly to use nanocomposites than to grow large whole crystals of these materials. The material can be fabricated at an industrial scale, further reducing cost. This material potentially offers the performance of $300/cc material (e.g., lanthanum bromide) at a cost of $1/cc. Because the material acts as a plastic, it is rugged and flexible, and can be made in large sheets, increasing the sensitivity of a detector using it. It would operate at ambient temperatures. Very large volumes of detector may be produced at greatly reduced cost, enhancing the non-proliferation posture of the nation for the same dollar value.

  20. Transition Metal Switchable Mirror

    ScienceCinema (OSTI)

    None

    2010-01-08

    The switchable-mirrors technology was developed by Tom Richardson and Jonathan Slack of Berkeley Lab's Environmental Energy Technologies Division. By using transition metals rather than the rare earth metals used in the first metal-hydride switchable mirrors, Richardson and Slack were able to lower the cost and simplify the manufacturing process. Energy performance is improved as well, because the new windows can reflect or transmit both visible and infrared light. Besides windows for offices and homes, possible applications include automobile sunroofs, signs and displays, aircraft windows, and spacecraft.

  1. Transition Metal Switchable Mirror

    ScienceCinema (OSTI)

    None

    2013-05-29

    The switchable-mirrors technology was developed by Tom Richardson and Jonathan Slack of Berkeley Lab's Environmental Energy Technologies Division. By using transition metals rather than the rare earth metals used in the first metal-hydride switchable mirrors, Richardson and Slack were able to lower the cost and simplify the manufacturing process. Energy performance is improved as well, because the new windows can reflect or transmit both visible and infrared light. Besides windows for offices and homes, possible applications include automobile sunroofs, signs and displays, aircraft windows, and spacecraft. More information at: http://windows.lbl.gov/materials/chromogenics/default.htm

  2. Transition Metal Switchable Mirror

    SciTech Connect (OSTI)

    2009-08-21

    The switchable-mirrors technology was developed by Tom Richardson and Jonathan Slack of Berkeley Lab's Environmental Energy Technologies Division. By using transition metals rather than the rare earth metals used in the first metal-hydride switchable mirrors, Richardson and Slack were able to lower the cost and simplify the manufacturing process. Energy performance is improved as well, because the new windows can reflect or transmit both visible and infrared light. Besides windows for offices and homes, possible applications include automobile sunroofs, signs and displays, aircraft windows, and spacecraft.

  3. Transition Metal Switchable Mirror

    SciTech Connect (OSTI)

    None

    2009-01-01

    The switchable-mirrors technology was developed by Tom Richardson and Jonathan Slack of Berkeley Lab's Environmental Energy Technologies Division. By using transition metals rather than the rare earth metals used in the first metal-hydride switchable mirrors, Richardson and Slack were able to lower the cost and simplify the manufacturing process. Energy performance is improved as well, because the new windows can reflect or transmit both visible and infrared light. Besides windows for offices and homes, possible applications include automobile sunroofs, signs and displays, aircraft windows, and spacecraft. More information at: http://windows.lbl.gov/materials/chromogenics/default.htm

  4. Wetting of Sodium on ??-Al2O3/YSZ Composites for Low Temperature Planar Sodium-Metal Halide Batteries

    SciTech Connect (OSTI)

    Reed, David M.; Coffey, Greg W.; Mast, Eric S.; Canfield, Nathan L.; Mansurov, Jirgal; Lu, Xiaochuan; Sprenkle, Vincent L.

    2013-04-01

    Wetting of Na on B”-Al2O3/YSZ composites was investigated using the sessile drop technique. The effects of moisture and surface preparation were studied at low temperatures. Electrical conductivity of Na/B”-Al2O3-YSZ/Na cells was also investigated at low temperatures and correlated to the wetting behavior. The use of planar B”-Al2O3 substrates at low temperature with low cost polymeric seals is realized due to improved wetting at low temperature and conductivity values consistent with the literature.

  5. Further reduction of efficiency droop effect by adding a lower-index dielectric interlayer in a surface plasmon coupled blue light-emitting diode with surface metal nanoparticles

    SciTech Connect (OSTI)

    Lin, Chun-Han; Su, Chia-Ying; Chen, Chung-Hui; Yao, Yu-Feng; Shih, Pei-Ying; Chen, Horng-Shyang; Hsieh, Chieh; Kiang, Yean-Woei Yang, C. C.; Kuo, Yang

    2014-09-08

    Further reduction of the efficiency droop effect and further enhancements of internal quantum efficiency (IQE) and output intensity of a surface plasmon coupled, blue-emitting light-emitting diode (LED) by inserting a dielectric interlayer (DI) of a lower refractive index between p-GaN and surface Ag nanoparticles are demonstrated. The insertion of a DI leads to a blue shift of the localized surface plasmon (LSP) resonance spectrum and increases the LSP coupling strength at the quantum well emitting wavelength in the blue range. With SiO{sub 2} as the DI, a thinner DI leads to a stronger LSP coupling effect, when compared with the case of a thicker DI. By using GaZnO, which is a dielectric in the optical range and a good conductor under direct-current operation, as the DI, the LSP coupling results in the highest IQE, highest LED output intensity, and weakest droop effect.

  6. Radiation-induced defects in GaN bulk grown by halide vapor phase epitaxy

    SciTech Connect (OSTI)

    Duc, Tran Thien; Pozina, Galia; Son, Nguyen Tien; Janzén, Erik; Hemmingsson, Carl; Ohshima, Takeshi

    2014-09-08

    Defects induced by electron irradiation in thick free-standing GaN layers grown by halide vapor phase epitaxy were studied by deep level transient spectroscopy. In as-grown materials, six electron traps, labeled D2 (E{sub C}–0.24?eV), D3 (E{sub C}–0.60?eV), D4 (E{sub C}–0.69?eV), D5 (E{sub C}–0.96?eV), D7 (E{sub C}–1.19?eV), and D8, were observed. After 2?MeV electron irradiation at a fluence of 1?×?10{sup 14?}cm{sup ?2}, three deep electron traps, labeled D1 (E{sub C}–0.12?eV), D5I (E{sub C}–0.89?eV), and D6 (E{sub C}–1.14?eV), were detected. The trap D1 has previously been reported and considered as being related to the nitrogen vacancy. From the annealing behavior and a high introduction rate, the D5I and D6 centers are suggested to be related to primary intrinsic defects.

  7. Directed light fabrication

    SciTech Connect (OSTI)

    Lewis, G.K.; Nemec, R.; Milewski, J.; Thoma, D.J.; Cremers, D.; Barbe, M.

    1994-09-01

    Directed Light Fabrication (DLF) is a rapid prototyping process being developed at Los Alamos National Laboratory to fabricate metal components. This is done by fusing gas delivered metal powder particles in the focal zone of a laser beam that is, programmed to move along or across the part cross section. Fully dense metal is built up a layer at a time to form the desired part represented by a 3 dimensional solid model from CAD software. Machine ``tool paths`` are created from the solid model that command the movement and processing parameters specific to the DLF process so that the part can be built one layer at a time. The result is a fully dense, near net shape metal part that solidifies under rapid solidification conditions.

  8. Adsorption and Separation of Light Gases on an Amino-Functionalized Metal–Organic Framework: An Adsorption and In Situ XRD Study

    SciTech Connect (OSTI)

    Couck S.; Stavitski E.; Gobehiya, E.; Kirschhock, C.E.A.; Serra-Crespo, P.; Juan-Alcaniz, J.; Martinez Joaristi, A.; Gascon, J.; Kapteijn, F.; Baron, G. V.; Denayer J.F.M.

    2012-02-29

    The NH{sub 2}-MIL-53(Al) metal-organic framework was studied for its use in the separation of CO{sub 2} from CH{sub 4}, H{sub 2}, N{sub 2} C{sub 2}H{sub 6} and C{sub 3}H{sub 8} mixtures. Isotherms of methane, ethane, propane, hydrogen, nitrogen, and CO{sub 2} were measured. The atypical shape of these isotherms is attributed to the breathing properties of the material, in which a transition from a very narrow pore form to a narrow pore form and from a narrow pore form to a large pore form occurs, depending on the total pressure and the nature of the adsorbate, as demonstrated by in-situ XRD patterns measured during adsorption. Apart from CO{sub 2}, all tested gases interacted weakly with the adsorbent. As a result, they are excluded from adsorption in the narrow pore form of the material at low pressure. CO{sub 2} interacted much more strongly and was adsorbed in significant amounts at low pressure. This gives the material excellent properties to separate CO{sub 2} from other gases. The separation of CO{sub 2} from methane, nitrogen, hydrogen, or a combination of these gases has been demonstrated by breakthrough experiments using pellets of NH{sub 2}-MIL-53(Al). The effect of total pressure (1-30 bar), gas composition, temperature (303-403 K) and contact time has been examined. In all cases, CO{sub 2} was selectively adsorbed, whereas methane, nitrogen, and hydrogen nearly did not adsorb at all. Regeneration of the adsorbent by thermal treatment, inert purge gas stripping, and pressure swing has been demonstrated. The NH{sub 2}-MIL-53(Al) pellets retained their selectivity and capacity for more than two years.

  9. Metal aminoboranes

    DOE Patents [OSTI]

    Burrell, Anthony K.; Davis, Benjamin J.; Thorn, David L.; Gordon, John C.; Baker, R. Thomas; Semelsberger, Troy Allen; Tumas, William; Diyabalanage, Himashinie Vichalya Kaviraj; Shrestha, Roshan P.

    2010-05-11

    Metal aminoboranes of the formula M(NH.sub.2BH.sub.3).sub.n have been synthesized. Metal aminoboranes are hydrogen storage materials. Metal aminoboranes are also precursors for synthesizing other metal aminoboranes. Metal aminoboranes can be dehydrogenated to form hydrogen and a reaction product. The reaction product can react with hydrogen to form a hydrogen storage material. Metal aminoboranes can be included in a kit.

  10. Smart Lighting Controller!! Smart lighting!

    E-Print Network [OSTI]

    Anderson, Betty Lise

    'll build the circuit! We'll use an LED to represent the room lights! #12;4! Block diagram! Battery! Rail! #12;23! LED: light-emitting diode! Diode conducts current in only one direction! When current flows1! Smart Lighting Controller!! #12;2! Smart lighting! No need to spend energy lighting the room if

  11. Europium-activated phosphors containing oxides of rare-earth and group-IIIB metals and method of making the same

    DOE Patents [OSTI]

    Comanzo, Holly Ann; Setlur, Anant Achyut; Srivastava, Alok Mani

    2006-04-04

    Europium-activated phosphors comprise oxides of at least a rare-earth metal selected from the group consisting of gadolinium, yttrium, lanthanum, and combinations thereof and at least a Group-IIIB metal selected from the group consisting of aluminum, gallium, indium, and combinations thereof. A method for making such phosphors comprises adding at least a halide of at least one of the selected Group-IIIB metals in a starting mixture. The method further comprises firing the starting mixture in an oxygen-containing atmosphere. The phosphors produced by such a method exhibit improved absorption in the UV wavelength range and improved quantum efficiency.

  12. Europium-activated phosphors containing oxides of rare-earth and group-IIIB metals and method of making the same

    DOE Patents [OSTI]

    Comanzo, Holly Ann; Setlur, Anant Achyut; Srivastava, Alok Mani; Manivannan, Venkatesan

    2004-07-13

    Europium-activated phosphors comprise oxides of at least a rare-earth metal selected from the group consisting of gadolinium, yttrium, lanthanum, and combinations thereof and at least a Group-IIIB metal selected from the group consisting of aluminum, gallium, indium, and combinations thereof. A method for making such phosphors comprises adding at least a halide of at least one of the selected Group-IIIB metals in a starting mixture. The method further comprises firing the starting mixture in an oxygen-containing atmosphere. The phosphors produced by such a method exhibit improved absorption in the UV wavelength range and improved quantum efficiency.

  13. Method of removal of heavy metal from molten salt in IFR fuel pyroprocessing

    DOE Patents [OSTI]

    Gay, E.C.

    1995-10-03

    An electrochemical method is described for separating heavy metal values from a radioactive molten salt including Li halide at temperatures of about 500 C. The method comprises positioning a solid Li--Cd alloy anode in the molten salt containing the heavy metal values, positioning a Cd-containing cathode or a solid cathode positioned above a catch crucible in the molten salt to recover the heavy metal values, establishing a voltage drop between the anode and the cathode to deposit material at the cathode to reduce the concentration of heavy metals in the salt, and controlling the deposition rate at the cathode by controlling the current between the anode and cathode. 3 figs.

  14. Chemistry of gaseous lower halides of uranium. Technical progress report, 1 September 1979-1 April 1980

    SciTech Connect (OSTI)

    Hildenbrand, D.L.

    1980-04-15

    The gaseous uranium species UF, UF/sub 2/, UF/sub 3/, and UF/sub 4/ were generated in effusion cell beams by vaporization of UF/sub 4/(s) under reducing conditions, and they were identified and studied by mass spectrometry. From extensive second-law studies of reaction equilibria involving these species and several reaction partners used as reference standards, the individual bond dissociation energies and standard enthalpies of formation of the U-F species were derived. Reaction entropies derived from the slope data indicate that the electronic entropies of the U-F species are substantial, and are comparable to or larger than that of atomic uranium. Additional thermochemical measurements were made to establish the properties of several Ag and Cu monohalides that have been or will be used as reference standards in the uranium halide measurements. From studies of the sublimation and decomposition of uranyl fluoride, UO/sub 2/F/sub 2/(s), the enthalpy of sublimation of UO/sub 2/F/sub 2/(g), has been determined, and another gaseous oxyfluoride, UOF/sub 4/(g), has been tentatively identified. The gaseous products of decomposition of UO/sub 2/F/sub 2/(s) observed by mass spectrometry differ from those postulated by other investigators, indicating that the mechanism of decomposition has not been clearly established. A search of the thermochemical literature on uranium halides has been completed.

  15. Light trapping limits in plasmonic solar cells: an analytical investigation

    E-Print Network [OSTI]

    Sheng, Xing

    We analytically investigate the light trapping performance in plasmonic solar cells with Si/metallic structures. We consider absorption enhancements for surface plasmon polaritons (SPPs) at planar Si/metal interfaces and ...

  16. A low cost high flux solar simulator

    E-Print Network [OSTI]

    Codd, Daniel S.

    A low cost, high flux, large area solar simulator has been designed, built and characterized for the purpose of studying optical melting and light absorption behavior of molten salts. Seven 1500 W metal halide outdoor ...

  17. Degradation in PV Encapsulation Transmittance: An Interlaboratory...

    Office of Scientific and Technical Information (OSTI)

    chambers (including Xenon, UVA-340, and metal-halide light sources) or field aging. The solar-weighted transmittance, yellowness index, and the UV cut-off wavelength, determined...

  18. EECBG Success Story: New Sustainability Manager Delivers Savings...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    30, 2010 - 2:04pm Addthis Metal halide light fixtures at Pompey Park are saving the City of Delray Beach money on its electricity bills. | Photo courtesy of the City of Delray...

  19. Metal inks

    DOE Patents [OSTI]

    Ginley, David S; Curtis, Calvin J; Miedaner, Alex; van Hest, Marinus Franciscus Antonius Maria; Kaydanova, Tatiana

    2014-02-04

    Self-reducing metal inks and systems and methods for producing and using the same are disclosed. In an exemplary embodiment, a method may comprise selecting metal-organic (MO) precursor, selecting a reducing agent, and dissolving the MO precursor and the reducing agent in an organic solvent to produce a metal ink that remains in a liquid phase at room temperature. Metal inks, including self-reducing and fire-through metal inks, are also disclosed, as are various applications of the metal inks.

  20. Halide, Chromate, and Phosphate Impacts on LAW Glass for Dynamic Flowsheet 24590-WTP-MCR-PET-09-0037, Rev. 1

    SciTech Connect (OSTI)

    Gimpel, Rodney F.; Kruger, Albert A.

    2013-12-16

    Revision 1 of this Model Change Request changed Equation 6 in Attachment Al only. Melter studies have shown that halide, chromium, and phosphates can cause precipitation of solids that can interfer the melting process. Pilot melter data now shows what concentrations LAW glass can tolerate. These limits shall be incorporated into the existing LAW glass algorithm per Attachment Al.

  1. 1302 J. Phys. Chem. 1981, 85,1302-1305 PhotochemicalIsotope Separation of Hg-196 by Reaction with Hydrogen Halides

    E-Print Network [OSTI]

    chloride as substrate with added butadiene. The enrichment is definedhere asthe finalisotopicabundanceover amounts of the hydrogen halide (HC1,HBr, or HI) gas to be mixed with a fractional amount of l,&butadiene are of the highest purity commercially available (>99.9% for HC1). Before entry into the reaction cell, the butadiene

  2. Porous light-emitting compositions

    DOE Patents [OSTI]

    Burrell, Anthony K. (Los Alamos, NM); McCleskey, Thomas Mark (Los Alamos, NM); Jia, Quanxi (Los Alamos, NM); Bauer, Eve (Los Alamos, NM); Mueller, Alexander H. (Los Alamos, NM)

    2012-04-17

    Light-emitting devices are prepared by coating a porous substrate using a polymer-assisted deposition process. Solutions of metal precursor and soluble polymers having binding properties for metal precursor were coated onto porous substrates. The coated substrates were heated at high temperatures under a suitable atmosphere. The result was a substrate with a conformal coating that did not substantially block the pores of the substrate.

  3. Tuning of the Metal-Insulator Transition via Alkali Adsorption

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tuning of the Metal-Insulator Transition via Alkali Adsorption Print Turning a material from an insulator to a metal, or vice versa, by light irradiation, exposure to electric or...

  4. Silicone metalization

    DOE Patents [OSTI]

    Maghribi, Mariam N. (Livermore, CA); Krulevitch, Peter (Pleasanton, CA); Hamilton, Julie (Tracy, CA)

    2008-12-09

    A system for providing metal features on silicone comprising providing a silicone layer on a matrix and providing a metal layer on the silicone layer. An electronic apparatus can be produced by the system. The electronic apparatus comprises a silicone body and metal features on the silicone body that provide an electronic device.

  5. Light Properties Light travels at the speed of light `c'

    E-Print Network [OSTI]

    Mojzsis, Stephen J.

    LIGHT!! #12;Light Properties Light travels at the speed of light `c' C = 3 x 108 m/s Or 190,000 miles/second!! Light could travel around the world about 8 times in one second #12;What is light?? Light is a "wave packet" A photon is a "light particle" #12;Electromagnetic Radiation and You Light is sometimes

  6. Photovoltaic device having light transmitting electrically conductive stacked films

    DOE Patents [OSTI]

    Weber, Michael F. (St. Paul, MN); Tran, Nang T. (St. Paul, MN); Jeffrey, Frank R. (St. Paul, MN); Gilbert, James R. (St. Paul, MN); Aspen, Frank E. (St. Paul, MN)

    1990-07-10

    A light transmitting electrically conductive stacked film, useful as a light transmitting electrode, including a first light transmitting electrically conductive layer, having a first optical thickness, a second light transmitting layer, having a second optical thickness different from the optical thickness of the first layer, and an electrically conductive metallic layer interposed between and in initimate contact with the first and second layers.

  7. Demonstration Assessment of LED Roadway Lighting: NE Cully Boulevard Portland, OR

    SciTech Connect (OSTI)

    Royer, Michael P.; Poplawski, Michael E.; Tuenge, Jason R.

    2012-06-29

    A new roadway lighting demonstration project was initiated in late 2010, which was planned in conjunction with other upgrades to NE Cully Boulevard, a residential collector road in the northeast area of Portland, OR. With the NE Cully Boulevard project, the Portland Bureau of Transportation hoped to demonstrate different light source technologies and different luminaires side-by-side. This report documents the initial performance of six different newly installed luminaires, including three LED products, one induction product, one ceramic metal halide product, and one high-pressure sodium (HPS) product that represented the baseline solution. It includes reported, calculated, and measured performance; evaluates the economic feasibility of each of the alternative luminaires; and documents user feedback collected from a group of local Illuminating Engineering Society (IES) members that toured the site. This report does not contain any long-term performance evaluations or laboratory measurements of luminaire performance. Although not all of the installed products performed equally, the alternative luminaires generally offered higher efficacy, more appropriate luminous intensity distributions, and favorable color quality when compared to the baseline HPS luminaire. However, some products did not provide sufficient illumination to all areas—vehicular drive lanes, bicycle lanes, and sidewalks—or would likely fail to meet design criteria over the life of the installation due to expected depreciation in lumen output. While the overall performance of the alternative luminaires was generally better than the baseline HPS luminaire, cost remains a significant barrier to widespread adoption. Based on the cost of the small quantity of luminaires purchased for this demonstration, the shortest calculated payback period for one of the alternative luminaire types was 17.3 years. The luminaire prices were notably higher than typical prices for currently available luminaires purchased in larger quantities. At prices that are more typical, the payback would be less than 10 years. In addition to the demonstration luminaires, a networked control system was installed for additional evaluation and demonstration purposes. The capability of control system to measure luminaire input power was explored in this study. A more exhaustive demonstration and evaluation of the control system will be the subject of future GATEWAY report(s).

  8. Optical amplifier operating at 1.3 microns useful for telecommunications and based on dysprosium-doped metal chloride host materials

    DOE Patents [OSTI]

    Page, R.H.; Schaffers, K.I.; Payne, S.A.; Krupke, W.F.; Beach, R.J.

    1997-12-02

    Dysprosium-doped metal chloride materials offer laser properties advantageous for use as optical amplifiers in the 1.3 {micro}m telecommunications fiber optic network. The upper laser level is characterized by a millisecond lifetime, the host material possesses a moderately low refractive index, and the gain peak occurs near 1.31 {micro}m. Related halide materials, including bromides and iodides, are also useful. The Dy{sup 3+}-doped metal chlorides can be pumped with laser diodes and yield 1.3 {micro}m signal gain levels significantly beyond those currently available. 9 figs.

  9. Optical amplifier operating at 1.3 microns useful for telecommunications and based on dysprosium-doped metal chloride host materials

    DOE Patents [OSTI]

    Page, Ralph H. (San Ramon, CA); Schaffers, Kathleen I. (Pleasanton, CA); Payne, Stephen A. (Castro Valley, CA); Krupke, William F. (Pleasanton, CA); Beach, Raymond J. (Livermore, CA)

    1997-01-01

    Dysprosium-doped metal chloride materials offer laser properties advantageous for use as optical amplifiers in the 1.3 .mu.m telecommunications fiber optic network. The upper laser level is characterized by a millisecond lifetime, the host material possesses a moderately low refractive index, and the gain peak occurs near 1.31 .mu.m. Related halide materials, including bromides and iodides, are also useful. The Dy.sup.3+ -doped metal chlorides can be pumped with laser diodes and yield 1.3 .mu.m signal gain levels significantly beyond those currently available.

  10. Density functional theory study on the interstitial chemical shifts of main-group-element centered hexazirconium halide clusters; synthetic control of speciation in [(Zr6ZCl12)] (Z = B, C)-based mixed ligand complexes 

    E-Print Network [OSTI]

    Shen, Jingyi

    2005-08-29

    The correlation between NMR chemical shifts of interstitial atoms and electronic structures of boron- and carbon-centered hexazirconium halide clusters was investigated by density functional theory (DFT) calculation. The ...

  11. Cerenkov Light

    ScienceCinema (OSTI)

    Slifer, Karl

    2014-05-22

    The bright blue glow from nuclear reactors is Cerenkov light. Karl Slifer describes how nuclear physicists can use this phenomenon to study the nucleus of the atom.

  12. Cerenkov Light

    SciTech Connect (OSTI)

    Slifer, Karl

    2013-06-13

    The bright blue glow from nuclear reactors is Cerenkov light. Karl Slifer describes how nuclear physicists can use this phenomenon to study the nucleus of the atom.

  13. Lighting Renovations

    Broader source: Energy.gov [DOE]

    When undertaking a lighting renovation in a Federal building, daylighting is the primary renewable energy opportunity. Photovoltaics (PV) also present an excellent opportunity. While this guide...

  14. Contour forming of metals by laser peening

    DOE Patents [OSTI]

    Hackel, Lloyd (Livermore, CA); Harris, Fritz (Rocklin, CA)

    2002-01-01

    A method and apparatus are provided for forming shapes and contours in metal sections by generating laser induced compressive stress on the surface of the metal workpiece. The laser process can generate deep compressive stresses to shape even thick components without inducing unwanted tensile stress at the metal surface. The precision of the laser-induced stress enables exact prediction and subsequent contouring of parts. A light beam of 10 to 100 J/pulse is imaged to create an energy fluence of 60 to 200 J/cm.sup.2 on an absorptive layer applied over a metal surface. A tamping layer of water is flowed over the absorptive layer. The absorption of laser light causes a plasma to form and consequently creates a shock wave that induces a deep residual compressive stress into the metal. The metal responds to this residual stress by bending.

  15. Metal oxide composite dosimeter method and material

    DOE Patents [OSTI]

    Miller, Steven D. (Richland, WA)

    1998-01-01

    The present invention is a method of measuring a radiation dose wherein a radiation responsive material consisting essentially of metal oxide is first exposed to ionizing radiation. The metal oxide is then stimulating with light thereby causing the radiation responsive material to photoluminesce. Photons emitted from the metal oxide as a result of photoluminescence may be counted to provide a measure of the ionizing radiation.

  16. Process for forming epitaxial perovskite thin film layers using halide precursors

    DOE Patents [OSTI]

    Clem, Paul G. (Albuquerque, NM); Rodriguez, Mark A. (Albuquerque, NM); Voigt, James A. (Corrales, NM); Ashley, Carol S. (Albuquerque, NM)

    2001-01-01

    A process for forming an epitaxial perovskite-phase thin film on a substrate. This thin film can act as a buffer layer between a Ni substrate and a YBa.sub.2 Cu.sub.3 O.sub.7-x superconductor layer. The process utilizes alkali or alkaline metal acetates dissolved in halogenated organic acid along with titanium isopropoxide to dip or spin-coat the substrate which is then heated to about 700.degree. C. in an inert gas atmosphere to form the epitaxial film on the substrate. The YBCO superconductor can then be deposited on the layer formed by this invention.

  17. Embedded metal nanopatterns as a general scheme for enhanced

    E-Print Network [OSTI]

    Burns, Michael J.

    Embedded metal nanopatterns as a general scheme for enhanced broadband light absorption Fan Ye Published online 24 October 2014 Keywords broadband enhanced absorption, embedded metal nanopattern of dielectric or metallic nanoparticles or nanopatterns on top of, below, or embedded within a photovoltaic (PV

  18. A method of measuring a molten metal liquid pool volume

    DOE Patents [OSTI]

    Garcia, G.V.; Carlson, N.M., Donaldson, A.D.

    1990-12-12

    A method of measuring a molten metal liquid pool volume and in particular molten titanium liquid pools, including the steps of (a) generating an ultrasonic wave at the surface of the molten metal liquid pool, (b) shining a light on the surface of a molten metal liquid pool, (c) detecting a change in the frequency of light, (d) detecting an ultrasonic wave echo at the surface of the molten metal liquid pool, and (e) computing the volume of the molten metal liquid. 3 figs.

  19. Transmissive metallic contact for amorphous silicon solar cells

    DOE Patents [OSTI]

    Madan, A.

    1984-11-29

    A transmissive metallic contact for amorphous silicon semiconductors includes a thin layer of metal, such as aluminum or other low work function metal, coated on the amorphous silicon with an antireflective layer coated on the metal. A transparent substrate, such as glass, is positioned on the light reflective layer. The metallic layer is preferably thin enough to transmit at least 50% of light incident thereon, yet thick enough to conduct electricity. The antireflection layer is preferably a transparent material that has a refractive index in the range of 1.8 to 2.2 and is approximately 550A to 600A thick.

  20. Lighting in the Library

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by your library lights E Kilowatt-hours consumed by your library lights F Annual cost of operating your library lights H Current lighting index for your library ...

  1. Light's Darkness

    ScienceCinema (OSTI)

    Padgett, Miles [University of Glasgow, Glasgow, Scotland

    2010-01-08

    Optical vortices and orbital angular momentum are currently topical subjects in the optics literature. Although seemingly esoteric, they are, in fact, the generic state of light and arise whenever three or more plane waves interfere. To be observed by eye the light must be monochromatic. Laser speckle is one such example, where the optical energy circulates around each black spot, giving a local orbital angular momentum. This talk with report three on-going studies. First, when considering a volume of interfering waves, the laser specs map out threads of complete darkness embedded in the light. Do these threads form loops? Links? Or even knots? Second, when looking through a rapidly spinning window, the image of the world on the other side is rotated: true or false? Finally, the entanglement of orbital angular momentum states means measuring how the angular position of one photons sets the angular momentum of another: is this an angular version of the EPR (Einstein, Podolsky, and Rosen) paradox?

  2. Light in tiny holes & T. W. Ebbesen1

    E-Print Network [OSTI]

    Turro, Nicholas J.

    REVIEWS Light in tiny holes C. Genet1 & T. W. Ebbesen1 The presence of tiny holes in an opaque metal film, with sizes smaller than the wavelength of incident light, leads to a wide variety of unexpected optical properties such as strongly enhanced transmission of light through the holes

  3. Photonic modes of organic light emitting Submitted by

    E-Print Network [OSTI]

    Exeter, University of

    is a metallic cathode. To achieve high efficiency OLEDs a primary issue to address is how the light resultingPhotonic modes of organic light emitting structures Submitted by Peter Allen Hobson for the award of a degree by this or any other University. #12;Abstract 2 Abstract Organic light emitting diodes

  4. Types of Lights Types of Lights

    E-Print Network [OSTI]

    1 Types of Lights Types of Lights q So far we have studied point lights ­ Radiate in all direc7ons q Other lights ­ Direc7onal lights (posi7on-independent) ­ Spotlights #12;2 Direc1onal Lights q Shine in a single, uniform direc7on q All rays

  5. Light Computing

    E-Print Network [OSTI]

    Gordon Chalmers

    2006-10-13

    A configuration of light pulses is generated, together with emitters and receptors, that allows computing. The computing is extraordinarily high in number of flops per second, exceeding the capability of a quantum computer for a given size and coherence region. The emitters and receptors are based on the quantum diode, which can emit and detect individual photons with high accuracy.

  6. Dry halide method for separating the components of spent nuclear fuels

    DOE Patents [OSTI]

    Christian, J.D.; Thomas, T.R.; Kessinger, G.F.

    1998-06-30

    The invention is a nonaqueous, single method for processing multiple spent nuclear fuel types by separating the fission and transuranic products from the nonradioactive and fissile uranium product. The invention has four major operations: exposing the spent fuels to chlorine gas at temperatures preferably greater than 1200 C to form volatile metal chlorides; removal of the fission product chlorides, transuranic product chlorides, and any nickel chloride and chromium chloride in a molten salt scrubber at approximately 400 C; fractional condensation of the remaining volatile chlorides at temperatures ranging from 164 to 2 C; and regeneration and recovery of the transferred spent molten salt by vacuum distillation. The residual fission products, transuranic products, and nickel- and chromium chlorides are converted to fluorides or oxides for vitrification. The method offers the significant advantages of a single, compact process that is applicable to most of the diverse nuclear fuels, minimizes secondary wastes, segregates fissile uranium from the high level wastes to resolve potential criticality concerns, segregates nonradioactive wastes from the high level wastes for volume reduction, and produces a common waste form glass or glass-ceramic. 3 figs.

  7. Dry halide method for separating the components of spent nuclear fuels

    DOE Patents [OSTI]

    Christian, Jerry Dale (Idaho Falls, ID); Thomas, Thomas Russell (Rigby, ID); Kessinger, Glen F. (Idaho Falls, ID)

    1998-01-01

    The invention is a nonaqueous, single method for processing multiple spent nuclear fuel types by separating the fission- and transuranic products from the nonradioactive and fissile uranium product. The invention has four major operations: exposing the spent fuels to chlorine gas at temperatures preferably greater than 1200.degree. C. to form volatile metal chlorides; removal of the fission product chlorides, transuranic product chlorides, and any nickel chloride and chromium chloride in a molten salt scrubber at approximately 400.degree. C.; fractional condensation of the remaining volatile chlorides at temperatures ranging from 164.degree. C. to 2.degree. C.; and regeneration and recovery of the transferred spent molten salt by vacuum distillation. The residual fission products, transuranic products, and nickel- and chromium chlorides are converted to fluorides or oxides for vitrification. The method offers the significant advantages of a single, compact process that is applicable to most of the diverse nuclear fuels, minimizes secondary wastes, segregates fissile uranium from the high level wastes to resolve potential criticality concerns, segregates nonradioactive wastes from the high level wastes for volume reduction, and produces a common waste form glass or glass-ceramic.

  8. Composite metal membrane

    DOE Patents [OSTI]

    Peachey, Nathaniel M. (Espanola, NM); Dye, Robert C. (Los Alamos, NM); Snow, Ronny C. (Los Alamos, NM); Birdsell, Stephan A. (Los Alamos, NM)

    1998-01-01

    A composite metal membrane including a first metal layer of Group IVB met or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof is provided together with a process for the recovery of hydrogen from a gaseous mixture including contacting a hydrogen-containing gaseous mixture with a first side of a nonporous composite metal membrane including a first metal of Group IVB metals or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof, and, separating hydrogen from a second side of the nonporous composite metal membrane.

  9. Composite metal membrane

    DOE Patents [OSTI]

    Peachey, N.M.; Dye, R.C.; Snow, R.C.; Birdsell, S.A.

    1998-04-14

    A composite metal membrane including a first metal layer of Group IVB met or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof is provided together with a process for the recovery of hydrogen from a gaseous mixture including contacting a hydrogen-containing gaseous mixture with a first side of a nonporous composite metal membrane including a first metal of Group IVB metals or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof, and, separating hydrogen from a second side of the nonporous composite metal membrane.

  10. Light Well: ATunable Free-Electron Light Source on a Chip K. F. MacDonald,1,* Y. H. Fu,2

    E-Print Network [OSTI]

    Zheludev, Nikolay

    Light Well: ATunable Free-Electron Light Source on a Chip G. Adamo,1 K. F. MacDonald,1,* Y. H. Fu,2 metal-dielectric structure creates a new type of tunable, nanoscale radiation source--a ``light well''. In the reported demonstration, tunable light is generated at an intensity of $200 W=cm2 as electrons with energies

  11. Lead (II) selenite halides Pb{sub 3}(SeO{sub 3}){sub 2}X{sub 2} (X = Br, I): Synthesis and crystal structure

    SciTech Connect (OSTI)

    Berdonosov, P. S., E-mail: berdonosov@inorg.chem.msu.ru; Olenev, A. V.; Dolgikh, V. A. [Moscow State University (Russian Federation)

    2012-03-15

    Two lead selenite halides, Pb{sub 3}(SeO{sub 3}){sub 2}Br{sub 2} and Pb{sub 3}(SeO{sub 3}){sub 2}I{sub 2}, have been prepared by solid-phase synthesis and structurally characterized. These compounds are isotypic and can be considered 3D with a microporous framework composed of lead polyhedra (distorted Archimedean antiprisms formed by oxygen and halogen atoms). The framework contains channels oriented in the [010] direction. These channels contain selenium atoms, which are bound with framework oxygen atoms belonging to different lead polyhedra.

  12. Electrical excitation of colloidally synthesized quantum dots in metal oxide structures

    E-Print Network [OSTI]

    Wood, Vanessa Claire

    2010-01-01

    This thesis develops methods for integrating colloidally synthesized quantum dots (QDs) and metal oxides in optoelectronic devices, presents three distinct light emitting devices (LEDs) with metal oxides surrounding a QD ...

  13. Metal Hydrides

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURING OFFICESpecial ReportProposal to changeNovemberEnergyMessage fromMetal

  14. Residential Lighting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMassR&D100Nationalquestionnaires 0 Averagequestionnaires 7tniLighting Sign In

  15. LED Lighting Basics

    Broader source: Energy.gov [DOE]

    Light-Emitting diodes (LEDs) efficiently produce light in a fundamentally different way than any legacy or traditional source of light.

  16. Magnetic Transitions in Iron Porphyrin Halides by Inelastic Neutron Scattering and Ab-initio Studies of Zero-Field Splittings

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stavretis, Shelby E.; Atanasov, Mihail; Podlesnyak, Andrey A.; Hunter, Seth C.; Neese, Frank; Xue, Zi-Ling

    2015-10-02

    Zero-field splitting (ZFS) parameters of nondeuterated metalloporphyrins [Fe(TPP)X] (X = F, Br, I; H2TPP = tetraphenylporphyrin) are determined by inelastic neutron scattering (INS). The ZFS values are D = 4.49(9) cm–1 for tetragonal polycrystalline [Fe(TPP)F], and D = 8.8(2) cm–1, E = 0.1(2) cm–1 and D = 13.4(6) cm–1, E = 0.3(6) cm–1 for monoclinic polycrystalline [Fe(TPP)Br] and [Fe(TPP)I], respectively. Along with our recent report of the ZFS value of D = 6.33(8) cm–1 for tetragonal polycrystalline [Fe(TPP)Cl], these data provide a rare, complete determination of ZFS parameters in a metalloporphyrin halide series. The electronic structure of [Fe(TPP)X] (X =more »F, Cl, Br, I) has been studied by multireference ab initio methods: the complete active space self-consistent field (CASSCF) and the N-electron valence perturbation theory (NEVPT2) with the aim of exploring the origin of the large and positive zero-field splitting D of the 6A1 ground state. D was calculated from wave functions of the electronic multiplets spanned by the d5 configuration of Fe(III) along with spin–orbit coupling accounted for by quasi degenerate perturbation theory. Results reproduce trends of D from inelastic neutron scattering data increasing in the order from F, Cl, Br, to I. A mapping of energy eigenvalues and eigenfunctions of the S = 3/2 excited states on ligand field theory was used to characterize the ?- and ?-antibonding effects decreasing from F to I. This is in agreement with similar results deduced from ab initio calculations on CrX63- complexes and also with the spectrochemical series showing a decrease of the ligand field in the same directions. A correlation is found between the increase of D and decrease of the ?- and ?-antibonding energies e?X (? = ?, ?) in the series from X = F to I. Analysis of this correlation using second-order perturbation theory expressions in terms of angular overlap parameters rationalizes the experimentally deduced trend. Furthermore, D parameters from CASSCF and NEVPT2 results have been calibrated against those from the INS data, yielding a predictive power of these approaches. Methods to improve the quantitative agreement between ab initio calculated and experimental D and spectroscopic transitions for high-spin Fe(III) complexes are proposed.« less

  17. Sandia Energy - (Lighting and) Solid-State Lighting: Science...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (Lighting and) Solid-State Lighting: Science, Technology, Economic Perspectives Home Energy Research EFRCs Solid-State Lighting Science EFRC (Lighting and) Solid-State Lighting:...

  18. Metal filled porous carbon

    DOE Patents [OSTI]

    Gross, Adam F. (Los Angeles, CA); Vajo, John J. (West Hills, CA); Cumberland, Robert W. (Malibu, CA); Liu, Ping (Irvine, CA); Salguero, Tina T. (Encino, CA)

    2011-03-22

    A porous carbon scaffold with a surface and pores, the porous carbon scaffold containing a primary metal and a secondary metal, where the primary metal is a metal that does not wet the surface of the pores of the carbon scaffold but wets the surface of the secondary metal, and the secondary metal is interspersed between the surface of the pores of the carbon scaffold and the primary metal.

  19. Sustainable Office Lighting Options

    E-Print Network [OSTI]

    Massachusetts at Amherst, University of

    Sustainable Office Lighting Options Task Lighting: Task lighting is a localized method of lighting a workspace so that additional, unnecessary lighting is eliminated, decreasing energy usage and costs. Illumination levels in the targeted work areas are higher with task lighting than with the ambient levels

  20. Nanoengineering for solid-state lighting.

    SciTech Connect (OSTI)

    Schubert, E. Fred; Koleske, Daniel David; Wetzel, Christian; Lee, Stephen Roger; Missert, Nancy A.; Lin, Shawn-Yu; Crawford, Mary Hagerott; Fischer, Arthur Joseph

    2009-09-01

    This report summarizes results from a 3-year Laboratory Directed Research and Development project performed in collaboration with researchers at Rensselaer Polytechnic Institute. Our collaborative effort was supported by Sandia's National Institute for Nanoengineering and focused on the study and application of nanoscience and nanoengineering concepts to improve the efficiency of semiconductor light-emitting diodes for solid-state lighting applications. The project explored LED efficiency advances with two primary thrusts: (1) the study of nanoscale InGaN materials properties, particularly nanoscale crystalline defects, and their impact on internal quantum efficiency, and (2) nanoscale engineering of dielectric and metal materials and integration with LED heterostructures for enhanced light extraction efficiency.

  1. Photochemical reductive elimination of halogen from transition metal complexes

    E-Print Network [OSTI]

    Cook, Timothy R. (Timothy Raymond), 1982-

    2010-01-01

    This thesis is focused on the synthesis and study of transition metal complexes that undergo halogen elimination when irradiated with UV and visible light. This chemistry is relevant for solar energy storage schemes in ...

  2. Extracting metals directly from metal oxides

    DOE Patents [OSTI]

    Wai, C.M.; Smart, N.G.; Phelps, C.

    1997-02-25

    A method of extracting metals directly from metal oxides by exposing the oxide to a supercritical fluid solvent containing a chelating agent is described. Preferably, the metal is an actinide or a lanthanide. More preferably, the metal is uranium, thorium or plutonium. The chelating agent forms chelates that are soluble in the supercritical fluid, thereby allowing direct removal of the metal from the metal oxide. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of {beta}-diketones, halogenated {beta}-diketones, phosphinic acids, halogenated phosphinic acids, carboxylic acids, halogenated carboxylic acids, and mixtures thereof. In especially preferred embodiments, at least one of the chelating agents is fluorinated. The method provides an environmentally benign process for removing metals from metal oxides without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the metal recovered, to provide an economic, efficient process. 4 figs.

  3. Extracting metals directly from metal oxides

    DOE Patents [OSTI]

    Wai, Chien M. (Moscow, ID); Smart, Neil G. (Moscow, ID); Phelps, Cindy (Moscow, ID)

    1997-01-01

    A method of extracting metals directly from metal oxides by exposing the oxide to a supercritical fluid solvent containing a chelating agent is described. Preferably, the metal is an actinide or a lanthanide. More preferably, the metal is uranium, thorium or plutonium. The chelating agent forms chelates that are soluble in the supercritical fluid, thereby allowing direct removal of the metal from the metal oxide. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of .beta.-diketones, halogenated .beta.-diketones, phosphinic acids, halogenated phosphinic acids, carboxylic acids, halogenated carboxylic acids, and mixtures thereof. In especially preferred embodiments, at least one of the chelating agents is fluorinated. The method provides an environmentally benign process for removing metals from metal oxides without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the metal recovered, to provide an economic, efficient process.

  4. COORDINATION CHEMISTRY OF METAL SURFACES AND METAL COMPLEXES

    E-Print Network [OSTI]

    Muetterties, E.L.

    2013-01-01

    4, 1980 Catalysis~ COORDINATION CHEMISTRY OF METAL SURFACESAND METAL COMPLEXES Earl L. Muetterties December 1979 TWO-10308 COORDINATION CHEt1ISTRY OF METAL SURFACES AND METAL

  5. Basis and Lattice Polarization Mechanisms for Light Transmission

    E-Print Network [OSTI]

    Brolo, Alexandre G.

    Basis and Lattice Polarization Mechanisms for Light Transmission through Nanohole Arrays in a Metal light transmission through double-hole and elliptical nanohole arrays in a thin gold film plasmon waves and the evanescent transmission through the nanoholes. Both of these effects need

  6. Fabrication of High Efficiency, Printable Organic Light Emitting Diodes

    E-Print Network [OSTI]

    Petta, Jason

    design of OLED: Transparent Anode--ITO Glass substrate Organic layer(s) Metal Cathode Light #12;PRISMFabrication of High Efficiency, Printable Organic Light Emitting Diodes Michael AdamsMichael Adams: Design, fabricate, and characterize high efficiency OLEDs · Introduction · Background on OLEDs · Methods

  7. Method and making group IIB metal - telluride films and solar cells

    DOE Patents [OSTI]

    Basol, Bulent M. (Redondo Beach, CA); Kapur, Vijay K. (Northridge, CA)

    1990-08-21

    A technique is disclosed forming thin films (13) of group IIB metal-telluride, such as Cd.sub.x Zn.sub.1-x Te (0.ltoreq.x.ltoreq.1), on a substrate (10) which comprises depositing Te (18) and at least one of the elements (19) of Cd, Zn, and Hg onto a substrate and then heating the elements to form the telluride. A technique is also provided for doping this material by chemically forming a thin layer of a dopant on the surface of the unreacted elements and then heating the elements along with the layer of dopant. A method is disclosed of fabricating a thin film photovoltaic cell which comprises depositing Te and at least one of the elements of Cd, Zn, and Hg onto a substrate which contains on its surface a semiconductor film (12) and then heating the elements in the presence of a halide of the Group IIB metals, causing the formation of solar cell grade Group IIB metal-telluride film and also causing the formation of a rectifying junction, in situ, between the semiconductor film on the substrate and the Group IIB metal-telluride layer which has been formed.

  8. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Trending: Metal Oxo Bonds Trending: Metal Oxo Bonds Print Wednesday, 29 May 2013 00:00 Metal oxides are important for scientific and technical applications in a variety of...

  9. Lighting Options for Homes.

    SciTech Connect (OSTI)

    Baker, W.S.

    1991-04-01

    This report covers many aspects of various lighting options for homes. Types of light sources described include natural light, artificial light, incandescent lamps, fluorescent lamps, and high intensity discharge lamps. A light source selection guide gives the physical characteristics of these, design considerations, and common applications. Color, strategies for efficient lighting, and types of lighting are discussed. There is one section giving tips for various situations in specific rooms. Rooms and types of fixtures are shown on a matrix with watts saved by using the recommended type lighting for that room and room location. A major emphasis of this report is saving energy by utilizing the most suitable, recommended lighting option. (BN)

  10. Mobile lighting apparatus

    DOE Patents [OSTI]

    Roe, George Michael; Klebanoff, Leonard Elliott; Rea, Gerald W; Drake, Robert A; Johnson, Terry A; Wingert, Steven John; Damberger, Thomas A; Skradski, Thomas J; Radley, Christopher James; Oros, James M; Schuttinger, Paul G; Grupp, David J; Prey, Stephen Carl

    2013-05-14

    A mobile lighting apparatus includes a portable frame such as a moveable trailer or skid having a light tower thereon. The light tower is moveable from a stowed position to a deployed position. A hydrogen-powered fuel cell is located on the portable frame to provide electrical power to an array of the energy efficient lights located on the light tower.

  11. Nanoantennas for enhanced light trapping in transparent organic solar cells

    E-Print Network [OSTI]

    Voroshilov, Pavel M; Belov, Pavel A

    2014-01-01

    We propose a light-trapping structure offering a significant enhancement of photovoltaic absorption in transparent organic solar cells operating at infrared while the visible light transmission keeps sufficiently high. The main mechanism of light trapping is related with the excitation of collective oscillations of the metal nanoantenna arrays, characterized by advantageous field distribution in the volume of the solar cell. It allows more than triple increase of infrared photovoltaic absorption.

  12. Practical image based lighting 

    E-Print Network [OSTI]

    Lee, Jaemin

    2003-01-01

    information is lighting. Image based lighting that is developed to recover illumination information of the real world from photographs has recently been popular in computer graphics. In this thesis we present a practical image based lighting method. Our...

  13. Light in the city

    E-Print Network [OSTI]

    Srinivasan, Kavita, 1976-

    2002-01-01

    This thesis focuses on enhancing the awareness of light for the pedestrian,and using light as a way of revealing the structure of the city and its relation to the cosmos. It proposes that aesthetic qualities of light inform ...

  14. Advances in Lighting 

    E-Print Network [OSTI]

    Tumber, A. J.

    1981-01-01

    Increasing electricity costs have made a significant impact on lighting. The Illuminating Engineering society (I.E.S.) and the lighting industry are producing new standards, procedures and products to make lighting more appropriate and energy...

  15. Natural lighting and skylights 

    E-Print Network [OSTI]

    Evans, Benjamin Hampton

    1961-01-01

    There are many physiological and psychological factors which enter into the proper design of space for human occupancy. One of these elements is light. Both natural light and manufactured light are basic tools with which any designer must work...

  16. Specific light in sculpture

    E-Print Network [OSTI]

    Powell, John William

    1989-01-01

    Specific light is defined as light from artificial or altered natural sources. The use and manipulation of light in three dimensional sculptural work is discussed in an historic and contemporary context. The author's work ...

  17. Advanced Demand Responsive Lighting

    E-Print Network [OSTI]

    Advanced Demand Responsive Lighting Host: Francis Rubinstein Demand Response Research Center demand responsive lighting systems ­ Importance of dimming ­ New wireless controls technologies · Advanced Demand Responsive Lighting (commenced March 2007) #12;Objectives · Provide up-to-date information

  18. Light Duty Combustion Research: Advanced Light-Duty Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Light Duty Combustion Research: Advanced Light-Duty Combustion Experiments Light Duty Combustion Research: Advanced Light-Duty Combustion Experiments 2009 DOE Hydrogen Program and...

  19. Lighting in Commercial Buildings

    U.S. Energy Information Administration (EIA) Indexed Site

    are also under consideration. Outside the DOE, the Environmental Protection Agency's Green Lights program promotes energy-efficient lighting as a means to reducing...

  20. Lighting in Commercial Buildings

    U.S. Energy Information Administration (EIA) Indexed Site

    Motivation and Computation of Lighting Measures Floorspace by Lighting Equipment Configuration As described in Appendix A, for each building b, the CBECS data set has the total...

  1. Lighting in Commercial Buildings

    U.S. Energy Information Administration (EIA) Indexed Site

    more comprehensive understanding of commercial lighting and the potential for lighting energy savings. Steps to build on this analysis can be taken in many directions. One...

  2. Leavenworth Tree Lighting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Join HERO for our annual Leavenworth Tree Lighting Ceremony & Shopping SATURDAY DECEMBER 12, 2015 Leavenworth Christmas Lighting Festival Visitors return year after year for some...

  3. Lighting in Commercial Buildings

    U.S. Energy Information Administration (EIA) Indexed Site

    light by passing electricity through mercury vapor, which causes the fluorescent coating to glow or fluoresce. High-Efficiency Ballast (HEB): A lighting conservation feature...

  4. Exciting White Lighting

    Broader source: Energy.gov [DOE]

    Windows that emit light and are more energy efficient? Universal Display’s PHOLED technology enables windows that have transparent light-emitting diodes in them.

  5. Composite metal foil and ceramic fabric materials

    DOE Patents [OSTI]

    Webb, B.J.; Antoniak, Z.I.; Prater, J.T.; DeSteese, J.G.

    1992-03-24

    The invention comprises new materials useful in a wide variety of terrestrial and space applications. In one aspect, the invention comprises a flexible cloth-like material comprising a layer of flexible woven ceramic fabric bonded with a layer of metallic foil. In another aspect, the invention includes a flexible fluid impermeable barrier comprising a flexible woven ceramic fabric layer having metal wire woven therein. A metallic foil layer is incontinuously welded to the woven metal wire. In yet another aspect, the invention includes a material comprising a layer of flexible woven ceramic fabric bonded with a layer of an organic polymer. In still another aspect, the invention includes a rigid fabric structure comprising a flexible woven ceramic fabric and a resinous support material which has been hardened as the direct result of exposure to ultraviolet light. Inventive methods for producing such material are also disclosed. 11 figs.

  6. Heavy metal biosensor

    DOE Patents [OSTI]

    Hillson, Nathan J; Shapiro, Lucille; Hu, Ping; Andersen, Gary L

    2014-04-15

    Compositions and methods are provided for detection of certain heavy metals using bacterial whole cell biosensors.

  7. Lighting Controls | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Controls Lighting Controls Use lighting controls to automatically turn lights on and off as needed, and save energy. | Photo courtesy of iStockphoto.comMaliketh. Use lighting...

  8. Pedestrian Friendly Outdoor Lighting

    SciTech Connect (OSTI)

    Miller, N. J.; Koltai, R. N.; McGowan, T. K.

    2013-12-01

    The GATEWAY program followed two pedestrian-scale lighting projects that required multiple mockups – one at Stanford University in California and the other at Chautauqua Institution in upstate New York. The report provides insight into pedestrian lighting criteria, how they differ from street and area lighting criteria, and how solid-state lighting can be better applied in pedestrian applications.

  9. Light emitting diode with high aspect ratio submicron roughness for light extraction and methods of forming

    SciTech Connect (OSTI)

    Li, Ting (Ventura, CA)

    2011-04-26

    The surface morphology of an LED light emitting surface is changed by applying a reactive ion etch (RIE) process to the light emitting surface. High aspect ratio, submicron roughness is formed on the light emitting surface by transferring a thin film metal hard-mask having submicron patterns to the surface prior to applying a reactive ion etch process. The submicron patterns in the metal hard-mask can be formed using a low cost, commercially available nano-patterned template which is transferred to the surface with the mask. After subsequently binding the mask to the surface, the template is removed and the RIE process is applied for time duration sufficient to change the morphology of the surface. The modified surface contains non-symmetric, submicron structures having high aspect ratio which increase the efficiency of the device.

  10. Light emitting diode with high aspect ratio submicron roughness for light extraction and methods of forming

    DOE Patents [OSTI]

    Li, Ting

    2013-08-13

    The surface morphology of an LED light emitting surface is changed by applying a reactive ion etch (RIE) process to the light emitting surface. High aspect ratio, submicron roughness is formed on the light emitting surface by transferring a thin film metal hard-mask having submicron patterns to the surface prior to applying a reactive ion etch process. The submicron patterns in the metal hard-mask can be formed using a low cost, commercially available nano-patterned template which is transferred to the surface with the mask. After subsequently binding the mask to the surface, the template is removed and the RIE process is applied for time duration sufficient to change the morphology of the surface. The modified surface contains non-symmetric, submicron structures having high aspect ratio which increase the efficiency of the device.

  11. Gamma ray spectroscopy employing divalent europium-doped alkaline earth halides and digital readout for accurate histogramming

    DOE Patents [OSTI]

    Cherepy, Nerine Jane; Payne, Stephen Anthony; Drury, Owen B; Sturm, Benjamin W

    2014-11-11

    A scintillator radiation detector system according to one embodiment includes a scintillator; and a processing device for processing pulse traces corresponding to light pulses from the scintillator, wherein pulse digitization is used to improve energy resolution of the system. A scintillator radiation detector system according to another embodiment includes a processing device for fitting digitized scintillation waveforms to an algorithm based on identifying rise and decay times and performing a direct integration of fit parameters. A method according to yet another embodiment includes processing pulse traces corresponding to light pulses from a scintillator, wherein pulse digitization is used to improve energy resolution of the system. A method in a further embodiment includes fitting digitized scintillation waveforms to an algorithm based on identifying rise and decay times; and performing a direct integration of fit parameters. Additional systems and methods are also presented.

  12. METAL NANOPARTICLES FUNCTIONALIZED WITH METAL-LIGAND COVALENT BONDS

    E-Print Network [OSTI]

    Kang, Xiongwu

    2012-01-01

    Formation of catalytic metal-molecule contacts. Science,of Organotransition Metal Compounds. Advances inof highly monodisperse metal nanoparticles. Journal of the

  13. Reduced ultraviolet light induced degradation and enhanced light harvesting using YVO{sub 4}:Eu{sup 3+} down-shifting nano-phosphor layer in organometal halide perovskite solar cells

    SciTech Connect (OSTI)

    Chander, Nikhil; Chandrasekhar, P. S.; Thouti, Eshwar; Swami, Sanjay Kumar; Dutta, Viresh; Komarala, Vamsi K.; Khan, A. F.

    2014-07-21

    We report a simple method to mitigate ultra-violet (UV) degradation in TiO{sub 2} based perovskite solar cells (PSC) using a transparent luminescent down-shifting (DS) YVO{sub 4}:Eu{sup 3+} nano-phosphor layer. The PSC coated with DS phosphor showed an improvement in stability under prolonged illumination retaining more than 50% of its initial efficiency, whereas PSC without the phosphor layer degraded to ?35% of its initial value. The phosphor layer also provided ?8.5% enhancement in photocurrent due to DS of incident UV photons into additional red photons. YVO{sub 4}:Eu{sup 3+} layer thus served a bi-functional role in PSC by reducing photo-degradation as well as enhancing energy conversion efficiency.

  14. Diffraction limited focusing and routing of gap plasmons by a metal-dielectric-metal lens

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dennis, Brian S.; Czaplewski, David A.; Haftel, Michael I.; Lopez, Daniel; Blumberg, Girsh; Aksyuk, Vladimir

    2015-08-12

    Passive optical elements can play key roles in photonic applications such as plasmonic integrated circuits. Here we experimentally demonstrate passive gap-plasmon focusing and routing in two-dimensions. This is accomplished using a high numerical-aperture metal-dielectric-metal lens incorporated into a planar-waveguide device. Fabrication via metal sputtering, oxide deposition, electron- and focused-ion- beam lithography, and argon ion-milling is reported on in detail. Diffraction-limited focusing is optically characterized by sampling out-coupled light with a microscope. The measured focal distance and full-width-half-maximum spot size agree well with the calculated lens performance. The surface plasmon polariton propagation length is measured by sampling light from multiple out-couplermore »slits.« less

  15. Metallic Carbon Nanotubes and Ag Nanocrystals

    SciTech Connect (OSTI)

    Brus, Louis E

    2014-03-04

    The goal of this DOE solar energy research was to understand how visible light interacts with matter, and how to make electric excitations evolve into separated electrons and holes in photovoltaic cells, especially in nanoparticles and nanowires. Our specific experiments focused on A) understanding plasmon enhanced spectroscopy and charge-transfer (metal-to-molecule) photochemistry on the surface of metallic particles and B) the spectroscopy and photochemistry of carbon nanotubes and graphene. I also worked closely with R. Friesner on theoretical studies of photo-excited electrons near surfaces of titanium dioxide nanoparticles; this process is relevant to the Gratzel photovoltaic cell.

  16. Reactor vessel using metal oxide ceramic membranes

    DOE Patents [OSTI]

    Anderson, Marc A. (Madison, WI); Zeltner, Walter A. (Oregon, WI)

    1992-08-11

    A reaction vessel for use in photoelectrochemical reactions includes as its reactive surface a metal oxide porous ceramic membrane of a catalytic metal such as titanium. The reaction vessel includes a light source and a counter electrode. A provision for applying an electrical bias between the membrane and the counter electrode permits the Fermi levels of potential reaction to be favored so that certain reactions may be favored in the vessel. The electrical biasing is also useful for the cleaning of the catalytic membrane.

  17. Metal halogen electrochemical cell

    SciTech Connect (OSTI)

    Walsh, F.M.

    1986-06-03

    An electrochemical cell is described having a metal anode selected from the group consisting of zinc and cadmium; a bromine cathode; and, an aqueous electrolyte containing a metal bromide, the metal having the same metal as the metal of the anode, the improvement comprising: a bromine complexing agent in the aqueous metal bromide electrolyte consisting solely of a tetraorgano substituted ammonium salt, which salt is soluble of water and forms and substantially water immiscible liquid bromine complex at temperatures in the range of about 10/sup 0/C. to about 60/sup 0/C. and wherein the tetraorgano substituted ammonium salt is selected from asymmetric quaternary ammonium compounds.

  18. Metal-Air Batteries

    SciTech Connect (OSTI)

    Zhang, Jiguang; Bruce, Peter G.; Zhang, Gregory

    2011-08-01

    Metal-air batteries have much higher specific energies than most currently available primary and rechargeable batteries. Recent advances in electrode materials and electrolytes, as well as new designs on metal-air batteries, have attracted intensive effort in recent years, especially in the development of lithium-air batteries. The general principle in metal-air batteries will be reviewed in this chapter. The materials, preparation methods, and performances of metal-air batteries will be discussed. Two main metal-air batteries, Zn-air and Li-air batteries will be discussed in detail. Other type of metal-air batteries will also be described.

  19. Progress in transition metal-based enantioselective catalysis

    E-Print Network [OSTI]

    Arp, Forrest O

    2008-01-01

    In Chapter 1, the first enantioselective cross-coupling reactions of racemic secondary benzylic halides are described (eq 1). This method was applied to the syntheses of intermediates employed by other groups in the ...

  20. Metal-Ion-Mediated Reactions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Metal-Ion-Mediated Reactions Metal-Ion-Mediated Reactions Print Monday, 19 December 2011 18:29 While mononuclear, polynuclear, and polymeric metal complexes are most often...

  1. Tips: Lighting | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tips: Lighting Tips: Lighting Lighting choices save you money. Energy-efficient light bulbs are available in a wide variety of sizes and shapes. Lighting choices save you money....

  2. Liquid-Metal Electrode to Enable Ultra-Low Temperature Sodium-Beta Alumina Batteries for Renewable Energy Storage

    SciTech Connect (OSTI)

    Lu, Xiaochuan; Li, Guosheng; Kim, Jin Yong; Mei, Donghai; Lemmon, John P.; Sprenkle, Vincent L.; Liu, Jun

    2014-08-01

    Metal electrodes have a high capacity for energy storage but have found limited applications in batteries because of dendrite formation and other problems. In this paper, we report a new alloying strategy that can significantly reduce the melting temperature and improve wetting with the electrolyte to allow the use of liquid metal as anode in sodium-beta alumina batteries (NBBs) at much lower temperatures (e.g., 95 to 175°C). Commercial NBBs such as sodium-sulfur (Na-S) battery and sodium-metal halide (ZEBRA) batteries typically operate at relatively high temperatures (e.g., 300-350°C) due to poor wettability of sodium on the surface of ?"-Al2O3. Our combined experimental and computational studies suggest that Na-Cs alloy can replace pure sodium as the anode material, which provides a significant improvement in wettability, particularly at lower temperatures (i.e., <200°C). Single cells with the Na-Cs alloy anode exhibit excellent cycling life over those with pure sodium anode at 175 and 150°C. The cells can even operate at 95°C, which is below the melting temperature of pure sodium. These results demonstrate that NBB can be operated at ultra lower temperatures with successfully solving the wetting issue. This work also suggests a new strategy to use liquid metal as the electrode materials for advanced batteries that can avoid the intrinsic safety issues associated with dendrite formation on the anode.

  3. Liquid Metal Transformers

    E-Print Network [OSTI]

    Sheng, Lei; Liu, Jing

    2014-01-01

    The room temperature liquid metal is quickly emerging as an important functional material in a variety of areas like chip cooling, 3D printing or printed electronics etc. With diverse capabilities in electrical, thermal and flowing behaviors, such fluid owns many intriguing properties that had never been anticipated before. Here, we show a group of unconventional phenomena occurring on the liquid metal objects. Through applying electrical field on the liquid metals immersed in water, a series of complex transformation behaviors such as self-assembling of a sheet of liquid metal film into a single sphere, quick mergences of separate metal droplets, controlled self-rotation and planar locomotion of liquid metal objects can be realized. Meanwhile, it was also found that two accompanying water vortexes were induced and reliably swirled near the rotating liquid metal sphere. Further, effects of the shape, size, voltage, orientation and geometries of the electrodes to control the liquid metal transformers were clar...

  4. Metal phthalocyanine catalysts

    DOE Patents [OSTI]

    Ellis, P.E. Jr.; Lyons, J.E.

    1994-10-11

    A new composition of matter is described which is an alkali metal or ammonium or tetraalkylammonium diazidoperfluorophthalocyanatoferrate. Other embodiments of the invention comprise compositions wherein the metal of the coordination complex is cobalt, manganese and chromium.

  5. Metal phthalocyanine catalysts

    DOE Patents [OSTI]

    Ellis, Jr., Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA)

    1994-01-01

    As a new composition of matter, alkali metal or ammonium or tetraalkylammonium diazidoperfluorophthalocyanatoferrate. Other embodiments of the invention comprise compositions wherein the metal of the coordination complex is cobalt, manganese and chromium.

  6. Metal catalyst technique for texturing silicon solar cells

    DOE Patents [OSTI]

    Ruby, Douglas S. (Albuquerque, NM); Zaidi, Saleem H. (Albuquerque, NM)

    2001-01-01

    Textured silicon solar cells and techniques for their manufacture utilizing metal sources to catalyze formation of randomly distributed surface features such as nanoscale pyramidal and columnar structures. These structures include dimensions smaller than the wavelength of incident light, thereby resulting in a highly effective anti-reflective surface. According to the invention, metal sources present in a reactive ion etching chamber permit impurities (e.g. metal particles) to be introduced into a reactive ion etch plasma resulting in deposition of micro-masks on the surface of a substrate to be etched. Separate embodiments are disclosed including one in which the metal source includes one or more metal-coated substrates strategically positioned relative to the surface to be textured, and another in which the walls of the reaction chamber are pre-conditioned with a thin coating of metal catalyst material.

  7. Trapped Electromagnetic Modes and Scaling in the Transmittance of Perforated Metal Films S. Selcuk, K. Woo, D. B. Tanner, and A. F. Hebard

    E-Print Network [OSTI]

    Hebard, Arthur F.

    Trapped Electromagnetic Modes and Scaling in the Transmittance of Perforated Metal Films S. Selcuk that light would not be transmitted by a metal film perforated by a set of holes with size smaller than

  8. Durable metallized polymer mirror

    DOE Patents [OSTI]

    Schissel, P.O.; Kennedy, C.E.; Jorgensen, G.J.; Shinton, Y.D.; Goggin, R.M.

    1994-11-01

    A metallized polymer mirror construction is disclosed having improved durability against delamination and tunneling, comprising: an outer layer of polymeric material; a metal oxide layer underlying the outer layer of polymeric material; a silver reflective layer underneath the metal oxide layer; and a layer of adhesive attaching the silver layer to a substrate. 6 figs.

  9. Durable metallized polymer mirror

    DOE Patents [OSTI]

    Schissel, Paul O. (Golden, CO); Kennedy, Cheryl E. (Lafayette, CO); Jorgensen, Gary J. (Pine, CO); Shinton, Yvonne D. (Northglenn, CO); Goggin, Rita M. (Englewood, CO)

    1994-01-01

    A metallized polymer mirror construction having improved durability against delamination and tunneling, comprising: an outer layer of polymeric material; a metal oxide layer underlying the outer layer of polymeric material; a silver reflective layer underneath the metal oxide layer; and a layer of adhesive attaching the silver layer to a substrate.

  10. PHYTOEXTRACTION OF HEAVY METALS

    E-Print Network [OSTI]

    Blouin-Demers, Gabriel

    Plants Chelating agents Pb hyperaccumulation Effects of pH on metal extraction Disposal options contaminants from soils Contaminants must be in harvestable portions of the plant (Wongkongkatep et al. 2003) Chelating Agents: desorb heavy metals from soil matrix and form water-soluble metal complexes (Shen et al

  11. Metal Affinity Chromatography (MAC)

    E-Print Network [OSTI]

    Lebendiker, Mario

    Fractogel® Metal Affinity Chromatography (MAC) Resins and Cartridges Tools for His·Tag® Fusion-MACTM Cartridges #12;2 Novagen · Fractogel Metal Affinity Chromatography (MAC) Resins Ni-MACTM , Co-MACTM and u-MACTM Metal Affinity Chromatography (MAC) Resins and Cartridges HI Ni2+ Ni2+ Ni2+ HISHISHI SHISHISHIS Ni2

  12. Metal roofing Shingle roofing

    E-Print Network [OSTI]

    Hutcheon, James M.

    Metal roofing panel Shingle roofing Water & ice barrier Thermal Barrier Plywood Student: Arpit a cost benefit analysis and choose the most efficient and cost effective modification. Metal or shingle roof with only a water barrier between the plywood and the roofing panels. Metal roofing panel Shingle

  13. Deficiencies of Lighting Codes and Ordinances in Controlling Light Pollution from Parking Lot Lighting Installations

    E-Print Network [OSTI]

    Royal, Emily

    2012-05-31

    The purpose of this research was to identify the main causes of light pollution from parking lot electric lighting installations and highlight the deficiencies of lighting ordinances in preventing light pollution. Using an industry-accepted lighting...

  14. OpenGL Lighting 13. OpenGL Lighting

    E-Print Network [OSTI]

    McDowell, Perry

    OpenGL Lighting 13. OpenGL Lighting · Overview of Lighting in OpenGL In order for lighting to have an effect in OpenGL, two things are required: A light An object to be lit Lights can be set to any color determine how they reflect the light which hits them. The color(s) of an object is determined

  15. Backward and forward modes guided by metal-dielectric-metal

    E-Print Network [OSTI]

    Backward and forward modes guided by metal-dielectric-metal plasmonic waveguides Arthur R. Davoyan by metal-dielectric-metal plasmonic waveguides Arthur R. Davoyan,a Ilya V. Shadrivov,a Sergey I.davoyan@gmail.com Abstract. We revisited the problem of the existence of plasmonic modes guided by metal- dielectric-metal

  16. CONNECTED LIGHTING SYSTEMS MEETING

    Office of Energy Efficiency and Renewable Energy (EERE)

    There is a lot of buzz today about the Internet of Things and the convergence of intelligent controllable light sources, communication networks, sensors, and data exchange in future lighting...

  17. Fast Light, Fast Neutrinos?

    E-Print Network [OSTI]

    Kevin Cahill

    2011-10-10

    In certain media, light has been observed with group velocities faster than the speed of light. The recent OPERA report of superluminal 17 GeV neutrinos may describe a similar phenomenon.

  18. Kyler Nelson Light Timer

    E-Print Network [OSTI]

    Kachroo, Pushkin

    designated by the user, the Arduino board will dim the light to save energy. The user designates the time instance, the light is dimmed using pulse width modulation (PWM) in the Arduino's pin number 11

  19. Automatic lighting controls demonstration

    SciTech Connect (OSTI)

    Rubinstein, F.; Verderber, R.

    1990-03-01

    The purpose of this work was to demonstrate, in a real building situation, the energy and peak demand reduction capabilities of an electronically ballasted lighting control system that can utilize all types of control strategies to efficiently manage lighting. The project has demonstrated that a state-of-the-art electronically ballasted dimmable lighting system can reduce energy and lighting demand by as least 50% using various combinations of control strategies. By reducing light levels over circulation areas (tuning) and reducing after hours light levels to accommodate the less stringent lighting demands of the cleaning crew (scheduling), lighting energy consumption on weekdays was reduced an average of 54% relative to the initial condition. 10 refs., 14 figs., 3 tabs.

  20. Emission of Visible Light by Hot Dense Metals

    E-Print Network [OSTI]

    More, R.M.

    2010-01-01

    we do not a priori know the emissivity E(to) or dielectricN+l unknowns: the N emissivities E(u)j) and the surfacedependence of the surface emissivity E(cu). For this reason

  1. Reliability Tools for Resonance Inspection of Light Metal Castings |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy BillsNo. 195 - Oct. 7,DOERTIRegulatory and Financial

  2. Controlling the Polarization of Light with Bilayer Subwavelength Metallic

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing BacteriaConnect Collider Testspolycarbonate and plastic

  3. Enhanced Resonance Inspection for Light Metal Castings | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015 Infographiclighbulbs - high-resolution2

  4. Lighting and Daylight Harvesting 

    E-Print Network [OSTI]

    Bos, J.

    2011-01-01

    in 1992 to serve the lighting design needs of the architectural and interior design communities. With over fifty years of combined experience, our areas of expertise range from architectural and theatrical lighting to custom fixture design. Bos... Lighting Design We are active members of the International Association of Lighting Designers, the American Institute of Architects, the Illuminating Engineering Society, International Dark Skies Association and the United States Green Building Council...

  5. LED Lighting Retrofit 

    E-Print Network [OSTI]

    Shaw-Meadow, N.

    2011-01-01

    kWh is the one that never gets used? ?Dedicated to making environmentally responsible products? Ringdale Introduction LED Roadway Lighting Better Light, Fewer Watts. Period. Nathan Shaw-Meadow LED Lighting Specialist Ringdale ActiveLED ESL.../exponential efficiency growth often deters investment today 7 Challenges to Implementation ESL-KT-11-11-57 CATEE 2011, Dallas, Texas, Nov. 7 ? 9, 2011 ? Municipal Street Light Case Study 8 ? Replaced 400W High Pressure Sodium fixtures with 52W Active...

  6. Light emitting device comprising phosphorescent materials for white light generation

    DOE Patents [OSTI]

    Thompson, Mark E.; Dapkus, P. Daniel

    2014-07-22

    The present invention relates to phosphors for energy downconversion of high energy light to generate a broadband light spectrum, which emit light of different emission wavelengths.

  7. And the Oscar for Sustainable Mobile Lighting Goes to.... Lighting...

    Energy Savers [EERE]

    And the Oscar for Sustainable Mobile Lighting Goes to.... Lighting Up Operations with Hydrogen and Fuel Cell Technology And the Oscar for Sustainable Mobile Lighting Goes to.......

  8. Reactor process using metal oxide ceramic membranes

    DOE Patents [OSTI]

    Anderson, M.A.

    1994-05-03

    A reaction vessel for use in photoelectrochemical reactions includes as its reactive surface a metal oxide porous ceramic membrane of a catalytic metal such as titanium. The reaction vessel includes a light source and a counter electrode. A provision for applying an electrical bias between the membrane and the counter electrode permits the Fermi levels of potential reaction to be favored so that certain reactions may be favored in the vessel. The electrical biasing is also useful for the cleaning of the catalytic membrane. Also disclosed is a method regenerating a porous metal oxide ceramic membrane used in a photoelectrochemical catalytic process by periodically removing the reactants and regenerating the membrane using a variety of chemical, thermal, and electrical techniques. 2 figures.

  9. Reactor process using metal oxide ceramic membranes

    DOE Patents [OSTI]

    Anderson, Marc A. (Madison, WI)

    1994-01-01

    A reaction vessel for use in photoelectrochemical reactions includes as its reactive surface a metal oxide porous ceramic membrane of a catalytic metal such as titanium. The reaction vessel includes a light source and a counter electrode. A provision for applying an electrical bias between the membrane and the counter electrode permits the Fermi levels of potential reaction to be favored so that certain reactions may be favored in the vessel. The electrical biasing is also useful for the cleaning of the catalytic membrane. Also disclosed is a method regenerating a porous metal oxide ceramic membrane used in a photoelectrochemical catalytic process by periodically removing the reactants and regenerating the membrane using a variety of chemical, thermal, and electrical techniques.

  10. High Metallicity LGRB Hosts

    E-Print Network [OSTI]

    Graham, J F; Levesque, E M; Kewley, L J; Tanvir, N R; Levan, A J; Patel, S K; Misra, K; Huang, K -H; Reichart, D E; Nysewander, M; Schady, P

    2015-01-01

    We present our imaging and spectroscopic observations of the host galaxies of two dark long bursts with anomalously high metallicities, LGRB 051022 and LGRB 020819B, which in conjunction with another LGRB event with an optical afterglow comprise the three LGRBs with high metallicity host galaxies in the Graham & Fruchter (2013) sample. In Graham & Fruchter (2013), we showed that LGRBs exhibit a strong and apparently intrinsic preference for low metallicity environments (12+log(O/H) & redshift. This is surprising: even among a preselected sample of high metallicity LGRBs, were the metal aversion to remain in effect for these objects, we would expect their metallicity to still be lower than the typical metallicity for the galaxies at that luminosity and redshift. Therefore we deduce that it...

  11. Extraction process for removing metallic impurities from alkalide metals

    DOE Patents [OSTI]

    Royer, L.T.

    1987-03-20

    A development is described for removing metallic impurities from alkali metals by employing an extraction process wherein the metallic impurities are extracted from a molten alkali metal into molten lithium metal due to the immiscibility of the alkali metals in lithium and the miscibility of the metallic contaminants or impurities in the lithium. The purified alkali metal may be readily separated from the contaminant-containing lithium metal by simple decanting due to the differences in densities and melting temperatures of the alkali metals as compared to lithium.

  12. Lighting Design | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Design Lighting Design Energy-efficient indoor and outdoor lighting design focuses on ways to improve both the quality and efficiency of lighting. | Photo courtesy of...

  13. Process for removing heavy metal compounds from heavy crude oil

    DOE Patents [OSTI]

    Cha, Chang Y. (Golden, CO); Boysen, John E. (Laramie, WY); Branthaver, Jan F. (Laramie, WY)

    1991-01-01

    A process is provided for removing heavy metal compounds from heavy crude oil by mixing the heavy crude oil with tar sand; preheating the mixture to a temperature of about 650.degree. F.; heating said mixture to up to 800.degree. F.; and separating tar sand from the light oils formed during said heating. The heavy metals removed from the heavy oils can be recovered from the spent sand for other uses.

  14. Boron-Containing Red Light-Emitting Phosphors And Light Sources Incorporating The Same

    DOE Patents [OSTI]

    Srivastava, Alok Mani (Niskayuna, NY); Comanzo, Holly Ann (Niskayuna, NY); Manivannan, Venkatesan (Clifton Park, NY)

    2006-03-28

    A boron-containing phosphor comprises a material having a formula of AD1-xEuxB9O16, wherein A is an element selected from the group consisting of Ba, Sr, Ca, Mg, and combinations thereof; D is at least an element selected from the group consisting of rare-earth metals other than europium; and x is in the range from about 0.005 to about 0.5. The phosphor is used in a blend with other phosphors in a light source for generating visible light with a high color rendering index.

  15. Light extraction from organic light-emitting diodes for lighting applications by sand-blasting

    E-Print Network [OSTI]

    Light extraction from organic light-emitting diodes for lighting applications by sand@ust.hk Abstract: Light extraction from organic light-emitting diodes (OLEDs) by scattering the light is one of the effective methods for large-area lighting applications. In this paper, we present a very simple and cost

  16. Induction Lighting: An Old Lighting Technology Made New Again

    Broader source: Energy.gov [DOE]

    Induction lighting is one of the best kept secrets in energy-efficient lighting. Simply stated, induction lighting is essentially a fluorescent light without electrodes or filaments, the items that...

  17. Lighting the Night: Technology, Urban Life and the Evolution of Street Lighting [Light in Place

    E-Print Network [OSTI]

    Holden, Alfred

    1992-01-01

    Electrical 16. "Highway Lighting by So­ dium Vapor Lamps,"Possibilities of Street: Lighting Improve­ ments," TheLaunches Broad Street Lighting Promotion Campaign," The

  18. ECE 466: LED Lighting Systems -Incandescent lightings rise and

    E-Print Network [OSTI]

    Connors, Daniel A.

    ECE 466: LED Lighting Systems - Incandescent lightings rise and demise via government policy - Alternative Fluorescent light sources and compact fluorescent lights (CFL) to incandescents - Alternative LED light sources - Color index as well as Watts to Lumens efficiency available from all three light sources

  19. Lighting and Surfaces 11.1 Introduction to Lighting

    E-Print Network [OSTI]

    Boyd, John P.

    Chapter 11 Lighting and Surfaces 11.1 Introduction to Lighting Three-dimensional surfaces can react to light, and how computer graphics simulates this. There are three species of light (or "illumination models"): 1. Intrinsic (self-emitting) 2. Ambient light (sometimes called "diffuse light") 3

  20. Parameters influencing the deposition of methylammonium lead halide iodide in hole conductor free perovskite-based solar cells

    SciTech Connect (OSTI)

    Cohen, Bat-El; Gamliel, Shany; Etgar, Lioz

    2014-08-01

    Perovskite is a promising light harvester for use in photovoltaic solar cells. In recent years, the power conversion efficiency of perovskite solar cells has been dramatically increased, making them a competitive source of renewable energy. An important parameter when designing high efficiency perovskite-based solar cells is the perovskite deposition, which must be performed to create complete coverage and optimal film thickness. This paper describes an in-depth study on two-step deposition, separating the perovskite deposition into two precursors. The effects of spin velocity, annealing temperature, dipping time, and methylammonium iodide concentration on the photovoltaic performance are studied. Observations include that current density is affected by changing the spin velocity, while the fill factor changes mainly due to the dipping time and methylammonium iodide concentration. Interestingly, the open circuit voltage is almost unaffected by these parameters. Hole conductor free perovskite solar cells are used in this work, in order to minimize other possible effects. This study provides better understanding and control over the perovskite deposition through highly efficient, low-cost perovskite-based solar cells.

  1. Sandia Energy - Light Creation Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Light Creation Materials Home Energy Research EFRCs Solid-State Lighting Science EFRC Overview Light Creation Materials Light Creation MaterialsAlyssa Christy2015-03-26T16:28:52+00...

  2. Arnold Schwarzenegger LIGHTING RESEARCH PROGRAM

    E-Print Network [OSTI]

    Project Summaries ELEMENT 2: ADVANCE LIGHTING TECHNOLOGIES PROJECT 2.1 LIGHT EMITTING DIODE (LED light emitting diodes (LED) technology for general lighting applications by developing a task lamp

  3. Narrow-band optical transmission of metallic nanoslit arrays

    SciTech Connect (OSTI)

    Sun Zhijun; Yang Ying; Zuo Xiaoliu

    2012-10-22

    Metallic nanoslit arrays usually demonstrate wide transmission bands for transverse-magnetic-polarized incidence light. Here, we show that by introducing multi-dielectric layers underneath the metallic structure layer on the substrate, a narrow peak is formed, whose bandwidth can be down to a few nanometers. Three types of resonance modes in the region under the metal layer are identified responsible for the formation of the peak, i.e., a two-dimensional cavity resonance mode, which supports optical transmission, and two in-plane hybrid surface plasmon resonance modes locating on both sides of the peak that suppresses the transmission. Such structures can be applied in advanced photonic devices.

  4. Understanding the movements of metal whiskers

    E-Print Network [OSTI]

    Victor G. Karpov

    2015-05-24

    Metal whiskers often grow across leads of electric equipment and electronic package causing current leakage or short circuits and raising significant reliability issues. The nature of metal whiskers remains a mystery after several decades of research. In addition, metal whiskers exhibit a rather unusual dynamic property of relatively high amplitude movements under gentle air flow or, according to some testimonies, without obvious stimuli. Understanding the physics behind that motion would give additional insights into the nature of metal whiskers. Here, we quantitatively analyze several possible mechanisms potentially responsible for the observed movements: (1) minute air currents, (2) Brownian motion due to random bombardments with the air molecules, (3) mechanically caused movements, such as (a) externally transmitted vibrations of the sample, and (b) torque exerted due to material propagation along curved whiskers responsible for the whisker growth (similar to the known garden hose oscillations), (4) time dependent electric fields due to diffusion of ions across the metal surface, and (5) nonequilibrium electric field configurations making it possible for {\\it some} whiskers to move. For all these scenarios we provide numerical estimates. Our conclusion is that the observed movements are likely due to the minor air currents, intentional or ill-controlled, and that external mechanical vibrations could force such movements in a rather harsh environment or/and for whiskers with severe constrictions. We argue that under non-steady state conditions, such as caused by changes in the external light intensity, some whiskers can exercise spontaneous oscillations.

  5. 47.2 / C. F. Qiu 47.2: Hole Injection and Power Efficiency of Organic Light Emitting Diodes

    E-Print Network [OSTI]

    been obtained. 1. Introduction Organic light-emitting diode (OLED) is challenging liquid- crystal (LC47.2 / C. F. Qiu 47.2: Hole Injection and Power Efficiency of Organic Light Emitting Diodes- metal layer such as, carbon, gallium, silicon, has been used as hole-injecting anode in organic light

  6. Metal atomization spray nozzle

    DOE Patents [OSTI]

    Huxford, T.J.

    1993-11-16

    A spray nozzle for a magnetohydrodynamic atomization apparatus has a feed passage for molten metal and a pair of spray electrodes mounted in the feed passage. The electrodes, diverging surfaces which define a nozzle throat and diverge at an acute angle from the throat. Current passes through molten metal when fed through the throat which creates the Lorentz force necessary to provide atomization of the molten metal. 6 figures.

  7. Dynamics Displayed by Energetic C60 Bombardment of Metal Overlayers on an Organic Substrate

    E-Print Network [OSTI]

    Zbigniew, Postawa

    in organic light- emitting diodes (OLED).5 However, metal layers have also been applied in developing organic used successfully to depth profile through OLED type devices using large gas cluster ion beams

  8. Polyacidic multiloading metal extractants 

    E-Print Network [OSTI]

    Gordon, R. J.; Campbell, J.; Henderson, D.K.; Henry, D. C. R.; Swart, R. M.; Tasker, P. A.; White, F. J.; Wood, J. L.; Yellowlees, L. J

    2008-01-01

    Novel polynucleating, di- and tri-acidic ligands have been designed to increase the molar and mass transport efficiencies for the recovery of base metals by solvent extraction.

  9. Simulations of optical sensors fabricated from metallic rods couplers

    SciTech Connect (OSTI)

    Singh, M. R.; Balakrishanan, Shankar

    2014-03-31

    We have developed the optical sensing mechanism of photonic couplers fabricated from the periodically arranged metallic rods. The metallic rod lattice is embedded between two dielectric material waveguides. This structure is called metallic coupler. Using the transfer matrix method, expressions for the reflection and transmission coefficients of electromagnetic wave propagating in waveguides have been obtained. We found that for certain energies, the electromagnetic wave is totally reflected from the coupler. Similarly, for a certain energy range the light is totally transmitted. It has also been found that by changing the periodicity of the metallic rods, the transmitted energy can be reflected. The periodicity of the metallic lattice can be modified by applying an external stress or pressure. In other words, the system can be used as stress and pressure sensors. The present findings can be used to make new types photonic sensors.

  10. Fabrication and Preliminary Evaluation of Metal Matrix Microencapsulated Fuels

    SciTech Connect (OSTI)

    Terrani, Kurt A [ORNL; Kiggans, Jim [ORNL; Snead, Lance Lewis [ORNL

    2012-01-01

    The metal matrix microencapsulated (M3) fuel concept for light water reactors (LWRs), consisting of coated fuel particles dispersed in a zirconium metal matrix, is introduced. Fabrication of M3 fuels by hot pressing, hot isostatic pressing, or extrusion methodologies has been demonstrated over the temperature range 800-1050 C. Various types of coated fuel particles with outermost layers of pyrocarbon, SiC, ZrC, and TiN have been incorporated into the zirconium metal matrix. Mechanical particle-particle and chemical particle-matrix interactions have been observed during the preliminary characterization of as-fabricated M3 specimens. Irradiation of three M3 rodlets with surrogate coated fuel particles was carried out at mean rod temperature of 400 C to 4.6 dpa in the zirconium metal matrix. Due to absence of texture in the metal matrix no irradiation growth strain (<0.09%) was detected during the post-irradiation examination.

  11. High efficiency incandescent lighting

    DOE Patents [OSTI]

    Bermel, Peter; Ilic, Ognjen; Chan, Walker R.; Musabeyoglu, Ahmet; Cukierman, Aviv Ruben; Harradon, Michael Robert; Celanovic, Ivan; Soljacic, Marin

    2014-09-02

    Incandescent lighting structure. The structure includes a thermal emitter that can, but does not have to, include a first photonic crystal on its surface to tailor thermal emission coupled to, in a high-view-factor geometry, a second photonic filter selected to reflect infrared radiation back to the emitter while passing visible light. This structure is highly efficient as compared to standard incandescent light bulbs.

  12. National Synchrotron Light Source

    ScienceCinema (OSTI)

    BNL

    2009-09-01

    A tour of Brookhaven's National Synchrotron Light Source (NSLS), hosted by Associate Laboratory Director for Light Sources, Stephen Dierker. The NSLS is one of the world's most widely used scientific research facilities, hosting more than 2,500 guest researchers each year. The NSLS provides intense beams of infrared, ultraviolet, and x-ray light for basic and applied research in physics, chemistry, medicine, geophysics, environmental, and materials sciences.

  13. Faster Than Light?

    E-Print Network [OSTI]

    Robert Geroch

    2010-05-10

    It is argued that special relativity remains a viable physical theory even when there is permitted signals traveling faster than light.

  14. Comparing Light Bulbs

    Office of Energy Efficiency and Renewable Energy (EERE)

    In this exercise, students will use a light to demonstrate the difference between being energy-efficient and energy-wasteful, and learn what energy efficiency means.

  15. Lighting in Commercial Buildings

    U.S. Energy Information Administration (EIA) Indexed Site

    Illuminance Assignments for CBECS Building Activity Categories Illuminance ranges were adopted from the 1987 Illuminating Engineering Society (IES) Lighting Handbook. The IES...

  16. Lighting in Commercial Buildings

    U.S. Energy Information Administration (EIA) Indexed Site

    from the engineering literature, based on CBECS building activity.) 4. Efficacy: an energy efficiency measure. Technically, the amount of light produced per unit of energy...

  17. Lighting in Commercial Buildings

    U.S. Energy Information Administration (EIA) Indexed Site

    (CEC), March 1990. Advanced Lighting Technologies Application Guidelines (ALTAG), Building and Appliance Efficiency Office. 3. Dubin, F.S., Mindell, H.L., and Bloome, S., 1976....

  18. Lighting in Commercial Buildings

    U.S. Energy Information Administration (EIA) Indexed Site

    energy are presented in this section. Statistics are presented by subgroups based on building characteristics, and by subgroups based on lighting equipment. The three sets of...

  19. Ultra-thin ohmic contacts for p-type nitride light emitting devices

    DOE Patents [OSTI]

    Raffetto, Mark (Raleigh, NC); Bharathan, Jayesh (Cary, NC); Haberern, Kevin (Cary, NC); Bergmann, Michael (Chapel Hill, NC); Emerson, David (Chapel Hill, NC); Ibbetson, James (Santa Barbara, CA); Li, Ting (Ventura, CA)

    2012-01-03

    A semiconductor based Light Emitting Device (LED) can include a p-type nitride layer and a metal ohmic contact, on the p-type nitride layer. The metal ohmic contact can have an average thickness of less than about 25 .ANG. and a specific contact resistivity less than about 10.sup.-3 ohm-cm.sup.2.

  20. Literature Review of the Effects of UV Exposure on PV Modules

    Broader source: Energy.gov [DOE]

    This PowerPoint presentation, originally presented at the NREL 2013 PV Module Reliability Workshop on Feb. 26-27, 2013 in Denver, CO, presents the literature review of the effects of prolonged UV exposure of PV modules, with a particular emphasis on UV exposure testing using artificial light sources, including fluorescent, Xenon, and metal halide lamps.

  1. Edmund G. Brown Jr. LIGHTING CALIFORNIA'S FUTURE

    E-Print Network [OSTI]

    Edmund G. Brown Jr. Governor LIGHTING CALIFORNIA'S FUTURE: SMART LIGHT-EMITTING DIODE LIGHTING's Future: Smart LightEmitting Diode Lighting in Residential Fans. California Energy Commission, PIER

  2. Ultrathin metal-semiconductor-metal resonator for angle invariant visible band transmission filters

    SciTech Connect (OSTI)

    Lee, Kyu-Tae; Seo, Sungyong; Yong Lee, Jae; Jay Guo, L.

    2014-06-09

    We present transmission visible wavelength filters based on strong interference behaviors in an ultrathin semiconductor material between two metal layers. The proposed devices were fabricated on 2?cm?×?2?cm glass substrate, and the transmission characteristics show good agreement with the design. Due to a significantly reduced light propagation phase change associated with the ultrathin semiconductor layer and the compensation in phase shift of light reflecting from the metal surface, the filters show an angle insensitive performance up to ±70°, thus, addressing one of the key challenges facing the previously reported photonic and plasmonic color filters. This principle, described in this paper, can have potential for diverse applications ranging from color display devices to the image sensors.

  3. Metal pad instabilities in liquid metal batteries

    E-Print Network [OSTI]

    Zikanov, Oleg

    2015-01-01

    A mechanical analogy is used to analyze the interaction between the magnetic field, electric current and deformation of interfaces in liquid metal batteries. It is found that, during charging or discharging, a sufficiently large battery is prone to instabilities of two types. One is similar to the metal pad instability known for aluminum reduction cells. Another type is new. It is related to the destabilizing effect of the Lorentz force formed by the azimuthal magnetic field induced by the base current and the current perturbations caused by the local variations of the thickness of the electrolyte layer.

  4. EURODISPLAY 2002 631 P-64: A Comparative Study of Metal Oxide Coated Indium-tin Oxide Anodes

    E-Print Network [OSTI]

    over that of a conventional OLED without an oxide capped anode. 1. Introduction Organic light for Organic Light-emitting Diodes Chengfeng Qiu, Haiying Chen, Zhilang Xie, Man Wong and Hoi Sing Kwok Center of metals enhance while other oxides degrade the hole-injection and quantum efficiencies of organic light

  5. Heavy Metal Humor: Reconsidering Carnival in Heavy Metal Culture 

    E-Print Network [OSTI]

    Powell, Gary Botts

    2013-06-05

    Bakhtin?s carnivalesque theory by analyzing comedic rhetoric performed by two comedic metal bands. Through the theories of Johan Huizinga and Mikhail Bakhtin, Chapter I: I Play Metal argues that heavy metal culture is a modern carnivalesque play...

  6. Metal-Organic Frameworks Based on Main Group Metals

    E-Print Network [OSTI]

    Zhao, Xiang

    2011-01-01

    Based Frameworks with Open Metal Sites In previous work, weClusters Introduction Porous metal-organic frameworks (MOFs)abundant choice of metal ions and clusters, numerous organic

  7. Metallic nanowire networks

    DOE Patents [OSTI]

    Song, Yujiang; Shelnutt, John A.

    2012-11-06

    A metallic nanowire network synthesized using chemical reduction of a metal ion source by a reducing agent in the presence of a soft template comprising a tubular inverse micellar network. The network of interconnected polycrystalline nanowires has a very high surface-area/volume ratio, which makes it highly suitable for use in catalytic applications.

  8. Porous metallic bodies

    DOE Patents [OSTI]

    Landingham, R.L.

    1984-03-13

    Porous metallic bodies having a substantially uniform pore size of less than about 200 microns and a density of less than about 25 percent theoretical, as well as the method for making them, are disclosed. Group IIA, IIIB, IVB, VB, and rare earth metal hydrides a

  9. Explosively pumped laser light

    DOE Patents [OSTI]

    Piltch, Martin S. (Los Alamos, NM); Michelotti, Roy A. (Los Alamos, NM)

    1991-01-01

    A single shot laser pumped by detonation of an explosive in a shell casing. The shock wave from detonation of the explosive causes a rare gas to luminesce. The high intensity light from the gas enters a lasing medium, which thereafter outputs a pulse of laser light to disable optical sensors and personnel.

  10. Light intensity compressor

    DOE Patents [OSTI]

    Rushford, Michael C. (Livermore, CA)

    1990-01-01

    In a system for recording images having vastly differing light intensities over the face of the image, a light intensity compressor is provided that utilizes the properties of twisted nematic liquid crystals to compress the image intensity. A photoconductor or photodiode material that is responsive to the wavelength of radiation being recorded is placed adjacent a layer of twisted nematic liquid crystal material. An electric potential applied to a pair of electrodes that are disposed outside of the liquid crystal/photoconductor arrangement to provide an electric field in the vicinity of the liquid crystal material. The electrodes are substantially transparent to the form of radiation being recorded. A pair of crossed polarizers are provided on opposite sides of the liquid crystal. The front polarizer linearly polarizes the light, while the back polarizer cooperates with the front polarizer and the liquid crystal material to compress the intensity of a viewed scene. Light incident upon the intensity compressor activates the photoconductor in proportion to the intensity of the light, thereby varying the field applied to the liquid crystal. The increased field causes the liquid crystal to have less of a twisting effect on the incident linearly polarized light, which will cause an increased percentage of the light to be absorbed by the back polarizer. The intensity of an image may be compressed by forming an image on the light intensity compressor.

  11. Production of magnesium metal

    DOE Patents [OSTI]

    Blencoe, James G. (Harriman, TN) [Harriman, TN; Anovitz, Lawrence M. (Knoxville, TN) [Knoxville, TN; Palmer, Donald A. (Oliver Springs, TN) [Oliver Springs, TN; Beard, James S. (Martinsville, VA) [Martinsville, VA

    2010-02-23

    A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention further relates to a process for production of magnesium metal or a magnesium compound where an external source of carbon dioxide is not used in any of the reactions of the process. The invention also relates to the magnesium metal produced by the processes described herein.

  12. Metallization of electronic insulators

    DOE Patents [OSTI]

    Gottesfeld, Shimshon (Los Alamos, NM); Uribe, Francisco A. (Los Alamos, NM)

    1994-01-01

    An electroplated element is formed to include an insulating substrate, a conducting polymer polymerized in situ on the substrate, and a metal layer deposited on the conducting polymer. In one application a circuit board is formed by polymerizing pyrrole on an epoxy-fiberglass substrate in a single step process and then electrodepositing a metal over the resulting polypyrrole polymer. No chemical deposition of the metal is required prior to electroplating and the resulting layer of substrate-polymer-metal has excellent adhesion characteristics. The metal deposition is surprisingly smooth and uniform over the relatively high resistance film of polypyrrole. A continuous manufacturing process is obtained by filtering the solution between successive substrates to remove polymer formed in the solution, by maintaining the solution oxidizing potential within selected limits, and by adding a strong oxidant, such as KMnO.sub.4 at periodic intervals to maintain a low sheet resistivity in the resulting conducting polymer film.

  13. Ionic liquid polyoxometalates as light emitting materials

    SciTech Connect (OSTI)

    Ortiz-acosta, Denisse [Los Alamos National Laboratory; Del Sesto, Rico E [Los Alamos National Laboratory; Scott, Brian [Los Alamos National Laboratory; Bennett, Bryan L [Los Alamos National Laboratory; Purdy, Geraldine M [Los Alamos National Laboratory; Muenchausen, Ross E [Los Alamos National Laboratory; Mc Kigney, Edward [Los Alamos National Laboratory; Gilbertson, Robert [Los Alamos National Laboratory

    2008-01-01

    The low melting point, negligible vapor pressure, good solubility, and thermal and chemical stability make ionic liquids useful materials for a wide variety of applications. Polyoxometalates are early transition metal oxygen clusters that can be synthesized in many different sizes and with a variety of heterometals. The most attractive feature of POMs is that their physical properties, in particular electrical, magnetic, and optical properties, can be easily modified following known procedures. It has been shown that POMs can exhibit cooperative properties, as superconductivity and energy transfer. POM ionic liquids can be obtained by selecting the appropliate cation. Different alkyl ammonium and alkyl phosphonium salts are being used to produce new POM ionic liquids together with organic or inorganic luminescent centers to design light emitting materials. Ammonium and phosphonium cations with activated, polymerizable groups are being used to further polymerize the ionic liquid into transparent, solid materials with high metal density.

  14. Nonlinear metaldielectric nanoantennas for light switching and routing This article has been downloaded from IOPscience. Please scroll down to see the full text article.

    E-Print Network [OSTI]

    Nonlinear metal­dielectric nanoantennas for light switching and routing This article has been for this issue, or go to the journal homepage for more Home Search Collections Journals About Contact us My metal­dielectric nanoantennas for light switching and routing R E Noskov1,3 , A E Krasnok1 and Yu

  15. Dielectric back scattering patterns for light trapping in thin-film Si solar cells

    E-Print Network [OSTI]

    Polman, Albert

    Dielectric back scattering patterns for light trapping in thin-film Si solar cells M. van Lare,1 of dielectric and metallic backscattering patterns in thin-film a-Si:H solar cells. We compare devices for Light Trapping in Thin-Film Silicon Solar Cells", in Proceedings of the 23rd European Photovoltaic Solar

  16. Buffer Layer Assisted Laser Patterning of Metals on Surfaces

    E-Print Network [OSTI]

    Asscher, Micha

    power. In general, absorbed laser power density above 10 MW/cm2 should be avoided, to conserve* Department of Physical Chemistry, The Farkas Center for Light Induced Processes, The Hebrew Uni tool of metallic thin films on surfaces due to their strong binding and the extremely high laser power

  17. Lighting affects appearance LightSource emits photons

    E-Print Network [OSTI]

    Jacobs, David

    1 Lighting affects appearance #12;2 LightSource emits photons Photons travel in a straight line). And then some reach the eye/camera. #12;3 Reflectance Model how objects reflect light. Model light sources Algorithms for computing Shading: computing intensities within polygons Determine what light strikes what

  18. VIRTUAL LIGHT: DIGITALLY-GENERATED LIGHTING FOR VIDEO CONFERENCING APPLICATIONS

    E-Print Network [OSTI]

    Greenberg, Albert

    VIRTUAL LIGHT: DIGITALLY-GENERATED LIGHTING FOR VIDEO CONFERENCING APPLICATIONS Andrea Basso method to improve the lighting conditions of a real scene or video sequence. In particular we concentrate on modifying real light sources intensities and inserting virtual lights into a real scene viewed from a fixed

  19. LightBox -Exploring Interaction Modalities with Colored Light

    E-Print Network [OSTI]

    of light to very subtle animations, transitions and dimmed lighting effects. Implementation LightBox is housed in an aluminum suitcase measuring 48x38x25cm. The lid of the suitcase contains a panel of 12x12 Design. Figure 1. An animated lighting sequence visualized on the hi-power LEDs of LightBox #12

  20. Indoor positioning algorithm using light-emitting diode visible light

    E-Print Network [OSTI]

    Kavehrad, Mohsen

    Indoor positioning algorithm using light- emitting diode visible light communications Zhou Zhou of Use: http://spiedl.org/terms #12;Indoor positioning algorithm using light-emitting diode visible light. This paper proposes a novel indoor positioning algorithm using visible light communications (VLC

  1. Metal nanodisks using bicellar templates

    DOE Patents [OSTI]

    Song, Yujiang; Shelnutt, John A

    2013-12-03

    Metallic nanodisks and a method of making them. The metallic nanodisks are wheel-shaped structures that that provide large surface areas for catalytic applications. The metallic nanodisks are grown within bicelles (disk-like micelles) that template the growth of the metal in the form of approximately circular dendritic sheets. The zero-valent metal forming the nanodisks is formed by reduction of a metal ion using a suitable electron donor species.

  2. Superconducting Detectors for Super Light Dark Matter

    E-Print Network [OSTI]

    Yonit Hochberg; Yue Zhao; Kathryn M. Zurek

    2015-04-27

    We propose and study a new class of of superconducting detectors which are sensitive to O(meV) electron recoils from dark matter-electron scattering. Such devices could detect dark matter as light as the warm dark matter limit, mX > keV. We compute the rate of dark matter scattering off free electrons in a (superconducting) metal, including the relevant Pauli blocking factors. We demonstrate that classes of dark matter consistent with all astrophysical and terrestrial constraints could be detected by such detectors with a moderate size exposure.

  3. Superconducting Detectors for Super Light Dark Matter

    E-Print Network [OSTI]

    Hochberg, Yonit; Zurek, Kathryn M

    2015-01-01

    We propose and study a new class of of superconducting detectors which are sensitive to O(meV) electron recoils from dark matter-electron scattering. Such devices could detect dark matter as light as the warm dark matter limit, mX > keV. We compute the rate of dark matter scattering off free electrons in a (superconducting) metal, including the relevant Pauli blocking factors. We demonstrate that classes of dark matter consistent with all astrophysical and terrestrial constraints could be detected by such detectors with a moderate size exposure.

  4. Superconducting Detectors for Super Light Dark Matter

    E-Print Network [OSTI]

    Yonit Hochberg; Yue Zhao; Kathryn M. Zurek

    2015-11-11

    We propose and study a new class of superconducting detectors which are sensitive to O(meV) electron recoils from dark matter-electron scattering. Such devices could detect dark matter as light as the warm dark matter limit, mX > keV. We compute the rate of dark matter scattering off of free electrons in a (superconducting) metal, including the relevant Pauli blocking factors. We demonstrate that classes of dark matter consistent with terrestrial and cosmological/astrophysical constraints could be detected by such detectors with a moderate size exposure.

  5. Preparation of uniform nanoparticles of ultra-high purity metal oxides, mixed metal oxides, metals, and metal alloys

    DOE Patents [OSTI]

    Woodfield, Brian F.; Liu, Shengfeng; Boerio-Goates, Juliana; Liu, Qingyuan; Smith, Stacey Janel

    2012-07-03

    In preferred embodiments, metal nanoparticles, mixed-metal (alloy) nanoparticles, metal oxide nanoparticles and mixed-metal oxide nanoparticles are provided. According to embodiments, the nanoparticles may possess narrow size distributions and high purities. In certain preferred embodiments, methods of preparing metal nanoparticles, mixed-metal nanoparticles, metal oxide nanoparticles and mixed-metal nanoparticles are provided. These methods may provide tight control of particle size, size distribution, and oxidation state. Other preferred embodiments relate to a precursor material that may be used to form nanoparticles. In addition, products prepared from such nanoparticles are disclosed.

  6. Metal-Poor Stars

    E-Print Network [OSTI]

    Anna Frebel

    2008-02-13

    The abundance patterns of metal-poor stars provide us a wealth of chemical information about various stages of the chemical evolution of the Galaxy. In particular, these stars allow us to study the formation and evolution of the elements and the involved nucleosynthesis processes. This knowledge is invaluable for our understanding of the cosmic chemical evolution and the onset of star- and galaxy formation. Metal-poor stars are the local equivalent of the high-redshift Universe, and offer crucial observational constraints on the nature of the first stars. This review presents the history of the first discoveries of metal-poor stars that laid the foundation to this field. Observed abundance trends at the lowest metallicities are described, as well as particular classes of metal-poor stars such as r-process and C-rich stars. Scenarios on the origins of the abundances of metal-poor stars and the application of large samples of metal-poor stars to cosmological questions are discussed.

  7. On Measuring the Metallicity of Supernovae Type Ia Progenitors

    E-Print Network [OSTI]

    Miles, Broxton J; Townsley, Dean M; Timmes, F X; Jackson, Aaron P; Calder, Alan C; Brown, Edward F

    2015-01-01

    In Type Ia Supernovae (\\sneia), the relative abundances of chemical elements are affected by the neutron excess in the composition of the progenitor white dwarf. Since these products leave signatures in the spectra near maximum light, spectral features may be used to constrain the composition of the progenitor. We calculate the nucleosynthetic yields for three \\snia simulations for a wide range of progenitor metallicities, and calculate synthetic light curves and spectra to explore correlations between progenitor metallicity and the strength of spectral features. We use two 2D simulations of the deflagration-detonation-transition scenario with different $^{56}$Ni yields and the W7 simulation to control for differences between explosion models and total yields. While the overall yields of intermediate mass elements (16 $<$ A $\\leq$ 40) differ between the three cases, trends in the yields are similar. With increasing metallicity, $^{28}$Si yields remain nearly constant, $^{40}$Ca yields decline, and Ti and $...

  8. Actinide metal processing

    DOE Patents [OSTI]

    Sauer, N.N.; Watkin, J.G.

    1992-03-24

    A process for converting an actinide metal such as thorium, uranium, or plutonium to an actinide oxide material by admixing the actinide metal in an aqueous medium with a hypochlorite as an oxidizing agent for sufficient time to form the actinide oxide material and recovering the actinide oxide material is described together with a low temperature process for preparing an actinide oxide nitrate such as uranyl nitrate. Additionally, a composition of matter comprising the reaction product of uranium metal and sodium hypochlorite is provided, the reaction product being an essentially insoluble uranium oxide material suitable for disposal or long term storage.

  9. Actinide metal processing

    DOE Patents [OSTI]

    Sauer, Nancy N. (Los Alamos, NM); Watkin, John G. (Los Alamos, NM)

    1992-01-01

    A process of converting an actinide metal such as thorium, uranium, or plnium to an actinide oxide material by admixing the actinide metal in an aqueous medium with a hypochlorite as an oxidizing agent for sufficient time to form the actinide oxide material and recovering the actinide oxide material is provided together with a low temperature process of preparing an actinide oxide nitrate such as uranyl nitrte. Additionally, a composition of matter comprising the reaction product of uranium metal and sodium hypochlorite is provided, the reaction product being an essentially insoluble uranium oxide material suitable for disposal or long term storage.

  10. EXELFS of Metallic Glasses

    SciTech Connect (OSTI)

    Ito, Y.; Alamgir, F.M.; Schwarz, R.B.; Jain, H.; Williams, D.B.

    1999-11-30

    The feasibility of using extended energy-loss fine structure (EXELFS) obtained from {approximately}1 nm regions of metallic glasses to study their short-range order has been examined. Ionization edges of the metallic glasses in the electron energy-loss spectrum (EELS) have been obtained from PdNiP bulk metallic glass and Ni{sub 2}P polycrystalline powder in a transmission electron microscope. The complexity of EXELFS analysis of L- and M-ionization edges of heavy elements (Z>22, i.e. Ni and Pd) is addressed by theoretical calculations using an ab initio computer code, and its results are compared with the experimental data.

  11. Liquid metal electric pump

    DOE Patents [OSTI]

    Abbin, J.P.; Andraka, C.E.; Lukens, L.L.; Moreno, J.B.

    1992-01-14

    An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other. 3 figs.

  12. White light velocity interferometer

    DOE Patents [OSTI]

    Erskine, D.J.

    1999-06-08

    The invention is a technique that allows the use of broadband and incoherent illumination. Although denoted white light velocimetry, this principle can be applied to any wave phenomenon. For the first time, powerful, compact or inexpensive sources can be used for remote target velocimetry. These include flash and arc lamps, light from detonations, pulsed lasers, chirped frequency lasers, and lasers operating simultaneously in several wavelengths. The technique is demonstrated with white light from an incandescent source to measure a target moving at 16 m/s. 41 figs.

  13. Green Light Pulse Oximeter

    DOE Patents [OSTI]

    Scharf, John Edward (Oldsmar, FL)

    1998-11-03

    A reflectance pulse oximeter that determines oxygen saturation of hemoglobin using two sources of electromagnetic radiation in the green optical region, which provides the maximum reflectance pulsation spectrum. The use of green light allows placement of an oximetry probe at central body sites (e.g., wrist, thigh, abdomen, forehead, scalp, and back). Preferably, the two green light sources alternately emit light at 560 nm and 577 nm, respectively, which gives the biggest difference in hemoglobin extinction coefficients between deoxyhemoglobin, RHb, and oxyhemoglobin, HbO.sub.2.

  14. Lakeview Light and Power- Commercial Lighting Rebate Program

    Broader source: Energy.gov [DOE]

    Lakeview Light and Power offers a commercial lighting rebate program. Rebates apply to the installation of energy efficient lighting retrofits in non-residential buildings. The rebate program is...

  15. Demonstration Assessment of Light-Emitting Diode (LED) Roadway Lighting

    SciTech Connect (OSTI)

    None

    2009-11-01

    A U.S. Department of Energy Solid-State Lighting Gateway Report on a Demonstration Assessment of Light-Emitting Diode (LED) Roadway Lighting in Lija Loop, Portland, Oregon.

  16. Method of producing thermally sprayed metallic coating

    DOE Patents [OSTI]

    Byrnes, Larry Edward (Rochester Hills, MI); Kramer, Martin Stephen (Clarkston, MI); Neiser, Richard A. (Albuquerque, NM)

    2003-08-26

    The cylinder walls of light metal engine blocks are thermally spray coated with a ferrous-based coating using an HVOF device. A ferrous-based wire is fed to the HVOF device to locate a tip end of the wire in a high temperature zone of the device. Jet flows of oxygen and gaseous fuel are fed to the high temperature zone and are combusted to generate heat to melt the tip end. The oxygen is oversupplied in relation to the gaseous fuel. The excess oxygen reacts with and burns a fraction of the ferrous-based feed wire in an exothermic reaction to generate substantial supplemental heat to the HVOF device. The molten/combusted metal is sprayed by the device onto the walls of the cylinder by the jet flow of gases.

  17. Columbia Water & Light- HVAC and Lighting Efficiency Rebates

    Broader source: Energy.gov [DOE]

    Columbia Water & Light (CWL) offers rebates to its commercial and industrial customers for the purchase of high efficiency HVAC installations and efficient lighting. Incentives for certain...

  18. Peninsula Light Company- Commercial Efficient Lighting Rebate Program

    Broader source: Energy.gov [DOE]

    Peninsula Light Company (PLC) offers a rebate program for commercial customers who wish to upgrade to energy efficient lighting. Participating customers must be served by PLC commercial service....

  19. Light Vector Mesons

    E-Print Network [OSTI]

    Alexander Milov

    2008-12-21

    This article reviews the current status of experimental results obtained in the measurement of light vector mesons produced in proton-proton and heavy ion collisions at different energies. The review is focused on two phenomena related to the light vector mesons; the modification of the spectral shape in search of Chiral symmetry restoration and suppression of the meson production in heavy ion collisions. The experimental results show that the spectral shape of light vector mesons are modified compared to the parameters measured in vacuum. The nature and the magnitude of the modification depends on the energy density of the media in which they are produced. The suppression patterns of light vector mesons are different from the measurements of other mesons and baryons. The mechanisms responsible for the suppression of the mesons are not yet understood. Systematic comparison of existing experimental results points to the missing data which may help to resolve the problem.

  20. lighting in the library

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    lamp produces about 1750 lumens. Footcandle: a lumen of light distributed over a 1-square-foot (0.09-square-meter) area. Ideal Illumination: the minimum number of footcandles...

  1. Solid State Lighting Reliability

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solid State Lighting Reliability 2015Building Technologies Office Peer Review Lynn Davis, PhD RTI International ldavis@rti.org --- 919-316-3325 Project Summary Timeline: Start...

  2. The Facts of Light

    E-Print Network [OSTI]

    Horn, Berthold K.P.

    This is a random collection of facts about radiant and luminous energy. Some of this information may be useful in the design of photo-diode image sensors, in the set-up of lighting for television microscopes and the ...

  3. National Synchrotron Light Source

    ScienceCinema (OSTI)

    None

    2010-01-08

    A tour of Brookhaven's National Synchrotron Light Source (NSLS). The NSLS is one of the world's most widely used scientific research facilities, hosting more than 2,500 guest researchers each year. The NSLS provides intense beams of infrared, ultraviole

  4. Lighting in Commercial Buildings

    U.S. Energy Information Administration (EIA) Indexed Site

    5.2 152.6 160.5 54.6 Assembly Health Care Lodging Office 0 20 40 60 80 100 120 140 160 180 Energy Information Administration Energy Consumption Series: Lighting in Commercial...

  5. Divalent metal nanoparticles

    E-Print Network [OSTI]

    DeVries, Gretchen Anne

    2008-01-01

    Metal nanoparticles hold promise for many scientific and technological applications, such as chemical and biological sensors, vehicles for drug delivery, and subdiffraction limit waveguides. To fabricate such devices, a ...

  6. Production of magnesium metal

    DOE Patents [OSTI]

    Blencoe, James G. (Harriman, TN); Anovitz, Lawrence M. (Knoxville, TN); Palmer, Donald A. (Oliver Springs, TN); Beard, James S. (Martinsville, VA)

    2012-04-10

    A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention also relates to the magnesium metal produced by the processes described herein.

  7. METALS DESIGN HANDBOOK DISCLAIMER

    Office of Scientific and Technical Information (OSTI)

    9 06 Revision 0 METALS DESIGN HANDBOOK DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States...

  8. Lithium metal reduction of plutonium oxide to produce plutonium metal

    DOE Patents [OSTI]

    Coops, Melvin S. (Livermore, CA)

    1992-01-01

    A method is described for the chemical reduction of plutonium oxides to plutonium metal by the use of pure lithium metal. Lithium metal is used to reduce plutonium oxide to alpha plutonium metal (alpha-Pu). The lithium oxide by-product is reclaimed by sublimation and converted to the chloride salt, and after electrolysis, is removed as lithium metal. Zinc may be used as a solvent metal to improve thermodynamics of the reduction reaction at lower temperatures. Lithium metal reduction enables plutonium oxide reduction without the production of huge quantities of CaO--CaCl.sub.2 residues normally produced in conventional direct oxide reduction processes.

  9. Solid state lighting component

    DOE Patents [OSTI]

    Yuan, Thomas; Keller, Bernd; Ibbetson, James; Tarsa, Eric; Negley, Gerald

    2010-10-26

    An LED component comprising an array of LED chips mounted on a planar surface of a submount with the LED chips capable of emitting light in response to an electrical signal. The LED chips comprise respective groups emitting at different colors of light, with each of the groups interconnected in a series circuit. A lens is included over the LED chips. Other embodiments can comprise thermal spreading structures included integral to the submount and arranged to dissipate heat from the LED chips.

  10. Solid state lighting component

    DOE Patents [OSTI]

    Keller, Bernd; Ibbetson, James; Tarsa, Eric; Negley, Gerald; Yuan, Thomas

    2012-07-10

    An LED component comprising an array of LED chips mounted on a planar surface of a submount with the LED chips capable of emitting light in response to an electrical signal. The LED chips comprise respective groups emitting at different colors of light, with each of the groups interconnected in a series circuit. A lens is included over the LED chips. Other embodiments can comprise thermal spreading structures included integral to the submount and arranged to dissipate heat from the LED chips.

  11. Light and Plants Plants use light to photosynthesize. Name two places that light can come from

    E-Print Network [OSTI]

    Koptur, Suzanne

    Light and Plants Plants use light to photosynthesize. Name two places that light can come from: 1 (CO2, a gas) from the air and turn it into SUGARS (food). This process is powered by energy from light plants) for energy. Photosynthetically Active Radiation (PAR) is a combination of red light and blue

  12. LED Lighting | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    focusing light in ways that are useful in homes and commercial settings. The light-emitting diode (LED) is one of today's most energy-efficient and rapidly-developing lighting...

  13. Energy Conservation in Industrial Lighting 

    E-Print Network [OSTI]

    Meharg, E.

    1979-01-01

    were identified. Savings in power and cost were quantified for typical examples as follows: Task lighting, high light source efficacy, high luminaire mounting height, efficient luminaires, surroundings painted a light color, regular luminaire cleaning...

  14. Higher order light propagation volumes

    E-Print Network [OSTI]

    Martin, Timothy Ly; Martin, Timothy Ly

    2012-01-01

    1.1 Introduction . . . . . . . . . 1.2 Light Propagation4.1.1 Injection of Virtual Point Lights and Geometryof the Stanford bunny, lit by an area light, rendered using

  15. Light as a Healing Mechanism

    E-Print Network [OSTI]

    Lingampalli, Nithya

    2013-01-01

    S. (1991). Meridians conduct light. Moskow: Raum and Zeit.the bod’ys absorption of light. Explore, 9(2), doi: https://01). The healing use of light and color. Health Care Design

  16. Lighting and the Bottom Line 

    E-Print Network [OSTI]

    Christensen, M.

    1981-01-01

    A discussion of the cost of light and how it relates to the cost of people. The new Illuminating Engineering Society recommended method of determining lighting levels will be explained. Also several ways of providing good lighting to increase...

  17. Molten metal reactors

    DOE Patents [OSTI]

    Bingham, Dennis N; Klingler, Kerry M; Turner, Terry D; Wilding, Bruce M

    2013-11-05

    A molten metal reactor for converting a carbon material and steam into a gas comprising hydrogen, carbon monoxide, and carbon dioxide is disclosed. The reactor includes an interior crucible having a portion contained within an exterior crucible. The interior crucible includes an inlet and an outlet; the outlet leads to the exterior crucible and may comprise a diffuser. The exterior crucible may contain a molten alkaline metal compound. Contained between the exterior crucible and the interior crucible is at least one baffle.

  18. Growth of metal and semiconductor nanostructures using localized photocatalysts

    SciTech Connect (OSTI)

    Shelnutt, John A; Wang, Zhongchun; Medforth, Craig J

    2006-03-08

    Our overall goal has been to understand and develop a light-driven approach to the controlled growth of novel metal and semiconductor nanostructures and nanomaterials. In this photochemical process, bio-inspired porphyrin-based photocatalysts reduce metal salts in aqueous solutions at ambient temperatures when exposed to visible light, providing metal nucleation and growth centers. The photocatalyst molecules are pre-positioned at the nanoscale to control the location of the deposition of metal and therefore the morphology of the nanostructures that are grown. Self-assembly, chemical confinement, and molecular templating are some of the methods we are using for nanoscale positioning of the photocatalyst molecules. When exposed to light, each photocatalyst molecule repeatedly reduces metal ions from solution, leading to deposition near the photocatalyst and ultimately the synthesis of new metallic nanostructures and nanostructured materials. Studies of the photocatalytic growth process and the resulting nanostructures address a number of fundamental biological, chemical, and environmental issues and draw on the combined nanoscience characterization and multi-scale simulation capabilities of the new DOE Center for Integrated Nanotechnologies at Sandia National Laboratories and the University of Georgia. Our main goals are to elucidate the processes involved in the photocatalytic growth of metal nanomaterials and provide the scientific basis for controlled nanosynthesis. The nanomaterials resulting from these studies have applications in nanoelectronics, photonics, sensors, catalysis, and micromechanical systems. Our specific goals for the past three years have been to understand the role of photocatalysis in the synthesis of dendritic metal (Pt, Pd, Au) nanostructures grown from aqueous surfactant solutions under ambient conditions and the synthesis of photocatalytic porphyrin nanostructures (e.g., nanotubes) as templates for fabrication of photo-active metal-composite nanodevices. The proposed nanoscience concentrates on two thematic research areas: (1) the creation of metal and semiconductor nanostructures and nanomaterials for realizing novel catalytic phenomena and quantum control, (2) understanding photocatalytic metal deposition processes at the nanoscale especially on photocatalytic porphyrin nanostructures such as nanotubes, and (3) the development and use of multi-scale, multi-phenomena theory and simulation for ionic self-assembly and catalytic processes.

  19. New Light Sources for Tomorrow's Lighting Designs 

    E-Print Network [OSTI]

    Krailo, D. A.

    1986-01-01

    and lighting systems. Table 2 shows the development of four-foot energy-saving retrofit lamps. By utilizing new cathode designed and different gas fills, 34-watt energy-saving lamps were developed that operate on existing rapid start ballasts and afford... of fluorescent lamps, two watts of system power are consumed in heating the lamp cath odes. The shedding of cathode heating wattage was the next lamp efficiency improvement to be introduced. One available sy tern dis connects the lamp cathodes from...

  20. Photochemical deterioration of the organic/metal contacts in organic optoelectronic devices

    SciTech Connect (OSTI)

    Wang Qi; Williams, Graeme; Aziz, Hany; Tsui Ting

    2012-09-15

    We study the effect of exposure to light on a wide range of organic/metal contacts that are commonly used in organic optoelectronic devices and found that irradiation by light in the visible and UV range results in a gradual deterioration in their electrical properties. This photo-induced contact degradation reduces both charge injection (i.e., from the metal to the organic layer) and charge extraction (i.e., from the organic layer to the metal). X-ray photoelectron spectroscopy (XPS) measurements reveal detectable changes in the interface characteristics after irradiation, indicating that the photo-degradation is chemical in nature. Changes in XPS characteristics after irradiation suggests a possible reduction in bonds associated with organic-metal complexes. Measurements of interfacial adhesion strength using the four-point flexure technique reveal a decrease in organic/metal adhesion in irradiated samples, consistent with a decrease in metal-organic bond density. The results shed the light on a new material degradation mechanism that appears to have a wide presence in organic/metal interfaces in general, and which likely plays a key role in limiting the stability of various organic optoelectronic devices such as organic light emitting devices, organic solar cells, and organic photo-detectors.

  1. Electrochemical nitridation of metal surfaces

    DOE Patents [OSTI]

    Wang, Heli; Turner, John A.

    2015-06-30

    Electrochemical nitridation of metals and the produced metals are disclosed. An exemplary method of electrochemical nitridation of metals comprises providing an electrochemical solution at low temperature. The method also comprises providing a three-electrode potentiostat system. The method also comprises stabilizing the three-electrode potentiostat system at open circuit potential. The method also comprises applying a cathodic potential to a metal.

  2. Lighting Design | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    as part of your whole-house design -- an approach for building an energy-efficient home. Indoor Lighting Design When designing indoor lighting for energy efficiency,...

  3. GATEWAY Demonstrations: LED Street Lighting

    SciTech Connect (OSTI)

    Cook, Tyson; Shackelford, Jordan; Pang, Terrance Pang

    2008-12-01

    This report summarizes an assessment project conducted to study the performance of light emitting diode (LED) luminaires in a street lighting application in San Francisco, CA.

  4. Interior Lighting Efficiency for Municipalities

    Broader source: Energy.gov [DOE]

    This webinar covered a basic understanding of lighting, different types of lamps and luminaries, importance of energy efficiency in lighting, and knowledge of where to find financial resources.

  5. 2010 US Lighting Market Characterization

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2010 U.S. Lighting Market Characterization January 2012 Prepared for: Solid-State Lighting Program Building Technologies Program Office of Energy Efficiency and Renewable Energy...

  6. Lighting Controls | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    fluorescent lighting fixtures rather than replace them. Dimmers and LEDs Some light-emitting diode (LED) lightbulbs can be used with dimmers. LED bulbs and fixtures must be...

  7. Thermally tolerant multilayer metal membrane

    DOE Patents [OSTI]

    Dye, Robert C. (Los Alamos, NM); Snow, Ronny C. (Los Alamos, NM)

    2001-01-01

    A composite metal membrane including a first metal layer of a Group IVB or Group VB metal sandwiched between two layers of a Group VIIIB metal selected from the group consisting of palladium, platinum, nickel, rhodium, iridium, cobalt, and alloys thereof, and a non-continuous layer of a metal chalcogenide upon one layer of the Group VIIIB metal is disclosed together with a process for the recovery of hydrogen from a gaseous mixture using such a composite membrane and a process for forming such a composite metal membrane.

  8. Project Profile: Halide and Oxy-Halide Eutectic Systems for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy Bills andOrderNATIONALofDefine ReviewImpactDepartment of

  9. IEEE TRANSACTIONS ON NANOTECHNOLOGY, VOL. 5, NO. 3, MAY 2006 291 Resonant Light Transmission Through a Nanohole

    E-Print Network [OSTI]

    Brolo, Alexandre G.

    IEEE TRANSACTIONS ON NANOTECHNOLOGY, VOL. 5, NO. 3, MAY 2006 291 Resonant Light Transmission Through a Nanohole in a Metal Film R. Gordon, Member, IEEE, L. Kiran Swaroop Kumar, and Alexandre G. Brolo

  10. Peroxotitanates for Biodelivery of Metals

    SciTech Connect (OSTI)

    Hobbs, David; Elvington, M.

    2009-02-11

    Metal-based drugs are largely undeveloped in pharmacology. One limiting factor is the systemic toxicity of metal-based compounds. A solid-phase, sequestratable delivery agent for local delivery of metals could reduce systemic toxicity, facilitating new drug development in this nascent area. Amorphous peroxotitanates (APT) are ion exchange materials with high affinity for several heavy metal ions, and have been proposed to deliver or sequester metal ions in biological contexts. In the current study, we tested a hypothesis that APT are able to deliver metals or metal compounds to cells. We exposed fibroblasts (L929) or monocytes (THP1) to metal-APT materials for 72 h in vitro, then measured cellular mitochondrial activity (SDH-MTT method) to assess the biological impact of the metal-APT materials vs. metals or APT alone. APT alone did not significantly affect cellular mitochondrial activity, but all metal-APT materials suppressed the mitochondrial activity of fibroblasts (by 30-65% of controls). The concentration of metal-APT materials required to suppress cellular mitochondrial activity was below that required for metals alone, suggesting that simple extracellular release of the metals from the metal-APT materials was not the primary mechanism of mitochondrial suppression. In contrast to fibroblasts, no metal-APT material had a measurable effect on THP1 monocyte mitochondrial activity, despite potent suppression by metals alone. This latter result suggested that 'biodelivery' by metal-APT materials may be cell type-specific. Therefore, it appears that APT are plausible solid phase delivery agents of metals or metal compounds to some types of cells for potential therapeutic effect.

  11. Liquid metal thermal electric converter

    DOE Patents [OSTI]

    Abbin, Joseph P. (Albuquerque, NM); Andraka, Charles E. (Albuquerque, NM); Lukens, Laurance L. (Albuquerque, NM); Moreno, James B. (Albuquerque, NM)

    1989-01-01

    A liquid metal thermal electric converter which converts heat energy to electrical energy. The design of the liquid metal thermal electric converter incorporates a unique configuration which directs the metal fluid pressure to the outside of the tube which results in the structural loads in the tube to be compressive. A liquid metal thermal electric converter refluxing boiler with series connection of tubes and a multiple cell liquid metal thermal electric converter are also provided.

  12. Lighting affects appearance LightSource emits photons

    E-Print Network [OSTI]

    Jacobs, David

    1 Lighting affects appearance #12;2 LightSource emits photons Photons travel in a straight line). And then some reach the eye/camera. #12;3 Basic fact: Light is linear Double intensity of sources, double photons reaching eye. Turn on two lights, and photons reaching eye are same as sum of number when each

  13. Quasi light fields: extending the light field to coherent radiation

    E-Print Network [OSTI]

    Wornell, Gregory W.

    Quasi light fields: extending the light field to coherent radiation Anthony Accardi1,2 and Gregory light field, and for coherent radiation using electromagnetic field theory. We present a model of coherent image formation that strikes a balance between the utility of the light field

  14. Interior Light Level Measurements Appendix F -Interior Light Level Measurements

    E-Print Network [OSTI]

    Appendix F ­ Interior Light Level Measurements #12;F.1 Appendix F - Interior Light Level. A potential concern is that a lower VT glazing may increase electric lighting use to compensate for lost qualify and quantify a representative loss of daylighting, and therefore electric lighting use

  15. Demonstration Assessment of LED Roadway Lighting: Philadelphia...

    Office of Scientific and Technical Information (OSTI)

    LED Roadway Lighting: Philadelphia, PA Royer, Michael P.; Tuenge, Jason R.; Poplawski, Michael E. Roadway Lighting; Solid-state lighting; LED lighting; SSL; LED; GATEWAY Roadway...

  16. Lighting Principles and Terms | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Principles and Terms Lighting Principles and Terms Light quantity, energy consumption, and light quality are the basic principles of lighting. | Photo courtesy of

  17. Testimonials - Partnerships in LED Lighting - Philips Lumileds...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    LED Lighting - Philips Lumileds Lighting, LLC Testimonials - Partnerships in LED Lighting - Philips Lumileds Lighting, LLC Addthis An error occurred. Try watching this video on...

  18. Flip-chip light emitting diode with resonant optical microcavity

    SciTech Connect (OSTI)

    Gee, James M.; Bogart, Katherine H.A.; Fischer, Arthur J.

    2005-11-29

    A flip-chip light emitting diode with enhanced efficiency. The device structure employs a microcavity structure in a flip-chip configuration. The microcavity enhances the light emission in vertical modes, which are readily extracted from the device. Most of the rest of the light is emitted into waveguided lateral modes. Flip-chip configuration is advantageous for light emitting diodes (LEDs) grown on dielectric substrates (e.g., gallium nitride LEDs grown on sapphire substrates) in general due to better thermal dissipation and lower series resistance. Flip-chip configuration is advantageous for microcavity LEDs in particular because (a) one of the reflectors is a high-reflectivity metal ohmic contact that is already part of the flip-chip configuration, and (b) current conduction is only required through a single distributed Bragg reflector. Some of the waveguided lateral modes can also be extracted with angled sidewalls used for the interdigitated contacts in the flip-chip configuration.

  19. Light Quark Mass Reweighting

    E-Print Network [OSTI]

    Qi Liu; Norman H. Christ; Chulwoo Jung

    2012-06-01

    We present a systematic study of the effectiveness of light quark mass reweighting. This method allows a single lattice QCD ensemble, generated with a specific value of the dynamical light quark mass, to be used to determine results for other, nearby light dynamical quark masses. We study two gauge field ensembles generated with 2+1 flavors of dynamical domain wall fermions with light quark masses m_l=0.02 (m_\\pi=620 MeV) and m_l=0.01 (m_\\pi=420 MeV). We reweight each ensemble to determine results which could be computed directly from the other and check the consistency of the reweighted results with the direct results. The large difference between the 0.02 and 0.01 light quark masses suggests that this is an aggressive application of reweighting as can be seen from fluctuations in the magnitude of the reweighting factor by four orders of magnitude. Never-the-less, a comparison of the reweighed topological charge, average plaquette, residual mass, pion mass, pion decay constant, and scalar correlator between these two ensembles shows agreement well described by the statistical errors. The issues of the effective number of configurations and finite sample size bias are discussed. An examination of the topological charge distribution implies that it is more favorable to reweight from heavier mass to lighter quark mass.

  20. High-Temperature Zirconia Oxygen Sensor with Sealed Metal/Metal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference...

  1. Alkali metal ionization detector

    DOE Patents [OSTI]

    Bauerle, James E. (Plum Borough, PA); Reed, William H. (Monroeville, PA); Berkey, Edgar (Murrysville, PA)

    1978-01-01

    Variations in the conventional filament and collector electrodes of an alkali metal ionization detector, including the substitution of helical electrode configurations for either the conventional wire filament or flat plate collector; or, the substitution of a plurality of discrete filament electrodes providing an in situ capability for transferring from an operationally defective filament electrode to a previously unused filament electrode without removing the alkali metal ionization detector from the monitored environment. In particular, the helical collector arrangement which is coaxially disposed about the filament electrode, i.e. the thermal ionizer, provides an improved collection of positive ions developed by the filament electrode. The helical filament design, on the other hand, provides the advantage of an increased surface area for ionization of alkali metal-bearing species in a monitored gas environment as well as providing a relatively strong electric field for collecting the ions at the collector electrode about which the helical filament electrode is coaxially positioned. Alternatively, both the filament and collector electrodes can be helical. Furthermore, the operation of the conventional alkali metal ionization detector as a leak detector can be simplified as to cost and complexity, by operating the detector at a reduced collector potential while maintaining the sensitivity of the alkali metal ionization detector adequate for the relatively low concentration of alkali vapor and aerosol typically encountered in leak detection applications.

  2. Are Light Gluinos Dead?

    E-Print Network [OSTI]

    Glennys R. Farrar

    1997-07-25

    Not yet. ALEPH's recent exclusion limit employs an aggressive determination of theoretical uncertainties using a simplified application of the Bayesian method. The validity of their analysis can be evaluated by its further implications, such as contradicting the existence a b quark and requiring relations between hadronic event-shape observables which are not observed. Traditional error estimation methods result in a much larger estimate for the theoretical uncertainties. This puts the ALEPH and also Csikor-Fodor limits at the $\\sim 1~ \\sigma$ level for the very light gluino scenario. A recent astrophysical result implies direct searches will be more difficult than previously anticipated, adding to the importance of reducing the QCD uncertainty in predictions sensitive to indirect effects of light gluinos. Some possible indications in favor of a light gluino are noted.

  3. Light harvesting arrays

    DOE Patents [OSTI]

    Lindsey, Jonathan S. (Raleigh, NC)

    2002-01-01

    A light harvesting array useful for the manufacture of devices such as solar cells comprises: (a) a first substrate comprising a first electrode; and (b) a layer of light harvesting rods electrically coupled to the first electrode, each of the light harvesting rods comprising a polymer of Formula I: X.sup.1.paren open-st.X.sup.m+1).sub.m (I) wherein m is at least 1, and may be from two, three or four to 20 or more; X.sup.1 is a charge separation group (and preferably a porphyrinic macrocycle, which may be one ligand of a double-decker sandwich compound) having an excited-state of energy equal to or lower than that of X.sup.2, and X.sup.2 through X.sup.m+1 are chromophores (and again are preferably porphyrinic macrocycles).

  4. Pupillary efficient lighting system

    DOE Patents [OSTI]

    Berman, Samuel M. (San Francisco, CA); Jewett, Don L. (Mill Valley, CA)

    1991-01-01

    A lighting system having at least two independent lighting subsystems each with a different ratio of scotopic illumination to photopic illumination. The radiant energy in the visible region of the spectrum of the lighting subsystems can be adjusted relative to each other so that the total scotopic illumination of the combined system and the total photopic illumination of the combined system can be varied independently. The dilation or contraction of the pupil of an eye is controlled by the level of scotopic illumination and because the scotopic and photopic illumination can be separately controlled, the system allows the pupil size to be varied independently of the level of photopic illumination. Hence, the vision process can be improved for a given level of photopic illumination.

  5. Sneaky light stop

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Eifert, Till; Nachman, Benjamin

    2015-02-20

    A light supersymmetric top quark partner (stop) with a mass nearly degenerate with that of the standard model (SM) top quark can evade direct searches. The precise measurement of SM top properties such as the cross-section has been suggested to give a handle for this ‘stealth stop’ scenario. We present an estimate of the potential impact a light stop may have on top quark mass measurements. The results indicate that certain light stop models may induce a bias of up to a few GeV, and that this effect can hide the shift in, and hence sensitivity from, cross-section measurements. Duemore »to the different initial states, the size of the bias is slightly different between the LHC and the Tevatron. The studies make some simplifying assumptions for the top quark measurement technique, and are based on truth-level samples.« less

  6. Light emitting ceramic device

    DOE Patents [OSTI]

    Valentine, Paul; Edwards, Doreen D.; Walker, Jr., William John; Slack, Lyle H.; Brown, Wayne Douglas; Osborne, Cathy; Norton, Michael; Begley, Richard

    2010-05-18

    A light-emitting ceramic based panel, hereafter termed "electroceramescent" panel, is herein claimed. The electroceramescent panel is formed on a substrate providing mechanical support as well as serving as the base electrode for the device. One or more semiconductive ceramic layers directly overlay the substrate, and electrical conductivity and ionic diffusion are controlled. Light emitting regions overlay the semiconductive ceramic layers, and said regions consist sequentially of a layer of a ceramic insulation layer and an electroluminescent layer, comprised of doped phosphors or the equivalent. One or more conductive top electrode layers having optically transmissive areas overlay the light emitting regions, and a multi-layered top barrier cover comprising one or more optically transmissive non-combustible insulation layers overlay said top electrode regions.

  7. Radioluminescent lighting technology

    SciTech Connect (OSTI)

    Not Available

    1990-01-01

    The glow-in-the-dark stereotype that characterizes the popular image of nuclear materials is not accidental. When the French scientist, Henri Becquerel, first discovered radioactivity in 1896, he was interested in luminescence. Radioluminescence, the production of light from a mixture of energetic and passive materials, is probably the oldest practical application of the unstable nucleus. Tritium-based radioluminescent lighting, in spite of the biologically favorable character of the gaseous tritium isotope, was included in the general tightening of environmental and safety regulations. Tritium light manufacturers would have to meet two fundamental conditions: (1) The benefit clearly outweighed the risk, to the extent that even the perceived risk of a skeptical public would be overcome. (2) The need was significant enough that the customer/user would be willing and able to afford the cost of regulation that was imposed both in the manufacture, use and eventual disposal of nuclear materials. In 1981, researchers at Oak Ridge National Laboratory were investigating larger radioluminescent applications using byproduct nuclear material such as krypton-85, as well as tritium. By 1982, it appeared that large source, (100 Curies or more) tritium gas tube, lights might be useful for marking runways and drop zones for military operations and perhaps even special civilian aviation applications. The successful development of this idea depended on making the light bright enough and demonstrating that large gas tube sources could be used and maintained safely in the environment. This successful DOE program is now in the process of being completed and closed-out. Working closely with the tritium light industry, State governments and other Federal agencies, the basic program goals have been achieved. This is a detailed report of what they have learned, proven, and discovered. 91 refs., 29 figs., 5 tabs. (JF)

  8. Fluorination of the cyanogen halides 

    E-Print Network [OSTI]

    Ward, Raymond Anthony

    1960-01-01

    link age. The trkjaer of cyanogen fluoride wae the product which wae laolated when fluorine wae eucceaefully reacted with the cyanogen group without breaking the carbon to nitrogen bond. An addition compound wae eetabllehed which correeponda to two... oliver fiuorfdea with one cyanogen iodide. ~lilt SIIII troll V. E. Cosslett reported th? preparation and character- laatlon of cyanogen l'luorlde ln I93I . Qther lnvestlgstore, l using Cosaiett~s method failed te prepare cyanogen fluoride Variations...

  9. Method for locating metallic nitride inclusions in metallic alloy ingots

    DOE Patents [OSTI]

    White, Jack C. (Albany, OR); Traut, Davis E. (Corvallis, OR); Oden, Laurance L. (Albany, OR); Schmitt, Roman A. (Corvallis, OR)

    1992-01-01

    A method of determining the location and history of metallic nitride and/or oxynitride inclusions in metallic melts. The method includes the steps of labeling metallic nitride and/or oxynitride inclusions by making a coreduced metallic-hafnium sponge from a mixture of hafnium chloride and the chloride of a metal, reducing the mixed chlorides with magnesium, nitriding the hafnium-labeled metallic-hafnium sponge, and seeding the sponge to be melted with hafnium-labeled nitride inclusions. The ingots are neutron activated and the hafnium is located by radiometric means. Hafnium possesses exactly the proper metallurgical and radiochemical properties for this use.

  10. Light is Heavy

    E-Print Network [OSTI]

    van der Mark, M B

    2015-01-01

    Einstein's relativity theory appears to be very accurate, but at times equally puzzling. On the one hand, electromagnetic radiation must have zero rest mass in order to propagate at the speed of light, but on the other hand, since it definitely carries momentum and energy, it has non-zero inertial mass. Hence, by the principle of equivalence, it must have non-zero gravitational mass, and so, light must be heavy. In this paper, no new results will be derived, but a possibly surprising perspective on the above paradox is given.

  11. Metal-optic and Plasmonic Semiconductor-based Nanolasers

    E-Print Network [OSTI]

    Lakhani, Amit

    2012-01-01

    of Metals . . . . . . . . . . . . . . . . . . . . . . .coupled Metal-optic Nanocavities . . . . . . . . . . . . . .dependent quality factors Q metal for good conduc- tors.

  12. Large area, surface discharge pumped, vacuum ultraviolet light source

    DOE Patents [OSTI]

    Sze, Robert C. (Santa Fe, NM); Quigley, Gerard P. (Los Alamos, NM)

    1996-01-01

    Large area, surface discharge pumped, vacuum ultraviolet (VUV) light source. A contamination-free VUV light source having a 225 cm.sup.2 emission area in the 240-340 nm region of the electromagnetic spectrum with an average output power in this band of about 2 J/cm.sup.2 at a wall-plug efficiency of approximately 5% is described. Only ceramics and metal parts are employed in this surface discharge source. Because of the contamination-free, high photon energy and flux, and short pulse characteristics of the source, it is suitable for semiconductor and flat panel display material processing.

  13. Large area, surface discharge pumped, vacuum ultraviolet light source

    DOE Patents [OSTI]

    Sze, R.C.; Quigley, G.P.

    1996-12-17

    Large area, surface discharge pumped, vacuum ultraviolet (VUV) light source is disclosed. A contamination-free VUV light source having a 225 cm{sup 2} emission area in the 240-340 nm region of the electromagnetic spectrum with an average output power in this band of about 2 J/cm{sup 2} at a wall-plug efficiency of approximately 5% is described. Only ceramics and metal parts are employed in this surface discharge source. Because of the contamination-free, high photon energy and flux, and short pulse characteristics of the source, it is suitable for semiconductor and flat panel display material processing. 3 figs.

  14. Hard metal composition

    DOE Patents [OSTI]

    Sheinberg, Haskell (Los Alamos, NM)

    1986-01-01

    A composition of matter having a Rockwell A hardness of at least 85 is formed from a precursor mixture comprising between 3 and 10 weight percent boron carbide and the remainder a metal mixture comprising from 70 to 90 percent tungsten or molybdenum, with the remainder of the metal mixture comprising nickel and iron or a mixture thereof. The composition has a relatively low density of between 7 to 14 g/cc. The precursor is preferably hot pressed to yield a composition having greater than 100% of theoretical density.

  15. Hard metal composition

    DOE Patents [OSTI]

    Sheinberg, H.

    1983-07-26

    A composition of matter having a Rockwell A hardness of at least 85 is formed from a precursor mixture comprising between 3 and 10 wt % boron carbide and the remainder a metal mixture comprising from 70 to 90% tungsten or molybdenum, with the remainder of the metal mixture comprising nickel and iron or a mixture thereof. The composition has a relatively low density of between 7 and 14 g/cc. The precursor is preferably hot pressed to yield a composition having greater than 100% of theoretical density.

  16. Metallic carbon materials

    DOE Patents [OSTI]

    Cohen, Marvin Lou (Berkeley, CA); Crespi, Vincent Henry (Darien, IL); Louie, Steven Gwon Sheng (Berkeley, CA); Zettl, Alexander Karlwalter (Kensington, CA)

    1999-01-01

    Novel metallic forms of planar carbon are described, as well as methods of designing and making them. Nonhexagonal arrangements of carbon are introduced into a graphite carbon network essentially without destroying the planar structure. Specifically a form of carbon comprising primarily pentagons and heptagons, and having a large density of states at the Fermi level is described. Other arrangements of pentagons and heptagons that include some hexagons, and structures incorporating squares and octagons are additionally disclosed. Reducing the bond angle symmetry associated with a hexagonal arrangement of carbons increases the likelihood that the carbon material will have a metallic electron structure.

  17. Fast Rotation vs. Metallicity

    E-Print Network [OSTI]

    Ronaldo Levenhagen; Nelson Vani Leister; Juan Zorec; Yves Fremat

    2005-09-07

    Fast rotation seems to be the major factor to trigger the Be phenomenon. Surface fast rotation can be favored by initial formation conditions such as metal abundance. Models of fast rotating atmospheres and evolutionary tracks are used to determine the stellar fundamental parameters of 120 Be stars situated in spatially well-separated regions to imply there is between them some gradient of metallicity. We study the effects of the incidence of this gradient on the nature of the studied stars as fast rotators.

  18. Catalysis Without Precious Metals

    SciTech Connect (OSTI)

    Bullock, R. Morris

    2010-11-01

    Written for chemists in industry and academia, this ready reference and handbook summarizes recent progress in the development of new catalysts that do not require precious metals. The research thus presented points the way to how new catalysts may ultimately supplant the use of precious metals in some types of reactions, while highlighting the remaining challenges. This material is based upon work supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the US Department of Energy, Office of Science, Office of Basic Energy Sciences.

  19. Metal alloy identifier

    DOE Patents [OSTI]

    Riley, William D. (Avondale, MD); Brown, Jr., Robert D. (Avondale, MD)

    1987-01-01

    To identify the composition of a metal alloy, sparks generated from the alloy are optically observed and spectrographically analyzed. The spectrographic data, in the form of a full-spectrum plot of intensity versus wavelength, provide the "signature" of the metal alloy. This signature can be compared with similar plots for alloys of known composition to establish the unknown composition by a positive match with a known alloy. An alternative method is to form intensity ratios for pairs of predetermined wavelengths within the observed spectrum and to then compare the values of such ratios with similar values for known alloy compositions, thereby to positively identify the unknown alloy composition.

  20. Metal-assisted chemical etch porous silicon formation method

    DOE Patents [OSTI]

    Li, Xiuling; Bohn, Paul W.; Sweedler, Jonathan V.

    2004-09-14

    A thin discontinuous layer of metal such as Au, Pt, or Au/Pd is deposited on a silicon surface. The surface is then etched in a solution including HF and an oxidant for a brief period, as little as a couple seconds to one hour. A preferred oxidant is H.sub.2 O.sub.2. Morphology and light emitting properties of porous silicon can be selectively controlled as a function of the type of metal deposited, Si doping type, silicon doping level, and/or etch time. Electrical assistance is unnecessary during the chemical etching of the invention, which may be conducted in the presence or absence of illumination.

  1. Reductive precipitation of metals photosensitized by tin and antimony porphyrins

    DOE Patents [OSTI]

    Shelnutt, John A.; Gong, Weiliang; Abdelouas, Abdesselam; Lutze, Werner

    2003-09-30

    A method for reducing metals using a tin or antimony porphyrin by forming an aqueous solution of a tin or antimony porphyrin, an electron donor, such as ethylenediaminetetraaceticacid, triethylamine, triethanolamine, and sodium nitrite, and at least one metal compound selected from a uranium-containing compound, a mercury-containing compound, a copper-containing compound, a lead-containing compound, a gold-containing compound, a silver-containing compound, and a platinum-containing compound through irradiating the aqueous solution with light.

  2. Solid State Lighting

    SciTech Connect (OSTI)

    Hastbacka, Mildred; Dieckmann, John; Bouza, Antonio

    2013-03-30

    The article discusses solid state lighting technologies. This topic was covered in two previous ASHRAE Journal columns (2010). This article covers advancements in technologies and the associated efficacies. The life-cycle, energy savings and market potential of these technologies are addressed as well.

  3. Fabricated Metals (2010 MECS) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fabricated Metals (2010 MECS) Fabricated Metals (2010 MECS) Manufacturing Energy and Carbon Footprint for Fabricated Metals Sector (NAICS 332) Energy use data source: 2010 EIA MECS...

  4. Locating experiential richness in doom metal

    E-Print Network [OSTI]

    Piper, Jonathan

    2013-01-01

    as Trouble) (1984), Metal Blade. Witchfinder General.Death Penalty (1982), Heavy Metal Records.the Balinese Death/ Thrash Metal Scene. ” Popular Music 22,

  5. Shaping metal nanocrystals through epitaxial seeded growth

    E-Print Network [OSTI]

    Habas, Susan E.; Lee, Hyunjoo; Radmilovic, Velimir; Somorjai, Gabor A.; Yang, Peidong

    2008-01-01

    Structural Evolution in Metal Oxide/Semiconductor Colloidalasymmetric one-sided metal-tipped semiconductor nanocrystalGrowth of Magnetic-Metal- Functionalized Semiconductor Oxide

  6. Metal working lubricant compositions

    SciTech Connect (OSTI)

    Andress, H.J.; Davis, R.H.; Schick, J.W.

    1981-08-11

    A lubricant concentrate for use in metal processing comprises a sulfur compound such as a sulfurized olefin or sulfurized mineral oil and an ester prepared from a fatty acid having 12 to 40 carbon atoms or the dimer thereof or a polyalkenylsuccinic acid or anhydride and a hydroxyl-containing amine.

  7. Ductile transplutonium metal alloys

    DOE Patents [OSTI]

    Conner, William V. (Boulder, CO)

    1983-01-01

    Alloys of Ce with transplutonium metals such as Am, Cm, Bk and Cf have properties making them highly suitable as sources of the transplutonium element, e.g., for use in radiation detector technology or as radiation sources. The alloys are ductile, homogeneous, easy to prepare and have a fairly high density.

  8. Ductile transplutonium metal alloys

    DOE Patents [OSTI]

    Conner, W.V.

    1981-10-09

    Alloys of Ce with transplutonium metals such as Am, Cm, Bk and Cf have properties making them highly suitable as souces of the transplutonium element, e.g., for use in radiation detector technology or as radiation sources. The alloys are ductile, homogeneous, easy to prepare and have a fairly high density.

  9. The erosion of metals

    E-Print Network [OSTI]

    Andrews, David Richard

    1980-10-21

    The study of the erosion of metallic surfaces by solid particles has been an area of dispute recently (1980) especially concerning the importance of target melting as a mechanism for the removal of material. In addition, erosion by particles at a...

  10. Light-harvesting materials: Soft support for energy conversion

    SciTech Connect (OSTI)

    Stolley, Ryan M.; Helm, Monte L.

    2014-11-10

    To convert solar energy into viable fuel sources, coupling light-harvesting materials to catalysts is a critical challenge. Now, coupling between an organic supramolecular hydrogel and a non precious metal catalyst has been demonstrated to be effective for photocatalytic H2 production. Ryan M. Stolley and Monte L. Helm are at Pacific Northwest National Laboratory (PNNL), Richland, WA, USA 99352. PNNL is operated by Battelle for the US Department of Energy. e-mail: Monte.Helm@pnnl.gov

  11. Method of producing adherent metal oxide coatings on metallic surfaces

    DOE Patents [OSTI]

    Lane, Michael H. (Clifton Park, NY); Varrin, Jr., Robert D. (McLean, VA)

    2001-01-01

    Provided is a process of producing an adherent synthetic corrosion product (sludge) coating on metallic surfaces. The method involves a chemical reaction between a dry solid powder mixture of at least one reactive metal oxide with orthophosphoric acid to produce a coating in which the particles are bound together and the matrix is adherent to the metallic surface.

  12. Mechanically flexible organic electroluminescent device with directional light emission

    DOE Patents [OSTI]

    Duggal, Anil Raj; Shiang, Joseph John; Schaepkens, Marc

    2005-05-10

    A mechanically flexible and environmentally stable organic electroluminescent ("EL") device with directional light emission comprises an organic EL member disposed on a flexible substrate, a surface of which is coated with a multilayer barrier coating which includes at least one sublayer of a substantially transparent organic polymer and at least one sublayer of a substantially transparent inorganic material. The device includes a reflective metal layer disposed on the organic EL member opposite to the substrate. The reflective metal layer provides an increased external quantum efficiency of the device. The reflective metal layer and the multilayer barrier coating form a seal around the organic EL member to reduce the degradation of the device due to environmental elements.

  13. 9 Metal to Non-metal Transitions in Solids and on Surfaces studied using Photoemission Spectroscopy

    E-Print Network [OSTI]

    Redner, Sidney

    9 Metal to Non-metal Transitions in Solids and on Surfaces studied using Photoemission Spectroscopy of the electrical properties of a material between those of a metal and those of a non-metal (be it semiconducting metal to non-metal transitions. (Thephrase `metal to non-metal transition' is used in this paper

  14. Electroless metal plating of plastics

    DOE Patents [OSTI]

    Krause, L.J.

    1982-09-20

    Process for plating main group metals on aromatic polymers is carried out by the use of a nonaqueous solution of a salt of an alkali metal in a positive valence state and a main group metal in a negative valence state with contact between the solution and polymer providing a redox reaction causing the deposition of the main group metal and the reduction of the polymer. Products from the process exhibit useful decorative and electrical properties.

  15. Electroless metal plating of plastics

    DOE Patents [OSTI]

    Krause, Lawrence J. (Chicago, IL)

    1984-01-01

    Process for plating main group metals on aromatic polymers is carried out by the use of a nonaqueous solution of a salt of an alkali metal in a positive valence state and a main group metal in a negative valence state with contact between the solution and polymer providing a redox reaction causing the deposition of the main group metal and the reduction of the polymer. Products from the process exhibit useful decorative and electrical properties.

  16. Electroless metal plating of plastics

    DOE Patents [OSTI]

    Krause, Lawrence J. (Chicago, IL)

    1986-01-01

    Process for plating main group metals on aromatic polymers is carried out by the use of a nonaqueous solution of a salt of an alkali metal in a positive valence state and a main group metal in a negative valence state with contact between the solution and polymer providing a redox reaction causing the deposition of the main group metal and the reduction of the polymer. Products from the process exhibit useful decorative and electrical properties.

  17. Upgrading platform using alkali metals

    SciTech Connect (OSTI)

    Gordon, John Howard

    2014-09-09

    A process for removing sulfur, nitrogen or metals from an oil feedstock (such as heavy oil, bitumen, shale oil, etc.) The method involves reacting the oil feedstock with an alkali metal and a radical capping substance. The alkali metal reacts with the metal, sulfur or nitrogen content to form one or more inorganic products and the radical capping substance reacts with the carbon and hydrogen content to form a hydrocarbon phase. The inorganic products may then be separated out from the hydrocarbon phase.

  18. Methods of recovering alkali metals

    DOE Patents [OSTI]

    Krumhansl, James L; Rigali, Mark J

    2014-03-04

    Approaches for alkali metal extraction, sequestration and recovery are described. For example, a method of recovering alkali metals includes providing a CST or CST-like (e.g., small pore zeolite) material. The alkali metal species is scavenged from the liquid mixture by the CST or CST-like material. The alkali metal species is extracted from the CST or CST-like material.

  19. Demonstration Assessment of Light-Emitting Diode Roadway Lighting...

    Office of Scientific and Technical Information (OSTI)

    New York Citation Details In-Document Search Title: Demonstration Assessment of Light-Emitting Diode Roadway Lighting on the FDR Drive in New York, New York This a report about a...

  20. Light Dance : light and the nature of body movement

    E-Print Network [OSTI]

    Riskin, Seth

    1989-01-01

    Light Dance is a conscious transfiguration of the body, its movement and the encompassing space; a transposition of matter to light exalted in the dance. This corresponds to the conceptualized spirit of the performer whose ...

  1. Making fuel from light: Argonne research sheds light on photosynthesis...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Making fuel from light: Argonne research sheds light on photosynthesis and creation of solar fuel By Jo Napolitano * September 1, 2015 Tweet EmailPrint Refined by nature over a...

  2. Inert electrode containing metal oxides, copper and noble metal

    DOE Patents [OSTI]

    Ray, Siba P. (Murrysville, PA); Woods, Robert W. (New Kensington, PA); Dawless, Robert K. (Monroeville, PA); Hosler, Robert B. (Sarver, PA)

    2001-01-01

    A cermet composite material is made by treating at an elevated temperature a mixture comprising a compound of iron and a compound of at least one other metal, together with an alloy or mixture of copper and a noble metal. The alloy or mixture preferably comprises particles having an interior portion containing more copper than noble metal and an exterior portion containing more noble metal than copper. The noble metal is preferably silver. The cermet composite material preferably includes alloy phase portions and a ceramic phase portion. At least part of the ceramic phase portion preferably has a spinel structure.

  3. Inert electrode containing metal oxides, copper and noble metal

    DOE Patents [OSTI]

    Ray, Siba P. (Murrysville, PA); Woods, Robert W. (New Kensington, PA); Dawless, Robert K. (Monroeville, PA); Hosler, Robert B. (Sarver, PA)

    2000-01-01

    A cermet composite material is made by treating at an elevated temperature a mixture comprising a compound of iron and a compound of at least one other metal, together with an alloy or mixture of copper and a noble metal. The alloy or mixture preferably comprises particles having an interior portion containing more copper than noble metal and an exterior portion containing more noble metal than copper. The noble metal is preferably silver. The cermet composite material preferably includes alloy phase portions and a ceramic phase portion. At least part of the ceramic phase portion preferably has a spinel structure.

  4. Fusion pumped light source

    DOE Patents [OSTI]

    Pappas, Daniel S. (Los Alamos, NM)

    1989-01-01

    Apparatus is provided for generating energy in the form of light radiation. A fusion reactor is provided for generating a long, or continuous, pulse of high-energy neutrons. The neutron flux is coupled directly with the lasing medium. The lasing medium includes a first component selected from Group O of the periodic table of the elements and having a high inelastic scattering cross section. Gamma radiation from the inelastic scattering reactions interacts with the first component to excite the first component, which decays by photon emission at a first output wavelength. The first output wavelength may be shifted to a second output wavelength using a second liquid component responsive to the first output wavelength. The light outputs may be converted to a coherent laser output by incorporating conventional optics adjacent the laser medium.

  5. Scattering Of Light Nuclei

    SciTech Connect (OSTI)

    Quaglioni, S; Navratil, P; Roth, R

    2009-12-15

    The exact treatment of nuclei starting from the constituent nucleons and the fundamental interactions among them has been a long-standing goal in nuclear physics. Above all nuclear scattering and reactions, which require the solution of the many-body quantum-mechanical problem in the continuum, represent an extraordinary theoretical as well as computational challenge for ab initio approaches.We present a new ab initio many-body approach which derives from the combination of the ab initio no-core shell model with the resonating-group method [4]. By complementing a microscopic cluster technique with the use of realistic interactions, and a microscopic and consistent description of the nucleon clusters, this approach is capable of describing simultaneously both bound and scattering states in light nuclei. We will discuss applications to neutron and proton scattering on sand light p-shell nuclei using realistic nucleon-nucleon potentials, and outline the progress toward the treatment of more complex reactions.

  6. OLEDS FOR GENERAL LIGHTING

    SciTech Connect (OSTI)

    Anil Duggal; Don Foust; Chris Heller; Bill Nealon; Larry Turner; Joe Shiang; Nick Baynes; Tim Butler; Nalin Patel

    2004-02-29

    The goal of this program was to reduce the long term technical risks that were keeping the lighting industry from embracing and developing organic light-emitting diode (OLED) technology for general illumination. The specific goal was to develop OLEDs for lighting to the point where it was possible to demonstrate a large area white light panel with brightness and light quality comparable to a fluorescence source and with an efficacy comparable to that of an incandescent source. it was recognized that achieving this would require significant advances in three area: (1) the improvement of white light quality for illumination, (2) the improvement of OLED energy efficiency at high brightness, and (3) the development of cost-effective large area fabrication techniques. The program was organized such that, each year, a ''deliverable'' device would be fabricated which demonstrated progress in one or more of the three critical research areas. In the first year (2001), effort concentrated on developing an OLED capable of generating high illumination-quality white light. Ultimately, a down-conversion method where a blue OLED was coupled with various down-conversion layers was chosen. Various color and scattering models were developed to aid in material development and device optimization. The first year utilized this approach to deliver a 1 inch x 1 inch OLED with higher illumination-quality than available fluorescent sources. A picture of this device is shown and performance metrics are listed. To their knowledge, this was the first demonstration of true illumination-quality light from an OLED. During the second year, effort concentrated on developing a scalable approach to large area devices. A novel device architecture consisting of dividing the device area into smaller elements that are monolithically connected in series was developed. In the course of this development, it was realized that, in addition to being scalable, this approach made the device tolerant to the most common OLED defect--electrical shorts. This architecture enabled the fabrication of a 6 inch x 6 inch OLED deliverable for 2002. A picture of this deliverable is shown and the performance metrics are listed. At the time, this was the highest efficiency, highest lumen output illumination-quality OLED in existence. The third year effort concentrated on improving the fabrication yield of the 6 inch x 6 inch devices and improving the underlying blue device efficiency. An efficiency breakthrough was achieved through the invention of a new device structure such that now 15 lumen per watt devices could be fabricated. A 2 feet x 2 feet OLED panel consisting of sixteen 6 inch x 6 inch high efficiency devices tiled together was then fabricated. Pictures of this panel are shown with performance metrics listed. This panel met all project objectives and was the final deliverable for the project. It is now the highest efficiency, highest lumen output, illumination-quality OLED in existence.

  7. Solid State Lighting Reliability

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy BillsNo.Hydrogen4EnergySolid State Lighting Reliability 2014 Building

  8. LED Lighting | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    are directional, focusing light in ways that are useful in homes and commercial settings. The light-emitting diode (LED) is one of today's most energy-efficient and...

  9. An International Year of Light

    E-Print Network [OSTI]

    Faure, Claudie

    of light-based technologies for the equitable development of global society. The project received, renewable energy and energy efficiency, and for PROSPECTUS An International Year of Light Science ­ Technology ­ Nature ­ Culture ­ Development

  10. FLUIDIC: Metal Air Recharged

    SciTech Connect (OSTI)

    Friesen, Cody

    2014-03-07

    Fluidic, with the help of ARPA-E funding, has developed and deployed the world's first proven high cycle life metal air battery. Metal air technology, often used in smaller scale devices like hearing aids, has the lowest cost per electron of any rechargeable battery storage in existence. Deploying these batteries for grid reliability is competitive with pumped hydro installations while having the advantages of a small footprint. Fluidic's battery technology allows utilities and other end users to store intermittent energy generated from solar and wind, as well as maintain reliable electrical delivery during power outages. The batteries are manufactured in the US and currently deployed to customers in emerging markets for cell tower reliability. As they continue to add customers, they've gained experience and real world data that will soon be leveraged for US grid reliability.

  11. FLUIDIC: Metal Air Recharged

    ScienceCinema (OSTI)

    Friesen, Cody

    2014-04-02

    Fluidic, with the help of ARPA-E funding, has developed and deployed the world's first proven high cycle life metal air battery. Metal air technology, often used in smaller scale devices like hearing aids, has the lowest cost per electron of any rechargeable battery storage in existence. Deploying these batteries for grid reliability is competitive with pumped hydro installations while having the advantages of a small footprint. Fluidic's battery technology allows utilities and other end users to store intermittent energy generated from solar and wind, as well as maintain reliable electrical delivery during power outages. The batteries are manufactured in the US and currently deployed to customers in emerging markets for cell tower reliability. As they continue to add customers, they've gained experience and real world data that will soon be leveraged for US grid reliability.

  12. Spray casting of metallic preforms

    DOE Patents [OSTI]

    Flinn, John E. (Idaho Falls, ID); Burch, Joseph V. (Shelley, ID); Sears, James W. (Niskayuna, NY)

    2000-01-01

    A metal alloy is melted in a crucible and ejected from the bottom of the crucible as a descending stream of molten metal. The descending stream is impacted with a plurality of primary inert gas jets surrounding the molten metal stream to produce a plume of atomized molten metal droplets. An inert gas is blown onto a lower portion of the plume with a plurality of auxiliary inert gas jets to deflect the plume into a more restricted pattern of high droplet density, thereby substantially eliminating unwanted overspray and resulting wasted material. The plume is projected onto a moving substrate to form a monolithic metallic product having generally parallel sides.

  13. Photodetector with enhanced light absorption

    DOE Patents [OSTI]

    Kane, James (Lawrenceville, NJ)

    1985-01-01

    A photodetector including a light transmissive electrically conducting layer having a textured surface with a semiconductor body thereon. This layer traps incident light thereby enhancing the absorption of light by the semiconductor body. A photodetector comprising a textured light transmissive electrically conducting layer of SnO.sub.2 and a body of hydrogenated amorphous silicon has a conversion efficiency about fifty percent greater than that of comparative cells. The invention also includes a method of fabricating the photodetector of the invention.

  14. Webinar: Fuel Cell Mobile Lighting

    Broader source: Energy.gov [DOE]

    Video recording of the Fuel Cell Technologies Office webinar, Fuel Cell Mobile Lighting, originally presented on November 13, 2012.

  15. Faster than Light Quantum Communication

    E-Print Network [OSTI]

    A. Y. Shiekh

    2008-04-05

    Faster than light communication might be possible using the collapse of the quantum wave-function without any accompanying paradoxes.

  16. Light Emission in Silicon from Carbon Nanotubes

    E-Print Network [OSTI]

    Gaufrès, Etienne; Noury, Adrien; Roux, Xavier Le; Rasigade, Gilles; Beck, Alexandre; Vivien, Laurent

    2015-01-01

    The use of optics in microelectronic circuits to overcome the limitation of metallic interconnects is more and more considered as a viable solution. Among future silicon compatible materials, carbon nanotubes are promising candidates thanks to their ability to emit, modulate and detect light in the wavelength range of silicon transparency. We report the first integration of carbon nanotubes with silicon waveguides, successfully coupling their emission and absorption properties. A complete study of this coupling between carbon nanotubes and silicon waveguides was carried out, which led to the demonstration of the temperature-independent emission from carbon nanotubes in silicon at a wavelength of 1.3 {\\mu}m. This represents the first milestone in the development of photonics based on carbon nanotubes on silicon.

  17. Self-assembled photosynthesis-inspired light harvesting material and solar cells containing the same

    DOE Patents [OSTI]

    Lindsey, Jonathan S. (Raleigh, NC); Chinnasamy, Muthiah (Raleigh, NC); Fan, Dazhong (Raleigh, NC)

    2009-12-15

    A solar cell is described that comprises: (a) a semiconductor charge separation material; (b) at least one electrode connected to the charge separation material; and (c) a light-harvesting film on the charge separation material, the light-harvesting film comprising non-covalently coupled, self-assembled units of porphyrinic macrocycles. The porphyrinic macrocycles preferably comprise: (i) an intramolecularly coordinated metal; (ii) a first coordinating substituent; and (iii) a second coordinating substituent opposite the first coordinating substituent. The porphyrinic macrocycles can be assembled by repeating intermolecular coordination complexes of the metal, the first coordinating substituent and the second coordinating substituent.

  18. Inverse design of periodic metallic slits for extraordinary optical transmission

    E-Print Network [OSTI]

    Deng, Yongbo; Liu, Zhenyu; Wu, Yihui

    2016-01-01

    The inverse design methodology of periodic metallic slits for extraordinary optical transmission is presented based on the topology optimization method. Several topological configurations of periodic metallic slits with typical subwavelength size are derived with transmission peaks at the prescribed incident wavelengths in the visible light region, where the transmissivity is enhanced by effective excitation of surface-plasmon-polariton at the inlet side of the slit, Fabry-P\\'erot resonance of surface-plasmon-polariton inside the slit and radiation of the electromagnetic energy at the outlet side of the slit. The transmission peaks of the derived metallic configurations are raised along with the red shift of the incident wavelength, because of the reduction of the energy absorption and increase of the propagation distance of surface-plasmon-polariton. And the shift of transmission peak is controlled by prescribing a different incident wavelength in the corresponding topology optimization problem. To reduce th...

  19. Hydrothermal alkali metal recovery process

    DOE Patents [OSTI]

    Wolfs, Denise Y. (Houston, TX); Clavenna, Le Roy R. (Baytown, TX); Eakman, James M. (Houston, TX); Kalina, Theodore (Morris Plains, NJ)

    1980-01-01

    In a coal gasification operation or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein solid particles containing alkali metal residues are produced, alkali metal constituents are recovered from the particles by treating them with a calcium or magnesium-containing compound in the presence of water at a temperature between about 250.degree. F. and about 700.degree. F. and in the presence of an added base to establish a pH during the treatment step that is higher than would otherwise be possible without the addition of the base. During the treating process the relatively high pH facilitates the conversion of water-insoluble alkali metal compounds in the alkali metal residues into water-soluble alkali metal constituents. The resultant aqueous solution containing water-soluble alkali metal constituents is then separated from the residue solids, which consist of the treated particles and any insoluble materials formed during the treatment step, and recycled to the gasification process where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst. Preferably, the base that is added during the treatment step is an alkali metal hydroxide obtained by water washing the residue solids produced during the treatment step.

  20. Lighting and Dark Sky Regulations

    E-Print Network [OSTI]

    Radcliffe, David

    Lighting and Dark Sky Regulations Marjorie Palmer Spring 2008 #12;The UGA Land Use Clinic provides Road, Room 101 Athens, GA 30602-1510 (706) 583-0373 · Fax (706) 583-0612 jroskie@uga.edu #12;Lighting......................................................................................................................................1 II. Approaches to Lighting Regulation

  1. Dimensionally stable metallic hydride composition

    DOE Patents [OSTI]

    Heung, Leung K. (Aiken, SC)

    1994-01-01

    A stable, metallic hydride composition and a process for making such a composition. The composition comprises a uniformly blended mixture of a metal hydride, kieselguhr, and a ballast metal, all in the form of particles. The composition is made by subjecting a metal hydride to one or more hydrogen absorption/desorption cycles to disintegrate the hydride particles to less than approximately 100 microns in size. The particles are partly oxidized, then blended with the ballast metal and the kieselguhr to form a uniform mixture. The mixture is compressed into pellets and calcined. Preferably, the mixture includes approximately 10 vol. % or more kieselguhr and approximately 50 vol. % or more ballast. Metal hydrides that can be used in the composition include Zr, Ti, V, Nb, Pd, as well as binary, tertiary, and more complex alloys of La, Al, Cu, Ti, Co, Ni, Fe, Zr, Mg, Ca, Mn, and mixtures and other combinations thereof. Ballast metals include Al, Cu and Ni.

  2. Corrosion protective coating for metallic materials

    DOE Patents [OSTI]

    Buchheit, R.G.; Martinez, M.A.

    1998-05-26

    Corrosion protective coatings for metallic materials, particularly aluminum and aluminum alloys, produced with simple, low-cost equipment and materials other than toxic metals or metal salts, or metal cyanides is disclosed. The metallic material is cleaned, degreased, and deoxidized, the surface is converted to a substantially alkaline condition, and the surface is chemically sealed with inorganic metal compounds. 1 fig.

  3. Laser remote sensing of backscattered light from a target sample

    DOE Patents [OSTI]

    Sweatt, William C. (Albuquerque, NM); Williams, John D. (Albuquerque, NM)

    2008-02-26

    A laser remote sensing apparatus comprises a laser to provide collimated excitation light at a wavelength; a sensing optic, comprising at least one optical element having a front receiving surface to focus the received excitation light onto a back surface comprising a target sample and wherein the target sample emits a return light signal that is recollimated by the front receiving surface; a telescope for collecting the recollimated return light signal from the sensing optic; and a detector for detecting and spectrally resolving the return light signal. The back surface further can comprise a substrate that absorbs the target sample from an environment. For example the substrate can be a SERS substrate comprising a roughened metal surface. The return light signal can be a surface-enhanced Raman signal or laser-induced fluorescence signal. For fluorescence applications, the return signal can be enhanced by about 10.sup.5, solely due to recollimation of the fluorescence return signal. For SERS applications, the return signal can be enhanced by 10.sup.9 or more, due both to recollimation and to structuring of the SERS substrate so that the incident laser and Raman scattered fields are in resonance with the surface plasmons of the SERS substrate.

  4. Reduction of Metal Oxide to Metal using Ionic Liquids

    SciTech Connect (OSTI)

    Dr. Ramana Reddy

    2012-04-12

    A novel pathway for the high efficiency production of metal from metal oxide means of electrolysis in ionic liquids at low temperature was investigated. The main emphasis was to eliminate the use of carbon and high temperature application in the reduction of metal oxides to metals. The emphasis of this research was to produce metals such as Zn, and Pb that are normally produced by the application of very high temperatures. The reduction of zinc oxide to zinc and lead oxide to lead were investigated. This study involved three steps in accomplishing the final goal of reduction of metal oxide to metal using ionic liquids: 1) Dissolution of metal oxide in an ionic liquid, 2) Determination of reduction potential using cyclic voltammetry (CV) and 3) Reduction of the dissolved metal oxide. Ionic liquids provide additional advantage by offering a wide potential range for the deposition. In each and every step of the process, more than one process variable has been examined. Experimental results for electrochemical extraction of Zn from ZnO and Pb from PbO using eutectic mixtures of Urea ((NH2)2CO) and Choline chloride (HOC2H4N(CH3)3+Cl-) or (ChCl) in a molar ratio 2:1, varying voltage and temperatures were carried out. Fourier Transform Infra-Red (FTIR) spectroscopy studies of ionic liquids with and without metal oxide additions were conducted. FTIR and induction coupled plasma spectroscopy (ICPS) was used in the characterization of the metal oxide dissolved ionic liquid. Electrochemical experiments were conducted using EG&G potentiostat/galvanostat with three electrode cell systems. Cyclic voltammetry was used in the determination of reduction potentials for the deposition of metals. Chronoamperometric experiments were carried out in the potential range of -0.6V to -1.9V for lead and -1.4V to -1.9V for zinc. The deposits were characterized using XRD and SEM-EDS for phase, morphological and elemental analysis. The results showed that pure metal was deposited on the cathode. Successful extraction of metal from metal oxide dissolved in Urea/ChCl (2:1) was accomplished. The current efficiencies were relatively high in both the metal deposition processes with current efficiency greater than 86% for lead and 95% for zinc. This technology will advance the metal oxide reduction process by increasing the process efficiency and also eliminate the production of CO2 which makes this an environmentally benign technology for metal extraction.

  5. Radiation, Matter and Energy What is light?

    E-Print Network [OSTI]

    Shirley, Yancy

    Radiation, Matter and Energy #12;What is light? #12;Light is an electromagnetic wave #12;Light is an electromagnetic wave #12;#12;Light is also a particle Photons: "pieces" of light, each with precise wavelength the visible spectrum, blue light has higher energy than red light Within the electromagnetic spectrum, X

  6. Light Board Operation 208 Jordan Hall

    E-Print Network [OSTI]

    Buechler, Steven

    Light Board Operation 208 Jordan Hall Using the Light Board 1. Turn on the lights next to the entry door. 2. Turn on the Light Board lights (illustration 1). The light switch is on the west wall, slightly behind the computer cart's display. 3. Locate the lapel microphone (usually on top of the Light

  7. Molding the flow of light at deep sub-wavelength scale

    E-Print Network [OSTI]

    Han, Seunghoon; Genov, Dentcho; Liu, Zhaowei; Bartal, Guy; Zhang, Xiang

    2007-01-01

    The diffractive nature of light has limited optics and photonics to operate at scales much larger than the wavelength of light. The major challenge in scaling-down integrated photonics is how to mold the light flow below diffraction-limit in all three dimensions. A high index solid immersion lens can improve the spatial resolution by increasing the medium refractive index, but only to few times higher than in air. Photonic crystals can guide light in three dimensions, however, the guided beam width is around a wavelength. Surface plasmons has a potential to reach the sub-wavelength scales; nevertheless, it is confined in the two-dimensional interface between metals and dielectrics. Here, we present a new approach for molding the light flow at the deep sub-wavelength scale, using metamaterials with uniquely designed dispersion. We develop a design methodology for realizing sub-wavelength ray optics, and demonstrate lambda/10 width light beams flow through three-dimensional space.

  8. Pedestrian Friendly Outdoor Lighting

    SciTech Connect (OSTI)

    Miller, Naomi J.; Koltai, Rita; McGowan, Terry

    2013-12-31

    This GATEWAY report discusses the problems of pedestrian lighting that occur with all technologies with a focus on the unique optical options and opportunities offered by LEDs through the findings from two pedestrian-focused projects, one at Stanford University in California, and one at the Chautauqua Institution in upstate New York. Incorporating user feedback this report reviews the tradeoffs that must be weighed among visual comfort, color, visibility, efficacy and other factors to stimulate discussion among specifiers, users, energy specialists, and in industry in hopes that new approaches, metrics, and standards can be developed to support pedestrian-focused communities, while reducing energy use.

  9. National Lighting Energy Consumption

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Financing Tool Fits the BillDepartmentSites KDFNational Fuel Cell andEnergy NationalLighting

  10. Extragalactic Background Light

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield MunicipalTechnical Report:Speeding accessby aLED Street Lighting HostDISCLAIMERlinacSYNCHROTRON

  11. Lighting Market Characterization

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACTThousand CubicResourcelogo and-E C H2015 Non-Residential Lighting Market

  12. Lighting Test Facilities

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACTThousand CubicResourcelogo and-E C H2015 Non-Residential Lighting

  13. Lighting in the Library

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACTThousand CubicResourcelogo and-E C H2015 Non-Residential LightingThe

  14. Lighting Principles and Terms | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Light quantity, energy consumption, and light quality are the basic principles of lighting. | Photo courtesy of

  15. Embodied Energy and Off-Grid Lighting

    E-Print Network [OSTI]

    Alstone, Peter

    2012-01-01

    Self-reported Impacts of LED Lighting Technology Compared to2011. Adoption of LED Lighting by Night Market Vendors inbased to rechargeable LED lighting. However, as with most

  16. Types of Lighting | Department of Energy

    Energy Savers [EERE]

    For a technical comparison of the different types of lighting, visit Energy Basics. External Resources Find a Lighting Designer - International Association of Lighting...

  17. Demand Responsive Lighting: A Scoping Study

    E-Print Network [OSTI]

    Rubinstein, Francis; Kiliccote, Sila

    2007-01-01

    3 3.0 Previous Experience with Demand Responsive Lighting11 4.3. Prevalence of Lighting13 4.4. Impact of Title 24 on Lighting

  18. Ecological Consequences of Artificial Night Lighting

    E-Print Network [OSTI]

    Piselli, Kathy

    2006-01-01

    of Artificial Night Lighting Catherine Rich and Travisof artificial night lighting. This book provides editedage of modern urban lighting was ushered in. Coincidentally,

  19. LIGHTING CONTROLS: SURVEY OF MARKET POTENTIAL

    E-Print Network [OSTI]

    Verderber, R.R.

    2010-01-01

    REFERENCES Task Report to Lighting Systems Research,Berkeley Laboratory, "Lighting Control System Market1980). Task Report to Lighting Systems Research, Lawrence

  20. LED Outdoor Area Lighting Fact Sheet

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Outdoor Area Lighting LED technology is rapidly becoming competitive with high-intensity discharge light sources for outdoor area lighting. This document reviews the major design...

  1. Controls for Solid-State Lighting

    E-Print Network [OSTI]

    Rubinstein, Francis

    2007-01-01

    of controlling LED lighting using the DALI protocol. Figurewith dimming white LED lighting depending on whether the LEDthe promising hybrid LED lighting systems are: 1. LED Hybrid

  2. Measuring Light Reflectance of BGO Crystal Surfaces

    E-Print Network [OSTI]

    Janecek, Martin

    2009-01-01

    Carlo program simulating light propagation in isotropic orTerms—Lambertian reflection, light collection, Monte Carloy-axis) and fraction specular light (right y- axis) for a

  3. Light propagation and Imaging in Indefinite Metamaterials

    E-Print Network [OSTI]

    Yao, Jie

    2010-01-01

    photolithography by polarized light,” Applied PhysicsZhang, “Imaging visible light using anisotropic metamaterialcross-sectional review of the light propagation of TE mode (

  4. COORDINATION CHEMISTRY OF METAL SURFACES AND METAL COMPLEXES

    E-Print Network [OSTI]

    Muetterties, E.L.

    2013-01-01

    molecular coordination chemistry of CH3NC has been reported.features of this surface chemistry. ACKNOw"LEDGMENTS The1980 Catalysis~ COORDINATION CHEMISTRY OF METAL SURFACES AND

  5. An Electrically Switchable Metal-Organic Framework

    SciTech Connect (OSTI)

    Fernandez, Carlos A.; Martin, Paul F.; Schaef, Herbert T.; Bowden, Mark E.; Thallapally, Praveen K.; Dang, Liem X.; Xu, Wu; Chen, Xilin; McGrail, B. Peter

    2014-08-19

    Crystalline metal organic framework (MOF) materials containing interconnected porosity can be chemically modified to promote stimulus-driven (light, magnetic or electric fields) structural transformations that can be used in a number of devices. Innovative research strategies are now focused on understanding the role of chemical bond manipulation to reversibly alter the free volume in such structures of critical importance for electro-catalysis, molecular electronics, energy storage technologies, sensor devices and smart membranes. In this letter, we study the mechanism for which an electrically switchable MOF composed of Cu(TCNQ) (TCNQ 5 7,7,8,8-tetracyanoquinodimethane) transitions from a high-resistance state to a conducting state in a reversible fashion by an applied potential. The actual mechanism for this reversible electrical switching is still not understood even though a number of reports are available describing the application of electric-field-induced switching of Cu(TCNQ) in device fabrication.

  6. An Electrically Switchable Metal-Organic Framework

    SciTech Connect (OSTI)

    Fernandez, CA; Martin, PC; Schaef, T; Bowden, ME; Thallapally, PK; Dang, L; Xu, W; Chen, XL; McGrail, BP

    2014-08-19

    Crystalline metal organic framework (MOF) materials containing interconnected porosity can be chemically modified to promote stimulus-driven (light, magnetic or electric fields) structural transformations that can be used in a number of devices. Innovative research strategies are now focused on understanding the role of chemical bond manipulation to reversibly alter the free volume in such structures of critical importance for electro-catalysis, molecular electronics, energy storage technologies, sensor devices and smart membranes. In this letter, we study the mechanism for which an electrically switchable MOF composed of Cu(TCNQ) (TCNQ = 7,7,8,8-tetracyanoquinodimethane) transitions from a high-resistance state to a conducting state in a reversible fashion by an applied potential. The actual mechanism for this reversible electrical switching is still not understood even though a number of reports are available describing the application of electric-field-induced switching of Cu(TCNQ) in device fabrication.

  7. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservationBio-Inspired SolarAbout / TransformingTransuranic Waste RetrievalTrending: Metal Oxo

  8. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservationBio-Inspired SolarAbout / TransformingTransuranic Waste RetrievalTrending: Metal

  9. Probing metal solidification nondestructively

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass mapSpeedingProgramExemptions | National NuclearProbingProbing metal solidification

  10. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With U.S.WeekProducts >TransportationEHSS A-ZTravisTrending: Metal

  11. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With U.S.WeekProducts >TransportationEHSSTrending: Metal Oxo Bonds

  12. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With U.S.WeekProducts >TransportationEHSSTrending: Metal Oxo

  13. Probing metal solidification nondestructively

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservation of Fe(II) by Carbon-Rich Matrices inPrincipalFirm Exchange . . .Probing metal

  14. Supported molten-metal catalysts

    DOE Patents [OSTI]

    Datta, Ravindra (Iowa City, IA); Singh, Ajeet (Iowa City, IA); Halasz, Istvan (Iowa City, IA); Serban, Manuela (Iowa City, IA)

    2001-01-01

    An entirely new class of catalysts called supported molten-metal catalysts, SMMC, which can replace some of the existing precious metal catalysts used in the production of fuels, commodity chemicals, and fine chemicals, as well as in combating pollution. SMMC are based on supporting ultra-thin films or micro-droplets of the relatively low-melting (<600.degree. C.), inexpensive, and abundant metals and semimetals from groups 1, 12, 13, 14, 15 and 16, of the periodic table, or their alloys and intermetallic compounds, on porous refractory supports, much like supported microcrystallites of the traditional solid metal catalysts. It thus provides orders of magnitude higher surface area than is obtainable in conventional reactors containing molten metals in pool form and also avoids corrosion. These have so far been the chief stumbling blocks in the application of molten metal catalysts.

  15. Degenerate doping of metallic anodes

    SciTech Connect (OSTI)

    Friesen, Cody A; Zeller, Robert A; Johnson, Paul B; Switzer, Elise E

    2015-05-12

    Embodiments of the invention relate to an electrochemical cell comprising: (i) a fuel electrode comprising a metal fuel, (ii) a positive electrode, (iii) an ionically conductive medium, and (iv) a dopant; the electrodes being operable in a discharge mode wherein the metal fuel is oxidized at the fuel electrode and the dopant increases the conductivity of the metal fuel oxidation product. In an embodiment, the oxidation product comprises an oxide of the metal fuel which is doped degenerately. In an embodiment, the positive electrode is an air electrode that absorbs gaseous oxygen, wherein during discharge mode, oxygen is reduced at the air electrode. Embodiments of the invention also relate to methods of producing an electrode comprising a metal and a doped metal oxidation product.

  16. Metal to ceramic sealed joint

    DOE Patents [OSTI]

    Lasecki, John V. (Livonia, MI); Novak, Robert F. (Farmington Hills, MI); McBride, James R. (Ypsilanti, MI)

    1991-01-01

    A metal to ceramic sealed joint which can withstand wide variations in temperature and maintain a good seal is provided for use in a device adapted to withstand thermal cycling from about 20 to about 1000 degrees C. The sealed joint includes a metal member, a ceramic member having an end portion, and an active metal braze forming a joint to seal the metal member to the ceramic member. The joint is positioned remote from the end portion of the ceramic member to avoid stresses at the ends or edges of the ceramic member. The sealed joint is particularly suited for use to form sealed metal to ceramic joints in a thermoelectric generator such as a sodium heat engine where a solid ceramic electrolyte is joined to metal parts in the system.

  17. Metal to ceramic sealed joint

    DOE Patents [OSTI]

    Lasecki, J.V.; Novak, R.F.; McBride, J.R.

    1991-08-27

    A metal to ceramic sealed joint which can withstand wide variations in temperature and maintain a good seal is provided for use in a device adapted to withstand thermal cycling from about 20 to about 1000 degrees C. The sealed joint includes a metal member, a ceramic member having an end portion, and an active metal braze forming a joint to seal the metal member to the ceramic member. The joint is positioned remote from the end portion of the ceramic member to avoid stresses at the ends or edges of the ceramic member. The sealed joint is particularly suited for use to form sealed metal to ceramic joints in a thermoelectric generator such as a sodium heat engine where a solid ceramic electrolyte is joined to metal parts in the system. 11 figures.

  18. REVERSIBLE METAL-TO-METAL METHYL TRANSFER IN n5-CYCLOPENTADIENYL(TRIPHENYLPHOSPHINE)DIMETHYLCOBALT(III)

    E-Print Network [OSTI]

    Bryndza, Henry E.

    2013-01-01

    transfer between transition metals which is assisted by aJournal of the American Chemical Society REVERSIBLE METAL-TO-METAL METHYL TRANSFER IN n 5-CYCLOPENTAOIENYL(

  19. Alkali metal ion battery with bimetallic electrode

    DOE Patents [OSTI]

    Boysen, Dane A; Bradwell, David J; Jiang, Kai; Kim, Hojong; Ortiz, Luis A; Sadoway, Donald R; Tomaszowska, Alina A; Wei, Weifeng; Wang, Kangli

    2015-04-07

    Electrochemical cells having molten electrodes having an alkali metal provide receipt and delivery of power by transporting atoms of the alkali metal between electrode environments of disparate chemical potentials through an electrochemical pathway comprising a salt of the alkali metal. The chemical potential of the alkali metal is decreased when combined with one or more non-alkali metals, thus producing a voltage between an electrode comprising the molten the alkali metal and the electrode comprising the combined alkali/non-alkali metals.

  20. Method for preparing porous metal hydride compacts

    DOE Patents [OSTI]

    Ron, M.; Gruen, D.M.; Mendelsohn, M.H.; Sheft, I.

    1980-01-21

    A method for preparing porous metallic-matrix hydride compacts which can be repeatedly hydrided and dehydrided without disintegration. A mixture of a finely divided metal hydride and a finely divided matrix metal is contacted with a poison which prevents the metal hydride from dehydriding at room temperature and atmospheric pressure. The mixture of matrix metal and poisoned metal hydride is then compacted under pressure at room temperature to form porous metallic-matrix hydride compacts.

  1. Method for preparing porous metal hydride compacts

    DOE Patents [OSTI]

    Ron, Moshe (Haifa, IL); Gruen, Dieter M. (Downers Grove, IL); Mendelsohn, Marshall H. (Woodridge, IL); Sheft, Irving (Oak Park, IL)

    1981-01-01

    A method for preparing porous metallic-matrix hydride compacts which can be repeatedly hydrided and dehydrided without disintegration. A mixture of a finely divided metal hydride and a finely divided matrix metal is contacted with a poison which prevents the metal hydride from dehydriding at room temperature and atmospheric pressure. The mixture of matrix metal and poisoned metal hydride is then compacted under pressure at room temperature to form porous metallic-matrix hydride compacts.

  2. A superconductor to superfluid phase transition in liquid metallic hydrogen

    E-Print Network [OSTI]

    Egor Babaev; Asle Sudbo; N. W. Ashcroft

    2004-10-18

    Although hydrogen is the simplest of atoms, it does not form the simplest of solids or liquids. Quantum effects in these phases are considerable (a consequence of the light proton mass) and they have a demonstrable and often puzzling influence on many physical properties, including spatial order. To date, the structure of dense hydrogen remains experimentally elusive. Recent studies of the melting curve of hydrogen indicate that at high (but experimentally accessible) pressures, compressed hydrogen will adopt a liquid state, even at low temperatures. In reaching this phase, hydrogen is also projected to pass through an insulator-to-metal transition. This raises the possibility of new state of matter: a near ground-state liquid metal, and its ordered states in the quantum domain. Ordered quantum fluids are traditionally categorized as superconductors or superfluids; these respective systems feature dissipationless electrical currents or mass flow. Here we report an analysis based on topological arguments of the projected phase of liquid metallic hydrogen, finding that it may represent a new type of ordered quantum fluid. Specifically, we show that liquid metallic hydrogen cannot be categorized exclusively as a superconductor or superfluid. We predict that, in the presence of a magnetic field, liquid metallic hydrogen will exhibit several phase transitions to ordered states, ranging from superconductors to superfluids.

  3. Electronic structure of metallic glasses

    SciTech Connect (OSTI)

    Oelhafen, P.; Lapka, R.; Gubler, U.; Krieg, J.; DasGupta, A.; Guentherodt, H.J.; Mizoguchi, T.; Hague, C.; Kuebler, J.; Nagel, S.R.

    1981-01-01

    This paper is organized in six sections and deals with (1) the glassy transition metal alloys, their d-band structure, the d-band shifts on alloying and their relation to the alloy heat of formation (..delta..H) and the glass forming ability, (2) the glass to crystal phase transition viewed by valence band spectroscopy, (3) band structure calculations, (4) metallic glasses prepared by laser glazing, (5) glassy normal metal alloys, and (6) glassy hydrides.

  4. Corrosion-resistant metal surfaces

    DOE Patents [OSTI]

    Sugama, Toshifumi (Wading River, NY)

    2009-03-24

    The present invention relates to metal surfaces having thereon an ultrathin (e.g., less than ten nanometer thickness) corrosion-resistant film, thereby rendering the metal surfaces corrosion-resistant. The corrosion-resistant film includes an at least partially crosslinked amido-functionalized silanol component in combination with rare-earth metal oxide nanoparticles. The invention also relates to methods for producing such corrosion-resistant films.

  5. Metal-ceramic joint assembly

    DOE Patents [OSTI]

    Li, Jian (New Milford, CT)

    2002-01-01

    A metal-ceramic joint assembly in which a brazing alloy is situated between metallic and ceramic members. The metallic member is either an aluminum-containing stainless steel, a high chromium-content ferritic stainless steel or an iron nickel alloy with a corrosion protection coating. The brazing alloy, in turn, is either an Au-based or Ni-based alloy with a brazing temperature in the range of 9500 to 1200.degree. C.

  6. Energy Savings Estimates of Light Emitting Diodes in Niche Lighting...

    Broader source: Energy.gov (indexed) [DOE]

    in Niche Lighting Applications Prepared for: Building Technologies Program Office of Energy Efficiency and Renewable Energy U.S. Department of Energy Prepared by: Navigant...

  7. Advanced Light Extraction Material for OLED Lighting | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Extraction Material for OLED Lighting Lead Performer: Pixelligent Technologies LLC - Baltimore, MD Partners: OLEDWorks LLC DOE Total Funding: 1,000,000 Project Term: April 6,...

  8. Solar optics: light as energy; energy as light

    SciTech Connect (OSTI)

    Bennett, D.J.; Eijadi, D.A.

    1980-05-01

    a prominent characteristic of earth-sheltered and underground buildings, as well as buildings designed to accommodate more uses within the same perimeters, is the prominence of interior space without direct access to natural light and view opportunities. Solar Optics, a technique for illuminating interior spaces with natural light, offers a way to satisfy the well-documented human affinity for natural light. The system, which uses a heliostat to track the sun and lenses and mirrors to direct the light to remote interior spaces, is more efficient than converting solar radiation into electricity. Through the use of cold mirrors, it is also possible to separate the infrared portion of the spectrum from visible light, thereby creating a cool light source that can reduce a building's space cooling demand. Solar Optics also offers energy savings by transmitting light through a small aperture, as opposed to a large window. Several design problems must still be addressed. The system will be demonstrated in a new building at the University of Minnesota. Because this is a limited demonstration, it does not include the integration of a natural light system with a central source light system...another promising application of Solar Optics.

  9. LIGHTING CONTROLS: SURVEY OF MARKET POTENTIAL

    E-Print Network [OSTI]

    Verderber, R.R.

    2010-01-01

    Floors Floor Area Lighting Power Density Light Output Lampenergy den- sity and power density for lighting to 3.5 kWh/Lighting Level (Lumens/Watt) (Footcandles) Power Density (

  10. Sandia Energy - Lighting Developments to 2030

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lighting Developments to 2030 Home Energy Research EFRCs Solid-State Lighting Science EFRC Lighting Developments to 2030 Lighting Developments to 2030Tara Camacho-Lopez2015-05-14T1...

  11. Tips: Shopping for Lighting | Department of Energy

    Energy Savers [EERE]

    Lighting Tips: Shopping for Lighting July 17, 2014 - 7:27pm Addthis With an array of lighting options, use the Lighting Facts label to determine the right lightbulb for you. |...

  12. Analysis of light transport in scattering media

    E-Print Network [OSTI]

    Mukaigawa, Yasuhiro

    We propose a new method to analyze light transport in homogeneous scattering media. The incident light undergoes multiple bounces in translucent objects, and produces a complex light field. Our method analyzes the light ...

  13. Metal-ion recycle technology for metal electroplating waste waters

    SciTech Connect (OSTI)

    Sauer, N.N.; Smith, B.F.

    1993-06-01

    As a result of a collaboration with Boeing Aerospace, the authors have begun a program to identify suitable treatments or to develop new treatments for electroplating baths. The target baths are mixed-metal or alloy baths that are being integrated into the Boeing electroplating complex. These baths, which are designed to replace highly toxic chromium and cadmium baths, contain mixtures of two metals, either nickel-tungsten, nickel-zinc, or zinc-tin. This report reviews the literature and details currently available on emerging technologies that could affect recovery of metals from electroplating baths under development by Boeing Aerospace. This literature survey summarizes technologies relevant to the recovery of metals from electroplating processes. The authors expanded the scope to investigate single metal ion recovery technologies that could be applied to metal ion recovery from alloy baths. This review clearly showed that the electroplating industry has traditionally relied on precipitation and more recently on electrowinning as its waste treatment methods. Despite the almost ubiquitous use of precipitation to remove contaminant metal ions from waste electroplating baths and rinse waters, this technology is clearly no longer feasible for the electroplating industry for several reasons. First, disposal of unstabilized sludge is no longer allowed by law. Second, these methods are no longer adequate as metal-removal techniques because they cannot meet stringent new metal discharge limits. Third, precious resources are being wasted or discarded because these methods do not readily permit recovery of the target metal ions. As a result, emerging technologies for metal recovery are beginning to see application to electroplating waste recycle. This report summarizes current research in these areas. Included are descriptions of various membrane technologies, such as reverse osmosis and ultrafiltration, ion exchange and chelating polymer technology, and electrodialysis.

  14. Light Meson Distribution Amplitudes

    E-Print Network [OSTI]

    R. Arthur; P. A. Boyle; D. Brömmel; M. A. Donnellan; J. M. Flynn; A. Jüttner; H. Pedroso de Lima; T. D. Rae; C. T. Sachrajda; B. Samways

    2010-11-12

    We calculated the first two moments of the light-cone distribution amplitudes for the pseudoscalar mesons ($\\pi$ and $K$) and the longitudinally polarised vector mesons ($\\rho$, $K^*$ and $\\phi$) as part of the UKQCD and RBC collaborations' $N_f=2+1$ domain-wall fermion phenomenology programme. These quantities were obtained with a good precision and, in particular, the expected effects of $SU(3)$-flavour symmetry breaking were observed. Operators were renormalised non-perturbatively and extrapolations to the physical point were made, guided by leading order chiral perturbation theory. The main results presented are for two volumes, $16^3\\times 32$ and $24^3\\times 64$, with a common lattice spacing. Preliminary results for a lattice with a finer lattice spacing, $32^3\\times64$, are discussed and a first look is taken at the use of twisted boundary conditions to extract distribution amplitudes.

  15. Clean Metal Casting

    SciTech Connect (OSTI)

    Makhlouf M. Makhlouf; Diran Apelian

    2002-02-05

    The objective of this project is to develop a technology for clean metal processing that is capable of consistently providing a metal cleanliness level that is fit for a given application. The program has five tasks: Development of melt cleanliness assessment technology, development of melt contamination avoidance technology, development of high temperature phase separation technology, establishment of a correlation between the level of melt cleanliness and as cast mechanical properties, and transfer of technology to the industrial sector. Within the context of the first task, WPI has developed a standardized Reduced Pressure Test that has been endorsed by AFS as a recommended practice. In addition, within the context of task1, WPI has developed a melt cleanliness sensor based on the principles of electromagnetic separation. An industrial partner is commercializing the sensor. Within the context of the second task, WPI has developed environmentally friendly fluxes that do not contain fluorine. Within the context of the third task, WPI modeled the process of rotary degassing and verified the model predictions with experimental data. This model may be used to optimize the performance of industrial rotary degassers. Within the context of the fourth task, WPI has correlated the level of melt cleanliness at various foundries, including a sand casting foundry, a permanent mold casting foundry, and a die casting foundry, to the casting process and the resultant mechanical properties. This is useful in tailoring the melt cleansing operations at foundries to the particular casting process and the desired properties of cast components.

  16. Metal deposition using seed layers

    DOE Patents [OSTI]

    Feng, Hsein-Ping; Chen, Gang; Bo, Yu; Ren, Zhifeng; Chen, Shuo; Poudel, Bed

    2013-11-12

    Methods of forming a conductive metal layers on substrates are disclosed which employ a seed layer to enhance bonding, especially to smooth, low-roughness or hydrophobic substrates. In one aspect of the invention, the seed layer can be formed by applying nanoparticles onto a surface of the substrate; and the metallization is achieved by electroplating an electrically conducting metal onto the seed layer, whereby the nanoparticles serve as nucleation sites for metal deposition. In another approach, the seed layer can be formed by a self-assembling linker material, such as a sulfur-containing silane material.

  17. Northeast Energy Efficiency Partnerships: Advanced Lighting Controls...

    Energy Savers [EERE]

    Northeast Energy Efficiency Partnerships: Advanced Lighting Controls Northeast Energy Efficiency Partnerships: Advanced Lighting Controls Credit: Northeast Energy Efficiency...

  18. 2014 Solid-State Lighting Project Portfolio

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    White LED Light Engines ... A-23 Phosphor Systems for Illumination Quality Solid State Lighting Products ... A-24...

  19. Metallic Stents for Tracheobronchial Pathology Treatment

    SciTech Connect (OSTI)

    Serrano, Carolina; Laborda, Alicia; Lozano, Juan M.; Caballero, Hugo; Sebastian, Antonio; Lopera, Jorge; Gregorio, Miguel Angel de

    2013-12-15

    Purpose: To present the 7-year experience of the treatment of benign and malignant tracheobronchial stenoses using metallic stents. Patients and Methods: One hundred twenty-three stents were inserted in 86 patients (74 benign and 12 malignant stenoses). Ninety-seven stents were placed in the trachea and 26 in the bronchi. The procedures were performed under fluoroscopic and flexible bronchoscopic guidance with the patient under light sedation. In cases of severe stenotic lesions or obstructions, laser resection was performed before stent placement. Clinical and functional pulmonary data were recorded before and 3 months after the procedure. Follow-up involved clinical data and radiographic techniques at 48 h and at 1-, 3-, 6-, and 12-month intervals. Results: The technical success was 100 %. Dyspnea disappearance, forced expiratory volume in the first second, and pulmonary functional data improvement was observed in all patients (p < 0.001). Complications were detected in 23 patients (26.7 %). Mean follow-up time was 6.3 {+-} 1.2 months in patients with malignant lesions and 76.2 {+-} 2.3 months patients with in benign lesions. By the end of the study, 100 % of patients with malignant pathology and 6.7 % of patients with benign lesions had died. Conclusion: Endoluminal treatment of tracheobronchial stenosis with metallic stents is a therapeutic alternative in patients who are poor candidates for surgery. In unresectable malignant lesions, the benefit of metallic stenting is unquestionable. In benign lesions, the results are satisfactory, but sometimes other interventions are required to treat complications. New stent technology may improve these results.

  20. Automatic Mechetronic Wheel Light Device

    DOE Patents [OSTI]

    Khan, Mohammed John Fitzgerald (Silver Spring, MD)

    2004-09-14

    A wheel lighting device for illuminating a wheel of a vehicle to increase safety and enhance aesthetics. The device produces the appearance of a "ring of light" on a vehicle's wheels as the vehicle moves. The "ring of light" can automatically change in color and/or brightness according to a vehicle's speed, acceleration, jerk, selection of transmission gears, and/or engine speed. The device provides auxiliary indicator lights by producing light in conjunction with a vehicle's turn signals, hazard lights, alarm systems, and etc. The device comprises a combination of mechanical and electronic components and can be placed on the outer or inner surface of a wheel or made integral to a wheel or wheel cover. The device can be configured for all vehicle types, and is electrically powered by a vehicle's electrical system and/or battery.

  1. Light-Like Noncommutativity, Light-Front Quantization and New Light on UV/IR Mixing

    E-Print Network [OSTI]

    M. M. Sheikh-Jabbari; A. Tureanu

    2010-10-02

    We revisit the problem of quantizing field theories on noncommutative Moyal spacetime with \\emph{light-like} noncommutativity. To tackle the issues arising from noncommuting and hence nonlocal time, we argue that for this case light-front quantization procedure should be employed. In this appropriate quantization scheme we perform the non-planar loop analysis for the light-like noncommutative field theories. One of the important and peculiar features of light-front quantization is that the UV cutoff of the light-cone Hamiltonian manifests itself as an IR cutoff for the light-cone momentum, $p^+$. Due to this feature, the naive results of covariant quantization for the light-like case allude to the absence of the UV/IR mixing in the light-front quantization. However, by a careful analysis of non-planar loop integrals we show that this is not the case and the UV/IR mixing persists. In addition, we argue in favour of the perturbative unitarity of light-like noncommutative field theories in the light-front quantization scheme.

  2. Integrated porous-silicon light-emitting diodes: A fabrication process using graded doping profiles

    SciTech Connect (OSTI)

    Barillaro, G.; Diligenti, A.; Pieri, F.; Fuso, F.; Allegrini, M.

    2001-06-25

    A fabrication process, compatible with an industrial bipolar+complementary metal{endash}oxide{endash}semiconductor (MOS)+diffusion MOS technology, has been developed for the fabrication of efficient porous-silicon-based light-emitting diodes. The electrical contact is fabricated with a double n{sup +}/p doping, achieving a high current injection efficiency and thus lower biasing voltages. The anodization is performed as the last step of the process, thus reducing potential incompatibilities with industrial processes. The fabricated devices show yellow-orange electroluminescence, visible with the naked eye in room lighting. A spectral characterization of light emission is presented and briefly discussed. {copyright} 2001 American Institute of Physics.

  3. Metal sulfide initiators for metal oxide sorbent regeneration

    DOE Patents [OSTI]

    Turk, B.S.; Gupta, R.P.

    1999-06-22

    A process of regenerating a sulfided sorbent is provided. According to the process of the invention, a substantial portion of the energy necessary to initiate the regeneration reaction is provided by the combustion of a particulate metal sulfide additive. In using the particulate metal sulfide additive, the oxygen-containing gas used to regenerate the sulfided sorbent can be fed to the regeneration zone without heating or at a lower temperature than used in conventional processes wherein the regeneration reaction is initiated only by heating the oxygen-containing gas. The particulate metal sulfide additive is preferably an inexpensive mineral ore such as iron pyrite which does not adversely affect the regeneration or corresponding desulfurization reactions. The invention further includes a sorbent composition comprising the particulate metal sulfide additive in admixture with an active metal oxide sorbent capable of removing one or more sulfur compounds from a sulfur-containing gas stream. 1 fig.

  4. Heavy metal movement in metal-contaminated soil profiles

    SciTech Connect (OSTI)

    Li, Zhenbin; Shuman, L.M.

    1996-10-01

    Heavy metal movement in soil profiles is a major environmental concern because even slow transport through the soil may eventually lead to deterioration of groundwater quality. In this study, three metal-contaminated soil (Fuquay, Dothan, and Clarendon) were selected from cropland were a high-metal flue dust had been applied annually for 6 years to raise soil pH, with application ending 4 years before sampling. One uncontaminated soil (Tifton) from the same physiographic area was also sampled as a control. Soil samples were collected in 15-cm increments from the surface to 105 cm in depth. Total contents of Zn, Cd, and Pb in the soils samples were determined. To better understand metal movement in relation to metal fractions in the soil profile, soil samples were also extracted sequentially for exchangeable (EXC), organic matter (OM), Mn oxide (MNO), amorphous Fe oxide (AFEO), crystalline Fe oxide (CFEO), and residual (RES) fractions. 35 refs., 6 figs., 2 tabs.

  5. Status of Light Gaugino Scenarios

    E-Print Network [OSTI]

    Glennys R. Farrar

    1997-10-08

    I summarize recent devlopments in supersymmetry scenarios which leave some or all gauginos light. The emphasis is on experimental and phenomenological progress in the past year.

  6. Fluorescent Lighting | Department of Energy

    Office of Environmental Management (EM)

    - by far the most common form of fluorescent lighting but rarely found in residential buildings -- are much more energy efficient than incandescent lamps and are ideally suited...

  7. Incandescent Lighting | Department of Energy

    Office of Environmental Management (EM)

    courtesy of iStockphotoTokenPhoto. Incandescent lamps are often considered the least energy efficient type of electric lighting commonly found in residential buildings....

  8. Linac Coherent Light Source Overview

    Office of Energy Efficiency and Renewable Energy (EERE)

    Take an animated tour of the Linac Coherent Light Source (LCLS). Follow the laser pulse from the injector gun all the way through to the Far Experimental Hall.

  9. Linac Coherent Light Source Overview

    ScienceCinema (OSTI)

    None

    2013-05-29

    Take an animated tour of the Linac Coherent Light Source (LCLS). Follow the laser pulse from the injector gun all the way through to the Far Experimental Hall.

  10. Common Industrial Lighting Upgrade Technologies

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    is used to regulate the ongoing electricity provided to the lamp. COMMON INDUSTRIAL LIGHTING UPGRADE TECHNOLOGIES Due to the phase-out of the incandescent bulb and magnetic...

  11. Shedding Light on Nanocrystal Defects

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Shedding Light on Nanocrystal Defects Print Nanocrystals have been the focus of much scientific interest lately, given their various advantageous mechanical properties. Their...

  12. Pedestrian-Friendly Nighttime Lighting

    Broader source: Energy.gov [DOE]

    This November 19, 2013 webinar presented issues and considerations related to pedestrian-friendly nighttime lighting, such as color rendering, safety, and adaptation. When it comes to outdoor...

  13. LETTER doi:10.1038/nature12622 Perovskite oxides for visible-light-absorbing

    E-Print Network [OSTI]

    Rappe, Andrew M.

    LETTER doi:10.1038/nature12622 Perovskite oxides for visible-light-absorbing ferroelectric perovskites (with ABO3 composition) is due to the fundamental characteristics of the metal­ oxygen A­O and B cations enable the perovskite oxide to exhibitferroelectricity12 . Owing to a large difference

  14. Thin film hydrous metal oxide catalysts

    DOE Patents [OSTI]

    Dosch, Robert G. (Albuquerque, NM); Stephens, Howard P. (Albuquerque, NM)

    1995-01-01

    Thin film (<100 nm) hydrous metal oxide catalysts are prepared by 1) synthesis of a hydrous metal oxide, 2) deposition of the hydrous metal oxide upon an inert support surface, 3) ion exchange with catalytically active metals, and 4) activating the hydrous metal oxide catalysts.

  15. Non-Destructive Inspection of Adhesive Bonds in Metal-Metal Joints...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Inspection of Adhesive Bonds in Metal-Metal Joints Non-Destructive Inspection of Adhesive Bonds in Metal-Metal Joints 2009 DOE Hydrogen Program and Vehicle Technologies Program...

  16. Histological Features of Pseudotumor-like Tissues From Metal-on-Metal Hips

    E-Print Network [OSTI]

    Campbell, Pat; Ebramzadeh, Edward; Nelson, Scott; Takamura, Karren; Smet, Koen; Amstutz, Harlan C.

    2010-01-01

    Fayyazi A, Flury R, Windler M, Koster G, Lohmann CH. Metal-on-metal bearings and hyper- sensitivity in patients withthe acetabular com- ponent and metal ion levels in metal-on-

  17. Light-by-Light Scattering Effect in Light-Cone Supergraphs

    E-Print Network [OSTI]

    Renata Kallosh; Pierre Ramond

    2010-06-24

    We give a relatively simple explanation of the light-cone supergraph prediction for the UV properties of the maximally supersymmetric theories. It is based on the existence of a dynamical supersymmetry which is not manifest in the light-cone supergraphs. It suggests that N=4 supersymmetric Yang-Mills theory is UV finite and N=8 supergravity is UV finite at least until 7 loops whereas the $n$-point amplitudes have no UV divergences at least until $L=n+3$. Here we show that this prediction can be deduced from the properties of light-cone supergraphs analogous to the light-by-light scattering effect in QED. A technical aspect of the argument relies on the observation that the dynamical supersymmetry action is, in fact, a compensating field-dependent gauge transformation required for the retaining the light-cone gauge condition $A_+=0$.

  18. Expanding hollow metal rings

    DOE Patents [OSTI]

    Peacock, Harold B. (Evans, GA); Imrich, Kenneth J. (Grovetown, GA)

    2009-03-17

    A sealing device that may expand more planar dimensions due to internal thermal expansion of a filler material. The sealing material is of a composition such that when desired environment temperatures and internal actuating pressures are reached, the sealing materials undergoes a permanent deformation. For metallic compounds, this permanent deformation occurs when the material enters the plastic deformation phase. Polymers, and other materials, may be using a sealing mechanism depending on the temperatures and corrosivity of the use. Internal pressures are generated by either rapid thermal expansion or material phase change and may include either liquid or solid to gas phase change, or in the gaseous state with significant pressure generation in accordance with the gas laws. Sealing material thickness and material composition may be used to selectively control geometric expansion of the seal such that expansion is limited to a specific facing and or geometric plane.

  19. Final Scientific/Technical Report "Arc Tube Coating System for Color Consistency"

    SciTech Connect (OSTI)

    Buelow, Roger; Jenson, Chris; Kazenski, Keith

    2013-03-21

    DOE has enabled the use of coating materials using low cost application methods on light sources to positively affect the output of those sources. The coatings and light source combinations have shown increased lumen output of LED fixtures (1.5%-2.0%), LED arrays (1.4%) and LED powered remote phosphor systems â?? Philips L-Prize lamp (0.9%). We have also demonstrated lifetime enhancements (3000 hrs vs 8000 hrs) and shifting to higher CRI (51 to 65) in metal halide high intensity discharge lamps with metal oxide coatings. The coatings on LEDs and LED products are significant as the market is moving increasingly more towards LED technology. Enhancements in LED performance are demonstrated in this work through the use of available materials and low cost application processes. EFOI used low refractive index fluoropolymers and low cost dipping processes for application of the material to surfaces related to light transmission of LEDs and LED products. Materials included Teflon AF, an amorphous fluorinated polymer and fluorinated acrylic monomers. The DOE SSL Roadmap sets goals for LED performance moving into the future. EFOIâ??s coating technology is a means to shift the performance curve for LEDs. This is not limited to one type of LED, but is relevant across LED technologies. The metal halide work included the use of sol-gel solutions resulting in silicon dioxide and titanium dioxide coatings on the quartz substrates of the metal halide arc tubes. The coatings were applied using low cost dipping processes.

  20. Liquid metal thermoacoustic engine

    SciTech Connect (OSTI)

    Swift, G.W.; Migliori, A.; Wheatley, J.C.

    1986-01-01

    We are studying a liquid metal thermoacoustic engine both theoretically and experimentally. This type of engine promises to produce large quantities of electrical energy from heat at modest efficiency with no moving parts. A sound wave is usually thought of as consisting of pressure oscillations, but always attendant to the pressure oscillation are temperature oscillations. The combination produces a rich variety of ''thermoacoustic'' effects. These effects are usually so small that they are never noticed in everyday life; nevertheless under the right circumstances they can be harnessed to produce powerful heat engines, heat pumps, and refrigerators. In our liquid metal thermoacoustic engine, heat flow from a high temperature source to a low temperature sink generates a high-amplitude standing acoustic wave in liquid sodium. This acoustic power is converted to electric power by a simple magnetohydrodynamic effect at the acoustic oscillation frequency. We have developed a detailed thermoacoustic theory applicable to this engine, and find that a reasonably designed liquid sodium engine operating between 700/sup 0/C and 100/sup 0/C should generate about 60 W/cm/sup 2/ of acoustic power at about 1/3 of Carnot's efficiency. Construction of a 3000 W-thermal laboratory model engine has just been completed, and we have exciting preliminary experimental results as of the time of preparation of this manuscript showing, basically, that the engine works. We have also designed and built a 1 kHz liquid sodium magnetohydrodynamic generator and have extensive measurements on it. It is now very well characterized both experimentally and theoretically. The first generator of its kind, it already converts acoustic power to electric power with 40% efficiency. 16 refs., 5 figs.