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We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

It's Elemental - The Element Mercury  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Gold Gold Previous Element (Gold) The Periodic Table of Elements Next Element (Thallium) Thallium The Element Mercury [Click for Isotope Data] 80 Hg Mercury 200.59 Atomic Number: 80 Atomic Weight: 200.59 Melting Point: 234.32 K (-38.83°C or -37.89°F) Boiling Point: 629.88 K (356.73°C or 674.11°F) Density: 13.5336 grams per cubic centimeter Phase at Room Temperature: Liquid Element Classification: Metal Period Number: 6 Group Number: 12 Group Name: none What's in a name? Named after the planet Mercury. Mercury's chemical symbol comes from the Greek word hydrargyrum, which means "liquid silver." Say what? Mercury is pronounced as MER-kyoo-ree. History and Uses: Mercury was known to the ancient Chinese and Hindus and has been found in 3500 year old Egyptian tombs. Mercury is not usually found free in nature

2

Long-Term Management and Storage of Elemental Mercury  

Broader source: Energy.gov [DOE]

In addition to banning the export of elemental mercury from the United States as of January 1, 2013, the Mercury Export Ban Act of 2008 (MEBA) required DOE to establish a facility for the long-term management and storage of elemental mercury.

3

Trace Element Analysis | Open Energy Information  

Open Energy Info (EERE)

Trace Element Analysis Trace Element Analysis Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Trace Element Analysis Details Activities (8) Areas (8) Regions (4) NEPA(0) Exploration Technique Information Exploration Group: Lab Analysis Techniques Exploration Sub Group: Fluid Lab Analysis Parent Exploration Technique: Fluid Lab Analysis Information Provided by Technique Lithology: Stratigraphic/Structural: Hydrological: Reconstructing the fluid circulation of a hydrothermal system Thermal: Cost Information Low-End Estimate (USD): 15.001,500 centUSD 0.015 kUSD 1.5e-5 MUSD 1.5e-8 TUSD / element Median Estimate (USD): 18.001,800 centUSD 0.018 kUSD 1.8e-5 MUSD 1.8e-8 TUSD / element High-End Estimate (USD): 106.0010,600 centUSD 0.106 kUSD 1.06e-4 MUSD 1.06e-7 TUSD / element

4

EIS-0423: Storage and Management of Elemental Mercury | Department of  

Broader source: Energy.gov (indexed) [DOE]

23: Storage and Management of Elemental Mercury 23: Storage and Management of Elemental Mercury EIS-0423: Storage and Management of Elemental Mercury Summary This EIS evaluates the environmental impacts associated with the reasonable alternatives for managing and storing elemental mercury at seven candidate locations (i.e., Colorado, Idaho, Missouri, Nevada, South Carolina, Texas, and Washington). The U.S. Environmental Protection Agency, the Texas Commission on Environmental Quality, and the Mesa County Board of Commissioners (Mesa County, Colorado) are cooperating agencies in the preparation of this EIS. Public Comment Opportunities None available at this time. Documents Available for Download June 5, 2012 EIS-0423-S1: Notice of Intent to Prepare a Supplemental Environmental Impact Statement Long-Term Management and Storage of Elemental Mercury

5

Traces of mercury surprise water officials By Mark Noack [ mark@hmbreview.com  

E-Print Network [OSTI]

Print Page Traces of mercury surprise water officials By Mark Noack [ mark of high mercury levels in fish found in Crystal Springs Reservoir -- an important water source, the test suggested the Crystal Springs fish population had one of the highest mercury levels in the state

6

Long-Term Management and Storage of Elemental Mercury | Department...  

Office of Environmental Management (EM)

Mercury Export Ban Act of 2008 (MEBA) (Public Law No. 110-414) requires the Department of Energy (DOE) to establish a facility for the long-term management and storage of elemental...

7

Amounts of Trace Elements in Marine Cephalopods  

Science Journals Connector (OSTI)

......Amounts of Trace Elements in Marine Cephalopods T. Ueda * M. Nakahara...H. Suzuki ** * Division of Marine Radioecology, National Institute...Power Reactor and Nuclear Fuel Development Cooperation, Tokyo...Co and Cs in 5 species of marine cephalopods were determined......

T. Ueda; M. Nakahara; T. Ishii; Y. Suzuki; H. Suzuki

1979-12-01T23:59:59.000Z

8

Vapor phase elemental sulfur amendment for sequestering mercury in contaminated soil  

DOE Patents [OSTI]

The process of treating elemental mercury within the soil is provided by introducing into the soil a heated vapor phase of elemental sulfur. As the vapor phase of elemental sulfur cools, sulfur is precipitated within the soil and then reacts with any elemental mercury thereby producing a reaction product that is less hazardous than elemental mercury.

Looney, Brian B.; Denham, Miles E.; Jackson, Dennis G.

2014-07-08T23:59:59.000Z

9

HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 Trace elements and alkaliTrace elements and alkali  

E-Print Network [OSTI]

elements in fossil - and waste-derived fuelsTrace elements in fossil - and waste-derived fuels Coal Peat Heavy fuel oil Pet coke MSW RDF Wood Waste wood Waste paper Scrap tyres Sew. sludge Hg 0.02-3 ~0.07 .153 Behaviour of trace elements in coalBehaviour of trace elements in coal combustion flue gasescombustion flue

Zevenhoven, Ron

10

Oxyfuel CO2 compression: The gas phase reaction of elemental mercury and \\{NOx\\} at high pressure and absorption into nitric acid  

Science Journals Connector (OSTI)

Abstract Oxyfuel combustion is a technology which combusts coal in oxygen and recycled flue gas, producing a carbon dioxide rich flue gas for sequestration. Oxyfuel flue gas contains trace amounts of elemental mercury, which may corrode brazed aluminium heat exchangers used in the carbon dioxide purification system. International gas vendors have tested the use of the compression system to remove other flue gas impurities such as NOx; however, the reaction mechanism of mercury and its reaction products with \\{NOx\\} and nitric acid formed with condensed water vapour are unclear. This study used lab scale experiments to study the absorption of gaseous elemental mercury into nitric acid and the gas phase reaction between mercury and nitrogen dioxide formed from oxidised NO at pressures up to 25bar. It was observed that mercury has limited absorption into nitric acid and may partially desorb out of solution after depressurisation. On the other hand, mercury reacted readily with nitrogen dioxide (formed from nitric oxide oxidation at high pressure) in the gas phase. These gas phase reactions from the oxidation of nitric oxide to nitrogen dioxide to the subsequent oxidation of elemental mercury by nitrogen dioxide were predicted using existing global kinetic equations. The limited absorption of gaseous elemental mercury in nitric acid and significant oxidation of gaseous elemental mercury by nitrogen dioxide suggests that the primary removal step for elemental mercury is through the gas phase reaction. Oxyfuel compression circuits should therefore allow sufficient residence time for this gas phase reaction to occur.

Timothy Ting; Rohan Stanger; Terry Wall

2014-01-01T23:59:59.000Z

11

Effect of Microbial Activity on Trace Element Release from Sewage  

E-Print Network [OSTI]

Effect of Microbial Activity on Trace Element Release from Sewage Sludge S H A B N A M Q U R E S H in mobilization of trace elements from land-applied wastewater sludge is not well-defined. Our study examined-effective management alternative. Unfor- tunately, sewage sludge also contains potentially toxic trace elements

Walter, M.Todd

12

Trace element emissions. Semi-annual report, October 1994--February 1995  

SciTech Connect (OSTI)

Many trace elements can exist in raw coal gas either in the form of metallic vapors or gaseous compounds which, besides their action on potentially ``very clean`` advanced power generating systems such as fuel cells and gas turbines, can also be detrimental to plant and animal life when released into the atmosphere. Therefore, volatile trace contaminants from coal which can also be toxic must be removed before they become detrimental to both power plant performance/endurance and the environment. Five trace elements were selected in this project based on: abundance in solid coal, volatility during gasification, effects on downstream systems and toxicity to plant and animal life. An understanding was sought in this investigation of the interactions of these five trace elements (and their high temperature species) with the different components in integrated cleanup and power generating systems, as well as the ultimate effects with respect to atmospheric emissions. Utilizing thermodynamic calculations and various experimental techniques, it was determined that a number of trace contaminants that exist in coal may be substantially removed by flyash, and after that by different sorbent systems. High temperature cleanup of contaminants by sorbents such as zinc titanate, primarily to remove sulfur, can also absorb some metallic contaminants such as cadmium and antimony. Further polishing will be required, however, to eliminate trace contaminant species incorporating the elements arsenic, selemium, lead, and mercury.

Pigeaud, A.; Maru, H.; Wilemski, G.; Helble, J.

1995-02-01T23:59:59.000Z

13

Trace element content of magnetohydrodynamic coal combustion effluents  

Science Journals Connector (OSTI)

Trace element contents from effluents of a simulated coal-fired magnetohydrodynamic (MHD) combustion process have been determined using thermal neutron activation analysis techniques. The quality control consi...

M. S. Akanni; V. O. Ogugbuaja; W. D. James

1983-01-01T23:59:59.000Z

14

Method for the removal of elemental mercury from a gas stream  

DOE Patents [OSTI]

A method is provided to remove elemental mercury from a gas stream by reacting the gas stream with an oxidizing solution to convert the elemental mercury to soluble mercury compounds. Other constituents are also oxidized. The gas stream is then passed through a wet scrubber to remove the mercuric compounds and oxidized constituents.

Mendelsohn, Marshall H. (Downers Grove, IL); Huang, Hann-Sheng (Darien, IL)

1999-01-01T23:59:59.000Z

15

An evaluation of elemental mercury vapor exposure to children due to silver-mercury dental amalgam restorations  

E-Print Network [OSTI]

AN EVALUATION OF ELEMENTAL MERCURY VAPOR EXPOSURE TO CHILDREN DUE TO SILVER-MERCURY DENTAL AMALGAM RESTORATIONS A Thesis By RONALD DALE TAYLOR Submitted to the Office of Graduate Studies College Texas A&M University in partial fulfillment.... . . . . 1X LIST OF FIGURES. I. INTRODUCTION. II ' LITERATURE REVIEW Dental Mercury Toxicology Body Burden. Inhalation Exposure. Childhood Exposure III. METHODOLOGY. . . . 3 5 . . . 8 . . . 10 . . . 14 . 16 Human Research Committee...

Taylor, Ronald Dale

1989-01-01T23:59:59.000Z

16

Distribution of hazardous air pollutant trace elements, total sulfur, and ash in coals from five Tertiary basins in the Rocky Mountain Region  

SciTech Connect (OSTI)

Arithmetic mean values of the contents of hazardous air pollutant (HAP) trace elements named in the 1990 Clean Air Act Amendments (antimony, arsenic, beryllium, cadmium, chromium, cobalt, lead, manganese, mercury, nickel, selenium, and uranium), ash, and total sulfur were statistically compared on a whole-coal basis for Paleocene coals from five Tertiary basins in the Rocky Mountain Region. The study of proximate and elemental analyses indicate a relationship between trace element contents and paleogeography.

Ellis, M.S.; Stricker, G.D.; Flores, R.M. [Geological Survey, Denver, CO (United States)

1994-12-31T23:59:59.000Z

17

Trace elements in oil shale. Progress report, 1979-1980  

SciTech Connect (OSTI)

The purpose of this research program is to understand the potential impact of an oil shale industry on environmental levels of trace contaminants in the region. The program involves a comprehensive study of the sources, release mechanisms, transport, fate, and effects of toxic trace chemicals, principally the trace elements, in an oil shale industry. The overall objective of the program is to evaluate the environmental and health consequences of the release of toxic trace elements by shale and oil production and use. The baseline geochemical survey shows that stable trace elements maps can be constructed for numerous elements and that the trends observed are related to geologic and climatic factors. Shale retorted by above-ground processes tends to be very homogeneous (both in space and in time) in trace element content. Leachate studies show that significant amounts of B, F, and Mo are released from retorted shales and while B and Mo are rapidly flushed out, F is not. On the other hand, As, Se, and most other trace elements are not present in significant quantities. Significant amounts of F and B are also found in leachates of raw shales. Very large concentrations of reduced sulfur species are found in leachates of processed shale. Very high levels of B and Mo are taken up in some plants growing on processed shale with and without soil cover. There is a tendency for some trace elements to associate with specific organic fractions, indicating that organic chelation or complexation may play an important role. Many of the so-called standard methods for analyzing trace elements in oil shale-related materials are inadequate. A sampling manual is being written for the environmental scientist and practicing engineer. A new combination of methods is developed for separating the minerals in oil shale into different density fractions. Microbial investigations have tentatively identified the existence of thiobacilli in oil shale materials such as leachates. (DC)

Chappell, W R

1980-01-01T23:59:59.000Z

18

E-Print Network 3.0 - atmospheric trace element Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: 6 2.0 Sources and Deposition of Trace Metals Trace elements enter the atmosphere via both natural... 5 Chapter 2: Sources and Deposition of Trace Metals...

19

Larval Behavior and Natural Trace Element Signatures as Indicators of Crustacean Population Connectivity  

E-Print Network [OSTI]

variability in an atlas of trace element signatures forin creating a trace element atlas, our results show thatstage to create a trace element atlas in 2009 (Table 4.2),

Miller, Seth Haylen

2011-01-01T23:59:59.000Z

20

A study on some trace elements in Chilean seafood  

Science Journals Connector (OSTI)

Levels of essential and toxic trace elements in six marine species greatly in demand in the international market (canned pink clams, razor clams, clams, king crab, sardines, and frozen albacore tuna fish) were...

N. Gras; L. Munoz; M. Thieck

1993-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "mercury trace elements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

NETL: IEP - Mercury and Air Toxic Element Impacts of CCB Disposal and  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mercury and Air Toxic Element Impacts of CCB Disposal and Utilization Mercury and Air Toxic Element Impacts of CCB Disposal and Utilization The goal of the proposed effort is to evaluate the impact of mercury and other air toxic elements on the management of CCBs. Supporting objectives are to 1) determine the release potential of selected air toxic elements, including mercury and arsenic, from CCBs under specific environmental conditions; 2) increase the database of information on mercury and other air toxic element releases for CCBs; 3) develop comparative laboratory and field data; and 4) develop appropriate laboratory and field protocols. The specific mechanisms of air toxic element releases to be evaluated will be leaching releases, vapor releases to the atmosphere, and biologically induced leaching and vapor releases.

22

Removal of Elemental Mercury from a Gas Stream Facilitated by a Non-Thermal Plasma Device  

SciTech Connect (OSTI)

Mercury generated from anthropogenic sources presents a difficult environmental problem. In comparison to other toxic metals, mercury has a low vaporization temperature. Mercury and mercury compounds are highly toxic, and organic forms such as methyl mercury can be bio-accumulated. Exposure pathways include inhalation and transport to surface waters. Mercury poisoning can result in both acute and chronic effects. Most commonly, chronic exposure to mercury vapor affects the central nervous system and brain, resulting in neurological damage. The CRE technology employs a series of non-thermal, plasma-jet devices to provide a method for elemental mercury removal from a gas phase by targeting relevant chemical reactions. The technology couples the known chemistry of converting elemental mercury to ionic compounds by mercury-chlorine-oxygen reactions with the generation of highly reactive species in a non-thermal, atmospheric, plasma device. The generation of highly reactive metastable species in a non-thermal plasma device is well known. The introduction of plasma using a jet-injection device provides a means to contact highly reactive species with elemental mercury in a manner to overcome the kinetic and mass-transfer limitations encountered by previous researchers. To demonstrate this technology, WRI has constructed a plasma test facility that includes plasma reactors capable of using up to four plasma jets, flow control instrumentation, an integrated control panel to operate the facility, a mercury generation system that employs a temperature controlled oven and permeation tube, combustible and mercury gas analyzers, and a ductless fume hood designed to capture fugitive mercury emissions. Continental Research and Engineering (CR&E) and Western Research Institute (WRI) successfully demonstrated that non-thermal plasma containing oxygen and chlorine-oxygen reagents could completely convert elemental mercury to an ionic form. These results demonstrate potential the application of this technology for removing elemental mercury from flue gas streams generated by utility boilers. On an absolute basis, the quantity of reagent required to accomplish the oxidation was small. For example, complete oxidation of mercury was accomplished using a 1% volume fraction of oxygen in a nitrogen stream. Overall, the tests with mercury validated the most useful aspect of the CR&E technology: Providing a method for elemental mercury removal from a gas phase by employing a specific plasma reagent to either increase reaction kinetics or promote reactions that would not have occurred under normal circumstances.

Charles Mones

2006-12-01T23:59:59.000Z

23

Trace element fingerprinting of ancient Chinese gold with femtosecond laser  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trace element fingerprinting of ancient Chinese gold with femtosecond laser Trace element fingerprinting of ancient Chinese gold with femtosecond laser ablation-inductivity coupled mass spectrometry Title Trace element fingerprinting of ancient Chinese gold with femtosecond laser ablation-inductivity coupled mass spectrometry Publication Type Journal Article Year of Publication 2009 Authors Brostoff, Lynn B., Jhanis J. Gonzalez, Paul Jett, and Richard E. Russo Journal Journal of Archeological Science Volume 36 Start Page 461 Issue 2 Pagination 461-466 Date Published 02/2009 Keywords Ancient gold, femtosecond, la-icp-ms, Trace element Abstract In this collaborative investigation, femtosecond laser ablation-inductively coupled mass spectrometry (LA-ICP-MS) was applied to the study of a remarkable group of ancient Chinese gold objects in the Smithsonian's Freer Gallery of Art and Arthur M. Sackler Gallery. Taking advantage of the superior ablation characteristics and high precision of a femtosecond 266 nm Ti:sapphire laser at Lawrence Berkeley National Laboratory, major, minor and trace element concentrations in the gold fragments were quantified. Results validate use of femtosecond LA-ICP-MS for revealing ''fingerprints'' in minute gold samples. These fingerprints allow us to establish patterns based on the association of silver, palladium and platinum that support historical, technical and stylistic relationships, and shed new light on these ancient objects.

24

Trace element partitioning between type B CAI melts and melilite and spinel: Implications for trace element distribution  

E-Print Network [OSTI]

. Partition coefficients between intermediate composition melilites and CAI melt are the following: Li, 0.5 size energetics analysis is used to assess isovalent partitioning into the different cation sites, interpreta- tion of the trace element and isotope compositions of CAIs, particularly the light elements Li

Mcdonough, William F.

25

Trace element partitioning in Texas lignite  

E-Print Network [OSTI]

), but collected from the one of the secondary tanks which contains the slurry that exits the scrubber tower and is either recycled or sent to the thickener tank. 10. Bag house FGD (flue gas desulfurization system) fly ash fines (BHA): white-gray, dry, fine... Station. Concentrations of 41 elements were determined by neutron activation analysis. The particle size distribution was determined by Coulter counter analysis for the fly ash collected from the electrostatic precipitator outlets and from the flue...

Acevedo, Lillian Esther

1989-01-01T23:59:59.000Z

26

Identification and measurement of neutron-absorbing elements on Mercury's David J. Lawrence a,*, William C. Feldman b  

E-Print Network [OSTI]

Identification and measurement of neutron-absorbing elements on Mercury's surface David J. Lawrence be an important discriminator for testing whether Mercury's high bulk metal fraction stemmed from aerodynamic drag

Nittler, Larry R.

27

Mercury and Air Toxic Element Impacts of Coal Combustion By-Product Disposal and Utilizaton  

SciTech Connect (OSTI)

The University of North Dakota Energy & Environmental Research Center (EERC) conducted a multiyear study to evaluate the impact of mercury and other air toxic elements (ATEs) on the management of coal combustion by-products (CCBs). The ATEs evaluated in this project were arsenic, cadmium, chromium, lead, nickel, and selenium. The study included laboratory tasks to develop measurement techniques for mercury and ATE releases, sample characterization, and release experiments. A field task was also performed to measure mercury releases at a field site. Samples of fly ash and flue gas desulfurization (FGD) materials were collected preferentially from full-scale coal-fired power plants operating both without and with mercury control technologies in place. In some cases, samples from pilot- and bench-scale emission control tests were included in the laboratory studies. Several sets of 'paired' baseline and test fly ash and FGD materials collected during full-scale mercury emission control tests were also included in laboratory evaluations. Samples from mercury emission control tests all contained activated carbon (AC) and some also incorporated a sorbent-enhancing agent (EA). Laboratory release experiments focused on measuring releases of mercury under conditions designed to simulate CCB exposure to water, ambient-temperature air, elevated temperatures, and microbes in both wet and dry conditions. Results of laboratory evaluations indicated that: (1) Mercury and sometimes selenium are collected with AC used for mercury emission control and, therefore, present at higher concentrations than samples collected without mercury emission controls present. (2) Mercury is stable on CCBs collected from systems both without and with mercury emission controls present under most conditions tested, with the exception of vapor-phase releases of mercury exposed to elevated temperatures. (3) The presence of carbon either from added AC or from unburned coal can result in mercury being sorbed onto the CCB when exposed to ambient-temperature air. The environmental performance of the mercury captured on AC used as a sorbent for mercury emission control technologies indicated that current CCB management options will continue to be sufficiently protective of the environment, with the potential exception of exposure to elevated temperatures. The environmental performance of the other ATEs investigated indicated that current management options will be appropriate to the CCBs produced using AC in mercury emission controls.

David Hassett; Loreal Heebink; Debra Pflughoeft-Hassett; Tera Buckley; Erick Zacher; Mei Xin; Mae Sexauer Gustin; Rob Jung

2007-03-31T23:59:59.000Z

28

Summary Final Long-Term Management and Storage of Elemental Mercury Supplemental Environmental Impact Statement  

Broader source: Energy.gov (indexed) [DOE]

Environmental Impact Statement Environmental Impact Statement Final LONG-TERM MANAGEMENT AND STORAGE OF ELEMENTAL MERCURY Final Supplemental Environmental Impact Statement LONG-TERM MANAGEMENT AND STORAGE OF ELEMENTAL MERCURY DOE/EIS-0423-S1 September 2013 SUMMARY AND GUIDE FOR STAKEHOLDERS U.S. Department of Energy Office of Environmental Management Washington, DC AVAILABILITY OF THIS FINAL LONG-TERM MANAGEMENT AND STORAGE OF ELEMENTAL MERCURY SUPPLEMENTAL ENVIRONMENTAL IMPACT STATEMENT For additional information on this Mercury Storage SEIS, contact: David Levenstein, Document Manager Office of Environmental Compliance (EM-11) U.S. Department of Energy Post Office Box 2612 Germantown, MD 20874 Website: http://www.mercurystorageeis.com Printed with soy ink on recycled paper FINAL LONG-TERM MANAGEMENT AND

29

STEIN'S METHOD, HEAT KERNEL, AND TRACES OF POWERS OF ELEMENTS OF COMPACT LIE GROUPS  

E-Print Network [OSTI]

STEIN'S METHOD, HEAT KERNEL, AND TRACES OF POWERS OF ELEMENTS OF COMPACT LIE GROUPS JASON FULMAN Abstract. Combining Stein's method with heat kernel techniques, we show that the trace of the jth power There is a large literature on the traces of powers of random elements of compact Lie groups. One of the earliest

Fulman, Jason

30

STEIN'S METHOD, HEAT KERNEL, AND TRACES OF POWERS OF ELEMENTS OF COMPACT LIE GROUPS  

E-Print Network [OSTI]

STEIN'S METHOD, HEAT KERNEL, AND TRACES OF POWERS OF ELEMENTS OF COMPACT LIE GROUPS JASON FULMAN Abstract. Combining Stein's method with heat kernel techniques, we show that the trace of the jth power on the traces of powers of random elements of compact Lie groups. One of the earliest results is due to Diaconis

Fulman, Jason

31

Microbial acidification and pH effects on trace element release from sewage sludge  

E-Print Network [OSTI]

Microbial acidification and pH effects on trace element release from sewage sludge Shabnam Qureshia; Trace metals; Mobilization; Land application 1. Introduction Trace elements in land-applied wastewater sludge (sewage biosolids) are potentially phyto- or zoo-toxic if present in sufficient concentration

Walter, M.Todd

32

DOE Mercury Control Research  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mercury Control Research Mercury Control Research Air Quality III: Mercury, Trace Elements, and Particulate Matter September 9-12, 2002 Rita A. Bajura, Director National Energy Technology Laboratory www.netl.doe.gov 169330 RAB 09/09/02 2 Potential Mercury Regulations MACT Standards * Likely high levels of Hg reduction * Compliance: 2007 Clean Power Act of 2001 * 4-contaminant control * 90% Hg reduction by 2007 Clear Skies Act of 2002 * 3-contaminant control * 46% Hg reduction by 2010 * 70% Hg reduction by 2018 * Hg emission trading President Bush Announcing Clear Skies Initiative February 14, 2002 169330 RAB 09/09/02 3 Uncertainties Mercury Control Technologies * Balance-of-plant impacts * By-product use and disposal * Capture effectiveness with low-rank coals * Confidence of performance 169330 RAB 09/09/02 4

33

Engineering development of selective agglomeration: Trace element removal study  

SciTech Connect (OSTI)

Southern Company Services, Inc., (SCS) was contracted in 1989 by the US Department of Energy (DOE) to develop a commercially acceptable selective agglomeration technology to enhance the use of high-sulfur coals by 1993. The project scope involved development of a bench-scale process and components, as well as the design, testing, and evaluation of a proof-of-concept (POC) facility. To that end, a two-ton-per-hour facility was constructed and tested near Wilsonville, Alabama. Although it was not the primary focus of the test program, SCS also measured the ability of selective agglomeration to remove trace elements from coal. This document describes the results of that program.

Not Available

1993-09-01T23:59:59.000Z

34

E-Print Network 3.0 - airborne trace element Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Sample search results for: airborne trace element Page: << < 1 2 3 4 5 > >> 1 AIR-DEPOSITED POLLUTION IN THE ANACOSTIA RIVER WATERSHED Summary: pollution in Lake...

35

An evaluation of trace element release associated with acid mine drainage  

SciTech Connect (OSTI)

The determination of trace element release from geologic materials, such as oil shale and coal overburden, is important for proper solid waste management planning. The objective of this study was to determine a correlation between release using the following methods: (1) sequential selective dissolution for determining trace element residencies, (2) toxicity characteristic leaching procedure (TCLP), and (3) humidity cell weathering study simulating maximum trace element release. Two eastern oil shales were used, a New Albany shale that contains 4.6 percent pyrite, and a Chattanooga shale that contains 1.5 percent pyrite. Each shale was analyzed for elemental concentrations by soluble, adsorbed, organic, carbonate, and sulfide phases. The results of the results of the selective dissolution studies show that each trace element has a unique distribution between the various phases. Thus, it is possible to predict trace element release based on trace element residency. The TCLP results show that this method is suitable for assessing soluble trace element release but does not realistically assess potential hazards. The results of the humidity cell studies do demonstrate a more reasonable method for predicting trace element release and potential water quality hazards. The humidity cell methods, however, require months to obtain the required data with a large number of analytical measurements. When the selective dissolution data are compared to the trace element concentrations in the TCLP and humidity cell leachates, it is shown that leachate concentrations are predicted by the selective dissolution data. Therefore, selective dissolution may represent a rapid method to assess trace element release associated with acid mine drainage.

Sullivan, P.J.; Yelton, J.L. (Univ. of Wyoming Research Corp., Laramie (United States))

1988-12-01T23:59:59.000Z

36

JV Task-123 Determination of Trace Element Concentrations at an Eastern Bituminous Coal Plant Employing an SCR and Wet FGD  

SciTech Connect (OSTI)

The Energy & Environmental Research Center (EERC), in partnership with Babcock & Wilcox (B&W) and with funding from U.S. Department of Energy (DOE), conducting tests to prove that a high level of mercury control (>90%) can be achieved at a power plant burning a high-sulfur eastern bituminous coal. With funding from the Electric Power Research Institute (EPRI), DOE, and Center for Air Toxic Metals{reg_sign} (CATM{reg_sign}) Affiliates Program, the EERC completed an additional sampling project to provide data as to the behavior of a number of trace elements across the various pollution control devices, with a special emphasis on the wet flue gas desulfurization (FGD) system. Results showed that the concentrations of almost all the elements of interest leaving the stack were very low, and a high percentage of the trace elements were captured in the electrostatic precipitator (ESP) (for most, >80%). Although, with a few exceptions, the overall mass balances were generally quite good, the mass balances across the wet FGD were more variable. This is most likely a result of some of the concentrations being very low and also the uncertainties in determining flows within a wet FGD.

Dennis Laudal

2008-05-01T23:59:59.000Z

37

Trace Element Analysis At Walker-Lane Transitional Zone Region (Coolbaugh,  

Open Energy Info (EERE)

Trace Element Analysis At Walker-Lane Transitional Zone Region (Coolbaugh, Trace Element Analysis At Walker-Lane Transitional Zone Region (Coolbaugh, Et Al., 2010) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Trace Element Analysis At Walker-Lane Transitional Zone Region (Coolbaugh, Et Al., 2010) Exploration Activity Details Location Walker-Lane Transition Zone Geothermal Region Exploration Technique Trace Element Analysis Activity Date Usefulness useful DOE-funding Unknown Notes "This second paper provides more detailed documentation on water and rock geochemistries and describes diagnostic major and trace element ratios and concentrations that can be used to distinguish tufa columns formed from thermal waters from those that formed from non-thermal waters." "In addition to providing a potentially diagnostic lithogeochemical tool for

38

Trace Element Analysis At Nw Basin & Range Region (Coolbaugh, Et Al., 2010)  

Open Energy Info (EERE)

Trace Element Analysis At Nw Basin & Range Region (Coolbaugh, Et Al., 2010) Trace Element Analysis At Nw Basin & Range Region (Coolbaugh, Et Al., 2010) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Trace Element Analysis At Nw Basin & Range Region (Coolbaugh, Et Al., 2010) Exploration Activity Details Location Northwest Basin and Range Geothermal Region Exploration Technique Trace Element Analysis Activity Date Usefulness useful DOE-funding Unknown Notes "This second paper provides more detailed documentation on water and rock geochemistries and describes diagnostic major and trace element ratios and concentrations that can be used to distinguish tufa columns formed from thermal waters from those that formed from non-thermal waters." "In addition to providing a potentially diagnostic lithogeochemical tool for

39

Trace element partitioning between baddeleyite and carbonatite melt at high pressures and high temperatures  

E-Print Network [OSTI]

as the heavy rare earth elements (HREE) prefer to enter baddeleyite rather than carbonate melts (D>1), whereas the light rare earth elements (LREE) and other trace elements behave incompatibly (D in carbonatite melts. Baddeleyite is known to accumulate the high field strength elements (HFSE) and some rare

40

Trace element behavior in the fluidized bed gasification of solid recovered fuels A thermodynamic study  

Science Journals Connector (OSTI)

Gasification of biomass and recycled fuels is of particular interest for the efficient production of power and heat. Trace elements present as impurities in the product gas should be removed very efficiently. The objective of this work has been to develop and test thermodynamic models for the reactions of trace elements with chlorine and sulfur in the gasification processes of recycled fuels. In particular, the chemical reactions of trace elements with main thermochemical conversion products, main ash components, and bed and sorbent material are implemented into the model. The possibilities of gas cleaning devices in condensing and removing the trace element compounds are studied by establishing the volatilization tendency of trace element compounds in reducing gases. The results obtained with the model are compared with the measured data of trace elements of gasification experiments using solid recovered fuel as feedstock. Some corresponding studies in the literature are also critically reviewed and compared. The observed discrepancies may be attributed to differences in thermodynamic databases applied and experimental arrangements. The method of removing gaseous trace elements by condensation is already in use in the 160MWth waste gasification plant in Lahti, Finland.

Jukka Konttinen; Rainer Backman; M. Hupa; Antero Moilanen; Esa Kurkela

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mercury trace elements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Trace-Element Distribution In An Active Hydrothermal System, Roosevelt Hot  

Open Energy Info (EERE)

Trace-Element Distribution In An Active Hydrothermal System, Roosevelt Hot Trace-Element Distribution In An Active Hydrothermal System, Roosevelt Hot Springs Thermal Area, Utah Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: Trace-Element Distribution In An Active Hydrothermal System, Roosevelt Hot Springs Thermal Area, Utah Details Activities (3) Areas (1) Regions (0) Abstract: Chemical interaction of thermal fluids with reservoir rock in the Roosevelt Hot Springs thermal area, Utah, has resulted in the development of characteristic trace-element dispersion patterns. Multielement analyses of surface rock samples, soil samples and drill cuttings from deep exploration wells provide a three-dimensional perspective of chemical redistribution within this structurally-controlled hot-water geothermal system. Five distinctive elemental suites of chemical enrichment are

42

Trace Element Analysis At Socorro Mountain Area (Owens, Et Al., 2005) |  

Open Energy Info (EERE)

Trace Element Analysis At Socorro Mountain Area (Owens, Et Al., 2005) Trace Element Analysis At Socorro Mountain Area (Owens, Et Al., 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Trace Element Analysis At Socorro Mountain Area (Owens, Et Al., 2005) Exploration Activity Details Location Socorro Mountain Area Exploration Technique Trace Element Analysis Activity Date Usefulness not indicated DOE-funding Unknown Notes In order to determine which of the faults in these regions were active and open to hydrothermal fluid circulation, we have employed selective ion geochemistry that is a new geochemical method capable of detecting anomalous concentrations for up to 47 elements transported to soils by geochemical cells or low pressure vapors. Enzyme leach and Terrasol leach are two such techniques. This method has to datae been mostly applied to

43

Time Series of Trace Element Concentrations Calculated from  

E-Print Network [OSTI]

a). A total of 120 samples were collected at sites within the Bay, outside the Golden Gate receives many waste water discharges, especially in areas south of the Dumbarton Bridge, that contain trace

44

Trace Element Geochemical Zoning in the Roosevelt Hot Springs Thermal Area,  

Open Energy Info (EERE)

Page Page Edit with form History Facebook icon Twitter icon » Trace Element Geochemical Zoning in the Roosevelt Hot Springs Thermal Area, Utah Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Paper: Trace Element Geochemical Zoning in the Roosevelt Hot Springs Thermal Area, Utah Abstract Chemical interaction of thermal brines with reservoir rock in the Roosevelt Hot Springs thermal area has resulted in the development of distinctive trace element signatures. Geochemical analysis of soil sample, shallow temperature gradient drill hole cuttings and deep drill hole cutting provides a three dimensional perspective of trace element distributions within the system. Distributions of As, Hg and Li provide the clearest expression of hydrothermal activity. Comparison of these distribution

45

Trace element mineral transformations associated with hydration and recarbonation of retorted oil shale  

Science Journals Connector (OSTI)

A laboratory study was conducted to evaluate the influence of hydration and recarbonation on the solidphase distribution of trace elements in retorted oil shale. The oil shale samples were retorted by the Paraho ...

M. E. Essington

46

E-Print Network 3.0 - aristotelis trace elements Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

results for: aristotelis trace elements Page: << < 1 2 3 4 5 > >> 1 Examen LA207 Matlab: applications en mecanique Summary: en imposant la vue de dessus avec la fonction...

47

Enhanced Elemental Mercury Removal from Coal-fired Flue Gas by Sulfur-chlorine Compounds  

E-Print Network [OSTI]

III T; Murphy J T. DOE/NETLs Phase II Mercury ControlFired Power Plants, DOE/NETL Mercury R&D Program Review,

Miller, Nai-Qiang Yan-Zan Qu Yao Chi Shao-Hua Qiao Ray Dod Shih-Ger Chang Charles

2008-01-01T23:59:59.000Z

48

Adsorption and Oxidation of Elemental Mercury over Ce-MnOx/Ti-PILCs  

Science Journals Connector (OSTI)

A series of innovative CeMn/Ti-pillared-clay (CeMn/Ti-PILC) catalysts combining the advantages of PILCs and CeMn were investigated for elemental mercury (Hg0) capture at 100350 C in the absence of HCl in the flue gas. ... The catalyst characterization indicated that the 6%Ce-6%MnOx/Ti-PILC catalyst possessed a large specific surface area and high dispersion of Ce and Mn on the surface. ... The experimental results indicated that the 6%Ce-6%MnOx/Ti-PILC catalyst exhibited high Hg0 capture (>90%) at 100350 C. ...

Chuan He; Boxiong Shen; Jianhong Chen; Ji Cai

2014-06-23T23:59:59.000Z

49

Zevenhoven & Kilpinen TRACE ELEMENTS, ALKALI METALS 19.6.2001 8-1 Chapter 8 Trace elements,  

E-Print Network [OSTI]

air pollutants), "known or suspected of causing cancer or other serious health effects" (see also, in part stemming from anthropogenic sources, i.e. pollution. In wastes and waste-derived fuels the "trace to fouling of turbine blades (mainly Ca)or pollute or poison catalysts (mainly As) or sorbents downstream

Zevenhoven, Ron

50

Trace elements in co-combustion of solid recovered fuel and coal  

Science Journals Connector (OSTI)

Trace element partitioning in co-combustion of a bituminous coal and a solid recovered fuel (SRF) was studied in an entrained flow reactor. The experiments were carried out at conditions similar to pulverized coal combustion, with SRF shares of 7.9wt.% (wet basis), 14.8wt.% and 25.0wt.%. In addition, the effect of additives such as NaCl, PVC, ammonium sulphate, and kaolinite on trace element partitioning was investigated. The trace elements studied were As, Cd, Cr, Pb, Sb and Zn, since these elements were significantly enriched in SRF as compared to coal. During the experiments, bottom ash was collected in a chamber, large fly ash particles were collected by a cyclone with a cut-off diameter of ~2.5?m, and the remaining fly ash particles were gathered in a filter. It was found that when coal was co-fired with SRF, the As, Cd, Pb, Sb and Zn content in filter ash/cyclone ash increased almost linearly with their content in fuel ash. This linear tendency was affected when the fuels were mixed with additives. The volatility of trace elements during combustion was assessed by applying a relative enrichment (RE) factor, and TEMEDS analysis was conducted to provide qualitative interpretations. The results indicated that As, Cd, Pb, Sb and Zn were highly volatile when co-firing coal and SRF, whereas the volatility of Cr was relatively low. Compared with coal combustion, co-firing of coal and SRF slightly enhanced the volatility of Cd, Pb and Zn, but reduced the volatility of Cr and Sb. The Cl-based additives increased the volatility of Cd, Pb and As, whereas addition of ammonium sulphate generally decreased the volatility of trace elements. Addition of kaolinite reduced the volatility of Pb, while the influence on other trace elements was insignificant. The results from the present work imply that trace element emission would be significantly increased when coal is co-fired with SRF, which may greatly enhance the toxicity of the dusts from coal-fired power plant. In order to minimize trace element emission in co-combustion, in addition to lowering the trace element content in SRF, utilizing SRF with low Cl content and coal with high S and aluminosilicates content would be desirable.

Hao Wu; Peter Glarborg; Flemming Jappe Frandsen; Kim Dam-Johansen; Peter Arendt Jensen; Bo Sander

2013-01-01T23:59:59.000Z

51

Trace Element Analysis At Central Nevada Seismic Zone Region (Coolbaugh, Et  

Open Energy Info (EERE)

Coolbaugh, Et Coolbaugh, Et Al., 2010) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Trace Element Analysis At Central Nevada Seismic Zone Region (Coolbaugh, Et Al., 2010) Exploration Activity Details Location Central Nevada Seismic Zone Geothermal Region Exploration Technique Trace Element Analysis Activity Date Usefulness useful DOE-funding Unknown Notes "This second paper provides more detailed documentation on water and rock geochemistries and describes diagnostic major and trace element ratios and concentrations that can be used to distinguish tufa columns formed from thermal waters from those that formed from non-thermal waters." "In addition to providing a potentially diagnostic lithogeochemical tool for geothermal exploration, the analysis of lithium and other elements in tufa

52

Trace elements in brown coal and its products of combustion  

Science Journals Connector (OSTI)

Concentrations of 38 elements in brown coal, bottom ash and size fractionated ESP coal ash from the Belchatw I Power Plant were determined by INAA. Based on enrichment factors calculated relatively to iron an...

U. Tomza; P. Kaleta

1986-10-20T23:59:59.000Z

53

Trace Element Analysis At Roosevelt Hot Springs Area (Christensen, Et Al.,  

Open Energy Info (EERE)

Christensen, Et Al., Christensen, Et Al., 1983) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Trace Element Analysis At Roosevelt Hot Springs Area (Christensen, Et Al., 1983) Exploration Activity Details Location Roosevelt Hot Springs Area Exploration Technique Trace Element Analysis Activity Date Usefulness useful DOE-funding Unknown Notes Three of the recognized trace-element suites are characteristic of the surface and near-surface environment. These are: (1) concentrations of As, Sb, Be and Hg associated with siliceous material at the location of liquid discharge, fluid mixing, or at boiling interfaces; (2) deposits of Mn and Fe oxides containing concentrations of Ba, W, Be, Co, Cu, As, Sb and Hg formed by the oxidation of cooled brines; and (3) high concentrations of Hg

54

Trace Element Analysis At Northern Basin & Range Region (Coolbaugh, Et Al.,  

Open Energy Info (EERE)

At Northern Basin & Range Region (Coolbaugh, Et Al., At Northern Basin & Range Region (Coolbaugh, Et Al., 2010) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Trace Element Analysis At Northern Basin & Range Region (Coolbaugh, Et Al., 2010) Exploration Activity Details Location Northern Basin and Range Geothermal Region Exploration Technique Trace Element Analysis Activity Date Usefulness useful DOE-funding Unknown Notes "This second paper provides more detailed documentation on water and rock geochemistries and describes diagnostic major and trace element ratios and concentrations that can be used to distinguish tufa columns formed from thermal waters from those that formed from non-thermal waters." "In addition to providing a potentially diagnostic lithogeochemical tool for

55

EIS-0423-S1: Supplemental Environmental Impact Statement for the Long-Term Management and Storage of Elemental Mercury  

Broader source: Energy.gov [DOE]

This SEIS supplements the January 2011 Environmental Impact Statement for the Long-Term Management and Storage of Elemental Mercury. It will analyze the potential environmental impact for a facility at and in the vicinity of the Waste Isolation Pilot Plant near Carlsbad, New Mexico.

56

Correlations of trace elements in breast human tissues: Evaluation of spatial distribution using {mu}-XRF  

SciTech Connect (OSTI)

The aim of this work is to investigate microscopic correlations between trace elements in breast human tissues. A synchrotron X-ray fluorescence microprobe system ({mu}-XRF) was used to obtain two-dimensional distribution of trace element Ca, Fe, Cu and Zn in normal (6 samples) and malignant (14 samples) breast tissues. The experiment was performed in X-ray Fluorescence beam line at Laboratorio Nacional de Luz Sincrotron (LNLS), Campinas, Brazil. The white microbeam was generated with a fine conical capillary with a 20 {mu}m output diameter. The samples were supported on a XYZ table. An optical microscope with motorized zoom was used for sample positioning and choice the area to be scanned. Automatic two-dimensional scans were programmed and performed with steps of 30 {mu}m in each direction (x, y) on the selected area. The fluorescence signals were recorded using a Si(Li) detector, positioned at 90 degrees with respect to the incident beam, with a collection time of 10 s per point. The elemental maps obtained from each sample were overlap to observe correlation between trace elements. Qualitative results showed that the pairs of elements Ca-Zn and Fe-Cu could to be correlated in malignant breast tissues. Quantitative results, achieved by Spearman correlation tests, indicate that there is a spatial correlation between these pairs of elements (p < 0.001) suggesting the importance of these elements in metabolic processes associated with the development of the tumor.

Piacenti da Silva, Marina; Silva, Deisy Mara da; Ribeiro-Silva, Alfredo; Poletti, Martin Eduardo [Departamento de Fisica, FFCLRP/USP, Av. dos Bandeirantes n. 3900, 14040-901 Ribeirao Preto - SP (Brazil); Departamento de Patologia, HCFM/USP, Av. dos Bandeirantes n. 3900, 14040-901 Ribeirao Preto - SP (Brazil); Departamento de Fisica, FFCLRP/USP, Av. dos Bandeirantes n. 3900, 14040-901 Ribeirao Preto - SP (Brazil)

2012-05-17T23:59:59.000Z

57

Distribution of trace elements in waters and sediments of the Seversky Donets  

E-Print Network [OSTI]

Distribution of trace elements in waters and sediments of the Seversky Donets transboundary sources in the transboundary watershed of the Seversky Donets River (Ukraine/Russia). Bed sediments, V) and Th were measured in stream water and sediments. The low levels and variability of Th

Paris-Sud XI, Université de

58

Elevated Trace Element Concentrations in Southern Toads, Bufo terrestris, Exposed to Coal Combustion Waste  

E-Print Network [OSTI]

, and behavioral abnormalities in amphibians to coal combustion wastes (coal ash). Few studies, however, have determined trace element concentrations in amphibians exposed to coal ash. In the current study we compare high levels of selenium and may be useful bioindicators in agricultural and coal ash-impacted habitats

Hopkins, William A.

59

Trace Elements in Tree Rings: Evidence of Recent and Historical Air Pollution  

E-Print Network [OSTI]

, or both. Tree rings have been used to construct records of climate (1), document heavy metal pollution (2Trace Elements in Tree Rings: Evidence of Recent and Historical Air Pollution C. F. Baes III and S and Historical Air Pollution Abstract. Annual growth rinks from short-leaf pine trees in the Great Smoky

Baes, Fred

60

Effect of Processing Mode on Trace Elements in Dewatered Sludge Products Brian K. Richards1  

E-Print Network [OSTI]

Effect of Processing Mode on Trace Elements in Dewatered Sludge Products Brian K. Richards1 *, John considering the land application of wastewater sludges. The effects of pelletization/drying, composting compared. A single day's production of dewatered anaerobically-digested sludge (Syracuse, NY) was used

Walter, M.Todd

Note: This page contains sample records for the topic "mercury trace elements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Extractable trace elements in the soil profile after years of biosolids application  

SciTech Connect (OSTI)

The US Environmental Protection Agency (USEPA) and some state agencies regulate trace element additions to soil from land application of biosolids. The authors generally consider trace elements added in biosolids (sewage sludge) to accumulate in the soil surface without significant transport below the plow layer. They used 11 yr of field-study information from biosolids addition to dryland hard red winter wheat (Triticum aestivum L. Vona or TAM107) to determine the distribution of NH{sub 4}HCO{sub 3} diethylenetriaminepentaacetic acid (AB-DTPA)-extractable Cd, Cr, Cu, Mo, Ni, Pb, and Zn in 0 to 20 (plow layer), 20 to 60, 60 to 100, and 100 to 150 cm depth increments. This study is unique since it involves multiple biosolids application in a dryland summer fallow agroecosystem. The authors applied five or six applications of biosolids from the cities of Littleton and Englewood, CO, to Weld loam or Platner loam at four locations. This paper focuses on the 0 (control), the 56 or 67 kg of N ha{sup {minus}1} fertilizer rates, and the 6.7 and 26.8 dry Mg of biosolids ha{sup {minus}1} rates that they added every crop year. The authors observed significant (P < 0.10) accumulations of the trace elements in the plow layer of the biosolids-amended soils. Only Zn showed consistent increases in extractable levels below the plow layer at all four sites. The biosolids Zn concentration was larger than any other trace element resulting in larger loading of this element.

Barbarick, K.A.; Ippolito, J.A.; Westfall, D.G. [Colorado State Univ., Fort Collins, CO (United States). Dept. of Soil and Crop Sciences

1998-07-01T23:59:59.000Z

62

A Critical Review on the Heterogeneous Catalytic Oxidation of Elemental Mercury in Flue Gases  

E-Print Network [OSTI]

of novel and highly efficient Hg0 oxidation catalysts. 1. INTRODUCTION Mercury is a leading concern among. Exposure to high levels of mercury has been associated with serious neurological and developmental effects to tremors, inability to walk, convulsions, and death.1,2 Coal-fired utility boilers, which release more than

Guo, John Zhanhu

63

Trace Element Analysis At Long Valley Caldera Area (Klusman & Landress,  

Open Energy Info (EERE)

Klusman & Landress, Klusman & Landress, 1979) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Trace Element Analysis At Long Valley Caldera Area (Klusman & Landress, 1979) Exploration Activity Details Location Long Valley Caldera Area Exploration Technique Trace Element Analysis Activity Date Usefulness useful DOE-funding Unknown Notes This study involved the field collection and laboratory analysis of Al-horizon soil samples in the vicinity of a known geothermal source at Long Valley, California. The samples were analyzed for several constituents known to have influence on Hg retention by soils, including pH, hydrous Fe and Mn, and organic carbon, as well as Hg. The data compiled for these secondary parameters and the field-determined parameters of geology, soil

64

Investigation on thermal and trace element characteristics during co-combustion biomass with coal gangue  

Science Journals Connector (OSTI)

Abstract The thermochemical behaviors during co-combustion of coal gangue (CG), soybean stalk (SS), sawdust (SD) and their blends prepared at different ratios have been determined via thermogravimetric analysis. The simulate experiments in a fixed bed reactor were performed to investigate the partition behaviors of trace elements during co-combustion. The combustion profiles of biomass was more complicated than that of coal gangue. Ignition property and thermal reactivity of coal gangue could be enhanced by the addition of biomass. No interactions were observed between coal gangue and biomass during co-combustion. The volatilization ratios of trace elements decrease with the increasing proportions of biomass in the blends during co-combustion. Based on the results of heating value, activation energy, base/acid ratio and gaseous pollutant emissions, the blending ratio of 2030% biomass content is regarded as optimum composition for blending and could be applied directly at current combustion application with few modifications.

Chuncai Zhou; Guijian Liu; Ting Fang; Paul Kwan Sing Lam

2015-01-01T23:59:59.000Z

65

Stein's method, heat kernel, and traces of powers of elements of compact Lie groups  

E-Print Network [OSTI]

Combining Stein's method with heat kernel techniques, we show that the trace of the jth power of an element of U(n,C), USp(n,C) or SO(n,R) has a normal limit with error term of order j/n. In contrast to previous works, here j may be growing with n. The technique should prove useful in the study of the value distribution of approximate eigenfunctions of Laplacians.

Jason Fulman

2010-05-07T23:59:59.000Z

66

Determination of organic inorganic associations of trace elements in New Albany shale kerogen  

SciTech Connect (OSTI)

The inorganic and organic trace element associations in the kerogen isolated from the New Albany shale were studied by analysis of kerogen fractions and a mineral residue obtained using density separations. Elemental mass balance data from these fractions indicate a predominantly inorganic association with pyrite and marcasite for several elements (As, Co, Ga, Mn, Ni, Sb and Se). The degree of inorganic association of these elements was determined by treatment of the mineral residue ({approximately}85% FeS{sub 2}) with dilute HNO{sub 3} to remove pyrite and marcasite. The association of several other elements in minerals which are insoluble in dilute HNO{sub 3} (rutile, zircon, etc.) were also determined. The results of these studies indicate an essentially total organic association for V and approximately 95% organic association for Ni in New Albany kerogen. The determination of organically combined elements is very difficult for those elements which are predominantly concentrated in the mineral fraction. Correction methods based on low temperature ashing, chemical removal of pyrite, and physical methods of separation are compared.

Mercer, G.E.; Filby, R.H. (Washington State Univ., Pullman (USA))

1989-03-01T23:59:59.000Z

67

Minor and Trace Element Determination of Food Spices and Pulses of Different Origins by NAA and PAA  

Science Journals Connector (OSTI)

INAA, RNAA and IPAA were employed to determine upto 26 trace elements in 32 spices of 18 species and 16 pulses of 8 species originating from different localities. The results are compared with each other and t...

Y. Miyamoto; A. Kajikawa; J. H. Zaidi

2000-03-01T23:59:59.000Z

68

Trace element mobility during sub-seafloor alteration of basaltic glass from Ocean Drilling Program site 953 (off Gran Canaria)  

Science Journals Connector (OSTI)

Trace element concentrations of altered basaltic glass shards (layer silicates) and zeolites in volcaniclastic sediments drilled in the volcanic apron northeast of Gran Canaria during Ocean Drilling Program (ODP)...

A. Utzmann; T. Hansteen; H.-U. Schmincke

2002-08-01T23:59:59.000Z

69

Application of synchrotron radiation to x-ray fluorescence analysis of trace elements  

SciTech Connect (OSTI)

The development of synchrotron radiation x-ray sources has provided the means to greatly extend the capabilities of x-ray fluorescence analysis for determinations of trace element concentrations. A brief description of synchrotron radiation properties provides a background for a discussion of the improved detection limits compared to existing x-ray fluorescence techniques. Calculated detection limits for x-ray microprobes with micrometer spatial resolutions are described and compared with experimental results beginning to appear from a number of laboratories. The current activities and future plans for a dedicated x-ray microprobe beam line at the National Synchrotron Light Source (NSLS) of Brookhaven National Laboratory are presented.

Gordon, B.M.; Jones, K.W.; Hanson, A.L.

1986-08-01T23:59:59.000Z

70

Heterogeneous distribution of trace elements and fluorine in phosphogypsum by-product  

Science Journals Connector (OSTI)

Phosphogypsum (PG), a by-product from phosphate fertilizer production, is composed mainly of gypsum (CaSO42H2O) but also contains minor quantities of trace elements (TE), rare earth elements (REE) and F. Some elements may be elevated in quantities to be of environmental concern. This study determined the distribution of TE, REE and F among three size fractions (53 ?m) in \\{PGs\\} derived from three different phosphate rock sources. Fine fraction PG (<20 ?m) composed of <10% of total PG mass but was highly enriched in TE, REE and F compared to unfractionated PG. For PG derived from Idaho rock, Se in the fine fraction was enriched 830 times over soil and 415 times over shale while Cd was enriched in the fine fraction 70-fold over shale and soil. Fluorine was elevated 37 times in the fine fraction compared to shale. The same trends were observed for PG derived from Togo and Florida rocks. Elevated elemental concentrations in fine particles and particle sorting during PG deposition may contribute to chemical heterogeneity of PG repositories, and make elements more susceptible to mobilization processes, such as leaching and erosion. Removal of fines will improve the utilization of PG in other industries, such as for use as an amendment to agricultural soils.

J.M. Arocena; P.M. Rutherford; M.J. Dudas

1995-01-01T23:59:59.000Z

71

Trace element geochemical zoning in the Roosevelt Hot Springs thermal area, Utah  

SciTech Connect (OSTI)

Chemical interaction of thermal brines with reservoir rock in the Roosevelt Hot Springs thermal area has resulted in the development of distinctive trace element signatures. Geochemical analysis of soil samples, shallow temperature-gradient drill hole cuttings and deep drill hole cuttings provides a three-dimensional perspective of trace element distributions within the system. Distributions of As, Hg and Li provide the clearest expression of hydrothermal activity. Comparison of these distributions suggests that Li, followed by As and Hg, are progressively deposited by outward flowing, cooling, thermal fluids. Hg, in contrast to As and Li, is distributed only within the outer portions of the thermal system where temperatures are less than about 225/sup 0/C. Heating experiments indicate that extensive Hg remobilization in Roosevelt samples occurs at temperatures as low as 200/sup 0/ to 250/sup 0/C. This suggests that the distribution of Hg largely reflects the present system thermal configuration and that this distribution may be a useful soild geothermometer.

Christensen, O.D.; Moore, J.N.; Capuano, R.M.

1980-09-01T23:59:59.000Z

72

The distribution of ten trace elements and minerals in three lignite seams from the Mae Moh Mine, Thailand  

SciTech Connect (OSTI)

Understanding the association of major, minor and trace elements in lignites and their accompanying strata is important from a number of perspectives which include: potential health problems from environmental pollutants, rehabilitation after mining, combustion for power etc. The material which follows represents some preliminary observations on the mineralogy and distribution of 10 trace elements in lignites and accompanying sediments from the Mae Moh mine, Thailand. Samples collected from freshly exposed mine faces were air dried and analyzed for moisture and ash. Trace element concentrations were determined on {open_quotes}whole{close_quotes} coals and sediments by NAA and XRF. All chemical analyses are expressed as a fraction of the total dry sediment. Mineralogy of both LTA and sediments was determined by XRD. The chemistry and morphology of individual particles were examined by the Electron microprobe. The analyses are used to make some conclusions about the spatial occurrence of these elements within the seam and their partitioning between organic and inorganic phases.

Hart, B.; Powell, M.P.; Fyfe, W.S. [Univ. of Ontario (Canada)

1994-12-31T23:59:59.000Z

73

Permitted Mercury Storage Facility Notifications | Department...  

Broader source: Energy.gov (indexed) [DOE]

Services Waste Management Waste Disposition Long-Term Management and Storage of Elemental Mercury is in the Planning Stages Permitted Mercury Storage Facility...

74

Emission factors for particles, elemental carbon, and trace gases from the Kuwait oil fires  

SciTech Connect (OSTI)

Emission factors are presented for particles, elemental carbon (i.e., soot), total organic carbon in particles and vapor, and for various trace gases from the 1991 Kuwait oil fires. Particle emissions accounted for {approximately} 2% of the fuel burned. In general, soot emission factors were substantially lower than those used in recent {open_quotes}nuclear winter{close_quotes} calculations. Differences in the emissions and appearances of some of the individual fires are discussed. Carbon budget data for the composite plumes from the Kuwait fires are summarized; most of the burned carbon in the plumes was in the form of CO{sub 2}. Fluxes are presented for several combustion products. 26 refs., 1 fig., 5 tabs.

Laursen, K.K.; Ferek, R.J.; Hobbs, P.V. [Univ. of Washington, Seattle, WA (United States); Rasmussen, R.A. [Oregon Graduate Institute of Science and Technology, Beaverton, OR (United States)

1992-09-20T23:59:59.000Z

75

Environmental impact assessment of radionuclides and trace elements at the Kurday U mining site, Kazakhstan  

Science Journals Connector (OSTI)

The Kurday uranium mining site in Kazakhstan operated from 1954 to 1965 as part of the USSR nuclear weapon programme. To assess the environmental impact of radionuclides and trace elements associated with the Kurday mining site, field expeditions were performed in 2006. In addition to in situ gamma and 220Rn dose rate measurements, sampling included at site fractionation of water as well as sampling of water, fish, sediment, soils and vegetation. The concentrations of U and associated trace metals were enriched in the Pit Lake and in the artesian water (U exceeding the WHO guideline value for drinking water), and decreased downstream from the mining area. Uranium, As, Mo and Ni were predominantly present as mobile low molecular mass species in waters, while a significant proportion of Cr, Mn and Fe were associated with colloids and particles. Due to oxidation of divalent iron in the artesian ground water upon contact with air, Fe served as scavenger for other elements, and peak concentrations of U-, Ra-isotopes, As and Mn were seen. Most radionuclides and trace elements were contained in minerals in soils and sediments, and good correlations were obtained between U and As, Cd, Mo and 226Ra. Based on sequential extractions, a significant fraction of U, Pb and Cd could be considered mobile. Radioactive particles carrying significant amount of trace metals may represent a hazard during strong wind events. The transfer of radionuclides and metals from soils or sediments to water was in general low. The Kd levels varied with the element in question, ranging from 0.5 to 3נ102L/kg d.w. for 238U being relatively mobile, 103 for 226Ra, As, Cd, Ni, to 104L/kg d.w. for Cu, Cr and Pb being rather inert The transfer of radionuclides and metals from soils to vegetation (TF) was low, while higher if the transfer to vegetation, especially underwater mosses, occurred via water (e.g., BCF 37L/kg w.w. for 238U and 3נ103L/kg w.w. for 226Ra). The transfer of Cd, Pb and As from water to fish liver (BCF) was rather high, showing \\{BCFs\\} in the range of 102103L/kg w.w., and may, if eaten, represent a health risk. Furthermore, the high Hg level in fish filet reaching 0.3mg/kg w.w. muscle and the tendency of biomagnification call for dietary restrictions. Total gamma and Rn dose rate to man amounted to about 6mSv/y, while the highest calculated dose rate for non-human species based on the ERICA Assessment Tool were obtained in aquatic plants, with calculated mean doses of 700 ?Gy/hr, mostly due to the U exposure. Overall, it is concluded that measures such as restricted access to the Pit Lake as well as dietary restrictions with respect to drinking water and intake of fish should be taken to reduce the environmental risk to man and biota.

B. Salbu; M. Burkitbaev; G. Strmman; I. Shishkov; P. Kayukov; B. Uralbekov; B.O. Rosseland

2013-01-01T23:59:59.000Z

76

Mercury Calibration System  

SciTech Connect (OSTI)

U.S. Environmental Protection Agency (EPA) Performance Specification 12 in the Clean Air Mercury Rule (CAMR) states that a mercury CEM must be calibrated with National Institute for Standards and Technology (NIST)-traceable standards. In early 2009, a NIST traceable standard for elemental mercury CEM calibration still does not exist. Despite the vacature of CAMR by a Federal appeals court in early 2008, a NIST traceable standard is still needed for whatever regulation is implemented in the future. Thermo Fisher is a major vendor providing complete integrated mercury continuous emissions monitoring (CEM) systems to the industry. WRI is participating with EPA, EPRI, NIST, and Thermo Fisher towards the development of the criteria that will be used in the traceability protocols to be issued by EPA. An initial draft of an elemental mercury calibration traceability protocol was distributed for comment to the participating research groups and vendors on a limited basis in early May 2007. In August 2007, EPA issued an interim traceability protocol for elemental mercury calibrators. Various working drafts of the new interim traceability protocols were distributed in late 2008 and early 2009 to participants in the Mercury Standards Working Committee project. The protocols include sections on qualification and certification. The qualification section describes in general terms tests that must be conducted by the calibrator vendors to demonstrate that their calibration equipment meets the minimum requirements to be established by EPA for use in CAMR monitoring. Variables to be examined include linearity, ambient temperature, back pressure, ambient pressure, line voltage, and effects of shipping. None of the procedures were described in detail in the draft interim documents; however they describe what EPA would like to eventually develop. WRI is providing the data and results to EPA for use in developing revised experimental procedures and realistic acceptance criteria based on actual capabilities of the current calibration technology. As part of the current effort, WRI worked with Thermo Fisher elemental mercury calibrator units to conduct qualification experiments to demonstrate their performance characteristics under a variety of conditions and to demonstrate that they qualify for use in the CEM calibration program. Monitoring of speciated mercury is another concern of this research. The mercury emissions from coal-fired power plants are comprised of both elemental and oxidized mercury. Current CEM analyzers are designed to measure elemental mercury only. Oxidized mercury must first be converted to elemental mercury prior to entering the analyzer inlet in order to be measured. CEM systems must demonstrate the ability to measure both elemental and oxidized mercury. This requires the use of oxidized mercury generators with an efficient conversion of the oxidized mercury to elemental mercury. There are currently two basic types of mercuric chloride (HgCl{sub 2}) generators used for this purpose. One is an evaporative HgCl{sub 2} generator, which produces gas standards of known concentration by vaporization of aqueous HgCl{sub 2} solutions and quantitative mixing with a diluent carrier gas. The other is a device that converts the output from an elemental Hg generator to HgCl{sub 2} by means of a chemical reaction with chlorine gas. The Thermo Fisher oxidizer system involves reaction of elemental mercury vapor with chlorine gas at an elevated temperature. The draft interim protocol for oxidized mercury units involving reaction with chlorine gas requires the vendors to demonstrate high efficiency of oxidation of an elemental mercury stream from an elemental mercury vapor generator. The Thermo Fisher oxidizer unit is designed to operate at the power plant stack at the probe outlet. Following oxidation of elemental mercury from reaction with chlorine gas, a high temperature module reduces the mercuric chloride back to elemental mercury. WRI conducted work with a custom laboratory configured stand-alone oxidized mercury generator unit prov

John Schabron; Eric Kalberer; Joseph Rovani; Mark Sanderson; Ryan Boysen; William Schuster

2009-03-11T23:59:59.000Z

77

Turtle With Mad Input (trace Unlimited Rays Through Lumped Elements) -- A Computer Program For Simulating Charged Particle Beam Transport Systems And Decay Turtle Including Decay Calculations  

E-Print Network [OSTI]

Turtle With Mad Input (trace Unlimited Rays Through Lumped Elements) -- A Computer Program For Simulating Charged Particle Beam Transport Systems And Decay Turtle Including Decay Calculations

Carey, D C

1999-01-01T23:59:59.000Z

78

POSTER INSTRUCTIONS International Symposium on Trace Elements in Man & Animals (TEMA 15) June 22-26, 2014  

E-Print Network [OSTI]

POSTER INSTRUCTIONS 15th International Symposium on Trace Elements in Man & Animals (TEMA 15) June 22-26, 2014 Orlando, Florida The B Resort in Walt Disney Poster Specifications Posters as during lunches on Monday and Tuesday. Posters will be limited to 4 feet high x 3 feet wide (1.22M high x

Jawitz, James W.

79

Correlation of mineralogy and trace element leaching behavior in modified in situ spent shales from Logan Wash, Colorado  

SciTech Connect (OSTI)

Oil shale retorting induces mineral and chemical reactions to occur on the macroscopic and microscopic levels in the kerogen-bearing marlstone. The nature and extent of the reactions is dependent upon process variables such as maximum temperature, time at temperature, atmosphere, and raw shale composition. This report describes the investigation of the mineral, chemical, and trace element release properties of spent shales retrieved from an experimental in situ retort at Occidental Oil Shale, Inc.'s Logan Wash site in Garfield County, Colorado. Correlation between mineralogy of the spent materials and the mobility of major, minor, and trace elements are indicated, and relationships with important process parameters are discussed. The progress of carbonate decomposition reactions and silication reactions is indicative of the processing conditions experienced by the shale materials and influences the mobility of major, minor, and trace elements when the solids are contacted by water. Shale minerals that are exposed to the extreme conditions reached in underground retorting form high temperature product phases including akermanite-gehlenite and diopside-augite solid solutions, kalsilite, monticellite, and forsterie. The persistence of relatively thermally stable phases, such as quartz, orthoclase, and albite provide insight into the extremes of processing conditions experienced by the spent shales. Leachate compositions suggest that several trace elements, including vanadium, boron, fluoride, and arsenic are not rendered immobile by the formation of the high-temperature silicate product phase akermanite-gehlenite.

Peterson, E.J.; O'Rourke, J.A.; Wagner, P.

1981-01-01T23:59:59.000Z

80

Trace element and isotope geochemistry of geothermal fluids, East Rift Zone, Kilauea, Hawaii  

SciTech Connect (OSTI)

A research program has been undertaken in an effort to better characterize the composition and the precipitation characteristic of the geothermal fluids produced by the HGP-A geothermal well located on the Kilauea East Rift Zone on the Island of Hawaii. The results of these studies have shown that the chemical composition of the fluids changed over the production life of the well and that the fluids produced were the result of mixing of at least two, and possibly three, source fluids. These source fluids were recognized as: a sea water composition modified by high temperature water-rock reactions; meteoric recharge; and a hydrothermal fluid that had been equilibrated with high temperature reservoir rocks and magmatic volatiles. Although the major alkali and halide elements show clearly increasing trends with time, only a few of the trace transition metals show a similar trend. The rare earth elements, were typically found at low concentrations and appeared to be highly variable with time. Studies of the precipitation characteristics of silica showed that amorphous silica deposition rates were highly sensitive to fluid pH and that increases in fluid pH above about 8.5 could flocculate more than 80% of the suspended colloidal silica in excess of its solubility. Addition of transition metal salts were also found to enhance the recovery fractions of silica from solution. The amorphous silica precipitate was also found to strongly scavenge the alkaline earth and transition metal ions naturally present in the brines; mild acid treatments were shown to be capable of removing substantial fractions of the scavenged metals from the silica flocs yielding a moderately pure gelatinous by-product. Further work on the silica precipitation process is recommended to improve our ability to control silica scaling from high temperature geothermal fluids or to recover a marketable silica by-product from these fluids prior to reinjection.

West, H.B.; Delanoy, G.A.; Thomas, D.M. (Hawaii Univ., Honolulu, HI (United States). Hawaii Inst. of Geophysics); Gerlach, D.C. (Lawrence Livermore National Lab., CA (United States)); Chen, B.; Takahashi, P.; Thomas, D.M. (Hawaii Univ., Honolulu, HI (United States) Evans (Charles) and Associates, Redwood City, CA (United States))

1992-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mercury trace elements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Distribution of arsenic, selenium, and other trace elements in high pyrite Appalachian coals: Evidence for multiple episodes of pyrite formation  

Science Journals Connector (OSTI)

Pennsylvanian coals in the Appalachian Basin host pyrite that is locally enriched in potentially toxic trace elements such as As, Se, Hg, Pb, and Ni. A comparison of pyrite-rich coals from northwestern Alabama, eastern Kentucky, and West Virginia reveals differences in concentrations and mode of occurrence of trace elements in pyrite. Pyrite occurs as framboids, dendrites, or in massive crystalline form in cell lumens or crosscutting veins. Metal concentrations in pyrite vary over all scales, from microscopic to mine to regional, because trace elements are inhomogeneously distributed in the different morphological forms of pyrite, and in the multiple generations of sulfide mineral precipitates. Early diagenetic framboidal pyrite is usually depleted in As, Se, and Hg, and enriched in Pb and Ni, compared to other pyrite forms. In dendritic pyrite, maps of As distribution show a chemical gradient from As-rich centers to As-poor distal branches, whereas Se concentrations are highest at the distal edges of the branches. Massive crystalline pyrite that fills veins is composed of several generations of sulfide minerals. Pyrite in late-stage veins commonly exhibits As-rich growth zones, indicating a probable epigenetic hydrothermal origin. Selenium is concentrated at the distal edges of veins. A positive correlation of As and Se in pyrite veins from Kentucky coals, and of As and Hg in pyrite-filled veins from Alabama coals, suggests coprecipitation of these elements from the same fluid. In the Kentucky coal samples (n=18), As and Se contents in pyrite-filled veins average 4200ppm and 200ppm, respectively. In Alabama coal samples, As in pyrite-filled veins averages 2700ppm (n=34), whereas As in pyrite-filled cellular structures averages 6470ppm (n=35). In these same Alabama samples, Se averages 80ppm in pyrite-filled veins, but was below the detection limit in cell structures. In samples of West Virginia massive pyrite, As averages 1700ppm, and Se averages 270ppm (n=24). The highest concentration of Hg (?102ppm) is in Alabama pyrite veins. Improved detailed descriptions of sulfide morphology, sulfide mineral paragenesis, and trace-element concentration and distribution allow more informed predictions of: (1) the relative rate of release of trace elements during weathering of pyrite in coals, and (2) the relative effectiveness of various coal-cleaning procedures of removing pyrite. For example, trace element-rich pyrite has been shown to be more soluble than stoichiometric pyrite, and fragile fine-grained pyrite forms such as dendrites and framboids are more susceptible to dissolution and disaggregation but less amenable to removal during coal cleaning.

S.F. Diehl; M.B. Goldhaber; A.E. Koenig; H.A. Lowers; L.F. Ruppert

2012-01-01T23:59:59.000Z

82

doi:10.1016/j.gca.2004.06.037 Effect of melt composition on the partitioning of trace elements  

E-Print Network [OSTI]

coefficients for the rare earth elements and for Th, Nb, and Ta reveal a strong influence of melt composition amounts of rare earth elements (REE) and high field strength elements (HFSE), it may significantly affectdoi:10.1016/j.gca.2004.06.037 Effect of melt composition on the partitioning of trace elements

83

Chemical composition and some trace element contents in coals and coal ash from Tamnava-Zapadno Polje Coal Field, Serbia  

SciTech Connect (OSTI)

The chemical compositions and trace element contents (Zn, Cu, Co, Cr, Ni, Pb, Cd, As, B, Hg, Sr, Se, Be, Ba, Mn, Th, V, U) in coal and coal ash samples from Tamnava-Zapadno Polje coal field in Serbia were studied. The coal from this field belongs to lignite. This high volatility coal has high moisture and low S contents, moderate ash yield, and high calorific value. The coal ash is abundant in alumosilicates. Many trace elements such as Ni > Cd > Cr > B > As > Cu > Co > Pb > V > Zn > Mn in the coal and Ni > Cr > As > B > Cu > Co = Pb > V > Zn > Mn in the coal ash are enriched in comparison with Clarke concentrations.

Vukasinovic-Pesic, V.; Rajakovic, L.J. [University of Montenegro, Podgorica (Montenegro)

2009-07-01T23:59:59.000Z

84

Recovery of mercury from mercury compounds via electrolytic methods  

DOE Patents [OSTI]

A process for electrolytically recovering mercury from mercury compounds is provided. In one embodiment, Hg is recovered from Hg.sub.2 Cl.sub.2 employing as the electrolyte solution a mixture of HCl and H.sub.2 O. In another embodiment, Hg is electrolytically recovered from HgO wherein the electrolyte solution is comprised of glacial acetic acid and H.sub.2 O. Also provided is an apparatus for producing isotopically enriched mercury compounds in a reactor and then transporting the dissolved compounds into an electrolytic cell where mercury ions are electrolytically reduced and elemental mercury recovered from the mercury compounds.

Grossman, Mark W. (Belmont, MA); George, William A. (Rockport, MA)

1989-01-01T23:59:59.000Z

85

Recovery of mercury from mercury compounds via electrolytic methods  

DOE Patents [OSTI]

A process for electrolytically recovering mercury from mercury compounds is provided. In one embodiment, Hg is recovered from Hg[sub 2]Cl[sub 2] employing as the electrolyte solution a mixture of HCl and H[sub 2]O. In another embodiment, Hg is electrolytically recovered from HgO wherein the electrolyte solution is comprised of glacial acetic acid and H[sub 2]O. Also provided is an apparatus for producing isotopically enriched mercury compounds in a reactor and then transporting the dissolved compounds into an electrolytic cell where mercury ions are electrolytically reduced and elemental mercury recovered from the mercury compounds. 3 figures.

Grossman, M.W.; George, W.A.

1991-06-18T23:59:59.000Z

86

Recovery of mercury from mercury compounds via electrolytic methods  

DOE Patents [OSTI]

A process for electrolytically recovering mercury from mercury compounds is provided. In one embodiment, Hg is recovered from Hg.sub.2 Cl.sub.2 employing as the electrolyte solution a mixture of HCl and H.sub.2 O. In another embodiment, Hg is electrolytically recovered from HgO wherein the electrolyte solution is comprised of glacial acetic acid and H.sub.2 O. Also provided is an apparatus for producing isotopically enriched mercury compounds in a reactor and then transporting the dissolved compounds into an electrolytic cell where mercury ions are electrolytically reduced and elemental mercury recovered from the mercury compounds.

Grossman, Mark W. (Belmont, MA); George, William A. (Rockport, MA)

1988-01-01T23:59:59.000Z

87

Recovery of mercury from mercury compounds via electrolytic methods  

DOE Patents [OSTI]

A process for electrolytically recovering mercury from mercury compounds is provided. In one embodiment, Hg is recovered from Hg.sub.2 Cl.sub.2 employing as the electrolyte solution a mixture of HCl and H.sub.2 O. In another embodiment, Hg is electrolytically recovered from HgO wherein the electrolyte solution is comprised of glacial acetic acid and H.sub.2 O. Also provided is an apparatus for producing isotopically enriched mercury compounds in a reactor and then transporting the dissolved compounds into an electrolytic cell where mercury ions are electrolytically reduced and elemental mercury recovered from the mercury compounds.

Grossman, Mark W. (Belmont, MA); George, William A. (Rockport, MA)

1991-01-01T23:59:59.000Z

88

Recovery of mercury from mercury compounds via electrolytic methods  

DOE Patents [OSTI]

A process for electrolytically recovering mercury from mercury compounds is provided. In one embodiment, Hg is recovered from Hg[sub 2]Cl[sub 2] employing as the electrolyte solution a mixture of HCl and H[sub 2]O. In another embodiment, Hg is electrolytically recovered from HgO wherein the electrolyte solution is comprised of glacial acetic acid and H[sub 2]O. Also provided is an apparatus for producing isotopically enriched mercury compounds in a reactor and then transporting the dissolved compounds into an electrolytic cell where mercury ions are electrolytically reduced and elemental mercury recovered from the mercury compounds. 3 figs.

Grossman, M.W.; George, W.A.

1989-11-07T23:59:59.000Z

89

Observations on the incorporation of trace elements in halite of Oligocene salt beds, Bourg-en-Bresse Basin, France  

SciTech Connect (OSTI)

It is common practice to employ trace elements found in chloride salts as indicators of the conditions of deposition. Because some halite contains abundant fluid inclusions, it is necessary to separate the salt from the inclusions before analysis. This study presents the data derived from the use of a simple preparative technique which permits analysis of the trace elements in solid halite, and provides a guide to test the success in elimination of the contaminants contained in the fluid inclusions. The differentiation is accomplished simply by crushing the salt in alcohol followed by separate analysis of the fluid and solid components, thus yielding accurate trace element concentrations in the solids (crystal lattice, dislocations, and grain boundaries) and the fluids. Br and K are present both in the solid and liquid phases of the halite, but Mg is exclusively in the fluid inclusions. The elimination of the Mg from the analysis of the solid phase may thus be employed as a monitor to indicate the degree of purification of the samples being analyzed.

Moretto, R. (Universite de Nancy I, Vandoeuvre-les-Nancy (France))

1988-12-01T23:59:59.000Z

90

Washability of trace elements in product coals from Illinois mines. Technical report, September 1--November 30, 1993  

SciTech Connect (OSTI)

The existing trace element washability data on Illinois coals are based on float-sink methods, and these data are not applicable to modern froth flotation or column flotation processes. Particularly, there is a lack of washability data on samples from modern preparation plants, as well as other product (as-shipped) coals. The goal of this project is to provide the needed trace element washability data on as-shipped coals that were collected during 1992--1993 from Illinois mines. The results generated by this project will promote Illinois coals for such prospective new markets as feed materials for advanced gasification processes, for synthetic organic chemicals, and to meet new environmental requirements for their use in utility steam generation. During the first quarter, each of 34 project samples were ground to about {approximately}100 mesh size and cleaned by use of a special froth flotation technique (release analysis). The flotation products were analyzed for ash, moisture, and heating value (BTU). The data were then used to construct a series of different-washability curves. For example, these curves can show variation in BTU or combustible recovery as a function of the amount of ash or S rejected, or as a function of the weight of the flotation products. From the relationship between %cumulative BTU and %cumulative weight, nine composite samples each having 80% of the total BTU were prepared from the individual flotation products and submitted for trace element analysis.

Demir, I.; Ruch, R.R.; Harvey, R.D.; Steele, J.D. [Illinois Dept. of Energy and Natural Resources, Springfield, IL (United States). Geological Survey

1993-12-31T23:59:59.000Z

91

DOE Interim Guidance on Mercury Management Procedures and Standards...  

Broader source: Energy.gov (indexed) [DOE]

Services Waste Management Waste Disposition Long-Term Management and Storage of Elemental Mercury is in the Planning Stages DOE Interim Guidance on Mercury Management...

92

MERCURY OXIDIZATION IN NON-THERMAL PLASMA BARRIER DISCHARGE SYSTEM  

SciTech Connect (OSTI)

In the past decade, the emission of toxic elements from human activities has become a matter of great public concern. Hg, As, Se and Cd typically volatilize during a combustion process and are not easily caught with conventional air pollution control techniques. In addition, there is no pollution prevention technique available now or likely be available in the foreseeable future that can prevent the emission of these trace elements. These trace elements pose additional scientific challenge as they are present at only ppb levels in large gas streams. Mercury, in particular, has attracted significant attention due to its high volatility, toxicity and potential threat to human health. In the present research work, a non-thermal plasma dielectric barrier discharge technique has been used to oxidize Hg{sup 0}(g) to HgO. The basic premise of this approach is that Hg{sup 0} in vapor form cannot be easily removed in an absorption tower whereas HgO as a particulate is amiable to water scrubbing. The work presented in this report consists of three steps: (1) setting-up of an experimental apparatus to generate mercury vapors at a constant rate and modifying the existing non-thermal plasma reactor system, (2) solving the analytical challenge for measuring mercury vapor concentration at ppb level, and (3) conducting experiments on mercury oxidation under plasma conditions to establish proof of concept.

V.K. Mathur

2003-02-01T23:59:59.000Z

93

Method for quantitative determination and separation of trace amounts of chemical elements in the presence of large quantities of other elements having the same atomic mass  

DOE Patents [OSTI]

Photoionization via autoionizing atomic levels combined with conventional mass spectroscopy provides a technique for quantitative analysis of trace quantities of chemical elements in the presence of much larger amounts of other elements with substantially the same atomic mass. Ytterbium samples smaller than 10 ng have been detected using an ArF* excimer laser which provides the atomic ions for a time-of-flight mass spectrometer. Elemental selectivity of greater than 5:1 with respect to lutetium impurity has been obtained. Autoionization via a single photon process permits greater photon utilization efficiency because of its greater absorption cross section than bound-free transitions, while maintaining sufficient spectroscopic structure to allow significant photoionization selectivity between different atomic species. Separation of atomic species from others of substantially the same atomic mass is also described.

Miller, C.M.; Nogar, N.S.

1982-09-02T23:59:59.000Z

94

Comparative bioaccumulation of trace elements between Nautilus pompilius and N.1 macromphalus (Cephalopoda: Nautiloidea) from Vanuatu and New-Caledonia2  

E-Print Network [OSTI]

clearly highlighted that the digestive gland32 played a key role in the bioaccumulation and storage of Ag are exposed to trace elements that are present in their diet and dissolved in49 seawater. This double exposure bioavailability of53 the metal in diet and seawater (Rainbow and Wang, 2001). Comparative analysis of trace54

Paris-Sud XI, Université de

95

Trace element partitioning between apatite and silicate melts Stefan Prowatke a,1  

E-Print Network [OSTI]

). The experiments were conducted at pressures of 1.0 GPa and temperatures of 1250 °C. The rare earth elements (La polymerisation of the melt, apatite/melt partition coefficients for the rare earth elements increase for about occurring apatites contain large amounts of the rare earth elements and Sr, it has been well known

96

Precise lattice location of trace elements within minerals and at their surfaces with x?ray standing waves (abstract)  

Science Journals Connector (OSTI)

Using x?ray standing waves (XSW) generated by dynamical Bragg diffraction we have precisely measured lattice locations of trace elements within and at the surface of mineral single crystals. Natural calcite samples were cleaved along the (1014) plane to obtain pristine surfaces. After cleavage some samples were reacted with a dilute aqueous Pb solution to obtain Pb?sorbed surfaces. XSW measurements were then performed on both unreacted and reacted samples using the calcite (1014) Bragg reflection. Results of these XSW measurements show that the naturally occurring trace element M substitutes for C. On the Pb?reacted calcite sample Pb was located on the calcite (1014) lattice plane where C atoms also reside. Our measurements clearly demonstrate a new and powerful application of synchrotron radiation in earth and environmental sciences to provide element?specific atomic?scale structural information within and at the surface of minerals. The XSW measurements were made at the NSLS X15A and X25 beamlines.

Y. Qian

1996-01-01T23:59:59.000Z

97

Effect of agricultural use of phosphogypsum on trace elements in soils and vegetation  

Science Journals Connector (OSTI)

The problem of the disposal of phosphogypsum, one of the main industrial wastes of phosphorus fertilizer production, is reviewed, from the point of view of element pollution of phosphate raw materials, when it is introduced to soil. When phosphogypsum from different phosphorus producing plants in the USSR is used in agriculture, the main element-pollutants are fluorine, sulphur, strontium and rare earth elements. Their concentration in soils and vegetation exceeds Clark values by 20100 times. The necessity for complex biogeochemical investigations to identify the hazards from these chemical elements in the environment is discussed.

A.V. Gorbunov; M.V. Frontasyeva; S.F. Gundorina; T.L. Onischenko; B.B. Maksjuta; Chen Sen Pal

1992-01-01T23:59:59.000Z

98

NETL: IEP - Mercury Emissions Control: Emissions Characterization  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Control Control Emissions Characterization In anticipation of the 1990 CAAAs, specifically the draft Title III regarding the characterization of potential HAPs from electric steam generating units, DOE initiated a new Air Toxics Program in 1989. The DOE Mercury Measurement and Control Program evolved as a result of the findings from the comprehensive assessment of hazardous air pollutants studies conducted by DOE from 1990 through 1997. DOE, in collaboration with EPRI, performed stack tests at a number of coal-fired power plants (identified on map below) to accurately determine the emission rates of a series of potentially toxic chemicals. These tests had not been conducted previously because of their cost, about $1 million per test, so conventional wisdom on emissions was based on emission factors derived from analyses of coal. In general, actual emissions were found to be about one-tenth previous estimates, due to a high fraction of the pollutants being captured by existing particulate control systems. These data resulted in a decision by EPA that most of these pollutants were not a threat to the environment, and needed no further regulation at power plants. This shielded the coal-fired power industry from major (tens of millions) costs that would have resulted from further controlling these emissions. However, another finding of these studies was that mercury was not effectively controlled in coal-fired utility boiler systems. Moreover, EPA concluded that a plausible link exists between these emissions and adverse health effects. Ineffective control of mercury by existing control technologies resulted from a number of factors, including variation in coal composition and variability in the form of the mercury in flue gases. The volatility of mercury was the main contributor for less removal, as compared to the less volatile trace elements/metals which were being removed at efficiencies over 99% with the fly ash. In addition, it was determined that there was no reliable mercury speciation method to accurately distinguish between the elemental and oxidized forms of mercury in the flue gas. These two forms of mercury respond differently to removal techniques in existing air pollution control devices utilized by the coal-fired utility industry.

99

Trace Elemental Variation in Dosidicus Gigas Statoliths Using LA-ICP-MS  

E-Print Network [OSTI]

classified as distinct group for the first time using these methods. Elemental fingerprint signatures were found to be significantly different at multiple ontogenic growth regions of the statolith. Seattle and California paralarvae exhibited similar...

Arbuckle, Nancy 1980-

2012-08-24T23:59:59.000Z

100

The distribution and association of trace elements in the bitumen, kerogen and pyrolysates from New Albany oil shale  

SciTech Connect (OSTI)

The distribution and association of trace elements in bitumen, kerogen and pyrolysates from New Albany oil shale were investigated using instrumental neutron activation analysis (INAA), x-ray diffraction (XRD), electron microprobe x-ray fluorescence (EMP-XRF), liquid chromatography, ultra-violet spectroscopy and mass spectrometry. The kerogen was found to contain several HCl/HF resistant minerals (determined by XRD), including pyrite, marcasite, chalcopyrite, rutile, and anatase, and the neoformed mineral ralstonite. Kerogens (prepared at UNOCAL, CA) which were fractionated in an aqueous ZnBr[sub 2] solution were found to contain [approximately]20% less acid-resistant minerals than traditional' HCl/HF isolated kerogens and were contaminated with Zn and Br. Kerogens (prepared at the University of Munich) treated with SnCl[sub 2]/H[sub 3]PO[sub 4] at 150-270[degrees]C (Kiba) and/or SnCl[sub 2]/HCl at 110[degrees]C were found to contain <10% of their original pyrite/marcasite (FeS[sub 2]), but were contaminated with large amounts of Sn. The Kiba treatment also appeared to demetallate Ni(II) and VO(II) porphyrins. The inorganic and organic associations of trace elements in New Albany kerogen were studied by analysis of kerogen fractions and a mineral residue ([approximately]85% FeS[sub 2]) obtained through density separations. The degree of association of several elements (As, Co, Mn, Mo, Ni, Sb, and Se) with FeS[sub 2] was determined through the analysis of individual mineral grains by EMP-XRF and by analysis of the mineral residue treated with dilute HNO[sub 3] to remove FeS[sub 2]. These studies indicated that essentially all of the V and [approximately]95% of the Ni present in New Albany kerogen is organically associated. Methods which are designed to account for the inorganic associations of trace elements in kerogens, including methods based on physical methods of separation, chemical removal of FeS[sub 2], EMP-XRF and low temperature ashing, are compared.

Mercer, G.E.

1992-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mercury trace elements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Long-term leaching of trace elements in a heavily sludge-amended silty clay loam soil  

SciTech Connect (OSTI)

Analysis by ICP-MS of shallow groundwater collected at a field site in New York that had been heavily loaded with sewage sludge more than 15 years earlier revealed elevated concentrations of Cu, Zn, Sr, Rb, Mo, Cd, As, Cr, Ni, Sb, W, Ag, Hg, and Sn compared with a nearby control site. Enhanced leaching of some elements from this near-neutral, fine-textured (silty clay loam) soil could be explained by exchange of soil-bound elements by components of the added sludge. For most of the heavy metals, however, increased leaching was a response to the high metal loadings in the soil, probably facilitated by higher dissolved organic matter in the leachate. Laboratory-determined distribution coefficients, K{sub D}, for the metals in newly prepared sludge/soil mixtures were lower than K{sub D} values of the field-aged sludge-treated soil, suggesting that metal mobility may have been substantially higher shortly after sludge application than many years later. Cumulative losses of certain trace elements from the topsoil have been estimated relative to Cr, a comparatively immobile element. These suggest that relative long-term losses range from 20 to 80%, with the order being: Sr, Mo, Sb {gt} Ni, Cd, Cu {gt} Zn, Ag. Generally, those elements with the smallest K{sub D} values (most soluble) measured recently in the soil had the largest loss estimates. However, present leaching loss rates are too slow to explain the estimated relative losses of several of these elements from the topsoil over the 15 or more years since sludge application.

McBride, M.B.; Richards, B.K.; Steenhuis, T.; Spiers, G.

1999-09-01T23:59:59.000Z

102

Measurement of particulate matter and trace elements from a coal-fired power plant with electrostatic precipitators equipped the low temperature economizer  

Science Journals Connector (OSTI)

Abstract The particulate matter and trace elements from a 660MW coal-fired power plant boiler which equipped with a novel electrostatic precipitator were sampled and analyzed. To promote the thermal efficiency of power plants, a low temperature economizer was installed at the inlet of electrostatic precipitator to collect the heat generated from flue gas. The low temperature economizer can reduce flue gas temperature, and then affect the operation of electrostatic precipitator. Therefore, this experiment was carried out to investigate the collection characteristics of this novel electrostatic precipitator on particulate matter. In addition, the distribution of trace elements in solid combustion residues was also studied. The results indicate that the low temperature economizer can markedly decrease the amount of particulate matter at the outlet of electrostatic precipitator. The collection efficiency of electrostatic precipitator on particulate matter is significantly improved by the low temperature economizer, whereby the collection efficiencies of PM2.5 and PM1.0 can reach 99.7% and 99.2%, respectively. Most of the trace elements remain in the fly ash collected by the electrostatic precipitator, and less than 10% remain in the bottom ash, but very rare emit from the electrostatic precipitator. The low temperature economizer not only reduces the emission of particulate matter, but also diminishes the emissions of trace elements in flue gas. The enrichment characteristics of trace elements in submicron particles were also studied.

Chao Wang; Xiaowei Liu; Dong Li; Junping Si; Bo Zhao; Minghou Xu

2014-01-01T23:59:59.000Z

103

Trace element chemistry of Apollo 14 lunar soil from Fra Mauro  

Science Journals Connector (OSTI)

Analytical data are presented for Apollo 14 fines ( Mauro Formation, possessed high concentrations (100200 chondrites) for many elements, prior to the excavation of the mare basins. A correlation may exist between Gd/Eu and Zr/Hf ratios in lunar materials.

S.R. Taylor; Patricia Muir; Maureen Kaye

1971-01-01T23:59:59.000Z

104

Association of trace elements with mineral species in the New Albany oil shale  

SciTech Connect (OSTI)

X-Ray diffraction (XRD), electron microprobe (EMP), scanning electron microscopy (SEM) and neutron activation analysis (NAA) were used to identify mineral species in the New Albany shale and kerogen isolates. Elemental abundances were determined by NAA and distributions of Ni, V, As, and other elements with-in mineral grains were determined by EMP-XRF. Vanadium in the New Albany shale was found to be associated primarily with clay minerals (illite, montmorrillonite). In the New Albany kerogen, Ni and V were shown to be predominantly associated with the organic matrix. Pyrite (and/or marcasite) was shown to occur in two forms, a euhedral variety and as framboidal clusters. The Ni content of the framboidal variety was found to be higher than that of the euhedral pyrite.

Fitzgerald, S.L.; Day, J.W.; Mercer, G.E.; Filby, R.H. (Washington State Univ., Pullman (USA))

1989-03-01T23:59:59.000Z

105

Determination of selected trace elements in human head hair by neutron activation analysis  

E-Print Network [OSTI]

the scope of this discussion. The final category of data contains barium and strontium. There was no data in the literature to use as a comparison, therefore the values of 49 ppm for barium and 87 ppm for strontium must stand on their own merit...) in Japan and of course, the current work in Texas. The results of the correlation analysis were that there were no significant correlations between any of the elements except in the case of strontium and barium which yielded a Pearson correlation coef...

Courson, Leonard Austin

2012-06-07T23:59:59.000Z

106

Multiple stirred-flow chamber assembly for simultaneous automatic fractionation of trace elements in fly ash samples using a multisyringe-based flow system  

SciTech Connect (OSTI)

There is a current trend in automation of leaching tests for trace elements in solid matrixes by use of flow injection based column approaches. However, as a result of the downscaled dimensions of the analytical manifold and execution of a single extraction at a time, miniaturized flow-through column approaches have merely found applications for periodic investigations of trace element mobility in highly homogeneous environmental solids. A novel flow-based configuration capitalized on stirred-flow cell extraction is proposed in this work for simultaneous fractionation of trace elements in three solid wastes with no limitation of sample amount up to 1.0 g. A two-step sequential extraction scheme involving water and acetic acid (or acetic acid/acetate buffer) is utilized for accurate assessment of readily mobilizable fractions of trace elements in fly ash samples. The W automated extraction system features high tolerance to flow rates ({<=} 6 mL min{sup -1}) and, as opposed to operationally defined batchwise methods, the solid to liquid ratio is not a critical parameter for, determination of overall readily leachable trace elements provided that exhaustive extraction is ensured. Analytical performance of the dynamic extractor is evaluated for fractionation analysis of a real coal fly ash and BCR-176R fly ash certified reference material. No significant differences were found at the 0.05 significance level between summation of leached concentrations in each fraction plus residue and concentration values of BCR-176R, thus revealing the accuracy of the automated method. Overall extractable pools of trace metals in three samples are separated in less than 115 min, even for highly contaminated ashes, versus 18-24 h per fraction in equilibrium leaching tests. The multiple stirred-flow cell assembly is thus suitable for routine risk assessment studies of industrial solid byproduct.

Boonjob, W.; Miro, M.; Cerda, V. [Mahidol University, Bangkok (Thailand). Faculty of Science

2008-10-01T23:59:59.000Z

107

Changes in trace element contents in ashes of oil shale fueled PF and CFB boilers during operation  

Science Journals Connector (OSTI)

Abstract Two oil shale combustion technologies, pulverized firing (PF) and circulated fluidized bed (CFB) were compared with respect to partitioning of selected elements (Ba, Cd, Co, Cr, Cu, Hg, Mn, Mo, Ni, Pb, Rb, Sb, Sn, Sr, Th, Tl, U, V, and Zn) in the ashes along the flue gas ducts. The ash samples were characterized by high-resolution ICP-MS. The average contents of toxic heavy metals in fly ash samples from the CFB boiler are lower compared to the PF boiler. Main differences in trace element contents between combustion technologies were as follows: Cd content in the fly ash samples of PF boiler was up to 0.9mg/kg while in CFB boiler it remained below 0.1mg/kg in all analyzed ash samples; Hg was observed in the ashes of electrostatic precipitator (ESP) of CFB boiler while in the PF boiler it was close to or below detection limit. In the PF boiler content of Sn was detected only in the ashes of ESPs, while in CFB boiler it was evenly distributed between bottom and fly ash samples. Highest content among heavy metals in ash samples was observed for Pb in the last field of ESP of the PF boiler (142mg/kg).

Janek Reinik; Natalya Irha; Eiliv Steinnes; Gary Urb; Jekaterina Jefimova; Eero Piirisalu; Jri Loosaar

2013-01-01T23:59:59.000Z

108

Simultaneous mobilization of trace elements and polycyclic aromatic hydrocarbon (PAH) compounds from soil with a nonionic surfactant and [S,S]-EDDS in admixture: Metals  

Science Journals Connector (OSTI)

This study evaluated the efficacy of soil washing with a nonionic surfactant (Brij98) in combination with a complexing reagent (ethylenediaminedisuccinic acid, [S,S]-EDDS) for the simultaneous mobilization of macro- and trace elements (MTEs) and PAH compounds from a field-contaminated soil. Soil fractionation studies indicated that an appreciable fraction of the Al, Ca, Cu, Fe and Mn was associated with the residual fraction but that much of the other trace elements (As, Cd, Cr, Ni, Pb and Zn) might be susceptible to soil washing. Ultrasonically aided mixing of the field contaminated soil with Brij98 and a sparing quantity (2mmol) of [S,S]-EDDS, simultaneously mobilized virtually all of the benzo[?]pyrene {B(a)P} and chrysene (CRY) and appreciable quantities of the trace elements (Cd, Cr, Mn, Ni, Pb, Zn) burdens. The recovery of both \\{PAHs\\} and trace elements were increased from the soil organic matter (SOM)-rich soil. This report concerns the fate of \\{MTEs\\} during soil washing. Multiple ultra-sonically aided washes (five or nine) with the same dosage of reagents mobilized virtually all of \\{PAHs\\} and decreased the levels of Cd, Cr, Ni, Pb and Zn to comply with recommended maxima. By contrast, the levels of As and Cu remained excessive after the treatments.

Yuexiang Wen; William D. Marshall

2011-01-01T23:59:59.000Z

109

TTG magmatism in the Congo craton; a view from major and trace element geochemistry, RbSr and SmNd systematics: case  

E-Print Network [OSTI]

TTG magmatism in the Congo craton; a view from major and trace element geochemistry, Rb­Sr and Sm of the Sangmelima region (Ntem complex, Congo craton) in southern Cameroon range in modal composition from rocks. TTG intrusions in the Sangmelima region represent a major Archaean accretion event in the Congo craton

Siebel, Wolfgang

110

The evolution of a complex type B allende inclusion: An ion microprobe trace element study  

SciTech Connect (OSTI)

USNM 5241 is a Type B1 refractory inclusion from Allende, first described by El Goresy et al. (1985), that consists of a 1.2 mm-thick melilite-rich and spinel-poor mantle enclosing a 0.6 cm-radius spinel-rich core; the inclusion contains xenoliths of spinel-free fassaite {plus minus} melilite {plus minus} anorthite incorporated within the spinel-rich core. Detailed ion microprobe analyses of individual phases in 5241 show that the rare earth element (REE) concentrations in mantle melilite vary irregularly with increasing distance from the rim of the inclusion, at first decreasing immediately below the rim and then remaining constant between {approximately}0.4 and 1.0 mm. More than 1.0 mm from the rim, the REE concentrations again decrease. Although counterintuitive in the context of traditional fractional crystallization models, these REE variations are in fact broadly consistent with such a model in light of recent experimental measurements of D{sub REE3+ (mel)}, that show a strong inverse correlation of D with the akermanite content of the melilite. Local variations, over distances of <20 {mu}m, in the akermanite content of mantle melilite--as much as 5-10 mol% Ak--with accompanying fluctuations in REE contents, are due to reaction of gehlenitic melilite with tiny inclusions of fassaite, producing narrow zones of more akermanitic melilite surrounding more fassaitic pyroxene. The authors interpret 5241 as having formed largely by fractional crystallization during the first {approximately}40% of its solidification; this was followed by fractional crystallization + xenolith assimilation during the last 60%.

MacPherson, G.J. (Smithsonian Institution, Washington, DC (USA)); Crozaz, G.; Lundberg, L.L. (Washington Univ., St. Louis, MO (USA))

1989-09-01T23:59:59.000Z

111

Telling friends from foes : strontium isotope and trace element analysis of companion burials from Pusilh, Toledo District, Belize  

E-Print Network [OSTI]

uranium, and the rare earth elements (REE) can readilyof uranium and the rare earth elements are extremely low andconsumed in vivo. The rare earth element lanthanum, like

Somerville, Andrew D.

2010-01-01T23:59:59.000Z

112

Electrostatic Precipitator Collection Efficiency and Trace Element Emissions from Co-Combustion of Biomass and Recovered Fuel in Fluidized-Bed Combustion  

Science Journals Connector (OSTI)

Electrostatic Precipitator Collection Efficiency and Trace Element Emissions from Co-Combustion of Biomass and Recovered Fuel in Fluidized-Bed Combustion ... In this investigation, electrostatic precipitator fractional collection efficiency and trace metal emissions were determined experimentally at a 66 MW biomass-fueled bubbling fluidized-bed combustion plant. ... The solid fuel combustion-generated particle emissions typically consist of two types of particles:? fine particles approximately 0.1?1 ?m in diameter that are formed from the ash-forming species that are volatilized during combustion and residual ash particles larger than 1 ?m in diameter that are formed from mineral impurities in the fuels (4). ...

Terttaliisa Lind; Jouni Hokkinen; Jorma K. Jokiniemi; Sanna Saarikoski; Risto Hillamo

2003-05-08T23:59:59.000Z

113

Carbon Nanotube-Silver Composite for Mercury Capture and Analysis  

Science Journals Connector (OSTI)

The mechanisms of capturing mercury on a sorbent vary from amalgamation, chemical adsorption to simple physical adsorption. ... Untreated carbon-based sorbents and mineral-based sorbents capture mercury mainly via physical adsorption that allows release of captured mercury at slightly higher temperatures. ... This paper outlines the results of a systematic study on the capture of trace mercury vapor from simulated flue gases, using activated carbons. ...

Guangqian Luo; Hong Yao; Minghou Xu; Xinwei Cui; Weixing Chen; Rajender Gupta; Zhenghe Xu

2009-12-17T23:59:59.000Z

114

Oxidation of trace amounts of transplutonium elements to the tetravalent state in solutions of mineral acids and their stabilities  

SciTech Connect (OSTI)

The behavior of trace amounts of americium(IV) in sulfuric and nitric acid solutions as a function of the mineral acid, potassium phosphotungstate, and ammonium persulfate concentrations was investigated. The stability of americium(IV) was studied. The optimal conditions and time of oxidation of trace amounts of americium to the tetravalent state were found on the basis of the experimental data obtained.

Milyukova, M.S.; Varezhkina, N.S.; Kuzovkina, E.V.; Malikov, D.A.; Myasoedov, B.F.

1989-01-01T23:59:59.000Z

115

PCB, PAH and trace element exposure in barn swallows nesting on the Grand Calumet River, IN, watershed  

SciTech Connect (OSTI)

The Grand Calumet River/Indiana Harbor Canal (GCR/IHC) is an International Joint Commission Area of Concern (AOC) and is heavily contaminated with polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs) and trace elements. Barn swallow hatchlings and nestlings were collected from four bridges which span the GCR/IHC and a reference location. PCB and PAH concentrations in hatchlings and nestlings were significantly higher in colonies along the GCR/IHC than the reference colony. For example, mean PCB concentrations in hatchlings and nestlings were significantly higher in colonies along the GCR/IHC than the reference colony. For example, mean PCB concentrations in hatchlings were 0.04 {micro}g/g wet weight at the reference colony and 20.42 {micro}g/g at one colony on the GCR/IHC; mean concentrations of PAHs were 0.05 {micro}g/g at the reference colony and 0.15 {micro}g/g at one colony on the GCR/IHC. PCBs accumulated in nestlings at a rate of 18.2 {micro}g/day at one colony on the GCR/IHC compared to 0.03 {micro}g/day at the reference colony. These data suggest that contaminants in the water and sediment of the GCR/IHC are being incorporated into the vertebrate food chain via aquatic insects. Because the contaminant data in the barn swallow hatchlings and nestlings seem to reflect the sediment chemistry nearby the colony, this study suggests that barn swallows are a useful biomonitoring species for this AOC.

Custer, T.W.; Sparks, D.W. [National Biological Service, La Crosse, WI (United States). Upper Mississippi Science Center; [Fish and Wildlife Service, Bloomington, IN (United States)

1995-12-31T23:59:59.000Z

116

NETL: Mercury Emissions Control Technologies - Pilot Testing of Mercury  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Testing of Mercury Oxidation Catalysts Project Summary Testing of Mercury Oxidation Catalysts Project Summary URS Group, Inc., Austin, TX, will demonstrate at the pilot scale the use of solid honeycomb catalysts to promote the oxidation of elemental mercury in the flue gas from coal combustion, and the use of a wet flue gas desulfurization (FGD) system downstream to remove the oxidized mercury at high efficiency. The project's pilot tests, conducted at electric generating plants using wet flue gas desulfurization systems and particulate collection systems, will be conducted for periods up to 14 months to provide data for future, full-scale designs. Mercury-oxidation potential will be measured periodically to provide long-term catalyst life data. The project is applicable to about 90,000 megawatts of generation capacity. Project partners are the Electric Power Research Institute, Palo Alto, CA, which will co-manage and co-fund the pilot tests, and five utilities.

117

An assessment of methyl mercury and volatile mercury in land-applied sewage sludge  

SciTech Connect (OSTI)

In 1993, the US Environmental Protection Agency issued regulations covering the land-application of municipal sewage sludge. These regulations established maximum pollutant concentrations and were based upon a risk assessment of human exposure. Mercury, assumed to be inorganic and non-volatile, was one pollutant evaluated. From April, 1995 through February, 1996, the authors studied the species of mercury contaminating municipal sludge applied to land, and the potential for volatilization of mercury from land-applied sludge. Methyl mercury was found at 0.1% of total mercury concentrations and was emitted from land-applied sludge to the atmosphere. Elemental mercury (Hg) was formed in land-applied sludge via the reduction of oxidized mercury and was also emitted to the atmosphere. Hg emission from land-applied sludge was significantly elevated over background soil emission. Methyl mercury is more toxic and more highly bioaccumulated than inorganic mercury, and warrants assessment considering these special criteria. Additionally, mercury emission from sludge-amended soil may lead to the contamination of other environmental media with significant concentrations of the metal. Although these pathways were not evaluated in the regulatory risk assessment, they are an important consideration for evaluating the risks from mercury in land-applied sludge. This presentation will summarize the results of a re-assessment of US EPA regulations regarding the land-application of municipal sewage sludge using data on methyl mercury toxicity and mercury transport in the atmosphere.

Carpi, A. [Cornell Univ., Ithaca, NY (United States); Lindberg, S.E. [Oak Ridge National Lab., TN (United States)

1995-12-31T23:59:59.000Z

118

Chemical Form Matters: Differential Accumulation of Mercury Following Inorganic and Organic Mercury Exposures in Zebrafish Larvae  

SciTech Connect (OSTI)

Mercury, one of the most toxic elements, exists in various chemical forms each with different toxicities and health implications. Some methylated mercury forms, one of which exists in fish and other seafood products, pose a potential threat, especially during embryonic and early postnatal development. Despite global concerns, little is known about the mechanisms underlying transport and toxicity of different mercury species. To investigate the impact of different mercury chemical forms on vertebrate development, we have successfully combined the zebrafish, a well-established developmental biology model system, with synchrotron-based X-ray fluorescence imaging. Our work revealed substantial differences in tissue-specific accumulation patterns of mercury in zebrafish larvae exposed to four different mercury formulations in water. Methylmercury species not only resulted in overall higher mercury burdens but also targeted different cells and tissues than their inorganic counterparts, thus revealing a significant role of speciation in cellular and molecular targeting and mercury sequestration. For methylmercury species, the highest mercury concentrations were in the eye lens epithelial cells, independent of the formulation ligand (chloride versus L-cysteine). For inorganic mercury species, in absence of L-cysteine, the olfactory epithelium and kidney accumulated the greatest amounts of mercury. However, with L-cysteine present in the treatment solution, mercuric bis-L-cysteineate species dominated the treatment, significantly decreasing uptake. Our results clearly demonstrate that the common differentiation between organic and inorganic mercury is not sufficient to determine the toxicity of various mercury species.

Korbas, Malgorzata; MacDonald, Tracy C.; Pickering, Ingrid J.; George, Graham N.; Krone, Patrick H. (Saskatchewan)

2013-04-08T23:59:59.000Z

119

Mercury capture in bench-scale absorbers  

SciTech Connect (OSTI)

This paper gives,a brief overview of research being conducted at Argonne National Laboratory on the capture of mercury by both dry sorbents and wet scrubbers. The emphasis in the research is on development of a better understanding of the key factors that control the capture of mercury. Future work is expected to utilize that information for the development of new or modified process concepts featuring enhanced mercury capture capabilities. The results and conclusions to date from the Argonne -research on dry sorbents can be summarized as follows: lime hydrates, either regular or high-surface-area, are `not effective in removing mercury; mercury removals are enhanced by the addition of activated carbon; mercury removals with activated carbon decrease with increasing temperature, larger particle size, and decreasing mercury concentration in the gas; and chemical pretreatment (e.g., with sulfur or (CaCl{sub 2}) can greatly increase the removal capacity of activated carbon. Preliminary results from the wet scrubbing research include: no removal of elemental mercury is obtained under normal scrubber operating conditions; mercury removal is improved by the addition of packing or production of smaller gas bubbles to increase the gas-liquid contact area; polysulfide solutions do not appear promising for enhancing mercury removal in typical FGC systems; stainless steel packing appears to have beneficial properties for mercury removal and should be investigated further; and other chemical additives may offer greatly enhanced removals.

Livengood, C.D.; Huang, H.S.; Mendelsohn, M.H.; Wu, J.M.

1994-08-01T23:59:59.000Z

120

Mercury Thermometer Replacement Alternatives Thermometer Description Non-Mercury Non-Mercury Non-Mercury  

E-Print Network [OSTI]

Mercury Thermometer Replacement Alternatives Length Thermometer Description Non-Mercury Non-Mercury Non-Mercury Range / Division VWR-Enviro-Safe® Fisherbrand® Brooklyn Thermometer Company Inc. Total/A #12;Mercury Thermometer Replacement Alternatives Length Thermometer Description Non-Mercury Non

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121

DOE Issues Final Mercury Storage Environmental Impact Statement: Texas Site  

Broader source: Energy.gov (indexed) [DOE]

DOE Issues Final Mercury Storage Environmental Impact Statement: DOE Issues Final Mercury Storage Environmental Impact Statement: Texas Site Is Preferred for Long-Term Mercury Storage DOE Issues Final Mercury Storage Environmental Impact Statement: Texas Site Is Preferred for Long-Term Mercury Storage January 19, 2011 - 12:00pm Addthis Media Contact (202) 586-4940 WASHINGTON - The Department of Energy has prepared a Final Long-Term Management and Storage of Elemental Mercury Environmental Impact Statement to analyze the potential environmental, human health, and socioeconomic impacts of elemental mercury storage at seven locations. Based on these factors, DOE identified the Waste Control Specialists, LLC, site near Andrews, Texas, as the preferred alternative for long-term management and storage of mercury. DOE will consider the environmental impact information presented in this

122

Trace elements found in the fuel and in-furnace fine particles collected from 80MW BFB combusting solid recovered fuel  

Science Journals Connector (OSTI)

The main fine particle (dpSRF) combustion the main elements were found to be: Ba, Br, Cr, Cu, Fe, Pb, Sb, Sn and Zn. Fine particle composition is presented for 6 different furnace heights of a bubbling fluidized bed (BFB) boiler. As the fine particles are formed of vaporized ash species the experimental results are discussed with the support of thermodynamic equilibrium modeling for estimating the forms of the gaseous elements in the furnace. The occurrence of bromine was found to be similar to chlorine as the main forms of bromine in the furnace were estimated to be KBr(g) and NaBr(g) complemented with CuBr3(g). It is proposed that the trace elements mentioned originate mainly from plastics and rubber where they are used as production additives, stabilisers, dyes, colorants and flame retardants. Cr, Cu and Zn may originate to a large extent from alloys and other metallic impurities. SEM-EDS analyses carried out for the SRF supports the postulated origin of the elements.

P. Vainikka; D. Lindberg; A. Moilanen; H. Ollila; M. Tiainen; J. Silvennoinen; M. Hupa

2013-01-01T23:59:59.000Z

123

Thermodynamic evaluation of the compounds of gold, silver, and other trace elements formed upon the combustion of brown coal  

Science Journals Connector (OSTI)

The thermodynamically most probable main compounds of Ag, Au, Ge, Se, Sr, U, and ash-forming elements formed upon the combustion of brown coal, which was close in the composition of organic and mineral matter ...

M. Ya. Shpirt; A. A. Lavrinenko; I. N. Kuznetsova

2013-09-01T23:59:59.000Z

124

PARTITIONING OF MAJOR, MINOR, AND TRACE ELEMENTS DURING SIMULATED IN SITU OIL SHALE RETORTING IN A CONTROLLED-STATE RETORT  

E-Print Network [OSTI]

elements. Over 25% of the raw shale gas five groups productsthe oil, in the raw oil shale gas, consequence of retortinggood product raw oil shale and input gases that is accounted

Fox, J. P.

2011-01-01T23:59:59.000Z

125

Trace element disequilibria and magnesium isotope heterogeneity in 3655A: Evidence for a complex multi-stage evolution of a typical Allende Type B1 CAI  

SciTech Connect (OSTI)

We used the Panurge ion microprobe to measure concentrations of the rare earth elements (REEs), Ba, Hf, and Sr in melilite, clinopyroxene. plagioclase, and perovskite and Mg isotopes in plagioclase, spinel, melilite, fassaite, hibonite, grossular, and monticellite from the Allende Type B1 calcium-, aluminum-rich inclusion (CAI), USNM 3655A. The distribution and concentration of Ba and the REE in melilite from the melilite-rich mantle of 3655A are unlike those predicted from melilite-melt REE partitioning experiments for closed system crystal fractionation. REE concentrations are lower than expected in the first crystallized gehlenitic melilite, increase rapidly to higher than expected concentrations in melilite with intermediate akermanite contents (Ak30-Ak40), and decrease as expected only during the late stage of mantle crystallization. Barium concentrations in melilite are 10-50 times those expected, and the LREE/HREE ratio increases continuously rather than remaining constant. The unexpected distribution of trace elements in melilite reflects a progressive enrichment of trace elements in the melt during the early stages of crystallization. A partial explanation for this observation is the dissolution of precursor perovskite that contained half or more of the total REE budget of the inclusion. The Mg isotope record of 3655A is distinguished by four salient features: (1) large {sup 26}Mg excesses correlated with the respective Al/Mg ratios in plagioclase, melilite, and hibonite, (2) F{sub Mg}, the mass-dependent fractionation of Mg, is positive. with enrichment of the heavier Mu isotopes in all primary phases, (3) a heterogeneous distribution of F{sub Mg} values. with F{sub Mg} in melilite systematically greater than in either spinel or fassaite, and (4) isotopically normal Mg in the secondary alteration phases, grossular and monticellite. 81 refs., 9 figs., 8 tabs.

Kennedy, A.K.; Hutcheon, I.D.; Beckett, J.R. [California Institute of Technology, Pasadena, CA (United States)] [and others] [California Institute of Technology, Pasadena, CA (United States); and others

1997-04-01T23:59:59.000Z

126

FY09 assessment of mercury reduction at SNL/NM.  

SciTech Connect (OSTI)

This assessment takes the result of the FY08 performance target baseline of mercury at Sandia National Laboratories/New Mexico, and records the steps taken in FY09 to collect additional data, encourage the voluntary reduction of mercury, and measure success. Elemental (metallic) mercury and all of its compounds are toxic, and exposure to excessive levels can permanently damage or fatally injure the brain and kidneys. Elemental mercury can also be absorbed through the skin and cause allergic reactions. Ingestion of inorganic mercury compounds can cause severe renal and gastrointestinal damage. Organic compounds of mercury such as methyl mercury, created when elemental mercury enters the environment, are considered the most toxic forms of the element. Exposures to very small amounts of these compounds can result in devastating neurological damage and death.1 SNL/NM is required to report annually on the site wide inventory of mercury for the Environmental Protection Agency's (EPA) Toxics Release Inventory (TRI) Program, as the site's inventory is excess of the ten pound reportable threshold quantity. In the fiscal year 2008 (FY08) Pollution Prevention Program Plan, Section 5.3 Reduction of Environmental Releases, a performance target stated was to establish a baseline of mercury, its principle uses, and annual quantity or inventory. This was accomplished on July 29, 2008 by recording the current status of mercury in the Chemical Information System (CIS).

McCord, Samuel Adam

2010-02-01T23:59:59.000Z

127

Mercury sorbent delivery system for flue gas  

DOE Patents [OSTI]

The invention presents a device for the removal of elemental mercury from flue gas streams utilizing a layer of activated carbon particles contained within the filter fabric of a filter bag for use in a flue gas scrubbing system.

Klunder; ,Edgar B. (Bethel Park, PA)

2009-02-24T23:59:59.000Z

128

Elements of environmental concern in the 1990 Clean Air Act Amendments: A perspective of Fort Union coals in northern Rocky Mountains and Great Plains region  

SciTech Connect (OSTI)

The elements of environmental concern (EECs) named in the 1990 Clean Air Act Amendments include 12 trace elements consisting of antimony, arsenic, beryllium, cadmium, chromium, cobalt, lead, manganese, mercury, nickel, selenium, and uranium. Although all these trace elements are potentially hazardous, arsenic, mercury, lead, and selenium may be targeted in forthcoming Environmental Protection Agency regulations. Fort Union coals contain all the trace elements named in the Clean Air Act Amendments; however, the presence and amounts of individual trace elements vary from basin to basin. In the Powder River Basin, the major producing Fort Union coals (Wyodak-Anderson and equivalent coal beds, and Rosebud coal bed) contain the lowest (or statistically as low) amounts of EECs of any of the coal producing basins (i.e., Williston, Hanna, and Green River) in the region. In addition, when the arithmetic means of these trace elements in Powder River Basin coals are compared to other regions in the conterminous US, they are lower than those of Cretaceous coals in Colorado Plateau, Tertiary lignites in the Gulf Coast, and Pennsylvanian coals in the Illinois and Appalachian Basins. Thus, elements of environmental concern are generally low in Fort Union coals in the Northern Rocky Mountains and Great Plains region, and particularly low in the Powder River Basin. Projected increase in production of Powder River Basin coals will, therefore, be of greater benefit to the nation than an increase in development and production of coals in other basins.

Stricker, G.D.; Ellis, M.E.; Flores, R.M.; Bader, L.R.

1998-07-01T23:59:59.000Z

129

Elements of environmental concern in the 1990 Clean Air Act amendments: A perspective of Fort Union coals in northern Rocky Mountains and Great Plains region  

SciTech Connect (OSTI)

The elements of environmental concern (EECs) named in the 1990 Clean Air Act Amendments include 12 trace elements consisting of antimony, arsenic, beryllium, cadmium, chromium, cobalt, lead, manganese, mercury, nickel, selenium, and uranium. Although all these trace elements are potentially hazardous, arsenic, mercury, lead, and selenium may be targeted in forthcoming Environmental Protection Agency regulations. Fort Union coals contain all the trace elements named in the Clean Air Act Amendments; however, the presence and amounts of individual trace elements vary from basin to basin. In the Powder River Basin, the major producing Fort Union coals (Wyodak-Anderson and equivalent coal beds, and Rosebud coal bed) contain the lowest (or statistically as low) amounts of EECs of any of the coal producing basins (i.e. Williston, Hanna, and Green River) in the region. In addition, when the arithmetic means of these trace elements in Powder River Basin coals are compared to other regions in the conterminous U.S., they are lower than those of Cretaceous coals in Colorado Plateau, Tertiary lignites in the Gulf Coast, and Pennsylvanian coals in the Illinois and Appalachian Basins. Thus, elements of environmental concern are generally low in Fort Union coals in the Northern Rocky Mountains and Great Plains region, and particularly low in the Powder River Basin. Projected increase in production of Powder River Basin coals will, therefore, be of greater benefit to the nation than an increase in development and production of coals in other basins.

Stricker, G.D.; Ellis, M.E.; Flores, R.M.; Bader, L.R. [Geological Survey, Denver, CO (United States)

1998-04-01T23:59:59.000Z

130

Partitioning of radionuclides and trace elements in phosphogypsum and its source materials based on sequential extraction methods  

Science Journals Connector (OSTI)

Phosphogypsum is a waste produced by the phosphate fertilizer industry. Although phosphogypsum is mainly calcium sulphate dihydrate, it contains elevated levels of impurities, which originate from the source phosphate rock used in the phosphoric acid production. Among these impurities, radionuclides from 238U and 232Th decay series are of most concern due to their radiotoxicity. Other elements, such as rare earth elements (REE) and Ba are also enriched in the phosphogypsum. The bioavailability of radionuclides (226Ra, 210Pb and 232Th), rare earth elements and Ba to the surrounding aquatic system was evaluated by the application of sequential leaching of the phosphogypsum samples from the Brazilian phosphoric acid producers. The sequential extraction results show that most of the radium and lead are located in the iron oxide (non-CaSO4) fraction, and that only 1318% of these radionuclides are distributed in the most labile fraction. Th, REE and Ba were found predominantly in the residual phase, which corresponds to a small fraction of the phosphate rock or monazite that did not react and to insoluble compounds such as sulphates, phosphates and silicates. It can be concluded that although all these elements are enriched in the phosphogypsum samples they are not associated with CaSO4 itself and therefore do not represent a threat to the surrounding aquatic environment.

A.J.G. Santos; B.P. Mazzilli; D.I.T. Fvaro; P.S.C. Silva

2006-01-01T23:59:59.000Z

131

Crystal Site Location of Iron and Trace Elements in a Magnesium-Iron Olivine by a New Crystallographic Technique  

Science Journals Connector (OSTI)

...element A can be shown to depend only on Ns;, NMg, and NA as obtained from the two spectra. The analysis used to determine CFe, CMn, and CN, in Table 1 is essentially as described above. However, in order to improve the statistical accuracy, three...

J. TAFT; J. C. H. SPENCE

1982-10-01T23:59:59.000Z

132

MERCURY EXCESS  

Science Journals Connector (OSTI)

Congress and EPA probe possibility of long-term STORAGE of liquid metal CHERYL HOGUE, C&EN WASHINGTON ... Hazardous waste handlers keep mercury from polluting the environment by reclaiming the liquid metal from scrap electrical switches, thermometers, and fluorescent light bulbs. ...

2007-07-02T23:59:59.000Z

133

Removal of mercury from coal via a microbial pretreatment process  

SciTech Connect (OSTI)

A process for the removal of mercury from coal prior to combustion is disclosed. The process is based on use of microorganisms to oxidize iron, sulfur and other species binding mercury within the coal, followed by volatilization of mercury by the microorganisms. The microorganisms are from a class of iron and/or sulfur oxidizing bacteria. The process involves contacting coal with the bacteria in a batch or continuous manner. The mercury is first solubilized from the coal, followed by microbial reduction to elemental mercury, which is stripped off by sparging gas and captured by a mercury recovery unit, giving mercury-free coal. The mercury can be recovered in pure form from the sorbents via additional processing.

Borole, Abhijeet P. (Knoxville, TN); Hamilton, Choo Y. (Knoxville, TN)

2011-08-16T23:59:59.000Z

134

NETL: Mercury Emissions Control Technologies - Bench Scale Kinetics of  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Bench Scale Kinetics of Mercury Reactions in FGD Liquors Bench Scale Kinetics of Mercury Reactions in FGD Liquors When research into the measurement and control of Hg emissions from coal-fired power plants began in earnest in the early 1990s, it was observed that oxidized mercury can be scrubbed at high efficiency in wet FGD systems, while elemental mercury can not. In many cases, elemental mercury concentrations were observed to increase slightly across wet FGD systems, but this was typically regarded as within the variability of the measurement methods. However, later measurements have shown substantial re-emissions from some FGD systems. The goal of this project is to develop a fundamental understanding of the aqueous chemistry of mercury (Hg) absorbed by wet flue gas desulfurization (FGD) scrubbing liquors. Specifically, the project will determine the chemical reactions that oxidized mercury undergoes once absorbed, the byproducts of those reactions, and reaction kinetics.

135

Mercury Continuous Emmission Monitor Calibration  

SciTech Connect (OSTI)

Mercury continuous emissions monitoring systems (CEMs) are being implemented in over 800 coal-fired power plant stacks throughput the U.S. Western Research Institute (WRI) is working closely with the Electric Power Research Institute (EPRI), the National Institute of Standards and Technology (NIST), and the Environmental Protection Agency (EPA) to facilitate the development of the experimental criteria for a NIST traceability protocol for dynamic elemental mercury vapor calibrators/generators. These devices are used to calibrate mercury CEMs at power plant sites. The Clean Air Mercury Rule (CAMR) which was published in the Federal Register on May 18, 2005 and vacated by a Federal appeals court in early 2008 required that calibration be performed with NIST-traceable standards. Despite the vacature, mercury emissions regulations in the future will require NIST traceable calibration standards, and EPA does not want to interrupt the effort towards developing NIST traceability protocols. The traceability procedures will be defined by EPA. An initial draft traceability protocol was issued by EPA in May 2007 for comment. In August 2007, EPA issued a conceptual interim traceability protocol for elemental mercury calibrators. The protocol is based on the actual analysis of the output of each calibration unit at several concentration levels ranging initially from about 2-40 {micro}g/m{sup 3} elemental mercury, and in the future down to 0.2 {micro}g/m{sup 3}, and this analysis will be directly traceable to analyses by NIST. The EPA traceability protocol document is divided into two separate sections. The first deals with the qualification of calibrator models by the vendors for use in mercury CEM calibration. The second describes the procedure that the vendors must use to certify the calibrators that meet the qualification specifications. The NIST traceable certification is performance based, traceable to analysis using isotope dilution inductively coupled plasma/mass spectrometry (ID/ICP/MS) performed by NIST in Gaithersburg, MD. The outputs of mercury calibrators are compared to one another using a nesting procedure which allows direct comparison of one calibrator with another at specific concentrations and eliminates analyzer variability effects. The qualification portion of the EPA interim traceability protocol requires the vendors to define calibrator performance as affected by variables such as pressure, temperature, line voltage, and shipping. In 2007 WRI developed and conducted a series of simplified qualification experiments to determine actual calibrator performance related to the variables defined in the qualification portion of the interim protocol.

John Schabron; Eric Kalberer; Ryan Boysen; William Schuster; Joseph Rovani

2009-03-12T23:59:59.000Z

136

Method for combined removal of mercury and nitrogen oxides from off-gas streams  

DOE Patents [OSTI]

A method for removing elemental Hg and nitric oxide simultaneously from a gas stream is provided whereby the gas stream is reacted with gaseous chlorinated compound to convert the elemental mercury to soluble mercury compounds and the nitric oxide to nitrogen dioxide. The method works to remove either mercury or nitrogen oxide in the absence or presence of each other.

Mendelsohn, Marshall H. (Downers Grove, IL); Livengood, C. David (Lockport, IL)

2006-10-10T23:59:59.000Z

137

ZZ Mercury Storage Book.indb  

Broader source: Energy.gov (indexed) [DOE]

2 2 Comment Response Document Environmental Impact Statement Final Final Environmental Impact Statement DOE/EIS-0423 January 2011 Long-Term Management and Storage of Elemental Mercury Long-Term Management and Storage of Elemental Mercury For additional information on this Final Mercury Storage EIS, contact: AVAILABILITY OF THIS FINAL LONG-TERM MANAGEMENT AND STORAGE OF ELEMENTAL MERCURY ENVIRONMENTAL IMPACT STATEMENT David Levenstein, Document Manager Office of Environmental Compliance (EM-41) U.S. Department of Energy Post Office Box 2612 Germantown, MD 20874 Website: http://www.mercurystorageeis.com Fax: 877-274-5462 Printed with soy ink on recycled paper Cover Sheet Lead Agency: U.S. Department of Energy (DOE) Cooperating Agencies: U.S. Environmental Protection Agency (EPA)

138

Uncertainty Measurement for Trace Element Analysis of Uranium and Plutonium Samples by Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) and Inductively Coupled Plasma-Mass Spectrometry (ICP-MS)  

SciTech Connect (OSTI)

The measurement uncertainty estimatino associated with trace element analysis of impurities in U and Pu was evaluated using the Guide to the Expression of Uncertainty Measurement (GUM). I this evalution the uncertainty sources were identified and standard uncertainties for the components were categorized as either Type A or B. The combined standard uncertainty was calculated and a coverage factor k = 2 was applied to obtain the expanded uncertainty, U. The ICP-AES and ICP-MS methods used were deveoped for the multi-element analysis of U and Pu samples. A typical analytical run consists of standards, process blanks, samples, matrix spiked samples, post digestion spiked samples and independent calibration verification standards. The uncertainty estimation was performed on U and Pu samples that have been analyzed previously as part of the U and Pu Sample Exchange Programs. Control chart results and data from the U and Pu metal exchange programs were combined with the GUM into a concentration dependent estimate of the expanded uncertainty. Comparison of trace element uncertainties obtained using this model was compared to those obtained for trace element results as part of the Exchange programs. This process was completed for all trace elements that were determined to be above the detection limit for the U and Pu samples.

Gallimore, David L. [Los Alamos National Laboratory

2012-06-13T23:59:59.000Z

139

Probing Mercury's Partnering Preferences  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Preferences Probing Mercury's Partnering Preferences Merc.gif Why it Matters: Mercury (Hg) is a major global pollutant arising from both natural and anthropogenic sources....

140

It's Elemental - The Element Gold  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Platinum Platinum Previous Element (Platinum) The Periodic Table of Elements Next Element (Mercury) Mercury The Element Gold [Click for Isotope Data] 79 Au Gold 196.966569 Atomic Number: 79 Atomic Weight: 196.966569 Melting Point: 1337.33 K (1064.18°C or 1947.52°F) Boiling Point: 3129 K (2856°C or 5173°F) Density: 19.282 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 6 Group Number: 11 Group Name: none What's in a name? From the Sanskrit word Jval and the Anglo-Saxon word gold. Gold's chemical symbol comes from the the latin word for gold, aurum. Say what? Gold is pronounced as GOLD. History and Uses: An attractive and highly valued metal, gold has been known for at least 5500 years. Gold is sometimes found free in nature but it is usually found

Note: This page contains sample records for the topic "mercury trace elements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Trace element and REE composition of five samples of the Yucca Mountain calcite-silica deposits. Special report No. 8  

SciTech Connect (OSTI)

The attached materials document the results of part of a recent effort of geochemical sampling and analysis at Yucca Mountain and nearby regions. The efforts come as a result of interest in comprehensive analyses of rare earth elements (REE), lanthanum (La) through lutecium (Lu). Several additional, non-REE analyses were obtained as well. Commercially available REE analyses have proved to be insufficiently sensitive for geochemical purposes. Dr. Roman Schmitt at the Radiation Center at Oregon State University in Corvallis was sent five samples as a trial effort. The results are very encouraging. The purpose of compiling Dr. Schmitt`s report and the other materials is to inform the sponsor of his independent observations of these results and other information that sent to him. To provide a more complete appreciation of the utility of REE analyses a copy of Dave Vaniman`s recent article is included in which he notes that REE analyses from Yucca Mountain indicate the occurrence of two distinctly different REE patterns as do several other chemical parameters of the calcite-silica deposits. Our four samples with high equivalent CaCO{sub 3} were collected from sites we believe to be spring deposits. One sample, 24D, is from southern Crater Flat which is acknowledged by U.S.G.S. investigators to be a spring deposit. All four of these samples have REE patterns similar to those from the saturated zone reported by Vaniman.

Livingston, D.

1993-07-01T23:59:59.000Z

142

A study of the effect of chloride on mercury removal in a fluidized bed combustion (FBC) system  

SciTech Connect (OSTI)

Mercury exists in three forms, which are elemental mercury, inorganic mercury compounds, and organic mercury. Each form of mercury has a very different exposure potential. Oxidized mercury is soluble and has a tendency to associate with particles. Nearly all the post-combustion flue gas cleaning systems proposed to remove mercury may be categorized as either scrubbers or adsorbers. Therefore, the mercury sink in the cleaning system will be either the excess water of a wet scrubber or the mercury laden sorbent from an absorber. The major problem for post-combustion mercury capture systems is capturing the practically water-insoluble elemental mercury. Co-firing with high chlorine coal or RDF in utility boiler systems can provide an HCI atmosphere for the oxidation of elemental mercury in flue gas at relatively low temperatures (500--600 C). The objective of this study is to increase the efficiency of mercury emission cleaning methods by using HCl to convert elemental mercury to oxidized mercury species at low monetary costs and lower other toxic air emissions. When high chlorine (0.3--0.5%) coals were burned and a high intensity vortex flow (from secondary air) was used, around 70% of the total mercury in the fuel was condensed and absorbed by the fly ash (including calcium compounds). The remaining 30% of total fuel mercury was emitted in the gas phase in the flue gas. As for the gas phase mercury, about 98% of it exists in an oxidized form with a higher boiling temperature than elemental mercury and can be easily captured by an ESP or FGP apparatus. Only about 0.5% of the total fuel mercury was released to the atmosphere in elemental form.

Liu, K.; Gao, Y.; Li, F.; Pan, W.P.; Riley, J.T.; Mehta, A.K.; Ho, K.K.; Smith, S.R.

2000-07-01T23:59:59.000Z

143

Mercury contamination extraction  

DOE Patents [OSTI]

Mercury is removed from contaminated waste by firstly applying a sulfur reagent to the waste. Mercury in the waste is then permitted to migrate to the reagent and is stabilized in a mercury sulfide compound. The stable compound may then be removed from the waste which itself remains in situ following mercury removal therefrom.

Fuhrmann, Mark (Silver Spring, MD); Heiser, John (Bayport, NY); Kalb, Paul (Wading River, NY)

2009-09-15T23:59:59.000Z

144

Assessing the Risk of Mercury in Drinking Water after UV Lamp Breaks Page 1 Assessing the Risk of Mercury in Drinking Water after UV Lamp Breaks  

E-Print Network [OSTI]

Assessing the Risk of Mercury in Drinking Water after UV Lamp Breaks Page 1 Assessing the Risk of Mercury in Drinking Water after UV Lamp Breaks Heidi Borchers University of New Hampshire, Environmental Ultraviolet (UV) lamps generate ultraviolet light through the vaporization of elemental mercury, by using

145

A Cavity Ring-Down Spectroscopy Mercury Continuous Emission Monitor  

SciTech Connect (OSTI)

The Sensor Research & Development Corporation (SRD) has undertaken the development of a Continuous Emissions Monitor (CEM) for mercury based on the technique of Cavity Ring-Down Spectroscopy (CRD). The project involved building an instrument for the detection of trace levels of mercury in the flue gas emissions from coal-fired power plants. The project has occurred over two phases. The first phase concentrated on the development of the ringdown cavity and the actual detection of mercury. The second phase dealt with the construction and integration of the sampling system, used to carry the sample from the flue stack to the CRD cavity, into the overall CRD instrument. The project incorporated a Pulsed Alexandrite Laser (PAL) system from Light Age Incorporated as the source to produce the desired narrow band 254 nm ultra-violet (UV) radiation. This laser system was seeded with a diode laser to bring the linewidth of the output beam from about 150 GHz to less than 60 MHz for the fundamental beam. Through a variety of non-linear optics the 761 nm fundamental beam is converted into the 254 nm beam needed for mercury detection. Detection of the mercury transition was verified by the identification of the characteristic natural isotopic structure observed at lower cavity pressures. The five characteristic peaks, due to both natural isotopic abundance and hyperfine splitting, provided a unique identifier for mercury. SRD scientists were able to detect mercury in air down below 10 parts-per-trillion by volume (pptr). This value is dependent on the pressure and temperature within the CRD cavity at the time of detection. Sulfur dioxide (SO{sub 2}) absorbs UV radiation in the same spectral region as mercury, which is a significant problem for most mercury detection equipment. However, SRD has not only been able to determine accurate mercury concentrations in the presence of SO{sub 2}, but the CRD instrument can in fact determine the SO{sub 2} concentration as well. Detection of mercury down to the low hundreds of pptr has been accomplished in the presence of SO{sub 2} at concentration levels much higher than that found in typical flue gas emissions. SRD scientists extended the interferent testing to each individual component found in flue gas. It was found that only SO{sub 2} had a significant effect on the ring-down decay curve. Upon completion of testing the components of flue gas individually a simulated flue gas stream was used to test to the CRD instrument. The result showed accurate detection of mercury down to levels below 100 pptr in a simulated flue gas stream with the concentrations of the various components above that found in a typical untreated flue gas. A sampling system was designed and integrated into the CRD instrument to carry the sample from the flue gas stack to the CRD cavity. The sampling system was constructed so that it could be placed very close to the sampling port. SRD scientists were able to couple the UV laser light into an optical fiber, which is then sent to the sampling system. This allows the laser system to be isolated from the sampling system. Initial long-term testing revealed a couple of problems related to the stability of the output frequency of the laser system. These problems have been successfully dealt with by incorporating specific software solutions into the overall data acquisition program. The project culminated in a field test conducted at the DOE/NETL pilot plant facility in Pittsburgh, Pennsylvania. The object of the test was the evaluation of a cavity ringdown spectrometer constructed for the detection of TOTAL vapor phase mercury as a continuous emission monitor (CEM). Although there is the potential for the instrument to determine the amount of speciation between neutral elemental mercury (Hg{sup (o)}) and oxidized mercury (Hg{sup (+2)}), the initial test plan was to concentrate on the measurement of the total mercury. Another added benefit is that the measurements will report the sulfur dioxide (SO 2) concentration throughout the test. This report concludes the technical work asso

Christopher C. Carter

2004-12-15T23:59:59.000Z

146

Isotope and trace element evolution of the Naica aquifer (Chihuahua, Mexico) over the past 60,000yr revealed by speleothems  

Science Journals Connector (OSTI)

Abstract The espada speleothems of Cueva de las Espadas (Naica Mine, Chihuahua, Mexico) comprise a high-purity selenite core overlain by successive deposits of calcite, gypsum and aragonite. Gypsum precipitated under water from a hydrothermal solution (~58C) when the water table was above the cave level ca. 57ka, during the last glaciation, and some intervals during deglaciation and the Holocene. Aragonite was deposited at lower temperatures (~26C) in a perched lake occupying the cave bottom, when the water table dropped below the cave level during brief dry intervals during deglaciation and the early Holocene. The isotopic composition of gypsum water of crystallization shows that the deglaciationHolocene aquifer water was enriched in deuterium by 12.88.7 relative to water from the last glaciation. This is attributed to an increased relative moisture contribution from the Gulf of Mexico during deglaciation and the Holocene compared to the last glaciation. This indicates that drier conditions occurred in the Naica area during the Holocene than around 57ka. Furthermore, trace element analyses of gypsum served to deduce the circulation regime of the Naica aquifer during the past 60,000yr, and also suggest that higher aquifer recharge occurred during the last glaciation.

Fernando Gzquez; Jos-Mara Calaforra; Heather Stoll; Laura Sanna; Paolo Forti; Stein-Erik Lauritzen; Antonio Delgado; Fernando Rull; Jess Martnez-Fras

2013-01-01T23:59:59.000Z

147

Historical Interrelated Variations of Mercury and Aquatic Organic Matter in Lake Sediment Cores from a Subarctic Lake in Yukon, Canada: Further Evidence toward the Algal-Mercury Scavenging Hypothesis  

Science Journals Connector (OSTI)

Historical Interrelated Variations of Mercury and Aquatic Organic Matter in Lake Sediment Cores from a Subarctic Lake in Yukon, Canada: Further Evidence toward the Algal-Mercury Scavenging Hypothesis ... In recent sediments, S1 is a good indicator of the labile portion of algal-derived organic matter, but it is highly susceptible to the degradation exerted by selective diagenetic processes (by bacterial processes and/or oxidation). ... The pelagic-to-benthic process of algal scavenging of contaminants such as Hg in these lakes is exactly analogous to the well-known biological pump that operates in the worlds oceans to transfer carbon and trace elements including Hg from the upper oceanic water column to bottom waters and sediments (24). ...

G. A. Stern; H. Sanei; P. Roach; J. DeLaronde; P. M. Outridge

2009-09-21T23:59:59.000Z

148

Thief carbon catalyst for oxidation of mercury in effluent stream  

DOE Patents [OSTI]

A catalyst for the oxidation of heavy metal contaminants, especially mercury (Hg), in an effluent stream is presented. The catalyst facilitates removal of mercury through the oxidation of elemental Hg into mercury (II) moieties. The active component of the catalyst is partially combusted coal, or "Thief" carbon, which can be pre-treated with a halogen. An untreated Thief carbon catalyst can be self-promoting in the presence of an effluent gas streams entrained with a halogen.

Granite, Evan J. (Wexford, PA); Pennline, Henry W. (Bethel Park, PA)

2011-12-06T23:59:59.000Z

149

Abstracts from a workshop on processes determining the input, behavior and fate of radionuclides and trace elements in continental shelf environments  

SciTech Connect (OSTI)

Abstracts of workshop presentations concerning input, behavior, and fate of trace metals and radionuclides in the marine system are presented. (ACR)

Not Available

1980-03-01T23:59:59.000Z

150

Development of an electromagnetically actuated mercury microvalve  

SciTech Connect (OSTI)

The development of microscale fluid handling components has been recognized as a crucial element in the design of microscale chemical detection systems. Recently, work has been undertaken at Sandia National Laboratories to construct a valve that uses a small mercury droplet to control the flow of gas through capillary passages. Electromagnetic forces that are provided by small permanent magnets and a current supply are used to drive the mercury into position. Driving the mercury droplet into a tapered passage halts gas flow through a capillary, while surface tension forces prevent the mercury from passing through the passage. Models have been developed to describe the movement of the mercury droplet and the sealing of the gas passage, and millimeter-scale units have been tested to explore design options. Predictions from the model show that a valve with 10 micron sized features can seal against pressures up to 1.5 atmospheres. Experiments have highlighted the promise of mercury valves and demonstrated problems that can arise from contamination of the mercury.

Adkins, D.R.; Wong, C.C.

1998-08-01T23:59:59.000Z

151

WDM school, January 14, 2008 Equation of State for Fluid Mercury  

E-Print Network [OSTI]

1 WDM school, January 14, 2008 Equation of State for Fluid Mercury Based on Interatomic Many, Fluid Metals (Princeton, 1999) elements Tc (K) Pc (bar) c (g/cm3) Mercury (Hg) Cesium (Cs) Rubidium (Rb.30 divalent monovalent (alkali) Importance of mercury -- lowest critical temperature -- critical point

152

Mercury and Fish  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mercury and Fish Mercury and Fish Name: donna Location: N/A Country: N/A Date: N/A Question: how does mercury get into fish in rivers. what is the ecological process involved which could produce toxic levels of mercury in fish and eventually get into humans? Replies: Hi Donna! Nowadays mercury or its compounds are used at a high scale in many industries as the manufacture of chemicals, paints, household itens, pesticides and fungicides. These products can contaminate humans (and mamals) by direct contact, ingestion or inhalation. Besides the air can become contaminated also, and since mercury compounds produce harmful effects in body tissues and functions, that pollution is very dangerous. Now for your question: Efluent wastes containing mercury in various forms sometimes are dropped in sea water or in rivers or lakes. There the mercury may be converted by bacteria, that are in the muddy sediments, into organic mercurial compounds particularly the highly toxic alkyl mercurials ( methyl and di-methyl mercury), which may in turn be concentrated by the fishes and other aquatic forms of life that are used as food by men. The fishes dont seem to be affected but they are able to concentrate mercury in high poisoning levels, and if human beings, mamals or birds eat these containing mercury fishes, algae, crabs or oysters they will be contaminated and poisoned.

153

Note: Production of a mercury beam with an electron cyclotron resonance ion source  

SciTech Connect (OSTI)

An electron cyclotron resonance ion source has been utilized to produce mercury beams with intensities of 4.5 e?A of {sup 202}Hg{sup 29+} and 3.0 e?A of {sup 202}Hg{sup 31+} from natural abundance mercury metal. The production technique relies on the evaporation of liquid mercury into the source plasma vacuum region and utilizes elemental mercury instead of a volatile organic compound as the neutral feed material.

Vondrasek, R.; Pardo, R.; Scott, R. [Physics Division, Argonne National Laboratory, Lemont, Illinois 60439 (United States)] [Physics Division, Argonne National Laboratory, Lemont, Illinois 60439 (United States)

2013-11-15T23:59:59.000Z

154

Geological and Anthropogenic Factors Influencing Mercury Speciation in Mine  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Geological and Anthropogenic Factors Influencing Mercury Speciation Geological and Anthropogenic Factors Influencing Mercury Speciation in Mine Wastes Christopher S. Kim,1 James J. Rytuba,2 Gordon E. Brown, Jr.3 1Department of Physical Sciences, Chapman University, Orange, CA 92866 2U.S. Geological Survey, Menlo Park, CA 94025 3Department of Geological and Environmental Sciences, Stanford University, Stanford, CA 94305 Introduction Figure 1. Dr. Christopher Kim collects a mine waste sample from the Oat Hill mercury mine in Northern California. The majority of mercury mine wastes at these sites are present as loose, unconsolidated piles, facilitating the transport of mercury-bearing material downstream into local watersheds. Mercury (Hg) is a naturally occurring element that poses considerable health risks to humans, primarily through the consumption of fish which

155

Sulfur isotope and trace element data from ore sulfides in the Noranda district (Abitibi, Canada): implications for volcanogenic massive sulfide deposit genesis  

Science Journals Connector (OSTI)

We examine models for volcanogenic massive sulfide (VMS) mineralization in the ~2.7-Ga Noranda camp, Abitibi subprovince, Superior Province, Canada, using a combination of multiple sulfur isotope and trace ele...

Elizabeth R. Sharman; Bruce E. Taylor; William G. Minarik

2014-10-01T23:59:59.000Z

156

Catalysts for Oxidation of Mercury in Flue Gas  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Catalysts for Oxidation of Mercury in Flue Gas Catalysts for Oxidation of Mercury in Flue Gas Opportunity The Department of Energy's National Energy Technology Laboratory (NETL) is seeking licensing partners interested in implementing United States Patent Number 7,776,780 entitled "Catalysts for Oxidation of Mercury in Flue Gas." Disclosed in this patent are catalysts for the oxidation of elemental mercury in flue gas. These novel catalysts include iridium (Ir), platinum/iridium (Pt/Ir), and Thief carbons. The catalyst materials will adsorb the oxidizing agents HCl, Cl 2 , and other halogen species in the flue gas stream that are produced when fuel is combusted. These adsorbed oxidizing agents can then react with elemental mercury in the stream, which is difficult to capture, and oxidize it to form Hg (II) species,

157

E-Print Network 3.0 - analyzing elemental composition Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

SIMS trace- element data (up to 33 elements analyzed) are among... thermal processing. Bulk trace-element compositions: Our broad- beam SIMS data imply that vapor... refractory...

158

Detection of concealed mercury with thermal neutrons  

SciTech Connect (OSTI)

In the United States today, governments at all levels and the citizenry are paying increasing attention to the effects, both real and hypothetical, of industrial activity on the environment. Responsible modem industries, reflecting this heightened public and regulatory awareness, are either substituting benign materials for hazardous ones, or using hazardous materials only under carefully controlled conditions. In addition, present-day environmental consciousness dictates that we deal responsibly with legacy wastes. The decontamination and decommissioning (D&D) of facilities at which mercury was used or processed presents a variety of challenges. Elemental mercury is a liquid at room temperature and readily evaporates in air. In large mercury-laden buildings, droplets may evaporate from one area only to recondense in other cooler areas. The rate of evaporation is a function of humidity and temperature; consequently, different parts of a building may be sources or sinks of mercury at different times of the day or even the year. Additionally, although mercury oxidizes in air, the oxides decompose upon heating. Hence, oxides contained within pipes or equipment, may be decomposed when those pipes and equipment are cut with saws or torches. Furthermore, mercury seeps through the pores and cracks in concrete blocks and pads, and collects as puddles and blobs in void spaces within and under them.

Bell, Z.W.

1994-08-18T23:59:59.000Z

159

Oxidation of Mercury in Products of Coal Combustion  

SciTech Connect (OSTI)

Laboratory measurements of mercury oxidation during selective catalytic reduction (SCR) of nitric oxide, simulation of pilot-scale measurements of mercury oxidation and adsorption by unburned carbon and fly ash, and synthesis of new materials for simultaneous oxidation and adsorption of mercury, were performed in support of the development of technology for control of mercury emissions from coal-fired boilers and furnaces. Conversion of gas-phase mercury from the elemental state to water-soluble oxidized form (HgCl{sub 2}) enables removal of mercury during wet flue gas desulfurization. The increase in mercury oxidation in a monolithic V{sub 2}O{sub 5}-WO{sub 3}/TiO{sub 2} SCR catalyst with increasing HCl at low levels of HCl (< 10 ppmv) and decrease in mercury oxidation with increasing NH{sub 3}/NO ratio during SCR were consistent with results of previous work by others. The most significant finding of the present work was the inhibition of mercury oxidation in the presence of CO during SCR of NO at low levels of HCl. In the presence of 2 ppmv HCl, expected in combustion products from some Powder River Basin coals, an increase in CO from 0 to 50 ppmv reduced the extent of mercury oxidation from 24 {+-} 3 to 1 {+-} 4%. Further increase in CO to 100 ppmv completely suppressed mercury oxidation. In the presence of 11-12 ppmv HCl, increasing CO from 0 to {approx}120 ppmv reduced mercury oxidation from {approx}70% to 50%. Conversion of SO{sub 2} to sulfate also decreased with increasing NH{sub 3}/NO ratio, but the effects of HCl and CO in flue gas on SO{sub 2} oxidation were unclear. Oxidation and adsorption of mercury by unburned carbon and fly ash enables mercury removal in a particulate control device. A chemical kinetic mechanism consisting of nine homogeneous and heterogeneous reactions for mercury oxidation and removal was developed to interpret pilot-scale measurements of mercury oxidation and adsorption by unburned carbon and fly ash in experiments at pilot scale, burning bituminous coals (Gale, 2006) and blends of bituminous coals with Powder River Basin coal (Gale, 2005). The removal of mercury by fly ash and unburned carbon in the flue gas from combustion of the bituminous coals and blends was reproduced with satisfactory accuracy by the model. The enhancement of mercury capture in the presence of calcium (Gale, 2005) explained a synergistic effect of blending on mercury removal across the baghouse. The extent of mercury oxidation, on the other hand, was not so well described by the simulation, because of oversensitivity of the oxidation process in the model to the concentration of unburned carbon. Combined catalysts and sorbents for oxidation and removal of mercury from flue gas at low temperature were based on surfactant-templated silicas containing a transition metal and an organic functional group. The presence of both metal ions and organic groups within the pore structure of the materials is expected to impart to them the ability to simultaneously oxidize elemental mercury and adsorb the resulting oxidized mercury. Twelve mesoporous organosilicate catalysts/sorbents were synthesized, with and without metals (manganese, titanium, vanadium) and organic functional groups (aminopropyl, chloropropyl, mercaptopropyl). Measurement of mercury oxidation and adsorption by the candidate materials remains for future work.

Peter Walsh; Giang Tong; Neeles Bhopatkar; Thomas Gale; George Blankenship; Conrad Ingram; Selasi Blavo Tesfamariam Mehreteab; Victor Banjoko; Yohannes Ghirmazion; Heng Ban; April Sibley

2009-09-14T23:59:59.000Z

160

Source-attribution for atmospheric mercury deposition: Where does the mercury in mercury deposition come from?  

E-Print Network [OSTI]

1 Source-attribution for atmospheric mercury deposition: Where does the mercury in mercury of the Mercury Working Group, Office of Air Quality, Indiana Department of Environmental Management (IDEM) April 21, 2005 #12;2 For mercury, how important is atmospheric deposition relative to other loading

Note: This page contains sample records for the topic "mercury trace elements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Long-Term Demonstration of Sorbent Enhancement Additive Technology for Mercury Control  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Long-Term DemonsTraTion of sorbenT Long-Term DemonsTraTion of sorbenT enhancemenT aDDiTive TechnoLogy for mercury conTroL Background The 2005 Clean Air Mercury Rule will require significant reductions in mercury emissions from coal-fired power plants. The combustion of subbituminous coals typically results in higher fractions of elemental mercury emissions than the combustion of bituminous coals. This complicates mercury capture efforts, particularly for technologies using powdered activated carbon (PAC) injection, because elemental mercury is not readily captured by PAC injection alone. In short, unmodified PACs are better suited for bituminous coals than for subbituminous coals. Various proprietary sorbent enhancement additives (SEA) have been developed to increase the mercury reactivity of PACs, and perhaps fly

162

Mercury Detection with Gold Nanoparticles  

E-Print Network [OSTI]

R. J. Warmack, Detection of mercury vapor using resonatingA surface acoustic wave mercury vapor sensor, Ieee Trans.N. E. Selin, Integrating mercury science and policy in the

Crosby, Jeffrey

2013-01-01T23:59:59.000Z

163

Process for low mercury coal  

DOE Patents [OSTI]

A process for producing low mercury coal during precombustion procedures by releasing mercury through discriminating mild heating that minimizes other burdensome constituents. Said mercury is recovered from the overhead gases by selective removal.

Merriam, Norman W. (Laramie, WY); Grimes, R. William (Laramie, WY); Tweed, Robert E. (Laramie, WY)

1995-01-01T23:59:59.000Z

164

Process for low mercury coal  

DOE Patents [OSTI]

A process is described for producing low mercury coal during precombustion procedures by releasing mercury through discriminating mild heating that minimizes other burdensome constituents. Said mercury is recovered from the overhead gases by selective removal. 4 figures.

Merriam, N.W.; Grimes, R.W.; Tweed, R.E.

1995-04-04T23:59:59.000Z

165

Could Pantheon Fossae be the result of the Apollodorus crater-forming impact within the Caloris basin, Mercury?  

E-Print Network [OSTI]

basin, Mercury? Andrew M. Freed a, , Sean C. Solomon b , Thomas R. Watters c , Roger J. Phillips d February 2009 Available online xxxx Editor: T. Spohn Keywords: Mercury Caloris basin Pantheon Fossae on Mercury. Here we use a series of nite element models to explore the idea that the Apollodorus crater

Freed, Andrew

166

Mercury Chamber Considerations  

E-Print Network [OSTI]

Mercury Chamber Considerations V. Graves IDS-NF Target Studies July 2011 #12;2 Managed by UT-Battelle for the U.S. Department of Energy Mercury Chamber Considerations, July 2011 Flow Loop Review · 1 cm dia nozzle, 20 m/s jet requires 1.57 liter/sec mercury flow (94.2 liter/min, 24.9 gpm). · MERIT experiment

McDonald, Kirk

167

Partitioning of mercury, arsenic, selenium, boron, and chloride in a full-scale coal combustion process equipped with selective catalytic reduction, electrostatic precipitation, and flue gas desulfurization systems  

SciTech Connect (OSTI)

A full-scale field study was carried out at a 795 MWe coal-fired power plant equipped with selective catalytic reduction (SCR), an electrostatic precipitator (ESP), and wet flue gas desulfurization (FGD) systems to investigate the distribution of selected trace elements (i.e., mercury, arsenic, selenium, boron, and chloride) from coal, FGD reagent slurry, makeup water to flue gas, solid byproduct, and wastewater streams. Flue gases were collected from the SCR outlet, ESP inlet, FGD inlet, and stack. Concurrent with flue gas sampling, coal, bottom ash, economizer ash, and samples from the FGD process were also collected for elemental analysis. By combining plant operation parameters, the overall material balances of selected elements were established. The removal efficiencies of As, Se, Hg, and B by the ESP unit were 88, 56, 17, and 8%, respectively. Only about 2.5% of Cl was condensed and removed from flue gas by fly ash. The FGD process removed over 90% of Cl, 77% of B, 76% of Hg, 30% of Se, and 5% of As. About 90% and 99% of the FGD-removed Hg and Se were associated with gypsum. For B and Cl, over 99% were discharged from the coal combustion process with the wastewater. Mineral trona (trisodium hydrogendicarbonate dehydrate, Na{sub 3}H(CO{sub 3}){sub 2}.2H{sub 2}O) was injected before the ESP unit to control the emission of sulfur trioxide (SO{sub 3}). By comparing the trace elements compositions in the fly ash samples collected from the locations before and after the trona injection, the injection of trona did not show an observable effect on the partitioning behaviors of selenium and arsenic, but it significantly increased the adsorption of mercury onto fly ash. The stack emissions of mercury, boron, selenium, and chloride were for the most part in the gas phase. 47 refs., 3 figs., 11 tabs.

Chin-Min Cheng; Pauline Hack; Paul Chu; Yung-Nan Chang; Ting-Yu Lin; Chih-Sheng Ko; Po-Han Chiang; Cheng-Chun He; Yuan-Min Lai; Wei-Ping Pan [Western Kentucky University, Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology

2009-09-15T23:59:59.000Z

168

Analysis of Halogen-Mercury Reactions in Flue Gas  

SciTech Connect (OSTI)

Oxidized mercury species may be formed in combustion systems through gas-phase reactions between elemental mercury and halogens, such as chorine or bromine. This study examines how bromine species affect mercury oxidation in the gas phase and examines the effects of mixtures of bromine and chlorine on extents of oxidation. Experiments were conducted in a bench-scale, laminar flow, methane-fired (300 W), quartz-lined reactor in which gas composition (HCl, HBr, NO{sub x}, SO{sub 2}) and temperature profile were varied. In the experiments, the post-combustion gases were quenched from flame temperatures to about 350 C, and then speciated mercury was measured using a wet conditioning system and continuous emissions monitor (CEM). Supporting kinetic calculations were performed and compared with measured levels of oxidation. A significant portion of this report is devoted to sample conditioning as part of the mercury analysis system. In combustion systems with significant amounts of Br{sub 2} in the flue gas, the impinger solutions used to speciate mercury may be biased and care must be taken in interpreting mercury oxidation results. The stannous chloride solution used in the CEM conditioning system to convert all mercury to total mercury did not provide complete conversion of oxidized mercury to elemental, when bromine was added to the combustion system, resulting in a low bias for the total mercury measurement. The use of a hydroxylamine hydrochloride and sodium hydroxide solution instead of stannous chloride showed a significant improvement in the measurement of total mercury. Bromine was shown to be much more effective in the post-flame, homogeneous oxidation of mercury than chlorine, on an equivalent molar basis. Addition of NO to the flame (up to 400 ppmv) had no impact on mercury oxidation by chlorine or bromine. Addition of SO{sub 2} had no effect on mercury oxidation by chlorine at SO{sub 2} concentrations below about 400 ppmv; some increase in mercury oxidation was observed at SO{sub 2} concentrations of 400 ppmv and higher. In contrast, SO{sub 2} concentrations as low as 50 ppmv significantly reduced mercury oxidation by bromine, this reduction could be due to both gas and liquid phase interactions between SO{sub 2} and oxidized mercury species. The simultaneous presence of chlorine and bromine in the flue gas resulted in a slight increase in mercury oxidation above that obtained with bromine alone, the extent of the observed increase is proportional to the chlorine concentration. The results of this study can be used to understand the relative importance of gas-phase mercury oxidation by bromine and chlorine in combustion systems. Two temperature profiles were tested: a low quench (210 K/s) and a high quench (440 K/s). For chlorine the effects of quench rate were slight and hard to characterize with confidence. Oxidation with bromine proved sensitive to quench rate with significantly more oxidation at the lower rate. The data generated in this program are the first homogeneous laboratory-scale data on bromine-induced oxidation of mercury in a combustion system. Five Hg-Cl and three Hg-Br mechanisms, some published and others under development, were evaluated and compared to the new data. The Hg-halogen mechanisms were combined with submechanisms from Reaction Engineering International for NO{sub x}, SO{sub x}, and hydrocarbons. The homogeneous kinetics under-predicted the levels of mercury oxidation observed in full-scale systems. This shortcoming can be corrected by including heterogeneous kinetics in the model calculations.

Paula Buitrago; Geoffrey Silcox; Constance Senior; Brydger Van Otten

2010-01-01T23:59:59.000Z

169

Sorption Mechanisms for Mercury Capture in Warm Post-Gasification Gas Clean-Up Systems  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sorption MechaniSMS for Mercury Sorption MechaniSMS for Mercury capture in WarM poSt-GaSification GaS clean-up SySteMS Background Power generation systems employing gasification technology must remove a variety of potential air pollutants, including mercury, from the synthetic gas steam prior to combustion. In general, efforts to remove mercury have focused on removal at lower temperatures (under 300 °F). The ability to remove mercury at warm-gas cleanup conditions (300 °F to 700 °F) or in the hot-gas cleanup range (above 1200 °F) would provide plant operators with greater flexibility to choose the treatment method best suited to conditions at their plant. The University of Arizona is investigating the use of paper waste-derived sorbents (PWDS) for the removal of mercury and other trace metals at temperatures in and

170

Dynamic duo captures mercury  

SciTech Connect (OSTI)

There is strong evidence that the combination of wet flue gas desulphurisation (FGD) scrubbers and selective catalytic reduction (SCR) can prove a viable and formidable combination for knocking out mercury. This article analyzes the capabilities and limitations of the SCR-FGD combination for mercury compliance, including applicability to different types of coal and issues with scrubber by-products. 3 figs.

Senior, C.; Adams, B. [Reaction Engineering International (United States)

2006-02-15T23:59:59.000Z

171

Mercury in the environment  

ScienceCinema (OSTI)

Abbott works for Idaho National Laboratory as an environmental scientist. Using state-of-thescienceequipment, he continuously samples the air, looking for mercury. In turn, he'll analyzethis long-term data and try to figure out the mercury's point of or

Idaho National Laboratory - Mike Abbott

2010-01-08T23:59:59.000Z

172

NETL: Mercury Emissions Control  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Home > Technologies > Coal & Power Systems > Innovations for Existing Plants > Mercury Emissions Control Home > Technologies > Coal & Power Systems > Innovations for Existing Plants > Mercury Emissions Control Innovations for Existing Plants Mercury Emissions Control NETL managed the largest funded research program in the country to develop an in-depth understanding of fossil combustion-based mercury emissions. The program goal was to develop effective control options that would allow generators to comply with regulations. Research focus areas included measurement and characterization of mercury emissions, as well as the development of cost-effective control technologies for the U.S. coal-fired electric generating industry. Control Technologies Field Testing Phase I & II Phase III Novel Concepts APCD Co-benefits Emissions Characterization

173

XAS Catches the Chemical Form of Mercury in Fish  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

view large image view large image contact info Friday, 29 August 2003 X-ray Absorption Spectroscopy Catches the Chemical Form of Mercury in Fish - SSRL Scientists Reveal New Findings in Science Article The presence of "methyl mercury" in fish is well-known, but until now the detailed chemical identity of the mercury has remained a mystery. In an x-ray absorption spectroscopy study published in the August 29 issue of Science (Science 301, 2003: 1203; Science now: Murky Picture on Fish Mercury), SSRL scientists report that the chemical form of mercury involves a sulfur atom (most likely in a so-called aliphatic form). The study presents significant new knowledge - because the toxic properties of mercury (or any element) are critically dependent upon its chemical form - and represents an important milestone in developing an understanding of how harmful mercury in fish might actually be. The study was carried out by SSRL staff scientists Ingrid Pickering and Graham George and postdoctoral fellow Hugh Harris using SSRL's structural molecular biology beam line 9-3. The very high flux, excellent beam stability and state-of-the-art detector technology allowed the team to measure samples of fish containing micromolar levels of mercury, much lower than had previously been possible.

174

Mercury removal in utility wet scrubber using a chelating agent  

DOE Patents [OSTI]

A method for capturing and reducing the mercury content of an industrial flue gas such as that produced in the combustion of a fossil fuel or solid waste adds a chelating agent, such as ethylenediaminetetraacetic acid (EDTA) or other similar compounds like HEDTA, DTPA and/or NTA, to the flue gas being scrubbed in a wet scrubber used in the industrial process. The chelating agent prevents the reduction of oxidized mercury to elemental mercury, thereby increasing the mercury removal efficiency of the wet scrubber. Exemplary tests on inlet and outlet mercury concentration in an industrial flue gas were performed without and with EDTA addition. Without EDTA, mercury removal totaled 42%. With EDTA, mercury removal increased to 71%. The invention may be readily adapted to known wet scrubber systems and it specifically provides for the removal of unwanted mercury both by supplying S.sup.2- ions to convert Hg.sup.2+ ions into mercuric sulfide (HgS) and by supplying a chelating agent to sequester other ions, including but not limited to Fe.sup.2+ ions, which could otherwise induce the unwanted reduction of Hg.sup.2+ to the form, Hg.sup.0.

Amrhein, Gerald T. (Louisville, OH)

2001-01-01T23:59:59.000Z

175

Chemical characterization of element 112  

Science Journals Connector (OSTI)

... directly comparing the adsorption characteristics of 283112 to that of mercury and the noble gas radon, we find that element 112 is very volatile and, unlike ... , we find that element 112 is very volatile and, unlike radon, reveals a metallic interaction with the gold surface. These adsorption characteristics establish element 112 ...

R. Eichler; N. V. Aksenov; A. V. Belozerov; G. A. Bozhikov; V. I. Chepigin; S. N. Dmitriev; R. Dressler; H. W. Gggeler; V. A. Gorshkov; F. Haenssler; M. G. Itkis; A. Laube; V. Ya. Lebedev; O. N. Malyshev; Yu. Ts. Oganessian; O. V. Petrushkin; D. Piguet; P. Rasmussen; S. V. Shishkin; A. V. Shutov; A. I. Svirikhin; E. E. Tereshatov; G. K. Vostokin; M. Wegrzecki; A. V. Yeremin

2007-05-03T23:59:59.000Z

176

Mercury Jet Studies Tristan Davenne  

E-Print Network [OSTI]

Mercury Jet Studies Tristan Davenne Rutherford Appleton Laboratory Joint UKNF, INO, UKIERI meeting mercury target and reported a radial velocity at surface of mercury jet due to proton beam is 36m/s #12;Numerical simulation of Sievers & Pugnat Result Click on image above to watch video of 2cm mercury target

McDonald, Kirk

177

Mercury Effects, Sources and Control Measures  

E-Print Network [OSTI]

Mercury Effects, Sources and Control Measures Prepared by Alan B. Jones, Brooks Rand, Ltd., Seattle ................................................................................................................................1 MERCURY SOURCES....................................................................................................................................................................................8 Mercury dumping from naval vessels

178

Mercury Sensing with Optically Responsive Gold Nanoparticles  

E-Print Network [OSTI]

We assume that the mass of mercury adsorbed at saturation istactics, nanoparticle based mercury sensing should advancemost sensitive method for mercury sensing. References "1!

James, Jay Zachary

2012-01-01T23:59:59.000Z

179

Mercury Contamination in Pelagic Fishes of the Gulf of Mexico  

E-Print Network [OSTI]

2 Map of sampling locations at the docks and offshore from ` Freeport and Port Aransas, Texas, and Venice, Louisiana, in the NW of Gulf of Mexico. .................................................................... 11 3 Mean Hg concentration...). Figure 1 Mercury cycling and bioaccumulation in aquatic system (Engstrom 2007). Elemental Hg can be oxidized by chemical reactions that depend on ozone, solar energy and water content in the atmosphere. Mercury oxidation is a photochemical 6...

Kuklyte, Ligita

2012-10-19T23:59:59.000Z

180

ORNL research reveals new challenges for mercury cleanup | ornl.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Jennifer Brouner Jennifer Brouner Communications 865.241.0709 ORNL research reveals new challenges for mercury cleanup ORNL researchers are learning more about the microbial processes that convert elemental mercury into methylmercury. ORNL researchers are learning more about the microbial processes that convert elemental mercury into methylmercury. (hi-res image) OAK RIDGE, Tenn., Aug. 5, 2013 - More forms of mercury can be converted to deadly methylmercury than previously thought, according to a study published Sunday in Nature Geoscience. The discovery provides scientists with another piece of the mercury puzzle, bringing them one step closer to understanding the challenges associated with mercury cleanup. Earlier this year, a multidisciplinary team of researchers at Oak Ridge

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181

Field Testing of Activated Carbon Injection Options for Mercury Control at TXU's Big Brown Station  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Field TesTing oF AcTivATed cArbon Field TesTing oF AcTivATed cArbon injecTion opTions For Mercury conTrol AT TXu's big brown sTATion Background The 2005 Clean Air Mercury Rule will require significant reductions in mercury emissions from coal-fired power plants. Lignite coal is unique because of its highly variable ash content (rich in alkali and alkaline-earth elements), high moisture levels, low chlorine content, and high calcium content. Unique to Texas lignite coals are relatively high iron and selenium concentrations. When combusting Texas lignite coals, up to 80 percent of the mercury in the flue gas is present as elemental mercury, which is not readily captured by downstream pollution control devices. To better understand the factors that influence mercury control at units firing

182

Final disposal options for mercury/uranium mixed wastes from the Oak Ridge Reservation  

SciTech Connect (OSTI)

Laboratory testing was completed on chemical stabilization and physical encapsulation methods that are applicable (to comply with federal and state regulations) to the final disposal of both hazardous and mixed hazardous elemental mercury waste that is in either of the following categories: (1) waste generated during decontamination and decommissioning (D and D) activities on mercury-contaminated buildings, such as Building 9201-4 at the Oak Ridge Y-12 Plant, or (2) waste stored and regulated under either the Federal Facilities Compliance Agreement or the Federal Facilities Compliance Act. Methods were used that produced copper-mercury, zinc-mercury, and sulfur-mercury materials at room temperature by dry mixing techniques. Toxicity Characteristic Leaching Procedure (TCLP) results for mercury on batches of both the copper-mercury and the sulfur-mercury amalgams consistently produced leachates with less than the 0.2-mg/L Resource Conservation and Recovery Act (RCRA) regulatory limit for mercury. The results clearly showed that the reaction of mercury with sulfur at room temperature produces black mercuric sulfide, a material that is well suited for land disposal. The results also showed that the copper-mercury and zinc-mercury amalgams had major adverse properties that make them undesirable for land disposal. In particular, they reacted readily in air to form oxides and liberate elemental mercury. Another major finding of this study is that sulfur polymer cement is potentially useful as a physical encapsulating agent for mercuric sulfide. This material provides a barrier in addition to the chemical stabilization that further prevents mercury, in the form of mercuric sulfide, from migrating into the environment.

Gorin, A.H.; Leckey, J.H.; Nulf, L.E.

1994-08-29T23:59:59.000Z

183

Demonstration of New Technologies Required for the Treatment of Mixed Waste Contaminated with {ge}260 ppm Mercury  

SciTech Connect (OSTI)

The Resource Conservation and Recovery Act (RCRA) defines several categories of mercury wastes, each of which has a defined technology or concentration-based treatment standard, or universal treatment standard (UTS). RCRA defines mercury hazardous wastes as any waste that has a TCLP value for mercury of 0.2 mg/L or greater. Three of these categories, all nonwastewaters, fall within the scope of this report on new technologies to treat mercury-contaminated wastes: wastes as elemental mercury; hazardous wastes with less than 260 mg/kg [parts per million (ppm)] mercury; and hazardous wastes with 260 ppm or more of mercury. While this report deals specifically with the last category--hazardous wastes with 260 ppm or more of mercury--the other two categories will be discussed briefly so that the full range of mercury treatment challenges can be understood. The treatment methods for these three categories are as follows: Waste as elemental mercury--RCRA identifies amalgamation (AMLGM) as the treatment standard for radioactive elemental mercury. However, radioactive mercury condensates from retorting (RMERC) processes also require amalgamation. In addition, incineration (IMERC) and RMERC processes that produce residues with >260 ppm of radioactive mercury contamination and that fail the RCRA toxicity characteristic leaching procedure (TCLP) limit for mercury (0.20 mg/L) require RMERC, followed by AMLGM of the condensate. Waste with <260 ppm mercury--No specific treatment method is specified for hazardous wastes containing <260 ppm. However, RCRA regulations require that such wastes (other than RMERC residues) that exceed a TCLP mercury concentration of 0.20 mg/L be treated by a suitable method to meet the TCLP limit for mercury of 0.025 mg/L. RMERC residues must meet the TCLP value of {ge}0.20 mg/L, or be stabilized and meet the {ge}0.025 mg/L limit. Waste with {ge}260 ppm mercury--For hazardous wastes with mercury contaminant concentrations {ge}260 ppm and RCRA-regulated organic contaminants (other than incinerator residues), incineration or retorting (IMERC or RMERC) is the treatment standard. For wastes with mercury contaminant concentrations {ge}260 ppm that are inorganic, including incinerator and retort residues, RMERC is the treatment standard. Mercury hazardous waste contaminated with {ge}260 ppm mercury is the primary focus of this report.

Morris, M.I.

2002-02-06T23:59:59.000Z

184

It's Elemental - The Element Indium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Cadmium Cadmium Previous Element (Cadmium) The Periodic Table of Elements Next Element (Tin) Tin The Element Indium [Click for Isotope Data] 49 In Indium 114.818 Atomic Number: 49 Atomic Weight: 114.818 Melting Point: 429.75 K (156.60°C or 313.88°F) Boiling Point: 2345 K (2072°C or 3762°F) Density: 7.31 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 5 Group Number: 13 Group Name: none What's in a name? Named after the bright indigo line in its spectrum. Say what? Indium is pronounced as IN-dee-em. History and Uses: Indium was discovered by the German chemists Ferdinand Reich and Hieronymus Theodor Richter in 1863. Reich and Richter had been looking for traces of the element thallium in samples of zinc ores. A brilliant indigo line in

185

Mercury Risk Assessment  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ASSESSING THE MERCURY HEALTH RISKS ASSOCIATED ASSESSING THE MERCURY HEALTH RISKS ASSOCIATED WITH COAL-FIRED POWER PLANTS: IMPACTS OF LOCAL DEPOSITIONS *T.M. Sullivan 1 , F.D. Lipfert 2 , S.M. Morris 2 , and S. Renninger 3 1 Building 830, Brookhaven National Laboratory, Upton, NY 11973 2 Private Consultants 3 Department of Energy, National Energy Technology Laboratory, Morgantown, WV ABSTRACT The U.S. Environmental Protection Agency has announced plans to regulate emissions of mercury to the atmosphere from coal-fired power plants. However, there is still debate over whether the limits should be placed on a nationwide or a plant-specific basis. Before a nationwide limit is selected, it must be demonstrated that local deposition of mercury from coal-fired power plants does not impose an excessive local health risk. The principal health

186

Enrichment of trace elements in rare-metal bearing pegmatites of the muscovite class: Examples from the Jasper, Thomaston-Barnesville, Troup and Cherokee-Pickens districts in Georgia  

SciTech Connect (OSTI)

Pegmatites from four important mining districts in Georgia: the Cherokee-Pickens district (mica and beryl), the Thomaston-Barnesville (mica), Troup (beryl), and Jasper County (feldspar) districts, generally contain quartz, muscovite, K-feldspar and oligoclase and can be included in the muscovite class of pegmatites. No source intrusions are known for any of these pegmatite districts. The Thomaston-Barnesville district covers about 2,000 km[sup 2] compared to the < 100 km[sup 2] of the other three districts and includes 3--4 times as many pegmatites as each of the other districts. The more highly fractionated pegmatites represent 42 to 48 % of the total number of pegmatites sampled in each district except for the Thomaston-Barnesville district in which only 7 % are more highly fractionated. Muscovites from the more highly fractionated pegmatites in these districts contain mean trace element values of 1,118--1,732 ppm Rb, 1,867--3,083 ppm F, 91--278 ppm Li, 7.7-31 ppm Be, 122--147 ppm Ga, 122--315 ppm Nb, and 137--254 ppm Zn. These pegmatites have mean Ba/Rb and Rb/K[sub 2]O ratios of 0.01--0.21 and 129--177 ppm. Mean Ba is 19--234 ppm. Mean trace element values of muscovites from the least fractionated pegmatites are 381--675 ppm Rb, 748--1,622 ppm F, 33--221 ppm Li, 4:8--20.6 ppm Be, 56--80 ppm Ga, 32--152 ppm Nb, and 59--113 ppm Zn. These pegmatites have mean Ba/Rb and Rb/K[sub 2]O ratios of 0.44--2.83 and 39--76. Mean Ba is 218--857 ppm. In each district, the more highly fractionated pegmatites contain beryl or are in the vicinity of beryl-bearing pegmatites.

Cocker, M.D. (Georgia Geologic Survey, Atlanta, GA (United States))

1992-01-01T23:59:59.000Z

187

TURTLE with MAD input (Trace Unlimited Rays Through Lumped Elements) -- A computer program for simulating charged particle beam transport systems and DECAY TURTLE including decay calculations  

SciTech Connect (OSTI)

TURTLE is a computer program useful for determining many characteristics of a particle beam once an initial design has been achieved, Charged particle beams are usually designed by adjusting various beam line parameters to obtain desired values of certain elements of a transfer or beam matrix. Such beam line parameters may describe certain magnetic fields and their gradients, lengths and shapes of magnets, spacings between magnetic elements, or the initial beam accepted into the system. For such purposes one typically employs a matrix multiplication and fitting program such as TRANSPORT. TURTLE is designed to be used after TRANSPORT. For convenience of the user, the input formats of the two programs have been made compatible. The use of TURTLE should be restricted to beams with small phase space. The lumped element approximation, described below, precludes the inclusion of the effect of conventional local geometric aberrations (due to large phase space) or fourth and higher order. A reading of the discussion below will indicate clearly the exact uses and limitations of the approach taken in TURTLE.

Carey, D.C.

1999-12-09T23:59:59.000Z

188

Determination of mercury and organic mercury contents in Malaysian seafood  

Science Journals Connector (OSTI)

The contents of mercury and organic mercury in various types of seafood from various location in Malaysia were determined...Rastrelliger kanagurta), Spanish mackerel (Scomberomurus commersoni), shrimp (Peneaus sp...

S. A. Rahman; A. K. Wood; S. Sarmani

1997-03-01T23:59:59.000Z

189

NETL: Mercury Emissions Inactive Mercury Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Completed Mercury Projects Completed Mercury Projects View specific project information by clicking the state of interest on the map. Clickable U.S. Map ALABAMA Characterizing Toxic Emissions from Coal-Fired Power Plants Southern Research Institute The objective of this contract is to perform sampling and analysis of air toxic emissions at commercial coal-fired power plants in order to collect data that the EPA will use in their Congressionally mandated report on Hazardous Air Pollutants from Electric Utilities. CALIFORNIA Assessment of Toxic Emissions from a Coal-Fired Power Plant Utilizing an ESP Energy & Environmental Research Corporation – CA The overall objective of this project is to conduct comprehensive assessments of toxic emissions of two coal-fired electric utility power plants. The power plant that was assessed for toxic emissions during Phase I was American Electric Power Service Corporation's Cardinal Station Unit 1.

190

Catalytic Reactor For Oxidizing Mercury Vapor  

DOE Patents [OSTI]

A catalytic reactor (10) for oxidizing elemental mercury contained in flue gas is provided. The catalyst reactor (10) comprises within a flue gas conduit a perforated corona discharge plate (30a, b) having a plurality of through openings (33) and a plurality of projecting corona discharge electrodes (31); a perforated electrode plate (40a, b, c) having a plurality of through openings (43) axially aligned with the through openings (33) of the perforated corona discharge plate (30a, b) displaced from and opposing the tips of the corona discharge electrodes (31); and a catalyst member (60a, b, c, d) overlaying that face of the perforated electrode plate (40a, b, c) opposing the tips of the corona discharge electrodes (31). A uniformly distributed corona discharge plasma (1000) is intermittently generated between the plurality of corona discharge electrode tips (31) and the catalyst member (60a, b, c, d) when a stream of flue gas is passed through the conduit. During those periods when corona discharge (1000) is not being generated, the catalyst molecules of the catalyst member (60a, b, c, d) adsorb mercury vapor contained in the passing flue gas. During those periods when corona discharge (1000) is being generated, ions and active radicals contained in the generated corona discharge plasma (1000) desorb the mercury from the catalyst molecules of the catalyst member (60a, b, c, d), oxidizing the mercury in virtually simultaneous manner. The desorption process regenerates and activates the catalyst member molecules.

Helfritch, Dennis J. (Baltimore, MD)

1998-07-28T23:59:59.000Z

191

Mercury-Related Materials Studies  

E-Print Network [OSTI]

Mercury-Related Materials Studies Van Graves IDS NF Ph M tiIDS-NF Phone Meeting Jan 26, 2010 #12 Evaluation of Cavitation Resistance of Type 316LN Stainless Steel in Mercury Using a Vibratory Horn," J. Nucl Pump Impeller Materials for Mercury Service at the Spallation Neutron Source," Oak Ridge National

McDonald, Kirk

192

Bioaccumulation of Mercury in Sharks  

E-Print Network [OSTI]

Bioaccumulation of Mercury in Sharks Part 2 a Using a subset of data collected on RJD shark research trips, you will analyze the mercury levels found in the Florida Sharks we catch. Based on your analysis, you will be able to conclude which species have the highest levels of mercury contamination

Miami, University of

193

Bioaccumulation of Mercury in Sharks  

E-Print Network [OSTI]

Resources: EPA General Info on Mercury - http://www.epa.gov/mercury/about.htm FDA Mercury Levels in Seafood - http://www.fda.gov/Food/GuidanceRegulation/GuidanceDocumentsRegulatoryInformation/ Seafood/ucm092041/en/index.html Monterey Bay Aquarium Sustainable Seafood Guide - http://www.montereybayaquarium.org/cr/Seafood

Miami, University of

194

Gas Mileage of 1994 Vehicles by Mercury  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

4 Mercury Vehicles 4 Mercury Vehicles EPA MPG MODEL City Comb Hwy 1994 Mercury Capri 4 cyl, 1.6 L, Automatic 4-spd, Regular Gasoline Compare 1994 Mercury Capri 20 City 21 Combined 24 Highway 1994 Mercury Capri 4 cyl, 1.6 L, Manual 5-spd, Regular Gasoline Compare 1994 Mercury Capri 21 City 23 Combined 26 Highway 1994 Mercury Capri 4 cyl, 1.6 L, Manual 5-spd, Regular Gasoline Compare 1994 Mercury Capri 22 City 24 Combined 28 Highway 1994 Mercury Cougar 6 cyl, 3.8 L, Automatic 4-spd, Regular Gasoline Compare 1994 Mercury Cougar 17 City 19 Combined 24 Highway 1994 Mercury Cougar 8 cyl, 4.6 L, Automatic 4-spd, Regular Gasoline Compare 1994 Mercury Cougar 16 City 18 Combined 23 Highway 1994 Mercury Grand Marquis 8 cyl, 4.6 L, Automatic 4-spd, Regular Gasoline Compare 1994 Mercury Grand Marquis 16

195

Gas Mileage of 1985 Vehicles by Mercury  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

5 Mercury Vehicles 5 Mercury Vehicles EPA MPG MODEL City Comb Hwy 1985 Mercury Capri 4 cyl, 2.3 L, Automatic 3-spd, Regular Gasoline Compare 1985 Mercury Capri 19 City 20 Combined 23 Highway 1985 Mercury Capri 4 cyl, 2.3 L, Manual 4-spd, Regular Gasoline Compare 1985 Mercury Capri 21 City 23 Combined 27 Highway 1985 Mercury Capri 6 cyl, 3.8 L, Automatic 3-spd, Regular Gasoline Compare 1985 Mercury Capri 17 City 18 Combined 20 Highway 1985 Mercury Capri 8 cyl, 5.0 L, Manual 5-spd, Regular Gasoline Compare 1985 Mercury Capri 15 City 17 Combined 22 Highway 1985 Mercury Capri 8 cyl, 5.0 L, Automatic 4-spd, Regular Gasoline Compare 1985 Mercury Capri 15 City 17 Combined 22 Highway 1985 Mercury Capri 4 cyl, 2.3 L, Automatic 3-spd, Regular Gasoline Compare 1985 Mercury Capri 18 City

196

NETL: Mercury Emissions Control Technologies - Oxidation of Mercury Across  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxidation of Mercury Across SCR Catalysts in Coal-Fired Power Plants Burning Low Rank Fuels Oxidation of Mercury Across SCR Catalysts in Coal-Fired Power Plants Burning Low Rank Fuels The objective of the proposed research is to assess the potential for the oxidation of mercury in flue gas across SCR catalysts in a coal fired power plant burning low rank fuels using a slipstream reactor containing multiple commercial catalysts in parallel. Results from the project will contribute to a greater understanding of mercury behavior across SCR catalysts. Additional tasks include: review existing pilot and field data on mercury oxidation across SCR catalysts and propose a mechanism for mercury oxidation and create a simple computer model for mercury oxidation based on the hypothetical mechanism. Related Papers and Publications: Final Report - December 31, 2004 [PDF-532KB]

197

Water displacement mercury pump  

DOE Patents [OSTI]

A water displacement mercury pump has a fluid inlet conduit and diffuser, a valve, a pressure cannister, and a fluid outlet conduit. The valve has a valve head which seats in an opening in the cannister. The entire assembly is readily insertable into a process vessel which produces mercury as a product. As the mercury settles, it flows into the opening in the cannister displacing lighter material. When the valve is in a closed position, the pressure cannister is sealed except for the fluid inlet conduit and the fluid outlet conduit. Introduction of a lighter fluid into the cannister will act to displace a heavier fluid from the cannister via the fluid outlet conduit. The entire pump assembly penetrates only a top wall of the process vessel, and not the sides or the bottom wall of the process vessel. This insures a leak-proof environment and is especially suitable for processing of hazardous materials.

Nielsen, Marshall G. (Woodside, CA)

1985-01-01T23:59:59.000Z

198

SULFUR POLYMER STABILIZATION/SOLIDIFICATION (SPSS) TREATABILITY OF LOS ALAMOS NATIONAL LABORATORY MERCURY WASTE.  

SciTech Connect (OSTI)

Brookhaven National Laboratory's Sulfur Polymer Stabilization/Solidification (SPSS) process was used to treat approximately 90kg of elemental mercury mixed waste from Los Alamos National Laboratory. Treatment was carried out in a series of eight batches using a 1 ft{sup 3} pilot-scale mixer, where mercury loading in each batch was 33.3 weight percent. Although leach performance is currently not regulated for amalgamated elemental mercury (Hg) mixed waste, Toxicity Characteristic Leach Procedure (TCLP) testing of SPSS treated elemental mercury waste indicates that leachability is readily reduced to below the TCLP limit of 200 ppb (regulatory requirement following treatment by retort for wastes containing > 260 ppb Hg), and with process optimization, to levels less than the stringent Universal Treatment Standard (UTS) limit of 25 ppb that is applied to waste containing < 260 ppm Hg. In addition, mercury-contaminated debris, consisting of primary glass and plastic containers, as well as assorted mercury thermometers, switches, and labware, was first reacted with SPSS components to stabilize the mercury contamination, then macroencapsulated in the molten SPSS product. This treatment was done by vigorous agitation of the sulfur polymer powder and the comminuted debris. Larger plastic and metal containers were reacted to stabilize internal mercury contamination, and then filled with molten sulfur polymer to encapsulate the treated product.

ADAMS,J.W.; KALB,P.D.

2001-11-01T23:59:59.000Z

199

Mercury Vapor | Open Energy Information  

Open Energy Info (EERE)

Mercury Vapor Mercury Vapor Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Mercury Vapor Details Activities (23) Areas (23) Regions (0) NEPA(0) Exploration Technique Information Exploration Group: Lab Analysis Techniques Exploration Sub Group: Fluid Lab Analysis Parent Exploration Technique: Fluid Lab Analysis Information Provided by Technique Lithology: Stratigraphic/Structural: Anomalously high concentrations can indicate high permeability or conduit for fluid flow Hydrological: Field wide soil sampling can generate a geometrical approximation of fluid circulation Thermal: High concentration in soils can be indicative of active hydrothermal activity Dictionary.png Mercury Vapor: Mercury is discharged as a highly volatile vapor during hydrothermal

200

MERCURY EMISSIONS FROM A SIMULATED IN-SITU OIL SHALE RETORT  

E-Print Network [OSTI]

from a Simulated In-Situ Oil Shale J. P. Fox, J. J. Duvall,of elements in rich oil shales of the Green River Formation,V. E . 1977; Mercury in Oil Shale from the Mahogany Zone

Fox, J. P.

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mercury trace elements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

E-Print Network 3.0 - arsenic antimony mercury Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

32. Nickel 7. Tantalum 20. Lead 33. Lithium 8. Arsenic 21... 12. Cesium 25. Mercury 13. Curium 26. Germanium 14. Zinc 27. Boron Short list for anagram element Source: Le Roy,...

202

Gas Mileage of 1986 Vehicles by Mercury  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

6 Mercury Vehicles 6 Mercury Vehicles EPA MPG MODEL City Comb Hwy 1986 Mercury Capri 4 cyl, 2.3 L, Automatic 3-spd, Regular Gasoline Compare 1986 Mercury Capri 18 City 20 Combined 23 Highway 1986 Mercury Capri 4 cyl, 2.3 L, Manual 4-spd, Regular Gasoline Compare 1986 Mercury Capri 21 City 23 Combined 26 Highway 1986 Mercury Capri 6 cyl, 3.8 L, Automatic 3-spd, Regular Gasoline Compare 1986 Mercury Capri 17 City 19 Combined 22 Highway 1986 Mercury Capri 8 cyl, 5.0 L, Automatic 4-spd, Regular Gasoline Compare 1986 Mercury Capri 15 City 18 Combined 24 Highway 1986 Mercury Capri 8 cyl, 5.0 L, Manual 5-spd, Regular Gasoline Compare 1986 Mercury Capri View MPG Estimates Shared By Vehicle Owners 15 City 18 Combined 23 Highway 1986 Mercury Cougar 4 cyl, 2.3 L, Automatic 3-spd, Regular Gasoline

203

Gas Mileage of 1991 Vehicles by Mercury  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

1 Mercury Vehicles 1 Mercury Vehicles EPA MPG MODEL City Comb Hwy 1991 Mercury Capri 4 cyl, 1.6 L, Automatic 4-spd, Regular Gasoline Compare 1991 Mercury Capri 21 City 22 Combined 24 Highway 1991 Mercury Capri 4 cyl, 1.6 L, Manual 5-spd, Regular Gasoline Compare 1991 Mercury Capri View MPG Estimates Shared By Vehicle Owners 21 City 23 Combined 26 Highway 1991 Mercury Capri 4 cyl, 1.6 L, Manual 5-spd, Regular Gasoline Compare 1991 Mercury Capri 22 City 24 Combined 28 Highway 1991 Mercury Cougar 6 cyl, 3.8 L, Automatic 4-spd, Regular Gasoline Compare 1991 Mercury Cougar 17 City 20 Combined 24 Highway 1991 Mercury Cougar 8 cyl, 5.0 L, Automatic 4-spd, Regular Gasoline Compare 1991 Mercury Cougar View MPG Estimates Shared By Vehicle Owners 16 City 18 Combined 22 Highway 1991 Mercury Grand Marquis 8 cyl, 5.0 L, Automatic 4-spd, Regular Gasoline

204

Direct Measurement of Mercury Reactions In Coal Power Plant Plumes  

SciTech Connect (OSTI)

Recent field and pilot-scale results indicate that divalent mercury emitted from power plants may rapidly transform to elemental mercury within the power plant plumes. Simulations of mercury chemistry in plumes based on measured rates to date have improved regional model fits to Mercury Deposition Network wet deposition data for particular years, while not degrading model verification fits for remaining years of the ensemble. The years with improved fit are those with simulated deposition in grid cells in the State of Pennsylvania that have matching MDN station data significantly less than the model values. This project seeks to establish a full-scale data basis for whether or not significant reduction or oxidation reactions occur to mercury emitted from coal-fired power plants, and what numerical redox rate should apply for extension to other sources and for modeling of power plant mercury plumes locally, regionally, and nationally. Although in-stack mercury (Hg) speciation measurements are essential to the development of control technologies and to provide data for input into atmospheric fate and transport models, the determination of speciation in a cooling coal combustion plume is more relevant for use in estimating Hg fate and effects through the atmosphere. It is mercury transformations that may occur in the plume that determine the eventual rate and patterns of mercury deposited to the earth's surface. A necessary first step in developing a supportable approach to modeling any such transformations is to directly measure the forms and concentrations of mercury from the stack exit downwind to full dispersion in the atmosphere. As a result, a study was sponsored by EPRI and jointly funded by EPRI, the U.S Department of Energy (DOE), and the Wisconsin Department of Administration. The study was designed to further our understanding of plume chemistry. The study was carried out at the We Energies Pleasant Prairie Power Plant, Pleasant Prairie, Wisconsin, just west of Kenosha. Aircraft and ground measurements support the occurrence of a reduction in the fraction of reactive gaseous mercury (RGM) (with a corresponding increase in elemental mercury) as part of the Total Gaseous Mercury (TGM) emitted from the Pleasant Prairie stack. This occurrence is based on comparison of the RGM concentrations in the plume (at standard conditions) compared to the RGM in the stack. There was found to be a 44% drop in the fraction of RGM between the stack exit and the first sampling arc and a 66% reduction from the stack to the 5-mile sampling arc, with no additional drop between the 5- and 10-mile arcs. Smaller-scale experiments in both test chambers and pilot-scale coal combustor exhaust streams have indicated the presence of rapid and relatively complete reduction reactions converting divalent into elemental mercury within power plant plumes prior to full dispersion in the atmosphere. These measurements, however, have been unable to identify whether the reactions occur during plume rise from physical to virtual stack height (during positive thermal buoyancy). The presence, rate, completeness, ubiquity, and dependence on source characteristics of these reactions, however, must be demonstrated in plume environments associated with fully operational power plants. That requirement, to capture either the reactions or the reaction products of chemistry that may be occurring very close to stack exits in highly turbulent environments, constrains the precision and reproducibility with which such full-scale experiments can be carried out. The work described here is one of several initial steps required to test whether, and in what direction, such rapid mercury redox reactions might be occurring in such plumes.

Leonard Levin

2005-12-31T23:59:59.000Z

205

Accretionary wedge harzburgite serpentinization and rodingitization constrained by perovskite U/Pb SIMS age, trace elements and Sm/Nd isotopes: Case study from the Western Carpathians, Slovakia  

Science Journals Connector (OSTI)

Abstract Perovskite-bearing harzburgites occur in a mlange type blueschist-bearing accretionary wedge complex of the Inner Western Carpathians Meliata Unit in Slovakia. Although dark rounded, slightly hydrated relic cores of harzburgite boulders are perovskite-free, perovskite (Prv) occurrence in the surrounding serpentinites and rodingites enabled dating of hydration, resulting in two metamorphicmetasomatic Prv generations. Perovskite (1) grows parallel to relic clinopyroxene exsolution lamellae or forms randomly oriented grain clusters in serpentinized orthopyroxene (Opx1) porphyroclasts, often accompanied by tiny andradite lamellae clusters, or it is partly replaced by Ti-andradite. Perovskite crystallization indicates evolving rodingitization fluids pervading the boundary between the harzburgite cores and Prv-free serpentinite. This strictly limited occurrence of Prv (1) within a 1 to 20-cm across-zone implies slightly postponed Prv crystallization to serpentinization by LREE(Ce,La), Ca2+, Ti/Fe3+-enriched aqueous fluids. A grain scale metasomatic mechanism partitioned Ca and Ti from the host orthopyroxene porphyroclasts, spinel (Ti) and grain-boundary pervasive fluids to Prv. In contrast, Prv (2) occurs in a 1 to 3cm across chlorite-rich blackwall zone between hosting serpentinite and rodingite veins, thus indicating channelled rodingitization fluid flow and accompanying hydraulic fracturing. Here, Prv (2) is ingrown by chlorite and apatite. Part of this Prv (2) formed in a rodingite vein mineral assemblage composed of diopside, andradite, vesuvianite, epidote/zoisite, apatite and chlorite. Both perovskite 1 and 2 are replaced by pyrophanite along the grain rims and interiors; most likely via fluid-aided coupled dissolutionreprecipitation at increased SiFeMnAl element solubility in rodingitization fluids pervading serpentinized harzburgite. Both Prv generations, especially Prv (2), can be partly to almost totally replaced by (Ti-) Adr. Overgrowths of spinel by andradite are occasionally observed in contact zones between the serpentinites and rodingites. LA-ICP-MS study revealed strong depletion in LREE from Prv (1) to Prv (2), and a more typically positive Eu anomaly for Prv (2). Our spider diagram depicts relative enrichment in U, Nb, La, Ce, Pr, Nd, and decreased Rb, Ba, Th, Ta, Pb, Sr, Zr in both Prv generations. The U/Pb SIMS concordia ages of Prv (1) from 3 samples range from 1371Ma to 1351Ma, with a mean of 135.60.58Ma, while Prv (2) was dated at 133.75.4Ma. Such negligible age differences imply a relatively short-lived rodingitization event responsible for crystallization of both Prv generations. The 143Nd/144Nd mean value of Prv (1) is 0.5121530.000017 by LA-MC-ICP-MS, thus corresponding to the initial ?Nd(t=135)=?8.20.4 (math's mean). This suggests that the subducted and dehydrated continental crust was the main source of the interactive fluids which initiated serpentinization and rodingitization in the Neotethyan Meliatic accretionary wedge following closure of the MeliataHallstatt Triassic to Jurassic oceanic back-arc basin and the high-pressure metamorphism dated at ca. 160150Ma by 40Ar/39Ar.

Xian-Hua Li; Marin Puti; Yue-Heng Yang; Mat Koppa; Marian Dyda

2014-01-01T23:59:59.000Z

206

Mercury control in 2009  

SciTech Connect (OSTI)

Although activated carbon injection (ACI) has been proven to be effective for many configurations and is a preferred option at many plants sufficient quantities of powdered activated coking (PAC) must be available to meet future needs. The authors estimate that upcoming federal and state regulations will result in tripling the annual US demand for activated carbon to nearly 1.5 billion lb from approximately 450 million lb. Rapid expansion of US production capacity is required. Many PAC manufacturers are discussing expansion of their existing production capabilities. One company, ADA Carbon Solutions, is in the process of constructing the largest activated carbon facility in North America to meet the future demand for PAC as a sorbent for mercury control. Emission control technology development and commercialization is driven by regulation and legislation. Although ACI will not achieve > 90% mercury control at every plant, the expected required MACT legislation level, it offers promise as a low-cost primary mercury control technology option for many configurations and an important trim technology for others. ACI has emerged as the clear mercury-specific control option of choice, representing over 98% of the commercial mercury control system orders to date. As state regulations are implemented and the potential for a federal rule becomes more imminent, suppliers are continuing to develop technologies to improve the cost effectiveness and limit the balance of plant impacts associated with ACI and are developing additional PAC production capabilities to ensure that the industry's needs are met. The commercialisation of ACI is a clear example of industry, through the dedication of many individuals and companies with support from the DOE and EPRI, meeting the challenge of developing cost-effectively reducing emissions from coal-fired power plants. 7 refs., 1 fig.

Sjostrom, S.; Durham, M.; Bustard, J.; Martin, C. [ADA Environmental Solutions, Littleton, CO (United States)

2009-07-15T23:59:59.000Z

207

EVALUATION OF MERCURY EMISSIONS FROM COAL-FIRED FACILITIES WITH SCR AND FGD SYSTEMS  

SciTech Connect (OSTI)

CONSOL Energy Inc., Research & Development (CONSOL), with support from the U.S. Department of Energy, National Energy Technology Laboratory (DOE) and the Electric Power Research Institute (EPRI), is evaluating the effects of selective catalytic reduction (SCR) on mercury (Hg) capture in coal-fired plants equipped with an electrostatic precipitator (ESP)--wet flue gas desulfurization (FGD) combination or a spray dryer absorber--fabric filter (SDA-FF) combination. In this program CONSOL is determining mercury speciation and removal at 10 coal-fired facilities. The objectives are (1) to evaluate the effect of SCR on mercury capture in the ESP-FGD and SDA-FF combinations at coal-fired power plants, (2) evaluate the effect of catalyst degradation on mercury capture; (3) evaluate the effect of low load operation on mercury capture in an SCR-FGD system, and (4) collect data that could provide the basis for fundamental scientific insights into the nature of mercury chemistry in flue gas, the catalytic effect of SCR systems on mercury speciation and the efficacy of different FGD technologies for mercury capture. This document, the seventh in a series of topical reports, describes the results and analysis of mercury sampling performed on a 1,300 MW unit burning a bituminous coal containing three percent sulfur. The unit was equipped with an ESP and a limestone-based wet FGD to control particulate and SO2 emissions, respectively. At the time of sampling an SCR was not installed on this unit. Four sampling tests were performed in September 2003. Flue gas mercury speciation and concentrations were determined at the ESP outlet (FGD inlet), and at the stack (FGD outlet) using the Ontario Hydro method. Process stream samples for a mercury balance were collected to coincide with the flue gas measurements. The results show that the FGD inlet flue gas oxidized:elemental mercury ratio was roughly 2:1, with 66% oxidized mercury and 34% elemental mercury. Mercury removal, on a coal-to-stack basis, was 53%. The average Hg concentration in the stack flue gas was 4.09 {micro}g/m{sup 3}. The average stack mercury emission was 3.47 Ib/TBtu. The mercury material balance closures ranged from 87% to 108%, with an average of 97%. A sampling program similar to this one was performed on a similar unit (at the same plant) that was equipped with an SCR for NOx control. Comparison of the results from the two units show that the SCR increases the percentage of mercury that is in the oxidized form, which, in turn, lends to more of the total mercury being removed in the wet scrubber. The principal purpose of this work is to develop a better understanding of the potential mercury removal ''co-benefits'' achieved by NOx, and SO{sub 2} control technologies. It is expected that this data will provide the basis for fundamental scientific insights into the nature of mercury chemistry in flue gas, the catalytic effect of SCR systems on mercury speciation and the efficacy of different FGD technologies for mercury capture. Ultimately, this insight could help to design and operate SCR and FGD systems to maximize mercury removal.

J.A. Withum; S.C. Tseng; J.E. Locke

2005-11-01T23:59:59.000Z

208

Gas Mileage of 2002 Vehicles by Mercury  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2 Mercury Vehicles 2 Mercury Vehicles EPA MPG MODEL City Comb Hwy 2002 Mercury Cougar 4 cyl, 2.0 L, Manual 5-spd, Regular Gasoline Compare 2002 Mercury Cougar View MPG Estimates Shared By Vehicle Owners 21 City 24 Combined 31 Highway 2002 Mercury Cougar 6 cyl, 2.5 L, Automatic 4-spd, Regular Gasoline Compare 2002 Mercury Cougar 18 City 21 Combined 26 Highway 2002 Mercury Cougar 6 cyl, 2.5 L, Manual 5-spd, Regular Gasoline Compare 2002 Mercury Cougar 18 City 21 Combined 27 Highway 2002 Mercury Grand Marquis 8 cyl, 4.6 L, Automatic 4-spd, Regular Gasoline Compare 2002 Mercury Grand Marquis View MPG Estimates Shared By Vehicle Owners 15 City 18 Combined 23 Highway 2002 Mercury Mountaineer 2WD 6 cyl, 4.0 L, Automatic 5-spd, Regular Gasoline Compare 2002 Mercury Mountaineer 2WD 14 City

209

Gas Mileage of 1989 Vehicles by Mercury  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

9 Mercury Vehicles 9 Mercury Vehicles EPA MPG MODEL City Comb Hwy 1989 Mercury Cougar 6 cyl, 3.8 L, Automatic 4-spd, Regular Gasoline Compare 1989 Mercury Cougar View MPG Estimates Shared By Vehicle Owners 17 City 20 Combined 25 Highway 1989 Mercury Cougar 6 cyl, 3.8 L, Automatic 4-spd, Premium Gasoline Compare 1989 Mercury Cougar 15 City 17 Combined 21 Highway 1989 Mercury Cougar 6 cyl, 3.8 L, Manual 5-spd, Premium Gasoline Compare 1989 Mercury Cougar 15 City 18 Combined 22 Highway 1989 Mercury Grand Marquis 8 cyl, 5.0 L, Automatic 4-spd, Regular Gasoline Compare 1989 Mercury Grand Marquis View MPG Estimates Shared By Vehicle Owners 15 City 18 Combined 22 Highway 1989 Mercury Grand Marquis Wagon 8 cyl, 5.0 L, Automatic 4-spd, Regular Gasoline Compare 1989 Mercury Grand Marquis Wagon 15

210

Gas Mileage of 1993 Vehicles by Mercury  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

3 Mercury Vehicles 3 Mercury Vehicles EPA MPG MODEL City Comb Hwy 1993 Mercury Capri 4 cyl, 1.6 L, Automatic 4-spd, Regular Gasoline Compare 1993 Mercury Capri 20 City 21 Combined 24 Highway 1993 Mercury Capri 4 cyl, 1.6 L, Manual 5-spd, Regular Gasoline Compare 1993 Mercury Capri View MPG Estimates Shared By Vehicle Owners 21 City 23 Combined 26 Highway 1993 Mercury Capri 4 cyl, 1.6 L, Manual 5-spd, Regular Gasoline Compare 1993 Mercury Capri View MPG Estimates Shared By Vehicle Owners 22 City 24 Combined 28 Highway 1993 Mercury Cougar 6 cyl, 3.8 L, Automatic 4-spd, Regular Gasoline Compare 1993 Mercury Cougar 17 City 19 Combined 24 Highway 1993 Mercury Cougar 8 cyl, 5.0 L, Automatic 4-spd, Regular Gasoline Compare 1993 Mercury Cougar View MPG Estimates Shared By Vehicle Owners 15

211

Gas Mileage of 2008 Vehicles by Mercury  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

8 Mercury Vehicles 8 Mercury Vehicles EPA MPG MODEL City Comb Hwy 2008 Mercury Grand Marquis FFV 8 cyl, 4.6 L, Automatic 4-spd, Regular Gas or E85 Compare 2008 Mercury Grand Marquis FFV Gas 15 City 18 Combined 23 Highway E85 11 City 13 Combined 16 Highway 2008 Mercury Mariner 4WD 4 cyl, 2.3 L, Automatic 4-spd, Regular Gasoline Compare 2008 Mercury Mariner 4WD 19 City 21 Combined 24 Highway 2008 Mercury Mariner 4WD 6 cyl, 3.0 L, Automatic 4-spd, Regular Gasoline Compare 2008 Mercury Mariner 4WD View MPG Estimates Shared By Vehicle Owners 17 City 19 Combined 22 Highway 2008 Mercury Mariner FWD 4 cyl, 2.3 L, Automatic 4-spd, Regular Gasoline Compare 2008 Mercury Mariner FWD 20 City 22 Combined 26 Highway 2008 Mercury Mariner FWD 6 cyl, 3.0 L, Automatic 4-spd, Regular Gasoline Compare 2008 Mercury Mariner FWD

212

Gas Mileage of 1987 Vehicles by Mercury  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

7 Mercury Vehicles 7 Mercury Vehicles EPA MPG MODEL City Comb Hwy 1987 Mercury Cougar 6 cyl, 3.8 L, Automatic 4-spd, Regular Gasoline Compare 1987 Mercury Cougar 17 City 19 Combined 24 Highway 1987 Mercury Cougar 8 cyl, 5.0 L, Automatic 4-spd, Regular Gasoline Compare 1987 Mercury Cougar View MPG Estimates Shared By Vehicle Owners 16 City 19 Combined 24 Highway 1987 Mercury Grand Marquis 8 cyl, 5.0 L, Automatic 4-spd, Regular Gasoline Compare 1987 Mercury Grand Marquis View MPG Estimates Shared By Vehicle Owners 16 City 19 Combined 24 Highway 1987 Mercury Grand Marquis Wagon 8 cyl, 5.0 L, Automatic 4-spd, Regular Gasoline Compare 1987 Mercury Grand Marquis Wagon 16 City 19 Combined 24 Highway 1987 Mercury Lynx 4 cyl, 1.9 L, Automatic 3-spd, Regular Gasoline Compare 1987 Mercury Lynx 23

213

Gas Mileage of 1990 Vehicles by Mercury  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

90 Mercury Vehicles 90 Mercury Vehicles EPA MPG MODEL City Comb Hwy 1990 Mercury Cougar 6 cyl, 3.8 L, Automatic 4-spd, Premium Gasoline Compare 1990 Mercury Cougar 15 City 18 Combined 21 Highway 1990 Mercury Cougar 6 cyl, 3.8 L, Automatic 4-spd, Regular Gasoline Compare 1990 Mercury Cougar View MPG Estimates Shared By Vehicle Owners 17 City 20 Combined 24 Highway 1990 Mercury Cougar 6 cyl, 3.8 L, Manual 5-spd, Premium Gasoline Compare 1990 Mercury Cougar 15 City 18 Combined 22 Highway 1990 Mercury Grand Marquis 8 cyl, 5.0 L, Automatic 4-spd, Regular Gasoline Compare 1990 Mercury Grand Marquis View MPG Estimates Shared By Vehicle Owners 15 City 18 Combined 22 Highway 1990 Mercury Grand Marquis Wagon 8 cyl, 5.0 L, Automatic 4-spd, Regular Gasoline Compare 1990 Mercury Grand Marquis Wagon 15

214

Biosequence Similarity Search on the Mercury System  

E-Print Network [OSTI]

Biosequence Similarity Search on the Mercury System Praveen Krishnamurthy, Jeremy Buhler, Roger Chamberlain, Mark Franklin, Kwame Gyang, and Joseph Lancaster, "Biosequence Similarity Search on the Mercury on the Mercury System Praveen Krishnamurthy, Jeremy Buhler, Roger Chamberlain, Mark Franklin, Kwame Gyang

Chamberlain, Roger

215

Recovery of mercury from acid waste residues  

DOE Patents [OSTI]

Mercury can be recovered from nitric acid-containing fluids by reacting the fluid with aluminum metal to produce mercury metal, and then quenching the reactivity of the nitric acid prior to nitration of the mercury metal.

Greenhalgh, Wilbur O. (Richland, WA)

1989-01-01T23:59:59.000Z

216

Recovery of mercury from acid waste residues  

DOE Patents [OSTI]

Mercury can be recovered from nitric acid-containing fluids by reacting the fluid with aluminum metal to produce mercury metal, and thence quenching the reactivity of the nitric acid prior to nitration of the mercury metal. 1 fig.

Greenhalgh, W.O.

1987-02-27T23:59:59.000Z

217

Mercury Strategic Plan Outfall 200 Mercury Treatment Facility  

Office of Environmental Management (EM)

Partial LMR * Alpha-5 LMR & Bldg Characterization * S&M mercury removal * Hg waterfishsediment studies * Technology Development Plan * Debris treatability study * Fate and...

218

Mercury oxidation promoted by a selective catalytic reduction catalyst under simulated Powder River Basin coal combustion conditions  

SciTech Connect (OSTI)

A bench-scale reactor consisting of a natural gas burner and an electrically heated reactor housing a selective catalytic reduction (SCR) catalyst was constructed for studying elemental mercury (Hg{sup 0}) oxidation under SCR conditions. A low sulfur Powder River Basin (PRB) subbituminous coal combustion fly ash was injected into the entrained-flow reactor along with sulfur dioxide (SO{sub 2}), nitrogen oxides (NOx), hydrogen chloride (HCl), and trace Hg{sup 0}. Concentrations of Hg{sup 0} and total mercury (Hg) upstream and downstream of the SCR catalyst were measured using a Hg monitor. The effects of HCl concentration, SCR operating temperature, catalyst space velocity, and feed rate of PRB fly ash on Hg0 oxidation were evaluated. It was observed that HCl provides the source of chlorine for Hg{sup 0} oxidation under simulated PRB coal-fired SCR conditions. The decrease in Hg mass balance closure across the catalyst with decreasing HCl concentration suggests that transient Hg capture on the SCR catalyst occurred during the short test exposure periods and that the outlet speciation observed may not be representative of steady-state operation at longer exposure times. Increasing the space velocity and operating temperature of the SCR led to less Hg{sup 0} oxidized. Introduction of PRB coal fly ash resulted in slightly decreased outlet oxidized mercury (Hg{sup 2+}) as a percentage of total inlet Hg and correspondingly resulted in an incremental increase in Hg capture. The injection of ammonia (NH{sub 3}) for NOx reduction by SCR was found to have a strong effect to decrease Hg oxidation. The observations suggest that Hg{sup 0} oxidation may occur near the exit region of commercial SCR reactors. Passage of flue gas through SCR systems without NH{sub 3} injection, such as during the low-ozone season, may also impact Hg speciation and capture in the flue gas. 18 refs., 7 figs., 3 tabs.

Chun W. Lee; Shannon D. Serre; Yongxin Zhao; Sung Jun Lee; Thomas W. Hastings [U.S. Environmental Protection Agency, Research Triangle Park, NC (United States). Office of Research and Development, National Risk Management Research Laboratory

2008-04-15T23:59:59.000Z

219

BEHAVIOR OF MERCURY DURING DWPF CHEMICAL PROCESS CELL PROCESSING  

SciTech Connect (OSTI)

The Defense Waste Processing Facility has experienced significant issues with the stripping and recovery of mercury in the Chemical Processing Cell (CPC). The stripping rate has been inconsistent, often resulting in extended processing times to remove mercury to the required endpoint concentration. The recovery of mercury in the Mercury Water Wash Tank has never been high, and has decreased significantly since the Mercury Water Wash Tank was replaced after the seventh batch of Sludge Batch 5. Since this time, essentially no recovery of mercury has been seen. Pertinent literature was reviewed, previous lab-scale data on mercury stripping and recovery was examined, and new lab-scale CPC Sludge Receipt and Adjustment Tank (SRAT) runs were conducted. For previous lab-scale data, many of the runs with sufficient mercury recovery data were examined to determine what factors affect the stripping and recovery of mercury and to improve closure of the mercury material balance. Ten new lab-scale SRAT runs (HG runs) were performed to examine the effects of acid stoichiometry, sludge solids concentration, antifoam concentration, form of mercury added to simulant, presence of a SRAT heel, operation of the SRAT condenser at higher than prototypic temperature, varying noble metals from none to very high concentrations, and higher agitation rate. Data from simulant runs from SB6, SB7a, glycolic/formic, and the HG tests showed that a significant amount of Hg metal was found on the vessel bottom at the end of tests. Material balance closure improved from 12-71% to 48-93% when this segregated Hg was considered. The amount of Hg segregated as elemental Hg on the vessel bottom was 4-77% of the amount added. The highest recovery of mercury in the offgas system generally correlated with the highest retention of Hg in the slurry. Low retention in the slurry (high segregation on the vessel bottom) resulted in low recovery in the offgas system. High agitation rates appear to result in lower retention of mercury in the slurry. Both recovery of mercury in the offgas system and removal (segregation + recovery) from the slurry correlate with slurry consistency. Higher slurry consistency results in better retention of Hg in the slurry (less segregation) and better recovery in the offgas system, but the relationships of recovery and retention with consistency are sludge dependent. Some correlation with slurry yield stress and acid stoichiometry was also found. Better retention of mercury in the slurry results in better recovery in the offgas system because the mercury in the slurry is stripped more easily than the segregated mercury at the bottom of the vessel. Although better retention gives better recovery, the time to reach a particular slurry mercury content (wt%) is longer than if the retention is poorer because the segregation is faster. The segregation of mercury is generally a faster process than stripping. The stripping factor (mass of water evaporated per mass of mercury stripped) of mercury at the start of boiling were found to be less than 1000 compared to the assumed design basis value of 750 (the theoretical factor is 250). However, within two hours, this value increased to at least 2000 lb water per lb Hg. For runs with higher mercury recovery in the offgas system, the stripping factor remained around 2000, but runs with low recovery had stripping factors of 4000 to 40,000. DWPF data shows similar trends with the stripping factor value increasing during boiling. These high values correspond to high segregation and low retention of mercury in the sludge. The stripping factor for a pure Hg metal bead in water was found to be about 10,000 lb/lb. About 10-36% of the total Hg evaporated in a SRAT cycle was refluxed back to the SRAT during formic acid addition and boiling. Mercury is dissolved as a result of nitric acid formation from absorption of NO{sub x}. The actual solubility of dissolved mercury in the acidic condensate is about 100 times higher than the actual concentrations measured. Mercury metal present in the MWWT from previous batch

Zamecnik, J.; Koopman, D.

2012-04-09T23:59:59.000Z

220

Advanced Gasification Mercury/Trace Metal Control With Monolith Traps  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Gasification Technologies Gasification Technologies CONTACTS Jenny Tennant Technology/Project Manager National Energy Technology Laboratory 3610 Collins Ferry Road P.O. Box 880, Morgantown, WV 26507-0880 304-285-4830 jenny.tennant@netl.doe.gov Michael Swanson Principal Investigator University of North Dakota Energy and Environmental Research Center 15 North 23rd Street Grand Forks, ND 58202 701-777-5239 MSwanson@undeerc.org PARTNERS Corning, Inc. PROJECT DURATION

Note: This page contains sample records for the topic "mercury trace elements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Neutrino Factory Mercury Flow Loop  

E-Print Network [OSTI]

Neutrino Factory Mercury Flow Loop V. GravesV. Graves C. Caldwell IDS-NF Videoconference March 9, 2010 #12;Flow Loop Review · 1 cm dia nozzle, 20 m/s jet requires 1.57 liter/sec mercury flow (94 2 liter/min 24 9 gpm)mercury flow (94.2 liter/min, 24.9 gpm). · MERIT experiment showed that a pump

McDonald, Kirk

222

Category:Mercury Vapor | Open Energy Information  

Open Energy Info (EERE)

search GEOTHERMAL ENERGYGeothermal Home Geothermalpower.jpg Looking for the Mercury Vapor page? For detailed information on Mercury Vapor as exploration techniques,...

223

Mercury Detection with Gold Nanoparticles  

E-Print Network [OSTI]

samples by cold vapor-atomic absorption spectrometry, J.S. Gucer, Direct atomic absorption determination of mercuryL. A. Vasilieva, Direct atomic absorption determination of

Crosby, Jeffrey

2013-01-01T23:59:59.000Z

224

Magnetoacoustic Effect in Mercury  

Science Journals Connector (OSTI)

Geometric resonances in the ultrasonic attenuations have been observed in high-purity mercury single crystals with longitudinal sound waves propagated along five crystallographic directions at frequencies up to 165 MHz. Of the five, only data for the (110), (110), and (112) directions are reported. The dominant resonance branches have been assigned to calipers of the second-band electron-lens surface, with three major symmetry calipers being obtained. The remainder of the resonance branches have been assigned to orbits on the first-band hole surface. Various breakthrough dimensions of the hole surface were determined from these orbits. The pseudopotential coefficients corresponding to the planes bounding the first Brillouin zone in mercury have been estimated by comparing the geometric resonance data with the results of a fourpseudowave calculation neglecting spin-orbit coupling.

Tommy E. Bogle; Julian B. Coon; Claude G. Grenier

1969-01-15T23:59:59.000Z

225

Apparatus for mercury refinement  

DOE Patents [OSTI]

The effluent from mercury collected during the photochemical separation of the [sup 196]Hg isotope is often contaminated with particulate mercurous chloride, Hg[sub 2]Cl[sub 2]. The use of mechanical filtering via thin glass tubes, ultrasonic rinsing with acetone (dimethyl ketone) and a specially designed cold trap have been found effective in removing the particulate (i.e., solid) Hg[sub 2]Cl[sub 2] contaminant. The present invention is particularly directed to such filtering. 5 figures.

Grossman, M.W.; Speer, R.; George, W.A.

1991-07-16T23:59:59.000Z

226

Method for mercury refinement  

DOE Patents [OSTI]

The effluent from mercury collected during the photochemical separation of the [sup 196]Hg isotope is often contaminated with particulate mercurous chloride, Hg[sub 2]Cl[sub 2]. The use of mechanical filtering via thin glass tubes, ultrasonic rinsing with acetone (dimethyl ketone) and a specially designed cold trap have been found effective in removing the particulate (i.e., solid) Hg[sub 2]Cl[sub 2] contaminant. The present invention is particularly directed to such filtering. 5 figures.

Grossman, M.W.; Speer, R.; George, W.A.

1991-04-09T23:59:59.000Z

227

Trace elements in zooplankton particulate products  

Science Journals Connector (OSTI)

... the Martin and Knauer4 method. Samples along with appropriate blanks and standards were analysed by flameless or flame atomic absorption spectro-photometry10 and instrumental neutron activation11.

SCOTT W. FOWLER

1977-09-01T23:59:59.000Z

228

Trace Element and Isotopic Fluxes/ Subducted Slab  

E-Print Network [OSTI]

MODELS OF SUBDUCTION 5 3.20.4 EARLY-STAGE PROCESSING OF SEDIMENTS AND PORE WATERS IN TRENCH AND SHALLOW FOREARC SETTINGS (Early Subduction Chemistries of HP and UHP Suites 28 3.20.5.10 Forearc to Subarc: Summary and Outstanding Questions 30 3

Bebout, Gray E.

229

Role of Trace Elements in Cancer  

Science Journals Connector (OSTI)

...from less than 30 @zg/g,wet weight, to 170 and 50 to 460...were observed in 5 patients in corn plete remission, and values...may be introduced during the milling process. It has been suggested...manganese (1.5 2 @g/g,wet weight) and manganese isprimarily...

Morton K. Schwartz

1975-11-01T23:59:59.000Z

230

Trace element analysis of Texas lignite  

E-Print Network [OSTI]

or in the planning stages, Near surface lignite re- sources are estimated to be 21 billion metric tons in Texas, while deep basin reserves are estimated at 31 billion metric tons. Near (3] surface reserves alone could fulfill Texas' electrical needs for 100 years... or in the planning stages, Near surface lignite re- sources are estimated to be 21 billion metric tons in Texas, while deep basin reserves are estimated at 31 billion metric tons. Near (3] surface reserves alone could fulfill Texas' electrical needs for 100 years...

Mahar, Sean

2012-06-07T23:59:59.000Z

231

Gas Mileage of 2000 Vehicles by Mercury  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2000 Mercury Vehicles 2000 Mercury Vehicles EPA MPG MODEL City Comb Hwy 2000 Mercury Cougar 4 cyl, 2.0 L, Manual 5-spd, Regular Gasoline Compare 2000 Mercury Cougar 21 City 25 Combined 31 Highway 2000 Mercury Cougar 6 cyl, 2.5 L, Automatic 4-spd, Regular Gasoline Compare 2000 Mercury Cougar View MPG Estimates Shared By Vehicle Owners 18 City 21 Combined 26 Highway 2000 Mercury Cougar 6 cyl, 2.5 L, Manual 5-spd, Regular Gasoline Compare 2000 Mercury Cougar View MPG Estimates Shared By Vehicle Owners 18 City 21 Combined 26 Highway 2000 Mercury Grand Marquis 8 cyl, 4.6 L, Automatic 4-spd, Regular Gasoline Compare 2000 Mercury Grand Marquis View MPG Estimates Shared By Vehicle Owners 16 City 18 Combined 23 Highway 2000 Mercury Mountaineer 2WD 6 cyl, 4.0 L, Automatic 5-spd, Regular Gasoline

232

Gas Mileage of 2004 Vehicles by Mercury  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

4 Mercury Vehicles 4 Mercury Vehicles EPA MPG MODEL City Comb Hwy 2004 Mercury Grand Marquis 8 cyl, 4.6 L, Automatic 4-spd, Regular Gasoline Compare 2004 Mercury Grand Marquis View MPG Estimates Shared By Vehicle Owners 15 City 18 Combined 23 Highway 2004 Mercury Marauder 8 cyl, 4.6 L, Automatic 4-spd, Premium Gasoline Compare 2004 Mercury Marauder View MPG Estimates Shared By Vehicle Owners 15 City 17 Combined 21 Highway 2004 Mercury Monterey Wagon FWD 6 cyl, 4.2 L, Automatic 4-spd, Regular Gasoline Compare 2004 Mercury Monterey Wagon FWD View MPG Estimates Shared By Vehicle Owners 15 City 17 Combined 21 Highway 2004 Mercury Mountaineer 2WD 8 cyl, 4.6 L, Automatic 5-spd, Regular Gasoline Compare 2004 Mercury Mountaineer 2WD 13 City 15 Combined 18 Highway 2004 Mercury Mountaineer 2WD 6 cyl, 4.0 L, Automatic 5-spd, Regular Gasoline

233

Gas Mileage of 1997 Vehicles by Mercury  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

7 Mercury Vehicles 7 Mercury Vehicles EPA MPG MODEL City Comb Hwy 1997 Mercury Cougar 6 cyl, 3.8 L, Automatic 4-spd, Regular Gasoline Compare 1997 Mercury Cougar View MPG Estimates Shared By Vehicle Owners 16 City 19 Combined 24 Highway 1997 Mercury Cougar 8 cyl, 4.6 L, Automatic 4-spd, Regular Gasoline Compare 1997 Mercury Cougar View MPG Estimates Shared By Vehicle Owners 15 City 18 Combined 23 Highway 1997 Mercury Grand Marquis 8 cyl, 4.6 L, Automatic 4-spd, Regular Gasoline Compare 1997 Mercury Grand Marquis View MPG Estimates Shared By Vehicle Owners 15 City 18 Combined 23 Highway 1997 Mercury Mountaineer 2WD 8 cyl, 5.0 L, Automatic 4-spd, Regular Gasoline Compare 1997 Mercury Mountaineer 2WD View MPG Estimates Shared By Vehicle Owners 12 City 14 Combined 17 Highway 1997 Mercury Mountaineer 4WD 8 cyl, 5.0 L, Automatic 4-spd, Regular Gasoline

234

Gas Mileage of 1995 Vehicles by Mercury  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

5 Mercury Vehicles 5 Mercury Vehicles EPA MPG MODEL City Comb Hwy 1995 Mercury Cougar 6 cyl, 3.8 L, Automatic 4-spd, Regular Gasoline Compare 1995 Mercury Cougar 17 City 19 Combined 24 Highway 1995 Mercury Cougar 8 cyl, 4.6 L, Automatic 4-spd, Regular Gasoline Compare 1995 Mercury Cougar View MPG Estimates Shared By Vehicle Owners 15 City 18 Combined 23 Highway 1995 Mercury Grand Marquis 8 cyl, 4.6 L, Automatic 4-spd, Regular Gasoline Compare 1995 Mercury Grand Marquis View MPG Estimates Shared By Vehicle Owners 15 City 18 Combined 23 Highway 1995 Mercury Mystique 4 cyl, 2.0 L, Automatic 4-spd, Regular Gasoline Compare 1995 Mercury Mystique View MPG Estimates Shared By Vehicle Owners 21 City 24 Combined 29 Highway 1995 Mercury Mystique 6 cyl, 2.5 L, Automatic 4-spd, Regular Gasoline

235

Gas Mileage of 2001 Vehicles by Mercury  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

1 Mercury Vehicles 1 Mercury Vehicles EPA MPG MODEL City Comb Hwy 2001 Mercury Cougar 4 cyl, 2.0 L, Manual 5-spd, Regular Gasoline Compare 2001 Mercury Cougar View MPG Estimates Shared By Vehicle Owners 21 City 24 Combined 31 Highway 2001 Mercury Cougar 6 cyl, 2.5 L, Automatic 4-spd, Regular Gasoline Compare 2001 Mercury Cougar View MPG Estimates Shared By Vehicle Owners 18 City 21 Combined 26 Highway 2001 Mercury Cougar 6 cyl, 2.5 L, Manual 5-spd, Regular Gasoline Compare 2001 Mercury Cougar View MPG Estimates Shared By Vehicle Owners 18 City 21 Combined 27 Highway 2001 Mercury Grand Marquis 8 cyl, 4.6 L, Automatic 4-spd, Regular Gasoline Compare 2001 Mercury Grand Marquis View MPG Estimates Shared By Vehicle Owners 16 City 18 Combined 23 Highway 2001 Mercury Mountaineer 2WD 6 cyl, 4.0 L, Automatic 5-spd, Regular Gasoline

236

Gas Mileage of 1998 Vehicles by Mercury  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

8 Mercury Vehicles 8 Mercury Vehicles EPA MPG MODEL City Comb Hwy 1998 Mercury Grand Marquis 8 cyl, 4.6 L, Automatic 4-spd, Regular Gasoline Compare 1998 Mercury Grand Marquis View MPG Estimates Shared By Vehicle Owners 15 City 18 Combined 22 Highway 1998 Mercury Mountaineer 2WD 6 cyl, 4.0 L, Automatic 5-spd, Regular Gasoline Compare 1998 Mercury Mountaineer 2WD View MPG Estimates Shared By Vehicle Owners 14 City 16 Combined 18 Highway 1998 Mercury Mountaineer 2WD 8 cyl, 5.0 L, Automatic 4-spd, Regular Gasoline Compare 1998 Mercury Mountaineer 2WD 12 City 14 Combined 17 Highway 1998 Mercury Mountaineer 4WD 6 cyl, 4.0 L, Automatic 5-spd, Regular Gasoline Compare 1998 Mercury Mountaineer 4WD View MPG Estimates Shared By Vehicle Owners 14 City 15 Combined 18 Highway 1998 Mercury Mountaineer 4WD 8 cyl, 5.0 L, Automatic 4-spd, Regular Gasoline

237

Gas Mileage of 2005 Vehicles by Mercury  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

5 Mercury Vehicles 5 Mercury Vehicles EPA MPG MODEL City Comb Hwy 2005 Mercury Grand Marquis 8 cyl, 4.6 L, Automatic 4-spd, Regular Gasoline Compare 2005 Mercury Grand Marquis View MPG Estimates Shared By Vehicle Owners 16 City 19 Combined 23 Highway 2005 Mercury Mariner 2WD 4 cyl, 2.3 L, Automatic 4-spd, Regular Gasoline Compare 2005 Mercury Mariner 2WD View MPG Estimates Shared By Vehicle Owners 19 City 21 Combined 24 Highway 2005 Mercury Mariner 2WD 6 cyl, 3.0 L, Automatic 4-spd, Regular Gasoline Compare 2005 Mercury Mariner 2WD View MPG Estimates Shared By Vehicle Owners 17 City 19 Combined 23 Highway 2005 Mercury Mariner 4WD 4 cyl, 2.3 L, Automatic 4-spd, Regular Gasoline Compare 2005 Mercury Mariner 4WD 17 City 19 Combined 21 Highway 2005 Mercury Mariner 4WD 6 cyl, 3.0 L, Automatic 4-spd, Regular Gasoline

238

Recent Approaches to Modeling Transport of Mercury in Surface Water and Groundwater - Case Study in Upper East Fork Poplar Creek, Oak Ridge, TN - 13349  

SciTech Connect (OSTI)

In this case study, groundwater/surface water modeling was used to determine efficacy of stabilization in place with hydrologic isolation for remediation of mercury contaminated areas in the Upper East Fork Poplar Creek (UEFPC) Watershed in Oak Ridge, TN. The modeling simulates the potential for mercury in soil to contaminate groundwater above industrial use risk standards and to contribute to surface water contamination. The modeling approach is unique in that it couples watershed hydrology with the total mercury transport and provides a tool for analysis of changes in mercury load related to daily precipitation, evaporation, and runoff from storms. The model also allows for simulation of colloidal transport of total mercury in surface water. Previous models for the watershed only simulated average yearly conditions and dissolved concentrations that are not sufficient for predicting mercury flux under variable flow conditions that control colloidal transport of mercury in the watershed. The transport of mercury from groundwater to surface water from mercury sources identified from information in the Oak Ridge Environmental Information System was simulated using a watershed scale model calibrated to match observed daily creek flow, total suspended solids and mercury fluxes. Mercury sources at the former Building 81-10 area, where mercury was previously retorted, were modeled using a telescopic refined mesh with boundary conditions extracted from the watershed model. Modeling on a watershed scale indicated that only source excavation for soils/sediment in the vicinity of UEFPC had any effect on mercury flux in surface water. The simulations showed that colloidal transport contributed 85 percent of the total mercury flux leaving the UEFPC watershed under high flow conditions. Simulation of dissolved mercury transport from liquid elemental mercury and adsorbed sources in soil at former Building 81-10 indicated that dissolved concentrations are orders of magnitude below a target industrial groundwater concentration beneath the source and would not influence concentrations in surface water at Station 17. This analysis addressed only shallow concentrations in soil and the shallow groundwater flow path in soil and unconsolidated sediments to UEFPC. Other mercury sources may occur in bedrock and transport though bedrock to UEFPC may contribute to the mercury flux at Station 17. Generally mercury in the source areas adjacent to the stream and in sediment that is eroding can contribute to the flux of mercury in surface water. Because colloidally adsorbed mercury can be transported in surface water, actions that trap colloids and or hydrologically isolate surface water runoff from source areas would reduce the flux of mercury in surface water. Mercury in soil is highly adsorbed and transport in the groundwater system is very limited under porous media conditions. (authors)

Bostick, Kent; Daniel, Anamary [Professional Project Services, Inc., Bethel Valley Road, Oak Ridge, TN, 37922 (United States)] [Professional Project Services, Inc., Bethel Valley Road, Oak Ridge, TN, 37922 (United States); Tachiev, Georgio [Florida International University, Applied Research Center 10555 W. Flagler St., EC 2100 Miami Florida 33174 (United States)] [Florida International University, Applied Research Center 10555 W. Flagler St., EC 2100 Miami Florida 33174 (United States); Malek-Mohammadi, Siamak [Bradley University, 413A Jobst Hall, Preoria, IL 61625 (United States)] [Bradley University, 413A Jobst Hall, Preoria, IL 61625 (United States)

2013-07-01T23:59:59.000Z

239

NETL: Mercury Emissions Control Technologies - Evaluation of Mercury  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Control Technology Evaluation of Mercury Emissions from Coal-Fired Facilities w/ SCR and FGD Systems Control Technology Evaluation of Mercury Emissions from Coal-Fired Facilities w/ SCR and FGD Systems CONSOL is evaluating the mercury removal co-benefits achieved by SCR-FGD combi nations. Specific issues that will be addressed include the effects of SCR, catalyst degradation, and load changes on mercury oxidation and capture. This objective will be achieved by measuring mercury removal achieved by SCR-FGD combinations at ten plants with such equipment configurations. These plants include five with wet limestone, three wet lime, and two with dry scrubbing. Material balance will be conducted. Related Papers and Publications: Final Report - April 2006 [PDF-377KB] Topical Report # 11 - January 2006 [PDF-19MB] Topical Report # 9 - January 2006 [PDF-6MB]

240

The removal of mercury from solid mixed waste using chemical leaching processes  

SciTech Connect (OSTI)

The focus of this research was to evaluate chemical leaching as a technique to treat soils, sediments, and glass contaminated with either elemental mercury or a combination of several mercury species. Potassium iodide/iodine solutions were investigated as chemical leaching agents for contaminated soils and sediments. Clean, synthetic soil material and surrogate storm sewer sediments contaminated with mercury were treated with KI/I{sub 2} solutions. It was observed that these leaching solutions could reduce the mercury concentration in soil and sediments by 99.8%. Evaluation of selected posttreatment sediment samples revealed that leachable mercury levels in the treated solids exceeded RCRA requirements. The results of these studies suggest that KI/I{sub 2} leaching is a treatment process that can be used to remove large quantities of mercury from contaminated soils and sediments and may be the only treatment required if treatment goals are established on Hg residual concentrations in solid matrices. Fluorescent bulbs were used to simulate mercury contaminated glass mixed waste. To achieve mercury contamination levels similar to those found in larger bulbs such as those used in DOE facilities a small amount of Hg was added to the crushed bulbs. The most effective agents for leaching mercury from the crushed fluorescent bulbs were KI/I{sub 2}, NaOCl, and NaBr + acid. Radionuclide surrogates were added to both the EPA synthetic soil material and the crushed fluorescent bulbs to determine the fate of radionuclides following chemical leaching with the leaching agents determined to be the most promising. These experiments revealed that although over 98% of the dosed mercury solubilized and was found in the leaching solution, no Cerium was measured in the posttreatment leaching solution. This finding suggest that Uranium, for which Ce was used as a surrogate, would not solubilize during leaching of mercury contaminated soil or glass.

Gates, D.D.; Chao, K.K.; Cameron, P.A.

1995-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "mercury trace elements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Bench-scale Kinetics Study of Mercury Reactions in FGD Liquors  

SciTech Connect (OSTI)

This document is the final report for Cooperative Agreement DE-FC26-04NT42314, 'Kinetics Study of Mercury Reactions in FGD Liquors'. The project was co-funded by the U.S. DOE National Energy Technology Laboratory and EPRI. The objective of the project has been to determine the mechanisms and kinetics of the aqueous reactions of mercury absorbed by wet flue gas desulfurization (FGD) systems, and develop a kinetics model to predict mercury reactions in wet FGD systems. The model may be used to determine optimum wet FGD design and operating conditions to maximize mercury capture in wet FGD systems. Initially, a series of bench-top, liquid-phase reactor tests were conducted and mercury species concentrations were measured by UV/visible light spectroscopy to determine reactant and byproduct concentrations over time. Other measurement methods, such as atomic absorption, were used to measure concentrations of vapor-phase elemental mercury, that cannot be measured by UV/visible light spectroscopy. Next, a series of bench-scale wet FGD simulation tests were conducted. Because of the significant effects of sulfite concentration on mercury re-emission rates, new methods were developed for operating and controlling the bench-scale FGD experiments. Approximately 140 bench-scale wet FGD tests were conducted and several unusual and pertinent effects of process chemistry on mercury re-emissions were identified and characterized. These data have been used to develop an empirically adjusted, theoretically based kinetics model to predict mercury species reactions in wet FGD systems. The model has been verified in tests conducted with the bench-scale wet FGD system, where both gas-phase and liquid-phase mercury concentrations were measured to determine if the model accurately predicts the tendency for mercury re-emissions. This report presents and discusses results from the initial laboratory kinetics measurements, the bench-scale wet FGD tests, and the kinetics modeling efforts.

Gary Blythe; John Currie; David DeBerry

2008-03-31T23:59:59.000Z

242

Thief process for the removal of mercury from flue gas  

DOE Patents [OSTI]

A system and method for removing mercury from the flue gas of a coal-fired power plant is described. Mercury removal is by adsorption onto a thermally activated sorbent produced in-situ at the power plant. To obtain the thermally activated sorbent, a lance (thief) is inserted into a location within the combustion zone of the combustion chamber and extracts a mixture of semi-combusted coal and gas. The semi-combusted coal has adsorptive properties suitable for the removal of elemental and oxidized mercury. The mixture of semi-combusted coal and gas is separated into a stream of gas and semi-combusted coal that has been converted to a stream of thermally activated sorbent. The separated stream of gas is recycled to the combustion chamber. The thermally activated sorbent is injected into the duct work of the power plant at a location downstream from the exit port of the combustion chamber. Mercury within the flue gas contacts and adsorbs onto the thermally activated sorbent. The sorbent-mercury combination is removed from the plant by a particulate collection system.

Pennline, Henry W. (Bethel Park, PA); Granite, Evan J. (Wexford, PA); Freeman, Mark C. (South Park Township, PA); Hargis, Richard A. (Canonsburg, PA); O'Dowd, William J. (Charleroi, PA)

2003-02-18T23:59:59.000Z

243

Mercury-Related Materials Studies  

E-Print Network [OSTI]

. Pawel, "Assessment of Cavitation-Erosion Resistance of Potential Pump Impeller Materials for MercuryMercury-Related Materials Studies Van Graves IDS NF Ph M tiIDS-NF Phone Meeting Jan 26, 2010 ­ updated Feb 3, 2010 #12;ORNL Material Reports Reviewed · IDS-NF requested ORNL research any past SNS

McDonald, Kirk

244

Stanford University Mercury Thermometer Replacement  

E-Print Network [OSTI]

Stanford University Mercury Thermometer Replacement Program Instructions for Reuniting Separated Fluid Column of Non-Mercury Thermometer Heating Method Heat the thermometers bulb in an upright position of the thermometer. Note that over filling the expansion chamber will break the thermometer. Tap the thermometer

245

RMP Mercury Strategy 06-03-09.doc Page 1 of 5 RMP MERCURY STRATEGY  

E-Print Network [OSTI]

RMP Mercury Strategy 06-03-09.doc Page 1 of 5 RMP MERCURY STRATEGY Mercury is a pollutant of high the information most urgently needed by managers to find remedies to the Bay's mercury problem. The focus of total mercury in the Bay are expected to slowly decline over coming decades. The premise

246

Mercury Speciation in the Presence of Polysulfides  

E-Print Network [OSTI]

Mercury Speciation in the Presence of Polysulfides J E N N Y A Y L A J A Y , * , F R A N C¸ O I Environmental mercury methylation appears modulated by sulfide concentrations, possibly via changes in mercury, there has been much recent interest in quantifying the chemical speciation and lipid solubility of mercury

Morel, François M. M.

247

Methods for dispensing mercury into devices  

DOE Patents [OSTI]

A process for dispensing mercury into devices which requires mercury. Mercury is first electrolytically separated from either HgO or Hg.sub.2 Cl.sub.2 and plated onto a cathode wire. The cathode wire is then placed into a device requiring mercury.

Grossman, Mark W. (Belmont, MA); George, William A. (Rockport, MA)

1987-04-28T23:59:59.000Z

248

Mercury and the Gold Country Angler Survey  

E-Print Network [OSTI]

#12;#12;Mercury and the Gold Rush #12;#12;#12;#12;#12;#12;#12;#12;#12;Gold Country Angler Survey A Pilot Study to Assess Mercury Exposure from Sport Fish Consumption in the Sierra Nevada Carrie Monohan, Ph.D. #12;Mercury and the Gold Rush Deer Creek 1908 Greenhorn Creek 2011 Mercury was used during

249

Methods for dispensing mercury into devices  

DOE Patents [OSTI]

A process is described for dispensing mercury into devices which requires mercury. Mercury is first electrolytically separated from either HgO or Hg[sub 2]Cl[sub 2] and plated onto a cathode wire. The cathode wire is then placed into a device requiring mercury. 2 figs.

Grossman, M.W.; George, W.A.

1987-04-28T23:59:59.000Z

250

Mercury Spill Information and Response Guidance  

E-Print Network [OSTI]

Mercury Spill Information and Response Guidance Background Information Mercury can be found, plumbing traps and vacuum pumps. When mercury is spilled, it forms beads or droplets that can accumulate mercury vapors can be very dangerous, depending on the amount inhaled and the length of exposure

Holland, Jeffrey

251

Collection of atomic mercury by electrostatic precipitators  

Science Journals Connector (OSTI)

... Flameless atomic absorption spectroscopy was used to measure the difference in the mercury concentration of gas ...

O. M. G. NEWMAN; D. J. PALMER

1978-10-12T23:59:59.000Z

252

Atmospheric Chemistry, Modeling, and Biogeochemistry of Mercury  

E-Print Network [OSTI]

activities that release mercury to the atmosphere include coal burning, industrial processes, waste incine

253

Mercury Isotope Fractionation by Environmental Transport and Transformation Processes  

E-Print Network [OSTI]

measurements of atomic mercury. Applied Physics B, 87(2),M. & Covelli, S. , 2000. Mercury speciation in sedimentsarea of the Idrija mercury mine, Slovenia. Environmental

Koster van Groos, Paul Gijsbert

2011-01-01T23:59:59.000Z

254

Mercury Vapor (Kooten, 1987) | Open Energy Information  

Open Energy Info (EERE)

Mercury Vapor (Kooten, 1987) Mercury Vapor (Kooten, 1987) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor (Kooten, 1987) Exploration Activity Details Location Unspecified Exploration Technique Mercury Vapor Activity Date Usefulness useful DOE-funding Unknown Notes Surface soil-mercury surveys are an inexpensive and useful exploration tool for geothermal resources. ---- Surface geochemical surveys for mercury were conducted in 16 areas in 1979-1981 by ARCO Oil and Gas Company as part of its geothermal evaluation program. Three techniques used together have proved satisfactory in evaluating surface mercury data. These are contouring, histograms and cumulative frequency plots of the data. Contouring geochemical data and constructing histograms are standard

255

THERMAL TECHNIQUES FOR THE IN-SITU CHARACTERIZATION AND REMEDIATION OF MERCURY: INSIGHTS FROM DEPLOYMENT OF THE MEMBRANE INTERFACE PROBE  

SciTech Connect (OSTI)

This presentation focuses on how thermal energy can effectively be used to enhance characterization, promote the remediation, and aid in delivering a sequestering agent to stabilize elemental mercury in subsurface soils. Slides and speaker notes are provided.

Jackson, Dennis; Looney, Brian; Eddy-Dilek, Carol A.

2013-08-07T23:59:59.000Z

256

Fluorescent sensor for mercury  

DOE Patents [OSTI]

The present invention provides a sensor for detecting mercury, comprising: a first polynucleotide, comprising a first region, and a second region, a second polynucleotide, a third polynucleotide, a fluorophore, and a quencher, wherein the third polynucleotide is optionally linked to the second region; the fluorophore is linked to the first polynucleotide and the quencher is linked to the second polynucleotide, or the fluorophore is linked to the second polynucleotide and the quencher is linked to the first polynucleotide; the first region and the second region hybridize to the second polynucleotide; and the second region binds to the third polynucleotide in the presence of Hg.sup.2+ ions.

Wang, Zidong (Urbana, IL); Lee, Jung Heon (Evanston, IL); Lu, Yi (Champaign, IL)

2011-11-22T23:59:59.000Z

257

Mercury (Hg) and methyl mercury (MMHg) bioaccumulation in three fish species (sea food) from Persian Gulf  

Science Journals Connector (OSTI)

In this study, mercury (Hg) and methyl mercury (MMHg) were determined in three fish species including benthic, benthopelagic and pelagic fish from Arvand river, northwest of Persian Gulf. Mercury and methyl mercu...

Sajad Abdolvand; Sahar Kayedinejad Esfahani

2014-09-01T23:59:59.000Z

258

EVALUATION OF MERCURY EMISSIONS FROM COAL-FIRED FACILITIES WITH SCR AND FGD SYSTEMS  

SciTech Connect (OSTI)

CONSOL Energy Inc., Research & Development (CONSOL), with support from the U.S. Department of Energy, National Energy Technology Laboratory (DOE) and the Electric Power Research Institute (EPRI), evaluated the effects of selective catalytic reduction (SCR) on mercury (Hg) capture in coal-fired plants equipped with an electrostatic precipitator (ESP)-wet flue gas desulfurization (FGD) combination or a spray dyer absorber-fabric filter (SDA-FF) combination. In this program CONSOL determined mercury speciation and removal at 10 bituminous coal-fired facilities; at four of these facilities, additional tests were performed on units without SCR, or with the existing SCR bypassed. This project final report summarizes the results and discusses the findings of the body of work as a whole. Eleven Topical Reports were issued (prior to this report) that describe in great detail the sampling results at each of the ten power plants individually. The results showed that the SCR-FGD combination removed a substantial fraction of mercury from flue gas. The coal-to-stack mercury removals ranged from 65% to 97% for the units with SCR and from 53% to 87% for the units without SCR. There was no indication that any type of FGD system was more effective at mercury removal than others. The coal-to-stack mercury removal and the removal in the wet scrubber were both negatively correlated with the elemental mercury content of the flue gas and positively correlated with the scrubber liquid chloride concentration. The coal chlorine content was not a statistically significant factor in either case. Mercury removal in the ESP was positively correlated with the fly ash carbon content and negatively correlated with the flue gas temperature. At most of the units, a substantial fraction (>35%) of the flue gas mercury was in the elemental form at the boiler economizer outlet. After passing through the SCR-air heater combination very little of the total mercury (<10%) remained in the elemental form in the flue gas; this was true for all SCR catalyst types and sources. Although chlorine has been suggested as a factor affecting the mercury speciation in flue gas, coal chlorine was not a statistically significant factor affecting mercury speciation at the economizer exit or at the air heater exit. The only statistically significant factors were the coal ash CaO content and the fly ash carbon content; the fraction of mercury in the elemental form at the economizer exit was positively correlated with both factors. In a direct comparison at four SCR-equipped units vs. similar units at the same sites without SCR (or with the SCR bypassed), the elemental mercury fractions (measured at the ESP outlet) were lower, and the coal-to-stack mercury removals were higher, when the SCR was present and operating. The average coal-to-stack mercury removal at the four units without an operating SCR was 72%, whereas the average removal at the same sites with operating SCRs was 88%. The unit mercury mass balance (a gauge of the overall quality of the tests) at all of the units ranged from 81% to 113%, which were within our QA/QC criterion of 80-120%.

J.A. Withum

2006-03-07T23:59:59.000Z

259

DIRECT MEASUREMENT OF MERCURY REACTIONS IN COAL POWER PLANT PLUMES  

SciTech Connect (OSTI)

This project was awarded under U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) Program Solicitation DE-PS26-02NT41422 and specifically addresses Program Area of Interest: No.5--Environmental and Water Resources. The project team includes the Electric Power Research Institute (EPRI) as the contractor and the University of North Dakota Energy & Environmental Research Center (EERC) and Frontier Geosciences as subcontractors. Wisconsin Energies and its Pleasant Prairie Power Plant acted as host for the field-testing portion of the research. The project is aimed at clarifying the role, rates, and end results of chemical transformations that may occur to mercury that has been emitted from elevated stacks of coal-fired electric power plants. Mercury emitted from power plants emerges in either its elemental, divalent, or particulate-bound form. Deposition of the divalent form is more likely to occur closer to the source than that of the other two forms, due to its solubility in water. Thus, if chemical transformations occur in the stack emissions plume, measurements in the stack may mischaracterize the fate of the material. Initial field and pilot plant measurements have shown significant and rapid chemical reduction of divalent to elemental mercury may occur in these plumes. Mercury models currently assume that the chemical form of mercury occurring in stacks is the same as that which enters the free atmosphere, with no alteration occurring in the emissions plume. Recent data indicate otherwise, but need to be evaluated at full operating scale under field conditions. Prestbo and others have demonstrated the likelihood of significant mercury chemical reactions occurring in power plant plumes (Prestbo et al., 1999; MDNR-PPRP, 2000; EERC, 2001). This experiment will thus increase our understanding of mercury atmospheric chemistry, allowing informed decisions regarding source attribution. The experiment was carried out during the period August 22-September 5, 2003. The experimental site was the Pleasant Prairie Power Plant in Pleasant Prairie, Wisconsin, just west of Kenosha. The experiment involved using an aircraft to capture emissions and document chemistry changes in the plume. While using the airplane for sampling, supplemental fast-response sensors for NOx, connected to data loggers, were used to gauge entry and exit times and transect intervals through plume emissions material. The Frontier Geosciences Static Plume Dilution Chamber (SPDC) was employed simultaneously adjacent to the stack to correlate its findings with the aircraft sampling, as well as providing evaluation of the SPDC as a rapid, less costly sampler for mercury chemistry. A complementary stack plume method, the Dynamic Plume Dilution (DPD) was used in the latter portion of the experiment to measure mercury speciation to observe any mercury reduction reaction with respect to both the reaction time (5 to 30 seconds) and dilution ratio. In addition, stack sampling using the ''Ontario Hydro'' wet chemistry method and continuous mercury monitors (CMM) were used to establish the baseline chemistry in the stack. Comparisons among stack, SPDC, DPD and aircraft measurements allow establishment of whether significant chemical changes to mercury occur in the plume, and of the verisimilitude of the SPDC and DPD methods. This progress report summarizes activities during a period of results review from the stack/aircraft subcontractor, data analysis and synthesis, and preparation and presentation of preliminary results to technical and oversight meetings.

Leonard Levin

2006-06-01T23:59:59.000Z

260

MESSENGER Observations of Magnetic Reconnection in Mercurys Magnetosphere  

Science Journals Connector (OSTI)

...Prague 14131, Czech Republic. Solar wind energy transfer to planetary magnetospheres...MP reconnection transfers solar wind energy into the magnetosphere, where...Mercury's magnetosphere. | Solar wind energy transfer to planetary magnetospheres...

James A. Slavin; Mario H. Acua; Brian J. Anderson; Daniel N. Baker; Mehdi Benna; Scott A. Boardsen; George Gloeckler; Robert E. Gold; George C. Ho; Haje Korth; Stamatios M. Krimigis; Ralph L. McNutt; Jr.; Jim M. Raines; Menelaos Sarantos; David Schriver; Sean C. Solomon; Pavel Trvn?ek; Thomas H. Zurbuchen

2009-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "mercury trace elements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Mercury's moment of inertia from spin and gravity data  

E-Print Network [OSTI]

2006), Evolution of Mercurys obliquity, Icarus, 181, 327longitude librations of Mercury, Icarus, 207, 11 of 11The free librations of Mercury and the size of its inner

2012-01-01T23:59:59.000Z

262

NETL: Mercury Emissions Control Technologies - Testing of Mercury Control  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Testing of Mercury Control with Calcium-Based Sorbents and Oxidizing Agents Testing of Mercury Control with Calcium-Based Sorbents and Oxidizing Agents Southern Research Institute, Birmingham, Alabama Subcontractor- ARCADIS Geraghty & Miller The overall goal of this project is to test the effectiveness of calcium-based sorbents and oxidizing agents for controlling mercury emissions from coal-fired power plant boilers. ARCADIS Geraghty & Miller, with EPA support, has developed calcium-based sorbents to remove SO2 and mercury simultaneously. The sorbents consist of hydrated lime (Ca(OH)2) and an added oxidant and a silica-modified calcium (CaSiO3) with an added oxidant. The mercury capacity in ug Hg/g sorbent for the two sorbents is 20 and 110-150, respectively, verses a mercury capacity for the current standard sorbent, activated carbon, of 70-100. The advantages of a lime based sorbent verses carbon is lower cost, simultaneous removal of sulfur, and allowance of ash to be utilized for a cement additive.

263

In situ mercury stabilization  

SciTech Connect (OSTI)

BNL Royalty Project Internal Status Report. The funds from the allotment of royalty income were used to experimentally explore feasibility of related, potential new techniques based on the Environmental Sciences Department successful technology licensed for the ex situ treatment of mercury. Specifically, this work is exploring the concept of using Sulfur Polymer Cement (SPC) in an in situ application to stabilize and/or remove mercury (Hg) from surficial soil. Patent disclosure forms have been filed for this process. Soil was artificially spiked with 500 ppm Hg and a series of experiments were set up in which SPC rods were placed in the center of a mass of this soil. Some experiments were conducted at 20 C and others at 50 C. After times ranging from 11 to 24 days, these experiments were opened, photographed and the soil was sampled from discrete locations in the containers. The soil and SPC samples were analyzed for Fe and Hg by x-ray fluorescence. The Hg profile in the soil was significantly altered, with concentrations along the outer edge of the soil reduced by as much as 80% from the starting concentration. Conversely, closer to the treatment rod containing SPC, concentrations of Hg were significantly increased over the original concentration. Preliminary results for elevated temperature sample are shown graphically in Figure 2. Apparently the Hg had migrated toward the SPC and reacted with sulfur to form Hg S. This appears to be a reaction between gaseous phases of both S and Hg, with Hg having a greater vapor pressure. The concentration of low solubility HgS (i.e., low leaching properties) developed within 11 days at 50 C and 21 days at 20 C, confirming the potential of this concept.

Fuhrmann, M.; Kalb, P.; Adams, J.

2004-09-01T23:59:59.000Z

264

Trace metal concentration in blood of the Kemp's ridley sea turtle (Lepidochelys kempii)  

E-Print Network [OSTI]

characterized the level of five trace metals in Kemp's ridleys and compared these levels in headstart and wild cohorts as well as between the sexes. Overall, copper, lead, mercury, silver and zinc levels in the blood of Kemp's ridleys were: copper (range = 215...

Orvik, Lisa Marie

1997-01-01T23:59:59.000Z

265

XAFS Investigation of Mercury Sorption on Carbon-based and Other Sorbent Materials  

Science Journals Connector (OSTI)

The sorption of mercury from simulated coal combustion flue gases on coal-derived chars, activated carbons, and zeolites has been examined using mercury LIII XAFS spectroscopy. The energy difference between the two inflection points (IPD) in the mercury XANES spectra has been shown to be a sensitive indicator of the local structure around the mercury adsorbed on the sorbent. The value of the IPD appears to reflect the form of mercury added to the flue gas and to be sensitive to acidic gaseous species such as HCl and H2SO4 that may be present in the flue gas, whether from addition to the flue gas or from the sulfur and chlorine in the coal. The data suggest that well-defined mercury species are not formed on carbon-based sorbents, but rather the structure and chemistry of the sorbed mercury species reflect the different anionic species present in the flue gas, as well as any activating element on the sorbent itself.

Frank E. Huggins; Nora Yap; Gerald P. Huffman

1999-01-01T23:59:59.000Z

266

Catalyst Additives to Enhance Mercury Oxidation and Capture  

SciTech Connect (OSTI)

Preliminary research has shown that SCR catalysts employed for nitrogen-oxide reduction can effectively oxidize mercury. This report discusses initial results from fundamental investigations into the behavior of mercury species in the presence of SCR catalysts at Southern Research Institute. The testing was performed at Southern Research's Catalyst Test Facility, a bench-scale reactor capable of simulating gas-phase reactions occurring in coal-fired utility pollution-control equipment. Three different SCR catalysts are currently being studied in this project--honeycomb-type, plate-type, and a hybrid-type catalyst. The catalysts were manufactured and supplied by Cormetech Inc., Hitachi America Ltd., and Haldor-Topsoe Inc., respectively. Parametric testing was performed to investigate the contribution of flue-gas chemistry on mercury oxidation via SCR catalysts. Methods and procedures for experimental testing continue to be developed to produce the highest quality mercury-oxidation data. During this past quarter, it was discovered that long periods (12 - 24 hours) are required to equilibrate the catalysts in the system. In addition, after the system has been equilibrated, operational changes to temperature, gas concentration, or flow rate shifts the equilibrium, and steady-state must be reestablished, which can require as much as twelve additional hours per condition change. In the last quarter of testing, it was shown that the inclusion of ammonia had a strong effect on the oxidation of mercury by SCR catalysts, both in the short-term (a transitional period of elemental and oxidized mercury off gassing) and the long-term (less steady-state mercury oxidation). All experiments so far have focused on testing the catalysts in a simulated Powder River Basin (PRB) flue-gas environment, which contains lower sulfur and chlorine than produced by other coals. In the next quarter, parametric testing will be expanded to include flue gases simulating power plants burning Midwestern and Eastern coals, which are higher in sulfur and chlorine. Also, the isolation of such gases as hydrogen chloride (HCl), ammonia (NH{sub 3}), and sulfur trioxide (SO{sub 3}) will be investigated. All of these efforts will be used to examine the kinetics of mercury oxidation across the SCR catalysts with respect to flue gas composition, temperature, and flow rate.

Jared W. Cannon; Thomas K. Gale

2005-06-30T23:59:59.000Z

267

Atmospheric Mercury Concentrations Near Salmon Falls Creek Reservoir - Phase 1  

SciTech Connect (OSTI)

Elemental and reactive gaseous mercury (EGM/RGM) were measured in ambient air concentrations over a two-week period in July/August 2005 near Salmon Falls Creek Reservoir, a popular fishery located 50 km southwest of Twin Falls, Idaho. A fish consumption advisory for mercury was posted at the reservoir in 2002 by the Idaho Department of Health and Welfare. The air measurements were part of a multi-media (water, sediment, precipitation, air) study initiated by the Idaho Department of Environmental Quality and the U.S. Environmental Protection Agency (EPA) Region 10 to identify potential sources of mercury contamination to the reservoir. The sampling site is located about 150 km northeast of large gold mining operations in Nevada, which are known to emit large amounts of mercury to the atmosphere (est. 2,200 kg/y from EPA 2003 Toxic Release Inventory). The work was co-funded by the Idaho National Laboratorys Community Assistance Program and has a secondary objective to better understand mercury inputs to the environment near the INL, which lies approximately 230 km to the northeast. Sampling results showed that both EGM and RGM concentrations were significantly elevated (~ 30 70%, P<0.05) compared to known regional background concentrations. Elevated short-term RGM concentrations (the primary form that deposits) were likely due to atmospheric oxidation of high EGM concentrations, which suggests that EGM loading from upwind sources could increase Hg deposition in the area. Back-trajectory analyses indicated that elevated EGM and RGM occurred when air parcels came out of north-central and northeastern Nevada. One EGM peak occurred when the air parcels came out of northwestern Utah. Background concentrations occurred when the air was from upwind locations in Idaho (both northwest and northeast). Based on 2003 EPA Toxic Release Inventory data, it is likely that most of the observed peaks were from Nevada gold mine sources. Emissions from known large natural mercury sources in that area cannot account for the observed EGM peaks due to their diffuse source geometry and the large (170 km) transport distance involved. The EGM peak originating from northwestern Utah air may be from three known mercury sources west of Salt Lake City (Kennecott, US Magnesium, Clean Harbors Aragonite) and/or the 1600 MW coal-fired Intermountain Power plant near Delta. However, the relative importance of these short-term peaks for long-term watershed mercury loading (critical factor affecting fish concentrations) is not known, and there is a need to better quantify the annual frequency and magnitude of these different inputs over a longer period of time.

M. L. Abbott

2005-10-01T23:59:59.000Z

268

IntroductionIntroduction Mercury: Monitoring Patients with ParkinsonMercury: Monitoring Patients with Parkinson''s Diseases Disease  

E-Print Network [OSTI]

IntroductionIntroduction Mercury: Monitoring Patients with ParkinsonMercury: Monitoring Patients's Disease EvaluationEvaluation Mercury ArchitectureMercury Architecture Mercury is a wireless sensor network and disconnections Node Behavior Hardware PlatformHardware Platform Usage Scenario InternetInternet http://fiji.eecs.harvard.edu/Mercury

Chen, Yiling

269

Nuclear elements in Banach Jordan pairs Ottmar Loos  

E-Print Network [OSTI]

Nuclear elements in Banach Jordan pairs Ottmar Loos Abstract We introduce nuclear elements in Banach Jordan pairs, generalizing the nuclear elements Jordan pairs and show that the trace form Trintroduced in [3] may be extended to the nuclear

270

Predictable SCR co-benefits for mercury control  

SciTech Connect (OSTI)

A test program, performed in cooperation with Dominion Power and the Babcock and Wilcox Co., was executed at Dominion Power's Mount Storm power plant in Grant County, W. Va. The program was focused on both the selective catalytic reduction (SCR) catalyst capability to oxide mercury as well as the scrubber's capability to capture and retain the oxidized mercury. This article focuses on the SCR catalyst performance aspects. The Mount Storm site consists of three units totaling approximately 1,660 MW. All units are equipped with SCR systems for NOx control. A full-scale test to evaluate the effect of the SCR was performed on Unit 2, a 550 MWT-fired boiler firing a medium sulfur bituminous coal. This test program demonstrated that the presence of an SCR catalyst can significantly affect the mercury speciation profile. Observation showed that in the absence of an SCR catalyst, the extent of oxidation of element a mercury at the inlet of the flue gas desulfurization system was about 64%. The presence of a Cornertech SCR catalyst improved this oxidation to levels greater than 95% almost all of which was captured by the downstream wet FGD system. Cornertech's proprietary SCR Hg oxidation model was used to accurately predict the field results. 1 ref., 2 figs., 1 tab.

Pritchard, S. [Cormtech Inc. (USA)

2009-01-15T23:59:59.000Z

271

Chronology of mercury enrichment factors in reef corals from western Venezuela Ruth Ramos a,*, Roberto Cipriani b  

E-Print Network [OSTI]

Keywords: Reef corals Sclerochronology Metal pollution Enrichment factors Mercury Petrochemical industry industrialized regions and petrochemical plants are polluted with this metal (Hornberger et al., 1999; Garcia material released into the atmosphere by vol- canic emissions and natural fires. Because traces of heavy

Bermingham, Eldredge

272

Mercury-Mercury Tunneling Junctions. 1. Electron Tunneling Across Symmetric and Asymmetric Alkanethiolate Bilayers  

E-Print Network [OSTI]

Mercury-Mercury Tunneling Junctions. 1. Electron Tunneling Across Symmetric and Asymmetric by bringing in contact two small (3 ? 10-3 cm2) mercury drop electrodes in a 5-20% (v/v) hexadecane solution incorporating alkanethiolate-type monolayer films. The results reported below convince us that the mercury

Majda, Marcin

273

NETL: Mercury Emissions Control Technologies - Mercury Control For Plants  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mercury Control For Plants Firing Texas Lignite and Equipped with ESP-wet FGD Mercury Control For Plants Firing Texas Lignite and Equipped with ESP-wet FGD URS Group, Inc., in collaboration with EPRI, Apogee Scientific, AEP, Texas Genco, and TXU Power, ADA-ES, will evaluate sorbent injection for mercury control in an 85/15 blend Texas lignite/PRB derived flue gas, upstream of a cold-side ESP – wet FGD combination. Full-scale sorbent injection tests conducted with various sorbents and combinations of fuel and plant air pollution control devices (APCD) have provided a good understanding of variables that affect sorbent performance. However, many uncertainties exist regarding long-term performance and data gaps remain for specific plant configurations. For example, sorbent injection has not been demonstrated at full-scale for plants firing Texas lignite, which represent approximately 10% of the annual U.S. power plant mercury emissions. The low and variable chloride content of Texas lignite may pose a challenge to achieving high levels of mercury removal with sorbent injection. Furthermore, activated carbon injection may render the fly ash unsuitable for sale, posing an economic liability to Texas lignite utilities. Alternatives to standard activated carbon, such as non-carbon sorbents and alternate injection locations (Toxecon II), have not been fully explored. Toxecon II involves sorbent injection in the middle field(s) of an ESP, thus preserving the integrity of the fly ash in the first fields.

274

Mercury switch with non-wettable electrodes  

DOE Patents [OSTI]

A mercury switch device comprising a pool of mercury and a plurality of electrical contacts made of or coated with a non-wettable material such as titanium diboride.

Karnowsky, Maurice M. (Albulquerque, NM); Yost, Frederick G. (Carlsbad, NM)

1987-01-01T23:59:59.000Z

275

Mercury Solar Systems | Open Energy Information  

Open Energy Info (EERE)

commercial and residential clients in the New York metrotri-state area. References: Mercury Solar Systems1 This article is a stub. You can help OpenEI by expanding it. Mercury...

276

Mercury speciation in the Persian Gulf sediments  

Science Journals Connector (OSTI)

The concentrations of total mercury (Hg) and methyl mercury (MMHg) were determined in 78 marine sediments in the Iranian coastal waters of the Persian Gulf along nine transects perpendicular to the coastline....?...

Homira Agah; Marc Elskens

2009-10-01T23:59:59.000Z

277

Rare Earth Elements:  

Science Journals Connector (OSTI)

...were also extracted as by-products of uranium mining from conglomerates at Elliot Lake...toxic waste lakes, acrid air, and high cancer rates in the Bayan Obo area. The environmental...Major and trace element composition of the depleted MORB mantle (DMM). Earth and Planetary...

Anton R. Chakhmouradian; Frances Wall

278

A Tragic Reminder about Organic Mercury  

Science Journals Connector (OSTI)

...politically contentious. Mercury is used in industry primarily in the manufacture of batteries, latex paint, urethane, and polyvinyl chloride. Pollution of the environment by mercury occurs mainly through incinerators, fossil-fuel plants, leaching from mining waste, and municipal sewage systems. Industrial discharge... Exposure to mercury and its potential toxic effects is a subject that involves everyone, because we are all frequently exposed. The toxicologic literature has clearly established the dangers of excessive exposure to mercury. What is less clear is the dose ...

Kulig K.

1998-06-04T23:59:59.000Z

279

CX-001459: Categorical Exclusion Determination | Department of...  

Broader source: Energy.gov (indexed) [DOE]

Categorical Exclusion Determination CX-001459: Categorical Exclusion Determination Air Quality VIII: An International Conference on Carbon Management, Mercury, Trace Elements,...

280

2003 Mercury Computer Systems, Inc. Data Reorganization  

E-Print Network [OSTI]

© 2003 Mercury Computer Systems, Inc. Data Reorganization Interface (DRI) Data Reorganization Interface (DRI) Kenneth Cain Jr. Mercury Computer Systems, Inc. High Performance Embedded Computing (HPEC Mercury Computer Systems, Inc. Status update for the DRI-1.0 standard since Sep. 2002 publication Outline

Kepner, Jeremy

Note: This page contains sample records for the topic "mercury trace elements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

3, 35253541, 2003 Modelling of Mercury  

E-Print Network [OSTI]

ACPD 3, 3525­3541, 2003 Modelling of Mercury with the Danish Eulerian Hemispheric Model J. H and Physics Discussions Modelling of mercury with the Danish Eulerian Hemispheric Model J. H. Christensen, J Correspondence to: J. H. Christensen (jc@dmu.dk) 3525 #12;ACPD 3, 3525­3541, 2003 Modelling of Mercury

Paris-Sud XI, Université de

282

Constraining Mercury Oxidation Using Wet Deposition  

E-Print Network [OSTI]

Constraining Mercury Oxidation Using Wet Deposition Noelle E. Selin and Christopher D. Holmes mercury oxidation [Selin & Jacob, Atmos. Env. 2008] 30 60 90 120 150 30 60 90 120 150 30 60 90 120 150 30 Influences on Mercury Wet Deposition · Hg wet dep = f(precipitation, [Hg(II)+Hg(P)]) Correlation (r2) between

Selin, Noelle Eckley

283

Mercury: Recovering Forgotten Passwords Using Personal Devices  

E-Print Network [OSTI]

Mercury: Recovering Forgotten Passwords Using Personal Devices Mohammad Mannan1 , David Barrera2, and to allow forgotten passwords to be securely restored, we present a scheme called Mercury. Its primary mode and revealed to the user. A prototype implementation of Mercury is available as an Android application. 1

Van Oorschot, Paul

284

2003 Mercury Computer Systems, Inc. Delivered Performance  

E-Print Network [OSTI]

© 2003 Mercury Computer Systems, Inc. Delivered Performance Predictions and Trends for RISC Applications Luke Cico (lcico@mc.com) Mark Merritt (mmerritt@mc.com) Mercury Computer Systems, Inc. Chelmsford, MA 01824 #12;© 2003 Mercury Computer Systems, Inc. Goals of PresentationGoals of Presentation

Kepner, Jeremy

285

Mercury Pollution in the Marine Environment  

E-Print Network [OSTI]

Collaborative December 2012 SourceSto Seafood SourceSto Seafood #12;About the report In 2010, the Toxic Metals.P. Mason, L.R. Rardin, C.V. Schmitt, N.S. Serrell, and E.M. Sunderland. 2012. Sources to Seafood: Mercury. 2 Sources to Seafood: Mercury Pollution in the Marine Environment #12;Executive Summary Mercury

Shepherd, Simon

286

REPLACE YOUR MERCURY THERMOMETERS BEFORE THEY BREAK!  

E-Print Network [OSTI]

REPLACE YOUR MERCURY THERMOMETERS BEFORE THEY BREAK! Did you know, mercury from broken thermometers to the local environment, if broken thermometers in sinks eventually end at the sanitary sewer plant. Broken mercury thermometers create hazardous waste that is costly to clean up and costly to dispose of. Other

287

EMSL - trace metals  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

trace-metals en Microbial Reductive Transformation of Phyllosilicate Fe(III) and U(VI) in Fluvial Subsurface Sediments. http:www.emsl.pnl.govemslwebpublications...

288

Elements & Compounds Atoms (Elements)  

E-Print Network [OSTI]

#12;Elements & Compounds #12;Atoms (Elements) Molecules (Compounds) Cells Elements & Compounds #12;Nucleus Electrons Cloud of negative charge (2 electrons) Fig. 2.5: Simplified model of a Helium (He) Atom He 4.002602 2 Helium Mass Number (~atomic mass) = number of Neutrons + Protons = 4 for Helium Atomic

Frey, Terry

289

DFJ Mercury | Open Energy Information  

Open Energy Info (EERE)

DFJ Mercury DFJ Mercury Jump to: navigation, search Name DFJ Mercury Place Houston, Texas Zip 77046 Product Houston-based seed and early-stage venture capital firm that targets the information technology, advanced materials, and bioscience sectors. Coordinates 29.76045°, -95.369784° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":29.76045,"lon":-95.369784,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

290

Mercury emissions during cofiring of sub-bituminous coal and biomass (chicken waste, wood, coffee residue, and tobacco stalk) in a laboratory-scale fluidized bed combustor  

SciTech Connect (OSTI)

Four types of biomass (chicken waste, wood pellets, coffee residue, and tobacco stalks) were cofired at 30 wt % with a U.S. sub-bituminous coal (Powder River Basin Coal) in a laboratory-scale fluidized bed combustor. A cyclone, followed by a quartz filter, was used for fly ash removal during tests. The temperatures of the cyclone and filter were controlled at 250 and 150{sup o}C, respectively. Mercury speciation and emissions during cofiring were investigated using a semicontinuous mercury monitor, which was certified using ASTM standard Ontario Hydra Method. Test results indicated mercury emissions were strongly correlative to the gaseous chlorine concentrations, but not necessarily correlative to the chlorine contents in cofiring fuels. Mercury emissions could be reduced by 35% during firing of sub-bituminous coal using only a quartz filter. Cofiring high-chlorine fuel, such as chicken waste (Cl = 22340 wppm), could largely reduce mercury emissions by over 80%. When low-chlorine biomass, such as wood pellets (Cl = 132 wppm) and coffee residue (Cl = 134 wppm), is cofired, mercury emissions could only be reduced by about 50%. Cofiring tobacco stalks with higher chlorine content (Cl = 4237 wppm) did not significantly reduce mercury emissions. Gaseous speciated mercury in flue gas after a quartz filter indicated the occurrence of about 50% of total gaseous mercury to be the elemental mercury for cofiring chicken waste, but occurrence of above 90% of the elemental mercury for all other cases. Both the higher content of alkali metal oxides or alkali earth metal oxides in tested biomass and the occurrence of temperatures lower than 650{sup o}C in the upper part of the fluidized bed combustor seemed to be responsible for the reduction of gaseous chlorine and, consequently, limited mercury emissions reduction during cofiring. 36 refs., 3 figs. 1 tab.

Yan Cao; Hongcang Zhou; Junjie Fan; Houyin Zhao; Tuo Zhou; Pauline Hack; Chia-Chun Chan; Jian-Chang Liou; Wei-ping Pan [Western Kentucky University (WKU), Bowling Green, KY (USA). Institute for Combustion Science and Environmental Technology (ICSET)

2008-12-15T23:59:59.000Z

291

Pilot Testing of Mercury Oxidation Catalysts for Upstream of Wet FGD Systems  

SciTech Connect (OSTI)

This document is the final technical report for Cooperative Agreement DE-FC26-04NT41992, 'Pilot Testing of Mercury Oxidation Catalysts for Upstream of Wet FGD Systems,' which was conducted over the time-period January 1, 2004 through December 31, 2010. The objective of this project has been to demonstrate at pilot scale the use of solid catalysts and/or fixed-structure mercury sorbents to promote the removal of total mercury and oxidation of elemental mercury in flue gas from coal combustion, followed by wet flue gas desulfurization (FGD) to remove the oxidized mercury at high efficiency. The project was co-funded by the U.S. DOE National Energy Technology Laboratory (DOE-NETL), EPRI, Great River Energy (GRE), TXU Energy (now called Luminant), Southern Company, Salt River Project (SRP) and Duke Energy. URS Group was the prime contractor. The mercury control process under development uses fixed-structure sorbents and/or catalysts to promote the removal of total mercury and/or oxidation of elemental mercury in the flue gas from coal-fired power plants that have wet lime or limestone FGD systems. Oxidized mercury not adsorbed is removed in the wet FGD absorbers and leaves with the byproducts from the FGD system. The project has tested candidate materials at pilot scale and in a commercial form, to provide engineering data for future full-scale designs. Pilot-scale catalytic oxidation tests have been completed for periods of approximately 14 to19 months at three sites, with an additional round of pilot-scale fixed-structure sorbent tests being conducted at one of those sites. Additionally, pilot-scale wet FGD tests have been conducted downstream of mercury oxidation catalysts at a total of four sites. The sites include the two of three sites from this project and two sites where catalytic oxidation pilot testing was conducted as part of a previous DOE-NETL project. Pilot-scale wet FGD tests were also conducted at a fifth site, but with no catalyst or fixed-structure mercury sorbent upstream. This final report presents and discusses detailed results from all of these efforts, and makes a number of conclusions about what was learned through these efforts.

Gary Blythe; Conor Braman; Katherine Dombrowski; Tom Machalek

2010-12-31T23:59:59.000Z

292

NETL: Mercury Emissions Control Technologies - Advanced Mercury Sorbents  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Advanced Mercury Sorbents with Low Impact on Power Plant Operations Advanced Mercury Sorbents with Low Impact on Power Plant Operations Apogee Scientific, Inc. (Apogee) will lead a Team comprised of Southern Company Services, TXU, Tennessee Valley Authority, EPRI, URS Group, University of Illinois-Illinois State Geological Survey (ISGS), Southern Research Institute (SRI), Calgon Carbon, and TDA Research, Inc., to evaluate a number of advanced sorbents for removing vapor-phase mercury from coal-fired flue gas that have minimal impact on by-product utilization and/or on existing particulate collection devices (PCD). The main objective of this program is to evaluate several advanced sorbents for removing mercury from coal-fired flue gas while posing minimal impact on plant operations through three advanced sorbent concepts: 1) Sorbents which minimize impact on concrete production through selective chemical passivation of activated carbon and use of non-carbon material, 2) sorbents that minimize baghouse pressure drop and ESP emissions, and 3) sorbents that can be recovered and reused.

293

Emissions, Monitoring and Control of Mercury from Subbituminous Coal-Fired Power Plants  

SciTech Connect (OSTI)

The Subbituminous Energy Coalition (SEC) identified a need to re-test stack gas emissions from power plants that burn subbituminous coal relative to compliance with the EPA mercury control regulations for coal-fired plants. In addition, the SEC has also identified the specialized monitoring needs associated with mercury continuous emissions monitors (CEM). The overall objectives of the program were to develop and demonstrate solutions for the unique emission characteristics found when burning subbituminous coals. The program was executed in two phases; Phase I of the project covered mercury emission testing programs at ten subbituminous coal-fired plants. Phase II compared the performance of continuous emission monitors for mercury at subbituminous coal-fired power plants and is reported separately. Western Research Institute and a number of SEC members have partnered with Eta Energy and Air Pollution Testing to assess the Phase I objective. Results of the mercury (Hg) source sampling at ten power plants burning subbituminous coal concluded Hg emissions measurements from Powder River Basin (PBR) coal-fired units showed large variations during both ICR and SEC testing. Mercury captures across the Air Pollution Control Devices (APCDs) present much more reliable numbers (i.e., the mercury captures across the APCDs are positive numbers as one would expect compared to negative removal across the APCDs for the ICR data). Three of the seven units tested in the SEC study had previously shown negative removals in the ICR testing. The average emission rate is 6.08 lb/TBtu for seven ICR units compared to 5.18 lb/TBtu for ten units in the SEC testing. Out of the ten (10) SEC units, Nelson Dewey Unit 1, burned a subbituminous coal and petcoke blend thus lowering the total emission rate by generating less elemental mercury. The major difference between the ICR and SEC data is in the APCD performance and the mercury closure around the APCD. The average mercury removal values across the APCDs are 2.1% and 39.4% with standard deviations (STDs) of 1990 and 75%, respectively for the ICR and SEC tests. This clearly demonstrates that variability is an issue irrespective of using 'similar' fuels at the plants and the same source sampling team measuring the species. The study also concluded that elemental mercury is the main Hg specie that needs to be controlled. 2004 technologies such as activated carbon injection (ACI) may capture up to 60% with double digit lb/MMacf addition of sorbent. PRB coal-fired units have an Hg input of 7-15 lb/TBtu; hence, these units must operate at over 60% mercury efficiency in order to bring the emission level below 5.8 lb/TBtu. This was non-achievable with the best technology available as of 2004. Other key findings include: (1) Conventional particulate collectors, such as Cold-side Electro-Static Precipitators (CESPs), Hot-side Electro-Static Precipitator (HESP), and Fabric Filter (FF) remove nearly all of the particulate bound mercury; (2) CESPs perform better highlighting the flue gas temperature effect on the mercury removal. Impact of speciation with flue gas cooling is apparent; (3) SDA's do not help in enhancing adsorption of mercury vapor species; and (4) Due to consistently low chlorine values in fuels, it was not possible to analyze the impact of chlorine. In summary, it is difficult to predict the speciation at two plants that burn the same fuel. Non-fuel issues, such as flue gas cooling, impact the speciation and consequently mercury capture potential.

Alan Bland; Kumar Sellakumar; Craig Cormylo

2007-08-01T23:59:59.000Z

294

All mercury lamps contain small amounts of mercury. An electric current passes through the lamp and vaporizes the mercury to generate light. Recycling mercury containing lamps protects human health and our environment from heavy  

E-Print Network [OSTI]

All mercury lamps contain small amounts of mercury. An electric current passes through the lamp and vaporizes the mercury to generate light. Recycling mercury containing lamps protects human health and our the environment by recycling universal wastes, contact EH&S at (949) 824-6200 or visit: www.ehs.uci.edu Mercury

George, Steven C.

295

Modeling and Experimental Studies of Mercury Oxidation and Adsorption in a Fixed-Bed and Entrained-Flow Reactor  

SciTech Connect (OSTI)

This report presents experimental and modeling mercury oxidation and adsorption data. Fixed-bed and single-particle models of mercury adsorption were developed. The experimental data were obtained with two reactors: a 300-W, methane-fired, tubular, quartz-lined reactor for studying homogeneous oxidation reactions and a fixed-bed reactor, also of quartz, for studying heterogeneous reactions. The latter was attached to the exit of the former to provide realistic combustion gases. The fixed-bed reactor contained one gram of coconut-shell carbon and remained at a temperature of 150oC. All methane, air, SO2, and halogen species were introduced through the burner to produce a radical pool representative of real combustion systems. A Tekran 2537A Analyzer coupled with a wet conditioning system provided speciated mercury concentrations. At 150?C and in the absence of HCl or HBr, the mercury uptake was about 20%. The addition of 50 ppm HCl caused complete capture of all elemental and oxidized mercury species. In the absence of halogens, SO2 increased the mercury adsorption efficiency to up to 30 percent. The extent of adsorption decreased with increasing SO2 concentration when halogens were present. Increasing the HCl concentration to 100 ppm lessened the effect of SO2. The fixed-bed model incorporates Langmuir adsorption kinetics and was developed to predict adsorption of elemental mercury and the effect of multiple flue gas components. This model neglects intraparticle diffusional resistances and is only applicable to pulverized carbon sorbents. It roughly describes experimental data from the literature. The current version includes the ability to account for competitive adsorption between mercury, SO2, and NO2. The single particle model simulates in-flight sorbent capture of elemental mercury. This model was developed to include Langmuir and Freundlich isotherms, rate equations, sorbent feed rate, and intraparticle diffusion. The Freundlich isotherm more accurately described in-flight mercury capture. Using these parameters, very little intraparticle diffusion was evident. Consistent with other data, smaller particles resulted in higher mercury uptake due to available surface area. Therefore, it is important to capture the particle size distribution in the model. At typical full-scale sorbent feed rates, the calculations underpredicted adsorption, suggesting that wall effects can account for as much as 50 percent of the removal, making it an important factor in entrained-mercury adsorption models.

Buitrago, Paula A; Morrill, Mike; Lighty, JoAnn S; Silcox, Geoffrey D

2014-08-20T23:59:59.000Z

296

Fate of Mercury in Synthetic Gypsum Used for Wallboard Production  

SciTech Connect (OSTI)

This report presents and discusses results from the project 'Fate of Mercury in Synthetic Gypsum Used for Wallboard Production', performed at five different full-scale commercial wallboard plants. Synthetic gypsum produced by wet flue gas desulfurization (FGD) systems on coal-fired power plants is commonly used in the manufacture of wallboard. This practice has long benefited the environment by recycling the FGD gypsum byproduct, which is becoming available in increasing quantities, decreasing the need to landfill this material, and increasing the sustainable design of the wallboard product. However, new concerns have arisen as recent mercury control strategies involve the capture of mercury in FGD systems. The objective of this study has been to determine whether any mercury is released into the atmosphere at wallboard manufacturing plants when the synthetic gypsum material is used as a feedstock for wallboard production. The project has been co-funded by the U.S. DOE National Energy Technology Laboratory (Cooperative Agreement DE-FC26-04NT42080), USG Corporation, and EPRI. USG Corporation is the prime contractor, and URS Group is a subcontractor. The project scope included seven discrete tasks, each including a test conducted at various USG wallboard plants using synthetic gypsum from different wet FGD systems. The project was originally composed of five tasks, which were to include (1) a base-case test, then variations representing differing power plant: (2) emissions control configurations, (3) treatment of fine gypsum particles, (4) coal types, and (5) FGD reagent types. However, Task 5,could not be conducted as planned and instead was conducted at conditions similar to Task 3. Subsequently an opportunity arose to test gypsum produced from the Task 5 FGD system, but with an additive expected to impact the stability of mercury, so Task 6 was added to the project. Finally, Task 7 was added to evaluate synthetic gypsum produced at a power plant from an additional coal type. In the project, process stacks in the wallboard plant were sampled using the Ontario Hydro method. In every task, the stack locations sampled included a gypsum dryer and a gypsum calciner. In Tasks 1 and 4 through 7, the stack of the dryer for the wet wallboard product was also tested. Also at each site, in-stream process samples were collected and analyzed for mercury concentration before and after each significant step in wallboard production. These results and process data were used to construct mercury mass balances across the wallboard plants. The results from the project showed a wide range of percentage mercury losses from the synthetic gypsum feedstocks as measured by the Ontario Hydro method at the process stacks, ranging from 2% to 55% of the mercury in the gypsum feedstock. For the tasks exceeding 10% mercury loss across the wallboard plant, most of the loss occurred across the gypsum calciner. When total wallboard emissions remained below 10%, the primary emission location varied with a much less pronounced difference in emission between the gypsum dryer, calciner and board dryer. For all seven tasks, the majority of the mercury emissions were measured to be in the elemental form (Hg{sup 0}). Overall, the measured mercury loss mass rates ranged from 0.01 to 0.17 grams of mercury per dry ton of synthetic gypsum processed, or 0.01 to 0.4 pounds of mercury released per million square feet of wallboard produced from synthetic gypsum. The Coal Combustion Product Production and Use Survey from the American Coal Ash Association (ACAA) indicate that 7,579,187 short tons of synthetic gypsum were used for wallboard production in 2006. Extrapolating the results of this study to the ACAA industry usage rate, we estimate that mercury releases from wallboard production plants in 2006 ranged between 150 to 3000 pounds for the entire U.S. wallboard industry. With only seven sets of wallboard plant measurements, it is difficult to draw firm conclusions about what variables impact the mercury loss percentages across the wallboard plants. One significant o

Jessica Sanderson

2007-12-31T23:59:59.000Z

297

MERCURY PURIFICATION IN THE MEGAWATT LIQUID METAL SPALLATION TARGET OF EURISOL-DS Joerg Neuhausena  

E-Print Network [OSTI]

MERCURY PURIFICATION IN THE MEGAWATT LIQUID METAL SPALLATION TARGET OF EURISOL-DS Joerg Neuhausena. For the development of a purification procedure, knowledge about the chemical state of the different elements present-components are of different origin: Gaseous impurities include oxygen, nitrogen and water. The construction materials

McDonald, Kirk

298

Microsoft Word - Vapor Phase Elemental Sulfur Tech Brief DRAFT bbl 08-24.docx  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AT A GLANCE AT A GLANCE  eliminates excavation expense  applicable to large or small sites  straightforward deployment  uses heat to distribute sulfur throughout a soil  mercury reacts with sulfur to form immobile and insoluble minerals  patent applied for TechBrief Vapor Phase Elemental Sulfur Amendment for Sequestering Mercury in Contaminated Soil Scientists at the Savannah River National Laboratory (SRNL) have identified a method of targeting mercury in contaminated soil zone by use of sulfur vapor heated gas. Background Mercury contamination in soil is a common problem in the environment. The most common treatment is excavation - a method that works well for small sites where the

299

Mercury emissions from municipal solid waste combustors  

SciTech Connect (OSTI)

This report examines emissions of mercury (Hg) from municipal solid waste (MSW) combustion in the United States (US). It is projected that total annual nationwide MSW combustor emissions of mercury could decrease from about 97 tonnes (1989 baseline uncontrolled emissions) to less than about 4 tonnes in the year 2000. This represents approximately a 95 percent reduction in the amount of mercury emitted from combusted MSW compared to the 1989 mercury emissions baseline. The likelihood that routinely achievable mercury emissions removal efficiencies of about 80 percent or more can be assured; it is estimated that MSW combustors in the US could prove to be a comparatively minor source of mercury emissions after about 1995. This forecast assumes that diligent measures to control mercury emissions, such as via use of supplemental control technologies (e.g., carbon adsorption), are generally employed at that time. However, no present consensus was found that such emissions control measures can be implemented industry-wide in the US within this time frame. Although the availability of technology is apparently not a limiting factor, practical implementation of necessary control technology may be limited by administrative constraints and other considerations (e.g., planning, budgeting, regulatory compliance requirements, etc.). These projections assume that: (a) about 80 percent mercury emissions reduction control efficiency is achieved with air pollution control equipment likely to be employed by that time; (b) most cylinder-shaped mercury-zinc (CSMZ) batteries used in hospital applications can be prevented from being disposed into the MSW stream or are replaced with alternative batteries that do not contain mercury; and (c) either the amount of mercury used in fluorescent lamps is decreased to an industry-wide average of about 27 milligrams of mercury per lamp or extensive diversion from the MSW stream of fluorescent lamps that contain mercury is accomplished.

Not Available

1993-05-01T23:59:59.000Z

300

ASSESING THE IMPACTS OF LOCAL DEPOSITION OF MERCURY ASSOCIATED WITH COAL-FIRED POWER PLANTS.  

SciTech Connect (OSTI)

Mercury emissions from coal fired plants will be limited by regulations enforced by the Environmental Protection Agency. However, there is still debate over whether the limits should be on a plant specific basis or a nationwide basis. The nationwide basis allows a Cap and Trade program similar to that for other air pollutants. Therefore, a major issue is the magnitude and extent of local deposition. Computer modeling suggests that increased local deposition will occur on a local (2 to 10 Km) to regional scale (20 to 50 Km) with the increase being a small percentage of background deposition on the regional scale. The amount of deposition depends upon many factors including emission rate, chemical form of mercury emitted (with reactive gaseous mercury depositing more readily than elemental mercury), other emission characteristics (stack height, exhaust temperature, etc), and meteorological conditions. Modeling suggests that wet deposition will lead to the highest deposition rates and that these will occur locally. Dry deposition is also predicted to deposit approximately the same amount of mass as wet deposition, but over a much greater area. Therefore, dry deposition rates will contribute a fraction of total deposition on the regional scale. The models have a number of assumptions pertaining to deposition parameters and there is uncertainty in the predicted deposition rates. A key assumption in the models is that the mixture of reactive gaseous mercury (RGM) to elemental mercury Hg(0) is constant in the exhaust plume. Recent work suggests that RGM converts to Hg(0) quickly. Deposition measurements around coal-fired power plants would help reduce the uncertainties in the models. A few studies have been performed to examine the deposition of mercury around point sources. Measurement of soil mercury downwind from chlor-alkali plants has shown increased deposition within a few Km. Studies of soils, sediments, and wet deposition around coal plants typically find some evidence of enhanced deposition; however, the statistical significance of the results is generally weak. A review of these studies is found in Lipfert. This study combines modeling of mercury deposition patterns with soil mercury measurements. The model used emissions data, meteorological conditions, and plant data to define sample locations likely to exhibit deposition in excess of background, that can be attributed to the power plant. Data were collected at the specified locations in November, 2003.

SULLIVAN, T.; BOWERMAN, B.; ADAMS, J.; OGEKA, C.; LIPFERT, F.; RENNINGER, S.

2004-03-28T23:59:59.000Z

Note: This page contains sample records for the topic "mercury trace elements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Xenon in Mercury-Manganese Stars  

E-Print Network [OSTI]

Previous studies of elemental abundances in Mercury-Manganese (HgMn) stars have occasionally reported the presence of lines of the ionized rare noble gas Xe II, especially in a few of the hottest stars with Teff ~ 13000--15000 K. A new study of this element has been undertaken using observations from Lick Observatory's Hamilton Echelle Spectrograph. In this work, the spectrum synthesis program UCLSYN has been used to undertake abundance analysis assuming LTE. We find that in the Smith & Dworetsky sample of HgMn stars, Xe is vastly over-abundant in 21 of 22 HgMn stars studied, by factors of 3.1--4.8 dex. There does not appear to be a significant correlation of Xe abundance with Teff. A comparison sample of normal late B stars shows no sign of Xe II lines that could be detected, consistent with the expected weakness of lines at normal abundance. The main reason for the previous lack of widespread detection in HgMn stars is probably due to the strongest lines being at longer wavelengths than the photographic blue. The lines used in this work were 4603.03A, 4844.33A and 5292.22A.

M. M. Dworetsky; J. L. Persaud; K. Patel

2008-01-16T23:59:59.000Z

302

A Mercury orientation model including non-zero obliquity and librations  

E-Print Network [OSTI]

Long-period forcing of Mercurys libration in longitude.M. : Resonant forcing of Mercurys libration in longitude.A revised control network for Mercury. J. Geophys. Res. 104,

Margot, Jean-Luc

2009-01-01T23:59:59.000Z

303

Atmospheric Mercury Deposition during the Last 270 Years: A  

E-Print Network [OSTI]

Atmospheric Mercury Deposition during the Last 270 Years: A Glacial Ice Core Record of Natural, and U.S. Geological Survey, Wisconsin District Mercury Research Laboratory, Middleton, Wisconsin 53562 Mercury (Hg) contamination of aquatic ecosystems and subsequent methylmercury bioaccumulation

304

Mercury-Contaminated Hydraulic Mining Debris in San Francisco Bay  

E-Print Network [OSTI]

S, and Flegal AR 2008. Mercury in the San Francisco Estuary.may 2010 Mercury-Contaminated Hydraulic Mining Debris in Sancontaminants such as ele- mental mercury and cyanide used in

Bouse, Robin M; Fuller, Christopher C; Luoma, Sam; Hornberger, Michelle I; Jaffe, Bruce E; Smith, Richard E

2010-01-01T23:59:59.000Z

305

Mercury Surface, Space Environment, Geochemistry, and Ranging Mission  

E-Print Network [OSTI]

MESSENGER Mercury Surface, Space Environment, Geochemistry, and Ranging Mission Frequently Asked Mercury's characteristics and environment during two complementary mission phases. The mission's primary goal is to increase our understanding of Mercury's density, geologic history, magnetic field, core

Mojzsis, Stephen J.

306

Control of mercury methylation in wetlands through iron addition  

E-Print Network [OSTI]

Mason, R. P. ; Flegal, A. R. , Mercury speciation in the SanP. ; Flegal, A. R. , Decadal mercury trends in San FranciscoP. G. ; Nelson, D. C. , Mercury methylation from unexpected

Sedlak, David L; Ulrich, Patrick D

2009-01-01T23:59:59.000Z

307

Determination of Mercury in Soils by Flameless Atomic Absorption Spectrometry  

Science Journals Connector (OSTI)

...chemical analysis exploration flameless geochemical methods mercury...Determination of Mercury in Soils by Flameless Atomic Absorption Spectrometry...Determinationof Mercury in Soilsby Flameless Atomic AbsorptionSpectrometry...the mercuryre- RF Induction Heater work coils 1. Carriergas...

B. G. Weissberg

308

COST OF MERCURY REMOVAL IN IGCC PLANTS  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Cost of Mercury Removal Cost of Mercury Removal in an IGCC Plant Final Report September 2002 Prepared for: The United States Department of Energy National Energy Technology Laboratory By: Parsons Infrastructure and Technology Group Inc. Reading, Pennsylvania Pittsburgh, Pennsylvania DOE Product Manager: Gary J. Stiegel DOE Task Manager: James R. Longanbach Principal Investigators: Michael G. Klett Russell C. Maxwell Michael D. Rutkowski PARSONS The Cost of Mercury Removal in an IGCC Plant Final Report i September 2002 TABLE OF CONTENTS Section Title Page 1 Summary 1 2 Introduction 3 3 Background 4 3.1 Regulatory Initiatives 4 3.2 Mercury Removal for Conventional Coal-Fired Plants 4 3.3 Mercury Removal Experience in Gasification 5 3.4 Variability of Mercury Content in Coal 6 4 Design Considerations 7 4.1 Carbon Bed Location

309

Assessment of Low Cost Novel Mercury Sorbents  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Testing of Mercury Control Technologies Testing of Mercury Control Technologies for Coal-Fired Power Plants by Thomas J. Feeley, III 1. , Lynn A. Brickett 1. , B. Andrew O'Palko 1. , and James T. Murphy 2. 1. U.S. Department of Energy, National Energy Technology Laboratory 2. Science Applications International Corporation The U.S. Department of Energy/National Energy Technology Laboratory (DOE/NETL) is conducting a comprehensive research, development, and demonstration (RD&D) program directed at advancing the performance and economics of mercury control technologies for coal- fired power plants. The program also includes evaluating the fate of mercury in coal by-products and studying the transport and transformation of mercury in power plant plumes. This paper presents results from ongoing full-scale and slip-stream field testing of several mercury control

310

Mercury Replacement Program It is the policy of California State University, Fullerton to remove mercury containing  

E-Print Network [OSTI]

Mercury Replacement Program I. Policy It is the policy of California State University, Fullerton to remove mercury containing devices throughout campus, insofar as is reasonably possible, and provide, the University has an obligation to safeguard employees from the potential health effects of mercury vapor while

de Lijser, Peter

311

Sulfurization of a carbon surface for vapor phase mercury removal II: Sulfur forms and mercury uptake  

E-Print Network [OSTI]

promote the formation of organic sulfur and the presence of H2S during the cooling process increased in the presence of H2S was very effective towards Hg uptake in nitrogen. Corre- lation of mercury uptake capacitySulfurization of a carbon surface for vapor phase mercury removal ­ II: Sulfur forms and mercury

Borguet, Eric

312

Mother-embryo isotope (15 C) fractionation and mercury (Hg)  

E-Print Network [OSTI]

used to investigate the trophic ecology, foraging habitats and heavy metal contamination). Consequently, Hg concentrations are important to monitor because of the toxicity of this metal. In order of this element in muscle and liver. Key words: sharks; stable isotopes; trace metal; maternal influence. hal

Paris-Sud XI, Université de

313

Trends in mercury concentrations in the hair of women of Nome, Alaska - Evidence of seafood consumption or abiotic absorption  

SciTech Connect (OSTI)

Eighty samples of hair from women of child-bearing age from Nome, Alaska, and seven control samples from women living in Sequim, Washington, were analyzed for mercury concentration by segmental analysis in an effort to determine whether seasonal fluctuations in mercury concentration in the hair samples can be correlated to seasonal seafood consumption. Full-length hair strands were analyzed in 1.1-cm segments representing 1 month's growth using a strong acid digestion and cold vapor atomic fluorescence analysis. It was assumed that the concentration of mercury in each segment is an indicator of the mercury body burden during the month in which the segment emerged from the scalp. Eighteen of the samples show seasonal variability, with five of the controls and one Nome resident showing winter highs while all Nome residents show summer highs. Twenty-six of the samples show an increase in mercury concentration toward the distal end of the strand regardless of month of growth. The trend of increasing mercury concentrations toward the distal end of the hair strand regardless of month of emergence, and the documented presence of elevated levels of elemental mercury in the Nome area suggest that these elevated levels may actually be due to external contamination of the hair strands by adsorption and not due to ingestion of contaminated foodstuffs such as seafood.

Lasorsa, B. (Battelle/Marine Sciences Lab., Sequim, WA (United States))

1992-06-01T23:59:59.000Z

314

Trends in mercury concentrations in the hair of women of Nome, Alaska - Evidence of seafood consumption or abiotic absorption?  

SciTech Connect (OSTI)

Eighty samples of hair from women of child-bearing age from Nome, Alaska, and seven control samples from women living in Sequim, Washington, were analyzed for mercury concentration by segmental analysis in an effort to determine whether seasonal fluctuations in mercury concentration in the hair samples can be correlated to seasonal seafood consumption. Full-length hair strands were analyzed in 1.1-cm segments representing 1 month`s growth using a strong acid digestion and cold vapor atomic fluorescence analysis. It was assumed that the concentration of mercury in each segment is an indicator of the mercury body burden during the month in which the segment emerged from the scalp. Eighteen of the samples show seasonal variability, with five of the controls and one Nome resident showing winter highs while all Nome residents show summer highs. Twenty-six of the samples show an increase in mercury concentration toward the distal end of the strand regardless of month of growth. The trend of increasing mercury concentrations toward the distal end of the hair strand regardless of month of emergence, and the documented presence of elevated levels of elemental mercury in the Nome area suggest that these elevated levels may actually be due to external contamination of the hair strands by adsorption and not due to ingestion of contaminated foodstuffs such as seafood.

Lasorsa, B. [Battelle/Marine Sciences Lab., Sequim, WA (United States)

1992-06-01T23:59:59.000Z

315

Process for removing mercury from aqueous solutions  

DOE Patents [OSTI]

A process for removing mercury from water to a level not greater than two parts per billion wherein an anion exchange material that is insoluble in water is contacted first with a sulfide containing compound and second with a compound containing a bivalent metal ion forming an insoluble metal sulfide. To this treated exchange material is contacted water containing mercury. The water containing not more than two parts per billion of mercury is separated from the exchange material.

Googin, John M. (Oak Ridge, TN); Napier, John M. (Oak Ridge, TN); Makarewicz, Mark A. (Knoxville, TN); Meredith, Paul F. (Knoxville, TN)

1986-01-01T23:59:59.000Z

316

Process for removing mercury from aqueous solutions  

DOE Patents [OSTI]

A process for removing mercury from water to a level not greater than two parts per billion wherein an anion exchange material that is insoluble in water is contacted first with a sulfide containing compound and second with a compound containing a bivalent metal ion forming an insoluble metal sulfide. To this treated exchange material is contacted water containing mercury. The water containing not more than two parts per billion of mercury is separated from the exchange material.

Googin, J.M.; Napier, J.M.; Makarewicz, M.A.; Meredith, P.F.

1985-03-04T23:59:59.000Z

317

Remediation of Mercury and Industrial Contaminants Applied Field...  

Office of Environmental Management (EM)

Remediation of Mercury and Industrial Contaminants Applied Field Research Initiative (RoMIC-AFRI) Remediation of Mercury and Industrial Contaminants Applied Field Research...

318

Mercury/Waterfilling: Optimum Power Allocation with Arbitrary Input Constellations  

E-Print Network [OSTI]

Mercury/Waterfilling: Optimum Power Allocation with Arbitrary Input Constellations Angel Lozano gives the power allocation policy, referred to as mercury/waterfilling, that maximizes the sum mutual

Verdú, Sergio

319

Mercury: A Diode-Pumped Solid-State Laser  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

with the development of the National Ignition Facility and its goal of achieving thermonuclear burn was another ambitious Livermore laser project named Mercury. The Mercury...

320

Apparatus for isotopic alteration of mercury vapor  

DOE Patents [OSTI]

An apparatus for enriching the isotopic Hg content of mercury is provided. The apparatus includes a reactor, a low pressure electric discharge lamp containing a fill including mercury and an inert gas. A filter is arranged concentrically around the lamp. In a preferred embodiment, constant mercury pressure is maintained in the filter by means of a water-cooled tube that depends from it, the tube having a drop of mercury disposed in it. The reactor is arranged around the filter, whereby radiation from said lamp passes through the filter and into said reactor. The lamp, the filter and the reactor are formed of a material which is transparent to ultraviolet light.

Grossman, Mark W. (Belmont, MA); George, William A. (Gloucester, MA); Marcucci, Rudolph V. (Danvers, MA)

1988-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mercury trace elements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Alkaline sorbent injection for mercury control  

DOE Patents [OSTI]

A mercury removal system for removing mercury from combustion flue gases is provided in which alkaline sorbents at generally extremely low stoichiometric molar ratios of alkaline earth or an alkali metal to sulfur of less than 1.0 are injected into a power plant system at one or more locations to remove at least between about 40% and 60% of the mercury content from combustion flue gases. Small amounts of alkaline sorbents are injected into the flue gas stream at a relatively low rate. A particulate filter is used to remove mercury-containing particles downstream of each injection point used in the power plant system.

Madden, Deborah A. (Boardman, OH); Holmes, Michael J. (Washington Township, Stark County, OH)

2003-01-01T23:59:59.000Z

322

Alkaline sorbent injection for mercury control  

DOE Patents [OSTI]

A mercury removal system for removing mercury from combustion flue gases is provided in which alkaline sorbents at generally extremely low stoichiometric molar ratios of alkaline earth or an alkali metal to sulfur of less than 1.0 are injected into a power plant system at one or more locations to remove at least between about 40% and 60% of the mercury content from combustion flue gases. Small amounts of alkaline sorbents are injected into the flue gas stream at a relatively low rate. A particulate filter is used to remove mercury-containing particles downstream of each injection point used in the power plant system.

Madden, Deborah A. (Boardman, OH); Holmes, Michael J. (Washington Township, Stark County, OH)

2002-01-01T23:59:59.000Z

323

Mercury Sensing with Optically Responsive Gold Nanoparticles  

E-Print Network [OSTI]

1.1.5 Mercury detection Atomic absorption 19 and atomicsacrifices in simplicity. Atomic absorption or fluorescencedown to low nanogram masses. Atomic absorption/fluorescence

James, Jay Zachary

2012-01-01T23:59:59.000Z

324

Separation of Mercury from Flue Gas Desulfurization Scrubber Produced Gypsum  

SciTech Connect (OSTI)

Frontier Geosciences (Frontier; FGS) proposed for DOE Grant No. DE-FG02-07ER84669 that mercury control could be achieved in a wet scrubber by the addition of an amendment to the wet-FGD scrubber. To demonstrate this, a bench-scale scrubber and synthetic flue-gas supply was designed to simulate the limestone fed, wet-desulfurization units utilized by coal-fired power plants. Frontier maintains that the mercury released from these utilities can be controlled and reduced by modifying the existing equipment at installations where wet flue-gas desulfurization (FGD) systems are employed. A key element of the proposal was FGS-PWN, a liquid-based mercury chelating agent, which can be employed as the amendment for removal of all mercury species which enter the wet-FGD scrubber. However, the equipment design presented in the proposal was inadequate to demonstrate these functions and no significant progress was made to substantiate these claims. As a result, funding for a Phase II continuation of this work will not be pursued. The key to implementing the technology as described in the proposal and report appears to be a high liquid-to-gas ratio (L/G) between the flue-gas and the scrubber liquor, a requirement not currently implemented in existing wet-FGD designs. It may be that this constraint can be reduced through parametric studies, but that was not apparent in this work. Unfortunately, the bench-scale system constructed for this project did not function as intended and the funds and time requested were exhausted before the separation studies could occur.

Hensman, Carl, E., P.h.D; Baker, Trevor

2008-06-16T23:59:59.000Z

325

Ultraviolet Light Initiated Oxidation of Elemental Hg  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The PCO Process for Removal of Mercury from Flue Gas The PCO Process for Removal of Mercury from Flue Gas Christopher R. McLarnon, Ph.D. Powerspan Corp., P.O. Box 219, 54 Old Bay Road, New Durham, NH 03855 Evan J. Granite* and Henry W. Pennline National Energy Technology Laboratory, United States Department of Energy, P.O. Box 10940, MS 58-106, Pittsburgh, PA 15236-0940 *Corresponding author. Tel.: +1412-386-4607; fax: +1412-386-6004 E-mail address: evan.granite@netl.doe.gov Abstract A promising technology has been developed to capture and remove elemental mercury species from coal-fired power plants. Powerspan Corp. has licensed the technology and initiated a bench and pilot test program to develop the Photochemical Oxidation, or PCO(tm), process for

326

Oak Ridge Moves Forward in Mercury Cleanup | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Oak Ridge Moves Forward in Mercury Cleanup Oak Ridge Moves Forward in Mercury Cleanup Oak Ridge Moves Forward in Mercury Cleanup March 28, 2013 - 12:00pm Addthis Workers recently removed five large mercury-contaminated tanks from Y-12. Workers recently removed five large mercury-contaminated tanks from Y-12. Removing these tanks is part of the steps to reduce potential risk from mercury at Y-12. Removing these tanks is part of the steps to reduce potential risk from mercury at Y-12. Workers recently removed five large mercury-contaminated tanks from Y-12. Removing these tanks is part of the steps to reduce potential risk from mercury at Y-12. OAK RIDGE, Tenn. - Oak Ridge's EM program is making significant progress to reduce environmental mercury releases from the Y-12 National Security Complex. Mercury is one of the greatest environmental concerns facing the Oak Ridge

327

Oak Ridge Moves Forward in Mercury Cleanup | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Moves Forward in Mercury Cleanup Moves Forward in Mercury Cleanup Oak Ridge Moves Forward in Mercury Cleanup March 28, 2013 - 12:00pm Addthis Workers recently removed five large mercury-contaminated tanks from Y-12. Workers recently removed five large mercury-contaminated tanks from Y-12. Removing these tanks is part of the steps to reduce potential risk from mercury at Y-12. Removing these tanks is part of the steps to reduce potential risk from mercury at Y-12. Workers recently removed five large mercury-contaminated tanks from Y-12. Removing these tanks is part of the steps to reduce potential risk from mercury at Y-12. OAK RIDGE, Tenn. - Oak Ridge's EM program is making significant progress to reduce environmental mercury releases from the Y-12 National Security Complex. Mercury is one of the greatest environmental concerns facing the Oak Ridge

328

EVALUATION OF MERCURY EMISSIONS FROM COAL-FIRED FACILITIES WITH SCR AND FGD SYSTEMS  

SciTech Connect (OSTI)

CONSOL Energy Inc., Research & Development (CONSOL), with support from the U.S. Department of Energy, National Energy Technology Laboratory (DOE) is evaluating the effects of selective catalytic reduction (SCR) on mercury (Hg) capture in coal-fired plants equipped with an electrostatic precipitator (ESP) - wet flue gas desulfurization (FGD) combination or a spray dyer absorber--fabric filter (SDA-FF) combination. In this program CONSOL is determining mercury speciation and removal at 10 coal-fired facilities. The objectives are (1) to evaluate the effect of SCR on mercury capture in the ESP-FGD and SDA-FF combinations at coal-fired power plants, (2) evaluate the effect of catalyst degradation on mercury capture; (3) evaluate the effect of low load operation on mercury capture in an SCR-FGD system, and (4) collect data that could provide the basis for fundamental scientific insights into the nature of mercury chemistry in flue gas, the catalytic effect of SCR systems on Hg speciation and the efficacy of different FGD technologies for Hg capture. This document, the second in a series of topical reports, describes the results and analysis of mercury sampling performed on a 330 MW unit burning a bituminous coal containing 1.0% sulfur. The unit is equipped with a SCR system for NOx control and a spray dryer absorber for SO{sub 2} control followed by a baghouse unit for particulate emissions control. Four sampling tests were performed in March 2003. Flue gas mercury speciation and concentrations were determined at the SCR inlet, air heater outlet (ESP inlet), and at the stack (FGD outlet) using the Ontario Hydro method. Process stream samples for a mercury balance were collected to coincide with the flue gas measurements. Due to mechanical problems with the boiler feed water pumps, the actual gross output was between 195 and 221 MW during the tests. The results showed that the SCR/air heater combination oxidized nearly 95% of the elemental mercury. Mercury removal, on a coal-to-stack basis, was 87%. The mercury material balance closures for the four tests conducted at the plant ranged from 89% to 114%, with an average of 100%. These results appear to show that the SCR had a positive effect on mercury removal. In earlier programs, CONSOL sampled mercury at six plants with wet FGDs for SO{sub 2} control without SCR catalysts. At those plants, an average of 61 {+-} 15% of the mercury was in the oxidized form at the air heater outlet. The principal purpose of this work is to develop a better understanding of the potential Hg removal ''co-benefits'' achieved by NOx, and SO{sub 2} control technologies. It is expected that this data will provide the basis for fundamental scientific insights into the nature of Hg chemistry in flue gas, the catalytic effect of SCR systems on Hg speciation and the efficacy of different FGD technologies for Hg capture. Ultimately, this insight could help to design and operate SCR and FGD systems to maximize Hg removal.

J. A. Withum; S.C. Tseng; J. E. Locke

2004-10-31T23:59:59.000Z

329

Mercury Vapor At Akutan Fumaroles Area (Kolker, Et Al., 2010) | Open Energy  

Open Energy Info (EERE)

Akutan Fumaroles Area (Kolker, Et Al., 2010) Akutan Fumaroles Area (Kolker, Et Al., 2010) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Akutan Fumaroles Area (Kolker, Et Al., 2010) Exploration Activity Details Location Akutan Fumaroles Area Exploration Technique Mercury Vapor Activity Date Usefulness useful DOE-funding Unknown Notes Arsenic (As), mercury (Hg), and carbon dioxide (CO2) all appear in anomalously high concentrations near the hot springs and at the junction of the Fumarole Valley and the HSBV. This indicates either that Hg is being lost from a reservoir due to boiling and steam loss, probably northwest of the junction, or erosion has carried these elements in sediment from the higher elevation manifestations. The presence of such volatiles in

330

Atmospheric Trace Gases from the Carbon Dioxide Information Analysis Center (CDIAC)  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

CDIAC products are indexed and searchable through a customized interface powered by ORNL's Mercury search engine. Products include numeric data packages, publications, trend data, atlases, models, etc. and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Some of the collections may also be included in the CDIAC publication, Trends Online: A Compendium of Global Change Data. Most data sets, many with numerous data files, are free to download from CDIAC's ftp area. The collections under the CDIAC heading of Atmospheric Trace Gases include: Atmospheric Carbon Dioxide, Atmospheric Methane, Atmospheric Carbon Monoxide, Atmospheric Hydrogen, Isotopes in Greenhouse Gases, Radionuclides, Aerosols, and Other Trace Gases.

331

Mercury oxidation over a vanadia-based selective catalytic reduction catalyst  

SciTech Connect (OSTI)

The process of the reaction among elemental mercury (Hg{sup 0}) and reactive flue gas components across the selective catalytic reduction (SCR) catalyst was studied in a laboratory-scale reactor. Prepared vanadia-based SCR catalysts were characterized and analyzed to understand the potential reaction pathways. Mercury oxidation was observed when pro-exposure of the SCR catalyst to HCl, followed by passing through Hg{sup 0}/N{sub 2} in the absence of gas-phase HCl. At testing conditions, Hg{sup 0} was found to desorb from the catalyst surface by adding HCl to the gas stream, which implies that HCl adsorption onto the SCR catalyst is strong relative to the mercury. Surface analysis verified the absorption of HCl onto the SCR catalysts, and the potential reaction pathways were proposed. Indeed, the monomeric vanadyl sites on the catalyst surface were found to be responsible for the adsorption of both Hg{sup 0} and HCl, which means they are active for mercury oxidation. Furthermore, the detailed Langmuir-Hinshelwood mechanism was proposed to explain the mercury oxidation on the SCR catalyst, where reactive Cl generated from adsorbed HCl reacts with adjacent Hg{sup 0}. 44 refs., 10 figs.

Sheng He; Jinsong Zhou; Yanqun Zhu; Zhongyang Luo; Mingjiang Ni; Kefa Cen [Zhejiang University, Hangzhou (China). State Key Laboratory of Clean Energy Utilization

2009-01-15T23:59:59.000Z

332

2006 Mercury Control Technology Conference Proceedings  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mercury Control Technology Conference Mercury Control Technology Conference December 11-13, 2006 Table of Contents Disclaimer Papers and Presentations Introduction Sorbent Injection By-Product Characterization/Management Mercury Oxidation and Co-Removal with FGD Systems Other Mercury Control Technology Panel Discussions Posters New 2006 Phase III Mercury Field Testing Projects Sorbent Injection Pretreatment of Coal Oxidation of Mercury Environmental Studies on Mercury Mercury in CUBs Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government or any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof.

333

Isotope Effect of Mercury Diffusion in Air  

Science Journals Connector (OSTI)

Isotope fractionation describes the separation of a reservoir with one isotope composition into fractions with different isotope compositions due to small isotopic differences in equilibrium partitioning, rates of mass transfer, or rates of transformation. ... (29) ?202Hg is the value most frequently used to examine mass dependent fractionation of mercury isotopes as 202Hg is the heaviest mercury isotope without significant isobaric interferences. ...

Paul G. Koster van Groos; Bradley K. Esser; Ross W. Williams; James R. Hunt

2013-12-23T23:59:59.000Z

334

The influence of floodplains on mercury availability  

SciTech Connect (OSTI)

The floodplains of the German river Elbe affect the mercury distribution in the river system in two different ways: they act both as a medium-term sink and as a long-term source. The large amounts of mercury deposited onto the floodplains during annual floodings are first effectively fixed in the soils, rendering them basically unavailable. Sequential extraction experiments reveal that only a small fraction of the mercury (< 3%) is present in available forms, whereas the vast majority is associated with humic substances or present in sulfidic binding forms. After deposition, a small fraction of the total mercury is gradually remobilized into the aqueous phase bound passively to water-soluble humic acids. The availability of mercury in these complexes is still low, since environmental influences such as changes in pH or redox potential and competition with other cations do not cause any mercury liberation. In the next step, reactions in the aqueous phase lead to the formation of the highly available volatile species Hg{sup 0} and dimethylmercury (DMM). Their evaporation gives rise to a strong mercury flux from the floodplains into the atmosphere. Preliminary mass balances indicate that the majority of the deposited mercury stays bound in the floodplain soils, while small amounts are emitted back into the river`s ecosystem. Atmospheric emission is more important as a remobilization pathway than aquatic export.

Wallschlaeger, D.; Wilken, R.D. [GKSS Research Center, Geesthacht (Germany). Inst. of Physical and Chemical Analytics

1997-09-01T23:59:59.000Z

335

Mercury Chamber NF-IDS Meeting  

E-Print Network [OSTI]

-Battelle for the U.S. Department of Energy Mercury Chamber Update Oct 2011 Starting Point: Coil and Shielding Concept IDS120H #12;3 Managed by UT-Battelle for the U.S. Department of Energy Mercury Chamber Update Oct 2011 · Penetrations (ports) into chamber ­ Nozzle ­ Hg drains (overflow and maintenance) ­ Vents (in and out) ­ Beam

McDonald, Kirk

336

Milestone Project Demonstrates Innovative Mercury Emissions Reduction  

Broader source: Energy.gov (indexed) [DOE]

Milestone Project Demonstrates Innovative Mercury Emissions Milestone Project Demonstrates Innovative Mercury Emissions Reduction Technology Milestone Project Demonstrates Innovative Mercury Emissions Reduction Technology January 12, 2010 - 12:00pm Addthis Washington, DC - An innovative technology that could potentially help some coal-based power generation facilities comply with anticipated new mercury emissions standards was successfully demonstrated in a recently concluded milestone project at a Michigan power plant. Under a cooperative agreement with the U.S. Department of Energy's (DOE's) National Energy Technology Laboratory (NETL), WE Energies demonstrated the TOXECON(TM) process in a $52.9million project at the Presque Isle Power Plant in Marquette, Mich. TOXECON is a relatively cost-effective option for achieving significant reductions in mercury emissions and increasing the

337

Effect of salinity on methylation of mercury  

SciTech Connect (OSTI)

Monomethyl and dimethylmercury are potent neurotoxins subject to biomagnification in food webs. This fact was tragically demonstrated by the Minamata and Niigata poisoning incidents in Japan in which 168 persons who ate seafood from mercury polluted waters were poisoned, 52 fatally. Shortly after these two incidents, work conducted in freshwater environments demonstrated the microbial conversion of inorganic and phenylmercury compounds to mono- and di-methylmercury. Consideration of some fragmentary evidence from the literature, however, indicates that the rate and the significance of microbial methylation of mercury in freshwater and saltwater environments may not be the same. A demonstrated relationship between mercury methylation rates and water salinity would greatly influence our thinking about mercury pollution effects in marine versus freshwater environments. Since we were unable to locate published reports on this subject, we are investigating the influence of salinity on the rate of mercury methylation in an estuarine sediment.

Blum, J.E.; Bartha, R.

1980-09-01T23:59:59.000Z

338

MERCURY HANDLING FOR THE TARGET SYSTEM FOR A MUON COLLIDER  

E-Print Network [OSTI]

MERCURY HANDLING FOR THE TARGET SYSTEM FOR A MUON COLLIDER Van Graves , ORNL, Oak Ridge, TN 37830 Factory is a free-stream mercury jet within a 20-T magnetic field being impacted by an 8-GeV proton beam. A pool of mercury serves as a receiving reservoir for the mercury and a dump for the unexpended proton

McDonald, Kirk

339

Thursday, March 15, 2007 POSTER SESSION II: MERCURY  

E-Print Network [OSTI]

Thursday, March 15, 2007 POSTER SESSION II: MERCURY 6:30 p.m. Fitness Center Dombard A. J. Hauck S. A. II Despinning Plus Global Contraction and the Orientation of Lobate Scarps on Mercury [#2026] We thermal models of Mercury. King S. D. A Possible Connection Between Convection in Mercury's Mantle

Rathbun, Julie A.

340

2003 Mercury Computer Systems, Inc. Optimizing System Compute  

E-Print Network [OSTI]

© 2003 Mercury Computer Systems, Inc. Optimizing System Compute Density for Deployed HPEC Electronics Engineering Mercury Computer Systems, Inc. rbanton@mc.com Richard Jaenicke, Director, Product Marketing Mercury Computer Systems, Inc. rjaenicke@mc.com #12;2 © 2002 Mercury Computer Systems, Inc.© 2003

Kepner, Jeremy

Note: This page contains sample records for the topic "mercury trace elements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Laser Altimeter Observations from MESSENGER's First Mercury Flyby  

E-Print Network [OSTI]

REPORT Laser Altimeter Observations from MESSENGER's First Mercury Flyby Maria T. Zuber,1 * David E Barnouin-Jha,8 John K. Harmon10 A 3200-kilometers-long profile of Mercury by the Mercury Laser Altimeter compensated. Sampled craters on Mercury are shallower than their counterparts on the Moon, at least in part

Hauck II, Steven A.

342

Sources to Seafood: Mercury Pollution in the Marine Environment  

E-Print Network [OSTI]

Sources to Seafood: Mercury Pollution in the Marine Environment The Coastal and Marine Mercury a series of scientific papers on mercury pollution in the marine environment from sources to seafood and in June 2012 in Environmental Health Perspectives. The summary report, Sources to Seafood: Mercury

343

A CAVITY RING-DOWN SPECTROSCOPY MERCURY CONTINUOUS EMISSION MONITOR  

SciTech Connect (OSTI)

The construction of the sampling system was completed during the past quarter. The sampling system has been built on a 3 feet x 4 feet x 2 inch breadboard table. The laser system, all the associated optics, and the mounts and hardware needed to couple the UV light into the fiber optic have also been condensed and placed on an identical 3 feet x 4 feet x 2 inch breadboard table. This reduces the footprint of each system for ease of operation at a field test facility. The two systems are only connected with a fiber optic, to bring the UV light to the CRD cavity, and a single coaxial cable used to apply a voltage to the diode seed laser to scan the frequency over the desired mercury transition. SRD software engineers applied a couple of software fixes to correct the problems of the diode seed laser drifting or mode hopping. Upon successful completion of the software fixes another long-term test was conducted. A nearly 3 day long, 24 hours/day, test was run to test out the new subroutines. Everything appeared to work as it should and the mercury concentrations were accurately reported for the entire test, with the exception of a small interval of time when the intensity of the UV light dropped low enough that the program was no longer triggering properly. After adjusting the power of the laser the program returned to proper operation. With the successful completion of a relatively long test SRD software engineer incorporated the new subroutine into an entirely new program. This program operates the CRD instrument automatically as a continuous emissions monitor for mercury. In addition the program also reports the concentration of SO{sub 2} determined in the sample flue gas stream. Various functions, operation of, and a description of the new program have been included with this report. This report concludes the technical work associated with Phase II of the Cavity Ring-Down project for the continuous detection of trace levels of mercury. The project is presently gearing up for additional testing in preparation for a field test to be conducted at the DOE/NETL pilot plant facility in Pittsburgh, Pennsylvania.

Christopher C. Carter

2004-03-31T23:59:59.000Z

344

Full-Scale Testing of a Mercury Oxidation Catalyst Upstream of a Wet FGD System  

SciTech Connect (OSTI)

This document presents and discusses results from Cooperative Agreement DE-FC26-06NT42778, 'Full-scale Testing of a Mercury Oxidation Catalyst Upstream of a Wet FGD System,' which was conducted over the time-period July 24, 2006 through June 30, 2010. The objective of the project was to demonstrate at full scale the use of solid honeycomb catalysts to promote the oxidation of elemental mercury in pulverized-coal-fired flue gas. Oxidized mercury is removed downstream in wet flue gas desulfurization (FGD) absorbers and collected with the byproducts from the FGD system. The project was co-funded by EPRI, the Lower Colorado River Authority (LCRA), who also provided the host site, Great River Energy, Johnson Matthey, Southern Company, Salt River Project (SRP), the Tennessee Valley Authority (TVA), NRG Energy, Ontario Power and Westar. URS Group was the prime contractor and also provided cofunding. The scope of this project included installing and testing a gold-based catalyst upstream of one full-scale wet FGD absorber module (about 200-MW scale) at LCRA's Fayette Power Project (FPP) Unit 3, which fires Powder River Basin coal. Installation of the catalyst involved modifying the ductwork upstream of one of three wet FGD absorbers on Unit 3, Absorber C. The FGD system uses limestone reagent, operates with forced sulfite oxidation, and normally runs with two FGD modules in service and one spare. The full-scale catalyst test was planned for 24 months to provide catalyst life data. Over the test period, data were collected on catalyst pressure drop, elemental mercury oxidation across the catalyst module, and mercury capture by the downstream wet FGD absorber. The demonstration period began on May 6, 2008 with plans for the catalyst to remain in service until May 5, 2010. However, because of continual increases in pressure drop across the catalyst and concerns that further increases would adversely affect Unit 3 operations, LCRA decided to end the demonstration early, during a planned unit outage. On October 2, 2009, Unit 3 was taken out of service for a fall outage and the catalyst upstream of Absorber C was removed. This ended the demonstration after approximately 17 months of the planned 24 months of operation. This report discusses reasons for the pressure drop increase and potential measures to mitigate such problems in any future application of this technology. Mercury oxidation and capture measurements were made on Unit 3 four times during the 17-month demonstration. Measurements were performed across the catalyst and Absorber C and 'baseline' measurements were performed across Absorber A or B, which did not have a catalyst upstream. Results are presented in the report from all four sets of measurements during the demonstration period. These results include elemental mercury oxidation across the catalyst, mercury capture across Absorber C downstream of the catalyst, baseline mercury capture across Absorber A or B, and mercury re-emissions across both absorbers in service. Also presented in the report are estimates of the average mercury control performance of the oxidation catalyst technology over the 17-month demonstration period and the resulting mercury control costs.

Gary Blythe; Jennifer Paradis

2010-06-30T23:59:59.000Z

345

Geothermal Exploration Using Surface Mercury Geochemistry | Open Energy  

Open Energy Info (EERE)

Surface Mercury Geochemistry Surface Mercury Geochemistry Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: Geothermal Exploration Using Surface Mercury Geochemistry Details Activities (5) Areas (3) Regions (0) Abstract: Shallow, soil-mercury surveys can be used effectively in exploration for geothermal resources. Soil-mercury data from six areas in Nevada, California and New Mexico are analyzed using contour maps, histogram and probability graphs. Plotting on probability graphs allows background and anomalous populations to be resolved even when considerable overlap between populations is present. As is shown in several examples, separate soil-mercury populations can be plausibly interpreted. Mercury data can significantly enhance the structural understanding of a prospect

346

Process for combined control of mercury and nitric oxide.  

SciTech Connect (OSTI)

Continuing concern about the effects of mercury in the environment may lead to requirements for the control of mercury emissions from coal-fired power plants. If such controls are mandated, the use of existing flue-gas cleanup systems, such as wet scrubbers currently employed for flue-gas desulfurization, would be desirable, Such scrubbers have been shown to be effective for capturing oxidized forms of mercury, but cannot capture the very insoluble elemental mercury (Hg{sup 0}) that can form a significant fraction of the total emissions. At Argonne National Laboratory, we have proposed and tested a concept for enhancing removal of Hg{sup 0}, as well as nitric oxide, through introduction of an oxidizing agent into the flue gas upstream of a scrubber, which readily absorbs the soluble reaction products. Recently, we developed a new method for introducing the oxidizing agent into the flue-gas stream that dramatically improved reactant utilization. The oxidizing agent employed was NOXSORB{trademark}, which is a commercial product containing chloric acid and sodium chlorate. When a dilute solution of this agent was introduced into a gas stream containing Hg{sup 0} and other typical flue-gas species at 300 F, we found that about 100% of the mercury was removed from the gas phase and recovered in process liquids. At the same time, approximately 80% of the nitric oxide was removed. The effect of sulfur dioxide on this process was also investigated and the results showed that it slightly decreased the amount of Hg{sup 0} oxidized while appearing to increase the removal of nitric oxide from the gas phase. We are currently testing the effects of variations in NOXSORB{trademark} concentration, sulfur dioxide concentration, nitric oxide concentration, and reaction time (residence time). Preliminary economic projections based on the results to date indicate that the chemical cost for nitric oxide oxidation could be less than $5,000/ton removed, while for Hg{sup 0} oxidation it would be about $20,000/lb removed.

Livengood, C. D.; Mendelsohn, M. H.

1999-11-03T23:59:59.000Z

347

Figure 2: The mercury jet target geometry. The proton beam and mercury jet cross at z=-37.5 cm.  

E-Print Network [OSTI]

Figure 2: The mercury jet target geometry. The proton beam and mercury jet cross at z=-37.5 cm. Figure 3: The layout of multiple proton beam entry directions relative to mercury jet at z=-75 cm. A PION of a free liquid mercury jet with an intense proton beam. We study the variation of meson production

McDonald, Kirk

348

Mercury Lamps Recycling Fluorescent light-tubes, compact fluorescent bulbs, mercury and sodium vapor lamps, ultraviolet and  

E-Print Network [OSTI]

Mercury Lamps Recycling Fluorescent light-tubes, compact fluorescent bulbs, mercury and sodium vapor lamps, ultraviolet and HID (high-intensity discharge) lamps and all other mercury containing labeled for shipment to a recycling plant for mercury, glass and aluminum recovery. The beneficial re

Baker, Chris I.

349

CGC Trace Species Partitioning  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trace Species Partitioning as Affected Trace Species Partitioning as Affected by Cold Gas Cleanup Conditions: A Thermodynamic Analysis February 10, 2011 DOE/NETL-2011/1503 T r ace Species P ar titioning at C old G as C leanup C onditions Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference therein to any specific commercial product, process, or service by trade name,

350

Parallel Seismic Ray Tracing  

E-Print Network [OSTI]

. . . . . . . . . . . . . . . . . . . . . 27 3.4.1 Rotated Take-Off Angle Mesh . . . . . . . . . . . . . . . . . . 28 3.4.2 Rotated Cubed Sphere Mesh . . . . . . . . . . . . . . . . . . . 29 3.4.3 Ray Tube Interpolation . . . . . . . . . . . . . . . . . . . . . . 30 3.5 Theoretical Model..., the ray parameters are defined as ?1 = ?(declination), ?2 = ?(azimuth), and ?3 = ?(travel-time). (b) Suppose we have a unit cube centered at the source point, then a ray can be traced from the source point through an evenly discretized point on the face...

Jain, Tarun K

2013-12-09T23:59:59.000Z

351

Phytoremediation of Ionic and Methyl Mercury P  

SciTech Connect (OSTI)

Our long-term goal is to enable highly productive plant species to extract, resist, detoxify, and/or sequester toxic heavy metal pollutants as an environmentally friendly alternative to physical remediation methods. We have focused this phytoremediation research on soil and water-borne ionic and methylmercury. Mercury pollution is a serious world-wide problem affecting the health of human and wild-life populations. Methylmercury, produced by native bacteria at mercury-contaminated wetland sites, is a particularly serious problem due to its extreme toxicity and efficient biomagnification in the food chain. We engineered several plant species (e.g., Arabidopsis, tobacco, canola, yellow poplar, rice) to express the bacterial genes, merB and/or merA, under the control of plant regulatory sequences. These transgenic plants acquired remarkable properties for mercury remediation. (1) Transgenic plants expressing merB (organomercury lyase) extract methylmercury from their growth substrate and degrade it to less toxic ionic mercury. They grow on concentrations of methylmercury that kill normal plants and accumulate low levels of ionic mercury. (2) Transgenic plants expressing merA (mercuric ion reductase) extract and electrochemically reduce toxic, reactive ionic mercury to much less toxic and volatile metallic mercury. This metal transformation is driven by the powerful photosynthetic reducing capacity of higher plants that generates excess NADPH using solar energy. MerA plants grow vigorously on levels of ionic mercury that kill control plants. Plants expressing both merB and merA degrade high levels of methylmercury and volatilize metallic mercury. These properties were shown to be genetically stable for several generations in the two plant species examined. Our work demonstrates that native trees, shrubs, and grasses can be engineered to remediate the most abundant toxic mercury pollutants. Building on these data our working hypothesis for the next grant period is that transgenic plants expressing the bacterial merB and merA genes will (a) remove mercury from polluted soil and water and (b) prevent methylmercury from entering the food chain. Our specific aims center on understanding the mechanisms by which plants process the various forms of mercury and volatilize or transpire mercury vapor. This information will allow us to improve the design of our current phytoremediation strategies. As an alternative to volatilizing mercury, we are using several new genes to construct plants that will hyperaccumulate mercury in above-ground tissues for later harvest. The Department of Energy's Oak Ridge National Laboratory and Brookhaven National Laboratory have sites with significant levels of mercury contamination that could be cleaned by applying the scientific discoveries and new phytoremediation technologies described in this proposal. The knowledge and expertise gained by engineering plants to hyperaccumulate mercury can be applied to the remediation of other heavy metals pollutants (e.g., arsenic, cesium, cadmium, chromium, lead, strontium, technetium, uranium) found at several DOE facilities.

Meagher, Richard B.

1999-06-01T23:59:59.000Z

352

Human exposure to mercury: A critical assessment of the evidence of adverse health effects  

SciTech Connect (OSTI)

The ubiquitous nature of mercury in the environment, its global atmospheric cycling, and its toxicity to humans at levels that are uncomfortably close to exposures experienced by a proportion of the population are some of the current concerns associated with this pollutant. The purpose of this review is to critically evaluate the scientific quality of published reports involving human exposures to mercury and associated health outcomes as an aid in the risk evaluation of this chemical. A comprehensive review of the scientific literature involving human exposures to mercury was performed and each publication evaluated using a defined set of criteria that are considered standards in epidemiologic and toxicologic research. Severe, sometimes fatal, effects of mercury exposure at high levels were primarily reported as case studies. The disasters in Minamata, Japan, in the 1950s and in Iraq in 1971-1972 clearly demonstrated neurologic effects associated with ingestion of methylmercury both in adults and in infants exposed in utero. The effects were convincingly Associated with methylmercury ingestion, despite limitations of the study design. Several well-conducted studies have investigated the effects of methylmercury at levels below those in the Iraq incident but have not provided clear evidence of an effect. The lower end of the dose-response curve constructed from the Iraq data therefore still needs to be confirmed. The studies of mercury exposure in the workplace were mainly of elemental or inorganic mercury, and effects that were observed at relatively low exposure levels were primarily neurologic and renal. Several studies have investigated effects associated with dental amalgam but have been rated as inconclusive because of methodologic deficiencies. In our overall evaluation, 29 of 110 occupational studies and 20 of 54 studies where exposure occurred in the natural environment provided at least suggestive evidence of an exposure-related effect. 259 refs., 4 tabs.

Ratcliffe, H.E.; Swanson, G.M.; Fischer, L.J. [Michigan State Univ., East Lansing, MI (United States)

1996-10-25T23:59:59.000Z

353

Effect of the shutdown of a large coal-fired power plant on ambient mercury  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Effect of the shutdown of a large coal-fired power plant on ambient mercury Effect of the shutdown of a large coal-fired power plant on ambient mercury species Title Effect of the shutdown of a large coal-fired power plant on ambient mercury species Publication Type Journal Article LBNL Report Number LBNL-6097E Year of Publication 2013 Authors Wang, Yungang, Jiaoyan Huang, Philip K. Hopke, Oliver V. Rattigan, David C. Chalupa, Mark J. Utell, and Thomas M. Holsen Journal Chemosphere Volume 92 Issue 4 Pagination 360-367 Date Published 07/2013 Abstract In the spring of 2008, a 260MWe coal-fired power plant (CFPP) located in Rochester, New York was closed over a 4 month period. Using a 2-years data record, the impacts of the shutdown of the CFPP on nearby ambient concentrations of three Hg species were quantified. The arithmetic average ambient concentrations of gaseous elemental mercury (GEM), gaseous oxidized mercury (GOM), and particulate mercury (PBM) during December 2007-November 2009 were 1.6ng/m3, 5.1pg/m3, and 8.9pg/m3, respectively. The median concentrations of GEM, GOM, and PBM significantly decreased by 12%, 73%, and 50% after the CFPP closed (Mann-Whitney test, p<0.001). Positive Matrix Factorization (EPA PMF v4.1) identified six factors including O3-rich, traffic, gas phase oxidation, wood combustion, nucleation, and CFPP. When the CFPP was closed, median concentrations of GEM, GOM, and PBM apportioned to the CFPP factor significantly decreased by 25%, 74%, and 67%, respectively, compared to those measured when the CFPP was still in operation (Mann-Whitney test, p<0.001). Conditional probability function (CPF) analysis showed the greatest reduction in all three Hg species was associated with northwesterly winds pointing toward the CFPP. These changes were clearly attributable to the closure of the CFPP.

354

Mercury cleanup efforts intensify | Y-12 National Security Complex  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mercury cleanup efforts ... Mercury cleanup efforts ... Mercury cleanup efforts intensify Posted: February 11, 2013 - 3:31pm | Y-12 Report | Volume 9, Issue 2 | 2013 Millions of pounds of mercury were required to support Y-12's post-World War II mission of separating lithium isotopes. Cleaning up the toxic heavy metal poses many challenges, but what Y-12 is learning could help conquer mercury pollution worldwide. There's a reason you won't find mercury in many thermometers these days. Mercury is a heavy metal that occurs in several chemical forms, all of which can produce toxic effects in high enough doses. Mercury was used in the column exchange process, which Y-12 employed to produce lithium-6 from 1953 to 1962. Through process spills, system leaks and surface runoff, some 700,000 pounds of mercury have been lost to the

355

NETL: Mercury Emissions Control Technologies - Enhanced High Temperature  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Enhanced High Temperature Mercury Oxidation and Enhanced High Temperature Mercury Oxidation and In-Situ Active Carbon Generation for Low Cost Mercury Capture Mercury oxidation phenomenon and the studies of this phenomenon have generally focused on lower temperatures, typically below 650°F. This has been based on the mercury vapor equilibrium speciation curve. The baseline extents of mercury oxidation as reported in the ICR dataset and observed during subsequent tests has shown a tremendous amount of scatter. The objective of this project is to examine, establish and demonstrate the effect of higher temperature kinetics on mercury oxidation rates. Further, it is the objective of this project to demonstrate how the inherent mercury oxidation kinetics can be influenced to dramatically increase the mercury oxidation.

356

Discussion on 'characteristics of fly ashes from full-scale coal-fired power plants and their relationship to mercury adsorption' by Lu et al.  

SciTech Connect (OSTI)

Mercury capture by coal-combustion fly ash is a function of the amount of Hg in the feed coal, the amount of carbon in the fly ash, the type of carbon in the fly ash (including variables introduced by the rank of the feed coal), and the flue gas temperature at the point of ash collection. In their discussion of fly ash and Hg adsorption, Lu et al. (Energy Fuels 2007, 21, 2112-2120) had some fundamental flaws in their techniques, which, in turn, impact the validity of analyzed parameters. First, they used mechanical sieving to segregate fly ash size fractions. Mechanical sieving does not produce representative size fractions, particularly for the finest sizes. If the study samples were not obtained correctly, the subsequent analyses of fly ash carbon and Hg cannot accurately represent the size fractions. In the analysis of carbon forms, it is not possible to accurately determine the forms with scanning electron microscopy. The complexity of the whole particles is overlooked when just examining the outer particle surface. Examination of elements such as Hg, present in very trace quantities in most fly ashes, requires careful attention to the analytical techniques. 36 refs., 3 figs., 1 tab.

James C. Hower; Bruno Valentim; Irena J. Kostova; Kevin R. Henke [University of Kentucky Center for Applied Energy Research, Lexington, KY (United States)

2008-03-15T23:59:59.000Z

357

Mercury contaminated sediment sitesAn evaluation of remedial options  

SciTech Connect (OSTI)

Mercury (Hg) is a naturally-occurring element that is ubiquitous in the aquatic environment. Though efforts have been made in recent years to decrease Hg emissions, historically-emitted Hg can be retained in the sediments of aquatic bodies where they may be slowly converted to methylmercury (MeHg). Consequently, Hg in historically-contaminated sediments can result in high levels of significant exposure for aquatic species, wildlife and human populations consuming fish. Even if source control of contaminated wastewater is achievable, it may take a very long time, perhaps decades, for Hg-contaminated aquatic systems to reach relatively safe Hg levels in both water and surface sediment naturally. It may take even longer if Hg is present at higher concentration levels in deep sediment. Hg contaminated sediment results from previous releases or ongoing contributions from sources that are difficult to identify. Due to human activities or physical, chemical, or biological processes (e.g. hydrodynamic flows, bioturbation, molecular diffusion, and chemical transformation), the buried Hg can be remobilized into the overlying water. Hg speciation in the water column and sediments critically affect the reactivity (i.e. conversion of inorganic Hg(II) to MeHg), transport, and its exposure to living organisms. Also, geochemical conditions affect the activity of methylating bacteria and its availability for methylation. This review paper discusses remedial considerations (e.g. key chemical factors in fate and transport of Hg, source characterization and control, environmental management procedures, remediation options, modeling tools) and includes practical case studies for cleaning up Hg-contaminated sediment sites. -- Highlights: ? Managing mercury-contaminated sediment sites are challenging to remediate. ? Remediation technologies are making a difference in managing these sites. ? Partitioning plays a dominant role in the distribution of mercury species. ? Mathematical models can be used to help us understand the chemistry and processes.

Randall, Paul M., E-mail: randall.paul@epa.gov [U.S. Environmental Protection Agency, Office of Research and Development, National Risk Management Research Laboratory, 26 West Martin Luther King Drive, Cincinnati, OH 45268 (United States); Chattopadhyay, Sandip, E-mail: Sandip.Chattopadhyay@tetratech.com [Tetra Tech, Inc., 250 West Court Street, Suite 200W, Cincinnati, OH 45202 (United States)] [Tetra Tech, Inc., 250 West Court Street, Suite 200W, Cincinnati, OH 45202 (United States)

2013-08-15T23:59:59.000Z

358

ENHANCED CONTROL OF MERCURY BY WET FLUE GAS DESULFURIZATION SYSTEMS  

SciTech Connect (OSTI)

The U.S. Department of Energy and EPRI co-funded this project to improve the control of mercury emissions from coal-fired power plants equipped with wet flue gas desulfurization (FGD) systems. The project has investigated catalytic oxidation of vapor-phase elemental mercury to a form that is more effectively captured in wet FGD systems. If successfully developed, the process could be applicable to over 90,000 MW of utility generating capacity with existing FGD systems, and to future FGD installations. Field tests were conducted to determine whether candidate catalyst materials remain active towards mercury oxidation after extended flue gas exposure. Catalyst life will have a large impact on the cost effectiveness of this potential process. A mobile catalyst test unit was used to test the activity of four different catalyst materials for a period of up to six months each at three utility sites. Catalyst testing was completed at the first site, which fires Texas lignite, in December 1998; at the second test site, which fires a Powder River Basin subbituminous coal, in November 1999; and at the third site, which fires a medium- to high-sulfur bituminous coal, in January 2001. Results of testing at each of the three sites were reported in previous technical notes. At Site 1, catalysts were tested only as powders dispersed in sand bed reactors. At Sites 2 and 3, catalysts were tested in two forms, including powders dispersed in sand and in commercially available forms such as extruded pellets and coated honeycomb structures. This final report summarizes and presents results from all three sites, for the various catalyst forms tested. Field testing was supported by laboratory tests to screen catalysts for activity at specific flue gas compositions, to investigate catalyst deactivation mechanisms and methods for regenerating spent catalysts. Laboratory results are also summarized and discussed in this report.

Unknown

2001-06-01T23:59:59.000Z

359

NETL: News Release - Meeting Mercury Standards  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

June 18, 2001 June 18, 2001 Meeting Mercury Standards DOE Selects 6 Projects to Develop Cost-Saving Technologies for Curbing Mercury Emissions from Coal Power Plants Power Plant with Fish - MORGANTOWN, WV - With President Bush's National Energy Plan calling for mandatory reductions in the release of mercury from electric power plants - part of the Plan's multi-pollutant reduction strategy - the U.S. Department of Energy today named six new projects to develop innovative technologies that can curb mercury emissions from coal plants more effectively and at a fraction of today's costs. The winning projects were submitted by the University of North Dakota's Energy & Environmental Research Center in Grand Forks; URS Group. Inc., of Austin, TX; CONSOL, Inc., of Library, PA; Southern Research Institute in

360

Future trends in environmental mercury concentrations: implications  

E-Print Network [OSTI]

Future trends in environmental mercury concentrations: implications for prevention strategies interactions among natural and human climate system components; objectively assess uncertainty in economic, monitor and verify greenhouse gas emissions and climatic impacts. This reprint is one of a series intended

Note: This page contains sample records for the topic "mercury trace elements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Remediation of Mercury and Industrial Contaminants  

Broader source: Energy.gov [DOE]

The mission of the Remediation of Mercury and Industrial Contaminants Applied Field Research Initiative is to control the flux of contaminants in soil and water environments for the purpose of...

362

Filter for isotopic alteration of mercury vapor  

DOE Patents [OSTI]

A filter for enriching the .sup.196 Hg content of mercury, including a reactor, a low pressure electric discharge lamp containing a fill of mercury and an inert gas. A filter is arranged concentrically around the lamp. The reactor is arranged around said filter, whereby radiation from said lamp passes through the filter and into said reactor. The lamp, the filter and the reactor are formed of quartz, and are transparent to ultraviolet light. The .sup.196 Hg concentration in the mercury fill is less than that which is present in naturally occurring mercury, that is less than about 0.146 atomic weight percent. Hydrogen is also included in the fill and serves as a quenching gas in the filter, the hydrogen also serving to prevent disposition of a dark coating on the interior of the filter.

Grossman, Mark W. (Belmont, MA); George, William A. (Gloucestor, MA)

1989-01-01T23:59:59.000Z

363

Filter for isotopic alteration of mercury vapor  

DOE Patents [OSTI]

A filter is described for enriching the [sup 196]Hg content of mercury, including a reactor, a low pressure electric discharge lamp containing a fill of mercury and an inert gas. A filter is arranged concentrically around the lamp. The reactor is arranged around said filter, whereby radiation from said lamp passes through the filter and into said reactor. The lamp, the filter and the reactor are formed of quartz, and are transparent to ultraviolet light. The [sup 196]Hg concentration in the mercury fill is less than that which is present in naturally occurring mercury, that is, less than about 0.146 atomic weight percent. Hydrogen is also included in the fill and serves as a quenching gas in the filter, the hydrogen also serving to prevent disposition of a dark coating on the interior of the filter. 9 figs.

Grossman, M.W.; George, W.A.

1989-06-13T23:59:59.000Z

364

Mercury's Magnetosphere After MESSENGER's First Flyby  

Science Journals Connector (OSTI)

...IMF is unfavorable to dayside magnetic reconnection with Mercury's magnetic field and greatly limits the rate of solar wind energy transfer across the MP (2). The earlier southward IMF intervals before MESSENGER's entry into the magnetosphere...

James A. Slavin; Mario H. Acua; Brian J. Anderson; Daniel N. Baker; Mehdi Benna; George Gloeckler; Robert E. Gold; George C. Ho; Rosemary M. Killen; Haje Korth; Stamatios M. Krimigis; Ralph L. McNutt; Jr.; Larry R. Nittler; Jim M. Raines; David Schriver; Sean C. Solomon; Richard D. Starr; Pavel Trvn?ek; Thomas H. Zurbuchen

2008-07-04T23:59:59.000Z

365

Fate of Mercury in Synthetic Gypsum Used for Wallboard Production  

SciTech Connect (OSTI)

This report presents and discusses results from Task 5 of the study ''Fate of Mercury in Synthetic Gypsum Used for Wallboard Production,'' performed at a full-scale commercial wallboard plant. Synthetic gypsum produced by wet flue gas desulfurization (FGD) systems on coal-fired power plants is commonly used in the manufacture of wallboard. The FGD process is used to control the sulfur dioxide emissions which would result in acid rain if not controlled. This practice has long benefited the environment by recycling the FGD gypsum byproduct, which is becoming available in increasing quantities, decreasing the need to landfill this material, and increasing the sustainable design of the wallboard product. However, new concerns have arisen as recent mercury control strategies developed for power plants involve the capture of mercury in FGD systems. The objective of this study is to determine whether any mercury is released into the atmosphere when the synthetic gypsum material is used as a feedstock for wallboard production. The project is being co-funded by the U.S. DOE National Energy Technology Laboratory (Cooperative Agreement DE-FC26-04NT42080), USG Corporation, and EPRI. USG Corporation is the prime contractor, and URS Group is a subcontractor. The project scope includes five discrete tasks, each conducted at various USG wallboard plants using synthetic gypsum from different FGD systems. The five tasks were to include (1) a baseline test, then variations representing differing power plant (2) emissions control configurations, (3) treatment of fine gypsum particles, (4) coal types, and (5) FGD reagent types. However, Task 5, which was to evaluate gypsum produced from an alternate FGD reagent, could not be conducted as planned. Instead, Task 5 was conducted at conditions similar to a previous task, Task 3, although with gypsum from an alternate FGD system. In this project, process stacks in the wallboard plant have been sampled using the Ontario Hydro method. The stack locations sampled for each task include a dryer for the wet gypsum as it enters the plant and a gypsum calciner. The stack of the dryer for the wet wallboard product was also tested as part of this task, and was tested as part of Tasks 1 and 4. Also at each site, in-stream process samples were collected and analyzed for mercury concentration before and after each significant step in wallboard production. The Ontario Hydro results, process sample mercury concentration data, and process data were used to construct mercury mass balances across the wallboard plants. Task 5 was conducted at a wallboard plant processing synthetic gypsum from a power plant that fires Eastern bituminous coal. The power plant is equipped with a selective catalytic reduction (SCR) system for NOX emissions control, but the SCR was bypassed during the time period the gypsum tested was produced. The power plant has a single-loop, open spray tower, limestone reagent FGD system, with forced oxidation conducted in a reaction tank integral with the FGD absorber. The FGD system has gypsum fines blow down as part of the dewatering step. Gypsum fines blow down is believed to be an important variable that impacts the amount of mercury in the gypsum byproduct and possibly its stability during the wallboard process. The results of the Task 5 stack testing, as measured by the Ontario Hydro method, detected that an average of 51% of the incoming mercury in the FGD gypsum was emitted during wallboard production. These losses were distributed as 2% or less each across the wet gypsum dryer and product wallboard dryer, and about 50% across the gypsum calciner. Emissions were similar to what Task 3 results showed, on both a percentage and a mass basis, for gypsum produced by a power plant firing bituminous coal and also having gypsum fines blow down as part of the FGD dewatering scheme. As was seen in the Task 1 through 4 results, most of the mercury detected in the stack testing on the wet gypsum dryer and kettle calciner was in the form of elemental mercury. In the wallboard dryer kiln, a more signific

Jessica Marshall Sanderson

2006-06-01T23:59:59.000Z

366

Symplectic Integrator Mercury: Bug Report  

E-Print Network [OSTI]

We report on a problem found in MERCURY, a hybrid symplectic integrator used for dynamical problems in Astronomy. The variable that keeps track of bodies' statuses is uninitialised, which can result in bodies disappearing from simulations in a non-physical manner. Some FORTRAN compilers implicitly initialise variables, preventing simulations from having this problem. With other compilers, simulations with a suitably large maximum number of bodies parameter value are also unaffected. Otherwise, the problem manifests at the first event after the integrator is started, whether from scratch or continuing a previously stopped simulation. Although the problem does not manifest in some conditions, explicitly initialising the variable solves the problem in a permanent and unconditional manner.

K. de Souza Torres; D. R. Anderson

2008-08-04T23:59:59.000Z

367

Mercury bioaccumulation in Lavaca Bay, Texas  

E-Print Network [OSTI]

MERCURY BIOACCUMULATION IN LAVACA BAY, TEXAS A Thesis by SALLY JO PALMER Submitted to the Office of Graduate Studies of Texas ABM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August 1992 Major... Subject: Oceanography MERCURY BIOACCUMULATION IN LAVACA BAY, TEXAS A Thesis by SALLY JO PALMER Approved as to style and content by: obby J. Pr y (Chair of Committee) Robe J. Tayl (Member) owell (Member) Marvin W. Rowe (Member) Gi bert T. Rowe...

Palmer, Sally Jo

2012-06-07T23:59:59.000Z

368

Pilot Testing of Mercury Oxidation Catalysts for Upstream of Wet FGD Systems  

SciTech Connect (OSTI)

This final report presents and discusses results from a mercury control process development project entitled ''Pilot Testing of Mercury Oxidation Catalysts for Upstream of Wet FGD Systems''. The objective of this project was to demonstrate at pilot scale a mercury control technology that uses solid honeycomb catalysts to promote the oxidation of elemental mercury in the flue gas from coal combustion. Oxidized mercury is removed in downstream wet flue gas desulfurization (FGD) absorbers and leaves with the FGD byproducts. The goal of the project was to achieve 90% oxidation of elemental mercury in the flue gas and 90% overall mercury capture with the downstream wet FGD system. The project was co-funded by EPRI and the U.S. Department of Energy's National Energy Technology Laboratory (DOE NETL) under Cooperative Agreement DE-FC26-01NT41185. Great River Energy (GRE) and City Public Service (now CPS Energy) of San Antonio were also project co-funders and provided host sites. URS Group, Inc. was the prime contractor. Longer-term pilot-scale tests were conducted at two sites to provide catalyst life data. GRE provided the first site, at their Coal Creek Station (CCS), which fires North Dakota lignite, and CPS Energy provided the second site, at their Spruce Plant, which fires Powder River Basin (PRB) coal. Mercury oxidation catalyst testing began at CCS in October 2002 and continued through the end of June 2004, representing nearly 21 months of catalyst operation. An important finding was that, even though the mercury oxidation catalyst pilot unit was installed downstream of a high-efficiency ESP, fly ash buildup began to plug flue gas flow through the horizontal catalyst cells. Sonic horns were installed in each catalyst compartment and appeared to limit fly ash buildup. A palladium-based catalyst showed initial elemental mercury oxidation percentages of 95% across the catalyst, declining to 67% after 21 months in service. A carbon-based catalyst began with almost 98% elemental mercury oxidation across the catalyst, but declined to 79% oxidation after nearly 13 months in service. The other two catalysts, an SCR-type catalyst (titanium/vanadium) and an experimental fly-ash-based catalyst, were significantly less active. The palladium-based and SCR-type catalysts were effectively regenerated at the end of the long-term test by flowing heated air through the catalyst overnight. The carbon-based catalyst was not observed to regenerate, and no regeneration tests were conducted on the fourth, fly-ash-based catalyst. Preliminary process economics were developed for the palladium and carbon-based catalysts for a scrubbed, North Dakota lignite application. As described above, the pilot-scale results showed the catalysts could not sustain 90% or greater oxidation of elemental mercury in the flue gas for a period of two years. Consequently, the economics were based on performance criteria in a later DOE NETL solicitation, which required candidate mercury control technologies to achieve at least a 55% increase in mercury capture for plants that fire lignite. These economics show that if the catalysts must be replaced every two years, the catalytic oxidation process can be 30 to 40% less costly than conventional (not chemically treated) activated carbon injection if the plant currently sells their fly ash and would lose those sales with carbon injection. If the plant does not sell their fly ash, activated carbon injection was estimated to be slightly less costly. There was little difference in the estimated cost for palladium versus the carbon-based catalysts. If the palladium-based catalyst can be regenerated to double its life to four years, catalytic oxidation process economics are greatly improved. With regeneration, the catalytic oxidation process shows over a 50% reduction in mercury control cost compared to conventional activated carbon injection for a case where the plant sells its fly ash. At Spruce Plant, mercury oxidation catalyst testing began in September 2003 and continued through the end of April 2005, interrupted only by a

Richard Rhudy

2006-06-30T23:59:59.000Z

369

Glutathione peroxidase response in tissues of rats fed diets containing fish protein concentrate prepared from shark flesh of known mercury and selenium contents  

SciTech Connect (OSTI)

Studies have been reported using experimental animals and synthetic diets containing selenium and mercury compounds to demonstrate detoxification of mercury by selenium. The mechanism of detoxification remains obscure. Most experiments have involved the use of high levels of both elements and relied on the observation of gross symptoms. The measurement of enzyme systems may be useful in detecting effects of mercury at a lower, subclinical level and in elucidating the biochemistry of mercury/selenium interactions. The activity of the selenoenzyme glutathione peroxidase (GSH-Px) in rats is dependent on dietary selenium and attempts have been made to use this enzyme as an indicator of mercury/selenium interactions. The research described in this paper was designed to investigate the effect of mercury, in the form and amounts which occur naturally in seafood, on the availability of selenium at levels approximating the nutritional requirement. In anticipation of mercury lowering the GSH-Px response a range of selenium concentrations was used, from nutritional deficiency to three times the nutritional requirement.

Thrower, S.J. (Commonwealth Scientific and Industrial Research Organization, Hobart, Australia); Andrewartha, K.A.

1981-01-01T23:59:59.000Z

370

MeTAGeM-Trace: Improving trace generation in model transformation by leveraging the role of transformation models  

Science Journals Connector (OSTI)

Abstract In the context of Model-Driven Engineering (MDE), generation of traces can be automated using the implicit traceability relationships contained in any model transformation. Besides, if transformations are developed adopting a Model-Driven Engineering (MDE) approach, i.e. promoting the role of models and the level of automation, model transformation will benefit from the promised advantages of MDE in terms of less costly software development while reducing the inherent complexity of coding model transformations. To put these ideas into practice, this work introduces MeTAGeM-Trace, the first prototype of an EMF-based toolkit for the MDD of model-to-model transformations which supports trace generation, i.e. it allows developing model transformations that produce not only the corresponding target models, but also a trace model between the elements of the source and target models involved in the transformation.

lvaro Jimnez; Juan M. Vara; Vernica A. Bollati; Esperanza Marcos

2015-01-01T23:59:59.000Z

371

Ray-tracing for coordinate knowledge in the JWST Integrated Science Instrument Module  

Science Journals Connector (OSTI)

We describe the matrix/vector ray tracing methods used to maintain pupil and image position knowledge in the James Webb Space Telescope Optical Telescope Element Simulator. These prove...

Sabatke, Derek S

372

Long-Term Column Leaching of Phase II Mercury Control Technology By-Products  

SciTech Connect (OSTI)

An NETL research, development and demonstration program under DOE/Fossil Energy Innovations for Existing Plants is directed toward the improvement of the performance and economics of mercury control from coal-fired plants. The current Phase II of the RD&D program emphasizes the evaluation of performance and cost of control technologies through slip-stream and full scale field testing while continuing the development of novel concepts. One of the concerns of the NETL program is the fate of the captured flue gas mercury which is transferred to the condensed phase by-product stream. The stability of mercury and any co-captured elements in the by-products could have a large economic impact if it reduced by-product sales or increasing their disposal costs. As part of a greater characterization effort of Phase II facility baseline and control technology sample pairs, NETL in-house laboratories have performed continuous leaching of a select subset of the available sample pairs using four leachants: water (pH=5.7), dilute sulfuric acid (pH=1.2), dilute acetic acid (pH=2.9), and sodium carbonate (pH=11.1). This report describes results obtained for mercury, arsenic, and selenium during the 5-month leaching experiments.

Schroeder, K.T.; Cardone, C.R.; White, Fredrick; Rohar, P.C.; Kim, A.G

2007-07-01T23:59:59.000Z

373

Evaluation of Sorbent Injection for Mercury Control  

SciTech Connect (OSTI)

The power industry in the U.S. is faced with meeting new regulations to reduce the emissions of mercury compounds from coal-fired plants. These regulations are directed at the existing fleet of nearly 1,100 boilers. These plants are relatively old with an average age of over 40 years. Although most of these units are capable of operating for many additional years, there is a desire to minimize large capital expenditures because of the reduced (and unknown) remaining life of the plant to amortize the project. Injecting a sorbent such as powdered activated carbon into the flue gas represents one of the simplest and most mature approaches to controlling mercury emissions from coal-fired boilers. This is the final site report for tests conducted at Laramie River Station Unit 3, one of five sites evaluated in this DOE/NETL program. The overall objective of the test program is to evaluate the capabilities of activated carbon injection at five plants: Sunflower Electric's Holcomb Station Unit 1, AmerenUE's Meramec Station Unit 2, Missouri Basin Power Project's Laramie River Station Unit 3, Detroit Edison's Monroe Power Plant Unit 4, and AEP's Conesville Station Unit 6. These plants have configurations that together represent 78% of the existing coal-fired generation plants. The goals for the program established by DOE/NETL are to reduce the uncontrolled mercury emissions by 50 to 70% at a cost 25 to 50% lower than the benchmark established by DOE of $60,000/lb mercury removed. The goals of the program were exceeded at Laramie River Station by achieving over 90% mercury removal at a sorbent cost of $3,980/lb ($660/oz) mercury removed for a coal mercury content of 7.9 lb/TBtu.

Sharon Sjostrom

2005-12-30T23:59:59.000Z

374

Dissolved gaseous mercury behavior in shallow water estuaries  

E-Print Network [OSTI]

The formation of dissolved gaseous mercury (DGM) can be an important pathway for mercury removal from an aquatic environment. DGM evasional fluxes from an aquatic system can account for up to 95% of atmospheric Hg and its deposition pathways. While...

Landin, Charles Melchor

2009-05-15T23:59:59.000Z

375

Mitigation and Remediation of Mercury Contamination at the Y...  

Office of Environmental Management (EM)

Mitigation and Remediation of Mercury Contamination at the Y-12 Plant Oak Ridge Mitigation and Remediation of Mercury Contamination at the Y-12 Plant Oak Ridge Full Document and...

376

Mercury in the sediments of the Pallanza Basin  

Science Journals Connector (OSTI)

... Pallanza Basin of Lago Maggiore, Italy, in 1970 have been analysed for mercury, using flameless atomic absorption spectrophotometry. The concentration of mercury in the Maggiore sediments proved to be ...

V. DAMIANI; R. L. THOMAS

1974-10-25T23:59:59.000Z

377

Emission factor of mercury from coal-fired power stations  

Science Journals Connector (OSTI)

Mercury emission from coal-fired power stations, situated in Poland in the Silesian region ... mercury in the consumed coal and in combustion gas, used in this research, are described. ... the air from coal combu...

Wojciech Mniszek

1994-11-01T23:59:59.000Z

378

Seismic effects of the Caloris basin impact, Mercury  

E-Print Network [OSTI]

Striking geological features on Mercury's surface have been linked to tectonic disruption associated with the Caloris impact and have the potential to provide information on the interior structure of Mercury. The unusual ...

L, Jiangning

2011-01-01T23:59:59.000Z

379

Mercury Vapor At Kawaihae Area (Thomas, 1986) | Open Energy Information  

Open Energy Info (EERE)

Mercury Vapor At Kawaihae Area (Thomas, 1986) Mercury Vapor At Kawaihae Area (Thomas, 1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Kawaihae Area (Thomas, 1986) Exploration Activity Details Location Kawaihae Area Exploration Technique Mercury Vapor Activity Date Usefulness not useful DOE-funding Unknown Notes The soil geochemistry yielded quite complex patterns of mercury concentrations and radonemanation rates within the survey area (Cox and Cuff, 1981c). Mercury concentrations (Fig. 38) showed a general minimum along the Kawaihae-Waimea roads and a broad trend of increasing mercury concentrations toward both the north and south. There is no correlation apparent between the mercury patterns and either the resistivity sounding data or the surface geology in the area. The radon emanometry data (Fig.

380

MERCURY REMOVAL IN A NON-THERMAL, PLASMA-BASED MULTI-POLLUTANT CONTROL TECHNOLOGY FOR UTILITY BOILERS  

SciTech Connect (OSTI)

This technical report describes the results from Task 1 of the Cooperative Agreement. Powerspan has installed, tested, and validated Hg SCEMS systems for measuring oxidized and elemental mercury at the pilot facility at R.E. Burger Generating Station in Shadyside, Ohio. When operating properly, these systems are capable of providing near real-time monitoring of inlet and outlet gas flow streams and are capable of extracting samples from different locations to characterize mercury removal at these different ECO process stages. This report discusses the final configuration of the Hg CEM systems and the operating protocols that increase the reliability of the HG SCEM measurements. Documentation on the testing done to verify the operating protocols is also provided. In addition the report provides details on the protocols developed and used for measurement of mercury in process liquid streams and in captured ash.

Matthew B. Loomis

2004-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "mercury trace elements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Study of mercury oxidation by a selective catalytic reduction catalyst in a pilot-scale slipstream reactor at a utility boiler burning bituminous coal  

SciTech Connect (OSTI)

One of the cost-effective mercury control technologies in coal-fired power plants is the enhanced oxidation of elemental mercury in selective catalytic reduction (SCR) followed by the capture of the oxidized mercury in the wet scrubber. This paper is the first in a series of two in which the validation of the SCR slipstream test and Hg speciation variation in runs with or without SCR catalysts inside the SCR slipstream reactor under special gas additions (HCl, Cl{sub 2}, SO{sub 2}, and SO{sub 3}) are presented. Tests indicate that the use of a catalyst in a SCR slipstream reactor can achieve greater than 90% NO reduction efficiency with a NH{sub 3}/NO ratio of about 1. There is no evidence to show that the reactor material affects mercury speciation. Both SCR catalysts used in this study exhibited a catalytic effect on the elemental mercury oxidation but had no apparent adsorption effect. SCR catalyst 2 seemed more sensitive to the operational temperature. The spike gas tests indicated that HCl can promote Hg{sup 0} oxidation but not Cl{sub 2}. The effect of Cl{sub 2} on mercury oxidation may be inhibited by higher concentrations of SO{sub 2}, NO, or H{sub 2}O in real flue-gas atmospheres within the typical SCR temperature range (300-350{sup o}C). SO{sub 2} seemed to inhibit mercury oxidation; however, SO{sub 3} may have some effect on the promotion of mercury oxidation in runs with or without SCR catalysts. 25 refs., 9 figs., 2 tabs.

Yan Cao; Bobby Chen; Jiang Wu; Hong Cui; John Smith; Chi-Kuan Chen; Paul Chu; Wei-Ping Pan [Western Kentucky University, Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology (ICSET)

2007-01-15T23:59:59.000Z

382

Investigation of the relationship between particulate-bound mercury and properties of fly ash in a full-scale 100 MWe pulverized coal combustion boiler  

SciTech Connect (OSTI)

The properties of fly ash in coal-fired boilers influence the emission of mercury from power plants into the environment. In this study, seven different bituminous coals were burned in a full-scale 100 MWe pulverized coal combustion boiler and the derived fly ash samples were collected from a mechanical hopper (MH) and an electrostatic precipitator hopper (ESP). The mercury content, specific surface area (SSA), unburned carbon, and elemental composition of the fly ash samples were analyzed to evaluate the correlation between the concentration of particulate-bound mercury and the properties of coal and fly ash. For a given coal, it was found that the mercury content in the fly ash collected from the ESP was greater than in the fly ash samples collected from the MHP. This phenomenon may be due to a lower temperature of flue gas at the ESP (about 135{sup o}C) compared to the temperature at the air preheater (about 350{sup o}C). Also, a significantly lower SSA observed in MH ash might also contribute to the observation. A comparison of the fly ash samples generated from seven different coals using statistical methods indicates that the mercury adsorbed on ESP fly ashes has a highly positive correlation with the unburned carbon content, manganese content, and SSA of the fly ash. Sulfur content in coal showed a significant negative correlation with the Hg adsorption. Manganese in fly ash is believed to participate in oxidizing volatile elemental mercury (Hg{sup 0}) to ionic mercury (Hg{sup 2+}). The oxidized mercury in flue gas can form a complex with the fly ash and then get removed before the flue gas leaves the stack of the boiler.

Sen Li; Chin-Min Cheng; Bobby Chen; Yan Cao; Jacob Vervynckt; Amanda Adebambo; Wei-Ping Pan [Western Kentucky University, Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology

2007-12-15T23:59:59.000Z

383

Groundwater Discharge of Mercury to California Coastal Waters  

E-Print Network [OSTI]

leading to levels in some seafood that can be dangerous ifis all the mercury in seafood coming from? says Russell

Flegal, Russell; Paytan, Adina; Black, Frank

2009-01-01T23:59:59.000Z

384

BIOLOGICAL TRACE ELEMENT RESEARCH 6, 159-A Minireview  

E-Print Network [OSTI]

). 'Conver!iion from wet weight as!iuming 80% moisture. Biomagnification Biomagnification. the process wherl

Canberra, University of

385

A baseline characterization of trace elements in Texas soils  

E-Print Network [OSTI]

A baseline survey of concentrations of Mn, Fe, Zn, Cu, Se, As, Cd, Cr, Co, Pb, Ba, and Ni was performed for 100 soils from seven Land Resource Areas of Texas. Nearly 300 soil samples from the upper, middle, and lower depths of selected pedons were...

Frybarger, Mary Rita

2012-06-07T23:59:59.000Z

386

The Leaching of Major and Trace Elements from Coal Ash  

Science Journals Connector (OSTI)

Most power stations currently operate wet ash disposal systems. However, this method of ash disposal is being subjected to increasing scrutiny as there is a potential for contamination of surface and groundwat...

D. R. Jones

1995-01-01T23:59:59.000Z

387

Nondestructive indices of trace element exposure in squamate reptiles  

E-Print Network [OSTI]

a , J.W. Snodgrass c , B.P. Jackson a , D.E Kling a , C.L. Rowe d , J.D. Congdon a a Savannah River Ecology Laboratory, University of Georgia, Aiken, SC 29802, USA b Department of Biological Sciences, snakes were either fed ®sh from a coal ash-contaminated site or uncontaminated food from a reference site

Hopkins, William A.

388

Trace elements in prehispanic hair samples of Gran Canaria  

Science Journals Connector (OSTI)

In the present study we have analysed hair Zn, Cu, Fe, Mn, Sr, Pb and Ca contents of 8 prehispanic hair specimens from Gran Canaria, comparing them with 10 acutal samples,...

E. Gonzlez-Reimers; M. Arnay-de-la-Rosa; V. Castro-Alemn

1991-04-01T23:59:59.000Z

389

Impact of Closing Canadas Largest Point-Source of Mercury Emissions on Local Atmospheric Mercury Concentrations  

Science Journals Connector (OSTI)

(29) Solar radiation measurements at the airport were initiated in August 2010. ... Steffen, A.; Schroeder, W. Standard Operating Procedures for Total Gaseous Mercury MeasurementsCanadian Atmospheric Mercury Measurement Network (CAMNet); Environment Canada: Toronto, Canada, 1999. ...

Chris S. Eckley; Matthew T. Parsons; Rachel Mintz; Monique Lapalme; Maxwell Mazur; Robert Tordon; Robert Elleman; Jennifer A. Graydon; Pierrette Blanchard; Vincent St Louis

2013-08-26T23:59:59.000Z

390

Mercury: Supporting Scalable Multi-Attribute Range Queries  

E-Print Network [OSTI]

Mercury: Supporting Scalable Multi-Attribute Range Queries Ashwin R. Bharambe Mukesh Agrawal 15213 Abstract This paper presents the design of Mercury, a scalable protocol for supporting multi-attribute range- based searches. Mercury differs from previous range-based query systems in that it supports mul

Keinan, Alon

391

Mercury/Waterfilling for Fixed Wireless OFDM Angel Lozano  

E-Print Network [OSTI]

Mercury/Waterfilling for Fixed Wireless OFDM Systems Angel Lozano Bell Labs (Lucent Technologies- mation is then given by the more general mercury/waterfilling policy. This paper illustrates the usance of mercury/waterfilling on frequency-selective OFDM channels with QAM constellations and it quantifies

Verdú, Sergio

392

MERCURY HANDLING FOR THE TARGET SYSTEM FOR A MUON COLLIDER  

E-Print Network [OSTI]

MERCURY HANDLING FOR THE TARGET SYSTEM FOR A MUON COLLIDER (IPAC12, WEPPD038) The target station a 15-20 T superconducting magnet. The target itself is a free mercury jet, moving at 20 m/s at an small angle to the magnetic axis, so as later to be collected in a mercury pool/beam dump. The replaceable

McDonald, Kirk

393

Powering Mercury's dynamo J.-P. Williams,1  

E-Print Network [OSTI]

Powering Mercury's dynamo J.-P. Williams,1 O. Aharonson,1 and F. Nimmo2 Received 6 July 2007 magnetic field of Mercury has implications for the interior structure of the planet and its thermal (2007), Powering Mercury's dynamo, Geophys. Res. Lett., 34, L21201, doi:10.1029/ 2007GL031164. 1

Nimmo, Francis

394

2003 Mercury Computer Systems, Inc. Session 5: Current &  

E-Print Network [OSTI]

© 2003 Mercury Computer Systems, Inc. Session 5: Current & Emerging Standards Session 5: Current & Emerging Standards Craig Lund, Chief Technology Officer Mercury Computer Systems, Inc. High Performance Embedded Computing (HPEC) Conference September 2003 #12;© 2003 Mercury Computer Systems, Inc. Agenda

Kepner, Jeremy

395

Wednesday, March 25, 2009 SPECIAL SESSION: MESSENGER AT MERCURY  

E-Print Network [OSTI]

Wednesday, March 25, 2009 SPECIAL SESSION: MESSENGER AT MERCURY: A GLOBAL PERSPECTIVE. T. MESSENGER's Newly Global Perspective on Mercury: Some Implications for Interior Evolution [#1750] MESSENGER's first two flybys of Mercury have revealed a planet with a richer history of magmatism

Rathbun, Julie A.

396

Exploring Mercury: Scientific Results from the MESSENGER Mission  

E-Print Network [OSTI]

#12;Exploring Mercury: Scientific Results from the MESSENGER Mission Larry R. Nittler Carnegie-Cahill · MESSENGER Science Team, Engineers, Mission Operations (APL) #12;Mars Mercury · Naked-eye planet, but very difficult to observe due to proximity to Sun May 12, 2011, from NZ (M. White, Flickr) Mercury Venus Jupiter

Rhoads, James

397

2003 Mercury Computer Systems, Inc. Beamforming for Radar  

E-Print Network [OSTI]

© 2003 Mercury Computer Systems, Inc. Beamforming for Radar Systems on COTS Heterogeneous ComputingHeterogeneous Computing PlatformsPlatforms Jeffrey A. Rudin Mercury Computer Systems, Inc. High Performance Embedded Computing (HPEC) Conference September 23, 2003 #12;2© 2003 Mercury Computer Systems, Inc. Outline

Kepner, Jeremy

398

MERCURY IN THE ATMOSPHERE, BIOSPHERE, AND POLICY SPHERE  

E-Print Network [OSTI]

MERCURY IN THE ATMOSPHERE, BIOSPHERE, AND POLICY SPHERE: Insights from a global 3D land.S. National Science Foundation Atmospheric Chemistry Program #12;FROM ATMOSPHERE TO FISH: MERCURY RISING Ice core from Wyoming [Schuster et al., ES&T 2002] Mercury deposition has increased by 300% since

Selin, Noelle Eckley

399

Mercury Beam Dump Simulations Tristan Davenne Ottone Caretta  

E-Print Network [OSTI]

Mercury Beam Dump Simulations Tristan Davenne Ottone Caretta STFC Rutherford Appleton Laboratory, UK 2nd Princeton-Oxford High Power Target Meeting 6-7 November-2008 #12;Mercury beam dump design from NUFACT Feasibility Study #12;Peter Loveridge, November-2008 Mercury beam dump design from NUFACT

McDonald, Kirk

400

Mercury Concentrations in Fish from the San Francisco Bay Area  

E-Print Network [OSTI]

Mercury Concentrations in Fish from the San Francisco Bay Area San Francisco Bay Regional Water on composite samples · Some mercury analysis on individual largemouth bass · Size targets #12;Tomales Bay Study chemical analyses (Hg and organics) conducted on composite samples · Some mercury analysis on individual

Note: This page contains sample records for the topic "mercury trace elements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Mercury's thermo-chemical evolution from numerical models constrained  

E-Print Network [OSTI]

Mercury's thermo-chemical evolution from numerical models constrained by MESSENGER observations Globe de Paris, France #12;Basics facts about Mercury · Semi-major axis: 0.39 AU · 3:2 spin Earth!) · Black body temperature: 440 K #12;Exploration of Mercury Mariner10 ·First spacecraft to use

Cerveny, Vlastislav

402

Mercury exosphere I. Global circulation model of its sodium component  

E-Print Network [OSTI]

Mercury exosphere I. Global circulation model of its sodium component Francois Leblanc a,*, R 2010 Accepted 27 April 2010 Available online 5 May 2010 Keywords: Mercury, Atmosphere Aeronomy a b s t r a c t Our understanding of Mercury's sodium exosphere has improved considerably in the last 5

Johnson, Robert E.

403

Mercury warning given to north state anglers By Ryan Sabalow  

E-Print Network [OSTI]

Mercury warning given to north state anglers By Ryan Sabalow Monday, June 7, 2010 A new study the highest levels of mercury contamination in the state. Although anglers arent being warned to wean,905 fish in 272 of Californias popular lakes and reservoirs for mercury, PCBs, DDT and other contaminants

404

Mercury reuses several external software tools developed by ORNL  

E-Print Network [OSTI]

Mercury reuses several external software tools developed by ORNL DAAC and other organizations-on,canopychemistryaccpclimatecollectionseoslandvalidationFIFEFIFEfollow-on fluxnethydroclimatologycollectionsmodelarchivenetprimaryproductivityNPPNBIIMAST- DCUSANPNIABINDataONEWENDI Mercury's architecture includes 1) a harvesting engine was packaged in such a way that all the Mercury projects will use the same harvester scripts, but each project

405

Mercury and Freon: Temperature Emulation and Management for Server Systems  

E-Print Network [OSTI]

Mercury and Freon: Temperature Emulation and Management for Server Systems Taliver Heath Dept by simulators and real measurements. In this paper, we introduce Mercury, a soft- ware suite that avoids data. Most importantly, Mercury runs the entire software stack natively, enables repeatable experiments

Bianchini, Ricardo

406

Thursday, March 26, 2009 POSTER SESSION II: MERCURY  

E-Print Network [OSTI]

Thursday, March 26, 2009 POSTER SESSION II: MERCURY 6:30 p.m. Town Center Exhibit Area Gómez-Perez N. Wicht J. Magnetic Field at Mercury: Effects of External Sources on Planetary Dynamos [#1634] In Mercury, magnetospheric currents induce a magnetic field at the top of the core. We study dynamo

Rathbun, Julie A.

407

Mercury: Supporting Scalable Multi-Attribute Range Ashwin R. Bharambe  

E-Print Network [OSTI]

Mercury: Supporting Scalable Multi-Attribute Range Queries Ashwin R. Bharambe ashu Carnegie Mellon University Pittsburgh, PA 15213 ABSTRACT This paper presents the design of Mercury, a scalable pro- tocol for supporting multi-attribute range-based searches. Mercury differs from previous

Krishnamurthy, Arvind

408

Mercury Beam Dump Simulations Tristan Davenne Ottone Caretta Chris Densham  

E-Print Network [OSTI]

Mercury Beam Dump Simulations Tristan Davenne Ottone Caretta Chris Densham STFC Rutherford Appleton Laboratory, UK 1st joint meeting of EUROnu WP2 (Superbeam) and NF-IDS target 15-17 December-2008 #12;Mercury beam dump design from NUFACT Feasibility Study #12;Peter Loveridge, November-2008 Mercury beam dump

McDonald, Kirk

409

MERCURY IN THE ATMOSPHERE, BIOSPHERE, AND POLICY SPHERE  

E-Print Network [OSTI]

MERCURY IN THE ATMOSPHERE, BIOSPHERE, AND POLICY SPHERE: Insights from global modeling Noelle Atmospheric Chemistry Program #12;FROM ATMOSPHERE TO FISH: MERCURY RISING Ice core from Wyoming [Schuster et al., ES&T 2002] Mercury deposition has increased by 300% since industrialization Major anthropogenic

Selin, Noelle Eckley

410

Tuesday, March 14, 2006 POSTER SESSION I: MERCURY  

E-Print Network [OSTI]

Tuesday, March 14, 2006 POSTER SESSION I: MERCURY 7:00 p.m. Fitness Center Helbert J. Moroz L. V for the MERTIS Instrument on the ESA BepiColombo Mission to Mercury [#1662] The MERTIS instrument on BepiColombo will study the surface of Mercury in the TIR. We will present a list of analog material compiled to support

Rathbun, Julie A.

411

MERCURY IN THE ATMOSPHERE, BIOSPHERE, AND POLICY SPHERE  

E-Print Network [OSTI]

MERCURY IN THE ATMOSPHERE, BIOSPHERE, AND POLICY SPHERE: Insights from Global Modeling Noelle #12;MERCURY IN THE ENVIRONMENT: OUTLINE 1. Deposition to the United States results from a mix of local and global sources, depending on the location 2. Historical and present releases of mercury will continue

Selin, Noelle Eckley

412

MESSENGER observations of magnetopause structure and dynamics at Mercury  

E-Print Network [OSTI]

MESSENGER observations of magnetopause structure and dynamics at Mercury Gina A. DiBraccio,1 James December 2012; accepted 10 January 2013; published 1 March 2013. [1] On 18 March 2011, MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) became the first spacecraft to orbit Mercury

Salzman, Daniel

413

Optical frequency standards based on mercury and aluminum ions  

E-Print Network [OSTI]

Optical frequency standards based on mercury and aluminum ions W. M. Itano, J. C. Bergquist, A-16 . Keywords: aluminum, atomic clocks, frequency standards, ion traps, mercury 1. INTRODUCTION Optical frequency standards based on the mercury ion and, more recently, the aluminum ion are under devel- opment

414

Environmental and health aspects of lighting: Mercury  

SciTech Connect (OSTI)

Most discharge lamps, including fluorescent lamps, metal halide lamps, and high pressure sodium lamps, contain Mercury, a toxic chemical. Lighting professionals need to be able to respond to questions about the direct hazards of Mercury from accidentally breaking lamps, and the potential environmental hazards of lamp operation and disposal. We calculated the exposures that could occur from an accidental breakage of lamps. Acute poisoning appears almost impossible. Under some circumstances a sealed environment, such as a space station, could be contaminated enough to make it unhealthy for long-term occupation. Mercury becomes a potential environmental hazard after it becomes methylated. Mercury is methylated in aquatic environments, where it may accumulate in fish, eventually rendering them toxic to people and other animals. Lighting causes Mercury to enter the environment directly from lamp disposal, and indirectly from power plant emissions. The environmental tradeoffs between incandescent and discharge lamps depend upon the amounts released by these two sources, their local concentrations, and their probabilities of being methylated. Indirect environmental effects of lighting also include the release of other heavy metals (Cadmium, Lead and Arsenic), and other air pollutants and carbon dioxide that are emitted by fossil fuel power plants. For a given light output, the level of power plant emissions depends upon the efficacy of the light source, and is thus much larger for incandescent lamps than for fluorescent or discharge lamps. As disposal and control technologies change the relative direct and indirect emissions from discharge and incandescent lamps will change.

Clear, R.; Berman, S.

1993-07-01T23:59:59.000Z

415

FIELD TEST PROGRAM TO DEVELOP COMPREHENSIVE DESIGN, OPERATING, AND COST DATA FOR MERCURY CONTROL SYSTEMS  

SciTech Connect (OSTI)

With the Nation's coal-burning utilities facing the possibility of tighter controls on mercury pollutants, the U.S. Department of Energy is funding projects that could offer power plant operators better ways to reduce these emissions at much lower costs. Mercury is known to have toxic effects on the nervous system of humans and wildlife. Although it exists only in trace amounts in coal, mercury is released when coal burns and can accumulate on land and in water. In water, bacteria transform the metal into methylmercury, the most hazardous form of the metal. Methylmercury can collect in fish and marine mammals in concentrations hundreds of thousands times higher than the levels in surrounding waters. One of the goals of DOE is to develop technologies by 2005 that will be capable of cutting mercury emissions 50 to 70 percent at well under one-half of today's costs. ADA Environmental Solutions (ADA-ES) is managing a project to test mercury control technologies at full scale at four different power plants from 2000--2003. The ADA-ES project is focused on those power plants that are not equipped with wet flue gas desulfurization systems. ADA-ES has developed a portable system that will be tested at four different utility power plants. Each of the plants is equipped with either electrostatic precipitators or fabric filters to remove solid particles from the plant's flue gas. ADA-ES's technology will inject a dry sorbent, such as activated carbon, which removes the mercury and makes it more susceptible to capture by the particulate control devices. A fine water mist may be sprayed into the flue gas to cool its temperature to the range where the dry sorbent is most effective. PG&E National Energy Group is providing two test sites that fire bituminous coals and both are equipped with electrostatic precipitators and carbon/ash separation systems. Wisconsin Electric Power Company is providing a third test site that burns Powder River Basin (PRB) coal and has an electrostatic precipitator for particulate control. Alabama Power Company will host a fourth test at its Plant Gaston, which is equipped with a hot-side electrostatic precipitator and a downstream fabric filter.

Michael D. Durham

2003-05-01T23:59:59.000Z

416

Mercury Absorption in Aqueous Oxidants Catalyzed by Mercury(II) Lynn L. Zhao and Gary T. Rochelle*  

E-Print Network [OSTI]

Mercury Absorption in Aqueous Oxidants Catalyzed by Mercury(II) Lynn L. Zhao and Gary T. Rochelle no immediate effect on mercury removal. In 0.8 M HNO3 with the addition of K2Cr2O7, the reaction is first at 25 °C. For mercury absorption in Hg(II) obtained by HgCl2 injection, the presence of HNO3 greatly

Rochelle, Gary T.

417

In Situ Mercury Stabilization (ISMS) Treatment: Technology Maturation Project Phase I Status Report  

SciTech Connect (OSTI)

Mercury (Hg) was used to separate lithium-6 isotope for weapons production at the Y-12 Plant in Oak Ridge in the 1950s and 1960s. As much as two million pounds of elemental mercury was 'lost' or unaccounted for and a large portion of that material is believed to have entered the environment. The DOE site office in Oak Ridge has identified Hg pollution in soils, sediments, and streams as the most significant environmental challenge currently faced. In industry, large amounts of mercury have been used to manufacture products (e.g., fluorescent light bulbs, thermometers) and for chemical processing (e.g., production of chlorine and alkali via mercury electrochemical cells) and many of these industrial sites are now polluted with mercury contaminated soil as a result of previous releases and/or inadvertent leaks. Remediation techniques for Hg contaminated soils are either based on thermal desorption and recovery of the mercury or excavation and shipping of large volumes of material to remote facilities for treatment and disposal. Both of these alternatives are extremely costly. The Brookhaven National Laboratory (BNL) Environmental Research & Technology Division (ERTD) has demonstrated, in laboratory-scale experiments, the viability of treating mercury contaminated soils by means of sulfide treatment rods inserted into the soil through a process known as In Situ Mercury Stabilization (ISMS). This approach is partly based on BNL's patented and successfully licensed ex situ process for Hg treatment, Sulfur Polymer Stabilization/Solidification (SPSS) which converts Hg to the more stable sulfide form. The original experiments showed that Hg homogeneously distributed in soil rapidly migrates to form a high concentration zone of chemically stable mercuric sulfide near the treatment rods while concentrations of Hg in surrounding areas away from the treatment rods are depleted to acceptable levels. BSA has subsequently filed for patent protection on the ISMS technology. If further developed it has the potential for large-scale in-situ treatment of contaminated soils that could substantially reduce the prohibitive cost of thermal desorption and/or excavation and disposal. Licensing and spin-off technology development opportunities would then be viable. Depending on performance and regulatory acceptance, the treated mercury could either be excavated for disposal elsewhere or left in place as a stable alternative. Excavated spent treatment rods could be processed by the SPSS process to reduce the potential for dispersion and lower leachability even further. The Phase I objectives of the In Situ Mercury Stabilization Treatment Process Technology Maturation Project were to: (1) replicate the original bench-scale results that formed the basis for BNL's patent application, i.e., mercury contamination in soil will migrate to and react with 'rods' containing sulfur and/or sulfur compounds, (2) provide enough information to evaluate a decision to conduct further development, and (3) establish some of the critical parameters that require further technology maturation during Phase II. The information contained in this report summarizes the work conducted in Phase I to meet these objectives.

Kalb,P.D.; Milian, L.

2008-03-01T23:59:59.000Z

418

Simultaneous Removal of NOx and Mercury in Low Temperature Selective Catalytic and Adsorptive Reactor  

SciTech Connect (OSTI)

The results of a 18-month investigation to advance the development of a novel Low Temperature Selective Catalytic and Adsorptive Reactor (LTSCAR), for the simultaneous removal of NO{sub x} and mercury (elemental and oxidized) from flue gases in a single unit operation located downstream of the particulate collectors, are reported. In the proposed LTSCAR, NO{sub x} removal is in a traditional SCR mode but at low temperature, and, uniquely, using carbon monoxide as a reductant. The concomitant capture of mercury in the unit is achieved through the incorporation of a novel chelating adsorbent. As conceptualized, the LTSCAR will be located downstream of the particulate collectors (flue gas temperature 140-160 C) and will be similar in structure to a conventional SCR. That is, it will have 3-4 beds that are loaded with catalyst and adsorbent allowing staged replacement of catalyst and adsorbent as required. Various Mn/TiO{sub 2} SCR catalysts were synthesized and evaluated for their ability to reduce NO at low temperature using CO as the reductant. It has been shown that with a suitably tailored catalyst more than 65% NO conversion with 100% N{sub 2} selectivity can be achieved, even at a high space velocity (SV) of 50,000 h-1 and in the presence of 2 v% H{sub 2}O. Three adsorbents for oxidized mercury were developed in this project with thermal stability in the required range. Based on detailed evaluations of their characteristics, the mercaptopropyltrimethoxysilane (MPTS) adsorbent was found to be most promising for the capture of oxidized mercury. This adsorbent has been shown to be thermally stable to 200 C. Fixed-bed evaluations in the targeted temperature range demonstrated effective removal of oxidized mercury from simulated flue gas at very high capacity ({approx}>58 mg Hg/g adsorbent). Extension of the capability of the adsorbent to elemental mercury capture was pursued with two independent approaches: incorporation of a novel nano-layer on the surface of the chelating mercury adsorbent to achieve in situ oxidation on the adsorbent, and the use of a separate titania-supported manganese oxide catalyst upstream of the oxidized mercury adsorbent. Both approaches met with some success. It was demonstrated that the concept of in situ oxidation on the adsorbent is viable, but the future challenge is to raise the operating capacity beyond the achieved limit of 2.7 mg Hg/g adsorbent. With regard to the manganese dioxide catalyst, elemental mercury was very efficiently oxidized in the absence of sulfur dioxide. Adequate resistance to sulfur dioxide must be incorporated for the approach to be feasible in flue gas. A preliminary benefits analysis of the technology suggests significant potential economic and environmental advantages.

Neville G. Pinto; Panagiotis G. Smirniotis

2006-03-31T23:59:59.000Z

419

NETL: Mercury Emissions Control Technologies - Advanced Utility  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Advanced Utility Mercury-Sorbent Field Testing Program Advanced Utility Mercury-Sorbent Field Testing Program Sorbent Technologies Corporation, will test an advanced halgenated activated carbon to determine the mercury removal performance and relative costs of sorbent injection for advanced sorbent materials in large-scale field trials of a variety of combinations of coal-type and utility plant-configuration. These include one site (Detroit Edison's St. Clair Station) with a cold-side ESP using subbituminous coal, or blend of subbituminous and bituminous coal, and one site (Duke Energy's Buck Plant) with a hot-side ESP which burns a bituminous coal. Related Papers and Publications: Semi-Annual Technical Progress Report for the period April 1 - October 31, 2004 [PDF-2275KB] Semi-Annual Technical Progress Report for the period of October 2003 - March 2004 [PDF-1108KB]

420

Geochemical, Genetic, and Community Controls on Mercury  

SciTech Connect (OSTI)

The sulfate-reducing bacteria (SRB) are soil bacteria that share two common characteristics, strict anaerobiosis and the ability to respire sulfate. The metabolic activities of these bacteria play significant roles in the global sulfur cycle, anaerobic degradation of biomass, biological metal corrosion in the environment and, recently, degradation of toxic compounds. The accumulation of evidence suggests these bacteria are also key to the production of the neurotoxin methylmercury in environmental settings. We propose to use our experience with the development of genetics in sulfate-reducing bacteria of the genus Desulfovibrio to create mutations that will eliminate the methylation of mercury, thereby identifying the genes essential for this process. This information may allow the environmental monitoring of the mercury methylation potential to learn the location and quantity of the production this toxin. From these data, more accurate predictive models of mercury cycling can be generated.

Wall, Judy D.

2014-11-10T23:59:59.000Z

Note: This page contains sample records for the topic "mercury trace elements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

It's Elemental - The Element Europium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Samarium Samarium Previous Element (Samarium) The Periodic Table of Elements Next Element (Gadolinium) Gadolinium The Element Europium [Click for Isotope Data] 63 Eu Europium 151.964 Atomic Number: 63 Atomic Weight: 151.964 Melting Point: 1095 K (822°C or 1512°F) Boiling Point: 1802 K (1529°C or 2784°F) Density: 5.24 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 6 Group Number: none Group Name: Lanthanide What's in a name? Named after the continent of Europe. Say what? Europium is pronounced as yoo-RO-pee-em. History and Uses: Europium was discovered by Eugène-Antole Demarçay, a French chemist, in 1896. Demarçay suspected that samples of a recently discovered element, samarium, were contaminated with an unknown element. He was able to produce

422

It's Elemental - The Element Potassium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Argon Argon Previous Element (Argon) The Periodic Table of Elements Next Element (Calcium) Calcium The Element Potassium [Click for Isotope Data] 19 K Potassium 39.0983 Atomic Number: 19 Atomic Weight: 39.0983 Melting Point: 336.53 K (63.38°C or 146.08°F) Boiling Point: 1032 K (759°C or 1398°F) Density: 0.89 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 4 Group Number: 1 Group Name: Alkali Metal What's in a name? From the English word potash. Potassium's chemical symbol comes from the Latin word for alkali, kalium. Say what? Potassium is pronounced as poh-TASS-ee-em. History and Uses: Although potassium is the eighth most abundant element on earth and comprises about 2.1% of the earth's crust, it is a very reactive element

423

It's Elemental - The Element Sulfur  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Phosphorus Phosphorus Previous Element (Phosphorus) The Periodic Table of Elements Next Element (Chlorine) Chlorine The Element Sulfur [Click for Isotope Data] 16 S Sulfur 32.065 Atomic Number: 16 Atomic Weight: 32.065 Melting Point: 388.36 K (115.21°C or 239.38°F) Boiling Point: 717.75 K (444.60°C or 832.28°F) Density: 2.067 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Non-metal Period Number: 3 Group Number: 16 Group Name: Chalcogen What's in a name? From the Sanskrit word sulvere and the Latin word sulphurium. Say what? Sulfur is pronounced as SUL-fer. History and Uses: Sulfur, the tenth most abundant element in the universe, has been known since ancient times. Sometime around 1777, Antoine Lavoisier convinced the rest of the scientific community that sulfur was an element. Sulfur is a

424

It's Elemental - The Element Magnesium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sodium Sodium Previous Element (Sodium) The Periodic Table of Elements Next Element (Aluminum) Aluminum The Element Magnesium [Click for Isotope Data] 12 Mg Magnesium 24.3050 Atomic Number: 12 Atomic Weight: 24.3050 Melting Point: 923 K (650°C or 1202°F) Boiling Point: 1363 K (1090°C or 1994°F) Density: 1.74 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 3 Group Number: 2 Group Name: Alkaline Earth Metal What's in a name? For Magnesia, a district in the region of Thessaly, Greece. Say what? Magnesium is pronounced as mag-NEE-zhi-em. History and Uses: Although it is the eighth most abundant element in the universe and the seventh most abundant element in the earth's crust, magnesium is never found free in nature. Magnesium was first isolated by Sir Humphry Davy, an

425

THEORY OF SECULAR CHAOS AND MERCURY'S ORBIT  

SciTech Connect (OSTI)

We study the chaotic orbital evolution of planetary systems, focusing on secular (i.e., orbit-averaged) interactions, which dominate on long timescales. We first focus on the evolution of a test particle that is forced by multiple planets. To linear order in eccentricity and inclination, its orbit precesses with constant frequencies. But nonlinearities modify the frequencies, and can shift them into and out of resonance with either the planets' eigenfrequencies (forming eccentricity or inclination secular resonances), or with linear combinations of those frequencies (forming mixed high-order secular resonances). The overlap of these nonlinear secular resonances drives secular chaos. We calculate the locations and widths of nonlinear secular resonances, display them together on a newly developed map (the 'map of the mean momenta'), and find good agreement between analytical and numerical results. This map also graphically demonstrates how chaos emerges from overlapping secular resonances. We then apply this newfound understanding to Mercury to elucidate the origin of its orbital chaos. We find that since Mercury's two free precession frequencies (in eccentricity and inclination) lie within {approx}25% of two other eigenfrequencies in the solar system (those of the Jupiter-dominated eccentricity mode and the Venus-dominated inclination mode), secular resonances involving these four modes overlap and cause Mercury's chaos. We confirm this with N-body integrations by showing that a slew of these resonant angles alternately librate and circulate. Our new analytical understanding allows us to calculate the criterion for Mercury to become chaotic: Jupiter and Venus must have eccentricity and inclination of a few percent. The timescale for Mercury's chaotic diffusion depends sensitively on the forcing. As it is, Mercury appears to be perched on the threshold for chaos, with an instability timescale comparable to the lifetime of the solar system.

Lithwick, Yoram [Department of Physics and Astronomy, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208 (United States); Wu Yanqin [Department of Astronomy and Astrophysics, University of Toronto, Toronto, ON M5S 3H4 (Canada)

2011-09-20T23:59:59.000Z

426

Mercury Vapor At Haleakala Volcano Area (Thomas, 1986) | Open Energy  

Open Energy Info (EERE)

Mercury Vapor At Haleakala Volcano Area (Thomas, 1986) Mercury Vapor At Haleakala Volcano Area (Thomas, 1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Haleakala Volcano Area (Thomas, 1986) Exploration Activity Details Location Haleakala Volcano Area Exploration Technique Mercury Vapor Activity Date Usefulness not indicated DOE-funding Unknown Notes The field survey program on the northwest rift zone consisted of soil mercury and radon emanometry surveys, groundwater temperature and chemistry studies, Schlumberger resistivity soundings and self-potential profiles. Geophysical and geochemical surveys along this rift (southwest) were limited by difficult field conditions and access limitations. The geophysical program consisted of one Schlumberger sounding, one

427

Sorbents for the oxidation and removal of mercury  

DOE Patents [OSTI]

A promoted activated carbon sorbent is described that is highly effective for the removal of mercury from flue gas streams. The sorbent comprises a new modified carbon form containing reactive forms of halogen and halides. Optional components may be added to increase reactivity and mercury capacity. These may be added directly with the sorbent, or to the flue gas to enhance sorbent performance and/or mercury capture. Mercury removal efficiencies obtained exceed conventional methods. The sorbent can be regenerated and reused. Sorbent treatment and preparation methods are also described. New methods for in-flight preparation, introduction, and control of the active sorbent into the mercury contaminated gas stream are described.

Olson, Edwin S. (Grand Forks, ND); Holmes, Michael J. (Thompson, ND); Pavlish, John H. (East Grand Forks, MN)

2008-10-14T23:59:59.000Z

428

Sorbents for the oxidation and removal of mercury  

DOE Patents [OSTI]

A promoted activated carbon sorbent is described that is highly effective for the removal of mercury from flue gas streams. The sorbent comprises a new modified carbon form containing reactive forms of halogen and halides. Optional components may be added to increase reactivity and mercury capacity. These may be added directly with the sorbent, or to the flue gas to enhance sorbent performance and/or mercury capture. Mercury removal efficiencies obtained exceed conventional methods. The sorbent can be regenerated and reused. Sorbent treatment and preparation methods are also described. New methods for in-flight preparation, introduction, and control of the active sorbent into the mercury contaminated gas stream are described.

Olson, Edwin S.; Holmes, Michael J.; Pavlish, John Henry

2014-09-02T23:59:59.000Z

429

Method for high temperature mercury capture from gas streams  

DOE Patents [OSTI]

A process to facilitate mercury extraction from high temperature flue/fuel gas via the use of metal sorbents which capture mercury at ambient and high temperatures. The spent sorbents can be regenerated after exposure to mercury. The metal sorbents can be used as pure metals (or combinations of metals) or dispersed on an inert support to increase surface area per gram of metal sorbent. Iridium and ruthenium are effective for mercury removal from flue and smelter gases. Palladium and platinum are effective for mercury removal from fuel gas (syngas). An iridium-platinum alloy is suitable for metal capture in many industrial effluent gas streams including highly corrosive gas streams.

Granite, E.J.; Pennline, H.W.

2006-04-25T23:59:59.000Z

430

Compound and Elemental Analysis At Kilauea East Rift Geothermal...  

Open Energy Info (EERE)

(XRF). The samples were made into thin sections as well as ground in a tungsten carbide grinding mill. A table of trace elements and amounts found during the analysis is...

431

Heat-Traced Fluid Transfer Lines  

E-Print Network [OSTI]

This paper discusses basic considerations in designing a heat tracing system using either team or electrical tracing. Four basic reasons to heat trace are dealt with: water freeze protection, chemical freeze protection, viscosity maintenance...

Schilling, R. E.

1984-01-01T23:59:59.000Z

432

Tracing Geothermal Fluids  

SciTech Connect (OSTI)

Geothermal water must be injected back into the reservoir after it has been used for power production. Injection is critical in maximizing the power production and lifetime of the reservoir. To use injectate effectively the direction and velocity of the injected water must be known or inferred. This information can be obtained by using chemical tracers to track the subsurface flow paths of the injected fluid. Tracers are chemical compounds that are added to the water as it is injected back into the reservoir. The hot production water is monitored for the presence of this tracer using the most sensitive analytic methods that are economically feasible. The amount and concentration pattern of the tracer revealed by this monitoring can be used to evaluate how effective the injection strategy is. However, the tracers must have properties that suite the environment that they will be used in. This requires careful consideration and testing of the tracer properties. In previous and parallel investigations we have developed tracers that are suitable from tracing liquid water. In this investigation, we developed tracers that can be used for steam and mixed water/steam environments. This work will improve the efficiency of injection management in geothermal fields, lowering the cost of energy production and increasing the power output of these systems.

Michael C. Adams; Greg Nash

2004-03-01T23:59:59.000Z

433

Laboratory scale studies of Pd/{gamma}-Al{sub 2}O{sub 3} sorbents for the removal of trace contaminants from coal-derived fuel gas at elevated temperatures  

SciTech Connect (OSTI)

The Integrated Gasification Combined Cycle (IGCC) is a promising technology for the use of coal in a clean and efficient manner. In order to maintain the overall efficiency of the IGCC process, it is necessary to clean the fuel gas of contaminants (sulfur, trace compounds) at warm (150540 C) to hot (>540 C) temperatures. Current technologies for trace contaminant (such as mercury) removal, primarily activated carbon based sorbents, begin to lose effectiveness above 100 C, creating the need to develop sorbents effective at elevated temperatures. As trace elements are of particular environmental concern, previous work by this group has focused on the development of a Pd/?-Al{sub 2}O{sub 3} sorbent for Hg removal. This paper extends the research to Se (as hydrogen selenide, H{sub 2}Se), As (as arsine, AsH{sub 3}), and P (as phosphine, PH{sub 3}) which thermodynamic studies indicate are present as gaseous species under gasification conditions. Experiments performed under ambient conditions in He on 20 wt.% Pd/?-Al{sub 2}O{sub 3} indicate the sorbent can remove the target contaminants. Further work is performed using a 5 wt.% Pd/?-Al{sub 2}O{sub 3} sorbent in a simulated fuel gas (H{sub 2}, CO, CO{sub 2}, N{sub 2} and H{sub 2}S) in both single and multiple contaminant atmospheres to gauge sorbent performance characteristics. The impact of H{sub 2}O, Hg and temperature on sorbent performance is explored.

Rupp, Erik C.; Granite, Evan J. [U.S. DOE; Stanko, Dennis C. [U.S. DOE

2013-01-01T23:59:59.000Z

434

NETL: Mercury Emissions Control Technologies - Full- Scale Testing of  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Full-Scale Testing of Enhanced Mercury Control in Wet FGD Full-Scale Testing of Enhanced Mercury Control in Wet FGD The goal of this project is to commercialize methods for the control of mercury in coal-fired electric utility systems equipped with wet flue gas desulfurization (wet FGD). The two specific objectives of this project are 1) ninety percent (90%) total mercury removal and 2) costs below 1/4 to 1/2 of today's commercially available activated carbon mercury removal technologies. Babcock and Wilcox and McDermott Technology, Inc's (B&W/MTI's) will demonstrate their wet scrubbing mercury removal technology (which uses very small amounts of a liquid reagent to achieve increased mercury removal) at two locations burning high-sulfur Ohio bituminous coal: 1) Michigan South Central Power Agency's (MSCPA) 55 MWe Endicott Station located in Litchfield, Michigan and 2) Cinergy's 1300 MWe Zimmer Station located near Cincinnati, Ohio.

435

NETL: News Release - Innovative Mercury Removal Technique Shows Early  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

August 5, 2003 August 5, 2003 Innovative Mercury Removal Technique Shows Early Promise Photochemical Process Developed in Federal Lab Removes Mercury from Flue Gas - NETL scientist Evan Granite prepares a lab test of the UV mercury removal process. - NETL scientist Evan Granite prepares for a lab test of the UV mercury removal process. MORGANTOWN, WV - A promising technology to remove mercury from coal-fired power plants -- dubbed the "GP-254 Process" -- has been developed and is currently being tested at the Department of Energy's National Energy Technology Laboratory (NETL). Newly patented, the GP-254 Process enhances mercury removal using ultraviolet light to induce various components of power plant stack gas to react with the mercury, and changes the

436

NETL: Mercury Emissions Control Technologies - Development of Comprehensive  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Full-Scale Testing of Mercury Control Via Sorbent Injection Full-Scale Testing of Mercury Control Via Sorbent Injection DOE has identified technologies (based on past DOE and other R&D organizations' mercury measurement and control achievements) that are expected to be important in developing possible strategies on mercury control for the coal-fired electric utility industry. To address critical questions related to cost and efficiency of these mercury control technologies, DOE has funded the first of a kind large-scale initiative aimed at testing and evaluating large-scale mercury control technologies for coal-based power systems. These tests will collect cost and performance data with parametric and long term field experiments at power plants with existing air pollution control devices (APCDs) utilized to control other pollutants as well as mercury in hopes of providing the cheapest control options for the utility industry in mid-term application (5 to 10 years).

437

Global change and mercury cycling: Challenges for implementing a global mercury treaty  

E-Print Network [OSTI]

The Minamata Convention aims to protect human health and the environment from anthropogenic emissions and releases of mercury. In the present study, the provisions of the Minamata Convention are examined to assess their ...

Selin, Noelle Eckley

438

It's Elemental - The Element Nitrogen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Carbon Carbon Previous Element (Carbon) The Periodic Table of Elements Next Element (Oxygen) Oxygen The Element Nitrogen [Click for Isotope Data] 7 N Nitrogen 14.0067 Atomic Number: 7 Atomic Weight: 14.0067 Melting Point: 63.15 K (-210.00°C or -346.00°F) Boiling Point: 77.36 K (-195.79°C or -320.44°F) Density: 0.0012506 grams per cubic centimeter Phase at Room Temperature: Gas Element Classification: Non-metal Period Number: 2 Group Number: 15 Group Name: Pnictogen What's in a name? From the Greek words nitron and genes, which together mean "saltpetre forming." Say what? Nitrogen is pronounced as NYE-treh-gen. History and Uses: Nitrogen was discovered by the Scottish physician Daniel Rutherford in 1772. It is the fifth most abundant element in the universe and makes up

439

It's Elemental - The Element Sodium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Neon Neon Previous Element (Neon) The Periodic Table of Elements Next Element (Magnesium) Magnesium The Element Sodium [Click for Isotope Data] 11 Na Sodium 22.98976928 Atomic Number: 11 Atomic Weight: 22.98976928 Melting Point: 370.95 K (97.80°C or 208.04°F) Boiling Point: 1156 K (883°C or 1621°F) Density: 0.97 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 3 Group Number: 1 Group Name: Alkali Metal What's in a name? From the English word soda and from the Medieval Latin word sodanum, which means "headache remedy." Sodium's chemical symbol comes from the Latin word for sodium carbonate, natrium. Say what? Sodium is pronounced as SO-dee-em. History and Uses: Although sodium is the sixth most abundant element on earth and comprises

440

It's Elemental - The Element Francium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Radon Radon Previous Element (Radon) The Periodic Table of Elements Next Element (Radium) Radium The Element Francium [Click for Isotope Data] 87 Fr Francium 223 Atomic Number: 87 Atomic Weight: 223 Melting Point: 300 K (27°C or 81°F) Boiling Point: Unknown Density: Unknown Phase at Room Temperature: Solid Element Classification: Metal Period Number: 7 Group Number: 1 Group Name: Alkali Metal Radioactive What's in a name? Named for the country of France. Say what? Francium is pronounced as FRAN-see-em. History and Uses: Francium was discovered by Marguerite Catherine Perey, a French chemist, in 1939 while analyzing actinium's decay sequence. Although considered a natural element, scientists estimate that there is no more than one ounce of francium in the earth's crust at one time. Since there is so little

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441

It's Elemental - The Element Phosphorus  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Silicon Silicon Previous Element (Silicon) The Periodic Table of Elements Next Element (Sulfur) Sulfur The Element Phosphorus [Click for Isotope Data] 15 P Phosphorus 30.973762 Atomic Number: 15 Atomic Weight: 30.973762 Melting Point: 317.30 K (44.15°C or 111.47°F) Boiling Point: 553.65 K (280.5°C or 536.9°F) Density: 1.82 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Non-metal Period Number: 3 Group Number: 15 Group Name: Pnictogen What's in a name? From the Greek word for light bearing, phosphoros. Say what? Phosphorus is pronounced as FOS-fer-es. History and Uses: In what is perhaps the most disgusting method of discovering an element, phosphorus was first isolated in 1669 by Hennig Brand, a German physician and alchemist, by boiling, filtering and otherwise processing as many as 60

442

It's Elemental - The Element Cerium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Lanthanum Lanthanum Previous Element (Lanthanum) The Periodic Table of Elements Next Element (Praseodymium) Praseodymium The Element Cerium [Click for Isotope Data] 58 Ce Cerium 140.116 Atomic Number: 58 Atomic Weight: 140.116 Melting Point: 1071 K (798°C or 1468°F) Boiling Point: 3697 K (3424°C or 6195°F) Density: 6.770 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 6 Group Number: none Group Name: Lanthanide What's in a name? Named for the asteroid Ceres. Say what? Cerium is pronounced as SER-ee-em. History and Uses: Cerium was discovered by Jöns Jacob Berzelius and Wilhelm von Hisinger, Swedish chemists, and independently by Martin Heinrich Klaproth, a German chemist, in 1803. Cerium is the most abundant of the rare earth elements

443

It's Elemental - The Element Neon  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fluorine Fluorine Previous Element (Fluorine) The Periodic Table of Elements Next Element (Sodium) Sodium The Element Neon [Click for Isotope Data] 10 Ne Neon 20.1797 Atomic Number: 10 Atomic Weight: 20.1797 Melting Point: 24.56 K (-248.59°C or -415.46°F) Boiling Point: 27.07 K (-246.08°C or -410.94°F) Density: 0.0008999 grams per cubic centimeter Phase at Room Temperature: Gas Element Classification: Non-metal Period Number: 2 Group Number: 18 Group Name: Noble Gas What's in a name? From the Greek word for new, neos. Say what? Neon is pronounced as NEE-on. History and Uses: Neon was discovered by Sir William Ramsay, a Scottish chemist, and Morris M. Travers, an English chemist, shortly after their discovery of the element krypton in 1898. Like krypton, neon was discovered through the

444

It's Elemental - The Element Technetium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Molybdenum Molybdenum Previous Element (Molybdenum) The Periodic Table of Elements Next Element (Ruthenium) Ruthenium The Element Technetium [Click for Isotope Data] 43 Tc Technetium 98 Atomic Number: 43 Atomic Weight: 98 Melting Point: 2430 K (2157°C or 3915°F) Boiling Point: 4538 K (4265°C or 7709°F) Density: 11 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 5 Group Number: 7 Group Name: none Radioactive and Artificially Produced What's in a name? From the Greek word for artificial, technetos. Say what? Technetium is pronounced as tek-NEE-she-em. History and Uses: Technetium was the first artificially produced element. It was isolated by Carlo Perrier and Emilio Segrè in 1937. Technetium was created by bombarding molybdenum atoms with deuterons that had been accelerated by a

445

It's Elemental - The Element Cobalt  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Iron Iron Previous Element (Iron) The Periodic Table of Elements Next Element (Nickel) Nickel The Element Cobalt [Click for Isotope Data] 27 Co Cobalt 58.933195 Atomic Number: 27 Atomic Weight: 58.933195 Melting Point: 1768 K (1495°C or 2723°F) Boiling Point: 3200 K (2927°C or 5301°F) Density: 8.86 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 4 Group Number: 9 Group Name: none What's in a name? From the German word for goblin or evil spirit, kobald and the Greek word for mine, cobalos. Say what? Cobalt is pronounced as KO-bolt. History and Uses: Cobalt was discovered by Georg Brandt, a Swedish chemist, in 1739. Brandt was attempting to prove that the ability of certain minerals to color glass blue was due to an unknown element and not to bismuth, as was commonly