National Library of Energy BETA

Sample records for merchant oxygenate plants

  1. Developing and financing merchant power plants in the U.S.

    SciTech Connect (OSTI)

    Ryan, M.J.

    1998-07-01

    Limited recourse financing for merchant plants in some areas of the world such as Latin America has become almost commonplace in the recent past. Limited recourse project financing for merchant plants in the US, once almost unthinkable, has already been achieved with the frontier-breaking Calpine Pasadena project. While long-term power purchase agreements have historically provided comfort to lenders and developers alike, they are increasingly becoming a thing of the past as utilities are reluctant to lock themselves into a fixed price, which may turn out to exceed the prices available in the open market. So, it seems that the trends toward merchant plants in Latin America will soon take hold in the domestic market. With the market for limited recourse project financing still in the embryonic stage, and the strong likelihood that long-term power purchase agreements will not be available, it is clear that successful domestic projects will have to be well conceived, properly structured and capitalized to secure debt and equity funding commitments. This paper will focus on opportunities for developing merchant plants, the major risks present to developers and investors and the most appropriate strategies for structuring finance for a project.

  2. Integrated turbomachine oxygen plant

    SciTech Connect (OSTI)

    Anand, Ashok Kumar; DePuy, Richard Anthony; Muthaiah, Veerappan

    2014-06-17

    An integrated turbomachine oxygen plant includes a turbomachine and an air separation unit. One or more compressor pathways flow compressed air from a compressor through one or more of a combustor and a turbine expander to cool the combustor and/or the turbine expander. An air separation unit is operably connected to the one or more compressor pathways and is configured to separate the compressed air into oxygen and oxygen-depleted air. A method of air separation in an integrated turbomachine oxygen plant includes compressing a flow of air in a compressor of a turbomachine. The compressed flow of air is flowed through one or more of a combustor and a turbine expander of the turbomachine to cool the combustor and/or the turbine expander. The compressed flow of air is directed to an air separation unit and is separated into oxygen and oxygen-depleted air.

  3. The Merchant Shipping (Dangerous Goods) Rules 1965 

    E-Print Network [OSTI]

    Noble, Michael; Mason, Roy

    1965-01-01

    STATUTORY INSTRUMENTS 1965 No. 1067 MERCHANT Shipping DANGEROUS GOODS The Merchant Shipping (Dangerous Goods) Rules 1965

  4. Merchant transmission investment

    E-Print Network [OSTI]

    Joskow, Paul L.

    2003-01-01

    We examine the performance attributes of a merchant transmission investment framework that relies on "market driven" transmission investment to provide the infrastructure to support competitive wholesale markets for ...

  5. Oxygen Handling and Cooling Options in High Temperature Electrolysis Plants

    SciTech Connect (OSTI)

    Manohar S. Sohal; J. Stephen Herring

    2008-07-01

    Idaho National Laboratory is working on a project to generate hydrogen by high temperature electrolysis (HTE). In such an HTE system, safety precautions need to be taken to handle high temperature oxygen at ~830°C. This report is aimed at addressing oxygen handling in a HTE plant.. Though oxygen itself is not flammable, most engineering material, including many gases and liquids, will burn in the presence of oxygen under some favorable physicochemical conditions. At present, an absolute set of rules does not exist that can cover all aspects of oxygen system design, material selection, and operating practices to avoid subtle hazards related to oxygen. Because most materials, including metals, will burn in an oxygen-enriched environment, hazards are always present when using oxygen. Most materials will ignite in an oxygen-enriched environment at a temperature lower than that in air, and once ignited, combustion rates are greater in the oxygen-enriched environment. Even many metals, if ignited, burn violently in an oxygen-enriched environment. However, these hazards do not preclude the operations and systems involving oxygen. Oxygen can be safely handled and used if all the materials in a system are not flammable in the end-use environment or if ignition sources are identified and controlled. In fact, the incidence of oxygen system fires is reported to be low with a probability of about one in a million. This report is a practical guideline and tutorial for the safe operation and handling of gaseous oxygen in high temperature electrolysis system. The intent is to provide safe, practical guidance that permits the accomplishment of experimental operations at INL, while being restrictive enough to prevent personnel endangerment and to provide reasonable facility protection. Adequate guidelines are provided to govern various aspects of oxygen handling associated with high temperature electrolysis system to generate hydrogen. The intent here is to present acceptable oxygen standards and practices for minimum safety requirements. A summary of operational hazards, along with oxygen safety and emergency procedures, are provided.

  6. Proceedings of IEEE Sensors 2003 Fiber Optic Oxygen Sensor for Power Plant Applications

    E-Print Network [OSTI]

    Ghosh, Ruby N.

    807 Proceedings of IEEE Sensors 2003 Paper 22-2 Fiber Optic Oxygen Sensor for Power Plant for power plant applications. The sensor utilizes quenching of the bright red fluorescence from inorganic. Motivation Combustion processes in power plants require the correct mix of fuel and oxygen to maximize

  7. Cruel Seas: World War 2 Merchant Marine-Related Nautical Fiction from the 1930s to Present

    E-Print Network [OSTI]

    Krummes, Daniel C

    2015-01-01

    Seas : World War 2 merchant marine related nautical fictionWorld War 2 merchant marine related nautical fiction "Seas : World War 2 merchant marine related nautical fiction

  8. Merchant and Regulated Transmission: Theory, Evidence and Policy

    E-Print Network [OSTI]

    Littlechild, Stephen

    in Europe and Australia would restrict merchant investment to interconnectors between adjacent markets, with remaining investment being carried out by a regulated Transco. (See also Brunekreeft 2005) Rious (2006) suggested that merchant investment would... for the market, along lines suggested by Demsetz, could be useful in radial but not meshed networks. In 1998 two merchant interconnectors were proposed in Australia (DirectLink and Murraylink), which came into operation in 2000 and 2002, respectively...

  9. Energy Merchant Marketing EMM | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButtePowerEdisto Electric Coop, Incsource History View New Pages RecentMerchant

  10. The effect of Sequoyah Nuclear Plant on dissolved oxygen in Chickamauga Reservoir

    SciTech Connect (OSTI)

    Butkus, S.R.; Shiao, M.C.; Yeager, B.L.

    1990-09-01

    During the summer of 1985, the Tennessee Division of Water Pollution Control and the Tennessee Wildlife Resources Agency measured dissolved oxygen (DO) concentrations downstream from the Sequoyah Nuclear Plant (SQN) discharge mixing zone that were below the state criterion for DO. The Tennessee General Water Quality Criteria'' specifies that DO should be a minimum of 5.0 mg/l measured at a depth of 5 feet for the protection of fish and aquatic life. The Tennessee Valley Authority developed the present study to answer general concerns about reservoir conditions and potential for adverse effects on aquatic biota. Four objectives were defined for this study: (1) to better define the extent and duration of the redistribution of DO in the reservoir, (2) to better understand DO dynamics within the mixing zone, (3) to determine whether DO is being lost (or added) as the condenser cooling water passes through the plant, and (4) to evaluate the potential for impact on aquatic life in the reservoir.

  11. Plant for producing an oxygen-containing additive as an ecologically beneficial component for liquid motor fuels

    DOE Patents [OSTI]

    Siryk, Yury Paul; Balytski, Ivan Peter; Korolyov, Volodymyr George; Klishyn, Olexiy Nick; Lnianiy, Vitaly Nick; Lyakh, Yury Alex; Rogulin, Victor Valery

    2013-04-30

    A plant for producing an oxygen-containing additive for liquid motor fuels comprises an anaerobic fermentation vessel, a gasholder, a system for removal of sulphuretted hydrogen, and a hotwell. The plant further comprises an aerobic fermentation vessel, a device for liquid substance pumping, a device for liquid aeration with an oxygen-containing gas, a removal system of solid mass residue after fermentation, a gas distribution device; a device for heavy gases utilization; a device for ammonia adsorption by water; a liquid-gas mixer; a cavity mixer, a system that serves superficial active and dispersant matters and a cooler; all of these being connected to each other by pipelines. The technical result being the implementation of a process for producing an oxygen containing additive, which after being added to liquid motor fuels, provides an ecologically beneficial component for motor fuels by ensuring the stability of composition fuel properties during long-term storage.

  12. Plants, Weathering, and the Evolution of Atmospheric Carbon Dioxide and Oxygen

    SciTech Connect (OSTI)

    Berner, Robert A

    2008-02-05

    Over the past six years we have published 24 papers that can be divided into three sections: (1) Study of plants and weathering, (2) modeling the evolution of atmospheric CO2 over Phanerozoic time (past 550 million years). (3) Modeling of atmospheric O2 over Phanerozoic time. References to papers published acknowledging this grant can be found at the end of this report and almost all are supplied in pdf form. (1) In the temperate forests of the Cascade Mountains, USA, calcium and magnesium meet vastly different fates beneath angiosperms vs gymnosperms. Calcium is leached beneath both groves of trees, but leached 20-40% more beneath the angiosperms. Magnesium is retained in the forest system beneath the angiosperms and leached from beneath the gymnosperms. (2) We have shown that climate and CO2, based on both carbon cycle modeling and hundreds of independent proxies for paleo-CO2, correlate very well over the past 550 million year. In a recent paper we use this correlation to deduce the sensitivity of global mean temperature to a doubling of atmospheric CO2, and results are in excellent agreement with the results of climatologists based on the historical record and on theoretical climate models (GCM’s).(3) We have shown that concentrations of atmospheric oxygen, calculated by a combined carbon-sulfur cycle model, over the past 550 million years have varied with and influenced biological evolution.

  13. Eighteenth-century colonial American merchant ship construction 

    E-Print Network [OSTI]

    VanHorn, Kellie Michelle

    2005-02-17

    ); and the Charon, Yorktown, Virginia (1778). Finally, two small riverine craft were also considered: the Brown?s Ferry vessel, Black River, South Carolina (pre-1740s) and the Town Point vessel, Pensacola, Florida (1763-1781). Figure 1 shows a map of these vessel...) (Head of Department) December 2004 Major Subject: Anthropology iii ABSTRACT Eighteenth-Century Colonial American Merchant Ship Construction. (December 2004) Kellie Michelle VanHorn, B.S., Indiana University Chair of Advisory...

  14. Influence of cellulose oxygen isotope variability in sub-fossil Sphagnum and plant macrofossil components on the reliability of paleoclimate records at the Mer

    E-Print Network [OSTI]

    Patterson, Timothy

    Influence of cellulose oxygen isotope variability in sub-fossil Sphagnum and plant macrofossil Available online 15 November 2011 a b s t r a c t This study provides a new understanding of cellulose) is com- prised primarily of cellulose (15­50%), hemicellulose (10­40%), lig- nin (5­30%), proteins (2

  15. The water street ship: preliminary analysis of an eighteenth-century merchant ship's bow 

    E-Print Network [OSTI]

    Rosloff, Jay Paul

    1986-01-01

    THE WATER STREET SHIP: PRELIMINARY ANALYSIS OF AN EIGHTEENTH-CENTURY MERCHANT SHIP'S BOW A Thesis by JAY PAUL ROSLOFF Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirements for the degree... of MASTER OF ARTS May 1986 Major Subject: Anthropology THE WATER STREET SHIP: PRELIMINARY ANALYSIS OF AN EIGHTEENTH-CENTURY MERCHANT SHIP'S BOW A Thesis by JAY PAUL ROSLOFF Approved as to style and content by: J. R. Steffy (Chairman of Co mittee...

  16. Oxygen-Fired CO{sub 2} Recycle for Application to Direct CO{sub 2} Capture form Coal-Fired Power Plants

    SciTech Connect (OSTI)

    Thomas Gale

    2010-09-26

    The Southern Research/Southern Company 1 MWth Pilot-Scale Coal-Fired Test Facility was successfully retrofit to fire in either the traditional air-fired mode or with 100% oxygen and recycled flue gas, with a fully integrated feedback and control system, including oxygen and recycled flue gas modulation during startup, transfer, and shutdown, safety and operational interlocks, and data acquisition. A MAXON Staged Oxygen Burner for Oxy-Coal Applications produced a stable flame over a significant range of firing turn-down, staging, and while firing five different U.S. coal types. The MAXON burner design produces lower flame temperatures than for air firing, which will enable (A) Safe operation, (B) Reduction of recycle flow without concern about furnace flame temperatures, and (C) May likely be affective at reducing slagging and fouling in the boiler and super heater at full-scale Power Plants. A CFD model of the Oxy-fired Combustion Research Facility (OCRF) was used to predict the flame geometry and temperatures in the OCRF and make a comparison with the air-fired case. The model predictions were consistent with the experimental data in showing that the MAXON burner fired with oxygen produced lower flame temperatures than the air-fired burner while firing with air.

  17. Oxygen analyzer

    DOE Patents [OSTI]

    Benner, W.H.

    1984-05-08

    An oxygen analyzer which identifies and classifies microgram quantities of oxygen in ambient particulate matter and for quantitating organic oxygen in solvent extracts of ambient particulate matter. A sample is pyrolyzed in oxygen-free nitrogen gas (N/sub 2/), and the resulting oxygen quantitatively converted to carbon monoxide (CO) by contact with hot granular carbon (C). Two analysis modes are made possible: (1) rapid determination of total pyrolyzable obtained by decomposing the sample at 1135/sup 0/C, or (2) temperature-programmed oxygen thermal analysis obtained by heating the sample from room temperature to 1135/sup 0/C as a function of time. The analyzer basically comprises a pyrolysis tube containing a bed of granular carbon under N/sub 2/, ovens used to heat the carbon and/or decompose the sample, and a non-dispersive infrared CO detector coupled to a mini-computer to quantitate oxygen in the decomposition products and control oven heating.

  18. The merchant of Genoa : the Crusades, the Genoese and the Latin East, 1187-1220s

    E-Print Network [OSTI]

    Mack, Merav

    2003-10-07

    period. Contents: I 2 3 4 5 Abbreviations List of maps and figures Tables Acknowledgments Introduction The cartularies Methodology Genoa and the Third Crusade 1187 - The response in Genoa to the fall of Jerusalem Merchants organising... and the Sicilian ounce, 1182-1216 174 The Nepitella family and its commercial contacts with Alexandria, 1184-1213 176 Bequest for the crusade in Genoese wills from 1216 178 Bibliography 179 I 3 Abbreviations Ann. Ian. Caffaro, Annali genovesi di Caffaro e de...

  19. Modeling the effects of low flow augmentation by discharge from a wastewater treatment plant on dissolved oxygen concentration in Leon Creek, San Antonio, Texas 

    E-Print Network [OSTI]

    Gholkar, Tejal A

    2000-01-01

    ' d ) /= time (s) L'= mean stream velocity (m s ) 1 u = stream velocitv (md ') x = distance dosvnstream 1'rom ihc BOD point discharge (m) x *= stream distance (m) a, ? rate of oxygen production per unit of algal photosynthesis (mg-0/mg-A) rr... & = rate of oxygen uptake per unit of ammonia nitrogen oxidation (mg-0/mg-N) rr, = rate of oxygen uptake per unit of nitrite nitrogen (mg-0/mg-N) rr, = rate of oxygen uptake per unit of per unit of algae respired (mg-/mg-A) P& = ammonia oxidation rate...

  20. UNIVERSITY OF UTAH INCOME ACCOUNTING/ STUDENT LOAN SERVICES SSB 165 801-585-5686 Merchant Account Close Form Fax to 801-581-4277

    E-Print Network [OSTI]

    Clayton, Dale H.

    UNIVERSITY OF UTAH INCOME ACCOUNTING/ STUDENT LOAN SERVICES SSB 165 801-585-5686 Merchant Account or Incomplete forms may delay processing. Request Date: Name of Account: Contact: Department Name (if different #: American Express Merchant #: Reason for Closure: Date of Last Batch: Do you have other accounts that should

  1. UNIVERSITY OF UTAH INCOME ACCOUNTING/ STUDENT LOAN SERVICES SSB 165 801-585-5686 Merchant Application Fax to 801-581-4277

    E-Print Network [OSTI]

    Clayton, Dale H.

    UNIVERSITY OF UTAH INCOME ACCOUNTING/ STUDENT LOAN SERVICES SSB 165 801-585-5686 10/11 Merchant be accepting donations with your merchant account? Yes No If no, do you anticipate taking donations Party" to submit w/ this application. Wells Fargo Checking Account for Deposits: Chartfield to debit

  2. SUBJECT: Effective Date: Policy Number: Credit Card Merchant Policy 05-18-11 3-206.4

    E-Print Network [OSTI]

    Glebov, Leon

    provider contract, which includes compliance with the Payment Card Industry's Data Security Standards (PCI of the card. Payment Card Industry's Data Security Standards (PCI DSS). These standards are technical and Accounting, Merchant Services Web Site Payment Card Industry Security Standards Council Data Security

  3. EFFICIENT OXYGEN SEPARATION MEMBRANE

    E-Print Network [OSTI]

    Mucina, Ladislav

    EFFICIENT OXYGEN SEPARATION MEMBRANE Summary of technology Oxygen can be separated from air using a uniquely structured ceramic ion transport membrane for oxygen separation thatshowsremarkablyhighflux © Curtin University 2013 Gas diffusion in conventional membrane Gas diffusion in new membrane New membrane

  4. Artificial oxygen transport protein

    DOE Patents [OSTI]

    Dutton, P. Leslie

    2014-09-30

    This invention provides heme-containing peptides capable of binding molecular oxygen at room temperature. These compounds may be useful in the absorption of molecular oxygen from molecular oxygen-containing atmospheres. Also included in the invention are methods for treating an oxygen transport deficiency in a mammal.

  5. Solid state oxygen sensor

    DOE Patents [OSTI]

    Garzon, F.H.; Chung, B.W.; Raistrick, I.D.; Brosha, E.L.

    1996-08-06

    Solid state oxygen sensors are provided with a yttria-doped zirconia as an electrolyte and use the electrochemical oxygen pumping of the zirconia electrolyte. A linear relationship between oxygen concentration and the voltage arising at a current plateau occurs when oxygen accessing the electrolyte is limited by a diffusion barrier. A diffusion barrier is formed herein with a mixed electronic and oxygen ion-conducting membrane of lanthanum-containing perovskite or zirconia-containing fluorite. A heater may be used to maintain an adequate oxygen diffusion coefficient in the mixed conducting layer. 4 figs.

  6. Solid state oxygen sensor

    DOE Patents [OSTI]

    Garzon, Fernando H. (Sante Fe, NM); Chung, Brandon W. (Los Alamos, NM); Raistrick, Ian D. (Los Alamos, NM); Brosha, Eric L. (Los Alamos, NM)

    1996-01-01

    Solid state oxygen sensors are provided with a yttria-doped zirconia as an electrolyte and use the electrochemical oxygen pumping of the zirconia electrolyte. A linear relationship between oxygen concentration and the voltage arising at a current plateau occurs when oxygen accessing the electrolyte is limited by a diffusion barrier. A diffusion barrier is formed herein with a mixed electronic and oxygen ion-conducting membrane of lanthanum-containing perovskite or zirconia-containing fluorite. A heater may be used to maintain an adequate oxygen diffusion coefficient in the mixed conducting layer.

  7. Compound hybrid geothermal-fossil power plants: thermodynamic...

    Office of Scientific and Technical Information (OSTI)

    SUPERHEATING; THERMODYNAMICS; WELL TEMPERATURE; WELLHEADS; WESTERN REGION; HEATING; HYDROGEN COMPOUNDS; NORTH AMERICA; OXYGEN COMPOUNDS; POWER PLANTS; RESERVOIR TEMPERATURE;...

  8. Solid state oxygen sensor

    DOE Patents [OSTI]

    Garzon, Fernando H. (Santa Fe, NM); Brosha, Eric L. (Los Alamos, NM)

    1997-01-01

    A potentiometric oxygen sensor is formed having a logarithmic response to a differential oxygen concentration while operating as a Nernstian-type sensor. Very thin films of mixed conducting oxide materials form electrode services while permitting diffusional oxygen access to the interface between the zirconia electrolyte and the electrode. Diffusion of oxygen through the mixed oxide is not rate-limiting. Metal electrodes are not used so that morphological changes in the electrode structure do not occur during extended operation at elevated temperatures.

  9. Oxygen partial pressure sensor

    DOE Patents [OSTI]

    Dees, D.W.

    1994-09-06

    A method for detecting oxygen partial pressure and an oxygen partial pressure sensor are provided. The method for measuring oxygen partial pressure includes contacting oxygen to a solid oxide electrolyte and measuring the subsequent change in electrical conductivity of the solid oxide electrolyte. A solid oxide electrolyte is utilized that contacts both a porous electrode and a nonporous electrode. The electrical conductivity of the solid oxide electrolyte is affected when oxygen from an exhaust stream permeates through the porous electrode to establish an equilibrium of oxygen anions in the electrolyte, thereby displacing electrons throughout the electrolyte to form an electron gradient. By adapting the two electrodes to sense a voltage potential between them, the change in electrolyte conductivity due to oxygen presence can be measured. 1 fig.

  10. Oxygen partial pressure sensor

    DOE Patents [OSTI]

    Dees, Dennis W. (Downers Grove, IL)

    1994-01-01

    A method for detecting oxygen partial pressure and an oxygen partial pressure sensor are provided. The method for measuring oxygen partial pressure includes contacting oxygen to a solid oxide electrolyte and measuring the subsequent change in electrical conductivity of the solid oxide electrolyte. A solid oxide electrolyte is utilized that contacts both a porous electrode and a nonporous electrode. The electrical conductivity of the solid oxide electrolyte is affected when oxygen from an exhaust stream permeates through the porous electrode to establish an equilibrium of oxygen anions in the electrolyte, thereby displacing electrons throughout the electrolyte to form an electron gradient. By adapting the two electrodes to sense a voltage potential between them, the change in electrolyte conductivity due to oxygen presence can be measured.

  11. Hybrid membrane/cryogenic separation of oxygen from air for use in the oxy-fuel process

    E-Print Network [OSTI]

    Struchtrup, Henning

    ] show that a gas turbine combined cycle power plant installed with the oxy-fuel process will reduce for the power plant is pure oxygen mixed with power plant exhaust [2]. Thus, the final exhaust is essentially cycle [4] the oxygen separation process, however, would be an addition to an existing power plant

  12. Use of experience curves to estimate the future cost of power plants with CO2 capture

    E-Print Network [OSTI]

    Rubin, Edward S.; Yeh, Sonia; Antes, Matt; Berkenpas, Michael; Davison, John

    2007-01-01

    plants, pulverized coal (PC) boilers, lique?ed natural gas (GTCC) Pulverized coal (PC) boilers LNG production OxygenLNG production, ( b) PC boilers, (c) oxygen production, (d)

  13. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Carter, J. David; Wang, Xiaoping; Vaughey, John; Krumpelt, Michael

    2004-11-23

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  14. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Vaughey, John (Elmhurst, IL); Krumpelt, Michael (Naperville, IL); Wang, Xiaoping (Downers Grove, IL); Carter, J. David (Bolingbrook, IL)

    2003-01-01

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  15. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Vaughey, John; Krumpelt, Michael; Wang, Xiaoping; Carter, J. David

    2005-07-12

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  16. Solid state oxygen sensor

    DOE Patents [OSTI]

    Garzon, F.H.; Brosha, E.L.

    1997-12-09

    A potentiometric oxygen sensor is formed having a logarithmic response to a differential oxygen concentration while operating as a Nernstian-type sensor. Very thin films of mixed conducting oxide materials form electrode services while permitting diffusional oxygen access to the interface between the zirconia electrolyte and the electrode. Diffusion of oxygen through the mixed oxide is not rate-limiting. Metal electrodes are not used so that morphological changes in the electrode structure do not occur during extended operation at elevated temperatures. 6 figs.

  17. High Selectivity Oxygen Delignification

    SciTech Connect (OSTI)

    Lucian A. Lucia

    2005-11-15

    Project Objective: The objectives of this project are as follows: (1) Examine the physical and chemical characteristics of a partner mill pre- and post-oxygen delignified pulp and compare them to lab generated oxygen delignified pulps; (2) Apply the chemical selectivity enhancement system to the partner pre-oxygen delignified pulps under mill conditions (with and without any predetermined amounts of carryover) to determine how efficiently viscosity is preserved, how well selectivity is enhanced, if strength is improved, measure any yield differences and/or bleachability differences; and (3) Initiate a mill scale oxygen delignification run using the selectivity enhancement agent, collect the mill data, analyze it, and propose any future plans for implementation.

  18. Plant Operational Status - Pantex Plant

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid youOxygen Generation | Center for GasPhysics Physics PrintPicturePlant

  19. Power Plant Power Plant

    E-Print Network [OSTI]

    Stillwater Power Plant Wabuska Power Plant Casa Diablo Power Plant Glass Mountain Geothermal Area Lassen Geothermal Area Coso Hot Springs Power Plants Lake City Geothermal Area Thermo Geothermal Area Lakeview Geothermal Area Raft River Geothermal Area Cove Fort Power Plant Roosevelt Power Plant Borax Lake

  20. A calcium oxygen secondary battery

    SciTech Connect (OSTI)

    Pujare, N.U.; Semkow, K.W.; Sammells, A.F.

    1988-01-01

    The authors report preliminary work performed in their laboratory on a high-temperature electrochemically reversible calcium-oxygen cell. Following an analogous strategy to that recently discussed for the lithium-oxygen secondary system, this calcium-oxygen cell utilizes stabilized zirconia oxygen vacancy conducting solid electrolytes to achieve effective separation between half-cell reactions.

  1. Optical oxygen concentration monitor

    DOE Patents [OSTI]

    Kebabian, P.

    1997-07-22

    A system for measuring and monitoring the concentration of oxygen uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to one of oxygen`s A-band absorption lines. In a preferred embodiment, the argon line is split into sets of components of shorter and longer wavelengths by a magnetic field of approximately 2,000 Gauss that is parallel to the light propagation from the lamp. The longer wavelength components are centered on an absorption line of oxygen and thus readily absorbed, and the shorter wavelength components are moved away from that line and minimally absorbed. A polarization modulator alternately selects the set of the longer wavelength, or upshifted, components or the set of the shorter wavelength, or downshifted, components and passes the selected set to an environment of interest. After transmission over a path through that environment, the transmitted optical flux of the argon line varies as a result of the differential absorption. The system then determines the concentration of oxygen in the environment based on the changes in the transmitted optical flux between the two sets of components. In alternative embodiments modulation is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to either the emitting plasma of the lamp or the environment of interest. 4 figs.

  2. Optical oxygen concentration monitor

    DOE Patents [OSTI]

    Kebabian, Paul (Acton, MA)

    1997-01-01

    A system for measuring and monitoring the concentration of oxygen uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to one of oxygen's A-band absorption lines. In a preferred embodiment, the argon line is split into sets of components of shorter and longer wavelengths by a magnetic field of approximately 2000 Gauss that is parallel to the light propagation from the lamp. The longer wavelength components are centered on an absorption line of oxygen and thus readily absorbed, and the shorter wavelength components are moved away from that line and minimally absorbed. A polarization modulator alternately selects the set of the longer wavelength, or upshifted, components or the set of the shorter wavelength, or downshifted, components and passes the selected set to an environment of interest. After transmission over a path through that environment, the transmitted optical flux of the argon line varies as a result of the differential absorption. The system then determines the concentration of oxygen in the environment based on the changes in the transmitted optical flux between the two sets of components. In alternative embodiments modulation is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to either the emitting plasma of the lamp or the environment of interest.

  3. Direct Observation of the Oxygenated Species during Oxygen Reduction...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Direct Observation of the Oxygenated Species during Oxygen Reduction on a Platinum Fuel Cell Cathode Friday, December 20, 2013 Fuel Cell Figure 1 Figure 1. In situ x-ray...

  4. High pressure oxygen furnace

    DOE Patents [OSTI]

    Morris, Donald E. (Kensington, CA)

    1992-01-01

    A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior.

  5. High pressure oxygen furnace

    DOE Patents [OSTI]

    Morris, D.E.

    1992-07-14

    A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized, the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior. 5 figs.

  6. Which oxygenates is right for you?

    SciTech Connect (OSTI)

    Chang, E.J. [SRI International, Menlo Park, CA (United States)

    1994-12-31

    Recent announcements of additional sources of oxygenates have generated considerable interest. Increasing demand for methyl tert-butyl ether (MTBE) worldwide, especially in the United States for oxygenated fuel and reformulated gasoline (RFG), provides the primary incentive for technologies that produce additional raw material (namely isobutene) and/or alternative oxygenate compounds. Normal butene isomerization and diisopropyl ether (DIPE) are two new processes introduced in 1992 to meet the oxygenate demand. The U.S. Clean Air Act Amendments of 1990 (CAAA) have created a huge demand for capital. Between 1991 and 2000, the U.S. refining industry will need to make capital expenditures of about $37 billion (1990 dollars) to meet refinery regulatory requirements, and to manufacture reformulated gasoline and ultra-low sulfur diesel fuel. To obtain financing, whether internally or from external sources, projects must provide sound economics and pose minimal technological risks. These concerns have prevented several large MTBE projects, involving both established and new technologies, from going forward. The introduction of normal butene isomerization and DIPE processes has generated a great deal of enthusiasm, but neither process had been licensed by the third quarter of 1993. Technology risk is a major barrier to obtaining financing inasmuch as lenders arc unlikely to finance the first commercial application of any technology. Currently, Texas Olefins/Phillips Petroleum and Lyondell have demonstrated normal butene isomerization on a commercial scale in their plants. However, Mobil has not demonstrated the DIPE process beyond the pilot plant stage. In this paper, we assess the technological aspects of normal butene isomerization and DIPE processes, and compare their economics with existing etherification processes.

  7. Characterizing the Oxygen Isotopic Composition of Phosphate Sources

    E-Print Network [OSTI]

    Paytan, Adina

    phosphorite ore, particulate aerosols, detergents, leachates of vegetation, soil, animal feces, and wastewater treatment plant effluent. We found a considerable range of 18 Op values (from +8.4 to +24.9) for the various to the phosphorus (P) in phosphate (PO4) (4-7). The primary goal of this study is to characterize the oxygen

  8. Protection by Isoprene against Singlet Oxygen in Leaves Hagit P. Affek and Dan Yakir*

    E-Print Network [OSTI]

    -methyl-1,3-butadiene) protection against effects of singlet oxygen was investigated in Myrtus communis conditions. Isoprene (2-methyl-1,3-butadiene) is emitted by a variety of plant species (Harley et al., 1999

  9. OXYGEN TRANSPORT CERAMIC MEMBRANES

    SciTech Connect (OSTI)

    Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

    2000-10-01

    This is the third quarterly report on oxygen Transport Ceramic Membranes. In the following, the report describes the progress made by our university partners in Tasks 1 through 6, experimental apparatus that was designed and built for various tasks of this project, thermodynamic calculations, where applicable and work planned for the future. (Task 1) Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints. (Task 2) Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability. (Task 3) Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres. (Task 4) Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures. (Task 5) Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability. (Task 6) Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

  10. Composite oxygen transport membrane

    DOE Patents [OSTI]

    Christie, Gervase Maxwell; Lane, Jonathan A.

    2014-08-05

    A method of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln.sub.1-xA.sub.x).sub.wCr.sub.1-yB.sub.yO.sub.3-.delta. and a doped zirconia. In the porous fuel oxidation layer and the optional porous surface exchange layer, A is Calcium and in the dense separation layer A is not Calcium and, preferably is Strontium. Preferred materials are (La.sub.0.8Ca.sub.0.2).sub.0.95Cr.sub.0.5Mn.sub.0.5O.sub.3-.delta. for the porous fuel oxidation and optional porous surface exchange layers and (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.5Fe.sub.0.5O.sub.3-.delta. for the dense separation layer. The use of such materials allows the membrane to sintered in air and without the use of pore formers to reduce membrane manufacturing costs. The use of materials, as described herein, for forming the porous layers have application for forming any type of porous structure, such as a catalyst support.

  11. High Selectivity Oxygen Delignification

    SciTech Connect (OSTI)

    Arthur J. Ragauskas

    2005-09-30

    The overall objective of this program was to develop improved extended oxygen delignification (EOD) technologies for current U.S. pulp mill operations. This was accomplished by: (1) Identifying pulping conditions that optimize O and OO performance; (2) Identifying structural features of lignin that enhance reactivity towards EOD of high kappa pulps; (3) Identifying factors minimizing carbohydrate degradation and improve pulp strength of EOD high kappa pulps; (4) Developing a simple, reproducible method of quantifying yield gains from EOD; and (5) Developing process conditions that significantly reduce the capital requirements of EOD while optimizing the yield benefits. Key research outcomes included, demonstrating the use of a mini-O sequence such as (E+O)Dkf:0.05(E+O) or Dkf:0.05(E+O)(E+O) without interstage washing could capture approximately 60% of the delignification efficiency of a conventional O-stage without the major capital requirements associated with an O-stage for conventional SW kraft pulps. The rate of formation and loss of fiber charge during an O-stage stage can be employed to maximize net fiber charge. Optimal fiber charge development and delignification are two independent parameters and do not parallel each other. It is possible to utilize an O-stage to enhance overall cellulosic fiber charge of low and high kappa SW kraft pulps which is beneficial for physical strength properties. The application of NIR and multi-variant analysis was developed into a rapid and simple method of determining the yield of pulp from an oxygen delignification stage that has real-world mill applications. A focus point of this program was the demonstration that Kraft pulping conditions and oxygen delignification of high and low-kappa SW and HW pulps are intimately related. Improved physical pulp properties and yield can be delivered by controlling the H-factor and active alkali charge. Low AA softwood kraft pulp with a kappa number 30 has an average improvement of 2% in yield and 4 cP in viscosity in comparison to high AA pulp for the oxygen delignification. This difference is also seen for high-kappa SW kraft pulps with an average improvement of {approx}3% in yield and 3 cP in viscosity for low AA high kappa number 50 pulp. Low AA hardwood kappa number 20 pulp had an average improvement of {approx}4% in yield and 6-12 cP in viscosity as compared to high AA pulp. Lower kraft cooking temperature (160 vs. 170 C) in combination with the medium AA provides a practical approach for integrating high kappa pulping of hardwoods (i.e., low rejects) with an advanced extended oxygen delignification stage. ECF pulp bleaching of low and high kappa kraft SW and HW pulps exhibit comparable optical and physical strength properties when bleached D(EPO)D.

  12. Oxygen-reducing catalyst layer

    DOE Patents [OSTI]

    O'Brien, Dennis P. (Maplewood, MN); Schmoeckel, Alison K. (Stillwater, MN); Vernstrom, George D. (Cottage Grove, MN); Atanasoski, Radoslav (Edina, MN); Wood, Thomas E. (Stillwater, MN); Yang, Ruizhi (Halifax, CA); Easton, E. Bradley (Halifax, CA); Dahn, Jeffrey R. (Hubley, CA); O'Neill, David G. (Lake Elmo, MN)

    2011-03-22

    An oxygen-reducing catalyst layer, and a method of making the oxygen-reducing catalyst layer, where the oxygen-reducing catalyst layer includes a catalytic material film disposed on a substrate with the use of physical vapor deposition and thermal treatment. The catalytic material film includes a transition metal that is substantially free of platinum. At least one of the physical vapor deposition and the thermal treatment is performed in a processing environment comprising a nitrogen-containing gas.

  13. Oxygenates from synthesis gas

    SciTech Connect (OSTI)

    Falter, W.; Keim, W.

    1994-12-31

    The direct synthesis of oxygenates starting from synthesis gas is feasible by homogeneous and heterogeneous catalysis. Homogeneous Rh and Ru based catalysts yielding methyl formate and alcohols will be presented. Interestingly, modified heterogeneous catalysts based on {open_quotes}Isobutyl Oel{close_quotes} catalysis, practized in Germany (BRD) up to 1952 and in the former DDR until recently, yield isobutanol in addition to methanol. These {open_quotes}Isobutyl Oel{close_quotes} catalysts are obtained by adding a base such as Li < Na < K < Cs to a Zn-Cr{sub 2}O{sub 3} methanol catalyst. Isobutanol is obtained in up to 15% yield. Our best catalyst a Zr-Zn-Mn-Li-Pd catalyst produced isobotanol up to 60% at a rate of 740g isobutanol per liter catalyst and hour.

  14. Oxygen detection using evanescent fields

    DOE Patents [OSTI]

    Duan, Yixiang (Los Alamos, NM); Cao, Weenqing (Los Alamos, NM)

    2007-08-28

    An apparatus and method for the detection of oxygen using optical fiber based evanescent light absorption. Methylene blue was immobilized using a sol-gel process on a portion of the exterior surface of an optical fiber for which the cladding has been removed, thereby forming an optical oxygen sensor. When light is directed through the optical fiber, transmitted light intensity varies as a result of changes in the absorption of evanescent light by the methylene blue in response to the oxygen concentration to which the sensor is exposed. The sensor was found to have a linear response to oxygen concentration on a semi-logarithmic scale within the oxygen concentration range between 0.6% and 20.9%, a response time and a recovery time of about 3 s, ant to exhibit good reversibility and repeatability. An increase in temperature from 21.degree. C. to 35.degree. C. does not affect the net absorption of the sensor.

  15. The effect of phosphomonoesterases on the oxygen isotope composition of phosphate

    E-Print Network [OSTI]

    Gilli, Adrian

    October 2013; available online 29 October 2013 Abstract Plants and microorganisms under phosphorus (P prepared in order to determine the oxygen isotope frac- tionation caused by these enzymes. Adenosine 50). In terrestrial systems, plants and soil microorganisms take up P as orthophosphate (Pi) from the soil solution

  16. EVOLUTION OF ATMOSPHERIC OXYGEN D Catling, University of Washington, Seattle, WA, USA

    E-Print Network [OSTI]

    Winglee, Robert M.

    , the biological process in which water molecules are split using the energy of sunlight. Today, green plants as the standard history of the Earth's atmosphere. This history has been a major influence on life. All animals, multicellular plants, and fungi rely on free oxygen to maintain their energy intensive lifestyles. Life

  17. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana

    2003-08-07

    In the present quarter, experiments are presented on ceramic/metal interactions of Zirconia/ Ni-B-Si system and with a thin Ti coating deposited on zirconia surface. Existing facilities were modified for evaluation of environmental assisted slow crack growth and creep in flexural mode. Processing of perovskites of LSC, LSF and LSCF composition were continued for evaluation of mechanical properties as a function of environment. These studies in parallel to those on the LSFCO composition is expect to yield important information on questions such as the role of cation segregation and the stability of the perovskite structure on crack initiation vs. crack growth. Studies have been continued on the La{sub 1-x}Sr{sub x}FeO{sub 3-d} composition using neutron diffraction and TGA studies. A transition from p-type to n-type of conductor was observed at relative low pO{sub 2}, at which the majority carriers changed from the holes to electrons because of the valence state decreases in Fe due to the further loss of oxygen. Investigation on the thermodynamic properties of the membrane materials are continued to develop a complete model for the membrane transport. Data obtained at 850 C show that the stoichiometry in La{sub 0.2}Sr{sub 0.8}Fe{sub 0.8}Cr{sub 0.2}O{sub 3-x} vary from {approx}2.85 to 2.6 over the pressure range studied. From the stoichiometry a lower limit of 2.6 corresponding to the reduction of all Fe{sup 4+} to Fe{sup 3+} and no reduction of Cr{sup 3+} is expected.

  18. Photochemical oxygenation of a technetium fluoride using F{sub 2} and O{sub 2}

    SciTech Connect (OSTI)

    Beitz, J.V.; Williams, C.W.

    1996-10-01

    Photochemical conversion of technetium fluorides and oxyfluorides is largely uninvestigated. Because technetium was introduced into U.S. uranium enrichment plants, decommissioning and decontamination of these plants will involve technetium fluorides and oxyfluorides. Photochemical conversion of such compounds may facilitate waste minimization and cost avoidance goals during plant clean-up. Photochemical fluorination using ultraviolet photolysis of a mixture of fluorine and oxygen gases is an effective means of converting solid, nonvolatile fluorides of fight actinides, such as U, Np, and Pu, into volatile hexafluorides thereby removing surface radioactive contamination. Our studies involved the interaction of ultraviolet light, oxygen, and fluorine with technetium fluoride.

  19. Use of experience curves to estimate the future cost of power plants with CO2 capture

    E-Print Network [OSTI]

    Rubin, Edward S.; Yeh, Sonia; Antes, Matt; Berkenpas, Michael; Davison, John

    2007-01-01

    lique?ed natural gas (LNG) production plants, oxygencoal (PC) boilers LNG production Oxygen production Hydrogenin this study for (a) LNG production, ( b) PC boilers, (c)

  20. Polycyclic Aromatic Triptycenes: Oxygen Substitution Cyclization Strategies

    E-Print Network [OSTI]

    VanVeller, Brett

    The cyclization and planarization of polycyclic aromatic hydrocarbons with concomitant oxygen substitution was achieved through acid catalyzed transetherification and oxygen-radical reactions. The triptycene scaffold ...

  1. Engineering MulticomponentNanocatalystsfor Oxygen Reduction ...

    Office of Scientific and Technical Information (OSTI)

    Engineering MulticomponentNanocatalystsfor Oxygen Reduction Citation Details In-Document Search Title: Engineering MulticomponentNanocatalystsfor Oxygen Reduction Authors: Guo,...

  2. A lithium oxygen secondary battery

    SciTech Connect (OSTI)

    Semkow, K.W.; Sammells, A.F.

    1987-08-01

    In principle the lithium-oxygen couple should provide one of the highest energy densities yet investigated for advanced battery systems. The problem to this time has been one of identifying strategies for achieving high electrochemical reversibilities at each electrode under conditions where one might anticipate to also achieve long materials lifetimes. This has been addressed in recent work by us via the application of stabilized zirconia oxygen vacancy conducting solid electrolytes, for the effective separation of respective half-cell reactions.

  3. EVALUATING AN INNOVATIVE OXYGEN SENSOR FOR REMOTE SUBSURFACE OXYGEN MEASUREMENTS

    SciTech Connect (OSTI)

    Millings, M; Brian Riha, B; Warren Hyde, W; Karen Vangelas, K; Brian02 Looney, B

    2006-10-12

    Oxygen is a primary indicator of whether anaerobic reductive dechlorination and similar redox based processes contribute to natural attenuation remedies at chlorinated solvent contaminated sites. Thus, oxygen is a viable indicator parameter for documenting that a system is being sustained in an anaerobic condition. A team of researchers investigated the adaptation of an optical sensor that was developed for oceanographic applications. The optical sensor, because of its design and operating principle, has potential for extended deployment and sensitivity at the low oxygen levels relevant to natural attenuation. The results of the research indicate this tool will be useful for in situ long-term monitoring applications, but that the traditional characterization tools continue to be appropriate for characterization activities.

  4. Integration of oxygen plants and gas turbines in IGCC facilities

    SciTech Connect (OSTI)

    Smith, A.R.; Sorensen, J.C.; Woodward, D.W.

    1996-10-01

    The commercialization of Integrated Gasification Combined-Cycle (IGCC) power has been aided by concepts involving the integration of a cryogenic air separation unit (ASU) with the gas turbine combined-cycle module. It is known and now widely accepted that an ASU designed for elevated pressure service and optimally integrated with the gas turbine can increase overall IGCC power output, increase overall efficiency, and decrease the net cost of power generation compared to non-integrated facilities employing low pressure ASU`s. Depending upon the specific gas turbine, gasification technology, NO{sub x} emission specification, and other site specific factors, various degrees of compressed air and nitrogen integration are optimal. Air Products has supplied ASU`s with no integration (Destec/Plaquemine IGCC), nitrogen-only integration (Tampa Electric/Polk County IGCC), and full air and nitrogen integration (Demkolec/Buggenum IGCC). Continuing advancements in both air separation and gas turbine technologies offer new integration opportunities to further improve performance and reduce costs. This paper reviews basic integration principles, highlights the integration scheme used at Polk County, and describes some advanced concepts based on emerging gas turbines. Operability issues associated with integration will be reviewed and control measures described for the safe, efficient, and reliable operation of these facilities.

  5. Oxygen uptake of benthic systems 

    E-Print Network [OSTI]

    Priebe, William Franklin

    1972-01-01

    mg/hr/sq m between standard and maximum mixing. Hanes and Irvine (23) made a determination of the effects of temperature on quiescent oxygen uptake rates by covering sludge with aerated water and allowing the supernatant to be totally de- pleted.... ECTROLTSIS STSTDI FOA MEMURIRC BOO. FIGURE 2. SWITCH ELECTROQE IN CONTACT WITH ELECTROIYTE. OXYGEN GENERATOR OFF. FIGURE 3. SWIICH ELECI'RODE NOT IN CONTACT' WITH -' ECTROLYTE. 0 0 0 a 0 0 0 ~ O0 0 o 0 0 o o 0 0 0 0 PIERRE A. HIGH SPEED NIXINC...

  6. Energy and materials flows in the production of liquid and gaseous oxygen

    SciTech Connect (OSTI)

    Shen, S.; Wolsky, A.M.

    1980-08-01

    Liquid and gaseous oxygen is produced in an energy-intensive air separation processo that also generates nitrogen. More than 65% of the cost of oxygen is attributable to energy costs. Energy use and materials flows are analyzed for various air separation methods. Effective approaches to energy and material conservation in air separation plants include efficient removal of contaminants (carbon dioxide and water), centralization of air products user-industries so that large air separation plants are cost-effective and the energy use in transportation is minimized, and increased production of nitrogen. Air separation plants can produce more than three times more nitrogen than oxygen, but present markets demand, at most, only 1.5 times more. Full utlization of liquid and gaseous nitrogen should be encouraged, so that the wasted separation energy is minimized. There are potential markets for nitrogen in, for example, cryogenic separation of metallic and plastic wastes, cryogenic particle size reduction, and production of ammonia for fertilizer.

  7. Methods for separating oxygen from oxygen-containing gases

    DOE Patents [OSTI]

    Mackay, Richard (Lafayette, CO); Schwartz, Michael (Boulder, CO); Sammells, Anthony F. (Boulder, CO)

    2000-01-01

    This invention provides mixed conducting metal oxides particularly useful for the manufacture of catalytic membranes for gas-phase oxygen separation processes. The materials of this invention have the general formula: A.sub.x A'.sub.x A".sub.2-(x+x') B.sub.y B'.sub.y B".sub.2-(y+y') O.sub.5+z ; where x and x' are greater than 0; y and y' are greater than 0; x+x' is less than or equal to 2; y+y' is less than or equal to 2; z is a number that makes the metal oxide charge neutral; A is an element selected from the f block lanthanide elements; A' is an element selected from Be, Mg, Ca, Sr, Ba and Ra; A" is an element selected from the f block lanthanides or Be, Mg, Ca, Sr, Ba and Ra; B is an element selected from the group consisting of Al, Ga, In or mixtures thereof; and B' and B" are different elements and are independently selected from the group of elements Mg or the d-block transition elements. The invention also provides methods for oxygen separation and oxygen enrichment of oxygen deficient gases which employ mixed conducting metal oxides of the above formula. Examples of the materials used for the preparation of the membrane include A.sub.x Sr.sub.x' B.sub.y Fe.sub.y' Co.sub.2-(y+y') O.sub.5+z, where x is about 0.3 to about 0.5, x' is about 1.5 to about 1.7, y is 0.6, y' is between about 1.0 and 1.4 and B is Ga or Al.

  8. Microchemical systems for singlet oxygen generation

    E-Print Network [OSTI]

    Hill, Tyrone F. (Tyrone Frank), 1980-

    2008-01-01

    Chemical Oxygen-Iodine Lasers (COIL) are a technology of interest for industrial and military audiences. COILs are flowing gas lasers where the gain medium of iodine atoms is collisionally pumped by singlet delta oxygen ...

  9. The Role of Oxygen in Coal Gasification 

    E-Print Network [OSTI]

    Klosek, J.; Smith, A. R.; Solomon, J.

    1986-01-01

    of capital and energy. This paper examines the major factors in oxygen purity selection for typical coal gasifiers. Examples demonstrating the effect of oxygen purity on several processes are presented: production of synthetic natural gas (SNG), integrated...

  10. Mitochondrial reactive oxygen species and cancer

    E-Print Network [OSTI]

    Chandel, Navdeep S

    Mitochondria produce reactive oxygen species (mROS) as a natural by-product of electron transport chain activity. While initial studies focused on the damaging effects of reactive oxygen species, a recent paradigm shift ...

  11. Microbial oceanography of anoxic oxygen minimum zones

    E-Print Network [OSTI]

    Ulloa, Osvaldo

    Vast expanses of oxygen-deficient and nitrite-rich water define the major oxygen minimum zones (OMZs) of the global ocean. They support diverse microbial communities that influence the nitrogen economy of the oceans, ...

  12. Oxygen addition to sulfur of metal thiolates 

    E-Print Network [OSTI]

    Soma, Takako

    1996-01-01

    chemistry. The oxidation reactions of metal thiolates by hydrogen peroxide, molecular oxygen, dioxiranes, and peracids have been reviewed. The compounds resulting from oxidation and oxygenation of nickel thiolate complexes have been isolated, separated...

  13. Catalyst containing oxygen transport membrane

    DOE Patents [OSTI]

    Christie, Gervase Maxwell; Wilson, Jamie Robyn; van Hassel, Bart Antonie

    2012-12-04

    A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a high average pore diameter and the intermediate porous layer has a lower permeability and lower pore diameter than the porous support layer. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer.

  14. Method for providing oxygen ion vacancies in lanthanide oxides

    DOE Patents [OSTI]

    Kay, D. Alan R. (4305 Lakeshore Rd., Burlington, CA); Wilson, William G. (820 Harden Dr., Pittsburgh, PA 15229)

    1989-12-05

    A method for desulfurization of fuel gases resulting from the incomplete combustion of sulfur containing hydrocarbons whereby the gases are treated with lanthanide oxides containing large numbers of oxygen-ion vacancies providing ionic porosity which enhances the ability of the lanthanide oxides to react more rapidly and completely with the sulfur in the fuel gases whereby the sulfur in such gases is reduced to low levels suitable for fuels for firing into boilers of power plants generating electricity with steam turbine driven generators, gas turbines, fuel cells and precursors for liquid fuels such as methanol and the like.

  15. Wastewater Discharge, Nutrient Loading, and Dissolved Oxygen Dynamics in a Shallow Texas Bay 

    E-Print Network [OSTI]

    Schroer, Lee Allen

    2014-05-07

    In Oso Bay, a wastewater treatment plant acts as a source of eutrophication and may have measureable impact on the health of the bay. The objectives of this study were to create a model for modeling dissolved oxygen concentrations over time...

  16. Consequences of a Rapid Cellulose Extraction Technique for Oxygen Isotope and Radiocarbon

    E-Print Network [OSTI]

    Schrag, Daniel

    Consequences of a Rapid Cellulose Extraction Technique for Oxygen Isotope and Radiocarbon Analyses isotope analyses to investigate the purity of cellulose extracted from wood using a rapid processing and plant physiological processes has typically focused on the R-cellulose component of wood, necessitating

  17. Physical Plant Power Plant - 32 

    E-Print Network [OSTI]

    Unknown

    2005-06-30

    Historically, a fixed cooling concept is used in the design of evaporative heat rejection systems for process and power plants. In the fixed cooling mode, a plant is designed for maximum output at the design summer wet bulb temperature...

  18. Oxygenate Supply/Demand Balances

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1Markets16 (next20, 20082008707Oxygenate

  19. Developments in ITM oxygen technology for IGCC

    SciTech Connect (OSTI)

    Stein, V.E.E.; Richards, R.E.

    1999-07-01

    In partnership with the U.S. Department of Energy (DOE), an Air Products-led team (with Ceramatec, Eltron Research, McDermott Technology, NREC, Texaco, the Pennsylvania State University, and the University of Pennsylvania) is developing a new technology for air separation - Ion Transport Membrane Oxygen - based on the use of mixed-conducting ceramic membranes that have both electronic and oxygen ionic conductivity when operated at high temperature, typically 800 to 900 C. Under the influence of an oxygen partial-pressure driving force, the ITM Oxygen process achieves a high-purity, high-flux separation of oxygen from a compressed-air stream. By integrating the energy-rich, oxygen-depleted, non-permeate stream with a gas turbine system, the ITM Oxygen process becomes a co-producer of high-purity oxygen, power, and steam. Under a recent CRADA entitled ``Ion Transport Membranes (ITM) for Oxygen-Blown IGCC Systems and Indirect Coal Liquefaction,'' Air Products and DOE completed an initial quantification of the benefits of an ITM Oxygen-integrated IGCC facility. Compared to the cryogenic oxygen base case, the ITM Oxygen technology can potentially: reduce total installed costs by 7%; improve thermal efficiency for the integrated IGCC system by about 3%, leading to further decreases in carbon dioxide and sulfur emissions; and reduce the cost of generated electric power by more than 6%. The ITM Oxygen development project will proceed in three phases. Phase 1, which commenced under a DOE Cooperative Agreement in October 1998, is a 3-year effort focusing on construction of a technology development unit (TDU) for process concept validation tests at a capacity of 0.1 ton-per-day (TPD) oxygen. To accomplish this objective, the Air Products team will address relevant technical challenges in ITM Oxygen materials, engineering, membrane module development, and performance testing. During Phase 1 the team will also verify the economic prospects for integrating ITM Oxygen technology with IGCC and other advanced power generation systems. After at least one intermediate scaleup, Phase 2 and 3 activities will culminate with scaleup to a 25- to 50-TPD pre-commercial demonstration unit, fully integrated with a gas turbine. Meeting these challenges of developing cost-effective fabrication techniques for ITM Oxygen devices, and successfully integrating them with commercially available gas turbine engines, is key to bringing ITM Oxygen technology to the marketplace.

  20. Energy Efficiency Improvement and Cost Saving Opportunities for the U.S. Iron and Steel Industry An ENERGY STAR(R) Guide for Energy and Plant Managers

    E-Print Network [OSTI]

    Worrell, Ernst

    2011-01-01

    In addition, the coking coal market began to deteriorateits permeability. Bituminous, or coking coal, is blended andmerchant coke plants, coking coal is heated in a low-oxygen,

  1. Energy Efficiency Improvement and Cost Saving Opportunities for the U.S. Iron and Steel Industry An ENERGY STAR(R) Guide for Energy and Plant Managers

    E-Print Network [OSTI]

    Worrell, Ernst

    2011-01-01

    and Blaustein, 2001). Heat Recovery. More than 85% of thePlant Focuses on Heat Recovery and Cogeneration duringwith coal injection, heat recovery, oxygen addition, and

  2. Energy Efficiency Improvement and Cost Saving Opportunities for the U.S. Iron and Steel Industry An ENERGY STAR(R) Guide for Energy and Plant Managers

    E-Print Network [OSTI]

    Worrell, Ernst

    2011-01-01

    Plant Focuses on Heat Recovery and Cogeneration duringand Blaustein, 2001). Heat Recovery. More than 85% of thewith coal injection, heat recovery, oxygen addition, and

  3. Device and method for separating oxygen isotopes

    DOE Patents [OSTI]

    Rockwood, Stephen D. (Los Alamos, NM); Sander, Robert K. (Los Alamos, NM)

    1984-01-01

    A device and method for separating oxygen isotopes with an ArF laser which produces coherent radiation at approximately 193 nm. The output of the ArF laser is filtered in natural air and applied to an irradiation cell where it preferentially photodissociates molecules of oxygen gas containing .sup.17 O or .sup.18 O oxygen nuclides. A scavenger such as O.sub.2, CO or ethylene is used to collect the preferentially dissociated oxygen atoms and recycled to produce isotopically enriched molecular oxygen gas. Other embodiments utilize an ArF laser which is narrowly tuned with a prism or diffraction grating to preferentially photodissociate desired isotopes. Similarly, desired mixtures of isotopic gas can be used as a filter to photodissociate enriched preselected isotopes of oxygen.

  4. Merchant Green | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OFAMERICA'SHeavyAgency (IRENA) JumpLiteratureMengdong Xiehe New Energy Co

  5. Identification of an Archean marine oxygen oasis

    SciTech Connect (OSTI)

    Riding, Dr Robert E; Fralick, Dr Philip; Liang, Liyuan

    2014-01-01

    The early Earth was essentially anoxic. A number of indicators suggest the presence of oxygenic photosynthesis 2700 3000 million years (Ma) ago, but direct evidence for molecular oxygen (O2) in seawater has remained elusive. Here we report rare earth element (REE) analyses of 2800 million year old shallowmarine limestones and deep-water iron-rich sediments at Steep Rock Lake, Canada. These show that the seawater from which extensive shallow-water limestones precipitated was oxygenated, whereas the adjacent deeper waters where iron-rich sediments formed were not. We propose that oxygen promoted limestone precipitation by oxidative removal of dissolved ferrous iron species, Fe(II), to insoluble Fe(III) oxyhydroxide, and estimate that at least 10.25 M oxygen concentration in seawater was required to accomplish this at Steep Rock. This agrees with the hypothesis that an ample supply of dissolved Fe(II) in Archean oceans would have hindered limestone formation. There is no direct evidence for the oxygen source at Steep Rock, but organic carbon isotope values and diverse stromatolites in the limestones suggest the presence of cyanobacteria. Our findings support the view that during the Archean significant oxygen levels first developed in protected nutrient-rich shallow marine habitats. They indicate that these environments were spatially restricted, transient, and promoted limestone precipitation. If Archean marine limestones in general reflect localized oxygenic removal of dissolved iron at the margins of otherwise anoxic iron-rich seas, then early oxygen oases are less elusive than has been assumed.

  6. Oxygen ion-beam microlithography

    DOE Patents [OSTI]

    Tsuo, Y.S.

    1991-08-20

    A method of providing and developing a resist on a substrate for constructing integrated circuit (IC) chips includes the following steps: of depositing a thin film of amorphous silicon or hydrogenated amorphous silicon on the substrate and exposing portions of the amorphous silicon to low-energy oxygen ion beams to oxidize the amorphous silicon at those selected portions. The nonoxidized portions are then removed by etching with RF-excited hydrogen plasma. Components of the IC chip can then be constructed through the removed portions of the resist. The entire process can be performed in an in-line vacuum production system having several vacuum chambers. Nitrogen or carbon ion beams can also be used. 5 figures.

  7. Transient oxygen consumption rate measurements with the BDT?M? oxygen biosensor system

    E-Print Network [OSTI]

    Low, Clarke Alan

    2008-01-01

    Oxygen consumption rate (OCR) is a reliable indicator of tissue health. Recently, the OCR of isolated human islets has been shown to predict transplant outcome in diabetic mice. The Oxygen Biosensor System (OBS) is a ...

  8. Oxygen-Reducing Biocathodes Operating with Passive Oxygen Transfer in Microbial Fuel Cells

    E-Print Network [OSTI]

    Oxygen-Reducing Biocathodes Operating with Passive Oxygen Transfer in Microbial Fuel Cells Xue Xia.R. China Department of Civil and Environmental Engineering, Penn State University, 231Q Sackett Building of the catholyte. To avoid the need for aeration, the ability of biocathodes to function with passive oxygen

  9. New Oxygen-Production Technology Proving Successful

    Broader source: Energy.gov [DOE]

    The Office of Fossil Energy's National Energy Technology Laboratory has partnered with Air Products and Chemicals Inc. of Allentown, Penn. to develop the Ion Transport Membrane (ITM) Oxygen, a revolutionary new oxygen-production technology that requires less energy and offers lower capital costs than conventional technologies.

  10. Oxygen ion-conducting dense ceramic

    DOE Patents [OSTI]

    Balachandran, Uthamalingam (Hinsdale, IL); Kleefisch, Mark S. (Naperville, IL); Kobylinski, Thaddeus P. (Lisle, IL); Morissette, Sherry L. (Las Cruces, NM); Pei, Shiyou (Naperville, IL)

    1997-01-01

    Preparation, structure, and properties of mixed metal oxide compositions containing at least strontium, cobalt, iron and oxygen are described. The crystalline mixed metal oxide compositions of this invention have, for example, structure represented by Sr.sub..alpha. (Fe.sub.1-x Co.sub.x).sub..alpha.+.beta. O.sub..delta. where x is a number in a range from 0.01 to about 1, .alpha. is a number in a range from about 1 to about 4, .beta. is a number in a range upward from 0 to about 20, and .delta. is a number which renders the compound charge neutral, and wherein the composition has a non-perovskite structure. Use of the mixed metal oxides in dense ceramic membranes which exhibit oxygen ionic conductivity and selective oxygen separation, are described as well as their use in separation of oxygen from an oxygen-containing gaseous mixture.

  11. Oxygen ion-conducting dense ceramic

    DOE Patents [OSTI]

    Balachandran, Uthamalingam (Hinsdale, IL); Kleefisch, Mark S. (Naperville, IL); Kobylinski, Thaddeus P. (Lisle, IL); Morissette, Sherry L. (Las Cruces, NM); Pei, Shiyou (Naperville, IL)

    1996-01-01

    Preparation, structure, and properties of mixed metal oxide compositions containing at least strontium, cobalt, iron and oxygen are described. The crystalline mixed metal oxide compositions of this invention have, for example, structure represented by Sr.sub..alpha. (Fe.sub.1-x Co.sub.x).sub..alpha.+.beta. O.sub..delta. where x is a number in a range from 0.01 to about 1, .alpha. is a number in a range from about 1 to about 4, .beta. is a number in a range upward from 0 to about 20, and .delta. is a number which renders the compound charge neutral, and wherein the composition has a non-perovskite structure. Use of the mixed metal oxides in dense ceramic membranes which exhibit oxygen ionic conductivity and selective oxygen separation, are described as well as their use in separation of oxygen from an oxygen-containing gaseous mixture.

  12. Modelling Hydrogen Reduction and Hydrodeoxygenation of Oxygenates

    SciTech Connect (OSTI)

    Zhao, Y.; Xu, Q.; Cheah, S.

    2013-01-01

    Based on Density Functional Theory (DFT) simulations, we have studied the reduction of nickel oxide and biomass derived oxygenates (catechol, guaiacol, etc.) in hydrogen. Both the kinetic barrier and thermodynamic favorability are calculated with respect to the modeled reaction pathways. In early-stage reduction of the NiO(100) surface by hydrogen, the pull-off of the surface oxygen atom and simultaneous activation of the nearby Ni atoms coordinately dissociate the hydrogen molecules so that a water molecule can be formed, leaving an oxygen vacancy on the surface. In hydrogen reaction with oxygenates catalyzed by transition metals, hydrogenation of the aromatic carbon ring normally dominates. However, selective deoxygenation is of particular interest for practical application such as biofuel conversion. Our modeling shows that doping of the transition metal catalysts can change the orientation of oxygenates adsorbed on metal surfaces. The correlation between the selectivity of reaction and the orientation of adsorption are discussed.

  13. Commercialization Development of Oxygen Fired CFB for Greenhouse Gas Control

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl; David G. Turek

    2007-03-31

    Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic (i.e., man-made) CO{sub 2} emissions. In 2001, ALSTOM Power Inc. (ALSTOM) began a two-phase program to investigate the feasibility of various carbon capture technologies. This program was sponsored under a Cooperative Agreement from the US Department of Energy's National Energy Technology Laboratory (DOE). The first phase entailed a comprehensive study evaluating the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen cases, representing various levels of technology development, were evaluated. Seven cases represented coal combustion in CFB type equipment. Four cases represented Integrated Gasification Combined Cycle (IGCC) systems. Two cases represented advanced Chemical Looping Combined Cycle systems. Marion, et al. reported the details of this work in 2003. One of the thirteen cases studied utilized an oxygen-fired circulating fluidized bed (CFB) boiler. In this concept, the fuel is fired with a mixture of oxygen and recirculated flue gas (mainly CO{sub 2}). This combustion process yields a flue gas containing over 80 percent (by volume) CO{sub 2}. This flue gas can be processed relatively easily to enrich the CO{sub 2} content to over 96 percent for use in enhanced oil or gas recovery (EOR or EGR) or simply dried for sequestration. The Phase I study identified the O{sub 2}-fired CFB as having a near term development potential, because it uses conventional commercial CFB technology and commercially available CO{sub 2} capture enabling technologies such as cryogenic air separation and simple rectification or distillation gas processing systems. In the long term, air separation technology advancements offer significant reductions in power requirements, which would improve plant efficiency and economics for the oxygen-fired technology. The second phase consisted of pilot-scale testing followed by a refined performance and economic evaluation of the O{sub 2} fired CFB concept. As a part of this workscope, ALSTOM modified its 3 MW{sub th} (9.9 MMBtu/hr) Multiuse Test Facility (MTF) pilot plant to operate with O{sub 2}/CO{sub 2} mixtures of up to 70 percent O{sub 2} by volume. Tests were conducted with coal and petroleum coke. The test objectives were to determine the impacts of oxygen firing on heat transfer, bed dynamics, potential agglomeration, and gaseous and particulate emissions. The test data results were used to refine the design, performance, costs, and economic models developed in Phase-I for the O{sub 2}-fired CFB with CO{sub 2} capture. Nsakala, Liljedahl, and Turek reported results from this study in 2004. ALSTOM identified several items needing further investigation in preparation for large scale demonstration of the oxygen-fired CFB concept, namely: (1) Operation and performance of the moving bed heat exchanger (MBHE) to avoid recarbonation and also for cost savings compared to the standard bubbling fluid bed heat exchanger (FBHE); (2) Performance of the back-end flash dryer absorber (FDA) for sulfur capture under high CO{sub 2}/high moisture flue gas environment using calcined limestone in the fly ash and using fresh commercial lime directly in the FDA; (3) Determination of the effect of recarbonation on fouling in the convective pass; (4) Assessment of the impact of oxygen firing on the mercury, other trace elements, and volatile organic compound (VOC) emissions; and (5) Develop a proposal-level oxygen-fired retrofit design for a relatively small existing CFB steam power plant in preparation for a large-scale demonstration of the O{sub 2} fired CFB concept. Hence, ALSTOM responded to a DOE Solicitation to address all these issues with further O{sub 2} fired MTF pilot testing and a subsequent retrofit design study of oxygen firing and CO{s

  14. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2004-04-01

    Conventional wisdom says adding oxygen to a combustion system enhances product throughput, system efficiency, and, unless special care is taken, increases NOx emissions. This increase in NOx emissions is typically due to elevated flame temperatures associated with oxygen use leading to added thermal NOx formation. Innovative low flame temperature oxy-fuel burner designs have been developed and commercialized to minimize both thermal and fuel NOx formation for gas and oil fired industrial furnaces. To be effective these systems require close to 100% oxy-fuel combustion and the cost of oxygen is paid for by fuel savings and other benefits. For applications to coal-fired utility boilers at the current cost of oxygen, however, it is not economically feasible to use 100% oxygen for NOx control. In spite of this conventional wisdom, Praxair and its team members, in partnership with the US Department of Energy National Energy Technology Laboratory, have developed a novel way to use oxygen to reduce NOx emissions without resorting to complete oxy-fuel conversion. In this concept oxygen is added to the combustion process to enhance operation of a low NOx combustion system. Only a small fraction of combustion air is replaced with oxygen in the process. By selectively adding oxygen to a low NOx combustion system it is possible to reduce NOx emissions from nitrogen-containing fuels, including pulverized coal, while improving combustion characteristics such as unburned carbon. A combination of experimental work and modeling was used to define how well oxygen enhanced combustion could reduce NOx emissions. The results of this work suggest that small amounts of oxygen replacement can reduce the NOx emissions as compared to the air-alone system. NOx emissions significantly below 0.15 lbs/MMBtu were measured. Oxygen addition was also shown to reduce carbon in ash. Comparison of the costs of using oxygen for NOx control against competing technologies, such as SCR, show that this concept offers substantial savings over SCR and is an economically attractive alternative to purchasing NOx credits or installing other conventional technologies. In conjunction with the development of oxygen based low NOx technology, Praxair also worked on developing the economically enhancing oxygen transport membrane (OTM) technology which is ideally suited for integration with combustion systems to achieve further significant cost reductions and efficiency improvements. This OTM oxygen production technology is based on ceramic mixed conductor membranes that operate at high temperatures and can be operated in a pressure driven mode to separate oxygen with infinite selectivity and high flux. An OTM material was selected and characterized. OTM elements were successfully fabricated. A single tube OTM reactor was designed and assembled. Testing of dense OTM elements was conducted with promising oxygen flux results of 100% of target flux. However, based on current natural gas prices and stand-alone air separation processes, ceramic membranes do not offer an economic advantage for this application. Under a different DOE-NETL Cooperative Agreement, Praxair is continuing to develop oxygen transport membranes for the Advanced Boiler where the economics appear more attractive.

  15. On the oxygen abundance in our Galaxy

    E-Print Network [OSTI]

    L. S. Pilyugin; F. Ferrini; R. V. Shkvarun

    2003-02-03

    The compilation of published spectra of Galactic HII regions with available diagnostic [OIII]4363 line has been carried out. Our list contains 71 individual measurements of 13 HII regions in the range of galactocentric distances from 6.6 to 14.8 kpc. The oxygen abundances in all the HII regions were recomputed in the same way, using the classic Te - method. The oxygen abundance at the solar galactocentric distance traced by those HII regions is in agreement with the oxygen abundance in the interstellar medium in the solar vicinity derived with high precision from the interstellar absorption lines towards stars. The derived radial oxygen abundance distribution was compared with that for HII regions from the Shaver et al. (1983) sample which is the basis of many models for the chemical evolution of our Galaxy. It was found that the original Shaver et al.'s oxygen abundances are overestimated by 0.2-0.3 dex. Oxygen abundances in HII regions from the Shaver et al. sample have been redetermined with the recently suggested P - method. The radial distribution of oxygen abundances from the Shaver et al. sample redetermined with the P - method is in agreement with our radial distribution of (O/H)_Te abundances.

  16. Physical Plant Power Plant - 43 

    E-Print Network [OSTI]

    Unknown

    2005-06-30

    with higher efficiency / R&D Climate friendly Power Plants Build coal fired Power Plants with CCS-technology 4 B a c k u p va W GGEHEN ESL-IC-08-10-27 Proceedings of the Eighth International Conference for Enhanced Building Operations, Berlin, Germany..., October 20-22, 2008 RWE Energy / Energieeffizienz bei Immobilien / U. K?nig / ICEBO '08 SEITE 9 Electricity Production: All Energy Sources have to be included! Lignite Power Plant (BoA) produces 8,8 TWh = appr. 12% of the annual demand for electricity...

  17. Modulating tissue mechanics to increase oxygen delivery to tumors

    E-Print Network [OSTI]

    Martin, John Daniel, Ph. D. Massachusetts Institute of Technology

    2015-01-01

    Solid tumors have low oxygen tension - hypoxia - that fuels disease progression and treatment resistance. Thus, strategies for alleviating hypoxia are needed. Two factors affect tissue oxygen levels: oxygen supply via blood ...

  18. Characterization of an oxygen suspension used for intravenous infusion

    E-Print Network [OSTI]

    Peña, Kristen Helen

    2012-01-01

    Oxygenated fluid mixture can be used to treat critically ill patients suffering from asphyxia, lung injury, and cardiac arrest. This oxygenated fluid delivered intravenously re-oxygenates the bloodstream, allowing for more ...

  19. Impact of UV light on the plant cell wall, methane emissions and ROS production 

    E-Print Network [OSTI]

    Messenger, David James

    2009-01-01

    This study presents the first attempt to combine the fields of ultraviolet (UV) photobiology, plant cell wall biochemistry, aerobic methane production and reactive oxygen species (ROS) mechanisms to investigate the effect ...

  20. Systems-level design of ion transport membrane oxy-combustion power plants

    E-Print Network [OSTI]

    Mancini, Nicholas D. (Nicholas David)

    2011-01-01

    Oxy-fuel combustion, particularly using an integrated oxygen ion transport membrane (ITM), is a thermodynamically attractive concept that seeks to mitigate the penalties associated with CO 2 capture from power plants. ...

  1. Selective reduction of NOx in oxygen rich environments with plasma...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    reduction of NOx in oxygen rich environments with plasma-assisted catalysis: Catalyst development and mechanistic studies Selective reduction of NOx in oxygen rich environments...

  2. Virtual Oxygen Sensor for Innovative NOx and PM Emission Control...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies A virtual O2 sensor for...

  3. Oxygen-Enriched Combustion for Military Diesel Engine Generators...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oxygen-Enriched Combustion for Military Diesel Engine Generators Oxygen-Enriched Combustion for Military Diesel Engine Generators Substantial increases in brake power and...

  4. Advantages of Oxygenates Fuels over Gasoline in Direct Injection...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines...

  5. Design optimization of oxygenated fluid pump

    E-Print Network [OSTI]

    Piazzarolo, Bruno Aiala

    2012-01-01

    In medical emergencies, an oxygen-starved brain quickly suffers irreparable damage. In many cases, patients who stop breathing can be resuscitated but suffer from brain damage. Dr. John Kheir from Boston Children's Hospital ...

  6. Dynamic Nuclear Polarization of Oxygen-17

    E-Print Network [OSTI]

    Michaelis, Vladimir K.

    Oxygen-17-detected DNP NMR of a water/glycerol glass enabled an 80-fold enhancement of signal intensity at 82 K, using the biradical TOTAPOL. The >6000-fold savings in acquisition time enable [superscript 17]O–[superscript ...

  7. OXYGEN DIFFUSION IN HYPOSTOICHIOMETRIC URANIUM DIOXIDE

    E-Print Network [OSTI]

    Kim, Kee Chul

    2010-01-01

    IN HYPOSTOICHIOMETRIC URANIUM DIOXIDE Kee Chul Kim Ph.D.727-366; Figure 1. Oxygen-uranium phase-equilibrium _ystem [18]. uranium dioxide powders and 18 0 enriched carbon

  8. Oxygen Enriched Combustion System Performance Study 

    E-Print Network [OSTI]

    Chen, S. L.; Kwan, Y.; Abele, A. R.; Silver, L. S.; Kobayashi, H.

    1987-01-01

    i ndustri al furnaces, such as gl ass melting furnaces, appear to be the most promising appli cations for oxygen enriched combustion. In these applications, the principal energy savings results from minimizing the fuel energy required to heat... with non-water cooled refractory burner til es. The Oxytherm Burner was developed jointly by Maxon and Corning Glass for application of oxygen/fuel combustion in glass furnaces. This burner is also a non-water cooled refractory design with a specially...

  9. Underground coal gasification using oxygen and steam

    SciTech Connect (OSTI)

    Yang, L.H.; Zhang, X.; Liu, S. [China University of Mining & Technology, Xuzhou (China)

    2009-07-01

    In this paper, through model experiment of the underground coal gasification, the effects of pure oxygen gasification, oxygen-steam gasification, and moving-point gasification methods on the underground gasification process and gas quality were studied. Experiments showed that H{sub 2} and CO volume fraction in product gas during the pure oxygen gasification was 23.63-30.24% and 35.22-46.32%, respectively, with the gas heating value exceeding 11.00 MJ/m{sup 3}; under the oxygen-steam gasification, when the steam/oxygen ratio stood at 2: 1, gas compositions remained virtually stable and CO + H{sub 2} was basically between 61.66 and 71.29%. Moving-point gasification could effectively improve the changes in the cavity in the coal seams or the effects of roof inbreak on gas quality; the ratio of gas flowing quantity to oxygen supplying quantity was between 3.1:1 and 3.5:1 and took on the linear changes; on the basis of the test data, the reasons for gas quality changes under different gasification conditions were analyzed.

  10. Magnetism in Lithium–Oxygen Discharge Product

    SciTech Connect (OSTI)

    Lu, Jun; Jung, Hun-Ji; Lau, Kah Chun; Zhang, Zhengcheng; Schlueter, John A.; Du, Peng; Assary, Rajeev S.; Greeley, Jeffrey P.; Ferguson, Glen A.; Wang, Hsien-Hau; Hassoun, Jusef; Iddir, Hakim; Zhou, Jigang; Zuin, Lucia; Hu, Yongfeng; Sun, Yang-Kook; Scrosati, Bruno; Curtiss, Larry A.; Amine, Khalil

    2013-05-13

    Nonaqueous lithium–oxygen batteries have a much superior theoretical gravimetric energy density compared to conventional lithium-ion batteries, and thus could render long-range electric vehicles a reality. A molecular-level understanding of the reversible formation of lithium peroxide in these batteries, the properties of major/minor discharge products, and the stability of the nonaqueous electrolytes is required to achieve successful lithium–oxygen batteries. We demonstrate that the major discharge product formed in the lithium–oxygen cell, lithium peroxide, exhibits a magnetic moment. These results are based on dc-magnetization measurements and a lithium– oxygen cell containing an ether-based electrolyte. The results are unexpected because bulk lithium peroxide has a significant band gap. Density functional calculations predict that superoxide- type surface oxygen groups with unpaired electrons exist on stoichiometric lithium peroxide crystalline surfaces and on nanoparticle surfaces; these computational results are consistent with the magnetic measurement of the discharged lithium peroxide product as well as EPR measurements on commercial lithium peroxide. The presence of superoxide-type surface oxygen groups with spin can play a role in the reversible formation and decomposition of lithium peroxide as well as the reversible formation and decomposition of electrolyte molecules.

  11. Atomic Oxygen in the Comae of Comets

    E-Print Network [OSTI]

    Anita L. Cochran

    2008-07-03

    We report on the detection of atomic oxygen lines in the spectra of 8 comets. These forbidden lines are a result of the photodissociation of the parent oxygen-bearing species directly into an excited state. We used high resolution spectra obtained at the McDonald Observatory 2.7m telescope to resolve the cometary oxygen lines from the telluric oxygen lines and from other cometary emissions. We find that the relative intensities of the two red lines (6300.304 and 6363.776A) are consistent with theory. The green line (5577.339A) has an intensity which is about 10% of the sum of the intensities of the two red lines. We show that collisional quenching may be important in the inner coma. If we assume the relative excitation rates of potential parents which have appeared in the literature, then H2O would be the parent of the cometary green oxygen line. However, those rates have been questioned. We measured the width of the three oxygen lines and find that the green line is wider than either of the two red lines. The finding of a wider line could imply a different parent for the green and red lines. However, the constancy of the green to red line flux ratio suggests the parent is the same for these lines but that the exciting photons have different energies.

  12. Oxygen generator for medical applications (USIC)

    SciTech Connect (OSTI)

    Staiger, C. L.

    2012-03-01

    The overall Project objective is to develop a portable, non-cryogenic oxygen generator capable of supplying medical grade oxygen at sufficient flow rates to allow the field application of the Topical Hyperbaric Oxygen Therapy (THOT{reg_sign}) developed by Numotech, Inc. This project was sponsored by the U.S. Department of Energy Global Initiatives for Proliferation Prevention (GIPP) and is managed by collaboration between Sandia National Laboratories (SNL), Numotech, Inc, and LLC SPE 'Spektr-Conversion.' The project had two phases, with the objective of Phase I being to develop, build and test a laboratory prototype of the membrane-pressure swing adsorber (PSA) system producing at 15 L/min of oxygen with a minimum of 98% oxygen purity. Phase II objectives were to further refine and identify the pre-requisites needed for a commercial product and to determine the feasibility of producing 15 L/min of oxygen with a minimum oxygen purity of 99%. In Phase I, Spektr built up the necessary infrastructure to perform experimental work and proceeded to build and demonstrate a membrane-PSA laboratory prototype capable of producing 98% purity oxygen at a flow rate of 5 L/min. Spektr offered a plausible path to scale up the process for 15 L/min. Based on the success and experimental results obtained in Phase I, Spektr performed work in three areas for Phase II: construction of a 15 L/min PSA; investigation of compressor requirements for the front end of the membrane/PSA system; and performing modeling and simulation of assess the feasibility of producing oxygen with a purity greater than 99%. Spektr successfully completed all of the tasks under Phase II. A prototype 15 L/min PSA was constructed and operated. Spektr determined that no 'off the shelf' air compressors met all of the specifications required for the membrane-PSA, so a custom compressor will likely need to be built. Modeling and simulation concluded that production of oxygen with purities greater than 99% was possible using a Membrane-PSA system.

  13. Primitive Land Plants 37 PRIMITIVE LAND PLANTS

    E-Print Network [OSTI]

    Koptur, Suzanne

    appeared at this time. Both of these groups of plants had life cycles, involving two generations. One of the year these mosses will produce tiny sporophytes. Prior to this generation, the tiny plants producedPrimitive Land Plants 37 PRIMITIVE LAND PLANTS These are the plants that were present soon after

  14. High energy density lithium-oxygen secondary battery

    SciTech Connect (OSTI)

    Sammells, A.F.

    1989-02-07

    A high energy density lithium-oxygen secondary cell is described comprising a lithium-containing negative electrode; a lithium ion conducting molten salt electrolyte contacting the negative electrode; an oxygen ion conducting solid electrolyte contacting and containing the molten salt electrolyte; and an oxygen redox positive electrode contacting the oxygen ion conducting solid electrolyte.

  15. Oxygen abundance of open cluster dwarfs

    E-Print Network [OSTI]

    Z. -X. Shen; X. -W. Liu; H. -W. Zhang; B. Jones; D. N. C. Lin

    2007-03-30

    We present oxygen abundances of dwarfs in the young open cluster IC 4665 deduced from the OI $\\lambda$7774 triplet lines and of dwarfs in the open cluster Pleiades derived from the [OI] $\\lambda$6300 forbidden line. Stellar parameters and oxygen abundances were derived using the spectroscopic synthesis tool SME (Spectroscopy Made Easy). We find a dramatic increase in the upper boundary of the OI triplet abundances with decreasing temperature in the dwarfs of IC 4665, consistent with the trend found by Schuler et al. in the open clusters Pleiades and M 34, and to a less extent in the cool dwarfs of Hyades (Schuler et al. 2006a) and UMa (King & Schuler 2005). By contrast, oxygen abundances derived from the [OI] $\\lambda$6300 forbidden line for stars in Pleiades and Hyades (Schuler et al. 2006b) are constant within the errors. Possible mechanisms that may lead a varying oxygen triplet line abundance are examined, including systematic errors in the stellar parameter determinations, the NLTE effects, surface activities and granulation. The age-related effects stellar surface activities (especially the chromospheric activities) are suggested by our analysis to blame for the large spreads of oxygen triplet line abundances.

  16. Oxygen isotopes in crystalline silicates of comet Wild 2: A comparison of oxygen isotope systematics between Wild 2 particles

    E-Print Network [OSTI]

    Meyers, Stephen R.

    Oxygen isotopes in crystalline silicates of comet Wild 2: A comparison of oxygen isotope 2012 Keywords: oxygen isotope ratios crystalline silicate comet 81P/Wild 2 solar system formation Stardust Abstract: Oxygen three-isotope ratios of nine crystalline silicate particles from comet Wild 2

  17. GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl

    2003-05-15

    Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this study, ALSTOM Power Inc. (ALSTOM) has investigated several coal fired power plant configurations designed to capture CO{sub 2} from effluent gas streams for use or sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB units results in significant Boiler Island cost savings. Additionally, ALSTOM has identified several advanced/novel plant configurations, which improve the efficiency and cost of the CO{sub 2} product cleanup and compression process. These advanced/novel concepts require long development efforts. An economic analysis indicates that the proposed oxygen-firing technology in circulating fluidized boilers could be developed and deployed economically in the near future in enhanced oil recovery (EOR) applications or enhanced gas recovery (EGR), such as coal bed methane recovery. ALSTOM received a Cooperative Agreement from the US Department of Energy National Energy Technology Laboratory (DOE) in 2001 to carry out a project entitled ''Greenhouse Gas Emissions Control by Oxygen Firing in Circulating Fluidized Bed Boilers.'' This two-phased project is in effect from September 28, 2001, to October 27, 2004. (U.S. DOE NETL Cooperative Agreement No. DE-FC26-01NT41146). Phase I consisted of an evaluation of the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants, and supporting bench-scale testing. And Phase II consists of pilot-scale testing, supporting a refined performance and economic evaluation of the oxygen-fired AFC concept. Phase I, detailed in this report, entails a comprehensive study evaluating the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen separate but related cases (listed below), representing various levels of technology development, were evaluated as described herein. The first seven cases represent coal combustion cases in CFB type equipment. The next four cases represent Integrated Gasification Combined Cycle (IGCC) systems. The last two cases represent advanced Chemical Looping systems, which were completely paid for by ALSTOM and included herein for completeness.

  18. Landscape Plants: Fertilizing & Watering

    E-Print Network [OSTI]

    Ishida, Yuko

    Landscape Plants: Fertilizing & Watering Landscape Plants: Fertilizing & Watering Prevent runoff and shrubs, either through directly killing plants or making them more prone to disease. Fertilizer runoff into storm drains pollutes waterways. Maintain plant health and protect water quality by fertilizing

  19. Energy-saving through remote control of a wastewater treatment plant

    E-Print Network [OSTI]

    Energy-saving through remote control of a wastewater treatment plant S. Marsili-Libelli *, G an energy-saving project being implemented on a conventional wastewater treatment plant, where several controllers. The main energy-saving target is the control of dissolved oxygen in the context of nitrogen

  20. Mechanism of singlet oxygen deactivation in an electric discharge oxygen – iodine laser

    SciTech Connect (OSTI)

    Azyazov, V N; Mikheyev, P A; Torbin, A P; Pershin, A A; Heaven, M C

    2014-12-31

    We have determined the influence of the reaction of molecular singlet oxygen with a vibrationally excited ozone molecule O{sub 2}(a {sup 1}?) + O{sub 3}(?) ? 2O{sub 2} + O on the removal rate of O{sub 2}(a {sup 1}?) in an electric-discharge-driven oxygen – iodine laser. This reaction has been shown to be a major channel of O{sub 2}(a {sup 1}?) loss at the output of an electric-discharge singlet oxygen generator. In addition, it can also contribute significantly to the loss of O{sub 2}(a {sup 1}?) in the discharge region of the generator. (lasers)

  1. An Advanced Oxygen Trim Control System 

    E-Print Network [OSTI]

    Miller, J. G.

    1985-01-01

    problems that can cause errors. First, the output of the cell is determined by the Nernst equation (B). (B) E RT 4r logn Pl P2 where E e.m.f. (potential) R Gas Co nstant T Absolute Temperature F Faraday Constant P2 Oxygen Partial Pressure...

  2. Novel Membranes and Processes for Oxygen Enrichment

    SciTech Connect (OSTI)

    Lin, Haiqing

    2011-11-15

    The overall goal of this project is to develop a membrane process that produces air containing 25-35% oxygen, at a cost of $25-40/ton of equivalent pure oxygen (EPO2). Oxygen-enriched air at such a low cost will allow existing air-fueled furnaces to be converted economically to oxygen-enriched furnaces, which in turn will improve the economic and energy efficiency of combustion processes significantly, and reduce the cost of CO{sub 2} capture and sequestration from flue gases throughout the U.S. manufacturing industries. During the 12-month Concept Definition project: We identified a series of perfluoropolymers (PFPs) with promising oxygen/nitrogen separation properties, which were successfully made into thin film composite membranes. The membranes showed oxygen permeance as high as 1,200 gpu and oxygen/nitrogen selectivity of 3.0, and the permeance and selectivity were stable over the time period tested (60 days). We successfully scaled up the production of high-flux PFP-based membranes, using MTR's commercial coaters. Two bench-scale spiral-wound modules with countercurrent designs were made and parametric tests were performed to understand the effect of feed flow rate and pressure, permeate pressure and sweep flow rate on the membrane module separation properties. At various operating conditions that modeled potential industrial operating conditions, the module separation properties were similar to the pure-gas separation properties in the membrane stamps. We also identified and synthesized new polymers [including polymers of intrinsic microporosity (PIMs) and polyimides] with higher oxygen/nitrogen selectivity (3.5-5.0) than the PFPs, and made these polymers into thin film composite membranes. However, these membranes were susceptible to severe aging; pure-gas permeance decreased nearly six-fold within two weeks, making them impractical for industrial applications of oxygen enrichment. We tested the effect of oxygen-enriched air on NO{sub x} emissions using a Bloom baffle burner at GTI. The results are positive and confirm that oxygen-enriched combustion can be carried out without producing higher levels of NOx than normal air firing, if lancing of combustion air is used and the excess air levels are controlled. A simple economic study shows that the membrane processes can produce O{sub 2} at less than $40/ton EPO{sub 2} and an energy cost of 1.1-1.5 MMBtu/ton EPO{sub 2}, which are very favorable compared with conventional technologies such as cryogenics and vacuum pressure swing adsorption processes. The benefits of integrated membrane processes/combustion process trains have been evaluated, and show good savings in process costs and energy consumption, as well as reduced CO{sub 2} emissions. For example, if air containing 30% oxygen is used in natural gas furnaces, the net natural gas savings are an estimated 18% at a burner temperature of 2,500 F, and 32% at a burner temperature of 3,000 F. With a 20% market penetration of membrane-based oxygen-enriched combustion in all combustion processes by 2020, the energy savings would be 414-736 TBtu/y in the U.S. The comparable net cost savings are estimated at $1.2-2.1 billion per year by 2020, calculated as the value of fuel savings subtracted from the cost of oxygen production. The fuel savings of 18%-32% by the membrane/oxygen-enriched combustion corresponds to an 18%-32% reduction in CO{sub 2} emissions, or 23-40 MM ton/y less CO{sub 2} from natural gas-fired furnaces by 2020. In summary, results from this project (Concept Definition phase) are highly promising and clearly demonstrate that membrane processes can produce oxygen-enriched air in a low cost manner that will lower operating costs and energy consumption in industrial combustion processes. Future work will focus on proof-of-concept bench-scale demonstration in the laboratory.

  3. Oxygen-producing inert anodes for SOM process

    SciTech Connect (OSTI)

    Pal, Uday B

    2014-02-25

    An electrolysis system for generating a metal and molecular oxygen includes a container for receiving a metal oxide containing a metallic species to be extracted, a cathode positioned to contact a metal oxide housed within the container; an oxygen-ion-conducting membrane positioned to contact a metal oxide housed within the container; an anode in contact with the oxygen-ion-conducting membrane and spaced apart from a metal oxide housed within the container, said anode selected from the group consisting of liquid metal silver, oxygen stable electronic oxides, oxygen stable crucible cermets, and stabilized zirconia composites with oxygen stable electronic oxides.

  4. Design, measurement, and analysis of oxygenated fluid pump system

    E-Print Network [OSTI]

    Mason, Alexander M., IV (Alexander Martin)

    2012-01-01

    The author sought out the opportunity to design and implement a system for pumping oxygenated fluid and mixing it with saline, for the purpose of providing sufficient levels of oxygen for patients undergoing forms of ...

  5. Oxygen levels in thermoplastic microfluidic devices during cell culture

    E-Print Network [OSTI]

    Ochs, Christopher J.

    We developed a computational model to predict oxygen levels in microfluidic plastic devices during cell culture. This model is based on experimental evaluation of oxygen levels. Conditions are determined that provide ...

  6. On the reduction of oxygen from dispersed media

    E-Print Network [OSTI]

    Roushdy, Omar H., 1977-

    2007-01-01

    The reduction of oxygen from an organic phase dispersed in a concentrated electrolyte is investigated. Dispersed organic phases are used to enhance oxygen transport in fermenters and artificial blood substitutes. This work ...

  7. Phase-based regional oxygen metabolism (PROM) using MRI

    E-Print Network [OSTI]

    Fan, Audrey Peiwen

    Venous oxygen saturation (Yv) in cerebral veins and the cerebral metabolic rate of oxygen (CMRO2) are important indicators for brain function and disease. Although MRI has been used for global measurements of these parameters, ...

  8. Electrical insulator assembly with oxygen permeation barrier

    DOE Patents [OSTI]

    Van Der Beck, Roland R. (Lansdale, PA); Bond, James A. (Exton, PA)

    1994-01-01

    A high-voltage electrical insulator (21) for electrically insulating a thermoelectric module (17) in a spacecraft from a niobium-1% zirconium alloy wall (11) of a heat exchanger (13) filled with liquid lithium (16) while providing good thermal conductivity between the heat exchanger and the thermoelectric module. The insulator (21) has a single crystal alumina layer (SxAl.sub.2 O.sub.3, sapphire) with a niobium foil layer (32) bonded thereto on the surface of the alumina crystal (26) facing the heat exchanger wall (11), and a molybdenum layer (31) bonded to the niobium layer (32) to act as an oxygen permeation barrier to preclude the oxygen depleting effects of the lithium from causing undesirable niobium-aluminum intermetallic layers near the alumina-niobium interface.

  9. Electrical insulator assembly with oxygen permeation barrier

    DOE Patents [OSTI]

    Van Der Beck, R.R.; Bond, J.A.

    1994-03-29

    A high-voltage electrical insulator for electrically insulating a thermoelectric module in a spacecraft from a niobium-1% zirconium alloy wall of a heat exchanger filled with liquid lithium while providing good thermal conductivity between the heat exchanger and the thermoelectric module. The insulator has a single crystal alumina layer (SxAl[sub 2]O[sub 3], sapphire) with a niobium foil layer bonded thereto on the surface of the alumina crystal facing the heat exchanger wall, and a molybdenum layer bonded to the niobium layer to act as an oxygen permeation barrier to preclude the oxygen depleting effects of the lithium from causing undesirable niobium-aluminum intermetallic layers near the alumina-niobium interface. 3 figures.

  10. GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS: PHASE II--PILOT SCALE TESTING AND UPDATED PERFORMANCE AND ECONOMICS FOR OXYGEN FIRED CFB WITH CO2 CAPTURE

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl; David G. Turek

    2004-10-27

    Because fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this Phase II study, ALSTOM Power Inc. (ALSTOM) has investigated one promising near-term coal fired power plant configuration designed to capture CO{sub 2} from effluent gas streams for sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}, along with some moisture, nitrogen, oxygen, and trace gases like SO{sub 2} and NO{sub x}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB plants results in significant Boiler Island cost savings resulting from reduced component The overall objective of the Phase II workscope, which is the subject of this report, is to generate a refined technical and economic evaluation of the Oxygen fired CFB case (Case-2 from Phase I) utilizing the information learned from pilot-scale testing of this concept. The objective of the pilot-scale testing was to generate detailed technical data needed to establish advanced CFB design requirements and performance when firing coals and delayed petroleum coke in O{sub 2}/CO{sub 2} mixtures. Firing rates in the pilot test facility ranged from 2.2 to 7.9 MM-Btu/hr. Pilot-scale testing was performed at ALSTOM's Multi-use Test Facility (MTF), located in Windsor, Connecticut.

  11. VARIATIONS IN THE DISSOLVED OXYGEN CONTENT OF INTRAGRAVEL WATER IN

    E-Print Network [OSTI]

    ^402: VARIATIONS IN THE DISSOLVED OXYGEN CONTENT OF INTRAGRAVEL WATER IN FOUR SPAWNING STREAMS IN THE DISSOLVED OXYGEN CONTENT OF INTRAGRAVEL WATER IN FOUR SPAWNING STREAMS OF SOUTHEASTERN ALASKA by William J Introduction 1 Sampling intragravel water for dissolved oxygen content 2 Obtaining water samples from

  12. The oxygen abundance distribution in M101

    E-Print Network [OSTI]

    L. S. Pilyugin

    2001-05-07

    The well-observed spiral galaxy M101 was considered. The radial distributions of oxygen abundances determined in three different ways (with the classic Te - method, with the R23 - method, and with the P -- method) were compared. It was found that the parameters (the central oxygen abundance and the gradient) of the radial O/H(P) abundance distribution are close to those of the O/H(Te) abundance distribution. The parameters of the O/H(R23) abundance distribution differ significantly from those of the O/H(Te) abundance distribution: the central O/H(R23) oxygen abundance is higher by around 0.4dex and the gradient is steeper by a factor of around 1.5 as compared to those values in the O/H(Te) abundance distribution. The dispersion in O/H(P) abundance at fixed radius is rather small, around 0.08 dex, and is equal to that in O/H(Te) abundance. The dispersion in O/H(R23) abundance at fixed radius is appreciably larger, around 0.16 dex, compared to that in O/H(Te) abundance. It has been shown that the extra dispersion in O/H(R23) abundances is an artifact and reflects scatter in excitation parameter P at fixed radius.

  13. DME-to-oxygenates process studies

    SciTech Connect (OSTI)

    Tartamella, T.L.; Sardesai, A.; Lee, S.; Kulik, C.J.

    1994-12-31

    The feasibility of the production of hydrocarbons from dimethyl ether (DNM) has been illustrated in a fixed bed micro-reactor as well as a bench scale fluidized bed reactor by the University of Akron/EPRI DME-to-Hydrocarbon (DTG) Process. The DTG process has distinct advantages over its methanol based counterpart. Specifically, the DTG process excels in the area of higher productivity, higher per-pass conversion, and lower heat duties than the MTG process. Also of special importance is the production of oxygenates -- including MTBE, ETBE, and TAME. DME may be reacted with isobutylene to produce a mixture of MTBE and ETBE. The properties of ETBE excel over MTBE in the areas of lower RVP and higher RON. According to industrial reports, MTBE is the fastest growing chemical (1992 US capacity 135,350 BPD, with expected growth of 34%/year to 1997). Also, recent renewed interest as an octane-enhancer and as a source of oxygen has spurred a growing interest in nonrefinery synthesis routes to ETBE. TAME, with its lower RVP and higher RON has proven useful as a gasoline blending agent and octane enhancer and may also be produced directly from DME. DME, therefore, serves as a valuable feedstock in the conversion of may oxygenates with wide-scale industrial importance. It should be also noted that the interest in the utilization of DME as process feedstock is based on the favorable process economics of EPRI/UA`s liquid phase DME process.

  14. Impact of different plants on the gas profile of a landfill cover

    SciTech Connect (OSTI)

    Reichenauer, Thomas G.; Watzinger, Andrea; Riesing, Johann; Gerzabek, Martin H.

    2011-05-15

    Research highlights: > Plants influence gas profile and methane oxidation in landfill covers. > Plants regulate water content and increase the availability of oxygen for methane oxidation. > Plant species with deep roots like alfalfa showed more stimulation of methane oxidation than plants with shallow root systems like grasses. - Abstract: Methane is an important greenhouse gas emitted from landfill sites and old waste dumps. Biological methane oxidation in landfill covers can help to reduce methane emissions. To determine the influence of different plant covers on this oxidation in a compost layer, we conducted a lysimeter study. We compared the effect of four different plant covers (grass, alfalfa + grass, miscanthus and black poplar) and of bare soil on the concentration of methane, carbon dioxide and oxygen in lysimeters filled with compost. Plants were essential for a sustainable reduction in methane concentrations, whereas in bare soil, methane oxidation declined already after 6 weeks. Enhanced microbial activity - expected in lysimeters with plants that were exposed to landfill gas - was supported by the increased temperature of the gas in the substrate and the higher methane oxidation potential. At the end of the first experimental year and from mid-April of the second experimental year, the methane concentration was most strongly reduced in the lysimeters containing alfalfa + grass, followed by poplar, miscanthus and grass. The observed differences probably reflect the different root morphology of the investigated plants, which influences oxygen transport to deeper compost layers and regulates the water content.

  15. Magnetic interaction in oxygenated alpha Fe-phthalocyanines

    SciTech Connect (OSTI)

    Kuzmann, Ern?, E-mail: kuzmann@caesar.elte.hu; Homonnay, Zoltán; Horváth, Attila [Institute of Chemistry, Eötvös Loránd University, P.O. Box 32, 1512 Budapest (Hungary); Pechousek, Jiri; Cuda, Jan; Machala, Libor; Zoppellaro, Giorgio; Zboril, Radek [Regional Centre of Advanced Technologies and Materials, Departments of Experimental Physics and Physical Chemistry, Faculty of Science Palacky University, 17. Listopadu 1192/12, 771 46 Olomouc (Czech Republic); Yin, Houping; Wei, Yen [Department of Chemistry, Drexel University, Philadelphia, PA 19104 (United States); Klencsár, Zoltán [Research Centre for Natural Sciences, Hungarian Academy of Sciences, Budapest, 1117 (Hungary); Kubuki, Shiro [Department of Chemistry, Graduate School of Science and Engineering, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachi-Oji, Tokyo 192-0397 (Japan); Nath, Amar [Department of Chemistry, University of North Carolina, Asheville, NC 28804 (United States)

    2014-10-27

    Alpha iron phthalocyanines (?-FePc) oxygenated at low temperatures were investigated with the help of {sup 57}Fe Mössbauer spectroscopy, magnetization measurements (SQUID) and X-ray diffractometry (XRD). Mössbauer spectroscopy revealed that upon oxygenation of ?-FePc, new species were formed which could be associated with Fe{sup III}Pc oxygen adducts. Unexpectedly, magnetically split spectrum of oxygenated ?-FePc was observed below 20 K. In-field Mössbauer spectra in a 5 T external magnetic field at 5K and magnetization measurements indicate antiferromagnetic coupling in oxygenated ?-FePc.

  16. Thermodynamic stability of oxygen point defects in cubic Zirconia

    E-Print Network [OSTI]

    Samanta, Amit; Li, Ju

    2010-01-01

    Zirconia (ZrO2) is an important material with technological applications which are affected by point defect physics. Ab-initio calculations are performed to understand the structural and electronic properties of oxygen vacancies and interstitials in different charge states in cubic zirconia. We find oxygen interstitials in cubic ZrO2 can have five different configurations - dumbbell, dumbbell, crowd-ion, octahedral, and distorted dumbbell. For a neutral and singly charged oxygen interstitial, the lowest energy configuration is the dumbbell, while for a doubly charged oxygen interstitial the octahedral site is energetically the most favorable. Both the oxygen interstitial and the oxygen vacancy are negative-U, so that the singly charged defects are unstable at any Fermi level. The thermodynamic stability of these defects are studied in terms of Fermi level, oxygen partial pressure and temperature. A method to determine the chemical potential of the system as a function of temperature and pressure is propo...

  17. Waste Treatment Plant Overview

    Office of Environmental Management (EM)

    contracted Bechtel National, Inc., to design and build the world's largest radioactive waste treatment plant. The Waste Treatment and Immobilization Plant (WTP), also known as the...

  18. Investigation of the electrocatalytic oxygen reduction and evolution reactions in lithium–oxygen batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Dong; Zhang, Xuran; Qu, Deyu; Yang, Xiao -Qing; Lee, Hung -Sui; Qu, Deyang

    2015-04-21

    Oxygen reduction and oxygen evolution reactions were examined on graphite electrodes with different crystal orientations. The kinetics for the redox couple O2/O2•- are very fast, therefore no catalyst seems necessary to assist the charge transfer process. Apparently, the main source of the overpotential for the O2 reduction reaction is from mass diffusion. Li2O2 becomes soluble in non-aqueous electrolytes in the presence of the tetraethylammonium tetrafluoroborate additive. The soluble B-O22- ions can be oxidized electro-catalytically. The edge orientation of graphite demonstrates superior catalytic activity for the oxidation over basal orientation. The findings reveal an opportunity for recharging Li-air batteries efficiently andmore »a new strategy of developing the catalyst for oxygen evolution reaction.« less

  19. Investigation of the electrocatalytic oxygen reduction and evolution reactions in lithium–oxygen batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Dong [Univ. of Wisconsin, Milwaukee, WI (United States). Collece of Engineering and Applied Science; Zhang, Xuran [Wuhan Univ. of Technology, Wuhan (China). School of Science; Qu, Deyu [Wuhan Univ. of Technology, Wuhan (China). School of Science; Yang, Xiao-Qing [Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.; Lee, Hung-Sui [Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.; Qu, Deyang [Univ. of Wisconsin, Milwaukee, WI (United States). Collece of Engineering and Applied Science

    2015-08-01

    Oxygen reduction and oxygen evolution reactions were studied on graphite electrodes with different crystal orientations. The kinetics for the redox couple O2/O2•- are very fast, therefore no catalyst seems necessary to assist the charge transfer process. Apparently, the main source of the overpotential for the O2 reduction reaction is from mass diffusion. Li2O2 becomes soluble in non-aqueous electrolytes in the presence of the tetraethylammonium tetrafluoroborate additive. The soluble B-O22- ions can be oxidized electro-catalytically. The edge orientation of graphite demonstrates superior catalytic activity for the oxidation over basal orientation. The findings reveal an opportunity for recharging Li-air batteries efficiently and a new strategy of developing the catalyst for oxygen evolution reaction.

  20. The Mechanisms of Oxygen Reduction and Evolution Reactions in Nonaqueous Lithium-Oxygen Batteries

    SciTech Connect (OSTI)

    Cao, Ruiguo; Walter, Eric D.; Xu, Wu; Nasybulin, Eduard N.; Bhattacharya, Priyanka; Bowden, Mark E.; Engelhard, Mark H.; Zhang, Jiguang

    2014-09-01

    The oxygen reduction/evolution reaction (ORR/OER) mechanisms in nonaqueous Li-O2 batteries have been investigated by using electron paramagnetic resonance spectroscopy in this work. We identified the superoxide radical anion (O2•-) as an intermediate in the ORR process using 5,5-dimethyl-pyrroline N-oxide as a spin trap, while no O2•- in OER was detected during the charge process. These findings provide insightful understanding on the fundamental oxygen reaction mechanisms in rechargeable nonaqueous Li-O2 batteries.

  1. Oxygen stabilized zirconium-vanadium-iron alloy

    DOE Patents [OSTI]

    Mendelsohn, Marshall H. (Woodridge, IL); Gruen, Dieter M. (Downers Grove, IL)

    1982-01-01

    An oxygen stabilized intermetallic compound having the formula (Zr.sub.1-x Ti.sub.x).sub.2-u (V.sub.1-y Fe.sub.y)O.sub.z where x=0.0 to 0.9, y=0.01 to 0.9, z=0.25 to 0.5 and u=0 to 1. The compound is capable of reversibly sorbing hydrogen at temperatures from -196.degree. C. to 200.degree. C. at pressures down to 10.sup.-6 torr. The compound is suitable for use as a hydrogen getter in low pressure, high temperature applications such as magnetic confinement fusion devices.

  2. Jupiter Oxygen Corporation | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas: Energy ResourcesOrder atHills,New York: EnergyUnlimitedEnergyJuniata,JupiterOxygen

  3. Polyhydroxyalkanoate synthesis in plants

    DOE Patents [OSTI]

    Srienc, Friedrich (Lake Elmo, MN); Somers, David A. (Roseville, MN); Hahn, J. J. (New Brighton, MN); Eschenlauer, Arthur C. (Circle Pines, MN)

    2000-01-01

    Novel transgenic plants and plant cells are capable of biosynthesis of polyhydroxyalkanoate (PHA). Heterologous enzymes involved in PHA biosynthesis, particularly PHA polymerase, are targeted to the peroxisome of a transgenic plant. Transgenic plant materials that biosynthesize short chain length monomer PHAs in the absence of heterologous .beta.-ketothiolase and acetoacetyl-CoA reductase are also disclosed.

  4. Ethylene insensitive plants

    DOE Patents [OSTI]

    Ecker, Joseph R. (Carlsbad, CA); Nehring, Ramlah (La Jolla, CA); McGrath, Robert B. (Philadelphia, PA)

    2007-05-22

    Nucleic acid and polypeptide sequences are described which relate to an EIN6 gene, a gene involved in the plant ethylene response. Plant transformation vectors and transgenic plants are described which display an altered ethylene-dependent phenotype due to altered expression of EIN6 in transformed plants.

  5. Electrochemical oxygen pumps. Final CRADA report.

    SciTech Connect (OSTI)

    Carter, J. D. Noble, J.

    2009-10-01

    All tasks of the Work Plan of ISTC Project 2277p have been completed, thus: (1) techniques of chemical synthesis were developed for more than ten recipes of electrolyte based on cerium oxide doped with 20 mole% of gadolinium (CeGd)O{sub 2}, doped by more than 10 oxide systems including 6 recipes in addition to the Work Plan; (2) electric conductivity and mechanical strength of CeGd specimens with additions of oxide systems were performed, two candidate materials for the electrolyte of electrochemical oxygen pump (pure CeGd and CeGd doped by 0.2 wt% of a transition metal) were chosen; (3) extended studies of mechanical strength of candidate material specimens were performed at room temperature and at 400, 600, 800 C; (4) fixtures for determination of mechanical strength of tubes by external pressure above 40 atmospheres at temperature up to 700 C were developed and fabricated; and (5) technology of slip casting of tubes from pure (Ce,Gd)O{sub 2} and of (Ce,Gd)O{sub 2} doped by 0.2 wt% of a transition metal, withstanding external pressure of minimum 40 atmospheres at temperature up to 700 C was developed, a batch of tubes was sent for testing to Argonne National Laboratory; (6) technology of making nanopowder from pure (Ce,Gd)O{sub 2} was developed based on chemical synthesis and laser ablation techniques, a batch of nanopowder with the weight 1 kg was sent for testing to Argonne National Laboratory; (7) a business plan for establishing a company for making powders of materials for electrochemical oxygen pump was developed; and (8) major results obtained within the Project were reported at international conferences and published in the Russian journal Electrochemistry. In accordance with the Work Plan a business trip of the following project participants was scheduled for April 22-29, 2006, to Tonawanda, NY, USA: Manager Victor Borisov; Leader of technology development Gennady Studenikin; Leader of business planning Elena Zadorozhnaya; Leader of production Vasily Lepalovsky; and Translator Vladimir Litvinov. During this trip project participants were to discuss with the project Technical Monitor J.D. Carter and representative of Praxair Inc. J. Chen the results of project activities (prospects of transition metal-doped material application in oxygen pumps), as well as the prospects of cooperation with Praxair at the meeting with the company management in the following fields: (1) Deposition of thin films of oxide materials of complex composition on support by magnetron and ion sputtering, research of coatings properties; (2) Development of block-type structure technology (made of porous and dense ceramics) for oxygen pump. The block-type structure is promising because when the size of electrolyte block is 2 x 2 inches and assembly height is 10 inches (5 blocks connected together) the area of active surface is ca. 290 square inches (in case of 8 slots), that roughly corresponds to one tube with diameter 1 inch and height 100 inches. So performance of the system made of such blocks may be by a factor of two or three higher than that of tube-based system. However one month before the visit, J. Chen notified us of internal changes at Praxair and the cancellation of the visit to Tonawanda, NY. During consultations with the project Technical Monitor J.D. Carter and Senior Project Manager A. Taylor a decision was made to extend the project term by 2 quarters to prepare proposals for follow-on activities during this extension (development of block-type structures made of dense and porous oxide ceramics for electrochemical oxygen pumps) using the funds that were not used for the trip to the US.

  6. Dilute Oxygen Combustion Phase I Final Report

    SciTech Connect (OSTI)

    Ryan, H.M.; Riley, M.F.; Kobayashi, H.

    1997-10-31

    A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NOx emissions below 5-10-3 g/MJ (10 ppm-air equivalent at 3% O2 dry) were obtained for furnace temperatures below 1533 K (2300°F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in-furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, wit6h increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of lower utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, required additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

  7. Dilute oxygen combustion. Phase I report

    SciTech Connect (OSTI)

    NONE

    1997-10-01

    A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NO{sub x}) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NO{sub x} through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NO{sub x} production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature ({approximately}1366 K) oxidant (7-27% O{sub 2} vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d{sup +} scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d{sup +} scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW ({approximately}0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NO{sub x} emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NO{sub x} emissions below 5{times}10{sup -3} g/MJ (10 ppm-air equivalent at 3% O{sub 2} dry) were obtained for furnace temperatures below 1533 K (2300{degree}F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in- furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, with increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, requires additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

  8. Poisonous Plant Management. 

    E-Print Network [OSTI]

    McGinty, Allan

    1985-01-01

    range specialist, The Texas A&M University System . 2 DIAGNOSING POISONOOS PLANT PROBLEMS Accurate diagnosis of poisonous plant problems can be extremely difficult. Many cases of livestock poisoning by plants have been improperly diagnosed... Agricultural Extension Service ~-P~,IJ& H~iN!/ P~,IJ&--------------- poisonous Plant ___ Management_ ..... Texas Agricultural Extension Service. The Texas A&M University System. College Station, Texas POISONO(]S PLANT MANAGEMENT Allan McGinty* Poisonous...

  9. Plant fatty acid hydroxylases

    DOE Patents [OSTI]

    Somerville, Chris (Portola Valley, CA); Broun, Pierre (Burlingame, CA); van de Loo, Frank (Lexington, KY)

    2001-01-01

    This invention relates to plant fatty acyl hydroxylases. Methods to use conserved amino acid or nucleotide sequences to obtain plant fatty acyl hydroxylases are described. Also described is the use of cDNA clones encoding a plant hydroxylase to produce a family of hydroxylated fatty acids in transgenic plants. In addition, the use of genes encoding fatty acid hydroxylases or desaturases to alter the level of lipid fatty acid unsaturation in transgenic plants is described.

  10. Preliminary Study of Oxygen-Enhanced Longitudinal Relaxation in MRI: A Potential Novel Biomarker of Oxygenation Changes in Solid Tumors

    SciTech Connect (OSTI)

    O'Connor, James P.B.; Naish, Josephine H.; Parker, Geoff J.M.; Waterton, John C.; Watson, Yvonne; Jayson, Gordon C.; Buonaccorsi, Giovanni A.; Cheung, Sue; Buckley, David L.; McGrath, Deirdre M.; West, Catharine M.L.; Davidson, Susan E.; Roberts, Caleb; Mills, Samantha J.; Mitchell, Claire L.; Hope, Lynn; Ton, N. Chan; Jackson, Alan

    2009-11-15

    Purpose: There is considerable interest in developing non-invasive methods of mapping tumor hypoxia. Changes in tissue oxygen concentration produce proportional changes in the magnetic resonance imaging (MRI) longitudinal relaxation rate (R{sub 1}). This technique has been used previously to evaluate oxygen delivery to healthy tissues and is distinct from blood oxygenation level-dependent (BOLD) imaging. Here we report application of this method to detect alteration in tumor oxygenation status. Methods and materials: Ten patients with advanced cancer of the abdomen and pelvis underwent serial measurement of tumor R{sub 1} while breathing medical air (21% oxygen) followed by 100% oxygen (oxygen-enhanced MRI). Gadolinium-based dynamic contrast-enhanced MRI was then performed to compare the spatial distribution of perfusion with that of oxygen-induced DELTAR{sub 1}. Results: DELTAR{sub 1} showed significant increases of 0.021 to 0.058 s{sup -1} in eight patients with either locally recurrent tumor from cervical and hepatocellular carcinomas or metastases from ovarian and colorectal carcinomas. In general, there was congruency between perfusion and oxygen concentration. However, regional mismatch was observed in some tumor cores. Here, moderate gadolinium uptake (consistent with moderate perfusion) was associated with low area under the DELTAR{sub 1} curve (consistent with minimal increase in oxygen concentration). Conclusions: These results provide evidence that oxygen-enhanced longitudinal relaxation can monitor changes in tumor oxygen concentration. The technique shows promise in identifying hypoxic regions within tumors and may enable spatial mapping of change in tumor oxygen concentration.

  11. Effects of Time, Heat, and Oxygen on K Basin Sludge Agglomeration, Strength, and Solids Volume

    SciTech Connect (OSTI)

    Delegard, Calvin H.; Sinkov, Sergey I.; Schmidt, Andrew J.; Daniel, Richard C.; Burns, Carolyn A.

    2011-01-04

    Sludge disposition will be managed in two phases under the K Basin Sludge Treatment Project. The first phase is to retrieve the sludge that currently resides in engineered containers in the K West (KW) Basin pool at ~10 to 18°C. The second phase is to retrieve the sludge from interim storage in the sludge transport and storage containers (STSCs) and treat and package it in preparation for eventual shipment to the Waste Isolation Pilot Plant. The work described in this report was conducted to gain insight into how sludge may change during long-term containerized storage in the STSCs. To accelerate potential physical and chemical changes, the tests were performed at temperatures and oxygen partial pressures significantly greater than those expected in the T Plant canyon cells where the STSCs will be stored. Tests were conducted to determine the effects of 50°C oxygenated water exposure on settled quiescent uraninite (UO2) slurry and a full simulant of KW containerized sludge to determine the effects of oxygen and heat on the composition and mechanical properties of sludge. Shear-strength measurements by vane rheometry also were conducted for UO2 slurry, mixtures of UO2 and metaschoepite (UO3•2H2O), and for simulated KW containerized sludge. The results from these tests and related previous tests are compared to determine whether the settled solids in the K Basin sludge materials change in volume because of oxidation of UO2 by dissolved atmospheric oxygen to form metaschoepite. The test results also are compared to determine if heating or other factors alter sludge volumes and to determine the effects of sludge composition and settling times on sludge shear strength. It has been estimated that the sludge volume will increase with time because of a uranium metal ? uraninite ? metaschoepite oxidation sequence. This increase could increase the number of containers required for storage and increase overall costs of sludge management activities. However, the volume might decrease because of decreases in the water-volume fraction caused by sludge solid reactions, compaction, or intergrowth and recrystallization of metaschoepite. In that case, fewer STSCs may be needed, but the shear strength would increase, and this could challenge recovery by water jet erosion and require more aggressive retrieval methods. Overall, the tests described herein indicate that the settled solids volume remains the same or decreases with time. The only case for which the sludge solids volumes increase with time is for the expansion factor attendant upon the anoxic corrosion of uranium metal to produce UO2 and subsequent reaction with oxygen to form equimolar UO2.25 and UO3•2H2O.

  12. Heat release analysis of oxygen-enriched diesel combustion

    SciTech Connect (OSTI)

    Assanis, D.; Karvounis, E. (Univ. of Illinois, Urbana, IL (United States)); Sekar, R.; Marr, W. (Argonne National Lab., IL (United States))

    1993-10-01

    A heat release correlation for oxygen-enriched diesel combustion is being developed through heat release analysis of cylinder pressure data from a single-cylinder diesel engine operating under various levels of oxygen enrichment. Results show that standard combustion correlations available in the literature do not accurately describe oxygen-enriched diesel combustion. A novel functional form is therefore proposed, which is shown to reproduce measured heat release profiles closely, under different operating conditions and levels of oxygen enrichment. The mathematical complexity of the associated curve-fitting problem is maintained at the same level of difficulty as for standard correlations. When the novel correlation is incorporated into a computer simulation of diesel engine operation with oxygen enrichment, the latter predicts pressure traces in excellent agreement with measured pressure data. This demonstrates the potential of the proposed combustion simulation to guide the application of oxygen-enriched technology successfully to a variety of multicylinder diesel systems.

  13. A fiber optic probe for oxygen partial pressure sensing 

    E-Print Network [OSTI]

    Schlain, Leslie Ariel

    1986-01-01

    of the electronic circuitry, and Steve Spar for software development. TABLE OF CONTENTS INTRODUCTION Purpose Current Status of Conventional Oxygen Sensors Optical Sensors Technical Obj ect ives 1 5 10 MATERIAL AND METHODS 14 Transducer Design... the partial pressure of oxygen (p02) in solutions. The research effort was specifically aimed at the development of an oxygen sensor suitable for physiological applications. The sensor described in this thesis is an application of a generic fiber optic...

  14. Strongly enhanced oxygen ion transport through samarium-doped...

    Office of Scientific and Technical Information (OSTI)

    Strongly enhanced oxygen ion transport through samarium-doped CeO2 nanopillars in nanocomposite films Citation Details In-Document Search This content will become publicly...

  15. Vehicle Technologies Office Merit Review 2014: Intake Air Oxygen...

    Energy Savers [EERE]

    Review 2015: Intake Air Oxygen Sensor Vehicle Technologies Office Merit Review 2014: Advanced Combustion Concepts - Enabling Systems and Solutions (ACCESS) for High Efficiency...

  16. Vehicle Technologies Office Merit Review 2015: Intake Air Oxygen...

    Energy Savers [EERE]

    Office Merit Review 2014: Intake Air Oxygen Sensor Bosch Powertrain Technologies Advanced Combustion Concepts - Enabling Systems and Solutions (ACCESS) for High Efficiency...

  17. Geothermal Reservoir Temperatures Estimated from the Oxygen Isotope...

    Open Energy Info (EERE)

    Geothermal Reservoir Temperatures Estimated from the Oxygen Isotope Compositions of Dissolved Sulfate and Water from Hot Springs and Shallow Drillholes Jump to: navigation, search...

  18. Geothermal reservoir temperatures estimated from the oxygen isotope...

    Open Energy Info (EERE)

    Geothermal reservoir temperatures estimated from the oxygen isotope compositions of dissolved sulfate and water from hot springs and shallow drillholes Jump to: navigation, search...

  19. Catalytic reduction system for oxygen-rich exhaust

    DOE Patents [OSTI]

    Vogtlin, G.E.; Merritt, B.T.; Hsiao, M.C.; Wallman, P.H.; Penetrante, B.M.

    1999-04-13

    Non-thermal plasma gas treatment is combined with selective catalytic reduction to enhance NO{sub x} reduction in oxygen-rich vehicle engine exhausts. 8 figs.

  20. Ultrafast kinetics subsequent to shock in an unreacted, oxygen...

    Office of Scientific and Technical Information (OSTI)

    subsequent to shock in an unreacted, oxygen balanced mixture of nitromethane and hydrogen peroxide Citation Details In-Document Search Title: Ultrafast kinetics subsequent to...

  1. SUPPORTED DENSE CERAMIC MEMBRANES FOR OXYGEN SEPARATION

    SciTech Connect (OSTI)

    Timothy L. Ward

    2002-07-01

    Mixed-conducting ceramics have the ability to conduct oxygen with perfect selectivity at elevated temperatures, making them extremely attractive as membrane materials for oxygen separation and membrane reactor applications. While the conductivity of these materials can be quite high at elevated temperatures (typically 800-1000 C), much higher oxygen fluxes, or, alternatively, equivalent fluxes at lower temperatures, could be provided by supported thin or thick film membrane layers. Based on that motivation, the objective of this project was to explore the use of ultrafine aerosol-derived powder of a mixed-conducting ceramic material for fabrication of supported thick-film dense membranes. The project focused on the mixed-conducting ceramic composition SrCo{sub 0.5}FeO{sub x} (SCFO) because of the desirable permeability and stability of that material, as reported in the literature. Appropriate conditions to produce the submicron SrCo{sub 0.5}FeO{sub x} powder using aerosol pyrolysis were determined. Porous supports of the same composition were produced by partial sintering of a commercially obtained powder that possessed significantly larger particle size than the aerosol-derived powder. The effects of sintering conditions (temperature, atmosphere) on the porosity and microstructure of the porous discs were studied, and a standard support fabrication procedure was adopted. Subsequently, a variety of paste and slurry formulations were explored utilizing the aerosol-derived SCFO powder. These formulations were applied to the porous SCFO support by a doctor blade or spin coating procedure. Sintering of the supported membrane layer was then conducted, and additional layers were deposited and sintered in some cases. The primary characterization methods were X-ray diffraction and scanning electron microscopy, and room-temperature nitrogen permeation was used to assess defect status of the membranes.We found that non-aqueous paste/slurry formulations incorporating dispersant, plasticizer and binder provided superior cracking resistance compared to simple water, alcohol, or polyethylene glycol (PEG) based formulations. With a formulation employing castor oil as dispersant, isopropyl alcohol/mineral spirits as solvent, polyvinyl butyral as binder, and dibutyl phthalate/PEG as plasticizer, sintered SCFO membrane layers approximately 5 {micro}m thick with no apparent cracks were prepared using spin coating with several coats and sintering cycles. A similar but more viscous formulation applied by doctor blade gave a {approx} 10 {micro}m thick membrane layer in one coat, but with some apparent cracking. We demonstrated that the membrane layer could be densified while retaining porosity in the chemically identical support. This was accomplished by pre-sintering the support in air (1050 C), which coarsened the grain size and provided a relatively stable plate-shaped granular microstructure, followed by membrane layer fabrication with the highly-sinterable aerosol powder. Final densification was conducted by sintering in nitrogen ({approx}1100 C), which provided accelerated sintering rates and led to the desired layered perovskite phase content. In spite of these successes, low-temperature pressure-driven permeation testing with N2 showed that even the best membranes were not sufficiently defect free for high-temperature oxygen permeation testing. The source of these defects were not readily apparent from scanning electron microscopy, though incomplete or nonuniform membrane layer coverage from edge to edge of the support was probably one important factor.

  2. ASME PTC 47 -- Calculation of overall IGCC plant performance

    SciTech Connect (OSTI)

    Xiong, T.; Horazak, D.A.

    1999-07-01

    An integrated gasification combined cycle (IGCC) plant is a combined chemical and power system that converts coal or other unrefined fuel into clean gaseous fuel, electric power, and other byproducts. The conversion process requires interactions among the gasification, gas cleaning, air or oxygen production, power and steam generation systems. Overall performance testing of IGCC plants. however, is based only on the streams that cross the overall plant boundary. This paper describes the calculation procedures required to conduct a fair and accurate performance test of an IGCC plant, as proposed for ASME Performance Test Code 47. Discussions include identification of parameters to be measured, calculations needed to evaluate performance, and corrections to performance data for test conditions that differ from reference conditions.

  3. In vivo effect of inosine, pyruvate, and phosphate on the oxygen hemoglobin equilibrium curve and tissue oxygenation 

    E-Print Network [OSTI]

    Ross, Joe Nevill

    1974-01-01

    and Mixed Venous Blood Samples 2, 3-Diphosphoglycerate Determination M asurement of Mean Capillary Oxygen Tersion ( P-0 ) c 2 Measurement of P O Results 10 13 13 16 Discussion 25 Conclusion References Appendix I . Appendix II Appendix III... equilibrium curve pkI The r, egative log o. the hydrogen ion concentratior PO PCO P 02 a 2 P-0 a v 2 Partial pressure oi' oxygen Partial pressure of carbon dioxide Partial pressure of oxygen ir' arteria. l blood The oxygen partial pressure...

  4. On the oxygen abundance determination in HII regions: the problem of the line intensities -- oxygen abundance calibration

    E-Print Network [OSTI]

    L. S. Pilyugin

    2000-04-04

    The problem of the line intensities -- oxygen abundance calibration has been considered. We confirm the idea of McGaugh (1991) that the strong oxygen lines ([OII] 3727, 3729 and [OIII] 4959, 5007) contain the necessary information for determination of accurate abundances in low-metallicity (and may be also in high-metallicity) HII regions. It has been found that the excitation parameters p3 or p2 (which are defined here as contributions of the radiation in [OIII] 4959, 5007 lines and in [OII] 3727, 3729 lines to the "total" oxygen radiation respectively) allow to take into account the variations in R23 values among HII regions with a given oxygen abundance. Based on this fact a new way of the oxygen abundance determination in HII regions has been constructed and corresponding relations between line intensities and the oxygen abundance have been derived empirically using the available oxygen abundances determined via measurement of temperature-sensitive line ratios. In parallel a new R23 calibration has been derived on the base of recent data and compared to previous calibrations. For oxygen-rich HII regions the present R23 calibration is close to that of Edmunds and Pagel (1984): their calibration has the same slope but is shifted towards higher oxygen abundances by around 0.07 dex as compared to the present calibration.

  5. Oxygen diffusion of anodic surface oxide film on titanium studied by Auger electron spectroscopy. [Oxygen diffusivity

    SciTech Connect (OSTI)

    Wang, P.S.; Wittberg, T.N.; Keil, R.G.

    1982-01-01

    TiO/sub 2/ films of about 1000 A were grown onto titanium foils anodically under galvanostatic conditions at 20 mA/cm/sup 2/ in saturated aqueous solutions of ammonium tetraborate. The samples were then aged at 450, 500, and 550/sup 0/C, and oxygen diffusion was observed by Auger electron spectroscopy (AES) profilings. The oxygen diffusivities were calculated by Fick's Second Law, using the Boltzmann-Matano solution, to be 9.4 x 10/sup -17/, 2.6 x 10/sup -16/, and 1.2 x 10/sup -15/ cm/sup 2//sec at 450, 500, and 550/sup 0/C, respectively. The diffusivities obtained by this method were also compared with those obtained using an exact solution to Fick's Second Law. The activation energy was calculated to be 30 kcal/mole.

  6. Department of Plant Sciences and Plant Pathology

    E-Print Network [OSTI]

    Maxwell, Bruce D.

    Crop Science Option The challenge for crop scientists is to implement crop and soil management systems, weed science, and entomology. Graduates find careers in farming and ranching; as crop productionDepartment of Plant Sciences and Plant Pathology Unique, hands-on study programs for students

  7. Plant Phenotype Characterization System

    SciTech Connect (OSTI)

    Daniel W McDonald; Ronald B Michaels

    2005-09-09

    This report is the final scientific report for the DOE Inventions and Innovations Project: Plant Phenotype Characterization System, DE-FG36-04GO14334. The period of performance was September 30, 2004 through July 15, 2005. The project objective is to demonstrate the viability of a new scientific instrument concept for the study of plant root systems. The root systems of plants are thought to be important in plant yield and thus important to DOE goals in renewable energy sources. The scientific study and understanding of plant root systems is hampered by the difficulty in observing root activity and the inadequacy of existing root study instrumentation options. We have demonstrated a high throughput, non-invasive, high resolution technique for visualizing plant root systems in-situ. Our approach is based upon low-energy x-ray radiography and the use of containers and substrates (artificial soil) which are virtually transparent to x-rays. The system allows us to germinate and grow plant specimens in our containers and substrates and to generate x-ray images of the developing root system over time. The same plant can be imaged at different times in its development. The system can be used for root studies in plant physiology, plant morphology, plant breeding, plant functional genomics and plant genotype screening.

  8. Eighteenth-century merchant ship interiors 

    E-Print Network [OSTI]

    Renner, Mary Anne

    1987-01-01

    ), the Reeg~t~ (1771), the /~~vs (1768), the g~~ (1768), the lla~ax (1768) and the ~ount (1787). The deck layouts for the FIGURE 1. Cross section of an 18th-century merchantman. l , )&kl@V:= , igpgj; 'k -. kl-, E$ )fp IK j 'B' " l ~ 1't P... OF FIGURES 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 18 20 21 22 23 24 25 26 27 28 Cross section of an 18th-century merchantman Deck plans for HMS Dispatch National Register district and site locations Y085: Test trenches...

  9. Effects of oxygen and catalyst on tetraphenylborate decomposition rate

    SciTech Connect (OSTI)

    Walker, D.D.

    1999-12-15

    Previous studies indicate that palladium catalyzes rapid decomposition of alkaline tetraphenylborate slurries. Oxygen inhibits the reaction at low temperature (25 C), presumably by preventing activation of the catalyst. The present study investigated oxygen's inhibiting effectiveness at higher temperature (45 C) and catalyst concentrations.

  10. Singlet oxygen luminescence detection with a fibre-coupled superconducting

    E-Print Network [OSTI]

    Greenaway, Alan

    Singlet oxygen luminescence detection with a fibre-coupled superconducting nanowire single luminescence detection Fibre-based singlet oxygen luminescence detection References Superconducting Detector, is an intermediate in many biological processes. We employ a superconducting nanowire single-photon detector (SNSPD

  11. Modeling In situ sediment oxygen demand in the Arroyo Colorado 

    E-Print Network [OSTI]

    Kasprzak, Kevin Ray

    2001-01-01

    and are targeted for rehabilitation under the Total Maximum Daily Load (TMDL) program. In some rivers, sediment oxygen demand (SOD) accounts for as much as 50% of the total oxygen depletion, making SOD a critical element in water quality modeling studies. SOD...

  12. 14. CARBON AND OXYGEN ISOTOPE ANALYSIS OF LAKE SEDIMENT CELLULOSE

    E-Print Network [OSTI]

    Edwards, Thomas W.D.

    14. CARBON AND OXYGEN ISOTOPE ANALYSIS OF LAKE SEDIMENT CELLULOSE: METHODS AND APPLICATIONS BRENT B and Environmental Sciences Wesleyan University, Middletown, CT USA 06459 Keywords: cellulose, lake sediment, oxygen of lake sediment cellulose is a recently developed paleolimnological approach that is gaining increasing

  13. Palladium-cobalt particles as oxygen-reduction electrocatalysts

    DOE Patents [OSTI]

    Adzic, Radoslav (East Setauket, NY); Huang, Tao (Manorville, NY)

    2009-12-15

    The present invention relates to palladium-cobalt particles useful as oxygen-reducing electrocatalysts. The invention also relates to oxygen-reducing cathodes and fuel cells containing these palladium-cobalt particles. The invention additionally relates to methods for the production of electrical energy by using the palladium-cobalt particles of the invention.

  14. Breath is a mixture of nitrogen, oxygen, carbon dioxide, water

    E-Print Network [OSTI]

    12 SCIENCE Breath is a mixture of nitrogen, oxygen, carbon dioxide, water vapour, inert gases. On the basis of proton affinity, the major constituents of air and breath (nitrogen, oxygen, carbon dioxide, as the products of normal metabolism and those that have altered owing to disease, and are transported via

  15. E.L. Grossman Chapter 10 Oxygen Isotope Stratigraphy

    E-Print Network [OSTI]

    Grossman, Ethan L.

    E.L. Grossman Chapter 10 Oxygen Isotope Stratigraphy Abstract:Variations in the 18 O/16 O ratios isotope stratigraphy, however, is hampered by the lack of unaltered authigenic marine sediments. Chapter.6. Oxygen Isotope Stratigraphy 188 10.6.1. Cenozoic 188 10.6.2. Mesozoic 191 10.6.3. Paleozoic 193

  16. Geothermal Demonstration Plant

    Office of Scientific and Technical Information (OSTI)

    configuration by the preparation of process flow diagrams for the initial plant operating condition and the 1-2 mid-range plant operating condition. have been revised and expanded...

  17. Plant centromere compositions

    DOE Patents [OSTI]

    Mach; Jennifer M. (Chicago, IL), Zieler; Helge (Del Mar, CA), Jin; RongGuan (Chesterfield, MO), Keith; Kevin (Three Forks, MT), Copenhaver; Gregory P. (Chapel Hill, NC), Preuss; Daphne (Chicago, IL)

    2011-11-22

    The present invention provides for the nucleic acid sequences of plant centromeres. This will permit construction of stably inherited recombinant DNA constructs and minichromosomes which can serve as vectors for the construction of transgenic plant and animal cells.

  18. Plant centromere compositions

    DOE Patents [OSTI]

    Mach, Jennifer (Chicago, IL); Zieler, Helge (Chicago, IL); Jin, James (Chicago, IL); Keith, Kevin (Chicago, IL); Copenhaver, Gregory (Chapel Hill, NC); Preuss, Daphne (Chicago, IL)

    2006-06-26

    The present invention provides for the nucleic acid sequences of plant centromeres. This will permit construction of stably inherited recombinant DNA constructs and minichromosomes which can serve as vectors for the construction of transgenic plant and animal cells.

  19. Plant centromere compositions

    DOE Patents [OSTI]

    Mach, Jennifer M. (Chicago, IL); Zieler, Helge (Del Mar, CA); Jin, RongGuan (Chesterfield, MO); Keith, Kevin (Three Forks, MT); Copenhaver, Gregory P. (Chapel Hill, NC); Preuss, Daphne (Chicago, IL)

    2011-08-02

    The present invention provides for the nucleic acid sequences of plant centromeres. This will permit construction of stably inherited recombinant DNA constructs and minichromosomes which can serve as vectors for the construction of transgenic plant and animal cells.

  20. Plant centromere compositions

    DOE Patents [OSTI]

    Mach, Jennifer (Chicago, IL); Zieler, Helge (Chicago, IL); Jin, RongGuan (Chicago, IL); Keith, Kevin (Chicago, IL); Copenhaver, Gregory (Chapel Hill, NC); Preuss, Daphne (Chicago, IL)

    2007-06-05

    The present invention provides for the nucleic acid sequences of plant centromeres. This will permit construction of stably inherited recombinant DNA constructs and minichromosomes which can serve as vectors for the construction of transgenic plant and animal cells.

  1. Plant centromere compositions

    DOE Patents [OSTI]

    Keith, Kevin; Copenhaver, Gregory; Preuss, Daphne

    2006-10-10

    The present invention provides for the nucleic acid sequences of plant centromeres. This will permit construction of stably inherited recombinant DNA constructs and minichromosomes which can serve as vectors for the construction of transgenic plant and animal cells.

  2. HYDROCARBONS & ENERGY FROM PLANTS

    E-Print Network [OSTI]

    Nemethy, E.K.

    2011-01-01

    LBL-8596 itr-t C,d.. HYDROCARBONS & ENERGY FROM PLANTS jmethods of isolating the hydrocarbon-like material from I.privatelyownedrights. HYDROCARBONS AND ENERGY FROM PLANTS

  3. Fiber Optical Micro-detectors for Oxygen Sensing in Power Plants

    Office of Scientific and Technical Information (OSTI)

    wave pass (LWP) filter are used to separate the pump and signal beams. The detection opticselectronics consists of a Hamamatsu Detector R955 and a Stanford SR570 current...

  4. 468 Photosphere oxygen than the enzyme of C3 plants, but photores-

    E-Print Network [OSTI]

    Govindjee

    at Sacramento Peak, Sunspot, New Mexico. (National Solar Observatory) ing photospheric structure. Magnetic flux (10,500 F). Radiation emitted from the photosphere accounts for most of the solar energy flux at the Earth. The solar photosphere provides a natural lab- oratory for the study of dynamical and magnetic pro

  5. Advanced integration concepts for oxygen plants and gas turbines in gasification/IGCC facilities

    SciTech Connect (OSTI)

    Smith, A.R.; Klosek, J.; Woodward, D.W.

    1996-12-31

    The commercialization of Integrated Gasification Combined-Cycle (IGCC) power has been aided by concepts involving the integration of a cryogenic air separation unit (ASU) with the gas turbine combined-cycle module. Other processes, such as coal-based ironmaking and combined power and industrial gas production facilities, can benefit from the integration of these two units. It is known and now widely accepted that an ASU designed for elevated pressure service and optimally integrated with the gas turbine can increase overall IGCC power output, increase overall efficiency, and decrease the net cost of power generation compared to non-integrated facilities employing low pressure ASU`s. Depending upon the specific gas turbine, gasification technology, NOx emission specification, and other site specific factors, various degrees of compressed air and nitrogen integration are optimal. Air Products has supplied ASU`s with no integration (Destec/Plaquemine IGCC), nitrogen-only integration (Tampa Electric/Polk County IGCC), and full air and nitrogen integration (Demkolec/Buggenum IGCC). Continuing advancements in both air separation and gas turbine technologies offer new integration opportunities to further improve performance and reduce costs. This paper will review basic integration principles and describe advanced concepts based on emerging high compression ratio gas turbines. Humid Air Turbine (HAT) cycles, and integration of compression heat and refrigeration sources from the ASU. Operability issues associated with integration will be reviewed and control measures described for the safe, efficient, and reliable operation of these facilities.

  6. Flow Metering and Oxygen Trim Control Reduce Dairy Steam Plant Fuel Costs 

    E-Print Network [OSTI]

    Foster, E. L.; Nelson, R. L.

    1985-01-01

    Milk processing in a dairy is a very energy intensive task requiring large amounts of energy to heat and cool the product. Since profit margins are small and energy costs represent such a large part of product cost it is essential that effective...

  7. Fiber Optical Micro-detectors for Oxygen Sensing in Power Plants

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield MunicipalTechnical Report:Speeding accessby aLED Street Lighting FINAL TECHNICAL REPORTFiber Optical

  8. Plant evolution The Evolution

    E-Print Network [OSTI]

    Rieseberg, Loren

    Plant evolution The Evolution of Plants by Kathy J. Willis and Jenny C. McElwain. Oxford University Press, 2002. $40.00/£22.99 pbk (378 pages) ISBN 0 19 850065 3 Developmental Genetics and Plant Evolution is observed for treatments of evolution and development. Titles of major monographs on the subject imply

  9. Power Plant Cycling Costs

    SciTech Connect (OSTI)

    Kumar, N.; Besuner, P.; Lefton, S.; Agan, D.; Hilleman, D.

    2012-07-01

    This report provides a detailed review of the most up to date data available on power plant cycling costs. The primary objective of this report is to increase awareness of power plant cycling cost, the use of these costs in renewable integration studies and to stimulate debate between policymakers, system dispatchers, plant personnel and power utilities.

  10. NUCLEAR PLANT AND CONTROL

    E-Print Network [OSTI]

    NUCLEAR PLANT OPERATIONS AND CONTROL KEYWORDS: software require- ments, safety analysis, formal for the digital protection systems of a nuclear power plant. When spec- ifying requirements for software and CRSA processes are described using shutdown system 2 of the Wolsong nuclear power plants as the digital

  11. Plant species as a significant factor in wastewater treatment in constructed wetlands 

    E-Print Network [OSTI]

    Varvel, Tracey W

    2013-02-22

    point of many current studies. They are designed to mimic natural wetlands, leaving the majority of wastewater cleanup to wetlands plant life. The use of plant life to remove or reduce environmental contaminants is known as phytoremediation (Anderson..., 1996). The environmental contaminants present in wastewater include nitrogen (N), phosphorus (P), Biochemical Oxygen Demand (BOD) levels, suspended solids, and pathogens. These constructed wetlands have many advantages such as; energy efficiency...

  12. Oxygen and organic matter thresholds for benthic faunal activity on the Pakistan margin oxygen minimum zone (7001100 m)

    E-Print Network [OSTI]

    Levin, Lisa

    Oxygen and organic matter thresholds for benthic faunal activity on the Pakistan margin oxygen) on the bathyal Pakistan margin, where sediments grade from fully laminated sediment at 700 m (0.12 mL LÀ1 O2 [5 m matter to generate abrupt faunal transitions on the Pakistan margin. & 2008 Elsevier Ltd. All rights

  13. Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy Bills andOrder 422.1,an R7-Compatible CumulativeSavingsPlant-widePlastics

  14. Nanoparticulate-catalyzed oxygen transfer processes

    DOE Patents [OSTI]

    Hunt, Andrew T. (Atlanta, GA); Breitkopf, Richard C. (Dunwoody, GA)

    2009-12-01

    Nanoparticulates of oxygen transfer materials that are oxides of rare earth metals, combinations of rare earth metals, and combinations of transition metals and rare earth metals are used as catalysts in a variety of processes. Unexpectedly large thermal efficiencies are achieved relative to micron sized particulates. Processes that use these catalysts are exemplified in a multistage reactor. The exemplified reactor cracks C6 to C20 hydrocarbons, desulfurizes the hydrocarbon stream and reforms the hydrocarbons in the stream to produce hydrogen. In a first reactor stage the steam and hydrocarbon are passed through particulate mixed rare earth metal oxide to crack larger hydrocarbon molecules. In a second stage, the steam and hydrocarbon are passed through particulate material that desulfurizes the hydrocarbon. In a third stage, the hydrocarbon and steam are passed through a heated, mixed transition metal/rare earth metal oxide to reform the lower hydrocarbons and thereby produce hydrogen. Stages can be alone or combined. Parallel reactors can provide continuous reactant flow. Each of the processes can be carried out individually.

  15. Simulation Modeling of Plants and Plant Przemyslaw Prusinkiewicz

    E-Print Network [OSTI]

    Prusinkiewicz, Przemyslaw

    Simulation Modeling of Plants and Plant Ecosystems Przemyslaw Prusinkiewicz Reference Przemyslaw Prusinkiewicz: Simulation Modeling of Plants and Plant Ecosystems. Communications of the ACM vol. 43 no. 7, pp The modeling of plants and plant ecosystems has the captivating appeal of reproducing the visual beauty

  16. Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two aromatic hydrocarbons, 17 nitrated PAHs (NPAHs) and 8 oxygenated PAHs (OPAHs) were carried out during hydrocarbons; Nitrated polycyclic aromatic hydrocarbons; Oxygenated polycyclic aromatic hydrocarbons

  17. PLANT DISEASES IN SOUTH CAROLINA

    E-Print Network [OSTI]

    Stuart, Steven J.

    INDEX OF PLANT DISEASES IN SOUTH CAROLINA James H. Blake, Ed.D. Director, Home & Garden Information to compile a list of plant diseases occurring on cultivated and native plants in South Carolina. The data or conclusive list of the diseases of plants in South Carolina. New plants as well as new plant pathogens

  18. Boron nitride nanosheets as oxygen-atom corrosion protective coatings

    SciTech Connect (OSTI)

    Yi, Min; Shen, Zhigang; Zhao, Xiaohu; Liang, Shuaishuai; Liu, Lei

    2014-04-07

    The research of two-dimensional nanomaterials for anticorrosion applications is just recently burgeoning. Herein, we demonstrate the boron nitride nanosheets (BNNSs) coatings for protecting polymer from oxygen-atom corrosion. High-quality BNNSs, which are produced by an effective fluid dynamics method with multiple exfoliation mechanisms, can be assembled into coatings with controlled thickness by vacuum filtration. After exposed in atom oxygen, the naked polymer is severely corroded with remarkable mass loss, while the BNNSs-coated polymer remains intact. Barrier and bonding effects of the BNNSs are responsible for the coating's protective performance. These preliminary yet reproducible results pave a way for resisting oxygen-atom corrosion.

  19. Solid phases of spatially nanoconfined oxygen: A neutron scattering study

    SciTech Connect (OSTI)

    Kojda, Danny [Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, 14109 Berlin (Germany) [Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, 14109 Berlin (Germany); Freie Universität Berlin, 14195 Berlin (Germany); Wallacher, Dirk; Hofmann, Tommy, E-mail: tommy.hofmann@helmholtz-berlin.de [Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, 14109 Berlin (Germany)] [Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, 14109 Berlin (Germany); Baudoin, Simon; Hansen, Thomas [Institut Laue-Langevin, BP 156, 38042 Grenoble Cedex 9 (France)] [Institut Laue-Langevin, BP 156, 38042 Grenoble Cedex 9 (France); Huber, Patrick [Technische Universität Hamburg-Harburg, 21073 Hamburg (Germany)] [Technische Universität Hamburg-Harburg, 21073 Hamburg (Germany)

    2014-01-14

    We present a comprehensive neutron scattering study on solid oxygen spatially confined in 12 nm wide alumina nanochannels. Elastic scattering experiments reveal a structural phase sequence known from bulk oxygen. With decreasing temperature cubic ?-, orthorhombic ?- and monoclinic ?-phases are unambiguously identified in confinement. Weak antiferromagnetic ordering is observed in the confined monoclinic ?-phase. Rocking scans reveal that oxygen nanocrystals inside the tubular channels do not form an isotropic powder. Rather, they exhibit preferred orientations depending on thermal history and the very mechanisms, which guide the structural transitions.

  20. Oxygen Enrichment in the Process and Chemical Industries 

    E-Print Network [OSTI]

    Milne, R. T.

    1984-01-01

    the efficiency of combustion processes. In a conventional ai r-fuel flame, combustion results from the collision of oxygen molecules wi th those 0f the fuel. The use 0f oxygen enrichment to increase the oxygen concentration in the fuel-air mixture... (Figure 3), which leads to improved heat transfer in the combustion zone. This results in a number of potential advantages: i. Fuel Savings At constant output the fuel firing rate may be reduced to compensate for the improved heat utilization...

  1. Hydrogen production using hydrogenase-containing oxygenic photosynthetic organisms

    DOE Patents [OSTI]

    Melis, Anastasios; Zhang, Liping; Benemann, John R.; Forestier, Marc; Ghirardi, Maria; Seibert, Michael

    2006-01-24

    A reversible physiological process provides for the temporal separation of oxygen evolution and hydrogen production in a microorganism, which includes the steps of growing a culture of the microorganism in medium under illuminated conditions to accumulate an endogenous substrate, depleting from the medium a nutrient selected from the group consisting of sulfur, iron, and/or manganese, sealing the culture from atmospheric oxygen, incubating the culture in light whereby a rate of light-induced oxygen production is equal to or less than a rate of respiration, and collecting an evolved gas. The process is particularly useful to accomplish a sustained photobiological hydrogen gas production in cultures of microorganisms, such as Chlamydomonas reinhardtii.

  2. Hydrogen Production Using Hydrogenase-Containing Oxygenic Photosynthetic Organisms

    DOE Patents [OSTI]

    Melis, A.; Zhang, L.; Benemann, J. R.; Forestier, M.; Ghirardi, M.; Seibert, M.

    2006-01-24

    A reversible physiological process provides for the temporal separation of oxygen evolution and hydrogen production in a microorganism, which includes the steps of growing a culture of the microorganism in medium under illuminated conditions to accumulate an endogenous substrate, depleting from the medium a nutrient selected from the group consisting of sulfur, iron, and/or manganese, sealing the culture from atmospheric oxygen, incubating the culture in light whereby a rate of light-induced oxygen production is equal to or less than a rate of respiration, and collecting an evolved gas. The process is particularly useful to accomplish a sustained photobiological hydrogen gas production in cultures of microorganisms, such as Chlamydomonas reinhardtii.

  3. THERMOCHEMICAL CONVERSION OF FERMENTATION-DERIVED OXYGENATES TO FUELS

    SciTech Connect (OSTI)

    Ramasamy, Karthikeyan K.; Wang, Yong

    2013-06-01

    At present ethanol generated from renewable resources through fermentation process is the dominant biofuel. But ethanol suffers from undesirable fuel properties such as low energy density and high water solubility. The production capacity of fermentation derived oxygenates are projected to rise in near future beyond the current needs. The conversion of oxygenates to hydrocarbon compounds that are similar to gasoline, diesel and jet fuel is considered as one of the viable option. In this chapter the thermo catalytic conversion of oxygenates generated through fermentation to fuel range hydrocarbons will be discussed.

  4. Production of Ultra-Cold-Neutrons in Solid ?-Oxygen

    E-Print Network [OSTI]

    E. Gutsmiedl; A. Frei; F. Boehle; A. Maier; S. Paul; H. Schober; A. Orecchini

    2010-07-30

    Our recent neutron scattering measurements of phonons and magnons in solid \\alpha-oxygen have led us to a new understanding of the production mechanismen of ultra-cold-neutrons (UCN) in this super-thermal converter. The UCN production in solid \\alpha-oxygen is dominated by the excitation of phonons. The contribution of magnons to UCN production becomes only slightly important above E >10 meV and at E >4 meV. Solid \\alpha-oxygen is in comparison to solid deuterium less effcient in the down-scattering of thermal or cold neutrons into the UCN energy regime.

  5. System Evaluation and Economic Analysis of a HTGR Powered High-Temperature Electrolysis Hydrogen Production Plant

    SciTech Connect (OSTI)

    Michael G. McKellar; Edwin A. Harvego; Anastasia A. Gandrik

    2010-10-01

    A design for a commercial-scale high-temperature electrolysis (HTE) plant for hydrogen production has been developed. The HTE plant is powered by a high-temperature gas-cooled reactor (HTGR) whose configuration and operating conditions are based on the latest design parameters planned for the Next Generation Nuclear Plant (NGNP). The current HTGR reference design specifies a reactor power of 600 MWt, with a primary system pressure of 7.0 MPa, and reactor inlet and outlet fluid temperatures of 322°C and 750°C, respectively. The power conversion unit will be a Rankine steam cycle with a power conversion efficiency of 40%. The reference hydrogen production plant operates at a system pressure of 5.0 MPa, and utilizes a steam-sweep system to remove the excess oxygen that is evolved on the anode (oxygen) side of the electrolyzer. The overall system thermal-to-hydrogen production efficiency (based on the higher heating value of the produced hydrogen) is 40.4% at a hydrogen production rate of 1.75 kg/s and an oxygen production rate of 13.8 kg/s. An economic analysis of this plant was performed with realistic financial and cost estimating assumptions. The results of the economic analysis demonstrated that the HTE hydrogen production plant driven by a high-temperature helium-cooled nuclear power plant can deliver hydrogen at a cost of $3.67/kg of hydrogen assuming an internal rate of return, IRR, of 12% and a debt to equity ratio of 80%/20%. A second analysis shows that if the power cycle efficiency increases to 44.4%, the hydrogen production efficiency increases to 42.8% and the hydrogen and oxygen production rates are 1.85 kg/s and 14.6 kg/s respectively. At the higher power cycle efficiency and an IRR of 12% the cost of hydrogen production is $3.50/kg.

  6. Seasonal and interannual oxygen variability on the Washington and Oregon continental shelves

    E-Print Network [OSTI]

    2015-01-01

    oxygen variability on the Washington and Oregon continentalin Juan de Fuca Canyon, Washington, Geophys. Res. Lett. ,oxygen ?uxes on the Washington shelf and slope: A comparison

  7. Microfluidic advantage : novel techniques for protein folding and oxygen control in cell cultures

    E-Print Network [OSTI]

    Polinkovsky, Mark E.; Polinkovsky, Mark E.

    2012-01-01

    Novel Techniques for Protein Folding and Oxygen Control inTemperature Jump System to Study Fast Protein FoldingNovel Techniques for Protein Folding and Oxygen Control in

  8. High-Temperature Zirconia Oxygen Sensor with Sealed Metal/Metal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference...

  9. Impact of ethanol and butanol as oxygenates on SIDI engine efficiency...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ethanol and butanol as oxygenates on SIDI engine efficiency and emissions using steady-state and transient test procedures Impact of ethanol and butanol as oxygenates on SIDI...

  10. Holocene hydrologic balance of tropical South America from oxygen isotopes of lake sediment opal, Venezuelan Andes

    E-Print Network [OSTI]

    Wolfe, Alexander P.

    Holocene hydrologic balance of tropical South America from oxygen isotopes of lake sediment opal.V. All rights reserved. Keywords: oxygen isotopes; biogenic opal; hydrologic balance; Holocene; Venezuela

  11. Conditional sterility in plants

    DOE Patents [OSTI]

    Meagher, Richard B. (Athens, GA); McKinney, Elizabeth (Athens, GA); Kim, Tehryung (Taejeon, KR)

    2010-02-23

    The present disclosure provides methods, recombinant DNA molecules, recombinant host cells containing the DNA molecules, and transgenic plant cells, plant tissue and plants which contain and express at least one antisense or interference RNA specific for a thiamine biosynthetic coding sequence or a thiamine binding protein or a thiamine-degrading protein, wherein the RNA or thiamine binding protein is expressed under the regulatory control of a transcription regulatory sequence which directs expression in male and/or female reproductive tissue. These transgenic plants are conditionally sterile; i.e., they are fertile only in the presence of exogenous thiamine. Such plants are especially appropriate for use in the seed industry or in the environment, for example, for use in revegetation of contaminated soils or phytoremediation, especially when those transgenic plants also contain and express one or more chimeric genes which confer resistance to contaminants.

  12. Reactive Oxygen Species Driven Angiogenesis by Inorganic Nanorods

    E-Print Network [OSTI]

    Patra, Chitta Ranjan

    The exact mechanism of angiogenesis by europium hydroxide nanorods was unclear. In this study we have showed that formation of reactive oxygen species (H2O2 and O2·?) is involved in redox signaling pathways during angiogenesis, ...

  13. Phosphorescent semiconductor nanocrystals and proteins for biological oxygen sensing

    E-Print Network [OSTI]

    McLaurin, Emily J. (Emily Jane)

    2011-01-01

    Oxygen is required for cellular respiration by all complex life making it a key metabolic profiling factor in biological systems. Tumors are defined by hypoxia (low pO2), which has been shown to influence response to ...

  14. Deciphering brain oxygenation and its change with age using phosphorescence

    E-Print Network [OSTI]

    Meunier, Michel

    for energy metabolism in every cell in the body. · The functioning of the brain is critically dependent #12;Oxygenation biomarkers · Average tissue pO2 · Spatial heterogeneity in tissue pO2 · pO2 gradient

  15. Enhancing SNCR-aided combustion with oxygen addition

    DOE Patents [OSTI]

    Kobayashi, Hisashi; Wu, Kuang Tsai; Bool, III, Lawrence E.

    2004-03-09

    NOx emissions from combustion are reduced, NOx reduction efficiency by SNCR is improved, and other efficiencies are realized, by injecting oxygen into a fuel-rich combustion zone under controlled conditions.

  16. In-situ generation of oxygen-releasing metal peroxides

    DOE Patents [OSTI]

    Looney, Brian B. (Aiken, SC); Denham, Miles E. (Aiken, SC)

    2007-01-09

    A method for remediation of contaminants in soil and groundwater is disclosed. The method generates oxygen releasing solids in groundwater or soil by injecting an aqueous energetic oxidant solution containing free radicals, oxidative conditions can be created within or ahead of a contaminant plume. Some contaminants may be remediated directly by reaction with the free radicals. Additionally and more importantly, the free radicals create an oxidative condition whereby native or injected materials, especially metals, are converted to peroxides. These peroxides provide a long-term oxygen reservoir, releasing oxygen relatively slowly over time. The oxygen can enhance microbial metabolism to remediate contaminants, can react with contaminant metals either to form immobile precipitants or to mobilize other metals to permit remediation through leaching techniques. Various injection strategies for injecting the energetic oxidant solution are also disclosed.

  17. Vehicle Technologies Office Merit Review 2014: Intake Air Oxygen Sensor

    Broader source: Energy.gov [DOE]

    Presentation given by Robert Bosch at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about intake air oxygen sensors.

  18. Vehicle Technologies Office Merit Review 2015: Intake Air Oxygen Sensor

    Broader source: Energy.gov [DOE]

    Presentation given by Robert Bosch at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about intake air oxygen sensor.

  19. Hybrid membrane--PSA system for separating oxygen from air

    DOE Patents [OSTI]

    Staiger, Chad L. (Albuquerque, NM); Vaughn, Mark R. (Albuquerque, NM); Miller, A. Keith (Albuquerque, NM); Cornelius, Christopher J. (Blackburg, VA)

    2011-01-25

    A portable, non-cryogenic, oxygen generation system capable of delivering oxygen gas at purities greater than 98% and flow rates of 15 L/min or more is described. The system consists of two major components. The first component is a high efficiency membrane capable of separating argon and a portion of the nitrogen content from air, yielding an oxygen-enriched permeate flow. This is then fed to the second component, a pressure swing adsorption (PSA) unit utilizing a commercially available, but specifically formulated zeolite compound to remove the remainder of the nitrogen from the flow. The system is a unique gas separation system that can operate at ambient temperatures, for producing high purity oxygen for various applications (medical, refining, chemical production, enhanced combustion, fuel cells, etc . . . ) and represents a significant advance compared to current technologies.

  20. COLLATERAL EFFECTS ON SOLAR NEBULA OXYGEN ISOTOPES DUE TO INJECTION...

    Office of Scientific and Technical Information (OSTI)

    COLLATERAL EFFECTS ON SOLAR NEBULA OXYGEN ISOTOPES DUE TO INJECTION OF sup 26Al BY A NEARBY SUPERNOVA Citation Details In-Document Search Title: COLLATERAL EFFECTS ON SOLAR...

  1. Titania may produce abiotic oxygen atmospheres on habitable exoplanets

    E-Print Network [OSTI]

    Narita, Norio; Masaoka, Shigeyuki; Kusakabe, Nobuhiko

    2015-01-01

    The search for habitable exoplanets in the Universe is actively ongoing in the field of astronomy. The biggest future milestone is to determine whether life exists on such habitable exoplanets. In that context, oxygen in the atmosphere has been considered strong evidence for the presence of photosynthetic organisms. In this paper, we show that a previously unconsidered photochemical mechanism by titanium(IV) oxide (titania) can produce abiotic oxygen from liquid water under near ultraviolet (NUV) lights on the surface of exoplanets. Titania works as a photocatalyst to dissociate liquid water in this process. This mechanism offers a different source of a possibility of abiotic oxygen in atmospheres of exoplanets from previously considered photodissociation of water vapor in upper atmospheres by extreme ultraviolet (XUV) light. Our order-of-magnitude estimation shows that possible amounts of oxygen produced by this abiotic mechanism can be comparable with or even more than that in the atmosphere of the current ...

  2. Ultrafast kinetics subsequent to shock in an unreacted, oxygen...

    Office of Scientific and Technical Information (OSTI)

    subsequent to shock in an unreacted, oxygen balanced mixture of nitromethane and hydrogen peroxide Armstrong, M R; Zaug, J M; Grant, C D; Crowhurst, J C; Bastea, S 75...

  3. Oxygen enhanced switching to combustion of lower rank fuels

    DOE Patents [OSTI]

    Kobayashi, Hisashi; Bool, III, Lawrence E.; Wu, Kuang Tsai

    2004-03-02

    A furnace that combusts fuel, such as coal, of a given minimum energy content to obtain a stated minimum amount of energy per unit of time is enabled to combust fuel having a lower energy content, while still obtaining at least the stated minimum energy generation rate, by replacing a small amount of the combustion air fed to the furnace by oxygen. The replacement of oxygen for combustion air also provides reduction in the generation of NOx.

  4. Method for making oxygen-reducing catalyst layers

    DOE Patents [OSTI]

    O'Brien, Dennis P.; Schmoeckel, Alison K.; Vernstrom, George D.; Atanasoski, Radoslav; Wood, Thomas E.; O'Neill, David G.

    2010-06-22

    Methods are provided for making oxygen-reducing catalyst layers, which include simultaneous or sequential stops of physical vapor depositing an oxygen-reducing catalytic material onto a substrate, the catalytic material comprising a transition metal that is substantially free of platinum; and thermally treating the catalytic material. At least one of the physical vapor deposition and the thermal treatment is performed in a processing environment comprising a nitrogen-containing gas.

  5. Determination of carbon, nitrogen, and oxygen in high purity magnesium 

    E-Print Network [OSTI]

    Roche, Neil Gerard

    1981-01-01

    DETERMINATION OF CARBON, NITROGEN, AND OXYGEN IN HIGH PURITY MAGNESIUM A Thesis by NEIL GERARD ROCHE Submitted to the Graduate College of Texas A8cM University in partial i'ulfillment of the requirement for the degree of MASTER OF SCIENCE... December 1981 Major Subject: Chemistry DETERMINATION OF CARBON, NITROGEN, AND OXYGEN IN HIGH PURITY MAGNESIUM A Thesis by NEIL GERARD ROCHE Approved as to style and content by: E. A. Schweikert (Chairman of Committee) G. J. Bastiaans (Member) L...

  6. Oxygen-permeable ceramic membranes for gas separation

    SciTech Connect (OSTI)

    Balachandran, U.; Ma, B.; Maiya, P.S.; Dusek, J.T.; Mieville, R.L.; Picciolo, J.J.

    1998-02-01

    Mixed-conducting oxides have a wide range of applications, including fuel cells, gas separation systems, sensors, and electrocatalytic equipment. Dense ceramic membranes made of mixed-conducting oxides are particularly attractive for gas separation and methane conversion processes. Membranes made of Sr-Fe-Co oxide, which exhibits high combined electronic and oxygen ionic conductivities, can be used to selectively transport oxygen during the partial oxidation of methane to synthesis gas (syngas, i.e., CO + H{sub 2}). The authors have fabricated tubular Sr{sub 2}Fe{sub 2}CoO{sub 6+{delta}} membranes and tested them (some for more than 1,000 h) in a methane conversion reactor that was operating at 850--950 C. An oxygen permeation flux of {approx} 10 scc/cm{sup 2} {center_dot} min was obtained at 900 C in a tubular membrane with a wall thickness of 0.75 mm. Using a gas-tight electrochemical cell, the authors have also measured the steady-state oxygen permeability of flat Sr{sub 2}Fe{sub 2}CoO{sub 6+{delta}} membranes as a function of temperature and oxygen partial pressure(pO{sub 2}). Steady-state oxygen permeability increases with increasing temperature and with the difference in pO{sub 2} on the two sides of the membrane. At 900 C, an oxygen permeability of {approx} 2.5 scc/cm{sup 2} {center_dot} min was obtained in a 2.9-mm-thick membrane. This value agrees with that obtained in methane conversion reactor experiments. Current-voltage (I-V) characteristics determined in the gas-tight cell indicate that bulk effect, rather than surface exchange effect, is the main limiting factor for oxygen permeation of {approx} 1-mm-thick Sr{sub 2}Fe{sub 2}CoO{sub 6+{delta}} membranes at elevated temperatures (> 650 C).

  7. Mult-Pollutant Control Through Novel Approaches to Oxygen Enhanced Combustion

    SciTech Connect (OSTI)

    Richard Axelbaum; Pratim Biswas

    2009-02-28

    Growing concerns about global climate change have focused effortss on identifying approaches to stabilizing carbon dioxide levels in the atmosphere. One approach utilizes oxy-fuel combustion to produce a concentrated flue gas that will enable economical CO{sub 2} capture by direct methods. Oxy-fuel combustion rewuires an Air Separation Unit (ASU) to provide a high-purity stream of oxygen as well as a Compression and Purification Unit (CPU) to clean and compress the CO{sub 2} for long term storage. Overall plant efficiency will suffer from the parasitic load of both the ASU and CPU and researchers are investigating techniques to enhance other aspects of the combustion and gas cleanup proceses to improve the benefit-to-cost ratio. This work examines the influence of oxy-fuel combustion and non-carbon based sorbents on the formation and fate of multiple combustion pollutants both numerically and experimentally.

  8. SC Johnson Waxdale Plant

    SciTech Connect (OSTI)

    2010-01-01

    This is a combined heat and power (CHP) project profile on a 6.4 MW CHP application at SC Johnson Waxdale Plant in Racine, Wisconsin.

  9. HYDROCARBONS & ENERGY FROM PLANTS

    E-Print Network [OSTI]

    Nemethy, E.K.

    2011-01-01

    17 harvest was 19 rainfall contributed 5.6" water. Harvest.harvest 29 Aug~st, when plants began to flower, approximately 15 irrigation water

  10. Strain effects on oxygen transport in tetragonal zirconium dioxide

    SciTech Connect (OSTI)

    Xian-Ming Bai; Yongfeng Zhang; Michael R. Tonks

    2013-11-01

    Temperature accelerated dynamics and molecular dynamics simulations are used to investigate the strain effects on oxygen interstitial and vacancy migration in tetragonal zirconium dioxide. At zero external strain, the anisotropic migration mechanisms of oxygen defects are characterized. At non-zero strains, both the crystal structure and defect migration barriers are modified by strain. Under compressive strains, the defect migration barrier increases with the increasing strain for both interstitials and vacancies. The crystal structure transforms from a tetragonal to a nearly cubic fluorite structure. Accordingly, the defect migration becomes nearly isotropic. Under dilative strains, the migration barrier first decreases then increases with increasing strain for both types of defects. The tetragonal phase transforms to a lower symmetry structure that is close to the orthorhombic phase. In turn, the defect migration becomes highly anisotropic. Under both compressive and dilative strains, interstitials respond to strain more strongly than vacancies. At small dilative strains, an oxygen interstitial has comparable diffusivity to a vacancy, suggesting that both types of defects can contribute to oxygen transport, if they are present. Although currently no previous result is available to validate oxygen interstitial diffusion behavior, the trend of strain effects on oxygen vacancy diffusion is in good agreement with available experimental and theoretical studies in the literature.

  11. Gasification Plant Cost and Performance Optimization

    SciTech Connect (OSTI)

    Samuel Tam; Alan Nizamoff; Sheldon Kramer; Scott Olson; Francis Lau; Mike Roberts; David Stopek; Robert Zabransky; Jeffrey Hoffmann; Erik Shuster; Nelson Zhan

    2005-05-01

    As part of an ongoing effort of the U.S. Department of Energy (DOE) to investigate the feasibility of gasification on a broader level, Nexant, Inc. was contracted to perform a comprehensive study to provide a set of gasification alternatives for consideration by the DOE. Nexant completed the first two tasks (Tasks 1 and 2) of the ''Gasification Plant Cost and Performance Optimization Study'' for the DOE's National Energy Technology Laboratory (NETL) in 2003. These tasks evaluated the use of the E-GAS{trademark} gasification technology (now owned by ConocoPhillips) for the production of power either alone or with polygeneration of industrial grade steam, fuel gas, hydrocarbon liquids, or hydrogen. NETL expanded this effort in Task 3 to evaluate Gas Technology Institute's (GTI) fluidized bed U-GAS{reg_sign} gasifier. The Task 3 study had three main objectives. The first was to examine the application of the gasifier at an industrial application in upstate New York using a Southeastern Ohio coal. The second was to investigate the GTI gasifier in a stand-alone lignite-fueled IGCC power plant application, sited in North Dakota. The final goal was to train NETL personnel in the methods of process design and systems analysis. These objectives were divided into five subtasks. Subtasks 3.2 through 3.4 covered the technical analyses for the different design cases. Subtask 3.1 covered management activities, and Subtask 3.5 covered reporting. Conceptual designs were developed for several coal gasification facilities based on the fluidized bed U-GAS{reg_sign} gasifier. Subtask 3.2 developed two base case designs for industrial combined heat and power facilities using Southeastern Ohio coal that will be located at an upstate New York location. One base case design used an air-blown gasifier, and the other used an oxygen-blown gasifier in order to evaluate their relative economics. Subtask 3.3 developed an advanced design for an air-blown gasification combined heat and power facility based on the Subtask 3.2 design. The air-blown case was chosen since it was less costly and had a better return on investment than the oxygen-blown gasifier case. Under appropriate conditions, this study showed a combined heat and power air-blown gasification facility could be an attractive option for upgrading or expanding the utilities area of industrial facilities. Subtask 3.4 developed a base case design for a large lignite-fueled IGCC power plant that uses the advanced GE 7FB combustion turbine to be located at a generic North Dakota site. This plant uses low-level waste heat to dry the lignite that otherwise would be rejected to the atmosphere. Although this base case plant design is economically attractive, further enhancements should be investigated. Furthermore, since this is an oxygen-blown facility, it has the potential for capture and sequestration of CO{sub 2}. The third objective for Task 3 was accomplished by having NETL personnel working closely with Nexant and Gas Technology Institute personnel during execution of this project. Technology development will be the key to the long-term commercialization of gasification technologies. This will be important to the integration of this environmentally superior solid fuel technology into the existing mix of power plants and industrial facilities. As a result of this study, several areas have been identified in which research and development will further advance gasification technology. Such areas include improved system availability, development of warm-gas clean up technologies, and improved subsystem designs.

  12. Interaction of light with the ZnO surface: Photon induced oxygen “breathing,” oxygen vacancies, persistent photoconductivity, and persistent photovoltage

    SciTech Connect (OSTI)

    Gurwitz, Ron; Cohen, Rotem; Shalish, Ilan

    2014-01-21

    ZnO surfaces adsorb oxygen in the dark and emit CO{sub 2} when exposed to white light, reminiscent of the lungs of living creatures. We find that this exchange of oxygen with the ambient affects the integrity of the ZnO surface. Thus, it forms a basis for several interesting surface phenomena in ZnO, such as photoconductivity, photovoltage, and gas sensing, and has a role in ZnO electrical conduction. Using x-ray photoelectron spectroscopy on ZnO nanowires, we observed a decomposition of ZnO under white light and formation of oxygen-depleted surface, which explains photoconductivity by the electron donation of oxygen vacancies. Our findings suggest that the observed decomposition of the ZnO lattice may only take place due to photon-induced reduction of ZnO by carbon containing molecules (or carbo-photonic reduction), possibly from the ambient gas, accounting in a consistent way for both the reduced demands on the energy required for decomposition and for the observed emission of lattice oxygen in the form of CO{sub 2}. The formation of oxygen-vacancy rich surface is suggested to induce surface delta doping, causing accumulation of electrons at the surface, which accounts for both the increase in conductivity and the flattening of the energy bands. Using surface photovoltage spectroscopy in ultra high vacuum, we monitored changes in the deep level spectrum. We observe a wide optical transition from a deep acceptor to the conduction band, which energy position coincides with the position of the so called “green luminescence” in ZnO. This green transition disappears with the formation of surface oxygen vacancies. Since the oxygen vacancies are donors, while the green transition involves surface acceptors, the results suggest that the initial emission of oxygen originates at the defect sites of the latter, thereby eliminating each other. This suggests that the green transition originates at surface Zn vacancy acceptors. Removing an oxygen atom from a Zn vacancy completes the vacancy to become a full ZnO molecule vacancy, which does not produce deep levels. Our results explain why ZnO finds use as an electrical detector for oxygen and for carbon containing gas molecules. They may also shed new light on photocatalytic uses of ZnO. It is suggested that similar surface phenomena may affect other semiconducting oxides.

  13. EARLY ENTRANCE COPRODUCTION PLANT

    SciTech Connect (OSTI)

    Fred D. Brent; Lalit Shah; Earl Berry; Charles H. Schrader; John Anderson; J. Erwin; Matthew G. Banks; Terry L. Ullman

    2004-01-12

    The overall objective of this project is the three phase development of an Early Entrance Coproduction Plant (EECP) which uses petroleum coke to produce at least one product from at least two of the following three categories: (1) electric power (or heat), (2) fuels, and (3) chemicals using ChevronTexaco's proprietary gasification technology. The objective of Phase I is to determine the feasibility and define the concept for the EECP located at a specific site; develop a Research, Development, and Testing (RD&T) Plan to mitigate technical risks and barriers; and prepare a Preliminary Project Financing Plan. The objective of Phase II is to implement the work as outlined in the Phase I RD&T Plan to enhance the development and commercial acceptance of coproduction technology. The objective of Phase III is to develop an engineering design package and a financing and testing plan for an EECP located at a specific site. The project's intended result is to provide the necessary technical, economic, and environmental information needed by industry to move the EECP forward to detailed design, construction, and operation. The partners in this project are Texaco Energy Systems LLC or TES (a subsidiary of ChevronTexaco), General Electric (GE), Praxair, and Kellogg Brown & Root (KBR) in addition to the U.S. Department of Energy (DOE). TES is providing gasification technology and Fischer-Tropsch (F-T) technology developed by Rentech, GE is providing combustion turbine technology, Praxair is providing air separation technology, and KBR is providing engineering. Each of the EECP subsystems was assessed for technical risks and barriers. A plan was developed to mitigate the identified risks (Phase II RD&T Plan, October 2000). Phase II RD&T Task 2.6 identified as potential technical risks to the EECP the fuel/engine performance and emissions of the F-T diesel fuel products. Hydrotreating the neat F-T diesel product reduces potentially reactive olefins, oxygenates, and acids levels and alleviates corrosion and fuel stability concerns. Future coproduction plants can maximize valuable transportation diesel by hydrocracking the F-T Synthesis wax product to diesel and naphtha. The upgraded neat F-T diesel, hydrotreater F-T diesel, and hydrocracker F-T diesel products would be final blending components in transportation diesel fuel. Phase II RD&T Task 2.6 successfully carried out fuel lubricity property testing, fuel response to lubricity additives, and hot-start transient emission tests on a neat F-T diesel product, a hydrocracker F-T diesel product, a blend of hydrotreater and hydrocracker F-T diesel products, and a Tier II California Air Resources Board (CARB)-like diesel reference fuel. Only the neat F-T diesel passed lubricity inspection without additive while the remaining three fuel candidates passed with conventional additive treatment. Hot-start transient emission tests were conducted on the four fuels in accordance with the U.S. Environmental Protection Agency (EPA) Federal Test Procedure (FTP) specified in Code of Federal Regulations, Title 40, Part 86, and Subpart N on a rebuilt 1991 Detroit Diesel Corporation Series 60 heavy-duty diesel engine. Neat F-T diesel fuel reduced oxides of nitrogen (NO{sub x}), total particulate (PM), hydrocarbons (HC), carbon monoxide (CO), and the Soluble Organic Fraction (SOF) by 4.5%, 31%, 50%, 29%, and 35%, respectively, compared to the Tier II CARB-like diesel. The hydrocracker F-T diesel product and a blend of hydrocracker and hydrotreater F-T diesel products also reduced NO{sub x}, PM, HC, CO and SOF by 13%, 16% to 17%, 38% to 63%, 17% to 21% and 21% to 39% compared to the Tier II CARB-like diesel. The fuel/engine performance and emissions of the three F-T diesel fuels exceed the performance of a Tier II CARB-like diesel. Phase II RD&T Task 2.6 successfully met the lubricity property testing and F-T diesel fuel hot-start transient emissions test objectives. The results of the testing help mitigate potential economic risks on obtaining a premium price for the F-T diesel fuel

  14. Modulating lignin in plants

    DOE Patents [OSTI]

    Apuya, Nestor; Bobzin, Steven Craig; Okamuro, Jack; Zhang, Ke

    2013-01-29

    Materials and methods for modulating (e.g., increasing or decreasing) lignin content in plants are disclosed. For example, nucleic acids encoding lignin-modulating polypeptides are disclosed as well as methods for using such nucleic acids to generate transgenic plants having a modulated lignin content.

  15. Plant pathogen resistance

    DOE Patents [OSTI]

    Greenberg, Jean T; Jung, Ho Won; Tschaplinski, Timothy

    2012-11-27

    Azelaic acid or its derivatives or analogs induce a robust and a speedier defense response against pathogens in plants. Azelaic acid treatment alone does not induce many of the known defense-related genes but activates a plant's defense signaling upon pathogen exposure.

  16. Plant fatty acid hydroxylase

    DOE Patents [OSTI]

    Somerville, Chris (Portola Valley, CA); van de Loo, Frank (Lexington, KY)

    2000-01-01

    The present invention relates to the identification of nucleic acid sequences and constructs, and methods related thereto, and the use of these sequences and constructs to produce genetically modified plants for the purpose of altering the composition of plant oils, waxes and related compounds.

  17. NUCLEAR PLANT OPERATIONS AND

    E-Print Network [OSTI]

    Demazière, Christophe

    NUCLEAR PLANT OPERATIONS AND CONTROL KEYWORDS: moderator temper ature coefficient, reactivity co reactor Unit 4 of the Ringhals Nuclear Power Plant (Sweden) during fuel cycle 16 is analyzed of Reactor Physics SE-41296 Gothenburg, Sweden GABOR PÓR Budapest University of Technology and Economics H

  18. NUCLEAR PLANT OPERATIONS AND

    E-Print Network [OSTI]

    Pázsit, Imre

    NUCLEAR PLANT OPERATIONS AND CONTROL KEYWORDS: moderator temper- ature coefficient, reactivity co reactor Unit 4 of the Ringhals Nuclear Power Plant (Sweden) during fuel cycle 16 is analyzed of Reactor Physics SE-41296 Gothenburg, Sweden GABOR PÓR Budapest University of Technology and Economics H

  19. Modeling plant growth and development Przemyslaw Prusinkiewicz

    E-Print Network [OSTI]

    Prusinkiewicz, Przemyslaw

    Modeling plant growth and development Przemyslaw Prusinkiewicz Department of Computer Science plant models or "virtual plants" are increasingly seen as a useful tool for comprehending complex relationships between gene function, plant physiology, plant development, and the resulting plant form

  20. The JET Hydrogen-Oxygen Recombination Sensor – A Safety Device for Hydrogen Isotope Processing Systems

    E-Print Network [OSTI]

    The JET Hydrogen-Oxygen Recombination Sensor – A Safety Device for Hydrogen Isotope Processing Systems

  1. BIOENERGIZEME INFOGRAPHIC CHALLENGE: Photosynthesis: Plants Making...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Photosynthesis: Plants Making Fuel BIOENERGIZEME INFOGRAPHIC CHALLENGE: Photosynthesis: Plants Making Fuel BIOENERGIZEME INFOGRAPHIC CHALLENGE: Photosynthesis: Plants Making Fuel...

  2. Commercial demonstration of atmospheric medium BTU fuel gas production from biomass without oxygen the Burlington, Vermont Project

    SciTech Connect (OSTI)

    Rohrer, J.W.

    1995-12-31

    The first U.S. demonstration of a gas turbine operating on fuel gas produced by the thermal gasification of biomass occurred at Battelle Columbus Labs (BCL) during 1994 using their high throughput indirect medium Btu gasification Process Research Unit (PRU). Zurn/NEPCO was retained to build a commercial scale gas plant utilizing this technology. This plant will have a throughput rating of 8 to 12 dry tons per hour. During a subsequent phase of the Burlington project, this fuel gas will be utilized in a commercial scale gas turbine. It is felt that this process holds unique promise for economically converting a wide variety of biomass feedstocks efficiently into both a medium Btu (500 Btu/scf) gas turbine and IC engine quality fuel gas that can be burned in engines without modification, derating or efficiency loss. Others are currently demonstrating sub-commercial scale thermal biomass gasification processes for turbine gas, utilizing both atmospheric and pressurized air and oxygen-blown fluid bed processes. While some of these approaches hold merit for coal, there is significant question as to whether they will prove economically viable in biomass facilities which are typically scale limited by fuel availability and transportation logistics below 60 MW. Atmospheric air-blown technologies suffer from large sensible heat loss, high gas volume and cleaning cost, huge gas compressor power consumption and engine deratings. Pressurized units and/or oxygen-blown gas plants are extremely expensive for plant scales below 250 MW. The FERCO/BCL process shows great promise for overcoming the above limitations by utilizing an extremely high throughout circulation fluid bed (CFB) gasifier, in which biomass is fully devolitalized with hot sand from a CFB char combustor. The fuel gas can be cooled and cleaned by a conventional scrubbing system. Fuel gas compressor power consumption is reduced 3 to 4 fold verses low Btu biomass gas.

  3. Natural Ores as Oxygen Carriers in Chemical Looping Combustion

    SciTech Connect (OSTI)

    Tian, Hanjing; Siriwardane, Ranjani; Simonyi, Thomas; Poston, James

    2013-08-01

    Chemical looping combustion (CLC) is a combustion technology that utilizes oxygen from oxygen carriers (OC), such as metal oxides, instead of air to combust fuels. The use of natural minerals as oxygen carriers has advantages, such as lower cost and availability. Eight materials, based on copper or iron oxides, were selected for screening tests of CLC processes using coal and methane as fuels. Thermogravimetric experiments and bench-scale fixed-bed reactor tests were conducted to investigate the oxygen transfer capacity, reaction kinetics, and stability during cyclic reduction/oxidation reaction. Most natural minerals showed lower combustion capacity than pure CuO/Fe{sub 2}O{sub 3} due to low-concentrations of active oxide species in minerals. In coal CLC, chryscolla (Cu-based), magnetite, and limonite (Fe-based) demonstrated better reaction performances than other materials. The addition of steam improved the coal CLC performance when using natural ores because of the steam gasification of coal and the subsequent reaction of gaseous fuels with active oxide species in the natural ores. In methane CLC, chryscolla, hematite, and limonite demonstrated excellent reactivity and stability in 50-cycle thermogravimetric analysis tests. Fe{sub 2}O{sub 3}-based ores possess greater oxygen utilization but require an activation period before achieving full performance in methane CLC. Particle agglomeration issues associated with the application of natural ores in CLC processes were also studied by scanning electron microscopy (SEM).

  4. Interaction of root nodule size and oxygen pressure on the rate of nitrogen fixation by cowpea and peanut

    SciTech Connect (OSTI)

    Sen, D.; Weaver, R.W.

    1987-04-01

    Size and anatomical features of nodules influence the rate of O/sub 2/ diffusion into nodules. Availability of oxygen can be a limiting factor in nitrogen fixation. Larger nodules have thicker cortices and low surface to volume ratio leading to lower rates of gaseous diffusion. Increased oxygen pressure in the environment alters the rate of nitrogen fixation but the rate of change may depend on the nodule size. This was investigated by measuring /sup 15/N/sub 2/ incorporation into nodules. Root nodules from 38 day old cowpea and peanut plants were collected and sorted into size groups having diameters of >3 mm, 2-3 mm, and just below 2 mm. Samples of each size group were enclosed in tubes and exposed to various combination of oxygen (8-28%) and /sup 15/N/sub 2/. With higher O/sub 2/ pressure all nodules showed increased N/sub 2/ fixation but the largest nodules showed the maximum increase. Specific activity of larger nodules was higher for N/sub 2/ fixation. For the sizes of nodules examined the largest nodules did not reflect any of the disadvantages of the large size but the benefits of higher rates of O/sub 2/ entry was evident.

  5. Zero Emissions Coal Syngas Oxygen Turbo Machinery

    SciTech Connect (OSTI)

    Dennis Horazak

    2010-12-31

    Siemens Energy, Inc. (formerly Siemens Westinghouse Power Corporation) worked with Clean Energy Systems and Florida Turbine Technologies to demonstrate the commercial feasibility of advanced turbines for oxy-fuel based power systems that discharge negligible CO{sub 2} into the atmosphere. The approach builds upon ultra supercritical steam turbine and advanced gas turbine technology with the goal of attaining plant efficiencies above 50% in the 2015 timeframe. Conceptual designs were developed for baseline, near term, and long term oxy-fuel turbine cycles, representing commercial introductions of increasingly advanced thermal conditions and increasing exposure to steam-CO{sub 2} mixtures. An economic analysis and market demand study was performed by Science Applications International Corp. (SAIC), and indicated that long-term oxy-fuel turbine cycles start to look attractive in 2025 when the CO{sub 2} tax is assumed to reach $40/ ton, and by 2030 it has a clear advantage over both IGCC with sequestration and pulverized coal with sequestration. A separate risk analysis of the oxy-fuel combustor, HP turbine, re-heater, and IP turbine of the long-term cycle identified and categorized risks and proposed mitigation measures. In 2007 the program began to focus on a potential oxy-fuel turbine power generation demonstration project in the 2012 -13 time period while still maintaining a link to the requirements of the long-term oxy-syngas cycle. The SGT-900 turbine was identified as the best fit for modification into an intermediate pressure turbine (IPT) for this application. The base metals, bond coats, thermal barrier coatings (TBCs), and rotor materials used in the SGT-900 were tested for their ability to operate in the steam- CO{sub 2} environment of the oxy-fuel OFT-900. Test results indicated that these same materials would operate satisfactorily, and the plan, is to use SGT-900materials for the OFT-900. Follow-on programs for corrosion testing and evaluation of crack growth rates in oxy-fuel environments have been proposed to build on these results and provide quantifiable assessments of the effects of oxy-fuel environments on the service lives of turbine components.

  6. Plant Phenotype Characterization System | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Plant Phenotype Characterization System Plant Phenotype Characterization System New X-Ray Technology Accelerates Plant Research The ability to analyze plant root structure and...

  7. Iowa Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Iowa nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net...

  8. Illinois Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Illinois nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear...

  9. Arkansas Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net...

  10. Nebraska Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Nebraska nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear...

  11. Washington Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Washington nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State...

  12. Mississippi Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Mississippi nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State...

  13. Connecticut Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Connecticut nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State...

  14. Maryland Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net...

  15. Missouri Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net...

  16. Virginia Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net...

  17. Arizona Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net...

  18. Pennsylvania Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Pennsylvania nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State...

  19. Florida Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Florida nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear...

  20. Ohio Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Ohio nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net...

  1. Michigan Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net...

  2. California Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    California nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State...

  3. Alabama Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net...

  4. Tennessee Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Tennessee nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear...

  5. Massachusetts Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net...

  6. Georgia Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net...

  7. Vermont Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net...

  8. Kansas Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Kansas nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear...

  9. Texas Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net...

  10. Minnesota Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Minnesota nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear...

  11. Wisconsin Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Wisconsin nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear...

  12. Fuel and oxygen addition for metal smelting or refining process

    DOE Patents [OSTI]

    Schlichting, M.R.

    1994-11-22

    A furnace for smelting iron ore and/or refining molten iron is equipped with an overhead pneumatic lance, through which a center stream of particulate coal is ejected at high velocity into a slag layer. An annular stream of nitrogen or argon enshrouds the coal stream. Oxygen is simultaneously ejected in an annular stream encircling the inert gas stream. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus to react with carbon monoxide gas rising from slag layer, thereby adding still more heat to the furnace. 7 figs.

  13. Fuel and oxygen addition for metal smelting or refining process

    DOE Patents [OSTI]

    Schlichting, Mark R. (Chesterton, IN)

    1994-01-01

    A furnace 10 for smelting iron ore and/or refining molten iron 20 is equipped with an overhead pneumatic lance 40, through which a center stream of particulate coal 53 is ejected at high velocity into a slag layer 30. An annular stream of nitrogen or argon 51 enshrouds the coal stream. Oxygen 52 is simultaneously ejected in an annular stream encircling the inert gas stream 51. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus 84 to react with carbon monoxide gas rising from slag layer 30, thereby adding still more heat to the furnace.

  14. Method and apparatus for producing oxygenates from hydrocarbons

    DOE Patents [OSTI]

    Kong, Peter C. (Idaho Falls, ID); Lessing, Paul A. (Idaho Falls, ID)

    1995-01-01

    A chemical reactor for oxygenating hydrocarbons includes: a) a dielectric barrier discharge plasma cell, the plasma cell comprising a pair of electrodes having a dielectric material and void therebetween, the plasma cell comprising a hydrocarbon gas inlet feeding to the void; b) a solid oxide electrochemical cell, the electrochemical cell comprising a solid oxide electrolyte positioned between a porous cathode and a porous anode, an oxygen containing gas inlet stream feeding to the porous cathode side of the electrochemical cell; c) a first gas passageway feeding from the void to the anode side of the electrochemical cell; and d) a gas outlet feeding from the anode side of the electrochemical cell to expel reaction products from the chemical reactor. A method of oxygenating hydrocarbons is also disclosed.

  15. Properties of reactive oxygen species by quantum Monte Carlo

    SciTech Connect (OSTI)

    Zen, Andrea; Trout, Bernhardt L.; Guidoni, Leonardo

    2014-07-07

    The electronic properties of the oxygen molecule, in its singlet and triplet states, and of many small oxygen-containing radicals and anions have important roles in different fields of chemistry, biology, and atmospheric science. Nevertheless, the electronic structure of such species is a challenge for ab initio computational approaches because of the difficulties to correctly describe the statical and dynamical correlation effects in presence of one or more unpaired electrons. Only the highest-level quantum chemical approaches can yield reliable characterizations of their molecular properties, such as binding energies, equilibrium structures, molecular vibrations, charge distribution, and polarizabilities. In this work we use the variational Monte Carlo (VMC) and the lattice regularized Monte Carlo (LRDMC) methods to investigate the equilibrium geometries and molecular properties of oxygen and oxygen reactive species. Quantum Monte Carlo methods are used in combination with the Jastrow Antisymmetrized Geminal Power (JAGP) wave function ansatz, which has been recently shown to effectively describe the statical and dynamical correlation of different molecular systems. In particular, we have studied the oxygen molecule, the superoxide anion, the nitric oxide radical and anion, the hydroxyl and hydroperoxyl radicals and their corresponding anions, and the hydrotrioxyl radical. Overall, the methodology was able to correctly describe the geometrical and electronic properties of these systems, through compact but fully-optimised basis sets and with a computational cost which scales as N{sup 3} ? N{sup 4}, where N is the number of electrons. This work is therefore opening the way to the accurate study of the energetics and of the reactivity of large and complex oxygen species by first principles.

  16. GEOTHERMAL POWER GENERATION PLANT

    Broader source: Energy.gov [DOE]

    Project objectives: Drilling a deep geothermal well on the Oregon Institute of Technology campus, Klamath Falls, OR. Constructing a geothermal power plant on the Oregon Institute of Technology campus.

  17. Plant Site Refrigeration Upgrade 

    E-Print Network [OSTI]

    Zdrojewski, R.; Healy, M.; Ramsey, J.

    1999-01-01

    Bayer Corporation operates a multi-division manufacturing facility in Bushy Park, South Carolina. Low temperature refrigeration (-4°F) is required by many of the chemical manufacturing areas and is provided by a Plant Site Refrigeration System...

  18. HYDROCARBONS & ENERGY FROM PLANTS

    E-Print Network [OSTI]

    Nemethy, E.K.

    2011-01-01

    categories: I. Methods of extraction of the dried plants.d) Processing methods: optimum extraction procedures;is the traditional method of extraction for rUbber-pr~duci

  19. Heating Plant Emergency Instructions

    E-Print Network [OSTI]

    de Leon, Alex R.

    Heating Plant Emergency Instructions In the event of an EMERGENCY dial 403-220-5333 for Campus room, closet or hallway (ground floor, if possible) Stay away from outside walls, windows and doors

  20. Plant Vascular Biology 2010

    SciTech Connect (OSTI)

    Ding, Biao

    2014-11-17

    This grant supported the Second International Conference on Plant Vascular Biology (PVB 2010) held July 24-28, 2010 on the campus of Ohio State University, Columbus, Ohio. Biao Ding (Ohio State University; OSU) and David Hannapel (Iowa State University; ISU) served as co-chairs of this conference. Biao Ding served as the local organizer. PVB is defined broadly here to include studies on the biogenesis, structure and function of transport systems in plants, under conditions of normal plant growth and development as well as of plant interactions with pathogens. The transport systems cover broadly the xylem, phloem, plasmodesmata and vascular cell membranes. The PVB concept has emerged in recent years to emphasize the integrative nature of the transport systems and approaches to investigate them.

  1. & Immobilization Plant Project

    Office of Environmental Management (EM)

    and monitoring challenges at the Waste Treatment Plant (WTP) in Hanford. The "black cell" design concept and the use of Power Fluidic Pulse Jet Mixer technology on which WTP is...

  2. Optimization of Oxygen Purity for Coal Conversion Energy Reduction 

    E-Print Network [OSTI]

    Baker, C. R.; Pike, R. A.

    1982-01-01

    or liquefaction. Gasification of coal is a partial oxidation process in which steam and oxygen are reacted with coal to produce a mixture of hydrogen and carbon monoxide plus a number of other components. This mixture has a heating value of about 300 Btu..., or hydrocarbon liquids. The synthesis gas mixture can also be converted by means of the water gas shift reaction to produce hydrogen Which, in turn, can be reacted with coal to form hydrocarbon liquids by direct liquefaction techniques. Oxygen is required...

  3. Demonstration of membrane aeration panels: City of Geneva Wastewater Treatment Plant. Final report

    SciTech Connect (OSTI)

    1995-01-01

    This report describes the design, construction, and testing of membrane aeration panels at the Marsh Creek wastewater treatment plant (WWTP) in Geneva, NY. The operators at the Geneva plant have undertaken a long-term program to upgrade wastewater treatment processes and lower operating costs. The aging mechanical surface aerators at the Marsh Creek treatment plant were replaced by a state-of-the-art membrane panel system. This fine-bubble diffused air system offers higher oxygen transfer efficiency than surface aerators or other types of fine-bubble diffused-air systems. The project had four objectives: to decrease the amount of electricity used at the plant for aeration; to enable the plant`s existing aeration basins to accommodate higher organic loads and/or nitrify the wastewater should the need arise; to provide an even distribution of dissolved oxygen within the aeration basins to enhance biological wastewater treatment activity; and to provide technical data to assess the performance of the membrane panel system versus other forms of wastewater aeration.

  4. Fiber-optic oxygen sensor using molybdenum chloride cluster luminescence

    E-Print Network [OSTI]

    Ghosh, Ruby N.

    been obtained, a range suitable for biological and automotive applications. The luminescence signal. S0003-6951 99 01445-X The quantitative detection of oxygen is important for industrial, automotive constant of 10 4 cm2 /s or a diffusion time of 1 s. PTMSP's mechanical properties, environmental stability

  5. Materials and methods for the separation of oxygen from air

    DOE Patents [OSTI]

    MacKay, Richard; Schwartz, Michael; Sammells, Anthony F.

    2003-07-15

    Metal oxides particularly useful for the manufacture of catalytic membranes for gas-phase oxygen separation processes having the formula: O.sub.5+z where: x and x' are greater than 0; y and y' are greater than 0; x+x' is equal to 2; y+y' is less than or equal to 2; z is a number that makes the metal oxide charge neutral; A is an element selected from the lanthanide elements; A' is an element selected from Be, Mg, Ca, Sr, Ba and Ra; A" is an element selected from the f block lanthanides, Be, Mg, Ca, Sr, Ba and Ra; B is an element selected from the group consisting of Al, Ga, In or mixtures thereof and B" is Co or Mg, with the exception that when B" is Mg, A' and A" are not Mg. The metal oxides are useful for preparation of dense membranes which may be formed from dense thin films of the mixed metal oxide on a porous metal oxide element. The invention also provides methods and catalytic reactors for oxygen separation and oxygen enrichment of oxygen deficient gases which employ mixed conducting metal oxides of the above formula.

  6. Methane Activation with Rhenium Catalysts. 1. Bidentate Oxygenated Ligands

    E-Print Network [OSTI]

    Goddard III, William A.

    Methane Activation with Rhenium Catalysts. 1. Bidentate Oxygenated Ligands Jason M. Gonzales, Jonas, California 90089 ReceiVed July 31, 2006 Trends in methane activation have been explored for rhenium complexes proceeds with methane activation through a barrier of less than 35 kcal mol-1 . Study

  7. Process for conversion of lignin to reformulated, partially oxygenated gasoline

    DOE Patents [OSTI]

    Shabtai, Joseph S. (Salt Lake City, UT); Zmierczak, Wlodzimierz W. (Salt Lake City, UT); Chornet, Esteban (Golden, CO)

    2001-01-09

    A high-yield process for converting lignin into reformulated, partially oxygenated gasoline compositions of high quality is provided. The process is a two-stage catalytic reaction process that produces a reformulated, partially oxygenated gasoline product with a controlled amount of aromatics. In the first stage of the process, a lignin feed material is subjected to a base-catalyzed depolymerization reaction, followed by a selective hydrocracking reaction which utilizes a superacid catalyst to produce a high oxygen-content depolymerized lignin product mainly composed of alkylated phenols, alkylated alkoxyphenols, and alkylbenzenes. In the second stage of the process, the depolymerized lignin product is subjected to an exhaustive etherification reaction, optionally followed by a partial ring hydrogenation reaction, to produce a reformulated, partially oxygenated/etherified gasoline product, which includes a mixture of substituted phenyl/methyl ethers, cycloalkyl methyl ethers, C.sub.7 -C.sub.10 alkylbenzenes, C.sub.6 -C.sub.10 branched and multibranched paraffins, and alkylated and polyalkylated cycloalkanes.

  8. Characteristics of Knock in Hydrogen-Oxygen-Argon SI Engine

    SciTech Connect (OSTI)

    Killingsworth, N; Rapp, V; Flowers, D; Aceves, S; Chen, J; Dibble, R

    2010-02-23

    A promising approach for improving the efficiency of internal combustion engines is to employ a working fluid with a high specific heat ratio such as the noble gas argon. Moreover, all harmful emissions are eliminated when the intake charge is composed of oxygen, nonreactive argon, and hydrogen fuel. Previous research demonstrated indicated thermal efficiencies greater than 45% at 5.5 compression ratio in engines operating with hydrogen, oxygen, and argon. However, knock limits spark advance and increasing the efficiency further. Conditions under which knock occurs in such engines differs from typical gasoline fueled engines. In-cylinder temperatures using hydrogen-oxygen-argon are higher due to the high specific heat ratio and pressures are lower because of the low compression ratio. Better understanding of knock under these conditions can lead to operating strategies that inhibit knock and allow operation closer to the knock limit. In this work we compare knock with a hydrogen, oxygen, and argon mixture to that of air-gasoline mixtures in a variable compression ratio cooperative fuels research (CFR) engine. The focus is on stability of knocking phenomena, as well as, amplitude and frequency of the resulting pressure waves.

  9. Utilization of Renewable Oxygenates as Gasoline Blending Components

    SciTech Connect (OSTI)

    Yanowitz, J.; Christensen, E.; McCormick, R. L.

    2011-08-01

    This report reviews the use of higher alcohols and several cellulose-derived oxygenates as blend components in gasoline. Material compatibility issues are expected to be less severe for neat higher alcohols than for fuel-grade ethanol. Very little data exist on how blending higher alcohols or other oxygenates with gasoline affects ASTM Standard D4814 properties. Under the Clean Air Act, fuels used in the United States must be 'substantially similar' to fuels used in certification of cars for emission compliance. Waivers for the addition of higher alcohols at concentrations up to 3.7 wt% oxygen have been granted. Limited emission testing on pre-Tier 1 vehicles and research engines suggests that higher alcohols will reduce emissions of CO and organics, while NOx emissions will stay the same or increase. Most oxygenates can be used as octane improvers for standard gasoline stocks. The properties of 2-methyltetrahydrofuran, dimethylfuran, 2-methylfuran, methyl pentanoate and ethyl pentanoate suggest that they may function well as low-concentration blends with gasoline in standard vehicles and in higher concentrations in flex fuel vehicles.

  10. Atomic oxygen patterning from a biomedical needle-plasma source

    SciTech Connect (OSTI)

    Kelly, Seán; Turner, Miles M.

    2013-09-28

    A “plasma needle” is a cold plasma source operating at atmospheric pressure. Such sources interact strongly with living cells, but experimental studies on bacterial samples show that this interaction has a surprising pattern resulting in circular or annular killing structures. This paper presents numerical simulations showing that this pattern occurs because biologically active reactive oxygen and nitrogen species are produced dominantly where effluent from the plasma needle interacts with ambient air. A novel solution strategy is utilised coupling plasma produced neutral (uncharged) reactive species to the gas dynamics solving for steady state profiles at the treated biological surface. Numerical results are compared with experimental reports corroborating evidence for atomic oxygen as a key bactericidal species. Surface losses are considered for interaction of plasma produced reactants with reactive solid and liquid interfaces. Atomic oxygen surface reactions on a reactive solid surface with adsorption probabilities above 0.1 are shown to be limited by the flux of atomic oxygen from the plasma. Interaction of the source with an aqueous surface showed hydrogen peroxide as the dominant species at this interface.

  11. Fault Tolerant Oxygen Control of a Diesel Engine Air System

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Fault Tolerant Oxygen Control of a Diesel Engine Air System Rainer Nitsche Matthias Bitzer control problem of a Diesel engine air system having a jammed Exhaust Gas Recirculation (EGR) valve of the air system. Keywords: Fault tolerant control, Diesel engine, Air system, Model-based trajectory

  12. An oxygen reduction electrocatalyst based on carbon nanotubegraphene complexes

    E-Print Network [OSTI]

    Pennycook, Steve

    such as platinum or its alloys are routinely used in fuel cells because of their high activity. Carbon alloys) for the oxygen reduction reaction (ORR) in acidic media for proton-exchange membrane fuel cells1, and designing catalysts with both optimal activity and stability for ORR in acidic solutions all remain

  13. Reaction Pathways for Oxygen Evolution Promoted by Cobalt Giuseppe Mattioli,*,

    E-Print Network [OSTI]

    Guidoni, Leonardo

    by such natural processes, the goal of artificial photosynthesis is to develop simplified but still efficient models in explicit water solution, we provide insight into the pathways for oxygen evolution of a cobalt routes to generate chemical fuels (e.g., H2) directly from sunlight by means of "artificial leafs",3,4 i

  14. High-temperature potentiometric oxygen sensor with internal reference

    DOE Patents [OSTI]

    Routbort, Jules L. (Hinsdale, IL); Singh, Dileep (Naperville, IL); Dutta, Prabir K. (Worthington, OH); Ramasamy, Ramamoorthy (North Royalton, OH); Spirig, John V. (Columbus, OH); Akbar, Sheikh (Hilliard, OH)

    2011-11-15

    A compact oxygen sensor is provided, comprising a mixture of metal and metal oxide an enclosure containing said mixture, said enclosure capable of isolating said mixture from an environment external of said enclosure, and a first wire having a first end residing within the enclosure and having a second end exposed to the environment. Also provided is a method for the fabrication of an oxygen sensor, the method comprising confining a metal-metal oxide solid mixture to a container which consists of a single material permeable to oxygen ions, supplying an electrical conductor having a first end and a second end, whereby the first end resides inside the container as a reference (PO.sub.2).sup.ref, and the second end resides outside the container in the atmosphere where oxygen partial pressure (PO.sub.2).sup.ext is to be measured, and sealing the container with additional single material such that grain boundary sliding occurs between grains of the single material and grains of the additional single material.

  15. OXYGEN BLOCK IN THE MAIN -STEM WILLAMETTE RIVER

    E-Print Network [OSTI]

    ^hly publicized run of spring-chinook salmon. Pollution of the Willamette River is a problem that has receivedOXYGEN BLOCK IN THE MAIN -STEM WILLAMETTE RIVER i.iiit' I'.iological Labordtory B R A tl Y OCT 9-STEM WILIA^TETTE RIVER By Frederic F. Fish In Charge, Western Fish-Cultural Investigations and Richard A

  16. IMPROVEMENTS IN MODELLING DISSOLVED OXYGEN IN ACTIVATED SLUDGE SYSTEMS

    E-Print Network [OSTI]

    Wells, Scott A.

    . Wells** *Technical University of Gdansk, Department of Environmental Engineering, ul. Narutowicza 11 the impact of reactor hydraulics and variable oxygen mass transfer on a predicted DO profile along the longitudinal axis of the activated sludge reactor. Many important parameters are influenced by the hydraulic

  17. INVESTIGATION OF OXYGEN REDUCTION MECHANISMS USING CATHODE MICROELECTRODES, PART II

    E-Print Network [OSTI]

    Yildiz, Bilge

    and alternatives are proposed for further investigation. INTRODUCTION The power of a solid oxide fuel cell (SOFC. Although oxygen re- duction at SOFC cathodes has been studied in the literature, a comprehensive and clear resistances and capacitances in the SOFC behavior. All implications presented in Refs. 2-7 have been based

  18. Oxygen adsorption on graphite and nanotubes P. Giannozzi,a)

    E-Print Network [OSTI]

    Giannozzi, Paolo

    Oxygen adsorption on graphite and nanotubes P. Giannozzi,a) R. Car, and G. Scoles Chemistry Department and Princeton Materials Institute, Princeton University, Princeton, New Jersey 08544 Received 29 in molecular form,6 with an estimated binding energy E 0.19 eV. This would be consistent with the well

  19. Kimberlina: a zero-emissions demonstration plant

    SciTech Connect (OSTI)

    Pronske, K.

    2007-06-15

    FutureGen may be getting the headlines, but it is not the only superclean demonstration plant in town. In fact, you could argue that other technologies are further down the evolutionary timeline. Case in point: Clean Energy Systems' adaptation of rocket engine technology to radically change the way fuel is burned. The result is a true zero-emissions power plant. Its most distinctive element is an oxy-combustor, similar to one used in rocket engines, that generates steam by burning clean, gaseous fuel in the presence of gaseous oxygen and water. The clean fuel is prepared by processing a conventional fossil fuel such as coal-derived syngas, refinery residues, biomass or biodigester gas, or natural or landfill gas. Combustion takes place at near-stoichiometric conditions to produce a mixture of steam and CO{sub 2} at high temperature and pressure. The steam conditions are suitable for driving a conventional or advanced steam turbine-generator, or a gas turbine modified to be driven by high-temperature steam or to do work as an expansion unit at intermediate pressure. After pressure through the turbine(s), the steam/CO{sub 2} mixture is condensed, cooled, and separated into water and CO{sub 2}. The CO{sub 2} can be sequestered and/or purified and sold for commercial use. Durability and performance tests carried out between March 2005 and March 2006 produced excellent results. CO and NOx emissions are considerably low than those of combined-cycle power plants fuelled by natural gas and using selective catalytic reduction for NOx control. Work is continuing under an NETL grant. Progress and plans are reported in the article. 7 figs.

  20. GEOTHERMAL POWER GENERATION PLANT

    SciTech Connect (OSTI)

    Boyd, Tonya

    2013-12-01

    Oregon Institute of Technology (OIT) drilled a deep geothermal well on campus (to 5,300 feet deep) which produced 196oF resource as part of the 2008 OIT Congressionally Directed Project. OIT will construct a geothermal power plant (estimated at 1.75 MWe gross output). The plant would provide 50 to 75 percent of the electricity demand on campus. Technical support for construction and operations will be provided by OIT’s Geo-Heat Center. The power plant will be housed adjacent to the existing heat exchange building on the south east corner of campus near the existing geothermal production wells used for heating campus. Cooling water will be supplied from the nearby cold water wells to a cooling tower or air cooling may be used, depending upon the type of plant selected. Using the flow obtained from the deep well, not only can energy be generated from the power plant, but the “waste” water will also be used to supplement space heating on campus. A pipeline will be construction from the well to the heat exchanger building, and then a discharge line will be construction around the east and north side of campus for anticipated use of the “waste” water by facilities in an adjacent sustainable energy park. An injection well will need to be drilled to handle the flow, as the campus existing injection wells are limited in capacity.

  1. Oxygen: From Environment to Genes. The periodic occurrence of oxygen minima can powerfully influence organisms living in near

    E-Print Network [OSTI]

    ­ Humans and Hypoxia in the Ocean, spread and recovery of dead zones. 20. Martini Arostegui - Oxygen terrestrial use flows into nearshore ocean waters. These high-nutrient inputs fuel phytoplankton blooms increasingly anoxic, zones are not directly human-induced, but occur with variations in the winds that drive

  2. Interaction of light with the ZnO surface: Photon induced oxygen "breathing," oxygen vacancies, persistent photoconductivity,

    E-Print Network [OSTI]

    Shalish, Ilan

    , which energy position coincides with the position of the so called "green luminescence" in Zn on the energy required for decomposition and for the observed emission of lattice oxygen in the form of CO2 of the energy bands. Using surface photovoltage spectroscopy in ultra high vacuum, we monitored changes

  3. Geothermal Plant Capacity Factors

    SciTech Connect (OSTI)

    Greg Mines; Jay Nathwani; Christopher Richard; Hillary Hanson; Rachel Wood

    2015-01-01

    The capacity factors recently provided by the Energy Information Administration (EIA) indicated this plant performance metric had declined for geothermal power plants since 2008. Though capacity factor is a term commonly used by geothermal stakeholders to express the ability of a plant to produce power, it is a term frequently misunderstood and in some instances incorrectly used. In this paper we discuss how this capacity factor is defined and utilized by the EIA, including discussion on the information that the EIA requests from operations in their 923 and 860 forms that are submitted both monthly and annually by geothermal operators. A discussion is also provided regarding the entities utilizing the information in the EIA reports, and how those entities can misinterpret the data being supplied by the operators. The intent of the paper is to inform the facility operators as the importance of the accuracy of the data that they provide, and the implications of not providing the correct information.

  4. Summary -Procedure For Shutting Off The Oxygen Zone Valve 1. Implement RACE Call the Emergency Operator at 4-2012.

    E-Print Network [OSTI]

    Acton, Scott

    Summary - Procedure For Shutting Off The Oxygen Zone Valve 1. Implement RACE ­ Call the Emergency-cylinders for low oxygen needs and bag ventilated patients using E-cylinders. 4. Identify oxygen zone valve for the affected rooms/areas. 5. Turn off the flow of oxygen at the zone valve if the oxygen cannot be turned off

  5. Open-cycle magnetohydrodynamic power plant with CO.sub.2 recycling

    DOE Patents [OSTI]

    Berry, Gregory F. (Naperville, IL)

    1991-01-01

    A method of converting the chemical energy of fossil fuel to electrical and mechanical energy with a MHD generator. The fossil fuel is mixed with preheated oxygen and carbon dioxide and a conducting seed of potassium carbonate to form a combustive and electrically conductive mixture which is burned in a combustion chamber. The burned combustion mixture is passed through a MHD generator to generate electrical energy. The burned combustion mixture is passed through a diffuser to restore the mixture approximately to atmospheric pressure, leaving a spent combustion mixture which is used to heat oxygen from an air separation plant and recycled carbon dioxide for combustion in a high temperature oxygen preheater and for heating water/steam for producing superheated steam. Relatively pure carbon dioxide is separated from the spent combustion mixture for further purification or for exhaust, while the remainder of the carbon dioxide is recycled from the spent combustion mixture to a carbon dioxide purification plant for removal of water and any nitrous oxides present, leaving a greater than 98% pure carbon dioxide. A portion of the greater then 98% pure carbon dioxide stream is recovered and the remainder is recycled to combine with the oxygen for preheating and combination with the fossil fuel to form a combustion mixture.

  6. Development, testing, and application of quantitative oxygenation imaging from magnetic susceptibility by MRI

    E-Print Network [OSTI]

    Fan, Audrey Peiwen

    2014-01-01

    The healthy brain consumes 20% of total oxygen used by the body under normal conditions. Continuous oxygen delivery to neural tissue is needed to maintain normal brain function and viability. Reliable measurements of brain ...

  7. In Situ Ambient Pressure X-ray Photoelectron Spectroscopy Studies of Lithium-Oxygen Redox Reactions

    E-Print Network [OSTI]

    Lu, Yi-chun

    The lack of fundamental understanding of the oxygen reduction and oxygen evolution in nonaqueous electrolytes significantly hinders the development of rechargeable lithium-air batteries. Here we employ a solid-state ...

  8. Electronic structure of perovskite oxide surfaces at elevated temperatures and its correlation with oxygen reduction reactivity

    E-Print Network [OSTI]

    Chen, Yan, Ph. D. Massachusetts Institute of Technology

    2014-01-01

    The objective is to understand the origin of the local oxygen reduction reaction (ORR) activity on the basis of the local electronic structure at the surface of transition metal oxides at elevated temperatures and in oxygen ...

  9. Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two;2 Abstract The size distribution of polycyclic aromatic hydrocarbons (PAHs) and PAH derivatives of compounds. Keywords: Polycyclic aromatic hydrocarbons; Nitrated polycyclic aromatic hydrocarbons; Oxygenated

  10. Direct Electrolysis of Molten Lunar Regolith for the Production of Oxygen and Metals on the Moon

    E-Print Network [OSTI]

    Sirk, Aislinn H.

    The feasibility of producing oxygen by direct electrolysis of the molten lunar regolith at 1600 C was investigated and the generation of usable oxygen gas at the anode and concomitant production of iron and silicon at the ...

  11. A finite difference model for predicting sediment oxygen demand in streams 

    E-Print Network [OSTI]

    Charbonnet, Danielle Andrea

    2003-01-01

    Sediment oxygen demand (SOD) is a significant part of the dissolved oxygen budget in waterways, comprising up to 50% in some systems. It, therefore, has the potential of having a significant impact on the environment. ...

  12. Phase-based regional oxygen metabolism in magnetic resonance imaging at high field

    E-Print Network [OSTI]

    Fan, Audrey Peiwen

    2010-01-01

    Venous oxygen saturation (Yv) in cerebral veins and the cerebral metabolic rate of oxygen (CMRO?) are important indicators for brain function and disease. Phase-susceptibility measurements in magnetic resonance imaging ...

  13. NUCLEAR PLANT OPERATIONS AND

    E-Print Network [OSTI]

    Pázsit, Imre

    NUCLEAR PLANT OPERATIONS AND CONTROL KEYWORDS: neutron flux, cur- rent noise, vibration diagnostics, localization algorithm LOCALIZATION OF A VIBRATING CONTROL ROD PIN IN PRESSURIZED WATER REACTORS USING. The possibility of the localization of a vibrating control rod pin in a pressurized water reactor control assembly

  14. Mechanisms in Plant Development

    SciTech Connect (OSTI)

    Hake, Sarah

    2013-08-21

    This meeting has been held every other year for the past twenty-two years and is the only regularly held meeting focused specifically on plant development. Topics covered included: patterning in developing tissues; short and long distance signaling; differentiation of cell types; the role of epigenetics in development; evolution; growth.

  15. Effects of oxygenate concentration on species mole fractions in premixed n-heptane flames

    E-Print Network [OSTI]

    Senkan, Selim M.

    -heptane/oxygenate mixtures were 2.7 and 3.4. Three different fuel oxygenates (i.e. MTBE, methanol, and ethanol) were tested in these emissions is the improvement in motor vehicle fuel properties. Fuel oxygenates were first used as an octane.e. oxygenates) such as alcohols (e.g. methanol, ethanol, and tertiary butyl alcohol) and ethers (e.g. methyl

  16. Solid Oxide Fuel Cell Cathodes. Unraveling the Relationship Between Structure, Surface Chemistry and Oxygen Reduction

    SciTech Connect (OSTI)

    Gopalan, Srikanth

    2013-03-31

    In this work we have considered oxygen reduction reaction on LSM and LSCF cathode materials. In particular we have used various spectroscopic techniques to explore the surface composition, transition metal oxidation state, and the bonding environment of oxygen to understand the changes that occur to the surface during the oxygen reduction process. In a parallel study we have employed patterned cathodes of both LSM and LSCF cathodes to extract transport and kinetic parameters associated with the oxygen reduction process.

  17. Top 10 plant pathogenic bacteria in molecular plant pathology.

    E-Print Network [OSTI]

    2012-01-01

    Foster, G.D. (2012) The top 10 fungal pathogens in molecularBLACKWELL PUBLISHING LTD Top 10 plant pathogenic bacteriaC. and Foster, G.D. (2011) Top 10 plant viruses in molecular

  18. Bimetallic Fe-Ni Oxygen Carriers for Chemical Looping Combustion

    SciTech Connect (OSTI)

    Bhavsar, Saurabh; Veser, Goetz

    2013-11-06

    The relative abundance, low cost, and low toxicity of iron make Fe-based oxygen carriers of great interest for chemical looping combustion (CLC), an emerging technology for clean and efficient combustion of fossil and renewable fuels. However, Fe also shows much lower reactivity than other metals (such as Ni and Cu). Here, we demonstrate strong improvement of Fe-based carriers by alloying the metal phase with Ni. Through a combination of carrier synthesis and characterization with thermogravimetric and fixed-bed reactor studies, we demonstrate that the addition of Ni results in a significant enhancement in activity as well as an increase in selectivity for total oxidation. Furthermore, comparing alumina and ceria as support materials highlights the fact that reducible supports can result in a strong increase in oxygen carrier utilization.

  19. Simultaneous analysis of oxygenated and nitrated polycylic aromatic hydrocarbons on standard reference material 1649a (urban dust) and

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Simultaneous analysis of oxygenated and nitrated polycylic aromatic hydrocarbons on standard nitrated polycylic aromatic hydrocarbons (NPAHs) and 9 oxygenated polycylic aromatic hydrocarbons (OPAHs aromatic hydrocarbons; Nitrated polycyclic aromatic hydrocarbons; Oxygenated polycyclic aromatic

  20. Beryllium, Lithium and Oxygen Abundances in F-type Stars

    E-Print Network [OSTI]

    R. J. Garcia Lopez; M. C. Dominguez Herrera; M. R. Perez de Taoro; C. Casares; J. L. Rasilla; R. Rebolo; C. Allende Prieto

    1997-10-07

    Beryllium and oxygen abundances have been derived in a sample of F-type field stars for which lithium abundances had been measured previously, with the aim of obtaining observational constraints to discriminate between the different mixing mechanisms proposed. Mixing associated with the transport of angular momentum in the stellar interior and internal gravity waves within the framework of rotating evolutionary models, appear to be promising ways to explain the observations.

  1. Diurnal patterns of denitrification, oxygen consumption and nitrous oxide production in rivers measured

    E-Print Network [OSTI]

    Seitzinger, Sybil

    Diurnal patterns of denitrification, oxygen consumption and nitrous oxide production in rivers Dame, Notre Dame, IN, U.S.A. SUMMARY 1. Denitrification, net oxygen consumption and net nitrous oxide. Denitrification, oxygen consumption and N2O flux were measured based on net changes in dissolved gas

  2. Oxygen production by molten alkali metal salts using multiple absorption-desorption cycles

    DOE Patents [OSTI]

    Cassano, A.A.

    1985-07-02

    A continuous chemical air separation is performed wherein oxygen is recovered with a molten alkali metal salt oxygen acceptor in a series of absorption zones which are connected to a plurality of desorption zones operated in separate parallel cycles with the absorption zones. A greater recovery of high pressure oxygen is achieved at reduced power requirements and capital costs. 3 figs.

  3. Explosion Hazard from a Propellant-Tank Breach in Liquid Hydrogen-Oxygen Rockets

    E-Print Network [OSTI]

    Muratov, Cyrill

    Explosion Hazard from a Propellant-Tank Breach in Liquid Hydrogen-Oxygen Rockets Viatcheslav Osipov liquid hydrogen-oxygen rockets during launch accidents is presented.The assessmentis based on the analysis of the data of purposefulrupture experiments with liquid oxygen and hydrogen tanks

  4. Faunal responses to oxygen gradients on the Pakistan margin: A comparison of foraminiferans, macrofauna and megafauna

    E-Print Network [OSTI]

    Levin, Lisa

    Faunal responses to oxygen gradients on the Pakistan margin: A comparison of foraminiferans Oxygen minimum zone Benthos Arabian Sea Biodiversity Deep sea a b s t r a c t The Pakistan Margin where oxygen levels were lowest. The rarity of larger animals between 300 and 700 m on the Pakistan

  5. The Role of Silicon Interstitials in the Formation of Boron-Oxygen Defects in Crystalline Silicon

    E-Print Network [OSTI]

    The Role of Silicon Interstitials in the Formation of Boron-Oxygen Defects in Crystalline Silicon@ise.fhg.de Keywords: crystalline silicon, Czochralski, boron-oxygen defect, silicon interstitial Abstract. Oxygen-rich crystalline silicon materials doped with boron are plagued by the presence of a well-known carrier

  6. Supplemental Oxygen and Mountaineer Death Rates on Everest and K2

    E-Print Network [OSTI]

    Huey, Raymond B.

    Supplemental Oxygen and Mountaineer Death Rates on Everest and K2 To the Editor: The use of supplemental oxygen by Hima- layan mountaineers has been debated for more than 8 de- cades.1 Although sometimes- veal an impact of supplemental oxygen on survival because de- scending mountaineers are often near

  7. Oxygen production by molten alkali metal salts using multiple absorption-desorption cycles

    DOE Patents [OSTI]

    Cassano, Anthony A. (Allentown, PA)

    1985-01-01

    A continuous chemical air separation is performed wherein oxygen is recovered with a molten alkali metal salt oxygen acceptor in a series of absorption zones which are connected to a plurality of desorption zones operated in separate parallel cycles with the absorption zones. A greater recovery of high pressure oxygen is achieved at reduced power requirements and capital costs.

  8. Wireless Harsh-Environment Oxygen Sensors D.W. Greve,1,2

    E-Print Network [OSTI]

    Greve, David.W.

    pollution. In oxy-fuel combustion of coal, separated oxygen is used so that the exhaust is nearly pure. INTRODUCTION Oxygen sensors are used in many combustion processes is order to improve efficiency and reduce the development of wireless oxygen sensors suitable for placement in the harsh environment of the combustion

  9. Kinetic fractionation of carbon and oxygen isotopes during hydration of carbon dioxide

    E-Print Network [OSTI]

    Zeebe, Richard E.

    Kinetic fractionation of carbon and oxygen isotopes during hydration of carbon dioxide Richard E the inorganic hydration of carbon dioxide (CO2) in aqueous solution cause reduced stable carbon and oxygen of the carbon and oxygen kinetic isotope fractionation (KIF) during hydration of CO2. Here I use transition

  10. Oxygen production and carbon sequestration in an upwelling coastal Burke Hales,1

    E-Print Network [OSTI]

    Oxygen production and carbon sequestration in an upwelling coastal margin Burke Hales,1 Lee Karp), Oxygen production and carbon sequestration in an upwelling coastal margin, Global Biogeochem. Cycles, 20 of particulate organic carbon (POC) and dissolved O2 during the upwelling season off the Oregon coast. Oxygen

  11. Doped Graphene as a Material for Oxygen Reduction Reaction in Hydrogen Fuel Cells: A Computational Study

    E-Print Network [OSTI]

    Krasheninnikov, Arkady V.

    Doped Graphene as a Material for Oxygen Reduction Reaction in Hydrogen Fuel Cells: A Computational fuel cells for oxygen reduction at the cathode. In an attempt to find a cheap yet efficient catalyst in graphene are promising candidates for the use in fuel cell cathodes for oxygen reduction reaction (ORR). We

  12. Degradation of Staphylococcus aureus bacteria by neutral oxygen atoms

    SciTech Connect (OSTI)

    Cvelbar, U.; Mozetic, M. [Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana (Slovenia); Hauptman, N.; Klanjsek-Gunde, M. [National Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana (Slovenia)

    2009-11-15

    The degradation of Staphylococcus aureus bacteria during treatment with neutral oxygen atoms was monitored by scanning electron microscopy. Experiments were performed in an afterglow chamber made from borosilicate glass. The source of oxygen atoms was remote inductively coupled radiofrequency oxygen plasma. The density of atoms at the samples was 8x10{sup 20} m{sup -3}. The treatment was performed at room temperature. The first effect was the removal of dried capsule. Capsule on exposed parts of bacteria was removed after receiving the dose of 6x10{sup 23} at./m{sup 2}, while the parts of capsule filling the gaps between bacteria were removed after receiving the dose of 2.4x10{sup 24} m{sup -2}. After removing the capsule, degradation continued as etching of bacterial cell wall. The etching was rather nonuniform as holes with diameter of several 10 nm were observed. The cell wall was removed after receiving the dose of about 7x10{sup 24} m{sup -2}. The etching probabilities were about 2x10{sup -5} for the capsule and 2x10{sup -6} for the cell wall. The results were explained by different compositions of capsule and the cell wall.

  13. The solar oxygen crisis: Probably not the last word

    E-Print Network [OSTI]

    H. Socas-Navarro A. A. Norton

    2007-03-26

    In this work we present support for recent claims that advocate a downward revision of the solar oxygen abundance. Our analysis employs spatially-resolved spectro-polarimetric observations including the \\FeI lines at 6302 \\AA and the \\OI infrared triplet around 7774 \\AA in the quiet Sun. We used the \\FeI lines to reconstruct the three-dimensional thermal and magnetic structure of the atmosphere. The simultaneous \\OI observations were then employed to determine the abundance of oxygen at each pixel, using both LTE and non-LTE (NLTE) approaches to the radiative transfer. In this manner, we obtain values of \\lgEO=8.63 (NLTE) and 8.93 (LTE) dex. We find an unsettling fluctuation of the oxygen abundance over the field of view. This is likely an artifact indicating that, even with this relatively refined strategy, important physical ingredients are still missing in the picture. By examining the spatial distribution of the abundance, we estimate realistic confidence limits of approximately 0.1 dex.

  14. Production of virus resistant plants

    DOE Patents [OSTI]

    Dougherty, William G. (Philomath, OR); Lindbo, John A. (Kent, WA)

    1996-01-01

    A method of suppressing virus gene expression in plants using untranslatable plus sense RNA is disclosed. The method is useful for the production of plants that are resistant to virus infection.

  15. Louisiana Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Louisiana nuclear power plants, summer capacity and net generation, 2010" "Plant NameTotal Reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear...

  16. Production of virus resistant plants

    DOE Patents [OSTI]

    Dougherty, W.G.; Lindbo, J.A.

    1996-12-10

    A method of suppressing virus gene expression in plants using untranslatable plus sense RNA is disclosed. The method is useful for the production of plants that are resistant to virus infection. 9 figs.

  17. Gene encoding plant asparagine synthetase

    DOE Patents [OSTI]

    Coruzzi, Gloria M. (New York, NY); Tsai, Fong-Ying (New York, NY)

    1993-10-26

    The identification and cloning of the gene(s) for plant asparagine synthetase (AS), an important enzyme involved in the formation of asparagine, a major nitrogen transport compound of higher plants is described. Expression vectors constructed with the AS coding sequence may be utilized to produce plant AS; to engineer herbicide resistant plants, salt/drought tolerant plants or pathogen resistant plants; as a dominant selectable marker; or to select for novel herbicides or compounds useful as agents that synchronize plant cells in culture. The promoter for plant AS, which directs high levels of gene expression and is induced in an organ specific manner and by darkness, is also described. The AS promoter may be used to direct the expression of heterologous coding sequences in appropriate hosts.

  18. Getting Inside Plants | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ability to use additional CO2, how plants pass on additional CO2 to bacteria in the soil (carbon sequestration), and in what ways potential biofuel-producing plants can be...

  19. Application of Oxygen Trim Control to Small Packaged Boilers 

    E-Print Network [OSTI]

    Nelson, R. L.

    1984-01-01

    Small packaged boilers are used to generate steam or hot water for industrial, commercial and institutional power plants. Due to their small size and relatively small fuel capacity, they have not received the energy saving attention that larger...

  20. Independent Oversight Evaluation, Pantex Plant - November 2000...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Evaluation, Pantex Plant - November 2000 Independent Oversight Evaluation, Pantex Plant - November 2000 November 2000 Evaluation of the Pantex Plant Emergency Response Exercise...

  1. Fate of Radionuclides in Wastewater Treatment Plants

    E-Print Network [OSTI]

    Shabani Samgh Abadi, Farzaneh

    2013-01-01

    21 3. NUCLEAR POWER PLANTS……………………………………………….. 23 3.1-25 3.2- WASTES FROM NUCLEAR POWER PLANTS………………………… 28 4.radionuclides 3. Nuclear Power Plants, which includes some

  2. Fate of Radionuclides in Wastewater Treatment Plants

    E-Print Network [OSTI]

    Shabani Samgh Abadi, Farzaneh

    2013-01-01

    concerns about nuclear power plants safety after the Threedoubts regarding nuclear power plants safety. 3.1- Nuclearof nuclear power plants in order to meet safety requirements

  3. Method and apparatus for producing oxygen and nitrogen and membrane therefor

    DOE Patents [OSTI]

    Roman, I.C.; Baker, R.W.

    1985-09-17

    Process and apparatus for the separation and purification of oxygen and nitrogen as well as a novel membrane useful therein are disclosed. The process utilizes novel facilitated transport membranes to selectively transport oxygen from one gaseous stream to another, leaving nitrogen as a byproduct. In the method, an oxygen carrier capable of reversibly binding molecular oxygen is dissolved in a polar organic membrane which separates a gaseous feed stream such as atmospheric air and a gaseous product stream. The feed stream is maintained at a sufficiently high oxygen pressure to keep the oxygen carrier in its oxygenated form at the interface of the feed stream with the membrane, while the product stream is maintained at a sufficiently low oxygen pressure to keep the carrier in its deoxygenated form at the interface of the product stream with the membrane. In an alternate mode of operation, the feed stream is maintained at a sufficiently low temperature and high oxygen pressure to keep the oxygen carrier in its oxygenated form at the interface of the feed stream with the membrane and the product stream is maintained at a sufficiently high temperature to keep the carrier in its deoxygenated form at the interface of the product stream with the membrane. Under such conditions, the carrier acts as a shuttle, picking up oxygen at the feed side of the membrane, diffusing across the membrane as the oxygenated complex, releasing oxygen to the product stream, and then diffusing back to the feed side to repeat the process. Exceptionally and unexpectedly high O[sub 2]/N[sub 2] selectivity, on the order of 10 to 30, is obtained, as well as exceptionally high oxygen permeability, on the order of 6 to 15 [times] 10[sup [minus]8] cm[sup 3]-cm/cm[sup 2]-sec-cmHg, as well as a long membrane life of in excess of 3 months, making the process commercially feasible. 2 figs.

  4. US prep plant census 2008

    SciTech Connect (OSTI)

    Fiscor, S.

    2008-10-15

    Each year Coal Age conducts a fairly comprehensive survey of the industry to produce the US coal preparation plant survey. This year's survey shows how many mergers and acquisitions have given coal operators more coal washing capacity. The plants are tabulated by state, giving basic details including company owner, plant name, raw feed, product ash %, quality, type of plant builder and year built. 1 tab., 1 photo.

  5. Regulating nutrient allocation in plants

    DOE Patents [OSTI]

    Udvardi, Michael; Yang, Jiading; Worley, Eric

    2014-12-09

    The invention provides coding and promoter sequences for a VS-1 and AP-2 gene, which affects the developmental process of senescence in plants. Vectors, transgenic plants, seeds, and host cells comprising heterologous VS-1 and AP-2 genes are also provided. Additionally provided are methods of altering nutrient allocation and composition in a plant using the VS-1 and AP-2 genes.

  6. Plant Microbiology Lab SYLLABUS 2014

    E-Print Network [OSTI]

    Brown, Sally

    of beneficial microorganisms on plants. Assays will include colonization of the plants, N stress alleviation for sequencing Mon Mar 3 Measure seedlings (5 wk data). Other plant phys expts? Early in the week: your sequencing results will be emailed to you Fri Mar 7 Lab write-up #2 on Strai

  7. North City Water Reclamation Plant

    E-Print Network [OSTI]

    Prevedouros, Panos D.

    -Site Cogeneration Methane Power Plant Methane piped in from: Miramar LandfillMiramar Landfill Metropolitan BiosolidsNorth City Water Reclamation Plant Maja Caroee Diana Lee Niko Salvador #12;What is Water% for plant operation 25% sold to local power grid #12;Technical Issues & Innovations COMNET Clean water

  8. Lattice Distortions and Oxygen Vacancies Produced in Au+-Irradiated Nanocrystalline Cubic Zirconia

    SciTech Connect (OSTI)

    Edmondson, P. D.; Weber, William J.; Namavar, Fereydoon; Zhang, Yanwen

    2011-07-13

    The oxygen ion conductivity, attributed to an oxygen vacancy mechanism, of yttria-stabilized zirconia membranes used in solid oxide fuel cells is restricted due to trapping limitations. In this work, a high concentration of oxygen vacancies has been deliberately introduced into nanocrystalline stabilizer-free zirconia through ion-irradiation. Oxygen vacancies with different charge states can be produced by varying irradiation temperatures. Due to the reduced trapping sites and high oxygen vacancy concentration, this work suggests that the efficiency of solid oxide fuel cells can be improved.

  9. Synthesis of oxygenate products for high volume fuels applications. Quarterly technical progress report, November 1, 1994--January 31, 1995

    SciTech Connect (OSTI)

    1995-03-08

    The objective of this project is to develop high yield syntheses of oxygenate products that are liquid at room temperature using as starting materials dimethy ether (DME) or methanol. The identified products include: Dimethyl Carbonate (DMC), 1,1-Dimethoxyethane (DMOE), C{sub 2}{sup +} Alcohols/Ethers (C{sub 2}AE). The technical strategy is outlined below: (A) Synthesis of DMC via oxidative carbonylation of DME instead of methanol. Since this synthesis would not co-produce water as a byproduct, there is a potential for very high DME conversions in contrast to the low (ca 20%) conversions obtained in conventional plants. Technical emphasis will be placed on development of a supported copper catalyst with a capability for cleavage of DME into its chemisorbed organic moieties. (B) Synthesis of 1,1-dimethoxymethane (DMOE) from acetylene/CO/H{sub 2} process streams obtained from commercial methane oxidative pyrolysis processes. In the overall processing scheme the syngas would be converted to DME. The wet acetylene stream would be partially condensed to retain an equivalent of water and then condensed with DME to produce EMOE. (C) Direct conversion of DME or DME/methanol to ethanol/propanol or their methyl ethers. Under the influence of functionalized alcohol condensation catalysts developed exclusively at Amoco it should be possible to achieve direct conversion of dimethyl ether (or methanol) to ethanol/propanol and/or the methyl ethers of these alcohols. Although this reaction is not currently known, a combination of key catalyst components from identified systems should result in a DME conversion catalyst to C{sub 2}+ oxygenates. (D) Reaction of DME or acetylene with synthesis gas (CO/H{sub 2}) or methanol. A variety of catalysts will be tested for conversion of acetylene/CO/H{sub 2} or acetylene/methanol to propylene and conversion of DME/CO/H{sub 2} or DME/methanol to dimenthyoxymethane (DMM) and/or other oxygenates.

  10. Grasses and Forage Plants

    E-Print Network [OSTI]

    Pittuck, B. C.

    1898-01-01

    State. A large number of the grasses, including many of the common culti? vated clovers and legumes, and many rare hay plants, on our experi? mental plots during 1897, were gathered and supplied by special agents of the United States Agricultural...), Trifolium hybridum (Alsike Clover), Large Red Clover, Trifolium repens (White Dutch Clover), suffered from the drouth and sun, but have made better growth at this place than during previous years. SPOROBOLUS. 8. wrighti*?Perennial. Germinated April 2...

  11. Oxygen transport membrane system and method for transferring heat to catalytic/process reactors

    DOE Patents [OSTI]

    Kelly, Sean M; Kromer, Brian R; Litwin, Michael M; Rosen, Lee J; Christie, Gervase Maxwell; Wilson, Jamie R; Kosowski, Lawrence W; Robinson, Charles

    2014-01-07

    A method and apparatus for producing heat used in a synthesis gas production is provided. The disclosed method and apparatus include a plurality of tubular oxygen transport membrane elements adapted to separate oxygen from an oxygen containing stream contacting the retentate side of the membrane elements. The permeated oxygen is combusted with a hydrogen containing synthesis gas stream contacting the permeate side of the tubular oxygen transport membrane elements thereby generating a reaction product stream and radiant heat. The present method and apparatus also includes at least one catalytic reactor containing a catalyst to promote the stream reforming reaction wherein the catalytic reactor is surrounded by the plurality of tubular oxygen transport membrane elements. The view factor between the catalytic reactor and the plurality of tubular oxygen transport membrane elements radiating heat to the catalytic reactor is greater than or equal to 0.5.

  12. Effect of surface strain on oxygen adsorption on Zr (0001) surface

    SciTech Connect (OSTI)

    Wang, Xing [Univ. of Wisconsin-Madison, Madison, WI (United States). Dept. of Engineering Physics; Khafizov, Marat [Idaho National Laboratory (INL), Idaho Falls, ID (United States); Szlufarska, Izabela [Univ. of Wisconsin-Madison, Madison, WI (United States). Dept. of Engineering Physics; Univ. of Wisconsin-Madison, Madison, WI (United States). Dept. of Materials Science and Engineering

    2014-02-01

    The effect of surface strain on oxygen adsorption on Zr (0 0 0 1) surface is investigated by density functional theory (DFT) calculations. It is demonstrated that both surface strain and interactions between oxygen adsorbates influence the adsorption process. Oxygen binding to zirconium becomes stronger as the strain changes from compressive to tensile. When oxygen coverage is low and the oxygen interactions are negligible, surface face-centered cubic sites are the most stable for O binding. At high coverage and under compression, octahedral sites between second and third Zr layers become most favorable because the interactions between adsorbates are weakened by positive charge screening. Calculations with both single-layer adsorption model and multiple-layer adsorption model demonstrate that compressive strain at the Zr/oxide interface will provide a thermodynamic driving force for oxygen to incorporate from the surface into the bulk of Zr, while binding oxygen to the Zr surface will be easier when tensile strain is applied.

  13. Pinellas Plant Environmental Baseline Report

    SciTech Connect (OSTI)

    Not Available

    1997-06-01

    The Pinellas Plant has been part of the Department of Energy`s (DOE) nuclear weapons complex since the plant opened in 1957. In March 1995, the DOE sold the Pinellas Plant to the Pinellas County Industry Council (PCIC). DOE has leased back a large portion of the plant site to facilitate transition to alternate use and safe shutdown. The current mission is to achieve a safe transition of the facility from defense production and prepare the site for alternative uses as a community resource for economic development. Toward that effort, the Pinellas Plant Environmental Baseline Report (EBR) discusses the current and past environmental conditions of the plant site. Information for the EBR is obtained from plant records. Historical process and chemical usage information for each area is reviewed during area characterizations.

  14. Oxygen vacancy ordering within anion-deficient Ceria

    SciTech Connect (OSTI)

    Hull, S.; Norberg, S.T.; Ahmed, I.; Eriksson, S.G.; Marrocchelli, D.; Madden, P.A.

    2009-10-15

    The structural properties of anion deficient ceria, CeO{sub 2-{delta}}, have been studied as a function of oxygen partial pressure, p(O{sub 2}), over the range 0>=log{sub 10p}(O{sub 2})>=-18.9 at 1273(2) K using the neutron powder diffraction technique. Rietveld refinement of the diffraction data collected on decreasing p(O{sub 2}) showed increases in the cubic lattice parameter, a, the oxygen nonstoichiometry, delta, and the isotropic thermal vibration parameters, u{sub Ce} and u{sub O}, starting at log{sub 10p}(O{sub 2}){approx}-11. The increases are continuous, but show a distinct kink at log{sub 10p}(O{sub 2}){approx}-14.5. Analysis of the total scattering (Bragg plus diffuse components) using reverse Monte Carlo (RMC) modelling indicates that the O{sup 2-} vacancies preferentially align as pairs in the <111> cubic directions as the degree of nonstoichiometry increases. This behaviour is discussed with reference to the chemical crystallography of the CeO{sub 2}-Ce{sub 2}O{sub 3} system at ambient temperature and, in particular, to the nature of the long-range ordering of O{sup 2-} vacancies within the crystal structure of Ce{sub 7}O{sub 12}. - Graphical abstract: Partial radial distribution function for oxygen vacancies within CeO{sub 1.710} at 1273 K (solid line) showing the increased tendency for local ordering in <111> directions compared to a random distribution (dashed line).

  15. HYDROCARBONS FROM PLANTS: ANALYTICAL METHODS AND OBSERVATIONS

    E-Print Network [OSTI]

    Calvin, Melvin

    2013-01-01

    the green plant to capture and store solar energy, is Brazilsolar energy capturing machine we know, namely, the green plant,

  16. Hydrogen and oxygen concentrations in IXCs: A compilation

    SciTech Connect (OSTI)

    Liljegren, L.M.; Terrones, G.T.; Melethil, P.K.

    1996-06-01

    This paper contains four reports and two internal letters that address the estimation of hydrogen and oxygen concentrations in ion exchange columns that treat the water of the K-East and K-West Basins at Hanford. The concern is the flammability of this mixture of gases and planning for safe transport during decommissioning. A transient will occur when the hydrogen filter is temporarily blocked by a sandbag. Analyses are provided for steady-state, transients, and for both wet and dry resins.

  17. Recent advances in the kinetics of oxygen reduction

    SciTech Connect (OSTI)

    Adzic, R.

    1996-07-01

    Oxygen reduction is considered an important electrocatalytic reaction; the most notable need remains improvement of the catalytic activity of existing metal electrocatalysts and development of new ones. A review is given of new advances in the understanding of reaction kinetics and improvements of the electrocatalytic properties of some surfaces, with focus on recent studies of relationship of the surface properties to its activity and reaction kinetics. The urgent need is to improve catalytic activity of Pt and synthesize new, possibly non- noble metal catalysts. New experimental techniques for obtaining new level of information include various {ital in situ} spectroscopies and scanning probes, some involving synchrotron radiation. 138 refs, 18 figs, 2 tabs.

  18. COURSE INFORMATION Plant Diversity and Evolution

    E-Print Network [OSTI]

    Chen, Kuang-Yu

    and experimental tools used to understand plant diversity. 4. "Vocabulary" of plant description (see list list) 7. Distinctive features of land plant diversity 8. The history of land plants through time #12COURSE INFORMATION Fall 2009 Plant Diversity and Evolution (11:704:411) and Advanced Plant

  19. Propagation of Ornamental Plants

    E-Print Network [OSTI]

    DeWerth, A. F.

    1955-01-01

    . Whenever possible, sow the seed of most After the seed have germinated, place th~ Texas ornamentals in flats or pots than container where the seedlings will get an abw directly in the open ground. dance of light. If kept in a shady location, leg...!! weak plants will result. Be sure there are cracks or holes in the bot- tom of the flat or that the hole in the bottom - Water from below whenever the soil becomP of the flower pot is kept open to allow excess water to pass quickly out of the soil...

  20. Nuclear Plant Data Bank

    SciTech Connect (OSTI)

    Booker, C.P.; Turner, M.R.; Spore, J.W.

    1986-01-01

    The Nuclear Plant Data Bank (NPDB) is being developed at the Los Alamos National Laboratory to assist analysts in the rapid and accurate creation of input decks for reactor transient analysis. The NPDB will reduce the time and cost of the creation or modification of a typical input deck. This data bank will be an invaluable tool in the timely investigation of recent and ongoing nuclear reactor safety analysis. This paper discusses the status and plans for the NPDB development and describes its anticipated structure and capabilities.

  1. Propagation of Ornamental Plants

    E-Print Network [OSTI]

    DeWerth, A. F.

    1955-01-01

    '~ihtenecl with a fine mist spray of water, since an important factor in rooting cuttings is to keep the cuttings moist. There are many advantages in the use of mist by the home gardener. A cutting continues to lose water by transpiration after... it is removed from the parent plant. It is impossible for the cuttings to take up sufficient water to replace that lost by rapid transpiration until new roots are formed. The mist system prevents ex- cessive loss of water by the cutting. Maintain- ing...

  2. Better Buildings, Better Plants:

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p a l De p uBUSEnergy|| Department ofBuildings, Better Plants: AMO

  3. Gasification Plant Databases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journal Article)ForthcomingGENERALProblems I n QEstimatesPlant Databases

  4. Plants & Animals

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesseworkSURVEYI/OPerformancePi Day Pi Day Pi Day isPlanning forPlants &

  5. OXYGEN ISOTOPE MEASUREMENTS OF A RARE MURCHISON TYPE A CAI AND ITS RIM. J. E. P. , J. I. Simon2

    E-Print Network [OSTI]

    to oxygen isotope zoning profiles measured from CAIs in other chondrites. MUM-1 Petrography: The petrography

  6. Type Ia supernovae from exploding oxygen-neon white dwarfs

    E-Print Network [OSTI]

    Marquardt, Kai S; Ruiter, Ashley J; Seitenzahl, Ivo R; Ohlmann, Sebastian T; Kromer, Markus; Pakmor, Ruediger; Roepke, Friedrich K

    2015-01-01

    The progenitor problem of Type Ia supernovae (SNe Ia) is still unsolved. Most of these events are thought to be explosions of carbon-oxygen (CO) white dwarfs (WDs), but for many of the explosion scenarios, particularly those involving the externally triggered detonation of a sub-Chandrasekhar mass WD (sub-M Ch WD), there is also a possibility of having an oxygen-neon (ONe) WD as progenitor. We simulate detonations of ONe WDs and calculate synthetic observables from these models. The results are compared with detonations in CO WDs of similar mass and observational data of SNe Ia. We perform hydrodynamic explosion simulations of detonations in initially hydrostatic ONe WDs for a range of masses below the Chandrasekhar mass (M Ch), followed by detailed nucleosynthetic postprocessing with a 384-isotope nuclear reaction network. The results are used to calculate synthetic spectra and light curves, which are then compared with observations of SNe Ia. We also perform binary evolution calculations to determine the nu...

  7. Sputtering of Oxygen Ice by Low Energy Ions

    E-Print Network [OSTI]

    Muntean, E A; Field, T A; Fitzsimmons, A; Hunniford, C A; McCullough, R W

    2015-01-01

    Naturally occurring ices lie on both interstellar dust grains and on celestial objects, such as those in the outer solar system. These ices are continu- ously subjected to irradiation by ions from the solar wind and/or cosmic rays, which modify their surfaces. As a result, new molecular species may form which can be sputtered off into space or planetary atmospheres. We determined the experimental values of sputtering yields for irradiation of oxygen ice at 10 K by singly (He+, C+, N+, O+ and Ar+) and doubly (C2+, N2+ and O2+) charged ions with 4 keV kinetic energy. In these laboratory experiments, oxygen ice was deposited and irradiated by ions in an ultra high vacuum chamber at low temperature to simulate the environment of space. The number of molecules removed by sputtering was observed by measurement of the ice thickness using laser interferometry. Preliminary mass spectra were taken of sputtered species and of molecules formed in the ice by temperature programmed desorption (TPD). We find that the experi...

  8. Nickel-hydrogen battery with oxygen and electrolyte management features

    DOE Patents [OSTI]

    Sindorf, John F. (Pewaukee, WI)

    1991-10-22

    A nickel-hydrogen battery or cell having one or more pressure vessels containing hydrogen gas and a plurality of cell-modules therein. Each cell-module includes a configuration of cooperatively associated oxygen and electrolyte mangement and component alignment features. A cell-module having electrolyte includes a negative electrode, a positive electrode adapted to facilitate oxygen diffusion, a separator disposed between the positive and negative electrodes for separating them and holding electrolyte for ionic conductivity, an absorber engaging the surface of the positive electrode facing away from the separator for providing electrolyte to the positive electrode, and a pair of surface-channeled diffusion screens for enclosing the positive and negative electrodes, absorber, and separator and for maintaining proper alignment of these components. The screens, formed in the shape of a pocket by intermittently sealing the edges together along as many as three sides, permit hydrogen gas to diffuse therethrough to the negative electrodes, and prevent the edges of the separator from swelling. Electrolyte is contained in the cell-module, absorbhed by the electrodes, the separator and the absorber.

  9. Perspectives on plant vulnerabilities & other plant and containment improvements

    SciTech Connect (OSTI)

    LaChance, J.; Kolaczkowski, A.; Kahn, J. [and others

    1996-01-01

    The primary goal of the Individual Plant Examination (IPE) Program was for licensees to identify plant-unique vulnerabilities and actions to address these vulnerabilities. A review of these vulnerabilities and plant improvements that were identified in the IPEs was performed as part of the IPE Insights Program sponsored by the U.S. Nuclear Regulatory Commission (NRC). The purpose of this effort was to characterize the identified vulnerabilities and the impact of suggested plant improvements. No specific definition for {open_quotes}vulnerability{close_quotes} was provided in NRC Generic Letter 88-20 or in the subsequent NRC IPE submittal guidance documented in NUREG-1335. Thus licensees were left to use their own definitions. Only 20% of the plants explicitly stated that they had vulnerabilities. However, most licensees identified other plant improvements to address issues not explicitly classified as vulnerabilities, but pertaining to areas in which overall plant safety could potentially be increased. The various definitions of {open_quotes}vulnerability{close_quotes} used by the licensees, explicitly identified vulnerabilities, proposed plant improvements to address these vulnerabilities, and other plant improvements are summarized and discussed.

  10. Plant–herbivore interactions mediated by plant toxicity

    E-Print Network [OSTI]

    2008-03-25

    Dec 17, 2007 ... O. Box 249118, Coral Gables, FL 33124, United States. .... Per capital death rate of herbivore unrelated to plant toxicity. 2. Analysis of the ...

  11. The SONATRACH jumbo LPG plant

    SciTech Connect (OSTI)

    Ahmed Khodja, A.; Bennaceur, A.

    1988-01-01

    The authors aim is to give to the 17 TH world gas conference a general idea on SONATRACH LPG PLANT which is located in the ARZEW area. They develop this communication as follows: general presentation of LPG plant: During the communication, the author's will give the assistance all the information concerning the contractions the erection's date and the LPG PLANT process, start-up of the plant: In this chapter, the authors's will describe the start-up condition, the performance test result, the flexibility test result and the total mechanical achievement of the plant; operation by SONATRACH: After the success that obtained during the mechanical achievement and performance test, the contractor handed over the plant to SONATRACH.

  12. Plant Physiology: Manipulating Plant Growth with Solar Radiation Dennis Decoteau, Ph.D.

    E-Print Network [OSTI]

    Decoteau, Dennis R.

    Plant Physiology: Manipulating Plant Growth with Solar Radiation Dennis Decoteau, Ph.D. Department of light that surrounds the plant. Light ­ Radiant Energy All light is made up of energy. Light to plants (Villee, 1977). Plant Uses Of Radiant Energy And Plant "Vision" Plants utilize specialized pigments

  13. Oxygen Isotope Dynamics of Atmospheric Nitrate and Its Precursor Molecules

    E-Print Network [OSTI]

    Michalski, Greg

    processes, with anthropogenic emissions from coal burning power plants and automobiles dom- inating global.1007/978-3-642-10637-8_30, # Springer-Verlag Berlin Heidelberg 2011 613 #12;d17 O ¼ 0:52 d18 O (30.1) A plot of d17 O vs. d18 O (dual

  14. Origin of deep subgap states in amorphous indium gallium zinc oxide: Chemically disordered coordination of oxygen

    SciTech Connect (OSTI)

    Sallis, S.; Williams, D. S.; Butler, K. T.; Walsh, A.; Quackenbush, N. F.; Junda, M.; Podraza, N. J.; Fischer, D. A.; Woicik, J. C.; White, B. E.; Piper, L. F. J.

    2014-06-09

    The origin of the deep subgap states in amorphous indium gallium zinc oxide (a-IGZO), whether intrinsic to the amorphous structure or not, has serious implications for the development of p-type transparent amorphous oxide semiconductors. We report that the deep subgap feature in a-IGZO originates from local variations in the oxygen coordination and not from oxygen vacancies. This is shown by the positive correlation between oxygen composition and subgap intensity as observed with X-ray photoelectron spectroscopy. We also demonstrate that the subgap feature is not intrinsic to the amorphous phase because the deep subgap feature can be removed by low-temperature annealing in a reducing environment. Atomistic calculations of a-IGZO reveal that the subgap state originates from certain oxygen environments associated with the disorder. Specifically, the subgap states originate from oxygen environments with a lower coordination number and/or a larger metal-oxygen separation.

  15. Controlled temperature expansion in oxygen production by molten alkali metal salts

    DOE Patents [OSTI]

    Erickson, D.C.

    1985-06-04

    A continuous process is set forth for the production of oxygen from an oxygen containing gas stream, such as air, by contacting a feed gas stream with a molten solution of an oxygen acceptor to oxidize the acceptor and cyclically regenerating the oxidized acceptor by releasing oxygen from the acceptor wherein the oxygen-depleted gas stream from the contact zone is treated sequentially to temperature reduction by heat exchange against the feed stream so as to condense out entrained oxygen acceptor for recycle to the process, combustion of the gas stream with fuel to elevate its temperature and expansion of the combusted high temperature gas stream in a turbine to recover power. 1 fig.

  16. Better Buildings, Better Plants Program

    SciTech Connect (OSTI)

    2011-12-08

    The Better Buildings, Better Plants Program is part of a national leadership initiative calling on business leaders and others to create American jobs through energy efficiency.

  17. Power Plant Modeling and Simulation

    ScienceCinema (OSTI)

    None

    2010-01-08

    The National Energy Technology Laboratory's Office of Research and Development provides open source tools and expetise for modeling and simulating power plants and carbon sequestration technologies.

  18. MHD plant turn down considerations

    SciTech Connect (OSTI)

    Lineberry, J.T.; Chapman, J.N.

    1991-01-01

    The topic of part load operation of the MHD power plant is assessed. Current and future planned MHD research is reviewed in terms of addressing topping and bottoming cycle integration needs. The response of the MHD generator to turn up and down scenarios is reviewed. The concept of turning the MHD power to met changes in plant load is discussed. The need for new ideas and focused research to study MHD plant integration and problems of plant turn down and up is cited. 7 refs., 5 figs., 1 tab.

  19. Better Plants | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Partners and welcomed more than 20 manufacturers into the program at the World Energy Engineering Congress on October 2, 2014. Read more Better Plants Program Logo Leading...

  20. Nuclear Power Plant Design Project

    E-Print Network [OSTI]

    Nuclear Power Plant Design Project A Response to the Environmental and Economic Challenge Of Global) .................................................................... 14 4.4 High Temperature Gas Reactor

  1. Power Plant Modeling and Simulation

    SciTech Connect (OSTI)

    2008-07-21

    The National Energy Technology Laboratory's Office of Research and Development provides open source tools and expetise for modeling and simulating power plants and carbon sequestration technologies.

  2. Blast furnace injection of massive quantities of coal with enriched air or pure oxygen

    SciTech Connect (OSTI)

    Ponghis, N.; Dufresne, P.; Vidal, R.; Poos, A. (Center de Recherches Metallurgiques, Liege (Belgium))

    1993-01-01

    An extensive study of the phenomena associated with the blast furnace injection of massive quantities of coal is described. Trials with conventional lances or oxy-coal injectors and hot blast at different oxygen contents - up to 40% - or with cold pure oxygen were realized at coal to oxygen ratios corresponding to a range of 150 to 440 kg. Pilot scale rigs, empty or filled with coke, as well as industrial blast furnaces were utilized.

  3. Lattice distortions and oxygen vacancies produced in Au+ irradiated nano-crystalline cubic zirconia

    SciTech Connect (OSTI)

    Edmondson, Philip D; Weber, William J; Namavar, Fereydoon; Zhang, Yanwen

    2011-01-01

    The structural impact of oxygen vacancies in nanocrystalline cubic zirconia is investigated. A non-equilibrium number of oxygen vacancies in introduced to the lattice by ion irradiation. The lattice is observed to be initially compressed, undergoes a relaxation at 0.7 displacements per atom (dpa), and experiences a contraction before reaching a temperature dependent steady state value at above 7 dpa. The level of lattice distortion is related to the charge state of the accumulating oxygen vacancies.

  4. Planting and Mulching Trees and Shrubs Selecting healthy plants

    E-Print Network [OSTI]

    New Hampshire, University of

    Planting and Mulching Trees and Shrubs Selecting healthy plants Take a step back to examine swollen nodules at the container edge, rather than circling like in a plastic container. The nodules store with soil or mulch ­ ignore these and find the first permanent woody root growing radially out from

  5. Ownership Change, Incentives and Plant Efficiency: The Divestiture of U.S. Electric Generation Plants

    E-Print Network [OSTI]

    Bushnell, James B.; Wolfram, Catherine

    2005-01-01

    ciency of Electric Generating Plants: A Stochastic Frontierthe existing stock of electricity generating plants. Betweenover 300 electric generating plants in the US, accounting

  6. Master Plant List for Texas Range and Pasture Plant Identification Contests 

    E-Print Network [OSTI]

    Ragsdale, Bobby

    2000-05-03

    Entrants in range and pasture plant identification contests will find this reference useful. It includes explanations of plant characteristics and a master list of plants....

  7. Next Generation Geothermal Power Plants

    SciTech Connect (OSTI)

    Brugman, John; Hattar, Mai; Nichols, Kenneth; Esaki, Yuri

    1995-09-01

    A number of current and prospective power plant concepts were investigated to evaluate their potential to serve as the basis of the next generation geothermal power plant (NGGPP). The NGGPP has been envisaged as a power plant that would be more cost competitive (than current geothermal power plants) with fossil fuel power plants, would efficiently use resources and mitigate the risk of reservoir under-performance, and minimize or eliminate emission of pollutants and consumption of surface and ground water. Power plant concepts were analyzed using resource characteristics at ten different geothermal sites located in the western United States. Concepts were developed into viable power plant processes, capital costs were estimated and levelized busbar costs determined. Thus, the study results should be considered as useful indicators of the commercial viability of the various power plants concepts that were investigated. Broadly, the different power plant concepts that were analyzed in this study fall into the following categories: commercial binary and flash plants, advanced binary plants, advanced flash plants, flash/binary hybrid plants, and fossil/geothed hybrid plants. Commercial binary plants were evaluated using commercial isobutane as a working fluid; both air-cooling and water-cooling were considered. Advanced binary concepts included cycles using synchronous turbine-generators, cycles with metastable expansion, and cycles utilizing mixtures as working fluids. Dual flash steam plants were used as the model for the commercial flash cycle. The following advanced flash concepts were examined: dual flash with rotary separator turbine, dual flash with steam reheater, dual flash with hot water turbine, and subatmospheric flash. Both dual flash and binary cycles were combined with other cycles to develop a number of hybrid cycles: dual flash binary bottoming cycle, dual flash backpressure turbine binary cycle, dual flash gas turbine cycle, and binary gas turbine cycle. Results of this study indicate that dual flash type plants are preferred at resources with temperatures above 400 F. Closed loop (binary type) plants are preferred at resources with temperatures below 400 F. A rotary separator turbine upstream of a dual flash plant can be beneficial at Salton Sea, the hottest resource, or at high temperature resources where there is a significant variance in wellhead pressures from well to well. Full scale demonstration is required to verify cost and performance. Hot water turbines that recover energy from the spent brine in a dual flash cycle improve that cycle's brine efficiency. Prototype field tests of this technology have established its technical feasibility. If natural gas prices remain low, a combustion turbine/binary hybrid is an economic option for the lowest temperature sites. The use of mixed fluids appear to be an attractive low risk option. The synchronous turbine option as prepared by Barber-Nichols is attractive but requires a pilot test to prove cost and performance. Dual flash binary bottoming cycles appear promising provided that scaling of the brine/working fluid exchangers is controllable. Metastable expansion, reheater, Subatmospheric flash, dual flash backpressure turbine, and hot dry rock concepts do not seem to offer any cost advantage over the baseline technologies. If implemented, the next generation geothermal power plant concept may improve brine utilization but is unlikely to reduce the cost of power generation by much more than 10%. Colder resources will benefit more from the development of a next generation geothermal power plant than will hotter resources. All values presented in this study for plant cost and for busbar cost of power are relative numbers intended to allow an objective and meaningful comparison of technologies. The goal of this study is to assess various technologies on an common basis and, secondarily, to give an approximate idea of the current costs of the technologies at actual resource sites. Absolute costs at a given site will be determined by the specifics of a given pr

  8. Table 10. U.S. Refiner Oxygenated Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    AdministrationPetroleum Marketing Annual 1999 Table 10. U.S. Refiner Oxygenated Motor Gasoline Prices by Grade and Sales Type (Cents per Gallon Excluding Taxes) Year Month...

  9. Oxygen-resistant hydrogenases and methods for designing and making same

    DOE Patents [OSTI]

    King, Paul; Ghirardi, Maria Lucia; Seibert, Michael

    2014-03-04

    The invention provides oxygen-resistant iron-hydrogenases ([Fe]-hydrogenases) for use in the production of H.sub.2. Methods used in the design and engineering of the oxygen-resistant [Fe]-hydrogenases are disclosed, as are the methods of transforming and culturing appropriate host cells with the oxygen-resistant [Fe]-hydrogenases. Finally, the invention provides methods for utilizing the transformed, oxygen insensitive, host cells in the bulk production of H.sub.2 in a light catalyzed reaction having water as the reactant.

  10. Modeling and Control of High-Velocity Oxygen-Fuel (HVOF) Thermal Spray: A Tutorial Review

    E-Print Network [OSTI]

    Li, Mingheng; Christofides, Panagiotis D.

    2009-01-01

    Fluid Dynamics Analysis of a Wire- Feed, High-Velocity Oxygen Fuel (Fluid Dynamic Modeling of Gas Flow Charac- teristics in a High-Velocity Oxy-Fuel

  11. Oxygen-resistant hydrogenases and methods for designing and making same

    DOE Patents [OSTI]

    King, Paul (Golden, CO); Ghirardi, Maria L (Lakewood, CO); Seibert, Michael (Lakewood, CO)

    2009-03-10

    The invention provides oxygen- resistant iron-hydrogenases ([Fe]-hydrogenases) for use in the production of H2. Methods used in the design and engineering of the oxygen-resistant [Fe]-hydrogenases are disclosed, as are the methods of transforming and culturing appropriate host cells with the oxygen-resistant [Fe]-hydrogenases. Finally, the invention provides methods for utilizing the transformed, oxygen insensitive, host cells in the bulk production of H.sub.2 in a light catalyzed reaction having water as the reactant.

  12. Anomalous expansion of the copper-apical-oxygen distance in supercondu...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Anomalous expansion of the copper-apical-oxygen distance in superconducting cuprate bilayers Citation Details In-Document Search Title: Anomalous expansion of the...

  13. Webinar: Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique

    Broader source: Energy.gov [DOE]

    Video recording of the Fuel Cell Technologies Office webinar, Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique, originally presented on March 12, 2013.

  14. Low oxygen biomass-derived pyrolysis oils and methods for producing the same

    DOE Patents [OSTI]

    Marinangeli, Richard; Brandvold, Timothy A; Kocal, Joseph A

    2013-08-27

    Low oxygen biomass-derived pyrolysis oils and methods for producing them from carbonaceous biomass feedstock are provided. The carbonaceous biomass feedstock is pyrolyzed in the presence of a catalyst comprising base metal-based catalysts, noble metal-based catalysts, treated zeolitic catalysts, or combinations thereof to produce pyrolysis gases. During pyrolysis, the catalyst catalyzes a deoxygenation reaction whereby at least a portion of the oxygenated hydrocarbons in the pyrolysis gases are converted into hydrocarbons. The oxygen is removed as carbon oxides and water. A condensable portion (the vapors) of the pyrolysis gases is condensed to low oxygen biomass-derived pyrolysis oil.

  15. Processing Argo OXYGEN data at the DAC level Version 1.3

    E-Print Network [OSTI]

    Lherminier, Pascale

    that all countries deploying floats equipped with oxygen sensors document the data and metadata related............................................................................... 4 3.2 "SENSOR" metadata............................................................................. 14 4.2 "SENSOR" metadata

  16. Task Technical Plan for Studies of Oxygen Consumption in the Catalyzed Hydrolysis of Tetraphenylborate Ion

    SciTech Connect (OSTI)

    Fink, S.D.

    1996-12-20

    This document presents the plan for studies of how dissolved oxygen affects the catalytic decomposition of the tetraphenylborate ion in alkaline aqueous solution.

  17. Constraining bubble dynamics and mixing with dissolved gases: Implications for productivity measurements by oxygen mass balance

    E-Print Network [OSTI]

    Hamme, Roberta C

    2006-01-01

    Implications for productivity measurements by oxygen masszone. Because the productivity measurement in the mixedproductivity estimates from continuous O 2 /Ar ratio measurements

  18. Computer Simulation of Defects and Oxygen Transport in Yttria-Stabilized Zirconia

    SciTech Connect (OSTI)

    Devanathan, Ram; Weber, William J.; Singhal, Subhash C.; Gale, Julian D.

    2006-06-15

    We have used molecular dynamics simulations and energy minimization calculations to examine defect energetics and oxygen diffusion in yttria-stabilized zirconia (YSZ). Oxygen vacancies prefer to be second nearest neighbors to yttrium dopants. The oxygen diffusion coefficient shows a peak at 8 mole % yttria consistent with experimental findings. The activation energy for oxygen diffusion varies from 0.6 to 1.0 eV depending on the yttria content. The Y-Vo-Y complex with a binding energy of -0.85 eV may play an important role in any conductivity degradation of YSZ.

  19. Oxygen-Dependent Morphogenesis of Modern Clumped Photosynthetic Mats and Implications for the Archean Stromatolite Record

    E-Print Network [OSTI]

    Sim, Min Sub

    Some modern filamentous oxygenic photosynthetic bacteria (cyanobacteria) form macroscopic tufts, laminated cones and ridges that are very similar to some Archean and Proterozoic stromatolites. However, it remains unclear ...

  20. The effect of an evaporation suppressant upon the liquid film oxygen transfer coefficient 

    E-Print Network [OSTI]

    Amad, Mohamad Towfic

    1967-01-01

    by organisms in a lake and the quantity of oxygen diffusion through the air-water interface were determined and the results were verified by field measurements. It was shown that the oxygen uptake rate of organisms in a body of water can be measured... diffusion. 3. To derive an expression to predict the minimum dissolved oxygen concentration during the critical night period for a lake o" pond treated with "Aquasave". The ~sco e of this research has been to determine the oxygen transfer coefficient...

  1. Increased reactive oxygen species production during reductive stress: The roles of mitochondrial glutathione and thioredoxin reductases

    E-Print Network [OSTI]

    Korge, P; Calmettes, G; Weiss, JN

    2015-01-01

    hydrogen peroxide production as determined by the pyridinereactive oxygen production, J. Biol. Chem. 280 (2005) 25305–NADPH fuels superoxide production in the failing heart, J.

  2. Complexes of self-interstitials with oxygen atoms in Ge

    SciTech Connect (OSTI)

    Khirunenko, L. I.; Pomozov, Yu. V.; Sosnin, M. G.; Abrosimov, N. V.; Riemann, H.

    2014-02-21

    Interactions of germanium self-interstitials with interstitial oxygen atoms in Ge subjected to irradiation at ?80 K and subsequently to annealing have been studied. To distinguish the processes involving vacancies and self-interstitials the doping with tin was used. It was shown that absorption lines with maximum at 602, 674, 713 and 803 cm{sup ?1} are self-interstitials-related. Two lines at 602 and 674, which develop upon annealing in the temperature range 180–240 K, belong to IO complexes, while the bands at 713 and 803 cm{sup ?1}, which emerge after annealing at T>220 K, are associated with I{sub 2}O. It is argued that the annealing of IO occurs by two mechanisms: by dissociation and by diffusion.

  3. Orbital reconstruction in a self-assembled oxygen vacancy nanostructure

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jang, H.; Kerr, G.; Lim, J. S.; Yang, C. -H.; Kao, C. -C.; Lee, J. -S.

    2015-07-27

    We demonstrate the microscopic role of oxygen vacancies spatially confined within nanometer inter-spacing (about 1nm) in BiFeO?, using resonant soft X-ray scattering techniques and soft X-ray spectroscopy measurements. Such vacancy confinements and total number of vacancy are controlled by substitution of Ca²? for Bi³? cation. We found that by increasing the substitution, the in-plane orbital bands of Fe³? cations are reconstructed without any redox reaction. It leads to a reduction of the hopping between Fe atoms, forming a localized valence band, in particular Fe 3d-electronic structure, around the Fermi level. This band localization causes to decrease the conductivity of themore »doped BiFeO? system.« less

  4. Oxygen-stabilized zirconium-vanadium-iron alloy

    DOE Patents [OSTI]

    Mendelsohn, M.H.; Gruen, D.M.

    1981-06-16

    An oxygen stabilized intermetallic compound is described which has the formula (Zr/sub 1-x/Ti/sub x/)/sub 2-u/(V/sub 1-y/Fe/sub y/)O/sub z/ where x = 0.0 to 0.9, y = 0.01 to 0.9, z = 0.25 to 0.5 and u = 0 to 1. The compound is capable of reversibly sorbing hydrogen at temperatures from -196/sup 0/C to 200/sup 0/C at pressures down to 10/sup -6/ torr. The compound is suitable for use as a hydrogen getter in low pressure, high temperature applications such as magnetic confinement fusion devices.

  5. Lithium-Beryllium-Boron and Oxygen in the early Galaxy

    E-Print Network [OSTI]

    Elisabeth Vangioni-Flam; Michel Casse

    2000-11-24

    Oxygen is a much better evolutionary index than iron to follow the history of Lithium-Beryllium-Boron (LiBeB) since it is the main producer of these light elements at least in the early Galaxy. The O-Fe relation is crucial to the determination of the exact physical process responsible for the LiBeB production. Calculated nucleosynthetic yields of massive stars, estimates of the energy cost of Be production, and above all recent observations reported in this meeting seem to favor a mechanism in which fast nuclei enriched into He, C and O arising from supernovae are accelerated in superbubbles and fragment on H and He in the interstellar medium.

  6. Metallicity of the intergalactic medium using pixel statistics: IV. Oxygen

    E-Print Network [OSTI]

    Anthony Aguirre; Corey Dow-Hygelund; Joop Schaye; Tom Theuns

    2008-07-21

    We have studied the abundance of oxygen in the IGM by analyzing OVI, CIV, SiIV, and HI pixel optical depths derived from a set of high-quality VLT and Keck spectra of 17 QSOs at 2.1 ~ 0.2. Consistent results are obtained by similarly comparing OVI to HI or OVI to SiIV optical depth ratios to simulation values, and also by directly ionization-correcting OVI optical depths as function of HI optical depths into [O/H] as a function of density. Subdividing the sample reveals no evidence for evolution, but low- and high-density samples are inconsistent, suggesting either density-dependence of [O/C] or -- more likely -- prevalence of collisionally-ionized gas at high density.

  7. Refinery, petrochemical plant injuries decline

    SciTech Connect (OSTI)

    Not Available

    1994-07-25

    The National Petroleum Refiners Association (NPRA) reports a 7% reduction in workplace injury and illness incidence rates for refineries in 1993, and a 21% decrease for petrochemical plants. The report summarizes data from 135 of the 162 US member refineries, and 117 of the 172 US member petrochemical plants. This paper summarizes the report findings.

  8. Do Plants Sweat? Core Content

    E-Print Network [OSTI]

    Kessler, Bruce

    in the bright sun and others are grouped together and are regularly sprinkled with water. You begin to wonder plant distribution where you see this principle in action? -Can you predict the effect of seasons data/graph] Three plants are grown in the same greenhouse with the same air temperature, amount

  9. CONSTRUCTION OF NUCLEAR POWER PLANTS

    E-Print Network [OSTI]

    CONSTRUCTION OF NUCLEAR POWER PLANTS A Workshop on "NUCLEAR ENERGY RENAISSANCE" Addressing OF ST. LUCIE-2 at FLORIDA POWER & LIGHT COMPANY · Robert E. Uhrig 1974-1986 ­ Vice President, Nuclear IN CONSTRUCTION OF ST. LUCIE-2 #12;LESSONS LEARNED FROM St. Lucie-2 NUCLEAR POWER PLANTS CAN BE BUILT

  10. Generation of highly reactive oxygen species by co-adsorption of oxygen and water on metal-supported MgO(100) thinfilms

    E-Print Network [OSTI]

    Song, Zhenjun

    2015-01-01

    The formation of highly reactive oxygen species (ROS) on metal oxide surfaces have attracted considerable interest due to their diverse applications. In this work, we have performed densi-ty-functional theory calculations to investigate the co-adsorption of oxygen and water on ul-trathin MgO(100) films deposited on Mo(100) substrate. We reveal that the molecular oxygen can be stepwise decomposed completely with the assistance of water. Consequently, a series of highly ROS including superoxide, hydroperoxide, hydroxyl and single oxygen adatom are formed on Mo(100) supported MgO(100) thinfilms. The reaction barriers accompanied by the generation of ROS are reported, and the influence of the thickness of MgO(100) films is also discussed. The most promising routes to produce these fascinating species provide valuable information to understand the importance of synergistic effect, namely the substrate, the co-adorbed species, and the film thickness, in multiphase catalyst design.

  11. Modification of Gold Catalysis withModification of Gold Catalysis with Aluminum Phosphate for OxygenAluminum Phosphate for Oxygen--Reduction ReactionReduction Reaction

    E-Print Network [OSTI]

    Park, Byungwoo

    (PEMFC + DMFC) General MotorsPanasonic Power Source * PEMFC: proton exchange membrane fuel cell DMFC) H+ Oxygen or Air Ecat Hydrogen (PEMFC) (DMFC) Carbon Dioxide Water CatalystsCatalysts Membrane

  12. Overview of enrichment plant safeguards

    SciTech Connect (OSTI)

    Swindle, D.W. Jr.; Wheeler, L.E.

    1982-01-01

    The relationship of enrichment plant safeguards to US nonproliferation objectives and to the operation and management of enrichment facilities is reviewed. During the review, the major components of both domestic and international safeguards systems for enrichment plants are discussed. In discussing domestic safeguards systems, examples of the technology currently in use to support nuclear materials accountability are described including the measurement methods, procedures and equipment used for weighing, sampling, chemical and isotopic analyses and nondestructive assay techniques. Also discussed is how the information obtained as part of the nuclear material accountancy task is useful to enrichment plant operations. International material accountancy verification and containment/surveillance concepts for enrichment plants are discussed, and the technologies presently being developed for international safeguards in enrichment plants are identified and the current development status is reported.

  13. Graduate Programs in Plant Biology and

    E-Print Network [OSTI]

    Wildermuth, Mary C

    not re- biochemistry, cell and molecular biology (B22). pmb.berkeley.edu Plant&Microbial Biology #12;The to the environment will continue to fuel the expansion of plant research well into the future. The plant biology program focuses on contemporary ba- sic plant research, design of biotechnologies, and plant-microbe

  14. Native Plants and PollinatorsNative Plants and PollinatorsNative Plants and PollinatorsNative Plants and Pollinators of Loney Meadowof Loney Meadowof Loney Meadowof Loney Meadow

    E-Print Network [OSTI]

    Ishida, Yuko

    Native Plants and PollinatorsNative Plants and PollinatorsNative Plants and PollinatorsNative Plants and Pollinators of Loney Meadowof Loney Meadowof Loney Meadowof Loney Meadow A walk with Dr.footwear. No dogs please.footwear. No dogs please. For more information please call: Kathy Van Zuuk, PlantFor more

  15. NRES 725 PLANT PHYSIOLOGICAL ECOLOGY Spring 2006

    E-Print Network [OSTI]

    Nowak, Robert S.

    1 NRES 725 ­ PLANT PHYSIOLOGICAL ECOLOGY Spring 2006 Reading List ­ Water Balance of Plants I) Water Balance of Plants A) Water potential B) Soil, plant, air continuum C) Physiological control 1 Kramer & Boyer (95) pp 16-41 & 42-83 Kramer & Boyer (95) pp 201-256 *Steudle (01) Ann Rev Plant Phy Mol

  16. Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen K-edge Spectroscopy and Electronic Structure Theory

    SciTech Connect (OSTI)

    Minasian, Stefan G.; Keith, Jason M.; Batista, Enrique R.; Boland, Kevin S.; Bradley, Joseph A.; Daly, Scott R.; Kozimor, Stosh A.; Lukens, Wayne W.; Martin, Richard L.; Nordlund, Dennis; Seidler, Gerald T.; Shuh, David K.; Sokaras, Dimosthenis; Tyliszczak, Tolek; Wagner, Gregory L.; Weng, Tsu-Chein; Yang, Ping

    2014-01-01

    Advancing theories of how metal oxygen bonding influences metal oxo properties can expose new avenues for innovation in materials science, catalysis, and biochemistry. Historically, spectroscopic analyses of the transition metal peroxyanions, MO4x-, have formed the basis for new M O bonding theories. Herein, relative changes in M O orbital mixing in MO42- (M = Cr, Mo, W) and MO41- (M = Mn, Tc, Re) are evaluated for the first time by non-resonant inelastic X-ray scattering, X-ray absorption spectroscopy using fluorescence and transmission (via a scanning transmission X-ray microscope), and linear-response density functional theory. The results suggest that moving from Group 6 to Group 7 or down the triads increases M O e () mixing. Meanwhile, t2 mixing ( + ) remains relatively constant within the same Group. These unexpected changes in frontier orbital energy and composition are evaluated in terms of periodic trends in d orbital energy and radial extension.

  17. Plant maintenance and plant life extension issue, 2007

    SciTech Connect (OSTI)

    Agnihotri, Newal (ed.)

    2007-03-15

    The focus of the March-April issue is on plant maintenance and plant life extension. Major articles/reports in this issue include: Three proposed COLs expected in 2007, by Dale E. Klein, U.S. Nuclear Regulatory Commission; Delivering behaviors that our customers value, by Jack Allen, Westinghouse Electric Company; Facilitating high-level and fuel waste disposal technologies, by Malcolm Gray, IAEA, Austria; Plant life management and long-term operation, by Pal Kovacs, OECD-NEA, France; Measuring control rod position, by R. Taymanov, K. Sapozhnikova, I. Druzhinin, D.I. Mendeleyev, Institue for Metrology, Russia; and, 'Modernization' means higher safety, by Svetlana Genova, Kozluduy NPP plc, Bulgaria.

  18. EARLY ENTRANCE COPRODUCTION PLANT

    SciTech Connect (OSTI)

    Lalit S. Shah; William K. Davis

    2000-05-01

    The overall objective of this project is the three phase development of an Early Entrance Coproduction Plant (EECP) which produces at least one product from at least two of the following three categories: (1) electric power (or heat), (2) fuels, and (3) chemicals. The objective is to have these products produced by technologies capable of using synthesis gas derived from coal or coal in combination with some other carbonaceous feedstock. The objective of Phase I is to determine the feasibility and define the concept for the EECP located at a specific site and to develop a Research, Development, and Test Plan (RD and T) for implementation in Phase II. The objective of Phase II is to conduct RD and T as outlined in the Phase I RD and T Plan to enhance the development and commercial acceptance of Coproduction technology that produces high-value products, particularly those that are critical to our domestic fuel and power requirements. The project will resolve critical knowledge and technology gaps on the integration of gasification and downstream processing to coproduce some combination of power, fuels, and chemicals from coal and other feedstocks. The objective of Phase III is to develop an engineering design package and a financing plan for an EECP located at a specific site. The project's intended result is to provide the necessary technical, economic, and environmental information that will be needed to move the EECP forward to detailed design, construction, and operation by industry.

  19. Low energy consumption method for separating gaseous mixtures and in particular for medium purity oxygen production

    DOE Patents [OSTI]

    Jujasz, Albert J. (North Olmsted, OH); Burkhart, James A. (Olmsted Falls, OH); Greenberg, Ralph (New York, NY)

    1988-01-01

    A method for the separation of gaseous mixtures such as air and for producing medium purity oxygen, comprising compressing the gaseous mixture in a first compressor to about 3.9-4.1 atmospheres pressure, passing said compressed gaseous mixture in heat exchange relationship with sub-ambient temperature gaseous nitrogen, dividing the cooled, pressurized gaseous mixture into first and second streams, introducing the first stream into the high pressure chamber of a double rectification column, separating the gaseous mixture in the rectification column into a liquid oxygen-enriched stream and a gaseous nitrogen stream and supplying the gaseous nitrogen stream for cooling the compressed gaseous mixture, removing the liquid oxygen-enriched stream from the low pressure chamber of the rectification column and pumping the liquid, oxygen-enriched steam to a predetermined pressure, cooling the second stream, condensing the cooled second stream and evaporating the oxygen-enriched stream in an evaporator-condenser, delivering the condensed second stream to the high pressure chamber of the rectification column, and heating the oxygen-enriched stream and blending the oxygen-enriched stream with a compressed blend-air stream to the desired oxygen concentration.

  20. Ascorbate dynamics and oxygen consumption during arousal from hibernation in Arctic ground squirrels

    E-Print Network [OSTI]

    Drew, Kelly L.

    at the time of peak O2 consumption and peak plasma urate production. The ascor- bate decrease didAscorbate dynamics and oxygen consumption during arousal from hibernation in Arctic ground and oxygen consumption during arousal from hibernation in Arctic ground squirrels. Am J Physiol Regulatory

  1. Generation of Reactive Oxygen Species Mediated by 1Hydroxyphenazine, a Virulence Factor of Pseudomonas aeruginosa

    E-Print Network [OSTI]

    Gates, Kent. S.

    Generation of Reactive Oxygen Species Mediated by 1Hydroxyphenazine, a Virulence Factor tool for the detection of ROS generation mediated by 1-HP. These assays provided evidence that 1-HP evidence that 1-HP mediates the generation of intracellular oxidants. Generation of reactive oxygen species

  2. Boundaries of the Peruvian Oxygen Minimum Zone shaped by coherent mesoscale dynamics

    E-Print Network [OSTI]

    Bettencourt, João H; García, Emilio Hernández; Montes, Ivonne; Sudre, Joël; Dewitte, Boris; Paulmier, Aurélien; Garçon, Véronique

    2015-01-01

    Dissolved oxygen in sea water is a major factor affecting marine habitats and biogeochemical cycles. Oceanic zones with oxygen deficits represent significant portions of the area and volume of the oceans and are thought to be expanding. The Peruvian oxygen minimum zone is one of the most pronounced and lies in a region of strong mesoscale activity in the form of vortices and frontal regions, whose effect in the dynamics of the oxygen minimum zone is largely unknown. Here, we study this issue from a modeling approach and a Lagrangian point of view, using a coupled physical-biogeochemical simulation of the Peruvian oxygen minimum zone and finite-size Lyapunov exponent fields to understand the link between mesoscale dynamics and oxygen variations. Our results show that, at depths between 380 and 600 meters, mesoscale structures have a relevant dual role. First, their mean positions and paths delimit and maintain the oxygen minimum zone boundaries. Second, their high frequency fluctuations entrain oxygen across t...

  3. The obligation to surface periodically and replenish oxygen stores limits the underwater foraging capacity of marine

    E-Print Network [OSTI]

    Burns, Jennifer M.

    , but also aids in conserving water and energy during terrestrial fasts (Ortiz et al., 1978; Costa and Ortiz with animal size and age. In adults, total body oxygen stores are proportional to body mass (Mb; Kooyman, 1989 animals have higher mass-specific metabolic rates and lower mass-specific total body oxygen stores

  4. Carbon dioxide and oxygen fluxes in the Southern Ocean: Mechanisms of interannual variability

    E-Print Network [OSTI]

    Follows, Mick

    Carbon dioxide and oxygen fluxes in the Southern Ocean: Mechanisms of interannual variability A) to highlight the importance of convective mixing in inducing anomalous air-sea fluxes of carbon dioxide (2007), Carbon dioxide and oxygen fluxes in the Southern Ocean: Mechanisms of interannual variability

  5. The performance of PEM fuel cells fed with oxygen through the free-convection mode

    E-Print Network [OSTI]

    The performance of PEM fuel cells fed with oxygen through the free-convection mode Pei-Wen Li; accepted 27 September 2002 Abstract The feasibility and restrictions of feeding oxygen to a PEM fuel cell at the cathode surface, which can be viewed in terms of the relationship of the fuel cell current density

  6. A reactor for high-temperature pyrolysis and oxygen isotopic analysis of cellulose via induction heating

    E-Print Network [OSTI]

    Evans, Michael N.

    A reactor for high-temperature pyrolysis and oxygen isotopic analysis of cellulose via induction and theory to recommend pyrolysis at temperatures above 14508C to minimize memory and fractionation effects of producing pyrolysis conditions for the analysis of oxygen and deuterium isotopic compositions of organic

  7. Hydrogen passivation and activation of oxygen complexes in silicon S. N. Rashkeev,a)

    E-Print Network [OSTI]

    Pantelides, Sokrates T.

    Hydrogen passivation and activation of oxygen complexes in silicon S. N. Rashkeev,a) M. Di Ventra-principles calculations in terms of which we describe the role of hydrogen in passivating or activating oxygen complexes activity of the cluster. Furthermore, the addition of a hydrogen atom in the core structure of thermal

  8. Oxygen isotope records of goethite from ferricrete deposits indicate regionally varying Holocene climate change in

    E-Print Network [OSTI]

    Hren, Michael

    Oxygen isotope records of goethite from ferricrete deposits indicate regionally varying Holocene isotopes of goethite from ferricrete deposits were measured from both northern and southern Rocky Mountain in oxygen isotope values of 14 C-dated goethites in the northern Rocky Mountains suggests a regional

  9. Hydrogen absorption characteristics of oxygen-stabilized rare-earth iron intermetallic compounds

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Hydrogen absorption characteristics of oxygen-stabilized rare-earth iron intermetallic compounds M Abstract. -- The thermal behavior of oxygen-stabilized RjFegO^-hydrogen (R = Y, Dy, Ho) systems was studied decade to the study of the hydrogenation characte- ristics of a variety of intermetallic compounds, our

  10. Polycyclic Aromatic Hydrocarbons (PAHs), nitrated PAHs and oxygenated PAHs in ambient air of the

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Polycyclic Aromatic Hydrocarbons (PAHs), nitrated PAHs and oxygenated PAHs in ambient air + particle phases) of 16 polycyclic aromatic hydrocarbons (PAHs), 17 nitrated PAHs (NPAHs) and 9 oxygenated when (before or during the sampling) the OPAHs are formed. Keywords: Polycyclic aromatic hydrocarbons

  11. Production of Organic Oxygenates in the Partial Oxidation of Methane in a Silent Electric Discharge Reactor

    E-Print Network [OSTI]

    Mallinson, Richard

    Production of Organic Oxygenates in the Partial Oxidation of Methane in a Silent Electric Discharge to convert methane into useful products such as higher hydrocarbons, synthesis gas, and organic oxygenate is important for a process to have commercial potential. Thus, this study examines the effect methane

  12. Metallic filament formation by aligned oxygen vacancies in ZnO-based resistive switches

    SciTech Connect (OSTI)

    Gu, Tingkun

    2014-05-28

    The electronic structure of ZnO with defects of oxygen vacancies were investigated by using first-principles methods. Some structure models were constructed in order to investigate the effects of the distribution of oxygen vacancies on the electronic properties of ZnO. By analyzing the calculated results, we found that only the aligned oxygen vacancies can form the conducting channel in ZnO, and the transformation of the oxygen vacancy from charged state to neutral state is consistent with the energetics rule of the forming aligned oxygen vacancies. As for the heterojunction of Pt/ZnO/Pt, the oxygen vacancies near the interface of Pt/ZnO depress the local Schottky barrier effectively, and the aligned oxygen vacancies in ZnO form a conducting filament connecting two Pt electrodes. The metallic filament formation in Pt/ZnO/Pt resistive switching cells should be closely related to the carrier injection from Pt electrode into ZnO and the arrangement of oxygen vacancies in ZnO slab.

  13. A climatology-based quality control procedure for profiling float oxygen data

    E-Print Network [OSTI]

    Riser, Stephen C.

    A climatology-based quality control procedure for profiling float oxygen data Yuichiro Takeshita,1 to a climatology derived from ship-based bottle and CTD data [Wong et al., 2003; Bohme and Send, 2005; Owens for profiling float oxygen data based on comparing float data to a monthly climatology and therefore driving

  14. Uranium in iron formations and the rise of atmospheric oxygen C.A. Partin a,

    E-Print Network [OSTI]

    Konhauser, Kurt

    Uranium in iron formations and the rise of atmospheric oxygen C.A. Partin a, , S.V. Lalonde b , N Paleoproterozoic Geochemical uranium cycle The concept of the Great Oxidation Event (GOE), during which atmospheric oxygenation through the record of uranium (U) concentrations in iron formations (IF). Just as IF are important

  15. Lung deflation and oxygen pulse in COPD: Results from the NETT randomized trial*

    E-Print Network [OSTI]

    Lung deflation and oxygen pulse in COPD: Results from the NETT randomized trial* Carolyn E. Come a July 2011 Available online 16 August 2011 KEYWORDS Cardiac function; Hyperinflation; Lung volume function. We examined whether lung deflation improves oxygen pulse, a surrogate marker of stroke volume

  16. Unified picture of the oxygen isotope effect in cuprate superconductors Ho-kwang Mao

    E-Print Network [OSTI]

    Wu, Zhigang

    Unified picture of the oxygen isotope effect in cuprate superconductors Ho-kwang Mao Xiao-Jia Chen, see: Reprints www.pnas.org/misc/reprints.shtml To order reprints, see: Notes: #12;Unified picture present a unified picture of the oxygen isotope effect in cuprate superconductors based on a phonon

  17. SHORT COMMUNICATION Metabolic oxygen consumption measurement with a single-cell

    E-Print Network [OSTI]

    Brenner, David Jonathan

    SHORT COMMUNICATION Metabolic oxygen consumption measurement with a single-cell biosensor after Ó Springer-Verlag Berlin Heidelberg 2014 Abstract A noninvasive, self-referencing biosensor Microbeam II end station. A single-cell oxygen consumption measurement has been conducted with this type

  18. Alkaline Microfluidic Hydrogen-Oxygen Fuel Cell as a Cathode Characterization Platform

    E-Print Network [OSTI]

    Kenis, Paul J. A.

    Alkaline Microfluidic Hydrogen-Oxygen Fuel Cell as a Cathode Characterization Platform Fikile R on an alkaline microfluidic fuel cell for catalyst and electrode characterization. Its constantly refreshing investigated and the dual effects of enhanced oxygen reduction reaction activity and improved ionic

  19. Study of using oxygen-enriched combustion air for locomotive diesel engines

    SciTech Connect (OSTI)

    Poola, R.B.; Sekar, R.; Assanis, D.N.; Cataldi, G.R.

    1996-12-31

    A thermodynamic simulation is used to study the effects of oxygen-enriched intake air on the performance and nitrogen oxide (NO) emissions of a locomotive diesel engine. The parasitic power of the air separation membrane required to supply the oxygen-enriched air is also estimated. For a given constraint on peak cylinder pressure, the gross and net power output of an engine operating under different levels of oxygen enrichment are compared with those obtained when a high-boost turbocharged engine is used. A 4% increase in peak cylinder pressure can result in an increase in net engine power of approximately 13% when intake air with an oxygen content of 28% by volume is used and fuel injection timing is retarded by 4 degrees. When the engine is turbocharged to a higher inlet boost, the same increase in peak cylinder pressure can improve power by only 4%. If part of the significantly higher exhaust enthalpies available as a result of oxygen enrichment are recovered, the power requirements of the air separator membrane can be met, resulting in substantial net power improvements. Oxygen enrichment with its attendant higher combustion temperatures, reduces emissions of particulates and visible smoke but increases NO emissions (by up to three times at 26% oxygen content). Therefore, exhaust gas after-treatment and heat recovery would be required if the full potential of oxygen enrichment for improving the performance of locomotive diesel engines is to be realized.

  20. Stress-Induced Nitrogen and Oxygen Segregation and Complexing Investigated by High Resolution Synchrotron FTIR

    E-Print Network [OSTI]

    . Ciszek4 1 . Dept. of Materials Science & Eng., North Carolina State University, NC 2 . Dept. of Materials, CA 4 : National Renewable Energy Laboratory, CO Abstract: Nitrogen doped Czochralski (N-CZ) and Float variations and the defect distributions revealed by an Oxygen Precipitate Profiler (OPP), and oxygen

  1. Triple oxygen isotope variations in sedimentary rocks Naomi E. Levin a,

    E-Print Network [OSTI]

    . However, recent oxygen isotope measurements of terrestrial rocks, minerals and waters also reveal common for various equilibrium and kinetic mechanisms. Here we pres- ent triple oxygen isotope data on sedimentary; Pack and Herwartz, 2014), but they are gener- ally overlooked in analysis of terrestrial rocks

  2. Holocene precipitation seasonality captured by a dual hydrogen and oxygen isotope approach at Steel Lake, Minnesota

    E-Print Network [OSTI]

    Hu, Feng Sheng

    Holocene precipitation seasonality captured by a dual hydrogen and oxygen isotope approach at SteelMenocal Keywords: seasonal precipitation middle Holocene oxygen isotopes hydrogen isotopes forest­prairie boundary midcontinental North America. However, neither the climatic driver nor the seasonal character of precipitation

  3. Plant Energy Cost Optimization Program (PECOP) 

    E-Print Network [OSTI]

    Robinson, A. M.

    1980-01-01

    The Plant Energy Cost Optimization Program (PECOP) is a Management System designed to reduce operating cost in a continuous operating multi product plant by reviewing all cost factors and selecting plant wide production schedules which are most...

  4. SENSIBLE HEAT STORAGE FOR A SOLAR THERMAL POWER PLANT

    E-Print Network [OSTI]

    Baldwin, Thomas F.

    2011-01-01

    of the Proposed Solar Power Plant Design The Impact ofof the Thesis SOLAR POWER PLANT DESIGN , Study Guidelines a.Reference Solar Power Plant Design e. Power Plant

  5. SENSIBLE HEAT STORAGE FOR A SOLAR THERMAL POWER PLANT

    E-Print Network [OSTI]

    Baldwin, Thomas F.

    2011-01-01

    storage can provide solar power plant energy storage for aconfiguration for a solar power plant without energy storagefor a solar power plant greatly influences the plant energy

  6. Prolonged cold storage of red blood cells by oxygen removal and additive usage

    DOE Patents [OSTI]

    Bitensky, M.W.; Yoshida, Tatsuro

    1998-08-04

    Prolonged cold storage of red blood cells by oxygen removal and additive usage. A cost-effective, 4 C storage procedure that preserves red cell quality and prolongs post-transfusion in vivo survival is described. The improved in vivo survival and the preservation of adenosine triphosphate levels, along with reduction in hemolysis and membrane vesicle production of red blood cells stored at 4 C for prolonged periods of time, is achieved by reducing the oxygen level therein at the time of storage; in particular, by flushing the cells with an inert gas, and storing them in an aqueous solution which includes adenine, dextrose, mannitol, citrate ion, and dihydrogen phosphate ion, but no sodium chloride, in an oxygen-permeable container which is located in an oxygen-free environment containing oxygen-scavenging materials. 8 figs.

  7. Prolonged cold storage of red blood cells by oxygen removal and additive usage

    DOE Patents [OSTI]

    Bitensky, Mark W. (Boston, MA); Yoshida, Tatsuro (Newton, MA)

    1998-01-01

    Prolonged cold storage of red blood cells by oxygen removal and additive usage. A cost-effective, 4.degree. C. storage procedure that preserves red cell quality and prolongs post-transfusion in vivo survival is described. The improved in vivo survival and the preservation of adenosine triphosphate levels, along with reduction in hemolysis and membrane vesicle production of red blood cells stored at 4.degree. C. for prolonged periods of time, is achieved by reducing the oxygen level therein at the time of storage; in particular, by flushing the cells with an inert gas, and storing them in an aqueous solution which includes adenine, dextrose, mannitol, citrate ion, and dihydrogen phosphate ion, but no sodium chloride, in an oxygen-permeable container which is located in an oxygen-free environment containing oxygen-scavenging materials.

  8. On the relationship between auroral and nebular oxygen line intensities in spectra of HII regions

    E-Print Network [OSTI]

    L. S. Pilyugin

    2005-04-18

    We investigate relationships between observed auroral and nebular oxygen line fluxes in spectra of HII regions. We find a relation that is metallicity-dependent at low metallicities, but becomes independent of metallicity (within the uncertainties of the available data) above 12+logO/H ~ 8.25, i.e. there is one-to-one correspondance (the ff - relation) between auroral and nebular oxygen line fluxes in spectra of high-metallicity HII regions. The ff - relation allows one to estimate the flux in the auroral line from strong oxygen line measurements. This solves the problem of the electron temperature (and, consequently, abundance) determination in high-metallicity HII regions. The ff - relation confirms the basic idea of the empirical method, proposed by Pagel et al. (1979) a qurter of a century ago, that the oxygen abundance in HII region can be estimated from the strong oxygen lines measurements only.

  9. Oxygen abundances in dwarf irregular galaxies and the metallicity - luminosity relationship

    E-Print Network [OSTI]

    L. S. Pilyugin

    2001-05-21

    The low-luminosity dwarf irregular galaxies are considered. The oxygen abundances in HII regions of dwarf irregular galaxies were recalculated from published spectra through the recently suggested P - method. It has been found that the metallicity of low-luminosity dwarf irregular galaxies, with a few exceptions, correlates well with galaxy luminosity. The dispersion of oxygen abundances around the metallicity - luminosity relationship increases with decreasing of galaxy luminosity, as was found by Richer and McCall (1995). No relationship between the oxygen abundance and the absolute magnitude in the blue band for irregular galaxies obtained by Hidalgo-Gamez and Olofsson (1998) can be explained by the large uncertainties in the oxygen abundances derived through the Te - method, that in turn can be explained by the large uncertainties in the measurements of the strengths of the weak oxygen line [OIII]4363 used in the Te - method.

  10. Pilot-Scale Demonstration of a Novel, Low-Cost Oxygen Supply Process and its Integration with Oxy-Fuel Coal-Fired Boilers

    SciTech Connect (OSTI)

    Krish Krishnamurthy; Divy Acharya; Frank Fitch

    2008-09-30

    In order to achieve DOE targets for carbon dioxide capture, it is crucial not only to develop process options that will generate and provide oxygen to the power cycle in a cost-effective manner compared to the conventional oxygen supply methods based on cryogenic air separation technology, but also to identify effective integration options for these new technologies into the power cycle with carbon dioxide capture. The Linde/BOC developed Ceramic Autothermal Recovery (CAR) process remains an interesting candidate to address both of these issues by the transfer of oxygen from the air to a recycled CO{sub 2} rich flue-gas stream in a cyclic process utilizing the high temperature sorption properties of perovskites. Good progress was made on this technology in this project, but significant challenges remain to be addressed before CAR oxygen production technology is ready for commercial exploitation. Phase 1 of the project was completed by the end of September 2008. The two-bed 0.7 tons/day O2 CAR process development unit (PDU) was installed adjacent to WRI's pilot scale coal combustion test facility (CTF). Start-up and operating sequences for the PDU were developed and cyclic operation of the CAR process demonstrated. Controlled low concentration methane addition allowed the beds to be heated up to operational temperature (800-900 C) and then held there during cyclic operation of the 2-bed CAR process, in this way overcoming unavoidable heat losses from the beds during steady state operation. The performance of the PDU was optimized as much as possible, but equipment limitations prevented the system from fully achieving its target performance. Design of the flue gas recirculation system to integrate CAR PDU with the CTF and the system was completed and integrated tests successfully performed at the end of the period. A detailed techno-economic analysis was made of the CAR process for supplying the oxygen in oxy-fuel combustion retrofit option using AEP's 450 MW Conesville, Ohio plant and contrasted with the cryogenic air separation option (ASU). Design of a large scale CAR unit was completed to support this techno-economic assessment. Based on the finding that the overall cost potential of the CAR technology compared to cryogenic ASU is nominal at current performance levels and that the risks related to both material and process scale up are still significant, the team recommended not to proceed to Phase 2. CAR process economics continue to look attractive if the original and still 'realistic' target oxygen capacities could be realized in practice. In order to achieve this end, a new fundamental materials development program would be needed. With the effective oxygen capacities of the current CAR materials there is, however, insufficient economic incentive to use this commercially unproven technology in oxy-fuel power plant applications in place of conventional ASUs. In addition, it is now clear that before a larger scale pilot demonstration of the CAR technology is made, a better understanding of the impact of flue-gas impurities on the CAR materials and of thermal transients in the beds is required.

  11. Enterprise Assessments Review, Waste Isolation Pilot Plant -...

    Office of Environmental Management (EM)

    Enterprise Assessments Review, Waste Isolation Pilot Plant - December 2014 Enterprise Assessments Review, Waste Isolation Pilot Plant - December 2014 December, 2014 Review of the...

  12. Independent Oversight Inspection, Pantex Plant - August 2005...

    Energy Savers [EERE]

    August 2005 Independent Oversight Inspection, Pantex Plant - August 2005 August 2005 Inspection of Emergency Management at the Pantex Site Office and the Pantex Plant This report...

  13. New Jersey Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net...

  14. New York Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net...

  15. North Carolina Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Carolina nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear...

  16. South Carolina Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    South Carolina nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State...

  17. New Hampshire Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (nw)","Net generation (thousand mwh)","Share of State nuclear net...

  18. Pre-In-Plant Training Webinar (Steam)

    Broader source: Energy.gov [DOE]

    This pre-In-Plant training webinar for the Better Plants Program covers how to find energy savings in steam systems.

  19. Independent Oversight Review, Portsmouth Gaseous Diffusion Plant...

    Office of Environmental Management (EM)

    January 2013 Independent Oversight Review, Portsmouth Gaseous Diffusion Plant - January 2013 January 2013 Review of the Portsmouth Gaseous Diffusion Plant Work Planning and Control...

  20. Independent Activity Report, Portsmouth Gaseous Diffusion Plant...

    Office of Environmental Management (EM)

    Portsmouth Gaseous Diffusion Plant - August 2011 Independent Activity Report, Portsmouth Gaseous Diffusion Plant - August 2011 August 2011 Orientation Visit to the Portsmouth...

  1. HYDROCARBONS FROM PLANTS: ANALYTICAL METHODS AND OBSERVATIONS

    E-Print Network [OSTI]

    Calvin, Melvin

    2013-01-01

    molecular weights of various hydrocarbon materials for fuelof oil and alcohol from hydrocarbon-producing plants. Into Die Naturwissenschaften HYDROCARBONS FROM PLANTS: METHODS

  2. EARLY ENTRANCE COPRODUCTION PLANT

    SciTech Connect (OSTI)

    John H. Anderson; William K. Davis; Thomas W. Sloop

    2001-03-21

    As part of the Department of Energy's (DOE) Gasification Technologies and Transportation Fuels and Chemicals programs, DOE and Texaco are partners through Cooperative Agreement DE-FC26-99FT40658 to determine the feasibility of developing, constructing and operating an Early Entrance Coproduction Plant (EECP). The overall objective of the project is the three-phase development of an EECP that produces at least one product from at least two of the following three categories: Electric power (or heat); Fuels; and Chemicals. The objective is to have these products produced by technologies capable of using synthesis gas derived from coal and/or some other carbonaceous feedstock, such as petroleum coke. The objective of Phase I was to determine the feasibility and define the concept for the EECP located at a specific site and to develop a Research, Development, and Testing (RD and T) Plan for implementation in Phase II. This objective has now been accomplished. A specific site, Motiva Refinery in Port Arthur, Texas, has been selected as the location best suited for the EECP. The specific work requirements of Phase I included: Prepare an EECP Preliminary Concept Report covering Tasks 2-8 specified in the Cooperative Agreement; Develop a Research, Development, and Testing (RD and T) Plan as specified in Task 9 of the Cooperative Agreement for implementation in Phase II; and Develop a Preliminary Project Financing Plan for the EECP Project as specified in Task 10 of the Cooperative Agreement. This document is the Preliminary Project Financing Plan for the design, construction, and operation of the EECP at the Motiva Port Arthur Refinery.

  3. Standard Test Method for Determination of Uranium, Oxygen to Uranium (O/U), and Oxygen to Metal (O/M) in Sintered Uranium Dioxide and Gadolinia-Uranium Dioxide Pellets by Atmospheric Equilibration

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2007-01-01

    Standard Test Method for Determination of Uranium, Oxygen to Uranium (O/U), and Oxygen to Metal (O/M) in Sintered Uranium Dioxide and Gadolinia-Uranium Dioxide Pellets by Atmospheric Equilibration

  4. Effects of Oxygen-Containing Functional Groups on Supercapacitor Performance

    SciTech Connect (OSTI)

    Kerisit, Sebastien N.; Schwenzer, Birgit; Vijayakumar, M.

    2014-07-03

    Molecular dynamics (MD) simulations of the interface between graphene and the ionic liquid 1-butyl-3-methylimidazolium trifluoromethanesulfonate (BMIM OTf) were carried out to gain molecular-level insights into the performance of graphene-based supercapacitors and, in particular, determine the effects of the presence of oxygen-containing defects at the graphene surface on their integral capacitance. The MD simulations predict that increasing the surface coverage of hydroxyl groups negatively affects the integral capacitance, whereas the effect of the presence of epoxy groups is much less significant. The calculated variations in capacitance are found to be directly correlated to the interfacial structure. Indeed, hydrogen bonding between hydroxyl groups and SO3 anion moieties prevents BMIM+ and OTf- molecules from interacting favorably in the dense interfacial layer and restrains the orientation and mobility of OTf- ions, thereby reducing the permittivity of the ionic liquid at the interface. The results of the molecular simulations can facilitate the rational design of electrode materials for supercapacitors.

  5. Oxygen enrichment in carbon-rich planetary nebulae

    E-Print Network [OSTI]

    Delgado-Inglada, Gloria; Peimbert, Manuel; Stasi?ska, Gra?yna; Morisset, Christophe

    2015-01-01

    We study the relation between the chemical composition and the type of dust present in a group of 20 Galactic planetary nebulae (PNe) that have high quality optical and infrared spectra. The optical spectra are used, together with the best available ionization correction factors, to calculate the abundances of Ar, C, Cl, He, N, Ne, and O relative to H. The infrared spectra are used to classify the PNe in two groups depending on whether the observed dust features are representative of oxygen-rich or carbon-rich environments. The sample contains one object from the halo, eight from the bulge, and eleven from the local disc. We compare their chemical abundances with nucleosynthesis model predictions and with the ones obtained in seven Galactic H II regions of the solar neighbourhood. We find evidence of O enrichment (by $\\sim$ 0.3 dex) in all but one of the PNe with carbon-rich dust (CRD). Our analysis shows that Ar, and especially Cl, are the best metallicity indicators of the progenitors of PNe. There is a tig...

  6. Oxygen sensor for monitoring gas mixtures containing hydrocarbons

    DOE Patents [OSTI]

    Ruka, R.J.; Basel, R.A.

    1996-03-12

    A gas sensor measures O{sub 2} content of a reformable monitored gas containing hydrocarbons, H{sub 2}O and/or CO{sub 2}, preferably in association with an electrochemical power generation system. The gas sensor has a housing communicating with the monitored gas environment and carries the monitored gas through an integral catalytic hydrocarbon reforming chamber containing a reforming catalyst, and over a solid electrolyte electrochemical cell used for sensing purposes. The electrochemical cell includes a solid electrolyte between a sensor electrode that is exposed to the monitored gas, and a reference electrode that is isolated in the housing from the monitored gas and is exposed to a reference gas environment. A heating element is also provided in heat transfer communication with the gas sensor. A circuit that can include controls operable to adjust operations via valves or the like is connected between the sensor electrode and the reference electrode to process the electrical signal developed by the electrochemical cell. The electrical signal varies as a measure of the equilibrium oxygen partial pressure of the monitored gas. Signal noise is effectively reduced by maintaining a constant temperature in the area of the electrochemical cell and providing a monitored gas at chemical equilibria when contacting the electrochemical cell. The output gas from the electrochemical cell of the sensor is fed back into the conduits of the power generating system. 4 figs.

  7. Porous platinum-based catalysts for oxygen reduction

    DOE Patents [OSTI]

    Erlebacher, Jonah D; Snyder, Joshua D

    2014-11-25

    A porous metal that comprises platinum and has a specific surface area that is greater than 5 m.sup.2/g and less than 75 m.sup.2/g. A fuel cell includes a first electrode, a second electrode spaced apart from the first electrode, and an electrolyte arranged between the first and the second electrodes. At least one of the first and second electrodes is coated with a porous metal catalyst for oxygen reduction, and the porous metal catalyst comprises platinum and has a specific surface area that is greater than 5 m.sup.2/g and less than 75 m.sup.2/g. A method of producing a porous metal according to an embodiment of the current invention includes producing an alloy consisting essentially of platinum and nickel according to the formula Pt.sub.xNi.sub.1-x, where x is at least 0.01 and less than 0.3; and dealloying the alloy in a substantially pH neutral solution to reduce an amount of nickel in the alloy to produce the porous metal.

  8. Oxygen sensor for monitoring gas mixtures containing hydrocarbons

    DOE Patents [OSTI]

    Ruka, Roswell J. (Pittsburgh, PA); Basel, Richard A. (Pittsburgh, PA)

    1996-01-01

    A gas sensor measures O.sub.2 content of a reformable monitored gas containing hydrocarbons H.sub.2 O and/or CO.sub.2, preferably in association with an electrochemical power generation system. The gas sensor has a housing communicating with the monitored gas environment and carries the monitored gas through an integral catalytic hydrocarbon reforming chamber containing a reforming catalyst, and over a solid electrolyte electrochemical cell used for sensing purposes. The electrochemical cell includes a solid electrolyte between a sensor electrode that is exposed to the monitored gas, and a reference electrode that is isolated in the housing from the monitored gas and is exposed to a reference gas environment. A heating element is also provided in heat transfer communication with the gas sensor. A circuit that can include controls operable to adjust operations via valves or the like is connected between the sensor electrode and the reference electrode to process the electrical signal developed by the electrochemical cell. The electrical signal varies as a measure of the equilibrium oxygen partial pressure of the monitored gas. Signal noise is effectively reduced by maintaining a constant temperature in the area of the electrochemical cell and providing a monitored gas at chemical equilibria when contacting the electrochemical cell. The output gas from the electrochemical cell of the sensor is fed back into the conduits of the power generating system.

  9. Plant salt-tolerance mechanisms

    SciTech Connect (OSTI)

    Deinlein, Ulrich; Stephan, Aaron B.; Horie, Tomoaki; Luo, Wei; Xu, Guohua; Schroeder, Julian I.

    2014-06-01

    Crop performance is severely affected by high salt concentrations in soils. To engineer more salt-tolerant plants it is crucial to unravel the key components of the plant salt-tolerance network. Here we review our understanding of the core salt-tolerance mechanisms in plants. Recent studies have shown that stress sensing and signaling components can play important roles in regulating the plant salinity stress response. We also review key Na+ transport and detoxification pathways and the impact of epigenetic chromatin modifications on salinity tolerance. In addition, we discuss the progress that has been made towards engineering salt tolerance in crops, including marker-assisted selection and gene stacking techniques. We also identify key open questions that remain to be addressed in the future.

  10. The Annual Growth In Plants

    E-Print Network [OSTI]

    Courtright, J. E.

    1903-01-01

    KU ScholarWorks | The University of Kansas Pre-1923 Dissertations and Theses Collection The Annual Growth In Plants 1903 by J. E. Courtright This work was digitized by the Scholarly Communications program staff in the KU Libraries’ Center...

  11. Water Filtration Using Plant Xylem

    E-Print Network [OSTI]

    Boutilier, Michael Stephen Ha

    Effective point-of-use devices for providing safe drinking water are urgently needed to reduce the global burden of waterborne disease. Here we show that plant xylem from the sapwood of coniferous trees – a readily available, ...

  12. USF PHYSICAL PLANT VEHICLE MAINTENANCE

    E-Print Network [OSTI]

    Meyers, Steven D.

    USF PHYSICAL PLANT VEHICLE MAINTENANCE TELEPHONE NO. 974-2500 GAS PUMP AUTHORIZATION FORM PLEASE. _____ THE FOLLOWING PERSONNEL ARE AUTHORIZED BY THIS DOCUMENT TO PUMP GASOLINE/DIESEL FUEL FOR OUR USF OWNED VEHICLES

  13. A neighborhood alternative energy plant

    E-Print Network [OSTI]

    Brooks, Douglas James

    1982-01-01

    A design that proposes the redefinition of the role of a power plant facility within a community by creating a humane environment for recreation, education, community gathering, living, and energy production; rather than ...

  14. Computer Control of Unattended Plants 

    E-Print Network [OSTI]

    Vinson, D. R.; Chatterjee, N.

    1984-01-01

    Providing a cost-effective and reliable computer monitoring, control, and optimization package is a greater challenge for small, unattended plants than for large energy intensive facilities. This paper describes the successful application of a...

  15. Development of BWR plant analyzer

    SciTech Connect (OSTI)

    Wulff, W.; Cheng, H.S.; Lekach, S.V.; Stritar, A.; Mallen, A.N.

    1984-01-01

    The BWR Plant Analyzer has been developed for realistic and accurate simulations of normal and severe abnormal transients in BWR power plants at high simulation speeds, low capital and operating costs and with outstanding user conveniences. The simulation encompasses neutron kinetics, heat conduction in fuel structures, nonequilibrium, nonhomogeneous coolant dynamics, steam line acoustics, and the dynamics of turbines, condensers, feedwater pumps and heaters, of the suppression pool, the control systems and the plant protection systems. These objectives have been achieved. Advanced modeling, using extensively analytical integration and dynamic evaluation of analytical solutions, has been combined with modern minicomputer technology for high-speed simulation of complex systems. The High-Speed Interactive Plant Analyzer code HIPA-BWR has been implemented on the AD10 peripheral parallel processor.

  16. Morris Plant Energy Efficiency Program 

    E-Print Network [OSTI]

    Betczynski, M. T.

    2004-01-01

    to existing operating practices. Plant management also takes an active role in recognizing accomplishments and holding personnel accountable for continued improvement in energy efficiency. The control systems group at Equistar has integrated an Aspen...

  17. Upgrading coal plant damper drives

    SciTech Connect (OSTI)

    Hood, N.R.; Simmons, K. [Alamaba Power (United States)

    2009-11-15

    The replacement of damper drives on two coal-fired units at the James H. Miller Jr. electric generating plant by Intelligent Contrac electric rotary actuators is discussed. 2 figs.

  18. Plant salt-tolerance mechanisms

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Deinlein, Ulrich; Stephan, Aaron B.; Horie, Tomoaki; Luo, Wei; Xu, Guohua; Schroeder, Julian I.

    2014-06-01

    Crop performance is severely affected by high salt concentrations in soils. To engineer more salt-tolerant plants it is crucial to unravel the key components of the plant salt-tolerance network. Here we review our understanding of the core salt-tolerance mechanisms in plants. Recent studies have shown that stress sensing and signaling components can play important roles in regulating the plant salinity stress response. We also review key Na+ transport and detoxification pathways and the impact of epigenetic chromatin modifications on salinity tolerance. In addition, we discuss the progress that has been made towards engineering salt tolerance in crops, including marker-assisted selectionmore »and gene stacking techniques. We also identify key open questions that remain to be addressed in the future.« less

  19. Scale Insects on Ornamental Plants 

    E-Print Network [OSTI]

    Muegge, Mark A.; Merchant, Michael E.

    2000-08-21

    Scale insects damage landscape plants, shrubs and trees. This publication explains how to control scale insects economically without damaging the environment, including sampling for scale crawlers, using natural enemies and applying pesticides....

  20. COKEMASTER: Coke plant management system

    SciTech Connect (OSTI)

    Johanning, J.; Reinke, M. [Krupp Koppers GmbH, Essen (Germany)

    1996-12-31

    To keep coke utilization in ironmaking as competitive as possible, the potential to improve the economics of coke production has to be utilized. As one measure to meet this need of its customers, Krupp Koppers has expanded its existing ECOTROL computer system for battery heating control to a comprehensive Coke Plant Management System. Increased capacity utilization, lower energy consumption, stabilization of plant operation and ease of operation are the main targets.

  1. Researching power plant water recovery

    SciTech Connect (OSTI)

    NONE

    2008-04-01

    A range of projects supported by NETl under the Innovations for Existing Plant Program are investigating modifications to power plant cooling systems for reducing water loss, and recovering water from the flue gas and the cooling tower. This paper discusses two technologies showing particular promise condense water that is typically lost to evaporation, SPX technologies' Air2Air{sup trademark} condenses water from a cooling tower, while Lehigh University's process condenses water and acid in flue gas. 3 figs.

  2. Common Aquatic Plants -- Identification, Control. 

    E-Print Network [OSTI]

    Klussmann, Wallace G. (Wallace Glenn); Lowman, Fred G.

    1964-01-01

    root. Duckweed float freely and are moved by wind current. Often they can be removed mechanically by net or similar device when plants are crowded against the shore by a strong wind. Use Chemical Control No.8. FLOATING PLANTS WATER STAR GRASS.... The genus Potamogeton J commonly called pond weeds, includes many species common to Texas waters. Group characteristics include alternate leaves with flowers and fruits in spikes or heads. Many have two kinds of leaves: (1) floating and firm textured and (2...

  3. Controlling Diseases on Ornamental Plants

    E-Print Network [OSTI]

    Horne, C. Wendell; Johnson, Jerral D.; Walla, Walter J.

    1979-01-01

    on elms and other shade trees. Mushroom-type fu ngal growths appear on trunk, limbs or roots near the soil surface. Rots may be present for several years before mushrooms ap pear. Tree becomes sus ceptible to wi nd damage. Plants may die back..., irises, lilies, narcissus and tulips. ROOT DISEASES Disease Cotton root rot (fungi) Crown gall Mushroom root rot Symptoms Small flowering plants die within a few days. Shrubs and trees die more slowly. Large trees may die within several...

  4. Thickness Dependence of Oxygen Reduction Reaction Kinetics on Strontium-Substituted Lanthanum Manganese Perovskite Thin-Film Microelectrodes

    E-Print Network [OSTI]

    la O’, G. J.

    Oxygen reduction reaction (ORR) kinetics was investigated on dense La?.?Sr?.?MnO? microelectrodes as a function of temperature and microelectrode thickness using electrochemical impedance spectroscopy. The surface oxygen ...

  5. PHYSICAL REVIEW B 84, 245206 (2011) First-principles study of band gap engineering via oxygen vacancy doping

    E-Print Network [OSTI]

    Rappe, Andrew M.

    2011-01-01

    vacancies can play a beneficial role. For example, in solid oxide fuel cells, oxygen vacancies enable for photovoltaic applications.6­8 Despite the technological relevance of oxygen vacancies in ferroelectric solutions are fundamentally interesting and technologically important. However, experimental

  6. EARLY ENTRANCE COPRODUCTION PLANT

    SciTech Connect (OSTI)

    Fred D. Brent; Lalit Shah; Earl Berry; Charles H. Schrader; John Anderson; Ming He; James F. Stevens; Centha A. Davis; Michael Henley; Jerome Mayer; Harry Tsang; Jimell Erwin; Jennifer Adams; Michael Tillman; Chris Taylor; Marjan J. Roos; Robert F. Earhart

    2004-01-27

    The overall objective of this project is the three phase development of an Early Entrance Coproduction Plant (EECP) which uses petroleum coke to produce at least one product from at least two of the following three categories: (1) electric power (or heat), (2) fuels, and (3) chemicals using ChevronTexaco's proprietary gasification technology. The objective of Phase I is to determine the feasibility and define the concept for the EECP located at a specific site; develop a Research, Development, and Testing (RD&T) Plan to mitigate technical risks and barriers; and prepare a Preliminary Project Financing Plan. The objective of Phase II is to implement the work as outlined in the Phase I RD&T Plan to enhance the development and commercial acceptance of coproduction technology. The objective of Phase III is to develop an engineering design package and a financing and testing plan for an EECP located at a specific site. The project's intended result is to provide the necessary technical, economic, and environmental information needed by industry to move the EECP forward to detailed design, construction, and operation. The partners in this project are Texaco Energy Systems LLC or TES (a subsidiary of ChevronTexaco), General Electric (GE), Praxair, and Kellogg Brown & Root (KBR) in addition to the U.S. Department of Energy (DOE). TES is providing gasification technology and Fischer-Tropsch (F-T) technology developed by Rentech, GE is providing combustion turbine technology, Praxair is providing air separation technology, and KBR is providing engineering. Each of the EECP subsystems was assessed for technical risks and barriers. A plan was developed to mitigate the identified risks (Phase II RD&T Plan, October 2000). The potential technical and economic risks to the EECP from Task 2.5 can be mitigated by demonstrating that the end-use products derived from the upgrading of the F-T synthesis total liquid product can meet or exceed current specifications for the manufacture of ethylene and propylene chemicals from F-T naphtha, for the generation of hydrogen from F-T naphtha to power fuel cells, for direct blending of F-T diesels into transportation fuels, for the conversion of F-T heavy product wax to transportation fuels, and the conversion of F-T Heavy product wax to a valuable high melting point food-grade specialty wax product. Product evaluations conducted under Task 2.5 of Phase II successfully mitigated the above technical and economic risks to the EECP with the development of product yields and product qualities for the production of chemicals, transportation fuels, and specialty food-grade waxes from the F-T synthesis products.

  7. EARLY ENTRANCE COPRODUCTION PLANT

    SciTech Connect (OSTI)

    John Anderson; Charles Schrader

    2004-01-26

    In 1999, the U. S. Department of Energy (DOE) awarded a Cooperative Agreement to Texaco Energy Systems Inc. to provide a preliminary engineering design of an Early Entrance Coproduction Plant (EECP). Since the award, continuous and diligent work has been undertaken to achieve the design of an economical facility that makes strides toward attaining the goal of DOE's Vision 21 Program. The objective of the EECP is to convert coal and/or petroleum coke to power while coproducing transportation fuels, chemicals, and useful utilities such as steam. This objective is being pursued in a three-phase effort through the partnership of the DOE with prime contractor Texaco Energy Systems, LLC. (TES), the successor to Texaco Energy Systems, Inc. The key subcontractors to TES include General Electric (GE), Praxair, and Kellogg Brown and Root. ChevronTexaco provided gasification technology and Rentech Inc.'s Fischer-Tropsch (F-T) technology that has been developed for non-natural gas sources. GE provided gas turbine technology for the combustion of low energy content gas. Praxair provided air separation technology and KBR provided engineering to integrate the facility. A conceptual design was completed in Phase I and the report was accepted by the DOE in May 2001. The Phase I work identified risks and critical research, development, and testing that would improve the probability of technical success of the EECP. The objective of Phase II was to mitigate the risks by executing research, development, and testing. Results from the Phase II work are the subject of this report. As the work of Phase II concluded, it became evident that sufficient, but not necessarily complete, technical information and data would be available to begin Phase III - Preliminary Engineering Design. Work in Phase II requires additional technical development work to correctly apply technology at a specific site. The project's intended result is to provide the necessary technical, economic, and environmental information needed by industry to move the EECP forward to detailed design, construction, and operation. The decision to proceed with Phase III centers on locating a new site and favorable commercial and economic factors.

  8. EARLY ENTRANCE COPRODUCTION PLANT

    SciTech Connect (OSTI)

    David Storm; Govanon Nongbri; Steve Decanio; Ming He; Lalit Shah; Charles Schrader; Earl Berry; Peter Ricci; Belma Demirel; Charles Benham; Mark Bohn

    2004-01-12

    The overall objective of this project is the three phase development of an Early Entrance Coproduction Plant (EECP) which uses petroleum coke to produce at least one product from at least two of the following three categories: (1) electric power (or heat), (2) fuels, and (3) chemicals using ChevronTexaco's proprietary gasification technology. The objective of Phase I is to determine the feasibility and define the concept for the EECP located at a specific site; develop a Research, Development, and Testing (RD&T) Plan to mitigate technical risks and barriers; and prepare a Preliminary Project Financing Plan. The objective of Phase II is to implement the work as outlined in the Phase I RD&T Plan to enhance the development and commercial acceptance of coproduction technology. The objective of Phase III is to develop an engineering design package and a financing and testing plan for an EECP located at a specific site. The project's intended result is to provide the necessary technical, economic, and environmental information needed by industry to move the EECP forward to detailed design, construction, and operation. The partners in this project are Texaco Energy Systems LLC or TES (a subsidiary of ChevronTexaco), General Electric (GE), Praxair, and Kellogg Brown & Root (KBR) in addition to the U.S. Department of Energy (DOE). TES is providing gasification technology and Fischer-Tropsch (F-T) technology developed by Rentech, Inc., GE is providing combustion turbine technology, Praxair is providing air separation technology, and KBR is providing engineering. During Phase I, a design basis for the Fischer-Tropsch Synthesis section was developed based on limited experience with the specified feed gas and operating conditions. The objective of this Task in Phase II RD&T work was to confirm the performance of the F-T reactor at the set design conditions. Although much of the research, development, and testing work were done by TES outside of this project, several important issues were addressed in this phase of the project. They included Rejuvenation/Regeneration of the Fischer-Tropsch Catalyst, online Catalyst Withdrawal and Addition from the synthesis reactor, and the Fischer-Tropsch Design Basis Confirmation. In Phase III the results from these RD&T work will be incorporated in developing the engineering design package. This Topical Report documents the Phase II RD&T work that was completed for this task.

  9. Plant salt stress status is transmitted systemically via propagating calcium waves

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stephan, Aaron B.; Schroeder, Julian I.

    2014-04-29

    The existence and relevance of rapid long distance signaling in plants is evident to any observer of the nastic movements of the Venus flytrap (Dionaea muscipula) or the sensitive plant (Mimosa pudica). However, all plants require the transmission of sensory information from the site of perception to other tissues to adjust their physiological states according to their environment. It is becoming increasingly apparent that rapid long-distance signals exist throughout the plant kingdom and may be responsible for initiating a multitude of physiological responses: electrical “action potentials” have been shown to convey wounding and saltstress information from leaf-to-leaf (1, 2); amore »“hydraulic signal” transmitted by the direction of water movement within the xylem can mediate long-distance signaling of water stress experienced by the roots to the leaves in Arabidopsis (3); and reactive oxygen species (ROS) have been shown to propagate across a plant and carry stimulus-specific information to a variety of stresses (4). In PNAS, Choi et al. (5) use elegant approaches and present advances demonstrating that calcium can function as a long-distance signaling messenger, propagating in waves from roots and carrying salt-stress signals to induce expression of salt tolerance genes in leaves.« less

  10. Plant salt stress status is transmitted systemically via propagating calcium waves.

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stephan, Aaron B.; Schroeder, Julian I.

    2014-04-29

    The existence and relevance of rapid long distance signaling in plants is evident to any observer of the nastic movements of the Venus flytrap (Dionaea muscipula) or the sensitive plant (Mimosa pudica). However, all plants require the transmission of sensory information from the site of perception to other tissues to adjust their physiological states according to their environment. It is becoming increasingly apparent that rapid long-distance signals exist throughout the plant kingdom and may be responsible for initiating a multitude of physiological responses: electrical “action potentials” have been shown to convey wounding and saltstress information from leaf-to-leaf (1, 2); a “hydraulic signal” transmitted by the direction of water movement within the xylem can mediate long-distance signaling of water stress experienced by the roots to the leaves in Arabidopsis (3); and reactive oxygen species (ROS) have been shown to propagate across a plant and carry stimulus-specific information to a variety of stresses (4). In PNAS, Choi et al. (5) use elegant approaches and present advances demonstrating that calcium can function as a long-distance signaling messenger, propagating in waves from roots and carrying salt-stress signals to induce expression of salt tolerance genes in leaves.

  11. Plant salt stress status is transmitted systemically via propagating calcium waves

    SciTech Connect (OSTI)

    Stephan, Aaron B. [Univ. of California, San Diego, CA (United States). Div. of Biological Sciences, Cell and Developmental Biology Section; Schroeder, Julian I. [Univ. of California, San Diego, CA (United States). Div. of Biological Sciences, Cell and Developmental Biology Section

    2014-04-29

    The existence and relevance of rapid long distance signaling in plants is evident to any observer of the nastic movements of the Venus flytrap (Dionaea muscipula) or the sensitive plant (Mimosa pudica). However, all plants require the transmission of sensory information from the site of perception to other tissues to adjust their physiological states according to their environment. It is becoming increasingly apparent that rapid long-distance signals exist throughout the plant kingdom and may be responsible for initiating a multitude of physiological responses: electrical “action potentials” have been shown to convey wounding and saltstress information from leaf-to-leaf (1, 2); a “hydraulic signal” transmitted by the direction of water movement within the xylem can mediate long-distance signaling of water stress experienced by the roots to the leaves in Arabidopsis (3); and reactive oxygen species (ROS) have been shown to propagate across a plant and carry stimulus-specific information to a variety of stresses (4). In PNAS, Choi et al. (5) use elegant approaches and present advances demonstrating that calcium can function as a long-distance signaling messenger, propagating in waves from roots and carrying salt-stress signals to induce expression of salt tolerance genes in leaves.

  12. THE MULTILINGUAL ENTITY TASK (MET) OVERVIEW Roberta Merchant

    E-Print Network [OSTI]

    expressions (percentage and money) in Spanish texts from Agence France Presse, in Japanese texts from Kyodo. In the fall, Government language teams retrieved training and test texts with multilingual softwarefor. elected to participate in all languages, SRA in Spanish and Japanese, BBN in Spanish (with FinCen) and Chi

  13. Regulated and merchant interconnectors in Australia: SNI and Murraylink revisited

    E-Print Network [OSTI]

    Littlechild, Stephen C

    2004-06-16

    This paper examines the history of the various actual and proposed interconnectors between New South Wales and Victoria into South Australia. It covers the period from the earliest proposal for a regulated interconnector to the recent Victoria...

  14. EA-303-A Saracen Merchant Energy, LP | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergy A plug-inPPL EnergyPlus, LLC to export electric energySvcsEmeraTexMexOrderSaracen

  15. El Paso Merchant Energy LP | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EA Jump to:of the NationalDynetekofEcogeoEdipowerEkisolarJorge-

  16. On the oxygen abundance determination in HII regions: High - metallicity regions

    E-Print Network [OSTI]

    L. S. Pilyugin

    2001-01-25

    This is our second paper devoted to the problem of line intensity - oxygen abundance calibration starting from the idea of McGaugh (1991) that the strong oxygen lines contain the necessary information to determine accurate abundances in HII regions. The high-metallicity HII regions are considered. A relation of the type O/H=f(P,R23) between oxygen abundance and the value of abundance index R23 introduced by Pagel et al. (1979) and the excitation parameter P (which is defined here as the contribution of the radiation in [OIII]4959,5007 lines to the "total" oxygen radiation) has been derived empirically using the available oxygen abundances determined via measurement of a temperature-sensitive line ratio [OIII]4959,5007/[OIII]4363 (Te - method). By comparing oxygen abundances derived with the Te - method and those derived with the suggested relations (P - method), it was found that the precision of oxygen abundance determination with the P - method is around 0.1 dex and is comparable to that of the Te - method. A relation of the type Te=f(P,R23) between electron temperature and the values of abundance index R23 and the excitation parameter P was derived empirically using the available electron temperatures determined via measurement of temperature-sensitive line ratios. The mean difference between electron temperatures derived through the Te=f(P,23 relation and determined via measurement of the temperature-sensitive line ratio is around 500K.

  17. Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen K-edge Spectroscopy and Electronic Structure Theory

    SciTech Connect (OSTI)

    Minasian, Stefan G.; Keith, Jason M.; Batista, Enrique R.; Boland, Kevin S.; Bradley, Joseph A.; Daly, Scott R.; Kozimor, Stosh A.; Lukens, Wayne W.; Martin, Richard L.; Nordlund, Dennis; Seidler, Gerald T.; Shuh, David K.; Sokaras, Dimosthenis; Tyliszczak, Tolek; Wagner, Gregory L.; Weng, Tsu-Chien; Yang, Ping

    2013-01-28

    Advancing theories of how metal-oxygen bonding influences metal oxo properties can expose new avenues for innovation in materials science, catalysis, and biochemistry. Historically, spectroscopic analyses of the transition metal MO4x- anions have formed the basis for new M-O bonding theories. Herein, relative changes in M-O orbital mixing in MO42- (M = Cr, Mo, W) and MO4- (M = Mn, Tc, Re) are evaluated for the first time by nonresonant inelastic X-ray scattering, X-ray absorption spectroscopy using fluorescence and transmission (via a scanning transmission X-ray microscope), and time-dependent density functional theory. The results suggest that moving from Group 6 to Group 7 or down the triads increases M-O e* (pi*) mixing; for example, it more than doubles in ReO4- relative to CrO42-. Mixing in the t(2)* orbitals (sigma* + pi*) remains relatively constant within the same Group, but increases on moving from Group 6 to Group 7. These unexpected changes in orbital energy and composition for formally isoelectronic tetraoxometalates are evaluated in terms of periodic trends in d orbital energy and radial extension.

  18. Intragrain oxygen isotope zoning in titanite by SIMS: Cooling rates and fluid infiltration along the Carthage-Colton Mylonite

    E-Print Network [OSTI]

    Meyers, Stephen R.

    Intragrain oxygen isotope zoning in titanite by SIMS: Cooling rates and fluid infiltration along studies because of the ubiquity of oxygen- bearing minerals and the dependence of mineral 18 O/16 O ratios on temperature and fluid composi- tion. In this study, subtle intragrain oxygen isotope zoning in titanite

  19. PII S0016-7037(98)00212-9 Measurement of oxygen fugacities under reducing conditions: Non-Nernstian behavior of

    E-Print Network [OSTI]

    -Nernstian behavior of Y2O3-doped zirconia oxygen sensors R. A. MENDYBAEV,1 J. R. BECKETT,2, * E. STOLPER,2 and L procedure is presented for the use of a Y2O3-stabilized zirconia (YSZ) oxygen sensor in 1 atm gas involved are adequately char- acterized. Yttrium oxide- (YSZ) and calcium oxide-doped (CSZ) zirconia oxygen

  20. The principal function of the cardiopulmonary system is the matching of oxygen and carbon dioxide transport to the

    E-Print Network [OSTI]

    Bennett, Albert F.

    The principal function of the cardiopulmonary system is the matching of oxygen and carbon dioxide (fH), systemic blood flow (Q . sys), rate of oxygen consumption (V . O) and rate of carbon dioxide transport to the metabolic requirements of different tissues. Increased oxygen demands (V . O), for example