National Library of Energy BETA

Sample records for melter thermal treatment

  1. EA-0821: Operation of the Glass Melter Thermal Treatment Unit at the U.S. Department of Energy's Mound Plant, Miamisburg, Ohio

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of a proposal to use an existing glass melter thermal treatment unit (also known as a Penberthy Pyro-Converter joule-heated glass furnace) for the...

  2. Advanced Mixed Waste Treatment Project melter system preliminary design technical review meeting

    SciTech Connect (OSTI)

    Eddy, T.L.; Raivo, B.D.; Soelberg, N.R.; Wiersholm, O.

    1995-02-01

    The Idaho National Engineering Laboratory Advanced Mixed Waste Treatment Project sponsored a plasma are melter technical design review meeting to evaluate high-temperature melter system configurations for processing heterogeneous alpha-contaminated low-level radioactive waste (ALLW). Thermal processing experts representing Department of Energy contractors, the Environmental Protection Agency, and private sector companies participated in the review. The participants discussed issues and evaluated alternative configurations for three areas of the melter system design: plasma torch melters and graphite arc melters, offgas treatment options, and overall system configuration considerations. The Technical Advisory Committee for the review concluded that graphite arc melters are preferred over plasma torch melters for processing ALLW. Initiating involvement of stakeholders was considered essential at this stage of the design. For the offgas treatment system, the advisory committee raised the question whether to a use wet-dry or a dry-wet system. The committee recommended that the waste stream characterization, feed preparation, and the control system are essential design tasks for the high-temperature melter treatment system. The participants strongly recommended that a complete melter treatment system be assembled to conduct tests with nonradioactive surrogate waste material. A nonradioactive test bed would allow for inexpensive design and operational changes prior to assembling a system for radioactive waste treatment operations.

  3. THERMAL ANALYSIS OF WASTE GLASS MELTER FEEDS Pavel Hrma,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    THERMAL ANALYSIS OF WASTE GLASS MELTER FEEDS Pavel Hrma, 1,2 David A. Pierce, 2 Richard Pokorn 3 1 Division of Advanced Nuclear Engineering, Pohang University of Science and...

  4. THERMAL ANALYSIS OF WASTE GLASS MELTER FEED Pavel Hrma,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    THERMAL ANALYSIS OF WASTE GLASS MELTER FEED Pavel Hrma, (a,b) David A. Pierce, (b) Richard Pokorn (b,c) (a) Division of Advanced Nuclear Engineering, Pohang University of Science...

  5. Thermal Cycling on Fatigue Failure of the Plutonium Vitrification Melter

    SciTech Connect (OSTI)

    Jordan, Jeffrey; Gorczyca, Jennifer

    2009-02-11

    One method for disposition of excess plutonium is vitrification into cylindrical wasteforms. Due to the hazards of working with plutonium, the vitrification process must be carried out remotely in a shielded environment. Thus, the equipment must be easily maintained. With their simple design, induction melters satisfy this criterion, making them ideal candidates for plutonium vitrification. However, due to repeated heating and cooling cycles and differences in coefficients of thermal expansion of contacting materials fatigue failure of the induction melter is of concern. Due to the cost of the melter, the number of cycles to failure is critical. This paper presents a method for determining the cycles to failure for an induction melter by using the results from thermal and structural analyses as input to a fatigue failure model.

  6. Determination of temperature-dependent heat conductivity and thermal diffusivity of waste glass melter feed

    SciTech Connect (OSTI)

    Pokorny, Richard; Rice, Jarrett A.; Schweiger, Michael J.; Hrma, Pavel R.

    2013-06-01

    The cold cap is a layer of reacting glass batch floating on the surface of melt in an all-electric continuous glass melter. The heat needed for the conversion of the melter feed to molten glass must be transferred to and through the cold cap. Since the heat flux into the cold cap determines the rate of melting, the heat conductivity is a key property of the reacting feed. We designed an experimental setup consisting of a large cylindrical crucible with an assembly of thermocouples that monitors the evolution of the temperature field while the crucible is heated at a constant rate. Then we used two methods to calculate the heat conductivity and thermal diffusivity of the reacting feed: the approximation of the temperature field by polynomial functions and the finite-volume method coupled with least-squares analysis. Up to 680°C, the heat conductivity of the reacting melter feed was represented by a linear function of temperature.

  7. Determination of heat conductivity and thermal diffusivity of waste glass melter feed: Extension to high temperatures

    SciTech Connect (OSTI)

    Rice, Jarrett A. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Pokorny, Richard [Inst. of Chemical Technology, Prague (Czech Republic); Schweiger, Michael J. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Hrma, Pavel R. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Pohang Univ. of Science and Technology (Korea, Republic of)

    2014-06-01

    The heat conductivity ({lambda}) and the thermal diffusivity (a) of reacting glass batch, or melter feed, control the heat flux into and within the cold cap, a layer of reacting material floating on the pool of molten glass in an all-electric continuous waste glass melter. After previously estimating {lambda} of melter feed at temperatures up to 680 deg C, we focus in this work on the {lambda}(T) function at T > 680 deg C, at which the feed material becomes foamy. We used a customized experimental setup consisting of a large cylindrical crucible with an assembly of thermocouples, which monitored the evolution of the temperature field while the crucible with feed was heated at a constant rate from room temperature up to 1100°C. Approximating measured temperature profiles by polynomial functions, we used the heat transfer equation to estimate the {lambda}(T) approximation function, which we subsequently optimized using the finite-volume method combined with least-squares analysis. The heat conductivity increased as the temperature increased until the feed began to expand into foam, at which point the conductivity dropped. It began to increase again as the foam turned into a bubble-free glass melt. We discuss the implications of this behavior for the mathematical modeling of the cold cap.

  8. The integrated melter off-gas treatment systems at the West Valley Demonstration Project

    SciTech Connect (OSTI)

    Vance, R.F.

    1991-12-01

    The West Valley Demonstration project was established by an act of Congress in 1980 to solidify the high level radioactive liquid wastes produced from operation of the Western New York Nuclear Services Center from 1966 to 1972. The waste will be solidified as borosilicate glass. This report describes the functions, the controlling design criteria, and the resulting design of the melter off-gas treatment systems.

  9. Melter Dismantlement

    SciTech Connect (OSTI)

    Richardson, BS

    2000-10-01

    The U.S. Department of Energy (DOE) has been utilizing vitrification processes to convert high-level radioactive waste forms into a stable glass for disposal in waste repositories. Vitrification facilities at the Savannah River Site (SRS) and at the West Valley Demonstration Project (WVDP) are converting liquid high level waste (HLW) by combining it with a glass-forming media to form a borosilicate glass, which will ensure safe long-term storage. Large, slurry fed melters, which are utilized for this process, were anticipated to have a finite life, on the order of two to three years, at which time they would have to be replaced using remote methods, due to the high radiation fields. In actuality the melters useable life span has, to date, have exceeded original life span estimates. Initial plans called for the removal of failed melters by placing the melter assembly into a container and storing in a concrete vault on the vitrification plant site pending size reduction, segregation, containerization, and shipment to appropriate storage facilities. Separate facilities for the processing of the failed melters currently do not exist. Options for handling these melters include (1) locating a facility to conduct the size reduction, characterization, and containerization as originally planned; (2) long-term storage or disposal of the complete melter assembly; and (3) attempting to refurbish the melter and to reuse the melter assembly. The focus of this report is to look at methods and issues pertinent to size reduction and/or melter refurbishment. In particular, removal of glass as a part of a refurbishment or for the purposes of reducing contamination levels (allowing for disposal of a greater proportion of the melter as low level waste) will be addressed.

  10. A JOULE-HEATED MELTER TECHNOLOGY FOR THE TREATMENT AND IMMOBILIZATION OF LOW-ACTIVITY WASTE

    SciTech Connect (OSTI)

    KELLY SE

    2011-04-07

    This report is one of four reports written to provide background information regarding immobilization technologies remaining under consideration for supplemental immobilization of Hanford's low-activity waste. This paper provides the reader a general understanding of joule-heated ceramic lined melters and their application to Hanford's low-activity waste.

  11. Thermal treatment wall

    DOE Patents [OSTI]

    Aines, Roger D. (Livermore, CA); Newmark, Robin L. (Livermore, CA); Knauss, Kevin G. (Livermore, CA)

    2000-01-01

    A thermal treatment wall emplaced to perform in-situ destruction of contaminants in groundwater. Thermal destruction of specific contaminants occurs by hydrous pyrolysis/oxidation at temperatures achievable by existing thermal remediation techniques (electrical heating or steam injection) in the presence of oxygen or soil mineral oxidants, such as MnO.sub.2. The thermal treatment wall can be installed in a variety of configurations depending on the specific objectives, and can be used for groundwater cleanup, wherein in-situ destruction of contaminants is carried out rather than extracting contaminated fluids to the surface, where they are to be cleaned. In addition, the thermal treatment wall can be used for both plume interdiction and near-wellhead in-situ groundwater treatment. Thus, this technique can be utilized for a variety of groundwater contamination problems.

  12. Crystallization In High Level Waste (HLW) Glass Melters: Operational Experience From The Savannah River Site

    SciTech Connect (OSTI)

    Fox, K. M.

    2014-02-27

    processing strategy for the Hanford Tank Waste Treatment and Immobilization Plant (WTP). The basis of this alternative approach is an empirical model predicting the crystal accumulation in the WTP glass discharge riser and melter bottom as a function of glass composition, time, and temperature. When coupled with an associated operating limit (e.g., the maximum tolerable thickness of an accumulated layer of crystals), this model could then be integrated into the process control algorithms to formulate crystal tolerant high level waste (HLW) glasses targeting higher waste loadings while still meeting process related limits and melter lifetime expectancies. This report provides a review of the scaled melter testing that was completed in support of the Defense Waste Processing Facility (DWPF) melter. Testing with scaled melters provided the data to define the DWPF operating limits to avoid bulk (volume) crystallization in the un-agitated DWPF melter and provided the data to distinguish between spinels generated by K-3 refractory corrosion versus spinels that precipitated from the HLW glass melt pool. This report includes a review of the crystallization observed with the scaled melters and the full scale DWPF melters (DWPF Melter 1 and DWPF Melter 2). Examples of actual DWPF melter attainment with Melter 2 are given. The intent is to provide an overview of lessons learned, including some example data, that can be used to advance the development and implementation of an empirical model and operating limit for crystal accumulation for WTP. Operation of the first and second (current) DWPF melters has demonstrated that the strategy of using a liquidus temperature predictive model combined with a 100 °C offset from the normal melter operating temperature of 1150 °C (i.e., the predicted liquidus temperature (TL) of the glass must be 1050 °C or less) has been successful in preventing any detrimental accumulation of spinel in the DWPF melt pool, and spinel has not been observed in any of the pour stream glass samples. Spinel was observed at the bottom of DWPF Melter 1 as a result of K-3 refractory corrosion. Issues have occurred with accumulation of spinel in the pour spout during periods of operation at higher waste loadings. Given that both DWPF melters were or have been in operation for greater than 8 years, the service life of the melters has far exceeded design expectations. It is possible that the DWPF liquidus temperature approach is conservative, in that it may be possible to successfully operate the melter with a small degree of allowable crystallization in the glass. This could be a viable approach to increasing waste loading in the glass assuming that the crystals are suspended in the melt and swept out through the riser and pour spout. Additional study is needed, and development work for WTP might be leveraged to support a different operating limit for the DWPF. Several recommendations are made regarding considerations that need to be included as part of the WTP crystal tolerant strategy based on the DWPF development work and operational data reviewed here. These include: Identify and consider the impacts of potential heat sinks in the WTP melter and glass pouring system; Consider the contributions of refractory corrosion products, which may serve to nucleate additional crystals leading to further accumulation; Consider volatilization of components from the melt (e.g., boron, alkali, halides, etc.) and determine their impacts on glass crystallization behavior; Evaluate the impacts of glass REDuction/OXidation (REDOX) conditions and the distribution of temperature within the WTP melt pool and melter pour chamber on crystal accumulation rate; Consider the impact of precipitated crystals on glass viscosity; Consider the impact of an accumulated crystalline layer on thermal convection currents and bubbler effectiveness within the melt pool; Evaluate the impact of spinel accumulation on Joule heating of the WTP melt pool; and Include noble metals in glass melt experiments because of their potential to act as nucleation site

  13. High Level Waste Remote Handling Equipment in the Melter Cave Support Handling System at the Hanford Waste Treatment Plant

    SciTech Connect (OSTI)

    Bardal, M.A. [PaR Systems, Inc., Shoreview, MN (United States); Darwen, N.J. [Bechtel National, Inc., Richland, WA (United States)

    2008-07-01

    Cold war plutonium production led to extensive amounts of radioactive waste stored in tanks at the Department of Energy's (DOE) Hanford site. Bechtel National, Inc. is building the largest nuclear Waste Treatment Plant in the world located at the Department of Energy's Hanford site to immobilize the millions of gallons of radioactive waste. The site comprises five main facilities; Pretreatment, High Level Waste vitrification, Low Active Waste vitrification, an Analytical Lab and the Balance of Facilities. The pretreatment facilities will separate the high and low level waste. The high level waste will then proceed to the HLW facility for vitrification. Vitrification is a process of utilizing a melter to mix molten glass with radioactive waste to form a stable product for storage. The melter cave is designated as the High Level Waste Melter Cave Support Handling System (HSH). There are several key processes that occur in the HSH cell that are necessary for vitrification and include: feed preparation, mixing, pouring, cooling and all maintenance and repair of the process equipment. Due to the cell's high level radiation, remote handling equipment provided by PaR Systems, Inc. is required to install and remove all equipment in the HSH cell. The remote handling crane is composed of a bridge and trolley. The trolley supports a telescoping tube set that rigidly deploys a TR 4350 manipulator arm with seven degrees of freedom. A rotating, extending, and retracting slewing hoist is mounted to the bottom of the trolley and is centered about the telescoping tube set. Both the manipulator and slewer are unique to this cell. The slewer can reach into corners and the manipulator's cross pivoting wrist provides better operational dexterity and camera viewing angles at the end of the arm. Since the crane functions will be operated remotely, the entire cell and crane have been modeled with 3-D software. Model simulations have been used to confirm operational and maintenance functional and timing studies throughout the design process. Since no humans can go in or out of the cell, there are several recovery options that have been designed into the system including jack-down wheels for the bridge and trolley, recovery drums for the manipulator hoist, and a wire rope cable cutter for the slewer jib hoist. If the entire crane fails in cell, the large diameter cable reel that provides power, signal, and control to the crane can be used to retrieve the crane from the cell into the crane maintenance area. (authors)

  14. MELTER: A model of the thermal response of cargos transported in the Safe-Secure Trailer subject to fire environments for risk assessment applications

    SciTech Connect (OSTI)

    Larsen, M.E.

    1994-08-01

    MELTER is an analysis of cargo responses inside a fire-threatened Safe-Secure Trailer (SST) developed for the Defense Program Transportation Risk Assessment (DPTRA). Many simplifying assumptions are required to make the subject problem tractable. MELTER incorporates modeling which balances the competing requirements of execution speed, generality, completeness of essential physics, and robustness. Input parameters affecting the analysis include those defining the fire scenario, those defining the cargo loaded in the SST, and those defining properties of the SST. For a specified fire, SST, and cargo geometry MELTER predicts the critical fire duration that will lead to a failure. The principal features of the analysis include: (a) Geometric considerations to interpret fire-scenario descriptors in terms of a thermal radiation boundary condition, (b) a simple model of the SST`s wall combining the diffusion model for radiation through optically-thick media with an endothermic reaction front to describe the charring of dimensional, rigid foam in the SST wall, (c) a transient radiation enclosure model, (d) a one-dimensional, spherical idealization of the shipped cargos providing modularity so that cargos of interest can be inserted into the model, and (e) associated numerical methods to integrate coupled, differential equations and find roots.

  15. Melter Disposal Strategic Planning Document

    SciTech Connect (OSTI)

    BURBANK, D.A.

    2000-09-25

    This document describes the proposed strategy for disposal of spent and failed melters from the tank waste treatment plant to be built by the Office of River Protection at the Hanford site in Washington. It describes program management activities, disposal and transportation systems, leachate management, permitting, and safety authorization basis approvals needed to execute the strategy.

  16. Induction melter apparatus

    DOE Patents [OSTI]

    Roach, Jay A [Idaho Falls, ID; Richardson, John G [Idaho Falls, ID; Raivo, Brian D [Idaho Falls, ID; Soelberg, Nicholas R [Idaho Falls, ID

    2008-06-17

    Apparatus and methods of operation are provided for a cold-crucible-induction melter for vitrifying waste wherein a single induction power supply may be used to effect a selected thermal distribution by independently energizing at least two inductors. Also, a bottom drain assembly may be heated by an inductor and may include an electrically resistive heater. The bottom drain assembly may be cooled to solidify molten material passing therethrough to prevent discharge of molten material therefrom. Configurations are provided wherein the induction flux skin depth substantially corresponds with the central longitudinal axis of the crucible. Further, the drain tube may be positioned within the induction flux skin depth in relation to material within the crucible or may be substantially aligned with a direction of flow of molten material within the crucible. An improved head design including four shells forming thermal radiation shields and at least two gas-cooled plenums is also disclosed.

  17. Underground Coal Thermal Treatment

    SciTech Connect (OSTI)

    P. Smith; M. Deo; E. Eddings; A. Sarofim; K. Gueishen; M. Hradisky; K. Kelly; P. Mandalaparty; H. Zhang

    2011-10-30

    The long-term objective of this work is to develop a transformational energy production technology by insitu thermal treatment of a coal seam for the production of substitute natural gas (SNG) while leaving much of the coalâ??s carbon in the ground. This process converts coal to a high-efficiency, low-GHG emitting gas fuel. It holds the potential of providing environmentally acceptable access to previously unusable coal resources. This topical report discusses the development of experimental capabilities, the collection of available data, and the development of simulation tools to obtain process thermo-chemical and geo-thermal parameters in preparation for the eventual demonstration in a coal seam. It also includes experimental and modeling studies of CO{sub 2} sequestration. Efforts focused on: â?˘ Constructing a suite of three different coal pyrolysis reactors. These reactors offer the ability to gather heat transfer, mass transfer and kinetic data during coal pyrolysis under conditions that mimic in situ conditions (Subtask 6.1). â?˘ Studying the operational parameters for various underground thermal treatment processes for oil shale and coal and completing a design matrix analysis for the underground coal thermal treatment (UCTT). This analysis yielded recommendations for terms of targeted coal rank, well orientation, rubblization, presence of oxygen, temperature, pressure, and heating sources (Subtask 6.2). â?˘ Developing capabilities for simulating UCTT, including modifying the geometry as well as the solution algorithm to achieve long simulation times in a rubblized coal bed by resolving the convective channels occurring in the representative domain (Subtask 6.3). â?˘ Studying the reactive behavior of carbon dioxide (CO{sub 2}) with limestone, sandstone, arkose (a more complex sandstone) and peridotite, including mineralogical changes and brine chemistry for the different initial rock compositions (Subtask 6.4). Arkose exhibited the highest tendency of participating in mineral reactions, which can be attributed to the geochemical complexity of its initial mineral assemblage. In experiments with limestone, continuous dissolution was observed with the release of CO{sub 2} gas, indicated by the increasing pressure in the reactor (formation of a gas chamber). This occurred due to the lack of any source of alkali to buffer the solution. Arkose has the geochemical complexity for permanent sequestration of CO{sub 2} as carbonates and is also relatively abundant. The effect of including NH{sub 3} in the injected gas stream was also investigated in this study. Precipitation of calcite and trace amounts of ammonium zeolites was observed. A batch geochemical model was developed using Geochemists Workbench (GWB). Degassing effect in the experiments was corrected using the sliding fugacity model in GWB. Experimental and simulation results were compared and a reasonable agreement between the two was observed.

  18. NEXT GENERATION MELTER(S) FOR VITRIFICATION OF HANFORD WASTE STATUS AND DIRECTION

    SciTech Connect (OSTI)

    RAMSEY WG; GRAY MF; CALMUS RB; EDGE JA; GARRETT BG

    2011-01-13

    Vitrification technology has been selected to treat high-level waste (HLW) at the Hanford Site, the West Valley Demonstration Project and the Savannah River Site (SRS), and low activity waste (LAW) at Hanford. In addition, it may potentially be applied to other defense waste streams such as sodium bearing tank waste or calcine. Joule-heated melters (already in service at SRS) will initially be used at the Hanford Site's Waste Treatment and Immobilization Plant (WTP) to vitrify tank waste fractions. The glass waste content and melt/production rates at WTP are limited by the current melter technology. Significant reductions in glass volumes and mission life are only possible with advancements in melter technology coupled with new glass formulations. The Next Generation Melter (NGM) program has been established by the U.S. Department of Energy's (DOE's), Environmental Management Office of Waste Processing (EM-31) to develop melters with greater production capacity (absolute glass throughput rate) and the ability to process melts with higher waste fractions. Advanced systems based on Joule-Heated Ceramic Melter (JHCM) and Cold Crucible Induction Melter (CCIM) technologies will be evaluated for HLW and LAW processing. Washington River Protection Solutions (WRPS), DOE's tank waste contractor, is developing and evaluating these systems in cooperation with EM-31, national and university laboratories, and corporate partners. A primary NGM program goal is to develop the systems (and associated flowsheets) to Technology Readiness Level 6 by 2016. Design and testing are being performed to optimize waste glass process envelopes with melter and balance of plant requirements. A structured decision analysis program will be utilized to assess the performance of the competing melter technologies. Criteria selected for the decision analysis program will include physical process operations, melter performance, system compatibility and other parameters.

  19. Milliwave melter monitoring system

    DOE Patents [OSTI]

    Daniel, William E. (North Augusta, SC); Woskov, Paul P. (Bedford, MA); Sundaram, Shanmugavelayutham K. (Richland, WA)

    2011-08-16

    A milliwave melter monitoring system is presented that has a waveguide with a portion capable of contacting a molten material in a melter for use in measuring one or more properties of the molten material in a furnace under extreme environments. A receiver is configured for use in obtaining signals from the melt/material transmitted to appropriate electronics through the waveguide. The receiver is configured for receiving signals from the waveguide when contacting the molten material for use in determining the viscosity of the molten material. Other embodiments exist in which the temperature, emissivity, viscosity and other properties of the molten material are measured.

  20. Operating an induction melter apparatus

    DOE Patents [OSTI]

    Roach, Jay A.; Richardson, John G.; Raivo, Brian D.; Soelberg, Nicholas R.

    2006-01-31

    Apparatus and methods of operation are provided for a cold-crucible-induction melter for vitrifying waste wherein a single induction power supply may be used to effect a selected thermal distribution by independently energizing at least two inductors. Also, a bottom drain assembly may be heated by an inductor and may include an electrically resistive heater. The bottom drain assembly may be cooled to solidify molten material passing therethrough to prevent discharge of molten material therefrom. Configurations are provided wherein the induction flux skin depth substantially corresponds with the central longitudinal axis of the crucible. Further, the drain tube may be positioned within the induction flux skin depth in relation to material within the crucible or may be substantially aligned with a direction of flow of molten material within the crucible. An improved head design including four shells forming thermal radiation shields and at least two gas-cooled plenums is also disclosed.

  1. Tunable, self-powered integrated arc plasma-melter vitrification system for waste treatment and resource recovery

    DOE Patents [OSTI]

    Titus, Charles H. (Newtown Square, PA); Cohn, Daniel R. (Chestnuthill, MA); Surma, Jeffrey E. (Kennewick, WA)

    1998-01-01

    The present invention provides a relatively compact self-powered, tunable waste conversion system and apparatus which has the advantage of highly robust operation which provides complete or substantially complete conversion of a wide range of waste streams into useful gas and a stable, nonleachable solid product at a single location with greatly reduced air pollution to meet air quality standards. The system provides the capability for highly efficient conversion of waste into high quality combustible gas and for high efficiency conversion of the gas into electricity by utilizing a high efficiency gas turbine or by an internal combustion engine. The solid product can be suitable for various commercial applications. Alternatively, the solid product stream, which is a safe, stable material, may be disposed of without special considerations as hazardous material. In the preferred embodiment of the invention, the arc plasma furnace and joule heated melter are formed as a fully integrated unit with a common melt pool having circuit arrangements for the simultaneous independently controllable operation of both the arc plasma and the joule heated portions of the unit without interference with one another. The preferred configuration of this embodiment of the invention utilizes two arc plasma electrodes with an elongated chamber for the molten pool such that the molten pool is capable of providing conducting paths between electrodes. The apparatus may additionally be employed with reduced or without further use of the gases generated by the conversion process. The apparatus may be employed as a self-powered or net electricity producing unit where use of an auxiliary fuel provides the required level of electricity production.

  2. Preliminary melter performance assessment report

    SciTech Connect (OSTI)

    Elliott, M.L.; Eyler, L.L.; Mahoney, L.A.; Cooper, M.F.; Whitney, L.D.; Shafer, P.J.

    1994-08-01

    The Melter Performance Assessment activity, a component of the Pacific Northwest Laboratory`s (PNL) Vitrification Technology Development (PVTD) effort, was designed to determine the impact of noble metals on the operational life of the reference Hanford Waste Vitrification Plant (HWVP) melter. The melter performance assessment consisted of several activities, including a literature review of all work done with noble metals in glass, gradient furnace testing to study the behavior of noble metals during the melting process, research-scale and engineering-scale melter testing to evaluate effects of noble metals on melter operation, and computer modeling that used the experimental data to predict effects of noble metals on the full-scale melter. Feed used in these tests simulated neutralized current acid waste (NCAW) feed. This report summarizes the results of the melter performance assessment and predicts the lifetime of the HWVP melter. It should be noted that this work was conducted before the recent Tri-Party Agreement changes, so the reference melter referred to here is the Defense Waste Processing Facility (DWPF) melter design.

  3. Lid heater for glass melter

    DOE Patents [OSTI]

    Phillips, T.D.

    1993-12-14

    A glass melter having a lid electrode for heating the glass melt radiantly. The electrode comprises a series of INCONEL 690 tubes running above the melt across the melter interior and through the melter walls and having nickel cores inside the tubes beginning where the tubes leave the melter interior and nickel connectors to connect the tubes electrically in series. An applied voltage causes the tubes to generate heat of electrical resistance for melting frit injected onto the melt. The cores limit heat generated as the current passes through the walls of the melter. Nickel bus connection to the electrical power supply minimizes heat transfer away from the melter that would occur if standard copper or water-cooled copper connections were used between the supply and the INCONEL 690 heating tubes. 3 figures.

  4. Independent Oversight Activity Report, Hanford Waste Treatment...

    Energy Savers [EERE]

    - October 2013 October 2013 Observation of Waste Treatment and Immobilization Plant Low Activity Waste Melter and Melter Off-gas Process System Hazards Analysis Activities...

  5. Vitrification Melter Waste Incidental to Reprocessing Determination...

    Office of Environmental Management (EM)

    DOE Manual 435.1-1 Waste-Incidental-To-Reprocessing Determination for the West Valley Demonstration Project Vitrification Melter Vitrification Melter Waste Incidental to...

  6. Melter Glass Removal and Dismantlement

    SciTech Connect (OSTI)

    Richardson, BS

    2000-10-31

    The U.S. Department of Energy (DOE) has been using vitrification processes to convert high-level radioactive waste forms into a stable glass for disposal in waste repositories. Vitrification facilities at the Savannah River Site (SRS) and at the West Valley Demonstration Project (WVDP) are converting liquid high-level waste (HLW) by combining it with a glass-forming media to form a borosilicate glass, which will ensure safe long-term storage. Large, slurry fed melters, which are used for this process, were anticipated to have a finite life (on the order of two to three years) at which time they would have to be replaced using remote methods because of the high radiation fields. In actuality the melters useable life spans have, to date, exceeded original life-span estimates. Initial plans called for the removal of failed melters by placing the melter assembly into a container and storing the assembly in a concrete vault on the vitrification plant site pending size-reduction, segregation, containerization, and shipment to appropriate storage facilities. Separate facilities for the processing of the failed melters currently do not exist. Options for handling these melters include (1) locating a facility to conduct the size-reduction, characterization, and containerization as originally planned; (2) long-term storing or disposing of the complete melter assembly; and (3) attempting to refurbish the melter and to reuse the melter assembly. The focus of this report is to look at methods and issues pertinent to size-reduction and/or melter refurbishment in particular, removing the glass as a part of a refurbishment or to reduce contamination levels (thus allowing for disposal of a greater proportion of the melter as low level waste).

  7. PHYSICAL CHARACTERIZATION OF VITREOUS STATE LABORATORY AY102/C106 AND AZ102 HIGH LEVEL WASTE MELTER FEED SIMULANTS (U)

    SciTech Connect (OSTI)

    Hansen, E

    2005-03-31

    The objective of this task is to characterize and report specified physical properties and pH of simulant high level waste (HLW) melter feeds (MF) processed through the scaled melters at Vitreous State Laboratories (VSL). The HLW MF simulants characterized are VSL AZ102 straight hydroxide melter feed, VSL AZ102 straight hydroxide rheology adjusted melter feed, VSL AY102/C106 straight hydroxide melter feed, VSL AY102/C106 straight hydroxide rheology adjusted melter feed, and Savannah River National Laboratory (SRNL) AY102/C106 precipitated hydroxide processed sludge blended with glass former chemicals at VSL to make melter feed. The physical properties and pH were characterized using the methods stated in the Waste Treatment Plant (WTP) characterization procedure (Ref. 7).

  8. Enterprise Assessments Review of the Hanford Site Waste Treatment...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Review of the Hanford Site Waste Treatment and Immobilization Plant Low-Activity Waste Facility Hazards Analysis Reports for the Melter and Melter Offgas Systems - September 2015...

  9. Graphite electrode arc melter demonstration Phase 2 test results

    SciTech Connect (OSTI)

    Soelberg, N.R.; Chambers, A.G.; Anderson, G.L.; O`Connor, W.K.; Oden, L.L.; Turner, P.C.

    1996-06-01

    Several U.S. Department of Energy organizations and the U.S. Bureau of Mines have been collaboratively conducting mixed waste treatment process demonstration testing on the near full-scale graphite electrode submerged arc melter system at the Bureau`s Albany (Oregon) Research Center. An initial test series successfully demonstrated arc melter capability for treating surrogate incinerator ash of buried mixed wastes with soil. The conceptual treatment process for that test series assumed that buried waste would be retrieved and incinerated, and that the incinerator ash would be vitrified in an arc melter. This report presents results from a recently completed second series of tests, undertaken to determine the ability of the arc melter system to stably process a wide range of {open_quotes}as-received{close_quotes} heterogeneous solid mixed wastes containing high levels of organics, representative of the wastes buried and stored at the Idaho National Engineering Laboratory (INEL). The Phase 2 demonstration test results indicate that an arc melter system is capable of directly processing these wastes and could enable elimination of an up-front incineration step in the conceptual treatment process.

  10. Melter development needs assessment for RWMC buried wastes

    SciTech Connect (OSTI)

    Donaldson, A.D.; Carpenedo, R.J.; Anderson, G.L.

    1992-02-01

    This report presents a survey and initial assessment of the existing state-of-the-art melter technology necessary to thermally treat (stabilize) buried TRU waste, by producing a highly leach resistant glass/ceramic waste form suitable for final disposal. Buried mixed transuranic (TRU) waste at the Idaho National Engineering Laboratory (INEL) represents an environmental hazard requiring remediation. The Environmental Protection Agency (EPA) placed the INEL on the National Priorities List in 1989. Remediation of the buried TRU-contaminated waste via the CERCLA decision process is required to remove INEL from the National Priorities List. A Waste Technology Development (WTD) Preliminary Systems Design and Thermal Technologies Screening Study identified joule-heated and plasma-heated melters as the most probable thermal systems technologies capable of melting the INEL soil and waste to produce the desired final waste form (Iron-Enriched Basalt (IEB) glass/ceramic). The work reported herein then surveys the state of existing melter technology and assesses it within the context of processing INEL buried TRU wastes and contaminated soils. Necessary technology development work is recommended.

  11. Melter development needs assessment for RWMC buried wastes

    SciTech Connect (OSTI)

    Donaldson, A.D.; Carpenedo, R.J.; Anderson, G.L.

    1992-02-01

    This report presents a survey and initial assessment of the existing state-of-the-art melter technology necessary to thermally treat (stabilize) buried TRU waste, by producing a highly leach resistant glass/ceramic waste form suitable for final disposal. Buried mixed transuranic (TRU) waste at the Idaho National Engineering Laboratory (INEL) represents an environmental hazard requiring remediation. The Environmental Protection Agency (EPA) placed the INEL on the National Priorities List in 1989. Remediation of the buried TRU-contaminated waste via the CERCLA decision process is required to remove INEL from the National Priorities List. A Waste Technology Development (WTD) Preliminary Systems Design and Thermal Technologies Screening Study identified joule-heated and plasma-heated melters as the most probable thermal systems technologies capable of melting the INEL soil and waste to produce the desired final waste form [Iron-Enriched Basalt (IEB) glass/ceramic]. The work reported herein then surveys the state of existing melter technology and assesses it within the context of processing INEL buried TRU wastes and contaminated soils. Necessary technology development work is recommended.

  12. Thermal treatment of dyes from military munitions

    SciTech Connect (OSTI)

    NONE

    1996-09-01

    Los Alamos National Laboratory has developed thermal treatment equipment to treat Navy smoke and dye compounds. Navy smokes were burned in the Los Alamos Controlled Air Incinerator (CAI) in the early 1980s. These test results were used in the development of a portable system consisting of a Thermal Treatment Unit (TTU), feed preparation and pumping skid, utility skid, and control trailer. This equipment was started up at Navy facilities at China Lake, CA where several destruction removal efficiency tests were completed in 1993 burning smoke compositions. The equipment was set up at the Nevada Test Site (NTS) in 1996 where tests were completed burning green Navy spotting dyes. Operating and test results from the NTS efforts resulted in clearer understanding of equipment deficiencies, dye characteristics and composition, and secondary wastes generated. Future tests, scheduled for July, 1996 will demonstrate higher bum rates, better pH measurement and control, and stack emission test results for other colored dyes.

  13. Effect of Bubbles and Silica Dissolution on Melter Feed Rheology...

    Office of Scientific and Technical Information (OSTI)

    Bubbles and Silica Dissolution on Melter Feed Rheology during Conversion to Glass As the nuclear waste glass melter feed is converted to molten glass, the feed becomes a...

  14. Advanced radioactive waste-glass melters

    SciTech Connect (OSTI)

    Bickford, D.F.

    1990-12-31

    During pilot scale operations of the Scale Glass Melter for the US Department of Energy a team of engineers and scientists was formed to assess the need for continued melter design development to support the Defense Waste Processing Facility (DWPF), and prioritize future efforts. Recently this has taken on new importance because of selection of the DWPF Melter design as the reference for the Hanford Waste Vitrification Project (HWVP), and increased interest at the West Valley Demonstration Project on melter life and replacement. Results of the study are summarized, and goals produced by the study are compared to the results of current programs at the Savannah River Laboratory (SRL).

  15. Advanced radioactive waste-glass melters

    SciTech Connect (OSTI)

    Bickford, D.F.

    1990-01-01

    During pilot scale operations of the Scale Glass Melter for the US Department of Energy a team of engineers and scientists was formed to assess the need for continued melter design development to support the Defense Waste Processing Facility (DWPF), and prioritize future efforts. Recently this has taken on new importance because of selection of the DWPF Melter design as the reference for the Hanford Waste Vitrification Project (HWVP), and increased interest at the West Valley Demonstration Project on melter life and replacement. Results of the study are summarized, and goals produced by the study are compared to the results of current programs at the Savannah River Laboratory (SRL).

  16. Three-Dimensional Thermal Tomography Advances Cancer Treatment...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Three-Dimensional Thermal Tomography Advances Cancer Treatment Technology available for licensing: A 3D technique to detect early skin changes due to radiation treatment in breast...

  17. DWPF Glass Melter Technology Manual: Volume 4

    SciTech Connect (OSTI)

    Iverson, D.C.

    1993-12-31

    This document details information about the design of a glass melter to be used at the Defense Waste Processing Facility located at the Savannah River Plant. Information contained in this document consists solely of a machine drawing and parts list and purchase orders with specifications of equipment used in the development of the melter.

  18. Final Vitrification Melter And Vessels Evaluation Documentation

    Broader source: Energy.gov [DOE]

    DOE has prepared final evaluations and made waste incidental to reprocessing determinations for the vitrification melter and feed vessels (the concentrator feed makeup tank and the melter feed hold tank), used by DOE’s West Valley Demonstration Project as part of the process to vitrify waste from prior commercial reprocessing of spent nuclear fuel.

  19. GTS Duratek, Phase I Hanford low-level waste melter tests: 100-kg melter offgas report

    SciTech Connect (OSTI)

    Eaton, W.C. [Westinghouse Hanford Co., Richland, WA (United States)] [Westinghouse Hanford Co., Richland, WA (United States)

    1995-11-01

    A multiphase program was initiated in 1994 to test commercially available melter technologies for the vitrification of the low-level waste (LLW) stream from defense wastes stored in underground tanks at the Hanford Site in southeastern Washington State. Phase 1 of the melter demonstration tests using simulated LLW was completed during fiscal year 1995. This document is the 100-kg melter offgas report on testing performed by GTS Duratek, Inc., in Columbia, Maryland. GTS Duratek (one of the seven vendors selected) was chosen to demonstrate Joule heated melter technology under WHC subcontract number MMI-SVV-384215. The document contains the complete offgas report on the 100-kg melter as prepared by Parsons Engineering Science, Inc. A summary of this report is also contained in the GTS Duratek, Phase I Hanford Low-Level Waste Melter Tests: Final Report (WHC-SD-WM-VI-027).

  20. HLW Melter Control Strategy Without Visual Feedback VSL-12R2500-1 Rev 0

    SciTech Connect (OSTI)

    Kruger, A A.; Joseph, Innocent; Matlack, Keith S.; Callow, Richard A.; Abramowitz, Howard; Pegg, Ian L.; Brandys, Marek; Kot, Wing K.

    2012-11-13

    Plans for the treatment of high level waste (HL W) at the Hanford Tank Waste Treatment and Immobilization Plant (WTP) are based upon the inventory of the tank wastes, the anticipated performance of the pretreatment processes, and current understanding of the capability of the borosilicate glass waste form [I]. The WTP HLW melter design, unlike earlier DOE melter designs, incorporates an active glass bubbler system. The bubblers create active glass pool convection and thereby improve heat and mass transfer and increase glass melting rates. The WTP HLW melter has a glass surface area of 3.75 m{sup 2} and depth of ~ 1.1 m. The two melters in the HLW facility together are designed to produce up to 7.5 MT of glass per day at 100% availability. Further increases in HL W waste processing rates can potentially be achieved by increasing the melter operating temperature above 1150?C and by increasing the waste loading in the glass product. Increasing the waste loading also has the added benefit of decreasing the number of canisters for storage.

  1. Selection of melter systems for the DOE/Industrial Center for Waste Vitrification Research

    SciTech Connect (OSTI)

    Bickford, D.F.

    1993-12-31

    The EPA has designated vitrification as the best developed available technology for immobilization of High-Level Nuclear Waste. In a recent federal facilities compliance agreement between the EPA, the State of Washington, and the DOE, the DOE agreed to vitrify all of the Low Level Radioactive Waste resulting from processing of High Level Radioactive Waste stored at the Hanford Site. This is expected to result in the requirement of 100 ton per day Low Level Radioactive Waste melters. Thus, there is increased need for the rapid adaptation of commercial melter equipment to DOE`s needs. DOE has needed a facility where commercial pilot scale equipment could be operated on surrogate (non-radioactive) simulations of typical DOE waste streams. The DOE/Industry Center for Vitrification Research (Center) was established in 1992 at the Clemson University Department of Environmental Systems Engineering, Clemson, SC, to address that need. This report discusses some of the characteristics of the melter types selected for installation of the Center. An overall objective of the Center has been to provide the broadest possible treatment capability with the minimum number of melter units. Thus, units have been sought which have broad potential application, and which had construction characteristics which would allow their adaptation to various waste compositions, and various operating conditions, including extreme variations in throughput, and widely differing radiological control requirements. The report discusses waste types suitable for vitrification; technical requirements for the application of vitrification to low level mixed wastes; available melters and systems; and selection of melter systems. An annotated bibliography is included.

  2. Summary - Building C-400 Thermal Treatment Remedial Design Report...

    Office of Environmental Management (EM)

    Paducah, KY EM Project: Building C400 Thermal Treatment ETR Report Date: August 2007 ETR-8 United States Department of Energy Office of Environmental Management (DOE-EM) External...

  3. Low level mixed waste thermal treatment technical basis report

    SciTech Connect (OSTI)

    Place, B.G.

    1994-12-01

    Detailed characterization of the existing and projected Hanford Site Radioactive Mixed Waste (RMW) inventory was initiated in 1993 (Place 1993). This report presents an analysis of the existing and projected RMW inventory. The subject characterization effort continues to be in support of the following engineering activities related to thermal treatment of Hanford Site RMW: (1) Contracting for commercial thermal treatment; (2) Installation and operation of an onsite thermal treatment facility (Project W-242); (3) Treatment at another Department of Energy (DOE) site. The collation of this characterization information (data) has emphasized the establishment of a common data base for the entire existing RMW inventory so that the specification of feed streams destined for different treatment facilities can be coordinated.

  4. DWPF Glass Melter Technology Manual: Volume 3

    SciTech Connect (OSTI)

    Iverson, D.C.

    1993-12-31

    This document details information about the design of a glass melter to be used at the Defense Waste Processing Facility located at the Savannah River Site. Topics discussed include: Information collected during testing, equipment, materials, design basis, feed tubes, and an evaluation of the performance of various components. Information is conveyed using many diagrams and photographs.

  5. Performance test report for the 1000 kg melter

    SciTech Connect (OSTI)

    Eaton, W.C.

    1995-11-01

    A multiphase program was initiated in 1994 to test commercially available melter technologies for the vitrification of the low-level waste (LLW) stream from defense wastes stored in underground tanks at the Hanford Site in southeastern Washington State. Phase 1 of the melter demonstration tests using simulated LLW was completed during fiscal year 1995. This document is the 100 kg melter offgas report on testing performed by GTS Duratek Inc., in Columbia, Maryland. GTS Duratek (one of the seven vendors selected) was chosen to demonstrate Joule heated melter technology under WHC subcontract number MMI-SVV- 384215. The document contains the complete offgas report on the 100 kg melter as prepared by Parsons Engineering Science, Inc. A summary of this report is also contained in the ``GTS Duratek, Phase 1 Hanford Low-Level Waste Melter Tests: Final Report`` (WHC-SD-VI-027).

  6. Responses to Public Comments on Draft Vitrification Melter Evaluation

    Office of Environmental Management (EM)

    of the impacts of transporting for disposal the Vitrification Melter and two other vessels used in vitrification processing. The Supplement Analysis concluded that the impacts...

  7. Waste simulant development for evaluation of LLW melter system technology

    SciTech Connect (OSTI)

    Shade, J.W.

    1994-05-25

    This document describes the LLW simulant compositions, basis for the simulants, and recipes for preparing nonradioactive simulants for LLW melter tests.

  8. Recirculation bubbler for glass melter apparatus

    DOE Patents [OSTI]

    Guerrero, Hector (Evans, GA); Bickford, Dennis (Folly Beach, SC)

    2007-06-05

    A gas bubbler device provides enhanced recirculation of molten glass within a glass melter apparatus. The bubbler device includes a tube member disposed within a pool of molten glass contained in the melter. The tube member includes a lower opening through which the molten glass enters and upper slots disposed close to (above or below) the upper surface of the pool of molten glass and from which the glass exits. A gas (air) line is disposed within the tube member and extends longitudinally thereof. A gas bubble distribution device, which is located adjacent to the lower end of the tube member and is connected to the lower end of the gas line, releases gas through openings therein so as to produce gas bubbles of a desired size in the molten glass and in a distributed pattern across the tube member.

  9. Letter report: Cold crucible melter assessment

    SciTech Connect (OSTI)

    Elliott, M.L.

    1996-03-01

    One of the activities of the PNL Vitrification Technology Development (PVTD) Project is to assist the Tank Waste Remediation Systems (TWRS) Program in determining which melter systems should be performance tested for potential implementation in the high-level waste (HLW) vitrification plant. The Richland Operations Office (RL) has recommended that the Cold Crucible Melter (CCM) be evaluated as a candidate ``next generation`` melter. As a result, the CCM System Evaluation cost account was established under the PVTD Project so that the CCM could be initially assessed on a high-priority basis. This letter report summarizes a brief initial review and assessment of the CCM. Using the recommendations made in this document, Westinghouse Hanford Company (WHC) and RL will make a decision regarding the urgency of performance testing the CCM. If the decision is favorable, a subcontract will be negotiated for performance testing of a CCM using Hanford HLW simulants in a pilot-scale facility. Because of the aggressive nature of the schedule, the CCM evaluation was not rigorous. The evaluation consisted of a literature review and interviews with proponents of the technology during a recent trip to France. This letter report summarizes the evaluation and makes recommendations regarding further work in this area.

  10. EFFECT OF MELTER-FEED-MAKEUP ON VITRIFICATION PROCESS

    SciTech Connect (OSTI)

    KRUGER AA; HRMA PR; SCHWEIGER MJ; HUMRICKHOUSE CJ; MOODY JA; TATE RM; TEGROTENHUIS NE; ARRIGONI BM; RODRIGUEZ CP

    2009-09-10

    Increasing the rate of glass processing in the Hanford Tank Waste Treatment and Immobilization Plant (WTP) will allow shortening the life cycle of waste cleanup at the Hanford Site. While the WTP melters have approached the limit of increasing the rate of melting by enhancing the heat transfer rate from molten glass to the cold cap, a substantial improvement can still be achieved by accelerating the feed-to-glass conversion kinetics. This study investigates how the feed-to-glass conversion process responds to the feed makeup. By identifying the means of control of primary foam formation and silica grain dissolution, it provides data needed for a meaningful and economical design of large-scale experiments aimed at achieving faster melting.

  11. Process modeling for the Integrated Thermal Treatment System (ITTS) study

    SciTech Connect (OSTI)

    Liebelt, K.H.; Brown, B.W.; Quapp, W.J.

    1995-09-01

    This report describes the process modeling done in support of the integrated thermal treatment system (ITTS) study, Phases 1 and 2. ITTS consists of an integrated systems engineering approach for uniform comparison of widely varying thermal treatment technologies proposed for treatment of the contact-handled mixed low-level wastes (MLLW) currently stored in the U.S. Department of Energy complex. In the overall study, 19 systems were evaluated. Preconceptual designs were developed that included all of the various subsystems necessary for a complete installation, from waste receiving through to primary and secondary stabilization and disposal of the processed wastes. Each system included the necessary auxiliary treatment subsystems so that all of the waste categories in the complex were fully processed. The objective of the modeling task was to perform mass and energy balances of the major material components in each system. Modeling of trace materials, such as pollutants and radioactive isotopes, were beyond the present scope. The modeling of the main and secondary thermal treatment, air pollution control, and metal melting subsystems was done using the ASPEN PLUS process simulation code, Version 9.1-3. These results were combined with calculations for the remainder of the subsystems to achieve the final results, which included offgas volumes, and mass and volume waste reduction ratios.

  12. Baseline tests for arc melter vitrification of INEL buried wastes. Volume 1: Facility description and summary data report

    SciTech Connect (OSTI)

    Oden, L.L.; O`Connor, W.K.; Turner, P.C.; Soelberg, N.R.; Anderson, G.L.

    1993-11-19

    This report presents field results and raw data from the Buried Waste Integrated Demonstration (BWID) Arc Melter Vitrification Project Phase 1 baseline test series conducted by the Idaho National Engineering Laboratory (INEL) in cooperation with the U.S. Bureau of Mines (USBM). The baseline test series was conducted using the electric arc melter facility at the USBM Albany Research Center in Albany, Oregon. Five different surrogate waste feed mixtures were tested that simulated thermally-oxidized, buried, TRU-contaminated, mixed wastes and soils present at the INEL. The USBM Arc Furnace Integrated Waste Processing Test Facility includes a continuous feed system, the arc melting furnace, an offgas control system, and utilities. The melter is a sealed, 3-phase alternating current (ac) furnace approximately 2 m high and 1.3 m wide. The furnace has a capacity of 1 metric ton of steel and can process as much as 1,500 lb/h of soil-type waste materials. The surrogate feed materials included five mixtures designed to simulate incinerated TRU-contaminated buried waste materials mixed with INEL soil. Process samples, melter system operations data and offgas composition data were obtained during the baseline tests to evaluate the melter performance and meet test objectives. Samples and data gathered during this program included (a) automatically and manually logged melter systems operations data, (b) process samples of slag, metal and fume solids, and (c) offgas composition, temperature, velocity, flowrate, moisture content, particulate loading and metals content. This report consists of 2 volumes: Volume I summarizes the baseline test operations. It includes an executive summary, system and facility description, review of the surrogate waste mixtures, and a description of the baseline test activities, measurements, and sample collection. Volume II contains the raw test data and sample analyses from samples collected during the baseline tests.

  13. Effluent treatment options for nuclear thermal propulsion system ground tests

    SciTech Connect (OSTI)

    Shipers, L.R.; Brockmann, J.E.

    1992-10-16

    A variety of approaches for handling effluent from nuclear thermal propulsion system ground tests in an environmentally acceptable manner are discussed. The functional requirements of effluent treatment are defined and concept options are presented within the framework of these requirements. System concepts differ primarily in the choice of fission-product retention and waste handling concepts. The concept options considered range from closed cycle (venting the exhaust to a closed volume or recirculating the hydrogen in a closed loop) to open cycle (real time processing and venting of the effluent). This paper reviews the strengths and weaknesses of different methods to handle effluent from nuclear thermal propulsion system ground tests.

  14. Volatilization of heavy metals and radionuclides from soil heated in an induction ``cold`` crucible melter

    SciTech Connect (OSTI)

    Aloy, A.S.; Belov, V.Z.; Trofimenko, A.S. [Khlopin Radium Inst., St. Petersburg (Russian Federation); Dmitriev, S.A.; Stefanovsky, S.V. [SIA Radon, Moscow (Russian Federation); Gombert, D.; Knecht, D.A. [Lockheed Martin Idaho Technologies Co., Idaho Falls, ID (United States)

    1997-12-31

    The behavior of heavy metals and radionuclides during high-temperature treatment is very important for the design and operational capabilities of the off-gas treatment system, as well as for a better understanding of the nature and forms of the secondary waste. In Russia, a process for high-temperature melting in an induction heated cold crucible system is being studied for vitrification of Low Level Waste (LLW) flyash and SYNROC production with simulated high level waste (HLW). This work was done as part of a Department of Energy (DOE) funded research project for thermal treatment of mixed low level waste (LLW). Soil spiked with heavy metals (Cd, Pb) and radionuclides (Cs-137, U-239, Pu-239) was used as a waste surrogate. The soil was melted in an experimental lab-scale system that consisted of a high-frequency generator (1.76 MHz, 60 kW), a cold crucible melter (300 mm high and 90 mm in diameter), a shield box, and an off-gas system. The process temperature was 1,350--1,400 C. Graphite and silicon carbide were used as sacrificial conductive materials to start heating and initial melting of the soil batch. The off-gas system was designed in such a manner that after each experiment, it can be disconnected to collect and analyze all deposits to determine the mass balance. The off-gases were also sampled during an experiment to analyze for hydrogen, NO{sub x}, carbon dioxide, carbon monoxide and chlorine formation. This paper describes distribution and mass balance of metals and radionuclides in various parts of the off-gas system. The leach rate of the solidified blocks identified by the PCT method is also reported.

  15. CALCULATION OF DEMONSTRATION BULK VITRIFICATION SYSTEM MELTER INLEAKAGE AND OFF-GAS GENERATION RATE

    SciTech Connect (OSTI)

    MAY TH

    2008-04-16

    The River Protection Project (RPP) mission is to safely store, retrieve, treat, immobilize, and dispose of the Hanford Site tank waste. The Demonstration Bulk Vitrification System (DBVS) is a research and development project whose objective is to demonstrate the suitability of Bulk Vitrification treatment technology waste form for disposing of low-activity waste from the Tank Farms. The objective of this calculation is to determine the DBVS melter inleakage and off-gas generation rate based on full scale testing data from 38D. This calculation estimates the DBVS melter in leakage and gas generation rate based on test data. Inleakage is estimated before the melt was initiated, at one point during the melt, and at the end of the melt. Maximum gas generation rate is also estimated.

  16. Spray Calciner/In-Can Melter high-level waste solidification technical manual

    SciTech Connect (OSTI)

    Larson, D.E. (ed.)

    1980-09-01

    This technical manual summarizes process and equipment technology developed at Pacific Northwest Laboratory over the last 20 years for vitrification of high-level liquid waste by the Spray Calciner/In-Can Melter process. Pacific Northwest Laboratory experience includes process development and demonstration in laboratory-, pilot-, and full-scale equipment using nonradioactive synthetic wastes. Also, laboratory- and pilot-scale process demonstrations have been conducted using actual high-level radioactive wastes. In the course of process development, more than 26 tonnes of borosilicate glass have been produced in 75 canisters. Four of these canisters contained radioactive waste glass. The associated process and glass chemistry is discussed. Technology areas described include calciner feed treatment and techniques, calcination, vitrification, off-gas treatment, glass containment (the canister), and waste glass chemistry. Areas of optimization and site-specific development that would be needed to adapt this base technology for specific plant application are indicated. A conceptual Spray Calciner/In-Can Melter system design and analyses are provided in the manual to assist prospective users in evaluating the process for plant application, to provide equipment design information, and to supply information for safety analyses and environmental reports. The base (generic) technology for the Spray Calciner/In-Can Melter process has been developed to a point at which it is ready for plant application.

  17. Maximum total organic carbon limit for DWPF melter feed

    SciTech Connect (OSTI)

    Choi, A.S.

    1995-03-13

    DWPF recently decided to control the potential flammability of melter off-gas by limiting the total carbon content in the melter feed and maintaining adequate conditions for combustion in the melter plenum. With this new strategy, all the LFL analyzers and associated interlocks and alarms were removed from both the primary and backup melter off-gas systems. Subsequently, D. Iverson of DWPF- T{ampersand}E requested that SRTC determine the maximum allowable total organic carbon (TOC) content in the melter feed which can be implemented as part of the Process Requirements for melter feed preparation (PR-S04). The maximum TOC limit thus determined in this study was about 24,000 ppm on an aqueous slurry basis. At the TOC levels below this, the peak concentration of combustible components in the quenched off-gas will not exceed 60 percent of the LFL during off-gas surges of magnitudes up to three times nominal, provided that the melter plenum temperature and the air purge rate to the BUFC are monitored and controlled above 650 degrees C and 220 lb/hr, respectively. Appropriate interlocks should discontinue the feeding when one or both of these conditions are not met. Both the magnitude and duration of an off-gas surge have a major impact on the maximum TOC limit, since they directly affect the melter plenum temperature and combustion. Although the data obtained during recent DWPF melter startup tests showed that the peak magnitude of a surge can be greater than three times nominal, the observed duration was considerably shorter, on the order of several seconds. The long surge duration assumed in this study has a greater impact on the plenum temperature than the peak magnitude, thus making the maximum TOC estimate conservative. Two models were used to make the necessary calculations to determine the TOC limit.

  18. Low-Level waste phase 1 melter testing off gas and mass balance evaluation

    SciTech Connect (OSTI)

    Wilson, C.N.

    1996-06-28

    Commercially available melter technologies were tested during 1994-95 as part of a multiphase program to test candidate technologies for vitrification of the low-level waste (LLW) stream to be derived from retrieval and pretreatment of Hanford Site tank wastes. Seven vendors were selected for Phase 1 testing to demonstrate vitrification of a high sodium content liquid LLW simulant. The tested melter technologies included four Joule-heated melters, a carbon electrode melter, a combustion melter, and a plasma melter. Various dry and slurry melter feed preparation processes were also tested. Various feed material samples, product glass samples, and process offgas streams were characterized to provide data for evaluation of process decontamination factors and material mass balances for each vitrification technology. This report describes the melter mass balance evaluations and results for six of the Phase 1 LLW melter vendor demonstration tests.

  19. Method and apparatus for a combination moving bed thermal treatment reactor and moving bed filter

    DOE Patents [OSTI]

    Badger, Phillip C.; Dunn, Jr., Kenneth J.

    2015-09-01

    A moving bed gasification/thermal treatment reactor includes a geometry in which moving bed reactor particles serve as both a moving bed filter and a heat carrier to provide thermal energy for thermal treatment reactions, such that the moving bed filter and the heat carrier are one and the same to remove solid particulates or droplets generated by thermal treatment processes or injected into the moving bed filter from other sources.

  20. High-Level Waste Melter Study Report

    SciTech Connect (OSTI)

    Perez, Joseph M.; Bickford, Dennis F.; Day, Delbert E.; Kim, Dong-Sang; Lambert, Steven L.; Marra, Sharon L.; Peeler, David K.; Strachan, Denis M.; Triplett, Mark B.; Vienna, John D.; Wittman, Richard S.

    2001-07-13

    At the Hanford Site in Richland, Washington, the path to site cleanup involves vitrification of the majority of the wastes that currently reside in large underground tanks. A Joule-heated glass melter is the equipment of choice for vitrifying the high-level fraction of these wastes. Even though this technology has general national and international acceptance, opportunities may exist to improve or change the technology to reduce the enormous cost of accomplishing the mission of site cleanup. Consequently, the U.S. Department of Energy requested the staff of the Tanks Focus Area to review immobilization technologies, waste forms, and modifications to requirements for solidification of the high-level waste fraction at Hanford to determine what aspects could affect cost reductions with reasonable long-term risk. The results of this study are summarized in this report.

  1. NEXT GENERATION MELTER OPTIONEERING STUDY - INTERIM REPORT

    SciTech Connect (OSTI)

    GRAY MF; CALMUS RB; RAMSEY G; LOMAX J; ALLEN H

    2010-10-19

    The next generation melter (NOM) development program includes a down selection process to aid in determining the recommended vitrification technology to implement into the WTP at the first melter change-out which is scheduled for 2025. This optioneering study presents a structured value engineering process to establish and assess evaluation criteria that will be incorporated into the down selection process. This process establishes an evaluation framework that will be used progressively throughout the NGM program, and as such this interim report will be updated on a regular basis. The workshop objectives were achieved. In particular: (1) Consensus was reached with stakeholders and technology providers represented at the workshop regarding the need for a decision making process and the application of the D{sub 2}0 process to NGM option evaluation. (2) A framework was established for applying the decision making process to technology development and evaluation between 2010 and 2013. (3) The criteria for the initial evaluation in 2011 were refined and agreed with stakeholders and technology providers. (4) The technology providers have the guidance required to produce data/information to support the next phase of the evaluation process. In some cases it may be necessary to reflect the data/information requirements and overall approach to the evaluation of technology options against specific criteria within updated Statements of Work for 2010-2011. Access to the WTP engineering data has been identified as being very important for option development and evaluation due to the interface issues for the NGM and surrounding plant. WRPS efforts are ongoing to establish precisely data that is required and how to resolve this Issue. It is intended to apply a similarly structured decision making process to the development and evaluation of LAW NGM options.

  2. U.S. Bureau of Mines, phase I Hanford low-level waste melter tests: Melter offgas report

    SciTech Connect (OSTI)

    Eaton, W.C.

    1995-10-27

    A multiphase program was initiated in 1994 to test commercially available melter technologies for the vitrification of the low-level waste (LLW) stream from defense wastes stored in underground tanks at the Hanford Site in southeastern Washington State. Phase 1 of the melter demonstration tests using simulated LLW was completed during fiscal year 1995. This document is the melter offgas report on testing performed by the U.S. Department of the Interior, Bureau of Mines, Albany Research Center in Albany, Oregon. The Bureau of Mines (one of the seven vendors selected) was chosen to demonstrate carbon electrode melter technology (also called carbon arc or electric arc) under WHC subcontract number MMI-SVV-384216. The document contains the complete offgas report for the first 24-hour melter test (WHC-1) as prepared by Entropy Inc. A summary of this report is also contained in the``U.S. Bureau of Mines, Phase 1 Hanford Low-Level Waste Melter Tests: Final Report`` (WHC-SD-WM-VI-030).

  3. CHARACTERIZATION OF DWPF MELTER OFF-GAS QUENCHER SAMPLE

    SciTech Connect (OSTI)

    Newell, J.

    2011-11-14

    The Savannah River National Laboratory (SRNL) recently received a deposit sample from the Melter Primary Off Gas System (POG) of the Defense Waste Processing Facility (DWPF). This sample was composed of material that had been collected while the quencher was in operation January 27, 2011 through March 31, 2011. DWPF requested, through a technical assistance request, characterization of the melter off-gas deposits by x-ray diffraction (XRD), scanning electron microscopy (SEM), and chemical analysis. The purpose of the Melter Off-Gas System is to reduce the amount of radioactive particles and mercury in the gases vented to the atmosphere. Gases emitted from the melter pass through the primary film cooler, quencher, Off-Gas Condensate Tank (OGCT), Steam Atomized Scrubbers (SAS), a condenser, a high efficiency mist eliminator, and a high efficiency particulate air filter, before being vented to the Process Vessel Vent System. The film coolers cool the gases leaving the melter vapor space from {approx}750 C to {approx}375 C, by introducing air and steam to the flow. In the next step, the quencher cools the gas to about 60 C by bringing the condensate from the OGCT in contact with the effluent (Figure 1). Most of the steam in the effluent is then condensed and the melter vapor space pressure is reduced. The purpose of the OGCT is to collect and store the condensate formed during the melter operation. Condensate from the OGCT is circulated to the SAS and atomized with steam. This atomized condensate is mixed with the off-gas to wet and join the particulate which is then removed in the cyclone. The next stage incorporates a chilled water condenser which separates the vapors and elemental mercury from the off-gas steam. Primary off-gas deposit samples from the DWPF melter have previously been analyzed. In 2003, samples from just past the film cooler, from the inlet of the quencher and inside the quencher were analyzed at SRNL. It was determined that the samples were a mixture of sludge and glass frit. The major component was Si along with Fe, Al, and other elements in the radioactive waste being processed. The deposits analyzed also contained U-235 fission products and actinide elements. Prior to that, deposits in the off-gas system in the DWPF nonradioactive half scale melter and the one-tenth scale integrated DWPF melter system were analyzed and determined to be mixtures of alkali rich chlorides, sulfates, borates, and fluorides entrained with iron oxides, spinels and frit particles formed by vapor-phase transport and condensation. Additional work was performed in 2007 in which researchers similarly found the deposits to be a combination of sludge and frit particles.

  4. Extended Development Work to Validate a HLW Calcine Waste Form via INL's Cold Crucible Induction Melter

    SciTech Connect (OSTI)

    James A. King; Vince Maio

    2011-09-01

    To accomplish calcine treatment objectives, the Idaho Clean-up Project contractor, CWI, has chosen to immobilize the calcine in a glass-ceramic via the use of a Hot-Isostatic-Press (HIP); a treatment selection formally documented in a 2010 Record of Decision (ROD). Even though the HIP process may prove suitable for the calcine as specified in the ROD and validated in a number of past value engineering sessions, DOE is evaluating back-up treatment methods for the calcine as a result of the technical, schedule, and cost risk associated with the HIPing process. Consequently DOE HQ has requested DOE ID to make INL's bench-scale cold-crucible induction melter (CCIM) available for investigating its viability as a process alternate to calcine treatment. The waste form is the key component of immobilization of radioactive waste. Providing a solid, stable, and durable material that can be easily be stored is the rationale for immobilization of radioactive waste material in glass, ceramic, or glass-ceramics. Ceramic waste forms offer an alternative to traditional borosilicate glass waste forms. Ceramics can usually accommodate higher waste loadings than borosilicate glass, leading to smaller intermediate and long-term storage facilities. Many ceramic phases are known to possess superior chemical durability as compared to borosilicate glass. However, ceramics are generally multiphase systems containing many minor phase that make characterization and prediction of performance within a repository challenging. Additionally, the technologies employed in ceramic manufacture are typically more complex and expensive. Thus, many have proposed using glass-ceramics as compromise between in the more inexpensive, easier to characterize glass waste forms and the more durable ceramic waste forms. Glass-ceramics have several advantages over traditional borosilicate glasses as a waste form. Borosilicate glasses can inadvertently devitrify, leading to a less durable product that could crack during cooling and crystals may be prone to dissolution. By designing a glass-ceramics, the risks of deleterious effects from devitrification are removed. Furthermore, glass-ceramics have higher mechanical strength and impact strengths and possess greater chemical durability as noted above. Glass-ceramics should provide a waste form with the advantages of glass - ease of manufacture - with improved mechanical properties, thermal stability, and chemical durability. This report will cover aspects relevant for the validation of the CCIM use in the production of glass-ceramic waste forms.

  5. Impact Of Melter Internal Design On Off-Gas Flammability

    SciTech Connect (OSTI)

    Choi, A. S.; Lee, S. Y.

    2012-05-30

    The purpose of this study was to: (1) identify the more dominant design parameters that can serve as the quantitative measure of how prototypic a given melter is, (2) run the existing DWPF models to simulate the data collected using both DWPF and non-DWPF melter configurations, (3) confirm the validity of the selected design parameters by determining if the agreement between the model predictions and data is reasonably good in light of the design and operating conditions employed in each data set, and (4) run Computational Fluid Dynamics (CFD) simulations to gain new insights into how fluid mixing is affected by the configuration of melter internals and to further apply the new insights to explaining, for example, why the agreement is not good.

  6. Tunable molten oxide pool assisted plasma-melter vitrification systems

    DOE Patents [OSTI]

    Titus, Charles H. (Newtown Square, PA); Cohn, Daniel R. (Chestnut Hill, MA); Surma, Jeffrey E. (Kennewick, WA)

    1998-01-01

    The present invention provides tunable waste conversion systems and apparatus which have the advantage of highly robust operation and which provide complete or substantially complete conversion of a wide range of waste streams into useful gas and a stable, nonleachable solid product at a single location with greatly reduced air pollution to meet air quality standards. The systems provide the capability for highly efficient conversion of waste into high quality combustible gas and for high efficiency conversion of the gas into electricity by utilizing a high efficiency gas turbine or an internal combustion engine. The solid product can be suitable for various commercial applications. Alternatively, the solid product stream, which is a safe, stable material, may be disposed of without special considerations as hazardous material. In the preferred embodiment, the arc plasma furnace and joule heated melter are formed as a fully integrated unit with a common melt pool having circuit arrangements for the simultaneous independently controllable operation of both the arc plasma and the joule heated portions of the unit without interference with one another. The preferred configuration of this embodiment of the invention utilizes two arc plasma electrodes with an elongated chamber for the molten pool such that the molten pool is capable of providing conducting paths between electrodes. The apparatus may additionally be employed with reduced use or without further use of the gases generated by the conversion process. The apparatus may be employed as a net energy or net electricity producing unit where use of an auxiliary fuel provides the required level of electricity production. Methods and apparatus for converting metals, non-glass forming waste streams and low-ash producing inorganics into a useful gas are also provided. The methods and apparatus for such conversion include the use of a molten oxide pool having predetermined electrical, thermal and physical characteristics capable of maintaining optimal joule heating and glass forming properties during the conversion process.

  7. Baldwin Thermal Treatment Facility, Baldwin, Illinois: Organics and contaminated soils

    SciTech Connect (OSTI)

    Kipin, P.

    1997-12-31

    The Baldwin Thermal Treatment Facility is located at the Illinois Power Company`s Baldwin Power Plant, east of St. Louis, Missouri. It consists of two coal fired cyclone boilers and one pulverized coal boiler. Wastes are fed to the two cyclone boilers, at present. Future expansion to the pulverizer unit is planned. The boilers burn at 3,000 F with six seconds retention. This exceeds blast furnaces and most incinerators. An added feature is that the coal and waste materials are injected directly into the hottest zone immediately preventing any possible creation of dioxins. Up to 600 tons of waste per day can be fed to the boilers. This will increase when the third boiler is added to the permit. The facility can take a wide range of sizes and concentrations of coal tars and oils. The on-site process equipment will process these with on-site coal in varying proportions as required to ensure a stable uniform feed to the boiler. The on-site process equipment can process intermixed rock, metal, concrete, soil into a uniform blend with coal tars and coal. On-site decontamination of scrap metal is also provided for.

  8. Earth melter with rubble walls and method of use

    DOE Patents [OSTI]

    Chapman, Chris C. (Richland, WA)

    1998-01-01

    The present invention is an improvement to the earth melter described and claimed in U.S. Pat. No. 5,443,618. The improvement is the use of rubble for retaining walls. More specifically, the retaining walls rest on ground level and extend above ground level piling rubble around a melt zone. A portion of the melter may be below grade wherein sidewalls are formed by the relatively undisturbed native soil or rock, and the rubble may be used as a backfill liner for the below grade sidewalls.

  9. Extending Fuzzy System Concepts for Control of a Vitrification Melter

    SciTech Connect (OSTI)

    Whitehouse, J.C.; Sorgel, W.; Garrison, A.; Schalkoff, R.J.

    1995-08-16

    Fuzzy systems provide a mathematical framework to capture uncertainty. The complete description of real, complex systems or situations often requires far more detail and information than could ever be obtained (or understood). Fuzzy approaches are an alternative technology for both system control and information processing and management. In this paper, we present the design of a fuzzy control system for a melter used in the vitrification of hazardous waste. Design issues, especially those related to melter shutdown and obtaining smooth control surfaces, are addressed. Several extensions to commonly-applied fuzzy techniques, notably adaptive defuzzification and modified rule structures are developed.

  10. DM100 AND DM1200 MELTER TESTING WITH HIGH WASTE LOADING GLASS FORMULATIONS FOR HANFORD HIGH-ALUMINUM HLW STREAMS

    SciTech Connect (OSTI)

    KRUGER AA; MATLACK KS; KOT WK; PEGG IL; JOSEPH I

    2009-12-30

    This Test Plan describes work to support the development and testing of high waste loading glass formulations that achieve high glass melting rates for Hanford high aluminum high level waste (HLW). In particular, the present testing is designed to evaluate the effect of using low activity waste (LAW) waste streams as a source of sodium in place ofchemical additives, sugar or cellulose as a reductant, boehmite as an aluminum source, and further enhancements to waste processing rate while meeting all processing and product quality requirements. The work will include preparation and characterization of crucible melts in support of subsequent DuraMelter 100 (DM 100) tests designed to examine the effects of enhanced glass formulations, glass processing temperature, incorporation of the LAW waste stream as a sodium source, type of organic reductant, and feed solids content on waste processing rate and product quality. Also included is a confirmatory test on the HLW Pilot Melter (DM1200) with a composition selected from those tested on the DM100. This work builds on previous work performed at the Vitreous State Laboratory (VSL) for Department of Energy's (DOE's) Office of River Protection (ORP) to increase waste loading and processing rates for high-iron HLW waste streams as well as previous tests conducted for ORP on the same waste composition. This Test Plan is prepared in response to an ORP-supplied statement of work. It is currently estimated that the number of HLW canisters to be produced in the Hanford Tank Waste Treatment and Immobilization Plant (WTP) is about 12,500. This estimate is based upon the inventory ofthe tank wastes, the anticipated performance of the sludge treatment processes, and current understanding of the capability of the borosilicate glass waste form. The WTP HLW melter design, unlike earlier DOE melter designs, incorporates an active glass bubbler system. The bubblers create active glass pool convection and thereby improve heat transfer and glass melting rate. The WTP HLW melter has a glass surface area of 3.75 m{sup 2} and depth of {approx}1.1 m. The two melters in the HLW facility together are designed to produce up to 7.5 MT of glass per day at 100% availability. Further increases in HLW waste processing rates can potentially be achieved by increasing the melter operating temperature above 1150 C and by increasing the waste loading in the glass product Increasing the waste loading also has the added benefit of decreasing the number of canisters for storage. The current estimates and glass formulation efforts have been conservative in terms of achievable waste loadings. These formulations have been specified to ensure that the glasses are homogenous, contain essentially no crystalline phases, are processable in joule-heated, ceramic-lined melters and meet WTP contract requirements. The WTP's overall mission will require the immobilization oftank waste compositions that are dominated by mixtures of aluminum (Al), chromium (Cr), bismuth (Bi), iron (Fe), phosphorous (P), zirconium (Zr), and sulfur (S) compounds as waste-limiting components. Glass compositions for these waste mixtures have been developed based upon previous experience and current glass property models. Recently, DOE has initiated a testing program to develop and characterize HLW glasses with higher waste loadings. Results of this work have demonstrated the feasibility of increases in waste-loading from about 25 wt% to 33-50 wt% (based on oxide loading) in the glass depending on the waste stream. It is expected that these higher waste loading glasses will reduce the HLW canister production requirement by about 25% or more.

  11. Preliminary Analysis of Species Partitioning in the DWPF Melter

    SciTech Connect (OSTI)

    Choi, A.; Kesterson, M.; Johnson, F.; McCabe, D.

    2015-07-15

    The work described in this report is preliminary in nature since its goal was to demonstrate the feasibility of estimating the off-gas entrainment rates from the Defense Waste Processing Facility (DWPF) melter based on a simple mass balance using measured feed and glass pour stream compositions and timeaveraged melter operating data over the duration of one canister-filling cycle. The only case considered in this study involved the SB6 pour stream sample taken while Canister #3472 was being filled over a 20-hour period on 12/20/2010, approximately three months after the bubblers were installed. The analytical results for that pour stream sample provided the necessary glass composition data for the mass balance calculations. To estimate the “matching” feed composition, which is not necessarily the same as that of the Melter Feed Tank (MFT) batch being fed at the time of pour stream sampling, a mixing model was developed involving three preceding MFT batches as well as the one being fed at that time based on the assumption of perfect mixing in the glass pool but with an induction period to account for the process delays involved in the calcination/fusion step in the cold cap and the melter turnover.

  12. FINAL REPORT REGULATORY OFF GAS EMISSIONS TESTING ON THE DM1200 MELTER SYSTEM USING HLW AND LAW SIMULANTS VSL-05R5830-1 REV 0 10/31/05

    SciTech Connect (OSTI)

    KRUGER AA; MATLACK KS; GONG W; BARDAKCI T; D'ANGELO NA; BRANDYS M; KOT WK; PEGG IL

    2011-12-29

    The operational requirements for the River Protection Project - Waste Treatment Plant (RPP-WTP) Low Activity Waste (LAW) and High Level Waste (HLW) melter systems, together with the feed constituents, impose a number of challenges to the off-gas treatment system. The system must be robust from the standpoints of operational reliability and minimization of maintenance. The system must effectively control and remove a wide range of solid particulate matter, acid mists and gases, and organic constituents (including those arising from products of incomplete combustion of sugar and organics in the feed) to concentration levels below those imposed by regulatory requirements. The baseline design for the RPP-WTP LAW primary off-gas system includes a submerged bed scrubber (SBS), a wet electrostatic precipitator (WESP), and a high efficiency particulate air (HEPA) filter. The secondary off-gas system includes a sulfur-impregnated activated carbon bed (AC-S), a thermal catalytic oxidizer (TCO), a single-stage selective catalytic reduction NOx treatment system (SCR), and a packed-bed caustic scrubber (PBS). The baseline design for the RPP-WTP HLW primary off-gas system includes an SBS, a WESP, a high efficiency mist eliminator (HEME), and a HEPA filter. The HLW secondary off-gas system includes a sulfur-impregnated activated carbon bed, a silver mordenite bed, a TCO, and a single-stage SCR. The one-third scale HLW DM1200 Pilot Melter installed at the Vitreous State Laboratory (VSL) was equipped with a prototypical off-gas train to meet the needs for testing and confirmation of the performance of the baseline off-gas system design. Various modifications have been made to the DM1200 system as the details of the WTP design have evolved, including the installation of a silver mordenite column and an AC-S column for testing on a slipstream of the off-gas flow; the installation of a full-flow AC-S bed for the present tests was completed prior to initiation of testing. The DM1200 system was reconfigured to enable testing of the baseline HLW or LAW off-gas trains to perform off-gas emissions testing with both LAW and HLW simulants in the present work. During 2002 and 2003, many of these off-gas components were tested individually and in an integrated manner with the DM1200 Pilot Melter. Data from these tests are being used to support engineering design confirmation and to provide data to support air permitting activities. In fiscal year 2004, the WTP Project was directed by the Office of River Protection (ORP) to comply with Environmental Protection Agency (EPA) Maximum Achievable Control Technology (MACT) requirements for organics. This requires that the combined melter and off-gas system have destruction and removal efficiency (DRE) of >99.99% for principal organic dangerous constituents (PODCs). In order to provide confidence that the melter and off-gas system are able to achieve the required DRE, testing has been directed with both LAW and HLW feeds. The tests included both 'normal' and 'challenge' WTP melter conditions in order to obtain data for the potential range of operating conditions for the WTP melters and off-gas components. The WTP Project, Washington State Department of Ecology, and ORP have agreed that naphthalene will be used for testing to represent semi-volatile organics and allyl alcohol will be used to represent volatile organics. Testing was also performed to determine emissions of halides, metals, products of incomplete combustion (PICs), dioxins, furans, coplanar PCBs, total hydrocarbons, and COX and NOX, as well as the particle size distribution (PSD) of particulate matter discharged at the end of the off-gas train. A description of the melter test requirements and analytical methods used is provided in the Test Plan for this work. Test Exceptions were subsequently issued which changed the TCO catalyst, added total organic emissions (TOE) to exhaust sampling schedule, and allowing modification of the test conditions in response to attainable plenum temperatures as well as temperature increases in the sulfur impr

  13. High-Intensity Plasma Glass Melter Final Technical Report

    SciTech Connect (OSTI)

    Gonterman, J. Ronald; Weinstein, Michael A.

    2006-10-27

    The purpose of this project was to demonstrate the energy efficiency and reduced emissions that can be obtained with a dual torch DC plasma transferred arc-melting system. Plasmelt Glass Technologies, LLC was formed to solicit and execute the project, which utilize a full-scale test melter system. The system is similar to the one that was originally constructed by Johns Manville, but Plasmelt has added significant improvements to the torch design and melter system that has extended the original JM short torch lives. The original JM design has been shown to achieve melt rates 5 to 10 times faster than conventional gas or electric melting, with improved energy efficiency and reduced emissions. This project began on 7/28/2003 and ended 7/27/06. A laboratory scale melter was designed, constructed, and operated to conduct multiple experimental melting trials on various glass compositions. Glass quality was assessed. Although the melter design is generic and equally applicable to all sectors within the glass industry, the development of this melter has focused primarily on fiberglass with additional exploratory melting trials of frits, specialty, and minerals-melting applications. Throughput, energy efficiency, and glass quality have been shown to be heavily dependent on the selected glass composition. During this project, Plasmelt completed the proof-of-concept work in our Boulder, CO Lab to show the technical feasibility of this transferred-arc plasma melter. Late in the project, the work was focused on developing the processes and evaluating the economic viability of plasma melting aimed at the specific glasses of interest to specific client companies. Post project work is on going with client companies to address broader non-glass materials such as refractories and industrial minerals. Exploratory melting trials have been conducted on several glasses of commercial interest including: C-glass, E-glass, S-Glass, AR-Glass, B-glass, Lighting Glass, NE-Glass, and various frits. Exploratory melts of non-glassy materials, such as wollastonite, zirconium silicate, and alumino-silicate melts were successfully done indicating that plasma melting has potential application beyond glass. Experimental results were generated that show the high quality of plasma-melted fiberglass compositions, such as E-glass, can result in good fiberizing performance. Fiberizing performance and tensile strength data were achieved during the project to support this conclusion. High seed counts are a feature of the current lab scale melter and must be dealt with via other means, since fining work was outside the scope of this project.

  14. Savannah River Site Marks Waste Processing Milestone with Melter’s 2,000th Waste Canister

    Broader source: Energy.gov [DOE]

    AIKEN, S.C. – The second melter to operate in the 16-year history of the nation’s largest radioactive waste glassification plant shows no signs of slowing after recently pouring its 2,000 canister of glass-formed hazardous waste.

  15. Technical Exchange on Improved Design and Performance of High Level Waste Melters - Final Report

    SciTech Connect (OSTI)

    SK Sundaram; ML Elliott; D Bickford

    1999-11-19

    SIA Radon is responsible for management of low- and intermediate-level radioactive waste (LILW) produced in Central Russia. In cooperation with Minatom organizations Radon carries out R and D programs on treatment of simulated high level waste (HLW) as well. Radon scientists deal with a study of materials for LILW, HLW, and Nuclear Power Plants (NPP) wastes immobilization, and development and testing of processes and technologies for waste treatment and disposal. Radon is mostly experienced in LILW vitrification. This experience can be carried over to HLW vitrification especially in field of melting systems. The melter chosen as a basic unit for the vitrification plant is a cold crucible. Later on Radon experience in LILW vitrification as well as our results on simulated HLW vitrification are briefly described.

  16. GTS Duratek, phase I Hanford low-level waste melter tests: Final report

    SciTech Connect (OSTI)

    Eaton, W.C.

    1995-10-26

    A multiphase program was initiated in 1994 to test commercially available melter technologies for the vitrification of the low-level waste (LLW) stream from defense waste stored in underground tanks at the Hanford Site in southeastern Washington State. Phase 1 of the melter demonstration tests using simulated LLW was completed during fiscal year 1995. This document is the final report on testing performed by GTS Duratek Inc. in Columbia, Maryland. GTS Duratek (one of the seven vendors selected) was chosen to demonstrate Joule heated melter technology under WHC subcontract number MMI-SVV-384215. The report contains description of the tests, observations, test data and some analysis of the data as it pertains to application of this technology for LLW vitrification. The document also contains summaries of the melter offgas reports issued as separate documents for the 100 kg melter (WHC-SD-WM-VI-028) and for the 1000 kg melter (WHC-SD-WM-VI-029).

  17. Cold crucible induction melter studies for making glass ceramic waste forms: A feasibility assessment

    SciTech Connect (OSTI)

    Crum, Jarrod; Maio, Vince; McCloy, John; Scott, Clark; Riley, Brian; Benefiel, Brad; Vienna, John; Archibald, Kip; Rodriguez, Carmen; Rutledge, Veronica; Zhu, Zihua; Ryan, Joe; Olszta, Matthew

    2014-01-01

    Glass ceramics are being developed to immobilize fission products, separated from used nuclear fuel by aqueous reprocessing, into a stable waste form suitable for disposal in a geological repository. This work documents the glass ceramic formulation at bench scale and for a scaled melter test performed in a pilot-scale (approximately 1/4 scale) cold crucible induction melter (CCIM). Melt viscosity, electrical conductivity, and crystallization behavior upon cooling were measured on a small set of compositions to select a formulation for melter testing. Property measurements also identified a temperature range for melter operation and cooling profiles necessary to crystallize the targeted phases in the waste form. Bench scale and melter run results successfully demonstrate the processability of the glass ceramic using the CCIM melter technology.

  18. Independent Oversight Activity Report, Hanford Waste Treatment...

    Broader source: Energy.gov (indexed) [DOE]

    June 2013 Hanford Waste Treatment and Immobilization Plant Low Activity Waste Melter Off-gas Process System Hazards Analysis Activity Observation HIAR-WTP-2013-05-13 This...

  19. The Effect of Foaming and Silica Dissolution on Melter Feed Rheology...

    Office of Scientific and Technical Information (OSTI)

    dissolving refractory constituents are suspended together with numerous gas bubbles. Knowledge of mechanical properties of the melter feed is crucial for understanding the...

  20. Melter system technology testing for Hanford Site low-level tankwaste vitrification

    SciTech Connect (OSTI)

    Wilson, C.N.

    1996-05-03

    Following revisions to the Tri-Party Agreement for Hanford Site cleanup, which specified vitrification for Complete melter feasibility and system operability immobilization of the low-level waste (LLW) tests, select reference melter(s), and establish reference derived from retrieval and pretreatment of the radioactive LLW glass formulation that meets complete systems defense wastes stored in 177 underground tanks, commercial requirements (June 1996). Available melter technologies were tested during 1994 to 1995 as part of a multiphase program to select reference Submit conceptual design and initiate definitive design technologies for the new LLW vitrification mission.

  1. THERMAL TREATMENT REVIEW . WTE I THERMAL TREATMENT Since the beginning of this century, global waste-to-energy capacity

    E-Print Network [OSTI]

    Columbia University

    of new waste-to gasification process at an industrial scale The Waste-To-Energy Research and Technology Council (WTERT), headquartered at Columbia University in New York City, keeps a close watch on the thermal waste-to-energy capacity has increased steadily at the rate of about four million tonnes of MSW per year

  2. Standard guide for characterization of radioactive and/or hazardous wastes for thermal treatment

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2003-01-01

    1.1 This guide identifies methods to determine the physical and chemical characteristics of radioactive and/or hazardous wastes before a waste is processed at high temperatures, for example, vitrification into a homogeneous glass ,glass-ceramic, or ceramic waste form. This includes waste forms produced by ex-situ vitrification (ESV), in-situ vitrification (ISV), slagging, plasma-arc, hot-isostatic pressing (HIP) and/or cold-pressing and sintering technologies. Note that this guide does not specifically address high temperature waste treatment by incineration but several of the analyses described in this guide may be useful diagnostic methods to determine incinerator off-gas composition and concentrations. The characterization of the waste(s) recommended in this guide can be used to (1) choose and develop the appropriate thermal treatment methodology, (2) determine if waste pretreatment is needed prior to thermal treatment, (3) aid in development of thermal treatment process control, (4) develop surrogate wa...

  3. Evaluation of melter technologies for vitrification of Hanford site low-level tank waste - phase 1 testing summary report

    SciTech Connect (OSTI)

    Wilson, C.N., Westinghouse Hanford

    1996-06-27

    Following negotiation of the fourth amendment to the Tri- Party Agreement for Hanford Site cleanup, commercially available melter technologies were tested during 1994 and 1995 for vitrification of the low-level waste (LLW) stream to be derived from retrieval and pretreatment of the radioactive defense wastes stored in 177 underground tanks. Seven vendors were selected for Phase 1 testing to demonstrate vitrification of a high-sodium content liquid LLW simulant. The tested melter technologies included four Joule-heated melters, a carbon electrode melter, a combustion melter, and a plasma melter. Various dry and slurry melter feed preparation processes also were tested. The technologies and Phase 1 testing results were evaluated and a preliminary technology down-selection completed. This report describes the Phase 1 LLW melter vendor testing and the tested technologies, and summarizes the testing results and the preliminary technology recommendations.

  4. Three-Dimensional Thermal Tomography Advances Cancer Treatment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With U.S.Week DayDr. JeffreyThermalš,,ThomasDimensional

  5. Three-Dimensional Thermal Tomography Advances Cancer Treatment | Argonne

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With U.S.Week DayDr. JeffreyThermalš,,ThomasDimensionalNational

  6. FINAL REPORT TESTS ON THE DURAMELTER 1200 HLW PILOT MELTER SYSTEM USING AZ-101 HLW SIMULANTS VSL-02R0100-2 REV 1 2/17/03

    SciTech Connect (OSTI)

    KRUGER AA; MATLACK KS; KOT WK; BARDAKCI T; GONG W; D'ANGELO NA; SCHATZ TR; PEGG IL

    2011-12-29

    This document provides the final report on data and results obtained from a series of nine tests performed on the one-third scale DuraMelter{trademark} 1200 (DM1200) HLW Pilot Melter system that has been installed at VSL with an integrated prototypical off-gas treatment system. That system has replaced the DM1000 system that was used for HLW throughput testing during Part B1 [1]. Both melters have similar melt surface areas (1.2 m{sup 2}) but the DM1200 is prototypical of the present RPP-WTP HLW melter design whereas the DM1000 was not. These tests were performed under a corresponding RPP-WTP Test Specification and associated Test Plans. The nine tests reported here were preceded by an initial series of short-duration tests conducted to support the start-up and commissioning of this system. This report is a followup to the previously issued Preliminary Data Summary Reports. The DM1200 system was deployed for testing and confirmation of basic design, operability, flow sheet, and process control assumptions as well as for support of waste form qualification and permitting. These tests include data on processing rates, off-gas treatment system performance, recycle stream compositions, as well as process operability and reliability. Consequently, this system is a key component of the overall HLW vitrification development strategy. The primary objective of the present series of tests was to determine the effects of a variety of parameters on the glass production rate in comparison to the RPP-WTP HL W design basis of 400 kg/m{sup 2}/d. Previous testing on the DMIOOO system [1] concluded that achievement of that rate with simulants of projected WTP melter feeds (AZ-101 and C-106/AY-102) was unlikely without the use of bubblers. As part of those tests, the same feed that was used during the cold-commissioning of the West Valley Demonstration Project (WVDP) HLW vitrification system was run on the DM1000 system. The DM1000 tests reproduced the rates that were obtained at the larger WVDP facility, lending confidence to the tests results [1]. Since the inclusion or exclusion of a bubbler has significant design implications, the Project commissioned further tests to address this issue. In an effort to identify factors that might increase the glass production rate for projected WTP melter feeds, a subsequent series of tests was performed on the DM100 system. Several tests variables led to glass production rate increases to values significantly above the 400 kg/m2/d requirement. However, while small-scale melter tests are useful for screening relative effects, they tend to overestimate absolute glass production rates, particularly for un-bubbled tests. Consequently, when scale-up effects were taken into account, it was not clear that any of the variables investigated would conclusively meet the 400 kg/m{sup 2}/d requirement without bubbling. The present series of tests was therefore performed on the DM1200 one-third scale HLW pilot melter system to provide the required basis for a final decision on whether bubblers would be included in the HLW melter. The present tests employed the same AZ-101 waste simulant and glass composition that was used for previous testing for consistency and comparability with the results from the earlier tests.

  7. Melter system technology testing for Hanford Site low-level tank waste vitrification

    SciTech Connect (OSTI)

    Wilson, C.N. [Westinghouse Hanford Company, Richland, WA (United States)

    1996-12-31

    Following revisions to the Tri-Party Agreement for Hanford Site cleanup, which specified vitrification for immobilization of the low-level waste (LLW) stream to be derived from retrieval and pretreatment of the radioactive defense wastes stored in 177 underground tanks, commercially available melter technologies were tested during 1994 to 1995 as part of a multiphase program to select reference technologies for the new LLW vitrification mission. Seven vendors were selected for Phase 1 testing to demonstrate vitrification of a high-sodium content liquid LLW simulant. The tested melter technologies included four Joule-heated melters, a carbon electrode melter, a combustion melter, and a plasma melter. Various dry and slurry melter feed preparation processes were also tested. The technologies and Phase 1 testing results were evaluated and a preliminary technology down-selection and recommendations for Phase 2 testing completed. This paper describes the Phase 1 LLW melter vendor testing program and the tested technologies, and summarizes the testing results and the preliminary technology recommendations.

  8. Thermal and high magnetic field treatment of materials and associated apparatus

    DOE Patents [OSTI]

    Kisner, Roger A.; Wilgen, John B.; Ludtka, Gerard M.; Jaramillo, Roger A.; Mackiewicz-Ludtka, Gail

    2010-06-29

    An apparatus and method for altering characteristics, such as can include structural, magnetic, electrical, optical or acoustical characteristics, of an electrically-conductive workpiece utilizes a magnetic field within which the workpiece is positionable and schemes for thermally treating the workpiece by heating or cooling techniques in conjunction with the generated magnetic field so that the characteristics of the workpiece are effected by both the generated magnetic field and the thermal treatment of the workpiece.

  9. Hanford low-level vitrification melter testing -- Master list of data submittals

    SciTech Connect (OSTI)

    Hendrickson, D.W.

    1995-03-15

    The Westinghouse Hanford Company (WHC) is conducting a two-phased effort to evaluate melter system technologies for vitrification of liquid low-level radioactive waste (LLW) streams. The evaluation effort includes demonstration testing of selected glass melter technologies and technical reports regarding the applicability of the glass melter technologies to the vitrification of Hanford LLW tank waste. The scope of this document is to identify and list vendor document submittals in technology demonstration support of the Hanford Low-Level Waste Vitrification melter testing program. The scope of this document is limited to those documents responsive to the Statement of Work, accepted and issued by the LLW Vitrification Program. The purpose of such a list is to maintain configuration control of vendor supplied data and to enable ready access to, and application of, vendor supplied data in the evaluation of melter technologies for the vitrification of Hanford low-level tank wastes.

  10. Cold Crucible Induction Melter Studies for Making Glass Ceramic Waste Forms: A Feasibility Assessment

    SciTech Connect (OSTI)

    Crum, Jarrod V.; Maio, Vincent; McCloy, John S.; Scott, Clark; Riley, Brian J.; Benefiel, Bradley; Vienna, John D.; Archibald, Kip; Rodriguez, Carmen P.; Rutledge, Veronica; Zhu, Zihua; Ryan, Joseph V.; Olszta, Matthew J.

    2014-01-01

    Glass ceramics are being developed to immobilize fission products, separated from used nuclear fuel by aqueous reprocessing, into a stable waste form suitable for disposal in a geological repository. This work documents the glass ceramic formulation at bench scale and for a scaled melter test performed in a pilot-scale (~1/4 scale) cold crucible induction meter (CCIM). Melt viscosity, electrical conductivity, and crystallization behavior upon cooling were measured on a small set of compositions to select a formulation for melter testing. Property measurements also identified a temperature range for melter operation and cooling profiles necessary to crystallize the targeted phases in the waste form. Bench scale and melter run results successfully demonstrate the processability of the glass ceramic using the CCIM melter technology.

  11. Review of the integrated thermal and nonthermal treatment system studies. Final report

    SciTech Connect (OSTI)

    NONE

    1996-10-01

    This report contains a review and evaluation of three systems analysis studies performed by LITCO on integrated thermal treatment systems and integrated nonthermal treatment systems for the remediation of mixed low-level waste stored throughout the US Department of Energy weapons complex. The review was performed by an independent team of nine researchers from the Energy and Environmental Research Center, Science Applications International Corporation, the Waste Policy Institute, and Virginia Tech. The three studies reviewed were as follows: Integrated Thermal Treatment System Study, Phase 1 -- issued July 1994; Integrated Thermal Treatment System Study, Phase 2 -- issued February 1996; and Integrated Nonthermal Treatment System Study -- drafted March 1996. The purpose of this review was to (1) determine whether the assumptions of the studies were adequate to produce an unbiased review of both thermal and nonthermal systems, (2) to identify the critical areas of the studies that would benefit from further investigation, and (3) to develop a standard template that could be used in future studies to assure a sound application of systems engineering.

  12. Integrated Pilot Plant for a Large Cold Crucible Induction Melter

    SciTech Connect (OSTI)

    Do Quang, R.; Jensen, A.; Prod'homme, A.; Fatoux, R.; Lacombe, J.

    2002-02-26

    COGEMA has been vitrifying high-level liquid waste produced during nuclear fuel reprocessing on an industrial scale for over 20 years, with two main objectives: containment of the long lived fission products and reduction of the final volume of waste. Research performed by the French Atomic Energy Commission (CEA) in the 1950s led to the selection of borosilicate glass as the most suitable containment matrix for waste from spent nuclear fuel and to the development of the induction melter technology. This was followed by the commissioning of the Marcoule Vitrification Facility (AVM) in 1978. The process was implemented at a larger scale in the late 1980s in the R7 and T7 facilities of the La Hague reprocessing plant. COGEMA facilities have produced more than 11,000 high level glass canisters, representing more than 4,500 metric tons of glass and 4.5 billion curies. To further improve the performance of the vitrification lines in the R7 and T7 facilities, the CEA and COGEMA have been developing the Cold Crucible Melter (CCM) technology since the 1980s. This technology benefits from the 20 years of COGEMA HLW vitrification experience and ensures a virtually unlimited equipment service life and extensive flexibility in dealing with different types of waste. The high specific power directly transferred by induction to the melt allows high operating temperatures without any impact on the process equipment. In addition, the mechanical stirring of the melter significantly reduces operating constraints. COGEMA is already providing the CCM technology to international customers for nuclear and non-nuclear applications and plans to implement it in the La Hague vitrification plant for the vitrification of highly concentrated and corrosive solutions produced by uranium/molybdenum fuel reprocessing. The paper presents the CCM project that led to the building and start-up of this evolutionary and flexible pilot plant. It also describes the plant's technical characteristics and reports commissioning results.

  13. Technical information report: Plasma melter operation, reliability, and maintenance analysis

    SciTech Connect (OSTI)

    Hendrickson, D.W. [ed.

    1995-03-14

    This document provides a technical report of operability, reliability, and maintenance of a plasma melter for low-level waste vitrification, in support of the Hanford Tank Waste Remediation System (TWRS) Low-Level Waste (LLW) Vitrification Program. A process description is provided that minimizes maintenance and downtime and includes material and energy balances, equipment sizes and arrangement, startup/operation/maintence/shutdown cycle descriptions, and basis for scale-up to a 200 metric ton/day production facility. Operational requirements are provided including utilities, feeds, labor, and maintenance. Equipment reliability estimates and maintenance requirements are provided which includes a list of failure modes, responses, and consequences.

  14. Resistance heater for use in a glass melter

    DOE Patents [OSTI]

    Routt, K.R.; Porter, M.A.

    1984-01-01

    A resistance heating element that includes: a resistance heating medium of a mixture of electrically conductive and insulative particles in powdered form mixed together in predetermined proportions to achieve a given resistivity; a hollow outer electrode surrounding the resistance heating medium; and an inner electrode coaxially disposed within said outer electrode. In its preferred embodiments, the electrically conductive powder is selected from the group consisting essentially of graphite, Inconel alloy, molybdenum, nichrome alloy and stainless steel, while the insulator powder is silicon dioxide or alumina. The resistance heating element, being resistant to damage from mechanical shock and corrosion at elevated temperatures, is used in a glass melter.

  15. Reduction of carbon content in waste-tire combustion ashes by bio-thermal treatment

    SciTech Connect (OSTI)

    Chen, C.C.; Lee, W.J.; Shih, S.I.; Mou, J.L.

    2009-07-01

    Application of bio-catalyst (NOE-7F) in thermal treatment can adequately dispose dark-black fly ashes from co-combustion of both waste tires and coal. After thermal treatment of fly ashes by adding 10% NOE-7F, the carbon contents reduced by 37.6% and the weight losses increased by 405%, compared with the fly ashes without mixing with NOE-7F. The combustion behaviors of wasted tires combustion fly ashes with NOE-7F were also investigated by both thermogravimetric analysis (TGA) and differential thermal analysis (DTA). The results verify that NOE-7F has positive effects on the combustion of residual carbon and toxic polycyclic aromatic hydrocarbons (PAHs) enhance the energy release and reduce the toxicity during the process of thermal treatment. Furthermore, using NOE-7F to dispose high-carbon content fly ashes did improve the compressive strength of fly ashes and concrete mixtures. Therefore, NOE-7F is a promising additive which could decrease treatment cost of high-carbon content fly ashes and reduce the amount of survival toxic PAHs.

  16. Pressurized heat treatment of glass-ceramic to control thermal expansion

    DOE Patents [OSTI]

    Kramer, Daniel P. (Dayton, OH)

    1985-01-01

    A method of producing a glass-ceramic having a specified thermal expansion value is disclosed. The method includes the step of pressurizing the parent glass material to a predetermined pressure during heat treatment so that the glass-ceramic produced has a specified thermal expansion value. Preferably, the glass-ceramic material is isostatically pressed. A method for forming a strong glass-ceramic to metal seal is also disclosed in which the glass-ceramic is fabricated to have a thermal expansion value equal to that of the metal. The determination of the thermal expansion value of a parent glass material placed in a high-temperature environment is also used to determine the pressure in the environment.

  17. Operation of a bushing melter system designed for actinide vitrification

    SciTech Connect (OSTI)

    Ramsey, W.G.

    1996-03-01

    The Westinghouse Savannah River Company is developing a melter system to vitrify actinide materials. The melter system will used to vitrify the americium and curium solution which is currently stored in one of the Savannah River Site`s (SRS) processing canyons. This solution is one of the materials designated by the Defense Nuclear Facilities Safety Board (DNFSB) to be dispositioned as part of the DNFSB recommendation 94-1. The Am/Cm solution contains an extremely large fraction (>2 kilograms of Cm and 10 kilograms of Am) of t he United States`s total inventory of both elements. They have an estimated value on the order of one billion dollars - if they are processed through the DOE Isotope Sales program at the Oak Ridge National Laboratory. It is therefore deemed highly desirable to transfer the material to Oak Ridge in a form which can allow for recovery of the material. A commercial glass composition has been demonstrated to be compatible with up to 40 weight percent of the Am/Cm solution contents. This glass is also selectively attacked by nitric acid. This allows the actinide to be recovered by common separation processes.

  18. Self-cleaning feed distributing delivery device for glass melters

    DOE Patents [OSTI]

    Mensink, Daniel L. (155 Gatewood Dr., Aiken, SC 29801)

    1992-01-01

    A self cleaning, plug resistant, adjustable parameter feed distributing and delivery apparatus for a glass melter comprising a housing with a passage therethrough for a glass slurry, a cold finger within the passage for creating a dispersion pattern of the slurry, a movable slotted tube for controlling the confluence of air propellant and slurry in the passage, and a plurality of ribs that extend through the slots in the slotted tube to urge the slurry forward if it becomes stuck or resists forward movement. Coolant passages in the housing and the cold finger maintain the slurry temperature below that of the melter plenum. The cold finger is axially movable to adjust the dispersion pattern to the desired consistency. Other design features of size can be applied for use in situations requiring different parameters of pattern, particle size, rate, and feed consistencies. The device utilizes air as both a propellant and a surface cleansing mechanism. Other fluids may be used as propellants where process compatibility requires.

  19. Evaluation Pilot-Scale Melter Systems for the Direct Vitrification Development Program

    SciTech Connect (OSTI)

    Mc Cray, Casey William; Thomson, Troy David

    2001-09-01

    This report documents the results of an evaluation conducted to identify a joule-heated melter system that could be installed in the Idaho Falls area in support of the Direct Vitrification Development Program. The relocation was to be completed by January 1, 2002, within a total budget of one million dollars. Coordination with the Department of Energy Tanks Focus Area identified five melters or melter systems that could potentially support the Direct Vitrification Development Program. Each unit was inspected and evaluated based on qualitative criteria such as availability, completeness of the system, contamination, scalability, materials of construction, facility requirements, and any unique features.

  20. Vectra GSI, Inc. low-level waste melter testing Phase 1 test report

    SciTech Connect (OSTI)

    Stegen, G.E.; Wilson, C.N.

    1996-02-21

    A multiphase program was initiated in 1994 to test commercially available melter technologies for the vitrification of the low-level waste (LLW) stream from defense wastes stored in underground tanks at the Hanford Site in southeastern Washington State. Vectra GSI, Inc. was one of seven vendors selected for Phase 1 of the melter demonstration tests using simulated LLW that were completed during fiscal year 1995. The attached report prepared by Vectra GSI, Inc. describes results of melter testing using slurry feed and dried feeds. Results of feed drying and prereaction tests using a fluid bed calciner and rotary dryer also are described.

  1. EA-0821: Final Environmental Assessment

    Office of Energy Efficiency and Renewable Energy (EERE)

    Operation of the Glass Melter Thermal Treatment Unit at the U.S. Department of Energy's Mound Plant, Miamisburg, Ohio

  2. Comparison of discrete and continuous thermal neutron scattering treatments in MCNP5

    SciTech Connect (OSTI)

    Pavlou, A. T. [Univ. of Michigan, Dept. of Nuclear Engineering and Radiological Sciences, 2355 Bonisteel Boulevard, Ann Arbor, MI 48109 (United States); Brown, F. B. [Los Alamos National Laboratory, Monte Carlo Codes Group, MS A143, PO Box 1663, Los Alamos, NM 87545 (United States); Martin, W. R. [Univ. of Michigan, Dept. of Nuclear Engineering and Radiological Sciences, 2355 Bonisteel Boulevard, Ann Arbor, MI 48109 (United States); Kiedrowski, B. C. [Los Alamos National Laboratory, Monte Carlo Codes Group, MS A143, PO Box 1663, Los Alamos, NM 87545 (United States)

    2012-07-01

    The standard discrete thermal neutron S({alpha},{beta}) scattering treatment in MCNP5 is compared with a continuous S({alpha},{beta}) scattering treatment using a criticality suite of 119 benchmark cases and ENDF/B-VII.0 nuclear data. In the analysis, six bound isotopes are considered: beryllium metal, graphite, hydrogen in water, hydrogen in polyethylene, beryllium in beryllium oxide and oxygen in beryllium oxide. Overall, there are only small changes in the eigenvalue (k{sub eff}) between discrete and continuous treatments. In the comparison of 64 cases that utilize S({alpha},{beta}) scattering, 62 agreed at the 95% confidence level, and the 2 cases with differences larger than 3 {sigma} agreed within 1 {sigma} when more neutrons were run in the calculations. The results indicate that the changes in eigenvalue between continuous and discrete treatments are random, small, and well within the uncertainty of measured data for reactor criticality experiments. (authors)

  3. Incorporating Cold Cap Behavior in a Joule-heated Waste Glass Melter Model

    SciTech Connect (OSTI)

    Varija Agarwal; Donna Post Guillen

    2013-08-01

    In this paper, an overview of Joule-heated waste glass melters used in the vitrification of high level waste (HLW) is presented, with a focus on the cold cap region. This region, in which feed-to-glass conversion reactions occur, is critical in determining the melting properties of any given glass melter. An existing 1D computer model of the cold cap, implemented in MATLAB, is described in detail. This model is a standalone model that calculates cold cap properties based on boundary conditions at the top and bottom of the cold cap. Efforts to couple this cold cap model with a 3D STAR-CCM+ model of a Joule-heated melter are then described. The coupling is being implemented in ModelCenter, a software integration tool. The ultimate goal of this model is to guide the specification of melter parameters that optimize glass quality and production rate.

  4. Thermal-Light-Induced Coherent Dynamics in Atoms and Molecules -- an Exact Quantum Mechanical Treatment

    E-Print Network [OSTI]

    David Avisar; Asaf Eilam; A. D. Wilson-Gordon

    2015-05-01

    The question of whether sunlight induces coherent dynamics in biological systems is under debate. Here we show, on the basis of an exact fully quantum mechanical treatment, that thermal light induces excited-state coherences in matter similar to those induced by a coherent state. We demonstrate the phenomenon on a V-type model system and a two-state Born-Oppenheimer molecular system. Remarkably, wavepacket-like dynamics is induced in the excited molecular potential-energy surface.

  5. U.S. Bureau of Mines, Phase 1 Hanford low-level waste melter tests. Final report

    SciTech Connect (OSTI)

    Eaton, W.C. [Westinghouse Hanford Co., Richland, WA (United States); Oden, L.L.; O`Connor, W.K. [Bureau of Mines, Albany, OR (United States). Albany Research Center

    1995-11-01

    A multiphase program was initiated in 1994 to test commercially available melter technologies for the vitrification of the low-level waste (LLW) stream from defense wastes stored in underground tanks at the Hanford Site in southeastern Washington State. Phase 1 of the melter demonstration tests using simulated LLW was completed during fiscal year 1995. This document is the melter offgas report on testing performed by the U.S. Department of the Interior, Bureau of Mines, Albany Research Center in Albany, Oregon. The Bureau of Mines (one of the seven vendors selected) was chosen to demonstrate carbon electrode melter technology (also called carbon arc or electric arc) under WHC Subcontract number MMI-SVV-384216. The report contains description of the tests, observation, test data and some analysis of the data as it pertains to application of this technology for LLW vitrification. Testing consisted of melter feed preparation and three melter tests, the first of which was to fulfill the requirements of the statement of work (WHC-SD-EM-RD-044), and the second and third were to address issues identified during the first test. The document also contains summaries of the melter offgas report issued as a separate document U.S. Bureau of Mines, Phase 1 Hanford Low-Level Waste Melter Tests: Melter Offgas Report (WHC-SD-WM-VI-032).

  6. Influence of surface modification adopting thermal treatments on dispersion of detonation nanodiamond

    SciTech Connect (OSTI)

    Xu Xiangyang . E-mail: xiangyang.xu@sohu.com; Yu Zhiming; Zhu Yongwei; Wang Baichun

    2005-03-15

    In order to improve the dispersion of detonation nanodiamonds (ND) in aqueous and non-aqueous media, a series of thermal treatments have been conducted in air ambient to modify ND surface. Small angle X-ray scattering (SAXS) technique and high resolution transmission electron microscopy (HRTEM) were introduced to observe the primary size of ND. Differential thermal analysis (DTA), X-ray diffraction (XRD) methodology, X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FTIR) spectroscopy were adopted to analyze the structure, bonds at surfaces of the treated ND. Malvern instrument Zetasizer3000HS was used for measuring the surface electric potential and the size distribution of ND. As thermal treatments can cause graphitization and oxidization of functional groups at the surface, ND treated at high temperature is correspondingly more negatively charged in an aqueous medium, and the increased absolute value of zeta potential ensures the electrostatic stability of ND particles. Specially, after being treated at a temperature more than 850K, ND can be well dispersed in various media.

  7. Non-Thermal Plasmas for NOx Treatment Y.N. Jaffre, T. Aka-Ngnui and A. Beroual

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Selective Catalytic Reduction (SCR) processes can be improved for NOx reduction by a Non- Thermal Plasma. European norm (standard specification) EURO 6 im- poses a reduction of 50% on automotive NOx emissionsNon-Thermal Plasmas for NOx Treatment Y.N. Jaffr´e, T. Aka-Ngnui and A. Beroual Ecole Centrale de

  8. Thermal treatment effects on charge storage performance of graphene-based materials for supercapacitors

    SciTech Connect (OSTI)

    Zhang, Hongxin; Bhat, Vinay V; Gallego, Nidia C; Contescu, Cristian I

    2012-01-01

    Graphene materials were synthesized by reduction of exfoliated graphene oxide sheets by hydrazine hydrate and then thermally treated in nitrogen to improve the surface area and their electrochemical performance as electrical double-layer capacitor electrodes. The structural and surface properties of the prepared reduced graphite oxide (RGO) were investigated using atomic force microscopy, scanning electron microscopy, Raman spectra, X-ray diffraction, and nitrogen adsorption / desorption. RGO forms a continuous network of crumpled sheets, which consist of numerous few-layer and single-layer graphenes. Electrochemical studies were conducted by cyclic voltammetry, impedance spectroscopy, and galvanostatic charge-discharge measurements. The modified RGO materials showed enhanced electrochemical performance, with maximum specific capacitance of 96 F/g, energy density of 12.8 Wh/kg, and power density of 160 kW/kg. The results demonstrate that thermal treatment of RGO at selected conditions is a convenient and efficient method for improving specific capacitance, energy, and power density.

  9. SMALL-SCALE MELTER TESTING WITH LAW SIMULANTS TO ASSESS THE IMPACT OF HIGHER TEMPERATURE MELTER OPERATIONS - Final Report, VSL-04R49801-1, Rev. 0, 2/13/03, Vitreous State Laboratory, The Catholic University of America, Washington, D.C.

    SciTech Connect (OSTI)

    KRUGER AA; MATLACK KS

    2012-02-07

    About 50 million gallons of high-level mixed waste is currently in storage in underground tanks at The United States Department of Energy's (DOE's) Hanford site in the State of Washington. The Hanford Tank Waste Treatment and Immobilization Plant (WTP) will provide DOE's Office of River Protection (ORP) with a means of treating this waste by vitrification for subsequent disposal. The tank waste will be separated into low- and high-activity fractions, which will then be vitrified respectively into Immobilized Low Activity Waste (ILAW) and Immobilized High Level Waste (IHLW) products. The ILAW product will be disposed of in an engineered facility on the Hanford site while the IHL W product will be directed to the national deep geological disposal facility for high-level nuclear waste. The ILAW and IHLW products must meet a variety of requirements with respect to protection of the environment before they can be accepted for disposal. The Office of River Protection is currently examining options to optimize the Low Activity Waste (LAW) facility and the LAW glass waste form. One option under evaluation is to enhance the waste processing rate of the vitrification plant currently under construction. It is likely that the capacity of the LAW vitrification plant can be increased incrementally by implementation of a variety of low-risk, high-probability changes, either separately or in combination. These changes include: (1) Operating at the higher processing rates demonstrated at the LAW Pilot Melter; (2) Increasing the glass pool surface area within the existing external melter envelope; (3) Increasing plant availability; (4) Increasing the glass waste loading; (5) Removing sulfate from the LAW stream; (6) Operating the melter at slightly higher temperature; (7) Installing the third LAW melter into the WTP plant; and (8) Other smaller impact changes. The tests describes in this report utilized blended feed (glass formers plus waste simulant) prepared by Optima Chemicals according to VSL specifications. Sufficient feed was prepared to produce nearly two metric tons of glass. Sugar was added (at VSL) to the feed at a ratio of 0.5 (1 mole sucrose per 16 mole NOx). The DM100-WV melter was used in order to provide a direct comparison with the LAW tests previously conducted on the same melter. Two 75-hour melter tests were conducted at two elevated temperatures, 1175 and 1225 C. These tests were preceded by the production of sufficient glass to turn over the melt pool to the target composition. Key operating parameters were held constant to investigate the effects of the operating temperature on processing characteristics, particularly melting rate. At each operating temperature, the feed rate was adjusted to provide a near-complete cold cap 99-100% of melt surface covered with feed. Quantitative measurements of glass production rates, melter operating conditions (temperatures, pressures, power, flows, etc.), and off-gas characteristics (NOx, SO{sub 2}, CO, particulate load and composition, and acid gases) were made for each test.

  10. Analysis of the Production Cost for Various Grades of Biomass Thermal Treatment

    SciTech Connect (OSTI)

    Robert S Cherry; Rick A. Wood; Tyler L Westover

    2013-12-01

    Process flow sheets were developed for the thermal treatment of southern pine wood chips at four temperatures (150, 180, 230, and 270 degrees C) and two different scales (20 and 100 ton/hour). The larger capacity processes had as their primary heat source hot gas assumed to be available in quantity from an adjacent biorefinery. Mass and energy balances for these flow sheets were developed using Aspen Plus process simulation software. The hot gas demands in the larger processes, up to 1.9 million lb/hour, were of questionable feasibility because of the volume to be moved. This heat was of low utility because the torrefaction process, especially at higher temperatures, is a net heat producer if the organic byproduct gases are burned. A thermal treatment flow sheet using wood chips dried in the biorefinery to 10% moisture content (rather than 30% for green chips) with transfer of high temperature steam from the thermal treatment depot to the biorefinery was also examined. The equipment size information from all of these cases was used in several different equipment cost estimating methods to estimate the major equipment costs for each process. From these, factored estimates of other plant costs were determined, leading to estimates (+ / - 30% accuracy) of total plant capital cost. The 20 ton/hour processes were close to 25 million dollars except for the 230 degrees C case using dried wood chips which was only 15 million dollars because of its small furnace. The larger processes ranged from 64-120 million dollars. From these capital costs and projections of several categories of operating costs, the processing cost of thermally treated pine chips was found to be $28-33 per ton depending on the degree of treatment and without any credits for steam generation. If the excess energy output of the two 20 ton/hr depot cases at 270 degrees C can be sold for $10 per million BTU, the net processing cost dropped to $13/ton product starting with green wood chips or only $3 per ton if using dried chips from the biorefinery. Including a 12% return on invested capital raised all of the operating cost results by about $20/ton.

  11. A method to characterize the influence of air distribution on the composting treatment: monitoring of the thermal fields

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 A method to characterize the influence of air distribution on the composting treatment of air distribution on the composting treatment: monitoring of the thermal fields Hénon Florent a:anne.tremier@cemagref.fr Abstract In a composting process the monitoring of heat flows is a useful tool in terms of phenomenological

  12. Vaporization of actinide oxides in thermal treatment processes for mixed waste

    SciTech Connect (OSTI)

    Ebbinghaus, B.B.; Krikorian, O.H.; Adamson, M.G.

    1994-10-04

    The purpose of this study is to evaluate the volatilities of U, Pu, and Am in thermal treatment processes for mixed wastes. The thermodynamics of vaporization U and Pu oxides in the presence of oxygen and water vapor and of U oxide in the presence of oxygen and chlorine were studied. Experimental studies of U oxide volatilities by previous authors have also been reviewed. For species where data are unavailable estimation methods were used to obtain free energies of formation of the gaseous species, The data are applied to thermal treatment processes in general and then more specifically to conditions representative of the Rocky Flats Plant Fluidized Bed Unit. (RFP FBU), molten salt oxidizer, and an incinerator. U volatilities are greatest ranging from 2.67 x 10{sup -7} gU/h in the RFP FBU to 4. 00 gU/h for typical incinerator conditions. Pu volatilities are almost 5 orders of magnitude less than U and Am volatilities are about 3 orders of magnitude less than Pu.

  13. The influence of thermal treatment on the preparation of PMN and PMN-PT thin films

    SciTech Connect (OSTI)

    Spagnol, P.D.; Valadares, L.F.; Varela, J.A.; Bertochi, M.A.Z

    2003-03-15

    Ferroelectric thin films belong to a class of materials with great technological importance in optic fibers, microelectromechanical systems, and microprocessors and computers memories. The (1-x)PbMg{sub 1/3}Nb{sub 2/3}O{sub 3}(x)PbTiO{sub 3} (PMN-PT) thin films, with x=0, 0.1, 0.35 and 0.5, were prepared by Pechini's process and deposited by spin-coating on Si(100), Pt/Ti/SiO{sub 2}/Si(100) and quartz substrates. The goal of the present paper is to verify the thermal treatment influence on the perovskite phase formation, which is desirable for these applications. The phase formation was analyzed by X-ray diffraction. The film's surface was characterized by atomic force microscopy to analyze the roughness and the homogeneity. The results of this study indicate that the optimum conditions for obtaining the perovskite phase using a Pt/Ti/SiO{sub 2}/Si(100) substrate, were drying each deposited layer at 140 deg. C (heating plate), and a final thermal treatment at 600 deg. C for 3 h in a closed system with a lead-rich atmosphere.

  14. The Effect of Foaming and Silica Dissolution on Melter Feed Rheology during Conversion to Glass

    SciTech Connect (OSTI)

    Marcial, Jose; Chun, Jaehun; Hrma, Pavel R.; Schweiger, Michael J.

    2014-11-23

    As the nuclear waste glass melter feed is converted to molten glass, the feed eventually becomes a continuous glass-forming melt in which dissolving refractory constituents are suspended together with numerous gas bubbles. Knowledge of mechanical properties of the melter feed is crucial for understanding the feed-to-glass conversion as it occurs in the cold cap. We measured the viscosity during heating of the feed and correlated it with the independently determined volume fractions of dissolving quartz particles and the gas phase. The measurement was performed with a rotating spindle rheometer on the melter feed heated at 5 K/min starting at several different temperatures. The effect of quartz particles, gas bubbles, and compositional inhomogeneity on the glass-forming melt viscosity was determined by fitting a linear relationship between log viscosity and volume fractions of suspended phases to data.

  15. Volatilization and redox testing in a DC arc melter: FY-93 and FY-94

    SciTech Connect (OSTI)

    Grandy, J.D.; Sears, J.W.; Soelberg, N.R.; Reimann, G.A.; McIlwain, M.E.

    1996-07-01

    The purpose of these experiments was to study the dissolution, retention, volatilization, and trapping of transuranic radionuclide elements (TRUs), mixed fission and activation products, and high vapor pressure metals (HVPMS) during processing in a high temperature arc furnace. In all cases, surrogate elements (lanthanides) were used in place of radioactive ones. The experiments were conducted utilizing a small DC arc melter developed at the Idaho National Engineering Laboratory (INEL) Research Center (IRC). The small arc melter was originally developed in 1992 and has been used previously for waste form studies of iron enriched basalt (IEB) and IEB with zirconium and titanium additions (IEB4). Section 3 contains a description of the small arc melter and its operational capabilities are discussed in Chapter 4. The remainder of the document describes each testing program and then discusses results and findings.

  16. Underground Coal Thermal Treatment Task 6 Topical Report, Utah Clean Coal Program

    SciTech Connect (OSTI)

    Smith, P.J.; Deo, M.; Edding, E.G.; Hradisky, M.; Kelly, K.E.; Krumm, R.; Sarofim, Adel; Wang, D.

    2014-08-15

    The long-term objective of this task is to develop a transformational energy production technology by in- situ thermal treatment of a coal seam for the production of substitute natural gas and/or liquid transportation fuels while leaving much of the coal’s carbon in the ground. This process converts coal to a high-efficiency, low-greenhouse gas (GHG) emitting fuel. It holds the potential of providing environmentally acceptable access to previously unusable coal resources. This task focused on three areas: • Experimental. The Underground Coal Thermal Treatment (UCTT) team focused on experiments at two scales, bench-top and slightly larger, to develop data to understand the feasibility of a UCTT process as well as to develop validation/uncertainty quantification (V/UQ) data for the simulation team. • Simulation. The investigators completed development of High Performance Computing (HPC) simulations of UCTT. This built on our simulation developments over the course of the task and included the application of Computational Fluid Dynamics (CFD)- based tools to perform HPC simulations of a realistically sized domain representative of an actual coal field located in Utah. • CO2 storage. In order to help determine the amount of CO2 that can be sequestered in a coal formation that has undergone UCTT, adsorption isotherms were performed on coals treated to 325, 450, and 600°C with slow heating rates. Raw material was sourced from the Sufco (Utah), Carlinville (Illinois), and North Antelope (Wyoming) mines. The study indicated that adsorptive capacity for the coals increased with treatment temperature and that coals treated to 325°C showed less or similar capacity to the untreated coals.

  17. Waste-Incidental-to-Reprocessing Evaluation for the West Valley Demonstration Project Vitrification Melter - 12167

    SciTech Connect (OSTI)

    McNeil, Jim; Kurasch, David; Sullivan, Dan; Crandall, Thomas

    2012-07-01

    The Department of Energy (DOE) has determined that the vitrification melter used in the West Valley Demonstration Project can be disposed of as low-level waste (LLW) after completion of a waste-incidental-to-reprocessing evaluation performed in accordance with the evaluation process of DOE Manual 435.1-1, Radioactive Waste Management Manual. The vitrification melter - which consists of a ceramic lined, electrically heated box structure - was operated for more than 5 years melting and fusing high-level waste (HLW) slurry and glass formers and pouring the molten glass into 275 stainless steel canisters. Prior to shutdown, the melter was decontaminated by processing low-activity decontamination flush solutions and by extracting molten glass from the melter cavity. Because it could not be completely emptied, residual radioactivity conservatively estimated at approximately 170 TBq (4,600 Ci) remained in the vitrification melter. To establish whether the melter was incidental to reprocessing, DOE prepared an evaluation to demonstrate that the vitrification melter: (1) had been processed to remove key radionuclides to the maximum extent technically and economically practical; (2) would be managed to meet safety requirements comparable to the performance objectives for LLW established by the Nuclear Regulatory Commission (NRC); and (3) would be managed by DOE in accordance with DOE's requirements for LLW after it had been incorporated in a solid physical form with radionuclide concentrations that do not exceed the NRC concentration limits for Class C LLW. DOE consulted with the NRC on the draft evaluation and gave other stakeholders an opportunity to submit comments before the determination was made. The NRC submitted a request for additional information in connection with staff review of the draft evaluation; DOE provided the additional information and made improvements to the evaluation, which was issued in January 2012. DOE considered the NRC Technical Evaluation Report as well as comments received from other stakeholders prior to making its determination that the vitrification melter is not HLW, does not require permanent isolation in a geologic repository, and can be disposed of as LLW. (authors)

  18. Noble Metals and Spinel Settling in High Level Waste Glass Melters

    SciTech Connect (OSTI)

    Sundaram, S. K.; Perez, Joseph M.

    2000-09-30

    In the continuing effort to support the Defense Waste Processing Facility (DWPF), the noble metals issue is addressed. There is an additional concern about the amount of noble metals expected to be present in the future batches that will be considered for vitrification in the DWPF. Several laboratory, as well as melter-scale, studies have been completed by various organizations (mainly PNNL, SRTC, and WVDP in the USA). This letter report statuses the noble metals issue and focuses at the settling of noble metals in melters.

  19. TECHNETIUM RETENTION IN WTP LAW GLASS WITH RECYCLE FLOW-SHEET DM10 MELTER TESTING VSL-12R2640-1 REV 0

    SciTech Connect (OSTI)

    Abramowitz, Howard; Brandys, Marek; Cecil, Richard; D'Angelo, Nicholas; Matlack, Keith S.; Muller, Isabelle S.; Pegg, Ian L.; Callow, Richard A.; Joseph, Innocent

    2012-12-11

    Melter tests were conducted to determine the retention of technetium and other volatiles in glass while processing simulated Low Activity Waste (LAW) streams through a DM10 melter equipped with a prototypical off-gas system that concentrates and recycles fluid effiuents back to the melter feed. To support these tests, an existing DM10 system installed at Vitreous State Laboratory (VSL) was modified to add the required recycle loop. Based on the Hanford Tank Waste Treatment and Immobilization Plant (WTP) LAW off-gas system design, suitably scaled versions of the Submerged Bed Scrubber (SBS), Wet Electrostatic Precipitator (WESP), and TLP vacuum evaporator were designed, built, and installed into the DM10 system. Process modeling was used to support this design effort and to ensure that issues associated with the short half life of the {sup 99m}Tc radioisotope that was used in this work were properly addressed and that the system would be capable of meeting the test objectives. In particular, this required that the overall time constant for the system was sufficiently short that a reasonable approach to steady state could be achieved before the {sup 99m}Tc activity dropped below the analytical limits of detection. The conceptual design, detailed design, flow sheet development, process model development, Piping and Instrumentation Diagram (P&ID) development, control system design, software design and development, system fabrication, installation, procedure development, operator training, and Test Plan development for the new system were all conducted during this project. The new system was commissioned and subjected to a series of shake-down tests before embarking on the planned test program. Various system performance issues that arose during testing were addressed through a series of modifications in order to improve the performance and reliability of the system. The resulting system provided a robust and reliable platform to address the test objectives.

  20. Defining And Characterizing Sample Representativeness For DWPF Melter Feed Samples

    SciTech Connect (OSTI)

    Shine, E. P.; Poirier, M. R.

    2013-10-29

    Representative sampling is important throughout the Defense Waste Processing Facility (DWPF) process, and the demonstrated success of the DWPF process to achieve glass product quality over the past two decades is a direct result of the quality of information obtained from the process. The objective of this report was to present sampling methods that the Savannah River Site (SRS) used to qualify waste being dispositioned at the DWPF. The goal was to emphasize the methodology, not a list of outcomes from those studies. This methodology includes proven methods for taking representative samples, the use of controlled analytical methods, and data interpretation and reporting that considers the uncertainty of all error sources. Numerous sampling studies were conducted during the development of the DWPF process and still continue to be performed in order to evaluate options for process improvement. Study designs were based on use of statistical tools applicable to the determination of uncertainties associated with the data needs. Successful designs are apt to be repeated, so this report chose only to include prototypic case studies that typify the characteristics of frequently used designs. Case studies have been presented for studying in-tank homogeneity, evaluating the suitability of sampler systems, determining factors that affect mixing and sampling, comparing the final waste glass product chemical composition and durability to that of the glass pour stream sample and other samples from process vessels, and assessing the uniformity of the chemical composition in the waste glass product. Many of these studies efficiently addressed more than one of these areas of concern associated with demonstrating sample representativeness and provide examples of statistical tools in use for DWPF. The time when many of these designs were implemented was in an age when the sampling ideas of Pierre Gy were not as widespread as they are today. Nonetheless, the engineers and statisticians used carefully thought out designs that systematically and economically provided plans for data collection from the DWPF process. Key shared features of the sampling designs used at DWPF and the Gy sampling methodology were the specification of a standard for sample representativeness, an investigation that produced data from the process to study the sampling function, and a decision framework used to assess whether the specification was met based on the data. Without going into detail with regard to the seven errors identified by Pierre Gy, as excellent summaries are readily available such as Pitard [1989] and Smith [2001], SRS engineers understood, for example, that samplers can be biased (Gy?s extraction error), and developed plans to mitigate those biases. Experiments that compared installed samplers with more representative samples obtained directly from the tank may not have resulted in systematically partitioning sampling errors into the now well-known error categories of Gy, but did provide overall information on the suitability of sampling systems. Most of the designs in this report are related to the DWPF vessels, not the large SRS Tank Farm tanks. Samples from the DWPF Slurry Mix Evaporator (SME), which contains the feed to the DWPF melter, are characterized using standardized analytical methods with known uncertainty. The analytical error is combined with the established error from sampling and processing in DWPF to determine the melter feed composition. This composition is used with the known uncertainty of the models in the Product Composition Control System (PCCS) to ensure that the wasteform that is produced is comfortably within the acceptable processing and product performance region. Having the advantage of many years of processing that meets the waste glass product acceptance criteria, the DWPF process has provided a considerable amount of data about itself in addition to the data from many special studies. Demonstrating representative sampling directly from the large Tank Farm tanks is a difficult, if not unsolvable enterprise due to li

  1. Gaseous and particulate emissions from a DC arc melter

    SciTech Connect (OSTI)

    Overcamp, T.J.; Speer, M.P.; Griner, S.J.; Cash, D.M. [Clemson Univ., Anderson, SC (United States)

    1997-12-31

    This paper presents the results of the gaseous and particulate emissions from eight experimental tests of a DC arc melter to treat simulated Savannah River soils contaminated with metals, surrogates for radionuclides, and organic debris. The gaseous analyses reported on the concentrations of oxygen, hydrogen, carbon monoxide, carbon dioxide, hydrogen, methane, nitric oxide, and nitrogen dioxide. The carbon dioxide concentration was high for all runs. For the runs with an air purge, the carbon monoxide concentration ranged up to 10% in the runs with the debris and 2% in the runs without debris. Hydrogen ranged up to 5% by with debris and up to 1% without debris. The methane concentration ranged up to 7,000 ppm{sub v} for the runs with debris and 2,000 ppm for the runs without debris. With a nitrogen purge, oxygen concentrations were less than 1%. The carbon dioxide concentrations ranged from 3 to 15%. Much of this carbon dioxide was probably due the carbonates added to the feed material. The carbon monoxide concentration ranged up to 20% with the debris and 7% without debris. Hydrogen was above 6% in with debris and up to 6% without debris. The methane concentration ranged up to 10,000 ppm{sub v} with debris and 4,000 ppm{sub v} without debris. The particulate concentrations exiting ranged from 32 to 145 g/m{sup 3}. From the chemical analyses, the primary elements were silicon and calcium. The CHN analyses indicated that carbon, probably as carbonates, are an additional component in the particulate matter. The estimated emissions were at a level of 3% or less for cerium, up to 7% for nickel, and 11 to 30% for cesium.

  2. FINAL REPORT START-UP AND COMMISSIONING TESTS ON THE DURAMELTER 1200 HLW PILOT MELTER SYSTEM USING AZ-101 HLW SIMULANTS VSL-01R0100-2 REV 0 1/20/03

    SciTech Connect (OSTI)

    KRUGER AA; MATLACK KS; KOT WK; BRANDYS M; WILSON CN; SCHATZ TR; GONG W; PEGG IL

    2011-12-29

    This document provides the final report on data and results obtained from commissioning tests performed on the one-third scale DuraMelter{trademark} 1200 (DM 1200) HLW Pilot Melter system that has been installed at VSL with an integrated prototypical off-gas treatment system. That system has replaced the DM1000 system that was used for HLW throughput testing during Part BI [1]. Both melters have similar melt surface areas (1.2 m{sup 2}) but the DM1200 is prototypical of the present RPP-WTP HLW melter design whereas the DM1000 was not. These tests were performed under a corresponding RPP-WTP Test Specification and associated Test Plan. This report is a followup to the previously issued Preliminary Data Summary Report. The DM1200 system will be used for testing and confirmation of basic design, operability, flow sheet, and process control assumptions as well as for support of waste form qualification and permitting. This will include data on processing rates, off-gas treatment system performance, recycle stream compositions, as well as process operability and reliability. Consequently, this system is a key component of the overall HLW vitrification development strategy. The results presented in this report are from the initial series of short-duration tests that were conducted to support the start-up and commissioning of this system prior to conducting the main body of development tests that have been planned for this system. These tests were directed primarily at system 'debugging,' operator training, and procedure refinement. The AZ-101 waste simulant and glass composition that was used for previous testing was selected for these tests.

  3. Partitioning planning studies: Preliminary evaluation of metal and radionuclide partitioning the high-temperature thermal treatment systems

    SciTech Connect (OSTI)

    Liekhus, K.; Grandy, J.; Chambers, A.

    1997-03-01

    A preliminary study of toxic metals and radionuclide partitioning during high-temperature processing of mixed waste has been conducted during Fiscal Year 1996 within the Environmental Management Technology Evaluation Project. The study included: (a) identification of relevant partitioning mechanisms that cause feed material to be distributed between the solid, molten, and gas phases within a thermal treatment system; (b) evaluations of existing test data from applicable demonstration test programs as a means to identify and understand elemental and species partitioning; and, (c) evaluation of theoretical or empirical partitioning models for use in predicting elemental or species partitioning in a thermal treatment system. This preliminary study was conducted to identify the need for and the viability of developing the tools capable of describing and predicting toxic metals and radionuclide partitioning in the most applicable mixed waste thermal treatment processes. This document presents the results and recommendations resulting from this study that may serve as an impetus for developing and implementing these predictive tools.

  4. Effects of thermal treatment of nanostructured trititanates on their crystallographic and textural properties

    SciTech Connect (OSTI)

    Morgado, Edisson; Jardim, Paula M.; Araujo, Antonio S.

    2007-09-04

    Nanostructured titanates (TTNT) with general formula Na {sub x}H{sub 2-x}Ti{sub 3}O{sub 7}.nH{sub 2}O were synthesized by hydrothermally reacting different TiO{sub 2} anatase (distinct crystal sizes) with NaOH at 120 deg. C followed by washing with water or diluted acid and drying of the precipitate. The resulting powders with different sodium contents were submitted to various calcination temperatures up to 800 deg. C and each calcined product was characterized as for its phase structure, composition, crystallite size and textural properties, namely BET surface area, mesopore volume and pore size distribution. Thermal transformations of TTNT samples were investigated by monitoring the modifications on crystallographic (X-ray diffraction) and textural (N{sub 2} desorption isotherms) properties, revealing the influence of the type of starting anatase and sodium content over the stability of TTNT. Moreover, a detailed study on the reduction of the interlayer distance in TTNT samples upon thermal treatment allowed corroborating the formation of an intermediate nanostructured hexatitanate, just before phase transformation into the corresponding TiO{sub 2} polymorphs and/or titanate crystals, depending on the sodium content and calcination temperature.

  5. Characterization of the solid low level mixed waste inventory for the solid waste thermal treatment activity - III

    SciTech Connect (OSTI)

    Place, B.G., Westinghouse Hanford

    1996-09-24

    The existing thermally treatable, radioactive mixed waste inventory is characterized to support implementation of the commercial, 1214 thermal treatment contract. The existing thermally treatable waste inventory has been identified using a decision matrix developed by Josephson et al. (1996). Similar to earlier waste characterization reports (Place 1993 and 1994), hazardous materials, radionuclides, physical properties, and waste container data are statistically analyzed. In addition, the waste inventory data is analyzed to correlate waste constituent data that are important to the implementation of the commercial thermal treatment contract for obtaining permits and for process design. The specific waste parameters, which were analyzed, include the following: ``dose equivalent`` curie content, polychlorinated biphenyl (PCB) content, identification of containers with PA-related mobile radionuclides (14C, 12 79Se, 99Tc, and U isotopes), tritium content, debris and non-debris content, container free liquid content, fissile isotope content, identification of dangerous waste codes, asbestos containers, high mercury containers, beryllium dust containers, lead containers, overall waste quantities, analysis of container types, and an estimate of the waste compositional split based on the thermal treatment contractor`s proposed process. A qualitative description of the thermally treatable mixed waste inventory is also provided.

  6. Composition of Municipal Solid Waste-Need for Thermal Treatment in the present Indian context

    E-Print Network [OSTI]

    Columbia University

    , Biomethanation, pelletization with or without energy recovery and other thermal processes for adoption

  7. The production of advanced glass ceramic HLW forms using cold crucible induction melter

    SciTech Connect (OSTI)

    Rutledge, V.J.; Maio, V. [Idaho National Laboratory: P.O. Box 1625, Idaho Falls, ID, 83415-2110 (United States)

    2013-07-01

    Cold Crucible Induction Melters (CCIM) will favorably change how High-Level radioactive Waste (from nuclear fuel recovery) is treated in a near future. Unlike the existing Joule-Heated Melters (JHM) currently in operation for the glass-based immobilization of High-Level Waste (HLW), CCIM offers unique material features that will increase melt temperatures, increase throughput, increase mixing, increase loading in the waste form, lower melter foot prints, eliminate melter corrosion and lower costs. These features not only enhance the technology for producing HLW forms, but also provide advantageous attributes to the waste form by allowing more durable alternatives to glass. It is concluded that glass ceramic waste forms that are tailored to immobilize fission products of HLW can be can be made from the HLW processed with the CCIM. The advantageous higher temperatures reached with the CCIM and unachievable with JHM allows the lanthanides, alkali, alkaline earths, and molybdenum to dissolve into a molten glass. Upon controlled cooling they go into targeted crystalline phases to form a glass ceramic waste form with higher waste loadings than achievable with borosilicate glass waste forms. Natural cooling proves to be too fast for the formation of all targeted crystalline phases.

  8. The Production of Advanced Glass Ceramic HLW Forms using Cold Crucible Induction Melter

    SciTech Connect (OSTI)

    Veronica J Rutledge; Vince Maio

    2013-10-01

    Cold Crucible Induction Melters (CCIMs) will favorably change how High-Level radioactive Waste (from nuclear fuel recovery) is treated in the 21st century. Unlike the existing Joule-Heated Melters (JHMs) currently in operation for the glass-based immobilization of High-Level Waste (HLW), CCIMs offer unique material features that will increase melt temperatures, increase throughput, increase mixing, increase loading in the waste form, lower melter foot prints, eliminate melter corrosion and lower costs. These features not only enhance the technology for producing HLW forms, but also provide advantageous attributes to the waste form by allowing more durable alternatives to glass. This paper discusses advantageous features of the CCIM, with emphasis on features that overcome the historical issues with the JHMs presently utilized, as well as the benefits of glass ceramic waste forms over borosilicate glass waste forms. These advantages are then validated based on recent INL testing to demonstrate a first-of-a-kind formulation of a non-radioactive ceramic-based waste form utilizing a CCIM.

  9. ROLE OF MANGANESE REDUCTION/OXIDATION (REDOX) ON FOAMING AND MELT RATE IN HIGH LEVEL WASTE (HLW) MELTERS (U)

    SciTech Connect (OSTI)

    Jantzen, C; Michael Stone, M

    2007-03-30

    High-level nuclear waste is being immobilized at the Savannah River Site (SRS) by vitrification into borosilicate glass at the Defense Waste Processing Facility (DWPF). Control of the Reduction/Oxidation (REDOX) equilibrium in the DWPF melter is critical for processing high level liquid wastes. Foaming, cold cap roll-overs, and off-gas surges all have an impact on pouring and melt rate during processing of high-level waste (HLW) glass. All of these phenomena can impact waste throughput and attainment in Joule heated melters such as the DWPF. These phenomena are caused by gas-glass disequilibrium when components in the melter feeds convert to glass and liberate gases such as H{sub 2}O vapor (steam), CO{sub 2}, O{sub 2}, H{sub 2}, NO{sub x}, and/or N{sub 2}. During the feed-to-glass conversion in the DWPF melter, multiple types of reactions occur in the cold cap and in the melt pool that release gaseous products. The various gaseous products can cause foaming at the melt pool surface. Foaming should be avoided as much as possible because an insulative layer of foam on the melt surface retards heat transfer to the cold cap and results in low melt rates. Uncontrolled foaming can also result in a blockage of critical melter or melter off-gas components. Foaming can also increase the potential for melter pressure surges, which would then make it difficult to maintain a constant pressure differential between the DWPF melter and the pour spout. Pressure surges can cause erratic pour streams and possible pluggage of the bellows as well. For these reasons, the DWPF uses a REDOX strategy and controls the melt REDOX between 0.09 {le} Fe{sup 2+}/{summation}Fe {le} 0.33. Controlling the DWPF melter at an equilibrium of Fe{sup +2}/{summation}Fe {le} 0.33 prevents metallic and sulfide rich species from forming nodules that can accumulate on the floor of the melter. Control of foaming, due to deoxygenation of manganic species, is achieved by converting oxidized MnO{sub 2} or Mn{sub 2}O{sub 3} species to MnO during melter preprocessing. At the lower redox limit of Fe{sup +2}/{summation}Fe {approx} 0.09 about 99% of the Mn{sup +4}/Mn{sup +3} is converted to Mn{sup +2}. Therefore, the lower REDOX limits eliminates melter foaming from deoxygenation.

  10. MODELING THE IMPACT OF ELEVATED MERCURY IN DEFENSE WASTE PROCESSING FACILITY MELTER FEED ON THE MELTER OFF-GAS SYSTEM - PRELIMINARY REPORT

    SciTech Connect (OSTI)

    Zamecnik, J.; Choi, A.

    2009-03-25

    The Defense Waste Processing Facility (DWPF) is currently evaluating an alternative Chemical Process Cell (CPC) flowsheet to increase throughput. It includes removal of the steam-stripping step, which would significantly reduce the CPC processing time and lessen the sampling needs. However, its downside would be to send 100% of the mercury that come in with the sludge straight to the melter. For example, the new mercury content in the Sludge Batch 5 (SB5) melter feed is projected to be 25 times higher than that in the SB4 with nominal steam stripping of mercury. This task was initiated to study the impact of the worst-case scenario of zero-mercury-removal in the CPC on the DWPF melter off-gas system. It is stressed that this study is intended to be scoping in nature, so the results presented in this report are preliminary. In order to study the impact of elevated mercury levels in the feed, it is necessary to be able to predict how mercury would speciate in the melter exhaust under varying melter operating conditions. A homogeneous gas-phase oxidation model of mercury by chloride was developed to do just that. The model contains two critical parameters pertaining to the partitioning of chloride among HCl, Cl, Cl{sub 2}, and chloride salts in the melter vapor space. The values for these parameters were determined at two different melter vapor space temperatures by matching the calculated molar ratio of HgCl (or Hg{sub 2}Cl{sub 2}) to HgCl{sub 2} with those measured during the Experimental-Scale Ceramic Melter (ESCM) tests run at the Pacific Northwest National Laboratory (PNNL). The calibrated model was then applied to the SB5 simulant used in the earlier flowsheet study with an assumed mercury stripping efficiency of zero; the molar ratio of Cl-to-Hg in the resulting melter feed was only 0.4, compared to 12 for the ESCM feeds. The results of the model run at the indicated melter vapor space temperature of 650 C (TI4085D) showed that due to excessive shortage of chloride, only 6% of the mercury fed is expected to get oxidized, mostly as HgCl, while the remaining mercury would exist either as elemental mercury vapor (90%) or HgO (4%). Noting that the measured chloride level in the SB5 qualification sample was an order of magnitude lower than that used in the SB5 simulant, the degree of chloride shortage will be even greater. As a result, the projected level of HgCl in the actual SB5 melter exhaust will be even lower than 6% of the total mercury fed, while that of elemental mercury is likely to be greater than 90%. The homogeneous oxidation of mercury in the off-gas was deemed to be of primary importance based on the postulation that mercury and other volatile salts form submicron sized aerosols upon condensation and thus remain largely in the gas stream downstream of the quencher where they can deposit in the off-gas lines, Steam-Atomized Scrubbers (SAS), and High-Efficiency Mist Eliminator (HEME). Formation of these submicron semi-volatile salts in the condensate liquid is considered to be unlikely, so the liquid phase reactions were considered to be less important. However, subsequent oxidation of mercury in the liquid phase in the off-gas system was examined in a simplified model of the off-gas condensate. It was found that the condensate chemistry was consistent with further oxidation of elemental mercury to Hg{sub 2}Cl{sub 2} and conversion of HgO to chlorides. The results were consistent with the available experimental data. It should also be noted that the model predictions presented in this report do not include any physically entrained solids, which typically account for much of the off-gas carryover on a mass basis. The high elemental mercury vapor content predicted at the DWPF Quencher inlet means that physically entrained solids could provide the necessary surface onto which elemental mercury vapor could condense, thereby coating the solids as well as the internal surfaces of the off-gas system with mercury. Clearly, there are many process benefits to be gained by removing the steam-stripping step from the CPC c

  11. MODELING THE IMPACT OF ELEVATED MERCURY IN DEFENSE WASTE PROCESSING FACILITY MELTER FEED ON THE MELTER OFF-GAS SYSTEM-PRELIMINARY REPORT

    SciTech Connect (OSTI)

    Zamecnik, J.; Choi, A.

    2010-08-18

    The Defense Waste Processing Facility (DWPF) is currently evaluating an alternative Chemical Process Cell (CPC) flowsheet to increase throughput. It includes removal of the steam-stripping step, which would significantly reduce the CPC processing time and lessen the sampling needs. However, its downside would be to send 100% of the mercury that comes in with the sludge straight to the melter. For example, the new mercury content in the Sludge Batch 5 (SB5) melter feed is projected to be 25 times higher than that in the SB4 with nominal steam stripping of mercury. This task was initiated to study the impact of the worst-case scenario of zero-mercury-removal in the CPC on the DWPF melter offgas system. It is stressed that this study is intended to be scoping in nature, so the results presented in this report are preliminary. In order to study the impact of elevated mercury levels in the feed, it is necessary to be able to predict how mercury would speciate in the melter exhaust under varying melter operating conditions. A homogeneous gas-phase oxidation model of mercury by chloride was developed to do just that. The model contains two critical parameters pertaining to the partitioning of chloride among HCl, Cl, Cl{sub 2}, and chloride salts in the melter vapor space. The values for these parameters were determined at two different melter vapor space temperatures by matching the calculated molar ratio of HgCl (or Hg{sub 2}Cl{sub 2}) to HgCl{sub 2} with those measured during the Experimental-Scale Ceramic Melter (ESCM) tests run at the Pacific Northwest National Laboratory (PNNL). The calibrated model was then applied to the SB5 simulant used in the earlier flowsheet study with an assumed mercury stripping efficiency of zero; the molar ratio of Cl-to-Hg in the resulting melter feed was only 0.4, compared to 12 for the ESCM feeds. The results of the model run at the indicated melter vapor space temperature of 650 C (TI4085D) showed that due to excessive shortage of chloride, only 6% of the mercury fed is expected to get oxidized, mostly as HgCl, while the remaining mercury would exist either as elemental mercury vapor (90%) or HgO (4%). Noting that the measured chloride level in the SB5 qualification sample was an order of magnitude lower than that used in the SB5 simulant, the degree of chloride shortage will be even greater. As a result, the projected level of HgCl in the actual SB5 melter exhaust will be even lower than 6% of the total mercury fed, while that of elemental mercury is likely to be greater than 90%. The homogeneous oxidation of mercury in the off-gas was deemed to be of primary importance based on the postulation that mercury and other volatile salts form submicron sized aerosols upon condensation and thus remain largely in the gas stream downstream of the quencher where they can deposit in the off-gas lines, Steam-Atomized Scrubbers (SAS), and High-Efficiency Mist Eliminator (HEME). Formation of these submicron semi-volatile salts in the condensate liquid is considered to be unlikely, so the liquid phase reactions were considered to be less important. However, subsequent oxidation of mercury in the liquid phase in the off-gas system was examined in a simplified model of the off-gas condensate. It was found that the condensate chemistry was consistent with further oxidation of elemental mercury to Hg{sub 2}Cl{sub 2} and conversion of HgO to chlorides. The results were consistent with the available experimental data. It should also be noted that the model predictions presented in this report do not include any physically entrained solids, which typically account for much of the off-gas carryover on a mass basis. The high elemental mercury vapor content predicted at the DWPF Quencher inlet means that physically entrained solids could provide the necessary surface onto which elemental mercury vapor could condense, thereby coating the solids as well as the internal surfaces of the off-gas system with mercury. Clearly, there are many process benefits to be gained by removing the steam-stripping step from the CPC c

  12. MELTER OFF-GAS FLAMMABILITY ASSESSMENT FOR DWPF ALTERNATE REDUCTANT FLOWSHEET OPTIONS

    SciTech Connect (OSTI)

    Choi, A.

    2011-07-08

    Glycolic acid and sugar are being considered as potential candidates to substitute for much of the formic acid currently being added to the Defense Waste Processing Facility (DWPF) melter feed as a reductant. A series of small-scale melter tests were conducted at the Vitreous State Laboratory (VSL) in January 2011 to collect necessary data for the assessment of the impact of these alternate reductants on the melter off-gas flammability. The DM10 melter with a 0.021 m{sup 2} melt surface area was run with three different feeds which were prepared at SRNL based on; (1) the baseline formic/nitric acid flowsheet, (2) glycolic/formic/nitric acid flowsheet, and (3) sugar/formic/nitric acid flowsheet - these feeds will be called the baseline, glycolic, and sugar flowsheet feeds, respectively, hereafter. The actual addition of sugar to the sugar flowsheet feed was made at VSL before it was fed to the melter. For each feed, the DM10 was run under both bubbled (with argon) and non-bubbled conditions at varying melter vapor space temperatures. The goal was to lower its vapor space temperature from nominal 500 C to less than 300 C at 50 C increments and maintain steady state at each temperature at least for one hour, preferentially for two hours, while collecting off-gas data including CO, CO{sub 2}, and H{sub 2} concentrations. Just a few hours into the first test with the baseline feed, it was discovered that the DM10 vapor space temperature would not readily fall below 350 C simply by ramping up the feed rate as the test plan called for. To overcome this, ambient air was introduced directly into the vapor space through a dilution air damper in addition to the natural air inleakage occurring at the operating melter pressure of -1 inch H{sub 2}O. A detailed description of the DM10 run along with all the data taken is given in the report issued by VSL. The SRNL personnel have analyzed the DM10 data and identified 25 steady state periods lasting from 32 to 92 minutes for all six melter runs (bubbled and non-bubbled runs for each of the three feeds). The steady state selection was made by limiting the standard deviation of the average vapor space temperature readings from two bare thermocouples (TT-03 and TT-05) to less than 5 C in most cases at a constant feed rate. The steady state data thus selected were mass and heat balanced and the off-gas data were re-baselined to assess the flammability potential of each feed under the DWPF melter operating conditions. Efforts were made to extract as much information out of the data as possible necessary to extend the applicability of the existing baseline cold cap and off-gas combustion models to the glycolic and sugar flowsheet feeds. This report details the outcome of these activities.

  13. Vitrification of HLW Produced by Uranium/Molybdenum Fuel Reprocessing in COGEMA's Cold Crucible Melter

    SciTech Connect (OSTI)

    Do Quang, R.; Petitjean, V.; Hollebecque, F.; Pinet, O.; Flament, T.; Prod'homme, A.

    2003-02-25

    The performance of the vitrification process currently used in the La Hague commercial reprocessing plants has been continuously improved during more than ten years of operation. In parallel COGEMA (industrial Operator), the French Atomic Energy Commission (CEA) and SGN (respectively COGEMA's R&D provider and Engineering) have developed the cold crucible melter vitrification technology to obtain greater operating flexibility, increased plant availability and further reduction of secondary waste generated during operations. The cold crucible is a compact water-cooled melter in which the radioactive waste and the glass additives are melted by direct high frequency induction. The cooling of the melter produces a solidified glass layer that protects the melter's inner wall from corrosion. Because the heat is transferred directly to the melt, high operating temperatures can be achieved with no impact on the melter itself. COGEMA plans to implement the cold crucible technology to vitrify high level liquid waste from reprocessed spent U-Mo-Sn-Al fuel (used in gas cooled reactor). The cold crucible was selected for the vitrification of this particularly hard-to-process waste stream because it could not be reasonably processed in the standard hot induction melters currently used at the La Hague vitrification facilities : the waste has a high molybdenum content which makes it very corrosive and also requires a special high temperature glass formulation to obtain sufficiently high waste loading factors (12 % in molybdenum). A special glass formulation has been developed by the CEA and has been qualified through lab and pilot testing to meet standard waste acceptance criteria for final disposal of the U-Mo waste. The process and the associated technologies have been also being qualified on a full-scale prototype at the CEA pilot facility in Marcoule. Engineering study has been integrated in parallel in order to take into account that the Cold Crucible should be installed remotely in one of the R7 vitrification cell. This paper will present the results obtained in the framework of these qualification programs.

  14. Active cooling-based surface confinement system for thermal soil treatment

    DOE Patents [OSTI]

    Aines, R.D.; Newmark, R.L.

    1997-10-28

    A thermal barrier is disclosed for surface confinement with active cooling to control subsurface pressures during thermal remediation of shallow (5-20 feet) underground contaminants. If steam injection is used for underground heating, the actively cooled thermal barrier allows the steam to be injected into soil at pressures much higher (20-60 psi) than the confining strength of the soil, while preventing steam breakthrough. The rising steam is condensed to liquid water at the thermal barrier-ground surface interface. The rapid temperature drop forced by the thermal barrier drops the subsurface pressure to below atmospheric pressure. The steam and contaminant vapors are contained by the thermal blanket, which can be made of a variety of materials such as steel plates, concrete slabs, membranes, fabric bags, or rubber bladders. 1 fig.

  15. Active cooling-based surface confinement system for thermal soil treatment

    DOE Patents [OSTI]

    Aines, Roger D. (Livermore, CA); Newmark, Robin L. (Pleasanton, CA)

    1997-01-01

    A thermal barrier is disclosed for surface confinement with active cooling to control subsurface pressures during thermal remediation of shallow (5-20 feet) underground contaminants. If steam injection is used for underground heating, the actively cooled thermal barrier allows the steam to be injected into soil at pressures much higher (20-60 psi) than the confining strength of the soil, while preventing steam breakthrough. The rising steam is condensed to liquid water at the thermal barrier-ground surface interface. The rapid temperature drop forced by the thermal barrier drops the subsurface pressure to below atmospheric pressure. The steam and contaminant vapors are contained by the thermal blanket, which can be made of a variety of materials such as steel plates, concrete slabs, membranes, fabric bags, or rubber bladders.

  16. Department of Energy Manual 435.1-1 Waste Incidental To Reprocessing Determination For The West Valley Demonstration Project Concentrator Feed Makeup Tank and Melter Feed Hold Tank

    Broader source: Energy.gov [DOE]

    Department of Energy Manual 435.1-1 Waste Incidental To Reprocessing Determination For The West Valley Demonstration Project Concentrator Feed Makeup Tank and Melter Feed Hold Tank

  17. INTEGRATED DM 1200 MELTER TESTING OF HLW C-106/AY-102 COMPOSITION USING BUBBLERS VSL-03R3800-1 REV 0 9/15/03

    SciTech Connect (OSTI)

    KRUGER AA; MATLACK KS; GONG W; BARDAKCI T; D'ANGELO NA; KOT WK; PEGG IL

    2011-12-29

    This report documents melter and off-gas performance results obtained on the DM1200 HLW Pilot Melter during processing of simulated HLW C-106/AY-102 feed. The principal objectives of the DM1200 melter testing were to determine the achievable glass production rates for simulated HLW C-106/AY-102 feed; determine the effect of bubbling rate on production rate; characterize melter off-gas emissions; characterize the performance of the prototypical off-gas system components as well as their integrated performance; characterize the feed, glass product, and off-gas effluents; and to perform pre- and post test inspections of system components.

  18. EFFECTS OF QUARTZ PARTICLE SIZE AND SUCROSE ADDITION ON MELTING BEHAVIOR OF A MELTER FEED FOR HIGH-LEVEL GLASS

    SciTech Connect (OSTI)

    MARCIAL J; KRUGER AA; HRMA PR; SCHWEIGER MJ; SWEARINGEN KJ; TEGROTENHUIS WE; HENAGER SH

    2010-07-28

    The behavior of melter feed (a mixture of nuclear waste and glass-forming additives) during waste-glass processing has a significant impact on the rate of the vitrification process. We studied the effects of silica particle size and sucrose addition on the volumetric expansion (foaming) of a high-alumina feed and the rate of dissolution of silica particles in feed samples heated at 5 C/min up to 1200 C. The initial size of quartz particles in feed ranged from 5 to 195 {micro}m. The fraction of the sucrose added ranged from 0 to 0.20 g per g glass. Extensive foaming occurred only in feeds with 5-{micro}m quartz particles; particles {ge}150 {micro}m formed clusters. Particles of 5 {micro}m completely dissolved by 900 C whereas particles {ge}150 {micro}m did not fully dissolve even when the temperature reached 1200 C. Sucrose addition had virtually zero impact on both foaming and the dissolution of silica particles. Over 100 sites in the United States are currently tasked with the storage of nuclear waste. The largest is the Hanford Site located in southeastern Washington State with 177 subterranean tanks containing over fifty-million gallons of nuclear waste from plutonium production from 1944 through 1987. This waste will be vitrified at the Hanford Tank Waste Treatment and Immobilization Plant. In the vitrification process, feed is charged into a melter and converted into glass to be ultimately stored in a permanent repository. The duration of waste-site cleanups by the vitrification process depends on the rate of melting, i.e., on the rate of the feed-to-glass conversion. Foaming associated with the melting process and the rate of dissolution of quartz particles (silica being the major glass-forming additive) are assumed to be important factors that influence the rate of melting. Previous studies on foaming of high-alumina feed demonstrated that varying the makeup of a melter feed has a significant impact on foaming. The volume of feeds that contained 5-{micro}m quartz particles substantially increased because of foaming. The extent of foaming decreased as the particle size of quartz increased. Moreover, samples containing quartz particles 195 {micro}m formed agglomerates at temperatures above 900 C that only slowly dissolved in the melt. This study continues previous work on the feed-melting process, specifically on the effects of the size of silica particles on the formation of nuclear-waste glasses to determine a suitable range of silica particle sizes that causes neither excessive foaming nor undesirable agglomeration. Apart from varying the silica-particle size, carbon was added in the form of sucrose. Sucrose has been used to accelerate the rate of melting. In this study, we have observed its impact on feed foaming and quartz dissolution.

  19. Melter technology evaluation for vitrification of Hanford Site low-level waste

    SciTech Connect (OSTI)

    Wilson, C.N.; Burgard, K.C.; Weber, E.T.; Brown, N.R.

    1995-04-01

    The current plan at the Hanford Site, in accordance with the Tri-Party Agreement among Washington State, the US Environmental Protection Agency, and the US Department of Energy, is to convert the low-level tank waste fraction into a silicate glass. The low-level waste will be composed primarily of sodium nitrate and nitrite salts concentrated in a highly alkaline aqueous solution. The capability to process up to 200 metric tons/day off glass will be established to produce an estimated 210,000 m{sup 3} for onsite disposal. A program to test and evaluate high-capacity melter technologies is in progress. Testing performed by seven different industrial sources using Joule heating, combustion, plasma, and carbon arc melters is described.

  20. Test Plan: Phase 1, Hanford LLW melter tests, GTS Duratek, Inc.

    SciTech Connect (OSTI)

    Eaton, W.C.

    1995-06-14

    This document provides a test plan for the conduct of vitrification testing by a vendor in support of the Hanford Tank Waste Remediation System (TWRS) Low-Level Waste (LLW) Vitrification Program. The vendor providing this test plan and conducting the work detailed within it [one of seven selected for glass melter testing under Purchase Order MMI-SVV-384215] is GTS Duratek, Inc., Columbia, Maryland. The GTS Duratek project manager for this work is J. Ruller. This test plan is for Phase I activities described in the above Purchase Order. Test conduct includes melting of glass with Hanford LLW Double-Shell Slurry Feed waste simulant in a DuraMelter{trademark} vitrification system.

  1. SETTLING OF SPINEL IN A HIGH-LEVEL WASTE GLASS MELTER

    SciTech Connect (OSTI)

    Pavel Hrma; Pert Schill; Lubomir Nemec

    2002-01-07

    High-level nuclear waste is being vitrified, i.e., converted to a durable glass that can be stored in a safe repository for hundreds of thousands of years. Waste vitrification is accomplished in reactors called melters to which the waste is charged together with glass-forming additives. The mixture is electrically heated to a temperature as high as 1150 decrees C to create a melt that becomes glass on cooling.

  2. Report - Melter Testing of New High Bismuth HLW Formulations VSL-13R2770-1

    SciTech Connect (OSTI)

    Kruger, Albert A.; Pegg, I. L.; Kot, W. K.; Gan, H.; Matlack, K. S.

    2013-11-13

    The primary objective of the work described was to test two glasses formulated for a high bismuth waste stream on the DM100 melter system. Testing was designed to determine processing characteristics and production rates, assess the tendency for foaming, and confirm glass properties. The glass compositions tested were previously developed to maintain high waste loadings and processing rates while suppressing the foaming observed in previous tests

  3. Vitrification of simulated radioactive Rocky Flats plutonium containing ash residue with a Stir Melter System

    SciTech Connect (OSTI)

    Marra, J.C.; Kormanyos, K.R.; Overcamp, T.J.

    1996-10-01

    A demonstration trial has been completed in which a simulated Rocky Flats ash consisting of an industrial fly-ash material doped with cerium oxide was vitrified in an alloy tank Stir-Melter{trademark} System. The cerium oxide served as a substitute for plutonium oxide present in the actual Rocky Flats residue stream. The glass developed falls within the SiO{sub 2} + Al{sub 2}O{sub 3}/{Sigma}Alkali/B{sub 2}O{sub 3} system. The glass batch contained approximately 40 wt% of ash, the ash was modified to contain {approximately} 5 wt% CeO{sub 2} to simulate plutonium chemistry in the glass. The ash simulant was mixed with water and fed to the Stir-Melter as a slurry with a 60 wt% water to 40 wt% solids ratio. Glass melting temperature was maintained at approximately 1,050 C during the melting trials. Melting rates as functions of impeller speed and slurry feed rate were determined. An optimal melting rate was established through a series of evolutionary variations of the control variables` settings. The optimal melting rate condition was used for a continuous six hour steady state run of the vitrification system. Glass mass flow rates of the melter were measured and correlated with the slurry feed mass flow. Melter off-gas was sampled for particulate and volatile species over a period of four hours during the steady state run. Glass composition and durability studies were run on samples collected during the steady state run.

  4. INSTALLATION OF BUBBLERS IN THE SAVANNAH RIVER SITED DEFENSE WASTE PROCESSING FACILITY MELTER

    SciTech Connect (OSTI)

    Smith, M.; Iverson, D.

    2010-12-08

    Savannah River Remediation (SRR) LLC assumed the liquid waste contract at the Savannah River Site (SRS) in the summer of 2009. The main contractual agreement was to close 22 High Level Waste (HLW) tanks in eight years. To achieve this aggressive commitment, faster waste processing throughout the SRS liquid waste facilities will be required. Part of the approach to achieve faster waste processing is to increase the canister production rate of the Defense Waste Processing Facility (DWPF) from approximately 200 canisters filled with radioactive waste glass per year to 400 canisters per year. To reach this rate for melter throughput, four bubblers were installed in the DWPF Melter in the late summer of 2010. This effort required collaboration between SRR, SRR critical subcontractor EnergySolutions, and Savannah River Nuclear Solutions, including the Savannah River National Laboratory (SRNL). The tasks included design and fabrication of the bubblers and related equipment, testing of the bubblers for various technical issues, the actual installation of the bubblers and related equipment, and the initial successful operation of the bubblers in the DWPF Melter.

  5. Final Report - Testing of Optimized Bubbler Configuration for HLW Melter VSL-13R2950-1, Rev. 0, dated 6/12/2013

    SciTech Connect (OSTI)

    Kruger, Albert A.; Pegg, I. L.; Callow, R. A.; Joseph, I.; Matlack, K. S.; Kot, W. K.

    2013-11-13

    The principal objective of this work was to determine the glass production rate increase and ancillary effects of adding more bubbler outlets to the current WTP HLW melter baseline. This was accomplished through testing on the HLW Pilot Melter (DM1200) at VSL. The DM1200 unit was selected for these tests since it was used previously with several HLW waste streams including the four tank wastes proposed for initial processing at Hanford. This melter system was also used for the development and optimization of the present baseline WTP HLW bubbler configuration for the WTP HLW melter, as well as for MACT testing for both HLW and LAW. Specific objectives of these tests were to: Conduct DM1200 melter testing with the baseline WTP bubbling configuration and as augmented with additional bubblers. Conduct DM1200 melter testing to differentiate the effects of total bubbler air flow and bubbler distribution on glass production rate and cold cap formation. Collect melter operating data including processing rate, temperatures at a variety of locations within the melter plenum space, melt pool temperature, glass melt density, and melter pressure with the baseline WTP bubbling configuration and as augmented with additional bubblers. Collect melter exhaust samples to compare particulate carryover for different bubbler configurations. Analyze all collected data to determine the effects of adding more bubblers to the WTP HLW melter to inform decisions regarding future lid re-designs. The work used a high aluminum HLW stream composition defined by ORP, for which an appropriate simulant and high waste loading glass formulation were developed and have been previously processed on the DM1200.

  6. SLUDGE TREATMENT PROJECT KOP DISPOSITION - THERMAL AND GAS ANALYSIS FOR THE COLD VACUUM DRYING FACILITY

    SciTech Connect (OSTI)

    SWENSON JA; CROWE RD; APTHORPE R; PLYS MG

    2010-03-09

    The purpose of this document is to present conceptual design phase thermal process calculations that support the process design and process safety basis for the cold vacuum drying of K Basin KOP material. This document is intended to demonstrate that the conceptual approach: (1) Represents a workable process design that is suitable for development in preliminary design; and (2) Will support formal safety documentation to be prepared during the definitive design phase to establish an acceptable safety basis. The Sludge Treatment Project (STP) is responsible for the disposition of Knock Out Pot (KOP) sludge within the 105-K West (KW) Basin. KOP sludge consists of size segregated material (primarily canister particulate) from the fuel and scrap cleaning process used in the Spent Nuclear Fuel process at K Basin. The KOP sludge will be pre-treated to remove fines and some of the constituents containing chemically bound water, after which it is referred to as KOP material. The KOP material will then be loaded into a Multi-Canister Overpack (MCO), dried at the Cold Vacuum Drying Facility (CVDF) and stored in the Canister Storage Building (CSB). This process is patterned after the successful drying of 2100 metric tons of spent fuel, and uses the same facilities and much of the same equipment that was used for drying fuel and scrap. Table ES-l present similarities and differences between KOP material and fuel and between MCOs loaded with these materials. The potential content of bound water bearing constituents limits the mass ofKOP material in an MCO load to a fraction of that in an MCO containing fuel and scrap; however, the small particle size of the KOP material causes the surface area to be significantly higher. This relatively large reactive surface area represents an input to the KOP thermal calculations that is significantly different from the calculations for fuel MCOs. The conceptual design provides for a copper insert block that limits the volume available to receive KOP material, enhances heat conduction, and functions as a heat source and sink during drying operations. This use of the copper insert represents a significant change to the thermal model compared to that used for the fuel calculations. A number of cases were run representing a spectrum of normal and upset conditions for the drying process. Dozens of cases have been run on cold vacuum drying of fuel MCOs. Analysis of these previous calculations identified four cases that provide a solid basis for judgments on the behavior of MCO in drying operations. These four cases are: (1) Normal Process; (2) Degraded vacuum pumping; (3) Open MCO with loss of annulus water; and (4) Cool down after vacuum drying. The four cases were run for two sets of input parameters for KOP MCOs: (1) a set of parameters drawn from safety basis values from the technical data book and (2) a sensitivity set using parameters selected to evaluate the impact of lower void volume and smaller particle size on MCO behavior. Results of the calculations for the drying phase cases are shown in Table ES-2. Cases using data book safety basis values showed dry out in 9.7 hours and heat rejection sufficient to hold temperature rise to less than 25 C. Sensitivity cases which included unrealistically small particle sizes and corresponding high reactive surface area showed higher temperature increases that were limited by water consumption. In this document and in the attachment (Apthorpe, R. and M.G. Plys, 2010) cases using Technical Databook safety basis values are referred to as nominal cases. In future calculations such cases will be called safety basis cases. Also in these documents cases using parameters that are less favorable to acceptable performance than databook safety values are referred to as safety cases. In future calculations such cases will be called sensitivity cases or sensitivity evaluations Calculations to be performed in support of the detailed design and formal safety basis documentation will expand the calculations presented in this document to include: additional features of th

  7. MWIP: Surrogate formulations for thermal treatment of low-level mixed waste. Part 4, Wastewater treatment sludges

    SciTech Connect (OSTI)

    Bostick, W.D.; Hoffmann, D.P.; Stevenson, R.J.; Richmond, A.A. [Oak Ridge National Lab., TN (United States); Bickford, D.F. [Westinghouse Savannah River Co., Aiken, SC (United States)

    1994-01-01

    The category of sludges, filter cakes, and other waste processing residuals represent the largest volume of low-level mixed (hazardous and radioactive) wastes within the US Department of Energy (DOE) complex. Treatment of these wastes to minimize the mobility of contaminants, and to eliminate the presence of free water, is required under the Federal Facility Compliance Act agreements between DOE and the Environmental Protection Agency. In the text, we summarize the currently available data for several of the high priority mixed-waste sludge inventories within DOE. Los Alamos National Laboratory TA-50 Sludge and Rocky Flats Plant By-Pass Sludge are transuranic (TRU)-contaminated sludges that were isolated with the use of silica-based filter aids. The Oak Ridge Y-12 Plant West End Treatment Facility Sludge is predominantly calcium carbonate and biomass. The Oak Ridge K-25 Site Pond Waste is a large-volume waste stream, containing clay, silt, and other debris in addition to precipitated metal hydroxides. We formulate ``simulants`` for the waste streams described above, using cerium oxide as a surrogate for the uranium or plutonium present in the authentic material. Use of nonradiological surrogates greatly simplifies material handling requirements for initial treatability studies. The use of synthetic mixtures for initial treatability testing will facilitate compositional variation for use in conjunction with statistical design experiments; this approach may help to identify any ``operating window`` limitations. The initial treatability testing demonstrations utilizing these ``simulants`` will be based upon vitrification, although the materials are also amenable to testing grout-based and other stabilization procedures. After the feasibility of treatment and the initial evaluation of treatment performance has been demonstrated, performance must be verified using authentic samples of the candidate waste stream.

  8. Evaluation of melter system technologies for vitrification of high-sodium content low-level radioactive liquid wastes

    SciTech Connect (OSTI)

    Wilson, C.N.

    1994-03-21

    Westinghouse Hanford Company (WHC) is conducting a two-phased demonstration testing and evaluation of candidate melter system technologies for vitrification of Hanford Site low-level tank wastes. The testing is to be performed by melter equipment and vitrification technology commercial suppliers. This Statement of Work is for Phases 1 and 2 of the demonstration testing program. The primary objective of the demonstration testing is to identify the best available melter system technology for the Hanford Site LLW vitrification facility. Data obtained also will support various WHC engineering studies and conceptual design of the LLW vitrification facility. Multiple technologies will be selected for demonstration and evaluation. Testing will be conducted using non-radioactive LLW simulants in Seller-specified pilot/testing facilities.

  9. Thermal treatment for increasing magnetostrictive response of rare earth-iron alloy rods

    DOE Patents [OSTI]

    Verhoeven, J.D.; McMasters, O.D.

    1989-07-18

    Magnetostrictive rods formed from rare earth-iron alloys are subjected to a short time heat treatment to increase their magnetostrictive response under compression. The heat treatment is preferably carried out at a temperature of from 900 to 1,000 C for 20 minutes to six hours.

  10. Development of US Navy Shipboard Systems for solid and liquid waste thermal treatment. Report for July 1995-April 1996

    SciTech Connect (OSTI)

    Gullet, B.K.

    1996-07-01

    The paper describes the U.S. Navy`s shipboard environmental challenges and a few of its research programs for meeting its needs for solid and liquid waste treatment. This objective is particularly important in environmentally sensitive areas, such as the Mediterranean Sea, where fleet deployment time is significant. Prohibitions on ocean dumping and anticipated requirements on effluent discharge quality have led the Navy to continue the research, development, and demonstration of shipboard systems to treat their unpreventable wastes. For solid, non-hazardous wastes, post-minimization efforts are geared toward long-term development of systems to thermally pyrolyze and oxidize the wastes into significantly reduced volume and weight.

  11. An Itegrated Approach to Water Treatment in Oil and Gas Industry via Thermal Membrane Distillation 

    E-Print Network [OSTI]

    Elsayed, Nesreen Ahmed Abdelmoez Mohamed

    2014-10-14

    This work is aimed at developing a systematic approach for designing treatment systems for wastewater streams resulting from upstream production and downstream processing of oil and gas systems. The approach will provide an optimum and integrated...

  12. EA-1189: Non-thermal Treatment of Hanford Site Low-level Mixed Waste, Richland, Washington

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts for the proposal to demonstrate the feasibility of commercial treatment of contact-handled low-level mixed waste to meet existing Federal and State...

  13. Effects of thermal treatment on the co-rolled U-Mo fuel foils

    SciTech Connect (OSTI)

    Dennis D. Keiser, Jr.; Tammy L. Trowbridge; Cynthia R. Breckenridge; Brady L. Mackowiak; Glenn A. Moore; Barry H. Rabin; Mitchell K. Meyer

    2014-11-01

    A monolithic fuel type is being developed to convert US high performance research and test reactors such as Advanced Test Reactor (ATR) at Idaho National Laboratory from highly enriched uranium (HEU) to low-enriched uranium (LEU). The interaction between the cladding and the U-Mo fuel meat during fuel fabrication and irradiation is known to have negative impacts on fuel performance, such as mechanical integrity and dimensional stability. In order to eliminate/minimize the direct interaction between cladding and fuel meat, a thin zirconium diffusion barrier was introduced between the cladding and U-Mo fuel meat through a co-rolling process. A complex interface between the zirconium and U-Mo was developed during the co-rolling process. A predictable interface between zirconium and U-Mo is critical to achieve good fuel performance since the interfaces can be the weakest link in the monolithic fuel system. A post co-rolling annealing treatment is expected to create a well-controlled interface between zirconium and U-Mo. A systematic study utilizing post co-rolling annealing treatment has been carried out. Based on microscopy results, the impacts of the annealing treatment on the interface between zirconium and U-Mo will be presented and an optima annealing treatment schedule will be suggested. The effects of the annealing treatment on the fuel performance will also be discussed.

  14. Adsorption and thermal treatments of 1-dodecene on Si(100) investigated by STM

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, H. W.; Fujikawa, Y.; Sadowski, J. T.; Xue, Q. -K.; Sakurai, T.

    2015-03-01

    We investigate the atomic behaviour of long-chain 1-dodecene adsorbed on Si(100) using a scanning tunnelling microscope with an exposure of 30 to 2.4 Langmuirs. Unlike previous reports on short-chain molecules, remarkable self-ordered assembly of molecules is not observed at room temperature, which is possibly attributed to the asymmetric molecular structure with long chains of 1-dodecene. After annealing at 500–580 °C, ordered patterns form with a c(4 × 4) structure, accompanied with thermal decomposition of molecules.

  15. Environmental Assessment Offsite Thermal Treatment of Low-Level Mixed Waste

    SciTech Connect (OSTI)

    N /A

    1999-05-06

    The U.S. Department of Energy (DOE), Richland Operations Office (RL) needs to demonstrate the economics and feasibility of offsite commercial treatment of contact-handled low-level mixed waste (LLMW), containing polychlorinated biphenyls (PCBS) and other organics, to meet existing regulatory standards for eventual disposal.

  16. Description of recommended non-thermal mixed waste treatment technologies: Version 1.0

    SciTech Connect (OSTI)

    1995-08-01

    This document contains description of the technologies selected for inclusions in the Integrated Nonthermal Treatment Systems (INTS) Study. The purpose of these descriptions is to provide a more complete description of the INTS technologies. It supplements the summary descriptions of candidate nonthermal technologies that were considered for the INTS.

  17. Vendor glass durability study during evaluation of melter system technologies for vitrification of Hanford low-level wastes

    SciTech Connect (OSTI)

    Feng, X.; Kim, D.; Schweiger, M.J. [Pacific Northwest Lab., Richland, WA (United States)] [and others

    1995-12-31

    The low level radioactive wastes (LLW) separated from the single-shell tanks and double-shell tanks at the Hanford Site will be immobilized into glass. A melter system technology testing, and evaluation program is being conducted to identify the demonstration, best overall melter system technology available to vitrify the Hanford LLW streams. The melter technologies being demonstrated use a variety of heating methods to melt the glass, including plasma torch, fossil-fuel-fired cyclone burner, carbon arc and joule-heating. The Phase I testing is a {open_quotes}proof of principle{close_quotes} test to demonstrate that a melter system technology can process a simulated highly alkaline, high nitrate/nitrite content LLW feed and produce a glass product of consistent quality. Target waste oxide loading of LLW simulant was specified to be about 25 wt%. Pacific Northwest Laboratory (PNL) is providing glass formulation support for this program. The five candidate vendor glasses at 20 wt% Na{sub 2}O level provided by PNL are alumino-borosilicate and aluminosilicate glasses with melting points around 1300{degrees}. Glasses adopted by vendors were tested at PNL to verify the required properties. The testing included durability evaluation through product consistency test, MCC-1 tests, and flow through tests and viscosity measurements.

  18. Evaluation of gasification and novel thermal processes for the treatment of municipal solid waste

    SciTech Connect (OSTI)

    Niessen, W.R.; Marks, C.H.; Sommerlad, R.E.

    1996-08-01

    This report identifies seven developers whose gasification technologies can be used to treat the organic constituents of municipal solid waste: Energy Products of Idaho; TPS Termiska Processor AB; Proler International Corporation; Thermoselect Inc.; Battelle; Pedco Incorporated; and ThermoChem, Incorporated. Their processes recover heat directly, produce a fuel product, or produce a feedstock for chemical processes. The technologies are on the brink of commercial availability. This report evaluates, for each technology, several kinds of issues. Technical considerations were material balance, energy balance, plant thermal efficiency, and effect of feedstock contaminants. Environmental considerations were the regulatory context, and such things as composition, mass rate, and treatability of pollutants. Business issues were related to likelihood of commercialization. Finally, cost and economic issues such as capital and operating costs, and the refuse-derived fuel preparation and energy conversion costs, were considered. The final section of the report reviews and summarizes the information gathered during the study.

  19. Combined Therapies for the Treatment of Technically Unresectable Liver Malignancies: Bland Embolization and Radiofrequency Thermal Ablation within the Same Session

    SciTech Connect (OSTI)

    Bonomo, Guido, E-mail: guido.bonomo@ieo.it; Della Vigna, Paolo, E-mail: paolo.dellavigna@ieo.it; Monfardini, Lorenzo, E-mail: lorenzo.monfardini@ieo.it; Orgera, Gianluigi, E-mail: gianluigi.orgera@ieo.it [European Institute of Oncology, Unit of Interventional Radiology (Italy); Chiappa, Antonio, E-mail: antonio.chiappa@ieo.it [European Institute of Oncology, Unit of Biliopancreatic Surgery (Italy); Bianchi, Paolo Pietro, E-mail: paolo.bianchi@ieo.it [European Institute of Oncology, Unit of Minimally-Invasive Surgery (Italy); Zampino, Maria Giulia, E-mail: maria.zampino@ieo.it [European Institute of Oncology, Division of Medical Oncology (Italy); Orsi, Franco, E-mail: franco.orsi@ieo.it [European Institute of Oncology, Unit of Interventional Radiology (Italy)

    2012-12-15

    Purpose: This retrospective study evaluated the feasibility, efficacy, and safety of combining transcatheter arterial embolization (TAE) with radiofrequency thermal ablation (RFA) in a single session for the treatment of technically unresectable liver-only malignancies. Methods: From May 2006 to January 2011, a total of 30 patients affected by liver metastases with single or multiple unresectable liver-only lesions underwent a combined treatment with TAE followed by RFA in the same session, for a total of 36 treated lesions. Patients were extrapolated from a cohort of patients discussed within the weekly institutional tumor board. TAE was performed by using 100 {mu}m microspheres; RFA was performed immediately after TAE by positioning the electrode needle via ultrasound and/or computed tomographic guidance. Local tumor responses and procedure-related complications were evaluated. Results: Completion of both procedures was obtained in all patients for all 36 lesions. Liver lesions had a maximum axial diameter ranging 16-59 mm. Postintervention unenhanced ablated areas ranged 28-104 mm in maximum axial diameter. Safety margins ranged 1-30.5 mm. Complete response, defined as complete devascularization at computed tomography, was obtained in all treated lesions for a maximum period of 12 months. Tumor relapse was observed in one patient at 12 months. Sixteen patients developed new liver lesions or progressive systemic disease during follow-up. Nine patients were still disease-free. Seven patients died as a result of systemic progressive disease. One major treatment-related complication was observed. Conclusions: In patients with technically unresectable liver-only malignancies, single-session combined TAE-RFA is an effective and safe treatment.

  20. An investigation of gas separation membranes for reduction of thermal treatment emissions

    SciTech Connect (OSTI)

    Stull, D.M.; Logsdon, B.W.; Pellegrino, J.J.

    1994-05-16

    Gas permeable membranes were evaluated for possible use as air pollution control devices on a fluidized bed catalytic incineration unit. The unit is a candidate technology for treatment of certain mixed hazardous and radioactive wastes at the Rocky Flats Plant. Cellulose acetate and polyimide membranes were tested to determine the permeance of typical off-gas components such as carbon dioxide, nitrogen, and oxygen. Multi-component permeation studies included gas mixtures containing light hydrocarbons. Experiments were also conducted to discover information about potential membrane degradation in the presence of organic compounds.

  1. Final Report - Glass Formulation Development and DM10 Melter Testing with ORP LAW Glasses, VSL-09R1510-2, Rev. 0, dated 6/12/09

    SciTech Connect (OSTI)

    Kruger, Albert A.; Pegg, I. L.; Matlack, K. S.; Joseph, I.; Muller, I. S.; Gong, W.

    2013-11-13

    The principal objective of the work described in this Final Report is to extend the glass formulation methodology developed in the earlier work by development of acceptable glass compositions for four LAW compositions specified by ORP that cover the range of sulfate to sodium and potassium to sodium ratios expected in Hanford LAW. The glass formulations were designed to exclude titanium and iron as glass former additives, while tin and vanadium as glass former additives were evaluated for beneficial effects in increasing waste loading in the glasses. This was accomplished through a combination of crucible-scale tests and tests on the DM10 melter system. This melter is the most efficient melter platform for screening glass compositions over a wide range of sulfate concentrations and therefore was selected for the present tests. The current tests provide information on melter processing characteristics and off-gas data, including sulfur incorporation and partitioning.

  2. Statistical process control applied to the liquid-fed ceramic melter process

    SciTech Connect (OSTI)

    Pulsipher, B.A.; Kuhn, W.L.

    1987-09-01

    In this report, an application of control charts to the apparent feed composition of a Liquid-Fed Ceramic Melter (LFCM) is demonstrated by using results from a simulation of the LFCM system. Usual applications of control charts require the assumption of uncorrelated observations over time. This assumption is violated in the LFCM system because of the heels left in tanks from previous batches. Methods for dealing with this problem have been developed to create control charts for individual batches sent to the feed preparation tank (FPT). These control charts are capable of detecting changes in the process average as well as changes in the process variation. All numbers reported in this document were derived from a simulated demonstration of a plausible LFCM system. In practice, site-specific data must be used as input to a simulation tailored to that site. These data directly affect all variance estimates used to develop control charts. 64 refs., 3 figs., 2 tabs.

  3. Assessment of the impact of the next generation solvent on DWPF melter off-gas flammability

    SciTech Connect (OSTI)

    Daniel, W. E.

    2013-02-13

    An assessment has been made to evaluate the impact on the DWPF melter off-gas flammability of replacing the current solvent used in the Modular Caustic-Side Solvent Extraction Process Unit (MCU) process with the Next Generation Solvent (NGS-MCU) and blended solvent. The results of this study showed that the concentrations of nonvolatile carbon and hydrogen of the current solvent in the Slurry Mix Evaporator (SME) product would both be about 29% higher than their counterparts of the NGS-MCU and blended solvent in the absence of guanidine partitioning. When 6 ppm of guanidine (TiDG) was added to the effluent transfer to DWPF to simulate partitioning for the NGS-MCU and blended solvent cases and the concentration of Isopar{reg_sign} L in the effluent transfer was controlled below 87 ppm, the concentrations of nonvolatile carbon and hydrogen of the NGS-MCU and blended solvent were still about 12% and 4% lower, respectively, than those of the current solvent. It is, therefore, concluded that as long as the volume of MCU effluent transfer to DWPF is limited to 15,000 gallons per Sludge Receipt and Adjustment Tank (SRAT)/SME cycle and the concentration of Isopar{reg_sign} L in the effluent transfer is controlled below 87 ppm, using the current solvent assumption of 105 ppm Isopar{reg_sign} L or 150 ppm solvent in lieu of NGS-MCU or blended solvent in the DWPF melter off-gas flammability assessment is conservative for up to an additional 6 ppm of TiDG in the effluent due to guanidine partitioning. This report documents the calculations performed to reach this conclusion.

  4. Pilot Testing of WRI'S Novel Mercury Control Technology by Pre-Combustion Thermal Treatment of Coal

    SciTech Connect (OSTI)

    Alan Bland; Jesse Newcomer; Kumar Sellakumar

    2008-08-17

    The challenges to the coal-fired power industry continue to focus on the emission control technologies, such as mercury, and plant efficiency improvements. An alternate approach to post-combustion control of mercury, while improving plant efficiency deals with Western Research Institute's (WRI)'s patented pre-combustion mercury removal and coal upgrading technology. WRI was awarded under the DOE's Phase III Mercury program, to evaluate the effectiveness of WRI's novel thermal pretreatment process to achieve >50% mercury removal, and at costs of <$30,000/lb of Hg removed. WRI has teamed with Etaa Energy, Energy and Environmental Research Center (EERC), Foster Wheeler North America Corp. (FWNA), and Washington Division of URS (WD-URS), and with project co-sponsors including Electric Power Research Institute (EPRI), Southern Company, Basin Electric Power Cooperative (BEPC), Montana-Dakota Utilities (MDU), North Dakota Industrial Commission (NDIC), Detroit Edison (DTE), and SaskPower to undertake this evaluation. The technical objectives of the project were structured in two phases: Phase I--coal selection and characterization, and bench-and PDU-scale WRI process testing and; and Phase II--pilot-scale pc combustion testing, design of an integrated boiler commercial configuration, its impacts on the boiler performance and the economics of the technology related to market applications. This report covers the results of the Phase I testing. The conclusion of the Phase I testing was that the WRI process is a technically viable technology for (1) removing essentially all of the moisture from low rank coals, thereby raising the heating value of the coal by about 30% for subbituminous coals and up to 40% for lignite coals, and (2) for removing volatile trace mercury species (up to 89%) from the coal prior to combustion. The results established that the process meets the goals of DOE of removing <50% of the mercury from the coals by pre-combustion methods. As such, further testing, demonstration and economic analysis as described in the Phase II effort is warranted and should be pursued.

  5. Earth melter

    DOE Patents [OSTI]

    Chapman, Christopher C. (Richland, WA)

    1995-01-01

    An apparatus, and method of operating the apparatus, wherein a feed material is converted into a glassified condition for subsequent use or disposal. The apparatus is particularly useful for disposal of hazardous or noxious waste materials which are otherwise either difficult or expensive to dispose of. The apparatus is preferably constructed either by excavating a melt zone in a quantity of soil or rock, or by constructing a melt zone in an apparatus above grade and lining the melt zone with a back fill material if refractory properties are needed. The feed material is fed into the melt zone and, preferably, combusted to an ash, whereupon the heat of combustion is used to melt the ash to a molten condition. Electrodes may be used to maintain the molten feed material in a molten condition, and to maintain homogeneity of the molten materials.

  6. Independent Oversight Review of the Hanford Site Waste Treatment...

    Office of Environmental Management (EM)

    Number 24590-LAW-M6-LMP-00043002, Rev. 0, LAW Melter Process System Melter 2 Melter Lid Cooling Loop * Specification No. 24590-WTP-3PS-E00X-T0003 Rev. 7, Engineering...

  7. Glass melter system technologies for vitrification of high-sodium-content low-level, radioactive, liquid wastes: Phase 1, SBS demonstration with simulated low-level waste. Final test report

    SciTech Connect (OSTI)

    Holmes, M.J.; Scotto, M.V.; Shiao, S.Y.

    1995-12-31

    The attached vendor report was prepared for Westinghouse Hanford Company by Babcock & Wilcox as documentation of the Phase I Final Test Report, Cyclone Combustion Melter Demonstration.

  8. Silicate Based Glass Formulations for Immobilization of U.S. Defense Wastes Using Cold Crucible Induction Melters

    SciTech Connect (OSTI)

    Smith, Gary L.; Kim, Dong-Sang; Schweiger, Michael J.; Marra, James C.; Lang, Jesse B.; Crum, Jarrod V.; Crawford, Charles L.; Vienna, John D.

    2014-05-22

    The cold crucible induction melter (CCIM) is an alternative technology to the currently deployed liquid-fed, ceramic-lined, Joule-heated melter for immobilizing of U.S. tank waste generated from defense related reprocessing. In order to accurately evaluate the potential benefits of deploying a CCIM, glasses must be developed specifically for that melting technology. Related glass formulation efforts have been conducted since the 1990s including a recent study that is first documented in this report. The purpose of this report is to summarize the silicate base glass formulation efforts for CCIM testing of U.S. tank wastes. Summaries of phosphate based glass formulation and phosphate and silicate based CCIM demonstration tests are reported separately (Day and Ray 2013 and Marra 2013, respectively). Combined these three reports summarize the current state of knowledge related to waste form development and process testing of CCIM technology for U.S. tank wastes.

  9. Final Report - Glass Formulation Testing to Increase Sulfate Volatilization from Melter, VSL-04R4970-1, Rev. 0, dated 2/24/05

    SciTech Connect (OSTI)

    Kruger, Albert A.; Matlack, K. A.; Pegg, I. L.; Gong, W.

    2013-11-13

    The principal objectives of the DM100 and DM10 tests were to determine the impact of four different organics and one inorganic feed additive on sulfate volatilization and to determine the sulfur partitioning between the glass and the off-gas system. The tests provided information on melter processing characteristics and off-gas data including sulfur incorporation and partitioning. A series of DM10 and DM100 melter tests were conducted using a LAW Envelope A feed. The testing was divided into three parts. The first part involved a series of DM10 melter tests with four different organic feed additives: sugar, polyethylene glycol (PEG), starch, and urea. The second part involved two confirmatory 50-hour melter tests on the DM100 using the best combination of reductants and conditions based on the DM10 results. The third part was performed on the DM100 with feeds containing vanadium oxide (V{sub 2}O{sub 5}) as an inorganic additive to increase sulfur partitioning to the off-gas. Although vanadium oxide is not a reductant, previous testing has shown that vanadium shows promise for partitioning sulfur to the melter exhaust, presumably through its known catalytic effect on the SO{sub 2}/SO{sub 3} reaction. Crucible-scale tests were conducted prior to the melter tests to confirm that the glasses and feeds would be processable in the melter and that the glasses would meet the waste form (ILAW) performance requirements. Thus, the major objectives of these tests were to: ? Perform screening tests on the DM10 followed by tests on the DM100-WV system using a LAW -Envelope A feed with four organic additives to assess their impact on sulfur volatilization. ? Perform tests on the DM100-WV system using a LAW -Envelope A feed containing vanadium oxide to assess its impact on sulfur volatilization. ? Determine feed processability and product quality with the above additives. ? Collect melter emissions data to determine the effect of additives on sulfur partitioning and melter emissions. ? Collect and analyze discharged glass to determine sulfur retention in the glass. ? Prepare and characterize feeds and glasses with the additives to confirm that the feeds and the glass melts are suitable for processing in the DM100 melter. ? Prepare and characterize glasses with the additives to confirm that the glasses meet the waste form (ILAW) performance requirements.

  10. Development of the high-level waste high-temperature melter feed preparation flowsheet for vitrification process testing

    SciTech Connect (OSTI)

    Seymour, R.G.

    1995-02-17

    High-level waste (HLW) feed preparation flowsheet development was initiated in fiscal year (FY) 1994 to evaluate alternative flowsheets for preparing melter feed for high-temperature melter (HTM) vitrification testing. Three flowsheets were proposed that might lead to increased processing capacity relative to the Hanford Waste Vitrification Plant (HWVP) and that were flexible enough to use with other HLW melter technologies. This document describes the decision path that led to the selection of flowsheets to be tested in the FY 1994 small-scale HTM tests. Feed preparation flowsheet development for the HLW HTM was based on the feed preparation flowsheet that was developed for the HWVP. This approach allowed the HLW program to build upon the extensive feed preparation flowsheet database developed under the HWVP Project. Primary adjustments to the HWVP flowsheet were to the acid adjustment and glass component additions. Developmental background regarding the individual features of the HLW feed preparation flowsheets is provided. Applicability of the HWVP flowsheet features to the new HLW vitrification mission is discussed. The proposed flowsheets were tested at the laboratory-scale at Pacific Northwest Laboratory. Based on the results of this testing and previously established criteria, a reductant-based flowsheet using glycolic acid and a nitric acid-based flowsheet were selected for the FY 1994 small-scale HTM testing.

  11. Thermal stability, acidity, catalytic properties, and deactivation behaviour of SAPO-5 catalysts: Effect of silicon content, acid treatment, and Na exchange

    SciTech Connect (OSTI)

    Akolekar, D.B.

    1994-09-01

    Crystalline microporous SAPO-5 molecular sieves with different silicon content, acid-treated SAPO-5 and Na-exchanged SAPO-5 were investigated for their thermal stability, and acidic and catalytic properties. SAPO-5 materials with increasing SI framework content exhibited lower thermal stability. The effects of the thermal treatment and Na exchange on the N{sub 2}-sorption capacity (at 78 K) of these materials were studied. In situ IR spectroscopic investigations of pyridine chemisorbed on the aluminophosphate catalysts revealed that the concentration of Broensted and Lewis acid sites are strongly affected by the Si content in the AlPO{sub 4} framework, acid treatment, and Na exchange. The results of temperature programmed desorption (TPD) and stepwise thermal desorption of pyridine suggest that there exists a broad site energy distribution over the aluminophosphate catalysts increases with the increasing Si content in the AlPO{sub 4} framework. The acid treatment and Na exchange showed a decrease in the number of strong acid sites on SAPO-5. The TPD of pyridine over SAPO-5, acid-treated SAPO-5, and Na-exchanged SAPO-5 indicated the presence of two types of acid sites. Correlation between the number of strong acid sites (measured in terms of the chemisorption of pyridine at 673 K) and framework charge on the aluminophosphate catalysts has also been obtained. The catalytic activities of SAPO-5 catalysts in the ethanol, n-hexane, isooctane, toluene, and o-xylene conversion reactions were studied. 22 refs., 11 figs., 5 tabs.

  12. REVIEW REPORT: BUILDING C-400 THERMAL TREATMENT 90 PERCENT REMEDIAL DESIGN REPORT AND SITE INVESTIGATION, PGDP, PADUCAH, KENTUCKY

    SciTech Connect (OSTI)

    Looney, B; Jed Costanza, J; Eva Davis, E; Joe Rossabi, J; Lloyd (Bo) Stewart, L; Hans Stroo, H

    2007-08-15

    On 9 April 2007, the U.S. Department of Energy (DOE) Headquarters, Office of Soil and Groundwater Remediation (EM-22) initiated an Independent Technical Review (ITR) of the 90% Remedial Design Report (RDR) and Site Investigation (RDSI) for thermal treatment of trichloroethylene (TCE) in the soil and groundwater in the vicinity of Building C-400 at the Paducah Gaseous Diffusion Plant (PGDP). The general ITR goals were to assess the technical adequacy of the 90% RDSI and provide recommendations sufficient for DOE to determine if modifications are warranted pertaining to the design, schedule, or cost of implementing the proposed design. The ultimate goal of the effort was to assist the DOE Paducah/Portsmouth Project Office (PPPO) and their contractor team in ''removing'' the TCE source zone located near the C-400 Building. This report provides the ITR findings and recommendations and supporting evaluations as needed to facilitate use of the recommendations. The ITR team supports the remedial action objective (RAO) at C-400 to reduce the TCE source area via subsurface Electrical Resistance Heating (ERH). Further, the ITR team commends PPPO, their contractor team, regulators, and stakeholders for the significant efforts taken in preparing the 90% RDR. To maximize TCE removal at the target source area, several themes emerge from the review which the ITR team believes should be considered and addressed before implementing the thermal treatment. These themes include the need for: (1) Accurate and site-specific models as the basis to verify the ERH design for full-scale implementation for this challenging hydrogeologic setting; (2) Flexible project implementation and operation to allow the project team to respond to observations and data collected during construction and operation; (3) Defensible performance metrics and monitoring, appropriate for ERH, to ensure sufficient and efficient clean-up; and (4) Comprehensive (creative and diverse) contingencies to address the potential for system underperformance, and other unforeseen conditions These themes weave through the ITR report and the various analyses and recommendations. The ITR team recognizes that a number of technologies are available for treatment of TCE sources. Further, the team supports the regulatory process through which the selected remedy is being implemented, and concurs that ERH is a potentially viable remedial technology to meet the RAOs adjacent to C-400. Nonetheless, the ITR team concluded that additional efforts are needed to provide an adequate basis for the planned ERH design, particularly in the highly permeable Regional Gravel Aquifer (RGA), where sustaining target temperatures present a challenge. The ERH design modeling in the 90% RDR does not fully substantiate that heating in the deep RGA, at the interface with the McNairy formation, will meet the design goals; specifically the target temperatures. Full-scale implementation of ERH to meet the RAOs is a challenge in the complex hydrogeologic setting at PGDP. Where possible, risks to the project identified in this ITR report as ''issues'' and ''recommendations'' should be mitigated as part of the final design process to increase the likelihood of remedial success. The ITR efforts were organized into five lines of inquiry (LOIs): (1) Site investigation and target zone delineation; (2) Performance objectives; (3) Project and design topics; (4) Health and safety; and (5) Cross cutting and independent cost evaluation. Within each of these LOIs, the ITR team identified a series of unresolved issues--topics that have remaining uncertainties or potential project risks. These issues were analyzed and one or more recommendations were developed for each. In the end, the ITR team identified 27 issues and provided 50 recommendations. The issues and recommendations are briefly summarized below, developed in Section 5, and consolidated into a single list in Section 6. The ITR team concluded that there are substantive unresolved issues and system design uncertainties, resulting in technical and financial risks to DOE.

  13. Hanford Waste Treatment Plant completes critical system design...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    trips. They are scheduled to arrive later this fall. "The LAW melters are the largest waste-processing melters ever built, and there's been considerable work dedicated to...

  14. Nuclear Waste Treatment Program annual report for FY 1988

    SciTech Connect (OSTI)

    Brouns, R.A.; Powell, J.A.

    1989-11-01

    Much emphasis continues to be on the transfer of remote design technology for components integral to the West Valley Demonstration Project's (WVDP) vitrification process. In addition to preparing equipment specifications and drawings, Pacific Northwest Laboratory (PNL) staff also participated in numerous design coordination meetings and reviews of drawings prepared by other WVDP contractors. Nearly 200 jumper drawings for the vitrification cell were prepared by this program in FY 1988. The remote jumpers connect vessels in the cell to each other for the transfer of solutions and provide for the flow of materials, instrumentation signals, and power from outside the cell. Analysis required in preparing the jumper designs involved balance, thermal stress, seismic, set-down stress, and displacement calculations. Design efforts were begun on the canister decontamination and swipe station and on the remote maintenance station. Equipment selection and layouts of the vitrification off-gas treatment system, including a reamer to remotely clean the melter off-gas line, were finalized. Also finalized were the designs for the high-efficiency particulate air (HEPA) filter assemblies for heating, cooling and air conditioning of the vitrification cell.

  15. Iron Phosphate Glass for Vitrifying Hanford AZ102 LAW in Joule Heated and Cold Crucible Induction Melters

    SciTech Connect (OSTI)

    Day, Delbert E.; Brow, R. K.; Ray, C. S.; Kim, Cheol-Woon; Reis, Signo T.; Vienna, John D.; Peeler, David K.; Johnson, Fabienne; Hansen, E. K.; Sevigny, Gary J.; Soelberg, Nicolas R.; Pegg, Ian L.; Gan, Hao

    2012-01-05

    An iron phosphate composition for vitrifying a high sulfate (~17 wt%) and high alkali (~80 wt%) low activity Hanford waste, known as AZ102 LAW, has been developed for processing in a Joule Heated Melter (JHM) or a Cold Crucible Induction Melter (CCIM). This composition produced a glass waste form, designated as MS26AZ102F-2, with a waste loading of 26 wt% of the AZ102 which corresponded to a total alkali and sulfate (SO3) content of 21 and 4.2 wt%, respectively. A slurry (7M Na) of MS26AZ102F-2 simulant was melted continuously at temperatures between 1030 and 1090°C for 10 days in a small JHM at PNNL and for 7 days in a CCIM at INL. The as-cast glasses produced in both melters and in trial laboratory experiments along with their CCC-treated counterparts met the DOE LAW requirements for the Product Consistency Test (PCT) and the Vapor Hydration Test (VHT). These glass waste forms retained up to 77 % of the SO3 (3.3 wt%), 100% of the Cesium, and 33 to 44% of the rhenium, surrogate for Tc-99, all of which either exceeded or were comparable to the retention limit for these species in borosilicate glass nuclear waste form. Analyses of commercial K-3 refractory lining and the Inconel 693 metal electrodes used in JHM indicated only minimum corrosion of these components by the iron phosphate glass. This is the first time that an iron phosphate composition (slurry feed) was melted continuously in the JHM and CCIM, thereby, demonstrating that iron phosphate glasses can be used as alternative hosts for vitrifying nuclear waste.

  16. FINAL REPORT INTEGRATED DM1200 MELTER TESTING USING AZ 102 AND C 106/AY-102 HLW SIMULANTS: HLW SIMULANT VERIFICATION VSL-05R5800-1 REV 0 6/27/05

    SciTech Connect (OSTI)

    KRUGER AA; MATLACK KS; GONG W; BARDAKCI T; D'ANGELO NA; BRANDYS M; KOT WK; PEGG IL

    2011-12-29

    The principal objectives of the DM1200 melter tests were to determine the effects of feed rheology, feed solid content, and bubbler configuration on glass production rate and off-gas system performance while processing the HLW AZ-101 and C-106/AY-102 feed compositions; characterize melter off-gas emissions; characterize the performance of the prototypical off-gas system components, as well as their integrated performance; characterize the feed, glass product, and off-gas effluents; and perform pre- and post test inspections of system components. The specific objectives (including test success criteria) of this testing, along with how each objective was met, are outlined in a table. The data provided in this Final Report address the impacts of HLW melter feed rheology on melter throughput and validation of the simulated HLW melter feeds. The primary purpose of this testing is to further validate/verify the HLW melter simulants that have been used for previous melter testing and to support their continued use in developing melter and off-gas related processing information for the Project. The primary simulant property in question is rheology. Simulants and melter feeds used in all previous melter tests were produced by direct addition of chemicals; these feed tend to be less viscous than rheological the upper-bound feeds made from actual wastes. Data provided here compare melter processing for the melter feed used in all previous DM100 and DM1200 tests (nominal melter feed) with feed adjusted by the feed vendor (NOAH Technologies) to be more viscous, thereby simulating more closely the upperbounding feed produced from actual waste. This report provides results of tests that are described in the Test Plan for this work. The Test Plan is responsive to one of several test objectives covered in the WTP Test Specification for this work; consequently, only part of the scope described in the Test Specification was addressed in this particular Test Plan. For the purpose of comparison, the tests reported here were performed with AZ-102 and C-106/AY-102 HLW simulants and glass compositions that are essentially the same as those used for recent DM1200 tests. One exception was the use of an alternate, higher-waste-loading C-106/AY-102 glass composition that was used in previous DM100 tests to further evaluate the performance of the optimized bubbler configuration.

  17. Non-thermal plasma based technologies for the after-treatment of automotive exhaust particulates and marine diesel exhaust NOx

    SciTech Connect (OSTI)

    McAdams, R; Beech, P; Gillespie, R; Guy, C; Jones,S; Liddell, T; Morgan, R; Shawcross, J; Weeks, D; Hughes, D; Oesterle, J; Eberspdcher,

    2003-08-24

    The trend in environmental legislation is such that primary engine modifications will not be sufficient to meet all future emissions requirements and exhaust aftertreatment technologies will need to be employed. One potential solution that is well placed to meet those requirements is non-thermal plasma technology. This paper will describe our work with some of our partners in the development of a plasma based diesel particulate filter (DPF) and plasma assisted catalytic reduction (PACR) for NOx removal. This paper describes the development of non-thermal plasma technology for the aftertreatment of particulates from a passenger car engine and NOx from a marine diesel exhaust application.

  18. Integrated thermal treatment system study: Phase 1 results. Appendix B, Flow sheets and material balances: Volume 2

    SciTech Connect (OSTI)

    Feizollahi, F.; Quapp, W.J.; Hempill, H.G.; Groffie, F.J.

    1994-07-01

    This document accompanies a full report which describes the testing and evaluation of ten different methods for incinerating mixed low-level radioactive wastes. It consists of flowsheets and diagrams of a rotary kiln, pyrolysis methods, a plasma furnace, a fixed hearth, and thermal desorption methods.

  19. CHARACTERIZATION OF DWPF MELTER OFF-GAS QUENCHER AND STEAM ATOMIZED SCRUBBER DEPOSIT SAMPLES

    SciTech Connect (OSTI)

    Zeigler, K; Ned Bibler, N

    2007-06-06

    This report summarizes the results from the characterization of deposits from the inlets of the primary off-gas Quencher and Steam Atomized Scrubber (SAS) in the Defense Waste Processing Facility (DWPF), as requested by a technical assistance request. DWPF requested elemental analysis and compound identification to help determine the potential causes for the substance formation. This information will be fed into Savannah River National Laboratory modeling programs to determine if there is a way to decrease the formation of the deposits. The general approach to the characterization of these samples included x-ray diffraction (XRD), scanning electron microscopy (SEM), and chemical analysis. The following conclusions are drawn from the analytical results found in this report: (1) The deposits are not high level waste glass from the DWPF melt pool based on comparison of the compositions of deposits to the composition of a sample of glass taken from the pour stream of the melter during processing of Sludge Batch 3. (2) Chemical composition results suggest that the deposits are probably a combination of sludge and frit particles entrained in the off-gas. (3) Gamma emitters, such as Co-60, Cs-137, Eu-154, Am-241, and Am-243 were detected in both the Quencher and SAS samples with Cs-137 having the highest concentration of the gamma emitters. (4) No evidence existed for accumulation of fissile material (U-233, U-235, and Pu-239) relative to Fe in either deposit. (5) XRD results indicated both samples were primarily amorphorous and contained some crystals of the iron oxides, hematite and magnetite (Fe{sub 2}O{sub 3} and Fe(Fe{sub 2}O{sub 4})), along with sodium nitrate (NaNO{sub 3}). The other main crystalline compound in the SAS deposit was mercurous chloride. The main crystalline compound in the Quencher deposit was a uranium oxide compound. These are all sludge components. (6) SEM analysis of the Quencher deposit revealed crystalline uranium compounds within the sample. SEM analysis of the SAS sample could not be performed due to the presence of a significant concentration of Hg in the sample. (7) Essentially all the Na and the S in the off-gas samples were soluble in water. (8) The main soluble anion was NO{sub 3}{sup -} with SO{sub 4}{sup 2-} being second. (9) In contrast to the results for the off-gas deposits analyzed in 2003, soluble compounds of fluoride and chloride were detected; however, their concentrations in the Quencher and SAS deposits were less than one weight percent. (10) The results suggest that the S is primarily in the deposits as the sulfate anion.

  20. Commercial waste treatment program annual progress report for FY 1983

    SciTech Connect (OSTI)

    McElroy, J.L.; Burkholder, H.C. (comps.)

    1984-02-01

    This annual report describes progress during FY 1983 relating to technologies under development by the Commercial Waste Treatment Program, including: development of glass waste form and vitrification equipment for high-level wastes (HLW); waste form development and process selection for transuranic (TRU) wastes; pilot-scale operation of a radioactive liquid-fed ceramic melter (LFCM) system for verifying the reliability of the reference HLW treatment proces technology; evaluation of treatment requirements for spent fuel as a waste form; second-generation waste form development for HLW; and vitrification process control and product quality assurance technologies.

  1. Final Report - Effects of High Spinel and Chromium Oxide Crystal Contents on Simulated HLW Vitrification in DM100 Melter Tests, VSL-09R1520-1, Rev. 0, dated 6/22/09

    SciTech Connect (OSTI)

    Kruger, Albert A.; Matlack, K. S.; Kot, W.; Pegg, I. L.; Chaudhuri, M.; Lutze, W.

    2013-11-13

    The principal objective of the work was to evaluate the effects of spinel and chromium oxide particles on WTP HLW melter operations and potential impacts on melter life. This was accomplished through a combination of crucible-scale tests, settling and rheological tests, and tests on the DM100 melter system. Crucible testing was designed to develop and identify HLW glass compositions with high waste loadings that exhibit formation of crystalline spinel and/or chromium oxide phases up to relatively high crystal contents (i.e., > 1 vol%). Characterization of crystal settling and the effects on melt rheology was performed on the HLW glass formulations. Appropriate candidate HLW glass formulations were selected, based on characterization results, to support subsequent melter tests. In the present work, crucible melts were formulated that exhibit up to about 4.4 vol% crystallization.

  2. Evaluation of a Novel Temperature Sensing Probe for Monitoring and Controlling Glass Temperature in a Joule-Heated Glass Melter

    SciTech Connect (OSTI)

    A. D. Watkins; C. A. Musick; C. Cannon (AccuTru Int'l Corp); N. M. Carlson; P. D. Mullenix (INEEL); R. D. Tillotson

    1999-04-29

    A self-verifying temperature sensor that employs advanced contact thermocouple probe technology was tested in a laboratory-scale, joule-heated, refractory-lined glass melter used for radioactive waste vitrification. The novel temperature probe monitors melt temperature at any given level of the melt chamber. The data acquisition system provides the real-time temperature for molten glass. Test results indicate that the self-verifying sensor is more accurate and reliable than classic platinum/rhodium thermocouple and sheath assemblies. The results of this test are reported as well as enhancements being made to the temperature probe. To obtain more reliable temperature measurements of the molten glass for improving production efficiency and ensuring consistent glass properties, optical sensing was reviewed for application in a high temperature environment.

  3. Assessing the perception and reality of arguments against thermal waste treatment plants in terms of property prices

    SciTech Connect (OSTI)

    Phillips, K.J.O.; Longhurst, P.J.; Wagland, S.T., E-mail: s.t.wagland@cranfield.ac.uk

    2014-01-15

    Highlights: • Previous research studies have shown that EfW facilities negatively impact the local house prices. • In this study property prices surrounding 3 operational EfW plants were analysed. • No significant negative effect on property prices due to an incinerator was found. - Abstract: The thermal processing of waste materials, although considered to be an essential part of waste management, is often sharply contested in the UK. Arguments such as health, depletion of resources, cost, noise, odours, traffic movement and house prices are often cited as reasons against the development of such facilities. This study aims to review the arguments and identify any effect on property prices due to the public perception of the plant. A selection of existing energy from waste (EfW) facilities in the UK, operational for at least 7 years, was selected and property sales data, within 5 km of the sites, was acquired and analysed in detail. The locations of the properties were calculated in relation to the plant using GIS software (ArcGIS) and the distances split into 5 zones ranging from 0 to 5 km from the site. The local property sale prices, normalised against the local house price index, were compared in two time periods, before and after the facility became operational, across each of the 5 zones. In all cases analysed no significant negative effect was observed on property prices at any distance within 5 km from a modern operational incinerator. This indicated that the perceived negative effect of the thermal processing of waste on local property values is negligible.

  4. Transitions of bandgap and built-in stress for sputtered HfZnO thin films after thermal treatments

    SciTech Connect (OSTI)

    Li, Chih-Hung; Chen, Jian-Zhang [Institute of Applied Mechanics, National Taiwan University, Taipei City 10617, Taiwan (China)] [Institute of Applied Mechanics, National Taiwan University, Taipei City 10617, Taiwan (China); Cheng, I-Chun [Graduate Institute of Photonics and Optoelectronics and Department of Electrical Engineering, National Taiwan University, Taipei City 10617, Taiwan (China)] [Graduate Institute of Photonics and Optoelectronics and Department of Electrical Engineering, National Taiwan University, Taipei City 10617, Taiwan (China)

    2013-08-28

    HfZnO thin films with various Hf contents are sputter-deposited on glass substrates from Hf{sub x}Zn{sub 1?x}O (x = 0, 2.5, 5, 7.5, and 10 at. %) targets at room temperature. The incorporation of Hf in the ZnO film leads to the amorphorization of the materials. The amorphous structures of high-Hf-content films remain after annealing at 600 °C for 30 min. The built-in stresses of as-deposited films are compressive. As the annealing temperature increases, the stresses are relaxed and even become tensile. The films exhibit a high transmission of 80% in the visible region. The optical bandgap increases with the Hf content, but it decreases with the annealing temperature. This can be attributed to the alteration of strain (stress) status in the films and atomic substitution. The reduction of bandgap partly results from the grain growth, which is due to the quantum confinement effect of the small grains. Hf doping increases the resistivity of ZnO owing to the disorder of the material structure and the higher bandgap, which result in more carrier traps and less thermally excited carriers in the conduction bands.

  5. Generalized Test Plan for the Vitrification of Simulated High-Level -Waste Calcine in the Idaho National Laboratory‘s Bench -Scale Cold Crucible Induction Melter

    SciTech Connect (OSTI)

    Vince Maio

    2011-08-01

    This Preliminary Idaho National Laboratory (INL) Test Plan outlines the chronological steps required to initially evaluate the validity of vitrifying INL surrogate (cold) High-Level-Waste (HLW) solid particulate calcine in INL's Cold Crucible Induction Melter (CCIM). Its documentation and publication satisfies interim milestone WP-413-INL-01 of the DOE-EM (via the Office of River Protection) sponsored work package, WP 4.1.3, entitled 'Improved Vitrification' The primary goal of the proposed CCIM testing is to initiate efforts to identify an efficient and effective back-up and risk adverse technology for treating the actual HLW calcine stored at the INL. The calcine's treatment must be completed by 2035 as dictated by a State of Idaho Consent Order. A final report on this surrogate/calcine test in the CCIM will be issued in May 2012-pending next fiscal year funding In particular the plan provides; (1) distinct test objectives, (2) a description of the purpose and scope of planned university contracted pre-screening tests required to optimize the CCIM glass/surrogate calcine formulation, (3) a listing of necessary CCIM equipment modifications and corresponding work control document changes necessary to feed a solid particulate to the CCIM, (4) a description of the class of calcine that will be represented by the surrogate, and (5) a tentative tabulation of the anticipated CCIM testing conditions, testing parameters, sampling requirements and analytical tests. Key FY -11 milestones associated with this CCIM testing effort are also provided. The CCIM test run is scheduled to be conducted in February of 2012 and will involve testing with a surrogate HLW calcine representative of only 13% of the 4,000 m3 of 'hot' calcine residing in 6 INL Bin Sets. The remaining classes of calcine will have to be eventually tested in the CCIM if an operational scale CCIM is to be a feasible option for the actual INL HLW calcine. This remaining calcine's make-up is HLW containing relatively high concentrations of zirconium and aluminum, representative of the cladding material of the reprocessed fuel that generated the calcine. A separate study to define the CCIM testing needs of these other calcine classifications in currently being prepared under a separate work package (WP-0) and will be provided as a milestone report at the end of this fiscal year.

  6. Test plan for glass melter system technologies for vitrification of high-sodium content low-level radioactive liquid waste, Project No. RDD-43288

    SciTech Connect (OSTI)

    Higley, B.A.

    1995-03-15

    This document provides a test plan for the conduct of combustion fired cyclone vitrification testing by a vendor in support of the Hanford Tank Waste Remediation System, Low-Level Waste Vitrification Program. The vendor providing this test plan and conducting the work detailed within it is the Babcock & Wilcox Company Alliance Research Center in Alliance, Ohio. This vendor is one of seven selected for glass melter testing.

  7. Laboratory Report on Performance Evaluation of Key Constituents during Pre-Treatment of High Level Waste Direct Feed

    SciTech Connect (OSTI)

    Huber, Heinz J.

    2013-06-24

    The analytical capabilities of the 222-S Laboratory are tested against the requirements for an optional start up scenario of the Waste Treatment and Immobilization Plant on the Hanford Site. In this case, washed and in-tank leached sludge would be sent directly to the High Level Melter, bypassing Pretreatment. The sludge samples would need to be analyzed for certain key constituents in terms identifying melter-related issues and adjustment needs. The analyses on original tank waste as well as on washed and leached material were performed using five sludge samples from tanks 241-AY-102, 241-AZ-102, 241-AN-106, 241-AW-105, and 241-SY-102. Additionally, solid phase characterization was applied to determine the changes in mineralogy throughout the pre-treatment steps.

  8. XRF and leaching characterization of waste glasses derived from wastewater treatment sludges

    SciTech Connect (OSTI)

    Ragsdale, R.G., Jr

    1994-12-01

    Purpose of this study was to investigate use of XRF (x-ray fluorescence spectrometry) as a near real-time method to determine melter glass compositions. A range of glasses derived from wastewater treatment sludges associated with DOE sites was prepared. They were analyzed by XRF and wet chemistry digestion with atomic absorption/inductively coupled emission spectrometry. Results indicated good correlation between these two methods. A rapid sample preparation and analysis technique was developed and demonstrated by acquiring a sample from a pilot-scale simulated waste glass melter and analyzing it by XRF within one hour. From the results, XRF shows excellent potential as a process control tool for waste glass vitrification. Glasses prepared for this study were further analyzed for durability by toxicity characteristic leaching procedure and product consistency test and results are presented.

  9. Waste Treatment And Immobilization Plant U. S. Department Of Energy Office Of River Protection Submerged Bed Scrubber Condensate Disposition Project - Abstract # 13460

    SciTech Connect (OSTI)

    Yanochko, Ronald M; Corcoran, Connie

    2012-11-15

    The Hanford Waste Treatment and Immobilization Plant (WTP) will generate an off-gas treatment system secondary liquid waste stream [submerged bed scrubber (SBS) condensate], which is currently planned for recycle back to the WTP Low Activity Waste (LAW) melter. This SBS condensate waste stream is high in Tc-99, which is not efficiently captured in the vitrified glass matrix. A pre-conceptual engineering study was prepared in fiscal year 2012 to evaluate alternate flow paths for melter off-gas secondary liquid waste generated by the WTP LAW facility. This study evaluated alternatives for direct off-site disposal of this SBS without pre-treatment, which mitigates potential issues associated with recycling.

  10. Evaluation of Exothermic Reactions from Bulk-Vitrification Melter Feeds Containing Cellulose

    SciTech Connect (OSTI)

    Scheele, Randall D.; McNamara, Bruce K.; Bagaasen, Larry M.; Bos, Stanley J.; Kozelisky, Anne E.; Berry, Pam

    2007-06-25

    PNNL has demonstrated that cellulose effectively reduces the amount of molten ionic salt during Bulk Vitrification of simulated Hanford Low Level Waste (LLW). To address concerns about the potential reactivity of cellulose-LLW, PNNL used thermogravimetric analysis, differential thermal analysis, and accelerating rate calorimetry to determine in these preliminary studies that these mixtures will support a self-sustaining reaction if heated to 110°C at adiabatic conditions. Additional testing is recommended.

  11. EA-0821: Finding of No Significant Impact | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Operation of the Glass Melter Thermal Treatment Unit at the U.S. Department of Energy's Mound Plant, Miamisburg, Ohio Based on the information and the analysis in the environmental...

  12. Feasibility Evaluation and Retrofit Plan for Cold Crucible Induction Melter Deployment in the Defense Waste Processing Facility at Savannah River Site

    SciTech Connect (OSTI)

    Barnes, A.B. [Savannah River National Laboratory, Washington Savannah River Company, Aiken, SC (United States); Iverson, D.C.; Adkins, B.J. [Liquid Waste Operations, Washington Savannah River Company, Aiken, SC (United States); Tchemitcheff, E. [AREVA NC Inc., Richland Office, Richland, WA (United States)

    2008-07-01

    Cold crucible induction melters (CCIM) have been proposed as an alternative technology for waste glass melting at the Defense Waste Processing Facility (DWPF) at Savannah River Site (SRS) as well as for other waste vitrification facilities. Proponents of this technology cite high temperature operation, high tolerance for noble metals and aluminum, high waste loading, high throughput capacity, and low equipment cost as the advantages over existing Joule Heated Melter (JHM) technology. The CCIM uses induction heating to maintain molten glass at high temperature. A water-cooled helical induction coil is connected to an AC current supply, typically operating at frequencies from 100 kHz to 5 MHz. The oscillating magnetic field generated by the oscillating current flow through the coil induces eddy currents in conductive materials within the coil. Those oscillating eddy currents, in turn, generate heat in the material. In the CCIM, the induction coil surrounds a 'Cold Crucible' which is formed by metal tubes, typically copper or stainless steel. The tubes are constructed such that the magnetic field does not couple with the crucible. Therefore, the field generated by the induction coil couples primarily with the conductive medium (hot glass) within. The crucible tubes are water cooled to maintain their temperature between 100 deg. C to 200 deg. C so that a protective layer of molten glass and/or batch material, referred to as a 'skull', forms between them and the hot, corrosive melt. Because the protective skull is the only material directly in contact with the molten glass, the CCIM doesn't have the temperature limitations of traditional refractory lined JHM. It can be operated at melt temperatures in excess of 2000 deg. C, allowing processing of high waste loading batches and difficult-to-melt compounds. The CCIM is poured through a bottom drain, typically through a water-cooled slide valve that starts and stops the pour stream. To promote uniform temperature distribution and increase heat transfer to the slurry fed High Level Waste (HLW) sludge, the CCIM may be equipped with bubblers and/or water cooled mechanical agitators. The DWPF could benefit from use of CCIM technology, especially in light of our latest projections of waste volume to be vitrified. Increased waste loading and increased throughput could result in substantial life cycle cost reduction. In order to significantly surpass the waste throughput capability of the currently installed JHM, it may be necessary to install two 950 mm CCIMs in the DWPF Melt Cell. A cursory evaluation of system design requirements and modifications to the facility that may be required to support installation and operation of two 950 mm CCIMs was performed. Based on this evaluation, it appears technically feasible to position two CCIMs in the Melt Cell of the DWPF within the existing footprint of the current melter. Interfaces with support systems and controls including Melter Feed, Power, Melter Cooling Water, Melter Off-gas, and Canister Operations must be designed to support dual CCIM operations. This paper describes the CCIM technology and identifies technical challenges that must be addressed in order to implement CCIMs in the DWPF. (authors)

  13. FEASIBILITY EVALUATION AND RETROFIT PLAN FOR COLD CRUCIBLE INDUCTION MELTER DEPLOYMENT IN THE DEFENSE WASTE PROCESSING FACILITY AT SAVANNAH RIVER SITE 8118

    SciTech Connect (OSTI)

    Barnes, A; Dan Iverson, D; Brannen Adkins, B

    2008-02-06

    Cold crucible induction melters (CCIM) have been proposed as an alternative technology for waste glass melting at the Defense Waste Processing Facility (DWPF) at Savannah River Site (SRS) as well as for other waste vitrification facilities. Proponents of this technology cite high temperature operation, high tolerance for noble metals and aluminum, high waste loading, high throughput capacity, and low equipment cost as the advantages over existing Joule Heated Melter (JHM) technology. The CCIM uses induction heating to maintain molten glass at high temperature. A water-cooled helical induction coil is connected to an AC current supply, typically operating at frequencies from 100 KHz to 5 MHz. The oscillating magnetic field generated by the oscillating current flow through the coil induces eddy currents in conductive materials within the coil. Those oscillating eddy currents, in turn, generate heat in the material. In the CCIM, the induction coil surrounds a 'Cold Crucible' which is formed by metal tubes, typically copper or stainless steel. The tubes are constructed such that the magnetic field does not couple with the crucible. Therefore, the field generated by the induction coil couples primarily with the conductive medium (hot glass) within. The crucible tubes are water cooled to maintain their temperature between 100 C to 200 C so that a protective layer of molten glass and/or batch material, referred to as a 'skull', forms between them and the hot, corrosive melt. Because the protective skull is the only material directly in contact with the molten glass, the CCIM doesn't have the temperature limitations of traditional refractory lined JHM. It can be operated at melt temperatures in excess of 2000 C, allowing processing of high waste loading batches and difficult-to-melt compounds. The CCIM is poured through a bottom drain, typically through a water-cooled slide valve that starts and stops the pour stream. To promote uniform temperature distribution and increase heat transfer to the slurry fed High Level Waste (HLW) sludge, the CCIM may be equipped with bubblers and/or water cooled mechanical agitators. The DWPF could benefit from use of CCIM technology, especially in light of our latest projections of waste volume to be vitrified. Increased waste loading and increased throughput could result in substantial life cycle cost reduction. In order to significantly surpass the waste throughput capability of the currently installed JHM, it may be necessary to install two 950 mm CCIMs in the DWPF Melt Cell. A cursory evaluation of system design requirements and modifications to the facility that may be required to support installation and operation of two 950 mm CCIMs was performed. Based on this evaluation, it appears technically feasible to position two CCIMs in the Melt Cell of the DWPF within the existing footprint of the current melter. Interfaces with support systems and controls including Melter Feed, Power, Melter Cooling Water, Melter Off-gas, and Canister Operations must be designed to support dual CCIM operations. This paper describes the CCIM technology and identifies technical challenges that must be addressed in order to implement CCIMs in the DWPF.

  14. Office of Enforcement and Oversight's Office of Safety and Emergency Management Evaluations Activity Report for Observation of Waste Treatment and Immobilization Plant LAW Melter and Melter Off-gas Process System Hazards Analysis _Oct 21-31

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i nAandSummary Areas of the country that haveSummary by Program for FY 2012

  15. Enterprise Assessments Review of the Hanford Site Waste Treatment and Immobilization Plant Low-Activity Waste Facility Hazards Analysis Reports for the Melter and Melter Offgas Systems Â… September 2015

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergy A plug-inPPLfor Innovative SolarSavingsAugustHanfordImmobilization Plant

  16. DEVELOPMENT OF AN ANTIFOAM TRACKING SYSTEM AS AN OPTION TO SUPPORT THE MELTER OFF-GAS FLAMMABILITY CONTROL STRATEGY AT THE DWPF

    SciTech Connect (OSTI)

    Edwards, T.; Lambert, D.

    2014-08-27

    The Savannah River National Laboratory (SRNL) has been working with the Savannah River Remediation (SRR) Defense Waste Processing Facility (DWPF) in the development and implementation of an additional strategy for confidently satisfying the flammability controls for DWPF’s melter operation. An initial strategy for implementing the operational constraints associated with flammability control in DWPF was based upon an analytically determined carbon concentration from antifoam. Due to the conservative error structure associated with the analytical approach, its implementation has significantly reduced the operating window for processing and has led to recurrent Slurry Mix Evaporator (SME) and Melter Feed Tank (MFT) remediation. To address the adverse operating impact of the current implementation strategy, SRR issued a Technical Task Request (TTR) to SRNL requesting the development and documentation of an alternate strategy for evaluating the carbon contribution from antifoam. The proposed strategy presented in this report was developed under the guidance of a Task Technical and Quality Assurance Plan (TTQAP) and involves calculating the carbon concentration from antifoam based upon the actual mass of antifoam added to the process assuming 100% retention. The mass of antifoam in the Additive Mix Feed Tank (AMFT), in the Sludge Receipt and Adjustment Tank (SRAT), and in the SME is tracked by mass balance as part of this strategy. As these quantities are monitored, the random and bias uncertainties affecting their values are also maintained and accounted for. This report documents: 1) the development of an alternate implementation strategy and associated equations describing the carbon concentration from antifoam in each SME batch derived from the actual amount of antifoam introduced into the AMFT, SRAT, and SME during the processing of the batch. 2) the equations and error structure for incorporating the proposed strategy into melter off-gas flammability assessments. Sample calculations of the system are also included in this report. Please note that the system developed and documented in this report is intended as an alternative to the current, analytically-driven system being utilized by DWPF; the proposed system is not intended to eliminate the current system. Also note that the system developed in this report to track antifoam mass in the AMFT, SRAT, and SME will be applicable beyond just Sludge Batch 8. While the model used to determine acceptability of the SME product with respect to melter off-gas flammability controls must be reassessed for each change in sludge batch, the antifoam mass tracking methodology is independent of sludge batch composition and as such will be transferable to future sludge batches.

  17. Utilization of Common Automotive Three-Way NO{sub x} Reduction Catalyst for Managing Off- Gas from Thermal Treatment of High-Nitrate Waste - 13094

    SciTech Connect (OSTI)

    Foster, Adam L.; Ki Song, P.E.

    2013-07-01

    Studsvik's Thermal Organic Reduction (THOR) steam reforming process has been tested and proven to effectively treat radioactive and hazardous wastes streams with high nitrate contents to produce dry, stable mineral products, while providing high conversion (>98%) of nitrates and nitrites directly to nitrogen gas. However, increased NO{sub x} reduction may be desired for some waste streams under certain regulatory frameworks. In order to enhance the NO{sub x} reduction performance of the THOR process, a common Three-Way catalytic NO{sub x} reduction unit was installed in the process gas piping of a recently completed Engineering Scale Technology Demonstration (ESTD). The catalytic DeNO{sub x} unit was located downstream of the main THOR process vessel, and it was designed to catalyze the reduction of residual NO{sub x} to nitrogen gas via the oxidation of the hydrogen, carbon monoxide, and volatile organic compounds that are inherent to the THOR process gas. There was no need for auxiliary injection of a reducing gas, such as ammonia. The unit consisted of four monolith type catalyst sections positioned in series with a gas mixing section located between each catalyst section. The process gas was monitored for NO{sub x} concentration upstream and downstream of the catalytic DeNO{sub x} unit. Conversion efficiencies ranged from 91% to 97% across the catalytic unit, depending on the composition of the inlet gas. Higher concentrations of hydrogen and carbon monoxide in the THOR process gas increased the NO{sub x} reduction capability of the catalytic DeNO{sub x} unit. The NO{sub x} destruction performance of THOR process in combination with the Three-Way catalytic unit resulted in overall system NO{sub x} reduction efficiencies of greater than 99.9% with an average NO{sub x} reduction efficiency of 99.94% for the entire demonstration program. This allowed the NO{sub x} concentration in the ESTD exhaust gas to be maintained at less than 40 parts per million (ppm), dry basis with an average concentration of approximately 17 ppm, dry basis. There were no signs of catalyst deactivation throughout the 6 day demonstration program, even under the high steam (>50%) content and chemically reducing conditions inherent to the THOR process. Utilization of the common Three-Way automotive catalyst may prove to be a cost effective method for improving NO{sub x} emissions from thermal treatment processes that utilize similar processing conditions. This paper will discuss the details of the implementation and performance of the Three-Way catalytic DeNO{sub x} unit at the THOR ESTD, as well as a discussion of future work to determine the long-term durability of the catalyst in the THOR process. (authors)

  18. Cold Crucible Induction Melter (CCIM) Demonstration Using a Representative Savannah River Site Sludge Simulant On the Large-Size Pilot Platform at the CEA-Marcoule

    SciTech Connect (OSTI)

    Girold, C.; Delaunay, M.; Dussossoy, J.L.; Lacombe, J. [CEA Marcoule, CEA/DEN/DTCD/SCDV, 30 (France); Marra, S.; Peeler, D.; Herman, C.; Smith, M.; Edwards, R.; Barnes, A.; Stone, M. [Savannah River National Laboratory (SRNL), Washington Savannah River Company, Savannah River Site, Aiken, SC (United States); Iverson, D. [Liquid Waste Operations, Washington Savannah River Company (WSRC), Aiken, SC (United States); Do Quang, R. [AREVA NC, Tour AREVA, 92 - Paris La Defense (France); Tchemitcheff, E. [AREVA Federal Services LLC, Richland Office, Richland, WA (United States); Veyer, C. [Consultant, 59 - Saint Waast la Vallee (France)

    2008-07-01

    The cold-crucible induction melter technology (CCIM) is considered worldwide for industrial implementation to overcome the current limits of high level waste vitrification technologies and to answer future challenges such as: new or difficult sludge compositions, need for improving waste loading, need for high temperatures, and corrosive effluents. More particularly, this technology is being considered for implementation at the US DOE Savannah River site to increase the rate of waste processing while reducing the number of HLW canisters to be produced through increased waste loading and improved waste throughput. A collaborative program involving AREVA, CEA (French Atomic Energy Commission), SRNL (Savannah River National Laboratory) and WSRC (Washington Savannah River Company) has thus been initiated in 2007 to demonstrate vitrification with waste loadings on the order of 50% (versus the current DWPF waste loading of about 35%) with a PUREX-type waste composition (high Fe{sub 2}O{sub 3} composition), and to perform two pilot-scale runs on the large size platform equipped with a 650 mm diameter CCIM at the CEA Marcoule. The objectives of the demonstrations were 1) to show the feasibility of processing a representative SRS sludge surrogate using continuous slurry feeding, 2) to produce a glass that would meet the acceptance specifications with an increased waste loading when compared to what is presently achieved at the DWPF, and 3) achieve improved waste throughputs. This presentation describes the platform and the very encouraging results obtained from the demonstration performed at temperatures, specific throughputs and waste loadings that overcome current DWPF limits. Results from the initial exploratory run and second demonstration run include 1) production of a glass product that achieved the targeted glass composition that was more durable than the standard Environmental Assessment (EA) glass, 2) successful slurry feeding of the CCIM, and 3) promising waste processing rates (at 1250 deg. C and 1300 deg. C melt pool temperature) that could result in processing of the Savannah River HLW faster than could be currently achieved with the existing Joule Heated melter in DWPF. In conclusion, this joint effort conducted by CEA, AREVA, SRNL and WSRC led to very encouraging results, demonstrating waste throughputs 44 % that of the DWPF ceramic melter throughput in a 650 mm CCIM melter for the same waste type with a Sludge Batch 3 PUREX-type waste feed flux of 150 L/h/m{sup 2} demonstrated at 1250 deg. C. The very high waste loading (above 52%) allows reducing the amount of glass to be produced by about 27% to treat the same amount of waste when compared to previous DWPF operation for this specific type of feed, since 27 % less glass is needed to immobilize the same amount of waste. It was also demonstrated, for this type of feed, an unusual behavior with regard to nepheline formation, which would require further evaluation for future applications. The product from the baseline demonstration run, with a waste loading of at least 52%, displayed a very good quality. Stabilized operation close to the maximum throughput was demonstrated. Cesium volatility was apparently between 7 and 12 % (based on glass analysis); however this value is only preliminary. This demonstration also allowed the CEA to better understand the SRS slurry feed behavior and to propose adaptations to the platform for any future demonstrations using this type of feed. Finally, use of a large diameter CCIM ({approx}1 meter) may allow faster processing of the SRS HLW than can be achieved with the current DWPF melter. (authors)

  19. FINAL REPORT INTEGRATED DM1200 MELTER TESTING OF BUBBLER CONFIGURATIONS USING HLW AZ-101 SIMULANTS VSL-04R4800-4 REV 0 10/5/04

    SciTech Connect (OSTI)

    KRUGER AA; MATLACK KS; GONG W; BARDAKCI T; D'ANGELO NA; LUTZE W; CALLOW RA; BRANDYS M; KOT WK; PEGG IL

    2011-12-29

    This report documents melter and off-gas performance results obtained on the DM1200 HLW Pilot Melter during processing of AZ-101 HLW simulants. The tests reported herein are a subset of six tests from a larger series of tests described in the Test Plan for the work; results from the other tests have been reported separately. The solids contents of the melter feeds were based on the WTP baseline value for the solids content of the feeds from pretreatment which changed during these tests from 20% to 15% undissolved solids resulting in tests conducted at two feed solids contents. Based on the results of earlier tests with single outlet 'J' bubblers, initial tests were performed with a total bubbling rate of 651 pm. The first set of tests (Tests 1A-1E) addressed the effects of skewing this total air flow rate back and forth between the two installed bubblers in comparison to a fixed equal division of flow between them. The second set of tests (2A-2D) addressed the effects of bubbler depth. Subsequently, as the location, type and number of bubbling outlets were varied, the optimum bubbling rate for each was determined. A third (3A-3C) and fourth (8A-8C) set of tests evaluated the effects of alternative bubbler designs with two gas outlets per bubbler instead of one by placing four bubblers in positions simulating multiple-outlet bubblers. Data from the simulated multiple outlet bubblers were used to design bubblers with two outlets for an additional set of tests (9A-9C). Test 9 was also used to determine the effect of small sugar additions to the feed on ruthenium volatility. Another set of tests (10A-10D) evaluated the effects on production rate of spiking the feed with chloride and sulfate. Variables held constant to the extent possible included melt temperature, plenum temperature, cold cap coverage, the waste simulant composition, and the target glass composition. The feed rate was increased to the point that a constant, essentially complete, cold cap was achieved, which was used as an indicator of a maximized feed rate for each test. The first day of each test was used to build the cold cap and decrease the plenum temperature. The remainder of each test was split into two- to six-day segments, each with a different bubbling rate, bubbler orientation, or feed concentration of chloride and sulfur.

  20. Test plan for evaluation of plasma melter technology for vitrification of high-sodium content low-level radioactive liquid wastes

    SciTech Connect (OSTI)

    McLaughlin, D.F.; Lahoda, E.J.; Gass, W.R.; D`Amico, N.

    1994-10-20

    This document provides a test plan for the conduct of plasma arc vitrification testing by a vendor in support of the Hanford Tank Waste Remediation System (TWRS) Low-Level Waste (LLW) Vitrification Program. The vendor providing this test plan and conducting the work detailed within it [one of seven selected for glass melter testing under Purchase Order MMI-SVV-384212] is the Westinghouse Science and Technology Center (WSTC) in Pittsburgh, PA. WSTC authors of the test plan are D. F. McLaughlin, E. J. Lahoda, W. R. Gass, and N. D`Amico. The WSTC Program Manager for this test is D. F. McLaughlin. This test plan is for Phase I activities described in the above Purchase Order. Test conduct includes melting of glass frit with Hanford LLW Double-Shell Slurry Feed waste simulant in a plasma arc fired furnace.

  1. Crystalline Ceramic Waste Forms: Report Detailing Data Collection In Support Of Potential FY13 Pilot Scale Melter Test

    SciTech Connect (OSTI)

    Brinkman, K. S.; Amoroso, J.; Marra, J. C.; Fox, K. M.

    2012-09-21

    The research conducted in this work package is aimed at taking advantage of the long term thermodynamic stability of crystalline ceramics to create more durable waste forms (as compared to high level waste glass) in order to reduce the reliance on engineered and natural barrier systems. Durable ceramic waste forms that incorporate a wide range of radionuclides have the potential to broaden the available disposal options and to lower the storage and disposal costs associated with advanced fuel cycles. Assemblages of several titanate phases have been successfully demonstrated to incorporate radioactive waste elements, and the multiphase nature of these materials allows them to accommodate variation in the waste composition. Recent work has shown that they can be successfully produced from a melting and crystallization process. The objective of this report is to summarize the data collection in support of future melter demonstration testing for crystalline ceramic waste forms. The waste stream used as the basis for the development and testing is a combination of the projected Cs/Sr separated stream, the Trivalent Actinide - Lanthanide Separation by Phosphorous reagent Extraction from Aqueous Komplexes (TALSPEAK) waste stream consisting of lanthanide fission products, the transition metal fission product waste stream resulting from the transuranic extraction (TRUEX) process, and a high molybdenum concentration with relatively low noble metal concentrations. The principal difficulties encountered during processing of the ?reference ceramic? waste form by a melt and crystallization process were the incomplete incorporation of Cs into the hollandite phase and the presence of secondary Cs-Mo non-durable phases. In the single phase hollandite system, these issues were addressed in this study by refining the compositions to include Cr as a transition metal element and the use of Ti/TiO{sub 2} buffer to maintain reducing conditions. Initial viscosity studies of ceramic waste forms indicated that the pour spout must be maintained above 1400{deg}C to avoid flow blockages due to crystallization. In-situ electron irradiations simulate radiolysis effects indicated hollandite undergoes a crystalline to amorphous transition after a radiation dose of 10{sup 13} Gy which corresponds to approximately 1000 years at anticipated doses (2?10{sup 10}-2?10{sup 11} Gy). Dual-beam ion irradiations employing light ion beam (such as 5 MeV alpha) and heavy ion beam (such as 100 keV Kr) studies indicate that reference ceramic waste forms are radiation tolerant to the ??particles and ?-particles, but are susceptible to a crystalline to amorphous transition under recoil nuclei effects. A path forward for refining the processing steps needed to form the targeted phase assemblages is outlined in this report. Processing modifications including melting in a reducing atmosphere with the use of Ti/TiO2 buffers, and the addition of Cr to the transition metal additives to facilitate Cs-incorporation in the hollandite phase. In addition to melt processing, alternative fabrication routes are being considered including Spark Plasma Sintering (SPS) and Hot Isostatic Pressing (HIP).

  2. Final Vitrification Melter Evaluation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015Executive Order14,Energy 9,UNIVERSITY OF TEXAS AT||Solar

  3. FINAL REPORT MELTER TESTS WITH AZ-101 HLW SIMULANT USING A DURAMELTER 100 VITRIFICATION SYSTEM VSL-01R10N0-1 REV 1 2/25/02

    SciTech Connect (OSTI)

    KRUGER AA; MATLACK KS; KOT WK; PEGG IL

    2011-12-29

    This report provides data, analyses, and conclusions from a series of tests that were conducted at the Vitreous State Laboratory of The Catholic of America (VSL) to determine the processing rates that are achievable with AZ-101 HLW simulants and corresponding melter feeds on a DuraMelter 100 (DM100) vitrification system. One of the most critical pieces of information in determining the required size of the RPP-WTP HLW melter is the specific glass production rate in terms of the mass of glass that can be produced per unit area of melt surface per unit time. The specific glass production rate together with the waste loading (essentially, the ratio of waste-in to glass-out, which is determined from glass formulation activities) determines the melt area that is needed to achieve a given waste processing rate with due allowance for system availability. Tests conducted during Part B1 (VSL-00R2590-2) on the DM1000 vitrification system installed at the Vitreous State Laboratory of The Catholic University of America showed that, without the use of bubblers, glass production rates with AZ-101 and C-106/AY-102 simulants were significantly lower than the Project design basis rate of 0.4 MT/m{sup 2}/d. Conversely, three-fold increases over the design basis rate were demonstrated with the use of bubblers. Furthermore, an un-bubbled control test using a replica of the melter feed used in cold commissioning tests at West Valley reproduced the rates that were observed with that feed on the WVDP production melter. More recent tests conducted on the DM1200 system, which more closely represents the present RPP-WTP design, are in general agreement with these earlier results. Screening tests conducted on the DM10 system have provided good indications of the larger-scale processing rates with bubblers (for both HL W and LAW feeds) but significantly overestimated the DM1000 un-bubbled rate observed for C-106/AY-102 melter feeds. This behavior is believed to be a consequence of the role of heat transfer in rate attainment and the much greater role of wall effects in heat transfer when the melt pool is not agitated. The DM100 melter used for the present tests has a surface area of 0.108 m{sup 2}, which is approximately 5 times larger than that of the DM10 (0.021 m{sup 2}) and approximately 11 times smaller than that of the DM1000 (1.2 m{sup 2}) (the DM1000 has since been replaced by a pilot-scale prototypical HLW melter, designated the DM1200, which has the same surface area as the DM1000). Testing on smaller melters is the most economical method for obtaining data over a wide range of operating conditions (particularly at extremes) and for guiding the more expensive tests that are performed at pilot-scale. Thus, one objective of these tests was to determine whether the DM100 melters are sufficiently large to reproduce the un-bubbled melt rates observed at the DM1000 scale, or to determine the extent of any off-set. DM100-scale tests can then be used to screen feed chemistry variations that may serve to increase the un-bubbled production rates prior to confirmation at pilot scale. Finally, extensive characterization data obtained on simulated HLW melter feeds formed from various glass forming additives indicated that there may be advantages in terms of feed rheology and stability to the replacement of some of the hydroxides by carbonates. A further objective of the present tests was therefore to identify any deleterious processing effects of such a change before adopting the carbonate feed as the baseline. Data from the WVDP melter using acidified (nitrated) feeds, and without bubbling, showed productions rates that are higher than those observed with the alkaline RPP feeds at the VSL. Therefore, the effect of feed acidification on production rate also was investigated. This work was performed under Test Specification, 'TSP-W375-00-00019, Rev 0, 'HLW-DM10 and DM100 Melter Tests' dated November 13, 2000 and the corresponding Test Plan. It should be noted, however, that the RPP-WTP Project directed a series of changes to the Test Plan as the result

  4. Thermal engine

    SciTech Connect (OSTI)

    Karnes, T.E.; Trupin, R.J.

    1984-01-03

    A thermal engine utilizing a strip of nitinol material or other thermally responsive shape memory effect material to drive a reciprocating output shaft, said strip of material forming a common wall between two different alternating temperature sources which thermally cycle the material.

  5. Waste Treatment Plant - 12508

    SciTech Connect (OSTI)

    Harp, Benton; Olds, Erik

    2012-07-01

    The Waste Treatment Plant (WTP) will immobilize millions of gallons of Hanford's tank waste into solid glass using a proven technology called vitrification. The vitrification process will turn the waste into a stable glass form that is safe for long-term storage. Our discussion of the WTP will include a description of the ongoing design and construction of this large, complex, first-of-a-kind project. The concept for the operation of the WTP is to separate high-level and low-activity waste fractions, and immobilize those fractions in glass using vitrification. The WTP includes four major nuclear facilities and various support facilities. Waste from the Tank Farms is first pumped to the Pretreatment Facility at the WTP through an underground pipe-in-pipe system. When construction is complete, the Pretreatment Facility will be 12 stories high, 540 feet long and 215 feet wide, making it the largest of the four major nuclear facilities that compose the WTP. The total size of this facility will be more than 490,000 square feet. More than 8.2 million craft hours are required to construct this facility. Currently, the Pretreatment Facility is 51 percent complete. At the Pretreatment Facility the waste is pumped to the interior waste feed receipt vessels. Each of these four vessels is 55-feet tall and has a 375,000 gallon capacity, which makes them the largest vessels inside the Pretreatment Facility. These vessels contain a series of internal pulse-jet mixers to keep incoming waste properly mixed. The vessels are inside the black-cell areas, completely enclosed behind thick steel-laced, high strength concrete walls. The black cells are designed to be maintenance free with no moving parts. Once hot operations commence the black-cell area will be inaccessible. Surrounded by black cells, is the 'hot cell canyon'. The hot cell contains all the moving and replaceable components to remove solids and extract liquids. In this area, there is ultrafiltration equipment, cesium-ion exchange columns, evaporator boilers and recirculation pumps, and various mechanical process pumps for transferring process fluids. During the first phase of pretreatment, the waste will be concentrated using an evaporation process. Solids will be filtered out, and the remaining soluble, highly radioactive isotopes will be removed using an ion-exchange process. The high-level solids will be sent to the High-Level Waste (HLW) Vitrification Facility, and the low activity liquids will be sent to the Low-Activity Waste (LAW) Vitrification Facility for further processing. The high-level waste will be transferred via underground pipes to the HLW Facility from the Pretreatment Facility. The waste first arrives at the wet cell, which rests inside a black-cell area. The pretreated waste is transferred through shielded pipes into a series of melter preparation and feed vessels before reaching the melters. Liquids from various facility processes also return to the wet cell for interim storage before recycling back to the Pretreatment Facility. (authors)

  6. Summary - Flowsheet for the Hanford Waste Treatment Plant

    Office of Environmental Management (EM)

    and effectiveness of cesium-137 monitoring. The control strategy for the LAW Vitrification Facility will likely lead to mis-batching of melter feed. Difficult to remove...

  7. FINAL REPORT INTEGRATED DM1200 MELTER TESTING OF REDOX EFFECTS USING HLW AZ-101 AND C-106/AY-102 SIMULANTS VSL-04R4800-1 REV 0 5/6/

    SciTech Connect (OSTI)

    KRUGER AA; MATLACK KS; GONG W; BARDAKCI T; D'ANGELO NA; LUTZE W; BIZOT PM; CALLOW RA; BRANDYS M; KOT WK; PEGG IL

    2011-12-29

    This report documents melter and off-gas performance results obtained on the DM1200 HLW Pilot Melter during processing of AZ-101 and C-106/AY-102 HLW simulants. The tests reported herein are a subset of three tests from a larger series of tests described in the Test Plan for the work; results from the remaining tests will be reported separately. Three nine day tests, one with AZ-101 and two with C-106/AY-102 feeds were conducted with variable amounts of added sugar to address the effects of redox. The test with AZ-101 included ruthenium spikes to also address the effects of redox on ruthenium volatility. One of tests addressed the effects of increased flow-sheet nitrate levels using C-106/AY-102 feeds. With high nitrate/nitrite feeds (such as WTP LAW feeds), reductants are required to prevent melt foaming and deleterious effects on glass production rates. Sugar is the baseline WTP reductant for this purpose. WTP HLW feeds typically have relatively low nitrate/nitrite content in comparison to the organic carbon content and, therefore, have typically not required sugar additions. However, HLW feed variability, particularly with respect to nitrate levels, may necessitate the use of sugar in some instances. The tests reported here investigate the effects of variable sugar additions to the melter feed as well as elevated nitrate levels in the waste. Variables held constant to the extent possible included melt temperature, bubbling rate, plenum temperature, cold cap coverage, the waste simulant composition, and the target glass composition. The principal objectives of the DM1200 melter testing were to determine the achievable glass production rates for simulated HLW feeds with variable amounts of added sugar and increased nitrate levels; characterize melter off-gas emissions; characterize the performance of the prototypical off-gas system components as well as their integrated performance; characterize the feed, glass product, and off-gas effluents; and perform pre- and post test inspections of system components. The specific objectives (including test success criteria) of this testing, along with how each objective was met, are outlined in a table.

  8. Performance Enhancements to the Hanford Waste Treatment and Immobilization Plant Low-Activity Waste Vitrification System

    SciTech Connect (OSTI)

    Hamel, W. F. [Office of River Protection, U.S. Department of Energy, 2400 Stevens Drive, Richland, WA 99354 (United States); Gerdes, K. [U.S. Department of Energy, 19901 Germantown Road, Germantown, MD 20874 (United States); Holton, L. K. [Pacific Northwest National Laboratory, PO Box 999, Richland, WA 99352 (United States); Pegg, I.L. [Vitreous State Laboratory, The Catholic University of America, 620 Michigan Avenue NE, Washington, DC 20064 (United States); Bowan, B.W. [Duratek, Inc., 10100 Old Columbia Road, Columbia, Maryland 21046 (United States)

    2006-07-01

    The U.S Department of Energy Office of River Protection (DOE-ORP) is constructing a Waste Treatment and Immobilization Plant (WTP) for the treatment and vitrification of underground tank wastes stored at the Hanford Site in Washington State. The WTP comprises four major facilities: a pretreatment facility to separate the tank waste into high level waste (HLW) and low-activity waste (LAW) process streams, a HLW vitrification facility to immobilize the HLW fraction; a LAW vitrification facility to immobilize the LAW fraction, and an analytical laboratory to support the operations of all four treatment facilities. DOE has established strategic objectives to optimize the performance of the WTP facilities and the LAW and HLW waste forms to reduce the overall schedule and cost for treatment and vitrification of the Hanford tank wastes. This strategy has been implemented by establishing performance expectations in the WTP contract for the facilities and waste forms. In addition, DOE, as owner-operator of the WTP facilities, continues to evaluate 1) the design, to determine the potential for performance above the requirements specified in the WTP contract; and 2) improvements in production of the LAW and HLW waste forms. This paper reports recent progress directed at improving production of the LAW waste form. DOE's initial assessment, which is based on the work reported in this paper, is that the treatment rate of the WTP LAW vitrification facility can be increased by a factor of 2 to 4 with a combination of revised glass formulations, modest increases in melter glass operating temperatures, and a second-generation LAW melter with a larger surface area. Implementing these improvements in the LAW waste immobilization capability can benefit the LAW treatment mission by reducing the cost of waste treatment. (authors)

  9. Solar Thermal Powered Evaporators

    E-Print Network [OSTI]

    Moe, Christian Robert

    2015-01-01

    Solar Thermal Collectors .is solar energy. Solar thermal collector arrays can be usedon integrating solar thermal collectors with desalination

  10. Solar Thermal Powered Evaporators

    E-Print Network [OSTI]

    Moe, Christian Robert

    2015-01-01

    and thermal energy storage in solar thermal applications,"aided or powered by solar thermal energy. A section is alsoexhaustive review of solar thermal energy systems has been

  11. Advanced Thermal Control

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    thermal models power density cost lifetime Advanced Thermal Interface Materials Advanced Heat Transfer Technologies Air Cooling Thermal System Performance and Integration Thermal...

  12. LABORATORY OPTIMIZATION TESTS OF TECHNETIUM DECONTAMINATION OF HANFORD WASTE TREATMENT PLANT LOW ACTIVITY WASTE OFF-GAS CONDENSATE SIMULANT

    SciTech Connect (OSTI)

    Taylor-Pashow, K.; Nash, C.; McCabe, D.

    2014-09-29

    The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream (LAW Off-Gas Condensate) from the off-gas system. The baseline plan for disposition of this stream is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility again. Alternate disposition of this stream would eliminate recycling of problematic components, and would enable de-coupled operation of the LAW melter and the Pretreatment Facilities. Eliminating this stream from recycling within WTP would also decrease the LAW vitrification mission duration and quantity of glass waste. This LAW Off-Gas Condensate stream contains components that are volatile at melter temperatures and are problematic for the glass waste form. Because this stream recycles within WTP, these components accumulate in the Condensate stream, exacerbating their impact on the number of LAW glass containers that must be produced. Approximately 32% of the sodium in Supplemental LAW comes from glass formers used to make the extra glass to dilute the halides to acceptable concentrations in the LAW glass, and diverting the stream reduces the halides in the recycled Condensate and is a key outcome of this work. Additionally, under possible scenarios where the LAW vitrification facility commences operation prior to the WTP Pretreatment facility, identifying a disposition path becomes vitally important. This task examines the potential treatment of this stream to remove radionuclides and subsequently disposition the decontaminated stream elsewhere, such as the Effluent Treatment Facility (ETF), for example. The treatment process envisioned is very similar to that used for the Actinide Removal Process (ARP) that has been operating for years at the Savannah River Site (SRS), and focuses on using mature radionuclide removal technologies that are also compatible with longterm tank storage and immobilization methods. For this new application, testing is needed to demonstrate acceptable treatment sorbents and precipitating agents and measure decontamination factors for additional radionuclides in this unique waste stream. The origin of this LAW Off-Gas Condensate stream will be the liquids from the Submerged Bed Scrubber (SBS) and the Wet Electrostatic Precipitator (WESP) from the LAW melter off-gas system. The stream is expected to be a dilute salt solution with near neutral pH, and will likely contain some insoluble solids from melter carryover. The soluble components are expected to be mostly sodium and ammonium salts of nitrate, chloride, and fluoride. This stream has not been generated yet and will not be available until the WTP begins operation, but a simulant has been produced based on models, calculations, and comparison with pilot-scale tests. One of the radionuclides that is volatile and expected to be in greatest abundance in this LAW Off-Gas Condensate stream is Technetium-99 ({sup 99}Tc). Technetium will not be removed from the aqueous waste in the Hanford WTP, and will primarily end up immobilized in the LAW glass by repeated recycle of the off-gas condensate into the LAW melter. Other radionuclides that are low but are also expected to be in measurable concentration in the LAW Off-Gas Condensate are {sup 129}I, {sup 90}Sr, {sup 137}Cs, {sup 241}Pu, and {sup 241}Am. These are present due to their partial volatility and some entrainment in the off-gas system. This report discusses results of optimized {sup 99}Tc decontamination testing of the simulant. Testing examined use of inorganic reducing agents for {sup 99}Tc. Testing focused on minimizing the quantity of sorbents/reactants added, and minimizing mixing time to reach the decontamination targets in this simulant formulation. Stannous chloride and ferrous sulfate were tested as reducing agents to determine the minimum needed to convert soluble pertechnetate to the insoluble technetium dioxide. The reducing agents were tried with and without sorbents.

  13. Laboratory Evaporation Testing Of Hanford Waste Treatment Plant Low Activity Waste Off-Gas Condensate Simulant

    SciTech Connect (OSTI)

    Adamson, Duane J.; Nash, Charles A.; McCabe, Daniel J.; Crawford, Charles L.; Wilmarth, William R.

    2014-01-27

    The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream, LAW Off-Gas Condensate, from the off-gas system. The baseline plan for disposition of this stream is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility again. Alternate disposition of this stream would eliminate recycling of problematic components, and would enable de-coupled operation of the LAW melter and the Pretreatment Facilities. Eliminating this stream from recycling within WTP would also decrease the LAW vitrification mission duration and quantity of canistered glass waste forms. This LAW Off-Gas Condensate stream contains components that are volatile at melter temperatures and are problematic for the glass waste form. Because this stream recycles within WTP, these components accumulate in the Condensate stream, exacerbating their impact on the number of LAW glass containers that must be produced. Approximately 32% of the sodium in Supplemental LAW comes from glass formers used to make the extra glass to dilute the halides to be within acceptable concentration ranges in the LAW glass. Diverting the stream reduces the halides in the recycled Condensate and is a key outcome of this work. Additionally, under possible scenarios where the LAW vitrification facility commences operation prior to the WTP Pretreatment facility, identifying a disposition path becomes vitally important. This task examines the impact of potential future disposition of this stream in the Hanford tank farms, and investigates auxiliary evaporation to enable another disposition path. Unless an auxiliary evaporator is used, returning the stream to the tank farms would require evaporation in the 242-A evaporator. This stream is expected to be unusual because it will be very high in corrosive species that are volatile in the melter (chloride, fluoride, sulfur), will have high ammonia, and will contain carryover particulates of glass-former chemicals. These species have potential to cause corrosion of tanks and equipment, precipitation of solids, release of ammonia gas vapors, and scale in the tank farm evaporator. Routing this stream to the tank farms does not permanently divert it from recycling into the WTP, only temporarily stores it prior to reprocessing. Testing is normally performed to demonstrate acceptable conditions and limits for these compounds in wastes sent to the tank farms. The primary parameter of this phase of the test program was measuring the formation of solids during evaporation in order to assess the compatibility of the stream with the evaporator and transfer and storage equipment. The origin of this LAW Off-Gas Condensate stream will be the liquids from the Submerged Bed Scrubber (SBS) and the Wet Electrostatic Precipitator (WESP) from the LAW facility melter offgas system. The stream is expected to be a dilute salt solution with near neutral pH, and will likely contain some insoluble solids from melter carryover. The soluble components are expected to be mostly sodium and ammonium salts of nitrate, chloride, and fluoride. This stream has not been generated yet, and, thus, the composition will not be available until the WTP begins operation, but a simulant has been produced based on models, calculations, and comparison with pilot-scale tests. This report discusses results of evaporation testing of the simulant. Two conditions were tested, one with the simulant at near neutral pH, and a second at alkaline pH. The neutral pH test is comparable to the conditions in the Hanford Effluent Treatment Facility (ETF) evaporator, although that evaporator operates at near atmospheric pressure and tests were done under vacuum. For the alkaline test, the target pH was based on the tank farm corrosion control program requirements, and the test protocol and equipment was comparable to that used for routine evaluation of feed compatibility studies for the 242-A evaporator. One of the

  14. Dry-out and low temperature calcination of DST/SST waste blend high temperature melter feed

    SciTech Connect (OSTI)

    Smith, H.D.; Tracey, E.M.

    1996-02-01

    The FY1994 DST/SST blend was prepared in accordance with the DST/SST blend feed specification. The laboratory preparation steps and observations were compared with an existing experience base to verify the acceptability of the feed specification for simulant make-up. The most significant test results included a variety of features. Ferrocyanide breaks down to NH{sub 3} plus formate, during the low-temperature calcining phase of the tests. Ferrocyanide displayed no redox reactivity with the nitrates and nitrites contained in the slurry in the absence of sugar. Sugar displays a redox reaction with the nitrates and nitrites in the blend similar to the redox. reaction observed in the LLW feed simulant. Boiling of a free flowing slurry occurs at temperatures below about 120{degrees}C. When about 45% of the total water loss has occurred, the feed slurry congeals and continues to lose water, shrinking and developing shrinkage cracks. Water stops coming off between 350{degrees}C and 400{degrees}C. Slurry shear strength and viscosity strongly increase as the weight percent solids increases from 20 wt% to 45 wt%. The 45 wt% solids corresponds to approximately a 40 % water loss. The principle beat sensitivity for this material is the exothermic reaction which is activated when the temperature exceeds about 250{degrees}C. The breakdown of ferrocyanide to ammonia and formate under strongly basic conditions may begin at temperatures less than 100{degrees}C, but the rate increased strongly with increasing temperature and appeared to be completed in the time of our tests. Differential thermal analysis (DTA) results on feed slurry without and with ferrocyanide showed only endothermic behavior. This is consistent with the dry out and low temperature calcine studies which did not indicate any exothermic behavior for the feed slurry with and without ferrocyanide.

  15. Waste Treatment and Immobilization Plant U. S. Department of Energy Office of River Protection Submerged Bed Scrubber Condensate Disposition Project - 13460

    SciTech Connect (OSTI)

    Yanochko, Ronald M. [Washington River Protection Solutions, P.O. Box 850, Richland, Washington 99352 (United States)] [Washington River Protection Solutions, P.O. Box 850, Richland, Washington 99352 (United States); Corcoran, Connie [AEM Consulting, LLC, 1201 Jadwin Avenue, Richland, Washington 99352 (United States)] [AEM Consulting, LLC, 1201 Jadwin Avenue, Richland, Washington 99352 (United States)

    2013-07-01

    The Hanford Waste Treatment and Immobilization Plant (WTP) will generate an off-gas treatment system secondary liquid waste stream [submerged bed scrubber (SBS) condensate], which is currently planned for recycle back to the WTP Low Activity Waste (LAW) melter. This SBS condensate waste stream is high in Tc-99, which is not efficiently captured in the vitrified glass matrix [1]. A pre-conceptual engineering study was prepared in fiscal year 2012 to evaluate alternate flow paths for melter off-gas secondary liquid waste generated by the WTP LAW facility [2]. This study evaluated alternatives for direct off-site disposal of this SBS without pre-treatment, which mitigates potential issues associated with recycling. This study [2] concluded that SBS direct disposal is a viable option to the WTP baseline. The results show: - Off-site transportation and disposal of the SBS condensate is achievable and cost effective. - Reduction of approximately 4,325 vitrified WTP Low Activity Waste canisters could be realized. - Positive WTP operational impacts; minimal WTP construction impacts are realized. - Reduction of mass flow from the LAW Facility to the Pretreatment Facility by 66%. - Improved Double Shell Tank (DST) space management is a benefit. (authors)

  16. Documentation on currently operating low-level radioactive waste treatment systems: National Low-Level Waste Management Program

    SciTech Connect (OSTI)

    Not Available

    1987-11-01

    In May 1985, the US Department of Energy issued a Program Research and Development Announcement requesting documentation on currently operating low-level radioactive waste treatment systems. Six grants were awarded to support that documentation. Final reports for the following grants and grantees are compiled in this document: Shredder/Compactor Report by Impell Corp., Volume Reduction and Solidification System for Low-Level Radwaste Treatment by Waste Chem Corp., Low-Level Radioactive Waste Treatment Systems in Northern Europe by Pacific Nuclear Services/Nuclear Packaging Inc., The University of Missouri Research Reactor Facility Can Melter System by the University of Missouri, Drying of Ion-Exchange Resin and Filter Media by Nuclear Packaging Inc., and Operational Experience with Selective Ion-Exchange Media in Sluiceable Pressurized Demineralizers at Nuclear Power Plants by Analytical Resources Inc. 65 refs., 4 figs., 7 tabs.

  17. Depleted uranium dioxide melting in cold crucible melter and production of granules from the melt for use in casks for spent nuclear fuel and radioactive wastes

    SciTech Connect (OSTI)

    Gotovchikov, V.T.; Seredenko, V.A.; Shatalov, V.V.; Mironov, B.S.; Kaplenkov, V.N.; Seredenko, A.V.; Saranchin, V.K.; Shulgin, A.S. [All-Russian Research Institute of Chemical Technology (ARRICT), Moscow (Russian Federation); Haire, M.J.; Forsberg, C.W. [Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

    2007-07-01

    This paper describes the results of a joint research program between the Russian Research Institute of Chemical Technology and Oak Ridge National Laboratory in the United States to develop new radiation shielding materials for use in the construction of casks for spent nuclear fuel (SNF) and radioactive wastes. Research and development is underway to develop SNF storage, transport, and disposal casks using shielding made with two new depleted uranium dioxide (DUO{sub 2}) materials: a DUO{sub 2}-steel cermet, and, DUCRETE with DUAGG (DUO{sub 2} aggregate). Melting the DUO{sub 2} and allowing it to freeze will produce a near 100% theoretical density product and assures that the product produces no volatile materials upon subsequent heating. Induction cold-crucible melters (ICCM) are being developed for this specific application. An ICCM is, potentially, a high throughput low-cost process. Schematics of a pilot facility were developed for the production of molten DUO{sub 2} from DU{sub 3}O{sub 8} to produce granules <1 mm in diameter in a continuous mode of operation. Thermodynamic analysis was conducted for uranium-oxygen system in the temperature range from 300 to 4000 K in various gas mediums. Temperature limits of stability for various uranium oxides were determined. Experiments on melting DUO{sub 2} were carried out in a high frequency ICCM in a cold crucible with a 120 mm in diameter. The microstructure of molten DUO{sub 2} was studied and lattice parameters were determined. It was experimentally proved, and validated by X-ray analysis, that an opportunity exists to produce molten DUO{sub 2} from mixed oxides (primarily DU{sub 3}O{sub 8}) by reduction melting in ICCM. This will allow using DU{sub 3}O{sub 8} directly to make DUO{sub 2}-a separate unit operation to produce UO{sub 2} feed material is not needed. Experiments were conducted concerning the addition of alloying components, gadolinium et al. oxides, into the DUO{sub 2} melt while in the crucible. These additives improve neutron and gamma radiation shielding and operation properties of the final solids. Cermet samples of 50 wt % DUO{sub 2} were produced. (authors)

  18. AQUIFER THERMAL ENERGY STORAGE

    E-Print Network [OSTI]

    Tsang, C.-F.

    2011-01-01

    varying solar energy inputs and thermal or power demands. Itusing aquifers for thermal energy storage. Problems outlinedmatical Modeling of Thermal Energy Storage in Aquifers,"

  19. Solar Thermal Powered Evaporators

    E-Print Network [OSTI]

    Moe, Christian Robert

    2015-01-01

    of solar collectors and thermal energy storage in solaraided or powered by solar thermal energy. A section is alsobesides MVC require thermal energy as their primary energy

  20. Solar Thermal Powered Evaporators

    E-Print Network [OSTI]

    Moe, Christian Robert

    2015-01-01

    15] O. A. Hamed, "THERMAL PERFORMANCE OF MULTISTAGE FLASHdesa4.aspx. [18] Encon, "Thermal Evaporators," June 2013. [http://www.evaporator.com/thermal-evaporator. [19] Y. Tian

  1. AQUIFER THERMAL ENERGY STORAGE

    E-Print Network [OSTI]

    Tsang, C.-F.

    2011-01-01

    of such an aquifer thermal storage system were studied andusing aquifers for thermal energy storage. Problems outlinedmatical Modeling of Thermal Energy Storage in Aquifers,"

  2. Solar Thermal Powered Evaporators

    E-Print Network [OSTI]

    Moe, Christian Robert

    2015-01-01

    This requires no thermal storage tanks, but can have athe need for large thermal storage equipment, the evaporatorinclude analysis of thermal storage. A way of keeping the

  3. AQUIFER THERMAL ENERGY STORAGE

    E-Print Network [OSTI]

    Tsang, C.-F.

    2011-01-01

    aquifers for thermal energy storage. Problems outlined aboveModeling of Thermal Energy Storage in Aquifers," Proceed-ings of Aquifer Thermal Energy Storage Workshop, Lawrence

  4. Examination of Thermal Impacts from Stormwater BMPs

    E-Print Network [OSTI]

    Examination of Thermal Impacts from Stormwater BMPs In a study in Durham, New Hampshire, four years treatment by infiltration and filtration can moderate runoff temperatures by thermal exchange with cool · Bioretention · Storm Tech Isolator Row · Detention Pond · Gravel Wetland · ADS Infiltration System · Retention

  5. Thermal Transport in Nanoporous Materials for Energy Applications

    E-Print Network [OSTI]

    Fang, Jin

    2012-01-01

    Thermal Conductivity Measurement . . . . . . . . . . . . .Thermal ConductivityThermal Conductivity . . . . . . . . . . . . . . . .Thermal

  6. Integrated nonthermal treatment system study

    SciTech Connect (OSTI)

    Biagi, C.; Bahar, D.; Teheranian, B.; Vetromile, J. [Morrison Knudsen Corp. (United States); Quapp, W.J. [Nuclear Metals (United States); Bechtold, T.; Brown, B.; Schwinkendorf, W. [Lockheed Martin Idaho Technologies Co., Idaho Falls, ID (United States); Swartz, G. [Swartz and Associates (United States)

    1997-01-01

    This report presents the results of a study of nonthermal treatment technologies. The study consisted of a systematic assessment of five nonthermal treatment alternatives. The treatment alternatives consist of widely varying technologies for safely destroying the hazardous organic components, reducing the volume, and preparing for final disposal of the contact-handled mixed low-level waste (MLLW) currently stored in the US Department of Energy complex. The alternatives considered were innovative nonthermal treatments for organic liquids and sludges, process residue, soil and debris. Vacuum desorption or various washing approaches are considered for treatment of soil, residue and debris. Organic destruction methods include mediated electrochemical oxidation, catalytic wet oxidation, and acid digestion. Other methods studied included stabilization technologies and mercury separation of treatment residues. This study is a companion to the integrated thermal treatment study which examined 19 alternatives for thermal treatment of MLLW waste. The quantities and physical and chemical compositions of the input waste are based on the inventory database developed by the US Department of Energy. The Integrated Nonthermal Treatment Systems (INTS) systems were evaluated using the same waste input (2,927 pounds per hour) as the Integrated Thermal Treatment Systems (ITTS). 48 refs., 68 figs., 37 tabs.

  7. Thermal and quantum noise in active systems

    E-Print Network [OSTI]

    Jean-Michel Courty; Francesca Grassia; Serge Reynaud

    2001-10-03

    We present a quantum network approach to the treatment of thermal and quantum fluctuations in measurement devices. The measurement is described as a scattering process of input fluctuations towards output ones. We present the results obtained with this method for the treatment of a cold damped capacitive accelerometer.

  8. Radioactive waste material melter apparatus

    DOE Patents [OSTI]

    Newman, D.F.; Ross, W.A.

    1990-04-24

    An apparatus for preparing metallic radioactive waste material for storage is disclosed. The radioactive waste material is placed in a radiation shielded enclosure. The waste material is then melted with a plasma torch and cast into a plurality of successive horizontal layers in a mold to form a radioactive ingot in the shape of a spent nuclear fuel rod storage canister. The apparatus comprises a radiation shielded enclosure having an opening adapted for receiving a conventional transfer cask within which radioactive waste material is transferred to the apparatus. A plasma torch is mounted within the enclosure. A mold is also received within the enclosure for receiving the melted waste material and cooling it to form an ingot. The enclosure is preferably constructed in at least two parts to enable easy transport of the apparatus from one nuclear site to another. 8 figs.

  9. Radioactive waste material melter apparatus

    DOE Patents [OSTI]

    Newman, Darrell F. (Richland, WA); Ross, Wayne A. (Richland, WA)

    1990-01-01

    An apparatus for preparing metallic radioactive waste material for storage is disclosed. The radioactive waste material is placed in a radiation shielded enclosure. The waste material is then melted with a plasma torch and cast into a plurality of successive horizontal layers in a mold to form a radioactive ingot in the shape of a spent nuclear fuel rod storage canister. The apparatus comprises a radiation shielded enclosure having an opening adapted for receiving a conventional transfer cask within which radioactive waste material is transferred to the apparatus. A plasma torch is mounted within the enclosure. A mold is also received within the enclosure for receiving the melted waste material and cooling it to form an ingot. The enclosure is preferably constructed in at least two parts to enable easy transport of the apparatus from one nuclear site to another.

  10. High Temperature Thermal Array for Next Generation Solar Thermal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Temperature Thermal Array for Next Generation Solar Thermal Power Production High Temperature Thermal Array for Next Generation Solar Thermal Power Production This...

  11. Technology for treatment of salt residue stored at NPPs

    SciTech Connect (OSTI)

    Kobelev, A.P.; Savkin, A.E.; Sinjakin, O.G.; Kachalova, E.A.; Sorokoletova, A.N.; Nechaev, V.R. [SUE Moscow SIA Radon (Russian Federation)

    2007-07-01

    At Moscow SIA 'Radon', three (3) options for NPP salt residue treatment were developed and tested. Option 1 consists of dissolving the salt residue and subsequent treatment by ozonization, separation of the deposits formed from ozonization and selective cleaning by ferrocyanide sorbents. Option 2 consists of fusion of the salt residue, addition of glass-forming additives and melting of borosilicate glass in a melter such as a 'cold crucible'. Option 3 consists of dissolving the salt residue, oxidation of the solution obtained, removal of radionuclides by collectors and the separate handling of formed deposits and the solution. The deposits containing more than 99 % of the activity are directed to vitrification and the solution is directed either to a concentrates dryer or to cementation. The vitrified waste product is placed in repository for solid radioactive waste storage and the solidified product from the solution goes to an industrial waste disposal site or a repository specially developed at NPP sites for 'exempt waste' products by IAEA classification. (authors)

  12. Effects of thermal fluctuations on thermal inflation

    E-Print Network [OSTI]

    Takashi Hiramatsu; Yuhei Miyamoto; Jun'ichi Yokoyama

    2014-12-25

    The mechanism of thermal inflation, a relatively short period of accelerated expansion after primordial inflation, is a desirable ingredient for a certain class of particle physics models if they are not to be in contention with the cosmology of the early Universe. Though thermal inflation is most simply described in terms of a thermal effective potential, a thermal environment also gives rise to thermal fluctuations that must be taken into account. We numerically study the effects of these thermal fluctuations using lattice simulations. We conclude that though they do not ruin the thermal inflation scenario, the phase transition at the end of thermal inflation proceeds through phase mixing and is therefore not accompanied by the formations of bubbles nor appreciable amplitude of gravitational waves.

  13. Solar Thermal Powered Evaporators

    E-Print Network [OSTI]

    Moe, Christian Robert

    2015-01-01

    storage in solar thermal applications," Applied Energy, pp.of Non-Tracking Solar Thermal Technology," 2011. [26] R.C. Y. Zhao, "A review of solar collectors and thermal energy

  14. Solar Thermal Powered Evaporators

    E-Print Network [OSTI]

    Moe, Christian Robert

    2015-01-01

    Evaporator Powered By Solar Thermal Energy 10:00 AM 10:00 AMaided or powered by solar thermal energy. A section is alsoexhaustive review of solar thermal energy systems has been

  15. Solar Thermal Powered Evaporators

    E-Print Network [OSTI]

    Moe, Christian Robert

    2015-01-01

    and thermal energy storage in solar thermal applications,"Solar infrastructure should include analysis of thermal storage.storage equipment, the evaporator can be integrated into the current solar

  16. US DOE Initiated Performance Enhancements to the Hanford Waste Treatment and Immobilization Plant (WTP) Low-activity Waste Vitrification (LAW) System

    SciTech Connect (OSTI)

    Hamel, William F.; Gerdes, Kurt D.; Holton, Langdon K.; Pegg, Ian L.; Bowen, Brad W.

    2006-03-03

    The U.S Department of Energy Office of River Protection (DOE-ORP) is constructing a Waste Treatment and Immobilization Plant (WTP) for the treatment and vitrification of underground tank wastes stored at the Hanford Site in Washington State. The WTP comprises four major facilities: a pretreatment facility to separate the tank waste into high level waste (HLW) and low-activity waste (LAW) process streams, a HLW vitrification facility to immobilize the HLW fraction; a LAW vitrification facility to immobilize the LAW fraction, and an analytical laboratory to support the operations of all four treatment facilities. DOE has established strategic objectives to optimize the performance of the WTP facilities and the LAW and HLW waste forms to reduce the overall schedule and cost for treatment and vitrification of the Hanford tank wastes. This strategy has been implemented by establishing performance expectations in the WTP contract for the facilities and waste forms. In addition, DOE, as owner-operator of the WTP facilities, continues to evaluate 1) the design, to determine the potential for performance above the requirements specified in the WTP contract; and 2) improvements in production of the LAW and HLW waste forms. This paper reports recent progress directed at improving production of the LAW waste form. DOE’s initial assessment, which is based on the work reported in this paper, is that the capacity of the WTP LAW vitrification facility can be increased by a factor of 2 to 4 with a combination of revised glass formulations, modest increases in melter glass operating temperatures, and a second-generation LAW melter with a larger surface area. Implementing these improvements in the LAW waste immobilization capability can benefit the LAW treatment mission by reducing both processing time and cost.

  17. Thermal Control & System Integration

    Broader source: Energy.gov [DOE]

    The thermal control and system integration activity focuses on issues such as the integration of motor and power control technologies and the development of advanced thermal control technologies....

  18. DNA Engine Thermal Cycler

    E-Print Network [OSTI]

    Raizada, Manish N.

    ® Peltier Thermal Cycler PTC-0200 DNA Engine Cycler Operations Manual Version 4.0 #12;ii Tech Support: 1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .vi The DNA Engine® Peltier Thermal Cycler Introduction

  19. Solar Thermal Powered Evaporators

    E-Print Network [OSTI]

    Moe, Christian Robert

    2015-01-01

    and C. Y. Zhao, "A review of solar collectors and thermalenergy storage in solar thermal applications," Appliedon photovoltaic/thermal hybrid solar technology," Applied

  20. AQUIFER THERMAL ENERGY STORAGE

    E-Print Network [OSTI]

    Tsang, C.-F.

    2011-01-01

    thermal energy becomes apparent with the development of solarsolar energy systems, aquifer energy storage provides a buffer between time-varying solar energy inputs and thermal

  1. Thermal Regimes of Northeast Streams

    E-Print Network [OSTI]

    Thermal Loading (USGS) Stormwater and Streams ­ Optimizing Stormwater Management to Protect the Thermal

  2. Waste Treatment Technology Process Development Plan For Hanford Waste Treatment Plant Low Activity Waste Recycle

    SciTech Connect (OSTI)

    McCabe, Daniel J.; Wilmarth, William R.; Nash, Charles A.

    2013-08-29

    The purpose of this Process Development Plan is to summarize the objectives and plans for the technology development activities for an alternative path for disposition of the recycle stream that will be generated in the Hanford Waste Treatment Plant Low Activity Waste (LAW) vitrification facility (LAW Recycle). This plan covers the first phase of the development activities. The baseline plan for disposition of this stream is to recycle it to the WTP Pretreatment Facility, where it will be concentrated by evaporation and returned to the LAW vitrification facility. Because this stream contains components that are volatile at melter temperatures and are also problematic for the glass waste form, they accumulate in the Recycle stream, exacerbating their impact on the number of LAW glass containers. Approximately 32% of the sodium in Supplemental LAW comes from glass formers used to make the extra glass to dilute the halides to acceptable concentrations in the LAW glass, and reducing the halides in the Recycle is a key component of this work. Additionally, under possible scenarios where the LAW vitrification facility commences operation prior to the WTP Pretreatment facility, this stream does not have a proven disposition path, and resolving this gap becomes vitally important. This task seeks to examine the impact of potential future disposition of this stream in the Hanford tank farms, and to develop a process that will remove radionuclides from this stream and allow its diversion to another disposition path, greatly decreasing the LAW vitrification mission duration and quantity of glass waste. The origin of this LAW Recycle stream will be from the Submerged Bed Scrubber (SBS) and the Wet Electrostatic Precipitator (WESP) from the LAW melter off-gas system. The stream is expected to be a dilute salt solution with near neutral pH, and will likely contain some insoluble solids from melter carryover or precipitates of scrubbed components (e.g. carbonates). The soluble components are mostly sodium and ammonium salts of nitrate, chloride, and fluoride. This stream has not been generated yet, and will not be available until the WTP begins operation, causing uncertainty in its composition, particularly the radionuclide content. This plan will provide an estimate of the likely composition and the basis for it, assess likely treatment technologies, identify potential disposition paths, establish target treatment limits, and recommend the testing needed to show feasibility. Two primary disposition options are proposed for investigation, one is concentration for storage in the tank farms, and the other is treatment prior to disposition in the Effluent Treatment Facility. One of the radionuclides that is volatile and expected to be in high concentration in this LAW Recycle stream is Technetium-99 ({sup 99}Tc), a long-lived radionuclide with a half-life of 210,000 years. Technetium will not be removed from the aqueous waste in the Hanford Waste Treatment and Immobilization Plant (WTP), and will primarily end up immobilized in the LAW glass, which will be disposed in the Integrated Disposal Facility (IDF). Because {sup 99}Tc has a very long half-life and is highly mobile, it is the largest dose contributor to the Performance Assessment (PA) of the IDF. Other radionuclides that are also expected to be in appreciable concentration in the LAW Recycle are {sup 129}I, {sup 90}Sr, {sup 137}Cs, and {sup 241}Am. The concentrations of these radionuclides in this stream will be much lower than in the LAW, but they will still be higher than limits for some of the other disposition pathways currently available. Although the baseline process will recycle this stream to the Pretreatment Facility, if the LAW facility begins operation first, this stream will not have a disposition path internal to WTP. One potential solution is to return the stream to the tank farms where it can be evaporated in the 242-A evaporator, or perhaps deploy an auxiliary evaporator to concentrate it prior to return to the tank farms. In either case, testing is needed to evaluat

  3. HEATS: Thermal Energy Storage

    SciTech Connect (OSTI)

    2012-01-01

    HEATS Project: The 15 projects that make up ARPA-E’s HEATS program, short for “High Energy Advanced Thermal Storage,” seek to develop revolutionary, cost-effective ways to store thermal energy. HEATS focuses on 3 specific areas: 1) developing high-temperature solar thermal energy storage capable of cost-effectively delivering electricity around the clock and thermal energy storage for nuclear power plants capable of cost-effectively meeting peak demand, 2) creating synthetic fuel efficiently from sunlight by converting sunlight into heat, and 3) using thermal energy storage to improve the driving range of electric vehicles (EVs) and also enable thermal management of internal combustion engine vehicles.

  4. Process system evaluation-consolidated letters. Volume 1. Alternatives for the off-gas treatment system for the low-level waste vitrification process

    SciTech Connect (OSTI)

    Peurrung, L.M.; Deforest, T.J; Richards, J.R.

    1996-03-01

    This report provides an evaluation of alternatives for treating off-gas from the low-level waste (LLW) melter. The study used expertise obtained from the commercial nonradioactive off-gas treatment industry. It was assumed that contact maintenance is possible, although the subsequent risk to maintenance personnel was qualitatively considered in selecting equipment. Some adaptations to the alternatives described may be required, depending on the extent of contact maintenance that can be achieved. This evaluation identified key issues for the off-gas system design. To provide background information, technology reviews were assembled for various classifications of off-gas treatment equipment, including off-gas cooling, particulate control, acid gas control, mist elimination, NO{sub x} reduction, and SO{sub 2} removal. An order-of-magnitude cost estimate for one of the off-gas systems considered is provided using both the off-gas characteristics associated with the Joule-heated and combustion-fired melters. The key issues identified and a description of the preferred off-gas system options are provided below. Five candidate treatment systems were evaluated. All of the systems are appropriate for the different melting/feed preparations currently being considered. The lowest technical risk is achieved using option 1, which is similar to designs for high-level waste (HLW) vitrification in the Hanford Waste Vitrification Project (HWVP) and the West Valley. Demonstration Project. Option 1 uses a film cooler, submerged bed scrubber (SBS), and high-efficiency mist eliminator (HEME) prior to NO{sub x} reduction and high-efficiency particulate air (HEPA) filtration. However, several advantages were identified for option 2, which uses high-temperature filtration. Based on the evaluation, option 2 was identified as the preferred alternative. The characteristics of this option are described below.

  5. Exfoliation of Graphite Oxide in Propylene Carbonate and Thermal

    E-Print Network [OSTI]

    as a "green" route to suspensions of RG-O.23 Direct thermal treatment at elevated tem- peratures provides of 5230 S/m. By adding tetraethylammonium tetrafluoroborate (TEA BF4) to the reduced graphene oxide

  6. Thermal and Electrical Transport in Oxide Heterostructures

    E-Print Network [OSTI]

    Ravichandran, Jayakanth

    2011-01-01

    of thermal conductivity . . . . . . . . . . . . . . . .4.4 Thermal transport in2.3.2 Thermal transport . . . . . . . . . . . . . . . .

  7. Thermal Energy Storage

    SciTech Connect (OSTI)

    Rutberg, Michael; Hastbacka, Mildred; Cooperman, Alissa; Bouza, Antonio

    2013-06-05

    The article discusses thermal energy storage technologies. This article addresses benefits of TES at both the building site and the electricity generation source. The energy savings and market potential of thermal energy store are reviewed as well.

  8. Thermal Management of Solar Cells

    E-Print Network [OSTI]

    Saadah, Mohammed Ahmed

    2013-01-01

    phonon transmission and interface thermal conductance acrossF. Miao, et al. , "Superior Thermal Conductivity of Single-Advanced Materials for Thermal Management of Electronic

  9. AQUIFER THERMAL ENERGY STORAGE

    E-Print Network [OSTI]

    Tsang, C.-F.

    2011-01-01

    time-varying solar energy inputs and thermal or powerthermal energy becomes apparent with the development of solar

  10. Multiwavelength Thermal Emission

    E-Print Network [OSTI]

    California at Santa Cruz, University of

    Multiwavelength Astronomy NASA #12;Thermal Emission #12;Thermal Emission Non-thermal p-p collisions Optical IR Radio/ Microwave sources of emission massive stars, WHIM, Ly many dust, cool objects-ray ~GeV Gamma-ray ~TeV sources of emission AGN, clusters, SNR, binaries, stars AGN (obscured), shocks

  11. Thermal neutron detection system

    DOE Patents [OSTI]

    Peurrung, Anthony J. (Richland, WA); Stromswold, David C. (West Richland, WA)

    2000-01-01

    According to the present invention, a system for measuring a thermal neutron emission from a neutron source, has a reflector/moderator proximate the neutron source that reflects and moderates neutrons from the neutron source. The reflector/moderator further directs thermal neutrons toward an unmoderated thermal neutron detector.

  12. Thermal Performance Benchmarking (Presentation)

    SciTech Connect (OSTI)

    Moreno, G.

    2014-11-01

    This project will benchmark the thermal characteristics of automotive power electronics and electric motor thermal management systems. Recent vehicle systems will be benchmarked to establish baseline metrics, evaluate advantages and disadvantages of different thermal management systems, and identify areas of improvement to advance the state-of-the-art.

  13. Enterprise Assessments Operational Awareness Record for the Review of the Waste Treatment and Immobilization Plant High-Level Waste Facility Concentrate Receipt/Melter Feed/Glass Formers Reagent Hazards Analysis Event Tables Â… June 2015

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n cEnergyNatural GasDepartmentApril 13,truck carries<Lessons

  14. Catalytic thermal barrier coatings

    DOE Patents [OSTI]

    Kulkarni, Anand A. (Orlando, FL); Campbell, Christian X. (Orlando, FL); Subramanian, Ramesh (Oviedo, FL)

    2009-06-02

    A catalyst element (30) for high temperature applications such as a gas turbine engine. The catalyst element includes a metal substrate such as a tube (32) having a layer of ceramic thermal barrier coating material (34) disposed on the substrate for thermally insulating the metal substrate from a high temperature fuel/air mixture. The ceramic thermal barrier coating material is formed of a crystal structure populated with base elements but with selected sites of the crystal structure being populated by substitute ions selected to allow the ceramic thermal barrier coating material to catalytically react the fuel-air mixture at a higher rate than would the base compound without the ionic substitutions. Precious metal crystallites may be disposed within the crystal structure to allow the ceramic thermal barrier coating material to catalytically react the fuel-air mixture at a lower light-off temperature than would the ceramic thermal barrier coating material without the precious metal crystallites.

  15. Hanford’s Supplemental Treatment Project: Full-Scale Integrated Testing of In-Container-Vitrification and a 10,000-Liter Dryer

    SciTech Connect (OSTI)

    Witwer, Keith S.; Dysland, Eric J.; Garfield, J. S.; Beck, T. H.; Matyas, Josef; Bagaasen, Larry M.; Cooley, Scott K.; Pierce, Eric M.; Kim, Dong-Sang; Schweiger, Michael J.

    2008-02-22

    The GeoMelt® In-Container Vitrification™ (ICV™) process was selected by the U.S. Department of Energy (DOE) in 2004 for further evaluation as the supplemental treatment technology for Hanford’s low-activity waste (LAW). Also referred to as “bulk vitrification,” this process combines glass forming minerals, LAW, and chemical amendments; dries the mixture; and then vitrifies the material in a refractory-lined steel container. AMEC Nuclear Ltd. (AMEC) is adapting its GeoMelt ICV™ technology for this application with technical and analytical support from Pacific Northwest National Laboratory (PNNL). The DVBS project is funded by the DOE Office of River Protection and administered by CH2M HILL Hanford Group, Inc. The Demonstration Bulk Vitrification Project (DBVS) was initiated to engineer, construct, and operate a full-scale bulk vitrification pilot-plant to treat up to 750,000 liters of LAW from Waste Tank 241-S-109 at the DOE Hanford Site. Since the beginning of the DBVS project in 2004, testing has used laboratory, crucible-scale, and engineering-scale equipment to help establish process limitations of selected glass formulations and identify operational issues. Full-scale testing has provided critical design verification of the ICV™ process before operating the Hanford pilot-plant. In 2007, the project’s fifth full-scale test, called FS-38D, (also known as the Integrated Dryer Melter Test, or IDMT,) was performed. This test had three primary objectives: 1) Demonstrate the simultaneous and integrated operation of the ICV™ melter with a 10,000-liter dryer, 2) Demonstrate the effectiveness of a new feed reformulation and change in process methodology towards reducing the production and migration of molten ionic salts (MIS), and, 3) Demonstrate that an acceptable glass product is produced under these conditions. Testing was performed from August 8 to 17, 2007. Process and analytical results demonstrated that the primary test objectives, along with a dozen supporting objectives, were successfully met. Glass performance exceeded all disposal performance criteria. A previous issue with MIS containment was successfully resolved in FS-38D, and the ICV™ melter was integrated with a full-scale, 10,000-liter dryer. This paper describes the rationale for performing the test, the purpose and outcome of scale-up tests preceding it, and the performance and outcome of FS-38D.

  16. Hanford's Supplemental Treatment Project: Full-Scale Integrated Testing of In-Container-Vitrification and a 10,000-Liter Dryer

    SciTech Connect (OSTI)

    Witwer, K.S.; Dysland, E.J.; Garfield, J.S.; Beck, T.H.; Matyas, J.; Bagaasen, L.M.; Cooley, S.K.; Pierce, E.; Kim, D.S.; Schweiger, M.J.

    2008-07-01

    The GeoMelt{sup R} In-Container Vitrification{sup TM} (ICV{sup TM}) process was selected by the U.S. Department of Energy (DOE) in 2004 for further evaluation as the supplemental treatment technology for Hanford's low-activity waste (LAW). Also referred to as 'bulk vitrification', this process combines glass forming minerals, LAW, and chemical amendments; dries the mixture; and then vitrifies the material in a refractory-lined steel container. AMEC Nuclear Ltd. (AMEC) is adapting its GeoMelt ICV{sup TM} technology for this application with technical and analytical support from Pacific Northwest National Laboratory (PNNL). The DVBS project is funded by the DOE Office of River Protection and administered by CH2M HILL Hanford Group, Inc. The Demonstration Bulk Vitrification Project (DBVS) was initiated to engineer, construct, and operate a full-scale bulk vitrification pilot-plant to treat up to 750,000 liters of LAW from Waste Tank 241-S-109 at the DOE Hanford Site. Since the beginning of the DBVS project in 2004, testing has used laboratory, crucible-scale, and engineering-scale equipment to help establish process limitations of selected glass formulations and identify operational issues. Full-scale testing has provided critical design verification of the ICV{sup TM} process before operating the Hanford pilot-plant. In 2007, the project's fifth full-scale test, called FS-38D, (also known as the Integrated Dryer Melter Test, or IDMT,) was performed. This test had three primary objectives: 1) Demonstrate the simultaneous and integrated operation of the ICV{sup TM} melter with a 10,000- liter dryer, 2) Demonstrate the effectiveness of a new feed reformulation and change in process methodology towards reducing the production and migration of molten ionic salts (MIS), and, 3) Demonstrate that an acceptable glass product is produced under these conditions. Testing was performed from August 8 to 17, 2007. Process and analytical results demonstrated that the primary test objectives, along with a dozen supporting objectives, were successfully met. Glass performance exceeded all disposal performance criteria. A previous issue with MIS containment was successfully resolved in FS-38D, and the ICV{sup TM} melter was integrated with a full-scale, 10,000-liter dryer. This paper describes the rationale for performing the test, the purpose and outcome of scale-up tests preceding it, and the performance and outcome of FS-38D. (authors)

  17. AQUIFER THERMAL ENERGY STORAGE

    E-Print Network [OSTI]

    Tsang, C.-F.

    2011-01-01

    aquifers for thermal energy storage. Problems outlined abovean Aquifer Used for Hot Water Storage: Digital Simulation ofof Aquifer Systems for Cyclic Storage of Water," of the Fall

  18. Scattering Solar Thermal Concentrators

    Office of Environmental Management (EM)

    sunshot DOEGO-102012-3669 * September 2012 MOTIVATION All thermal concentrating solar power (CSP) systems use solar tracking, which involves moving large mirror surfaces...

  19. Solar Thermal Powered Evaporators

    E-Print Network [OSTI]

    Moe, Christian Robert

    2015-01-01

    pp. 67-73, 2003. [17] "Energy Requirements of Desalinationof solar collectors and thermal energy storage in solarapplications," Applied Energy, pp. 538-553, 2013. [20] P. G.

  20. Solar Thermal Powered Evaporators

    E-Print Network [OSTI]

    Moe, Christian Robert

    2015-01-01

    C. Y. Zhao, "A review of solar collectors and thermal energya Passive Flat-Plate Solar Collector," International Journalof Flat Plate Solar Collector Equipped with Rectangular Cell

  1. Fast Thermal Simulation for Architecture Level Dynamic Thermal Management

    E-Print Network [OSTI]

    Tan, Sheldon X.-D.

    Fast Thermal Simulation for Architecture Level Dynamic Thermal Management Pu Liu, Zhenyu Qi, Hang temperature by dynamic thermal managements becomes necessary. This paper proposes a novel approach to the thermal analysis at chip architecture level for efficient dynamic thermal management. Our new approach

  2. Thermal protection apparatus

    DOE Patents [OSTI]

    Bennett, G.A.; Elder, M.G.; Kemme, J.E.

    1984-03-20

    The disclosure is directed to an apparatus for thermally protecting sensitive components in tools used in a geothermal borehole. The apparatus comprises a Dewar within a housing. The Dewar contains heat pipes such as brass heat pipes for thermally conducting heat from heat sensitive components such as electronics to a heat sink such as ice.

  3. Thermal protection apparatus

    DOE Patents [OSTI]

    Bennett, Gloria A. (Los Alamos, NM); Elder, Michael G. (Los Alamos, NM); Kemme, Joseph E. (Albuquerque, NM)

    1985-01-01

    An apparatus which thermally protects sensitive components in tools used in a geothermal borehole. The apparatus comprises a Dewar within a housing. The Dewar contains heat pipes such as brass heat pipes for thermally conducting heat from heat sensitive components to a heat sink such as ice.

  4. Thermal radiation Ron Zevenhoven

    E-Print Network [OSTI]

    Zevenhoven, Ron

    .00032, similarly for 2·T = 0.7·2500 = 1750 µmK4 this gives f0-2 = 0.03392. Thus for 0.4 - 0.7 µm, f1-2 = 0Thermal radiation revisited Ron Zevenhoven Ĺbo Akademi University Thermal and Flow Engineering Laboratory / Värme- och strömningsteknik tel. 3223 ; ron.zevenhoven@abo.fi Process Engineering

  5. Mechanical Engineering & Thermal Group

    E-Print Network [OSTI]

    Mojzsis, Stephen J.

    LASP's mechanical analysts also lead mechanical verification testing including: random vibration, forceMechanical Engineering & Thermal Group The Mechanical Engineering (ME) & Thermal Group at LASP has, and ground- based mechanical systems. Instrument Design Building on decades of design experience that has

  6. Tunable thermal link

    DOE Patents [OSTI]

    Chang, Chih-Wei; Majumdar, Arunava; Zettl, Alexander K.

    2014-07-15

    Disclosed is a device whereby the thermal conductance of a multiwalled nanostructure such as a multiwalled carbon nanotube (MWCNT) can be controllably and reversibly tuned by sliding one or more outer shells with respect to the inner core. As one example, the thermal conductance of an MWCNT dropped to 15% of the original value after extending the length of the MWCNT by 190 nm. The thermal conductivity returned when the tube was contracted. The device may comprise numbers of multiwalled nanotubes or other graphitic layers connected to a heat source and a heat drain and various means for tuning the overall thermal conductance for applications in structure heat management, heat flow in nanoscale or microscale devices and thermal logic devices.

  7. Solar thermal aircraft

    DOE Patents [OSTI]

    Bennett, Charles L. (Livermore, CA)

    2007-09-18

    A solar thermal powered aircraft powered by heat energy from the sun. A heat engine, such as a Stirling engine, is carried by the aircraft body for producing power for a propulsion mechanism, such as a propeller. The heat engine has a thermal battery in thermal contact with it so that heat is supplied from the thermal battery. A solar concentrator, such as reflective parabolic trough, is movably connected to an optically transparent section of the aircraft body for receiving and concentrating solar energy from within the aircraft. Concentrated solar energy is collected by a heat collection and transport conduit, and heat transported to the thermal battery. A solar tracker includes a heliostat for determining optimal alignment with the sun, and a drive motor actuating the solar concentrator into optimal alignment with the sun based on a determination by the heliostat.

  8. Phase Change Materials for Thermal Energy Storage in Concentrated Solar Thermal Power Plants

    E-Print Network [OSTI]

    Hardin, Corey Lee

    2011-01-01

    and Background Solar thermal energy collection is anThermal Energy Storage in Concentrated Solar Thermal PowerThermal Energy Storage in Concentrated Solar Thermal Power

  9. Laboratory Scoping Tests Of Decontamination Of Hanford Waste Treatment Plant Low Activity Waste Off-Gas Condensate Simulant

    SciTech Connect (OSTI)

    Taylor-Pashow, Kathryn M.; Nash, Charles A.; Crawford, Charles L.; McCabe, Daniel J.; Wilmarth, William R.

    2014-01-21

    The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream (LAW Off-Gas Condensate) from the off-gas system. The baseline plan for disposition of this stream is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility again. Alternate disposition of this stream would eliminate recycling of problematic components, and would enable de-coupled operation of the LAW melter and the Pretreatment Facilities. Eliminating this stream from recycling within WTP would also decrease the LAW vitrification mission duration and quantity of glass waste. This LAW Off-Gas Condensate stream contains components that are volatile at melter temperatures and are problematic for the glass waste form. Because this stream recycles within WTP, these components accumulate in the Condensate stream, exacerbating their impact on the number of LAW glass containers that must be produced. Approximately 32% of the sodium in Supplemental LAW comes from glass formers used to make the extra glass to dilute the halides to acceptable concentrations in the LAW glass, and diverting the stream reduces the halides in the recycled Condensate and is a key outcome of this work. Additionally, under possible scenarios where the LAW vitrification facility commences operation prior to the WTP Pretreatment facility, identifying a disposition path becomes vitally important. This task seeks to examine the potential treatment of this stream to remove radionuclides and subsequently disposition the decontaminated stream elsewhere, such as the Effluent Treatment Facility (ETF), for example. The treatment process envisioned is very similar to that used for the Actinide Removal Process (ARP) that has been operating for years at the Savannah River Site (SRS), and focuses on using mature radionuclide removal technologies that are also compatible with longterm tank storage and immobilization methods. For this new application, testing is needed to demonstrate acceptable treatment sorbents and precipitating agents and measure decontamination factors for additional radionuclides in this unique waste stream. The origin of this LAW Off-Gas Condensate stream will be the liquids from the Submerged Bed Scrubber (SBS) and the Wet Electrostatic Precipitator (WESP) from the LAW melter off-gas system. The stream is expected to be a dilute salt solution with near neutral pH, and will likely contain some insoluble solids from melter carryover. The soluble components are expected to be mostly sodium and ammonium salts of nitrate, chloride, and fluoride. This stream has not been generated yet and will not be available until the WTP begins operation, but a simulant has been produced based on models, calculations, and comparison with pilot-scale tests. One of the radionuclides that is volatile and expected to be in high concentration in this LAW Off-Gas Condensate stream is Technetium-99 ({sup 99}Tc). Technetium will not be removed from the aqueous waste in the Hanford WTP, and will primarily end up immobilized in the LAW glass by repeated recycle of the off-gas condensate into the LAW melter. Other radionuclides that are also expected to be in appreciable concentration in the LAW Off-Gas Condensate are {sup 129}I, {sup 90}Sr, {sup 137}Cs, and {sup 241}Am. This report discusses results of preliminary radionuclide decontamination testing of the simulant. Testing examined use of Monosodium Titanate (MST) to remove {sup 90}Sr and actinides, inorganic reducing agents for {sup 99}Tc, and zeolites for {sup 137}Cs. Test results indicate that excellent removal of {sup 99}Tc was achieved using Sn(II)Cl{sub 2} as a reductant, coupled with sorption onto hydroxyapatite, even in the presence of air and at room temperature. This process was very effective at neutral pH, with a Decontamination Factor (DF) >577 in two hours. It was less effective at alkaline pH. Conversely, removal of the cesium was more effective at alka

  10. Thermally-related safety issues associated with thermal batteries.

    SciTech Connect (OSTI)

    Guidotti, Ronald Armand

    2006-06-01

    Thermal batteries can experience thermal runaway under certain usage conditions. This can lead to safety issues for personnel and cause damage to associated test equipment if the battery thermally self destructs. This report discusses a number of thermal and design related issues that can lead to catastrophic destruction of thermal batteries under certain conditions. Contributing factors are identified and mitigating actions are presented to minimize or prevent undesirable thermal runaway.

  11. Thermal Giant Gravitons

    E-Print Network [OSTI]

    Armas, Jay; Obers, Niels A; Orselli, Marta; Pedersen, Andreas Vigand

    2012-01-01

    We study the giant graviton solution as the AdS_5 X S^5 background is heated up to finite temperature. The analysis employs the thermal brane probe technique based on the blackfold approach. We focus mainly on the thermal giant graviton corresponding to a thermal D3-brane probe wrapped on an S^3 moving on the S^5 of the background at finite temperature. We find several interesting new effects, including that the thermal giant graviton has a minimal possible value for the angular momentum and correspondingly also a minimal possible radius of the S^3. We compute the free energy of the thermal giant graviton in the low temperature regime, which potentially could be compared to that of a thermal state on the gauge theory side. Moreover, we analyze the space of solutions and stability of the thermal giant graviton and find that, in parallel with the extremal case, there are two available solutions for a given temperature and angular momentum, one stable and one unstable. In order to write down the equations of mot...

  12. U.S. Department of Energy (DOE) initiated performance enhancements to the Hanford waste treatment and immobilization plant (WTP) high-level waste vitrification (HLW) system

    SciTech Connect (OSTI)

    Bowan, Bradley [Energy Solutions, LLC (United States); Gerdes, Kurt [United States Department of Energy (United States); Pegg, Ian [Vitreous State Laboratory, Catholic University of America, 400 Hannan Hall 620 Michigan Avenue, NE Washington, DC 20064 (United States); Holton, Langdon [Pacific Northwest National Laboratory, PO Box 999, Richland WA 99352 (United States)

    2007-07-01

    Available in abstract form only. Full text of publication follows: The U.S Department of Energy is currently constructing, at the Hanford, Washington Site, a Waste Treatment and Immobilization Plant (WTP) for the treatment and immobilization, by vitrification, of stored underground tank wastes. The WTP is comprised of four major facilities: a Pretreatment facility to separate the tank waste into high level waste (HLW) and low activity waste (LAW); a HLW vitrification facility to immobilize the HLW fraction; a LAW vitrification facility to immobilize the LAW fraction and an analytical Laboratory to support the treatment facilities. DOE has strategic objectives to optimize the performance of the WTP facilities, and waste forms, in order to reduce the overall schedule and cost for the treatment of the Hanford tank wastes. One key part of this strategy is to maximize the loading of inorganic waste components in the final glass product (waste loading). For the Hanford tank wastes, this is challenging because of the compositional diversity of the wastes generated over several decades. This paper presents the results of an initial series of HLW waste loading enhancement tests, using diverse HLW compositions that are projected for treatment at the WTP. Specifically, results of glass formulation development and melter testing with simulated Hanford HLW containing high concentrations of troublesome components such as bismuth, aluminum, aluminum-sodium, and chromium will be presented. (authors)

  13. Thermal hydraulics development for CASL

    SciTech Connect (OSTI)

    Lowrie, Robert B

    2010-12-07

    This talk will describe the technical direction of the Thermal-Hydraulics (T-H) Project within the Consortium for Advanced Simulation of Light Water Reactors (CASL) Department of Energy Innovation Hub. CASL is focused on developing a 'virtual reactor', that will simulate the physical processes that occur within a light-water reactor. These simulations will address several challenge problems, defined by laboratory, university, and industrial partners that make up CASL. CASL's T-H efforts are encompassed in two sub-projects: (1) Computational Fluid Dynamics (CFD), (2) Interface Treatment Methods (ITM). The CFD subproject will develop non-proprietary, scalable, verified and validated macroscale CFD simulation tools. These tools typically require closures for their turbulence and boiling models, which will be provided by the ITM sub-project, via experiments and microscale (such as DNS) simulation results. The near-term milestones and longer term plans of these two sub-projects will be discussed.

  14. Multilayer thermal barrier coating systems

    DOE Patents [OSTI]

    Vance, Steven J. (Orlando, FL); Goedjen, John G. (Oviedo, FL); Sabol, Stephen M. (Orlando, FL); Sloan, Kelly M. (Longwood, FL)

    2000-01-01

    The present invention generally describes multilayer thermal barrier coating systems and methods of making the multilayer thermal barrier coating systems. The thermal barrier coating systems comprise a first ceramic layer, a second ceramic layer, a thermally grown oxide layer, a metallic bond coating layer and a substrate. The thermal barrier coating systems have improved high temperature thermal and chemical stability for use in gas turbine applications.

  15. Thermally Polymerized Rylene Nanoparticles

    E-Print Network [OSTI]

    Andrew, Trisha Lionel

    Rylene dyes functionalized with varying numbers of phenyl trifluorovinyl ether (TFVE) moieties were subjected to a thermal emulsion polymerization to yield shape-persistent, water-soluble chromophore nanoparticles. Perylene ...

  16. Thermal Insulation Systems 

    E-Print Network [OSTI]

    Stanley, T. F.

    1982-01-01

    Thermal insulation systems are receiving a high degree of attention in view of increasing energy cost. Industrial, commercial and residential energy users are all well aware of energy cost increases and great emphasis is being directed to energy...

  17. Contact thermal lithography

    E-Print Network [OSTI]

    Schmidt, Aaron Jerome, 1979-

    2004-01-01

    Contact thermal lithography is a method for fabricating microscale patterns using heat transfer. In contrast to photolithography, where the minimum achievable feature size is proportional to the wavelength of light used ...

  18. Photovoltaic-thermal collectors

    DOE Patents [OSTI]

    Cox, III, Charles H. (Carlisle, MA)

    1984-04-24

    A photovoltaic-thermal solar cell including a semiconductor body having antireflective top and bottom surfaces and coated on each said surface with a patterned electrode covering less than 10% of the surface area. A thermal-absorbing surface is spaced apart from the bottom surface of the semiconductor and a heat-exchange fluid is passed between the bottom surface and the heat-absorbing surface.

  19. Thermal Resonance Fusion

    E-Print Network [OSTI]

    Bao-Guo Dong

    2015-07-07

    We first show a possible mechanism to create a new type of nuclear fusion, thermal resonance fusion, i.e. low energy nuclear fusion with thermal resonance of light nuclei or atoms, such as deuterium or tritium. The fusion of two light nuclei has to overcome the Coulomb barrier between these two nuclei to reach up to the interacting region of nuclear force. We found nuclear fusion could be realized with thermal vibrations of crystal lattice atoms coupling with light atoms at low energy by resonance to overcome this Coulomb barrier. Thermal resonances combining with tunnel effects can greatly enhance the probability of the deuterium fusion to the detectable level. Our low energy nuclear fusion mechanism research - thermal resonance fusion mechanism results demonstrate how these light nuclei or atoms, such as deuterium, can be fused in the crystal of metal, such as Ni or alloy, with synthetic thermal vibrations and resonances at different modes and energies experimentally. The probability of tunnel effect at different resonance energy given by the WKB method is shown that indicates the thermal resonance fusion mode, especially combined with the tunnel effect, is possible and feasible. But the penetrating probability decreases very sharply when the input resonance energy decreases less than 3 keV, so for thermal resonance fusion, the key point is to increase the resonance peak or make the resonance sharp enough to the acceptable energy level by the suitable compound catalysts, and it is better to reach up more than 3 keV to make the penetrating probability larger than 10^{-10}.

  20. Thermal Resonance Fusion

    E-Print Network [OSTI]

    Dong, Bao-Guo

    2015-01-01

    We first show a possible mechanism to create a new type of nuclear fusion, thermal resonance fusion, i.e. low energy nuclear fusion with thermal resonance of light nuclei or atoms, such as deuterium or tritium. The fusion of two light nuclei has to overcome the Coulomb barrier between these two nuclei to reach up to the interacting region of nuclear force. We found nuclear fusion could be realized with thermal vibrations of crystal lattice atoms coupling with light atoms at low energy by resonance to overcome this Coulomb barrier. Thermal resonances combining with tunnel effects can greatly enhance the probability of the deuterium fusion to the detectable level. Our low energy nuclear fusion mechanism research - thermal resonance fusion mechanism results demonstrate how these light nuclei or atoms, such as deuterium, can be fused in the crystal of metal, such as Ni or alloy, with synthetic thermal vibrations and resonances at different modes and energies experimentally. The probability of tunnel effect at dif...

  1. Coral Thermal Tolerance: Tuning Gene Expression to Resist Thermal Stress

    E-Print Network [OSTI]

    Coral Thermal Tolerance: Tuning Gene Expression to Resist Thermal Stress Anthony J. Bellantuono1 thermal tolerance in the scleractinian coral Acropora millepora, corals preconditioned to a sub under which non-preconditioned corals bleached and preconditioned corals (thermal-tolerant) maintained

  2. Thermal Lens Spectroscopy Mladen Franko

    E-Print Network [OSTI]

    Reid, Scott A.

    Thermal Lens Spectroscopy Mladen Franko Laboratory of Environmental Research, University of Nova-beam Instruments 5 3.3 Differential Thermal Lens Instruments 7 3.4 Multiwavelength and Tunable Thermal Lens Spectrometers 8 3.5 Circular Dichroism TLS Instruments 9 3.6 Miniaturization of Thermal Lens Instruments 9 4

  3. Rejuvenation of metallic glasses by non-affine thermal strain

    E-Print Network [OSTI]

    Ketov, S. V.; Sun, Y. H.; Nachum, S.; Lu, Z.; Checchi, A.; Beraldin, A. R.; Bai, H. Y.; Wang, W. H.; Louzguine-Luzgin, D. V.; Carpenter, M. A.; Greer, A. L.

    2015-08-12

    be compared with the property improvements (hardness, wear resistance) obtained by deep cryogenic treatment (DCT) of steels22. DCT, however, works through phase changes (transformation of residual austenite, precipitation of fine carbides) on holding at low... treatment on the thermal decomposition of Fe–C martensite. J. Mater. Sci. 49, 8183–8191 (2014). 23. Ma, B. M. Nuclear Reactor Materials and Applications, Sect. 6.7.2. Thermal-cycling growth, pp. 149?151 (Van Nostrand, New York, 1983). 24. Yuan, C., Wang...

  4. Liquefaction and storage of thermal treatment off-gases

    SciTech Connect (OSTI)

    Stull, D.M. . Rocky Flats Plant); Golden, J.O. )

    1992-09-08

    A fluidized bed catalytic oxidation unit is being developed for use in the destruction of mixed waste at the Rocky Flats Plant. Cyclones, filters, in situ neutralization of acid gases, and a catalytic converter are used to meet emission standards. Because there is concern by the public that these measures may not be adequate, two off-gas capture systems were evaluated. Both systems involve liquefaction of carbon dioxide produced in the oxidation process. The carbon dioxide would be released only after analysis proved that all appropriate emission standards are met.

  5. Building C-400 Thermal Treatment 90% Remedial Design Report and...

    Office of Environmental Management (EM)

    Effect of temperature and pore size on the hydraulic properties and flow of a hydrocarbon oil in the subsurface, Journal of Contaminant Hydrology, 16:55-86, 1994. Davis, E.L., Hot...

  6. Article for thermal energy storage

    DOE Patents [OSTI]

    Salyer, Ival O. (Dayton, OH)

    2000-06-27

    A thermal energy storage composition is provided which is in the form of a gel. The composition includes a phase change material and silica particles, where the phase change material may comprise a linear alkyl hydrocarbon, water/urea, or water. The thermal energy storage composition has a high thermal conductivity, high thermal energy storage, and may be used in a variety of applications such as in thermal shipping containers and gel packs.

  7. Thermal noise driven computing

    E-Print Network [OSTI]

    Laszlo B. Kish

    2006-10-28

    The possibility of a new type of computing, where thermal noise is the information carrier and the clock in a computer, is studied. The information channel capacity and the lower limit of energy requirement/dissipation are studied in a simple digital system with zero threshold voltage, for the case of error probability close to 0.5, when the thermal noise is equal to or greater than the digital signal. In a simple hypothetical realization of a thermal noise driven gate, the lower limit of energy needed to generate the digital signal is 1.1*kT/bit. The arrangement has potentially improved energy efficiency and it is free of leakage current, crosstalk and ground plane electromagnetic interference problems. Disadvantage is the large number of redundancy elements needed for low-error operation.

  8. Thermal trim for luminaire

    DOE Patents [OSTI]

    Bazydola, Sarah; Ghiu, Camil-Daniel; Harrison, Robert; Jeswani, Anil

    2013-11-19

    A luminaire with a thermal pathway to reduce the junction temperature of the luminaire's light source, and methods for so doing, are disclosed. The luminaire includes a can, a light engine, and a trim, that define a substantially continuous thermal pathway from the light engine to a surrounding environment. The can defines a can cavity and includes a can end region. The light engine is within the can cavity and includes a light source and a heat sink, including a heat sink end region, coupled thereto. The trim is at least partially disposed within the can cavity and includes a first trim end region coupled to the heat sink end region and a second trim end region coupled to the can end region. Thermal interface material may be located between: the heat sink and the trim, the trim and the can, and/or the heat sink and the light source.

  9. Thermal insulated glazing unit

    DOE Patents [OSTI]

    Selkowitz, S.E.; Arasteh, D.K.; Hartmann, J.L.

    1988-04-05

    An improved insulated glazing unit is provided which can attain about R5 to about R10 thermal performance at the center of the glass while having dimensions about the same as those of a conventional double glazed insulated glazing unit. An outer glazing and inner glazing are sealed to a spacer to form a gas impermeable space. One or more rigid, non-structural glazings are attached to the inside of the spacer to divide the space between the inner and outer glazings to provide insulating gaps between glazings of from about 0.20 inches to about 0.40 inches. One or more glazing surfaces facing each thermal gap are coated with a low emissivity coating. Finally, the thermal gaps are filled with a low conductance gas such as krypton gas. 2 figs.

  10. Thermal insulated glazing unit

    DOE Patents [OSTI]

    Selkowitz, Stephen E. (Piedmont, CA); Arasteh, Dariush K. (Oakland, CA); Hartmann, John L. (Seattle, WA)

    1991-01-01

    An improved insulated glazing unit is provided which can attain about R5 to about R10 thermal performance at the center of the glass while having dimensions about the same as those of a conventional double glazed insulated glazing unit. An outer glazing and inner glazing are sealed to a spacer to form a gas impermeable space. One or more rigid, non-structural glazings are attached to the inside of the spacer to divide the space between the inner and outer glazings to provide insulating gaps between glazings of from about 0.20 inches to about 0.40 inches. One or more glazing surfaces facing each thermal gap are coated with a low emissivity coating. Finally, the thermal gaps are filled with a low conductance gas such as krypton gas.

  11. Highly directional thermal emitter

    DOE Patents [OSTI]

    Ribaudo, Troy; Shaner, Eric A; Davids, Paul; Peters, David W

    2015-03-24

    A highly directional thermal emitter device comprises a two-dimensional periodic array of heavily doped semiconductor structures on a surface of a substrate. The array provides a highly directional thermal emission at a peak wavelength between 3 and 15 microns when the array is heated. For example, highly doped silicon (HDSi) with a plasma frequency in the mid-wave infrared was used to fabricate nearly perfect absorbing two-dimensional gratings structures that function as highly directional thermal radiators. The absorption and emission characteristics of the HDSi devices possessed a high degree of angular dependence for infrared absorption in the 10-12 micron range, while maintaining high reflectivity of solar radiation (.about.64%) at large incidence angles.

  12. Pressurized heat treatment of glass ceramic

    DOE Patents [OSTI]

    Kramer, D.P.

    1984-04-19

    A method of producing a glass-ceramic having a specified thermal expansion value is disclosed. The method includes the step of pressurizing the parent glass material to a predetermined pressure during heat treatment so that the glass-ceramic produced has a specified thermal expansion value. Preferably, the glass-ceramic material is isostatically pressed. A method for forming a strong glass-ceramic to metal seal is also disclosed in which the glass-ceramic is fabricated to have a thermal expansion value equal to that of the metal. The determination of the thermal expansion value of a parent glass material placed in a high-temperature environment is also used to determine the pressure in the environment.

  13. Thermal ignition combustion system

    DOE Patents [OSTI]

    Kamo, Roy (Columbus, IN); Kakwani, Ramesh M. (Columbus, IN); Valdmanis, Edgars (Columbus, IN); Woods, Melvins E. (Columbus, IN)

    1988-01-01

    The thermal ignition combustion system comprises means for providing walls defining an ignition chamber, the walls being made of a material having a thermal conductivity greater than 20 W/m.degree. C. and a specific heat greater than 480 J/kg.degree. C. with the ignition chamber being in constant communication with the main combustion chamber, means for maintaining the temperature of the walls above a threshold temperature capable of causing ignition of a fuel, and means for conducting fuel to the ignition chamber.

  14. Thermal ignition combustion system

    DOE Patents [OSTI]

    Kamo, R.; Kakwani, R.M.; Valdmanis, E.; Woods, M.E.

    1988-04-19

    The thermal ignition combustion system comprises means for providing walls defining an ignition chamber, the walls being made of a material having a thermal conductivity greater than 20 W/m C and a specific heat greater than 480 J/kg C with the ignition chamber being in constant communication with the main combustion chamber, means for maintaining the temperature of the walls above a threshold temperature capable of causing ignition of a fuel, and means for conducting fuel to the ignition chamber. 8 figs.

  15. Cermet fuel thermal conductivity 

    E-Print Network [OSTI]

    Alvis, John Mark

    1988-01-01

    VITA 36 37 40 40 40 40 44 45 47 48 LIST OF FIGURES Figure Unit cell for derivation of model Page Heat Conduction Solution 22 3 Fission Gas Release Model 26 4A Metal Matrix Thermal Conductivity 4B Ceramic Fuel Thermal Conductivity 5... is based on the simple heat conduction equation. It is assumed that there is a uniform distribution of fuel particles in a regular array. A unit cell consists of a cube of matrix material of side length L, containing a spherical fuel particle of radius, r...

  16. Scattering Solar Thermal Concentrators

    Broader source: Energy.gov [DOE]

    "This fact sheet describes a scattering solar thermal concentrators project awarded under the DOE's 2012 SunShot Concentrating Solar Power R&D award program. The team, led by the Pennsylvania State University, is working to demonstrate a new, scattering-based approach to concentrating sunlight that aims to improve the overall performance and reliability of the collector field. The research team aims to show that scattering solar thermal collectors are capable of achieving optical performance equal to state-of-the-art parabolic trough systems, but with the added benefits of immunity to wind-load tracking error, more efficient land use, and utilization of stationary receivers."

  17. Phase Change Materials for Thermal Energy Storage in Concentrated Solar Thermal Power Plants

    E-Print Network [OSTI]

    Hardin, Corey Lee

    2011-01-01

    and Background Solar thermal energy collection is anCHANGE THERMAL ENERGY STORAGE FOR CONCENTRATING SOLAR POWERfor Thermal Energy Storage in Concentrated Solar Thermal

  18. Phase Change Materials for Thermal Energy Storage in Concentrated Solar Thermal Power Plants

    E-Print Network [OSTI]

    Hardin, Corey Lee

    2011-01-01

    ENERGY STORAGE FOR CONCENTRATING SOLAR POWER PLANTS,”Thermal Energy Storage in Concentrated Solar Thermal PowerThermal Energy Storage in Concentrated Solar Thermal Power

  19. Microsoft Word - M117 Melter.DOC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on77 PAGE OF PAGESpersonal CERTIFIEDPUB-3140September 17,J6763 2.5

  20. Thermal Reactor Safety

    SciTech Connect (OSTI)

    Not Available

    1980-06-01

    Information is presented concerning fire risk and protection; transient thermal-hydraulic analysis and experiments; class 9 accidents and containment; diagnostics and in-service inspection; risk and cost comparison of alternative electric energy sources; fuel behavior and experiments on core cooling in LOCAs; reactor event reporting analysis; equipment qualification; post facts analysis of the TMI-2 accident; and computational methods.

  1. Solar thermal financing guidebook

    SciTech Connect (OSTI)

    Williams, T.A.; Cole, R.J.; Brown, D.R.; Dirks, J.A.; Edelhertz, H.; Holmlund, I.; Malhotra, S.; Smith, S.A.; Sommers, P.; Willke, T.L.

    1983-05-01

    This guidebook contains information on alternative financing methods that could be used to develop solar thermal systems. The financing arrangements discussed include several lease alternatives, joint venture financing, R and D partnerships, industrial revenue bonds, and ordinary sales. In many situations, alternative financing arrangements can significantly enhance the economic attractiveness of solar thermal investments by providing a means to efficiently allocate elements of risk, return on investment, required capital investment, and tax benefits. A net present value approach is an appropriate method that can be used to investigate the economic attractiveness of alternative financing methods. Although other methods are applicable, the net present value approach has advantages of accounting for the time value of money, yielding a single valued solution to the financial analysis, focusing attention on the opportunity cost of capital, and being a commonly understood concept that is relatively simple to apply. A personal computer model for quickly assessing the present value of investments in solar thermal plants with alternative financing methods is presented in this guidebook. General types of financing arrangements that may be desirable for an individual can be chosen based on an assessment of his goals in investing in solar thermal systems and knowledge of the individual's tax situation. Once general financing arrangements have been selected, a screening analysis can quickly determine if the solar investment is worthy of detailed study.

  2. Thermal barrier coating

    DOE Patents [OSTI]

    Bowker, Jeffrey Charles (Gibsonia, PA); Sabol, Stephen M. (Orlando, FL); Goedjen, John G. (Oviedo, FL)

    2001-01-01

    A thermal barrier coating for hot gas path components of a combustion turbine based on a zirconia-scandia system. A layer of zirconium scandate having the hexagonal Zr.sub.3 Sc.sub.4 O.sub.12 structure is formed directly on a superalloy substrate or on a bond coat formed on the substrate.

  3. Process and apparatus for thermal enhancement

    DOE Patents [OSTI]

    Burrill, Jr., Charles E. (Billerica, MA); Smirlock, Martin E. (Brimfield, MA); Krepchin, Ira P. (Newton Upper Falls, MA)

    1984-06-26

    Thermal treatment apparatus for downhole deployment comprising a combustion stage with an elongated hot wall combustion zone for the substantially complete combustion of the fuel-air mixture and an ignition zone immediately upstream from the combustion zone in which a mixture of atomized liquid fuel and air at or below stoichiometric ratio is ignited; together with a water injection stage immediately downstream from the combustion zone through which essentially partuculate free high temperature combustion products flow from the combustion zone and into which water is sprayed. The resulting mixture of steam and combustion products is injected into an oil formation for enhancing the speed and effectiveness of reservoir response due to physical, chemical, and/or thermal stimulation interactions.

  4. Process for thermal hydrocracking of coal

    SciTech Connect (OSTI)

    Yamashita, K.; Kimura, M.

    1983-11-01

    A process for liquefying and gasifying coal by thermal treatment in the presence of hydrogen gas for hydrocracking is disclosed. The process comprises a sequence of the following two steps: (1) coal fines are injected into a heated hydrogen gas stream at a pressure of from 35 to 250 kg/cm G such that they are rapidly heated to a temperature of from 750/sup 0/ to 1100/sup 0/ C. for thermal cracking thereof; and (2) the resulting liquid product is subjected to hydrocracking for a period of from 1.0 to 60 seconds at a temperature that is lower than the temperature used in the first step and which is in the range of from 570/sup 0/ to 850/sup 0/ C.

  5. Thermal denitration and mineralization of waste constituents

    SciTech Connect (OSTI)

    Nenni, J.A.; Boardman, R.D.

    1997-08-01

    In order to produce a quality grout from LLW using hydraulic cements, proper conditioning of the waste is essential for complete cement curing. Several technologies were investigated as options for conditions. Since the LLW is dilute, removal of all, or most, of the water will significantly reduce the final waste volume. Neutralization of the LLW is also desirable since acidic liquids to not allow cement to cure properly. The nitrate compounds are very soluble and easily leached from solid waste forms; therefore, denitration is desirable. Thermal and chemical denitration technologies have the advantages of water removal, neutralization, and denitration. The inclusion of additives during thermal treatment were investigated as a method of forming insoluable waste conditions.

  6. Giant Thermal Rectification from Polyethylene Nanofiber Thermal Diodes

    E-Print Network [OSTI]

    Zhang, Teng

    2015-01-01

    The realization of phononic computing is held hostage by the lack of high performance thermal devices. Here we show through theoretical analysis and molecular dynamics simulations that unprecedented thermal rectification factors (as large as 1.20) can be achieved utilizing the phase dependent thermal conductivity of polyethylene nanofibers. More importantly, such high thermal rectifications only need very small temperature differences (< 20 oC) across the device, which is a significant advantage over other thermal diodes which need temperature biases on the order of the operating temperature. Taking this into consideration, we show that the dimensionless temperature-scaled rectification factors of the polymer nanofiber diodes range from 12 to 25 - much larger than other thermal diodes (< 8). The polymer nanofiber thermal diode consists of a crystalline portion whose thermal conductivity is highly phase-sensitive and a cross-linked portion which has a stable phase. Nanoscale size effect can be utilized t...

  7. Thermal desorption treatability test conducted with VAC*TRAX Unit

    SciTech Connect (OSTI)

    1996-01-01

    In 1992, Congress passed the Federal Facilities Compliance Act, requiring the U.S. Department of Energy (DOE) to treat and dispose of its mixed waste in accordance with Resource Conservation and Recovery Act (RCRA) treatment standards. In response to the need for mixed-waste treatment capacity, where off-site commercial treatment facilities do not exist or cannot be used, the DOE Albuquerque Operations Office (DOE-AL) organized a Treatment Selection Team to match mixed waste with treatment options and develop a strategy for treatment of mixed waste. DOE-AL manages nine sites with mixed-waste inventories. The Treatment Selection Team determined a need to develop mobile treatment units (MTUs) to treat waste at the sites where the wastes are generated. Treatment processes used for mixed wastes must remove the hazardous component (i.e., meet RCRA treatment standards) and contain the radioactive component in a form that will protect the worker, public, and environment. On the basis of the recommendations of the Treatment Selection Team, DOE-AL assigned projects to the sites to bring mixed-waste treatment capacity on-line. The three technologies assigned to the DOE Grand Junction Projects Office (DOE-GJPO) include thermal desorption (TD), evaporative oxidation, and waste water evaporation.

  8. Desalination and Water Treatment www.deswater.com

    E-Print Network [OSTI]

    Desalination and Water Treatment www.deswater.com 1944-3994 / 1944-3986 © 2011 Desalination 1. Introduction Membrane distillation (MD) is a thermally driven desalination process that involves. / Desalination and Water Treatment 32 (2011) 234­241 235 100% rejection of ions, dissolved non-volatile organics

  9. Mechanical Properties, Thermal Stability and Radiation Damage of Ferritic Steels Processed by Thermal Mechanical Treatments 

    E-Print Network [OSTI]

    Song, Miao

    2014-08-04

    for extending the operation life of current reactors and the design of generation IV nuclear reactors and future fusion reactors. Due to their superior radiation tolerance, ferrite steels are currently the primary candidate under examination for generation IV...

  10. Thermal Modeling of Lundell Alternators

    E-Print Network [OSTI]

    Tang, Sai Chun

    Thermal analysis of Lundell alternators used in automobiles is presented. An analytical thermal model for Lundell alternators is proposed, and procedures for acquiring the model parameters are elucidated. Based on the ...

  11. Removal of Pollutants by Atmospheric Non Thermal Plasmas

    E-Print Network [OSTI]

    Khacef, Ahmed; Pouvesle, Jean Michel; Van, Tiep Le

    2008-01-01

    Results on the application of non thermal plasmas in two environmentally important fields: oxidative removal of VOC and NOx in excess of oxygen were presented. The synergetic application of a plasma-catalytic treatment of NOx in excess of oxygen is also described.

  12. Modeling the Thermal Response of Porcine Cartilage to Laser Irradiation

    E-Print Network [OSTI]

    Aguilar, Guillermo

    with experiments. The model simulations will provide insights to the relationship between the laser treatment advantage of using laser radiation to generate thermal energy in tissue is the precise control of the space animal and human studies have demonstrated clinical feasibility [2,3] the fundamental biophysical

  13. Ocean Thermal Extractable Energy Visualization: Final Technical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ocean Thermal Extractable Energy Visualization: Final Technical Report Ocean Thermal Extractable Energy Visualization: Final Technical Report Report about the Ocean Thermal...

  14. Harvesting nanoscale thermal radiation using pyroelectric materials

    E-Print Network [OSTI]

    Fang, Jin; Frederich, Hugo; Pilon, Laurent

    2010-01-01

    the other hand, energy transfer by thermal radiation betweenit was shown that energy transfer by thermal radi- ationpyroelectric energy conversion and nanoscale thermal

  15. AQUIFER THERMAL ENERGY STORAGE-A SURVEY

    E-Print Network [OSTI]

    Tsang, Chin Fu

    2012-01-01

    1978, High temperature underground thermal energy storage,in Proceedings, Thermal Energy Storage in Aquifers Workshop:High temperature underground thermal energy storage, in ATES

  16. Modeling thermal comfort in stratified environments

    E-Print Network [OSTI]

    Zhang, H.; Huizenga, C.; Arens, Edward A; Yu, T.

    2005-01-01

    non-uniform thermal environments", European Journal of7730, 1994, Moderate Thermal Environments – Determination offor assessing complex thermal environments,” Building and

  17. Evolving opportunities for providing thermal comfort

    E-Print Network [OSTI]

    Brager, Gail; Zhang, Hui; Arens, Edward

    2015-01-01

    field measurement of thermal environment and questionnaireand non-uniform thermal environments, PhD Thesis, Center forPerception of transient thermal environments: Pleasure and

  18. Thermal Transport in Graphene Multilayers and Nanoribbons

    E-Print Network [OSTI]

    Subrina, Samia

    2011-01-01

    1 CHAPTER 2 Thermal transport atvalues of graphene’s thermal conductivity and different1 Thermal conductivity : metals and non - metallic

  19. Evolving opportunities for providing thermal comfort

    E-Print Network [OSTI]

    Brager, Gail; Zhang, Hui; Arens, Edward

    2015-01-01

    control in offices for thermal comfort and energy savings.ANSI/ASHRAE 55-2013: Thermal environmental conditions forA global database of thermal comfort field experiments.

  20. Thermal Conductivity of Polycrystalline Semiconductors and Ceramics

    E-Print Network [OSTI]

    Wang, Zhaojie

    2012-01-01

    35, (3-6), Dames, C. ; Chen, G. , Thermal Conductivity ofProperties of Matter: Thermal conductivity: nonmetallicSociety), Dames, C. ; Chen, G. , Thermal Conductivity of

  1. Thermal Conduction in Graphene and Graphene Multilayers

    E-Print Network [OSTI]

    Ghosh, Suchismita

    2009-01-01

    1 1.2 Thermal transport atxv Introduction xii 1.1 Thermal conductivity and65 4.13 Thermal conductivity of graphene as a function of

  2. THERMAL ENERGY STORAGE IN AQUIFERS WORKSHOP

    E-Print Network [OSTI]

    Authors, Various

    2011-01-01

    Energy can be saved and thermal pollution reduced if a totalnatural flow, and thermal pollution caused by simultaneousStored Heat Energy and Thermal Pollution Daily stored heat

  3. AQUIFER THERMAL ENERGY STORAGE-A SURVEY

    E-Print Network [OSTI]

    Tsang, Chin Fu

    2012-01-01

    Reduction of air and thermal pollution are additionalsubsidence or upliftu thermal pollution, water chemistry,or ponds to avoid thermal pollution. Because periods of heat

  4. THERMAL ENERGY STORAGE IN AQUIFERS WORKSHOP

    E-Print Network [OSTI]

    Authors, Various

    2011-01-01

    the possibility of thermal stratification, i.e. the tendencyratio is very large. Thermal stratification A simple model (ef- fects of thermal stratification. This ideal- ized model

  5. Power Electronic Thermal System Performance and Integration ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Motor Thermal Control Thermal Stress and Reliability for Advanced Power Electronics and Electric Machines Integrated Vehicle Thermal Management...

  6. AQUIFER THERMAL ENERGY STORAGE-A SURVEY

    E-Print Network [OSTI]

    Tsang, Chin Fu

    2012-01-01

    the prob- lem of seasonal storage of thermal energy (Matheyto study seasonal storage of thermal energy: winter storagewithin the Seasonal Thermal Energy Storage Program managed

  7. AQUIFER THERMAL ENERGY STORAGE-A SURVEY

    E-Print Network [OSTI]

    Tsang, Chin Fu

    2012-01-01

    High temperature underground thermal energy storage, inProceedings, Thermal Energy Storage in Aquifers Workshop:underground thermal energy storage, in ATES newsletter:

  8. THERMAL ENERGY STORAGE IN AQUIFERS WORKSHOP

    E-Print Network [OSTI]

    Authors, Various

    2011-01-01

    Survey of Thermal Energy Storage in Aquifers Coupled withLow Temperature Thermal Energy Storage Program of Oak Ridgefor Seasonal Thermal Energy Storage: An Overview of the DOE-

  9. THERMAL ENERGY STORAGE IN AQUIFERS WORKSHOP

    E-Print Network [OSTI]

    Authors, Various

    2011-01-01

    Scale Thermal Energy Storage for Cogeneration and Solarsolar captors, thermal effluents, low cost energy duringSeale Thermal Energy Storage for Cogeneration and Solar

  10. Ocean Thermal Energy Conversion Basics

    Broader source: Energy.gov [DOE]

    A process called ocean thermal energy conversion (OTEC) uses the heat energy stored in the Earth's oceans to generate electricity.

  11. Liquid metal thermal electric converter

    DOE Patents [OSTI]

    Abbin, Joseph P. (Albuquerque, NM); Andraka, Charles E. (Albuquerque, NM); Lukens, Laurance L. (Albuquerque, NM); Moreno, James B. (Albuquerque, NM)

    1989-01-01

    A liquid metal thermal electric converter which converts heat energy to electrical energy. The design of the liquid metal thermal electric converter incorporates a unique configuration which directs the metal fluid pressure to the outside of the tube which results in the structural loads in the tube to be compressive. A liquid metal thermal electric converter refluxing boiler with series connection of tubes and a multiple cell liquid metal thermal electric converter are also provided.

  12. ,{ MO. REV. NO. THERMAL DESIGN

    E-Print Network [OSTI]

    Rathbun, Julie A.

    ,{ MO. REV. NO. LRRR 300 THERMAL DESIGN FINAL REPORT ATM-931 PAGE i OF iv DATE 1 S Dec 1970 The results of thermal design/analyses performed on the 300 corner Laser Ranging Retro-Reflector (LRRR 300 performance profiles are contained herein, The entire LRRR thermal design effort is des- cribed commendng

  13. Thermal synthesis apparatus

    DOE Patents [OSTI]

    Fincke, James R. (Idaho Falls, ID) [Idaho Falls, ID; Detering, Brent A. (Idaho Falls, ID) [Idaho Falls, ID

    2009-08-18

    An apparatus for thermal conversion of one or more reactants to desired end products includes an insulated reactor chamber having a high temperature heater such as a plasma torch at its inlet end and, optionally, a restrictive convergent-divergent nozzle at its outlet end. In a thermal conversion method, reactants are injected upstream from the reactor chamber and thoroughly mixed with the plasma stream before entering the reactor chamber. The reactor chamber has a reaction zone that is maintained at a substantially uniform temperature. The resulting heated gaseous stream is then rapidly cooled by passage through the nozzle, which "freezes" the desired end product(s) in the heated equilibrium reaction stage, or is discharged through an outlet pipe without the convergent-divergent nozzle. The desired end products are then separated from the gaseous stream.

  14. Thermally stable diamond brazing

    DOE Patents [OSTI]

    Radtke, Robert P. (Kingwood, TX)

    2009-02-10

    A cutting element and a method for forming a cutting element is described and shown. The cutting element includes a substrate, a TSP diamond layer, a metal interlayer between the substrate and the diamond layer, and a braze joint securing the diamond layer to the substrate. The thickness of the metal interlayer is determined according to a formula. The formula takes into account the thickness and modulus of elasticity of the metal interlayer and the thickness of the TSP diamond. This prevents the use of a too thin or too thick metal interlayer. A metal interlayer that is too thin is not capable of absorbing enough energy to prevent the TSP diamond from fracturing. A metal interlayer that is too thick may allow the TSP diamond to fracture by reason of bending stress. A coating may be provided between the TSP diamond layer and the metal interlayer. This coating serves as a thermal barrier and to control residual thermal stress.

  15. Thermal reactor safety

    SciTech Connect (OSTI)

    Not Available

    1980-06-01

    Information is presented concerning new trends in licensing; seismic considerations and system structural behavior; TMI-2 risk assessment and thermal hydraulics; statistical assessment of potential accidents and verification of computational methods; issues with respect to improved safety; human factors in nuclear power plant operation; diagnostics and activities in support of recovery; LOCA transient analysis; unresolved safety issues and other safety considerations; and fission product transport.

  16. Thermally actuated thermionic switch

    DOE Patents [OSTI]

    Barrus, D.M.; Shires, C.D.

    1982-09-30

    A thermally actuated thermionic switch which responds to an increase of temperature by changing from a high impedance to a low impedance at a predictable temperature set point. The switch has a bistable operation mode switching only on temperature increases. The thermionic material may be a metal which is liquid at the desired operation temperature and held in matrix in a graphite block reservoir, and which changes state (ionizes, for example) so as to be electrically conductive at a desired temperature.

  17. Methods of forming thermal management systems and thermal management methods

    DOE Patents [OSTI]

    Gering, Kevin L.; Haefner, Daryl R.

    2012-06-05

    A thermal management system for a vehicle includes a heat exchanger having a thermal energy storage material provided therein, a first coolant loop thermally coupled to an electrochemical storage device located within the first coolant loop and to the heat exchanger, and a second coolant loop thermally coupled to the heat exchanger. The first and second coolant loops are configured to carry distinct thermal energy transfer media. The thermal management system also includes an interface configured to facilitate transfer of heat generated by an internal combustion engine to the heat exchanger via the second coolant loop in order to selectively deliver the heat to the electrochemical storage device. Thermal management methods are also provided.

  18. Multiscale thermal transport.

    SciTech Connect (OSTI)

    Graham, Samuel Jr. (; .); Wong, C. C.; Piekos, Edward Stanley

    2004-02-01

    A concurrent computational and experimental investigation of thermal transport is performed with the goal of improving understanding of, and predictive capability for, thermal transport in microdevices. The computational component involves Monte Carlo simulation of phonon transport. In these simulations, all acoustic modes are included and their properties are drawn from a realistic dispersion relation. Phonon-phonon and phonon-boundary scattering events are treated independently. A new set of phonon-phonon scattering coefficients are proposed that reflect the elimination of assumptions present in earlier analytical work from the simulation. The experimental component involves steady-state measurement of thermal conductivity on silicon films as thin as 340nm at a range of temperatures. Agreement between the experiment and simulation on single-crystal silicon thin films is excellent, Agreement for polycrystalline films is promising, but significant work remains to be done before predictions can be made confidently. Knowledge gained from these efforts was used to construct improved semiclassical models with the goal of representing microscale effects in existing macroscale codes in a computationally efficient manner.

  19. Thermal control structure and garment

    DOE Patents [OSTI]

    Klett, James W. (Knoxville, TN); Cameron, Christopher Stan (Sanford, NC)

    2012-03-13

    A flexible thermally conductive structure. The structure generally includes a plurality of thermally conductive yarns, at least some of which are at least partially disposed adjacent to an elastomeric material. Typically, at least a portion of the plurality of thermally conductive yarns is configured as a sheet. The yarns may be constructed from graphite, metal, or similar materials. The elastomeric material may be formed from urethane or silicone foam that is at least partially collapsed, or from a similar material. A thermal management garment is provided, the garment incorporating a flexible thermally conductive structure.

  20. Thermal management systems and methods

    DOE Patents [OSTI]

    Gering, Kevin L.; Haefner, Daryl R.

    2006-12-12

    A thermal management system for a vehicle includes a heat exchanger having a thermal energy storage material provided therein, a first coolant loop thermally coupled to an electrochemical storage device located within the first coolant loop and to the heat exchanger, and a second coolant loop thermally coupled to the heat exchanger. The first and second coolant loops are configured to carry distinct thermal energy transfer media. The thermal management system also includes an interface configured to facilitate transfer of heat generated by an internal combustion engine to the heat exchanger via the second coolant loop in order to selectively deliver the heat to the electrochemical storage device. Thermal management methods are also provided.

  1. INITIAL SELECTION OF SUPPLEMENTAL TREATMENT TECHNOLOGIES FOR HANFORDS LOW ACTIVITY TANK WASTE

    SciTech Connect (OSTI)

    RAYMOND, R.E.

    2004-02-20

    In 2002, the U.S. Department of Energy (DOE) documented a plan for accelerating cleanup of the Hanford Site, located in southeastern Washington State, by at least 35 years. A key element of the plan was acceleration of the tank waste program and completion of ''tank waste treatment by 2028 by increasing the capacity of the planned Waste Treatment Plant (WTP) and using supplemental technologies for waste treatment and immobilization.'' The plan identified specific technologies to be evaluated for supplemental treatment of as much as 70% of the low-activity waste (LAW). In concert with this acceleration plan, DOE, the U.S. Environmental Protection Agency, and the Washington State Department of Ecology proposed to accelerate--from 2014 to 2006--the Hanford Federal Facility Agreement and Consent Order milestone (M-62-11) associated with a final decision on the balance of tank waste that is beyond the capacity of the WTP. The DOE Office of River Protection tank farm contractor, CH2M HILL Hanford Group, Inc. (CH2M HILL), was tasked with testing and evaluating selected supplemental technologies to support final decisions on tank waste treatment. Three technologies and corresponding vendors were selected to support an initial technology selection in 2003. The three technologies were containerized grout called cast stone (Fluor Federal Services); bulk vitrification (AMEC Earth and Environmental, Inc.); and steam reforming (THOR Treatment Technologies, LLC.). The cast stone process applies an effective grout waste formulation to the LAW and places the cement-based product in a large container for solidification and disposal. Unlike the WTP LAW treatment, which applies vitrification within continuous-fed joule-heated ceramic melters, bulk vitrification produces a glass waste form using batch melting within the disposal container. Steam reforming produces a granular denitrified mineral waste form using a high-temperature fluidized bed process. An initial supplemental technology selection was completed in December 2003, enabling DOE and CH2M HILL to focus investments in 2004 on the testing and production-scale demonstrations needed to support the 2006 milestone.

  2. Thermal and non-thermal energies in solar flares

    E-Print Network [OSTI]

    Pascal Saint-Hilaire; Arnold O. Benz

    2005-03-03

    The energy of the thermal flare plasma and the kinetic energy of the non-thermal electrons in 14 hard X-ray peaks from 9 medium-sized solar flares have been determined from RHESSI observations. The emissions have been carefully separated in the spectrum. The turnover or cutoff in the low-energy distribution of electrons has been studied by simulation and fitting, yielding a reliable lower limit to the non-thermal energy. It remains the largest contribution to the error budget. Other effects, such as albedo, non-uniform target ionization, hot target, and cross-sections on the spectrum have been studied. The errors of the thermal energy are about equally as large. They are due to the estimate of the flare volume, the assumption of the filling factor, and energy losses. Within a flare, the non-thermal/thermal ratio increases with accumulation time, as expected from loss of thermal energy due to radiative cooling or heat conduction. Our analysis suggests that the thermal and non-thermal energies are of the same magnitude. This surprising result may be interpreted by an efficient conversion of non-thermal energy to hot flare plasma.

  3. Characterization of a new acne vulgaris treatment device combining light and thermal treatment methods

    E-Print Network [OSTI]

    Chen, Zhongping

    on the tip and 39.7 1C in the porcine skin samples. The peak intensity of the light-emitting diode (LED

  4. MULTISPECTRAL THERMAL IMAGER - OVERVIEW

    SciTech Connect (OSTI)

    P. WEBER

    2001-03-01

    The Multispectral Thermal Imager satellite fills a new and important role in advancing the state of the art in remote sensing sciences. Initial results with the full calibration system operating indicate that the system was already close to achieving the very ambitious goals which we laid out in 1993, and we are confident of reaching all of these goals as we continue our research and improve our analyses. In addition to the DOE interests, the satellite is tasked about one-third of the time with requests from other users supporting research ranging from volcanology to atmospheric sciences.

  5. Response microcantilever thermal detector

    DOE Patents [OSTI]

    Cunningham, Joseph P.; Rajic, Slobodan; Datskos, Panagiotis G.; Evans III, Boyd M.

    2004-10-19

    A "folded leg" thermal detector microcantilever constructed of a substrate with at least one leg interposed between a fixed end and a deflective end, each leg having at least three essentially parallel leg segments interconnected on alternate opposing ends and aligned in a serpentine pattern with only the first leg segment attached to the fixed end and only the last leg segment attached to the deflective end. Alternate leg segment are coated on the pentalever with coating applied to the top of the first, third, and fifth leg segments of each leg and to the bottom of the second and fourth leg segments of each leg.

  6. Thermally cleavable surfactants

    DOE Patents [OSTI]

    McElhanon, James R. (Manteca, CA); Simmons, Blake A. (San Francisco, CA); Zifer, Thomas (Manteca, CA); Jamison, Gregory M. (Albuquerque, NM); Loy, Douglas A. (Albuquerque, NM); Rahimian, Kamyar (Albuquerque, NM); Long, Timothy M. (Urbana, IL); Wheeler, David R. (Albuquerque, NM); Staiger, Chad L. (Albuquerque, NM)

    2009-11-24

    Two new surfactant molecules are reported which contain thermally labile Diels-Alder adducts connecting the polar and non-polar sections of each molecule. The two surfactants possess identical non-polar dodecyl tail segments but exhibit different polar headgroups. The surfactants become soluble in water when anionic salts are formed through the deprotonation of the surfactant headgroups by the addition of potassium hydroxide. When either surfactant is exposed to temperature above about 60.degree. C., the retro Diels-Alder reaction occurs, yielding hydrophilic and hydrophobic fragments or the aqueous solutions of the surfactants subsequently exhibit loss of all surface-active behavior.

  7. Thermally cleavable surfactants

    DOE Patents [OSTI]

    McElhanon, James R. (Manteca, CA); Simmons, Blake A. (San Francisco, CA); Zifer, Thomas (Manteca, CA); Jamison, Gregory M. (Albuquerque, NM); Loy, Douglas A. (Albuquerque, NM); Rahimian, Kamyar (Albuquerque, NM); Long, Timothy M. (Urbana, IL); Wheeler, David R. (Albuquerque, NM); Staiger, Chad L. (Albuquerque, NM)

    2009-09-29

    Two new surfactant molecules are reported which contain thermally labile Diels-Alder adducts connecting the polar and non-polar sections of each molecule. The two surfactants possess identical non-polar dodecyl tail segments but exhibit different polar headgroups. The surfactants become soluble in water when anionic salts are formed through the deprotonation of the surfactant headgroups by the addition of potassium hydroxide. When either surfactant is exposed to temperature above about 60.degree. C., the retro Diels-Alder reaction occurs, yielding hydrophilic and hydrophobic fragments or the aqueous solutions of the surfactants subsequently exhibit loss of all surface-active behavior.

  8. Thermally cleavable surfactants

    DOE Patents [OSTI]

    McElhanon, James R. (Manteca, CA); Simmons, Blake A. (San Francisco, CA); Zifer, Thomas (Manteca, CA); Jamison, Gregory M. (Albuquerque, NM); Loy, Douglas A. (Albuquerque, NM); Rahimian, Kamyar (Albuquerque, NM); Long, Timothy M. (Urbana, IL); Wheeler, David R. (Albuquerque, NM); Staiger, Chad L. (Albuquerque, NM)

    2006-04-04

    Two new surfactant molecules are reported which contain thermally labile Diels-Alder adducts connecting the polar and non-polar sections of each molecule. The two surfactants possess identical non-polar dodecyl tail segments but exhibit different polar headgroups. The surfactants become soluble in water when anionic salts are formed through the deprotonation of the surfactant headgroups by the addition of potassium hydroxide. When either surfactant is exposed to temperature above about 60.degree. C., the retro Diels-Alder reaction occurs, yielding hydrophilic and hydrophobic fragments and the aqueous solutions of the surfactants subsequently exhibit loss of all surface-active behavior.

  9. Thermal network reduction

    SciTech Connect (OSTI)

    Balcomb, J.D.

    1983-01-01

    A method is presented for reducing the number of elements required in a thermal network representation of a building. The method is based on matching the actual building response at two frequencies, the diurnal response and 3-day response. The procedure provides a straightforward methodology for combining all the various materials inside a discrete building zone into a few nodes while retaining a high degree of accuracy in the dynamic response. An example is given showing a comparison between a large network and the reduced network.

  10. Thermal network reduction

    SciTech Connect (OSTI)

    Balcomb, J.D.

    1983-06-01

    A method is presented for reducing the number of elements required in a thermal network representation of a building. The method is based on matching the actual building response at two frequencies, the diurnal response and 3-day response. The procedure provides a straightforward methodology for combining all the various materials inside a discrete building zone into a few nodes while retaining a high degree of accuracy in the dynamic response. An example is given showing a comparison between a large network and the reduced network.

  11. Thermal indicator for wells

    DOE Patents [OSTI]

    Gaven, Jr., Joseph V. (Oakton, VA); Bak, Chan S. (Newbury Park, CA)

    1983-01-01

    Minute durable plate-like thermal indicators are employed for precision measuring static and dynamic temperatures of well drilling fluids. The indicators are small enough and sufficiently durable to be circulated in the well with drilling fluids during the drilling operation. The indicators include a heat resistant indicating layer, a coacting meltable solid component and a retainer body which serves to unitize each indicator and which may carry permanent indicator identifying indicia. The indicators are recovered from the drilling fluid at ground level by known techniques.

  12. Solid state thermal engine

    SciTech Connect (OSTI)

    Wayman, C.M.

    1981-01-27

    An improved solid state thermal engine utilizes as a drive member a braided belt fabricated from a memory alloy such as nickel-titanium and nickel-titanium ternary alloys, copper-zinc and copper-zinc ternary alloys, and the like. The braided belt is mounted on a set of pulleys to provide passage through a hot zone where the belt contracts and develops tension, and through a cold zone where it relaxes and stretches. Since more energy is delivered by contraction than is required for relaxation, positive work output results with an efficiency of between onefifth and one-third of the carnot cycle.

  13. Thermally switchable dielectrics

    DOE Patents [OSTI]

    Dirk, Shawn M.; Johnson, Ross S.

    2013-04-30

    Precursor polymers to conjugated polymers, such as poly(phenylene vinylene), poly(poly(thiophene vinylene), poly(aniline vinylene), and poly(pyrrole vinylene), can be used as thermally switchable capacitor dielectrics that fail at a specific temperature due to the non-conjugated precursor polymer irreversibly switching from an insulator to the conjugated polymer, which serves as a bleed resistor. The precursor polymer is a good dielectric until it reaches a specific temperature determined by the stability of the leaving groups. Conjugation of the polymer backbone at high temperature effectively disables the capacitor, providing a `built-in` safety mechanism for electronic devices.

  14. Thermally Oxidized Silicon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With U.S.Week DayDr. JeffreyThermal Multi-layer4 Anneli Munkholm

  15. Electric Vehicle Battery Thermal Issues and Thermal Management Techniques (Presentation)

    SciTech Connect (OSTI)

    Rugh, J. P.; Pesaran, A.; Smith, K.

    2013-07-01

    This presentation examines the issues concerning thermal management in electric drive vehicles and management techniques for improving the life of a Li-ion battery in an EDV.

  16. Solar thermal power system

    DOE Patents [OSTI]

    Bennett, Charles L.

    2010-06-15

    A solar thermal power generator includes an inclined elongated boiler tube positioned in the focus of a solar concentrator for generating steam from water. The boiler tube is connected at one end to receive water from a pressure vessel as well as connected at an opposite end to return steam back to the vessel in a fluidic circuit arrangement that stores energy in the form of heated water in the pressure vessel. An expander, condenser, and reservoir are also connected in series to respectively produce work using the steam passed either directly (above a water line in the vessel) or indirectly (below a water line in the vessel) through the pressure vessel, condense the expanded steam, and collect the condensed water. The reservoir also supplies the collected water back to the pressure vessel at the end of a diurnal cycle when the vessel is sufficiently depressurized, so that the system is reset to repeat the cycle the following day. The circuital arrangement of the boiler tube and the pressure vessel operates to dampen flow instabilities in the boiler tube, damp out the effects of solar transients, and provide thermal energy storage which enables time shifting of power generation to better align with the higher demand for energy during peak energy usage periods.

  17. Handling effluent from nuclear thermal propulsion system ground tests

    SciTech Connect (OSTI)

    Shipers, L.R.; Allen, G.C.

    1992-09-09

    A variety of approaches for handling effluent from nuclear thermal propulsion system ground tests in an environmentally acceptable manner are discussed. The functional requirements of effluent treatment are defined and concept options are presented within the framework of these requirements. System concepts differ primarily in the choice of fission-product retention and waste handling concepts. The concept options considered range from closed cycle (venting the exhaust to a closed volume or recirculating the hydrogen in a closed loop) to open cycle (real time processing and venting of the effluent). This paper reviews the different methods to handle effluent from nuclear thermal propulsion system ground tests.

  18. Thermal Flipping of Interstellar Grains

    E-Print Network [OSTI]

    Joseph C. Weingartner

    2008-08-27

    In interstellar dust grains, internal processes dissipate rotational kinetic energy. The dissipation is accompanied by thermal fluctuations, which transfer energy from the vibrational modes to rotation. Together, these processes are known as internal relaxation. For the past several years, internal relaxation has been thought to give rise to thermal flipping, with profound consequences for grain alignment theory. I show that thermal flipping is not possible in the limit that the inertia tensor does not vary with time.

  19. Thermal desorption for passive dosimeter 

    E-Print Network [OSTI]

    Liu, Wen-Chen

    1981-01-01

    recovery of styrene and improved precision when compared with thermal desorption. In addition, thermal desorption tended to breakdown sty- rene, which is vulnerable to heat. The breakdown product may interfere with the analysis results if thermal desorp... of the activation processes. (12, 1&) The first step in the production of activated carbon is carbonization, which is the formation of a char from a source material. The source materials may be coconut shells, peach pits, sawdust, wood char, etc ~ Carbonization...

  20. Waste Treatment Plant Overview

    Office of Environmental Management (EM)

    contracted Bechtel National, Inc., to design and build the world's largest radioactive waste treatment plant. The Waste Treatment and Immobilization Plant (WTP), also known as the...

  1. Thermal Management of Solar Cells

    E-Print Network [OSTI]

    Saadah, Mohammed Ahmed

    2013-01-01

    cell. The solar cell’s power conversion efficiency, ? is theEfficiency ..5 Thermal Managements of SolarTemperature on Efficiency Photons incident on a solar cell

  2. Actively driven thermal radiation shield

    DOE Patents [OSTI]

    Madden, Norman W. (Livermore, CA); Cork, Christopher P. (Pleasant Hill, CA); Becker, John A. (Alameda, CA); Knapp, David A. (Livermore, CA)

    2002-01-01

    A thermal radiation shield for cooled portable gamma-ray spectrometers. The thermal radiation shield is located intermediate the vacuum enclosure and detector enclosure, is actively driven, and is useful in reducing the heat load to mechanical cooler and additionally extends the lifetime of the mechanical cooler. The thermal shield is electrically-powered and is particularly useful for portable solid-state gamma-ray detectors or spectrometers that dramatically reduces the cooling power requirements. For example, the operating shield at 260K (40K below room temperature) will decrease the thermal radiation load to the detector by 50%, which makes possible portable battery operation for a mechanically cooled Ge spectrometer.

  3. Overview of solar thermal technologies

    SciTech Connect (OSTI)

    None, None

    2009-01-18

    The solar-thermal overview section of the Renewable Energy Technology Characterizations describes the technical and economic status of this emerging renewable energy option for electricity supply.

  4. Underfloor air distribution: thermal stratification

    E-Print Network [OSTI]

    Webster, T.; Bauman, Fred; Reese, J.

    2002-01-01

    Air Distribution: Thermal Stratification By Tom Webster, Pthermal bypassing of convective loads that occurs above the stratificationthermal plumes that develop over heat sources in the room. A stratification

  5. Guide to Setting Thermal Comfort Criteria and Minimizing Energy Use in Delivering Thermal Comfort

    E-Print Network [OSTI]

    Regnier, Cindy

    2014-01-01

    including cost, energy and thermal comfort analysis, whichfor greatest energy benefits, prioritize thermal comfortMinimizing Energy Use in Delivering Thermal Comfort Cindy

  6. Human thermal sensation and comfort in transient and non-uniform thermal environments

    E-Print Network [OSTI]

    Zhang, H.

    2003-01-01

    the Human and the Thermal Environment." ASHRAE TransactionA field Study of Thermal Environment and Comfort in OfficeISO 7730 - Moderate Thermal Environments - Determination of

  7. Thermal sensation and comfort in transient non-uniform thermal environments

    E-Print Network [OSTI]

    Zhang, Hui; Huizenga, Charlie; Arens, Edward; Wang, Danni

    2004-01-01

    for assessing complex thermal environments. Building andand non-uniform thermal environment. ” Ph.D. thesis,Non-Uniform Thermal Environments Hui Zhang, Charlie

  8. Evaluating thermal environments by using a thermal manikin with controlled skin surface temperature

    E-Print Network [OSTI]

    Tanabe, S.; Arens, Edward A; Bauman, Fred; Zhang, H.; Madsen, T.

    1994-01-01

    betweenhumans their thermal and environment. WinslowandErgonomics of the thermal environment--Estimation of theSymposium on Man-Thermal Environment System, Tokyo. Olesen,

  9. Thermal Properties of Graphene and Applications for Thermal Management of High-Power Density Electronics

    E-Print Network [OSTI]

    Yan, Zhong

    2013-01-01

    Raman Spectroscopy and Thermal Properties of Graphenegraphite heat spreaders for thermal management of high-powerthe Raman spectroscopy and thermal properties of a novel

  10. Phase Change Materials for Thermal Energy Storage in Concentrated Solar Thermal Power Plants

    E-Print Network [OSTI]

    Hardin, Corey Lee

    2011-01-01

    well a molten salt thermal storage system could be utilizedof Solar Two [2] Thermal storage in these plants is anper kilowatt goes towards thermal storage[3]. Considering a

  11. Phase Change Materials for Thermal Energy Storage in Concentrated Solar Thermal Power Plants

    E-Print Network [OSTI]

    Hardin, Corey Lee

    2011-01-01

    Storage in Concentrated Solar Thermal Power Plants A ThesisStorage in Concentrated Solar Thermal Power Plants by Coreysystems for concentrated solar thermal power (CSP) systems.

  12. Thermally stabilized heliostat

    DOE Patents [OSTI]

    Anderson, Alfred J. (Littleton, CO)

    1983-01-01

    An improvement in a heliostat having a main support structure and pivoting and tilting motors and gears and a mirror module for reflecting solar energy onto a collector, the improvement being characterized by an internal support structure within each mirror module and front and back sheets attached to the internal support structure, the front and back sheets having the same coefficient of thermal expansion such that no curvature is induced by temperature change, and a layer of adhesive adhering the mirror to the front sheet. The adhesive is water repellent and has adequate set strength to support the mirror but has sufficient shear tolerance to permit the differential expansion of the mirror and the front sheet without inducing stresses or currature effect. The adhesive also serves to dampen fluttering of the mirror and to protect the mirror backside against the adverse effects of weather. Also disclosed are specific details of the preferred embodiment.

  13. Thermal barrier coatings

    DOE Patents [OSTI]

    Alvin, Mary Anne (Pittsburg, PA)

    2010-06-22

    This disclosure addresses the issue of providing a metallic-ceramic overlay coating that potentially serves as an interface or bond coat layer to provide enhanced oxidation resistance to the underlying superalloy substrate via the formation of a diffusion barrier regime within the supporting base material. Furthermore, the metallic-ceramic coating is expected to limit the growth of a continuous thermally grown oxide (TGO) layer that has been primarily considered to be the principal cause for failure of existing TBC systems. Compositional compatibility of the metallic-ceramic with traditional yttria-stabilized zirconia (YSZ) top coats is provided to further limit debond or spallation of the coating during operational use. A metallic-ceramic architecture is disclosed wherein enhanced oxidation resistance is imparted to the surface of nickel-based superalloy or single crystal metal substrate, with simultaneous integration of the yttria stabilized zirconia (YSZ) within the metallic-ceramic overlayer.

  14. On the thermal expansion of composite materials and cross-property connection between thermal expansion and thermal conductivity

    E-Print Network [OSTI]

    Sevostianov, Igor

    On the thermal expansion of composite materials and cross-property connection between thermal expansion and thermal conductivity Igor Sevostianov Department of Mechanical and Aerospace Engineering, New: Composite material Thermal expansion Cross-property Microstructure Thermal conductivity a b s t r a c

  15. Final Report - Crystal Settling, Redox, and High Temperature Properties of ORP HLW and LAW Glasses, VSL-09R1510-1, Rev. 0, dated 6/18/09

    SciTech Connect (OSTI)

    Kruger, Albert A.; Wang, C.; Gan, H.; Pegg, I. L.; Chaudhuri, M.; Kot, W.; Feng, Z.; Viragh, C.; McKeown, D. A.; Joseph, I.; Muller, I. S.; Cecil, R.; Zhao, W.

    2013-11-13

    The radioactive tank waste treatment programs at the U. S. Department of Energy (DOE) have featured joule heated ceramic melter technology for the vitrification of high level waste (HLW). The Hanford Tank Waste Treatment and Immobilization Plant (WTP) employs this same basic technology not only for the vitrification of HLW streams but also for the vitrification of Low Activity Waste (LAW) streams. Because of the much greater throughput rates required of the WTP as compared to the vitrification facilities at the West Valley Demonstration Project (WVDP) or the Defense Waste Processing Facility (DWPF), the WTP employs advanced joule heated melters with forced mixing of the glass pool (bubblers) to improve heat and mass transport and increase melting rates. However, for both HLW and LAW treatment, the ability to increase waste loadings offers the potential to significantly reduce the amount of glass that must be produced and disposed and, therefore, the overall project costs. This report presents the results from a study to investigate several glass property issues related to WTP HLW and LAW vitrification: crystal formation and settling in selected HLW glasses; redox behavior of vanadium and chromium in selected LAW glasses; and key high temperature thermal properties of representative HLW and LAW glasses. The work was conducted according to Test Plans that were prepared for the HLW and LAW scope, respectively. One part of this work thus addresses some of the possible detrimental effects due to considerably higher crystal content in waste glass melts and, in particular, the impact of high crystal contents on the flow property of the glass melt and the settling rate of representative crystalline phases in an environment similar to that of an idling glass melter. Characterization of vanadium redox shifts in representative WTP LAW glasses is the second focal point of this work. The third part of this work focused on key high temperature thermal properties of representative WTP HLW and LAW glasses over a wide range of temperatures, from the melter operating temperature to the glass transition.

  16. Thermal Evolution of Strange Stars

    E-Print Network [OSTI]

    Zhou Xia; Wang Lingzhi; Zhou Aizhi

    2007-09-03

    We investigated the thermal evolution of rotating strange stars with the deconfinement heating due to magnetic braking. We consider the stars consisting of either normal quark matter or color-flavor-locked phase. Combining deconfinement heating with magnetic field decay, we find that the thermal evolution curves are identical to pulsar data.

  17. Thermal entanglement of bosonic modes

    E-Print Network [OSTI]

    M. Asoudeh

    2006-07-21

    We study the change of entanglement under general linear transformation of modes in a bosonic system and determine the conditions under which entanglement can be generated under such transformation. As an example we consider the thermal entanglement between the vibrational modes of two coupled oscillators and determine the temperature above which quantum correlations are destroyed by thermal fluctuations.

  18. Peg supported thermal insulation panel

    DOE Patents [OSTI]

    Nowobilski, J.J.; Owens, W.J.

    1985-04-30

    A thermal insulation panel which is lightweight, load bearing, accommodates thermal stress, and has excellent high temperature insulation capability comprises high performance insulation between thin metal walls supported by high density, high strength glass pegs made in compliance with specified conditions of time, temperature and pressure. 2 figs.

  19. LMFBR thermal-striping evaluation

    SciTech Connect (OSTI)

    Brunings, J.E.

    1982-10-01

    Thermal striping is defined as the fluctuating temperature field that is imposed on a structure when fluid streams at different temperatures mix in the vicinity of the structure surface. Because of the uncertainty in structural damage in LMFBR structures subject to thermal striping, EPRI has funded an effort for the Rockwell International Energy Systems Group to evaluate this problem. This interim report presents the following information: (1) a Thermal Striping Program Plan which identifies areas of analytic and experimental needs and presents a program of specific tasks to define damage experienced by ordinary materials of construction and to evaluate conservatism in the existing approach; (2) a description of the Thermal Striping Test Facility and its operation; and (3) results from the preliminary phase of testing to characterize the fluid environment to be applied in subsequent thermal striping damage experiments.

  20. 303:20130618.1036 Thermal Engineering Group

    E-Print Network [OSTI]

    Mojzsis, Stephen J.

    303:20130618.1036 Thermal Engineering Group LASP's Thermal Engineering Group is involved in all of the component, as well as on-orbit trending and operations planning. Design Experience The Thermal Engineering Systems Engineering The group has formulated general thermal design and thermal interface requirements

  1. Thermal to electricity conversion using thermal magnetic properties

    DOE Patents [OSTI]

    West, Phillip B [Idaho Falls, ID; Svoboda, John [Idaho Falls, ID

    2010-04-27

    A system for the generation of Electricity from Thermal Energy using the thermal magnetic properties of a Ferromagnetic, Electrically Conductive Material (FECM) in one or more Magnetic Fields. A FECM is exposed to one or more Magnetic Fields. Thermal Energy is applied to a portion of the FECM heating the FECM above its Curie Point. The FECM, now partially paramagnetic, moves under the force of the one or more Magnetic Fields. The movement of the FECM induces an electrical current through the FECM, generating Electricity.

  2. Thermal Stress and Reliability for Advanced Power Electronics...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    & Publications Thermal Stress and Reliability for Advanced Power Electronics and Electric Machines Power Electronic Thermal System Performance and Integration Thermal...

  3. Solar Thermal Demonstration Project

    SciTech Connect (OSTI)

    Biesinger, K.; Cuppett, D.; Dyer, D.

    2012-01-30

    HVAC Retrofit and Energy Efficiency Upgrades at Clark High School, Las Vegas, Nevada The overall objectives of this project are to increase usage of alternative/renewable fuels, create a better and more reliable learning environment for the students, and reduce energy costs. Utilizing the grant resources and local bond revenues, the District proposes to reduce electricity consumption by installing within the existing limited space, one principal energy efficient 100 ton adsorption chiller working in concert with two 500 ton electric chillers. The main heating source will be primarily from low nitrogen oxide (NOX), high efficiency natural gas fired boilers. With the use of this type of chiller, the electric power and cost requirements will be greatly reduced. To provide cooling to the information technology centers and equipment rooms of the school during off-peak hours, the District will install water source heat pumps. In another measure to reduce the cooling requirements at Clark High School, the District will replace single pane glass and metal panels with â??Kalwallâ?? building panels. An added feature of the â??Kalwallâ?ť system is that it will allow for natural day lighting in the student center. This system will significantly reduce thermal heat/cooling loss and control solar heat gain, thus delivering significant savings in heating ventilation and air conditioning (HVAC) costs.

  4. Microelectromechanical (MEM) thermal actuator

    DOE Patents [OSTI]

    Garcia, Ernest J. (Albuquerque, NM); Fulcher, Clay W. G. (Sandia Park, NM)

    2012-07-31

    Microelectromechanical (MEM) buckling beam thermal actuators are disclosed wherein the buckling direction of a beam is constrained to a desired direction of actuation, which can be in-plane or out-of-plane with respect to a support substrate. The actuators comprise as-fabricated, linear beams of uniform cross section supported above the substrate by supports which rigidly attach a beam to the substrate. The beams can be heated by methods including the passage of an electrical current through them. The buckling direction of an initially straight beam upon heating and expansion is controlled by incorporating one or more directional constraints attached to the substrate and proximal to the mid-point of the beam. In the event that the beam initially buckles in an undesired direction, deformation of the beam induced by contact with a directional constraint generates an opposing force to re-direct the buckling beam into the desired direction. The displacement and force generated by the movement of the buckling beam can be harnessed to perform useful work, such as closing contacts in an electrical switch.

  5. Thermal energy storage apparatus

    SciTech Connect (OSTI)

    Thoma, P.E.

    1980-04-22

    A thermal energy storage apparatus and method employs a container formed of soda lime glass and having a smooth, defectfree inner wall. The container is filled substantially with a material that can be supercooled to a temperature greater than 5* F., such as ethylene carbonate, benzophenone, phenyl sulfoxide, di-2-pyridyl ketone, phenyl ether, diphenylmethane, ethylene trithiocarbonate, diphenyl carbonate, diphenylamine, 2benzoylpyridine, 3-benzoylpyridine, 4-benzoylpyridine, 4methylbenzophenone, 4-bromobenzophenone, phenyl salicylate, diphenylcyclopropenone, benzyl sulfoxide, 4-methoxy-4prmethylbenzophenone, n-benzoylpiperidine, 3,3pr,4,4pr,5 pentamethoxybenzophenone, 4,4'-bis-(Dimethylamino)-benzophenone, diphenylboron bromide, benzalphthalide, benzophenone oxime, azobenzene. A nucleating means such as a seed crystal, a cold finger or pointed member is movable into the supercoolable material. A heating element heats the supercoolable material above the melting temperature to store heat. The material is then allowed to cool to a supercooled temperature below the melting temperature, but above the natural, spontaneous nucleating temperature. The liquid in each container is selectively initiated into nucleation to release the heat of fusion. The heat may be transferred directly or through a heat exchange unit within the material.

  6. THERMAL ENERGY STORAGE IN AQUIFERS WORKSHOP

    E-Print Network [OSTI]

    Authors, Various

    2011-01-01

    the arrival Stored Heat Energy and Thermal Pollution DailyAn Answer to Energy Conservation and Thermal validity of ourWells for Conserving Energy and Reducing Thermal Pollution,"

  7. THERMAL ENERGY STORAGE IN AQUIFERS WORKSHOP

    E-Print Network [OSTI]

    Authors, Various

    2011-01-01

    Resources Res. 14: 273-280. THERMAL STORAGE OF COLD WATER INR.C. HARE, 1972. Thermal Storage for Eco-Energy Utilities,W.J. MASICA, 1977. "Thermal Storage for Electric Utilities,"

  8. AQUIFER THERMAL ENERGY STORAGE-A SURVEY

    E-Print Network [OSTI]

    Tsang, Chin Fu

    2012-01-01

    R. C. 1 1972 1 Thermal storage for eco=energy utilities: GE-and Harris, w. B. 0 1978 0 Thermal storage of cold water induration EXPERIMENTS Thermal storage radius (m) thickness

  9. Lake thermal structure influences macroinvertebrate predation on

    E-Print Network [OSTI]

    Arnott, Shelley

    . KEYWORDS: thermal stratification; climate warming; Chaoborus; notonectid; Boreal Shield; mesocosm INTRODUCTION Climate change is expected to alter the timing, strength and depth of thermal stratificationLake thermal structure influences macroinvertebrate predation on crustacean zooplankton SHANNON A

  10. Thermal properties of soils and soils testing

    SciTech Connect (OSTI)

    Not Available

    1981-02-17

    The thermal properties of soils are reviewed with reference to the use of soils as heat sources, heat sinks, or thermal storage. Specific heat and thermal conductivity are discussed. (ACR)

  11. THERMAL ENERGY STORAGE IN AQUIFERS WORKSHOP

    E-Print Network [OSTI]

    Authors, Various

    2011-01-01

    20) E. B. Quale. Seasonal storage of thermal energy in waterE.B. , 1976. "Seasonal Storage of Thermal Energy in Water ina truly worthwhile goal. Seasonal Storage of Thermal Energy

  12. Advanced nanofabrication of thermal emission devices

    E-Print Network [OSTI]

    Hurley, Fergus (Fergus Gerard)

    2008-01-01

    Nanofabricated thermal emission devices can be used to modify and modulate blackbody thermal radiation. There are many areas in which altering thermal radiation is extremely useful, especially in static power conversion, ...

  13. Recycling of wasted energy : thermal to electrical energy conversion

    E-Print Network [OSTI]

    Lim, Hyuck

    2011-01-01

    ocean thermal energy, distributed solar thermal energy,heat source can be solar thermal energy, biological thermaland concentrated solar thermal energy farms. They demand

  14. Thermoelectrics Combined with Solar Concentration for Electrical and Thermal Cogeneration

    E-Print Network [OSTI]

    Jackson, Philip Robert

    2012-01-01

    significant challenge for solar thermal energy generation issolar thermal, cogeneration of electrical and thermal energy, andfor efficient energy production. Solar thermal plants, such

  15. Thermoelectrics Combined with Solar Concentration for Electrical and Thermal Cogeneration

    E-Print Network [OSTI]

    Jackson, Philip Robert

    2012-01-01

    significant challenge for solar thermal energy generation issolar thermal, cogeneration of electrical and thermal energy,for efficient energy production. Solar thermal plants, such

  16. Recycling of wasted energy : thermal to electrical energy conversion

    E-Print Network [OSTI]

    Lim, Hyuck

    2011-01-01

    heat source can be solar thermal energy, biological thermaland concentrated solar thermal energy farms. They demandsources include solar thermal energy, geo-thermal energy,

  17. Ocean Thermal Extractable Energy Visualization

    SciTech Connect (OSTI)

    Ascari, Matthew

    2012-10-28

    The Ocean Thermal Extractable Energy Visualization (OTEEV) project focuses on assessing the Maximum Practicably Extractable Energy (MPEE) from the world’s ocean thermal resources. MPEE is defined as being sustainable and technically feasible, given today’s state-of-the-art ocean energy technology. Under this project the OTEEV team developed a comprehensive Geospatial Information System (GIS) dataset and software tool, and used the tool to provide a meaningful assessment of MPEE from the global and domestic U.S. ocean thermal resources.

  18. Rapid thermal processing by stamping

    DOE Patents [OSTI]

    Stradins, Pauls; Wang, Qi

    2013-03-05

    A rapid thermal processing device and methods are provided for thermal processing of samples such as semiconductor wafers. The device has components including a stamp (35) having a stamping surface and a heater or cooler (40) to bring it to a selected processing temperature, a sample holder (20) for holding a sample (10) in position for intimate contact with the stamping surface; and positioning components (25) for moving the stamping surface and the stamp (35) in and away from intimate, substantially non-pressured contact. Methods for using and making such devices are also provided. These devices and methods allow inexpensive, efficient, easily controllable thermal processing.

  19. Integrated External Aerodynamic and Underhood Thermal Analysis...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    External Aerodynamic and Underhood Thermal Analysis for Heavy Vehicles Integrated External Aerodynamic and Underhood Thermal Analysis for Heavy Vehicles 2012 DOE Hydrogen and Fuel...

  20. Develop & Evaluate Materials & Additives that Enhance Thermal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Evaluate Materials & Additives that Enhance Thermal & Overcharge Abuse Develop & Evaluate Materials & Additives that Enhance Thermal & Overcharge Abuse 2011 DOE Hydrogen and Fuel...

  1. Continuous Processing of High Thermal Conductivity Polyethylene...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Processing of High Thermal Conductivity Polyethylene Fibers and Sheets Continuous Processing of High Thermal Conductivity Polyethylene Fibers and Sheets Massachusetts Institute of...

  2. Thermally Activated Technologies Technology Roadmap, May 2003...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermally Activated Technologies Technology Roadmap, May 2003 Thermally Activated Technologies Technology Roadmap, May 2003 The purpose of this Technology Roadmap is to outline a...

  3. Scattering Solar Thermal Concentrators

    SciTech Connect (OSTI)

    Giebink, Noel C.

    2015-01-31

    This program set out to explore a scattering-based approach to concentrate sunlight with the aim of improving collector field reliability and of eliminating wind loading and gross mechanical movement through the use of a stationary collection optic. The approach is based on scattering sunlight from the focal point of a fixed collection optic into the confined modes of a sliding planar waveguide, where it is transported to stationary tubular heat transfer elements located at the edges. Optical design for the first stage of solar concentration, which entails focusing sunlight within a plane over a wide range of incidence angles (>120 degree full field of view) at fixed tilt, led to the development of a new, folded-path collection optic that dramatically out-performs the current state-of-the-art in scattering concentration. Rigorous optical simulation and experimental testing of this collection optic have validated its performance. In the course of this work, we also identified an opportunity for concentrating photovoltaics involving the use of high efficiency microcells made in collaboration with partners at the University of Illinois. This opportunity exploited the same collection optic design as used for the scattering solar thermal concentrator and was therefore pursued in parallel. This system was experimentally demonstrated to achieve >200x optical concentration with >70% optical efficiency over a full day by tracking with <1 cm of lateral movement at fixed latitude tilt. The entire scattering concentrator waveguide optical system has been simulated, tested, and assembled at small scale to verify ray tracing models. These models were subsequently used to predict the full system optical performance at larger, deployment scale ranging up to >1 meter aperture width. Simulations at an aperture widths less than approximately 0.5 m with geometric gains ~100x predict an overall optical efficiency in the range 60-70% for angles up to 50 degrees from normal. However, the concentrator optical efficiency was found to decrease significantly with increasing aperture width beyond 0.5 m due to parasitic waveguide out-coupling loss and low-level absorption that become dominant at larger scale. A heat transfer model was subsequently implemented to predict collector fluid heat gain and outlet temperature as a function of flow rate using the optical model as a flux input. It was found that the aperture width size limitation imposed by the optical efficiency characteristics of the waveguide limits the absolute optical power delivered to the heat transfer element per unit length. As compared to state-of-the-art parabolic trough CPV system aperture widths approaching 5 m, this limitation leads to an approximate factor of order of magnitude increase in heat transfer tube length to achieve the same heat transfer fluid outlet temperature. The conclusion of this work is that scattering solar thermal concentration cannot be implemented at the scale and efficiency required to compete with the performance of current parabolic trough CSP systems. Applied within the alternate context of CPV, however, the results of this work have likely opened up a transformative new path that enables quasi-static, high efficiency CPV to be implemented on rooftops in the form factor of traditional fixed-panel photovoltaics.

  4. Acknowledgments Hard and Thermal Photon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acknowledgments Hard and Thermal Photon Absorption in a QGP Eric Palmerduca 1,2 Advisor: Dr. Rainer Fries 2 1 Colgate University 2 Cyclotron Institute, Department of Physics and...

  5. Hanford High-Level Waste Vitrification Program at the Pacific Northwest National Laboratory: technology development - annotated bibliography

    SciTech Connect (OSTI)

    Larson, D.E.

    1996-09-01

    This report provides a collection of annotated bibliographies for documents prepared under the Hanford High-Level Waste Vitrification (Plant) Program. The bibliographies are for documents from Fiscal Year 1983 through Fiscal Year 1995, and include work conducted at or under the direction of the Pacific Northwest National Laboratory. The bibliographies included focus on the technology developed over the specified time period for vitrifying Hanford pretreated high-level waste. The following subject areas are included: General Documentation; Program Documentation; High-Level Waste Characterization; Glass Formulation and Characterization; Feed Preparation; Radioactive Feed Preparation and Glass Properties Testing; Full-Scale Feed Preparation Testing; Equipment Materials Testing; Melter Performance Assessment and Evaluations; Liquid-Fed Ceramic Melter; Cold Crucible Melter; Stirred Melter; High-Temperature Melter; Melter Off-Gas Treatment; Vitrification Waste Treatment; Process, Product Control and Modeling; Analytical; and Canister Closure, Decontamination, and Handling

  6. Advanced Thermally Stable Jet Fuels

    SciTech Connect (OSTI)

    A. Boehman; C. Song; H. H. Schobert; M. M. Coleman; P. G. Hatcher; S. Eser

    1998-01-01

    The Penn State program in advanced thermally stable jet fuels has five components: 1) development of mechanisms of degradation and solids formation; 2) quantitative measurement of growth of sub-micrometer and micrometer-sized particles during thermal stressing; 3) characterization of carbonaceous deposits by various instrumental and microscopic methods; 4) elucidation of the role of additives in retarding the formation of carbonaceous solids; and 5) assessment of the potential of producing high yields of cycloalkanes and hydroaromatics from coal.

  7. Thermally activated technologies: Technology Roadmap

    SciTech Connect (OSTI)

    None, None

    2003-05-01

    The purpose of this Technology Roadmap is to outline a set of actions for government and industry to develop thermally activated technologies for converting America’s wasted heat resources into a reservoir of pollution-free energy for electric power, heating, cooling, refrigeration, and humidity control. Fuel flexibility is important. The actions also cover thermally activated technologies that use fossil fuels, biomass, and ultimately hydrogen, along with waste heat.

  8. Power Electronics Thermal Control (Presentation)

    SciTech Connect (OSTI)

    Narumanchi, S.

    2010-05-05

    Thermal management plays an important part in the cost of electric drives in terms of power electronics packaging. Very promising results have been obtained by using microporous coatings and skived surfaces in conjunction with single-phase and two-phase flows. Sintered materials and thermoplastics with embedded fibers show significant promise as thermal interface materials, or TIMs. Appropriate cooling technologies depend on the power electronics package application and reliability.

  9. Lih thermal energy storage device

    DOE Patents [OSTI]

    Olszewski, Mitchell (Knoxville, TN); Morris, David G. (Knoxville, TN)

    1994-01-01

    A thermal energy storage device for use in a pulsed power supply to store waste heat produced in a high-power burst operation utilizes lithium hydride as the phase change thermal energy storage material. The device includes an outer container encapsulating the lithium hydride and an inner container supporting a hydrogen sorbing sponge material such as activated carbon. The inner container is in communication with the interior of the outer container to receive hydrogen dissociated from the lithium hydride at elevated temperatures.

  10. Onsite Wastewater Treatment Systems: Aerobic Treatment Unit 

    E-Print Network [OSTI]

    Lesikar, Bruce J.

    2008-10-31

    Aerobic units treat wastewater using the same process, only scaled down, as municipal wastewater treatment systems. This publication explains how aerobic units work, what their design requirements are, and how to maintain them....

  11. Thermal Batteries for Electric Vehicles

    SciTech Connect (OSTI)

    2011-11-21

    HEATS Project: UT Austin will demonstrate a high-energy density and low-cost thermal storage system that will provide efficient cabin heating and cooling for EVs. Compared to existing HVAC systems powered by electric batteries in EVs, the innovative hot-and-cold thermal batteries-based technology is expected to decrease the manufacturing cost and increase the driving range of next-generation EVs. These thermal batteries can be charged with off-peak electric power together with the electric batteries. Based on innovations in composite materials offering twice the energy density of ice and 10 times the thermal conductivity of water, these thermal batteries are expected to achieve a comparable energy density at 25% of the cost of electric batteries. Moreover, because UT Austin’s thermal energy storage systems are modular, they may be incorporated into the heating and cooling systems in buildings, providing further energy efficiencies and positively impacting the emissions of current building heating/cooling systems.

  12. Emergency Medical Treatment Required

    E-Print Network [OSTI]

    McQuade, D. Tyler

    Emergency Medical Treatment Required Non-Emergency Medical Treatment Required If possible, get help from colleague or supervisor Call 911 or go to hospital emergency room (for chemical exposure, bring Investigation Report" to Environmental Health & Safety within 48 hours Emergency Medical Treatment Required

  13. Thermal storage module for solar dynamic receivers

    DOE Patents [OSTI]

    Beatty, Ronald L. (Farragut, TN); Lauf, Robert J. (Oak Ridge, TN)

    1991-01-01

    A thermal energy storage system comprising a germanium phase change material and a graphite container.

  14. Thermal to Visible Face Recognition Jonghyun Choi

    E-Print Network [OSTI]

    Daume III, Hal

    Thermal to Visible Face Recognition Jonghyun Choi , Shuowen Hu , S. Susan Young and Larry S. Davis surveillance, thermal imaging is commonly used because of the intrinsic emissivity of thermal radiation from the human body. However, matching thermal images of faces acquired at nighttime to the predominantly visible

  15. Thermal diffusion shock waves Sorasak Danworaphong1

    E-Print Network [OSTI]

    Craig, Walter

    Thermal diffusion shock waves Sorasak Danworaphong1 , Walter Craig3 , Vitalyi Gusev4 , and Gerald J and are concentrated by a thermal gradient imposed on a salt solution, the separation of the components of a mixture in a thermal field, known as "thermal diffusion", or the Ludwig-Soret effect has been found not only in liquids

  16. Battery Thermal Management System Design Modeling (Presentation)

    SciTech Connect (OSTI)

    Kim, G-H.; Pesaran, A.

    2006-10-01

    Presents the objectives and motivations for a battery thermal management vehicle system design study.

  17. Device for thermal transfer and power generation

    DOE Patents [OSTI]

    Weaver, Stanton Earl (Northville, NY); Arik, Mehmet (Niskayuna, NY)

    2011-04-19

    A system is provided. The system includes a device that includes top and bottom thermally conductive substrates positioned opposite to one another, wherein a top surface of the bottom thermally conductive substrate is substantially atomically flat and a thermal blocking layer disposed between the top and bottom thermally conductive substrates. The device also includes top and bottom electrodes separated from one another between the top and bottom thermally conductive substrates to define a tunneling path, wherein the top electrode is disposed on the thermal blocking layer and the bottom electrode is disposed on the bottom thermally conductive substrate.

  18. Active Thermal Extraction of Near-field Thermal Radiation

    E-Print Network [OSTI]

    Ding, Ding

    2015-01-01

    Radiative heat transport between materials supporting surface-phonon polaritons is greatly enhanced when the materials are placed at sub-wavelength separation as a result of the contribution of near-field surface modes. However, the enhancement is limited to small separations due to the evanescent decay of the surface waves. In this work, we propose and numerically demonstrate an active scheme to extract these modes to the far-field. Our approach exploits the monochromatic nature of near-field thermal radiation to drive a transition in a laser gain medium, which, when coupled with external optical pumping, allows the resonant surface mode to be emitted into the far-field. Our study demonstrates a new approach to manipulate thermal radiation that could find applications in thermal management.

  19. Validation of thermal models for a prototypical MEMS thermal actuator.

    SciTech Connect (OSTI)

    Gallis, Michail A.; Torczynski, John Robert; Piekos, Edward Stanley; Serrano, Justin Raymond; Gorby, Allen D.; Phinney, Leslie Mary

    2008-09-01

    This report documents technical work performed to complete the ASC Level 2 Milestone 2841: validation of thermal models for a prototypical MEMS thermal actuator. This effort requires completion of the following task: the comparison between calculated and measured temperature profiles of a heated stationary microbeam in air. Such heated microbeams are prototypical structures in virtually all electrically driven microscale thermal actuators. This task is divided into four major subtasks. (1) Perform validation experiments on prototypical heated stationary microbeams in which material properties such as thermal conductivity and electrical resistivity are measured if not known and temperature profiles along the beams are measured as a function of electrical power and gas pressure. (2) Develop a noncontinuum gas-phase heat-transfer model for typical MEMS situations including effects such as temperature discontinuities at gas-solid interfaces across which heat is flowing, and incorporate this model into the ASC FEM heat-conduction code Calore to enable it to simulate these effects with good accuracy. (3) Develop a noncontinuum solid-phase heat transfer model for typical MEMS situations including an effective thermal conductivity that depends on device geometry and grain size, and incorporate this model into the FEM heat-conduction code Calore to enable it to simulate these effects with good accuracy. (4) Perform combined gas-solid heat-transfer simulations using Calore with these models for the experimentally investigated devices, and compare simulation and experimental temperature profiles to assess model accuracy. These subtasks have been completed successfully, thereby completing the milestone task. Model and experimental temperature profiles are found to be in reasonable agreement for all cases examined. Modest systematic differences appear to be related to uncertainties in the geometric dimensions of the test structures and in the thermal conductivity of the polycrystalline silicon test structures, as well as uncontrolled nonuniform changes in this quantity over time and during operation.

  20. High Performance Thermal Interface Technology Overview

    E-Print Network [OSTI]

    R. Linderman; T. Brunschwiler; B. Smith; B. Michel

    2008-01-07

    An overview on recent developments in thermal interfaces is given with a focus on a novel thermal interface technology that allows the formation of 2-3 times thinner bondlines with strongly improved thermal properties at lower assembly pressures. This is achieved using nested hierarchical surface channels to control the particle stacking with highly particle-filled materials. Reliability testing with thermal cycling has also demonstrated a decrease in thermal resistance after extended times with longer overall lifetime compared to a flat interface.

  1. Treatment-resistant pyoderma gangrenosum

    E-Print Network [OSTI]

    Kosari, Payman; Feldman, Steven R

    2012-01-01

    of compliance with psoriasis treatment. J Cutan Med Surg .in the treatment of psoriasis: a systematic review.acid gel for plaque psoriasis treatment. Arch Dermatol 141(

  2. Considering biomedical/CAM treatments

    E-Print Network [OSTI]

    Cheng, JX; Widjaja, F; Choi, JE; Hendren, RL

    2013-01-01

    and possible use of biomedical CAM treatments, including24 April 2013 ? 6:40 pm Biomedical Complementary Treatment24 April 2013 ? 6:40 pm Biomedical Complementary Treatment

  3. THERMALLY ACTIVATED MARTENSITE: ITS RELATIONSHIP TO NON-THERMALLY ACTIVATED (ATHERMAL) MARTENSITE

    E-Print Network [OSTI]

    Laughlin, David E.

    THERMALLY ACTIVATED MARTENSITE: ITS RELATIONSHIP TO NON-THERMALLY ACTIVATED (ATHERMAL) MARTENSITE Keywords: Thermal Activation, Isothermal, Athermal, Activation Energy Abstract The classification of no thermal activation. Processes with no thermal activation do not depend on time, as there is no need

  4. Thermal properties of graphene and multilayer graphene: Applications in thermal interface materials

    E-Print Network [OSTI]

    Thermal properties of graphene and multilayer graphene: Applications in thermal interface materials 2012 Accepted by L. Bery Available online 25 April 2012 Keywords: A. Graphene A. Thermal interface materials C. Graphene composites D. Thermal properties a b s t r a c t We review the thermal properties

  5. Thermal Signature: A Simple Yet Accurate Thermal Index for Floorplan Optimization

    E-Print Network [OSTI]

    Sapatnekar, Sachin

    Thermal Signature: A Simple Yet Accurate Thermal Index for Floorplan Optimization ABSTRACT evaluation should be done extremely fast with high accuracy. A new thermal index, named thermal signature's function and power density in- tegrated over space. The correlation coefficient between thermal signature

  6. UNH Thermal WorkshopUNH Thermal Workshop or how important isor how important is

    E-Print Network [OSTI]

    UNH Thermal WorkshopUNH Thermal Workshop or how important isor how important is stream) EPA grants to UNH for thermal regimes of Northeast g g Streams and Thermal Impacts of Stormwater BMPsResponse curves created for original R1 RARE Extension to fish communities Build on UNH BMP Thermal work

  7. Thermal trim for a luminaire

    DOE Patents [OSTI]

    Bazydola, Sarah; Ghiu, Camil-Daniel; Harrison, Robert; Jeswani, Anil

    2013-02-19

    A luminaire with a thermal pathway to reduce the junction temperature of the luminaire's light source, and methods for so doing, are disclosed. The luminaire includes a can, a light engine, and a trim, that define a substantially continuous thermal pathway from the light engine to a surrounding environment. The can defines a can cavity and includes a can end region. The light engine is within the can cavity and includes a light source and a heat sink, including a heat sink end region, coupled thereto. The trim is at least partially disposed within the can cavity and includes a first trim end region coupled to the heat sink end region and a second trim end region coupled to the can end region. Thermal interface material may be located between: the heat sink and the trim, the trim and the can, and/or the heat sink and the light source.

  8. Holographic thermalization of charged operators

    E-Print Network [OSTI]

    Alejandro Giordano; Nicolas E. Grandi; Guillermo A. Silva

    2014-12-26

    We study a light-like charged collapsing shell in AdS-Reissner-Nordstrom spacetime, investigating whether the corresponding Vaidya metric is supported by matter that satisfies the null energy condition. We find that, if the absolute value of the charge decreases during the collapse, energy conditions are fulfilled everywhere in spacetime. On the other hand, if the absolute value of the charge increases, the metric does not satisfy energy conditions in the IR region. Therefore, from the gauge/gravity perspective, this last case is only useful to study the thermalization of the UV degrees of freedom. For all these geometries, we probe the thermalization process with two point correlators of charged operators, finding that the thermalization time grows with the charge of the operator, as well as with the dimension of space.

  9. Thermality of the Hawking flux

    E-Print Network [OSTI]

    Visser, Matt

    2014-01-01

    Is the Hawking flux "thermal"? Unfortunately, the answer to this seemingly innocent question depends on a number of often unstated, but quite crucial, technical assumptions built into modern (mis-)interpretations of the word "thermal". The original 1850's notions of thermality --- based on classical thermodynamic reasoning applied to idealized "black bodies" or "lamp black surfaces" --- when supplemented by specific basic quantum ideas from the early 1900's, immediately led to the notion of the black-body spectrum, (the Planck-shaped spectrum), but "without" any specific assumptions or conclusions regarding correlations between the quanta. Many (not all) modern authors (often implicitly and unintentionally) add an extra, and quite unnecessary, assumption that there are no correlations in the black-body radiation; but such usage is profoundly ahistorical and dangerously misleading. Specifically, the Hawking flux from an evaporating black hole, (just like the radiation flux from a leaky furnace or a burning lum...

  10. On the origin of thermality

    E-Print Network [OSTI]

    Bernard S. Kay

    2012-12-04

    It is well-known that a small system weakly coupled to a large energy bath in a total microcanonical ensemble will find itself in an (approximately) thermal state and, recently, it has been shown that, if the total state is, instead, a random pure state with energy in a narrow range, then the small system will still be approximately thermal with a high probability (wrt `Haar measure'). We ask what conditions are required for something resembling these 'traditional' and 'modern' thermality results to still hold when system and energy bath are of comparable size. In Part 1, we show that, for given system and energy-bath densities of states, s_S(e) and s_B(e), thermality does not hold in general, as we illustrate when both increase as powers of energy, but that it does hold in certain approximate senses, in both traditional and modern frameworks, when both grow as exp(be) or as exp(qe^2) and we calculate the system entropy in these cases. In their 'modern' version, our results rely on new quantities, which we introduce and call the S and B 'modapprox' density operators, which, we claim, will, with high probability, give a close approximation to the reduced density operator for the system and energy bath when the total state of system plus energy bath is a random pure state with energy in a narrow range. In Part 2 we clarify the meaning of these modapprox density operators and give arguments for our claim. The prime examples of non-small thermal systems are quantum black holes. Here and in two companion papers, we argue that current string-theoretic derivations of black hole entropy and thermal properties are incomplete and, on the question of information loss, inconclusive. However, we argue that these deficiencies are remedied with a modified scenario which relies on the modern strand of our methods and results here and is based on our previous 'matter-gravity entanglement hypothesis'.

  11. Effective Thermal Conductivity of Graded Nanocomposites with Interfacial Thermal

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    .M. Yin", G. H. Paulino", W.G. Buttlar", and L.Z. Sun'' '^Department of Civil and Environmental the effective thermal conductivity distribution in functionally graded materials (FGMs) considering the Kapitza is developed to derive the averaged heat flux field of the particle phase. Then the temperature gradient can

  12. Advances in Psoriasis Treatment

    E-Print Network [OSTI]

    Feldman, Steven R

    2000-01-01

    population of patients with psoriasis. Cutis 58 (3):216-220,The economic impact of psoriasis increases with psoriasisterm cyclosporin treatment of psoriasis [see comments]. Br J

  13. Investigations of the small-scale thermal behavior of sol-gel thermites.

    SciTech Connect (OSTI)

    Warren, Mial E.; Farrow, Matthew; Tappan, Alexander Smith

    2009-02-01

    Sol-gel thermites, formulated from nanoporous oxides and dispersed fuel particles, may provide materials useful for small-scale, intense thermal sources, but understanding the factors affecting performance is critical prior to use. Work was conducted on understanding the synthesis conditions, thermal treatments, and additives that lead to different performance characteristics in iron oxide sol-gel thermites. Additionally, the safety properties of sol-gel thermites were investigated, especially those related to air sensitivity. Sol-gel thermites were synthesized using a variety of different techniques and there appear to be many viable routes to relatively equivalent thermites. These thermites were subjected to several different thermal treatments under argon in a differential scanning calorimeter, and it was shown that a 65 C hold for up to 200 minutes was effective for the removal of residual solvent, thus preventing boiling during the final thermal activation step. Vacuum-drying prior to this heating was shown to be even more effective at removing residual solvent. The addition of aluminum and molybdenum trioxide (MoO{sub 3}) reduced the total heat release per unit mass upon exposure to air, probably due to a decrease in the amount of reduced iron oxide species in the thermite. For the thermal activation step of heat treatment, three different temperatures were investigated. Thermal activation at 200 C resulted in increased ignition sensitivity over thermal activation at 232 C, and thermal activation at 300 C resulted in non-ignitable material. Non-sol-gel iron oxide did not exhibit any of the air-sensitivity observed in sol-gel iron oxide. In the DSC experiments, no bulk ignition of sol-gel thermites was observed upon exposure to air after thermal activation in argon; however ignition did occur when the material was heated in air after thermal treatment. In larger-scale experiments, up to a few hundred milligrams, no ignition was observed upon exposure to air after thermal activation in vacuum; however ignition by resistively-heated tungsten wire was possible. Thin films of thermite were fabricated using a dispersed mixture of aluminum and iron oxide particles, but ignition and propagation of these films was difficult. The only ignition and propagation observed was in a preheated sample.

  14. Phase Change Materials for Thermal Energy Storage in Concentrated Solar Thermal Power Plants

    E-Print Network [OSTI]

    Hardin, Corey Lee

    2011-01-01

    COST REDUCTION STUDY FOR SOLAR THERMAL POWER PLANTS, Ottawa,Storage in Concentrated Solar Thermal Power Plants A ThesisStorage in Concentrated Solar Thermal Power Plants by Corey

  15. Thermal Preconditioning and Heat-Shock Protein 72 Preserve Synaptic Transmission during Thermal Stress

    E-Print Network [OSTI]

    Robertson, Meldrum

    Thermal Preconditioning and Heat-Shock Protein 72 Preserve Synaptic Transmission during Thermal therapeutic implications. Key words: hyperthermia; heat shock; synaptic transmission; miniature postsynaptic, exposing the mammalian CNS to nonle- thal heat stress (i.e., thermal preconditioning) increases levels

  16. THERMAL HYDRAULICS KEYWORDS: neutron activation,

    E-Print Network [OSTI]

    Pázsit, Imre

    THERMAL HYDRAULICS KEYWORDS: neutron activation, flow measurements, evaluation methods FLOWACT, FLOW RATE MEASUREMENTS IN PIPES WITH THE PULSED-NEUTRON ACTIVATION METHOD PER LINDÉN,* GUDMAR GROSSHÖG- neutron activation (PNA) in a specially designed test loop. A stationary neutron generator was used

  17. Low Conductivity Thermal Barrier Coatings

    E-Print Network [OSTI]

    Wadley, Haydn

    Low Conductivity Thermal Barrier Coatings A Dissertation Presented to The Faculty of the School ________________________________________________________________________ Abstract The dissertation begins by exploring the growth of 7YSZ coatings on vapor deposited NiCoCrAlY bond coats at different substrate rotation rates. The experiments show that as the rotation rate

  18. Thermo Tracer Infrared Thermal Imager

    E-Print Network [OSTI]

    Walker, D. Greg

    -range area G Environment monitoring Volcano, ecology, vegetation, global warming, pollution G R&D Evaluation is a fixed installation type infrared thermal imaging camera to monitor important facilities Production line monitoring Quality anomalies in production processes G Facility monitoring Anomalies

  19. Solar mechanics thermal response capabilities.

    SciTech Connect (OSTI)

    Dobranich, Dean D.

    2009-07-01

    In many applications, the thermal response of structures exposed to solar heat loads is of interest. Solar mechanics governing equations were developed and integrated with the Calore thermal response code via user subroutines to provide this computational simulation capability. Solar heat loads are estimated based on the latitude and day of the year. Vector algebra is used to determine the solar loading on each face of a finite element model based on its orientation relative to the sun as the earth rotates. Atmospheric attenuation is accounted for as the optical path length varies from sunrise to sunset. Both direct and diffuse components of solar flux are calculated. In addition, shadowing of structures by other structures can be accounted for. User subroutines were also developed to provide convective and radiative boundary conditions for the diurnal variations in air temperature and effective sky temperature. These temperature boundary conditions are based on available local weather data and depend on latitude and day of the year, consistent with the solar mechanics formulation. These user subroutines, coupled with the Calore three-dimensional thermal response code, provide a complete package for addressing complex thermal problems involving solar heating. The governing equations are documented in sufficient detail to facilitate implementation into other heat transfer codes. Suggestions for improvements to the approach are offered.

  20. Solar energy thermalization and storage device

    DOE Patents [OSTI]

    McClelland, John F. (Ames, IA)

    1981-09-01

    A passive solar thermalization and thermal energy storage assembly which is visually transparent. The assembly consists of two substantial parallel, transparent wall members mounted in a rectangular support frame to form a liquid-tight chamber. A semitransparent thermalization plate is located in the chamber, substantially paralled to and about equidistant from the transparent wall members to thermalize solar radiation which is stored in a transparent thermal energy storage liquid which fills the chamber. A number of the devices, as modules, can be stacked together to construct a visually transparent, thermal storage wall for passive solar-heated buildings.

  1. Phase Change Materials for Thermal Energy Storage in Concentrated Solar Thermal Power Plants

    E-Print Network [OSTI]

    Hardin, Corey Lee

    2011-01-01

    STORAGE FOR CONCENTRATING SOLAR POWER PLANTS,” Eurosun 2010,COST REDUCTION STUDY FOR SOLAR THERMAL POWER PLANTS, Ottawa,Storage in Concentrated Solar Thermal Power Plants A Thesis

  2. Phase Change Materials for Thermal Energy Storage in Concentrated Solar Thermal Power Plants

    E-Print Network [OSTI]

    Hardin, Corey Lee

    2011-01-01

    ENERGY STORAGE FOR CONCENTRATING SOLAR POWER PLANTS,”Energy Storage in Concentrated Solar Thermal Power Plants AEnergy Storage in Concentrated Solar Thermal Power Plants by

  3. Phase Change Materials for Thermal Energy Storage in Concentrated Solar Thermal Power Plants

    E-Print Network [OSTI]

    Hardin, Corey Lee

    2011-01-01

    FOR CONCENTRATING SOLAR POWER PLANTS,” Eurosun 2010, Graz,STUDY FOR SOLAR THERMAL POWER PLANTS, Ottawa, Ontario: 1999.heat transfer in solar thermal power plants utilizing phase

  4. Thermal Properties of Graphene and Applications for Thermal Management of High-Power Density Electronics

    E-Print Network [OSTI]

    Yan, Zhong

    2013-01-01

    on Thermal Management, Las Gatos, CA, Nov. 2012 [3] Z. Yan,Thermal Management, Las Gatos, CA, Nov. 2012 Young Scientist

  5. Advanced thermally stable jet fuels

    SciTech Connect (OSTI)

    Schobert, H.H.

    1999-01-31

    The Pennsylvania State University program in advanced thermally stable coal-based jet fuels has five broad objectives: (1) Development of mechanisms of degradation and solids formation; (2) Quantitative measurement of growth of sub-micrometer and micrometer-sized particles suspended in fuels during thermal stressing; (3) Characterization of carbonaceous deposits by various instrumental and microscopic methods; (4) Elucidation of the role of additives in retarding the formation of carbonaceous solids; (5) Assessment of the potential of production of high yields of cycloalkanes by direct liquefaction of coal. Future high-Mach aircraft will place severe thermal demands on jet fuels, requiring the development of novel, hybrid fuel mixtures capable of withstanding temperatures in the range of 400--500 C. In the new aircraft, jet fuel will serve as both an energy source and a heat sink for cooling the airframe, engine, and system components. The ultimate development of such advanced fuels requires a thorough understanding of the thermal decomposition behavior of jet fuels under supercritical conditions. Considering that jet fuels consist of hundreds of compounds, this task must begin with a study of the thermal degradation behavior of select model compounds under supercritical conditions. The research performed by The Pennsylvania State University was focused on five major tasks that reflect the objectives stated above: Task 1: Investigation of the Quantitative Degradation of Fuels; Task 2: Investigation of Incipient Deposition; Task 3: Characterization of Solid Gums, Sediments, and Carbonaceous Deposits; Task 4: Coal-Based Fuel Stabilization Studies; and Task 5: Exploratory Studies on the Direct Conversion of Coal to High Quality Jet Fuels. The major findings of each of these tasks are presented in this executive summary. A description of the sub-tasks performed under each of these tasks and the findings of those studies are provided in the remainder of this volume (Sections 1 through 5).

  6. Nanoscale thermal transport. II. 2003–2012

    E-Print Network [OSTI]

    Cahill, David G.

    A diverse spectrum of technology drivers such as improved thermal barriers, higher efficiency thermoelectric energy conversion, phase-change memory, heat-assisted magnetic recording, thermal management of nanoscale ...

  7. Thermal pumping of light-emitting diodes

    E-Print Network [OSTI]

    Gray, Dodd (Dodd J.)

    2011-01-01

    The work presented here is a study of thermally enhanced injection in light-emitting diodes (LEDs). This effect, which we refer to as "thermal pumping", results from Peltier energy exchange from the lattice to charge ...

  8. THERMAL ENERGY STORAGE IN AQUIFERS WORKSHOP

    E-Print Network [OSTI]

    Authors, Various

    2011-01-01

    environmentally sound method of using thermal energy storageconcept of thermal energy of energy conversion methods tothermal energy, particularly cavern storage, appears to offer a promising near-term method

  9. Thermal Storage with Conventional Cooling Systems 

    E-Print Network [OSTI]

    Kieninger, R. T.

    1994-01-01

    simple thermal energy storage system that already exists in almost every structure - concrete. Thermal storage calculations simulate sub-cooling of a building's structure during unoccupied times. During occupied times, the sub-cooled concrete reduces peak...

  10. Thermal Storage with Conventional Cooling Systems 

    E-Print Network [OSTI]

    McGee, E. E.

    1990-01-01

    "Thermal Storage" is a term that describes a mechanical systems ability to sustain normal HVAC operations through a thermal retention source. This system allows for the curtailment of operating major refrigeration equipment during periods of high kw...

  11. Successfully Marketing Thermal Storage in Commercial Buildings 

    E-Print Network [OSTI]

    McDonald, C.

    1988-01-01

    This paper first reviews the key hurdles to thermal energy storage. Next, case studies of three electric utility thermal storage marketing programs are reviewed. The results of these case studies. as well as advice and experiences from other...

  12. Doctoral Defense "Thermal-hydro-mechanical model

    E-Print Network [OSTI]

    Kamat, Vineet R.

    Doctoral Defense "Thermal-hydro-mechanical model for freezing and thawing soils" Yao Zhang Date been implemented in a finite element system, with a thermal-hydro- mechanical framework being used

  13. Journal of Thermal Biology 31 (2006) 149158 A role for octopamine in coordinating thermoprotection of

    E-Print Network [OSTI]

    Robertson, Meldrum

    2006-01-01

    to failure under heat stress but protective measures taken by the central nervous system (CNS) in particular in insects similar to norepinephrine in vertebrates and is released in response to heat stress. It is a known-lethal thermal stress, heat shock (HS) treatment which entails 3 h at 45 1C followed by a 1 h recovery at room

  14. Solar Thermal Policy in the U.S.: A Review of Best Practices

    E-Print Network [OSTI]

    Delaware, University of

    Waste Water Treatment Plant · Front Page Bottom Picture ­ National Renewable Energy Labs SolarSolar Thermal Policy in the U.S.: A Review of Best Practices in Leading States Renewable Energy · Colleen McCann Kettles ­ Florida Solar Energy Center · Germaine Salim ­ Hawaii Public Utilities Commission

  15. Photothermal investigation of the thermal shock behavior of alumina ceramics for engine components

    E-Print Network [OSTI]

    Mandelis, Andreas

    Photothermal investigation of the thermal shock behavior of alumina ceramics for engine components of alumina ceramic materials (96% Al2O3/3% SiO2/0.9% MgO) treated by applying high temperature and high pressure, a process known as ASPRO conversion technology. Alumina ceramics subjected to ASPRO treatment

  16. Thermal Energy Storage for Cooling of Commercial Buildings

    E-Print Network [OSTI]

    Akbari, H.

    2010-01-01

    of Commercial Building Thermal Energy _Storage in ASEANGas Electric Company, "Thermal Energy Storage for Cooling,"LBL--25393 DE91 ,THERMAL ENERGY STORAGE FOR COOLING OF

  17. OCEAN THERMAL ENERGY CONVERSION: AN OVERALL ENVIRONMENTAL ASSESSMENT

    E-Print Network [OSTI]

    Sands, M.Dale

    2013-01-01

    M.D. (editor). 1980. Ocean Thermal Energy Conversion Draft1980 :. i l OCEAN THERMAL ENERGY CONVERSION: ENVIRONMENTALDevelopment Plan. Ocean Thermal Energy Conversion. U.S. DOE

  18. A Magnetomechanical Thermal Energy Harvester With A Reversible Liquid Interface

    E-Print Network [OSTI]

    He, Hong

    2012-01-01

    for Waste Heat Energy Harvesting and Thermal Conductanceand Mechanical Model of a Thermal Energy Harvesting Device”,to remove the excess thermal energy and prevent burning of

  19. Recycling of wasted energy : thermal to electrical energy conversion

    E-Print Network [OSTI]

    Lim, Hyuck

    2011-01-01

    Recycling of Wasted Energy : Thermal to Electrical EnergyRecycling of Wasted Energy : Thermal to Electrical Energyelectric energy generation and thermal energy conduction

  20. DRAFT. ENVIRONMENTAL ASSESSMENT OCEAN THERMAL ENERGY CONVERSION (OTEC) PILOT PLANTS

    E-Print Network [OSTI]

    Sullivan, S.M.

    2014-01-01

    1979. Commercial ocean thermal energy conversion ( OTEC)field of ocean thermal energy conversion discharges. I~. L.II of the Sixth Ocean Thermal Energy conversion Conference.

  1. SENSIBLE HEAT STORAGE FOR A SOLAR THERMAL POWER PLANT

    E-Print Network [OSTI]

    Baldwin, Thomas F.

    2011-01-01

    studies, electric energy and thermal energy were assumed totemperatures to storage. and thermal energy transfer ratesstores or releases thermal energy. This subsystem consists

  2. ENVIRONMENTAL ASSESSMENT OCEAN THERMAL ENERGY CONVERSION (OTEC) PILOT PLANTS

    E-Print Network [OSTI]

    Sullivan, S.M.

    2014-01-01

    1979. Commercial ocean thermal energy conversion (OTEC)of the Fifth Ocean Thermal Energy Conversion Conference,Sands. 1980. Ocean thermal energy conversion (OTEC) pilot

  3. OCEAN THERMAL ENERGY CONVERSION (OTEC) PROGRAMMATIC ENVIRONMENTAL ANALYSIS

    E-Print Network [OSTI]

    Sands, M. D.

    2011-01-01

    310, the Ocean the Ocean Energy Thermal Energy Conversionfor the commercialization of ocean thermal energy conversionOpen cycle ocean thermal energy conversion. A preliminary

  4. Thermal Adaptation in the Built Environment: a Literature Review

    E-Print Network [OSTI]

    de Dear, Richard; Brager, G. S.

    1998-01-01

    f the Bruce, Man and his thermal environment: physiologicalrecipient of the given thermal environment, but instead isa "comfortable' thermal environment? The answer to this

  5. Thermal Imaging of Single Living Cells Using Semiconductor Quantum Dots

    E-Print Network [OSTI]

    Yang, Jui-Ming

    2009-01-01

    A novel method of thermal activation and temperatureS. Ishiwata, "Imaging of thermal activation of actomyosinbeen used to image thermal activation of single actomyosin

  6. Discrete Element Modeling of Impact Damage on Thermal Barrier Coatings

    E-Print Network [OSTI]

    Minor, Peter Michel

    2013-01-01

    Thermal barrier coating morphology produced by air plasmacompared to other potential thermal barrier coating2 Thermal Barrier Coatings 2.1 System of

  7. Thermoelectrics Combined with Solar Concentration for Electrical and Thermal Cogeneration

    E-Print Network [OSTI]

    Jackson, Philip Robert

    2012-01-01

    designed for optimal thermal storage after extracting theand hot water for thermal storage. 2. Theory and Backgroundnot as ideal for thermal storage. An insulated reservoir

  8. Thermal Energy Storage for Cooling of Commercial Buildings

    E-Print Network [OSTI]

    Akbari, H.

    2010-01-01

    23) Knipp, R. "Marketing Thermal Storage," In Proceedings:1986. Tejl, D.S. , "Thermal Storage Strategies for Energy14) Ott, V,J. , "Thermal Storage Air Conditioning with

  9. Thermal Performance of Phase Change Wallboard for Residential Cooling Application

    E-Print Network [OSTI]

    Feustel, H.E.

    2011-01-01

    Coupling latent thermal storage with the ground by means ofcooling sources. Large thermal storage devices have beenmaterial, would permit the thermal storage to become part of

  10. SENSIBLE HEAT STORAGE FOR A SOLAR THERMAL POWER PLANT

    E-Print Network [OSTI]

    Baldwin, Thomas F.

    2011-01-01

    ADVANCED THERMAL ENERGY STORAGE CONCEPT DEFINITION STUDY FORSchilling. F. E. , Thermal Energy Storage Using PrestressedNo ~cumulate thermal energy storage. Estimate ESTrof2(

  11. Thermal stratification performance of underfloor air distribution (UFAD) systems

    E-Print Network [OSTI]

    Webster, T.; Bauman, Fred; Shi, M.; Reese, J.

    2002-01-01

    Distribution (UFAD): Thermal Stratification Performance,"Engineers, Inc. Thermal Stratification Performance ofSAT) on the thermal stratification in interior spaces, and

  12. Recycling of wasted energy : thermal to electrical energy conversion

    E-Print Network [OSTI]

    Lim, Hyuck

    2011-01-01

    and nuclear power plants, solar thermal energy, geothermalpower plants, distributed solar thermal energy, geo/ocean-power plants and concentrated solar thermal energy farms.

  13. SENSIBLE HEAT STORAGE FOR A SOLAR THERMAL POWER PLANT

    E-Print Network [OSTI]

    Baldwin, Thomas F.

    2011-01-01

    HEAT STORAGE FOR A SOLAR THERMAL POWER PLANT Thomas F.CENTRAL RECEIVER SOLAR THERMAL POWER SYSTEM, PHASE progressCorporation, RECEIVER SOLAR THERMAL POWER SYSTEM, PHASE I,

  14. Thermal Energy Storage for Cooling of Commercial Buildings

    E-Print Network [OSTI]

    Akbari, H.

    2010-01-01

    Building Thermal Energy _Storage in ASEAN Countries,"Company, "Thermal Energy Storage for Cooling," Seminar25393 DE91 ,THERMAL ENERGY STORAGE FOR COOLING OF COMMERCIAL

  15. Comparison of thermal annealing effects on electrical activation of MBE grown and ion implant Si-doped In0.53Ga0.47As

    E-Print Network [OSTI]

    Florida, University of

    Comparison of thermal annealing effects on electrical activation of MBE grown and ion implant Si are metastable and susceptible to deactivation upon subsequent thermal treatments after growth. Active Si doping.47As Appl. Phys. Lett. 105, 042113 (2014); 10.1063/1.4892079 Electrically active Er doping in InAs, In0

  16. Battery Thermal Modeling and Testing (Presentation)

    SciTech Connect (OSTI)

    Smith, K.

    2011-05-01

    This presentation summarizes NREL battery thermal modeling and testing work for the DOE Annual Merit Review, May 9, 2011.

  17. Thermal Spray Coatings for Coastal Infrastructure

    SciTech Connect (OSTI)

    Holcomb, G.R.; Covino, BernardS. Jr.; Cramer, S.D.; Bullard, S.J.

    1997-11-01

    Several protection strategies for coastal infrastructure using thermal-spray technology are presented from research at the Albany Research Center. Thermal-sprayed zinc coatings for anodes in impressed current cathodic protection systems are used to extend the service lives of reinforced concrete bridges along the Oregon coast. Thermal-sprayed Ti is examined as an alternative to the consumable zinc anode. Sealed thermal-sprayed Al is examined as an alternative coating to zinc dust filled polyurethane paint for steel structures.

  18. Battery Thermal Management System Design Modeling

    SciTech Connect (OSTI)

    Pesaran, A.; Kim, G. H.

    2006-11-01

    Looks at the impact of cooling strategies with air and both direct and indirect liquid cooling for battery thermal management.

  19. THERMALLY ACTIVATED REVERSAL IN MAGNETIC NANOSTRUCTURES

    E-Print Network [OSTI]

    Usadel, K. D.

    THERMALLY ACTIVATED REVERSAL IN MAGNETIC NANOSTRUCTURES ULRICH NOWAK Theoretische Physik, Gerhard to the nanometer scale. With decreasing size of magnetic particles thermal activation becomes rel­ evant an overview on numerical ap­ proaches to thermal activation in magnetic systems as far as they can

  20. Thermal Preference and Tolerance of Alvinellids

    E-Print Network [OSTI]

    Girguis, Peter R.

    Thermal Preference and Tolerance of Alvinellids Peter R. Girguis1 * and Raymond W. Lee2 * T he thermal tolerance of marine animals has been debated for some time (1, 2). At deep-sea hydrothermal vents found that the rapid mixing of hot vent fluids and cold seawater produces a dynamic thermal regime

  1. Thermal Conductivity of Electrons and Muons

    E-Print Network [OSTI]

    Gnedin, Oleg Y.

    Thermal Conductivity of Electrons and Muons in Neutron Star Cores O.Y. Gnedin and D.G. Yakovlev A thermal conductivity of dense matter (ae ? ¸ 10 14 g cm \\Gamma3 ) in neutron star cores with various expressions valid for a wide class of models of dense matter. 1 #12; 1 Introduction Thermal conductivity

  2. NO. REV. NO. APOLLO 12 PSE THERMAL

    E-Print Network [OSTI]

    Rathbun, Julie A.

    : . .'.) NO. REV. NO. ATM 887 APOLLO 12 PSE THERMAL ANOMALY FINAL REPORT PAGE I DATE 5 This ATM summarizes the results of the BxA study conducted to investigate the ALSEP Flight I PSE Thermal Anomaly) determine the most probable cause of the temperature related anomalies, (3) recommend possible thermal

  3. the thermal-8 to-plasma

    E-Print Network [OSTI]

    Vertes, Akos

    Modeling the thermal- 8 to-plasma . transitions for Cu photoablation by A. Vertes R. W. Dreyfus D. E. Platt Excimer laser ablation of metals starts as a thermal process in the -1-J/cm2 fluence range on the thermal (diffusivity and vapor pressure) properties of copper, along with electron heating by inverse

  4. Weak measurement based on thermal noise effect

    E-Print Network [OSTI]

    Gang Li; Tao Wang; Shuang Xu; He-Shan Song

    2015-07-03

    Weak measurement with thermal state pointer can give rise to an amplification effect, and we give the generalization of the mechanism behind the amplification with pure Gaussion state pointer. We find that the maximal value of this effect can reach thermal fluctuations, and propose two schemes to implement room temperature weak measurement with thermal state pointer in optomechanical system.

  5. Thermal Conductivity of Graphene Laminate H. Malekpour,

    E-Print Network [OSTI]

    Thermal Conductivity of Graphene Laminate H. Malekpour, K.-H. Chang, J.-C. Chen, C.-Y. Lu, D. L, Manchester, United Kingdom *S Supporting Information ABSTRACT: We have investigated thermal conductivity and a set of suspended samples with the graphene laminate thickness from 9 to 44 m. The thermal conductivity

  6. Measurements of the Thermal Neutron Scattering Kernel

    E-Print Network [OSTI]

    Danon, Yaron

    Measurements of the Thermal Neutron Scattering Kernel Li (Emily) Liu, Yaron Danon, Bjorn Becker and discussions Problems and Future study Questions #12;3 M. Mattes and J. Keinert, Thermal Neutron Scattering experimental data used was from 1973-1974! M. Mattes and J. Keinert, Thermal Neutron Scattering Data

  7. Thermal Dynamics in General Relativity

    E-Print Network [OSTI]

    C. S. Lopez-Monsalvo; N. Andersson

    2010-06-15

    We discuss a relativistic model for heat conduction, building on a convective variational approach to multi-fluid systems where the entropy is treated as a distinct dynamical entity. We demonstrate how this approach leads to a relativistic version of the Cattaneo equation, encoding the finite thermal relaxation time that is required to satisfy causality. We also show that the model naturally includes the non-equilibrium Gibbs relation that is a key ingredient in most approaches to extended thermodynamics. Focussing on the pure heat conduction problem, we compare the variational results to the second-order model developed by Israel and Stewart. The comparison shows that, despite the very different philosophies behind the two approaches, the two models are equivalent at first order deviations from thermal equilibrium. Finally, we complete the picture by working out the non-relativistic limit of our results, making contact with recent work in that regime.

  8. Microwavable thermal energy storage material

    DOE Patents [OSTI]

    Salyer, I.O.

    1998-09-08

    A microwavable thermal energy storage material is provided which includes a mixture of a phase change material and silica, and a carbon black additive in the form of a conformable dry powder of phase change material/silica/carbon black, or solid pellets, films, fibers, moldings or strands of phase change material/high density polyethylene/ethylene vinyl acetate/silica/carbon black which allows the phase change material to be rapidly heated in a microwave oven. The carbon black additive, which is preferably an electrically conductive carbon black, may be added in low concentrations of from 0.5 to 15% by weight, and may be used to tailor the heating times of the phase change material as desired. The microwavable thermal energy storage material can be used in food serving applications such as tableware items or pizza warmers, and in medical wraps and garments. 3 figs.

  9. Microwavable thermal energy storage material

    DOE Patents [OSTI]

    Salyer, Ival O. (Dayton, OH)

    1998-09-08

    A microwavable thermal energy storage material is provided which includes a mixture of a phase change material and silica, and a carbon black additive in the form of a conformable dry powder of phase change material/silica/carbon black, or solid pellets, films, fibers, moldings or strands of phase change material/high density polyethylene/ethylene-vinyl acetate/silica/carbon black which allows the phase change material to be rapidly heated in a microwave oven. The carbon black additive, which is preferably an electrically conductive carbon black, may be added in low concentrations of from 0.5 to 15% by weight, and may be used to tailor the heating times of the phase change material as desired. The microwavable thermal energy storage material can be used in food serving applications such as tableware items or pizza warmers, and in medical wraps and garments.

  10. Thermal well-test method

    DOE Patents [OSTI]

    Tsang, Chin-Fu (Albany, CA); Doughty, Christine A. (Berkeley, CA)

    1985-01-01

    A well-test method involving injection of hot (or cold) water into a groundwater aquifer, or injecting cold water into a geothermal reservoir. By making temperature measurements at various depths in one or more observation wells, certain properties of the aquifer are determined. These properties, not obtainable from conventional well test procedures, include the permeability anisotropy, and layering in the aquifer, and in-situ thermal properties. The temperature measurements at various depths are obtained from thermistors mounted in the observation wells.

  11. Medical Actinium Therapeutic Treatment

    ScienceCinema (OSTI)

    None

    2013-05-28

    Learn how INL researchers are increasing world supplies of Bismuth 213 to help with cancer treatments. For more information about INL research projects, visit http://www.facebook.com/idahonationallaboratory.

  12. Harvesting thermal fluctuations: Activation process induced by a nonlinear chain in thermal equilibrium

    E-Print Network [OSTI]

    Galán, Antonio Sarmiento

    Harvesting thermal fluctuations: Activation process induced by a nonlinear chain in thermal of a bistable system is a molecular chain which in turn is connected to a thermal environment of the Langevin. The distribution, intensity, and mobility of thermal fluctuations in these chains is strongly dependent

  13. Thermal challenges in MEMS applications: phase change phenomena and thermal bonding processes

    E-Print Network [OSTI]

    Lin, Liwei

    Thermal challenges in MEMS applications: phase change phenomena and thermal bonding processes Liwei, MC 1740, Berkeley, CA 94720, USA Abstract Two thermal challenges for current and next generation generate single, spherical and controllable thermal bubbles with diameters between 2 and 500 mm. Both

  14. J. of Thermal Science Vol.2, No4. Journal of Thermal Science Science Press 1993 ~

    E-Print Network [OSTI]

    Zhang, Yuwen

    J. of Thermal Science Vol.2, No4. Journal of Thermal Science· Science Press 1993 ~ Flow P atterns and Thermal Drag in a One-Dimen- sional Inviscid Channel wit h Heating or Cooling Yuwen Zhang Yonglin Ju investigations on the fl.ow patterns and the thermal drag phenomenon in one-dimensional inviscid channel fiow

  15. Odne Stokke Burheim Thermal Signature and Thermal Conductivities of PEM Fuel Cells

    E-Print Network [OSTI]

    Kjelstrup, Signe

    Odne Stokke Burheim Thermal Signature and Thermal Conductivities of PEM Fuel Cells Thesis-Holst for believing in me and for giving me the opportunity to join the work on the "Thermal Effects in Fuel cell The work presented here gives estimates on thermal gradients within the PEM fuel cell, an experimental

  16. The effect of thermal aging on the thermal conductivity of plasma sprayed and EB-PVD thermal barrier coatings

    SciTech Connect (OSTI)

    Dinwiddie, R.B.; Beecher, S.C.; Porter, W.D.; Nagaraj, B.A.

    1996-05-01

    Thermal barrier coatings (TBCs) applied to the hot gas components of turbine engines lead to enhanced fuel efficiency and component reliability. Understanding the mechanisms which control the thermal transport behavior of the TBCs is of primary importance. Electron beam-physical vapor deposition (EV-PVD) and air plasma spraying (APS) are the two most commonly used coating techniques. These techniques produce coatings with unique microstructures which control their performance and stability. The density of the APS coatings was controlled by varying the spray parameters. The low density APS yttria-partially stabilized zirconia (yttria-PSZ) coatings yielded a thermal conductivity that is lower than both the high density APS coatings and the EB-PVD coatings. The thermal aging of both fully and partially stabilized zirconia are compared. The thermal conductivity of the coatings permanently increases upon exposure to high temperatures. These increases are attributed to microstructural changes within the coatings. This increase in thermal conductivity can be modeled using a relationship which depends on both the temperature and time of exposure. Although the EB-PVD coatings are less susceptible to thermal aging effects, results suggest that they typically have a higher thermal conductivity than APS coatings before thermal aging. The increases in thermal conductivity due to thermal aging for plasma sprayed partially stabilized zirconia have been found to be less than for plasma sprayed fully stabilized zirconia coatings.

  17. Thermality of the Hawking flux

    E-Print Network [OSTI]

    Matt Visser

    2015-05-06

    Is the Hawking flux "thermal"? Unfortunately, the answer to this seemingly innocent question depends on a number of often unstated, but quite crucial, technical assumptions built into modern (mis-)interpretations of the word "thermal". The original 1850's notions of thermality --- based on classical thermodynamic reasoning applied to idealized "black bodies" or "lamp black surfaces" --- when supplemented by specific basic quantum ideas from the early 1900's, immediately led to the notion of the black-body spectrum, (the Planck-shaped spectrum), but "without" any specific assumptions or conclusions regarding correlations between the quanta. Many (not all) modern authors (often implicitly and unintentionally) add an extra, and quite unnecessary, assumption that there are no correlations in the black-body radiation; but such usage is profoundly ahistorical and dangerously misleading. Specifically, the Hawking flux from an evaporating black hole, (just like the radiation flux from a leaky furnace or a burning lump of coal), is only "approximately" Planck-shaped over a bounded frequency range. Standard physics (phase space and adiabaticity effects) explicitly bound the frequency range over which the Hawking flux is "approximately" Planck-shaped from both above and below --- the Hawking flux is certainly not exactly Planckian, and there is no compelling physics reason to assume the Hawking photons are uncorrelated.

  18. Thermal Stability Of Formohydroxamic Acid

    SciTech Connect (OSTI)

    Fondeur, F. F.; Rudisill, T. S.

    2011-10-21

    The thermal stability of formohydroxamic acid (FHA) was evaluated to address the potential for exothermic decomposition during storage and its use in the uranium extraction process. Accelerating rate calorimetry showed rapid decomposition at a temperature above 65 {degree}?C; although, the rate of pressure rise was greater than two orders of magnitude less than the lower bound for materials which have no explosive properties with respect to transportation. FHA solutions in water and nitric acid did not reach runaway conditions until 150 {degree}?C. Analysis by differential scanning calorimetry showed that FHA melted at 67 {degree}?C and thermally decomposed at 90 {degree}?C with an enthalpy of -1924 J/g. The energics of the FHA thermal decomposition are comparable to those measured for aqueous solutions of hydroxylamine nitrate. Solid FHA should be stored in a location where the temperature does not exceed 20-25 {degree}?C. As a best practice, the solid material should be stored in a climate-controlled environment such as a refrigerator or freezer. FHA solutions in water are not susceptible to degradation by acid hydrolysis and are the preferred way to handle FHA prior to use.

  19. Pillar Structured Thermal Neutron Detector

    SciTech Connect (OSTI)

    Nikolic, R; Conway, A; Reinhardt, C; Graff, R; Wang, T; Deo, N; Cheung, C

    2008-06-10

    This work describes an innovative solid state device structure that leverages advanced semiconductor fabrication technology to produce an efficient device for thermal neutron detection which we have coined the 'Pillar Detector'. State-of-the-art thermal neutron detectors have shortcomings in simultaneously achieving high efficiency, low operating voltage while maintaining adequate fieldability performance. By using a three dimensional silicon PIN diode pillar array filled with isotopic {sup 10}boron ({sup 10}B), a high efficiency device is theoretically possible. Here we review the design considerations for going from a 2-D to 3-D device and discuss the materials trade-offs. The relationship between the geometrical features and efficiency within our 3-D device is investigated by Monte Carlo radiation transport method coupled with finite element drift-diffusion carrier transport simulations. To benchmark our simulations and validate the predicted efficiency scaling, experimental results of a prototype device are illustrated. The fabricated pillar structures reported in this work are composed of 2 {micro}m diameter silicon pillars with a 2 {micro}m spacing and pillar height of 12 {micro}m. The pillar detector with a 12 {micro}m height achieved a thermal neutron detection efficiency of 7.3% at a reverse bias of -2 V.

  20. Portable treatment systems study

    SciTech Connect (OSTI)

    Sherick, M.J.; Schwinkendorf, W.E.; Bechtold, T.E.; Cole, L.T.

    1997-03-01

    In developing their Site Treatment Plans (STPs), many of the Department of Energy installations identified some form of portable treatment, to facilitate compliant disposition of select mixed low-level wastestreams. The Environmental Management Office of Science and Technology requested that a systems study be performed to better define the potential role of portable treatment with respect to mixed low-level waste, highlight obstacles to implementation, and identify opportunities for future research and development emphasis. The study was performed by first establishing a representative set of mixed waste, then formulating portable treatment system concepts to meet the required processing needs for these wastes. The portable systems that were conceptualized were evaluated and compared to a fixed centralized treatment alternative. The system evaluations include a life-cycle cost analysis and an assessment of regulatory, institutional, and technical issues associated with the potential use of portable systems. The results of this study show that when all costs are included, there are no significant cost differences between portable systems and fixed systems. However, it is also emphasized that many uncertainties exist that could impact the cost of implementing portable treatment systems. Portable treatment could be made more attractive through private sector implementation, although there is little economic incentive for a commercial vendor to develop small, specialized treatment capabilities with limited applicability. Alternatively, there may also be valid reasons why fixed units cannot be used for some problematic wastestreams. In any event, there are some site-specific problems that still need to be addressed, and there may be some opportunity for research and development to make a positive impact in these areas.