National Library of Energy BETA

Sample records for melt zones beneath

  1. A Low-Velocity Zone in the Basement Beneath the Valles Caldera...

    Open Energy Info (EERE)

    Zone in the Basement Beneath the Valles Caldera, New Mexico Abstract We present quantitative results of forward modeling applied to a suite of travel time delays observed...

  2. Melt zones beneath five volcanic complexes in California: an...

    Open Energy Info (EERE)

    Bridge. Related Geothermal Exploration Activities Activities (4) Geothermal Literature Review At Coso Geothermal Area (1984) Geothermal Literature Review At Geysers...

  3. Melt Zones Beneath Five Volcanic Complexes in California: An...

    Open Energy Info (EERE)

    No.: LBL-18232. Related Geothermal Exploration Activities Activities (1) Geothermal Literature Review At Long Valley Caldera Geothermal Area (Goldstein & Flexser, 1984) Areas (1)...

  4. A comprehensive analysis of contaminant transport in the vadose zone beneath tank SX-109

    SciTech Connect (OSTI)

    Ward, A.L.; Gee, G.W.; White, M.D.

    1997-02-01

    The Vadose Zone Characterization Project is currently investigating the subsurface distribution of gamma-emitting radionuclides in S and SX Waste Management Area (WMA-S-SX) located in the 200 West Area of the US Department of Energy`s Hanford Site in southeastern Washington State. Spectral-gamma logging of boreholes has detected elevated {sup 137}Cs concentrations as deep as 38 m, a depth considered excessive based on the assumed geochemistry of {sup 137}Cs in Hanford sediments. Routine groundwater sampling under the Resource Conservation and Recovery Act (RCRA) have also detected elevated levels of site-specific contaminants downgradient of WMA-S-SX. The objective of this report is to explore the processes controlling the migration of {sup 137}Cs, {sup 99}Tc, and NO{sub 3} through the vadose zone of WMA-S-SX, particularly beneath tank SX-109.

  5. Preliminary results of characteristic seismic anisotropy beneath Sunda-Banda subduction-collision zone

    SciTech Connect (OSTI)

    Wiyono, Samsul H.; Nugraha, Andri Dian

    2015-04-24

    Determining of seismic anisotropy allowed us for understanding the deformation processes that occured in the past and present. In this study, we performed shear wave splitting to characterize seismic anisotropy beneath Sunda-Banda subduction-collision zone. For about 1,610 XKS waveforms from INATEWS-BMKG networks have been analyzed. From its measurements showed that fast polarization direction is consistent with trench-perpendicular orientation but several stations presented different orientation. We also compared between fast polarization direction with absolute plate motion in the no net rotation and hotspot frame. Its result showed that both absolute plate motion frame had strong correlation with fast polarization direction. Strong correlation between the fast polarization direction and the absolute plate motion can be interpreted as the possibility of dominant anisotropy is in the asthenosphere.

  6. Vertical zone melt growth of GaAs

    SciTech Connect (OSTI)

    Henry, R.L.; Nordquist, P.E.R.; Gorman, R.J.

    1993-12-31

    A Vertical Zone Melt (VZM) technique has been applied to the single crystal growth of GaAs. A pyrolytic boron nitride crucible and a (100) oriented seed were used along with liquid encapsulation by boric oxide. In the case of GaAs, the ampoule was pressurized with either argon or argensic vapor from elemental arsenic at pressures ranging from 1 to 2 atmospheres. A molten zone length of 22 mm gave a growth interface which is nearly flat and resulted in routine single crystal growth. Temperature gradients of 4{degrees}C/cm. and 9{degrees}C/cm. have produced dislocation densities of <1000/cm{sup 2} and 2000-5000/cm{sup 2} respectively for 34 mm diameter crystals of GaAs. Post growth cooling rates for GaAs have been 35, 160 and 500{degrees}C/hr. The cooling rate has been found to affect the number and size of arsenic precipitates and the EL2 concentration in the GaAs crystal. The effects of these and other growth parameters on the crystalline perfection and electrical properties of the crystals will be discussed.

  7. Crustal structure beneath two seismic stations in the Sunda-Banda arc transition zone derived from receiver function analysis

    SciTech Connect (OSTI)

    Syuhada; Hananto, Nugroho D.; Handayani, Lina; Puspito, Nanang T; Yudistira, Tedi; Anggono, Titi

    2015-04-24

    We analyzed receiver functions to estimate the crustal thickness and velocity structure beneath two stations of Geofon (GE) network in the Sunda-Banda arc transition zone. The stations are located in two different tectonic regimes: Sumbawa Island (station PLAI) and Timor Island (station SOEI) representing the oceanic and continental characters, respectively. We analyzed teleseismic events of 80 earthquakes to calculate the receiver functions using the time-domain iterative deconvolution technique. We employed 2D grid search (H-κ) algorithm based on the Moho interaction phases to estimate crustal thickness and Vp/Vs ratio. We also derived the S-wave velocity variation with depth beneath both stations by inverting the receiver functions. We obtained that beneath station PLAI the crustal thickness is about 27.8 km with Vp/Vs ratio 2.01. As station SOEI is covered by very thick low-velocity sediment causing unstable solution for the inversion, we modified the initial velocity model by adding the sediment thickness estimated using high frequency content of receiver functions in H-κ stacking process. We obtained the crustal thickness is about 37 km with VP/Vs ratio 2.2 beneath station SOEI. We suggest that the high Vp/Vs in station PLAI may indicate the presence of fluid ascending from the subducted plate to the volcanic arc, whereas the high Vp/Vs in station SOEI could be due to the presence of sediment and rich mafic composition in the upper crust and possibly related to the serpentinization process in the lower crust. We also suggest that the difference in velocity models and crustal thicknesses between stations PLAI and SOEI are consistent with their contrasting tectonic environments.

  8. Probing the deep critical zone beneath the Luquillo Experimental Forest, Puerto Rico

    SciTech Connect (OSTI)

    Buss, Heather; Brantley, S. L.; Scatena, Fred; Bazilevskaya, Ekaterina; Blum, Alex; Schulz, M; Jimenez, M; White, Art; Rother, Gernot; Cole, David

    2013-01-01

    Recent work has suggested that weathering processes occurring in the subsurface produce the majority of silicate weathering products discharged to the world s oceans, thereby exerting a primary control on global temperature via the well-known positive feedback between silicate weathering and CO2. In addition, chemical and physical weathering processes deep within the critical zone create aquifers and control groundwater chemistry, watershed geometry and regolith formation rates. Despite this, most weathering studies are restricted to the shallow critical zone (e.g., soils, outcrops). Here we investigate the chemical weathering, fracturing and geomorphology of the deep critical zone in the Bisley watershed in the Luquillo Critical Zone Observatory, Puerto Rico, from two boreholes drilled to 37.2 and 27.0 m depth, from which continuous core samples were taken. Corestones exposed aboveground were also sampled. Weathered rinds developed on exposed corestones and along fracture surfaces on subsurface rocks slough off of exposed corestones once rinds attain a thickness up to ~1 cm, preventing the corestones from rounding due to diffusion limitation. Such corestones at the land surface are assumed to be what remains after exhumation of similar, fractured bedrock pieces that were observed in the drilled cores between thick layers of regolith. Some of these subsurface corestones are massive and others are highly fractured, whereas aboveground corestones are generally massive with little to no apparent fracturing. Subsurface corestones are larger and less fractured in the borehole drilled on a road where it crosses a ridge compared to the borehole drilled where the road crosses the stream channel. Both borehole profiles indicate that the weathering zone extends to well below the stream channel in this upland catchment; hence weathering depth is not controlled by the stream level within the catchment and not all of the water in the watershed is discharged to the stream.

  9. Microstructure formation in partially melted zone during gas tungsten arc welding of AZ91 Mg cast alloy

    SciTech Connect (OSTI)

    Zhu Tianping Chen, Zhan W.; Gao Wei

    2008-11-15

    During gas tungsten arc (GTA) welding of AZ91 Mg cast alloy, constitutional liquid forms locally in the original interdendritic regions in the partially melted zone (PMZ). The PMZ re-solidification behaviour has not been well understood. In this study, the gradual change of the re-solidification microstructure within PMZ from base metal side to weld metal side was characterised. High cooling rate experiments using Gleeble thermal simulator were also conducted to understand the morphological change of the {alpha}-Mg/{beta}-Mg{sub 17}Al{sub 12} phase interface formed during re-solidification after partial melting. It was found that the original partially divorced eutectic structure has become a more regular eutectic phase in most of the PMZ, although close to the fusion boundary the re-solidified eutectic is again a divorced one. Proceeding the eutectic re-solidification, if the degree of partial melting is sufficiently high, {alpha}-Mg re-solidified with a cellular growth, resulting in a serrated interface between {alpha}-Mg and {alpha}-Mg/{beta}-Mg{sub 17}Al{sub 12} in the weld sample and between {alpha}-Mg and {beta}-Mg{sub 17}Al{sub 12} (fully divorced eutectic) in Gleeble samples. The morphological changes affected by the peak temperature and cooling rate are also explained.

  10. Laser powder-bed fusion additive manufacturing: Physics of complex melt flow and formation mechanisms of pores, spatter, and denudation zones

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Khairallah, Saad A.; Anderson, Andrew T.; Rubenchik, Alexander; King, Wayne E.

    2016-02-23

    Our study demonstrates the significant effect of the recoil pressure and Marangoni convection in laser powder bed fusion (L-PBF) of 316L stainless steel. A three-dimensional high fidelity powder-scale model reveals how the strong dynamical melt flow generates pore defects, material spattering (sparking), and denudation zones. The melt track is divided into three sections: a topological depression, a transition and a tail region, each being the location of specific physical effects. The inclusion of laser ray-tracing energy deposition in the powder-scale model improves over traditional volumetric energy deposition. It enables partial particle melting, which impacts pore defects in the denudation zone.more » Different pore formation mechanisms are observed at the edge of a scan track, at the melt pool bottom (during collapse of the pool depression), and at the end of the melt track (during laser power ramp down). Finally, we discuss remedies to these undesirable pores are discussed. The results are validated against the experiments and the sensitivity to laser absorptivity.« less

  11. Perched-Water Evaluation for the Deep Vadose Zone Beneath the B, BX, and BY Tank Farms Area of the Hanford Site

    SciTech Connect (OSTI)

    Truex, Michael J.; Oostrom, Martinus; Carroll, KC; Chronister, Glen B.

    2013-06-28

    Perched-water conditions have been observed in the vadose zone above a fine-grained zone that is located a few meters above the water table within the B, BX, and BY Tank Farms area. The perched water contains elevated concentrations of uranium and technetium-99. This perched-water zone is important to consider in evaluating the future flux of contaminated water into the groundwater. The study described in this report was conducted to examine the perched-water conditions and quantitatively evaluate 1) factors that control perching behavior, 2) contaminant flux toward groundwater, and 3) associated groundwater impact.

  12. Aeromagnetic anomalies and discordant lineations beneath the Niger Delta: Implications for new fracture zones and multiple sea-floor spreading directions in the meso-Atlantic' Gulf of Guinea cul-de-sac

    SciTech Connect (OSTI)

    Babalola, O.O.; Gipson, M. Jr. )

    1991-06-01

    An aeromagnetic contour map compiled over shallow water and onshore portions of the Nigerian continental margin, shows several elongate, long-wavelength anomaly closures with some alternating polarity, separated by steep gradient, NE lineations. The lineations are interpreted as new fracture zones or extensions of previously mapped ones. The NE trend in the western delta region is concordant with the fracture zone trends of the deeper Gulf of Guinea. Aeromagnetic lineations of the SE Niger Delta Basin however, discordantly trend ENE. Their termination against the former, is interpreted as evidence of early sea-floor spreading in a ENE-WSW direction in addition to the well documented NE-SW spreading of the Gulf of Guinea and the rest of the meso-Atlantic sea-floor; The geophysical crustal structure indicate the existence of two Early Cretaceous triple junctions beneath the Niger Delta Basin. The two triple-junctions further support the hypothesis that the African continent was a multi-plate system (in the Niger Delta region) during the early opening of the Atlantic.

  13. Capillary Break Beneath a Slab: Polyethylene Sheeting over Aggregate, Southwestern Pennsylvania (Fact Sheet), Building America Case Study: Technology Solutions for New and Existing Homes, Building Technologies Office (BTO)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Capillary Break Beneath a Slab: Polyethylene Sheeting Over Aggregate Southwestern Pennsylvania PROJECT INFORMATION Project Name: Capillary Break Beneath a Slab: Polyethylene Sheeting Over Aggregate Location: Southwestern PA Type: Residential Partners: Builder is confidential Building America Team: IBACOS, www.ibacos.com Building Component: Foundation, water management Application: New construction; single- and multifamily homes Year Tested: 2013 Applicable Climate Zone(s): All except dry

  14. Vitrification of waste with conitnuous filling and sequential melting

    DOE Patents [OSTI]

    Powell, James R.; Reich, Morris

    2001-09-04

    A method of filling a canister with vitrified waste starting with a waste, such as high-level radioactive waste, that is cooler than its melting point. Waste is added incrementally to a canister forming a column of waste capable of being separated into an upper zone and a lower zone. The minimum height of the column is defined such that the waste in the lower zone can be dried and melted while maintaining the waste in the upper zone below its melting point. The maximum height of the column is such that the upper zone remains porous enough to permit evolved gases from the lower zone to flow through the upper zone and out of the canister. Heat is applied to the waste in the lower zone to first dry then to raise and maintain its temperature to a target temperature above the melting point of the waste. Then the heat is applied to a new lower zone above the melted waste and the process of adding, drying and melting the waste continues upward in the canister until the entire canister is filled and the entire contents are melted and maintained at the target temperature for the desired period. Cooling of the melted waste takes place incrementally from the bottom of the canister to the top, or across the entire canister surface area, forming a vitrified product.

  15. A Preparation Zone For Volcanic Explosions Beneath Naka-Dake...

    Open Energy Info (EERE)

    activity including a decrease in the level of the lake water, mud eruptions, and red hot glows on the crater wall. Temporal variations in the geomagnetic field observed...

  16. Multiple plates subducting beneath Colombia, as illuminated by seismicity and velocity from the joint inversion of seismic and gravity data

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Syracuse, Ellen M.; Maceira, Monica; Prieto, German A.; Zhang, Haijiang; Ammon, Charles J.

    2016-04-12

    Subduction beneath the northernmost Andes in Colombia is complex. Based on seismicity distributions, multiple segments of slab appear to be subducting, and arc volcanism ceases north of 5° N. Here, we illuminate the subduction system through hypocentral relocations and Vp and Vs models resulting from the joint inversion of local body wave arrivals, surface wave dispersion measurements, and gravity data. The simultaneous use of multiple data types takes advantage of the differing sensitivities of each data type, resulting in velocity models that have improved resolution at both shallower and deeper depths than would result from traditional travel time tomography alone.more » The relocated earthquake dataset and velocity model clearly indicate a tear in the Nazca slab at 5° N, corresponding to a 250-km shift in slab seismicity and the termination of arc volcanism. North of this tear, the slab is flat, and it comprises slabs of two sources: the Nazca and Caribbean plates. The Bucaramanga nest, a small region of among the most intense intermediate-depth seismicity globally, is associated with the boundary between these two plates and possibly with a zone of melting or elevated water content, based on reduced Vp and increased Vp/Vs. As a result, we also use relocated seismicity to identify two new faults in the South American plate, one related to plate convergence and one highlighted by induced seismicity.« less

  17. ARM - What About Melting Polar Ice Caps and Sea Levels?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    What About Melting Polar Ice Caps and Sea Levels? Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans What About Melting Polar Ice Caps and Sea Levels? As the northern polar zone warms up, sea ice could melt (very probable) and the sea/ice interface could retreat to the north. This is likely to

  18. Melt containment member

    DOE Patents [OSTI]

    Rieken, Joel R.; Heidloff, Andrew J.

    2014-09-09

    A tubular melt containment member for transient containment of molten metals and alloys, especially reactive metals and alloys, includes a melt-contacting layer or region that comprises an oxygen-deficient rare earth oxide material that is less reactive as compared to the counterpart stoichiometric rare earth oxide. The oxygen-deficient (sub-stoichiometric) rare earth oxide can comprise oxygen-deficient yttria represented by Y.sub.2O.sub.3-x wherein x is from 0.01 to 0.1. Use of the oxygen-deficient rare earth oxide as the melt-contacting layer or region material reduces reaction with the melt for a given melt temperature and melt contact time.

  19. Grenville foreland thrust belt hidden beneath the eastern US midcontinent

    SciTech Connect (OSTI)

    Hauser, E.C. (Cornell Univ., Ithaca, NY (United States))

    1993-01-01

    Grenville foreland thrust structures are observed beneath the eastern US midcontinent on COCORP (Consortium for Continental Reflection Profiling) line OH-1 and a short seismic line in southwest Ohio. These structures represent the first evidence for a significant Grenville foreland thrust belt preserved in eastern North America. On the COCORP lines, the structures include a thrust ramp anticline and an associated asymmetric syncline. The Grenville front tectonic zone appears to truncate these foreland structures, indicating a later, second phase expressed as a deeply penetrating, out-of-sequence thrust zone associated with the main uplift of the Grenville province on the east. A short, shallow seismic line in southwestern Ohio reveals an east-dipping sequence of prominently layered rocks that may lie above a footwall ramp to a deeper Grenville thrust fault. A drill hole into the less reflective top of this dipping sequence encountered unmetamorphosed sedimentary rocks like those increasingly reported from other drill holes in southwestern Ohio and adjacent states. Although possibly part of a late Precambrian (Keweenawan ) rift, these clastic sedimentary rocks may instead preserve evidence of a heretofore unrecognized Grenville foreland basin in eastern North America. Alternatively these Precambrian sedimentary rocks together with an underlying, but yet undrilled, strongly layered sequence may correlate with similarly layered rocks observed on COCORP and industrial seismic lines within the Middle Proterozoic granite-rhyolite province to the west in Indiana and Illinois and indicate that unmetamorphosed sedimentary material is an important constituent of the granite-rhyolite province. 25 refs., 6 figs.

  20. Evidence for long-lived subduction of an ancient tectonic plate beneath the southern Indian Ocean

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Simmons, N. A.; Myers, S. C.; Johannesson, G.; Matzel, E.; Grand, S. P.

    2015-11-14

    In this study, ancient subducted tectonic plates have been observed in past seismic images of the mantle beneath North America and Eurasia, and it is likely that other ancient slab structures have remained largely hidden, particularly in the seismic-data-limited regions beneath the vast oceans in the Southern Hemisphere. Here we present a new global tomographic image, which shows a slab-like structure beneath the southern Indian Ocean with coherency from the upper mantle to the core-mantle boundary region—a feature that has never been identified. We postulate that the structure is an ancient tectonic plate that sank into the mantle along anmore » extensive intraoceanic subduction zone that migrated southwestward across the ancient Tethys Ocean in the Mesozoic Era. Slab material still trapped in the transition zone is positioned near the edge of East Gondwana at 140 Ma suggesting that subduction terminated near the margin of the ancient continent prior to breakup and subsequent dispersal of its subcontinents.« less

  1. Evidence for long-lived subduction of an ancient tectonic plate beneath the southern Indian Ocean

    SciTech Connect (OSTI)

    Simmons, N. A.; Myers, S. C.; Johannesson, G.; Matzel, E.; Grand, S. P.

    2015-11-14

    In this study, ancient subducted tectonic plates have been observed in past seismic images of the mantle beneath North America and Eurasia, and it is likely that other ancient slab structures have remained largely hidden, particularly in the seismic-data-limited regions beneath the vast oceans in the Southern Hemisphere. Here we present a new global tomographic image, which shows a slab-like structure beneath the southern Indian Ocean with coherency from the upper mantle to the core-mantle boundary region—a feature that has never been identified. We postulate that the structure is an ancient tectonic plate that sank into the mantle along an extensive intraoceanic subduction zone that migrated southwestward across the ancient Tethys Ocean in the Mesozoic Era. Slab material still trapped in the transition zone is positioned near the edge of East Gondwana at 140 Ma suggesting that subduction terminated near the margin of the ancient continent prior to breakup and subsequent dispersal of its subcontinents.

  2. Analysis of Picosecond Pulsed Laser Melted Graphite

    DOE R&D Accomplishments [OSTI]

    Steinbeck, J.; Braunstein, G.; Speck, J.; Dresselhaus, M. S.; Huang, C. Y.; Malvezzi, A. M.; Bloembergen, N.

    1986-12-01

    A Raman microprobe and high resolution TEM have been used to analyze the resolidified region of liquid carbon generated by picosecond pulse laser radiation. From the relative intensities of the zone center Raman-allowed mode for graphite at 1582 cm{sup -1} and the disorder-induced mode at 1360 cm{sup -1}, the average graphite crystallite size in the resolidified region is determined as a function of position. By comparison with Rutherford backscattering spectra and Raman spectra from nanosecond pulsed laser melting experiments, the disorder depth for picosecond pulsed laser melted graphite is determined as a function of irradiating energy density. Comparisons of TEM micrographs for nanosecond and picosecond pulsed laser melting experiments show that the structure of the laser disordered regions in graphite are similar and exhibit similar behavior with increasing laser pulse fluence.

  3. Energy Saving Melting and Revert Reduction Technology: Melting...

    Office of Scientific and Technical Information (OSTI)

    Consequently, die casters need to make careful choices in selecting and operating melting equipment and procedures. The capital cost of new melting equipment with higher efficiency ...

  4. Improved MK42 Melting Model

    SciTech Connect (OSTI)

    Tudor, A.A.

    2001-09-19

    An improved Mark 42 melting model has been defined for establishing confinement protection limits (CPLs). This report describes the new melting model and its application in computing CPLs.

  5. Evidence For Gas And Magmatic Sources Beneath The Yellowstone...

    Open Energy Info (EERE)

    of magma beneath the Yellowstone caldera. Authors Stephan Husen, Robert B. Smith and Gregory P. Waite Published Journal Journal of Volcanology and Geothermal Research,...

  6. Anomalous shear wave attenuation in the shallow crust beneath...

    Open Energy Info (EERE)

    volcanic region, California Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Anomalous shear wave attenuation in the shallow crust beneath the...

  7. Inferences On The Hydrothermal System Beneath The Resurgent Dome...

    Open Energy Info (EERE)

    Inferences On The Hydrothermal System Beneath The Resurgent Dome In Long Valley Caldera, East-Central California, USA, From Recent Pumping Tests And Geochemical Sampling Jump to:...

  8. Technology Solutions Case Study: Capillary Break Beneath a Slab: Polyethylene Sheeting over Aggregate, Southwestern Pennsylvania

    SciTech Connect (OSTI)

    2014-07-01

    In this project, Building America team IBACOS worked with a builder of single- and multifamily homes in southwestern Pennsylvania (climate zone 5) to understand its methods of successfully using polyethylene sheeting over aggregate as a capillary break beneath the slab in new construction. This builder’s homes vary in terms of whether they have crawlspaces or basements. However, in both cases, the strategy protects the home from water intrusion via capillary action (e.g., water wicking into cracks and spaces in the slab), thereby helping to preserve the durability of the home.

  9. Preliminary result of P-wave speed tomography beneath North Sumatera region

    SciTech Connect (OSTI)

    Jatnika, Jajat; Nugraha, Andri Dian; Wandono

    2015-04-24

    The structure of P-wave speed beneath the North Sumatra region was determined using P-wave arrival times compiled by MCGA from time periods of January 2009 to December 2012 combining with PASSCAL data for February to May 1995. In total, there are 2,246 local earthquake events with 10,666 P-wave phases from 63 stations seismic around the study area. Ray tracing to estimate travel time from source to receiver in this study by applying pseudo-bending method while the damped LSQR method was used for the tomographic inversion. Based on assessment of ray coverage, earthquakes and stations distribution, horizontal grid nodes was set up of 3030 km2 for inside the study area and 8080 km2 for outside the study area. The tomographic inversion results show low Vp anomaly beneath Toba caldera complex region and around the Sumatra Fault Zones (SFZ). These features are consistent with previous study. The low Vp anomaly beneath Toba caldera complex are observed around Mt. Pusuk Bukit at depths of 5?km down to 100?km. The interpretation is these anomalies may be associated with ascending hot materials from subduction processes at depths of 80?km down to 100?km. The obtained Vp structure from local tomography will give valuable information to enhance understanding of tectonic and volcanic in this study area.

  10. Laser thermoelastic generation in metals above the melt threshold

    SciTech Connect (OSTI)

    Every, A. G.; Utegulov, Z. N.; Veres, I. A.

    2013-11-28

    An approach is presented for calculating thermoelastic generation of ultrasound in a metal plate exposed to nanosecond pulsed laser heating, sufficient to cause melting but not ablation. Detailed consideration is given to the spatial and temporal profiles of the laser pulse, penetration of the laser beam into the sample, the appearance and subsequent growth and then contraction of the melt pool, and the time dependent thermal conduction in the melt and surrounding solid throughout. The excitation of the ultrasound takes place during and shortly after the laser pulse and occurs predominantly within the thermal diffusion length of a micron or so beneath the surface. It is shown how, because of this, the output of the thermal simulations can be expressed as axially symmetric transient radial and normal surface force distributions. The epicentral displacement response to these force distributions is obtained by two methods, the one based on the elastodynamic Green's functions for plate geometry determined by the Cagniard generalized ray method and the other using a finite element numerical method. The two approaches are in very close agreement. Numerical simulations are reported on the epicentral displacement response of a 3.12 mm thick tungsten plate irradiated with a 4 ns pulsed laser beam with Gaussian spatial profile, at intensities below and above the melt threshold.

  11. Climate Zones

    Broader source: Energy.gov [DOE]

    Building America determines building practices based on climate zones to achieve the most energy savings in a home. This page offers some general guidelines on the definitions of the various...

  12. Isothermal Melting | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    New Energy-Efficient Melting Process Saves Energy and Reduces Production Losses Aluminum ... thermal, and mechanical robustness required in an industrial molten aluminum environment. ...

  13. Crust and Upper Mantle P Wave Velocity Structure Beneath Valles...

    Open Energy Info (EERE)

    by mantle-derived melts has occurred. Authors Lee K. Steck, Clifford H. Thurber, Michael C. Fehler, William J. Lutter, Peter M. Roberts, W. Scott Baldridge, Darrik G....

  14. Geochemical Processes Data Package for the Vadose Zone in the Single-Shell Tank Waste Management Areas at the Hanford Site

    SciTech Connect (OSTI)

    Cantrell, Kirk J.; Zachara, John M.; Dresel, P. Evan; Krupka, Kenneth M.; Serne, R. Jeffrey

    2007-09-28

    This data package discusses the geochemistry of vadose zone sediments beneath the single-shell tank farms at the U.S. Department of Energy’s (DOE’s) Hanford Site. The purpose of the report is to provide a review of the most recent and relevant geochemical process information available for the vadose zone beneath the single-shell tank farms and the Integrated Disposal Facility. Two companion reports to this one were recently published which discuss the geology of the farms (Reidel and Chamness 2007) and groundwater flow and contamination beneath the farms (Horton 2007).

  15. What lies beneath the Cerro Prieto geothermal field?

    SciTech Connect (OSTI)

    Elders, W.A.; Williams, A.E.; Biehler, S.

    1997-12-31

    Although the Cerro Prieto geothermal reservoir is one of the world`s largest geothermal developments, conflicting ideas persist about the basement beneath it. The current plan to drill a 6 km deep exploratory well in the eastern part of the field has brought this controversy into sharper focus. This paper discusses criteria which any model of what lies beneath the reservoir must meet, in terms of regional tectonics and geophysics, of the metamorphic and igneous rocks thus far encountered in drilling, and of models of possible heat sources and coupling between the hydrothermal and magmatic systems. Our analysis confirms the interpretation that the crystalline basement beneath the sediments, rather than being granitic, is oceanic in character, resembling an ophiolite complex. The heat source is most likely a cooling gabbroic intrusion, several kilometers in diameter, overlain by a sheeted dike swarm. A 6 km deep bore-hole centered over such an intrusion would not only be one of the world`s deepest geothermal wells but could also be one of the hottest.

  16. High gain photoconductive semiconductor switch having tailored doping profile zones

    DOE Patents [OSTI]

    Baca, Albert G.; Loubriel, Guillermo M.; Mar, Alan; Zutavern, Fred J; Hjalmarson, Harold P.; Allerman, Andrew A.; Zipperian, Thomas E.; O'Malley, Martin W.; Helgeson, Wesley D.; Denison, Gary J.; Brown, Darwin J.; Sullivan, Charles T.; Hou, Hong Q.

    2001-01-01

    A photoconductive semiconductor switch with tailored doping profile zones beneath and extending laterally from the electrical contacts to the device. The zones are of sufficient depth and lateral extent to isolate the contacts from damage caused by the high current filaments that are created in the device when it is turned on. The zones may be formed by etching depressions into the substrate, then conducting epitaxial regrowth in the depressions with material of the desired doping profile. They may be formed by surface epitaxy. They may also be formed by deep diffusion processes. The zones act to reduce the energy density at the contacts by suppressing collective impact ionization and formation of filaments near the contact and by reducing current intensity at the contact through enhanced current spreading within the zones.

  17. Pulsed laser generation of ultrasound in a metal plate between the melting and ablation thresholds

    SciTech Connect (OSTI)

    Every, A. G.; Utegulov, Z. N.; Veres, I. A.

    2015-03-31

    The generation of ultrasound in a metal plate exposed to nanosecond pulsed laser heating, sufficient to cause melting but not ablation, is treated. Consideration is given to the spatial and temporal profiles of the laser pulse, penetration of the laser beam into the sample, the evolution of the melt pool, and thermal conduction in the melt and surrounding solid. The excitation of the ultrasound takes place over a few nanoseconds, and occurs predominantly within the thermal diffusion length of a micron or so beneath the surface. Because of this, the output of the thermal simulations can be represented as axially symmetric transient radial and normal surface force distributions. The epicentral displacement response at the opposite surface to these forces is obtained by two methods, the one based on the elastodynamic Green’s functions for plate geometry determined by the Cagniard generalized ray method, and the other using a finite element numerical method. The two approaches are in very close agreement. Numerical simulations are reported of the epicentral displacement response of a 3.12mm thick tungsten plate irradiated with a 4 ns pulsed laser beam with Gaussian spatial profile, at intensities below and above the melt threshold. Comparison is made between results obtained using available temperature dependent thermophysical data, and room temperature materials constants except near the melting point.

  18. Real-Space Microscopic Electrical Imaging of n+-p Junction Beneath Front-Side Ag Contact of Multicrystalline Si Solar Cells

    SciTech Connect (OSTI)

    Jiang, C. S.; Li, Z. G.; Moutinho, H. R.; Liang, L.; Ionkin, A.; Al-Jassim, M. M.

    2012-04-15

    We investigated the quality of the n+-p diffused junction beneath the front-side Ag contact of multicrystalline Si solar cells by characterizing the uniformities of electrostatic potential and doping concentration across the junction using the atomic force microscopy-based electrical imaging techniques of scanning Kelvin probe force microscopy and scanning capacitance microscopy. We found that Ag screen-printing metallization fired at the over-fire temperature significantly degrades the junction uniformity beneath the Ag contact grid, whereas metallization at the optimal- and under-fire temperatures does not cause degradation. Ag crystallites with widely distributed sizes were found at the Ag-grid/emitter-Si interface of the over-fired cell, which is associated with the junction damage beneath the Ag grid. Large crystallites protrude into Si deeper than the junction depth. However, the junction was not broken down; instead, it was reformed on the entire front of the crystallite/Si interface. We propose a mechanism of junction-quality degradation, based on emitter Si melting at the temperature around the Ag-Si eutectic point during firing, and subsequent re-crystallization with incorporation of Ag and other impurities and with formation of crystallographic defects during quenching. The effect of this junction damage on solar cell performance is discussed.

  19. Inferences On The Hydrothermal System Beneath The Resurgent Dome...

    Open Energy Info (EERE)

    of this zone would allow a pressure change induced at distances of several kilometers below the well to be observable within a matter of days. This indicates that...

  20. Baseline Mapping Study of the Steed Pond Aquifer and Crouch Branch Confining Unit Beneath A/M Area, Savannah River Site, Aiken, South Carolina

    SciTech Connect (OSTI)

    JACKSON, DENNISG.

    1998-09-01

    This report presents the results of a baseline mapping project conducted for the Environmental Restoration Department at Savannah River Site. The purpose of this report is to map the distribution of mud (clay and silt-sized material) within each hydrogeologic unit from the surface down to the top of the Crouch Branch aquifer beneath the A/M Area. The distribution of mud layers and variations in the percentage of clay and silt within the strata is extremely important in order to fully characterize the extent of DNAPL beneath the A/M Area and determine the geometry of the contaminant plumes emanating from them. Precision mapping of these layers can aid in locating areas where contamination is most likely to have migrated into the saturated zone. In addition, this information can be used to refine the current remediation systems or assist in designing new remedial systems.

  1. Isotopic discontinuities in ground water beneath Yucca Mountain, Nevada

    SciTech Connect (OSTI)

    Stuckless, J.S.; Whelan, J.F.; Steinkampf, W.C.

    1991-05-01

    Analytical data for stable isotopes in ground water from beneath Yucca Mountain, when examined in map view, show areal patterns of heterogeneity that can be interpreted in terms of mixing of at least three end members. One end member must be isotopically heavy in terms of hydrogen and oxygen and have a young apparent {sup 14}C age such as water found at the north end of Yucca Mountain beneath Fortymile Wash. A second end member must contain isotopically heavy carbon and have an old apparent {sup 14}C age such as water from the Paleozoic aquifer. The third end member cannot be tightly defined. It must be isotopically lighter than the first with respect of hydrogen and oxygen and be intermediate to the first and second end members with respect to both apparent {sup 14}C age and {delta}{sup 13}C. The variable isotopic compositions of hydrogen and oxygen indicate that two of the end members are waters, but the variable carbon isotopic composition could represent either a third water end member or reaction of water with a carbon-bearing solids such as calcite. 15 refs., 4 figs., 1 tab.

  2. Analysis of pumping-induced unsaturated regions beneath aperennial river

    SciTech Connect (OSTI)

    Su, G.W.; Jasperse, J.; Seymour, D.; Constantz, J.; Zhou, Q.

    2007-05-15

    The presence of an unsaturated region beneath a streambedduring groundwater pumping near streams reduces the pumping capacity whenit reaches the well screens, changes flow paths, and alters the types ofbiological transformations in the streambed sediments. Athree-dimensional, multi-phase flow model of two horizontal collectorwells along the Russian River near Forestville, California was developedto investigate the impact of varying the ratio of the aquifer tostreambed permeability on (1) the formation of an unsaturated regionbeneath the stream, (2) the pumping capacity, (3) stream-water fluxesthrough the streambed, and (4) stream-water travel times to the collectorwells. The aquifer to streambed permeability ratio at which theunsaturated region was initially observed ranged from 10 to 100. The sizeof the unsaturated region beneath the streambed increased as the aquiferto streambed permeability ratio increased. The simulations also indicatedthat for a particular aquifer permeability, decreasing the streambedpermeability by only a factor of 2-3 from the permeability wheredesaturation initially occurred resulted in reducing the pumpingcapacity. In some cases, the stream-water fluxes increased as thestreambed permeability decreased. However, the stream water residencetimes increased and the fraction of stream water that reached that thewells decreased as the streambed permeability decreased, indicating thata higher streambed flux does not necessarily correlate to greaterrecharge of stream water around the wells.

  3. A Serendipitous, Long-Term Infiltration Experiment: Water and Tritium Circulation Beneath the CAMBRIC Ditch at the Nevada Test Site

    SciTech Connect (OSTI)

    Maxwell, R M; Tompson, A B; Kollet, S J

    2008-11-20

    Underground nuclear weapons testing at the Nevada Test Site introduced numerous radionuclides that may be used to characterize subsurface hydrologic transport processes in arid climates. A sixteen year pumping experiment designed to examine radionuclide migration away from the CAMBRIC nuclear test, conducted in groundwater beneath Frenchman Flat in 1965, gave rise to an unintended second experiment involving radionuclide infiltration through the vadose zone, as induced by seepage of pumping effluents beneath an unlined discharge trench. The combined experiments have been reanalyzed using a detailed, three-dimensional numerical model of transient, variably saturated flow and mass transport, tailored specifically for large scale and efficient calculations. Simulations have been used to estimate radionuclide travel and residence times in various parts of the system for comparison with observations in wells. Model predictions of mass transport were able to clearly demonstrate radionuclide recycling behavior between the ditch and pumping well previously suggested by isotopic age dating information; match travel time estimates for radionuclides moving between the ditch, the water table, and monitoring wells; and provide more realistic ways in which to interpret the pumping well elution curves. Collectively, the results illustrate the utility of integrating detailed numerical modeling with diverse observational data in developing accurate interpretations and forecasts of contaminant migration processes.

  4. Zone separator for multiple zone vessels

    DOE Patents [OSTI]

    Jones, John B.

    1983-02-01

    A solids-gas contact vessel, having two vertically disposed distinct reaction zones, includes a dynamic seal passing solids from an upper to a lower zone and maintaining a gas seal against the transfer of the separate treating gases from one zone to the other, and including a stream of sealing fluid at the seal.

  5. Water freezing and ice melting

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Malolepsza, Edyta; Keyes, Tom

    2015-10-12

    The generalized replica exchange method (gREM) is designed to sample states with coexisting phases and thereby to describe strong first order phase transitions. The isobaric MD version of the gREM is presented and applied to freezing of liquid water, and melting of hexagonal and cubic ice. It is confirmed that coexisting states are well sampled. The statistical temperature as a function of enthalpy, TS(H), is obtained. Hysteresis between freezing and melting is observed and discussed. The entropic analysis of phase transitions is applied and equilibrium transition temperatures, latent heats, and surface tensions are obtained for hexagonal ice↔liquid and cubic ice↔liquid,more » with excellent agreement with published values. A new method is given to assign water molecules among various symmetry types. As a result, pathways for water freezing, ultimately leading to hexagonal ice, are found to contain intermediate layered structures built from hexagonal and cubic ice.« less

  6. Airflow-terrain interactions through a mountain gap, with an example of eolian activity beneath an atmospheric hydraulic jump

    SciTech Connect (OSTI)

    Gaylord, D.R.; Dawson, P.J.

    1987-09-01

    The integration of atmospheric soundings from a fully instrumented aircraft with detailed sedimentary and geomorphic analyses of eolian features in the Ferris dune field of south-central Wyoming lends insight into the manner in which topography interacts with airflow to modify eolian activity. Topographically modified airflow results in zones of airflow deceleration, acceleration, and enhanced atmospheric turbulence, all of which influence the surface morphology and sedimentology. Extreme lateral confluence of prevailing airflow produces accelerated, unidirectional winds. These winds correlate with unusually continuous and elongate parabolic dunes that extend into a mountain gap (Windy Gap). Persistently heightened winds produced at the entrance to Windy Gap have resulted in a concentration of active sand dunes that lack slipfaces. Common development of a strongly amplified atmospheric wave analogous to a hydraulic jump in the gap contributes to the formation of a variety of eolian features that mantle the surface of Windy Gap and the Ferris dune field tail. Heightened, unidirectional winds in this zone promote grain-size segregation, the formation of elongated and aligned sand drifts, climbing and falling dunes, elongate scour streaks, and parabolic dunes that have low-angle (< 20/sup 0/) cross-stratification. Deflation of bedrock and loose sediment has been enhanced in the zone of maximum turbulence beneath the hydraulic jump.

  7. Structure of the Crust beneath Cameroon, West Africa, from the Joint Inversion of Rayleigh Wave Group Velocities and Receiver Functions

    SciTech Connect (OSTI)

    Tokam, A K; Tabod, C T; Nyblade, A A; Julia, J; Wiens, D A; Pasyanos, M E

    2010-02-18

    The Cameroon Volcanic Line (CVL) is a major geologic feature that cuts across Cameroon from the south west to the north east. It is a unique volcanic lineament which has both an oceanic and a continental sector and consists of a chain of Tertiary to Recent, generally alkaline volcanoes stretching from the Atlantic island of Pagalu to the interior of the African continent. The oceanic sector includes the islands of Bioko (formerly Fernando Po) and Sao Tome and Principe while the continental sector includes the Etinde, Cameroon, Manengouba, Bamboutos, Oku and Mandara mountains, as well as the Adamawa and Biu Plateaus. In addition to the CVL, three other major tectonic features characterize the region: the Benue Trough located northwest of the CVL, the Central African Shear Zone (CASZ), trending N70 degrees E, roughly parallel to the CVL, and the Congo Craton in southern Cameroon. The origin of the CVL is still the subject of considerable debate, with both plume and non-plume models invoked by many authors (e.g., Deruelle et al., 2007; Ngako et al, 2006; Ritsema and Allen, 2003; Burke, 2001; Ebinger and Sleep, 1998; Lee et al, 1994; Dorbath et al., 1986; Fairhead and Binks, 1991; King and Ritsema, 2000; Reusch et al., 2010). Crustal structure beneath Cameroon has been investigated previously using active (Stuart et al, 1985) and passive (Dorbath et al., 1986; Tabod, 1991; Tabod et al, 1992; Plomerova et al, 1993) source seismic data, revealing a crust about 33 km thick at the south-western end of the continental portion of the CVL (Tabod, 1991) and the Adamawa Plateau, and thinner crust (23 km thick) beneath the Garoua Rift in the north (Stuart et al, 1985) (Figure 1). Estimates of crustal thickness obtained using gravity data show similar variations between the Garoua rift, Adamawa Plateau, and southern part of the CVL (Poudjom et al., 1995; Nnange et al., 2000). In this study, we investigate further crustal structure beneath the CVL and the adjacent regions in

  8. Investigation of platinum alloys for melting of inclusion free laser glass: Final report

    SciTech Connect (OSTI)

    Izumitani, T.; Toratani, H.; Meissner, H.E.

    1986-02-28

    The objective of this work is to evaluate the suitability of Pt alloys as crucible materials for melting LHG-8 phosphate laser glass. The tendency of forming metallic inclusions and ionic dissolution of alloy components in the glass is to be compared with that of pure Pt. Ionic Pt is introduced into the glass melt by direct dissolution of Pt at the crucible-melt interface and by vapor phase transport. It was felt that a Pt-alloy may behave sufficiently differently from Pt that a number of alloys should be studied. Pt inclusions may originate from Pt which reprecipitates from the glass melt on cooling or change in redox-conditions; from volatilized Pt which deposits in colder zones of the melting environment as crystallites which may drop back into the glass melt; and/or from Pt particles which are mechanically removed from the crucible and drop into the glass melt. Besides pure Pt, the following alloys have been tested: Pt//sup 10/Ir, Pt//sup 10/Rh, Pt//sup 5/Au, Pt-ZGS, Pt//sup 5/Au-ZGS, Pt//sup 10/Rh-ZGS.

  9. An FTIR Study of Hydrogen in Anorthosite and Associated Melt Inclusions

    SciTech Connect (OSTI)

    Seaman,S.; Dyar, M.; Marinkovic, N.; Dunbar, N.

    2006-01-01

    the crystals formed, based on this study, and at these low melt water concentrations, is approximately 1:10. However, water concentration varies significantly from one melt inclusion to another, possibly suggesting initial melt water heterogeneity. Maps of water concentration show that variations in water concentration within melt inclusions are associated with fractures that cut the melt inclusions and in some cases do not extend out into surrounding crystals or into crystal inclusions. Thin ({approx}50 {micro}m thick) zones of elevated water concentrations on the boundaries of the crystals in contact with melt inclusions suggest that water has diffused into the crystals from the melt inclusions.

  10. Developing vanadium valence state oxybarometers (spinel-melt...

    Office of Scientific and Technical Information (OSTI)

    olivine-melt, spinel-olivine) and V(Cr+Al) partitioning (spinel-melt) for ... olivine-melt, spinel-olivine) and V(Cr+Al) partitioning (spinel-melt) for ...

  11. Zoning and Permitting Resources

    Broader source: Energy.gov [DOE]

    Zoning and permitting is commonly controlled by local governments and may be applicable to both residential and commercial properties.

  12. Purification of tantalum by plasma arc melting

    DOE Patents [OSTI]

    Dunn, Paul S.; Korzekwa, Deniece R.

    1999-01-01

    Purification of tantalum by plasma arc melting. The level of oxygen and carbon impurities in tantalum was reduced by plasma arc melting the tantalum using a flowing plasma gas generated from a gas mixture of helium and hydrogen. The flowing plasma gases of the present invention were found to be superior to other known flowing plasma gases used for this purpose.

  13. Melt dumping in string stabilized ribbon growth

    DOE Patents [OSTI]

    Sachs, Emanuel M.

    1986-12-09

    A method and apparatus for stabilizing the edge positions of a ribbon drawn from a melt includes the use of wettable strings drawn in parallel up through the melt surface, the ribbon being grown between the strings. A furnace and various features of the crucible used therein permit continuous automatic growth of flat ribbons without close temperature control or the need for visual inspection.

  14. Layered rocks beneath the Phanerozoic platform of the US midcontinent

    SciTech Connect (OSTI)

    Hauser, E.C. (Cornell Univ., Ithaca, NY (United States))

    1991-03-01

    A thick sequence of layered rocks lies hidden beneath the Phanerozoic cover of the central US over large regions. A thick sequence of Precambrian layered rocks in imaged on the COCORP transect across southern Illinois and Indiana. The thickness of this layered sequence varies from 1-3 times the thickness of the overlying Phanerozoic section of the Illinois basin. The layered sequence is observed for close to 200 km in an east-west direction. Similar layered reflections are seen on the COCORP data from Hardeman Co., TX, and neighboring southwest Oklahoma. Both of these known occurrences lie within the region of the middle Proterozoic Granite/Rhyolite province of the US midcontinent, an area within which scattered wells to basement commonly encounter 1.3-1.5 Ga undeformed granite and/or compositionally similar rhyolite. Therefore, these layered assemblages may comprise a thick sequence of silicic volcanic and sedimentary rocks (perhaps also injected by mafic sills) between scattered volcanic-intrusive centers, such as exposed in the St. Francois Mountains of southeast Missouri. However, in places such as Illinois and Indiana, the near absence of deep wells leaves the possibility that the upper portion of these layered rocks may locally be of late Proterozoic or earliest Paleozoic age. The reprocessing of available industry data, analyzed in conjunction with the existing COCORP data, includes extended vibroseis correlation. These industry data are invaluable in the author's effort to expand the known distribution of these layered rocks (e.g., into north-central Illinois) and to map their structures.

  15. Nanotexturing of surfaces to reduce melting point.

    SciTech Connect (OSTI)

    Garcia, Ernest J.; Zubia, David; Mireles, Jose; Marquez, Noel; Quinones, Stella

    2011-11-01

    This investigation examined the use of nano-patterned structures on Silicon-on-Insulator (SOI) material to reduce the bulk material melting point (1414 C). It has been found that sharp-tipped and other similar structures have a propensity to move to the lower energy states of spherical structures and as a result exhibit lower melting points than the bulk material. Such a reduction of the melting point would offer a number of interesting opportunities for bonding in microsystems packaging applications. Nano patterning process capabilities were developed to create the required structures for the investigation. One of the technical challenges of the project was understanding and creating the specialized conditions required to observe the melting and reshaping phenomena. Through systematic experimentation and review of the literature these conditions were determined and used to conduct phase change experiments. Melting temperatures as low as 1030 C were observed.

  16. Method and apparatus for improved melt flow during continuous strip casting

    DOE Patents [OSTI]

    Follstaedt, Donald W.; King, Edward L.; Schneider, Ken C.

    1991-11-12

    The continuous casting of metal strip using the melt overflow process is improved by controlling the weir conditions in the nozzle to provide a more uniform flow of molten metal across the width of the nozzle and reducing the tendency for freezing of metal along the interface with refractory surfaces. A weir design having a sloped rear wall and tapered sidewalls and critical gap controls beneath the weir has resulted in the drastic reduction in edge tearing and a significant improvement in strip uniformity. The floor of the container vessel is preferably sloped and the gap between the nozzle and the rotating substrate is critically controlled. The resulting flow patterns observed with the improved casting process have reduced thermal gradients in the bath, contained surface slag and eliminated undesirable solidification near the discharge area by increasing the flow rates at those points.

  17. Method and apparatus for improved melt flow during continuous strip casting

    DOE Patents [OSTI]

    Follstaedt, D.W.; King, E.L.; Schneider, K.C.

    1991-11-12

    The continuous casting of metal strip using the melt overflow process is improved by controlling the weir conditions in the nozzle to provide a more uniform flow of molten metal across the width of the nozzle and reducing the tendency for freezing of metal along the interface with refractory surfaces. A weir design having a sloped rear wall and tapered sidewalls and critical gap controls beneath the weir has resulted in the drastic reduction in edge tearing and a significant improvement in strip uniformity. The floor of the container vessel is preferably sloped and the gap between the nozzle and the rotating substrate is critically controlled. The resulting flow patterns observed with the improved casting process have reduced thermal gradients in the bath, contained surface slag and eliminated undesirable solidification near the discharge area by increasing the flow rates at those points. 8 figures.

  18. Complex systems influence melting of Greenland ice sheet

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    melting of Greenland ice sheet Complex systems influence melting of Greenland ice sheet International research team's field work shows that, well, things are more complicated...

  19. ITP Metal Casting: Advanced Melting Technologies: Energy Saving...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Melting Technologies: Energy Saving Concepts and Opportunities for the Metal Casting Industry ITP Metal Casting: Advanced Melting Technologies: Energy Saving Concepts and ...

  20. Sandia Energy - Molten Salt Test Loop Melted Salt

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Salt Home Renewable Energy Energy News Concentrating Solar Power Solar Molten Salt Test Loop Melted Salt Previous Next Molten Salt Test Loop Melted Salt The Molten Salt Test...

  1. ARM - Lesson Plans: When Land Ice Melts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Arctic and Antarctica are covered with large, heavy sheets of ice. Other islands like New Zealand have ice masses in the form of glaciers on them. When land-based ice melts, ...

  2. Gold nanorod melting | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Gold nanorod melting Share Topic Programs Materials science Materials simulation & theory Nanoscience Surface & interface studies Mathematics, computing, & computer science Modeling, simulation, & visualization Supercomputing & high-performance computing

  3. ESR melting under constant voltage conditions

    SciTech Connect (OSTI)

    Schlienger, M.E.

    1997-02-01

    Typical industrial ESR melting practice includes operation at a constant current. This constant current operation is achieved through the use of a power supply whose output provides this constant current characteristic. Analysis of this melting mode indicates that the ESR process under conditions of constant current is inherently unstable. Analysis also indicates that ESR melting under the condition of a constant applied voltage yields a process which is inherently stable. This paper reviews the process stability arguments for both constant current and constant voltage operation. Explanations are given as to why there is a difference between the two modes of operation. Finally, constant voltage process considerations such as melt rate control, response to electrode anomalies and impact on solidification will be discussed.

  4. Energy-Efficient Glass Melting: Submerged Combustion

    SciTech Connect (OSTI)

    2004-01-01

    Oxy-gas-fired submerged combustion melter offers simpler, improved performance. For the last 100 years, the domestic glass industry has used the same basic equipment for melting glass on an industrial scale.

  5. Two-zone countercurrent smelter system and process

    DOE Patents [OSTI]

    Cox, James H.; Fruehan, Richard J.; Elliott, deceased, John F.

    1995-01-01

    A process for continuously smelting iron ore by use of coal to yield molten iron or semi-steel is disclosed. The process comprises the steps of establishing a melt covered by slag; inducing the slag and the molten iron to flow countercurrently to one another, toward opposite ends of the smelter; maintaining iron oxide-reducing conditions in that zone of the smelter towards which the slag flows; maintaining carbon-oxidizing conditions in that zone of the smelter towards which the molten iron flows; continuously or semicontinuously tapping the slag from the reducing zone end of the smelter; continuously or semicontinuously tapping the molten iron from the oxidizing zone end of the smelter; and adding to both zones iron ore, coal, oxygen, and flux at addition rates sufficient to keep the molten iron in the reducing zone substantially saturated with carbon, maintain in the slag being tapped an FeO content of about 5 weight percent or less, and maintain in the molten iron being tapped a carbon content of about 0.5 to 5 weight percent. A slag dam preferably is included in the smelter, to impede the backflow of the slag from the reducing zone to the oxidizing zone. A metal bath dam with one or more flow-through portals also is preferably used, submerged below the slag dam, to impede the backflow of the hot metal.

  6. Two-zone countercurrent smelter system and process

    DOE Patents [OSTI]

    Cox, J.H.; Fruehan, R.J.; Elliott, J.F.

    1995-01-03

    A process for continuously smelting iron ore by use of coal to yield molten iron or semi-steel is disclosed. The process comprises the steps of establishing a melt covered by slag; inducing the slag and the molten iron to flow countercurrently to one another, toward opposite ends of the smelter; maintaining iron oxide-reducing conditions in that zone of the smelter towards which the slag flows; maintaining carbon-oxidizing conditions in that zone of the smelter towards which the molten iron flows; continuously or semicontinuously tapping the slag from the reducing zone end of the smelter; continuously or semicontinuously tapping the molten iron from the oxidizing zone end of the smelter; and adding to both zones iron ore, coal, oxygen, and flux at addition rates sufficient to keep the molten iron in the reducing zone substantially saturated with carbon, maintain in the slag being tapped an FeO content of about 5 weight percent or less, and maintain in the molten iron being tapped a carbon content of about 0.5 to 5 weight percent. A slag dam preferably is included in the smelter, to impede the backflow of the slag from the reducing zone to the oxidizing zone. A metal bath dam with one or more flow-through portals also is preferably used, submerged below the slag dam, to impede the backflow of the hot metal. 8 figures.

  7. Energy Saving Melting and Revert Reduction Technology (E-SMARRT): Melting Efficiency Improvement

    SciTech Connect (OSTI)

    Principal Investigator Kent Peaslee; Co-PI’s: Von Richards, Jeffrey Smith

    2012-07-31

    Steel foundries melt recycled scrap in electric furnaces and typically consume 35-100% excess energy from the theoretical energy requirement required to pour metal castings. This excess melting energy is multiplied by yield losses during casting and finishing operations resulting in the embodied energy in a cast product typically being three to six times the theoretical energy requirement. The purpose of this research project was to study steel foundry melting operations to understand energy use and requirements for casting operations, define variations in energy consumption, determine technologies and practices that are successful in reducing melting energy and develop new melting techniques and tools to improve the energy efficiency of melting in steel foundry operations.

  8. DWPF Macrobatch 2 Melt Rate Tests

    SciTech Connect (OSTI)

    Stone, M.E.

    2001-01-03

    The Defense Waste Processing Facility (DWPF) canister production rate must be increased to meet canister production goals. Although a number of factors exist that could potentially increase melt rate, this study focused on two: (1) changes in frit composition and (2) changes to the feed preparation process to alter the redox of the melter feed. These two factors were investigated for Macrobatch 2 (sludge batch 1B) utilizing crucible studies and a specially designed ''melt rate'' furnace. Other potential factors that could increase melt rate include: mechanical mixing via stirring or the use of bubblers, changing the power skewing to redistribute the power input to the melter, and elimination of heat loss (e.g. air in leakage). The melt rate testing in FY00 demonstrated that melt rate can be improved by adding a different frit or producing a much more reducing glass by the addition of sugar as a reductant. The frit that melted the fastest in the melt rate testing was Frit 165. A paper stud y was performed using the Product Composition Control System (PCCS) to determine the impact on predicted glass viscosity, liquidus, durability, and operating window if the frit was changed from Frit 200 to Frit 165. PCCS indicated that the window was very similar for both frits. In addition, the predicted viscosity of the frit 165 glass was 46 poise versus 84 poise for the Frit 200 glass. As a result, a change from Frit 200 to Frit 165 is expected to increase the melt rate in DWPF without decreasing waste loading.

  9. Manufacturing laser glass by continuous melting

    SciTech Connect (OSTI)

    Campbell, J H; Suratwala, T; krenitsky, S; Takeuchi, K

    2000-07-01

    A novel, continuous melting process is being used to manufacture meter-sized plates of laser glass at a rate 20-times faster, 5-times cheaper, and with 2-3 times better optical quality than with previous one-at-a-time, ''discontinuous'' technology processes. This new technology for manufacturing laser glass, which is arguably the most difficult continuously-melted optical material ever produced, comes as a result of a $60 million, six-year joint R&D program between government and industry. The glasses manufactured by the new continuous melting process are Nd-doped phosphate-based glasses and are marketed under the product names LG-770 (Schott Glass Technologies) and LHG-8 (Hoya Corporation USA). With this advance in glass manufacturing technology, it is now possible to construct high-energy, high-peak-power lasers for use in fusion energy development, national defense, and basic physics research that would have been impractical to build using the old melting technology. The development of continuously melted laser glass required technological advances that have lead to improvements in the manufacture of other optical glass products as well. For example, advances in forming, annealing, and conditioning steps of the laser glass continuous melting process are now being used in manufacture of other large-size optical glasses.

  10. Submerged combustion melting processes for producing glass and similar materials, and systems for carrying out such processes

    DOE Patents [OSTI]

    Charbonneau, Mark William

    2015-08-04

    Processes of controlling submerged combustion melters, and systems for carrying out the methods. One process includes feeding vitrifiable material into a melter vessel, the melter vessel including a fluid-cooled refractory panel in its floor, ceiling, and/or sidewall, and heating the vitrifiable material with a burner directing combustion products into the melting zone under a level of the molten material in the zone. Burners impart turbulence to the molten material in the melting zone. The fluid-cooled refractory panel is cooled, forming a modified panel having a frozen or highly viscous material layer on a surface of the panel facing the molten material, and a sensor senses temperature of the modified panel using a protected thermocouple positioned in the modified panel shielded from direct contact with turbulent molten material. Processes include controlling the melter using the temperature of the modified panel. Other processes and systems are presented.

  11. ASHRAE Climate Zones | Open Energy Information

    Open Energy Info (EERE)

    navigation, search Subtype A Subtype B Subtype C Climate Zone Number 1 Zone 1A Zone 1B NA Climate Zone Number 2 Zone 2A Zone 2B NA Climate Zone Number 3 Zone 3A Zone 3B Zone...

  12. Energy Saving Melting and Revert Reduction Technology: Melting Efficiency in Die Casting Operations

    SciTech Connect (OSTI)

    David Schwam

    2012-12-15

    This project addressed multiple aspects of the aluminum melting and handling in die casting operations, with the objective of increasing the energy efficiency while improving the quality of the molten metal. The efficiency of melting has always played an important role in the profitability of aluminum die casting operations. Consequently, die casters need to make careful choices in selecting and operating melting equipment and procedures. The capital cost of new melting equipment with higher efficiency can sometimes be recovered relatively fast when it replaces old melting equipment with lower efficiency. Upgrades designed to improve energy efficiency of existing equipment may be well justified. Energy efficiency is however not the only factor in optimizing melting operations. Melt losses and metal quality are also very important. Selection of melting equipment has to take into consideration the specific conditions at the die casting shop such as availability of floor space, average quantity of metal used as well as the ability to supply more metal during peaks in demand. In all these cases, it is essential to make informed decisions based on the best available data.

  13. ESR Process Instabilities while Melting Pipe Electrodes

    SciTech Connect (OSTI)

    Melgaard, D.K.; Shelmidine, G.J.

    1999-01-06

    With the demonstration of the viability of using the electroslag remelting process for the decontamination of radionuclides, interest has increased in examining the unique aspects associated with melting steel pipe electrodes. These electrodes consist of several nested pipes, welded concentrically to atop plate. Since these electrodes can be half as dense as a solid electrode, they present unique challenges to the standard algorithms used in controlling the melting process. Naturally the electrode must be driven down at a dramatically increased speed. However, since the heat transfer is greatly influenced and enhanced with the increased area to volume ratio, considerable variation in the melting rate of the pipes has been found. Standard control methods can become unstable as a result of the variation at increased speeds, particularly at shallow immersion depths. The key to good control lies in the understanding of the melting process. Several experiments were conducted to observe the characteristics of the melting using two different control modes. By using a pressure transducer to monitor the pressure inside the pipes, the venting of the air trapped inside the electrode was observed. The measurements reveal that for a considerable amount of time. the pipes are not completely immersed in the slag, allowing the gas inside to escape without the formation of bubbles. This result has implications for the voltage swing as well as for the decontamination reactions.

  14. Scrap uranium recycling via electron beam melting

    SciTech Connect (OSTI)

    McKoon, R.

    1993-11-01

    A program is underway at the Lawrence Livermore National Laboratory (LLNL) to recycle scrap uranium metal. Currently, much of the material from forging and machining processes is considered radioactive waste and is disposed of by oxidation and encapsulation at significant cost. In the recycling process, uranium and uranium alloys in various forms will be processed by electron beam melting and continuously cast into ingots meeting applicable specifications for virgin material. Existing vacuum processing facilities at LLNL are in compliance with all current federal and state environmental, safety and health regulations for the electron beam melting and vaporization of uranium metal. One of these facilities has been retrofitted with an auxiliary electron beam gun system, water-cooled hearth, crucible and ingot puller to create an electron beam melt furnace. In this furnace, basic process R&D on uranium recycling will be performed with the goal of eventual transfer of this technology to a production facility.

  15. Renewable Energy Renaissance Zones

    Office of Energy Efficiency and Renewable Energy (EERE)

    For the purposes of renaissance zone designation, “renewable energy facility” means a facility that creates energy, fuels, or chemicals directly from the wind, the sun, trees, grasses, bio-solids,...

  16. Deep Vadose Zone

    Broader source: Energy.gov [DOE]

    The Mission of the Deep Vadose Zone Applied Field Research Initiative is to protect water resources across the DOE complex over the long-term by developing effective solutions to solve DOE’s most...

  17. Rock melting tool with annealer section

    DOE Patents [OSTI]

    Bussod, Gilles Y.; Dick, Aaron J.; Cort, George E.

    1998-01-01

    A rock melting penetrator is provided with an afterbody that rapidly cools a molten geological structure formed around the melting tip of the penetrator to the glass transition temperature for the surrounding molten glass-like material. An annealing afterbody then cools the glass slowly from the glass transition temperature through the annealing temperature range to form a solid self-supporting glass casing. This allows thermally induced strains to relax by viscous deformations as the molten glass cools and prevents fracturing of the resulting glass liner. The quality of the glass lining is improved, along with its ability to provide a rigid impermeable casing in unstable rock formations.

  18. Method and apparatus for melting metals

    DOE Patents [OSTI]

    Moore, Alan F.; Schechter, Donald E.; Morrow, Marvin Stanley

    2006-03-14

    A method and apparatus for melting metals uses microwave energy as the primary source of heat. The metal or mixture of metals are placed in a ceramic crucible which couples, at least partially, with the microwaves to be used. The crucible is encased in a ceramic casket for insulation and placed within a microwave chamber. The chamber may be evacuated and refilled to exclude oxygen. After melting, the crucible may be removed for pouring or poured within the chamber by dripping or running into a heated mold within the chamber. Apparent coupling of the microwaves with softened or molten metal produces high temperatures with great energy savings.

  19. Deep Vadose Zone - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Long-Range Deep Vadose Zone Program Plan, (Rev. 0) - (PDF) Implementation Plan for the Deep Vadose Zone Applied Field Research Center (DVZ-AFRC) - (PDF) Ecology's groundwater...

  20. Silicon purification melting for photovoltaic applications

    SciTech Connect (OSTI)

    VAN DEN AVYLE,JAMES A.; HO,PAULINE; GEE,JAMES M.

    2000-04-01

    The availability of polysilicon feedstock has become a major issue for the photovoltaic (PV) industry in recent years. Most of the current polysilicon feedstock is derived from rejected material from the semiconductor industry. However, the reject material can become scarce and more expensive during periods of expansion in the integrated-circuit industry. Continued rapid expansion of the PV crystalline-silicon industry will eventually require a dedicated supply of polysilicon feedstock to produce solar cells at lower costs. The photovoltaic industry can accept a lower purity polysilicon feedstock (solar-grade) compared to the semiconductor industry. The purity requirements and potential production techniques for solar-grade polysilicon have been reviewed. One interesting process from previous research involves reactive gas blowing of the molten silicon charge. As an example, Dosaj et all reported a reduction of metal and boron impurities from silicon melts using reactive gas blowing with 0{sub 2} and Cl{sub 2}. The same authors later reassessed their data and the literature, and concluded that Cl{sub 2}and 0{sub 2}/Cl{sub 2} gas blowing are only effective for removing Al, Ca, and Mg from the silicon melt. Researchers from Kawasaki Steel Corp. reported removal of B and C from silicon melts using reactive gas blowing with an 0{sub 2}/Ar plasma torch. Processes that purify the silicon melt are believed to be potentially much lower cost compared to present production methods that purify gas species.

  1. Method for the melting of metals

    DOE Patents [OSTI]

    White, Jack C.; Traut, Davis E.

    1992-01-01

    A method of quantitatively determining the molten pool configuration in melting of metals. The method includes the steps of introducing hafnium metal seeds into a molten metal pool at intervals to form ingots, neutron activating the ingots and determining the hafnium location by radiometric means. Hafnium possesses exactly the proper metallurgical and radiochemical properties for this use.

  2. Determination of the fundamental softening and melting characteristics of blast furnace burden materials

    SciTech Connect (OSTI)

    Bakker, T.; Heerema, R.H.

    1996-12-31

    An experimental technique to investigate the fundamental mechanisms taking place on a microscale in the softening and melting zone in the blast furnace, is presented. In the present paper, attention is focused on determination of the softening viscosity of porous wustite. The technique may be potentially useful to investigate more complex samples of ironbearing material, as occurring in the blast furnace. In comparison with the results obtained by other researchers the viscosity of porous wustite found in the present work is substantially higher than reported elsewhere for sinter and pellets. This may be an indication that softening is not merely a reflection of the solid state deformation under load of wustite. An important factor may be local melting of some of the phases present within the sinter and pellet structures.

  3. Trace-element zoning in garnets from sheared mantle xenoliths

    SciTech Connect (OSTI)

    Griffin, W.L.; Cousens, D.R.; Ryan, C.G.; Sie, S.H.; Suter, G.F. ); Smith, D. ); Boyd, F.R. )

    1989-02-01

    Proton-microprobe analyses of garnets from sheared high-temperature ultramafic xenoliths reveal marked zonation of trace elements, paralleling trends in major and minor elements. Garnet rims (600-1,000 {mu}m wide) are enriched in Fe, Ti, Zr, Y and Ga, and either enriched or depleted in Cr, relative to cores. Zoning profiles for Ti and Zr are S-shaped and extend further into the grains than the Cr and Ga gradients. The profiles are consistent with the formation of Ti, Zr, Y-enriched garnet overgrowths, followed by diffusive equilibration between rim and core over years to hundreds of years. This enrichment in Fe, Ca, Al and incompatible elements is ascribed to melt infiltration and consequent melt-crystal exchange and garnet growth, shortly before eruption. Zr/Y is 1 to 2 in garnet cores but 4 to 5 in rims, and so the infiltrating melt may have been relatively alkalic. Major and trace element concentrations in such high-temperature sheared xenoliths are not likely to resemble those of primitive mantle or of residual mantle depleted by melt extraction.

  4. Energy-Efficient Melting and Direct Delivery of High Quality...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy-Efficient Melting and Direct Delivery of High Quality Molten Aluminum Energy-Efficient Melting and Direct Delivery of High Quality Molten Aluminum itmdelivery.pdf (572.12 ...

  5. Dynamics and pattern selection at the crystal-melt interface

    SciTech Connect (OSTI)

    Cummins, H.Z.

    1990-01-01

    This report discusses: light scattering at the crystal-melt interface; morphological instability and pattern selection; and sidebranching.

  6. Method and apparatus for drawing monocrystalline ribbon from a melt

    DOE Patents [OSTI]

    Ciszek, Theodore F.; Schwuttke, Guenter H.

    1981-11-10

    A method and apparatus for drawing a monocrystalline ribbon or web from a melt comprising utilizing a shaping die including at least two elements spaced one from the other each having a portion thereof located below the level of the melt and another portion located above the level of the melt a distance sufficient to form a raised meniscus of melt about the corresponding element.

  7. Melt behavior of aluminum clad rods

    SciTech Connect (OSTI)

    Geiger, G.T.; Long, T.A.; DeWald, A.B. Jr.

    1994-08-01

    Since the Li-Al alloy cores in control rods used to control production reactors are susceptible to corrosion by heavy water, they were clad with Al. This paper reports results of an experimental and numerical study of the behavior of control rods heated to the point of clad and rod-core failure. Results show that the core of the rod melts first; the clad fails only after significant additional heating. Once the rod breaks and drops to the bottom of the quartz tube in the furnace, the lower section of the rod fails by ``poker-chipping`` downward as the topmost portion fails before the portion below it. Part of the core in the remaining top of the rod relocates immediately after rod separation, leaving a hollow tube of Al which also melts upon further heating.

  8. Core-melt source reduction system

    DOE Patents [OSTI]

    Forsberg, Charles W.; Beahm, Edward C.; Parker, George W.

    1995-01-01

    A core-melt source reduction system for ending the progression of a molten core during a core-melt accident and resulting in a stable solid cool matrix. The system includes alternating layers of a core debris absorbing material and a barrier material. The core debris absorbing material serves to react with and absorb the molten core such that containment overpressurization and/or failure does not occur. The barrier material slows the progression of the molten core debris through the system such that the molten core has sufficient time to react with the core absorbing material. The system includes a provision for cooling the glass/molten core mass after the reaction such that a stable solid cool matrix results.

  9. Core-melt source reduction system

    DOE Patents [OSTI]

    Forsberg, C.W.; Beahm, E.C.; Parker, G.W.

    1995-04-25

    A core-melt source reduction system for ending the progression of a molten core during a core-melt accident and resulting in a stable solid cool matrix. The system includes alternating layers of a core debris absorbing material and a barrier material. The core debris absorbing material serves to react with and absorb the molten core such that containment overpressurization and/or failure does not occur. The barrier material slows the progression of the molten core debris through the system such that the molten core has sufficient time to react with the core absorbing material. The system includes a provision for cooling the glass/molten core mass after the reaction such that a stable solid cool matrix results. 4 figs.

  10. Precipitation of metal nitrides from chloride melts

    SciTech Connect (OSTI)

    Slater, S.A.; Miller, W.E.; Willit, J.L.

    1996-12-31

    Precipitation of actinides, lanthanides, and fission products as nitrides from molten chloride melts is being investigated for use as a final cleanup step in treating radioactive salt wastes generated by electrometallurgical processing of spent nuclear fuel. The radioactive components (eg, fission products) need to be removed to reduce the volume of high-level waste that requires disposal. To extract the fission products from the salt, a nitride precipitation process is being developed. The salt waste is first contacted with a molten metal; after equilibrium is reached, a nitride is added to the metal phase. The insoluble nitrides can be recovered and converted to a borosilicate glass after air oxidation. For a bench-scale experimental setup, a crucible was designed to contact the salt and metal phases. Solubility tests were performed with candidate nitrides and metal nitrides for which there are no solubility data. Experiments were performed to assess feasibility of precipitation of metal nitrides from chloride melts.

  11. Thermally efficient melting for glass making

    DOE Patents [OSTI]

    Chen, Michael S. K.; Painter, Corning F.; Pastore, Steven P.; Roth, Gary; Winchester, David C.

    1991-01-01

    The present invention is an integrated process for the production of glass utilizing combustion heat to melt glassmaking materials in a glassmaking furnace. The fuel combusted to produce heat sufficient to melt the glassmaking materials is combusted with oxygen-enriched oxidant to reduce heat losses from the offgas of the glassmaking furnace. The process further reduces heat losses by quenching hot offgas from the glassmaking furnace with a process stream to retain the heat recovered from quench in the glassmaking process with subsequent additional heat recovery by heat exchange of the fuel to the glassmaking furnace, as well as the glassmaking materials, such as batch and cullet. The process includes recovery of a commercially pure carbon dioxide product by separatory means from the cooled, residual offgas from the glassmaking furnace.

  12. Low-melting point heat transfer fluid

    DOE Patents [OSTI]

    Cordaro, Joseph Gabriel; Bradshaw, Robert W.

    2010-11-09

    A low-melting point, heat transfer fluid made of a mixture of five inorganic salts including about 29.1-33.5 mol % LiNO.sub.3, 0-3.9 mol % NaNO.sub.3, 2.4-8.2 mol % KNO.sub.3, 18.6-19.9 mol % NaNO.sub.2, and 40-45.6 mol % KNO.sub.2. These compositions can have liquidus temperatures below 80.degree. C. for some compositions.

  13. Analysis of Fracture in Cores from the Tuff Confining Unit beneath Yucca Flat, Nevada Test Site

    SciTech Connect (OSTI)

    Lance Prothro

    2008-03-01

    The role fractures play in the movement of groundwater through zeolitic tuffs that form the tuff confining unit (TCU) beneath Yucca Flat, Nevada Test Site, is poorly known. This is an important uncertainty, because beneath most of Yucca Flat the TCU lies between the sources of radionuclide contaminants produced by historic underground nuclear testing and the regional carbonate aquifer. To gain a better understanding of the role fractures play in the movement of groundwater and radionuclides through the TCU beneath Yucca Flat, a fracture analysis focusing on hydraulic properties was performed on conventional cores from four vertical exploratory holes in Area 7 of Yucca Flat that fully penetrate the TCU. The results of this study indicate that the TCU is poorly fractured. Fracture density for all fractures is 0.27 fractures per vertical meter of core. For open fractures, or those observed to have some aperture, the density is only 0.06 fractures per vertical meter of core. Open fractures are characterized by apertures ranging from 0.1 to 10 millimeter, and averaging 1.1 millimeter. Aperture typically occurs as small isolated openings along the fracture, accounting for only 10 percent of the fracture volume, the rest being completely healed by secondary minerals. Zeolite is the most common secondary mineral occurring in 48 percent of the fractures observed.

  14. Behavior of melts during softening and melting down of iron ore sinter under load

    SciTech Connect (OSTI)

    Cho, Y.H.

    1995-12-01

    In order to achieve effective operation in the blast furnace, the distribution control and quality improvement of burden materials are very important. In spite of the difficulties in obtaining suitable samples and making direct observation, significant progress including the placement of probes into the stack, tuyere drilling and laboratory simulation studies has been made. Investigation of the behavior of melts during softening and melting down was carried out in the temperature range of 800 C to 1,515 C. In this report, emphasis is given to investigating the mineral formation and properties of melts during softening and melting down of the iron ore sinter. Sized coke layers were placed above and below the sample to maintain uniform upward flow of gas and insure a smooth downward flow of melts. When the temperature of the sample reached the set point during the test the power was shut off and the sample was cooled in the furnace air. The weight, the height, porosity and contraction of each sample were measured. Chemical composition, observation of microstructures, SEM analysis and X-ray diffraction analysis were conducted. Results are presented.

  15. Vadose zone water fluxmeter

    DOE Patents [OSTI]

    Faybishenko, Boris A.

    2005-10-25

    A Vadose Zone Water Fluxmeter (WFM) or Direct Measurement WFM provides direct measurement of unsaturated water flow in the vadose zone. The fluxmeter is a cylindrical device that fits in a borehole or can be installed near the surface, or in pits, or in pile structures. The fluxmeter is primarily a combination of tensiometers and a porous element or plate in a water cell that is used for water injection or extraction under field conditions. The same water pressure measured outside and inside of the soil sheltered by the lower cylinder of the fluxmeter indicates that the water flux through the lower cylinder is similar to the water flux in the surrounding soil. The fluxmeter provides direct measurement of the water flow rate in the unsaturated soils and then determines the water flux, i.e. the water flow rate per unit area.

  16. Shallow melt apparatus for semicontinuous czochralski crystal growth

    DOE Patents [OSTI]

    Wang, Tihu; Ciszek, Theodore F.

    2006-01-10

    In a single crystal pulling apparatus for providing a Czochralski crystal growth process, the improvement of a shallow melt In a single crystal pulling apparatus for providing a Czochralski crystal growth process, the improvement of a shallow melt crucible (20) to eliminate the necessity supplying a large quantity of feed stock materials that had to be preloaded in a deep crucible to grow a large ingot, comprising a gas tight container a crucible with a deepened periphery (25) to prevent snapping of a shallow melt and reduce turbulent melt convection; source supply means for adding source material to the semiconductor melt; a double barrier (23) to minimize heat transfer between the deepened periphery (25) and the shallow melt in the growth compartment; offset holes (24) in the double barrier (23) to increase melt travel length between the deepened periphery (25) and the shallow growth compartment; and the interface heater/heat sink (22) to control the interface shape and crystal growth rate.

  17. Contaminants in Vadose Zone Environments

    Broader source: Energy.gov [DOE]

    The Deep Vadose Zone – Applied Field Research Initiative (DVZ-AFRI) partnered with the Vadose Zone Journal to create a special section of the journal's November 2012 issue.

  18. Renewable liquid reflecting zone plate

    DOE Patents [OSTI]

    Toor, Arthur; Ryutov, Dmitri D.

    2003-12-09

    A renewable liquid reflecting zone plate. Electrodes are operatively connected to a dielectric liquid in a circular or other arrangement to produce a reflecting zone plate. A system for renewing the liquid uses a penetrable substrate.

  19. Enterprise Zone | Open Energy Information

    Open Energy Info (EERE)

    Zone Jump to: navigation, search This article is a stub. You can help OpenEI by expanding it. Retrieved from "http:en.openei.orgwindex.php?titleEnterpriseZone&oldid542697"...

  20. Radiant zone heated particulate filter

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2011-12-27

    A system includes a particulate matter (PM) filter including an upstream end for receiving exhaust gas and a downstream end. A radiant zoned heater includes N zones, where N is an integer greater than one, wherein each of the N zones includes M sub-zones, where M is an integer greater than or equal to one. A control module selectively activates at least a selected one of the N zones to initiate regeneration in downstream portions of the PM filter from the one of the N zones, restricts exhaust gas flow in a portion of the PM filter that corresponds to the selected one of the N zones, and deactivates non-selected ones of the N zones.

  1. Ferritic steel melt and FLiBe/steel experiment : melting ferritic steel.

    SciTech Connect (OSTI)

    Troncosa, Kenneth P.; Smith, Brandon M.; Tanaka, Tina Joan

    2004-11-01

    In preparation for developing a Z-pinch IFE power plant, the interaction of ferritic steel with the coolant, FLiBe, must be explored. Sandia National Laboratories Fusion Technology Department was asked to drop molten ferritic steel and FLiBe in a vacuum system and determine the gas byproducts and ability to recycle the steel. We tried various methods of resistive heating of ferritic steel using available power supplies and easily obtained heaters. Although we could melt the steel, we could not cause a drop to fall. This report describes the various experiments that were performed and includes some suggestions and materials needed to be successful. Although the steel was easily melted, it was not possible to drip the molten steel into a FLiBe pool Levitation melting of the drop is likely to be more successful.

  2. Santa Clara County- Zoning Ordinance

    Broader source: Energy.gov [DOE]

    Santa Clara County's Zoning Ordinance includes standards for wind and solar structures for residential, agricultural, and commercial uses.

  3. Yucca Mountain Area Saturated Zone Dissolved Organic Carbon Isotopic Data

    SciTech Connect (OSTI)

    Thomas, James; Decker, David; Patterson, Gary; Peterman, Zell; Mihevc, Todd; Larsen, Jessica; Hershey, Ronald

    2007-06-25

    groundwater ages. The DIC calculated groundwater ages were compared with DOC calculated groundwater ages and both of these ages were compared to travel times developed in ground-water flow and transport models. If nuclear waste is stored in Yucca Mountain, the saturated zone is the final barrier against the release of radionuclides to the environment. The most recent rendition of the TSPA takes little credit for the presence of the saturated zone and is a testament to the inadequate understanding of this important barrier. If radionuclides reach the saturated zone beneath Yucca Mountain, then there is a travel time before they would leave the Yucca Mountain area and flow down gradient to the Amargosa Valley area. Knowing how long it takes groundwater in the saturated zone to flow from beneath Yucca Mountain to down gradient areas is critical information for potential radionuclide transport. Radionuclide transport in groundwater may be the quickest pathway for radionuclides in the proposed Yucca Mountain repository to reach land surface by way of groundwater pumped in Amargosa Valley. An alternative approach to ground-water flow and transport models to determine the travel time of radionuclides from beneath Yucca Mountain to down gradient areas in the saturated zone is by carbon-14 dating of both inorganic and organic carbon dissolved in the groundwater. A standard method of determining ground-water ages is to measure the carbon-13 and carbon-14 of DIC in the groundwater and then correct the measured carbon-14 along a flow path for geochemical reactions that involve carbon containing phases. These geochemical reactions are constrained by carbon-13 and isotopic fractionations. Without correcting for geochemical reactions, the ground-water ages calculated from only the differences in carbon-14 measured along a flow path (assuming the decrease in carbon-14 is due strictly to radioactive decay) could be tens of thousands of years too old. The computer program NETPATH, developed by

  4. X-ray Raman scattering study of MgSiO₃ glass at high pressure: Implication for triclustered MgSiO₃ melt in Earth's mantle

    SciTech Connect (OSTI)

    Lee, Sung Keun; Lin, Jung-Fu; Cai, Yong Q.; Hiraoka, Nozomu; Eng, Peter J.; Okuchi, Takuo; Mao, Ho-kwang; Meng, Yue; Hu, Michael Y.; Chow, Paul; Shu, Jinfu; Li, Baosheng; Fukui, Hiroshi; Lee, Bum Han; Kim, Hyun Na; Yoo, Choong-Shik

    2015-02-09

    Silicate melts at the top of the transition zone and the core-mantle boundary have significant influences on the dynamics and properties of Earth's interior. MgSiO3-rich silicate melts were among the primary components of the magma ocean and thus played essential roles in the chemical differentiation of the early Earth. Diverse macroscopic properties of silicate melts in Earth's interior, such as density, viscosity, and crystal-melt partitioning, depend on their electronic and short-range local structures at high pressures and temperatures. Despite essential roles of silicate melts in many geophysical and geodynamic problems, little is known about their nature under the conditions of Earth's interior, including the densification mechanisms and the atomistic origins of the macroscopic properties at high pressures. Here, we have probed local electronic structures of MgSiO3 glass (as a precursor to Mg-silicate melts), using high-pressure x-ray Raman spectroscopy up to 39 GPa, in which high-pressure oxygen K-edge features suggest the formation of tricluster oxygens (oxygen coordinated with three Si frameworks; [3]O) between 12 and 20 GPa. Our results indicate that the densification in MgSiO3 melt is thus likely to be accompanied with the formation of triculster, in addition to a reduction in nonbridging oxygens. The pressure-induced increase in the fraction of oxygen triclusters >20 GPa would result in enhanced density, viscosity, and crystal-melt partitioning, and reduced element diffusivity in the MgSiO3 melt toward deeper part of the Earth's lower mantle.

  5. Saturated Zone Colloid Transport

    SciTech Connect (OSTI)

    H. S. Viswanathan

    2004-10-07

    This scientific analysis provides retardation factors for colloids transporting in the saturated zone (SZ) and the unsaturated zone (UZ). These retardation factors represent the reversible chemical and physical filtration of colloids in the SZ. The value of the colloid retardation factor, R{sub col} is dependent on several factors, such as colloid size, colloid type, and geochemical conditions (e.g., pH, Eh, and ionic strength). These factors are folded into the distributions of R{sub col} that have been developed from field and experimental data collected under varying geochemical conditions with different colloid types and sizes. Attachment rate constants, k{sub att}, and detachment rate constants, k{sub det}, of colloids to the fracture surface have been measured for the fractured volcanics, and separate R{sub col} uncertainty distributions have been developed for attachment and detachment to clastic material and mineral grains in the alluvium. Radionuclides such as plutonium and americium sorb mostly (90 to 99 percent) irreversibly to colloids (BSC 2004 [DIRS 170025], Section 6.3.3.2). The colloid retardation factors developed in this analysis are needed to simulate the transport of radionuclides that are irreversibly sorbed onto colloids; this transport is discussed in the model report ''Site-Scale Saturated Zone Transport'' (BSC 2004 [DIRS 170036]). Although it is not exclusive to any particular radionuclide release scenario, this scientific analysis especially addresses those scenarios pertaining to evidence from waste-degradation experiments, which indicate that plutonium and americium may be irreversibly attached to colloids for the time scales of interest. A section of this report will also discuss the validity of using microspheres as analogs to colloids in some of the lab and field experiments used to obtain the colloid retardation factors. In addition, a small fraction of colloids travels with the groundwater without any significant retardation

  6. Liquid zone seal

    DOE Patents [OSTI]

    Klebanoff, Leonard E.

    2001-01-01

    A seal assembly that provides a means for establishing multiple pressure zones within a system. The seal assembly combines a plate extending from the inner wall of a housing or inner enclosure that intersects with and is immersed in the fluid contained in a well formed in a tray contained within the enclosure. The fluid is a low vapor pressure oil, chemically inert and oxidation resistant. The use of a fluid as the sealing component provides a seal that is self-healing and mechanically robust not subject to normal mechanical wear, breakage, and formation of cracks or pinholes and decouples external mechanical vibrations from internal structural members.

  7. Shallow Melt Apparatus for Semicontinuous Czochralski Crystal Growth

    DOE Patents [OSTI]

    Wang, T.; Ciszek, T. F.

    2006-01-10

    In a single crystal pulling apparatus for providing a Czochralski crystal growth process, the improvement of a shallow melt crucible (20) to eliminate the necessity supplying a large quantity of feed stock materials that had to be preloaded in a deep crucible to grow a large ingot, comprising a gas tight container a crucible with a deepened periphery (25) to prevent snapping of a shallow melt and reduce turbulent melt convection; source supply means for adding source material to the semiconductor melt; a double barrier (23) to minimize heat transfer between the deepened periphery (25) and the shallow melt in the growth compartment; offset holes (24) in the double barrier (23) to increase melt travel length between the deepened periphery (25) and the shallow growth compartment; and the interface heater/heat sink (22) to control the interface shape and crystal growth rate.

  8. High pressure melting curves of silver, gold and copper

    SciTech Connect (OSTI)

    Hieu, Ho Khac

    2013-11-15

    In this work, based on the Lindemann's formula of melting and the pressure-dependent Grüneisen parameter, we have investigated the pressure effect on melting temperature of silver, gold and copper metals. The analytical expression of melting temperature as a function of volume compression has been derived. Our results are compared with available experimental data as well as with previous theoretical studies and the good and reasonable agreements are found. We also proposed the potential of this approach on predicting melting of copper at very high pressure.

  9. Ultralow viscosity of carbonate melts at high pressures (Journal...

    Office of Scientific and Technical Information (OSTI)

    Title: Ultralow viscosity of carbonate melts at high pressures Authors: Kono, Yoshio ; Kenney-Benson, Curtis ; Hummer, Daniel ; Ohfuji, Hiroaki ; Park, Changyong ; Shen, Guoyin ; ...

  10. Numerical modeling of aerial bursts and ablation melting of Libyan...

    Office of Scientific and Technical Information (OSTI)

    Sponsoring Org: USDOE Country of Publication: United States Language: English Subject: 58 GEOSCIENCES; ABLATION; DESERTS; GLASS; MELTING; MATHEMATICAL MODELS; LIBYAN ARAB ...

  11. Breathing zone air sampler

    DOE Patents [OSTI]

    Tobin, John

    1989-01-01

    A sampling apparatus is provided which comprises a sampler for sampling air in the breathing zone of a wearer of the apparatus and a support for the sampler preferably in the form of a pair of eyeglasses. The sampler comprises a sampling assembly supported on the frame of the eyeglasses and including a pair of sample transport tubes which are suspended, in use, centrally of the frame so as to be disposed on opposite sides of the nose of the wearer and which each include an inlet therein that, in use, is disposed adjacent to a respective nostril of the nose of the wearer. A filter holder connected to sample transport tubes supports a removable filter for filtering out particulate material in the air sampled by the apparatus. The sample apparatus is connected to a pump for drawing air into the apparatus through the tube inlets so that the air passes through the filter.

  12. Low-melting point heat transfer fluid

    DOE Patents [OSTI]

    Cordaro, Joseph G.; Bradshaw, Robert W.

    2011-04-12

    A low-melting point, heat transfer fluid comprising a mixture of LiNO.sub.3, NaNO.sub.3, KNO.sub.3, NaNO.sub.2 and KNO.sub.2 salts where the Li, Na and K cations are present in amounts of about 20-33.5 mol % Li, about 18.6-40 mol % Na, and about 40-50.3 mol % K and where the nitrate and nitrite anions are present in amounts of about 36-50 mol % NO.sub.3, and about 50-62.5 mol % NO.sub.2. These compositions can have liquidus temperatures between 70.degree. C. and 80.degree. C. for some compositions.

  13. Stratified precambrian rocks (sedimentary?) beneath the midcontinent region of the US. Final technical report

    SciTech Connect (OSTI)

    Hauser, E.C.

    1993-02-01

    A thick sequence of layered rocks occurs beneath the Phanerozoic platform strata which blanket the US midcontinent. Observed on COCORP deep reflection data in southern Illinois and Indiana and in SW Oklahoma and adjacent Texas, this sequence is locally 1--3 times as thick as the overlying Paleozoic cover, but the origin of this sequence and its ultimate lateral extent are unknown. However, the occurrences of Precambrian layered rocks on both the COCORP profiles and reprocessed industry seismic reflection data from the region lie within regions of generally low amplitude and low frequency aeromagnetic anomaly, suggesting an even greater distribution. Unmetamorphosed Precambrian sedimentary rocks have been recovered from drill holes in southwest Ohio and adjacent northern Kentucky and southwesternmost Indiana. These Precambrian sedimentary rocks lie above and may be part of an underlying package of strongly layered rocks imaged on a short and shallow seismic profile in southwest Ohio. These Precambrian sedimentary rocks were originally viewed as part of a late Precambrian (Keweenawan?) rift; however, in light of Grenville foreland structures seen on the COCORP profile to the north in west central Ohio, these Precambrian strata may (1) be part of a heretofore unrecognized Grenville foreland basin, or (2) indicate that unmetamorphosed Precambrian sedimentary material may be an important constituent of the layered rocks observed on COCORP beneath southern Illinois and Indiana.

  14. Stratified precambrian rocks (sedimentary ) beneath the midcontinent region of the US

    SciTech Connect (OSTI)

    Hauser, E.C.

    1993-02-01

    A thick sequence of layered rocks occurs beneath the Phanerozoic platform strata which blanket the US midcontinent. Observed on COCORP deep reflection data in southern Illinois and Indiana and in SW Oklahoma and adjacent Texas, this sequence is locally 1--3 times as thick as the overlying Paleozoic cover, but the origin of this sequence and its ultimate lateral extent are unknown. However, the occurrences of Precambrian layered rocks on both the COCORP profiles and reprocessed industry seismic reflection data from the region lie within regions of generally low amplitude and low frequency aeromagnetic anomaly, suggesting an even greater distribution. Unmetamorphosed Precambrian sedimentary rocks have been recovered from drill holes in southwest Ohio and adjacent northern Kentucky and southwesternmost Indiana. These Precambrian sedimentary rocks lie above and may be part of an underlying package of strongly layered rocks imaged on a short and shallow seismic profile in southwest Ohio. These Precambrian sedimentary rocks were originally viewed as part of a late Precambrian (Keweenawan ) rift; however, in light of Grenville foreland structures seen on the COCORP profile to the north in west central Ohio, these Precambrian strata may (1) be part of a heretofore unrecognized Grenville foreland basin, or (2) indicate that unmetamorphosed Precambrian sedimentary material may be an important constituent of the layered rocks observed on COCORP beneath southern Illinois and Indiana.

  15. City of Austin- Zoning Code

    Broader source: Energy.gov [DOE]

    The Zoning Code also allows for preservation plans in historic districts to incorporate sustainability measures such as solar technologies and other energy generation and efficiency measures.

  16. Western Renewable Energy Zones (Presentation)

    SciTech Connect (OSTI)

    Hein, J.

    2011-06-01

    This presentation summarizes recent developments and trends pertaining to competitive renewable energy zones, transmission planning and the integration of renewable generation resources.

  17. Sandia defines solar variability zones

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    defines solar variability zones - Sandia Energy Energy Search Icon Sandia Home Locations ... Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power ...

  18. Water and Heat Balance Model for Predicting Drainage Below the Plant Root Zone

    Energy Science and Technology Software Center (OSTI)

    1989-11-01

    UNSAT-H Version 2.0 is a one-dimensional model that simulates the dynamic processes of infiltration, drainage, redistribution, surface evaporation, and the uptake of water from soil by plants. The model was developed for assessing the water dynamics of arid sites used or proposed for near-surface waste disposal. In particular, the model is used for simulating the water balance of cover systems over buried waste and for estimating the recharge rate (i.e., the drainage rate beneath themore » plant root zone when a sizable vadose zone is present). The mathematical base of the model are Richards'' equation for water flow, Ficks'' law for vapor diffusion, and Fouriers law for heat flow. The simulated profile can be homogeneous or layered. The boundary conditions can be controlled as either constant (potential or temperature) or flux conditions to reflect actual conditions at a given site.« less

  19. Science Road Map for Phase 2 of the Tank-Farm Vadose Zone Program

    SciTech Connect (OSTI)

    Zachara, John M.; Freshley, Mark D.; Mann, Frederick M.

    2008-08-18

    Phase 1 of the Tank-Farm Vadose Zone Program (TFVZP) developed information on the nature and extent of vadose zone contamination in the tank farms through field studies, laboratory analyses and experiments, and historical data searches; assembled data and performed tank-farm risk analysis; and initiated interim corrective actions to lessen the impacts of tank leak contaminants. Pacific Northwest National Laboratory scientists and external collaborators at universities and U.S. Department of Energy user facilities sampled and analyzed contaminant plumes. These types of activities will continue during Phase 2 of the TFVZP to refine and expand scientific understanding of the subsurface beneath tank farms, especially of water movement, residual waste leaching, and contaminant transport.

  20. T-TY Tank Farm Interim Surface Barrier Demonstration - Vadose Zone Monitoring FY10 Report

    SciTech Connect (OSTI)

    Zhang, Z. F.; Strickland, Christopher E.; Field, Jim G.; Parker, Danny L.

    2011-01-01

    The U.S. Department of Energy’s Office of River Protection has constructed interim surface barriers over a portion of the T and TY tank farms as part of the Interim Surface Barrier Demonstration Project. The interim surface barriers (hereafter referred to as the surface barriers or barriers) are designed to minimize the infiltration of precipitation into the soil zones containing radioactive contaminants and minimize the movement of the contaminants. As part of the demonstration effort, vadose zone moisture is being monitored to assess the effectiveness of the barriers at reducing soil moisture. Solar-powered systems were installed to continuously monitor soil water conditions at four locations in the T (i.e., instrument Nests TA, TB, TC, and TD) and the TY (i.e., instrument Nests TYA and TYB) Farms beneath the barriers and outside the barrier footprint as well as site meteorological conditions. Nests TA and TYA are placed in the area outside the barrier footprint and serve as controls, providing subsurface conditions outside the influence of the surface barriers. Nest TB provides subsurface measurements to assess surface-barrier edge effects. Nests TC, TD, and TYB are used to assess changes in soil-moisture conditions beneath the interim surface barriers.

  1. T Tank Farm Interim Surface Barrier Demonstration - Vadose Zone Monitoring FY08 Report

    SciTech Connect (OSTI)

    Zhang, Z. F.; Strickland, Christopher E.; Field, Jim G.; Parker, Danny L.

    2009-02-01

    DOE’s Office of River Protection constructed a temporary surface barrier over a portion of the T Tank Farm as part of the T Farm Interim Surface Barrier Demonstration Project. The surface barrier is designed to minimize the infiltration of precipitation into the contaminated soil zone created by the Tank T-106 leak and minimize movement of the contamination. As part of the demonstration effort, vadose zone moisture is being monitored to assess the effectiveness of the barrier at reducing soil moisture. A solar-powered system was installed to continuously monitor soil water conditions at four locations (i.e., instrument Nests A, B, C, and D) beneath the barrier and outside the barrier footprint as well as site meteorological conditions. Nest A is placed in the area outside the barrier footprint and serves as a control, providing subsurface conditions outside the influence of the surface barrier. Nest B provides subsurface measurements to assess surface-barrier edge effects. Nests C and D are used to assess changes in soil-moisture conditions beneath the interim surface barrier.

  2. Electron beam melting of charge based on titanium sponge

    SciTech Connect (OSTI)

    Tikhonovsky, A.L.; Tikhonovsky, K.A.

    1995-12-31

    An experience of 0.8 MW consumable box melting furnace operation and theoretical simulation have led to the further development of the FIKO plant under construction on the base of melting of two consumable box-like bullets which move opposite each other and form narrow heated space between melted butt ends. It allows to reduce vaporization, spatter and radiation losses by several times and to reach two times increase in melting rate and 99%(97%) yield for c.p. titanium (alloys) without furnace power add. Future furnace design will provide the optimum protection of vacuum pumps against chlorides, the safety when melting titanium sponge and will permit hot ingots to move to the special furnace for EB surface conditioning. The maximum productivity is to be 18,000 t/year. The furnace can be used for the manufacture of aluminum-, copper-, iron-, nickel-, tungsten-based alloys and others of any charge including salvage.

  3. Flow induced migration in polymer melts – Theory and simulation

    SciTech Connect (OSTI)

    Dorgan, John Robert Rorrer, Nicholas Andrew

    2015-04-28

    Flow induced migration, whereby polymer melts are fractionated by molecular weight across a flow field, represents a significant complication in the processing of polymer melts. Despite its long history, such phenomena remain relatively poorly understood. Here a simple analytical theory is presented which predicts the phenomena based on well-established principles of non-equilibrium thermodynamics. It is unambiguously shown that for purely viscous materials, a gradient in shear rate is needed to drive migration; for purely viscometric flows no migration is expected. Molecular scale simulations of flow migration effects in dense polymer melts are also presented. In shear flow the melts exhibit similar behavior as the quiescent case; a constant shear rate across the gap does not induce chain length based migration. In comparison, parabolic flow causes profound migration for both unentangled and entangled melts. These findings are consistent with the analytical theory. The picture that emerges is consistent with flow induced migration mechanisms predominating over competing chain degradation mechanisms.

  4. Evaluating Contaminant Flux from the Vadose Zone to the Groundwater in the Hanford Central Plateau. SX Tank Farms Case Study

    SciTech Connect (OSTI)

    Truex, Michael J.; Oostrom, Martinus; Last, George V.; Strickland, Christopher E.; Tartakovsky, Guzel D.

    2015-09-01

    At the DOE Hanford Site, contaminants were discharged to the subsurface through engineered waste sites in the Hanford Central Plateau. Additional waste was released through waste storage tank leaks. Much of the contaminant inventory is still present within the unsaturated vadose zone sediments. The nature and extent of future groundwater contaminant plumes and the growth or decline of current groundwater plumes beneath the Hanford Central Plateau are a function of the contaminant flux from the vadose zone to the groundwater. In general, contaminant transport is slow through the vadose zone and it is difficult to directly measure contaminant flux in the vadose zone. Predictive analysis, supported by site characterization and monitoring data, was applied using a structured, systems-based approach to estimate the future contaminant flux to groundwater in support of remediation decisions for the vadose zone and groundwater (Truex and Carroll 2013). The SX Tank Farm was used as a case study because of the existing contaminant inventory in the vadose zone, observations of elevated moisture content in portions of the vadose zone, presence of a limited-extent groundwater plume, and the relatively large amount and wide variety of data available for the site. Although the SX Tank Farm case study is most representative of conditions at tank farm sites, the study has elements that are also relevant to other types of disposal sites in the Hanford Central Plateau.

  5. Glass Furnace Combustion and Melting Research Facility.

    SciTech Connect (OSTI)

    Connors, John J.; McConnell, John F.; Henry, Vincent I.; MacDonald, Blake A.; Gallagher, Robert J.; Field, William B.; Walsh, Peter M.; Simmons, Michael C.; Adams, Michael E.; Leadbetter, James M.; Tomasewski, Jack W.; Operacz, Walter J.; Houf, William G.; Davis, James W.; Marvin, Bart G.; Gunner, Bruce E.; Farrell, Rick G.; Bivins, David P.; Curtis, Warren; Harris, James E.

    2004-08-01

    The need for a Combustion and Melting Research Facility focused on the solution of glass manufacturing problems common to all segments of the glass industry was given high priority in the earliest version of the Glass Industry Technology Roadmap (Eisenhauer et al., 1997). Visteon Glass Systems and, later, PPG Industries proposed to meet this requirement, in partnership with the DOE/OIT Glass Program and Sandia National Laboratories, by designing and building a research furnace equipped with state-of-the-art diagnostics in the DOE Combustion Research Facility located at the Sandia site in Livermore, CA. Input on the configuration and objectives of the facility was sought from the entire industry by a variety of routes: (1) through a survey distributed to industry leaders by GMIC, (2) by conducting an open workshop following the OIT Glass Industry Project Review in September 1999, (3) from discussions with numerous glass engineers, scientists, and executives, and (4) during visits to glass manufacturing plants and research centers. The recommendations from industry were that the melting tank be made large enough to reproduce the essential processes and features of industrial furnaces yet flexible enough to be operated in as many as possible of the configurations found in industry as well as in ways never before attempted in practice. Realization of these objectives, while still providing access to the glass bath and combustion space for optical diagnostics and measurements using conventional probes, was the principal challenge in the development of the tank furnace design. The present report describes a facility having the requirements identified as important by members of the glass industry and equipped to do the work that the industry recommended should be the focus of research. The intent is that the laboratory would be available to U.S. glass manufacturers for collaboration with Sandia scientists and engineers on both precompetitive basic research and the

  6. Hydrogeology of the unsaturated zone, Yucca Mountain, Nevada

    SciTech Connect (OSTI)

    Montazer, P.; Wilson, W.E.

    1985-12-31

    The unsaturated volcanic tuff beneath Yucca Mountain, Nevada, is being evaluated by the US Department of Energy as a host rock for a potential mined geologic repository for high-level radioactive waste. Assessment of site suitability needs an efficient and focused investigative program. A conceptual hydrogeologic model that simulates the flow of fluids through the unsaturated zone at Yucca Mountain was developed to guide the program and to provide a basis for preliminary assessment of site suitability. The study was made as part of the Nevada Nuclear Waste Storage Investigations Project of the US Department of Energy. Thickness of the unsaturated zone is about 1640 to 2460 feet (500 to 750 meters). Based on physical properties, the rocks in the unsaturated zone are grouped for the purpose of this paper into five informal hydrogeologic units. From top to bottom these units are: Tiva Canyon welded unit, Paintbrush nonwelded unit. Topopah Spring welded unit, Calico Hills nonwelded unit, and Crater Flat unit. Welded units have a mean fracture density of 8 to 40 fractures per unit cubic meter, mean matrix porosities of 12 to 23%, matrix hydraulic conductivities with geometric means ranging from 6.5 x 10{sup -6} to 9.8 x 10{sup -6} foot per day (2 x 10{sup -6} to 3 x 10{sup -6} meter per day), and bulk hydraulic conductivities of 0.33 to 33 feet per day (0.1 to 10 meters per day). The nonwelded units have a mean fracture density of 1 to 3 fractures per unit cubic meter, mean matrix porosities of 31 to 46%, and saturated hydraulic conductivities with geometric means ranging from 2.6 x 10{sup -5} to 2.9 x 10{sup -2} foot per day (8 x 10{sup -6} to 9 x 10{sup -3} meter per day). 15 refs., 4 figs., 1 tab.

  7. String melting in a photon bath

    SciTech Connect (OSTI)

    Karouby, Johanna

    2013-10-01

    We compute the decay rate of a metastable cosmic string in contact with a thermal bath by finding the instanton solution. The new feature is that this decay rate is found in the context of non thermal scalar fields in contact with a thermal bath of photons. In general, to make topologically unstable strings stable, one can couple them to such a bath. The resulting plasma effect creates metastable configurations which can decay from the false vacuum to the true vacuum. In our specific set-up, the instanton computation is realized for the case of two out-of-equilibrium complex scalar fields: one is charged and coupled to the photon field, and the other is neutral. New effects coming from the thermal bath of photons make the radius of the nucleated bubble and most of the relevant physical quantities temperature-dependent. However, the temperature appears in a different way than in the purely thermal case, where all scalar fields are in thermal equilibrium. As a result of the tunneling, the core of the initial string melts while bubbles of true vacuum expand at the speed of light.

  8. Deep crustal sediment study: Widespread precambrian layered rocks (sedimentary ?) beneath the US midcontinent

    SciTech Connect (OSTI)

    Hauser, E.C. [Cornell Univ., Ithaca, NY (United States)

    1992-05-01

    A thick sequence of layered rocks occurs beneath the Phanerozoic platform strata which blanket the U.S. midcontinent. Observed on COCORP deep reflection data in southern Illinois and Indiana and in SW Oklahoma and adjacent Texas, this sequence is locally 1-3 times as thick as the overlying Paleozoic cover, but the origin of this sequence, its ultimate lateral extent, and resource potential are unknown. The objective of this project is to seek and reprocess seismic reflection data provided by industry from the U.S. midcontinent, and together with the COCORP deep reflection data and information from the scattered basement-penetrating drill holes, to begin to constrain the distribution, origin and evolution of this enigmatic layered sequence, particularly to evaluate if sedimentary material may be an important constituent (i.e., deep gas potential).

  9. Deep crustal sediment study: Widespread Precambrian layered rocks (Sedimentary ) beneath the US midcontinent

    SciTech Connect (OSTI)

    Hauser, E.C.

    1992-01-01

    A thick sequence of layered rocks occurs beneath the Phanerozoic platform strata which blanket the US midcontinent. Observed on COCORP deep reflection data in southern Illinois and Indiana and in SW Oklahoma and adjacent Texas, this sequence is locally 1--3 times as thick as the overlying Paleozoic cover, but the origin of this sequence, its ultimate lateral extent, and resource potential are unknown. The objective of this project is to seek and reprocess seismic reflection data provided by industry from the US midcontinent and together with the COCORP deep reflection data and information from the scattered basement-penetrating drill holes, to begin to constrain the distribution, origin and evolution of this enigmatic layered sequence, particularly to evaluate if sedimentary material may be an important constituent (i.e., deep gas potential).

  10. Deep crustal sediment study: Widespread Precambrian layered rocks (Sedimentary ?) beneath the US midcontinent

    SciTech Connect (OSTI)

    Hauser, E.C.

    1992-06-01

    A thick sequence of layered rocks occurs beneath the Phanerozoic platform strata which blanket the US midcontinent. Observed on COCORP deep reflection data in southern Illinois and Indiana and in SW Oklahoma and adjacent Texas, this sequence is locally 1--3 times as thick as the overlying Paleozoic cover, but the origin of this sequence, its ultimate lateral extent, and resource potential are unknown. The objective of this project is to seek and reprocess seismic reflection data provided by industry from the US midcontinent and together with the COCORP deep reflection data and information from the scattered basement-penetrating drill holes, to begin to constrain the distribution, origin and evolution of this enigmatic layered sequence, particularly to evaluate if sedimentary material may be an important constituent (i.e., deep gas potential).

  11. Assessment of ceramic coatings for metal fuel melting crucible

    SciTech Connect (OSTI)

    Kim, Ki-Hwan; Song, Hoon; Kim, Jong-Hwan; Oh, Seok-Jin; Kim, Hyung-Tae; Lee, Chan-Bock

    2013-07-01

    The objective of this study is to develop a coating method and material for crucibles to prevent material interactions with the U-Zr/U-TRU-Zr fuels during the manufacturing of SFR fuels. Refractory coatings were applied to niobium substrates by vacuum plasma-spray coating method. Melt dipping tests conducted were the coated rods lowered into the fuel melt at 1600 C. degrees, and withdrawn and cooled outside the crucible in the inert atmosphere of the induction furnace. Melt dipping tests of the coated Nb rods indicated that plasma-sprayed Y{sub 2}O{sub 3} coating doesn't form significant reaction layer between fuel melt and coating layer. Melt dipping tests of the coated Nb rods showed that TiC, TaC, and Y{sub 2}O{sub 3} coatings exhibited the promising performance among other ceramic coatings. These materials could be promising candidate materials for the reusable melt crucible of metal fuel for SFR. In addition, in order to develop the vacuum plasma-spray coating method for re-usable crucible of metal fuel slugs to be overcome the issue of thermal expansion mismatch between coating material and crucible, various combinations of coating conditions were investigated to find the bonding effect on the substrate in pursuit of more effective ways to withstand the thermal stresses. It is observed that most coating methods maintained sound coating state in U-Zr melt. (authors)

  12. Computational fluid dynamics simulations of a glass melting furnace

    SciTech Connect (OSTI)

    Egelja, A.; Lottes, S. A.

    2000-05-09

    The glass production industry is one of the major users of natural gas in the US, and approximately 75% of the energy produced from natural gas is used in the melting process. Industrial scale glass melting furnaces are large devices, typically 5 or more meters wide, and twice as long. To achieve efficient heat transfer to the glass melt below, the natural gas flame must extend over a large portion of the glass melt. Therefore modern high efficiency burners are not used in these furnaces. The natural gas is injected as a jet, and a jet flame forms in the flow of air entering the furnace. In most current glass furnaces the energy required to melt the batch feed stock is about twice the theoretical requirement. An improved understanding of the heat transfer and two phase flow processes in the glass melt and solid batch mix offers a substantial opportunity for energy savings and consequent emission reductions. The batch coverage form and the heat flux distribution have a strong influence on the glass flow pattern. This flow pattern determines to a significant extent the melting rate and the quality of glass.

  13. Technical Basis for Evaluating Surface Barriers to Protect Groundwater from Deep Vadose Zone Contamination

    SciTech Connect (OSTI)

    Fayer, Michael J.; Ward, Anderson L.; Freedman, Vicky L.

    2010-02-03

    This document presents a strategy for evaluating the effectiveness of surface barriers for site-specific deep vadose zone remediation. The strategy provides a technically defensible approach to determine the depth to which a surface barrier can effectively isolate contaminants in the vadose at a specific site as a function of subsurface properties, contaminant distribution, barrier design, and infiltration control performance. The strategy also provides an assessment of additional data and information needs with respect to surface barrier performance for deep vadose zone applications. The strategy addresses the linkage between surface barriers and deep vadose zone in situ remediation activities, monitoring issues, and emerging science, technology, and regulatory objectives. In short, the report documents the existing knowledge base, identifies knowledge needs (based on data gaps), and suggests tasks whose outcomes will address those knowledge needs. More important, the report serves as a starting point to engage the regulator and stakeholder community on the viability of deploying surface barriers for deep vadose zone contamination. As that engagement unfolds, a systematic methodology can be formalized and instituted. The strategy is focused on deep vadose zone contamination and the methods needed to determine the impact to groundwater from those deep vadose zone contaminants. Processes that affect surface barrier performance, recharge in the areas surrounding the surface barrier, and the near-surface vadose zone beneath the barrier are acknowledged but are not addressed by this strategy. In addition, the collection of site-specific data on contaminant distribution and geologic structure and properties are programmatic responsibilities and are not provided by this strategy.

  14. Method for Synthesizing Extremeley High Temperature Melting Materials

    DOE Patents [OSTI]

    Saboungi, Marie-Louise and Glorieux, Benoit

    2005-11-22

    The invention relates to a method of synthesizing high-temperature melting materials. More specifically the invention relates to a containerless method of synthesizing very high temperature melting materials such as borides, carbides and transition-metal, lanthanide and actinide oxides, using an Aerodynamic Levitator and a laser. The object of the invention is to provide a method for synthesizing extremely high-temperature melting materials that are otherwise difficult to produce, without the use of containers, allowing the manipulation of the phase (amorphous/crystalline/metastable) and permitting changes of the environment such as different gaseous compositions.

  15. Melting of Ice Under Pressure | Argonne Leadership Computing Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Melting of Ice Under Pressure Authors: Schwegler, E., Sharma, M., Gygi, F., Galli, G. The melting of ice under pressure is investigated with a series of first-principles molecular dynamics simulations. In particular, a two-phase approach is used to determine the melting temperature of the ice-VII phase in the range of 10 Publication Date: August, 2008 Name of Publication Source: The National Academy of Sciences Proceedings Publisher: The National Academy of Sciences of the USA Volume: 0 Issue: 0

  16. Energy Efficient Glass Melting - The Next Generation Melter

    SciTech Connect (OSTI)

    David Rue

    2008-03-01

    The objective of this project is to demonstrate a high intensity glass melter, based on the submerged combustion melting technology. This melter will serve as the melting and homogenization section of a segmented, lower-capital cost, energy-efficient Next Generation Glass Melting System (NGMS). After this project, the melter will be ready to move toward commercial trials for some glasses needing little refining (fiberglass, etc.). For other glasses, a second project Phase or glass industry research is anticipated to develop the fining stage of the NGMS process.

  17. Method for synthesizing extremely high-temperature melting materials

    DOE Patents [OSTI]

    Saboungi, Marie-Louise (Chicago, IL); Glorieux, Benoit (Perpignan, FR)

    2007-11-06

    The invention relates to a method of synthesizing high-temperature melting materials. More specifically the invention relates to a containerless method of synthesizing very high temperature melting materials such as carbides and transition-metal, lanthanide and actinide oxides, using an aerodynamic levitator and a laser. The object of the invention is to provide a method for synthesizing extremely high-temperature melting materials that are otherwise difficult to produce, without the use of containers, allowing the manipulation of the phase (amorphous/crystalline/metastable) and permitting changes of the environment such as different gaseous compositions.

  18. Method For Synthesizing Extremely High-Temperature Melting Materials

    DOE Patents [OSTI]

    Saboungi, Marie-Louise; Glorieux, Benoit

    2005-11-22

    The invention relates to a method of synthesizing high-temperature melting materials. More specifically the invention relates to a containerless method of synthesizing very high temperature melting materials such as borides, carbides and transition-metal, lanthanide and actinide oxides, using an Aerodynamic Levitator and a laser. The object of the invention is to provide a method for synthesizing extremely high-temperature melting materials that are otherwise difficult to produce, without the use of containers, allowing the manipulation of the phase (amorphous/crystalline/metastable) and permitting changes of the environment such as different gaseous compositions.

  19. Geek-Up: K East Reactor Demolition, Retrograde Melting and Cloud Pattern Tracking

    Broader source: Energy.gov [DOE]

    Recovery Act funds help clean up the Hanford site, retrograde melting (melting as something cools) and how open-cell clouds could help predict climate change.

  20. DOE - NNSA/NFO -- Kids Zone

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ZONE NNSANFO Language Options U.S. DOENNSA - Nevada Field Office Cartoon drawing of science girl Kids Zone Welcome K-12 students and teachers The NNSANFO Kids Zone contains ...

  1. Climate Zone 1B | Open Energy Information

    Open Energy Info (EERE)

    Zone Subtype B. Climate Zone 1B is defined as Dry with IP Units 9000 < CDD50F and SI Units 5000 < CDD10C . The following places are categorized as class 1B climate zones:...

  2. Turkey Near-Zero Zone

    Broader source: Energy.gov [DOE]

    The Turkey Near-Zero Zone is an industrial energy efficiency project designed to reduce Turkey’s dependence on energy imports, bolster energy security, cut carbon emissions, and create business opportunities.

  3. Cohesive Zone Model User Element

    Energy Science and Technology Software Center (OSTI)

    2007-04-17

    Cohesive Zone Model User Element (CZM UEL) is an implementation of a Cohesive Zone Model as an element for use in finite element simulations. CZM UEL computes a nodal force vector and stiffness matrix from a vector of nodal displacements. It is designed for structural analysts using finite element software to predict crack initiation, crack propagation, and the effect of a crack on the rest of a structure.

  4. Dacite Melt at the Puna Geothermal Venture Wellfield, Big Island...

    Open Energy Info (EERE)

    (PGV) well field, on the island of Hawaii, a 75-meter interval of diorite containing brown glass inclusions was penetrated at a depth of 2415 m. At a depth of 2488 m a melt of...

  5. Melting of ice wedges adds to arctic warming

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ice wedges are a particularly cool surface feature in the Arctic tundra. And new research suggests they are melting fast, which is bad news for the ecosystem at the top of the ...

  6. Transition Zone Geothermal Region | Open Energy Information

    Open Energy Info (EERE)

    Unknown Planned Capacity 1 Geothermal Areas within the Transition Zone Geothermal Region Energy Generation Facilities within the Transition Zone Geothermal Region Geothermal Power...

  7. GridZone | Open Energy Information

    Open Energy Info (EERE)

    search Name: GridZone Sector: Efficiency, Services, Transmission Technology: Smart Grid, Energy Storage, Energy Security ParentHolding Organization: GridZone Limited Company...

  8. Wetlands and Riparian Zones | Open Energy Information

    Open Energy Info (EERE)

    Wetlands and Riparian Zones Jump to: navigation, search Retrieved from "http:en.openei.orgwindex.php?titleWetlandsandRiparianZones&oldid612217...

  9. Melting of ice wedges adds to arctic warming

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Can we someday predict earthquakes? Melting of ice wedges adds to arctic warming New ways of looking at seismic information and innovative laboratory experiments are offering tantalizing clues to what triggers earthquakes-and when. March 14, 2016 Ice throughout the Arctic is vanishing due to a rapidly warming climate. Ice throughout the Arctic is vanishing due to a rapidly warming climate. Melting of ice wedges adds to arctic warming Ice wedges are a particularly cool surface feature in the

  10. Apparatus for melt growth of crystalline semiconductor sheets

    DOE Patents [OSTI]

    Ciszek, Theodore F.; Hurd, Jeffery L.

    1986-01-01

    An economical method is presented for forming thin sheets of crystalline silicon suitable for use in a photovoltaic conversion cell by solidification from the liquid phase. Two spatially separated, generally coplanar filaments wettable by liquid silicon and joined together at the end by a bridge member are immersed in a silicon melt and then slowly withdrawn from the melt so that a silicon crystal is grown between the edge of the bridge and the filaments.

  11. Method and apparatus for melt growth of crystalline semiconductor sheets

    DOE Patents [OSTI]

    Ciszek, T.F.; Hurd, J.L.

    1981-02-25

    An economical method is presented for forming thin sheets of crystalline silicon suitable for use in a photovoltaic conversion cell by solidification from the liquid phase. Two spatially separated, generally coplanar filaments wettable by liquid silicon and joined together at the end by a bridge member are immersed in a silicon melt and then slowly withdrawn from the melt so that a silicon crystal is grown between the edge of the bridge and the filaments.

  12. ITP Metal Casting: Advanced Melting Technologies: Energy Saving Concepts

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Opportunities for the Metal Casting Industry | Department of Energy Advanced Melting Technologies: Energy Saving Concepts and Opportunities for the Metal Casting Industry ITP Metal Casting: Advanced Melting Technologies: Energy Saving Concepts and Opportunities for the Metal Casting Industry advancedmeltingtechnologies.pdf (1.83 MB) More Documents & Publications ITP Metal Casting: Theoretical/Best Practice Energy Use in Metalcasting Operations ITP Metal Casting: Energy and

  13. MELT RATE FURNACE TESTING FOR SLUDGE BATCH 5 FRIT OPTIMIZATION

    SciTech Connect (OSTI)

    Miller, D; Fox, K; Pickenheim, B; Stone, M

    2008-10-03

    Savannah River National Laboratory (SRNL) was requested to provide the Defense Waste Processing Facility (DWPF) with a frit composition for Sludge Batch 5 (SB5) to optimize processing. A series of experiments were designed for testing in the Melt Rate Furnace (MRF). This dry fed tool can be used to quickly determine relative melt rates for a large number of candidate frit compositions and lead to a selection for further testing. Simulated Sludge Receipt and Adjustment Tank (SRAT) product was made according to the most recent SB5 sludge projections and a series of tests were conducted with frits that covered a range of boron and alkali ratios. Several frits with relatively large projected operating windows indicated melt rates that would not severely impact production. As seen with previous MRF testing, increasing the boron concentration had positive impacts on melt rate on the SB5 system. However, there appears to be maximum values for both boron and sodium above which the there is a negative effect on melt rate. Based on these data and compositional trends, Frit 418 and a specially designed frit (Frit 550) have been selected for additional melt rate testing. Frit 418 and Frit 550 will be run in the Slurry Fed Melt Rate Furnace (SMRF), which is capable of distinguishing rheological properties not detected by the MRF. Frit 418 will be used initially for SB5 processing in DWPF (given its robustness to compositional uncertainty). The Frit 418-SB5 system will provide a baseline from which potential melt rate advantages of Frit 550 can be gauged. The data from SMRF testing will be used to determine whether Frit 550 should be recommended for implementation in DWPF.

  14. Complex systems influence melting of Greenland ice sheet

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Complex systems influence melting of Greenland ice sheet Complex systems influence melting of Greenland ice sheet International research team's field work shows that, well, things are more complicated than we thought December 22, 2014 The newly discovered rolling movement shown in (A) three-dimensional cryo-electron microscopy image of ribosome, and (B) computer-generated atomic-resolution model of the human ribosome consistent with microscopy. An international team of researchers deployed to

  15. Adams County, Washington ASHRAE 169-2006 Climate Zone | Open...

    Open Energy Info (EERE)

    ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Adams County, Washington ASHRAE Standard ASHRAE 169-2006 Climate Zone Number Climate Zone...

  16. Crystallographic texture engineering through novel melt strategies via electron beam melting: Inconel 718

    SciTech Connect (OSTI)

    Dehoff, Ryan R.; Kirka, Michael M.; List, III, Frederick Alyious; Unocic, Kinga A.; Sames, William J.

    2014-01-01

    Preliminary research has demonstrated the ability to utilise novel scan strategies in the electron beam melting (EBM) process to establish control of crystallographic texture within Inconel 718 deposits. Conventional EBM scan strategies and process parameters yield coarse columnar grains aligned parallel to the build direction. Through varying process parameters such as beam power, beam velocity, beam focus and scan strategy, the behaviour of the electron beam can be manipulated from a line source to a point source. The net effect of these variations is that the resulting crystallographic texture is controlled in a manner to produce either epitaxial deposits or fully equiaxed deposits. Furthermore, this research demonstrates the ability to change the crystallographic texture on the macroscale indicating that EBM technology can be used to create complex geometric components with both site-specific microstructures and material properties.

  17. Crystallographic texture engineering through novel melt strategies via electron beam melting: Inconel 718

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dehoff, Ryan R.; Kirka, Michael M.; List, III, Frederick Alyious; Unocic, Kinga A.; Sames, William J.

    2014-01-01

    Preliminary research has demonstrated the ability to utilise novel scan strategies in the electron beam melting (EBM) process to establish control of crystallographic texture within Inconel 718 deposits. Conventional EBM scan strategies and process parameters yield coarse columnar grains aligned parallel to the build direction. Through varying process parameters such as beam power, beam velocity, beam focus and scan strategy, the behaviour of the electron beam can be manipulated from a line source to a point source. The net effect of these variations is that the resulting crystallographic texture is controlled in a manner to produce either epitaxial deposits ormore » fully equiaxed deposits. Furthermore, this research demonstrates the ability to change the crystallographic texture on the macroscale indicating that EBM technology can be used to create complex geometric components with both site-specific microstructures and material properties.« less

  18. Pressure fluctuations beneath instability wavepackets and turbulent spots in a hypersonic boundary layer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Casper, Katya M.; Beresh, Steven J.; Schneider, Steven P.

    2014-09-09

    To investigate the pressure-fluctuation field beneath turbulent spots in a hypersonic boundary layer, a study was conducted on the nozzle wall of the Boeing/AFOSR Mach-6 Quiet Tunnel. Controlled disturbances were created by pulsed-glow perturbations based on the electrical breakdown of air. Under quiet-flow conditions, the nozzle-wall boundary layer remains laminar and grows very thick over the long nozzle length. This allows the development of large disturbances that can be well-resolved with high-frequency pressure transducers. A disturbance first grows into a second-mode instability wavepacket that is concentrated near its own centreline. Weaker disturbances are seen spreading from the centre. The wavesmore » grow and become nonlinear before breaking down to turbulence. The breakdown begins in the core of the packets where the wave amplitudes are largest. Second-mode waves are still evident in front of and behind the breakdown point and can be seen propagating in the spanwise direction. The turbulent core grows downstream, resulting in a spot with a classical arrowhead shape. Behind the spot, a low-pressure calmed region develops. However, the spot is not merely a localized patch of turbulence; instability waves remain an integral part. Limited measurements of naturally occurring disturbances show many similar characteristics. From the controlled disturbance measurements, the convection velocity, spanwise spreading angle, and typical pressure-fluctuation field were obtained.« less

  19. Pressure fluctuations beneath instability wavepackets and turbulent spots in a hypersonic boundary layer

    SciTech Connect (OSTI)

    Casper, Katya M.; Beresh, Steven J.; Schneider, Steven P.

    2014-09-09

    To investigate the pressure-fluctuation field beneath turbulent spots in a hypersonic boundary layer, a study was conducted on the nozzle wall of the Boeing/AFOSR Mach-6 Quiet Tunnel. Controlled disturbances were created by pulsed-glow perturbations based on the electrical breakdown of air. Under quiet-flow conditions, the nozzle-wall boundary layer remains laminar and grows very thick over the long nozzle length. This allows the development of large disturbances that can be well-resolved with high-frequency pressure transducers. A disturbance first grows into a second-mode instability wavepacket that is concentrated near its own centreline. Weaker disturbances are seen spreading from the centre. The waves grow and become nonlinear before breaking down to turbulence. The breakdown begins in the core of the packets where the wave amplitudes are largest. Second-mode waves are still evident in front of and behind the breakdown point and can be seen propagating in the spanwise direction. The turbulent core grows downstream, resulting in a spot with a classical arrowhead shape. Behind the spot, a low-pressure calmed region develops. However, the spot is not merely a localized patch of turbulence; instability waves remain an integral part. Limited measurements of naturally occurring disturbances show many similar characteristics. From the controlled disturbance measurements, the convection velocity, spanwise spreading angle, and typical pressure-fluctuation field were obtained.

  20. Phase structure within a fracture network beneath a surface pond: Field experiment

    SciTech Connect (OSTI)

    GLASS JR.,ROBERT J.; NICHOLL,M.J.

    2000-05-09

    The authors performed a simple experiment to elucidate phase structure within a pervasively fractured welded tuff. Dyed water was infiltrated from a surface pond over a 36 minute period while a geophysical array monitored the wetted region within vertical planes directly beneath. They then excavated the rock mass to a depth of {approximately}5 m and mapped the fracture network and extent of dye staining in a series of horizontal pavements. Near the pond the network was fully stained. Below, the phase structure immediately expanded and with depth, the structure became fragmented and complicated exhibiting evidence of preferential flow, fingers, irregular wetting patterns, and varied behavior at fracture intersections. Limited transient geophysical data suggested that strong vertical pathways form first followed by increased horizontal expansion and connection within the network. These rapid pathways are also the first to drain. Estimates also suggest that the excavation captured from {approximately}10% to 1% or less of the volume of rock interrogated by the infiltration slug and thus the penetration depth could have been quite large.

  1. Distribution of radionuclides and water in Bandelier Tuff beneath a former Los Alamos liquid waste disposal site after 33 years

    SciTech Connect (OSTI)

    Nyhan, J.W.; Drennon, B.J.; Abeele, W.V.; Trujillo, G.; Herrera, W.J.; Wheeler, M.L.; Booth, J.W.; Purtymun, W.D.

    1984-07-01

    The distribution of radionuclides and water in Bandelier Tuff beneath a former liquid waste disposal site at Los Alamos was investigated. The waste use history of the site was described, as well as several pertinent laboratory and field studies of water and radionuclide migration in Bandelier Tuff. The distribution of plutonium, /sup 241/Am, and water was determined in a set of about 800 tuff samples collected to sampling depths of 30 m beneath two absorption beds. These data were then related to site geohydrologic data. Water and radionuclide concentrations found after 33 years were compared with the results of similar studies previously performed at this site, and the implications of these comparisons are discussed relative to nuclear waste management. 19 references, 6 figures, 4 tables.

  2. Device and method for skull-melting depth measurement

    DOE Patents [OSTI]

    Lauf, Robert J. (Oak Ridge, TN); Heestand, Richard L. (Oak Ridge, TN)

    1993-01-01

    A method of skull-melting comprises the steps of: a. providing a vessel adapted for a skull-melting process, the vessel having an interior, an underside, and an orifice in connecting the interior and the underside; b. disposing a waveguide in the orifice so that the waveguide protrudes sufficiently into the interior to interact with the skull-melting process; c. providing a signal energy transducer in signal communication with the waveguide; d. introducing into the vessel a molten working material; e. carrying out the skull-melting process so that a solidified skull of the working material is formed, the skull and the vessel having an interface therebetween, the skull becoming fused to the waveguide so the signal energy can be transmitted through the waveguide and the skull without interference from the interface; f. activating the signal energy transducer so that a signal is propagated through the waveguide; and, g. controlling at least one variable of the skull-melting process utilizing feedback information derived from the propagated signal energy.

  3. Device and method for skull-melting depth measurement

    DOE Patents [OSTI]

    Lauf, R.J.; Heestand, R.L.

    1993-02-09

    A method of skull-melting comprises the steps of: (a) providing a vessel adapted for a skull-melting process, the vessel having an interior, an underside, and an orifice connecting the interior and the underside; (b) disposing a waveguide in the orifice so that the waveguide protrudes sufficiently into the interior to interact with the skull-melting process; (c) providing a signal energy transducer in signal communication with the waveguide; (d) introducing into the vessel a molten working material; (e) carrying out the skull-melting process so that a solidified skull of the working material is formed, the skull and the vessel having an interface therebetween, the skull becoming fused to the waveguide so the signal energy can be transmitted through the waveguide and the skull without interference from the interface; (f) activating the signal energy transducer so that a signal is propagated through the waveguide; and, (g) controlling at least one variable of the skull-melting process utilizing feedback information derived from the propagated signal energy.

  4. T Tank Farm Interim Surface Barrier Demonstration--Vadose Zone Monitoring Plan

    SciTech Connect (OSTI)

    Zhang, Z. F.; Keller, Jason M.; Strickland, Christopher E.

    2007-04-01

    The Hanford Site has 149 underground single-shell tanks that store hazardous radioactive waste. Many of these tanks and their associated infrastructure (e.g., pipelines, diversion boxes) have leaked. Some of the leaked waste has entered the groundwater. The largest known leak occurred from the T-106 Tank in 1973. Many of the contaminants from that leak still reside within the vadose zone beneath the T Tank Farm. CH2M Hill Hanford Group, Inc. seeks to minimize movement of this residual contaminant plume by placing an interim barrier on the surface. Such a barrier is expected to prevent infiltrating water from reaching the plume and moving it further. A plan has been prepared to monitor and determine the effectiveness of the interim surface barrier. Soil water content and water pressure will be monitored using off-the-shelf equipment that can be installed by the hydraulic hammer technique. In fiscal year 2006, two instrument nests were installed. Each instrument nest contains a neutron probe access tube, a capacitance probe, four heat-dissipation units, and a drain gauge to measure soil water flux. A meteorological station has been installed outside of the fence. In fiscal year 2007, two additional instrument nests are planned to be installed beneath the proposed barrier.

  5. Data Package for Past and Current Groundwater Flow and Contamination beneath Single-Shell Tank Waste Management Areas

    SciTech Connect (OSTI)

    Horton, Duane G.

    2007-03-16

    This appendix summarizes historic and recent groundwater data collected from the uppermost aquifer beneath the 200 East and 200 West Areas. Although the area of interest is the Hanford Site Central Plateau, most of the information discussed in this appendix is at the scale of individual single-shell tank waste management areas. This is because the geologic, and thus the hydraulic, properties and the geochemical properties (i.e., groundwater composition) are different in different parts of the Central Plateau.

  6. Melt processing of Bi--2212 superconductors using alumina

    DOE Patents [OSTI]

    Holesinger, Terry G.

    1999-01-01

    Superconducting articles and a method of forming them, where the superconducting phase of an article is Bi.sub.2 Sr.sub.2 CaCu.sub.2 O.sub.y (Bi-2212). Alumina is combined with Bi-2212 powder or Bi-2212 precursor powder and, in order to form an intimate mixture, the mixture is melted and rapidly cooled to form a glassy solid. The glassy solid is comminuted and the resulting powder is combined with a carrier. An alternative to melting is to form the mixture of nanophase alumina and material having a particle size of less than about 10 microns. The powder, with the carrier, is melt processed to form a superconducting article.

  7. Technical and economical considerations of new DRI melting process

    SciTech Connect (OSTI)

    Ito, Shuzo; Tokuda, Koji; Sammt, F.; Gray, R.

    1997-12-31

    The new DRI melting process can effectively and economically produce high quality molten iron. This process utilizes hot charging of DRI directly from a reduction furnace into a dedicated new melting furnace. The molten iron from this DRI premelter can be charged into a steelmaking furnace, such as an electric arc furnace (EAF), where the molten iron, together with other iron sources, can be processed to produce steel. Alternatively the molten iron can be pigged or granulated for off-site merchant sales. Comprehensive research and development of the new process has been conducted including operational process simulation, melting tests using FASTMET DRI, slag technology development, and refractory corrosion testing. This paper describes the process concept, its operational characteristics and further applications of the process.

  8. Review and model-based analysis of factors influencing soil carbon sequestration beneath switchgrass (Panicum virgatum)

    SciTech Connect (OSTI)

    Garten Jr, Charles T [ORNL

    2012-01-01

    Abstract. A simple, multi-compartment model was developed to predict soil carbon sequestration beneath switchgrass (Panicum virgatum) plantations in the southeastern United States. Soil carbon sequestration is an important component of sustainable switchgrass production for bioenergy because soil organic matter promotes water retention, nutrient supply, and soil properties that minimize erosion. A literature review was included for the purpose of model parameterization and five model-based experiments were conducted to predict how changes in environment (temperature) or crop management (cultivar, fertilization, and harvest efficiency) might affect soil carbon storage and nitrogen losses. Predictions of soil carbon sequestration were most sensitive to changes in annual biomass production, the ratio of belowground to aboveground biomass production, and temperature. Predictions of ecosystem nitrogen loss were most sensitive to changes in annual biomass production, the soil C/N ratio, and nitrogen remobilization efficiency (i.e., nitrogen cycling within the plant). Model-based experiments indicated that 1) soil carbon sequestration can be highly site specific depending on initial soil carbon stocks, temperature, and the amount of annual nitrogen fertilization, 2) response curves describing switchgrass yield as a function of annual nitrogen fertilization were important to model predictions, 3) plant improvements leading to greater belowground partitioning of biomass could increase soil carbon sequestration, 4) improvements in harvest efficiency have no indicated effects on soil carbon and nitrogen, but improve cumulative biomass yield, and 5) plant improvements that reduce organic matter decomposition rates could also increase soil carbon sequestration, even though the latter may not be consistent with desired improvements in plant tissue chemistry to maximize yields of cellulosic ethanol.

  9. Property:Buildings/ModelClimateZone | Open Energy Information

    Open Energy Info (EERE)

    Climate Zone 7A Climate Zone 7B Climate Zone 8A Climate Zone 8B Pages using the property "BuildingsModelClimateZone" Showing 12 pages using this property. G General Merchandise...

  10. Overlap zoned electrically heated particulate filter

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Chapman, Mark R [Brighton, MI

    2011-07-19

    A system includes a particulate matter (PM) filter that includes an upstream end for receiving exhaust gas and a downstream end. A zoned heater is arranged spaced from the upstream end and comprises N zones, where N is an integer greater than one, wherein each of the N zones comprises M sub-zones, where M is an integer greater than or equal to one, and wherein the N zones and the M sub-zones are arranged in P layers, where P is an integer greater than one. A control module selectively activates at least a selected one of the N zones to initiate regeneration in downstream portions of the PM filter from the one of the N zones and deactivates non-selected ones of the N zones.

  11. Melting of Uranium Metal Powders with Residual Salts

    SciTech Connect (OSTI)

    Jin-Mok Hur; Dae-Seung Kang; Chung-Seok Seo

    2007-07-01

    The Advanced Spent Fuel Conditioning Process (ACP) of the Korea Atomic Energy Research Institute focuses on the conditioning of Pressurized Water Reactor spent oxide nuclear fuel. After the oxide reduction step of the ACP, the resultant metal powders containing {approx} 30 wt% residual LiCl-Li{sub 2}O should be melted for a consolidation of the fine metal powders. In this study, we investigated the melting behaviors of uranium metal powders considering the effects of a LiCl-Li{sub 2}O residual salt. (authors)

  12. Vadose zone characterization project at the Hanford Tank Farms: BY Tank Farm report

    SciTech Connect (OSTI)

    Kos, S.E.

    1997-02-01

    The US Department of Energy Grand Junction Office (GJO) was tasked by the DOE Richland Operations Office (DOE-RL) to perform a baseline characterization of the contamination distributed in the vadoze zone sediment beneath and around the single-shell tanks (SSTs) at the Hanford Site. The intent of this characterization is to determine the nature and extent of the contamination, to identify contamination sources, and to develop a baseline of the contamination distribution that will permit future data comparisons. This characterization work also allows an initial assessment of the impacts of the vadose zone contamination as required by the Resource Conservation and Recovery Act (RCRA). This characterization project involves acquiring information about the vadose zone contamination with borehole geophysical logging methods and documenting that information in a series of reports. Data from boreholes surrounding each tank are compiled into individual Tank Summary Data Reports. The data from each tank farm are then compiled and summarized in a Tank Farm Report. This document is the Tank Farm Report for the BY Tank Farm.

  13. Model of fracture of metal melts and the strength of melts under dynamic conditions

    SciTech Connect (OSTI)

    Mayer, P. N. Mayer, A. E.

    2015-07-15

    The development of a continuum model of deformation and fracture of melts is needed for the description of the behavior of metals in extreme states, in particular, under high-current electron and ultrashort laser irradiation. The model proposed includes the equations of mechanics of a two-phase continuum and the equations of the kinetics of phase transitions. The change (exchange) of the volumes of dispersed and carrier phases and of the number of dispersed particles is described, and the energy and mass exchange between the phases due to phase transitions is taken into account. Molecular dynamic (MD) calculations are carried out with the use of the LAMMPS program. The continuum model is verified by MD, computational, and experimental data. The strength of aluminum, copper, and nickel is determined at various temperatures and strain rates. It is shown that an increase in the strain rate leads to an increase in the strength of a liquid metal, while an increase in temperature leads to a decrease in its strength.

  14. EVALUATION OF VADOSE ZONE TREATMENT TECHNOLOGIES TO IMMOBILIZE TECHNETIUM-99

    SciTech Connect (OSTI)

    PETERSEN, S.W.

    2006-03-15

    The Hanford Site End State Vision document (DOE/RL-2003-59) states: ''There should be an aggressive plan to develop technology for remediation of the contamination that could get to the groundwater (particularly the technetium [{sup 99}Tc])''. In addition, there is strong support from the public and regulatory agencies for the above statement, with emphasis on investigation of treatment alternatives. In July 2004, PNNL completed a preliminary evaluation of remediation technologies with respect to their effectiveness and implementability for immobilization of {sup 99}Tc beneath the BC Cribs in the 200 West Area (Truex, 2004). As a result of this evaluation, PNNL recommended treatability testing of in situ soil desiccation, because it has the least uncertainty of those technologies evaluated in July 2004 (Treatability Test Outline, September 30, 2004). In 2005, DOE-RL and Fluor Hanford convened an independent technical panel to review alternative remediation technologies, including desiccation, at a three-day workshop in Richland, Washington. The panel was composed of experts in vadose-zone transport, infiltration control, hydrology, geochemistry, environmental engineering, and geology. Their backgrounds include employment in academia, government laboratories, industry, and consulting. Their review, presented in this document, is based upon written reports from Hanford, oral presentations from Hanford staff, and each panel members' years of experience in their particular field of expertise. The purpose of this report is to document the panel's evaluation of various treatment alternatives with potential for minimizing contaminant migration in the deep vadose zone at the Department of Energy Hanford Site. The panel was tasked with assessing the most viable and practical approach and making recommendations for testing. The evaluation of vadose-zone treatment alternatives was conducted to be broadly applicable at a variety of locations at Hanford. However, because of

  15. Unsaturated Zone and Saturated Zone Transport Properties (U0100)

    SciTech Connect (OSTI)

    J. Conca

    2000-12-20

    This Analysis/Model Report (AMR) summarizes transport properties for the lower unsaturated zone hydrogeologic units and the saturated zone at Yucca Mountain and provides a summary of data from the Busted Butte Unsaturated Zone Transport Test (UZTT). The purpose of this report is to summarize the sorption and transport knowledge relevant to flow and transport in the units below Yucca Mountain and to provide backup documentation for the sorption parameters decided upon for each rock type. Because of the complexity of processes such as sorption, and because of the lack of direct data for many conditions that may be relevant for Yucca Mountain, data from systems outside of Yucca Mountain are also included. The data reported in this AMR will be used in Total System Performance Assessment (TSPA) calculations and as general scientific support for various Process Model Reports (PMRs) requiring knowledge of the transport properties of different materials. This report provides, but is not limited to, sorption coefficients and other relevant thermodynamic and transport properties for the radioisotopes of concern, especially neptunium (Np), plutonium (Pu), Uranium (U), technetium (Tc), iodine (I), and selenium (Se). The unsaturated-zone (UZ) transport properties in the vitric Calico Hills (CHv) are discussed, as are colloidal transport data based on the Busted Butte UZTT, the saturated tuff, and alluvium. These values were determined through expert elicitation, direct measurements, and data analysis. The transport parameters include information on interactions of the fractures and matrix. In addition, core matrix permeability data from the Busted Butte UZTT are summarized by both percent alteration and dispersion.

  16. Biotic and Abiotic Transformation of a Volatile Organics Plume in a Semi-Arid Vadose Zone

    SciTech Connect (OSTI)

    Studer, J.E.; Singletary, M.A.; Miller, D.R.

    1999-04-08

    An evaluation of biotic and abiotic attenuation processes potentially important to chlorinated and non-chlorinated volatile organic compound (VOC) fate and transport in the 148 meter thick vadose zone beneath the Chemical Waste Landfill (CWL) was conducted. A unique feature of this evaluation is the comparison of two estimates of VOC mass present in the soil gas, pore-water, and solid phases (but not including mass as non-aqueous phase liquid [NAPL]) of the vadose zone in 1993. One estimate, 1,800 kg, was obtained from vadose zone transport modeling that incorporated molecular diffusion and volatilization to the atmosphere, but not biotic or chemical processes. The other estimate, 2,120 kg, was obtained from the sum of VOC mass physically removed during soil vapor extraction and an estimate of VOC mass remaining in the vadose zone in 1998, both adjusted to exclude NAPL mass. This comparison indicates that biogeochemical processes were at best slightly important to historical VOC plume development. Some evidence of aerobic degradation of non-chlorinated VOCs and abiotic transformation of 1,1,1-Trichloroethane was identified. Despite potentially amenable site conditions, no evidence was found of cometabolic and anaerobic transformation pathways. Relying principally on soil-gas analytical results, an upper-bound estimate of 21% mass reduction due to natural biogeochemical processes was developed. Although available information for the CWL indicates that natural attenuation processes other than volatilization to the atmosphere did not effective y enhance groundwater protection, these processes could be important in significantly reducing groundwater contamination and exposure risks at other sites. More laboratory and field research is required to improve our collective ability to characterize and exploit natural VOC attenuation processes, especially with respect to the combination of relatively thick and dry vadose zones and chlorinated VOCs.

  17. Mixing of Isotactic and Syndiotactic Polypropylenes in the Melt

    SciTech Connect (OSTI)

    CLANCY,THOMAS C.; PUTZ,MATHIAS; WEINHOLD,JEFFREY D.; CURRO,JOHN G.; MATTICE,WAYNE L.

    2000-07-14

    The miscibility of polypropylene (PP) melts in which the chains differ only in stereochemical composition has been investigated by two different procedures. One approach used detailed local information from a Monte Carlo simulation of a single chain, and the other approach takes this information from a rotational isomeric state model devised decades ago, for another purpose. The first approach uses PRISM theory to deduce the intermolecular packing in the polymer blend, while the second approach uses a Monte Carlo simulation of a coarse-grained representation of independent chains, expressed on a high-coordination lattice. Both approaches find a positive energy change upon mixing isotactic PP (iPP) and syndiotactic polypropylene (sPP) chains in the melt. This conclusion is qualitatively consistent with observations published recently by Muelhaupt and coworkers. The size of the energy chain on mixing is smaller in the MC/PRISM approach than in the RIS/MC simulation, with the smaller energy change being in better agreement with the experiment. The RIS/MC simulation finds no demixing for iPP and atactic polypropylene (aPP) in the melt, consistent with several experimental observations in the literature. The demixing of the iPP/sPP blend may arise from attractive interactions in the sPP melt that are disrupted when the sPP chains are diluted with aPP or iPP chains.

  18. Laser beam surface melting of high alloy austenitic stainless steel

    SciTech Connect (OSTI)

    Woollin, P.

    1996-12-31

    The welding of high alloy austenitic stainless steels is generally accompanied by a substantial reduction in pitting corrosion resistance relative to the parent, due to microsegregation of Mo and Cr. This prevents the exploitation of the full potential of these steels. Processing to achieve remelting and rapid solidification offers a means of reducing microsegregation levels and improving corrosion resistance. Surface melting of parent UNS S31254 steel by laser beam has been demonstrated as a successful means of producing fine, as-solidified structures with pitting resistance similar to that of the parent, provided that an appropriate minimum beam travel speed is exceeded. The use of N{sub 2} laser trail gas increased the pitting resistance of the surface melted layer. Application of the technique to gas tungsten arc (GTA) melt runs has shown the ability to raise the pitting resistance significantly. Indeed, the use of optimized beam conditions, N{sub 2} trail gas and appropriate surface preparation prior to laser treatment increased the pitting resistance of GTA melt runs to a level approaching that of the parent material.

  19. Decontamination of steel by melt refining: A literature review

    SciTech Connect (OSTI)

    Ozturk, B.; Fruehan, R.J.

    1994-12-31

    It has been reported that a large amount of metal waste is produced annually by nuclear fuel processing and nuclear power plants. These metal wastes are contaminated with radioactive elements, such as uranium and plutonium. Current Department of Energy guidelines require retrievable storage of all metallic wastes containing transuranic elements above a certain level. Because of high cost, it is important to develop an effective decontamination and volume reduction method for low level contaminated metals. It has been shown by some investigators that a melt refining technique can be used for the processing of the contaminated metal wastes. In this process, contaminated metal is melted wit a suitable flux. The radioactive elements are oxidized and transferred to a slag phase. In order to develop a commercial process it is important to have information on the thermodynamics and kinetics of the removal. Therefore, a literature search was carried out to evaluate the available information on the decontamination uranium and transuranic-contaminated plain steel, copper and stainless steel by melt a refining technique. Emphasis was given to the thermodynamics and kinetics of the removal. Data published in the literature indicate that it is possible to reduce the concentration of radioactive elements to a very low level by the melt refining method. 20 refs.

  20. Decontamination of transuranic contaminated metals by melt refining

    SciTech Connect (OSTI)

    Heshmatpour, B.; Copeland, G.L.; Heestand, R.L.

    1983-01-01

    Melt refining of transuranic contaminated metals is a possible decontamination process with the potential advantages of producing metal for reuse and of simplifying chemical analyses. By routinely achieving the 10 nCi/g( about0.1ppm) level by melt refining, scrap metal can be removed from the transuranic waste category. (To demonstrate the effectiveness of this melt refining process, mild steel, stainless steel, nickel, and copper were contaminated with 500 ppm (..mu..g/g) PuO/sub 2/ and melted with various fluxes. The solidified slags and metals were analyzed for their plutonium contents, and corresponding partition ratios for plutonium were calculated. Some metals were double refined in order to study the effect of secondary slag treatment. The initial weight of the slags was also varied to investigate the effect of slag weight on the degree of plutonium removal. In general, all four metals could be decontaminated below 1 ppm (..mu..g/g) Pu ( about100 nCi/g) by a single slag treatment. Doubling the slag weight did not improve decontamination significantly; however, double slag treatment using 5 wt.% slag did decontaminate the metals to below 0.1 ppm (..mu..g/g) Pu (10 nCi/g).)

  1. Structural Properties and Melting of 2D-Plasma Crystals

    SciTech Connect (OSTI)

    Knapek, C.; Samsonov, D.; Zhdanov, S.; Konopka, U.; Morfill, G.E.

    2005-10-31

    Melting of a monolayer plasma crystal was induced by an electric pulse. We investigated, how structural parameters like defect fraction and correlation lengths as well as dynamical properties like the particle kinetic energy changed during the recrystallisation. As an indication of the phase transition, the change of the Lindemann parameter and the Coulomb coupling parameter were considered.

  2. Decontamination and melting of low-level waste

    SciTech Connect (OSTI)

    Clements, D.W.

    1997-03-01

    This article describes the decommissioning project of the Capenhurst Diffusion Plant in Europe. Over 99 percent of the low-level waste was successfully treated and recycled. Topics include the following: decommissioning philosophy; specialized techniques including plant pretreatment, plant dismantling, size reduction, decontamination, melting, and encapsulation of waste; recycled materials and waste stream; project safety; cost drivers and savings. 5 refs., 5 figs.

  3. Energy Saving Melting and Revert Reduction Technology: Innovative Semi-Solid Metal (SSM) Processing

    SciTech Connect (OSTI)

    Diran Apelian

    2012-08-15

    Semi-solid metal (SSM) processing has emerged as an attractive method for near-net-shape manufacturing due to the distinct advantages it holds over conventional near-net-shape forming technologies. These advantages include lower cycle time, increased die life, reduced porosity, reduced solidification shrinkage, improved mechanical properties, etc. SSM processing techniques can not only produce the complex dimensional details (e.g. thin-walled sections) associated with conventional high-pressure die castings, but also can produce high integrity castings currently attainable only with squeeze and low-pressure permanent mold casting processes. There are two primary semi-solid processing routes, (a) thixocasting and (b) rheocasting. In the thixocasting route, one starts from a non-dendritic solid precursor material that is specially prepared by a primary aluminum manufacturer, using continuous casting methods. Upon reheating this material into the mushy (a.k.a. "two-phase") zone, a thixotropic slurry is formed, which becomes the feed for the casting operation. In the rheocasting route (a.k.a. "slurry-on-demand" or "SoD"), one starts from the liquid state, and the thixotropic slurry is formed directly from the melt via careful thermal management of the system; the slurry is subsequently fed into the die cavity. Of these two routes, rheocasting is favored in that there is no premium added to the billet cost, and the scrap recycling issues are alleviated. The CRP (Trade Marked) is a process where the molten metal flows through a reactor prior to casting. The role of the reactor is to ensure that copious nucleation takes place and that the nuclei are well distributed throughout the system prior to entering the casting cavity. The CRP (Trade Marked) has been successfully applied in hyper-eutectic Al-Si alloys (i.e., 390 alloy) where two liquids of equal or different compositions and temperatures are mixed in the reactor and creating a SSM slurry. The process has been mostly

  4. Eastern Energy Zones Mapping Tool

    Broader source: Energy.gov [DOE]

    The Eastern Interconnection States’ Planning Council (EISPC) has released the Energy Zones (EZ) Mapping Tool, a free, web-based interactive tool that will help states and other stakeholders in the Eastern Interconnection identify geographic areas suitable for the development of clean energy resources (natural gas, sequestration or utilitization locations for C02 from coal, nuclear, and renewable) which can potentially provide significant amounts of new electric power generation.

  5. TASK 2: QUENCH ZONE SIMULATION

    SciTech Connect (OSTI)

    Fusselman, Steve

    2015-09-30

    Aerojet Rocketdyne (AR) has developed an innovative gasifier concept incorporating advanced technologies in ultra-dense phase dry feed system, rapid mix injector, and advanced component cooling to significantly improve gasifier performance, life, and cost compared to commercially available state-of-the-art systems. A key feature of the AR gasifier design is the transition from the gasifier outlet into the quench zone, where the raw syngas is cooled to ~ 400°C by injection and vaporization of atomized water. Earlier pilot plant testing revealed a propensity for the original gasifier outlet design to accumulate slag in the outlet, leading to erratic syngas flow from the outlet. Subsequent design modifications successfully resolved this issue in the pilot plant gasifier. In order to gain greater insight into the physical phenomena occurring within this zone, AR developed a cold flow simulation apparatus with Coanda Research & Development with a high degree of similitude to hot fire conditions with the pilot scale gasifier design, and capable of accommodating a scaled-down quench zone for a demonstration-scale gasifier. The objective of this task was to validate similitude of the cold flow simulation model by comparison of pilot-scale outlet design performance, and to assess demonstration scale gasifier design feasibility from testing of a scaled-down outlet design. Test results did exhibit a strong correspondence with the two pilot scale outlet designs, indicating credible similitude for the cold flow simulation device. Testing of the scaled-down outlet revealed important considerations in the design and operation of the demonstration scale gasifier, in particular pertaining to the relative momentum between the downcoming raw syngas and the sprayed quench water and associated impacts on flow patterns within the quench zone. This report describes key findings from the test program, including assessment of pilot plant configuration simulations relative to actual

  6. REACTIVE MULTIPHASE BEHAVIOR OF CO2 IN SALINE AQUIFERS BENEATH THE COLORADO PLATEAU

    SciTech Connect (OSTI)

    R.G. Allis; J. Moore; S. White

    2003-01-30

    Gas reservoirs developed within the Colorado Plateau and Southern Rocky Mountains region are natural laboratories for studying the factors that promote long-term storage of CO{sub 2}. They also provide sites for storing additional CO{sub 2} if it can be separated from the flue gases of coal-fired power plants in this part of the U.S.A. These natural reservoirs are developed primarily in sandstones and dolomites; shales, mudstones and anhydrite form seals. In many fields, stacked reservoirs are present, indicating that the gas has migrated up through the section. There are also geologically young travertine deposits at the surface, and CO{sub 2}-charged groundwater and springs in the vicinity of known CO{sub 2} occurrences. These near-surface geological and hydrological features also provide examples of the environmental effects of leakage of CO{sub 2} from reservoirs, and justify further study. During reporting period covered here (the first quarter of Year 3 of the project, i.e. October 1-December 31, 2002), the main achievements were: (1) Planning workshop for project participants as well as other Utah researchers involved in CO{sub 2} projects (22 October, 2002), and Utah Geological Survey, Salt Lake City; (2) Presentation of paper to special CO{sub 2} sequestration session at the Geological Society of America Annual Meeting, Denver, 29 October, 2002; (3) Presentation of paper to special CO{sub 2} sequestration session at the Fall Meeting of American Geophysical Union, San Francisco, 10 December, 2002; (4) Identification of dawsonite (sodium-aluminum carbonate) as a late stage mineral deposited in CO{sub 2} feedzone at Springerville, Arizona; (5) Successful matching of known physical constraints to flow beneath the Hunter cross section being used to simulate the effects of CO{sub 2} injection. In about 1000 years, most injected CO{sub 2} may be lost to the surface from the three shallowest reservoirs considered, assuming no reactive processes; and (6) Inclusion

  7. Pellet Zone Ltd | Open Energy Information

    Open Energy Info (EERE)

    Pellet Zone Ltd Jump to: navigation, search Name: Pellet Zone Ltd Place: England, United Kingdom Zip: NR19 1AE Sector: Biomass Product: UK based biomass pellet trading firm....

  8. Climate Zone 8B | Open Energy Information

    Open Energy Info (EERE)

    Subtype B. Climate Zone 8B is defined as Subarctic with IP Units 12600 < HDD65F and SI Units 7000 < HDD18C . The following places are categorized as class 8B climate zones:...

  9. Climate Zone 8A | Open Energy Information

    Open Energy Info (EERE)

    A. Climate Zone Number 8A is defined as Subarctic with IP Units 12600 < HDD65F and SI Units 7000 < HDD18C . The following places are categorized as class 8A climate zones:...

  10. Climate Zone 1A | Open Energy Information

    Open Energy Info (EERE)

    A. Climate Zone 1A is defined as Very Hot - Humid with IP Units 9000 < CDD50F and SI Units 5000 < CDD10C . The following places are categorized as class 1A climate zones:...

  11. Climate Zone Number 5 | Open Energy Information

    Open Energy Info (EERE)

    Climate Zone Number 5 Jump to: navigation, search A type of climate defined in the ASHRAE 169-2006 standard. Climate Zone Number 5 is defined as Cool- Humid(5A) with IP Units 5400...

  12. Farmland Security Zone | Open Energy Information

    Open Energy Info (EERE)

    Security Zone Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- OtherOther: Farmland Security ZoneLegal Abstract California Department of...

  13. Internal zone growth method for producing metal oxide metal eutectic composites

    DOE Patents [OSTI]

    Clark, Grady W.; Holder, John D.; Pasto, Arvid E.

    1980-01-01

    An improved method for preparing a cermet comprises preparing a compact having about 85 to 95 percent theoretical density from a mixture of metal and metal oxide powders from a system containing a eutectic composition, and inductively heating the compact in a radiofrequency field to cause the formation of an internal molten zone. The metal oxide particles in the powder mixture are effectively sized relative to the metal particles to permit direct inductive heating of the compact by radiofrequency from room temperature. Surface melting is prevented by external cooling or by effectively sizing the particles in the powder mixture.

  14. Microstructure of selective laser melted nickeltitanium

    SciTech Connect (OSTI)

    Bormann, Therese; Mller, Bert; Kessler, Anja; Thalmann, Peter

    2014-08-15

    In selective laser melting, the layer-wise local melting of metallic powder by means of a scanning focused laser beam leads to anisotropic microstructures, which reflect the pathway of the laser beam. We studied the impact of laser power, scanning speed, and laser path onto the microstructure of NiTi cylinders. Here, we varied the laser power from 56 to 100 W and the scanning speed from about 100 to 300 mm/s. In increasing the laser power, the grain width and length increased from (33 7) to (90 15) ?m and from (60 20) to (600 200) ?m, respectively. Also, the grain size distribution changed from uni- to bimodal. Ostwald-ripening of the crystallites explains the distinct bimodal size distributions. Decreasing the scanning speed did not alter the microstructure but led to increased phase transformation temperatures of up to 40 K. This was experimentally determined using differential scanning calorimetry and explained as a result of preferential nickel evaporation during the fabrication process. During selective laser melting of the NiTi shape memory alloy, the control of scanning speed allows restricted changes of the transformation temperatures, whereas controlling the laser power and scanning path enables us to tailor the microstructure, i.e. the crystallite shapes and arrangement, the extent of the preferred crystallographic orientation and the grain size distribution. - Highlights: Higher laser powers during selective laser melting of NiTi lead to larger grains. Selective laser melting of NiTi gives rise to preferred <111> orientation. The observed Ni/Ti ratio depends on the exposure time. Ostwald ripening explains the bimodal grain size distribution.

  15. Zero Zone Comment | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Zero Zone Comment Zero Zone Comment These comments are submitted by Zero Zone Inc., a manufacturer of CRE equipment, in response to the U.S. Department of Energy's (DOE) notice in the July 3, 2014 Federal Register requesting information to assist DOE in reviewing existing regulations and in making its regulatory program more effective and less burdensome. Zero Zone comments (101.48 KB) More Documents & Publications Regulatory Burden RFI Executive Order 13563 certification, compliance and

  16. Barron County, Wisconsin ASHRAE 169-2006 Climate Zone | Open...

    Open Energy Info (EERE)

    Barron County, Wisconsin ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Barron County, Wisconsin ASHRAE Standard ASHRAE 169-2006 Climate Zone...

  17. Becker County, Minnesota ASHRAE 169-2006 Climate Zone | Open...

    Open Energy Info (EERE)

    Becker County, Minnesota ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Becker County, Minnesota ASHRAE Standard ASHRAE 169-2006 Climate Zone...

  18. Alfalfa County, Oklahoma ASHRAE 169-2006 Climate Zone | Open...

    Open Energy Info (EERE)

    Alfalfa County, Oklahoma ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Alfalfa County, Oklahoma ASHRAE Standard ASHRAE 169-2006 Climate Zone...

  19. Atkinson County, Georgia ASHRAE 169-2006 Climate Zone | Open...

    Open Energy Info (EERE)

    Atkinson County, Georgia ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Atkinson County, Georgia ASHRAE Standard ASHRAE 169-2006 Climate Zone...

  20. Central Nevada Seismic Zone Geothermal Region | Open Energy Informatio...

    Open Energy Info (EERE)

    Central Nevada Seismic Zone Geothermal Region (Redirected from Central Nevada Seismic Zone) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Central Nevada Seismic Zone...

  1. Adams County, Mississippi ASHRAE 169-2006 Climate Zone | Open...

    Open Energy Info (EERE)

    Adams County, Mississippi ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Adams County, Mississippi ASHRAE Standard ASHRAE 169-2006 Climate Zone...

  2. Anderson County, Kentucky ASHRAE 169-2006 Climate Zone | Open...

    Open Energy Info (EERE)

    Anderson County, Kentucky ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Anderson County, Kentucky ASHRAE Standard ASHRAE 169-2006 Climate Zone...

  3. Advanced Melting Technologies: Energy Saving Concepts and Opportunities for the Metal Casting Industry

    SciTech Connect (OSTI)

    none,

    2005-11-01

    The study examines current and emerging melting technologies and discusses their technical barriers to scale-up issues and research needed to advance these technologies, improving melting efficiency, lowering metal transfer heat loss, and reducing scrap.

  4. Exploration of Melt Spinning as a Route to Large Volume Production of Skutterudite Thermoelectric Materials

    Broader source: Energy.gov [DOE]

    Melt spinning combined with Spark Plasma Sintering provides a potential route to the mass production of Skutterudite based thermoelectric materials

  5. Molecular dynamics simulations of the melting curve of NiAl alloy under pressure

    SciTech Connect (OSTI)

    Zhang, Wenjin; Peng, Yufeng; Liu, Zhongli

    2014-05-15

    The melting curve of B2-NiAl alloy under pressure has been investigated using molecular dynamics technique and the embedded atom method (EAM) potential. The melting temperatures were determined with two approaches, the one-phase and the two-phase methods. The first one simulates a homogeneous melting, while the second one involves a heterogeneous melting of materials. Both approaches reduce the superheating effectively and their results are close to each other at the applied pressures. By fitting the well-known Simon equation to our melting data, we yielded the melting curves for NiAl: 1783(1 + P/9.801){sup 0.298} (one-phase approach), 1850(1 + P/12.806){sup 0.357} (two-phase approach). The good agreement of the resulting equation of states and the zero-pressure melting point (calc., 1850 25 K, exp., 1911 K) with experiment proved the correctness of these results. These melting data complemented the absence of experimental high-pressure melting of NiAl. To check the transferability of this EAM potential, we have also predicted the melting curves of pure nickel and pure aluminum. Results show the calculated melting point of Nickel agrees well with experiment at zero pressure, while the melting point of aluminum is slightly higher than experiment.

  6. An Integrated Method for Accurate Determination of Melting in High-Pressure Laser Heating Experiments

    SciTech Connect (OSTI)

    Benedetti, L R; Antonangeli, D; Farber, D L; Mezouar, M

    2007-11-19

    We present an integrated approach for melting determination by monitoring several criteria simultaneously. In particular we combine x-ray diffraction observations with the detection of discontinuities in the optical properties by spectroradiometric measurements. This approach significantly increases the confidence of melt identification, especially with low-Z samples. We demonstrate the method with observations of melt in oxygen at 47 and 55 gigapascals.

  7. Vadose zone transport field study: Detailed test plan for simulated leak tests

    SciTech Connect (OSTI)

    AL Ward; GW Gee

    2000-06-23

    The US Department of Energy (DOE) Groundwater/Vadose Zone Integration Project Science and Technology initiative was created in FY 1999 to reduce the uncertainty associated with vadose zone transport processes beneath waste sites at DOE's Hanford Site near Richland, Washington. This information is needed not only to evaluate the risks from transport, but also to support the adoption of measures for minimizing impacts to the groundwater and surrounding environment. The principal uncertainties in vadose zone transport are the current distribution of source contaminants and the natural heterogeneity of the soil in which the contaminants reside. Oversimplified conceptual models resulting from these uncertainties and limited use of hydrologic characterization and monitoring technologies have hampered the understanding contaminant migration through Hanford's vadose zone. Essential prerequisites for reducing vadose transport uncertainly include the development of accurate conceptual models and the development or adoption of monitoring techniques capable of delineating the current distributions of source contaminants and characterizing natural site heterogeneity. The Vadose Zone Transport Field Study (VZTFS) was conceived as part of the initiative to address the major uncertainties confronting vadose zone fate and transport predictions at the Hanford Site and to overcome the limitations of previous characterization attempts. Pacific Northwest National Laboratory (PNNL) is managing the VZTFS for DOE. The VZTFS will conduct field investigations that will improve the understanding of field-scale transport and lead to the development or identification of efficient and cost-effective characterization methods. Ideally, these methods will capture the extent of contaminant plumes using existing infrastructure (i.e., more than 1,300 steel-cased boreholes). The objectives of the VZTFS are to conduct controlled transport experiments at well-instrumented field sites at Hanford to

  8. Low melting high lithia glass compositions and methods

    DOE Patents [OSTI]

    Jantzen, Carol M.; Pickett, John B.; Cicero-Herman, Connie A.; Marra, James C.

    2003-09-23

    The invention relates to methods of vitrifying waste and for lowering the melting point of glass forming systems by including lithia formers in the glass forming composition in significant amounts, typically from about 0.16 wt % to about 11 wt %, based on the total glass forming oxides. The lithia is typically included as a replacement for alkali oxide glass formers that would normally be present in a particular glass forming system. Replacement can occur on a mole percent or weight percent basis, and typically results in a composition wherein lithia forms about 10 wt % to about 100 wt % of the alkali oxide glass formers present in the composition. The present invention also relates to the high lithia glass compositions formed by these methods. The invention is useful for stabilization of numerous types of waste materials, including aqueous waste uranium oxides The decrease in melting point achieved by the present invention desirably prevents volatilization of hazardous or radioactive species during vitrification.

  9. Microstructure Development in Electron Beam-Melted Inconel 718 and Associated Tensile Properties

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kirka, M. M.; Unocic, K. A.; Raghavan, N.; Medina, F.; Dehoff, R. R.; Babu, S. S.

    2016-02-12

    During the electron beam melting (EBM) process, builds occur at temperatures in excess of 800°C for nickel-base superalloys such as Inconel 718. When coupled with the temporal differences between the start and end of a build, a top-to-bottom microstructure gradient forms. Characterized in this study is the microstructure gradient and associated tensile property gradient that are common to all EBM Inconel 718 builds. From the characteristic microstructure elements observed in EBM Inconel 718 material, the microstructure gradient can be classified into three distinct regions. Region 1 (top of a build) and is comprised of a cored dendritic structure that includesmore » carbides and Laves phase within the interdendritic regions. Region 2 is an intermediate transition zone characterized by a diffuse dendritic structure, dissolution of the Laves phase, and precipitation of δ needle networks within the interdendritic regions. The bulk structure (Region 3) is comprised of a columnar grain structure lacking dendritic characteristics with δ networks having precipitated within the grain interiors. Mechanically at both 20°C and 650° C, the yield strength, ultimate tensile strength, and elongation at failure exhibit the general trend of increasing with increasing build height.« less

  10. Method of melting metals to reduce contamination from crucibles

    DOE Patents [OSTI]

    Banker, John G.; Wigginton, Hubert L.

    1977-01-01

    Contamination of metals from crucible materials during melting operations is reduced by coating the interior surface of the crucible with a ceramic non-reactive with the metallic charge and disposing a metal liner formed from a portion of the metallic charge within the coated crucible. The liner protects the ceramic coating during loading of the remainder of the charge and expands against the ceramic coating during heat-up to aid in sintering the coating.

  11. Advanced coal-fired glass melting development program

    SciTech Connect (OSTI)

    Not Available

    1991-05-01

    The objective of Phase 1 of the current contract was to verify the technical feasibility and economic benefits of Vortec's advanced combustion/melting technology using coal as the fuel of choice. The objective of the Phase 2 effort was to improve the performance of the primary components and demonstrate the effective operation of a subscale process heater system integrated with a glass separator/reservoir. (VC)

  12. Distribution of radionuclides during melting of carbon steel

    SciTech Connect (OSTI)

    Thurber, W.C.; MacKinney, J.

    1997-02-01

    During the melting of steel with radioactive contamination, radionuclides may be distributed among the metal product, the home scrap, the slag, the furnace lining and the off-gas collection system. In addition, some radionuclides will pass through the furnace system and vent to the atmosphere. To estimate radiological impacts of recycling radioactive scrap steel, it is essential to understand how radionuclides are distributed within the furnace system. For example, an isotope of a gaseous element (e.g., radon) will exhaust directly from the furnace system into the atmosphere while a relatively non-volatile element (e.g., manganese) can be distributed among all the other possible media. This distribution of radioactive contaminants is a complex process that can be influenced by numerous chemical and physical factors, including composition of the steel bath, chemistry of the slag, vapor pressure of the particular element of interest, solubility of the element in molten iron, density of the oxide(s), steel melting temperature and melting practice (e.g., furnace type and size, melting time, method of carbon adjustment and method of alloy additions). This paper discusses the distribution of various elements with particular reference to electric arc furnace steelmaking. The first two sections consider the calculation of partition ratios for elements between metal and slag based on thermodynamic considerations. The third section presents laboratory and production measurements of the distribution of various elements among slag, metal, and the off-gas collection system; and the final section provides recommendations for the assumed distribution of each element of interest.

  13. Melt processing of radioactive waste: A technical overview

    SciTech Connect (OSTI)

    Schlienger, M.E.; Buckentin, J.M.; Damkroger, B.K.

    1997-04-01

    Nuclear operations have resulted in the accumulation of large quantities of contaminated metallic waste which are stored at various DOE, DOD, and commercial sites under the control of DOE and the Nuclear Regulatory Commission (NRC). This waste will accumulate at an increasing rate as commercial nuclear reactors built in the 1950s reach the end of their projected lives, as existing nuclear powered ships become obsolete or unneeded, and as various weapons plants and fuel processing facilities, such as the gaseous diffusion plants, are dismantled, repaired, or modernized. For example, recent estimates of available Radioactive Scrap Metal (RSM) in the DOE Nuclear Weapons Complex have suggested that as much as 700,000 tons of contaminated 304L stainless steel exist in the gaseous diffusion plants alone. Other high-value metals available in the DOE complex include copper, nickel, and zirconium. Melt processing for the decontamination of radioactive scrap metal has been the subject of much research. A major driving force for this research has been the possibility of reapplication of RSM, which is often very high-grade material containing large quantities of strategic elements. To date, several different single and multi-step melting processes have been proposed and evaluated for use as decontamination or recycling strategies. Each process offers a unique combination of strengths and weaknesses, and ultimately, no single melt processing scheme is optimum for all applications since processes must be evaluated based on the characteristics of the input feed stream and the desired output. This paper describes various melt decontamination processes and briefly reviews their application in developmental studies, full scale technical demonstrations, and industrial operations.

  14. Melt-spin processing of high {Tc} oxide superconductors

    SciTech Connect (OSTI)

    Folkerts, T.J.; Wu, Hengning; Yoo, S.I.; Merkle, B.D.; Arrasmith, S.R.; Dennis, K.W.; Kramer, M.J.; McCallum, R.W.

    1993-10-01

    Containerless techniques offer distinct advantages for the melt processing of oxide superconductors. The majority of these materials form liquids which are highly reactive with standard crucible materials such as Al{sub 2}O{sub 3} and Pt, resulting in non-negligible contamination. We have developed a containerless melt-spin processing technique where in 50--400 {mu}m particles of REBa{sub 2}Cu{sub 3}O{sub 7-x} high temperature oxide superconductors are melted in free fall through a vertical tube furnace and quenched onto a copper wheel. Previously this method has been successful in producing glasses of NdBa{sub 2}Cu{sub 3}O{sub 7-x} and GdBa{sub 2}Cu{sub 3}O{sub 7-x}. In this report we discuss the results for both stoichiometric and non-stoichiometric YBa{sub 2}Cu{sub 3}O{sub 7-x} (Y123). Thermal, microstructural, and superconducting characterization of both the as-quenched and the annealed materials will be presented.

  15. U.S. Climate Zones Map for Commercial Buildings

    U.S. Energy Information Administration (EIA) Indexed Site

    U.S. Climate Zone U. S. Climate Zones for 2003 CBECS: climate zones map Note:Map updated with corrections, February 2012 Further Explanation on How Climate Zones are Defined...

  16. U.S. Climate Zones Map for Commercial Buildings

    U.S. Energy Information Administration (EIA) Indexed Site

    Past Climate Zones U. S. Climate Zones for 1979-1999 CBECS: climate zone map Return to Climate Zones for 2003 CBECS Return to CBECS Home Page Note:Map updated with corrections,...

  17. Property:ASHRAE 169 Climate Zone Subtype | Open Energy Information

    Open Energy Info (EERE)

    A + Adair County, Oklahoma ASHRAE 169-2006 Climate Zone + Climate Zone Subtype A + Adams County, Colorado ASHRAE 169-2006 Climate Zone + Climate Zone Subtype B + Adams County,...

  18. Property:ASHRAE 169 Climate Zone Number | Open Energy Information

    Open Energy Info (EERE)

    5 + Adair County, Oklahoma ASHRAE 169-2006 Climate Zone + Climate Zone Number 3 + Adams County, Colorado ASHRAE 169-2006 Climate Zone + Climate Zone Number 5 + Adams County,...

  19. REACTIVE MULTIPHASE BEHAVIOR OF CO{sub 2} IN SALINE AQUIFERS BENEATH THE COLORADO PLATEAU

    SciTech Connect (OSTI)

    R.G. Allis; J. Moore; S. White

    2005-02-08

    Soil gas surveys have been carried out on the Colorado Plateau over areas with natural occurrences of CO{sub 2}. At Farnham Dome, Utah, and Springerville-St. Johns, Arizona, proven CO{sub 2} reservoirs occur at 600-800 m depth, but no anomalous soil gas CO{sub 2} flux was detected. Background CO{sub 2} fluxes of up to about 5 g m{sup -2} day{sup -1} were common in arid, poorly vegetated areas, and fluxes up to about 20 g m{sup -2} day{sup -1} were found at Springerville-St. Johns in heavily vegetated, wet ground adjacent to springs. These elevated fluxes are attributed to shallow root zone activity rather than to a deep upflow of CO{sub 2}. Localized areas of anomalously high CO{sub 2} gas flux ({approx} 100 g m{sup -2} day{sup -1}) were documented along the Little Grand Wash Fault Zone near Crystal Geyser, Utah and nearby in Ten Mile Graben, but those in Ten Mile Graben are not directly associated with the major faults. In both areas, features with a visible gas flux are present. Isotopic measurements on the CO{sub 2} gas confirm that it originated at depth. Evidence of widespread vein calcite at the surface at Farnham Dome and travertine deposits in the other areas suggests that there has been an outflow of CO{sub 2}-rich fluids in the past. 14C ages of pollen trapped in the travertine at Springerville-St. Johns record a period of CO{sub 2} leakage to the atmosphere between 887 {+-} 35 and 3219 {+-} 30 years BP. No travertine deposits appear to be currently forming. At Springerville-St. Johns, Crystal Geyser and Ten Mile Graben, there are significant outflows of high-bicarbonate water. Movement of CO{sub 2}-rich groundwaters may be the dominant mechanism controlling the mobility of CO{sub 2} today. The very localized nature of the soil gas anomalies, evidence of large scale discharge of CO{sub 2} over a very short period of time and the outflow of ground water containing dissolved CO{sub 2} will present challenges for effective, long term monitoring of CO{sub 2

  20. Removing a sheet from the surface of a melt using gas jets

    DOE Patents [OSTI]

    Kellerman, Peter L; Thronson, Gregory D; Sun, Dawei

    2014-04-01

    In one embodiment, a sheet production apparatus comprises a vessel configured to hold a melt of a material. A cooling plate is disposed proximate the melt and is configured to form a sheet of the material on the melt. A first gas jet is configured to direct a gas toward an edge of the vessel. A sheet of a material is translated horizontally on a surface of the melt and the sheet is removed from the melt. The first gas jet may be directed at the meniscus and may stabilize this meniscus or increase local pressure within the meniscus.

  1. Implementation Plan for the Deep Vadose Zone-Applied Field Research Center

    SciTech Connect (OSTI)

    Wellman, Dawn M.; Truex, Michael J.; Freshley, Mark D.; Gephart, Roy E.; Triplett, Mark B.; Johnson, Timothy C.

    2011-02-11

    The Long-Range Deep Vadose Zone Program Plan was published in October 2010. It summarized the U.S. Department of Energy’s (DOE’s) state-of-knowledge about the contaminant remediation challenges facing the deep vadose zone (DVZ) beneath the Central Plateau of the Hanford Site and their approach to solving those challenges. Developing an implementation plan is the next step to address the knowledge and capabilities required to solve DVZ challenges when needed. This multi-year plan (FY-11 through FY-20) identifies the short to long-term research, management, and execution plans required to solve those problems facing the DVZ-Applied Field Research Center (DVZ-AFRC). The schedule supporting implementation overlies existing activities and milestones from Hanford’s DOE-Environmental Management (EM) end-user projects. Success relies upon multi-project teams focused on coordinated subsurface projects undertaken across the DOE Complex combined with facilitated, problem-focused, research investments implemented through the DVZ-AFRC.

  2. REACTIVE MULTIPHASE BEHAVIOR OF CO2 IN SALINE AQUIFERS BENEATH THE COLORADO PLATEAU

    SciTech Connect (OSTI)

    R.G. Allis; J. Moore; S. White

    2005-05-16

    Soil CO{sub 2} flux surveys have been conducted over known CO{sub 2} reservoirs at Farnham Dome, Utah, Crystal Geyser-Ten Mile Graben in Utah and Springerville-St. Johns, Arizona. No anomalous CO{sub 2} flux was detected at the Farnham Dome and Springerville-St. Johns. At Crystal Geyser-Ten Mile Graben, localized areas of anomalously high CO{sub 2} flux ({approx}100 g m{sup -2} day{sup -1}) occur along a fault zone near visibly degassing features. Isotopic measurements on CO{sub 2} collected from nearby springs indicate that it originated at depth. Evidence of widespread vein calcite at the surface (Farnham Dome) and travertine deposits at the other two areas suggests that discharge of CO{sub 2}-rich fluids has occurred in the past. Despite the lack of evidence for significant present day leakage of CO{sub 2} to the atmosphere at Springerville-St. Johns and Crystal Geyser-Ten Mile Graben, there are significant outflows of high-bicarbonate water in both areas suggesting continuous migration of CO{sub 2} in the aqueous phase from depth. The very localized nature of the CO{sub 2} flux anomalies, and the outflow of ground water containing dissolved CO{sub 2} present challenges for effective, long term monitoring of CO{sub 2} leakage.

  3. Applied Field Research Initiative Deep Vadose Zone

    Office of Environmental Management (EM)

    Applied Field Research Initiative Deep Vadose Zone Located on the Hanford Site in Richland, Washington, the Deep Vadose Zone Applied Field Research Initiative (DVZ AFRI) was established to protect water resources by addressing the challenge of preventing contamination in the deep vadose zone from reaching groundwater. Led by the Pacific Northwest National Laboratory, the Initiative is a collaborative effort that leverages Department of Energy (DOE) investments in basic science and applied

  4. Coastal Zone Management Act and Regulations (NOAA)

    Broader source: Energy.gov [DOE]

    The Coastal Zone Management Act (CZMA) of 1972 provides for the management of the nation’s coastal resources, including the Great Lakes.

  5. Washington Coastal Zone Management Regulatory Handbook | Open...

    Open Energy Info (EERE)

    to library PermittingRegulatory Guidance - GuideHandbook: Washington Coastal Zone Management Regulatory HandbookPermittingRegulatory GuidanceGuideHandbook Author Washington...

  6. Vadose Zone Microbiology: Science and Applications

    SciTech Connect (OSTI)

    Brockman, Fred J.; Bradley, Stephen D.; Kieft, Thomas L.

    2002-03-12

    Brockman FJ, SN Bradley and TL Kieft. 2002. Vadose zone microbiology. In Encyclopedia of Environmental Microbiology, volume 6, pp. 3236-3246. John Wiley and Sons, New York.

  7. Maricopa County- Renewable Energy Systems Zoning Ordinance

    Broader source: Energy.gov [DOE]

    The Maricopa County Zoning Ordinance contains provisions for siting renewable energy systems. The ordinance defines renewable energy as "energy derived primarily from sources other than fossil...

  8. Climate Zone 2B | Open Energy Information

    Open Energy Info (EERE)

    are categorized as class 2B climate zones: Bandera County, Texas Dimmit County, Texas Edwards County, Texas Frio County, Texas Imperial County, California Kinney County, Texas La...

  9. Coastal Zone Management Act | Open Energy Information

    Open Energy Info (EERE)

    and the National Estuarine Research Reserve System. The 34 coastal programs aim to balance competing land and water issues in the coastal zone, while estuarine reserves serve...

  10. Mapping Hydrothermal Upwelling and Outflow Zones: Preliminary...

    Open Energy Info (EERE)

    temperature anomaly has been mapped. A group of subtle temperature anomalies along Simpson Pass, south of the current production area, are interpreted as an upwelling zone with...

  11. Coastal Zone Management Act and Regulations

    Broader source: Energy.gov [DOE]

    The Coastal Zone Management Act (CZMA) of 1972 provides for the management of the nation’s coastal resources, including the Great Lakes.

  12. Evolution of Pre-Jurassic basement beneath northern Gulf of Mexico coastal plain

    SciTech Connect (OSTI)

    Van Siclen, D.C.

    1990-09-01

    Data from the northern Gulf Coast region reveal a late Paleozoic wrench fault system along which North America (NA) moved southeast (present directions) alongside the northeastern edge of future South America (SA), to where collision with that continent converted a broad continental embankment off the Southern Oklahoma aulacogen into the Ouachita thrust belt. At the same time, Africa farther east, to which protruding SA was firmly joined, was continuing to advance the Appalachian thrusts on the opposite side of these faults. This relationship left no space between the American continents for the conventional remnant ocean or microcontinents. By Late Triassic time, however, extension south of the Ouachita Mountains was forming the series of Interior rift basins, at both ends of which new wrench faults transferred the extension southward to the DeSoto Canyon and South Texas rift basins. Genetically, the Ouachita thrusts are part of the subduction zone along the front of a former SA forearc basin, which continued to receive marine sediments into middle Permian. The Wiggins arch southeast of it is a sliver of that continent, left with NA when the Interior basin rifting jumped from that forearc basin southward across bordering outer basement highs to begin opening the deep Gulf of Mexico (GOM) basin. The Late Triassic crustal extension resulted from right-lateral translation of NA around the bulge of northwestern Africa. About 200 mi of this placed Cape Hatteras against Africa's Cap Blanc, in the configuration from which the magnetic data indicate spreading began in the Central North Atlantic Ocean. The reality of this translation is confirmed by widespread rifting at the same time in western North Africa and between all three northern Atlantic continents; this drew the tip of the Tethys sea southward to Cape Hatteras and led to deposition of voluminous Late Triassic red beds and evaporites along it.

  13. Method for harvesting single crystals from a peritectic melt

    DOE Patents [OSTI]

    Todt, Volker R.; Sengupta, Suvankar; Shi, Donglu

    1996-01-01

    A method of preparing single crystals. The method of preparation involves preparing precursor materials of a particular composition, heating the precursor material to achieve a peritectic mixture of peritectic liquid and crystals, cooling the peritectic mixture to quench directly the mixture on a porous, wettable inert substrate to wick off the peritectic liquid, leaving single crystals on the porous substrate. Alternatively, the peritectic mixture can be cooled to a solid mass and reheated on a porous, inert substrate to melt the matrix of peritectic fluid while leaving the crystals unmelted, allowing the wicking away of the peritectic liquid.

  14. Method for harvesting single crystals from a peritectic melt

    DOE Patents [OSTI]

    Todt, V.R.; Sengupta, S.; Shi, D.

    1996-08-27

    A method of preparing single crystals is disclosed. The method of preparation involves preparing precursor materials of a particular composition, heating the precursor material to achieve a peritectic mixture of peritectic liquid and crystals, cooling the peritectic mixture to quench directly the mixture on a porous, wettable inert substrate to wick off the peritectic liquid, leaving single crystals on the porous substrate. Alternatively, the peritectic mixture can be cooled to a solid mass and reheated on a porous, inert substrate to melt the matrix of peritectic fluid while leaving the crystals unmelted, allowing the wicking away of the peritectic liquid. 2 figs.

  15. Method to decrease loss of aluminum and magnesium melts

    DOE Patents [OSTI]

    Hryn, John N.; Pellin, Michael J.; Calaway, Jr., Wallis F.; Moore, Jerry F.; Krumdick, Gregory K.

    2002-01-01

    A method to minimize oxidation of metal during melting processes is provided, the method comprising placing solid phase metal into a furnace environ-ment, transforming the solid-phase metal into molten metal phase having a molten metal surface, and creating a barrier between the surface and the environment. Also provided is a method for isolating the surface of molten metal from its environment, the method comprising confining the molten metal to a controlled atmos-phere, and imposing a floating substrate between the surface and the atmosphere.

  16. Hydrostatic extrusion of Cu-Ag melt spun ribbon

    DOE Patents [OSTI]

    Hill, M.A.; Bingert, J.F.; Bingert, S.A.; Thoma, D.J.

    1998-09-08

    The present invention provides a method of producing high-strength and high-conductance copper and silver materials comprising the steps of combining a predetermined ratio of the copper with the silver to produce a composite material, and melt spinning the composite material to produce a ribbon of copper and silver. The ribbon of copper and silver is heated in a hydrogen atmosphere, and thereafter die pressed into a slug. The slug then is placed into a high-purity copper vessel and the vessel is sealed with an electron beam. The vessel and slug then are extruded into wire form using a cold hydrostatic extrusion process. 5 figs.

  17. Hydrostatic extrusion of Cu-Ag melt spun ribbon

    DOE Patents [OSTI]

    Hill, Mary Ann; Bingert, John F.; Bingert, Sherri A.; Thoma, Dan J.

    1998-01-01

    The present invention provides a method of producing high-strength and high-conductance copper and silver materials comprising the steps of combining a predetermined ratio of the copper with the silver to produce a composite material, and melt spinning the composite material to produce a ribbon of copper and silver. The ribbon of copper and silver is heated in a hydrogen atmosphere, and thereafter die pressed into a slug. The slug then is placed into a high-purity copper vessel and the vessel is sealed with an electron beam. The vessel and slug then are extruded into wire form using a cold hydrostatic extrusion process.

  18. Low-melting point inorganic nitrate salt heat transfer fluid

    DOE Patents [OSTI]

    Bradshaw, Robert W.; Brosseau, Douglas A.

    2009-09-15

    A low-melting point, heat transfer fluid made of a mixture of four inorganic nitrate salts: 9-18 wt % NaNO.sub.3, 40-52 wt % KNO.sub.3, 13-21 wt % LiNO.sub.3, and 20-27 wt % Ca(NO.sub.3).sub.2. These compositions can have liquidus temperatures less than 100 C; thermal stability limits greater than 500 C; and viscosity in the range of 5-6 cP at 300 C; and 2-3 cP at 400 C.

  19. Core melt/coolant interactions: modelling. [PWR; BWR

    SciTech Connect (OSTI)

    Berman, M.; McGlaun, J.M.; Corradini, M.L.

    1983-01-01

    If there is not adequate cooling water in the core of a light-water reactor (LWR), the fission product decay heat would eventually cause the reactor fuel and cladding to melt. This could lead to slumping of the molten core materials into the lower plenum of the reactor vessel, possibly followed by failure of the vessel wall and pouring of the molten materials into the reactor cavity. When the molten core materials enter either region, there is a strong possibility of molten core contacting water. This paper focuses on analysis of recent FITS experiments, mechanistic and probabilistic model development, and the application of these models to reactor considerations.

  20. Treating tar sands formations with karsted zones

    DOE Patents [OSTI]

    Vinegar, Harold J.; Karanikas, John Michael

    2010-03-09

    Methods for treating a tar sands formation are described herein. The tar sands formation may have one or more karsted zones. Methods may include providing heat from one or more heaters to one or more karsted zones of the tar sands formation to mobilize fluids in the formation. At least some of the mobilized fluids may be produced from the formation.

  1. Characterization of Vadose Zone Sediment: Slant Borehole SX-108 in the S-SX Waste Management Area

    SciTech Connect (OSTI)

    Serne, R. Jeffrey; Last, George V.; Schaef, Herbert T.; Lanigan, David C.; Lindenmeier, Clark W.; Ainsworth, Calvin C.; Clayton, Ray E.; Legore, Virginia L.; O'Hara, Matthew J.; Brown, Christopher F.; Orr, Robert D.; Kutnyakov, Igor V.; Wilson, Teresa C.; Wagnon, Kenneth B.; Williams, Bruce A.; Burke, Deborah S.

    2008-09-11

    This report was revised in September 2008 to remove acid-extractable sodium data from Table 4.17. The sodium data was removed due to potential contamination introduced during the acid extraction process. The rest of the text remains unchanged from the original report issued in February 2002. The overall goal of the of the Tank Farm Vadose Zone Project, led by CH2M HILL Hanford Group, Inc., is to define risks from past and future single-shell tank farm activities. To meet this goal, CH2M HILL Hanford Group, Inc., asked scientists from Pacific Northwest National Laboratory to perform detailed analyses on vadose zone sediment from within the S-SX Waste Management Area. This report is the fourth in a series of four reports to present the results of these analyses. Specifically, this report contains all the geologic, geochemical, and selected physical characterization data collected on vadose zone sediment recovered from a slant borehole installed beneath tank SX-108 (or simply SX-108 slant borehole).

  2. Vadose zone characterization project at the Hanford Tank Farms: U Tank Farm Report

    SciTech Connect (OSTI)

    1997-05-01

    The U.S. Department of Energy Grand Junction Office (DOE-GJO) was tasked by the DOE Richland Operations Office (DOE-RL) to perform a baseline characterization of the gamma-ray-emitting radionuclides that are distributed in the vadose zone sediments beneath and around the single-shell tanks (SSTs) at the Hanford Site. The intent of this characterization is to determine the nature and extent of the contamination, to identify contamination sources when possible, and to develop a baseline of the contamination distribution that will permit future data comparisons. This characterization work also allows an initial assessment of the impacts of the vadose zone contamination as required by the Resource Conservation and Recovery Act (RCRA). This characterization project involves acquiring information regarding vadose zone contamination with borehole geophysical logging methods and documenting that information in a series of reports. This information is presently limited to detection of gamma-emitting radionuclides from both natural and man-made sources. Data from boreholes surrounding each tank are compiled into individual Tank Summary Data Reports. The data from each tank in a tank farm are then compiled and summarized in a Tank Farm Report. This document is the Tank Farm Report for the U Tank Farm. Logging operations used high-purity germanium detection systems to acquire laboratory-quality assays of the gamma-emitting radionuclides in the sediments around and below the tanks. These assays were acquired in 59 boreholes that surround the U Tank Farm tanks. Logging of all boreholes was completed in December 1995, and the last Tank Summary Data Report for the U Tank Farm was issued in September 1996.

  3. Significance of water fluxes in a deep arid-region vadose zone to waste disposal strategies

    SciTech Connect (OSTI)

    Johnejack, K.R.; Blout, D.O.; Sully, M.J.; Emer, D.F.; Hammermeister, D.P. [Reynolds Electrical and Engineering Co., Inc., Las Vegas, NV (United States); Dever, L.G.; O`Neill, L.J. [DOE Nevada Operations Office, Las Vegas, NV (United States). Waste Management Div.; Tyler, S.W. [Desert Research Institute, Reno, NV (United States). Water Resources Center; Chapman, J. [Desert Research Institute, Las Vegas, NV (United States). Water Resources Center

    1994-03-01

    Recently collected subsurface site characterization data have led to the development of a conceptual model of water movement beneath the Area 5 Radioactive Waste Management Site (RWMS) at the Nevada Test Site (NTS) that differs significantly from the conceptual model of water movement inherent in Resource Conservation and Recovery Act (RCRA) regulations. At the Area 5 RWMS, water fluxes in approximately the upper 75 m (250 ft) of the vadose zone point in the upward direction (rather than downward) which effectively isolates this region from the deep (approximately 250 m (820 ft)) uppermost aquifer. Standard RCRA approaches for detection and containment (groundwater monitoring and double liners/leachate collection/leak detection systems) are not able to fulfill their intended function in this rather unique hydrogeologic environment. In order to better fulfill the waste detection and containment intentions of RCRA for mixed waste disposal at the Area 5 RWMS, the Department of Energy, Nevada Operations Office (DOE/NV) is preparing a single petition for both a waiver from groundwater monitoring and an exemption from double liners with leachate collection/leak detection. DOE/NV proposes in this petition that the containment function of liners and leachate collection is better accomplished by the natural hydrogeologic processes operating in the upper vadose zone; and the detection function of groundwater monitoring and the leak detection system in liners is better fulfilled by an alternative vadose zone monitoring system. In addition, an alternative point of compliance is proposed that will aid in early detection, as well as limit the extent of potential contamination before detection. Finally, special cell design features and operation practices will be implemented to limit leachate formation, especially while the cell is open to the atmosphere during waste emplacement.

  4. Quantum Hooke's Law to classify pulse laser induced ultrafast melting

    SciTech Connect (OSTI)

    Hu, Hao; Ding, Hepeng; Liu, Feng

    2015-02-03

    Ultrafast crystal-to-liquid phase transition induced by femtosecond pulse laser excitation is an interesting material's behavior manifesting the complexity of light-matter interaction. There exist two types of such phase transitions: one occurs at a time scale shorter than a picosecond via a nonthermal process mediated by electron-hole plasma formation; the other at a longer time scale via a thermal melting process mediated by electron-phonon interaction. However, it remains unclear what material would undergo which process and why? Here, by exploiting the property of quantum electronic stress (QES) governed by quantum Hooke's law, we classify the transitions by two distinct classes of materials: the faster nonthermal process can only occur in materials like ice having an anomalous phase diagram characterized with dTm/dP < 0, where Tm is the melting temperature and P is pressure, above a high threshold laser fluence; while the slower thermal process may occur in all materials. Especially, the nonthermal transition is shown to be induced by the QES, acting like a negative internal pressure, which drives the crystal into a super pressing state to spontaneously transform into a higher-density liquid phase. Our findings significantly advance fundamental understanding of ultrafast crystal-to-liquid phase transitions, enabling quantitative a priori predictions.

  5. Microwires fabricated by glass-coated melt spinning

    SciTech Connect (OSTI)

    Zhao, Y. Y.; Li, H.; Hao, H. Y.; Li, M.; Zhang, Y.; Liaw, P. K.

    2013-07-15

    The glass-coated melt spinning method offers a route for the manufacture of metal filaments with a few micrometers in diameter in a single operation directly from the melt. Cobalt-based amorphous wires, Cu-15.0 atomic percent (at. %) Sn shape-memory wires, and Ni{sub 2}MnGa (atomic percent) ferromagnetic wires were successfully produced by this method. The cobalt-based amorphous wire is flexible, and Cu-15.0 at. % Sn shape-memory wires have the tensile elongation of 14%. However, because of chemical reaction with glass and oxidation, it is hard to make CuAlNi shape-memory wires and NiNbSn amorphous wires. Conditions for preparing these materials were summarized, and the differences of the solidification processes among glass-coated amorphous cobalt-based wires, Cu-15.0 at. % Sn shape-memory wires, and Ni{sub 2}MnGa wires were analyzed and discussed.

  6. Low melting high lithia glass compositions and methods

    DOE Patents [OSTI]

    Jantzen, Carol M.; Pickett, John B.; Cicero-Herman, Connie A.; Marra, James C.

    2003-10-07

    The invention relates to methods of vitrifying waste and for lowering the melting point of glass forming systems by including lithia formers in the glass forming composition in significant amounts, typically from about 0.16 wt % to about 11 wt %, based on the total glass forming oxides. The lithia is typically included as a replacement for alkali oxide glass formers that would normally be present in a particular glass forming system. Replacement can occur on a mole percent or weight percent basis, and typically results in a composition wherein lithia forms about 10 wt % to about 100 wt % of the alkali oxide glass formers present in the composition. The present invention also relates to the high lithia glass compositions formed by these methods. The invention is useful for stabilization of numerous types of waste materials, including aqueous waste streams, sludge solids, mixtures of aqueous supernate and sludge solids, combinations of spent filter aids from waste water treatment and waste sludges, supernate alone, incinerator ash, incinerator offgas blowdown, or combinations thereof, geological mine tailings and sludges, asbestos, inorganic filter media, cement waste forms in need of remediation, spent or partially spent ion exchange resins or zeolites, contaminated soils, lead paint, etc. The decrease in melting point achieved by the present invention desirably prevents volatilization of hazardous or radioactive species during vitrification.

  7. Low melting high lithia glass compositions and methods

    DOE Patents [OSTI]

    Jantzen, Carol M.; Pickett, John B.; Cicero-Herman, Connie A.; Marra, James C.

    2004-11-02

    The invention relates to methods of vitrifying waste and for lowering the melting point of glass forming systems by including lithia formers in the glass forming composition in significant amounts, typically from about 0.16 wt % to about 11 wt %, based on the total glass forming oxides. The lithia is typically included as a replacement for alkali oxide glass formers that would normally be present in a particular glass forming system. Replacement can occur on a mole percent or weight percent basis, and typically results in a composition wherein lithia forms about 10 wt % to about 100 wt % of the alkali oxide glass formers present in the composition. The present invention also relates to the high lithia glass compositions formed by these methods. The invention is useful for stabilization of numerous types of waste materials, including aqueous waste streams, sludge solids, mixtures of aqueous supernate and sludge solids, combinations of spent filter aids from waste water treatment and waste sludges, supernate alone, incinerator ash, incinerator offgas blowdown, or combinations thereof, geological mine tailings and sludges, asbestos, inorganic filter media, cement waste forms in need of remediation, spent or partially spent ion exchange resins or zeolites, contaminated soils, lead paint, etc. The decrease in melting point achieved by the present invention desirably prevents volatilization of hazardous or radioactive species during vitrification.

  8. Low melting high lithia glass compositions and methods

    DOE Patents [OSTI]

    Jantzen, Carol M.; Pickett, John B.; Cicero-Herman, Connie A.; Marra, James C.

    2000-01-01

    The invention relates to methods of vitrifying waste and for lowering the melting point of glass forming systems by including lithia formers in the glass forming composition in significant amounts, typically from about 0.16 wt % to about 11 wt %, based on the total glass forming oxides. The lithia is typically included as a replacement for alkali oxide glass formers that would normally be present in a particular glass forming system. Replacement can occur on a mole percent or weight percent basis, and typically results in a composition wherein lithia forms about 10 wt % to about 100 wt % of the alkali oxide glass formers present in the composition. The present invention also relates to the high lithia glass compositions formed by these methods. The invention is useful for stabilization of numerous types of waste materials, including aqueous waste streams, sludge solids, mixtures of aqueous supernate and sludge solids, combinations of spent filter aids from waste water treatment and waste sludges, supernate alone, incinerator ash, incinerator offgas blowdown, or combinations thereof, geological mine tailings and sludges, asbestos, inorganic filter media, cement waste forms in need of remediation, spent or partially spent ion exchange resins or zeolites, contaminated soils, lead paint, etc. The decrease in melting point achieved by the present invention desirably prevents volatilization of hazardous or radioactive species during vitrification.

  9. Quantum Hooke's Law to classify pulse laser induced ultrafast melting

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hu, Hao; Ding, Hepeng; Liu, Feng

    2015-02-03

    Ultrafast crystal-to-liquid phase transition induced by femtosecond pulse laser excitation is an interesting material's behavior manifesting the complexity of light-matter interaction. There exist two types of such phase transitions: one occurs at a time scale shorter than a picosecond via a nonthermal process mediated by electron-hole plasma formation; the other at a longer time scale via a thermal melting process mediated by electron-phonon interaction. However, it remains unclear what material would undergo which process and why? Here, by exploiting the property of quantum electronic stress (QES) governed by quantum Hooke's law, we classify the transitions by two distinct classes ofmore » materials: the faster nonthermal process can only occur in materials like ice having an anomalous phase diagram characterized with dTm/dP < 0, where Tm is the melting temperature and P is pressure, above a high threshold laser fluence; while the slower thermal process may occur in all materials. Especially, the nonthermal transition is shown to be induced by the QES, acting like a negative internal pressure, which drives the crystal into a “super pressing” state to spontaneously transform into a higher-density liquid phase. Our findings significantly advance fundamental understanding of ultrafast crystal-to-liquid phase transitions, enabling quantitative a priori predictions.« less

  10. Thermal sprayed composite melt containment tubular component and method of making same

    DOE Patents [OSTI]

    Besser, Matthew F.; Terpstra, Robert L.; Sordelet, Daniel J.; Anderson, Iver E.

    2002-03-19

    A tubular thermal sprayed melt containment component for transient containment of molten metal or alloy wherein the tubular member includes a thermal sprayed inner melt-contacting layer for contacting molten metal or alloy to be processed, a thermal sprayed heat-generating layer deposited on the inner layer, and an optional thermal sprayed outer thermal insulating layer. The thermal sprayed heat-generating layer is inductively heated as a susceptor of an induction field or electrical resistively heated by passing electrical current therethrough. The tubular thermal sprayed melt containment component can comprise an elongated melt pour tube of a gas atomization apparatus where the melt pour tube supplies molten material from a crucible to an underlying melt atomization nozzle.

  11. A new estimate of the chondrule cooling rate deduced from an analysis of compositional zoning of relict olivine

    SciTech Connect (OSTI)

    Miura, H.; Yamamoto, T.

    2014-03-01

    Compositional zoning in chondrule phenocrysts records the crystallization environments in the early solar nebula. We modeled the growth of olivine phenocrysts from a silicate melt and proposed a new fractional crystallization model that provides a relation between the zoning profile and the cooling rate. In our model, we took elemental partitioning at a growing solid-liquid interface and time-dependent solute diffusion in the liquid into consideration. We assumed a local equilibrium condition, namely, that the compositions at the interface are equal to the equilibrium ones at a given temperature. We carried out numerical simulations of the fractional crystallization in one-dimensional planar geometry. The simulations revealed that under a constant cooling rate the growth velocity increases exponentially with time and a linear zoning profile forms in the solid as a result. We derived analytic formulae of the zoning profile, which reproduced the numerical results for wide ranges of crystallization conditions. The formulae provide a useful tool to estimate the cooling rate from the compositional zoning. Applying the formulae to low-FeO relict olivine grains in type II porphyritic chondrules observed by Wasson and Rubin, we estimate the cooling rate to be ?200-2000 K s{sup 1}, which is greater than that expected from furnace-based experiments by orders of magnitude. Appropriate solar nebula environments for such rapid cooling conditions are discussed.

  12. Removing a sheet from the surface of a melt using elasticity and buoyancy

    DOE Patents [OSTI]

    Kellerman, Peter L.; Sun, Dawei; Helenbrook, Brian; Harvey, David S.

    2014-07-01

    Embodiments related to sheet production are disclosed. A melt of a material is cooled to form a sheet of the material on the melt. The sheet is formed in a first region at a first sheet height. The sheet is translated to a second region such that it has a second sheet height higher than the first sheet height. The sheet is then separated from the melt. A seed wafer may be used to form the sheet.

  13. Thermographic In-Situ Process Monitoring of the Electron Beam Melting

    Office of Scientific and Technical Information (OSTI)

    Technology used in Additive Manufacturing (Conference) | SciTech Connect Thermographic In-Situ Process Monitoring of the Electron Beam Melting Technology used in Additive Manufacturing Citation Details In-Document Search Title: Thermographic In-Situ Process Monitoring of the Electron Beam Melting Technology used in Additive Manufacturing Oak Ridge National Laboratory (ORNL) has been utilizing the ARCAM electron beam melting technology to additively manufacture complex geometric structures

  14. Thermodynamic principles of the process of the effect of electromagnetic fields on a polymer melt

    SciTech Connect (OSTI)

    Miroshnichenko, V.F.; Semenyuk, N.I.

    1989-06-23

    The effect of electromagnetic fields on a polymer melt leads to an increase in the strength of polymers while magnetostatic field virtually does not have an effect on the immobile polymer melt. However, if relative motion of magnetic field and polymer melt occurs, then, according to the laws of electrodynamics, besides magnetic field in the polymer melt appears the electric field, which will interact with the macromolecules of polymer. As a result of this can be changed the structure of polymer melt, which will be fixed/recorded in proportion to cooling fusion/melt, which must immediately be reflected in the properties of solid polymer. Change in structure of polymer melt can be considered as peculiar phase transitions. Apparently, for the polymer melts besides the phase transformations of the first and second kind there are other, possibly, mixed phase transitions. We experimentally established presence of Delta T-effect in polymer melts, which is characteristic for phase second-order transformations. Therefore in this article we use theory of second-order phase transitions in application to the phenomena in question.

  15. Ex-Vessel Core Melt Modeling Comparison between MELTSPREAD-CORQUENCH and MELCOR 2.1

    SciTech Connect (OSTI)

    Robb, Kevin R.; Farmer, Mitchell; Francis, Matthew W.

    2014-03-01

    System-level code analyses by both United States and international researchers predict major core melting, bottom head failure, and corium-concrete interaction for Fukushima Daiichi Unit 1 (1F1). Although system codes such as MELCOR and MAAP are capable of capturing a wide range of accident phenomena, they currently do not contain detailed models for evaluating some ex-vessel core melt behavior. However, specialized codes containing more detailed modeling are available for melt spreading such as MELTSPREAD as well as long-term molten corium-concrete interaction (MCCI) and debris coolability such as CORQUENCH. In a preceding study, Enhanced Ex-Vessel Analysis for Fukushima Daiichi Unit 1: Melt Spreading and Core-Concrete Interaction Analyses with MELTSPREAD and CORQUENCH, the MELTSPREAD-CORQUENCH codes predicted the 1F1 core melt readily cooled in contrast to predictions by MELCOR. The user community has taken notice and is in the process of updating their systems codes; specifically MAAP and MELCOR, to improve and reduce conservatism in their ex-vessel core melt models. This report investigates why the MELCOR v2.1 code, compared to the MELTSPREAD and CORQUENCH 3.03 codes, yield differing predictions of ex-vessel melt progression. To accomplish this, the differences in the treatment of the ex-vessel melt with respect to melt spreading and long-term coolability are examined. The differences in modeling approaches are summarized, and a comparison of example code predictions is provided.

  16. MELTING OF GLASS BATCH: MODEL FOR MULTIPLE OVERLAPPING GAS-EVOLVING...

    Office of Scientific and Technical Information (OSTI)

    Subject: 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; GLASS; HEATING; KINETICS; MELTING; SIMULATION; THERMAL GRAVIMETRIC ANALYSIS; WASTES Word Cloud More Like This ...

  17. The re-evaluation of the AVR melt-wire experiment with specific...

    Office of Scientific and Technical Information (OSTI)

    strategies and simplifications Citation Details In-Document Search Title: The re-evaluation of the AVR melt-wire experiment with specific focus on different modeling strategies ...

  18. Exploration of Melt Spinning as a Route to Large Volume Production...

    Broader source: Energy.gov (indexed) [DOE]

    Melt spinning combined with Spark Plasma Sintering provides a potential route to the mass production of Skutterudite based thermoelectric materials salvador.pdf (5.17 MB) More ...

  19. Surface layering and melting in an ionic liquid studied by resonant...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    hard X-ray reflectivity, small- and wide-angle X-ray scattering, and infrared spectroscopy uncovered an intriguing melting mechanism for the layered region,...

  20. Mobile machine hazardous working zone warning system

    DOE Patents [OSTI]

    Schiffbauer, William H.; Ganoe, Carl W.

    1999-01-01

    A warning system is provided for a mobile working machine to alert an individual of a potentially dangerous condition in the event the individual strays into a hazardous working zone of the machine. The warning system includes a transmitter mounted on the machine and operable to generate a uniform magnetic field projecting beyond an outer periphery of the machine in defining a hazardous working zone around the machine during operation thereof. A receiver, carried by the individual and activated by the magnetic field, provides an alarm signal to alert the individual when he enters the hazardous working zone of the machine.

  1. Mobile machine hazardous working zone warning system

    DOE Patents [OSTI]

    Schiffbauer, W.H.; Ganoe, C.W.

    1999-08-17

    A warning system is provided for a mobile working machine to alert an individual of a potentially dangerous condition in the event the individual strays into a hazardous working zone of the machine. The warning system includes a transmitter mounted on the machine and operable to generate a uniform magnetic field projecting beyond an outer periphery of the machine in defining a hazardous working zone around the machine during operation. A receiver, carried by the individual and activated by the magnetic field, provides an alarm signal to alert the individual when he enters the hazardous working zone of the machine. 3 figs.

  2. Eutectic precipitation of melt quenched titanium-silicon-neodymium alloy

    SciTech Connect (OSTI)

    Li, G.P.; Liu, Y.Y.; Li, D.; Hu, Z.Q. . Inst. of Metal Research)

    1995-01-15

    Titanium based metallic glasses have attracted keen interest because of the promise of industrial applications owing to their improves corrosion resistance, better mechanical properties, occurrence of superconductivity and superior magnetic properties. The titanium alloy systems where metallic glass has been obtained include Ti-Cu, Ti-Be, Ti-Si, Ti-B. Polk et al. had reported that they were able to produce an amorphous phase in binary Ti[sub 80]Si[sub 20] alloy system by using an arc-melting piston and anvil apparatus. In the present study, the authors have investigated the effect of adding rare earth element Nd on eutective precipitation of the amorphous Ti[sub 80]Si[sub 20] alloy and the orientation relationship which exists between the [beta]-Ti and Ti[sub 5]Si[sub 3].

  3. Temporal Characterization of Hydrates System Dynamics beneath Seafloor Mounds. Integrating Time-Lapse Electrical Resistivity Methods and In Situ Observations of Multiple Oceanographic Parameters

    SciTech Connect (OSTI)

    Lutken, Carol; Macelloni, Leonardo; D'Emidio, Marco; Dunbar, John; Higley, Paul

    2015-01-31

    This study was designed to investigate temporal variations in hydrate system dynamics by measuring changes in volumes of hydrate beneath hydrate-bearing mounds on the continental slope of the northern Gulf of Mexico, the landward extreme of hydrate occurrence in this region. Direct Current Resistivity (DCR) measurements were made contemporaneously with measurements of oceanographic parameters at Woolsey Mound, a carbonate-hydrate complex on the mid-continental slope, where formation and dissociation of hydrates are most vulnerable to variations in oceanographic parameters affected by climate change, and where changes in hydrate stability can readily translate to loss of seafloor stability, impacts to benthic ecosystems, and venting of greenhouse gases to the water-column, and eventually, the atmosphere. We focused our study on hydrate within seafloor mounds because the structurally-focused methane flux at these sites likely causes hydrate formation and dissociation processes to occur at higher rates than at sites where the methane flux is less concentrated and we wanted to maximize our chances of witnessing association/dissociation of hydrates. We selected a particularly well-studied hydrate-bearing seafloor mound near the landward extent of the hydrate stability zone, Woolsey Mound (MC118). This mid-slope site has been studied extensively and the project was able to leverage considerable resources from the team’s research experience at MC118. The site exhibits seafloor features associated with gas expulsion, hydrates have been documented at the seafloor, and changes in the outcropping hydrates have been documented, photographically, to have occurred over a period of months. We conducted observatory-based, in situ measurements to 1) characterize, geophysically, the sub-bottom distribution of hydrate and its temporal variability, and 2) contemporaneously record relevant environmental parameters (temperature, pressure, salinity, turbidity, bottom currents) to

  4. Computer Simulations of Bottle Brushes: From Melts to Soft Networks

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cao, Zhen; Sheiko, Sergei; Dobrynin, Andrey

    2015-01-01

    Using a combination of Molecular dynamics simulations and analytical calculations, we study dens bottle-brush systems in a melt and network State. Analysis. of our simulation results shows That bottle-brush macromolecules in melt behave as ideal chains with effective Kuhn length b(K). Simulations show that the bottle-brush-induced bending rigidity is due to an entropy decrease caused by redistribution of the side chains upon backbone bending The Kuhn length of the bottle:brushes increases with increasing the side-chain degree of polymerization n(sc) as b(K) proportional to n(sc)(0.46). This model of bottle brush macromolecules is extended to describe mechanical properties of bottle brush networksmore » in linear and nonlinear deformation regimes. In the linear deformation regime, the network shear modulus scales with the degree of polymerization of the side chains as G(0) proportional to (n(sc) + 1)(-1) as long as the ratio of the Kuhn length, b(K), to the size of the fully extended bottle-brush backbone between cross-links, R-max, is smaller than unity, b(K)/R-max << 1. Bottle-brush networks With b(K)/R-max proportional to 1 demonstrate behavior similar to that of networks Of semiflexible chains with G(0) proportional to n(sc)(-0.5). In the nonlinear network deformation regime, the deformation-dependent shear modulus is a universal function of the first strain invariant I-1 and bottle-brush backbone deformation ratio beta describing stretching ability of the bottle-brush backbone between cross-links.« less

  5. Category:ASHRAE Climate Zones | Open Energy Information

    Open Energy Info (EERE)

    Category Edit History Category:ASHRAE Climate Zones Jump to: navigation, search Climate Zones defined in the ASHRAE 169-2006 standards. Pages in category "ASHRAE Climate Zones" The...

  6. China-Low Carbon Development Zones | Open Energy Information

    Open Energy Info (EERE)

    China-Low Carbon Development Zones (Redirected from E3G-China-Low Carbon Development Zones) Jump to: navigation, search Name China-Low Carbon Development Zones AgencyCompany...

  7. San Diego County- Solar Zoning Regulations

    Office of Energy Efficiency and Renewable Energy (EERE)

    The County of San Diego has established zoning guidelines for solar electric systems of varying sizes in the unincorporated areas of San Diego County. Photovoltaic (PV) systems which have their...

  8. Local Option- Rural Renewable Energy Development Zones

    Broader source: Energy.gov [DOE]

    Commercial renewable energy property in these zones are eligible for a 3 to 5 year local property tax exemption. Eligible property includes either wind, geothermal, solar, biomass, or other uncon...

  9. Climate Zone 5C | Open Energy Information

    Open Energy Info (EERE)

    C. Climate Zone 5C is defined as Marine with IP Units 5400 < HDD65F 7200 and SI Units 3000 < HDD18C 4000 . The following places are categorized as class 5C...

  10. Vadose Zone Transport Field Study: Status Report

    SciTech Connect (OSTI)

    Gee, Glendon W.; Ward, Anderson L.

    2001-11-30

    Studies were initiated at the Hanford Site to evaluate the process controlling the transport of fluids in the vadose zone and to develop a reliable database upon which vadose-zone transport models can be calibrated. These models are needed to evaluate contaminant migration through the vadose zone to underlying groundwaters at Hanford. A study site that had previously been extensively characterized using geophysical monitoring techniques was selected in the 200 E Area. Techniques used previously included neutron probe for water content, spectral gamma logging for radionuclide tracers, and gamma scattering for wet bulk density. Building on the characterization efforts of the past 20 years, the site was instrumented to facilitate the comparison of nine vadose-zone characterization methods: advanced tensiometers, neutron probe, electrical resistance tomography (ERT), high-resolution resistivity (HRR), electromagnetic induction imaging (EMI), cross-borehole radar (XBR), and cross-borehole seismic (XBS). Soil coring was used to obtain soil samples for analyzing ionic and isotopic tracers.

  11. Zone heated diesel particulate filter electrical connection

    DOE Patents [OSTI]

    Gonze, Eugene V.; Paratore, Jr., Michael J.

    2010-03-30

    An electrical connection system for a particulate filter is provided. The system includes: a particulate filter (PF) disposed within an outer shell wherein the PF is segmented into a plurality of heating zones; an outer mat disposed between the particulate filter and the outer shell; an electrical connector coupled to the outer shell of the PF; and a plurality of printed circuit connections that extend along the outer surface of the PF from the electrical connector to the plurality of heating zones.

  12. U-PLANT GEOGRAPHIC ZONE CLEANUP PROTOTYPE

    SciTech Connect (OSTI)

    ROMINE, L.D.

    2006-02-01

    The U Plant geographic zone (UPZ) occupies 0.83 square kilometers on the Hanford Site Central Plateau (200 Area). It encompasses the U Plant canyon (221-U Facility), ancillary facilities that supported the canyon, soil waste sites, and underground pipelines. The UPZ cleanup initiative coordinates the cleanup of the major facilities, ancillary facilities, waste sites, and contaminated pipelines (collectively identified as ''cleanup items'') within the geographic zone. The UPZ was selected as a geographic cleanup zone prototype for resolving regulatory, technical, and stakeholder issues and demonstrating cleanup methods for several reasons: most of the area is inactive, sufficient characterization information is available to support decisions, cleanup of the high-risk waste sites will help protect the groundwater, and the zone contains a representative cross-section of the types of cleanup actions that will be required in other geographic zones. The UPZ cleanup demonstrates the first of 22 integrated zone cleanup actions on the Hanford Site Central Plateau to address threats to groundwater, the environment, and human health. The UPZ contains more than 100 individual cleanup items. Cleanup actions in the zone will be undertaken using multiple regulatory processes and decision documents. Cleanup actions will include building demolition, waste site and pipeline excavation, and the construction of multiple, large engineered barriers. In some cases, different cleanup actions may be taken at item locations that are immediately adjacent to each other. The cleanup planning and field activities for each cleanup item must be undertaken in a coordinated and cohesive manner to ensure effective execution of the UPZ cleanup initiative. The UPZ zone cleanup implementation plan (ZCIP) was developed to address the need for a fundamental integration tool for UPZ cleanup. As UPZ cleanup planning and implementation moves forward, the ZCIP is intended to be a living document that will

  13. Treating nahcolite containing formations and saline zones

    DOE Patents [OSTI]

    Vinegar, Harold J

    2013-06-11

    A method for treating a nahcolite containing subsurface formation includes removing water from a saline zone in or near the formation. The removed water is heated using a steam and electricity cogeneration facility. The heated water is provided to the nahcolite containing formation. A fluid is produced from the nahcolite containing formation. The fluid includes at least some dissolved nahcolite. At least some of the fluid is provided to the saline zone.

  14. Androscoggin County, Maine ASHRAE 169-2006 Climate Zone | Open...

    Open Energy Info (EERE)

    Apps Datasets Community Login | Sign Up Search Page Edit History Androscoggin County, Maine ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place...

  15. DOE New Madrid Seismic Zone Electric Utility Workshop Summary...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    New Madrid Seismic Zone Electric Utility Workshop Summary Report - August 2010 DOE New Madrid Seismic Zone Electric Utility Workshop Summary Report - August 2010 The DOE New Madrid ...

  16. Future Energy Zone Private Ltd FEZ | Open Energy Information

    Open Energy Info (EERE)

    Zone Private Ltd FEZ Jump to: navigation, search Name: Future Energy Zone Private Ltd (FEZ) Place: Chennai, Tamil Nadu, India Sector: Renewable Energy Product: Focused on building...

  17. Walker-Lane Transition Zone Geothermal Region | Open Energy Informatio...

    Open Energy Info (EERE)

    At Walker-Lane Transitional Zone Region (Coolbaugh, Et Al., 2005 - 2) Direct-Current Resistivity Survey At Walker-Lane Transitional Zone Region (Pritchett,...

  18. Alleghany County, North Carolina ASHRAE 169-2006 Climate Zone...

    Open Energy Info (EERE)

    Alleghany County, North Carolina ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Alleghany County, North Carolina ASHRAE Standard ASHRAE 169-2006...

  19. Alamance County, North Carolina ASHRAE 169-2006 Climate Zone...

    Open Energy Info (EERE)

    Alamance County, North Carolina ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Alamance County, North Carolina ASHRAE Standard ASHRAE 169-2006...

  20. Alexander County, North Carolina ASHRAE 169-2006 Climate Zone...

    Open Energy Info (EERE)

    Alexander County, North Carolina ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Alexander County, North Carolina ASHRAE Standard ASHRAE 169-2006...

  1. Geodetic Survey At Walker-Lane Transitional Zone Region (Blewitt...

    Open Energy Info (EERE)

    Zone Region (Blewitt Et Al, 2005) Exploration Activity Details Location Walker-Lane Transition Zone Geothermal Region Exploration Technique Geodetic Survey Activity Date...

  2. Field Mapping At Walker-Lane Transitional Zone Region (Blewitt...

    Open Energy Info (EERE)

    Zone Region (Blewitt Et Al, 2005) Exploration Activity Details Location Walker-Lane Transition Zone Geothermal Region Exploration Technique Field Mapping Activity Date Usefulness...

  3. Teleseismic-Seismic Monitoring At Walker-Lane Transitional Zone...

    Open Energy Info (EERE)

    Zone Region (Biasi, Et Al., 2009) Exploration Activity Details Location Walker-Lane Transition Zone Geothermal Region Exploration Technique Teleseismic-Seismic Monitoring Activity...

  4. Compound and Elemental Analysis At Walker-Lane Transitional Zone...

    Open Energy Info (EERE)

    Zone Region (Laney, 2005) Exploration Activity Details Location Walker-Lane Transition Zone Geothermal Region Exploration Technique Compound and Elemental Analysis...

  5. Isotopic Analysis At Walker-Lane Transitional Zone Region (Laney...

    Open Energy Info (EERE)

    Zone Region (Laney, 2005) Exploration Activity Details Location Walker-Lane Transition Zone Geothermal Region Exploration Technique Isotopic Analysis- Fluid Activity Date...

  6. Teleseismic-Seismic Monitoring At Walker-Lane Transitional Zone...

    Open Energy Info (EERE)

    Zone Region (Biasi, Et Al., 2008) Exploration Activity Details Location Walker-Lane Transition Zone Geothermal Region Exploration Technique Teleseismic-Seismic Monitoring Activity...

  7. Geographic Information System At Walker-Lane Transitional Zone...

    Open Energy Info (EERE)

    Zone Region (Laney, 2005) Exploration Activity Details Location Walker-Lane Transition Zone Geothermal Region Exploration Technique Geographic Information System Activity...

  8. Geothermometry At Walker-Lane Transitional Zone Region (Laney...

    Open Energy Info (EERE)

    Zone Region (Laney, 2005) Exploration Activity Details Location Walker-Lane Transition Zone Geothermal Region Exploration Technique Geothermometry Activity Date Usefulness...

  9. Archive Reference Buildings by Climate Zone: 3A Atlanta, Georgia...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Archive Reference Buildings by Climate Zone: 3B Los Angeles, California Archive Reference Buildings by Climate Zone: 3B Las Vegas, Nevada Archive ...

  10. Longyang Zone Hongqiang Hydroelectric Power Development Co Ltd...

    Open Energy Info (EERE)

    Longyang Zone Hongqiang Hydroelectric Power Development Co Ltd Jump to: navigation, search Name: Longyang Zone Hongqiang Hydroelectric Power Development Co., Ltd. Place: Baoshan...

  11. Belknap County, New Hampshire ASHRAE 169-2006 Climate Zone |...

    Open Energy Info (EERE)

    Help Apps Datasets Community Login | Sign Up Search Page Edit History Belknap County, New Hampshire ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone...

  12. Central Nevada Seismic Zone Geothermal Region | Open Energy Informatio...

    Open Energy Info (EERE)

    Central Nevada Seismic Zone Geothermal Region Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Central Nevada Seismic Zone Geothermal Region Details Areas (3) Power...

  13. An Updated Site Scale Saturated Zone Ground Water Transport Model...

    Office of Scientific and Technical Information (OSTI)

    An Updated Site Scale Saturated Zone Ground Water Transport Model for Yucca Mountain. Citation Details In-Document Search Title: An Updated Site Scale Saturated Zone Ground Water ...

  14. Montana Streamside Management Zone Law Webpage | Open Energy...

    Open Energy Info (EERE)

    Zone Law Webpage Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Montana Streamside Management Zone Law Webpage Abstract Provides information on...

  15. LADOL Integrated Logistics Free Zone Enterprise LILE | Open Energy...

    Open Energy Info (EERE)

    LADOL Integrated Logistics Free Zone Enterprise LILE Jump to: navigation, search Name: LADOL Integrated Logistics Free Zone Enterprise (LILE) Place: Lagos, Nigeria Product:...

  16. Haleakala SW Rift Zone Exploration | Open Energy Information

    Open Energy Info (EERE)

    SW Rift Zone Exploration Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Development Project: Haleakala SW Rift Zone Exploration Project Location Information...

  17. Electrically heated particulate filter with zoned exhaust flow...

    Office of Scientific and Technical Information (OSTI)

    Electrically heated particulate filter with zoned exhaust flow control Title: Electrically heated particulate filter with zoned exhaust flow control A system includes a particulate ...

  18. Adams County, Pennsylvania ASHRAE 169-2006 Climate Zone | Open...

    Open Energy Info (EERE)

    Adams County, Pennsylvania ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Adams County, Pennsylvania ASHRAE Standard ASHRAE 169-2006 Climate...

  19. Berkeley County, South Carolina ASHRAE 169-2006 Climate Zone...

    Open Energy Info (EERE)

    Berkeley County, South Carolina ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Berkeley County, South Carolina ASHRAE Standard ASHRAE 169-2006...

  20. Berkeley County, West Virginia ASHRAE 169-2006 Climate Zone ...

    Open Energy Info (EERE)

    Berkeley County, West Virginia ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Berkeley County, West Virginia ASHRAE Standard ASHRAE 169-2006...

  1. Anderson County, Tennessee ASHRAE 169-2006 Climate Zone | Open...

    Open Energy Info (EERE)

    Anderson County, Tennessee ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Anderson County, Tennessee ASHRAE Standard ASHRAE 169-2006 Climate...

  2. Anderson County, South Carolina ASHRAE 169-2006 Climate Zone...

    Open Energy Info (EERE)

    Anderson County, South Carolina ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Anderson County, South Carolina ASHRAE Standard ASHRAE 169-2006...

  3. Alameda County, California ASHRAE 169-2006 Climate Zone | Open...

    Open Energy Info (EERE)

    Alameda County, California ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Alameda County, California ASHRAE Standard ASHRAE 169-2006 Climate...

  4. Bernalillo County, New Mexico ASHRAE 169-2006 Climate Zone |...

    Open Energy Info (EERE)

    Bernalillo County, New Mexico ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Bernalillo County, New Mexico ASHRAE Standard ASHRAE 169-2006...

  5. Workers Create Demolition Zone at Hanford Site's Plutonium Finishing...

    Office of Environmental Management (EM)

    Create Demolition Zone at Hanford Site's Plutonium Finishing Plant Workers Create Demolition Zone at Hanford Site's Plutonium Finishing Plant August 28, 2014 - 12:00pm Addthis The ...

  6. P-SV conversions at a shallow boundary beneath Campi Flegrei caldera (Italy) - evidence for the magma chamber

    SciTech Connect (OSTI)

    Ferrucci, F.; Hirn, A.; De Natale, G.; Virieux, J.; Mirabile, L. Inst. de Physique du Globe, Paris Osservatorio Vesuviano, Naples CNRS, Inst. de Geodynamique, Valbonne Ist. Universitario Navale, Naples )

    1992-10-01

    Seismograms from an active seismic experiment carried out at Campi Flegrei caldera (near Naples, Italy), show a large-amplitude SV-polarized shear wave, following by less than 1.5-s P waves reflected at wide angle from a deep crustal interface. Early arriving SV-polarized waves, with the same delay to direct P waves, are also observed in seismograms from a regional 280 km-deep, magnitude 5.1 earthquake. Such short delays of S to P waves are consistent with a P-SV conversion on transmission occurring at a shallow boundary beneath the receivers. The large amplitude of the converted-SV phase, along with that the P waves are near vertical, requires a boundary separating a very low rigidity layer from the upper caldera fill. The converted phases are interpreted as a seismic marker of a magma chamber. The top of this magma chamber is located slightly deeper than the deepest earthquakes observed during the 1982-1984 unrest of Campi Flegrei. 8 refs.

  7. Measurement of the Melting Point Temperature of Several Lithium-Sodium-Beryllium Fluoride Salt (Flinabe) Mixtures

    SciTech Connect (OSTI)

    McDonald, J.M; Nygren, R.E.; Lutz, T.J.; Tanaka, T.J; Ulrickson, M.A.; Boyle, T.J.; Troncosa, K.P.

    2005-04-15

    The molten salt Flibe, a combination of lithium and beryllium fluorides studied for molten salt fission reactors, has been proposed as a breeder and coolant for fusion applications. The melting points of 2LiF-BeF{sub 2} and LiF-BeF{sub 2} are 460 deg. C and 363 deg. C, but LiF-BeF{sub 2} is rather viscous and has less lithium for breeding. In the Advanced Power Extraction (APEX) Program, concepts with a free flowing liquid for the first wall and blanket were investigated. Flinabe (a mixture of LiF, BeF{sub 2} and NaF) was selected for a molten salt design because a melting temperature below 350 deg. C appeared possible and this provided an attractive operating temperature window for a reactor. To confirm that a ternary salt with a low melting temperature existed, several combinations of the fluoride salts, LiF, NaF and BeF{sub 2}, were melted in a stainless steel crucible under vacuum. One had an apparent melting temperature of 305 deg. C. The test system, preparation of the mixtures, melting procedures and temperature curves for the melting and cooling are presented along with the apparent melting points. Thermal modeling of the salt pool and crucible is reported in an accompanying paper.

  8. Glass science tutorial: Lecture No. 4, commercial glass melting and associated air emission issues

    SciTech Connect (OSTI)

    Kruger, A.A.

    1995-01-01

    This document serves as a manual for a workshop on commercial glass melting and associated air emission issues. Areas covered include: An overview of the glass industry; Furnace design and construction practices; Melting furnace operation; Energy input methods and controls; Air legislation and regulations; Soda lime emission mechanisms; and, Post furnace emission controls. Supporting papers are also included.

  9. Low-melting elemental metal or fusible alloy encapsulated polymerization initiator for delayed initiation

    DOE Patents [OSTI]

    Hermes, Robert E.

    2015-12-22

    An encapsulated composition for polymerization includes an initiator composition for initiating a polymerization reaction, and a capsule prepared from an elemental metal or fusible alloy having a melting temperature from about 20.degree. C. to about 200.degree. C. A fluid for polymerization includes the encapsulated composition and a monomer. When the capsule melts or breaks open, the initiator is released.

  10. Thermomechanical response of a semicrystalline polymer in the vicinity of the melting by using microcantilever technology

    SciTech Connect (OSTI)

    Soccio, M.; Rueda, D. R.; Garca-Gutirrez, M. C.; Ezquerra, T. A.; Luongo, G.; Esteves, C.; Salvador-Matar, A.; Ahumada, O.; Lotti, N.; Munari, A.

    2014-06-23

    The melting transition of a model semicrystalline polymer has been detected by the microcantilever deflection as a function of temperature. Deflection measurements were done on arrays of 8-cantilevers spin coated with the semicrystalline polymer: poly (propylene azelate). The melting of the polymer has been corroborated by grazing incidence wide angle x-ray scattering experiments performed with synchrotron radiation over a single cantilever.

  11. Detection of melting by X-ray imaging at high pressure

    SciTech Connect (OSTI)

    Li, Li; Weidner, Donald J.

    2014-06-15

    The occurrence of partial melting at elevated pressure and temperature is documented in real time through measurement of volume strain induced by a fixed temperature change. Here we present the methodology for measuring volume strains to one part in 10{sup ?4} for mm{sup 3} sized samples in situ as a function of time during a step in temperature. By calibrating the system for sample thermal expansion at temperatures lower than the solidus, the onset of melting can be detected when the melting volume increase is of comparable size to the thermal expansion induced volume change. We illustrate this technique with a peridotite sample at 1.5 GPa during partial melting. The Re capsule is imaged with a CCD camera at 20 frames/s. Temperature steps of 100 K induce volume strains that triple with melting. The analysis relies on image comparison for strain determination and the thermal inertia of the sample is clearly seen in the time history of the volume strain. Coupled with a thermodynamic model of the melting, we infer that we identify melting with 2 vol.% melting.

  12. Adams County, Colorado ASHRAE 169-2006 Climate Zone | Open Energy...

    Open Energy Info (EERE)

    ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Adams County, Colorado ASHRAE Standard ASHRAE 169-2006 Climate Zone Number Climate Zone...

  13. Baxter County, Arkansas ASHRAE 169-2006 Climate Zone | Open Energy...

    Open Energy Info (EERE)

    ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Baxter County, Arkansas ASHRAE Standard ASHRAE 169-2006 Climate Zone Number Climate Zone...

  14. New time-line technique for station blackout core-melt analysis

    SciTech Connect (OSTI)

    Stutzke, M.A.

    1986-01-01

    Florida Power Corporation (FPC) has developed a new method for analyzing station blackout (SBO) core-melt accidents. This method, created during the recent probabilistic risk assessment (PRA) of Crystal River Unit 3 (CR-3), originated from the need to analyze the interactions among the two-train emergency feedwater (EFW) system, station batteries, and diesel generators (DGs) following a loss of off-site power (LOSP) event. SBO core-melt sequences for CR-3 are unique since the time core-melt commences depends on which DG fails last. The purpose of this paper is to outline the new method of analysis of SBO core-melt accidents at CR-3. The significance of SBO core-melt accidents to total plant risk, along with the efficacy of various methods to reduce SBO risk, are also discussed.

  15. MEASUREMENT OF THE SHOCK-HEATED MELT CURVE OF LEAD USING PYROMETRY AND REFLECTOMETRY

    SciTech Connect (OSTI)

    D. Partouche-Sebban and J. L. Pelissier, Commissariat a` l'Energie Atomique,; F. G. Abeyta, Los Alamos National Laboratory; W. W. Anderson, Los Alamos National Laboratory; M. E. Byers, Los Alamos National Laboratory; D. Dennis-Koller, Los Alamos National Laboratory; J. S. Esparza, Los Alamos National Laboratory; S. D. Borror, Bechtel Nevada; C. A. Kruschwitz, Bechtel Nevada

    2004-01-01

    Data on the high-pressure melting temperatures of metals is of great interest in several fields of physics including geophysics. Measuring melt curves is difficult but can be performed in static experiments (with laser-heated diamond-anvil cells for instance) or dynamically (i.e., using shock experiments). However, at the present time, both experimental and theoretical results for the melt curve of lead are at too much variance to be considered definitive. As a result, we decided to perform a series of shock experiments designed to provide a measurement of the melt curve of lead up to about 50 GPa in pressure. At the same time, we developed and fielded a new reflectivity diagnostic, using it to make measurements on tin. The results show that the melt curve of lead is somewhat higher than the one previously obtained with static compression and heating techniques.

  16. Effect of minor chemistry elements on GTA weld fusion zone characteristics of a commercial grade titanium

    SciTech Connect (OSTI)

    Marya, S.K.

    1996-06-01

    Gas Tungsten Arc Welding (GTAW) is the most common technique employed in the fabrication of rolled thin tubes. One of the major manufacturing problems concerns the stability of weld fusion zone on materials from different casts, notwithstanding stringent monitoring of the process parameters -- current, voltage and travel speed. These parameters determine the theoretical weld heat and are expected to control the instantaneous mass of melt. According to the data compiled by Sahoo et al., oxygen is known to reduce the surface tension of most of the metals. However, investigations on the role of minor changes in concentrations of elements like sulphur, oxygen, selenium, bismuth, aluminium, and titanium in steels have very often attributed the cast to cast variations to different temperature gradients of surface tension over the weldpool. To the author`s knowledge, no reported work so far has revealed changing weld profiles in autogeneous mechanized GTA welds on titanium due to minor composition changes.

  17. Heat-affected zone liquation crack on resistance spot welded TWIP steels

    SciTech Connect (OSTI)

    Saha, Dulal Chandra [Department of Advanced Materials Engineering, Dong-Eui University, 995 Eomgwangno, Busanjin-gu, Busan 614-714 (Korea, Republic of); Chang, InSung [Automotive Production Development Division, Hyundai Motor Company (Korea, Republic of); Park, Yeong-Do, E-mail: ypark@deu.ac.kr [Department of Advanced Materials Engineering, Dong-Eui University, 995 Eomgwangno, Busanjin-gu, Busan 614-714 (Korea, Republic of)

    2014-07-01

    In this study, the heat affected zone (HAZ) liquation crack and segregation behavior of the resistance spot welded twinning induced plasticity (TWIP) steel have been reported. Cracks appeared in the post-welded joints that originated at the partially melted zone (PMZ) and propagated from the PMZ through the heat affected zone (HAZ) to the base metal (BM). The crack length and crack opening widths were observed increasing with heat input; and the welding current was identified to be the most influencing parameter for crack formation. Cracks appeared at the PMZ when nugget diameter reached at 4.50 mm or above; and the liquation cracks were found to occur along two sides of the notch tip in the sheet direction rather than in the electrode direction. Cracks were backfilled with the liquid films which has lamellar structure and supposed to be the eutectic constituent. Co-segregation of alloy elements such as, C and Mn were detected on the liquid films by electron-probe microanalysis (EPMA) line scanning and element map which suggests that the liquid film was enrich of Mn and C. The eutectic constituent was identified by analyzing the calculated phase diagram along with thermal temperature history of finite element simulation. Preliminary experimental results showed that cracks have less/no significant effect on the static cross-tensile strength (CTS) and the tensile-shear strength (TSS). In addition, possible ways to avoid cracking were discussed. - Highlights: The HAZ liquation crack during resistance spot welding of TWIP steel was examined. Cracks were completely backfilled and healed with divorced eutectic secondary phase. Co-segregation of C and Mn was detected in the cracked zone. Heat input was the most influencing factor to initiate liquation crack. Cracks have less/no significant effect on static tensile properties.

  18. Melt Infiltrated Ceramic Composites (Hipercomp) for Gas Turbine Engine Applications

    SciTech Connect (OSTI)

    Gregory Corman; Krishan Luthra

    2005-09-30

    This report covers work performed under the Continuous Fiber Ceramic Composites (CFCC) program by GE Global Research and its partners from 1994 through 2005. The processing of prepreg-derived, melt infiltrated (MI) composite systems based on monofilament and multifilament tow SiC fibers is described. Extensive mechanical and environmental exposure characterizations were performed on these systems, as well as on competing Ceramic Matrix Composite (CMC) systems. Although current monofilament SiC fibers have inherent oxidative stability limitations due to their carbon surface coatings, the MI CMC system based on multifilament tow (Hi-Nicalon ) proved to have excellent mechanical, thermal and time-dependent properties. The materials database generated from the material testing was used to design turbine hot gas path components, namely the shroud and combustor liner, utilizing the CMC materials. The feasibility of using such MI CMC materials in gas turbine engines was demonstrated via combustion rig testing of turbine shrouds and combustor liners, and through field engine tests of shrouds in a 2MW engine for >1000 hours. A unique combustion test facility was also developed that allowed coupons of the CMC materials to be exposed to high-pressure, high-velocity combustion gas environments for times up to {approx}4000 hours.

  19. Rouse mode analysis of chain relaxation in homopolymer melts

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kalathi, Jagannathan T.; Kumar, Sanat K.; Rubinstein, Michael; Grest, Gary S.

    2014-09-15

    We use molecular dynamics simulations of the Kremer–Grest (KG) bead–spring model of polymer chains of length between 10 and 500, and a closely related analogue that allows for chain crossing, to clearly delineate the effects of entanglements on the length-scale-dependent chain relaxation in polymer melts. We analyze the resulting trajectories using the Rouse modes of the chains and find that entanglements strongly affect these modes. The relaxation rates of the chains show two limiting effective monomeric frictions, with the local modes experiencing much lower effective friction than the longer modes. The monomeric relaxation rates of longer modes vary approximately inverselymore » with chain length due to kinetic confinement effects. The time-dependent relaxation of Rouse modes has a stretched exponential character with a minimum of stretching exponent in the vicinity of the entanglement chain length. None of these trends are found in models that allow for chain crossing. As a result, these facts, in combination, argue for the confined motion of chains for time scales between the entanglement time and their ultimate free diffusion.« less

  20. Tape casting and partial melting of Bi-2212 thick films

    SciTech Connect (OSTI)

    Buhl, D.; Lang, T.; Heeb, B.

    1994-12-31

    To produce Bi-2212 thick films with high critical current densities tape casting and partial melting is a promising fabrication method. Bi-2212 powder and organic additives were mixed into a slurry and tape casted onto glass by the doctor blade tape casting process. The films were cut from the green tape and partially molten on Ag foils during heat treatment. We obtained almost single-phase and well-textured films over the whole thickness of 20 {mu}m. The orientation of the (a,b)-plane of the grains were parallel to the substrate with a misalignment of less than 6{degrees}. At 77K/OT a critical current density of 15`000 A/cm{sup 2} was reached in films of the dimension 1cm x 2cm x 20{mu}m (1{mu}V/cm criterion, resistively measured). At 4K/OT the highest value was 350`000 A/cm{sup 2} (1nV/cm criterion, magnetically measured).

  1. Equilibration of long chain polymer melts in computer simulations.

    SciTech Connect (OSTI)

    Plimpton, Steven James; Kremer, Kurt; Grest, Gary Stephen; Auhl, Rolf; Everaers, Ralf

    2003-06-01

    Several methods for preparing well equilibrated melts of long chains polymers are studied. We show that the standard method in which one starts with an ensemble of chains with the correct end-to-end distance arranged randomly in the simulation cell and introduces the excluded volume rapidly, leads to deformation on short length scales. This deformation is strongest for long chains and relaxes only after the chains have moved their own size. Two methods are shown to overcome this local deformation of the chains. One method is to first pre-pack the Gaussian chains, which reduces the density fluctuations in the system, followed by a gradual introduction of the excluded volume. The second method is a double-bridging algorithm in which new bonds are formed across a pair of chains, creating two new chains each substantially different from the original. We demonstrate the effectiveness of these methods for a linear bead spring polymer model with both zero and nonzero bending stiffness, however the methods are applicable to more complex architectures such as branched and star polymer.

  2. Rouse mode analysis of chain relaxation in homopolymer melts

    SciTech Connect (OSTI)

    Kalathi, Jagannathan T.; Kumar, Sanat K.; Rubinstein, Michael; Grest, Gary S.

    2014-09-15

    We use molecular dynamics simulations of the Kremer–Grest (KG) bead–spring model of polymer chains of length between 10 and 500, and a closely related analogue that allows for chain crossing, to clearly delineate the effects of entanglements on the length-scale-dependent chain relaxation in polymer melts. We analyze the resulting trajectories using the Rouse modes of the chains and find that entanglements strongly affect these modes. The relaxation rates of the chains show two limiting effective monomeric frictions, with the local modes experiencing much lower effective friction than the longer modes. The monomeric relaxation rates of longer modes vary approximately inversely with chain length due to kinetic confinement effects. The time-dependent relaxation of Rouse modes has a stretched exponential character with a minimum of stretching exponent in the vicinity of the entanglement chain length. None of these trends are found in models that allow for chain crossing. As a result, these facts, in combination, argue for the confined motion of chains for time scales between the entanglement time and their ultimate free diffusion.

  3. Energetics of melts from thermal diffusion studies. Final report

    SciTech Connect (OSTI)

    Lesher, C.E.

    1998-12-01

    Most processes in geology are a consequence at some level of the flow of energy or mass. Heat conduction and chemical diffusion are examples of two of these sorts of flows which are driven by temperature and chemical potential imbalances, respectively. In the general case these flows may be coupled so that, for instance, a temperature gradient may result in a flow of mass as well as heat. This effect in liquids was demonstrated by Soret (1879) and bears his name. In gases or solids the phenomenon is given the general name thermal diffusion. It was the purpose of this research program to examine the Soret effect in molten silicates under laboratory conditions. Results of these experiments are used to evaluate the form and quantitative values of many thermodynamic and kinetic properties of silicate melts over a range of temperature, pressure, and bulk composition. The author published a comprehensive review and synthesis with a microscopic theoretical explanation for the effect at low pressure in silicate liquids of geological interest. He conducted experimental investigations of molecular diffusion in the absence of a thermal gradient through experiments involving dissolution of solid silicates in molten silicate and interdiffusion of species between miscible silicate liquids. Collectively these results enable the author to construct a more comprehensive model of molecular diffusion in magmatic liquids. He has applied this model to problems of magma mixing and crustal assimilation.

  4. Zoned electrical heater arranged in spaced relationship from particulate filter

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2011-11-15

    A system comprises a particulate matter (PM) filter that comprises an upstream end for receiving exhaust gas and a downstream end. A zoned heater is arranged spaced from the upstream end and comprises N zones, where N is an integer greater than one, wherein each of the N zones comprises M sub-zones, where M is an integer greater than one. A control module selectively activates at least a selected one of the N zones to initiate regeneration in downstream portions of the PM filter from the one of the N zones and deactivates non-selected ones of the N zones.

  5. Dynamics and pattern selection at the crystal-melt interface. Progress report No. 4, March 1, 1989--February 28, 1990

    SciTech Connect (OSTI)

    Cummins, H.Z.

    1990-12-31

    This report discusses: light scattering at the crystal-melt interface; morphological instability and pattern selection; and sidebranching.

  6. Numerical and experimental investigation of melting with internal heat generation within cylindrical enclosures

    SciTech Connect (OSTI)

    Amber Shrivastava; Brian Williams; Ali S. Siahpush; Bruce Savage; John Crepeau

    2014-06-01

    There have been significant efforts by the heat transfer community to investigate the melting phenomenon of materials. These efforts have included the analytical development of equations to represent melting, numerical development of computer codes to assist in modeling the phenomena, and collection of experimental data. The understanding of the melting phenomenon has application in several areas of interest, for example, the melting of a Phase Change Material (PCM) used as a thermal storage medium as well as the melting of the fuel bundle in a nuclear power plant during an accident scenario. The objective of this research is two-fold. First a numerical investigation, using computational fluid dynamics (CFD), of melting with internal heat generation for a vertical cylindrical geometry is presented. Second, to the best of authors knowledge, there are very limited number of engineering experimental results available for the case of melting with Internal Heat Generation (IHG). An experiment was performed to produce such data using resistive, or Joule, heating as the IHG mechanism. The numerical results are compared against the experimental results and showed favorable correlation. Uncertainties in the numerical and experimental analysis are discussed. Based on the numerical and experimental analysis, recommendations are made for future work.

  7. Intraplate-type magmatism in a continent-island-arc collision zone: Porgera intrusive complex, Papua New Guinea

    SciTech Connect (OSTI)

    Richards, J.P.; Chappell, B.W.; McCulloch, M.T. )

    1990-10-01

    Cogenetic volatile-rich alkali basalts and gabbros, hawaiites, and mugearites occur in the late Miocene age epizonal Porgera intrusive complex, which is temporally and spatially associated with rich gold-silver mineralization. The least evolved rocks show enrichments in light rare earth elements ((La/Yb){sub cn} = 15-19) and other incompatible elements (e.g., Ba/La {approx} 8-10, La/Nb {approx} 0.6-0.7, Sr/Nd {approx} 25) characteristic of intraplate alkalic basalts and have isotopic compositions ({sup 87}Sr/{sup 86}Sr {approx} 0.7035, {epsilon}{sub Nd} {approx} +6, {sup 206}Pb/{sup 204}Pb {approx} 18.66, {sup 207}Pb/{sup 204}Pb {approx} 15.56, {sup 298}Pb/{sup 204}Pb {approx} 38.55) consistent with derivation from a time-averaged depleted mantle source. The Porgera intrusive complex was emplaced at 6 Ma in Jurassic-Cretaceous shelf-facies sedimentary rocks near the edge of the Australasian plate. Intrusion appears to have occurred in a back-arc environment during subduction of an oceanic microplate segment on two sides, beneath the continental margin and an island arc. We suggest that this unusual tectonic setting promoted partial melting of asthenospheric source materials that were perhaps modified by deep (>150 km) subduction processes to form alkalic magmas with intraplate character.

  8. Detonation Reaction Zones in Condensed Explosives

    SciTech Connect (OSTI)

    Tarver, C M

    2005-07-14

    Experimental measurements using nanosecond time resolved embedded gauges and laser interferometric techniques, combined with Non-Equilibrium Zeldovich--von Neumann--Doring (NEZND) theory and Ignition and Growth reactive flow hydrodynamic modeling, have revealed the average pressure/particle velocity states attained in reaction zones of self-sustaining detonation waves in several solid and liquid explosives. The time durations of these reaction zone processes is discussed for explosives based on pentaerythritol tetranitrate (PETN), nitromethane, octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX), triaminitrinitrobenzene(TATB) and trinitrotoluene (TNT).

  9. Innovation and Success in Planning and Zoning | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Planning and Zoning Innovation and Success in Planning and Zoning This document summarizes several successful initiatives to implement solar-friendly planes and zoning codes. webinar_072413_planning_zoning.pdf (2.99 MB) More Documents & Publications webinar_innovation_planning_zoning.doc SunShot Vision Study: February 2012 (Book), SunShot, Energy Efficiency & Renewable Energy (EERE) The SunShot Vision Study

  10. Zone Freezing Study for Pyrochemical Process Waste Minimization

    SciTech Connect (OSTI)

    Ammon Williams

    2012-05-01

    Pyroprocessing technology is a non-aqueous separation process for treatment of used nuclear fuel. At the heart of pyroprocessing lies the electrorefiner, which electrochemically dissolves uranium from the used fuel at the anode and deposits it onto a cathode. During this operation, sodium, transuranics, and fission product chlorides accumulate in the electrolyte salt (LiCl-KCl). These contaminates change the characteristics of the salt overtime and as a result, large volumes of contaminated salt are being removed, reprocessed and stored as radioactive waste. To reduce the storage volumes and improve recycling process for cost minimization, a salt purification method called zone freezing has been proposed at Korea Atomic Energy Research Institute (KAERI). Zone freezing is melt crystallization process similar to the vertical Bridgeman method. In this process, the eutectic salt is slowly cooled axially from top to bottom. As solidification occurs, the fission products are rejected from the solid interface and forced into the liquid phase. The resulting product is a grown crystal with the bulk of the fission products near the bottom of the salt ingot, where they can be easily be sectioned and removed. Despite successful feasibility report from KAERI on this process, there were many unexplored parameters to help understanding and improving its operational routines. Thus, this becomes the main motivation of this proposed study. The majority of this work has been focused on the CsCl-LiCl-KCl ternary salt. CeCl3-LiCl-KCl was also investigated to check whether or not this process is feasible for the trivalent species—surrogate for rare-earths and transuranics. For the main part of the work, several parameters were varied, they are: (1) the retort advancement rate—1.8, 3.2, and 5.0 mm/hr, (2) the crucible lid configurations—lid versus no-lid, (3) the amount or size of mixture—50 and 400 g, (4) the composition of CsCl in the salt—1, 3, and 5 wt%, and (5) the

  11. Theory of melting at high pressures: Amending density functional theory with quantum Monte Carlo

    SciTech Connect (OSTI)

    Shulenburger, L.; Desjarlais, M. P.; Mattsson, T. R.

    2014-10-01

    We present an improved first-principles description of melting under pressure based on thermodynamic integration comparing Density Functional Theory (DFT) and quantum Monte Carlo (QMC) treatments of the system. The method is applied to address the longstanding discrepancy between density functional theory (DFT) calculations and diamond anvil cell (DAC) experiments on the melting curve of xenon, a noble gas solid where van der Waals binding is challenging for traditional DFT methods. The calculations show excellent agreement with data below 20 GPa and that the high-pressure melt curve is well described by a Lindemann behavior up to at least 80 GPa, a finding in stark contrast to DAC data.

  12. Archived Reference Climate Zone: 8 Fairbanks, Alaska

    Broader source: Energy.gov [DOE]

    Here you will find past versions of the commercial reference building models for existing buildings constructed before 1980, organized by building type and location. A summary ofbuilding types and climate zonesis available for reference.Current versionsare also available.

  13. Archived Reference Climate Zone: 8 Fairbanks, Alaska

    Broader source: Energy.gov [DOE]

    Here you will find past versions of the commercial reference building models for existing buildings constructed in or after 1980, organized by building type and location. A summary of building types and climate zones is available for reference. Current versions are also available.

  14. Injectivity Testing for Vapour Dominated Feed Zones

    SciTech Connect (OSTI)

    Clotworthy, A.W.; Hingoyon, C.S.

    1995-01-01

    Wells with vapor dominated feed zones yield abnormal pressure data. This is caused by the condensation of vapor during water injection. A revised injectivity test procedure currently applied by PNOC at the Leyte Geothermal Power Project has improved the injectivity test results.

  15. Climate Zone Number 1 | Open Energy Information

    Open Energy Info (EERE)

    Zone Number 1 is defined as Very Hot - Humid(1A) with IP Units 9000 < CDD50F and SI Units 5000 < CDD10C Dry(1B) with IP Units 9000 < CDD50F and SI Units 5000 < CDD10C...

  16. FED. Zoning for TRUMP Heat Transfer Code

    SciTech Connect (OSTI)

    Elrod, D.

    1987-10-23

    FED reduces the effort required to obtain the necessary geometric input for problems which are to be solved using the heat-transfer code, TRUMP. TRUMP calculates transient and steady-state temperature distributions in multidimensional systems. FED can properly zone any body of revolution in one, two, or three dimensions.

  17. Eastern Energy Zones Mapping Tool Now Available

    Broader source: Energy.gov [DOE]

    The Eastern Interconnection States’ Planning Council (EISPC) has released the Energy Zones (EZ) Mapping Tool, a free, web-based interactive tool that will help states and other stakeholders in the Eastern Interconnection identify geographic areas suitable for the development of clean energy resources which can potentially provide significant amounts of new electric power generation.

  18. Webinar: EISPC Energy Zones Mapping Tool Demonstration

    Broader source: Energy.gov [DOE]

    Argonne National Laboratory has organized a webinar demonstration of the Eastern Interconnection States’ Planning Council (EISPC) Energy Zones (EZ) Mapping Tool, a free online mapping tool for identifying areas in all 39 EISPC states that may be suitable for new clean power generation. The tool is maintained by Argonne National Laboratory with funding from the U.S. Department of Energy.

  19. Archived Reference Climate Zone: 7 Duluth, Minnesota

    Broader source: Energy.gov [DOE]

    Here you will find past versions of the commercial reference building models for existing buildings constructed in or after 1980, organized by building type and location. A summary of building types and climate zones is available for reference. Current versions are also available.

  20. Archived Reference Climate Zone: 7 Duluth, Minnesota

    Broader source: Energy.gov [DOE]

    Here you will find past versions of the commercial reference building models for existing buildings constructed before 1980, organized by building type and location. A summary ofbuilding types and climate zones is available for reference. Current versions are also available.

  1. Site-Scale Saturated Zone Flow Model

    SciTech Connect (OSTI)

    G. Zyvoloski

    2003-12-17

    The purpose of this model report is to document the components of the site-scale saturated-zone flow model at Yucca Mountain, Nevada, in accordance with administrative procedure (AP)-SIII.lOQ, ''Models''. This report provides validation and confidence in the flow model that was developed for site recommendation (SR) and will be used to provide flow fields in support of the Total Systems Performance Assessment (TSPA) for the License Application. The output from this report provides the flow model used in the ''Site-Scale Saturated Zone Transport'', MDL-NBS-HS-000010 Rev 01 (BSC 2003 [162419]). The Site-Scale Saturated Zone Transport model then provides output to the SZ Transport Abstraction Model (BSC 2003 [164870]). In particular, the output from the SZ site-scale flow model is used to simulate the groundwater flow pathways and radionuclide transport to the accessible environment for use in the TSPA calculations. Since the development and calibration of the saturated-zone flow model, more data have been gathered for use in model validation and confidence building, including new water-level data from Nye County wells, single- and multiple-well hydraulic testing data, and new hydrochemistry data. In addition, a new hydrogeologic framework model (HFM), which incorporates Nye County wells lithology, also provides geologic data for corroboration and confidence in the flow model. The intended use of this work is to provide a flow model that generates flow fields to simulate radionuclide transport in saturated porous rock and alluvium under natural or forced gradient flow conditions. The flow model simulations are completed using the three-dimensional (3-D), finite-element, flow, heat, and transport computer code, FEHM Version (V) 2.20 (software tracking number (STN): 10086-2.20-00; LANL 2003 [161725]). Concurrently, process-level transport model and methodology for calculating radionuclide transport in the saturated zone at Yucca Mountain using FEHM V 2.20 are being

  2. High exhaust temperature, zoned, electrically-heated particulate matter filter

    DOE Patents [OSTI]

    Gonze, Eugene V.; Paratore, Jr., Michael J.; Bhatia, Garima

    2015-09-22

    A system includes a particulate matter (PM) filter, an electric heater, and a control circuit. The electric heater includes multiple zones, which each correspond to longitudinal zones along a length of the PM filter. A first zone includes multiple discontinuous sub-zones. The control circuit determines whether regeneration is needed based on an estimated level of loading of the PM filter and an exhaust flow rate. In response to a determination that regeneration is needed, the control circuit: controls an operating parameter of an engine to increase an exhaust temperature to a first temperature during a first period; after the first period, activates the first zone; deactivates the first zone in response to a minimum filter face temperature being reached; subsequent to deactivating the first zone, activates a second zone; and deactivates the second zone in response to the minimum filter face temperature being reached.

  3. Melting of “non-magic” argon clusters and extrapolation to the bulk limit

    SciTech Connect (OSTI)

    Senn, Florian Wiebke, Jonas; Schumann, Ole; Gohr, Sebastian; Schwerdtfeger, Peter; Pahl, Elke

    2014-01-28

    The melting of argon clusters Ar{sub N} is investigated by applying a parallel-tempering Monte Carlo algorithm for all cluster sizes in the range from 55 to 309 atoms. Extrapolation to the bulk gives a melting temperature of 85.9 K in good agreement with the previous value of 88.9 K using only Mackay icosahedral clusters for the extrapolation [E. Pahl, F. Calvo, L. Koči, and P. Schwerdtfeger, “Accurate melting temperatures for neon and argon from ab initio Monte Carlo simulations,” Angew. Chem., Int. Ed. 47, 8207 (2008)]. Our results for argon demonstrate that for the extrapolation to the bulk one does not have to restrict to magic number cluster sizes in order to obtain good estimates for the bulk melting temperature. However, the extrapolation to the bulk remains a problem, especially for the systematic selection of suitable cluster sizes.

  4. The Use of Induction Melting for the Treatment of Metal Radioactive Waste - 13088

    SciTech Connect (OSTI)

    Zherebtsov, Alexander; Pastushkov, Vladimir; Poluektov, Pavel; Smelova, Tatiana; Shadrin, Andrey

    2013-07-01

    The aim of the work is to assess the efficacy of induction melting metal for recycling radioactive waste in order to reduce the volume of solid radioactive waste to be disposed of, and utilization of the metal. (authors)

  5. Mathematical modeling of cold cap: Effect of bubbling on melting rate

    SciTech Connect (OSTI)

    Pokorny, Richard; Kruger, Albert A.; Hrma, Pavel R.

    2014-12-31

    The rate of melting is a primary concern in the vitrification of radioactive wastes because it directly influences the life cycle of nuclear waste cleanup efforts. To increase glass melting performance, experimental and industrial all-electric waste glass melters employ various melt-rate enhancement techniques, the most prominent being the application of bubblers submerged into molten glass. This study investigates various ways in which bubbling affects melting rate in a waste glass melter. Using the recently developed cold cap model, we suggest that forced convection of molten glass, which increases the cold cap bottom temperature, is the main factor. Other effects, such as stirring the feed into molten glass or reducing the insulating effect of foaming, also play a role.

  6. Migration of carbon in tempered martensitic steel during excimer laser melting

    SciTech Connect (OSTI)

    Hirvonen, J.P.; Jervis, T.R.; Zocco, T.G.

    1989-01-01

    The migration of ion implanted {sup 13}C in tempered martensitic steel (nominal composition 1.05 wt. % C, 0.2 wt. % Si, and 0.3 wt. % Mn) during excimer laser melting was examined utilizing the resonance of the {sup 13}C(p,{gamma}){sup 14}N reaction at Ep = 1747.6 keV. Depth concentration profiles after five and ten laser pulses of 1 J/cm{sup 2} revealed deviation from random walk diffusion in a homogeneous media. This was modelled by using the solubility controlled flow of carbon in iron-carbon melt. A diffusion length of 2{radical}D{tau} 34 {plus minus} 2 nm during a period {tau} of the melted phase was deduced. Significant amorphous to crystalline transformation occurred during the rapid self quenching following laser melting. 18 refs., 3 figs.

  7. Energy-Efficient Melting and Direct Delivery of High Quality Molten Aluminum

    SciTech Connect (OSTI)

    None

    2009-05-01

    This factsheet describes a research project whose main objective is demonstrating a technology that will eliminate melting and holding furnaces at the casting cell and move these operations to centralized and optimized off-site facilities.

  8. Melting in the Iron-Oxygen-Silicon System up to 85 GPa. (Journal...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Melting in the Iron-Oxygen-Silicon System up to 85 GPa. Citation Details ... Country of Publication: United States Language: English Word Cloud More Like This Full ...

  9. Melting in the Iron-Oxygen-Silicon System up to 85 GPa. (Journal...

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Search Results Journal Article: Melting in the Iron-Oxygen-Silicon System ... Country of Publication: United States Language: English Word Cloud More Like This Full ...

  10. Analysis of impact melt and vapor production in CTH for planetary applications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Quintana, S. N.; Crawford, D. A.; Schultz, P. H.

    2015-05-19

    This study explores impact melt and vapor generation for a variety of impact speeds and materials using the shock physics code CTH. The study first compares the results of two common methods of impact melt and vapor generation to demonstrate that both the peak pressure method and final temperature method are appropriate for high-speed impact models (speeds greater than 10 km/s). However, for low-speed impact models (speeds less than 10 km/s), only the final temperature method is consistent with laboratory analyses to yield melting and vaporization. Finally, a constitutive model for material strength is important for low-speed impacts because strengthmore » can cause an increase in melting and vaporization.« less

  11. Melting Hanford LAW into Iron-Phosphate Glass in a CCIM (Technical...

    Office of Scientific and Technical Information (OSTI)

    Title: Melting Hanford LAW into Iron-Phosphate Glass in a CCIM A vitrification test has been conducted using the cold crucible induction melter (CCIM) test system at the Idaho ...

  12. High Pressure Melting Curve of TIn (Journal Article) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    High Pressure Melting Curve of TIn Citation Details ... OSTI Identifier: 1124823 Report Number(s): LLNL-JRNL-522418 DOE Contract Number: W-7405-ENG-48 Resource Type: Journal ...

  13. Controlling electrode gap during vacuum arc remelting at low melting current

    DOE Patents [OSTI]

    Williamson, R.L.; Zanner, F.J.; Grose, S.M.

    1997-04-15

    An apparatus and method are disclosed for controlling electrode gap in a vacuum arc remelting furnace, particularly at low melting currents. Spectrographic analysis is performed of the metal vapor plasma, from which estimates of electrode gap are derived. 5 figs.

  14. Controlling electrode gap during vacuum arc remelting at low melting current

    DOE Patents [OSTI]

    Williamson, Rodney L.; Zanner, Frank J.; Grose, Stephen M.

    1997-01-01

    An apparatus and method for controlling electrode gap in a vacuum arc remelting furnace, particularly at low melting currents. Spectrographic analysis is performed of the metal vapor plasma, from which estimates of electrode gap are derived.

  15. Status of understanding of the saturated-zone ground-water flow system at Yucca Mountain, Nevada, as of 1995

    SciTech Connect (OSTI)

    Luckey, R.R.; Tucci, P.; Faunt, C.C.; Ervin, E.M.

    1996-12-31

    Yucca Mountain, which is being studied extensively because it is a potential site for a high-level radioactive-waste repository, consists of a thick sequence of volcanic rocks of Tertiary age that are underlain, at least to the southeast, by carbonate rocks of Paleozoic age. Stratigraphic units important to the hydrology of the area include the alluvium, pyroclastic rocks of Miocene age (the Timber Mountain Group; the Paintbrush Group; the Calico Hills Formation; the Crater Flat Group; the Lithic Ridge Tuff; and older tuffs, flows, and lavas beneath the Lithic Ridge Tuff), and sedimentary rocks of Paleozoic age. The saturated zone generally occurs in the Calico Hills Formation and stratigraphically lower units. The saturated zone is divided into three aquifers and two confining units. The flow system at Yucca Mountain is part of the Alkali Flat-Furnace Creek subbasin of the Death Valley groundwater basin. Variations in the gradients of the potentiometric surface provided the basis for subdividing the Yucca Mountain area into zones of: (1) large hydraulic gradient where potentiometric levels change at least 300 meters in a few kilometers; (2) moderate hydraulic gradient where potentiometric levels change about 45 meters in a few kilometers; and (3) small hydraulic gradient where potentiometric levels change only about 2 meters in several kilometers. Vertical hydraulic gradients were measured in only a few boreholes around Yucca Mountain; most boreholes had little change in potentiometric levels with depth. Limited hydraulic testing of boreholes in the Yucca Mountain area indicated that the range in transmissivity was more than 2 to 3 orders of magnitude in a particular hydrogeologic unit, and that the average values for the individual hydrogeologic units generally differed by about 1 order of magnitude. The upper volcanic aquifer seems to be the most permeable hydrogeologic unit, but this conclusion was based on exceedingly limited data.

  16. New climate model predicts likelihood of Greenland ice melt, sea level rise

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and dangerous temperatures New climate model predicts likelihood of Greenland ice melt New climate model predicts likelihood of Greenland ice melt, sea level rise and dangerous temperatures A new computer model of accumulated carbon emissions predicts the likelihood of crossing several dangerous climate change thresholds. November 20, 2015 Greenland ice loss. Greenland ice loss. Contact Kevin Roark Communications Office (505) 665-9202 Email "The model is based on idealized

  17. Ab Initio Investigation of the Melting Line of Nitrogen at High Pressure |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne Leadership Computing Facility Investigation of the Melting Line of Nitrogen at High Pressure Authors: Donadio, D., Spanu, L., Duchemin, I., Gygi, F., Galli, G. Understanding the behavior of molecular systems under pressure is a fundamental problem in condensed-matter physics. In the case of nitrogen, the determination of the phase diagram and, in particular, of the melting line, are largely open problems. Two independent experiments have reported the presence of a maximum in the

  18. Voronoi analysis of the short–range atomic structure in iron and iron–carbon melts

    SciTech Connect (OSTI)

    Sobolev, Andrey; Mirzoev, Alexander

    2015-08-17

    In this work, we simulated the atomic structure of liquid iron and iron–carbon alloys by means of ab initio molecular dynamics. Voronoi analysis was used to highlight changes in the close environments of Fe atoms as carbon concentration in the melt increases. We have found, that even high concentrations of carbon do not affect short–range atomic order of iron atoms — it remains effectively the same as in pure iron melts.

  19. Contribution of Anticipated Transients Without Scram (ATWS) to core melt at United States nuclear power plants

    SciTech Connect (OSTI)

    Giachetti, R.T. (Giachetti (Richard T.), Ann Arbor, MI (USA))

    1989-09-01

    This report looks at WASH-1400 and several other Probabilistic Risk Assessments (PRAs) and Probabilistic Safety Studies (PSSs) to determine the contribution of Anticipated Transients Without Scram (ATWS) events to the total core melt probability at eight nuclear power plants in the United States. After considering each plant individually, the results are compared from plant to plant to see if any generic conclusions regarding ATWS, or core melt in general, can be made. 8 refs., 34 tabs.

  20. Chemistry modification of high oxygen-carbon powder by plasma melting: Follow up to complete the story

    SciTech Connect (OSTI)

    Dunn, P.S.; Korzekwa, D.R.; Garcia, F.G.; Michaluk, C.A.

    1998-03-01

    State of the art melting of tantalum and tantalum alloys has relied on electron beam (EB) or vacuum arc remelting (VAR) for commercial ingot production. Plasma arc melting (PAM) provides an alternative for melting tantalum that contains very high levels of interstitials where other melting techniques can not be applied. Previous work in this area centered on plasma arc melt quality and final interstitial content of tantalum feedstock containing excessive levels of interstitial impurities as a function of melt rate and plasma gas. This report is an expansion of this prior study and provides the findings from the analysis of second phase components observed in the microstructure of the PAM tantalum. In addition, results from subsequent EB melting trials of PAM tantalum are included.

  1. Investigation of MSWI fly ash melting characteristic by DSC-DTA

    SciTech Connect (OSTI)

    Li, Rundong Wang, Lei; Yang, Tianhua; Raninger, Bernhard

    2007-07-01

    The melting process of MSWI (Municipal Solid Waste Incineration) fly ash has been studied by high-temperature DSC-DTA experiments. The experiments were performed at a temperature range of 20-1450 deg. C, and the considerable variables included atmosphere (O{sub 2} and N{sub 2}), heating rates (5 deg. C/min, 10 deg. C/min, 20 deg. C/min) and CaO addition. Three main transitions were observed during the melting process of fly ash: dehydration, polymorphic transition and fusion, occurring in the temperature range of 100-200 deg. C, 480-670 deg. C and 1101-1244 deg. C, respectively. The apparent heat capacity and heat requirement for melting of MSWI fly ash were obtained by DSC (Differential Scanning Calorimeter). A thermodynamic modeling to predict the heat requirements for melting process has been presented, and it agrees well with the experimental data. Finally, a zero-order kinetic model of fly ash melting transition was established. The apparent activation energy of MSWI fly ash melting transition was obtained.

  2. Melt spreading code assessment, modifications, and application to the EPR core catcher design.

    SciTech Connect (OSTI)

    Farmer, M. T .; Nuclear Engineering Division

    2009-03-30

    The Evolutionary Power Reactor (EPR) is under consideration by various utilities in the United States to provide base load electrical production, and as a result the design is undergoing a certification review by the U.S. Nuclear Regulatory Commission (NRC). The severe accident design philosophy for this reactor is based upon the fact that the projected power rating results in a narrow margin for in-vessel melt retention by external cooling of the reactor vessel. As a result, the design addresses ex-vessel core melt stabilization using a mitigation strategy that includes: (1) an external core melt retention system to temporarily hold core melt released from the vessel; (2) a layer of 'sacrificial' material that is admixed with the melt while in the core melt retention system; (3) a melt plug in the lower part of the retention system that, when failed, provides a pathway for the mixture to spread to a large core spreading chamber; and finally, (4) cooling and stabilization of the spread melt by controlled top and bottom flooding. The overall concept is illustrated in Figure 1.1. The melt spreading process relies heavily on inertial flow of a low-viscosity admixed melt to a segmented spreading chamber, and assumes that the melt mass will be distributed to a uniform height in the chamber. The spreading phenomenon thus needs to be modeled properly in order to adequately assess the EPR design. The MELTSPREAD code, developed at Argonne National Laboratory, can model segmented, and both uniform and nonuniform spreading. The NRC is thus utilizing MELTSPREAD to evaluate melt spreading in the EPR design. MELTSPREAD was originally developed to support resolution of the Mark I containment shell vulnerability issue. Following closure of this issue, development of MELTSPREAD ceased in the early 1990's, at which time the melt spreading database upon which the code had been validated was rather limited. In particular, the database that was utilized for initial validation consisted

  3. Analysis of offsite emergency planning zones project

    SciTech Connect (OSTI)

    Petrocchi, A.J.; Armstrong, C.E. . Rocky Flats Plant); McKinney, J.M.; Verholek, M.G.; Fraser, P.J.; Dalfonso, P.H. )

    1991-07-18

    The Rocky Flats Plant maintains and uses significant nonradioactive chemically hazardous material (HAZMAT) inventories. Some of these materials are used in sufficient quantities to represent a credible risk to the offsite public in the event of an emergency at the facility. In Phase 2 of this project, the EG G Rocky Flats, Inc. and TENERA, L.P. Task Team (Task Team) produced an initial screening-level modeling analysis study and an Emergency Planning Zone (EPZ) encompassing the Vulnerable Zones (VZs) for hazardous materials stored at the facility. The screening-level analysis will be supplemented with more refined evaluations during subsequent phases of the project. The existence of these chemicals in the Rocky Flats Plant Occupational Health Information System (OHIS) chemical inventory database was verified. All liquid and gaseous chemicals were considered as potential hazardous material source terms for further screening analysis. Hazards associated with solid substances were not considered in this phase of the project. 2 figs., 13 tabs.

  4. Vadose Zone Transport Field Study: Summary Report

    SciTech Connect (OSTI)

    Ward, Andy L.; Conrad, Mark E.; Daily, William D.; Fink, James B.; Freedman, Vicky L.; Gee, Glendon W.; Hoversten, Gary M.; Keller, Jason M.; Majer, Ernest L.; Murray, Christopher J.; White, Mark D.; Yabusaki, Steven B.; Zhang, Z. F.

    2006-07-31

    From FY 2000 through FY 2003, a series of vadose zone transport field experiments were conducted as part of the U.S. Department of Energys Groundwater/Vadose Zone Integration Project Science and Technology Project, now known as the Remediation and Closure Science Project, and managed by the Pacific Northwest National Laboratory (PNNL). The series of experiments included two major field campaigns, one at a 299-E24-11 injection test site near PUREX and a second at a clastic dike site off Army Loop Road. The goals of these experiments were to improve our understanding of vadose zone transport processes; to develop data sets to validate and calibrate vadose zone flow and transport models; and to identify advanced monitoring techniques useful for evaluating flow-and-transport mechanisms and delineating contaminant plumes in the vadose zone at the Hanford Site. This report summarizes the key findings from the field studies and demonstrates how data collected from these studies are being used to improve conceptual models and develop numerical models of flow and transport in Hanfords vadose zone. Results of these tests have led to a better understanding of the vadose zone. Fine-scale geologic heterogeneities, including grain fabric and lamination, were observed to have a strong effect on the large-scale behavior of contaminant plumes, primarily through increased lateral spreading resulting from anisotropy. Conceptual models have been updated to include lateral spreading and numerical models of unsaturated flow and transport have revised accordingly. A new robust model based on the concept of a connectivity tensor was developed to describe saturation-dependent anisotropy in strongly heterogeneous soils and has been incorporated into PNNLs Subsurface Transport Over Multiple Phases (STOMP) simulator. Application to field-scale transport problems have led to a better understanding plume behavior at a number of sites where lateral spreading may have dominated waste migration

  5. Diesel particulate filter with zoned resistive heater

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2011-03-08

    A diesel particulate filter assembly comprises a diesel particulate filter (DPF) and a heater assembly. The DPF filters a particulate from exhaust produced by an engine. The heater assembly has a first metallic layer that is applied to the DPF, a resistive layer that is applied to the first metallic layer, and a second metallic layer that is applied to the resistive layer. The second metallic layer is etched to form a plurality of zones.

  6. Rural Productivity Zones (RPZs) for microenterprises

    SciTech Connect (OSTI)

    Hansen, R.D.

    1997-12-01

    In this paper the authors discuss the concept of rural productivity zones (RPZs) which are defined as a business incubator to foster income-producing opportunities for the rural poor. The essential ingredients of such a program include: electric power; business development assistance; office services; and quality work space. The electric power source must be a good quality system, consisting of a diesel/wind/photovoltaic hybrid type system, providing reliable service, with a local maintenance program and a functional load management program.

  7. Capillary zone electrophoresis-mass spectrometer interface

    DOE Patents [OSTI]

    D`Silva, A.

    1996-08-06

    A device for providing equal electrical potential between two loci unconnected by solid or liquid electrical conductors is provided. The device comprises a first electrical conducting terminal, a second electrical conducting terminal connected to the first terminal by a rigid dielectric structure, and an electrically conducting gas contacting the first and second terminals. This device is particularly suitable for application in the electrospray ionization interface between a capillary zone electrophoresis apparatus and a mass spectrometer. 1 fig.

  8. Capillary zone electrophoresis-mass spectrometer interface

    DOE Patents [OSTI]

    D'Silva, Arthur

    1996-08-06

    A device for providing equal electrical potential between two loci unconnected by solid or liquid electrical conducts is provided. The device comprises a first electrical conducting terminal, a second electrical conducting terminal connected to the first terminal by a rigid dielectric structure, and an electrically conducting gas contacting the first and second terminals. This device is particularly suitable for application in the electrospray ionization interface between a capillary zone electrophoresis apparatus and a mass spectrometer.

  9. Baroclinic instability in stellar radiation zones

    SciTech Connect (OSTI)

    Kitchatinov, L. L.

    2014-03-20

    Surfaces of constant pressure and constant density do not coincide in differentially rotating stars. Stellar radiation zones with baroclinic stratification can be unstable. Instabilities in radiation zones are of crucial importance for angular momentum transport, mixing of chemical species, and, possibly, for magnetic field generation. This paper performs linear analysis of baroclinic instability in differentially rotating stars. Linear stability equations are formulated for differential rotation of arbitrary shape and then solved numerically for rotation nonuniform in radius. As the differential rotation increases, r- and g-modes of initially stable global oscillations transform smoothly into growing modes of baroclinic instability. The instability can therefore be interpreted as stability loss to r- and g-modes excitation. Regions of stellar parameters where r- or g-modes are preferentially excited are defined. Baroclinic instability onsets at a very small differential rotation of below 1%. The characteristic time of instability growth is about 1000 rotation periods. Growing disturbances possess kinetic helicity. Magnetic field generation by the turbulence resulting from baroclinic instability in differentially rotating radiation zones is therefore possible.

  10. Gulf of California Rift Zone Geothermal Region | Open Energy...

    Open Energy Info (EERE)

    Projects (0) Techniques (0) Map: Name The Gulf of California rift zone is a complex transition zone between the dextral (right-lateral) motion of the San Andreas transform...

  11. Evaluation of a Multifamily Retrofit in Climate Zone 5, Boulder...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Project Name: Evaluation of a Low-Rise Multifamily Retrofit in Boulder, CO Location: ... Applicable Climate Zone(s): Cold, very cold PERFORMANCE DATA Cost of Energy Efficiency Measure ...

  12. Diffusion releases through one and two finite planar zones from...

    Office of Scientific and Technical Information (OSTI)

    When the effective diffusion coefficient in the first zone is several orders of magnitude lower than that in the host rock, then the two-zone geometry can be approximately by a ...

  13. DETERMINATION OF HLW GLASS MELT RATE USING X-RAY COMPUTED TOMOGRAPHY

    SciTech Connect (OSTI)

    Choi, A.; Miller, D.; Immel, D.

    2011-10-06

    The purpose of the high-level waste (HLW) glass melt rate study is two-fold: (1) to gain a better understanding of the impact of feed chemistry on melt rate through bench-scale testing, and (2) to develop a predictive tool for melt rate in support of the on-going frit development efforts for the Defense Waste Processing Facility (DWPF). In particular, the focus is on predicting relative melt rates, not the absolute melt rates, of various HLW glass formulations solely based on feed chemistry, i.e., the chemistry of both waste and glass-forming frit for DWPF. Critical to the successful melt rate modeling is the accurate determination of the melting rates of various HLW glass formulations. The baseline procedure being used at the Savannah River National Laboratory (SRNL) is to; (1) heat a 4 inch-diameter stainless steel beaker containing a mixture of dried sludge and frit in a furnace for a preset period of time, (2) section the cooled beaker along its diameter, and (3) measure the average glass height across the sectioned face using a ruler. As illustrated in Figure 1-1, the glass height is measured for each of the 16 horizontal segments up to the red lines where relatively large-sized bubbles begin to appear. The linear melt rate (LMR) is determined as the average of all 16 glass height readings divided by the time during which the sample was kept in the furnace. This 'visual' method has proved useful in identifying melting accelerants such as alkalis and sulfate and further ranking the relative melt rates of candidate frits for a given sludge batch. However, one of the inherent technical difficulties of this method is to determine the glass height in the presence of numerous gas bubbles of varying sizes, which is prevalent especially for the higher-waste-loading glasses. That is, how the red lines are drawn in Figure 1-1 can be subjective and, therefore, may influence the resulting melt rates significantly. For example, if the red lines are drawn too low, a

  14. Reaction of Inconel 690 and 693 in Iron Phosphate Melts: Alternative Glasses for Waste Vitrification

    SciTech Connect (OSTI)

    Day, Delbert E.

    2005-09-13

    The corrosion resistance of candidate materials used for the electrodes (Inconel 690 & 693) and the melt contact refractory (Monofrax K-3) in a Joule Heated Melter (JHM) has been investigated at the University of Missouri-Rolla (UMR) during the period from June 1, 2004 to August 31, 2005. This work was supported by the U.S. Department of Energy (DOE) Office of Biological and Environmental Research (DE-FG02-04ER63831). The unusual properties and characteristics of iron phosphate glasses, as viewed from the standpoint of alternative glasses for vitrifying nuclear and hazardous wastes which contain components that make them poorly suited for vitrification in borosilicate glass, were recently discovered at UMR. The expanding national and international interest in iron phosphate glasses for waste vitrification stems from their rapid melting and chemical homogenization which results in higher furnace output, their high waste loading that varies from 32 wt% up to 75 wt% for the Hanford LAW and HLW, respectively, and the outstanding chemical durability of the iron phosphate wasteforms which meets all present DOE requirements (PCT and VHT). The higher waste loading in iron phosphate glasses, compared to the baseline borosilicate glass, can reduce the time and cost of vitrification considerably since a much smaller mass of glass will be produced, for example, about 43% less glass when the LAW at Hanford is vitrified in an iron phosphate glass according to PNNL estimates. In view of the promising performance of iron phosphate glasses, information is needed for how to best melt these glasses on the scale needed for practical use. Melting iron phosphate glasses in a JHM is considered the preferred method at this time because its design could be nearly identical to the JHM now used to melt borosilicate glasses at the Defense Waste Processing Facility (DWPF), Westinghouse Savannah River Co. Therefore, it is important to have information for the corrosion of candidate electrode

  15. On the Chemistry and Physical Properties of Flux and Floating Zone Grown SmB6 Single Crystals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Phelan, W. A.; Koohpayeh, S. M.; Cottingham, P.; Tutmaher, J. A.; Leiner, J. C.; Lumsden, M. D.; Lavelle, C. M.; Wang, X. P.; Hoffmann, C.; Siegler, M. A.; et al

    2016-02-19

    Recent theoretical and experimental findings suggest the long-known but not well understood low temperature resistance plateau of SmB6 may originate from protected surface states arising from a topologically non-trivial bulk band structure having strong Kondo hybridization. Yet others have ascribed this feature to impurities, vacancies, and surface reconstructions. Given the typical methods used to prepare SmB6 single crystals, flux and floating-zone procedures, such ascriptions should not be taken lightly. We demonstrate how compositional variations and/or observable amounts of impurities in SmB6 crystals grown using both procedures affect the physical properties. From X-ray diffraction, neutron diffraction, and X-ray computed tomography experimentsmore » we observe that natural isotope containing (SmB6) and doubly isotope enriched (154Sm11B6) crystals prepared using aluminum flux contain co-crystallized, epitaxial aluminum. Further, a large, nearly stoichiometric crystal of SmB6 was successfully grown using the float-zone technique; upon continuing the zone melting, samarium vacancies were introduced. These samarium vacancies drastically alter the resistance and plateauing magnitude of the low temperature resistance compared to stoichiometric SmB6. Finally, these results highlight that impurities and compositional variations, even at low concentrations, must be considered when collecting/analyzing physical property data of SmB6. Finally, a more accurate samarium-154 coherent neutron scattering length, 8.9(1) fm, is reported.« less

  16. Modeling-Computer Simulations At Central Nevada Seismic Zone...

    Open Energy Info (EERE)

    navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Modeling-Computer Simulations At Central Nevada Seismic Zone Region (Pritchett, 2004) Exploration...

  17. DOE New Madrid Seismic Zone Electric Utility Workshop Summary Report -

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    August 2010 | Department of Energy New Madrid Seismic Zone Electric Utility Workshop Summary Report - August 2010 DOE New Madrid Seismic Zone Electric Utility Workshop Summary Report - August 2010 The DOE New Madrid Seismic Zone Electric Utilities Workshop, held in Memphis, TN, in July 2010 for the electric utilities in the seismic zone was a chance to bring together a diverse set of industry partners to discuss the potential effects of an earthquake in the New Madrid and Wabash Valley

  18. Modeling magnetic fields from a DC power cable buried beneath San Francisco Bay based on empirical measurements

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kavet, Robert; Wyman, Megan T.; Klimley, A. Peter; Carretero, Luis

    2016-02-25

    Here, the Trans Bay Cable (TBC) is a ±200-kilovolt (kV), 400 MW 85-km long High Voltage Direct Current (DC) buried transmission line linking Pittsburg, CA with San Francisco, CA (SF) beneath the San Francisco Estuary. The TBC runs parallel to the migratory route of various marine species, including green sturgeon, Chinook salmon, and steelhead trout. In July and August 2014, an extensive series of magnetic field measurements were taken using a pair of submerged Geometrics magnetometers towed behind a survey vessel in four locations in the San Francisco estuary along profiles that cross the cable’s path; these included the Sanmore » Francisco-Oakland Bay Bridge (BB), the Richmond-San Rafael Bridge (RSR), the Benicia- Martinez Bridge (Ben) and an area in San Pablo Bay (SP) in which a bridge is not present. In this paper, we apply basic formulas that ideally describe the magnetic field from a DC cable summed vectorially with the background geomagnetic field (in the absence of other sources that would perturb the ambient field) to derive characteristics of the cable that are otherwise not immediately observable. Magnetic field profiles from measurements taken along 170 survey lines were inspected visually for evidence of a distinct pattern representing the presence of the cable. Many profiles were dominated by field distortions unrelated to the cable caused by bridge structures or other submerged objects, and the cable’s contribution to the field was not detectable. BB, with 40 of the survey lines, did not yield usable data for these reasons. The unrelated anomalies could be up to 100 times greater than those from the cable. In total, discernible magnetic field profiles measured from 76 survey lines were regressed against the equations, representing eight days of measurement. The modeled field anomalies due to the cable (the difference between the maximum and minimum field along the survey line at the cable crossing) were virtually identical to the measured

  19. SATURATED ZONE IN-SITU TESTING

    SciTech Connect (OSTI)

    P.W. REIMUS

    2004-11-08

    The purpose of this scientific analysis is to document the results and interpretations of field experiments that test and validate conceptual flow and radionuclide transport models in the saturated zone (SZ) near Yucca Mountain, Nevada. The test interpretations provide estimates of flow and transport parameters used in the development of parameter distributions for total system performance assessment (TSPA) calculations. These parameter distributions are documented in ''Site-Scale Saturated Zone Flow Model (BSC 2004 [DIRS 170037]), Site-Scale Saturated Zone Transport'' (BSC 2004 [DIRS 170036]), Saturated Zone Colloid Transport (BSC 2004 [DIRS 170006]), and ''Saturated Zone Flow and Transport Model Abstraction'' (BSC 2004 [DIRS 170042]). Specifically, this scientific analysis contributes the following to the assessment of the capability of the SZ to serve as part of a natural barrier for waste isolation for the Yucca Mountain repository system: (1) The bases for selection of conceptual flow and transport models in the saturated volcanics and the saturated alluvium located near Yucca Mountain. (2) Results and interpretations of hydraulic and tracer tests conducted in saturated fractured volcanics at the C-wells complex near Yucca Mountain. The test interpretations include estimates of hydraulic conductivities, anisotropy in hydraulic conductivity, storativities, total porosities, effective porosities, longitudinal dispersivities, matrix diffusion mass transfer coefficients, matrix diffusion coefficients, fracture apertures, and colloid transport parameters. (3) Results and interpretations of hydraulic and tracer tests conducted in saturated alluvium at the Alluvial Testing Complex (ATC) located at the southwestern corner of the Nevada Test Site (NTS). The test interpretations include estimates of hydraulic conductivities, storativities, total porosities, effective porosities, longitudinal dispersivities, matrix diffusion mass transfer coefficients, and colloid

  20. Zoning for Distributed Wind Power - Breaking Down Barriers: Preprint

    SciTech Connect (OSTI)

    Green, J.; Sagrillo, M.

    2005-08-01

    Zoning regulations for the use of small wind turbines vary from state to state and from one local jurisdiction to the next. This paper examines the zoning experiences of small wind turbine owners, options for local actions, and examples of state and federal limited preemption of local zoning authority as a means of promoting the implementation of new technologies.

  1. Models and correlations of the DEBRIS Late-Phase Melt Progression Model

    SciTech Connect (OSTI)

    Schmidt, R.C.; Gasser, R.D.

    1997-09-01

    The DEBRIS Late Phase Melt Progression Model is an assembly of models, embodied in a computer code, which is designed to treat late-phase melt progression in dry rubble (or debris) regions that can form as a consequence of a severe core uncover accident in a commercial light water nuclear reactor. The approach is fully two-dimensional, and incorporates a porous medium modeling framework together with conservation and constitutive relationships to simulate the time-dependent evolution of such regions as various physical processes act upon the materials. The objective of the code is to accurately model these processes so that the late-phase melt progression that would occur in different hypothetical severe nuclear reactor accidents can be better understood and characterized. In this report the models and correlations incorporated and used within the current version of DEBRIS are described. These include the global conservation equations solved, heat transfer and fission heating models, melting and refreezing models (including material interactions), liquid and solid relocation models, gas flow and pressure field models, and the temperature and compositionally dependent material properties employed. The specific models described here have been used in the experiment design analysis of the Phebus FPT-4 debris-bed fission-product release experiment. An earlier DEBRIS code version was used to analyze the MP-1 and MP-2 late-phase melt progression experiments conducted at Sandia National Laboratories for the US Nuclear Regulatory Commission.

  2. Nuclear reactor melt-retention structure to mitigate direct containment heating

    DOE Patents [OSTI]

    Tutu, Narinder K.; Ginsberg, Theodore; Klages, John R.

    1991-01-01

    A light water nuclear reactor melt-retention structure to mitigate the extent of direct containment heating of the reactor containment building. The structure includes a retention chamber for retaining molten core material away from the upper regions of the reactor containment building when a severe accident causes the bottom of the pressure vessel of the reactor to fail and discharge such molten material under high pressure through the reactor cavity into the retention chamber. In combination with the melt-retention chamber there is provided a passageway that includes molten core droplet deflector vanes and has gas vent means in its upper surface, which means are operable to deflect molten core droplets into the retention chamber while allowing high pressure steam and gases to be vented into the upper regions of the containment building. A plurality of platforms are mounted within the passageway and the melt-retention structure to direct the flow of molten core material and help retain it within the melt-retention chamber. In addition, ribs are mounted at spaced positions on the floor of the melt-retention chamber, and grid means are positioned at the entrance side of the retention chamber. The grid means develop gas back pressure that helps separate the molten core droplets from discharged high pressure steam and gases, thereby forcing the steam and gases to vent into the upper regions of the reactor containment building.

  3. Lattice model of linear telechelic polymer melts. II. Influence of chain stiffness on basic thermodynamic properties

    SciTech Connect (OSTI)

    Xu, Wen-Sheng; Freed, Karl F.

    2015-07-14

    The lattice cluster theory (LCT) for semiflexible linear telechelic melts, developed in Paper I, is applied to examine the influence of chain stiffness on the average degree of self-assembly and the basic thermodynamic properties of linear telechelic polymer melts. Our calculations imply that chain stiffness promotes self-assembly of linear telechelic polymer melts that assemble on cooling when either polymer volume fraction ϕ or temperature T is high, but opposes self-assembly when both ϕ and T are sufficiently low. This allows us to identify a boundary line in the ϕ-T plane that separates two regions of qualitatively different influence of chain stiffness on self-assembly. The enthalpy and entropy of self-assembly are usually treated as adjustable parameters in classical Flory-Huggins type theories for the equilibrium self-assembly of polymers, but they are demonstrated here to strongly depend on chain stiffness. Moreover, illustrative calculations for the dependence of the entropy density of linear telechelic polymer melts on chain stiffness demonstrate the importance of including semiflexibility within the LCT when exploring the nature of glass formation in models of linear telechelic polymer melts.

  4. Decontamination of metals by melt refining/slagging: First year progress report

    SciTech Connect (OSTI)

    Mizia, R.E.; Worcester, S.A.; Twidwell, L.G.; Paolini, D.J.; Weldon, T.A.

    1994-03-01

    As the number of nuclear installations undergoing decontamination and decommissioning (D&D) increases, current radioactive waste storage space is consumed and establishment of new waste storage areas becomes increasingly difficult. The problem of handling and storing radioactive scrap metal (RSM) gains increasing importance in the DOE Environmental Restoration and Waste Management Program. To alleviate present and future waste storage problems, Westinghouse Idaho Nuclear Company (WINCO) is managing a program for the recycling of RSM for beneficial use within the DOE complex. As part of that effort, Montana Tech has been awarded a contract to help optimize melting and refining technologies for the recycling of stainless steel RSM. The scope of the Montana Tech program includes a literature survey, a decontaminating slag design study, small scale melting studies to determine optimum slag compositions for removal of radioactive contaminant surrogates, analysis of preferred melting techniques, and coordination of pilot scale melting demonstrations (100-500 lbs) to be conducted at selected commercial facilities. This program will identify methods that can be used to recycle stainless steel RSM which will be used to fabricate high and low level waste canisters for the Idaho Waste Immobilization Facility. This report summarizes the results of an extensive literature review and the first year`s progress on slag design, small-scale melt refining of surrogate-containing stainless steel (presently only a three month effort), and pilot-scale preparation of surrogate master ingots.

  5. Decontamination of metals by melt refinings/slagging: An annotated bibliography

    SciTech Connect (OSTI)

    Mizia, R.E.; Worcester, S.A.; Twidwell, L.G.; Paolini, D.J.; Weldon, T.A.

    1993-07-01

    As the number of nuclear installations undergoing decontamination and decommissioning (D&D) increases, current radioactive waste storage space is consumed and establishment of new waste storage areas becomes increasingly difficult, the problem of handling and storing radioactive scrap metal (RSM) gains increasing importance in the DOE Environmental Restoration and Waste Management Program. To alleviate present and future waste storage problems, Westinghouse Idaho Nuclear Company (WINCO) is managing a program for the recycling of RSM for beneficial use within the DOE complex. As part of that effort, Montana Tech has been awarded a contract to help optimize melting and refining technology for the recycling of stainless steel RSM. The scope of the Montana Tech program includes a literature survey, a decontaminating slag design study, small scale melting studies to determine optimum slag compositions for removal of radioactive contaminant surrogates, analysis of preferred melting techniques, and coordination of large scale melting demonstrations (100--500 lbs) to be conducted at selected facilities. The program will support recycling and decontaminating stainless steel RSM for use in waste canisters for Idaho Waste Immobilization Facility densified high level waste. This report is the result of the literature search conducted to establish a basis for experimental melt/slag program development.

  6. Melting temperatures of the ZrO{sub 2}-MOX system

    SciTech Connect (OSTI)

    Uchida, T.; Hirooka, S.; Kato, M.; Morimoto, K.; Sugata, H.; Shibata, K.; Sato, D.

    2013-07-01

    Severe accidents occurred at the Fukushima Daiichi Nuclear Power Plant Units 1-3 on March 11, 2011. MOX fuels were loaded in the Unit 3. For the thermal analysis of the severe accident, melting temperature and phase state of MOX corium were investigated. The simulated coriums were prepared from 4%Pu-containing MOX, 8%Pu-containing MOX and ZrO{sub 2}. Then X-ray diffraction, density and melting temperature measurements were carried out as a function of zirconium and plutonium contents. The cubic phase was observed in the 25%Zr-containing corium and the tetragonal phase was observed in the 50% and 75%Zr-containing coria. The lattice parameter and density monotonically changed with Pu content. Melting temperature increased with increasing Pu content; melting temperature were estimated to be 2932 K for 4%Pu MOX corium and 3012 K for 8%Pu MOX corium in the 25%ZrO{sub 2}-MOX system. The lowest melting temperature was observed for 50%Zr-containing corium. (authors)

  7. Adams County, Wisconsin ASHRAE 169-2006 Climate Zone | Open Energy...

    Open Energy Info (EERE)

    Adams County, Wisconsin ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Adams County, Wisconsin ASHRAE Standard ASHRAE 169-2006 Climate Zone...

  8. Anderson County, Kansas ASHRAE 169-2006 Climate Zone | Open Energy...

    Open Energy Info (EERE)

    Anderson County, Kansas ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Anderson County, Kansas ASHRAE Standard ASHRAE 169-2006 Climate Zone...

  9. PLANETARY CHAOTIC ZONE CLEARING: DESTINATIONS AND TIMESCALES

    SciTech Connect (OSTI)

    Morrison, Sarah; Malhotra, Renu

    2015-01-20

    We investigate the orbital evolution of particles in a planet's chaotic zone to determine their final destinations and their timescales of clearing. There are four possible final states of chaotic particles: collision with the planet, collision with the star, escape, or bounded but non-collision orbits. In our investigations, within the framework of the planar circular restricted three body problem for planet-star mass ratio μ in the range 10{sup –9} to 10{sup –1.5}, we find no particles hitting the star. The relative frequencies of escape and collision with the planet are not scale-free, as they depend upon the size of the planet. For planet radius R{sub p} ≥ 0.001 R{sub H} where R{sub H} is the planet's Hill radius, we find that most chaotic zone particles collide with the planet for μ ≲ 10{sup –5}; particle scattering to large distances is significant only for higher mass planets. For fixed ratio R{sub p} /R{sub H} , the particle clearing timescale, T {sub cl}, has a broken power-law dependence on μ. A shallower power law, T {sub cl} ∼ μ{sup –1/3}, prevails at small μ where particles are cleared primarily by collisions with the planet; a steeper power law, T {sub cl} ∼ μ{sup –3/2}, prevails at larger μ where scattering dominates the particle loss. In the limit of vanishing planet radius, we find T {sub cl} ≈ 0.024 μ{sup –3/2}. The interior and exterior boundaries of the annular zone in which chaotic particles are cleared are increasingly asymmetric about the planet's orbit for larger planet masses; the inner boundary coincides well with the classical first order resonance overlap zone, Δa {sub cl,} {sub int} ≅ 1.2 μ{sup 0.28} a{sub p} ; the outer boundary is better described by Δa {sub cl,} {sub ext} ≅ 1.7 μ{sup 0.31} a{sub p} , where a{sub p} is the planet-star separation.

  10. The surface quasiliquid melt acceleration and the role of thermodynamic phase in the thermal decomposition of crystalline organic explosives

    SciTech Connect (OSTI)

    Henson, Bryan F

    2010-01-01

    We show that melt acceleration in the thermal decomposition of crystalline organic solids is a manifestation of the surface quasiliquid phase. We derive a single universal rate law for melt acceleration that is a simple function of the metastable liquid activity below the melting point, and has a zero order term proportional to the quasiliquid thickness. We argue that the underlying mechanisms of this model will provide a molecular definition for the stability of the class of secondary explosives.

  11. Systematic prediction of high-pressure melting curves of transition metals

    SciTech Connect (OSTI)

    Hieu, Ho Khac, E-mail: hieuhk@duytan.edu.vn [Institute of Research and Development, Duy Tan University, K7/25 Quang Trung, Danang (Viet Nam)

    2014-10-28

    The pressure effects on melting temperatures of transition metals have been studied based on the combination of the modified Lindemann criterion with statistical moment method in quantum statistical mechanics. Numerical calculations have been performed for five transition metals including Cu, Pd, Pt, Ni, and Mn up to pressure 100?GPa. Our results are in good and reasonable agreements with available experimental data. This approach gives us a relatively simple method for qualitatively calculating high-pressure melting temperature. Moreover, it can be used to verify future experimental and theoretical works. This research proposes the potential of the combination of statistical moment method and the modified Lindemann criterion on predicting high-pressure melting of materials.

  12. Chromium Phase Behavior in a Multi-Component Borosilicate Glass Melt

    SciTech Connect (OSTI)

    Hrma, Pavel R.; Vienna, John D.; Wilson, B. K.; Plaisted, Trevor J.; Heald, Steve M.

    2006-07-31

    This paper reports the phase behavior of a multicomponent borosilicate glass melt with 0?3 mass% Cr2O3 at 800?1500C in equilibrium with air. Both upper and lower liquidus temperatures were observed. When the temperature was between the upper and lower liquidus temperatures, eskolaite (Cr2O3) formed in melts with >2 mass% Cr2O3. Below the lower liquidus temperature, a dispersed chromate phase appeared in the melt that eventually became macroscopically segregated. The chemical durability of the glasses was virtually unaffected by chromium concentration. The particular glass studied was prototypic for the vitrification of high-Cr high-level radioactive wastes stored in underground tanks at the Hanford site. The results suggest a significant potential cost benefit for Hanford tank waste cleanup.

  13. Study on LiCl waste salt treatment process by layer melt crystallization

    SciTech Connect (OSTI)

    Cho, Yung-Zun; Lee, Tae-Kyo; Choi, Jung-Hoon; Eun, Hee-Chul; Park, Hwan-Seo; Kim, In-Tae; Park, Geun-Il

    2013-07-01

    Layer melt crystallization operated in a static mode has been applied to separate Group I and II chlorides from surrogate LiCl waste salt. The effects of operating conditions such as crystal growing rate(or flux) and initial impurity concentration on separation (or concentration) of cesium, strontium and barium involved in a LiCl melts were analyzed. In a layer crystallization process, separation was impaired by occlusion of impurities and by residual melt adhering to LiCl crystal after at the end of the process. The crystal growth rate strongly affects the crystal structure, therefore the separation efficiency, while the effect of the initial Cs and Sr concentration in LiCl molten salt was nearly negligible. (authors)

  14. Cold Crucible Induction Melting Technology for Vitrification of High Level Waste: Development and Status in India

    SciTech Connect (OSTI)

    Sugilal, G.; Sengar, P.B.S. [Nuclear Recycle Group, Bhabha Atomic Research Centre, Trombay, Mumbai (India)

    2008-07-01

    Cold crucible induction melting is globally emerging as an alternative technology for the vitrification of high level radioactive waste. The new technology offers several advantages such as high temperature availability with long melter life, high waste loading, high specific capacity etc. Based on the laboratory and bench scale studies, an engineering scale cold crucible induction melter was locally developed in India. The melter was operated continuously to assess its performance. The electrical and thermal efficiencies were found to be in the range of 70-80 % and 10-20 % respectively. Glass melting capacities up to 200 kg m{sup -2} hr{sup -1} were accomplished using the ESCCIM. Industrially adaptable melter operating procedures for start-up, melting and pouring operations were established (author)

  15. Measurement of diffusion potentials at porous diaphragms separating chloride and chloride-fluoride melts

    SciTech Connect (OSTI)

    Mitysev, V.S.; Komarov, V.E.

    1985-09-01

    An attempt was made in this work to measure the potential drops across diaphragms separating chloride and chloride-fluoride melts. These values can then be taken into account when analyzing the results of emf measurements made with the galvanic cell expressed here, and will help to make them more reliable, according to the authors. To check whether the activities of the alkali metal in alloys of the two half cells remained equal throughout the entire experiment, an experimental cell was used where alloy M-Bi was placed into a crucible of metallic molybdenum (d = 10 mm, h = 10 mm), which was immersed in turns into the chloride melt and into the chloride-fluoride melt while keeping the setup closed. The emf values increase with increasing temperature and alkali-metal fluoride concentration. They decrease with increasing cation radius in the salt medium.

  16. Influence of lithium-containing waste materials on the melting of packaging glass

    SciTech Connect (OSTI)

    Katkova, K.S.; Balandina, T.I.; Belyaeva, A.G.; Guloyan, Y.A.; Seregina, E.P.

    1986-07-01

    Lithium-containing waste materials from mica enrichment factories are studied. The possibilities of using the wastes for melting of green and semi-white sodium calcium silicate glasses are studied as well. Using physical methods, the authors study the influence of lithium-containing mica waste materials on the process of batch melting, silicate and glass formation, and clarification of molten glass. Tables show melting characteristics with various additions of lithium-containing mica waste, and the influence of added Li/sub 2/O on glass clarification. It is shown that the addition of lithium-containing mica waste materials to sodium calcium silicate glass has a positive effect on silicate and glass formation and on clarification.

  17. Melt-processing of Y-Ba-Cu-O superconductors for improved levitation

    SciTech Connect (OSTI)

    Balachandran, U.; Zhong, W.; Emerson, J.E.; McDaniel, R.L.

    1994-04-01

    Melt processed bulk YBa{sub 2}Cu{sub 3}O{sub 7{minus}{delta}} (YBCO) superconductors are of considerable interest in the application of low-friction, superconducting permanent magnet bearings and flywheel-energy-storage devices. The mechanisms of enhanced flux pinning in the melt processed samples has been the subject of many investigations. Fine precipitates of Y{sub 2}BaCuO{sub 5} (211) are considered potential flux-pinning sites by many investigators. Several groups have reported the refinement of 211 precipitates through Pt additions. In this paper, the authors describe the melt processing of YBCO with additives such as 211, Pt, and Ag. Large single domain regions are obtained using small SmBa2Cu3O{sub 7{minus}{delta}} (Sm-123) single crystal seeds. The microstructure and levitation forces are measured and reported here.

  18. Method for melting glass by measurement of non-bridging oxygen

    DOE Patents [OSTI]

    Jantzen, Carol M.

    1992-01-01

    A method for making better quality molten glass in a glass melter, the glass having the desired viscosity and, preferably, also the desired resistivity so that the glass melt can be established effectively and the product of the glass melter will have the desired level of quality. The method includes the adjustment of the composition of the glass constituents that are fed into the melter in accordance with certain correlations that reliably predict the viscosity and resistivity from the melter temperature and the melt composition, then heating the ingredients to the melter's operating temperature until they melt and homogenize. The equations include the calculation of a "non-bridging oxygen" term from the numbers of moles of the various ingredients, and then the determination of the viscosity and resistivity from the operating temperature of the melter and the non-bridging oxygen term.

  19. Glass Melt Emissivity, Viscosity, and Foaming Monitoring with Millimeter-Waves

    SciTech Connect (OSTI)

    Woskov, Paul P.; Sundaram, S.K.; Daniel, William E.; Hadidi, Kamal; Bromberg, Leslie; Miller, Don; Rogers, L.A.

    2003-09-10

    Nuclear waste glass processing efficiencies, improved melter control to anomalies such as foaming, and environmental compliance would be facilitated by the availability of on-line monitoring technologies. It has been shown that the millimeter-wave (MMW) range of the electromagnetic spectrum (0.3-10 mm) is ideally suited to hot melter environments by having wavelengths long enough to penetrate optically obscure views yet short enough to provide spatial resolution with reliable refractory quasi-optical components. A thermal return reflection (TRR) method has been developed that allows a millimeter-wave pyrometer to determine emissivity by returning a portion of the thermal emission as a probe. Melt glass viscosities in the range 20 -2000 Poise and specific gravities have been measured by rates of flow and displacements inside hollow MMW ceramic waveguides immersed into the melts. Glass foaming has been observed by detecting the melt surface swelling followed by the increase in surface emissivity after gases break the surface.

  20. Ceramic plasma-sprayed coating of melting crucibles for casting metal fuel slugs

    SciTech Connect (OSTI)

    K.H. Kim; C.T. Lee; C.B. Lee; R.S. Fielding; J.R. Kennedy

    2013-10-01

    Thermal cycling and melt reaction studies of ceramic coatings plasma-sprayed on Nb substrates were carried out to evaluate the performance of barrier coatings for metallic fuel casting applications. Thermal cycling tests of the ceramic plasma-sprayed coatings to 1450 degrees C showed that HfN, TiC, ZrC, and Y2O3 coating had good cycling characteristics with few interconnected cracks even after 20 cycles. Interaction studies by 1550 degrees C melt dipping tests of the plasma-sprayed coatings also indicated that HfN and Y2O3 do not form significant reaction layer between U20 wt.% Zr melt and the coating layer. Plasma-sprayed Y2O3 coating exhibited the most promising characteristics among HfN, TiC, ZrC, and Y2O3 coating.

  1. Method for melting glass by measurement of non-bridging oxygen

    DOE Patents [OSTI]

    Jantzen, C.M.

    1992-04-07

    A method is described for making better quality molten glass in a glass melter, the glass having the desired viscosity and, preferably, also the desired resistivity so that the glass melt can be established effectively and the product of the glass melter will have the desired level of quality. The method includes the adjustment of the composition of the glass constituents that are fed into the melter in accordance with certain correlations that reliably predict the viscosity and resistivity from the melter temperature and the melt composition, then heating the ingredients to the melter's operating temperature until they melt and homogenize. The equations include the calculation of a non-bridging oxygen' term from the numbers of moles of the various ingredients, and then the determination of the viscosity and resistivity from the operating temperature of the melter and the non-bridging oxygen term. 4 figs.

  2. Theory of melting at high pressures: Amending density functional theory with quantum Monte Carlo

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shulenburger, L.; Desjarlais, M. P.; Mattsson, T. R.

    2014-10-01

    We present an improved first-principles description of melting under pressure based on thermodynamic integration comparing Density Functional Theory (DFT) and quantum Monte Carlo (QMC) treatments of the system. The method is applied to address the longstanding discrepancy between density functional theory (DFT) calculations and diamond anvil cell (DAC) experiments on the melting curve of xenon, a noble gas solid where van der Waals binding is challenging for traditional DFT methods. The calculations show excellent agreement with data below 20 GPa and that the high-pressure melt curve is well described by a Lindemann behavior up to at least 80 GPa, amore » finding in stark contrast to DAC data.« less

  3. Shock compression behavior of bi-material powder composites with disparate melting temperatures

    SciTech Connect (OSTI)

    Sullivan, Kyle T.; Swift, Damian; Barham, Matthew; Stlken, James; Kuntz, Joshua; Kumar, Mukul

    2014-01-14

    Laser driven experiments were used to investigate the shock compression behavior of powder processed Bismuth/Tungsten (Bi/W) composite samples. The constituents provide different functionality to the composite behavior as Bi could be shock melted at the pressures attained in this work, while the W could not. Samples were prepared by uniaxial pressing, and the relative density was measured as a function of particle size, applied pressure, and composition for both hot and cold pressing conditions. This resulted in sample densities between 73% and 99% of the theoretical maximum density, and also noticeable differences in microstructure in the hot and cold pressed samples. The compression waves were generated with a 1.3 1.3?mm square spot directly onto the surface of the sample, using irradiances between 10{sup 12} and 10{sup 13}?W/cm{sup 2}, which resulted in calculated peak pressures between 50 and 150?GPa within a few micrometers. Sample recovery and post-mortem analysis revealed the formation of a crater on the laser drive surface, and the depth of this crater corresponded to the depth to which the Bi had been melted. The melt depth was found to be primarily a function of residual porosity and composition, and ranged from 167 to 528??m. In general, a higher porosity led to a larger melt depth. Direct numerical simulations were performed, and indicated that the observed increase in melt depth for low-porosity samples could be largely attributed to increased heating associated with work done for pore collapse. However, the relative scaling was sensitive to composition, with low volume fraction Bi samples exhibiting a much stronger dependence on porosity than high Bi content samples. Select samples were repeated using an Al foil ablator, but there were no noticeable differences ensuring that the observed melting was indeed pressure-driven and was not a result of direct laser heating. The resultant microstructures and damage near the spall surface were also

  4. NaturAnalogs for the Unsaturated Zone

    SciTech Connect (OSTI)

    A. Simmons; A. Unger; M. Murrell

    2000-03-08

    The purpose of this Analysis/Model Report (AMR) is to document natural and anthropogenic (human-induced) analog sites and processes that are applicable to flow and transport processes expected to occur at the potential Yucca Mountain repository in order to build increased confidence in modeling processes of Unsaturated Zone (UZ) flow and transport. This AMR was prepared in accordance with ''AMR Development Plan for U0135, Natural Analogs for the UZ'' (CRWMS 1999a). Knowledge from analog sites and processes is used as corroborating information to test and build confidence in flow and transport models of Yucca Mountain, Nevada. This AMR supports the Unsaturated Zone (UZ) Flow and Transport Process Model Report (PMR) and the Yucca Mountain Site Description. The objectives of this AMR are to test and build confidence in the representation of UZ processes in numerical models utilized in the UZ Flow and Transport Model. This is accomplished by: (1) applying data from Boxy Canyon, Idaho in simulations of UZ flow using the same methodologies incorporated in the Yucca Mountain UZ Flow and Transport Model to assess the fracture-matrix interaction conceptual model; (2) Providing a preliminary basis for analysis of radionuclide transport at Pena Blanca, Mexico as an analog of radionuclide transport at Yucca Mountain; and (3) Synthesizing existing information from natural analog studies to provide corroborating evidence for representation of ambient and thermally coupled UZ flow and transport processes in the UZ Model.

  5. A new method for separating first row transition metals and actinides from synthetic melt glass

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Roman, Audrey Rae; Bond, Evelyn M.

    2016-01-14

    A new method was developed for separating Co, Fe, and Sc from complex debris matrices using the extraction chromatography resin DGA. The activation products Co-58, Mn-54, and Sc-46 were used to characterize the separation of the synthetic melt glass solutions. In the separation scheme that was developed, Au, Co, Cu, Fe, Sc, and Ti were separated from the rest of the sample constituents. In this paper, the synthetic melt glass separation method, efficiency, recoveries, and the length of procedure will be discussed. In conclusion, batch contact adsorption studies for Na and Sc for DGA resin are discussed as well.

  6. Method for producing melt-infiltrated ceramic composites using formed supports

    DOE Patents [OSTI]

    Corman, Gregory Scot (Ballston Lake, NY); Brun, Milivoj Konstantin (Ballston Lake, NY); McGuigan, Henry Charles (Duanesburg, NY)

    2003-01-01

    A method for producing shaped articles of ceramic composites provides a high degree of dimensional tolerance to these articles. A fiber preform is disposed on a surface of a stable formed support, a surface of which is formed with a plurality of indentations, such as grooves, slots, or channels. Precursors of ceramic matrix materials are provided to the fiber preform to infiltrate from both sides of the fiber preform. The infiltration is conducted under vacuum at a temperature not much greater than a melting point of the precursors. The melt-infiltrated composite article substantially retains its dimension and shape throughout the fabrication process.

  7. Temperature and melting of laser-shocked iron releasing into an LiF window

    SciTech Connect (OSTI)

    Huser, G.; Koenig, M.; Benuzzi-Mounaix, A.; Henry, E.; Vinci, T.; Faral, B.; Tomasini, M.; Telaro, B.; Batani, D.

    2005-06-15

    Absolute reflectivity and self-emission diagnostics are used to determine the gray-body equivalent temperature of laser-shocked iron partially releasing into a lithium fluoride window. Pressure and reflectivity are measured simultaneously by means of velocity interferometer system for any reflector interferometers. In the temperature-pressure plane, a temperature plateau in the release is observed which is attributed to iron's melting line. Extrapolation of data leads to a melting temperature at Earth's inner-outer core boundary of 7800{+-}1200 K, in good agreement with previous works based on dynamic compression. Shock temperatures were calculated and found to be in the liquid phase.

  8. SUMMARY OF 2010 DOE EM INTERNATIONAL PROGRAM STUDIES OF WASTE GLASS MELT RATE ENHANCEMENT

    SciTech Connect (OSTI)

    Fox, K.; Marra, J.

    2011-01-19

    A collaborative study has been established under the U.S. Department of Energy (DOE) Office of Environmental Management International Program between the Savannah River National Laboratory (SRNL) and the V. G. Khlopin Radium Institute (KRI) in St. Petersburg, Russia, to investigate potential improvements in melt rate via chemical additions to the glass frit. Researchers at KRI suggested a methodology for selecting frit additives based on empirical coefficients for optimization of glass melting available in the Russian literature. Using these coefficients, KRI identified B{sub 2}O{sub 3}, CuO, and MnO as frit additives that were likely to improve melt rate without having adverse effects on crystallization of the glass or its chemical durability. The results of the melt rate testing in the SMK melter showed that the slurry feed rate (used as a gauge of melt rate) could be significantly increased when MnO or CuO were added to Frit 550 with the SMR-2 sludge. The feed rates increased by about 27% when MnO was added to the frit and by about 26% when CuO was added to the frit, as compared to earlier results for Frit 550 alone. The impact of adding additional B{sub 2}O{sub 3} to the frit was minor when added with CuO. The additional B{sub 2}O{sub 3} showed a more significant, 39% improvement in melt rate when added with MnO. The additional B{sub 2}O{sub 3} also reduced the viscosity of the glasses during pouring. Samples of the glasses from the melt rate testing characterized at SRNL showed that there were no significant impacts on crystallization of the glasses. All of the glasses had very good chemical durability. Chemical composition measurements showed that the frit additives were present in concentrations below the targeted values in some of the glasses. Therefore, it is possible that higher concentrations of these additives may further improve melt rate, although the impacts of higher concentrations of these components on crystallization and durability would need to

  9. Primary arm spacing in chill block melt spun Ni-Mo alloys

    SciTech Connect (OSTI)

    Tewari, S.N.; Glasgow, T.K.

    1986-01-01

    Chill block melt spun ribbons of Ni-Mo binary alloys containing 8.0 to 41.8 wt % Mo have been prepared under carefully controlled processing conditions. The growth velocity has been determined as a function of distance from the quench surface from the observed ribbon thickness dependence on the melt puddle residence time. Primary arm spacings measured at the midribbon thickness locations show a dependence on growth velocity and alloy composition which is expected from dendritic growth models for binary alloys directionally solidified in a positive temperature gradient.

  10. Double patterning HSQ processes of zone plates for 10 nm diffraction...

    Office of Scientific and Technical Information (OSTI)

    ... Using the new process, we successfully realized zone plates of 10 nm and 12 nm outermost zones. Fig. 3 shows the SEM micrographs of the zone plates outer regions. The zone plates ...

  11. Anderson County, Texas ASHRAE 169-2006 Climate Zone | Open Energy...

    Open Energy Info (EERE)

    ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Anderson County, Texas ASHRAE Standard ASHRAE 169-2006 Climate Zone Number Climate Zone Number...

  12. ESTIMATING FATE AND TRANSPORT OF MULTIPLE CONTAMINANTS IN THE VADOSE ZONE USING A MULTI-LAYERED SOIL COLUMN AND THREE-PHASE EQUILIBRIUM PARTITIONING MODEL

    SciTech Connect (OSTI)

    Rucker, G

    2007-05-01

    Soils at waste sites must be evaluated for the potential of residual soil contamination to leach and migrate to the groundwater beneath the disposal area. If migration to the aquifer occurs, contaminants can travel vast distances and contaminate drinking water wells, thus exposing human receptors to harmful levels of toxins and carcinogens. To prevent groundwater contamination, a contaminant fate and transport analysis is necessary to assess the migration potential of residual soil contaminates. This type of migration analysis is usually performed using a vadose zone model to account for complex geotechnical and chemical variables including: contaminant decay, infiltration rate, soil properties, vadose zone thickness, and chemical behavior. The distinct advantage of using a complex model is that less restrictive, but still protective, soil threshold levels may be determined avoiding the unnecessary and costly remediation of marginally contaminated soils. However, the disadvantage of such modeling is the additional cost for data collection and labor required to apply these models. In order to allay these higher costs and to achieve a less restrictive but still protective clean-up level, a multiple contaminant and multi layered soil column equilibrium partitioning model was developed which is faster, simpler and less expensive to use.

  13. Estimating fate and transport of multiple contaminants in the vadose zone using a multi-layered soil column and three-phase equilibrium partitioning model

    SciTech Connect (OSTI)

    Rucker, Gregory G.

    2007-07-01

    Soils at waste sites must be evaluated for the potential of residual soil contamination to leach and migrate to the groundwater beneath the disposal area. If migration to the aquifer occurs, contaminants can travel vast distances and pollute drinking water wells, thus exposing human receptors to harmful levels of toxins and carcinogens. To prevent groundwater contamination, a contaminant fate and transport analysis is necessary to assess the migration potential of residual soil contaminants. This type of migration analysis is usually performed using a vadose zone model to account for complex geotechnical and chemical variables including: decay processes, infiltration rate, soil properties, vadose zone thickness, and chemical behavior. The distinct advantage of using a complex model is that less restrictive, but still protective, soil threshold levels may be determined avoiding the unnecessary and costly remediation of marginally contaminated soils. However, the disadvantage of such modeling is the additional cost for data collection and labor required to apply these models. In order to allay these higher costs and to achieve a less restrictive but still protective clean-up level, a multiple contaminant and multi layered soil column equilibrium partitioning model was developed which is faster, simpler and less expensive to use. (authors)

  14. T Tank Farm Interim Surface Barrier Demonstration - Vadose Zone Monitoring FY09 Report

    SciTech Connect (OSTI)

    Zhang, Z. F.; Strickland, Christopher E.; Field, Jim G.; Parker, Danny L.

    2010-01-01

    DOEs Office of River Protection constructed a temporary surface barrier over a portion of the T Tank Farm as part of the T Farm Interim Surface Barrier Demonstration Project. As part of the demonstration effort, vadose zone moisture is being monitored to assess the effectiveness of the barrier at reducing soil moisture. A solar-powered system was installed to continuously monitor soil water conditions at four locations (i.e., instrument Nests A, B, C, and D) beneath the barrier and outside the barrier footprint as well as site meteorological conditions. Nest A is placed in the area outside the barrier footprint and serves as a control, providing subsurface conditions outside the influence of the surface barrier. Nest B provides subsurface measurements to assess surface-barrier edge effects. Nests C and D are used to assess changes in soil-moisture conditions beneath the interim surface barrier. Each instrument nest is composed of a capacitance probe (CP) with multiple sensors, multiple heat-dissipation units (HDUs), and a neutron probe (NP) access tube. The monitoring results in FY09 are summarized below. The solar panels functioned normally and could provide sufficient power to the instruments. The CP in Nest C after September 20, 2009, was not functional. The CP sensors in Nest B after July 13 and the 0.9-m CP sensor in Nest D before June 10 gave noisy data. Other CPs were functional normally. All the HDUs were functional normally but some pressure-head values measured by HDUs were greater than the upper measurement-limit. The higher-than-upper-limit values might be due to the very wet soil condition and/or measurement error but do not imply the malfunction of the sensors. Similar to FY07 and FY08, in FY09, the soil under natural conditions (Nest A) was generally recharged during the winter period (October-March) and discharged during the summer period (April-September). Soil water conditions above about 1.5-m to 2-m depth from all three types of measurements (i

  15. SITE-SCALE SATURATED ZONE TRANSPORT

    SciTech Connect (OSTI)

    S. KELLER

    2004-11-03

    This work provides a site-scale transport model for calculating radionuclide transport in the saturated zone (SZ) at Yucca Mountain, for use in the abstractions model in support of ''Total System Performance Assessment for License Application'' (TSPA-LA). The purpose of this model report is to provide documentation for the components of the site-scale SZ transport model in accordance with administrative procedure AP-SIII.10Q, Models. The initial documentation of this model report was conducted under the ''Technical Work Plan For: Saturated Zone Flow and Transport Modeling and Testing'' (BSC 2003 [DIRS 163965]). The model report has been revised in accordance with the ''Technical Work Plan For: Natural System--Saturated Zone Analysis and Model Report Integration'', Section 2.1.1.4 (BSC 2004 [DIRS 171421]) to incorporate Regulatory Integration Team comments. All activities listed in the technical work plan that are appropriate to the transport model are documented in this report and are described in Section 2.1.1.4 (BSC 2004 [DIRS 171421]). This report documents: (1) the advection-dispersion transport model including matrix diffusion (Sections 6.3 and 6.4); (2) a description and validation of the transport model (Sections 6.3 and 7); (3) the numerical methods for simulating radionuclide transport (Section 6.4); (4) the parameters (sorption coefficient, Kd ) and their uncertainty distributions used for modeling radionuclide sorption (Appendices A and C); (5) the parameters used for modeling colloid-facilitated radionuclide transport (Table 4-1, Section 6.4.2.6, and Appendix B); and (6) alternative conceptual models and their dispositions (Section 6.6). The intended use of this model is to simulate transport in saturated fractured porous rock (double porosity) and alluvium. The particle-tracking method of simulating radionuclide transport is incorporated in the finite-volume heat and mass transfer numerical analysis (FEHM) computer code, (FEHM V2.20, STN: 10086

  16. Near-field/altered-zone models report

    SciTech Connect (OSTI)

    Hardin, E. L., LLNL

    1998-03-01

    The U.S. Department of Energy is studying Yucca Mountain as the possible site for the first underground repository for permanent disposal of spent fuel from commercial nuclear reactors as well as for other types high-level nuclear waste. Emplacement of high-level radioactive waste, especially commercial spent nuclear fuel (CSNF), in Yucca Mountain will release a large amount of heat into the rock above and below the repository. The heating rate will decrease with time, creating a thermal pulse. Over a period of several thousand years, the rock temperature will rise initially, then drop when the production of decay heat falls below the rate at which heat escapes from the hot zone. Besides raising the rock temperature, much of this heat will vaporize water, which will then condense in cooler regions. The condensate is likely to form a gravity-driven heat pipe above the repository, creating the possibility that water may drain back onto the waste packages (WPs) or that it may ''shed'' through the pillars between emplacement drifts. The long-term importance of these effects has been investigated through the development, testing, and application of thermohydrologic (TH) models. Other effects, such coupled chemical and mechanical processes, may also influence the movement of water above, within, and below the emplacement drifts. A recent report on thermally driven coupled processes (Hardin and Chesnut, 1997) provides a qualitative assessment of the probable significance of these processes for the Yucca Mountain Site Characterization Project (YMSCP) and is the phenomenological framework for the present report. This report describes the conceptual and numerical models that have been developed to predict the thermal, mechanical, hydrologic, and chemical responses to the cumulative heat production of the potential host rock at Yucca Mountain. As proposed, the repository horizon will be situated within the Topopah Spring tuff, in the adjacent middle nonlithophysal and lower

  17. Numerical simulation of viscoelastic layer rearrangement in polymer melts using OpenFOAM®

    SciTech Connect (OSTI)

    Köpplmayr, Thomas Mayrhofer, Elias

    2015-05-22

    In addition to their shear-thinning behavior, polymer melts are characterized by first and second normal stress differences, which cause secondary motions. Polymer coextrusion processes involve viscoelastic two-phase flows that influence layer formation. Using polymer melts with different pigmentation makes visible the layers deformed by second normal stress differences. We used a new solver for the OpenFOAM CFD toolbox which handles viscoelastic two-phase flows. A derivative of the volume-of-fluid (VoF) methodology was employed to describe the interface. Different types of polymer melt, such as polyethylene (PE), polypropylene (PP) and polyethylene terephthalate (PET) were investigated. In a coextrusion process, the less viscous phase usually tends to encapsulate the more viscous one. However, the different viscoelastic properties of the melts also influence interface deformation. The materials were characterized by small-amplitude oscillatory-shear rheometry, and a multimode Giesekus model was used to fit shear viscosity, storage and loss modulus. Our simulations also took interfacial tension into account. Experimental observations and corresponding numerical simulations were found to be in good accordance.

  18. Arc-melting preparation of single crystal LaB.sub.6 cathodes

    DOE Patents [OSTI]

    Gibson, Edwin D.; Verhoeven, John D.

    1977-06-21

    A method for preparing single crystals of lanthanum hexaboride (LaB.sub.6) by arc melting a rod of compacted LaB.sub.6 powder. The method is especially suitable for preparing single crystal LaB.sub.6 cathodes for use in scanning electron microscopes (SEM) and scanning transmission electron microscopes (STEM).

  19. Laboratory-Scale Melter for Determination of Melting Rate of Waste Glass Feeds

    SciTech Connect (OSTI)

    Kim, Dong-Sang; Schweiger, Michael J.; Buchmiller, William C.; Matyas, Josef

    2012-01-09

    The purpose of this study was to develop the laboratory-scale melter (LSM) as a quick and inexpensive method to determine the processing rate of various waste glass slurry feeds. The LSM uses a 3 or 4 in. diameter-fused quartz crucible with feed and off-gas ports on top. This LSM setup allows cold-cap formation above the molten glass to be directly monitored to obtain a steady-state melting rate of the waste glass feeds. The melting rate data from extensive scaled-melter tests with Hanford Site high-level wastes performed for the Hanford Tank Waste Treatment and Immobilization Plant have been compiled. Preliminary empirical model that expresses the melting rate as a function of bubbling rate and glass yield were developed from the compiled database. The two waste glass feeds with most melter run data were selected for detailed evaluation and model development and for the LSM tests so the melting rates obtained from LSM tests can be compared with those from scaled-melter tests. The present LSM results suggest the LSM setup can be used to determine the glass production rates for the development of new glass compositions or feed makeups that are designed to increase the processing rate of the slurry feeds.

  20. Melting process of nanometer-sized in particles embedded in an Al matrix synthesized by ball milling

    SciTech Connect (OSTI)

    Sheng, H.W.; Xu, J.; Yu, L.G.; Sun, X.K.; Hu, Z.Q.; Lu, K.

    1996-11-01

    Dispersions of nanometer-sized In particles embedded in an Al matrix (10 wt.{percent} In) have been synthesized by ball milling of a mixture of Al and In powders. The as-milled product was characterized by using x-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive x-ray spectrometer (EDX), transmission electron microscopy (TEM), and high resolution transmission electron microscopy (HREM), respectively. It was found that In and Al are pure components immiscible with each other, with nanometer-sized In particles dispersively embedded in the Al matrix. The melting behavior of In particles was investigated by means of differential scanning calorimeter (DSC). The calorimetric measurements indicate that both the melting point and the melting enthalpy of the In nanoparticles decrease with increasing milling time, or refinement of the In particles. Compared to its bulk melting temperature, a melting point depression of 13.4 K was observed when the mean grain size of In is 15 nm, and the melting point depression of In nanoparticles is proportional to the reciprocal of the mean grain size. The melting enthalpy depression was interpreted according to the two-state concept for the nanoparticles. Melting of the interface was deduced to be an exothermal process due to its large excess energy/volume. {copyright} {ital 1996 Materials Research Society.}

  1. Central Plateau Groundwater and Deep Vadose Zone Strategy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vadose Zone Executive Council Hanford Advisory Board River and Plateau Committee Briant L. Charboneau DOE-RL, Soil and Groundwater Federal Project Director October 9, 2012 1 Discussion Topics * Purpose of the Executive Council - Why was this established? * Who participates? * What are the integration topics of interest to the Council? * Examples of groundwater and vadose zone integration - Deep Vadose Zone treatability testing leading to evaluation of measures to protect groundwater - B complex

  2. IMPACT OF SMALL COLUMN ION EXCHANGE STREAMS ON DWPF GLASS FORMULATION MELT RATE STUDIES

    SciTech Connect (OSTI)

    Fox, K.; Miller, D.; Koopman, D.

    2011-04-26

    This study was undertaken to evaluate the potential impacts of the Small Column Ion Exchange (SCIX) streams - particularly the addition of Monosodium Titanate (MST) and Crystalline Silicotitanate (CST) - on the melt rate of simulated feed for the Defense Waste Processing Facility (DWPF). Additional MST was added to account for contributions from the Salt Waste Processing Facility (SWPF). The Savannah River National Laboratory (SRNL) Melt Rate Furnace (MRF) was used to evaluate four melter feed compositions: two with simulated SCIX and SWPF material and two without. The Slurry-fed Melt Rate Furnace (SMRF) was then used to compare two different feeds: one with and one without bounding concentrations of simulated SCIX and SWPF material. Analyses of the melter feed materials confirmed that they met their targeted compositions. Four feeds were tested in triplicate in the MRF. The linear melt rates were determined by using X-ray computed tomography to measure the height of the glass formed along the bottom of the beakers. The addition of the SCIX and SWPF material reduced the average measured melt rate by about 10% in MRF testing, although there was significant scatter in the data. Two feeds were tested in the SMRF. It was noted that the ground CST alone (ground CST with liquid in a bucket) was extremely difficult to resuspend during preparation of the feed with material from SCIX and SWPF. This feed was also more difficult to pump than the material without MST and CST due to settling occurring in the melter feed line, although the yield stress of both feeds was high relative to the DWPF design basis. Steady state feeding conditions were maintained for about five hours for each feed. There was a reduction in the feed and pour rates of approximately 15% when CST and MST were added to the feed, although there was significant scatter in the data. Analysis of samples collected from the SMRF pour stream showed that the composition of the glass changed as expected when MST and

  3. Geodetic Survey At Central Nevada Seismic Zone Region (Laney...

    Open Energy Info (EERE)

    Laney, 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geodetic Survey At Central Nevada Seismic Zone Region (Laney, 2005) Exploration...

  4. Geodetic Survey At Walker-Lane Transitional Zone Region (Laney...

    Open Energy Info (EERE)

    Laney, 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geodetic Survey At Walker-Lane Transitional Zone Region (Laney, 2005) Exploration...

  5. Tectonic analysis of the Rio Grande Rift Zone, central Colorado...

    Open Energy Info (EERE)

    Rift Zone, central ColoradoThesisDissertation Abstract Abstract unavailable. Author D.H. Knepper Organization Colorado School of Mines Published Publisher Not Provided, 1974...

  6. Modeling-Computer Simulations At Walker-Lane Transitional Zone...

    Open Energy Info (EERE)

    navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Modeling-Computer Simulations At Walker-Lane Transitional Zone Region (Laney, 2005) Exploration...

  7. Modeling-Computer Simulations At Walker-Lane Transitional Zone...

    Open Energy Info (EERE)

    navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Modeling-Computer Simulations At Walker-Lane Transitional Zone Region (Pritchett, 2004) Exploration...

  8. Modeling-Computer Simulations At Central Nevada Seismic Zone...

    Open Energy Info (EERE)

    navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Modeling-Computer Simulations At Central Nevada Seismic Zone Region (Biasi, Et Al., 2009) Exploration...

  9. Modeling-Computer Simulations At Walker-Lane Transitional Zone...

    Open Energy Info (EERE)

    navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Modeling-Computer Simulations At Walker-Lane Transitional Zone Region (Biasi, Et Al., 2009) Exploration...

  10. East Tennessee Technology Park Zones 1 and 2

    Broader source: Energy.gov [DOE]

    This document explains the cleanup activities and any use limitations for the land surrounding the East Tennessee Technology Park’s Zones 1 and 2.

  11. Baltimore County, Maryland ASHRAE 169-2006 Climate Zone | Open...

    Open Energy Info (EERE)

    Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit History Baltimore County, Maryland ASHRAE 169-2006 Climate Zone Jump to: navigation, search County...

  12. Baltimore City County, Maryland ASHRAE 169-2006 Climate Zone...

    Open Energy Info (EERE)

    Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit History Baltimore City County, Maryland ASHRAE 169-2006 Climate Zone Jump to: navigation, search...

  13. Field Mapping At Central Nevada Seismic Zone Region (Blewitt...

    Open Energy Info (EERE)

    to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Field Mapping At Central Nevada Seismic Zone Region (Blewitt Et Al, 2005) Exploration Activity...

  14. Walker-Lane Transition Zone Geothermal Region | Open Energy Informatio...

    Open Energy Info (EERE)

    Geothermal Area Wilson Hot Spring Geothermal Area Winnemucca Dry Lake Geothermal Area Energy Generation Facilities within the Walker-Lane Transition Zone Geothermal Region...

  15. Eastern Energy Zones Mapping Tool | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    The Eastern Interconnection States' Planning Council (EISPC) has released the Energy Zones (EZ) Mapping Tool, a free, web-based interactive tool that will help states and other ...

  16. Zone heated inlet ignited diesel particulate filter regeneration...

    Office of Scientific and Technical Information (OSTI)

    Data Explorer Search Results Zone heated inlet ignited diesel particulate filter ... An exhaust system that processes exhaust generated by an engine is provided. The system ...

  17. Data Acquisition-Manipulation At Walker-Lane Transitional Zone...

    Open Energy Info (EERE)

    (Coolbaugh, Et Al., 2005 - 2) Exploration Activity Details Location Walker-Lane Transition Zone Geothermal Region Exploration Technique Data Acquisition-Manipulation Activity...

  18. Field Mapping At Walker-Lane Transitional Zone Region (Shevenell...

    Open Energy Info (EERE)

    Region (Shevenell, Et Al., 2008) Exploration Activity Details Location Walker-Lane Transition Zone Geothermal Region Exploration Technique Field Mapping Activity Date Usefulness...

  19. Geothermometry At Walker-Lane Transitional Zone Region (Shevenell...

    Open Energy Info (EERE)

    (Shevenell & De Rocher, 2005) Exploration Activity Details Location Walker-Lane Transition Zone Geothermal Region Exploration Technique Geothermometry Activity Date Usefulness...

  20. Refraction Survey At Walker-Lane Transitional Zone Region (Heimgartner...

    Open Energy Info (EERE)

    Region (Heimgartner, Et Al., 2005) Exploration Activity Details Location Walker-Lane Transition Zone Geothermal Region Exploration Technique Refraction Survey Activity Date...

  1. High pressure floating zone growth and structural properties...

    Office of Scientific and Technical Information (OSTI)

    quantum paraelectric BaFe12O19 Citation Details In-Document Search Title: High pressure floating zone growth and structural properties of ferrimagnetic quantum ...

  2. Production from multiple zones of a tar sands formation

    DOE Patents [OSTI]

    Karanikas, John Michael; Vinegar, Harold J

    2013-02-26

    A method for treating a tar sands formation includes providing heat to at least part of a hydrocarbon layer in the formation from a plurality of heaters located in the formation. The heat is allowed to transfer from the heaters to at least a portion of the formation. Fluids are produced from the formation through at least one production well that is located in at least two zones in the formation. The first zone has an initial permeability of at least 1 darcy. The second zone has an initial of at most 0.1 darcy. The two zones are separated by a substantially impermeable barrier.

  3. Geodetic Survey At Central Nevada Seismic Zone Region (Blewitt...

    Open Energy Info (EERE)

    Geodetic Survey At Central Nevada Seismic Zone Region (Blewitt Et Al, 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geodetic Survey At...

  4. Geothermometry At Central Nevada Seismic Zone Region (Shevenell...

    Open Energy Info (EERE)

    Geothermometry At Central Nevada Seismic Zone Region (Shevenell & De Rocher, 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry...

  5. Teleseismic-Seismic Monitoring At Central Nevada Seismic Zone...

    Open Energy Info (EERE)

    Teleseismic-Seismic Monitoring At Central Nevada Seismic Zone Region (Biasi, Et Al., 2008) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity:...

  6. Washington Coastal Zone Management Webpage | Open Energy Information

    Open Energy Info (EERE)

    Webpage Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Washington Coastal Zone Management Webpage Abstract Provides overview of Washington's coastal...

  7. Water Sampling At Central Nevada Seismic Zone Region (Laney,...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water Sampling At Central Nevada Seismic Zone Region (Laney, 2005) Exploration Activity...

  8. Water Sampling At Walker-Lane Transitional Zone Region (Laney...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water Sampling At Walker-Lane Transitional Zone Region (Laney, 2005) Exploration Activity...

  9. EPA Coastal Zone Act Reauthorization Amendments (CZARA) Section...

    Open Energy Info (EERE)

    Section 6217 Webpage Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: EPA Coastal Zone Act Reauthorization Amendments (CZARA) Section 6217 Webpage...

  10. Geothermal Literature Review At Walker-Lane Transitional Zone...

    Open Energy Info (EERE)

    navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermal Literature Review At Walker-Lane Transitional Zone Region (Laney, 2005) Exploration Activity...

  11. AltaRock Energy Announces Successful Multiple-Zone Stimulation...

    Energy Savers [EERE]

    Geothermal Systems Demonstration AltaRock Energy Announces Successful Multiple-Zone Stimulation of Well at the Newberry Enhanced Geothermal Systems Demonstration January 22, 2013 - ...

  12. Data Acquisition-Manipulation At Central Nevada Seismic Zone...

    Open Energy Info (EERE)

    - 2) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Data Acquisition-Manipulation At Central Nevada Seismic Zone Region (Coolbaugh, Et Al., 2005...

  13. Baoding High Tech Industry Development Zone | Open Energy Information

    Open Energy Info (EERE)

    Name: Baoding High-Tech Industry Development Zone Place: China Product: Government & NGO ( State-owned commercial entity ) References: Baoding High-Tech Industry Development...

  14. Gradient zone boundary control in salt gradient solar ponds

    DOE Patents [OSTI]

    Hull, John R.

    1984-01-01

    A method and apparatus for suppressing zone boundary migration in a salt gradient solar pond includes extending perforated membranes across the pond at the boundaries, between the convective and non-convective zones, the perforations being small enough in size to prevent individual turbulence disturbances from penetrating the hole, but being large enough to allow easy molecular diffusion of salt thereby preventing the formation of convective zones in the gradient layer. The total area of the perforations is a sizable fraction of the membrane area to allow sufficient salt diffusion while preventing turbulent entrainment into the gradient zone.

  15. Variation in sericite composition from fracture zones within...

    Open Energy Info (EERE)

    found in drillhole samples within the geothermal system at Coso Hot Springs. Low-permeability zones of the crystalline basement contain coarse-grained relict muscovite, whereas...

  16. Compound and Elemental Analysis At Central Nevada Seismic Zone...

    Open Energy Info (EERE)

    Nevada Seismic Zone Geothermal Region Exploration Technique Compound and Elemental Analysis Activity Date Usefulness not indicated DOE-funding Unknown Notes Geochemical...

  17. Isotopic Analysis At Central Nevada Seismic Zone Region (Laney...

    Open Energy Info (EERE)

    Location Central Nevada Seismic Zone Geothermal Region Exploration Technique Isotopic Analysis- Fluid Activity Date Usefulness not indicated DOE-funding Unknown Notes...

  18. Community Wind Handbook/Understand Permitting & Zoning | Open...

    Open Energy Info (EERE)

    Permitting & Zoning < Community Wind Handbook Jump to: navigation, search WIND ENERGY STAKEHOLDER ENGAGEMENT & OUTREACHCommunity Wind Handbook WindTurbine-icon.png...

  19. NELHA Creates the 'Green Energy Zone.' | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    NELHA Creates the 'Green Energy Zone' (5.54 MB) More Documents & Publications EA-1336: Final Environmental Assessment Ocean Thermal Extractable Energy Visualization: Final ...

  20. Plasma Sprayed Pour Tubes and Other Melt Handling Components for Use in Gas Atomization

    SciTech Connect (OSTI)

    Byrd, David; Rieken, Joel; Heidloff, Andy; Besser, Matthew; Anderson, Iver

    2011-04-01

    Ames Laboratory has successfully used plasma sprayed ceramic components made from yttria stabilized zirconia as melt pouring tubes for gas atomization for many years. These tubes have proven to be strong, thermal shock resistant and versatile. Various configurations are possible both internally and externally. Accurate dimensions are achieved internally with a machined fugitive graphite mandrel and externally by diamond grinding. The previous study of the effect of spray parameters on density was extended to determine the effect of the resulting density on the thermal shock characteristics on down-quenching and up-quenching. Encouraging results also prompted investigation of the use of plasma spraying as a method to construct a melt pour exit stopper that is mechanically robust, thermal shock resistant, and not susceptible to attack by reactive melt additions. The Ames Laboratory operates two close-coupled high pressure gas atomizers. These two atomizers are designed to produce fine and coarse spherical metal powders (5{mu} to 500{mu} diameter) of many different metals and alloys. The systems vary in size, but generally the smaller atomizer can produce up to 5 kg of powder whereas the larger can produce up to 25 kg depending on the charge form and density. In order to make powders of such varying compositions, it is necessary to have melt systems capable of heating and containing the liquid charge to the desired superheat temperature prior to pouring through the atomization nozzle. For some metals and alloys this is not a problem; however for some more reactive and/or high melting materials this can pose unique challenges. Figure 1 is a schematic that illustrates the atomization system and its components.

  1. Treatment of Asbestos Wastes Using the GeoMelt Vitrification Process

    SciTech Connect (OSTI)

    Finucane, K.G. [AMEC Nuclear Holdings Ltd., GeoMelt Div., Richland, WA (United States); Thompson, L.E. [Capto Group LLC, Dallas, TX (United States); Abuku, T. [ISV Japan Ltd., Yokohama-city (Japan); Nakauchi, H. [Mie Chuo Kaihatsu Co. Ltd., Hachiya, Iga City (Japan)

    2008-07-01

    The disposal of waste asbestos from decommissioning activities is becoming problematic in countries which have limited disposal space. A particular challenge is the disposal of asbestos wastes from the decommissioning of nuclear sites because some of it is radioactively contaminated or activated and disposal space for such wastes is limited. GeoMelt{sup R} vitrification is being developed as a treatment method for volume and toxicity minimization and radionuclide immobilization for UK radioactive asbestos mixed waste. The common practice to date for asbestos wastes is disposal in licensed landfills. In some cases, compaction techniques are used to minimize the disposal space requirements. However, such practices are becoming less practical. Social pressures have resulted in changes to disposal regulations which, in turn, have resulted in the closure of some landfills and increased disposal costs. In the UK, tens of thousands of tonnes of asbestos waste will result from the decommissioning of nuclear sites over the next 20 years. In Japan, it is estimated that over 40 million tonnes of asbestos materials used in construction will require disposal. Methods for the safe and cost effective volume reduction of asbestos wastes are being evaluated for many sites. The GeoMelt{sup R} vitrification process is being demonstrated at full-scale in Japan for the Japan Ministry of Environment and plans are being developed for the GeoMelt treatment of UK nuclear site decommissioning-related asbestos wastes. The full-scale treatment operations in Japan have also included contaminated soils and debris. The GeoMelt{sup R} vitrification process result in the maximum possible volume reduction, destroys the asbestos fibers, treats problematic debris associated with asbestos wastes, and immobilizes radiological contaminants within the resulting glass matrix. Results from recent full-scale treatment operations in Japan are discussed and plans for GeoMelt treatment of UK nuclear site

  2. Chemical speciation of U, Fe, and Pu in melt glass from nuclear weapons testing

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pacold, J. I.; Lukens, W. W.; Booth, C. H.; Shuh, D. K.; Knight, K. B.; Eppich, G. R.; Holliday, K. S.

    2016-05-18

    We report that nuclear weapons testing generates large volumes of glassy materials that influence the transport of dispersed actinides in the environment and may carry information on the composition of the detonated device. We determine the oxidation state of U and Fe (which is known to buffer the oxidation state of actinide elements and to affect the redox state of groundwater) in samples of melt glass collected from three U.S. nuclear weapons tests. For selected samples, we also determine the coordination geometry of U and Fe, and we report the oxidation state of Pu from one melt glass sample. Wemore » find significant variations among the melt glass samples and, in particular, find a clear deviation in one sample from the expected buffering effect of Fe(II)/Fe(III) on the oxidation state of uranium. In the first direct measurement of Pu oxidation state in a nuclear test melt glass, we obtain a result consistent with existing literature that proposes Pu is primarily present as Pu(IV) in post-detonation material. In addition, our measurements imply that highly mobile U(VI) may be produced in significant quantities when melt glass is quenched rapidly following a nuclear detonation, though these products may remain immobile in the vitrified matrices. The observed differences in chemical state among the three samples show that redox conditions can vary dramatically across different nuclear test conditions. The local soil composition, associated device materials, and the rate of quenching are all likely to affect the final redox state of the glass. Lastly, the resulting variations in glass chemistry are significant for understanding and interpreting debris chemistry and the later environmental mobility of dispersed material.« less

  3. Models for mean bonding length, melting point and lattice thermal expansion of nanoparticle materials

    SciTech Connect (OSTI)

    Omar, M.S.

    2012-11-15

    Graphical abstract: Three models are derived to explain the nanoparticles size dependence of mean bonding length, melting temperature and lattice thermal expansion applied on Sn, Si and Au. The following figures are shown as an example for Sn nanoparticles indicates hilly applicable models for nanoparticles radius larger than 3 nm. Highlights: ► A model for a size dependent mean bonding length is derived. ► The size dependent melting point of nanoparticles is modified. ► The bulk model for lattice thermal expansion is successfully used on nanoparticles. -- Abstract: A model, based on the ratio number of surface atoms to that of its internal, is derived to calculate the size dependence of lattice volume of nanoscaled materials. The model is applied to Si, Sn and Au nanoparticles. For Si, that the lattice volume is increases from 20 Å{sup 3} for bulk to 57 Å{sup 3} for a 2 nm size nanocrystals. A model, for calculating melting point of nanoscaled materials, is modified by considering the effect of lattice volume. A good approach of calculating size-dependent melting point begins from the bulk state down to about 2 nm diameter nanoparticle. Both values of lattice volume and melting point obtained for nanosized materials are used to calculate lattice thermal expansion by using a formula applicable for tetrahedral semiconductors. Results for Si, change from 3.7 × 10{sup −6} K{sup −1} for a bulk crystal down to a minimum value of 0.1 × 10{sup −6} K{sup −1} for a 6 nm diameter nanoparticle.

  4. A quasimechanism of melt acceleration in the thermal decomposition of crystalline organic solids

    SciTech Connect (OSTI)

    Henson, Bryan F

    2009-01-01

    It has been know for half a century that many crystalline organic solids undergo an acceleration in the rate of thermal decomposition as the melting temperature is approached. This acceleration terminates at the melting point, exhibiting an Arrhenius-like temperature dependence in the faster decomposition rate from the liquid phase. This observation has been modeled previously using various premelting behaviors based on e.g. freezing point depression induced by decomposition products or solvent impurities. These models do not, however, indicate a mechanism for liquid formation and acceleration which is an inherent function of the bulk thermodynamics of the molecule. Here we show that such an inherent thermodynamic mechanism for liquid formation exists in the form of the so-called quasi-liquid layer at the solid surface. We explore a kinetic mechanism which describes the acceleration of rate and is a function of the free energies of sublimation and vaporization. We construct a differential rate law from these thermodynamic free energies and a normalized progress variable. We further construct a reduced variable formulation of the model which is a simple function of the metastable liquid activity below the melting point, and show that it is applicable to the observed melt acceleration in several common organic crystalline solids. A component of the differential rate law, zero order in the progress variable, is shown to be proportional to the thickness of the quasiliquid layer predicted by a recent thermodynamic theory for this phenomenon. This work therefore serves not only to provide new insight into thermal decomposition in a broad class or organic crystalline solids, but also further validates the underlying thermodynamic nature of the phenomenon of liquid formation on the molecular surface at temperatures below the melting point.

  5. Molecular dynamics simulation of Coulomb explosion, melting and shock wave creation in silicon after an ionization pulse

    SciTech Connect (OSTI)

    Li, Zhongyu; Shao, Lin; Chen, Di; Wang, Jing

    2014-04-14

    Strong electronic stopping power of swift ions in a semiconducting or insulating substrate can lead to localized electron stripping. The subsequent repulsive interactions among charged target atoms can cause Coulomb explosion. Using molecular dynamics simulation, we simulate Coulomb explosion in silicon by introducing an ionization pulse lasting for different periods, and at different substrate temperatures. We find that the longer the pulse period, the larger the melting radius. The observation can be explained by a critical energy density model assuming that melting required thermal energy density is a constant value and the total thermal energy gained from Coulomb explosion is linearly proportional to the ionization period. Our studies also show that melting radius is larger at higher substrate temperatures. The temperature effect is explained due to a longer structural relaxation above the melting temperature at original ionization boundary due to lower heat dissipation rates. Furthermore, simulations show the formation of shock waves, created due to the compression from the melting core.

  6. Study of formation mechanism of incipient melting in thixo-cast Al–Si–Cu–Mg alloys

    SciTech Connect (OSTI)

    Du, Kang Zhu, Qiang Li, Daquan Zhang, Fan

    2015-08-15

    Mechanical properties of thixo-cast Al–Si–Cu–Mg alloys can be enhanced by T61 heat treatment. Copper and magnesium atoms in aluminum matrix can form homogeneously distributed precipitations after solution and aging treatment which harden the alloys. However, microsegregation of these alloying elements could form numerous tiny multi-compound phases during solidification. These phases could cause incipient melting defects in subsequent heat treatment process and degrade the macro-mechanical properties of productions. This study is to present heterogeneous distribution of Cu, Si, and Mg elements and formation of incipient melting defects (pores). In this study, incipient melting pores that occurred during solution treatment at various temperatures, even lower than common melting points of various intermetallic phases, were identified, in terms of a method of investigating the same surface area in the samples before and after solution treatment in a vacuum environment. The results also show that the incipient melting mostly originates at the clusters with fine intermetallic particles while also some at the edge of block-like Al{sub 2}Cu. The fine particles were determined being Al{sub 2}Cu, Al{sub 5}Cu{sub 2}Mg{sub 8}Si{sub 6} and Al{sub 8}Mg{sub 3}FeSi{sub 2}. Tendency of the incipient melting decreases with decreases of the width of the clusters. The formation mechanism of incipient melting pores in solution treatment process was discussed using both the Fick law and the LSW theory. Finally, a criterion of solution treatment to avoid incipient melting pores for the thixo-cast alloys is proposed. - Highlights: • In-situ comparison technique was used to analysis the change of eutectic phases. • The ralationship between eutectic phase size and incipient melting was studied. • Teat treatment criterion for higher incipient melting resistance was proposed.

  7. Cutting-Edge Savannah River Site Project Avoids Millions in Costs, Removes Chemical Solvents from Underground: Project avoided costs totaling more than $15 million, removed tons of chemical solvents from beneath the Savannah River Site

    Office of Energy Efficiency and Renewable Energy (EERE)

    AIKEN, S.C. – Workers recently completed a multiyear project that removed more than 33,000 gallons of non-radioactive chemical solvents from beneath a portion of the Savannah River Site (SRS), preventing those pollutants from entering the local water table and helping the site avoid costs of more than $15 million.

  8. Melting characteristics of the stainless steel generated from the uranium conversion plant

    SciTech Connect (OSTI)

    Choi, W.K.; Song, P.S.; Oh, W.Z.; Jung, C.H.; Min, B.Y.

    2007-07-01

    The partition ratio of cerium (Ce) and uranium (U) in the ingot, slag and dust phases has been investigated for the effect of the slag type, slag concentration and basicity in an electric arc melting process. An electric arc furnace (EAF) was used to melt the stainless steel wastes, simulated by uranium oxide and the real wastes from the uranium conversion plant in Korea Atomic Energy Research Institute (KAERI). The composition of the slag former used to capture the contaminants such as uranium, cerium, and cesium during the melt decontamination process generally consisted of silica (SiO{sub 2}), calcium oxide (CaO) and aluminum oxide (Al{sub 2}O{sub 3}). Also, Calcium fluoride (CaF{sub 2} ), nickel oxide (NiO), and ferric oxide (Fe{sub 2}O{sub 3}) were added to provide an increase in the slag fluidity and oxidative potential. Cerium was used as a surrogate for the uranium because the thermochemical and physical properties of cerium are very similar to those of uranium. Cerium was removed from the ingot phase to slag phase by up to 99% in this study. The absorption ratio of cerium was increased with an increase of the amount of the slag former. And the maximum removal of cerium occurred when the basicity index of the slag former was 0.82. The natural uranium (UO{sub 2}) was partitioned from the ingot phase to the slag phase by up to 95%. The absorption of the natural uranium was considerably dependent on the basicity index of the slag former and the composition of the slag former. The optimum condition for the removal of the uranium was about 1.5 for the basicity index and 15 wt% of the slag former. According to the increase of the amount of slag former, the absorption of uranium oxide in the slag phase was linearly increased due to an increase of its capacity to capture uranium oxide within the slag phase. Through experiments with various slag formers, we verified that the slag formers containing calcium fluoride (CaF{sub 2}) and a high amount of silica were more

  9. Significance of Soft Zone Sediments at the SRS

    SciTech Connect (OSTI)

    Aadland, R.K.

    2000-02-03

    The purpose of this report is to provide information on the origin, extent and stability of ''soft zones'' in the carbonate bearing strata at the Savannah River Site (SRS). As part of this study, a comprehensive historical compendium of how soft zones have been addressed during the past 47 years at SRS is reviewed.

  10. Deep Vadose Zone Applied Field Research Initiative (DVZ AFRI) - Overview

    SciTech Connect (OSTI)

    2011-02-01

    The Deep Vadoze Zone Applied Field Research Initiative (DVZ AFRI) was established to protect water resources and to address the challenge of preventing contamination in the deep vadose zone from reaching groundwater. This factsheet provides an overview of the initiative and the approach to integrate basic science and needs-driven applied research activities with cleanup operations.

  11. Category:County Climate Zones | Open Energy Information

    Open Energy Info (EERE)

    zone information in the United States of America. Contents: Top - 0-9 A B C D E F G H I J K L M N O P Q R S T U V W X Y Z Pages in category "County Climate Zones" The following...

  12. Multi-zone methods to predict gas well performance

    SciTech Connect (OSTI)

    Blanchard, L.A.; Newhouse, J.R.

    1982-01-01

    The contributing elements of a formula developed for accurately predicting the performance of gas wells which include a high permeability zone interbedded with one or more low permeability zones are discussed. The theory assumes the existence of 3 conditions: (1) the well depletes without water encroachment; (2) each zone remains discreet from every other - that is, without cross flow among zones when the well is producing; and (3) each zone has either a hydraulic fracture or some skin effect. As a practical matter in using the model, only one of these reservoir conditions need to be met - freedom from water encroachment. The model developed does not adapt to reservoirs that have limited cross flow between zones. It also adapts to those with a hydraulic fracture in only some of the zones and includes equations which help to calculate matrix permeability whenever a known hydraulic fracture does exist. The functions of the model are illustrated by assuming the existence of a shaley-sand, 6-zone reservoir and by ascribing to it certain characteristics. The use of the model is examined and its results are discussed.

  13. Confined zone dispersion flue gas desulfurization demonstration

    SciTech Connect (OSTI)

    Not Available

    1992-02-27

    The confined zone dispersion (CZD) process involves flue gas post-treatment, physically located between a boiler's outlet and its particulate collector, which in the majority of cases is an electrostatic precipitator. The features that distinguish this process from other similar injection processes are: Injection of an alkaline slurry directly into the duct, instead of injection of dry solids into the duct ahead of a fabric filter. Use of an ultrafine calcium/magnesium hydroxide, type S pressure-hydrated dolomitic lime. This commercial product is made from plentiful, naturally occurring dolomite. Low residence time, made possible by the high effective surface area of the Type S lime. Localized dispersion of the reagent. Slurry droplets contact only part of the gas while the droplets are drying, to remove up to 50 percent of the S0{sub 2} and significant amounts of NO{sub x}. The process uses dual fluid rather than rotary atomizers. Improved electrostatic precipitator performance via gas conditioning from the increased water vapor content, and lower temperatures. Supplemental conditioning with S0{sub 3} is not believed necessary for satisfactory removal of particulate matter.

  14. HYDROGEN GREENHOUSE PLANETS BEYOND THE HABITABLE ZONE

    SciTech Connect (OSTI)

    Pierrehumbert, Raymond; Gaidos, Eric E-mail: gaidos@hawaii.edu

    2011-06-10

    We show that collision-induced absorption allows molecular hydrogen to act as an incondensible greenhouse gas and that bars or tens of bars of primordial H{sub 2}-He mixtures can maintain surface temperatures above the freezing point of water well beyond the 'classical' habitable zone defined for CO{sub 2} greenhouse atmospheres. Using a one-dimensional radiative-convective model, we find that 40 bars of pure H{sub 2} on a three Earth-mass planet can maintain a surface temperature of 280 K out to 1.5 AU from an early-type M dwarf star and 10 AU from a G-type star. Neglecting the effects of clouds and of gaseous absorbers besides H{sub 2}, the flux at the surface would be sufficient for photosynthesis by cyanobacteria (in the G star case) or anoxygenic phototrophs (in the M star case). We argue that primordial atmospheres of one to several hundred bars of H{sub 2}-He are possible and use a model of hydrogen escape to show that such atmospheres are likely to persist further than 1.5 AU from M stars, and 2 AU from G stars, assuming these planets have protecting magnetic fields. We predict that the microlensing planet OGLE-05-390Lb could have retained an H{sub 2}-He atmosphere and be habitable at {approx}2.6 AU from its host M star.

  15. Deficiencies in Vadose Zone Understanding at the INEEL

    SciTech Connect (OSTI)

    Wood, Thomas Ronald; Bates, Dona Louise; Bishop, Carolyn Wagoner; Heard, Robert Eugene; Hubbell, Joel Michael; Hull, Laurence Charles; Lehman, Richard Michael; Magnuson, Swen O; Mattson, Earl Douglas; Mccarthy, James Michael; Porro, Indrek; Ritter, Paul David; Roddy, Michael Scott; Singler, Robert Edward; Smith, Richard Paul

    2000-08-01

    Subsurface contamination in the vadose zone, that portion of the subsurface pathway between land surface and an underlying aquifer, poses environmental problems at the Idaho National Engineering and Environmental Laboratory (INEEL) in eastern Idaho and across the U.S. Department of Energy complex. Assessing potential adverse impacts from these contaminated sites requires an understanding of the mechanisms controlling contaminant transport. Currently, vadose zone experts at the INEEL cannot with confidence predict the movement of water and contaminants in the complex, heterogeneous, fractured subsurface at the INEEL, especially within the vadose zone. In the draft version (Revision 1) of the Vadose Zone Deficiencies document, deficiencies in scientific understanding of flow and transport processes in the vadose zone at the INEEL were identified and grouped into 13 categories and recommendations were provided to address each of the deficiencies. The draft document provided the basis for an INEEL Vadose Zone Workshop that was conducted October 20 and 21, 1999, in Idaho Falls, Idaho. The workshop was conducted to group and rank the previously identified deficiencies and for the subsequent development of science plans to address the deficiencies that limit reliable predictions of water and contaminant movement in the subsurface. The workshop participants, comprising INEEL and scientists and project managers and non-INEEL scientists knowledgeable about the vadose zone, developed science- and technology-based recommendations derived through a series of technical sessions at the workshop. In this document, the final version of the Vadose Zone Deficiencies document, the draft document has been incorporated, largely intact, as well as the results from the workshop. The workshop participants grouped the deficiencies in vadose zone understanding at the INEEL into seven categories. These seven categories will be the focus areas of five science plans that are being developed to

  16. The effect of venting on cookoff of a melt-castable explosive (Comp-B)

    SciTech Connect (OSTI)

    Hobbs, Michael L.; Kaneshige, Michael J.

    2015-03-01

    Occasionally, our well-controlled cookoff experiments with Comp-B give anomalous results when venting conditions are changed. For example, a vented experiment may take longer to ignite than a sealed experiment. In the current work, we show the effect of venting on thermal ignition of Comp-B. We use Sandia’s Instrumented Thermal Ignition (SITI) experiment with various headspace volumes in both vented and sealed geometries to study ignition of Comp-B. In some of these experiments, we have used a boroscope to observe Comp-B as it melts and reacts. We propose that the mechanism for ignition involves TNT melting, dissolution of RDX, and complex bubbly liquid flow. High pressure inhibits bubble formation and flow is significantly reduced. At low pressure, a vigorous dispersed bubble flow was observed.

  17. Melt-cast organic glasses as high-efficiency fast neutron scintillators

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Carlson, Joseph S.; Feng, Patrick L.

    2016-06-24

    In this work we report a new class of organic-based scintillators that combines several of the desirable attributes of existing crystalline, liquid, and plastic organic scintillators. The prepared materials may be isolated in single crystalline form or melt-cast to produce highly transparent glasses that have been shown to provide high light yields of up to 16,000 photons/MeVee, as evaluated against EJ-200 plastic scintillators and solution-grown trans-stilbene crystals. The prepared organic glasses exhibit neutron/gamma pulse-shape discrimination (PSD) and are compatible with wavelength shifters to reduce optical self-absorption effects that are intrinsic to pure materials such as crystalline organics. In conclusion, themore » combination of high scintillation efficiency, PSD capabilities, and facile scale-up via melt-casting distinguishes this new class of amorphous materials from existing alternatives.« less

  18. Reducing Ultra-Clean Transportation Fuel Costs with HyMelt Hydrogen

    SciTech Connect (OSTI)

    Donald P. Malone; William R. Renner

    2006-01-01

    This report describes activities for the thirteenth quarter of work performed under this agreement. EnviRes initiated a wire transfer of funds for procurement of a pressure vessel and associated refractory lining. Phase I of the work to be done under this agreement consisted of conducting atmospheric gasification of coal using the HyMelt technology to produce separate hydrogen rich and carbon monoxide rich product streams. In addition smaller quantities of petroleum coke and a low value refinery stream were gasified. Phase II of the work to be done under this agreement, consists of gasification of the above-mentioned feeds at a gasifier pressure of approximately 5 bar. The results of this work will be used to evaluate the technical and economic aspects of producing ultra-clean transportation fuels using the HyMelt technology in existing and proposed refinery configurations.

  19. Reducing Ultra-Clean Transportation Fuel Costs with HyMelt Hydrogen

    SciTech Connect (OSTI)

    Donald P. Malone; William R. Renner

    2006-04-01

    Phase I of the work to be done under this agreement consisted of conducting atmospheric gasification of coal using the HyMelt technology to produce separate hydrogen rich and carbon monoxide rich product streams. In addition smaller quantities of petroleum coke and a low value refinery stream were gasified. Phase II of the work to be done under this agreement, consists of gasification of the above-mentioned feeds at a gasifier pressure of approximately 5 bar. The results of this work will be used to evaluate the technical and economic aspects of producing ultra-clean transportation fuels using the HyMelt technology in existing and proposed refinery configurations. This report describes activities for the thirteenth quarter of work performed under this agreement. MEFOS, the gasification testing subcontractor, reported to EnviRes that they were having difficulty with refractory vendors meeting specifications for the lining of the pressure vessel. EnviRes is working to resolve this issue.

  20. Melting behaviour of gold-platinum nanoalloy clusters by molecular dynamics simulations

    SciTech Connect (OSTI)

    Ong, Yee Pin; Yoon, Tiem Leong; Lim, Thong Leng

    2015-04-24

    The melting behavior of bimetallic gold-platinum nanoclusters is studied by applying Brownian-type isothermal molecular dynamics (MD) simulation, a program modified from the cubic coupling scheme (CCS). The process begins with the ground-state structures obtained from global minimum search algorithm and proceeds with the investigation of the effect of temperature on the thermal properties of gold-platinum nanoalloy clusters. N-body Gupta potential has been employed in order to account for the interactions between gold and platinum atoms. The ground states of the nanoalloy clusters, which are core-shell segregated, are heated until they become thermally segregated. The detailed melting mechanism of the nanoalloy clusters is studied via this approach to provide insight into the thermal stability of the nanoalloy clusters.

  1. Melt-castable energetic compounds comprising oxadiazoles and methods of production thereof

    DOE Patents [OSTI]

    Pagoria, Philip F; Zhang, Mao X

    2013-11-12

    In one embodiment, a melt-castable energetic material comprises at least one of: 3,5-bis(4-nitro-1,2,5-oxadiazol-3-yl)-1,2,4-oxadiazole (DNFO), and 3-(4-amino-1,2,5-oxadiazol-3-yl)-5-(4-nitro-1,2,5-oxadiazol-3-yl)-1,2- ,4-oxadiazole (ANFO). In another embodiment, a method for forming a melt-castable energetic material includes reacting 3,5-bis(4-amino-1,2,5-oxadiazol-3-yl)-1,2,4-oxadiazole (DAFO) with oxygen or an oxygen-containing compound to form a mixture of at least: DNFO, and ANFO.

  2. Surface hardening of titanium alloys with melting depth controlled by heat sink

    DOE Patents [OSTI]

    Oden, Laurance L.; Turner, Paul C.

    1995-01-01

    A process for forming a hard surface coating on titanium alloys includes providing a piece of material containing titanium having at least a portion of one surface to be hardened. The piece having a portion of a surface to be hardened is contacted on the backside by a suitable heat sink such that the melting depth of said surface to be hardened may be controlled. A hardening material is then deposited as a slurry. Alternate methods of deposition include flame, arc, or plasma spraying, electrodeposition, vapor deposition, or any other deposition method known by those skilled in the art. The surface to be hardened is then selectively melted to the desired depth, dependent on the desired coating thickness, such that a molten pool is formed of the piece surface and the deposited hardening material. Upon cooling a hardened surface is formed.

  3. Study of microstructure and electrical properties of bulk YBCO prepared by melt textured growth technique

    SciTech Connect (OSTI)

    Gonal, M. R.; Krishnan, Madangopal; Tewari, R.; Tyagi, A. K.; Gyore, A.; Vajda, I.

    2015-06-24

    Bulk YBCO components were prepared using Melt Texture Growth (MTG) technique. Components were fabricated using MTG by addition of Y{sub 2}BaCuO{sub 5} (Y211) and Ag to YBCO, which leads to improved grain size without affecting superconducting properties. Green compacts prepared by cold isostatic pressing were pre-sintered at 930°C before subjecting melt texturing. Cooling rates lower than 1 °C.h{sup −1} was used, in between (peritectic) temperature of about 995 and 1025°C, to obtain large grained components. Microstructure studies in details were carried out by Scanning Electron Microscope (SEM), Electron Probe Micro Analysis (EPMA), Orientation Imaging Microscope (OIM) and TEM correlated with electrical properties like Critical current density (J{sub c})

  4. The effect of venting on cookoff of a melt-castable explosive (Comp-B)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hobbs, Michael L.; Kaneshige, Michael J.

    2015-03-01

    Occasionally, our well-controlled cookoff experiments with Comp-B give anomalous results when venting conditions are changed. For example, a vented experiment may take longer to ignite than a sealed experiment. In the current work, we show the effect of venting on thermal ignition of Comp-B. We use Sandia’s Instrumented Thermal Ignition (SITI) experiment with various headspace volumes in both vented and sealed geometries to study ignition of Comp-B. In some of these experiments, we have used a boroscope to observe Comp-B as it melts and reacts. We propose that the mechanism for ignition involves TNT melting, dissolution of RDX, and complexmore » bubbly liquid flow. High pressure inhibits bubble formation and flow is significantly reduced. At low pressure, a vigorous dispersed bubble flow was observed.« less

  5. Separation of CsCl from a Ternary CsCl-LiCl-KCl Salt via a Melt Crystallization Technique for Pyroprocessing Waste Minimization

    SciTech Connect (OSTI)

    Ammon Williams; Supathorn Phongikaroon; Michael Simpson

    2013-02-01

    A parametric study has been conducted to identify the effects of several parameters on the separation of CsCl from molten LiCl-KCl salt via a melt crystallization process. A reverse vertical Bridgman technique was used to grow the salt crystals. The investigated parameters were: (1) the advancement rate, (2) the crucible lid configuration, (3) the amount of salt mixture, (4) the initial composition of CsCl, and (5) the temperature difference between the high and low furnace zones. From each grown crystal, samples were taken axially and analyzed using inductively coupled plasma mass spectrometry (ICP-MS). Results show that CsCl concentrations at the top of the crystals were low and increased to a maximum at the bottom of the salt. Salt (LiCl-KCl) recycle percentages for the experiments ranged from 50% to 75% and the CsCl composition in the waste salt was low. To increase the recycle percentage and the concentration of CsCl in the waste form, the possibility of using multiple crystallization stages was explored to further optimize the process. Results show that multiple crystallization stages are practical and the optimal experimental conditions should be operated at 5.0 mm/hr rate with a lid configuration and temperature difference of 200 C for a total of five crystallization stages. Under these conditions, up to 88% of the salt can be recycled.

  6. Relationship between Structural and Stress Relaxation in a Block-Copolymer Melt

    SciTech Connect (OSTI)

    Patel, Amish J.; Narayanan, Suresh; Sandy, Alec; Mochrie, Simon G. J.; Garetz, Bruce A.; Watanabe, Hiroshi; Balsara, Nitash P.

    2006-06-30

    The relationship between structural relaxation on molecular length scales and macroscopic stress relaxation was explored in a disordered block-copolymer melt. Experiments show that the structural relaxation time, measured by x-ray photon correlation spectroscopy is larger than the terminal stress relaxation time, measured by rheology, by factors as large as 100. We demonstrate that the structural relaxation data are dominated by the diffusion of intact micelles while the stress relaxation data are dominated by contributions due to disordered concentration fluctuations.

  7. Draft report on melt point as a function of composition for urania-based systems

    SciTech Connect (OSTI)

    Valdez, James A; Byler, Darrin D

    2012-06-08

    This report documents the testing of a urania (UO{sub 2.00}) sample as a baseline and the attempt to determine the melt point associated with 4 compositions of urania-ceria and urania-neodymia pseudo binaries provided by ORNL, with compositions of 95/5, and 80/20 and of (U/Ce)O{sub 2.00} and (U/Nd)O{sub 2.00} in the newly developed ceramic melt point determination system. A redesign of the system using parts fabricated from tungsten was undertaken in order to help prevent contamination and tungsten carbide formation in the crucibles. The previously developed system employed mostly graphite parts that were shown to react with the sample containment black-body crucible leading to unstable temperature readings and crucible failure, thus the redesign. Measured melt point values of UO{sub 2.00} and U{sub 0.95}Ce{sub 0.05}O{sub 2.00}, U{sub 0.80}Ce{sub 0.20}O{sub 2.00}, U{sub 0.95}Nd{sub 0.05}O{sub 2.00} and U{sub 0.80}Nd{sub 0.20}O{sub 2.00} were measured using a 2-color pyrometer. The value measured for UO{sub 2.00} was consistent with the published accepted value 2845 C {+-} 25 C, although a wide range of values has been published by researchers and will be discussed later in the text. For comparison, values obtained from a published binary phase diagram of UO{sub 2}-Nd{sub 2}O{sub 3} were used for comparison with our measure values. No literature melt point values for comparison with the measurements performed in this study were found for (U/Ce)O{sub 2.00} in our stoichiometry range.

  8. CHEMISTRY OF IMPACT-GENERATED SILICATE MELT-VAPOR DEBRIS DISKS

    SciTech Connect (OSTI)

    Visscher, Channon; Fegley, Bruce Jr.

    2013-04-10

    In the giant impact theory for lunar origin, the Moon forms from material ejected by the impact into an Earth-orbiting disk. Here we report the initial results from a silicate melt-vapor equilibrium chemistry model for such impact-generated planetary debris disks. In order to simulate the chemical behavior of a two-phase (melt+vapor) disk, we calculate the temperature-dependent pressure and chemical composition of vapor in equilibrium with molten silicate from 2000 to 4000 K. We consider the elements O, Na, K, Fe, Si, Mg, Ca, Al, Ti, and Zn for a range of bulk silicate compositions (Earth, Moon, Mars, eucrite parent body, angrites, and ureilites). In general, the disk atmosphere is dominated by Na, Zn, and O{sub 2} at lower temperatures (<3000 K) and SiO, O{sub 2}, and O at higher temperatures. The high-temperature chemistry is consistent for any silicate melt composition, and we thus expect abundant SiO, O{sub 2}, and O to be a common feature of hot, impact-generated debris disks. In addition, the saturated silicate vapor is highly oxidizing, with oxygen fugacity (f{sub O{sub 2}}) values (and hence H{sub 2}O/H{sub 2} and CO{sub 2}/CO ratios) several orders of magnitude higher than those in a solar-composition gas. High f{sub O{sub 2}} values in the disk atmosphere are found for any silicate composition because oxygen is the most abundant element in rock. We thus expect high oxygen fugacity to be a ubiquitous feature of any silicate melt-vapor disk produced via collisions between rocky planets.

  9. Mixed Waste Treatment Cost Analysis for a Range of GeoMelt Vitrification Process Configurations

    SciTech Connect (OSTI)

    Thompson, L. E.

    2002-02-27

    GeoMelt is a batch vitrification process used for contaminated site remediation and waste treatment. GeoMelt can be applied in several different configurations ranging from deep subsurface in situ treatment to aboveground batch plants. The process has been successfully used to treat a wide range of contaminated wastes and debris including: mixed low-level radioactive wastes; mixed transuranic wastes; polychlorinated biphenyls; pesticides; dioxins; and a range of heavy metals. Hypothetical cost estimates for the treatment of mixed low-level radioactive waste were prepared for the GeoMelt subsurface planar and in-container vitrification methods. The subsurface planar method involves in situ treatment and the in-container vitrification method involves treatment in an aboveground batch plant. The projected costs for the subsurface planar method range from $355-$461 per ton. These costs equate to 18-20 cents per pound. The projected cost for the in-container method is $1585 per ton. This cost equates to 80 cents per pound. These treatment costs are ten or more times lower than the treatment costs for alternative mixed waste treatment technologies according to a 1996 study by the US Department of Energy.

  10. Reconsideration of natural-gas immersion burners to melt recycled aluminum

    SciTech Connect (OSTI)

    Clark, John A., III; Thekdi, Arvind; Ningileri, S.; Han, Q.

    2005-09-01

    The best open flame reverberatory aluminum melting furnaces are approximately 45% efficient. Furnace efficiency can be increased by using immersed tube burners. Currently, recuperated tube burners with capacities to remelt aluminum are available. Tube burners would allow remelt furnaces to operate at lower temperatures, reduce dross formation, reduce particulate emissions, and provide clean flue gas to other energy intensive processes. Babcock and Wilcox, under GRI (now GTI – Gas Technology Institute) contract in the late-1980’s, demonstrated the technically feasibility of immersion melting of aluminum. However, tube reliability was problematic due to metal penetration, dross build-up, thermal shock, and mechanical failure. Also, the concept of “cold start” melting was not addressed. The Albany Research Center (U.S. DOE) is cooperating with Secat, E3M Inc., the University of Kentucky, and Oak Ridge National Laboratory in an ITP-sponsored program to combine emerging technologies in a retrofitable furnace package targeting improved remelt efficiency ranging from 55% to 75%.

  11. Theoretical calculation of the melting curve of Cu-Zr binary alloys

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gunawardana, K. G.S.H.; Wilson, S. R.; Mendelev, M. I.; Song, Xueyu

    2014-11-14

    Helmholtz free energies of the dominant binary crystalline solids found in the Cu-Zr system at high temperatures close to the melting curve are calculated. This theoretical approach combines fundamental measure density functional theory (applied to the hard-sphere reference system) and a perturbative approach to include the attractive interactions. The studied crystalline solids are Cu(fcc), Cu51Zr14(β), CuZr(B2), CuZr2(C11b), Zr(hcp), and Zr(bcc). The calculated Helmholtz free energies of crystalline solids are in good agreement with results from molecular-dynamics (MD) simulations. Using the same perturbation approach, the liquid phase free energies are calculated as a function of composition and temperature, from which themore » melting curve of the entire composition range of this system can be obtained. Phase diagrams are determined in this way for two leading embedded atom method potentials, and the results are compared with experimental data. Furthermore, theoretical melting temperatures are compared both with experimental values and with values obtained directly from MD simulations at several compositions.« less

  12. Theoretical calculation of the melting curve of Cu-Zr binary alloys

    SciTech Connect (OSTI)

    Gunawardana, K. G.S.H.; Wilson, S. R.; Mendelev, M. I.; Song, Xueyu

    2014-11-14

    Helmholtz free energies of the dominant binary crystalline solids found in the Cu-Zr system at high temperatures close to the melting curve are calculated. This theoretical approach combines fundamental measure density functional theory (applied to the hard-sphere reference system) and a perturbative approach to include the attractive interactions. The studied crystalline solids are Cu(fcc), Cu51Zr14(β), CuZr(B2), CuZr2(C11b), Zr(hcp), and Zr(bcc). The calculated Helmholtz free energies of crystalline solids are in good agreement with results from molecular-dynamics (MD) simulations. Using the same perturbation approach, the liquid phase free energies are calculated as a function of composition and temperature, from which the melting curve of the entire composition range of this system can be obtained. Phase diagrams are determined in this way for two leading embedded atom method potentials, and the results are compared with experimental data. Furthermore, theoretical melting temperatures are compared both with experimental values and with values obtained directly from MD simulations at several compositions.

  13. Melting and thermal expansion in the Fe-FeO system at high pressure

    SciTech Connect (OSTI)

    Seagle, C. T.; Heinz, D. L.; Campbell, A. J.; Prakapenka, V. B.; Wanless, S. T.

    2015-02-26

    Melting in the Fe–FeO system was investigated at pressures up to 93 GPa using synchrotron X-ray diffraction (XRD) and a laser heated diamond anvil cell (DAC). The criteria for melting were the disappearance of reflections associated with one of the end-member phases upon raising the temperature above the eutectic and the reappearance of those reflections on dropping the temperature below the eutectic. The Fe–FeO system is a simple eutectic at 50 GPa and remains eutectic to at least 93 GPa. The eutectic temperature was bound at several pressure points between 19 and 93 GPa, and in some cases the liquidus temperature was also determined. The eutectic temperature rises rapidly with pressure closely following the melting curve of pure Fe. A detailed phase diagram at 50 GPa is presented; the eutectic temperature is 2500 ± 150 K and the eutectic composition is bound between 7.6 ± 1.0 and 9.5 ± 1.0 wt.% O. The coefficient of thermal expansion of FeO is a strong function of volume and decreases with pressure according to a simple power law.

  14. Electric-resistance furnace for melting ash from municipal solid waste incinerator

    SciTech Connect (OSTI)

    Nakao, Tsuyoshi; Nakahara, Keisuke; Akashi, Tetsuo

    1997-12-31

    Existing landfill capacity is dwindling in Japan and it is difficult to find new landfill sites because of strong opposition from residents. Under the Waste Disposal and Public Cleaning Law in 1991 in Japan, fly ashes from municipal solid waste (MSW) incinerator have to be treated by one of the four methods: (1) vitrification, (2) solidification by cement, (3) stabilization using chemical agents, or (4) extraction with acid or other solvent. In these four technologies, the vitrification technology has some advantages: decreasing ash volume which can solve the landfill problem, de-taxiing ash, and utilization of its products from residues. NKK has developed an electric resistance furnace for melting MSW incineration residues and built a demonstration plant (24t/d). The performance test results showed as follows; (1) Si, Al, and Ca tended to become the molten slag. Cu, P, and Fe tended to become the molten metal. Pb, Zn, and Cd tended to become the molten fly ash. (2) HCl from the slag resistance electric furnace was 60 ppm and very low compared with other melting systems. (3) Decomposition rate of dioxins was 99 % in the melting furnace. (4) Concentration of heavy metals in the molten slag was low and leaching of heavy metals was below Japanese regulation.

  15. Enhanced power factor of higher manganese silicide via melt spin synthesis method

    SciTech Connect (OSTI)

    Shi, Xiaoya; Shi, Xun; Li, Yulong; He, Ying; Chen, Lidong; Li, Qiang

    2014-12-30

    We report on the thermoelectric properties of the Higher Manganese Silicide MnSi₁.₇₅ (HMS) synthesized by means of a one-step non-equilibrium method. The ultrahigh cooling rate generated from the melt-spin technique is found to be effective in reducing second phases, which are inevitable during the traditional solid state diffusion processes. Aside from being detrimental to thermoelectric properties, second phases skew the revealing of the intrinsic properties of this class of materials, for example the optimal level of carrier concentration. With this melt-spin sample, we are able to formulate a simple model based on a single parabolic band that can well describe the carrier concentration dependence of the Seebeck coefficient and power factor of the data reported in the literature. An optimal carrier concentration around 5x10²⁰ cm⁻³ at 300 K is predicted according to this model. The phase-pure melt-spin sample shows the largest power factor at high temperature, resulting in the highest zT value among the three samples in this paper; the maximum value is superior to those reported in the literatures.

  16. Enhanced power factor of higher manganese silicide via melt spin synthesis method

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shi, Xiaoya; Shi, Xun; Li, Yulong; He, Ying; Chen, Lidong; Li, Qiang

    2014-12-30

    We report on the thermoelectric properties of the Higher Manganese Silicide MnSi₁.₇₅ (HMS) synthesized by means of a one-step non-equilibrium method. The ultrahigh cooling rate generated from the melt-spin technique is found to be effective in reducing second phases, which are inevitable during the traditional solid state diffusion processes. Aside from being detrimental to thermoelectric properties, second phases skew the revealing of the intrinsic properties of this class of materials, for example the optimal level of carrier concentration. With this melt-spin sample, we are able to formulate a simple model based on a single parabolic band that can well describemore » the carrier concentration dependence of the Seebeck coefficient and power factor of the data reported in the literature. An optimal carrier concentration around 5x10²⁰ cm⁻³ at 300 K is predicted according to this model. The phase-pure melt-spin sample shows the largest power factor at high temperature, resulting in the highest zT value among the three samples in this paper; the maximum value is superior to those reported in the literatures.« less

  17. Enhanced power factor of higher manganese silicide via melt spin synthesis method

    SciTech Connect (OSTI)

    Shi, Xiaoya; Li, Qiang; Shi, Xun; Chen, Lidong; Li, Yulong; He, Ying

    2014-12-28

    We report on the thermoelectric properties of the higher manganese silicide MnSi{sub 1.75} synthesized by means of a one-step non-equilibrium method. The ultrahigh cooling rate generated from the melt-spin technique is found to be effective in reducing second phases, which are inevitable during the traditional solid state diffusion processes. Aside from being detrimental to thermoelectric properties, second phases skew the revealing of the intrinsic properties of this class of materials, for example, the optimal level of carrier concentration. With this melt-spin sample, we are able to formulate a simple model based on a single parabolic band that can well describe the carrier concentration dependence of the Seebeck coefficient and power factor of the data reported in the literature. An optimal carrier concentration around 5 × 10{sup 20 }cm{sup −3} at 300 K is predicted according to this model. The phase-pure melt-spin sample shows the largest power factor at high temperature, resulting in the highest zT value among the three samples in this paper.

  18. Cluster Morphology-Polymer Dynamics Correlations in Sulfonated Polystyrene Melts: Computational Study

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Agrawal, Anupriya; Perahia, Dvora; Grest, Gary S.

    2016-04-11

    Reaching exceptionally long times up to 500 ns in equilibrium and nonequilibrium molecular dynamics simulations studies, we have attained a fundamental molecular understanding of the correlation of ionomer clusters structure and multiscale dynamics, providing new insight into one critical, long-standing challenge in ionic polymer physics. The cluster structure in melts of sulfonated polystyrene with Na+ and Mg2+ counterions are resolved and correlated with the dynamics on multiple length and time scales extracted from measurements of the dynamic structure factor and shear rheology. We find that as the morphology of the ionic clusters changes from ladderlike for Na+ to disordered structuresmore » for Mg2+, the dynamic structure factor is affected on the length scale corresponding to the ionic clusters. Lastly, rheology studies show that the viscosity for Mg2+ melts is higher than for Na+ ones for all shear rates, which is well correlated with the larger ionic clusters’ size for the Mg2+ melts.« less

  19. Enhanced power factor of higher manganese silicide via melt spin synthesis method

    SciTech Connect (OSTI)

    Shi, Xiaoya; Shi, Xun; Li, Yulong; He, Ying; Chen, Lidong; Li, Qiang

    2014-12-30

    We report on the thermoelectric properties of the Higher Manganese Silicide MnSi?.?? (HMS) synthesized by means of a one-step non-equilibrium method. The ultrahigh cooling rate generated from the melt-spin technique is found to be effective in reducing second phases, which are inevitable during the traditional solid state diffusion processes. Aside from being detrimental to thermoelectric properties, second phases skew the revealing of the intrinsic properties of this class of materials, for example the optimal level of carrier concentration. With this melt-spin sample, we are able to formulate a simple model based on a single parabolic band that can well describe the carrier concentration dependence of the Seebeck coefficient and power factor of the data reported in the literature. An optimal carrier concentration around 5x10? cm? at 300 K is predicted according to this model. The phase-pure melt-spin sample shows the largest power factor at high temperature, resulting in the highest zT value among the three samples in this paper. And the maximum value is superior to those reported in the literatures.

  20. Melting of the metallic wastes generated by dismantling retired nuclear research facilities

    SciTech Connect (OSTI)

    Chong-Hun Jung; Pyung-Seob Song; Byung-Youn Min; Wang-Kyu Choi

    2008-01-15

    The decommissioning of nuclear installations results in considerably large amounts of radioactive metallic wastes such as stainless steel, carbon steel, aluminum, copper etc. It is known that the reference 1,000 MWe PWR and 881 MWe PHWR will generate metal wastes of 24,800 ton and 26,500 ton, respectively. In Korea, the D and D of KRR-2 and a UCP at KAERI have been performed. The amount of metallic wastes from the KRR-1 and UCP was about 160 ton and 45 ton, respectively, up to now. These radioactive metallic wastes will induce problems of handling and storing these materials from environmental and economical aspects. For this reason, prompt countermeasures should be taken to deal with the metal wastes generated by dismantling retired nuclear facilities. The most interesting materials among the radioactive metal wastes are stainless steel (SUS), carbon steel (CS) and aluminum wastes because they are the largest portions of the metallic wastes generated by dismantling retired nuclear research facilities. As most of these steels are slightly contaminated, if they are properly treated they are able to be recycled and reused in the nuclear field. In general, the technology of a metal melting is regarded as one of the most effective methods to treat metallic wastes from nuclear facilities. In conclusion: The melting of metal wastes (Al, SUS, carbon steel) from a decommissioning of research reactor facilities was carried out with the use of a radioisotope such as cobalt and cesium in an electric arc furnace. In the aluminum melting tests, the cobalt was captured at up to 75% into the slag phase. Most of the cesium was completely eliminated from the aluminum ingot phase and moved into the slag and dust phases. In the melting of the stainless steel wastes, the {sup 60}Co could almost be retained uniformly in the ingot phase. However, we found that significant amounts of {sup 60}Co remained in the slag at up to 15%. However the removal of the cobalt from the ingot phase was