Sample records for metal based durables

  1. Durable metallized polymer mirror

    DOE Patents [OSTI]

    Schissel, Paul O. (Golden, CO); Kennedy, Cheryl E. (Lafayette, CO); Jorgensen, Gary J. (Pine, CO); Shinton, Yvonne D. (Northglenn, CO); Goggin, Rita M. (Englewood, CO)

    1994-01-01T23:59:59.000Z

    A metallized polymer mirror construction having improved durability against delamination and tunneling, comprising: an outer layer of polymeric material; a metal oxide layer underlying the outer layer of polymeric material; a silver reflective layer underneath the metal oxide layer; and a layer of adhesive attaching the silver layer to a substrate.

  2. Durable metallized polymer mirror

    DOE Patents [OSTI]

    Schissel, P.O.; Kennedy, C.E.; Jorgensen, G.J.; Shinton, Y.D.; Goggin, R.M.

    1994-11-01T23:59:59.000Z

    A metallized polymer mirror construction is disclosed having improved durability against delamination and tunneling, comprising: an outer layer of polymeric material; a metal oxide layer underlying the outer layer of polymeric material; a silver reflective layer underneath the metal oxide layer; and a layer of adhesive attaching the silver layer to a substrate. 6 figs.

  3. Impact of Biodiesel Metals on the Performance and Durability...

    Broader source: Energy.gov (indexed) [DOE]

    Impact of Biodiesel Metals on the Performance and Durability of DOC and DPF Technologies Impact of Biodiesel Metals on the Performance and Durability of DOC and DPF Technologies...

  4. Durability of Metallic Interconnects and Protective Coatings

    SciTech Connect (OSTI)

    Yang, Zhenguo; Stevenson, Jeffry W.

    2009-12-15T23:59:59.000Z

    To build up a useful voltage, a number of solid oxide fuel cells (SOFCs) are electrically connected into series in a stack via interconnects, which are placed between adjacent cells. In addition to functioning as a bi-polar electrical connector, the interconnect also acts as a separator plate that separates the fuel at the anode side of one cell from the air at the cathode side on an adjacent cell. During SOFC operation at the high temperatures, the interconnects are thus simultaneously exposed to the oxidizing air at one side and a reducing fuel that can be either hydrogen or hydrocarbon at the other. Besides, they are in contact with adjacent components, such as electrodes or electrical contacts, seals, etc. With steady reduction in SOFC operating temperatures into the low or intermediate range 600-850oC, oxidation resistant alloys are often used to construct interconnects. However, the metallic interconnects may degrade via interactions at their interfaces with surrounding environments or adjacent components, potentially affecting the stability and performance of interconnects and the SOFC stacks. Thus protection layers are applied to metallic interconnects that also intend to mitigate or prevent chromium migration into cells and the cell poisoning. This chapter provides a comprehensive review of materials for metallic interconnects, their degradation and coating protection.

  5. Durable pd-based alloy and hydrogen generation membrane thereof

    DOE Patents [OSTI]

    Benn, Raymond C. (Madison, CT); Opalka, Susanne M. (Glastonbury, CT); Vanderspurt, Thomas Henry (Glastonbury, CT)

    2010-02-02T23:59:59.000Z

    A durable Pd-based alloy is used for a H.sub.2-selective membrane in a hydrogen generator, as in the fuel processor of a fuel cell plant. The Pd-based alloy includes Cu as a binary element, and further includes "X", where "X" comprises at least one metal from group "M" that is BCC and acts to stabilize the .beta. BCC phase for stability during operating temperatures. The metal from group "M" is selected from the group consisting of Fe, Cr, Nb, Ta, V, Mo, and W, with Nb and Ta being most preferred. "X" may further comprise at least one metal from a group "N" that is non-BCC, preferably FCC, that enhances other properties of the membrane, such as ductility. The metal from group "N" is selected from the group consisting of Ag, Au, Re, Ru, Rh, Y, Ce, Ni, Ir, Pt, Co, La and In. The at. % of Pd in the binary Pd--Cu alloy ranges from about 35 at. % to about 55 at. %, and the at. % of "X" in the higher order alloy, based on said binary alloy, is in the range of about 1 at. % to about 15 at. %. The metals are selected according to a novel process.

  6. Durability-Based Design Guide for an Automotive Structural Composite: Part 2. Background Data and Models

    SciTech Connect (OSTI)

    Corum, J.M. [ORNL; Battiste, R.L. [ORNL; Brinkman, C.R. [ORNL; Ren, W. [ORNL; Ruggles, M.B. [ORNL; Weitsman, Y.J. [ORNL; Yahr, G.T. [ORNL

    1998-02-01T23:59:59.000Z

    This background report is a companion to the document entitled ''Durability-Based Design Criteria for an Automotive Structural Composite: Part 1. Design Rules'' (ORNL-6930). The rules and the supporting material characterization and modeling efforts described here are the result of a U.S. Department of Energy Advanced Automotive Materials project entitled ''Durability of Lightweight Composite Structures.'' The overall goal of the project is to develop experimentally based, durability-driven design guidelines for automotive structural composites. The project is closely coordinated with the Automotive Composites Consortium (ACC). The initial reference material addressed by the rules and this background report was chosen and supplied by ACC. The material is a structural reaction injection-molded isocyanurate (urethane), reinforced with continuous-strand, swirl-mat, E-glass fibers. This report consists of 16 position papers, each summarizing the observations and results of a key area of investigation carried out to provide the basis for the durability-based design guide. The durability issues addressed include the effects of cyclic and sustained loadings, temperature, automotive fluids, vibrations, and low-energy impacts (e.g., tool drops and roadway kickups) on deformation, strength, and stiffness. The position papers cover these durability issues. Topics include (1) tensile, compressive, shear, and flexural properties; (2) creep and creep rupture; (3) cyclic fatigue; (4) the effects of temperature, environment, and prior loadings; (5) a multiaxial strength criterion; (6) impact damage and damage tolerance design; (7) stress concentrations; (8) a damage-based predictive model for time-dependent deformations; (9) confirmatory subscale component tests; and (10) damage development and growth observations.

  7. Induction furnace testing of the durability of prototype crucibles in a molten metal environment

    SciTech Connect (OSTI)

    Jablonski, Paul D.

    2005-09-01T23:59:59.000Z

    Engineered ceramic crucibles are commonly used to contain molten metal. Besides high temperature stability, other desired crucible characteristics include thermal shock resistance, minimal reaction with the molten metal and resistance to attack from the base metal oxide formed during melting. When used in an induction furnace, they can be employed as a “semi-permanent” crucible incorporating a dry ram backup and a ceramic cap. This report covers several 250-lb single melt crucible tests in an air melt induction furnace. These tests consisted of melting a charge of 17-4PH stainless steel, holding the charge molten for two hours before pouring off the heat and then subsequently sectioning the crucible to review the extent of erosion, penetration and other physical characteristics. Selected temperature readings were made throughout each melt. Chemistry samples were also taken from each heat periodically throughout the hold. The manganese level was observed to affect the rate of chromium loss in a non-linear fashion.

  8. Carbon nanotubes based ultrasonic microtransducers for durability monitoring Aligned carbon nanotubes based ultrasonic microtransducers

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    -mail: berengere.lebental@ifsttar.fr Abstract: Structural health monitoring of porous materials such as concrete facilities. Durability in porous materials depends on nanoscale features which need to be monitored in a porous material in order to provide with information on its durability by monitoring in-situ neighboring

  9. ADVANCED COMPOSITE WIND TURBINE BLADE DESIGN BASED ON DURABILITY AND DAMAGE TOLERANCE

    SciTech Connect (OSTI)

    Galib Abumeri; Frank Abdi (PhD)

    2012-02-16T23:59:59.000Z

    The objective of the program was to demonstrate and verify Certification-by-Analysis (CBA) capability for wind turbine blades made from advanced lightweight composite materials. The approach integrated durability and damage tolerance analysis with robust design and virtual testing capabilities to deliver superior, durable, low weight, low cost, long life, and reliable wind blade design. The GENOA durability and life prediction software suite was be used as the primary simulation tool. First, a micromechanics-based computational approach was used to assess the durability of composite laminates with ply drop features commonly used in wind turbine applications. Ply drops occur in composite joints and closures of wind turbine blades to reduce skin thicknesses along the blade span. They increase localized stress concentration, which may cause premature delamination failure in composite and reduced fatigue service life. Durability and damage tolerance (D&DT) were evaluated utilizing a multi-scale micro-macro progressive failure analysis (PFA) technique. PFA is finite element based and is capable of detecting all stages of material damage including initiation and propagation of delamination. It assesses multiple failure criteria and includes the effects of manufacturing anomalies (i.e., void, fiber waviness). Two different approaches have been used within PFA. The first approach is Virtual Crack Closure Technique (VCCT) PFA while the second one is strength-based. Constituent stiffness and strength properties for glass and carbon based material systems were reverse engineered for use in D&DT evaluation of coupons with ply drops under static loading. Lamina and laminate properties calculated using manufacturing and composite architecture details matched closely published test data. Similarly, resin properties were determined for fatigue life calculation. The simulation not only reproduced static strength and fatigue life as observed in the test, it also showed composite damage and fracture modes that resemble those reported in the tests. The results show that computational simulation can be relied on to enhance the design of tapered composite structures such as the ones used in turbine wind blades. A computational simulation for durability, damage tolerance (D&DT) and reliability of composite wind turbine blade structures in presence of uncertainties in material properties was performed. A composite turbine blade was first assessed with finite element based multi-scale progressive failure analysis to determine failure modes and locations as well as the fracture load. D&DT analyses were then validated with static test performed at Sandia National Laboratories. The work was followed by detailed weight analysis to identify contribution of various materials to the overall weight of the blade. The methodology ensured that certain types of failure modes, such as delamination progression, are contained to reduce risk to the structure. Probabilistic analysis indicated that composite shear strength has a great influence on the blade ultimate load under static loading. Weight was reduced by 12% with robust design without loss in reliability or D&DT. Structural benefits obtained with the use of enhanced matrix properties through nanoparticles infusion were also assessed. Thin unidirectional fiberglass layers enriched with silica nanoparticles were applied to the outer surfaces of a wind blade to improve its overall structural performance and durability. The wind blade was a 9-meter prototype structure manufactured and tested subject to three saddle static loading at Sandia National Laboratory (SNL). The blade manufacturing did not include the use of any nano-material. With silica nanoparticles in glass composite applied to the exterior surfaces of the blade, the durability and damage tolerance (D&DT) results from multi-scale PFA showed an increase in ultimate load of the blade by 9.2% as compared to baseline structural performance (without nano). The use of nanoparticles lead to a delay in the onset of delamination. Load-displacement relati

  10. Durable Zinc Oxide-Based Regenerable Sorbents for Desulfurization

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem Not Found Item Not Found The itemAIR57451 CleanFOR IMMEDIATEDurable Zinc Oxide-Based

  11. Chemically durable nitrogen containing phosphate glasses useful for sealing to metals

    DOE Patents [OSTI]

    Day, Delbert E. (Rolla, MO); Wilder, Jr., James A. (Albuquerque, NM)

    1984-01-01T23:59:59.000Z

    The chemical durability of alkali phosphate glasses is improved by incorporation of up to 23 weight percent of nitrogen. A typical phosphate glass contains: 10 to 60 mole % of Li.sub.2 O, Na.sub.2 O or K.sub.2 O; 5-40 mole % of BaO or CAO; 0-1 to 10 mole % of Al.sub.2 O.sub.3 ; and 40-70 mole % of P.sub.2 O.sub.5. Nitrides, such as AlN, are the favored additives.

  12. On Coating Durability of Polymer Coated Sheet Metal under Plastic Deformation 

    E-Print Network [OSTI]

    Huang, Yu-Hsuan

    2011-08-08T23:59:59.000Z

    Polymer coated sheet metal components find diverse applications in many industries. The manufacturing of the components generally involves forming of sheet metal into the desired shape and coating of the formed part with organic coating...

  13. Impact of Fuel Metal Impurities on the Durability of a Light-Duty Diesel Aftertreatment System

    SciTech Connect (OSTI)

    Williams, A.; Burton, J.; McCormick, R. L.; Toops, T.; Wereszczak, A. A.; Fox, E. E.; Lance, M. J.; Cavataio, G.; Dobson, D.; Warner, J.; Brezny, R.; Nguyen, K.; Brookshear, D. W.

    2013-04-01T23:59:59.000Z

    Alkali and alkaline earth metal impurities found in diesel fuels are potential poisons for diesel exhaust catalysts. A set of diesel engine production exhaust systems was aged to 150,000 miles. These exhaust systems included a diesel oxidation catalyst, selective catalytic reduction (SCR) catalyst, and diesel particulate filter (DPF). Four separate exhaust systems were aged, each with a different fuel: ultralow sulfur diesel containing no measureable metals, B20 (a common biodiesel blend) containing sodium, B20 containing potassium, and B20 containing calcium, which were selected to simulate the maximum allowable levels in B100 according to ASTM D6751. Analysis included Federal Test Procedure emissions testing, bench-flow reactor testing of catalyst cores, electron probe microanalysis (EPMA), and measurement of thermo-mechanical properties of the DPFs. EPMA imaging found that the sodium and potassium penetrated into the washcoat, while calcium remained on the surface. Bench-flow reactor experiments were used to measure the standard nitrogen oxide (NOx) conversion, ammonia storage, and ammonia oxidation for each of the aged SCR catalysts. Vehicle emissions tests were conducted with each of the aged catalyst systems using a chassis dynamometer. The vehicle successfully passed the 0.2 gram/mile NOx emission standard with each of the four aged exhaust systems.

  14. Durability-Based Design Criteria for a Quasi-Isotropic Carbon-Fiber-Reinforced Thermoplastic Automotive Composite

    SciTech Connect (OSTI)

    Naus, Dan J [ORNL; Corum, James [ORNL; Klett, Lynn B [ORNL; Davenport, Mike [ORNL; Battiste, Rick [ORNL; Simpson, Jr., William A [ORNL

    2006-04-01T23:59:59.000Z

    This report provides recommended durability-based design properties and criteria for a quais-isotropic carbon-fiber thermoplastic composite for possible automotive structural applications. The composite consisted of a PolyPhenylene Sulfide (PPS) thermoplastic matrix (Fortron's PPS - Ticona 0214B1 powder) reinforced with 16 plies of carbon-fiber unidirectional tape, [0?/90?/+45?/-45?]2S. The carbon fiber was Hexcel AS-4C and was present in a fiber volume of 53% (60%, by weight). The overall goal of the project, which is sponsored by the U.S. Department of Energy's Office of Freedom Car and Vehicle Technologies and is closely coordinated with the Advanced Composites Consortium, is to develop durability-driven design data and criteria to assure the long-term integrity of carbon-fiber-based composite systems for automotive structural applications. This document is in two parts. Part 1 provides design data and correlations, while Part 2 provides the underlying experimental data and models. The durability issues addressed include the effects of short-time, cyclic, and sustained loadings; temperature; fluid environments; and low-energy impacts (e.g., tool drops and kickups of roadway debris) on deformation, strength, and stiffness. Guidance for design analysis, time-independent and time-dependent allowable stresses, rules for cyclic loadings, and damage-tolerance design guidance are provided.

  15. Optical durability testing of candidate solar mirrors

    SciTech Connect (OSTI)

    Jorgensen, G.; Kennedy, C.; King, D.; Terwilliger, K.

    2000-03-24T23:59:59.000Z

    Durability testing of a variety of candidate solar reflector materials at outdoor test sites and in laboratory accelerated weathering chambers is the main activity within the Advanced Materials task of the Concentrated Solar Power (CSP) Program. Outdoor exposure testing (OET) at up to eight outdoor, worldwide exposure sites has been underway for several years. This includes collaboration under the auspices of the International Energy Agency (IEA) Solar Power and Chemical Energy Systems (SolarPACES) agreement. Outdoor sites are fully instrumented in terms of monitoring meteorological conditions and solar irradiance. Candidate materials are optically characterized prior to being subjected to exposure in real and simulated weathering environments. Optical durability is quantified by periodically re-measuring hemispherical and specular reflectance as a function of exposure time. By closely monitoring the site- and time-dependent environmental stress conditions experienced by the material samples, site-dependent loss of performance may be quantified. In addition, accelerated exposure testing (AET) of these materials in parallel under laboratory-controlled conditions may permit correlating the outdoor results with AET, and subsequently predicting service lifetimes. Test results to date for a large number of candidate solar reflector materials are presented in this report. Acronyms are defined. Based upon OET and AET results to date, conclusions can be drawn about the optical durability of the candidate reflector materials. The optical durability of thin glass, thick glass, and two metallized polymers can be characterized as excellent. The all-polymeric construction, several of the aluminized reflectors, and a metallized polymer can be characterized as having intermediate durability and require further improvement, testing and evaluation, or both.

  16. Durable silver coating for mirrors

    DOE Patents [OSTI]

    Wolfe, Jesse D. (Discovery Bay, CA); Thomas, Norman L. (Livermore, CA)

    2000-01-01T23:59:59.000Z

    A durable multilayer mirror includes reflective layers of aluminum and silver and has high reflectance over a broad spectral range from ultraviolet to visible to infrared. An adhesion layer of a nickel and/or chromium alloy or nitride is deposited on an aluminum surface, and a thin layer of silver is then deposited on the adhesion layer. The silver layer is protected by a passivation layer of a nickel and/or chromium alloy or nitride and by one or more durability layers made of metal oxides and typically a first layer of metal nitride. The durability layers may include a composite silicon aluminum nitride and an oxinitride transition layer to improve bonding between nitride and oxide layers.

  17. Duct Tape Durability Testing

    SciTech Connect (OSTI)

    Sherman, Max H.; Walker, Iain S.

    2004-04-01T23:59:59.000Z

    Duct leakage is a major source of energy loss in residential buildings. Most duct leakage occurs at the connections to registers, plenums, or branches in the duct system. At each of these connections, a method of sealing the duct system is required. Typical sealing methods include tapes or mastics applied around the joints in the system. Field examinations of duct systems have shown that taped seals tend to fail over extended periods of time. The Lawrence Berkeley National Laboratory (LBNL) has been testing sealant durability for several years using accelerated test methods and found that typical duct tape (i.e., cloth-backed tapes with natural rubber adhesives) fails more rapidly than other duct sealants. This report summarizes the results of duct sealant durability testing over two years for four UL 181B-FX listed duct tapes (two cloth tapes, a foil tape and an Oriented Polypropylene (OPP) tape). One of the cloth tapes was specifically developed in collaboration with a tape manufacturer to perform better in our durability testing. The tests involved the aging of common ''core-to-collar joints'' of flexible duct to sheet metal collars. Periodic air leakage tests and visual inspection were used to document changes in sealant performance. After two years of testing, the flex-to-collar connections showed little change in air leakage, but substantial visual degradation from some products. A surprising experimental result was failure of most of the clamps used to mechanically fasten the connections. This indicates that the durability of clamps also need to be addressed ensure longevity of the duct connection. An accelerated test method developed during this study has been used as the basis for an ASTM standard (E2342-03).

  18. Probabilistic analysis of turbine blade durability

    E-Print Network [OSTI]

    Kountras, Apostolos, 1970-

    2004-01-01T23:59:59.000Z

    The effect of variability on turbine blade durability was assessed for seven design/operating parameters in three blade designs. The parameters included gas path and cooling convective parameters, metal and coating thermal ...

  19. Development of Highly Durable and Reactive Regenerable Magnesium-Based Sorbents for CO2 Separation in Coal Gasification Process

    SciTech Connect (OSTI)

    Javad Abbasian; Armin Hassanzadeh Khayyat; Rachid B. Slimane

    2005-06-01T23:59:59.000Z

    The specific objective of this project was to develop physically durable and chemically regenerable MgO-based sorbents that can remove carbon dioxide from raw coal gas at operating condition prevailing in IGCC processes. A total of sixty two (62) different sorbents were prepared in this project. The sorbents were prepared either by various sol-gel techniques (22 formulations) or modification of dolomite (40 formulations). The sorbents were prepared in the form of pellets and in granular forms. The solgel based sorbents had very high physical strength, relatively high surface area, and very low average pore diameter. The magnesium content of the sorbents was estimated to be 4-6 % w/w. To improve the reactivity of the sorbents toward CO{sub 2}, The sorbents were impregnated with potassium salts. The potassium content of the sorbents was about 5%. The dolomite-based sorbents were prepared by calcination of dolomite at various temperature and calcination environment (CO{sub 2} partial pressure and moisture). Potassium carbonate was added to the half-calcined dolomite through wet impregnation method. The estimated potassium content of the impregnated sorbents was in the range of 1-6% w/w. In general, the modified dolomite sorbents have significantly higher magnesium content, larger pore diameter and lower surface area, resulting in significantly higher reactivity compared to the sol-gel sorbents. The reactivities of a number of sorbents toward CO{sub 2} were determined in a Thermogravimetric Analyzer (TGA) unit. The results indicated that at the low CO{sub 2} partial pressures (i.e., 1 atm), the reactivities of the sorbents toward CO{sub 2} are very low. At elevated pressures (i.e., CO{sub 2} partial pressure of 10 bar) the maximum conversion of MgO obtained with the sol-gel based sorbents was about 5%, which corresponds to a maximum CO{sub 2} absorption capacity of less than 1%. The overall capacity of modified dolomite sorbents were at least one order of magnitude higher than those of the sol-gel based sorbents. The results of the tests conducted with various dolomite-based sorbent indicate that the reactivity of the modified dolomite sorbent increases with increasing potassium concentration, while higher calcination temperature adversely affects the sorbent reactivity. Furthermore, the results indicate that as long as the absorption temperature is well below the equilibrium temperature, the reactivity of the sorbent improves with increasing temperature (350-425 C). As the temperature approaches the equilibrium temperature, because of the significant increase in the rate of reverse (i.e., regeneration) reaction, the rate of CO{sub 2} absorption decreases. The results of cyclic tests show that the reactivity of the sorbent gradually decreases in the cyclic process. To improve long-term durability (i.e., reactivity and capacity) of the sorbent, the sorbent was periodically re-impregnated with potassium additive and calcined. The results indicate that, in general, re-treatment improves the performance of the sorbent, and that, the extent of improvement gradually decreases in the cyclic process. The presence of steam significantly enhances the sorbent reactivity and significantly decreases the rate of decline in sorbent deactivation in the cyclic process.

  20. Chemomechanics of calcium leaching of cement-based materials at different scales : the role of CH-dissolution and C-S-H degradation on strength and durability performance of materials and structures

    E-Print Network [OSTI]

    Heukamp, Franz H. (Franz Hoyte), 1973-

    2003-01-01T23:59:59.000Z

    Calcium leaching is a durability threat for cement-based materials employed in critical infrastructures, such as Nuclear Waste Storage Systems. This thesis presents a comprehensive study of the material and structural ...

  1. Lewis Acid-Base Interactions between Polysulfides and Metal Organic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lewis Acid-Base Interactions between Polysulfides and Metal Organic Framework in Lithium Sulfur Batteries. Lewis Acid-Base Interactions between Polysulfides and Metal Organic...

  2. Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control Catalysts Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control Catalysts Presents...

  3. DOE Award No. DE-FC36-03GO13108 NOVEL NON-PRECIOUS METAL CATALYSTS FOR PEMFC: CATALYST SELECTION THROUGH MOLECULAR MODELING AND DURABILITY STUDIES Final Report (September 2003 – October 2008)

    SciTech Connect (OSTI)

    Branko N. Popov

    2009-03-03T23:59:59.000Z

    The objective of this project is to develop novel non-precious metal electrocatalysts for oxygen reduction reaction (ORR), and demonstrate the potential of the catalysts to perform at least as good as conventional Pt catalysts currently in use in polymer electrolyte membrane fuel cell (PEMFC) with a cost at least 50 % less than a target of 0.2 g (Pt loading)/peak kW and with durability > 2,000 h operation with less than 10 % power degradation. A novel nitrogen-modified carbon-based catalyst was obtained by modifying carbon black with nitrogen-containing organic precursor in the absence of transition metal precursor. The catalyst shows the onset potential of approximately 0.76 V (NHE) for ORR and the amount of H2O2 of approximately 3% at 0.5 V (NHE). Furthermore, a carbon composite catalyst was achieved through the high-temperature pyrolysis of the precursors of transition metal (Co and Fe) and nitrogen supported on the nitrogen-modified carbon-based catalyst, followed by chemical post-treatment. This catalyst showed an onset potential for ORR as high as 0.87 V (NHE), and generated less than 1 % of H2O2. The PEM fuel cell exhibited a current density of 2.3 A cm-2 at 0.2 V for a catalyst loading of 6.0 mg cm-2. No significant performance degradation was observed for 480 h continuous operation. The characterization studies indicated that the metal-nitrogen chelate complexes decompose at the temperatures above 800 oC. During the pyrolysis, the transition metals facilitate the incorporation of pyridinic and graphitic nitrogen groups into the carbon matrix, and the carbon surface modified with nitrogen is active for ORR. In order to elucidate the role of transition metal precursor played in the formation of active sites in the non-precious metal catalysts, a novel ruthenium-based chelate (RuNx) catalyst was synthesized by using RuCl3 and propylene diammine as the Ru and N precursors, respectively, followed by high-temperature pyrolysis. This catalyst exhibited comparable catalytic activity and selectivity for ORR as the Pt catalyst. A theoretical analysis is made of the four-electron reduction reaction of oxygen to water over the mixed anion and cation (202) surface of pentlandite structure Co9Se8, one of several selenide phases. Reversible potentials for forming adsorbed reaction intermediates in acid are predicted using adsorption energies calculated with the Vienna ab initio simulation program (VASP) and the known bulk solution values together in a linear Gibbs energy relationship. The effect of hydrophobic and structural properties of a single/dual-layer cathode gas diffusion layer on mass transport in PEM fuel cells was studied using an analytical expression. The simulations indicated that liquid water transport at the cathode is controlled by the fraction of hydrophilic surface and the average pore diameter in the cathode gas diffusion layer. The optimized hydrophobicity and pore geometry in a dual-layer cathode GDL leads to an effective water management, and enhances the oxygen diffusion kinetics.

  4. DOE Award No. DE-FC36-03GO13108 NOVEL NON-PRECIOUS METAL CATALYSTS FOR PEMFC: CATALYST SELECTION THROUGH MOLECULAR MODELING AND DURABILITY STUDIES Final Report (September 2003 – October 2008)

    SciTech Connect (OSTI)

    Branko N. Popov

    2009-02-20T23:59:59.000Z

    The objective of this project is to develop novel non-precious metal electrocatalysts for oxygen reduction reaction (ORR), and demonstrate the potential of the catalysts to perform at least as good as conventional Pt catalysts currently in use in polymer electrolyte membrane fuel cell (PEMFC) with a cost at least 50 % less than a target of 0.2 g (Pt loading)/peak kW and with durability > 2,000 h operation with less than 10 % power degradation. A novel nitrogen-modified carbon-based catalyst was obtained by modifying carbon black with nitrogen-containing organic precursor in the absence of transition metal precursor. The catalyst shows the onset potential of approximately 0.76 V (NHE) for ORR and the amount of H2O2 of approximately 3% at 0.5 V (NHE). Furthermore, a carbon composite catalyst was achieved through the high-temperature pyrolysis of the precursors of transition metal (Co and Fe) and nitrogen supported on the nitrogen-modified carbon-based catalyst, followed by chemical post-treatment. This catalyst showed an onset potential for ORR as high as 0.87 V (NHE), and generated less than 1 % of H2O2. The PEM fuel cell exhibited a current density of 2.3 A cm-2 at 0.2 V for a catalyst loading of 6.0 mg cm-2. No significant performance degradation was observed for 480 h continuous operation. The characterization studies indicated that the metal-nitrogen chelate complexes decompose at the temperatures above 800 oC. During the pyrolysis, the transition metals facilitate the incorporation of pyridinic and graphitic nitrogen groups into the carbon matrix, and the carbon surface modified with nitrogen is active for ORR. In order to elucidate the role of transition metal precursor played in the formation of active sites in the non-precious metal catalysts, a novel ruthenium-based chelate (RuNx) catalyst was synthesized by using RuCl3 and propylene diammine as the Ru and N precursors, respectively, followed by high-temperature pyrolysis. This catalyst exhibited comparable catalytic activity and selectivity for ORR as the Pt catalyst. A theoretical analysis is made of the four-electron reduction reaction of oxygen to water over the mixed anion and cation (202) surface of pentlandite structure Co9Se8, one of several selenide phases. Reversible potentials for forming adsorbed reaction intermediates in acid are predicted using adsorption energies calculated with the Vienna ab initio simulation program (VASP) and the known bulk solution values together in a linear Gibbs energy relationship. The effect of hydrophobic and structural properties of a single/dual-layer cathode gas diffusion layer on mass transport in PEM fuel cells was studied using an analytical expression. The simulations indicated that liquid water transport at the cathode is controlled by the fraction of hydrophilic surface and the average pore diameter in the cathode gas diffusion layer. The optimized hydrophobicity and pore geometry in a dual-layer cathode GDL leads to an effective water management, and enhances the oxygen diffusion kinetics.

  5. Highly Dispersed Alloy Catalyst for Durability

    SciTech Connect (OSTI)

    Vivek S. Murthi (Primary Contact), Elise Izzo, Wu Bi, Sandra Guerrero and Lesia Protsailo

    2013-01-08T23:59:59.000Z

    Achieving DOE�¢����s stated 5000-hr durability goal for light-duty vehicles by 2015 will require MEAs with characteristics that are beyond the current state of the art. Significant effort was placed on developing advanced durable cathode catalysts to arrive at the best possible electrode for high performance and durability, as well as developing manufacturing processes that yield significant cost benefit. Accordingly, the overall goal of this project was to develop and construct advanced MEAs that will improve performance and durability while reducing the cost of PEMFC stacks. The project, led by UTC Power, focused on developing new catalysts/supports and integrating them with existing materials (membranes and gas diffusion layers (GDLs)) using state-of-the-art fabrication methods capable of meeting the durability requirements essential for automotive applications. Specifically, the project work aimed to lower platinum group metals (PGM) loading while increasing performance and durability. Appropriate catalysts and MEA configuration were down-selected that protects the membrane, and the layers were tailored to optimize the movements of reactants and product water through the cell to maximize performance while maintaining durability.

  6. Base metal dehydrogenation of amine-boranes

    DOE Patents [OSTI]

    Blacquiere, Johanna Marie (Ottawa, CA); Keaton, Richard Jeffrey (Pearland, TX); Baker, Ralph Thomas (Los Alamos, NM)

    2009-06-09T23:59:59.000Z

    A method of dehydrogenating an amine-borane having the formula R.sup.1H.sub.2N--BH.sub.2R.sup.2 using base metal catalyst. The method generates hydrogen and produces at least one of a [R.sup.1HN--BHR.sup.2].sub.m oligomer and a [R.sup.1N--BR.sup.2].sub.n oligomer. The method of dehydrogenating amine-boranes may be used to generate H.sub.2 for portable power sources, such as, but not limited to, fuel cells.

  7. Investigating the durability of structures

    E-Print Network [OSTI]

    Saba, Dana (Dana Walid)

    2013-01-01T23:59:59.000Z

    The durability of structures is one of primary concerns in the engineering industry. Poor durability in design may result in a structure losing its performance to the extent where structural integrity is no longer satisfied ...

  8. Highly durable graphene nanoplatelets supported Pt nanocatalysts...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    durable graphene nanoplatelets supported Pt nanocatalysts for oxygen reduction . Highly durable graphene nanoplatelets supported Pt nanocatalysts for oxygen reduction . Abstract:...

  9. Sintering and ripening resistant noble metal nanostructures

    DOE Patents [OSTI]

    van Swol, Frank B; Song, Yujiang; Shelnutt, John A; Miller, James E; Challa, Sivakumar R

    2013-09-24T23:59:59.000Z

    Durable porous metal nanostructures comprising thin metal nanosheets that are metastable under some conditions that commonly produce rapid reduction in surface area due to sintering and/or Ostwald ripening. The invention further comprises the method for making such durable porous metal nanostructures. Durable, high-surface area nanostructures result from the formation of persistent durable holes or pores in metal nanosheets formed from dendritic nanosheets.

  10. Deactivation Mechanisms of Base Metal/Zeolite Urea Selective...

    Broader source: Energy.gov (indexed) [DOE]

    peden16807.pdf More Documents & Publications Understanding the Deactivation Mechanisms of CuZeolite SCR Catalysts in Diesel Application Deactivation Mechanisms of Base Metal...

  11. Low Cost, Durable Seal

    SciTech Connect (OSTI)

    Roberts, George; Parsons, Jason; Friedman, Jake

    2010-12-17T23:59:59.000Z

    Seal durability is critical to achieving the 2010 DOE operational life goals for both stationary and transportation PEM fuel cell stacks. The seal material must be chemically and mechanically stable in an environment consisting of aggressive operating temperatures, humidified gases, and acidic membranes. The seal must also be producible at low cost. Currentlyused seal materials do not meet all these requirements. This project developed and demonstrated a high consistency hydrocarbon rubber seal material that was able to meet the DOE technical and cost targets. Significant emphasis was placed on characterization of the material and full scale molding demonstrations.

  12. Metal-Organic Frameworks Based on Main Group Metals

    E-Print Network [OSTI]

    Zhao, Xiang

    2011-01-01T23:59:59.000Z

    supramolecular assemblies and another pathway to make lithium based crystalline porous materials.Supramolecular Assemblies Using Lithium Cubane Clusters as Novel Tectonics Introduction The designed synthesis of crystalline porous materials (

  13. DURABLE GLASS FOR THOUSANDS OF YEARS

    SciTech Connect (OSTI)

    Jantzen, C.

    2009-12-04T23:59:59.000Z

    The durability of natural glasses on geological time scales and ancient glasses for thousands of years is well documented. The necessity to predict the durability of high level nuclear waste (HLW) glasses on extended time scales has led to various thermodynamic and kinetic approaches. Advances in the measurement of medium range order (MRO) in glasses has led to the understanding that the molecular structure of a glass, and thus the glass composition, controls the glass durability by establishing the distribution of ion exchange sites, hydrolysis sites, and the access of water to those sites. During the early stages of glass dissolution, a 'gel' layer resembling a membrane forms through which ions exchange between the glass and the leachant. The hydrated gel layer exhibits acid/base properties which are manifested as the pH dependence of the thickness and nature of the gel layer. The gel layer ages into clay or zeolite minerals by Ostwald ripening. Zeolite mineral assemblages (higher pH and Al{sup 3+} rich glasses) may cause the dissolution rate to increase which is undesirable for long-term performance of glass in the environment. Thermodynamic and structural approaches to the prediction of glass durability are compared versus Ostwald ripening.

  14. Durable silver mirror with ultra-violet thru far infra-red reflection

    DOE Patents [OSTI]

    Wolfe, Jesse D. (Discovery Bay, CA)

    2010-11-23T23:59:59.000Z

    A durable highly reflective silver mirror characterized by high reflectance in a broad spectral range of about 300 nm in the UV to the far infrared (.about.10000 nm), as well as exceptional environmental durability. A high absorptivity metal underlayer is used which prevents the formation of a galvanic cell with a silver layer while increasing the reflectance of the silver layer. Environmentally durable overcoat layers are provided to enhance mechanical and chemical durability and protect the silver layer from corrosion and tarnishing, for use in a wide variety of surroundings or climates, including harsh or extreme environments.

  15. Durable Fuel Cell Membrane Electrode Assembly (MEA)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Durable Fuel Cell Membrane Electrode Assembly (MEA) Durable Fuel Cell Membrane Electrode Assembly (MEA) A revolutionary method of building a membrane electrode assembly (MEA) for...

  16. Durability of Polymeric Glazing and Absorber Materials

    SciTech Connect (OSTI)

    Jorgensen, G.; Terwilliger, K.; Bingham, C.; Lindquist, C.; Milbourne, M.

    2005-11-01T23:59:59.000Z

    The Solar Heating and Lighting Program has set the goal of reducing the cost of solar water heating systems by at least 50%. An attractive approach to such large cost reduction is to replace glass and metal parts with less-expensive, lighter-weight, more-integrated polymeric components. The key challenge with polymers is to maintain performance and assure requisite durability for extended lifetimes. We have begun evaluation of several new UV-screened polycarbonate sheet glazing constructions. This has involved interactions with several major polymer industry companies to obtain improved candidate samples. Proposed absorber materials were tested for UV resistance, and appear adequate for unglazed ICS absorbers.

  17. african base metal: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and analysis of lateral SiC N-emitter SiGe P-base Schottky metal-collector (NPM) HBT on SOI Engineering Websites Summary: on SOI M. Jagadesh Kumar *, C. Linga Reddy...

  18. Method of determining glass durability

    DOE Patents [OSTI]

    Jantzen, C.M.; Pickett, J.B.; Brown, K.G.; Edwards, T.B.

    1998-12-08T23:59:59.000Z

    A process is described for determining one or more leachate concentrations of one or more components of a glass composition in an aqueous solution of the glass composition by identifying the components of the glass composition, including associated oxides, determining a preliminary glass dissolution estimator, {Delta}G{sub p}, based upon the free energies of hydration for the component reactant species, determining an accelerated glass dissolution function, {Delta}G{sub a}, based upon the free energy associated with weak acid dissociation, {Delta}G{sub a}{sup WA}, and accelerated matrix dissolution at high pH, {Delta}G{sub a}{sup SB} associated with solution strong base formation, and determining a final hydration free energy, {Delta}G{sub f}. This final hydration free energy is then used to determine leachate concentrations for elements of interest using a regression analysis and the formula log{sub 10}(N C{sub i}(g/L))=a{sub i} + b{sub i}{Delta}G{sub f}. The present invention also includes a method to determine whether a particular glass to be produced will be homogeneous or phase separated. The present invention is also directed to methods of monitoring and controlling processes for making glass using these determinations to modify the feedstock materials until a desired glass durability and homogeneity is obtained. 4 figs.

  19. Method of determining glass durability

    DOE Patents [OSTI]

    Jantzen, Carol Maryanne (Aiken, SC); Pickett, John Butler (Aiken, SC); Brown, Kevin George (Augusta, GA); Edwards, Thomas Barry (Aiken, SC)

    1998-01-01T23:59:59.000Z

    A process for determining one or more leachate concentrations of one or more components of a glass composition in an aqueous solution of the glass composition by identifying the components of the glass composition, including associated oxides, determining a preliminary glass dissolution estimator, .DELTA.G.sub.p, based upon the free energies of hydration for the component reactant species, determining an accelerated glass dissolution function, .DELTA.G.sub.a, based upon the free energy associated with weak acid dissociation, .DELTA.G.sub.a.sup.WA, and accelerated matrix dissolution at high pH, .DELTA.G.sub.a.sup.SB associated with solution strong base formation, and determining a final hydration free energy, .DELTA.G.sub.f. This final hydration free energy is then used to determine leachate concentrations for elements of interest using a regression analysis and the formula log.sub.10 (N C.sub.i (g/L))=a.sub.i +b.sub.i .DELTA.G.sub.f. The present invention also includes a method to determine whether a particular glass to be produced will be homogeneous or phase separated. The present invention is also directed to methods of monitoring and controlling processes for making glass using these determinations to modify the feedstock materials until a desired glass durability and homogeneity is obtained.

  20. Durable Goods, Price Indexes, and Monetary Policy

    E-Print Network [OSTI]

    Han, Kyoung Soo

    2009-05-15T23:59:59.000Z

    The dissertation studies the relationship among durable goods, price indexes and monetary policy in two sticky-price models with durable goods. One is a one-sector model with only durable goods and the other is a two-sector model with durable...

  1. Metal-oxide-based energetic materials and synthesis thereof

    DOE Patents [OSTI]

    Tillotson, Thomas M. (Tracy, CA), Simpson; Randall L. (Livermore, CA); Hrubesh, Lawrence W. (Pleasanton, CA)

    2006-01-17T23:59:59.000Z

    A method of preparing energetic metal-oxide-based energetic materials using sol-gel chemistry has been invented. The wet chemical sol-gel processing provides an improvement in both safety and performance. Essentially, a metal-oxide oxidizer skeletal structure is prepared from hydrolyzable metals (metal salts or metal alkoxides) with fuel added to the sol prior to gelation or synthesized within the porosity metal-oxide gel matrix. With metal salt precursors a proton scavenger is used to destabilize the sol and induce gelation. With metal alkoxide precursors standard well-known sol-gel hydrolysis and condensation reactions are used. Drying is done by standard sol-gel practices, either by a slow evaporation of the liquid residing within the pores to produce a high density solid nanocomposite, or by supercritical extraction to produce a lower density, high porous nanocomposite. Other ingredients may be added to this basic nanostructure to change physical and chemical properties, which include organic constituents for binders or gas generators during reactions, burn rate modifiers, or spectral emitters.

  2. Biofuels Impact on DPF Durability

    Broader source: Energy.gov (indexed) [DOE]

    Biofuels Impact on DPF Durability Michael J. Lance, Todd J. Toops, Andrew A. Wereszczak, John M.E. Storey, Dane F. Wilson, Bruce G. Bunting, Samuel A. Lewis Sr., and Andrea...

  3. Biofuels Impact on DPF Durability

    Broader source: Energy.gov (indexed) [DOE]

    Biofuels Impact on DPF Durability Michael J. Lance, Bruce G. Bunting, Andrew A. Wereszczak, Todd J. Toops, and Matt Ferber Oak Ridge National Laboratory May 15 th , 2012 PM040 This...

  4. Lightweight, durable lead-acid batteries

    SciTech Connect (OSTI)

    Lara-Curzio, Edgar (Lenoir City, TN); An, Ke (Knoxville, TX); Kiggans, Jr., James O. (Oak Ridge, TN); Dudney, Nancy J. (Knoxville, TN); Contescu, Cristian I. (Knoxville, TN); Baker, Frederick S. (Oak Ridge, TN); Armstrong, Beth L. (Clinton, TN)

    2011-09-13T23:59:59.000Z

    A lightweight, durable lead-acid battery is disclosed. Alternative electrode materials and configurations are used to reduce weight, to increase material utilization and to extend service life. The electrode can include a current collector having a buffer layer in contact with the current collector and an electrochemically active material in contact with the buffer layer. In one form, the buffer layer includes a carbide, and the current collector includes carbon fibers having the buffer layer. The buffer layer can include a carbide and/or a noble metal selected from of gold, silver, tantalum, platinum, palladium and rhodium. When the electrode is to be used in a lead-acid battery, the electrochemically active material is selected from metallic lead (for a negative electrode) or lead peroxide (for a positive electrode).

  5. Lightweight, durable lead-acid batteries

    SciTech Connect (OSTI)

    Lara-Curzio, Edgar; An, Ke; Kiggans, Jr., James O; Dudney, Nancy J; Contescu, Cristian I; Baker, Frederick S; Armstrong, Beth L

    2013-05-21T23:59:59.000Z

    A lightweight, durable lead-acid battery is disclosed. Alternative electrode materials and configurations are used to reduce weight, to increase material utilization and to extend service life. The electrode can include a current collector having a buffer layer in contact with the current collector and an electrochemically active material in contact with the buffer layer. In one form, the buffer layer includes a carbide, and the current collector includes carbon fibers having the buffer layer. The buffer layer can include a carbide and/or a noble metal selected from of gold, silver, tantalum, platinum, palladium and rhodium. When the electrode is to be used in a lead-acid battery, the electrochemically active material is selected from metallic lead (for a negative electrode) or lead peroxide (for a positive electrode).

  6. International Monetary Policy Analysis with Durable Goods 

    E-Print Network [OSTI]

    Lee, Kang Koo

    2010-10-12T23:59:59.000Z

    The dissertation studies a model of an economy which produces and exports durable goods. It analyzes the optimal monetary policy for such a country. Generally, monetary policy has a bigger economic effect on durable goods ...

  7. Durability of Polymeric Glazing and Absorber Materials

    SciTech Connect (OSTI)

    Jorgensen, G.; Terwilliger, K.; Bingham, C.; Milbourne, M.

    2005-01-01T23:59:59.000Z

    The Solar Heating and Lighting Program has set the goal of reducing the cost of solar water heating systems by at least 50%. An attractive approach to such large cost reduction is to replace glass and metal parts with less-expensive, lighter-weight, more-integrated polymeric components. The key challenge with polymers is to maintain performance and assure requisite durability for extended lifetimes. The objective of this task is to quantify lifetimes through measurement of the optical and mechanical stability of candidate polymeric glazing and absorber materials. Polycarbonate sheet glazings, as proposed by two industry partners, have been tested for resistance to UV radiation with three complementary methods. Incorporation of a specific 2-mil thick UV-absorbing screening layer results in glazing lifetimes of at least 15 years; improved screens promise even longer lifetimes. Proposed absorber materials were tested for creep and embrittlement under high temperature, and appear adequate for planned ICS absorbers.

  8. Compositional threshold for Nuclear Waste Glass Durability

    SciTech Connect (OSTI)

    Kruger, Albert A. [Pacific Northwest National Lab., Richland, WA (United States); Farooqi, Rahmatullah [Pohang Univ. of Science and Technology, (Korea, Republic of); Hrma, Pavel R. [Pacific Northwest National Lab., Richland, WA (United States), Pohang Univ. of Science and Technology, (Korea, Republic of)

    2013-04-24T23:59:59.000Z

    Within the composition space of glasses, a distinct threshold appears to exist that separates "good" glasses, i.e., those which are sufficiently durable, from "bad" glasses of a low durability. The objective of our research is to clarify the origin of this threshold by exploring the relationship between glass composition, glass structure and chemical durability around the threshold region.

  9. Thin Metal Oxide Films to Modify a Window Layer in CdTe-Based...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thin Metal Oxide Films to Modify a Window Layer in CdTe-Based Solar Cells for Improved Performance. Thin Metal Oxide Films to Modify a Window Layer in CdTe-Based Solar Cells for...

  10. Durability of Polymeric Glazing Materials for Solar Applications: Preprint

    SciTech Connect (OSTI)

    Jorgensen, G.; Brunold, S.; Carlsson, B.; Heck, M.; Kohl, M.; Moller, K.

    2003-09-01T23:59:59.000Z

    The economic viability of solar collector systems for domestic hot water (DHW) generation is strongly linked to the cost of such systems. Installation and hardware costs must be reduced by 50% to allow significant market penetration[1]. An attractive approach to cost reduction is to replace glass and metal parts with less expensive, lighter-weight polymeric components. Weight reduction decreases the cost of shipping, handling, and installation. The use of polymeric materials also allows the benefits and cost savings associated with well established manufacturing processes, along with savings associated with improved fastening, reduced part count, and overall assembly refinements. A key challenge is to maintain adequate system performance and assure requisite durability for extended lifetimes. Results of preliminary and ongoing screening tests for a large number of candidate polymeric glazing materials are presented. Based on these results, two specific glazings are selected to demonstrate how a service lifetime methodology can be applied to accurately predict the optical performance of these materials during in-service use.

  11. Infrared transparent frequency selective surface based on metallic meshes

    SciTech Connect (OSTI)

    Yu, Miao [Key Laboratory of Optical System Advanced Manufacturing Technology, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun, 130033 (China) [Key Laboratory of Optical System Advanced Manufacturing Technology, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun, 130033 (China); University of Chinese Academy of Sciences, Beijing, 100049 (China); Xu, Nianxi; Liu, Hai; Gao, Jinsong, E-mail: gaojs@ciomp.ac.cn [Key Laboratory of Optical System Advanced Manufacturing Technology, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun, 130033 (China)] [Key Laboratory of Optical System Advanced Manufacturing Technology, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun, 130033 (China)

    2014-02-15T23:59:59.000Z

    This paper presents an infrared transparent frequency selective surface (ITFSS) based on metallic meshes. In this ITFSS structure, periodic cross-slot units are integrated on square metallic meshes empowered by coating and UV-lithography. A matching condition is proposed to avoid the distortion of units. Experimental results show that this ITFSS possesses a good transmittance of 80% in the infrared band of 3–5 ?m, and also a stable band-pass behavior at the resonance frequency of 36.4 GHz with transmittance of ?0.56 dB. Theoretical simulations about the ITFSS diffractive characteristics and frequency responses are also investigated. The novel ITFSS will attract renewed interest and be exploited for applications in various fields.

  12. Quantum-Based Atomistic Simulation of Metals at Extreme Conditions

    SciTech Connect (OSTI)

    Moriarty, J A; Glosli, J N; Hood, R Q; Klepeis, J E; Orlikowski, D A; Soderlind, P; Yang, L H

    2008-01-15T23:59:59.000Z

    First-principles generalized pseudopotential theory (GPT) provides a fundamental basis for bridging the quantum-atomistic gap from density-functional quantum mechanics to large scale atomistic simulation in metals and alloys. In directionally-bonded bcc transition metals, advanced generation model GPT or MGPT potentials based on canonical d bands have been developed for Ta, Mo and V and successfully applied to a wide range of thermodynamic and mechanical properties at both ambient and extreme conditions of pressure and temperature, including high-pressure phase transitions, multiphase equation of state; melting and solidification; thermoelasticity; and the atomistic simulation of point defects, dislocations and grain boundaries needed for the multiscale modeling of plasticity and strength. Recent algorithm improvements have also allowed an MGPT implementation beyond canonical bands to achieve increased accuracy, extension to f-electron actinide metals, and high computational speed. A further advance in progress is the development temperature-dependent MGPT potentials that subsume electron-thermal contributions to high-temperature properties.

  13. Optical and Durability Evaluation for Silvered Polymeric Mirrors and Reflectors: Cooperative Research and Development Final Report, CRADA Number, CRD-08-316

    SciTech Connect (OSTI)

    Gray, M.

    2014-08-01T23:59:59.000Z

    3M is currently developing silvered polymeric mirror reflectors as low-cost replacements for glass mirrors in concentrating solar power (CSP) systems. This effort is focused on development of reflectors comprising both metallized polymeric mirror films based on improved versions of ECP-305+ or other durable mirror film concepts and appropriate mechanically robust substrates. The objectives for this project are to reduce the system capital and operating costs and to lower the levelized cost of energy for CSP installations. The development of mirror reflectors involves work on both full reflectors and mirror films with and without coatings. Mirror reflectors must meet rigid optical specifications in terms of radius of curvature, slope errors and specularity. Mirror films must demonstrate long-term durability and maintain high reflectivity. 3M would like to augment internal capabilities to validate product performance with methods and tools developed at NREL to address these areas.

  14. Durability of Diesel Engine Particulate Filters

    Broader source: Energy.gov (indexed) [DOE]

    * Funding received: - FY09 318k - FY10 238k Barriers * - Advanced Combustion Engine Research: Emission Control System: * Poor durability thermal stresses and porosity *...

  15. Durability Improvements Through Degradation Mechanism Studies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Improvements Through Degradation Mechanism Studies Durability Improvements Through Degradation Mechanism Studies Presented at the Department of Energy Fuel Cell Projects Kickoff...

  16. Enduring Legacy? Charles Tilly and Durable Inequality

    E-Print Network [OSTI]

    Voss, Kim

    2010-01-01T23:59:59.000Z

    Charles Tilly’s durable inequality. Comparative Studies inThe relational basis of inequality: generic and contingentA. , & Voss, K. (1996). Inequality by design: Cracking the

  17. ACCEPTABILITY ENVELOPE FOR METAL HYDRIDE-BASED HYDROGEN STORAGE SYSTEMS

    SciTech Connect (OSTI)

    Hardy, B.; Corgnale, C.; Tamburello, D.; Garrison, S.; Anton, D.

    2011-07-18T23:59:59.000Z

    The design and evaluation of media based hydrogen storage systems requires the use of detailed numerical models and experimental studies, with significant amount of time and monetary investment. Thus a scoping tool, referred to as the Acceptability Envelope, was developed to screen preliminary candidate media and storage vessel designs, identifying the range of chemical, physical and geometrical parameters for the coupled media and storage vessel system that allow it to meet performance targets. The model which underpins the analysis allows simplifying the storage system, thus resulting in one input-one output scheme, by grouping of selected quantities. Two cases have been analyzed and results are presented here. In the first application the DOE technical targets (Year 2010, Year 2015 and Ultimate) are used to determine the range of parameters required for the metal hydride media and storage vessel. In the second case the most promising metal hydrides available are compared, highlighting the potential of storage systems, utilizing them, to achieve 40% of the 2010 DOE technical target. Results show that systems based on Li-Mg media have the best potential to attain these performance targets.

  18. All-Metallic Vertical Transistors Based on Stacked Dirac Materials

    E-Print Network [OSTI]

    Wang, Yangyang

    It is an ongoing pursuit to use metal as a channel material in a field effect transistor. All metallic transistor can be fabricated from pristine semimetallic Dirac materials (such as graphene, silicene, and germanene), ...

  19. Comprehensive data base of high-level nuclear waste glasses: September 1987 status report: Volume 1, Discussion and glass durability data

    SciTech Connect (OSTI)

    Kindle, C.H.; Kreiter, M.R.

    1987-12-01T23:59:59.000Z

    The Materials Characterization Center (MCC) at Pacific Northwest Laboratory is assembling a comprehensive data base (CDB) of experimental data collected for high-level nuclear waste package components. Data collected throughout the world are included in the data base; current emphasis is on waste glasses and their properties. The goal is to provide a data base of properties and compositions and an analysis of dominant property trends as a function of composition. This data base is a resource that nuclear waste producers, disposers, and regulators can use to compare properties of a particular high-level nuclear waste glass product with the properties of other glasses of similar compositions. Researchers may use the data base to guide experimental tests to fill gaps in the available knowledge or to refine empirical models. The data are incorporated into a computerized data base that will allow the data to be extracted based on, for example, glass composition or test duration. 3 figs.

  20. Stress-corrosion fatiguecrack growth in a Zr-based bulk amorphous metal

    E-Print Network [OSTI]

    Ritchie, Robert

    Stress-corrosion fatigue­crack growth in a Zr-based bulk amorphous metal V. Schroeder 1 , R metallic glass; Amorphous metal; Fatigue; Stress corrosion; Crack growth 1. Introduction In recent years­crack growth resistance [1­5], its corresponding properties in the presence of a corrosive environment have

  1. Emissions and Durability of Underground Mining Diesel Particulate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Durability of Underground Mining Diesel Particulate Filter Applications Emissions and Durability of Underground Mining Diesel Particulate Filter Applications Presentation given at...

  2. Durability of Diesel Engine Particulate Filters (Agreement ID...

    Broader source: Energy.gov (indexed) [DOE]

    Durability of Diesel Engine Particulate Filters (Agreement ID:10461) Durability of Diesel Engine Particulate Filters (Agreement ID:10461) 2013 DOE Hydrogen and Fuel Cells Program...

  3. Critical Performance and Durability Parameters of an Integrated...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Durability Parameters of an Integrated Aftertreatment System used to Meet Tier II Emission Standards Critical Performance and Durability Parameters of an Integrated...

  4. Integration of Advanced Materials and Interfaces for Durable...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Materials and Interfaces for Durable Thermoelectric Automobile Exhaust Waste Heat Harvesting Devices Integration of Advanced Materials and Interfaces for Durable...

  5. Membrane Performance and Durability Overview for Automotive Fuel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Performance and Durability Overview for Automotive Fuel Cell Applications Membrane Performance and Durability Overview for Automotive Fuel Cell Applications Presented by Tom...

  6. Analysis of the Durability of PEM FC Membrane Electrode Assemblies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Durability of PEM FC Membrane Electrode Assemblies in Automotive Applications Analysis of the Durability of PEM FC Membrane Electrode Assemblies in Automotive Applications...

  7. Commercial Implementation of Model-Based Manufacturing of Nanostructured Metals

    SciTech Connect (OSTI)

    Lowe, Terry C. [Los Alamos National Laboratory

    2012-07-24T23:59:59.000Z

    Computational modeling is an essential tool for commercial production of nanostructured metals. Strength is limited by imperfections at the high strength levels that are achievable in nanostructured metals. Processing to achieve homogeneity at the micro- and nano-scales is critical. Manufacturing of nanostructured metals is intrinsically a multi-scale problem. Manufacturing of nanostructured metal products requires computer control, monitoring and modeling. Large scale manufacturing of bulk nanostructured metals by Severe Plastic Deformation is a multi-scale problem. Computational modeling at all scales is essential. Multiple scales of modeling must be integrated to predict and control nanostructural, microstructural, macrostructural product characteristics and production processes.

  8. Review Article: Rare-earth monosulfides as durable and efficient cold cathodesa) Marc Cahayb)

    E-Print Network [OSTI]

    Boolchand, Punit

    structure, rare-earth monosulfides offer a more stable alternative to alkali metals to attain lowReview Article: Rare-earth monosulfides as durable and efficient cold cathodesa) Marc Cahayb made of these materials are very unstable. Beginning in 2001, we have studied rare-earth (RE

  9. Supramolecular structures and metal-organic frameworks based on metal dipyrrin building blocks

    E-Print Network [OSTI]

    Halper, Sara R.

    2006-01-01T23:59:59.000Z

    assembly of supramolecular materials. [19-21] Specifically,to the metal. Supramolecular materials have an advantageproperties of supramolecular materials can be tuned by

  10. Electron-Transport in Calcium-Based Metallic Glasses

    E-Print Network [OSTI]

    Naugle, Donald G.; DELGADO, R.; ARMBRUSTER, H.; TSAI, CL; CALLAWAY, TO; REYNOLDS, D.; MORUZZI, VL.

    1986-01-01T23:59:59.000Z

    . Comparison of results from electronic-structure calculations for CaAl, Ca3A1, CaGa, and Ca3Ga alloys in a dose-packed crystalline structure with experiment indicates that the Ca d band may dominate the electron-transport properties of these glassy metals.... I. INTRODUCTION Considerable progress has b n made in the understand- ing of the electrical properties of glassy metals, particular- ly those whose constituents are simple metals. Generally the resistivity values for simple metal glassy alloys...

  11. Analysis of Heat Transfer in Metal Hydride Based Hydrogen Separation

    SciTech Connect (OSTI)

    Fleming, W.H. Jr.

    1999-10-20T23:59:59.000Z

    This thesis presents a transient heat transfer analysis to model the heat transfer in the Pd/k packed column, and the impact of adding metallic foam.

  12. Electrically conductive polycrystalline diamond and particulate metal based electrodes

    DOE Patents [OSTI]

    Swain, Greg M.; Wang, Jian

    2005-04-26T23:59:59.000Z

    An electrically conducting and dimensionally stable diamond (12, 14) and metal particle (13) electrode produced by electrodepositing the metal on the diamond is described. The electrode is particularly useful in harsh chemical environments and at high current densities and potentials. The electrode is particularly useful for generating hydrogen, and for reducing oxygen and oxidizing methanol in reactions which are of importance in fuel cells.

  13. Durability of Diesel Engine Particulate Filters

    Broader source: Energy.gov (indexed) [DOE]

    Durability of Diesel Engine Particulate Filters Thomas Watkins, Amit Shyam, H.T. Lin, Edgar Lara-Curzio and Amit Pandey; ORNL Randall Stafford; Cummins Inc. Sponsored by U.S....

  14. International Monetary Policy Analysis with Durable Goods

    E-Print Network [OSTI]

    Lee, Kang Koo

    2010-10-12T23:59:59.000Z

    INTERNATIONAL MONETARY POLICY ANALYSIS WITH DURABLE GOODS A Dissertation by KANG KOO LEE Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree... of DOCTOR OF PHILOSOPHY August 2009 Major Subject: Economics INTERNATIONAL MONETARY POLICY ANALYSIS WITH DURABLE GOODS A Dissertation by KANG KOO LEE Submitted to the Office of Graduate Studies of Texas A&M University...

  15. Niobate-based octahedral molecular sieves

    DOE Patents [OSTI]

    Nenoff, Tina M.; Nyman, May D.

    2003-07-22T23:59:59.000Z

    Niobate-based octahedral molecular sieves having significant activity for multivalent cations and a method for synthesizing such sieves are disclosed. The sieves have a net negatively charged octahedral framework, comprising niobium, oxygen, and octahedrally coordinated lower valence transition metals. The framework can be charge balanced by the occluded alkali cation from the synthesis method. The alkali cation can be exchanged for other contaminant metal ions. The ion-exchanged niobate-based octahedral molecular sieve can be backexchanged in acidic solutions to yield a solution concentrated in the contaminant metal. Alternatively, the ion-exchanged niobate-based octahedral molecular sieve can be thermally converted to a durable perovskite phase waste form.

  16. Niobate-based octahedral molecular sieves

    DOE Patents [OSTI]

    Nenoff, Tina M.; Nyman, May D.

    2006-10-17T23:59:59.000Z

    Niobate-based octahedral molecular sieves having significant activity for multivalent cations and a method for synthesizing such sieves are disclosed. The sieves have a net negatively charged octahedral framework, comprising niobium, oxygen, and octahedrally coordinated lower valence transition metals. The framework can be charge balanced by the occluded alkali cation from the synthesis method. The alkali cation can be exchanged for other contaminant metal ions. The ion-exchanged niobate-based octahedral molecular sieve can be backexchanged in acidic solutions to yield a solution concentrated in the contaminant metal. Alternatively, the ion-exchanged niobate-based octahedral molecular sieve can be thermally converted to a durable perovskite phase waste form.

  17. Optical Durability of Candidate Solar Reflectors for Concentrating Solar Power

    SciTech Connect (OSTI)

    Kennedy, C. E.; Terwilliger, K.

    2007-01-01T23:59:59.000Z

    Concentrating solar power (CSP) technologies use large mirrors to collect sunlight to convert thermal energy to electricity. The viability of CSP systems requires the development of advanced reflector materials that are low in cost and maintain high specular reflectance for extended lifetimes under severe outdoor environments. The long-standing goals for a solar reflector are specular reflectance above 90% into a 4 mrad half-cone angle for at least 10 years outdoors with a cost of less than $13.8/m{sup 2} (the 1992 $10.8/m{sup 2} goal corrected for inflation to 2002 dollars) when manufactured in large volumes. Durability testing of a variety of candidate solar reflector materials at outdoor test sites and in laboratory accelerated weathering chambers is the main activity within the Advanced Materials task of the CSP Program at the National Renewable Energy Laboratory (NREL) in Golden, Colorado. Test results to date for several candidate solar reflector materials will be presented. These include the optical durability of thin glass, thick glass, aluminized reflectors, front-surface mirrors, and silvered polymer mirrors. The development, performance, and durability of these materials will be discussed. Based on accelerated exposure testing the glass, silvered polymer, and front-surface mirrors may meet the 10 year lifetime goals, but at this time because of significant process changes none of the commercially available solar reflectors and advanced solar reflectors have demonstrated the 10 year or more aggressive 20 year lifetime goal.

  18. Synthesis and Hydrogen Sorption Properties of Carborane Based Metal-Organic Framework Materials

    E-Print Network [OSTI]

    Synthesis and Hydrogen Sorption Properties of Carborane Based Metal-Organic Framework Materials@northwestern.edu Tailorable inorganic coordination polymers,1-7 in particular, metal-organic frameworks (MOFs)2-7 comprise an important emerging class of materials. They are noteworthy for their structural and chemical diversity, high

  19. The strong reactions of Lewis-base noble-metals with vanadium and other acidic transition metals

    SciTech Connect (OSTI)

    Ebbinghaus, B.B.

    1991-05-01T23:59:59.000Z

    The noble metals often thought of as unreactive solids,react strongly with nearly 40% of the elements in the periodictable: group IIIB-VB transition metals, lanthanides, theactinides, and group IIIA-IVA non-transition metals. These strong reactions arise from increased bonding/electron transfer fromnonbonding electrons d electron pairs on the noble metal tovacant orbitals on V, etc. This effect is a generalized Lewis acid-base interaction. The partial Gibbs energy of V in the noblemetals has been measured as a function of concentration at a temperature near 1000C. Thermodynamics of the intermetallics are determined by ternary oxide equilibria, ternary carbide equilibria, and the high-temperature galvanic cell technique. These experimental methods use equilibrated solid composite mixtures in which grains of V oxides or of V carbides are interspersed with grains of V-NM(noble-metal) alloys. In equilibrium the activity of V in the oxide or the carbide equals the activity in the alloy. Consequently, the thermodynamics available in the literature for the V oxides and V carbides are reviewed. Test runs on the galvanic cell were attempted. The V oxide electrode reacts with CaF[sub 2], ThO[sub 2], YDT(0.85ThO[sub 2]-0.15YO[sub 1.5]), and LDT(0.85ThO[sub 2]- 0.15LaO[sub 1.5]) to interfere with the measured data observed toward the beginning of a galvanic cell experiment are the most accurate. The interaction of vanadium at infinite dilution in the noble-metals was determined.

  20. The strong reactions of Lewis-base noble-metals with vanadium and other acidic transition metals

    SciTech Connect (OSTI)

    Ebbinghaus, B.B.

    1991-05-01T23:59:59.000Z

    The noble metals often thought of as unreactive solids,react strongly with nearly 40% of the elements in the periodictable: group IIIB-VB transition metals, lanthanides, theactinides, and group IIIA-IVA non-transition metals. These strong reactions arise from increased bonding/electron transfer fromnonbonding electrons d electron pairs on the noble metal tovacant orbitals on V, etc. This effect is a generalized Lewis acid-base interaction. The partial Gibbs energy of V in the noblemetals has been measured as a function of concentration at a temperature near 1000C. Thermodynamics of the intermetallics are determined by ternary oxide equilibria, ternary carbide equilibria, and the high-temperature galvanic cell technique. These experimental methods use equilibrated solid composite mixtures in which grains of V oxides or of V carbides are interspersed with grains of V-NM(noble-metal) alloys. In equilibrium the activity of V in the oxide or the carbide equals the activity in the alloy. Consequently, the thermodynamics available in the literature for the V oxides and V carbides are reviewed. Test runs on the galvanic cell were attempted. The V oxide electrode reacts with CaF{sub 2}, ThO{sub 2}, YDT(0.85ThO{sub 2}-0.15YO{sub 1.5}), and LDT(0.85ThO{sub 2}- 0.15LaO{sub 1.5}) to interfere with the measured data observed toward the beginning of a galvanic cell experiment are the most accurate. The interaction of vanadium at infinite dilution in the noble-metals was determined.

  1. Strength, transport efficiency and selectivity of novel extractants for the recovery of base metals 

    E-Print Network [OSTI]

    Lin, Tai

    2009-01-01T23:59:59.000Z

    This thesis concerns the development of new types of solvent extractants for use in the hydrometallurgical recovery of base metals, and addresses the ligand design features which are needed to control the strength, ...

  2. Vehicle Technologies Office Merit Review 2014: Metal-Based High Capacity Li-Ion Anodes

    Broader source: Energy.gov [DOE]

    Presentation given by Binghamton University-SUNY at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about metal-based high...

  3. Investigation on Aluminum-Based Amorphous Metallic Glass as New Anode Material in Lithium Ion Batteries

    E-Print Network [OSTI]

    Meng, Shirley Y.

    Aluminum based amorphous metallic glass powders were produced and tested as the anode materials for the lithium ion rechargeable batteries. Ground Al??Ni₁?La₁? was found to have a ...

  4. EXPERIMENTAL INVESTIGATION OF ORGANIC MEMS BASED CONDUCTIVE POLYMER-METAL COMPOSITE

    E-Print Network [OSTI]

    Kassegne, Samuel Kinde

    EXPERIMENTAL INVESTIGATION OF ORGANIC MEMS BASED CONDUCTIVE POLYMER-METAL COMPOSITE Diego State University, 2012 This research investigates SU-8/Ag conductive polymer composite of conductive polymer composite. Microscopic analysis using 3D microscope carried out for agglomeration

  5. A dislocation-based, strain–gradient–plasticity strengthening model for deformation processed metal–metal composites

    SciTech Connect (OSTI)

    Tian, Liang [Ames Laboratory; Russell, Alan [Ames Laboratory; Anderson, Iver [Ames Laboratory

    2014-01-03T23:59:59.000Z

    Deformation processed metal–metal composites (DMMCs) are high-strength, high-electrical conductivity composites developed by severe plastic deformation of two ductile metal phases. The extraordinarily high strength of DMMCs is underestimated using the rule of mixture (or volumetric weighted average) of conventionally work-hardened metals. In this article, a dislocation-density-based, strain–gradient–plasticity model is proposed to relate the strain-gradient effect with the geometrically necessary dislocations emanating from the interface to better predict the strength of DMMCs. The model prediction was compared with the experimental findings of Cu–Nb, Cu–Ta, and Al–Ti DMMC systems to verify the applicability of the new model. The results show that this model predicts the strength of DMMCs better than the rule-of-mixture model. The strain-gradient effect, responsible for the exceptionally high strength of heavily cold worked DMMCs, is dominant at large deformation strain since its characteristic microstructure length is comparable with the intrinsic material length.

  6. UV-Shifted Durable Silver Coating for Astronomical Mirrors

    SciTech Connect (OSTI)

    Thomas, N.L.; Wolfe, J.

    2000-06-01T23:59:59.000Z

    Silver has the highest reflectance of all of the metals, but it tarnishes in the presence of sulfides, chlorides, and oxides in the atmosphere. Also, the silver reflectance is very low at wavelengths below 400 nm making aluminum more desirable mirror coating for the UV region. They have found a way to prevent silver tarnishing by sandwiching the silver layer between two thin layers of NiCrN{sub x}, and to extend the metal's high reflectance down to 200 nm by depositing the (thin) Ag layer on top of Al. Thus, the uv is transmitted through the thin Ag layer below 400 nm wavelength, and is reflected from the Al layer underneath. This UV-shifted durable coating provides a valuable alternative to the aluminum coating for telescope mirror coatings where high throughput and durability are important considerations. The throughput for a telescope with, say, six reflections from silver coatings is (0.97){sup 6} = 83% compared to (0.92){sup 6} = 60% for aluminum coatings, or 28% less. The use of silver coatings allows more photons to be collected by primary mirror. Aluminum also has a reflectance dip at 850 nm caused by inter-band transitions which is eliminated by placing the thin Ag layer on top. This paper describes a non-tarnishing silver coating having high reflectance down into the UV region. The average specular reflectance is 70%-97% in the near-UV, 95%-99% in the visible region, and {ge} 99% in the infrared region covering the total wavelength range 200 nm to 10,000 nm. Figure 1 compares the reflectance of the UVHR-LLNL silver coating to bare silver and aluminum over-coated with magnesium fluoride over the wavelength range 300 nm to 2000 nm.

  7. Center for By-Products Utilization High Durability Concrete Using

    E-Print Network [OSTI]

    Saldin, Dilano

    TESTING · Fresh Concrete Properties ·Unit Weight (ASTM C 138) ·Air Content (ASTM C 237) ·Slump (ASTM C 143Center for By-Products Utilization High Durability Concrete Using High-Carbon Fly Ash and Pulp Mill-Products Utilization Durable Concrete in Northern Climates · Producing durable concrete in a freezing and thawing

  8. NREL Determines Better Testing Methods for Photovoltaic Module Durability (Fact Sheet), NREL Highlights, Research & Development

    SciTech Connect (OSTI)

    Not Available

    2011-11-01T23:59:59.000Z

    NREL discoveries will enable manufacturers to produce more robust photovoltaic modules. Over the past decade, some photovoltaic (PV) modules have experienced power losses because of the system voltage stress that modules experience in fielded arrays. This is partly because qualification tests and standards do not adequately evaluate the durability of modules that undergo the long-term effects of high voltage. Scientists at the National Renewable Energy Laboratory (NREL) tried various testing methods and stress levels to demonstrate module durability to system voltage potential-induced degradation (PID) mechanisms. The results of these accelerated tests, along with outdoor testing, were used to estimate the acceleration factors needed to more accurately evaluate the durability of modules to system voltage stress. NREL was able to determine stress factors, levels, and methods for testing based on the stresses experienced by modules in the field. These results, in combination with those in the literature, suggest that constant stress with humidity and system voltage is more damaging than stress applied intermittently or with periods of recovery comprising hot and dry conditions or alternating bias in between. NREL has determined some module constructions to be extremely durable to PID. These findings will help the manufacturers of PV materials and components produce more durable products that better satisfy their customers. NREL determined that there is rapid degradation of some PV modules under system voltage stress and evaluated degradation rates in the field to develop more accurate accelerated testing methods. PV module manufacturers will be better able to choose robust materials and durable designs and guarantee sturdier, longer-lasting products. As PV modules become more durable, and thus more efficient over the long term, the risks and the cost of PV power will be reduced.

  9. Thermal conductivity studies of metal dispersed multiwalled carbon nanotubes in water and ethylene glycol based nanofluids

    SciTech Connect (OSTI)

    Jha, Neetu; Ramaprabhu, S. [Department of Physics, Alternative Energy and Nanotechnology Laboratory (AENL), Nano Functional Materials Technology Centre (NFMTC), Indian Institute of Technology Madras, Chennai 600036 (India)

    2009-10-15T23:59:59.000Z

    High thermal conducting metal nanoparticles have been dispersed on the multiwalled carbon nanotubes (MWNTs) outer surface. Structural and morphological characterizations of metal dispersed MWNTs have been carried out using x-ray diffraction analysis, high resolution transmission electron microscopy, energy dispersive x-ray analysis, and Fourier transform infrared spectroscopy. Nanofluids have been synthesized using metal-MWNTs in de-ionized water (DI water) and ethylene glycol (EG) base fluids. It has been observed that nanofluids maintain the same sequence of thermal conductivity as that of metal nanoparticles Ag-MWNTs>Au-MWNTs>Pd-MWNTs. A maximum enhancement of 37.3% and 11.3% in thermal conductivity has been obtained in Ag-MWNTs nanofluid with DI water and EG as base fluids, respectively, at a volume fraction of 0.03%. Temperature dependence study also shows enhancement of thermal conductivity with temperature.

  10. LaNi{sub 5}-based metal hydride electrode in Ni-MH rechargeable cells

    DOE Patents [OSTI]

    Bugga, R.V.; Fultz, B.; Bowman, R.; Surampudi, S.R.; Witham, C.K.; Hightower, A.

    1999-03-30T23:59:59.000Z

    An at least ternary metal alloy of the formula AB{sub (Z-Y)}X{sub (Y)} is disclosed. In this formula, A is selected from the rare earth elements, B is selected from the elements of Groups 8, 9, and 10 of the Periodic Table of the Elements, and X includes at least one of the following: antimony, arsenic, germanium, tin or bismuth. Z is greater than or equal to 4.8 and less than or equal to 6.0. Y is greater than 0 and less than 1. Ternary or higher-order substitutions to the base AB{sub 5} alloys that form strong kinetic interactions with the predominant metals in the base metal hydride are used to form metal alloys with high structural integrity after multiple cycles of hydrogen sorption. 16 figs.

  11. Measurement of Exterior Foundation Insulation to Assess Durability in Energy-Saving Performance

    SciTech Connect (OSTI)

    Kehrer, Manfred [ORNL; Christian, Jeff [Oak Ridge National Laboratory (ORNL)

    2012-04-01T23:59:59.000Z

    The foundation of a house is a sometimes ignored component of the building because of its low visibility. It is increasingly evident, however, that attention to good foundation design and construction significantly benefits the homeowner and the builder by mitigating future problems. Good foundation design and construction practice involves not only insulating to save energy but also providing effective structural design as well as moisture, termite, and radon control techniques as appropriate. Energy efficiency in housing is augmented by use of exterior slab and basement insulation, but high moisture content in the insulation material has led to concerns about its durability. The activity under this task was to extract six different exterior insulation systems that were characterized at installation and have been in the ground for 9 months to 15 years. R-value and moisture content were measured and inspections conducted for evidence of termite intrusion or deterioration. Based on the results, the durability of the various systems has been documented and assessments made of which systems appear to be best practice. Heat flux and temperature measurement data had been archived for some of the exterior insulation tests, thereby providing a unique opportunity to assess energy-saving performance and durability over the long term. The results show that the durability of foundation insulation systems depends on insulation type as well as on foundation type and local boundary conditions, the latter of which may have a marked influence on the durability of energy-saving performance.

  12. Carborane-Based Metal-Organic Framework with High Methane and Hydrogen Storage Capacities

    E-Print Network [OSTI]

    Carborane-Based Metal-Organic Framework with High Methane and Hydrogen Storage Capacities Robert D of Chemical & Biological Engineering, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208 of Pennsylvania, Philadelphia, Pennsylvania 19104, United States *S Supporting Information ABSTRACT: A Cu-carborane-based

  13. Metal-optic and Plasmonic Semiconductor-based Nanolasers

    E-Print Network [OSTI]

    Lakhani, Amit

    2012-01-01T23:59:59.000Z

    cubic wavelengths). The ultra-small laser volume is achievedthey are useful for ultra-small laser designs. Unlikeelectrically injected lasers based on ultra-thin epitaxial

  14. Electronic Durability of Flexible Transparent Films from Type-Specific Single-Wall Carbon Nanotubes

    SciTech Connect (OSTI)

    Harris, J; Iyer, S; Bernhardt, A; Huh, JY; Hudson, S; Fagan, J; Hobbie, E.

    2011-12-11T23:59:59.000Z

    The coupling between mechanical flexibility and electronic performance is evaluated for thin films of metallic and semiconducting single-wall carbon nanotubes (SWCNTs) deposited on compliant supports. Percolated networks of type-purified SWCNTs are assembled as thin conducting coatings on elastic polymer substrates, and the sheet resistance is measured as a function of compression and cyclic strain through impedance spectroscopy. The wrinkling topography, microstructure and transparency of the films are independently characterized using optical microscopy, electron microscopy, and optical absorption spectroscopy. Thin films made from metallic SWCNTs show better durability as flexible transparent conductive coatings, which we attribute to a combination of superior mechanical performance and higher interfacial conductivity.

  15. Tin-Based Reactive Solders for Ceramic/Metal Joints RAKESH R. KAPOOR and THOMAS W . EAGAR

    E-Print Network [OSTI]

    Eagar, Thomas W.

    ( { ) Tin-Based Reactive Solders for Ceramic/Metal Joints RAKESH R. KAPOOR and THOMAS W . EAGAR engine com- ponents), wear parts, tool materials, electrical feed- throughs, and metal contacts on ceramics. To overcome this problem, reactive metals are added to the filler metai.11- 181These reactive

  16. Advanced Metal-Hydrides-Based Thermal Battery: A New Generation of High Density Thermal Battery Based on Advanced Metal Hydrides

    SciTech Connect (OSTI)

    None

    2011-12-01T23:59:59.000Z

    HEATS Project: The University of Utah is developing a compact hot-and-cold thermal battery using advanced metal hydrides that could offer efficient climate control system for EVs. The team’s innovative designs of heating and cooling systems for EVs with high energy density, low-cost thermal batteries could significantly reduce the weight and eliminate the space constraint in automobiles. The thermal battery can be charged by plugging it into an electrical outlet while charging the electric battery and it produces heat and cold through a heat exchanger when discharging. The ultimate goal of the project is a climate-controlling thermal battery that can last up to 5,000 charge and discharge cycles while substantially increasing the driving range of EVs, thus reducing the drain on electric batteries.

  17. Intermediate Ethanol Blends Catalyst Durability Program

    SciTech Connect (OSTI)

    West, Brian H; Sluder, Scott; Knoll, Keith; Orban, John; Feng, Jingyu

    2012-02-01T23:59:59.000Z

    In the summer of 2007, the U.S. Department of Energy (DOE) initiated a test program to evaluate the potential impacts of intermediate ethanol blends (also known as mid-level blends) on legacy vehicles and other engines. The purpose of the test program was to develop information important to assessing the viability of using intermediate blends as a contributor to meeting national goals for the use of renewable fuels. Through a wide range of experimental activities, DOE is evaluating the effects of E15 and E20 - gasoline blended with 15% and 20% ethanol - on tailpipe and evaporative emissions, catalyst and engine durability, vehicle driveability, engine operability, and vehicle and engine materials. This report provides the results of the catalyst durability study, a substantial part of the overall test program. Results from additional projects will be reported separately. The principal purpose of the catalyst durability study was to investigate the effects of adding up to 20% ethanol to gasoline on the durability of catalysts and other aspects of the emissions control systems of vehicles. Section 1 provides further information about the purpose and context of the study. Section 2 describes the experimental approach for the test program, including vehicle selection, aging and emissions test cycle, fuel selection, and data handling and analysis. Section 3 summarizes the effects of the ethanol blends on emissions and fuel economy of the test vehicles. Section 4 summarizes notable unscheduled maintenance and testing issues experienced during the program. The appendixes provide additional detail about the statistical models used in the analysis, detailed statistical analyses, and detailed vehicle specifications.

  18. Impact of Biodiesel Metals on the Performance and Durability...

    Broader source: Energy.gov (indexed) [DOE]

    accelerated test method to expose diesel catalysts - 8 DOCs, 8 DPFs and 4 SCRs * Biodiesel ash did not adversely impact the back pressure of a DPF * Biodiesel ash caused...

  19. Impact of Biodiesel Metals on Aftertreatment System Durability | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet),Energy Petroleum TechnologyEnergyImaging Ahead

  20. (Durability of building materials and components)

    SciTech Connect (OSTI)

    Naus, D.J.

    1990-11-27T23:59:59.000Z

    The traveler participated in the fourth meeting of RILEM 100-TSL, Techniques for Service Life Prediction,'' and The Fifth International Conference on Durability of Building Materials and Components.'' In addition, the traveler met with staff members at Taywood Engineering Ltd., Electricite de France, and AEA Technology. The meeting pertained to performance of concrete materials in nuclear power plant structures, time variation of concrete material properties, methods for evaluating concrete structures, and modeling to predict the effects of degradation factors on concrete materials. As many of the concrete structures in general civil engineering applications as well as nuclear power plant applications in Europe are aging, there is increasing emphasis on assessing the durability of these structures. Information was provided of direct application to the Structural Aging Program which would not have been available without these visits. Of equal, or possibly more importance, was the individual contacts established at the organizations visited. Each organization was extremely interested in both the approach and scope of the Structural Aging Program and requested that they be informed of progress. The initial steps were taken to cooperate with several of these researchers and this should help the Structural Aging Program keep abreast of related European activities. In summary, information obtained during this trip will benefit the ongoing Structural Aging Program by informing Oak Ridge National Laboratory (ORNL) of the extensive European research programs addressing the durability of concrete structures, and also by forming and strengthening acquaintances with counterparts in other countries, thus enhancing the basis for possible international cooperation.

  1. Durability Evaluation of Reversible Solid Oxide Cells

    SciTech Connect (OSTI)

    Xiaoyu Zhang; James E. O'Brien; Robert C. O'Brien; Gregory K. Housley

    2013-11-01T23:59:59.000Z

    An experimental investigation on the performance and durability of single solid oxide cells (SOCs) is under way at the Idaho National Laboratory. Reversible operation of SOCs includes electricity generation in the fuel cell mode and hydrogen generation in the electrolysis mode. Degradation is a more significant issue when operating SOCs in the electrolysis mode. In order to understand and mitigate the degradation issues in high temperature electrolysis, single SOCs with different configurations from several manufacturers have been evaluated for initial performance and long-term durability. A new test apparatus for single cell and small stack tests has been developed for this purpose. Cells were obtained from four industrial partners. Cells from Ceramatec Inc. and Materials and Systems Research Inc. (MSRI) showed improved durability in electrolysis mode compared to previous stack tests. Cells from Saint Gobain Advanced Materials Inc. (St. Gobain) and SOFCPower Inc. demonstrated stable performance in the fuel cell mode, but rapid degradation in the electrolysis mode, especially at high current density. Electrolyte-electrode delamination was found to have a significant impact on degradation in some cases. Enhanced bonding between electrolyte and electrode and modification of the electrode microstructure helped to mitigate degradation. Polarization scans and AC impedance measurements were performed during the tests to characterize cell performance and degradation.

  2. Structure and magnetic behavior of transition metal based ionic liquids

    SciTech Connect (OSTI)

    Del Sesto, Rico E [Los Alamos National Laboratory (LANL); Mccleskey, T [Los Alamos National Laboratory (LANL); Burrell, Anthony K [ORNL; Baker, Gary A [ORNL; Thompson, Joe D. [Los Alamos National Laboratory (LANL); Scott, Brian L. [Los Alamos National Laboratory (LANL); Wilkes, John S [United States Air Force Academy (USAFA), Colorado; Williams, Peg [United States Air Force Academy (USAFA), Colorado

    2008-01-01T23:59:59.000Z

    A series of ionic liquids containing different paramagnetic anions have been prepared and all show paramagnetic behavior with potential applications for magnetic and electrochromic switching as well as novel magnetic transport; also, the tetraalkylphosphonium-based ionic liquids reveal anomalous magnetic behavior.

  3. Low beryllium content Zr-based bulk metallic glass composite with plasticity and work hardenability

    SciTech Connect (OSTI)

    Zheng, Q., E-mail: qiangzheng616@hotmail.com, E-mail: dujuan@nimte.ac.cn [School of Materials Science and Engineering, Ningbo University of Technology, Ningbo, 315016, China and Ningbo Branch of China Academy of Ordnance Science, Ningbo, 315103 (China); Du, J., E-mail: qiangzheng616@hotmail.com, E-mail: dujuan@nimte.ac.cn [Key Laboratory of Magnetic Materials and Devices, Ningbo Institute of Material Technology and Engineering (NIMTE), Chinese Academy of Sciences (CAS), Zhejiang Province Key Laboratory of Magnetic Materials and Application Technology, NIMTE, CAS, Ningbo 315201 (China)

    2014-01-28T23:59:59.000Z

    A modified Zr-based bulk metallic glass matrix composite Zr{sub 47.67}Cu{sub 40}Ti{sub 3.66}Ni{sub 2.66}Be{sub 6} has been produced by increasing the contents of elements of Zr and Cu with higher Poisson ratio and reducing the contents of Ti, Ni, and Be elements with lower Poisson ratio based on famous metallic glass former Vitreloy 1. A compressive yielding strength of 1804?MPa, fracture strength of 1938?MPa and 3.5% plastic strain was obtained for obtained metallic glass composite. Also, work-hardening behavior was observed during compressive experiment which was ascribed to the interaction of the in situ precipitated CuZr phase and shear bands.

  4. Modeling of dual-metal Schottky contacts based silicon micro and nano wire solar cells

    E-Print Network [OSTI]

    Anantaram, M. P.

    Modeling of dual-metal Schottky contacts based silicon micro and nano wire solar cells M. Golam Work function Lifetime Diffusion length Interdigitated solar cell a b s t r a c t We study solar cell nanowires and nanotubes are considered to be potential candidates for low cost and high efficiency solar

  5. A Modeling-Based Technique for Nondestructive Evaluation of Metal Powders Undergoing Microwave Sintering

    E-Print Network [OSTI]

    Yakovlev, Vadim

    A Modeling-Based Technique for Nondestructive Evaluation of Metal Powders Undergoing Microwave of sensors and probes (see, e.g., [9]) is very limited here because of high (up to hundreds degrees Celsius the development of suitable means of nondestructive evaluation (NDE) of powder samples under microwave 978

  6. Corrosion performances in simulated body fluids and cytotoxicity evaluation of Fe-based bulk metallic glasses

    E-Print Network [OSTI]

    Zheng, Yufeng

    Corrosion performances in simulated body fluids and cytotoxicity evaluation of Fe-based bulk December 2011 Available online 27 December 2011 Keywords: Bulk metallic glass Corrosion Biocompatibility Electrochemical characterization Biomedical applications The aim of this work is to investigate the corrosion

  7. Improved Thermoelectric Power Factor in Metal-Based Superlattices Daryoosh Vashaee and Ali Shakouri*

    E-Print Network [OSTI]

    Improved Thermoelectric Power Factor in Metal-Based Superlattices Daryoosh Vashaee and Ali Shakouri and thermoelectric transport perpendicular to heterostructure superlattices. This nonlinear transport regime above with tall barriers can achieve a large effective thermoelectric figure of merit (ZT > 5 at room temperature

  8. Oxygen impurity and microalloying effect in a Zr-based bulk metallic glass alloy

    E-Print Network [OSTI]

    Pennycook, Steve

    Oxygen impurity and microalloying effect in a Zr-based bulk metallic glass alloy C.T. Liu*, M composition Zr­10 at.%Al­5% Ti­17.9% Cu­14.6% Ni (BAM-11) was used to study the effects of oxygen impurities and microalloying on the microstructure and mechanical properties. Oxygen impurity at a level of 3000 appm

  9. Durability of Diesel Particulate Filters - Bench Studies on Cordierite...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Particulate Filters - Bench Studies on Cordierite Filters Durability of Diesel Particulate Filters - Bench Studies on Cordierite Filters Presentation given at DEER 2006, August...

  10. Future Engine Fluids Technologies: Durable, Fuel-Efficient, and...

    Office of Environmental Management (EM)

    Engine Fluids Technologies: Durable, Fuel-Efficient, and Emissions-Friendly 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters...

  11. Combined hydrophobicity and mechanical durability through surface nanoengineering

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Elliott, Paul R.; Stagon, Stephen P.; Huang, Hanchen; Furrer, David U.; Burlatsky, Sergei F.; Filburn, Thomas P.

    2015-04-08T23:59:59.000Z

    This paper reports combined hydrophobicity and mechanical durability through the nanoscale engineering of surfaces in the form of nanorod-polymer composites. Specifically, the hydrophobicity derives from nanoscale features of mechanically hard ZnO nanorods and the mechanical durability derives from the composite structure of a hard ZnO nanorod core and soft polymer shell. Experimental characterization correlates the morphology of the nanoengineered surfaces with the combined hydrophobicity and mechanical durability, and reveals the responsible mechanisms. Such surfaces may find use in applications, such as boat hulls, that benefit from hydrophobicity and require mechanical durability.

  12. Membrane Performance and Durability Overview for Automotive Fuel...

    Broader source: Energy.gov (indexed) [DOE]

    September 14, 2006 Membrane Performance and Durability Overview for Automotive Fuel Cell Applications Tom Greszler General Motors Corporation Fuel Cell Activities Honeoye...

  13. New MEA Materials for Improved DMFC Performance, Durability and...

    Broader source: Energy.gov (indexed) [DOE]

    performance and durability - Johnson Matthey * MEA fabrication scale up and MEA optimization 2 Project Objectives * Leverage the PolyFuel Passive water recovery MEA design to...

  14. Economizer Based Data Center Liquid Cooling with Advanced Metal Interfaces

    SciTech Connect (OSTI)

    Timothy Chainer

    2012-11-30T23:59:59.000Z

    A new chiller-less data center liquid cooling system utilizing the outside air environment has been shown to achieve up to 90% reduction in cooling energy compared to traditional chiller based data center cooling systems. The system removes heat from Volume servers inside a Sealed Rack and transports the heat using a liquid loop to an Outdoor Heat Exchanger which rejects the heat to the outdoor ambient environment. The servers in the rack are cooled using a hybrid cooling system by removing the majority of the heat generated by the processors and memory by direct thermal conduction using coldplates and the heat generated by the remaining components using forced air convection to an air- to- liquid heat exchanger inside the Sealed Rack. The anticipated benefits of such energy-centric configurations are significant energy savings at the data center level. When compared to a traditional 10 MW data center, which typically uses 25% of its total data center energy consumption for cooling this technology could potentially enable a cost savings of up to $800,000-$2,200,000/year (assuming electricity costs of 4 to 11 cents per kilowatt-hour) through the reduction in electrical energy usage.

  15. Durable Fuel Cell Membrane Electrode Assembly (MEA)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power AdministrationField Campaign:INEA :Work with Jefferson Lab | JeffersonDurable Fuel Cell

  16. Springback prediction in sheet metal forming process based on the hybrid SA

    SciTech Connect (OSTI)

    Guo Yuqin; Jiang Hong; Wang Xiaochun [School of Mechanical Engineering, Xi' an Jiaotong University, Xi' an 710049 (China); Li Fuzhu [Technology Institute, Xuzhou Normal University, XuZhou 221011 (China)

    2005-08-05T23:59:59.000Z

    In terms of the intensive similarity between the sheet metal forming-springback process and that of the annealing of metals, it is suggested that the simulation of the sheet metal forming process is performed with the Nonlinear FEM and the springback prediction is implemented by solving the large-scale combinational optimum problem established on the base of the energy descending and balancing in deformed part. The BFGS-SA hybrid SA approach is proposed to solve this problem and improve the computing efficiency of the traditional SA and its capability of obtaining the global optimum solution. At the same time, the correlative annealing strategies for the SA algorithm are determined in here. By comparing the calculation results of sample part with those of experiment measurement at the specified sections, the rationality of the schedule of springback prediction used and the validity of the BFGS-SA algorithm proposed are verified.

  17. CHP Fuel Cell Durability Demonstration - Final Report

    SciTech Connect (OSTI)

    Petrecky, James; Ashley, Christopher J

    2014-07-21T23:59:59.000Z

    Plug Power has managed a demonstration project that has tested multiple units of its high-temperature, PEM fuel cell system in micro-combined heat and power (?-CHP) applications in California. The specific objective of the demonstration project was to substantiate the durability of GenSys Blue, and, thereby, verify its technology and commercial readiness for the marketplace. In the demonstration project, Plug Power, in partnership with the National Fuel Cell Research Center (NFCRC) at the University of California, Irvine (UCI), and Sempra, will execute two major tasks: • Task 1: Internal durability/reliability fleet testing. Six GenSys Blue units will be built and will undergo an internal test regimen to estimate failure rates. This task was modified to include 3 GenSys Blue units installed in a lab at UCI. • Task 2: External customer testing. Combined heat and power units will be installed and tested in real-world residential and/or light commercial end user locations in California.

  18. The optimal suppression of a low-cost technology by a durable-good monopoly

    E-Print Network [OSTI]

    Karp, Larry; Perloff, Jeffrey M

    1994-01-01T23:59:59.000Z

    SUPPRESSION OF A LOW-COST TECHNOLOGY BY A DURABLE-GOODsuppression of a low-cost technology by a durable-goodSuppression of a Low-Cost Technology by a Durable-Good

  19. Glacier: Highly durable, decentralized storage despite massive correlated failures

    E-Print Network [OSTI]

    Pennsylvania, University of

    Glacier: Highly durable, decentralized storage despite massive correlated failures Andreas be considered when attempting to provide highly durable storage. In this paper, we describe Glacier failures. Glacier is designed to aggressively minimize the cost of this redun- dancy in space and time

  20. Irradiation effects on base metal and welds of 9Cr-1Mo (EM10) martensitic steel

    SciTech Connect (OSTI)

    Alamo, A.; Seran, J.L.; Rabouille, O.; Brachet, J.C.; Maillard, A.; Touron, H.; Royer, J. [CEA Saclay, Gif-sur-Yvette (France)

    1996-12-31T23:59:59.000Z

    9Cr martensitic steels are being developed for core components (wrapper tubes) of fast breeder reactors as well as for fusion reactor structures. Here, the effects of fast neutron irradiation on the mechanical behavior of base metal and welds of 9Cr-1Mo (EM10) martensitic steel have been studied. Two types of weldments have been produced by TIG and electron beam techniques. Half of samples have been post-weld heat treated to produce a stress-relieved structure. The irradiation has been conducted in the Phenix reactor to doses of 63--65 dpa in the temperature range 450--459 C. The characterization of the welds, before and after irradiation, includes metallographic observations, hardness measurements, tensile and Charpy tests. It is shown that the mechanical properties of the welds after irradiation are in general similar to the characteristics obtained on the base metal, which is little affected by neutron irradiation.

  1. Low-cost and durable catalyst support for fuel cells: graphite...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cost and durable catalyst support for fuel cells: graphite submicronparticles. Low-cost and durable catalyst support for fuel cells: graphite submicronparticles. Abstract: Low-cost...

  2. Assessment of Metal Media Filters for Advanced Coal-Based Power Generation Applications

    SciTech Connect (OSTI)

    Alvin, M.A.

    2002-09-19T23:59:59.000Z

    Advanced coal and biomass-based gas turbine power generation technologies (IGCC, PFBC, PCFBC, and Hipps) are currently under development and demonstration. Efforts at Siemens Westinghouse Power Corporation (SWPC) have been focused on the development and demonstration of hot gas filter systems as an enabling technology for power generation. This paper reviews SWPC's material and component assessment efforts, identifying the performance, stability, and life of porous metal, advanced alloy, and intermetallic filters under simulated, pressurized fluidized-bed combustion conditions.

  3. Creep rupture testing of alloy 617 and A508/533 base metals and weldments.

    SciTech Connect (OSTI)

    Natesan, K.; Li, M.; Soppet, W.K.; Rink, D.L. (Nuclear Engineering Division)

    2012-01-17T23:59:59.000Z

    The NGNP, which is an advanced HTGR concept with emphasis on both electricity and hydrogen production, involves helium as the coolant and a closed-cycle gas turbine for power generation with a core outlet/gas turbine inlet temperature of 750-1000 C. Alloy 617 is a prime candidate for VHTR structural components such as reactor internals, piping, and heat exchangers in view of its resistance to oxidation and elevated temperature strength. However, lack of adequate data on the performance of the alloy in welded condition prompted to initiate a creep test program at Argonne National Laboratory. In addition, Testing has been initiated to evaluate the creep rupture properties of the pressure vessel steel A508/533 in air and in helium environments. The program, which began in December 2009, was certified for quality assurance NQA-1 requirements during January and February 2010. Specimens were designed and fabricated during March and the tests were initiated in April 2010. During the past year, several creep tests were conducted in air on Alloy 617 base metal and weldment specimens at temperatures of 750, 850, and 950 C. Idaho National Laboratory, using gas tungsten arc welding method with Alloy 617 weld wire, fabricated the weldment specimens. Eight tests were conducted on Alloy 617 base metal specimens and nine were on Alloy 617 weldments. The creep rupture times for the base alloy and weldment tests were up to {approx}3900 and {approx}4500 h, respectively. The results showed that the creep rupture lives of weld specimens are much longer than those for the base alloy, when tested under identical test conditions. The test results also showed that the creep strain at fracture is in the range of 7-18% for weldment samples and were much lower than those for the base alloy, under similar test conditions. In general, the weldment specimens showed more of a flat or constant creep rate region than the base metal specimens. The base alloy and the weldment exhibited tertiary creep after 50-60% of the rupture life, irrespective of test temperature in the range of 750-950 C. The results showed that the stress dependence of the creep rate followed a power law for both base alloy and weldments. The data also showed that the stress exponent for creep is the same and one can infer that the same mechanism is operative in both base metal and weldments in the temperature range of the current study. SEM fractography analysis indicated that both base metal and weldment showed combined fracture modes consisting of dimple rupture and intergranular cracking. Intergranular cracking was more evident in the weldment specimens, which is consistent with the observation of lower creep ductility in the weldment than in the base metal.

  4. Multi component Nanoparticle Based Lubricant Additive to Improve...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Multi-component Nanoparticle Based Lubricant Additive to Improve Efficiency and Durability in Engines ITP Nanomanufacturing:...

  5. Method for separating metal chelates from other materials based on solubilities in supercritical fluids

    DOE Patents [OSTI]

    Wai, Chien M. (Moscow, ID); Smart, Neil G. (Workington, GB); Phelps, Cindy (Moscow, ID)

    2001-01-01T23:59:59.000Z

    A method for separating a desired metal or metalloi from impurities using a supercritical extraction process based on solubility differences between the components, as well as the ability to vary the solvent power of the supercritical fluid, is described. The use of adduct-forming agents, such as phosphorous-containing ligands, to separate metal or metalloid chelates in such processes is further disclosed. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of .beta.-diketones; phosphine oxides, such as trialkylphosphine oxides, triarylphosphine oxides and alkylarylphosphine oxides; phosphinic acids; carboxylic acids; phosphates, such as trialkylphosphates, triarylphosphates and alkylarylphosphates; crown ethers; dithiocarbamates; phosphine sulfides; phosphorothioic acids; thiophosphinic acids; halogenated analogs of these chelating agents; and mixtures of these chelating agents. In especially preferred embodiments, at least one of the chelating agents is fluorinated.

  6. Durability of Poly(Methyl Methacrylate) Lenses Used in Concentrating Photovoltaic Technology (Revised) (Presentation)

    SciTech Connect (OSTI)

    Miller, D. C.; Carloni, J. D.; Pankow, J. W.; Gjersing, E. L.; To, B.; Packard, C. E.; Kennedy, C. E.; Kurtz, S. R.

    2012-01-01T23:59:59.000Z

    Concentrating photovoltaic (CPV) technology recently gained interest based on its expected low levelized cost of electricity, high efficiency, and scalability. Many CPV systems employ Fresnel lenses composed of poly(methyl methacrylate) (PMMA) to obtain a high optical flux density on the cell. The optical and mechanical durability of these lenses, however, is not well established relative to the desired surface life of 30 years. Our research aims to quantify the expected lifetime of PMMA in key market locations (FL, AZ, and CO).

  7. Effect of System and Air Contaminants on PEMFC Performance and Durability (Presentation)

    SciTech Connect (OSTI)

    Dinh, H.

    2010-06-11T23:59:59.000Z

    This presentation summarizes Effect of System and Air Contaminants on PEMFC Performance and Durability.

  8. DOE Zero Energy Ready Home: Durable Energy Builders, Houston...

    Energy Savers [EERE]

    roof, 11,500 gallon rainwater cistern to supply most of the home's drinking water, hurricane-proof roof, and triple-pane windows. DOE Zero Energy Ready Home: Durable Energy...

  9. Request for Information: Photovoltaic Reliability and Durability Research and Development

    Broader source: Energy.gov [DOE]

    The United States Department of Energy (DOE) – Office of Energy Efficiency and Renewable Energy (EERE) seeks feedback from industry, academia, research laboratories, government agencies, and other stakeholders on issues related to solar photovoltaic (PV) reliability and durability research and development.

  10. Durability of Diesel Engine Particulate Filters CRADA No. ORNL...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filters CRADA No. ORNL-04-0692 with Cummins Inc. Durability of Diesel Engine Particulate Filters CRADA No. ORNL-04-0692 with Cummins Inc. Presentation from the U.S. DOE Office of...

  11. affects durably bonding: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Marc Cahayb made of these materials are very unstable. Beginning in 2001, we have studied rare-earth (RE Boolchand, Punit 124 High-cycle fatigue and durability of polycrystalline...

  12. Performance and durability of PSA Peugeot Citroen's DPF System...

    Broader source: Energy.gov (indexed) [DOE]

    long idle) Next step : durability at 120,000 km trap after re-manufacturing 22 Acknowledgement The authors would like to thank: Institut Franais du Ptrole (IFP) PSA Peugeot...

  13. New Cerium-Based Metal-Organic Scintillators for Radiation Detection

    SciTech Connect (OSTI)

    Boatner, Lynn A [ORNL; Neal, John S [ORNL; Ramey, Joanne Oxendine [ORNL; Chakoumakos, Bryan C [ORNL; Custelcean, Radu [ORNL; Van Loef, Edgar [Radiation Monitoring Devices, Watertown, MA; Markosyan, G [Radiation Monitoring Devices, Watertown, MA

    2013-01-01T23:59:59.000Z

    We have previously shown that a new class of scintillating materials can be developed based on the synthesis and crystal growth of rare-earth metal-organic compounds. The first scintillator of this type consisted of single crystals of CeCl3(CH3OH)4 that were grown from a methanol solution. These crystals were shown to be applicable to both gamma-ray and fast neutron detection. Subsequently, metal-organic scintillators consisting of the compound LaBr3(CH3OH)4 activated with varying levels of Ce3+ and of CeBr3(CH3OH)4 were grown in single crystal form. We have now extended the development of this new class of scintillators to more complex organic components by reacting rare-earth halides such as CeCl3 or CeBr3 with different isomers of propanol and butanol including 1-propanol, isobutanol, n-butanol, and tert-butanol. The reaction of CeCl3 or CeBr3 with these organics results in the formation of new and relatively complex molecular crystals whose structures were determined using single-crystal X-ray diffraction. These new metal-organic scintillating materials were grown in single crystal form from solution, and their scintillation characteristics have been investigated using X-ray-excited luminescence plus energy spectra obtained with gamma-ray and alpha-particle sources. If the reactions between the inorganic and organic components are not carried out under very dry and highly controlled conditions, molecular structures can be formed that incorporate waters of hydration. The present observation of scintillation in these hydrated rare-earth metal-organic compounds is apparently an original finding, since we are not aware of any previous reports of scintillation being observed in a material that incorporates waters of hydration

  14. Facile creation of bio-inspired superhydrophobic Ce-based metallic glass surfaces

    SciTech Connect (OSTI)

    Liu Kesong; Li Zhou [Key Laboratory of Bio-Inspired Smart Interfacial Science and Technology of Ministry of Education, School of Chemistry and Environment, Beihang University, Beijing 100191 (China); Wang Weihua [Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Jiang Lei [Key Laboratory of Bio-Inspired Smart Interfacial Science and Technology of Ministry of Education, School of Chemistry and Environment, Beihang University, Beijing 100191 (China); Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190 (China)

    2011-12-26T23:59:59.000Z

    A bio-inspired synthesis strategy was conducted to fabricate superhydrophobic Ce-based bulk metallic glass (BMG) surfaces with self-cleaning properties. Micro-nanoscale hierarchical structures were first constructed on BMG surfaces and then modified with the low surface energy coating. Surface structures, surface chemical compositions, and wettability were characterized by combining scanning electron microscopy, atomic force microscopy, x-ray photoelectron spectroscopy, and contact angle measurements. Research indicated that both surface multiscale structures and the low surface free energy coating result in the final formation of superhydrophobicity.

  15. Supercapacitors Based on Metal Electrodes Prepared from Nanoparticle Mixtures at Room Temperature

    SciTech Connect (OSTI)

    Nakanishi, Hideyuki [Northwestern Univ., Evanston, IL (United States); Grzybowski, Bartosz A. [Northwestern Univ., Evanston, IL (United States)

    2010-01-01T23:59:59.000Z

    Films comprising Au and Ag nanoparticles are transformed into porous metal electrodes by desorption of weak organic ligands followed by wet chemical etching of silver. Thus prepared electrodes provide the basis for supercapacitors whose specific capacitances approach 70 F/g. Cyclic voltammetry measurement yield “rectangular” I?V curves even at high scan rates, indicating that the supercapacitors have low internal resistance. Owing to this property, the supercapacitors have a high power density ?12 kW/kg, comparable with that of the state-of-the-art carbon-based devices. The entire assembly protocol does not require high-temperature processing or the use of organic binders.

  16. Glass durability evaluation using product consistency, single-pass flow-through, and vapor hydration tests

    SciTech Connect (OSTI)

    Feng, X.; Hrma, P.; Kim, D. [Pacific Northwest National Lab., Richland, WA (United States)] [and others

    1996-12-31T23:59:59.000Z

    The current approach to assessing chemical durability of waste glasses focuses on a suite of short-term laboratory tests such as dynamic single-pass flow-through (SPFT) tests, static product consistency tests (PCT), and vapor hydration tests. The behavior of the glasses in the three types of tests is quite different, but each test provides insight into the glass corrosion process. The PCT data showed that at constant alumina, silica, and sodium levels the glass durability order for different glass systems is: Boron-series > Boron-Calcium-series > Calcium-series, while the opposite order is observed in SPFT tests. The order for vapor hydration tests is similar to that observed in the PCT tests. The PCT results are consistent with the current understanding of glass structure and are consistent with vapor hydration tests. The SPFT results can be explained using arguments based on solution chemistry.

  17. Exploring Phase Change Memory and 3D Die-Stacking for Power/Thermal Friendly, Fast and Durable Memory Architectures

    E-Print Network [OSTI]

    Kavi, Krishna

    Exploring Phase Change Memory and 3D Die-Stacking for Power/Thermal Friendly, Fast and Durable) as a promising candidate to achieve scalable, low power and thermal friendly memory system architecture leakages and retention time. DRAM-based main memory is also consuming an increasing proportion of the power

  18. Performance limits of tunnel transistors based on mono-layer transition-metal dichalcogenides

    SciTech Connect (OSTI)

    Jiang, Xiang-Wei, E-mail: xwjiang@semi.ac.cn; Li, Shu-Shen [State Key Laboratory of Superlattices and Microstructures, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083 (China); Synergetic Innovation Center of Quantum Information and Quantum Physics, University of Science and Technology of China, Hefei, Anhui 230026 (China)

    2014-05-12T23:59:59.000Z

    Performance limits of tunnel field-effect transistors based on mono-layer transition metal dichalcogenides are investigated through numerical quantum mechanical simulations. The atomic mono-layer nature of the devices results in a much smaller natural length ?, leading to much larger electric field inside the tunneling diodes. As a result, the inter-band tunneling currents are found to be very high as long as ultra-thin high-k gate dielectric is possible. The highest on-state driving current is found to be close to 600??A/?m at V{sub g}?=?V{sub d}?=?0.5?V when 2?nm thin HfO{sub 2} layer is used for gate dielectric, outperforming most of the conventional semiconductor tunnel transistors. In the five simulated transition-metal dichalcogenides, mono-layer WSe{sub 2} based tunnel field-effect transistor shows the best potential. Deep analysis reveals that there is plenty room to further enhance the device performance by either geometry, alloy, or strain engineering on these mono-layer materials.

  19. Anionic Gallium-Based Metal;#8722;Organic Framework and Its Sorption and Ion-Exchange Properties

    SciTech Connect (OSTI)

    Banerjee, Debasis; Kim, Sun Jin; Wu, Haohan; Xu, Wenqian; Borkowski, Lauren A.; Li, Jing; Parise, John B. (Kwangju); (Rutgers); (SBU)

    2012-04-30T23:59:59.000Z

    A gallium-based metal-organic framework Ga{sub 6}(C{sub 9}H{sub 3}O{sub 6}){sub 8} {center_dot} (C{sub 2}H{sub 8}N){sub 6}(C{sub 3}H{sub 7}NO){sub 3}(H{sub 2}O){sub 26} [1, Ga{sub 6}(1,3,5-BTC){sub 8} {center_dot} 6DMA {center_dot} 3DMF {center_dot} 26H{sub 2}O], GaMOF-1; BTC = benzenetricarboxylate/trimesic acid and DMA = dimethylamine, with space group I{bar 4}3d, a = 19.611(1) {angstrom}, and V = 7953.4(6) {angstrom}{sup 3}, was synthesized using solvothermal techniques and characterized by synchrotron-based X-ray microcrystal diffraction. Compound 1 contains isolated gallium tetrahedra connected by the organic linker (BTC) forming a 3,4-connected anionic porous network. Disordered positively charged ions and solvent molecules are present in the pore, compensating for the negative charge of the framework. These positively charged molecules could be exchanged with alkali-metal ions, as is evident by an ICP-MS study. The H{sub 2} storage capacity of the parent framework is moderate with a H{sub 2} storage capacity of {approx}0.5 wt % at 77 K and 1 atm.

  20. Heterojunction thin films based on multifunctional metal oxides for photovoltaic application

    SciTech Connect (OSTI)

    Prabhu, M.; Soundararajan, N.; Ramachandran, K. [School of Physics, Madurai Kamaraj University, Madurai - 625021 (India); Marikkannan, M.; Mayandi, J. [School of Chemistry, Madurai Kamaraj University, Madurai - 625021 (India)

    2014-04-24T23:59:59.000Z

    Metal oxides based multifunctional heterojunction thin films of ZnO/SnO{sub 2} and ZnO/SnO{sub 2}/CuO QDs were prepared by spin-coating technique. The crystallographic properties and the surface morphologies of the films were studied by X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. The optical absorption studies revealed that the film thickness has considerable effect on the band gap values and is found to be in the range of 3.73–3.48 eV. The photoluminescence spectra showed several weak visible emission peaks related to the deep level defects (450-575 nm). Finally, the current density-voltage (J-V) characteristic of ZnO/SnO{sub 2}/CuO QDs (ZSCI) based heterojunction thin film coated on ITO is also reported.

  1. LaNi.sub.5 is-based metal hydride electrode in Ni-MH rechargeable cells

    DOE Patents [OSTI]

    Bugga, Ratnakumar V. (Arcadia, CA); Fultz, Brent (Pasadena, CA); Bowman, Robert (La Mesa, CA); Surampudi, Subra Rao (Glendora, CA); Witham, Charles K. (Pasadena, CA); Hightower, Adrian (Pasadena, CA)

    1999-01-01T23:59:59.000Z

    An at least ternary metal alloy of the formula AB.sub.(Z-Y) X.sub.(Y) is disclosed. In this formula, A is selected from the rare earth elements, B is selected from the elements of Groups 8, 9, and 10 of the Periodic Table of the Elements, and X includes at least one of the following: antimony, arsenic, germanium, tin or bismuth. Z is greater than or equal to 4.8 and less than or equal to 6.0. Y is greater than 0 and less than 1. Ternary or higher-order substitutions to the base AB.sub.5 alloys that form strong kinetic interactions with the predominant metals in the base metal hydride are used to form metal alloys with high structural integrity after multiple cycles of hydrogen sorption.

  2. Erectile Function Durability Following Permanent Prostate Brachytherapy

    SciTech Connect (OSTI)

    Taira, Al V. [Department of Radiation Oncology, University of Washington, Seattle, WA (United States); Merrick, Gregory S., E-mail: gmerrick@urologicresearchinstitute.or [Schiffler Cancer Center, Wheeling Jesuit University, Wheeling, West Virginia (United States); Galbreath, Robert W.; Butler, Wayne M. [Schiffler Cancer Center, Wheeling Jesuit University, Wheeling, West Virginia (United States); Wallner, Kent E. [Puget Sound Healthcare Corporation, Group Health Cooperative, University of Washington, Seattle, WA (United States); Kurko, Brian S.; Anderson, Richard; Lief, Jonathan H. [Schiffler Cancer Center, Wheeling Jesuit University, Wheeling, West Virginia (United States)

    2009-11-01T23:59:59.000Z

    Purpose: To evaluate long-term changes in erectile function following prostate brachytherapy. Methods and Materials: This study included 226 patients with prostate cancer and preimplant erectile function assessed by the International Index of Erectile Function-6 (IIEF-6) who underwent brachytherapy in two prospective randomized trials between February 2001 and January 2003. Median follow-up was 6.4 years. Pre- and postbrachytherapy potency was defined as IIEF-6 >= 13 without pharmacologic or mechanical support. The relationship among clinical, treatment, and dosimetric parameters and erectile function was examined. Results: The 7-year actuarial rate of potency preservation was 55.6% with median postimplant IIEF of 22 in potent patients. Potent patients were statistically younger (p = 0.014), had a higher preimplant IIEF (p < 0.001), were less likely to be diabetic (p = 0.002), and were more likely to report nocturnal erections (p = 0.008). Potency preservation in men with baseline IIEF scores of 29-30, 24-28, 18-23, and 13-17 were 75.5% vs. 73.6%, 51.7% vs. 44.8%, 48.0% vs. 40.0%, and 23.5% vs. 23.5% in 2004 vs. 2008. In multivariate Cox regression analysis, preimplant IIEF, hypertension, diabetes, prostate size, and brachytherapy dose to proximal penis strongly predicted for potency preservation. Impact of proximal penile dose was most pronounced for men with IIEF of 18-23 and aged 60-69. A significant minority of men who developed postimplant impotence ultimately regained erectile function. Conclusion: Potency preservation and median IIEF scores following brachytherapy are durable. Thoughtful dose sparing of proximal penile structures and early penile rehabilitation may further improve these results.

  3. Fiber-based adsorbents having high adsorption capacities for recovering dissolved metals and methods thereof

    DOE Patents [OSTI]

    Janke, Christopher J; Dai, Sheng; Oyola, Yatsandra

    2014-05-13T23:59:59.000Z

    A fiber-based adsorbent and a related method of manufacture are provided. The fiber-based adsorbent includes polymer fibers with grafted side chains and an increased surface area per unit weight over known fibers to increase the adsorption of dissolved metals, for example uranium, from aqueous solutions. The polymer fibers include a circular morphology in some embodiments, having a mean diameter of less than 15 microns, optionally less than about 1 micron. In other embodiments, the polymer fibers include a non-circular morphology, optionally defining multiple gear-shaped, winged-shaped or lobe-shaped projections along the length of the polymer fibers. A method for forming the fiber-based adsorbents includes irradiating high surface area polymer fibers, grafting with polymerizable reactive monomers, reacting the grafted fibers with hydroxylamine, and conditioning with an alkaline solution. High surface area fiber-based adsorbents formed according to the present method demonstrated a significantly improved uranium adsorption capacity per unit weight over existing adsorbents.

  4. Impact of Biodiesel Impurities on the Performance and Durability of DOC, DPF and SCR Technologies

    SciTech Connect (OSTI)

    Williams, A.; McCormick, R.; Luecke, J.; Brezny, R.; Geisselmann, A.; Voss, K.; Hallstrom, K.; Leustek, M.; Parsons, J.; Abi-Akar, H.

    2011-06-01T23:59:59.000Z

    It is estimated that operating continuously on a B20 fuel containing the current allowable ASTM specification limits for metal impurities in biodiesel could result in a doubling of ash exposure relative to lube-oil derived ash. The purpose of this study was to determine if a fuel containing metals at the ASTM limits could cause adverse impacts on the performance and durability of diesel emission control systems. An accelerated durability test method was developed to determine the potential impact of these biodiesel impurities. The test program included engine testing with multiple DPF substrate types as well as DOC and SCR catalysts. The results showed no significant degradation in the thermo-mechanical properties of cordierite, aluminum titanate, or silicon carbide DPFs after exposure to 150,000 mile equivalent biodiesel ash and thermal aging. However, exposure of a cordierite DPF to 435,000 mile equivalent aging resulted in a 69% decrease in the thermal shock resistance parameter. It is estimated that the additional ash from 150,000 miles of biodiesel use would also result in a moderate increases in exhaust backpressure for a DPF. A decrease in DOC activity was seen after exposure to 150,000 mile equivalent aging, resulting in higher HC slip and a reduction in NO{sub 2} formation. The metal-zeolite SCR catalyst experienced a slight loss in activity after exposure to 435,000 mile equivalent aging. This catalyst, placed downstream of the DPF, showed a 5% reduction in overall NOx conversion activity over the HDDT test cycle.

  5. DURABILITY TESTING OF FLUIDIZED BED STEAM REFORMER (FBSR) WASTE FORMS

    SciTech Connect (OSTI)

    Jantzen, C

    2006-01-06T23:59:59.000Z

    Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of high sodium aqueous radioactive wastes. The addition of clay and a catalyst as co-reactants converts high sodium aqueous low activity wastes (LAW) such as those existing at the Hanford and Idaho DOE sites to a granular ''mineralized'' waste form that may be made into a monolith form if necessary. Simulant Hanford and Idaho high sodium wastes were processed in a pilot scale FBSR at Science Applications International Corporation (SAIC) Science and Technology Applications Research (STAR) facility in Idaho Falls, ID. Granular mineral waste forms were made from (1) a basic Hanford Envelope A low-activity waste (LAW) simulant and (2) an acidic INL simulant commonly referred to as sodium-bearing waste (SBW). The FBSR waste forms were characterized and the durability tested via ASTM C1285 (Product Consistency Test), the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP), and the Single Pass Flow Through (SPFT) test. The durability of the FBSR waste form products was tested in order to compare the measured durability to previous FBSR waste form testing on Hanford Envelope C waste forms that were made by THOR Treatment Technologies (TTT) and to compare the FBSR durability to vitreous LAW waste forms, specifically the Hanford low activity waste (LAW) glass known as the Low-activity Reference Material (LRM). The durability of the FBSR waste form is comparable to that of the LRM glass for the test responses studied.

  6. Proton-induced transient effects in a metal-semiconductor-metal (MSM) photodetector for optical-based data transfer

    SciTech Connect (OSTI)

    Marshall, C.J. [NASA/GSFC, Greenbelt, MD (United States)] [NASA/GSFC, Greenbelt, MD (United States); [NRL, Washington, DC (United States); Marshall, P.W.; Carts, M.A. [NRL, Washington, DC (United States)] [NRL, Washington, DC (United States); [SFA, Largo, MD (United States); Reed, R.A.; LaBel, K.A. [NASA/GSFC, Greenbelt, MD (United States)] [NASA/GSFC, Greenbelt, MD (United States)

    1998-12-01T23:59:59.000Z

    The authors present a study of proton transient effects in metal-semiconductor-metal (MSM) photodetectors, which demonstrates their inherent advantage for minimizing Single Event Effects (SEEs) in proton environments. Upset mechanisms are characterized for 830 nm GaAs and 1300 nm InGaAs detectors. Only protons incident at grazing angles are likely to cause a bit errors by direct ionization. The MSM technology appears to be a more robust to single bit errors than thicker 1300 nm p-i-n diode structures which the authors have previously shown to be susceptible to errors from direct ionization events at all angles, and also are relatively high optical powders. For a given receiver, the relative contributions of direct ionization and nuclear reaction upset mechanisms at a specific data rate and optical power are determined by the geometry of the charge collection volume of the detector. The authors show that state-of-the-art p-i-n detectors can also display a reduced sensitivity to direct ionization by incident protons except at grazing angles.

  7. PASSIVATION LAYER STABILITY OF A METALLIC ALLOY WASTE FORM

    SciTech Connect (OSTI)

    Williamson, M.; Mickalonis, J.; Fisher, D.; Sindelar, R.

    2010-08-16T23:59:59.000Z

    Alloy waste form development under the Waste Forms Campaign of the DOE-NE Fuel Cycle Research & Development program includes the process development and characterization of an alloy system to incorporate metal species from the waste streams generated during nuclear fuel recycling. This report describes the tests and results from the FY10 activities to further investigate an Fe-based waste form that uses 300-series stainless steel as the base alloy in an induction furnace melt process to incorporate the waste species from a closed nuclear fuel recycle separations scheme. This report is focused on the initial activities to investigate the formation of oxyhydroxide layer(s) that would be expected to develop on the Fe-based waste form as it corrodes under aqueous repository conditions. Corrosion tests were used to evaluate the stability of the layer(s) that can act as a passivation layer against further corrosion and would affect waste form durability in a disposal environment.

  8. Direct measurement of the kinetics of volume and enthalpy relaxation of an Au-based bulk metallic glass

    SciTech Connect (OSTI)

    Bünz, J.; Wilde, G. [Institute of Materials Physics, University of Münster, 48149 Münster (Germany)] [Institute of Materials Physics, University of Münster, 48149 Münster (Germany)

    2013-12-14T23:59:59.000Z

    Structural relaxation of glasses below their glass transition is a well-studied phenomenon that still poses several open issues. With the advent of bulk metallic glasses with exceptionally low glass transition temperatures, new options are available that are based on the experimental assessment of the time dependence of several different thermodynamic quantities by direct measurements with high accuracy. In this contribution the first direct measurement of the isothermal relaxation of the volume and the enthalpy of an Au-based bulk metallic glassformer are reported and discussed with respect of the characteristics describing the underlying processes.

  9. Determination of welding fume size with time using E7018 electrodes and A131B base metal 

    E-Print Network [OSTI]

    Owen, Richard James

    1976-01-01T23:59:59.000Z

    DETERMINATION OF WELDING FUME SIZE WITH TIME USING E7018 ELECTRODES AND A131B BASE METAL A Thesis by RICHARD JAMES OWEN Submitted to the Graduate College of Texas AILM University in partial fulfillment of the requirement for the degree... of MASTER OF SCIENCE December 1976 Major Subject: Industrial Hygiene DETERMINATION OF WELDING FUME SIZE WITH TIME USING E7018 ELECTRODES AND Al 318 BASE METAL A Thesis by RICHARD JAMES OWEN Approved as to style and content by: Cha&rman of Comm t ad...

  10. Lewis Acid-Base Interactions between Polysulfides and Metal Organic Framework in Lithium Sulfur Batteries

    SciTech Connect (OSTI)

    Zheng, Jianming; Tian, Jian; Wu, Dangxin; Gu, Meng; Xu, Wu; Wang, Chong M.; Gao, Fei; Engelhard, Mark H.; Zhang, Jiguang; Liu, Jun; Xiao, Jie

    2014-04-04T23:59:59.000Z

    Lithium-sulfur (Li-S) battery is one of the most promising energy storage systems because of its high specific capacity of 1675 mAh g-1 based on sulfur. However, the rapid capacity degradation, mainly caused by polysulfide dissolution, remains a significant challenge prior to practical applications. Here, we report a novel Ni-based metal organic framework (Ni-MOF), Ni6(BTB)4(BP)3 (BTB = benzene-1,3,5-tribenzoate and BP = 4,4?-bipridyl), that can remarkably immobilize polysulfides within the cathode structure through physical and chemical interactions at the molecular level. The capacity retention achieves up to 89% after 100 cycles at 0.1 C. The interwoven mesopores (~2.8 nm) and micropores (~1.4 nm) of Ni-MOF firstly provide an ideal matrix to confine polysulfides. Additionally, the strong interactions between Lewis acidic Ni(II) center and the polysulfides base significantly slow down the migration of soluble polysulfides out of the pores, which leads to the excellent cycling performance of Ni-MOF/S composite.

  11. Attrition resistant catalysts and sorbents based on heavy metal poisoned FCC catalysts

    DOE Patents [OSTI]

    Gangwal, S.; Jothimurugesan, K.

    1999-07-27T23:59:59.000Z

    A heavy metal poisoned, spent FCC catalyst is treated by chemically impregnating the poisoned catalyst with a new catalytic metal or metal salt to provide an attrition resistant catalyst or sorbent for a different catalytic or absorption process, such as catalysts for Fischer-Tropsh Synthesis, and sorbents for removal of sulfur gases from fuel gases and flue-gases. The heavy metal contaminated FCC catalyst is directly used as a support for preparing catalysts having new catalytic properties and sorbents having new sorbent properties, without removing or passivating the heavy metals on the spent FCC catalyst as an intermediate step.

  12. Novel Sorbent-Based Process for High Temperature Trace Metal Removal

    SciTech Connect (OSTI)

    Gokhan Alptekin

    2008-09-30T23:59:59.000Z

    The objective of this project was to demonstrate the efficacy of a novel sorbent can effectively remove trace metal contaminants (Hg, As, Se and Cd) from actual coal-derived synthesis gas streams at high temperature (above the dew point of the gas). The performance of TDA's sorbent has been evaluated in several field demonstrations using synthesis gas generated by laboratory and pilot-scale coal gasifiers in a state-of-the-art test skid that houses the absorbent and all auxiliary equipment for monitoring and data logging of critical operating parameters. The test skid was originally designed to treat 10,000 SCFH gas at 250 psig and 350 C, however, because of the limited gas handling capabilities of the test sites, the capacity was downsized to 500 SCFH gas flow. As part of the test program, we carried out four demonstrations at two different sites using the synthesis gas generated by the gasification of various lignites and a bituminous coal. Two of these tests were conducted at the Power Systems Demonstration Facility (PSDF) in Wilsonville, Alabama; a Falkirk (North Dakota) lignite and a high sodium lignite (the PSDF operator Southern Company did not disclose the source of this lignite) were used as the feedstock. We also carried out two other demonstrations in collaboration with the University of North Dakota Energy Environmental Research Center (UNDEERC) using synthesis gas slipstreams generated by the gasification of Sufco (Utah) bituminous coal and Oak Hills (Texas) lignite. In the PSDF tests, we showed successful operation of the test system at the conditions of interest and showed the efficacy of sorbent in removing the mercury from synthesis gas. In Test Campaign No.1, TDA sorbent reduced Hg concentration of the synthesis gas to less than 5 {micro}g/m{sup 3} and achieved over 99% Hg removal efficiency for the entire test duration. Unfortunately, due to the relatively low concentration of the trace metals in the lignite feed and as a result of the intermittent operation of the PSDF gasifier (due to the difficulties in the handling of the low quality lignite), only a small fraction of the sorbent capacity was utilized (we measured a mercury capacity of 3.27 mg/kg, which is only a fraction of the 680 mg/kg Hg capacity measured for the same sorbent used at our bench-scale evaluations at TDA). Post reaction examination of the sorbent by chemical analysis also indicated some removal As and Se (we did not detect any significant amounts of Cd in the synthesis gas or over the sorbent). The tests at UNDEERC was more successful and showed clearly that the TDA sorbent can effectively remove Hg and other trace metals (As and Se) at high temperature. The on-line gas measurements carried out by TDA and UNDEERC separately showed that TDA sorbent can achieve greater than 95% Hg removal efficiency at 260 C ({approx}200g sorbent treated more than 15,000 SCF synthesis gas). Chemical analysis conducted following the tests also showed modest amounts of As and Se accumulation in the sorbent bed (the test durations were still short to show higher capacities to these contaminants). We also evaluated the stability of the sorbent and the fate of mercury (the most volatile and unstable of the trace metal compounds). The Synthetic Ground Water Leaching Procedure Test carried out by an independent environmental laboratory showed that the mercury will remain on the sorbent once the sorbent is disposed. Based on a preliminary engineering and cost analysis, TDA estimated the cost of mercury removal from coal-derived synthesis gas as $2,995/lb (this analysis assumes that this cost also includes the cost of removal of all other trace metal contaminants). The projected cost will result in a small increase (less than 1%) in the cost of energy.

  13. Durable Joining of Dissimilar Materials - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power AdministrationField Campaign:INEA :Work with Jefferson Lab | JeffersonDurable FuelDurable

  14. The effect of chemical composition on the PCT durability of mixed waste glasses from wastewater treatment sludges

    SciTech Connect (OSTI)

    Resce, J.L.; Ragsdale, R.G.; Overcamp, T.J. [Clemson Univ., SC (United States); Bickford, D.F.; Cicero, C.A. [Savannah River Technology Center, Aiken, SC (United States)

    1995-01-25T23:59:59.000Z

    An experimental program has been designed to examine the chemical durability of glass compositions derived from the vitrification of simulated wastewater treatment sludges. These sludges represent the majority of low-level mixed wastes currently in need of treatment by the US DOE. The major oxides in these model glasses included SiO{sub 2}, Al{sub 2}O{sub 3}, B{sub 2}O{sub 3}, Na{sub 2}O, CaO and Fe{sub 2}O{sub 3}. In addition, three minor oxides, BaO, NiO, and PbO, were added as hazardous metals. The major oxides were each varied at two levels resulting in 32 experimental glasses. The chemical durability was measured by the 7-Day Product Consistency Test (PCT). The normalized sodium release rates (NRR{sub Na}) of these glasses ranged from 0.01 to 4.99 g/m{sup 2}. The molar ratio of the glass-former to glass-modifier (F/M) was found to have the greatest effect on PCT durability. Glass-formers included SiO{sub 2}, Al{sub 2}O{sub 3}, and B{sub 2}O{sub 3}, while Na{sub 2}O, CaO, BaO, NiO, and PbO were glass-modifiers. As this ratio increased from 0.75 to 2.0, NRR{sub Na} was found to decrease between one and two orders of magnitude. Another important effect on NRR{sub Na} was the Na{sub 2}O/CaO ratio. As this ratio increased from 0.5 to 2.0, NRR{sub Na} increased up to two orders of magnitude for the glasses with the low F/M ratio but almost no effect was observed for the glasses with the high F/M ratio. Increasing the iron oxide content from 2 to 18 mole% was found to decrease NRR{sub Na} one order of magnitude for the glasses with low F/M but iron had little effect on the glasses with the high F/M ratio. The durability also increased when 10 mole percent Al{sub 2}O{sub 3} was included in low iron oxide glasses but no effect was observed with the high iron glasses. The addition of B{sub 2}O{sub 3} had little effect on durability. The effects of other composition parameters on durability are discussed as well.

  15. Development of a Durable Low-Temperature Urea-SCR Catalyst for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Durable Low-Temperature Urea-SCR Catalyst for CIDI Engines Development of a Durable Low-Temperature Urea-SCR Catalyst for CIDI Engines 2004 Diesel Engine Emissions Reduction (DEER)...

  16. Thermal Durability of Cu-CHA NH3-SCR Catalysts for Diesel NOx...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Durability of Cu-CHA NH3-SCR Catalysts for Diesel NOx Reduction. Thermal Durability of Cu-CHA NH3-SCR Catalysts for Diesel NOx Reduction. Abstract: Multiple catalytic functions...

  17. Durability of Materials in a Stress-Response Framework: Acrylic Materials for Photovoltaic Systems

    E-Print Network [OSTI]

    Rollins, Andrew M.

    Durability of Materials in a Stress-Response Framework: Acrylic Materials for Photovoltaic Systems materials for enhanced photovoltaic (PV) performance, it is critical to have quantitative knowledge developed for solar radiation durability studies of solar and environmentally exposed photovoltaic materials

  18. PII S0016-7037(01)00579-8 The origin and evolution of base metal mineralising brines and hydrothermal fluids,

    E-Print Network [OSTI]

    Banks, David

    PII S0016-7037(01)00579-8 The origin and evolution of base metal mineralising brines are the source of the mineralising fluids. Cl and Br systematics suggest that the brines were formed either cation composition (Na, Ca, K, Mg) of the brines is not consistent solely with evaporation processes

  19. Environmental impacts of unmanaged solid waste at a former base metal mining and ore processing site (Kirki, Greece)

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Environmental impacts of unmanaged solid waste at a former base metal mining and ore processing-00553648,version1-30Jan2014 Author manuscript, published in "Waste Management & Research 28, 11 (2010) p, among the mining waste abandoned at a mine and processing plant, the most critical potential pollution

  20. Metal complex-based electron-transfer mediators in dye-sensitized solar cells

    DOE Patents [OSTI]

    Elliott, C. Michael (Fort Collins, CO); Sapp, Shawn A. (Broomfield, CO); Bignozzi, Carlo Alberto (Ferrara, IT); Contado, Cristiano (Legnago, IT); Caramori, Stefano (Viconovo, IT)

    2006-03-28T23:59:59.000Z

    This present invention provides a metal-ligand complex and methods for using and preparing the same. In particular, the metal-ligand complex of the present invention is of the formula: L.sub.a-M-X.sub.b where L, M, X, a, and b are those define herein. The metal-ligand complexes of the present invention are useful in a variety of applications including as electron-transfer mediators in dye-sensitized solar cells and related photoelectrochromic devices.

  1. Ten-year PVC geomembrane durability E. J. Newman1

    E-Print Network [OSTI]

    PROOFS Ten-year PVC geomembrane durability E. J. Newman1 and T. D. Stark2 1 Graduate Research of an ongoing study on the long-term performance of a PVC geomembrane in northern Minnesota are presented. Samples of PVC geomembrane and seams are exhumed periodically over a 30-year period and tested to measure

  2. SOLAR RADIATION DURABILITY OF MATERIALS, COMPONENTS AND SYSTEMS FOR PHOTOVOLTAICS

    E-Print Network [OSTI]

    Rollins, Andrew M.

    SOLAR RADIATION DURABILITY OF MATERIALS, COMPONENTS AND SYSTEMS FOR PHOTOVOLTAICS Myles P. Murray 1 exposed photovoltaic materials, is defined as the rate of photodarkening or photobleaching of a material testing. The potential to predict power losses in a photovoltaic system over time caused

  3. Cell Host & Microbe Durable Protection from Herpes Simplex Virus-2

    E-Print Network [OSTI]

    Lieberman, Judy

    Cell Host & Microbe Article Durable Protection from Herpes Simplex Virus-2 Transmission Following is a problem. Intravaginal administration of small interfering RNA (siRNA) lipoplexes targeting Herpes Simplex protection against viral transmission. INTRODUCTION Genital Herpes Simplex Virus 2 (HSV-2) infection causes

  4. TEACHING DURABILITY IN AUTOMOTIVE APPLICATIONS USING A RELIABILITY

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    , initially developed in the automotive industry and since extended to the aeronautical and mechanical a probabilistic method, initially developed in the automotive industry and since extended to the aeronautical1 TEACHING DURABILITY IN AUTOMOTIVE APPLICATIONS USING A RELIABILITY APPROACH Anne Morel (1), André

  5. Iron-Based Amorphous-Metals: High-Performance Corrosion-Resistant Material (HPCRM) Development

    SciTech Connect (OSTI)

    Farmer, J C; Choi, J S; Saw, C; Haslam, J; Day, D; Hailey, P; Lian, T; Rebak, R; Perepezko, J; Payer, J; Branagan, D; Beardsley, B; D'Amato, A; Aprigliano, L

    2008-01-09T23:59:59.000Z

    An overview of the High-Performance Corrosion-Resistant Materials (HPCRM) Program, which was co-sponsored by the Defense Advanced Research Projects Agency (DARPA) Defense Sciences Office (DSO) and the United States Department of Energy (DOE) Office of Civilian and Radioactive Waste Management (OCRWM), is discussed. Programmatic investigations have included a broad range of topics: alloy design and composition; materials synthesis; thermal stability; corrosion resistance; environmental cracking; mechanical properties; damage tolerance; radiation effects; and important potential applications. Amorphous alloys identified as SAM2X5 (Fe{sub 49.7}Cr{sub 17.7}Mn{sub 1.9}Mo{sub 7.4}W{sub 1.6}B{sub 15.2}C{sub 3.8}Si{sub 2.4}) and SAM1651 (Fe{sub 48}Mo{sub 14}Cr{sub 15}Y{sub 2}C{sub 15}B{sub 6}) have been produced as melt-spun ribbons, drop-cast ingots and thermal-spray coatings. Chromium (Cr), molybdenum (Mo) and tungsten (W) additions provided corrosion resistance, while boron (B) enabled glass formation. Earlier electrochemical studies of melt-spun ribbons and ingots of these amorphous alloys demonstrated outstanding passive film stability. More recently thermal-spray coatings of these amorphous alloys have been made and subjected to long-term salt-fog and immersion tests. Good corrosion resistance has been observed during salt-fog testing. Corrosion rates were measured in situ with linear polarization, while simultaneously monitoring the open-circuit corrosion potentials. Reasonably good performance was observed. The sensitivity of these measurements to electrolyte composition and temperature was determined. The high boron content of this particular amorphous metal makes this amorphous alloy an effective neutron absorber, and suitable for criticality control applications. In general, the corrosion resistance of such iron-based amorphous metals is maintained at operating temperatures up to the glass transition temperature. These materials are much harder than conventional stainless steel and nickel-based materials, and are proving to have excellent wear properties, sufficient to warrant their use in earth excavation, drilling and tunnel boring applications. Large areas have been successfully coated with these materials, with thicknesses of approximately one centimeter. The observed corrosion resistance may enable applications of importance in industries such as: oil and gas production, refining, nuclear power generation, shipping, and others.

  6. Iron-Based Amorphous Metals:The High Performance Corrosion Resistant Materials(HPCRM) Program

    SciTech Connect (OSTI)

    Farmer, J

    2007-07-09T23:59:59.000Z

    An overview of the High-Performance Corrosion-Resistant Materials (HPCRM) Program, which was co-sponsored by the Defense Advanced Research Projects Agency (DARPA) Defense Sciences Office (DSO) and the United States Department of Energy (DOE) Office of Civilian and Radioactive Waste Management (OCRWM), is discussed. Programmatic investigations have included a broad range of topics: alloy design and composition; materials synthesis; thermal stability; corrosion resistance; environmental cracking; mechanical properties; damage tolerance; radiation effects; and important potential applications. Amorphous alloys identified as SAM2X5 (Fe{sub 49.7}Cr{sub 17.7}Mn{sub 1.9}Mo{sub 7.4}W{sub 1.6}B{sub 15.2}C{sub 3.8}Si{sub 2.4}) and SAM1651 (Fe{sub 48}Mo{sub 14}Cr{sub 15}Y{sub 2}C{sub 15}B{sub 6}) have been produced as melt-spun ribbons, drop-cast ingots and thermal-spray coatings. Chromium (Cr), molybdenum (Mo) and tungsten (W) additions provided corrosion resistance, while boron (B) enabled glass formation. Earlier electrochemical studies of melt-spun ribbons and ingots of these amorphous alloys demonstrated outstanding passive film stability. More recently thermal-spray coatings of these amorphous alloys have been made and subjected to long-term salt-fog and immersion tests. Good corrosion resistance has been observed during salt-fog testing. Corrosion rates were measured in situ with linear polarization, while simultaneously monitoring the open-circuit corrosion potentials. Reasonably good performance was observed. The sensitivity of these measurements to electrolyte composition and temperature was determined. The high boron content of this particular amorphous metal makes this amorphous alloy an effective neutron absorber, and suitable for criticality control applications. In general, the corrosion resistance of such iron-based amorphous metals is maintained at operating temperatures up to the glass transition temperature. These materials are much harder than conventional stainless steel and nickel-based materials, and are proving to have excellent wear properties, sufficient to warrant their use in earth excavation, drilling and tunnel boring applications. Large areas have been successfully coated with these materials, with thicknesses of approximately one centimeter. The observed corrosion resistance may enable applications of importance in industries such as: oil and gas production, refining, nuclear power generation, shipping, and others.

  7. 2D-simulation and analysis of lateral SiC N-emitter SiGe P-base Schottky metal-collector (NPM) HBT on SOI

    E-Print Network [OSTI]

    Kumar, M. Jagadesh

    2D-simulation and analysis of lateral SiC N-emitter SiGe P-base Schottky metal-collector (NPM) HBT metal-collector NPM HBT on SOI. The proposed lateral NPM HBT performance has been evaluated in detail silicon NPM BJT structures. Based on our simu- lation results, it is observed that while both the lateral

  8. UNCORRECTED 2 Spall strength of a zirconium-based bulk metallic glass under

    E-Print Network [OSTI]

    Rollins, Andrew M.

    of Mechanical and Aerospace Engineering, Case Western Reserve University, 10900 Euclid Avenue, Glennan 616 B. Introduction 40 Bulk amorphous metals, also referred to as bulk metallic 41 glasses (BMG), are alloys in which super-cooling of a liquid 42 alloy produces a metastable phase, thus preventing forma- 43 tion

  9. A transport based one-dimensional perturbation code for reactivity calculations in metal systems

    SciTech Connect (OSTI)

    Wenz, T.R.

    1995-02-01T23:59:59.000Z

    A one-dimensional reactivity calculation code is developed using first order perturbation theory. The reactivity equation is based on the multi-group transport equation using the discrete ordinates method for angular dependence. In addition to the first order perturbation approximations, the reactivity code uses only the isotropic scattering data, but cross section libraries with higher order scattering data can still be used with this code. The reactivity code obtains all the flux, cross section, and geometry data from the standard interface files created by ONEDANT, a discrete ordinates transport code. Comparisons between calculated and experimental reactivities were done with the central reactivity worth data for Lady Godiva, a bare uranium metal assembly. Good agreement is found for isotopes that do not violate the assumptions in the first order approximation. In general for cases where there are large discrepancies, the discretized cross section data is not accurately representing certain resonance regions that coincide with dominant flux groups in the Godiva assembly. Comparing reactivities calculated with first order perturbation theory and a straight {Delta}k/k calculation shows agreement within 10% indicating the perturbation of the calculated fluxes is small enough for first order perturbation theory to be applicable in the modeled system. Computation time comparisons between reactivities calculated with first order perturbation theory and straight {Delta}k/k calculations indicate considerable time can be saved performing a calculation with a perturbation code particularly as the complexity of the modeled problems increase.

  10. Synthesis and Structural Characterization of Lithium-Based Metal?Organic Frameworks

    SciTech Connect (OSTI)

    Banerjee, Debasis; Borkowski, Lauren A.; Kim, Sun Jin; Parise, John B.; (IST-Korea); (SBU)

    2009-12-01T23:59:59.000Z

    Two lithium-based metal-organic frameworks, Li{sub 2}(C{sub 14}H{sub 8}O{sub 4}) [Li{sub 2}(4,4'-BPDC) [1]; ULMOF-2, UL = ultralight; BPDC = biphenyldicarboxylate]; space group P2{sub 1}/c, a = 12.758(2) {angstrom}, b = 5.142(4) {angstrom}, c = 8.00(2) {angstrom}, {beta} = 97.23{sup o}, V = 520.6(14) {angstrom}{sup 3} and Li{sub 2}(C{sub 14}H{sub 8}O{sub 6}S) [Li{sub 2}(4,4'-SDB) [2]; ULMOF-3, UL = ultralight; SDB = sulfonyldibenzoate], space group P2{sub 1}/n, a = 5.5480(11) {angstrom}, b = 23.450(5) {angstrom}, c = 10.320(2) {angstrom}, {beta} = 96.47(3){sup o}, V = 1334.1(5) {angstrom}3, were synthesized. Compounds 1 and 2 were synthesized by solvothermal methods and were characterized using single crystal X-ray diffraction. Structure 1 consists of layers of two-dimensional antifluorite related LiO motif connected by BPDC linkers, whereas structure 2 is constructed by a combination of tetrameric lithium polyhedral clusters connected by the sulfonyldibenzoate linker. The frameworks are stable up to 575 and 500 C, respectively, under N{sub 2} atmosphere.

  11. Multi-component Nanoparticle Based Lubricant Additive to Improve...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Nanoparticle Based Lubricant Additive to Improve Efficiency and Durability in Engines Multi-component Nanoparticle Based Lubricant Additive to Improve Efficiency and...

  12. Durable polymer-aerogel based superhydrophobic coatings, a composite material

    DOE Patents [OSTI]

    Kissel, David J; Brinker, Charles Jeffrey

    2014-03-04T23:59:59.000Z

    Provided are polymer-aerogel composite coatings, devices and articles including polymer-aerogel composite coatings, and methods for preparing the polymer-aerogel composite. The exemplary article can include a surface, wherein the surface includes at least one region and a polymer-aerogel composite coating disposed over the at least one region, wherein the polymer-aerogel composite coating has a water contact angle of at least about 140.degree. and a contact angle hysteresis of less than about 1.degree.. The polymer-aerogel composite coating can include a polymer and an ultra high water content catalyzed polysilicate aerogel, the polysilicate aerogel including a three dimensional network of silica particles having surface functional groups derivatized with a silylating agent and a plurality of pores.

  13. INITIAL CHARACTERIZATION AND PERFORMANCE EVALUATION OF A ZIRCONIUM-BASED METALLIC WASTE FORM

    SciTech Connect (OSTI)

    Kane, M; Robert Sindelar, R

    2008-09-30T23:59:59.000Z

    A metallic waste form or alloy system for immobilization of Zircaloy cladding hulls, Undissolved Solids (UDS), Technicium (Tc) metal and Transition Metal Fission Products (TMFP) waste stream materials from separations processes for commercial spent nuclear fuel has been developed, and initial characterization of the phase assemblage and composition, and corrosion testing under aqueous conditions has been completed for the waste form with various levels of surrogate waste species. The waste stream materials are those from processes being developed as part of the Separations Campaign under the Department of Energy's (DOE's) Global Nuclear Energy Partnership (GNEP) program. The development of waste forms for these materials is under the Waste Form Campaign.

  14. High-Efficiency 6?? Multicrystalline Black Solar Cells Based on Metal-Nanoparticle-Assisted Chemical Etching

    E-Print Network [OSTI]

    Hsu, W. Chuck

    2012-01-01T23:59:59.000Z

    Multicrystalline silicon (mc-Si) photovoltaic (PV) solar cells with nanoscale surface texturing by metal-nanoparticle-assisted etching are proposed to achieve high power efficiency. The investigation of average nanorod ...

  15. Consolidation of zirconium-based metallic glass powder by equal channel angular extrusion

    E-Print Network [OSTI]

    Robertson, Jonathan Mark

    2002-01-01T23:59:59.000Z

    tensile strength, hardness and impact fracture energy as well as viscous deformability and excellent resistances to both wear and corrosion [02]. Metallic glasses are appealing materials for applications in many areas of industry. It has also been shown... dimensions. In the past it was only possible to produce metallic glasses as thin ribbons due to the rapid cooling rates necessary to achieve an amorphous state. In the last decade, however, advances in the selection of composition of glass forming alloys...

  16. Method for improving the durability of ion insertion materials

    DOE Patents [OSTI]

    Lee, Se-Hee (Lakewood, CO); Tracy, C. Edwin (Golden, CO); Cheong, Hyeonsik M. (Seoul, KR)

    2002-01-01T23:59:59.000Z

    The invention provides a method of protecting an ion insertion material from the degradative effects of a liquid or gel-type electrolyte material by disposing a protective, solid ion conducting, electrically insulating, layer between the ion insertion layer and the liquid or gel-type electrolyte material. The invention further provides liquid or gel-type electrochemical cells having improved durability having a pair of electrodes, a pair of ion insertion layers sandwiched between the pair of electrodes, a pair of solid ion conducting layers sandwiched between the ion insertion layers, and a liquid or gel-type electrolyte material disposed between the solid ion conducting layers, where the solid ion conducting layer minimizes or prevents degradation of the faces of the ion insertion materials facing the liquid or gel-type electrolyte material. Electrochemical cells of this invention having increased durability include secondary lithium batteries and electrochromic devices.

  17. High H2 Storage of Hexagonal Metal-Organic Frameworks from First-Principles-Based Grand Canonical Monte Carlo Simulations

    E-Print Network [OSTI]

    Goddard III, William A.

    High H2 Storage of Hexagonal Metal-Organic Frameworks from First-Principles-Based Grand Canonical IRMOF-2-60, which we calculate to bind 9.7 wt % H2 storage at 77 K and 70 bar, the highest known value even at ambient temperatures. For example, IRMOF-2-96-Li leads to 6.0 wt % H2 storage at 273 K and 100

  18. Durable zinc ferrite sorbent pellets for hot coal gas desulfurization

    DOE Patents [OSTI]

    Jha, Mahesh C. (Arvada, CO); Blandon, Antonio E. (Thornton, CO); Hepworth, Malcolm T. (Edina, MN)

    1988-01-01T23:59:59.000Z

    Durable, porous sulfur sorbents useful in removing hydrogen sulfide from hot coal gas are prepared by water pelletizing a mixture of fine zinc oxide and fine iron oxide with inorganic and organic binders and small amounts of activators such as sodium carbonate and molybdenite; the pellets are dried and then indurated at a high temperature, e.g., 1800.degree. C., for a time sufficient to produce crush-resistant pellets.

  19. Correlation between medium-range order structure and glass-forming ability for Al-based metallic glasses

    SciTech Connect (OSTI)

    Wu, N. C. [College of Material and Metallurgy, Northeastern University, Shenyang 110004 (China); Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016 (China); Yan, M. [Queensland Centre for Advanced Materials Processing and Manufacturing (AMPAM), School of Mechanical and Mining Engineering, The University of Queensland, Brisbane (Australia); Zuo, L. [College of Material and Metallurgy, Northeastern University, Shenyang 110004 (China); Wang, J. Q., E-mail: jqwang@imr.ac.cn [Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016 (China)

    2014-01-28T23:59:59.000Z

    To clarify the correlation of medium-range order (MRO) structure with glass forming ability (GFA) of Al-based metallic glasses, Al{sub 86}Ni{sub 14-a}Y{sub a} (a?=?2?9 at.?%) metallic glasses were analyzed by x-ray diffraction in detail and further verified by synchrotron high-energy x-ray diffraction. The prepeak that reflects the MRO structural evolution was found to be much sensitive to alloy composition. We have proposed an icosahedral supercluster MRO structure model in Al-TM (transition metal)-RE (rare earth metal) system, which consists of 12 RE(TM)-centered clusters on the vertex of icosahedral supercluster, one RE(TM)-centered clusters in the center, and TM(RE) atoms located at RE(TM)-centered cluster tetrahedral interstices in the icosahedral supercluster. It was indicated that the MRO structural stability mainly depends on the interaction of efficient dense packing and electrochemical potential equalization principle. The Al{sub 86}Ni{sub 9}Y(La){sub 5} alloys present good GFA due to the combination of the two structural factors.

  20. A Durable Alternative for Proton-Exchange Membranes: Sulfonated Poly(Benzoxazole Thioether Sulfone)s

    SciTech Connect (OSTI)

    Zhao, Dan; Li, Jin Hui; Song, Min Kyu; Yi, Baolian; Zhang, Huamin; Liu, Meilin

    2011-01-01T23:59:59.000Z

    To develop a durable proton-exchange membrane (PEM) for fuel-cell applications, a series of sulfonated poly(benzoxazole thioether sulfone)s ( SPTESBOs) are designed and synthesized, with anticipated good dimensional stability (via acid–base cross linking), improved oxidative stability against free radicals (via incorporation of thioether groups), and enhanced inherent stability (via elimination of unstable end groups) of the backbone. The structures and the degree of sulfonation of the copolymers are characterized using Fourier-transform infrared spectroscopy, and nuclear magnetic resonance spectroscopy ({sup 1}H NMR and {sup 19}F NMR). The electrochemical stabilities of the monomers are examined using cyclic voltammetry in a typical three-electrode cell configuration. The physicochemical properties of the membranes vital to fuel-cell performance are also carefully evaluated under conditions relevant to fuel-cell operation, including chemical and thermal stability, proton conductivity, solubility in different solvents, water uptake, and swelling ratio. The new membranes exhibit low dimensional change at 25°C to 90°C and excellent thermal stability up to 250°C. Upon elimination of unstable end groups, the co-polymers display enhanced chemical resistance and oxidative stability in Fenton's test. Further, the SPTESBO-HFB-60 (HFB-60=hexafluorobenzene, 60 mol% sulfone) membrane displays comparable fuel-cell performance to that of an NRE 212 membrane at 80°C under fully humidified condition, suggesting that the new membranes have the potential to be more durable but less expensive for fuel-cell applications.

  1. Compositions of corrosion-resistant Fe-based amorphous metals suitable for producing thermal spray coatings

    DOE Patents [OSTI]

    Farmer, Joseph C.; Wong, Frank M. G.; Haslam, Jeffery J.; Ji, Xiaoyan (Jane); Day, Sumner D.; Blue, Craig A.; Rivard, John D. K.; Aprigliano, Louis F.; Kohler, Leslie K.; Bayles, Robert; Lemieux, Edward J.; Yang, Nancy; Perepezko, John H.; Kaufman, Larry; Heuer, Arthur; Lavernia, Enrique J.

    2013-07-09T23:59:59.000Z

    A method of coating a surface comprising providing a source of amorphous metal that contains manganese (1 to 3 atomic %), yttrium (0.1 to 10 atomic %), and silicon (0.3 to 3.1 atomic %) in the range of composition given in parentheses; and that contains the following elements in the specified range of composition given in parentheses: chromium (15 to 20 atomic %), molybdenum (2 to 15 atomic %), tungsten (1 to 3 atomic %), boron (5 to 16 atomic %), carbon (3 to 16 atomic %), and the balance iron; and applying said amorphous metal to the surface by a spray.

  2. Compositions of corrosion-resistant Fe-based amorphous metals suitable for producing thermal spray coatings

    DOE Patents [OSTI]

    Farmer, Joseph C; Wong, Frank M.G.; Haslam, Jeffery J; Ji, Xiaoyan; Day, Sumner D; Blue, Craig A; Rivard, John D.K.; Aprigliano, Louis F; Kohler, Leslie K; Bayles, Robert; Lemieux, Edward J; Yang, Nancy; Perepezko, John H; Kaufman, Larry; Heuer, Arthur; Lavernia, Enrique J

    2013-09-03T23:59:59.000Z

    A method of coating a surface comprising providing a source of amorphous metal that contains manganese (1 to 3 atomic %), yttrium (0.1 to 10 atomic %), and silicon (0.3 to 3.1 atomic %) in the range of composition given in parentheses; and that contains the following elements in the specified range of composition given in parentheses: chromium (15 to 20 atomic %), molybdenum (2 to 15 atomic %), tungsten (1 to 3 atomic %), boron (5 to 16 atomic %), carbon (3 to 16 atomic %), and the balance iron; and applying said amorphous metal to the surface by a spray.

  3. Pervasive liquid metal based direct writing electronics with roller-ball pen

    SciTech Connect (OSTI)

    Zheng, Yi; Zhang, Qin [Beijing Key Lab of CryoBiomedical Eng. and Key Lab of Cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190 (China)] [Beijing Key Lab of CryoBiomedical Eng. and Key Lab of Cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190 (China); Liu, Jing, E-mail: jliu@mail.ipc.ac.cn [Beijing Key Lab of CryoBiomedical Eng. and Key Lab of Cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190 (China) [Beijing Key Lab of CryoBiomedical Eng. and Key Lab of Cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190 (China); Department of Biomedical Engineering, School of Medicine, Tsinghua University, Beijing 100084 (China)

    2013-11-15T23:59:59.000Z

    A roller-ball pen enabled direct writing electronics via room temperature liquid metal ink was proposed. With the rolling to print mechanism, the metallic inks were smoothly written on flexible polymer substrate to form conductive tracks and electronic devices. The contact angle analyzer and scanning electron microscope were implemented to disclose several unique inner properties of the obtained electronics. An ever high writing resolution with line width and thickness as 200 ?m and 80 ?m, respectively was realized. Further, with the administration of external writing pressure, GaIn{sub 24.5} droplets embody increasing wettability on polymer which demonstrates the pervasive adaptability of the roller-ball pen electronics.

  4. Ab initio correlation effects on the electronic and transport properties of metal(II)-phthalocyanine based devices

    E-Print Network [OSTI]

    Arrigo Calzolari; Andrea Ferretti; Marco Buongiorno Nardelli

    2007-05-30T23:59:59.000Z

    Using first principles calculations in the framework of Density Functional Theory, we investigated the electronic and transport properties of metal(II)-phthalocyanine (M(II)Pc) systems, both in a single molecule configuration and in a model-device geometry. In particular, using the Copper(II)- and Manganese(II)-Pc as prototypical examples, we studied how electronic correlations on the central metal-ion influence the analysis of the electronic structure of the system and we demonstrated that the choice of the exchange-correlation functional, also beyond the standard local or gradient corrected level, is of crucial importance for a correct interpretation of the data. Finally, our electronic transport simulations have shown that M(II)Pc-based devices can act selectively as molecular conductors, as in the case of Copper, or as spin valves, as in the case of Manganese, demonstrating once more the great potential of these systems for molecular nanoelectronics applications.

  5. Crystalline Metal-Organic Frameworks Based on Conformationally Flexible Phosphonic Acids

    E-Print Network [OSTI]

    Gagnon, Kevin James

    2013-07-19T23:59:59.000Z

    Alkylbisphosphonates ................................................ 4 Effects of External Stimuli on Metal Phosphonates........................................................ 6 CHAPTER II MATERIALS AND EXPERIMENTAL... for the system CoCl2?6H2O/IBMPA/[BdMIM] [BF4]. .......................................................................................................................... 23 Figure 2. Thermal ellipsoid plot of compound 1...

  6. Experimental and numerical analysis of metal leaching from fly ash-amended highway bases

    SciTech Connect (OSTI)

    Cetin, Bora [Department of Civil and Environmental Engineering, University of Maryland, College Park, MD 20742 (United States); Aydilek, Ahmet H., E-mail: aydilek@umd.edu [Department of Civil and Environmental Engineering, University of Maryland, College Park, MD 20742 (United States); Li, Lin [Department of Civil and Environmental Engineering, Jackson State University, Jackson, MS 17068 (United States)

    2012-05-15T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer This study is the evaluation of leaching potential of fly ash-lime mixed soils. Black-Right-Pointing-Pointer This objective is met with experimental and numerical analysis. Black-Right-Pointing-Pointer Zn leaching decreases with increase in fly ash content while Ba, B, Cu increases. Black-Right-Pointing-Pointer Decrease in lime content promoted leaching of Ba, B and Cu while Zn increases. Black-Right-Pointing-Pointer Numerical analysis predicted lower field metal concentrations. - Abstract: A study was conducted to evaluate the leaching potential of unpaved road materials (URM) mixed with lime activated high carbon fly ashes and to evaluate groundwater impacts of barium, boron, copper, and zinc leaching. This objective was met by a combination of batch water leach tests, column leach tests, and computer modeling. The laboratory tests were conducted on soil alone, fly ash alone, and URM-fly ash-lime kiln dust mixtures. The results indicated that an increase in fly ash and lime content has significant effects on leaching behavior of heavy metals from URM-fly ash mixture. An increase in fly ash content and a decrease in lime content promoted leaching of Ba, B and Cu whereas Zn leaching was primarily affected by the fly ash content. Numerically predicted field metal concentrations were significantly lower than the peak metal concentrations obtained in laboratory column leach tests, and field concentrations decreased with time and distance due to dispersion in soil vadose zone.

  7. Experimental and numerical analysis of metal leaching from fly ash-amended highway bases

    E-Print Network [OSTI]

    Aydilek, Ahmet

    December 2011 Available online xxxx Keywords: Coal combustion by products Fly ash Heavy metals Leaching road materials (URM) mixed with lime activated high carbon fly ashes and to evaluate groundwater is produced in the United States as a by-product of burning coal in electric power plants (ACAA, 2009

  8. Effect of process variables on the density and durability of the pellets made from high moisture corn stover

    SciTech Connect (OSTI)

    Jaya Shankar Tumuluru

    2014-03-01T23:59:59.000Z

    A flat die pellet mill was used to understand the effect of high levels of feedstock moisture content in the range of 28–38% (w.b.), with die rotational speeds of 40–60 Hz, and preheating temperatures of 30–110 °C on the pelleting characteristics of 4.8 mm screen size ground corn stover using an 8 mm pellet die. The physical properties of the pelletised biomass studied are: (a) pellet moisture content, (b) unit, bulk and tapped density, and (c) durability. Pelletisation experiments were conducted based on central composite design. Analysis of variance (ANOVA) indicated that feedstock moisture content influenced all of the physical properties at P < 0.001. Pellet moisture content decreased with increase in preheating temperature to about 110 °C and decreasing the feedstock moisture content to about 28% (w.b.). Response surface models developed for quality attributes with respect to process variables has adequately described the process with coefficient of determination (R2) values of >0.88. The other pellet quality attributes such as unit, bulk, tapped density, were maximised at feedstock moisture content of 30–33% (w.b.), die speeds of >50 Hz and preheating temperature of >90 °C. In case of durability a medium moisture content of 33–34% (w.b.) and preheating temperatures of >70 °C and higher die speeds >50 Hz resulted in high durable pellets. It can be concluded from the present study that feedstock moisture content, followed by preheating, and die rotational speed are the interacting process variables influencing pellet moisture content, unit, bulk and tapped density and durability.

  9. Impact of process conditions on the density and durability of wheat, oat, canola, and barley straw briquettes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tumuluru, J. S.; Tabil, L. G.; Song, Y.; Iroba, K. L.; Meda, V.

    2015-03-01T23:59:59.000Z

    The present study is to understand the impact of process conditions on the quality attributes of wheat oat, barley, and canola straw briquettes. Analysis of variance indicated that briquette moisture content and initial density immediately after compaction and final density after 2 weeks of storage are strong functions of feedstock moisture content and compression pressure, whereas durability rating is influenced by die temperature and feedstock moisture content. Briquettes produced at a low feedstock moisture content of 9 % (w.b.) yielded maximum densities >700 kg/m3 for wheat, oat, canola, and barley straws. Lower feedstock moisture content of more »higher die temperatures >110 °C and compression pressure >10 MPa minimized the briquette moisture content and maximized densities and durability rating based on surface plots observations. Optimal process conditions indicated that a low feedstock moisture content of about 9 % (w.b.), high die temperature of 120–130 °C, medium-to-large hammer mill screen sizes of about 24 to 31.75 mm, and low to high compression pressures of 7.5 to 12.5 MPa minimized briquette moisture content to 700 kg/m3. Durability rating >90 % is achievable at higher die temperatures of >123 °C, lower to medium feedstock moisture contents of 9 to 12 % (w.b.), low to high compression pressures of 7.5 to 12.5 MPa, and large hammer mill screen size of 31.75 mm, except for canola where a lower compression pressure of 7.5 to 8.5 MPa and a smaller hammer mill screen size of 19 mm for oat maximized the durability rating values.« less

  10. Impact of process conditions on the density and durability of wheat, oat, canola, and barley straw briquettes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tumuluru, J. S.; Tabil, L. G.; Song, Y.; Iroba, K. L.; Meda, V.

    2015-03-01T23:59:59.000Z

    The present study is to understand the impact of process conditions on the quality attributes of wheat oat, barley, and canola straw briquettes. Analysis of variance indicated that briquette moisture content and initial density immediately after compaction and final density after 2 weeks of storage are strong functions of feedstock moisture content and compression pressure, whereas durability rating is influenced by die temperature and feedstock moisture content. Briquettes produced at a low feedstock moisture content of 9 % (w.b.) yielded maximum densities >700 kg/m3 for wheat, oat, canola, and barley straws. Lower feedstock moisture content of 110 °C and compression pressure >10 MPa minimized the briquette moisture content and maximized densities and durability rating based on surface plots observations. Optimal process conditions indicated that a low feedstock moisture content of about 9 % (w.b.), high die temperature of 120–130 °C, medium-to-large hammer mill screen sizes of about 24 to 31.75 mm, and low to high compression pressures of 7.5 to 12.5 MPa minimized briquette moisture content to 700 kg/m3. Durability rating >90 % is achievable at higher die temperatures of >123 °C, lower to medium feedstock moisture contents of 9 to 12 % (w.b.), low to high compression pressures of 7.5 to 12.5 MPa, and large hammer mill screen size of 31.75 mm, except for canola where a lower compression pressure of 7.5 to 8.5 MPa and a smaller hammer mill screen size of 19 mm for oat maximized the durability rating values.

  11. Durability of Poly (Methyl Methacrylate) Lenses Used in Concentrating Photovoltaics (Presentation)

    SciTech Connect (OSTI)

    Miller, D.; Gedvilas, L.; To, B.; Kennedy, C.; Kurtz, S.

    2010-10-21T23:59:59.000Z

    This presentation reports the findings of NREL's screen test to characterize the durability of poly (methyl methacrylate) lenses used in concentrated photovoltaics.

  12. Rapid Relaxation and Embrittlement of Zr-based Bulk Metallic Glasses by Electropulsing

    SciTech Connect (OSTI)

    Yiu, P [Department of Materials Science and Engineering, National Taiwan University, Taipei 106, Taiwan; Chen, Y. C. [National Taiwan University of Science & Technology; Chu, J. P. [National Taiwan Ocean University; Chang, S Y [National Chung Hsing University; Bei, Hongbin [ORNL; Jang, J. S.C. [National Central University, Jhongli 32001, Taiwan; Hsueh, C. H. [Department of Materials Science and Engineering, National Taiwan University, Taipei 106, Taiwan

    2013-01-01T23:59:59.000Z

    Mechanical relaxation and embrittlement of Zr52.5Cu17.9Ni14.6Al10Ti5 bulk metallic glasses were achieved rapidly by the direct current electropulsing treatment. The temperature profile was recorded by an infrared camera and it was found to be non-uniform in the treated specimen. Specifically, temperatures below the glass transition temperature, near and above the crystallization temperature could be ach- ieved, respectively, at different locations in the same treated specimen. Two sets of nanoindentation were conducted. While the first set investigated the mechanical properties of three individually elec- tropulsed specimens with different conditions, the second set indented a single treated specimen along its temperature gradient. Both sets of indentation revealed that by Joule heating to different tempera- tures, relaxation, embrittlement, and crystallization were significantly accelerated by electrical pulses. Results suggest that electropulsing provides an opportunity to simultaneously achieve plastic forming and mechanical property control of metallic glasses.

  13. Durable innovative solar optical materials: the international challenge

    SciTech Connect (OSTI)

    Lampert, C.M.

    1982-01-01T23:59:59.000Z

    A variety of optical coatings are discussed in the context of solar energy utilization. Well known coatings such as heat mirrors, selective absorbers, and reflective films are covered briefly. Emphasis is placed on the materials limitations and design choices for various lesser known optical coatings and materials. Physical and optical properties are detailed for protective antireflection films, fluorescent concentrator materials, holographic films, cold mirrors, radiative cooling surfaces, and optical switching films including electrochromic, thermochromic, photochromic, and liquid crystal types. For many of these materials research is only now being considered, and various design and durability issues must be addressed.

  14. PEM Fuel Cell Freeze Durability and Cold Start Project

    SciTech Connect (OSTI)

    Patterson, T.; O'Neill, Jonathan

    2008-01-02T23:59:59.000Z

    UTC has taken advantage of the unique water management opportunities inherent in micro-porous bipolar-plates to improve the cold-start performance of its polymer electrolyte fuel cells (PEFC). Diagnostic experiments were used to determine the limiting factors in micro-porous plate PEFC freeze performance and the causes of any performance decay. Alternative cell materials were evaluated for their freeze performance. Freeze-thaw cycling was also performed to determine micro-porous plate PEFC survivability. Data from these experiments has formed the basis for continuing development of advanced materials capable of supporting DOE's cold-start and durability objectives.

  15. Water-thinnable polymers for durable coatings for different materials

    SciTech Connect (OSTI)

    Jankowski, Piotr, E-mail: piotr.jankowski@ichp.pl; Kijowska, Dorota, E-mail: piotr.jankowski@ichp.pl [Industrial Chemistry Research Institute, Department of Polyesters, Epoxides and Polyurethanes, 8 Rydygiera Str., 01-793 Warszawa (Poland)

    2014-05-15T23:59:59.000Z

    The methods of obtaining water-thinnable polymers - water-thinnable unsaturated polyester resins (WTUPR) - by polycondensation were elaborate and optimized. As hydrophilic monomers different types of sulfonate monomers were used. The monomers, with sulfonate groups and other reactive groups, were obtained by sulfonation of organic compounds with satisfactory yield. All products were analyzed by {sup 1}H NMR and {sup 13}C NMR spectra. WTUPR were used as polymeric binders for coatings applications. Coatings with relatively high pendulum hardness, good properties and durability, useful for practical applications, were obtained. Typical existing equipment for the production of unsaturated polyester resins can be applied for the industrial preparation of WTUPR.

  16. Durable silver thin film coating for diffraction gratings

    DOE Patents [OSTI]

    Wolfe, Jesse D. (Discovery Bay, CA); Britten, Jerald A. (Oakley, CA); Komashko, Aleksey M. (San Diego, CA)

    2006-05-30T23:59:59.000Z

    A durable silver film thin film coated non-planar optical element has been developed to replace Gold as a material for fabricating such devices. Such a coating and resultant optical element has an increased efficiency and is resistant to tarnishing, can be easily stripped and re-deposited without modifying underlying grating structure, improves the throughput and power loading of short pulse compressor designs for ultra-fast laser systems, and can be utilized in variety of optical and spectrophotometric systems, particularly high-end spectrometers that require maximized efficiency.

  17. Durability of Polymeric Encapsulation Materials for Concentrating Photovoltaic Systems (Poster)

    SciTech Connect (OSTI)

    Miller, D. C.; Kempe, M. D.; Araki, K.; Kennedy, C. E.; Kurtz, S. R.

    2011-02-01T23:59:59.000Z

    Polymeric encapsulation materials are typically used in concentrating photovoltaic (CPV) modules to protect the cell from the field environment. Because it is physically located adjacent to the cell, the encapsulation is exposed to a high optical flux, often including light in the ultraviolet (UV) and infrared (IR) wavelengths. The durability of encapsulants used in CPV modules is critical to the technology, but is presently not well understood. This work seeks to identify the appropriate material types, field-induced failure mechanisms, and factors of influence (if possible) of polymeric encapsulation. These results will ultimately be weighed against those of future qualification and accelerated life test procedures.

  18. Durability of Polymeric Encapsulation Materials for Concentrating Photovoltaic Systems (Presentation)

    SciTech Connect (OSTI)

    Miller, D. C.; Muller, M.; Kempe, M. D.; Araki, K.; Kennedy, C. E.; Kurtz, S. R.

    2011-04-01T23:59:59.000Z

    Presented at the 7th International Conference on Concentrating Photovoltaic Systems (CPV-7), 4-6 April 2011, Las Vegas, Nevada. Many concentrating photovoltaic (CPV) systems use a polymeric encapsulant to couple an optical component and/or coverglass to the cell. In that location, the encapsulation improves the transmission of concentrated optical flux through interfaces(s) while protecting the cell from the environment. The durability of encapsulation materials, however, is not well established relative to the desired service life of 30 years. Therefore, we have initiated a screen test to identify the field-induced failure modes for a variety of popular PV encapsulation materials.

  19. Durable, Low Cost, Improved Fuel Cell Membranes | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny:Revised Finding of No53197E TDrew Bittner About UsDurable, Low Cost, Improved Fuel

  20. Durable Fuel Cell Membrane Electrode Assembly (MEA) - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power AdministrationField Campaign:INEA :Work with Jefferson Lab | JeffersonDurable Fuel

  1. Reconfigurable liquid metal based terahertz metamaterials via selective erasure and refilling to the unit cell level

    SciTech Connect (OSTI)

    Wang, Jinqi; Liu, Shuchang; Nahata, Ajay, E-mail: ajay.nahata@utah.edu [Department of Electrical and Computer Engineering, University of Utah, Salt Lake City, Utah 84112 (United States)] [Department of Electrical and Computer Engineering, University of Utah, Salt Lake City, Utah 84112 (United States); Guruswamy, Sivaraman [Department of Metallurgical Engineering, University of Utah, Salt Lake City, Utah 84112 (United States)] [Department of Metallurgical Engineering, University of Utah, Salt Lake City, Utah 84112 (United States)

    2013-11-25T23:59:59.000Z

    We demonstrate a technique for selectively erasing and refilling unit cells of terahertz (THz) metamaterials. The structures are formed by injecting eutectic gallium indium (EGaIn), a liquid metal at room temperature, into microchannels within a polydimethylsiloxane (PDMS) mold fabricated using conventional soft lithography techniques. The thin oxide layer that forms on the surface of EGaIn can be locally dissolved via exposure to hydrochloric acid (HCl) introduced at the surface of the gas permeable PDMS mold. In the absence of the oxide skin, the liquid metal retracts to a position where a stable new oxide layer can be formed, effectively erasing the liquid metal structure in the presence of HCl. After erasing selected structures, EGaIn can be re-injected into microchannels to yield the initial structure. In the case of small unit cells, we show that mechanical pressure can be used to effectively erase individual elements. We use THz time-domain spectroscopy to characterize the distinct transmission properties for each of these different structures.

  2. An overview of the Noncyanide Metal Stripper program conducted at Kelly Air Force Base

    SciTech Connect (OSTI)

    Argyle, M.D.; Cowan, R.L.

    1995-01-01T23:59:59.000Z

    The Noncyanide Metal Stripper Program was a waste minimization effort aimed at identifying and testing suitable noncyanide stripping solutions that could replace the cyanide stripping solutions found in the United States Air Force (USAF) Air Logistics Centers (ALC). The program started with laboratory testing of commercial stripping solutions. The performance of these solutions was compared with the cyanide process solutions C-101 and C-106 targeted for replacement. Plate metal stripping rate, basis metal corrosion, and compatibility with masking materials and biodegradability were all used to determine the performance of each product. Those products that passed the acceptance criteria were field tested using 25 to 50-gallon solutions to determine optimum operating conditions, stripper maintenance requirements, and maximum solution loading and longevity. The program included investigating any adverse effects these new products might have on existing chemical and biological waste treatment processes. All cyanide stripping solutions at the San Antonio Air Logistics Command Center have been successfully replaced with commercial noncyanide products. Generally, these replacements were less toxic and generated less waste and had longer lifetimes than their cyanide counterparts.

  3. Determination of welding fume size with time using E7018 electrodes and A131B base metal

    E-Print Network [OSTI]

    Owen, Richard James

    1976-01-01T23:59:59.000Z

    . 81 0. 14 0. 70 0. 06 0. 64 0. 25 0. 42 0. 83 mglottie velocity 150. Thermal agglomeration is enhanced by the turbulent conditions from the heat generated by the welding process. Not only are the fumes themselves hot, but the air in which...DETERMINATION OF WELDING FUME SIZE WITH TIME USING E7018 ELECTRODES AND A131B BASE METAL A Thesis by RICHARD JAMES OWEN Submitted to the Graduate College of Texas AILM University in partial fulfillment of the requirement for the degree...

  4. Final Report of a CRADA Between Pacific Northwest National Laboratory and the Ford Motor Company (CRADA No. PNNL/265): “Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials, and Development of Zeolite-Based Hydrocarbon Adsorber Materials”

    SciTech Connect (OSTI)

    Gao, Feng; Kwak, Ja Hun; Lee, Jong H.; Tran, Diana N.; Peden, Charles HF; Howden, Ken; Cheng, Yisun; Lupescu, Jason; Cavattaio, Giovanni; Lambert, Christine; McCabe, Robert W.

    2013-02-14T23:59:59.000Z

    Reducing NOx emissions and particulate matter (PM) are primary concerns for diesel vehicles required to meet current LEV II and future LEV III emission standards which require 90+% NOx conversion. Currently, urea SCR as the NOx reductant and a Catalyzed Diesel Particulate Filter (CDPF) are being used for emission control system components by Ford Motor Company for 2010 and beyond diesel vehicles. Because the use of this technology for vehicle applications is new, the relative lack of experience makes it especially challenging to satisfy durability requirements. Of particular concern is being able to realistically simulate actual field aging of the catalyst systems under laboratory conditions. This is necessary both as a rapid assessment tool for verifying improved performance and certifiability of new catalyst formulations, and to develop a good understanding of deactivation mechanisms that can be used to develop improved catalyst materials. In addition to NOx and PM, the hydrocarbon (HC) emission standards are expected to become much more stringent during the next few years. Meanwhile, the engine-out HC emissions are expected to increase and/or be more difficult to remove. Since HC can be removed only when the catalyst becomes warm enough for its oxidation, three-way catalyst (TWC) and diesel oxidation catalyst (DOC) formulations often contain proprietary zeolite materials to hold the HC produced during the cold start period until the catalyst reaches its operating temperature (e.g., >200°C). Unfortunately, much of trapped HC tends to be released before the catalyst reaches the operating temperature. Among materials effective for trapping HC during the catalyst warm-up period, siliceous zeolites are commonly used because of their high surface area and high stability under typical operating conditions. However, there has been little research on the physical properties of these materials related to the adsorption and release of various hydrocarbon species found in the engine exhaust. For these reasons, automakers and engine manufacturers have difficulty improving their catalytic converters for meeting the stringent HC emission standards. In this collaborative program, scientists and engineers in the Institute for Integrated Catalysis at Pacific Northwest National Laboratory and at Ford Motor Company have investigated laboratory- and engine-aged SCR catalysts, containing mainly base metal zeolites. These studies are leading to a better understanding of various aging factors that impact the long-term performance of SCR catalysts and improve the correlation between laboratory and engine aging, saving experimental time and cost. We have also studied materials effective for the temporary storage of HC species during the cold-start period. In particular, we have examined the adsorption and desorption of various HC species produced during the combustion with different fuels (e.g., gasoline, E85, diesel) over potential HC adsorber materials, and measured the kinetic parameters to update Ford’s HC adsorption model. Since this CRADA has now been completed, in this final report we will provide brief summaries of most of the work carried out on this CRADA over the last several years.

  5. Effects of extreme pressure additive chemistry on rolling element bearing surface durability

    SciTech Connect (OSTI)

    Evans, Ryan D. [Timken Company; Nixon, H. P. [Timken Company; Darragh, Craig V. [Timken Company; Howe, Jane Y [ORNL; Coffey, Dorothy W [ORNL

    2007-01-01T23:59:59.000Z

    Lubricant additives have been known to affect rolling element bearing surface durability for many years. Tapered roller bearings were used in fatigue testing of lubricants formulated with gear oil type additive systems. These systems have sulfur- and phosphoruscontaining compounds used for gear protection as well as bearing lubrication. Several variations of a commercially available base additive formulation were tested having modified sulfur components. The variations represent a range of ''active'' extreme pressure (EP) chemistries. The bearing fatigue test results were compared with respect to EP formulation and test conditions. Inner ring near-surface material in selected test bearings was evaluated on two scales: the micrometer scale using optical metallography and the nanometer scale using transmission electron microscopy (TEM). Focused-ion beam (FIB) techniques were used for TEM specimen preparation. Imaging and chemical analysis of the bearing samples revealed near-surface material and tribofilm characteristics. These results are discussed with respect to the relative fatigue lives.

  6. Principles of passive and active cooling of mirror-based hybrid systems employing liquid metals

    SciTech Connect (OSTI)

    Anglart, Henryk [Div. of Nuclear Technology, School of Engineering Sciences, Royal Institute of Technology Roslagstullsbacken 21, 106-91 Stockholm (Sweden)

    2012-06-19T23:59:59.000Z

    This paper presents principles of passive and active cooling that are suitable to mirrorbased hybrid, nuclear fission/fusion systems. It is shown that liquid metal lead-bismuth cooling of the mirror machine with 25 m height and 1.5 GW thermal power is feasible both in the active mode during the normal operation and in the passive mode after the reactor shutdown. In the active mode the achievable required pumping power can well be below 50 MW, whereas the passive mode provides enough coolant flow to keep the clad temperature below the damage limits.

  7. Metal-Based, High-Capacity Lithium-Ion Anodes | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(FactDepartment3311, 3312), OctoberMayEnergy Metal Organic Heat

  8. Final Report - MEA and Stack Durability for PEM Fuel Cells

    SciTech Connect (OSTI)

    Yandrasits, Michael A.

    2008-02-15T23:59:59.000Z

    Proton exchange membrane fuel cells are expected to change the landscape of power generation over the next ten years. For this to be realized one of the most significant challenges to be met for stationary systems is lifetime, where 40,000 hours of operation with less than 10% decay is desired. This project conducted fundamental studies on the durability of membrane electrode assemblies (MEAs) and fuel cell stack systems with the expectation that knowledge gained from this project will be applied toward the design and manufacture of MEAs and stack systems to meet DOE’s 2010 stationary fuel cell stack systems targets. The focus of this project was PEM fuel cell durability – understanding the issues that limit MEA and fuel cell system lifetime, developing mitigation strategies to address the lifetime issues and demonstration of the effectiveness of the mitigation strategies by system testing. To that end, several discoveries were made that contributed to the fundamental understanding of MEA degradation mechanisms. (1) The classically held belief that membrane degradation is solely due to end-group “unzipping” is incorrect; there are other functional groups present in the ionomer that are susceptible to chemical attack. (2) The rate of membrane degradation can be greatly slowed or possibly eliminated through the use of additives that scavenge peroxide or peroxyl radicals. (3) Characterization of GDL using dry gases is incorrect due to the fact that fuel cells operate utilizing humidified gases. The proper characterization method involves using wet gas streams and measuring capillary pressure as demonstrated in this project. (4) Not all Platinum on carbon catalysts are created equally – the major factor impacting catalyst durability is the type of carbon used as the support. (5) System operating conditions have a significant impact of lifetime – the lifetime was increased by an order of magnitude by changing the load profile while all other variables remain the same. (6) Through the use of statistical lifetime analysis methods, it is possible to develop new MEAs with predicted durability approaching the DOE 2010 targets. (7) A segmented cell was developed that extend the resolution from ~ 40 to 121 segments for a 50cm2 active area single cell which allowed for more precise investigation of the local phenomena in a operating fuel cell. (8) The single cell concept was extended to a fuel size stack to allow the first of its kind monitoring and mapping of an operational fuel cell stack. An internal check used during this project involved evaluating the manufacturability of any new MEA component. If a more durable MEA component was developed in the lab, but could not be scaled-up to ‘high speed, high volume manufacturing’, then that component was not selected for the final MEA-fuel cell system demonstration. It is the intent of the team to commercialize new products developed under this project, but commercialization can not occur if the manufacture of said new components is difficult or if the price is significantly greater than existing products as to make the new components not cost competitive. Thus, the end result of this project is the creation of MEA and fuel cell system technology that is capable of meeting the DOEs 2010 target of 40,000 hours for stationary fuel cell systems (although this lifetime has not been demonstrated in laboratory or field testing yet) at a cost that is economically viable for the developing fuel cell industry. We have demonstrated over 2,000 hours of run time for the MEA and system developed under this project.

  9. Comparison of Crevice Corrosion of Fe-Based Amorphous Metal and Crystalline Ni-Cr-Mo Alloy

    SciTech Connect (OSTI)

    Shan, X; Ha, H; Payer, J H

    2008-07-24T23:59:59.000Z

    The crevice corrosion behaviors of an Fe-based bulk metallic glass alloy (SAM1651) and a Ni-Cr-Mo crystalline alloy (C-22) were studied in 4M NaCl at 100 C with cyclic potentiodynamic polarization and constant potential tests. The corrosion damage morphologies, corrosion products and the compositions of corroded surfaces of these two alloys were studied with optical 3D reconstruction, Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS) and Auger Electron Spectroscopy (AES). It was found that the Fe-based bulk metallic glass (amorphous alloy) SAM1651 had a more positive breakdown potential and repassivation potential than crystalline alloy C-22 in cyclic potentiodynamic polarization tests and required a more positive oxidizing potential to initiate crevice corrosion in constant potential test. Once crevice corrosion initiated, the corrosion propagation of C-22 was more localized near the crevice border compared to SAM1651, and SAM1651 repassivated more readily than C-22. The EDS results indicated that the corrosion products of both alloys contained high amount of O and were enriched in Mo and Cr. The AES results indicated that a Cr-rich oxide passive film was formed on the surfaces of both alloys, and both alloys were corroded congruently.

  10. Plain Talk About Condensation and Radiation Below Metal Roof Assemblies

    E-Print Network [OSTI]

    Ward, L.

    . Unfortunately, some of these advantages may give rise to certain disadvantages in comfort, durability and operating costs (7) This paper provides a brief historical overview of common metal roof insulation methods as well as recent innovations for low cost... assemblies. INTRODUCTION A primary objective of this paper is to try and simplify the complex subject of condensation in metal roof assemblies. A secondary objective is to focus on condensation considerations with reflective insulation systems (as...

  11. E-Area Vault Concrete Material Property And Vault Durability/Degradation Projection Recommendations

    SciTech Connect (OSTI)

    Phifer, M. A.

    2014-03-11T23:59:59.000Z

    Subsequent to the 2008 E-Area Low-Level Waste Facility (ELLWF) Performance Assessment (PA) (WSRC 2008), two additional E-Area vault concrete property testing programs have been conducted (Dixon and Phifer 2010 and SIMCO 2011a) and two additional E-Area vault concrete durability modeling projections have been made (Langton 2009 and SIMCO 2012). All the information/data from these reports has been evaluated and consolidated herein by the Savannah River National Laboratory (SRNL) at the request of Solid Waste Management (SWM) to produce E-Area vault concrete hydraulic and physical property data and vault durability/degradation projection recommendations that are adequately justified for use within associated Special Analyses (SAs) and future PA updates. The Low Activity Waste (LAW) and Intermediate Level (IL) Vaults structural degradation predictions produced by Carey 2006 and Peregoy 2006, respectively, which were used as the basis for the 2008 ELLWF PA, remain valid based upon the results of the E-Area vault concrete durability simulations reported by Langton 2009 and those reported by SIMCO 2012. Therefore revised structural degradation predictions are not required so long as the mean thickness of the closure cap overlying the vaults is no greater than that assumed within Carey 2006 and Peregoy 2006. For the LAW Vault structural degradation prediction (Carey 2006), the mean thickness of the overlying closure cap was taken as nine feet. For the IL Vault structural degradation prediction (Peregoy 2006), the mean thickness of the overlying closure cap was taken as eight feet. The mean closure cap thicknesses as described here for both E-Area Vaults will be included as a key input and assumption (I&A) in the next revision to the closure plan for the ELLWF (Phifer et al. 2009). In addition, it has been identified as new input to the PA model to be assessed in the ongoing update to the new PA Information UDQE (Flach 2013). Once the UDQE is approved, the SWM Key I&A database will be updated with this new information.

  12. First principles study of Fe in diamond: A diamond-based half metallic dilute magnetic semiconductor

    SciTech Connect (OSTI)

    Benecha, E. M. [Department of Physics, University of South Africa, P.O. Box 392, UNISA 0003 Pretoria (South Africa); Lombardi, E. B., E-mail: lombaeb@unisa.ac.za [College of Graduate Studies, University of South Africa, P.O. Box 392, UNISA 0003 Pretoria (South Africa)

    2013-12-14T23:59:59.000Z

    Half-metallic ferromagnetic ordering in semiconductors, essential in the emerging field of spintronics for injection and transport of highly spin polarised currents, has up to now been considered mainly in III–V and II–VI materials. However, low Curie temperatures have limited implementation in room temperature device applications. We report ab initio Density Functional Theory calculations on the properties of Fe in diamond, considering the effects of lattice site, charge state, and Fermi level position. We show that the lattice sites and induced magnetic moments of Fe in diamond depend strongly on the Fermi level position and type of diamond co-doping, with Fe being energetically most favorable at the substitutional site in p-type and intrinsic diamond, while it is most stable at a divacancy site in n-type diamond. Fe induces spin polarized bands in the band gap, with strong hybridization between Fe-3d and C-2s,2p bands. We further consider Fe-Fe spin interactions in diamond and show that substitutional Fe{sup +1} in p-type diamond exhibits a half-metallic character, with a magnetic moment of 1.0??{sub B} per Fe atom and a large ferromagnetic stabilization energy of 33?meV, an order of magnitude larger than in other semiconductors, with correspondingly high Curie temperatures. These results, combined with diamond's unique properties, demonstrate that Fe doped p-type diamond is likely to be a highly suitable candidate material for spintronics applications.

  13. Durability is one of the most critical remaining issues impeding successful commercialization of broad

    E-Print Network [OSTI]

    fuel cells have the potential to replace the vehicle's internal combustion engine. Specifically is the current focus for light-duty vehicles. The durability of fuel cell sys- tems, however, has not been of broad PEM fuel cell stationary and transportation energy applications, and the durability of fuel cell

  14. LA CERTIFICATION FORESTIERE COMME NORME DE GESTION DURABLE DES FORETS TROPICALES : UNE LABORIEUSE APPLICATION EN AFRIQUE

    E-Print Network [OSTI]

    Boyer, Edmond

    LA CERTIFICATION FORESTIERE COMME NORME DE GESTION DURABLE DES FORETS TROPICALES : UNE LABORIEUSE sous l'effet de pressions du marché européen que par souci écologique de gestion durable des forêts nombreuses Organisations Non Gouvernementales Internationales (ONGI) basées dans les pays du Nord et militant

  15. Effect of Electric Arc Furnace Bag House Dust on Concrete Durability Researcher: Fahad Al-Mutlaq

    E-Print Network [OSTI]

    Birmingham, University of

    Effect of Electric Arc Furnace Bag House Dust on Concrete Durability Researcher: Fahad Al billions of dollars annually. While steel is normally protected from corrosion in concrete by a passive of the effects of addition of Bag House Dust (BHD) on aspects of concrete durability. BHD is a fine powder

  16. Analysis of the Durability of PEM FC Membrane Electrode Assemblies in Automotive Applications

    E-Print Network [OSTI]

    g y Analysis of the Durability of PEM FC Membrane Electrode Assemblies in Automotive Applications materials degradation mechanisms under automotive conditions that can lead to recommendations for mitigation, to better understand the durability at low relative humidity and during automotive cycling operation

  17. Various sizes of sliding event bursts in the plastic flow of metallic glasses based on a spatiotemporal dynamic model

    SciTech Connect (OSTI)

    Ren, Jingli, E-mail: renjl@zzu.edu.cn, E-mail: g.wang@shu.edu.cn; Chen, Cun [School of Mathematics and Statistics, Zhengzhou University, Zhengzhou 450001 (China); Wang, Gang, E-mail: renjl@zzu.edu.cn, E-mail: g.wang@shu.edu.cn [Laboratory for Microstructures, Shanghai University, Shanghai 200444 (China); Cheung, Wing-Sum [Department of Mathematics, The University of HongKong, HongKong (China); Sun, Baoan; Mattern, Norbert [IFW-dresden, Institute for Complex Materials, P.O. Box 27 01 16, D-01171 Dresden (Germany); Siegmund, Stefan [Department of Mathematics, TU Dresden, D-01062 Dresden (Germany); Eckert, Jürgen [IFW-dresden, Institute for Complex Materials, P.O. Box 27 01 16, D-01171 Dresden (Germany); Institute of Materials Science, TU Dresden, D-01062 Dresden (Germany)

    2014-07-21T23:59:59.000Z

    This paper presents a spatiotemporal dynamic model based on the interaction between multiple shear bands in the plastic flow of metallic glasses during compressive deformation. Various sizes of sliding events burst in the plastic deformation as the generation of different scales of shear branches occurred; microscopic creep events and delocalized sliding events were analyzed based on the established model. This paper discusses the spatially uniform solutions and traveling wave solution. The phase space of the spatially uniform system applied in this study reflected the chaotic state of the system at a lower strain rate. Moreover, numerical simulation showed that the microscopic creep events were manifested at a lower strain rate, whereas the delocalized sliding events were manifested at a higher strain rate.

  18. Impact of Biodiesel Impurities on the Performance and Durability of DOC, DPF and SCR Technologies: Preprint

    SciTech Connect (OSTI)

    Williams, A.; McCormick, R.; Luecke, J.; Brezny, R.; Geisselmann, A.; Voss, K.; Hallstrom, K.; Leustek, M.; Parsons, J.; Abi-Akar, H.

    2011-04-01T23:59:59.000Z

    An accelerated durability test method determined the potential impact of biodiesel ash impurities, including engine testing with multiple diesel particulate filter substrate types, as well as diesel oxidation catalyst and selective catalyst reduction catalysts. The results showed no significant degradation in the thermo-mechanical properties of a DPF after exposure to 150,000-mile equivalent biodiesel ash and thermal aging. However, exposure to 435,000-mile equivalent aging resulted in a 69% decrease in thermal shock resistance. A decrease in DOC activity was seen after exposure to 150,000-mile equivalent aging, resulting in higher hydrocarbon slip and a reduction in NO2 formation. The SCR catalyst experienced a slight loss in activity after exposure to 435,000-mile equivalent aging. The SCR catalyst, placed downstream of the DPF and exposed to B20 exhaust suffered a 5% reduction in overall NOx conversion activity over the HDDT test cycle. It is estimated that the additional ash from 150,000 miles of biodiesel use would also result in a moderate increases in exhaust backpressure for a DPF. The results of this study suggest that long-term operation with B20 at the current specification limits for alkali and alkaline earth metal impurities will adversely impact the performance of DOC, DPF and SCR systems.

  19. Durability of Low Platinum Fuel Cells Operating at High Power Density

    SciTech Connect (OSTI)

    Polevaya, Olga [Nuvera Fuel Cells Inc.] [Nuvera Fuel Cells Inc.; Blanchet, Scott [Nuvera Fuel Cells Inc.] [Nuvera Fuel Cells Inc.; Ahluwalia, Rajesh [Argonne National Lab] [Argonne National Lab; Borup, Rod [Los-Alamos National Lab] [Los-Alamos National Lab; Mukundan, Rangachary [Los-Alamos National Lab] [Los-Alamos National Lab

    2014-03-19T23:59:59.000Z

    Understanding and improving the durability of cost-competitive fuel cell stacks is imperative to successful deployment of the technology. Stacks will need to operate well beyond today’s state-of-the-art rated power density with very low platinum loading in order to achieve the cost targets set forth by DOE ($15/kW) and ultimately be competitive with incumbent technologies. An accelerated cost-reduction path presented by Nuvera focused on substantially increasing power density to address non-PGM material costs as well as platinum. The study developed a practical understanding of the degradation mechanisms impacting durability of fuel cells with low platinum loading (?0.2mg/cm2) operating at high power density (?1.0W/cm2) and worked out approaches for improving the durability of low-loaded, high-power stack designs. Of specific interest is the impact of combining low platinum loading with high power density operation, as this offers the best chance of achieving long-term cost targets. A design-of-experiments approach was utilized to reveal and quantify the sensitivity of durability-critical material properties to high current density at two levels of platinum loading (the more conventional 0.45 mgPt.cm–1 and the much lower 0.2 mgPt.cm–2) across several cell architectures. We studied the relevance of selected component accelerated stress tests (AST) to fuel cell operation in power producing mode. New stress tests (NST) were designed to investigate the sensitivity to the addition of electrical current on the ASTs, along with combined humidity and load cycles and, eventually, relate to the combined city/highway drive cycle. Changes in the cathode electrochemical surface area (ECSA) and average oxygen partial pressure on the catalyst layer with aging under AST and NST protocols were compared based on the number of completed cycles. Studies showed elevated sensitivity of Pt growth to the potential limits and the initial particle size distribution. The ECSA loss was correlated with the upper potential limit in the cycle tests, although the performance degradation was found to be a strong function of initial Pt loading. A large fraction of the voltage degradation was found due to increased mass transfer overpotentials, especially in the lower Pt loading cells. Increased mass transfer overpotentials were responsible for a large fraction of the voltage degradation at high current densities. Analysis of the impedance and polarization data indicated O2 diffusion in the aged electrode ionomer to be the main source of the increased mass transfer overpotentials. Results from the experimental parametric studies were used to inform and calibrate newly developed durability model, simulating lifetime performance of the fuel cell under variety of load-cycle protocols, electrode loadings and throughout wide range of operating conditions, including elevated-to-3.0A/cm2 current densities. Complete durability model included several sub-models: platinum dissolution-and-growth as well as reaction-diffusion model of cathode electrode, applied sequentially to study the lifetime predictions of ECSA and polarization performance in the ASTs and NSTs. These models establish relations between changes in overpotentials, ECSA and oxygen mass transport in fuel cell cathodes. The model was calibrated using single cells with land-channel and open flowfield architectures. The model was validated against Nuvera Orion® (open flowfield) short stack data in the load cycle durability tests. The reaction-diffusion model was used to correlate the effective mass transfer coefficients for O2 diffusion in cathode ionomer and separately in gas pores with the operating conditions (pressure, temperature, gas velocity in flow field and current density), Pt loading, and ageing related growth in Pt particles and thinning of the electrode. Achievements of both modeling and experimental objectives were demonstrated in a full format, subscale stacks operating in a simulated but fully realistic ambient environment, using system-compatible operating protocols.

  20. Preparation of metallic cation conducting polymers based on sterically hindered phenols containing polymeric systems

    DOE Patents [OSTI]

    Skotheim, Terje A. (Shoreham, NY); Okamoto, Yoshiyuki (Fort Lee, NJ); Lee, Hung S. (Woodside, NY)

    1989-01-01T23:59:59.000Z

    The present invention relates to ion-conducting solvent-free polymeric systems characterized as being cationic single ion conductors. The solvent-free polymer electrolytes comprise a flexible polymer backbone to which is attached a metal salt, such as a lithium, sodium or potassium salt, of a sterically hindered phenol. The solid polymer electrolyte may be prepared either by (1) attaching the hindered phenol directly to a flexible polymeric backbone, followed by neutralization of the phenolic OH's or (2) reacting the hindered phenol with a polymer precursor which is then polymerized to form a flexible polymer having phenolic OH's which are subsequently neutralized. Preferably the hindered phenol-modified polymeric backbone contains a polyether segment. The ionic conductivity of these solvent-free polymer electrolytes has been measured to be in the range of 10.sup.-4 to 10.sup.-7 S cm.sup.-1 at room temperature.

  1. Preparation of metallic cation conducting polymers based on sterically hindered phenols containing polymeric systems

    DOE Patents [OSTI]

    Skotheim, T.A.; Okamoto, Yoshiyuki; Lee, H.S.

    1989-11-21T23:59:59.000Z

    The present invention relates to ion-conducting solvent-free polymeric systems characterized as being cationic single ion conductors. The solvent-free polymer electrolytes comprise a flexible polymer backbone to which is attached a metal salt, such as a lithium, sodium or potassium salt, of a sterically hindered phenol. The solid polymer electrolyte may be prepared either by (1) attaching the hindered phenol directly to a flexible polymeric backbone, followed by neutralization of the phenolic OH's or (2) reacting the hindered phenol with a polymer precursor which is then polymerized to form a flexible polymer having phenolic OH's which are subsequently neutralized. Preferably the hindered phenol-modified polymeric backbone contains a polyether segment. The ionic conductivity of these solvent-free polymer electrolytes has been measured to be in the range of 10[sup [minus]4] to 10[sup [minus]7] S cm[sup [minus]1] at room temperature.

  2. Serrated flow behaviors of a Zr-based bulk metallic glass by nanoindentation

    SciTech Connect (OSTI)

    Cheng, L.; Jiao, Z. M.; Ma, S. G.; Wang, Z. H., E-mail: qiaojunwei@gmail.com, E-mail: wangzhihua@tyut.edu.cn [Institute of Applied Mechanics and Biomedical Engineering, Taiyuan University of Technology, Taiyuan 030024 (China); Qiao, J. W., E-mail: qiaojunwei@gmail.com, E-mail: wangzhihua@tyut.edu.cn [Institute of Applied Mechanics and Biomedical Engineering, Taiyuan University of Technology, Taiyuan 030024 (China); Laboratory of Applied Physics and Mechanics of Advanced Materials, College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024 (China)

    2014-02-28T23:59:59.000Z

    Instrumented nanoindentation tests were used to investigate the mechanical properties of Zr{sub 52.5}Cu{sub 17.9}Ni{sub 14.6}Al{sub 10}Ti{sub 5} bulk metallic glass. The corresponding loading strain rates were ranged from 0.002?s{sup ?1}, 0.02?s{sup ?1} to 0.2?s{sup ?1}. Plastic flow of this material exhibited remarkable serrations at low strain rates and increasingly became weakening until disappearance with increasing indentation strain rate, implying strong rate sensitivity. A significant pile-up around the indents was observed through atomic force microscopy, which suggested a highly localized plastic deformation. Mechanism governing the deformation was tentatively discussed in terms of the increasing process of free volume with a negligible temperature rise under low strain rate, which well explained the declining trend of elastic modulus and hardness with an increase of indentation depth.

  3. Self-heating simulation of GaN-based metal-oxide-semiconductor high-electron-mobility transistors including hot electron

    E-Print Network [OSTI]

    Ye, Peide "Peter"

    Self-heating simulation of GaN-based metal-oxide-semiconductor high-electron-mobility transistors the results of self-heating simulations of the GaN-based MOS-HEMTs, including hot electron and quantum effects of the gate and source/drain extension lengths on both the output performance and self-heating is discussed

  4. Deproto-metallation using mixed lithium-zinc and lithium-copper bases and computed CH acidity of 2-substituted quinolines

    E-Print Network [OSTI]

    Boyer, Edmond

    Deproto-metallation using mixed lithium-zinc and lithium-copper bases and computed CH acidity of 2 corresponding iodo derivatives or 2-chlorophenyl ketones using the lithium-zinc or the lithium using the lithium-zinc base. With 3-pyridyl, 2-furyl and 2-thienyl substituents, the reaction took place

  5. Fluorescence-based detection methodologies for nitric oxide using transition metal scaffolds

    E-Print Network [OSTI]

    Hilderbrand, Scott A. (Scott Alan), 1976-

    2004-01-01T23:59:59.000Z

    Chapter 1. Fluorescence-Based Detection Methodologies for Nitric Oxide: A Review. Chapter 2. Cobalt Chemistry with Mixed Aminotroponimine Salicylaldimine Ligands: Synthesis, Characterization, and Nitric Oxide Reactivity. ...

  6. 3500-hour durability testing of commercial ceramic materials. Interim report

    SciTech Connect (OSTI)

    Carruthers, W.D.; Richerson, D.W.; Benn, K.W.

    1980-07-01T23:59:59.000Z

    A two-year durability testing program was performed by AiResearch Phoenix to evaluate four commercially available ceramic materials under simulated automotive gas turbine combustor discharge conditions. These conditions included extended cyclic thermal exposures up to 2500/sup 0/F and 3500 h. The four materials selected for evaluation were Norton NCX-34 hot pressed silicon nitride, AiResearch RBN 101 reaction bonded silicon nitride, Carborundum pressureless sintered ..cap alpha..-SiC and British Nuclear Fuels, Ltd. Refel reaction sintered silicon carbide marketed by Pure Carbon Co. These materials initially were exposed to 350 h/1750 cycles at 1200 and 1370/sup 0/C (2200 and 2500/sup 0/F). Subsequent exposures to 1050, 2100, and 3500 h were performed on the materials maintaining 50% of baseline strength after the initial exposure. Additional evaluations of exposed bars included dimension changes, weight changes, dye penetrant, specific damping capacity changes, Scanning Electron Microscope (SEM) fractography and x-ray diffraction.

  7. The Role of Partial Crystallinity on Hydrogen Permeation in Fe–Ni–B–Mo Based Metallic Glass Membranes

    SciTech Connect (OSTI)

    Brinkman, K.; Su, D.; Fox, E.; Korinko, P.; Missimer, D.; Adams, T.

    2011-08-15T23:59:59.000Z

    A potentially exciting material for membrane separations are metallic glass materials due to their low cost, high elastic toughness and resistance to hydrogen embrittlement as compared to crystalline Pd-based membrane systems. However, at elevated temperatures and extended operation times structural changes including partial crystallinity may appear in these amorphous metallic systems. This study reports on the investigation of time and temperature dependent crystalline phase formation in conjunction with in situ crystallization/hydrogen permeation experiments at elevated temperatures. At temperatures near 400 C a FeNi crystalline phase appears as 22 vol.% inside the host amorphous matrix and the resulting composite structure remains stable over 3 h at temperature. The hydrogen permeation at 400 C of the partially crystalline material is similar to the fully amorphous material near 5 x 10{sup -9} mol H{sub 2}/m s Pa{sup 1/2}, while ambient temperature electrochemical permeation at 25 C revealed an order of magnitude decrease in the permeation of partially crystalline materials due to differences in the amorphous versus crystalline phase activation energy for hydrogen permeation.

  8. Durability Testing of Fluidized Bed Steam Reforming Products

    SciTech Connect (OSTI)

    JANTZEN, CAROL M.; PAREIZS, JOHN M.; LORIER, TROY H.; MARRA, JAMES C.

    2005-07-01T23:59:59.000Z

    Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of radioactive wastes but especially aqueous high sodium wastes at the Hanford site, at the Idaho National Laboratory (INL), and at the Savannah River Site (SRS). The FBSR technology converts organic compounds to CO{sub 2} and H{sub 2}O, converts nitrate/nitrite species to N{sub 2}, and produces a solid residue through reactions with superheated steam, the fluidizing media. If clay is added during processing a ''mineralized'' granular waste form can be produced. The mineral components of the waste form are primarily Na-Al-Si (NAS) feldspathoid minerals with cage-like and ring structures and iron bearing spinel minerals. The cage and ring structured minerals atomically bond radionuclides like Tc{sup 99} and Cs{sup 137} and anions such as SO{sub 4}, I, F, and Cl. The spinel minerals appear to stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Durability testing of the FBSR products was performed using ASTM C1285 (Product Consistency Test) and the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP). The FBSR mineral products (bed and fines) evaluated in this study were found to be two orders of magnitude more durable than the Hanford Low Activity Waste (LAW) glass requirement of 2 g/m{sup 2} release of Na{sup +}. The PCT responses for the FBSR samples tested were consistent with results from previous FBSR Hanford LAW product testing. Differences in the response can be explained by the minerals formed and their effects on PCT leachate chemistry.

  9. HIGH-CURRENT ZINC-AIR MICROBATTERY BASED ON A MICROMACHINED MULTILAYER LATERAL METALLIC SCAFFOLD

    E-Print Network [OSTI]

    `skeleton'. This scaffold consists of alternating copper and nickel layers supporting zinc as electrodeposited anode material. A proof-of-concept zinc-air microbattery based on this technology was developed

  10. Molten salt extraction process for the recovery of valued transition metals from land-based and deep-sea minerals

    DOE Patents [OSTI]

    Maroni, Victor A. (Naperville, IL); von Winbush, Samuel (Huntington, NY)

    1988-01-01T23:59:59.000Z

    A process for extracting transition metals and particularly cobalt and manganese together with iron, copper and nickel from low grade ores (including ocean-floor nodules) by converting the metal oxides or other compositions to chlorides in a molten salt, and subsequently using a combination of selective distillation at temperatures below about 500.degree. C., electrolysis at a voltage not more negative than about -1.5 volt versus Ag/AgCl, and precipitation to separate the desired manganese and cobalt salts from other metals and provide cobalt and manganese in metallic forms or compositions from which these metals may be more easily recovered.

  11. Molten salt extraction process for the recovery of valued transition metals from land-based and deep-sea minerals

    DOE Patents [OSTI]

    Maroni, V.A.; von Winbush, S.

    1987-05-01T23:59:59.000Z

    A process for extracting transition metals and particularly cobalt and manganese together with iron, copper and nickel from low grade ores (including ocean-floor nodules) by converting the metal oxides or other compositions to chlorides in a molten salt, and subsequently using a combination of selective distillation at temperatures below about 500/degree/C, electrolysis at a voltage not more negative that about /minus/1.5 volt versus Ag/AgCl, and precipitation to separate the desired manganese and cobalt salts from other metals and provide cobalt and manganese in metallic forms or compositions from which these metals may be more easily recovered.

  12. On Coating Durability of Polymer Coated Sheet Metal under Plastic Deformation

    E-Print Network [OSTI]

    Huang, Yu-Hsuan

    2011-08-08T23:59:59.000Z

    -off apparatus that measures the coating pull-off stress was used to indicate the coating adhesion strength. Several types of specimen were designed to obtain uniaxial tension, biaxial tension, and tension-compression deformation modes on pre-coated sheet...

  13. Impact of Biodiesel Metals on the Performance and Durability of DOC and DPF

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet),Energy Petroleum TechnologyEnergyImaging AheadTechnologies |

  14. New MEA Materials for Improved DMFC Performance, Durability and Cost

    SciTech Connect (OSTI)

    Fletcher, James H. [University of North Florida; Campbell, Joseph L. [University of North Florida; Cox, Philip [University of North Florida; Harrington, William J. [University of North Florida

    2013-09-16T23:59:59.000Z

    Abstract Project Title: New MEA Materials for Improved DMFC Performance, Durability and Cost The University of North Florida (UNF)--with project partners the University of Florida, Northeastern University, and Johnson Matthey--has recently completed the Department of Energy (DOE) project entitled “New MEA Materials for Improved DMFC Performance, Durability and Cost”. The primary objective of the project was to advance portable fuel cell MEA technology towards the commercial targets as laid out in the DOE R&D roadmap by developing a passive water recovery MEA (membrane electrode assembly). Developers at the University of North Florida identified water management components as an insurmountable barrier to achieving the required system size and weight necessary to achieve the energy density requirements of small portable power applications. UNF developed an innovative “passive water recovery” MEA for direct methanol fuel cells (DMFC) which provides a path to system simplification and optimization. The passive water recovery MEA incorporates a hydrophobic, porous, barrier layer within the cathode electrode, so that capillary pressure forces the water produced at the cathode through holes in the membrane and back to the anode. By directly transferring the water from the cathode to the anode, the balance of plant is very much simplified and the need for heavy, bulky water recovery components is eliminated. At the heart of the passive water recovery MEA is the UNF DM-1 membrane that utilizes a hydrocarbon structure to optimize performance in a DMFC system. The membrane has inherent performance advantages, such as a low methanol crossover (high overall efficiency), while maintaining a high proton conductivity (good electrochemical efficiency) when compared to perfluorinated sulfonic acid membranes such as Nafion. Critically, the membrane provides an extremely low electro-osmotic drag coefficient of approximately one water molecule per proton (versus the 2-3 for Nafion) that minimizes flooding issues at the cathode, which often fatally limit open cathode MEA performance. During this successfully completed DOE program the project team met all of the project goals. The team built and tested over 1,500 MEAs with a wide range of different manufacturing chemistries and process conditions. This project demonstrated that the UNF MEA design could be fabricated with a high degree of reproducibility and repeatability. Some specific achievements include: • Durability - The UNF MEA has demonstrated over 11,000 hours continuous operation in a short stack configuration. The root cause of an off-state degradation issue was successfully mitigated by modifying the manufacturing process by changing the wetting agents used in the catalyst printing. The stability of the anode electrode was increased by replacing the anode electrodes with a stabilized PtRu/C catalyst. The overall degradation rate was significantly reduced through optimization of the MEA operating conditions. • Performance - The project team optimized the performance of the critical MEA sub-components. By increasing the membrane thickness, the methanol crossover was reduced, thereby increasing the fuel utilization efficiency without sacrificing any electrochemical performance. The reduction in methanol crossover increased the fuel utilization efficiency from 78% to over 90%. The liquid barrier layer was optimized to provide improved reproducibility, thereby improving stack voltage uniformity and reliability. Additionally the barrier layer water permeability was lowered without sacrificing any power density, thereby enabling increased operating temperature. Improvements in the cathode catalyst selection and coating provided an additional 10% to 20% improvement in the MEA performance at the target operating range. • Cost - Commercially scalable processes were developed for all of the critical MEA components which led to improved yields and lower overall manufacturing costs. Furthermore, significant steps have been made in improving the process control, which increases MEA

  15. Stabilization of Electrocatalytic Metal Nanoparticles at Metal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electrocatalytic Metal Nanoparticles at Metal-Metal Oxide-Graphene Triple Junction Points. Stabilization of Electrocatalytic Metal Nanoparticles at Metal-Metal Oxide-Graphene...

  16. Synthesis-Structure-Performance Correlation for Polyaniline-Me-C Non-Precious Metal Cathode Catalysts for Oxygen Reduction in Fuel Cells

    SciTech Connect (OSTI)

    Wu, Gang [Los Alamos National Laboratory (LANL); Johnston, Christina [Los Alamos National Laboratory (LANL); Mack, Nathan [Los Alamos National Laboratory (LANL); Artyushkova, Kateryna [University of New Mexico, Albuquerque; Ferrandon, Magali [Argonne National Laboratory (ANL); Nelson, Mark [Los Alamos National Laboratory (LANL); Lezama-pacheco, Juan [Los Alamos National Laboratory (LANL); Conradson, Steven [Los Alamos National Laboratory (LANL); More, Karren Leslie [ORNL; Myers, Deborah [Argonne National Laboratory (ANL); Zelenay, Piotr [Los Alamos National Laboratory (LANL)

    2011-01-01T23:59:59.000Z

    In this report, we present the systematic preparation of active and durable non-precious metal catalysts (NPMCs) for the oxygen reduction reaction in polymer electrolyte fuel cells (PEFCs) based on the heat treatment of polyaniline/metal/carbon precursors. Variation of the synthesis steps, heat-treatment temperature, metal loading, and the metal type in the synthesis leads to markedly different catalyst activity, speciation, and morphology. Microscopy studies demonstrate notable differences in the carbon structure as a function of these variables. Balancing the need to increase the catalyst's degree of graphitization through heat treatment versus the excessive loss of surface area that occurs at higher temperatures is a key to preparing an active catalyst. XPS and XAFS spectra are consistent with the presence of Me-N{sub x} structures in both the Co and Fe versions of the catalyst, which are often proposed to be active sites. The average speciation and coordination environment of nitrogen and metal, however, depends greatly on the choice of Co or Fe. Taken together, the data indicate that better control of the metal-catalyzed transformations of the polymer into new graphitized carbon forms in the heat-treatment step will allow for even further improvement of this class of catalysts.

  17. The dynamic behavior of thin-film ionic transition metal complex-based light-emitting electrochemical cells

    SciTech Connect (OSTI)

    Meier, Sebastian B., E-mail: sebastian.meier@belectric.com, E-mail: wiebke.sarfert@siemens.com [Department of Materials Science VI: Materials for Electronics and Energy Technology, Friedrich-Alexander-University of Erlangen-Nuremberg, 91058 Erlangen (Germany); Siemens AG, Corporate Technology, CT RTC MAT IEC-DE, 91058 Erlangen (Germany); Hartmann, David; Sarfert, Wiebke, E-mail: sebastian.meier@belectric.com, E-mail: wiebke.sarfert@siemens.com [Siemens AG, Corporate Technology, CT RTC MAT IEC-DE, 91058 Erlangen (Germany); Winnacker, Albrecht [Department of Materials Science VI: Materials for Electronics and Energy Technology, Friedrich-Alexander-University of Erlangen-Nuremberg, 91058 Erlangen (Germany)

    2014-09-14T23:59:59.000Z

    Light-emitting electrochemical cells (LECs) have received increasing attention during recent years due to their simple architecture, based on solely air-stabile materials, and ease of manufacture in ambient atmosphere, using solution-based technologies. The LEC's active layer offers semiconducting, luminescent as well as ionic functionality resulting in device physical processes fundamentally different as compared with organic light-emitting diodes. During operation, electrical double layers (EDLs) form at the electrode interfaces as a consequence of ion accumulation and electrochemical doping sets in leading to the in situ development of a light-emitting p-i-n junction. In this paper, we comment on the use of impedance spectroscopy in combination with complex nonlinear squares fitting to derive key information about the latter events in thin-film ionic transition metal complex-based light-emitting electrochemical cells based on the model compound bis-2-phenylpyridine 6-phenyl-2,2?-bipyridine iridium(III) hexafluoridophosphate ([Ir(ppy){sub 2}(pbpy)][PF{sub 6}]). At operating voltages below the bandgap potential of the ionic complex used, we obtain the dielectric constant of the active layer, the conductivity of mobile ions, the transference numbers of electrons and ions, and the thickness of the EDLs, whereas the transient thickness of the p-i-n junction is determined at voltages above the bandgap potential. Most importantly, we find that charge transport is dominated by the ions when carrier injection from the electrodes is prohibited, that ion movement is limited by the presence of transverse internal interfaces and that the width of the intrinsic region constitutes almost 60% of the total active layer thickness in steady state at a low operating voltage.

  18. THE DEVELOPMENT AND ON-ROAD PERFORMANCE AND DURABILITY OF THE FOUR-WAY EMISSION CONTROL SCRT{trademark} SYSTEM

    SciTech Connect (OSTI)

    Cooper, BJ; McDonald, AC; Walker, AP; Sanchez, M

    2003-08-24T23:59:59.000Z

    legislation worldwide necessitates the development of pollution control systems capable of enabling engines to meet the incoming legislative requirements. It is clear that to maximize the benefit to the environment, as well as to meet the very stringent future standards (especially the US 2010 limits), systems capable of high simultaneous conversions of all four major pollutants, carbon monoxide (CO), hydrocarbons (HC), oxides of nitrogen (NOx) and Particulate Matter (PM), are required. Very high conversions of CO, HC and PM are achieved using catalyst-based Diesel Particulate Filter (DPF) systems, such as the Continuously Regenerating Technology, CRT{reg_sign}, system. High NOx conversions can be obtained using Selective Catalytic Reduction (SCR) systems, in which ammonia (generated from urea) is used to selectively reduce the NOx. This paper summarizes the key steps in the development of the four-way SCRT system, which comprises the CRT system followed by an SCR system. Engine bench results obtained during the development of this system are presented and discussed. However, the key to real-world emissions benefit is the actual on-road performance of such systems. It is well established that the CRT system provides very high and durable conversions of CO, HC and PM, so the focus of this current work was to demonstrate the NOx conversion capability and durability of the SCRT system. The SCRT unit was installed on a long-haul truck powered by a 15 litre Cummins engine. On-road NOx emissions performance was measured using NOx sensors located upstream and downstream of the SCRT unit. Over an 850 km evaluation route, the average on-road NOx conversion obtained was up to 82%, even when the urea injection quantity was set to give a maximum NOx conversion of around 85%. The durability of the system has also been assessed. Over the course of 150,000 km, no reduction in the NOx conversion efficiency of the system was observed. The results presented in this paper demonstrate that the SCRT system provides very high on-road NOx conversion, and that the system has excellent durability within real-world applications.

  19. Enhanced-wetting, boron-based liquid-metal ion source and method

    DOE Patents [OSTI]

    Bozack, M.J.; Swanson, L.W.; Bell, A.E.; Clark, W.M. Jr.; Utlaut, M.W.; Storms, E.K.

    1999-02-16T23:59:59.000Z

    A binary, boron-based alloy as a source for field-emission-type, ion-beam generating devices, wherein boron predominates in the alloy, preferably with a presence of about 60 atomic percent is disclosed. The other constituent in the alloy is selected from the group of elements consisting of nickel, palladium and platinum. Predominance of boron in these alloys, during operation, promotes combining of boron with trace impurities of carbon in the alloys to form B{sub 4}C and thus to promote wetting of an associated carbon support substrate. 1 fig.

  20. History of the application of the generalized Lewis acid-base theory to metals

    SciTech Connect (OSTI)

    Brewer, L.

    1988-11-01T23:59:59.000Z

    The history of my experiences with intermetallics has been found useful by students seeking my advice on which directions in science they should be emphasizing. In response to their question, I point to a mobile in my office consisting of seven hands pointing in different directions. Science comes up with so many unexpected developments that one's education should have a broad enough base to allow one to branch out in any direction to take advantage of unexpected opportunities. My historical presentation will be a personal account that I hope will serve as a guide to students. There have been many unexpected abrupt changes in my research.

  1. Enhanced-wetting, boron-based liquid-metal ion source and method

    DOE Patents [OSTI]

    Bozack, Michael J. (Opelika, AL); Swanson, Lynwood W. (Portland, OR); Bell, Anthony E. (McMinnville, OR); Clark Jr., William M. (Thousand Oaks, CA); Utlaut, Mark W. (Saugus, CA); Storms, Edmund K. (Los Alamos, NM)

    1999-01-01T23:59:59.000Z

    A binary, boron-based alloy as a source for field-emission-type, ion-beam generating devices, wherein boron predominates in the alloy, preferably with a presence of about 60 atomic percent. The other constituent in the alloy is selected from the group of elements consisting of nickel, palladium and platinum. Predominance of boron in these alloys, during operation, promotes combining of boron with trace impurities of carbon in the alloys to form B.sub.4 C and thus to promote wetting of an associated carbon support substrate.

  2. Durability of Acrylic: Stress and Response Characterization of Materials for Photovoltaics

    E-Print Network [OSTI]

    Rollins, Andrew M.

    Durability of Acrylic: Stress and Response Characterization of Materials for Photovoltaics Myles P of materials for enhanced photovoltaic (PV) performance, it is critical to have quantitative knowledge of acrylic PMMA are reported. Keywords-Acrylic, Degradation, Photovoltaics, Photodegradation I. INTRODUCTION

  3. Characterization of Sensor Performance and Durability for Structural Health Monitoring Systems

    E-Print Network [OSTI]

    Giurgiutiu, Victor

    Characterization of Sensor Performance and Durability for Structural Health Monitoring Systems with regard to successfully implementing Structural Health Monitoring technologies in Air Force systems sensor system design and packaging. Keywords: Structural Health Monitoring, Piezo Wafer Active Sensors

  4. Environmental durability of FRP bond to concrete subjected to freeze-thaw action

    E-Print Network [OSTI]

    Dohnálek, Pavel

    2006-01-01T23:59:59.000Z

    An experimental study was performed to determine the environmental durability of the adhesive bond between fiber-reinforced plastic (FRP) and concrete. The study specifically focused on freeze-thaw cycling exposure of such ...

  5. A Study of Fire Durability for a Road Tunnel: Comparing CFD and Simple Analytical Models 

    E-Print Network [OSTI]

    Reszka, Pedro; Steinhaus, Thomas; Biteau, Hubert; Carvel, Ricky O; Rein, Guillermo; Torero, Jose L

    The durability of various typical tunnel sections in the event of a prescribed 100 MW fire has been assessed. Cast-iron sections, pre-cast concrete sections and in-situ concrete cut and cover sections are all considered ...

  6. Assessment of durability performance of "Early-Opening-to-Traffic" Portland Cement Concrete pavement and patches

    E-Print Network [OSTI]

    Shrestha, Pradhumna Babu

    1999-01-01T23:59:59.000Z

    This study relates the assessment of durability to ''early-opening-to-traffic'' (EOT) portland cement concrete (PCC). Several factors were identified relative to the performance of EOT PCC. Each of these factors was considered in terms of freeze...

  7. Decomposition of Perfluorocompounds on Alumina-Based Catalyst

    SciTech Connect (OSTI)

    Kanno, Shuichi; Tamata, Shin; Kurokawa, Hideaki

    2004-03-31T23:59:59.000Z

    The control of the atmospheric release of PFCs (perfluorocompounds) is an important environmental problem worldwide. PFCs are powerful greenhouse gases used by the semiconductor and liquid crystal industries as etching and cleaning agents. We developed a catalyst that decomposes PFCs with only water. Al2O3 was selected from the survey of some single metal-oxide catalysts. Addition of another metal-oxide improved the decomposition ratio and durability. The Al2O3-based catalyst decomposed CF4, C2F6, C3F8, C4F8, NF3 and SF6 by more than 99% at 750 degrees Celsius. Furthermore, our catalyst retained a high decomposition ratio as demonstrated by a continuous run for about 4000 hours at 700-750 degrees Celsius. The influence of chlorine as an impurity with regard to the SF6 decomposition ratio on the catalyst was examined. SF6 was decomposed at more than 99% during 8 hours in the presence of 400 ppm chlorine. Chlorine concentration in the outlet gas was less than TLV. No chlorine compounds were found by X-ray diffraction analysis of the used catalyst. That is, the hydrogenation of chlorine did not inhibit the surface catalytic reaction for PFC. Also, CF4 was decomposed at the condition of 1.4% of high concentration. The conversion remained higher than 99% throughout during a durability test. Furthermore, we investigated a large-scale decomposition system in the paper.

  8. Durability of Polymeric Encapsulation Materials for Concentrating Photovoltaic Systems (Presentation)

    SciTech Connect (OSTI)

    Miller, D. C.; Muller, M.; Kempe, M. D.; Araki, K.; Kennedy, C. E.; Kurtz, S. R.

    2012-03-01T23:59:59.000Z

    Many concentrating photovoltaic (CPV) systems use a polymeric encapsulant to couple and optical component and/or coverglass to the cell. In that location, the encapsulation improves the transmission of concentrated optical flux through interface(s), while protecting the cell from the environment. The durability of encapsulation materials, however, is not well established relative to the desired service life of 30 years. Therefore, we have initiated a screen test to identify the field-induced failure modes for a variety of popular PV encapsulation materials. An existing CPV module (with no PV cells present) was modified to accommodate encapsulation specimens. The module (where nominal concentration of solar flux is 500x for the domed-Fresnel design) has been mounted on a tracker in Golden, CO (elevation 1.79 km). Initial results are reported here for 18 months cumulative exposure, including the hottest and coldest months of the past year. Characteristics observed at intervals during that time include: visual appearance, direct and hemispherical transmittance, and mass. Degradation may be assessed from subsequent analysis (including yellowness index and cut-on frequency) relative to the ambient conditions present during field exposure. The fluorescence signature observed of all the silicone specimens is examined here, including possible factors of causation -- the platinum catalyst used in the addition cured materials as well as the primer used to promote adhesion to the quartz substrate and superstrate.

  9. Durability study of a vehicle-scale hydrogen storage system.

    SciTech Connect (OSTI)

    Johnson, Terry Alan; Dedrick, Daniel E.; Behrens, Richard, Jr.

    2010-11-01T23:59:59.000Z

    Sandia National Laboratories has developed a vehicle-scale demonstration hydrogen storage system as part of a Work for Others project funded by General Motors. This Demonstration System was developed based on the properties and characteristics of sodium alanates which are complex metal hydrides. The technology resulting from this program was developed to enable heat and mass management during refueling and hydrogen delivery to an automotive system. During this program the Demonstration System was subjected to repeated hydriding and dehydriding cycles to enable comparison of the vehicle-scale system performance to small-scale sample data. This paper describes the experimental results of life-cycle studies of the Demonstration System. Two of the four hydrogen storage modules of the Demonstration System were used for this study. A well-controlled and repeatable sorption cycle was defined for the repeated cycling, which began after the system had already been cycled forty-one times. After the first nine repeated cycles, a significant hydrogen storage capacity loss was observed. It was suspected that the sodium alanates had been affected either morphologically or by contamination. The mechanisms leading to this initial degradation were investigated and results indicated that water and/or air contamination of the hydrogen supply may have lead to oxidation of the hydride and possibly kinetic deactivation. Subsequent cycles showed continued capacity loss indicating that the mechanism of degradation was gradual and transport or kinetically limited. A materials analysis was then conducted using established methods including treatment with carbon dioxide to react with sodium oxides that may have formed. The module tubes were sectioned to examine chemical composition and morphology as a function of axial position. The results will be discussed.

  10. FY05 HPCRM Annual Report: High-Performance Corrosion-Resistant Iron-Based Amorphous Metal Coatings

    SciTech Connect (OSTI)

    Farmer, J; Choi, J; Haslam, J; Day, S; Yang, N; Headley, T; Lucadamo, G; Yio, J; Chames, J; Gardea, A; Clift, M; Blue, G; Peters, W; Rivard, J; Harper, D; Swank, D; Bayles, R; Lemieux, E; Brown, R; Wolejsza, T; Aprigliano, L; Branagan, D; Marshall, M; Meacham, B; Aprigliano, L; Branagan, D; Marshall, M; Meacham, B; Lavernia, E; Schoenung, J; Ajdelsztajn, L; Dannenberg, J; Graeve, O; Lewandowski, J; Perepezko, J; Hildal, K; Kaufman, L; Boudreau, J

    2007-09-20T23:59:59.000Z

    New corrosion-resistant, iron-based amorphous metals have been identified from published data or developed through combinatorial synthesis, and tested to determine their relative corrosion resistance. Many of these materials can be applied as coatings with advanced thermal spray technology. Two compositions have corrosion resistance superior to wrought nickel-based Alloy C-22 (UNS No. N06022) in some very aggressive environments, including concentrated calcium-chloride brines at elevated temperature. Two Fe-based amorphous metal formulations have been found that appear to have corrosion resistance comparable to, or better than that of Ni-based Alloy C-22, based on breakdown potential and corrosion rate. Both Cr and Mo provide corrosion resistance, B enables glass formation, and Y lowers critical cooling rate (CCR). SAM1651 has yttrium added, and has a nominal critical cooling rate of only 80 Kelvin per second, while SAM2X7 (similar to SAM2X5) has no yttrium, and a relatively high critical cooling rate of 610 Kelvin per second. Both amorphous metal formulations have strengths and weaknesses. SAM1651 (yttrium added) has a low critical cooling rate (CCR), which enables it to be rendered as a completely amorphous thermal spray coating. Unfortunately, it is relatively difficult to atomize, with powders being irregular in shape. This causes the powder to be difficult to pneumatically convey during thermal spray deposition. Gas atomized SAM1651 powder has required cryogenic milling to eliminate irregularities that make flow difficult. SAM2X5 (no yttrium) has a high critical cooling rate, which has caused problems associated with devitrification. SAM2X5 can be gas atomized to produce spherical powders of SAM2X5, which enable more facile thermal spray deposition. The reference material, nickel-based Alloy C-22, is an outstanding corrosion-resistant engineering material. Even so, crevice corrosion has been observed with C-22 in hot sodium chloride environments without buffer or inhibitor. Comparable metallic alloys such as SAM2X5 and SAM1651 may also experience crevice corrosion under sufficiently harsh conditions. Accelerated crevice corrosion tests are now being conducted to intentionally induce crevice corrosion, and to determine those environmental conditions where such localized attack occurs. Such materials are extremely hard, and provide enhanced resistance to abrasion and gouges (stress risers) from backfill operations, and possibly even tunnel boring. The hardness of Type 316L Stainless Steel is approximately 150 VHN, that of Alloy C-22 is approximately 250 VHN, and that of HVOF SAM2X5 ranges from 1100-1300 VHN. These new materials provide a viable coating option for repository engineers. SAM2X5 and SAM1651 coatings can be applied with thermal spray processes without any significant loss of corrosion resistance. Both Alloy C-22 and Type 316L stainless lose their resistance to corrosion during thermal spraying. Containers for the transportation, storage and disposal of spent nuclear fuel (SNF) and high-level radioactive waste (HLW) with corrosion resistant coatings are envisioned. For example, an enhanced multi-purpose container (MPC) could be made with such coatings, leveraging existing experience in the fabrication of such containers. These coating materials could be used to protect the final closure weld on SNF/HLW disposal containers, eliminate need for stress mitigation. Integral drip shield could be produced by directly spraying it onto the disposal container, thereby eliminating the need for an expensive titanium drip shield. In specific areas where crevice corrosion is anticipated, such as the contact point between the disposal container and pallet, HVOF coatings could be used to buildup thickness, thereby selectively adding corrosion life where it is needed. Both SAM2X5 & SAM1651 have high boron content which enable them to absorb neutrons and therefore be used for criticality control in baskets. Alloy C-22 and 316L have no neutron absorber, and cannot be used for such functions. Borated stainless steel and G

  11. Iron-Based Amorphous-Metals: High-Performance Corrosion-Resistant Materials (HPCRM) Development Final Report

    SciTech Connect (OSTI)

    Farmer, J C; Choi, J; Saw, C; Haslem, J; Day, D; Hailey, P; Lian, T; Rebak, R; Perepezko, J; Payer, J; Branagan, D; Beardsley, B; D'Amato, A; Aprigliano, L

    2009-03-16T23:59:59.000Z

    An overview of the High-Performance Corrosion-Resistant Materials (HPCRM) Program, which was co-sponsored by the Defense Advanced Research Projects Agency (DARPA) Defense Sciences Office (DSO) and the United States Department of Energy (DOE) Office of Civilian and Radioactive Waste Management (OCRWM), is discussed. Programmatic investigations have included a broad range of topics: alloy design and composition; materials synthesis; thermal stability; corrosion resistance; environmental cracking; mechanical properties; damage tolerance; radiation effects; and important potential applications. Amorphous alloys identified as SAM2X5 (Fe{sub 49.7}Cr{sub 17.7}Mn{sub 1.9}Mo{sub 7.4}W{sub 1.6}B{sub 15.2}C{sub 3.8}Si{sub 2.4}) and SAM1651 (Fe{sub 48}Mo{sub 14}Cr{sub 15}Y{sub 2}C{sub 15}B{sub 6}) have been produced as melt-spun ribbons, drop-cast ingots and thermal-spray coatings. Chromium (Cr), molybdenum (Mo) and tungsten (W) additions provided corrosion resistance, while boron (B) enabled glass formation. Earlier electrochemical studies of melt-spun ribbons and ingots of these amorphous alloys demonstrated outstanding passive film stability. More recently thermal-spray coatings of these amorphous alloys have been made and subjected to long-term salt-fog and immersion tests. Good corrosion resistance has been observed during salt-fog testing. Corrosion rates were measured in situ with linear polarization, while simultaneously monitoring the open-circuit corrosion potentials. Reasonably good performance was observed. The sensitivity of these measurements to electrolyte composition and temperature was determined. The high boron content of this particular amorphous metal make this amorphous alloy an effective neutron absorber, and suitable for criticality control applications. In general, the corrosion resistance of these iron-based amorphous metals is maintained at operating temperatures up to the glass transition temperature. These materials are much harder than conventional stainless steel and nickel-based materials, and are proving to have excellent wear properties, sufficient to warrant their use in earth excavation, drilling and tunnel boring applications. The observed corrosion resistance may enable applications of importance in industries such as: oil and gas production, refining, nuclear power generation, shipping, and others. Large areas have been successfully coated with these materials, with thicknesses of approximately one centimeter.

  12. M5Si3(M=Ti, Nb, Mo) Based Transition-Metal Silicides for High Temperature Applications

    SciTech Connect (OSTI)

    Zhihong Tang

    2007-12-01T23:59:59.000Z

    Transition metal silicides are being considered for future engine turbine components at temperatures up to 1600 C. Although significant improvement in high temperature strength, room temperature fracture toughness has been realized in the past decade, further improvement in oxidation resistance is needed. Oxidation mechanism of Ti{sub 5}Si{sub 3}-based alloys was investigated. Oxidation behavior of Ti{sub 5}Si{sub 3}-based alloy strongly depends on the atmosphere. Presence of Nitrogen alters the oxidation behavior of Ti{sub 5}Si{sub 3} by nucleation and growth of nitride subscale. Ti{sub 5}Si{sub 3.2} and Ti{sub 5}Si{sub 3}C{sub 0.5} alloys exhibited an excellent oxidation resistance in nitrogen bearing atmosphere due to limited dissolution of nitrogen and increased Si/Ti activity ratio. MoSi{sub 2} coating developed by pack cementation to protect Mo-based Mo-Si-B composites was found to be effective up to 1500 C. Shifting coating composition to T1+T2+Mo{sub 3}Si region showed the possibility to extend the coating lifetime above 1500 C by more than ten times via formation of slow growing Mo{sub 3}Si or T2 interlayer without sacrificing the oxidation resistance of the coating. The phase equilibria in the Nb-rich portion of Nb-B system has been evaluated experimentally using metallographic analysis and differential thermal analyzer (DTA). It was shown that Nb{sub ss} (solid solution) and NbB are the only two primary phases in the 0-40 at.% B composition range, and the eutectic reaction L {leftrightarrow} Nb{sub SS} + NbB was determined to occur at 2104 {+-} 5 C by DTA.

  13. Use of novel synchrotron-based techniques to explore the connection between metal speciation in soils and plants

    E-Print Network [OSTI]

    Sparks, Donald L.

    speciation in soils and plants David H. McNear Jr.1, Edward Peltier1, Jeff Everhart1, D. L. Sparks1, Rufus L. Chaney2, S. Sutton3, and M. Newville3. (1) Department of Plant and Soil Sciences, University of Delaware as the primary interplant metal species. To ascertain the partitioning of metals within the plant tissue, SEM

  14. A High-Performance Corrosion-Resistant Iron-Based Amorphous Metal - The Effects of Composition, Structure and Environment on Corrosion Resistance

    SciTech Connect (OSTI)

    Farmer, J.; Haslam, J.; Day, D.; Lian, T.; Saw, C.; Hailey, P.; Choi, J.S.; Rebak, R. [Lawrence Livermore National Laboratory, Livermore, CA, 94550 (United States); Yang, N. [Sandia National Laboratory, Livermore, CA, 94550 (United States); Bayles, R. [Naval Research Laboratory, Washington, DC, 20375 (United States); Aprigliano, L. [Consultant, Berlin, MD, 21811 (United States); Payer, J. [Case Western Reserve University, Cleveland, OH, 44106 (United States); Perepezko, J.; Hildal, K. [University of Wisconsin, Madison, WI, 53706 (United States); Lavernia, E.; Ajdelsztajn, L. [University of California, Davis, CA, 95616 (United States); Branagan, D. [The NanoSteel Company, Idaho Falls, ID, 83402 (United States); Beardsley, B. [Caterpillar, Peoria, IL, 61656 (United States)

    2007-07-01T23:59:59.000Z

    The passive film stability of several Fe-based amorphous metal formulations have been found to be comparable to that of high-performance Ni-based alloys, and superior to that of stainless steels, based on electrochemical measurements of the passive film breakdown potential and general corrosion rates. Chromium (Cr), molybdenum (Mo) and tungsten (W) provide corrosion resistance; boron (B) enables glass formation; and rare earths such as yttrium (Y) lower critical cooling rate (CCR). The high boron content of this particular amorphous metal also makes it an effective neutron absorber, and suitable for criticality control applications, as discussed in companion publications. Corrosion data for SAM2X5 (Fe{sub 49.7}Cr{sub 17.7}Mn{sub 1.9}Mo{sub 7.4}W{sub 1.6}B{sub 15.2}C{sub 3.8}Si{sub 2.4}) is discussed here. (authors)

  15. Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials, and Development of Zeolite-Based Hydrocarbon Adsorber Materials

    SciTech Connect (OSTI)

    Gao, Feng; Kwak, Ja Hun; Lee, Jong H.; Tran, Diana N.; Peden, Charles HF; Howden, Ken; Cheng, Yisun; Lupescu, Jason; Cavattaio, Giovanni; Lambert, Christine; McCabe, Robert W.

    2012-12-31T23:59:59.000Z

    In this collaborative program, scientists and engineers in the Institute for Integrated Catalysis at Pacific Northwest National Laboratory and at Ford Motor Company have investigated laboratory- and engine-aged SCR catalysts, containing mainly base metal zeolites. These studies are leading to a better understanding of various aging factors that impact the long-term performance of SCR catalysts and improve the correlation between laboratory and engine aging, saving experimental time and cost. We have also studied materials effective for the temporary storage of HC species during the cold-start period. In particular, we have examined the adsorption and desorption of various HC species produced during the combustion with different fuels (e.g., gasoline, E85, diesel) over potential HC adsorber materials, and measured the kinetic parameters to update Ford’s HC adsorption model. Since this CRADA has now been completed, in this annual report we will provide very brief summaries of most of the work carried out on this CRADA over the last several years.

  16. Metal aminoboranes

    DOE Patents [OSTI]

    Burrell, Anthony K.; Davis, Benjamin J.; Thorn, David L.; Gordon, John C.; Baker, R. Thomas; Semelsberger, Troy Allen; Tumas, William; Diyabalanage, Himashinie Vichalya; Shrestha, Roshan P.

    2010-05-11T23:59:59.000Z

    Metal aminoboranes of the formula M(NH2BH3)n have been synthesized. Metal aminoboranes are hydrogen storage materials. Metal aminoboranes are also precursors for synthesizing other metal aminoboranes. Metal aminoboranes can be dehydrogenated to form hydrogen and a reaction product. The reaction product can react with hydrogen to form a hydrogen storage material. Metal aminoboranes can be included in a kit.

  17. IMPROVING THERMOELECTRIC TECHNOLOGY PERFORMANCE AND DURABILITY WITH AEROGEL

    E-Print Network [OSTI]

    Jeff Sakamoto; Thierry Caillat; Jean-pierre Fleurial; Steve Jones; Jong-ah Paik; Winny Dong

    path required for metal vapor to permeate aerogel is extremely tortuous, thus significantly decreasing sublimation rates. Another added benefit to using aerogel as a coating is that it can also serve as thermal insulation. Since aerogel is made through liquid synthesis it can be cast in or around

  18. Layer-by-Layer Fabrication of Oriented Porous Thin Films Based on Porphyrin-Containing Metal-Organic Frameworks

    E-Print Network [OSTI]

    with number of growth cycles. Polarization excitation and fluorescence measurements indicate, Papanikolas et al. have reported on the fabrication and energy migration dynamics of metal for its exploitation for the preparation of molecular devices.19 Example materials include HKUST-1

  19. Turn-on fluorescence in tetraphenylethylene-based metal-organic frameworks: An alternative to aggregation-induced emission

    E-Print Network [OSTI]

    Shustova, Natalia B.

    Coordinative immobilization of functionalized tetraphenylethylene within rigid porous metal–organic frameworks (MOFs) turns on fluorescence in the typically non-emissive tetraphenylethylene core. The matrix coordination-induced ...

  20. New Conducting and Electrically Switching Molecular Materials based on Main Group and Transition Metal Ions Bridged by TCNQ Derivatives

    E-Print Network [OSTI]

    Zhang, Zhongyue

    2013-05-24T23:59:59.000Z

    ,7,8,8-tetracyanoquinodimethane) has played a central role in the design of many unprecedented conducting materials including the first purely organic conductor (TTF)(TCNQ) (TTF = tetrathiafulvalene) which is nearly metallic and the electrically bistable switching material Cu...

  1. Synchronization of pairwise-coupled, identical, relaxation oscillators based on metal-insulator phase transition devices: A Model Study

    E-Print Network [OSTI]

    Abhinav Parihar; Nikhil Shukla; Suman Datta; Arijit Raychowdhury

    2014-08-11T23:59:59.000Z

    Computing with networks of synchronous oscillators has attracted wide-spread attention as novel materials and device topologies have enabled realization of compact, scalable and low-power coupled oscillatory systems. Of particular interest are compact and low-power relaxation oscillators that have been recently demonstrated using MIT (metal- insulator-transition) devices using properties of correlated oxides. This paper presents an analysis of the dynamics and synchronization of a system of two such identical coupled relaxation oscillators implemented with MIT devices. We focus on two implementations of the oscillator: (a) a D-D configuration where complementary MIT devices (D) are connected in series to provide oscillations and (b) a D-R configuration where it is composed of a resistor (R) in series with a voltage-triggered state changing MIT device (D). The MIT device acts like a hysteresis resistor with different resistances in the two different states. The synchronization dynamics of such a system has been analyzed with purely charge based coupling using a resistive (Rc) and a capacitive (Cc) element in parallel. It is shown that in a D-D configuration symmetric, identical and capacitively coupled relaxation oscillator system synchronizes to an anti-phase locking state, whereas when coupled resistively the system locks in phase. Further, we demonstrate that for certain range of values of Rc and Cc, a bistable system is possible which can have potential applications in associative computing. In D-R configuration, we demonstrate the existence of rich dynamics including non-monotonic flows and complex phase relationship governed by the ratios of the coupling impedance. Finally, the developed theoretical formulations have been shown to explain experimentally measured waveforms of such pairwise coupled relaxation oscillators.

  2. DURABILITY EVALUATION AND PRODUCTION OF MANUFACTURED AGGREGATES FROM COAL COMBUSTION BY-PRODUCTS

    SciTech Connect (OSTI)

    M. M. Wu

    2005-02-01T23:59:59.000Z

    Under the cooperative agreement with DOE, the Research and Development Department of CONSOL Energy (CONSOL R&D), teamed with Universal Aggregates, LLC, to conduct a systematic study of the durability of aggregates manufactured using a variety of flue gas desulfurization (FGD), fluidized-bed combustion (FBC) and fly ash specimens with different chemical and physical properties and under different freeze/thaw, wet/dry and long-term natural weathering conditions. The objectives of the study are to establish the relationships among the durability and characteristics of FGD material, FBC ash and fly ash, and to identify the causes of durability problems, and, ultimately, to increase the utilization of FGD material, FBC ash and fly ash as a construction material. Manufactured aggregates made from FGD material, FBC ash and fly ash, and products made from those manufactured aggregates were used in the study. The project is divided into the following activities: sample collection and characterization; characterization and preparation of manufactured aggregates; determination of durability characteristics of manufactured aggregates; preparation and determination of durability characteristics of manufactured aggregate products; and data evaluation and reporting.

  3. subcollector Schottky collector contact & interconnect metals

    E-Print Network [OSTI]

    Rodwell, Mark J. W.

    base collector depletion layer subcollector ohmic metal (a) base collector depletion layer Schottky metal base emitter collector collector We emitter base emitter emitter We Wc Wc (b) Schottky collector contact & interconnect metals Emitter & collector Ohmics undoped collector depletion layer base N

  4. Characterization of Carbon-Based Biomaterials 

    E-Print Network [OSTI]

    Zhou, Yan

    2014-04-24T23:59:59.000Z

    new lubricants that will be more efficient, more environmental friendly, and more durable. The carbon-based biomaterials would lead to a new generation of artificial joints that help to improve the quality life for patients who need prosthesis....

  5. Recycled Unbound Base Pooled Fund Study

    E-Print Network [OSTI]

    Minnesota, University of

    Recycled Unbound Base Pooled Fund Study Tuncer B. Edil Recycled Materials Resource Center Geological Engineering Program University of Wisconsin-Madison #12;·! Recycled Concrete Aggregate (RCA absorption ­! Un-Hydrated cement increases strength and durability ·! Recycled asphalt pavement (RAP

  6. Final Technical Report on DE-SC00002460 [Bimetallic or trimetallic materials with structural metal centers based on Mn, Fe or V

    SciTech Connect (OSTI)

    Takeuchi, Esther Sans [Stony Brook University; Takeuchi, Kenneth James [Stony Brook University; Marschilok, Amy Catherine [Stony Brook University

    2013-07-26T23:59:59.000Z

    Bimetallic or trimetallic materials with structural metal centers based on Mn, Fe or V were investigated under this project. These metal centers are the focus of this research as they have high earth abundance and have each shown success as cathode materials in lithium batteries. Silver ion, Ag{sup +}, was initially selected as the displacement material as reduction of this center should result in increased conductivity as Ag{sup 0} metal particles are formed in-situ upon electrochemical reduction. The in-situ formation of metal nanoparticles upon electrochemical reduction has been previously noted, and more recently, we have investigated the resulting increase in conductivity. Layered materials as well as materials with tunnel or channel type structures were selected. Layered materials are of interest as they can provide 2-dimensional ion mobility. Tunnel or channel structures are also of interest as they provide a rigid framework that should remain stable over many discharge/charge cycles. We describe some examples of materials we have synthesized that demonstrate promising electrochemistry.

  7. Mixed hydrocarbon/fluoropolymer membrane/ionomer MEAs for durability studies

    SciTech Connect (OSTI)

    Li, Bo [Los Alamos National Laboratory; Kim, Yu Seung [Los Alamos National Laboratory; Mukundan, Rangachary [Los Alamos National Laboratory; Borup, Rodney L [Los Alamos National Laboratory; Wilson, Mahlon S [Los Alamos National Laboratory; Welch, Cynthia [Los Alamos National Laboratory; Fenton, James [FLORIDA SOLAR ENERGY CENTER

    2010-01-01T23:59:59.000Z

    The durability of polymer electrolyte membrane (PEM) fuel cells is a major barrier to the commercialization of these systems for stationary and transportation power applications. Commercial viability depends on improving the durability of the fuel cell components to increase the system reliability. The aim of this work is to separate ionomer degradation from membrane degradation via mixed membrane/ionomer MEA experiments. The challenges of mixed MEA fabrication due to the incompatibility of the membrane and the electrode are addressed. OCV accelerated testing experiment (AST) were performed. Development of in situ diagnostics and unique experiments to characterize the performance and properties of the ionomer in the electrode as a function of time is reported. These measurements, along with extensive ex situ and post-mortem characterization, can delineate the degradation mechanisms in order to develop more durable fuel cells and fuel cell components.

  8. Development of a Low-Cost, Durable Membrane and MEA for Stationary and Mobile Fuel Cell Applications

    SciTech Connect (OSTI)

    Michel Foure, Scott Gaboury, Jim Goldbach, David Mountz and Jung Yi (no longer with company)

    2008-01-31T23:59:59.000Z

    The development of low cost, durable membranes and membranes electrode assemblies (MEAs) remain a critical challenge for the successful introduction of fuel cells into mass markets. It was the goal of the team lead by Arkema, Inc. (formerly Atofina, Inc.) to address these shortages. Thus, this project addresses the following technical barriers from the Fuel Cells section of the Hydrogen Fuel Cells and Infrastructure Technologies Program Multi-Year Research, Development and Demonstration Plan: (A) Durability (B) Cost Arkema’s approach consisted in using blends of polyvinylidenefluoride (PVDF) and proprietary sulfonated polyelectrolytes. The strength and originality of Arkema’s approach lies in the decoupling of ion conductivity from the other requirements. Kynar® (Arkema trade name for PVDF) provides an exceptional combination of properties that make it ideally suited for a membrane matrix. In a first phase, Arkema demonstrated the feasibility of the concept with the M31 membrane generation. After MEA optimization, it was shown that the beginning-of-life (BOL) performance of M31 MEAs was essentially on a par with that of PFSA MEAs at 60ºC under fully humidified conditions. On the other hand, long-term durability studies showed a high decay rate of 45µV/h over a 2100 hr. test. Arkema then designed several families of polyelectrolyte candidates, which – in principle – could not undergo the same failure mechanisms. A new membrane candidate was developed: M41. It offered the same generally good mechanical, ex-situ conductivity and gas barrier properties as M31. In addition, ex-situ accelerated testing suggested a several orders of magnitude improvement in chemical stability. M41 based MEAs showed comparable BOL performance with that of PFSA (80ºC, 100% RH). M41 MEAs were further shown to be able to withstand several hours temperature excursions at 120ºC without apparent damage. Accelerated studies were carried out using the DOE and/or US Fuel Cell Council protocols. M41 MEAs shown sizeable advantages over PFSA MEAs in the Open Circuit Voltage Hold test, Relative Humidity Cycling test and the Voltage Cycling test. The main known limitation of the M41 family is its ability to function well at low RH.

  9. Method for the continuous processing of hermetic fiber optic components and the resultant fiber optic-to-metal components

    DOE Patents [OSTI]

    Kramer, D.P.

    1994-08-09T23:59:59.000Z

    Hermetic fiber optic-to-metal components and method for making hermetic fiber optic-to-metal components by assembling and fixturing elements comprising a metal shell, a glass preform, and a metal-coated fiber optic into desired relative positions and then sealing said fixtured elements preferably using a continuous heating process is disclosed. The resultant hermetic fiber optic-to-metal components exhibit high hermeticity and durability despite the large differences in thermal coefficients of expansion among the various elements. 3 figs.

  10. October 14 WA Division Newsletter Page 4 Tool durability and steel microstructure in friction stir welding of mild steel

    E-Print Network [OSTI]

    Cambridge, University of

    ) of aluminium alloys are cost effective and durable, whereas the much larger market for welding of steels for the welding of 7075 aluminium alloy. The results were presented as easy to use maps of "tool durability index- ium alloys has been applied to the FSW of steel. The calculations were extended to predict

  11. PHYSICAL REVIEW B 85, 045126 (2012) Toward an orbital-free density functional theory of transition metals based on

    E-Print Network [OSTI]

    Carter, Emily A.

    2012-01-01T23:59:59.000Z

    , Princeton, New Jersey 08544, USA Emily A. Carter Departments of Mechanical and Aerospace Engineering. However, OF-DFT Ag-Al alloy properties differ substantially from those predicted by KS-DFT using nonlocal is that when the system contains many different elements, such as in complex metal alloys, it becomes difficult

  12. Photon-pair source with controllable delay based on shaped inhomogeneous broadening of rare-earth-metal-doped solids

    SciTech Connect (OSTI)

    Sekatski, Pavel; Sangouard, Nicolas; Gisin, Nicolas; Afzelius, Mikael [Group of Applied Physics, University of Geneva, CH-1211 Geneva 4 (Switzerland); Riedmatten, Hugues de [Group of Applied Physics, University of Geneva, CH-1211 Geneva 4 (Switzerland); ICFO-Institute of Photonic Sciences, Mediterranean Technology Park, E-08860 Castelldefels (Barcelona) (Spain); ICREA-Institucio Catalana de Recerca i Estudis Avancats, E-08015 Barcelona (Spain)

    2011-05-15T23:59:59.000Z

    Spontaneous Raman emission in atomic gases provides an attractive source of photon pairs with a controllable delay. We show how this technique can be implemented in solid state systems by appropriately shaping the inhomogeneous broadening. Our proposal is eminently feasible with current technology and provides a realistic solution to entangle remote rare-earth-metal-doped solids in a heralded way.

  13. TECHNOLOGICAL IMPROVEMENTS OF A METAL OXIDE GAS MULTI-SENSOR BASED ON A MICRO-HOTPLATE STRUCTURE AND INKJET DEPOSI-

    E-Print Network [OSTI]

    (CO-100ppm, NO2-0.2ppm, NH3- 5ppm and C2H4O-2ppm). Keywords: Gas Sensors, Metal Oxides (MOX), Micro on the fact that the current/voltage characteristic of MOX films exhibits a non-linear behavior [7]. More presented here aims at presenting and characterizing an optimized MOX multi-sensor struc- ture developed

  14. Epsilon Metal Waste Form for Immobilization of Noble Metals from Used Nuclear Fuel

    SciTech Connect (OSTI)

    Crum, Jarrod V.; Strachan, Denis M.; Rohatgi, Aashish; Zumhoff, Mac R.

    2013-10-01T23:59:59.000Z

    Epsilon metal (?-metal), an alloy of Mo, Pd, Rh, Ru, and Tc, is being developed as a waste form to treat and immobilize the undissolved solids and dissolved noble metals from aqueous reprocessing of commercial used nuclear fuel. Epsilon metal is an attractive waste form for several reasons: increased durability relative to borosilicate glass, it can be fabricated without additives (100% waste loading), and in addition it also benefits borosilicate glass waste loading by eliminating noble metals from the glass and thus the processing problems related there insolubility in glass. This work focused on the processing aspects of the epsilon metal waste form development. Epsilon metal is comprised of refractory metals resulting in high reaction temperatures to form the alloy, expected to be 1500 - 2000°C making it a non-trivial phase to fabricate by traditional methods. Three commercially available advanced technologies were identified: spark-plasma sintering, microwave sintering, and hot isostatic pressing, and investigated as potential methods to fabricate this waste form. Results of these investigations are reported and compared in terms of bulk density, phase assemblage (X-ray diffraction and elemental analysis), and microstructure (scanning electron microscopy).

  15. In Patrick Matagne (dir.), Les effets du dveloppement durable : gouvernance, agriculture et consommation, entreprise, ducation, Paris, L'Harmattan, 2006, p.19-28.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    consommation, entreprise, éducation, Paris, L'Harmattan, 2006, p.19-28. Développement durable, gouvernance et

  16. Metal inks

    DOE Patents [OSTI]

    Ginley, David S; Curtis, Calvin J; Miedaner, Alex; van Hest, Marinus Franciscus Antonius Maria; Kaydanova, Tatiana

    2014-02-04T23:59:59.000Z

    Self-reducing metal inks and systems and methods for producing and using the same are disclosed. In an exemplary embodiment, a method may comprise selecting metal-organic (MO) precursor, selecting a reducing agent, and dissolving the MO precursor and the reducing agent in an organic solvent to produce a metal ink that remains in a liquid phase at room temperature. Metal inks, including self-reducing and fire-through metal inks, are also disclosed, as are various applications of the metal inks.

  17. L'agriculture durable, lment de stratgie pour le dveloppement rural communal Cas de la Commune d'Ampitatafika-District d'Antanifotsy-Rgion du Vakinankaratra

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    L'agriculture durable, élément de stratégie pour le développement rural communal Cas de la Commune,S., Ramananarivo, R., Aubert Gilon, S. ISDA 2010, Montpellier, June 28-30, 2010 L'AGRICULTURE DURABLE, ELEMENT DE "ISDA 2010, Montpellier : France (2010)" #12;L'agriculture durable, élément de stratégie pour le

  18. LONG TERM DURABILITY OF CARBON FRP COMPOSITES APPLIED TO RC BRIDGES

    E-Print Network [OSTI]

    Ring, Terry A.

    LONG TERM DURABILITY OF CARBON FRP COMPOSITES APPLIED TO RC BRIDGES: STATE STREET BRIDGE) composite system, used as a seismic retrofit of State Street Bridge on Interstate 80. Non types of CFRP composite test specimens, including CFRP composite tensile coupons, CFRP composite rings

  19. MOISTURE EFFECT ON DURABILITY OF AXIALLY LOADED CONCRETE-FILLED TUBULAR FRP PILES

    E-Print Network [OSTI]

    MOISTURE EFFECT ON DURABILITY OF AXIALLY LOADED CONCRETE-FILLED TUBULAR FRP PILES Miguel Pando, Ph_rizkalla@ncsu.edu ABSTRACT Fiber reinforced polymer (FRP) composite piles are a possible foundation alternative for projects located in harsh marine environments. Problems associated with traditional pile materials used in harsh

  20. Consequences of the ion beam irradiation on the chemical durability of Thorium Phosphate Diphosphate Kinetics study.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Consequences of the ion beam irradiation on the chemical durability of Thorium Phosphate of the long-term specific immobilization of actinides, Thorium Phosphate Diphosphate (-TPD), as potential-13], and thorium-actinide phosphate-diphosphate solid solutions (-Th4-xAnx(PO4)4P2O7) with associated -TPD

  1. Method and apparatus for increasing the durability and yield of thin film photovoltaic devices

    DOE Patents [OSTI]

    Phillips, James E. (Newark, DE); Lasswell, Patrick G. (Newark, DE)

    1987-01-01T23:59:59.000Z

    Thin film photovoltaic cells having a pair of semiconductor layers between an opaque and a transparent electrical contact are manufactured in a method which includes the step of scanning one of the semiconductor layers to determine the location of any possible shorting defect. Upon the detection of such defect, the defect is eliminated to increase the durability and yield of the photovoltaic device.

  2. Background: Subsurface Water Retention Technology (SWRT) Durable and easy to install: Water

    E-Print Network [OSTI]

    Background: Subsurface Water Retention Technology (SWRT) Benefits Durable and easy to install: Water retaining membranes can last at least 40 years and can be installed quickly and costeffectively permeable marginal soils converting them to much higher production levels of food crops. Better water

  3. GESTION DURABLE DES RISQUES D'AFFAISSEMENT MINIER : CHOIX DE STRATEGIES -CAS DE MOYEUVRE-GRANDE.

    E-Print Network [OSTI]

    Boyer, Edmond

    GESTION DURABLE DES RISQUES D'AFFAISSEMENT MINIER : CHOIX DE STRATEGIES - CAS DE MOYEUVRE abandonnées. La gestion des risques qui en découle peut se faire selon différentes stratégies et conduire à un application à l'étude du cas de la commune de Moyeuvre-Grande (57) à travers une analyse coûts

  4. MICRO-CAPTEURS POUR LA GESTION DURABLE DE LA QUALITE DES EAUX Namour Philippe1 *

    E-Print Network [OSTI]

    Boyer, Edmond

    1 MICRO-CAPTEURS POUR LA GESTION DURABLE DE LA QUALITE DES EAUX Namour Philippe1 * , Khadro Basma 2 gestion, de protection et de restauration des eaux de surface et des ressources souterraines des bassins gestion et d'interprétation de ces données. Toutefois actuellement ce nouveau type d'instrumentation ne

  5. Molecular Characterization of Durable Yellow and Leaf Rust Resistance in Two Wheat Populations

    E-Print Network [OSTI]

    Basnet, Bhoja

    2012-07-16T23:59:59.000Z

    , characterize and utilize Adult Plant Resistance (APR), a.k.a. slow rusting resistance, in wheat germplasm to promote durability of resistance against rust. The objectives of this study were to 1) understand the genetics of APR to YR and/or LR present in two...

  6. Solar Radiation Durability Framework Applied To Acrylic Solar Myles P. Murraya

    E-Print Network [OSTI]

    Rollins, Andrew M.

    Solar Radiation Durability Framework Applied To Acrylic Solar Mirrors Myles P. Murraya , Devin) when compared with traditional flat panel PV technologies. In MAPV systems electrical output per unit browning, and very rapid power degradation. Due in part to this failure, module manufactures may not honor

  7. Improving the mechanical stability of zirconium-based metal-organic frameworks by incorporation of acidic modulators

    E-Print Network [OSTI]

    Van de Voorde, Ben; Stassen, Ivo; Bueken, Bart; Vermoortele, Frederik; De Vos, Dirk; Ameloot, Rob; Tan, Jin-Chong; Bennett, Thomas D.

    2014-12-01T23:59:59.000Z

    capable of retaining their structure under harsh processing conditions. Introduction Metal-organic frameworks (MOFs) are microporous materials incorporating both organic and inorganic moieties connected in 20 a three-dimensional crystal lattice.1... trifluoroacetic acid to UiO-66 synthesis results in striking increases in physical stability under ball-milling, 75 despite generating more materials of almost identical porosity. In the case of the latter, TFA modulated framework, porosity is retained...

  8. Silicone metalization

    DOE Patents [OSTI]

    Maghribi, Mariam N. (Livermore, CA); Krulevitch, Peter (Pleasanton, CA); Hamilton, Julie (Tracy, CA)

    2008-12-09T23:59:59.000Z

    A system for providing metal features on silicone comprising providing a silicone layer on a matrix and providing a metal layer on the silicone layer. An electronic apparatus can be produced by the system. The electronic apparatus comprises a silicone body and metal features on the silicone body that provide an electronic device.

  9. Ammonia-treated phosphate glasses useful for sealing to metals

    DOE Patents [OSTI]

    Brow, R.K.; Day, D.E.

    1991-09-03T23:59:59.000Z

    A method of improving surface-dependent properties of phosphate glass such as durability and wear resistance without significantly affecting its thermal expansion coefficient is provided which comprises annealing the glass in a dry ammonia atmosphere at temperatures approximating the transition temperature of the glass. The ammonia annealing treatment of the present invention is carried out for a time sufficient to allow incorporation of a thin layer of nitrogen into the surface of the phosphate glass, and the treatment improves the durability of the glass without the reduction in the thermal expansion coefficient that has restricted the effectiveness of prior ammonia treatments. The improved phosphate glass resulting from this method is superior in wear resistance, yet maintains suitable thermal expansion properties so that it may be used effectively in a variety of applications requiring hermetic glass-metal seals.

  10. Metal-ceramic joint assembly

    DOE Patents [OSTI]

    Li, Jian (New Milford, CT)

    2002-01-01T23:59:59.000Z

    A metal-ceramic joint assembly in which a brazing alloy is situated between metallic and ceramic members. The metallic member is either an aluminum-containing stainless steel, a high chromium-content ferritic stainless steel or an iron nickel alloy with a corrosion protection coating. The brazing alloy, in turn, is either an Au-based or Ni-based alloy with a brazing temperature in the range of 9500 to 1200.degree. C.

  11. Hydrothermal alkali metal recovery process

    DOE Patents [OSTI]

    Wolfs, Denise Y. (Houston, TX); Clavenna, Le Roy R. (Baytown, TX); Eakman, James M. (Houston, TX); Kalina, Theodore (Morris Plains, NJ)

    1980-01-01T23:59:59.000Z

    In a coal gasification operation or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein solid particles containing alkali metal residues are produced, alkali metal constituents are recovered from the particles by treating them with a calcium or magnesium-containing compound in the presence of water at a temperature between about 250.degree. F. and about 700.degree. F. and in the presence of an added base to establish a pH during the treatment step that is higher than would otherwise be possible without the addition of the base. During the treating process the relatively high pH facilitates the conversion of water-insoluble alkali metal compounds in the alkali metal residues into water-soluble alkali metal constituents. The resultant aqueous solution containing water-soluble alkali metal constituents is then separated from the residue solids, which consist of the treated particles and any insoluble materials formed during the treatment step, and recycled to the gasification process where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst. Preferably, the base that is added during the treatment step is an alkali metal hydroxide obtained by water washing the residue solids produced during the treatment step.

  12. Novel Metal-Sulfur-Based Air-Stable Passivation of GaAs with Very Low Surface State Densities

    SciTech Connect (OSTI)

    Ashby, Carol I.H.; Baca, Albert G.; Chang, P.-C; Hafich, M.J.; Hammons, B.E.; Zavadil, Kevin R.

    1999-08-09T23:59:59.000Z

    A new air-stable electronic surface passivation for GaAs and other III-V compound semiconductors that employs sulfur and a suitable metal ion, e.g., Zn, and that is robust towards plasma dielectric deposition has been developed. Initial improvements in photoluminescence are twice that of S-only treatments and have been preserved for >11 months with SiO{sub x}N{sub y} dielectric encapsulation. Photoluminescence and X-ray photoelectron spectroscopies indicate that the passivation consists of two major components with one being stable for >2 years in air. This process improves heterojunction bipolar transistor current gain for both large and small area devices.

  13. Fundamental Studies of the Durability of Materials for Interconnects in Solid Oxide Fuel Cells

    SciTech Connect (OSTI)

    Frederick S. Pettit; Gerald H. Meier

    2006-06-30T23:59:59.000Z

    Ferritic stainless steels are a leading candidate material for use as an SOFC interconnect, but have the problem of forming volatile chromia species that lead to cathode poisoning. This project has focused both on optimization of ferritic alloys for SOFC applications and evaluating the possibility of using alternative materials. The initial efforts involved studying the oxidation behavior of a variety of chromia-forming ferritic stainless steels in the temperature range 700-900 C in atmospheres relevant to solid oxide fuel cell operation. The alloys exhibited a wide variety of oxidation behavior based on composition. A method for reducing the vaporization is to add alloying elements that lead to the formation of a thermally grown oxide layer over the protective chromia. Several commercial steels form manganese chromate on the surface. This same approach, combined with observations of TiO{sub 2} overlayer formation on the chromia forming, Ni-based superalloy IN 738, has resulted in the development of a series of Fe-22 Cr-X Ti alloys (X=0-4 wt%). Oxidation testing has indicated that this approach results in significant reduction in chromia evaporation. Unfortunately, the Ti also results in accelerated chromia scale growth. Fundamental thermo-mechanical aspects of the durability of solid oxide fuel cell (SOFC) interconnect alloys have also been investigated. A key failure mechanism for interconnects is the spallation of the chromia scale that forms on the alloy, as it is exposed to fuel cell environments. Indentation testing methods to measure the critical energy release rate (Gc) associated with the spallation of chromia scale/alloy systems have been evaluated. This approach has been used to evaluate the thermomechanical stability of chromia films as a function of oxidation exposure. The oxidation of pure nickel in SOFC environments was evaluated using thermogravimetric analysis (TGA) to determine the NiO scaling kinetics and a four-point probe was used to measure the area-specific resistance (ASR) to estimate the electrical degradation of the interconnect. In addition to the baseline study of pure nickel, steps were taken to decrease the ASR through alloying and surface modifications. Finally, high conductivity composite systems, consisting of nickel and silver, were studied. These systems utilize high conductivity silver pathways through nickel while maintaining the mechanical stability that a nickel matrix provides.

  14. ESTABLISHING SUSTAINABLE US HEV/PHEV MANUFACTURING BASE: STABILIZED LITHIUM METAL POWDER, ENABLING MATERIAL AND REVOLUTIONARY TECHNOLOGY FOR HIGH ENERGY LI-ION BATTERIES

    SciTech Connect (OSTI)

    Yakovleva, Marina

    2012-12-31T23:59:59.000Z

    FMC Lithium Division has successfully completed the project “Establishing Sustainable US PHEV/EV Manufacturing Base: Stabilized Lithium Metal Powder, Enabling Material and Revolutionary Technology for High Energy Li-ion Batteries”. The project included design, acquisition and process development for the production scale units to 1) produce stabilized lithium dispersions in oil medium, 2) to produce dry stabilized lithium metal powders, 3) to evaluate, design and acquire pilot-scale unit for alternative production technology to further decrease the cost, and 4) to demonstrate concepts for integrating SLMP technology into the Li- ion batteries to increase energy density. It is very difficult to satisfy safety, cost and performance requirements for the PHEV and EV applications. As the initial step in SLMP Technology introduction, industry can use commercially available LiMn2O4 or LiFePO4, for example, that are the only proven safer and cheaper lithium providing cathodes available on the market. Unfortunately, these cathodes alone are inferior to the energy density of the conventional LiCoO2 cathode and, even when paired with the advanced anode materials, such as silicon composite material, the resulting cell will still not meet the energy density requirements. We have demonstrated, however, if SLMP Technology is used to compensate for the irreversible capacity in the anode, the efficiency of the cathode utilization will be improved and the cost of the cell, based on the materials, will decrease.

  15. An Insulating Glass Knowledge Base

    SciTech Connect (OSTI)

    Michael L. Doll; Gerald Hendrickson; Gerard Lagos; Russell Pylkki; Chris Christensen; Charlie Cureija

    2005-08-01T23:59:59.000Z

    This report will discuss issues relevant to Insulating Glass (IG) durability performance by presenting the observations and developed conclusions in a logical sequential format. This concluding effort discusses Phase II activities and focuses on beginning to quantifying IG durability issues while continuing the approach presented in the Phase I activities (Appendix 1) which discuss a qualitative assessment of durability issues. Phase II developed a focus around two specific IG design classes previously presented in Phase I of this project. The typical box spacer and thermoplastic spacer design including their Failure Modes and Effect Analysis (FMEA) and Fault Tree diagrams were chosen to address two currently used IG design options with varying components and failure modes. The system failures occur due to failures of components or their interfaces. Efforts to begin quantifying the durability issues focused on the development and delivery of an included computer based IG durability simulation program. The focus/effort to deliver the foundation for a comprehensive IG durability simulation tool is necessary to address advancements needed to meet current and future building envelope energy performance goals. This need is based upon the current lack of IG field failure data and the lengthy field observation time necessary for this data collection. Ultimately, the simulation program is intended to be used by designers throughout the current and future industry supply chain. Its use is intended to advance IG durability as expectations grow around energy conservation and with the growth of embedded technologies as required to meet energy needs. In addition the tool has the immediate benefit of providing insight for research and improvement prioritization. Included in the simulation model presentation are elements and/or methods to address IG materials, design, process, quality, induced stress (environmental and other factors), validation, etc. In addition, acquired data is presented in support of project and model assumptions. Finally, current and suggested testing protocol and procedure for future model validation and IG physical testing are discussed.

  16. Vehicle Technologies Office Merit Review 2014: Durability of Diesel Particulate Filters (Agreement ID:10461) Project ID:18519

    Broader source: Energy.gov [DOE]

    Presentation given by Oak Ridge National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about durability of...

  17. Durable regenerable sorbent pellets for removal of hydrogen sulfide from coal gas

    DOE Patents [OSTI]

    Siriwardane, Ranjani V. (Morgantown, WV)

    1997-01-01T23:59:59.000Z

    Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

  18. Durable regenerable sorbent pellets for removal of hydrogen sulfide from coal gas

    DOE Patents [OSTI]

    Siriwardane, R.V.

    1997-12-30T23:59:59.000Z

    Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

  19. Durable regenerable sorbent pellets for removal of hydrogen sulfide from coal gas

    DOE Patents [OSTI]

    Siriwardane, R.V.

    1999-02-02T23:59:59.000Z

    Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form, usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

  20. Durable regenerable sorbent pellets for removal of hydrogen sulfide coal gas

    DOE Patents [OSTI]

    Siriwardane, Ranjani V. (Morgantown, WV)

    1999-01-01T23:59:59.000Z

    Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form, usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

  1. High-Performance Corrosion-Resistant Iron-Based Amorphous Metals: The Effects of Composition, Structure and Environment on Corrosion Resistance

    SciTech Connect (OSTI)

    Farmer, J; Choi, J S; Haslam, J; Lian, T; Day, S; Yang, N; Blue, C; Peters, W; Bayles, R; Lewandowski, J; Perepezko, J; Hildal, K; Lavernia, E; Ajdelsztajn, A; Grave, O; Aprigliano, L; Kaufman, L; Boudreau, J; Branagan, D J; Beardsley, B

    2006-04-11T23:59:59.000Z

    New corrosion-resistant, iron-based amorphous metals have been identified from published data or developed through combinatorial synthesis, and tested to determine their relative thermal phase stability, microstructure, mechanical properties, damage tolerance, and corrosion resistance. Some alloy additions are known to promote glass formation and to lower the critical cooling rate [F. Guo, S. J. Poon, Applied Physics Letters, 83 (13) 2575-2577, 2003]. Other elements are known to enhance the corrosion resistance of conventional stainless steels and nickel-based alloys [A. I. Asphahani, Materials Performance, Vol. 19, No. 12, pp. 33-43, 1980] and have been found to provide similar benefits to iron-based amorphous metals. Many of these materials can be cast as relatively thick ingots, or applied as coatings with advanced thermal spray technology. A wide variety of thermal spray processes have been developed by industry, and can be used to apply these new materials as coatings. Any of these can be used for the deposition of the formulations discussed here, with varying degrees of residual porosity and crystalline structure. Thick protective coatings have now been made that are fully dense and completely amorphous in the as-sprayed condition. An overview of the High-Performance Corrosion Resistant Materials (HPCRM) Project will be given, with particular emphasis on the corrosion resistance of several different types of iron-based amorphous metals in various environments of interest. The salt fog test has been used to compare the performance of various wrought alloys, melt-spun ribbons, arc-melted drop-cast ingots, and thermal-spray coatings for their susceptibility to corrosion in marine environments. Electrochemical tests have also been performed in seawater. Spontaneous breakdown of the passive film and localized corrosion require that the open-circuit corrosion potential exceed the critical potential. The resistance to localized corrosion is seawater has been quantified through measurement of the open-circuit corrosion potential (E{sub corr}), the breakdown potential (E{sub crit}) and the repassivation potential (E{sub rp}). The greater the difference between the open-circuit corrosion potential and the repassivation potential ({Delta}E), the more resistant a material is to modes of localized corrosion such as pitting and crevice corrosion. Cyclic polarization (CP) was used as a means of measuring the critical potential (E{sub crit}) relative to the open-circuit corrosion potential (E{sub corr}). Linear polarization (LP) has been used to determine the corrosion current (i{sub corr}) and the corresponding corrosion rate. Other aspects of the materials will also be discussed, as well as potential applications.

  2. Effect of geometrical constraint condition on the formation of nanoscale twins in the Ni-based metallic glass composite

    SciTech Connect (OSTI)

    Lee, M.H.; Kim, B.S.; Kim, D.H.; Ott, R.T.; Sansoz, F.; Eckert, J.

    2014-04-25T23:59:59.000Z

    We investigated the effect of geometrically constrained stress-strain conditions on the formation of nanotwins in alpha-brass phase reinforced Ni59Zr20Ti16Si2Sn3 metallic glass (MG) matrix deformed under macroscopic uniaxial compression. The specific geometrically constrained conditions in the samples lead to a deviation from a simple uniaxial state to a multi-axial stress state, for which nanocrystallization in the MG matrix together with nanoscale twinning of the brass reinforcement is observed in localized regions during plastic flow. The nanocrystals in the MG matrix and the appearance of the twinned structure in the reinforcements indicate that the strain energy is highly confined and the local stress reaches a very high level upon yielding. Both the effective distribution of reinforcements on the strain enhancement of composite and the effects of the complicated stress states on the development of nanotwins in the second-phase brass particles are discussed.

  3. Method and apparatus for increasing the durability and yield of thin film photovoltaic devices

    DOE Patents [OSTI]

    Phillips, J.E.; Lasswell, P.G.

    1987-02-03T23:59:59.000Z

    Thin film photovoltaic cells having a pair of semiconductor layers between an opaque and a transparent electrical contact are manufactured in a method which includes the step of scanning one of the semiconductor layers to determine the location of any possible shorting defect. Upon the detection of such defect, the defect is eliminated to increase the durability and yield of the photovoltaic device. 10 figs.

  4. Method of immobilizing weapons plutonium to provide a durable, disposable waste product

    DOE Patents [OSTI]

    Ewing, Rodney C. (Albuquerque, NM); Lutze, Werner (Albuquerque, NM); Weber, William J. (Richland, WA)

    1996-01-01T23:59:59.000Z

    A method of atomic scale fixation and immobilization of plutonium to provide a durable waste product. Plutonium is provided in the form of either PuO.sub.2 or Pu(NO.sub.3).sub.4 and is mixed with and SiO.sub.2. The resulting mixture is cold pressed and then heated under pressure to form (Zr,Pu)SiO.sub.4 as the waste product.

  5. Volvo Penta 4.3 GL E15 Emissions and Durability Test

    SciTech Connect (OSTI)

    Zoubul, G.; Cahoon, M.; Kolb, R.

    2011-10-01T23:59:59.000Z

    A new Volvo Penta carbureted 4.3 GL engine underwent emissions and dynamometer durability testing from break-in to expected end of life using an accelerated ICOMIA marine emissions cycle and E15 fuel. Only ethanol content was controlled. All aging used splash-blended E15 fuel. Exhaust emissions, exhaust gas temperature, torque, power, barometric pressure, air temperature, and fuel flow were measured at five intervals using site-blended E15 aging fuel and certification fuel (E0). The durability test cycle showed no noticeable impact on mechanical durability or engine power. Emissions performance degraded beyond the certification limit for this engine family, mostly occurring by 28% of expected life. Such degradation is inconsistent with prior experience. Comparisons showed that E15 resulted in lower CO and HC, but increased NOX, as expected for non-feedback-controlled carbureted engines with increased oxygen in the fuel. Fuel consumption also increased with E15 compared with E0. Throughout testing, poor starting characteristics were exhibited on E15 fuel for hot re-start and cold-start. Cranking time to start and smooth idle was roughly doubled compared with typical E0 operation. The carburetor was factory-set for lean operation to ensure emissions compliance. Test protocols did not include carburetor adjustment to account for increased oxygen in the E15 fuel.

  6. Primer on Durability of Nuclear Power Plant Reinforced Concrete Structures - A Review of Pertinent Factors

    SciTech Connect (OSTI)

    Naus, Dan J [ORNL

    2007-02-01T23:59:59.000Z

    The objective of this study was to provide a primer on the environmental effects that can affect the durability of nuclear power plant concrete structures. As concrete ages, changes in its properties will occur as a result of continuing microstructural changes (i.e., slow hydration, crystallization of amorphous constituents, and reactions between cement paste and aggregates), as well as environmental influences. These changes do not have to be detrimental to the point that concrete will not be able to meet its performance requirements. Concrete, however, can suffer undesirable changes with time because of improper specifications, a violation of specifications, or adverse performance of its cement paste matrix or aggregate constituents under either physical or chemical attack. Contained in this report is a discussion on concrete durability and the relationship between durability and performance, a review of the historical perspective related to concrete and longevity, a description of the basic materials that comprise reinforced concrete, and information on the environmental factors that can affect the performance of nuclear power plant concrete structures. Commentary is provided on the importance of an aging management program.

  7. NEPHELINE FORMATION POTENTIAL IN SLUDGE BATCH 4 AND ITS IMPACT ON DURABILITY: SELECTING GLASSES FOR A PHASE 3 STUDY

    SciTech Connect (OSTI)

    Fox, K

    2006-01-27T23:59:59.000Z

    Savannah River National Laboratory's frit development effort for SB4 is being driven by the most current CBU option for this sludge, referred to as Case 15C Blend 1. Candidate frits have been identified for this option via a paper study approach developed by Peeler and Edwards with the intent of down-selecting to a set of key frits whose operating windows (i.e., WL intervals that meet PCCS MAR criteria) are robust to and/or selectively optimal for this sludge option. The primary frits that appear attractive on paper (i.e., down-selected via the paper study) are now being incorporated into this experimental study. The potential for the formation of a nepheline primary crystalline phase is an important factor in frit development for SB4, due to the high Al{sub 2}O{sub 3} content of this sludge. Based upon earlier work by Li et al., glasses that do not satisfy the constraint: (SiO{sub 2}/SiO{sub 2} + Na{sub 2}O + Al{sub 2}O{sub 3}) > 0.62 where the oxides are expressed as mass fractions in the glass, will precipitate nepheline as their primary crystalline phase, hindering the durability of the glass. Based on the most recent compositional projection from the CBU for SB4 (Case 15C Blend 1), 16 glasses have been selected to complement the earlier work by continuing the investigation into the ability of the above constraint to predict the occurrence of a nepheline primary crystalline phase for SB4 glasses and into the impact of such phases on the durability of the SB4 glasses. Glasses were selected to cover WLs which tightly bound the nepheline discriminator value of 0.62, with the intent of refining this value to a level of confidence where it can be incorporated into offline administrative controls and/or the PCCS to support SME acceptability decisions. In addition, glass specimens at WLs of 35 and 40% will be prepared and analyzed to contribute needed data to the ComPro{trademark} database in anticipation of a variability study for SB4. The glasses in Table 4-3 are to batched and fabricated using standard procedures. Visual observations and other analytical techniques are to be used, as needed, to assess the presence of crystals with specific interest in the nepheline primary phase. The durability of these glasses (for both quenched and centerline canister cooled versions) is to be measured using the ASTM PCT Method A. The results from these efforts are to be documented in a subsequent report. The results of this study will provide valuable input for the frit development efforts and subsequent feedback to the CBU regarding the relative viability of the current SB4 option under consideration. The refined nepheline discriminator value will provide a guideline for the avoidance of nepheline crystallization in SB4 glasses and aid in down-selection of frit compositions. These data will be combined with the results of melt rate studies and a paper study of the frits robustness with regard to variability in the sludge composition to provide an optimized frit recommendation to DWPF for immobilization of SB4.

  8. Toward Photochemical Water Splitting Using Band-Gap-Narrowed Semiconductors and Transition-Metal Based Molecular Catalysts

    SciTech Connect (OSTI)

    Muckerman,J.T.; Rodriguez, J.A.; Fujita, E.

    2009-06-07T23:59:59.000Z

    We are carrying out coordinated theoretical and experimental studies of toward photochemical water splitting using band-gap-narrowed semiconductors (BGNSCs) with attached multi-electron molecular water oxidation and hydrogen production catalysts. We focus on the coupling between the materials properties and the H{sub 2}O redox chemistry, with an emphasis on attaining a fundamental understanding of the individual elementary steps in the following four processes: (1) Light-harvesting and charge-separation of stable oxide or oxide-derived semiconductors for solar-driven water splitting, including the discovery and characterization of the behavior of such materials at the aqueous interface; (2) The catalysis of the four-electron water oxidation by dinuclear hydroxo transition-metal complexes with quinonoid ligands, and the rational search for improved catalysts; (3) Transfer of the design principles learned from the elucidation of the DuBois-type hydrogenase model catalysts in acetonitrile to the rational design of two-electron hydrogen production catalysts for aqueous solution; (4) Combining these three elements to examine the function of oxidation catalysts on BGNSC photoanode surfaces and hydrogen production catalysts on cathode surfaces at the aqueous interface to understand the challenges to the efficient coupling of the materials functions.

  9. Structure, magnetic and electronic properties of new 1111-type and 42622-type transition metal-based oxyarsenides 

    E-Print Network [OSTI]

    Kasperkiewicz, Karolina

    2014-06-28T23:59:59.000Z

    Discovery of high-temperature superconductors aroused a great interest in studies on these materials. In 1987 an yttrium-based compound YBCO (Yttrium-Barium- Copper-Oxide) was synthesised with Tc at 93 K. It was immediately ...

  10. HIGHWAY INFRASTRUCTURE FOCUS AREA NEXT-GENERATION INFRASTRUCTURE MATERIALS VOLUME I - TECHNICAL PROPOSAL & MANAGEMENTENHANCEMENT OF TRANSPORTATION INFRASTRUCTURE WITH IRON-BASED AMORPHOUS-METAL AND CERAMIC COATINGS

    SciTech Connect (OSTI)

    Farmer, J C

    2007-12-04T23:59:59.000Z

    The infrastructure for transportation in the United States allows for a high level of mobility and freight activity for the current population of 300 million residents, and several million business establishments. According to a Department of Transportation study, more than 230 million motor vehicles, ships, airplanes, and railroads cars were used on 6.4 million kilometers (4 million miles) of highways, railroads, airports, and waterways in 1998. Pipelines and storage tanks were considered to be part of this deteriorating infrastructure. The annual direct cost of corrosion in the infrastructure category was estimated to be approximately $22.6 billion in 1998. There were 583,000 bridges in the United States in 1998. Of this total, 200,000 bridges were steel, 235,000 were conventional reinforced concrete, 108,000 bridges were constructed using pre-stressed concrete, and the balance was made using other materials of construction. Approximately 15 percent of the bridges accounted for at this point in time were structurally deficient, primarily due to corrosion of steel and steel reinforcement. Iron-based amorphous metals, including SAM2X5 (Fe{sub 49.7}Cr{sub 17.7}Mn{sub 1.9}Mo{sub 7.4}W{sub 1.6}B{sub 15.2}C{sub 3.8}Si{sub 2.4}) and SAM1651 (Fe{sub 48}Mo{sub 14}Cr{sub 15}Y{sub 2}C{sub 15}B{sub 6}) have been developed, and have very good corrosion resistance. These materials have been prepared as a melt-spun ribbons, as well as gas atomized powders and thermal-spray coatings. During electrochemical testing in several environments, including seawater at 90 C, the passive film stabilities of these materials were found to be comparable to that of more expensive high-performance alloys, based on electrochemical measurements of the passive film breakdown potential and general corrosion rates. These materials also performed very well in standard salt fog tests. Chromium (Cr), molybdenum (Mo) and tungsten (W) provided corrosion resistance, and boron (B) enabled glass formation. The high boron content of this particular amorphous metal made it an effective neutron absorber, and suitable for criticality control applications. These amorphous alloys appear to maintain their corrosion resistance up to the glass transition temperature. Visionary research is proposed to extend the application of corrosion-resistant iron-based amorphous metal coatings, and variants of these coatings, to protection of the Nation's transportation infrastructure. Specific objectives of the proposed work are: (1) fabrication of appropriate test samples for evaluation of concept; (2) collection of production and test data for coated steel reinforcement bars, enabling systematic comparison of various coating options, based upon performance and economic considerations; and (3) construction and testing of concrete structures with coated steel reinforcement bars, thereby demonstrating the value of amorphous-metal coatings. The benefits of ceramic coatings as thermal barriers will also be addressed.

  11. Metal oxide films on metal

    DOE Patents [OSTI]

    Wu, Xin D. (Los Alamos, NM); Tiwari, Prabhat (Los Alamos, NM)

    1995-01-01T23:59:59.000Z

    A structure including a thin film of a conductive alkaline earth metal oxide selected from the group consisting of strontium ruthenium trioxide, calcium ruthenium trioxide, barium ruthenium trioxide, lanthanum-strontium cobalt oxide or mixed alkaline earth ruthenium trioxides thereof upon a thin film of a noble metal such as platinum is provided.

  12. Variable tunneling barriers in FEBID based PtC metal-matrix nanocomposites as a transducing element for humidity sensing

    E-Print Network [OSTI]

    such as high temperatures or special environments. In this study we demonstrate a new gas sensing concept based special reformation conditions after detection events, whereas non-polar species (O2, CO2, N2) produce the particles, which governs the final conductivity. The specific change of these dielectric properties

  13. A MEMS-enabled 3D zincair microbattery with improved discharge characteristics based on a multilayer metallic substructure

    E-Print Network [OSTI]

    , zinc­air batteries are good candidates for the previously mentioned miniaturized applications. Commercially available zinc­air batteries utilize Zn powder for the anode electrode, achieving high surfaceA MEMS-enabled 3D zinc­air microbattery with improved discharge characteristics based

  14. Metals 2000

    SciTech Connect (OSTI)

    Allison, S.W.; Rogers, L.C.; Slaughter, G. [Oak Ridge National Lab., TN (United States); Boensch, F.D. [6025 Oak Hill Lane, Centerville, OH (United States); Claus, R.O.; de Vries, M. [Virginia Polytechnic Inst. and State Univ., Blacksburg, VA (United States)

    1993-05-01T23:59:59.000Z

    This strategic planning exercise identified and characterized new and emerging advanced metallic technologies in the context of the drastic changes in global politics and decreasing fiscal resources. In consideration of a hierarchy of technology thrusts stated by various Department of Defense (DOD) spokesmen, and the need to find new and creative ways to acquire and organize programs within an evolving Wright Laboratory, five major candidate programs identified are: C-17 Flap, Transport Fuselage, Mach 5 Aircraft, 4.Fighter Structures, and 5. Missile Structures. These results were formed by extensive discussion with selected major contractors and other experts, and a survey of advanced metallic structure materials. Candidate structural applications with detailed metal structure descriptions bracket a wide variety of uses which warrant consideration for the suggested programs. An analysis on implementing smart skins and structures concepts is given from a metal structures perspective.

  15. Dendritic metal nanostructures

    DOE Patents [OSTI]

    Shelnutt, John A. (Tijeras, NM); Song, Yujiang (Albuquerque, NM); Pereira, Eulalia F. (Vila Nova de Gaia, PT); Medforth, Craig J. (Winters, CA)

    2010-08-31T23:59:59.000Z

    Dendritic metal nanostructures made using a surfactant structure template, a metal salt, and electron donor species.

  16. An Innovative Technique for Evaluating the Integrity and Durability of Wind Turbine Blade Composites

    SciTech Connect (OSTI)

    Wang, Jy-An John [ORNL; Ren, Fei [ORNL

    2010-09-01T23:59:59.000Z

    Wind turbine blades are subjected to complex multiaxial stress states during operation. A review of the literature suggests that mixed mode fracture toughness can be significantly less than that of the tensile opening mode (Mode I), implying that fracture failure can occur at a much lower load capacity if the structure is subject to mixed-mode loading. Thus, it will be necessary to identify the mechanisms that might lead to failure in blade materials under mixed-mode loading conditions. Meanwhile, wind turbine blades are typically fabricated from fiber reinforced polymeric materials, e.g. fiber glass composites. Due to the large degree of anisotropy in mechanical properties that is usually associated with laminates, the fracture behavior of these composite materials is likely to be strongly dependent on the loading conditions. This may further strengthen the need to study the effect of mixed-mode loading on the integrity and durability of the wind turbine blade composites. To quantify the fracture behavior of composite structures under mixed mode loading conditions, particularly under combined Mode I (flexural or normal tensile stress) and Mode III (torsional shear stress) loading, a new testing technique is proposed based on the spiral notch torsion test (SNTT). As a 2002 R&D 100 Award winner, SNTT is a novel fracture testing technology. SNTT has many advantages over conventional fracture toughness methods and has been used to determine fracture toughness values on a wide spectrum of materials. The current project is the first attempt to utilize SNTT on polymeric and polymer-based composite materials. It is expected that mixed-mode failure mechanisms of wind turbine blades induced by typical in-service loading conditions, such as delamination, matrix cracking, fiber pull-out and fracture, can be effectively and economically investigated by using this methodology. This project consists of two phases. The Phase I (FY2010) effort includes (1) preparation of testing material and testing equipment set-up, including calibration of associated instruments/sensors, (2) development of design protocols for the proposed SNTT samples for both polymer and composite materials, such as sample geometries and fabrication techniques, (3) manufacture of SNTT samples, and (4) fracture toughness testing using the SNTT method. The major milestone achieved in Phase I is the understanding of fracture behaviors of polymeric matrix materials from testing numerous epoxy SNTT samples. Totals of 30 epoxy SNTT samples were fabricated from two types of epoxy materials provided by our industrial partners Gougeon Brothers, Inc. and Molded Fiber Glass Companies. These samples were tested with SNTT in three groups: (1) fracture due to monotonic loading, (2) fracture due to fatigue cyclic loading, and (3) monotonic loading applied to fatigue-precracked samples. Brittle fractures were observed on all tested samples, implying linear elastic fracture mechanics analysis can be effectively used to estimate the fracture toughness of these materials with confidence. Appropriate fatigue precracking protocols were established to achieve controllable crack growth using the SNTT approach under pure torsion loading. These fatigue protocols provide the significant insights of the mechanical behavior of epoxy polymeric materials and their associated rate-dependent characteristics. Effects of mixed-mode loading on the fracture behavior of epoxy materials was studied. It was found that all epoxy samples failed in brittle tensile failure mode; the fracture surfaces always follow a 45o spiral plane that corresponded to Mode I tensile failure, even when the initial pitch angle of the machined spiral grooves was not at 45o. In addition, general observation from the fatigue experiments implied that loading rate played an important role determining the fracture behavior of epoxy materials, such that a higher loading rate resulted in a shorter fatigue life. A detailed study of loading rate effect will be continued in the Phase II. On the other hand, analytical finite element ana

  17. Building, Testing, and Post Test Analysis of Durability Heat Pipe No.6

    SciTech Connect (OSTI)

    MOSS, TIMOTHY A.

    2002-03-01T23:59:59.000Z

    The Solar Thermal Program at Sandia supports work developing dish/Stirling systems to convert solar energy into electricity. Heat pipe technology is ideal for transferring the energy of concentrated sunlight from the parabolic dish concentrators to the Stirling engine heat tubes. Heat pipes can absorb the solar energy at non-uniform flux distributions and release this energy to the Stirling engine heater tubes at a very uniform flux distribution thus decoupling the design of the engine heater head from the solar absorber. The most important part of a heat pipe is the wick, which transports the sodium over the heated surface area. Bench scale heat pipes were designed and built to more economically, both in time and money, test different wicks and cleaning procedures. This report covers the building, testing, and post-test analysis of the sixth in a series of bench scale heat pipes. Durability heat pipe No.6 was built and tested to determine the effects of a high temperature bakeout, 950 C, on wick corrosion during long-term operation. Previous tests showed high levels of corrosion with low temperature bakeouts (650-700 C). Durability heat pipe No.5 had a high temperature bakeout and reflux cleaning and showed low levels of wick corrosion after long-term operation. After testing durability heat pipe No.6 for 5,003 hours at an operating temperature of 750 C, it showed low levels of wick corrosion. This test shows a high temperature bakeout alone will significantly reduce wick corrosion without the need for costly and time consuming reflux cleaning.

  18. Supported molten-metal catalysts

    DOE Patents [OSTI]

    Datta, Ravindra (Iowa City, IA); Singh, Ajeet (Iowa City, IA); Halasz, Istvan (Iowa City, IA); Serban, Manuela (Iowa City, IA)

    2001-01-01T23:59:59.000Z

    An entirely new class of catalysts called supported molten-metal catalysts, SMMC, which can replace some of the existing precious metal catalysts used in the production of fuels, commodity chemicals, and fine chemicals, as well as in combating pollution. SMMC are based on supporting ultra-thin films or micro-droplets of the relatively low-melting (<600.degree. C.), inexpensive, and abundant metals and semimetals from groups 1, 12, 13, 14, 15 and 16, of the periodic table, or their alloys and intermetallic compounds, on porous refractory supports, much like supported microcrystallites of the traditional solid metal catalysts. It thus provides orders of magnitude higher surface area than is obtainable in conventional reactors containing molten metals in pool form and also avoids corrosion. These have so far been the chief stumbling blocks in the application of molten metal catalysts.

  19. Overview of ORNL/NRC programs addressing durability of concrete structures

    SciTech Connect (OSTI)

    Naus, D.J.; Oland, C.B.

    1994-06-01T23:59:59.000Z

    The role of reinforced concrete relative to its applications as either safety-related structures in nuclear power or engineered barriers of low-level radioactive waste disposal facilities is described. Factors that can affect the long-term durability of reinforced concrete are identified. Overviews are presented of the Structural Aging Program, which is addressing the aging management of safety-related concrete structures in nuclear power plants, and the Permeability Test Methods and Data Program, which is identifying pertinent data and information for use in performance assessments of engineered barriers for low-level radioactive waste disposal.

  20. Technical Note: Updated durability/composition relationships for Hanford high-level waste glasses

    SciTech Connect (OSTI)

    Piepel, G.F.; Hartley, S.A.; Redgate, P.E.

    1996-03-01T23:59:59.000Z

    This technical note presents empirical models developed in FYI 995 to predict durability as functions of glass composition. Models are presented for normalized releases of B, Li, Na, and Si from the 7-day Product Consistency Test (PCT) applied to quenched and canister centerline cooled (CCC) glasses as well as from the 28-day Materials Characterization Center-1 (MCC-1) test applied to quenched glasses. Models are presented for Composition Variation Study (CVS) data from low temperature melter (LTM) studies (Hrma, Piepel, et al. 1994) and high temperature melter (HTM) studies (Vienna et al. 1995). The data used for modeling in this technical note are listed in Appendix A.

  1. Reliability-Based Design Optimization for Durability of Ground Vehicle Suspension System Components

    E-Print Network [OSTI]

    Grujicic, Mica

    structures infused with impact resistant epoxy polymer systems) as well as in the integration of multifunc

  2. Interfacial analysis of the ex-situ reinforced phase of a laser spot welded Zr-based bulk metallic glass composite

    SciTech Connect (OSTI)

    Wang, Huei-Sen, E-mail: huei@isu.edu.tw [Department of Materials Science and Engineering, I-Shou University, Kaohsiung, 84001, Taiwan (China); Department of Chemical and Materials Engineering, National University of Kaohsiung, 81148, Kaohsiung, Taiwan (China); Chen, Hou-Guang [Department of Materials Science and Engineering, I-Shou University, Kaohsiung, 84001, Taiwan (China); Jang, Jason Shian-Ching [Institute of Materials Science and Engineering and Department of Mechanical Engineering, National Central University, Chung-Li 32001, Taiwan (China); Lin, Dong-Yih [Department of Chemical and Materials Engineering, National University of Kaohsiung, 81148, Kaohsiung, Taiwan (China); Gu, Jhen-Wang [Department of Materials Science and Engineering, I-Shou University, Kaohsiung, 84001, Taiwan (China)

    2013-12-15T23:59:59.000Z

    To study the interfacial reaction of the ex-situ reinforced phase (Ta) of a Zr-based ((Zr{sub 48}Cu{sub 36}Al{sub 8}Ag{sub 8})Si{sub 0.75} + Ta{sub 5}) bulk metallic glass composite after laser spot welding, the interfacial regions of the reinforced phases located at specific zones in the welds including the parent material, weld fusion zone and heat affected zone were investigated. Specimen preparation from the specific zones for transmission electron microscopy analysis was performed using the focused ion beam technique. The test results showed that the reinforced phases in the parent material, weld fusion zone and heat affected zone were all covered by an interfacial layer. From microstructure analysis, and referring to the phase diagram, it was clear that the thin layers are an intermetallic compound ZrCu phase. However, due to their different formation processes, those layers show the different morphologies or thicknesses. - Highlights: • An ex-situ Zr-based BMG composite was laser spot welded. • The interfacial regions of the RPs located at PM, WFZ and HAZ were investigated. • The RPs in the PM, WFZ and HAZ were all covered by a ZrCu interfacial layer. • Due to different formation processes, those layers show the different morphology.

  3. Thin Metal Oxide Films to Modify a Window Layer in CdTe-Based Solar Cells for Improved Performance

    SciTech Connect (OSTI)

    Lemmon, John P.; Polikarpov, Evgueni; Bennett, Wendy D.; Kovarik, Libor

    2012-05-05T23:59:59.000Z

    We report on CdS/CdTe photovoltaic devices that contain a thin Ta2O5 film deposited onto the CdS window layer by sputtering. We show that for thicknesses below 5 nm, Ta2O5 films between CdS and CdTe positively affect the solar cell performance, improving JSC, VOC, and the cell power conversion efficiency despite the insulating nature of the interlayer material. Using the Ta2O5 interlayer, a VOC gain of over 100 mV was demonstrated compared to a CdTe/CdS baseline. Application of a 1nm Ta2O5 interlayer enabled the fabrication of CdTe solar cells with extremely thin (less than 30 nm) CdS window layers. The efficiency of these cells exceeded that of a base line cell with 95 nm of CdS.

  4. Stress-Rupture, Overstressing and a Proposed New Methodology to Assess the Durability and Reliability of Ceramic Matrix Composites at Elevated Temperatures

    SciTech Connect (OSTI)

    Lara-Curzio, E.

    1999-07-05T23:59:59.000Z

    A new testing strategy is proposed to assess the durability and reliability of non- oxide continuous fiber-reinforced ceramic composites for high temperature structural applications. The strategy is based on determining the reliability (probability of failure) of these materials when subjected to random loading schedules consisting of load and temperature spikes that are superimposed on otherwise constant stress and temperature histories. The frequency and magnitude of the load and temperature spikes would be representative of the number and characteristics of the transients that are associated with a particular industrial application and that are expected to occur over the life of the component. The effect of overstressing on the stress- ruptttre behavior of a CG-NicalonTM fiber-reinforced SiC composite was investigated and results arc presented from tests conducted in ambient air at 950"C.

  5. Extended Durability Testing of an External Fuel Processor for a Solid Oxide Fuel Cell (SOFC)

    SciTech Connect (OSTI)

    Mark Perna; Anant Upadhyayula; Mark Scotto

    2012-11-05T23:59:59.000Z

    Durability testing was performed on an external fuel processor (EFP) for a solid oxide fuel cell (SOFC) power plant. The EFP enables the SOFC to reach high system efficiency (electrical efficiency up to 60%) using pipeline natural gas and eliminates the need for large quantities of bottled gases. LG Fuel Cell Systems Inc. (formerly known as Rolls-Royce Fuel Cell Systems (US) Inc.) (LGFCS) is developing natural gas-fired SOFC power plants for stationary power applications. These power plants will greatly benefit the public by reducing the cost of electricity while reducing the amount of gaseous emissions of carbon dioxide, sulfur oxides, and nitrogen oxides compared to conventional power plants. The EFP uses pipeline natural gas and air to provide all the gas streams required by the SOFC power plant; specifically those needed for start-up, normal operation, and shutdown. It includes a natural gas desulfurizer, a synthesis-gas generator and a start-gas generator. The research in this project demonstrated that the EFP could meet its performance and durability targets. The data generated helped assess the impact of long-term operation on system performance and system hardware. The research also showed the negative impact of ambient weather (both hot and cold conditions) on system operation and performance.

  6. Effect of Stainless Steel Can/Glass-Ceramic Interaction Layer on Aqueous Durability

    SciTech Connect (OSTI)

    McGlinn, Peter J.; Zhang, Yingjie; Li, Huijun; Payne, Timothy E. [Australian Nuclear Science and Technology Organisation, New Illawarra Road, Lucas Heights (Australia)

    2007-07-01T23:59:59.000Z

    Calcined high-level radioactive waste (HLW) stored at the Idaho National Laboratory (INL) will eventually be immobilised in a suitable wasteform before disposal. A tailored glass-ceramic wasteform, produced by hot isostatic pressing (HIPing) in stainless steel (SS) cans, has been developed at the Australian Nuclear Science and Technology Organisation (ANSTO) as a cost-saving alternative to glass which would improve waste loading and density, and reduce waste volume. We have studied the SS/wasteform interactions under HIPing conditions to understand whether such interactions would have any detrimental effect on long-term wasteform stability. This has been demonstrated by carrying out aqueous durability tests, under near-neutral and alkaline conditions, on the wasteform at the interaction layer, and on the wasteform distal to this reaction edge. Reaction during HIPing resulted in verifiable Cr diffusion from the can wall into the wasteform, yet without any detectable detrimental impact on the HIP can or the aqueous durability of the wasteform. (authors)

  7. Durability of (Pr0.7sr0.3)Mn03 +/-delta/8ysz

    SciTech Connect (OSTI)

    An, Ke [ORNL; Reifsnider, K L [University of Connecticut, Storrs; Gao, C Y [University of Tennessee, Knoxville (UTK)

    2006-01-01T23:59:59.000Z

    Half cell SOFCs with Durability of (Pr{sub 0.7}Sr{sub 0.3})Mn0{sub 3}{+-}{delta}/8YSZ composite cathodes on 8YSZ electrolytes were aged up to 1000 h at 1000 C in air with/without 0.318 A cm{sup -2} cathodic polarization. During the aging, the performance of the half cell SOFCs was measured using electrochemical impedance spectroscopy (EIS). After aging, the surface of the composite cathode and the interface between the composite cathode and the electrolyte was investigated with scanning electron microscopy (SEM). Chemical element analysis was performed with energy dispersive X-ray spectroscopy (EDS). The performance of the half cell SOFCs degraded after aging with/without polarization compared to the initial state. The SOFCs had a larger polarization resistance after 1000 h of aging. The cathodic current was shown to have an impact on the performance by slowing down the rate of decrease of polarization resistance of the SOFCs. After aging, the microstructural properties--mean pore size increased and cumulative pore volume decreased, and growth of grains was found on the Durability of (Pr{sub 0.7}Sr{sub 0.3})Mn0{sub 3}{+-}{delta} phases.

  8. Metal Hydrides

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(FactDepartment3311, 3312), OctoberMay 18-19,DepartmentEnergyMetalMetal

  9. A REVISED METHOD FOR ESTIMATING OXIDE BASICITY PER THE SMITH SCALE WITH EXAMPLE APPLICATION TO GLASS DURABILITY

    SciTech Connect (OSTI)

    REYNOLDS JG

    2011-07-27T23:59:59.000Z

    Previous researchers have developed correlations between oxide electronegativity and oxide basicity. The present paper revises those correlations using a newer method of calculating electronegativity of the oxygen anion. Basicity is expressed using the Smith {alpha} parameter scale. A linear relation was found between the oxide electronegativity and the Smith {alpha} parameter, with an R{sup 2} of 0.92. An example application of this new correlation to the durability of high-level nuclear waste glass is demonstrated. The durability of waste glass was found to be directly proportional to the quantity and basicity of the oxides of tetrahedrally coordinated network forming ions.

  10. Development of Metal Oxide Nanostructure-based Optical Sensors for Fossil Fuel Derived Gases Measurement at High Temperature

    SciTech Connect (OSTI)

    Chen, Kevin

    2014-08-31T23:59:59.000Z

    This final technical report details research works performed supported by a Department of Energy grant (DE-FE0003859), which was awarded under the University Coal Research Program administrated by National Energy Technology Laboratory. This research program studied high temperature fiber sensor for harsh environment applications. It developed two fiber optical sensor platform technology including regenerative fiber Bragg grating sensors and distributed fiber optical sensing based on Rayleigh backscattering optical frequency domain reflectometry. Through the studies of chemical and thermal regenerative techniques for fiber Bragg grating (FBG) fabrication, high-temperature stable FBG sensors were successfully developed and fabricated in air-hole microstructured fibers, high-attenuation fibers, rare-earth doped fibers, and standard telecommunication fibers. By optimizing the laser processing and thermal annealing procedures, fiber grating sensors with stable performance up to 1100oC have been developed. Using these temperature-stable FBG gratings as sensor platform, fiber optical flow, temperature, pressure, and chemical sensors have been developed to operate at high temperatures up to 800oC. Through the integration of on-fiber functional coating, the use of application-specific air-hole microstructural fiber, and application of active fiber sensing scheme, distributed fiber sensor for temperature, pressure, flow, liquid level, and chemical sensing have been demonstrated with high spatial resolution (1-cm or better) with wide temperature ranges. These include the demonstration of 1) liquid level sensing from 77K to the room temperature, pressure/temperature sensing from the room temperature to 800C and from the 15psi to 2000 psi, and hydrogen concentration measurement from 0.2% to 10% with temperature ranges from the room temperature to 700C. Optical sensors developed by this program has broken several technical records including flow sensors with the highest operation temperature up to 750oC, first distributed chemical measurements at the record high temperature up to 700oC, first distributed pressure measurement at the record high temperature up to 800oC, and the fiber laser sensors with the record high operation temperature up to 700oC. The research performed by this program dramatically expand the functionality, adaptability, and applicability of distributed fiber optical sensors with potential applications in a number of high-temperature energy systems such as fossil-fuel power generation, high-temperature fuel cell applications, and potential for nuclear energy systems.

  11. Tool Durability Maps for Friction Stir Welding of an Aluminum Alloy T. DebRoy, A. De*, H.K.D.H. Bhadeshia**, V. D. Manvatkar*, A. Arora

    E-Print Network [OSTI]

    Cambridge, University of

    1 Tool Durability Maps for Friction Stir Welding of an Aluminum Alloy T. DebRoy, A. De*, H of premature tool failure. A scheme is created which exploits the physical three-dimensional heat and mass flow accumulation models, enables the plotting of tool durability maps which define the domains of satisfactory tool

  12. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing...

  13. An Innovative Technique for Evaluating the Integrity and Durability of Wind Turbine Blade Composites - Final Project Report

    SciTech Connect (OSTI)

    Wang, Jy-An John [ORNL; Ren, Fei [ORNL; Tan, Ting [ORNL; Mandell, John [Montana State University; Agastra, Pancasatya [Montana State University

    2011-11-01T23:59:59.000Z

    To build increasingly larger, lightweight, and robust wind turbine blades for improved power output and cost efficiency, durability of the blade, largely resulting from its structural composites selection and aerodynamic shape design, is of paramount concern. The safe/reliable operation of structural components depends critically on the selection of materials that are resistant to damage and failure in the expected service environment. An effective surveillance program is also necessary to monitor the degradation of the materials in the course of service. Composite materials having high specific strength/stiffness are desirable for the construction of wind turbines. However, most high-strength materials tend to exhibit low fracture toughness. That is why the fracture toughness of the composite materials under consideration for the manufacture of the next generation of wind turbines deserves special attention. In order to achieve the above we have proposed to develop an innovative technology, based on spiral notch torsion test (SNTT) methodology, to effectively investigate the material performance of turbine blade composites. SNTT approach was successfully demonstrated and extended to both epoxy and glass fiber composite materials for wind turbine blades during the performance period. In addition to typical Mode I failure mechanism, the mixed-mode failure mechanism induced by the wind turbine service environments and/or the material mismatch of the composite materials was also effectively investigated using SNTT approach. The SNTT results indicate that the proposed protocol not only provides significant advance in understanding the composite failure mechanism, but also can be readily utilized to assist the development of new turbine blade composites.

  14. CONTRIBUTION A UNE GESTION DURABLE DE STRUCTURES EN BETON ARME SOUMISES A LA PENETRATION D'IONS CHLORURE

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    CONTRIBUTION A UNE GESTION DURABLE DE STRUCTURES EN BETON ARME SOUMISES A LA PENETRATION D économiques et environnementaux afin de réduire l'impact environnemental, d'optimiser la gestion des'IONS CHLORURE CONTRIBUTION TO SUSTAINABLE MANAGEMENT OF REINFORCED CONCRETE STRUCTURES SUBJECTED TO CHLORIDE

  15. Ion assisted deposition of optical and protective coatings for heavy metal fluoride glass

    SciTech Connect (OSTI)

    McNally, J.J.; Al-Jumaily, G.A.; McNeil, J.R.

    1986-06-15T23:59:59.000Z

    Heavy metal fluoride glass materials are attractive for optical applications in the near UV through IR wavelength regions. However, many compositions are relatively soft and hygroscopic and possess low softening temperature (250--300/sup 0/C). We have applied ion assisted deposition (IAD) techniques to deposit MgF/sub 2/, SiO/sub 2/, and Al/sub 2/O/sub 3//SiO/sub 2/ thin film structures on fluoride glass substrates at ambient substrate temperature (--100/sup 0/C). The coatings deposited using IAD improve the environmental durability of the fluoride glass and appear to have reasonably good optical characteristics; without application of IAD, the deposited coatings are not durable and have poor adhesion.

  16. Electrochromically switched, gas-reservoir metal hydride devices with application to energy-efficient windows

    SciTech Connect (OSTI)

    Anders, Andre; Slack, Jonathan L.; Richardson, Thomas J.

    2008-05-05T23:59:59.000Z

    Proof-of-principle gas-reservoir MnNiMg electrochromic mirror devices have been investigated. In contrast to conventional electrochromic approaches, hydrogen is stored (at low concentration) in the gas volume between glass panes of the insulated glass units (IGUs). The elimination of a solid state ion storage layer simplifies the layer stack, enhances overall transmission, and reduces cost. The cyclic switching properties were demonstrated and system durability improved with the incorporation a thin Zr barrier layer between the MnNiMg layer and the Pd catalyst. Addition of 9 percent silver to the palladium catalyst further improved system durability. About 100 full cycles have been demonstrated before devices slow considerably. Degradation of device performance appears to be related to Pd catalyst mobility, rather than delamination or metal layer oxidation issues originally presumed likely to present significant challenges.

  17. The Durability of Various Crucible Materials for Aluminum Nitride Crystal growth by Sublimation

    SciTech Connect (OSTI)

    Liu,B.; Edgar, J.; Gu, Z.; Zhuang, D.; Raghothamachar, B.; Dudley, M.; Sarua, A.; Kuball, M.; Meyer, H.

    2004-01-01T23:59:59.000Z

    Producing high purity aluminum nitride crystals by the sublimation-recondensation technique is difficult due to the inherently reactive crystal growth environment, normally at temperature in excess of 2100 C. The durability of the furnace fixture materials (crucibles, retorts, etc.) at such a high temperature remains a critical problem. In the present study, the suitability of several refractory materials for AlN crystal growth is investigated, including tantalum carbide, niobium carbide, tungsten, graphite, and hot-pressed boron nitride. The thermal and chemical properties and performance of these materials in inert gas, as well as under AlN crystal growth conditions are discussed. TaC and NbC are the most stable crucible materials with very low elemental vapor pressures in the crystal growth system. Compared with refractory material coated graphite crucibles, HPBN crucible is better for AlN self-seeded growth, as crystals tend to nucleate in thin colorless platelets with low dislocation density.

  18. Factors affecting the microstructural stability and durability of thermal barrier coatings fabricated by air plasma spraying

    SciTech Connect (OSTI)

    Helminiak, M. A. [National Energy Technology Laboratory (NETL) and Univ. of Pittsburgh, PA (United States); Yanar, N. M. [National Energy Technology Laboratory (NETL) and Univ. of Pittsburgh, PA (United States); Pettit, F. S. [National Energy Technology Laboratory (NETL) and Univ. of Pittsburgh, PA (United States); Taylor, T. A. [Praxair Surface Technologies, Inc., Indianapolis, IN (United States); Meier, G. H. [National Energy Technology Laboratory (NETL) and Univ. of Pittsburgh, PA (United States)

    2012-10-01T23:59:59.000Z

    The high-temperature behavior of high-purity, low-density (HP-LD) air plasma sprayed (APS) thermal barrier coatings (TBCs) with NiCoCrAlY bond coats deposited by argon-shrouded plasma spraying is described. The high purity yttria-stabilized zirconia resulted in top coats which are highly resistant to sintering and transformation from the metastable tetragonal phase to the equilibrium mixture of monoclinic and cubic phases. The thermal conductivity of the as-processed TBC is low but increases during high temperature exposure even before densification occurs. The porous topcoat microstructure also resulted in good spallation resistance during thermal cycling. The actual failure mechanisms of the APS coatings were found to depend on topcoat thickness, topcoat density, and the thermal cycle frequency. The failure mechanisms are described and the durability of the HP-LD coatings is compared with that of state-of-the-art electron beam physical vapor deposition TBCs.

  19. DURABILITY TESTING OF FLUIDIZED BED STEAM REFORMER WASTE FORMS FOR SODIUM BEARING WASTE AT IDAHO NATIONAL LABORATORY

    SciTech Connect (OSTI)

    Crawford, C; Carol Jantzen, C

    2007-08-27T23:59:59.000Z

    Fluidized Bed Steam Reforming (FBSR) processing of Sodium Bearing Waste simulants was performed in December 2006 by THOR{sup sm} Treatment Technologies LLC (TTT) The testing was performed at the Hazen Research Inc. (HRI) pilot plant facilities in Golden, CO. FBSR products from these pilot tests on simulated waste representative of the SBW at the Idaho Nuclear Technology and Engineering Center (INTEC) were subsequently transferred to the Savannah River National Laboratory (SRNL) for characterization and leach testing. Four as-received Denitration and Mineralization Reformer (DMR) granular/powder samples and four High Temperature Filter (HTF) powder samples were received by SRNL. FBSR DMR samples had been taken from the ''active'' bed, while the HTF samples were the fines collected as carryover from the DMR. The process operated at high fluidizing velocities during the mineralization test such that nearly all of the product collected was from the HTF. Active bed samples were collected from the DMR to monitor bed particle size distribution. Characterization of these crystalline powder samples shows that they are primarily Al, Na and Si, with > 1 wt% Ca, Fe and K. The DMR samples contained less than 1 wt% carbon and the HTF samples ranged from 13 to 26 wt% carbon. X-ray diffraction analyses show that the DMR samples contained significant quantities of the Al{sub 2}O{sub 3} startup bed. The DMR samples became progressively lower in starting bed alumina with major Na/Al/Si crystalline phases (nepheline and sodium aluminosilicate) present as cumulative bed turnover occurred but 100% bed turnover was not achieved. The HTF samples also contained these major crystalline phases. Durability testing of the DMR and HTF samples using the ASTM C1285 Product Consistency Test (PCT) 7-day leach test at 90 C was performed along with several reference glass samples. Comparison of the normalized leach rates for the various DMR and HTF components was made with the reference glasses and the Low Activity Waste (LAW) specification for the Hanford Waste Treatment and Vitrification Plant (WTP). Normalized releases from the DMR and HTF samples were all less than 1 g/m{sup 2}. For comparison, normalized release from the High-Level Waste (HLW) benchmark Environmental Assessment (EA) glass for Si, Li, Na and B ranges from 2 to 8 g/m{sup 2}. The normalized release specification for LAW glass for the Hanford WTP is 2 g/m{sup 2}. The Toxicity Characteristic Leach Test (TCLP) was performed on DMR and HTF as received samples and the tests showed that these products meet the criteria for the EPA RCRA Universal Treatment Standards for all of the constituents contained in the starting simulants such as Cr, Pb and Hg (RCRA characteristically hazardous metals) and Ni and Zn (RCRA metals required for listed wastes).

  20. Topological evolution and photoluminescent properties of a series of divalent zinc-based metal–organic frameworks tuned via ancillary ligating spacers

    SciTech Connect (OSTI)

    Lian, Xiao-Min; Zhao, Wen [Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, 3663 North Zhongshan Road, Shanghai 200062 (China); Zhao, Xiao-Li, E-mail: xlzhao@chem.ecnu.edu.cn [Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, 3663 North Zhongshan Road, Shanghai 200062 (China)

    2013-04-15T23:59:59.000Z

    The combination of divalent zinc ions, 4-(4-carboxybenzamido)benzoic acid and exo-bidendate bipyridine ligands gave rise to a series of new MOFs: [ZnL(bipy)]·DMF·H{sub 2}O (1), [ZnL(bpe)]·1.5H{sub 2}O (2), [ZnL(bpa)]·4H{sub 2}O (3) and [ZnL(bpp)]·1.75H{sub 2}O (4) (MOF=metal-organic framework, bipy=4,4?-bipyridine, bpe=trans-1,2-bis(4-pyridyl)ethylene, bpa=1,2-bis(4-pyridinyl)ethane, bpp=1,3-bis(4-pyridinyl)propane, H{sub 2}L=4,4?-(carbonylimino)dibenzoic acid). Fine tune over the topology of the MOFs was achieved via systematically varying the geometric length of the second ligating bipyridine ligands. Single-crystal X-ray analysis reveals that complex 1 has a triply interpenetrated three-dimensional (3D) framework with elongated primitive cubic topology, whereas isostructural complexes 2 and 3 each possesses a 6-fold interpenetrated diamondiod 3D framework. Further expansion of the length of the bipyridine ligand to bpp leads to the formation of 4, which features an interesting entangled architecture of 2D?3D parallel polycatenation. In addition, the thermogravimetric analyses and solid-state photoluminescent properties of the selected complexes are investigated. - Graphical abstract: The incorporation of exo-bidendate bipyridine spacers into the Zn–H{sub 2}L system has yielded a series of new MOFs exhibiting topological evolution from 3-fold interpenetration to 6-fold interpenetration and 2D?3D parallel polycatenation. Highlights: ? The effect of the pyridyl-based spacers on the formation of MOFs was explored. ? Fine tune over the topology of the MOFs was achieved. ? An interesting structure of 2D?3D parallel polycatenation is reported.

  1. Metallicity and Quasar Outflows

    E-Print Network [OSTI]

    Wang, Huiyuan; Yuan, Weimin; Wang, Tinggui

    2012-01-01T23:59:59.000Z

    Correlations are investigated of the outflow strength of quasars, as measured by the blueshift and asymmetry index (BAI) of the CIV line (Wang et al. 2011), with intensities and ratios of broad emission lines, based on composite quasar spectra built from the Sloan Digital Sky Survey. We find that most of the line ratios of other ions to CIV prominently increases with BAI. These behaviors can be well understood in the context of increasing metallicity with BAI. The strength of dominant coolant, CIV line, decreases and weak collisionally excited lines increase with gas metallicity as a result of the competition between different line coolants. Using SiIV+OIV]/CIV as an indicator of gas metallicity, we present, for the first time, a strong correlation between the metallicitiy and the outflow strength of quasars over a wide range of 1.7 to 6.9 times solar abundance. Our result implies that the metallicity plays an important role in the formation of quasar outflows, likely via affecting outflow acceleration. This ...

  2. Synthesis of Cationic Extended Frameworks for Anion-Based Applications

    E-Print Network [OSTI]

    Fei, Honghan

    2012-01-01T23:59:59.000Z

    frameworks based on rare earth metals are the most developedwhere M is rare earth metals. The first structurallybased on trivalent rare earth metals, including Yb 3+ , Y 3

  3. Optical amplifier operating at 1.3 microns useful for telecommunications and based on dysprosium-doped metal chloride host materials

    DOE Patents [OSTI]

    Page, R.H.; Schaffers, K.I.; Payne, S.A.; Krupke, W.F.; Beach, R.J.

    1997-12-02T23:59:59.000Z

    Dysprosium-doped metal chloride materials offer laser properties advantageous for use as optical amplifiers in the 1.3 {micro}m telecommunications fiber optic network. The upper laser level is characterized by a millisecond lifetime, the host material possesses a moderately low refractive index, and the gain peak occurs near 1.31 {micro}m. Related halide materials, including bromides and iodides, are also useful. The Dy{sup 3+}-doped metal chlorides can be pumped with laser diodes and yield 1.3 {micro}m signal gain levels significantly beyond those currently available. 9 figs.

  4. Optical amplifier operating at 1.3 microns useful for telecommunications and based on dysprosium-doped metal chloride host materials

    DOE Patents [OSTI]

    Page, Ralph H. (San Ramon, CA); Schaffers, Kathleen I. (Pleasanton, CA); Payne, Stephen A. (Castro Valley, CA); Krupke, William F. (Pleasanton, CA); Beach, Raymond J. (Livermore, CA)

    1997-01-01T23:59:59.000Z

    Dysprosium-doped metal chloride materials offer laser properties advantageous for use as optical amplifiers in the 1.3 .mu.m telecommunications fiber optic network. The upper laser level is characterized by a millisecond lifetime, the host material possesses a moderately low refractive index, and the gain peak occurs near 1.31 .mu.m. Related halide materials, including bromides and iodides, are also useful. The Dy.sup.3+ -doped metal chlorides can be pumped with laser diodes and yield 1.3 .mu.m signal gain levels significantly beyond those currently available.

  5. Extracting metals directly from metal oxides

    DOE Patents [OSTI]

    Wai, C.M.; Smart, N.G.; Phelps, C.

    1997-02-25T23:59:59.000Z

    A method of extracting metals directly from metal oxides by exposing the oxide to a supercritical fluid solvent containing a chelating agent is described. Preferably, the metal is an actinide or a lanthanide. More preferably, the metal is uranium, thorium or plutonium. The chelating agent forms chelates that are soluble in the supercritical fluid, thereby allowing direct removal of the metal from the metal oxide. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of {beta}-diketones, halogenated {beta}-diketones, phosphinic acids, halogenated phosphinic acids, carboxylic acids, halogenated carboxylic acids, and mixtures thereof. In especially preferred embodiments, at least one of the chelating agents is fluorinated. The method provides an environmentally benign process for removing metals from metal oxides without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the metal recovered, to provide an economic, efficient process. 4 figs.

  6. Extracting metals directly from metal oxides

    DOE Patents [OSTI]

    Wai, Chien M. (Moscow, ID); Smart, Neil G. (Moscow, ID); Phelps, Cindy (Moscow, ID)

    1997-01-01T23:59:59.000Z

    A method of extracting metals directly from metal oxides by exposing the oxide to a supercritical fluid solvent containing a chelating agent is described. Preferably, the metal is an actinide or a lanthanide. More preferably, the metal is uranium, thorium or plutonium. The chelating agent forms chelates that are soluble in the supercritical fluid, thereby allowing direct removal of the metal from the metal oxide. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of .beta.-diketones, halogenated .beta.-diketones, phosphinic acids, halogenated phosphinic acids, carboxylic acids, halogenated carboxylic acids, and mixtures thereof. In especially preferred embodiments, at least one of the chelating agents is fluorinated. The method provides an environmentally benign process for removing metals from metal oxides without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the metal recovered, to provide an economic, efficient process.

  7. Molybdenum-based additives to mixed-metal oxides for use in hot gas cleanup sorbents for the catalytic decomposition of ammonia in coal gases

    DOE Patents [OSTI]

    Ayala, Raul E. (Clifton Park, NY)

    1993-01-01T23:59:59.000Z

    This invention relates to additives to mixed-metal oxides that act simultaneously as sorbents and catalysts in cleanup systems for hot coal gases. Such additives of this type, generally, act as a sorbent to remove sulfur from the coal gases while substantially simultaneously, catalytically decomposing appreciable amounts of ammonia from the coal gases.

  8. Thermodynamic estimation of minor element distribution between immiscible liquids in Fe-Cu-based metal phase generated in melting treatment of municipal solid wastes

    SciTech Connect (OSTI)

    Lu, X. [School of Metallurgical and Ecological Engineering, The University of Science and Technology Beijing, 30 Xueyuan Road, Haidian District, Beijing 100083 (China); Nakajima, K.; Sakanakura, H. [Research Center for Material Cycles and Waste Management, National Institute for Environmental Studies (NIES), 16-2 Onogawa, Tsukuba 305-8506 (Japan); Matsubae, K. [Graduate School of Engineering, Tohoku University, 6-6-11 Aza-Aoba, Aramaki, Sendai 980-8579 (Japan); Bai, H. [School of Metallurgical and Ecological Engineering, The University of Science and Technology Beijing, 30 Xueyuan Road, Haidian District, Beijing 100083 (China); Nagasaka, T., E-mail: t-nagasaka@m.tohoku.ac.jp [Graduate School of Engineering, Tohoku University, 6-6-11 Aza-Aoba, Aramaki, Sendai 980-8579 (Japan)

    2012-06-15T23:59:59.000Z

    Graphical abstract: Display Omitted Highlights: Black-Right-Pointing-Pointer Two liquids separation of metal occurs in the melting of municipal solid waste. Black-Right-Pointing-Pointer The distribution of PGMs etc. between two liquid metal phases is studied. Black-Right-Pointing-Pointer Quite simple thermodynamic model is applied to predict the distribution ratio. Black-Right-Pointing-Pointer Au and Ag originated from WEEE are found to be concentrated into Cu-rich phase. - Abstract: Waste electrical and electronic equipment (WEEE) has become an important target in managing material cycles from the viewpoint of not only waste management and control of environmental pollution but also resource conservation. This study investigated the distribution tendency of trace elements in municipal solid waste (MSW) or incinerator ash, including valuable non-ferrous metals (Ni, Co, Cr, Mn, Mo, Ti, V, W, Zr), precious group metals (PGMs) originated from WEEE (Ag, Au, Pd, Pt), and others (Al, B, Pb, Si), between Fe-rich and Cu-rich metal phases by means of simple thermodynamic calculations. Most of the typical alloying elements for steel (Co, Cr, Mo, Nb, Ni, Si, Ti, V, and W) and Rh were preferentially distributed into the Fe-rich phase. PGMs, such as Au, Ag, and Pd, were enriched in the Cu-rich phase, whereas Pt was almost equally distributed into both phases. Since the primary metallurgical processing of Cu is followed by an electrolysis for refining, and since PGMs in crude copper have been industrially recovered from the resulting anode slime, our results indicated that Ag, Au, and Pd could be effectively recovered from MSW if the Cu-rich phase could be selectively collected.

  9. Metal-phosphate binders

    DOE Patents [OSTI]

    Howe, Beth Ann [Lewistown, IL; Chaps-Cabrera, Jesus Guadalupe [Coahuila, MX

    2009-05-12T23:59:59.000Z

    A metal-phosphate binder is provided. The binder may include an aqueous phosphoric acid solution, a metal-cation donor including a metal other than aluminum, an aluminum-cation donor, and a non-carbohydrate electron donor.

  10. Metal Hydrides - Science Needs

    Broader source: Energy.gov (indexed) [DOE]

    with traditions in metal hydride research Metal and Ceramic Sciences Condensed Matter Physics Materials Chemistry Chemical and Biological Sciences Located on campus of Tier...

  11. Spin current and inverse spin Hall effect in ferromagnetic metals probed by Y{sub 3}Fe{sub 5}O{sub 12}-based spin pumping

    SciTech Connect (OSTI)

    Wang, Hailong; Du, Chunhui; Chris Hammel, P., E-mail: hammel@physics.osu.edu; Yang, Fengyuan, E-mail: fyyang@physics.osu.edu [Department of Physics, The Ohio State University, Columbus, Ohio 43210 (United States)

    2014-05-19T23:59:59.000Z

    Using ferromagnetic (FM) resonance spin pumping, we observe injection of spin currents from Y{sub 3}Fe{sub 5}O{sub 12} (YIG) films to FM metals, including Ni{sub 81}Fe{sub 19} (Py), Fe, Co, and Ni, and detection of spin currents by inverse spin Hall effect (ISHE) in the FM metals. We obtain a high effective spin mixing conductance of 6.3?×?10{sup 18}?m{sup ?2} in a YIG/Cu/Py trilayer and a spin Hall angle of 0.020 for Py. The spin pumping signals in Fe, Co, and Ni confirm the mechanism of ISHE in FMs is the inverse process of the anomalous Hall effect.

  12. Standard practice for qualification and acceptance of boron based metallic neutron absorbers for nuclear criticality control for dry cask storage systems and transportation packaging

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2007-01-01T23:59:59.000Z

    1.1 This practice provides procedures for qualification and acceptance of neutron absorber materials used to provide criticality control by absorbing thermal neutrons in systems designed for nuclear fuel storage, transportation, or both. 1.2 This practice is limited to neutron absorber materials consisting of metal alloys, metal matrix composites (MMCs), and cermets, clad or unclad, containing the neutron absorber boron-10 (10B). 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

  13. Ultraviolet GaN photodetectors on Si via oxide buffer heterostructures with integrated short period oxide-based distributed Bragg reflectors and leakage suppressing metal-oxide-semiconductor contacts

    SciTech Connect (OSTI)

    Szyszka, A., E-mail: szyszka@ihp-microelectronics.com, E-mail: adam.szyszka@pwr.wroc.pl [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany); Faculty of Microsystem Electronics and Photonics, Wroclaw University of Technology, Janiszewskiego 11/17, 50-372 Wroclaw (Poland); Lupina, L.; Lupina, G.; Schubert, M. A.; Zaumseil, P. [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany); Haeberlen, M.; Storck, P.; Thapa, S. B. [Siltronic, Hanns-Seidel-Platz 4, 81737 München (Germany); Schroeder, T. [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany); BTU Cottbus-Senftenberg, Konrad-Zuse-Strasse 1, 03046 Cottbus (Germany)

    2014-08-28T23:59:59.000Z

    Based on a novel double step oxide buffer heterostructure approach for GaN integration on Si, we present an optimized Metal-Semiconductor-Metal (MSM)-based Ultraviolet (UV) GaN photodetector system with integrated short-period (oxide/Si) Distributed Bragg Reflector (DBR) and leakage suppressing Metal-Oxide-Semiconductor (MOS) electrode contacts. In terms of structural properties, it is demonstrated by in-situ reflection high energy electron diffraction and transmission electron microscopy-energy dispersive x-ray studies that the DBR heterostructure layers grow with high thickness homogeneity and sharp interface structures sufficient for UV applications; only minor Si diffusion into the Y{sub 2}O{sub 3} films is detected under the applied thermal growth budget. As revealed by comparative high resolution x-ray diffraction studies on GaN/oxide buffer/Si systems with and without DBR systems, the final GaN layer structure quality is not significantly influenced by the growth of the integrated DBR heterostructure. In terms of optoelectronic properties, it is demonstrated that—with respect to the basic GaN/oxide/Si system without DBR—the insertion of (a) the DBR heterostructures and (b) dark current suppressing MOS contacts enhances the photoresponsivity below the GaN band-gap related UV cut-off energy by almost up to two orders of magnitude. Given the in-situ oxide passivation capability of grown GaN surfaces and the one order of magnitude lower number of superlattice layers in case of higher refractive index contrast (oxide/Si) systems with respect to classical III-N DBR superlattices, virtual GaN substrates on Si via functional oxide buffer systems are thus a promising robust approach for future GaN-based UV detector technologies.

  14. Titanium metal: extraction to application

    SciTech Connect (OSTI)

    Gambogi, Joseph (USGS, Reston, VA); Gerdemann, Stephen J.

    2002-09-01T23:59:59.000Z

    In 1998, approximately 57,000 tons of titanium metal was consumed in the form of mill products (1). Only about 5% of the 4 million tons of titanium minerals consumed each year is used to produce titanium metal, with the remainder primarily used to produce titanium dioxide pigment. Titanium metal production is primarily based on the direct chlorination of rutile to produce titanium tetrachloride, which is then reduced to metal using the Kroll magnesium reduction process. The use of titanium is tied to its high strength-to-weight ratio and corrosion resistance. Aerospace is the largest application for titanium. In this paper, we discuss all aspects of the titanium industry from ore deposits through extraction to present and future applications. The methods of both primary (mining of ore, extraction, and purification) and secondary (forming and machining) operations will be analyzed. The chemical and physical properties of titanium metal will be briefly examined. Present and future applications for titanium will be discussed. Finally, the economics of titanium metal production also are analyzed as well as the advantages and disadvantages of various alternative extraction methods.

  15. Radiation Induced Nanocrystal Formation in Metallic Glasses

    E-Print Network [OSTI]

    Carter, Jesse

    2010-01-14T23:59:59.000Z

    The irradiation of metallic glasses to induce nanocrystallization was studied in two metallic glass compositions, Cu50Zr45Ti5 and Zr55Cu30Al10Ni5. Atomic mobility was described using a model based on localized excess free volume due to displace...

  16. Corrosion resistant metallic bipolar plate

    DOE Patents [OSTI]

    Brady, Michael P. (Oak Ridge, TN); Schneibel, Joachim H. (Knoxville, TN); Pint, Bruce A. (Knoxville, TN); Maziasz, Philip J. (Oak Ridge, TN)

    2007-05-01T23:59:59.000Z

    A corrosion resistant, electrically conductive component such as a bipolar plate for a PEM fuel cell includes 20 55% Cr, balance base metal such as Ni, Fe, or Co, the component having thereon a substantially external, continuous layer of chromium nitride.

  17. Transition metal sulfide loaded catalyst

    DOE Patents [OSTI]

    Maroni, V.A.; Iton, L.E.; Pasterczyk, J.W.; Winterer, M.; Krause, T.R.

    1994-04-26T23:59:59.000Z

    A zeolite-based catalyst is described for activation and conversion of methane. A zeolite support includes a transition metal (Mo, Cr or W) sulfide disposed within the micropores of the zeolite. The catalyst allows activation and conversion of methane to C[sub 2]+ hydrocarbons in a reducing atmosphere, thereby avoiding formation of oxides of carbon.

  18. Heavy metal biosensor

    SciTech Connect (OSTI)

    Hillson, Nathan J; Shapiro, Lucille; Hu, Ping; Andersen, Gary L

    2014-04-15T23:59:59.000Z

    Compositions and methods are provided for detection of certain heavy metals using bacterial whole cell biosensors.

  19. FLUIDIZED BED STEAM REFORMED MINERAL WASTE FORMS: CHARACTERIZATION AND DURABILITY TESTING

    SciTech Connect (OSTI)

    Jantzen, C; Troy Lorier, T; John Pareizs, J; James Marra, J

    2006-12-06T23:59:59.000Z

    Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of high sodium low activity wastes (LAW) such as those existing at the Hanford site, at the Idaho National Laboratory (INL), and the Savannah River Site (SRS). The addition of clay, charcoal, and a catalyst as co-reactants with the waste denitrates the aqueous wastes and forms a granular mineral waste form that can subsequently be made into a monolith for disposal if necessary. The waste form produced is a multiphase mineral assemblage of Na-Al-Si (NAS) feldspathoid minerals with cage and ring structures and iron bearing spinel minerals. The mineralization occurs at moderate temperatures between 650-750 C in the presence of superheated steam. The cage and ring structured feldspathoid minerals atomically bond radionuclides like Tc-99 and Cs-137 and anions such as SO{sub 4}, I, F, and Cl. The spinel minerals stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Granular mineral waste forms were made from (1) a basic Hanford Envelope A low activity waste (LAW) simulant and (2) an acidic INL simulant commonly referred to as sodium bearing waste (SBW) in pilot scale facilities at the Science Applications International Corporation (SAIC) Science and Technology Applications Research (STAR) facility in Idaho Falls, ID. The FBSR waste forms were characterized and the durability tested via ASTM C1285 (Product Consistency Test), the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP), and the Single Pass Flow Through (SPFT) test. The results of the SPFT testing and the activation energies for dissolution are discussed in this study.

  20. FLUIDIZED BED STEAM REFORMED MINERAL WASTE FORMS: CHARACTERIZATION AND DURABILITY TESTING

    SciTech Connect (OSTI)

    Jantzen, C; Troy Lorier, T; John Pareizs, J; James Marra, J

    2007-03-31T23:59:59.000Z

    Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of high sodium low activity wastes (LAW) such as those existing at the Hanford site, at the Idaho National Laboratory (INL), and the Savannah River Site (SRS). The addition of clay, charcoal, and a catalyst as co-reactants with the waste denitrates the aqueous wastes and forms a granular mineral waste form that can subsequently be made into a monolith for disposal if necessary. The waste form produced is a multiphase mineral assemblage of Na-Al-Si (NAS) feldspathoid minerals with cage and ring structures and iron bearing spinel minerals. The mineralization occurs at moderate temperatures between 650-750 C in the presence of superheated steam. The cage and ring structured feldspathoid minerals atomically bond radionuclides like Tc-99 and Cs-137 and anions such as SO4, I, F, and Cl. The spinel minerals stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Granular mineral waste forms were made from (1) a basic Hanford Envelope A low-activity waste (LAW) simulant and (2) an acidic INL simulant commonly referred to as sodium bearing waste (SBW) in pilot scale facilities at the Science Applications International Corporation (SAIC) Science and Technology Applications Research (STAR) facility in Idaho Falls, ID. The FBSR waste forms were characterized and the durability tested via ASTM C1285 (Product Consistency Test), the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP), and the Single Pass Flow Through (SPFT) test. The results of the SPFT testing and the activation energies for dissolution are discussed in this study.

  1. High-Performance Corrosion-Resistant Materials: Iron-Based Amorphous-Metal Thermal-Spray Coatings: SAM HPCRM Program ? FY04 Annual Report ? Rev. 0 - DARPA DSO & DOE OCRWM Co-Sponsored Advanced Materials Program

    SciTech Connect (OSTI)

    Farmer, J; Haslam, J; Wong, F; Ji, S; Day, S; Branagan, D; Marshall, M; Meacham, B; Buffa, E; Blue, C; Rivard, J; Beardsley, M; Buffa, E; Blue, C; Rivard, J; Beardsley, M; Weaver, D; Aprigliano, L; Kohler, L; Bayles, R; Lemieux, E; Wolejsza, T; Martin, F; Yang, N; Lucadamo, G; Perepezko, J; Hildal, K; Kaufman, L; Heuer, A; Ernst, F; Michal, G; Kahn, H; Lavernia, E

    2007-09-19T23:59:59.000Z

    The multi-institutional High Performance Corrosion Resistant Materials (HPCRM) Team is cosponsored by the Defense Advanced Projects Agency (DARPA) Defense Science Office (DSO) and the Department of Energy (DOE) Office of Civilian Radioactive Waste Management (OCRWM), and has developed new corrosion-resistant, iron-based amorphous metals that can be applied as coatings with advanced thermal spray technology. Two compositions have corrosion resistance superior to wrought nickel-based Alloy C-22 (UNS No. N06022) in very aggressive environments, including concentrated calcium-chloride brines at elevated temperature. Corrosion costs the Department of Defense billions of dollars every year, with an immense quantity of material in various structures undergoing corrosion. For example, in addition to fluid and seawater piping, ballast tanks, and propulsions systems, approximately 345 million square feet of structure aboard naval ships and crafts require costly corrosion control measures. The use of advanced corrosion-resistant materials to prevent the continuous degradation of this massive surface area would be extremely beneficial. The Fe-based corrosion-resistant, amorphous-metal coatings under development may prove of importance for applications on ships. Such coatings could be used as an 'integral drip shield' on spent fuel containers, as well as protective coatings that could be applied over welds, thereby preventing exposure to environments that might cause stress corrosion cracking. In the future, such new high-performance iron-based materials could be substituted for more-expensive nickel-based alloys, thereby enabling a reduction in the $58-billion life cycle cost for the long-term storage of the Nation's spent nuclear fuel by tens of percent.

  2. Making better batteries with metal oxide & graphene composites

    SciTech Connect (OSTI)

    None

    2011-03-01T23:59:59.000Z

    Learn how PNNL and Princeton scientists create better materials for batteries, materials that assemble on their own into durable nanocomposites.

  3. Making better batteries with metal oxide & graphene composites

    ScienceCinema (OSTI)

    None

    2012-12-31T23:59:59.000Z

    Learn how PNNL and Princeton scientists create better materials for batteries, materials that assemble on their own into durable nanocomposites.

  4. Metallization and insulization during impact

    SciTech Connect (OSTI)

    Gilman, J.J.

    1992-10-01T23:59:59.000Z

    It is pointed out that the large strains produced by hypervelocity impacts can be expected to produce dramatic changes in the chemical bonding (electronic structures) of materials. This will change the mechanical behavior towards increased ductility when a semiconductor is compressed until it becomes metallic; and towards increased brittleness when a transition metal is expanded so as to localize its d-band electrons. Both isotropic compression (expansion) and shear strains can cause these transformations. Critical deformation criteria are given based on the observed cubic to tetragonal transformations in compressed semiconductors.

  5. Photobiomolecular metallic particles and films

    DOE Patents [OSTI]

    Hu, Zhong-Cheng

    2003-05-06T23:59:59.000Z

    The method of the invention is based on the unique electron-carrying function of a photocatalytic unit such as the photosynthesis system I (PSI) reaction center of the protein-chlorophyll complex isolated from chloroplasts. The method employs a photo-biomolecular metal deposition technique for precisely controlled nucleation and growth of metallic clusters/particles, e.g., platinum, palladium, and their alloys, etc., as well as for thin-film formation above the surface of a solid substrate. The photochemically mediated technique offers numerous advantages over traditional deposition methods including quantitative atom deposition control, high energy efficiency, and mild operating condition requirements.

  6. Stabilization of Metal Nanoparticles in Cubic Mesostructured...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of regenerable metal-based adsorbents which can remove sulfur impurities from warm syngas stream down to less than 60 parts per billion by volume (ppbv) is described. This same...

  7. Hydrogen-permeable composite metal membrane and uses thereof

    DOE Patents [OSTI]

    Edlund, David J. (Bend, OR); Friesen, Dwayne T. (Bend, OR)

    1993-06-08T23:59:59.000Z

    Various hydrogen production and hydrogen sulfide decomposition processes are disclosed that utilize composite metal membranes that contain an intermetallic diffusion barrier separating a hydrogen-permeable base metal and a hydrogen-permeable coating metal. The barrier is a thermally stable inorganic proton conductor.

  8. Long-term durability of polyethylene for encapsulation of low-level radioactive, hazardous, and mixed wastes

    SciTech Connect (OSTI)

    Kalb, P.D.; Heiser, J.H.; Colombo, P.

    1991-01-01T23:59:59.000Z

    The durability of polyethylene waste forms for treatment of low-level radioactive, hazardous, and mixed wastes is examined. Specific potential failure mechanisms investigated include biodegradation, radiation, chemical attack, flammability, environmental stress cracking, and photodegradation. These data are supported by results from waste form performance testing including compressive yield strength, water immersion, thermal cycling, leachability of radioactive and hazardous species, irradiation, biodegradation, and flammability. Polyethylene was found to be extremely resistant to each of these potential failure modes under anticipated storage and disposal conditions. 16 refs., 3 figs., 1 tab.

  9. West Valley glass product qualification durability studies, FY 1987--1988: Effects of composition, redox state, thermal history, and groundwater

    SciTech Connect (OSTI)

    Reimus, M.A.H.; Piepel, G.F.; Mellinger, G.B.; Bunnell, L.R.

    1988-11-01T23:59:59.000Z

    The product qualification subtask of the West Valley Support Task (WVST) at Pacific Northwest Laboratory (PNL) provides support for the waste form qualification efforts at West Valley Nuclear Services Co. Testing is being conducted to determine waste form chemical durability in support of these efforts. The effects of composition, ferrous/ferric ratio (redox state), thermal history, and groundwater are being investigated. Glasses were tested using modified Materials Characterization Center (MCC) -3 and MCC-1 test methods. Results obtained in fiscal years (FY) 1987 and 1988 are presented here. 13 refs., 27 figs., 36 tabs.

  10. MINERALIZATION OF RADIOACTIVE WASTES BY FLUIDIZED BED STEAM REFORMING (FBSR): COMPARISONS TO VITREOUS WASTE FORMS, AND PERTINENT DURABILITY TESTING

    SciTech Connect (OSTI)

    Jantzen, C

    2008-12-26T23:59:59.000Z

    The Savannah River National Laboratory (SRNL) was requested to generate a document for the Washington State Department of Ecology and the U.S. Environmental Protection Agency that would cover the following topics: (1) A description of the mineral structures produced by Fluidized Bed Steam Reforming (FBSR) of Hanford type Low Activity Waste (LAW including LAWR which is LAW melter recycle waste) waste, especially the cage structured minerals and how they are formed. (2) How the cage structured minerals contain some contaminants, while others become part of the mineral structure (Note that all contaminants become part of the mineral structure and this will be described in the subsequent sections of this report). (3) Possible contaminant release mechanisms from the mineral structures. (4) Appropriate analyses to evaluate these release mechanisms. (5) Why the appropriate analyses are comparable to the existing Hanford glass dataset. In order to discuss the mineral structures and how they bond contaminants a brief description of the structures of both mineral (ceramic) and vitreous waste forms will be given to show their similarities. By demonstrating the similarities of mineral and vitreous waste forms on atomic level, the contaminant release mechanisms of the crystalline (mineral) and amorphous (glass) waste forms can be compared. This will then logically lead to the discussion of why many of the analyses used to evaluate vitreous waste forms and glass-ceramics (also known as glass composite materials) are appropriate for determining the release mechanisms of LAW/LAWR mineral waste forms and how the durability data on LAW/LAWR mineral waste forms relate to the durability data for LAW/LAWR glasses. The text will discuss the LAW mineral waste form made by FBSR. The nanoscale mechanism by which the minerals form will be also be described in the text. The appropriate analyses to evaluate contaminant release mechanisms will be discussed, as will the FBSR test results to date and how they compare to testing performed on LAW glasses. Other details about vitreous waste form durability and impacts of REDuction/OXidation (REDOX) on durability are given in Appendix A. Details about the FBSR process, various pilot scale demonstrations, and applications are given in Appendix B. Details describing all the different leach tests that need to be used jointly to determine the leaching mechanisms of a waste form are given in Appendix C. Cautions regarding the way in which the waste form surface area is measured and in the choice of leachant buffers (if used) are given in Appendix D.

  11. Effect of degree of synthetic lightweight aggregate pre-wetting on the freeze-thaw durability of lightweight concrete

    E-Print Network [OSTI]

    Kanabar, C. N

    1966-01-01T23:59:59.000Z

    an important role in frost resistance of concrete. The moist curing period of the concrete has been found to be of significant importance for the frost resistance in fresh water. But in sea water, the moist curing period has only a small effect on freeze-chaw...EFFECT OF DEGREE OF SYNTHETIC LIGHTWEIGHT AGGREGATE PRE-WETTING ON THE FREEZE-THAW DURABILITY OF LIGHTWEIGHT CONCRETE A Thesis By CHANDRAKANT N. KANABAR Submitted to the Graduate College of the Texas A&M University in partial fulfillment...

  12. Contact Resistance for "End-Contacted" Metal-Graphene and Metal-Nanotube Interfaces from Quantum Mechanics

    E-Print Network [OSTI]

    Goddard III, William A.

    resistance of "end-contacted" metal electrode-graphene and metal electrode-carbon nanotube (CNT) interfaces for five metals, Ti, Pd, Pt, Cu, and Au, based on the first-principles quantum mechanical (QM) density atoms) is 107 k for Ti, 142 k for Pd, 149 k for Pt, 253 k for Cu, and 187 k for Au. This can be compared

  13. Metal-Air Batteries

    SciTech Connect (OSTI)

    Zhang, Jiguang; Bruce, Peter G.; Zhang, Gregory

    2011-08-01T23:59:59.000Z

    Metal-air batteries have much higher specific energies than most currently available primary and rechargeable batteries. Recent advances in electrode materials and electrolytes, as well as new designs on metal-air batteries, have attracted intensive effort in recent years, especially in the development of lithium-air batteries. The general principle in metal-air batteries will be reviewed in this chapter. The materials, preparation methods, and performances of metal-air batteries will be discussed. Two main metal-air batteries, Zn-air and Li-air batteries will be discussed in detail. Other type of metal-air batteries will also be described.

  14. Clean Metal Casting

    SciTech Connect (OSTI)

    Makhlouf M. Makhlouf; Diran Apelian

    2002-02-05T23:59:59.000Z

    The objective of this project is to develop a technology for clean metal processing that is capable of consistently providing a metal cleanliness level that is fit for a given application. The program has five tasks: Development of melt cleanliness assessment technology, development of melt contamination avoidance technology, development of high temperature phase separation technology, establishment of a correlation between the level of melt cleanliness and as cast mechanical properties, and transfer of technology to the industrial sector. Within the context of the first task, WPI has developed a standardized Reduced Pressure Test that has been endorsed by AFS as a recommended practice. In addition, within the context of task1, WPI has developed a melt cleanliness sensor based on the principles of electromagnetic separation. An industrial partner is commercializing the sensor. Within the context of the second task, WPI has developed environmentally friendly fluxes that do not contain fluorine. Within the context of the third task, WPI modeled the process of rotary degassing and verified the model predictions with experimental data. This model may be used to optimize the performance of industrial rotary degassers. Within the context of the fourth task, WPI has correlated the level of melt cleanliness at various foundries, including a sand casting foundry, a permanent mold casting foundry, and a die casting foundry, to the casting process and the resultant mechanical properties. This is useful in tailoring the melt cleansing operations at foundries to the particular casting process and the desired properties of cast components.

  15. Method of making metal matrix composites reinforced with ceramic particulates

    DOE Patents [OSTI]

    Cornie, James A. (North Chelmsford, MA); Kattamis, Theodoulos (Watertown, MA); Chambers, Brent V. (Cambridge, MA); Bond, Bruce E. (Bedford, MA); Varela, Raul H. (Canton, MA)

    1989-01-01T23:59:59.000Z

    Composite materials and methods for making such materials are disclosed in which dispersed ceramic particles are at chemical equilibrium with a base metal matrix, thereby permitting such materials to be remelted and subsequently cast or otherwise processed to form net weight parts and other finished (or semi-finished) articles while maintaining the microstructure and mechanical properties (e.g. wear resistance or hardness) of the original composite. The composite materials of the present invention are composed of ceramic particles in a base metal matrix. The ceramics are preferably carbides of titanium, zirconium, tungsten, molybdenum or other refractory metals. The base metal can be iron, nickel, cobalt, chromium or other high temperature metal and alloys thereof. For ferrous matrices, alloys suitable for use as the base metal include cast iron, carbon steels, stainless steels and iron-based superalloys.

  16. Method of making metal matrix composites reinforced with ceramic particulates

    DOE Patents [OSTI]

    Cornie, J.A.; Kattamis, T.; Chambers, B.V.; Bond, B.E.; Varela, R.H.

    1989-08-01T23:59:59.000Z

    Composite materials and methods for making such materials are disclosed in which dispersed ceramic particles are at chemical equilibrium with a base metal matrix, thereby permitting such materials to be remelted and subsequently cast or otherwise processed to form net weight parts and other finished (or semi-finished) articles while maintaining the microstructure and mechanical properties (e.g. wear resistance or hardness) of the original composite. The composite materials of the present invention are composed of ceramic particles in a base metal matrix. The ceramics are preferably carbides of titanium, zirconium, tungsten, molybdenum or other refractory metals. The base metal can be iron, nickel, cobalt, chromium or other high temperature metal and alloys thereof. For ferrous matrices, alloys suitable for use as the base metal include cast iron, carbon steels, stainless steels and iron-based superalloys. 2 figs.

  17. Metal phthalocyanine catalysts

    DOE Patents [OSTI]

    Ellis, Jr., Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA)

    1994-01-01T23:59:59.000Z

    As a new composition of matter, alkali metal or ammonium or tetraalkylammonium diazidoperfluorophthalocyanatoferrate. Other embodiments of the invention comprise compositions wherein the metal of the coordination complex is cobalt, manganese and chromium.

  18. Liquid Metal Transformers

    E-Print Network [OSTI]

    Sheng, Lei; Liu, Jing

    2014-01-01T23:59:59.000Z

    The room temperature liquid metal is quickly emerging as an important functional material in a variety of areas like chip cooling, 3D printing or printed electronics etc. With diverse capabilities in electrical, thermal and flowing behaviors, such fluid owns many intriguing properties that had never been anticipated before. Here, we show a group of unconventional phenomena occurring on the liquid metal objects. Through applying electrical field on the liquid metals immersed in water, a series of complex transformation behaviors such as self-assembling of a sheet of liquid metal film into a single sphere, quick mergences of separate metal droplets, controlled self-rotation and planar locomotion of liquid metal objects can be realized. Meanwhile, it was also found that two accompanying water vortexes were induced and reliably swirled near the rotating liquid metal sphere. Further, effects of the shape, size, voltage, orientation and geometries of the electrodes to control the liquid metal transformers were clar...

  19. Metal-carbon nanostructures

    SciTech Connect (OSTI)

    Puretzky, A.A.; Hettich, R.L.; Jin, Changming; Haufler, R.E.; Compton, R.N. [Oak Ridge National Lab., TN (United States); Tuinman, A.A. [Tennessee Univ., Knoxville, TN (United States). Dept. of Chemistry

    1993-12-31T23:59:59.000Z

    Ultrafine particles formed by XeCl laser photolysis of M(CO){sub 6}, M = V, Cr, Mo, and W, have been analyzed by Fourier transform mass spectrometry and other techniques. Novel metal carbide clusters, (MoC{sub 4}){sub n}, n = 1 {minus} 4 and (WC{sub 4}){sub m}, m = 1 {minus} 8, were detected and studied. The material produced by photolysis of V(CO){sub 6} shows a series of vanadium-oxygen clusters, V{sub x}O{sub 2x+2}, x = 2 {minus} 10. No clusters of any type were detected in the photolysis product of Cr(CO){sub 6}. Structures based on the experimental evidence are proposed and discussed in light of their chemical reactivity.

  20. PHYTOEXTRACTION OF HEAVY METALS

    E-Print Network [OSTI]

    Blouin-Demers, Gabriel

    Plants Chelating agents Pb hyperaccumulation Effects of pH on metal extraction Disposal options contaminants from soils Contaminants must be in harvestable portions of the plant (Wongkongkatep et al. 2003) Chelating Agents: desorb heavy metals from soil matrix and form water-soluble metal complexes (Shen et al

  1. Extraction of trace metals from fly ash

    DOE Patents [OSTI]

    Blander, Milton (Palos Park, IL); Wai, Chien M. (Moscow, ID); Nagy, Zoltan (Woodridge, IL)

    1984-01-01T23:59:59.000Z

    A process for recovering silver, gallium and/or other trace metals from a fine grained industrial fly ash associated with a process for producing phosphorous, the fly ash having a silicate base and containing surface deposits of the trace metals as oxides, chlorides or the like, with the process being carried out by contacting the fly ash with AlCl.sub.3 in an alkali halide melt to react the trace metals with the AlCl.sub.3 to form compositions soluble in the melt and a residue containing the silicate and aluminum oxide or other aluminum precipitate, and separating the desired trace metal or metals from the melt by electrolysis or other separation techniques.

  2. Extraction of trace metals from fly ash

    DOE Patents [OSTI]

    Blander, M.; Wai, C.M.; Nagy, Z.

    1983-08-15T23:59:59.000Z

    A process is described for recovering silver, gallium and/or other trace metals from a fine grained industrial fly ash associated with a process for producing phosphorous. The fly ash has a silicate base and contains surface deposits of the trace metals as oxides, chlorides or the like. The process is carried out by contacting the fly ash with AlCl/sub 3/ in an alkali halide melt to react the trace metals with the AlCl/sub 3/ to form compositions soluble in the melt and a residue containing the silicate and aluminum oxide or other aluminum precipitate, and separating the desired trace metal or metals from the melt by electrolysis or other separation techniques.

  3. Determination of Interfacial Adhesion Strength between Oxide Scale and Substrate for Metallic SOFC Interconnects

    SciTech Connect (OSTI)

    Sun, Xin; Liu, Wenning N.; Stephens, Elizabeth V.; Khaleel, Mohammad A.

    2008-01-21T23:59:59.000Z

    The interfacial adhesion strength between the oxide scale and the substrate is crucial to the reliability and durability of metallic interconnects in SOFC operating environments. It is necessary, therefore, to establish a methodology to quantify the interfacial adhesion strength between the oxide scale and the metallic interconnect substrate, and furthermore to design and optimize the interconnect material as well as the coating materials to meet the design life of an SOFC system. In this paper, we present an integrated experimental/analytical methodology for quantifying the interfacial adhesion strength between oxide scale and a ferritic stainless steel interconnect. Stair-stepping indentation tests are used in conjunction with subsequent finite element analyses to predict the interfacial strength between the oxide scale and Crofer 22 APU substrate.

  4. Composite Metal-hydrogen Electrodes for Metal-Hydrogen Batteries

    SciTech Connect (OSTI)

    Ruckman, M W; Wiesmann, H; Strongin, M; Young, K; Fetcenko, M

    1997-04-01T23:59:59.000Z

    The purpose of this project is to develop and conduct a feasibility study of metallic thin films (multilayered and alloy composition) produced by advanced sputtering techniques for use as anodes in Ni-metal hydrogen batteries. The anodes could be incorporated in thin film solid state Ni-metal hydrogen batteries that would be deposited as distinct anode, electrolyte and cathode layers in thin film devices. The materials could also be incorporated in secondary consumer batteries (i.e. type AF(4/3 or 4/5)) which use electrodes in the form of tapes. The project was based on pioneering studies of hydrogen uptake by ultra-thin Pd-capped metal-hydrogen ratios exceeding and fast hydrogen charging and Nb films, these studies suggested that materials with those of commercially available metal hydride materials discharging kinetics could be produced. The project initially concentrated on gas phase and electrochemical studies of Pd-capped niobium films in laboratory-scale NiMH cells. This extended the pioneering work to the wet electrochemical environment of NiMH batteries and exploited advanced synchrotron radiation techniques not available during the earlier work to conduct in-situ studies of such materials during hydrogen charging and discharging. Although batteries with fast charging kinetics and hydrogen-metal ratios approaching unity could be fabricated, it was found that oxidation, cracking and corrosion in aqueous solutions made pure Nb films-and multiiayers poor candidates for battery application. The project emphasis shifted to alloy films based on known elemental materials used for NiMH batteries. Although commercial NiMH anode materials contain many metals, it was found that 0.24 µm thick sputtered Zr-Ni films cycled at least 50 times with charging efficiencies exceeding 95% and [H]/[M] ratios of 0.7-1.0. Multilayered or thicker Zr-Ni films could be candidates for a thin film NiMH battery that may have practical applications as an integrated power source for modern electronic devices.

  5. Liquid Metal Transformers

    E-Print Network [OSTI]

    Lei Sheng; Jie Zhang; Jing Liu

    2014-01-30T23:59:59.000Z

    The room temperature liquid metal is quickly emerging as an important functional material in a variety of areas like chip cooling, 3D printing or printed electronics etc. With diverse capabilities in electrical, thermal and flowing behaviors, such fluid owns many intriguing properties that had never been anticipated before. Here, we show a group of unconventional phenomena occurring on the liquid metal objects. Through applying electrical field on the liquid metals immersed in water, a series of complex transformation behaviors such as self-assembling of a sheet of liquid metal film into a single sphere, quick mergences of separate metal droplets, controlled self-rotation and planar locomotion of liquid metal objects can be realized. Meanwhile, it was also found that two accompanying water vortexes were induced and reliably swirled near the rotating liquid metal sphere. Further, effects of the shape, size, voltage, orientation and geometries of the electrodes to control the liquid metal transformers were clarified. Such events are hard to achieve otherwise on rigid metal or conventional liquid spheres. This finding has both fundamental and practical significances which suggest a generalized way of making smart soft machine, collecting discrete metal fluids, as well as flexibly manipulating liquid metal objects including accompanying devices.

  6. Extraction process for removing metallic impurities from alkalide metals

    DOE Patents [OSTI]

    Royer, Lamar T. (Knoxville, TN)

    1988-01-01T23:59:59.000Z

    A development is described for removing metallic impurities from alkali metals by employing an extraction process wherein the metallic impurities are extracted from a molten alkali metal into molten lithium metal due to the immiscibility of the alkali metals in lithium and the miscibility of the metallic contaminants or impurities in the lithium. The purified alkali metal may be readily separated from the contaminant-containing lithium metal by simple decanting due to the differences in densities and melting temperatures of the alkali metals as compared to lithium.

  7. Microscale Laser Shock Processing (LSP) of Metal Thin Films Wenwu Zhang*

    E-Print Network [OSTI]

    Yao, Y. Lawrence

    surfaces is the major cause of failure for silicon-based micro-engines, while tungsten-coated polysilicon of these metal microstructures, such as micro- electromechanical actuators, metal gears, and metal switches the confining medium (such as water) onto a metallic surface, which is applied with a sacrificial coating

  8. A Science-Based Approach to Understanding Waste Form Durability in Open and Closed Nuclear Fuel Cycles

    SciTech Connect (OSTI)

    Peters, M.T. [Applied Science and Technology, Argonne National Laboratory, 9700 South Cass Ave., Argonne, IL, 60439 (United States); Ewing, R.C. [Department of Geological Sciences, The University of Michigan, 2534 C.C. Little Bldg., 1100 N. University, Ann Arbor, MI, 48109-1005 (United States)

    2007-07-01T23:59:59.000Z

    There are two compelling reasons for understanding source term and near-field processes in a radioactive waste geologic repository. First, almost all of the radioactivity is initially in the waste form, mainly in the spent nuclear fuel (SNF) or nuclear waste glass. Second, over long periods, after the engineered barriers are degraded, the waste form is a primary control on the release of radioactivity. Thus, it is essential to know the physical and chemical state of the waste form after hundreds of thousands of years. The United States Department of Energy's Yucca Mountain Repository Program has initiated a long-term program to develop a basic understanding of the fundamental mechanisms of radionuclide release and a quantification of the release as repository conditions evolve over time. Specifically, the research program addresses four critical areas: a) SNF dissolution mechanisms and rates; b) formation and properties of U{sup 6+}- secondary phases; c) waste form-waste package interactions in the near-field; and d) integration of in-package chemical and physical processes. The ultimate goal is to integrate the scientific results into a larger scale model of source term and near-field processes. This integrated model will be used to provide a basis for understanding the behavior of the source term over long time periods (greater than 10{sup 5} years). Such a fundamental and integrated experimental and modeling approach to source term processes can also be readily applied to development of advanced waste forms as part of a closed nuclear fuel cycle. Specifically, a fundamental understanding of candidate waste form materials stability in high temperature/high radiation environments and near-field geochemical/hydrologic processes could enable development of advanced waste forms 'tailored' to specific geologic settings. (authors)

  9. Modeling of Damage in Cement-Based Materials Subjected to External Sulfate Attack. I: Formulation

    E-Print Network [OSTI]

    Mobasher, Barzin

    Modeling of Damage in Cement-Based Materials Subjected to External Sulfate Attack. I: Formulation subject headings: Damage; Models; Sulfates; Cements. Introduction A majority of the durability issues. Portland cement-based materials subjected to attack from external sulfates may suffer from two types of dam

  10. Metal-Organic Frameworks Based on Main Group Metals

    E-Print Network [OSTI]

    Zhao, Xiang

    2011-01-01T23:59:59.000Z

    and gravimetric hydrogen storage capacity. 23 Unfortunately,storage. Such binding energy is very important for the near room temperature adsorption of hydrogen

  11. Metal-Organic Frameworks Based on Main Group Metals

    E-Print Network [OSTI]

    Zhao, Xiang

    2011-01-01T23:59:59.000Z

    2009, 38, Banerjee, D. ; Parise, J. B. Cryst. Growth Des.Banerjee, D. ; Kim, S. J. ; Parise, J. B. Cryst. Growth Des.L. A. ; Kim, S. J. ; Parise, J. B. Cryst. Growth Des. 2009,

  12. Metal-Organic Frameworks Based on Main Group Metals

    E-Print Network [OSTI]

    Zhao, Xiang

    2011-01-01T23:59:59.000Z

    aip + sdc NPO CPM-8 [NMe 2 ] 10 [In 10 (pdc) 16 (bpdc)4 ]·solvent pdc + bpdc JS-MOP CPM-9 [NMe 2 ] 10 [In 10 (pdc) 16 (1,4-ndc) 4 ]·solvent pdc +

  13. Method of producing solution-derived metal oxide thin films

    DOE Patents [OSTI]

    Boyle, Timothy J. (Albuquerque, NM); Ingersoll, David (Albuquerque, NM)

    2000-01-01T23:59:59.000Z

    A method of preparing metal oxide thin films by a solution method. A .beta.-metal .beta.-diketonate or carboxylate compound, where the metal is selected from groups 8, 9, 10, 11, and 12 of the Periodic Table, is solubilized in a strong Lewis base to form a homogeneous solution. This precursor solution forms within minutes and can be deposited on a substrate in a single layer or a multiple layers to form a metal oxide thin film. The substrate with the deposited thin film is heated to change the film from an amorphous phase to a ceramic metal oxide and cooled.

  14. Long-term treatment with the pure anti-estrogen fulvestrant durably remodels estrogen signaling in BG-1 ovarian cancer cells

    E-Print Network [OSTI]

    Boyer, Edmond

    ovarian cancers are estrogen-positive and hormonal treatments using anti-estrogens or aromatase inhibitors1 Long-term treatment with the pure anti-estrogen fulvestrant durably remodels estrogen signaling in BG-1 ovarian cancer cells Eric Badia1* , Aurélie Docquier1 , Muriel Busson1 , Marion Lapierre1

  15. Long-Term Durability of a 20 mil PVC Geomembrane E. J. NEWMAN & T. D. STARK, Dept. of Civ. & Environmental Engrg., Univ. of Illinois,

    E-Print Network [OSTI]

    Long-Term Durability of a 20 mil PVC Geomembrane E. J. NEWMAN & T. D. STARK, Dept. of Civ a 0.51 mm thick fish grade PVC geomembrane. A fish grade PVC geomembrane is specially formulated to promote aquatic life through the omission of biocides from the basic PVC geomembrane formulation that may

  16. Standard test methods for determining chemical durability of nuclear, hazardous, and mixed waste glasses and multiphase glass ceramics: The product consistency test (PCT)

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2002-01-01T23:59:59.000Z

    1.1 These product consistency test methods A and B evaluate the chemical durability of homogeneous glasses, phase separated glasses, devitrified glasses, glass ceramics, and/or multiphase glass ceramic waste forms hereafter collectively referred to as “glass waste forms” by measuring the concentrations of the chemical species released to a test solution. 1.1.1 Test Method A is a seven-day chemical durability test performed at 90 ± 2°C in a leachant of ASTM-Type I water. The test method is static and conducted in stainless steel vessels. Test Method A can specifically be used to evaluate whether the chemical durability and elemental release characteristics of nuclear, hazardous, and mixed glass waste forms have been consistently controlled during production. This test method is applicable to radioactive and simulated glass waste forms as defined above. 1.1.2 Test Method B is a durability test that allows testing at various test durations, test temperatures, mesh size, mass of sample, leachant volume, a...

  17. Durability Prediction of Solid Oxide Fuel Cell Anode Material under Thermo-Mechanical and Fuel Gas Contaminants Effects

    SciTech Connect (OSTI)

    Iqbal, Gulfam; Guo, Hua; Kang , Bruce S.; Marina, Olga A.

    2011-01-10T23:59:59.000Z

    Solid Oxide Fuel Cells (SOFCs) operate under harsh environments, which cause deterioration of anode material properties and service life. In addition to electrochemical performance, structural integrity of the SOFC anode is essential for successful long-term operation. The SOFC anode is subjected to stresses at high temperature, thermal/redox cycles, and fuel gas contaminants effects during long-term operation. These mechanisms can alter the anode microstructure and affect its electrochemical and structural properties. In this research, anode material degradation mechanisms are briefly reviewed and an anode material durability model is developed and implemented in finite element analysis. The model takes into account thermo-mechanical and fuel gas contaminants degradation mechanisms for prediction of long-term structural integrity of the SOFC anode. The proposed model is validated experimentally using a NexTech ProbostatTM SOFC button cell test apparatus integrated with a Sagnac optical setup for simultaneously measuring electrochemical performance and in-situ anode surface deformation.

  18. Comparative Study on the Corrosion Resistance of Fe-Based Amorphous Metal, Borated Stainless Steel and Ni-Cr-Mo-Gd Alloy

    SciTech Connect (OSTI)

    Lian, Tiangan; Day, Daniel; Hailey, Phillip; Choi, Jor-Shan; Farmer, Joseph [Lawrence Livermore National Laboratory, Livermore, CA, 94550 (United States)

    2007-07-01T23:59:59.000Z

    Iron-based amorphous alloy Fe{sub 49.7}Cr{sub 17.7}Mn{sub 1.9}Mo{sub 7.4}W{sub 1.6}B{sub 15.2}C{sub 3.8}Si{sub 2.4} was compared to borated stainless steel and Ni-Cr-Mo-Gd alloy on their corrosion resistance in various high-concentration chloride solutions. The melt-spun ribbon of this iron-based amorphous alloy have demonstrated a better corrosion resistance than the bulk borated stainless steel and the bulk Ni-Cr-Mo-Gd alloy, in high-concentration chloride brines at temperatures 90 deg. C or higher. (authors)

  19. Cr-free Fe-based metal oxide catalysts for high temperature water gas shift reaction of fuel processor using LPG

    SciTech Connect (OSTI)

    lee, Joon Y.; Lee, Dae-Won; Lee, Kwan Young; Wang, Yong

    2009-08-15T23:59:59.000Z

    The goal of this study was to identify the most suitable chromium-free iron-based catalysts for the HTS (high temperature shift) reaction of a fuel processor using LPG. Hexavalent chromium (Cr6+) in the commercial HTS catalyst has been regarded as hazardous material. We selected Ni and Co as the substitution for chromium in the Fe-based HTS catalyst and investigated the HTS activities of these Crfree catalysts at LPG reformate condition. Cr-free Fe-based catalysts which contain Ni, Zn, or Co instead of Cr were prepared by coprecipitation method and the performance of the catalysts in HTS was evaluated under gas mixture conditions (42% H2, 10% CO, 37% H2O, 8% CO2, and 3% CH4; R (reduction factor): about 1.2) similar to the gases from steam reforming of LPG (100% conversion at steam/carbon ratio = 3), which is higher than R (under 1) of typically studied LNG reformate condition. Among the prepared Cr-free Febased catalysts, the 5 wt%-Co/Fe/20 wt%-Ni and 5 wt%-Zn/Fe/20 wt%-Ni catalysts showed good catalytic activity under this reaction condition simulating LPG reformate gas.

  20. Metal atomization spray nozzle

    DOE Patents [OSTI]

    Huxford, T.J.

    1993-11-16T23:59:59.000Z

    A spray nozzle for a magnetohydrodynamic atomization apparatus has a feed passage for molten metal and a pair of spray electrodes mounted in the feed passage. The electrodes, diverging surfaces which define a nozzle throat and diverge at an acute angle from the throat. Current passes through molten metal when fed through the throat which creates the Lorentz force necessary to provide atomization of the molten metal. 6 figures.

  1. Incinerator residue in bituminous base construction

    E-Print Network [OSTI]

    Haynes, Joseph Anthony

    1975-01-01T23:59:59.000Z

    for use of the material in a bituminous base. Preliminary investigation on the optimum mix design included Hveem stability, Marshall stability and Durability tests, A test section consisting of the experimental hot-mixed pavement, littercrete, and a... for flexural fatigue tests, Hveem and Marshall stabilities, thermal expansion, direct tension, splitting tensile and Schmidt tests. Four in. (10. 2 cm. ) diameter cores were taken after compaction (before traffic) and after six months in service. Samples...

  2. Influence of surface defects and local structure on acid/base properties and oxidation pathways over metal oxide surfaces. Final report, June 1990--January 1997

    SciTech Connect (OSTI)

    Cox, D.F.

    1997-12-31T23:59:59.000Z

    This final report covers work done during project period one and project period two. All the work in project period one was focused on the selective oxidation of oxygenated hydrocarbons over the SnO{sub 2}(110) single crystal surface. In project period two, the emphasis was on the acid/base properties of SnO{sub 2}(110) as well as two different Cu{sub 2}O single crystal surfaces. Prior to the summary of results, a description of these different surfaces is given as background information. Results are described for the dissociation and reaction of Bronsted acids (methanol, formic acid, water, formaldehyde, acetone, propene, acetic acid, and carbon monoxide). Results from project period two include: ammonia adsorption, CO{sub 2} adsorption, propene adsorption and oxidation, with tin oxides; complimentary work with copper oxides; and STM investigations.

  3. A Comparison of the Corrosion Resistance of Iron-Based Amorphous Metals and Austenitic Alloys in Synthetic Brines at Elevated Temperature

    SciTech Connect (OSTI)

    Farmer, J C

    2008-11-25T23:59:59.000Z

    Several hard, corrosion-resistant and neutron-absorbing iron-based amorphous alloys have now been developed that can be applied as thermal spray coatings. These new alloys include relatively high concentrations of Cr, Mo, and W for enhanced corrosion resistance, and substantial B to enable both glass formation and neutron absorption. The corrosion resistances of these novel alloys have been compared to that of several austenitic alloys in a broad range of synthetic brines, with and without nitrate inhibitor, at elevated temperature. Linear polarization and electrochemical impedance spectroscopy have been used for in situ measurement of corrosion rates for prolonged periods of time, while scanning electron microscopy (SEM) and energy dispersive analysis of X-rays (EDAX) have been used for ex situ characterization of samples at the end of tests. The application of these new coatings for the protection of spent nuclear fuel storage systems, equipment in nuclear service, steel-reinforced concrete will be discussed.

  4. A novel plating process for microencapsulating metal hydrides

    SciTech Connect (OSTI)

    Law, H.H.; Vyas, B.; Zahurak, S.M.; Kammlott, G.W. [AT and T Bell Labs., Murray Hill, NJ (United States)

    1996-08-01T23:59:59.000Z

    One approach to increasing the lifetime of the metal hydride electrode has been the use of conventional electroless plating to produce a coating of copper or nickel on the surface of the metal hydride powders. In this paper, a novel method for microencapsulating the active electrode powders is presented. This new plating technique takes advantage of the reducing power of hydrogen already stored inside the metal hydride to plate a variety of metals onto metal hydride materials. This method greatly simplifies electroless plating for these powders, eliminating the need for stabilizers and additives typically required for conventional electroless plating solutions. Metals that can be electrolessly plated with stored hydrogen have been identified based on thermodynamic considerations. Experimentally, micrometers thick coatings of copper, silver, and nickel have been plated on several metal hydrides.

  5. FY05 HPCRM Annual Report: High-Performance Corrosion-Resistant Iron-Based Amorphous Metal Coatings Evaluation of Corrosion Reistance FY05 HPCRM Annual Report # Rev. 1DOE-DARPA Co-Sponsored Advanced Materials Program

    SciTech Connect (OSTI)

    Farmer, J C; Haslam, J J; Day, S D

    2007-09-19T23:59:59.000Z

    New corrosion-resistant, iron-based amorphous metals have been identified from published data or developed through combinatorial synthesis, and tested to determine their relative corrosion resistance. Many of these materials can be applied as coatings with advanced thermal spray technology. Two compositions have corrosion resistance superior to wrought nickel-based Alloy C-22 (UNS No. N06022) in some very aggressive environments, including concentrated calcium-chloride brines at elevated temperature. Two Fe-based amorphous metal formulations have been found that appear to have corrosion resistance comparable to, or better than that of Ni-based Alloy C-22, based on breakdown potential and corrosion rate. Both Cr and Mo provide corrosion resistance, B enables glass formation, and Y lowers critical cooling rate (CCR). SAM1651 has yttrium added, and has a nominal critical cooling rate of only 80 Kelvin per second, while SAM2X7 (similar to SAM2X5) has no yttrium, and a relatively high critical cooling rate of 610 Kelvin per second. Both amorphous metal formulations have strengths and weaknesses. SAM1651 (yttrium added) has a low critical cooling rate (CCR), which enables it to be rendered as a completely amorphous thermal spray coating. Unfortunately, it is relatively difficult to atomize, with powders being irregular in shape. This causes the powder to be difficult to pneumatically convey during thermal spray deposition. Gas atomized SAM1651 powder has required cryogenic milling to eliminate irregularities that make flow difficult. SAM2X5 (no yttrium) has a high critical cooling rate, which has caused problems associated with devitrification. SAM2X5 can be gas atomized to produce spherical powders of SAM2X5, which enable more facile thermal spray deposition. The reference material, nickel-based Alloy C-22, is an outstanding corrosion-resistant engineering material. Even so, crevice corrosion has been observed with C-22 in hot sodium chloride environments without buffer or inhibitor. Comparable metallic alloys such as SAM2X5 and SAM1651 may also experience crevice corrosion under sufficiently harsh conditions. Accelerated crevice corrosion tests are now being conducted to intentionally induce crevice corrosion, and to determine those environmental conditions where such localized attack occurs. Such materials are extremely hard, and provide enhanced resistance to abrasion and gouges (stress risers) from backfill operations, and possibly even tunnel boring. The hardness of Type 316L Stainless Steel is approximately 150 VHN, that of Alloy C-22 is approximately 250 VHN, and that of HVOF SAM2X5 ranges from 1100-1300 VHN. These new materials provide a viable coating option for repository engineers. SAM2X5 and SAM1651 coatings can be applied with thermal spray processes without any significant loss of corrosion resistance. Both Alloy C-22 and Type 316L stainless lose their resistance to corrosion during thermal spraying. Containers for the transportation, storage and disposal of spent nuclear fuel (SNF) and high-level radioactive waste (HLW) with corrosion resistant coatings are envisioned. For example, an enhanced multi-purpose container (MPC) could be made with such coatings, leveraging existing experience in the fabrication of such containers. These coating materials could be used to protect the final closure weld on SNF/HLW disposal containers, eliminate need for stress mitigation. Integral drip shield could be produced by directly spraying it onto the disposal container, thereby eliminating the need for an expensive titanium drip shield. In specific areas where crevice corrosion is anticipated, such as the contact point between the disposal container and pallet, HVOF coatings could be used to buildup thickness, thereby selectively adding corrosion life where it is needed. Both SAM2X5 & SAM1651 have high boron content which enable them to absorb neutrons and therefore be used for criticality control in baskets. Alloy C-22 and 316L have no neutron absorber, and cannot be used for such functions. Borated stainless steel and G

  6. Heavy Metal Humor: Reconsidering Carnival in Heavy Metal Culture

    E-Print Network [OSTI]

    Powell, Gary Botts

    2013-06-05T23:59:59.000Z

    This thesis considers Bakhtin?s carnivalesque theory by analyzing comedic rhetoric performed by two comedic metal bands. Through the theories of Johan Huizinga and Mikhail Bakhtin, Chapter I: I Play Metal argues that heavy metal culture is a modern...

  7. Transition Metal Dopants Essential for Producing Ferromagnetism...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Metal Dopants Essential for Producing Ferromagnetism in Metal Oxide Nanoparticles. Transition Metal Dopants Essential for Producing Ferromagnetism in Metal Oxide Nanoparticles....

  8. Metal roofing Shingle roofing

    E-Print Network [OSTI]

    Hutcheon, James M.

    Metal roofing panel Shingle roofing Water & ice barrier Thermal Barrier Plywood Student: Arpit between the roof and the attic. · Apply modifications to traditional roofing assembly and roofing roof with only a water barrier between the plywood and the roofing panels. Metal roofing panel Shingle

  9. Porous metallic bodies

    DOE Patents [OSTI]

    Landingham, R.L.

    1984-03-13T23:59:59.000Z

    Porous metallic bodies having a substantially uniform pore size of less than about 200 microns and a density of less than about 25 percent theoretical, as well as the method for making them, are disclosed. Group IIA, IIIB, IVB, VB, and rare earth metal hydrides a

  10. Influence of Aluminum Content on Grain Refinement and Strength of AZ31 Magnesium GTA Weld Metal

    SciTech Connect (OSTI)

    Babu, N. Kishore [Singapore Institute of Manufacturing Technology; Cross, Carl E. [Los Alamos National Laboratory

    2012-06-28T23:59:59.000Z

    The goal is to characterize the effect of Al content on AZ31 weld metal, the grain size and strength, and examine role of Al on grain refinement. The approach is to systematically vary the aluminum content of AZ31 weld metal, Measure average grain size in weld metal, and Measure cross-weld tensile properties and hardness. Conclusions are that: (1) increased Al content in AZ31 weld metal results in grain refinement Reason: higher undercooling during solidification; (2) weld metal grain refinement resulted in increased strength & hardness Reason: grain boundary strengthening; and (3) weld metal strength can be raised to wrought base metal levels.

  11. Effects of the Exposure to Corrosive Salts on the Frictional Behavior of Gray Cast Iron and a Titanium-Based Metal Matrix Composite

    SciTech Connect (OSTI)

    Blau, Peter Julian [ORNL; Truhan, Jr., John J [ORNL; Kenik, Edward A [ORNL

    2007-01-01T23:59:59.000Z

    The introduction of increasingly aggressive road-deicing chemicals has created significant and costly corrosion problems for the trucking industry. From a tribological perspective, corrosion of the sliding surfaces of brakes after exposure to road salts can create oxide scales on the surfaces that affect friction. This paper describes experiments on the effects of exposure to sodium chloride and magnesium chloride sprays on the transient frictional behavior of cast iron and a titanium-based composite sliding against a commercial brake lining material. Corrosion scales on cast iron initially act as abrasive third-bodies, then they become crushed, spread out, and behave as a solid lubricant. The composition and subsurface microstructures of the corrosion products on the cast iron were analyzed. Owing to its greater corrosion resistance, the titanium composite remained scale-free and its frictional response was markedly different. No corrosion scales were formed on the titanium composite after aggressive exposure to salts; however, a reduction in friction was still observed. Unlike the crystalline sodium chloride deposits that tended to remain dry, hygroscopic magnesium chloride deposits absorbed ambient moisture from the air, liquefied, and retained a persistent lubricating effect on the titanium surfaces.

  12. Rechargeable Lithium-Air Batteries: Development of Ultra High Specific Energy Rechargeable Lithium-Air Batteries Based on Protected Lithium Metal Electrodes

    SciTech Connect (OSTI)

    None

    2010-07-01T23:59:59.000Z

    BEEST Project: PolyPlus is developing the world’s first commercially available rechargeable lithium-air (Li-Air) battery. Li-Air batteries are better than the Li-Ion batteries used in most EVs today because they breathe in air from the atmosphere for use as an active material in the battery, which greatly decreases its weight. Li-Air batteries also store nearly 700% as much energy as traditional Li-Ion batteries. A lighter battery would improve the range of EVs dramatically. Polyplus is on track to making a critical breakthrough: the first manufacturable protective membrane between its lithium–based negative electrode and the reaction chamber where it reacts with oxygen from the air. This gives the battery the unique ability to recharge by moving lithium in and out of the battery’s reaction chamber for storage until the battery needs to discharge once again. Until now, engineers had been unable to create the complex packaging and air-breathing components required to turn Li-Air batteries into rechargeable systems.

  13. Charge transfer from an adsorbed ruthenium-based photosensitizer through an ultra-thin aluminium oxide layer and into a metallic substrate

    E-Print Network [OSTI]

    Gibson, Andrew J; Handrup, Karsten; Weston, Matthew; Mayor, Louise C; O'Shea, James N

    2014-01-01T23:59:59.000Z

    The interaction of the dye molecule N3 (cis-bis(isothiocyanato)bis(2,2-bipyridyl-4,4'-dicarboxylato)-ruthenium(II)) with the ultra-thin oxide layer on a AlNi(110) substrate, has been studied using synchrotron radiation based photoelectron spectroscopy, resonant photoemission spectroscopy (RPES) and near edge X-ray absorption fine structure spectroscopy (NEXAFS). Calibrated X-ray absorption and valence band spectra of the monolayer and multilayer coverages reveal that charge transfer is possible from the molecule to the AlNi(110) substrate via tunnelling through the ultra-thin oxide layer and into the conduction band edge of the substrate. This charge transfer mechanism is possible from the LUMO+2&3 in the excited state but not from the LUMO, therefore enabling core-hole clock analysis, which gives an upper limit of $6.0\\pm$2.5fs for the transfer time. This indicates that ultra-thin oxide layers are a viable material for use in dye-sensitized solar cells (DSSC), which may lead to reduced recombination effe...

  14. Production of magnesium metal

    DOE Patents [OSTI]

    Blencoe, James G. (Harriman, TN) [Harriman, TN; Anovitz, Lawrence M. (Knoxville, TN) [Knoxville, TN; Palmer, Donald A. (Oliver Springs, TN) [Oliver Springs, TN; Beard, James S. (Martinsville, VA) [Martinsville, VA

    2010-02-23T23:59:59.000Z

    A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention further relates to a process for production of magnesium metal or a magnesium compound where an external source of carbon dioxide is not used in any of the reactions of the process. The invention also relates to the magnesium metal produced by the processes described herein.

  15. Epsilon Metal Summary Report FY 2011

    SciTech Connect (OSTI)

    Strachan, Denis M.; Crum, Jarrod V.; Zumhoff, Mac R.; Bovaird, Chase C.; Windisch, Charles F.; Riley, Brian J.

    2011-09-30T23:59:59.000Z

    The Epsilon-metal ({var_epsilon}-metal) phase was selected in FY 2009 as a potential waste form to for immobilizing the noble metals found in the undissolved solids + aqueous stream, and the soluble Tc from ion-exchange process, each resulting from proposed aqueous reprocessing. {var_epsilon}-metal phase is observed in used nuclear fuel and the natural reactors of Oklobono in Gabon, where the long-term corrosion behavior was demonstrated. This makes {var_epsilon}-metal a very attractive waste form. Last fiscal year, {var_epsilon}-metal was successfully fabricated by combining the five-metals, Mo, Ru, Rh, Pd and Re (surrogate for Tc), into pellets followed by consolidation with an arc melter. The arc melter produced fully dense samples with the epsilon structure. However, some chemistry differences were observed in the microstructure that resulted in regions rich in Re and Mo, and others rich in Pd, while Ru and Rh remained fairly constant throughout. This year, thermal stability (air), and corrosion testing of the samples fabricated by arc melting were the main focus for experimental work. Thermal stability was measured with a differential scanning calorimeter - thermogravimetric analyzer, by both ramp heating as well as step heating. There is clear evidence during the ramp heating experiment of an exothermic event + a weight loss peak both beginning at {approx}700 C. Step heating showed an oxidation event at {approx}690 C with minimal weight gain that occurs just before the weight loss event at 700 C. The conclusion being that the e-metal begins to oxidize and then become volatile. These findings are useful for considering the effects of voloxidation process. Three different pellets were subjected to electrochemical testing to study the corrosion behavior of the epsilon-metal phase in various conditions, namely acidic, basic, saline, and inert. Test was done according to an interim procedure developed for the alloy metal waste form. First an open circuit potential was measured, followed by linear polarization sweeps. The linear polarization sweep range was the Tafel equation was fit to the linear polarization sweep data to determine the corrosion rate of each pellet in each test solution. The average calculated corrosion rates of the three pellets according to solution conditions were: -1.91 x 10{sup -4} mm/yr (0.001 M NaOH), -1.48 x 10{sup -3} mm/yr (0.01 M NaCl), -8.77 x 10{sup -4} mm/yr (0.001 M H{sub 2}SO{sub 4}), -2.09 x 10{sup -3} mm/yr (0.001 M NaOH + 0.01 M NaCl), and -1.54 x 10{sup -3} mm/yr (0.001 M H{sub 2}SO{sub 4} + 0.01 M NaCl). Three single-pass flow through (SPFT) test were conducted at a flow rate of 10 ml/day, at 90 C, and pH of 2.5, 7.0, and 9.0 for up to 322 days. Results of the tests indicate that dissolution rates were 5 x 10{sup -4} g m{sup 2} d{sup -1} at pH 9.0, 1.2 x 10{sup -4} g m{sup -2} d{sup -1} at pH 7.0, and 2 x 10{sup -4} g m{sup -2} d{sup -1} at pH 2.5. The sample used for the pH 7.0 SPFT test contains extra Re compared to samples used for the other two SPFT test, which came from a single pellet. The corrosion data measured this year indicate that the {var_epsilon}-metal phase is chemically durable. The two chemically different phases, but structurally the same, behave differently during dissolution according to the microstructure changes observed in both the electrochemical and in SPFT test. Characterization of the test specimens after testing suggests that the dissolution is complex and involves oxidative dissolution followed by precipitation of both oxide and metallic phases. These data suggest that the dissolution in the electrochemical and SPFT tests is different; a process that needs further investigation.

  16. Metal loading and reactivity of Zeolite Y

    E-Print Network [OSTI]

    Sa?enz, Marc Gerard

    1988-01-01T23:59:59.000Z

    . XRD pattern for calcined MoNiY 13. IR spectra for NiY 14. IR spectra for MoNiY 15. HDN product distribution, alumina based catalyst 16. HDN product distribution, zeolite based catalyst 17. Adjusted HDN product distribution, alumina based catalyst...V) are transi- tion metal oxides or sulfides on an alumina support. These catalysts were not specifically developed for hydrodenitrogenaiion but were adopted from hydrocracking or hydrodesul- furization (HDS) processes. HDN is more difficult than HDS; thus...

  17. Studies on the optimization of deformation processed metal metal matrix composites

    SciTech Connect (OSTI)

    Ellis, T.W.

    1994-01-04T23:59:59.000Z

    A methodology for the production of deformation processed metal metal matrix composites from hyper-eutectic copper-chromium alloys was developed. This methodology was derived from a basic study of the precipitation phenomena in these alloys encompassing evaluation of microstructural, electrical, and mechanical properties. The methodology developed produces material with a superior combination of electrical and mechanical properties compared to those presently available in commercial alloys. New and novel alloying procedures were investigated to extend the range of production methods available for these material. These studies focused on the use of High Pressure Gas Atomization and the development of new containment technologies for the liquid alloy. This allowed the production of alloys with a much more refined starting microstructure and lower contamination than available by other methods. The knowledge gained in the previous studies was used to develop two completely new families of deformation processed metal metal matrix composites. These composites are based on immissible alloys with yttrium and magnesium matrices and refractory metal reinforcement. This work extends the physical property range available in deformation processed metal metal matrix composites. Additionally, it also represents new ways to apply these metals in engineering applications.

  18. Volatilization of Fission Products from Metallic Melts in the Melt-Dilute Treatment Technology Development for Al-Based DOE Spent Nuclear Fuels

    SciTech Connect (OSTI)

    Adams, T.

    1999-11-18T23:59:59.000Z

    The melt-dilute treatment technology is being developed to facilitate the ultimate disposition of highly enriched Al-Base DOE spent nuclear fuels in a geologic repository such as that proposed for Yucca Mountain. Currently, approximately 28 MTHM is expected to be returned to the Savannah River Site from domestic and foreign research reactors. The melt-dilute treatment technology will melt the fuel assemblies to reduce their volume and alloys them with depleted uranium to isotopically dilute the 235U concentration. The resulting alloy is cast into a form for long term geologic repository storage. Benefits accrued from the melt-dilute process include the potential for significant volume reduction; reduced criticality potential, and proliferation concerns. A critical technology element in the development of the melt-dilute process is the development of offgas system requirements. The volatilization of radioactive species during the melting stage of the process primarily constitutes the offgas in this process. Several of the species present following irradiation of a fuel assembly have been shown to be volatile or semi-volatile under reactor core melt-down conditions. Some of the key species that have previously been studied are krypton, iodine, and cesium. All of these species have been shown to volatilize during melting experiments however, the degree to which they are released is highly dependent upon atmosphere, fuel burnup, temperature, and fuel composition. With this in mind an analytical and experimental program has been undertaken to assess the volatility and capture of species under the melt-dilute operating conditions.

  19. Amorphous Metallic Glass as New High Power and Energy Density Anodes For Lithium Ion Rechargeable Batteries

    E-Print Network [OSTI]

    Meng, Shirley Y.

    We have investigated the use of aluminum based amorphous metallic glass as the anode in lithium ion rechargeable batteries. Amorphous metallic glasses have no long-range ordered microstructure; the atoms are less closely ...

  20. Cadmium and Zinc Thiolate and Selenolate Metal-Organic Frameworks

    SciTech Connect (OSTI)

    Turner, D.; Stone, K; Stephens, P; Vaid, T

    2010-01-01T23:59:59.000Z

    Metal-organic frameworks based on metal-sulfur or metal-selenium bonds are relatively rare; herein we describe the synthesis and structural characterization of several examples, including, for example, [Cd(en){sub 3}][Cd(SC{sub 6}H{sub 4}S){sub 2}], which contains the anionic two-dimensional square-grid network [Cd(SC{sub 6}H{sub 4}S){sub 2}]{sub n}{sup 2n-}.

  1. IS THERE ROOM FOR DURABLE ANALOG INFORMATION STORAGE IN A DIGITAL WORLD

    SciTech Connect (OSTI)

    R. A. STUTZ; L. HERETH

    2000-09-20T23:59:59.000Z

    Information technology has completely changed our concept of record keeping--the advent of digital records was a momentous discovery, as significant as the invention of the printing press. Digital records allowed huge amounts of information to be stored in a very small space and to be examined quickly. However, digital documents are much more vulnerable to the passage of time than printed documents, because the media on which they are stored are easily affected by physical phenomena, such as magnetic fields, oxidation, material decay, and by various environmental factors that may erase the information. Even more important, digital information becomes obsolete, because even if future generations maybe able to read it, they may not necessarily be able to interpret it. Over the centuries analog documents have been written on solid materials such as stone, clay and metal plates using tools to inscribe the characters. These archival methods have preserved records for centuries, and even millennia, but suffer from low information density. Modem methods facilitate writing pages on smooth material surfaces at high information densities. This writing can generate from about 25 to 100,000 times the area information density of microfilm and work with either analog or digital storage methods. Information of all types is becoming more dependent on digital records. These records are often created and stored on computer systems by scanning in documents or creating them directly on the system. Often analog information (human viewable information) is forced into binary form (ones and zeros). The necessity for the accurate and accessible storage of these documents is increasing for a number of reasons, including legal and environment issues. This paper will discuss information storage life, methods of information storage, media life considerations, and life cycle costs associated with several methods of storage.

  2. Role of the dielectric for the charging dynamics of the dielectric/barrier interface in AlGaN/GaN based metal-insulator-semiconductor structures under forward gate bias stress

    SciTech Connect (OSTI)

    Lagger, P., E-mail: peter.lagger@infineon.com [Infineon Technologies Austria AG, Siemensstraße 2, 9500 Villach (Austria); Institute of Solid State Electronics, Vienna University of Technology, Floragasse 7, 1040 Wien (Austria); Steinschifter, P.; Reiner, M.; Stadtmüller, M.; Denifl, G.; Ostermaier, C. [Infineon Technologies Austria AG, Siemensstraße 2, 9500 Villach (Austria); Naumann, A.; Müller, J.; Wilde, L.; Sundqvist, J. [Fraunhofer IPMS-CNT, Königsbrücker Straße 178, 01099 Dresden (Germany); Pogany, D. [Institute of Solid State Electronics, Vienna University of Technology, Floragasse 7, 1040 Wien (Austria)

    2014-07-21T23:59:59.000Z

    The high density of defect states at the dielectric/III-N interface in GaN based metal-insulator-semiconductor structures causes tremendous threshold voltage drifts, ?V{sub th}, under forward gate bias conditions. A comprehensive study on different dielectric materials, as well as varying dielectric thickness t{sub D} and barrier thickness t{sub B}, is performed using capacitance-voltage analysis. It is revealed that the density of trapped electrons, ?N{sub it}, scales with the dielectric capacitance under spill-over conditions, i.e., the accumulation of a second electron channel at the dielectric/AlGaN barrier interface. Hence, the density of trapped electrons is defined by the charging of the dielectric capacitance. The scaling behavior of ?N{sub it} is explained universally by the density of accumulated electrons at the dielectric/III-N interface under spill-over conditions. We conclude that the overall density of interface defects is higher than what can be electrically measured, due to limits set by dielectric breakdown. These findings have a significant impact on the correct interpretation of threshold voltage drift data and are of relevance for the development of normally off and normally on III-N/GaN high electron mobility transistors with gate insulation.

  3. Preparation of uniform nanoparticles of ultra-high purity metal oxides, mixed metal oxides, metals, and metal alloys

    DOE Patents [OSTI]

    Woodfield, Brian F.; Liu, Shengfeng; Boerio-Goates, Juliana; Liu, Qingyuan; Smith, Stacey Janel

    2012-07-03T23:59:59.000Z

    In preferred embodiments, metal nanoparticles, mixed-metal (alloy) nanoparticles, metal oxide nanoparticles and mixed-metal oxide nanoparticles are provided. According to embodiments, the nanoparticles may possess narrow size distributions and high purities. In certain preferred embodiments, methods of preparing metal nanoparticles, mixed-metal nanoparticles, metal oxide nanoparticles and mixed-metal nanoparticles are provided. These methods may provide tight control of particle size, size distribution, and oxidation state. Other preferred embodiments relate to a precursor material that may be used to form nanoparticles. In addition, products prepared from such nanoparticles are disclosed.

  4. The Behavior and Effects of the Noble Metals in the DWPF Melter System

    SciTech Connect (OSTI)

    Smith, M.E. [Westinghouse Savannah River Company, AIKEN, SC (United States); Bickford, D.F.

    1997-11-30T23:59:59.000Z

    Governments worldwide have committed to stabilization of high-level nuclear waste (HLW) by vitrification to a durable glass form for permanent disposal. All of these nuclear wastes contain the fission-product noble metals: ruthenium, rhodium, and palladium. SRS wastes also contain natural silver from iodine scrubbers. Closely associated with the noble metals are the fission products selenium and tellurium which are chemical analogs of sulfur and which combine with noble metals to influence their behavior and properties. Experience has shown that these melt insoluble metals and their compounds tend to settle to the floor of Joule-heated ceramic melters. In fact, almost all of the major research and production facilities have experienced some operational problem which can be associated with the presence of dense accumulations of these relatively conductive metals and/or their compounds. In most cases, these deposits have led to a loss of production capability, in some cases, to the point that melter operation could not continue. HLW nuclear waste vitrification facilities in the United States are the Department of Energy`s Defense Waste Processing Facility (DWPF) at the Savannah River Site, the planned Hanford Waste Vitrification Plant (HWVP) at the Hanford Site and the operating West Valley Demonstration Project (WVDP) at West Valley, NY. The Integrated DWPF Melter System (IDMS) is a vitrification test facility at the Savannah River Technology Center (SRTC). It was designed and constructed to provide an engineering-scale representation of the DWPF melter and its associated feed preparation and off-gas treatment systems. An extensive noble metals testing program was begun in 1990. The objectives of this task were to explore the effects of the noble metals on the DWPF melter feed preparation and waste vitrification processes. This report focuses on the vitrification portion of the test program.

  5. Liquid metal electric pump

    DOE Patents [OSTI]

    Abbin, J.P.; Andraka, C.E.; Lukens, L.L.; Moreno, J.B.

    1992-01-14T23:59:59.000Z

    An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other. 3 figs.

  6. Actinide metal processing

    DOE Patents [OSTI]

    Sauer, N.N.; Watkin, J.G.

    1992-03-24T23:59:59.000Z

    A process for converting an actinide metal such as thorium, uranium, or plutonium to an actinide oxide material by admixing the actinide metal in an aqueous medium with a hypochlorite as an oxidizing agent for sufficient time to form the actinide oxide material and recovering the actinide oxide material is described together with a low temperature process for preparing an actinide oxide nitrate such as uranyl nitrate. Additionally, a composition of matter comprising the reaction product of uranium metal and sodium hypochlorite is provided, the reaction product being an essentially insoluble uranium oxide material suitable for disposal or long term storage.

  7. Actinide metal processing

    DOE Patents [OSTI]

    Sauer, Nancy N. (Los Alamos, NM); Watkin, John G. (Los Alamos, NM)

    1992-01-01T23:59:59.000Z

    A process of converting an actinide metal such as thorium, uranium, or plnium to an actinide oxide material by admixing the actinide metal in an aqueous medium with a hypochlorite as an oxidizing agent for sufficient time to form the actinide oxide material and recovering the actinide oxide material is provided together with a low temperature process of preparing an actinide oxide nitrate such as uranyl nitrte. Additionally, a composition of matter comprising the reaction product of uranium metal and sodium hypochlorite is provided, the reaction product being an essentially insoluble uranium oxide material suitable for disposal or long term storage.

  8. Transition Metal Switchable Mirror

    ScienceCinema (OSTI)

    None

    2010-01-08T23:59:59.000Z

    The switchable-mirrors technology was developed by Tom Richardson and Jonathan Slack of Berkeley Lab's Environmental Energy Technologies Division. By using transition metals rather than the rare earth metals used in the first metal-hydride switchable mirrors, Richardson and Slack were able to lower the cost and simplify the manufacturing process. Energy performance is improved as well, because the new windows can reflect or transmit both visible and infrared light. Besides windows for offices and homes, possible applications include automobile sunroofs, signs and displays, aircraft windows, and spacecraft.

  9. Transition Metal Switchable Mirror

    ScienceCinema (OSTI)

    None

    2013-05-29T23:59:59.000Z

    The switchable-mirrors technology was developed by Tom Richardson and Jonathan Slack of Berkeley Lab's Environmental Energy Technologies Division. By using transition metals rather than the rare earth metals used in the first metal-hydride switchable mirrors, Richardson and Slack were able to lower the cost and simplify the manufacturing process. Energy performance is improved as well, because the new windows can reflect or transmit both visible and infrared light. Besides windows for offices and homes, possible applications include automobile sunroofs, signs and displays, aircraft windows, and spacecraft. More information at: http://windows.lbl.gov/materials/chromogenics/default.htm

  10. Transition Metal Switchable Mirror

    SciTech Connect (OSTI)

    None

    2009-01-01T23:59:59.000Z

    The switchable-mirrors technology was developed by Tom Richardson and Jonathan Slack of Berkeley Lab's Environmental Energy Technologies Division. By using transition metals rather than the rare earth metals used in the first metal-hydride switchable mirrors, Richardson and Slack were able to lower the cost and simplify the manufacturing process. Energy performance is improved as well, because the new windows can reflect or transmit both visible and infrared light. Besides windows for offices and homes, possible applications include automobile sunroofs, signs and displays, aircraft windows, and spacecraft. More information at: http://windows.lbl.gov/materials/chromogenics/default.htm

  11. Transition Metal Switchable Mirror

    SciTech Connect (OSTI)

    2009-08-21T23:59:59.000Z

    The switchable-mirrors technology was developed by Tom Richardson and Jonathan Slack of Berkeley Lab's Environmental Energy Technologies Division. By using transition metals rather than the rare earth metals used in the first metal-hydride switchable mirrors, Richardson and Slack were able to lower the cost and simplify the manufacturing process. Energy performance is improved as well, because the new windows can reflect or transmit both visible and infrared light. Besides windows for offices and homes, possible applications include automobile sunroofs, signs and displays, aircraft windows, and spacecraft.

  12. Liquid metal electric pump

    DOE Patents [OSTI]

    Abbin, Joseph P. (Albuquerque, NM); Andraka, Charles E. (Albuquerque, NM); Lukens, Laurance L. (Albuquerque, NM); Moreno, James B. (Albuquerque, NM)

    1992-01-01T23:59:59.000Z

    An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other.

  13. High Temperature Flue Gas Desulfurization In Moving Beds With Regenerable Copper Based Sorbents

    SciTech Connect (OSTI)

    Cengiz, P.A.; Ho, K.K.; Abbasian, J.; Lau, F.S.

    2002-09-20T23:59:59.000Z

    The objective of this study was to develop new and improved regenerable copper based sorbent for high temperature flue gas desulfurization in a moving bed application. The targeted areas of sorbent improvement included higher effective capacity, strength and long-term durability for improved process control and economic utilization of the sorbent.

  14. Final Technical Report: Effects of Impurities on Fuel Cell Performance and Durability

    SciTech Connect (OSTI)

    James G. Goodwin, Jr.; Hector Colon-Mercado; Kitiya Hongsirikarn; and Jack Z. Zhang

    2011-11-11T23:59:59.000Z

    The main objectives of this project were to investigate the effect of a series of potential impurities on fuel cell operation and on the particular components of the fuel cell MEA, to propose (where possible) mechanism(s) by which these impurities affected fuel cell performance, and to suggest strategies for minimizing these impurity effects. The negative effect on Pt/C was to decrease hydrogen surface coverage and hydrogen activation at fuel cell conditions. The negative effect on Nafion components was to decrease proton conductivity, primarily by replacing/reacting with the protons on the Bronsted acid sites of the Nafion. Even though already well known as fuel cell poisons, the effects of CO and NH3 were studied in great detail early on in the project in order to develop methodology for evaluating poisoning effects in general, to help establish reproducibility of results among a number of laboratories in the U.S. investigating impurity effects, and to help establish lower limit standards for impurities during hydrogen production for fuel cell utilization. New methodologies developed included (1) a means to measure hydrogen surface concentration on the Pt catalyst (HDSAP) before and after exposure to impurities, (2) a way to predict conductivity of a Nafion membranes exposed to impurities using a characteristic acid catalyzed reaction (methanol esterification of acetic acid), and, more importantly, (3) application of the latter technique to predict conductivity on Nafion in the catalyst layer of the MEA. H2-D2 exchange was found to be suitable for predicting hydrogen activation of Pt catalysts. The Nafion (ca. 30 wt%) on the Pt/C catalyst resides primarily on the external surface of the C support where it blocks significant numbers of micropores, but only partially blocks the pore openings of the meso- and macro-pores wherein lie the small Pt particles (crystallites). For this reason, even with 30 wt% Nafion on the Pt/C, few Pt sites are blocked and, hence, are accessible for hydrogen activation. Of the impurities studied, CO, NH3, perchloroethylene (also known as tetrachloroethylene), tetrahydrofuran, diborane, and metal cations had significant negative effects on the components in a fuel cell. While CO has no effect on the Nafion, it significantly poisons the Pt catalyst by adsorbing and blocking hydrogen activation. The effect can be reversed with time once the flow of CO is stopped. NH3 has no effect on the Pt catalyst at fuel cell conditions; it poisons the proton sites on Nafion (by forming NH4+ cations), decreasing drastically the proton conductivity of Nafion. This poisoning can slowly be reversed once the flow of NH3 is stopped. Perchloroethylene has a major effect on fuel cell performance. Since it has little/no effect on Nafion conductivity, its poisoning effect is on the Pt catalyst. However, this effect takes place primarily for the Pt catalyst at the cathode, since the presence of oxygen is very important for this poisoning effect. Tetrahydrofuran was shown not to impact Nafion conductivity; however, it does affect fuel cell performance. Therefore, its primary effect is on the Pt catalyst. The effect of THF on fuel cell performance is reversible. Diborane also can significant affect fuel cell performance. This effect is reversible once diborane is removed from the inlet streams. H2O2 is not an impurity usually present in the hydrogen or oxygen streams to a fuel cell. However, it is generated during fuel cell operation. The presence of Fe cations in the Nafion due to system corrosion and/or arising from MEA production act to catalyze the severe degradation of the Nafion by H2O2. Finally, the presence of metal cation impurities (Na+, Ca 2+, Fe3+) in Nafion from MEA preparation or from corrosion significantly impacts its proton conductivity due to replacement of proton sites. This effect is not reversible. Hydrocarbons, such as ethylene, might be expected to affect Pt or Nafion but do not at a typical fuel cell temperature of 80oC. In the presence of large quantities of hydrogen on the anode side, ethylene i

  15. Characterization of Nanoporous Metal-Carbon Nanotube Composite Arrays

    E-Print Network [OSTI]

    Collins, Gary S.

    has been conducted on carbon fibers at X'ian University of Technology in China. This method consistsCharacterization of Nanoporous Metal-Carbon Nanotube Composite Arrays Chloe Heinen, Dr. David Bahr, Hang Zhou, and Chunlan Ren. "Research on Surface Metallization of Carbon Fiber Based on Electroless

  16. Lithium metal reduction of plutonium oxide to produce plutonium metal

    DOE Patents [OSTI]

    Coops, Melvin S. (Livermore, CA)

    1992-01-01T23:59:59.000Z

    A method is described for the chemical reduction of plutonium oxides to plutonium metal by the use of pure lithium metal. Lithium metal is used to reduce plutonium oxide to alpha plutonium metal (alpha-Pu). The lithium oxide by-product is reclaimed by sublimation and converted to the chloride salt, and after electrolysis, is removed as lithium metal. Zinc may be used as a solvent metal to improve thermodynamics of the reduction reaction at lower temperatures. Lithium metal reduction enables plutonium oxide reduction without the production of huge quantities of CaO--CaCl.sub.2 residues normally produced in conventional direct oxide reduction processes.

  17. Divalent metal nanoparticles

    E-Print Network [OSTI]

    DeVries, Gretchen Anne

    2008-01-01T23:59:59.000Z

    Metal nanoparticles hold promise for many scientific and technological applications, such as chemical and biological sensors, vehicles for drug delivery, and subdiffraction limit waveguides. To fabricate such devices, a ...

  18. Production of magnesium metal

    DOE Patents [OSTI]

    Blencoe, James G. (Harriman, TN); Anovitz, Lawrence M. (Knoxville, TN); Palmer, Donald A. (Oliver Springs, TN); Beard, James S. (Martinsville, VA)

    2012-04-10T23:59:59.000Z

    A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention also relates to the magnesium metal produced by the processes described herein.

  19. Functionalized Silicone Nanospheres: Synthesis, Transition Metal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Functionalized Silicone Nanospheres: Synthesis, Transition Metal Immobilization, and Catalytic Applications. Functionalized Silicone Nanospheres: Synthesis, Transition Metal...

  20. Plate-Based Fuel Processing System Final Report

    SciTech Connect (OSTI)

    Carlos Faz; Helen Liu; Jacques Nicole; David Yee

    2005-12-22T23:59:59.000Z

    On-board reforming of liquid fuels into hydrogen is an enabling technology that could accelerate consumer usage of fuel cell powered vehicles. The technology would leverage the convenience of the existing gasoline fueling infrastructure while taking advantage of the fuel cell efficiency and low emissions. Commercial acceptance of on-board reforming faces several obstacles that include: (1) startup time, (2) transient response, and (3) system complexity (size, weight and cost). These obstacles are being addressed in a variety of projects through development, integration and optimization of existing fuel processing system designs. In this project, CESI investigated steam reforming (SR), water-gas-shift (WGS) and preferential oxidation (PrOx) catalysts while developing plate reactor designs and hardware where the catalytic function is integrated into a primary surface heat exchanger. The plate reactor approach has several advantages. The separation of the reforming and combustion streams permits the reforming reaction to be conducted at a higher pressure than the combustion reaction, thereby avoiding costly gas compression for combustion. The separation of the two streams also prevents the dilution of the reformate stream by the combustion air. The advantages of the plate reactor are not limited to steam reforming applications. In a WGS or PrOx reaction, the non-catalytic side of the plate would act as a heat exchanger to remove the heat generated by the exothermic WGS or PrOx reactions. This would maintain the catalyst under nearly isothermal conditions whereby the catalyst would operate at its optimal temperature. Furthermore, the plate design approach results in a low pressure drop, rapid transient capable and attrition-resistant reactor. These qualities are valued in any application, be it on-board or stationary fuel processing, since they reduce parasitic losses, increase over-all system efficiency and help perpetuate catalyst durability. In this program, CESI took the initial steam reforming plate-reactor concept and advanced it towards an integrated fuel processing system. A substantial amount of modeling was performed to guide the catalyst development and prototype hardware design and fabrication efforts. The plate-reactor mechanical design was studied in detail to establish design guidelines which would help the plate reactor survive the stresses of repeated thermal cycles (from start-ups and shut-downs). Integrated system performance modeling was performed to predict system efficiencies and determine the parameters with the most significant impact on efficiency. In conjunction with the modeling effort, a significant effort was directed towards catalyst development. CESI developed a highly active, sulfur tolerant, coke resistant, precious metal based reforming catalyst. CESI also developed its own non-precious metal based water-gas shift catalyst and demonstrated the catalysts durability over several thousands of hours of testing. CESI also developed a unique preferential oxidation catalyst capable of reducing 1% CO to < 10 ppm CO over a 35 C operating window through a single pass plate-based reactor. Finally, CESI combined the modeling results and steam reforming catalyst development efforts into prototype hardware. The first generation 3kW(e) prototype was fabricated from existing heat-exchanger plates to expedite the fabrication process. This prototype demonstrated steady state operation ranging from 5 to 100% load conditions. The prototype also demonstrated a 20:1 turndown ratio, 10:1 load transient operation and rapid start-up capability.

  1. Molten metal reactors

    DOE Patents [OSTI]

    Bingham, Dennis N; Klingler, Kerry M; Turner, Terry D; Wilding, Bruce M

    2013-11-05T23:59:59.000Z

    A molten metal reactor for converting a carbon material and steam into a gas comprising hydrogen, carbon monoxide, and carbon dioxide is disclosed. The reactor includes an interior crucible having a portion contained within an exterior crucible. The interior crucible includes an inlet and an outlet; the outlet leads to the exterior crucible and may comprise a diffuser. The exterior crucible may contain a molten alkaline metal compound. Contained between the exterior crucible and the interior crucible is at least one baffle.

  2. Metal hydride fuel storage and method thereof

    DOE Patents [OSTI]

    Morse, Jeffrey D. (Martinez, CA); Jankowski, Alan F. (Livermore, CA); Yu, Conrad (Antioch, CA)

    2006-10-17T23:59:59.000Z

    Disclosed herein is a metal hydride fuel storage cartridge having integrated resistive heaters that can be used in conjunction with fuel cells such as MEMS-based fuel cells. The cartridge is fabricated using micromachining methods and thin/thick film materials synthesis techniques.

  3. Metal hydride fuel storage and method thereof

    DOE Patents [OSTI]

    Morse, Jeffrey D [Martinez, CA; Jankowski, Alan F [Livermore, CA; Yu, Conrad [Antioch, CA

    2009-05-05T23:59:59.000Z

    Disclosed herein is a metal hydride fuel storage cartridge having integrated resistive heaters that can be used in conjunction with fuel cells such as MEMS-based fuel cells. The cartridge is fabricated using micromachining methods and thin/thick film materials synthesis techniques.

  4. Modeling of durability of polyelectrolyte membrane of O2/H2 fuel cell

    E-Print Network [OSTI]

    Atrazhev, Vadim V

    2014-01-01T23:59:59.000Z

    In this paper, we discuss critical aspects of the mechanisms and features of polymer proton exchange membrane (PEM) degradation in low-temperature H2/O2 fuel cell. In this paper, we focused on chemical mechanism of OH radical generation and their distribution in operational fuel cell. According to the current concept, free radicals are generated from hydrogen and oxygen crossover gases at the surface of Pt particles that precipitated in the membrane. We explicitly calculate Pt precipitation rate and electrochemical potential distribution in the membrane that controls it. Based on radical generation rate and Pt distribution we calculate degradation rate of the membrane taking advantage of simple kinetics equations.

  5. Transition metal complex-based molecular machines 

    E-Print Network [OSTI]

    Sooksawat, Dhassida

    2015-06-30T23:59:59.000Z

    Inspired by the performance and evolutionarily-optimised natural molecular machines that carry out all the essential tasks contributing to the molecular basis of life, chemists aim towards fabricating synthetic molecular ...

  6. Method for forming metal contacts

    DOE Patents [OSTI]

    Reddington, Erik; Sutter, Thomas C; Bu, Lujia; Cannon, Alexandra; Habas, Susan E; Curtis, Calvin J; Miedaner, Alexander; Ginley, David S; Van Hest, Marinus Franciscus Antonius Maria

    2013-09-17T23:59:59.000Z

    Methods of forming metal contacts with metal inks in the manufacture of photovoltaic devices are disclosed. The metal inks are selectively deposited on semiconductor coatings by inkjet and aerosol apparatus. The composite is heated to selective temperatures where the metal inks burn through the coating to form an electrical contact with the semiconductor. Metal layers are then deposited on the electrical contacts by light induced or light assisted plating.

  7. Characterizing the nano and micro structure of concrete to improve its durability

    SciTech Connect (OSTI)

    Monteiro, P.J.M.; Kirchheim, A.P.; Chae, S.; Fischer, P.; MacDowell, A.A.; Schaible, E.; Wenk, H.R.

    2008-10-22T23:59:59.000Z

    New and advanced methodologies have been developed to characterize the nano and microstructure of cement paste and concrete exposed to aggressive environments. High resolution full-field soft X-ray imaging in the water window is providing new insight on the nano scale of the cement hydration process, which leads to a nano-optimization of cement-based systems. Hard X-ray microtomography images on ice inside cement paste and cracking caused by the alkali-silica reaction (ASR) enables three-dimensional structural identification. The potential of neutron diffraction to determine reactive aggregates by measuring their residual strains and preferred orientation is studied. Results of experiments using these tools will be shown on this paper.

  8. High-Temperature Zirconia Oxygen Sensor with Sealed Metal/Metal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference...

  9. Recycle of contaminated scrap metal, Volume 2. Semi-annual report, September 1993--January 1996

    SciTech Connect (OSTI)

    NONE

    1996-07-01T23:59:59.000Z

    Catalytic Extraction Processing (CEP) has been demonstrated to be a robust, one-step process that is relatively insensitive to wide variations in waste composition and is applicable to a broad spectrum of DOE wastes. Catalytic Processing Unit (CPU) design models have been validated through experimentation to provide a high degree of confidence in our ability to design a bulk solids CPU for processing DOE wastes. Two commercial CEP facilities have been placed in commission and are currently processing mixed low level wastes. These facilities provide a compelling indication of the maturity, regulatory acceptance, and commercial viability of CEP. In concert with the DOE, Nolten Metal Technology designed a program which would challenge preconceptions of the limitations of waste processing technologies: demonstrate the recycling of ferrous and non-ferrous metals--to establish that radioactively contaminated scrap metal could be converted to high-grade, ferrous and non-ferrous alloys which can be reused by DOE or reintroduced into commerce; immobilize radionuclides--that CEP would concentrate the radionuclides in a durable vitreous phase, minimize secondary waste generation and stabilize and reduce waste volume; destroy hazardous organics--that CEP would convert hazardous organics to valuable industrial gases, which could be used as an energy source; recover volatile heavy metals--that CEP`s off-gas treatment system would capture volatile heavy metals, such as mercury and lead; and establish that CEP is economical for processing contaminated scrap metal in the DOE inventory. The execution of this program resulted in all objectives being met. Volume II contains: Task 1.4, optimization of the vitreous phase for stabilization of radioactive species; Task 1.5, experimental testing of Resource Conservation and Recovery Act (RCRA) wastes; and Task 1.6, conceptual design of a CEP facility.

  10. Electron Microscopy Characterization of Tc-Bearing Metallic Waste Forms- Final Report FY10

    SciTech Connect (OSTI)

    Buck, Edgar C.; Neiner, Doinita

    2010-09-30T23:59:59.000Z

    The DOE Fuel Cycle Research & Development (FCR&D) Program is developing aqueous and electrochemical approaches to the processing of used nuclear fuel that will generate technetium-bearing waste streams. This final report presents Pacific Northwest National Laboratory (PNNL) research in FY10 to evaluate an iron-based alloy waste form for Tc that provides high waste loading within waste form processing limitations, meets waste form performance requirements for durability and the long-term retention of radionuclides and can be produced with consistent physical, chemical, and radiological properties that meet regulatory acceptance requirements for disposal.

  11. Photobiomolecular deposition of metallic particles and films

    DOE Patents [OSTI]

    Hu, Zhong-Cheng

    2005-02-08T23:59:59.000Z

    The method of the invention is based on the unique electron-carrying function of a photocatalytic unit such as the photosynthesis system I (PSI) reaction center of the protein-chlorophyll complex isolated from chloroplasts. The method employs a photo-biomolecular metal deposition technique for precisely controlled nucleation and growth of metallic clusters/particles, e.g., platinum, palladium, and their alloys, etc., as well as for thin-film formation above the surface of a solid substrate. The photochemically mediated technique offers numerous advantages over traditional deposition methods including quantitative atom deposition control, high energy efficiency, and mild operating condition requirements.

  12. Metal behavior during fluidized bed thermal treatment of soil

    SciTech Connect (OSTI)

    Ho, T.C.; Lee, H.T.; Shiao, C.C.; Hopper, J.R. [Lamar Univ., Beaumont, TX (United States). Dept. of Chemical Engineering] [Lamar Univ., Beaumont, TX (United States). Dept. of Chemical Engineering; Bostick, W.D. [Martin Marietta Energy Systems, Inc., Oak Ridge, TN (United States). Chemistry Dept.] [Martin Marietta Energy Systems, Inc., Oak Ridge, TN (United States). Chemistry Dept.

    1995-12-31T23:59:59.000Z

    The Superfund dumpsites are frequently composed of soils contaminated with hazardous organic constituents and toxic heavy metals. While thermal treatment is an effective method of remediating the contaminated soils, the major environmental concerns are the emissions of toxic metal fumes during the treatment and the leaching of metals from the treated soil. The US EPA has reported that metals can account for almost all of the identified cancer risks from waste incineration systems. Research leading to better understanding of their behavior and better controlling of their emissions is urgently needed. In this study, the behavior of metals during the fluidized bed thermal treatment of artificially prepared metal-contaminated clay was experimentally and theoretically investigated. The objective of the study was to evaluate the effects of operating conditions on metal volatilization and metal leachability associated with the process. Metal experiments were carried out in a well instrumented 76 mm (3 inch) i.d. fluidized bed incinerator. The metals involved were compounds of lead and cadmium and the operating parameters included metal concentration, air flow rate, treatment temperature and treatment duration. The observed results indicated that metal volatilization is mainly a function of treatment temperature and treatment duration. The degree of volatilization was observed to range from 5 to 40% depending on the operating conditions. Cadmium leachability was observed to be relatively high compared to that of lead. In addition to the experimental study, a theoretical model based on the laws of heat and mass transfer operations and reaction kinetics was derived to simulate the metal volatilization process. The derived model was found to predict reasonably well the experimental observations.

  13. Mechanical Properties of Bulk Metallic Glasses and Composites

    E-Print Network [OSTI]

    Lee, M.L.

    We have studied the mechanical properties of monolithic bulk metallic glasses and composite in the La based alloys. La???yAl??(Cu, Ni)y (y=24 to 32) alloy systems was used to cast the ...

  14. area metal oxide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Science Websites Summary: have generated considerable interest for applications such as thin film displays with improved color of a metal oxide-based QD-LED structure10 injection...

  15. Near room temperature lithographically processed metal-oxide transistors

    E-Print Network [OSTI]

    Tang, Hui, M. Eng. Massachusetts Institute of Technology

    2008-01-01T23:59:59.000Z

    A fully lithographic process at near-room-temperature was developed for the purpose of fabricating transistors based on metal-oxide channel materials. The combination of indium tin oxide (ITO) as the source/drain electrodes, ...

  16. Barrier Coatings for Refractory Metals and Superalloys

    SciTech Connect (OSTI)

    SM Sabol; BT Randall; JD Edington; CJ Larkin; BJ Close

    2006-02-23T23:59:59.000Z

    In the closed working fluid loop of the proposed Prometheus space nuclear power plant (SNPP), there is the potential for reaction of core and plant structural materials with gas phase impurities and gas phase transport of interstitial elements between superalloy and refractory metal alloy components during service. Primary concerns are surface oxidation, interstitial embrittlement of refractory metals and decarburization of superalloys. In parallel with kinetic investigations, this letter evaluates the ability of potential coatings to prevent or impede communication between reactor and plant components. Key coating requirements are identified and current technology coating materials are reviewed relative to these requirements. Candidate coatings are identified for future evaluation based on current knowledge of design parameters and anticipated environment. Coatings were identified for superalloys and refractory metals to provide diffusion barriers to interstitial transport and act as reactive barriers to potential oxidation. Due to their high stability at low oxygen potential, alumina formers are most promising for oxidation protection given the anticipated coolant gas chemistry. A sublayer of iridium is recommended to provide inherent diffusion resistance to interstitials. Based on specific base metal selection, a thin film substrate--coating interdiffusion barrier layer may be necessary to meet mission life.

  17. Nanotube Formation: Researchers Learn To Control The Dimensions Of Metal Oxide Nanotubes

    E-Print Network [OSTI]

    Nair, Sankar

    made from metal oxides -- work that could lead to a technique for precisely conNanotube Formation: Researchers Learn To Control The Dimensions Of Metal Oxide Nanotubes Science their diameter and length. Based on metal oxides in combination with silicon and germanium, such single

  18. Method for producing nanostructured metal-oxides

    DOE Patents [OSTI]

    Tillotson, Thomas M.; Simpson, Randall L.; Hrubesh, Lawrence W.; Gash, Alexander

    2006-01-17T23:59:59.000Z

    A synthetic route for producing nanostructure metal-oxide-based materials using sol-gel processing. This procedure employs the use of stable and inexpensive hydrated-metal inorganic salts and environmentally friendly solvents such as water and ethanol. The synthesis involves the dissolution of the metal salt in a solvent followed by the addition of a proton scavenger, which induces gel formation in a timely manner. Both critical point (supercritical extraction) and atmospheric (low temperature evaporation) drying may be employed to produce monolithic aerogels and xerogels, respectively. Using this method synthesis of metal-oxide nanostructured materials have been carried out using inorganic salts, such as of Fe3+, Cr3+, Al3+, Ga3+, In3+, Hf4+, Sn4+, Zr4+, Nb5+, W6+, Pr3+, Er3+, Nd3+, Ce3+, U3+ and Y3+. The process is general and nanostructured metal-oxides from the following elements of the periodic table can be made: Groups 2 through 13, part of Group 14 (germanium, tin, lead), part of Group 15 (antimony, bismuth), part of Group 16 (polonium), and the lanthanides and actinides. The sol-gel processing allows for the addition of insoluble materials (e.g., metals or polymers) to the viscous sol, just before gelation, to produce a uniformly distributed nanocomposites upon gelation. As an example, energetic nanocomposites of FexOy gel with distributed Al metal are readily made. The compositions are stable, safe, and can be readily ignited to thermitic reaction.

  19. Process for production of a metal hydride

    DOE Patents [OSTI]

    Allen, Nathan Tait; Butterick, III, Robert; Chin, Arthur Achhing; Millar, Dean Michael; Molzahn, David Craig

    2014-08-12T23:59:59.000Z

    A process for production of a metal hydride compound MH.sub.x, wherein x is one or two and M is an alkali metal, Be or Mg. The process comprises combining a compound of formula (R.sup.1O).sub.xM with aluminum, hydrogen and at least one metal selected from among titanium, zirconium, hafnium, niobium, vanadium, tantalum and iron to produce a compound of formula MH.sub.x. R.sup.1 is phenyl or phenyl substituted by at least one alkyl or alkoxy group. A mole ratio of aluminum to (R.sup.1O).sub.xM is from 0.1:1 to 1:1. The catalyst is present at a level of at least 200 ppm based on weight of aluminum.

  20. Reaction-Forming Method for Producing Near Net-Shape Refractory Metal Carbides

    DOE Patents [OSTI]

    Palmisiano, Marc N.; Jakubenas, Kevin J.; Baranwal, Rita

    2004-07-20T23:59:59.000Z

    A method for reaction forming refractory metal carbides. The method involves the fabrication of a glassy carbon preform by casting an organic, resin-based liquid mixture into a mold and subsequently heat treating it in two steps, which cures and pyrolizes the resin resulting in a porous carbon preform. By varying the amounts of the constituents in the organic, resin-based liquid mixture, control over the density of the carbon preform is obtained. Control of the density and microstructure of the carbon preform allows for determination of the microstructure and properties of the refractory metal carbide material produced. The glassy carbon preform is placed on a bed of refractory metal or refractory metal--silicon alloy. The pieces are heated above the melting point of the metal or alloy. The molten metal wicks inside the porous carbon preform and reacts, forming the refractory metal carbide or refractory metal carbide plus a minor secondary phase.

  1. Nitrided Metallic Bipolar Plates

    SciTech Connect (OSTI)

    Brady, Michael P [ORNL; Tortorelli, Peter F [ORNL; Pihl, Josh A [ORNL; Toops, Todd J [ORNL; More, Karren Leslie [ORNL; Meyer III, Harry M [ORNL; Vitek, John Michael [ORNL; Wang, Heli [National Renewable Energy Laboratory (NREL); Turner, John [National Renewable Energy Laboratory (NREL); Wilson, Mahlon [Los Alamos National Laboratory (LANL); Garzon, Fernando [Los Alamos National Laboratory (LANL); Rockward, Tommy [Los Alamos National Laboratory (LANL); Connors, Dan [GenCell Corp; Rakowski, Jim [Allegheny Ludlum; Gervasio, Don [Arizona State University

    2008-01-01T23:59:59.000Z

    The objectives are: (1) Develop and optimize stainless steel alloys amenable to formation of a protective Cr-nitride surface by gas nitridation, at a sufficiently low cost to meet DOE targets and with sufficient ductility to permit manufacture by stamping. (2) Demonstrate capability of nitridation to yield high-quality stainless steel bipolar plates from thin stamped alloy foils (no significant stamped foil warping or embrittlement). (3) Demonstrate single-cell fuel cell performance of stamped and nitrided alloy foils equivalent to that of machined graphite plates of the same flow-field design ({approx}750-1,000 h, cyclic conditions, to include quantification of metal ion contamination of the membrane electrode assembly [MEA] and contact resistance increase attributable to the bipolar plates). (4) Demonstrate potential for adoption in automotive fuel cell stacks. Thin stamped metallic bipolar plates offer the potential for (1) significantly lower cost than currently-used machined graphite bipolar plates, (2) reduced weight/volume, and (3) better performance and amenability to high volume manufacture than developmental polymer/carbon fiber and graphite composite bipolar plates. However, most metals exhibit inadequate corrosion resistance in proton exchange membrane fuel cell (PEMFC) environments. This behavior leads to high electrical resistance due to the formation of surface oxides and/or contamination of the MEA by metallic ions, both of which can significantly degrade fuel cell performance. Metal nitrides offer electrical conductivities up to an order of magnitude greater than that of graphite and are highly corrosion resistant. Unfortunately, most conventional coating methods (for metal nitrides) are too expensive for PEMFC stack commercialization or tend to leave pinhole defects, which result in accelerated local corrosion and unacceptable performance.

  2. Durability of Actinide Ceramic Waste Forms Under Conditions of Granitoid Rocks

    SciTech Connect (OSTI)

    Burakov, B. E.; Anderson, E. B.

    2002-02-26T23:59:59.000Z

    Three samples of {sup 239}Pu-{sup 241}Am-doped ceramics obtained from previous research were used for alteration experiments simulating corrosion of waste forms in ion-saturated solutions. These were ceramics based on: pyrochlore, (Ca,Hf,Pu,U,Gd){sub 2}Ti{sub 2}O{sub 7}, containing 10 wt.% Pu and 0.1 wt.% Am; zircon, (Zr,Pu)SiO{sub 4}, containing 5-6 wt.% Pu and 0.05 wt.% Am; cubic zirconia, (Zr,Gd,Pu)O{sub 2}, containing 10 wt.% Pu and 0.1 wt.% Am. All these samples were milled in an agate mortar to obtain powder with particle sizes less than 30 micron. Sample of granite taken from the depth 500-503 m was studied and then used for preparing ion-saturated water solutions. A rock sample was ground, washed and classified. A fraction with particle size 0.10-0.25 mm was selected for alteration experiments. Powdered ceramic samples were separately placed into deionized water together with ground granite (approximately 1gram granite per 12-ml water) in special Teflon{trademark} vessels and set at 90 C in the oven for 3 months. After alteration experiments, the ceramic powders were studied by precise XRD analysis. Aqueous solutions and granite grains were analyzed for Am and Pu contents. The results show that alteration did not cause significant phase transformation in all ceramic samples. For all altered samples, the Am contents in aqueous solutions after experiments were similar (approximately n x 10{sup 2} Bq/ml) as well as Am amounts absorbed on granite grains (approximately n x 10{sup 5} Bq/g). Results on Pu contents were varied: for the solutions--from 60 Bq/ml for pyrochlore ceramic to 2.1 x 10{sup 3} Bq/ml for zircon ceramic; and for the absorption on granite--from 2.6 x 10{sup 4} Bq/g for zirconia ceramic to 1.4-6.8 x 10{sup 5} Bq/g for pyrochlore and zircon ceramics.

  3. Metallic coating of microspheres

    SciTech Connect (OSTI)

    Meyer, S.F.

    1980-08-15T23:59:59.000Z

    Extremely smooth, uniform metal coatings of micrometer thicknesses on microscopic glass spheres (microspheres) are often needed as targets for inertial confinement fusion (ICF) experiments. The first part of this paper reviews those methods used successfully to provide metal coated microspheres for ICF targets, including magnetron sputtering, electro- and electroless plating, and chemical vapor pyrolysis. The second part of this paper discusses some of the critical aspects of magnetron sputter coating of microspheres, including substrate requirements, the sticking of microspheres during coating (preventing a uniform coating), and the difficulties in growing the desired dense, smooth, uniform microstructure on continuously moving spherical substrates.

  4. Hard metal composition

    DOE Patents [OSTI]

    Sheinberg, Haskell (Los Alamos, NM)

    1986-01-01T23:59:59.000Z

    A composition of matter having a Rockwell A hardness of at least 85 is formed from a precursor mixture comprising between 3 and 10 weight percent boron carbide and the remainder a metal mixture comprising from 70 to 90 percent tungsten or molybdenum, with the remainder of the metal mixture comprising nickel and iron or a mixture thereof. The composition has a relatively low density of between 7 to 14 g/cc. The precursor is preferably hot pressed to yield a composition having greater than 100% of theoretical density.

  5. Hard metal composition

    DOE Patents [OSTI]

    Sheinberg, H.

    1983-07-26T23:59:59.000Z

    A composition of matter having a Rockwell A hardness of at least 85 is formed from a precursor mixture comprising between 3 and 10 wt % boron carbide and the remainder a metal mixture comprising from 70 to 90% tungsten or molybdenum, with the remainder of the metal mixture comprising nickel and iron or a mixture thereof. The composition has a relatively low density of between 7 and 14 g/cc. The precursor is preferably hot pressed to yield a composition having greater than 100% of theoretical density.

  6. Metal alloy identifier

    DOE Patents [OSTI]

    Riley, William D. (Avondale, MD); Brown, Jr., Robert D. (Avondale, MD)

    1987-01-01T23:59:59.000Z

    To identify the composition of a metal alloy, sparks generated from the alloy are optically observed and spectrographically analyzed. The spectrographic data, in the form of a full-spectrum plot of intensity versus wavelength, provide the "signature" of the metal alloy. This signature can be compared with similar plots for alloys of known composition to establish the unknown composition by a positive match with a known alloy. An alternative method is to form intensity ratios for pairs of predetermined wavelengths within the observed spectrum and to then compare the values of such ratios with similar values for known alloy compositions, thereby to positively identify the unknown alloy composition.

  7. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengthening a solidSynthesisAppliancesTrending: Metal Oxo Bonds Print Metal

  8. Method of producing thermally sprayed metallic coating

    DOE Patents [OSTI]

    Byrnes, Larry Edward (Rochester Hills, MI); Kramer, Martin Stephen (Clarkston, MI); Neiser, Richard A. (Albuquerque, NM)

    2003-08-26T23:59:59.000Z

    The cylinder walls of light metal engine blocks are thermally spray coated with a ferrous-based coating using an HVOF device. A ferrous-based wire is fed to the HVOF device to locate a tip end of the wire in a high temperature zone of the device. Jet flows of oxygen and gaseous fuel are fed to the high temperature zone and are combusted to generate heat to melt the tip end. The oxygen is oversupplied in relation to the gaseous fuel. The excess oxygen reacts with and burns a fraction of the ferrous-based feed wire in an exothermic reaction to generate substantial supplemental heat to the HVOF device. The molten/combusted metal is sprayed by the device onto the walls of the cylinder by the jet flow of gases.

  9. Wick for metal vapor laser

    DOE Patents [OSTI]

    Duncan, David B. (Livermore, CA)

    1992-01-01T23:59:59.000Z

    An improved wick for a metal vapor laser is made of a refractory metal cylinder, preferably molybdenum or tungsten for a copper laser, which provides the wicking surface. Alternately, the inside surface of the ceramic laser tube can be metalized to form the wicking surface. Capillary action is enhanced by using wire screen, porous foam metal, or grooved surfaces. Graphite or carbon, in the form of chunks, strips, fibers or particles, is placed on the inside surface of the wick to reduce water, reduce metal oxides and form metal carbides.

  10. Glassy slags as novel waste forms for remediating mixed wastes with high metal contents

    SciTech Connect (OSTI)

    Feng, X.; Wronkiewicz, D.J.; Bates, J.K.; Brown, N.R.; Buck, E.C.; Gong, M.; Ebert, W.L.

    1994-03-01T23:59:59.000Z

    Argonne National Laboratory (ANL) is developing a glassy slag final waste form for the remediation of low-level radioactive and mixed wastes with high metal contents. This waste form is composed of various crystalline and metal oxide phases embedded in a silicate glass phase. This work indicates that glassy slag shows promise as final waste form because (1) it has similar or better chemical durability than high-level nuclear waste (HLW) glasses, (2) it can incorporate large amounts of metal wastes, (3) it can incorporate waste streams having low contents of flux components (boron and alkalis), (4) it has less stringent processing requirements (e.g., viscosity and electric conductivity) than glass waste forms, (5) its production can require little or no purchased additives, which can result in greater reduction in waste volume and overall treatment costs. By using glassy slag waste forms, minimum additive waste stabilization approach can be applied to a much wider range of waste streams than those amenable only to glass waste forms.

  11. Energy Dense, Lighweight, Durable, Systems for Storage and Delivery of Hydrogen

    SciTech Connect (OSTI)

    Jacky Pruez; Samir Shoukry; Gergis William; Thomas Evans; Hermann Alcazar

    2008-12-31T23:59:59.000Z

    The work presented in this report summarizes the current state-of-the-art in on-board storage on compressed gaseous hydrogen as well as the development of analysis tools, methods, and theoretical data for devising high performance design configurations for hydrogen storage. The state-of-the-art in the area of compressed hydrogen storage reveals that the current configuration of the hydrogen storage tank is a seamless cylindrical part with two end domes. The tank is composed of an aluminum liner overwrapped with carbon fibers. Such a configuration was proved to sustain internal pressures up to 350 bars (5,000 psi). Finite-element stress analyses were performed on filament-wound hydrogen storage cylindrical tanks under the effect of internal pressure of 700 bars (10,000 psi). Tank deformations, stress fields, and intensities induced at the tank wall were examined. The results indicated that the aluminum liner can not sustain such a high pressure and initiate the tank failure. Thus, hydrogen tanks ought to be built entirely out of composite materials based on carbon fibers or other innovative composite materials. A spherical hydrogen storage tank was suggested within the scope of this project. A stress reduction was achieved by this change of the tank geometry, which allows for increasing the amount of the stored hydrogen and storage energy density. The finite element modeling of both cylindrical and spherical tank design configurations indicate that the formation of stress concentration zones in the vicinity of the valve inlet as well as the presence of high shear stresses in this area. Therefore, it is highly recommended to tailor the tank wall design to be thicker in this region and tapered to the required thickness in the rest of the tank shell. Innovative layout configurations of multiple tanks for enhanced conformability in limited space have been proposed and theoretically modeled using 3D finite element analysis. Optimum tailoring of fiber orientations and lay-ups are needed to relieve the high stress in regions of high stress concentrations between intersecting tanks/ tank sections. Filament winding process is the most suitable way for producing both cylindrical and spherical hydrogen storage tanks with high industrial quality. However, due to the unavailability of such equipment at West Virginia University and limited funding, the composite structures within this work were produced by hand layup and bag molding techniques. More advanced manufacturing processes can significantly increase the structural strength of the tank and enhances its performance and also further increase weight saving capabilities. The concept of using a carbon composite liner seems to be promising in overcoming the low strength of the aluminum liner at internal high pressures. This could be further enhanced by using MetPreg filament winding to produce such a liner. Innovative designs for the polar boss of the storage tanks and the valve connections are still needed to reduce the high stress formed in these zones to allow for the tank to accommodate higher internal pressures. The Continuum Damage Mechanics (CDM) approach was applied for fault-tolerant design and efficient maintenance of lightweight automotive structures made of composite materials. Potential effects of damage initiation and accumulation are formulated for various design configurations, with emphasis on lightweight fiber-reinforced composites. The CDM model considers damage associated with plasticity and fatigue.

  12. Lithium Metal Anodes for Rechargeable Batteries. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Metal Anodes for Rechargeable Batteries. Lithium Metal Anodes for Rechargeable Batteries. Abstract: Rechargeable lithium metal batteries have much higher energy density than those...

  13. Ductile transplutonium metal alloys

    DOE Patents [OSTI]

    Conner, W.V.

    1981-10-09T23:59:59.000Z

    Alloys of Ce with transplutonium metals such as Am, Cm, Bk and Cf have properties making them highly suitable as souces of the transplutonium element, e.g., for use in radiation detector technology or as radiation sources. The alloys are ductile, homogeneous, easy to prepare and have a fairly high density.

  14. Speed of Sound in metal Speed of Sound in metal

    E-Print Network [OSTI]

    Yu, Jaehoon

    the metal rod and metal bar. 2. Acquire a metal bar or rod and measure its mass. Use the meter stick and measure and record the length in meters. Use the vernier calipers and measure the other dimensionBar Select the Smart Tool. Position the Smart tool so that the vertical line bisects the pulse. The (x

  15. Method of producing adherent metal oxide coatings on metallic surfaces

    DOE Patents [OSTI]

    Lane, Michael H. (Clifton Park, NY); Varrin, Jr., Robert D. (McLean, VA)

    2001-01-01T23:59:59.000Z

    Provided is a process of producing an adherent synthetic corrosion product (sludge) coating on metallic surfaces. The method involves a chemical reaction between a dry solid powder mixture of at least one reactive metal oxide with orthophosphoric acid to produce a coating in which the particles are bound together and the matrix is adherent to the metallic surface.

  16. Calixarene supported transition metal clusters 

    E-Print Network [OSTI]

    Taylor, Stephanie Merac

    2013-06-29T23:59:59.000Z

    This thesis describes a series of calix[n]arene polynuclear transition metal and lanthanide complexes. Calix[4]arenes possess lower-rim polyphenolic pockets that are ideal for the complexation of various transition metal ...

  17. Localization of Competing Metals (Ni, Co, and Zn) in Alyssum using micro-XRF and Tomography. (3564)

    E-Print Network [OSTI]

    Sparks, Donald L.

    Localization of Competing Metals (Ni, Co, and Zn) in Alyssum using micro-XRF and Tomography. (3564 and observed metal localization in root and shoot tissue using synchrotron based micro-XRF and tomography

  18. Carbon-Based Materials, High-Surface-Area Sorbents, and New Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    technologies includes a range of carbon-based materials such as carbon nanotubes, aerogels, nanofibers (including metal-doped hybrids), as well as metal-organic frameworks,...

  19. Development of materials resistant to metal dusting degradation.

    SciTech Connect (OSTI)

    Natesan, K.; Zeng, Z.

    2006-04-24T23:59:59.000Z

    Metal dusting corrosion has been a serious problem in the petroleum and petrochemical industries, such as reforming and syngas production systems. This form of deterioration has led to worldwide material loss for 50 years. For the past three years, we have studied the mechanism of metal dusting for Fe- and Ni-base alloys. In this report, we present a correlation between the weight loss and depth of pits that form in Ni-base alloys. Nickel-base alloys were also tested at 1 and 14.8 atm (210 psi), in a high carbon activity environment. Higher system pressure was found to accelerate corrosion in most Ni-base alloys. To reduce testing time, a pre-pitting method was developed. Mechanical scratches on the alloy surface led to fast metal dusting corrosion. We have also developed preliminary data on the performance of weldments of several Ni-base alloys in a metal dusting environment. Finally, Alloy 800 tubes and plates used in a reformer plant were examined by scanning electron microscopy, energy dispersive X-ray, and Raman spectroscopy. The oxide scale on the surface of the Alloy 800 primarily consists of Fe{sub 1+x}Cr{sub 2-X}O{sub 4} spinel phase with high Fe content. Carbon can diffuse through this oxide scale. It was discovered that the growth of metal dusting pits could be stopped by means of a slightly oxidized alloy surface. This leads to a new way to solve metal dusting problem.

  20. Electroless metal plating of plastics

    DOE Patents [OSTI]

    Krause, Lawrence J. (Chicago, IL)

    1984-01-01T23:59:59.000Z

    Process for plating main group metals on aromatic polymers is carried out by the use of a nonaqueous solution of a salt of an alkali metal in a positive valence state and a main group metal in a negative valence state with contact between the solution and polymer providing a redox reaction causing the deposition of the main group metal and the reduction of the polymer. Products from the process exhibit useful decorative and electrical properties.

  1. Electroless metal plating of plastics

    DOE Patents [OSTI]

    Krause, L.J.

    1982-09-20T23:59:59.000Z

    Process for plating main group metals on aromatic polymers is carried out by the use of a nonaqueous solution of a salt of an alkali metal in a positive valence state and a main group metal in a negative valence state with contact between the solution and polymer providing a redox reaction causing the deposition of the main group metal and the reduction of the polymer. Products from the process exhibit useful decorative and electrical properties.

  2. Electroless metal plating of plastics

    DOE Patents [OSTI]

    Krause, Lawrence J. (Chicago, IL)

    1986-01-01T23:59:59.000Z

    Process for plating main group metals on aromatic polymers is carried out by the use of a nonaqueous solution of a salt of an alkali metal in a positive valence state and a main group metal in a negative valence state with contact between the solution and polymer providing a redox reaction causing the deposition of the main group metal and the reduction of the polymer. Products from the process exhibit useful decorative and electrical properties.

  3. Upgrading platform using alkali metals

    DOE Patents [OSTI]

    Gordon, John Howard

    2014-09-09T23:59:59.000Z

    A process for removing sulfur, nitrogen or metals from an oil feedstock (such as heavy oil, bitumen, shale oil, etc.) The method involves reacting the oil feedstock with an alkali metal and a radical capping substance. The alkali metal reacts with the metal, sulfur or nitrogen content to form one or more inorganic products and the radical capping substance reacts with the carbon and hydrogen content to form a hydrocarbon phase. The inorganic products may then be separated out from the hydrocarbon phase.

  4. Methods of recovering alkali metals

    DOE Patents [OSTI]

    Krumhansl, James L; Rigali, Mark J

    2014-03-04T23:59:59.000Z

    Approaches for alkali metal extraction, sequestration and recovery are described. For example, a method of recovering alkali metals includes providing a CST or CST-like (e.g., small pore zeolite) material. The alkali metal species is scavenged from the liquid mixture by the CST or CST-like material. The alkali metal species is extracted from the CST or CST-like material.

  5. Fabrication of metallic glass structures

    DOE Patents [OSTI]

    Cline, C.F.

    1983-10-20T23:59:59.000Z

    Amorphous metal powders or ribbons are fabricated into solid shapes of appreciable thickness by the application of compaction energy. The temperature regime wherein the amorphous metal deforms by viscous flow is measured. The metal powders or ribbons are compacted within the temperature regime.

  6. Integrated decontamination process for metals

    DOE Patents [OSTI]

    Snyder, Thomas S. (Oakmont, PA); Whitlow, Graham A. (Murrysville, PA)

    1991-01-01T23:59:59.000Z

    An integrated process for decontamination of metals, particularly metals that are used in the nuclear energy industry contaminated with radioactive material. The process combines the processes of electrorefining and melt refining to purify metals that can be decontaminated using either electrorefining or melt refining processes.

  7. Transparent and Conductive Carbon Nanotube Multilayer Thin Films Suitable as an Indium Tin Oxide Replacement 

    E-Print Network [OSTI]

    Park, Yong Tae

    2012-07-16T23:59:59.000Z

    Transparent electrodes made from metal oxides suffer from poor flexibility and durability. Highly transparent and electrically conductive thin films based on carbon nanotubes (CNTs) were assembled as a potential indium tin oxide (ITO) replacement...

  8. Compatibility Study for Plastic, Elastomeric, and Metallic Fueling Infrastructure Materials Exposed to Aggressive Formulations of Ethanol-blended Gasoline

    SciTech Connect (OSTI)

    Kass, Michael D [ORNL; Pawel, Steven J [ORNL; Theiss, Timothy J [ORNL; Janke, Christopher James [ORNL

    2012-07-01T23:59:59.000Z

    In 2008 Oak Ridge National Laboratory began a series of experiments to evaluate the compatibility of fueling infrastructure materials with intermediate levels of ethanol-blended gasoline. Initially, the focus was elastomers, metals, and sealants, and the test fuels were Fuel C, CE10a, CE17a and CE25a. The results of these studies were published in 2010. Follow-on studies were performed with an emphasis on plastic (thermoplastic and thermoset) materials used in underground storage and dispenser systems. These materials were exposed to test fuels of Fuel C and CE25a. Upon completion of this effort, it was felt that additional compatibility data with higher ethanol blends was needed and another round of experimentation was performed on elastomers, metals, and plastics with CE50a and CE85a test fuels. Compatibility of polymers typically relates to the solubility of the solid polymer with a solvent. It can also mean susceptibility to chemical attack, but the polymers and test fuels evaluated in this study are not considered to be chemically reactive with each other. Solubility in polymers is typically assessed by measuring the volume swell of the polymer exposed to the solvent of interest. Elastomers are a class of polymers that are predominantly used as seals, and most o-ring and seal manufacturers provide compatibility tables of their products with various solvents including ethanol, toluene, and isooctane, which are components of aggressive oxygenated gasoline as described by the Society of Automotive Engineers (SAE) J1681. These tables include a ranking based on the level of volume swell in the elastomer associated with exposure to a particular solvent. Swell is usually accompanied by a decrease in hardness (softening) that also affects performance. For seal applications, shrinkage of the elastomer upon drying is also a critical parameter since a contraction of volume can conceivably enable leakage to occur. Shrinkage is also indicative of the removal of one or more components of the elastomers (by the solvent). This extraction of additives can negatively change the properties of the elastomer, leading to reduced performance and durability. For a seal application, some level of volume swell is acceptable, since the expansion will serve to maintain a seal. However, the acceptable level of swell is dependent on the particular application of the elastomer product. It is known that excessive swell can lead to unacceptable extrusion of the elastomer beyond the sealed interface, where it becomes susceptible to damage. Also, since high swell is indicative of high solubility, there is a heightened potential for fluid to seep through the seal and into the environment. Plastics, on the other hand, are used primarily in structural applications, such as solid components, including piping and fluid containment. Volume change, especially in a rigid system, will create internal stresses that may negatively affect performance. In order to better understand and predict the compatibility for a given polymer type and fuel composition, an analysis based on Hansen solubility theory was performed for each plastic and elastomer material. From this study, the solubility distance was calculated for each polymer material and test fuel combination. Using the calculated solubility distance, the ethanol concentration associated with peak swell and overall extent of swell can be predicted for each polymer. The bulk of the material discussion centers on the plastic materials, and their compatibility with Fuel C, CE25a, CE50a, and CE85a. The next section of this paper focuses on the elastomer compatibility with the higher ethanol concentrations with comparison to results obtained previously for the lower ethanol levels. The elastomers were identical to those used in the earlier study. Hansen solubility theory is also applied to the elastomers to provide added interpretation of the results. The final section summarizes the performance of the metal coupons.

  9. Wood Durability Service & Reliability

    E-Print Network [OSTI]

    and testing (e.g., presses, mat former, blender, injection molding machine, twin- screw extrusion machine, univer- sal testing machine, etc.). SEM, ICP and HPLC available on LSU Baton Rouge campus. How Can We- ence Internationally recognized scien- tists All tests include a report that details the procedures

  10. DSpace: Durable Digital Documents

    E-Print Network [OSTI]

    Branschofsky, Margret

    2002-01-01T23:59:59.000Z

    The DSpace system for long-term management of institutional scholarly research repositories is now in use at the MIT Libraries; we will demonstrate the system and provide more information about its design, use at MIT, and ...

  11. Durability | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny:Revised Finding of No53197E TDrew Bittner About Us DrewDualLight-Duty2of

  12. PLUTONIUM METAL: OXIDATION CONSIDERATIONS AND APPROACH

    SciTech Connect (OSTI)

    Estochen, E.

    2013-03-20T23:59:59.000Z

    Plutonium is arguably the most unique of all metals when considered in the combined context of metallurgical, chemical, and nuclear behavior. Much of the research in understanding behavior and characteristics of plutonium materials has its genesis in work associated with nuclear weapons systems. However, with the advent of applications in fuel materials, the focus in plutonium science has been more towards nuclear fuel applications, as well as long term storage and disposition. The focus of discussion included herein is related to preparing plutonium materials to meet goals consistent with non-proliferation. More specifically, the emphasis is on the treatment of legacy plutonium, in primarily metallic form, and safe handling, packaging, and transport to meet non-proliferation goals of safe/secure storage. Elevated temperature oxidation of plutonium metal is the treatment of choice, due to extensive experiential data related to the method, as the oxide form of plutonium is one of only a few compounds that is relatively simple to produce, and stable over a large temperature range. Despite the simplicity of the steps required to oxidize plutonium metal, it is important to understand the behavior of plutonium to ensure that oxidation is conducted in a safe and effective manner. It is important to understand the effect of changes in environmental variables on the oxidation characteristics of plutonium. The primary purpose of this report is to present a brief summary of information related to plutonium metal attributes, behavior, methods for conversion to oxide, and the ancillary considerations related to processing and facility safety. The information provided is based on data available in the public domain and from experience in oxidation of such materials at various facilities in the United States. The report is provided as a general reference for implementation of a simple and safe plutonium metal oxidation technique.

  13. Automated Immobilized Metal Affinity Chromatography System for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Immobilized Metal Affinity Chromatography System for Enrichment of Escherichia coli Phosphoproteome. Automated Immobilized Metal Affinity Chromatography System for Enrichment of...

  14. Beryllium abundances in metal-poor stars

    E-Print Network [OSTI]

    K. F. Tan; J. R. Shi; G. Zhao

    2008-10-15T23:59:59.000Z

    We have determined beryllium abundances for 25 metal-poor stars based on the high resolution and high signal-to-noise ratio spectra from the VLT/UVES database. Our results confirm that Be abundances increase with Fe, supporting the global enrichment of Be in the Galaxy. Oxygen abundances based on [O I] forbidden line implies a linear relation with a slope close to one for the Be vs. O trend, which indicates that Be is probably produced in a primary process. Some strong evidences are found for the intrinsic dispersion of Be abundances at a given metallicity. The deviation of HD132475 and HD126681 from the general Be vs. Fe and Be vs. O trend favours the predictions of the superbubble model, though the possibility that such dispersion originates from the inhomogeneous enrichment in Fe and O of the protogalactic gas cannot be excluded.

  15. Spray casting of metallic preforms

    DOE Patents [OSTI]

    Flinn, John E. (Idaho Falls, ID); Burch, Joseph V. (Shelley, ID); Sears, James W. (Niskayuna, NY)

    2000-01-01T23:59:59.000Z

    A metal alloy is melted in a crucible and ejected from the bottom of the crucible as a descending stream of molten metal. The descending stream is impacted with a plurality of primary inert gas jets surrounding the molten metal stream to produce a plume of atomized molten metal droplets. An inert gas is blown onto a lower portion of the plume with a plurality of auxiliary inert gas jets to deflect the plume into a more restricted pattern of high droplet density, thereby substantially eliminating unwanted overspray and resulting wasted material. The plume is projected onto a moving substrate to form a monolithic metallic product having generally parallel sides.

  16. Functional Metal Phosphonates

    E-Print Network [OSTI]

    Perry, Houston Phillipp

    2012-02-14T23:59:59.000Z

    ......................................................... 39 12 Zr6 prepared at 205 ?C with HF as a solubilizing agent ................................ 43 13 Layered structure of Zn(O3PC6H4CN)(H2O) and Mn(O3PC6H4CN)(H2O) viewed along the c-axis. The coordinating water molecules are between... acid groups form hydrogen-bonded pairs in in Zn(O3PC6H4CO2H)(H2O) and Mn(O3PC6H4CO2H)(H2O). ..................... 55 15 Inorganic layered structure common to divalent metal phosphonates. Octahedral metal ions are coordinated by five phosphonate...

  17. FLUIDIC: Metal Air Recharged

    ScienceCinema (OSTI)

    Friesen, Cody

    2014-04-02T23:59:59.000Z

    Fluidic, with the help of ARPA-E funding, has developed and deployed the world's first proven high cycle life metal air battery. Metal air technology, often used in smaller scale devices like hearing aids, has the lowest cost per electron of any rechargeable battery storage in existence. Deploying these batteries for grid reliability is competitive with pumped hydro installations while having the advantages of a small footprint. Fluidic's battery technology allows utilities and other end users to store intermittent energy generated from solar and wind, as well as maintain reliable electrical delivery during power outages. The batteries are manufactured in the US and currently deployed to customers in emerging markets for cell tower reliability. As they continue to add customers, they've gained experience and real world data that will soon be leveraged for US grid reliability.

  18. FLUIDIC: Metal Air Recharged

    SciTech Connect (OSTI)

    Friesen, Cody

    2014-03-07T23:59:59.000Z

    Fluidic, with the help of ARPA-E funding, has developed and deployed the world's first proven high cycle life metal air battery. Metal air technology, often used in smaller scale devices like hearing aids, has the lowest cost per electron of any rechargeable battery storage in existence. Deploying these batteries for grid reliability is competitive with pumped hydro installations while having the advantages of a small footprint. Fluidic's battery technology allows utilities and other end users to store intermittent energy generated from solar and wind, as well as maintain reliable electrical delivery during power outages. The batteries are manufactured in the US and currently deployed to customers in emerging markets for cell tower reliability. As they continue to add customers, they've gained experience and real world data that will soon be leveraged for US grid reliability.

  19. Metal enrichment processes

    E-Print Network [OSTI]

    S. Schindler; A. Diaferio

    2008-01-07T23:59:59.000Z

    There are many processes that can transport gas from the galaxies to their environment and enrich the environment in this way with metals. These metal enrichment processes have a large influence on the evolution of both the galaxies and their environment. Various processes can contribute to the gas transfer: ram-pressure stripping, galactic winds, AGN outflows, galaxy-galaxy interactions and others. We review their observational evidence, corresponding simulations, their efficiencies, and their time scales as far as they are known to date. It seems that all processes can contribute to the enrichment. There is not a single process that always dominates the enrichment, because the efficiencies of the processes vary strongly with galaxy and environmental properties.

  20. Corrosion protective coating for metallic materials

    DOE Patents [OSTI]

    Buchheit, Rudolph G. (Albuquerque, NM); Martinez, Michael A. (Albuquerque, NM)

    1998-01-01T23:59:59.000Z

    Corrosion protective coatings for metallic materials, particularly aluminum and aluminum alloys, produced with simple, low-cost equipment and materials other than toxic metals or metal salts, or metal cyanides. The metallic material is cleaned, degreased, and deoxidized, the surface is converted to a substantially alkaline condition, and the surface is chemically sealed with inorganic metal compounds.