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1

AP-XPS Measures MIEC Oxides in Action  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AP-XPS Measures MIEC Oxides in AP-XPS Measures MIEC Oxides in Action AP-XPS Measures MIEC Oxides in Action Print Wednesday, 25 May 2011 00:00 Oxide materials with mixed ionic-electronic conductivity (MIEC) can conduct both electrons and oxygen ions. MIEC oxides have broad applications, including use in solid-oxide fuel cells, high-temperature electrolysis for synthetic fuel production, and oxygen-separating membranes for chemical processes or NOx-free combustion; however, their surface activity under reaction conditions has been difficult, if not impossible, to ascertain, until recently. A team from the University of Maryland and Sandia National Laboratories joined ALS scientists on Beamlines 9.3.2 and 11.0.2 to overcome the vacuum limitations of conventional XPS instruments using ambient-pressure x-ray photoelectron spectroscopy (AP-XPS), providing the first in situ measurements of local surface oxidation states and electric potential in active MIEC electrodes.

2

AP-XPS Measures MIEC Oxides in Action  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AP-XPS Measures MIEC Oxides in Action Print AP-XPS Measures MIEC Oxides in Action Print Oxide materials with mixed ionic-electronic conductivity (MIEC) can conduct both electrons and oxygen ions. MIEC oxides have broad applications, including use in solid-oxide fuel cells, high-temperature electrolysis for synthetic fuel production, and oxygen-separating membranes for chemical processes or NOx-free combustion; however, their surface activity under reaction conditions has been difficult, if not impossible, to ascertain, until recently. A team from the University of Maryland and Sandia National Laboratories joined ALS scientists on Beamlines 9.3.2 and 11.0.2 to overcome the vacuum limitations of conventional XPS instruments using ambient-pressure x-ray photoelectron spectroscopy (AP-XPS), providing the first in situ measurements of local surface oxidation states and electric potential in active MIEC electrodes.

3

AP-XPS Measures MIEC Oxides in Action  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AP-XPS Measures MIEC Oxides in Action Print AP-XPS Measures MIEC Oxides in Action Print Oxide materials with mixed ionic-electronic conductivity (MIEC) can conduct both electrons and oxygen ions. MIEC oxides have broad applications, including use in solid-oxide fuel cells, high-temperature electrolysis for synthetic fuel production, and oxygen-separating membranes for chemical processes or NOx-free combustion; however, their surface activity under reaction conditions has been difficult, if not impossible, to ascertain, until recently. A team from the University of Maryland and Sandia National Laboratories joined ALS scientists on Beamlines 9.3.2 and 11.0.2 to overcome the vacuum limitations of conventional XPS instruments using ambient-pressure x-ray photoelectron spectroscopy (AP-XPS), providing the first in situ measurements of local surface oxidation states and electric potential in active MIEC electrodes.

4

AP-XPS Measures MIEC Oxides in Action  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AP-XPS Measures MIEC Oxides in Action Print AP-XPS Measures MIEC Oxides in Action Print Oxide materials with mixed ionic-electronic conductivity (MIEC) can conduct both electrons and oxygen ions. MIEC oxides have broad applications, including use in solid-oxide fuel cells, high-temperature electrolysis for synthetic fuel production, and oxygen-separating membranes for chemical processes or NOx-free combustion; however, their surface activity under reaction conditions has been difficult, if not impossible, to ascertain, until recently. A team from the University of Maryland and Sandia National Laboratories joined ALS scientists on Beamlines 9.3.2 and 11.0.2 to overcome the vacuum limitations of conventional XPS instruments using ambient-pressure x-ray photoelectron spectroscopy (AP-XPS), providing the first in situ measurements of local surface oxidation states and electric potential in active MIEC electrodes.

5

AP-XPS Measures MIEC Oxides in Action  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

models of these materials for use in designing more efficient hydrogen gas production processes, like electrolysis, from renewable power sources, like water, allowing for...

6

Direct Measurement of Oxygen Incorporation into Thin Film Oxides...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Measurement of Oxygen Incorporation into Thin Film Oxides at Room Temperature Upon Ultraviolet Phton Irradiation. Direct Measurement of Oxygen Incorporation into Thin Film Oxides...

7

Direct measurement and analysis of cyclohexadienyl oxidation  

E-Print Network [OSTI]

The oxidation of cyclohexadienyl radical (c-C?H?) and similar resonantly stabilized radicals are important in an astonishing array of processes in nature. Cyclohexadienyl radical has been postulated to be significant in a ...

Taylor, James Wagner

2005-01-01T23:59:59.000Z

8

Photo-oxidation of Ge Nanocrystals: Kinetic Measurements by In Situ Raman Spectroscopy  

E-Print Network [OSTI]

Photo-oxidation of Ge Nanocrystals: Kinetic Measurements byrate enhancement is due to a photo-chemical process. Thenanocrystals can be rapidly photo-oxidized. This oxidation

2008-01-01T23:59:59.000Z

9

Hydrogen pickup measurements in zirconium alloys: Relation to oxidation kinetics  

E-Print Network [OSTI]

Hydrogen pickup measurements in zirconium alloys: Relation to oxidation kinetics Adrien Couet a to reduce hydrogen pickup during operation, and the associated cladding degradation. The present study focuses on precisely and accurately measuring hydrogen pickup fraction for a set of alloys to specifically

Motta, Arthur T.

10

Passive Time Coincidence Measurements with HEU Oxide Fuel Pins  

SciTech Connect (OSTI)

Passive time coincidence measurements have been performed on highly enriched uranium (HEU) oxide fuel pins at the Idaho National Laboratory Power Burst Facility. These experiments evaluate HEU detection capability using passive coincidence counting when utilizing moderated 3He tubes. Data acquisition was performed with the Nuclear Material Identification System (NMIS) to calculate the neutron coincidence time distributions. The amounts of HEU measured were 1 kg, 4 kg, and 8 kg in sealed 55-gallon drums. Data collected with the 3He tubes also include passive measurement of 31 kg of depleted uranium (DU) in order to determine the ability to distinguish HEU from DU. This paper presents results from the measurements.

McConchie, Seth M [ORNL] [ORNL; Hausladen, Paul [ORNL] [ORNL; Mihalczo, John T [ORNL] [ORNL

2008-01-01T23:59:59.000Z

11

ALSNews Vol. 320  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The beam status in real time can be found on the ALS home page. In This Issue Cool Magnetic Molecules AP-XPS Measures MIEC Oxides in Action ALS Users' Meeting Update General...

12

Electrocatalytic Measurement Methodology of Oxide Catalysts Using a Thin-Film Rotating Disk Electrode  

E-Print Network [OSTI]

Transition-metal oxides can exhibit high electrocatalytic activity for reactions such as the oxygen reduction reaction (ORR) in alkaline media. It is often difficult to measure and compare the activities of oxide catalysts ...

Suntivich, Jin

13

Solid oxide fuel cells having porous cathodes infiltrated with oxygen-reducing catalysts  

DOE Patents [OSTI]

Solid-oxide fuel cells include an electrolyte and an anode electrically coupled to a first surface of the electrolyte. A cathode is provided, which is electrically coupled to a second surface of the electrolyte. The cathode includes a porous backbone having a porosity in a range from about 20% to about 70%. The porous backbone contains a mixed ionic-electronic conductor (MIEC) of a first material infiltrated with an oxygen-reducing catalyst of a second material different from the first material.

Liu, Meilin; Liu, Ze; Liu, Mingfei; Nie, Lifang; Mebane, David Spencer; Wilson, Lane Curtis; Surdoval, Wayne

2014-08-12T23:59:59.000Z

14

Measurement and Meaning of Oxidatively Modified DNA Lesions in Urine  

Science Journals Connector (OSTI)

...commercially available kits presently on the market. Two are available from JICA, named...oxidative stress-inducing agents, such as diesel emission particles or potassium bromate...Moller P, et al. Repeated inhalations of diesel exhaust particles and oxidatively damaged...

Marcus S. Cooke; Ryszard Olinski; and Steffen Loft

2008-01-01T23:59:59.000Z

15

MOISTURE AND SURFACE AREA MEASUREMENTS OF PLUTONIUM-BEARING OXIDES  

SciTech Connect (OSTI)

To ensure safe storage, plutonium-bearing oxides are stabilized at 950 C for at least two hours in an oxidizing atmosphere. Stabilization conditions are expected to decompose organic impurities, convert metals to oxides, and result in moisture content below 0.5 wt%. During stabilization, the specific surface area is reduced, which minimizes readsorption of water onto the oxide surface. Plutonium oxides stabilized according to these criteria were sampled and analyzed to determine moisture content and surface area. In addition, samples were leached in water to identify water-soluble chloride impurity content. Results of these analyses for seven samples showed that the stabilization process produced low moisture materials (< 0.2 wt %) with low surface area ({le} 1 m{sup 2}/g). For relatively pure materials, the amount of water per unit surface area corresponded to 1.5 to 3.5 molecular layers of water. For materials with chloride content > 360 ppm, the calculated amount of water per unit surface area increased with chloride content, indicating hydration of hygroscopic salts present in the impure PuO{sub 2}-containing materials. The low moisture, low surface area materials in this study did not generate detectable hydrogen during storage of four or more years.

Crowder, M.; Duffey, J.; Livingston, R.; Scogin, J.; Kessinger, G.; Almond, P.

2009-09-28T23:59:59.000Z

16

Pulsed DD Neutron Generator Measurements for HEU Oxide Fuel Pins Using Liquid Scintillators with Pulse Shape Discrimination  

E-Print Network [OSTI]

measurements have been performed on high-enriched uranium (HEU) oxide fuel pins and depleted uranium metal

Pennycook, Steve

17

Evaluating two experimental approaches for measuring ecosystem carbon oxidation state and oxidative ratio  

E-Print Network [OSTI]

tissue construction cost from heat of combustion and organicanalysis, and (2) heat of combustion (DH c ) measured bymeasurement of DH c (heat of combustion) and %C, and (3) via

Masiello, C. A; Gallagher, M. E; Randerson, J. T; Deco, R. M; Chadwick, O. A

2008-01-01T23:59:59.000Z

18

Functionally Graded Cathodes for Solid Oxide Fuel Cells  

SciTech Connect (OSTI)

This DOE SECA project focused on both experimental and theoretical understanding of oxygen reduction processes in a porous mixed-conducting cathode in a solid oxide fuel cell (SOFC). Elucidation of the detailed oxygen reduction mechanism, especially the rate-limiting step(s), is critical to the development of low-temperature SOFCs (400 C to 700 C) and to cost reduction since much less expensive materials may be used for cell components. However, cell performance at low temperatures is limited primarily by the interfacial polarization resistances, specifically by those associated with oxygen reduction at the cathode, including transport of oxygen gas through the porous cathode, the adsorption of oxygen onto the cathode surface, the reduction and dissociation of the oxygen molecule (O{sub 2}) into the oxygen ion (O{sup 2-}), and the incorporation of the oxygen ion into the electrolyte. In order to most effectively enhance the performance of the cathode at low temperatures, we must understand the mechanism and kinetics of the elementary processes at the interfaces. Under the support of this DOE SECA project, our accomplishments included: (1) Experimental determination of the rate-limiting step in the oxygen reduction mechanism at the cathode using in situ FTIR and Raman spectroscopy, including surface- and tip-enhanced Raman spectroscopy (SERS and TERS). (2) Fabrication and testing of micro-patterned cathodes to compare the relative activity of the TPB to the rest of the cathode surface. (3) Construction of a mathematical model to predict cathode performance based on different geometries and microstructures and analyze the kinetics of oxygen-reduction reactions occurring at charged mixed ionic-electronic conductors (MIECs) using two-dimensional finite volume models with ab initio calculations. (4) Fabrication of cathodes that are graded in composition and microstructure to generate large amounts of active surface area near the cathode/electrolyte interface using a novel combustion chemical vapor deposition (CCVD) technique. (5) Application of advanced quantum chemical calculations to interpret measured spectroscopic information, as well as to guide design of high efficient cathode materials.

YongMan Choi; Meilin Liu

2006-09-30T23:59:59.000Z

19

Redox Bias in Loss on Ignition Moisture Measurement for Relatively Pure Plutonium-Bearing Oxide Materials  

SciTech Connect (OSTI)

This paper evaluates potential analytical bias in application of the Loss on Ignition (LOI) technique for moisture measurement to relatively pure (plutonium assay of 80 wt.% or higher) oxides containing uranium that have been stabilized according to stabilization and storage standard DOE-STD-3013-2000 (STD- 3013). An immediate application is to Rocky Flats (RF) materials derived from high-grade metal hydriding separations subsequently treated by multiple calcination cycles. Specifically evaluated are weight changes due to oxidation/reduction of multivalent impurity oxides that could mask true moisture equivalent content measurement. Process knowledge and characterization of materials representing complex-wide materials to be stabilized and packaged according to STD-3013, and particularly for the immediate RF target stream, indicate that oxides of uranium, iron and gallium are the only potential multivalent constituents expected to be present above 0.5 wt.%. The evaluation show s that of these constituents, with few exceptions, only uranium oxides can be present at a sufficient level to produce weight gain biases significant with respect to the LOI stability test. In general, these formerly high-value, high-actinide content materials are reliably identifiable by process knowledge and measurement. Significant bias also requires that UO2 components remain largely unoxidized after calcination and are largely converted to U3O8 during LOI testing at only slightly higher temperatures. Based on well-established literature, it is judged unlikely that this set of conditions will be realized in practice. We conclude that it is very likely that LOI weight gain bias will be small for the immediate target RF oxide materials containing greater than 80 wt.% plutonium plus a much smaller uranium content. Recommended tests are in progress to confirm these expectations and to provide a more authoritative basis for bounding LOI oxidation/reduction biases. LOI bias evaluation is more difficult for lower purity materials and for fuel-type uranium-plutonium oxides. However, even in these cases testing may show that bias effects are manageable.

Eller, P. G.; Stakebake, J. L.; Cooper, T. D.

2002-02-26T23:59:59.000Z

20

Pulsed D-D Neutron Generator Measurements of HEU Oxide Fuel Pins  

SciTech Connect (OSTI)

Pulsed neutron interrogation measurements have been performed on highly enriched uranium (HEU) oxide fuel pins and depleted uranium (DU) metal using a D-D neutron generator (2x10{sup 6} neutrons-s{sup -1}) and moderated {sup 3}He tubes at the Idaho National Laboratory Power Burst Facility. These measurements demonstrate the ability to distinguish HEU from DU by coincidence counting using a pulsed source. The amount of HEU measured was 8 kg in a sealed 55-gallon drum compared to 31 kg of DU. Neutron events were counted during and after the pulse with the Nuclear Materials Identification System (NMIS) and used to calculate the neutron coincidence time distributions. Passive measurements were also performed for comparison with the pulsed measurements. This paper presents the neutron coincidence time distribution and Feynman variance results from the measurements.

McConchie, Seth; Hausladen, Paul; Mihalczo, John [Oak Ridge National Laboratory, 1 Bethel Valley Road, P.O. Box 2008, Oak Ridge, TN 37831 (United States); Blackburn, Brandon; Chichester, David [Idaho National Laboratory, 2525 North Fremont Avenue, P.O. Box 1625, Idaho Falls, ID 83415 (United States)

2009-03-10T23:59:59.000Z

Note: This page contains sample records for the topic "measures miec oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Pulsed D-D Neutron Generator Measurements of HEU Oxide Fuel Pins  

SciTech Connect (OSTI)

Pulsed neutron interrogation measurements have been performed on highly enriched uranium (HEU) oxide fuel pins and depleted uranium (DU) metal using a D-D neutron generator (2 x 10{sup 6} neutrons-s{sup -1}) and moderated {sup 3}He tubes at the Idaho National Laboratory Power Burst Facility. These measurements demonstrate the ability to distinguish HEU from DU by coincidence counting using a pulsed source. The amount of HEU measured was 8 kg in a sealed 55-gallon drum compared to 31 kg of DU. Neutron events were counted during and after the pulse with the Nuclear Materials Identification System (NMIS) and used to calculate the neutron coincidence time distributions. Passive measurements were also performed for comparison with the pulsed measurements. This paper presents the neutron coincidence distribution and Feynman variance results from the measurements.

McConchie, Seth M [ORNL] [ORNL; Hausladen, Paul [ORNL] [ORNL; Mihalczo, John T [ORNL] [ORNL; Blackburn, Brandon [Idaho National Laboratory (INL)] [Idaho National Laboratory (INL); Chichester, David [Idaho National Laboratory (INL)] [Idaho National Laboratory (INL)

2009-01-01T23:59:59.000Z

22

Acid strength of silica-supported oxide catalysts studied by microcalorimetric measurements of pyridine adsorption  

SciTech Connect (OSTI)

Microcalorimetric measurements of the differential heat of pyridine adsorption were used to probe the distribution of acid strength on a series of silica-supported oxide catalysts. Depositing oxides of the following cations onto silica increased the acid strength of the catalyst: Ga{sup 3{plus}}, Zn{sup 2{plus}}, Al{sup 3{plus}}, Fe{sup 3{plus}}, Fe{sup 2{plus}}, Mg{sup 2{plus}}, and Sc{sup 3{plus}}. The acid strength distribution curves for the supported oxide samples showed either two or three regions of constant heat of adsorption while silica had an energetically homogeneous surface. The Ga, Al, and Sc samples were found to have both Bronsted and Lewis acidity while the remaining samples showed only Lewis acidity. Incremental adsorption of pyridine indicated that the initial region of highest heat corresponds to strong Lewis acidity while intermediate heats seemed to be due to weaker Lewis acid sites or a combination of Lewis and Bronsted acid sites. The final region of lowest heat was due to H-bonded pyridine on silica. Estimates of the entropies of adsorption were determined, providing information about the mobility of the adsorbed pyridine molecules. The initial differential heat of adsorption increases proportionally to the Sanderson electronegativity of the added oxide.

Cardona-Martinez, N.; Dumesic, J.A. (Univ. of Wisconsin, Madison (USA))

1991-02-01T23:59:59.000Z

23

Redox bias in loss of ignition moisture measurement for relatively pure plutonium-bearing oxide materials.  

SciTech Connect (OSTI)

This paper evaluates potential analytical bias in application of the Loss on Ignition (LOI) technique for moisture measurement to relatively pure (plutonium assay of 80 wt.% or higher) oxides containing uranium that have been stabilized according to stabilization and storage standard DOE-STD-3013-2000 (STD-3013). An immediate application is to Rocky Flats (RF) materials derived from highgrade metal hydriding separations subsequently treated by multiple calcination cycles. Specifically evaluated are weight changes due to oxidatiodreduction of multivalent impurity oxides that could mask true moisture equivalent content measurement. Process knowledge and characterization of materials representing complex-wide materials to be stabilized and packaged according to STD-3013, and particularly for the immediate RF target stream, indicate that oxides of uranium, iron and gallium are the only potential multivalent constituents expected to be present above 0.5 wt.%. The evaluation shows that of these constituents, with few exceptions, only uranium oxides can be present at a sufficient level to produce weight gain biases significant with respect to the LO1 stability test. In general, these formerly high-value, high-actinide content materials are reliably identifiable by process knowledge and measurement. Si&icant bias also requires that UO1 components remain largely unoxidized after calcination and are largely converted to U30s clsning LO1 testing at only slightly higher temperatures. Based on wellestablished literature, it is judged unlikely that this set of conditions will be realized in practice. We conclude that it is very likely that LO1 weight gain bias will be small for the immediate target RF oxide materials containing greater than 80 wt.% plutonium plus a much smaller uranium content. Recommended tests are in progress to confum these expectations and to provide a more authoritative basis for bounding LO1 oxidatiodreduction biases. LO1 bias evaluation is more difficult for lower purity materials and for fuel-type uranium-plutonium oxides. However, even in these cases testing may show that bias effects are manageable.

Eller, P. G. (Phillip Gary); Stakebake, J. L. (Jerry L.); Cooper, T. D. (Thruman D.)

2001-01-01T23:59:59.000Z

24

Improving clay content measurement in oxidic and volcanic ash soils of Hawaii by increasing dispersant concentration and ultrasonic energy levels  

Science Journals Connector (OSTI)

Abstract Quantifying clay content is a fundamental step in predicting and managing soil behaviors such as nutrient and water retention. However, clay measurements are underestimated when using standard methods of dispersion in soils rich in oxides and volcanic ash-derived non-crystalline minerals. Increasing levels of the chemical dispersant and ultrasonic energy are two simple techniques found to increase dispersion and clay measurements in temperate soils, but their effects are less known for oxidic and volcanic ash soils. In this study we investigated the effects of increasing dispersion concentration and ultrasonic energy on clay measurements for a range of oxidic and volcanic ash soils from Hawaii. While doubling and tripling the standard sodium hexametaphosphate concentration of 0.441 g L? 1 did not increase estimates of clay content, increasing levels of ultrasonic energy up to 1600 J mL? 1 significantly increased measured clay content for all oxide and volcanic ash soils. The response to ultrasonication was dependent on soil carbon, oxide content, and surface charge, with more energy needed to disperse soils higher in carbon, oxides, and positive charge. Scanning electron microscopy revealed damage to the sand fraction in some soils when ultrasonicated, but the extent of this damage was viewed as negligible. Porous sand-sized particles resembling pumice grains were also observed in some soils, suggesting that conventional particle size analysis and clay interpretations may not adequately describe surface related behaviors.

Joshua H.S. Silva; Jonathan L. Deenik; Russell S. Yost; Gregory L. Bruland; Susan E. Crow

2015-01-01T23:59:59.000Z

25

Role of Photoexcitation and Field Ionization in the Measurement of Accurate Oxide Stoichiometry by Laser-Assisted Atom Probe Tomography  

SciTech Connect (OSTI)

Pulsed lasers extend the high spatial and mass resolution of atom probe tomography (APT) to non-conducting materials, such as oxides. For prototypical metal oxide MgO, measured stoichiometry depends strongly upon pulse energy and applied voltage. Very low laser energies (0.02 pJ) and high electric fields yield optimal stoichiometric accuracy, attributed to the field-dependent ionization of photo-desorbed O or O2 neutrals. This emphasizes the importance of considering electronic excitations in APT analysis of oxides ionic materials.

Devaraj, Arun; Colby, Robert J.; Hess, Wayne P.; Perea, Daniel E.; Thevuthasan, Suntharampillai

2013-03-06T23:59:59.000Z

26

Use of high-temperature gas-tight electrochemical cells to measure electronic transport and thermodynamics in metal oxides  

SciTech Connect (OSTI)

By using a gas-tight electrochemical cell, the authors can perform high-temperature coulometric titration and measure electronic transport properties to determine the electronic defect structure of metal oxides. This technique reduces the time and expense required for conventional thermogravimetric measurements. The components of the gas-tight coulometric titration cell are an oxygen sensor, Pt/yttria stabilized zirconia (YSZ)/Pt, and an encapsulated metal oxide sample. Based on cell design, both transport and thermodynamic measurements can be performed over a wide range of oxygen partial pressures (pO{sub 2} = 10{sup {minus}35} to 1 atm). This paper describes the high-temperature gas-tight electrochemical cells used to determine electronic defect structures and transport properties for pure and doped-oxide systems, such as YSZ, doped and pure ceria (Ca-CeO{sub 2} and CeO{sub 2}), copper oxides, and copper-oxide-based ceramic superconductors, transition metal oxides, SrFeCo{sub 0.5}O{sub x}, and BaTiO{sub 3}.

Park, J.H.; Ma, B.; Park, E.T. [Argonne National Lab., IL (United States). Energy Technology Div.

1997-10-01T23:59:59.000Z

27

Measuring the Kinetics of the Reduction of Iron Oxide with Carbon Monoxide in a Fluidized Bed  

Science Journals Connector (OSTI)

Combusting a solid fuel in the presence of a metal oxide rather than air, chemical looping combustion, generates CO2suitable for sequestration and the reduced metal. For the case of iron, the reduced oxide can be...

C. D. Bohnt; J. P. Cleeton; C. M. Miiller…

2010-01-01T23:59:59.000Z

28

Evaluation and Comparison of Test Methods to Measure the Oxidation Stability of Neat Biodiesel  

SciTech Connect (OSTI)

The purpose of this project was to compare and evaluate several candidate test methods for evaluating oxidation stability of biodiesel.

Westbrook, S. R.

2005-11-01T23:59:59.000Z

29

Laser-saturated fluorescence of nitric oxide and chemiluminescence measurements in premixed ethanol flames  

SciTech Connect (OSTI)

In this study, nitric oxide laser-saturated fluorescence (LSF) measurements were acquired from premixed ethanol flames at atmospheric pressure in a burner. NO-LSF experimental profiles for fuel-rich premixed ethanol flames ({phi} = 1.34 and {phi} = 1.66) were determined through the excitation/detection scheme of the Q{sub 2}(26.5) rotational line in the A{sup 2}{sigma}{sup +} - X{sup 2}{pi} (0,0) vibronic band and {gamma}(0,1) emission band. A calibration procedure by NO doping into the flame was applied to establish the NO concentration profiles in these flames. Chemiluminescent emission measurements in the (0, 0) vibronic emission bands of the OH{sup *} (A{sup 2}{sigma}{sup +} - X{sup 2}{pi}) and CH{sup *}(A{sup 2}{delta} - X{sup 2}{pi}) radicals were also obtained with high spatial and spectral resolution for fuel-rich premixed ethanol flames to correlate them with NO concentrations. Experimental chemiluminescence profiles and the ratios of the integrated areas under emission spectra (A{sub CH*}/A{sub CH*}(max.) and A{sub CH*}/A{sub OH*}) were determined. The relationships between chemiluminescence and NO concentrations were established along the premixed ethanol flames. There was a strong connection between CH{sup *} radical chemiluminescence and NO formation and the prompt-NO was identified as the governing mechanism for NO production. The results suggest the optimum ratio of the chemiluminescence of two radicals (A{sub CH*}/A{sub OH*}) for NO diagnostic purposes. (author)

Marques, Carla S.T.; Barreta, Luiz G.; Sbampato, Maria E.; dos Santos, Alberto M. [Aerothermodynamic and Hypersonic Division, Institute of Advanced Studies - General Command of Aerospatial Technology, Rodovia dos Tamoios, km 5.5, 12228-001 Sao Jose dos Campos - SP (Brazil)

2010-11-15T23:59:59.000Z

30

Fundamental studies of perovskite related oxide thin films for oxygen electrocatalysis at intermediate temperatures  

E-Print Network [OSTI]

Discovering highly active and stable catalysts for electrochemical energy conversion and storage is essential to envision a new generation of renewable energy applications. Mixed ionic and electronic conductors (MIECs) ...

Lee, Dongkyu, Ph. D. Massachusetts Institute of Technology

2014-01-01T23:59:59.000Z

31

Hard X-ray Fluorescence Measurements of Heteroepitaxial Solid Oxide Fuel Cell Cathode Materials  

SciTech Connect (OSTI)

Commonly, SOFCs are operated at high temperatures (above 800°C). At these temperatures expensive housing is needed to contain an operating stack as well as coatings to contain the oxidation of the metallic interconnects. Lowering the temperature of an operating device would allow for more conventional materials to be used, thus lowering overall cost. Understanding the surface chemical states of cations in the surface of the SOFC cathode is vital to designing a system that will perform well at lower temperatures. The samples studied were grown by pulsed laser deposition (PLD) at the Environmental Molecular Sciences Laboratory (EMSL) at Pacific Northwest National Laboratory (PNNL). 20% strontium doped lanthanum manganite (LSM-20) was grown on YSZ and NGO (neodymium gallate). The films on YSZ have a fiber texture. LSM-20 on NGO is heteroepitaxial. Lanthanum strontium cobalt ferrite (LSCF-6428) films were grown on LAO and YSZ with a GDC barrier layer. Total X-ray Reflection Fluorescence (TXRF) was used to depth profile the samples. In a typical experiment, the angle of the incident beam is varied though the critical angle. Below the critical angle, the x-ray decays as an evanescent wave and will only penetrate the top few nanometers. TXRF experiments done on LSM films have suggested strontium segregates to the surface and form strontium enriched nanoparticles (1). It should be pointed out that past studies have focused on 30% strontium A-site doping, but this project uses 20% strontium doped lanthanum manganite. XANES and EXAFS data were taken as a function of incoming angle to probe composition as a function of depth. XANES spectra can be difficult to analyze fully. For other materials density functional theory calculations compared to near edge measurements have been a good way to understand the 3d valence electrons (2).

Davis, Jacob N.; Miara, Lincoln J.; Saraf, Laxmikant V.; Kaspar, Tiffany C.; Gopalan, Srikanth; Pal, Uday B.; Woicik, Joseph C.; Basu, Soumendra N.; Ludwig, Karl F.

2012-12-01T23:59:59.000Z

32

Measurement of Nitric Oxide Production from Lymphatic Entothelial Cells Under Mechanical Stimuli  

E-Print Network [OSTI]

mechanisms to pump lymph. Intrinsic pumping involves the active contraction of vessels, a phenomenon that is regulated in part by nitric oxide (NO) produced by lymphatic endothelial cells (LECs). NO production by arterial endothelial cells has been shown...

Jafarnejad, Mohammad 1987-

2012-11-16T23:59:59.000Z

33

Two-photon nitric oxide laser-induced fluorescence measurements in a diesel engine  

Science Journals Connector (OSTI)

A two-photon nitric oxide (NO) laser-induced fluorescence (LIF) technique was developed and applied to study in-cylinder diesel combustion. The technique prevents many problems...

Martin, Glen C; Mueller, Charles J; Lee, Chia-Fon F

2006-01-01T23:59:59.000Z

34

Chemiluminescence and Ignition Delay Time Measurements of C9H20 Oxidation in O2-Ar Behind Reflected Shock Waves  

E-Print Network [OSTI]

CHEMILUMINESCENCE AND IGNITION DELAY TIME MEASUREMENTS OF C9H20 OXIDATION IN O2-Ar BEHIND REFLECTED SHOCK WAVES A Thesis by BRANDON MICHAEL ROTAVERA Submitted to the Office of Graduate Studies of Texas A&M University... WAVES A Thesis by BRANDON MICHAEL ROTAVERA Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE Approved by: Chair of Committee, Eric L...

Rotavera, Brandon

2011-02-22T23:59:59.000Z

35

Lithium intercalation in sputter deposited antimony-doped tin oxide thin films: Evidence from electrochemical and optical measurements  

SciTech Connect (OSTI)

Transparent conducting oxides are used as transparent electrical contacts in a variety of applications, including in electrochromic smart windows. In the present work, we performed a study of transparent conducting antimony-doped tin oxide (ATO) thin films by chronopotentiometry in a Li{sup +}-containing electrolyte. The open circuit potential vs. Li was used to investigate ATO band lineups, such as those of the Fermi level and the ionization potential, as well as the dependence of these lineups on the preparation conditions for ATO. Evidence was found for Li{sup +} intercalation when a current pulse was set in a way so as to drive ions from the electrolyte into the ATO lattice. Galvanostatic intermittent titration was then applied to determine the lithium diffusion coefficient within the ATO lattice. The electrochemical density of states of the conducting oxide was studied by means of the transient voltage recorded during the chronopotentiometry experiments. These measurements were possible because, as Li{sup +} intercalation took place, charge compensating electrons filled the lowest part of the conduction band in ATO. Furthermore, the charge insertion modified the optical properties of ATO according to the Drude model.

Montero, J., E-mail: jose.montero@angstrom.uu.se; Granqvist, C. G.; Niklasson, G. A. [Department of Engineering Sciences, The A°ngström Laboratory, Uppsala University, P.O. Box 534, SE-751 21 Uppsala (Sweden); Guillén, C.; Herrero, J. [Department of Energy, Ciemat, Avda. Complutense 40, Ed. 42, E-28040 Madrid (Spain)

2014-04-21T23:59:59.000Z

36

Microsensor Measurements of Sulfate Reduction and Sulfide Oxidation in Compact Microbial Communities of Aerobic Biofilms  

Science Journals Connector (OSTI)

...studied by measuring concentration...simple one-dimensional diffusion...oxic-anoxic interface, although...technique for measuring sulfate reduction...20 C) in standard pH buffers...checked for by measuring several microprofiles...biofilm-water interface and through...law of one-dimensional diffusion...

Michael Kühl; Bo Barker Jørgensen

1992-04-01T23:59:59.000Z

37

Raman spectroscopic measurement of oxidation in supercritical water. 2: Conversion of isopropyl alcohol to acetone  

SciTech Connect (OSTI)

The oxidation of isopropyl alcohol in supercritical water has been investigated using Raman spectroscopy. Results for species concentration as a function of residence-time are presented for temperatures ranging from 400 to 480 C at constant pressure, 24.4 {+-} 0.3 MPa, and constant equivalence ratio, 0.88 {+-} 0.0. Acetone has been identified as the principal intermediate formed and subsequently destroyed, during the oxidation process. By assuming first-order kinetics for the destruction of both isopropyl alcohol and acetone, effective first-order rate constants have been determined from fits of the experimental data. Assuming Arrhenius behavior, the fits yield rate constants for isopropyl alcohol, k{sub eff,ipa} = 3.255 {times} 10{sup 22}(s{sup {minus}1}) exp [{minus}301.1 (kJ/mol)/RT], and for acetone, k{sub eff,ace} = 1.948 {times} 10{sup 10}(s{sup {minus}1}) exp[{minus}137.7(kJ/mol)/RT]. These results indicate that for temperatures greater than 425 C, the destruction of isopropyl alcohol proceeds faster than that of acetone.

Hunter, T.B.; Rice, S.F.; Hanush, R.G. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility] [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility

1996-11-01T23:59:59.000Z

38

High Temperture Ceramic Fuel Cell Measurement and Diagnostics for Application to Solid Oxide Fuel Cell Systems  

SciTech Connect (OSTI)

This paper is the result of an extensive literature review and technology evaluation, performed to determine the status of sensors and measurement technologies.

Koehler, Theresa M.; Jarrell, Donald B.; Bond, Leonard J.

2001-10-29T23:59:59.000Z

39

On-Board Measurement of Ammonia and Nitrous Oxide Using Feedback...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Resonance and Low Pressure Sampling A first set of results has found that LASAR and VLPS data in the laboratory closely correlate with real-time, in-use measurement of NH3 and NO...

40

Neurochemical Measurements in Rodents that Model Huntingtion's Disease and Oxidative Stress  

E-Print Network [OSTI]

voltammetry to measure dopamine release and reserve pool dopamine in genetically and chemically altered rodents that model HD. Genetic HD model mice and rats (R6/1 mice, R/2 mice, and HDtg rats) showed an age-dependent decrease in dopamine release...

Ortiz, Andrea Naomi

2011-05-31T23:59:59.000Z

Note: This page contains sample records for the topic "measures miec oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Relation between surface adsorption states and emf in a solid electrolyte concentration cell during carbon monoxide oxidation on platinum studied by local current measurement  

SciTech Connect (OSTI)

The importance of measuring adsorption during surface catalysis has been emphasized often. This is true for the oxidation of carbon monoxide on a platinum surface. Surface adsorption states during the reaction under steady states can be learned from electromotive force (emf) measurement with appropriate assumptions. Two mechanisms for emf generation have been proposed, one is that only oxygen activity generates emf, the other is that both oxygen and CO adsorption generates emf.

Okamoto, H.; Kawamura, G.; Kudo, T.

1984-04-01T23:59:59.000Z

42

Mechanical, Electrical, and Optical Properties of (Pr,Ce)O[subscript 2] Solid Solutions: Kinetic Studies  

E-Print Network [OSTI]

Praseodymium doped cerium oxide (PCO) shows mixed ionic and electronic conducting (MIEC) characteristics at relatively high pO2 (e.g. air) and enhanced oxygen storage capacity (OSC), of interest for solid oxide fuel cell ...

Chen, Di

43

Electron Energy-Loss Safe-Dose Limits for Manganese Valence Measurements in Environmentally Relevant Manganese Oxides  

E-Print Network [OSTI]

19717-1303, United States § U.S. Army Engineer Research & Development Center, 3909 Halls Ferry Road are among the strongest mineral oxidants in the environment and impose significant influence on mobility. INTRODUCTION Mn exists in the 2+, 3+, and 4+ valence states in natural environment and, most of the time, as Mn

Sparks, Donald L.

44

High-Precision Measurements of [superscript 33]S and [superscript 34]S Fractionation during SO[subscript 2] Oxidation Reveal Causes of Seasonality in SO[subscript 2] and Sulfate Isotopic Composition  

E-Print Network [OSTI]

This study presents high-precision isotope ratio-mass spectrometric measurements of isotopic fractionation during oxidation of SO[subscript 2] by OH radicals in the gas phase and H[subscript 2]O[subscript 2] and transition ...

Harris, Eliza

45

Development of All-Solid-State Sensors for Measurement of Nitric Oxide and Ammonia Concentrations by Optical Absorption in Particle-Laden Combustion Exhaust Streams  

SciTech Connect (OSTI)

An all-solid-state continuous-wave (cw) laser system for ultraviolet absorption measurements of the nitric oxide (NO) molecule has been developed and demonstrated. For the NO sensor, 250 nW of tunable cw ultraviolet radiation is produced by sum-frequency-mixing of 532-nm radiation from a diode-pumped Nd:YAG laser and tunable 395-nm radiation from an external cavity diode laser (ECDL). The sum-frequency-mixing process occurs in a beta-barium borate crystal. The nitric oxide absorption measurements are performed by tuning the ECDL and scanning the sum-frequency-mixed radiation over strong nitric oxide absorption lines near 226 nm. In Year 1 of the research, the nitric oxide sensor was used for measurements in the exhaust of a coal-fired laboratory combustion facility. The Texas A&M University boiler burner facility is a 30 kW (100,000 Btu/hr) downward-fired furnace with a steel shell encasing ceramic insulation. Measurements of nitric oxide concentration in the exhaust stream were performed after modification of the facility for laser based NOx diagnostics. The diode-laser-based ultraviolet absorption measurements were successful even when the beam was severely attenuated by particulate in the exhaust stream and window fouling. Single-laser-sweep measurements were demonstrated with an effective time resolution of 100 msec, limited at this time by the scan rate of our mechanically tuned ECDL system. In Year 2, the Toptica ECDL in the original system was replaced with a Sacher Lasers ECDL. The mode-hop-free tuning range and tuning rate of the Toptica ECDL were 25 GHz and a few Hz, respectively. The mode-hop-free tuning range and tuning rate of the Sacher Lasers ECDL were 90 GHz and a few hundred Hz, respectively. The Sacher Lasers ECDL thus allows us to scan over the entire NO absorption line and to determine the absorption baseline with increased accuracy and precision. The increased tuning rate is an advantage in that data can be acquired much more rapidly and the absorption measurements are less susceptible to the effects of transient fluctuations in the properties of the coal combustor exhaust stream. Gas cell measurements were performed using the NO sensor with the new ECDL, and a few spectra were acquired from the coal exhaust stream. However, the laser diode in the new ECDL failed during the coal combustor tests. In Year 3, however, we obtained a new GaN laser diode for our ECDL system, installed it, and completed an extensive series of measurements in the Texas A&M coal-fired laboratory combustion facility. The combustor was operated with coal and coal/biomass as fuels, with and without reburn, and with and without ammonia injection. Several different fuel equivalence ratios were investigated for each operating condition.

Jerald A. Caton; Kalyan Annamalai; Robert P. Lucht

2006-12-31T23:59:59.000Z

46

Correlating the NMR self-diffusion and relaxation measurements with ionic conductivity in polymer electrolytes composed of cross-linked poly(ethylene oxide-propylene oxide) doped with LiN(SO 2 CF 3 ) 2  

Science Journals Connector (OSTI)

A solvent-free solid-polymer electrolyte based on a cross-linked poly(ethylene oxide-propylene oxide) random copolymer doped with LiN(SO 2 CF 3 ) 2 was studied using multinuclear NMR and ionic conductivity. The NMR spin-lattice relaxation times T 1 of the bulk polymer ( 1 H ) the lithium ion ( 7 Li ) and the anion ( 19 F ) were analyzed using single exponential analysis above the glass transition temperatures. Since the temperature dependent 1 H and 7 Li NMR T 1 values had minima the reorientational correlation times were obtained for the segmental motion of the CH 2 CH 2 O/ CH 2 CH ( CH 3 ) O moiety of the bulk polymer and the hopping motion of the lithium ions correlated with the segmental motion. The spin–spin relaxation of the anion signals appeared single exponential with respect to time whereas that of the polymer and the lithium echo signals were at least bi-exponential. Since both the spin-lattice and spin–spin relaxation of the anion indicated a single component the self-diffusion coefficients D were measured using 19 F pulsed-gradient spin-echo (PGSE) NMR measurements. Although the PGSE attenuation data appeared single exponential at each value of the separation between the gradient pulses ? the measured D values had a ? -dependence. Phenomenologically the anion diffuses quicker in a shorter range and the activation energy of the shorter-time diffusion is smaller than that of the longer-time diffusion. The apparent self-diffusion coefficients became smaller for longer ? and approached a constant when ? was longer than 0.05 s. The mean square displacements of the anion were inconsistent with standard diffusion models including “anomalous diffusion” as found for a neutral particle diffusing in a fractal network [i.e. ?r 2 (?)??? ? with ?<1(??2/d w where d w is the random walk fractal dimension)]. The apparent diffusion coefficients of the lithium ions at ?=0.02? s are almost independent of temperature and smaller than the corresponding diffusion coefficients of the anion. Since the activation energy of the anion determined for ? longer than 0.05 s correlates well with those obtained from the ionic conductivity the ion conduction in the solid-polymer medium is driven mainly by fast transfer of the anions.

Kikuko Hayamizu; Yuichi Aihara; William S. Price

2000-01-01T23:59:59.000Z

47

Measurement  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

localization that limits the present measurements. The knowledge thus gained will have input not only to fusion research, but to may ques- tions of basic plasma physics....

48

Measurement  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in the Department of Physics & Astronomy. Chapel Hill 2005 Approved: A. E. Champagne, Advisor J. C. Blackmon, Reader C. Iliadis, Reader ABSTRACT Ryan P. Fitzgerald: Measurement of...

49

Time-Resolved Quantitative Measurement of OH HO2 and CH2O in Fuel Oxidation Reactions by High Resolution IR Absorption Spectroscopy.  

SciTech Connect (OSTI)

Combined with a Herriott-type multi-pass slow flow reactor, high-resolution differential direct absorption spectroscopy has been used to probe, in situ and quantitatively, hydroxyl (OH), hydroperoxy (HO 2 ) and formaldehyde (CH 2 O) molecules in fuel oxidation reactions in the reactor, with a time resolution of about 1 micro-second. While OH and CH 2 O are probed in the mid-infrared (MIR) region near 2870nm and 3574nm respectively, HO 2 can be probed in both regions: near-infrared (NIR) at 1509nm and MIR at 2870nm. Typical sensitivities are on the order of 10 10 - 10 11 molecule cm -3 for OH at 2870nm, 10 11 molecule cm -3 for HO 2 at 1509nm, and 10 11 molecule cm -3 for CH 2 O at 3574nm. Measurements of multiple important intermediates (OH and HO 2 ) and product (CH 2 O) facilitate to understand and further validate chemical mechanisms of fuel oxidation chemistry.

Huang, Haifeng; Rotavera, Brandon; Taatjes, Craig A.

2014-08-01T23:59:59.000Z

50

An improved characterization method for international accountancy measurements of fresh and irradiated mixed oxide (MOX) fuel: helping achieve continual monitoring and safeguards through the fuel cycle  

SciTech Connect (OSTI)

Nuclear fuel accountancy measurements are conducted at several points through the nuclear fuel cycle to ensure continuity of knowledge (CofK) of special nuclear material (SNM). Non-destructive assay (NDA) measurements are performed on fresh fuel (prior to irradiation in a reactor) and spent nuclear fuel (SNF) post-irradiation. We have developed a fuel assembly characterization system, based on the novel concept of 'neutron fingerprinting' with multiplicity signatures to ensure detailed CofK of nuclear fuel through the entire fuel cycle. The neutron fingerprint in this case is determined by the measurement of the various correlated neutron signatures, specific to fuel isotopic composition, and therefore offers greater sensitivity to variations in fissile content among fuel assemblies than other techniques such as gross neutron counting. This neutron fingerprint could be measured at the point of fuel dispatch (e.g. from a fuel fabrication plant prior to irradiation, or from a reactor site post-irradiation), monitored during transportation of the fuel assembly, and measured at a subsequent receiving site (e.g. at the reactor site prior to irradiation, or reprocessing facility post-irradiation); this would confirm that no unexpected changes to the fuel composition or amount have taken place during transportation and/ or reactor operations. Changes may indicate an attempt to divert material for example. Here, we present the current state of the practice of fuel measurements for both fresh mixed oxide (MOX) fuel and SNF (both MOX and uranium dioxide). This is presented in the framework of international safeguards perspectives from the US and UK. We also postulate as to how the neutron fingerprinting concept could lead to improved fuel characterization (both fresh MOX and SNF) resulting in: (a) assured CofK of fuel across the nuclear fuel cycle, (b) improved detection of SNM diversion, and (c) greater confidence in safeguards of SNF transportation.

Evans, Louise G [Los Alamos National Laboratory; Croft, Stephen [Los Alamos National Laboratory; Swinhoe, Martyn T [Los Alamos National Laboratory; Tobin, S. J. [Los Alamos National Laboratory; Menlove, H. O. [Los Alamos National Laboratory; Schear, M. A. [Los Alamos National Laboratory; Worrall, Andrew [U.K. NNL

2011-01-13T23:59:59.000Z

51

An improved characterization method for international accountancy measurements of fresh and irradiated mixed oxide (MOX) fuel: helping achieve continual monitoring and safeguards through the fuel cycle  

SciTech Connect (OSTI)

Nuclear fuel accountancy measurements are conducted at several points through the nuclear fuel cycle to ensure continuity of knowledge (CofK) of special nuclear material (SNM). Non-destructive assay (NDA) measurements are performed on fresh fuel (prior to irradiation in a reactor) and spent nuclear fuel (SNF) post-irradiation. We have developed a fuel assembly characterization system, based on the novel concept of 'neutron fingerprinting' with multiplicity signatures to ensure detailed CofK of nuclear fuel through the entire fuel cycle. The neutron fingerprint in this case is determined by the measurement of the various correlated neutron signatures, specific to fuel isotopic composition, and therefore offers greater sensitivity to variations in fissile content among fuel assemblies than other techniques such as gross neutron counting. This neutron fingerprint could be measured at the point of fuel dispatch (e.g. from a fuel fabrication plant prior to irradiation, or from a reactor site post-irradiation), monitored during transportation of the fuel assembly, and measured at a subsequent receiving site (e.g. at the reactor site prior to irradiation, or reprocessing facility post-irradiation); this would confirm that no unexpected changes to the fuel composition or amount have taken place during transportation and/or reactor operations. Changes may indicate an attempt to divert material for example. Here, we present the current state of the practice of fuel measurements for both fresh mixed oxide (MOX) fuel and SNF (both MOX and uranium dioxide). This is presented in the framework of international safeguards perspectives from the US and UK. We also postulate as to how the neutron fingerprinting concept could lead to improved fuel characterization (both fresh MOX and SNF) resulting in: (a) assured CofK of fuel across the nuclear fuel cycle, (b) improved detection of SNM diversion, and (c) greater confidence in safeguards of SNF transportation.

Evans, Louise G [Los Alamos National Laboratory; Croft, Stephen [Los Alamos National Laboratory; Swinhoe, Martyn T [Los Alamos National Laboratory; Tobin, S. J. [Los Alamos National Laboratory; Boyer, B. D. [Los Alamos National Laboratory; Menlove, H. O. [Los Alamos National Laboratory; Schear, M. A. [Los Alamos National Laboratory; Worrall, Andrew [U.K., NNL

2010-11-24T23:59:59.000Z

52

Characterization and analysis methods for the examination of the heterogeneous solid oxide fuel cell electrode microstructure: Part 2. Quantitative measurement of the microstructure and contributions to transport losses  

SciTech Connect (OSTI)

Advanced characterization and analysis of multifunctional materials, such as the materials found in heterogeneous solid oxide fuel cell (SOFC) electrode architectures, can help to provide a qualitative and quantitative understanding of how these structures respond to different manufacturing and operating practices. Dense, opaque materials, which have large X-ray mass absorption coefficients and features on sub-micrometer length scales, can make characterization difficult. Advances in tomographic X-ray imaging can permit this level of detailed characterization, and complement stereographic scanning electron microscope measurements that have also been reported. In this second part of a two-part study, details regarding quantitative characterization methods that have been used to examine the SOFC anode microstructure are reported. The detailed formulation and validation of a phase size distributions for the three constitutive phases, as well as resistive loss microstructure-induced resistive loss distributions in the nickel (Ni) and yttria-stabilized zirconia (YSZ) phases are provided in this section.

Grew, Kyle N.; Peracchio, Aldo A.; Chiu, W. K. S.

2010-01-01T23:59:59.000Z

53

Lactose oxidation kinetics with oxygen in catalyst-solution-gas three-phase system with simultaneous electrical potential measurement of supported gold catalyst  

Science Journals Connector (OSTI)

Lactose oxidation kinetics was studied on an supported gold catalyst with simultaneous control of catalyst potential. The experimental data were described well...

D. Yu. Murzin; E. V. Murzina; A. V. Tokarev…

2009-09-01T23:59:59.000Z

54

Characterization and Analysis Methods for the Examination of the Heterogeneous Solid Oxide Fuel Cell Electrode Microstructure, Part 1: Volumetric Measurements of the Heterogeneous Structure  

SciTech Connect (OSTI)

Advanced imaging and characterization methods have permitted the 3-D and phase-specific reconstruction of dense and opaque samples with features that have a length scale on the order of tens of nanometers and comprised of materials with large X-ray mass absorption coefficients. Engineered materials, like those found in solid oxide fuel cell (SOFC) electrodes, use complex materials that have often limited opportunities to perform 3-D characterization and analysis. Still, characterization and analysis methods are needed to better understand these structures and their functional impact. The development, verification, and validation of methods used by the authors for the characterization and analysis of the heterogeneous SOFC anode are discussed in this work. These methods include the measurement of the volume fractions of the individual phases, contiguity or volumetric connectivity, tortuosity, and interfacial properties. A second and complementary part of this work will examine quantitative methods that provide detailed descriptions of the structure and its relations to the transport processes that it must support. These efforts are intended to describe the formulation of methods developed to provide insight into the SOFC anode nano/microstructure.

Grew, Kyle N.; Peracchio, Aldo A.; Joshi, Abhijit S.; Izzo, Jr., John R.; Chiu, W. K. S.

2010-01-01T23:59:59.000Z

55

Oxidative Degradation of Monoethanolamine  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxidative Degradation of Monoethanolamine Oxidative Degradation of Monoethanolamine Susan Chi Gary T. Rochelle* (gtr@che.utexas.edu, 512-471-7230) The University of Texas at Austin Department of Chemical Engineering Austin, Texas 78712 Prepared for presentation at the First National Conference on Carbon Sequestration, Washington, DC, May 14-17, 2001 Abstract Oxidative degradation of monoethanolamine (MEA) was studied under typical absorber condition of 55°C. The rate of evolution of NH 3 , which was indicative of the overall rate of degradation, was measured continuously in a batch system sparged with air. Dissolved iron from 0.0001 mM to 1 mM yields oxidation rates from 0.37 to 2 mM/hr in MEA solutions loaded with 0.4 mole CO 2 / mole MEA. Ethylenediaminetetraacetic acid (EDTA) and N,N-bis(2- hydroxyethyl)glycine effectively decrease the rate of oxidation in the presence of iron by 40 to

56

Metal Oxides  

Science Journals Connector (OSTI)

Metal oxides are the class of materials having the widest application in gas sensors. This chapter presents information related to the application of various metal oxides in gas sensors designed on different p...

Ghenadii Korotcenkov

2013-01-01T23:59:59.000Z

57

On-Board Measurement of Ammonia and Nitrous Oxide Using Feedback Absorption Laser Spectroscopy Combined with Amplified Resonance and Low Pressure Sampling  

Broader source: Energy.gov [DOE]

A first set of results has found that LASAR and VLPS data in the laboratory closely correlate with real-time, in-use measurement of NH3 and NO under various driving conditions.

58

Oxidation of Propane by Doped Nickel Oxides  

Science Journals Connector (OSTI)

... present study, however, indicate that in the absence of excess oxygen, direct oxidation of propane by the oxide lattice can occur.

D. W. McKEE

1964-04-11T23:59:59.000Z

59

Isotope loss from exhaled moisture and correlation of multifrequency bioelectrical impedance to body fluid compartments measured by intravenous deuterium oxide and sodium bromide dilution in dogs  

E-Print Network [OSTI]

for this route of isotope loss was necessary. Sodium bromide concentrations at 90 minutes and 180 minutes were tested for statistical equivalency to determine if NaBr had equilibrated by 90 minutes. Finally, impedance measured with electrodes separated by 2...

Witten, Tiffani Tipton

2012-06-07T23:59:59.000Z

60

An Automated System for the Measurement of Nitrogen Oxides and Ozone Concentrations from a Passenger Aircraft:? Instrumentation and First Results of the NOXAR Project  

Science Journals Connector (OSTI)

Exhaust gas from the analyzer is drawn through a thermal ozone scrubber (ECO PHYSICS) and into the vacuum pump (P1 in Figures 1 and 3). ... The individual capacity of each one of the 110 W fans (2100 m3/h in free air) is sufficient to ensure that the rack will not overheat even if the other should malfunction. ... Photolysis rates were calculated for clear-sky conditions from all daytime NO and O3 measurements at solar zenith angles <85° using the STAR (system for transfer of atmospheric radiation) model (27). ...

Peter Dias-Lalcaca; Dominik Brunner; Walter Imfeld; Werner Moser; Johannes Staehelin

1998-09-04T23:59:59.000Z

Note: This page contains sample records for the topic "measures miec oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Electron Emission from Slightly Oxidized Depleted Uranium Generated by its Own Radioactivity Measured by Electron Spectroscopy, and Electron-Induced Dissociation and Ionization of Hydrogen Near its Surface.  

SciTech Connect (OSTI)

Energy dependent electron emission (counts per second) between zero and 1.4 keV generated by the natural reactivity of uranium was measured by an electrostatic spectrometer with known acceptance angle and acceptance area. The electron intensity decreases continuously with energy, but at different rates in different energy regimes, suggesting that a variety of processes may be involved in producing the observed electron emission. The spectrum was converted to energy dependent electron flux (e-/cm{sup 2} s) using the assumption that the emission has a cosine angular distribution. The flux decreased rapidly from {approx}10{sup 6}/cm{sup 2}s to {approx}10{sup 5}/cm{sup 2}s in the energy range from zero to 200 eV, and then more slowly from {approx}10{sup 5}/cm{sup 2}s to {approx}3*10{sup 4}/cm{sup 2} s in the range from 200 to 1400 eV. The energy dependent electron mean free path in gases together with literature cross sections for electron induced reactions were used to determine the number of ionization and dissociation reactions per cm{sup 2}s within the inelastic mean free path of electrons, and found to be about 1.3*10{sup 8}/cm{sup 2}s and 1.5*10{sup 7}/cm{sup 2}s, respectively, for hydrogen. An estimate of the number of ionization and dissociation reactions occurring within the total range, rather than the mean free path of electrons in gases resulted in 6.2*10{sup 9}/cm{sup 2}s and 1.3*10{sup 9}/cm{sup 2}s, respectively. The total energy flux carried by electrons from the surface is suspiciously close to the total possible energy generated by one gram of uranium. A likely source of error is the assumption that the electron emission has a cosine distribution. Angular distribution measurements of the electron emission would check that assumption, and actual measurement of the total current emanating from the surface are needed to confirm the value of the current calculated in section II. These results must therefore be used with caution - until they are confirmed by other measurements.

Siekhaus, W J; Nelson, A J

2011-10-26T23:59:59.000Z

62

Investigation of oxides formed in the corrosion of SUS-304 in high-temperature water through the measurement of evolved hydrogen and radiochemical analyses  

SciTech Connect (OSTI)

Corrosion behavior of SUS-304 at 280/sup 0/C in deaerated water has been traced both through measuring H/sub 2/ gas, concomitantly formed with corrosion, and through radiochemical analysis of the corrosion layers. The calculated H/sub 2/ yield based on the reaction, M + x.H/sub 2/O = MO /sub x/ + x.H/sub 2/ (M: iron, chromium, nickel, manganese, and cobalt), agreed reasonably well with the observed H/sub 2/ yields, showing that iron is mainly in a magnetite form and chromium is in a Cr(III) state. More than 85% of the corrosion layers were recovered by repeating ultrasonic cleaning and electrostripping processes. The residual fraction was rich in chromium and dissolved in the subsequent electropolishing process. The total corrosion increases with the reaction time, although the ''inner layer'' tends to stay almost constant at a longer reaction time. In some cases, both neutron irradiated and nonirradiated SUS coexisted. Mutual transfer of the elements from one SUS to the other has been examined.

Tachikawa, E.; Hoshi, M.; Nakashima, M.; Sagawa, C.; Yonezawa, C.

1984-04-01T23:59:59.000Z

63

Asphalt Oxidation Kinetics and Pavement Oxidation Modeling  

E-Print Network [OSTI]

Most paved roads in the United States are surfaced with asphalt. These asphalt pavements suffer from fatigue cracking and thermal cracking, aggravated by the oxidation and hardening of asphalt. This negative impact of asphalt oxidation on pavement...

Jin, Xin

2012-07-16T23:59:59.000Z

64

Density measurements Viscosity measurements  

E-Print Network [OSTI]

Density measurements Viscosity measurements Temperature measurements Pressure measurements Flow rate measurements Velocity measurements Sensors How to measure fluid flow properties ? Am´elie Danlos Ravelet Experimental methods for fluid flows: an introduction #12;Density measurements Viscosity

Ravelet, Florent

65

Increased Cytotoxicity of Oxidized Flame Soot  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Increased Cytotoxicity of Oxidized Flame Soot Increased Cytotoxicity of Oxidized Flame Soot Title Increased Cytotoxicity of Oxidized Flame Soot Publication Type Journal Article Year of Publication 2012 Authors Holder, Amara L., Brietta J. Carter, Regine Goth-Goldstein, Donald Lucas, and Catherine P. Koshland Journal Atmospheric Pollution Research Volume 3 Start Page 25 Issue 1 Pagination 25-31 Date Published 01/2012 Keywords health effects, ozone, soot, toxicity Abstract Combustion-generated particles released into the atmosphere undergo reactions with oxidants, which can change the particles' physiochemical characteristics. In this work, we compare the physical and chemical properties and cellular response of particles fresh from a flame with those oxidized by ozone and nitrogen dioxide. The reaction with ozone and nitrogen dioxide does not significantly modify the physical characteristics of the particles (primary particle size, fractal dimension, and surface area). However, oxidation affects the chemical characteristics of the particles, creating more oxygen and nitrogen containing functional groups, and increases their hydrophilicity. In addition, oxidized soot generates more reactive oxygen species, as measured by the dithiothreitol (DTT) assay. Furthermore, oxidized soot is 1.5-2 times more toxic than soot that was not reacted with ozone, but the inflammatory response, measured by interleukin-8 (IL-8) secretion, is unchanged. These results imply that combustion-generated particles released into the atmosphere will have an increased toxicity on or after high ozone days.

66

Oxidation of propylene over copper oxide catalysts  

E-Print Network [OSTI]

to the study of propylene oxidation. Dunlop (17) reported that small quantities of iron compounds substantially enhanced the catalytic activity of chromia-alumina catalysts with respect to propylene oxidation, Woodharn (72) has suggested that under... between 360 C and 430oC the rate of propane oxidation decreases as the teznperature is increased, and the rate of conversion to olefins, especially propylene, becomes progressively greater. Above 430 C the proportion of propane converted to ethylene in...

Billingsley, David Stuart

2012-06-07T23:59:59.000Z

67

Characterization of low-temperature microwave loss of thin aluminum oxide formed by plasma oxidation  

SciTech Connect (OSTI)

We report on the characterization of microwave loss of thin aluminum oxide films at low temperatures using superconducting lumped resonators. The oxide films are fabricated using plasma oxidation of aluminum and have a thickness of 5?nm. We measure the dielectric loss versus microwave power for resonators with frequencies in the GHz range at temperatures from 54 to 303?mK. The power and temperature dependence of the loss are consistent with the tunneling two-level system theory. These results are relevant to understanding decoherence in superconducting quantum devices. The obtained oxide films are thin and robust, making them suitable for capacitors in compact microwave resonators.

Deng, Chunqing, E-mail: cdeng@uwaterloo.ca; Otto, M.; Lupascu, A., E-mail: alupascu@uwaterloo.ca [Institute for Quantum Computing, Department of Physics and Astronomy, and Waterloo Institute for Nanotechnology, University of Waterloo, Waterloo, Ontario N2L 3G1 (Canada)

2014-01-27T23:59:59.000Z

68

Investigation of abnormal negative threshold voltage shift under positive bias stress in input/output n-channel metal-oxide-semiconductor field-effect transistors with TiN/HfO{sub 2} structure using fast I-V measurement  

SciTech Connect (OSTI)

This letter investigates abnormal negative threshold voltage shifts under positive bias stress in input/output (I/O) TiN/HfO{sub 2} n-channel metal-oxide-semiconductor field-effect transistors using fast I-V measurement. This phenomenon is attributed to a reversible charge/discharge effect in pre-existing bulk traps. Moreover, in standard performance devices, threshold-voltage (V{sub t}) shifts positively during fast I-V double sweep measurement. However, in I/O devices, V{sub t} shifts negatively since electrons escape from bulk traps to metal gate rather than channel electrons injecting to bulk traps. Consequently, decreasing pre-existing bulk traps in I/O devices, which can be achieved by adopting Hf{sub x}Zr{sub 1?x}O{sub 2} as gate oxide, can reduce the charge/discharge effect.

Ho, Szu-Han; Chen, Ching-En; Tseng, Tseung-Yuen [Department of Electronics Engineering, National Chiao Tung University, Hsinchu 300, Taiwan (China); Chang, Ting-Chang, E-mail: tcchang@mail.phys.nsysu.edu.tw; Lu, Ying-Hsin; Tsai, Jyun-Yu; Liu, Kuan-Ju [Department of Physics, National Sun Yat-Sen University, Kaohsiung 804, Taiwan (China); Cheng, Osbert; Huang, Cheng-Tung; Lu, Ching-Sen [Device Department, United Microelectronics Corporation, Tainan Science Park, Taiwan (China)

2014-03-17T23:59:59.000Z

69

Kinetics of Diesel Nanoparticle Oxidation  

Science Journals Connector (OSTI)

The oxidation rates in air of diesel nanoparticles sampled directly from the exhaust stream of a medium-duty diesel engine were measured over the temperature range of 800?1140 °C using online aerosol techniques. ... Particulate emission from diesel engines is currently a topic of great concern from both pollution and public health standpoints. ... In addition, the fundamental carbon-to-hydrogen ratio may be different in diesel particles as compared to the commonly used surrogates (15). ...

Kelly J. Higgins; Heejung Jung; David B. Kittelson; Jeffrey T. Roberts; Michael R. Zachariah

2003-03-25T23:59:59.000Z

70

Solid Oxide Fuel Cells  

Science Journals Connector (OSTI)

A Solid Oxide Fuel Cell (SOFC) is typically composed of two porous electrodes, interposed between an electrolyte made of a particular solid oxide ceramic material. The system originates from the work of Nernst...

Nigel M. Sammes; Roberto Bove; Jakub Pusz

2006-01-01T23:59:59.000Z

71

Characterization of metal oxide layers grown on CVD graphene  

SciTech Connect (OSTI)

Growth of a fully oxidized aluminum oxide layer with low surface roughness on graphene grown by chemical vapor deposition is demonstrated. This is accomplished by the deposition of a 0.2 nm thick titanium seed layer on the graphene prior to the deposition of the aluminum under ultra high vacuum conditions, which was subsequently oxidized. The stoichiometry and surface roughness of the oxide layers were measured for a range of titanium and aluminum depositions utilizing ex situ x-ray photoelectron spectrometry and atomic force microscopy. These fully oxidized films are expected to produce good dielectric layers for use in graphene based electronic devices.

Matsubayashi, Akitomo; Abel, Joseph; Prasad Sinha, Dhiraj; Lee, Ji Ung; LaBella, Vincent P. [College of Nanoscale Science and Engineering, University at Albany, SUNY, Albany, New York 12203 (United States)

2013-03-15T23:59:59.000Z

72

Sandia National Laboratories: Synchrotron photoionization measurements...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

photoionization measurements of fundamental autoignition reactions: Product formation in low-temperature isobutane oxidation Two CRF Papers Named "Distinguished" for 34th...

73

Investigation of Structural and Electronic Properties of Graphene Oxide  

SciTech Connect (OSTI)

The local atomic structure of graphene oxide has been probed using synchrotron radiations. Detailed investigations of recently proposed simplistic model of graphene oxide using x-ray absorption near edge spectroscopy have been performed. X-ray diffraction measurements and calculations indicate loss of coherence between graphene-like layers. However, larger in-plane structural coherence is understood to be present. Selected area electron diffraction measurements indicate the presence of graphitic regions in graphene oxide which is expected to produce interesting confinement effects in graphene oxide which could be important for the development of tunable electronic and photonic devices.

S Saxena; T Tyson; S Shukla; E Negusse; H Chen; J Bai

2011-12-31T23:59:59.000Z

74

Comparison of the Catalytic Oxidation Reaction on Graphene Oxide and Reduced Graphene Oxide  

E-Print Network [OSTI]

Comparison of the Catalytic Oxidation Reaction on Graphene Oxide and Reduced Graphene Oxide Laboratory (PAL), Pohang 790-784, Republic of Korea ABSTRACT: The capacities of graphene oxide (GO) and reduced graphene oxide (rGO) films grown on silicon substrate to cause the aniline to azobenzene oxidation

Kim, Sehun

75

Oxidation Resistant Graphite Studies  

SciTech Connect (OSTI)

The Very High Temperature Reactor (VHTR) Graphite Research and Development Program is investigating doped nuclear graphite grades exhibiting oxidation resistance. During a oxygen ingress accident the oxidation rates of the high temperature graphite core region would be extremely high resulting in significant structural damage to the core. Reducing the oxidation rate of the graphite core material would reduce the structural effects and keep the core integrity intact during any air-ingress accident. Oxidation testing of graphite doped with oxidation resistant material is being conducted to determine the extent of oxidation rate reduction. Nuclear grade graphite doped with varying levels of Boron-Carbide (B4C) was oxidized in air at nominal 740°C at 10/90% (air/He) and 100% air. The oxidation rates of the boronated and unboronated graphite grade were compared. With increasing boron-carbide content (up to 6 vol%) the oxidation rate was observed to have a 20 fold reduction from unboronated graphite. Visual inspection and uniformity of oxidation across the surface of the specimens were conducted. Future work to determine the remaining mechanical strength as well as graphite grades with SiC doped material are discussed.

W. Windes; R. Smith

2014-07-01T23:59:59.000Z

76

Surface oxidation of Permalloy thin films  

SciTech Connect (OSTI)

The chemical and magnetic structures of oxides on the surface of Permalloy Ni{sub 81}Fe{sub 19} films were investigated as functions of annealing time with x-ray and polarized neutron reflectometry. For annealing times of less than one hour, the oxide consisted of a 1.5-nm-thick layer of NiO on an Fe oxide layer that was in contact with Permalloy. The Fe oxide thickness increases with annealing time with a parabolic rate constant of 10{sup -18} cm{sup 2} s{sup -1} (for an annealing temperature of 373 K). The growth of the oxide layer is limited by the rate at which oxygen appears below the NiO layer. No portion of the oxide region was found to be ferromagnetically ordered for films annealed less than one hour. The growth of the Fe oxide region is well correlated with the measured increase of the second-order magnetic susceptibility for similarly prepared samples.

Fitzsimmons, M. R.; Crawford, T. M. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Silva, T. J. [National Institute of Standards and Technology, Boulder, Colorado 80303 (United States)

2006-01-01T23:59:59.000Z

77

Aromatics oxidation and soot formation in flames  

SciTech Connect (OSTI)

This project is concerned with the kinetics and mechanisms of aromatics oxidation and soot and fullerenes formation in flames. The scope includes detailed measurements of profiles of stable and radical species concentrations in low-pressure one-dimensional premixed flames. Intermediate species identifications and mole fractions, fluxes, and net reaction rates calculated from the measured profiles are used to test postulated reaction mechanisms. Particular objectives are to identify and to determine or confirm rate constants for the main benzene oxidation reactions in flames, and to characterize fullerenes and their formation mechanisms and kinetics.

Howard, J.B.; Pope, C.J.; Shandross, R.A.; Yadav, T. [Massachusetts Institute of Technology, Cambridge (United States)

1993-12-01T23:59:59.000Z

78

METAL OXIDE NANOPARTICLES  

SciTech Connect (OSTI)

This chapter covers the fundamental science, synthesis, characterization, physicochemical properties and applications of oxide nanomaterials. Explains fundamental aspects that determine the growth and behavior of these systems, briefly examines synthetic procedures using bottom-up and top-down fabrication technologies, discusses the sophisticated experimental techniques and state of the art theory results used to characterize the physico-chemical properties of oxide solids and describe the current knowledge concerning key oxide materials with important technological applications.

FERNANDEZ-GARCIA,M.; RODGRIGUEZ, J.A.

2007-10-01T23:59:59.000Z

79

Transition metal oxides deposited on rhodium and platinum: Surface chemistry and catalysis  

SciTech Connect (OSTI)

The surface chemistry and catalytic reactivity of transition metal oxides deposited on Rh and Pt substrates has been examined in order to establish the role of oxide-metal interactions in influencing catalytic activity. The oxides investigated included titanium oxide (TiOx), vanadium oxide (VOx), iron oxide (FeOx), zirconium oxide (ZrOx), niobium oxide (NbOx), tantalum oxide (TaOx), and tungsten oxide (WOx). The techniques used to characterize the sample included AES, XPS, LEED, TPD, ISS, and STM. After characterization of the surface in UHV, the sample was enclosed in an atmospheric reaction cell to measure the influence of the oxide deposits on the catalytic activity of the pure metal for CO and CO{sub 2} hydrogenation. The oxide deposits were found to strongly enhance the reactivity of the Rh foil. The rates of methane formation were promoted by up to 15 fold with the maximum in rate enhancement occurring at oxide coverages of approximately 0.5 ML. TiOx TaOx, and NbOx were the most effective promoters and were stable in the highest oxidation states during both reactions (compared to VOx, WOx, and FeOx). The trend in promoter effectiveness was attributed to the direct relationship between oxidation state and Lewis acidity. Bonding at the metal oxide/metal interface between the oxygen end of adsorbed CO and the Lewis acidic oxide was postulated to facilitate C-O bond dissociation and subsequent hydrogenation. 192 refs.

Boffa, A.B. [Univ. of California, Berkeley, CA (United States). Dept. of Chemistry; [Lawrence Berkeley Lab., CA (United States). Materials Sciences Div.

1994-07-01T23:59:59.000Z

80

Measurement-Measurement-  

E-Print Network [OSTI]

Internet Measurement- System A Measurement- System B Control System GPS Satellite GPS Satellite GPS Receiver GPS Receiver 2) measurement 3) data1) command Methodology for One-way IP Performance Measurement This paper proposes a methodology for measurement of one-way IP performance metrics such as one-way delay

Jeong, Jaehoon "Paul"

Note: This page contains sample records for the topic "measures miec oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Stabilized chromium oxide film  

DOE Patents [OSTI]

Stabilized air-oxidized chromium films deposited on high-power klystron ceramic windows and sleeves having a thickness between 20 and 150.ANG. are useful in lowering secondary electron emission yield and in avoiding multipactoring and window failure due to overheating. The ceramic substrate for the film is chosen from alumina, sapphire or beryllium oxide.

Garwin, Edward L. (Los Altos, CA); Nyaiesh, Ali R. (Palo Alto, CA)

1988-01-01T23:59:59.000Z

82

Stabilized chromium oxide film  

DOE Patents [OSTI]

Stabilized air-oxidized chromium films deposited on high-power klystron ceramic windows and sleeves having a thickness between 20 and 150A are useful in lowering secondary electron emission yield and in avoiding multipactoring and window failure due to overheating. The ceramic substrate for the film is chosen from alumina, sapphire or beryllium oxide.

Nyaiesh, A.R.; Garwin, E.L.

1986-08-04T23:59:59.000Z

83

Ethylene Oxide Explosions  

Science Journals Connector (OSTI)

... THE occasional occurrence of ethylene oxide explosions during the fumigation of dried fruit has led us to undertake a detailed ... yielded results somewhat like those for acetaldehyde1,2.. Cool flames can be initiated in ethylene oxide – air mixtures in the neighbourhood of 330° C. at atmospheric pressure. ...

J. H. BURGOYNE; F. A. BURDEN

1948-07-31T23:59:59.000Z

84

Stress dependent oxidation of sputtered niobium and effects on superconductivity  

SciTech Connect (OSTI)

We report on the suppression of room temperature oxidation of DC sputtered niobium films and the effects upon the superconductive transition temperature, T{sub c}. Niobium was sputter-deposited on silicon dioxide coated 150?mm wafers and permitted to oxidize at room temperature and pressure for up to two years. Resistivity and stress measurements indicate that tensile films greater than 400?MPa resist bulk oxidation with measurements using transmission electron microscope, electron dispersive X-ray spectroscopy, x-ray photoelectric spectroscopy, and secondary ion mass spectrometry confirming this result. Although a surface oxide, Nb{sub 2}O{sub 5}, consumed the top 6–10?nm, we measure less than 1 at. % oxygen and nitrogen in the bulk of the films after the oxidation period. T{sub c} measurements using a SQUID magnetometer indicate that the tensile films maintained a T{sub c} approaching the dirty superconductive limit of 8.4?K after two years of oxidation while maintaining room temperature sheet resistance. This work demonstrates that control over niobium film stress during deposition can prevent bulk oxidation by limiting the vertical grain boundaries ability to oxidize, prolonging the superconductive properties of sputtered niobium when exposed to atmosphere.

David Henry, M., E-mail: mdhenry@sandia.gov; Wolfley, Steve; Monson, Todd; Clark, Blythe G.; Shaner, Eric; Jarecki, Robert [Sandia National Labs, MESA Fabrication Facility PO Box 5800 MS 1084, Albuquerque, New Mexico 87185-1084 (United States)

2014-02-28T23:59:59.000Z

85

Diffraction from oxide confinement apertures in vertical-cavity lasers  

SciTech Connect (OSTI)

Direct measurement of scattered fields from oxide confinement apertures in vertical-cavity lasers is presented. Diffraction fringes associated with each transverse lasing mode are detected in the far field from devices with varying oxide aperture dimensions and with quantum efficiencies as high as 48{percent}. The diffracted pattern symmetries match the rectangular symmetry of the oxide apertures present in the devices and fringe locations are compared to Fraunhofer theory. The fraction of power diffracted from the lasing mode remains roughly constant as a function of relative pump rate, but is shown to depend on both transverse mode order and oxide aperture size. {copyright} {ital 1999 American Institute of Physics.}

Roos, P.A.; Carlsten, J.L. [Montana State University, Department of Physics, Bozeman, Montana 59717 (United States)] [Montana State University, Department of Physics, Bozeman, Montana 59717 (United States); Kilper, D.C. [University of North Carolina at Charlotte, Department of Physics, Charlotte, North Carolina 28223 (United States)] [University of North Carolina at Charlotte, Department of Physics, Charlotte, North Carolina 28223 (United States); Lear, K.L. [MicroOptical Devices Inc., 5601C Midway Park Pl. NE, Albuquerque, New Mexico 87109 (United States)] [MicroOptical Devices Inc., 5601C Midway Park Pl. NE, Albuquerque, New Mexico 87109 (United States)

1999-08-01T23:59:59.000Z

86

Phase-Transfer-Catalyzed Oxidations  

Science Journals Connector (OSTI)

Phase-transfer catalysis (PTC) offers many excellent opportunities for conducting oxidation reactions using inexpensive primary oxidants such as oxygen, sodium hypochlorite, hydrogen peroxide, electrooxidation...

Charles M. Starks; Charles L. Liotta; Marc E. Halpern

1994-01-01T23:59:59.000Z

87

Regenerative catalytic oxidation  

SciTech Connect (OSTI)

Currently Regenerative Thermal Oxidizers (R.T.O.`s) are an accepted technology for the control of volatile organic compounds (VOC`s) and hazardous air pollutants (HAP`s). This control technology, when introduced, offered substantial reductions in operating costs, especially auxiliary fuel requirements when compared to existing control technologies such as recuperative thermal and recuperative catalytic oxidizers. While these savings still exist, there is a demand for control of new and/or hybrid technologies, one of which is Regenerative Catalytic Oxidizers (R.C.O.`s). This paper will explore the development of regenerative catalytic oxidation from the theoretical stage through pilot testing through a commercial installation. The operating cost of R.C.O.`s will be compared to R.T.O.`s to verify the savings that are achievable through the use of regenerative catalytic oxidation. In the development of this technology, which is a combination of two (2) existing technologies, R.T.O.`s and catalysis, a second hybrid technology was explored and pilot tested. This is a combination R.C.O. for VOC and HAP control and simultaneous SCR (Selective Catalytic Reduction) for NOx (Oxides of Nitrogen) control. Based on the pilot and full scale testing, both regenerative catalytic oxidizers and systems which combine R.C.O. with SCR for both VOC and NOx reduction are economically viable and are in fact commercially available. 6 figs., 2 tabs.

Gribbon, S.T. [Engelhard Process Emission Systems, South Lyon, MI (United States)

1996-12-31T23:59:59.000Z

88

Oxidation of magnesium single crystals and evaporated films  

Science Journals Connector (OSTI)

The oxidation of (001) and (100) faces of pure magnesium single crystals at 2.5 mm Hg oxygen pressure was measured at 400°C and 440°C by means of an all-quartz, high vacuum microbalance. In a first approximation a parabolic oxidation law is observed. The oxidation rate on the basal plane is initially higher than on the prismatic plane. Electron diffraction patterns and photomicrographs indicate that the oxide has a preferred orientation on the basal plane, even for a thickness of about 1000 Å. The oxidation of evaporated magnesium films at room temperature was also investigated. After an induction period a logarithmic oxidation law is observed, where the limiting thickness is dependent on the oxygen pressure.

R.R Addiss Jr.

1963-01-01T23:59:59.000Z

89

A comprehensive kinetics model for CO oxidation during char combustion  

SciTech Connect (OSTI)

The most important parameter in representing energy feedback to a particle during char combustion concerns the oxidation of CO to CO/sub 2/. If substantial oxidation of CO occurs near a particle, then the greater heat of combustion for the complete oxidation of carbon to CO/sub 2/ (94.1 kcal/mole vs. 26.4 kcal/mole for oxidation to CO) is available for energy feedback mechanisms. ''Energy feedback'' is here defined as any situation in which an individual particle receives a significant fraction of its heat of combustion directly, through the localized oxidation of emitted combustible species, i.e. CO. Conversely, if the oxidation of CO does not occur near a particle, then energy feedback will occur only indirectly, through heating of the bulk gas. The primary reaction product at the particle surface during char combustion is generally considered to be CO, and the location of the subsequent CO oxidation zone plays a very important role in determining the particle temperature. Ayling and Smith performed experimental and modeling work which indicates that CO oxidation is not of major importance under the conditions they investigated, although they noted the need for improved accuracy in measuring char reactivities, as well as for better modeling of the gas phase CO oxidation kinetics. The modeling work presented in this paper attempts to develop an improved understanding of the boundary layer oxidation of CO through the use of a comprehensive set of kinetic expressions.

Haussmann, G.; Kruger, C.

1986-04-01T23:59:59.000Z

90

SOLID OXIDE PLANAR AND TUBULAR SOLID OXIDE FUEL  

E-Print Network [OSTI]

SOLID OXIDE PLANAR AND TUBULAR SOLID OXIDE FUEL CELLS Dynamic Simulation Approach Modular Approach · Parallel planes: PSOFC · Other: combustor, reformer Solid Oxide Fuel Cell Electrochemistry Cell Reactions · Slow pressure transients #12;Fuel Cell Assumptions · H2 electrochemically oxidized only · CO consumed

Mease, Kenneth D.

91

Cu- and Ag-modified cerium oxide catalysts for methane oxidation  

SciTech Connect (OSTI)

The catalytic activity of nanocrystalline doped ceria and Cu- and Ag-modified ceria for the complete oxidation of methane was studied in this work. The catalyst structure was studied by X-ray diffraction (XRD) and related to the availability of low-temperature oxygen species. Selected samples were also analyzed by STEM/EDX, HRTEM, and XPS. Temperature-programmed reduction (TPR) by H{sub 2} and CH{sub 4}, as well as oxygen chemisorption, measurements were used to characterize the different oxygen species present on the catalyst. La and Zr were used as dopants to modify the crystal size and reduction properties of ceria. Enhanced activity for the complete oxidation of methane is discussed in terms of ceria reducibility, crystal size, and formation of oxygen defects at the surface (extrinsic oxygen vacancies). Addition of transition metal oxides (CuO) or transition metals (Ag) improves the low-temperature oxidation activity of cerium oxide. The interaction of ceria with Ag and CuO is a strong function of the crystal size of ceria. In the presence of the transition metal or metal oxide, a small crystal size of ceria favors the formation of highly reducible oxygen species and enhances the methane oxidation activity.

Kundakovic, L.; Flytzani-Stephanopoulis, M. [Tufts Univ., Medford, MA (United States). Dept. of Chemical Engineering] [Tufts Univ., Medford, MA (United States). Dept. of Chemical Engineering

1998-10-01T23:59:59.000Z

92

Development of a New Chemiluminescence Detector for Sub-ppm Level Nitrous Oxide  

Science Journals Connector (OSTI)

......atmosphere (15) and sea water (7), sometimes...sub-ppm level atmospheric N2O without any...through a standard gas generator (Model SGGU-72...Lodger, Jr. Atmospheric ni- trious oxide...Measurement of atmospheric nitrous oxide using...oxide in air and water using a 5A molecular......

Shun Araki; Shigetaka Suzuki; Masaaki Yamada; Hiroshi Suzuki; Toshiyuki Hobo

1978-06-01T23:59:59.000Z

93

Uranium Oxide as a Highly Reflective Coating from 150-350 eV  

E-Print Network [OSTI]

of depleted uranium metal (less than 0.2% U-235). After sputtering, the uranium was allowed to oxidize1 Uranium Oxide as a Highly Reflective Coating from 150-350 eV Richard L. Sandberg, David D. Allred.byu.edu ABSTRACT We present the measured reflectances (beamline 6.3.2, ALS at LBNL) of naturally oxidized uranium

Hart, Gus

94

Syngas Oxidation Mechanism  

Science Journals Connector (OSTI)

A comprehensive analysis of synthesis gas (syngas) oxidation kinetics in wide ranges of temperature ... on the basis of the reaction mechanism of syngas ignition and combustion in air. A vast set of experimental ...

A. M. Starik; N. S. Titova; A. S. Sharipov…

2010-09-01T23:59:59.000Z

95

E-Print Network 3.0 - acetate-oxidizing obligate microaerophile...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

organisms recovered were in the family Geobacteraceae. MATERIALS... acceptor. Acetate oxidation was monitored by measuring the production of ... Source: Lovley, Derek - Department...

96

E-Print Network 3.0 - area metal-oxide-semiconductor electron...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

inversion layer mobility Joo-Hiuk Son,a) Seongtae... measured absorption of terahertz radiation pulses by metal-oxide-semiconductor MOS inversion layers... of the...

97

Nitric oxide inhibition of soot oxidation by oxygen atoms at 298/sup 0/Ktiation  

SciTech Connect (OSTI)

Nitric oxide is observed to inhibit the rate of soot oxidation by oxygen atoms at 298 K. Small amounts of added NO reduce the rates of production of CO/sub 2/ and CO by up to 35%. The authors show experimentally that NO is not reducing the gas phase O atom concentration. Thermal description mass spectrometry is used to measure the small adsorption of NO on the soot; this NO adsorption corresponds to 1.5% of the carbon atoms on the surface of the individual soot spheres. This inhibition is interpreted in terms of a relatively small number of reactive sites on the soot at which soot gasification occurs and which are effectively blocked by NO. When considered together with our previously reported work on oxidation of soot by oxygen atoms at 298 K, these results allow a partial mechanism to be formulated for this soot oxidation process.

Wicke, B.G.; Grady, K.A.

1987-01-01T23:59:59.000Z

98

Controlled CO preferential oxidation  

DOE Patents [OSTI]

Method is described for controlling the supply of air to a PROX (PReferential OXidation for CO cleanup) reactor for the preferential oxidation in the presence of hydrogen wherein the concentration of the hydrogen entering and exiting the PROX reactor is monitored, the difference there between correlated to the amount of air needed to minimize such difference, and based thereon the air supply to the PROX reactor adjusted to provide such amount and minimize such difference. 2 figs.

Meltser, M.A.; Hoch, M.M.

1997-06-10T23:59:59.000Z

99

Modeling of Diesel Oxidation Catalyst  

Science Journals Connector (OSTI)

Modeling of Diesel Oxidation Catalyst ... Optimization of hydrocarbon (HC) oxidation over a diesel oxidation catalyst (DOC) requires consideration of (i) HC gas diffusion into the catalyst layer, (ii) HC gas adsorption and desorption from catalyst sites, and (iii) kinetics of the oxidation reaction. ... Mutagenicity of Diesel Engine Exhaust Is Eliminated in the Gas Phase by an Oxidation Catalyst but Only Slightly Reduced in the Particle Phase ...

Yasushi Tanaka; Takashi Hihara; Makoto Nagata; Naoto Azuma; Akifumi Ueno

2005-09-30T23:59:59.000Z

100

Reference electrode for strong oxidizing acid solutions  

DOE Patents [OSTI]

A reference electrode for the measurement of the oxidation-reduction potentials of solutions is especially suitable for oxidizing solutions such as highly concentrated and fuming nitric acids, the solutions of nitrogen oxides, N.sub.2 O.sub.4 and N.sub.2 O.sub.5, in nitric acids. The reference electrode is fabricated of entirely inert materials, has a half cell of Pt/Ce(IV)/Ce(III)/70 wt. % HNO.sub.3, and includes a double-junction design with an intermediate solution of 70 wt. % HNO.sub.3. The liquid junctions are made from Corning No. 7930 glass for low resistance and negligible solution leakage.

Rigdon, Lester P. (Livermore, CA); Harrar, Jackson E. (Castro Valley, CA); Bullock, Sr., Jack C. (Pleasanton, CA); McGuire, Raymond R. (Brentwood, CA)

1990-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "measures miec oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Thermo-Oxidation of Tokamak Carbon Dust  

SciTech Connect (OSTI)

The oxidation of dust and flakes collected from the DIII-D tokamak, and various commercial dust specimens, has been measured at 350 ºC and 2.0 kPa O2 pressure. Following an initial small mass loss, most of the commercial dust specimens showed very little effect due to O2 exposure. Similarly, dust collected from underneath DIII-D tiles, which is thought to comprise largely Grafoil™ particulates, also showed little susceptibility to oxidation at this temperature. However, oxidation of the dust collected from tile surfaces has led to ~ 18% mass loss after 8 hours; thereafter, little change in mass was observed. This suggests that the surface dust includes some components of different composition and/or structure – possibly fragments of codeposited layers. The oxidation of codeposit flakes scraped form DIII-D upper divertor tiles showed an initial 25% loss in mass due to heating in vacuum, and the gradual loss of 30-38% mass during the subsequent 24 hours exposure to O2. This behavior is significantly different from that observed for the oxidation of thinner DIII-D codeposit specimens which were still adhered to tile surfaces, and this is thought to be related to the low deuterium content (D/C ~ 0.03 – 0.04) of the flakes.

J.W. Davis; B.W.N. Fitzpatrick; J.P. Sharpe; A.A. Haasz

2008-04-01T23:59:59.000Z

102

Oxidation kinetics of some nickel-based superalloy foils and electronic resistance of the oxide scale formed in air. Part 1  

SciTech Connect (OSTI)

Haynes 230, Inconel 625, Inconel 718, and Hastelloy X foil specimens were oxidized in air for several thousand hours in the temperature range of 800--1,100 C. The oxidation kinetics of alloys studied obeyed the parabolic rate law. Haynes 230 exhibited the slowest oxidation kinetics of the alloys studied. X-ray diffraction, scanning electron microscopy, and electron probe microanalysis (EPMA) were the principal characterization tools employed. Chromium oxide, Cr{sub 2}O{sub 3}, was the predominant oxide phase in the oxide scale of all alloys studied. Manganese chromate was also detected in the oxide scales of Haynes 230, Hastelloy X, and Inconel 625. EPMA showed that the concentration of Mn in the oxide scale was much higher than in the alloy, indicating selective oxidation of Mn. The electronic resistance of the oxide scale was measured in air at temperatures up to 800 C on samples oxidized in air for up to several thousand hours. The oxide scale on Haynes 230 exhibited the lowest area-specific resistance, consistent with its slower oxidation kinetics.

England, D.M.; Virkar, A.V.

1999-09-01T23:59:59.000Z

103

Effect of microstructure on air oxidation resistance of nuclear graphite  

SciTech Connect (OSTI)

Oxidation resistance in air of three grades of nuclear graphite with different structures was compared using a standard thermogravimetric method. Differences in the oxidation behavior have been identified with respect to both (i) the rate of oxidation in identical conditions and the derived apparent activation energy and pre-exponential factor and (ii) the penetration depth of the oxidant and the development of the oxidized layer. These differences were ascribed to structural differences between the three graphite grades, in particular the grain size and shape of the graphite filler, and the associated textural properties, such as total BET surface area and porosity distribution in the un-oxidized material. It was also found that the amount of strongly bonded surface oxygen complexes measured by thermodesorption significantly exceeds the amount afforded by the low BET surface area, and therefore low temperature oxygen chemisorption is not a reliable method for determining the amount of surface sites (re)active during air oxidation. The relationship between nuclear graphite microstructure and its oxidation resistance demonstrated in this work underlines the importance of performing comprehensive oxidation characterization studies of the new grades of nuclear graphite considered as candidates for very high temperature gas-cooled reactors.

Contescu, Cristian I [ORNL; Guldan, Tyler R [ORNL; Wang, Peng [ORNL; Burchell, Timothy D [ORNL

2012-01-01T23:59:59.000Z

104

Oxidation of Mercury in Products of Coal Combustion  

SciTech Connect (OSTI)

Laboratory measurements of mercury oxidation during selective catalytic reduction (SCR) of nitric oxide, simulation of pilot-scale measurements of mercury oxidation and adsorption by unburned carbon and fly ash, and synthesis of new materials for simultaneous oxidation and adsorption of mercury, were performed in support of the development of technology for control of mercury emissions from coal-fired boilers and furnaces. Conversion of gas-phase mercury from the elemental state to water-soluble oxidized form (HgCl{sub 2}) enables removal of mercury during wet flue gas desulfurization. The increase in mercury oxidation in a monolithic V{sub 2}O{sub 5}-WO{sub 3}/TiO{sub 2} SCR catalyst with increasing HCl at low levels of HCl (< 10 ppmv) and decrease in mercury oxidation with increasing NH{sub 3}/NO ratio during SCR were consistent with results of previous work by others. The most significant finding of the present work was the inhibition of mercury oxidation in the presence of CO during SCR of NO at low levels of HCl. In the presence of 2 ppmv HCl, expected in combustion products from some Powder River Basin coals, an increase in CO from 0 to 50 ppmv reduced the extent of mercury oxidation from 24 {+-} 3 to 1 {+-} 4%. Further increase in CO to 100 ppmv completely suppressed mercury oxidation. In the presence of 11-12 ppmv HCl, increasing CO from 0 to {approx}120 ppmv reduced mercury oxidation from {approx}70% to 50%. Conversion of SO{sub 2} to sulfate also decreased with increasing NH{sub 3}/NO ratio, but the effects of HCl and CO in flue gas on SO{sub 2} oxidation were unclear. Oxidation and adsorption of mercury by unburned carbon and fly ash enables mercury removal in a particulate control device. A chemical kinetic mechanism consisting of nine homogeneous and heterogeneous reactions for mercury oxidation and removal was developed to interpret pilot-scale measurements of mercury oxidation and adsorption by unburned carbon and fly ash in experiments at pilot scale, burning bituminous coals (Gale, 2006) and blends of bituminous coals with Powder River Basin coal (Gale, 2005). The removal of mercury by fly ash and unburned carbon in the flue gas from combustion of the bituminous coals and blends was reproduced with satisfactory accuracy by the model. The enhancement of mercury capture in the presence of calcium (Gale, 2005) explained a synergistic effect of blending on mercury removal across the baghouse. The extent of mercury oxidation, on the other hand, was not so well described by the simulation, because of oversensitivity of the oxidation process in the model to the concentration of unburned carbon. Combined catalysts and sorbents for oxidation and removal of mercury from flue gas at low temperature were based on surfactant-templated silicas containing a transition metal and an organic functional group. The presence of both metal ions and organic groups within the pore structure of the materials is expected to impart to them the ability to simultaneously oxidize elemental mercury and adsorb the resulting oxidized mercury. Twelve mesoporous organosilicate catalysts/sorbents were synthesized, with and without metals (manganese, titanium, vanadium) and organic functional groups (aminopropyl, chloropropyl, mercaptopropyl). Measurement of mercury oxidation and adsorption by the candidate materials remains for future work.

Peter Walsh; Giang Tong; Neeles Bhopatkar; Thomas Gale; George Blankenship; Conrad Ingram; Selasi Blavo Tesfamariam Mehreteab; Victor Banjoko; Yohannes Ghirmazion; Heng Ban; April Sibley

2009-09-14T23:59:59.000Z

105

Thermally Oxidized Silicon  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Anneli Munkholm (Lumileds Lighting) and Sean Brennan (SSRL) Anneli Munkholm (Lumileds Lighting) and Sean Brennan (SSRL) Illustration of the silicon positions near the Si-SiO2 interface for a 4° miscut projected onto the ( ) plane. The silicon atoms in the substrate are blue and those in the oxide are red. The small black spots represent the translated silicon positions in the absence of static disorder. The silicon atoms in the oxide have been randomly assigned a magnitude and direction based on the static disorder value at that position in the lattice. The outline of four silicon unit cells is shown in black, whereas the outline of four expanded lattice cells in the oxide is shown in blue One of the most studied devices of modern technology is the field-effect transistor, which is the basis for most integrated circuits. At its heart

106

Oxidative Tritium Decontamination System  

SciTech Connect (OSTI)

The Princeton Plasma Physics Laboratory, Tritium Systems Group has developed and fabricated an Oxidative Tritium Decontamination System (OTDS), which is designed to reduce tritium surface contamination on various components and items. The system is configured to introduce gaseous ozone into a reaction chamber containing tritiated items that require a reduction in tritium surface contamination. Tritium surface contamination (on components and items in the reaction chamber) is removed by chemically reacting elemental tritium to tritium oxide via oxidation, while purging the reaction chamber effluent to a gas holding tank or negative pressure HVAC system. Implementing specific concentrations of ozone along with catalytic parameters, the system is able to significantly reduce surface tritium contamination on an assortment of expendable and non-expendable items. This paper will present the results of various experimentation involving employment of this system.

Charles A. Gentile; John J. Parker; Gregory L. Guttadora; Lloyd P. Ciebiera

2002-02-11T23:59:59.000Z

107

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

1999-01-01T23:59:59.000Z

108

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

2001-01-01T23:59:59.000Z

109

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

Ahmed, S.; Kumar, R.; Krumpelt, M.

1999-08-17T23:59:59.000Z

110

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

Ahmed, S.; Kumar, R.; Krumpelt, M.

1999-08-24T23:59:59.000Z

111

DISSOLUTION OF NEPTUNIUM OXIDE RESIDUES  

SciTech Connect (OSTI)

This report describes the development of a dissolution flowsheet for neptunium (Np) oxide (NpO{sub 2}) residues (i.e., various NpO{sub 2} sources, HB-Line glovebox sweepings, and Savannah River National Laboratory (SRNL) thermogravimetric analysis samples). Samples of each type of materials proposed for processing were dissolved in a closed laboratory apparatus and the rate and total quantity of off-gas were measured. Samples of the off-gas were also analyzed. The quantity and type of solids remaining (when visible) were determined after post-dissolution filtration of the solution. Recommended conditions for dissolution of the NpO{sub 2} residues are: Solution Matrix and Loading: {approx}50 g Np/L (750 g Np in 15 L of dissolver solution), using 8 M nitric acid (HNO{sub 3}), 0.025 M potassium fluoride (KF) at greater than 100 C for at least 3 hours. Off-gas: Analysis of the off-gas indicated nitric oxide (NO), nitrogen dioxide (NO{sub 2}) and nitrous oxide (N{sub 2}O) as the only identified components. No hydrogen (H{sub 2}) was detected. The molar ratio of off-gas produced per mole of Np dissolved ranged from 0.25 to 0.4 moles of gas per mole of Np dissolved. A peak off-gas rate of {approx}0.1 scfm/kg bulk oxide was observed. Residual Solids: Pure NpO{sub 2} dissolved with little or no residue with the proposed flowsheet but the NpCo and both sweepings samples left visible solid residue after dissolution. For the NpCo and Part II Sweepings samples the residue amounted to {approx}1% of the initial material, but for the Part I Sweepings sample, the residue amounted to {approx}8 % of the initial material. These residues contained primarily aluminum (Al) and silicon (Si) compounds that did not completely dissolve under the flowsheet conditions. The residues from both sweepings samples contained minor amounts of plutonium (Pu) particles. Overall, the undissolved Np and Pu particles in the residues were a very small fraction of the total solids.

Kyser, E

2009-01-12T23:59:59.000Z

112

Tetraalklylammonium polyoxoanionic oxidation catalysts  

DOE Patents [OSTI]

Alkanes are catalytically oxidized in air or oxygen using iron-substituted polyoxoanions (POAs) of the formula: H{sub e{minus}z}[(n-C{sub 4}H{sub 9}){sub 4}N]{sub z}(XM{sub 11}M{prime}O{sub 39}){sup {minus}e}. The M{prime} (e.g., iron(III)/iron(II)) reduction potential of the POAs is affected by selection of the central atom X and the framework metal M, and by the number of tetrabutyl-ammonium groups. Decreased Fe(III)/Fe(II) reduction potential has been found to correlate to increased oxidation activity.

Ellis, P.E.; Lyons, J.E.; Myers, H.K. Jr.; Shaikh, S.N.

1998-10-06T23:59:59.000Z

113

Tetraalykylammonium polyoxoanionic oxidation catalysts  

DOE Patents [OSTI]

Alkanes are catalytically oxidized in air or oxygen using iron-substituted polyoxoanions (POAs) of the formula: H.sub.e-z ›(n-C.sub.4 H.sub.9).sub.4 N!.sub.z (XM.sub.11 M'O.sub.39).sup.-e The M' (e.g., iron(III)/iron(II)) reduction potential of the POAs is affected by selection of the central atom X and the framework metal M, and by the number of tetrabutyl-ammonium groups. Decreased Fe(III)/Fe(II) reduction potential has been found to correlate to increased oxidation activity.

Ellis, Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA); Myers, Jr., Harry K. (Cochranville, PA); Shaikh, Shahid N. (Media, PA)

1998-01-01T23:59:59.000Z

114

A Porphyrin-Stabilized Iridium Oxide Water Oxidation Catalyst  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A Porphyrin-Stabilized Iridium Oxide Water Oxidation Catalyst Authors: Sherman, B. D., Pillai, S., Kodis, G., Bergkamp, J., Mallouk, T. E., Gust, D., Moore, T. A., and Moore, A. L....

115

Oxidative Reforming of Biodiesel Over Molybdenum (IV) Oxide  

E-Print Network [OSTI]

as potential feedstock in solid oxide fuel cells. Petroleum based fuels become scarcer daily, and biodiesel for use in solid oxide fuel cells. This cutting edge area of research continues to be important as energy prove useful for solid oxide fuel cells. METHODS Commercial molybdenum dioxide was used for all tests

Collins, Gary S.

116

Highly oxidized superconductors  

DOE Patents [OSTI]

Novel superconducting materials in the form of compounds, structures or phases are formed by performing otherwise known synthesis in a highly oxidizing atmosphere rather than that created by molecular oxygen at atmospheric pressure or below. This leads to the successful synthesis of novel superconducting compounds which are thermodynamically stable at the conditions under which they are formed. 16 figs.

Morris, D.E.

1994-09-20T23:59:59.000Z

117

Active & passive oxidation of dense SiC & Al?O? composites  

E-Print Network [OSTI]

Preparation for Oxidation. . . . . Oxidation. . Graphite Furnace. . Tube Furnace. . Sample Characterization. Density Measurement. X-Ray Diffraction Analysis. Electron Microprobe Analysis. . . . . . . . . . . Scanning Electron Microscopy... Density Measurement. . . . . . . . . . . . . . . . . 23 Schematic of Hot Isostatic Press. 25 Variation of Pressure and Temperature During Sintering Cycle (not to scale). 26 Schematic of the Graphite Furnace...

Malhotra, Rohit

2012-06-07T23:59:59.000Z

118

Staged membrane oxidation reactor system  

DOE Patents [OSTI]

Ion transport membrane oxidation system comprising (a) two or more membrane oxidation stages, each stage comprising a reactant zone, an oxidant zone, one or more ion transport membranes separating the reactant zone from the oxidant zone, a reactant gas inlet region, a reactant gas outlet region, an oxidant gas inlet region, and an oxidant gas outlet region; (b) an interstage reactant gas flow path disposed between each pair of membrane oxidation stages and adapted to place the reactant gas outlet region of a first stage of the pair in flow communication with the reactant gas inlet region of a second stage of the pair; and (c) one or more reactant interstage feed gas lines, each line being in flow communication with any interstage reactant gas flow path or with the reactant zone of any membrane oxidation stage receiving interstage reactant gas.

Repasky, John Michael; Carolan, Michael Francis; Stein, VanEric Edward; Chen, Christopher Ming-Poh

2012-09-11T23:59:59.000Z

119

Staged membrane oxidation reactor system  

DOE Patents [OSTI]

Ion transport membrane oxidation system comprising (a) two or more membrane oxidation stages, each stage comprising a reactant zone, an oxidant zone, one or more ion transport membranes separating the reactant zone from the oxidant zone, a reactant gas inlet region, a reactant gas outlet region, an oxidant gas inlet region, and an oxidant gas outlet region; (b) an interstage reactant gas flow path disposed between each pair of membrane oxidation stages and adapted to place the reactant gas outlet region of a first stage of the pair in flow communication with the reactant gas inlet region of a second stage of the pair; and (c) one or more reactant interstage feed gas lines, each line being in flow communication with any interstage reactant gas flow path or with the reactant zone of any membrane oxidation stage receiving interstage reactant gas.

Repasky, John Michael; Carolan, Michael Francis; Stein, VanEric Edward; Chen, Christopher Ming-Poh

2014-05-20T23:59:59.000Z

120

Staged membrane oxidation reactor system  

DOE Patents [OSTI]

Ion transport membrane oxidation system comprising (a) two or more membrane oxidation stages, each stage comprising a reactant zone, an oxidant zone, one or more ion transport membranes separating the reactant zone from the oxidant zone, a reactant gas inlet region, a reactant gas outlet region, an oxidant gas inlet region, and an oxidant gas outlet region; (b) an interstage reactant gas flow path disposed between each pair of membrane oxidation stages and adapted to place the reactant gas outlet region of a first stage of the pair in flow communication with the reactant gas inlet region of a second stage of the pair; and (c) one or more reactant interstage feed gas lines, each line being in flow communication with any interstage reactant gas flow path or with the reactant zone of any membrane oxidation stage receiving interstage reactant gas.

Repasky, John Michael; Carolan, Michael Francis; Stein, VanEric Edward; Chen, Christopher Ming-Poh

2013-04-16T23:59:59.000Z

Note: This page contains sample records for the topic "measures miec oxides" from the National Library of EnergyBeta (NLEBeta).
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121

Ultrafast Graphene Oxide Humidity Sensors  

Science Journals Connector (OSTI)

Ultrafast Graphene Oxide Humidity Sensors ... Graphene oxide can be exploited in humidity and temperature sensors with a number of convenient features such as flexibility, transparency and suitability for large-scale manufacturing. ... Here we show that the two-dimensional nature of graphene oxide and its superpermeability to water combine to enable humidity sensors with unprecedented response speed (?30 ms response and recovery times). ...

Stefano Borini; Richard White; Di Wei; Michael Astley; Samiul Haque; Elisabetta Spigone; Nadine Harris; Jani Kivioja; Tapani Ryhänen

2013-11-09T23:59:59.000Z

122

Doped palladium containing oxidation catalysts  

DOE Patents [OSTI]

A supported oxidation catalyst includes a support having a metal oxide or metal salt, and mixed metal particles thereon. The mixed metal particles include first particles including a palladium compound, and second particles including a precious metal group (PMG) metal or PMG metal compound, wherein the PMG metal is not palladium. The oxidation catalyst may also be used as a gas sensor.

Mohajeri, Nahid

2014-02-18T23:59:59.000Z

123

Graphene and Graphene Oxide: Biofunctionalization and Applications...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Graphene Oxide: Biofunctionalization and Applications in Biotechnology. Graphene and Graphene Oxide: Biofunctionalization and Applications in Biotechnology. Abstract: Graphene...

124

Nickel-and Ruthenium-Doped Lanthanum Chromite Anodes: Effects of Nanoscale Metal Precipitation on Solid Oxide  

E-Print Network [OSTI]

on Solid Oxide Fuel Cell Performance W. Kobsiriphat,* B. D. Madsen, Y. Wang, M. Shah, L. D. Marks, and S. A characterization and electrochemical measurements in solid oxide fuel cells SOFCs . Transmission electron. Nanometer-scale electrode structures in solid oxide fuel cells SOFCs have the potential to yield improved

Marks, Laurence D.

125

Fundamental studies of stress distributions and stress relaxation in oxide scales on high temperature alloys. [Final progress report  

SciTech Connect (OSTI)

This report summarizes a three-year study of stresses arising in the oxide scale and underlying metal during high temperature oxidation and of scale cracking. In-situ XRD was developed to measure strains during oxidation over 1000{degrees}C on pure metals. Acoustic emission was used to observe scale fracture during isothermal oxidation and cooling, and statistical analysis was used to infer mechanical aspects of cracking. A microscratch technique was used to measure the fracture toughness of scale/metal interface. A theoretical model was evaluated for the development and relaxation of stresses in scale and metal substrate during oxidation.

Shores, D.A.; Stout, J.H.; Gerberich, W.W.

1993-06-01T23:59:59.000Z

126

Oxidation resistant alloys, method for producing oxidation resistant alloys  

DOE Patents [OSTI]

A method for producing oxidation-resistant austenitic alloys for use at temperatures below 800.degree. C. comprising of: providing an alloy comprising, by weight %: 14-18% chromium, 15-18% nickel, 1-3% manganese, 1-2% molybdenum, 2-4% silicon, 0% aluminum and the balance being iron; heating the alloy to 800.degree. C. for between 175-250 hours prior to use in order to form a continuous silicon oxide film and another oxide film. The method provides a means of producing stainless steels with superior oxidation resistance at temperatures above 700.degree. C. at a low cost

Dunning, John S. (Corvallis, OR); Alman, David E. (Salem, OR)

2002-11-05T23:59:59.000Z

127

Oxidation resistant alloys, method for producing oxidation resistant alloys  

DOE Patents [OSTI]

A method for producing oxidation-resistant austenitic alloys for use at temperatures below 800 C. comprising of: providing an alloy comprising, by weight %: 14-18% chromium, 15-18% nickel, 1-3% manganese, 1-2% molybdenum, 2-4% silicon, 0% aluminum and the balance being iron; heating the alloy to 800 C. for between 175-250 hours prior to use in order to form a continuous silicon oxide film and another oxide film. The method provides a means of producing stainless steels with superior oxidation resistance at temperatures above 700 C. at a low cost

Dunning, John S.; Alman, David E.

2002-11-05T23:59:59.000Z

128

Core-level spectroscopy of thin oxides and oxynitrides  

SciTech Connect (OSTI)

Several spectroscopic methods are discussed that use core levels, such as photoelectron spectroscopy and absorption spectroscopy with photoelectron or fluorescence detection. Measurements are presented on the desorption of a chemical oxide and the growth of oxynitrides with N{sub 2}0 on Si(100). The stoichiometry is found to change strongly with thickness, from a nitrogen-terminated Si surface to a nearly-pure oxide in the outer region of 40--60 {Angstrom} films. Using a third generation synchrotron beam line a sensitivity of better than a tenth of a monolayer is achieved by a simple photocurrent measurement.

Himpsel, F.J.; Akatsu, H. [International Business Machines Corp., Yorktown Heights, NY (United States). Thomas J. Watson Research Center; Carlisle, J.A. [Lawrence Livermore National Lab., CA (United States)] [and others

1994-07-19T23:59:59.000Z

129

Enhanced Thermal Conductivity Oxide Fuels  

SciTech Connect (OSTI)

the purpose of this project was to investigate the feasibility of increasing the thermal conductivity of oxide fuels by adding small fractions of a high conductivity solid phase.

Alvin Solomon; Shripad Revankar; J. Kevin McCoy

2006-01-17T23:59:59.000Z

130

Anodic oxidation of zircaloy-2  

Science Journals Connector (OSTI)

The anodic polarization of zircaloy-2 in different electrolytic baths has been investigated in order to obtain thick oxide films with properties suitable for wear applications.

A. Conte; A. Borello; A. Cabrini

1976-07-01T23:59:59.000Z

131

Ferric oxide quantum dots in stable phosphate glass system and their magneto-optical study  

SciTech Connect (OSTI)

Graphical abstract: We report synthesis of ferric oxide embedded low melting phosphate glass nanocomposite and also the effect of ferric oxide nanoparticles (NCs) content on the optical and magneto-optical properties of the glasses. Faraday rotation of the glass nanocomposites was measured and showed variation in Verdet constant with concentration of ferric oxide. Interestingly, the host glass itself showed fairly good Verdet constant (11.5°/T cm) and there is a threefold enhancement in the Verdet constant of ferric oxide quantum dot-glass nanocomposite. Highlights: ? We synthesize ferric oxide embedded low melting stable phosphate glass nanocomposite. ? Glasses doped with 0.25 and 2% ferric oxide show particle size in the range of 4–12 nm. ? The host phosphate glass itself shows fairly good Verdet constant (11.5°/T cm). ? Glasses doped with 0.25% ferric oxide show high Verdet constant (30.525°/T cm). ? The as synthesis glasses may have potential application in magneto optical devices. -- Abstract: Herein, we report the synthesis of ferric oxide embedded low melting phosphate glass nanocomposite and also the effect of ferric oxide nanoparticles content on the optical and magneto-optical properties of the glasses. The optical study clearly showed red shift in optical cut off with increasing ferric oxide concentration. The band gap of the host glass was observed to be 3.48 eV and it shifted to 3.14 eV after doping with ferric oxide. The glasses doped with 0.25 and 2% ferric oxide showed particle size of 4–6 nm and 8–12 nm, respectively. Faraday rotation of the glass nanocomposites was measured and showed variation in the Verdet constant as per increasing concentration of ferric oxide. Interestingly, the host glass itself showed fairly good Verdet constant (11.5°/T cm) and threefold enhancement was observed in the Verdet constant of ferric oxide quantum dot-glass nanocomposite.

Garaje, Sunil N.; Apte, Sanjay K. [Nanocomposite Group, Centre for Materials for Electronics Technology (C-MET), Department of Electronics and Information Technology (DeitY), Government of India, Panchawati, Off Pashan Road, Pune 411008 (India)] [Nanocomposite Group, Centre for Materials for Electronics Technology (C-MET), Department of Electronics and Information Technology (DeitY), Government of India, Panchawati, Off Pashan Road, Pune 411008 (India); Kumar, Ganpathy [Department of Electrical and Computer Engineering, Tennessee Technological University, 1 William L. Jones Drive, Cookeville, TN 38505 (United States)] [Department of Electrical and Computer Engineering, Tennessee Technological University, 1 William L. Jones Drive, Cookeville, TN 38505 (United States); Panmand, Rajendra P.; Naik, Sonali D. [Nanocomposite Group, Centre for Materials for Electronics Technology (C-MET), Department of Electronics and Information Technology (DeitY), Government of India, Panchawati, Off Pashan Road, Pune 411008 (India)] [Nanocomposite Group, Centre for Materials for Electronics Technology (C-MET), Department of Electronics and Information Technology (DeitY), Government of India, Panchawati, Off Pashan Road, Pune 411008 (India); Mahajan, Satish M., E-mail: smahajan@tntech.edu [Department of Electrical and Computer Engineering, Tennessee Technological University, 1 William L. Jones Drive, Cookeville, TN 38505 (United States); Chand, Ramesh [Ministry of Communications and Information Technology, Department of Electronics and Information Technology (DeitY), Electronics Niketan, 6, CGO Complex, New Delhi 110003 (India)] [Ministry of Communications and Information Technology, Department of Electronics and Information Technology (DeitY), Electronics Niketan, 6, CGO Complex, New Delhi 110003 (India); Kale, Bharat B., E-mail: bbkale@cmet.gov.in [Nanocomposite Group, Centre for Materials for Electronics Technology (C-MET), Department of Electronics and Information Technology (DeitY), Government of India, Panchawati, Off Pashan Road, Pune 411008 (India)

2013-02-15T23:59:59.000Z

132

Operation of staged membrane oxidation reactor systems  

SciTech Connect (OSTI)

A method of operating a multi-stage ion transport membrane oxidation system. The method comprises providing a multi-stage ion transport membrane oxidation system with at least a first membrane oxidation stage and a second membrane oxidation stage, operating the ion transport membrane oxidation system at operating conditions including a characteristic temperature of the first membrane oxidation stage and a characteristic temperature of the second membrane oxidation stage; and controlling the production capacity and/or the product quality by changing the characteristic temperature of the first membrane oxidation stage and/or changing the characteristic temperature of the second membrane oxidation stage.

Repasky, John Michael

2012-10-16T23:59:59.000Z

133

Catalytic wet oxidation of phenolic wastes  

E-Print Network [OSTI]

Possible catalyst deactivation problems High capital, low operating Supercritical water oxidation (SCWO) Feasible only at high organic concentra- tions High Fast reaction, complete oxidation Severe reaction conditions, canosion problems... of milder reaction conditions and is much less energy intensive. Thus, catalytic wet oxidation would be an alternative to solvent extraction, supercritical water oxidation, homogeneous oxidation, and incineration. It should also be feasible at low...

Thomas, Brook James

1995-01-01T23:59:59.000Z

134

Low Temperature Constrained Sintering of Cerium Gadolinium Oxide Films for Solid Oxide Fuel Cell Applications  

E-Print Network [OSTI]

Temperature Solid Oxide Fuel Cells, In: S.C. Singhal and M.solidoxide.html, Tubular Solid Oxide Fuel Cell Technology,Oxide Films for Solid Oxide Fuel Cell Applications by Jason

Nicholas, Jason.D.

2007-01-01T23:59:59.000Z

135

ARM - Measurement - Trace gas concentration  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

govMeasurementsTrace gas concentration govMeasurementsTrace gas concentration ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Trace gas concentration The amount per unit volume of trace gases other than carbon dioxide, ozone and water vapor, typically measured in conjunction with in situ aerosol measurements, e.g. carbon monoxide, nitrogen oxides, sulfur dioxide. Categories Atmospheric Carbon, Atmospheric State Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including those recorded for diagnostic or quality assurance purposes. ARM Instruments CO : Carbon Monoxide Mixing Ratio System

136

Metal oxide films on metal  

DOE Patents [OSTI]

A structure including a thin film of a conductive alkaline earth metal oxide selected from the group consisting of strontium ruthenium trioxide, calcium ruthenium trioxide, barium ruthenium trioxide, lanthanum-strontium cobalt oxide or mixed alkaline earth ruthenium trioxides thereof upon a thin film of a noble metal such as platinum is provided.

Wu, Xin D. (Los Alamos, NM); Tiwari, Prabhat (Los Alamos, NM)

1995-01-01T23:59:59.000Z

137

Ethylene Oxide for Soil Sterilization  

Science Journals Connector (OSTI)

... , this method may be time-consuming, and in view of the physical properties of ethylene oxide (solubility in water and boiling point 12-5 C.) it was considered ... consists of making up an aqueous solution to supply 2 or 4 c.c. of ethylene oxide in a given amount of water, using pre-chilled glassware and water. The ...

R. E. ROSE; R. W. BAILEY

1952-04-26T23:59:59.000Z

138

Different Approach to the Aluminium Oxide Topography Characterisation  

SciTech Connect (OSTI)

Different surface topographic techniques are being widely used for quantitative measurements of typical industrial aluminium oxide surfaces. In this research, specific surface of aluminium oxide layer on the offset printing plate has been investigated by using measuring methods which have previously not been used for characterisation of such surfaces. By using two contact instruments and non-contact laser profilometer (LPM) 2D and 3D roughness parameters have been defined. SEM micrographs of the samples were made. Results have shown that aluminium oxide surfaces with the same average roughness value (Ra) and mean roughness depth (Rz) typically used in the printing plate surface characterisation, have dramatically different surface topographies. According to the type of instrument specific roughness parameters should be used for defining the printing plate surfaces. New surface roughness parameters were defined in order to insure detailed characterisation of the printing plates in graphic reproduction process.

Poljacek, Sanja Mahovic; Gojo, Miroslav [Faculty of Graphic Arts, University of Zagreb, Getaldiceva 2, 10000 Zagreb (Croatia); Raos, Pero; Stoic, Antun [Mechanical Engineering Faculty, J.J. Strossmayer University of Osijek, Trg Ivane Brlic Mazuranic 2, 35000 Slavonski Brod (Croatia)

2007-04-07T23:59:59.000Z

139

Ultra Supercritical Steamside Oxidation  

SciTech Connect (OSTI)

Ultra supercritical (USC) power plants offer the promise of higher efficiencies and lower emissions, which are goals of the U.S. Department of Energy's Advanced Power Systems Initiatives. Most current coal power plants in the U.S. operate at a maximum steam temperature of 538 C. However, new supercritical plants worldwide are being brought into service with steam temperatures of up to 620 C. Current Advanced Power Systems goals include coal generation at 60% efficiency, which require steam temperatures of up to 760 C. This research examines the steamside oxidation of advanced alloys for use in USC systems, with emphasis placed on alloys for high- and intermediate-pressure turbine sections. Initial results of this research are presented.

Holcomb, Gordon R.; Cramer, Stephen D.; Covino, Bernard S., Jr.; Bullard, Sophie J.; Ziomek-Moroz, Malgorzata

2005-01-01T23:59:59.000Z

140

Carbon monoxide oxidation on Rh(111): Velocity and angular distributions of the CO2 product  

E-Print Network [OSTI]

Carbon monoxide oxidation on Rh(111): Velocity and angular distributions of the CO2 product J. I and angular distributions of CO2 produced by CO oxidation on Rh 111 have been measured as a function a fundamental and a practical point of view. CO2 formation serves as a model recombina- tion reaction

Sibener, Steven

Note: This page contains sample records for the topic "measures miec oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Aluminum oxide tunnel barriers for single electron memory devices Kameshwar K. Yadavallia,  

E-Print Network [OSTI]

oxide. These devices are characterized at 300 mK and show a definite threshold for tunneling through and storage dots in ultra thin poly-Si films [3], one-dimensional array of Al/ Al2O3 tunnel junctions [4], non aluminum oxide is deposited by atomic layer deposition. Measurements performed at 300 mK show nonvolatile

Orlov, Alexei

142

Parasitic infection and oxidative status are associated and vary with breeding activity in the Seychelles warbler  

Science Journals Connector (OSTI)

...assist). Social status may be important...they may invest more energy into reproduction...measured could help us to interpret links...activation and oxidative status (see [34...differ in oxidative status in selected lines...body composition and energy expenditure in nature...

2012-01-01T23:59:59.000Z

143

Nitrous Oxide Fluxes from the Gulf of Mexico "Dead Zone" Primary Investigator: Craig Stow -NOAA GLERL  

E-Print Network [OSTI]

forecasts require accurate estimates of greenhouse gas emission rates. Currently, there are few measurements Management Research Laboratory Overview Nitrous oxide is a potent greenhouse gas with a global warming oxide is a potent greenhouse gas with a global warming potential ~300 times that of carbon dioxide

144

Measurement of microbial oxidation of methane in lake water  

Science Journals Connector (OSTI)

Oct 5, 1973 ... displacing the water through a second 26-G needle. ... and the shaking of serum bottles was car- ried out in diffuse ... to power source;. 3-plastic.

145

Measurement of nitric oxide with an antimonide diode laser  

E-Print Network [OSTI]

lasers while retaining the practical advantages of room- temperature or thermoelectrically cooled the selective detection of NO under reduced pressure conditions was identified. With wavelength- modulation cooling is not required. © 1997 Optical Society of America Key words: Diode laser, antimonide, nitric

146

Nanostructured Solid Oxide Fuel Cell Electrodes  

E-Print Network [OSTI]

post-Doping of Solid Oxide Fuel Cell Cathodes,? P.h.D.and V. I. Birss, in Solid Oxide Fuel Cells (SOFC IX), S. C.Nanostructured Solid Oxide Fuel Cell Electrodes By Tal Zvi

Sholklapper, Tal Zvi

2007-01-01T23:59:59.000Z

147

Detection of oxidation in human serum lipoproteins  

E-Print Network [OSTI]

A method for the oxidation of lipoproteins in vitro was developed using the free radical initiator, 2,2?-azobis-(2-amidinopropane) dihydrochloride (AAPH). Following in vitro oxidation, the susceptibility to oxidation of the serum samples...

Myers, Christine Lee

2006-04-12T23:59:59.000Z

148

Quantitative NDA Measurements of Advanced Reprocessing Product Materials Containing U, NP, PU, and AM  

E-Print Network [OSTI]

of this first principle technique have been identified: (1) quantitative measurement of uranium, neptunium, plutonium, and americium materials; (2) quantitative measurement of mixed oxide (MOX) materials; (3) quantitative measurement of uranium materials; and (4...

Goddard, Braden

2013-04-05T23:59:59.000Z

149

vibration measurement  

Science Journals Connector (OSTI)

vibration measurement ? Erschütterungsmessung, Schwingungsmessung f [Schwingungsmessungen dienen dazu, die Schwingungsanfälligkeit von Bauwerken realitätsnah zu erfassen

2014-08-01T23:59:59.000Z

150

New manganese catalyst for light alkane oxidation  

DOE Patents [OSTI]

Aluminophosphates containing manganese in the structural framework are employed for the oxidation of alkanes, for example the vapor phase oxidation of methane to methanol.

Durante, Vincent A. (West Chester, PA); Lyons, James E. (Wallingford, PA); Walker, Darrell W. (Visalia, CA); Marcus, Bonita K. (Radnor, PA)

1994-01-01T23:59:59.000Z

151

Tributylphosphate Extraction Behavior of Bismuthate-Oxidized Americium  

SciTech Connect (OSTI)

Higher oxidation states of americium have long been known; however, options for their preparation in acidic solution are limited. The conventional choice, silver-catalyzed peroxydisulfate, is not useful at nitric acid concentrations above about 0.3 M. We investigated the use of sodium bismuthate as an oxidant for Am3+ in acidic solution. Room-temperature oxidation produced AmO2 2+ quantitatively, whereas oxidation at 80 °C produced AmO2+ quantitatively. The efficacy of the method for the production of oxidized americium was verified by fluoride precipitation and by spectroscopic absorbance measurements. We performed absorbance measurements using a conventional 1 cm cell for high americium concentrations and a 100 cm liquid waveguide capillary cell for low americium concentrations. Extinction coefficients for the absorbance of Am3+ at 503 nm, AmO2+ at 514 nm, and AmO2 2+ at 666 nm in 0.1 M nitric acid are reported. We also performed solvent extraction experiments with the hexavalent americium using the common actinide extraction ligand tributyl phosphate (TBP) for comparison to the other hexavalent actinides. Contact with 30% tributyl phosphate in dodecane reduced americium; it was nevertheless extracted using short contact times. The TBP extraction of AmO2 2+ over a range of nitric acid concentrations is shown for the first time and was found to be analogous to that of uranyl, neptunyl, and plutonyl ions.

Mincher; Leigh R. Martin; Nicholas C. Schmitt

2008-08-01T23:59:59.000Z

152

Evaluating two experimental approaches for measuring ecosystem carbon oxidation state and oxidative ratio  

E-Print Network [OSTI]

is abbreviated as Williams PCE 87. All equations in thiswith (A1). When equations are from Williams PCE 87, they areadditionally denoted as W PCE 87 (equation number), where

Masiello, C. A; Gallagher, M. E; Randerson, J. T; Deco, R. M; Chadwick, O. A

2008-01-01T23:59:59.000Z

153

Biostimulation of Iron Reduction and Subsequent Oxidation of Sediment Containing Fe-silicates and Fe-oxides: Effect of Redox Cycling on Fe(III) Bioreduction  

SciTech Connect (OSTI)

Microbial reduction of iron has been shown to be important in the transformation and remediation of contaminated sediments. Re-oxidation of microbially reduced iron may occur in sediments that experience oxidation-reduction cycling and can thus impact the extent of contaminant remediation. The purpose of this research was to quantify iron oxidation in a flow-through column filled with biologically-reduced sediment and to compare the iron phases in the re-oxidized sediment to both the pristine and biologically-reduced sediment. The sediment contained both Fe(III)-oxides (primarily goethite) and silicate Fe (illite/vermiculite) and was biologically reduced in phosphate buffered (PB) medium during a 497 day column experiment with acetate supplied as the electron donor. Long-term iron reduction resulted in partial reduction of silicate Fe(III) without any goethite reduction, based on Mössbauer spectroscopy measurements. This reduced sediment was treated with an oxygenated PB solution in a flow-through column resulting in the oxidation of 38% of the biogenic Fe(II). Additional batch experiments showed that the Fe(III) in the oxidized sediment was more quickly reduced compared to the pristine sediment, indicating that oxidation of the sediment not only regenerated Fe(III) but also enhanced iron reduction compared to the pristine sediment. Oxidation-reduction cycling may be a viable method to extend iron-reducing conditions during in-situ bioremediation.

Komlos, John; Kukkadapu, Ravi K.; Zachara, John M.; Jaffe, Peter R.

2007-07-01T23:59:59.000Z

154

Femtosecond pump-probe studies of reduced graphene oxide thin films  

E-Print Network [OSTI]

The dynamics of photocarriers in reduced graphene oxide thin films is studied by using ultrafast pump-probe spectroscopy. Time dependent differential transmissions are measured with sample temperatures ranging from 9 to 300 K. At each sample...

Ruzicka, Brian Andrew; Werake, Lalani Kumari; Zhao, Hui; Wang, Shuai; Loh, Kian Ping

2010-04-01T23:59:59.000Z

155

Nitric oxide inhibits the production of soluble endothelin converting enzyme-1  

Science Journals Connector (OSTI)

This study examined the effect of nitric oxide on the production of soluble ECE-1. Activity of ECE-1 in media was measured using a quenched fluorescent substrate assay, and expressed as a percentage of control...

Sanjaya Kuruppu; Niwanthi W. Rajapakse…

2014-11-01T23:59:59.000Z

156

Variations in organic aerosol optical and hygroscopic properties upon heterogeneous OH oxidation  

E-Print Network [OSTI]

Measurements of the evolution of organic aerosol extinction cross sections (?[subscript ext]) and subsaturated hygroscopicity upon heterogeneous OH oxidation are reported for two model compounds, squalane (a C30 saturated ...

Cappa, Christopher D.

157

The effects of asphalt binder oxidation on hot mix asphalt concrete mixture rheology and fatigue performance  

E-Print Network [OSTI]

. The decline in mixture fatigue life (determined using the calibrated mechanistic fatigue analysis approach with surface energy measurement) due to oxidation is significant. Pavement service life is dependent on the mixture, but can be estimated by a cumulative...

Jung, Sung Hoon

2009-06-02T23:59:59.000Z

158

The variability of methane, nitrous oxide and sulfur hexafluoride in Northeast India  

E-Print Network [OSTI]

High-frequency atmospheric measurements of methane (CH[subscript 4]), nitrous oxide (N[subscript 2]O) and sulfur hexafluoride (SF[subscript 6]) from Darjeeling, India are presented from December 2011 (CH[subscript 4])/March ...

Chatterjee, A.

159

Areal Contrasts in the Abundance of Hydrocarbon Oxidizing Microbes in Soils  

Science Journals Connector (OSTI)

...readily demonstrated. This is in- terpreted to mean that biomethane is widely prevalent in soils. Despite the presumed greater amount of methane (that is, petromethane plus biomethane) over an oil field, the measurement of methane oxidation...

J. B. Davis; R. L. Raymond; J. P. Stanley

1959-05-01T23:59:59.000Z

160

Pulsed quantum cascade laser instrument with compact design for rapid, high sensitivity measurements of trace gases in air  

Science Journals Connector (OSTI)

We have developed a compact instrument for sensitive, rapid and continuous measurement of trace gases in air, with results presented here for methane (CH4), nitric oxide (NO), nitrous oxide (N2O) and ammonia (NH3

J.B. McManus; J.H. Shorter; D.D. Nelson; M.S. Zahniser; D.E. Glenn…

2008-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "measures miec oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Structure, adhesion, and stability of metal/oxide and oxide/oxide interfaces  

SciTech Connect (OSTI)

Studies of structural, electronic, and chemical properties of metal/oxide and oxide/oxide interfaces were performed on well-defined interfaces that created by depositing ultra-thin potassium and aluminum films and their oxides onto single crystal TiO[sub 2] and NiO surfaces. Work focused on determining the structure, growth mechanisms, and morphologies of metal and oxide films as they are deposited an single crystal oxide surfaces using RHEED and atomic force microscopy probing electronic structure, bonding and chemical interactions at the interfaces using x-ray and uv photoelectron spectroscopies (XPS, UPS) and Auger electron spectroscopy (AES), and understanding factors affecting stability and reactivity of the interface regions including the role of defects and impurities. Results indicate that kinetic effects have an important influence on interface structure and composition, and they also show that defects in the oxide substrate induce new electronic states at the interface which play a major role in cation-anion bonding and interface interactions. The results establish a link between electronic and chemical bonding properties and the interface structure and morphology, which is required to successfully manipulate the interfacial properties of advanced ceramic materials.

Lad, R.J.

1992-11-01T23:59:59.000Z

162

On-board Measurement of NO and NO2 using Non-dispersive Ultraviolet...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

On-Board Measurement of Ammonia and Nitrous Oxide Using Feedback Absorption Laser Spectroscopy Combined with Amplified Resonance and Low Pressure Sampling Study of...

163

Single crystal oxide and oxide/oxide eutectic fibres for high temperature composites  

Science Journals Connector (OSTI)

The utilisation of fibre-reinforced metal, intermetallic and ceramic matrix composites (CMCs) in gas turbine engines offers the potential of improved fuel efficiency, higher operating temperature and greater thrust to weight ratio. The development of ceramic fibres with high strength, excellent strength retention at elevated temperatures and good creep resistance is essential to the successful implementation of composites in various high temperature components. Several single crystal oxide and oxide/oxide eutectic fibres have been developed to meet the demanding performance requirements. Recent progress made on developing these fibers will be discussed.

J.-M. Yang

2001-01-01T23:59:59.000Z

164

The catalytic oxidation of propane  

E-Print Network [OSTI]

THE CATALYTIC OXIDATION OP PROPANE A Thesis By Charles Frederick Sandersont * * June 1949 Approval as to style and content recommended: Head of the Department of Chemical Engineering THE CATALYTICi OXIDATTON OF PROPANE A Thesis By Charles... Frederick ;Sandersonit * June 1949 THE CATALYTIC OXIDATION OP PROPANE A Thesis Submitted to the Faculty of the Agricultural and Mechanical College of Texas in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy Major...

Sanderson, Charles Frederick

2013-10-04T23:59:59.000Z

165

Plutonium Oxidation and Subsequent Reduction by Mn (IV) Minerals  

SciTech Connect (OSTI)

Plutonium sorbed to rock tuff was preferentially associated with manganese oxides. On tuff and synthetic pyrolusite (Mn{sup IV}O{sub 2}), Pu(IV) or Pu(V) was initially oxidized, but over time Pu(IV) became the predominant oxidation state of sorbed Pu. Reduction of Pu(V/VI), even on non-oxidizing surfaces, is proposed to result from a lower Gibbs free energy of the hydrolyzed Pu(IV) surface species versus that of the Pu(V) or Pu(VI) surface species. This work suggests that despite initial oxidation of sorbed Pu by oxidizing surfaces to more soluble forms, the less mobile form of Pu, Pu(IV), will dominate Pu solid phase speciation during long term geologic storage. The safe design of a radioactive waste or spent nuclear fuel geologic repository requires a risk assessment of radionuclides that may potentially be released into the surrounding environment. Geochemical knowledge of the radionuclide and the surrounding environment is required for predicting subsurface fate and transport. Although difficult even in simple systems, this task grows increasingly complicated for constituents, like Pu, that exhibit complex environmental chemistries. The environmental behavior of Pu can be influenced by complexation, precipitation, adsorption, colloid formation, and oxidation/reduction (redox) reactions (1-3). To predict the environmental mobility of Pu, the most important of these factors is Pu oxidation state. This is because Pu(IV) is generally 2 to 3 orders of magnitude less mobile than Pu(V) in most environments (4). Further complicating matters, Pu commonly exists simultaneously in several oxidation states (5, 6). Choppin (7) reported Pu may exist as Pu(IV), Pu(V), or Pu(VI) oxic natural groundwaters. It is generally accepted that plutonium associated with suspended particulate matter is predominantly Pu(IV) (8-10), whereas Pu in the aqueous phase is predominantly Pu(V) (2, 11-13). The influence of the character of Mn-containing minerals expected to be found in subsurface repository environments on Pu oxidation state distributions has been the subject of much recent research. Kenney-Kennicutt and Morse (14), Duff et al. (15), and Morgenstern and Choppin (16) observed oxidation of Pu facilitated by Mn(IV)-bearing minerals. Conversely, Shaughnessy et al. (17) used X-ray Absorption near-edge spectroscopy (XANES) to show reduction of Pu(VI) by hausmannite (Mn{sup II}Mn{sub 2}{sup III}O{sub 4}) and manganite ({gamma}-Mn{sup III}OOH) and Kersting et al., (18) observed reduction of Pu(VI) by pyrolusite (Mn{sup IV}O{sub 2}). In this paper, we attempt to reconcile the apparently conflicting datasets by showing that Mn-bearing minerals can indeed oxidize Pu, however, if the oxidized species remains on the solid phase, the oxidation step competes with the formation of Pu(IV) that becomes the predominant solid phase Pu species with time. The experimental approach we took was to conduct longer term (approximately two years later) oxidation state analyses on the Pu sorbed to Yucca Mountain tuff (initial analysis reported by Duff et al., (15)) and measure the time-dependant changes in the oxidation state distribution of Pu in the presence of the Mn mineral pyrolusite.

KAPLAN, DANIEL

2005-09-13T23:59:59.000Z

166

Measurement fundamentals  

SciTech Connect (OSTI)

The need to have accurate petroleum measurement is obvious. Petroleum measurement is the basis of commerce between oil producers, royalty owners, oil transporters, refiners, marketers, the Department of Revenue, and the motoring public. Furthermore, petroleum measurements are often used to detect operational problems or unwanted releases in pipelines, tanks, marine vessels, underground storage tanks, etc. Therefore, consistent, accurate petroleum measurement is an essential part of any operation. While there are several methods and different types of equipment used to perform petroleum measurement, the basic process stays the same. The basic measurement process is the act of comparing an unknown quantity, to a known quantity, in order to establish its magnitude. The process can be seen in a variety of forms; such as measuring for a first-down in a football game, weighing meat and produce at the grocery, or the use of an automobile odometer.

Webb, R.A. [Marathon Pipe Line Co., Findlay, OH (United States)

1995-12-01T23:59:59.000Z

167

Rapid thermal oxidation of silicon in mixtures of oxygen and nitrous oxide  

SciTech Connect (OSTI)

Oxidation in nitrous oxide by conventional hot wall furnace processing and by rapid thermal oxidation (RTO) has been a subject of much interest in recent years. RTO is a fundamentally different process than furnace oxidation, however, and the full effects of this type of processing on the oxidation kinetics are not well understood. Oxidation of silicon by RTO at a variety of pressures, temperatures, and oxidation gas mixtures has been studied. Although at lower temperatures (< 850 C) the atmospheric pressure oxidation rate in nitrous oxide is very close to that in oxygen, at higher temperatures the oxidation rate in nitrous oxide is much lower than that in oxygen. At lower pressures in a RTO process, the oxidation rate in nitrous oxide is higher than that in oxygen. The effect of the nitrogen incorporated in the oxide acting as a diffusion barrier has been proposed as the mechanism of temperature dependence for atmospheric pressure oxidation in nitrous oxide. This does not explain the effects seen at lower pressure,s however, The authors propose that some of the intermediate species produced in the decomposition of nitrous oxide into molecular nitrogen, molecular oxygen, and nitric oxide play a role in the initial stages of oxidation by RTO in nitrous oxide.

Grant, J.M.; Karim, Z. [Sharp Microelectronics Technology, Inc., Camas, WA (United States)

1996-12-01T23:59:59.000Z

168

In situ reduction and oxidation of nickel from solid oxide fuel cells in a Titan ETEM  

E-Print Network [OSTI]

In situ reduction and oxidation of nickel from solid oxide fuel cells in a Titan ETEM A. Faes1. C. Singhal, K. Kendall, High Temperature Solid Oxide Fuel Cell - Fundamentals, Design, Denmark antonin.faes@epfl.ch Keywords: In situ ETEM, nickel oxide, reduction, RedOx, SOFC Solid Oxide Fuel

Dunin-Borkowski, Rafal E.

169

Transparent conducting oxides and production thereof  

SciTech Connect (OSTI)

Transparent conducting oxides and production thereof are disclosed. An exemplary method of producing a transparent conducting oxide (TCO) material may comprise: providing a TCO target doped with either a high-permittivity oxide or a low-permittivity oxide in a process chamber. The method may also comprise depositing a metal oxide on the target in the process chamber to form a thin film having enhanced optical properties without substantially decreasing electrical quality.

Gessert, Timothy A.; Yoshida, Yuki; Coutts, Timothy J.

2014-06-10T23:59:59.000Z

170

Transparent conducting oxides and production thereof  

SciTech Connect (OSTI)

Transparent conducting oxides and production thereof are disclosed. An exemplary method of producing a transparent conducting oxide (TCO) material may comprise: providing a TCO target (110) doped with either a high-permittivity oxide or a low-permittivity oxide in a process chamber (100). The method may also comprise depositing a metal oxide on the target (110) to form a thin film having enhanced optical properties without substantially decreasing electrical quality.

Gessert, Timothy A; Yoshida, Yuki; Coutts, Timothy J

2014-05-27T23:59:59.000Z

171

In situ Oxidation of Ultrathin Silver Films on Ni(111)  

SciTech Connect (OSTI)

Oxidation of silver films of one- and two-monolayer thicknesses on the Ni(111) surface was investigated by low-energy electron microscopy at temperatures of 500 and 600 K. Additionally, intensity-voltage curves were measured in situ during oxidation to reveal the local film structure on a nanometer scale. At both temperatures, we find that exposure to molecular oxygen leads to the destabilization of the Ag film with subsequent relocation of the silver atoms to small few-layer-thick silver patches and concurrent evolution of NiO(111) regions. Subsequent exposure of the oxidized surface to ethylene initiates the transformation of bilayer islands back into monolayer islands, demonstrating at least partial reversibility of the silver relocation process at 600 K.

A Meyer; I Flege; S Senanayake; B Kaemena; R Rettew; F Alamgir; J Falta

2011-12-31T23:59:59.000Z

172

In situ ion exchange preparation of Pt/carbon nanotubes electrode: Effect of two-step oxidation of carbon nanotubes  

SciTech Connect (OSTI)

Multi-walled carbon nanotubes (MWNTs) supported Pt electrode is prepared by in-situ ion exchange method. X-ray photoelectron spectroscopy (XPS) confirms that compared with the only electrochemical oxidation or chemical oxidation treatment, more carboxylic acid groups are produced on the surface of MWNTs treated by dual-oxidation, which involves both electrochemical oxidation and chemical oxidation. Transmission electron microscopy (TEM) shows that Pt nanoparticles deposited via in-situ ion exchange are highly dispersed on the MWNTs surface. Electrochemical measurements show that the resultant Pt/MWNTs electrode treated by dual-oxidation exhibits the largest electrochemical surface area and the highest activity for oxygen reduction reaction (ORR) among the investigated electrodes. This can be attributed to the fact that dual-oxidation treatment produces more carboxylic acid groups at the electroactive sites on MWNTs surface, which results in loading more Pt nanoparticles in the following ion exchange process.

Zhang, Sheng; Shao, Yuyan; Gao, Yunzhi; Chen, Guangyu; Lin, Yuehe; Yin, Geping

2011-12-01T23:59:59.000Z

173

Biogas fuel reforming for solid oxide fuel cells  

Science Journals Connector (OSTI)

In this paper strategies for biogas reforming and their ensuing effects on solid oxide fuel cell(SOFC) performance are explored. Synthesized biogas (65% CH4?+?35% CO2) fuel streams are reformed over a rhodium catalyst supported on a porous ?-alumina foam. Reforming approaches include steam reforming and catalytic partial oxidation (CPOX) utilizing either air or pure oxygen as the oxidant. A computational model is developed and utilized to guide the specification of reforming conditions that maximize both CH4 and CO2 conversions. Model predictions are validated with experimental measurements over a wide range of biogas-reforming conditions. Higher reforming temperatures are shown to activate the biogas-borne CO2 to enable significant methane dry-reforming chemistry. Dry reforming minimizes the oxidant-addition needs for effective biogas conversion potentially decreasing the thermal requirements for reactant heating and improving system efficiency. Such high-temperature reforming conditions are prevalent during CPOX with a pure-O2 oxidant. While CPOX-with-O2 reforming is highly exothermic the endothermicity of dry-reforming chemistry can be exploited to ensure that catalyst temperatures do not reach levels which cause catalyst sintering and degradation. SOFCelectrochemical performance under biogas reformate is shown to vary substantially with reforming approach. Cell operation under CPOX-with-O2 reformate is found to be comparable to that under humidified hydrogen.

Danielle M. Murphy; Amy E. Richards; Andrew Colclasure; Wade A. Rosensteel; Neal P. Sullivan

2012-01-01T23:59:59.000Z

174

Photo-oxidation effects in porous silicon luminescence  

Science Journals Connector (OSTI)

We investigate the photoluminescence (PL) evolution of porous silicon samples when exposed to air in darkness and under illumination. Oxygen incorporation is monitored through ir spectroscopy. Fourier transform infrared measurements show that samples exposed to air in darkness exhibit low oxidation rates whereas its PL spectra remain unchanged. On the other hand, samples exposed to air under illumination show a remarkable change in its PL together with a drastic increase in the oxidation rate. A well defined PL peak starts to grow at the expense of a peak located at lower energies, which is present in the PL spectra of the as-prepared samples. The set of PL spectra obtained during the evolution shows an isostilbic point that suggests the existence of two emitting components kinetically correlated. The application of the factor analysis technique confirms this asseveration and enables us to obtain the spectrum of each single emitting component. The oxidation behavior, together with the shape and evolution of the PL spectra, are explained in terms of the quantum wires hypothesis combined with an oxidation mechanism with significant nucleation. The whole set of results demonstrates that quantum size effects may rule the photo-oxidation of the porous silicon structure, and gives strong support to a quantum confinement model for porous silicon PL.

R. R. Koropecki; R. D. Arce; J. A. Schmidt

2004-05-26T23:59:59.000Z

175

Evaluation of a Combined Ultraviolet Photocatalytic Oxidation (UVPCO) /  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Evaluation of a Combined Ultraviolet Photocatalytic Oxidation (UVPCO) / Evaluation of a Combined Ultraviolet Photocatalytic Oxidation (UVPCO) / Chemisorbent Air Cleaner for Indoor Air Applications Title Evaluation of a Combined Ultraviolet Photocatalytic Oxidation (UVPCO) / Chemisorbent Air Cleaner for Indoor Air Applications Publication Type Report LBNL Report Number LBNL-62202 Year of Publication 2007 Authors Hodgson, Alfred T., Hugo Destaillats, Toshifumi Hotchi, and William J. Fisk Report Number LBNL-62202 Abstract We previously reported that gas-phase byproducts of incomplete oxidation were generated when a prototype ultraviolet photocatalytic oxidation (UVPCO) air cleaner was operated in the laboratory with indoor-relevant mixtures of VOCs at realistic concentrations. Under these conditions, there was net production of formaldehyde and acetaldehyde, two important indoor air toxicants. Here, we further explore the issue of byproduct generation. Using the same UVPCO air cleaner, we conducted experiments to identify common VOCs that lead to the production of formaldehyde and acetaldehyde and to quantify their production rates. We sought to reduce the production of formaldehyde and acetaldehyde to acceptable levels by employing different chemisorbent scrubbers downstream of the UVPCO device. Additionally, we made preliminary measurements to estimate the capacity and expected lifetime of the chemisorbent media. For most experiments, the system was operated at 680 - 780 m3/h (400 - 460 cfm).

176

Modification of epitaxial oxide films with ion implantation  

SciTech Connect (OSTI)

Ion implantation is used to modify the properties of oxide (YBCO and YSZ) thin films. Both superconducting and dielectric epitaxial oxide films, grown by laser ablation, are studied. The properties of the implanted oxide films are characterized by SIMS, XPS, DC resistivity and AC susceptibility measurements. By introducing reactive ions into superconducting oxide films, the conductivity of the material is inhibited possibly due to the interaction of the implanted ions with oxygen originally bound to the copper atoms. Al, Si, Ag and Ca ions are implanted into epitaxial YBCO films with injection energies ranging from 50--100 KeV and doses ranging from 1 {times} 10{sup 15}--1 {times} 10{sup 16}/cm{sup 2}. XPS analysis shows that the implanted Si ions form SiO{sub x}. The inhibition method has been applied to the fabrication of superconducting electronic devices, such as SQUIDs. Dielectric oxide films are doped by the implantation of conductive and nonconductive ions. YSZ films are doped with Ag and Si ions and the ions are found to increase the conductivity.

Hong, S.H.; Miller, J.R.; Ma, Q.Y.; Yang, E.S. [Columbia Univ., New York, NY (United States). Dept. of Electrical Engineering; Fenner, D.B. [AFR Inc., East Hartford, CT (United States); Yang, C.Y. [Santa Clara Univ., CA (United States). Microelectronics Lab.; Budnick, J.I. [Univ. of Connecticut, Storrs, CT (United States). Dept. of Physics

1996-11-01T23:59:59.000Z

177

Structural characterization of terrestrial microbial Mn oxides from Pinal Creek, AZ  

SciTech Connect (OSTI)

The microbial catalysis of Mn(II) oxidation is believed to be a dominant source of abundant sorption- and redox-active Mn oxides in marine, freshwater, and subsurface aquatic environments. In spite of their importance, environmental oxides of known biogenic origin have generally not been characterized in detail from a structural perspective. Hyporheic zone Mn oxide grain coatings at Pinal Creek, Arizona, a metals-contaminated stream, have been identified as being dominantly microbial in origin and are well studied from bulk chemistry and contaminant hydrology perspectives. This site thus presents an excellent opportunity to study the structures of terrestrial microbial Mn oxides in detail. XRD and EXAFS measurements performed in this study indicate that the hydrated Pinal Creek Mn oxide grain coatings are layer-type Mn oxides with dominantly hexagonal or pseudo-hexagonal layer symmetry. XRD and TEM measurements suggest the oxides to be nanoparticulate plates with average dimensions on the order of 11 nm thick x 35 nm diameter, but with individual particles exhibiting thickness as small as a single layer and sheets as wide as 500 nm. The hydrated oxides exhibit a 10-A basal-plane spacing and turbostratic disorder. EXAFS analyses suggest the oxides contain layer Mn(IV) site vacancy defects, and layer Mn(III) is inferred to be present, as deduced from Jahn-Teller distortion of the local structure. The physical geometry and structural details of the coatings suggest formation within microbial biofilms. The biogenic Mnoxides are stable with respect to transformation into thermodynamically more stable phases over a time scale of at least 5 months. The nanoparticulate layered structural motif, also observed in pure culture laboratory studies, appears to be characteristic of biogenic Mn oxides and may explain the common occurrence of this mineral habit in soils and sediments.

Bargar, John; Fuller, Christopher; Marcus, Matthew A.; Brearley, Adrian J.; Perez De la Rosa, M.; Webb, Samuel M.; Caldwell, Wendel A.

2008-03-19T23:59:59.000Z

178

ARM - Measurements  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Measurement Instrument Sponsor Aircraft State PositionVelocity @ 10Hz Trimble DSM(tm) AAF PitchRollAzimuth Trimble Advanced Navigation System (TANS)10Hz AAF...

179

Shell Measures  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Residential Commercial Commercial Industrial Lighting Energy Smart Grocer Program HVAC Program Shell Measures Commercial Kitchen & Food Service Equipment Plug Load New...

180

Solid oxide electrochemical reactor science.  

SciTech Connect (OSTI)

Solid-oxide electrochemical cells are an exciting new technology. Development of solid-oxide cells (SOCs) has advanced considerable in recent years and continues to progress rapidly. This thesis studies several aspects of SOCs and contributes useful information to their continued development. This LDRD involved a collaboration between Sandia and the Colorado School of Mines (CSM) ins solid-oxide electrochemical reactors targeted at solid oxide electrolyzer cells (SOEC), which are the reverse of solid-oxide fuel cells (SOFC). SOECs complement Sandia's efforts in thermochemical production of alternative fuels. An SOEC technology would co-electrolyze carbon dioxide (CO{sub 2}) with steam at temperatures around 800 C to form synthesis gas (H{sub 2} and CO), which forms the building blocks for a petrochemical substitutes that can be used to power vehicles or in distributed energy platforms. The effort described here concentrates on research concerning catalytic chemistry, charge-transfer chemistry, and optimal cell-architecture. technical scope included computational modeling, materials development, and experimental evaluation. The project engaged the Colorado Fuel Cell Center at CSM through the support of a graduate student (Connor Moyer) at CSM and his advisors (Profs. Robert Kee and Neal Sullivan) in collaboration with Sandia.

Sullivan, Neal P. (Colorado School of Mines, Golden, CO); Stechel, Ellen Beth; Moyer, Connor J. (Colorado School of Mines, Golden, CO); Ambrosini, Andrea; Key, Robert J. (Colorado School of Mines, Golden, CO)

2010-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "measures miec oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Emf measurements on nanocrystalline copper-doped ceria  

SciTech Connect (OSTI)

Mixed oxide samples of nanostructured Cu{sub x}Ce{sub 1{minus}x}O{sub 2{minus}y} of various composition were generated by (i) chemical precipitation and ball milling and (ii) inert gas condensation. X-ray diffraction measurements suggested that copper oxide was dissolved in nanostructured cerium oxide up to concentrations of x = 0.15. Solid electrolyte cells of the type A, Cu{sub 2}O/CuBr/Cu{sub x}Ce{sub 1{minus}x}O{sub 2{minus}y} (A = Cu or CuO) showed reversible cell voltages. The ratio of the formal chemical activities of CuO and Cu{sub 2}O dissolved in nanostructured cerium oxide were calculated from the cell voltages. The results are discussed in terms of an apparent macroscopic solubility, due to interfacial segregation of copper oxide on nanostructured cerium oxide.

Knauth, P.; Villain, S. [Faculte des Sciences de Marseille-St. Jerome, Marseille (France). Lab. de Metallurgie EDIFIS] [Faculte des Sciences de Marseille-St. Jerome, Marseille (France). Lab. de Metallurgie EDIFIS; Schwitzgebel, G.; Tschoepe, A. [Univ. des Saarlandes, Saarbruecken (Germany)] [Univ. des Saarlandes, Saarbruecken (Germany)

1998-11-01T23:59:59.000Z

182

Oxidants, Antioxidants and Cell Signaling  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxidants, Antioxidants and Cell Signaling Oxidants, Antioxidants and Cell Signaling Speaker(s): Chandan K. Sen Date: February 17, 1998 - 12:00pm Location: 90-3148 Seminar Host/Point of Contact: Richard Sextro Reactive oxygen species represent a common mediator of environmental stress such as during physical exercise, ozone exposure, UV radiation and xenobiotic (pollutant) metabolism. Antioxidant defense systems protect against the ravages of such reactive species. In contrast to the conventional idea that reactive oxygen is mostly a trigger for oxidative damage of biological structures, now we know that low physiologically relevant concentration of reactive oxygen species can regulate a variety of key molecular mechanisms that may be linked with important processes such as immune response, cell-cell adhesion, cell proliferation, inflammation,

183

Graphite Oxidation Thermodynamics/Reactions  

SciTech Connect (OSTI)

The vulnerability of graphite-matrix spent nuclear fuel to oxidation by the ambient atmosphere if the fuel canister is breached was evaluated. Thermochemical and kinetic data over the anticipated range of storage temperatures (200 to 400 C) were used to calculate the times required for a total carbon mass loss of 1 mgcm-2 from a fuel specimen. At 200 C, the time required to produce even this small loss is large, 900,000 yr. However, at 400 C the time required is only 1.9 yr. The rate of oxidation at 200 C is negligible, and the rate even at 400 C is so small as to be of no practical consequence. Therefore, oxidation of the spent nuclear fuel upon a loss of canister integrity is not anticipated to be a concern based upon the results of this study.

Propp, W.A.

1998-09-01T23:59:59.000Z

184

MEASURING GASEOUS EMISSIONS FROM STORED PIG SLURRY S. Espagnol1  

E-Print Network [OSTI]

2 MEASURING GASEOUS EMISSIONS FROM STORED PIG SLURRY S. Espagnol1 , L. Loyon2 , F. Guiziou2 , P to measure emissions factors of ammonia (NH3), nitrous oxide (N2O) methane (CH4) and carbon dioxide (CO2) from stored pig slurry and measured the variations of the emissions in time and space. In 2006, dynamic

Boyer, Edmond

185

Aromatic-radical oxidation chemistry  

SciTech Connect (OSTI)

The research effort has focussed on discovering an explanation for the anomalously high CO{sub 2} concentrations observed early in the reaction sequence of the oxidation of cyclopentadiene. To explain this observation, a number of plausible mechanisms have been developed which now await experimental verification. One experimental technique for verifying mechanisms is to probe the reacting system by perturbing the radical concentrations. Two forms of chemical perturbation of the oxidation of cyclopentadiene were begun during this past year--the addition of NO{sub 2} and CO to the reacting mixture.

Glassman, I.; Brezinsky, K. [Princeton Univ., NJ (United States)

1993-12-01T23:59:59.000Z

186

Solid oxide fuel cell generator  

DOE Patents [OSTI]

A solid oxide fuel cell generator has a pair of spaced apart tubesheets in a housing. At least two intermediate barrier walls are between the tubesheets and define a generator chamber between two intermediate buffer chambers. An array of fuel cells have tubes with open ends engaging the tubesheets. Tubular, axially elongated electrochemical cells are supported on the tubes in the generator chamber. Fuel gas and oxidant gas are preheated in the intermediate chambers by the gases flowing on the other side of the tubes. Gas leakage around the tubes through the tubesheets is permitted. The buffer chambers reentrain the leaked fuel gas for reintroduction to the generator chamber.

Draper, Robert (Churchill Boro, PA); George, Raymond A. (Pittsburgh, PA); Shockling, Larry A. (Plum Borough, PA)

1993-01-01T23:59:59.000Z

187

Zinc oxide thin film acoustic sensor  

SciTech Connect (OSTI)

This paper reports the implementation of (750 nm) thickness of Zinc Oxide (ZnO) thin film for the piezoelectric pressure sensors. The film was prepared and deposited employing the spray pyrolysis technique. XRD results show that the growth preferred orientation is the (002) plane. A polycrystalline thin film (close to mono crystallite like) was obtained. Depending on the Scanning Electron Microscopy photogram, the film homogeneity and thickness were shown. The resonance frequency measured (about 19 kHz) and the damping coefficient was calculated and its value was found to be about (2.5538), the thin film be haves as homogeneous for under and over damped. The thin film pressure sensing was approximately exponentially related with frequency, the thin film was observed to has a good response for mechanical stresses also it is a good material for the piezoelectric properties.

Mohammed, Ali Jasim; Salih, Wafaa Mahdi; Hassan, Marwa Abdul Muhsien; Nusseif, Asmaa Deiaa; Kadhum, Haider Abdullah [Department of Physics , College of Science, Al-Mustansiriyah University, Baghdad (Iraq); Mansour, Hazim Louis [Department of Physics , College of Education, Al-Mustansiriyah University, Baghdad (Iraq)

2013-12-16T23:59:59.000Z

188

Ultrafast Infrared Heating Laser Pulse-Induced Micellization Kinetics of Poly(ethylene oxide)-Poly(propylene oxide)-Poly(ethylene oxide) in  

E-Print Network [OSTI]

Ultrafast Infrared Heating Laser Pulse-Induced Micellization Kinetics of Poly(ethylene oxide)-Poly(propylene oxide)-Poly(ethylene oxide) in Water Xiaodong Ye, Yijie Lu, Shilin Liu,*, Guangzhao Zhang, and Chi Wu-induced micellization of poly(ethylene oxide)-b-poly(propylene oxide)-b-poly(ethylene oxide) (Pluronic PE10300) triblock

Liu, Shilin

189

Influence of Ionic Surfactants on the Aggregation of Poly(Ethylene Oxide)-Poly(Propylene Oxide)-Poly(Ethylene Oxide) Block Copolymers Studied by Differential Scanning and  

E-Print Network [OSTI]

Influence of Ionic Surfactants on the Aggregation of Poly(Ethylene Oxide)-Poly(Propylene Oxide)-Poly(Ethylene copolymers of poly(ethylene oxide) and poly(propylene oxide), EOnPOmEOn, and the ionic surfactants sodium the aggregates of all three polymers. Introduction Water-soluble poly(ethylene oxide)-poly(propylene oxide)- poly(ethylene

Loh, Watson

190

Using CrAIN Multilayer Coatings to Improve Oxidation Resistance...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Coatings to Improve Oxidation Resistance of Steel Interconnects for Solid Oxide Fuel Cell Stacks. Using CrAIN Multilayer Coatings to Improve Oxidation Resistance of Steel...

191

Computational Modeling of Graphene Oxide Exfoliation and Lithium Storage Characteristics.  

E-Print Network [OSTI]

??Graphene oxide is a two dimensional material obtained by adsorption of oxygen or oxygen-containing groups on graphene. Stacked layers of graphene oxide constitute graphite oxide.… (more)

Mortezaee, Reza

2013-01-01T23:59:59.000Z

192

Solid oxide steam electrolysis for high temperature hydrogen production .  

E-Print Network [OSTI]

??This study has focused on solid oxide electrolyser cells for high temperature steam electrolysis. Solid oxide electrolysis is the reverse operation of solid oxide fuel… (more)

Eccleston, Kelcey L.

2007-01-01T23:59:59.000Z

193

Structure, adhesion, and stability of metal/oxide and oxide/oxide interfaces  

SciTech Connect (OSTI)

During the past six months, we have begun our studies of the fundamental properties of metal/oxide and oxide/oxide heterogeneous interfaces which are being prepared by epitaxial growth of ultra-thin-films on single crystal TiO{sub 2} and NiO surfaces. A new ultra-high vacuum film growth chamber was assembled and coupled to an existing surface analysis chamber; a sample transfer system, metal deposition sources, and a RHEED systems with microchannel plate detection were constructed and implemented. Atomic Force Microscopy was used to characterize and refine the preparation procedures for the single crystal surfaces. The electronic structure of stoichiometric, oxygen-deficient, and potassium-covered TiO{sub 2} (110) surfaces was investigated. Preliminary results on the Al/TiO{sub 2} (110) system have been obtained. Two graduate students have begun thesis research on the project. 6 figs.

Lad, R.J.

1991-01-01T23:59:59.000Z

194

Scaling methane oxidation: From laboratory incubation experiments to landfill cover field conditions  

SciTech Connect (OSTI)

Evaluating field-scale methane oxidation in landfill cover soils using numerical models is gaining interest in the solid waste industry as research has made it clear that methane oxidation in the field is a complex function of climatic conditions, soil type, cover design, and incoming flux of landfill gas from the waste mass. Numerical models can account for these parameters as they change with time and space under field conditions. In this study, we developed temperature, and water content correction factors for methane oxidation parameters. We also introduced a possible correction to account for the different soil structure under field conditions. These parameters were defined in laboratory incubation experiments performed on homogenized soil specimens and were used to predict the actual methane oxidation rates to be expected under field conditions. Water content and temperature corrections factors were obtained for the methane oxidation rate parameter to be used when modeling methane oxidation in the field. To predict in situ measured rates of methane with the model it was necessary to set the half saturation constant of methane and oxygen, K{sub m}, to 5%, approximately five times larger than laboratory measured values. We hypothesize that this discrepancy reflects differences in soil structure between homogenized soil conditions in the lab and actual aggregated soil structure in the field. When all of these correction factors were re-introduced into the oxidation module of our model, it was able to reproduce surface emissions (as measured by static flux chambers) and percent oxidation (as measured by stable isotope techniques) within the range measured in the field.

Abichou, Tarek, E-mail: abichou@eng.fsu.edu [Florida State University, Tallahassee, FL 32311 (United States); Mahieu, Koenraad; Chanton, Jeff [Florida State University, Tallahassee, FL 32311 (United States); Romdhane, Mehrez; Mansouri, Imane [Unite de Recherche M.A.C.S., Ecole Nationale d'Ingenieurs de Gabes, Route de Medenine, 6029 Gabes (Tunisia)

2011-05-15T23:59:59.000Z

195

A study on the oxidation characteristics of cast irons containing aluminum  

SciTech Connect (OSTI)

Isothermal-oxidation characteristics of cast irons containing aluminum (5-15% Al) from 700 to 1000{degrees}C in air have been studied. In addition to mass-gain measurements, the morphology and composition of the oxide scales have been examined by SEM-EDX system and XRD analysis. A normal Fe-5Al-C alloy does not develop protective, adherent scales. Even the addition of misch metal and calcium silicide to such an alloy does not improve its oxidation resistance. But aluminum cast iron develops considerable oxidation resistance only when a sufficient quantity of silicon is also present in the alloy. Treatment of the alloy with misch metal and calcium silicide together assists in protective scale formation. Among the alloys investigated Fe-15Al-Si-C treated with misch metal and calcium silicide shows minimum oxidation at 1000{degrees}C.

Ghosh, S.; Prodhan, A. [National Metallurigical Laboratory, Jamshedpur (India); Mohanty, O.N. [Tata Steel, Jamshedpur (India)] [and others

1996-02-01T23:59:59.000Z

196

Abstract Measurement  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

however, are not well understood in this energy range. This dissertation presents a measurement of the ratio of CC + to CCQE cross-sections for muon neutrinos on mineral oil (CH...

197

A Measuring  

Office of Scientific and Technical Information (OSTI)

clozapine. Relation to extrapyramidal side ffects. Arch Gen Psychiatry 1992; 49538-544. Smith M, Wolf AP, Brodie JD, et. al. Serial '*F-N- methylspiroperidol PET studies to measure...

198

Perovskite catalysts for oxidative coupling  

DOE Patents [OSTI]

Perovskites of the structure A.sub.2 B.sub.2 C.sub.3 O.sub.10 are useful as catalysts for the oxidative coupling of lower alkane to heavier hydrocarbons. A is alkali metal; B is lanthanide or lanthanum, cerium, neodymium, samarium, praseodymium, gadolinium or dysprosium; and C is titanium.

Campbell, Kenneth D. (Charleston, WV)

1991-01-01T23:59:59.000Z

199

Perovskite catalysts for oxidative coupling  

DOE Patents [OSTI]

Perovskites of the structure A[sub 2]B[sub 2]C[sub 3]O[sub 10] are useful as catalysts for the oxidative coupling of lower alkane to heavier hydrocarbons. A is alkali metal; B is lanthanide or lanthanum, cerium, neodymium, samarium, praseodymium, gadolinium or dysprosium; and C is titanium.

Campbell, K.D.

1991-06-25T23:59:59.000Z

200

Solid oxide fuel cell generator  

DOE Patents [OSTI]

A solid oxide fuel cell generator has a plenum containing at least two rows of spaced apart, annular, axially elongated fuel cells. An electrical conductor extending between adjacent rows of fuel cells connects the fuel cells of one row in parallel with each other and in series with the fuel cells of the adjacent row. 5 figures.

Di Croce, A.M.; Draper, R.

1993-11-02T23:59:59.000Z

Note: This page contains sample records for the topic "measures miec oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

15 - Measurement  

Science Journals Connector (OSTI)

Publisher Summary This chapter focuses on the various methods and equipments used in the measurement of liquids and gases in pipelines. Streams that transport mixed natural gas liquids require the use of mass measurement to accurately account for the volume of the components, which make up the mix. Mass measurement eliminates the effects of non-ideal mixing and the need for compressibility factors. The measurement system that provides basic simplicity, reliability, wide acceptance, and the capability of handling variable mix streams without breaking new frontiers in measurement methods is the orifice flow measuring element with online density meter and microprocessor flow computer. The orifice is a static device generally inert to the measured fluid conditions, and calibration consists of simple dimensional measurement and conformance to specified physical tolerances. The second element, the density meter, is an external unit that is easily isolated from the flowing stream for calibration, inspection, and maintenance. The relative insensitivity of CO2 density to small changes in pressure in the primary flow to the orifice meters permits locating the density meter upstream of the meter manifold, thereby serving several meters. The microprocessor flow computer, or third element of the system, is essential to achieve the advantages of integrated mass flow, which comes from the ability of the computer to make computations in essentially "real time." A development program to improve the overall uncertainty of orifice metering was initiated by Shell Pipeline Corporation. The program's goal was to develop an economical method for proving ethylene orifice meters under actual operating conditions. Shell's ethylene systems are operated in the dense phase fluid region due to lower transportation costs. The ethylene meter stations operate in two regions, the dense-phase fluid and single-phase gas regions.

2005-01-01T23:59:59.000Z

202

Oxidation kinetics of aluminum diboride  

SciTech Connect (OSTI)

The oxidation characteristics of aluminum diboride (AlB{sub 2}) and a physical mixture of its constituent elements (Al+2B) were studied in dry air and pure oxygen using thermal gravimetric analysis to obtain non-mechanistic kinetic parameters. Heating in air at a constant linear heating rate of 10 °C/min showed a marked difference between Al+2B and AlB{sub 2} in the onset of oxidation and final conversion fraction, with AlB{sub 2} beginning to oxidize at higher temperatures but reaching nearly complete conversion by 1500 °C. Kinetic parameters were obtained in both air and oxygen using a model-free isothermal method at temperatures between 500 and 1000 °C. Activation energies were found to decrease, in general, with increasing conversion for AlB{sub 2} and Al+2B in both air and oxygen. AlB{sub 2} exhibited O{sub 2}-pressure-independent oxidation behavior at low conversions, while the activation energies of Al+2B were higher in O{sub 2} than in air. Differences in the composition and morphology between oxidized Al+2B and AlB{sub 2} suggested that Al{sub 2}O{sub 3}–B{sub 2}O{sub 3} interactions slowed Al+2B oxidation by converting Al{sub 2}O{sub 3} on aluminum particles into a Al{sub 4}B{sub 2}O{sub 9} shell, while the same Al{sub 4}B{sub 2}O{sub 9} developed a needle-like morphology in AlB{sub 2} that reduced oxygen diffusion distances and increased conversion. The model-free kinetic analysis was critical for interpreting the complex, multistep oxidation behavior for which a single mechanism could not be assigned. At low temperatures, moisture increased the oxidation rate of Al+2B and AlB{sub 2}, but both appear to be resistant to oxidation in cool, dry environments. - Graphical abstract: Isothermal kinetic data for AlB{sub 2} in air, showing a constantly decreasing activation energy with increasing conversion. Model-free analysis allowed for the calculation of global kinetic parameters despite many simultaneous mechanisms occurring concurrently. (a) Time–temperature plots, (b) conversion as a function of time, (c) Arrhenius plots used to calculate activation energies, and (d) activation energy as a function of conversion. Display Omitted - Highlights: • First reported kinetic parameters for AlB{sub 2} and Al+2B oxidation in air and O{sub 2}. • Possible mechanism of enhanced boron combustion presented. • Moisture sensitivity shown to be problematic for AlB{sub 2}, less for Al+2B.

Whittaker, Michael L., E-mail: michaelwhittaker2016@u.northwestern.edu [Department of Materials Science and Engineering, University of Utah, 122S. Central Campus Drive, Salt Lake City, UT 84112 (United States); Sohn, H.Y. [Department of Metallurgical Engineering, University of Utah, 135S 1460 E, Rm 00412, Salt Lake City, UT 84112 (United States); Cutler, Raymond A. [Ceramatec, Inc., 2425S. 900W., Salt Lake City, UT 84119 (United States)

2013-11-15T23:59:59.000Z

203

Role of Nitrous Oxide in Ambulatory Anaesthesia  

Science Journals Connector (OSTI)

As the oldest anaesthetic still in routine use, the continued role of nitrous oxide is frequently questioned. There are a few well-defined situations in which nitrous oxide is contraindicated or undesirable; i...

Sarah Billingham; Ian Smith

2014-12-01T23:59:59.000Z

204

Complex oxides useful for thermoelectric energy conversion  

DOE Patents [OSTI]

The invention provides for a thermoelectric system comprising a substrate comprising a first complex oxide, wherein the substrate is optionally embedded with a second complex oxide. The thermoelectric system can be used for thermoelectric power generation or thermoelectric cooling.

Majumdar, Arunava (Orinda, CA); Ramesh, Ramamoorthy (Moraga, CA); Yu, Choongho (College Station, TX); Scullin, Matthew L. (Berkeley, CA); Huijben, Mark (Enschede, NL)

2012-07-17T23:59:59.000Z

205

Rare Iron Oxide in Ancient Chinese Pottery  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Rare Iron Oxide in Ancient Chinese Pottery Rare Iron Oxide in Ancient Chinese Pottery Print Friday, 26 September 2014 14:37 Jian ware (or Tenmoku) ceramic bowls, famous for their...

206

NANO - "Green" metal oxides ... | ornl.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

NANO - "Green" metal oxides ... Water and nano-sized particles isolated from trees, plants and algae are the ingredients of a new recipe for low-cost metal oxides that are widely...

207

Vapor phase modifiers for oxidative coupling  

DOE Patents [OSTI]

Volatilized metal compounds retard vapor phase alkane conversion reactions in oxidative coupling processes that convert lower alkanes to higher hydrocarbons.

Warren, Barbara K. (Charleston, WV)

1991-01-01T23:59:59.000Z

208

High quality oxide films on substrates  

DOE Patents [OSTI]

A method is described for providing an oxide film of a material on the surface of a substrate using a reactive deposition of the material onto the substrate surface in the presence of a solid or liquid layer of an oxidizing gas. The oxidizing gas is provided on the substrate surface in an amount sufficient to dissipate the latent heat of condensation occurring during deposition as well as creating a favorable oxidizing environment for the material. 4 figures.

Ruckman, M.W.; Strongin, M.; Gao, Y.L.

1994-02-01T23:59:59.000Z

209

Oxide Film Aging on Alloy 22 in Halide Containing Solutions  

SciTech Connect (OSTI)

Passive and corrosion behaviors of Alloy 22 in chloride and fluoride containing solutions, changing the heat treatment of the alloy, the halide concentration and the pH of the solutions at 90 deg. C, was investigated. The study was implemented using electrochemical techniques, which included open circuit potential monitoring over time, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) measurements carried out at open circuit and at passivity potentials. Corrosion rates obtained by EIS measurements after 24 h immersion in naturally aerated solutions were below 0.5 {mu}m/year. The corrosion rates were practically independent of solution pH, alloy heat treatment and halide ion nature and concentration. EIS low frequency resistance values increased with applied potential in the passive domain and with polarization time in pH 6 - 1 M NaCl at 90 deg. C. This effect was attributed to an increase in the oxide film thickness and oxide film aging. High frequency capacitance measurements indicated that passive oxide on Alloy 22 presented a double n-type/p-type semiconductor behavior in the passive potential range. (authors)

Rodriguez, Martin A.; Carranza, Ricardo M. [Dept. Materiales, Comision Nacional de Energia Atomica, Av. Gral. Paz 1499, Villa Maipu, 1650 (Argentina); Rebak, Raul B. [Lawrence Livermore National Laboratory, 7000 East Ave, L-631, Livermore, CA, 94550-9698 (United States)

2007-07-01T23:59:59.000Z

210

Oxidative Transformation of Triclosan and Chlorophene by  

E-Print Network [OSTI]

Oxidative Transformation of Triclosan and Chlorophene by Manganese Oxides H U I C H U N Z H A N G of Technology, Atlanta, Georgia 30332 The antibacterial agents triclosan (5-chloro-2-(2,4- dichlorophenoxy(-MnO2 andMnOOH)yielding MnII ions. Both the initial reaction rate and adsorption of triclosan to oxide

Huang, Ching-Hua

211

Nitrous oxide emissions from wastewater treatment processes  

Science Journals Connector (OSTI)

...specific ammonia oxidation rate. Symbols represent...Research Council (ARC) for funding this...correlated to its ammonia oxidation rate. 51 Arp, D...1146/annurev.micro.61.080706.093449...1146/annurev.micro.61.080706.093449...2004 Anaerobic oxidation of inorganic nitrogen...

2012-01-01T23:59:59.000Z

212

REVERSIBLE SOLID OXIDE CELLS Mogens Mogensen1  

E-Print Network [OSTI]

The reversibility of solid oxide fuel cells (SOFC), i.e. that they could also work in the solid oxide electrolyser1 REVERSIBLE SOLID OXIDE CELLS Mogens Mogensen1 , Søren Højgaard Jensen1,2 , Anne Hauch1,3 , Ib Chorkendorff2 and Torben Jacobsen3 1 Fuel Cell and Solid State Chemistry Department Risø National Laboratory

213

Solid Oxide Electrolysis Cells Performance and Durability  

E-Print Network [OSTI]

Title: Solid Oxide Electrolysis Cells ­ Performance and Durability Department: Fuel Cells and SolidSolid Oxide Electrolysis Cells ­ Performance and Durability Anne Hauch Risø-PhD-37(EN) Risø : Images from transmission electron microscopy investigation of the H2 electrode for the solid oxide cell

214

Photo-oxides of Carcinogenic Hydrocarbons  

Science Journals Connector (OSTI)

... are involved in the biological action of carcinogenic hydrocarbons, we have attempted to isolate the photo-oxides of some of these hydrocarbons. Such ... -oxides of some of these hydrocarbons. Such photo-oxides would naturally be insoluble in water and hence would represent merely one stage in ...

J. W. COOK; R. MARTIN; E. M. F. ROE

1939-06-17T23:59:59.000Z

215

Dense high temperature ceramic oxide superconductors  

DOE Patents [OSTI]

Dense superconducting ceramic oxide articles of manufacture and methods for producing these articles are described. Generally these articles are produced by first processing these superconducting oxides by ceramic processing techniques to optimize materials properties, followed by reestablishing the superconducting state in a desired portion of the ceramic oxide composite.

Landingham, Richard L. (Livermore, CA)

1993-01-01T23:59:59.000Z

216

ORIGINAL ARTICLE Sulfur oxidizers dominate carbon fixation  

E-Print Network [OSTI]

). Methylotrophs and iron oxidizers were also active in plume waters and expressed key proteins for methane by bacteria (especially, alpha-, gamma- and epsilon-proteobacteria) that likely participate in the oxidationORIGINAL ARTICLE Sulfur oxidizers dominate carbon fixation at a biogeochemical hot spot in the dark

Hansell, Dennis

217

Nanotube Fabrication byNanotube Fabrication by Anodic Aluminum Oxide,Anodic Aluminum Oxide,  

E-Print Network [OSTI]

Nanotube Fabrication byNanotube Fabrication by Anodic Aluminum Oxide,Anodic Aluminum Oxide, Self-regulating phenomena in materials science: Self-assembly of nanopores during anodic oxidation of aluminum (AAO) Self combined anodic aluminum oxide (AAO) nanostructures with atomic layer deposition (ALD) to fabricate

Rubloff, Gary W.

218

Effect of morphology and solvent on two-photon absorption of nano zinc oxide  

SciTech Connect (OSTI)

Highlights: ? ZnO nanospheres and triangular structures synthesis by novel precipitation technique. ? The effect of precursor concentration on the size and shape of nano ZnO. ? Open aperture Z-scan measurements of the ZnO nanoparticle dispersions. ? Nanospheres exhibit higher two photon absorption coefficient than triangular nanostructures. ? Nanospheres dispersed in water exhibit higher two photon absorption coefficient than its dispersion in 2-propanol. - Abstract: In this paper, we report the effect of morphology and solvent on the two-photon absorption of nano zinc oxide. Zinc oxide nanoparticles in two different morphologies like nanospheres and triangular nanostructures are synthesized by novel precipitation technique and their two-photon absorption coefficient is measured using open aperture Z-scan technique. Experimental results show that the zinc oxide nanospheres exhibit higher two-photon absorption coefficient than the zinc oxide triangular nanostructures. The zinc oxide nanospheres dispersed in water exhibit higher two-photon absorption coefficient than that of its dispersion in 2-propanol. The zinc oxide nanospheres dispersed in water shows a decrease in two-photon absorption coefficient with an increase in on-axis irradiance. The result confirms the dependence of shape and solvent on the two-photon absorption of nano zinc oxide.

Kavitha, M.K. [Department of Chemistry, Indian Institute of Space Science and Technology, Valiamala, Thiruvananthapuram 695547, Kerala (India); Haripadmam, P.C.; Gopinath, Pramod; Krishnan, Bindu [Department of Physics, Indian Institute of Space Science and Technology, Valiamala, Thiruvananthapuram 695547, Kerala (India); John, Honey, E-mail: honey@iist.ac.in [Department of Chemistry, Indian Institute of Space Science and Technology, Valiamala, Thiruvananthapuram 695547, Kerala (India)

2013-05-15T23:59:59.000Z

219

Direct oxidation of hydrocarbons in a solid oxide fuel cell. I. Methane oxidation  

SciTech Connect (OSTI)

The performance of Cu cermets as anodes for the direct oxidation of CH{sub 4} in solid oxide fuel cells was examined. Mixtures of Cu and yttria-stabilized zirconia (YAZ) were found to give similar performance to Ni-YSZ cermets when H{sub 2} was used as the fuel, but did not deactivate in dry CH{sub 4}. While Cu-YSZ was essentially inert to methane, the addition of ceria to the anode gave rise to reasonable power densities and stable operation over a period of at least 3 days. Proof of direct oxidation of CH{sub 4} came from chemical analysis of the products leaving the cell. The major carbon-containing product was CO{sub 2}, with only traces of CO observed, and there was excellent agreement between the actual cell current and that predicted by the methane conversion. These results demonstrate that direct, electrocatalytic oxidation of dry methane is possible, with reasonable performance.

Park, S.; Craciun, R.; Vohs, J.M.; Gorte, R.J.

1999-10-01T23:59:59.000Z

220

High-temperature oxidation of an alumina-coated Ni-base alloy  

SciTech Connect (OSTI)

Alumina coatings were applied to Ni-20Cr (wt%) using combustion chemical vapor deposition (combustion CVD). Combustion CVD is an open air deposition technique performed in a flame. The oxidation kinetics of coated and uncoated specimens were measured by isothermal oxidation tests carried out in pure flowing air at temperatures of 800, 900, 1,000 and 1,100 C. The alumina coatings reduced the oxidation kinetics at all temperatures. The morphologies and compositions of the alumina coatings were characterized by transmission and scanning electron microscopy, energy dispersive x-ray spectroscopy and x-ray photoelectron spectroscopy.

Hendrick, M.R.; Hampikian, J.M.; Carter, W.B.

1996-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "measures miec oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Doped, porous iron oxide films and their optical functions and anodic photocurrents for solar water splitting  

SciTech Connect (OSTI)

The fabrication and morphological, optical, and photoelectrochemical characterization of doped iron oxide films is presented. The complex index of refraction and absorption coefficient of polycrystalline films are determined through measurement and modeling of spectral transmission and reflection data using appropriate dispersion relations. Photoelectrochemical characterization for water photo-oxidation reveals that the conversion efficiencies of electrodes are strongly influenced by substrate temperature during their oblique-angle physical vapor deposition. These results are discussed in terms of the films' morphological features and the known optoelectronic limitations of iron oxide films for application in solar water splitting devices.

Kronawitter, Coleman X.; Mao, Samuel S. [Department of Mechanical Engineering, University of California at Berkeley, Berkeley, California 94720, USA and Environmental Energy Technologies Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Antoun, Bonnie R. [Sandia National Laboratories, Livermore, California 94551 (United States)

2011-02-28T23:59:59.000Z

222

A novel clean and effective syngas production system based on partial oxidation of methane assisted solid oxide co-electrolysis process  

Science Journals Connector (OSTI)

Abstract Development of the syngas production from solid oxide H2O/CO2 co-electrolysis is limited by the intensive energy input and low efficiency. Here, we present a new concept to efficiently generate syngas in both sides of the solid oxide electrolyzer by synergistically combining co-electrolysis with partial oxidation of methane (POM). Thermodynamic calculation and electrochemical measurements for the POM assisted solid oxide co-electrolysis processes on the SFM-SDC/LSGM/SFM-SDC cells exhibited an reduced electric input, increased energy conversion efficiency and decreased cathodic co-electrolysis polarization resistance in comparison with the conventional co-electrolysis. This method will be crucial to establish a clean and effective energy conversion system to meet global sustainable energy needs.

Yao Wang; Tong Liu; Shumin Fang; Guoliang Xiao; Huanting Wang; Fanglin Chen

2015-01-01T23:59:59.000Z

223

Nitrous oxide (N?O) isotopic composition in the troposphere : instrumentation, observations at Mace Head, Ireland, and regional modeling  

E-Print Network [OSTI]

Nitrous oxide (N?O) is a significant greenhouse gas and main contributor to stratospheric ozone destruction. Surface measurements of N?O mole fractions have been used to attribute source and sink strengths, but large ...

Potter, Katherine Ellison

2011-01-01T23:59:59.000Z

224

Specific Visualization of Nitric Oxide in the Vasculature with Two-Photon Microscopy Using a Copper Based Fluorescent Probe  

E-Print Network [OSTI]

To study the role and (sub) cellular nitric oxide (NO) constitution in various disease processes, its direct and specific detection in living cells and tissues is a major requirement. Several methods are available to measure ...

Ghosh, Mitrajit

225

Reduction of iron-oxide-carbon composites: part I. Estimation of the rate constants  

SciTech Connect (OSTI)

A new ironmaking concept using iron-oxide-carbon composite pellets has been proposed, which involves the combination of a rotary hearth furnace (RHF) and an iron bath smelter. This part of the research focuses on studying the two primary chemical kinetic steps. Efforts have been made to experimentally measure the kinetics of the carbon gasification by CO{sub 2} and wustite reduction by CO by isolating them from the influence of heat- and mass-transport steps. A combined reaction model was used to interpret the experimental data and determine the rate constants. Results showed that the reduction is likely to be influenced by the chemical kinetics of both carbon oxidation and wustite reduction at the temperatures of interest. Devolatilized wood-charcoal was observed to be a far more reactive form of carbon in comparison to coal-char. Sintering of the iron-oxide at the high temperatures of interest was found to exert a considerable influence on the reactivity of wustite by virtue of altering the internal pore surface area available for the reaction. Sintering was found to be predominant for highly porous oxides and less of an influence on the denser ores. It was found using an indirect measurement technique that the rate constants for wustite reduction were higher for the porous iron-oxide than dense hematite ore at higher temperatures (> 1423 K). Such an indirect mode of measurement was used to minimize the influence of sintering of the porous oxide at these temperatures.

Halder, S.; Fruehan, R.J. [Praxair Inc., Tonawanda, NY (United States). Technological Center

2008-12-15T23:59:59.000Z

226

Nitrogen Oxides Emission Control Options  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nitrogen Nitrogen Oxides Emission Control Options for Coal-Fired Electric Utility Boilers Ravi K. Srivastava and Robert E. Hall U.S. Environmental Protection Agency, National Risk Management Research Laboratory, Air Pollution Prevention and Control Division, Research Triangle Park, NC Sikander Khan and Kevin Culligan U.S. Environmental Protection Agency, Office of Air and Radiation, Clean Air Markets Division, Washington, DC Bruce W. Lani U.S. Department of Energy, National Energy Technology Laboratory, Environmental Projects Division, Pittsburgh, PA ABSTRACT Recent regulations have required reductions in emissions of nitrogen oxides (NO x ) from electric utility boilers. To comply with these regulatory requirements, it is increas- ingly important to implement state-of-the-art NO x con- trol technologies on coal-fired utility boilers. This paper reviews NO x control

227

Semiconductive Properties of Uranium Oxides  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

SEMICONDUCTIVE PROPERTIES OF URANIUM OXIDES SEMICONDUCTIVE PROPERTIES OF URANIUM OXIDES Thomas Meek Materials Science Engineering Department University of Tennessee Knoxville, TN 37931 Michael Hu and M. Jonathan Haire Chemical Technology Division Oak Ridge National Laboratory * Oak Ridge, Tennessee 37831-6179 August 2000 For the Waste Management 2001 Symposium Tucson, Arizona February 25-March 1, 2001 The submitted manuscript has been authored by a contractor of the U.S. Government under contract DE-AC05-00OR22725. Accordingly, the U.S. Government retains a nonexclusive, royalty-free license to publish or reproduce the published form of this contribution, or allow others to do so, for U.S. Government purposes. _________________________ * Oak Ridge National Laboratory, managed by UT-Battelle, LLC, for the U.S. Department of Energy

228

Classification of oxide glasses: A polarizability approach  

SciTech Connect (OSTI)

A classification of binary oxide glasses has been proposed taking into account the values obtained on their refractive index-based oxide ion polarizability {alpha}{sub O2-}(n{sub 0}), optical basicity {lambda}(n{sub 0}), metallization criterion M(n{sub 0}), interaction parameter A(n{sub 0}), and ion's effective charges as well as O1s and metal binding energies determined by XPS. Four groups of oxide glasses have been established: glasses formed by two glass-forming acidic oxides; glasses formed by glass-forming acidic oxide and modifier's basic oxide; glasses formed by glass-forming acidic and conditional glass-forming basic oxide; glasses formed by two basic oxides. The role of electronic ion polarizability in chemical bonding of oxide glasses has been also estimated. Good agreement has been found with the previous results concerning classification of simple oxides. The results obtained probably provide good basis for prediction of type of bonding in oxide glasses on the basis of refractive index as well as for prediction of new nonlinear optical materials.

Dimitrov, Vesselin [Department of Silicate Technology, University of Chemical Technology and Metallurgy, 8 Kl. Ohridski Blvd., Sofia 1756 (Bulgaria); Komatsu, Takayuki [Department of Chemistry, The Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka-shi, Niigata-ken 940-2188 (Japan)]. E-mail: komatsu@chem.nagaokaut.ac.jp

2005-03-15T23:59:59.000Z

229

Atmospheric Oxidation of Coal at Moderate Temperatures. Effect of Oxidation on the Carbonizing Properties of Representative Coking Coals.  

Science Journals Connector (OSTI)

Atmospheric Oxidation of Coal at Moderate Temperatures. ... Effect of Oxidation on the Carbonizing Properties of Representative Coking Coals. ...

L Schmidt; J Elder; J Davis

1940-01-01T23:59:59.000Z

230

Nanowire-based All Oxide Solar Cells  

SciTech Connect (OSTI)

We present an all-oxide solar cell fabricated from vertically oriented zinc oxide nanowires and cuprous oxide nanoparticles. Our solar cell consists of vertically oriented n-type zinc oxide nanowires, surrounded by a film constructed from p-type cuprous oxide nanoparticles. Our solution-based synthesis of inexpensive and environmentally benign oxide materials in a solar cell would allow for the facile production of large-scale photovoltaic devices. We found that the solar cell performance is enhanced with the addition of an intermediate oxide insulating layer between the nanowires and the nanoparticles. This observation of the important dependence of the shunt resistance on the photovoltaic performance is widely applicable to any nanowire solar cell constructed with the nanowire array in direct contact with one electrode.

Yang*, Benjamin D. Yuhas and Peidong; Yang, Peidong

2008-12-07T23:59:59.000Z

231

Graphene oxide oxidizes stannous ions to synthesize tin sulfidegraphene nanocomposites with small crystal size for high performance lithium ion  

E-Print Network [OSTI]

Graphene oxide oxidizes stannous ions to synthesize tin sulfide­graphene nanocomposites with small September 2012 DOI: 10.1039/c2jm34864k This study reports a novel strategy of preparing graphene composites by employing graphene oxide as precursor and oxidizer. It is demonstrated that graphene oxide can oxidize

Cao, Guozhong

232

Corporate Performance Measures Definitions | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Budget & Performance » Corporate Budget & Performance » Corporate Performance Measures Definitions Corporate Performance Measures Definitions Corporate Performance Measures Plutonium Metal or Oxide packaged for long-term storage (number of containers): Certified DOE storage/treatment/disposal (STD) 3013 containers (or equivalent) of plutonium metal or oxide packaged and ready for long-term storage. Enriched Uranium packaged for long-term storage (number of containers): Certified containers packaged and ready for long-term storage. Plutonium or Uranium Residues packaged for disposition (kg of bulk material): Amount of residue material packaged and ready for disposition/disposal. Depleted and other Uranium packaged for disposition (metric tons): Depleted and natural uranium packaged in a form suitable for disposition.

233

Salt-stone Oxidation Study: Leaching Method - 13092  

SciTech Connect (OSTI)

Cementitious waste forms can be designed to chemically stabilize selected contaminants, such as Tc{sup +7} and Cr{sup +6}, by chemically reduction to lower valance states, Tc{sup +4} and Cr{sup +3}, respectively, and precipitation of these species in alkaline media as low solubility solid phases. Data for oxidation of this type of cementitious waste form cured under field conditions as a function of time is required for predicting the performance of the waste form and disposal facility. The rate of oxidation (oxidation front advancement) is an important parameter for predicting performance because the solubilities of some radionuclide contaminants, e.g., technetium, are a function of the oxidation state. A non-radioactive experiment was designed for quantifying the oxidation front advancement using chromium, as an approximate redox-sensitive surrogate (Cr{sup +6} / Cr{sup +3}) for technetium (Tc{sup +7} / Tc{sup +4}). Nonradioactive cementitious waste forms were prepared in the laboratory and cured under both laboratory and 'field conditions'. Laboratory conditions were ambient temperature and sealed sample containers. Field conditions were approximated by curing samples in open containers which were placed inside a plastic container stored outdoors at SRS. The container had a lid and was instrumented with temperature and humidity probes. Sub-samples as thin as 0.2 mm were taken as a function of distance from the exposed surface of the as-cast sample. The sub-samples were leached and the leachates were analyzed for chromium, nitrate, nitrite and sodium. Nitrate, nitrite, and sodium concentrations were used to provide baseline data because these species are not chemically retained in the waste form matrix to any significant extent and are not redox sensitive. 'Effective' oxidation fronts for Cr were measured for samples containing 1000, 500 and 20 mg/kg Cr added as soluble sodium chromate, Na{sub 2}CrO{sub 4}. For a sample cured for 129 days under field conditions, leachable Cr (assumed to be the oxidized form, i.e., Cr{sup +6} was detected in the top 15 to 20 mm of the sample spiked with 1000 mg/kg Cr. Below about 20 mm, the Cr concentrations in leachates were below the detection limit (< 0.010 mg/L) which indicates that the oxidation as the result of exposure to air was limited to the top 20 mm of the sample after exposure for 129 days and that the bulk of the waste form was not affected, i.e., the Cr was stabilized and insoluble. For samples cured in the laboratory, leachable Cr was detected in the top 8 mm of the Cr 1000 sample cured in the laboratory for 37 days. Between 8 and 14 mm, the concentration Cr in the leachate dropped by a factor of about 20 to just above the detection limit. These depth of penetration results indicate that the rate of advancement of the oxidation front for samples spiked with 1000 mg/kg Cr cured under 'field conditions' for 129 days is less than that for the sample cured in the laboratory for 37 days, i.e., 0.156 and 0.216 mm/day, respectively. Additional data are presented for samples spiked with 500 and 20 mg/kg Cr. In summary, cementitious waste forms are porous solids with a network of interconnected pores ranging in diameter from 10 E-10 m to greater than a few mm. The oxidation process is assumed to occur as the result of oxygen transport through the interconnected porosity which may be filled with air, aqueous salt solution, or both. Upon oxidation, the Cr becomes soluble and can be transported in solution through aqueous pore fluid or leachate. (authors)

Langton, C.A.; Stefanko, D.B.; Burns, H.H. [Savannah River National Laboratory, Savannah River Remediation, LLC, Savannah River Site, Aiken, SC 29808 (United States)] [Savannah River National Laboratory, Savannah River Remediation, LLC, Savannah River Site, Aiken, SC 29808 (United States)

2013-07-01T23:59:59.000Z

234

Step-Orientation-Dependent Oxidation: From 1D to 2D Oxides  

Science Journals Connector (OSTI)

Using scanning tunneling microscopy and density functional theory, we have studied the initial oxidation of Rh(111) surfaces with two types of straight steps, having {100} and {111} microfacets. The one-dimensional (1D) oxide initially formed at the steps acts as a barrier impeding formation of the 2D oxide on the (111) terrace behind it. We demonstrate that the details of the structure of the 1D oxide govern the rate of 2D oxidation and discuss implications for oxidation of nanoparticles.

J. Klikovits; M. Schmid; L. R. Merte; P. Varga; R. Westerström; A. Resta; J. N. Andersen; J. Gustafson; A. Mikkelsen; E. Lundgren; F. Mittendorfer; G. Kresse

2008-12-29T23:59:59.000Z

235

Degradation of Rabeprazole-N-oxide in aqueous solution using sonication as an advanced oxidation process  

Science Journals Connector (OSTI)

Abstract The degradation of Rabeprazole-N-oxide with sonication (US), peroxide mediated sonication (US/H2O2), Sono-Fenton (US/Fenton), TiO2 mediated sonication (US/TiO2) and sonication in combination with H2O2 and TiO2 (US/TiO2 + H2O2) is investigated and compared for their treatment efficiency. The effects of the frequency, power, different reactant concentrations and pH on the degradation rate have been examined. The efficiency of the treatment system is measured in terms of compound degradation and COD reduction. Among all the treatment processes studied, US/TiO2 + H2O2 is observed to be effective in degrading the drug impurity. A maximum of 72% degradation of the compound is observed at pH 7 with 50 mg of TiO2 and peroxide concentration of 500 mg/L.

G. Shankaraiah; P. Saritha; Nalini Vijayalaximi Pedamalla; D. Bhagawan; V. Himabindu

2014-01-01T23:59:59.000Z

236

Plasmonic transparent conducting metal oxide nanoparticles and films for optical sensing applications  

DOE Patents [OSTI]

The disclosure relates to a method of detecting a change in a chemical composition by contacting a doped oxide material with a monitored stream, illuminating the doped oxide material with incident light, collecting exiting light, monitoring an optical signal based on a comparison of the incident light and the exiting light, and detecting a shift in the optical signal. The doped metal oxide has a carrier concentration of at least 10.sup.18/cm.sup.3, a bandgap of at least 2 eV, and an electronic conductivity of at least 10.sup.1 S/cm, where parameters are specified at a temperature of 25.degree. C. The optical response of the doped oxide materials results from the high carrier concentration of the doped metal oxide, and the resulting impact of changing gas atmospheres on that relatively high carrier concentration. These changes in effective carrier densities of conducting metal oxide nanoparticles are postulated to be responsible for the change in measured optical absorption associated with free carriers. Exemplary doped metal oxides include but are not limited to Al-doped ZnO, Sn-doped In.sub.2O.sub.3, Nb-doped TiO.sub.2, and F-doped SnO.sub.2.

Ohodnicki, Jr., Paul R; Wang, Congjun; Andio, Mark A

2014-01-28T23:59:59.000Z

237

Electronically conducting metal oxide nanoparticles and films for optical sensing applications  

DOE Patents [OSTI]

The disclosure relates to a method of detecting a change in a chemical composition by contacting a conducting oxide material with a monitored stream, illuminating the conducting oxide material with incident light, collecting exiting light, monitoring an optical signal based on a comparison of the incident light and the exiting light, and detecting a shift in the optical signal. The conducting metal oxide has a carrier concentration of at least 10.sup.17/cm.sup.3, a bandgap of at least 2 eV, and an electronic conductivity of at least 10.sup.-1 S/cm, where parameters are specified at the gas stream temperature. The optical response of the conducting oxide materials is proposed to result from the high carrier concentration and electronic conductivity of the conducting metal oxide, and the resulting impact of changing gas atmospheres on that relatively high carrier concentration and electronic conductivity. These changes in effective carrier densities and electronic conductivity of conducting metal oxide films and nanoparticles are postulated to be responsible for the change in measured optical absorption associated with free carriers. Exemplary conducting metal oxides include but are not limited to Al-doped ZnO, Sn-doped In.sub.2O.sub.3, Nb-doped TiO.sub.2, and F-doped SnO.sub.2.

Ohodnicki, Jr., Paul R.; Wang, Congjun; Andio, Mark A

2014-09-16T23:59:59.000Z

238

Fusion Techniques for the Oxidation of Refractory Actinide Oxides  

SciTech Connect (OSTI)

Small-scale experiments were performed to demonstrate the feasibility of fusing refractory actinide oxides with a series of materials commonly used to decompose minerals, glasses, and other refractories as a pretreatment to dissolution and subsequent recovery operations. In these experiments, 1-2 g of plutonium or neptunium oxide (PuO2 or NpO2) were calcined at 900 degrees Celsius, mixed and heated with the fusing reagent(s), and dissolved. For refractory PuO2, the most effective material tested was a lithium carbonate (Li2CO3)/sodium tetraborate (Na2B4O7) mixture which aided in the recovery of 90 percent of the plutonium. The fused product was identified as a lithium plutonate (Li3PuO4) by x-ray diffraction. The use of a Li2CO3/Na2B4O7 mixture to solubilize high-fired NpO2 was not as effective as demonstrated for refractory PuO2. In a small-scale experiment, 25 percent of the NpO2 was oxidized to a neptunium (VI) species that dissolved in nitric acid. The remaining neptunium was then easily recovered from the residue by fusing with sodium peroxide (Na2O2). Approximately 70 percent of the neptunium dissolved in water to yield a basic solution of neptunium (VII). The remainder was recovered as a neptunium (VI) solution by dissolving the residue in 8M nitric acid. In subsequent experiments with Na2O2, the ratio of neptunium (VII) to (VI) was shown to be a function of the fusion temperature, with higher temperatures (greater than approximately 400 degrees C) favoring the formation of neptunium (VII). The fusion of an actual plutonium-containing residue with Na2O2 and subsequent dissolution was performed to demonstrate the feasibility of a pretreatment process on a larger scale. Sodium peroxide was chosen due to the potential of achieving higher actinide recoveries from refractory materials. In this experiment, nominally 10 g of a graphite-containing residue generated during plutonium casting operations was initially calcined to remove the graphite. Removal of combustible material prior to a large-scale fusion with Na2O2 is needed due to the large amount of heat liberated during oxidation. Two successive fusions using the residue from the calcination and the residue generated from the initial dissolution allowed recovery of 98 percent of the plutonium. The fusion of the residue following the first dissolution was performed at a higher temperature (600 degrees Celsius versus 450 degrees Celsius during the first fusion). The ability to recover most of the remaining plutonium from the residue suggest the oxidation efficiency of the Na2O2 fusion improves with higher temperatures similar to results observed with NpO2 fusion.

Rudisill, T.S.

1999-04-15T23:59:59.000Z

239

Radiation effects on the electrical properties of hafnium oxide based MOS capacitors.  

SciTech Connect (OSTI)

Hafnium oxide-based MOS capacitors were investigated to determine electrical property response to radiation environments. In situ capacitance versus voltage measurements were analyzed to identify voltage shifting as a result of changes to trapped charge with increasing dose of gamma, neutron, and ion radiation. In situ measurements required investigation and optimization of capacitor fabrication to include dicing, cleaning, metalization, packaging, and wire bonding. A top metal contact of 200 angstroms of titanium followed by 2800 angstroms of gold allowed for repeatable wire bonding and proper electrical response. Gamma and ion irradiations of atomic layer deposited hafnium oxide on silicon devices both resulted in a midgap voltage shift of no more than 0.2 V toward less positive voltages. This shift indicates recombination of radiation induced positive charge with negative trapped charge in the bulk oxide. Silicon ion irradiation caused interface effects in addition to oxide trap effects that resulted in a flatband voltage shift of approximately 0.6 V also toward less positive voltages. Additionally, no bias dependent voltage shifts with gamma irradiation and strong oxide capacitance room temperature annealing after ion irradiation was observed. These characteristics, in addition to the small voltage shifts observed, demonstrate the radiation hardness of hafnium oxide and its applicability for use in space systems.

Petrosky, J. C. (Air Force Institute of Technology, Wright-Patterson Air Force Base, OH); McClory, J. W. (Air Force Institute of Technology, Wright-Patterson Air Force Base, OH); Bielejec, Edward Salvador; Foster, J. C. (Air Force Institute of Technology, Wright-Patterson Air Force Base, OH)

2010-10-01T23:59:59.000Z

240

Oxidation and Volatilization from Tantalum Alloy T-222 During Air Exposure  

SciTech Connect (OSTI)

Tantalum alloys are one of the refractory metals with renewed consideration for high temperatures in fusion reactor applications. Tantalum alloys perform well in protective environments but oxidized readily in gases containing higher oxygen levels. In addition, the radioactive isotope Ta-182 would be produced in tantalum and could be a significant contributor to dose if mobilized. Other isotopes of importance are produced from tungsten and hafnium. Mobilization of activated products during an accident with air ingress is therefore a safety issue. In this study, we measured the extent of oxidation and mobilization from tantalum alloy T-222 oxidized in flowing air between 500 and 1200 C. This alloy nominally contains 10 wt% tungsten, 2.5 wt% hafnium and 0.01 wt% carbon. We found that the mobilization of Ta and Hf was closely linked to the occurrence of oxide spalling. These elements showed no migration from the test chamber. Some W was mobilized by volatilization as evidenced by transport from the chamber. Tungsten volatilization could occur primarily during initial stages of oxidation before an oxide scale forms and impedes the process. The mobilization of Ta and W are presented in terms of the mass flux (g/m 2 -h) as a function of test temperature. These measurements along with specific designs, activation calculations, and accident scenarios provide information useful for dose calculations of future fusion devices.

Smolik, G.R.; Petti, D.A.; Sharpe, J.P.; Schuetz, S.T.

2000-10-31T23:59:59.000Z

Note: This page contains sample records for the topic "measures miec oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Oxidation and Volatilization from Tantalum Alloy T-222 During Air Exposure  

SciTech Connect (OSTI)

Tantalum alloys are one of the refractory metals with renewed consideration for high temperatures in fusion reactor applications. Tantalum alloys perform well in protective environments but oxidized readily in gases containing higher oxygen levels. In addition, the radioactive isotope Ta-182 would be produced in tantalum and could be a significant contributor to dose if mobilized. Other isotopes of importance are produced from tungsten and hafnium. Mobilization of activated products during an accident with air ingress is therefore a safety issue. In this study, we measured the extent of oxidation and mobilization from tantalum alloy T-222 oxidized in flowing air between 500 and 1200°C. This alloy nominally contains 10 wt% tungsten, 2.5 wt% hafnium and 0.01 wt% carbon. We found that the mobilization of Ta and Hf was closely linked to the occurrence of oxide spalling. These elements showed no migration from the test chamber. Some W was mobilized by volatilization as evidenced by transport from the chamber. Tungsten volatilization could occur primarily during initial stages of oxidation before an oxide scale forms and impedes the process. The mobilization of Ta and W are presented in terms of the mass flux (g/m 2 -h) as a function of test temperature. These measurements along with specific designs, activation calculations, and accident scenarios provide information useful for dose calculations of future fusion devices

Smolik, Galen Richard; Petti, David Andrew; Sharpe, John Phillip; Schuetz, Stanley Thomas

2000-10-01T23:59:59.000Z

242

Why Sequence Freshwater Iron-Oxidizing Bacteria?  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Freshwater Iron-Oxidizing Bacteria? Freshwater Iron-Oxidizing Bacteria? The goal of this project is to obtain complete genome sequences for six different freshwater iron (Fe)-oxidizing bacteria (FeOB). Four of these are oxygen-dependent iron-oxidizing β-proteobacteria, and three of these, Sideroxydans lithotrophicus, Gallionella capsiferriformans, and strain TW-2, are capable of chemolithoautotrophic growth (that is, obtaining energy by the oxidation of inorganic compounds) using Fe(II) as sole energy source under microaerobic (low-oxygen) conditions. The fourth organism, Leptothrix cholodnii, is a sheath-forming heterotrophic (i.e., using complex organic compounds for nutrition) organism that oxidizes both Fe(II) and Mn(II) and deposits a ferromanganic coating on its sheath. In addition,

243

Unfamiliar oxidation states and their stabilization  

E-Print Network [OSTI]

ferrate formation. Oxidation of copper(II) hydroxide in alkaline solution with sodium hydroperoxide, Na.OOH, apparently gives copper (III) oxide.8 Determination of the voltage-current curve for a silver anode in sodium hydroxide solution gives breaks... of a knowledge of the chemical prop erties of the substance in question is made apparent by the following illustration: a compound containing silver and oxygen in equal atomic proportions may be made by the oxidation of unipositive silver...

Kleinberg, Jacob

1950-01-01T23:59:59.000Z

244

Solid-oxide fuel cell electrolyte  

DOE Patents [OSTI]

A solid-oxide electrolyte operable at between 600.degree. C. and 800.degree. C. and a method of producing the solid-oxide electrolyte are provided. The solid-oxide electrolyte comprises a combination of a compound having weak metal-oxygen interactions with a compound having stronger metal-oxygen interactions whereby the resulting combination has both strong and weak metal-oxygen interaction properties.

Bloom, Ira D. (Bolingbrook, IL); Hash, Mark C. (Joliet, IL); Krumpelt, Michael (Naperville, IL)

1993-01-01T23:59:59.000Z

245

Epitaxial-Graphene/Graphene-Oxide Junction: An Essential Step towards Epitaxial Graphene Electronics  

Science Journals Connector (OSTI)

Graphene-oxide (GO) flakes have been deposited to bridge the gap between two epitaxial-graphene electrodes to produce all-graphene devices. Electrical measurements indicate the presence of Schottky barriers at the graphene/graphene-oxide junctions, as a consequence of the band gap in GO. The barrier height is found to be about 0.7 eV, and is reduced after annealing at 180?°C, implying that the gap can be tuned by changing the degree of oxidation. A lower limit of the GO mobility was found to be 850??cm2/V?s, rivaling silicon. In situ local oxidation of patterned epitaxial graphene has been achieved.

Xiaosong Wu; Mike Sprinkle; Xuebin Li; Fan Ming; Claire Berger; Walt A. de Heer

2008-07-07T23:59:59.000Z

246

Water-gas Shift Reaction on oxide/Cu(111): Rational Catalyst Screening from Density Functional Theory  

SciTech Connect (OSTI)

Developing improved catalysts based on a fundamental understanding of reaction mechanism has become one of the grand challenges in catalysis. A theoretical understanding and screening the metal-oxide composite catalysts for the water-gas shift (WGS) reaction is presented here. Density functional theory was employed to identify the key step for the WGS reaction on the Au, Cu-oxide catalysts, where the calculated reaction energy for water dissociation correlates well with the experimental measured WGS activity. Accordingly, the calculated reaction energy for water dissociation was used as the scaling descriptor to screen the inverse model catalysts, oxide/Cu(111), for the better WGS activity. Our calculations predict that the WGS activity increases in a sequence: Cu(111), ZnO/Cu(111) < TiO{sub 2}/Cu(111), ZrO{sub 2}/Cu(111) < MoO{sub 3}/Cu(111). Our results imply that the high performances of Au, Cu-oxide nanocatalysts in the WGS reaction rely heavily on the direct participation of both oxide and metal sites. The degree that the oxide is reduced by Cu plays an important role in determining the WGS activity of oxide/Cu catalysts. The reducible oxide can be transformed from the fully oxidized form to the reduced form due to the interaction with Cu and, therefore, the transfer of electron density from Cu, which helps in releasing the bottleneck water dissociation and, therefore, facilitating the WGS reaction on copper.

Liu, P.

2010-11-28T23:59:59.000Z

247

Vibrational spectra of CO adsorbed on oxide thin films: A tool to probe the surface defects and phase changes of oxide thin films  

SciTech Connect (OSTI)

Thin films of iron oxide were grown on Pt(111) single crystals using cycles of physical vapor deposition of iron followed by oxidative annealing in an ultrahigh vacuum apparatus. Two procedures were utilized for film growth of ?15–30 ML thick films, where both procedures involved sequential deposition+oxidation cycles. In procedure 1, the iron oxide film was fully grown via sequential deposition+oxidation cycles, and then the fully grown film was exposed to a CO flux equivalent to 8 × 10{sup ?7} millibars, and a vibrational spectrum of adsorbed CO was obtained using infrared reflection-absorption spectroscopy. The vibrational spectra of adsorbed CO from multiple preparations using procedure 1 show changes in the film termination structure and/or chemical nature of the surface defects—some of which are correlated with another phase that forms (“phase B”), even before enough of phase B has formed to be easily detected using low energy electron diffraction (LEED). During procedure 2, CO vibrational spectra were obtained between deposition+oxidation cycles, and these spectra show that the film termination structure and/or chemical nature of the surface defects changed as a function of sequential deposition+oxidation cycles. The authors conclude that measurement of vibrational spectra of adsorbed CO on oxide thin films provides a sensitive tool to probe chemical changes of defects on the surface and can thus complement LEED techniques by probing changes not visible by LEED. Increased use of vibrational spectra of adsorbed CO on thin films would enable better comparisons between films grown with different procedures and by different groups.

Savara, Aditya, E-mail: savaraa@ornl.gov [Chemical Sciences Division, Oak Ridge National Lab, 1 Bethel Valley Road, Oak Ridge, Tennessee 37831 (United States)

2014-03-15T23:59:59.000Z

248

Effects of Tungsten Oxide Addition on the Electrochemical Performance of Nanoscale Tantalum Oxide-Based Electrocatalysts for Proton Exchange Membrane PEM Fuel Cells  

SciTech Connect (OSTI)

In the present study, the properties of a series of non-platinum based nanoscale tantalum oxide/tungsten oxide-carbon composite catalysts was investigated for potential use in catalyzing the oxygen reduction reaction (ORR) on the cathode side of a PEM fuel cell membrane electrode assembly. Electrochemical performance was measured using a half-cell test set up with a rotating disc electrode and compared with a commercial platinum-on-carbon (Pt/C) catalyst. Overall, all of the oxide-based composite catalysts exhibit high ORR on-set potentials, comparable to that of the baseline Pt/C catalyst. The addition of tungsten oxide as a dopant to tantalum oxide greatly improved mass specific current density. Maximum performance was achieved with a catalyst containing 32 mol% of tungsten oxide, which exhibited a mass specific current density ~8% that of the Pt/C catalyst at 0.6 V vs. the normal hydrogen electrode (NHE) and ~35% that of the Pt/C catalyst at 0.2 V vs. NHE. Results from X-ray photoelectron spectroscopy analysis indicated that the tungsten cations in the composite catalysts exist in the +6 oxidation state, while the tantalum displays an average valence of +5, suggesting that the addition of tungsten likely creates an oxygen excess in the tantalum oxide structure that influences its oxygen absorption kinetics. When the 32mol% tungsten doped catalyst loading on the working electrode was increased to five times that of the original loading (which was equivalent to that of the baseline Pt/C catalyst), the area specific current density improved four fold, achieving an area specific current density ~35% that of the Pt/C catalyst at 0.6 V vs. NHE.

Oh, Tak Keun; Kim, Jin Yong; Shin, Yongsoon; Engelhard, Mark H.; Weil, K. Scott

2011-08-01T23:59:59.000Z

249

High Temperature Oxidation Resistance and Surface Electrical...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

plates with oxidation resistant coatings. Candidate coatings must exhibit chemical and thermal-mechanical stability and high electrical conductivity during long-term...

250

Precursors of copper/zinc oxide catalysts  

Science Journals Connector (OSTI)

Recent results on hydroxycarbonate precursors of copper/zinc oxide catalysts for methanol synthesis are reinterpreted, taking into account earlier work on these systems.

M.S. Spencer

251

Vapor phase modifiers for oxidative coupling  

DOE Patents [OSTI]

Volatilized metal compounds are described which are capable of retarding vapor phase alkane conversion reactions in oxidative coupling processes that convert lower alkanes to higher hydrocarbons.

Warren, B.K.

1991-12-17T23:59:59.000Z

252

Double perovskite catalysts for oxidative coupling  

DOE Patents [OSTI]

Alkali metal doped double perovskites containing manganese and at least one of cobalt, iron and nickel are useful in the oxidative coupling of alkane to higher hydrocarbons.

Campbell, K.D.

1991-01-01T23:59:59.000Z

253

Lanthanide doped barium phosphorous oxide scintillators  

DOE Patents [OSTI]

The present invention provides for a composition comprising an inorganic scintillator comprising a lanthanide-doped barium phosphorous oxide useful for detecting nuclear material.

Borade, Ramesh B; Bourret-Courchesne, Edith; Denzo, Stephen E

2013-02-26T23:59:59.000Z

254

Breakout Group 5: Solid Oxide Fuel Cells  

Broader source: Energy.gov (indexed) [DOE]

Oxide Fuel Cells PARTICIPANTS Name Organization Robert Ploessl Corning, Inc. Tim Armstrong Oak Ridge National Laboratory Barbara Heydorn SRI International Suresh Baskaran...

255

NETL: Solid Oxide Fuel Cells Publications  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Solid Oxide Fuel Cells Publications Operating Principles AEC Development Atmospheric Pressure Systems Pressurized Systems Program Plan Project Portfolio Project Information Systems...

256

How to overcome the oxide barrier | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

oxide semiconductor Atomistic diagram for crystalline chromium metal (light blue) on strontium titanate(top), an equation that describes the transport process (middle), and an...

257

Cation Defects and Conductivity in Transparent Oxides  

SciTech Connect (OSTI)

High quality doped zinc oxide and mixed transition metal spinel oxide films have been deposited by means of sputter deposition from metal and metal oxide targets, and by spin casting from aqueous or alcoholic precursor solutions. Deposition conditions and post-deposition processing are found to alter cation oxidation states and their distributions in both oxide materials resulting in marked changes to both optical transmission and electrical response. For ZnO, partial reduction of the neat or doped material by hydrogen treatment of the heated film or by electrochemical processing renders the oxide n-type conducting. Continued reduction was found to diminish conductivity. In contrast, oxidation of the infrared transparent p-type spinel conductors typified by NiCo2O4 was found to increase conductivity. The disparate behavior of these two materials is caused in part by the sign of the charge carrier and by the existence of two different charge transport mechanisms that are identified as free carrier conduction and polaron hopping. While much work has been reported concerning structure/property relationships in the free carrier conducting oxides, there is a significantly smaller body of information on transparent polaron conductors. In this paper, we identify key parameters that promote conductivity in mixed metal spinel oxides and compare their behavior with that of the free carrier TCO’s.

Exarhos, Gregory J.; Windisch, Charles F.; Ferris, Kim F.; Owings, Robert R.

2007-10-24T23:59:59.000Z

258

Photosynthetic water oxidation versus photovoltaic water electrolysis  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

News Media about Center Center Video Library Bisfuel Picture Gallery Photosynthetic water oxidation versus photovoltaic water electrolysis 13 May 2011 Professor Tom Moore, a...

259

Oxidative Remobilization of Technetium Sequestered by Sulfide...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Remobilization of Technetium Sequestered by Sulfide-Transformed Nano Zerovalent Iron. Oxidative Remobilization of Technetium Sequestered by Sulfide-Transformed Nano Zerovalent...

260

Graphene oxide/poly(acrylic acid) hydrogel by ?-ray pre-irradiation on graphene oxide surface  

Science Journals Connector (OSTI)

Graphene oxide/poly(acrylic acid) (GO/PAA)...?...-ray pre-irradiation technique. The functional groups in graphene oxide were modified to peroxide in an...2 environment with ?...-ray radiation. Radical species fr...

Sungyoung Lee; Hoik Lee; Jae Hyun Sim; Daewon Sohn

2014-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "measures miec oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

The Oxidation of Ferritic Stainless Steels in Simulated Solid-Oxide Fuel-Cell Atmospheres  

Science Journals Connector (OSTI)

The cyclic oxidation of a variety of chromia-forming ferritic stainless steels has been studied in the temperature range 700–900°C in atmospheres relevant to solid-oxide fuel-cell operation. The most detriment...

J. E. Hammer; S. J. Laney; R. W. Jackson; K. Coyne; F. S. Pettit…

2007-02-01T23:59:59.000Z

262

Iodine doping effects on the lattice thermal conductivity of oxidized polyacetylene nanofibers  

SciTech Connect (OSTI)

Thermal transport in oxidized polyacetylene (PA) nanofibers with diameters in the range between 74 and 126?nm is measured with the use of a suspended micro heater device. With the error due to both radiation and contact thermal resistance corrected via a differential measurement procedure, the obtained thermal conductivity of oxidized PA nanofibers varies in the range between 0.84 and 1.24?W?m{sup ?1}?K{sup ?1} near room temperature, and decreases by 40%–70% after iodine doping. It is also found that the thermal conductivity of oxidized PA nanofibers increases with temperature between 100 and 350?K. Because of exposure to oxygen during sample preparation, the PA nanofibers are oxidized to be electrically insulating before and after iodine doping. The measurement results reveal that iodine doping can result in enhanced lattice disorder and reduced lattice thermal conductivity of PA nanofibers. If the oxidation issue can be addressed via further research to increase the electrical conductivity via doping, the observed suppressed lattice thermal conductivity in doped polymer nanofibers can be useful for the development of such conducting polymer nanostructures for thermoelectric energy conversion.

Bi, Kedong, E-mail: lishi@mail.utexas.edu, E-mail: kedongbi@seu.edu.cn [Jiangsu Key Laboratory for Design and Manufacture of Micro-Nano Biomedical Instruments, School of Mechanical Engineering, Southeast University, Nanjing 211189 (China); Department of Mechanical Engineering, University of Texas at Austin, Austin, Texas 78712 (United States); Weathers, Annie; Pettes, Michael T.; Shi, Li, E-mail: lishi@mail.utexas.edu, E-mail: kedongbi@seu.edu.cn [Department of Mechanical Engineering, University of Texas at Austin, Austin, Texas 78712 (United States); Matsushita, Satoshi; Akagi, Kazuo [Department of Polymer Chemistry, Kyoto University, Kyoto 615-8510 (Japan); Goh, Munju [Department of Polymer Chemistry, Kyoto University, Kyoto 615-8510 (Japan); Institute of Advanced Composite Materials, Korea Institute of Science and Technology (KIST), Eunha-ri san 101, Bondong-eup, Wanju-gun, Jeolabuk-do 565-905 (Korea, Republic of)

2013-11-21T23:59:59.000Z

263

Tin oxide-titanium oxide/graphene composited as anode materials for lithium-ion batteries  

Science Journals Connector (OSTI)

A tin oxide-titanium oxide/graphene (SnO2-TiO2.../G) ternary nanocomposite as high-performance anode for Li-ion batteries was prepared via a simple reflux method. ... The graphite oxide (GO) was reduced to graphene

Shan-Shan Chen; Xue Qin

2014-10-01T23:59:59.000Z

264

Correlating Catalytic Methanol Oxidation with the Structure and Oxidation State of Size-Selected Pt Nanoparticles  

E-Print Network [OSTI]

of this process is a limiting factor in the performance of direct methanol fuel cells, which produce electricityCorrelating Catalytic Methanol Oxidation with the Structure and Oxidation State of Size-Selected Pt nanoparticles (NPs) prepared by micelle encapsulation and supported on -Al2O3 during the oxidation of methanol

Kik, Pieter

265

Durability Evaluation of Reversible Solid Oxide Cells  

SciTech Connect (OSTI)

An experimental investigation on the performance and durability of single solid oxide cells (SOCs) is under way at the Idaho National Laboratory. Reversible operation of SOCs includes electricity generation in the fuel cell mode and hydrogen generation in the electrolysis mode. Degradation is a more significant issue when operating SOCs in the electrolysis mode. In order to understand and mitigate the degradation issues in high temperature electrolysis, single SOCs with different configurations from several manufacturers have been evaluated for initial performance and long-term durability. A new test apparatus for single cell and small stack tests has been developed for this purpose. Cells were obtained from four industrial partners. Cells from Ceramatec Inc. and Materials and Systems Research Inc. (MSRI) showed improved durability in electrolysis mode compared to previous stack tests. Cells from Saint Gobain Advanced Materials Inc. (St. Gobain) and SOFCPower Inc. demonstrated stable performance in the fuel cell mode, but rapid degradation in the electrolysis mode, especially at high current density. Electrolyte-electrode delamination was found to have a significant impact on degradation in some cases. Enhanced bonding between electrolyte and electrode and modification of the electrode microstructure helped to mitigate degradation. Polarization scans and AC impedance measurements were performed during the tests to characterize cell performance and degradation.

Xiaoyu Zhang; James E. O'Brien; Robert C. O'Brien; Gregory K. Housley

2013-11-01T23:59:59.000Z

266

Measuring Terrorism  

E-Print Network [OSTI]

Terrorism will be high on the political agenda for many years to come. Various policies are open to a government fighting terrorism but, in any case, considerable costs are involved. In the competition for political support, the costs and benefits of anti-terrorism policies will be debated. Better information about terrorism and its consequences can improve policy outcome if there is electoral competition. Over the last few years, economic scholars have analysed the effects terrorist acts have on various aspects of the economy. The findings of these impact studies are summarised in this paper. They capture, however, only part of the overall utility losses. Hence, several approaches to value public goods and conceptual issues concerning their application to terrorism are discussed. In particular, the hedonic market approach, the averting behaviour method, the contingent valuation method and vote and popularity functions are reviewed. Further, an exploratory analysis of estimating individuals ’ utility losses using life satisfaction or happiness data is presented. This paper also discusses a substantially different approach combining measurement and decision-making, namely popular referenda.

Bruno S. Frey; Simon Luechinger

2003-01-01T23:59:59.000Z

267

Oxidation and volatilization of a niobium alloy  

SciTech Connect (OSTI)

This report presents the findings from a preliminary investigation into oxidation and volatilization characteristics of a niobium alloy. Niobium is a candidate alloy for use in plasma facing components (PFCS) in experimental fusion reactors like the Intemational Thermonuclear Experimental Reactor (ITER). An experimental alloy was tailored to simulate small changes in chemistry which could result from transmutations from irradiation. The alloy was exposed in air and steam between 800[degree]C and 1200[degree]C. Volatilized products and hydrogen were collected and measured. Post-test examinations were also performed on the samples to determine the amount of material loss during the exposures. The obtained measurements of volatilization flux (g/m[sup 2]-s), hydrogen generation rates (liters/m[sup 2]-s), and recession rates (mm/s) are data which can be used for safety analyses and material performance to predict consequences which may result from an accident involving the ingress of air or steam into the plasma chamber of fusion reactor. In our volatility tests, only molybdenum and niobium were found at release levels above the detection limit. Although molybdenum is present at only 0.12 wt%, the quantities of this element volatilized in air are nearly comparable to the quantities of niobium released. The niobium release in steam is only three to four times higher than that of molybdenum in steam. The hydrogen production of the niobium alloy is compared with other PFC materials that we have tested, specifically, beryllium, graphite, and a tunesten alloy. At high temperatures, the hydrogen production rate of the niobium alloy is among the lowest of these materials, significantly lower than beryllium. To understand what this means in an accident situation, modeling is necessary to predict temperatures, and therefore total hydrogen production. The INEL is currently doing this modeling.

Smolik, G.R.; McCarthy, K.A.

1992-07-01T23:59:59.000Z

268

Investigation of Self-Assembly and Micelle Polarity for a Wide Range of Ethylene Oxide-Propylene Oxide-Ethylene  

E-Print Network [OSTI]

Investigation of Self-Assembly and Micelle Polarity for a Wide Range of Ethylene Oxide-Propylene Oxide-Ethylene Oxide Block Copolymers in Water Josias R. Lopes and Watson Loh* Instituto de Qui of 15 EO-PO-EO (EO ) ethylene oxide, PO ) propylene oxide) block copolymers by using three different

Loh, Watson

269

Magnetotelluric measurements  

SciTech Connect (OSTI)

The ideas of flux quantization and Josephson tunneling are reviewed, and the operation of the dc SQUID as a magnetometer is described. The SQUID currently used for magnetotellurics has a sensitivity of 10/sup -14/ T Hz/sup -1/2/, a dynamic range at 10/sup 7/ in a 1 Hz bandwidth, a frequency response from 0 to 40 kHz, and a slewing rate of 5 x 10/sup -5/T s/sup -1/. Recent improvements in sensitivity are discussed: SQUIDS are rapidly approaching the limit imposed by the uncertainty principle. The essential ideas of magnetotelluric (MT) measurements are outlined, and it is shown how the remote reference method can lead to major reductions in bias errors compared to more conventional schemes. The field techniques of the Berkeley group are described. The practical application of MT requires that amplitude and phase spectra of apparent resistivities be transformed into a geologically useful distribution of subsurface resistivities. In many areas where MT is being applied today, the technique may not provide the information needed because stations are too few and widely spaced, or because we are unable to interpret data influenced by complex 3-D resistivity features. The results of two surveys, one detailed, the other regional, over the Klamath Basin, Oregon, are examined. The detailed survey is able to resolve small (1 km wide) structural features that are missed or add a component of spatial aliasing to the regional data. On the other hand, the regional survey avoids truncation effects that may occur when the survey undersamples an area.

Clarke, J.; Goldstein, N.E.

1980-06-01T23:59:59.000Z

270

Constraining Mercury Oxidation Using Wet Deposition  

E-Print Network [OSTI]

Constraining Mercury Oxidation Using Wet Deposition Noelle E. Selin and Christopher D. Holmes mercury oxidation [Selin & Jacob, Atmos. Env. 2008] 30 60 90 120 150 30 60 90 120 150 30 60 90 120 150 30 Influences on Mercury Wet Deposition · Hg wet dep = f(precipitation, [Hg(II)+Hg(P)]) Correlation (r2) between

Selin, Noelle Eckley

271

Nanocomposite of graphene and metal oxide materials  

SciTech Connect (OSTI)

Nanocomposite materials comprising a metal oxide bonded to at least one graphene material. The nanocomposite materials exhibit a specific capacity of at least twice that of the metal oxide material without the graphene at a charge/discharge rate greater than about 10C.

Liu, Jun; Aksay, Ilhan A.; Choi, Daiwon; Wang, Donghai; Yang, Zhenguo

2012-09-04T23:59:59.000Z

272

Evaluating Environmental Influences Oxidation Kinetics by a  

E-Print Network [OSTI]

strategies for remediation of As-contaminated waters. In this study, the influence of goethite (R D O N A L D L . S P A R K S Department of Land, Air and Water Resources, The University of As-Mn systems demonstrate rapid oxidation of AsIII , catalyzed by Mn-oxides, producing less toxic

Sparks, Donald L.

273

The High-Temperature Oxidation of Propane  

Science Journals Connector (OSTI)

...research-article The High-Temperature Oxidation of Propane J. W. Falconer J. H. Knox Above 400 degrees C propane is oxidized by a two-stage degenerately...of propylene becomes important. While propane still in the main reacts to form propylene...

1959-01-01T23:59:59.000Z

274

Apparatus and method for oxidizing organic materials  

DOE Patents [OSTI]

The invention is a method and apparatus using high cerium concentration in the anolyte of an electrochemical cell to oxidize organic materials. The method and apparatus further use an ultrasonic mixer to enhance the oxidation rate of the organic material in the electrochemical cell. 6 figs.

Surma, J.E.; Bryan, G.H.; Geeting, J.G.H.; Butner, R.S.

1998-01-13T23:59:59.000Z

275

Electrochemical behavior of reactively sputtered iron-doped nickel oxide  

SciTech Connect (OSTI)

Iron-doped nickel oxide films were deposited by reactive sputtering from elemental and alloy targets in a 20% oxygen/argon atmosphere and were characterized for use as oxygen evolution catalysts. The incorporation of iron reduced the overpotential required for oxygen evolution by as much as 300 mV at a current density of 100 mA/cm{sup 2} compared to undoped nickel oxide deposited under similar conditions. Tafel slopes were reduced from 95 mV/dec in undoped NiO{sub x} films to less than 40 mV/dec for films containing 1.6 to 5.6 mole percent (m/o) iron, indicating a change in the rate-limiting step from the primary discharge of OH{sup {minus}} ions to the recombination of oxygen radicals. Resistivity, structural, and compositional measurements indicate that high oxygen content is necessary to gain the full benefit of the iron dopant. Initial tests in KOH indicate excellent long-term stability. A film deposited from the FeNi alloy target, which exhibited low oxygen overpotentials and a Tafel slope of 35 mV/dec, had not degraded appreciably following more than 7,000 h of operation at an anodic current density of 20 mA/cm{sup 2}. Taken together, the low oxygen evolution reaction overpotentials, the excellent stability in KOH, and the relative insensitivity to iron content indicative that reactively sputtered iron-doped nickel oxide is promising as an oxygen catalyst.

Miller, E.L.; Rocheleau, R.E. [Univ. of Hawaii, Honolulu, HI (United States)

1997-09-01T23:59:59.000Z

276

nitrogen oxides | OpenEI  

Open Energy Info (EERE)

20 20 Varnish cache server Browse Upload data GDR 429 Throttled (bot load) Error 429 Throttled (bot load) Throttled (bot load) Guru Meditation: XID: 2142279720 Varnish cache server nitrogen oxides Dataset Summary Description Emissions from energy use in buildings are usually estimated on an annual basis using annual average multipliers. Using annual numbers provides a reasonable estimation of emissions, but it provides no indication of the temporal nature of the emissions. Therefore, there is no way of understanding the impact on emissions from load shifting and peak shaving technologies such as thermal energy storage, on-site renewable energy, and demand control. Source NREL Date Released April 11th, 2011 (3 years ago) Date Updated April 11th, 2011 (3 years ago)

277

Oxidation of carburized Hastelloy X  

SciTech Connect (OSTI)

In a high temperature gas-cooled reactor (HTGR), small quantities of impurities such as H/sub 2/, H/sub 2/O, CO, CO/sub 2/, and CH/sub 4/ are present in the helium coolant. Prolonged exposure to these impurities at high temperature can result in undesirable mechanical properties due to corrosion. Extensive research has been performed on many candidate alloys to study their properties in HTGR helium, and in addition to oxidation, it has been found that carburization is also a possible problem in HTGR. Carbon in the graphite core, carried out by carbon-containing impurities such as CO and CH/sub 4/, can deposit on and diffuse into metallic components and cause carburization. The purpose of this research was to study the effects of carburization on an accelerated test.

Gan, D.

1983-07-01T23:59:59.000Z

278

Production of ozone and nitrogen oxides by laser filamentation  

SciTech Connect (OSTI)

We have experimentally measured that laser filaments in air generate up to 10{sup 14}, 3x10{sup 12}, and 3x10{sup 13} molecules of O{sub 3}, NO, and NO{sub 2}, respectively. The corresponding local concentrations in the filament active volume are 10{sup 16}, 3x10{sup 14}, and 3x10{sup 15} cm{sup -3}, and allows efficient oxidative chemistry of nitrogen, resulting in concentrations of HNO{sub 3} in the parts per million range. The latter forming binary clusters with water, our results provide a plausible pathway for the efficient nucleation recently observed in laser filaments.

Petit, Yannick; Henin, Stefano; Kasparian, Jerome; Wolf, Jean-Pierre [GAP Biophotonics, Universite de Geneve, 20 rue de l'Ecole de Medecine, CH1211 Geneve 4 (Switzerland)

2010-07-12T23:59:59.000Z

279

THE FAR-INFRARED ROTATIONAL SPECTRUM OF ETHYLENE OXIDE  

SciTech Connect (OSTI)

High-resolution FTIR spectra of ethylene oxide have been measured in the far-infrared region using synchrotron radiation. A total of 1182 lines between 15 and 73 cm{sup -1} were assigned, with J{sub max} = 64, expanding upon previous studies that had recorded spectra up to 12 cm{sup -1}, J{sub max} = 49. All available data were co-fitted to provide greatly imp- roved rotational constants for the ground vibrational state that are capable of predicting transitions up to 73 cm{sup -1}.

Medcraft, Chris; Thompson, Christopher D.; McNaughton, Don [School of Chemistry, Monash University, Wellington Road, Clayton, Victoria 3800 (Australia); Robertson, Evan G. [Department of Chemistry, La Trobe Institute of Molecular Sciences, La Trobe University, Bundoora, Victoria 3086 (Australia); Appadoo, Dominique R. T., E-mail: donald.mcnaughton@monash.edu [Australian Synchrotron, 800 Blackburn Road, Clayton, Victoria 3168 (Australia)

2012-07-01T23:59:59.000Z

280

Evaporative oxidation treatability test report  

SciTech Connect (OSTI)

In 1992, Congress passed the Federal Facilities Compliance Act that requires the U.S. Department of Energy (DOE) to treat and dispose of its mixed waste in accordance with the Resource Conservation and Recovery Act (RCRA) land disposal restrictions (LDRs). In response to the need for mixed-waste treatment capacity where available off-site commercial treatment facilities do not exist or cannot be used, the DOE Albuquerque Operations Office (DOE-AL) organized a Treatment Selection Team to match mixed wastes with treatment options and develop a strategy for treatment of its mixed wastes. DOE-AL manages operations at nine sites with mixed-waste inventories. The Treatment Selection Team determined a need to develop mobile treatment capacity to treat wastes at the sites where the wastes are generated. Treatment processes used for mixed waste not only must address the hazardous component (i.e., meet LDRs) but also must contain the radioactive component in a form that allows final disposal while protecting workers, the public, and the environment. On the basis of recommendations of the Treatment Selection Team, DOE-AL assigned projects to the sites to bring mixed-waste treatment capacity on-line. The three technologies assigned to the DOE Grand Junction Projects Office (GJPO) are evaporative oxidation, thermal desorption, and treated wastewater evaporation. Rust Geotech, the DOE-GJPO prime contractor, was assigned to design and fabricate mobile treatment units (MTUs) for these three technologies and to deliver the MTUs to selected DOE-AL sites. To conduct treatability tests at the GJPO, Rust leased a pilot-scale evaporative oxidation unit from the Clemson Technical Center (CTC), Anderson, South Carolina. The purpose of this report is to document the findings and results of tests performed using this equipment.

NONE

1995-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "measures miec oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

EIA - Greenhouse Gas Emissions - Nitrous Oxide Emissions  

Gasoline and Diesel Fuel Update (EIA)

4. Nitrous Oxide Emissions 4. Nitrous Oxide Emissions 4.1 Total emissions U.S. nitrous oxide emissions in 2009 were 4 MMTCO2e (1.7 percent) below their 2008 total (Table 22). Sources of U.S. nitrous oxide emissions include agriculture, energy use, industrial processes, and waste management (Figure 22). The largest source is agriculture (73 percent), and the majority of agricultural emissions result from nitrogen fertilization of agricultural soils (87 percent of the agriculture total) and management of animal waste (13 percent). U.S. nitrous oxide emissions rose from 1990 to 1994, fell from 1994 to 2002, and returned to an upward trajectory from 2003 to 2007, largely as a result of increased use of synthetic fertilizers. Fertilizers are the primary contributor of emissions from nitrogen fertilization of soils, which grew by more than 30 percent from

282

Two Dimensional Polymer That Generates Nitric Oxide.  

DOE Patents [OSTI]

A polymeric composition that generates nitric oxide and a process for rendering the surface of a substrate nonthrombogenic by applying a coating of the polymeric composition to the substrate are disclosed. The composition comprises: (1) a crosslinked chemical combination of (i) a polymer having amino group-containing side chains along a backbone forming the polymer, and (ii) a crosslinking agent containing functional groups capable of reacting with the amino groups; and (2) a plurality of nitric oxide generating functional groups associated with the crosslinked chemical combination. Once exposed to a physiological environment, the coating generates nitric oxide thereby inhibiting platelet aggregation. In one embodiment, the nitric oxide generating functional groups are provided by a nitrated compound (e.g., nitrocellulose) imbedded in the polymeric composition. In another embodiment, the nitric oxide generating functional groups comprise N2O2- groups covalently bonded to amino groups on the polymer.

McDonald, William F. (Utica, OH); Koren, Amy B. (Lansing, MI)

2005-10-04T23:59:59.000Z

283

Revealing the Nature of Emergent Ferromagnetism at an Oxide Heterointe...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of thin-film structures 6-8. LaAlO3 (lanthanum aluminium oxide, LAO) and SrTiO3 (strontium titanium oxide, STO) materials are perovskites, a class of mineral oxides whose...

284

Graphene oxide-based materials : synthesis, characterization and applications.  

E-Print Network [OSTI]

??In this study, the properties and applications of graphene oxide-based materials have been explored. Specifically, graphene oxide, i.e. a single layer of graphite oxide, reduced… (more)

Zhou, Xiaozhu.

2010-01-01T23:59:59.000Z

285

Detection of natural oxidation of coking coal by TG-FTIR—mechanistic implications  

Science Journals Connector (OSTI)

The natural oxidation/weathering of coal continues to be a subject of interest both scientifically and industrially, in part due to the complexity of the molecular processes at hand as well as to the commercial implications involved. It is widely recognized that coking can be adversely affected by weathering whereas, combustion processes appear to be enhanced as result of oxidation. Combustion techniques are commonly used in the analysis of coal, and organic compounds in general, for the determination of elemental hydrogen, carbon and nitrogen. For oxygen, the method in common practice involves the determination by difference from directly determined values for moisture, ash, sulphur, hydrogen, carbon and nitrogen. This has led us to consider the use of thermogravimetry coupled to gas analysis by infrared spectroscopy (TG-FTIR) to measure organic oxygen in coal directly. Although this technique, developed by Solomon and coworkers, has been extensively used by our group and others, it appears not to have been considered for this particular purpose. Recently, we have shown that TG-FTIR is capable of measuring all the organic oxygen in both fresh and oxidized coal by simultaneous measurement of the three main oxygen-containing gases H2O, CO and CO2 evolved during rapid pyrolysis. This gives us a way of measuring quantitatively the oxygen introduced into the coal matrix during oxidation and at least a partial capability of establishing oxygen speciation. We have found, using TG-FTIR, that the early stages of coal oxidation results in the appearance of O-containing functional groups not present in the original coal. The nature of these functional groups is directly related to the oxidation reaction mechanism. These results will be presented and discussed in detail.

J.A. MacPhee; L. Giroux; J.-P. Charland; J.F. Gransden; J.T. Price

2004-01-01T23:59:59.000Z

286

OXIDATION OF MERCURY ACROSS SCR CATALYSTS IN COAL-FIRED POWER PLANTS BURNING LOW RANK FUELS  

SciTech Connect (OSTI)

The objectives of this program were to measure the oxidation of mercury in flue gas across SCR catalyst in a coal-fired power plant burning low rank fuels using a slipstream reactor containing multiple commercial catalysts in parallel and to develop a greater understanding of mercury oxidation across SCR catalysts in the form of a simple model. The Electric Power Research Institute (EPRI) and Argillon GmbH provided co-funding for this program. REI used a multicatalyst slipstream reactor to determine oxidation of mercury across five commercial SCR catalysts at a power plant that burned a blend of 87% subbituminous coal and 13% bituminous coal. The chlorine content of the blend was 100 to 240 {micro}g/g on a dry basis. Mercury measurements were carried out when the catalysts were relatively new, corresponding to about 300 hours of operation and again after 2,200 hours of operation. NO{sub x}, O{sub 2} and gaseous mercury speciation at the inlet and at the outlet of each catalyst chamber were measured. In general, the catalysts all appeared capable of achieving about 90% NO{sub x} reduction at a space velocity of 3,000 hr{sup -1} when new, which is typical of full-scale installations; after 2,200 hours exposure to flue gas, some of the catalysts appeared to lose NO{sub x} activity. For the fresh commercial catalysts, oxidation of mercury was in the range of 25% to 65% at typical full-scale space velocities. A blank monolith showed no oxidation of mercury under any conditions. All catalysts showed higher mercury oxidation without ammonia, consistent with full-scale measurements. After exposure to flue gas for 2,200 hours, some of the catalysts showed reduced levels of mercury oxidation relative to the initial levels of oxidation. A model of Hg oxidation across SCRs was formulated based on full-scale data. The model took into account the effects of temperature, space velocity, catalyst type and HCl concentration in the flue gas.

Constance Senior

2004-12-31T23:59:59.000Z

287

Ethylene oxidation in a well-stirred reactor  

SciTech Connect (OSTI)

The detailed ethylene oxidation data set of Thornton, obtained for a well-stirred reactor operated fuel-lean at atmospheric pressure and for temperatures of 1003K to 1253K, is used as a basis for the comparison of chemical kinetic mechanisms reported in the literature and for the development of a new ethylene oxidation mechanism. The mechanisms examined are those of Westbrook and Pitz and Dagaut et al. These mechanisms indicated that unusually large rates for the vinyl decomposition reaction are required to obtain agreement with the Thornton data set. A new ethylene oxidation mechanism is developed in order to overcome some of the drawbacks of the previous mechanisms. The new mechanism closely simulates the overall rate of loss of ethylene, and the concentation of CO, CO{sub 2}, H{sub 2}, CH{sub 2}O, C{sub 2}H{sub 2}, CH{sub 3}OH, CH{sub 4}, and C{sub 2}H{sub 6} measured for the stirred reactor. Predictions by this mechanism are dependent on a new high temperature vinyl oxidation route, C{sub 2}H{sub 3} + O{sub 2} = CH{sub 2}CHO + O with a k{sub C2H3+O2=CH2CHO+O}/k{sub C2H3+O2=CH2O+HCO} branching ratio of 1.20 at 1053K to 2.05 at 1253K. The branching ratio values were dependent upon the extent of fall-off for the C{sub 2}H{sub 3} + O{sub 2} = CH{sub 2}O + HCO reaction.

Marinov, N.M. [Lawrence Livermore National Lab., CA (United States); Malte, P.C. [Washington Univ., Seattle, WA (United States). Dept. of Mechanical Engineering

1994-10-01T23:59:59.000Z

288

Influence of NaCl on cathode performance of solid oxide fuel cells  

Science Journals Connector (OSTI)

Degradation induced by sodium chloride in air was...0.8Sr0.2)0.98MnO3(LSM) and La0.6Sr0.4Co0.2Fe0.8O3(LSCF) cathodes in solid oxide fuel cells(SOFC). Cell performance was measured by volatilizing NaCl to...2...fo...

Run-ru Liu; De-jun Wang; Jing Leng

2013-08-01T23:59:59.000Z

289

Transition metal-catalyzed oxidation of atmospheric sulfur: Global implications for the sulfur budget  

E-Print Network [OSTI]

of the oxygen-17 excess (D17 O) of sulfate in the Arctic to quantify the sulfate source from aqueous SO2 (S concentrations, respectively. The solubility and oxidation state of these metals is determined by cloud liquid discrepancies with surface SO2 and sulfate observations in Europe. Oxygen isotope measurements of sulfate

Alexander, Becky

290

Two-dimensional Electron Liquid State at Oxide Interfaces J. Mannhart  

E-Print Network [OSTI]

Two-dimensional Electron Liquid State at Oxide Interfaces J. Mannhart Max Planck InstituteAlO3 #12;LaAlO3 - SrTiO3 YBa2Cu3O7 G. Hammerl #12;Interfaces with Standard Semiconductors: Space Charge;Conductance-voltage characteristics It/ Vs Vs were measured using a standard lock-in technique.24 Simulta

Yeh, Nai-Chang

291

Kinetic effects of non-equilibrium plasma-assisted methane oxidation on diffusion flame extinction limits  

E-Print Network [OSTI]

. The prod- ucts of plasma assisted CH4 oxidation were measured using the Two-photon Absorption Laser to understand the role of plasma generated species on ignition, flame speed, and flame stabilization. For ignition studies, the reduction of ignition delay time by non-equilibrium nanosecond pulsed discharges

Ju, Yiguang

292

Author's personal copy Highly active surfaces for CO oxidation on Rh, Pd, and Pt  

E-Print Network [OSTI]

to that found at ultrahigh vacuum (UHV) condi- tions [4]. In contrast, for Ru the reaction mechanism is dra- matically different for CO oxidation at UHV conditions and at atmospheric conditions [14,25]. In UHV, Ru that measured in UHV. The signif- icantly higher activity near one atmosphere at stoichiome- tric reaction

Goodman, Wayne

293

Preparation and evaluation of novel hydrous metal oxide (HMO)-supported noble metal catalysts  

SciTech Connect (OSTI)

Hydrous Metal Oxides (HMOs) are chemically synthesized materials that, because of their high cation exchange capacity, possess a unique ability to allow the preparation of highly dispersed supported-metal catalyst precursors with high metal loadings. This study evaluates high weight loading Rh/HMO catalysts with a wide range of HMO support compositions, including hydrous titanium oxide (HTO), silica-doped hydrous titanium oxide (HTO:Si), hydrous zirconium oxide (HZO), and silica-doped hydrous zirconium oxide (HZO:Si), against conventional oxide-supported Rh catalysts with similar weight loadings and support chemistries. Catalyst activity measurements for a structure-sensitive model reaction (n-butane hydrogenolysis) as a function of catalyst activation conditions show superior activity and stability for the ZrO{sub 2}, HZO, and HZO:Si supports, although all of the Rh/HMO catalysts have high ethane selectivity indicative of high Rh dispersion. For the TiO{sub 2}-, HTO-, and HTO:Si supported Rh catalysts, a significant loss of both catalyst activity and Rh dispersion is observed at more aggressive activation conditions, consistent with TiO{sub x} migration associated with SMSI phenomena. Of all the Rh/HMO catalysts, the Rh/HZO:Si catalysts appear to offer the best tradeoff in terms of high Rh dispersion, high activity, and high selectivity.

Gardner, T.J.; McLaughlin, L.I.; Evans, L.R. [Sandia National Labs., Albuquerque, NM (United States). Catalysis and Chemical Technologies Dept.; Datye, A.K. [Univ. of New Mexico, Albuquerque, NM (United States)

1998-04-01T23:59:59.000Z

294

Wiremesh Substrates for Enhanced Particulate Oxidation and Efficient...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Wiremesh Substrates for Enhanced Particulate Oxidation and Efficient Urea SCR NOx Reduction Wiremesh Substrates for Enhanced Particulate Oxidation and Efficient Urea SCR NOx...

295

High surface area, electrically conductive nanocarbon-supported metal oxide  

DOE Patents [OSTI]

A metal oxide-carbon composite includes a carbon aerogel with an oxide overcoat. The metal oxide-carbon composite is made by providing a carbon aerogel, immersing the carbon aerogel in a metal oxide sol under a vacuum, raising the carbon aerogel with the metal oxide sol to atmospheric pressure, curing the carbon aerogel with the metal oxide sol at room temperature, and drying the carbon aerogel with the metal oxide sol to produce the metal oxide-carbon composite. The step of providing a carbon aerogel can provide an activated carbon aerogel or provide a carbon aerogel with carbon nanotubes that make the carbon aerogel mechanically robust.

Worsley, Marcus A; Han, Thomas Yong-Jin; Kuntz, Joshua D; Cervanted, Octavio; Gash, Alexander E; Baumann, Theodore F; Satcher, Jr., Joe H

2014-03-04T23:59:59.000Z

296

Polyelectrolyte-Induced Reduction of Exfoliated Graphite Oxide...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reduction of Exfoliated Graphite Oxide: A Facile Route to Synthesis of Soluble Graphene Nanosheets. Polyelectrolyte-Induced Reduction of Exfoliated Graphite Oxide: A Facile...

297

Rational Catalyst Design Applied to Development of Advanced Oxidation...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Catalyst Design Applied to Development of Advanced Oxidation Catalysts for Diesel Emission Control Rational Catalyst Design Applied to Development of Advanced Oxidation...

298

Effects of Diesel Exhaust Emissions on Soot Oxidation and DPF...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Diesel Exhaust Emissions on Soot Oxidation and DPF Regeneration Effects of Diesel Exhaust Emissions on Soot Oxidation and DPF Regeneration DPF regeneration experiments verified the...

299

Arginine-Containing Ligands Enhance H-2 Oxidation Catalyst Performance...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Arginine-Containing Ligands Enhance H-2 Oxidation Catalyst Performance. Arginine-Containing Ligands Enhance H-2 Oxidation Catalyst Performance. Abstract: In H2 fuel cells,...

300

Cryogenic CO2 Formation on Oxidized Gold Clusters Synthesized...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Cryogenic CO2 Formation on Oxidized Gold Clusters Synthesized via Reactive Layer Assisted Deposition. Cryogenic CO2 Formation on Oxidized Gold Clusters Synthesized via Reactive...

Note: This page contains sample records for the topic "measures miec oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Photoluminescence Properties of Alkaline-Earth Oxide Nanoparticles...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Properties of Alkaline-Earth Oxide Nanoparticles. Photoluminescence Properties of Alkaline-Earth Oxide Nanoparticles. Abstract: Previous experiments have demonstrated that...

302

Robust control strategies for hybrid solid oxide fuel cell systems.  

E-Print Network [OSTI]

??Solid Oxide Fuel Cell (SOFC) systems are electrochemical energy conversion devices characterized by the use of solid oxide as the electrolyte. They operate at high… (more)

Mathew, Anju Ann

2010-01-01T23:59:59.000Z

303

Biostimulation of Iron Reduction and Subsequent Oxidation of...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Biostimulation of Iron Reduction and Subsequent Oxidation of Sediment Containing Fe-silicates and Fe-oxides: Effect of Redox Biostimulation of Iron Reduction and Subsequent...

304

Graphene/metal Oxide Nanocomposites for Li-ion Batteries  

Science Journals Connector (OSTI)

Our work focuses on preparing the graphene/metal oxide nanocomposites by facile methold and exploring the graphene/metal oxide composites with unique structural or compositions for...

Liang, Junfei; Li, Lidong; Guo, Lin

305

Enzyme-free Detection of Hydrogen Peroxide from Cerium Oxide...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

free Detection of Hydrogen Peroxide from Cerium Oxide Nanoparticles Immobilized on Poly(4-vinylpyridine) Self-Assembled Enzyme-free Detection of Hydrogen Peroxide from Cerium Oxide...

306

Impact of the Fuel Molecular Structure on the Oxidation Process...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Oxidation Process of Real Diesel fuels According to Storage Conditions and Biodiesel Content Impact of the Fuel Molecular Structure on the Oxidation Process of Real Diesel fuels...

307

EIS-0360: Depleted Uranium Oxide Conversion Product at the Portsmouth...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

60: Depleted Uranium Oxide Conversion Product at the Portsmouth, Ohio Site EIS-0360: Depleted Uranium Oxide Conversion Product at the Portsmouth, Ohio Site Summary This...

308

Solid Oxide Membrane (SOM) Electrolysis of Magnesium: Scale-Up...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Solid Oxide Membrane (SOM) Electrolysis of Magnesium: Scale-Up Research and Engineering for Light-Weight Vehicles Solid Oxide Membrane (SOM) Electrolysis of Magnesium: Scale-Up...

309

Interactions of nickel/zirconia solid oxide fuel cell anodes...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Interactions of nickelzirconia solid oxide fuel cell anodes with coal gas containing arsenic. Interactions of nickelzirconia solid oxide fuel cell anodes with coal gas containing...

310

Advanced Oxidation & Stabilization of PAN-Based Carbon Precursor...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications Advanced Oxidation & Stabilization of PAN-Based Carbon Precursor Fibers Advanced Oxidation & Stabilization of PAN-Based Carbon Precursor...

311

Advanced Oxidation & Stabilization of PAN-Based Carbon Precursor...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications Advanced Oxidation & Stabilization of PAN-Based Carbon Precursor Fibers Vehicle Technologies Office Merit Review 2014: Advanced Oxidation &...

312

Radiation Stability of Nanoclusters in Nano-structured Oxide...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Stability of Nanoclusters in Nano-structured Oxide Dispersion Strengthened (ODS) Steels. Radiation Stability of Nanoclusters in Nano-structured Oxide Dispersion Strengthened (ODS)...

313

Understanding Atom Probe Tomography of Oxide-Supported Metal...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Atom Probe Tomography of Oxide-Supported Metal Nanoparticles by Correlation with Atomic Resolution Electron Understanding Atom Probe Tomography of Oxide-Supported Metal...

314

Taking snapshots of different redox states of the water oxidation...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

natural photosynthetic water oxidation mechanism empowers designers of artificial photosynthesis with knowledge to construct better water oxidation catalysts for solar fuel...

315

High-Affinity and Cooperative Binding of Oxidized Calmodulin by Methionine Sulfoxide Reductase  

SciTech Connect (OSTI)

Methionines play an important role in modulating protein-protein interactions associated with intracellular signaling, and their reversible oxidation to form methionine sulfoxides [Met(O)] in calmodulin (CaM) and other signaling proteins has been suggested to couple cellular redox changes to protein function changes through the action of methionine sulfoxide reductases (Msr). Prior measurements indicate the full recovery of target protein activation upon the stereospecific reduction of oxidized CaM by MsrA, where the formation of the S-stereoisomer of Met(O) selectively inhibits the CaM-dependent activation of the Ca-ATPase. However, the physiological substrates of MsrA remain unclear, as neither the binding specificities nor affinities of protein targets have been measured. To assess the specificity of binding and its possible importance in the maintenance of CaM function, we have measured the kinetics of repair and the binding affinity between oxidized CaM and MsrA. Reduction of Met(O) in fully oxidized CaM by MsrA is sensitive to protein folding, as repair of the intact protein is incomplete, with > 6 Met(O) remaining in each CaM following MsrA reduction. In contrast, following proteolytic digestion, MsrA is able to fully reduce one-half of the oxidized methionines, indicating that Met(O) within folded proteins are not substrates for MsrA repair. Further, in comparison to free Met(O), the turnover number and Km for oxidized CaM (CaMox) are substantially smaller, indicating that the binding interaction retards Msr recycling to reduce steady-state enzyme activity. Mutation of the active site (i.e., C72S) in MsrA permitted equilibrium-binding measurements using both ensemble and single-molecule measurements obtained by fluorescence correlation spectroscopy (FCS). Multiple MsrA bind tightly to CaMox (Kd = 70 +- 10 nM) with an affinity that is three orders of magnitude greater than the Michaelis constant (KM = 71 +- 8 micromolar). These results indicate that MsrA selectively reduces surface-exposed Met(O) within unstructured sequences and suggest that only a small subset of oxidized proteins are substrates for MsrA, which may selectively modulate the function of key signaling proteins as part of an adaptive response to oxidative stress.

Xiong, Yijia; Chen, Baowei; Smallwood, Heather S.; Urbauer, Ramona J.; Markillie, Lye Meng; Galeva, Nadezhda A.; Williams, Todd D.; Squier, Thomas C.

2006-12-12T23:59:59.000Z

316

Emergent Phenomena at Oxide Interfaces  

SciTech Connect (OSTI)

Transition metal oxides (TMOs) are an ideal arena for the study of electronic correlations because the s-electrons of the transition metal ions are removed and transferred to oxygen ions, and hence the strongly correlated d-electrons determine their physical properties such as electrical transport, magnetism, optical response, thermal conductivity, and superconductivity. These electron correlations prohibit the double occupancy of metal sites and induce a local entanglement of charge, spin, and orbital degrees of freedom. This gives rise to a variety of phenomena, e.g., Mott insulators, various charge/spin/orbital orderings, metal-insulator transitions, multiferroics, and superconductivity. In recent years, there has been a burst of activity to manipulate these phenomena, as well as create new ones, using oxide heterostructures. Most fundamental to understanding the physical properties of TMOs is the concept of symmetry of the order parameter. As Landau recognized, the essence of phase transitions is the change of the symmetry. For example, ferromagnetic ordering breaks the rotational symmetry in spin space, i.e., the ordered phase has lower symmetry than the Hamiltonian of the system. There are three most important symmetries to be considered here. (i) Spatial inversion (I), defined as r {yields} -r. In the case of an insulator, breaking this symmetry can lead to spontaneous electric polarization, i.e. ferroelectricity, or pyroelectricity once the point group belongs to polar group symmetry. (ii) Time-reversal symmetry (T) defined as t {yields} -t. In quantum mechanics, the time-evolution of the wave-function {Psi} is given by the phase factor e{sup -iEt/{h_bar}} with E being the energy, and hence time-reversal basically corresponds to taking the complex conjugate of the wave-function. Also the spin, which is induced by the 'spinning' of the particle, is reversed by time-reversal. Broken T-symmetry is most naturally associated with magnetism, since the spin operator changes sign with T-operation. (iii) Gauge symmetry (G), which is associated with a change in the phase of the wave-function as {Psi} {yields} e{sup i{theta}}{Psi}. Gauge symmetry is connected to the law of charge conservation, and broken G-symmetry corresponds to superconductivity/superfluidity. To summarize, the interplay among these electronic degrees of freedom produces various forms of symmetry breaking patterns of I, T, and G, leading to novel emergent phenomena, which can appear only by the collective behavior of electrons and cannot be expected from individual electrons. Figure 1 shows this schematically by means of several representative phenomena. From this viewpoint, the interfaces of TMOs offer a unique and important laboratory because I is already broken by the structure itself, and the detailed form of broken I-symmetry can often be designed. Also, two-dimensionality usually enhances the effects of electron correlations by reducing their kinetic energy. These two features of oxide interfaces produce many novel effects and functions that cannot be attained in bulk form. Given that the electromagnetic responses are a major source of the physical properties of solids, and new gauge structures often appear in correlated electronic systems, we put 'emergent electromagnetism' at the center of Fig. 1.

Hwang, H.Y.

2012-02-16T23:59:59.000Z

317

The cycling and oxidation pathways of organic carbon in a shallow estuary along the Texas Gulf Coast  

SciTech Connect (OSTI)

The cycling and oxidation pathways of organic carbon were investigated at a single shallow water estuarine site in Trinity Bay, Texas, the uppermost lobe of Galveston Bay, during November 2000. Radio-isotopes were used to estimate sediment mixing and accumulation rates, and benthic chamber and pore water measurements were used to determine sediment-water exchange fluxes of oxygen, nutrients and metals, and infer carbon oxidation rates.

Warnken, Kent W.; Santschi, Peter H.; Roberts, Kimberly A.; Gill, Gary A.

2007-08-08T23:59:59.000Z

318

Origin of the 871-keV gamma ray and the ``oxide'' attribute  

SciTech Connect (OSTI)

This work concludes the investigation of the oxide attribute of current interest for the characterization of stored plutonium. Originally it was believed that the presence of oxide could be ascertained by measurement of the 871-keV line in a high-resolution gamma-ray spectrum. However, recent work has suggested that the 871-keV gamma ray in plutonium oxide arises from the reaction {sup 14}N({alpha},p){sup 17}O rather than the inelastic scattering reaction {sup 17}O({alpha},{alpha}{prime}){sup 17}O*. This conclusion, though initially surprising, was obtained during efforts to determine the relative importance of americium and plutonium alpha-particle decay for the production of the 871-keV gamma ray. Several questions were raised by previous experiments: What role, if any does {sup 17}O have in the generation of the 871-keV gamma ray? How does sufficient nitrogen come to be present in plutonium oxide? Under what conditions is the 871-keV gamma ray measurable in plutonium oxide? This paper describes the answers to these questions.

AJ Peurrung; RJ Arthur; BD Geelhood; RD Scheele; RJ Elovich; SL Pratt

2000-03-22T23:59:59.000Z

319

Apparatus for making cathodo- and photo- luminescent measurements of thin film phosphors  

E-Print Network [OSTI]

the understanding of the thin film phosphor, tungsten doped zinc oxide. Principally, a vacuum system is constructed and provides for both photo-and cathode-phosphor excitations. A measurement capability is then included. Finally, additions are mentioned...

Babuchna, Paul Michael

1998-01-01T23:59:59.000Z

320

E-Print Network 3.0 - atpase binding measured Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

dependence of Na,K-ATPase... activity was measured at 37 jC using an assay that coupled ATP hydrolysis to NADH oxidation 25. Na,K-ATPase... and ouabain-insensitive ... Source:...

Note: This page contains sample records for the topic "measures miec oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Structural Characterization and Catalytic Activity of Nanosized CexM1-xO2 (M = Zr and Hf) Mixed Oxides  

Science Journals Connector (OSTI)

RS measurements suggest a defective structure of the mixed oxides resulting in the formation of oxygen vacancies. ... Improvements in such features are currently in demand for designing better catalytic cartridges for new-generation cleaner cars. ...

Benjaram M. Reddy; Pankaj Bharali; Pranjal Saikia; Sang-Eon Park; Maurits W. E. van den Berg; Martin Muhler; Wolfgang Grünert

2008-07-16T23:59:59.000Z

322

Direct atomic-scale observation of layer-by-layer oxide growth during magnesium oxidation  

SciTech Connect (OSTI)

The atomic-scale oxide growth dynamics are directly revealed by in situ high resolution transmission electron microscopy during the oxidation of Mg surface. The oxidation process is characterized by the layer-by-layer growth of magnesium oxide (MgO) nanocrystal via the adatom process. Consistently, the nucleated MgO crystals exhibit faceted surface morphology as enclosed by (200) lattice planes. It is believed that the relatively lower surface energies of (200) lattice planes should play important roles, governing the growth mechanism. These results facilitate the understanding of the nanoscale oxide growth mechanism that will have an important impact on the development of magnesium or magnesium alloys with improved resistance to oxidation.

Zheng, He; Wu, Shujing; Sheng, Huaping; Liu, Chun; Liu, Yu; Cao, Fan; Zhou, Zhichao; Zhao, Dongshan, E-mail: wang@whu.edu.cn, E-mail: dszhao@whu.edu.cn; Wang, Jianbo, E-mail: wang@whu.edu.cn, E-mail: dszhao@whu.edu.cn [School of Physics and Technology, Center for Electron Microscopy and MOE Key Laboratory of Artificial Micro- and Nano-structures, Wuhan University, Wuhan 430072 (China); Zhao, Xingzhong [School of Physics and Technology, Key Laboratory of Artificial Micro- and Nano-Structures of Ministry of Education, Wuhan University, Wuhan 430072 (China)

2014-04-07T23:59:59.000Z

323

Green method to produce propylene oxide  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Materials Materials Argonne National Laboratory Center for Nanoscale Materials U.S. Department of Energy Search CNM ... Search Argonne Home > Center for Nanoscale Materials > CNM Home About CNM Research Facilities People For Users Publications News & Highlights News Research Highlights Newsletters CNM Images on Flickr Events Jobs CNM Users Organization Contact Us Other DOE Nanoscale Science Research Centers Green method to produce propylene oxide conversion of propylene to polyene oxide via silver nanoclusters Simulation of propylene to propylene oxide conversion via silver nanoclusters supported on an alumina surface. Propylene oxide is an important chemical whose current industrial production is energy intensive and environmentally unfriendly. Attempts to solve this problem by using catalysts based on bulk silver surfaces with

324

Why Sequence Sulfur-Oxidizing Bacteria?  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sulfur-Oxidizing Bacteria? Sulfur-Oxidizing Bacteria? Several environmental problems, such as acid rain, biocorrosion, etc., are caused by sulfur compounds, such as sulfur dioxide (SO2) and hydrogen sulfide (H2S). A sustainable process to remove these sulfur compounds is the production of elemental sulfur from H2S-containing gas streams by the use of sulfide-oxidizing bacteria. In this process, H2S is absorbed into the alkaline solution in the scrubber unit, followed by the biological oxidation of H2S to elemental sulfur and the recycling of water. With this two-step process, a variety of gas streams (i.e., natural gas, synthesis gas, biogas, and refinery gas) can be treated. For the treatment of sulfate-containing waste streams, an extra step has to be introduced: the transformation of sulfate into H2S by sulfate-reducing bacteria. In

325

Iridium material for hydrothermal oxidation environments  

DOE Patents [OSTI]

A process for hydrothermal oxidation of combustible materials in which, during at least a part of the oxidation, corrosive material is present and makes contact with at least a portion of the apparatus over a contact area on the apparatus. At least a portion of the contact surface area comprises iridium, iridium oxide, an iridium alloy, or a base metal overlaid with an iridium coating. Iridium has been found to be highly resistant to environments encountered in the process of hydrothermal oxidation. Such environments typically contain greater than 50 mole percent water, together with oxygen, carbon dioxide, and a wide range of acids, bases and salts. Pressures are typically about 27.5 to about 1000 bar while temperatures range as high as 800.degree. C.

Hong, Glenn T. (Tewksbury, MA); Zilberstein, Vladimir A. (Brookline, MA)

1996-01-01T23:59:59.000Z

326

Degenerate cadmium oxide films for electronic devices  

Science Journals Connector (OSTI)

Highly conducting and transparent cadmium oxide films have been deposited on Corning 7059 glass substrates by ion-beam sputtering and by spray pyrolysis. The electrical and optical properties of CdO films prep...

T. L. Chu; Shirley S. Chu

327

Nitrogen oxide delivery systems for biological media  

E-Print Network [OSTI]

Elevated levels of nitric oxide (NO) in vivo are associated with a variety of cellular modifications thought to be mutagenic or carcinogenic. These processes are likely mediated by reactive nitrogen species (RNS) such as ...

Skinn, Brian Thomas

2012-01-01T23:59:59.000Z

328

Assessment of Oxidation in Carbon Foam  

E-Print Network [OSTI]

Carbon foams exhibit numerous unique properties which are attractive for light weight applications such as aircraft and spacecraft as a tailorable material. Carbon foams, when exposed to air, oxidize at temperatures as low as 500-600 degrees Celsius...

Lee, Seung Min

2010-07-14T23:59:59.000Z

329

Metallic Materials in Solid Oxide Fuel Cells  

Science Journals Connector (OSTI)

Fe-Cr alloys with variations in chromium content and additions of different elements were studied for potential application in intermediate temperature Solid Oxide Fuel Cell (SOFC). Recently, a new type of FeC...

V. Shemet; J. Piron-Abellan; W.J. Quadakkers…

2005-01-01T23:59:59.000Z

330

Modeling of solid oxide fuel cells  

E-Print Network [OSTI]

A comprehensive membrane-electrode assembly (MEA) model of Solid Oxide Fuel Cell (SOFC)s is developed to investigate the effect of various design and operating conditions on the cell performance and to examine the underlying ...

Lee, Won Yong, S.M. Massachusetts Institute of Technology

2006-01-01T23:59:59.000Z

331

Oxidation of methionine residues in protein pharmaceuticals  

E-Print Network [OSTI]

(cont.) of free methionine. Therefore, the environments surrounding different methionine sites in G-CSF mainly provide spatial restriction to the access to the solvent but do not affect oxidation in a specific manner, ...

Chu, Jhih-Wei, 1973-

2004-01-01T23:59:59.000Z

332

Bringing oxides into the visible realm | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

visible realm Bringing oxides into the visible realm Reducing the optical band gap of strontium titanate thin films This is a model of the growth process showing one lanthanum and...

333

Oxidized coal in coking: A review  

Science Journals Connector (OSTI)

A literature review shows that the oxidation of coal changes its granulometric composition, packing density, ... clinkering properties, the quality of the resulting coke, and the yield of coking byproducts. On ac...

N. A. Desna; D. V. Miroshnichenko

2011-05-01T23:59:59.000Z

334

Interfacial material for solid oxide fuel cell  

DOE Patents [OSTI]

Solid oxide fuel cells having improved low-temperature operation are disclosed. In one embodiment, an interfacial layer of terbia-stabilized zirconia is located between the air electrode and electrolyte of the solid oxide fuel cell. The interfacial layer provides a barrier which controls interaction between the air electrode and electrolyte. The interfacial layer also reduces polarization loss through the reduction of the air electrode/electrolyte interfacial electrical resistance. In another embodiment, the solid oxide fuel cell comprises a scandia-stabilized zirconia electrolyte having high electrical conductivity. The scandia-stabilized zirconia electrolyte may be provided as a very thin layer in order to reduce resistance. The scandia-stabilized electrolyte is preferably used in combination with the terbia-stabilized interfacial layer. The solid oxide fuel cells are operable over wider temperature ranges and wider temperature gradients in comparison with conventional fuel cells.

Baozhen, Li (Essex Junction, VT); Ruka, Roswell J. (Pittsburgh, PA); Singhal, Subhash C. (Murrysville, PA)

1999-01-01T23:59:59.000Z

335

Structural Determination of Marine Bacteriogenic Manganese Oxides  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

fig 2 Figure 2. (A) X-ray diffraction intensity data for bacteriogenic manganese oxides produced in sea water. The bottom pattern is for clean cells. (B) X-ray diffraction...

336

Microsecond Catalytic Partial Oxidation of Alkanes  

Science Journals Connector (OSTI)

...HICKMAN A. D. , PRODUCTION OF SYNGAS BY DIRECT CATALYTIC-OXIDATION OF METHANE...PFEFFERLE D. L. , CATALYSIS IN COMBUSTION , CATALYSIS...a-alu-mina monoliths coated with Rh (for syngas) (1, 2) or with Pt (for olefins...

Duane A. Goetsch; Lanny D. Schmidt

1996-03-15T23:59:59.000Z

337

Removing sulphur oxides from a fluid stream  

DOE Patents [OSTI]

A process for removing sulphur oxides from a fluid stream, such as flue gas, comprising: providing a non-aqueous absorption liquid containing at least one hydrophobic amine, the liquid being incompletely miscible with water; treating the fluid stream in an absorption zone with the non-aqueous absorption liquid to transfer at least part of the sulphur oxides into the non-aqueous absorption liquid and to form a sulphur oxide-hydrophobic amine-complex; causing the non-aqueous absorption liquid to be in liquid-liquid contact with an aqueous liquid whereby at least part of the sulphur oxide-hydrophobic amine-complex is hydrolyzed to release the hydrophobic amine and sulphurous hydrolysis products, and at least part of the sulphurous hydrolysis products is transferred into the aqueous liquid; separating the aqueous liquid from the non-aqueous absorption liquid. The process mitigates absorbent degradation problems caused by sulphur dioxide and oxygen in flue gas.

Katz, Torsten; Riemann, Christian; Bartling, Karsten; Rigby, Sean Taylor; Coleman, Luke James Ivor; Lail, Marty Alan

2014-04-08T23:59:59.000Z

338

Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons  

DOE Patents [OSTI]

Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons is carried out over metal vanadate catalysts under oxidizing conditions. The vanadate catalysts are represented by the formulas M[sub 3](VO[sub 4])[sub 2] and MV[sub 2]O[sub 6], M representing Mg, Zn, Ca, Pb, or Cd. The reaction is carried out in the presence of oxygen, but the formation of oxygenate by-products is suppressed.

Kung, H.H.; Chaar, M.A.

1988-10-11T23:59:59.000Z

339

Three-Electrode Metal Oxide Reduction Cell  

DOE Patents [OSTI]

A method of electrochemically reducing a metal oxide to the metal in an electrochemical cell is disclosed along with the cell. Each of the anode and cathode operate at their respective maximum reaction rates. An electrolyte and an anode at which oxygen can be evolved, and a cathode including a metal oxide to be reduced are included as is a third electrode with independent power supplies connecting the anode and the third electrode and the cathode and the third electrode.

Dees, Dennis W. (Downers Grove, IL); Ackerman, John P. (Downers Grove, IL)

2005-06-28T23:59:59.000Z

340

Synthesis and processing of monosized oxide powders  

DOE Patents [OSTI]

Uniform-size, high-purity, spherical oxide powders are formed by hydrolysis of alkoxide precursors in dilute alcoholic solutions. Under controlled conditions (concentrations of 0.03 to 0.2 M alkoxide and 0.2 to 1.5 M water, for example) oxide particles on the order of about 0.05 to 0.7 micron can be produced. Methods of doping such powders and forming sinterable compacts are also disclosed.

Barringer, Eric A. (Waltham, MA); Fegley, Jr., M. Bruce (Waban, MA); Bowen, H. Kent (Belmont, MA)

1985-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "measures miec oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Process for etching mixed metal oxides  

DOE Patents [OSTI]

An etching process using dicarboxylic and tricarboxylic acids as chelating etchants for mixed metal oxide films such as high temperature superconductors and ferroelectric materials. Undesirable differential etching rates between different metal oxides are avoided by selection of the proper acid or combination of acids. Feature sizes below one micron, excellent quality vertical edges, and film thicknesses in the 100 Angstom range may be achieved by this method.

Ashby, Carol I. H. (Edgewood, NM); Ginley, David S. (Evergreen, CO)

1994-01-01T23:59:59.000Z

342

Superconductive articles including cerium oxide layer  

DOE Patents [OSTI]

A ceramic superconductor comprising a metal oxide substrate, a ceramic high temperature superconductive material, and a intermediate layer of a material having a cubic crystal structure, said layer situated between the substrate and the superconductive material is provided, and a structure for supporting a ceramic superconducting material is provided, said structure comprising a metal oxide substrate, and a layer situated over the surface of the substrate to substantially inhibit interdiffusion between the substrate and a ceramic superconducting material deposited upon said structure.

Wu, Xin D. (Greenbelt, MD); Muenchausen, Ross E. (Espanola, NM)

1993-01-01T23:59:59.000Z

343

Steam Oxidation of Advanced Steam Turbine Alloys  

SciTech Connect (OSTI)

Power generation from coal using ultra supercritical steam results in improved fuel efficiency and decreased greenhouse gas emissions. Results of ongoing research into the oxidation of candidate nickel-base alloys for ultra supercritical steam turbines are presented. Exposure conditions range from moist air at atmospheric pressure (650°C to 800°C) to steam at 34.5 MPa (650°C to 760°C). Parabolic scale growth coupled with internal oxidation and reactive evaporation of chromia are the primary corrosion mechanisms.

Holcomb, Gordon R.

2008-01-01T23:59:59.000Z

344

Three-electrode metal oxide reduction cell  

DOE Patents [OSTI]

A method of electrochemically reducing a metal oxide to the metal in an electrochemical cell is disclosed along with the cell. Each of the anode and cathode operate at their respective maximum reaction rates. An electrolyte and an anode at which oxygen can be evolved, and a cathode including a metal oxide to be reduced are included as is a third electrode with independent power supplies connecting the anode and the third electrode and the cathode and the third electrode.

Dees, Dennis W. (Downers Groves, IL); Ackerman, John P. (Downers Grove, IL)

2008-08-12T23:59:59.000Z

345

SOFTWARE RELATEDSOFTWARE-RELATED MEASUREMENT:MEASUREMENT  

E-Print Network [OSTI]

SOFTWARE RELATEDSOFTWARE-RELATED MEASUREMENT:MEASUREMENT: RISKS AND OPPORTUNITIES CEM KANER, J and lazy? Most managers who I know have tried at least oney g measurement program--and abandoned them: · Measurement theory and how it applies to software development metrics (which, at their core, are typically

346

Band offsets of ultrathin high-{kappa} oxide films with Si  

SciTech Connect (OSTI)

Valence- and conduction-band edges of ultrathin oxides (SiO{sub 2}, HfO{sub 2}, Hf{sub 0.7}Si{sub 0.3}O{sub 2}, ZrO{sub 2}, and Al{sub 2}O{sub 3}) grown on a silicon substrate have been measured using ultraviolet photoemission and inverse photoemission spectroscopies in the same UHV chamber. The combination of these two techniques has enabled the direct determination of the oxide energy gaps as well as the offsets of the oxide valence- and conduction-band edges from those of the silicon substrate. These results are supplemented with synchrotron x-ray photoemission spectroscopy measurements allowing further characterization of the oxide composition and the evaluation of the silicon substrate contribution to the spectra. The electron affinity has also been systematically measured on the same samples. We find reasonably good agreement with earlier experiments where assumptions regarding energy-gap values were needed to establish the conduction-band offsets. The systematics of our photoemission and inverse photoemission results on different ultrathin films provide a comprehensive comparison of these related systems.

Bersch, Eric; Rangan, Sylvie; Bartynski, Robert Allen; Garfunkel, Eric; Vescovo, Elio [Department of Physics and Astronomy and Laboratory for Surface Modification, Rutgers University, 136 Frelinghuysen Road, Piscataway, New Jersey 08854 (United States); Department of Chemistry and Chemical Biology and Laboratory for Surface Modification, Rutgers University, 610 Taylor Road, Piscataway, New Jersey 08854 (United States); National Synchrotron Light Source, Brookhaven National Laboratory, Upton, New York 11973 (United States)

2008-08-15T23:59:59.000Z

347

Ethylene oxide and Acetaldehyde in hot cores  

E-Print Network [OSTI]

[Abridged] Ethylene oxide and its isomer acetaldehyde are important complex organic molecules because of their potential role in the formation of amino acids. Despite the fact that acetaldehyde is ubiquitous in the interstellar medium, ethylene oxide has not yet been detected in cold sources. We aim to understand the chemistry of the formation and loss of ethylene oxide in hot and cold interstellar objects (i) by including in a revised gas-grain network some recent experimental results on grain surfaces and (ii) by comparison with the chemical behaviour of its isomer, acetaldehyde. We test the code for the case of a hot core. The model allows us to predict the gaseous and solid ethylene oxide abundances during a cooling-down phase prior to star formation and during the subsequent warm-up phase. We can therefore predict at what temperatures ethylene oxide forms on grain surfaces and at what temperature it starts to desorb into the gas phase. The model reproduces the observed gaseous abundances of ethylene oxid...

Occhiogrosso, A; Herbst, E; Viti, S; Ward, M D; Price, S D; Brown, W A

2014-01-01T23:59:59.000Z

348

Solid oxide fuel cell with monolithic core  

DOE Patents [OSTI]

A solid oxide fuel cell in which fuel and oxidant gases undergo an electrochemical reaction to produce an electrical output includes a monolithic core comprised of a corrugated conductive sheet disposed between upper and lower generally flat sheets. The corrugated sheet includes a plurality of spaced, parallel, elongated slots which form a series of closed, linear, first upper and second lower gas flow channels with the upper and lower sheets within which a fuel gas and an oxidant gas respectively flow. Facing ends of the fuel cell are generally V-shaped and provide for fuel and oxidant gas inlet and outlet flow, respectively, and include inlet and outlet gas flow channels which are continuous with the aforementioned upper fuel gas and lower oxidant gas flow channels. The upper and lower flat sheets and the intermediate corrugated sheet are preferably comprised of ceramic materials and are securely coupled together such as by assembly in the green state and sintering together during firing at high temperatures. A potential difference across the fuel cell, or across a stacked array of similar fuel cells, is generated when an oxidant gas such as air and a fuel such as hydrogen gas is directed through the fuel cell at high temperatures, e.g., between 700 C and 1,100 C. 8 figs.

McPheeters, C.C.; Mrazek, F.C.

1988-08-02T23:59:59.000Z

349

Solid oxide fuel cell with monolithic core  

DOE Patents [OSTI]

A solid oxide fuel cell in which fuel and oxidant gases undergo an electrochemical reaction to produce an electrical output includes a monolithic core comprised of a corrugated conductive sheet disposed between upper and lower generally flat sheets. The corrugated sheet includes a plurality of spaced, parallel, elongated slots which form a series of closed, linear, first upper and second lower gas flow channels with the upper and lower sheets within which a fuel gas and an oxidant gas respectively flow. Facing ends of the fuel cell are generally V-shaped and provide for fuel and oxidant gas inlet and outlet flow, respectively, and include inlet and outlet gas flow channels which are continuous with the aforementioned upper fuel gas and lower oxidant gas flow channels. The upper and lower flat sheets and the intermediate corrugated sheet are preferably comprised of ceramic materials and are securely coupled together such as by assembly in the green state and sintering together during firing at high temperatures. A potential difference across the fuel cell, or across a stacked array of similar fuel cells, is generated when an oxidant gas such as air and a fuel such as hydrogen gas is directed through the fuel cell at high temperatures, e.g., between 700.degree. C. and 1100.degree. C.

McPheeters, Charles C. (Plainfield, IL); Mrazek, Franklin C. (Hickory Hills, IL)

1988-01-01T23:59:59.000Z

350

Conversion of a regenerative oxidizer into catalytic unit  

SciTech Connect (OSTI)

Use of a VOC oxidation catalyst in the existing regenerative thermal oxidizers may greatly reduce fuel consumption and improve the oxidizer performance. This was demonstrated in a commercial 25,000 SCFM unit installed at a printing facility. The paper discusses the principles of the oxidizer retrofit design and test results obtained at various conditions of operation.

Matros, Y.S.; Bunimovich, G.A.; Strots, V.O. [Matros Technologies, Chesterfield, MO (United States)] [and others

1997-12-31T23:59:59.000Z

351

Reactivity and Transformation of Antibacterial N-Oxides in the  

E-Print Network [OSTI]

shown in Figure 1) represent organic N-oxides that are common in many pharmaceuticals, agrochemicals

Huang, Ching-Hua

352

Catalytic oxidation of light alkanes in presence of a base  

DOE Patents [OSTI]

The presence of a base in the reaction mixture in a metal-ligand catalyzed partial oxidation of alkanes results in sustained catalyst activity, and in greater percent conversion as compared with oxidation in the absence of base, while maintaining satisfactory selectivity for the desired oxidation, for example the oxidation of isobutane to isobutanol.

Bhinde, Manoj V. (Boothwyn, PA); Bierl, Thomas W. (West Chester, PA)

1998-01-01T23:59:59.000Z

353

Catalytic oxidation of light alkanes in presence of a base  

DOE Patents [OSTI]

The presence of a base in the reaction mixture in a metal-ligand catalyzed partial oxidation of alkanes results in sustained catalyst activity, and in greater percent conversion as compared with oxidation in the absence of base, while maintaining satisfactory selectivity for the desired oxidation, for example the oxidation of isobutane to isobutanol. 1 fig.

Bhinde, M.V.; Bierl, T.W.

1998-03-03T23:59:59.000Z

354

Methods of producing adsorption media including a metal oxide  

DOE Patents [OSTI]

Methods of producing a metal oxide are disclosed. The method comprises dissolving a metal salt in a reaction solvent to form a metal salt/reaction solvent solution. The metal salt is converted to a metal oxide and a caustic solution is added to the metal oxide/reaction solvent solution to adjust the pH of the metal oxide/reaction solvent solution to less than approximately 7.0. The metal oxide is precipitated and recovered. A method of producing adsorption media including the metal oxide is also disclosed, as is a precursor of an active component including particles of a metal oxide.

Mann, Nicholas R; Tranter, Troy J

2014-03-04T23:59:59.000Z

355

An experimental and kinetic modelling study of the oxidation of the four isomers of butanol  

E-Print Network [OSTI]

Butanol, an alcohol which can be produced from biomass sources, has received recent interest as an alternative to gasoline for use in spark ignition engines and as a possible blending compound with fossil diesel or biodiesel. Therefore, the autoignition of the four isomers of butanol (1-butanol, 2-butanol, iso-butanol, and tert-butanol) has been experimentally studied at high temperatures in a shock tube and a kinetic mechanism for description of their high-temperature oxidation has been developed. Ignition delay times for butanol/oxygen/argon mixtures have been measured behind reflected shock waves at temperatures and pressures ranging from approximately 1200 to 1800 K and 1 to 4 bar. Electronically excited OH emission and pressure measurements were used to determine ignition delay times. A detailed kinetic mechanism has been developed to describe the oxidation of the butanol isomers and validated by comparison to the shock tube measurements. Reaction flux and sensitivity analysis indicate that the consumpti...

Moss, J T; Oehlschlaeger, M A; Biet, Joffrey; Warth, Valérie; Glaude, Pierre-Alexandre; Battin-Leclerc, Frédérique; 10.1021/jp806464p

2008-01-01T23:59:59.000Z

356

Real-Time Redox Measurements during Endoplasmic Reticulum Stress Reveal  

E-Print Network [OSTI]

Real-Time Redox Measurements during Endoplasmic Reticulum Stress Reveal Interlinked Protein Folding.10.011 SUMMARY Disruption of protein folding in the endoplasmic reticulum (ER) causes unfolded proteins to accumu is active. Because ER redox po- tential is optimized for oxidative protein folding, we reasoned

Mullins, Dyche

357

Polymorphous Transformations of Nanometric Iron(III) Oxide: A Review  

Science Journals Connector (OSTI)

Because of its polymorphism, iron(III) oxide (ferric oxide, Fe2O3) is one of the most interesting and potentially useful phases of the iron oxides. ... Structural and magnetic properties, methods of synthesis, and applications of seven Fe(III) oxide polymorphs, including rare beta, epsilon, amorphous, and high-pressure forms, are reviewed. ... Films of ?-Fe2O3 nanoparticles were synthesized by oxidizing Fe films rapidly in air. ...

Libor Machala; Ji?í Tu?ek; Radek Zbo?il

2011-06-01T23:59:59.000Z

358

Development of Vanadium Phosphaate Catalysts for Methanol Production by Selective Oxidation of Methane.  

SciTech Connect (OSTI)

This DOE sponsored study of methane partial oxidation was initiated at Amax Research and Development in Golden, CO in October of 1993. Shortly thereafter the management of Amax closed this R&D facility and the PI moved to the Colorado School of Mines. The project was begun again after contract transfer via a novation agreement. Experimental work began with testing of vandyl pyrophosphate (VPO), a well known alkane selective oxidation catalyst. It was found that VPO was not a selective catalyst for methane conversion yielding primarily CO. However, promotion of VPO with Fe, Cr, and other first row transition metals led to measurable yields for formaldehyde, as noted in the summary table. Catalyst characterization studies indicated that the role of promoters was to stabilize some of the vanadium in the V{sup 5+} oxidation state rather than the V{sup 4+} state formally expected for (VO){sub 2}P{sub 2}O{sub 7}.

McCormick, R.L.

1997-10-01T23:59:59.000Z

359

Growth and properties of crystalline barium oxide on the GaAs(100) substrate  

SciTech Connect (OSTI)

Growing a crystalline oxide film on III-V semiconductor renders possible approaches to improve operation of electronics and optoelectronics heterostructures such as oxide/semiconductor junctions for transistors and window layers for solar cells. We demonstrate the growth of crystalline barium oxide (BaO) on GaAs(100) at low temperatures, even down to room temperature. Photoluminescence (PL) measurements reveal that the amount of interface defects is reduced for BaO/GaAs, compared to Al{sub 2}O{sub 3}/GaAs, suggesting that BaO is a useful buffer layer to passivate the surface of the III-V device material. PL and photoemission data show that the produced junction tolerates the post heating around 600?°C.

Yasir, M.; Dahl, J.; Lång, J.; Tuominen, M.; Punkkinen, M. P. J.; Laukkanen, P., E-mail: pekka.laukkanen@utu.fi; Kokko, K. [Department of Physics and Astronomy, University of Turku, FI-20014 Turku (Finland)] [Department of Physics and Astronomy, University of Turku, FI-20014 Turku (Finland); Kuzmin, M. [Department of Physics and Astronomy, University of Turku, FI-20014 Turku (Finland) [Department of Physics and Astronomy, University of Turku, FI-20014 Turku (Finland); Ioffe Physical-Technical Institute, Russian Academy of Sciences, St. Petersburg 194021 (Russian Federation); Korpijärvi, V.-M.; Polojärvi, V.; Guina, M. [Optoelectronics Research Centre, Tampere University of Technology, FI-33101 Tampere (Finland)] [Optoelectronics Research Centre, Tampere University of Technology, FI-33101 Tampere (Finland)

2013-11-04T23:59:59.000Z

360

Vibration Measurement and Monitoring  

Science Journals Connector (OSTI)

Successful vibration measurement and analysis require an intimate familiarity with types of measurement, transducer characteristics and application, plus the...

V. Schlegel

1984-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "measures miec oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Heterodyne vibration measurement  

Science Journals Connector (OSTI)

Analytic expressions are derived for the vibration amplitude and frequency in a heterodyne measurement method. The measurement accuracy is estimated.

A. A. Titov

1993-08-01T23:59:59.000Z

362

Assessor Training Measurement Uncertainty  

E-Print Network [OSTI]

NVLAP Assessor Training Measurement Uncertainty #12;Assessor Training 2009: Measurement Uncertainty Training 2009: Measurement Uncertainty 3 Measurement Uncertainty ·Calibration and testing labs performing Training 2009: Measurement Uncertainty 4 Measurement Uncertainty ·When the nature of the test precludes

363

Structure and Electronic Configurations of the Intermediates of Water Oxidation in Blue Ruthenium Dimer Catalysis  

SciTech Connect (OSTI)

Catalytic O{sub 2} evolution with cis,cis-[(bpy){sub 2}(H{sub 2}O)Ru{sup III}ORu{sup III}(OH{sub 2})(bpy){sub 2}]{sup 4+} (bpy is 2,2-bipyridine), the so-called blue dimer, the first designed water oxidation catalyst, was monitored by UV-vis, EPR, and X-ray absorption spectroscopy (XAS) with ms time resolution. Two processes were identified, one of which occurs on a time scale of 100 ms to a few seconds and results in oxidation of the catalyst with the formation of an intermediate, here termed [3,4]'. A slower process occurring on the time scale of minutes results in the decay of this intermediate and O{sub 2} evolution. Spectroscopic data suggest that within the fast process there is a short-lived transient intermediate, which is a precursor of [3,4]'. When excess oxidant was used, a highly oxidized form of the blue dimer [4,5] was spectroscopically resolved within the time frame of the fast process. Its structure and electronic state were confirmed by EPR and XAS. As reported earlier, the [3,4]' intermediate likely results from reaction of [4,5] with water. While it is generated under strongly oxidizing conditions, it does not display oxidation of the Ru centers past [3,4] according to EPR and XAS. EXAFS analysis demonstrates a considerably modified ligand environment in [3,4]'. Raman measurements confirmed the presence of the O-O fragment by detecting a new vibration band in [3,4]' that undergoes a 46 cm{sup -1} shift to lower energy upon {sup 16}O/{sup 18}O exchange. Under the conditions of the experiment at pH 1, the [3,4]' intermediate is the catalytic steady state form of the blue dimer catalyst, suggesting that its oxidation is the rate-limiting step.

Moonshiram, Dooshaye; Jurss, Jonah W.; Concepcion, Javier J.; Zakharova, Taisiya; Alperovich, Igor; Meyer, Thomas J.; Pushkar, Yulia (Purdue); (UNC)

2013-04-08T23:59:59.000Z

364

Effect of Substrate Thickness on Oxide Scale Spallation for Solid Oxide Fuel Cells  

SciTech Connect (OSTI)

In this paper, the effect of the ferritic substrate's thickness on the delamination/spallation of the oxide scale was investigated experimentally and numerically. At the high-temperature oxidation environment of solid oxide fuel cells (SOFCs), a combination of growth stress with thermal stresses may lead to scale delamination/buckling and eventual spallation during SOFC stack cooling, even leading to serious degradation of cell performance. The growth stress is induced by the growth of the oxide scale on the scale/substrate interface, and thermal stress is induced by a mismatch of the coefficient of thermal expansion between the oxide scale and the substrate. The numerical results show that the interfacial shear stresses, which are the driving force of scale delamination between the oxide scale and the ferritic substrate, increase with the growth of the oxide scale and also with the thickness of the ferritic substrate; i.e., the thick ferritic substrate can easily lead to scale delamination and spallation. Experimental observation confirmed the predicted results of the delamination and spallation of the oxide scale on the ferritic substrate.

Liu, Wenning N.; Sun, Xin; Stephens, Elizabeth V.; Khaleel, Mohammad A.

2011-07-01T23:59:59.000Z

365

Method for facilitating catalyzed oxidation reactions, device for facilitating catalyzed oxidation reactions  

DOE Patents [OSTI]

A catalytic process for the oxidation of organic. Oxygen is loaded into a metal foil by heating the foil while in contact with an oxygen-containing fluid. After cooling the oxygen-activated foil to room temperature, oxygen diffuses through the foil and oxidizes reactants exposed to the other side of the foil.

Beuhler, Robert J. (East Moriches, NY); White, Michael G. (Blue Point, NY); Hrbek, Jan (Rocky Point, NY)

2006-08-15T23:59:59.000Z

366

Nano-sized manganese oxides as biomimetic catalysts for water oxidation in artificial photosynthesis: a review  

Science Journals Connector (OSTI)

...review-article Review articles 1004 30 36 15 Nano-sized manganese oxides as biomimetic...of about approximately 0.5 nm. Thus, nano-sized manganese compounds might be good...particles. In this paper, we focus on nano-sized manganese oxides as functional...

2012-01-01T23:59:59.000Z

367

Aromatic hydroxylation. 8. A radiation chemical study of the oxidation of hydroxycyclohexadienyl radicals  

SciTech Connect (OSTI)

Substituted hydroxycyclohexadienyl radicals have been generated by pulse radiolysis of N/sub 2/O-saturated aqueous solutions of monosubstituted benzene derivatives. Their rates of disproportionation/dimerization and of oxidation by Fe(CN)/sub 6//sup 3 -/ and by IrCl/sub 6//sup 2 -/ have been measured by optical and conductimetric methods. For the fluoro- and chlorohydroxycyclohexadienyl radicals disproportionation is shown to involve hydrogen atom abstraction rather than electron transfer. However, the Fe(CN)/sub 6//sup 3 -/ oxidation of the substituted hydroxycyclohexadienyl radicals occurs by a rate-determining electron transfer followed by a fast proton loss rather than by hydrogen atom abstraction or synchronous removal of an electron and a proton. A plot of the log of the rate constants for oxidation against Hammett sigma/sup +/ constants gives a good linear relationship with a rho value of -3.0 +/- 0.1. With the more powerful oxidant IrCl/sub 6//sup -/, the electron-transfer oxidation of all but the least reactive hydroxycyclohexadienyl radicals is diffusion controlled.

Buxton, G.V.; Langan, J.R.; Smith, J.R.L.

1986-11-06T23:59:59.000Z

368

IMPACTS OF ANTIFOAM ADDITIONS AND ARGON BUBBLING ON DEFENSE WASTE PROCESSING FACILITY REDUCTION/OXIDATION  

SciTech Connect (OSTI)

During melting of HLW glass, the REDOX of the melt pool cannot be measured. Therefore, the Fe{sup +2}/{Sigma}Fe ratio in the glass poured from the melter must be related to melter feed organic and oxidant concentrations to ensure production of a high quality glass without impacting production rate (e.g., foaming) or melter life (e.g., metal formation and accumulation). A production facility such as the Defense Waste Processing Facility (DWPF) cannot wait until the melt or waste glass has been made to assess its acceptability, since by then no further changes to the glass composition and acceptability are possible. therefore, the acceptability decision is made on the upstream process, rather than on the downstream melt or glass product. That is, it is based on 'feed foward' statistical process control (SPC) rather than statistical quality control (SQC). In SPC, the feed composition to the melter is controlled prior to vitrification. Use of the DWPF REDOX model has controlled the balanjce of feed reductants and oxidants in the Sludge Receipt and Adjustment Tank (SRAT). Once the alkali/alkaline earth salts (both reduced and oxidized) are formed during reflux in the SRAT, the REDOX can only change if (1) additional reductants or oxidants are added to the SRAT, the Slurry Mix Evaporator (SME), or the Melter Feed Tank (MFT) or (2) if the melt pool is bubble dwith an oxidizing gas or sparging gas that imposes a different REDOX target than the chemical balance set during reflux in the SRAT.

Jantzen, C.; Johnson, F.

2012-06-05T23:59:59.000Z

369

Electrical conductivity in oxygen-deficient phases of transition metal oxides from first-principles calculations.  

SciTech Connect (OSTI)

Density-functional theory calculations, ab-initio molecular dynamics, and the Kubo-Greenwood formula are applied to predict electrical conductivity in Ta2Ox (0x5) as a function of composition, phase, and temperature, where additional focus is given to various oxidation states of the O monovacancy (VOn; n=0,1+,2+). Our calculations of DC conductivity at 300K agree well with experimental measurements taken on Ta2Ox thin films and bulk Ta2O5 powder-sintered pellets, although simulation accuracy can be improved for the most insulating, stoichiometric compositions. Our conductivity calculations and further interrogation of the O-deficient Ta2O5 electronic structure provide further theoretical basis to substantiate VO0 as a donor dopant in Ta2O5 and other metal oxides. Furthermore, this dopant-like behavior appears specific to neutral VO cases in both Ta2O5 and TiO2 and was not observed in other oxidation states. This suggests that reduction and oxidation reactions may effectively act as donor activation and deactivation mechanisms, respectively, for VO0 in transition metal oxides.

Bondi, Robert James; Desjarlais, Michael Paul; Thompson, Aidan Patrick; Brennecka, Geoffrey L.; Marinella, Matthew

2013-09-01T23:59:59.000Z

370

Synthesis and characterizations of graphene oxide and reduced graphene oxide nanosheets  

SciTech Connect (OSTI)

Interest in graphene on its excellent mechanical, electrical, thermal and optical properties, it’s very high specific surface area, and our ability to influence these properties through chemical functionalization. Chemical reduction of graphene oxide is one of the main routes of preparation for large quantities of graphenes. Hydrazine hydrate used as reducing agent to prepare for the reduced graphene oxide (RGO). There are a number of methods for generating graphene and chemically modified graphene from natural graphite flakes, graphite derivative (such as graphite oxide) and graphite interaction compounds (i.e. expandable graphite). Here we review the use of colloidal suspensions of reduced graphene oxide (RGO) with large scalable, and is adaptable to a wide variety of applications. The graphene oxide (GO) and the reduced material (RGO) were characterized by XRD, UV-Vis spectroscopy, Thermo-gravimetric analysis (TGA), Raman spectroscopy and Field emission Scanning electron microscopy (FESEM) etc.

Venkanna, M., E-mail: venkanna.pcu@gmail.com; Chakraborty, Amit K., E-mail: venkanna.pcu@gmail.com [Carbon Nanotechnology Laboratory, Department of Physics, National Institute of Technology Durgapur, M.G. Avenue, Durgapur - 713209 (India)

2014-04-24T23:59:59.000Z

371

Inhibition of Oxidation in Nuclear Graphite  

SciTech Connect (OSTI)

Graphite is a fundamental material of high temperature gas cooled nuclear reactors, providing both structure and neutron moderation. Its high thermal conductivity, chemical inertness, thermal heat capacity, and high thermal structural stability under normal and off normal conditions contribute to the inherent safety of these reactor designs. One of the primary safety issues for a high temperature graphite reactor core is the possibility of rapid oxidation of the carbon structure during an off normal design basis event where an oxidizing atmosphere (air ingress) can be introduced to the hot core. Although the current Generation IV high temperature reactor designs attempt to mitigate any damage caused by a postualed air ingress event, the use of graphite components that inhibit oxidation is a logical step to increase the safety of these reactors. Recent experimental studies of graphite containing between 5.5 and 7 wt% boron carbide (B4C) indicate that oxidation is dramatically reduced even at prolonged exposures at temperatures up to 900°C. The proposed addition of B4C to graphite components in the nuclear core would necessarily be enriched in B-11 isotope in order to minimize B-10 neutron absorption and graphite swelling. The enriched boron can be added to the graphite during billet fabrication. Experimental oxidation rate results and potential applications for borated graphite in nuclear reactor components will be discussed.

Phil Winston; James W. Sterbentz; William E. Windes

2013-10-01T23:59:59.000Z

372

The effect of thermo-oxidation on plasma performance and in-vessel components in DIII-D  

SciTech Connect (OSTI)

In April 2010, two thermo-oxidation experiments ('O-bakes') were performed in the DIII-D tokamak. Internal surfaces of the tokamak, as well as a number of specimens inserted into the torus, were exposed to a mixture of 20% O2/80% He at a nominal pressure of 9.5 Torr (1.27 kPa) at a temperature of 350 360 C for a duration of 2 h. Three primary conclusions have been drawn from these experiments: (1) laboratory measurements on the release of deuterium from tokamak codeposits by oxidation have been duplicated in a tokamak environment, (2) no internal tokamak components or systems were adversely affected by the oxidation and (3) the recovery of plasma performance following oxidation was similar to that following regular torus openings.

Allen, S. L. [Lawrence Livermore National Laboratory (LLNL); Fitzpatrick, B. W. N. [University of Toronto, Institute for Aerospace Studies, Canada; Davis, J. W. [University of Toronto, Canada; Brooks, N. H. [General Atomics, San Diego; Chrobak, C P [General Atomics, San Diego; Ellis, R [Lawrence Livermore National Laboratory (LLNL); Haasz, A. A. [University of Toronto, Canada; Jackson, G. L. [General Atomics; Leonard, A. W. [General Atomics; McLean, A. G. [Oak Ridge National Laboratory (ORNL); Rudakov, D. L. [University of California, San Diego; Stangeby, P. C. [University of Toronto, Canada; Tsui, C. [University of Toronto, Canada; Umstadter, K. [University of California, San Diego; Unterberg, Ezekial A [ORNL; Wampler, W. R. [Sandia National Laboratories (SNL)

2013-01-01T23:59:59.000Z

373

MERCURY OXIDIZATION IN NON-THERMAL PLASMA BARRIER DISCHARGE SYSTEM  

SciTech Connect (OSTI)

In the past decade, the emission of toxic elements from human activities has become a matter of great public concern. Hg, As, Se and Cd typically volatilize during a combustion process and are not easily caught with conventional air pollution control techniques. In addition, there is no pollution prevention technique available now or likely be available in the foreseeable future that can prevent the emission of these trace elements. These trace elements pose additional scientific challenge as they are present at only ppb levels in large gas streams. Mercury, in particular, has attracted significant attention due to its high volatility, toxicity and potential threat to human health. In the present research work, a non-thermal plasma dielectric barrier discharge technique has been used to oxidize Hg{sup 0}(g) to HgO. The basic premise of this approach is that Hg{sup 0} in vapor form cannot be easily removed in an absorption tower whereas HgO as a particulate is amiable to water scrubbing. The work presented in this report consists of three steps: (1) setting-up of an experimental apparatus to generate mercury vapors at a constant rate and modifying the existing non-thermal plasma reactor system, (2) solving the analytical challenge for measuring mercury vapor concentration at ppb level, and (3) conducting experiments on mercury oxidation under plasma conditions to establish proof of concept.

V.K. Mathur

2003-02-01T23:59:59.000Z

374

Stress and phase transformation phenomena in oxide films  

SciTech Connect (OSTI)

In situ optical methods are reviewed for characterization of phase transformation processes and evaluation of residual stress in solution- deposited metastable oxide films. Such low density films most often are deposited as disordered phases making them prone to crystallization and attendant densification when subjected to increased temperature and/or applied pressure. Inherent stress imparted during film deposition and its evolution during the transformation are evaluated from phonon frequency shifts seen in Raman spectra (TiO{sub 2}) or from changes in the laser-induced fluorescence emission spectra for films containing rare earth (Sm{sup +3}:Y{sub 3}Al{sub 5}O{sub 12}) or transition metal (Cr{sup +3}:Al{sub 2}O{sub 3}) dopants. The data in combination with measured increases in line intensities intrinsic to the evolving phase are used to follow crystallization processes in thin films. In general, film deposition parameters are found to influence the crystallite ingrowth kinetics and the magnitude of stress and stress relaxation in the film during the transformation. The utility of these methods to probe crystallization phenomena in oxide films will be addressed.

Exarhos, G.J.; Hess, N.J.

1992-04-01T23:59:59.000Z

375

SUITABILITY OF MAGNESIUM OXIDE AS A VISAR WINDOW  

SciTech Connect (OSTI)

Impedance matching of a velocity interferometer for any reflector (VISAR) window to a material under study helps simplify a shock experiment by effectively allowing one to measure an in situ particle velocity. The shock impedance of magnesium oxide (MgO) falls roughly midway between those of sapphire and LiF, two of the most frequently used VISAR window materials. A series of symmetric impact experiments was performed to characterize the suitability of single crystal, (100) oriented magnesium oxide as a VISAR window material. These experiments yielded good results and show the viability of MgO as a VISAR window up to 23 GPa. Results were used to determine window correction factors and, subsequently, to estimate the pressure induced change in index of refraction. In many of the shots in this work we exceeded the Hugoniot elastic limit (HEL) of MgO, and both elastic and plastic waves are evident in the velocity profiles. The presence of both waves within the VISAR window complicates the typical VISAR window correction analysis. Preliminary analysis of the elastic and plastic contributions to the window correction is presented.

G. D. Stevens; L. R. Veeser; P. A. Rigg; R. S. Hixson

2005-01-01T23:59:59.000Z

376

Effect of oxidizing environment on the strength and oxidation kinetics of HTGR graphites. Part I. Reactivity and strength loss of H451, PGX and IG-11 graphites  

SciTech Connect (OSTI)

The effects of oxidizing atmosphere and temperature on the reactivities and strengths of PGX, H451, and IG-11 were examined. Preliminary measurements of the oxidation kinetics of these graphites in H/sub 2/O-, CO/sub 2/- and O/sub 2/-containing atmospheres indicated that the reactivities of H451 graphite toward O/sub 2/ and H/sub 2/O are quite similar to those of IG-11 graphite. The apparent activation energy for oxidation of these in O/sub 2/ were estimated to be approx. 175 kJ/mol while that in H/sub 2/O is probably approx. 200 kJ/mol. The apparent activation energy of IG-11 graphite oxidized in CO/sub 2/ is 255 +- 18 kJ/mol. PGX graphite was found to be quite variable in its reactivity toward H/sub 2/O. A linear dependence with (Fe) was determined, but other intrinsic properties were found to affect its absolute reactivity by as much as a factor of X50.

Eto, M.; Growcock, F.B.

1981-09-01T23:59:59.000Z

377

Solid Oxide Fuel Cells | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Solid Oxide Fuel Cells Solid Oxide Fuel Cells Solid Oxide Fuel Cells FE researchers at NETL have developed a unique test platform, called the multi-cell array (MCA), to rapidly test multiple fuel cells and determine how they degrade when contaminants exist in the fuel stream, such as might occur when using syngas from a coal gasifier. FE researchers at NETL have developed a unique test platform, called the multi-cell array (MCA), to rapidly test multiple fuel cells and determine how they degrade when contaminants exist in the fuel stream, such as might occur when using syngas from a coal gasifier. Fuel cells are an energy user's dream: an efficient, combustion-less, virtually pollution-free power source, capable of being sited in downtown urban areas or in remote regions that runs almost silently and has few

378

Why Sequence a Methane-Oxidizing Archaean?  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

a Methane-Oxidizing Archaeon? a Methane-Oxidizing Archaeon? Methane is a potent greenhouse gas whose atmospheric concentration has increased significantly because of anthropogenic activities and fluctuated naturally over glacial and interglacial cycles. While the importance of methane in Earth's climate dynamics has been well established, the global processes regulating its oceanic cycling remain poorly understood. Although there are high rates of methane production in many marine sedimentary environments (including a number that have been targeted as petroleum reserves), net methane sources from the ocean to the atmosphere appear to be small. This is due in large part to a biogeochemical process known as the anaerobic oxidation of methane (AOM). Microbially mediated AOM reduces methane flux from ocean to atmosphere, stimulates subsurface microbial

379

Lithium metal oxide electrodes for lithium batteries  

DOE Patents [OSTI]

An uncycled electrode for a non-aqueous lithium electrochemical cell including a lithium metal oxide having the formula Li.sub.(2+2x)/(2+x)M'.sub.2x/(2+x)M.sub.(2-2x)/(2+x)O.sub.2-.delta., in which 0.ltoreq.x<1 and .delta. is less than 0.2, and in which M is a non-lithium metal ion with an average trivalent oxidation state selected from two or more of the first row transition metals or lighter metal elements in the periodic table, and M' is one or more ions with an average tetravalent oxidation state selected from the first and second row transition metal elements and Sn. Methods of preconditioning the electrodes are disclosed as are electrochemical cells and batteries containing the electrodes.

Thackeray, Michael M. (Naperville, IL); Kim, Jeom-Soo (Naperville, IL); Johnson, Christopher S. (Naperville, IL)

2008-01-01T23:59:59.000Z

380

Method for fluorination of uranium oxide  

DOE Patents [OSTI]

Highly pure uranium hexafluoride is made from uranium oxide and fluorine. The uranium oxide, which includes UO.sub.3, UO.sub.2, U.sub.3 O.sub.8 and mixtures thereof, is introduced together with a small amount of a fluorine-reactive substance, selected from alkali chlorides, silicon dioxide, silicic acid, ferric oxide, and bromine, into a constant volume reaction zone. Sufficient fluorine is charged into the zone at a temperature below approximately 0.degree. C. to provide an initial pressure of at least approximately 600 lbs/sq. in. at the ambient atmospheric temperature. The temperature is then allowed to rise in the reaction zone until reaction occurs.

Petit, George S. (Oak Ridge, TN)

1987-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "measures miec oxides" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
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381

In situ oxidation of subsurface formations  

DOE Patents [OSTI]

Methods and systems for treating a hydrocarbon containing formation described herein include providing heat to a first portion of the formation from a plurality of heaters in the first portion, producing produced through one or more production wells in a second portion of the formation, reducing or turning off heat provided to the first portion after a selected time, providing an oxidizing fluid through one or more of the heater wells in the first portion, providing heat to the first portion and the second portion through oxidation of at least some hydrocarbons in the first portion, and producing fluids through at least one of the production wells in the second portion. The produced fluids may include at least some oxidized hydrocarbons produced in the first portion.

Beer, Gary Lee (Houston, TX); Mo, Weijian (Sugar Land, TX); Li, Busheng (Houston, TX); Shen, Chonghui (Calgary, CA)

2011-01-11T23:59:59.000Z

382

OXIDATION OF DRY HYDROCARBONS AT HIGH-POWER DENSITY ANODES  

SciTech Connect (OSTI)

This work builds upon discoveries by the University of Pennsylvania and others pertaining to the oxidation of dry hydrocarbon fuels in high temperature solid oxide fuel cells. The work reported here was restricted primarily to dry methane and confirms that YSZ-based cells, having ceria in the anode as a catalyst and copper in the anode as a current collector, can operate on dry methane for extended periods. Thirty-three lab-scale cells of various designs were fabricated and operated under a variety of conditions. The longest-lived cell gave stable performance on dry methane at 800 C for over 305 hours. Only slight carbon deposition was noted at the completion of the test. A corresponding nickel/YSZ-based anode would have lasted for less than an hour under these test conditions (which included open circuit potential measurements) before carbon fouling essentially destroyed the cell. The best performing cell achieved 112 mW/cm{sub 2} on dry methane at 800 C. Several problems were encountered with carbon fouling and declining open circuit voltages in many of the test cells after switching from operation on hydrogen to dry methane. Although not rigorously confirmed by experimentation, the results suggested that air infiltration through less than perfect perimeter seals or pinholes in the electrolytes, or both gave rise to conditions that caused the carbon fouling and OCV decline. Small amounts of air reacting with methane in a partial oxidation reaction could produce carbon monoxide that, in turn, would deposit the carbon. If this mechanism is confirmed, it implies that near perfect hardware is required for extended operation. Some evidence was also found for the formation of electrical shorts, probably from carbon deposits bridging the electrolyte. Work with odorized methane and with methane containing 100-ppm hydrogen sulfide confirmed that copper is stable at 800 C in dry hydrocarbon fuels in the presence of sulfur. In a number of cases, but not exclusively, the performance life on dry methane with sulfur compounds was much longer than with dry methane alone. The effect of sulfur compounds in these cases appeared to correlate with inhibition of carbon deposition. Mixed results were obtained for the effect of the sulfur compounds on power density. Progress also was made in understanding the mechanisms involved in direct utilization of dry natural gas. Evidence was developed for three possible mechanisms for dry methane utilization in addition to the usually cited mechanism--direct oxidation of methane by oxygen anions. Further work is required at a fundamental level before the knowledge gained here can be translated into higher levels of performance.

K.Krist; O. Spaldon-Stewart; R. Remick

2004-03-01T23:59:59.000Z

383

Superconductive articles including cerium oxide layer  

DOE Patents [OSTI]

A ceramic superconductor comprising a metal oxide substrate, a ceramic high temperature superconductive material, and a intermediate layer of a material having a cubic crystal structure, said layer situated between the substrate and the superconductive material is provided, and a structure for supporting a ceramic superconducting material is provided, said structure comprising a metal oxide substrate, and a layer situated over the surface of the substrate to substantially inhibit interdiffusion between the substrate and a ceramic superconducting material deposited upon said structure. 7 figures.

Wu, X.D.; Muenchausen, R.E.

1993-11-16T23:59:59.000Z

384

Steam reforming utilizing iron oxide catalyst  

SciTech Connect (OSTI)

High activity steam reforming iron oxide catalysts are described. Such catalysts can be unsupported utilizing at least 90% by weight iron oxide and various modifiers (Ai/sub 2/O/sub 3/, K/sub 2/O, CaO, SiO/sub 2/) or unmodified and supported on such things as alumina, CaO impregnated alumina, and lanthanum stabilized alumina. When used in steam reformers such as autothermal and tubular steam reformers, these catalysts demonstrate much improved resistance to carbon plugging.

Setzer, H. T.; Bett, J. A. S.

1985-06-11T23:59:59.000Z

385

Direct electrochemical reduction of metal-oxides  

DOE Patents [OSTI]

A method of controlling the direct electrolytic reduction of a metal oxide or mixtures of metal oxides to the corresponding metal or metals. A non-consumable anode and a cathode and a salt electrolyte with a first reference electrode near the non-consumable anode and a second reference electrode near the cathode are used. Oxygen gas is produced and removed from the cell. The anode potential is compared to the first reference electrode to prevent anode dissolution and gas evolution other than oxygen, and the cathode potential is compared to the second reference electrode to prevent production of reductant metal from ions in the electrolyte.

Redey, Laszlo I. (Downers Grove, IL); Gourishankar, Karthick (Downers Grove, IL)

2003-01-01T23:59:59.000Z

386

Introduction Dynamic Risk Measures  

E-Print Network [OSTI]

Introduction Dynamic Risk Measures Dynamic Risk Measures from BMO martingales Bid-Ask Dynamic Pricing Procedure Conclusion MESURES DE RISQUE DYNAMIQUES DYNAMIC RISK MEASURES Jocelyne Bion-Nadal CNRS Risk Measures Dynamic Risk Measures from BMO martingales Bid-Ask Dynamic Pricing Procedure Conclusion

Bion-Nadal, Jocelyne

387

Investigation of the Local Structure of Graphene Oxide  

SciTech Connect (OSTI)

A study of the local structure of graphene oxide is presented. Graphene oxide is understood to be partially oxidized graphene. Absorption peaks corresponding to interlayer states suggest the presence of pristine graphitic nanoislands in graphene oxide. Site-projected partial density of states of carbon atoms bonded to oxygen atoms suggests that the broadening of the peak due to interlayer states in the carbon K-edge spectrum of graphene oxide is predominantly due to formation of epoxide linkages. Density functional theory suggests that multilayers of graphene oxide are linked by peroxide-like linkages.

S Saxena; T Tyson; E Negusse

2011-12-31T23:59:59.000Z

388

Catalytic reactions on well-characterized vanadium oxide catalysts. 1. Oxidation of carbon monoxide  

SciTech Connect (OSTI)

The oxidation of carbon monoxide over unsupported and supported vanadium oxide catalysts was investigated from the standpoint of structure sensitivity. The activity of unsupported V/sub 2/O/sub 5/ markedly decreased the turnover frequency, while the reduction-oxidation treatment of the fused catalyst increased it. The turnover frequency of V/sub 2/O/sub 5//TiO/sub 2/ with low V/sub 2/O/sub 5/ content was much smaller than that of the V/sub 2/O/sub 5//TiO/sub 2/ with high V/sub 2/O/sub 5/ content or the unsupported V/sub 2/O/sub 5/. Such a retarding effect of the TiO/sub 2/ support on the activity of the oxidation of carbon monoxide is in contrast to the known promoting effect of TiO/sub 2/ for the oxidations of various hydrocarbons. From these results coupled with the characterization of the catalysts, it was concluded that the oxidation of carbon monoxide on vanadium oxide catalysts is a structure-sensitive reaction and that the activity of surface defects such as steps, kinks, and vacancies is much higher than that of the surface V=O species in the smooth (010) face of V/sub 2/O/sub 5/. 39 references, 9 figures, 2 tables.

Mori, K.; Miyamoto, A.; Murakami, Y.

1984-06-21T23:59:59.000Z

389

Synthesis of Co oxide doped carbon aerogel catalyst and catalytic performance in heterogeneous oxidation of phenol in water  

Science Journals Connector (OSTI)

Co oxide doped carbon aerogel (Co/CA) was prepared, characterised by several techniques, and tested for heterogeneous oxidation of phenol in aqueous solution using oxone as an oxidant. For a comparison, homogeneous oxidation of phenol in Co2+/oxone was also investigated. It was found that homogeneous oxidation of phenol using Co2+/oxone was more effective than Co2+/H2O2 and homogeneous oxidation was faster than heterogeneous Co/CA–oxone. Heterogeneous oxidation of phenol in Co/CA–oxone system followed first order kinetics and the activation energy of the heterogeneous system was estimated to be 62.9 kJ/mol. Several factors influencing phenol degradation in the heterogeneous oxidation were studied. Co/CA loading played a more important role in phenol degradation than oxone concentration, and the presence of other organics in solution resulted in a lower phenol oxidation.

Yasnessya Hardjono; Hongqi Sun; Huyong Tian; C.E. Buckley; Shaobin Wang

2011-01-01T23:59:59.000Z

390

Effect of Coal Gas Contaminants on Solid Oxide Fuel Cell Operation...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Coal Gas Contaminants on Solid Oxide Fuel Cell Operation. Effect of Coal Gas Contaminants on Solid Oxide Fuel Cell Operation. Abstract: The operation of solid oxide fuel cells...

391

Anomalous behaviour of magnetic coercivity in graphene oxide and reduced graphene oxide  

SciTech Connect (OSTI)

In this report, we present the temperature dependence of the magnetic coercivity of graphene oxide (GO) and reduced graphene oxide (RGO). We observe an anomalous decrease in coercivity of GO and RGO with decreasing temperature. The observation could be understood by invoking the inherent presence of wrinkles on graphene oxide due to presence of oxygen containing groups. Scanning electron microscopic image reveals high wrinkles in GO than RGO. We observe higher coercivity in RGO than in GO. At room temperature, we observe antiferromagnetic and ferromagnetic behaviours in GO and RGO, respectively. Whereas, at low temperatures (below T?=?60–70?K), both materials show paramagnetic behaviour.

Bagani, K.; Bhattacharya, A.; Kaur, J.; Rai Chowdhury, A.; Ghosh, B.; Banerjee, S., E-mail: sangam.banerjee@saha.ac.in [Saha Institute of Nuclear Physics, Surface Physics Division, 1/AF Bidhannagar, Kolkata 700064 (India); Sardar, M. [Material Science Division, Indira Gandhi Centre for Atomic Research, Kalpakkam 603102 (India)

2014-01-14T23:59:59.000Z

392

Measuring Verification Coverage  

Science Journals Connector (OSTI)

In order to measure verification progress, we measure verification converage because verification coverage defines the extent of the verification problem. In order to measure anything however, we need metrics....

2008-01-01T23:59:59.000Z

393

Ground Vibration Measurement  

Science Journals Connector (OSTI)

Measurement of ground vibration is important for checking of amplitudes of ... confirmation of efficiency of control measures of ground vibration. The properties of measuring instruments used can affect the resul...

Dr. Milutin Srbulov

2010-01-01T23:59:59.000Z

394

Elevation in Exhaled Nitric Oxide Predicts for Radiation Pneumonitis  

SciTech Connect (OSTI)

Purpose: Radiation pneumonitis is a major toxicity after thoracic radiotherapy (RT), with no method available to accurately predict the individual risk. This was a prospective study to evaluate exhaled nitric oxide as a predictive biomarker for radiation pneumonitis in esophageal cancer patients. Patients and Methods: A total of 34 patients prescribed neoadjuvant chemoradiotherapy for esophageal cancer were enrolled in the present trial. Each patient underwent respiratory surveys and exhaled nitric oxide (NO) measurements before, at the end of, and 1 to 2 months after completing RT. Pneumonitis toxicity was scored using the Common Terminology Criteria for Adverse Events, version 4.0. The demographics, dosimetric factors, and exhaled NO levels were evaluated for correlation with symptomatic patients (scores {>=}2). Results: Of the 34 patients, 28 were evaluable. All had received 50.4 Gy RT with concurrent chemotherapy. The pneumonitis toxicity score was Grade 3 for 1, Grade 2 for 3, Grade 1 for 7, and Grade 0 for 17. The dosimetric factors were not predictive of symptoms. The mean exhaled NO level measured before, at completion, and at restaging was 17.3 {+-} 8.5 (range, 5.5-36.7), 16.0 {+-} 14.2 (range, 5.8-67.7), and 14.7 {+-} 6.2 (range, 5.5-28.0) parts per billion, respectively. The ratio of exhaled NO at the end of RT vs. before treatment was 3.4 (range, 1.7-6.7) for the symptomatic and 0.8 (range, 0.3-1.3) for the asymptomatic (p = .0017) patients. The elevation in exhaled NO preceded the peak symptoms by 33 days (range, 21-50). The interval to peak symptoms was inversely related to the exhaled NO elevation. Conclusions: Elevations in exhaled NO at the end of RT was found to predict for radiation pneumonitis symptoms.

Guerrero, Thomas, E-mail: tguerrero@mdanderson.org [Division of Radiation Oncology, University of Texas M. D. Anderson Cancer Center, Houston, TX (United States); University of Texas Graduate School of Biomedical Sciences at Houston, Houston, TX (United States); Martinez, Josue [Department of Statistics, Texas A and M University, College Station, TX (United States); McCurdy, Matthew R. [Department of Radiation Oncology, Baylor College of Medicine, Houston, TX (United States); Wolski, Michael [Department of Radiation Oncology, University of Texas Medical Branch, Galveston, TX (United States); McAleer, Mary Francis [Division of Radiation Oncology, University of Texas M. D. Anderson Cancer Center, Houston, TX (United States)

2012-02-01T23:59:59.000Z

395

Improving dielectric performance in anodic aluminum oxide via detection and passivation of defect states  

SciTech Connect (OSTI)

The electronic and ionic transports in 32–56?nm thick anodic aluminum oxide films are investigated before and after a 1-h anneal at 200–400?°C in argon. Results are correlated to their defect density as measured by the Mott-Schottky technique. Solid state measurements show that electronic conduction upon annealing is hindered by an increase in the Schottky emission barrier, induced by a reduction in dopant density. Using an electrochemical contact, the films fail rapidly under cathodic polarization, unless defect density is decreased down to 10{sup 17}?cm{sup ?3}, resulting in a three order of magnitude reduction in current and no visible gas evolution. Under anodic polarization, the decrease in defect density delays the onset of ionic conduction as well as further oxide growth and failure.

Mibus, M.; Zangari, G. [Department of Materials Science and Engineering, University of Virginia, Charlottesville, Virginia 22904 (United States); Jensen, C. [Department of Chemical Engineering, University of Virginia, Charlottesville, Virginia 22904 (United States); Hu, X.; Reed, M. L. [Department of Mechanical and Aerospace Engineering, University of Virginia, Charlottesville, Virginia 22904 (United States); Knospe, C. [Department of Electrical and Computer Engineering, University of Virginia, Charlottesville, Virginia 22904 (United States)

2014-06-16T23:59:59.000Z

396

Power dissipation characteristics of zinc-oxide arresters for HVDC systems  

SciTech Connect (OSTI)

Zinc-oxide arresters without series gaps have been used for HVDC systems. The voltage wave shapes applied to HVDC arresters are not a simple sinusoidal shape, so that the leakage current contains high frequency components. The power dissipation characteristics of a thyristor valve arrester were measured using a 1/25 prorated arrester section with a 5kV/500kW thyristor bridge. High frequency power dissipation characteristics of zinc-oxide elements were measured and it was shown that the high frequency power dissipation of the thyristor valve arrester was larger than that of an AC system arrester. Consideration of the equivalent continuous operating voltage for the performance test of an HVDC arrester are presented.

Horiuchi, S.; Ichikawa, F. (Tokyo Electric Power Co., Inc., Tokyo (JP)); Mizukoshi, A. (Hitachi Research Lab., Hitachi Ltd. (JP)); Kurita, K.; Shirakawa, S. (Kokubu Works Hitachi Ltd., Ibaraki (JP))

1988-10-01T23:59:59.000Z

397

Measuring Energy Achievements  

Broader source: Energy.gov [DOE]

This presentation covers types of energy measurements essential to industrial facilities and discusses the benefits of metrics. ArcelorMittal provides examples from their experience measuring energy achievements.

398

Spectroscopic ellipsometry of electrochemical precipitation and oxidation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Spectroscopic ellipsometry of electrochemical precipitation and oxidation Spectroscopic ellipsometry of electrochemical precipitation and oxidation of nickel hydroxide films Title Spectroscopic ellipsometry of electrochemical precipitation and oxidation of nickel hydroxide films Publication Type Journal Article Year of Publication 1998 Authors Kong, Fanping, Robert Kostecki, Frank R. McLarnon, and Rolf H. Muller Journal Thin Solid Films Volume 313-314 Pagination 775-780 Keywords effective medium approximation, electrochemical precipitation, inhomogeneous films, nickel hydroxide, spectroscopic ellipsometry Abstract In situ spectroscopic ellipsometry was used to investigate the electrochemical precipitation of nickel hydroxide films. By use of optical models for inhomogeneous films it was found that a specific precipitation current density produced the most compact and homogeneous film structures. The density of nickel hydroxide films was derived to be 1.25-1.50 g/cm3. The redox behavior of precipitated nickel hydroxide films was studied with an effective-medium optical model. Incomplete conversion to nickel oxyhydroxide and a reduction in film thickness were found during the oxidation cycle.

399

Metal current collect protected by oxide film  

DOE Patents [OSTI]

Provided are low-cost, mechanically strong, highly electronically conductive current collects and associated structures for solid-state electrochemical devices, techniques for forming these structures, and devices incorporating the structures. The invention provides solid state electrochemical devices having as current interconnects a ferritic steel felt or screen coated with a protective oxide film.

Jacobson, Craig P. (Lafayette, CA); Visco, Steven J. (Berkeley, CA); DeJonghe, Lutgard C. (Lafayette, CA)

2004-05-25T23:59:59.000Z

400

Nitrated metalloporphyrins as catalysts for alkane oxidation  

DOE Patents [OSTI]

Compositions of matter comprising nitro-substituted metal complexes of porphyrins are catalysts for the oxidation of alkanes. The metal is iron, chromium, manganese, ruthenium, copper or cobalt. The porphyrin ring has nitro groups attached thereto in meso and/or [beta]-pyrrolic positions.

Ellis, P.E. Jr.; Lyons, J.E.

1994-01-18T23:59:59.000Z

Note: This page contains sample records for the topic "measures miec oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

The Photo-Sensitized Oxidation of Ethanol  

Science Journals Connector (OSTI)

...research-article The Photo-Sensitized Oxidation of Ethanol J. L. Bolland H. R. Cooper Certain...photosensitizers of the autoxidation of ethanol. In this quantitative investigation the...mechanism, abstracting hydrogen from the ethanol to give a semi-quinone radical which...

1954-01-01T23:59:59.000Z

402

Electrical Properties of Tungsten Oxide Films  

Science Journals Connector (OSTI)

... appear that the mechanism of electron emission with oxide films is different from that with roughened electrodes. This would be the case for short gaps if the electrons were drawn ... located on the upper surface of the film, as envisaged by Paetov1, while with roughened electrodes it is possible that photo-ionization can take place throughout the gap due to ...

F. LLEWELLYN JONES

1946-03-23T23:59:59.000Z

403

Gold catalyst Styrene Benzaldehyde Styrene oxide Acetophenone  

E-Print Network [OSTI]

O O O + + O2 Gold catalyst Styrene Benzaldehyde Styrene oxide Acetophenone studies. However, the study by Turner et al.1 seems to be the first to use Au55 in the synthesis of supported gold catalysts a very narrow and reproducible size distribution for the result- ing particles. Traditional catalyst

Rouyer, Francois

404

Oxidative Stress Resistance in Deinococcus radiodurans  

Science Journals Connector (OSTI)

...phosphate pathway (683). The energy required for the recovery process...considerable potential interest and sustainable global significance for the...tetrad. FIG. 2. Sources of energy and building blocks in oxidatively...Both can be used as sources of energy, while polyphosphates also...

Dea Slade; Miroslav Radman

2011-03-01T23:59:59.000Z

405

Molybdenum oxide electrodes for thermoelectric generators  

DOE Patents [OSTI]

The invention is directed to a composite article suitable for use in thermoelectric generators. The article comprises a thin film comprising molybdenum oxide as an electrode deposited by physical deposition techniques onto solid electrolyte. The invention is also directed to the method of making same.

Schmatz, Duane J. (Dearborn Heights, MI)

1989-01-01T23:59:59.000Z

406

Oxidized messenger RNA induces translation errors  

Science Journals Connector (OSTI)

...passed through a QIA shredder (Qiagen) to reduce...bound and the unbound fraction, respectively. Sucrose...and a Foxy Jr. fraction collector (ISCO). Each fraction was resuspended in distilled water...oxidized mRNA. In light of these findings...

Mikiei Tanaka; P. Boon Chock; Earl R. Stadtman

2007-01-01T23:59:59.000Z

407

Potential oxidative stress due to Pb exposure  

E-Print Network [OSTI]

increases in oxidation of glutathione in K562 myelogenous leukemia cells at low Pb levels. The approach consisted of incubating K562 cells in solutions of 0, 300, and 700 ppb Pb dissolved in RPMI cell medium for a total of 96 hours. After this period...

Elms, Rene' Davina

2013-02-22T23:59:59.000Z

408

Nitrated metalloporphyrins as catalysts for alkane oxidation  

DOE Patents [OSTI]

Alkanes are oxidized by contact with oxygen-containing gas in the presence as catalyst of a metalloporphyrin in which hydrogen atoms in the porphyrin ring have been replaced with one or more nitro groups. Hydrogen atoms in the porphyrin ring may also be substituted with halogen atoms.

Ellis, Jr., Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA)

1992-01-01T23:59:59.000Z

409

Chemical vapor deposition of aluminum oxide  

DOE Patents [OSTI]

An aluminum oxide film is deposited on a heated substrate by CVD from one or more alkylaluminum alkoxide compounds having composition R.sub.n Al.sub.2 (OR').sub.6-n, wherein R and R' are alkyl groups and n is in the range of 1 to 5.

Gordon, Roy (Cambridge, MA); Kramer, Keith (Cleveland, OH); Liu, Xinye (Cambridge, MA)

2000-01-01T23:59:59.000Z

410

Solid oxide fuel cell having monolithic core  

DOE Patents [OSTI]

A solid oxide fuel cell is described for electrochemically combining fuel and oxidant for generating galvanic output, wherein the cell core has an array of electrolyte and interconnect walls that are substantially devoid of any composite inert materials for support. Instead, the core is monolithic, where each electrolyte wall consists of thin layers of cathode and anode materials sandwiching a thin layer of electrolyte material therebetween. The electrolyte walls are arranged and backfolded between adjacent interconnect walls operable to define a plurality of core passageways alternately arranged where the inside faces thereof have only the anode material or only the cathode material exposed. Means direct the fuel to the anode-exposed core passageways and means direct the oxidant to the anode-exposed core passageways and means direct the oxidant to the cathode-exposed core passageway; and means also direct the galvanic output to an exterior circuit. Each layer of the electrolyte and interconnect materials is of the order of 0.002 to 0.01 cm thick; and each layer of the cathode and anode materials is of the order of 0.002 to 0.05 cm thick.

Ackerman, J.P.; Young, J.E.

1983-10-12T23:59:59.000Z

411

Nitrous Oxide Emissions from a Municipal Landfill  

Science Journals Connector (OSTI)

Nitrous Oxide Emissions from a Municipal Landfill ... Due to the small area of landfills as compared to other land-use classes, the total N2O emissions from landfills are estimated to be of minor importance for the total emissions from Finland. ...

Janne Rinne; Mari Pihlatie; Annalea Lohila; Tea Thum; Mika Aurela; Juha-Pekka Tuovinen; Tuomas Laurila; Timo Vesala

2005-09-21T23:59:59.000Z

412

Nitrated metalloporphyrins as catalysts for alkane oxidation  

DOE Patents [OSTI]

Compositions of matter comprising nitro-substituted metal complexes of porphyrins are catalysts for the oxidation of alkanes. The metal is iron, chromium, manganese, ruthenium, copper or cobalt. The porphyrin ring has nitro groups attached thereto in meso and/or .beta.-pyrrolic positions.

Ellis, Jr., Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA)

1994-01-01T23:59:59.000Z

413

Report on Ultra-high Resolution Gamma- / X-ray Analysis of Uranium Skull Oxide  

SciTech Connect (OSTI)

We have utilized the high energy resolution and high peak-to-background ratio of superconducting TES {gamma}-detectors at very low energies for non-destructive analysis of a skull oxide derived from reprocessed nuclear fuel. Specifically, we demonstrate that superconducting detectors can separate and analyze the strong actinide emission lines in the spectral region below 60 keV that are often obscured in {gamma}-measurements with conventional Ge detectors.

Friedrich, S; Velazquez, M; Drury, O; Salaymeh, S

2009-11-02T23:59:59.000Z

414

Effect of Carbon Deposition on the Oxidation Rate of Copper/Bentonite in the Chemical Looping Process  

SciTech Connect (OSTI)

The presented work is part of the Industrial Carbon Management Initiative (ICMI) on the development of metal oxide oxygen carriers for use in the chemical looping combustion process. An oxygen carrier, CuO/bentonite (60:40%), was reacted with methane gas and then oxidized in air. The change in weight and reaction gas concentrations were measured using a thermogravimetric analyzer (TGA) equipped with a real-time gas analyzer. The reduction–oxidation cycle was conducted within the temperature range of 750–900 °C for 10 cycles, using 20, 50, and100% CH{sub 4} concentrations in N{sub 2} for the reduction segment and dry air for the oxidation segment. Several analysis methods were evaluated to fit the oxidation of reduced CuO (i.e., Cu) data over the complete conversion range with suitable rate expressions derived from existing models for oxidation, including the shrinking core model (diffusion and reaction control), first- and second-order reaction rates, parallel and series reaction mechanisms, and Johnson–Mehl–Avrami (JMA) rate. The best agreement between the experimental data and the models of the Cu oxidation was accomplished using the JMA model. The reactivity of the oxygen carrier during the oxidation reactions was affected by the CH{sub 4} concentration as well as the temperature. The rate of fractional uptake of oxygen onto the carrier decreased as the temperature increased, contrary to expectations and indicative that the mechanism is changing during the test. Analysis of the exit gas provided evidence of carbon deposition on the reduced sorbent particle and resulted in the CO{sub 2} product upon oxidation. The oxidation of this carbon releases significant heat that is capable of changing the particle morphology (Zhu, Y.; Mimura, K.; Isshiki, M. Oxid. Met. 2004, 62, 207?222). On the basis of experimental results, the overall reaction process in the fuel reactor may be considered to consist of the decomposition of CH{sub 4} into C and H{sub 2} and reduction of CuO/bentonite by the resulting H{sub 2} and the parallel reaction of CH{sub 4} with CuO/bentonite. The extent of carbon deposition in the carrier particle increased with an increasing temperature and CH{sub 4} concentration. This deposited carbon not only leads to CO{sub 2} release from the oxidation reactor but, more importantly, causes degredation of the carrier capacity and its reactivity.

Monazam, Esmail R.; Breault, Ronald W.; Siriwardane, Ranjani

2012-11-01T23:59:59.000Z

415

National Energy Technology Laboratory Publishes Solid Oxide Fuel Cell  

Broader source: Energy.gov (indexed) [DOE]

National Energy Technology Laboratory Publishes Solid Oxide Fuel National Energy Technology Laboratory Publishes Solid Oxide Fuel Cell Studies National Energy Technology Laboratory Publishes Solid Oxide Fuel Cell Studies July 23, 2013 - 1:07pm Addthis National Energy Technology Laboratory Publishes Solid Oxide Fuel Cell Studies What does this project do? For more information on DOE's efforts to make solid oxide fuel cells an efficient and economically compelling option, please visit: The NETL Solid Oxide Fuel Cells Program Webpage Solid oxide fuel cells are among the cleanest, most efficient power-generating technologies now being developed. They provide excellent electrical efficiencies and are capable of operating on a wide variety of fuels, from coal and natural gas to landfill waste and hydrogen. And with continued advancements, solid oxide fuel cells can provide clean

416

Tetrahydrothiophene 1-oxide as an electron acceptor for Escherichia coli.  

Science Journals Connector (OSTI)

...research-article Research Article Tetrahydrothiophene 1-oxide as an electron acceptor...Schrementi Escherichia coli used tetrahydrothiophene 1-oxide (THTO) as an electron...source; the THTO was reduced to tetrahydrothiophene. Cell extracts also reduced THTO...

R Meganathan; J Schrementi

1987-06-01T23:59:59.000Z

417

Engineered Graphite Oxide Materials for Application in Water Purification  

Science Journals Connector (OSTI)

Engineered Graphite Oxide Materials for Application in Water Purification ... The research results could open avenues for developing low-cost water purification materials for the developing economies. ... water purification; graphite oxide; mercury removal; diazonium chemistry; Rhodamine B; sand coating ...

Wei Gao; Mainak Majumder; Lawrence B. Alemany; Tharangattu N. Narayanan; Miguel A. Ibarra; Bhabendra K. Pradhan; Pulickel M. Ajayan

2011-05-13T23:59:59.000Z

418

Synthesis Dependent Core Level Binding Energy Shift in the Oxidation...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Energy Shift in the Oxidation State ofPlatinum Coated on Ceria–Titania and its Synthesis Dependent Core Level Binding Energy Shift in the Oxidation State ofPlatinum Coated...

419

Solid Oxide Fuel Cell System Utilizing Syngas from Coal Gasifiers  

Science Journals Connector (OSTI)

Solid Oxide Fuel Cell System Utilizing Syngas from Coal Gasifiers ... The oxidizer is expected to be similar in design to a HRSG duct firing burner (at the inlet of a HRSG). ...

Hossein Ghezel-Ayagh; Stephen Jolly; Dilip Patel; David Stauffer

2013-01-10T23:59:59.000Z

420

Functionalization of Graphene and Graphene Oxide for Biosensing and Imaging  

SciTech Connect (OSTI)

Recent advances in our group about graphene biofunctionalization are discussed. In particular, the functionalization of graphene and graphene oxide, biosensing and bioimaging by using graphene-based nanomaterials, and some fundamental studies of graphene and graphene oxide have been summarized.

Li, Zhaohui; Wang, Ying; Du, Dan; Tang, Zhiwen; Wang, Jun; Lin, Yuehe

2011-08-15T23:59:59.000Z

Note: This page contains sample records for the topic "measures miec oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Mechanisms of Oxidation-Enhanced Wear in Diesel Exhaust Valves...  

Broader source: Energy.gov (indexed) [DOE]

of wear oxidation microstructures of alloys Fe-, Ni-, Co-alloys h T h i h v Combined plastic deformation, wear, and oxidation on both valve and seat surfaces 6 Managed by...

422

Oxidation of graphite surface: the role of water  

E-Print Network [OSTI]

Based on density functional calculations, we demonstrate a significant difference in oxidation patterns between graphene and graphite and the formation of defects after oxidation. Step-by-step modeling demonstrates that oxidation of 80% of the graphite surface is favorable. Oxidation above half of the graphite surface significantly decreases the energy costs of vacancy formation with CO2 production. The presence of water is crucial in the transformation of epoxy groups to hydroxyl, the intercalation with further bundle and exfoliation. In water-rich conditions, water intercalates graphite at the initial stages of oxidation and oxidation, which is similar to the oxidation process of free-standing graphene; in contrast, in water-free conditions, large molecules intercalate graphite only after oxidation occurs on more than half of the surface.

Boukhvalov, D W

2014-01-01T23:59:59.000Z

423

Ovarian nitric oxide synthase gene expression during peripubertal development  

E-Print Network [OSTI]

Nitric oxide (NO) is generated from L-arginine by different isoforms of the enzyme nitric oxide synthase. (NOS) and is known to be involved in mediating several biological functions, some of which are associated with reproduction. Much attention...

Jones, Benjamin James

1997-01-01T23:59:59.000Z

424

Reversible Poisoning of the Nickel/Zirconia Solid Oxide Fuel...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Poisoning of the NickelZirconia Solid Oxide Fuel Cell Anodes by Hydrogen Chloride in Coal Gas. Reversible Poisoning of the NickelZirconia Solid Oxide Fuel Cell Anodes by Hydrogen...

425

Breakout Group 5: Solid Oxide Fuel Cells | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Breakout Group 5: Solid Oxide Fuel Cells Breakout Group 5: Solid Oxide Fuel Cells Report from Breakout Group 5 of the Fuel Cell Pre-Solicitation Workshop, January 23-24, 2008...

426

Iron oxide nanoparticles as a contrast agent for thermoacoustic tomography  

E-Print Network [OSTI]

radiation. The addition of an exogenous contrast agent improves image quality by more effectively converting microwave energy to heat. The use of iron oxide nanoparticles in MRI applications has been explored but super paramagnetic iron oxide nanoparticles...

Keho, Aaron Lopez

2009-06-02T23:59:59.000Z

427

Role of Ethylene Oxidation in the Mechanism of Ethylene Action  

Science Journals Connector (OSTI)

Oxidation of ethylene to ethylene oxide by ethylene monooxygenase (EM) has been shown to...Mycobacterium paraffinicum...(14, 16, 17, 18, 32), plants (8, 21, 24), and animals (22, 23). In microorga...

F. B. Abeles

1984-01-01T23:59:59.000Z

428

Toward an Improved Model of Asphalt Binder Oxidation in Pavements  

E-Print Network [OSTI]

Asphalt binder oxidation in pavements has been proven to be an ongoing process throughout a pavement's service life. Understanding the nature of the oxidation process is a critical step toward better pavement design to achieve greater pavement...

Prapaitrakul, Nikornpon

2011-02-22T23:59:59.000Z

429

Minimal Proton Channel Enables H2 Oxidation and Production with...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Minimal Proton Channel Enables H2 Oxidation and Production with a Water-Soluble Nickel-Based Catalyst. Minimal Proton Channel Enables H2 Oxidation and Production with a...

430

Morphology and Electronic Structure of the Oxide Shell on the...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Structure of the Oxide Shell on the Surface of Iron Nanoparticles. Abstract: A iron nanoparticle exposed to air at room temperature will be instantly covered by an oxide shell of...

431

Neutron field characterisation at mixed oxide fuel plant  

Science Journals Connector (OSTI)

......plutonium oxide (PuO2) and 70 % depleted uranium oxide (UO2) are blended together...and typical field conditions. Health Phys. (1990) 58(6):691-704...Power Plants Quality Assurance, Health Care Radiation Dosage Radiation......

C. Passmore; M. Million; M. Kirr; J. Bartz; M. S. Akselrod; A. Devita; J. Berard

2012-06-01T23:59:59.000Z

432

Sulfated Mesoporous Niobium Oxide Catalyzed 5-Hydroxymethylfurfural Formation from Sugars  

Science Journals Connector (OSTI)

Sulfated Mesoporous Niobium Oxide Catalyzed 5-Hydroxymethylfurfural Formation from Sugars ... The effectiveness of sulfated mesoporous niobium oxide (MNO-S) as a catalyst for the production of 5-hydroxymethylfurfural (5-HMF) from sugar was studied and is reported herein. ...

Ernest Lau Sze Ngee; Yongjun Gao; Xi Chen; Timothy Misso Lee; Zhigang Hu; Dan Zhao; Ning Yan

2014-08-25T23:59:59.000Z

433

Effect of Thermal Neutron Irradiation on Oxide Catalysts for the Decomposition of Nitrous Oxide  

Science Journals Connector (OSTI)

... alpha-particles which are produced by an (n, a) reaction with lithium-6 or boron-10 atoms. Nickel oxide contains excess oxygen ions as a £-type semiconductor and probably ...

YASUKAZU SAITO; YUKIO YONEDA; SHOJI MAKISHIMA

1959-02-07T23:59:59.000Z

434

Metal oxide catalysts for the low temperature selective oxidation of propane to iso-propanol.  

E-Print Network [OSTI]

??A range of Ga203/Mo03 and C03O4 catalysts have been prepared and tested for the oxidative dehydrogenation of propane to propene. The Ga2(VMo03 physical mixture demonstrated… (more)

Davies, Thomas Edward.

2006-01-01T23:59:59.000Z

435

Graphite Oxidation Simulation in HTR Accident Conditions  

SciTech Connect (OSTI)

Massive air and water ingress, following a pipe break or leak in steam-generator tubes, is a design-basis accident for high-temperature reactors (HTRs). Analysis of these accidents in both prismatic and pebble bed HTRs requires state-of-the-art capability for predictions of: 1) oxidation kinetics, 2) air ?helium gas mixture stratification and diffusion into the core following the depressurization, 3) transport of multi-species gas mixture, and 4) graphite corrosion. This project will develop a multi-dimensional, comprehensive oxidation kinetics model of graphite in HTRs, with diverse capabilities for handling different flow regimes. The chemical kinetics/multi-species transport model for graphite burning and oxidation will account for temperature-related changes in the properties of graphite, oxidants (O2, H2O, CO), reaction products (CO, CO2, H2, CH4) and other gases in the mixture (He and N2). The model will treat the oxidation and corrosion of graphite in geometries representative of HTR core component at temperatures of 900°C or higher. The developed chemical reaction kinetics model will be user-friendly for coupling to full core analysis codes such as MELCOR and RELAP, as well as computational fluid dynamics (CFD) codes such as CD-adapco. The research team will solve governing equations for the multi-dimensional flow and the chemical reactions and kinetics using Simulink, an extension of the MATLAB solver, and will validate and benchmark the model's predictions using reported experimental data. Researchers will develop an interface to couple the validated model to a commercially available CFD fluid flow and thermal-hydraulic model of the reactor , and will perform a simulation of a pipe break in a prismatic core HTR, with the potential for future application to a pebble-bed type HTR.

Mohamed El-Genk

2012-10-19T23:59:59.000Z

436

In Situ Studies of Fuel Oxidation in Solid Oxide Fuel Cells  

Science Journals Connector (OSTI)

In Situ Studies of Fuel Oxidation in Solid Oxide Fuel Cells ... Re-optimization of the Raman signal shows two broad, strong features in the OCV spectrum indicating large amounts of disordered graphite as evidenced by a broad D band (at 1350 cm-1) accompanying the G band (at 1585 cm-1) (Figure 2, right panel). ... intensities from a nonresonant, bond polarizability model optimized for sp2 carbon are also in qual. ...

Michael B. Pomfret; Jeffrey C. Owrutsky; Robert A. Walker

2007-02-13T23:59:59.000Z

437

Thief Carbon Catalyst for Oxidation of Mercury in Effluent Stream  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Carbon Catalyst for Oxidation of Mercury in Effluent Carbon Catalyst for Oxidation of Mercury in Effluent Stream Contact NETL Technology Transfer Group techtransfer@netl.doe.gov January 2012 Significance * Oxidizes heavy metal contaminants, especially mercury, in gas streams * Uses partially combusted coal ("Thief" carbon) * Yields an inexpensive catalyst * Cheap enough to be a disposable catalyst * Cuts long-term costs * Simultaneously addresses oxidation and adsorption issues Applications * Any process requiring removal of heavy

438

Process Modeling of Global Soil Nitrous Oxide Emissions  

E-Print Network [OSTI]

Nitrous oxide is an important greenhouse gas and is a major ozone-depleting substance. To understand and

Saikawa, E.

2011-09-01T23:59:59.000Z

439

Methane oxidation rates in the anaerobic sediments of Saanich Inlet  

Science Journals Connector (OSTI)

water methane concentration were avail- able. ... water solute concentrations and methane oxidation rates ..... Diffusion of light paraffin hydrocarbons in water.

2000-02-09T23:59:59.000Z

440

Investigation on edge fringing effect and oxide thickness dependence of inversion current in metal-oxide-semiconductor tunneling diodes with comb-shaped electrodes  

SciTech Connect (OSTI)

A particular edge-dependent inversion current behavior of metal-oxide-semiconductor (MOS) tunneling diodes was investigated utilizing square and comb-shaped electrodes. The inversion tunneling current exhibits the strong dependence on the tooth size of comb-shaped electrodes and oxide thickness. Detailed illustrations of current conduction mechanism are developed by simulation and experimental measurement results. It is found that the electron diffusion current and Schottky barrier height lowering for hole tunneling current both contribute on inversion current conduction. In MOS tunneling photodiode applications, the photoresponse can be improved by decreasing SiO{sub 2} thickness and using comb-shaped electrodes with smaller tooth spacing. Meantime, the high and steady photosensitivity can also be approached by introducing HfO{sub 2} into dielectric stacks.

Lin, Chien-Chih; Hsu, Pei-Lun; Lin, Li; Hwu, Jenn-Gwo, E-mail: jghwu@ntu.edu.tw [Graduate Institute of Electronics Engineering, Department of Electrical Engineering, National Taiwan University, Taipei 10617, Taiwan (China)

2014-03-28T23:59:59.000Z

Note: This page contains sample records for the topic "measures miec oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

On the electrical stress-induced oxide-trapped charges in thin HfO{sub 2}/SiO{sub 2} gate dielectric stack  

SciTech Connect (OSTI)

Oxide charge buildup and its generation kinetics during constant voltage stress in TaN/HfO{sub 2}/SiO{sub 2}/p-Si structures have been experimentally investigated. From the oxide charge relaxation experiments, nature and energy location of the as-fabricated intrinsic hole traps in the gate stack have also been determined. Our measurement results indicate that the dispersive proton transport through the interfacial SiO{sub 2} contributes larger than hole trapping in positive charge buildup in the stack. From the bias temperature stress measurement results in both control oxide and HfO{sub 2}/SiO{sub 2} stacks, we have identified overcoordinated [Si{sub 2}=OH]{sup +} centers as the proton-induced defects located in the interfacial SiO{sub 2} layer of the stack. Finally, an empirical equation is proposed to explain the stress-induced oxide positive charge buildup.

Samanta, Piyas; Zhu Chunxiang; Chan, Mansun [Department of Electronic and Computer Engineering, The Hong Kong University of Science and Technology, Clear Water Bay Road, Kowloon, Hong Kong (China); Department of Electrical and Computer Engineering, National University of Singapore, 10 Kent Ridge Crescent, Singapore 119260 (Singapore); Department of Electronic and Computer Engineering, The Hong Kong University of Science and Technology, Clear Water Bay Road, Kowloon, Hong Kong (China)

2007-09-10T23:59:59.000Z

442

ATOMIC-LAYER-DEPOSITED ALUMINUM OXIDE FOR THE SURFACE PASSIVATION OF HIGH-EFFICIENCY SILICON SOLAR CELLS  

E-Print Network [OSTI]

ATOMIC-LAYER-DEPOSITED ALUMINUM OXIDE FOR THE SURFACE PASSIVATION OF HIGH-EFFICIENCY SILICON SOLAR to those measured on reference cells passivated by an aluminum-annealed thermal SiO2, while those of the Al of aluminum ox- ide (Al2O3) grown by atomic layer deposition (ALD) pro- vide an excellent level of sur

443

Strains in Thermally Growing Alumina Films Measured in-situ usingSynchrotron X-rays  

SciTech Connect (OSTI)

Strains in thermally grown oxides have been measured in-situ, as the oxides develop and evolve. Extensive data have been acquired from oxides grown in air at elevated temperatures on different model alloys that form Al{sub 2}O{sub 3}. Using synchrotron x-rays at the Advanced Photon Source (Beamline 12BM, Argonne National Laboratory), Debye-Scherrer diffraction patterns from the oxidizing specimen were recorded every 5 minutes during oxidation and subsequent cooling. The diffraction patterns were analyzed to determine strains in the oxides, as well as phase changes and the degree of texture. To study a specimen's response to stress perturbation, the oxidizing temperature was quickly cooled from 1100 to 950 C to impose a compressive thermal stress in the scale. This paper describes this new experimental approach and gives examples from oxidized {beta}-NiAl, Fe-20Cr-10Al, Fe-28Al-5Cr and H{sub 2}-annealed Fe-28Al-5Cr (all at. %) alloys to illustrate some current understanding of the development and relaxation of growth stresses in Al{sub 2}O{sub 3}.

Hou, P.Y.; Paulikas, A.P.; Veal, B.W.

2006-01-02T23:59:59.000Z

444

Tungsten oxide nanowire-reduced graphene oxide aerogel for high-efficiency visible light photocatalysis  

Science Journals Connector (OSTI)

Abstract A light, 3-D, porous aerogel was fabricated by way of a simple approach from 1-D tungsten oxide nanowires and 2-D reduced graphene oxide sheets. The as-prepared graphene oxide, tungsten oxide nanowires, and tungsten oxide-reduced graphene oxide (W18O49-RGO) aerogel were characterised. The photocatalytic activities of as-prepared aerogel under visible light irradiation were investigated through the degradation of six different organic dyes including Rhodamine B, reactive black 39, reactive yellow 145, weak acid black BR, methyl orange, and weak acid yellow G. In comparison with the pure W18O49 nanowires, the prepared W18O49-RGO aerogel had significantly improved photocatalytic efficiency. Also, the photocatalysis of W18O49-RGO aerogel maintained its efficiency after 30 cycles for each of the six dyes. The photocatalytic mechanism was studied by adding hole and radical scavengers: the results confirmed that the holes generated in W18O49-RGO aerogel played a key role in the visible light photocatalytic process.

Xiubing Li; Siwei Yang; Jing Sun; Peng He; Xuguang Xu; Guqiao Ding

2014-01-01T23:59:59.000Z

445

Significant influence of insufficient lithium on electrochemical performance of lithium-rich layered oxide cathodes for lithium ion batteries  

Science Journals Connector (OSTI)

Abstract With an aim to broaden the understanding of the factors that govern electrochemical performance of lithium-rich layered oxide, the influences of insufficient lithium on reversible capacity, cyclic stability and rate capability of the oxide as cathode of lithium ion battery are investigated in this study. Various concentrations of lithium precursor are introduced to synthesize a target composition Li[Li0.13Ni0.30Ni0.57]O2, and the resulting products are characterized with inductively coupled plasma spectrum, scanning electron microscope, X-ray diffraction, Raman spectroscopy, and electrochemical measurements. The results indicate that the lithium content in the resulting oxide decreases with reducing the concentration of lithium precursor from 10wt%-excess lithium to stoichiometric lithium, due to insufficient compensation for lithium volatilization during synthesis process at high temperature. However, all these oxides still exhibit typically structural and electrochemical characteristics of lithium-rich layered oxides. Interestingly, with decreasing the Li content in the oxide, its reversible capacity increases due to relatively higher content of active transition-metal ions, while the cyclic stability degrades severely because of structural instability induced by higher content of Mn3+ ions and deeper lithium extraction.

Xingde Xiang; Weishan Li

2014-01-01T23:59:59.000Z

446

COMPUTATIONAL FLUID DYNAMICS MODELING OF SOLID OXIDE FUEL CELLS  

E-Print Network [OSTI]

COMPUTATIONAL FLUID DYNAMICS MODELING OF SOLID OXIDE FUEL CELLS Ugur Pasaogullari and Chao-dimensional model has been developed to simulate solid oxide fuel cells (SOFC). The model fully couples current density operation. INTRODUCTION Solid oxide fuel cells (SOFC) are among possible candidates

447

P0301-Mogensen Performance of Reversible Solid Oxide Cells  

E-Print Network [OSTI]

that solid oxide fuel cells (SOFC) could also work in the solid oxide electrolyser cell (SOEC) mode1 P0301-Mogensen Performance of Reversible Solid Oxide Cells: A Review Mogens Mogensen1 , Søren Højgaard Jensen1,2 , Anne Hauch1,3 , Ib Chorkendorff2 and Torben Jacobsen3 1 Fuel Cell and Solid State

448

Semiconducting chalcogenide buffer layer for oxide heteroepitaxy on Si,,001...  

E-Print Network [OSTI]

controlled laminar growth of a crystalline transition metal oxide on Si 001 without SiOx or silicide/or silicides at the Si/oxide interface. Subnanometer buffer layers can prevent interface reac- tions while, also enables flexible strain relief. We observe nei- ther oxide nor silicide formation at the buried Si

Olmstead, Marjorie

449

A New Instrument For Characterizing Solid Oxide Fuel Cell Catalysts  

E-Print Network [OSTI]

RESEARCH HIGHLIGHTS A New Instrument For Characterizing Solid Oxide Fuel Cell Catalysts From fuels to renewable energy sources. Solid oxide fuel cells (SOFCs) have enormous potential in this area A New Instrument For Characterizing Solid Oxide Fuel Cell Catalysts Rob Usiskin In partnership

450

Electrode electrolyte interlayers containing cerium oxide for electrochemical fuel cells  

DOE Patents [OSTI]

An electrochemical cell is made having a porous fuel electrode (16) and a porous air electrode (13), with solid oxide electrolyte (15) therebetween, where the air electrode surface opposing the electrolyte has a separate, attached, dense, continuous layer (14) of a material containing cerium oxide, and where electrolyte (16) contacts the continuous oxide layer (14), without contacting the air electrode (13).

Borglum, Brian P. (Edgewood, PA); Bessette, Norman F. (N. Huntingdon, PA)

2000-01-01T23:59:59.000Z

451

Mechanical Engineering Manufacturing Solid Oxide Fuel Cells for Improved Electro-  

E-Print Network [OSTI]

Uday Pal Mechanical Engineering Manufacturing Solid Oxide Fuel Cells for Improved Electro- chemical for the commercialization of solid oxide fuel cells (SOFCs) are its high manufacturing and material costs expressed in terms at 800oC with humidified hydrogen (3% H2O) as the fuel and air as the oxidant. The cells were also tested

Lin, Xi

452

MICROBIAL AMMONIA OXIDATION IN DEEP-SEA HYDROTHERMAL PLUMES  

E-Print Network [OSTI]

MICROBIAL AMMONIA OXIDATION IN DEEP-SEA HYDROTHERMAL PLUMES A DISSERTATION SUBMITTED;ABSTRACT Autotrophic ammonia oxidation has been documented for the first time in deep- sea hydrothermal autotrophic ammonia oxidation at ~ 91 nM d-1 , and potentially produces de novo organic carbon at a rate (0

Luther, Douglas S.

453

Toolbox Safety Talk Ethylene Oxide (EtO) Awareness  

E-Print Network [OSTI]

Toolbox Safety Talk Ethylene Oxide (EtO) Awareness Environmental Health & Safety Facilities Safety-in sheet to Environmental Health & Safety for recordkeeping. Ethylene Oxide (EtO) is used during hospital REQUIREMENTS Because of the severe potential health effects of Ethylene Oxide (EtO) all Cornell members

Pawlowski, Wojtek

454

Distribution of Grain Boundary Planes and Misorientations in Magnesium Oxide  

E-Print Network [OSTI]

Distribution of Grain Boundary Planes and Misorientations in Magnesium Oxide D.M. Saylor 1 , A distribution, magnesium oxide. Abstract. We have developed a technique that allows the geometry of polycrystalline magnesium oxide. Using these data, we have specified the distribution of grain boundaries within

Rohrer, Gregory S.

455

UNIVERSITY of CALIFORNIA ATOMIC LAYER DEPOSITION OF ALUMINUM OXIDE  

E-Print Network [OSTI]

UNIVERSITY of CALIFORNIA SANTA CRUZ ATOMIC LAYER DEPOSITION OF ALUMINUM OXIDE A thesis submitted deposition (ALD) of aluminum oxide on crystalline silicon and anodized aluminum substrates. A homemade ALD system is used with trimethylaluminum (TMA) and water as precursors to deposit uniform aluminum oxide

Belanger, David P.

456

Glass Based on the oxides of Molybdenum, Tungsten and Uranium  

Science Journals Connector (OSTI)

... IN previous publications from this Laboratory, attention has been directed to glasses of unusual composition based on the oxides of tellurium and vanadium1-4. This article ... the oxides of tellurium and vanadium1-4. This article describes the development of further unusual glasses based on the oxides of molybdenum, tungsten and uranium.

P. L. BAYNTON; H. RAWSON; J. E. STANWORTH

1956-10-27T23:59:59.000Z

457

Measuring Energy Sustainability  

E-Print Network [OSTI]

20 Measuring Energy Sustainability David L. Greene Abstract For the purpose of measurement, energy here is only meaningful when placed in a broader context. Still, measuring energy sustainability in relation to measures of ultimate resources, and because conflicts between fossil energy use

458

Electromagnetic Measurements at RHIC  

E-Print Network [OSTI]

Electromagnetic Measurements at RHIC Hideki Hamagaki Center for Nuclear Study Graduate School of Science the University of Tokyo #12;2006/06/29 "Electromagnetic measurements at RHIC"@ATHIC 2006 Hideki;2006/06/29 "Electromagnetic measurements at RHIC"@ATHIC 2006 Hideki Hamagaki 3 Prologue ­ scope of EM measurements · EM

Hamagaki, Hideki

459

Structural and electrochemical characterization of two proton conducting oxide thin films for a microfabricated solid oxide fuel cell  

E-Print Network [OSTI]

The use of proton conducting oxide materials as an electrolyte offers the potential to reduce the operating temperature of a solid oxide fuel cell (SOFC), leading to improved thermal management and material compatibility. ...

Capozzoli, Peter M

2006-01-01T23:59:59.000Z

460

THE IMPACT OF VARIOUS OXIDIZERS ON THE OVERALL PERFORMACE OF A DIRECT FLAME SOLID OXIDE FUEL CELL.  

E-Print Network [OSTI]

??The power output of a direct-flame solid oxide fuel cell (SOFC) was studied using hydrogen (H2) as the fuel for the flame and various oxidizers,… (more)

Donadio, Nicholas

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "measures miec oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Synthesis of graphene oxide nanosheet: A novel glucose sensor based on nickel-graphene oxide composite film  

Science Journals Connector (OSTI)

The graphene oxide (GO) nanosheets were produced by ... IR). An electrochemical sensor based on Ni/graphene (GR) composite film was developed by...2+ into the graphene oxide film modified glassy carbon electrode ...

Fereshteh Chekin; Samira Bagheri…

2014-11-01T23:59:59.000Z

462

Graphene Oxide vs. Reduced Graphene Oxide as saturable absorbers for Er-doped passively mode-locked fiber laser  

Science Journals Connector (OSTI)

In this work we demonstrate comprehensive studies on graphene oxide (GO) and reduced graphene oxide (rGO) based saturable absorbers (SA) for mode-locking of Er-doped fiber lasers. The...

Sobon, Grzegorz; Sotor, Jaroslaw; Jagiello, Joanna; Kozinski, Rafal; Zdrojek, Mariusz; Holdynski, Marcin; Paletko, Piotr; Boguslawski, Jakub; Lipinska, Ludwika; Abramski, Krzysztof M

2012-01-01T23:59:59.000Z

463

What is the Rate of the Csp2?Csp2 Reductive Elimination Step? Revealing an Unusually Fast Ni-Catalyzed Negishi-Type Oxidative Coupling Reaction  

Science Journals Connector (OSTI)

What is the Rate of the Csp2?Csp2 Reductive Elimination Step? ... For a direct quantitative investigation of the Csp2?Csp2 reductive elimination rate within a catalytic cycle, a novel oxidative coupling system in the presence of a Ni catalyst and desyl chloride as the oxidant is devised. ... This allows direct measurement of the Csp2?Csp2 reductive elimination rate constant within a catalytic cycle. ...

Liqun Jin; Hua Zhang; Peng Li; John R. Sowa, Jr.; Aiwen Lei

2009-07-06T23:59:59.000Z

464

Hydrogen Oxidation Reaction at the Ni/YSZ Anode of Solid Oxide Fuel Cells from First Principles  

Science Journals Connector (OSTI)

By means of ab initio simulations we here provide a comprehensive scenario for hydrogen oxidation reactions at the Ni/zirconia anode of solid oxide fuel cells. The simulations have also revealed that in the presence of water chemisorbed at the oxide surface, the active region for H oxidation actually extends beyond the metal/zirconia interface unraveling the role of water partial pressure in the decrease of the polarization resistance observed experimentally.

Clotilde S. Cucinotta; Marco Bernasconi; Michele Parrinello

2011-11-08T23:59:59.000Z

465

Mercury oxidation promoted by a selective catalytic reduction catalyst under simulated Powder River Basin coal combustion conditions  

SciTech Connect (OSTI)

A bench-scale reactor consisting of a natural gas burner and an electrically heated reactor housing a selective catalytic reduction (SCR) catalyst was constructed for studying elemental mercury (Hg{sup 0}) oxidation under SCR conditions. A low sulfur Powder River Basin (PRB) subbituminous coal combustion fly ash was injected into the entrained-flow reactor along with sulfur dioxide (SO{sub 2}), nitrogen oxides (NOx), hydrogen chloride (HCl), and trace Hg{sup 0}. Concentrations of Hg{sup 0} and total mercury (Hg) upstream and downstream of the SCR catalyst were measured using a Hg monitor. The effects of HCl concentration, SCR operating temperature, catalyst space velocity, and feed rate of PRB fly ash on Hg0 oxidation were evaluated. It was observed that HCl provides the source of chlorine for Hg{sup 0} oxidation under simulated PRB coal-fired SCR conditions. The decrease in Hg mass balance closure across the catalyst with decreasing HCl concentration suggests that transient Hg capture on the SCR catalyst occurred during the short test exposure periods and that the outlet speciation observed may not be representative of steady-state operation at longer exposure times. Increasing the space velocity and operating temperature of the SCR led to less Hg{sup 0} oxidized. Introduction of PRB coal fly ash resulted in slightly decreased outlet oxidized mercury (Hg{sup 2+}) as a percentage of total inlet Hg and correspondingly resulted in an incremental increase in Hg capture. The injection of ammonia (NH{sub 3}) for NOx reduction by SCR was found to have a strong effect to decrease Hg oxidation. The observations suggest that Hg{sup 0} oxidation may occur near the exit region of commercial SCR reactors. Passage of flue gas through SCR systems without NH{sub 3} injection, such as during the low-ozone season, may also impact Hg speciation and capture in the flue gas. 18 refs., 7 figs., 3 tabs.

Chun W. Lee; Shannon D. Serre; Yongxin Zhao; Sung Jun Lee; Thomas W. Hastings [U.S. Environmental Protection Agency, Research Triangle Park, NC (United States). Office of Research and Development, National Risk Management Research Laboratory

2008-04-15T23:59:59.000Z

466

Torsional texturing of superconducting oxide composite articles  

DOE Patents [OSTI]

A method of texturing a multifilamentary article having filaments comprising a desired oxide superconductor or its precursors by torsionally deforming the article is provided. The texturing is induced by applying a torsional strain which is at least about 0.3 and preferably at least about 0.6 at the surface of the article, but less than the strain which would cause failure of the composite. High performance multifilamentary superconducting composite articles having a plurality of low aspect ratio, twisted filaments with substantially uniform twist pitches in the range of about 1.00 inch to 0.01 inch (25 to 0.25 mm), each comprising a textured desired superconducting oxide material, may be obtained using this texturing method. If tighter twist pitches are desired, the article may be heat treated or annealed and the strain repeated as many times as necessary to obtain the desired twist pitch. It is preferred that the total strain applied per step should be sufficient to provide a twist pitch tighter than 5 times the diameter of the article, and twist pitches in the range of 1 to 5 times the diameter of the article are most preferred. The process may be used to make a high performance multifilamentary superconducting article, having a plurality of twisted filaments, wherein the degree of texturing varies substantially in proportion to the radial distance from the center of the article cross-section, and is substantially radially homogeneous at any given cross-section of the article. Round wires and other low aspect ratio multifilamentary articles are preferred forms. The invention is not dependent on the melting characteristics of the desired superconducting oxide. Desired oxide superconductors or precursors with micaceous or semi-micaceous structures are preferred. When used in connection with desired superconducting oxides which melt irreversibly, it provides multifilamentary articles that exhibit high DC performance characteristics and AC performance markedly superior to any currently available for these materials. In a preferred embodiment, the desired superconducting oxide material is BSCCO 2223.

Christopherson, Craig John (Grafton, MA); Riley, Jr., Gilbert N. (Marlborough, MA); Scudiere, John (Bolton, MA)

2002-01-01T23:59:59.000Z

467

Selective Catalytic Oxidation (SCO) of NH3 to N2 for Hot Exhaust Treatment  

Broader source: Energy.gov [DOE]

Investigation of a series of transition metal oxides and precious metal based catalysts for ammonia selective oxidation at low temperatures

468

Synthesis and Stability of a Nanoparticle-Infiltrated Solid Oxide Fuel Cell Electrode  

E-Print Network [OSTI]

Nanoparticle-Infiltrated Solid Oxide Fuel Cell Electrode Talinfiltrated into SOFC (Solid Oxide Fuel Cell) electrodes can

Sholklapper, Tal Z.; Radmilovic, Velimir; Jacobson, Craig P.; Visco, Steven J.; De Jonghe, Lutgard C.

2006-01-01T23:59:59.000Z

469

Synthesis and Oxidation Behavior of Nanocrystalline MCrA1Y Bond Coats  

E-Print Network [OSTI]

spraying gun passes can be critical for the oxidation behavior because of the inter-pass oxidation presence in HVOF

Ajdelsztajn, Leonardo; Tang, Feng; Picas, Josep; Kim, Geoge E.; Provenzano, Virgil; Schoenung, Julie M.

2002-01-01T23:59:59.000Z

470

EFFECT OF MECHANICAL DISCONTINUITIES ON THE STRENGTH OF POLYCRYSTALLINE ALUMINUM OXIDE  

E-Print Network [OSTI]

THE STRENGTH OF POLYCRYSTALLINE ALUMINUM OXIDE S. Wallace ofThe variables and number of aluminum oxide (almnina). size~

Wallace, J.S.

2011-01-01T23:59:59.000Z

471

E-Print Network 3.0 - acid oxidation held Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Calcium oxide Water Carbon (activated) Calcium... hypochlorite, all oxidizing agents Carbon tetrachloride Sodium Chlorates Ammonium salts, acids, powdered metals... ,...

472

E-Print Network 3.0 - acid oxidation defects-remaining Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Calcium oxide Water Carbon (activated) Calcium... hypochlorite, all oxidizing agents Carbon tetrachloride Sodium Chlorates Ammonium salts, acids, powdered metals... ,...

473

Unveiling and controlling the electronic structure of oxidized semiconductor surfaces: Crystalline oxidized InSb(100)(1 × 2)-O  

Science Journals Connector (OSTI)

The exothermic nature of oxidation causes nearly all semiconductor applications in various fields like electronics, medicine, photonics, and sensor technology to acquire an oxidized semiconductor surface part during the application manufacturing. The significance of understanding and controlling the atomic scale properties of oxidized semiconductor surfaces is expected to increase even further with the development of nanoscale semiconductor crystals. The nature of oxidized semiconductor layers is, however, hard to predict and characterize as they are usually buried and amorphous. To shed light on these issues, we pursue a different approach based on oxidized III-V semiconductor layers that are crystalline. We present a comprehensive characterization of oxidized crystalline InSb(100)(1×2)-O layers by ab initio calculations, photoelectron spectroscopy, scanning tunneling microscopy, and spectroscopy, and demonstrate the electronic band structures of different oxidized phases of the semiconductor, which elucidate the previous contradictory semiconductor-oxidation effects. At 0.5 monolayer (ML) oxidation, oxygen atoms tend to occupy subsurface Sb sites, leading to metallic states in the semiconductor band gap, which arise from top dimers. When the oxidation is increased to the 1.0–2.0 ML concentration, oxygen occupies also interstitial sites, and the insulating band structure without gap states is stabilized with unusual occupied In dangling bonds. In contrast, the 2.5–3.0 ML oxide phases undergo significant changes toward a less ordered structure. The findings suggest a methodology for manipulating the electronic structure of oxidized semiconductor layers.

J. J. K. Lång; M. P. J. Punkkinen; M. Tuominen; H.-P. Hedman; M. Vähä-Heikkilä; V. Polojärvi; J. Salmi; V.-M. Korpijärvi; K. Schulte; M. Kuzmin; R. Punkkinen; P. Laukkanen; M. Guina; K. Kokko

2014-07-29T23:59:59.000Z

474

Mechanistic Studies of Water Electrolysis and Hydrogen Electro-Oxidation on High Temperature Ceria-Based Solid Oxide  

E-Print Network [OSTI]

conversion devices with multicomponent materials (e.g., solid oxide fuel cells, electrolyzers-Based Solid Oxide Electrochemical Cells Chunjuan Zhang,,# Yi Yu,,# Michael E. Grass,,# Catherine Dejoie spectroscopy (APXPS) and a single-sided solid oxide electrochemical cell (SOC), we have studied the mechanism

Li, Weixue

475

Hibiscus Protocatechuic Acid or Esculetin Can Inhibit Oxidative LDL Induced by Either Copper Ion or Nitric Oxide Donor  

Science Journals Connector (OSTI)

Hibiscus Protocatechuic Acid or Esculetin Can Inhibit Oxidative LDL Induced by Either Copper Ion or Nitric Oxide Donor ... Several groups using different flavonoids, such as quercetin, catechin, morin, rutin, fisetin, and gossypetin, also showed that flavonoids could inhibit copper-catalyzed and macrophage-mediated LDL oxidation (13?16). ... morin and fisetin 1 ?M; quercetin and gossypetin 2 ?M). ...

Miao-Jane Lee; Fen-Pi Chou; Tsui-Hwa Tseng; Ming-Hsun Hsieh; Ming-Cheng Lin; Chau-Jong Wang

2002-02-16T23:59:59.000Z

476

Correlating catalytic methanol oxidation with the structure and oxidation state of size-1 selected Pt nanoparticles2  

E-Print Network [OSTI]

in the performance of direct methanol fuel cells (DMFC), which produce electricity from11 liquid fuel without1 Correlating catalytic methanol oxidation with the structure and oxidation state of size-1 * Corresponding author: roldan@ucf.edu9 Keywords: platinum; methanol oxidation; operando; XAS; EXAFS; alumina

Kik, Pieter

477

Measurement of valence band structure in arbitrary dielectric films  

SciTech Connect (OSTI)

A new way of measuring the band structure of various dielectric materials using the secondary electron emission from Auger neutralization of ions is introduced. The first example of this measurement scheme is the magnesium oxide (MgO) films with respect to the application of the films in the display industries. The density of state in the valence bands of MgO film and MgO film with a functional layer (FL) deposited over a dielectric surface reveals that the density peak of film with a FL is considerably less than that of film, thereby indicating a better performance of MgO film with functional layer in display devices. The second example of the measurement is the boron-zinc oxide (BZO) films with respect to the application of the films to the development of solar cells. The measurement of density of state in BZO film suggests that a high concentration of boron impurity in BZO films may enhance the transition of electrons and holes through the band gap from the valence to the conduction band in zinc oxide crystals; thereby improving the conductivity of the film. Secondary electron emission by the Auger neutralization of ions is highly instrumental for the determination of the density of states in the valence band of dielectric materials.

Uhm, Han S., E-mail: hsuhm@kw.ac.kr [Department of Electrophysics, Kwangwoon University, 447-1 Wolgye-Dong, Nowon-Gu, Seoul 139-701 (Korea, Republic of); Choi, Eun H. [Department of Electrophysics, Kwangwoon University, 447-1 Wolgye-Dong, Nowon-Gu, Seoul 139-701 (Korea, Republic of)] [Department of Electrophysics, Kwangwoon University, 447-1 Wolgye-Dong, Nowon-Gu, Seoul 139-701 (Korea, Republic of)

2012-10-15T23:59:59.000Z

478

Isothermal heat measurements of TBP-nitric acid solutions  

SciTech Connect (OSTI)

Net heats of reaction were measured in an isothermal calorimeter for TBP/HNO{sub 3} solutions at ambient pressure and temperatures above 100{degrees}C. Carbon and nitrogen balances were performed giving the reaction stoichiometry. Rate expressions were derived and rate constants determined for both the single and two phase systems which included mass lost from the reacting system by evaporation. This mathematical model was fit to the experimental data (including the measured net heat and off-gas rate) gathered over a wide range of conditions. The oxidation rate constant was determined to be 5.4E-4 min{sup -1} at 110{degrees}C for an open {open_quotes}vented{close_quotes} system as compared to >1E-3min{sup -1} in a closed system. The heat released per unit material oxidized was also reduced due to a decrease in dissolved oxidants and an inefficient reduction of HNO{sub 3}. Oxidation in the organic phase was found to be first order in nitric acid and pseudo-zero order in butylnitrate and water.

Smith, J.R.; Cavin, W.S. [Westinghouse Savannah River Company, Aiken, SC (United States)

1995-12-31T23:59:59.000Z

479

Characterization of Neptunium Oxide Generated Using the HB-Line Phase II Flowsheet  

SciTech Connect (OSTI)

Approximately 98 grams of neptunium(IV) oxide (NpO{sub 2}) were produced at the Savannah River Technology Center (SRTC) for use in gas generation tests to support the neptunium stabilization program at the Savannah River Site (SRS). The NpO{sub 2} was produced according to the anticipated HB-Line flowsheet consisting of anion exchange, oxalate precipitation, filtration, and calcination. Characterization of the NpO{sub 2} product to be used in gas generation tests included bulk and tap density measurements, X-ray diffraction, particle size distribution, specific surface area measurements, and moisture analysis.

Duffey, J

2003-08-29T23:59:59.000Z

480

Oxidative DNA damage and its repair in rat spleen following subchronic exposure to aniline  

SciTech Connect (OSTI)

The mechanisms by which aniline exposure elicits splenotoxic response, especially the tumorigenic response, are not well-understood. Splenotoxicity of aniline is associated with iron overload and generation of reactive oxygen species (ROS) which can cause oxidative damage to DNA, proteins and lipids (oxidative stress). 8-Hydroxy-2'-deoxyguanosine (8-OHdG) is one of the most abundant oxidative DNA lesions resulting from ROS, and 8-oxoguanine glycosylase 1 (OGG1), a specific DNA glycosylase/lyase enzyme, plays a key role in the removal of 8-OHdG adducts. This study focused on examining DNA damage (8-OHdG) and repair (OGG1) in the spleen in an experimental condition preceding a tumorigenic response. To achieve that, male Sprague-Dawley rats were subchronically exposed to aniline (0.5 mmol/kg/day via drinking water for 30 days), while controls received drinking water only. Aniline treatment led to a significant increase in splenic oxidative DNA damage, manifested as a 2.8-fold increase in 8-OHdG levels. DNA repair activity, measured as OGG1 base excision repair (BER) activity, increased by {approx} 1.3 fold in the nuclear protein extracts (NE) and {approx} 1.2 fold in the mitochondrial protein extracts (ME) of spleens from aniline-treated rats as compared to the controls. Real-time PCR analysis for OGG1 mRNA expression in the spleen revealed a 2-fold increase in expression in aniline-treated rats than the controls. Likewise, OGG1 protein expression in the NEs of spleens from aniline-treated rats was {approx} 1.5 fold higher, whereas in the MEs it was {approx} 1.3 fold higher than the controls. Aniline treatment also led to stronger immunostaining for both 8-OHdG and OGG1 in the spleens, confined to the red pulp areas. It is thus evident from our studies that aniline-induced oxidative stress is associated with increased oxidative DNA damage. The BER pathway was also activated, but not enough to prevent the accumulation of oxidative DNA damage (8-OHdG). Accumulation of mutagenic oxidative DNA lesions in the spleen following exposure to aniline could play a critical role in the tumorigenic process.

Ma Huaxian; Wang Jianling [Department of Pathology, University of Texas Medical Branch, Galveston, TX 77555 (United States); Abdel-Rahman, Sherif Z. [Department of Preventive Medicine and Community Health, University of Texas Medical Branch, Galveston, TX 77555 (United States); Boor, Paul J. [Department of Pathology, University of Texas Medical Branch, Galveston, TX 77555 (United States); Khan, M. Firoze [Department of Pathology, University of Texas Medical Branch, Galveston, TX 77555 (United States)], E-mail: mfkhan@utmb.edu

2008-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "measures miec oxides" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Manganese Oxidation In A Natural Marine Environment- San Antonio Bay  

E-Print Network [OSTI]

and can be oxidized to any higher oxidation state, but Mn4+ is the most stable form first achieved (Stumm and Morgan 1996; Armstrong 2008). Mn3+ is a transitional/ metastable state that persists in nature before being further oxidized to the stable form... of Mn4+, which has also been described as a thermodynamic sink (Hem and Lind 1983; Stumm and Morgan 1996; Armstrong 2008). Mn oxides are found in the geologic record associated with other metal oxides such as iron (Fe) and cerium (Ce) (Braun et al...

Neyin, Rosemary Ogheneochuko

2013-04-12T23:59:59.000Z

482

Oxidation of boron silicide and materials based on it  

SciTech Connect (OSTI)

Boron silicide and compounds based on its containing titanium, chromium, nickel, and yttrium and scandium oxides are studied for their oxidation in air from room temperature to 1300{degrees}C. It is shown that chromium boride markedly improves the heat resistance of B{sub 4}Si over a wide temperature range (700-1300{degrees}C) probably as a result chromium-oxide dissolution in borosilicate glass and alteration of its structure. A favorable effect of yttrium and scandium oxides as well of nickel silicide appears at above 1000{degrees}C as a result of forming complex oxide compounds in the scale.

Golovko, E.I.; Makarenko, G.N.; Voitovich, R.F.; Fedorus, V.B. [Institute of Materials Science, Kiev (Russian Federation)

1994-05-01T23:59:59.000Z

483

Lithium metal reduction of plutonium oxide to produce plutonium metal  

DOE Patents [OSTI]

A method is described for the chemical reduction of plutonium oxides to plutonium metal by the use of pure lithium metal. Lithium metal is used to reduce plutonium oxide to alpha plutonium metal (alpha-Pu). The lithium oxide by-product is reclaimed by sublimation and converted to the chloride salt, and after electrolysis, is removed as lithium metal. Zinc may be used as a solvent metal to improve thermodynamics of the reduction reaction at lower temperatures. Lithium metal reduction enables plutonium oxide reduction without the production of huge quantities of CaO--CaCl.sub.2 residues normally produced in conventional direct oxide reduction processes.

Coops, Melvin S. (Livermore, CA)

1992-01-01T23:59:59.000Z

484

Fundamental kinetics of methane oxidation in supercritical water. Summary report  

SciTech Connect (OSTI)

Fundamental understanding of the oxidation of compounds in supercritical water is essential for the design, development and operation of a supercritical water oxidation unit. Previous work in our group determined the oxidation kinetics of carbon monoxide and ethanol in supercritical water for temperatures ranging from 400 to 540 C. Oxidation studies of methane up to 700 C have recently been completed and are presented in this report. Theoretical studies of fundamental kinetics and mechanistic pathways for the oxidation of methane in supercritical water are discussed. Application of current gas phase elementary reaction models are briefly presented and their limitations discussed.

Webley, P.A.; Tester, J.W. [Massachusetts Inst. of Tech., Cambridge, MA (United States). Dept. of Chemical Engineering

1989-05-22T23:59:59.000Z

485

Diacylglycerol kinase regulation of protein kinase D during oxidative stress-induced intestinal cell injury  

SciTech Connect (OSTI)

We recently demonstrated that protein kinase D (PKD) exerts a protective function during oxidative stress-induced intestinal epithelial cell injury; however, the exact role of DAG kinase (DGK){zeta}, an isoform expressed in intestine, during this process is unknown. We sought to determine the role of DGK during oxidative stress-induced intestinal cell injury and whether DGK acts as an upstream regulator of PKD. Inhibition of DGK with R59022 compound or DGK{zeta} siRNA transfection decreased H{sub 2}O{sub 2}-induced RIE-1 cell apoptosis as measured by DNA fragmentation and increased PKD phosphorylation. Overexpression of kinase-dead DGK{zeta} also significantly increased PKD phosphorylation. Additionally, endogenous nuclear DGK{zeta} rapidly translocated to the cytoplasm following H{sub 2}O{sub 2} treatment. Our findings demonstrate that DGK is involved in the regulation of oxidative stress-induced intestinal cell injury. PKD activation is induced by DGK{zeta}, suggesting DGK is an upstream regulator of oxidative stress-induced activation of the PKD signaling pathway in intestinal epithelial cells.

Song Jun [Department of Surgery, University of Texas Medical Branch, 301 University Blvd., Children's Hospital Room 3.200-E, Galveston, TX 77555-0353 (United States); Li Jing [Department of Surgery, University of Texas Medical Branch, 301 University Blvd., Children's Hospital Room 3.200-E, Galveston, TX 77555-0353 (United States); Sealy Center for Cancer Cell Biology, University of Texas Medical Branch, 301 University Blvd., Galveston, TX 77555-1048 (United States); Mourot, Joshua M. [Department of Surgery, University of Texas Medical Branch, 301 University Blvd., Children's Hospital Room 3.200-E, Galveston, TX 77555-0353 (United States); Mark Evers, B. [Department of Surgery, University of Texas Medical Branch, 301 University Blvd., Children's Hospital Room 3.200-E, Galveston, TX 77555-0353 (United States); Sealy Center for Cancer Cell Biology, University of Texas Medical Branch, 301 University Blvd., Galveston, TX 77555-1048 (United States); Chung, Dai H. [Department of Surgery, University of Texas Medical Branch, 301 University Blvd., Children's Hospital Room 3.200-E, Galveston, TX 77555-0353 (United States); Sealy Center for Cancer Cell Biology, University of Texas Medical Branch, 301 University Blvd., Galveston, TX 77555-1048 (United States)], E-mail: dhchung@utmb.edu

2008-10-17T23:59:59.000Z

486

Cast Stone Oxidation Front Evaluation: Preliminary Results For Samples Exposed To Moist Air  

SciTech Connect (OSTI)

The rate of oxidation is important to the long-term performance of reducing salt waste forms because the solubility of some contaminants, e.g., technetium, is a function of oxidation state. TcO{sub 4}{sup ?} in the salt solution is reduced to Tc(IV) and has been shown to react with ingredients in the waste form to precipitate low solubility sulfide and/or oxide phases. Upon exposure to oxygen, the compounds containing Tc(IV) oxidize to the pertechnetate ion, Tc(VII)O{sub 4}{sup ?}, which is very soluble. Consequently the rate of technetium oxidation front advancement into a monolith and the technetium leaching profile as a function of depth from an exposed surface are important to waste form performance and ground water concentration predictions. An approach for measuring contaminant oxidation rate (effective contaminant specific oxidation rate) based on leaching of select contaminants of concern is described in this report. In addition, the relationship between reduction capacity and contaminant oxidation is addressed. Chromate (Cr(VI) was used as a non-radioactive surrogate for pertechnetate, Tc(VII), in Cast Stone samples prepared with 5 M Simulant. Cast Stone spiked with pertechnetate was also prepared and tested. Depth discrete subsamples spiked with Cr were cut from Cast Stone exposed to Savannah River Site (SRS) outdoor ambient temperature fluctuations and moist air. Depth discrete subsamples spiked with Tc-99 were cut from Cast Stone exposed to laboratory ambient temperature fluctuations and moist air. Similar conditions are expected to be encountered in the Cast Stone curing container. The leachability of Cr and Tc-99 and the reduction capacities, measured by the Angus-Glasser method, were determined for each subsample as a function of depth from the exposed surface. The results obtained to date were focused on continued method development and are preliminary and apply to the sample composition and curing / exposure conditions described in this report. The Cr oxidation front (depth to which soluble Cr was detected) for the Cast Stone sample exposed for 68 days to ambient outdoor temperatures and humid air (total age of sample was 131 days) was determined to be about 35 mm below the top sample surface exposed. The Tc oxidation front, depth at which Tc was insoluble, was not determined. Interpretation of the results indicates that the oxidation front is at least 38 mm below the exposed surface. The sample used for this measurement was exposed to ambient laboratory conditions and humid air for 50 days. The total age of the sample was 98 days. Technetium appears to be more easily oxidized than Cr in the Cast Stone matrix. The oxidized forms of Tc and Cr are soluble and therefore leachable. Longer exposure times are required for both the Cr and Tc spiked samples to better interpret the rate of oxidation. Tc spiked subsamples need to be taken further from the exposed surface to better define and interpret the leachable Tc profile. Finally Tc(VII) reduction to Tc(IV) appears to occur relatively fast. Results demonstrated that about 95 percent of the Tc(VII) was reduced to Tc(IV) during the setting and very early stage setting for a Cast Stone sample cured 10 days. Additional testing at longer curing times is required to determine whether additional time is required to reduce 100 % of the Tc(VII) in Cast Stone or whether the Tc loading exceeded the ability of the waste form to reduce 100 % of the Tc(VII). Additional testing is required for samples cured for longer times. Depth discrete subsampling in a nitrogen glove box is also required to determine whether the 5 percent Tc extracted from the subsamples was the result of the sampling process which took place in air. Reduction capacity measurements (per the Angus-Glasser method) performed on depth discrete samples could not be correlated with the amount of chromium or technetium leached from the depth discrete subsamples or with the oxidation front inferred from soluble chromium and technetium (i.e., effective Cr and Tc oxidation fronts). Residual reduction capacity

Langton, C. A.; Almond, P. M.

2013-11-26T23:59:59.000Z

487

NREL: Measurements and Characterization - About Measurements and  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

About Measurements and Characterization About Measurements and Characterization Graphic of three intersecting circles depicting the M&C modes of support, collaborative R&D, and technique development. The modes of operation for the M&C group at NREL integrates support, collaborative R&D, and technique development. The Measurements and Characterization (M&C) division at the National Renewable Energy Laboratory and the National Center for Photovoltaics provides characterization support, collaborative research, and the development of new measurement techniques for the advancement of the photovoltaic (PV) generation of energy. The M&C group uses experienced researchers and state-of-the-art capabilities to solve problems in all phases of material and device development. Throughout this site you will

488

Oxidized low density lipoprotein increases RANKL level in human vascular cells. Involvement of oxidative stress  

SciTech Connect (OSTI)

Highlights: •Oxidized LDL enhances RANKL level in human smooth muscle cells. •The effect of OxLDL is mediated by the transcription factor NFAT. •UVA, H{sub 2}O{sub 2} and buthionine sulfoximine also increase RANKL level. •All these effects are observed in human fibroblasts and endothelial cells. -- Abstract: Receptor Activator of NF?B Ligand (RANKL) and its decoy receptor osteoprotegerin (OPG) have been shown to play a role not only in bone remodeling but also in inflammation, arterial calcification and atherosclerotic plaque rupture. In human smooth muscle cells, Cu{sup 2+}-oxidized LDL (CuLDL) 10–50 ?g/ml increased reactive oxygen species (ROS) and RANKL level in a dose-dependent manner, whereas OPG level was not affected. The lipid extract of CuLDL reproduced the effects of the whole particle. Vivit, an inhibitor of the transcription factor NFAT, reduced the CuLDL-induced increase in RANKL, whereas PKA and NF?B inhibitors were ineffective. LDL oxidized by myeloperoxidase (MPO-LDL), or other pro-oxidant conditions such as ultraviolet A (UVA) irradiation, incubation with H{sub 2}O{sub 2} or with buthionine sulfoximine (BSO), an inhibitor of glutathione synthesis{sub ,} also induced an oxidative stress and enhanced RANKL level. The increase in RANKL in pro-oxidant conditions was also observed in fibroblasts and endothelial cells. Since RANKL is involved in myocardial inflammation, vascular calcification and plaque rupture, this study highlights a new mechanism whereby OxLDL might, by generation of an oxidative stress, exert a deleterious effect on different cell types of the arterial wall.

Mazière, Cécile, E-mail: maziere.cecile@chu-amiens.fr [Biochemistry Laboratory, South Hospital University, René Laennec Avenue, Amiens 80000 (France)] [Biochemistry Laboratory, South Hospital University, René Laennec Avenue, Amiens 80000 (France); Salle, Valéry [Internal Medicine, North Hospital University, Place Victor Pauchet, Amiens 80000 (France) [Internal Medicine, North Hospital University, Place Victor Pauchet, Amiens 80000 (France); INSERM U1088 (EA 4292), SFR CAP-Santé (FED 4231), University of Picardie – Jules Verne (France); Gomila, Cathy; Mazière, Jean-Claude [Biochemistry Laboratory, South Hospital University, René Laennec Avenue, Amiens 80000 (France)] [Biochemistry Laboratory, South Hospital University, René Laennec Avenue, Amiens 80000 (France)

2013-10-18T23:59:59.000Z

489

ENS'07 Paris, France, 3-4 December 2007 NANOSTRUCTURES DEFINED BY THE LOCAL OXIDATION  

E-Print Network [OSTI]

53 Praha 6, Czech Republic ABSTRACT The results of Local Anodic Oxidation (LAO) on the thin Ga in monitoring substrate tip water oxide substrate tip water oxide Fig. 1 Local anodic oxidation by the AFM tip for pattern transfer, local anodic oxidation and subsequent use of the oxide as the etch mask, and maskless

Boyer, Edmond

490

Why sequence carbon monoxide oxidizing thermophiles?  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

carbon monoxide oxidizing thermophiles? carbon monoxide oxidizing thermophiles? Many microbes that use carbon monoxide as an energy source are found in high temperature environments such as geothermal areas. Researchers think that these carboxydotrophs may be involved in reducing potentially toxic carbon monoxide hotspots by combine with water to form hydrogen, carbon dioxide and acetate, which are in turn used for thermophilic energy conservation and carbon sequestration mechanisms. The project focuses on sequencing two closely related microbes, one of which is Carboxydothermus hydrogenformans. A strain of C. hydrogenformans has been grown in hydrogen-enriched synthesis gas (syngas), which contains a mix of hydrogen and carbon monoxide. Researchers are interested in sequencing both microbial strains to track the genome's evolution and

491

Flameless thermal oxidation. Innovative technology summary report  

SciTech Connect (OSTI)

The Flameless Thermal Oxidizer (FTO) is a commercial technology offered by Thermatrix, Inc. The FTO has been demonstrated to be an effective destructive technology for process and waste stream off-gas treatment of volatile organic compounds (VOCs), and in the treatment of VOC and chlorinated volatile organic compounds (CVOCs) off-gases generated during site remediation using either baseline or innovative in situ environmental technologies. The FTO process efficiently converts VOCs and CVOCs to carbon dioxide, water, and hydrogen chloride. When FTO is coupled with a baseline technology, such as soil vapor extraction (SVE), an efficient in situ soil remediation system is produced. The innovation is in using a simple, reliable, scalable, and robust technology for the destruction of VOC and CVOC off-gases based on a des