National Library of Energy BETA

Sample records for membrane fuel cells

  1. Microcomposite Fuel Cell Membranes

    Broader source: Energy.gov [DOE]

    Summary of microcomposite fuel cell membrane work presented to the High Temperature Membrane Working Group Meeting, Orlando FL, October 17, 2003

  2. Fuel cell membrane humidification

    DOE Patents [OSTI]

    Wilson, Mahlon S. (Los Alamos, NM)

    1999-01-01

    A polymer electrolyte membrane fuel cell assembly has an anode side and a cathode side separated by the membrane and generating electrical current by electrochemical reactions between a fuel gas and an oxidant. The anode side comprises a hydrophobic gas diffusion backing contacting one side of the membrane and having hydrophilic areas therein for providing liquid water directly to the one side of the membrane through the hydrophilic areas of the gas diffusion backing. In a preferred embodiment, the hydrophilic areas of the gas diffusion backing are formed by sewing a hydrophilic thread through the backing. Liquid water is distributed over the gas diffusion backing in distribution channels that are separate from the fuel distribution channels.

  3. Durable Fuel Cell Membrane Electrode Assembly (MEA)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Durable Fuel Cell Membrane Electrode Assembly (MEA) Durable Fuel Cell Membrane Electrode Assembly (MEA) A revolutionary method of building a membrane electrode assembly (MEA) for...

  4. Corrugated Membrane Fuel Cell Structures

    SciTech Connect (OSTI)

    Grot, Stephen President, Ion Power Inc.

    2013-09-30

    One of the most challenging aspects of traditional PEM fuel cell stacks is the difficulty achieving the platinum catalyst utilization target of 0.2 gPt/kWe set forth by the DOE. Good catalyst utilization can be achieved with state-of-the-art catalyst coated membranes (CCM) when low catalyst loadings (<0.3 mg/cm2) are used at a low current. However, when low platinum loadings are used, the peak power density is lower than conventional loadings, requiring a larger total active area and a larger bipolar plate. This results in a lower overall stack power density not meeting the DOE target. By corrugating the fuel cell membrane electrode structure, Ion Power?s goal is to realize both the Pt utilization targets as well as the power density targets of the DOE. This will be achieved by demonstrating a fuel cell single cell (50 cm2) with a twofold increase in the membrane active area over the geometric area of the cell by corrugating the MEA structure. The corrugating structure must be able to demonstrate the target properties of < 10 mOhm-cm2 electrical resistance at > 20 psi compressive strength over the active area, in combination with offering at least 80% of power density that can be achieved by using the same MEA in a flat plate structure. Corrugated membrane fuel cell structures also have the potential to meet DOE power density targets by essentially packaging more membrane area into the same fuel cell volume as compared to conventional stack constructions.

  5. New Membranes for PEM Fuel Cells

    Broader source: Energy.gov [DOE]

    Presentation on New Membranes for PEM Fuel Cells to the High Temperature Membrane Working Group Meeting held in Arlington, Virginia, May 26,2005.

  6. DYNAMIC MODELING PROTON EXCHANGE MEMBRANE FUEL CELL

    E-Print Network [OSTI]

    Mease, Kenneth D.

    DYNAMIC MODELING PROTON EXCHANGE MEMBRANE FUEL CELL OVERVIEW Current/Completed Plug Power to garner SCAQMD funding for fuel cell testing GenCore system is sensitive to diluents · As built design stream to compensate for removal of EGR · Functionality of the modified GenCore Fuel Cell system

  7. Diffuse charge effects in fuel cell membranes

    E-Print Network [OSTI]

    Biesheuvel, P. M.

    It is commonly assumed that electrolyte membranes in fuel cells are electrically neutral, except in unsteady situations, when the double-layer capacitance is heuristically included in equivalent circuit calculations. Indeed, ...

  8. Proton Exchange Membrane Fuel Cells for Electrical Power Generation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Proton Exchange Membrane Fuel Cells for Electrical Power Generation On-Board Commercial Airplanes Proton Exchange Membrane Fuel Cells for Electrical Power Generation On-Board...

  9. Proton conducting membrane for fuel cells

    DOE Patents [OSTI]

    Colombo, Daniel G.; Krumpelt, Michael; Myers, Deborah J.; Kopasz, John P.

    2005-12-20

    An ion conducting membrane comprising dendrimeric polymers covalently linked into a network structure. The dendrimeric polymers have acid functional terminal groups and may be covalently linked via linking compounds, cross-coupling reactions, or copolymerization reactions. The ion conducting membranes may be produced by various methods and used in fuel cells.

  10. Proton conducting membrane for fuel cells

    DOE Patents [OSTI]

    Colombo, Daniel G.; Krumpelt, Michael; Myers, Deborah J.; Kopasz, John P.

    2007-03-27

    An ion conducting membrane comprising dendrimeric polymers covalently linked into a network structure. The dendrimeric polymers have acid functional terminal groups and may be covalently linked via linking compounds, cross-coupling reactions, or copolymerization reactions. The ion conducting membranes may be produced by various methods and used in fuel cells.

  11. Catalytic membranes for fuel cells

    DOE Patents [OSTI]

    Liu, Di-Jia (Naperville, IL); Yang, Junbing (Bolingbrook, IL); Wang, Xiaoping (Naperville, IL)

    2011-04-19

    A fuel cell of the present invention comprises a cathode and an anode, one or both of the anode and the cathode including a catalyst comprising a bundle of longitudinally aligned graphitic carbon nanotubes including a catalytically active transition metal incorporated longitudinally and atomically distributed throughout the graphitic carbon walls of said nanotubes. The nanotubes also include nitrogen atoms and/or ions chemically bonded to the graphitic carbon and to the transition metal. Preferably, the transition metal comprises at least one metal selected from the group consisting of Fe, Co, Ni, Mn, and Cr.

  12. Alternate Fuel Cell Membranes for Energy Independence

    SciTech Connect (OSTI)

    Storey, Robson, F.; Mauritz, Kenneth, A.; Patton, Derek, L.; Savin, Daniel, A.

    2012-12-18

    The overall objective of this project was the development and evaluation of novel hydrocarbon fuel cell (FC) membranes that possess high temperature performance and long term chemical/mechanical durability in proton exchange membrane (PEM) fuel cells (FC). The major research theme was synthesis of aromatic hydrocarbon polymers of the poly(arylene ether sulfone) (PAES) type containing sulfonic acid groups tethered to the backbone via perfluorinated alkylene linkages and in some cases also directly attached to the phenylene groups along the backbone. Other research themes were the use of nitrogen-based heterocyclics instead of acid groups for proton conduction, which provides high temperature, low relative humidity membranes with high mechanical/thermal/chemical stability and pendant moieties that exhibit high proton conductivities in the absence of water, and synthesis of block copolymers consisting of a proton conducting block coupled to poly(perfluorinated propylene oxide) (PFPO) blocks. Accomplishments of the project were as follows: 1) establishment of a vertically integrated program of synthesis, characterization, and evaluation of FC membranes, 2) establishment of benchmark membrane performance data based on Nafion for comparison to experimental membrane performance, 3) development of a new perfluoroalkyl sulfonate monomer, N,N-diisopropylethylammonium 2,2-bis(p-hydroxyphenyl) pentafluoropropanesulfonate (HPPS), 4) synthesis of random and block copolymer membranes from HPPS, 5) synthesis of block copolymer membranes containing high-acid-concentration hydrophilic blocks consisting of HPPS and 3,3'-disulfonate-4,4'-dichlorodiphenylsulfone (sDCDPS), 6) development of synthetic routes to aromatic polymer backbones containing pendent 1H-1,2,3-triazole moieties, 7) development of coupling strategies to create phase-separated block copolymers between hydrophilic sulfonated prepolymers and commodity polymers such as PFPO, 8) establishment of basic performance properties of experimental membranes, 9) fabrication and FC performance testing of membrane electrode assemblies (MEA) from experimental membranes, and 10) measurement of ex situ and in situ membrane durability of experimental membranes. Although none of the experimental hydrocarbon membranes that issued from the project displayed proton conductivities that met DOE requirements, the project contributed to our basic understanding of membrane structure-property relationships in a number of key respects. An important finding of the benchmark studies is that physical degradation associated with humidity and temperature variations in the FC tend to open new fuel crossover pathways and act synergistically with chemical degradation to accelerate overall membrane degradation. Thus, for long term membrane survival and efficient fuel utilization, membranes must withstand internal stresses due to humidity and temperature changes. In this respect, rigid aromatic hydrocarbon fuel cell membranes, e.g. PAES, offer an advantage over un-modified Nafion membranes. The benchmark studies also showed that broadband dielectric spectroscopy is a potentially powerful tool in assessing shifts in the fundamental macromolecular dynamics caused by Nafion chemical degradation, and thus, this technique is of relevance in interrogating proton exchange membrane durability in fuel cells and macromolecular dynamics as coupled to proton migration, which is of fundamental relevance in proton exchange membranes in fuel cells. A key finding from the hydrocarbon membrane synthesis effort was that rigid aromatic polymers containing isolated ion exchange groups tethered tightly to the backbone (short tether), such as HPPS, provide excellent mechanical and durability properties but do not provide sufficient conductivity, in either random or block configuration, when used as the sole ion exchange monomer. However, we continue to hypothesize that longer tethers, and tethered groups spaced more closely within the hydrophilic chain elements of the polymer, will yield highly conductive materials with excellent mech

  13. Fuel cell membranes and crossover prevention

    DOE Patents [OSTI]

    Masel, Richard I. (Champaign, IL); York, Cynthia A. (Newington, CT); Waszczuk, Piotr (White Bear Lake, MN); Wieckowski, Andrzej (Champaign, IL)

    2009-08-04

    A membrane electrode assembly for use with a direct organic fuel cell containing a formic acid fuel includes a solid polymer electrolyte having first and second surfaces, an anode on the first surface and a cathode on the second surface and electrically linked to the anode. The solid polymer electrolyte has a thickness t:.gtoreq..times..times..times..times. ##EQU00001## where C.sub.f is the formic acid fuel concentration over the anode, D.sub.f is the effective diffusivity of the fuel in the solid polymer electrolyte, K.sub.f is the equilibrium constant for partition coefficient for the fuel into the solid polymer electrolyte membrane, I is Faraday's constant n.sub.f is the number of electrons released when 1 molecule of the fuel is oxidized, and j.sub.f.sup.c is an empirically determined crossover rate of fuel above which the fuel cell does not operate.

  14. Advanced membrane electrode assemblies for fuel cells

    DOE Patents [OSTI]

    Kim, Yu Seung; Pivovar, Bryan S

    2014-02-25

    A method of preparing advanced membrane electrode assemblies (MEA) for use in fuel cells. A base polymer is selected for a base membrane. An electrode composition is selected to optimize properties exhibited by the membrane electrode assembly based on the selection of the base polymer. A property-tuning coating layer composition is selected based on compatibility with the base polymer and the electrode composition. A solvent is selected based on the interaction of the solvent with the base polymer and the property-tuning coating layer composition. The MEA is assembled by preparing the base membrane and then applying the property-tuning coating layer to form a composite membrane. Finally, a catalyst is applied to the composite membrane.

  15. Advanced membrane electrode assemblies for fuel cells

    DOE Patents [OSTI]

    Kim, Yu Seung; Pivovar, Bryan S.

    2012-07-24

    A method of preparing advanced membrane electrode assemblies (MEA) for use in fuel cells. A base polymer is selected for a base membrane. An electrode composition is selected to optimize properties exhibited by the membrane electrode assembly based on the selection of the base polymer. A property-tuning coating layer composition is selected based on compatibility with the base polymer and the electrode composition. A solvent is selected based on the interaction of the solvent with the base polymer and the property-tuning coating layer composition. The MEA is assembled by preparing the base membrane and then applying the property-tuning coating layer to form a composite membrane. Finally, a catalyst is applied to the composite membrane.

  16. Fuel cell subassemblies incorporating subgasketed thrifted membranes

    DOE Patents [OSTI]

    Iverson, Eric J; Pierpont, Daniel M; Yandrasits, Michael A; Hamrock, Steven J; Obradovich, Stephan J; Peterson, Donald G

    2014-01-28

    A fuel cell roll good subassembly is described that includes a plurality of individual electrolyte membranes. One or more first subgaskets are attached to the individual electrolyte membranes. Each of the first subgaskets has at least one aperture and the first subgaskets are arranged so the center regions of the individual electrolyte membranes are exposed through the apertures of the first subgaskets. A second subgasket comprises a web having a plurality of apertures. The second subgasket web is attached to the one or more first subgaskets so the center regions of the individual electrolyte membranes are exposed through the apertures of the second subgasket web. The second subgasket web may have little or no adhesive on the subgasket surface facing the electrolyte membrane.

  17. Model Compound Studies of Fuel Cell Membrane Degradation

    Broader source: Energy.gov [DOE]

    Presentation on Model Compound Studies of Fuel Cell Membrane Degradation to the High Temperature Membrane Working Group Meeting held in Arlington, Virginia, May 26,2005.

  18. Development of Advanced High Temperature Fuel Cell Membranes

    Broader source: Energy.gov [DOE]

    Presentation on Development of Advanced High Temperature Fuel Cell Membranes to the High Temperature Membrane Working Group Meeting held in Arlington, Virginia, May 26,2005.

  19. Alternate Fuel Cell Membranes at the University of Southern Mississipp...

    Broader source: Energy.gov (indexed) [DOE]

    of Southern Mississippi studied structure-property relationships in order to develop fuel cell membranes capable of operating at high temperatures. As fuel cells must be able...

  20. Fuel cell membrane hydration and fluid metering

    DOE Patents [OSTI]

    Jones, Daniel O. (Glenville, NY); Walsh, Michael M. (Fairfield, CT)

    2003-01-01

    A hydration system includes fuel cell fluid flow plate(s) and injection port(s). Each plate has flow channel(s) with respective inlet(s) for receiving respective portion(s) of a given stream of reactant fluid for a fuel cell. Each injection port injects a portion of liquid water directly into its respective flow channel. This serves to hydrate at least corresponding part(s) of a given membrane of the corresponding fuel cell(s). The hydration system may be augmented by a metering system including flow regulator(s). Each flow regulator meters an injecting at inlet(s) of each plate of respective portions of liquid into respective portion(s) of a given stream of fluid by corresponding injection port(s).

  1. Fuel cell membrane hydration and fluid metering

    DOE Patents [OSTI]

    Jones, Daniel O. (Glenville, NY); Walsh, Michael M. (Fairfield, CT)

    1999-01-01

    A hydration system includes fuel cell fluid flow plate(s) and injection port(s). Each plate has flow channel(s) with respective inlet(s) for receiving respective portion(s) of a given stream of reactant fluid for a fuel cell. Each injection port injects a portion of liquid water directly into its respective flow channel in order to mix its respective portion of liquid water with the corresponding portion of the stream. This serves to hydrate at least corresponding part(s) of a given membrane of the corresponding fuel cell(s). The hydration system may be augmented by a metering system including flow regulator(s). Each flow regulator meters an injecting at inlet(s) of each plate of respective portions of liquid into respective portion(s) of a given stream of fluid by corresponding injection port(s).

  2. The Path a Proton Takes Through a Fuel Cell Membrane

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Path a Proton Takes Through a Fuel Cell Membrane The Path a Proton Takes Through a Fuel Cell Membrane October 11, 2012 Linda Vu, lvu@lbl.gov, +1 510 495 2402 Ram.jpg The cover...

  3. 2007 Status of Manufacturing: Polymer Electrolyte Membrane (PEM) Fuel Cells

    SciTech Connect (OSTI)

    Wheeler, D.; Sverdrup, G.

    2008-03-01

    In this document we assess the North American industry's current ability to manufacture polymer electrolyte membrane (PEM) fuel cells.

  4. Investigation of Transient Phenomena of Proton Exchange Membrane Fuel Cells

    E-Print Network [OSTI]

    Victoria, University of

    Investigation of Transient Phenomena of Proton Exchange Membrane Fuel Cells by Roongrojana of Proton Exchange Membrane Fuel Cells by Roongrojana Songprakorp BSc, Prince of Songkhla University to the modeling and under- standing of the dynamic behavior of proton exchange membrane fuel cells (PEMFCs

  5. Nonminimum-Phase Phenomenon of PEM Fuel Cell Membrane

    E-Print Network [OSTI]

    Peng, Huei

    Nonminimum-Phase Phenomenon of PEM Fuel Cell Membrane Humidifiers Dongmei Chen Huei Peng1 Professor 48109-2125 A membrane-based humidifier that uses cooling water of a fuel cell system to humidify electrolyte membrane fuel cells PEMFCs have drawn much attention from industries and academia in recent years

  6. Water Visualization and Flooding in Polymer Electrolyte Membrane Fuel Cells

    E-Print Network [OSTI]

    Petta, Jason

    Water Visualization and Flooding in Polymer Electrolyte Membrane Fuel Cells Brian Holsclaw West- 2H2O e- e- e- e- e- H+ H+ H+ Membrane + Schematic of a PEMFC Operation #12;PFR PEM Fuel Cell Plug for membrane Two-phase flow in channels #12;CSTR PEM Fuel Cell Continuous Stirred-Tank Reactor (CSTR) "Perfect

  7. Membrane processes relevant for the polymer electrolyte fuel cell

    E-Print Network [OSTI]

    Kjelstrup, Signe

    Membrane processes relevant for the polymer electrolyte fuel cell Aleksander Kolstad Chemical. The important aspects concerning the Polymer Electrolyte Membrane Fuel Cell, more commonly known as Proton Exchange Membrane Fuel Cell (PEMFC), have been studied in two separate parts. Part 1 of the thesis

  8. Nafion-sepiolite composite membranes for improved Proton Exchange Membrane Fuel Cell performance.

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Nafion®-sepiolite composite membranes for improved Proton Exchange Membrane Fuel Cell performance, characterized and integrated in Membrane-Electrodes Assembly to be tested in fuel cell operating conditions, mobile or stationary), Proton Exchange Membrane Fuel Cells (PEMFC) are amongst the most studied fuel

  9. Membrane catalyst layer for fuel cells

    DOE Patents [OSTI]

    Wilson, Mahlon S. (Los Alamos, NM)

    1993-01-01

    A gas reaction fuel cell incorporates a thin catalyst layer between a solid polymer electrolyte (SPE) membrane and a porous electrode backing. The catalyst layer is preferably less than about 10 .mu.m in thickness with a carbon supported platinum catalyst loading less than about 0.35 mgPt/cm.sup.2. The film is formed as an ink that is spread and cured on a film release blank. The cured film is then transferred to the SPE membrane and hot pressed into the surface to form a catalyst layer having a controlled thickness and catalyst distribution. Alternatively, the catalyst layer is formed by applying a Na.sup.+ form of a perfluorosulfonate ionomer directly to the membrane, drying the film at a high temperature, and then converting the film back to the protonated form of the ionomer. The layer has adequate gas permeability so that cell performance is not affected and has a density and particle distribution effective to optimize proton access to the catalyst and electronic continuity for electron flow from the half-cell reaction occurring at the catalyst.

  10. Computational Modeling and Optimization of Proton Exchange Membrane Fuel Cells

    E-Print Network [OSTI]

    Victoria, University of

    Computational Modeling and Optimization of Proton Exchange Membrane Fuel Cells by Marc Secanell and Optimization of Proton Exchange Membrane Fuel Cells by Marc Secanell Gallart Bachelor in Engineering cells. In this thesis, a computational framework for fuel cell analysis and optimization is presented

  11. Blend Membranes of Highly Phosphonated Polysulfone and Polybenzimidazoles for High Temperature Proton Exchange Membrane Fuel Cells

    E-Print Network [OSTI]

    Potrekar, Ravindra

    2014-01-01

    Energy, Office of Hydrogen, Fuel Cells and InfrastructureD. Kreuer, and J. Maier, Fuel Cells 5, 335 2. M. A. Hickner,Proton Exchange Membrane Fuel Cells R. A. Potrekar † , K. T.

  12. Design and optimization of polymer electrolyte membrane (PEM) fuel cells

    E-Print Network [OSTI]

    Grujicic, Mica

    Design and optimization of polymer electrolyte membrane (PEM) fuel cells M. Grujicic* , K optimization algorithm to determine an optimum design of the fuel cell with respect to the operation difference has the largest effect on the predicted polarization curve of the fuel cell. However, the optimal

  13. Polymer-electrolyte membrane, electrochemical fuel cell, and related method

    DOE Patents [OSTI]

    Krishnan, Lakshmi; Yeager, Gary William; Soloveichik, Grigorii Lev

    2014-12-09

    A polymer-electrolyte membrane is presented. The polymer-electrolyte membrane comprises an acid-functional polymer, and an additive incorporated in at least a portion of the membrane. The additive comprises a fluorinated cycloaliphatic additive, a hydrophobic cycloaliphatic additive, or combinations thereof, wherein the additive has a boiling point greater than about 120.degree. C. An electrochemical fuel cell including the polymer-electrolyte membrane, and a related method, are also presented.

  14. Using Fuel Cell Membranes to Improve Power

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservationBio-Inspired SolarAbout /Two0 - 19PortalStatusUserUserHome AccountFuel Cell

  15. Durable Fuel Cell Membrane Electrode Assembly (MEA)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit theCovalentLaboratory |Sectorfor $1.14 Per1-E WholesaleDurable Fuel Cell

  16. Interferometric tomography of fuel cells for monitoring membrane water content

    E-Print Network [OSTI]

    Waller, Laura

    We have developed a system that uses two 1D interferometric phase projections for reconstruction of 2D water content changes over time in situ in a proton exchange membrane (PEM) fuel cell system. By modifying the filtered ...

  17. Corrugated Membrane Fuel Cell Structures | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based Fuels|ProgramsLakeDepartment ofofCorrugated Membrane Fuel Cell Structures

  18. Catalytic membranes for CO oxidation in fuel cells

    DOE Patents [OSTI]

    Sandi-Tapia, Giselle; Carrado Gregar, Kathleen; Kizilel, Riza

    2010-06-08

    A hydrogen permeable membrane, which includes a polymer stable at temperatures of about 200 C having clay impregnated with Pt or Au or Ru or Pd particles or mixtures thereof with average diameters of less than about 10 nanometers (nms) is disclosed. The membranes are useful in fuel cells or any device which requires hydrogen to be separated from carbon monoxide.

  19. Improved Membrane Materials for PEM Fuel Cell Application

    SciTech Connect (OSTI)

    Kenneth A. Mauritz; Robert B. Moore

    2008-06-30

    The overall goal of this project is to collect and integrate critical structure/property information in order to develop methods that lead to significant improvements in the durability and performance of polymer electrolyte membrane fuel cell (PEMFC) materials. This project is focused on the fundamental improvement of PEMFC membrane materials with respect to chemical, mechanical and morphological durability as well as the development of new inorganically-modified membranes.

  20. Proton Transport and the Water Environment in Nafion Fuel Cell Membranes and AOT Reverse Micelles

    E-Print Network [OSTI]

    Fayer, Michael D.

    Proton Transport and the Water Environment in Nafion Fuel Cell Membranes and AOT Reverse Micelles D channels of Nafion fuel cell membranes at various hydration levels are compared to water in a series by its use as a proton conducting membrane in fuel cells. Nafion membranes in fuel cells allow protons

  1. Fuel cell electrolyte membrane with acidic polymer

    DOE Patents [OSTI]

    Hamrock, Steven J. (Stillwater, MN); Larson, James M. (Saint Paul, MN); Pham, Phat T. (Little Canada, MN); Frey, Matthew H. (Cottage Grove, MN); Haugen, Gregory M. (Edina, MN); Lamanna, William M. (Stillwater, MN)

    2009-04-14

    An electrolyte membrane is formed by an acidic polymer and a low-volatility acid that is fluorinated, substantially free of basic groups, and is either oligomeric or non-polymeric.

  2. Proton exchange membrane fuel cells with chromium nitride nanocrystals as electrocatalysts

    E-Print Network [OSTI]

    Zhong, Hexiang; Chen, Xiaobo; Zhang, Huamin; Wang, Meiri; Mao, Samuel S.

    2007-01-01

    S. Srinivasan, V. Antonucci, Fuel Cells 1, 133 (2001). 15 Y.Proton exchange membrane fuel cells with chromium nitridePolymer electrolyte membrane fuel cells (PEMFCs) are energy

  3. Recent developments in proton exchange membranes for fuel cells

    SciTech Connect (OSTI)

    Devanathan, Ramaswami

    2008-07-23

    Proton exchange membranes (PEMs) that operate at temperatures above 120 °C are needed to avoid catalyst poisoning, speed up electrochemical reactions, simplify the design and reduce the cost of fuel cells. This review summarizes developments in PEMs over the last five years. In order to design new membranes for elevated temperature operation, one must understand the chemistry, morphology and dynamics of protons and small molecules in existing membranes. The integration of experiments with modeling and simulation can shed light on the hierarchical structure of the membrane and dynamical processes associated with molecular transport. Based on such a fundamental understanding, membranes can be modified by controlling the polymer chemistry and architecture or adding inorganic fillers that can retain water under low relative humidity conditions. In addition, the development of anhydrous membranes based on phosphoric acid doped polymers, ionic liquid-infused polymer gels and solid acids can enable fuel cell operation above 150 °C. Considerable work remains to be done to identify proton transport mechanisms in novel membranes and evaluate membrane durability under real world operating conditions.

  4. Fuel cell electrolyte membrane with basic polymer

    DOE Patents [OSTI]

    Larson, James M.; Pham, Phat T.; Frey, Matthew H.; Hamrock, Steven J.; Haugen, Gregory M.; Lamanna, William M.

    2012-12-04

    The present invention is an electrolyte membrane comprising an acid and a basic polymer, where the acid is a low-volatile acid that is fluorinated and is either oligomeric or non-polymeric, and where the basic polymer is protonated by the acid and is stable to hydrolysis.

  5. Fuel cell electrolyte membrane with basic polymer

    DOE Patents [OSTI]

    Larson, James M. (Saint Paul, MN); Pham, Phat T. (Little Canada, MN); Frey, Matthew H. (Cottage Grove, MN); Hamrock, Steven J. (Stillwater, MN); Haugen, Gregory M. (Edina, MN); Lamanna, William M. (Stillwater, MN)

    2010-11-23

    The present invention is an electrolyte membrane comprising an acid and a basic polymer, where the acid is a low-volatile acid that is fluorinated and is either oligomeric or non-polymeric, and where the basic polymer is protonated by the acid and is stable to hydrolysis.

  6. Performance modelling of a proton exchange membrane fuel cell

    SciTech Connect (OSTI)

    Marr, C.; Li, X.

    1998-12-31

    This paper presents a performance model of a proton exchange membrane fuel cell that has sufficient accuracy for engineering applications with reduced computational requirements. The model includes electrochemical reaction in the catalyst layers and formulation for electrical resistance in the membrane, electrodes and bipolar plates, and employs engineering correlation for the reactant gas transport in the flow channels and through the electrodes. It is shown that the present model predictions are in reasonable agreement with known experimental observations, indicating that the present model can be employed for fuel cell stack and system modeling. The effect of various operating and design parameters on the cell performance has been investigated. It is found that mass transport limitations are the largest cause of performance loss in the cell when graphite is used as the material for bipolar plates and electrodes. If conducting polymers are substituted as construction materials, cell performance is expected to suffer considerably at high current densities due to their reduced electrical conductivity.

  7. Theory of proton exchange membranes fuel cells and the testing of performance characteristics of polymer electrolyte membranes

    E-Print Network [OSTI]

    Cruz-Gonzalez, Tizoc, 1982-

    2004-01-01

    Proton exchange membrane (PEM) fuel cells hold great promise as source of power. A hydrogen and oxygen PEM fuel is a simple fuel cell that can be theoretically characterized. The performance of a PEM fuel cell can be ...

  8. Arylene-fluorinated-sulfonimide ionomers and membranes for fuel cells

    DOE Patents [OSTI]

    Teasley, Mark F. (Landenberg, PA)

    2011-11-15

    The preparation of aromatic sulfonimide polymers useful as membranes in electrochemical cells is described.

  9. InVited Feature Article Water Dynamics and Proton Transfer in Nafion Fuel Cell Membranes

    E-Print Network [OSTI]

    Fayer, Michael D.

    InVited Feature Article Water Dynamics and Proton Transfer in Nafion Fuel Cell Membranes David E is the most widely used polyelectrolyte membrane in fuel cells. Ultrafast infrared spectroscopy of the O but has since become the most commonly used membrane separator in polymer electrolyte membrane fuel cells

  10. PROTON EXCHANGE MEMBRANE FUEL CELL OPERATION AND DEGRADATION IN SHORT-CIRCUIT

    E-Print Network [OSTI]

    Boyer, Edmond

    PROTON EXCHANGE MEMBRANE FUEL CELL OPERATION AND DEGRADATION IN SHORT-CIRCUIT R.E. Silvaa, b, d , F exchange membrane fuel cells, short circuit, degradation mechanism, electrochemical impedance spectroscopy an electrical short circuit of a proton exchange membrane fuel cell stack. The physical quantities in the fuel

  11. Computer Modeling Illuminates Degradation Pathways of Cations in Alkaline Membrane Fuel Cells (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-08-01

    Cation degradation insights obtained by computational modeling could result in better performance and longer lifetime for alkaline membrane fuel cells.

  12. Percolation in a Proton Exchange Membrane Fuel Cell Catalyst Layer

    SciTech Connect (OSTI)

    Stacy, Stephen; Allen, Jeffrey

    2012-07-01

    Water management in the catalyst layers of proton exchange membrane fuel cells (PEMFC) is confronted by two issues, flooding and dry out, both of which result in improper functioning of the fuel cell and lead to poor performance and degradation. At the present time, the data that has been reported about water percolation and wettability within a fuel cell catalyst layer is limited. A method and apparatus for measuring the percolation pressure in the catalyst layer has been developed based upon an experimental apparatus used to test water percolation in porous transport layers (PTL). The experimental setup uses a pseudo Hele-Shaw type testing where samples are compressed and a fluid is injected into the sample. Testing the samples gives percolation pressure plots which show trends in increasing percolation pressure with an increase in flow rate. A decrease in pressure was seen as percolation occurred in one sample, however the pressure only had a rising effect in the other sample.

  13. Alkaline membrane fuel cells with in-situ cross-linked ionomers Yongjun Leng a

    E-Print Network [OSTI]

    optimization is needed for the commercialization of alkaline membrane fuel cell (AMFC) technologiesAlkaline membrane fuel cells with in-situ cross-linked ionomers Yongjun Leng a , Lizhu Wang b membrane fuel cell (AMFC) in-situ cross-linking ionomer net water transport coefficient A B S T R A C

  14. Three steps in the anode reaction of the polymer electrolyte membrane fuel cell. Effect of CO

    E-Print Network [OSTI]

    Kjelstrup, Signe

    Three steps in the anode reaction of the polymer electrolyte membrane fuel cell. Effect of CO Anne in the polymer electrolyte membrane fuel cell (PEMFC) using electrochemical impedance spectroscopy (EIS mechanism 1. Introduction In the polymer electrolyte membrane fuel cell (PEMFC), the largest overpotential

  15. Diffuse Charge Effects in Fuel Cell Membranes P. Maarten Biesheuvel,a,b,z

    E-Print Network [OSTI]

    Bazant, Martin Z.

    Diffuse Charge Effects in Fuel Cell Membranes P. Maarten Biesheuvel,a,b,z Alejandro A. Franco membranes in fuel cells are electrically neutral, except in unsteady situations, when the double pressure, which is a thermodynamic constant of the fuel cell membrane. Diffuse layer polarization

  16. Proton Exchange Membrane Fuel Cell Characterization for Electric Vehicle Applications

    E-Print Network [OSTI]

    Swan, D.H.; Dickinson, B.E.; Arikara, M.P.

    1994-01-01

    Fuel CelL/Battery HybridSystemfor Electric Vehicle Applications",Fuel Cell Characterization for Electric Vehicle Applicationsthe fuel cell ~stemfor electric vehicle applications. Where

  17. Electrochemistry of Fuel Cells and Batteries (ME/MS 545) Course Description: Electrochemistry of fuel cells, batteries, sensors, membrane

    E-Print Network [OSTI]

    Lin, Xi

    Electrochemistry of Fuel Cells and Batteries (ME/MS 545) Course Description: Electrochemistry of fuel cells, batteries, sensors, membrane separation and electrolytic methods are discussed J. Bard and Larry R. Faulkner, John Wiley. Recommended/reference text: Fuel Cell Handbook 7, DOE

  18. 2011 Alkaline Membrane Fuel Cell Workshop Final Report

    SciTech Connect (OSTI)

    Pivovar, B.

    2012-02-01

    A workshop addressing the current state-of-the-art in alkaline membrane fuel cells (AMFCs) was held May 8-9, 2011, at the Crystal Gateway Marriott in Arlington, Virginia. This workshop was the second of its kind, with the first being held December 11-13, 2006, in Phoenix, Arizona. The 2011 workshop and associated workshop report were created to assess the current state of AMFC technology (taking into account recent advances), investigate the performance potential of AMFC systems across all possible power ranges and applications, and identify the key research needs for commercial competitiveness in a variety of areas.

  19. Proton Exchange Membrane Fuel Cell degradation prediction based on Adaptive Neuro Fuzzy Inference Systems

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Proton Exchange Membrane Fuel Cell degradation prediction based on Adaptive Neuro Fuzzy Inference online XX XX XXXX Keywords: Proton Exchange Membrane fuel cell degradation, Prognostic and Health nominal operating condition of a PEM fuel cell stack. It proposes a methodology based on Adaptive Neuro

  20. Control of the mass and energy dynamics of polybenzimidazole-membrane fuel cells

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Control of the mass and energy dynamics of polybenzimidazole-membrane fuel cells Federico Zenith-temperature proton- exchange-membrane fuel cell are investigated. For a particular configuration, three lumped the necessary conditions for the fuel-cell stack to operate. It is possible to control temperature by using only

  1. Aalborg Universitet Modelling and Validation of Water Hydration of PEM Fuel Cell Membrane in Dynamic

    E-Print Network [OSTI]

    Liso, Vincenzo

    Aalborg Universitet Modelling and Validation of Water Hydration of PEM Fuel Cell Membrane of Water Hydration of PEM Fuel Cell Membrane in Dynamic Operations. In ECS Transactions. (Vol. 68). ECS from vbn.aau.dk on: november 29, 2015 #12;Modelling and Validation of Water Hydration of PEM Fuel Cell

  2. Growth of Pt nanoparticle for proton-exchange-membrane fuel cells by

    E-Print Network [OSTI]

    PEMFC Growth of Pt nanoparticle for proton-exchange-membrane fuel cells at anode side of a polymer electrolyte membrane (PEM) fuel cell. With a Pt loading of 25 g-Pt/cm2 , current of the electrochemical test result and fuel cell performance agree with each other. Key word : Pulsed laser deposition

  3. Isothermal Ice-Crystallization Kinetics in the Gas-Diffusion Layer of a Proton-Exchange-Membrane Fuel Cell

    E-Print Network [OSTI]

    Dursch, Thomas J.

    2013-01-01

    Renewable Energy, Office of Fuel Cell Technologies, of theProton-Exchange- Membrane Fuel Cell T. J. Dursch, 1,2 M. A.proton-exchange membrane fuel cell (PEMFC) are investigated

  4. Investigation of the performance and water transport of a polymer electrolyte membrane (pem) fuel cell 

    E-Print Network [OSTI]

    Park, Yong Hun

    2009-05-15

    Fuel cell performance was obtained as functions of the humidity at the anode and cathode sites, back pressure, flow rate, temperature, and channel depth. The fuel cell used in this work included a membrane and electrode assembly (MEA) which...

  5. Growth of Carbon Support for Proton-Exchange-Membrane Fuel Cell by

    E-Print Network [OSTI]

    Growth of Carbon Support for Proton-Exchange-Membrane Fuel Cell by Pulsed-Laser Deposition (PLDGDL)(catalyst) (pulsed laser deposition PLD) (plasma plume) () #12;III Abstract key word: Fuel CellPulsed Laser. People begin to develop fuel cells for seeking alternative energy sources. Fuel cell use the chemical

  6. Economics of Direct Hydrogen Polymer Electrolyte Membrane Fuel Cell Systems

    SciTech Connect (OSTI)

    Mahadevan, Kathyayani

    2011-10-04

    Battelle's Economic Analysis of PEM Fuel Cell Systems project was initiated in 2003 to evaluate the technology and markets that are near-term and potentially could support the transition to fuel cells in automotive markets. The objective of Battelle?s project was to assist the DOE in developing fuel cell systems for pre-automotive applications by analyzing the technical, economic, and market drivers of direct hydrogen PEM fuel cell adoption. The project was executed over a 6-year period (2003 to 2010) and a variety of analyses were completed in that period. The analyses presented in the final report include: Commercialization scenarios for stationary generation through 2015 (2004); Stakeholder feedback on technology status and performance status of fuel cell systems (2004); Development of manufacturing costs of stationary PEM fuel cell systems for backup power markets (2004); Identification of near-term and mid-term markets for PEM fuel cells (2006); Development of the value proposition and market opportunity of PEM fuel cells in near-term markets by assessing the lifecycle cost of PEM fuel cells as compared to conventional alternatives used in the marketplace and modeling market penetration (2006); Development of the value proposition of PEM fuel cells in government markets (2007); Development of the value proposition and opportunity for large fuel cell system application at data centers and wastewater treatment plants (2008); Update of the manufacturing costs of PEM fuel cells for backup power applications (2009).

  7. Process for recycling components of a PEM fuel cell membrane electrode assembly

    DOE Patents [OSTI]

    Shore, Lawrence (Edison, NJ)

    2012-02-28

    The membrane electrode assembly (MEA) of a PEM fuel cell can be recycled by contacting the MEA with a lower alkyl alcohol solvent which separates the membrane from the anode and cathode layers of the assembly. The resulting solution containing both the polymer membrane and supported noble metal catalysts can be heated under mild conditions to disperse the polymer membrane as particles and the supported noble metal catalysts and polymer membrane particles separated by known filtration means.

  8. Computational Modeling of Electrolyte/Cathode Interfaces in Proton Exchange Membrane Fuel Cells

    E-Print Network [OSTI]

    Bjørnstad, Ottar Nordal

    Computational Modeling of Electrolyte/Cathode Interfaces in Proton Exchange Membrane Fuel Cells Dr Proton exchange membrane fuel cells (PEMFCs) are alternative energy conversion devices that efficiently. The fundamental relationship between operating conditions and device performance will help to optimize the device

  9. Low Crossover of Methanol and Water Through Thin Membranes in Direct Methanol Fuel Cells

    E-Print Network [OSTI]

    Low Crossover of Methanol and Water Through Thin Membranes in Direct Methanol Fuel Cells Fuqiang State University, University Park, Pennsylvania 16802, USA Low crossover of both methanol and water through a polymer membrane in a direct methanol fuel cell DMFC is essential for using high concentration

  10. Proton Exchange Membrane Fuel Cell Characterization for Electric Vehicle Applications

    E-Print Network [OSTI]

    Swan, D.H.; Dickinson, B.E.; Arikara, M.P.

    1994-01-01

    Characterization for Electric Vehicle Applications D.H. SwanHybridSystemfor Electric Vehicle Applications", SAEPaperFuel Cells for Electric Vehicles, Knowledge Gaps and

  11. A Mathematical Model for Predicting the Life of PEM Fuel Cell Membranes Subjected to Hydration Cycling

    E-Print Network [OSTI]

    Burlatsky, S F; O'Neill, J; Atrazhev, V V; Varyukhin, A N; Dmitriev, D V; Erikhman, N S

    2013-01-01

    Under typical PEM fuel cell operating conditions, part of membrane electrode assembly is subjected to humidity cycling due to variation of inlet gas RH and/or flow rate. Cyclic membrane hydration/dehydration would cause cyclic swelling/shrinking of the unconstrained membrane. In a constrained membrane, it causes cyclic stress resulting in mechanical failure in the area adjacent to the gas inlet. A mathematical modeling framework for prediction of the lifetime of a PEM FC membrane subjected to hydration cycling is developed in this paper. The model predicts membrane lifetime as a function of RH cycling amplitude and membrane mechanical properties. The modeling framework consists of three model components: a fuel cell RH distribution model, a hydration/dehydration induced stress model that predicts stress distribution in the membrane, and a damage accrual model that predicts membrane life-time. Short descriptions of the model components along with overall framework are presented in the paper. The model was used...

  12. An Investigation of Different Methods of Fabricating Membrane Electrode Assemblies for Methanol Fuel Cells

    E-Print Network [OSTI]

    Hall, Kwame (Kwame J.)

    2009-01-01

    Methanol fuel cells are electrochemical conversion devices that produce electricity from methanol fuel. The current process of fabricating membrane electrode assemblies (MEAs) is tedious and if it is not sufficiently ...

  13. A sandwich structured membrane for direct methanol fuel cells operating with neat methanol

    E-Print Network [OSTI]

    Zhao, Tianshou

    A sandwich structured membrane for direct methanol fuel cells operating with neat methanol Q.X. Wu i g h t s " A sandwich structured membrane for DMFCs operating with neat methanol is proposed. " The membrane offers better water management for DMFCs operating with neat methanol. " The sandwich structured

  14. Comparison of platinum deposit methods on carbon aerogels used in Proton Exchange Membrane Fuel Cells (PEMFC)

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    to be taken up. Consequently, a strong research effort is devoted to cleaner energy converters like fuel cells. In the car industry, Proton Exchange Membrane Fuel Cells (PEMFC) are chosen by a majority. But, remaining on the performances of new electrocatalysts and to the understanding of phenomena occurring in fuel cells. Nowadays

  15. Membranes produced by PECVD technique for low temperature fuel cell applications

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Membranes produced by PECVD technique for low temperature fuel cell applications Aboubakr to manufacture by plasma processes all active layers of fuel cells cores to be integrated in original compact stability; Transport properties. 1. Introduction Micro fuel cells have received considerable attention over

  16. Transient Analysis of Proton Electrolyte Membrane Fuel Cells (PEMFC) at Start-Up

    E-Print Network [OSTI]

    Yanikoglu, Berrin

    Transient Analysis of Proton Electrolyte Membrane Fuel Cells (PEMFC) at Start-Up and Failure M. F perfor- mance of the fuel cell has already been reported, when inter- digitated flow fields are used [1 with experiments to study the effect of temperature, humidity, and pressure on fuel cell performance

  17. Affordable Hydrogen Fuel Cell Vehicles: Quaternary Phosphonium Based Hydroxide Exchange Membranes

    SciTech Connect (OSTI)

    2010-01-01

    Broad Funding Opportunity Announcement Project: The University of Delaware is developing a new fuel cell membrane for vehicles that relies on cheaper and more abundant materials than those used in current fuel cells. Conventional fuel cells are very acidic, so they require acid-resistant metals like platinum to generate electricity. The University of Delaware is developing an alkaline fuel cell membrane that can operate in a non-acidic environment where cheaper materials like nickel and silver, instead of platinum, can be used. In addition to enabling the use of cheaper metals, the University of Delaware’s membrane is 500 times less expensive than other polymer membranes used in conventional fuel cells.

  18. Alkaline Membrane Fuel Cell System Break-Out Session

    E-Print Network [OSTI]

    incumbent battery and Gensets for stationary application ­ Significant price advantage over PEM fuel cells levels Application Description Power range Military Remote sensor Battery approach to resolve the role and effect of carbonate · Optimize operation conditions for durability

  19. Ion Exchange Membrane Cathodes for Scalable Microbial Fuel Cells

    E-Print Network [OSTI]

    applications. Introduction A microbial fuel cell (MFC) is a new technology for bioenergy production because separator to reduce oxygen diffusion to the anode can increase volumetric power density to 627 W/

  20. Carbon corrosion of proton exchange membrane fuel cell catalyst layers studied by scanning transmission X-ray microscopy

    E-Print Network [OSTI]

    Hitchcock, Adam P.

    Carbon corrosion of proton exchange membrane fuel cell catalyst layers studied by scanning a l a b s t r a c t STXM is used to analyze polymer membrane fuel cell cathodes. Carbon corrosion Keywords: Polymer electrolyte membrane fuel cells X-ray microscopy Ionomer Carbon corrosion Platinum

  1. An alkaline direct ethanol fuel cell with a cation exchange membrane Liang An and T. S. Zhao*

    E-Print Network [OSTI]

    Zhao, Tianshou

    An alkaline direct ethanol fuel cell with a cation exchange membrane Liang An and T. S. Zhao the performance of anion exchange membrane (AEM) direct ethanol fuel cells (DEFCs) is that state-of-the-art AEMs exchange membrane direct ethanol fuel cells (AEM- DEFCs) have received ever-increasing attention, mainly

  2. Control of the transient behaviour of polymer electrolyte membrane fuel cell systems

    E-Print Network [OSTI]

    Grujicic, Mica

    , Michigan, USA Abstract: The transient behaviour of a polymer electrolyte membrane fuel cell (PEMFC) system by a vehicle powered by the fuel cell system. The PEMFC system analysed consists of air and fuel supply the transient behaviour of the PEMFC system with respect to maintaining the necessary level of the oxygen

  3. Modeling of durability of polyelectrolyte membrane of O2/H2 fuel cell

    E-Print Network [OSTI]

    Atrazhev, Vadim V

    2014-01-01

    In this paper, we discuss critical aspects of the mechanisms and features of polymer proton exchange membrane (PEM) degradation in low-temperature H2/O2 fuel cell. In this paper, we focused on chemical mechanism of OH radical generation and their distribution in operational fuel cell. According to the current concept, free radicals are generated from hydrogen and oxygen crossover gases at the surface of Pt particles that precipitated in the membrane. We explicitly calculate Pt precipitation rate and electrochemical potential distribution in the membrane that controls it. Based on radical generation rate and Pt distribution we calculate degradation rate of the membrane taking advantage of simple kinetics equations.

  4. Proton Exchange Membrane Fuel Cells for Electrical Power Generation On-Board Commercial Airplanes

    Fuel Cell Technologies Publication and Product Library (EERE)

    Deployed on a commercial airplane, proton exchange membrane fuel cells may offer emissions reductions, thermal efficiency gains, and enable locating the power near the point of use. This work seeks to

  5. Influence of electrode stress on proton exchange membrane fuel cell performance : experimental characterization and power optimization

    E-Print Network [OSTI]

    Gallant, Betar M. (Betar Maurkah)

    2008-01-01

    Compressive stress applied to the electrode area of a Proton Exchange Membrane (PEM) fuel cell is known to significantly affect power output. In practice, electrode stress arises during operation due to the clamping force ...

  6. Low platinum loading electrospun electrodes for proton exchange membrane fuel cells

    E-Print Network [OSTI]

    Singer, Simcha Lev

    2006-01-01

    An experimental study was performed to evaluate the utility of electrospun carbon nanofiber supports for sputtered platinum catalyst in proton exchange membrane fuel cells. The performance of the sputtered nanofiber supports ...

  7. Record activity and stability of dealloyed bimetallic catalysts for proton exchange membrane fuel cells

    E-Print Network [OSTI]

    Han, Binghong

    We demonstrate the unprecedented proton exchange membrane fuel cell (PEMFC) performance durability of a family of dealloyed Pt–Ni nanoparticle catalysts for the oxygen reduction reaction (ORR), exceeding scientific and ...

  8. A feasibility study of internal evaporative cooling for proton exchange membrane fuel cells 

    E-Print Network [OSTI]

    Snyder, Loren E

    2006-04-12

    An investigation was conducted to determine the feasibility of using the technique of ultrasonic nebulization of water into the anode gas stream for evaporative cooling of a Proton Exchange Membrane (PEM) fuel cell. The basic concept of this form...

  9. Nitrogen Front Evolution in Purged Polymer Electrolyte Membrane Fuel Cell with Dead-Ended Anode

    E-Print Network [OSTI]

    Stefanopoulou, Anna

    Nitrogen Front Evolution in Purged Polymer Electrolyte Membrane Fuel Cell with Dead-Ended Anode plugging of the channels, and flooding of the gas diffusion layer. The observation of each phenomenon

  10. Simplified process for leaching precious metals from fuel cell membrane electrode assemblies

    DOE Patents [OSTI]

    Shore, Lawrence (Edison, NJ); Matlin, Ramail (Berkeley Heights, NJ)

    2009-12-22

    The membrane electrode assemblies of fuel cells are recycled to recover the catalyst precious metals from the assemblies. The assemblies are cryogenically embrittled and pulverized to form a powder. The pulverized assemblies are then mixed with a surfactant to form a paste which is contacted with an acid solution to leach precious metals from the pulverized membranes.

  11. A critical review of cooling techniques in proton exchange membrane fuel cell stacks

    E-Print Network [OSTI]

    Kandlikar, Satish

    November 2011 Keywords: Proton exchange membrane fuel cell PEMFC Stacks Heat generation Cooling Review a b fuel cell (PEMFC) stacks with high power. The narrow range of operating temperature and the small of the heat generation and cooling requirements in a PEMFC stack are introduced. Then the advantages

  12. Insight into Proton Transfer in Phosphotungstic Acid Functionalized Mesoporous Silica-Based Proton Exchange Membrane Fuel Cells

    E-Print Network [OSTI]

    Goddard III, William A.

    Exchange Membrane Fuel Cells Yuhua Zhou, Jing Yang, Haibin Su,*,, Jie Zeng,§ San Ping Jiang,*,§ and William have developed for fuel cells a novel proton exchange membrane (PEM) using inorganic phosphotungstic temperature PEM fuel cells are prone to poisoning by impurities in fuels such as carbon monoxide and (2

  13. A Comparison of Biomimetic Design and TRIZ Applied to the Design of a Proton Exchange Membrane Fuel Cell

    E-Print Network [OSTI]

    Shu, Lily H.

    Engineering, University of Toronto *shu@mie.utoronto.ca Abstract The Proton Exchange Membrane (PEM) fuel cell Introduction A proton exchange membrane (PEM) fuel cell converts the stored chemical energy in a fuel, e.g., hydrogen, into electrical energy. An important and current challenge in PEM fuel cells involves water

  14. Membrane Durability in PEM Fuel Cells: Chemical Degradation

    Broader source: Energy.gov [DOE]

    Presentation at the 2008 High Temperature Membrane Working Group Meeting held June 9, 2008, in Washington, DC

  15. Strategy for Aging Tests of Fuel Cell Membranes (Presentation)

    Broader source: Energy.gov [DOE]

    Presented at the High Temperature Membrane Working Group Meeting (HTMWG) held October 10, 2007 in Washington, D.C.

  16. A Mathematical Model for Predicting the Life of PEM Fuel Cell Membranes Subjected to Hydration Cycling

    E-Print Network [OSTI]

    S. F. Burlatsky; M. Gummalla; J. O'Neill; V. V. Atrazhev; A. N. Varyukhin; D. V. Dmitriev; N. S. Erikhman

    2013-06-19

    Under typical PEM fuel cell operating conditions, part of membrane electrode assembly is subjected to humidity cycling due to variation of inlet gas RH and/or flow rate. Cyclic membrane hydration/dehydration would cause cyclic swelling/shrinking of the unconstrained membrane. In a constrained membrane, it causes cyclic stress resulting in mechanical failure in the area adjacent to the gas inlet. A mathematical modeling framework for prediction of the lifetime of a PEM FC membrane subjected to hydration cycling is developed in this paper. The model predicts membrane lifetime as a function of RH cycling amplitude and membrane mechanical properties. The modeling framework consists of three model components: a fuel cell RH distribution model, a hydration/dehydration induced stress model that predicts stress distribution in the membrane, and a damage accrual model that predicts membrane life-time. Short descriptions of the model components along with overall framework are presented in the paper. The model was used for lifetime prediction of a GORE-SELECT membrane.

  17. Steady State Multiplicity in a Polymer Electrolyte Membrane Fuel Cell

    E-Print Network [OSTI]

    Ee-Sunn J. Chia; Jay B. Benziger; Ioannis G. Kevrekidis

    2003-06-16

    A simplified differential reactor model that embodies the essential physics controlling PEM fuel cell (PEM-FC) dynamics is presented. A remarkable analogy exists between water management in the differential PEM-FC and energy balance in the classical exothermic stirred tank reactor. Water, the reaction product in the PEM-FC autocatalytically accelerates the reaction rate by enhancing proton transport through the PEM. Established analyses of heat autocatalyticity in a CSTR are modified to present water management autocatalyticity in a stirred tank reactor PEM-FC.

  18. Predicting the Remaining Useful Lifetime of a Proton Exchange Membrane Fuel Cell using an Echo State Network

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Predicting the Remaining Useful Lifetime of a Proton Exchange Membrane Fuel Cell using an Echo industrial Fuel Cell (FC) application resides in the system limited useful lifetime. Consequently, it Membrane Fuel Cell using an iterative predictive structure, which is the most common approach performing

  19. Biohydrogen production using green microalgae as an approach to operate a small Proton Exchange Membrane Fuel Cell

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Membrane Fuel Cell Samira Chader1,2,* , Bouziane Mahmah1 , Khaled Chetehouna3 , Fethia Amrouche1 , Kamel to produce hydrogen in a 500 ml photobioreactor coupled to a small Proton Exchange Membrane Fuel Cell (PEMFC system show that the produced biohydrogen can be used to operate a PEM Fuel Cell with good performances

  20. Water Dynamics in Nafion Fuel Cell Membranes: The Effects of Confinement and Structural Changes on the Hydrogen Bond Network

    E-Print Network [OSTI]

    Fayer, Michael D.

    Water Dynamics in Nafion Fuel Cell Membranes: The Effects of Confinement and Structural Changes emissions energy source is hydrogen. Hydrogen powered vehicles using polymer electrolyte membrane fuel cells and hydrophilic aggregates.1-4 Hydrogen fuel cells operate through the oxidation of hydrogen gas at the anode

  1. Temperature-Dependent Simulations of Dry Gas Transport in the Electrodes of Proton Exchange Membrane Fuel Cells

    E-Print Network [OSTI]

    Stockie, John

    Membrane Fuel Cells M. J. Kermani1 J. M. Stockie2 mkermani@unb.ca stockie@unb.ca 1 Post Doctoral Fellow the cathode of a proton exchange membrane (PEM) fuel cell is studied numerically. The di usion to achieve this goal is via proton exchange mem- brane (PEM) fuel cells, which in principle combine oxygen

  2. Proton exchange membrane fuel cells for electrical power generation on-board commercial airplanes.

    SciTech Connect (OSTI)

    Curgus, Dita Brigitte; Munoz-Ramos, Karina; Pratt, Joseph William; Akhil, Abbas Ali; Klebanoff, Leonard E.; Schenkman, Benjamin L.

    2011-05-01

    Deployed on a commercial airplane, proton exchange membrane fuel cells may offer emissions reductions, thermal efficiency gains, and enable locating the power near the point of use. This work seeks to understand whether on-board fuel cell systems are technically feasible, and, if so, if they offer a performance advantage for the airplane as a whole. Through hardware analysis and thermodynamic and electrical simulation, we found that while adding a fuel cell system using today's technology for the PEM fuel cell and hydrogen storage is technically feasible, it will not likely give the airplane a performance benefit. However, when we re-did the analysis using DOE-target technology for the PEM fuel cell and hydrogen storage, we found that the fuel cell system would provide a performance benefit to the airplane (i.e., it can save the airplane some fuel), depending on the way it is configured.

  3. Proton Exchange Membrane Fuel Cells for Electrical Power Generation On-Board Commercial Airplanes

    SciTech Connect (OSTI)

    Pratt, Joesph W.; Klebanoff, Leonard E.; Munoz-Ramos, Karina; Akhil, Abbas A.; Curgus, Dita B.; Schenkman, Benjamin L.

    2011-05-01

    Deployed on a commercial airplane, proton exchange membrane fuel cells may offer emissions reductions, thermal efficiency gains, and enable locating the power near the point of use. This work seeks to understand whether on-board fuel cell systems are technically feasible, and, if so, if they offer a performance advantage for the airplane as a whole. Through hardware analysis and thermodynamic and electrical simulation, we found that while adding a fuel cell system using today’s technology for the PEM fuel cell and hydrogen storage is technically feasible, it will not likely give the airplane a performance benefit. However, when we re-did the analysis using DOE-target technology for the PEM fuel cell and hydrogen storage, we found that the fuel cell system would provide a performance benefit to the airplane (i.e., it can save the airplane some fuel), depending on the way it is configured.

  4. Water transport in fuel cell membranes measured by laser interferometry

    E-Print Network [OSTI]

    Kim, Jungik, 1973-

    2009-01-01

    (cont.) The coefficients of electro-osmotic drag were found to increase with the increasing water content, which indicates that the Grotthuss mechanism of proton transfer is not active in the membranes with low water ...

  5. Alkaline Membrane Fuel Cell Workshop Welcome and OverviewInnovation |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based Fuels Research at NRELDepartmentJune 2, 2015AlignedRPTnnnn

  6. Anion Exchange Membranes for Fuel Cells | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based Fuels Research at 1 Table ofDepartment of

  7. Alternate Fuel Cell Membranes at the University of Southern Mississippi |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels DataEnergy Webinar:I Due Date Adv.Alison Markovitz About Us

  8. High resolution neutron imaging of water in the polymer electrolyte fuel cell membrane

    SciTech Connect (OSTI)

    Mukherjee, Partha P [Los Alamos National Laboratory; Makundan, Rangachary [Los Alamos National Laboratory; Spendelow, Jacob S [Los Alamos National Laboratory; Borup, Rodney L [Los Alamos National Laboratory; Hussey, D S [NIST; Jacobson, D L [NIST; Arif, M [NIST

    2009-01-01

    Water transport in the ionomeric membrane, typically Nafion{reg_sign}, has profound influence on the performance of the polymer electrolyte fuel cell, in terms of internal resistance and overall water balance. In this work, high resolution neutron imaging of the Nafion{reg_sign} membrane is presented in order to measure water content and through-plane gradients in situ under disparate temperature and humidification conditions.

  9. Proton Exchange Membrane Fuel Cells for Electrical Power Generation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy BillsNo. 195 - Oct. 7, 2011 | Department ofEnergyOn-Board Commercial

  10. 2011 Alkaline Membrane Fuel Cell Workshop Final Report | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Financing ToolInternationalReport FY2014Conference Presentations |InfrastructureWESTERN

  11. Durable Low Cost Improved Fuel Cell Membranes | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based| Department8,Department of2 FederalEnergyDuctsDurable Low Cost

  12. Synergy between Membranes and Microbial Fuel Cells | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergyPlan | Department ofSUPPLEMENTSwitzerland 2012 ProgramSynergy between

  13. Alkaline Membrane Fuel Cell Workshop | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative FuelsofProgram:Y-12 Beta-3AUDITLeslieAlgae Biomass Summit AlgaeAlice

  14. Isothermal Ice-Crystallization Kinetics in the Gas-Diffusion Layer of a Proton-Exchange-Membrane Fuel Cell

    E-Print Network [OSTI]

    Dursch, Thomas J.

    2013-01-01

    exchange membrane fuel cell (PEMFC) are investigated usinglow emissions. In a PEMFC, reduction of oxygen to waterexperimental studies of PEMFC cold- start primarily focus on

  15. Enhancement of water retention in the membrane electrode assembly for direct methanol fuel cells operating with neat

    E-Print Network [OSTI]

    Zhao, Tianshou

    al. [10], assuming the overall efficiency of the fuel cell system is 20%, the specific energyEnhancement of water retention in the membrane electrode assembly for direct methanol fuel cells 31 July 2010 Keywords: Fuel cell Direct methanol fuel cell (DMFC) Neat-methanol operation Water

  16. Water-retaining Polymer Membranes for Fuel Cell Applications - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking WithTelecentricN AProject Assessment Customer

  17. Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Financing Tool Fits theCommitteeCrystalline Siliconof Division F, TitleFAC4 -PollutionApplications

  18. The Path a Proton Takes Through a Fuel Cell Membrane

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservationBio-Inspired Solar FuelTechnologyTel: Name:Department ofThe DOEThe New YorkTheThe

  19. Membrane Performance and Durability Overview for Automotive Fuel Cell

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURING OFFICESpecial ReportProposal to changeNovember 5-6, 2001Final ReportA

  20. 2006 Alkaline Membrane Fuel Cell Workshop Final Report | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Financing ToolInternationalReport FY2014 -EnergyEnergySenior Chapter2Energy 06 Alkaline

  1. Durable, Low Cost, Improved Fuel Cell Membranes | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based| Department8,Department of2 FederalEnergyDuctsDurable Low CostDurable,

  2. Durable Fuel Cell Membrane Electrode Assembly (MEA) - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit theCovalentLaboratory |Sectorfor $1.14 Per1-E WholesaleDurable Fuel

  3. High Performance Alkaline Fuel Cell Membranes > Research Highlights >

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid you notHeat Pumps Heat Pumps An error occurred. Try| Center forResearch

  4. Structures and Transport Properties of Hydrated Water-Soluble Dendrimer-Grafted Polymer Membranes for Application to Polymer Electrolyte Membrane Fuel Cells

    E-Print Network [OSTI]

    Goddard III, William A.

    for application to polymer electrolyte membrane fuel cells (PEMFC). Using full-atomistic molecular dynamics materials for polymer electrolyte membrane fuel cells (PEMFC).1-6 This has led to a number of new materials or above). Recently, we proposed a strategy for improving the perfor- mance of PEMFC by utilizing

  5. Cathode and electrolyte materials for solid oxide fuel cells and ion transport membranes

    SciTech Connect (OSTI)

    Jacobson, Allan J; Wang, Shuangyan; Kim, Gun Tae

    2014-01-28

    Novel cathode, electrolyte and oxygen separation materials are disclosed that operate at intermediate temperatures for use in solid oxide fuel cells and ion transport membranes based on oxides with perovskite related structures and an ordered arrangement of A site cations. The materials have significantly faster oxygen kinetics than in corresponding disordered perovskites.

  6. Materials for use as proton conducting membranes for fuel cells

    SciTech Connect (OSTI)

    Einsla, Brian R.; McGrath, James E.

    2009-01-06

    A family of polymers having pendent sulfonate moieties connected to polymeric main chain phenyl groups are described. These polymers are prepared by the steps of polymerization (using a monomer with a phenyl with an alkoxy substitution), deportation by converting the alkoxy to a hydroxyl, and functionalization of the polymer with a pendant sulfonate group. As an example, sulfonated poly(arylene ether sulfone) copolymers with pendent sulfonic acid groups are synthesized by the direct copolymerization of methoxy-containing poly(arylene ether sulfone)s, then converting the methoxy groups to the reactive hydroxyl form, and finally functionalizing the hydroxyl form with proton-conducting sites through nucleophilic substitution. The family of polymers may have application in proton exchange membranes and in other applications.

  7. Nanomaterials for Polymer Electrolyte Membrane Fuel Cells; Materials Challenges Facing Electrical Energy Storate

    SciTech Connect (OSTI)

    Gopal Rao, MRS Web-Editor; Yury Gogotsi, Drexel University; Karen Swider-Lyons, Naval Research Laboratory

    2010-08-05

    Symposium T: Nanomaterials for Polymer Electrolyte Membrane Fuel Cells Polymer electrolyte membrane (PEM) fuel cells are under intense investigation worldwide for applications ranging from transportation to portable power. The purpose of this seminar is to focus on the nanomaterials and nanostructures inherent to polymer fuel cells. Symposium topics will range from high-activity cathode and anode catalysts, to theory and new analytical methods. Symposium U: Materials Challenges Facing Electrical Energy Storage Electricity, which can be generated in a variety of ways, offers a great potential for meeting future energy demands as a clean and efficient energy source. However, the use of electricity generated from renewable sources, such as wind or sunlight, requires efficient electrical energy storage. This symposium will cover the latest material developments for batteries, advanced capacitors, and related technologies, with a focus on new or emerging materials science challenges.

  8. Numerical investigation of interfacial transport resistance due to water droplets in proton exchange membrane fuel cell air channels

    E-Print Network [OSTI]

    Kandlikar, Satish

    (GDL) interface is needed in modelling the performance of a proton exchange membrane fuel cell (PEMFC representative case of a PEMFC air flow channel. The results show that the droplets significantly increase Sh of a proton exchange membrane fuel cell (PEMFC) is an active area of research. The O2 transport loss becomes

  9. UNDERSTANDING THE EFFECTS OF COMPRESSION AND CONSTRAINTS ON WATER UPTAKE OF FUEL-CELL MEMBRANES

    E-Print Network [OSTI]

    Kusoglu, Ahmet

    2013-01-01

    of Fuel Cells – Fundamentals, Technology and Applications ,polymer-electrolyte-fuel-cell (PEFC) applications are always

  10. Direct-hydrogen-fueled proton-exchange-membrane fuel cell system for transportation applications: Conceptual vehicle design report pure fuel cell powertrain vehicle

    SciTech Connect (OSTI)

    Oei, D.; Kinnelly, A.; Sims, R.; Sulek, M.; Wernette, D.

    1997-02-01

    In partial fulfillment of the Department of Energy (DOE) Contract No. DE-AC02-94CE50389, {open_quotes}Direct-Hydrogen-Fueled Proton-Exchange-Membrane (PEM) Fuel Cell for Transportation Applications{close_quotes}, this preliminary report addresses the conceptual design and packaging of a fuel cell-only powered vehicle. Three classes of vehicles are considered in this design and packaging exercise, the Aspire representing the small vehicle class, the Taurus or Aluminum Intensive Vehicle (AIV) Sable representing the mid-size vehicle and the E-150 Econoline representing the van-size class. A fuel cell system spreadsheet model and Ford`s Corporate Vehicle Simulation Program (CVSP) were utilized to determine the size and the weight of the fuel cell required to power a particular size vehicle. The fuel cell power system must meet the required performance criteria for each vehicle. In this vehicle design and packaging exercise, the following assumptions were made: fuel cell power system density of 0.33 kW/kg and 0.33 kg/liter, platinum catalyst loading less than or equal to 0.25 mg/cm{sup 2} total and hydrogen tanks containing gaseous hydrogen under 340 atm (5000 psia) pressure. The fuel cell power system includes gas conditioning, thermal management, humidity control, and blowers or compressors, where appropriate. This conceptual design of a fuel cell-only powered vehicle will help in the determination of the propulsion system requirements for a vehicle powered by a PEMFC engine in lieu of the internal combustion (IC) engine. Only basic performance level requirements are considered for the three classes of vehicles in this report. Each vehicle will contain one or more hydrogen storage tanks and hydrogen fuel for 560 km (350 mi) driving range. Under these circumstances, the packaging of a fuel cell-only powered vehicle is increasingly difficult as the vehicle size diminishes.

  11. Control of the mass and energy dynamics of polybenzimidazole-membrane fuel cells Federico Zenith *, Sigurd Skogestad

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Control of the mass and energy dynamics of polybenzimidazole-membrane fuel cells Federico Zenith Received in revised form 17 June 2008 Accepted 21 June 2008 Keywords: Fuel cell Dynamics Control a b s t r conditions for the fuel cell stack to operate. It is possible to control temperature by using only air

  12. A Two-Stage Microbial Fuel Cell and Anaerobic Fluidized Bed Membrane Bioreactor (MFC-AFMBR) System for Effective Domestic

    E-Print Network [OSTI]

    interest in the use of wastewater as a source of renewable energy.1 Microbial fuel cells (MFCs) are beingA Two-Stage Microbial Fuel Cell and Anaerobic Fluidized Bed Membrane Bioreactor (MFC-AFMBR) System, Pennsylvania 16802, United States *S Supporting Information ABSTRACT: Microbial fuel cells (MFCs

  13. Influence of membrane-electrode interface on long-term performance of direct methanol fuel cells

    SciTech Connect (OSTI)

    Kim, Y. S. (Yu Seung); Pivovar, B. S. (Bryan Scott)

    2004-01-01

    Long-term stability of direct methanol fuel cells (DMFCs) is one of the most critical requirements for the successful launch of this technology to commercial market. When a DMFC is operated for extended periods of time, performance decreases continuously. The performance decay in continuous operation of DMFCs is caused by several different attributes, such as surface oxidation of platinum at the cathode, loss of catalytic active surface area, interfacial failure between membrane and electrode, changing hydrophobicity of backing layers or ruthenium crossover. Among those attributes, the interfacial incompatibility between membrane and electrode becomes more important when alternative polymer electrolyte membranes (PEM) are used with Nafion-bonded electrode. In earlier work, we demonstrated that the direct methanol fuel cells (DMFCs) using alternative fully aromatic hydrocarbon based PEMs initially outperformed the DMFCs using industrial standard Nafion membranes. Nonetheless, the longer-term performance of the alternative system deteriorated rather faster probably due to the interfacial incompatibility. In this presentation, the effect of interfacial incompatibility of membrane electrode assemblies (MEAs) on long-term DMFC performance is presented in a systematic manner. A series of disulfonated poly(arylene ether) copolymers having different ion exchange capacity and fluorine content was prepared. The effects of chemical structure of the PEMs on interfacial compatibility and long-term performance were investigated and compared with Nation control membraneelectrode assembly.

  14. Biodegradation test of SPS-LS blends as polymer electrolyte membrane fuel cells

    SciTech Connect (OSTI)

    Putri, Zufira, E-mail: zufira.putri@gmail.com, E-mail: arcana@chem.itb.ac.id; Arcana, I Made, E-mail: zufira.putri@gmail.com, E-mail: arcana@chem.itb.ac.id [Inorganic and Physical Chemistry Research Groups, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Bandung (Indonesia)

    2014-03-24

    Sulfonated polystyrene (SPS) can be applied as a proton exchange membrane fuel cell due to its fairly good chemical stability. In order to be applied as polymer electrolyte membrane fuel cells (PEMFCs), membrane polymer should have a good ionic conductivity, high proton conductivity, and high mechanical strength. Lignosulfonate (LS) is a complex biopolymer which has crosslinks and sulfonate groups. SPS-LS blends with addition of SiO{sub 2} are used to increase the proton conductivity and to improve the mechanical properties and thermal stability. However, the biodegradation test of SPS-LS blends is required to determine whether the application of these membranes to be applied as an environmentally friendly membrane. In this study, had been done the synthesis of SPS, biodegradability test of SPS-LS blends with variations of LS and SiO{sub 2} compositions. The biodegradation test was carried out in solid medium of Luria Bertani (LB) with an activated sludge used as a source of microorganism at incubation temperature of 37°C. Based on the results obtained indicated that SPS-LS-SiO{sub 2} blends are more decomposed by microorganism than SPS-LS blends. This result is supported by analysis of weight reduction percentage, functional groups with Fourier Transform Infrared (FTIR) Spectroscopy, and morphological surface with Scanning Electron Microscopy (SEM)

  15. Method for recovering catalytic elements from fuel cell membrane electrode assemblies

    DOE Patents [OSTI]

    Shore, Lawrence (Edison, NJ); Matlin, Ramail (Berkeley Heights, NJ); Heinz, Robert (Ludwigshafen, DE)

    2012-06-26

    A method for recovering catalytic elements from a fuel cell membrane electrode assembly is provided. The method includes converting the membrane electrode assembly into a particulate material, wetting the particulate material, forming a slurry comprising the wetted particulate material and an acid leachate adapted to dissolve at least one of the catalytic elements into a soluble catalytic element salt, separating the slurry into a depleted particulate material and a supernatant containing the catalytic element salt, and washing the depleted particulate material to remove any catalytic element salt retained within pores in the depleted particulate material.

  16. New Membranes for High Temperature Proton Exchange Membrane Fuel Cells Based on Heteropoly Acids

    Broader source: Energy.gov [DOE]

    "Summary of Colorado School of Mines heteropolyacid research presented to the High Temperature Membrane Working Group Meeting, Orlando FL, October 17, 2003 "

  17. DOE Fuel Cell Technologies Office Record 14012: Fuel Cell System...

    Broader source: Energy.gov (indexed) [DOE]

    the cost of automotive polymer electrolyte membrane (PEM) fuel cell systems. DOE Hydrogen and Fuel Cells Program Record 14012 More Documents & Publications DOE Fuel Cell...

  18. Gas-Crossover and Membrane-Pinhole Effects in Polymer-Electrolyte Fuel Cells

    E-Print Network [OSTI]

    Weber, Adam

    2008-01-01

    Newman, in Advances in Fuel Cells, Vol. 1 , T. S. Zhao, K. -and tortuosity gas phase fuel-cell inlet conditions liquidw water References Hydrogen, fuel cells & infrastructure

  19. Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications Download the...

  20. Membrane Performance and Durability Overview for Automotive Fuel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Membrane Performance and Durability Overview for Automotive Fuel Cell Applications Membrane Performance and Durability Overview for Automotive Fuel Cell Applications Presented by...

  1. Quasi-elastic Neutron Scattering Investigation of the Hydrogen Surface Self-Diffusion on Polymer Electrolyte Membrane Fuel Cell Catalyst Support

    E-Print Network [OSTI]

    Kjelstrup, Signe

    Electrolyte Membrane Fuel Cell Catalyst Support Ole-Erich Haas* Department of Chemistry, Norwegian Uni in polymer electrolyte membrane fuel cells, called XC-72. QENS spectra were recorded at the time through the backing electrode and catalyst layer in the polymer electrolyte membrane fuel cell (PEMFC

  2. Pre-Oxidized and Nitrided Stainless Steel Foil for Proton Exchange Membrane Fuel Cell Bipolar Plates: Part 2- Single-Cell Fuel Cell Evaluation of Stamped Plates

    SciTech Connect (OSTI)

    Toops, Todd J [ORNL; Brady, Michael P [ORNL; Tortorelli, Peter F [ORNL; Pihl, Josh A [ORNL; EstevezGenCell, Francisco [GenCell Corp; Connors, Dan [GenCell Corp; Garzon, Fernando [Los Alamos National Laboratory (LANL); Rockward, Tommy [Los Alamos National Laboratory (LANL); Gervasio, Don [Arizona State University; Kosaraju, S.H. [Arizona State University

    2010-01-01

    Thermal (gas) nitridation of stainless steel alloys can yield low interfacial contact resistance (ICR), electrically conductive and corrosion-resistant nitride containing surface layers (Cr{sub 2}N, CrN, TiN, V{sub 2}N, VN, etc.) of interest for fuel cells, batteries, and sensors. This paper presents results of proton exchange membrane (PEM) single-cell fuel cell studies of stamped and pre-oxidized/nitrided developmental Fe-20Cr-4V weight percent (wt.%) and commercial type 2205 stainless steel alloy foils. The single-cell fuel cell behavior of the stamped and pre-oxidized/nitrided material was compared to as-stamped (no surface treatment) 904L, 2205, and Fe-20Cr-4V stainless steel alloy foils and machined graphite of similar flow field design. The best fuel cell behavior among the alloys was exhibited by the pre-oxidized/nitrided Fe-20Cr-4V, which exhibited {approx}5-20% better peak power output than untreated Fe-20Cr-4V, 2205, and 904L metal stampings. Durability was assessed for pre-oxidized/nitrided Fe-20Cr-4V, 904L metal, and graphite plates by 1000+ h of cyclic single-cell fuel cell testing. All three materials showed good durability with no significant degradation in cell power output. Post-test analysis indicated no metal ion contamination of the membrane electrode assemblies (MEAs) occurred with the pre-oxidized and nitrided Fe-20Cr-4V or graphite plates, and only a minor amount of contamination with the 904L plates.

  3. DEVELOPMENT AND SELECTION OF IONIC LIQUID ELECTROLYTES FOR HYDROXIDE CONDUCTING POLYBENZIMIDAZOLE MEMBRANES IN ALKALINE FUEL CELLS

    SciTech Connect (OSTI)

    Fox, E.

    2012-05-01

    Alkaline fuel cell (AFC) operation is currently limited to specialty applications such as low temperatures and pure H{sub 2}/O{sub 2} due to the corrosive nature of the electrolyte and formation of carbonates. AFCs are the cheapest and potentially most efficient (approaching 70%) fuel cells. The fact that non-Pt catalysts can be used, makes them an ideal low cost alternative for power production. The anode and cathode are separated by and solid electrolyte or alkaline porous media saturated with KOH. However, CO{sub 2} from the atmosphere or fuel feed severely poisons the electrolyte by forming insoluble carbonates. The corrosivity of KOH (electrolyte) limits operating temperatures to no more than 80?C. This chapter examines the development of ionic liquids electrolytes that are less corrosive, have higher operating temperatures, do not chemically bond to CO{sub 2}, and enable alternative fuels. Work is detailed on the IL selection and characterization as well as casting methods within the polybenzimidazole based solid membrane. This approach is novel as it targets the root of the problem (the electrolyte) unlike other current work in alkaline fuel cells which focus on making the fuel cell components more durable.

  4. The design and evaluation of a water delivery system for evaporative cooling of a proton exchange membrane fuel cell 

    E-Print Network [OSTI]

    Al-Asad, Dawood Khaled Abdullah

    2009-06-02

    An investigation was performed to demonstrate system design for the delivery of water required for evaporative cooling of a proton exchange membrane fuel cell (PEMFC). The water delivery system uses spray nozzles capable of injecting water directly...

  5. Effect of direct liquid water injection and interdigitated flow field on the performance of proton exchange membrane fuel cells

    E-Print Network [OSTI]

    Wood, D. L.; Yi, Y. S.; Van Nguyen, Trung

    1998-01-01

    Proper water management is vital to ensuring successful performance of proton exchange membrane fuel cells. The effectiveness of the direct liquid water injection scheme and the interdigitated flow field design towards providing adequate gas...

  6. Effective Transport Properties Accounting for Electrochemical Reactions of Proton-Exchange Membrane Fuel Cell Catalyst Layers

    SciTech Connect (OSTI)

    Pharoah, Jon; Choi, Hae-Won; Chueh, Chih-Che; Harvey, David

    2011-07-01

    There has been a rapidly growing interest in three-dimensional micro-structural reconstruction of fuel cell electrodes so as to derive more accurate descriptors of the pertinent geometric and effective transport properties. Due to the limited accessibility of experiments based reconstruction techniques, such as dual-beam focused ion beam-scanning electro microscopy or micro X-Ray computed tomography, within sample micro-structures of the catalyst layers in polymer electrolyte membrane fuel cells (PEMFCs), a particle based numerical model is used in this study to reconstruct sample microstructure of the catalyst layers in PEMFCs. Then the reconstructed sample structure is converted into the computational grid using body-fitted/cut-cell based unstructured meshing technique. Finally, finite volume methods (FVM) are applied to calculate effective properties on computational sample domains.

  7. Wastewater treatment, energy recovery and desalination using a forward osmosis membrane in an air-cathode microbial osmotic fuel cell

    E-Print Network [OSTI]

    Wastewater treatment, energy recovery and desalination using a forward osmosis membrane in an air-cathode microbial osmotic fuel cell Craig M. Werner a,n , Bruce E. Logan b , Pascal E. Saikaly a , Gary L. Amy Keywords: Forward osmosis Desalination Fouling Microbial osmotic fuel cell a b s t r a c t A microbial

  8. Poly(cyclohexadiene)-Based Polymer Electrolyte Membranes for Fuel Cell Applications

    SciTech Connect (OSTI)

    Mays, Jimmy W.

    2011-03-07

    The goal of this research project was to create and develop fuel cell membranes having high proton conductivity at high temperatures and high chemical and mechanical durability. Poly(1,3-cyclohexadiene) (PCHD) is of interest as an alternative polymer electrolyte membrane (PEM) material due to its ring-like structure which is expected to impart superior mechanical and thermal properties, and due to the fact that PCHD can readily be incorporated into a range of homopolymer and copolymer structures. PCHD can be aromatized, sulfonated, or fluorinated, allowing for tuning of key performance structure and properties. These factors include good proton transport, hydrophilicity, permeability (including fuel gas impermeability), good mechanical properties, morphology, thermal stability, crystallinity, and cost. The basic building block, 1,3-cyclohexadiene, is a hydrocarbon monomer that could be inexpensively produced on a commercial scale (pricing typical of other hydrocarbon monomers). Optimal material properties will result in novel low cost PEM membranes engineered for high conductivity at elevated temperatures and low relative humidities, as well as good performance and durability. The primary objectives of this project were: (1) To design, synthesize and characterize new non-Nafion PEM materials that conduct protons at low (25-50%) RH and at temperatures ranging from room temperature to 120 C; and (2) To achieve these objectives, a range of homopolymer and copolymer materials incorporating poly(cyclohexadiene) (PCHD) will be synthesized, derivatized, and characterized. These two objectives have been achieved. Sulfonated and crosslinked PCHD homopolymer membranes exhibit proton conductivities similar to Nafion in the mid-RH range, are superior to Nafion at higher RH, but are poorer than Nafion at RH < 50%. Thus to further improve proton conductivity, particularly at low RH, poly(ethylene glycol) (PEG) was incorporated into the membrane by blending and by copolymerization. Conductivity measurements at 120 C over RH ranging from 20 to 100% using the BekkTech protocol showed much improved proton conductivities. Conductivities for the best of these new membranes exceed the DOE Year 3 milestone of 100 mS/cm at 50% RH at 120 C. Further optimization of these very promising low cost membranes could be pursued in the future.

  9. UNDERSTANDING THE EFFECTS OF COMPRESSION AND CONSTRAINTS ON WATER UPTAKE OF FUEL-CELL MEMBRANES

    E-Print Network [OSTI]

    Kusoglu, Ahmet

    2013-01-01

    D. A. Dillard, Journal of Fuel Cell Science and Technology ,W. Liu, in Handbook of Fuel Cells – Fundamentals, TechnologyWang and M. A. Hickner, Fuel Cells , 9 , 432 L. M. Onishi,

  10. Effects of Membrane- and Catalyst-layer-thickness Nonuniformities in Polymer-electrolyte Fuel Cells

    E-Print Network [OSTI]

    Weber, Adam Z.; Newman, John

    2006-01-01

    Energy, Office of Hydrogen, Fuel Cell, and Infrastructurein Polymer-electrolyte Fuel Cells Adam Z. Weber 1, * ,z andAs polymer-electrolyte fuel cells (PEFCs) make the transfer

  11. Development of Novel PEM Membrane and Multiphase CD Modeling of PEM Fuel Cell

    SciTech Connect (OSTI)

    K. J. Berry; Susanta Das

    2009-12-30

    To understand heat and water management phenomena better within an operational proton exchange membrane fuel cell's (PEMFC) conditions, a three-dimensional, two-phase computational fluid dynamic (CFD) flow model has been developed and simulated for a complete PEMFC. Both liquid and gas phases are considered in the model by taking into account the gas flow, diffusion, charge transfer, change of phase, electro-osmosis, and electrochemical reactions to understand the overall dynamic behaviors of species within an operating PEMFC. The CFD model is solved numerically under different parametric conditions in terms of water management issues in order to improve cell performance. The results obtained from the CFD two-phase flow model simulations show improvement in cell performance as well as water management under PEMFCs operational conditions as compared to the results of a single phase flow model available in the literature. The quantitative information obtained from the two-phase model simulation results helped to develop a CFD control algorithm for low temperature PEM fuel cell stacks which opens up a route in designing improvement of PEMFC for better operational efficiency and performance. To understand heat and water management phenomena better within an operational proton exchange membrane fuel cell's (PEMFC) conditions, a three-dimensional, two-phase computational fluid dynamic (CFD) flow model has been developed and simulated for a complete PEMFC. Both liquid and gas phases are considered in the model by taking into account the gas flow, diffusion, charge transfer, change of phase, electro-osmosis, and electrochemical reactions to understand the overall dynamic behaviors of species within an operating PEMFC. The CFD model is solved numerically under different parametric conditions in terms of water management issues in order to improve cell performance. The results obtained from the CFD two-phase flow model simulations show improvement in cell performance as well as water management under PEMFCs operational conditions as compared to the results of a single phase flow model available in the literature. The quantitative information obtained from the two-phase model simulation results helped to develop a CFD control algorithm for low temperature PEM fuel cell stacks which opens up a route in designing improvement of PEMFC for better operational efficiency and performance.

  12. Proton exchange membrane fuel cells with chromium nitride nanocrystals as electrocatalysts

    E-Print Network [OSTI]

    Zhong, Hexiang; Chen, Xiaobo; Zhang, Huamin; Wang, Meiri; Mao, Samuel S.

    2007-01-01

    results in reduced fuel cell efficiency. 7 Alloying Pt withfuel cells (PEMFCs) have many advantages, including high energy conversion efficiency,

  13. Determining the quality and quantity of heat produced by proton exchange membrane fuel cells with application to air-cooled stacks for combined heat and power

    E-Print Network [OSTI]

    Victoria, University of

    Determining the quality and quantity of heat produced by proton exchange membrane fuel cells Determining the quality and quantity of heat produced by proton exchange membrane fuel cells with application). The experiments and simulations focused on the air-cooled Ballard Nexa fuel cell. The experimental

  14. X-ray Line Profile Analysis of Nanoparticles in Proton Exchange Membrane Fuel Cell Matthias Loster,*, Davor Balzar, K. Andreas Friedrich, and Ju1rgen Garche

    E-Print Network [OSTI]

    Balzar, Davor

    on the power and durability of a fuel cell and can be further optimized, for example with respectX-ray Line Profile Analysis of Nanoparticles in Proton Exchange Membrane Fuel Cell Electrodes exchange membrane fuel cells (PEMFCs), where it is particularly useful to determine particle size

  15. Conceptual design report for a Direct Hydrogen Proton Exchange Membrane Fuel Cell for transportation application

    SciTech Connect (OSTI)

    NONE

    1995-09-05

    This report presents the conceptual design for a Direct-Hydrogen-Fueled Proton Exchange Membrane (PEM) Fuel Cell System for transportation applications. The design is based on the initial selection of the Chrysler LH sedan as the target vehicle with a 50 kW (gross) PEM Fuel Cell Stack (FCS) as the primary power source, a battery-powered Load Leveling Unit (LLU) for surge power requirements, an on-board hydrogen storage subsystem containing high pressure gaseous storage, a Gas Management Subsystem (GMS) to manage the hydrogen and air supplies for the FCS, and electronic controllers to control the electrical system. The design process has been dedicated to the use of Design-to-Cost (DTC) principles. The Direct Hydrogen-Powered PEM Fuel Cell Stack Hybrid Vehicle (DPHV) system is designed to operate on the Federal Urban Driving Schedule (FUDS) and Hiway Cycles. These cycles have been used to evaluate the vehicle performance with regard to range and hydrogen usage. The major constraints for the DPHV vehicle are vehicle and battery weight, transparency of the power system and drive train to the user, equivalence of fuel and life cycle costs to conventional vehicles, and vehicle range. The energy and power requirements are derived by the capability of the DPHV system to achieve an acceleration from 0 to 60 MPH within 12 seconds, and the capability to achieve and maintain a speed of 55 MPH on a grade of seven percent. The conceptual design for the DPHV vehicle is shown in a figure. A detailed description of the Hydrogen Storage Subsystem is given in section 4. A detailed description of the FCS Subsystem and GMS is given in section 3. A detailed description of the LLU, selection of the LLU energy source, and the power controller designs is given in section 5.

  16. Hydrogen Fuel Cell Vehicles

    E-Print Network [OSTI]

    Delucchi, Mark

    1992-01-01

    Membrane Fuel Cells and Electrolyzers," Journal of PowerAdvanced Alkaline Electrolyzer for Solar Operation,"requirements are for electrolyzer feedwater. T h e high-

  17. Proton exchange membrane materials for the advancement of direct methanol fuel-cell technology

    DOE Patents [OSTI]

    Cornelius, Christopher J. (Albuquerque, NM)

    2006-04-04

    A new class of hybrid organic-inorganic materials, and methods of synthesis, that can be used as a proton exchange membrane in a direct methanol fuel cell. In contrast with Nafion.RTM. PEM materials, which have random sulfonation, the new class of materials have ordered sulfonation achieved through self-assembly of alternating polyimide segments of different molecular weights comprising, for example, highly sulfonated hydrophilic PDA-DASA polyimide segment alternating with an unsulfonated hydrophobic 6FDA-DAS polyimide segment. An inorganic phase, e.g., 0.5 5 wt % TEOS, can be incorporated in the sulfonated polyimide copolymer to further improve its properties. The new materials exhibit reduced swelling when exposed to water, increased thermal stability, and decreased O.sub.2 and H.sub.2 gas permeability, while retaining proton conductivities similar to Nafion.RTM.. These improved properties may allow direct methanol fuel cells to operate at higher temperatures and with higher efficiencies due to reduced methanol crossover.

  18. Characterization of proton exchange membrane materials for fuel cells by solid state nuclear magnetic resonance

    SciTech Connect (OSTI)

    Kong, Zueqian

    2010-03-15

    Solid-state nuclear magnetic resonance (NMR) has been used to explore the nanometer-scale structure of Nafion, the widely used fuel cell membrane, and its composites. We have shown that solid-state NMR can characterize chemical structure and composition, domain size and morphology, internuclear distances, molecular dynamics, etc. The newly-developed water channel model of Nafion has been confirmed, and important characteristic length-scales established. Nafion-based organic and inorganic composites with special properties have also been characterized and their structures elucidated. The morphology of Nafion varies with hydration level, and is reflected in the changes in surface-to-volume (S/V) ratio of the polymer obtained by small-angle X-ray scattering (SAXS). The S/V ratios of different Nafion models have been evaluated numerically. It has been found that only the water channel model gives the measured S/V ratios in the normal hydration range of a working fuel cell, while dispersed water molecules and polymer ribbons account for the structures at low and high hydration levels, respectively.

  19. Cellulose nanocrystal-based composite electrolyte with superior dimensional stability for alkaline fuel cell membranes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lu, Yuan; Artmentrout, Aaron A.; Li, Juchuan; Tekinalp, Halil L.; Nanda, Jagjit; Ozcan, Soydan

    2015-05-13

    Cellulose nanocrystal (CNC)-based composite films were prepared as a solid electrolyte for alkaline fuel cells. Poly (vinyl alcohol) (PVA) and silica gel hybrid was used to bind the CNCs to form a robust composite film. The mass ratio (i.e., 1 : 1, 1 : 2) of PVA and silica gel was tuned to control the hydrophobicity of the resulting films. Composite films with a range of CNC content (i.e., 20 to 60%) were prepared to demonstrate the impact of CNC on the performance of these materials as a solid electrolyte for alkaline fuel cells. Different from previously reported cross-linked polymermore »films, CNC-based composite films with 40% hydrophobic binder (i.e., PVA : silica gel=1 : 2) exhibited simultaneous low water swelling (e.g., ~5%) and high water uptake (e.g., ~80%) due to the hydrophilicity and extraordinary dimensional stability of CNC. It also showed a conductivity of 0.044 and 0.065 S/cm at 20 and 60 oC, respectively. To the best of our knowledge, the film with 60% CNC and 40% binder is characterized by the lowest hydroxide conductivity-normalized swelling ratio. Decreased CNC content (i.e., 40 and 20%) resulted in comparable hydroxide conductivity but a greater swelling ratio. These results demonstrate the advantage of CNC as a key component for a solid electrolyte for alkaline fuel cells over conventional polymers, suggesting the great potential of CNCs in improving the dimensional stability while maintaining the conductivity of existing anion exchange membranes.« less

  20. Optimum Performance of Direct Hydrogen Hybrid Fuel Cell Vehicles

    E-Print Network [OSTI]

    Zhao, Hengbing; Burke, Andy

    2009-01-01

    Exchange Membrane fuel cell (PEMFC) technology is one of theExchange Membrane fuel cell ( PEMFC) technology for use in

  1. UNDERSTANDING THE EFFECTS OF COMPRESSION AND CONSTRAINTS ON WATER UPTAKE OF FUEL-CELL MEMBRANES

    E-Print Network [OSTI]

    Kusoglu, Ahmet

    2013-01-01

    polymer-electrolyte-fuel-cell (PEFC) applications are alwayssuch as conductivity. In a PEFC, the extent to which the

  2. Development of Thin Film Membrane Assemblies with Novel Nanostructured Electrocatalyst for Next Generation Fuel Cells

    E-Print Network [OSTI]

    Popov, Branko N.

    of the efficiency loss (80%) in a fuel cell arises due to the cathode. Oxygen reduction at the cathode requires Generation Fuel Cells Abstract: While problems related to CO poisoning still exist for the anode, most the largest amount of the catalyst in PEM fuel cells due to its lower activity. This problem needs

  3. Multi-paradigm multi-scale simulations for fuel cell catalysts and membranes

    E-Print Network [OSTI]

    van Duin, Adri

    materials and structures for fuel cells and for the associated hydrocarbon fuel reformers in an overall fuel processes of PEM fuel cells including: . the catalytic reactions at the anode, . the migration and intermediates at the cathode, and . the cathode based catalytic reactions to produce water. Such studies of new

  4. Liquid water quantification in the cathode side gas channels of a proton exchange membrane fuel cell through two-phase flow

    E-Print Network [OSTI]

    Kandlikar, Satish

    t s Liquid water in the cathode side channels of PEM fuel cell is quantified. Algorithm developed in MATLABÒ electrolyte membrane fuel cell Two-phase flow visualization Gas channels Area coverage ratio Water quantification a b s t r a c t Water management is crucial to the performance of PEM fuel cells. Water

  5. Solar-Hydrogen Fuel-Cell Vehicles

    E-Print Network [OSTI]

    DeLuchi, Mark A.; Ogden, Joan M.

    1993-01-01

    fuel cells are being developed: proton-exchange membrane (PEM), phosphoric acid, alkaline, molten carbonate

  6. Fuel cell water transport

    DOE Patents [OSTI]

    Vanderborgh, Nicholas E. (Los Alamos, NM); Hedstrom, James C. (Los Alamos, NM)

    1990-01-01

    The moisture content and temperature of hydrogen and oxygen gases is regulated throughout traverse of the gases in a fuel cell incorporating a solid polymer membrane. At least one of the gases traverses a first flow field adjacent the solid polymer membrane, where chemical reactions occur to generate an electrical current. A second flow field is located sequential with the first flow field and incorporates a membrane for effective water transport. A control fluid is then circulated adjacent the second membrane on the face opposite the fuel cell gas wherein moisture is either transported from the control fluid to humidify a fuel gas, e.g., hydrogen, or to the control fluid to prevent excess water buildup in the oxidizer gas, e.g., oxygen. Evaporation of water into the control gas and the control gas temperature act to control the fuel cell gas temperatures throughout the traverse of the fuel cell by the gases.

  7. Performance of a Polymer Electrolyte Membrane Fuel Cell Exposed to Transient CO Concentrations

    E-Print Network [OSTI]

    Van Zee, John W.

    fuel cell PEMFC . The data include relatively high 500 and 3000 ppm CO levels at 70°C cell temperature PEMFC applications. Poisoning and recovery rates are reported for saturated conditions and these rates are suitable for verifying numerical models of a PEMFC and establishing a baseline for new recovery schemes

  8. Nonlinear modelling of polymer electrolyte membrane fuel cell stack using nonlinear cancellation technique

    SciTech Connect (OSTI)

    Barus, R. P. P.; Tjokronegoro, H. A.; Leksono, E.; Ismunandar

    2014-09-25

    Fuel cells are promising new energy conversion devices that are friendly to the environment. A set of control systems are required in order to operate a fuel cell based power plant system optimally. For the purpose of control system design, an accurate fuel cell stack model in describing the dynamics of the real system is needed. Currently, linear model are widely used for fuel cell stack control purposes, but it has limitations in narrow operation range. While nonlinear models lead to nonlinear control implemnetation whos more complex and hard computing. In this research, nonlinear cancellation technique will be used to transform a nonlinear model into a linear form while maintaining the nonlinear characteristics. The transformation is done by replacing the input of the original model by a certain virtual input that has nonlinear relationship with the original input. Then the equality of the two models is tested by running a series of simulation. Input variation of H2, O2 and H2O as well as disturbance input I (current load) are studied by simulation. The error of comparison between the proposed model and the original nonlinear model are less than 1 %. Thus we can conclude that nonlinear cancellation technique can be used to represent fuel cell nonlinear model in a simple linear form while maintaining the nonlinear characteristics and therefore retain the wide operation range.

  9. Modeling and High-Resolution-Imaging Studies of Water-Content Profiles in a Polymer-Electrolyte-Fuel-Cell Membrane-Electrode Assembly

    E-Print Network [OSTI]

    Weber, A.Z.

    2008-01-01

    electrolyte-fuel-cell (PEFC) membrane electrode assembly (of a high aspect ratio PEFC with an active area of 2.1 x 7.7be considered in future PEFC modeling. The complicated GDL

  10. Air Breathing Direct Methanol Fuel Cell

    DOE Patents [OSTI]

    Ren; Xiaoming (Los Alamos, NM)

    2003-07-22

    A method for activating a membrane electrode assembly for a direct methanol fuel cell is disclosed. The method comprises operating the fuel cell with humidified hydrogen as the fuel followed by running the fuel cell with methanol as the fuel.

  11. Thin graphite bipolar plate with associated gaskets and carbon cloth flow-field for use in an ionomer membrane fuel cell

    DOE Patents [OSTI]

    Marchetti, George A. (Western Springs, IL)

    2003-01-03

    The present invention comprises a thin graphite plate with associated gaskets and pieces of carbon cloth that comprise a flow-field. The plate, gaskets and flow-field comprise a "plate and gasket assembly" for use in an ionomer membrane fuel cell, fuel cell stack or battery.

  12. Direct-hydrogen-fueled proton-exchange-membrane fuel cell system for transportation applications. Hydrogen vehicle safety report

    SciTech Connect (OSTI)

    Thomas, C.E. [Directed Technologies, Inc., Arlington, VA (United States)

    1997-05-01

    This report reviews the safety characteristics of hydrogen as an energy carrier for a fuel cell vehicle (FCV), with emphasis on high pressure gaseous hydrogen onboard storage. The authors consider normal operation of the vehicle in addition to refueling, collisions, operation in tunnels, and storage in garages. They identify the most likely risks and failure modes leading to hazardous conditions, and provide potential countermeasures in the vehicle design to prevent or substantially reduce the consequences of each plausible failure mode. They then compare the risks of hydrogen with those of more common motor vehicle fuels including gasoline, propane, and natural gas.

  13. Bipolar plate/diffuser for a proton exchange membrane fuel cell

    DOE Patents [OSTI]

    Besmann, Theodore M. (Oak Ridge, TN); Burchell, Timothy D. (Oak Ridge, TN)

    2001-01-01

    A combination bipolar plate/diffuser fuel cell component includes an electrically conducting solid material having: a porous region having a porous surface; and a hermetic region, the hermetic region defining at least a portion of at least one coolant channel, the porous region defining at least a portion of at least one reactant channel, the porous region defining a flow field medium for diffusing the reactant to the porous surface.

  14. Bipolar plate/diffuser for a proton exchange membrane fuel cell

    DOE Patents [OSTI]

    Besmann, Theodore M. (Oak Ridge, TN); Burchell, Timothy D. (Oak Ridge, TN)

    2000-01-01

    A combination bipolar plate/diffuser fuel cell component includes an electrically conducting solid material having: a porous region having a porous surface; and a hermetic region, the hermetic region defining at least a portion of at least one coolant channel, the porous region defining at least a portion of at least one reactant channel, the porous region defining a flow field medium for diffusing the reactant to the porous surface.

  15. Positronium Formation Of Glyeisdyl Methacrylic Acid (GMA)/Styrene Grafted On PVDF Membrane For Fuel Cells

    SciTech Connect (OSTI)

    Abdel-Hady, E. E.; Abdel-Hamed, M. O. [Physics Dpt, Faculty of Science, Minia University, Minia 61519 (Egypt); Eltonny, M. M. [Polymer Dpt, Atomic Energy Authority, Cairo (Egypt)

    2011-06-01

    Simultaneous gamma irradiation was used effectively for grafting of glycidyl methacrylic acid and styrene onto Poly vinyldine fluoride (PVDF). Membranes were characterized by thermal gravimetric analysis (TGA) and scanning electron microscopy (SEM). The properties of the obtained membranes were evaluated in terms of proton conductivity, methanol permeability and positron annihilation lifetime (PALS) parameters. The high probability of Positronium formation enables the application of PALS to the study of free volume. Good property values approved the applicability of the membrane from the cost benefit point of view.

  16. Elastic configurations of self-supported oxide membranes for fuel cells K. Kerman a,*,1

    E-Print Network [OSTI]

    Mahadevan, L.

    . Tallinen a,c,1 , S. Ramanathan a , L. Mahadevan a,b a School of Engineering and Applied Sciences, Harvard micro-machined yttria-stabilized zirconia membranes of edge length 160 mm fabricated by lithography

  17. Direct-hydrogen-fueled proton-exchange-membrane (PEM) fuel cell system for transportation applications. Quarterly technical progress report No. 4, April 1, 1995--June 30, 1995

    SciTech Connect (OSTI)

    Oei, D.

    1995-08-03

    This is the fourth Technical Progress Report for DOE Contract No. DE-AC02-94CE50389 awarded to Ford Motor Company on July 1, 1994. The overall objective of this contract is to advance the Proton-Exchange-Membrane (PEM) fuel cell technology for automotive applications. Specifically, the objectives resulting from this contract are to: (1) Develop and demonstrate on a laboratory propulsion system within 2-1/2 years a fully functional PEM Fuel Cell Power System (including fuel cell peripherals, peak power augmentation and controls). This propulsion system will achieve, or will be shown to have the growth potential to achieve, the weights, volumes, and production costs which are competitive with those same attributes of equivalently performing internal combustion engine propulsion systems; (2) Select and demonstrate a baseline onboard hydrogen storage method with acceptable weight, volume, cost, and safety features and analyze future alternatives; and (3) Analyze the hydrogen infrastructure components to ensure that hydrogen can be safely supplied to vehicles at geographically widespread convenient sites and at prices which are less than current gasoline prices per vehicle-mile; (4) Identify any future R&D needs for a fully integrated vehicle and for achieving the system cost and performance goals.

  18. 2007 Fuel Cell Technologies Market Report | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    power, and transportation -- including data on the range of fuel cell technologies -- polymer electrolyte membrane fuel cell (PEMFC), solid oxide fuel cell (SOFC), alkaline...

  19. Miniature fuel-cell system complete with on-demand fuel and oxidant supply

    E-Print Network [OSTI]

    Hur, JI; Kim, CJ

    2015-01-01

    scale direct methanol fuel cell development,” Energy, vol.flow-based microfluidic fuel cell," J. Am. Chem. Soc. , vol.electrolyte membrane fuel cell design," J. Power Sources,

  20. Characterization of Fuel-Cell Diffusion Media

    E-Print Network [OSTI]

    Gunterman, Haluna Penelope Frances

    2011-01-01

    polymer electrolyte membrane fuel cells, 2009. C. Lim and C.be incorporated directly into full fuel-cell simulations toFCgen1020ACS, www.ballard.com/fuel-cell-products, Accessed

  1. Commercialization of fuel-cells

    SciTech Connect (OSTI)

    Penner, S.S.; Appleby, A.J.; Baker, B.S.; Bates, J.L.; Buss, L.B.; Dollard, W.J.; Farris, P.J.; Gillis, E.A.; Gunsher, J.A.; Khandkar, A.; Krumpelt, M.; O'Sullivan, J.B.; Runte, G.; Savinell, R.F.; Selman, J.R.; Shores, D.A.; Tarman, P.

    1995-03-01

    This report is an abbreviated version of the ''Report of the DOE Advanced Fuel Cell Commercialization Working Group (AFC2WG),'' released January 1995. We describe fuel-cell commercialization for stationary power applications of phosphoric acid, molten carbonate, solid oxide, and polymer electrolyte membrane fuel cells.

  2. Research and development of Proton-Exchange-Membrane (PEM) fuel cell system for transportation applications. Fuel cell infrastructure and commercialization study

    SciTech Connect (OSTI)

    1996-11-01

    This paper has been prepared in partial fulfillment of a subcontract from the Allison Division of General Motors under the terms of Allison`s contract with the U.S. Department of Energy (DE-AC02-90CH10435). The objective of this task (The Fuel Cell Infrastructure and Commercialization Study) is to describe and prepare preliminary evaluations of the processes which will be required to develop fuel cell engines for commercial and private vehicles. This report summarizes the work undertaken on this study. It addresses the availability of the infrastructure (services, energy supplies) and the benefits of creating public/private alliances to accelerate their commercialization. The Allison prime contract includes other tasks related to the research and development of advanced solid polymer fuel cell engines and preparation of a demonstration automotive vehicle. The commercialization process starts when there is sufficient understanding of a fuel cell engine`s technology and markets to initiate preparation of a business plan. The business plan will identify each major step in the design of fuel cell (or electrochemical) engines, evaluation of the markets, acquisition of manufacturing facilities, and the technical and financial resources which will be required. The process will end when one or more companies have successfully developed and produced fuel cell engines at a profit. This study addressed the status of the information which will be required to prepare business plans, develop the economic and market acceptance data, and to identify the mobility, energy and environment benefits of electrochemical or fuel cell engines. It provides the reader with information on the status of fuel cell or electrochemical engine development and their relative advantages over competitive propulsion systems. Recommendations and descriptions of additional technical and business evaluations that are to be developed in more detail in Phase II, are included.

  3. Using polymer electrolyte membrane fuel cells in a hybrid surface ship propulsion plant to increase fuel efficiency

    E-Print Network [OSTI]

    Kroll, Douglas M. (Douglas Michael)

    2010-01-01

    An increasingly mobile US Navy surface fleet and oil price uncertainty contrast with the Navy's desire to lower the amount of money spent purchasing fuel. Operational restrictions limiting fuel use are temporary and cannot ...

  4. Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy Bills andOrder 422.1,an R7-CompatiblePlaying7NEPA/309Proceedings2 DOE1

  5. Identification and Characterization of Near-Term Direct Hydrogen Proton Exchange Membrane Fuel Cell Markets

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,ExecutiveFinancingR Walls21,Equipment:PetroleumDepartmentIdahoThis report is a

  6. Using a Quasipotential Transformation for Modeling Diffusion Media in Polymer-Electrolyte Fuel Cells

    E-Print Network [OSTI]

    Weber, Adam Z.

    2008-01-01

    Proton Exchange Membrane Fuel Cell , Numerical Heat Transferof Polymer Electrolyte Fuel Cells Using a Two-EquationLayers for Proton Exchange Membrane Fuel Cells 2. Absolute

  7. Using a Quasipotential Transformation for Modeling Diffusion Media in Polymer-Electrolyte Fuel Cells

    E-Print Network [OSTI]

    Weber, Adam Z.

    2008-01-01

    Proton Exchange Membrane Fuel Cell , Numerical Heat Transferof Polymer Electrolyte Fuel Cells Using a Two-EquationExchange Membrane Fuel Cells 2. Absolute Permeability ,

  8. Membranes > Batteries & Fuel Cells > Research > The Energy Materials Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid you notHeatMaRIE /about/_assets/images/icon-faces.jpgMeet

  9. Optimization of Fuel Cell System Operating Conditions for Fuel Cell Vehicles

    E-Print Network [OSTI]

    Zhao, Hengbing; Burke, Andy

    2008-01-01

    and Optimization of PEMFC Systems and its Application onExchange Membrane fuel cell (PEMFC) technology for use inExchange Membrane fuel cell (PEMFC) technology for use in

  10. Micro Fuel Cells Direct Methanol Fuel Cells

    E-Print Network [OSTI]

    Micro Fuel Cells TM Direct Methanol Fuel Cells for Portable Power A Fuel Cell System Developer-17, 2002 Phoenix, Arizona #12;Micro Fuel Cells Direct Methanol Fuel Cells for Portable Power Outline (1 Energy Content (Wh) Volume(cm^3) Li-Ion Battery DMFC #12;Direct Methanol Fuel Cell Technology

  11. Federico Zenith Control of fuel cells

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Federico Zenith Control of fuel cells Doctoral thesis for the degree of philosophiæ doctor with control of fuel cells, focusing on high-temperature proton- exchange-membrane fuel cells. Fuel cells-wide electric grids. Whereas studies about the design of fuel cell systems and the electrochemical properties

  12. Federico Zenith Control of fuel cells

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Federico Zenith Control of fuel cells Doctoral thesis for the degree of philosophiæ doctor with control of fuel cells, focusing on high-temperature proton-exchange-membrane fuel cells. Fuel cells-wide electric grids. Whereas studies about the design of fuel cell systems and the electrochemical properties

  13. NREL: Hydrogen and Fuel Cells Research - Hydrogen and Fuel Cell...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Adam Phillips, whose study was on membrane electrode assembly defect detection in PEM fuel cells. Phillips said that Ulsh and Bender helped him acclimate not only to NREL but...

  14. PEM/SPE fuel cell

    DOE Patents [OSTI]

    Grot, Stephen Andreas (Henrietta, NY)

    1998-01-01

    A PEM/SPE fuel cell including a membrane-electrode assembly (MEA) having a plurality of oriented filament embedded the face thereof for supporting the MEA and conducting current therefrom to contiguous electrode plates.

  15. PEM/SPE fuel cell

    DOE Patents [OSTI]

    Grot, S.A.

    1998-01-13

    A PEM/SPE fuel cell is described including a membrane-electrode assembly (MEA) having a plurality of oriented filament embedded the face thereof for supporting the MEA and conducting current therefrom to contiguous electrode plates. 4 figs.

  16. Methods of conditioning direct methanol fuel cells

    DOE Patents [OSTI]

    Rice, Cynthia (Newington, CT); Ren, Xiaoming (Menands, NY); Gottesfeld, Shimshon (Niskayuna, NY)

    2005-11-08

    Methods for conditioning the membrane electrode assembly of a direct methanol fuel cell ("DMFC") are disclosed. In a first method, an electrical current of polarity opposite to that used in a functioning direct methanol fuel cell is passed through the anode surface of the membrane electrode assembly. In a second method, methanol is supplied to an anode surface of the membrane electrode assembly, allowed to cross over the polymer electrolyte membrane of the membrane electrode assembly to a cathode surface of the membrane electrode assembly, and an electrical current of polarity opposite to that in a functioning direct methanol fuel cell is drawn through the membrane electrode assembly, wherein methanol is oxidized at the cathode surface of the membrane electrode assembly while the catalyst on the anode surface is reduced. Surface oxides on the direct methanol fuel cell anode catalyst of the membrane electrode assembly are thereby reduced.

  17. Abstract --The simulation of Proton Exchange Membrane Fuel Cells (PEMFC) may work as a powerful tool in the

    E-Print Network [OSTI]

    Simões, Marcelo Godoy

    be included in the fuel cell model. However, the current high costs of the FC stacks make both development tool in the development and widespread testing of alternative energy sources. In order to obtain hydropower), the Fuel Cell (FC) stacks have received heightened attention in the last few years

  18. A Carbon Corrosion Model to Evaluate the Effect of Steady State and Transient Operation of a Polymer Electrolyte Membrane Fuel Cell

    E-Print Network [OSTI]

    Pandy, Arun; Gummalla, Mallika; Atrazhev, Vadim V; Kuzminyh, Nikolay Yu; Sultanov, Vadim I; Burlatsky, Sergei F

    2014-01-01

    A carbon corrosion model is developed based on the formation of surface oxides on carbon and platinum of the polymer electrolyte membrane fuel cell electrode. The model predicts the rate of carbon corrosion under potential hold and potential cycling conditions. The model includes the interaction of carbon surface oxides with transient species like OH radicals to explain observed carbon corrosion trends under normal PEM fuel cell operating conditions. The model prediction agrees qualitatively with the experimental data supporting the hypothesis that the interplay of surface oxide formation on carbon and platinum is the primary driver of carbon corrosion.

  19. Fuel cell-fuel cell hybrid system

    DOE Patents [OSTI]

    Geisbrecht, Rodney A.; Williams, Mark C.

    2003-09-23

    A device for converting chemical energy to electricity is provided, the device comprising a high temperature fuel cell with the ability for partially oxidizing and completely reforming fuel, and a low temperature fuel cell juxtaposed to said high temperature fuel cell so as to utilize remaining reformed fuel from the high temperature fuel cell. Also provided is a method for producing electricity comprising directing fuel to a first fuel cell, completely oxidizing a first portion of the fuel and partially oxidizing a second portion of the fuel, directing the second fuel portion to a second fuel cell, allowing the first fuel cell to utilize the first portion of the fuel to produce electricity; and allowing the second fuel cell to utilize the second portion of the fuel to produce electricity.

  20. Hydrogen Fuel Cell Vehicles

    E-Print Network [OSTI]

    Delucchi, Mark

    1992-01-01

    Reforming for Molten Carbonate Fuel Cells," Berichte derVan Dijkum, "The Molten Carbonate Fuel Cell Programme in thealkaline, molten carbonate, and solid oxide. (Fuel cells

  1. Proton Transfer and Proton Concentrations in Protonated Nafion Fuel Cell Membranes D. B. Spry and M. D. Fayer*

    E-Print Network [OSTI]

    Fayer, Michael D.

    electrolyte fuel cells (PEFCs).1 In a PEFC, hydrogen is oxidized at the anode to generate a supply to the cathode, while preventing the passage of the reactant gases, is essential for the PEFC's operation. Nafion

  2. Fuel Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journal Article)Forthcoming UpgradesArea: PADD 1 to PADDFuelFuelFuel

  3. Scientists teach short course on fuel cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    covering Hydrogen and Lab Safety, the Laboratory's Membrane-and-Electrode Process, Fuel Cell Materials Characterization, Modeling, Durability and Testing. October 8, 2015...

  4. Manufacturing and Performance Assessment of Stamped, Laser Welded, and Nitrided FeCrV Stainless Steel Bipolar Plates for Proton Exchange Membrane Fuel Cells

    SciTech Connect (OSTI)

    Brady, Michael P; Abdelhamid, Mahmoud; Dadheech, G; Bradley, J; Toops, Todd J; Meyer III, Harry M; Tortorelli, Peter F

    2013-01-01

    A manufacturing and single-cell fuel cell performance study of stamped, laser welded, and gas nitrided ferritic stainless steel foils in an advanced automotive bipolar plate assembly design was performed. Two developmental foil compositions were studied: Fee20Cre4V and Fee23Cre4V wt.%. Foils 0.1 mm thick were stamped and then laser welded together to create single bipolar plate assemblies with cooling channels. The plates were then surface treated by pre-oxidation and nitridation in N2e4H2 based gas mixtures using either a conventional furnace or a short-cycle quartz lamp infrared heating system. Single-cell fuel cell testing was performed at 80 C for 500 h at 0.3 A/cm2 using 100% humidification and a 100%/40% humidification cycle that stresses the membrane and enhances release of the fluoride ion and promotes a more corrosive environment for the bipolar plates. Periodic high frequency resistance potential-current scans during the 500 h fuel cell test and posttest analysis of the membrane indicated no resistance increase of the plates and only trace levels of metal ion contamination.

  5. (Fuel Cells)(Fuel Cells) William Grove

    E-Print Network [OSTI]

    Chen, Yang-Yuan

    Fuel Cell #12; H2 O2 Power CH4 H2 Toyota H2 H2 #12; H2 ~253 #12; 2. 3. : 1. #12; #12;Fuel Cell #12; (Fuel Cells)(Fuel Cells) 1839 William Grove A H2O2 H2O2 2H; Fuel Cell #12;!! PEMFC DMFC SOFC (60~200) (60~100) (600~1000) #12; Proton

  6. fuel cells

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal GasAdministration Medal01 Sandia4)9 Federal RegisterStorm1 3446 YEAR/%2Afissile4/%2A en

  7. Hydrogen and Fuel Cell Technologies Program: Fuel Cells Fact...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen and Fuel Cell Technologies Program: Fuel Cells Fact Sheet Hydrogen and Fuel Cell Technologies Program: Fuel Cells Fact Sheet Fact sheet produced by the Fuel Cell...

  8. Modeling and High-Resolution-Imaging Studies of Water-Content Profiles in a Polymer-Electrolyte-Fuel-Cell Membrane-Electrode Assembly

    SciTech Connect (OSTI)

    Stevenson, Cynthia; Weber, A.Z.; Hickner, M.A.

    2008-03-06

    Water-content profiles across the membrane electrode assembly of a polymer-electrolyte fuel cell were measured using high-resolution neutron imaging and compared to mathematical-modeling predictions. It was found that the membrane held considerably more water than the other membrane-electrode constituents (catalyst layers, microporous layers, and macroporous gas-diffusion layers) at low temperatures, 40 and 60 C. The water content in the membrane and the assembly decreased drastically at 80 C where vapor transport and a heat-pipe effect began to dominate the water removal from the membrane-electrode assembly. In the regimes where vapor transport was significant, the through-plane water-content profile skewed towards the cathode. Similar trends were observed as the relative humidity of the inlet gases was lowered. This combined experimental and modeling approach has been beneficial in rationalizing the results of each and given insight into future directions for new experimental work and refinements to currently available models.

  9. DualNanofiber Composite Membranes for Formic Acid Fuel Cells Adam Edwards, Jun Woo Park, and Peter Pintauro

    E-Print Network [OSTI]

    formic acid crossover membranes. A dualnanofiber electrospinning approach was employed where composite. · Identify the membrane structure with superior resistance to crossover. Methodology: An electrospinning of the polymers and different membrane thicknesses. Electrospinning Conditions Results: Acknowledgements: NSF TN

  10. Ambient pressure fuel cell system

    DOE Patents [OSTI]

    Wilson, Mahlon S. (Los Alamos, NM)

    2000-01-01

    An ambient pressure fuel cell system is provided with a fuel cell stack formed from a plurality of fuel cells having membrane/electrode assemblies (MEAs) that are hydrated with liquid water and bipolar plates with anode and cathode sides for distributing hydrogen fuel gas and water to a first side of each one of the MEAs and air with reactant oxygen gas to a second side of each one of the MEAs. A pump supplies liquid water to the fuel cells. A recirculating system may be used to return unused hydrogen fuel gas to the stack. A near-ambient pressure blower blows air through the fuel cell stack in excess of reaction stoichiometric amounts to react with the hydrogen fuel gas.

  11. Fuel Cells and Renewable Gaseous Fuels

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cell Technologies Office | 1 7142015 Fuel Cells and Renewable Gaseous Fuels Bioenergy 2015: Renewable Gaseous Fuels Breakout Session Sarah Studer, PhD ORISE Fellow Fuel Cell...

  12. Fuel Cell Handbook, Fourth Edition

    SciTech Connect (OSTI)

    Stauffer, D.B; Hirschenhofer, J.H.; Klett, M.G.; Engleman, R.R.

    1998-11-01

    Robust progress has been made in fuel cell technology since the previous edition of the Fuel Cell Handbook was published in January 1994. This Handbook provides a foundation in fuel cells for persons wanting a better understanding of the technology, its benefits, and the systems issues that influence its application. Trends in technology are discussed, including next-generation concepts that promise ultra high efficiency and low cost, while providing exceptionally clean power plant systems. Section 1 summarizes fuel cell progress since the last edition and includes existing power plant nameplate data. Section 2 addresses the thermodynamics of fuel cells to provide an understanding of fuel cell operation at two levels (basic and advanced). Sections 3 through 6 describe the four major fuel cell types and their performance based on cell operating conditions. The section on polymer electrolyte membrane fuel cells has been added to reflect their emergence as a significant fuel cell technology. Phosphoric acid, molten carbonate, and solid oxide fuel cell technology description sections have been updated from the previous edition. New information indicates that manufacturers have stayed with proven cell designs, focusing instead on advancing the system surrounding the fuel cell to lower life cycle costs. Section 7, Fuel Cell Systems, has been significantly revised to characterize near-term and next-generation fuel cell power plant systems at a conceptual level of detail. Section 8 provides examples of practical fuel cell system calculations. A list of fuel cell URLs is included in the Appendix. A new index assists the reader in locating specific information quickly.

  13. Development of alkaline fuel cells.

    SciTech Connect (OSTI)

    Hibbs, Michael R.; Jenkins, Janelle E.; Alam, Todd Michael; Janarthanan, Rajeswari; Horan, James L.; Caire, Benjamin R.; Ziegler, Zachary C.; Herring, Andrew M.; Yang, Yuan; Zuo, Xiaobing; Robson, Michael H.; Artyushkova, Kateryna; Patterson, Wendy; Atanassov, Plamen Borissov

    2013-09-01

    This project focuses on the development and demonstration of anion exchange membrane (AEM) fuel cells for portable power applications. Novel polymeric anion exchange membranes and ionomers with high chemical stabilities were prepared characterized by researchers at Sandia National Laboratories. Durable, non-precious metal catalysts were prepared by Dr. Plamen Atanassov's research group at the University of New Mexico by utilizing an aerosol-based process to prepare templated nano-structures. Dr. Andy Herring's group at the Colorado School of Mines combined all of these materials to fabricate and test membrane electrode assemblies for single cell testing in a methanol-fueled alkaline system. The highest power density achieved in this study was 54 mW/cm2 which was 90% of the project target and the highest reported power density for a direct methanol alkaline fuel cell.

  14. Electrochemical Removal of Carbon Monoxide in Reformate Hydrogen for Fueling Proton Exchange Membrane

    E-Print Network [OSTI]

    Weidner, John W.

    - based fuels is known to degrade the performance of a proton ex- change membrane fuel cell PEMFC effects of CO on the performance of a PEMFC, researchers have explored ways to modify fuel cell opera

  15. Ceramic Fuel Cells (SOFC)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Engineering Argonne National Laboratory Thursday, August 11, 2011 Ceramic Fuel Cells (SOFC) Manufacturing Fuel Cell Manhattan Project: * Joe Bonadies - Delphi * Rick...

  16. Modeling of solid oxide fuel cells

    E-Print Network [OSTI]

    Lee, Won Yong, S.M. Massachusetts Institute of Technology

    2006-01-01

    A comprehensive membrane-electrode assembly (MEA) model of Solid Oxide Fuel Cell (SOFC)s is developed to investigate the effect of various design and operating conditions on the cell performance and to examine the underlying ...

  17. Using a Quasipotential Transformation for Modeling Diffusion Media in Polymer-Electrolyte Fuel Cells

    E-Print Network [OSTI]

    Weber, Adam Z.

    2008-01-01

    Exchange Membrane Fuel Cells , Journal of Power Sources,in Polymer-Electrolyte Fuel Cells , in M. Schlesinger, ed. ,in Polymer- Electrolyte Fuel Cells , Journal of the

  18. Modeling Cold Start in a Polymer-Electrolyte Fuel Cell

    E-Print Network [OSTI]

    Balliet, Ryan

    2010-01-01

    Polymer Electrolyte Fuel Cell Cross—Section Below Freezingstart—up of a fuel cell from below freezing. Because waterFreezing in a Polymer—Electrolyte—Membrane Fuel Cell,” ECS

  19. Simulating Nonuniform Properties in Polymer-Electrolyte Fuel Cells

    E-Print Network [OSTI]

    Weber, A.Z.; Newman, J.

    2006-01-01

    IN POLYMER-ELECTROLYTE FUEL CELLS A. Z. Weber and J. Newmanvapor flow throughout all of the fuel-cell sandwich layers,of the membrane thickness in fuel-cell water management. The

  20. DOE Fuel Cell Technologies Office: 2013 Fuel Cell Seminar and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Office: 2013 Fuel Cell Seminar and Energy Exposition DOE Fuel Cell Technologies Office: 2013 Fuel Cell Seminar and Energy Exposition Overview of DOE's Fuel Cell Technologies Office...

  1. Method of fabricating electrode catalyst layers with directionally oriented carbon support for proton exchange membrane fuel cell

    DOE Patents [OSTI]

    Liu, Di-Jia (Naperville, IL); Yang, Junbing (Bolingbrook, IL)

    2012-03-20

    A membrane electrode assembly (MEA) of the invention comprises an anode and a cathode and a proton conductive membrane therebetween, the anode and the cathode each comprising a patterned sheet of longitudinally aligned transition metal-containing carbon nanotubes, wherein the carbon nanotubes are in contact with and are aligned generally perpendicular to the membrane, wherein a catalytically active transition metal is incorporated throughout the nanotubes.

  2. POLYMER ELECTROLYTE FUEL CELLS

    E-Print Network [OSTI]

    Petta, Jason

    POLYMER ELECTROLYTE FUEL CELLS: The Gas Diffusion Layer Johannah Itescu Princeton University PRISM REU #12;PEM FUEL CELLS: A little background information I. What do fuel cells do? Generate electricity through chemical reaction #12;PEM FUEL CELLS: A little background information -+ + eHH 442 2 0244 22 He

  3. Molecular modeling of the morphology and transport properties of two direct methanol fuel cell membranes: phenylated sulfonated poly(ether ether ketone ketone) versus Nafion

    SciTech Connect (OSTI)

    Devanathan, Ramaswami; Idupulapati, Nagesh B.; Dupuis, Michel

    2012-08-14

    We have used molecular dynamics simulations to examine membrane morphology and the transport of water, methanol and hydronium in phenylated sulfonated poly ether ether ketone ketone (Ph-SPEEKK) and Nafion membranes at 360 K for a range of hydration levels. At comparable hydration levels, the pore diameter is smaller, the sulfonate groups are more closely packed, the hydronium ions are more strongly bound to sulfonate groups, and the diffusion of water and hydronium is slower in Ph-SPEEKK relative to the corresponding properties in Nafion. The aromatic carbon backbone of Ph-SPEEKK is less hydrophobic than the fluorocarbon backbone of Nafion. Water network percolation occurs at a hydration level ({lambda}) of {approx}8 H{sub 2}O/SO{sub 3}{sup -}. At {lambda} = 20, water, methanol and hydronium diffusion coefficients were 1.4 x 10{sup -5}, 0.6 x 10{sup -5} and 0.2 x 10{sup -5} cm{sup 2}/s, respectively. The pore network in Ph-SPEEKK evolves dynamically and develops wide pores for {lambda} > 20, which leads to a jump in methanol crossover and ion transport. This study demonstrates the potential of aromatic membranes as low-cost challengers to Nafion for direct methanol fuel cell applications and the need to develop innovative strategies to combat methanol crossover at high hydration levels.

  4. Hydrogen Fuel Cell Vehicles

    E-Print Network [OSTI]

    Delucchi, Mark

    1992-01-01

    Experience with the German Hydrogen Fuel Project," HydrogenHydrogen Fuel Cell Vehicles UCD-ITS-RR-92-14 September bycost than both. Solar-hydrogen fuel- cell vehicles would be

  5. Model-based control strategies in the dynamic interaction of air supply and fuel cell

    E-Print Network [OSTI]

    Grujicic, Mica

    to the type of membrane (polymer electrolyte membrane fuel cells, solid oxide fuel cells, molten carbonate to analyse and optimize the transient behaviour of a polymer electrolyte membrane (PEM) fuel cell system such as a battery. Keywords: polymer electrolyte membrane, fuel cells NOTATION a water vapour activity cv water

  6. Sandia Energy - ECIS-Automotive Fuel Cell Corporation: Hydrocarbon...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ECIS-Automotive Fuel Cell Corporation: Hydrocarbon Membrane Fuels the Success of Future Generation Vehicles Home Energy Transportation Energy CRF Partnership Energy Efficiency...

  7. Platinum-Alloy Cathode Catalyst Degradation in Proton Exchange Membrane Fuel Cells: Nanometer-Scale Compositional and Morphological Changes

    E-Print Network [OSTI]

    Chen, Shuo

    Electrochemical measurements showed an ?75% Pt surface area loss and an ?40% specific activity loss for a membrane electrode assembly (MEA) cathode with acid-treated “Pt[subscript 3]Co ” catalyst particles in a H[subscript ...

  8. Influence of wettability on liquid water transport in gas diffusion layer of proton exchange membrane fuel cells (PEMFC)

    E-Print Network [OSTI]

    Hamza Chraibi; L. Ceballos; M. Prat; Michel Quintard; Alexandre Vabre

    2009-09-16

    Water management is a key factor that limits PEFC's performance. We show how insights into this problem can be gained from pore-scale simulations of water invasion in a model fibrous medium. We explore the influence of contact angle on the water invasion pattern and water saturation at breakthrough and show that a dramatic change in the invasion pattern, from fractal to compact, occurs as the system changes from hydrophobic to hydrophilic. Then, we explore the case of a system of mixed wettability, i.e. containing both hydrophilic and hydrophobic pores. The saturation at breakthrough is studied as a function of the fraction of hydrophilic pores. The results are discussed in relation with the water management problem, the optimal design of a GDL and the fuel cell performance degradation mechanisms. We outline how the study could be extended to 3D systems, notably from binarised images of GDLs obtained by X ray microtomography.

  9. Microbial fuel cells

    DOE Patents [OSTI]

    Nealson, Kenneth H; Pirbazari, Massoud; Hsu, Lewis

    2013-04-09

    A microbial fuel cell includes an anode compartment with an anode and an anode biocatalyst and a cathode compartment with a cathode and a cathode biocatalyst, with a membrane positioned between the anode compartment and the cathode compartment, and an electrical pathway between the anode and the cathode. The anode biocatalyst is capable of catalyzing oxidation of an organic substance, and the cathode biocatalyst is capable of catalyzing reduction of an inorganic substance. The reduced organic substance can form a precipitate, thereby removing the inorganic substance from solution. In some cases, the anode biocatalyst is capable of catalyzing oxidation of an inorganic substance, and the cathode biocatalyst is capable of catalyzing reduction of an organic or inorganic substance.

  10. Nanoscale study of reactive transport in catalyst layer of proton exchange membrane fuel cells with precious and non-precious catalysts using lattice Boltzmann method

    E-Print Network [OSTI]

    Chen, Li; Kang, Qinjun; Holby, Edward F; Tao, Wen-Quan

    2014-01-01

    High-resolution porous structures of catalyst layer (CL) with multicomponent in proton exchange membrane fuel cells are reconstructed using a reconstruction method called quartet structure generation set. Characterization analyses of nanoscale structures are implemented including pore size distribution, specific area and phase connectivity. Pore-scale simulation methods based on the lattice Boltzmann method are developed and used to predict the macroscopic transport properties including effective diffusivity and proton conductivity. Nonuniform distributions of ionomer in CL generates more tortuous pathway for reactant transport and greatly reduces the effective diffusivity. Tortuosity of CL is much higher than conventional Bruggeman equation adopted. Knudsen diffusion plays a significant role in oxygen diffusion and significantly reduces the effective diffusivity. Reactive transport inside the CL is also investigated. Although the reactive surface area of non-precious metal catalyst (NPMC) CL is much higher t...

  11. Catalysts and materials development for fuel cell power generation

    E-Print Network [OSTI]

    Weiss, Steven E

    2005-01-01

    Catalytic processing of fuels was explored in this thesis for both low-temperature polymer electrolyte membrane (PEM) fuel cell as well as high-temperature solid oxide fuel cell (SOFC) applications. Novel catalysts were ...

  12. Fuel Cells Fact Sheet

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015ExecutiveFluorescentDanKathy LoftusFuel CellFuel Fuel CellsCells Fuel

  13. 40 The Electrochemical Society Interface Winter 2003 ne quickly realizes that a polymer electrolyte membrane fuel cell

    E-Print Network [OSTI]

    Sethuraman, Vijay A.

    . Rather, it is a tightly integrated system of pumps, valves, flow meters, sensors, and heat exchangers complete form, a MEA consists of seven layers: a proton exchange membrane, three-phase anode and cathode- tetrafluoroethylene (PTFE) backbone with perfluorinated- vinyl-polyether side chains containing sulphonic acid end

  14. Webinar: Fuel Cell Buses

    Broader source: Energy.gov [DOE]

    Video recording and text version of the webinar titled, Fuel Cell Buses, originally presented on September 12, 2013.

  15. Hydrogen Fuel Cell Vehicles

    E-Print Network [OSTI]

    Delucchi, Mark

    1992-01-01

    California, June (1986). General Electric, Direct Energy Conversion Programs, Feasibility Study ofSPE Fuel Cell Power Plants

  16. Optimization of the performance of polymer electrolyte fuel cell membrane-electrode assemblies : roles of curing parameters on the catalyst and ionomer structures and morphology.

    SciTech Connect (OSTI)

    Bose, A. B.; Shaik, R.; Mawdsley, J.; Chemical Sciences and Engineering Division; Northern Illinois Univ.

    2008-07-15

    In order to understand the origin of performance variations in polymer electrolyte membrane fuel cells (PEMFCs), a series of membrane-electrode assemblies (MEAs) with identical electrode layer compositions were prepared using different electrode curing conditions, their performances were evaluated, and their morphologies determined by scanning electron microscopy (SEM). The polarization curves varied markedly primarily due to differences in morphologies of electrodes, which were dictated by the curing processes. The highest performing MEAs (1.46 W cm{sup -2} peak power density at 3.2 A cm{sup -2} and 80 C) were prepared using a slow curing process at a lower temperature, whereas those MEAs prepared using a faster curing process performed poorly (0.1948 W cm{sup -2} peak power density at 440 mA cm{sup -2} and 80 C). The slowly cured MEAs showed uniform electrode catalyst and ionomer distributions, as revealed in SEM images and elemental maps. The relatively faster cured materials exhibited uneven distribution of ionomer with significant catalyst clustering. Collectively, these results indicate that to achieve optimal performance, factors that affect the dynamics of the curing process, such as rate of solvent evaporation, must be carefully controlled to avoid solvent trapping, minimize catalyst coagulation, and promote even distribution of ionomer.

  17. Formic acid fuel cells and catalysts

    DOE Patents [OSTI]

    Masel, Richard I.; Larsen, Robert; Ha, Su Yun

    2010-06-22

    An exemplary fuel cell of the invention includes a formic acid fuel solution in communication with an anode (12, 134), an oxidizer in communication with a cathode (16, 135) electrically linked to the anode, and an anode catalyst that includes Pd. An exemplary formic acid fuel cell membrane electrode assembly (130) includes a proton-conducting membrane (131) having opposing first (132) and second surfaces (133), a cathode catalyst on the second membrane surface, and an anode catalyst including Pd on the first surface.

  18. Fuel cells and fuel cell catalysts

    DOE Patents [OSTI]

    Masel, Richard I.; Rice, Cynthia A.; Waszczuk, Piotr; Wieckowski, Andrzej

    2006-11-07

    A direct organic fuel cell includes a formic acid fuel solution having between about 10% and about 95% formic acid. The formic acid is oxidized at an anode. The anode may include a Pt/Pd catalyst that promotes the direct oxidation of the formic acid via a direct reaction path that does not include formation of a CO intermediate.

  19. Method of fabricating electrode catalyst layers with directionally oriented carbon support for proton exchange membrane fuel cell

    DOE Patents [OSTI]

    Liu, Di-Jia (Naperville, IL); Yang, Junbing (Willow brook, IL)

    2010-07-20

    A method of making a membrane electrode assembly (MEA) having an anode and a cathode and a proton conductive membrane there between. A bundle of longitudinally aligned carbon nanotubes with a catalytically active transition metal incorporated in the nanotubes forms at least one portion of the MEA and is in contact with the membrane. A combination selected from one or more of a hydrocarbon and an organometallic compound containing an catalytically active transition metal and a nitrogen containing compound and an inert gas and a reducing gas is introduced into a first reaction zone maintained at a first reaction temperature for a time sufficient to vaporize material therein. The vaporized material is transmitted to a second reaction zone maintained at a second reaction temperature for a time sufficient to grow longitudinally aligned carbon nanotubes with a catalytically active transition metal incorporated throughout the nanotubes. The nanotubes are in contact with a portion of the MEA at production or being positioned in contact thereafter. Methods of forming a PEMFC are also disclosed.

  20. IMIDAZOLE-BASED IONIC LIQUIDS FOR USE IN POLYMER ELECTROLYTE MEMBRANE FUEL CELLS: EFFECT OF ELECTRON-WITHDRAWING AND ELECTRON-DONATING SUBSTITUENTS

    SciTech Connect (OSTI)

    Chang, E.; Fu, Y.; Kerr, J.

    2009-01-01

    Current polymer electrolyte membrane fuel cells (PEMFCs) require humidifi cation for acceptable proton conductivity. Development of a novel polymer that is conductive without a water-based proton carrier is desirable for use in automobiles. Imidazole (Im) is a possible replacement for water as a proton solvent; Im can be tethered to the polymer structure by means of covalent bonds, thereby providing a solid state proton conducting membrane where the solvating groups do not leach out of the fuel cell. These covalent bonds can alter the electron availability of the Im molecule. This study investigates the effects of electron-withdrawing and electron-donating substituents on the conductivity of Im complexed with methanesulfonic acid (MSA) in the form of ionic liquids. Due to the changes in the electronegativity of nitrogen, it is expected that 2-phenylimidazole (2-PhIm, electron-withdrawing) will exhibit increased conductivity compared to Im, while 2-methylimidazole (2-MeIm, electron-donating) will exhibit decreased conductivity. Three sets of ionic liquids were prepared at defi ned molar ratios: Im-MSA, 2-PhIm-MSA, and 2-MeIm- MSA. Differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and 1H-NMR were used to characterize each complex. Impedance analysis was used to determine the conductivity of each complex. Both the 2-PhIm-MSA and 2-MeIm-MSA ionic liquids were found to be less conductive than the Im-MSA complex at base-rich compositions, but more conductive at acid-rich compositions. 1H-NMR data shows a downfi eld shift of the proton on nitrogen in 2-PhIm compared to Im, suggesting that other factors may diminish the electronic effects of the electron withdrawing group at base-rich compositions. Further studies examining these effects may well result in increased conductivity for Im-based complexes. Understanding the conductive properties of Im-derivatives due to electronic effects will help facilitate the development of a new electrolyte appropriate for automotive fuel cell use.

  1. Micro fuel cell

    SciTech Connect (OSTI)

    Zook, L.A.; Vanderborgh, N.E. [Los Alamos National Lab., NM (United States); Hockaday, R. [Energy Related Devices Inc., Los Alamos, NM (United States)

    1998-12-31

    An ambient temperature, liquid feed, direct methanol fuel cell device is under development. A metal barrier layer was used to block methanol crossover from the anode to the cathode side while still allowing for the transport of protons from the anode to the cathode. A direct methanol fuel cell (DMFC) is an electrochemical engine that converts chemical energy into clean electrical power by the direct oxidation of methanol at the fuel cell anode. This direct use of a liquid fuel eliminates the need for a reformer to convert the fuel to hydrogen before it is fed into the fuel cell.

  2. Hydrogen and Fuel Cell Technologies Update: 2010 Fuel Cell Seminar...

    Broader source: Energy.gov (indexed) [DOE]

    2010 Fuel Cell Seminar and Exposition on October 19, 2010. Hydrogen and Fuel Cell Technologies Update More Documents & Publications DOE Hydrogen and Fuel Cell Overview: 2011...

  3. Stationary Fuel Cells: Overview of Hydrogen and Fuel Cell Activities

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Stationary Fuel Cells: Overview of Hydrogen and Fuel Cell Activities Pete Devlin Fuel Cell Technologies Program United States Department of Energy Federal Utility Partnership...

  4. Fuel Cells for Supermarkets: Cleaner Energy with Fuel Cell Combined...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Supermarkets: Cleaner Energy with Fuel Cell Combined Heat and Power Systems Fuel Cells for Supermarkets: Cleaner Energy with Fuel Cell Combined Heat and Power Systems Presented...

  5. Center for Fuel Cells I/UCRC Membership Agreement

    E-Print Network [OSTI]

    Almor, Amit

    Center for Fuel Cells I/UCRC Membership Agreement This agreement is made this _____ day of Proton Exchange Membrane Fuel Cells (PEMFCs) by performing research in (1) fuel cell design; (2) fuel for hydrogen production and the fuel cell electrodes; and (5) motor design and power conditioning

  6. Molten carbonate fuel cell

    DOE Patents [OSTI]

    Kaun, Thomas D. (New Lenox, IL); Smith, James L. (Lemont, IL)

    1987-01-01

    A molten electrolyte fuel cell with an array of stacked cells and cell enclosures isolating each cell except for access to gas manifolds for the supply of fuel or oxidant gas or the removal of waste gas, the cell enclosures collectively providing an enclosure for the array and effectively avoiding the problems of electrolyte migration and the previous need for compression of stack components, the fuel cell further including an inner housing about and in cooperation with the array enclosure to provide a manifold system with isolated chambers for the supply and removal of gases. An external insulated housing about the inner housing provides thermal isolation to the cell components.

  7. Molten carbonate fuel cell

    DOE Patents [OSTI]

    Kaun, T.D.; Smith, J.L.

    1986-07-08

    A molten electrolyte fuel cell is disclosed with an array of stacked cells and cell enclosures isolating each cell except for access to gas manifolds for the supply of fuel or oxidant gas or the removal of waste gas. The cell enclosures collectively provide an enclosure for the array and effectively avoid the problems of electrolyte migration and the previous need for compression of stack components. The fuel cell further includes an inner housing about and in cooperation with the array enclosure to provide a manifold system with isolated chambers for the supply and removal of gases. An external insulated housing about the inner housing provides thermal isolation to the cell components.

  8. Direct hydrocarbon fuel cells

    DOE Patents [OSTI]

    Barnett, Scott A.; Lai, Tammy; Liu, Jiang

    2010-05-04

    The direct electrochemical oxidation of hydrocarbons in solid oxide fuel cells, to generate greater power densities at lower temperatures without carbon deposition. The performance obtained is comparable to that of fuel cells used for hydrogen, and is achieved by using novel anode composites at low operating temperatures. Such solid oxide fuel cells, regardless of fuel source or operation, can be configured advantageously using the structural geometries of this invention.

  9. Chalcogen catalysts for polymer electrolyte fuel cell

    DOE Patents [OSTI]

    Alonso-Vante, Nicolas (Buxerolles, FR); Zelenay, Piotr (Los Alamos, NM); Choi, Jong-Ho (Los Alamos, NM); Wieckowski, Andrzej (Champaign, IL); Cao, Dianxue (Urbana, IL)

    2009-09-15

    A methanol-tolerant cathode catalyst and a membrane electrode assembly for fuel cells that includes such a cathode catalyst. The cathode catalyst includes a support having at least one transition metal in elemental form and a chalcogen disposed on the support. Methods of making the cathode catalyst and membrane electrode assembly are also described.

  10. Chalcogen catalysts for polymer electrolyte fuel cell

    DOE Patents [OSTI]

    Zelenay, Piotr (Los Alamos, NM); Choi, Jong-Ho (Los Alamos, NM); Alonso-Vante, Nicolas (France, FR); Wieckowski, Andrzej (Champaign, IL); Cao, Dianxue (Urbana, IL)

    2010-08-24

    A methanol-tolerant cathode catalyst and a membrane electrode assembly for fuel cells that includes such a cathode catalyst. The cathode catalyst includes a support having at least one transition metal in elemental form and a chalcogen disposed on the support. Methods of making the cathode catalyst and membrane electrode assembly are also described.

  11. Engineering supported membranes for cell biology

    E-Print Network [OSTI]

    Yu, Cheng-han; Groves, Jay T.

    2010-01-01

    membranes in structural biology. J Struct Biol 168:1–2 50.supported membranes for cell biology Cheng-han Yu • Jay T.range problems in cell biology. Because lateral mobility of

  12. Fuel Cells at NASCAR

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015ExecutiveFluorescentDanKathy LoftusFuel CellFuel Fuelgreen h yFuel Cells

  13. Commercializing light-duty plug-in/plug-out hydrogen-fuel-cell vehicles: “Mobile Electricity” technologies and opportunities

    E-Print Network [OSTI]

    Williams, Brett D; Kurani, Kenneth S

    2007-01-01

    plots two different fuel-cell applications with dramaticallycommercializing fuel cells in various applications, startingMembrane Fuel Cell System for Transportation Applications:

  14. Sputter-Deposited Pt PEM Fuel Cell Electrodes: Particles vs M. D. Gasda,a

    E-Print Network [OSTI]

    Gall, Daniel

    Sputter-Deposited Pt PEM Fuel Cell Electrodes: Particles vs Layers M. D. Gasda,a R. Teki,b T.-M. Lu as cathode electrodes in proton exchange membrane PEM fuel cells using Nafion 1135 membranes and Teflon, 2009. Published March 24, 2009. Polymer electrolyte membrane or proton exchange membrane PEM fuel cells

  15. Fuel Cell Technologies Overview

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015ExecutiveFluorescentDanKathy LoftusFuel Cell Seminar2015ofFuel Cell

  16. Fuel Cell Technologies Overview

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015ExecutiveFluorescentDanKathy LoftusFuel Cell Seminar2015ofFuel CellStates

  17. FUEL CELLS FOR TRANSPORTATION

    E-Print Network [OSTI]

    for Fuel Cells for Transportation Energy Efficiency and Renewable Energy Office of Transportation............................................................................................. 101 A. R&D of a 50-kW, High-Efficiency, High-Power-Density, CO-Tolerant PEM Fuel Cell Stack SystemFUEL CELLS FOR TRANSPORTATION 2 0 0 1 A N N U A L P R O G R E S S R E P O R T U.S. Department

  18. Hydrogen Fuel Cells

    Fuel Cell Technologies Publication and Product Library (EERE)

    The fuel cell — an energy conversion device that can efficiently capture and use the power of hydrogen — is the key to making it happen.

  19. Opportunities with Fuel Cells

    Reports and Publications (EIA)

    1994-01-01

    The concept for fuel cells was discovered in the nineteenth century. Today, units incorporating this technology are becoming commercially available for cogeneration applications.

  20. Fuel Cell Technologies Budget

    SciTech Connect (OSTI)

    EERE

    2012-03-16

    The Fuel Cell Technologies Office receives appropriations from Energy and Water Development. The offices's major activities and budget are outlined in this Web page.

  1. THERMAL ANALYSIS OF AIR-COOLED FUEL CELLS Setareh Shahsavari

    E-Print Network [OSTI]

    Bahrami, Majid

    - cooled proton exchange membrane fuel cells (PEMFC). In the modeled fuel cell stack, forced air flow for thermal analysis of air-cooled PEMFC stacks, where temperature non-uniformity is high and thermal

  2. Bootstrapping a Sustainable North American PEM Fuel Cell Industry...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Industry: Could a Federal Acquisition Program Make a Difference? The North American Proton Exchange Membrane (PEM) fuel cell industry may be at a critical juncture. A...

  3. DOE/Boeing Sponsored Projects in Aviation Fuel Cell Technology...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    30, 2010, in Washington, DC. aircraft8klebanoff.pdf More Documents & Publications Proton Exchange Membrane Fuel Cells for Electrical Power Generation On-Board Commercial...

  4. Early Adoption of Fuel Cell Technologies | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    about this study, view the full report, Bootstrapping a Sustainable North American Proton Exchange Membrane Fuel Cell Industry: Could a Federal Acquisition Program Make a...

  5. High Temperature Fuel Cells in the European Union

    Broader source: Energy.gov [DOE]

    Presentation on High Temperature Fuel Cells in the European Union to the High Temperature Membrane Working Group, May 25, 2004 in Philadelphia, PA.

  6. Fuel Cell Freeze Startup and Landscape of FC Freeze Patents

    E-Print Network [OSTI]

    Fuel Cell Freeze Startup and Landscape of FC Freeze Patents DOE Workshop on Fuel Cell Operations of PEM fuel cells from sub-freezing temperatures. Approach · Collect data/information through literature and other factors within a vehicle. #12;4 Freeze & Rapid Startup of PEM Fuel Cells · Maintaining membrane

  7. Preventing CO poisoning in fuel cells

    DOE Patents [OSTI]

    Gottesfeld, Shimshon (Los Alamos, NM)

    1990-01-01

    Proton exchange membrane (PEM) fuel cell performance with CO contamination of the H.sub.2 fuel stream is substantially improved by injecting O.sub.2 into the fuel stream ahead of the fuel cell. It is found that a surface reaction occurs even at PEM operating temperatures below about 100.degree. C. to oxidatively remove the CO and restore electrode surface area for the H.sub.2 reaction to generate current. Using an O.sub.2 injection, a suitable fuel stream for a PEM fuel cell can be formed from a methanol source using conventional reforming processes for producing H.sub.2.

  8. Webinar: Fuel Cell Mobile Lighting

    Broader source: Energy.gov [DOE]

    Video recording of the Fuel Cell Technologies Office webinar, Fuel Cell Mobile Lighting, originally presented on November 13, 2012.

  9. Fuel Cells in Telecommunications

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015ExecutiveFluorescentDanKathy LoftusFuel CellFuel Fuelgreen hfor|Fuel

  10. Controlling the mechanical and transport properties of layer-by-layer films and electrospun mat composite membranes for fuel cell applications

    E-Print Network [OSTI]

    Liu, David ShinRen

    2014-01-01

    There is an ever increasing need for clean, portable energy devices, such as fuel cells and high energy batteries to replace or reduce the world's dependence on fossil fuels. The continued development of thin-film solid ...

  11. Unveiling N-Protonation and Anion-Binding Effects on Fe/N/C Catalysts for O2 Reduction in Proton-Exchange-Membrane Fuel Cells

    SciTech Connect (OSTI)

    J Herranz; F Jaouen; M Lefevre; U Kramm; E Proietti; J Dodelet; P Bogdanoff; S Fiechter; I Abs-Wurbach; et al.

    2011-12-31

    The high cost of proton-exchange-membrane fuel cells would be considerably reduced if platinum-based catalysts were replaced by iron-based substitutes, which have recently demonstrated comparable activity for oxygen reduction but whose cause of activity decay in acidic medium has been elusive. Here, we reveal that the activity of Fe/N/C catalysts prepared through a pyrolysis in NH{sub 3} is mostly imparted by acid-resistant FeN{sub 4} sites whose turnover frequency for the O{sub 2} reduction can be regulated by fine chemical changes of the catalyst surface. We show that surface N-groups protonate at pH 1 and subsequently bind anions. This results in decreased activity for the O{sub 2} reduction. The anions can be removed chemically or thermally, which restores the activity of acid-resistant FeN{sub 4} sites. These results are interpreted as an increased turnover frequency of FeN{sub 4} sites when specific surface N-groups protonate. These unprecedented findings provide a new perspective for stabilizing the most active Fe/N/C catalysts known to date.

  12. Annealing induced interfacial layers in niobium-clad stainless steel developed as a bipolar plate material for polymer electrolyte membrane fuel cell stacks

    SciTech Connect (OSTI)

    Hong, Sung Tae; Weil, K. Scott; Choi, Jung-Pyung; Bae, In-Tae; Pan, Jwo

    2010-05-01

    Niobium (Nb)-clad 304L stainless steel (SS) manufactured by cold rolling is currently under consideration for use as a bipolar plate material in polymer electrolyte membrane fuel cell (PEMFC) stacks. To make the fabrication of bipolar plates using the Nb-clad SS feasible, annealing may be necessary for the Nb-clad SS to reduce the springback induced by cold rolling. However, the annealing can develop an interfacial layer between the Nb cladding and the SS core and the interfacial layer plays a key role in the failure of the Nb-clad SS as reported earlier [JPS our work]. In this investigation, the Nb-clad SS specimens in as-rolled condition were annealed at different combinations of temperature and time. Based on the results of scanning electron microscope (SEM) analysis, an annealing process map for the Nb-clad SS was obtained. The results of SEM analysis and Transmission Electron Microscope (TEM) analysis also suggest that different interfacial layers occurred based on the given annealing conditions.

  13. Effect of scale up, stacking, self humidification and use of lightweight components on the performance of a proton exchange membrane fuel cell 

    E-Print Network [OSTI]

    Tran, Doanh Thuc

    1995-01-01

    The effects of various design and operating variables on the performances of a PEM fuel cell were investigated. Performance was evaluated in terms of the polarization curves (cell potential versus current density plots). ...

  14. Fuel Cells Go Live

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015ExecutiveFluorescentDanKathy LoftusFuel CellFuel Fuelgreen h y d r o g e

  15. 2007 Fuel Cell Technologies Market Report

    SciTech Connect (OSTI)

    McMurphy, K.

    2009-07-01

    The fuel cell industry, which has experienced continued increases in sales, is an emerging clean energy industry with the potential for significant growth in the stationary, portable, and transportation sectors. Fuel cells produce electricity in a highly efficient electrochemical process from a variety of fuels with low to zero emissions. This report describes data compiled in 2008 on trends in the fuel cell industry for 2007 with some comparison to two previous years. The report begins with a discussion of worldwide trends in units shipped and financing for the fuel cell industry for 2007. It continues by focusing on the North American and U.S. markets. After providing this industry-wide overview, the report identifies trends for each of the major fuel cell applications -- stationary power, portable power, and transportation -- including data on the range of fuel cell technologies -- polymer electrolyte membrane fuel cell (PEMFC), solid oxide fuel cell (SOFC), alkaline fuel cell (AFC), molten carbonate fuel cell (MCFC), phosphoric acid fuel cell (PAFC), and direct-methanol fuel cell (DMFC) -- used for these applications.

  16. Rapidly refuelable fuel cell

    DOE Patents [OSTI]

    Joy, Richard W. (Santa Clara, CA)

    1983-01-01

    This invention is directed to a metal-air fuel cell where the consumable metal anode is movably positioned in the cell and an expandable enclosure, or bladder, is used to press the anode into contact with separating spacers between the cell electrodes. The bladder may be depressurized to allow replacement of the anode when consumed.

  17. Solid-polymer-electrolyte fuel cells

    SciTech Connect (OSTI)

    Fuller, T.F.

    1992-07-01

    A transport model for polymer electrolytes is presented, based on concentrated solution theory and irreversible thermodynamics. Thermodynamic driving forces are developed, transport properties are identified and experiments devised. Transport number of water in Nafion 117 membrane is determined using a concentration cell. It is 1.4 for a membrane equilibrated with saturated water vapor at 25{degrees}C, decreases slowly as the membrane is dehydrated, and falls sharply toward zero as the water content approaches zero. The relation between transference number, transport number, and electroosmotic drag coefficient is presented, and their relevance to water-management is discussed. A mathematical model of transport in a solid-polymer-electrolyte fuel cell is presented. A two-dimensional membrane-electrode assembly is considered. Water management, thermal management, and utilization of fuel are examined in detail. The membrane separators of these fuel cells require sorbed water to maintain conductivity; therefore it is necessary to manage the water content in membranes to ensure efficient operation. Water and thermal management are interrelated. Rate of heat removal is shown to be a critical parameter in the operation of these fuel cells. Current-voltage curves are presented for operation on air and reformed methanol. Equations for convective diffusion to a rotating disk are solved numerically for a consolute point between the bulk concentration and the surface. A singular-perturbation expansion is presented for the condition where the bulk concentration is nearly equal to the consolute-point composition. Results are compared to Levich's solution and analysis.

  18. Miniature ceramic fuel cell

    DOE Patents [OSTI]

    Lessing, Paul A. (Idaho Falls, ID); Zuppero, Anthony C. (Idaho Falls, ID)

    1997-06-24

    A miniature power source assembly capable of providing portable electricity is provided. A preferred embodiment of the power source assembly employing a fuel tank, fuel pump and control, air pump, heat management system, power chamber, power conditioning and power storage. The power chamber utilizes a ceramic fuel cell to produce the electricity. Incoming hydro carbon fuel is automatically reformed within the power chamber. Electrochemical combustion of hydrogen then produces electricity.

  19. Air Liquide - Biogas & Fuel Cells

    Broader source: Energy.gov (indexed) [DOE]

    and the environment PT Loma WWTP, Biogas to Fuel Cell Power BioFuels Energy Biogas to BioMethane to 4.5 MW Fuel Cell Power 3 FCE Fuel Cells 2 via directed...

  20. PEM fuel cell durability studies

    SciTech Connect (OSTI)

    Borup, Rodney L [Los Alamos National Laboratory; Davey, John R [Los Alamos National Laboratory; Ofstad, Axel B [Los Alamos National Laboratory; Xu, Hui [Los Alamos National Laboratory

    2008-01-01

    The durability of polymer electrolyte membrane (PEM) fuel cells is a major barrier to the commercialization for stationary and transportation power applications. For transportation applications, the durability target for fuel cell power systems is a 5,000 hour lifespan and able to function over a range of vehicle operating conditions (-40{sup o} to +40{sup o}C). However, durability is difficult to quantify and improve because of the quantity and duration of testing required, and also because the fuel cell stack contains many components, for which the degradation mechanisms, component interactions and effects of operating conditions are not fully understood. These requirements have led to the development of accelerated testing protocols for PEM fuel cells. The need for accelerated testing methodology is exemplified by the times required for standard testing to reach their required targets: automotive 5,000 hrs = {approx} 7 months; stationary systems 40,000 hrs = {approx} 4.6 years. As new materials continue to be developed, the need for relevant accelerated testing increases. In this investigation, we examine the durability of various cell components, examine the effect of transportation operating conditions (potential cycling, variable RH, shut-down/start-up, freeze/thaw) and evaluate durability by accelerated durability protocols. PEM fuel cell durability testing is performed on single cells, with tests being conducted with steady-state conditions and with dynamic conditions using power cycling to simulate a vehicle drive cycle. Component and single-cell characterization during and after testing was conducted to identify changes in material properties and related failure mechanisms. Accelerated-testing experiments were applied to further examine material degradation.

  1. Fuel cell stack arrangements

    DOE Patents [OSTI]

    Kothmann, Richard E. (Churchill Boro, PA); Somers, Edward V. (Murrysville, PA)

    1982-01-01

    Arrangements of stacks of fuel cells and ducts, for fuel cells operating with separate fuel, oxidant and coolant streams. An even number of stacks are arranged generally end-to-end in a loop. Ducts located at the juncture of consecutive stacks of the loop feed oxidant or fuel to or from the two consecutive stacks, each individual duct communicating with two stacks. A coolant fluid flows from outside the loop, into and through cooling channels of the stack, and is discharged into an enclosure duct formed within the loop by the stacks and seals at the junctures at the stacks.

  2. Reforming of fuel inside fuel cell generator

    DOE Patents [OSTI]

    Grimble, Ralph E. (Finleyville, PA)

    1988-01-01

    Disclosed is an improved method of reforming a gaseous reformable fuel within a solid oxide fuel cell generator, wherein the solid oxide fuel cell generator has a plurality of individual fuel cells in a refractory container, the fuel cells generating a partially spent fuel stream and a partially spent oxidant stream. The partially spent fuel stream is divided into two streams, spent fuel stream I and spent fuel stream II. Spent fuel stream I is burned with the partially spent oxidant stream inside the refractory container to produce an exhaust stream. The exhaust stream is divided into two streams, exhaust stream I and exhaust stream II, and exhaust stream I is vented. Exhaust stream II is mixed with spent fuel stream II to form a recycle stream. The recycle stream is mixed with the gaseous reformable fuel within the refractory container to form a fuel stream which is supplied to the fuel cells. Also disclosed is an improved apparatus which permits the reforming of a reformable gaseous fuel within such a solid oxide fuel cell generator. The apparatus comprises a mixing chamber within the refractory container, means for diverting a portion of the partially spent fuel stream to the mixing chamber, means for diverting a portion of exhaust gas to the mixing chamber where it is mixed with the portion of the partially spent fuel stream to form a recycle stream, means for injecting the reformable gaseous fuel into the recycle stream, and means for circulating the recycle stream back to the fuel cells.

  3. Hydrogen Fuel Cell Demonstration ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Brothers, Ltd., at their facility in the Port of Honolulu. The pilot hydrogen fuel cell unit will be used in place of a diesel generator currently used to provide power for...

  4. Proceedings of FuelCell2008 Sixth International Fuel Cell Science, Engineering and Technology Conference

    E-Print Network [OSTI]

    Stefanopoulou, Anna

    structure of a polymer electrolyte membrane fuel cell (PEMFC) with a dead-ended anode is observed using for differentiating between anode and cathode water flooding. The rate of accumulation of anode liquid water, and its generation of a popular category of fuel cells depends on the proton-conducting properties of their polymer

  5. Compliant fuel cell system

    DOE Patents [OSTI]

    Bourgeois, Richard Scott (Albany, NY); Gudlavalleti, Sauri (Albany, NY)

    2009-12-15

    A fuel cell assembly comprising at least one metallic component, at least one ceramic component and a structure disposed between the metallic component and the ceramic component. The structure is configured to have a lower stiffness compared to at least one of the metallic component and the ceramic component, to accommodate a difference in strain between the metallic component and the ceramic component of the fuel cell assembly.

  6. Electrocatalysts for Fuel Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HABFES Science NetworkMediatorElectrocatalysts for Fuel Cells June

  7. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Di Croce, A. Michael (Murrysville, PA); Draper, Robert (Churchill Boro, PA)

    1993-11-02

    A solid oxide fuel cell generator has a plenum containing at least two rows of spaced apart, annular, axially elongated fuel cells. An electrical conductor extending between adjacent rows of fuel cells connects the fuel cells of one row in parallel with each other and in series with the fuel cells of the adjacent row.

  8. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Di Croce, A.M.; Draper, R.

    1993-11-02

    A solid oxide fuel cell generator has a plenum containing at least two rows of spaced apart, annular, axially elongated fuel cells. An electrical conductor extending between adjacent rows of fuel cells connects the fuel cells of one row in parallel with each other and in series with the fuel cells of the adjacent row. 5 figures.

  9. Distributed parameter model simulation tool for PEM fuel cells

    E-Print Network [OSTI]

    Batlle, Carles

    for proton exchange membrane fuel cells (PEMFC) has been developed, based on a distributed parameter model and durability of PEMFC. Keywords: PEMFC, distributed parameter modeling, dynamic simulation 1. Introduction The proton exchange membrane fuel cells (PEMFC) technology has been incorporated to a wide range of portable

  10. Hydrogen Fuel Cell Vehicles

    E-Print Network [OSTI]

    Delucchi, Mark

    1992-01-01

    freezing and about a hundred freeze-thaw cycles, there is no change in fuel cellfuel cell is operating, it generates more than enough heat to prevent water and moisture from freezingfuel cell system, because in the present design the flow fields and manifolds would be damaged by the freezing-

  11. Fuel cell system

    DOE Patents [OSTI]

    Early, Jack (Perth Amboy, NJ); Kaufman, Arthur (West Orange, NJ); Stawsky, Alfred (Teaneck, NJ)

    1982-01-01

    A fuel cell system is comprised of a fuel cell module including sub-stacks of series-connected fuel cells, the sub-stacks being held together in a stacked arrangement with cold plates of a cooling means located between the sub-stacks to function as electrical terminals. The anode and cathode terminals of the sub-stacks are connected in parallel by means of the coolant manifolds which electrically connect selected cold plates. The system may comprise a plurality of the fuel cell modules connected in series. The sub-stacks are designed to provide a voltage output equivalent to the desired voltage demand of a low voltage, high current DC load such as an electrolytic cell to be driven by the fuel cell system. This arrangement in conjunction with switching means can be used to drive a DC electrical load with a total voltage output selected to match that of the load being driven. This arrangement eliminates the need for expensive voltage regulation equipment.

  12. Method of improving fuel cell performance by removing at least one metal oxide contaminant from a fuel cell electrode

    DOE Patents [OSTI]

    Kim, Yu Seung (Los Alamos, NM); Choi, Jong-Ho (Los Alamos, NM); Zelenay, Piotr (Los Alamos, NM)

    2009-08-18

    A method of removing contaminants from a fuel cell catalyst electrode. The method includes providing a getter electrode and a fuel cell catalyst electrode having at least one contaminant to a bath and applying a voltage sufficient to drive the contaminant from the fuel cell catalyst electrode to the getter electrode. Methods of removing contaminants from a membrane electrode assembly of a fuel cell and of improving performance of a fuel cell are also provided.

  13. Proceedings of the ASME Fuel Cell Division 2000: The 2000 ASME International Mechanical Engineering Congress & Exposition

    E-Print Network [OSTI]

    Wang, Chao-Yang

    Proceedings of the ASME Fuel Cell Division ­ 2000: The 2000 ASME International Mechanical ANALYSIS OF TRANSPORT AND REACTION IN PROTON EXCHANGE MEMBRANE FUEL CELLS Sukkee Um and C.Y. Wang exchange membrane (PEM) fuel cells with a Nafion 117 membrane and an interdigitated flow field

  14. Power from the Fuel Cell

    E-Print Network [OSTI]

    Lipman, Timothy E.

    2000-01-01

    Power for Buildings Using Fuel-Cell Cars,” Proceedings ofwell as to drive down fuel-cell system costs through productPower from the Fuel Cell BY TIMOTHY E. LIPMAN A U T O M O B

  15. DOE Hydrogen & Fuel Cell Overview

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    t t 1 | Fuel Cell Technologies Program eere.energy.gov Fuel Cell Technologies Program DOE Hydrogen & Fuel Cell Overview Dr. Sunita Satyapal Program Manager U S D f E Overview U.S....

  16. Hydrogen and Fuel Cell Activities

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Activities Mr. Pete Devlin U.S. Department of Energy Fuel Cell Technologies Program Market Transformation Manager Stationary Fuel Cell Applications First National Bank of Omaha...

  17. Webinar: Fuel Cells at NASCAR

    Broader source: Energy.gov [DOE]

    Video recording and text version of the Fuel Cell Technologies Office webinar "Fuel Cells at NASCAR," originally presented on April 17, 2014.

  18. Solid polymer MEMS-based fuel cells

    DOE Patents [OSTI]

    Jankowski, Alan F. (Livermore, CA); Morse, Jeffrey D. (Pleasant Hill, CA)

    2008-04-22

    A micro-electro-mechanical systems (MEMS) based thin-film fuel cells for electrical power applications. The MEMS-based fuel cell may be of a solid oxide type (SOFC), a solid polymer type (SPFC), or a proton exchange membrane type (PEMFC), and each fuel cell basically consists of an anode and a cathode separated by an electrolyte layer. The electrolyte layer can consist of either a solid oxide or solid polymer material, or proton exchange membrane electrolyte materials may be used. Additionally catalyst layers can also separate the electrodes (cathode and anode) from the electrolyte. Gas manifolds are utilized to transport the fuel and oxidant to each cell and provide a path for exhaust gases. The electrical current generated from each cell is drawn away with an interconnect and support structure integrated with the gas manifold. The fuel cells utilize integrated resistive heaters for efficient heating of the materials. By combining MEMS technology with thin-film deposition technology, thin-film fuel cells having microflow channels and full-integrated circuitry can be produced that will lower the operating temperature an will yield an order of magnitude greater power density than the currently known fuel cells.

  19. Solid oxide MEMS-based fuel cells

    DOE Patents [OSTI]

    Jankowksi, Alan F.; Morse, Jeffrey D.

    2007-03-13

    A micro-electro-mechanical systems (MEMS) based thin-film fuel cells for electrical power applications. The MEMS-based fuel cell may be of a solid oxide type (SOFC), a solid polymer type (SPFC), or a proton exchange membrane type (PEMFC), and each fuel cell basically consists of an anode and a cathode separated by an electrolyte layer. The electrolyte layer can consist of either a solid oxide or solid polymer material, or proton exchange membrane electrolyte materials may be used. Additionally catalyst layers can also separate the electrodes (cathode and anode) from the electrolyte. Gas manifolds are utilized to transport the fuel and oxidant to each cell and provide a path for exhaust gases. The electrical current generated from each cell is drawn away with an interconnect and support structure integrated with the gas manifold. The fuel cells utilize integrated resistive heaters for efficient heating of the materials. By combining MEMS technology with thin-film deposition technology, thin-film fuel cells having microflow channels and full-integrated circuitry can be produced that will lower the operating temperature an will yield an order of magnitude greater power density than the currently known fuel cells.

  20. Optical rheology for live cell membranes

    E-Print Network [OSTI]

    Park, YongKeun, S.M. Massachusetts Institute of Technology

    2007-01-01

    We present a novel optical methodology including both instrumentation and theory aimed at retrieving the full viscoelastic information of cell membrane material properties. Red blood cells (RBC) are chosen for this study ...

  1. Commercializing Light-Duty Plug-In/Plug-Out Hydrogen-Fuel-Cell Vehicles:“Mobile Electricity” Technologies, Early California Household Markets, and Innovation Management

    E-Print Network [OSTI]

    Williams, Brett D

    2007-01-01

    plots two different fuel-cell applications with dramaticallycommercializing fuel cells in various applications, startingMembrane Fuel Cell System for Transportation Applications:

  2. Commercializing Light-Duty Plug-In/Plug-Out Hydrogen-Fuel-Cell Vehicles: "Mobile Electricity" Technologies, Early California Household Markets, and Innovation Management

    E-Print Network [OSTI]

    Williams, Brett D

    2010-01-01

    plots two different fuel-cell applications with dramaticallycommercializing fuel cells in various applications, startingMembrane Fuel Cell System for Transportation Applications:

  3. In situ PEM fuel cell water measurements

    SciTech Connect (OSTI)

    Borup, Rodney L [Los Alamos National Laboratory; Mukundan, Rangachary [Los Alamos National Laboratory; Davey, John R [Los Alamos National Laboratory; Spendelow, Jacob S [Los Alamos National Laboratory; Hussey, Daniel S [NIST; Jacobson, David L [NIST; Arif, Muhammad [NIST

    2009-01-01

    Efficient PEM (Polymer Electrolyte Membrane) fuel cell performance requires effective water management. To achieve a deeper understanding of water transport and performance issues associated with water management, we have conducted in situ water examinations to help understand the effects of components and operations. High Frequency Resistance (HFR), AC Impedance and Neutron imaging were used to measure water content in operating fuel cells, with various conditions, including current density, relative humidity, inlet flows, flow orientation and variable Gas Diffusion Layer (GDL) properties. High resolution neutron radiography was used to image fuel cells during a variety of conditions. The effect of specific operating conditions, including flow direction (co-flow or counter-flow) was examined. Counter-flow operation was found to result in higher water content than co-flow operation, which correlates to lower membrane resistivity. A variety of cells were used to quantify the membrane water in situ during exposure to saturated gases, during fuel cell operation, and during hydrogen pump operation. The quantitative results show lower membrane water content than previous results suggested.

  4. Ice-Crystallization Kinetics during Fuel-Cell Cold-Start

    E-Print Network [OSTI]

    Dursch, Thomas James

    2014-01-01

    A.Z. Weber, Water uptake of fuel-cell catalyst layers, J.Layer of a Proton- Exchange-Membrane Fuel Cell 2.1.Diffusion Layer of a Fuel Cell from Differential Scanning

  5. Fuel cell system combustor

    DOE Patents [OSTI]

    Pettit, William Henry (Rochester, NY)

    2001-01-01

    A fuel cell system including a fuel reformer heated by a catalytic combustor fired by anode and cathode effluents. The combustor includes a turbulator section at its input end for intimately mixing the anode and cathode effluents before they contact the combustors primary catalyst bed. The turbulator comprises at least one porous bed of mixing media that provides a tortuous path therethrough for creating turbulent flow and intimate mixing of the anode and cathode effluents therein.

  6. Summer School Diagnostics and Prognostics of Fuel Cell Systems

    E-Print Network [OSTI]

    Jeanjean, Louis

    ANR PROPICE Summer School Diagnostics and Prognostics of Fuel Cell Systems 01-04 July 2014, FCLAB, Belfort, France https://propice.ens2m.fr/ecole-diag-pron-PAC.html Motivations and objectives Fuel Cell, particularly by increasing their limited lifespan. Indeed, Proton Exchange Membrane Fuel Cell systems (PEMFC

  7. Fuel cell stack with passive air supply

    DOE Patents [OSTI]

    Ren, Xiaoming; Gottesfeld, Shimshon

    2006-01-17

    A fuel cell stack has a plurality of polymer electrolyte fuel cells (PEFCs) where each PEFC includes a rectangular membrane electrode assembly (MEA) having a fuel flow field along a first axis and an air flow field along a second axis perpendicular to the first axis, where the fuel flow field is long relative to the air flow field. A cathode air flow field in each PEFC has air flow channels for air flow parallel to the second axis and that directly open to atmospheric air for air diffusion within the channels into contact with the MEA.

  8. Fuel cell anode configuration for CO tolerance

    DOE Patents [OSTI]

    Uribe, Francisco A.; Zawodzinski, Thomas A.

    2004-11-16

    A polymer electrolyte fuel cell (PEFC) is designed to operate on a reformate fuel stream containing oxygen and diluted hydrogen fuel with CO impurities. A polymer electrolyte membrane has an electrocatalytic surface formed from an electrocatalyst mixed with the polymer and bonded on an anode side of the membrane. An anode backing is formed of a porous electrically conductive material and has a first surface abutting the electrocatalytic surface and a second surface facing away from the membrane. The second surface has an oxidation catalyst layer effective to catalyze the oxidation of CO by oxygen present in the fuel stream where at least the layer of oxidation catalyst is formed of a non-precious metal oxidation catalyst selected from the group consisting of Cu, Fe, Co, Tb, W, Mo, Sn, and oxides thereof, and other metals having at least two low oxidation states.

  9. Fuel cell cooler-humidifier plate

    SciTech Connect (OSTI)

    Vitale, N.G.; Jones, D.O.

    2000-05-23

    A cooler-humidifier plate for use in a proton exchange membrane (PEM) fuel cell stack assembly is provided. The cooler-humidifier plate combines functions of cooling and humidification within the fuel cell stack assembly, thereby providing a more compact structure, simpler manifolding, and reduced reject heat from the fuel cell. Coolant on the cooler side of the plate removes heat generated within the fuel cell assembly. Heat is also removed by the humidifier side of the plate for use in evaporating the humidification water. On the humidifier side of the plate, evaporating water humidifies reactant gas flowing over a moistened wick. After exiting the humidifier side of the plate, humidified reactant gas provides needed moisture to the proton exchange membranes used in the fuel cell stack assembly. The invention also provides a fuel cell plate that maximizes structural support within the fuel cell by ensuring that the ribs that form the boundaries of channels on one side of the plate have ends at locations that substantially correspond to the locations of ribs on the opposite side of the plate.

  10. Fuel cell cooler-humidifier plate

    DOE Patents [OSTI]

    Vitale, Nicholas G. (Albany, NY); Jones, Daniel O. (Glenville, NY)

    2000-01-01

    A cooler-humidifier plate for use in a proton exchange membrane (PEM) fuel cell stack assembly is provided. The cooler-humidifier plate combines functions of cooling and humidification within the fuel cell stack assembly, thereby providing a more compact structure, simpler manifolding, and reduced reject heat from the fuel cell. Coolant on the cooler side of the plate removes heat generated within the fuel cell assembly. Heat is also removed by the humidifier side of the plate for use in evaporating the humidification water. On the humidifier side of the plate, evaporating water humidifies reactant gas flowing over a moistened wick. After exiting the humidifier side of the plate, humidified reactant gas provides needed moisture to the proton exchange membranes used in the fuel cell stack assembly. The invention also provides a fuel cell plate that maximizes structural support within the fuel cell by ensuring that the ribs that form the boundaries of channels on one side of the plate have ends at locations that substantially correspond to the locations of ribs on the opposite side of the plate.

  11. Electrochemistry of Fuel Cells and Batteries (ME/MS 545) Course Description: Fundamental Electrochemistry of fuel cells, batteries, sensors,

    E-Print Network [OSTI]

    Electrochemistry of Fuel Cells and Batteries (ME/MS 545) Course Description: Fundamental Electrochemistry of fuel cells, batteries, sensors, membrane separation and electrolytic methods are discussed. Recommended/reference text: Fuel Cell Handbook 7, DOE-NETL Production and list of related publications Course

  12. Comparative analysis of selected fuel cell vehicles

    SciTech Connect (OSTI)

    NONE

    1993-05-07

    Vehicles powered by fuel cells operate more efficiently, more quietly, and more cleanly than internal combustion engines (ICEs). Furthermore, methanol-fueled fuel cell vehicles (FCVs) can utilize major elements of the existing fueling infrastructure of present-day liquid-fueled ICE vehicles (ICEVs). DOE has maintained an active program to stimulate the development and demonstration o fuel cell technologies in conjunction with rechargeable batteries in road vehicles. The purpose of this study is to identify and assess the availability of data on FCVs, and to develop a vehicle subsystem structure that can be used to compare both FCVs and ICEV, from a number of perspectives--environmental impacts, energy utilization, materials usage, and life cycle costs. This report focuses on methanol-fueled FCVs fueled by gasoline, methanol, and diesel fuel that are likely to be demonstratable by the year 2000. The comparative analysis presented covers four vehicles--two passenger vehicles and two urban transit buses. The passenger vehicles include an ICEV using either gasoline or methanol and an FCV using methanol. The FCV uses a Proton Exchange Membrane (PEM) fuel cell, an on-board methanol reformer, mid-term batteries, and an AC motor. The transit bus ICEV was evaluated for both diesel and methanol fuels. The transit bus FCV runs on methanol and uses a Phosphoric Acid Fuel Cell (PAFC) fuel cell, near-term batteries, a DC motor, and an on-board methanol reformer. 75 refs.

  13. Compact fuel cell

    DOE Patents [OSTI]

    Jacobson, Craig (Moraga, CA); DeJonghe, Lutgard C. (Lafayette, CA); Lu, Chun (Richland, WA)

    2010-10-19

    A novel electrochemical cell which may be a solid oxide fuel cell (SOFC) is disclosed where the cathodes (144, 140) may be exposed to the air and open to the ambient atmosphere without further housing. Current collector (145) extends through a first cathode on one side of a unit and over the unit through the cathode on the other side of the unit and is in electrical contact via lead (146) with housing unit (122 and 124). Electrical insulator (170) prevents electrical contact between two units. Fuel inlet manifold (134) allows fuel to communicate with internal space (138) between the anodes (154 and 156). Electrically insulating members (164 and 166) prevent the current collector from being in electrical contact with the anode.

  14. California Fuel Cell Partnership: Alternative Fuels Research...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    research. cafcpinitiativescall.pdf More Documents & Publications The Department of Energy Hydrogen and Fuel Cells Program Plan Vehicle Technologies Office Merit Review 2015:...

  15. Air breathing direct methanol fuel cell

    DOE Patents [OSTI]

    Ren, Xiaoming (Los Alamos, NM)

    2002-01-01

    An air breathing direct methanol fuel cell is provided with a membrane electrode assembly, a conductive anode assembly that is permeable to air and directly open to atmospheric air, and a conductive cathode assembly that is permeable to methanol and directly contacting a liquid methanol source.

  16. Breakthrough Vehicle Development - Fuel Cells

    Fuel Cell Technologies Publication and Product Library (EERE)

    Document describing research and development program for fuel cell power systems for transportation applications.

  17. National Fuel Cell Research Center

    E-Print Network [OSTI]

    Mease, Kenneth D.

    the optimal conditions to operate a molten carbonate fuel cell, can be used to garner fundamental insightNational Fuel Cell Research Center www.nfcrc.uci.edu MOLTEN CARBONATE FUEL CELLS STEADY STATE MODELING OF MOLTEN CARBONATE FUEL CELLS FOR SYSTEM PERFORMANCE ANALYSES OVERVIEW Development of steady

  18. Hydrogen & Fuel Cells -Program Overview -

    E-Print Network [OSTI]

    Analysis Fuel Cells Solid oxide fuel cell (kW-scale) R&D led to 75% weight reduction and >80% volume,000 35,000 2008 2009 2010 2011 2012P (SystemsShipped) Fuel Cell Systems Shipped by Application, World Research Market Growth Fuel cell markets continue to grow 48% increase in global MWs shipped 62% increase

  19. Seventh Edition Fuel Cell Handbook

    SciTech Connect (OSTI)

    NETL

    2004-11-01

    Provides an overview of fuel cell technology and research projects. Discusses the basic workings of fuel cells and their system components, main fuel cell types, their characteristics, and their development status, as well as a discussion of potential fuel cell applications.

  20. Enhanced methanol utilization in direct methanol fuel cell

    DOE Patents [OSTI]

    Ren, Xiaoming (Los Alamos, NM); Gottesfeld, Shimshon (Los Alamos, NM)

    2001-10-02

    The fuel utilization of a direct methanol fuel cell is enhanced for improved cell efficiency. Distribution plates at the anode and cathode of the fuel cell are configured to distribute reactants vertically and laterally uniformly over a catalyzed membrane surface of the fuel cell. A conductive sheet between the anode distribution plate and the anodic membrane surface forms a mass transport barrier to the methanol fuel that is large relative to a mass transport barrier for a gaseous hydrogen fuel cell. In a preferred embodiment, the distribution plate is a perforated corrugated sheet. The mass transport barrier may be conveniently increased by increasing the thickness of an anode conductive sheet adjacent the membrane surface of the fuel cell.

  1. Fuel dissipater for pressurized fuel cell generators

    DOE Patents [OSTI]

    Basel, Richard A.; King, John E.

    2003-11-04

    An apparatus and method are disclosed for eliminating the chemical energy of fuel remaining in a pressurized fuel cell generator (10) when the electrical power output of the fuel cell generator is terminated during transient operation, such as a shutdown; where, two electrically resistive elements (two of 28, 53, 54, 55) at least one of which is connected in parallel, in association with contactors (26, 57, 58, 59), a multi-point settable sensor relay (23) and a circuit breaker (24), are automatically connected across the fuel cell generator terminals (21, 22) at two or more contact points, in order to draw current, thereby depleting the fuel inventory in the generator.

  2. Fuel cell generator energy dissipator

    DOE Patents [OSTI]

    Veyo, Stephen Emery (Murrysville, PA); Dederer, Jeffrey Todd (Valencia, PA); Gordon, John Thomas (Ambridge, PA); Shockling, Larry Anthony (Pittsburgh, PA)

    2000-01-01

    An apparatus and method are disclosed for eliminating the chemical energy of fuel remaining in a fuel cell generator when the electrical power output of the fuel cell generator is terminated. During a generator shut down condition, electrically resistive elements are automatically connected across the fuel cell generator terminals in order to draw current, thereby depleting the fuel

  3. Fuel Cell Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Cell Systems Fuel Cell Systems The design of fuel cell systems is complex, and can vary significantly depending upon fuel cell type and application. However, several basic...

  4. Fuel Cells Fact Sheet | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fact Sheet Fact sheet produced by the Fuel Cell Technologies Office describing hydrogen fuel cell technology. Fuel Cells More Documents & Publications Hydrogen and Fuel Cell...

  5. 2009 Fuel Cell Market Report

    SciTech Connect (OSTI)

    Vincent, Bill; Gangi, Jennifer; Curtin, Sandra; Delmont, Elizabeth

    2010-11-01

    Fuel cells are electrochemical devices that combine hydrogen and oxygen to produce electricity, water, and heat. Unlike batteries, fuel cells continuously generate electricity, as long as a source of fuel is supplied. Moreover, fuel cells do not burn fuel, making the process quiet, pollution-free and two to three times more efficient than combustion. Fuel cell systems can be a truly zero-emission source of electricity, if the hydrogen is produced from non-polluting sources. Global concerns about climate change, energy security, and air pollution are driving demand for fuel cell technology. More than 630 companies and laboratories in the United States are investing $1 billion a year in fuel cells or fuel cell component technologies. This report provides an overview of trends in the fuel cell industry and markets, including product shipments, market development, and corporate performance. It also provides snapshots of select fuel cell companies, including general.

  6. Method of making MEA for PEM/SPE fuel cell

    DOE Patents [OSTI]

    Hulett, Jay S. (West Henrietta, NY)

    2000-01-01

    A method of making a membrane-electrode-assembly (MEA) for a PEM/SPE fuel cell comprising applying a slurry of electrode-forming material directly onto a membrane-electrolyte film. The slurry comprises a liquid vehicle carrying catalyst particles and a binder for the catalyst particles. The membrane-electrolyte is preswollen by contact with the vehicle before the electrode-forming slurry is applied to the membrane-electrolyte. The swollen membrane-electrolyte is constrained against shrinking in the "x" and "y" directions during drying. Following assembly of the fuel cell, the MEA is rehydrated inside the fuel cell such that it swells in the "z" direction for enhanced electrical contact with contiguous electrically conductive components of the fuel cell.

  7. Solid-polymer-electrolyte fuel cells

    SciTech Connect (OSTI)

    Fuller, T.F.

    1992-07-01

    A transport model for polymer electrolytes is presented, based on concentrated solution theory and irreversible thermodynamics. Thermodynamic driving forces are developed, transport properties are identified and experiments devised. Transport number of water in Nafion 117 membrane is determined using a concentration cell. It is 1.4 for a membrane equilibrated with saturated water vapor at 25{degrees}C, decreases slowly as the membrane is dehydrated, and falls sharply toward zero as the water content approaches zero. The relation between transference number, transport number, and electroosmotic drag coefficient is presented, and their relevance to water-management is discussed. A mathematical model of transport in a solid-polymer-electrolyte fuel cell is presented. A two-dimensional membrane-electrode assembly is considered. Water management, thermal management, and utilization of fuel are examined in detail. The membrane separators of these fuel cells require sorbed water to maintain conductivity; therefore it is necessary to manage the water content in membranes to ensure efficient operation. Water and thermal management are interrelated. Rate of heat removal is shown to be a critical parameter in the operation of these fuel cells. Current-voltage curves are presented for operation on air and reformed methanol. Equations for convective diffusion to a rotating disk are solved numerically for a consolute point between the bulk concentration and the surface. A singular-perturbation expansion is presented for the condition where the bulk concentration is nearly equal to the consolute-point composition. Results are compared to Levich`s solution and analysis.

  8. Fuel cell CO sensor

    DOE Patents [OSTI]

    Grot, Stephen Andreas (Rochester, NY); Meltser, Mark Alexander (Pittsford, NY); Gutowski, Stanley (Pittsford, NY); Neutzler, Jay Kevin (Rochester, NY); Borup, Rodney Lynn (East Rochester, NY); Weisbrod, Kirk (Los Alamos, NM)

    1999-12-14

    The CO concentration in the H.sub.2 feed stream to a PEM fuel cell stack is monitored by measuring current and/or voltage behavior patterns from a PEM-probe communicating with the reformate feed stream. Pattern recognition software may be used to compare the current and voltage patterns from the PEM-probe to current and voltage telltale outputs determined from a reference cell similar to the PEM-probe and operated under controlled conditions over a wide range of CO concentrations in the H.sub.2 fuel stream. A CO sensor includes the PEM-probe, an electrical discharge circuit for discharging the PEM-probe to monitor the CO concentration, and an electrical purging circuit to intermittently raise the anode potential of the PEM-probe's anode to at least about 0.8 V (RHE) to electrochemically oxidize any CO adsorbed on the probe's anode catalyst.

  9. Fuel cell current collector

    DOE Patents [OSTI]

    Katz, Murray (Newington, CT); Bonk, Stanley P. (West Willington, CT); Maricle, Donald L. (Glastonbury, CT); Abrams, Martin (Glastonbury, CT)

    1991-01-01

    A fuel cell has a current collector plate (22) located between an electrode (20) and a separate plate (25). The collector plate has a plurality of arches (26, 28) deformed from a single flat plate in a checkerboard pattern. The arches are of sufficient height (30) to provide sufficient reactant flow area. Each arch is formed with sufficient stiffness to accept compressive load and sufficient resiliently to distribute the load and maintain electrical contact.

  10. Carbonate fuel cell matrix

    DOE Patents [OSTI]

    Farooque, M.; Yuh, C.Y.

    1996-12-03

    A carbonate fuel cell matrix is described comprising support particles and crack attenuator particles which are made platelet in shape to increase the resistance of the matrix to through cracking. Also disclosed is a matrix having porous crack attenuator particles and a matrix whose crack attenuator particles have a thermal coefficient of expansion which is significantly different from that of the support particles, and a method of making platelet-shaped crack attenuator particles. 8 figs.

  11. Air breathing direct methanol fuel cell

    DOE Patents [OSTI]

    Ren, Xiaoming (Los Alamos, NM); Gottesfeld, Shimshon (Los Alamos, NM)

    2002-01-01

    An air breathing direct methanol fuel cell is provided with a membrane electrode assembly, a conductive anode assembly that is permeable to air and directly open to atmospheric air, and a conductive cathode assembly that is permeable to methanol and directly contacting a liquid methanol source. Water loss from the cell is minimized by making the conductive cathode assembly hydrophobic and the conductive anode assembly hydrophilic.

  12. Air-Breathing Laminar Flow-Based Direct Methanol Fuel Cell with Alkaline Electrolyte

    E-Print Network [OSTI]

    Kenis, Paul J. A.

    methanol fuel cells DMFCs and polymer electrolyte membrane-based fuel cells PEMFCs, operated with hydrogen/oxygen .1-3 In most fuel cells, a polymer electrolyte membrane such as Nafion allows protons to dif- fuse to fuel cross- over, cathode flooding and anode dry-out water management due to osmotic drag of water

  13. Developmental Cell MPK-1 ERK Controls Membrane

    E-Print Network [OSTI]

    Developmental Cell Article MPK-1 ERK Controls Membrane Organization in C. elegans Oogenesis via/ERK in the proximal germ- line to control plasma membrane biogenesis and organization during oogenesis and oocyte production is dramatically downregulated. The RTK-RAS-ERK pathway relays physiological and devel

  14. California Fuel Cell Partnership: Alternative Fuels Research

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based Fuels| Department ofBusinessCEA90:2:09California EnergyFuel Cell

  15. Recent Progress in Nanostructured Electrocatalysts for PEM Fuel Cells

    SciTech Connect (OSTI)

    Zhang, Sheng; Shao, Yuyan; Yin, Geping; Lin, Yuehe

    2013-03-30

    Polymer electrolyte membrane (PEM) fuel cells are attracting much attention as promising clean power sources and an alternative to conventional internal combustion engines, secondary batteries, and other power sources. Much effort from government laboratories, industry, and academia has been devoted to developing PEM fuel cells, and great advances have been achieved. Although prototype cars powered by fuel cells have been delivered, successful commercialization requires fuel cell electrocatalysts, which are crucial components at the heart of fuel cells, meet exacting performance targets. In this review, we present a brief overview of the recent progress in fuel cell electrocatalysts, which involves catalyst supports, Pt and Pt-based electrocatalysts, and non-Pt electrocatalysts.

  16. Fuel processor for fuel cell power system

    DOE Patents [OSTI]

    Vanderborgh, Nicholas E. (Los Alamos, NM); Springer, Thomas E. (Los Alamos, NM); Huff, James R. (Los Alamos, NM)

    1987-01-01

    A catalytic organic fuel processing apparatus, which can be used in a fuel cell power system, contains within a housing a catalyst chamber, a variable speed fan, and a combustion chamber. Vaporized organic fuel is circulated by the fan past the combustion chamber with which it is in indirect heat exchange relationship. The heated vaporized organic fuel enters a catalyst bed where it is converted into a desired product such as hydrogen needed to power the fuel cell. During periods of high demand, air is injected upstream of the combustion chamber and organic fuel injection means to burn with some of the organic fuel on the outside of the combustion chamber, and thus be in direct heat exchange relation with the organic fuel going into the catalyst bed.

  17. Advanced Membrane Systems: Recovering Wasteful and Hazardous Fuel Vapors at the Gasoline Tank

    Office of Energy Efficiency and Renewable Energy (EERE)

    Case study covering Compact Membrane Systems, Inc. and its membrane vapor processor that recovers fuel vapors from gasoline refueling.

  18. Light Duty Fuel Cell Electric Vehicle Hydrogen Fueling Protocol...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Light Duty Fuel Cell Electric Vehicle Hydrogen Fueling Protocol Light Duty Fuel Cell Electric Vehicle Hydrogen Fueling Protocol Download the webinar slides from the U.S. Department...

  19. Texas Hydrogen Highway - Fuel Cell Hybrid Bus and Fueling Infrastructu...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Highway - Fuel Cell Hybrid Bus and Fueling Infrastructure Technology Showcase Texas Hydrogen Highway - Fuel Cell Hybrid Bus and Fueling Infrastructure Technology Showcase...

  20. Carbonate fuel cell anodes

    DOE Patents [OSTI]

    Donado, Rafael A. (Chicago, IL); Hrdina, Kenneth E. (Glenview, IL); Remick, Robert J. (Bolingbrook, IL)

    1993-01-01

    A molten alkali metal carbonates fuel cell porous anode of lithium ferrite and a metal or metal alloy of nickel, cobalt, nickel/iron, cobalt/iron, nickel/iron/aluminum, cobalt/iron/aluminum and mixtures thereof wherein the total iron content including ferrite and iron of the composite is about 25 to about 80 percent, based upon the total anode, provided aluminum when present is less than about 5 weight percent of the anode. A process for production of the lithium ferrite containing anode by slipcasting.

  1. Carbonate fuel cell anodes

    DOE Patents [OSTI]

    Donado, R.A.; Hrdina, K.E.; Remick, R.J.

    1993-04-27

    A molten alkali metal carbonates fuel cell porous anode of lithium ferrite and a metal or metal alloy of nickel, cobalt, nickel/iron, cobalt/iron, nickel/iron/aluminum, cobalt/iron/aluminum and mixtures thereof wherein the total iron content including ferrite and iron of the composite is about 25 to about 80 percent, based upon the total anode, provided aluminum when present is less than about 5 weight percent of the anode. A process is described for production of the lithium ferrite containing anode by slipcasting.

  2. 2009 Fuel Cell Market Report

    Fuel Cell Technologies Publication and Product Library (EERE)

    Fuel cells are electrochemical devices that combine hydrogen and oxygen to produce electricity, water, and heat. Unlike batteries, fuel cells continuously generate electricity, as long as a source of

  3. Fuel Cell Technical Team Roadmap

    SciTech Connect (OSTI)

    2013-06-01

    The Fuel Cell Technical Team promotes the development of a fuel cell power system for an automotive powertrain that meets the U.S. DRIVE Partnership (United States Driving Research and Innovation for Vehicle efficiency and Energy sustainability) goals.

  4. Direct methanol fuel cell and system

    DOE Patents [OSTI]

    Wilson, Mahlon S. (Los Alamos, NM)

    2004-10-26

    A fuel cell having an anode and a cathode and a polymer electrolyte membrane located between anode and cathode gas diffusion backings uses a methanol vapor fuel supply. A permeable polymer electrolyte membrane having a permeability effective to sustain a carbon dioxide flux equivalent to at least 10 mA/cm.sup.2 provides for removal of carbon dioxide produced at the anode by reaction of methanol with water. Another aspect of the present invention includes a superabsorpent polymer material placed in proximity to the anode gas diffusion backing to hold liquid methanol or liquid methanol solution without wetting the anode gas diffusion backing so that methanol vapor from the liquid methanol or liquid methanol-water solution is supplied to the membrane.

  5. EFFECT OF FUEL IMPURITIES ON FUEL CELL PERFORMANCE AND DURABILITY

    SciTech Connect (OSTI)

    Colon-Mercado, H.

    2010-09-28

    A fuel cell is an electrochemical energy conversion device that produces electricity during the combination of hydrogen and oxygen to produce water. Proton exchange membranes fuel cells are favored for portable applications as well as stationary ones due to their high power density, low operating temperature, and low corrosion of components. In real life operation, the use of pure fuel and oxidant gases results in an impractical system. A more realistic and cost efficient approach is the use of air as an oxidant gas and hydrogen from hydrogen carriers (i.e., ammonia, hydrocarbons, hydrides). However, trace impurities arising from different hydrogen sources and production increases the degradation of the fuel cell. These impurities include carbon monoxide, ammonia, sulfur, hydrocarbons, and halogen compounds. The International Organization for Standardization (ISO) has set maximum limits for trace impurities in the hydrogen stream; however fuel cell data is needed to validate the assumption that at those levels the impurities will cause no degradation. This report summarizes the effect of selected contaminants tested at SRNL at ISO levels. Runs at ISO proposed concentration levels show that model hydrocarbon compound such as tetrahydrofuran can cause serious degradation. However, the degradation is only temporary as when the impurity is removed from the hydrogen stream the performance completely recovers. Other molecules at the ISO concentration levels such as ammonia don't show effects on the fuel cell performance. On the other hand carbon monoxide and perchloroethylene shows major degradation and the system can only be recovered by following recovery procedures.

  6. National Fuel Cell Research Center

    E-Print Network [OSTI]

    Mease, Kenneth D.

    National Fuel Cell Research Center www.nfcrc.uci.edu SOFC AND PEMFC COMPARISON Efficiency ­ Higher FOR OPTIMIZATION · Fuel Cell · Compressor · Combustor · Turbine · Storage Tank · Heat Exchanger·Battery · Motor of the system. · Operating characteristics of fuel cells at pressures less than 1 atm are largely unknown

  7. Microfluidic Fuel Cells Erik Kjeang

    E-Print Network [OSTI]

    Victoria, University of

    Microfluidic Fuel Cells by Erik Kjeang M.Sc., Umeå University, 2004 A Dissertation Submitted Supervisory Committee Microfluidic Fuel Cells by Erik Kjeang M.Sc., Umeå University, 2004 Supervisory University External Examiner Microfluidic fuel cell architectures are presented in this thesis. This work

  8. Fuel Cell Handbook, Fifth Edition

    SciTech Connect (OSTI)

    Energy and Environmental Solutions

    2000-10-31

    Progress continues in fuel cell technology since the previous edition of the Fuel Cell Handbook was published in November 1998. Uppermost, polymer electrolyte fuel cells, molten carbonate fuel cells, and solid oxide fuel cells have been demonstrated at commercial size in power plants. The previously demonstrated phosphoric acid fuel cells have entered the marketplace with more than 220 power plants delivered. Highlighting this commercial entry, the phosphoric acid power plant fleet has demonstrated 95+% availability and several units have passed 40,000 hours of operation. One unit has operated over 49,000 hours. Early expectations of very low emissions and relatively high efficiencies have been met in power plants with each type of fuel cell. Fuel flexibility has been demonstrated using natural gas, propane, landfill gas, anaerobic digester gas, military logistic fuels, and coal gas, greatly expanding market opportunities. Transportation markets worldwide have shown remarkable interest in fuel cells; nearly every major vehicle manufacturer in the U.S., Europe, and the Far East is supporting development. This Handbook provides a foundation in fuel cells for persons wanting a better understanding of the technology, its benefits, and the systems issues that influence its application. Trends in technology are discussed, including next-generation concepts that promise ultrahigh efficiency and low cost, while providing exceptionally clean power plant systems. Section 1 summarizes fuel cell progress since the last edition and includes existing power plant nameplate data. Section 2 addresses the thermodynamics of fuel cells to provide an understanding of fuel cell operation at two levels (basic and advanced). Sections 3 through 8 describe the six major fuel cell types and their performance based on cell operating conditions. Alkaline and intermediate solid state fuel cells were added to this edition of the Handbook. New information indicates that manufacturers have stayed with proven cell designs, focusing instead on advancing the system surrounding the fuel cell to lower life cycle costs. Section 9, Fuel Cell Systems, has been significantly revised to characterize near-term and next-generation fuel cell power plant systems at a conceptual level of detail. Section 10 provides examples of practical fuel cell system calculations. A list of fuel cell URLs is included in the Appendix. A new index assists the reader in locating specific information quickly.

  9. Fuel cell with interdigitated porous flow-field

    DOE Patents [OSTI]

    Wilson, Mahlon S. (Los Alamos, NM)

    1997-01-01

    A polymer electrolyte membrane (PEM) fuel cell is formed with an improved system for distributing gaseous reactants to the membrane surface. A PEM fuel cell has an ionic transport membrane with opposed catalytic surfaces formed thereon and separates gaseous reactants that undergo reactions at the catalytic surfaces of the membrane. The fuel cell may also include a thin gas diffusion layer having first and second sides with a first side contacting at least one of the catalytic surfaces. A macroporous flow-field with interdigitated inlet and outlet reactant channels contacts the second side of the thin gas diffusion layer for distributing one of the gaseous reactants over the thin gas diffusion layer for transport to an adjacent one of the catalytic surfaces of the membrane. The porous flow field may be formed from a hydrophilic material and provides uniform support across the backside of the electrode assembly to facilitate the use of thin backing layers.

  10. Fuel cell with interdigitated porous flow-field

    DOE Patents [OSTI]

    Wilson, M.S.

    1997-06-24

    A polymer electrolyte membrane (PEM) fuel cell is formed with an improved system for distributing gaseous reactants to the membrane surface. A PEM fuel cell has an ionic transport membrane with opposed catalytic surfaces formed thereon and separates gaseous reactants that undergo reactions at the catalytic surfaces of the membrane. The fuel cell may also include a thin gas diffusion layer having first and second sides with a first side contacting at least one of the catalytic surfaces. A macroporous flow-field with interdigitated inlet and outlet reactant channels contacts the second side of the thin gas diffusion layer for distributing one of the gaseous reactants over the thin gas diffusion layer for transport to an adjacent one of the catalytic surfaces of the membrane. The porous flow field may be formed from a hydrophilic material and provides uniform support across the backside of the electrode assembly to facilitate the use of thin backing layers. 9 figs.

  11. Improving water desalination by hydraulically coupling an osmotic microbial fuel cell with a microbial desalination cell

    E-Print Network [OSTI]

    Improving water desalination by hydraulically coupling an osmotic microbial fuel cell with a microbial desalination cell Bo Zhang, Zhen He n Department of Civil Engineering and Mechanics, University Keywords: Forward osmosis Ion exchange membrane Microbial fuel cell Microbial desalination cell Wastewater

  12. Prognostics of PEM fuel cell in a particle filtering framework Marine Jouin

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Prognostics of PEM fuel cell in a particle filtering framework Marine Jouin , Rafael Gouriveau.jouin@femto-st.fr Abstract Proton Exchange Membrane Fuel Cells (PEMFC) suffer from a limited lifespan, which impedes of the proposed approach. Keywords: Proton exchange membrane (PEM) fuel cell, Prognostics, Remaining useful life

  13. High Power Impulse Magnetron Sputtering deposition of Pt inside fuel cell electrodes

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 High Power Impulse Magnetron Sputtering deposition of Pt inside fuel cell electrodes S Cuynet1 as a cathode of a proton exchange membrane fuel cell. An increase of 80 % at 0.65 V of the PEMFC power density) 272001" #12;2 Proton exchange membrane fuel cells (PEMFC) have the potential to provide

  14. 1 Copyright 2009 by ASME Proceedings of FuelCell2009

    E-Print Network [OSTI]

    Hidrovo, Carlos H.

    of polymer electrolyte membrane fuel cells (PEMFCs) in automobiles has long been a promising prospect in polymer electrolyte membrane fuel cells (PEMFCs) has increased recently due to their low local emissions neutron radiography the dynamics of water production and movement within a fuel cell can be imaged during

  15. Organic fuel cells and fuel cell conducting sheets

    DOE Patents [OSTI]

    Masel, Richard I. (Champaign, IL); Ha, Su (Champaign, IL); Adams, Brian (Savoy, IL)

    2007-10-16

    A passive direct organic fuel cell includes an organic fuel solution and is operative to produce at least 15 mW/cm.sup.2 when operating at room temperature. In additional aspects of the invention, fuel cells can include a gas remover configured to promote circulation of an organic fuel solution when gas passes through the solution, a modified carbon cloth, one or more sealants, and a replaceable fuel cartridge.

  16. Proceedings of FuelCell2009 Seventh International Fuel Cell Science, Engineering and Technology Conference

    E-Print Network [OSTI]

    Stefanopoulou, Anna

    of Engineering & Natural Sciences Sabanci University Istanbul, Turkey ABSTRACT In a PEMFC, feeding dry hydrogen nearest the outlet as shown in the neutron imaging of a 53 cm2 PEMFC. This method allows in Exchange Membrane Fuel Cell (PEMFC) reduces the overall system cost, weight and volume due to reduced need

  17. Novel Materials for High Efficiency Direct Methanol Fuel Cells

    SciTech Connect (OSTI)

    Carson, Stephen; Mountz, David; He, Wensheng; Zhang, Tao

    2013-12-31

    Direct methanol fuel cell membranes were developed using blends of different polyelectrolytes with PVDF. The membranes showed complex relationships between polyelectrolyte chemistry, morphology, and processing. Although the PVDF grade was found to have little effect on the membrane permselectivity, it does impact membrane conductivity and methanol permeation values. Other factors, such as varying the polyelectrolyte polarity, using varying crosslinking agents, and adjusting the equivalent weight of the membranes impacted methanol permeation, permselectivity, and areal resistance. We now understand, within the scope of the project work completed, how these inter-related performance properties can be tailored to achieve a balance of performance.

  18. Micro/Nano Materials for Energy Storage, Fuel Cells and Sensors

    E-Print Network [OSTI]

    Nakamura, Iku

    15 Micro/Nano Materials for Energy Storage, Fuel Cells and Sensors Speaker: Prof. Dr. Li-Xian Sun energy including hydrogen storage material, fuel cells such as biofuel cells, proton exchange membrane fuel cells, direct methanol fuel cells, clean combustion of coal, etc.; 3) Bio/chemical sensors based

  19. Sustainable Power Generation in Microbial Fuel Cells Using

    E-Print Network [OSTI]

    Tullos, Desiree

    Sustainable Power Generation in Microbial Fuel Cells Using Bicarbonate Buffer and Proton Transfer applications, especially for wastewater treatment. Introduction Microbial fuel cell (MFC) technology has drawn of electrodes (6­9), (iii) selection and treatment of membranes (10­12), and (iv) optimization of the MFC design

  20. Fuel Station of the Future- Innovative Approach to Fuel Cell...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Station of the Future- Innovative Approach to Fuel Cell Technology Unveiled in California Fuel Station of the Future- Innovative Approach to Fuel Cell Technology Unveiled in...

  1. Hydrogen Fueling for Current and Anticipated Fuel Cell Electric...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Current and Anticipated Fuel Cell Electric Vehicles (FCEVs) Hydrogen Fueling for Current and Anticipated Fuel Cell Electric Vehicles (FCEVs) Download presentation slides from...

  2. Center for Intelligent Fuel Cell Materials Design

    SciTech Connect (OSTI)

    Santurri, P.R., (Chemsultants International); Hartmann-Thompson, C.; Keinath, S.E. (Michigan Molecular Inst.)

    2008-08-26

    The goal of this work was to develop a composite proton exchange membrane utilizing 1) readily available, low cost materials 2) readily modified and 3) easily processed to meet the chemical, mechanical and electrical requirements of high temperature PEM fuel cells. One of the primary goals was to produce a conducting polymer that met the criteria for strength, binding capability for additives, chemical stability, dimensional stability and good conductivity. In addition compatible, specialty nanoparticles were synthesized to provide water management and enhanced conductivity. The combination of these components in a multilayered, composite PEM has demonstrated improved conductivity at high temperatures and low humidity over commercially available polymers. The research reported in this final document has greatly increased the knowledge base related to post sulfonation of chemically and mechanically stable engineered polymers (Radel). Both electrical and strength factors for the degree of post sulfonation far exceed previous data, indicating the potential use of these materials in suitable proton exchange membrane architectures for the development of fuel cells. In addition compatible, hydrophilic, conductive nano-structures have been synthesized and incorporated into unique proton exchange membrane architectures. The use of post sulfonation for the engineered polymer and nano-particle provide cost effective techniques to produce the required components of a proton exchange membrane. The development of a multilayer proton exchange membrane as described in our work has produced a highly stable membrane at 170°C with conductivities exceeding commercially available proton exchange membranes at high temperatures and low humidity. The components and architecture of the proton exchange membrane discussed will provide low cost components for the portable market and potentially the transportation market. The development of unique components and membrane architecture provides a key element for the United States: 1) to transition the country from a fossil fuel based energy economy to a renewable energy based economy, and 2) to reduce our dependence on foreign oil. Developments of this program will serve as an important step toward continuing PEMFC technology and ultimately the broad-based commercial availability of this technology and its benefits.

  3. Microfluidic Microbial Fuel Cells for Microstructure Interrogations

    E-Print Network [OSTI]

    Parra, Erika Andrea

    2010-01-01

    Sediment microbial fuel cells demonstrating marine (left)Model of hydrogen fuel cell kinetic losses including5 FutureWork 5.1 Microfluidic Microbial Fuel Cell Continued

  4. Microfluidic Microbial Fuel Cells for Microstructure Interrogations

    E-Print Network [OSTI]

    Parra, Erika Andrea

    2010-01-01

    microbial fuel cell applications using dielectrophoresis,”electrochemistry: Application to Fuel Cells. PhD thesis,scale, microbial fuel cells find their application in the

  5. Microfluidic Microbial Fuel Cells for Microstructure Interrogations

    E-Print Network [OSTI]

    Parra, Erika Andrea

    2010-01-01

    on hydrogen fuel cell theoretical efficiency, ? rev , andon hydrogen fuel cell theoretical efficiency, ? rev , andand power and efficiency of PEM fuel cells. In this section,

  6. Microfluidic Microbial Fuel Cells for Microstructure Interrogations

    E-Print Network [OSTI]

    Parra, Erika Andrea

    2010-01-01

    Model of hydrogen fuel cell kinetic losses includingschematic of typical hydrogen fuel cell performancephase factors on hydrogen fuel cell theoretical efficiency,

  7. Sandia Energy - Maritime Hydrogen Fuel Cell Project

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fuel Cell Project Home Transportation Energy Hydrogen Market Transformation Maritime Hydrogen & SF-BREEZE Maritime Hydrogen Fuel Cell Project Maritime Hydrogen Fuel Cell...

  8. Modeling and High-Resolution-Imaging Studies of Water-Content Profiles in a Polymer-Electrolyte-Fuel-Cell Membrane-Electrode Assembly

    E-Print Network [OSTI]

    Weber, A.Z.

    2008-01-01

    the weighted sum of the water content in the membrane in theposition of the maximum water content and the water-contentgradient in the water content and capillary pressure,

  9. Modeling and High-Resolution-Imaging Studies of Water-Content Profiles in a Polymer-Electrolyte-Fuel-Cell Membrane-Electrode Assembly

    E-Print Network [OSTI]

    Weber, A.Z.

    2008-01-01

    is the weighted sum of the water content in the membrane inResolution-Imaging Studies of Water-Content Profiles in aPark, PA 16802, USA. b Water-content profiles across the

  10. Extended Platinum Nanotubes as Fuel Cell Catalysts

    SciTech Connect (OSTI)

    Alia, S.; Pivovar, B. S.; Yan, Y.

    2012-01-01

    Energy consumption has relied principally on fossil fuels as an energy source; fuel cells, however, can provide a clean and sustainable alternative, an answer to the depletion and climate change concerns of fossil fuels. Within proton exchange membrane fuel cells, high catalyst cost and poor durability limit the commercial viability of the device. Recently, platinum nanotubes (PtNTs) were studied as durable, active catalysts, providing a platform to meet US Department of Energy vehicular activity targets.[1] Porous PtNTs were developed to increase nanotube surface area, improving mass activity for oxygen reduction without sacrificing durability.[2] Subsurface platinum was then replaced with palladium, forming platinum-coated palladium nanotubes.[3] By forming a core shell structure, platinum utilization was increased, reducing catalyst cost. Alternative substrates have also been examined, modifying platinum surface facets and increasing oxygen reduction specific activity. Through modification of the PtNT platform, catalyst limitations can be reduced, ensuring a commercially viable device.

  11. Hybrid Fuel Cell Technology Overview

    SciTech Connect (OSTI)

    None available

    2001-05-31

    For the purpose of this STI product and unless otherwise stated, hybrid fuel cell systems are power generation systems in which a high temperature fuel cell is combined with another power generating technology. The resulting system exhibits a synergism in which the combination performs with an efficiency far greater than can be provided by either system alone. Hybrid fuel cell designs under development include fuel cell with gas turbine, fuel cell with reciprocating (piston) engine, and designs that combine different fuel cell technologies. Hybrid systems have been extensively analyzed and studied over the past five years by the Department of Energy (DOE), industry, and others. These efforts have revealed that this combination is capable of providing remarkably high efficiencies. This attribute, combined with an inherent low level of pollutant emission, suggests that hybrid systems are likely to serve as the next generation of advanced power generation systems.

  12. Fuel Cell Technologies Program Overview

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015ExecutiveFluorescentDanKathy LoftusFuel Cell Seminar2015ofFuelCell|FYIEA

  13. Fuel Cell Technologies Program Overview

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015ExecutiveFluorescentDanKathy LoftusFuel Cell Seminar2015ofFuelCell|FYIEA

  14. Fuel Cell Technologies Program Overview

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015ExecutiveFluorescentDanKathy LoftusFuel CellFuel Cell Technologies

  15. Fuel Cell Research

    SciTech Connect (OSTI)

    Weber, Peter M.

    2014-03-30

    Executive Summary In conjunction with the Brown Energy Initiative, research Projects selected for the fuel cell research grant were selected on the following criteria: ? They should be fundamental research that has the potential to significantly impact the nation’s energy infrastructure. ? They should be scientifically exciting and sound. ? They should synthesize new materials, lead to greater insights, explore new phenomena, or design new devices or processes that are of relevance to solving the energy problems. ? They involve top-caliper senior scientists with a record of accomplishment, or junior faculty with outstanding promise of achievement. ? They should promise to yield at least preliminary results within the given funding period, which would warrant further research development. ? They should fit into the overall mission of the Brown Energy Initiative, and the investigators should contribute as partners to an intellectually stimulating environment focused on energy science. Based on these criteria, fourteen faculty across three disciplines (Chemistry, Physics and Engineering) and the Charles Stark Draper Laboratory were selected to participate in this effort.1 In total, there were 30 people supported, at some level, on these projects. This report highlights the findings and research outcomes of the participating researchers.

  16. Fuel Cell Technologies Program Overview

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015ExecutiveFluorescentDanKathy LoftusFuel Cell

  17. Fuel Cell Technologies Office: Publications

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuelsof Energy Services »Information Resources » Fuel Cell

  18. Fuel Cells | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data CenterFinancial Opportunities Financialof Energy Cell

  19. Financing Fuel Cells

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015Executive Order14,Energy 9,UNIVERSITYDepartment of

  20. Fuel Cell Case Study

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015ExecutiveFluorescentDanKathy Loftus Global Leader, Sustainable

  1. Fuel cell gas management system

    DOE Patents [OSTI]

    DuBose, Ronald Arthur (Marietta, GA)

    2000-01-11

    A fuel cell gas management system including a cathode humidification system for transferring latent and sensible heat from an exhaust stream to the cathode inlet stream of the fuel cell; an anode humidity retention system for maintaining the total enthalpy of the anode stream exiting the fuel cell equal to the total enthalpy of the anode inlet stream; and a cooling water management system having segregated deionized water and cooling water loops interconnected by means of a brazed plate heat exchanger.

  2. Molten carbonate fuel cell separator

    DOE Patents [OSTI]

    Nickols, Richard C. (East Hartford, CT)

    1986-09-02

    In a stacked array of molten carbonate fuel cells, a fuel cell separator is positioned between adjacent fuel cells to provide isolation as well as a conductive path therebetween. The center portion of the fuel cell separator includes a generally rectangular, flat, electrical conductor. Around the periphery of the flat portion of the separator are positioned a plurality of elongated resilient flanges which form a gas-tight seal around the edges of the fuel cell. With one elongated flange resiliently engaging a respective edge of the center portion of the separator, the sealing flanges, which are preferably comprised of a noncorrosive material such as an alloy of yttrium, iron, aluminum or chromium, form a tight-fitting wet seal for confining the corrosive elements of the fuel cell therein. This arrangement permits a good conductive material which may be highly subject to corrosion and dissolution to be used in combination with a corrosion-resistant material in the fuel cell separator of a molten carbonate fuel cell for improved fuel cell conductivity and a gas-tight wet seal.

  3. Molten carbonate fuel cell separator

    DOE Patents [OSTI]

    Nickols, R.C.

    1984-10-17

    In a stacked array of molten carbonate fuel cells, a fuel cell separator is positioned between adjacent fuel cells to provide isolation as well as a conductive path therebetween. The center portion of the fuel cell separator includes a generally rectangular, flat, electrical conductor. Around the periphery of the flat portion of the separator are positioned a plurality of elongated resilient flanges which form a gas-tight seal around the edges of the fuel cell. With one elongated flange resiliently engaging a respective edge of the center portion of the separator, the sealing flanges, which are preferably comprised of a noncorrosive material such as an alloy of yttrium, iron, aluminum or chromium, form a tight-fitting wet seal for confining the corrosive elements of the fuel cell therein. This arrangement permits a good conductive material which may be highly subject to corrosion and dissolution to be used in combination with a corrosion-resistant material in the fuel cell separator of a molten carbonate fuel cell for improved fuel cell conductivity and a gas-tight wet seal.

  4. Fuel Cell Handbook (Seventh Edition)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Directly to the Local Utility...... 8-37 8.2.6 Power Conditioners for Automotive Fuel Cells ... 8-39 8.2.7 Power Conversion...

  5. Fuel cell system with interconnect

    DOE Patents [OSTI]

    Goettler, Richard; Liu, Zhien

    2015-08-11

    The present invention includes a fuel cell system having a plurality of adjacent electrochemical cells formed of an anode layer, a cathode layer spaced apart from the anode layer, and an electrolyte layer disposed between the anode layer and the cathode layer. The fuel cell system also includes at least one interconnect, the interconnect being structured to conduct free electrons between adjacent electrochemical cells. Each interconnect includes a primary conductor embedded within the electrolyte layer and structured to conduct the free electrons.

  6. Fuel cell system with interconnect

    SciTech Connect (OSTI)

    Liu, Zhien; Goettler, Richard

    2015-09-29

    The present invention includes a fuel cell system having a plurality of adjacent electrochemical cells formed of an anode layer, a cathode layer spaced apart from the anode layer, and an electrolyte layer disposed between the anode layer and the cathode layer. The fuel cell system also includes at least one interconnect, the interconnect being structured to conduct free electrons between adjacent electrochemical cells. Each interconnect includes a primary conductor embedded within the electrolyte layer and structured to conduct the free electrons.

  7. Fuel cell system with interconnect

    DOE Patents [OSTI]

    Goettler, Richard; Liu, Zhien

    2015-03-10

    The present invention includes a fuel cell system having a plurality of adjacent electrochemical cells formed of an anode layer, a cathode layer spaced apart from the anode layer, and an electrolyte layer disposed between the anode layer and the cathode layer. The fuel cell system also includes at least one interconnect, the interconnect being structured to conduct free electrons between adjacent electrochemical cells. Each interconnect includes a primary conductor embedded within the electrolyte layer and structured to conduct the free electrons.

  8. Low Temperature Fuel Cell and Electrolyzer Balance-of-Plant Manufactur...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electrolyte Membrane (PEM) Fuel Cell for Material Handling Applications Manufacturing Cost Analysis of 1 kW and 5 kW Solid Oxide Fuel Cell (SOFC) for Auxiliary Power Applications...

  9. Biomimetic Synthesis of Noble Metal Nanoparticles and Their Applications as Electro-catalysts in Fuel Cells

    E-Print Network [OSTI]

    Li, Yujing

    2012-01-01

    membrane fuel cell (PEMFC) and direct methanol fuel cell (operation and performance of PEMFC and DMFC depend largelyused electro-catalysts for PEMFC and DMFC are Pt-based noble

  10. Fuel Cell Technologies Overview

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Financing Tool Fits the Bill Financing Tool Fits theSunShot Prize:4 FuelAbout Key Activities

  11. Internal reforming fuel cell assembly with simplified fuel feed

    DOE Patents [OSTI]

    Farooque, Mohammad (Huntington, CT); Novacco, Lawrence J. (Brookfield, CT); Allen, Jeffrey P. (Naugatuck, CT)

    2001-01-01

    A fuel cell assembly in which fuel cells adapted to internally reform fuel and fuel reformers for reforming fuel are arranged in a fuel cell stack. The fuel inlet ports of the fuel cells and the fuel inlet ports and reformed fuel outlet ports of the fuel reformers are arranged on one face of the fuel cell stack. A manifold sealing encloses this face of the stack and a reformer fuel delivery system is arranged entirely within the region between the manifold and the one face of the stack. The fuel reformer has a foil wrapping and a cover member forming with the foil wrapping an enclosed structure.

  12. Identification and Characterization of Near-Term Direct Hydrogen PEM Fuel Cell Markets

    Fuel Cell Technologies Publication and Product Library (EERE)

    This document provides information about near-term markets (such as for forklifts and telecommunications) for proton exchange membrane fuel cells.

  13. SBIR/STTR FY15 Release 1 Awards Announced-Includes Fuel Cell...

    Office of Environmental Management (EM)

    production of reversible alkaline membrane fuel cells with better performance and lower cost than current technology. Detection of Contaminants in Hydrogen: Southwest...

  14. Report of the DOE Advanced Fuel-Cell Commercialization Working Group

    SciTech Connect (OSTI)

    Penner, S.S.

    1995-03-01

    This report describes commercialization for stationary power applications of phosphoric acid, molten carbonate, solid oxide, and polymer electrolyte membrane fuel cells.

  15. Identification and Characterization of Near-Term Direct Hydrogen PEM Fuel Cell Markets

    SciTech Connect (OSTI)

    Mahadevan, K.; Judd, K.; Stone, H.; Zewatsky, J.; Thomas, A.; Mahy, H.; Paul, D.

    2007-04-15

    This document provides information about near-term markets (such as for forklifts and telecommunications) for proton exchange membrane fuel cells.

  16. Modeling and Optimization of PEMFC Systems and its Application to Direct Hydrogen Fuel Cell Vehicles

    E-Print Network [OSTI]

    Zhao, Hengbing; Burke, Andy

    2008-01-01

    and Optimization of PEMFC Systems and its Application toand Optimization of PEMFC Systems and its Application onExchange Membrane fuel cell (PEMFC) technology for use in

  17. Microfluidic Microbial Fuel Cells for Microstructure Interrogations

    E-Print Network [OSTI]

    Parra, Erika Andrea

    2010-01-01

    process for the dual channeled microbial fuel cell. Theprocess for the dual channeled microbial fuel cell. The

  18. Characterization of Fuel-Cell Diffusion Media

    E-Print Network [OSTI]

    Gunterman, Haluna Penelope Frances

    2011-01-01

    electrolyte fuel cells (PEFC) is an ongoing challenge.PEFC.electrolyte fuel cell (PEFC) is a device that converts

  19. Sandia Energy - Fuel Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid youOxygen GenerationTechnologiesEnergy ConversionEngine CombustionFuel

  20. Ohio Fuel Cell Initiative

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy Bills and ReduceNovemberDOE'sManagement ofOh, the (Energy-Related) Stories

  1. Fuel Cell Financing Options

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015ExecutiveFluorescentDanKathy Loftus Global Leader, Sustainable4IssuesUTC

  2. Hydrogen & Fuel Cells -Program Overview -

    E-Print Network [OSTI]

    and Peer Evaluation Meeting May 14, 2012 #12;Petroleum 37% Natural Gas 25% Coal 21% Nuclear Energy 9% Korea 7% Canada 3% Taiwan 1% Great Britain 1% France 1% Other 3% Japan 31% Fuel Cell Patents Geographic Others. For 2008-2011 All Others Germany South Korea Japan United States Fuel Cell Market Overview

  3. Energy 101: Fuel Cell Technology

    ScienceCinema (OSTI)

    None

    2014-06-06

    Learn how fuel cell technology generates clean electricity from hydrogen to power our buildings and transportation-while emitting nothing but water. This video illustrates the fundamentals of fuel cell technology and its potential to supply our homes, offices, industries, and vehicles with sustainable, reliable energy.

  4. Bonded polyimide fuel cell package

    DOE Patents [OSTI]

    Morse, Jeffrey D.; Jankowski, Alan; Graff, Robert T.; Bettencourt, Kerry

    2010-06-08

    Described herein are processes for fabricating microfluidic fuel cell systems with embedded components in which micron-scale features are formed by bonding layers of DuPont Kapton.TM. polyimide laminate. A microfluidic fuel cell system fabricated using this process is also described.

  5. Energy 101: Fuel Cell Technology

    SciTech Connect (OSTI)

    2014-03-11

    Learn how fuel cell technology generates clean electricity from hydrogen to power our buildings and transportation-while emitting nothing but water. This video illustrates the fundamentals of fuel cell technology and its potential to supply our homes, offices, industries, and vehicles with sustainable, reliable energy.

  6. Bronx Zoo Fuel Cell Project

    SciTech Connect (OSTI)

    Hoang Pham

    2007-09-30

    A 200 kW Fuel Cell has been installed in the Lion House, Bronx Zoo, NY. The Fuel Cell is a 200 kW phosphoric acid type manufactured by United Technologies Corporation (UTC) and will provide thermal energy at 725,000 Btu/hr.

  7. Hydrogen & Fuel Cells Program Overview

    E-Print Network [OSTI]

    and Peer Evaluation Meeting May 9, 2011 #12;Enable widespread commercialization of hydrogen and fuel cell: > 300-mile range for vehicles--without compromising interior space or performance #12;Balance of Plant estimate" for 2008 http://hydrogendoedev.nrel.gov/peer_reviews.html Progress ­ Fuel Cell R&D 2010 2007 6

  8. Fuel cell generator with fuel electrodes that control on-cell fuel reformation

    DOE Patents [OSTI]

    Ruka, Roswell J. (Pittsburgh, PA); Basel, Richard A. (Pittsburgh, PA); Zhang, Gong (Murrysville, PA)

    2011-10-25

    A fuel cell for a fuel cell generator including a housing including a gas flow path for receiving a fuel from a fuel source and directing the fuel across the fuel cell. The fuel cell includes an elongate member including opposing first and second ends and defining an interior cathode portion and an exterior anode portion. The interior cathode portion includes an electrode in contact with an oxidant flow path. The exterior anode portion includes an electrode in contact with the fuel in the gas flow path. The anode portion includes a catalyst material for effecting fuel reformation along the fuel cell between the opposing ends. A fuel reformation control layer is applied over the catalyst material for reducing a rate of fuel reformation on the fuel cell. The control layer effects a variable reformation rate along the length of the fuel cell.

  9. Membrane Cells in Chlor Alkali Application 

    E-Print Network [OSTI]

    Lesker, K.

    1992-01-01

    stream_source_info ESL-IE-92-04-46.pdf.txt stream_content_type text/plain stream_size 8868 Content-Encoding ISO-8859-1 stream_name ESL-IE-92-04-46.pdf.txt Content-Type text/plain; charset=ISO-8859-1 MEMBRANE CELLS... and paper industry, there is still a n overall increase in production due to the higher growth rates in the A~ian region. Tht: t:wllolllical anu t:Cological auvalllagt:s of membrane technology have been growing since its introduction more than one...

  10. Automotive Fuel Cell Corporation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room News PublicationsAudits & Inspections Audits & Inspections

  11. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Draper, R.; George, R.A.; Shockling, L.A.

    1993-04-06

    A solid oxide fuel cell generator has a pair of spaced apart tubesheets in a housing. At least two intermediate barrier walls are between the tubesheets and define a generator chamber between two intermediate buffer chambers. An array of fuel cells have tubes with open ends engaging the tubesheets. Tubular, axially elongated electrochemical cells are supported on the tubes in the generator chamber. Fuel gas and oxidant gas are preheated in the intermediate chambers by the gases flowing on the other side of the tubes. Gas leakage around the tubes through the tubesheets is permitted. The buffer chambers reentrain the leaked fuel gas for reintroduction to the generator chamber.

  12. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Draper, Robert (Churchill Boro, PA); George, Raymond A. (Pittsburgh, PA); Shockling, Larry A. (Plum Borough, PA)

    1993-01-01

    A solid oxide fuel cell generator has a pair of spaced apart tubesheets in a housing. At least two intermediate barrier walls are between the tubesheets and define a generator chamber between two intermediate buffer chambers. An array of fuel cells have tubes with open ends engaging the tubesheets. Tubular, axially elongated electrochemical cells are supported on the tubes in the generator chamber. Fuel gas and oxidant gas are preheated in the intermediate chambers by the gases flowing on the other side of the tubes. Gas leakage around the tubes through the tubesheets is permitted. The buffer chambers reentrain the leaked fuel gas for reintroduction to the generator chamber.

  13. Fuel cell electric power production

    DOE Patents [OSTI]

    Hwang, Herng-Shinn (Livingston, NJ); Heck, Ronald M. (Frenchtown, NJ); Yarrington, Robert M. (Westfield, NJ)

    1985-01-01

    A process for generating electricity from a fuel cell includes generating a hydrogen-rich gas as the fuel for the fuel cell by treating a hydrocarbon feed, which may be a normally liquid feed, in an autothermal reformer utilizing a first monolithic catalyst zone having palladium and platinum catalytic components therein and a second, platinum group metal steam reforming catalyst. Air is used as the oxidant in the hydrocarbon reforming zone and a low oxygen to carbon ratio is maintained to control the amount of dilution of the hydrogen-rich gas with nitrogen of the air without sustaining an insupportable amount of carbon deposition on the catalyst. Anode vent gas may be utilized as the fuel to preheat the inlet stream to the reformer. The fuel cell and the reformer are preferably operated at elevated pressures, up to about a pressure of 150 psia for the fuel cell.

  14. Fuel Cells | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EA Jump to:ofEnia SpAFlex FuelsEnergyInc| OpenFuMA TechFuel Cells

  15. Fuel Cells in the States

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015ExecutiveFluorescentDanKathy LoftusFuel CellFuel Fuelgreen hfor|Fuelin

  16. Corrosion resistant PEM fuel cell

    DOE Patents [OSTI]

    Li, Y.; Meng, W.J.; Swathirajan, S.; Harris, S.J.; Doll, G.L.

    1997-04-29

    The present invention contemplates a PEM fuel cell having electrical contact elements (including bipolar plates/septums) comprising a titanium nitride coated light weight metal (e.g., Al or Ti) core, having a passivating, protective metal layer intermediate the core and the titanium nitride. The protective layer forms a barrier to further oxidation/corrosion when exposed to the fuel cell`s operating environment. Stainless steels rich in Cr, Ni, and Mo are particularly effective protective interlayers. 6 figs.

  17. Double interconnection fuel cell array

    DOE Patents [OSTI]

    Draper, R.; Zymboly, G.E.

    1993-12-28

    A fuel cell array is made, containing number of tubular, elongated fuel cells which are placed next to each other in rows (A, B, C, D), where each cell contains inner electrodes and outer electrodes, with solid electrolyte between the electrodes, where the electrolyte and outer electrode are discontinuous, having two portions, and providing at least two opposed discontinuities which contain at least two oppositely opposed interconnections contacting the inner electrode, each cell having only three metallic felt electrical connectors which contact surrounding cells, where each row is electrically connected to the other. 5 figures.

  18. Double interconnection fuel cell array

    DOE Patents [OSTI]

    Draper, Robert (Churchill Boro, PA); Zymboly, Gregory E. (Murrysville, PA)

    1993-01-01

    A fuel cell array (10) is made, containing number of tubular, elongated fuel cells (12) which are placed next to each other in rows (A, B, C, D), where each cell contains inner electrodes (14) and outer electrodes (18 and 18'), with solid electrolyte (16 and 16') between the electrodes, where the electrolyte and outer electrode are discontinuous, having two portions, and providing at least two opposed discontinuities which contain at least two oppositely opposed interconnections (20 and 20') contacting the inner electrode (14), each cell (12) having only three metallic felt electrical connectors (22) which contact surrounding cells, where each row is electrically connected to the other.

  19. Nanostructured Solid Oxide Fuel Cell Electrodes

    E-Print Network [OSTI]

    Sholklapper, Tal Zvi

    2007-01-01

    that fuel cells are superior from an efficiency standpointefficiency is only The theoretical voltage obtained from fuel cellof the efficiency vs. rate power for fuel cells is compared

  20. Canadian Fuel Cell Commercialization Roadmap Update: Progress...

    Open Energy Info (EERE)

    Canadian Fuel Cell Commercialization Roadmap Update: Progress of Canada's Hydrogen and Fuel Cell Industry Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Canadian Fuel...

  1. Hydrogen Fuel Cell Vehicles

    E-Print Network [OSTI]

    Delucchi, Mark

    1992-01-01

    to produce a unit of bio-energy than is required to producecompared the amount of bio-energy (45 eJ) that could besource (electricity or bio-energy) or the end-use fuel (

  2. Navy fuel cell demonstration project.

    SciTech Connect (OSTI)

    Black, Billy D.; Akhil, Abbas Ali

    2008-08-01

    This is the final report on a field evaluation by the Department of the Navy of twenty 5-kW PEM fuel cells carried out during 2004 and 2005 at five Navy sites located in New York, California, and Hawaii. The key objective of the effort was to obtain an engineering assessment of their military applications. Particular issues of interest were fuel cell cost, performance, reliability, and the readiness of commercial fuel cells for use as a standalone (grid-independent) power option. Two corollary objectives of the demonstration were to promote technological advances and to improve fuel performance and reliability. From a cost perspective, the capital cost of PEM fuel cells at this stage of their development is high compared to other power generation technologies. Sandia National Laboratories technical recommendation to the Navy is to remain involved in evaluating successive generations of this technology, particularly in locations with greater environmental extremes, and it encourages their increased use by the Navy.

  3. Climate Change Fuel Cell Program

    SciTech Connect (OSTI)

    Paul Belard

    2006-09-21

    Verizon is presently operating the largest Distributed Generation Fuel Cell project in the USA. Situated in Long Island, NY, the power plant is composed of seven (7) fuel cells operating in parallel with the Utility grid from the Long Island Power Authority (LIPA). Each fuel cell has an output of 200 kW, for a total of 1.4 mW generated from the on-site plant. The remaining power to meet the facility demand is purchased from LIPA. The fuel cell plant is utilized as a co-generation system. A by-product of the fuel cell electric generation process is high temperature water. The heat content of this water is recovered from the fuel cells and used to drive two absorption chillers in the summer and a steam generator in the winter. Cost savings from the operations of the fuel cells are forecasted to be in excess of $250,000 per year. Annual NOx emissions reductions are equivalent to removing 1020 motor vehicles from roadways. Further, approximately 5.45 million metric tons (5 millions tons) of CO2 per year will not be generated as a result of this clean power generation. The project was partially financed with grants from the New York State Energy R&D Authority (NYSERDA) and from Federal Government Departments of Defense and Energy.

  4. DOE Fuel Cell Technologies Office Record 14012: Fuel Cell System...

    Broader source: Energy.gov (indexed) [DOE]

    Results from the analysis were communicated to the FCT Office at the DOE Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation 3 and at a meeting of the...

  5. Fuel Cell Stack Components BipolarPlate

    E-Print Network [OSTI]

    for Metallic Bipolar Plates · Carbon Foam for Fuel Cell Humidification · High Temperature Proton ExchangeFuel Cell Stack Components Fuel Processor BipolarPlate Cathode+ Anode- Electrolyte H+ H+ HYDROGEN Crossover Fuel Cell Stack Components #12;Barriers

  6. Fuel Cell R&D Pre-Solicitation Workshop

    E-Print Network [OSTI]

    Fuel Cell Membranes · Water Transport Within the Stack · Advanced Cathode Catalysts and Supports · Cell Hardware (Bipolar Plates, Seals) · Freeze-Capable Stacks · Balance of Plant (Compressors, Auxiliary Motor resistant to humidity cycling damage. #12;Topic 2: Water Transport Within the Stack Topic 2A: Exploratory

  7. ADVANCED HYDROGEN TRANSPORT MEMBRANES FOR VISION 21 FOSSIL FUEL PLANTS

    SciTech Connect (OSTI)

    Shane E. Roark; Tony F. Sammells; Richard A. Mackay; Adam E. Calihman; Lyrik Y. Pitzman; Tom F. Barton; Sara L. Rolfe; Richard N. Kleiner; James E. Stephan; Mike J. Holmes; Aaron L. Wagner

    2001-07-30

    Eltron Research Inc., and team members, are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. This objective is being pursued using dense membranes based in part on Eltron-patented ceramic materials with a demonstrated ability for proton and electron conduction. The technical goals are being addressed by modifying single-phase and composite membrane composition and microstructure to maximize proton and electron conductivity without loss of material stability. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. During this quarter, ceramic, cermet (ceramic/metal), and thin film membranes were prepared, characterized, and evaluated for H{sub 2} transport. For selected ceramic membrane compositions an optimum range for transition metal doping was identified, and it was determined that highest proton conductivity occurred for two-phase ceramic materials. Furthermore, a relationship between transition metal dopant atomic number and conductivity was observed. Ambipolar conductivities of {approx}6 x 10{sup -3} S/cm were achieved for these materials, and {approx} 1-mm thick membranes generated H{sub 2} transport rates as high as 0.3 mL/min/cm{sup 2}. Cermet membranes during this quarter were found to have a maximum conductivity of 3 x 10{sup -3} S/cm, which occurred at a metal phase contact of 36 vol.%. Homogeneous dense thin films were successfully prepared by tape casting and spin coating; however, there remains an unacceptably high difference in shrinkage rates between the film and support, which led to membrane instability. Further improvements in high pressure membrane seals also were achieved during this quarter, and a maximum pressure of 100 psig was attained. CoorsTek optimized many of the processing variables relevant to manufacturing scale production of ceramic H{sub 2} transport membranes, and SCI used their expertise to deposit a range of catalysts compositions onto ceramic membrane surfaces. Finally, MTI compiled relevant information regarding Vision 21 fossil fuel plant operation parameters, which will be used as a starting point for assessing the economics of incorporating a H{sub 2} separation unit.

  8. MATHEMATICAL MODELING OF CHANNEL POROUS LAYER INTERFACES IN PEM FUEL CELLS

    E-Print Network [OSTI]

    Ehrhardt, Matthias

    MATHEMATICAL MODELING OF CHANNEL ­ POROUS LAYER INTERFACES IN PEM FUEL CELLS M. EHRHARDT, J, Germany ABSTRACT In proton exchange membrane (PEM) fuel cells, the transport of the fuel to the active diffusion layers. In order to improve existing mathematical and numerical models of PEM fuel cells, a deeper

  9. Additive Manufacturing for Fuel Cells

    Broader source: Energy.gov [DOE]

    Blake Marshall, AMO's lead for Additive Manufacturing Technologies, will provide an overview of current R&D activities in additive manufacturing and its application to fuel cell prototyping and...

  10. CLIMATE CHANGE FUEL CELL PROGRAM

    SciTech Connect (OSTI)

    Mike Walneuski

    2004-09-16

    ChevronTexaco has successfully operated a 200 kW PC25C phosphoric acid fuel cell power plant at the corporate data center in San Ramon, California for the past two years and seven months following installation in December 2001. This site was chosen based on the ability to utilize the combined heat (hot water) and power generation capability of this modular fuel cell power plant in an office park setting . In addition, this project also represents one of the first commercial applications of a stationary fuel cell for a mission critical data center to assess power reliability benefits. This fuel cell power plant system has demonstrated outstanding reliability and performance relative to other comparably sized cogeneration systems.

  11. Metrology for Fuel Cell Manufacturing

    SciTech Connect (OSTI)

    Stocker, Michael; Stanfield, Eric

    2015-02-04

    The project was divided into three subprojects. The first subproject is Fuel Cell Manufacturing Variability and Its Impact on Performance. The objective was to determine if flow field channel dimensional variability has an impact on fuel cell performance. The second subproject is Non-contact Sensor Evaluation for Bipolar Plate Manufacturing Process Control and Smart Assembly of Fuel Cell Stacks. The objective was to enable cost reduction in the manufacture of fuel cell plates by providing a rapid non-contact measurement system for in-line process control. The third subproject is Optical Scatterfield Metrology for Online Catalyst Coating Inspection of PEM Soft Goods. The objective was to evaluate the suitability of Optical Scatterfield Microscopy as a viable measurement tool for in situ process control of catalyst coatings.

  12. Cornell Fuel Cell Institute: Materials Discovery to Enable Fuel Cell Technologies

    SciTech Connect (OSTI)

    Abruna, H.D.; DiSalvo, Francis J.

    2012-06-29

    The discovery and understanding of new, improved materials to advance fuel cell technology are the objectives of the Cornell Fuel Cell Institute (CFCI) research program. CFCI was initially formed in 2003. This report highlights the accomplishments from 2006-2009. Many of the grand challenges in energy science and technology are based on the need for materials with greatly improved or even revolutionary properties and performance. This is certainly true for fuel cells, which have the promise of being highly efficient in the conversion of chemical energy to electrical energy. Fuel cells offer the possibility of efficiencies perhaps up to 90 % based on the free energy of reaction. Here, the challenges are clearly in the materials used to construct the heart of the fuel cell: the membrane electrode assembly (MEA). The MEA consists of two electrodes separated by an ionically conducting membrane. Each electrode is a nanocomposite of electronically conducting catalyst support, ionic conductor and open porosity, that together form three percolation networks that must connect to each catalyst nanoparticle; otherwise the catalyst is inactive. This report highlights the findings of the three years completing the CFCI funding, and incudes developments in materials for electrocatalyts, catalyst supports, materials with structured and functional porosity for electrodes, and novel electrolyte membranes. The report also discusses developments at understanding electrocatalytic mechanisms, especially on novel catalyst surfaces, plus in situ characterization techniques and contributions from theory. Much of the research of the CFCI continues within the Energy Materials Center at Cornell (emc2), a DOE funded, Office of Science Energy Frontier Research Center (EFRC).

  13. Stationary Fuel Cell Evaluation (Presentation)

    SciTech Connect (OSTI)

    Kurtz, J.; Wipke, K.; Sprik, S.; Ramsden, T.; Ainscough, C.

    2012-05-01

    This powerpoint presentation discusses its objectives: real world operation data from the field and state-of-the-art lab; collection; analysis for independent technology validation; collaboration with industry and end users operating stationary fuel cell systems and reporting on technology status, progress and technical challenges. The approach and accomplishments are: A quarterly data analysis and publication of first technical stationary fuel cell composite data products (data through June 2012).

  14. Variable area fuel cell cooling

    DOE Patents [OSTI]

    Kothmann, Richard E. (Churchill Borough, PA)

    1982-01-01

    A fuel cell arrangement having cooling fluid flow passages which vary in surface area from the inlet to the outlet of the passages. A smaller surface area is provided at the passage inlet, which increases toward the passage outlet, so as to provide more uniform cooling of the entire fuel cell. The cooling passages can also be spaced from one another in an uneven fashion.

  15. Corrosion resistant PEM fuel cell

    DOE Patents [OSTI]

    Li, Yang (Troy, MI); Meng, Wen-Jin (Okemos, MI); Swathirajan, Swathy (West Bloomfield, MI); Harris, Stephen J. (Bloomfield, MI); Doll, Gary L. (Orion Township, Oakland County, MI)

    1997-01-01

    The present invention contemplates a PEM fuel cell having electrical contact elements (including bipolar plates/septums) comprising a titanium nitride coated light weight metal (e.g., Al or Ti) core, having a passivating, protective metal layer intermediate the core and the titanium nitride. The protective layer forms a barrier to further oxidation/corrosion when exposed to the fuel cell's operating environment. Stainless steels rich in CR, Ni, and Mo are particularly effective protective interlayers.

  16. Corrosion resistant PEM fuel cell

    DOE Patents [OSTI]

    Li, Yang; Meng, Wen-Jin; Swathirajan, Swathy; Harris, Stephen Joel; Doll, Gary Lynn

    2001-07-17

    The present invention contemplates a PEM fuel cell having electrical contact elements (including bipolar plates/septums) comprising a titanium nitride coated light weight metal (e.g., Al or Ti) core, having a passivating, protective metal layer intermediate the core and the titanium nitride. The protective layer forms a barrier to further oxidation/corrosion when exposed to the fuel cell's operating environment. Stainless steels rich in CR, Ni, and Mo are particularly effective protective interlayers.

  17. Corrosion resistant PEM fuel cell

    DOE Patents [OSTI]

    Li, Yang (Troy, MI); Meng, Wen-Jin (Okemos, MI); Swathirajan, Swathy (West Bloomfield, MI); Harris, Stephen Joel (Bloomfield, MI); Doll, Gary Lynn (Orion Township, Oakland County, MI)

    2002-01-01

    The present invention contemplates a PEM fuel cell having electrical contact elements (including bipolar plates/septums) comprising a titanium nitride coated light weight metal (e.g., Al or Ti) core, having a passivating, protective metal layer intermediate the core and the titanium nitride. The protective layer forms a barrier to further oxidation/corrosion when exposed to the fuel cell's operating environment. Stainless steels rich in CR, Ni, and Mo are particularly effective protective interlayers.

  18. Rapidly refuelable fuel cell

    DOE Patents [OSTI]

    Joy, Richard W. (Santa Clara, CA)

    1985-01-01

    A rapidly refuelable dual cell of an electrochemical type wherein a single anode cooperates with two cathodes and wherein the anode has a fixed position and the cathodes are urged toward opposite faces of the anodes at constant and uniform force. The associated cathodes are automatically retractable to permit the consumed anode remains to be removed from the housing and a new anode inserted between the two cathodes.

  19. Rapidly refuelable fuel cell

    DOE Patents [OSTI]

    Joy, R.W.

    1982-09-20

    A rapidly refuelable dual cell of an electrochemical type is described wherein a single anode cooperates with two cathodes and wherein the anode has a fixed position and the cathodes are urged toward opposite faces of the anodes at constant and uniform force. The associated cathodes are automatically retractable to permit the consumed anode remains to be removed from the housing and a new anode inserted between the two cathodes.

  20. Membrane Transport Chloride Transport Across Vesicle and Cell

    E-Print Network [OSTI]

    Smith, Bradley D.

    Membrane Transport Chloride Transport Across Vesicle and Cell Membranes by Steroid-Based Receptors-established that molecules which transport cations across cell membranes (cationophores) can have potent biological effects of biological activity. Indeed, chloride transporters have direct medical potential as treatments for cystic

  1. Optimization of Fuel Cell System Operating Conditions for Fuel Cell Vehicles

    E-Print Network [OSTI]

    Zhao, Hengbing; Burke, Andy

    2008-01-01

    Optimization of Fuel Cell System Operating Conditions forOptimization of Fuel Cell System Operating Conditions forOptimization of Fuel Cell System Operating Conditions for

  2. Optimization of Fuel Cell System Operating Conditions for Fuel Cell Vehicles

    E-Print Network [OSTI]

    Zhao, Hengbing; Burke, Andy

    2008-01-01

    R.M. Moore, PEM Fuel Cell System Optimization, ProceedingsInterface of the fuel cell system optimization model Fig. 5hydrogen fuel cell vehicle; optimization model; simulation *

  3. Optimization of Fuel Cell System Operating Conditions for Fuel Cell Vehicles

    E-Print Network [OSTI]

    Zhao, Hengbing; Burke, Andy

    2008-01-01

    and cost [ 1]. Fuel cell applications in automobiles arete d M fuel cell systems for vehicle applications, Journalof the fuel cell for vehicle applications. The air supply

  4. Optimization of Fuel Cell System Operating Conditions for Fuel Cell Vehicles

    E-Print Network [OSTI]

    Zhao, Hengbing; Burke, Andy

    2008-01-01

    simulation tool for hydrogen fuel cell vehicles, Journal ofApplication on Direct Hydrogen Fuel Cell Vehicles, 2008. Accell system for direct hydrogen fuel cell vehicles Fig. 3

  5. Fuel Cell Hybrid Bus Lands at Hickam AFB: Hydrogen Fuel Cell...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hybrid Bus Lands at Hickam AFB: Hydrogen Fuel Cell & Infrastructure Technologies Program, Fuel Cell Bus Demonstration Project (Fact Sheet) Fuel Cell Hybrid Bus Lands at Hickam AFB:...

  6. Optimization of Fuel Cell System Operating Conditions for Fuel Cell Vehicles

    E-Print Network [OSTI]

    Zhao, Hengbing; Burke, Andy

    2008-01-01

    An Indirect Methanol Pem Fuel Cell System, SAE 2001, (paperof automotive PEM fuel cell stacks, SAE 2000 (paper numberParasitic Loads in Fuel Cell Vehicles, International Journal

  7. Fuel Cell Handbook (Seventh Edition)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HABFES OctoberEvanServicesAmesFourFromFuel Cell Handbook (Seventh

  8. 1986 fuel cell seminar: Program and abstracts

    SciTech Connect (OSTI)

    1986-10-01

    Ninety nine brief papers are arranged under the following session headings: gas industry's 40 kw program, solid oxide fuel cell technology, phosphoric acid fuel cell technology, molten carbonate fuel cell technology, phosphoric acid fuel cell systems, power plants technology, fuel cell power plant designs, unconventional fuels, fuel cell application and economic assessments, and plans for commerical development. The papers are processed separately for the data base. (DLC)

  9. Intra-Fuel Cell Stack Measurements of Transient Concentration Distributions

    SciTech Connect (OSTI)

    Partridge Jr, William P; Toops, Todd J; Green Jr, Johney Boyd; Armstrong, Timothy R.

    2006-01-01

    Intra-fuel-cell measurements are required to understand detailed fuel-cell chemistry and physics, validate models, optimize system design and control, and realize enhanced efficiency regimes; in comparison, conventional integrated fuel-cell supply and effluent measurements are fundamentally limited in value. Intra-reactor measurements are needed for all fuel cell types. This paper demonstrates the ability of a capillary-inlet mass spectrometer to resolve transient species distributions within operating polymer-electrolyte-membrane (PEM) fuel cells and at temperatures typical of solid-oxide fuel cells (SOFC). This is the first such demonstration of a diagnostic that is sufficiently minimally invasive as to allow measurements throughout an operating fuel cell stack. Measurements of transient water, hydrogen, oxygen and diluent concentration dynamics associated with fuel-cell load switching suggest oxygen-limited chemistry. Intra-PEM fuel cell measurements of oxygen distribution at various fuel-cell loads are used to demonstrate concentration gradients, non-uniformities, and anomalous fuel cell operation.

  10. Fuel Cells for Portable Power: 1. Introduction to DMFCs; 2. Advanced Materials and Concepts for Portable Power Fuel Cells

    SciTech Connect (OSTI)

    Zelenay, Piotr [Los Alamos National Laboratory

    2012-07-16

    Thanks to generally less stringent cost constraints, portable power fuel cells, the direct methanol fuel cell (DMFC) in particular, promise earlier market penetration than higher power polymer electrolyte fuel cells (PEFCs) for the automotive and stationary applications. However, a large-scale commercialization of DMFC-based power systems beyond niche applications already targeted by developers will depend on improvements to fuel cell performance and performance durability as well as on the reduction in cost, especially of the portable systems on the higher end of the power spectrum (100-250 W). In this part of the webinar, we will focus on the development of advanced materials (catalysts, membranes, electrode structures, and membrane electrode assemblies) and fuel cell operating concepts capable of fulfilling two key targets for portable power systems: the system cost of $5/W and overall fuel conversion efficiency of 2.0-2.5 kWh/L. Presented research will concentrate on the development of new methanol oxidation catalysts, hydrocarbon membranes with reduced methanol crossover, and improvements to component durability. Time permitted, we will also present a few highlights from the development of electrocatalysts for the oxidation of two alternative fuels for the direct-feed fuel cells: ethanol and dimethyl ether.

  11. NREL: Hydrogen and Fuel Cells Research - Fuel Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on771/6/14RecentGeospatialReliabilityWorking with UstheCells Photo of

  12. ADVANCED HYDROGEN TRANSPORT MEMBRANES FOR VISION 21 FOSSIL FUEL PLANTS

    SciTech Connect (OSTI)

    Shane E. Roark; Tony F. Sammells; Adam E. Calihman; Lyrik Y. Pitzman; Pamela M. Van Calcar; Richard A. Mackay; Tom F. Barton; Sara L. Rolfe; Richard N. Kleiner; James E. Stephan; Tim R. Armstrong; Mike J. Holmes; Aaron L. Wagner

    2001-04-30

    Eltron Research Inc., and team members, are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. This objective is being pursued using dense membranes based in part on Eltron-patented ceramic materials with a demonstrated ability for proton and electron conduction. The technical goals are being addressed by modifying single-phase and composite membrane composition and microstructure to maximize proton and electron conductivity without loss of material stability. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. During this quarter, it was demonstrated that increasing the transition metal loading in a model perovskite composition resulted in an increase in hydrogen flux. Improved flux corresponded to the emergence of additional phases in the ceramic membrane, and highest flux was achieved for a composite consisting of pseudo-cubic and rhombohedral perovskite phases. A 0.9-mm thick membrane of this material generated a hydrogen flux in excess of 0.1 mL/min/cm{sup 2}, which was approximately 35 times greater than analogs with lower transition metal levels. The dopant level and crystal structure also correlated with membrane density and coefficient of thermal expansion, but did not appear to affect grain size or shape. Additionally, preliminary ceramic-metal (cermet) composite membranes demonstrated a 10-fold increase in flux relative to analogous membranes composed of only the ceramic component. The hydrogen flux for these cermet samples corresponded to a conductivity of {approx} 10{sup -3} S/cm, which was consistent with the predicted proton conductivity of the ceramic phase. Increasing the sweep gas flow rate in test reactors was found to significantly increase hydrogen flux, as well as apparent material conductivity for all samples tested. Adding humidity to the feed gas stream produced a small increase in hydrogen flux. However, the catalyst on ceramic membrane surfaces did not affect flux, which suggested that the process was membrane-diffusion limited. Representative samples and fabrication processes were evaluated on the basis of manufacturing practicality. it was determined that optimum membrane densification occurs over a very narrow temperature range for the subject ceramics. Additionally, calcination temperatures currently employed result in powders that are difficult mill and screen. These issues must be addressed to improve large-scale fabricability.

  13. Sputter-Deposited Pt/CrN Nanoparticle PEM Fuel Cell Cathodes: Limited Proton Conductivity Through Electrode

    E-Print Network [OSTI]

    Gall, Daniel

    Sputter-Deposited Pt/CrN Nanoparticle PEM Fuel Cell Cathodes: Limited Proton Conductivity Through for proton exchange membrane PEM fuel cells. X-ray diffraction and scanning electron microscopy show manuscript received September 17, 2009. Published November 13, 2009. Proton exchange membrane PEM fuel cells

  14. Nanorod PEM Fuel Cell Cathodes with Controlled Porosity M. D. Gasda, G. A. Eisman,* and D. Gallz

    E-Print Network [OSTI]

    Gall, Daniel

    Nanorod PEM Fuel Cell Cathodes with Controlled Porosity M. D. Gasda, G. A. Eisman,* and D. Gallz as cathode electrodes in proton exchange membrane PEM fuel cells. Deposition on flat substrates yields February 4, 2010. Proton exchange membrane PEM fuel cells are promising for future automotive applications

  15. A Parametric Study of Cathode Catalyst Layer Structural Parameters on the Performance of a PEM Fuel Cell

    E-Print Network [OSTI]

    Stockie, John

    exchange membrane fuel cell (PEMFC) and how changes in its structural parameters affect performance. These results give useful guidelines for manufactures of PEMFC catalyst layers. Keywords: PEM fuel cell In a proton exchange membrane fuel cell (or PEMFC), electrical energy is generated directly through

  16. Fuel Cells Calendar | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Cells Calendar Fuel Cells Calendar Upcoming events for the Fuel Cell Technologies Office are listed below. Find past events. June 2015 < prev next > Sun Mon Tue Wed Thu Fri...

  17. Solid Oxide Fuel Cell Manufacturing Overview

    E-Print Network [OSTI]

    Solid Oxide Fuel Cell Manufacturing Overview Hydrogen and Fuel Cell Technologies Manufacturing R Reserved. 3 The Solid Oxide Fuel Cell Electrochemistry #12;Copyright © 2011 Versa Power Systems. All Rights

  18. Nanostructured Solid Oxide Fuel Cell Electrodes

    E-Print Network [OSTI]

    Sholklapper, Tal Zvi

    2007-01-01

    post-Doping of Solid Oxide Fuel Cell Cathodes,? P.h.D.and Technology of Ceramic Fuel Cells, p. 209, Elsevier, NewI. Birss, in Solid Oxide Fuel Cells (SOFC IX), S. C. Singhal

  19. Aalborg Universitet HTPEM Fuel Cell Impedance

    E-Print Network [OSTI]

    Berning, Torsten

    Aalborg Universitet HTPEM Fuel Cell Impedance Vang, Jakob Rabjerg Publication date: 2014 Document Citation for published version (APA): Vang, J. R. (2014). HTPEM Fuel Cell Impedance: Mechanistic Modelling #12;HTPEM fuel cell impedance - Mechanistic modelling and experimental characterisation Jakob Rabjerg

  20. Solar-Hydrogen Fuel-Cell Vehicles

    E-Print Network [OSTI]

    DeLuchi, Mark A.; Ogden, Joan M.

    1993-01-01

    264. DeLuchi M. A. (1992). Hydrogen Fuel-Cell Vehicles. Re-or regulation. Solar-Hydrogen Fuel-Cell Vehicles MarkA.Solar-Hydrogen Fuel-Cell Mark Ao DeLuchi Joan M. Ogden

  1. Microfluidic Microbial Fuel Cells for Microstructure Interrogations

    E-Print Network [OSTI]

    Parra, Erika Andrea

    2010-01-01

    5 FutureWork 5.1 Microfluidic Microbial Fuel Cell ContinuedSediment microbial fuel cells demonstrating marine (left)Model of hydrogen fuel cell kinetic losses including

  2. DOE Hydrogen and Fuel Cells Program Record 14014: Fuel Cell System...

    Office of Environmental Management (EM)

    Hydrogen and Fuel Cells Program Record 14014: Fuel Cell System Cost - 2014 DOE Hydrogen and Fuel Cells Program Record 14014: Fuel Cell System Cost - 2014 Program record 14014 from...

  3. Fuel Cells in Telecommunications | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Cells in Telecommunications Fuel Cells in Telecommunications Presentation by Joe Blanchard, ReliOn, at the Technology Transition Corporation and U.S. Department of Energy...

  4. Characterization of Fuel-Cell Diffusion Media

    E-Print Network [OSTI]

    Gunterman, Haluna Penelope Frances

    2011-01-01

    Characterization of Fuel-Cell Diffusion Media by HalunaFall 2011 Abstract Characterization of Fuel-Cell Diffusionpredictive capabilities. Characterization of DM and their

  5. Fuel Cell Power Plant Experience Naval Applications

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    reliable, efficient, ultra-clean Fuel Cell Power Plant Experience Naval Applications US Department of Energy Office of Naval Research Shipboard Fuel Cell Workshop Washington, DC...

  6. Fuel Cell School Buses: Report to Congress

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Activities, Progress, and Plans: Report to Congress ii December 2008 Fuel Cell School Buses Report to Congress Fuel Cell School Buses: Report to Congress Preface This Department of...

  7. Webinar: National Fuel Cell Technology Evaluation Center

    Broader source: Energy.gov [DOE]

    Video recording and text version of the Fuel Cell Technologies Office webinar titled "National Fuel Cell Technology Evaluation Center (NFCTEC)," originally presented on March 11, 2014.

  8. Characterization of Fuel-Cell Diffusion Media

    E-Print Network [OSTI]

    Gunterman, Haluna Penelope Frances

    2011-01-01

    to take up or eject fluid. Most fuel-cell materials arethe wetting fluid. Therefore, P C for fuel-cell systems is

  9. Pacific Fuel Cell Corporation | Open Energy Information

    Open Energy Info (EERE)

    Fuel Cell Corporation Jump to: navigation, search Name: Pacific Fuel Cell Corporation Address: 26985 Lakeland Blvd. Place: Euclid, Ohio Zip: 44132 Sector: Buildings, Efficiency,...

  10. Fuel Cell Technologies Office Information Resources | Department...

    Energy Savers [EERE]

    Information Resources Fuel Cell Technologies Office Information Resources Learn about hydrogen and fuel cells, find publications and technical information, view and download...

  11. Fuel Cell Animation- Chemical Process (Text Version)

    Broader source: Energy.gov [DOE]

    This text version of the fuel cell animation demonstrates how a fuel cell uses hydrogen to produce electricity, with only water and heat as byproducts.

  12. Hydrogen, Fuel Cells and Infrastructure Technologies Program...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen, Fuel Cells and Infrastructure Technologies Program: 2002 Annual Progress Report Hydrogen, Fuel Cells and Infrastructure Technologies Program: 2002 Annual Progress Report...

  13. Hydrogen, Fuel Cells and Infrastructure Technologies Program...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen, Fuel Cells and Infrastructure Technologies Program FY2003 Merit Review and Peer Evaluation Report Hydrogen, Fuel Cells and Infrastructure Technologies Program FY2003...

  14. Fuel cell with internal flow control

    DOE Patents [OSTI]

    Haltiner, Jr., Karl J. (Fairport, NY); Venkiteswaran, Arun (Karnataka, IN)

    2012-06-12

    A fuel cell stack is provided with a plurality of fuel cell cassettes where each fuel cell cassette has a fuel cell with an anode and cathode. The fuel cell stack includes an anode supply chimney for supplying fuel to the anode of each fuel cell cassette, an anode return chimney for removing anode exhaust from the anode of each fuel cell cassette, a cathode supply chimney for supplying oxidant to the cathode of each fuel cell cassette, and a cathode return chimney for removing cathode exhaust from the cathode of each fuel cell cassette. A first fuel cell cassette includes a flow control member disposed between the anode supply chimney and the anode return chimney or between the cathode supply chimney and the cathode return chimney such that the flow control member provides a flow restriction different from at least one other fuel cell cassettes.

  15. Ion transport through cell membrane channels

    E-Print Network [OSTI]

    Jan Gomulkiewicz; Jacek Miekisz; Stanislaw Miekisz

    2007-06-05

    We discuss various models of ion transport through cell membrane channels. Recent experimental data shows that sizes of ion channels are compared to those of ions and that only few ions may be simultaneously in any single channel. Theoretical description of ion transport in such channels should therefore take into account interactions between ions and between ions and channel proteins. This is not satisfied by macroscopic continuum models based on Poisson-Nernst-Planck equations. More realistic descriptions of ion transport are offered by microscopic Brownian and molecular dynamics. One should also take into account a dynamical character of the channel structure. This is not yet addressed in the literature

  16. Membrane Purification Cell for Aluminum Recycling

    SciTech Connect (OSTI)

    David DeYoung; James Wiswall; Cong Wang

    2011-11-29

    Recycling mixed aluminum scrap usually requires adding primary aluminum to the scrap stream as a diluent to reduce the concentration of non-aluminum constituents used in aluminum alloys. Since primary aluminum production requires approximately 10 times more energy than melting scrap, the bulk of the energy and carbon dioxide emissions for recycling are associated with using primary aluminum as a diluent. Eliminating the need for using primary aluminum as a diluent would dramatically reduce energy requirements, decrease carbon dioxide emissions, and increase scrap utilization in recycling. Electrorefining can be used to extract pure aluminum from mixed scrap. Some example applications include producing primary grade aluminum from specific scrap streams such as consumer packaging and mixed alloy saw chips, and recycling multi-alloy products such as brazing sheet. Electrorefining can also be used to extract valuable alloying elements such as Li from Al-Li mixed scrap. This project was aimed at developing an electrorefining process for purifying aluminum to reduce energy consumption and emissions by 75% compared to conventional technology. An electrolytic molten aluminum purification process, utilizing a horizontal membrane cell anode, was designed, constructed, operated and validated. The electrorefining technology could also be used to produce ultra-high purity aluminum for advanced materials applications. The technical objectives for this project were to: - Validate the membrane cell concept with a lab-scale electrorefining cell; - Determine if previously identified voltage increase issue for chloride electrolytes holds for a fluoride-based electrolyte system; - Assess the probability that voltage change issues can be solved; and - Conduct a market and economic analysis to assess commercial feasibility. The process was tested using three different binary alloy compositions (Al-2.0 wt.% Cu, Al-4.7 wt.% Si, Al-0.6 wt.% Fe) and a brazing sheet scrap composition (Al-2.8 wt.% Si-0.7 wt.% Fe-0.8 wt.% Mn),. Purification factors (defined as the initial impurity concentration divided by the final impurity concentration) of greater than 20 were achieved for silicon, iron, copper, and manganese. Cell performance was measured using its current and voltage characteristics and composition analysis of the anode, cathode, and electrolytes. The various cells were autopsied as part of the study. Three electrolyte systems tested were: LiCl-10 wt. % AlCl3, LiCl-10 wt. % AlCl3-5 wt.% AlF3 and LiF-10 wt.% AlF3. An extended four-day run with the LiCl-10 wt.% AlCl3-5 wt.% AlF3 electrolyte system was stable for the entire duration of the experiment, running at energy requirements about one third of the Hoopes and the conventional Hall-Heroult process. Three different anode membranes were investigated with respect to their purification performance and survivability: a woven graphite cloth with 0.05 cm nominal thickness & > 90 % porosity, a drilled rigid membrane with nominal porosity of 33%, and another drilled rigid graphite membrane with increased thickness. The latter rigid drilled graphite was selected as the most promising membrane design. The economic viability of the membrane cell to purify scrap is sensitive to primary & scrap aluminum prices, and the cost of electricity. In particular, it is sensitive to the differential between scrap and primary aluminum price which is highly variable and dependent on the scrap source. In order to be economically viable, any scrap post-processing technology in the U.S. market must have a total operating cost well below the scrap price differential of $0.20-$0.40 per lb to the London Metal Exchange (LME), a margin of 65%-85% of the LME price. The cost to operate the membrane cell is estimated to be < $0.24/lb of purified aluminum. The energy cost is estimated to be $0.05/lb of purified aluminum with the remaining costs being repair and maintenance, electrolyte, labor, taxes and depreciation. The bench-scale work on membrane purification cell process has demonstrated technological advantages and subs

  17. Direct Carbon Fuel Cell System Utilizing Solid Carbonaceous Fuels

    SciTech Connect (OSTI)

    Turgut Gur

    2010-04-30

    This 1-year project has achieved most of its objective and successfully demonstrated the viability of the fluidized bed direct carbon fuel cell (FB-DCFC) approach under development by Direct Carbon technologies, LLC, that utilizes solid carbonaceous fuels for power generation. This unique electrochemical technology offers high conversion efficiencies, produces proportionately less CO{sub 2} in capture-ready form, and does not consume or require water for gasification. FB-DCFC employs a specialized solid oxide fuel cell (SOFC) arrangement coupled to a Boudouard gasifier where the solid fuel particles are fluidized and reacted by the anode recycle gas CO{sub 2}. The resulting CO is electrochemically oxidized at the anode. Anode supported SOFC structures employed a porous Ni cermet anode layer, a dense yttria stabilized zirconia membrane, and a mixed conducting porous perovskite cathode film. Several kinds of untreated solid fuels (carbon and coal) were tested in bench scale FBDCFC prototypes for electrochemical performance and stability testing. Single cells of tubular geometry with active areas up to 24 cm{sup 2} were fabricated. The cells achieved high power densities up to 450 mW/cm{sup 2} at 850 C using a low sulfur Alaska coal char. This represents the highest power density reported in the open literature for coal based DCFC. Similarly, power densities up to 175 mW/cm{sup 2} at 850 C were demonstrated with carbon. Electrical conversion efficiencies for coal char were experimentally determined to be 48%. Long-term stability of cell performance was measured under galvanostatic conditions for 375 hours in CO with no degradation whatsoever, indicating that carbon deposition (or coking) does not pose any problems. Similar cell stability results were obtained in coal char tested for 24 hours under galvanostatic conditions with no sign of sulfur poisoning. Moreover, a 50-cell planar stack targeted for 1 kW output was fabricated and tested in 95% CO (balance CO{sub 2}) that simulates the composition of the coal syngas. At 800 C, the stack achieved a power density of 1176 W, which represents the largest power level demonstrated for CO in the literature. Although the FB-DCFC performance results obtained in this project were definitely encouraging and promising for practical applications, DCFC approaches pose significant technical challenges that are specific to the particular DCFC scheme employed. Long term impact of coal contaminants, particularly sulfur, on the stability of cell components and cell performance is a critically important issue. Effective current collection in large area cells is another challenge. Lack of kinetic information on the Boudouard reactivity of wide ranging solid fuels, including various coals and biomass, necessitates empirical determination of such reaction parameters that will slow down development efforts. Scale up issues will also pose challenges during development of practical FB-DCFC prototypes for testing and validation. To overcome some of the more fundamental problems, initiation of federal support for DCFC is critically important for advancing and developing this exciting and promising technology for third generation electricity generation from coal, biomass and other solid fuels including waste.

  18. ADVANCED HYDROGEN TRANSPORT MEMBRANES FOR VISION 21 FOSSIL FUEL PLANTS

    SciTech Connect (OSTI)

    Shane E. Roark; Anthony F. Sammells; Richard Mackay; Stewart R. Schesnack; Scott R. Morrison; Thomas F. Barton; Sara L. Rolfe; U. Balachandran; Richard N. Kleiner; James E. Stephan; Frank E. Anderson; Aaron L. Wagner; Jon P. Wagner

    2003-10-30

    Eltron Research Inc. and team members CoorsTek, Sued Chemie, Argonne National Laboratory, and NORAM are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative, which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. Over the past 12 months, this project has focused on four basic categories of dense membranes: (1) mixed conducting ceramic/ceramic composites, (2) mixed conducting ceramic/metal (cermet) composites, (3) cermets with hydrogen permeable metals, and (4) layered composites containing hydrogen permeable alloys. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. The ceramic/ceramic composites demonstrate the lowest hydrogen permeation rates, with a maximum of approximately 0.1 mL/min/cm{sup 2} for 0.5-mm thick membranes at 800 to 950 C. Under equivalent conditions, cermets achieve a hydrogen permeation rate near 1 mL/min/cm{sup 2}, and the metal phase also improves structural stability and surface catalysis for hydrogen dissociation. Furthermore, if metals with high hydrogen permeability are used in cermets, permeation rates near 4 mL/min/cm{sup 2} are achievable with relatively thick membranes. Layered composite membranes have by far the highest permeation rates with a maximum flux in excess of 200 mL {center_dot} min{sup -1} {center_dot} cm{sup -2}. Moreover, these permeation rates were achieved at a total pressure differential across the membrane of 450 psi. Based on these results, effort during the next year will focus on this category of membranes. This report contains long-term hydrogen permeation data over eight-months of continuous operation, and permeation results as a function of operating conditions at high pressure for layered composite membranes. Additional progress with cermet and thin film membranes also is presented.

  19. ADVANCED HYDROGEN TRANSPORT MEMBRANES FOR VISION 21 FOSSIL FUEL PLANTS

    SciTech Connect (OSTI)

    Shane E. Roark; Anthony F. Sammells; Richard A. Mackay; Lyrik Y. Pitzman; Thomas A. Zirbel; Stewart R. Schesnack; Thomas F. Barton; Sara L. Rolfe; U. (Balu) Balachandran; Richard N. Kleiner; James E. Stephan; Frank E. Anderson; Aaron L. Wagner; Jon P. Wagner

    2003-01-30

    Eltron Research Inc., and team members CoorsTek, Sued Chemie, and Argonne National Laboratory are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. This objective is being pursued using dense membranes based in part on Eltron-patented ceramic materials with a demonstrated ability for proton and electron conduction. The technical goals are being addressed by modifying composite membrane composition and microstructure to maximize hydrogen permeation without loss of material stability. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. During this quarter, a composite metal membrane based on an inexpensive hydrogen permeable metal achieved permeation rates in excess of 25 mL/min/cm{sup 2}. Preliminary attempts to incorporate this metal into a cermet were successful, and a thick cermet membrane (0.83 mm) with 40 vol.% metal phase achieved a permeation rate of nearly 0.4 mL/min/cm{sup 2}. Increasing the metal phase content and decreasing membrane thickness should significantly increase permeation, while maintaining the benefits derived from cermets. Two-phase ceramic/ceramic composite membranes had low hydrogen permeability, likely due to interdiffusion of constituents between the phases. However, these materials did demonstrate high resistance to corrosion, and might be good candidates for other composite membranes. Temperature-programmed reduction measurements indicated that model cermet materials absorbed 2.5 times as much hydrogen than the pure ceramic analogs. This characteristic, in addition to higher electron conductivity, likely explains the relatively high permeation for these cermets. Incorporation of catalysts with ceramics and cermets increased hydrogen uptake by 800 to more than 900%. Finally, new high-pressure seals were developed for cermet membranes that maintained a pressure differential of 250 psi. This result indicated that the approach for high-pressure seal development could be adapted for a range of compositions. Other items discussed in this report include mechanical testing, new proton conducting ceramics, supported thin films, and alkane to olefin conversion.

  20. Fuel Cell Distributed Power Package Unit: Fuel Processing Based On

    E-Print Network [OSTI]

    have been metAll milestones have been met #12;4 Autothermal Cyclic Reforming for PEM Fuel Cell CH4 + H2Fuel Cell Distributed Power Package Unit: Fuel Processing Based On Autothermal Cyclic Reforming-2000) Bread-Board Fuel Processor Development DOE (2001-3) Integrated Fuel Processor Development CEC/ARB (2002

  1. ADVANCED HYDROGEN TRANSPORT MEMBRANES FOR VISION 21 FOSSIL FUEL PLANTS

    SciTech Connect (OSTI)

    Shane E. Roark; Tony F. Sammells; Adam Calihman; Andy Girard; Pamela M. Van Calcar; Richard Mackay; Tom Barton; Sara Rolfe

    2001-01-30

    Eltron Research Inc., and team members CoorsTek, McDermott Technology, Inc., Sued Chemie, Argonne National Laboratory, and Oak Ridge National Laboratory are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This objective is being pursued using dense membranes based in part on Eltron-patented ceramic materials with a demonstrated ability for proton and electron conduction. The technical goals are being addressed by modifying single-phase and composite membrane composition and microstructure to maximize proton and electron conductivity without loss of material stability. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. The proposed technology addresses the DOE Vision 21 initiative in two ways. First, this process offers a relatively inexpensive solution for pure hydrogen separation that can be easily incorporated into Vision 21 fossil fuel plants. Second, this process could reduce the cost of hydrogen, which is a clean burning fuel under increasing demand as supporting technologies are developed for hydrogen utilization and storage. Additional motivation for this project arises from the potential of this technology for other applications. Membranes testing during this reporting period were greater than 1 mm thick and had the general perovskite composition AB{sub 1-x}B'{sub x}O{sub 3-{delta}}, where 0.05 {<=} x {<=} 0.3. These materials demonstrated hydrogen separation rates between 1 and 2 mL/min/cm{sup 2}, which represents roughly 20% of the target goal for membranes of this thickness. The sintered membranes were greater than 95% dense, but the phase purity decreased with increasing dopant concentration. The quantity of dopant incorporated into the perovskite phase was roughly constant, with excess dopant forming an additional phase. Composite materials with distinct ceramic and metallic phases, and thin film perovskites (100 {micro}m) also were successfully prepared, but have not yet been tested for hydrogen transport. Finally, porous platinum was identified as a excellent catalyst for evaluation of membrane materials, however, lower cost nickel catalyst systems are being developed.

  2. FUEL CELL SYSTEM ECONOMICS: COMPARING THE COSTS OF GENERATING POWER WITH STATIONARY

    E-Print Network [OSTI]

    Kammen, Daniel M.

    , University of California, 4152 Etcheverry Hall, Berkeley, CA 94720, USA Abstract This investigation examines the economics of producing electricity from proton-exchange membrane (PEM) fuel cell systems under various of natural gas, electricity prices, fuel cell and reformer system costs, and fuel cell system durability

  3. A DC-DC Converter-Based PEM Fuel Cell System Emulator

    E-Print Network [OSTI]

    Boyer, Edmond

    A DC-DC Converter-Based PEM Fuel Cell System Emulator Daoud Rezzak, Farid Khoucha, Mohamed Benbouzid, Abdelaziz Kheloui and Abdeslam Mamoune Abstract--The Proton Exchange Membrane Fuel Cell (PEMFC power supplies. Fuel cell systems are characterized by high costs and complex auxiliary devices

  4. EFFECT OF PTFE ON THERMAL CONDUCTIVITY OF GAS DIFFUSION LAYERS OF PEM FUEL CELLS

    E-Print Network [OSTI]

    Bahrami, Majid

    The efficiency and performance of proton exchange membrane fuel cells (PEMFCs) depends heavily on the heat, the added PTFE can change the thermal resistance of GDLs and, hence, affects the fuel cell heat managementEFFECT OF PTFE ON THERMAL CONDUCTIVITY OF GAS DIFFUSION LAYERS OF PEM FUEL CELLS Hamidreza

  5. Pt/CARBON XEROGEL CATALYSTS FOR PEM FUEL CELLS Nathalie JOBa

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Pt/CARBON XEROGEL CATALYSTS FOR PEM FUEL CELLS Nathalie JOBa , Frédéric MAILLARDb , Jean of proton exchange membrane (PEM) fuel cells in order to decrease the mass transport limitations The catalytic layer configuration is a key-element in the design of PEM fuel cells [1]. Indeed, besides

  6. Fuel Cells prognostics using Echo State Network S. Morando1,2,3

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Fuel Cells prognostics using Echo State Network S. Morando1,2,3 , S. Jemei1,2 , R. Gouriveau2,3 , N department / ENSMM Abstract-- One remaining technological bottleneck to develop industrial Fuel Cell (FC Life of a Proton Exchange Membrane Fuel Cell. Developments emphasize on the prediction of the mean

  7. Preparation of Solid Alkaline Fuel Cell Binders Based on Fluorinated Poly(diallyldimethylammonium chloride)s

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Preparation of Solid Alkaline Fuel Cell Binders Based on Fluorinated Poly to be used in a Solid Alkaline Fuel Cell (SAFC) needs to (i) be insoluble in both aqueous solutions,10% > 320 °C). When used in a fuel cell as a binder in the membrane-electrodes assembly (MEA

  8. A non-isothermal PEM fuel cell model including two water transport mechanisms in the

    E-Print Network [OSTI]

    Münster, Westfälische Wilhelms-Universität

    A non-isothermal PEM fuel cell model including two water transport mechanisms in the membrane K Freiburg Germany A dynamic two-phase flow model for proton exchange mem- brane (PEM) fuel cells and the species concentrations. In order to describe the charge transport in the fuel cell the Poisson equations

  9. Three-Dimensional Computational Analysis of Transport Phenomena in a PEM Fuel Cell

    E-Print Network [OSTI]

    Victoria, University of

    Three-Dimensional Computational Analysis of Transport Phenomena in a PEM Fuel Cell by Torsten or other means, without permission of the author. #12;Supervisor: Dr. N. Djilali Abstract Fuel cells-isothermal computational model of a proton exchange membrane fuel cell (PEMFC). The model was developed to improve

  10. Science Highlight December 2010 Electrochemical Surface Science: Hard X-rays Probe Fuel Cell Model Catalyst

    E-Print Network [OSTI]

    Wechsler, Risa H.

    Science Highlight ­ December 2010 Electrochemical Surface Science: Hard X-rays Probe Fuel Cell. Proton exchange membrane fuel cells (PEMFCs) are promising power sources since they can generate distribution network. Large-scale deployment of fuel cells, however, has been hampered by cost and performance

  11. Development of high-power electrodes for a liquid-feed direct methanol fuel cell

    E-Print Network [OSTI]

    Development of high-power electrodes for a liquid-feed direct methanol fuel cell C. Lim, C.Y. Wang for a liquid-feed direct methanol fuel cell (DMFC) were fabricated by using a novel method of modi®ed Na.V. All rights reserved. Keywords: Direct methanol fuel cells; Membrane-electrode assembly (MEA); Polymer

  12. Proceedings of FUELCELL2006 The 4th International Conference on FUEL CELL SCIENCE, ENGINEERING and TECHNOLOGY

    E-Print Network [OSTI]

    Yao, Bin

    Proceedings of FUELCELL2006 The 4th International Conference on FUEL CELL SCIENCE, ENGINEERING and TECHNOLOGY June 19-21, 2006, Irvine, CA FUELCELL2006-97067 MODELING AND SIMULATION OF A MODERN PEM FUEL CELL and advances in hydrogen/air Proton Ex- change Membrane Fuel Cells (PEMFC) are incorporated into a dynamic

  13. Heat and Mass Transfer Modeling of Dry Gases in the Cathode of PEM Fuel Cells

    E-Print Network [OSTI]

    Stockie, John

    Heat and Mass Transfer Modeling of Dry Gases in the Cathode of PEM Fuel Cells M.J. Kermani1 J and N2, through the cathode of a proton exchange membrane (PEM) fuel cell is studied numerically) an energy equation, written in a form that has enthalpy as the dependent variable. Keywords: PEM fuel cells

  14. A SHARP INTERFACE REDUCTION FOR MULTIPHASE TRANSPORT IN A POROUS FUEL CELL ELECTRODE

    E-Print Network [OSTI]

    Stockie, John

    A SHARP INTERFACE REDUCTION FOR MULTIPHASE TRANSPORT IN A POROUS FUEL CELL ELECTRODE KEITH exchange membrane fuel cell is a highly porous material which acts to distribute reactant gases uniformly perturbation, fuel cell electrodes, free surface. AMS subject classifications. 35B40, 35K55, 76R99, 76S05 1

  15. PEM fuel cell monitoring system

    DOE Patents [OSTI]

    Meltser, M.A.; Grot, S.A.

    1998-06-09

    Method and apparatus are disclosed for monitoring the performance of H{sub 2}--O{sub 2} PEM fuel cells. Outputs from a cell/stack voltage monitor and a cathode exhaust gas H{sub 2} sensor are corrected for stack operating conditions, and then compared to predetermined levels of acceptability. If certain unacceptable conditions coexist, an operator is alerted and/or corrective measures are automatically undertaken. 2 figs.

  16. PEM fuel cell monitoring system

    DOE Patents [OSTI]

    Meltser, Mark Alexander (Pittsford, NY); Grot, Stephen Andreas (West Henrietta, NY)

    1998-01-01

    Method and apparatus for monitoring the performance of H.sub.2 --O.sub.2 PEM fuel cells. Outputs from a cell/stack voltage monitor and a cathode exhaust gas H.sub.2 sensor are corrected for stack operating conditions, and then compared to predetermined levels of acceptability. If certain unacceptable conditions coexist, an operator is alerted and/or corrective measures are automatically undertaken.

  17. Electrochemical impedance study of electrode-membrane assemblies in PEM fuel cells. 1: Electro-oxidation of H{sub 2} and H{sub 2}/CO mixtures on Pt-based gas-diffusion electrodes

    SciTech Connect (OSTI)

    Ciureanu, M.; Wang, H.

    1999-11-01

    In situ EIS data are presented on the anodic process in proton exchange membrane (PEM) fuel cells and the influence of CO poisoning of the Pt gas-diffusion electrodes (GDE) is examined. A characterization of the effects of interfacial kinetics in determining polarization losses in the presence of CO is performed by comparing impedance patterns obtained for cells of the type H{sub 2}/H{sub 2} with H{sub 2}/(H{sub 2} + CO). The impedance spectrum of the poisoned electrode is strongly dependent on potential and on the CO concentration in the gas feed. In the range between 0 and 0.3 V the impedance increases rapidly with the potential, while at potentials higher than 0.3 V a pseudoinductive behavior is observed, in which a positive loop at higher frequencies is accompanied by a low frequency (LF) loop in the fourth quadrant. The latter was assigned to a new rate-determining process, the oxidation of CO{sub ads} by Pt-H{sub 2}O{sub ads}. As a critical potential V{sub crit} is attained, the diameters of the two loops become almost equal and the LF limit of the impedance (R{sub o}) approaches the value for unpoisoned electrode, showing that the activity of the electrode activity has been restored. The value of V{sub crit} is 0.43 and 0.58 V for electrodes poisoned with 100 ppm and 2% CO, respectively. At very high potentials, where the oxidizing species are Pt-OH{sub ads}, the impedance pattern is reserved to the second and third quadrants. Stripping voltammetry and polarization curves recorded in situ, are used to support the conclusions obtained from impedance measurements.

  18. Evaluation of Stationary Fuel Cell Deployments, Costs, and Fuels (Presentation)

    SciTech Connect (OSTI)

    Ainscough, C.; Kurtz, J.; Peters, M.; Saur, G.

    2013-10-01

    This presentation summarizes NREL's technology validation of stationary fuel cell systems and presents data on number of deployments, system costs, and fuel types.

  19. ADVANCED HYDROGEN TRANSPORT MEMBRANES FOR VISION 21 FOSSIL FUEL PLANTS

    SciTech Connect (OSTI)

    Shane E. Roark; Anthony F. Sammells; Richard A. Mackay; Lyrik Y. Pitzman; Thomas A. Zirbel; Thomas F. Barton; Sara L. Rolfe; U. (Balu) Balachandran; Richard N. Kleiner; James E. Stephan; Frank E. Anderson; George Farthing; Dan Rowley; Tim R. Armstrong; R.D. Carneim; P.F. Becher; C-H. Hsueh; Aaron L. Wagner; Jon P. Wagner

    2002-04-30

    Eltron Research Inc., and team members CoorsTek, McDermott Technology, inc., Sued Chemie, Argonne National Laboratory, and Oak Ridge National Laboratory are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. This objective is being pursued using dense membranes based in part on Eltron-patented ceramic materials with a demonstrated ability for proton and electron conduction. The technical goals are being addressed by modifying single-phase and composite membrane composition and microstructure to maximize proton and electron conductivity without loss of material stability. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur.

  20. Corrosion resistant PEM fuel cell

    DOE Patents [OSTI]

    Fronk, Matthew Howard (Honeoye Falls, NY); Borup, Rodney Lynn (East Rochester, NY); Hulett, Jay S. (Rochester, NY); Brady, Brian K. (North Chili, NY); Cunningham, Kevin M. (Romeo, MI)

    2002-01-01

    A PEM fuel cell having electrical contact elements comprising a corrosion-susceptible substrate metal coated with an electrically conductive, corrosion-resistant polymer containing a plurality of electrically conductive, corrosion-resistant filler particles. The substrate may have an oxidizable metal first layer (e.g., stainless steel) underlying the polymer coating.