Sample records for measures miec oxides

  1. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  2. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    H2O electrolysis and H2 oxidation, dense thin-film CeO2-x electrodes with Au current collectors were deposited onto YSZ electrolytes with a thin-film Pt counter electrode. The...

  3. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See theDoctoral20ALSNewstt^ \AP-XPS Measures MIECAP-XPS

  4. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearchSOLICITATIONIMODI FICATION OF CONTRACT 1 OTATI OEP AEGraphic of09 I N DAP-XPS

  5. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearchSOLICITATIONIMODI FICATION OF CONTRACT 1 OTATI OEP AEGraphic of09 I N

  6. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearchSOLICITATIONIMODI FICATION OF CONTRACT 1 OTATI OEP AEGraphic of09 I NAP-XPS

  7. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See theDoctoral20ALSNewstt^ \ #ANUDlSiTM-40AP-XPS

  8. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See theDoctoral20ALSNewstt^ \ #ANUDlSiTM-40AP-XPSAP-XPS

  9. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See theDoctoral20ALSNewstt^ \

  10. Direct Measurement of Oxygen Incorporation into Thin Film Oxides...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Measurement of Oxygen Incorporation into Thin Film Oxides at Room Temperature Upon Ultraviolet Phton Irradiation. Direct Measurement of Oxygen Incorporation into Thin Film Oxides...

  11. Direct measurement and analysis of cyclohexadienyl oxidation

    E-Print Network [OSTI]

    Taylor, James Wagner

    2005-01-01T23:59:59.000Z

    The oxidation of cyclohexadienyl radical (c-C?H?) and similar resonantly stabilized radicals are important in an astonishing array of processes in nature. Cyclohexadienyl radical has been postulated to be significant in a ...

  12. Hydrogen pickup measurements in zirconium alloys: Relation to oxidation kinetics

    E-Print Network [OSTI]

    Motta, Arthur T.

    Hydrogen pickup measurements in zirconium alloys: Relation to oxidation kinetics Adrien Couet a to reduce hydrogen pickup during operation, and the associated cladding degradation. The present study focuses on precisely and accurately measuring hydrogen pickup fraction for a set of alloys to specifically

  13. Predicted versus measured tritium oxide concentrations at SRS

    SciTech Connect (OSTI)

    Simpkins, A.A.

    1995-12-01T23:59:59.000Z

    Measured tritium oxide concentrations at various offsite locations are compared with concentrations predicted by three computer codes that are utilized at SRS to predict doses to the maximally exposed offsite individuals. Annual average concentrations predicted by the computer programs were compared with measured average concentrations taken form data contained in the last ten years of SRS Environmental Reports. The computer programs used for the comparison are ACAIRQ, CAP88, and MAXIGASP.

  14. On-Board Measurement of Ammonia and Nitrous Oxide Using Feedback...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Board Measurement of Ammonia and Nitrous Oxide Using Feedback Absorption Laser Spectroscopy Combined with Amplified Resonance and Low Pressure Sampling On-Board Measurement of...

  15. Solid oxide fuel cells having porous cathodes infiltrated with oxygen-reducing catalysts

    DOE Patents [OSTI]

    Liu, Meilin; Liu, Ze; Liu, Mingfei; Nie, Lifang; Mebane, David Spencer; Wilson, Lane Curtis; Surdoval, Wayne

    2014-08-12T23:59:59.000Z

    Solid-oxide fuel cells include an electrolyte and an anode electrically coupled to a first surface of the electrolyte. A cathode is provided, which is electrically coupled to a second surface of the electrolyte. The cathode includes a porous backbone having a porosity in a range from about 20% to about 70%. The porous backbone contains a mixed ionic-electronic conductor (MIEC) of a first material infiltrated with an oxygen-reducing catalyst of a second material different from the first material.

  16. Pulsed DD Neutron Generator Measurements for HEU Oxide Fuel Pins Using Liquid Scintillators with Pulse Shape Discrimination

    E-Print Network [OSTI]

    Pennycook, Steve

    measurements have been performed on high-enriched uranium (HEU) oxide fuel pins and depleted uranium metal

  17. Photo-oxidation of Ge Nanocrystals: Kinetic Measurements by In Situ Raman Spectroscopy

    E-Print Network [OSTI]

    2008-01-01T23:59:59.000Z

    Photo-oxidation of Ge Nanocrystals: Kinetic Measurements byBerkeley, CA, 94720 ABSTRACT Ge nanocrystals are formed inthe Raman spectra of the Ge nanocrystals in-situ. The

  18. Ultra-thin Titanium Oxide Films on Accession #s 00936, 00937,00938 Mo(112), Measured by XPS Technique: XPS

    E-Print Network [OSTI]

    Goodman, Wayne

    Ultra-thin Titanium Oxide Films on Accession #s 00936, 00937,00938 Mo(112), Measured by XPS preparation methods were employed to grow a well-ordered ultra-thin titanium oxide film on Mo(J (2), The tirst: photoemission; titanium oxide; tllin film PACS: 81.15.Gh. 79,60.Dp SPECIMEN DESCRIPTION (Accession #00936) Host

  19. Micro-PIXE measurement of Ni distribution over supported nickel oxide catalyst

    SciTech Connect (OSTI)

    Ahmed, M.; Rahman, A.; Nickel, J. [King Fahd Univ., Dhahran (Saudi Arabia)] [and others

    1994-12-31T23:59:59.000Z

    Supported nickel oxide catalysts have a wide range of applications in petrochemical industry. This work reports the results of a micro-PIXE measurement of Ni distribution in a supported nickel oxide catalyst over individual silica base particles, 60-200 {mu}m in size. These catalysts were synthesized with 1% and 5% then calcined at 400 {degrees}C. A 2.5 MeV proton microbeam was used to scan the samples of individual grains. Two dimensional distribution maps of Ni and Si have been measured. This paper discusses the important effects of the process of calcination on the distribution of Ni. The effects of different nickel loading and other synthesis conditions will also be discussed.

  20. Measurement of Nitric Oxide Production from Lymphatic Entothelial Cells Under Mechanical Stimuli

    E-Print Network [OSTI]

    Jafarnejad, Mohammad 1987-

    2012-11-16T23:59:59.000Z

    MEASUREMENT OF NITRIC OXIDE PRODUCTION FROM LYMPHATIC ENDOTHELIAL CELLS UNDER MECHANICAL STIMULI A Thesis by MOHAMMAD JAFARNEJAD Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... Engineering Copyright 2012 Mohammad Jafarnejad ii ABSTRACT The lymphatic system plays an important role in fluid and protein balance within the interstitial spaces. Its dysfunction could result in a number of debilitating diseases, namely...

  1. Kinetics of rapid oxidant consumption: measurements with a rotating ring disc electrode

    SciTech Connect (OSTI)

    Jaworske, D.A.

    1983-01-01T23:59:59.000Z

    Coastal and marine waters receive strong oxidants, such as ozone and chlorine, from several natural and anthropogenic sources. These oxidants react rapidly with Br/sup -/ and I/sup -/ in seawater to produce Br/sub 2/, I/sub 2/ and various hydrolysis products. The fate of these halogen products is of geochemical and biological interest. The rotating ring disc electrode (RRDE) was used to study the rapid decay of these oxidants in natural waters. Copper-plated disc experiments address the hypothesis that Cu catalyzes the decomposition of oxidant. Pseudo first-order and second-order reaction kinetics of model compounds and field samples were also studied, via in situ generation of Br/sub 3/. Pseudo first-order behavior is observed for ammonia and glycine, and the rate constants obtained from the RRDE method compare favorably with the literature (8.1 x 10/sup 7/ and 8.5 x 10/sup 7/ L/mol-sec, respectively). Second-order behavior is observed in natural water samples collected from the Patuxent River. Calculations suggest that the observed fast demand has a rate constant in excess of 10/sup 7/ L/mol-sec, and that the substrate responsible for the demand approaches concentrations of 1 x 10/sup -5/ M. The ubiquitous distribution of rapid demand, as measured in the Patuxent estuary, suggests that proteinaceous organosulfur may contribute to the observed rapid demand.

  2. The underwater coincidence counter for plutonium measurements in mixed-oxide fuel assemblies manual

    SciTech Connect (OSTI)

    G. W. Eccleston; H. O. Menlove; M. Abhold; M. Baker; J. Pecos

    1999-05-01T23:59:59.000Z

    This manual describes the Underwater Coincidence Counter (UWCC) that has been designed for the measurement of plutonium in mixed-oxide (MOX) fuel assemblies prior to irradiation. The UWCC uses high-efficiency {sup 3}He neutron detectors to measure the spontaneous-fission and induced-fission rates in the fuel assembly. Measurements can be made on MOX fuel assemblies in air or underwater. The neutron counting rate is analyzed for singles, doubles, and triples time correlations to determine the {sup 240}Pu effective mass per unit length of the fuel assembly. The system can verify the plutonium loading per unit length to a precision of less than 1% in a measurement time of 2 to 3 minutes. System design, components, performance tests, and operational characteristics are described in this manual.

  3. Verification of d-wave pairing symmetry by microwave intermodulation distortion measurements in yttrium barium copper oxide

    E-Print Network [OSTI]

    Park, Sang-Hoon, Ph. D. Massachusetts Institute of Technology

    2004-01-01T23:59:59.000Z

    We report measurements of the temperature and power dependence of the microwave frequency intermodulation distortion (IMD) in high quality pulsed laser deposition (PLD) Yttrium Barium Copper Oxide (YBCO) on LaAlO3 substrate. ...

  4. Liquidus Temperature Measurements for Modeling Oxide Glass Systems Relevant to Nuclear Waste Vitrification

    SciTech Connect (OSTI)

    Hanni, Jonathan; Pressly, Eric D.; Crum, Jarrod V.; Minister, Kevin B.; Tran, Diana N.; Hrma, Pavel R.; Vienna, John D.

    2005-12-01T23:59:59.000Z

    Liquidus temperatures TL have been measured and primary phases have been determined for 42 (from an initial test matrix of 60) compositions within the Al2O3-B2O3-CaO-Na2O-SiO2 glass forming network. These data have been used to test TL calculations and primary phase predictions obtained using a modified associate species model (ASM). This paper highlights the strong linear correlations between composition and TL for glasses within the same primary phase fields, the strengths of the ASM in determining TL and phase for glasses observed to precipitate nepheline, and weaknesses of the ASM in predicting phase information and TL for calcia- and boria-rich glasses. TL has also been measured for glasses using two baseline compositions from the five-component network that have been individually doped with Fe2O3, Li2O, NiO, ZrO2, Cr2O3, ZnO, and MnO. These additional oxide glasses are intended for use as benchmark data for testing the model as more oxides are included.

  5. Oxide thickness measurement technique for duplex-layer Zircaloy-4 cladding

    SciTech Connect (OSTI)

    McClelland, R.G.; O'Leary, P.M. (Siemens Nuclear Power Corp., Richland, WA (United States))

    1992-01-01T23:59:59.000Z

    Siemens Nuclear Power Corporation (SNP) is investigating the use of duplex-layer Zircaloy-4 tubing to improve the waterside corrosion resistance of cladding for high-burnup pressurized water reactor (PWR) fuel designs. Standard SNP PWR cladding is typically 0.762-mm (0.030-in.)-thick Zircaloy-4. The SNP duplex cladding is nominally 0.660-mm (0.026-in.)-thick Zircalloy-4 with an [approximately]0.102-mm (0.004-in.) outer layer of another, more corrosion-resistant, zirconium-based alloy. It is common industry practice to monitor the in-reactor corrosion behavior of Zircaloy cladding by using an eddy-current lift-off' technique to measure the oxide thickness on the outer surface of the fuel cladding. The test program evaluated three different cladding samples, all with the same outer diameter and wall thickness: Zircaloy-4 and duplex clad types D2 and D4.

  6. Evaluation and Comparison of Test Methods to Measure the Oxidation Stability of Neat Biodiesel

    SciTech Connect (OSTI)

    Westbrook, S. R.

    2005-11-01T23:59:59.000Z

    The purpose of this project was to compare and evaluate several candidate test methods for evaluating oxidation stability of biodiesel.

  7. Method Evaluation And Field Sample Measurements For The Rate Of Movement Of The Oxidation Front In Saltstone

    SciTech Connect (OSTI)

    Almond, P. M. [Savannah River Site (SRS), Aiken, SC (United States); Kaplan, D. I. [Savannah River Site (SRS), Aiken, SC (United States); Langton, C. A. [Savannah River Site (SRS), Aiken, SC (United States); Stefanko, D. B. [Savannah River Site (SRS), Aiken, SC (United States); Spencer, W. A. [Savannah River Site (SRS), Aiken, SC (United States); Hatfield, A. [Clemson University, Clemson, SC (United States); Arai, Y. [Clemson University, Clemson, SC (United States)

    2012-08-23T23:59:59.000Z

    The objective of this work was to develop and evaluate a series of methods and validate their capability to measure differences in oxidized versus reduced saltstone. Validated methods were then applied to samples cured under field conditions to simulate Performance Assessment (PA) needs for the Saltstone Disposal Facility (SDF). Four analytical approaches were evaluated using laboratory-cured saltstone samples. These methods were X-ray absorption spectroscopy (XAS), diffuse reflectance spectroscopy (DRS), chemical redox indicators, and thin-section leaching methods. XAS and thin-section leaching methods were validated as viable methods for studying oxidation movement in saltstone. Each method used samples that were spiked with chromium (Cr) as a tracer for oxidation of the saltstone. The two methods were subsequently applied to field-cured samples containing chromium to characterize the oxidation state of chromium as a function of distance from the exposed air/cementitious material surface.

  8. Novel lanthanide-labeled metal oxide nanoparticles improve the measurement of in vivo clearance and translocation

    E-Print Network [OSTI]

    Abid, Aamir D; Anderson, Donald S; Das, Gautom K; Van Winkle, Laura S; Kennedy, Ian M

    2013-01-01T23:59:59.000Z

    and translocation of europium-doped gadolinium oxideemission from the lanthanide Europium ion, and has a similarcorrespond to monoclinic europium oxide (PDF 00-034-0072). [

  9. Hard X-ray Fluorescence Measurements of Heteroepitaxial Solid Oxide Fuel Cell Cathode Materials

    SciTech Connect (OSTI)

    Davis, Jacob N.; Miara, Lincoln J.; Saraf, Laxmikant V.; Kaspar, Tiffany C.; Gopalan, Srikanth; Pal, Uday B.; Woicik, Joseph C.; Basu, Soumendra N.; Ludwig, Karl F.

    2012-12-01T23:59:59.000Z

    Commonly, SOFCs are operated at high temperatures (above 800°C). At these temperatures expensive housing is needed to contain an operating stack as well as coatings to contain the oxidation of the metallic interconnects. Lowering the temperature of an operating device would allow for more conventional materials to be used, thus lowering overall cost. Understanding the surface chemical states of cations in the surface of the SOFC cathode is vital to designing a system that will perform well at lower temperatures. The samples studied were grown by pulsed laser deposition (PLD) at the Environmental Molecular Sciences Laboratory (EMSL) at Pacific Northwest National Laboratory (PNNL). 20% strontium doped lanthanum manganite (LSM-20) was grown on YSZ and NGO (neodymium gallate). The films on YSZ have a fiber texture. LSM-20 on NGO is heteroepitaxial. Lanthanum strontium cobalt ferrite (LSCF-6428) films were grown on LAO and YSZ with a GDC barrier layer. Total X-ray Reflection Fluorescence (TXRF) was used to depth profile the samples. In a typical experiment, the angle of the incident beam is varied though the critical angle. Below the critical angle, the x-ray decays as an evanescent wave and will only penetrate the top few nanometers. TXRF experiments done on LSM films have suggested strontium segregates to the surface and form strontium enriched nanoparticles (1). It should be pointed out that past studies have focused on 30% strontium A-site doping, but this project uses 20% strontium doped lanthanum manganite. XANES and EXAFS data were taken as a function of incoming angle to probe composition as a function of depth. XANES spectra can be difficult to analyze fully. For other materials density functional theory calculations compared to near edge measurements have been a good way to understand the 3d valence electrons (2).

  10. Fundamental studies of perovskite related oxide thin films for oxygen electrocatalysis at intermediate temperatures

    E-Print Network [OSTI]

    Lee, Dongkyu, Ph. D. Massachusetts Institute of Technology

    2014-01-01T23:59:59.000Z

    Discovering highly active and stable catalysts for electrochemical energy conversion and storage is essential to envision a new generation of renewable energy applications. Mixed ionic and electronic conductors (MIECs) ...

  11. Oxidation kinetics of methylphosphonic acid in supercritical water : experimental measurements and model development

    E-Print Network [OSTI]

    Sullivan, Patricia A. (Patricia Ann), 1978-

    2004-01-01T23:59:59.000Z

    (cont.) at well-defined operating conditions and to develop. both microscopic and macroscopic models, ranging from regressed global models to an elementary reaction mechanism, to quantify MPA oxidation kinetics in supercritical ...

  12. Spatial variability of nitrous oxide flux measurements at the plot, field and farm scale 

    E-Print Network [OSTI]

    Cowan, Nicholas Jon

    2015-06-30T23:59:59.000Z

    Nitrous oxide (N2O) is a potent greenhouse gas (GHG) which is released naturally into the atmosphere as a by-product of the microbial processes of nitrification and denitrification. Agricultural activities are believed ...

  13. Lithium intercalation in sputter deposited antimony-doped tin oxide thin films: Evidence from electrochemical and optical measurements

    SciTech Connect (OSTI)

    Montero, J., E-mail: jose.montero@angstrom.uu.se; Granqvist, C. G.; Niklasson, G. A. [Department of Engineering Sciences, The A°ngström Laboratory, Uppsala University, P.O. Box 534, SE-751 21 Uppsala (Sweden); Guillén, C.; Herrero, J. [Department of Energy, Ciemat, Avda. Complutense 40, Ed. 42, E-28040 Madrid (Spain)

    2014-04-21T23:59:59.000Z

    Transparent conducting oxides are used as transparent electrical contacts in a variety of applications, including in electrochromic smart windows. In the present work, we performed a study of transparent conducting antimony-doped tin oxide (ATO) thin films by chronopotentiometry in a Li{sup +}-containing electrolyte. The open circuit potential vs. Li was used to investigate ATO band lineups, such as those of the Fermi level and the ionization potential, as well as the dependence of these lineups on the preparation conditions for ATO. Evidence was found for Li{sup +} intercalation when a current pulse was set in a way so as to drive ions from the electrolyte into the ATO lattice. Galvanostatic intermittent titration was then applied to determine the lithium diffusion coefficient within the ATO lattice. The electrochemical density of states of the conducting oxide was studied by means of the transient voltage recorded during the chronopotentiometry experiments. These measurements were possible because, as Li{sup +} intercalation took place, charge compensating electrons filled the lowest part of the conduction band in ATO. Furthermore, the charge insertion modified the optical properties of ATO according to the Drude model.

  14. High Temperture Ceramic Fuel Cell Measurement and Diagnostics for Application to Solid Oxide Fuel Cell Systems

    SciTech Connect (OSTI)

    Koehler, Theresa M.; Jarrell, Donald B.; Bond, Leonard J.

    2001-10-29T23:59:59.000Z

    This paper is the result of an extensive literature review and technology evaluation, performed to determine the status of sensors and measurement technologies.

  15. Direct Determination of Equilibrium Potentials for Hydrogen Oxidation/Production by Open Circuit Potential Measurements in Acetonitrile

    SciTech Connect (OSTI)

    Roberts, John A.; Bullock, R. Morris

    2013-03-14T23:59:59.000Z

    Open circuit potentials were measured for acetonitrile solutions of a variety of acids and their conjugate bases under 1 atm H2. Acids examined include triethylammonium, dimethylformamidium, 2,6-dichloroanilinium, 4-cyanoanilinium, 4-bromoanilinium, and 4-anisidinium salts. These potentials, together with the pKa values of the acids, establish the value of the standard hydrogen electrode (SHE) potential in acetonitrile as ?0.028(4) V vs the ferrocenium/ferrocene couple. Dimethylformamidium is shown to form homoconjugates and other aggregates with dimethylformamide; open circuit potentials are used to quantify the extent of these reactions. Overpotentials for electrocatalytic hydrogen production and oxidation were determined from open circuit potentials and voltammograms of acidic or basic catalyst solutions under H2. This method requires neither pKa values, homoconjugation constants, nor an estimate for the SHE potential and thus allows direct comparison of catalytic systems in different media.

  16. A method for measuring methane oxidation rates using low levels of 14C-labeled methane and accelerator mass spectrometry

    E-Print Network [OSTI]

    2011-01-01T23:59:59.000Z

    oxidation of methane above gas hydrates at Hydrate Ridge, NEsediment from a marine gas hydrate area. Environ. Microbiol.

  17. Development of All-Solid-State Sensors for Measurement of Nitric Oxide and Ammonia Concentrations by Optical Absorption in Particle-Laden Combusion Exhaust Streams

    SciTech Connect (OSTI)

    Jerald A. Caton; Kalyan Annamalai

    2003-09-24T23:59:59.000Z

    An all-solid-state continuous-wave (cw) laser system for ultraviolet absorption measurements of the nitric oxide (NO) molecule has been developed and demonstrated. For the NO sensor, 250 nW of tunable cw ultraviolet radiation is produced by sum-frequency-mixing of 532-nm radiation from a diode-pumped Nd:YAG laser and tunable 395-nm radiation from an external cavity diode laser (ECDL). The sum-frequency-mixing process occurs in a beta-barium borate crystal. The nitric oxide absorption measurements are performed by tuning the ECDL and scanning the sum-frequency-mixed radiation over strong nitric oxide absorption lines near 226 nm. The nitric oxide sensor has been used for measurements in the exhaust of a coal-fired laboratory combustion facility. The Texas A&M University boiler burner facility is a 30 kW (100,000 Btu/hr) downward-fired furnace with a steel shell encasing ceramic insulation. Measurements of nitric oxide concentration in the exhaust stream were performed after modification of the facility for laser based NOx diagnostics. The diode-laser-based sensor measurements showed good agreement with the results from physical probe sampling of the combustion exhaust. The diode-laser-based ultraviolet absorption measurements were successful even when the beam was severely attenuated by particulate in the exhaust stream and window fouling. Single-laser-sweep measurements were demonstrated with an effective time resolution of 100 msec, limited at this time by the scan rate of our mechanically tuned ECDL system. Future planned modifications will lead to even faster response times at sensitivity levels at or below 1 ppm.

  18. Spectroscopic measurement of bromine oxide and ozone in the high Arctic during Polar Sunrise Experiment 1992

    SciTech Connect (OSTI)

    Hausmann, M.; Platt, U. [Universitaet Heidelberg (Germany)] [Universitaet Heidelberg (Germany)

    1994-12-20T23:59:59.000Z

    The authors report the measurement of BrO radical densities and ozone in the Arctic troposphere by means of differential optical absorption using very long paths. They observed levels of BrO which varied from below the detection limit to 17 ppt. Such concentrations alone cannot account for the catalytic destruction of ozone observed during periods of episodic ozone variation. The authors offer a model which involves BrO catalyzed reactions, advection, and atmospheric mixing which they argue could account for the observed ozone depletions.

  19. New Measurements of the Solubility of Metal Oxides at High Temperature

    SciTech Connect (OSTI)

    G.A. Palmer; P. Benezeth; D.J. Wesolowski; S.A. Wood; C. Xiao

    2000-06-30T23:59:59.000Z

    The results of high temperature solubility studies at ORNL are presented in which mainly direct pH measurements were made of aqueous solutions in contact with the crystalline solid phases: Al(OH){sub 3}, AlOOH, Fe{sub 3}O{sub 4}, Mg(OH){sub 2}, Nd(OH){sub 3}, and ZnO. Examples are highlighted of specific phenomena such as: the kinetics of gibbsite and boehmite dissolution and precipitation; the appearance of metastable equilibria in the dissolution of Fe{sub 3}O{sub 4}; the extremely rapid precipitation of crystalline brucite, Mg(OH){sub 2}; and anomalies in the apparent solubility profiles of AlO(OH) and ZnO. General trends associated with the effects of temperature and ionic strength are mentioned. Some of the potentiometric investigations were augmented by conventional batch [AlO(OH) and ZnO], and flow-through column (ZnO) experiments. In the additional case of ZnCr{sub 2}O{sub 4}, the extremely low solubility of this spinel permitted application of only the latter technique and these results are discussed in terms of the measured chromium levels that resulted from incongruent dissolution.

  20. Electrochemical Performance and Stability of the Cathode for Solid Oxide Fuel Cells. I. Cross Validation of Polarization Measurements by Impedance Spectroscopy and Current-Potential Sweep

    SciTech Connect (OSTI)

    Zhou, Xiao Dong; Pederson, Larry R.; Templeton, Jared W.; Stevenson, Jeffry W.

    2009-12-09T23:59:59.000Z

    The aim of this paper is to address three issues in solid oxide fuel cells: (1) cross-validation of the polarization of a single cell measured using both dc and ac approaches, (2) the precise determination of the total areal specific resistance (ASR), and (3) understanding cathode polarization with LSCF cathodes. The ASR of a solid oxide fuel cell is a dynamic property, meaning that it changes with current density. The ASR measured using ac impedance spectroscopy (low frequency interception with real Z´ axis of ac impedance spectrum) matches with that measured from a dc IV sweep (the tangent of dc i-V curve). Due to the dynamic nature of ASR, we found that an ac impedance spectrum measured under open circuit voltage or on a half cell may not represent cathode performance under real operating conditions, particularly at high current density. In this work, the electrode polarization was governed by the cathode activation polarization; the anode contribution was negligible.

  1. Development of All-Solid-State Sensors for Measurement of Nitric Oxide and Ammonia Concentrations by Optical Absorption in Particle-Laden Combustion Exhaust Streams

    SciTech Connect (OSTI)

    Jerald A. Caton; Kalyan Annamalai; Robert P. Lucht

    2005-09-30T23:59:59.000Z

    An all-solid-state continuous-wave (cw) laser system for ultraviolet absorption measurements of the nitric oxide (NO) molecule has been developed and demonstrated. For the NO sensor, 250 nW of tunable cw ultraviolet radiation is produced by sum-frequency-mixing of 532-nm radiation from a diode-pumped Nd:YAG laser and tunable 395-nm radiation from an external cavity diode laser (ECDL). The sum-frequency-mixing process occurs in a beta-barium borate crystal. The nitric oxide absorption measurements are performed by tuning the ECDL and scanning the sum-frequency-mixed radiation over strong nitric oxide absorption lines near 226 nm. In Year 1 of the research, the nitric oxide sensor was used for measurements in the exhaust of a coal-fired laboratory combustion facility. The Texas A&M University boiler burner facility is a 30 kW (100,000 Btu/hr) downward-fired furnace with a steel shell encasing ceramic insulation. Measurements of nitric oxide concentration in the exhaust stream were performed after modification of the facility for laser based NOx diagnostics. The diode-laser-based ultraviolet absorption measurements were successful even when the beam was severely attenuated by particulate in the exhaust stream and window fouling. Single-laser-sweep measurements were demonstrated with an effective time resolution of 100 msec, limited at this time by the scan rate of our mechanically tuned ECDL system. In Year 2, the Toptica ECDL in the original system was replaced with a Sacher Lasers ECDL. The mode-hop-free tuning range and tuning rate of the Toptica ECDL were 25 GHz and a few Hz, respectively. The mode-hop-free tuning range and tuning rate of the Sacher Lasers ECDL were 90 GHz and a few hundred Hz, respectively. The Sacher Lasers ECDL thus allows us to scan over the entire NO absorption line and to determine the absorption baseline with increased accuracy and precision. The increased tuning rate is an advantage in that data can be acquired much more rapidly and the absorption measurements are less susceptible to the effects of transient fluctuations in the properties of the coal combustor exhaust stream. Gas cell measurements were performed using the NO sensor with the new ECDL, and a few spectra were acquired from the coal exhaust stream. However, the laser diode in the new ECDL failed during the coal combustor tests. In Year 3, however, we obtained a new GaN laser diode for our ECDL system, installed it, and completed an extensive series of measurements in the Texas A&M coal-fired laboratory combustion facility. The combustor was operated with coal and coal/biomass as fuels, with and without reburn, and with and without ammonia injection. Several different fuel equivalence ratios were investigated for each operating condition. A series of spectral simulations was performed using the HITRAN code to investigate the potential sensitivity of absorption measurements of ammonia in different spectral regions. It was concluded that ammonia absorption features in the 3000-nm spectral region would be hard to measure due to water vapor interferences. We will concentrate on the spectral region near 1530 nm, where other researchers have had some success in measuring ammonia.

  2. Measurement of the Nickel/Nickel Oxide Phase Transition in High Temperature Hydrogenated Water Using the Contact Electric Resistance (CER) Technique

    SciTech Connect (OSTI)

    S.A. Attanasio; D.S. Morton; M.A. Ando; N.F. Panayotou; C.D. Thompson

    2001-05-08T23:59:59.000Z

    Prior studies of Alloy 600 and Alloy X-750 have shown the existence of a maximum in stress corrosion cracking (SCC) susceptibility in high temperature water (e.g., at 360 C), when testing is conducted over a range of dissolved (i.e., aqueous) hydrogen (H{sub 2}) concentrations. It has also been shown that this maximum in SCC susceptibility tends to occur in proximity to the nickel/nickel oxide (Ni/NiO) phase transition, suggesting that oxide phase stability may affect primary water SCC (PWSCC) resistance. Previous studies have estimated the Ni/NiO transition using thermodynamic calculations based on free energies of formation for NiO and H{sub 2}O. The present study reports experimental measurements of the Ni/NiO transition performed using a contact electric resistance (CER) instrument. The CER is capable of measuring the surface resistance of a metal to determine whether it is oxide-covered or oxide-free at a given condition. The transition aqueous hydrogen (H{sub 2}) concentration corresponding to the Ni/NiO equilibrium was measured at 288, 316, 338 and 360 C using high purity Ni specimens. The results showed an appreciable deviation (i.e., 7 to 58 scc H{sub 2}/kg H{sub 2}O) between the measured Ni/NiO transition and the theoretical Ni/NiO transition previously calculated using free energy data from the Journal of Solution Chemistry. The CER-measured position of the Ni/NiO transition is in good agreement with the maxima in PWSCC susceptibility at 338 and 360 C. The measured Ni/NiO transition provides a reasonable basis for estimating the aqueous H{sub 2} level at which the maximum in SCC susceptibility is likely to be observed at temperatures lower than 338 to 360 C, at which SCC tests are time-consuming to perform. Limited SCC data are presented which are consistent with the observation that SCC susceptibility is maximized near the Ni/NiO transition at 288 C.

  3. High-Precision Measurements of [superscript 33]S and [superscript 34]S Fractionation during SO[subscript 2] Oxidation Reveal Causes of Seasonality in SO[subscript 2] and Sulfate Isotopic Composition

    E-Print Network [OSTI]

    Harris, Eliza

    This study presents high-precision isotope ratio-mass spectrometric measurements of isotopic fractionation during oxidation of SO[subscript 2] by OH radicals in the gas phase and H[subscript 2]O[subscript 2] and transition ...

  4. DEVELOPMENT OF ALL-SOLID-STATE SENSORS FOR MEASUREMENT OF NITRIC OXIDE AND AMMONIA CONCENTRATIONS BY OPTICAL ABSORPTION IN PARTICLE-LADEN COMBUSTION EXHAUST STREAMS

    SciTech Connect (OSTI)

    Jerald A. Caton; Kalyan Annamalai; Robert P. Lucht

    2004-09-30T23:59:59.000Z

    An all-solid-state continuous-wave (cw) laser system for ultraviolet absorption measurements of the nitric oxide (NO) molecule has been developed and demonstrated. For the NO sensor, 250 nW of tunable cw ultraviolet radiation is produced by sum-frequency-mixing of 532-nm radiation from a diode-pumped Nd:YAG laser and tunable 395-nm radiation from an external cavity diode laser (ECDL). The sum-frequency-mixing process occurs in a beta-barium borate crystal. The nitric oxide absorption measurements are performed by tuning the ECDL and scanning the sum-frequency-mixed radiation over strong nitric oxide absorption lines near 226 nm. In Year 1 of the research, the nitric oxide sensor was used for measurements in the exhaust of a coal-fired laboratory combustion facility. The Texas A&M University boiler burner facility is a 30 kW (100,000 Btu/hr) downward-fired furnace with a steel shell encasing ceramic insulation. Measurements of nitric oxide concentration in the exhaust stream were performed after modification of the facility for laser based NOx diagnostics. The diode-laser-based ultraviolet absorption measurements were successful even when the beam was severely attenuated by particulate in the exhaust stream and window fouling. Single-laser-sweep measurements were demonstrated with an effective time resolution of 100 msec, limited at this time by the scan rate of our mechanically tuned ECDL system. In Year 2 described in this progress report, the Toptica ECDL in the original system was replaced with a Sacher Lasers ECDL. The mode-hop-free tuning range and tuning rate of the Toptica ECDL were 25 GHz and a few Hz, respectively. The mode-hop-free tuning range and tuning rate of the Sacher Lasers ECDL were 90 GHz and a few hundred Hz, respectively. The Sacher Lasers ECDL thus allows us to scan over the entire NO absorption line and to determine the absorption baseline with increased accuracy and precision. The increased tuning rate is an advantage in that data can be acquired much more rapidly and the absorption measurements are less susceptible to the effects of transient fluctuations in the properties of the coal combustor exhaust stream. Gas cell measurements were performed using the NO sensor with the new ECDL, and a few spectra were acquired from the coal exhaust stream. However, the laser diode in the new ECDL failed during the coal combustor tests. A series of spectral simulations was performed using the HITRAN code to investigate the potential sensitivity of absorption measurements of ammonia in different spectral regions. It was concluded that ammonia absorption features in the 3000-nm spectral region would be hard to measure due to water vapor interferences.

  5. Development of All-Solid-State Sensors for Measurement of Nitric Oxide and Ammonia Concentrations by Optical Absorption in Particle-Laden Combustion Exhaust Streams

    SciTech Connect (OSTI)

    Jerald A. Caton; Kalyan Annamalai; Robert P. Lucht

    2006-12-31T23:59:59.000Z

    An all-solid-state continuous-wave (cw) laser system for ultraviolet absorption measurements of the nitric oxide (NO) molecule has been developed and demonstrated. For the NO sensor, 250 nW of tunable cw ultraviolet radiation is produced by sum-frequency-mixing of 532-nm radiation from a diode-pumped Nd:YAG laser and tunable 395-nm radiation from an external cavity diode laser (ECDL). The sum-frequency-mixing process occurs in a beta-barium borate crystal. The nitric oxide absorption measurements are performed by tuning the ECDL and scanning the sum-frequency-mixed radiation over strong nitric oxide absorption lines near 226 nm. In Year 1 of the research, the nitric oxide sensor was used for measurements in the exhaust of a coal-fired laboratory combustion facility. The Texas A&M University boiler burner facility is a 30 kW (100,000 Btu/hr) downward-fired furnace with a steel shell encasing ceramic insulation. Measurements of nitric oxide concentration in the exhaust stream were performed after modification of the facility for laser based NOx diagnostics. The diode-laser-based ultraviolet absorption measurements were successful even when the beam was severely attenuated by particulate in the exhaust stream and window fouling. Single-laser-sweep measurements were demonstrated with an effective time resolution of 100 msec, limited at this time by the scan rate of our mechanically tuned ECDL system. In Year 2, the Toptica ECDL in the original system was replaced with a Sacher Lasers ECDL. The mode-hop-free tuning range and tuning rate of the Toptica ECDL were 25 GHz and a few Hz, respectively. The mode-hop-free tuning range and tuning rate of the Sacher Lasers ECDL were 90 GHz and a few hundred Hz, respectively. The Sacher Lasers ECDL thus allows us to scan over the entire NO absorption line and to determine the absorption baseline with increased accuracy and precision. The increased tuning rate is an advantage in that data can be acquired much more rapidly and the absorption measurements are less susceptible to the effects of transient fluctuations in the properties of the coal combustor exhaust stream. Gas cell measurements were performed using the NO sensor with the new ECDL, and a few spectra were acquired from the coal exhaust stream. However, the laser diode in the new ECDL failed during the coal combustor tests. In Year 3, however, we obtained a new GaN laser diode for our ECDL system, installed it, and completed an extensive series of measurements in the Texas A&M coal-fired laboratory combustion facility. The combustor was operated with coal and coal/biomass as fuels, with and without reburn, and with and without ammonia injection. Several different fuel equivalence ratios were investigated for each operating condition.

  6. In situ measurements of nitric oxide in coal-combustion exhaust using a sensor based on a widely tunable external-cavity GaN diode laser

    SciTech Connect (OSTI)

    Anderson, T.N.; Lucht, R.P.; Priyadarsan, S.; Annamalai, K.; Caton, J.A. [Purdue University, West Lafayette, IN (United States). School of Mechanical Engineers

    2007-07-15T23:59:59.000Z

    A diode-laser-based sensor has been developed to measure nitric oxide mole fractions using absorption spectroscopy. The sensor is based on sum-frequency mixing of a 395 nm external-cavity diode laser (ECDL) and a 532 run laser in a beta-barium-borate crystal. Using a new tuning scheme, the GaN ECDL wavelength was modulated over 90 GHz without mode hops. The sensor was applied for measurements of the NO mole fraction in the exhaust of a laboratory-scale, 30 kW, coal-fired boiler burner. Absorption measurements were successfully performed despite severe attenuation by scattering from ash particles in the exhaust stream and on the exhaust-section windows. A detection limit (1 sigma) of 4.5 ppm m/root Hz at 700 K was demonstrated in coal-combustion exhaust at a maximum detection rate of 5 Hz.

  7. Magnetization measurements and XMCD studies on ion irradiated...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    measurements and XMCD studies on ion irradiated iron oxide and core-shell ironiron-oxide nanomaterials. Magnetization measurements and XMCD studies on ion irradiated iron oxide...

  8. Time-Resolved Quantitative Measurement of OH HO2 and CH2O in Fuel Oxidation Reactions by High Resolution IR Absorption Spectroscopy.

    SciTech Connect (OSTI)

    Huang, Haifeng; Rotavera, Brandon; Taatjes, Craig A.

    2014-08-01T23:59:59.000Z

    Combined with a Herriott-type multi-pass slow flow reactor, high-resolution differential direct absorption spectroscopy has been used to probe, in situ and quantitatively, hydroxyl (OH), hydroperoxy (HO 2 ) and formaldehyde (CH 2 O) molecules in fuel oxidation reactions in the reactor, with a time resolution of about 1 micro-second. While OH and CH 2 O are probed in the mid-infrared (MIR) region near 2870nm and 3574nm respectively, HO 2 can be probed in both regions: near-infrared (NIR) at 1509nm and MIR at 2870nm. Typical sensitivities are on the order of 10 10 - 10 11 molecule cm -3 for OH at 2870nm, 10 11 molecule cm -3 for HO 2 at 1509nm, and 10 11 molecule cm -3 for CH 2 O at 3574nm. Measurements of multiple important intermediates (OH and HO 2 ) and product (CH 2 O) facilitate to understand and further validate chemical mechanisms of fuel oxidation chemistry.

  9. An improved characterization method for international accountancy measurements of fresh and irradiated mixed oxide (MOX) fuel: helping achieve continual monitoring and safeguards through the fuel cycle

    SciTech Connect (OSTI)

    Evans, Louise G [Los Alamos National Laboratory; Croft, Stephen [Los Alamos National Laboratory; Swinhoe, Martyn T [Los Alamos National Laboratory; Tobin, S. J. [Los Alamos National Laboratory; Menlove, H. O. [Los Alamos National Laboratory; Schear, M. A. [Los Alamos National Laboratory; Worrall, Andrew [U.K. NNL

    2011-01-13T23:59:59.000Z

    Nuclear fuel accountancy measurements are conducted at several points through the nuclear fuel cycle to ensure continuity of knowledge (CofK) of special nuclear material (SNM). Non-destructive assay (NDA) measurements are performed on fresh fuel (prior to irradiation in a reactor) and spent nuclear fuel (SNF) post-irradiation. We have developed a fuel assembly characterization system, based on the novel concept of 'neutron fingerprinting' with multiplicity signatures to ensure detailed CofK of nuclear fuel through the entire fuel cycle. The neutron fingerprint in this case is determined by the measurement of the various correlated neutron signatures, specific to fuel isotopic composition, and therefore offers greater sensitivity to variations in fissile content among fuel assemblies than other techniques such as gross neutron counting. This neutron fingerprint could be measured at the point of fuel dispatch (e.g. from a fuel fabrication plant prior to irradiation, or from a reactor site post-irradiation), monitored during transportation of the fuel assembly, and measured at a subsequent receiving site (e.g. at the reactor site prior to irradiation, or reprocessing facility post-irradiation); this would confirm that no unexpected changes to the fuel composition or amount have taken place during transportation and/ or reactor operations. Changes may indicate an attempt to divert material for example. Here, we present the current state of the practice of fuel measurements for both fresh mixed oxide (MOX) fuel and SNF (both MOX and uranium dioxide). This is presented in the framework of international safeguards perspectives from the US and UK. We also postulate as to how the neutron fingerprinting concept could lead to improved fuel characterization (both fresh MOX and SNF) resulting in: (a) assured CofK of fuel across the nuclear fuel cycle, (b) improved detection of SNM diversion, and (c) greater confidence in safeguards of SNF transportation.

  10. An improved characterization method for international accountancy measurements of fresh and irradiated mixed oxide (MOX) fuel: helping achieve continual monitoring and safeguards through the fuel cycle

    SciTech Connect (OSTI)

    Evans, Louise G [Los Alamos National Laboratory; Croft, Stephen [Los Alamos National Laboratory; Swinhoe, Martyn T [Los Alamos National Laboratory; Tobin, S. J. [Los Alamos National Laboratory; Boyer, B. D. [Los Alamos National Laboratory; Menlove, H. O. [Los Alamos National Laboratory; Schear, M. A. [Los Alamos National Laboratory; Worrall, Andrew [U.K., NNL

    2010-11-24T23:59:59.000Z

    Nuclear fuel accountancy measurements are conducted at several points through the nuclear fuel cycle to ensure continuity of knowledge (CofK) of special nuclear material (SNM). Non-destructive assay (NDA) measurements are performed on fresh fuel (prior to irradiation in a reactor) and spent nuclear fuel (SNF) post-irradiation. We have developed a fuel assembly characterization system, based on the novel concept of 'neutron fingerprinting' with multiplicity signatures to ensure detailed CofK of nuclear fuel through the entire fuel cycle. The neutron fingerprint in this case is determined by the measurement of the various correlated neutron signatures, specific to fuel isotopic composition, and therefore offers greater sensitivity to variations in fissile content among fuel assemblies than other techniques such as gross neutron counting. This neutron fingerprint could be measured at the point of fuel dispatch (e.g. from a fuel fabrication plant prior to irradiation, or from a reactor site post-irradiation), monitored during transportation of the fuel assembly, and measured at a subsequent receiving site (e.g. at the reactor site prior to irradiation, or reprocessing facility post-irradiation); this would confirm that no unexpected changes to the fuel composition or amount have taken place during transportation and/or reactor operations. Changes may indicate an attempt to divert material for example. Here, we present the current state of the practice of fuel measurements for both fresh mixed oxide (MOX) fuel and SNF (both MOX and uranium dioxide). This is presented in the framework of international safeguards perspectives from the US and UK. We also postulate as to how the neutron fingerprinting concept could lead to improved fuel characterization (both fresh MOX and SNF) resulting in: (a) assured CofK of fuel across the nuclear fuel cycle, (b) improved detection of SNM diversion, and (c) greater confidence in safeguards of SNF transportation.

  11. Journal of the European Ceramic Society 25 (2005) 13131324 High temperature elasticity measurements on oxides by Brillouin

    E-Print Network [OSTI]

    Jackson, Jennifer M.

    2005-01-01T23:59:59.000Z

    for determining the elastic moduli at high temperatures, using both electric resistive heating (to 1800 K) and CO2 by Elsevier Ltd. Keywords: Spectroscopy; Mechanical properties; High-temperature elasticity measurements by Brillouin scattering 1. Introduction Knowledge of the high-temperature elastic properties is fundamental

  12. Overall Rate Constant Measurements of the Reaction of Hydroxy-and Chloroalkylperoxy Radicals Derived from Methacrolein and Methyl Vinyl Ketone with Nitric Oxide

    E-Print Network [OSTI]

    Elrod, Matthew J.

    and to lead to additional ozone production in regions where isoprene oxidation chemistry is dominant Derived from Methacrolein and Methyl Vinyl Ketone with Nitric Oxide Hong Yuan Hsin and Matthew J. Elrod- and chloroalkylperoxy radicals, derived from the OH- and Cl-initiated oxidation of methacrolein and methyl vinyl ketone

  13. Development of Metal Oxide Nanostructure-based Optical Sensors for Fossil Fuel Derived Gases Measurement at High Temperature

    SciTech Connect (OSTI)

    Chen, Kevin

    2014-08-31T23:59:59.000Z

    This final technical report details research works performed supported by a Department of Energy grant (DE-FE0003859), which was awarded under the University Coal Research Program administrated by National Energy Technology Laboratory. This research program studied high temperature fiber sensor for harsh environment applications. It developed two fiber optical sensor platform technology including regenerative fiber Bragg grating sensors and distributed fiber optical sensing based on Rayleigh backscattering optical frequency domain reflectometry. Through the studies of chemical and thermal regenerative techniques for fiber Bragg grating (FBG) fabrication, high-temperature stable FBG sensors were successfully developed and fabricated in air-hole microstructured fibers, high-attenuation fibers, rare-earth doped fibers, and standard telecommunication fibers. By optimizing the laser processing and thermal annealing procedures, fiber grating sensors with stable performance up to 1100oC have been developed. Using these temperature-stable FBG gratings as sensor platform, fiber optical flow, temperature, pressure, and chemical sensors have been developed to operate at high temperatures up to 800oC. Through the integration of on-fiber functional coating, the use of application-specific air-hole microstructural fiber, and application of active fiber sensing scheme, distributed fiber sensor for temperature, pressure, flow, liquid level, and chemical sensing have been demonstrated with high spatial resolution (1-cm or better) with wide temperature ranges. These include the demonstration of 1) liquid level sensing from 77K to the room temperature, pressure/temperature sensing from the room temperature to 800C and from the 15psi to 2000 psi, and hydrogen concentration measurement from 0.2% to 10% with temperature ranges from the room temperature to 700C. Optical sensors developed by this program has broken several technical records including flow sensors with the highest operation temperature up to 750oC, first distributed chemical measurements at the record high temperature up to 700oC, first distributed pressure measurement at the record high temperature up to 800oC, and the fiber laser sensors with the record high operation temperature up to 700oC. The research performed by this program dramatically expand the functionality, adaptability, and applicability of distributed fiber optical sensors with potential applications in a number of high-temperature energy systems such as fossil-fuel power generation, high-temperature fuel cell applications, and potential for nuclear energy systems.

  14. Method for Determining Performance of Sulfur Oxide Adsorbents...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Method for Determining Performance of Sulfur Oxide Adsorbents for Diesel Emission Control Using Online Measurement of SO2 and Method for Determining Performance of Sulfur Oxide...

  15. Measurement Measurement

    E-Print Network [OSTI]

    Type Measurement Type Measurement Type Measurement Type Measurement Catch Composition - Pelagic codes M Male F Female I Indeterminate U Unknown (not inspected) #12;Type Measurement Type Measurement Type Measurement Type Measurement Photos Comment Length 1 Version 1.2 6/2011 HookNo. Species name

  16. Hard X-ray Fluorescence Measurements of Heteroepitaxial Solid...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hard X-ray Fluorescence Measurements of Heteroepitaxial Solid Oxide Fuel Cell Cathode Materials. Hard X-ray Fluorescence Measurements of Heteroepitaxial Solid Oxide Fuel Cell...

  17. Enhanced mercury oxidation

    SciTech Connect (OSTI)

    Gretta, W.J.; Wu, S.; Kikkawa, H. [Hitachi Power Systems America, Basting Ridge, NJ (United States)

    2009-06-15T23:59:59.000Z

    A new catalyst offers a new way to enhance mercury control from bituminous coal-fired power plants. Hitachi has developed an SCR catalyst which satisfies high Hg{sup 0} oxidation and low SO{sub 2} oxidation requirements under high temperatures (716 to 770 F). This triple action catalysts, TRAC can significantly enhance mercury oxidation and reduce or eliminate the need for additional mercury control measures such as activated carbon injection. After laboratory testing, pilot-scale tests confirmed an activity of 1.4-1.7 times higher than that of conventional SCR catalyst. The new catalyst has been successfully applied in a commercial PRB-fired boiler without the need for halogens to be added to the fuel feed or flue gas. 2 figs.

  18. Oxidation catalyst

    DOE Patents [OSTI]

    Ceyer, Sylvia T. (Cambridge, MA); Lahr, David L. (Cambridge, MA)

    2010-11-09T23:59:59.000Z

    The present invention generally relates to catalyst systems and methods for oxidation of carbon monoxide. The invention involves catalyst compositions which may be advantageously altered by, for example, modification of the catalyst surface to enhance catalyst performance. Catalyst systems of the present invention may be capable of performing the oxidation of carbon monoxide at relatively lower temperatures (e.g., 200 K and below) and at relatively higher reaction rates than known catalysts. Additionally, catalyst systems disclosed herein may be substantially lower in cost than current commercial catalysts. Such catalyst systems may be useful in, for example, catalytic converters, fuel cells, sensors, and the like.

  19. Isotope loss from exhaled moisture and correlation of multifrequency bioelectrical impedance to body fluid compartments measured by intravenous deuterium oxide and sodium bromide dilution in dogs

    E-Print Network [OSTI]

    Witten, Tiffani Tipton

    2000-01-01T23:59:59.000Z

    for this route of isotope loss was necessary. Sodium bromide concentrations at 90 minutes and 180 minutes were tested for statistical equivalency to determine if NaBr had equilibrated by 90 minutes. Finally, impedance measured with electrodes separated by 2...

  20. BAR-CODE BASED WEIGHT MEASUREMENT STATION FOR PHYSICAL INVENTORY TAKING OF PLUTONIUM OXIDE CONTAINERS AT THE MINING AND CHEMICAL COMBINE RADIOCHEMICAL REPROCESSING PLANT NEAR KRASNOYARSK, SIBERIA.

    SciTech Connect (OSTI)

    SUDA,S.

    1999-09-20T23:59:59.000Z

    This paper describes the technical tasks being implemented to computerize the physical inventory taking (PIT) at the Mining and Chemical Combine (Gorno-Khimichesky Kombinat, GKhK) radiochemical plant under the US/Russian cooperative nuclear material protection, control, and accounting (MPC and A) program. Under the MPC and A program, Lab-to-Lab task agreements with GKhK were negotiated that involved computerized equipment for item verification and confirmatory measurement of the Pu containers. Tasks under Phase I cover the work for demonstrating the plan and procedures for carrying out the comparison of the Pu container identification on the container with the computerized inventory records. In addition to the records validation, the verification procedures include the application of bar codes and bar coded TIDs to the Pu containers. Phase II involves the verification of the Pu content. A plan and procedures are being written for carrying out confirmatory measurements on the Pu containers.

  1. Asphalt Oxidation Kinetics and Pavement Oxidation Modeling

    E-Print Network [OSTI]

    Jin, Xin

    2012-07-16T23:59:59.000Z

    Most paved roads in the United States are surfaced with asphalt. These asphalt pavements suffer from fatigue cracking and thermal cracking, aggravated by the oxidation and hardening of asphalt. This negative impact of asphalt oxidation on pavement...

  2. Impact of GaN cap on charges in Al?O?/(GaN/)AlGaN/GaN metal-oxide-semiconductor heterostructures analyzed by means of capacitance measurements and simulations

    SciTech Connect (OSTI)

    ?apajna, M., E-mail: milan.tapajna@savba.sk; Jurkovi?, M.; Válik, L.; Haš?ík, Š.; Gregušová, D.; Kuzmík, J. [Institute of Electrical Engineering, Slovak Academy of Sciences, Dúbravská cesta 9, 841 04 Bratislava (Slovakia); Brunner, F.; Cho, E.-M. [Ferdinand-Braun-Institut, Leibniz Institut für Höchstfrequenztechnik, Gustav-Kirchhoff-Strasse 4, 12489 Berlin (Germany); Hashizume, T. [Research Center for Integrated Quantum Electronics (RCIQE), Hokkaido University, 060-0814 Sapporo, Japan and JST-CREST, 102-0075 Tokyo (Japan)

    2014-09-14T23:59:59.000Z

    Oxide/semiconductor interface trap density (D{sub it}) and net charge of Al?O?/(GaN)/AlGaN/GaN metal-oxide-semiconductor high-electron mobility transistor (MOS-HEMT) structures with and without GaN cap were comparatively analyzed using comprehensive capacitance measurements and simulations. D{sub it} distribution was determined in full band gap of the barrier using combination of three complementary capacitance techniques. A remarkably higher D{sub it} (?5–8?×?10¹²eV?¹?cm?²) was found at trap energies ranging from EC-0.5 to 1?eV for structure with GaN cap compared to that (D{sub it}???2–3?×?10¹²eV?¹?cm?²) where the GaN cap was selectively etched away. D{sub it} distributions were then used for simulation of capacitance-voltage characteristics. A good agreement between experimental and simulated capacitance-voltage characteristics affected by interface traps suggests (i) that very high D{sub it} (>10¹³eV?¹?cm?²) close to the barrier conduction band edge hampers accumulation of free electron in the barrier layer and (ii) the higher D{sub it} centered about EC-0.6?eV can solely account for the increased C-V hysteresis observed for MOS-HEMT structure with GaN cap. Analysis of the threshold voltage dependence on Al?O? thickness for both MOS-HEMT structures suggests that (i) positive charge, which compensates the surface polarization, is not necessarily formed during the growth of III-N heterostructure, and (ii) its density is similar to the total surface polarization charge of the GaN/AlGaN barrier, rather than surface polarization of the top GaN layer only. Some constraints for the positive surface compensating charge are discussed.

  3. Search for quantum transducers between electromagnetic and gravitational radiation: A measurement of an upper limit on the transducer conversion efficiency of yttrium barium copper oxide

    E-Print Network [OSTI]

    R. Y. Chiao; W. J. Fitelson; A. D. Speliotopoulos

    2003-04-07T23:59:59.000Z

    A minimal coupling rule for the coupling of the electron spin to curved spacetime in general relativity suggests the possibility of a coupling between electromagnetic and gravitational radiation mediated by means of a quantum fluid. Thus quantum transducers between these two kinds of radiation fields might exist. We report here on the first attempt at a Hertz-type experiment, in which a high-$\\rm{T_c}$ superconductor (YBCO) was the sample material used as a possible quantum transducer to convert EM into GR microwaves, and a second piece of YBCO in a separate apparatus was used to back-convert GR into EM microwaves. An upper limit on the conversion efficiency of YBCO was measured to be $1.6\\times10^{-5}$ at liquid nitrogen temperature.

  4. Water oxidation reaction in natural and artificial photosynthetic systems

    SciTech Connect (OSTI)

    Yano, Junko; Yachandra, Vittal [Physical Biosciences Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Rd., Berkeley, CA 94720 (United States)

    2013-12-10T23:59:59.000Z

    Understanding the structure and mechanism of water oxidation catalysts is an essential component for developing artificial photosynthetic devices. In the natural water oxidation catalyst, the geometric and electronic structure of its inorganic core, the Mn{sub 4}CaO{sub 5} cluster, has been studied by spectroscopic and diffraction measurements. In inorganic systems, metal oxides seem to be good candidates for water oxidation catalysts. Understanding the reaction mechanism in both natural and oxide-based catalysts will helpin further developing efficient and robust water oxidation catalysts.

  5. Photo-oxidation catalysts

    DOE Patents [OSTI]

    Pitts, J. Roland (Lakewood, CO); Liu, Ping (Irvine, CA); Smith, R. Davis (Golden, CO)

    2009-07-14T23:59:59.000Z

    Photo-oxidation catalysts and methods for cleaning a metal-based catalyst are disclosed. An exemplary catalyst system implementing a photo-oxidation catalyst may comprise a metal-based catalyst, and a photo-oxidation catalyst for cleaning the metal-based catalyst in the presence of light. The exposure to light enables the photo-oxidation catalyst to substantially oxidize absorbed contaminants and reduce accumulation of the contaminants on the metal-based catalyst. Applications are also disclosed.

  6. Applied Surface Science 323 (2014) 7177 Contents lists available at ScienceDirect

    E-Print Network [OSTI]

    Lin, Xi

    2014-01-01T23:59:59.000Z

    .8O3-i (LSCF-6428) were investigated. (0 0 1)-oriented LSCF-6428 thin films were deposited on lattice-i (LSCF-6428), is a commonly used perovskite-type material for cathodes in solid oxide fuel cells (SOFCs). The advantages of LSCF-6428 lie in its mixed ionic and electronic conductor (MIEC) behavior

  7. Oxidation of propylene over copper oxide catalysts

    E-Print Network [OSTI]

    Billingsley, David Stuart

    1958-01-01T23:59:59.000Z

    results were obtained using an asbestos supported CuO-Cr203 catalyst. Venkataramam and his co-workers (66) studied the catalytic oxidation of ethylene to ethylene oxide by the fluidized bed technique using a static bed of catalyst. Precipitated Ag20... in the air-ethylene ratio to maintain good yields of ethylene oxide. Wan (68) reported the oxidation of ethylene to acetaldehyde by use of a silver catalyst in a 5/16 dnch inner diameter stainless steel tube with a catalyst bed up to 30. 3 centimeters...

  8. Cerium Oxide Coating for Oxidation Reduction

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Award In order to produce power more efficiently and cleanly, the next generation of power plant boilers, turbines, solid oxide fuel cells (SOFCs) and other essential...

  9. Graphite oxidation modeling for application in MELCOR.

    SciTech Connect (OSTI)

    Gelbard, Fred

    2009-01-01T23:59:59.000Z

    The Arrhenius parameters for graphite oxidation in air are reviewed and compared. One-dimensional models of graphite oxidation coupled with mass transfer of oxidant are presented in dimensionless form for rectangular and spherical geometries. A single dimensionless group is shown to encapsulate the coupled phenomena, and is used to determine the effective reaction rate when mass transfer can impede the oxidation process. For integer reaction order kinetics, analytical expressions are presented for the effective reaction rate. For noninteger reaction orders, a numerical solution is developed and compared to data for oxidation of a graphite sphere in air. Very good agreement is obtained with the data without any adjustable parameters. An analytical model for surface burn-off is also presented, and results from the model are within an order of magnitude of the measurements of burn-off in air and in steam.

  10. Mixed Ionic and Electonic Conductors for Hydrogen Generation and Separation: A New Approach

    SciTech Connect (OSTI)

    Srikanth Gopalan

    2006-12-31T23:59:59.000Z

    Composite mixed conductors comprising one electronic conducting phase, and one ionic conducting phase (MIECs) have been developed in this work. Such MIECs have applications in generating and separating hydrogen from hydrocarbon fuels at high process rates and high purities. The ionic conducting phase comprises of rare-earth doped ceria and the electronic conducting phase of rare-earth doped strontium titanate. These compositions are ideally suited for the hydrogen separation application. In the process studied in this project, steam at high temperatures is fed to one side of the MIEC membrane and hydrocarbon fuel or reformed hydrocarbon fuel to the other side of the membrane. Oxygen is transported from the steam side to the fuel side down the electrochemical potential gradient thereby enriching the steam side flow in hydrogen. The remnant water vapor can then be condensed to obtain high purity hydrogen. In this work we have shown that two-phase MIECs comprising rare-earth ceria as the ionic conductor and doped-strontium titanate as the electronic conductor are stable in the operating environment of the MIEC. Further, no adverse reaction products are formed when these phases are in contact at elevated temperatures. The composite MIECs have been characterized using a transient electrical conductivity relaxation technique to measure the oxygen chemical diffusivity and the surface exchange coefficient. Oxygen permeation and hydrogen generation rates have been measured under a range of process conditions and the results have been fit to a model which incorporates the oxygen chemical diffusivity and the surface exchange coefficient from the transient measurements.

  11. THE MICROSTRUCTURAL LOCATION OF THE INTERGRANULAR METAL OXIDE PHASE IN A ZINC OXIDE VARISTOR

    E-Print Network [OSTI]

    Clarke, D. E

    2011-01-01T23:59:59.000Z

    OXIDE PHASE IN A ZINC OXIDE VARISTOR MICROSI'RUCTIJRALMETAL OXIDE PHASE IN A ZINC OXIDE VARISTOR David R. Clarke

  12. Comparison of the Catalytic Oxidation Reaction on Graphene Oxide and Reduced Graphene Oxide

    E-Print Network [OSTI]

    Kim, Sehun

    Comparison of the Catalytic Oxidation Reaction on Graphene Oxide and Reduced Graphene Oxide Laboratory (PAL), Pohang 790-784, Republic of Korea ABSTRACT: The capacities of graphene oxide (GO) and reduced graphene oxide (rGO) films grown on silicon substrate to cause the aniline to azobenzene oxidation

  13. Measurement of the Nickel/Nickel Oxide Transition in Ni-Cr-Fe Alloys and Updated Data and Correlations to Quantify the Effect of Aqueous Hydrogen on Primary Water SCC

    SciTech Connect (OSTI)

    Steven A. Attanasio; David S. Morton

    2003-06-16T23:59:59.000Z

    Alloys 600 and X-750 have been shown to exhibit a maximum in primary water stress corrosion cracking (PWSCC) susceptibility, when testing is conducted over a range of aqueous hydrogen (H{sub 2}) levels. Contact electric resistance (CER) and corrosion coupon testing using nickel specimens has shown that the maximum in SCC susceptibility occurs in proximity to the nickel-nickel oxide (Ni/NiO) phase transition. The measured location of the Ni/NiO transition has been shown to vary with temperature, from 25 scc/kg H{sub 2} at 360 C to 4 scc/kg H{sub 2} at 288 C. New CER measurements show that the Ni/NiO transition is located at 2 scc/kg H{sub 2} at 260 C. An updated correlation of the phase transition is provided. The present work also reports CER testing conducted using an Alloy 600 specimen at 316 C. A large change in resistance occurred between 5 and 10 scc/kg H{sub 2}, similar to the results obtained at 316 C using a nickel specimen. This result adds confidence in applying the Ni/NiO transition measurements to Ni-Cr-Fe alloys. The understanding of the importance of the Ni/NiO transition to PWSCC has been used previously to quantify H{sub 2} effects on SCC growth rate (SCCGR). Specifically, the difference in the electrochemical potential (EcP) of the specimen or component from the Ni/NiO transition (i.e., EcP{sub Ni/NiO}-EcP) has been used as a correlating parameter. In the present work, these SCCGR-H{sub 2} correlations, which were based on SCCGR data obtained at relatively high test temperatures (338 and 360 C), are evaluated via SCCGR tests at a reduced temperature (316 C). The 316 C data are in good agreement with the predictions, implying that the SCCGR-H{sub 2} correlations extrapolate well to reduced temperatures. The SCCGR-H{sub 2} correlations have been revised to reflect the updated Ni/NiO phase transition correlation. New data are presented for EN82H weld metal (also known as Alloy 82) at 338 C. Similar to other nickel alloys, SCC of EN82H is a function of the aqueous H{sub 2} level, with the SCCGR exhibiting a maximum near the Ni/NiO transition. For example, the SCCGR at 8 scc/kg H{sub 2} is {approx} 81 x higher than at 60 scc/kg H{sub 2}. The 8 scc/kg H{sub 2} condition is near the Ni/NiO transition (located at {approx} 14 scc/kg H{sub 2} at 338 C), while 60 scc/kg H{sub 2} is well into the nickel metal regime. A hydrogen-SCCGR correlation is provided for EN82H. The data and understanding obtained from the present work show that SCC can be mitigated by adjusting the aqueous H{sub 2} level. For example, SCCGR is typically minimized at relatively high aqueous H{sub 2} levels, that are well into the nickel metal regime (i.e., far from the Ni/NiO transition).

  14. Oxidation Resistant Graphite Studies

    SciTech Connect (OSTI)

    W. Windes; R. Smith

    2014-07-01T23:59:59.000Z

    The Very High Temperature Reactor (VHTR) Graphite Research and Development Program is investigating doped nuclear graphite grades exhibiting oxidation resistance. During a oxygen ingress accident the oxidation rates of the high temperature graphite core region would be extremely high resulting in significant structural damage to the core. Reducing the oxidation rate of the graphite core material would reduce the structural effects and keep the core integrity intact during any air-ingress accident. Oxidation testing of graphite doped with oxidation resistant material is being conducted to determine the extent of oxidation rate reduction. Nuclear grade graphite doped with varying levels of Boron-Carbide (B4C) was oxidized in air at nominal 740°C at 10/90% (air/He) and 100% air. The oxidation rates of the boronated and unboronated graphite grade were compared. With increasing boron-carbide content (up to 6 vol%) the oxidation rate was observed to have a 20 fold reduction from unboronated graphite. Visual inspection and uniformity of oxidation across the surface of the specimens were conducted. Future work to determine the remaining mechanical strength as well as graphite grades with SiC doped material are discussed.

  15. Aromatics oxidation and soot formation in flames

    SciTech Connect (OSTI)

    Howard, J.B.; Pope, C.J.; Shandross, R.A.; Yadav, T. [Massachusetts Institute of Technology, Cambridge (United States)

    1993-12-01T23:59:59.000Z

    This project is concerned with the kinetics and mechanisms of aromatics oxidation and soot and fullerenes formation in flames. The scope includes detailed measurements of profiles of stable and radical species concentrations in low-pressure one-dimensional premixed flames. Intermediate species identifications and mole fractions, fluxes, and net reaction rates calculated from the measured profiles are used to test postulated reaction mechanisms. Particular objectives are to identify and to determine or confirm rate constants for the main benzene oxidation reactions in flames, and to characterize fullerenes and their formation mechanisms and kinetics.

  16. METAL OXIDE NANOPARTICLES

    SciTech Connect (OSTI)

    FERNANDEZ-GARCIA,M.; RODGRIGUEZ, J.A.

    2007-10-01T23:59:59.000Z

    This chapter covers the fundamental science, synthesis, characterization, physicochemical properties and applications of oxide nanomaterials. Explains fundamental aspects that determine the growth and behavior of these systems, briefly examines synthetic procedures using bottom-up and top-down fabrication technologies, discusses the sophisticated experimental techniques and state of the art theory results used to characterize the physico-chemical properties of oxide solids and describe the current knowledge concerning key oxide materials with important technological applications.

  17. Barium oxide, calcium oxide, magnesia, and alkali oxide free glass

    DOE Patents [OSTI]

    Lu, Peizhen Kathy; Mahapatra, Manoj Kumar

    2013-09-24T23:59:59.000Z

    A glass composition consisting essentially of about 10-45 mole percent of SrO; about 35-75 mole percent SiO.sub.2; one or more compounds from the group of compounds consisting of La.sub.2O.sub.3, Al.sub.2O.sub.3, B.sub.2O.sub.3, and Ni; the La.sub.2O.sub.3 less than about 20 mole percent; the Al.sub.2O.sub.3 less than about 25 mole percent; the B.sub.2O.sub.3 less than about 15 mole percent; and the Ni less than about 5 mole percent. Preferably, the glass is substantially free of barium oxide, calcium oxide, magnesia, and alkali oxide. Preferably, the glass is used as a seal in a solid oxide fuel/electrolyzer cell (SOFC) stack. The SOFC stack comprises a plurality of SOFCs connected by one or more interconnect and manifold materials and sealed by the glass. Preferably, each SOFC comprises an anode, a cathode, and a solid electrolyte.

  18. Mixed oxide solid solutions

    DOE Patents [OSTI]

    Magno, Scott (Dublin, CA); Wang, Ruiping (Fremont, CA); Derouane, Eric (Liverpool, GB)

    2003-01-01T23:59:59.000Z

    The present invention is a mixed oxide solid solution containing a tetravalent and a pentavalent cation that can be used as a support for a metal combustion catalyst. The invention is furthermore a combustion catalyst containing the mixed oxide solid solution and a method of making the mixed oxide solid solution. The tetravalent cation is zirconium(+4), hafnium(+4) or thorium(+4). In one embodiment, the pentavalent cation is tantalum(+5), niobium(+5) or bismuth(+5). Mixed oxide solid solutions of the present invention exhibit enhanced thermal stability, maintaining relatively high surface areas at high temperatures in the presence of water vapor.

  19. Electrodeposition of hybrid organicinorganic films containing iron oxide

    E-Print Network [OSTI]

    Niewczas, Marek

    Electrodeposition of hybrid organic­inorganic films containing iron oxide I. Zhitomirsky *, M has been developed for the preparation of hybrid organic­inorganic films containing iron oxide properties could be varied. Magnetic measurements revealed that the nanocomposite films are superparamagnetic

  20. Cerium Oxide Coating for Oxidation Reduction

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t z C oCNMSStaffCerium Oxide Coating for Oxidation

  1. Variable-Temperature Electrical Measurements of Zinc Oxide/Tin Oxide-Cosubstituted Indium Oxide

    E-Print Network [OSTI]

    Poeppelmeier, Kenneth R.

    as transparent electrodes in solar cells, flat panel displays, and many other applications. The commercial TCO: Flat Panel Display Mater. Large Area Processes 1998, 508, 308. (4) Minami, T.; Takata, S.; Kakumu, T

  2. Stabilized chromium oxide film

    DOE Patents [OSTI]

    Garwin, Edward L. (Los Altos, CA); Nyaiesh, Ali R. (Palo Alto, CA)

    1988-01-01T23:59:59.000Z

    Stabilized air-oxidized chromium films deposited on high-power klystron ceramic windows and sleeves having a thickness between 20 and 150.ANG. are useful in lowering secondary electron emission yield and in avoiding multipactoring and window failure due to overheating. The ceramic substrate for the film is chosen from alumina, sapphire or beryllium oxide.

  3. Stabilized chromium oxide film

    DOE Patents [OSTI]

    Nyaiesh, A.R.; Garwin, E.L.

    1986-08-04T23:59:59.000Z

    Stabilized air-oxidized chromium films deposited on high-power klystron ceramic windows and sleeves having a thickness between 20 and 150A are useful in lowering secondary electron emission yield and in avoiding multipactoring and window failure due to overheating. The ceramic substrate for the film is chosen from alumina, sapphire or beryllium oxide.

  4. Reducible oxide based catalysts

    DOE Patents [OSTI]

    Thompson, Levi T.; Kim, Chang Hwan; Bej, Shyamal K.

    2010-04-06T23:59:59.000Z

    A catalyst is disclosed herein. The catalyst includes a reducible oxide support and at least one noble metal fixed on the reducible oxide support. The noble metal(s) is loaded on the support at a substantially constant temperature and pH.

  5. Size Effect of Ruthenium Nanoparticles in Catalytic Carbon Monoxide Oxidation

    SciTech Connect (OSTI)

    Joo, Sang Hoon; Park, Jeong Y.; Renzas, J. Russell; Butcher, Derek R.; Huang, Wenyu; Somorjai, Gabor A.

    2010-04-04T23:59:59.000Z

    Carbon monoxide oxidation over ruthenium catalysts has shown an unusual catalytic behavior. Here we report a particle size effect on CO oxidation over Ru nanoparticle (NP) catalysts. Uniform Ru NPs with a tunable particle size from 2 to 6 nm were synthesized by a polyol reduction of Ru(acac){sub 3} precursor in the presence of poly(vinylpyrrolidone) stabilizer. The measurement of catalytic activity of CO oxidation over two-dimensional Ru NPs arrays under oxidizing reaction conditions (40 Torr CO and 100 Torr O{sub 2}) showed an activity dependence on the Ru NP size. The CO oxidation activity increases with NP size, and the 6 nm Ru NP catalyst shows 8-fold higher activity than the 2 nm catalysts. The results gained from this study will provide the scientific basis for future design of Ru-based oxidation catalysts.

  6. Intra-channel mass and heat-transfer modeling in diesel oxidation catalysts

    E-Print Network [OSTI]

    Tennessee, University of

    02FCC-140 Intra-channel mass and heat-transfer modeling in diesel oxidation catalysts Kalyana transfer in modeling the performance of diesel oxidation catalysts. Many modeling studies have assumed experimental measurements of CO and hydrocarbon oxidation in diesel exhaust re- veal that actual mass

  7. Uranium Oxide as a Highly Reflective Coating from 150-350 eV

    E-Print Network [OSTI]

    Hart, Gus

    of depleted uranium metal (less than 0.2% U-235). After sputtering, the uranium was allowed to oxidize1 Uranium Oxide as a Highly Reflective Coating from 150-350 eV Richard L. Sandberg, David D. Allred.byu.edu ABSTRACT We present the measured reflectances (beamline 6.3.2, ALS at LBNL) of naturally oxidized uranium

  8. Growth of tungsten oxide on carbon nanowalls templates

    SciTech Connect (OSTI)

    Wang, Hua, E-mail: wanghua@dlou.edu.cn [Faculty of Chemical, Environmental and Biological Science and Technology, Dalian University of Technology, Dalian 116024 (China); College of Fisheries and Life Science, Dalian Ocean University, Dalian 116023 (China); Su, Yan [Faculty of Chemical, Environmental and Biological Science and Technology, Dalian University of Technology, Dalian 116024 (China); Chen, Shuo, E-mail: shuochen@dlut.edu.cn [Faculty of Chemical, Environmental and Biological Science and Technology, Dalian University of Technology, Dalian 116024 (China); Quan, Xie [Faculty of Chemical, Environmental and Biological Science and Technology, Dalian University of Technology, Dalian 116024 (China)

    2013-03-15T23:59:59.000Z

    Highlights: ? Tungsten oxide deposited on carbon nanowalls by hot filament chemical vapor deposition technique. ? This composite has two-dimensional uniform morphology with a crystalline structure of monoclinic tungsten trioxide. ? Surface photoelectric voltage measurements show that this product has photoresponse properties. - Abstract: In the present work we present a simple approach for coupling tungsten oxide with carbon nanowalls. The two-dimensional carbon nanowalls with open boundaries were grown using plasma enhanced hot filament chemical vapor deposition, and the subsequent tungsten oxide growth was performed in the same equipment by direct heating of a tungsten filament. The tungsten oxide coating is found to have uniform morphology with a crystalline structure of monoclinic tungsten trioxide. Surface photoelectric voltage measurements show that this product has photoresponse properties. The method of synthesis described here provides an operable route to the production of two-dimensional tungsten oxide nanocomposites.

  9. Oxidative Tritium Decontamination System

    DOE Patents [OSTI]

    Gentile, Charles A. (Plainsboro, NJ), Guttadora, Gregory L. (Highland Park, NJ), Parker, John J. (Medford, NJ)

    2006-02-07T23:59:59.000Z

    The Oxidative Tritium Decontamination System, OTDS, provides a method and apparatus for reduction of tritium surface contamination on various items. The OTDS employs ozone gas as oxidizing agent to convert elemental tritium to tritium oxide. Tritium oxide vapor and excess ozone gas is purged from the OTDS, for discharge to atmosphere or transport to further process. An effluent stream is subjected to a catalytic process for the decomposition of excess ozone to diatomic oxygen. One of two configurations of the OTDS is employed: dynamic apparatus equipped with agitation mechanism and large volumetric capacity for decontamination of light items, or static apparatus equipped with pressurization and evacuation capability for decontamination of heavier, delicate, and/or valuable items.

  10. Electrical resistance measurements of highly inhibited SiC coated carbon-carbon laminates

    E-Print Network [OSTI]

    Parker, Paul Albert

    1998-01-01T23:59:59.000Z

    resistance values to the mass loss. In-situ electrical resistance measurements are taken at 900'C and shear modulus measurements are obtained at room temperature prior to and following oxidation. Initial oxidation damage is incurred preferentially along both...

  11. Controlled CO preferential oxidation

    DOE Patents [OSTI]

    Meltser, M.A.; Hoch, M.M.

    1997-06-10T23:59:59.000Z

    Method is described for controlling the supply of air to a PROX (PReferential OXidation for CO cleanup) reactor for the preferential oxidation in the presence of hydrogen wherein the concentration of the hydrogen entering and exiting the PROX reactor is monitored, the difference there between correlated to the amount of air needed to minimize such difference, and based thereon the air supply to the PROX reactor adjusted to provide such amount and minimize such difference. 2 figs.

  12. ADVANCED OXIDATION PROCESS

    SciTech Connect (OSTI)

    Dr. Colin P. Horwitz; Dr. Terrence J. Collins

    2003-11-04T23:59:59.000Z

    The removal of recalcitrant sulfur species, dibenzothiophene and its derivatives, from automotive fuels is an integral component in the development of cleaner burning and more efficient automobile engines. Oxidative desulfurization (ODS) wherein the dibenzothiophene derivative is converted to its corresponding sulfoxide and sulfone is an attractive approach to sulfur removal because the oxidized species are easily extracted or precipitated and filtered from the hydrocarbon phase. Fe-TAML{reg_sign} activators of hydrogen peroxide (TAML is Tetra-Amido-Macrocyclic-Ligand) catalytically convert dibenzothiophene and its derivatives rapidly and effectively at moderate temperatures (50-60 C) and ambient pressure to the corresponding sulfoxides and sulfones. The oxidation process can be performed in both aqueous systems containing alcohols such as methanol, ethanol, or t-butanol, and in a two-phase hydrocarbon/aqueous system containing tert-butanol or acetonitrile. In the biphasic system, essentially complete conversion of the DBT to its oxidized products can be achieved using slightly longer reaction times than in homogeneous solution. Among the key features of the technology are the mild reaction conditions, the very high selectivity where no over oxidation of the sulfur compounds occurs, the near stoichiometric use of hydrogen peroxide, the apparent lack of degradation of sensitive fuel components, and the ease of separation of oxidized products.

  13. Measurement-Measurement-

    E-Print Network [OSTI]

    Jeong, Jaehoon "Paul"

    Internet Measurement- System A Measurement- System B Control System GPS Satellite GPS Satellite GPS Receiver GPS Receiver 2) measurement 3) data1) command Methodology for One-way IP Performance Measurement This paper proposes a methodology for measurement of one-way IP performance metrics such as one-way delay

  14. Thermo-Oxidation of Tokamak Carbon Dust

    SciTech Connect (OSTI)

    J.W. Davis; B.W.N. Fitzpatrick; J.P. Sharpe; A.A. Haasz

    2008-04-01T23:59:59.000Z

    The oxidation of dust and flakes collected from the DIII-D tokamak, and various commercial dust specimens, has been measured at 350 ºC and 2.0 kPa O2 pressure. Following an initial small mass loss, most of the commercial dust specimens showed very little effect due to O2 exposure. Similarly, dust collected from underneath DIII-D tiles, which is thought to comprise largely Grafoil™ particulates, also showed little susceptibility to oxidation at this temperature. However, oxidation of the dust collected from tile surfaces has led to ~ 18% mass loss after 8 hours; thereafter, little change in mass was observed. This suggests that the surface dust includes some components of different composition and/or structure – possibly fragments of codeposited layers. The oxidation of codeposit flakes scraped form DIII-D upper divertor tiles showed an initial 25% loss in mass due to heating in vacuum, and the gradual loss of 30-38% mass during the subsequent 24 hours exposure to O2. This behavior is significantly different from that observed for the oxidation of thinner DIII-D codeposit specimens which were still adhered to tile surfaces, and this is thought to be related to the low deuterium content (D/C ~ 0.03 – 0.04) of the flakes.

  15. Oxidation of Mercury in Products of Coal Combustion

    SciTech Connect (OSTI)

    Peter Walsh; Giang Tong; Neeles Bhopatkar; Thomas Gale; George Blankenship; Conrad Ingram; Selasi Blavo Tesfamariam Mehreteab; Victor Banjoko; Yohannes Ghirmazion; Heng Ban; April Sibley

    2009-09-14T23:59:59.000Z

    Laboratory measurements of mercury oxidation during selective catalytic reduction (SCR) of nitric oxide, simulation of pilot-scale measurements of mercury oxidation and adsorption by unburned carbon and fly ash, and synthesis of new materials for simultaneous oxidation and adsorption of mercury, were performed in support of the development of technology for control of mercury emissions from coal-fired boilers and furnaces. Conversion of gas-phase mercury from the elemental state to water-soluble oxidized form (HgCl{sub 2}) enables removal of mercury during wet flue gas desulfurization. The increase in mercury oxidation in a monolithic V{sub 2}O{sub 5}-WO{sub 3}/TiO{sub 2} SCR catalyst with increasing HCl at low levels of HCl (< 10 ppmv) and decrease in mercury oxidation with increasing NH{sub 3}/NO ratio during SCR were consistent with results of previous work by others. The most significant finding of the present work was the inhibition of mercury oxidation in the presence of CO during SCR of NO at low levels of HCl. In the presence of 2 ppmv HCl, expected in combustion products from some Powder River Basin coals, an increase in CO from 0 to 50 ppmv reduced the extent of mercury oxidation from 24 {+-} 3 to 1 {+-} 4%. Further increase in CO to 100 ppmv completely suppressed mercury oxidation. In the presence of 11-12 ppmv HCl, increasing CO from 0 to {approx}120 ppmv reduced mercury oxidation from {approx}70% to 50%. Conversion of SO{sub 2} to sulfate also decreased with increasing NH{sub 3}/NO ratio, but the effects of HCl and CO in flue gas on SO{sub 2} oxidation were unclear. Oxidation and adsorption of mercury by unburned carbon and fly ash enables mercury removal in a particulate control device. A chemical kinetic mechanism consisting of nine homogeneous and heterogeneous reactions for mercury oxidation and removal was developed to interpret pilot-scale measurements of mercury oxidation and adsorption by unburned carbon and fly ash in experiments at pilot scale, burning bituminous coals (Gale, 2006) and blends of bituminous coals with Powder River Basin coal (Gale, 2005). The removal of mercury by fly ash and unburned carbon in the flue gas from combustion of the bituminous coals and blends was reproduced with satisfactory accuracy by the model. The enhancement of mercury capture in the presence of calcium (Gale, 2005) explained a synergistic effect of blending on mercury removal across the baghouse. The extent of mercury oxidation, on the other hand, was not so well described by the simulation, because of oversensitivity of the oxidation process in the model to the concentration of unburned carbon. Combined catalysts and sorbents for oxidation and removal of mercury from flue gas at low temperature were based on surfactant-templated silicas containing a transition metal and an organic functional group. The presence of both metal ions and organic groups within the pore structure of the materials is expected to impart to them the ability to simultaneously oxidize elemental mercury and adsorb the resulting oxidized mercury. Twelve mesoporous organosilicate catalysts/sorbents were synthesized, with and without metals (manganese, titanium, vanadium) and organic functional groups (aminopropyl, chloropropyl, mercaptopropyl). Measurement of mercury oxidation and adsorption by the candidate materials remains for future work.

  16. Oxidation of propylene over copper oxide catalysts 

    E-Print Network [OSTI]

    Billingsley, David Stuart

    1958-01-01T23:59:59.000Z

    sulfate of either sodium, potassium, lithium, rubidium or cesium. The active agent was prepared in the form of a slurry which was deposited on the carrier by agitating the two materials together. The carrier was alumina or silicon carbide. Oxidation... welded on each end. On the bottom of the tank was a drain connection which was closed; the tank also contained a thermometer well. The tank was connected to the vent system through a needle valve and also through a safety valve which was set...

  17. Elongational viscosity of photo-oxidated LDPE

    SciTech Connect (OSTI)

    Rolón-Garrido, Víctor H., E-mail: victor.h.rolongarrido@tu-berlin.de, E-mail: manfred.wagner@tu-berlin.de; Wagner, Manfred H., E-mail: victor.h.rolongarrido@tu-berlin.de, E-mail: manfred.wagner@tu-berlin.de [Chair of Polymer Engineering and Polymer Physics, Berlin Institute of Technology-TU Berlin. Fasanenstr. 90. 10623 Berlin (Germany)

    2014-05-15T23:59:59.000Z

    Sheets of low-density polyethylene (LDPE) were photo-oxidatively treated at room temperature, and subsequently characterized rheologically in the melt state by shear and uniaxial extensional experiments. For photo-oxidation, a xenon lamp was used to irradiate the samples for times between 1 day and 6 weeks. Linear-viscoelastic characterization was performed in a temperature range of 130 to 220°C to obtain the master curve at 170°C, the reference temperature at which the elongational viscosities were measured. Linear viscoelasticity is increasingly affected by increasing photo-oxidation due to crosslinking of LDPE, as corroborated by an increasing gel fraction as determined by a solvent extraction method. The elongational measurements reveal a strong enhancement of strain hardening until a saturation level is achieved. The elongational data are analyzed in the frame work of two constitutive equations, the rubber-like liquid and the molecular stress function models. Within the experimental window, timedeformation separability is confirmed for all samples, independent of the degree of photo-oxidation.

  18. Aromatics oxidation and soot formation in flames

    SciTech Connect (OSTI)

    Howard, J.B.; Pope, C.J.; Shandross, R.A.; Yadav, T.

    1993-04-01T23:59:59.000Z

    This project is concerned with the kinetics and mechanisms of aromatics oxidation and soot and fullerenes formation in flames. The scope includes detailed measurements of profiles of stable and radical species concentrations in low-pressure one-dimensional premixed flames. Intermediate species identifications and mole fractions, fluxes, and net reaction rates calculated from the measured profiles are used to test postulated reaction mechanisms. Particular objectives are to identify, and to confirm or determine rate constants for, the main benzene oxidation reactions in flames, and to characterize soot and fullerenes and their formation mechanisms and kinetics. Stable and radical species profiles in the aromatics oxidation study are measured using molecular beam sampling with on-line mass spectrometry. The rate of soot formation measured by conventional optical techniques is found to support the hypotheses that particle inception occurs through reactive coagulation of high molecular weight PAH in competition with destruction by OHattack, and that the subsequent growth of the soot mass occurs through addition reactions of PAH and C[sub 2]H[sub 2] with the soot particles. During the first year of this reporting period, fullerenes C[sub 60] and C[sub 70] in substantial quantities were found in the flames being studied. The fullerenes were recovered, purified and spectroscopically identified. The yields of C[sub 60] and C[sub 70] were then determined over ranges of conditions in low-pressure premixed flames of benzene and oxygen.

  19. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

    1999-01-01T23:59:59.000Z

    A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

  20. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

    2001-01-01T23:59:59.000Z

    A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

  1. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, S.; Kumar, R.; Krumpelt, M.

    1999-08-24T23:59:59.000Z

    A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

  2. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, S.; Kumar, R.; Krumpelt, M.

    1999-08-17T23:59:59.000Z

    A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

  3. Low temperature oxidation of plutonium

    SciTech Connect (OSTI)

    Nelson, Art J. [Lawrence Livermore National Laboratory, Livermore, California 94551 (United States); Roussel, Paul [AWE, Aldermaston, Reading, Berkshire, RG7 4PR (United Kingdom)

    2013-05-15T23:59:59.000Z

    The initial oxidation of gallium stabilized {delta}-plutonium metal at 193 K has been followed using x-ray photoelectron spectroscopy. On exposure to Langmuir quantities of oxygen, plutonium rapidly forms a trivalent oxide followed by a tetravalent plutonium oxide. The growth modes of both oxides have been determined. Warming the sample in vacuum, the tetravalent oxide reduces to the trivalent oxide. The kinetics of this reduction reaction have followed and the activation energy has been determined to be 38.8 kJ mol{sup -1}.

  4. DISSOLUTION OF NEPTUNIUM OXIDE RESIDUES

    SciTech Connect (OSTI)

    Kyser, E

    2009-01-12T23:59:59.000Z

    This report describes the development of a dissolution flowsheet for neptunium (Np) oxide (NpO{sub 2}) residues (i.e., various NpO{sub 2} sources, HB-Line glovebox sweepings, and Savannah River National Laboratory (SRNL) thermogravimetric analysis samples). Samples of each type of materials proposed for processing were dissolved in a closed laboratory apparatus and the rate and total quantity of off-gas were measured. Samples of the off-gas were also analyzed. The quantity and type of solids remaining (when visible) were determined after post-dissolution filtration of the solution. Recommended conditions for dissolution of the NpO{sub 2} residues are: Solution Matrix and Loading: {approx}50 g Np/L (750 g Np in 15 L of dissolver solution), using 8 M nitric acid (HNO{sub 3}), 0.025 M potassium fluoride (KF) at greater than 100 C for at least 3 hours. Off-gas: Analysis of the off-gas indicated nitric oxide (NO), nitrogen dioxide (NO{sub 2}) and nitrous oxide (N{sub 2}O) as the only identified components. No hydrogen (H{sub 2}) was detected. The molar ratio of off-gas produced per mole of Np dissolved ranged from 0.25 to 0.4 moles of gas per mole of Np dissolved. A peak off-gas rate of {approx}0.1 scfm/kg bulk oxide was observed. Residual Solids: Pure NpO{sub 2} dissolved with little or no residue with the proposed flowsheet but the NpCo and both sweepings samples left visible solid residue after dissolution. For the NpCo and Part II Sweepings samples the residue amounted to {approx}1% of the initial material, but for the Part I Sweepings sample, the residue amounted to {approx}8 % of the initial material. These residues contained primarily aluminum (Al) and silicon (Si) compounds that did not completely dissolve under the flowsheet conditions. The residues from both sweepings samples contained minor amounts of plutonium (Pu) particles. Overall, the undissolved Np and Pu particles in the residues were a very small fraction of the total solids.

  5. Characterization of Amorphous Zinc Tin Oxide Semiconductors....

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Amorphous Zinc Tin Oxide Semiconductors. Characterization of Amorphous Zinc Tin Oxide Semiconductors. Abstract: Amorphous zinc tin oxide (ZTO) was investigated to determine the...

  6. Tetraalklylammonium polyoxoanionic oxidation catalysts

    DOE Patents [OSTI]

    Ellis, P.E.; Lyons, J.E.; Myers, H.K. Jr.; Shaikh, S.N.

    1998-10-06T23:59:59.000Z

    Alkanes are catalytically oxidized in air or oxygen using iron-substituted polyoxoanions (POAs) of the formula: H{sub e{minus}z}[(n-C{sub 4}H{sub 9}){sub 4}N]{sub z}(XM{sub 11}M{prime}O{sub 39}){sup {minus}e}. The M{prime} (e.g., iron(III)/iron(II)) reduction potential of the POAs is affected by selection of the central atom X and the framework metal M, and by the number of tetrabutyl-ammonium groups. Decreased Fe(III)/Fe(II) reduction potential has been found to correlate to increased oxidation activity.

  7. Tetraalykylammonium polyoxoanionic oxidation catalysts

    DOE Patents [OSTI]

    Ellis, Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA); Myers, Jr., Harry K. (Cochranville, PA); Shaikh, Shahid N. (Media, PA)

    1998-01-01T23:59:59.000Z

    Alkanes are catalytically oxidized in air or oxygen using iron-substituted polyoxoanions (POAs) of the formula: H.sub.e-z ›(n-C.sub.4 H.sub.9).sub.4 N!.sub.z (XM.sub.11 M'O.sub.39).sup.-e The M' (e.g., iron(III)/iron(II)) reduction potential of the POAs is affected by selection of the central atom X and the framework metal M, and by the number of tetrabutyl-ammonium groups. Decreased Fe(III)/Fe(II) reduction potential has been found to correlate to increased oxidation activity.

  8. Selective oxidation of buried AlGaAs for fabrication of vertical-cavity lasers

    SciTech Connect (OSTI)

    Choquette, K.D.; Geib, K.M.; Chui, H.C.; Hou, H.Q. [Sandia National Labs., Albuquerque, NM (United States). Photonics Research Dept.; Hull, R. [Univ. of Virginia, Charlottesville, VA (United States). Dept. of Materials Science

    1996-06-01T23:59:59.000Z

    The authors discuss the selective conversion of buried layers of AlGaAs to a stable oxide and the implementation of this oxide into high performance vertical-cavity surface emitting lasers (VCSELs). The rate of lateral oxidation is shown to be linear with an Arrhenius temperature dependence. The measured activation energies vary with Al composition, providing a high degree of oxidation selectivity between AlGaAs alloys. Thus buried oxide layers can be selectively fabricated within the VCSEL through small compositional variations in the AlGaAs layers. The oxidation of AlGaAs alloys, as opposed to AlAs, is found to provide robust processing of reliable lasers. The insulating and low refractive index oxide provides enhanced electrical and optical confinement for ultralow threshold currents in oxide-apertured VCSELs.

  9. Role of Photoexcitation and Field Ionization in the Measurement...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Field Ionization in the Measurement of Accurate Oxide Stoichiometry by Laser-Assisted Atom Probe Abstract: Pulsed lasers extend the high spatial and mass...

  10. Nanostructured transition metal oxides useful for water oxidation catalysis

    DOE Patents [OSTI]

    Frei, Heinz M; Jiao, Feng

    2013-12-24T23:59:59.000Z

    The present invention provides for a composition comprising a nanostructured transition metal oxide capable of oxidizing two H.sub.2O molecules to obtain four protons. In some embodiments of the invention, the composition further comprises a porous matrix wherein the nanocluster of the transition metal oxide is embedded on and/or in the porous matrix.

  11. SOLID OXIDE PLANAR AND TUBULAR SOLID OXIDE FUEL

    E-Print Network [OSTI]

    Mease, Kenneth D.

    SOLID OXIDE PLANAR AND TUBULAR SOLID OXIDE FUEL CELLS Dynamic Simulation Approach Modular Approach: Individual simulation modules for each fuel cell type · Tubular SOFC · Planar SOFC · MCFC · PEM Reformer · Slow pressure transients #12;Fuel Cell Assumptions · H2 electrochemically oxidized only · CO consumed

  12. Oxidative Reforming of Biodiesel Over Molybdenum (IV) Oxide

    E-Print Network [OSTI]

    Collins, Gary S.

    Oxidative Reforming of Biodiesel Over Molybdenum (IV) Oxide Jessica Whalen, Oscar Marin Flores, Su University INTRODUCTION Energy consumption continues to skyrocket worldwide. Biodiesel is a renewable fuel as potential feedstock in solid oxide fuel cells. Petroleum based fuels become scarcer daily, and biodiesel

  13. Staged membrane oxidation reactor system

    DOE Patents [OSTI]

    Repasky, John Michael; Carolan, Michael Francis; Stein, VanEric Edward; Chen, Christopher Ming-Poh

    2013-04-16T23:59:59.000Z

    Ion transport membrane oxidation system comprising (a) two or more membrane oxidation stages, each stage comprising a reactant zone, an oxidant zone, one or more ion transport membranes separating the reactant zone from the oxidant zone, a reactant gas inlet region, a reactant gas outlet region, an oxidant gas inlet region, and an oxidant gas outlet region; (b) an interstage reactant gas flow path disposed between each pair of membrane oxidation stages and adapted to place the reactant gas outlet region of a first stage of the pair in flow communication with the reactant gas inlet region of a second stage of the pair; and (c) one or more reactant interstage feed gas lines, each line being in flow communication with any interstage reactant gas flow path or with the reactant zone of any membrane oxidation stage receiving interstage reactant gas.

  14. Staged membrane oxidation reactor system

    DOE Patents [OSTI]

    Repasky, John Michael; Carolan, Michael Francis; Stein, VanEric Edward; Chen, Christopher Ming-Poh

    2012-09-11T23:59:59.000Z

    Ion transport membrane oxidation system comprising (a) two or more membrane oxidation stages, each stage comprising a reactant zone, an oxidant zone, one or more ion transport membranes separating the reactant zone from the oxidant zone, a reactant gas inlet region, a reactant gas outlet region, an oxidant gas inlet region, and an oxidant gas outlet region; (b) an interstage reactant gas flow path disposed between each pair of membrane oxidation stages and adapted to place the reactant gas outlet region of a first stage of the pair in flow communication with the reactant gas inlet region of a second stage of the pair; and (c) one or more reactant interstage feed gas lines, each line being in flow communication with any interstage reactant gas flow path or with the reactant zone of any membrane oxidation stage receiving interstage reactant gas.

  15. Staged membrane oxidation reactor system

    DOE Patents [OSTI]

    Repasky, John Michael; Carolan, Michael Francis; Stein, VanEric Edward; Chen, Christopher Ming-Poh

    2014-05-20T23:59:59.000Z

    Ion transport membrane oxidation system comprising (a) two or more membrane oxidation stages, each stage comprising a reactant zone, an oxidant zone, one or more ion transport membranes separating the reactant zone from the oxidant zone, a reactant gas inlet region, a reactant gas outlet region, an oxidant gas inlet region, and an oxidant gas outlet region; (b) an interstage reactant gas flow path disposed between each pair of membrane oxidation stages and adapted to place the reactant gas outlet region of a first stage of the pair in flow communication with the reactant gas inlet region of a second stage of the pair; and (c) one or more reactant interstage feed gas lines, each line being in flow communication with any interstage reactant gas flow path or with the reactant zone of any membrane oxidation stage receiving interstage reactant gas.

  16. Doped zinc oxide microspheres

    DOE Patents [OSTI]

    Arnold, W.D. Jr.; Bond, W.D.; Lauf, R.J.

    1993-12-14T23:59:59.000Z

    A new composition and method of making same for a doped zinc oxide microsphere and articles made therefrom for use in an electrical surge arrestor which has increased solid content, uniform grain size and is in the form of a gel. 4 figures.

  17. Highly oxidized superconductors

    DOE Patents [OSTI]

    Morris, Donald E. (Kensington, CA)

    1994-01-01T23:59:59.000Z

    Novel superconducting materials in the form of compounds, structures or phases are formed by performing otherwise known syntheses in a highly oxidizing atmosphere rather than that created by molecular oxygen at atmospheric pressure or below. This leads to the successful synthesis of novel superconducting compounds which are thermodynamically stable at the conditions under which they are formed.

  18. Highly oxidized superconductors

    DOE Patents [OSTI]

    Morris, D.E.

    1994-09-20T23:59:59.000Z

    Novel superconducting materials in the form of compounds, structures or phases are formed by performing otherwise known synthesis in a highly oxidizing atmosphere rather than that created by molecular oxygen at atmospheric pressure or below. This leads to the successful synthesis of novel superconducting compounds which are thermodynamically stable at the conditions under which they are formed. 16 figs.

  19. Optically transparent yttrium oxide

    SciTech Connect (OSTI)

    Hartnett, T.; Greenberg, M.; Gentilman, R.L.

    1988-08-02T23:59:59.000Z

    A body is described comprising at least 99.9% yttrium oxide having a density of at least 99% of theoretically density, a sample of the body having a in-line transmission of at least 73%, over a wavelength range of 2-5 microns with the sample having a thickness of 0.375 inches.

  20. Zircaloy-4 oxidation at 1300 to 2400/sup 0/C

    SciTech Connect (OSTI)

    Prater, J.T.; Courtright, E.L.

    1987-04-01T23:59:59.000Z

    The oxidation kinetics of Zircaloy-4 in steam have been extended to 2400/sup 0/C. The ZrO/sub 2/ and ..cap alpha..-Zr layers display parabolic growth behavior over the entire temperature range studied. A discontinuity in the oxidation kinetics at 1510/sup 0/C causes rates to increase above those previously established by the Baker-Just relationship. This increase coincides with the tetragonal-to-cubic phase transformation in ZrO/sub 2-x/. No additional discontinuity in the oxide growth rate was observed when the metal phase melted. The effects of temperature gradients were taken into account, and corrected values representative of near-isothermal conditions were computed. Oxide growth was also measured in various steam-hydrogen mixtures at 1565/sup 0/C and 1815/sup 0/C. Hydrogen concentrations up to 90 mol% had no effect on oxidation kinetics. The rate-controlling factor appears to be diffusion through the oxide layer. Finally, the oxidation kinetics of prereacted Zircaloy-15 mol% UO/sub 2/ were measured at 1400 to 2150/sup 0/C. The rates were comparable to those obtained for Zircaloy above 1500/sup 0/C.

  1. REVIEW OF PLUTONIUM OXIDATION LITERATURE

    SciTech Connect (OSTI)

    Korinko, P.

    2009-11-12T23:59:59.000Z

    A brief review of plutonium oxidation literature was conducted. The purpose of the review was to ascertain the effect of oxidation conditions on oxide morphology to support the design and operation of the PDCF direct metal oxidation (DMO) furnace. The interest in the review was due to a new furnace design that resulted in oxide characteristics that are different than those of the original furnace. Very little of the published literature is directly relevant to the DMO furnace operation, which makes assimilation of the literature data with operating conditions and data a convoluted task. The oxidation behavior can be distilled into three regimes, a low temperature regime (RT to 350 C) with a relatively slow oxidation rate that is influenced by moisture, a moderate temperature regime (350-450 C) that is temperature dependent and relies on more or less conventional oxidation growth of a partially protective oxide scale, and high temperature oxidation (> 500 C) where the metal autocatalytically combusts and oxidizes. The particle sizes obtained from these three regimes vary with the finest being from the lowest temperature. It is surmised that the slow growth rate permits significant stress levels to be achieved that help break up the oxides. The intermediate temperatures result in a fairly compact scale that is partially protective and that grows to critical thickness prior to fracturing. The growth rate in this regime may be parabolic or paralinear, depending on the oxidation time and consequently the oxide thickness. The high temperature oxidation is invariant in quiescent or nearly quiescent conditions due to gas blanketing while it accelerates with temperature under flowing conditions. The oxide morphology will generally consist of fine particles (<15 {micro}m), moderately sized particles (15 < x < 250 {micro}m) and large particles (> 250 {micro}m). The particle size ratio is expected to be < 5%, 25%, and 70% for fine, medium and large particles, respectively, for metal temperatures in the 500-600 C range.

  2. Low cation coordination in oxide melts

    SciTech Connect (OSTI)

    Skinner, Lawrie [State University of New York, Stony Brook] [State University of New York, Stony Brook; Benmore, Chris J [Argonne National Laboratory (ANL)] [Argonne National Laboratory (ANL); Du, Jincheng [University of North Texas] [University of North Texas; Weber, Richard [Argonne National Laboratory (ANL)] [Argonne National Laboratory (ANL); Neuefeind, Joerg C [ORNL] [ORNL; Tumber, Sonia [Materials Development, Inc., Evanston, IL] [Materials Development, Inc., Evanston, IL; Parise, John B [Stony Brook University (SUNY)] [Stony Brook University (SUNY)

    2014-01-01T23:59:59.000Z

    The complete set of Faber-Ziman partial pair distribution functions for a rare earth oxide liquid were measured for the first time by combining aerodynamic levitation, neutron diffraction, high energy x-ray diffraction and isomorphic substitution using Y2 O3 and Ho2 O3 melts. The average Y- O coordination is measured to be 5.5(2), which is significantly less than the octahedral coordination of crystalline Y2 O3 (or Ho2 O3 ). Investigation of high temperature La2 O3 , ZrO2 , SiO2 , and Al2 O3 melts by x-ray diffraction and molecular dynamics simulations also show lower-than-crystal cation- oxygen coordination. These measurements suggest a general trend towards lower M-O coordination compared to their crystalline counterparts. It is found that this coordination number drop is larger for lower field strength, larger radius cations and is negligible for high field strength (network forming) cations. These findings have broad implications for predicting the local structure and related physical properties of metal-oxide melts and oxide glasses.

  3. Doped palladium containing oxidation catalysts

    DOE Patents [OSTI]

    Mohajeri, Nahid

    2014-02-18T23:59:59.000Z

    A supported oxidation catalyst includes a support having a metal oxide or metal salt, and mixed metal particles thereon. The mixed metal particles include first particles including a palladium compound, and second particles including a precious metal group (PMG) metal or PMG metal compound, wherein the PMG metal is not palladium. The oxidation catalyst may also be used as a gas sensor.

  4. Model catalytic oxidation studies using supported monometallic and heterobimetallic oxides

    SciTech Connect (OSTI)

    Ekerdt, J.G.

    1992-02-03T23:59:59.000Z

    This research program is directed toward a more fundamental understanding of the effects of catalyst composition and structure on the catalytic properties of metal oxides. Metal oxide catalysts play an important role in many reactions bearing on the chemical aspects of energy processes. Metal oxides are the catalysts for water-gas shift reactions, methanol and higher alcohol synthesis, isosynthesis, selective catalytic reduction of nitric oxides, and oxidation of hydrocarbons. A key limitation to developing insight into how oxides function in catalytic reactions is in not having precise information of the surface composition under reaction conditions. To address this problem we have prepared oxide systems that can be used to study cation-cation effects and the role of bridging (-O-) and/or terminal (=O) surface oxygen anion ligands in a systematic fashion. Since many oxide catalyst systems involve mixtures of oxides, we selected a model system that would permit us to examine the role of each cation separately and in pairwise combinations. Organometallic molybdenum and tungsten complexes were proposed for use, to prepare model systems consisting of isolated monomeric cations, isolated monometallic dimers and isolated bimetallic dimers supported on silica and alumina. The monometallic and bimetallic dimers were to be used as models of more complex mixed- oxide catalysts. Our current program was to develop the systems and use them in model oxidation reactions.

  5. Graphene and Graphene Oxide: Biofunctionalization and Applications...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Graphene Oxide: Biofunctionalization and Applications in Biotechnology. Graphene and Graphene Oxide: Biofunctionalization and Applications in Biotechnology. Abstract: Graphene...

  6. Model catalytic oxidation studies using supported monometallic and heterobimetallic oxides

    SciTech Connect (OSTI)

    Ekerdt, J.G.

    1991-04-30T23:59:59.000Z

    This research program is directed toward developing a fundamental understanding of how catalyst composition, redox ability, and structure control the catalytic properties of metal oxides. Oxide systems that permit examination of the role of metal oxide cations separately and in pairwise combinations are being developed. Organometallic complexes containing C{sub 3}-allyl, cyclopentadienyl, or carbonyl ligands are exchanged with the hydroxide ligands of silica, alumina, titania, zirconia and magnesia supports. The exchange technique is used to achieve high metal oxide loadings without the formation of supported crystallites over silica. The organometallic route may also lead to oxygen-bridged cations and/or cation pairs over the supports prior to full oxidation. The anchored complex is subsequently oxidized to generate a supported oxide. 2 refs., 1 tab.

  7. Millisecond Oxidation of Alkanes

    Broader source: Energy.gov [DOE]

    This factsheet describes a project whose goal is to commercialize a production process for propylene and acrylic acid from propane using a catalytic auto-thermal oxydehydrogenation process operating at short contact times. Auto-thermal oxidation for conversion of propane to propylene and acrylic acid promises energy savings of 20 trillion Btu per year by 2020. In addition to reducing energy consumption, this technology can reduce manufacturing costs by up to 25 percent, and reduce a variety of greenhouse gas emissions.

  8. Nonisostructural complex oxide heteroepitaxy

    SciTech Connect (OSTI)

    Wong, Franklin J., E-mail: fwong@seas.harvard.edu; Ramanathan, Shriram [School of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts 02138 (United States)

    2014-07-01T23:59:59.000Z

    The authors present an overview of the fundamentals and representative examples of the growth of epitaxial complex oxide thin films on structurally dissimilar substrates. The authors will delineate how the details of particular crystal structures and symmetry of different oxide surfaces can be employed for a rational approach to the synthesis of nonisostructural epitaxial heterostructures. The concept of oxygen eutaxy can be widely applied. Materials combinations will be split into three categories, and in all cases the films and substrates occur in different crystal structures: (1) common translational and rotational symmetry between the film and substrate planes; (2) translational symmetry mismatch between the substrates and films that is distinct from a simple mismatch in lattice parameters; and (3) rotational symmetry mismatch. In case (1), in principle single-crystalline thin films can be attained despite the films and substrates possessing different crystal structures. In case (2), antiphase boundaries will be prevalent in the thin films. In case (3), thin-film rotational variants that are joined by tilt boundaries will be present. Diffraction techniques to determine crystallographic alignment and epitaxial variants are discussed, and transmission electron microscopy studies to investigate extended defects in the thin films will also be reviewed. The authors end with open problems in this field regarding the structure of oxide interfaces that can be topics for future research.

  9. Hysteresis-free high rate reactive sputtering of niobium oxide, tantalum oxide, and aluminum oxide

    SciTech Connect (OSTI)

    Särhammar, Erik, E-mail: erik.sarhammar@angstrom.uu.se; Berg, Sören; Nyberg, Tomas [Department of Solid State Electronics, The Ångström Laboratory, Uppsala University, Box 534, SE-751 21 Uppsala (Sweden)

    2014-07-01T23:59:59.000Z

    This work reports on experimental studies of reactive sputtering from targets consisting of a metal and its oxide. The composition of the targets varied from pure metal to pure oxide of Al, Ta, and Nb. This combines features from both the metal target and oxide target in reactive sputtering. If a certain relation between the metal and oxide parts is chosen, it may be possible to obtain a high deposition rate, due to the metal part, and a hysteresis-free process, due to the oxide part. The aim of this work is to quantify the achievable boost in oxide deposition rate from a hysteresis-free process by using a target consisting of segments of a metal and its oxide. Such an increase has been previously demonstrated for Ti using a homogeneous substoichiometric target. The achievable gain in deposition rate depends on transformation mechanisms from oxide to suboxides due to preferential sputtering of oxygen. Such mechanisms are different for different materials and the achievable gain is therefore material dependent. For the investigated materials, the authors have demonstrated oxide deposition rates that are 1.5–10 times higher than what is possible from metal targets in compound mode. However, although the principle is demonstrated for oxides of Al, Ta, and Nb, a similar behavior is expected for most oxides.

  10. Microstructure of amorphous indium oxide and tin oxide thin films

    SciTech Connect (OSTI)

    Rauf, I.A.; Brown, L.M. (Univ. of Cambridge (United Kingdom))

    1994-03-15T23:59:59.000Z

    Indium oxide, tin oxide, and some other doped and undoped oxide semiconductors show an interesting and technologically important combination of properties. They have high luminous transparency, good electrical conductivity and high infrared reflectivity. Numerous techniques for depositing these materials have been developed and have undergone a number of changes during last two decades. An understanding of the basic physics of these materials has begun to dawn. Most of the literature on transparent conducting oxides consists of studying the dependence of the properties on the composition, preparation conditions, such as deposition rate, substrate temperature or post-deposition heat treatment. In this paper the authors have employed the transmission electron microscopy to study the microstructure of reactively evaporated, electron beam evaporated, ion-beam sputtered amorphous indium oxide and reactively evaporated amorphous tin oxide thin films. These films, which have received little attention in the past, can have enormous potential as transparent conductive coatings on heat-sensitive substrates and inexpensive solar cells.

  11. Oxidative stress and oxidative damage in chemical carcinogenesis

    SciTech Connect (OSTI)

    Klaunig, James E., E-mail: jklauni@indiana.edu; Wang Zemin; Pu Xinzhu; Zhou Shaoyu

    2011-07-15T23:59:59.000Z

    Reactive oxygen species (ROS) are induced through a variety of endogenous and exogenous sources. Overwhelming of antioxidant and DNA repair mechanisms in the cell by ROS may result in oxidative stress and oxidative damage to the cell. This resulting oxidative stress can damage critical cellular macromolecules and/or modulate gene expression pathways. Cancer induction by chemical and physical agents involves a multi-step process. This process includes multiple molecular and cellular events to transform a normal cell to a malignant neoplastic cell. Oxidative damage resulting from ROS generation can participate in all stages of the cancer process. An association of ROS generation and human cancer induction has been shown. It appears that oxidative stress may both cause as well as modify the cancer process. Recently association between polymorphisms in oxidative DNA repair genes and antioxidant genes (single nucleotide polymorphisms) and human cancer susceptibility has been shown.

  12. Oxidation resistant alloys, method for producing oxidation resistant alloys

    DOE Patents [OSTI]

    Dunning, John S. (Corvallis, OR); Alman, David E. (Salem, OR)

    2002-11-05T23:59:59.000Z

    A method for producing oxidation-resistant austenitic alloys for use at temperatures below 800.degree. C. comprising of: providing an alloy comprising, by weight %: 14-18% chromium, 15-18% nickel, 1-3% manganese, 1-2% molybdenum, 2-4% silicon, 0% aluminum and the balance being iron; heating the alloy to 800.degree. C. for between 175-250 hours prior to use in order to form a continuous silicon oxide film and another oxide film. The method provides a means of producing stainless steels with superior oxidation resistance at temperatures above 700.degree. C. at a low cost

  13. Oxidation resistant alloys, method for producing oxidation resistant alloys

    DOE Patents [OSTI]

    Dunning, John S.; Alman, David E.

    2002-11-05T23:59:59.000Z

    A method for producing oxidation-resistant austenitic alloys for use at temperatures below 800 C. comprising of: providing an alloy comprising, by weight %: 14-18% chromium, 15-18% nickel, 1-3% manganese, 1-2% molybdenum, 2-4% silicon, 0% aluminum and the balance being iron; heating the alloy to 800 C. for between 175-250 hours prior to use in order to form a continuous silicon oxide film and another oxide film. The method provides a means of producing stainless steels with superior oxidation resistance at temperatures above 700 C. at a low cost

  14. Zinc oxide varistors and/or resistors

    DOE Patents [OSTI]

    Arnold, Jr., Wesley D. (Oak Ridge, TN); Bond, Walter D. (Knoxville, TN); Lauf, Robert J. (Oak Ridge, TN)

    1993-01-01T23:59:59.000Z

    Varistors and/or resistors that includes doped zinc oxide gel microspheres. The doped zinc oxide gel microspheres preferably have from about 60 to about 95% by weight zinc oxide and from about 5 to about 40% by weight dopants based on the weight of the zinc oxide. The dopants are a plurality of dopants selected from silver salts, boron oxide, silicon oxide and hydrons oxides of aluminum, bismuth, cobalt, chromium, manganese, nickel, and antimony.

  15. Zinc oxide varistors and/or resistors

    DOE Patents [OSTI]

    Arnold, W.D. Jr.; Bond, W.D.; Lauf, R.J.

    1993-07-27T23:59:59.000Z

    Varistors and/or resistors are described that include doped zinc oxide gel microspheres. The doped zinc oxide gel microspheres preferably have from about 60 to about 95% by weight zinc oxide and from about 5 to about 40% by weight dopants based on the weight of the zinc oxide. The dopants are a plurality of dopants selected from silver salts, boron oxide, silicon oxide and hydrons oxides of aluminum, bismuth, cobalt, chromium, manganese, nickel, and antimony.

  16. Effect of interfacial oxide layers on the current-voltage characteristics of Al-Si contacts 

    E-Print Network [OSTI]

    Nishizono, Taira

    1976-01-01T23:59:59.000Z

    etched using a photolithographic technique. Aluminum was evaporated on the wafers, making the silicon surfaces highly reflective, and a Varian k ? Scope Interferometer was used. The microscopic view through the interferometer, simulated in Fig. 3. 1...-insulator-semiconductor 9 contact. 3 ' 1 Oxide thickness measurement. 0 3. 2 Growth of oxide film ( ? 400A) on silicon. Growth of oxide film ( 200)() on silicon. 3. 4 MOS capacitance structure. 3 ' 5 Capacitance ? voltage curves on MOS. 3. 6 Simplified schematic of C...

  17. ARM - Oxides of Nitrogen

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadap Documentation TDMADAP : XDCnarrowbandheat fluxChinaNews : AMFAlaskaNewsOxides of Nitrogen

  18. Enhanced Thermal Conductivity Oxide Fuels

    SciTech Connect (OSTI)

    Alvin Solomon; Shripad Revankar; J. Kevin McCoy

    2006-01-17T23:59:59.000Z

    the purpose of this project was to investigate the feasibility of increasing the thermal conductivity of oxide fuels by adding small fractions of a high conductivity solid phase.

  19. Continuous lengths of oxide superconductors

    DOE Patents [OSTI]

    Kroeger, Donald M. (Knoxville, TN); List, III, Frederick A. (Andersonville, TN)

    2000-01-01T23:59:59.000Z

    A layered oxide superconductor prepared by depositing a superconductor precursor powder on a continuous length of a first substrate ribbon. A continuous length of a second substrate ribbon is overlaid on the first substrate ribbon. Sufficient pressure is applied to form a bound layered superconductor precursor powder between the first substrate ribbon and the second substrate ribbon. The layered superconductor precursor is then heat treated to establish the oxide superconducting phase. The layered oxide superconductor has a smooth interface between the substrate and the oxide superconductor.

  20. Buried oxide layer in silicon

    DOE Patents [OSTI]

    Sadana, Devendra Kumar (Pleasantville, NY); Holland, Orin Wayne (Lenoir, TN)

    2001-01-01T23:59:59.000Z

    A process for forming Silicon-On-Insulator is described incorporating the steps of ion implantation of oxygen into a silicon substrate at elevated temperature, ion implanting oxygen at a temperature below 200.degree. C. at a lower dose to form an amorphous silicon layer, and annealing steps to form a mixture of defective single crystal silicon and polycrystalline silicon or polycrystalline silicon alone and then silicon oxide from the amorphous silicon layer to form a continuous silicon oxide layer below the surface of the silicon substrate to provide an isolated superficial layer of silicon. The invention overcomes the problem of buried isolated islands of silicon oxide forming a discontinuous buried oxide layer.

  1. Using CrAIN Multilayer Coatings to Improve Oxidation Resistance of Steel Interconnects for Solid Oxide Fuel Cell Stacks

    SciTech Connect (OSTI)

    Smith, Richard J.; Tripp, C.; Knospe, Anders; Ramana, C. V.; Gorokhovsky, Vladimir I.; Shutthanandan, V.; Gelles, David S.

    2004-06-01T23:59:59.000Z

    The requirements of low cost and high-tempurature corrosion resistance for bipolar interconnect plates in solid oxide fuel cell stacks has directed attention to the use of metal plates with oxidation resistant coatings. We have investigatedt he performance of steel plates with multilayer coatings consisting of CrN for electrical conductivity and CrAIN for oxidation resistance. The coatings were deposited usin large area filterd arc deposition technolgy, and subsequently annealed in air for up to 25 hours at 800 degrees celsius. The composition, structer and morphology of the coated plates were characterized using RBS, nuclear reaction analysis, AFM and TEM techniques. By altering the architecture of the layers within the coatings, the rate of oxidation was reduced by more than an order of magnitute. Electrical resistance was measured at room temperature.

  2. Operation of staged membrane oxidation reactor systems

    DOE Patents [OSTI]

    Repasky, John Michael

    2012-10-16T23:59:59.000Z

    A method of operating a multi-stage ion transport membrane oxidation system. The method comprises providing a multi-stage ion transport membrane oxidation system with at least a first membrane oxidation stage and a second membrane oxidation stage, operating the ion transport membrane oxidation system at operating conditions including a characteristic temperature of the first membrane oxidation stage and a characteristic temperature of the second membrane oxidation stage; and controlling the production capacity and/or the product quality by changing the characteristic temperature of the first membrane oxidation stage and/or changing the characteristic temperature of the second membrane oxidation stage.

  3. Low Temperature Constrained Sintering of Cerium Gadolinium Oxide Films for Solid Oxide Fuel Cell Applications

    E-Print Network [OSTI]

    Nicholas, Jason.D.

    2007-01-01T23:59:59.000Z

    Temperature Solid Oxide Fuel Cells, In: S.C. Singhal and M.Tubular Solid Oxide Fuel Cell Technology, U.S. Department ofOxide Films for Solid Oxide Fuel Cell Applications by Jason

  4. Stability of catalase and its role in lipid oxidation in beef muscle

    E-Print Network [OSTI]

    Pradhan, Abhijeet Amar

    1997-01-01T23:59:59.000Z

    lowered lipid oxidation (as measured by 2-thiobarbituric acid-reactive substances, TBARS) about 8% in the 6 days of storage. When 3-aniino-1,2,4-triazole (2.5%), a catalase inhibitor, was added to ground beef SM, lipid oxidation (peroxide values) was also...

  5. OH-initiated oxidation of benzene Part I. Phenol formation under atmospheric conditions

    E-Print Network [OSTI]

    OH-initiated oxidation of benzene Part I. Phenol formation under atmospheric conditions Rainer-radical initiated oxidation of benzene was studied in two simulation chambers: (1) the large-volume outdoor chamber-red spectroscopy (FTIR) were used to simultaneously measure phenol and benzene. The second study used only FTIR

  6. Different Approach to the Aluminium Oxide Topography Characterisation

    SciTech Connect (OSTI)

    Poljacek, Sanja Mahovic; Gojo, Miroslav [Faculty of Graphic Arts, University of Zagreb, Getaldiceva 2, 10000 Zagreb (Croatia); Raos, Pero; Stoic, Antun [Mechanical Engineering Faculty, J.J. Strossmayer University of Osijek, Trg Ivane Brlic Mazuranic 2, 35000 Slavonski Brod (Croatia)

    2007-04-07T23:59:59.000Z

    Different surface topographic techniques are being widely used for quantitative measurements of typical industrial aluminium oxide surfaces. In this research, specific surface of aluminium oxide layer on the offset printing plate has been investigated by using measuring methods which have previously not been used for characterisation of such surfaces. By using two contact instruments and non-contact laser profilometer (LPM) 2D and 3D roughness parameters have been defined. SEM micrographs of the samples were made. Results have shown that aluminium oxide surfaces with the same average roughness value (Ra) and mean roughness depth (Rz) typically used in the printing plate surface characterisation, have dramatically different surface topographies. According to the type of instrument specific roughness parameters should be used for defining the printing plate surfaces. New surface roughness parameters were defined in order to insure detailed characterisation of the printing plates in graphic reproduction process.

  7. P-31 / Schlott P-31: Nodule Formation on Indium-Oxide Tin-Oxide

    E-Print Network [OSTI]

    P-31 / Schlott P-31: Nodule Formation on Indium-Oxide Tin-Oxide Sputtering Targets M. Schlott, M from indium-oxide tin-oxide (ITO) targets [1]. Unfor- tunately, black growths, or nodules, commonly isostatic pressing partly reduced powder mixtures of 90 wt.% indium-oxide and 10 wt.% tin-oxide [4

  8. Metal oxide films on metal

    DOE Patents [OSTI]

    Wu, Xin D. (Los Alamos, NM); Tiwari, Prabhat (Los Alamos, NM)

    1995-01-01T23:59:59.000Z

    A structure including a thin film of a conductive alkaline earth metal oxide selected from the group consisting of strontium ruthenium trioxide, calcium ruthenium trioxide, barium ruthenium trioxide, lanthanum-strontium cobalt oxide or mixed alkaline earth ruthenium trioxides thereof upon a thin film of a noble metal such as platinum is provided.

  9. Detection of oxidation in human serum lipoproteins 

    E-Print Network [OSTI]

    Myers, Christine Lee

    2006-04-12T23:59:59.000Z

    A method for the oxidation of lipoproteins in vitro was developed using the free radical initiator, 2,2?-azobis-(2-amidinopropane) dihydrochloride (AAPH). Following in vitro oxidation, the susceptibility to oxidation of ...

  10. Electronic and Magnetization Dynamics of Cobalt Substituted Iron Oxide Nanocrystals 

    E-Print Network [OSTI]

    Chen, Tai-Yen

    2011-02-22T23:59:59.000Z

    of photoexcited colloidal cobalt substituted iron oxide nanocrystals, CoxFe3-xO4, were investigated through transient absorption and pump-probe Faraday rotation measurements. In this dissertation, linearly polarized femtosecond optical pulses at 780 nm were used...

  11. Electronically conductive ceramics for high temperature oxidizing environments

    DOE Patents [OSTI]

    Kucera, G.H.; Smith, J.L.; Sim, J.W.

    1983-11-10T23:59:59.000Z

    This invention pertains to a high temperature, ceramic composition having electronic conductivity as measured by resistivity below about 500 ohm-cm, chemical stability particularly with respect to cathode conditions in a molten carbonate fuel cell, and composed of an alkali metal, transition metal oxide containing a dopant metal in the crystalline structure to replace a portion of the alkali metal or transition metal.

  12. Spectroscopic Characterization of a Multiband Complex Oxide:...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a Multiband Complex Oxide: Insulating and Conducting Cement 12CaO·7AlO. Spectroscopic Characterization of a Multiband Complex Oxide: Insulating and Conducting Cement...

  13. New manganese catalyst for light alkane oxidation

    DOE Patents [OSTI]

    Durante, Vincent A. (West Chester, PA); Lyons, James E. (Wallingford, PA); Walker, Darrell W. (Visalia, CA); Marcus, Bonita K. (Radnor, PA)

    1994-01-01T23:59:59.000Z

    Aluminophosphates containing manganese in the structural framework are employed for the oxidation of alkanes, for example the vapor phase oxidation of methane to methanol.

  14. Precise Application of Transparent Conductive Oxide Coatings...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Application of Transparent Conductive Oxide Coatings for Flat Panel Displays and Photovoltaic Cells Technology available for licensing: New transparent conducting oxide (TCO)...

  15. Chapter 6: Thallium-Oxide Superconductors

    SciTech Connect (OSTI)

    Bhattacharya, R. N.

    2010-01-01T23:59:59.000Z

    This chapter has 2 sections titled: (1) Spray-Deposited, TI-Oxide Films, and (2) Electrodeposited Ti-Oxide Superconductors.

  16. Manganese Oxide Composite Electrodes for Lithium Batteries |...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Manganese Oxide Composite Electrodes for Lithium Batteries Technology available for licensing: Improved spinel-containing "layered-layered" lithium metal oxide electrodes Materials...

  17. XPS Determination of Uranium Oxidations States. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    extent, are relatively insensitive to compositionstructure within the oxide-hydroxide-hydrate system and can be used to both identify and help quantify U oxidation states in mixed...

  18. Ethanol oxidation on metal oxide-supported platinum catalysts

    SciTech Connect (OSTI)

    L. M. Petkovic 090468; Sergey N. Rashkeev; D. M. Ginosar

    2009-09-01T23:59:59.000Z

    Ethanol is a renewable fuel that can be used as an additive to gasoline (or its substitute) with the advantage of octane enhancement and reduced carbon monoxide exhaust emissions. However, on Ethanol is a renewable fuel that can be used as an additive to gasoline (or its substitute) with the advantage of octane enhancement and reduced carbon monoxide exhaust emissions. However, on the standard three-way catalysts, the conversion of unburned ethanol is low because both ethanol and some of its partially oxidized derivatives are highly resistant to oxidation. A combination of first-principles density-functional theory (DFT) based calculations and in-situ diffuse reflectance infrared spectroscopy (DRIFTS) analysis was applied to uncover some of the fundamental phenomena associated with ethanol oxidation on Pt containing catalysts. In particular, the objective was to analyze the role of the oxide (i.e., ?-Al2O3 or SiO2) substrate on the ethanol oxidation activity. The results showed that Pt nanoparticles trap and accumulate oxygen at their surface and perimeter sites and play the role of “stoves” that burn ethanol molecules and their partially oxidized derivatives to the “final” products. The ?-Al2O3 surfaces provided higher mobility of the fragments of ethanol molecules than the SiO2 surface and hence increased the supply rate of these objects to the Pt particles. This will in turn produce a higher conversion rate of unburned ethanol.and some of its partially oxidized derivatives are highly resistant to oxidation. A combination of first-principles density-functional theory (DFT) based calculations and in-situ diffuse reflectance infrared spectroscopy (DRIFTS) analysis was applied to uncover some of the fundamental phenomena associated with ethanol oxidation on Pt containing catalysts. In particular, the objective was to analyze the role of the oxide (i.e., ?-Al2O3 or SiO2) substrate on the ethanol oxidation activity. The results showed that Pt nanoparticles trap and accumulate oxygen at their surface and perimeter sites and play the role of “stoves” that burn ethanol molecules and their partially oxidized derivatives to the “final” products. The ?-Al2O3 surfaces provided higher mobility of the fragments of ethanol molecules than the SiO2 surface and hence increased the supply rate of these objects to the Pt particles. This will in turn produce a higher conversion rate of unburned ethanol.

  19. High temperature oxidation behavior of Fe-Cr-Al foils

    SciTech Connect (OSTI)

    Chang, C.S.; Jha, B. [Texas Instruments, Inc., Attleboro, MA (United States)

    1998-12-31T23:59:59.000Z

    Metallic catalytic converters for automotive emission control is becoming an important application for heat resistant alloys as more design opportunities are realized. The service conditions and design of metallic catalytic converters require the alloy to be highly oxidation resistant at gauges typically at 50 microns or less. For conventional heat resistant alloy design the goal is to form a well adherent scale on the alloy surface to protect the alloy matrix from being oxidized. However, the thin gauge results in a limited supply of alloying elements that can form the protective scale on the surface. The alloy chemistry has to be optimized to have the minimum oxidation while maintaining processing characteristics. Furthermore, the ratio of scale thickness to foil gauge is significant and the stress state between them introduces measurable permanent distortion of the foil. In this study, the effect of alloying elements on the oxidation behavior of commonly used Fe-Cr-Al alloys was quantified by the oxidation weight gain and length change measurements.

  20. Electrical properties and defect structures of praseodymium-cerium oxide solid solutions

    E-Print Network [OSTI]

    Stefanik, Todd Stanley, 1973-

    2004-01-01T23:59:59.000Z

    A defect chemistry model consistent with observed trends in the pO2 and temperature dependence of electrical conductivity in praseodymium cerium oxide (PCO) was developed. Four point DC conductivity measurements were made ...

  1. The variability of methane, nitrous oxide and sulfur hexafluoride in Northeast India

    E-Print Network [OSTI]

    Chatterjee, A.

    High-frequency atmospheric measurements of methane (CH[subscript 4]), nitrous oxide (N[subscript 2]O) and sulfur hexafluoride (SF[subscript 6]) from Darjeeling, India are presented from December 2011 (CH[subscript 4])/March ...

  2. Femtosecond pump-probe studies of reduced graphene oxide thin films

    E-Print Network [OSTI]

    Ruzicka, Brian Andrew; Werake, Lalani Kumari; Zhao, Hui; Wang, Shuai; Loh, Kian Ping

    2010-04-01T23:59:59.000Z

    The dynamics of photocarriers in reduced graphene oxide thin films is studied by using ultrafast pump-probe spectroscopy. Time dependent differential transmissions are measured with sample temperatures ranging from 9 to 300 K. At each sample...

  3. Variations in organic aerosol optical and hygroscopic properties upon heterogeneous OH oxidation

    E-Print Network [OSTI]

    Cappa, Christopher D.

    Measurements of the evolution of organic aerosol extinction cross sections (?[subscript ext]) and subsaturated hygroscopicity upon heterogeneous OH oxidation are reported for two model compounds, squalane (a C30 saturated ...

  4. Robust Nitrogen Oxide/Ammonia Sensors for Vehicle On-board Emissions...

    Broader source: Energy.gov (indexed) [DOE]

    2014: Robust Nitrogen oxideAmmonia Sensors for Vehicle on-board Emissions Control CumminsORNL-FEERC CRADA: NOx Control & Measurement Technology for Heavy-Duty Diesel Engines...

  5. Evaluation of Residual Stress Levels in Plasma Electrolytic Oxidation Coatings using a Curvature Method

    E-Print Network [OSTI]

    Dean, J.; Gu, T.; Clyne, T. W.

    2014-11-09T23:59:59.000Z

    Experimental estimates have been made of typical levels of residual stress in plasma electrolytic oxidation (PEO) coatings formed on aluminium and magnesium alloy substrates. This has been done via measurement of the curvature exhibited by thin...

  6. Quantitative NDA Measurements of Advanced Reprocessing Product Materials Containing U, NP, PU, and AM

    E-Print Network [OSTI]

    Goddard, Braden

    2013-04-05T23:59:59.000Z

    of this first principle technique have been identified: (1) quantitative measurement of uranium, neptunium, plutonium, and americium materials; (2) quantitative measurement of mixed oxide (MOX) materials; (3) quantitative measurement of uranium materials; and (4...

  7. Impact of Biodiesel on the Oxidation Kinetics and Morphology of Diesel Particulate

    SciTech Connect (OSTI)

    Strzelec, Andrea [ORNL] [ORNL; Toops, Todd J [ORNL] [ORNL; Daw, C Stuart [ORNL] [ORNL

    2011-01-01T23:59:59.000Z

    We compare the oxidation characteristics of four different diesel particulates generated with a modern light-duty engine. The four particulates represent engine fueling with conventional ultra-low sulfur diesel (ULSD), biodiesel, and two intermediate blends of these fuels. The comparisons discussed here are based on complementary measurements implemented in a laboratory micro-reactor, including temperature programmed desorption and oxidation, pulsed isothermal oxidation, and BET surface area. From these measurements we have derived models that are consistent with the observed oxidation reactivity differences. When accessible surface area effects are properly accounted for, the oxidation kinetics of the fixed carbon components were found to consistently exhibit an Arrhenius activation energy of 113 6 kJ/mol. Release of volatile carbon from the as-collected particulate appears to follow a temperaturedependent rate law.

  8. Investigation of Mixed Oxide Catalysts for NO Oxidation

    SciTech Connect (OSTI)

    Szanyi, Janos; Karim, Ayman M.; Pederson, Larry R.; Kwak, Ja Hun; Mei, Donghai; Tran, Diana N.; Herling, Darrell R.; Muntean, George G.; Peden, Charles HF; Howden, Ken; Qi, Gongshin; Li, Wei

    2014-12-09T23:59:59.000Z

    The oxidation of engine-generated NO to NO2 is an important step in the reduction of NOx in lean engine exhaust because NO2 is required for the performance of the LNT technology [2], and it enhances the activities of ammonia selective catalytic reduction (SCR) catalysts [1]. In particular, for SCR catalysts an NO:NO2 ratio of 1:1 is most effective for NOx reduction, whereas for LNT catalysts, NO must be oxidized to NO2 before adsorption on the storage components. However, NO2 typically constitutes less than 10% of NOx in lean exhaust, so catalytic oxidation of NO is essential. Platinum has been found to be especially active for NO oxidation, and is widely used in DOC and LNT catalysts. However, because of the high cost and poor thermal durability of Pt-based catalysts, there is substantial interest in the development of alternatives. The objective of this project, in collaboration with partner General Motors, is to develop mixed metal oxide catalysts for NO oxidation, enabling lower precious metal usage in emission control systems. [1] M. Koebel, G. Madia, and M. Elsener, Catalysis Today 73, 239 (2002). [2] C. H. Kim, G. S. Qi, K. Dahlberg, and W. Li, Science 327, 1624 (2010).

  9. Measurement of nitric oxide with an antimonide diode laser

    E-Print Network [OSTI]

    lasers while retaining the practical advantages of room- temperature or thermoelectrically cooled E-11, Santa Fe, New Mexico 87505. Rece

  10. Compositional Tuning of Ultrathin Surface Oxides on Metal and...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    that the native oxide on 5%Ni-Al alloy is primarily composed of aluminum oxide with no nickel oxide whereas the photon-assisted oxide comprises of both aluminum oxide and nickel...

  11. Structure of graphene oxide dispersed with ZnO nanoparticles

    SciTech Connect (OSTI)

    Yadav, Rishikesh, E-mail: rishikesh.yadav62@gmail.com; Pandey, Devendra K., E-mail: devendrakphy@gmail.com [School of Nanotechnology, Rajiv Gandhi Proudyogiki Vishwavidalaya, Bhopal, M.P. (India); Khare, P. S., E-mail: purnimaswarup@hotmail.com [Department of Physics, Rajiv Gandhi Proudyogiki Vishwavidalaya, Bhopal M.P. (India)

    2014-10-15T23:59:59.000Z

    Graphene has been proposed as a promising two-dimensional nanomaterial with outstanding electronic, optical, thermal and mechanical properties for many applications. In present work a process of dispersion of graphene oxide with ZnO nanoparticles in ethanol solution with different pH values, have been studied. Samples have been characterized by XRD, SEM, PL, UV-visible spectroscopy and particles size measurement. The results analysis indicates overall improved emission spectrum. It has been observed that the average diameter of RGO (Reduced Graphene Oxide) decreases in presence of ZnO nanoparticles from 3.8?m to 0.41?m.

  12. Oxides having high energy densities

    DOE Patents [OSTI]

    Ceder, Gerbrand; Kang, Kisuk

    2013-09-10T23:59:59.000Z

    Certain disclosed embodiments generally relate to oxide materials having relatively high energy and/or power densities. Various aspects of the embodiments are directed to oxide materials having a structure B.sub.i(M.sub.jY.sub.k)O.sub.2, for example, a structure Li.sub.j(Ni.sub.jY.sub.k)O.sub.2 such as Li(Ni.sub.0.5Mn.sub.0.5)O.sub.2. In this structure, Y represents one or more atoms, each independently selected from the group consisting of alkaline earth metals, transition metals, Group 14 elements, Group 15, or Group 16 elements. In some embodiments, such an oxide material may have an O3 crystal structure, and/or a layered structure such that the oxide comprises a plurality of first, repeating atomic planes comprising Li, and a plurality of second, repeating atomic planes comprising Ni and/or Y.

  13. Thermal oxidation procedure PREPARATION........................................................................................................................................... 2

    E-Print Network [OSTI]

    Hochberg, Michael

    procedure - 2 - Preparation. The preparation procedure sets up the power, gas supplies, cooling water, (DI to check all the supplies. Cooling water Gas supplies Routing DI water for wet oxidation We start........................................................................................................................................... 2 Step 1 Turn on the cooling water

  14. Study of O/Ni(100) with LEED (low-energy electron diffraction) and AES (auger electron spectroscopy) from chemisorption to oxidation

    SciTech Connect (OSTI)

    Wang, Wen-Di.

    1990-11-16T23:59:59.000Z

    The structures formed on the Ni(100) surface during oxygen adsorption, leading to oxidation, are studied with Video-LEED (low-energy electron diffraction) and AES (Auger electron spectroscopy). The temperature- and exposure-dependence in the development of LEED patterns observed during oxidation of Ni(100), at oxidation temperatures of 80 to 400 K, are investigated extensively. Integrated diffraction spot intensities and fractional spot profiles are measured quantitatively and continuously, allowing unambiguous correlation of various surface processes. AES is used to measure the oxidation onset during adsorption and the final relative thickness of the oxide. 48 figs., 79 refs.

  15. Surface Properties of Photo-Oxidized Bituminous Coals: Final report

    SciTech Connect (OSTI)

    NONE

    1998-09-01T23:59:59.000Z

    Natural weathering has a detrimental effect on the hydrophobic nature of coal, which in turn can influence clean-coal recovery during flotation. Few techniques are available that can establish the quality of coal surfaces and that have a short analysis time to provide input for process control. Luminescence emissions which can be quantified with an optical microscope and photometer system, are measurably influenced by degree of weathering as well as by mild storage deterioration. In addition, it has been shown that when vitrinite is irradiated with a relatively high intensity flux of violet- or ultraviolet- light in the presence of air, photo-oxidation of the surface occurs. The combination of measuring the change in luminescence emission intensity with degree of surface oxidation provided the impetus for the current investigation. The principal aim of this research was to determine whether clear correlations could be established among surface oxygen functionality, hydrophobicity induced by photo-oxidation, and measurements of luminescence intensity and alteration. If successful, the project would result in quantitative luminescence techniques based on optical microscopy that would provide a measure of the changes in surface properties as a function of oxidation and relate them to coal cleanability. Two analytical techniques were designed to achieve these goals. Polished surfaces of vitrain bands or a narrow size fraction of powdered vitrain concentrates were photo-oxidized using violet or ultraviolet light fluxes and then changes in surface properties and chemistry were measured using a variety of near-surface analytical techniques. Results from this investigation demonstrate that quantitative luminescence intensity measurements can be performed on fracture surfaces of bituminous rank coals (vitrains) and that the data obtained do reveal significant variations depending upon the level of surface oxidation. Photo-oxidation induced by violet or ultraviolet light fluxes does result in a progressive and significant increase in the amount of near-surface oxygen concentration at about the same level regardless of bituminous coal rank. These incremental changes in oxygen concentration appear to lower the hydrophobicity as shown by contact angle measurements on polished surfaces. Although this influence diminished as coal rank increased, the level of oxygen uptake was about the same, suggesting that the type of oxygen functionality formed during oxidation may be of great importance in modifying surface hydrophobicity. Changes in functional-group chemistry, measured by a variety of near-surface techniques, showed a general increase in the concentration of carbonyl-containing groups while those of CH{sub 2} groups decreased. All of these observations follow the trends observed in previous investigations of naturally weathered coals. The photo-oxidation technique also resulted in the development of phenolic, ester and anhydride moieties instead of the expected emplacement of carboxylic acid groups which are normally associated with naturally weathered coals. The importance of this observation is that esters and anhydrides would result in a more hydrophobic surface in comparison to the more hydrophilic surface resulting from acid functionality. This observation is consistent with the results of film flotation of UV-irradiated powdered vitrain in which floatability was generally observed to increase with increasing photo- oxidation.

  16. The catalytic oxidation of propane 

    E-Print Network [OSTI]

    Sanderson, Charles Frederick

    1949-01-01T23:59:59.000Z

    THE CATALYTIC OXIDATION OP PROPANE A Thesis By Charles Frederick Sandersont * * June 1949 Approval as to style and content recommended: Head of the Department of Chemical Engineering THE CATALYTICi OXIDATTON OF PROPANE A Thesis By Charles... Frederick ;Sandersonit * June 1949 THE CATALYTIC OXIDATION OP PROPANE A Thesis Submitted to the Faculty of the Agricultural and Mechanical College of Texas in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy Major...

  17. The catalytic oxidation of propane

    E-Print Network [OSTI]

    Sanderson, Charles Frederick

    1949-01-01T23:59:59.000Z

    THE CATALYTIC OXIDATION OP PROPANE A Thesis By Charles Frederick Sandersont * * June 1949 Approval as to style and content recommended: Head of the Department of Chemical Engineering THE CATALYTICi OXIDATTON OF PROPANE A Thesis By Charles... Frederick ;Sandersonit * June 1949 THE CATALYTIC OXIDATION OP PROPANE A Thesis Submitted to the Faculty of the Agricultural and Mechanical College of Texas in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy Major...

  18. Metal oxide nanostructures with hierarchical morphology

    DOE Patents [OSTI]

    Ren, Zhifeng (Newton, MA); Lao, Jing Yu (Saline, MI); Banerjee, Debasish (Ann Arbor, MI)

    2007-11-13T23:59:59.000Z

    The present invention relates generally to metal oxide materials with varied symmetrical nanostructure morphologies. In particular, the present invention provides metal oxide materials comprising one or more metallic oxides with three-dimensionally ordered nanostructural morphologies, including hierarchical morphologies. The present invention also provides methods for producing such metal oxide materials.

  19. In situ reduction and oxidation of nickel from solid oxide fuel cells in a Titan ETEM

    E-Print Network [OSTI]

    Dunin-Borkowski, Rafal E.

    In situ reduction and oxidation of nickel from solid oxide fuel cells in a Titan ETEM A. Faes1, Denmark antonin.faes@epfl.ch Keywords: In situ ETEM, nickel oxide, reduction, RedOx, SOFC Solid Oxide Fuel. C. Singhal, K. Kendall, High Temperature Solid Oxide Fuel Cell - Fundamentals, Design

  20. Millisecond Oxidation of Alkanes

    SciTech Connect (OSTI)

    Scott Han

    2011-09-30T23:59:59.000Z

    This project was undertaken in response to the Department of Energy's call to research and develop technologies 'that will reduce energy consumption, enhance economic competitiveness, and reduce environmental impacts of the domestic chemical industry.' The current technology at the time for producing 140 billion pounds per year of propylene from naphtha and Liquified Petroleum Gas (LPG) relied on energy- and capital-intensive steam crackers and Fluidized Catalytic Cracking (FCC) units. The propylene is isolated from the product stream in a costly separation step and subsequently converted to acrylic acid and other derivatives in separate production facilities. This project proposed a Short Contact Time Reactor (SCTR)-based catalytic oxydehydrogenation process that could convert propane to propylene and acrylic acid in a cost-effective and energy-efficient fashion. Full implementation of this technology could lead to sizeable energy, economic and environmental benefits for the U. S. chemical industry by providing up to 45 trillion BTUs/year, cost savings of $1.8 billion/year and a combined 35 million pounds/year reduction in environmental pollutants such as COx, NOx, and SOx. Midway through the project term, the program directive changed, which approval from the DOE and its review panel, from direct propane oxidation to acrylic acid at millisecond contact times to a two-step process for making acrylic acid from propane. The first step was the primary focus, namely the conversion of propane to propylene in high yields assisted by the presence of CO2. The product stream from step one was then to be fed directly into a commercially practiced propylene-to-acrylic acid tandem reactor system.

  1. Transparent conducting oxides and production thereof

    SciTech Connect (OSTI)

    Gessert, Timothy A.; Yoshida, Yuki; Coutts, Timothy J.

    2014-06-10T23:59:59.000Z

    Transparent conducting oxides and production thereof are disclosed. An exemplary method of producing a transparent conducting oxide (TCO) material may comprise: providing a TCO target doped with either a high-permittivity oxide or a low-permittivity oxide in a process chamber. The method may also comprise depositing a metal oxide on the target in the process chamber to form a thin film having enhanced optical properties without substantially decreasing electrical quality.

  2. Transparent conducting oxides and production thereof

    SciTech Connect (OSTI)

    Gessert, Timothy A; Yoshida, Yuki; Coutts, Timothy J

    2014-05-27T23:59:59.000Z

    Transparent conducting oxides and production thereof are disclosed. An exemplary method of producing a transparent conducting oxide (TCO) material may comprise: providing a TCO target (110) doped with either a high-permittivity oxide or a low-permittivity oxide in a process chamber (100). The method may also comprise depositing a metal oxide on the target (110) to form a thin film having enhanced optical properties without substantially decreasing electrical quality.

  3. Structural characterization of terrestrial microbial Mn oxides from Pinal Creek, AZ

    SciTech Connect (OSTI)

    Bargar, John; Fuller, Christopher; Marcus, Matthew A.; Brearley, Adrian J.; Perez De la Rosa, M.; Webb, Samuel M.; Caldwell, Wendel A.

    2008-03-19T23:59:59.000Z

    The microbial catalysis of Mn(II) oxidation is believed to be a dominant source of abundant sorption- and redox-active Mn oxides in marine, freshwater, and subsurface aquatic environments. In spite of their importance, environmental oxides of known biogenic origin have generally not been characterized in detail from a structural perspective. Hyporheic zone Mn oxide grain coatings at Pinal Creek, Arizona, a metals-contaminated stream, have been identified as being dominantly microbial in origin and are well studied from bulk chemistry and contaminant hydrology perspectives. This site thus presents an excellent opportunity to study the structures of terrestrial microbial Mn oxides in detail. XRD and EXAFS measurements performed in this study indicate that the hydrated Pinal Creek Mn oxide grain coatings are layer-type Mn oxides with dominantly hexagonal or pseudo-hexagonal layer symmetry. XRD and TEM measurements suggest the oxides to be nanoparticulate plates with average dimensions on the order of 11 nm thick x 35 nm diameter, but with individual particles exhibiting thickness as small as a single layer and sheets as wide as 500 nm. The hydrated oxides exhibit a 10-A basal-plane spacing and turbostratic disorder. EXAFS analyses suggest the oxides contain layer Mn(IV) site vacancy defects, and layer Mn(III) is inferred to be present, as deduced from Jahn-Teller distortion of the local structure. The physical geometry and structural details of the coatings suggest formation within microbial biofilms. The biogenic Mnoxides are stable with respect to transformation into thermodynamically more stable phases over a time scale of at least 5 months. The nanoparticulate layered structural motif, also observed in pure culture laboratory studies, appears to be characteristic of biogenic Mn oxides and may explain the common occurrence of this mineral habit in soils and sediments.

  4. On the Design of Oxide Films, Nanomaterials, and Heterostructures for Solar Water Oxidation Photoanodes

    E-Print Network [OSTI]

    Kronawitter, Coleman

    2012-01-01T23:59:59.000Z

    lower oxides of titanium, 25 this energy gap, as defined inlies at greater energies than reference titanium oxides. Thetitanium oxides have been comprehensively documented. 25,26,27,28 The two sets of local maxima over this energy

  5. Modelling of stable isotope fractionation by methane oxidation and diffusion in landfill cover soils

    SciTech Connect (OSTI)

    Mahieu, Koenraad [Laboratory of Applied Physical Chemistry (ISOFYS), Ghent University, Coupure links 653, B-9000 Ghent (Belgium); Department of Applied Mathematics, Biometrics and Process Control (BIOMATH), Ghent University, Coupure links 653, B-9000 Ghent (Belgium)], E-mail: Koenraad.mahieu@lid.kviv.be; De Visscher, Alex [Department of Chemical and Petroleum Engineering, Schulich School of Engineering, University of Calgary, 2500 University Drive N.W., Calgary, Alberta, T2N 1N4 (Canada); Vanrolleghem, Peter A. [Department of Applied Mathematics, Biometrics and Process Control (BIOMATH), Ghent University, Coupure links 653, B-9000 Ghent (Belgium); Department of Civil Engineering (modelEAU), Universite Laval, Pavillon Pouliot, Quebec, G1K 7P4 (Canada); Van Cleemput, Oswald [Laboratory of Applied Physical Chemistry (ISOFYS), Ghent University, Coupure links 653, B-9000 Ghent (Belgium)

    2008-07-01T23:59:59.000Z

    A technique to measure biological methane oxidation in landfill cover soils that is gaining increased interest is the measurement of stable isotope fractionation in the methane. Usually to quantify methane oxidation, only fractionation by oxidation is taken into account. Recently it was shown that neglecting the isotope fractionation by diffusion results in underestimation of the methane oxidation. In this study a simulation model was developed that describes gas transport and methane oxidation in landfill cover soils. The model distinguishes between {sup 12}CH{sub 4}, {sup 13}CH{sub 4}, and {sup 12}CH{sub 3}D explicitly, and includes isotope fractionation by diffusion and oxidation. To evaluate the model, the simulations were compared with column experiments from previous studies. The predicted concentration profiles and isotopic profiles match the measured ones very well, with a root mean square deviation (RMSD) of 1.7 vol% in the concentration and a RMSD of 0.8 per mille in the {delta}{sup 13}C value, with {delta}{sup 13}C the relative {sup 13}C abundance as compared to an international standard. Overall, the comparison shows that a model-based isotope approach for the determination of methane oxidation efficiencies is feasible and superior to existing isotope methods.

  6. Solid oxide electrochemical reactor science.

    SciTech Connect (OSTI)

    Sullivan, Neal P. (Colorado School of Mines, Golden, CO); Stechel, Ellen Beth; Moyer, Connor J. (Colorado School of Mines, Golden, CO); Ambrosini, Andrea; Key, Robert J. (Colorado School of Mines, Golden, CO)

    2010-09-01T23:59:59.000Z

    Solid-oxide electrochemical cells are an exciting new technology. Development of solid-oxide cells (SOCs) has advanced considerable in recent years and continues to progress rapidly. This thesis studies several aspects of SOCs and contributes useful information to their continued development. This LDRD involved a collaboration between Sandia and the Colorado School of Mines (CSM) ins solid-oxide electrochemical reactors targeted at solid oxide electrolyzer cells (SOEC), which are the reverse of solid-oxide fuel cells (SOFC). SOECs complement Sandia's efforts in thermochemical production of alternative fuels. An SOEC technology would co-electrolyze carbon dioxide (CO{sub 2}) with steam at temperatures around 800 C to form synthesis gas (H{sub 2} and CO), which forms the building blocks for a petrochemical substitutes that can be used to power vehicles or in distributed energy platforms. The effort described here concentrates on research concerning catalytic chemistry, charge-transfer chemistry, and optimal cell-architecture. technical scope included computational modeling, materials development, and experimental evaluation. The project engaged the Colorado Fuel Cell Center at CSM through the support of a graduate student (Connor Moyer) at CSM and his advisors (Profs. Robert Kee and Neal Sullivan) in collaboration with Sandia.

  7. Method for hot pressing beryllium oxide articles

    DOE Patents [OSTI]

    Ballard, Ambrose H. (Oak Ridge, TN); Godfrey, Jr., Thomas G. (Oak Ridge, TN); Mowery, Erb H. (Clinton, TN)

    1988-01-01T23:59:59.000Z

    The hot pressing of beryllium oxide powder into high density compacts with little or no density gradients is achieved by employing a homogeneous blend of beryllium oxide powder with a lithium oxide sintering agent. The lithium oxide sintering agent is uniformly dispersed throughout the beryllium oxide powder by mixing lithium hydroxide in an aqueous solution with beryllium oxide powder. The lithium hydroxide is converted in situ to lithium carbonate by contacting or flooding the beryllium oxide-lithium hydroxide blend with a stream of carbon dioxide. The lithium carbonate is converted to lithium oxide while remaining fixed to the beryllium oxide particles during the hot pressing step to assure uniform density throughout the compact.

  8. Oxidation reactions on neutral cobalt oxide clusters: experimental and theoretical studies

    E-Print Network [OSTI]

    Rocca, Jorge J.

    oxidation,24­41 nitrogen monoxide reduction and oxidation,24,36a,42­44 and Fischer­Tropsch reactions.45

  9. Influence of Ionic Surfactants on the Aggregation of Poly(Ethylene Oxide)-Poly(Propylene Oxide)-Poly(Ethylene Oxide) Block Copolymers Studied by Differential Scanning and

    E-Print Network [OSTI]

    Loh, Watson

    Influence of Ionic Surfactants on the Aggregation of Poly(Ethylene Oxide)-Poly(Propylene Oxide copolymers of poly(ethylene oxide) and poly(propylene oxide), EOnPOmEOn, and the ionic surfactants sodium the aggregates of all three polymers. Introduction Water-soluble poly(ethylene oxide)-poly(propylene oxide)- poly

  10. Using CrAIN Multilayer Coatings to Improve Oxidation Resistance...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coatings to Improve Oxidation Resistance of Steel Interconnects for Solid Oxide Fuel Cell Stacks. Using CrAIN Multilayer Coatings to Improve Oxidation Resistance of Steel...

  11. MICROSTRUCTURE-PROPERTY RELATIONSHIPS OF A ZINC OXIDE VARISTOR MATERIAL

    E-Print Network [OSTI]

    Williama, Pamela Louise

    2011-01-01T23:59:59.000Z

    RELATIONSHIPS OF A ZINC OXIDE VARISTOR MATERIAL Pamelaresistors, and zinc oxide varistors are semiconductorRELATIONSHIPS OF A ZINC OXIDE VARISTOR MATERIAL CONTENTS

  12. Effects of Tungsten Oxide Addition on the Electrochemical Performance...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tungsten Oxide Addition on the Electrochemical Performance of Nanoscale Tantalum Oxide-Based Electrocatalysts for Effects of Tungsten Oxide Addition on the Electrochemical...

  13. Effects of air oxidation on the dissolution rate of LWR spent fuel

    SciTech Connect (OSTI)

    Gray, W.J.; Thomas, L.E.; Einziger, R.E.

    1992-11-01T23:59:59.000Z

    Dissolution rates for air-oxidized spent fuel were measured in flowthrough tests. Results from two types of specimens, separated grains and multigrain particles, both in oxidized (U[sub 4]O[sub 9+x]) and unoxidized (UO[sub 2]) conditions indicated only minor effects of oxidation on the surface-area-normalized rates. Similar results were obtained for unirradiated specimens in three different oxidation states (UO[sub 2], U[sub 3]O[sub 7], and U[sub 3]O[sub 8]). These observations have important practical implications for disposal of spent fuel in a geologic repository as well as implications regarding the oxidative dissolution mechanism of UO[sub 2] fuel.

  14. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Draper, R.; George, R.A.; Shockling, L.A.

    1993-04-06T23:59:59.000Z

    A solid oxide fuel cell generator has a pair of spaced apart tubesheets in a housing. At least two intermediate barrier walls are between the tubesheets and define a generator chamber between two intermediate buffer chambers. An array of fuel cells have tubes with open ends engaging the tubesheets. Tubular, axially elongated electrochemical cells are supported on the tubes in the generator chamber. Fuel gas and oxidant gas are preheated in the intermediate chambers by the gases flowing on the other side of the tubes. Gas leakage around the tubes through the tubesheets is permitted. The buffer chambers reentrain the leaked fuel gas for reintroduction to the generator chamber.

  15. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Draper, Robert (Churchill Boro, PA); George, Raymond A. (Pittsburgh, PA); Shockling, Larry A. (Plum Borough, PA)

    1993-01-01T23:59:59.000Z

    A solid oxide fuel cell generator has a pair of spaced apart tubesheets in a housing. At least two intermediate barrier walls are between the tubesheets and define a generator chamber between two intermediate buffer chambers. An array of fuel cells have tubes with open ends engaging the tubesheets. Tubular, axially elongated electrochemical cells are supported on the tubes in the generator chamber. Fuel gas and oxidant gas are preheated in the intermediate chambers by the gases flowing on the other side of the tubes. Gas leakage around the tubes through the tubesheets is permitted. The buffer chambers reentrain the leaked fuel gas for reintroduction to the generator chamber.

  16. Aromatic-radical oxidation chemistry

    SciTech Connect (OSTI)

    Glassman, I.; Brezinsky, K. [Princeton Univ., NJ (United States)

    1993-12-01T23:59:59.000Z

    The research effort has focussed on discovering an explanation for the anomalously high CO{sub 2} concentrations observed early in the reaction sequence of the oxidation of cyclopentadiene. To explain this observation, a number of plausible mechanisms have been developed which now await experimental verification. One experimental technique for verifying mechanisms is to probe the reacting system by perturbing the radical concentrations. Two forms of chemical perturbation of the oxidation of cyclopentadiene were begun during this past year--the addition of NO{sub 2} and CO to the reacting mixture.

  17. Scaling methane oxidation: From laboratory incubation experiments to landfill cover field conditions

    SciTech Connect (OSTI)

    Abichou, Tarek, E-mail: abichou@eng.fsu.edu [Florida State University, Tallahassee, FL 32311 (United States); Mahieu, Koenraad; Chanton, Jeff [Florida State University, Tallahassee, FL 32311 (United States); Romdhane, Mehrez; Mansouri, Imane [Unite de Recherche M.A.C.S., Ecole Nationale d'Ingenieurs de Gabes, Route de Medenine, 6029 Gabes (Tunisia)

    2011-05-15T23:59:59.000Z

    Evaluating field-scale methane oxidation in landfill cover soils using numerical models is gaining interest in the solid waste industry as research has made it clear that methane oxidation in the field is a complex function of climatic conditions, soil type, cover design, and incoming flux of landfill gas from the waste mass. Numerical models can account for these parameters as they change with time and space under field conditions. In this study, we developed temperature, and water content correction factors for methane oxidation parameters. We also introduced a possible correction to account for the different soil structure under field conditions. These parameters were defined in laboratory incubation experiments performed on homogenized soil specimens and were used to predict the actual methane oxidation rates to be expected under field conditions. Water content and temperature corrections factors were obtained for the methane oxidation rate parameter to be used when modeling methane oxidation in the field. To predict in situ measured rates of methane with the model it was necessary to set the half saturation constant of methane and oxygen, K{sub m}, to 5%, approximately five times larger than laboratory measured values. We hypothesize that this discrepancy reflects differences in soil structure between homogenized soil conditions in the lab and actual aggregated soil structure in the field. When all of these correction factors were re-introduced into the oxidation module of our model, it was able to reproduce surface emissions (as measured by static flux chambers) and percent oxidation (as measured by stable isotope techniques) within the range measured in the field.

  18. Hydrous metal oxide catalysts for oxidation of hydrocarbons

    SciTech Connect (OSTI)

    Miller, J.E.; Dosch, R.G.; McLaughlin, L.I. [Sandia National Labs., Albuquerque, NM (United States). Process Research Dept.

    1993-07-01T23:59:59.000Z

    This report describes work performed at Sandia under a CRADA with Shell Development of Houston, Texas aimed at developing hydrous metal oxide (HMO) catalysts for oxidation of hydrocarbons. Autoxidation as well as selective oxidation of 1-octene was studied in the presence of HMO catalysts based on known oxidation catalysts. The desired reactions were the conversion of olefin to epoxides, alcohols, and ketones, HMOs seem to inhibit autoxidation reactions, perhaps by reacting with peroxides or radicals. Attempts to use HMOs and metal loaded HMOs as epoxidation catalysts were unsuccessful, although their utility for this reaction was not entirely ruled out. Likewise, alcohol formation from olefins in the presence of HMO catalysts was not achieved. However, this work led to the discovery that acidified HMOs can lead to carbocation reactions of hydrocarbons such as cracking. An HMO catalyst containing Rh and Cu that promotes the reaction of {alpha}-olefins with oxygen to form methyl ketones was identified. Although the activity of the catalyst is relatively low and isomerization reactions of the olefin simultaneously occur, results indicate that these problems may be addressed by eliminating mass transfer limitations. Other suggestions for improving the catalyst are also made. 57 refs.

  19. Plasma-activated direct bonding of diamond-on-insulator wafers to thermal oxide grown silicon wafers

    E-Print Network [OSTI]

    Akin, Tayfun

    microscopy, profilometer and wafer bow measurements. Plasma-activated direct bonding of DOI wafers to thermalPlasma-activated direct bonding of diamond-on-insulator wafers to thermal oxide grown silicon (CMP) on the diamond surface makes a poor bonding to silicon wafers with thermal oxide. Our results

  20. Graphene oxide nanocomposites and their electrorheology

    SciTech Connect (OSTI)

    Zhang, Wen Ling; Liu, Ying Dan; Choi, Hyoung Jin, E-mail: hjchoi@inha.ac.kr

    2013-12-15T23:59:59.000Z

    Graphical abstract: - Highlights: • GO-based PANI, NCOPA and PS nanocomposites are prepared. • The nanocomposites are adopted as novel electrorheological (ER) candidates. • Their critical ER characteristics and dielectric performance are analyzed. • Typical ER behavior widens applications of GO-based nanocomposites. - Abstract: Graphene oxide (GO), a novel one-atom carbon system, has become one of the most interesting materials recently due to its unique physical and chemical properties in addition to graphene. This article briefly reviews a recent progress of the fabrication of GO-based polyaniline, ionic N-substituted copolyaniline and polystyrene nanocomposites. The critical electrorheological characteristics such as flow response and yield stress from rheological measurement, relaxation time and achievable polarizability from dielectric analysis are also analyzed.

  1. Genomic consequences of DNA oxidation by peroxynitrite

    E-Print Network [OSTI]

    Neeley, William Louis

    2006-01-01T23:59:59.000Z

    The radicals nitric oxide and superoxide are produced endogenously by activated macrophages and neutrophils and combine in a diffusion-limited reaction to form peroxynitrite, a powerful oxidizing and nitrating agent capable ...

  2. Solid Oxide Fuel Cell Manufacturing Overview

    E-Print Network [OSTI]

    Solid Oxide Fuel Cell Manufacturing Overview Hydrogen and Fuel Cell Technologies Manufacturing R Reserved. 3 The Solid Oxide Fuel Cell Electrochemistry #12;Copyright © 2011 Versa Power Systems. All Rights

  3. NANO - "Green" metal oxides ... | ornl.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    "Green" metal oxides ... Water and nano-sized particles isolated from trees, plants and algae are the ingredients of a new recipe for low-cost metal oxides that are widely used in...

  4. Complex oxides useful for thermoelectric energy conversion

    DOE Patents [OSTI]

    Majumdar, Arunava (Orinda, CA); Ramesh, Ramamoorthy (Moraga, CA); Yu, Choongho (College Station, TX); Scullin, Matthew L. (Berkeley, CA); Huijben, Mark (Enschede, NL)

    2012-07-17T23:59:59.000Z

    The invention provides for a thermoelectric system comprising a substrate comprising a first complex oxide, wherein the substrate is optionally embedded with a second complex oxide. The thermoelectric system can be used for thermoelectric power generation or thermoelectric cooling.

  5. Perovskite catalysts for oxidative coupling

    DOE Patents [OSTI]

    Campbell, Kenneth D. (Charleston, WV)

    1991-01-01T23:59:59.000Z

    Perovskites of the structure A.sub.2 B.sub.2 C.sub.3 O.sub.10 are useful as catalysts for the oxidative coupling of lower alkane to heavier hydrocarbons. A is alkali metal; B is lanthanide or lanthanum, cerium, neodymium, samarium, praseodymium, gadolinium or dysprosium; and C is titanium.

  6. Perovskite catalysts for oxidative coupling

    DOE Patents [OSTI]

    Campbell, K.D.

    1991-06-25T23:59:59.000Z

    Perovskites of the structure A[sub 2]B[sub 2]C[sub 3]O[sub 10] are useful as catalysts for the oxidative coupling of lower alkane to heavier hydrocarbons. A is alkali metal; B is lanthanide or lanthanum, cerium, neodymium, samarium, praseodymium, gadolinium or dysprosium; and C is titanium.

  7. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Di Croce, A. Michael (Murrysville, PA); Draper, Robert (Churchill Boro, PA)

    1993-11-02T23:59:59.000Z

    A solid oxide fuel cell generator has a plenum containing at least two rows of spaced apart, annular, axially elongated fuel cells. An electrical conductor extending between adjacent rows of fuel cells connects the fuel cells of one row in parallel with each other and in series with the fuel cells of the adjacent row.

  8. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Di Croce, A.M.; Draper, R.

    1993-11-02T23:59:59.000Z

    A solid oxide fuel cell generator has a plenum containing at least two rows of spaced apart, annular, axially elongated fuel cells. An electrical conductor extending between adjacent rows of fuel cells connects the fuel cells of one row in parallel with each other and in series with the fuel cells of the adjacent row. 5 figures.

  9. Formulations for iron oxides dissolution

    DOE Patents [OSTI]

    Horwitz, Earl P. (Argonne, IL); Chiarizia, Renato (Argonne, IL)

    1992-01-01T23:59:59.000Z

    A mixture of a di- or polyphosphonic acid and a reductant wherein each is present in a sufficient amount to provide a synergistic effect with respect to the dissolution of metal oxides and optionally containing corrosion inhibitors and pH adjusting agents.

  10. MEASURING GASEOUS EMISSIONS FROM STORED PIG SLURRY S. Espagnol1

    E-Print Network [OSTI]

    Boyer, Edmond

    2 MEASURING GASEOUS EMISSIONS FROM STORED PIG SLURRY S. Espagnol1 , L. Loyon2 , F. Guiziou2 , P to measure emissions factors of ammonia (NH3), nitrous oxide (N2O) methane (CH4) and carbon dioxide (CO2) from stored pig slurry and measured the variations of the emissions in time and space. In 2006, dynamic

  11. LASH oxidation, waste management

    SciTech Connect (OSTI)

    Shires, P.J.; Katta, S.; Henningsen, G.

    1993-09-01T23:59:59.000Z

    Temperature for highest sulfation of both as-received KRW LASH and FW LASH was found to be 1700{degrees}F in the temperature range of 1500 to 1700{degrees}F studied. No significant amount of SO{sub 2} was measured by gas analysis in the tests reported here. Confirmation of SO{sub 2} release by sulfur balance including the solids is in progress. The sulfide conversion achieved for HSCF KRW LASH including the conversion obtained in the muffle furnace was about 80%. Grinding it did not enhance the conversion. By grinding and then doping it with an alkali, the conversion was increased to about 95%. The impregnation of CFHS FW LASH with the alkali enhanced the sulfide conversion to a high level (94%) just as observed for HSCF KRW LASH. The absorption of H{sub 2}S by the KRW LASH is as good as that observed for the two pure limestones used in this study. The absorption of SO{sub 2} by the KRW LASH is poor compared to that of the pure limestones. Additional experiments are planned to attempt to identify the mechanism.

  12. Effect of morphology and solvent on two-photon absorption of nano zinc oxide

    SciTech Connect (OSTI)

    Kavitha, M.K. [Department of Chemistry, Indian Institute of Space Science and Technology, Valiamala, Thiruvananthapuram 695547, Kerala (India); Haripadmam, P.C.; Gopinath, Pramod; Krishnan, Bindu [Department of Physics, Indian Institute of Space Science and Technology, Valiamala, Thiruvananthapuram 695547, Kerala (India); John, Honey, E-mail: honey@iist.ac.in [Department of Chemistry, Indian Institute of Space Science and Technology, Valiamala, Thiruvananthapuram 695547, Kerala (India)

    2013-05-15T23:59:59.000Z

    Highlights: ? ZnO nanospheres and triangular structures synthesis by novel precipitation technique. ? The effect of precursor concentration on the size and shape of nano ZnO. ? Open aperture Z-scan measurements of the ZnO nanoparticle dispersions. ? Nanospheres exhibit higher two photon absorption coefficient than triangular nanostructures. ? Nanospheres dispersed in water exhibit higher two photon absorption coefficient than its dispersion in 2-propanol. - Abstract: In this paper, we report the effect of morphology and solvent on the two-photon absorption of nano zinc oxide. Zinc oxide nanoparticles in two different morphologies like nanospheres and triangular nanostructures are synthesized by novel precipitation technique and their two-photon absorption coefficient is measured using open aperture Z-scan technique. Experimental results show that the zinc oxide nanospheres exhibit higher two-photon absorption coefficient than the zinc oxide triangular nanostructures. The zinc oxide nanospheres dispersed in water exhibit higher two-photon absorption coefficient than that of its dispersion in 2-propanol. The zinc oxide nanospheres dispersed in water shows a decrease in two-photon absorption coefficient with an increase in on-axis irradiance. The result confirms the dependence of shape and solvent on the two-photon absorption of nano zinc oxide.

  13. Vapor phase modifiers for oxidative coupling

    DOE Patents [OSTI]

    Warren, Barbara K. (Charleston, WV)

    1991-01-01T23:59:59.000Z

    Volatilized metal compounds retard vapor phase alkane conversion reactions in oxidative coupling processes that convert lower alkanes to higher hydrocarbons.

  14. Oxide Film Aging on Alloy 22 in Halide Containing Solutions

    SciTech Connect (OSTI)

    Rodriguez, Martin A.; Carranza, Ricardo M. [Dept. Materiales, Comision Nacional de Energia Atomica, Av. Gral. Paz 1499, Villa Maipu, 1650 (Argentina); Rebak, Raul B. [Lawrence Livermore National Laboratory, 7000 East Ave, L-631, Livermore, CA, 94550-9698 (United States)

    2007-07-01T23:59:59.000Z

    Passive and corrosion behaviors of Alloy 22 in chloride and fluoride containing solutions, changing the heat treatment of the alloy, the halide concentration and the pH of the solutions at 90 deg. C, was investigated. The study was implemented using electrochemical techniques, which included open circuit potential monitoring over time, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) measurements carried out at open circuit and at passivity potentials. Corrosion rates obtained by EIS measurements after 24 h immersion in naturally aerated solutions were below 0.5 {mu}m/year. The corrosion rates were practically independent of solution pH, alloy heat treatment and halide ion nature and concentration. EIS low frequency resistance values increased with applied potential in the passive domain and with polarization time in pH 6 - 1 M NaCl at 90 deg. C. This effect was attributed to an increase in the oxide film thickness and oxide film aging. High frequency capacitance measurements indicated that passive oxide on Alloy 22 presented a double n-type/p-type semiconductor behavior in the passive potential range. (authors)

  15. Oxide Electronic Conductivity and Hydrogen Pickup Fraction in Zr alloys Adrien Coueta

    E-Print Network [OSTI]

    Motta, Arthur T.

    and instantaneous hydrogen pickup fractions was measured using in-situ Electrochemical Impedance Spectroscopy (EIS it with the observed hydrogen pickup fraction variations. In-Situ Electrochemical Impedance Spectroscopy Impedance-up and oxide growth were precisely measured as a function of exposure time in an autoclave for a set

  16. Comment on "Catalytic Activity of the Rh Surface Oxide: CO Oxidation over Rh(111)

    E-Print Network [OSTI]

    Goodman, Wayne

    . Obviously, heating Rh in pure oxygen to T ) 230 °C and above will lead to the formation of surface Rh oxideComment on "Catalytic Activity of the Rh Surface Oxide: CO Oxidation over Rh(111) under Realistic suggest the importance of a surface oxide phase for high CO2 formation in CO-O2 reactions. However

  17. Correlating Catalytic Methanol Oxidation with the Structure and Oxidation State of Size-Selected Pt Nanoparticles

    E-Print Network [OSTI]

    Kik, Pieter

    Correlating Catalytic Methanol Oxidation with the Structure and Oxidation State of Size-Selected Pt nanoparticles (NPs) prepared by micelle encapsulation and supported on -Al2O3 during the oxidation of methanol the pretreatment. KEYWORDS: platinum, methanol oxidation, operando, XAFS, EXAFS, XANES, alumina, nanoparticle, size

  18. Additive and Competitive Effects of Bacteria and Mn Oxides on Arsenite Oxidation Kinetics

    E-Print Network [OSTI]

    Sparks, Donald L.

    Additive and Competitive Effects of Bacteria and Mn Oxides on Arsenite Oxidation Kinetics L oxidizing As(III) at the same time than for either component alone. The additive effect of the mixed cell even though As(III) was oxidized fastest in a mixed cell--MnO2 system. The additive effect of biotic

  19. Dense high temperature ceramic oxide superconductors

    DOE Patents [OSTI]

    Landingham, Richard L. (Livermore, CA)

    1993-01-01T23:59:59.000Z

    Dense superconducting ceramic oxide articles of manufacture and methods for producing these articles are described. Generally these articles are produced by first processing these superconducting oxides by ceramic processing techniques to optimize materials properties, followed by reestablishing the superconducting state in a desired portion of the ceramic oxide composite.

  20. Dense high temperature ceramic oxide superconductors

    DOE Patents [OSTI]

    Landingham, R.L.

    1993-10-12T23:59:59.000Z

    Dense superconducting ceramic oxide articles of manufacture and methods for producing these articles are described. Generally these articles are produced by first processing these superconducting oxides by ceramic processing techniques to optimize materials properties, followed by reestablishing the superconducting state in a desired portion of the ceramic oxide composite.

  1. Structure formation upon reactive direct current magnetron sputtering of transition metal oxide films

    SciTech Connect (OSTI)

    Ngaruiya, J.M.; Kappertz, O.; Mohamed, S.H.; Wuttig, M. [I. Physikalisches Institut der RWTH Aachen, D-52056 Aachen, Germany and Jomo Kenyatta University of Agriculture and Technology, Box 62000 Nairobi (Kenya); I. Physikalisches Institut der RWTH Aachen, D-52056 Aachen (Germany)

    2004-08-02T23:59:59.000Z

    A comparative study of reactive direct current magnetron sputtering for different transition metal oxides reveals crystalline films at room temperature for group 4 and amorphous films for groups 5 and 6. This observation cannot be explained by the known growth laws and is attributed to the impact of energetic particles, originating from the oxidized target, on the growing film. This scenario is supported by measured target characteristics, the evolution of deposition stress of the films, and the observed backsputtering.

  2. Low contact resistivity of metals on nitrogen-doped cuprous oxide (Cu 2O) thin-films

    E-Print Network [OSTI]

    Siah, Sin Cheng

    Forming low-resistivity contacts on cuprous oxide (Cu[subscript 2]O) is an essential step toward demonstrating its suitability as a candidate solar cell material. We measure the contact resistivity of three noble metals ...

  3. Nitrous oxide (N?O) isotopic composition in the troposphere : instrumentation, observations at Mace Head, Ireland, and regional modeling

    E-Print Network [OSTI]

    Potter, Katherine Ellison

    2011-01-01T23:59:59.000Z

    Nitrous oxide (N?O) is a significant greenhouse gas and main contributor to stratospheric ozone destruction. Surface measurements of N?O mole fractions have been used to attribute source and sink strengths, but large ...

  4. Reduction of iron-oxide-carbon composites: part I. Estimation of the rate constants

    SciTech Connect (OSTI)

    Halder, S.; Fruehan, R.J. [Praxair Inc., Tonawanda, NY (United States). Technological Center

    2008-12-15T23:59:59.000Z

    A new ironmaking concept using iron-oxide-carbon composite pellets has been proposed, which involves the combination of a rotary hearth furnace (RHF) and an iron bath smelter. This part of the research focuses on studying the two primary chemical kinetic steps. Efforts have been made to experimentally measure the kinetics of the carbon gasification by CO{sub 2} and wustite reduction by CO by isolating them from the influence of heat- and mass-transport steps. A combined reaction model was used to interpret the experimental data and determine the rate constants. Results showed that the reduction is likely to be influenced by the chemical kinetics of both carbon oxidation and wustite reduction at the temperatures of interest. Devolatilized wood-charcoal was observed to be a far more reactive form of carbon in comparison to coal-char. Sintering of the iron-oxide at the high temperatures of interest was found to exert a considerable influence on the reactivity of wustite by virtue of altering the internal pore surface area available for the reaction. Sintering was found to be predominant for highly porous oxides and less of an influence on the denser ores. It was found using an indirect measurement technique that the rate constants for wustite reduction were higher for the porous iron-oxide than dense hematite ore at higher temperatures (> 1423 K). Such an indirect mode of measurement was used to minimize the influence of sintering of the porous oxide at these temperatures.

  5. Study of nanocomposites based on iron oxides and pectin

    SciTech Connect (OSTI)

    Chistyakova, Nataliya I., E-mail: nchistyakova@yandex.ru; Shapkin, Alexey A., E-mail: nchistyakova@yandex.ru; Sirazhdinov, Ruslan R., E-mail: nchistyakova@yandex.ru; Gubaidulina, Tatiana V., E-mail: nchistyakova@yandex.ru; Kiseleva, Tatiana Yu., E-mail: nchistyakova@yandex.ru; Kazakov, Alexander P., E-mail: nchistyakova@yandex.ru; Rusakov, Vyacheslav S., E-mail: nchistyakova@yandex.ru [M. V. Lomonosov Moscow State University, Faculty of Physics, Leninskie gory, 119991 Moscow (Russian Federation)

    2014-10-27T23:59:59.000Z

    Mössbauer and X-ray diffraction study of nanocomposites based on iron oxides and pectin (PC) was carried out involving magnetization measurements. The concentrations of PC in nanocomposites varied from 0 to 10%. Mössbauer investigations of nanocomposites were carried out in the temperature range from 5 to 300 K. Many-state superparamagnetic relaxation model was used for spectra fitting. The magnetization, M(T,H), was measured in the temperature interval of 80-300 K and magnetic field up to 10 kOe. Formation of the 'iron-polymer' interface was not observed. Particle sizes were estimated using the Mössbauer and X-ray powder diffraction data.

  6. THE ROLE OF ACTIVE ELEMENTS AND OXIDE DISPERSIONS IN THE DEVELOPMENT OF OXIDATION-RESISTANT ALLOYS AND COATINGS

    E-Print Network [OSTI]

    Allam, I.M.

    2010-01-01T23:59:59.000Z

    of the oxide and alloy and these lead to spallation of theleads to a uniform distribution of fine internal oxide

  7. Nanowire-based All Oxide Solar Cells

    SciTech Connect (OSTI)

    Yang*, Benjamin D. Yuhas and Peidong; Yang, Peidong

    2008-12-07T23:59:59.000Z

    We present an all-oxide solar cell fabricated from vertically oriented zinc oxide nanowires and cuprous oxide nanoparticles. Our solar cell consists of vertically oriented n-type zinc oxide nanowires, surrounded by a film constructed from p-type cuprous oxide nanoparticles. Our solution-based synthesis of inexpensive and environmentally benign oxide materials in a solar cell would allow for the facile production of large-scale photovoltaic devices. We found that the solar cell performance is enhanced with the addition of an intermediate oxide insulating layer between the nanowires and the nanoparticles. This observation of the important dependence of the shunt resistance on the photovoltaic performance is widely applicable to any nanowire solar cell constructed with the nanowire array in direct contact with one electrode.

  8. Graphene oxide oxidizes stannous ions to synthesize tin sulfidegraphene nanocomposites with small crystal size for high performance lithium ion

    E-Print Network [OSTI]

    Cao, Guozhong

    Graphene oxide oxidizes stannous ions to synthesize tin sulfide­graphene nanocomposites with small September 2012 DOI: 10.1039/c2jm34864k This study reports a novel strategy of preparing graphene composites by employing graphene oxide as precursor and oxidizer. It is demonstrated that graphene oxide can oxidize

  9. Coal combustion by wet oxidation

    SciTech Connect (OSTI)

    Bettinger, J.A.; Lamparter, R.A.; McDowell, D.C.

    1980-11-15T23:59:59.000Z

    The combustion of coal by wet oxidation was studied by the Center for Waste Management Programs, of Michigan Technological University. In wet oxidation a combustible material, such as coal, is reacted with oxygen in the presence of liquid water. The reaction is typically carried out in the range of 204/sup 0/C (400/sup 0/F) to 353/sup 0/C (650/sup 0/F) with sufficient pressure to maintain the water present in the liquid state, and provide the partial pressure of oxygen in the gas phase necessary to carry out the reaction. Experimental studies to explore the key reaction parameters of temperature, time, oxidant, catalyst, coal type, and mesh size were conducted by running batch tests in a one-gallon stirred autoclave. The factors exhibiting the greatest effect on the extent of reaction were temperature and residence time. The effect of temperature was studied from 204/sup 0/C (400/sup 0/F) to 260/sup 0/C (500/sup 0/F) with a residence time from 600 to 3600 seconds. From this data, the reaction activation energy of 2.7 x 10/sup 4/ calories per mole was determined for a high-volatile-A-Bituminous type coal. The reaction rate constant may be determined at any temperature from the activation energy using the Arrhenius equation. Additional data were generated on the effect of mesh size and different coal types. A sample of peat was also tested. Two catalysts were evaluated, and their effects on reaction rate presented in the report. In addition to the high temperature combustion, low temperature desulfurization is discussed. Desulfurization can improve low grade coal to be used in conventional combustion methods. It was found that 90% of the sulfur can be removed from the coal by wet oxidation with the carbon untouched. Further desulfurization studies are indicated.

  10. Method and apparatus for detecting the presence and thickness of carbon and oxide layers on EUV reflective surfaces

    DOE Patents [OSTI]

    Malinowski, Michael E.

    2005-01-25T23:59:59.000Z

    The characteristics of radiation that is reflected from carbon deposits and oxidation formations on highly reflective surfaces such as Mo/Si mirrors can be quantified and employed to detect and measure the presence of such impurities on optics. Specifically, it has been shown that carbon deposits on a Mo/Si multilayer mirror decreases the intensity of reflected HeNe laser (632.8 nm) light. In contrast, oxide layers formed on the mirror should cause an increase in HeNe power reflection. Both static measurements and real-time monitoring of carbon and oxide surface impurities on optical elements in lithography tools should be achievable.

  11. Optical indices of lithiated electrochromic oxides

    SciTech Connect (OSTI)

    Rubin, M.; Rottkay, K. von; Wen, S.J.; Ozer, N.; Slack, J.

    1996-09-01T23:59:59.000Z

    Optical indices have been determined for thin films of several electrochromic oxide materials. One of the most important materials in electrochromic devices, WO{sub 3}, was thoroughly characterized for a range of electrochromic states by sequential injection of Li ions. Another promising material, Li{sub 0.5}Ni{sub 0.5}O, was also studied in detail. Less detailed results are presented for three other common lithium-intercalating electrochromic electrode materials: V{sub 2}O{sub 5}, LiCoO{sub 2}, and CeO{sub 2}-TiO{sub 2}. The films were grown by sputtering, pulsed laser deposition (PLD) and sol-gel techniques. Measurements were made using a combination of variable-angle spectroscopy ellipsometry and spectroradiometry. The optical constants were then extracted using physical and spectral models appropriate to each material. Optical indices of the underlying transparent conductors, determined in separate studies, were fixed in the models of this work. The optical models frequently agree well with independent physical measurements of film structure, particularly surface roughness by atomic force microscopy. Inhomogeneity due to surface roughness, gradient composition, and phase separation are common in both the transparent conductors and electrochromics, resulting sometimes in particularly complex models for these materials. Complete sets of data are presented over the entire solar spectrum for a range of colored states. This data is suitable for prediction of additional optical properties such as oblique transmittance and design of complete electrochromic devices.

  12. Tribological interaction between polytetrafluoroethylene and silicon oxide surfaces

    SciTech Connect (OSTI)

    Uçar, A.; Çopuro?lu, M.; Suzer, S., E-mail: suzer@fen.bilkent.edu.tr [Department of Chemistry, Bilkent University, 06800 Ankara (Turkey); Baykara, M. Z. [Department of Mechanical Engineering, Bilkent University, 06800 Ankara (Turkey); Ar?kan, O. [Department of Electrical and Electronics Engineering, Bilkent University, 06800 Ankara (Turkey)

    2014-10-28T23:59:59.000Z

    We investigated the tribological interaction between polytetrafluoroethylene (PTFE) and silicon oxide surfaces. A simple rig was designed to bring about a friction between the surfaces via sliding a piece of PTFE on a thermally oxidized silicon wafer specimen. A very mild inclination (?0.5°) along the sliding motion was also employed in order to monitor the tribological interaction in a gradual manner as a function of increasing contact force. Additionally, some patterns were sketched on the silicon oxide surface using the PTFE tip to investigate changes produced in the hydrophobicity of the surface, where the approximate water contact angle was 45° before the transfer. The nature of the transferred materials was characterized by X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). XPS results revealed that PTFE was faithfully transferred onto the silicon oxide surface upon even at the slightest contact and SEM images demonstrated that stable morphological changes could be imparted onto the surface. The minimum apparent contact pressure to realize the PTFE transfer is estimated as 5 kPa, much lower than reported previously. Stability of the patterns imparted towards many chemical washing processes lead us to postulate that the interaction is most likely to be chemical. Contact angle measurements, which were carried out to characterize and monitor the hydrophobicity of the silicon oxide surface, showed that upon PTFE transfer the hydrophobicity of the SiO{sub 2} surface could be significantly enhanced, which might also depend upon the pattern sketched onto the surface. Contact angle values above 100° were obtained.

  13. Structural transformation of nickel hydroxide films during anodic oxidation

    SciTech Connect (OSTI)

    Crocker, R.W.; Muller, R.H.

    1992-05-01T23:59:59.000Z

    The transformation of anodically formed nickel hydroxide/oxy-hydroxide electrodes has been investigated. A mechanism is proposed for the anodic oxidation reaction, in which the reaction interface between the reduced and oxidized phases of the electrode evolves in a nodular topography that leads to inefficient utilization of the active electrode material. In the proposed nodular transformation model for the anodic oxidation reaction, nickel hydroxide is oxidized to nickel oxy-hydroxide in the region near the metal substrate. Since the nickel oxy-hydroxide is considerably more conductive than the surrounding nickel hydroxide, as further oxidation occurs, nodular features grow rapidly to the film/electrolyte interface. Upon emerging at the electrolyte interface, the reaction boundary between the nickel hydroxide and oxy-hydroxide phases spreads laterally across the film/electrolyte interface, creating an overlayer of nickel oxy-hydroxide and trapping uncharged regions of nickel hydroxide within the film. The nickel oxy-hydroxide overlayer surface facilitates the oxygen evolution side reaction. Scanning tunneling microscopy of the electrode in its charged state revealed evidence of 80 {endash} 100 Angstrom nickel oxy-hydroxide nodules in the nickel hydroxide film. In situ spectroscopic ellipsometer measurements of films held at various constant potentials agree quantitatively with optical models appropriate to the nodular growth and subsequent overgrowth of the nickel oxy-hydroxide phase. A two-dimensional, numerical finite difference model was developed to simulate the current distribution along the phase boundary between the charged and uncharged material. The model was used to explore the effects of the physical parameters that govern the electrode behavior. The ratio of the conductivities of the nickel hydroxide and oxy-hydroxide phases was found to be the dominant parameter in the system.

  14. Depth distribution of lithium in oxidized binary Al-Li alloys determined by secondary ion mass spectrometry and neutron depth profiling

    SciTech Connect (OSTI)

    Soni, K.K. (Univ. of Chicago, IL (United States)); Williams, D.B. (Lehigh Univ., Bethlehem, PA (United States)); Newbury, D.E.; Chi, P.; Downing, R.G.; Lamaza, G. (National Inst. of Standards and Technology, Gaithersburg, MD (United States))

    1993-01-01T23:59:59.000Z

    Oxidation of binary Al-Li alloys during short exposures at 530 C and long exposures at 200 C was studied with regard to the Li distribution. Secondary ion mass spectrometry (SIMS) and neutron depth profiling (NDP) were used to obtain quantitative Li depth profiles across the surface oxide layer and the underlying alloy. The underlying alloy was depleted in Li as a result of oxidation at 530 and 200 C. The SIMS and NDP results showed good mutual agreement and were used to evaluate the oxide thickness, the Li concentration at the oxide-ally interface, and the mass balance between oxide and alloy. The Li depletion profiles in the alloy were also calculated using the interdiffusion coefficients reported in the literature and compared with the measured profiles; the two profiles differed at 530 C but showed good agreement at 200 C.

  15. Compositional Analysis of the High Molecular Weight Ethylene Oxide Propylene Oxide Copolymer by MALDI Mass Spectrometry

    E-Print Network [OSTI]

    Houshia, Orwa Jaber

    2012-01-01T23:59:59.000Z

    The composition of narrow distribution poly ethylene oxide-propylene oxide copolymer (Mw ~ 8700 Da) was studied using matrix assisted laser desorption ionization (MALDI) mass spectrometry. The ethylene oxide-propylene oxide copolymer produced oligomers separated by 14 Da. The average resolving power over the entire spectrum was 28,000. Approximately 448 isotopically resolved peaks representing about 56 oligomers are identified. Although agreement between experimental and calculated isotopic distributions was strong, the compositional assignment was difficult. This is due to the large number of possible isobaric components. The purpose of this research is to resolve and study the composition of high mass copolymer such as ethylene oxide-propylene oxide.

  16. Electrochromic devices embodying W oxide/Ni oxide tandem films

    SciTech Connect (OSTI)

    Azens, A.; Vaivars, G.; Veszelei, M.; Kullman, L.; Granqvist, C. G.

    2001-06-15T23:59:59.000Z

    Six-layer electrochromic devices of indium tin oxide (ITO)/NiO{sub x}H{sub y}/WO{sub 3}/ZrP-electrolyte/WO{sub 3}/ITO were made by reactive dc magnetron sputtering and lamination. The WO{sub 3} layer between the acidic ZrP-based electrolyte and the NiO{sub x}H{sub y} layer served as optically passive protective layer. The optical inactivity of the protective layer could be understood from arguments based on electron density of states. {copyright} 2001 American Institute of Physics.

  17. Electronically conducting metal oxide nanoparticles and films for optical sensing applications

    SciTech Connect (OSTI)

    Ohodnicki, Jr., Paul R.; Wang, Congjun; Andio, Mark A

    2014-09-16T23:59:59.000Z

    The disclosure relates to a method of detecting a change in a chemical composition by contacting a conducting oxide material with a monitored stream, illuminating the conducting oxide material with incident light, collecting exiting light, monitoring an optical signal based on a comparison of the incident light and the exiting light, and detecting a shift in the optical signal. The conducting metal oxide has a carrier concentration of at least 10.sup.17/cm.sup.3, a bandgap of at least 2 eV, and an electronic conductivity of at least 10.sup.-1 S/cm, where parameters are specified at the gas stream temperature. The optical response of the conducting oxide materials is proposed to result from the high carrier concentration and electronic conductivity of the conducting metal oxide, and the resulting impact of changing gas atmospheres on that relatively high carrier concentration and electronic conductivity. These changes in effective carrier densities and electronic conductivity of conducting metal oxide films and nanoparticles are postulated to be responsible for the change in measured optical absorption associated with free carriers. Exemplary conducting metal oxides include but are not limited to Al-doped ZnO, Sn-doped In.sub.2O.sub.3, Nb-doped TiO.sub.2, and F-doped SnO.sub.2.

  18. Plasmonic transparent conducting metal oxide nanoparticles and films for optical sensing applications

    DOE Patents [OSTI]

    Ohodnicki, Jr., Paul R; Wang, Congjun; Andio, Mark A

    2014-01-28T23:59:59.000Z

    The disclosure relates to a method of detecting a change in a chemical composition by contacting a doped oxide material with a monitored stream, illuminating the doped oxide material with incident light, collecting exiting light, monitoring an optical signal based on a comparison of the incident light and the exiting light, and detecting a shift in the optical signal. The doped metal oxide has a carrier concentration of at least 10.sup.18/cm.sup.3, a bandgap of at least 2 eV, and an electronic conductivity of at least 10.sup.1 S/cm, where parameters are specified at a temperature of 25.degree. C. The optical response of the doped oxide materials results from the high carrier concentration of the doped metal oxide, and the resulting impact of changing gas atmospheres on that relatively high carrier concentration. These changes in effective carrier densities of conducting metal oxide nanoparticles are postulated to be responsible for the change in measured optical absorption associated with free carriers. Exemplary doped metal oxides include but are not limited to Al-doped ZnO, Sn-doped In.sub.2O.sub.3, Nb-doped TiO.sub.2, and F-doped SnO.sub.2.

  19. ARM - Measurements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadap Documentation TDMADAP : XDCnarrowbandheat flux ARM DatagovMeasurementsVisibilityMeasurements

  20. Vapour phase approach for iron oxide nanoparticle synthesis from solid precursors

    SciTech Connect (OSTI)

    Singh, Mandeep; Ulbrich, Pavel; Prokopec, Vadym [Institute of Chemical Technology Prague, Technicka 5, 166 28 Prague 6 (Czech Republic); Svoboda, Pavel [Faculty of Mathematics and Physics, Charles University, Ke Karlovu 5, 120 00 Prague 2 (Czech Republic); Šantavá, Eva [Institute of Physics ASCR, Na Slovance 2, 182 21 Prague 8 (Czech Republic); Št?pánek, František, E-mail: Frantisek.Stepanek@vscht.cz [Institute of Chemical Technology Prague, Technicka 5, 166 28 Prague 6 (Czech Republic)

    2013-04-15T23:59:59.000Z

    A new non-solution mediated approach to the synthesis of iron oxide nanoparticles directly from solid FeCl{sub 2} salt precursors has been developed. The method is rapid, simple and scalable. The structural properties and the phase of the resulting iron oxide particles has been determined by a range of methods including XRD, FT-IR and Mössbauer spectroscopy, and the phase is shown to be maghemite (?-Fe{sub 2}O{sub 3}). The magnetic properties of the iron oxide particles have been measured using SQUID, confirming superparamagnetic behaviour of the powder and a saturation magnetization of 53.0 emu g{sup ?1} at 300 K. Aqueous dispersions at increasing concentrations were prepared and their heating rate under a 400 kHz alternating magnetic field measured. The specific absorption rate (SAR) of the iron oxide was found to be 84.8 W g{sup ?1}, which makes the material suitable for the formulation of ferrofluids or ferrogels with RF heating properties. - Graphical Abstract: Superparamagnetic iron oxide nanoparticles obtained by a novel vapour phase approach. Highlights: ? Novel vapour phase (non-solvent) approach for iron oxide nanoparticle synthesis. ? Attractive alternative approach to the present co-precipitation method. ? Better magnetic properties with high coercivity of nanoparticles. ? A high specific absorption rate (SAR) for hyperthermia applications.

  1. Oxidation and Volatilization from Tantalum Alloy T-222 During Air Exposure

    SciTech Connect (OSTI)

    Smolik, Galen Richard; Petti, David Andrew; Sharpe, John Phillip; Schuetz, Stanley Thomas

    2000-10-01T23:59:59.000Z

    Tantalum alloys are one of the refractory metals with renewed consideration for high temperatures in fusion reactor applications. Tantalum alloys perform well in protective environments but oxidized readily in gases containing higher oxygen levels. In addition, the radioactive isotope Ta-182 would be produced in tantalum and could be a significant contributor to dose if mobilized. Other isotopes of importance are produced from tungsten and hafnium. Mobilization of activated products during an accident with air ingress is therefore a safety issue. In this study, we measured the extent of oxidation and mobilization from tantalum alloy T-222 oxidized in flowing air between 500 and 1200°C. This alloy nominally contains 10 wt% tungsten, 2.5 wt% hafnium and 0.01 wt% carbon. We found that the mobilization of Ta and Hf was closely linked to the occurrence of oxide spalling. These elements showed no migration from the test chamber. Some W was mobilized by volatilization as evidenced by transport from the chamber. Tungsten volatilization could occur primarily during initial stages of oxidation before an oxide scale forms and impedes the process. The mobilization of Ta and W are presented in terms of the mass flux (g/m 2 -h) as a function of test temperature. These measurements along with specific designs, activation calculations, and accident scenarios provide information useful for dose calculations of future fusion devices

  2. Oxidation and Volatilization from Tantalum Alloy T-222 During Air Exposure

    SciTech Connect (OSTI)

    Smolik, G.R.; Petti, D.A.; Sharpe, J.P.; Schuetz, S.T.

    2000-10-31T23:59:59.000Z

    Tantalum alloys are one of the refractory metals with renewed consideration for high temperatures in fusion reactor applications. Tantalum alloys perform well in protective environments but oxidized readily in gases containing higher oxygen levels. In addition, the radioactive isotope Ta-182 would be produced in tantalum and could be a significant contributor to dose if mobilized. Other isotopes of importance are produced from tungsten and hafnium. Mobilization of activated products during an accident with air ingress is therefore a safety issue. In this study, we measured the extent of oxidation and mobilization from tantalum alloy T-222 oxidized in flowing air between 500 and 1200 C. This alloy nominally contains 10 wt% tungsten, 2.5 wt% hafnium and 0.01 wt% carbon. We found that the mobilization of Ta and Hf was closely linked to the occurrence of oxide spalling. These elements showed no migration from the test chamber. Some W was mobilized by volatilization as evidenced by transport from the chamber. Tungsten volatilization could occur primarily during initial stages of oxidation before an oxide scale forms and impedes the process. The mobilization of Ta and W are presented in terms of the mass flux (g/m 2 -h) as a function of test temperature. These measurements along with specific designs, activation calculations, and accident scenarios provide information useful for dose calculations of future fusion devices.

  3. Application of chemical structure and bonding of actinide oxide materials for forensic science

    SciTech Connect (OSTI)

    Wilkerson, Marianne Perry [Los Alamos National Laboratory

    2010-01-01T23:59:59.000Z

    We are interested in applying our understanding of actinide chemical structure and bonding to broaden the suite of analytical tools available for nuclear forensic analyses. Uranium- and plutonium-oxide systems form under a variety of conditions, and these chemical species exhibit some of the most complex behavior of metal oxide systems known. No less intriguing is the ability of AnO{sub 2} (An: U, Pu) to form non-stoichiometric species described as AnO{sub 2+x}. Environmental studies have shown the value of utilizing the chemical signatures of these actinide oxide materials to understand transport following release into the environment. Chemical speciation of actinide-oxide samples may also provide clues as to the age, source, or process history of the material. The scientific challenge is to identify, measure and understand those aspects of speciation of actinide analytes that carry information about material origin and history most relevant to forensics. Here, we will describe our efforts in material synthesis and analytical methods development that we will use to provide the fundamental science to characterize actinide oxide molecular structures for forensic science. Structural properties and initial results to measure structural variability of uranium oxide samples using synchrotron-based X-ray Absorption Fine Structure will be discussed.

  4. Nitrogen and carbon oxides chemistry in the HRS retorting process

    SciTech Connect (OSTI)

    Reynolds, J.G.

    1993-11-12T23:59:59.000Z

    The HRS Oil Shale Retort process consists of a pyrolysis section which converts kerogen of the shale to liquid and gaseous products, and a combustion section which burns residual carbon on the shale to heat the process. Average gas concentrations of selected gas phase species were determined from data measured at several placed on the combustion system of the Lawrence Livermore National Laboratory Hot-Recycled-Solids Retort Pilot Plant for representative rich and lean shale runs. The data was measured on-line and in real time by on-line meters (CO{sub 2}, CO, O{sub 2}), mass spectrometry (CO{sub 2}, O{sub 2}, H{sub 2}O, NO, CH{sub 4}, SO{sub 2}, N{sub 2} and Ar), and Fourier transform infrared spectroscopy (CO{sub 2}, CO, H{sub 2}O, NO, N{sub 2}O, NO{sub 2}, CH{sub 4}, SO{sub 2}, NH{sub 3}, and HCN). For both the rich and leans shale runs, the Lift-Pipe Combustor (LFT) exhibited gas concentrations (sampled at the exit of the LFT) indicative of incomplete combustion and oxidation; the Delayed-Fall Combustor (DFC) exhibited gas concentrations (sampled at the annulus and the exit of the DFC) indicative of much more complete combustion and oxidation. The Fluidized-Bed Combustor exhibited gas concentrations which were controlled to a large extent by the injection atmosphere of the FBC. High levels of nitrogen oxides and low levels of CO were detected when full air injection was used, while high levels of CO and low levels of nitrogen-oxides were detected with partial N{sub 2} injection. Sequential sampling limitations and nitrogen balances are also discussed.

  5. Thermal and Physical Properties of Plutonium Dioxide Produced from the Oxidation of Metal: a Data Summary

    SciTech Connect (OSTI)

    Wayne, David M. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2014-01-13T23:59:59.000Z

    The ARIES Program at the Los Alamos National Laboratory removes plutonium metal from decommissioned nuclear weapons, and converts it to plutonium dioxide in a specially-designed Direct Metal Oxidation furnace. The plutonium dioxide is analyzed for specific surface area, particle size distribution, and moisture content. The purpose of these analyses is to certify that the plutonium dioxide powder meets or exceeds the specifications of the end-user, and the specifications for the packaging and transport of nuclear materials. Analytical results from plutonium dioxide from ARIES development activities, from ARIES production activities, from muffle furnace oxidation of metal, and from metal that was oxidized over a lengthy time interval in air at room temperature, are presented. The processes studied produce plutonium dioxide powder with distinct differences in measured properties, indicating the significant influence of oxidation conditions on physical properties.

  6. Constructivism, measurement, mathematics Concepts of measurement

    E-Print Network [OSTI]

    Hennig, Christian

    Constructivism, measurement, mathematics Concepts of measurement Measurement and statistics Conclusion Measurement as a constructive act - a statistician's view Christian Hennig March 14, 2013 Christian Hennig Measurement as a constructive act - a statistician's view #12;Constructivism, measurement

  7. Novel oxide-oxide fiber reinforced hot gas filter development

    SciTech Connect (OSTI)

    Wagner, R.A.

    1995-12-01T23:59:59.000Z

    The objective of this program is to fabricate and test oxide fiber reinforced composite hot gas filter elements for advanced power generation systems. The level of mechanical durability exhibited by the currently available filters in field tests indicates that more rugged filters are required to meet the demands of large power generation systems. Furthermore, long term corrosion resistance of currently available filters has yet to be demonstrated in PFBC systems. The essential requirements of a composite material designed to meet the program objective for a toughened hot gas filter include the following: Stable continuous fiber; rigid porous matrix; engineered fiber-matrix interface; and cost effectiveness. Based on properties, availability, and cost, Mitsui`s ALMAX alumina fiber and 3M`s NEXTEL 610 alumina fiber were selected as the oxide reinforcement fibers. In order to meet the economic goals of the program it is essential that the cost and amount of continuous fiber be minimized. A four axis filament winder will be used to fabricate filter Preforms in a variety of fiber architectures. Carbon was used as the initial fiber coating because it was known to be resistant to the Processing chemicals. The coating was produced by pyrolysis of the resin based sizings on the continuous fibers. The matrix of the composite filter is comprised of chopped ceramic fiber. Saffil fiber was used for all compositions in this program.

  8. Effects of Tungsten Oxide Addition on the Electrochemical Performance of Nanoscale Tantalum Oxide-Based Electrocatalysts for Proton Exchange Membrane PEM Fuel Cells

    SciTech Connect (OSTI)

    Oh, Tak Keun; Kim, Jin Yong; Shin, Yongsoon; Engelhard, Mark H.; Weil, K. Scott

    2011-08-01T23:59:59.000Z

    In the present study, the properties of a series of non-platinum based nanoscale tantalum oxide/tungsten oxide-carbon composite catalysts was investigated for potential use in catalyzing the oxygen reduction reaction (ORR) on the cathode side of a PEM fuel cell membrane electrode assembly. Electrochemical performance was measured using a half-cell test set up with a rotating disc electrode and compared with a commercial platinum-on-carbon (Pt/C) catalyst. Overall, all of the oxide-based composite catalysts exhibit high ORR on-set potentials, comparable to that of the baseline Pt/C catalyst. The addition of tungsten oxide as a dopant to tantalum oxide greatly improved mass specific current density. Maximum performance was achieved with a catalyst containing 32 mol% of tungsten oxide, which exhibited a mass specific current density ~8% that of the Pt/C catalyst at 0.6 V vs. the normal hydrogen electrode (NHE) and ~35% that of the Pt/C catalyst at 0.2 V vs. NHE. Results from X-ray photoelectron spectroscopy analysis indicated that the tungsten cations in the composite catalysts exist in the +6 oxidation state, while the tantalum displays an average valence of +5, suggesting that the addition of tungsten likely creates an oxygen excess in the tantalum oxide structure that influences its oxygen absorption kinetics. When the 32mol% tungsten doped catalyst loading on the working electrode was increased to five times that of the original loading (which was equivalent to that of the baseline Pt/C catalyst), the area specific current density improved four fold, achieving an area specific current density ~35% that of the Pt/C catalyst at 0.6 V vs. NHE.

  9. Vibrational spectra of CO adsorbed on oxide thin films: A tool to probe the surface defects and phase changes of oxide thin films

    SciTech Connect (OSTI)

    Savara, Aditya, E-mail: savaraa@ornl.gov [Chemical Sciences Division, Oak Ridge National Lab, 1 Bethel Valley Road, Oak Ridge, Tennessee 37831 (United States)

    2014-03-15T23:59:59.000Z

    Thin films of iron oxide were grown on Pt(111) single crystals using cycles of physical vapor deposition of iron followed by oxidative annealing in an ultrahigh vacuum apparatus. Two procedures were utilized for film growth of ?15–30 ML thick films, where both procedures involved sequential deposition+oxidation cycles. In procedure 1, the iron oxide film was fully grown via sequential deposition+oxidation cycles, and then the fully grown film was exposed to a CO flux equivalent to 8 × 10{sup ?7} millibars, and a vibrational spectrum of adsorbed CO was obtained using infrared reflection-absorption spectroscopy. The vibrational spectra of adsorbed CO from multiple preparations using procedure 1 show changes in the film termination structure and/or chemical nature of the surface defects—some of which are correlated with another phase that forms (“phase B”), even before enough of phase B has formed to be easily detected using low energy electron diffraction (LEED). During procedure 2, CO vibrational spectra were obtained between deposition+oxidation cycles, and these spectra show that the film termination structure and/or chemical nature of the surface defects changed as a function of sequential deposition+oxidation cycles. The authors conclude that measurement of vibrational spectra of adsorbed CO on oxide thin films provides a sensitive tool to probe chemical changes of defects on the surface and can thus complement LEED techniques by probing changes not visible by LEED. Increased use of vibrational spectra of adsorbed CO on thin films would enable better comparisons between films grown with different procedures and by different groups.

  10. Solid-oxide fuel cell electrolyte

    DOE Patents [OSTI]

    Bloom, Ira D. (Bolingbrook, IL); Hash, Mark C. (Joliet, IL); Krumpelt, Michael (Naperville, IL)

    1993-01-01T23:59:59.000Z

    A solid-oxide electrolyte operable at between 600.degree. C. and 800.degree. C. and a method of producing the solid-oxide electrolyte are provided. The solid-oxide electrolyte comprises a combination of a compound having weak metal-oxygen interactions with a compound having stronger metal-oxygen interactions whereby the resulting combination has both strong and weak metal-oxygen interaction properties.

  11. Oxidation of hydrogen halides to elemental halogens

    DOE Patents [OSTI]

    Rohrmann, Charles A. (Kennewick, WA); Fullam, Harold T. (Richland, WA)

    1985-01-01T23:59:59.000Z

    A process for oxidizing hydrogen halides having substantially no sulfur impurities by means of a catalytically active molten salt is disclosed. A mixture of the subject hydrogen halide and an oxygen bearing gas is contacted with a molten salt containing an oxidizing catalyst and alkali metal normal sulfates and pyrosulfates to produce an effluent gas stream rich in the elemental halogen and substantially free of sulfur oxide gases.

  12. Spectroscopic studies of metal growth on oxides

    E-Print Network [OSTI]

    Luo, Kai

    2000-01-01T23:59:59.000Z

    : Chemistry SPECTROSCOPIC STUDIES OF METAL GROWTH ON OXIDES A Thesis by KAI LUO Submitted to Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE Approved as to style a d content by: avid W. Goodman.... , Jilin University, P. R. China Chair of Advisory Committee: Dr, David W. Goodman Metal/oxide chemistry and metal cluster growth on oxides are fundamental to our understanding of the catalytic activity and selectivity of metal catalysts, thus...

  13. Poly(ethylene oxide) functionalization

    DOE Patents [OSTI]

    Pratt, Russell Clayton

    2014-04-08T23:59:59.000Z

    A simple procedure is provided by which the hydroxyl termini of poly(ethylene oxide) can be appended with functional groups to a useful extent by reaction and precipitation. The polymer is dissolved in warmed toluene, treated with an excess of organic base and somewhat less of an excess of a reactive acylating reagent, reacted for several hours, then precipitated in isopropanol so that the product can be isolated as a solid, and salt byproducts are washed away. This procedure enables functionalization of the polymer while not requiring laborious purification steps such as solvent-solvent extraction or dialysis to remove undesirable side products.

  14. The Measure of a Measurement

    E-Print Network [OSTI]

    Palle E. T. Jorgensen

    2007-07-23T23:59:59.000Z

    While finite non-commutative operator systems lie at the foundation of quantum measurement, they are also tools for understanding geometric iterations as used in the theory of iterated function systems (IFSs) and in wavelet analysis. Key is a certain splitting of the total Hilbert space and its recursive iterations to further iterated subdivisions. This paper explores some implications for associated probability measures (in the classical sense of measure theory), specifically their fractal components. We identify a fractal scale $s$ in a family of Borel probability measures $\\mu$ on the unit interval which arises independently in quantum information theory and in wavelet analysis. The scales $s$ we find satisfy $s\\in \\mathbb{R}_{+}$ and $s\

  15. Kinetics and Mechanism of Oxidative Dehydrogenation of Propane on Vanadium, Molybdenum, and Tungsten Oxides

    E-Print Network [OSTI]

    Iglesia, Enrique

    Kinetics and Mechanism of Oxidative Dehydrogenation of Propane on Vanadium, Molybdenum catalysts confirmed that oxidative dehydrogenation of propane occurs via similar pathways, which involve for propane dehydrogenation and for propene combustion increase in the sequence VOx/ZrO2

  16. Oxidative Remobilization of Technetium Sequestered by Sulfide...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Remobilization of Technetium Sequestered by Sulfide-Transformed Nano Zerovalent Iron. Oxidative Remobilization of Technetium Sequestered by Sulfide-Transformed Nano Zerovalent...

  17. Vapor phase modifiers for oxidative coupling

    DOE Patents [OSTI]

    Warren, B.K.

    1991-12-17T23:59:59.000Z

    Volatilized metal compounds are described which are capable of retarding vapor phase alkane conversion reactions in oxidative coupling processes that convert lower alkanes to higher hydrocarbons.

  18. Double perovskite catalysts for oxidative coupling

    DOE Patents [OSTI]

    Campbell, K.D.

    1991-01-01T23:59:59.000Z

    Alkali metal doped double perovskites containing manganese and at least one of cobalt, iron and nickel are useful in the oxidative coupling of alkane to higher hydrocarbons.

  19. Unfamiliar oxidation states and their stabilization

    E-Print Network [OSTI]

    Kleinberg, Jacob

    1950-01-01T23:59:59.000Z

    appropriate conditions, either of free metals or of ions in lower states, has served for the preparation of higher oxidation states. Reference has already been made to the formation of the ferrate ion, FeOf2, and of Ago, by the electrolytic oxidation... compartments (Fig. 2), indicates (according to calculations based on Faraday's law) that the metal leaving the electrode has an average oxidation number in the neighborhood of 2.5.* The alu- * Oxidation numbers as low as 1.9 have recently been obtained...

  20. Lanthanide doped barium phosphorous oxide scintillators

    DOE Patents [OSTI]

    Borade, Ramesh B; Bourret-Courchesne, Edith; Denzo, Stephen E

    2013-02-26T23:59:59.000Z

    The present invention provides for a composition comprising an inorganic scintillator comprising a lanthanide-doped barium phosphorous oxide useful for detecting nuclear material.

  1. Sandia National Laboratories: indium tin oxide

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    indium tin oxide Sandian Selected for Outstanding Engineer Award On December 10, 2014, in Energy, Materials Science, News, News & Events, Photovoltaic, Renewable Energy, Research &...

  2. The effect of valinomycin in fibroblasts from patients with fatty acid oxidation disorders

    SciTech Connect (OSTI)

    Ndukwe Erlingsson, Uzochi Chimdinma [Division of Medical Genetics, Department of Pediatrics, University of Utah, 2C412 SOM, 50 North Mario Capecchi Drive, Salt Lake City, UT 84132 (United States)] [Division of Medical Genetics, Department of Pediatrics, University of Utah, 2C412 SOM, 50 North Mario Capecchi Drive, Salt Lake City, UT 84132 (United States); Iacobazzi, Francesco [Division of Medical Genetics, Department of Pediatrics, University of Utah, 2C412 SOM, 50 North Mario Capecchi Drive, Salt Lake City, UT 84132 (United States) [Division of Medical Genetics, Department of Pediatrics, University of Utah, 2C412 SOM, 50 North Mario Capecchi Drive, Salt Lake City, UT 84132 (United States); Department of Basic Medical Sciences, University of Bari, Piazza Giulio Cesare 11, Policlinico, I-70124 Bari (Italy); Liu, Aiping [ARUP Institute for Clinical and Experimental Pathology, ARUP Laboratories, 500 Chipeta Way, Salt Lake City, UT 84108 (United States)] [ARUP Institute for Clinical and Experimental Pathology, ARUP Laboratories, 500 Chipeta Way, Salt Lake City, UT 84108 (United States); Ardon, Orly; Pasquali, Marzia [Division of Medical Genetics, Department of Pediatrics, University of Utah, 2C412 SOM, 50 North Mario Capecchi Drive, Salt Lake City, UT 84132 (United States) [Division of Medical Genetics, Department of Pediatrics, University of Utah, 2C412 SOM, 50 North Mario Capecchi Drive, Salt Lake City, UT 84132 (United States); ARUP Institute for Clinical and Experimental Pathology, ARUP Laboratories, 500 Chipeta Way, Salt Lake City, UT 84108 (United States); Department of Pathology, University of Utah, Salt Lake City, UT 84132 (United States); Longo, Nicola, E-mail: Nicola.Longo@hsc.utah.edu [Division of Medical Genetics, Department of Pediatrics, University of Utah, 2C412 SOM, 50 North Mario Capecchi Drive, Salt Lake City, UT 84132 (United States) [Division of Medical Genetics, Department of Pediatrics, University of Utah, 2C412 SOM, 50 North Mario Capecchi Drive, Salt Lake City, UT 84132 (United States); ARUP Institute for Clinical and Experimental Pathology, ARUP Laboratories, 500 Chipeta Way, Salt Lake City, UT 84108 (United States); Department of Pathology, University of Utah, Salt Lake City, UT 84132 (United States)

    2013-08-09T23:59:59.000Z

    Highlights: •Valinomycin can cause mitochondrial stress and stimulate fatty acid oxidation. •Cells with VLCAD deficiency fail to increase fatty acid oxidation in response to valinomycin. •Response to valinomycin can help in the diagnosis of VLCAD deficiency. -- Abstract: Disorders of the carnitine cycle and of the beta oxidation spiral impair the ability to obtain energy from fats at time of fasting and stress. This can result in hypoketotic hypoglycemia, cardiomyopathy, cardiac arrhythmia and other chronic medical problems. The in vitro study of fibroblasts from patients with these conditions is impaired by their limited oxidative capacity. Here we evaluate the capacity of valinomycin, a potassium ionophore that increases mitochondrial respiration, to increase the oxidation of fatty acids in cells from patients with inherited fatty acid oxidation defects. The addition of valinomycin to fibroblasts decreased the accumulation of the lipophilic cation tetraphenylphosphonium (TPP{sup +}) at low concentrations due to the dissipation of the mitochondrial membrane potential. At higher doses, valinomycin increased TPP{sup +} accumulation due to the increased potassium permeability of the plasma membrane and subsequent cellular hyperpolarization. The incubation of normal fibroblasts with valinomycin increased [{sup 14}C]-palmitate oxidation (measured as [{sup 14}C]O{sub 2} release) in a dose-dependent manner. By contrast, valinomycin failed to increase palmitate oxidation in fibroblasts from patients with very long chain acyl CoA dehydrogenase (VLCAD) deficiency. This was not observed in fibroblasts from patients heterozygous for this condition. These results indicate that valinomycin can increase fatty acid oxidation in normal fibroblasts and could be useful to differentiate heterozygotes from patients affected with VLCAD deficiency.

  3. The oxidative dimerization of methane over promoted and unpromoted magnesium oxide monoliths

    E-Print Network [OSTI]

    Aigler, Jane Marie

    1989-01-01T23:59:59.000Z

    for the degree of MASTER OF SCIENCE May 1989 Major Subject: Chemistry THE OXIDATIVE DIMERIZATION OF METHANE OVER PROMOTED AND UNPROMOTED MAGNESIUM OxiDE MONOLITHS A Thesis by JANE MARIE AIGLER Approved as to style and content by: uns or (Chair of Commi... ee) os e (Member) nt ony (Member) a (Head of Department) May 1989 ABSTRACT The Oxidative Dimerization of Methane over Promoted and Unpromoted Magnesium Oxide Monoliths. (May 1989) Jane Marie Aigier, B. S. , Pennsylvania State University...

  4. ARM - Measurements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem NotEnergy,ARMForms About Become a User Recovery ActgovMeasurements Measurement

  5. Polysaccharide Nanocomposites Reinforced with Graphene Oxide and Keratin-Grafted Graphene Oxide

    E-Print Network [OSTI]

    Polysaccharide Nanocomposites Reinforced with Graphene Oxide and Keratin-Grafted Graphene Oxide, chitosan-starch, and carboxymethyl cellulose-starch reinforced with graphene oxide and graphene grafted with keratin were developed. Composites films had been prepared for the casting/solvent evaporation method

  6. TIME DEPENDENT BREAKDOWN OF GATE OXIDE AND PREDICTION OF OXIDE GATE LIFETIME

    E-Print Network [OSTI]

    Mahmoodi, Hamid

    TIME DEPENDENT BREAKDOWN OF GATE OXIDE AND PREDICTION OF OXIDE GATE LIFETIME A thesis submitted Masters of Science In Engineering: Embedded System by Bin Wu San Francisco, California May, 2012 #12;CERTIFICATION OF APPROVAL I certify that I have read Time dependent Breakdown of Gate Oxide and Prediction

  7. Comparison of a thermospheric photochemical model with Student Nitric Oxide Explorer (SNOE) observations of nitric oxide

    E-Print Network [OSTI]

    Bailey, Scott

    and of time. There are two principal energy sources that lead to the production of nitric oxideComparison of a thermospheric photochemical model with Student Nitric Oxide Explorer (SNOE) observations of nitric oxide C. A. Barth Laboratory for Atmospheric and Space Physics, University of Colorado

  8. Single-Crystal Tungsten Oxide Nanosheets: Photochemical Water Oxidation in the Quantum Confinement Regime

    E-Print Network [OSTI]

    Osterloh, Frank

    Single-Crystal Tungsten Oxide Nanosheets: Photochemical Water Oxidation in the Quantum Confinement, catalysis, WO3, tungsten oxide, nanosheet, nanocrystal, quantum confinement, solar energy conversion INTRODUCTION Tungsten trioxide crystallizes in the ReO3 structure type and is an n-type semiconductor with a 2

  9. Fundamentals of Mercury Oxidation in Flue Gas

    SciTech Connect (OSTI)

    JoAnn Lighty; Geoffrey Silcox; Constance Senior; Joseph Helble; Balaji Krishnakumar

    2008-07-31T23:59:59.000Z

    The objective of this project was to understand the importance of and the contribution of gas-phase and solid-phase coal constituents in the mercury oxidation reactions. The project involved both experimental and modeling efforts. The team was comprised of the University of Utah, Reaction Engineering International, and the University of Connecticut. The objective was to determine the experimental parameters of importance in the homogeneous and heterogeneous oxidation reactions; validate models; and, improve existing models. Parameters studied include HCl, NO{sub x}, and SO{sub 2} concentrations, ash constituents, and temperature. The results suggested that homogeneous mercury oxidation is below 10% which is not consistent with previous data of others and work which was completed early in this research program. Previous data showed oxidation above 10% and up to 100%. However, the previous data are suspect due to apparent oxidation occurring within the sampling system where hypochlorite ion forms in the KCl impinger, which in turn oxidized mercury. Initial tests with entrained iron oxide particles injected into a flame reactor suggest that iron present on fly ash particle surfaces can promote heterogeneous oxidation of mercury in the presence of HCl under entrained flow conditions. Using the data generated above, with homogeneous reactions accounting for less than 10% of the oxidation, comparisons were made to pilot- and full-scale data. The results suggest that heterogeneous reactions, as with the case of iron oxide, and adsorption on solid carbon must be taking place in the full-scale system. Modeling of mercury oxidation using parameters from the literature was conducted to further study the contribution of homogeneous pathways to Hg oxidation in coal combustion systems. Calculations from the literature used rate parameters developed in different studies, in some cases using transition state theory with a range of approaches and basis sets, and in other cases using empirical approaches. To address this, rate constants for the entire 8-step homogeneous Hg oxidation sequence were developed using an internally consistent transition state approach. These rate constants when combined with the appropriate sub-mechanisms produced lower estimates of the overall extent of homogeneous oxidation, further suggesting that heterogeneous pathways play an important role in Hg oxidation in coal-fired systems.

  10. Durability Evaluation of Reversible Solid Oxide Cells

    SciTech Connect (OSTI)

    Xiaoyu Zhang; James E. O'Brien; Robert C. O'Brien; Gregory K. Housley

    2013-11-01T23:59:59.000Z

    An experimental investigation on the performance and durability of single solid oxide cells (SOCs) is under way at the Idaho National Laboratory. Reversible operation of SOCs includes electricity generation in the fuel cell mode and hydrogen generation in the electrolysis mode. Degradation is a more significant issue when operating SOCs in the electrolysis mode. In order to understand and mitigate the degradation issues in high temperature electrolysis, single SOCs with different configurations from several manufacturers have been evaluated for initial performance and long-term durability. A new test apparatus for single cell and small stack tests has been developed for this purpose. Cells were obtained from four industrial partners. Cells from Ceramatec Inc. and Materials and Systems Research Inc. (MSRI) showed improved durability in electrolysis mode compared to previous stack tests. Cells from Saint Gobain Advanced Materials Inc. (St. Gobain) and SOFCPower Inc. demonstrated stable performance in the fuel cell mode, but rapid degradation in the electrolysis mode, especially at high current density. Electrolyte-electrode delamination was found to have a significant impact on degradation in some cases. Enhanced bonding between electrolyte and electrode and modification of the electrode microstructure helped to mitigate degradation. Polarization scans and AC impedance measurements were performed during the tests to characterize cell performance and degradation.

  11. EURODISPLAY 2002 631 P-64: A Comparative Study of Metal Oxide Coated Indium-tin Oxide Anodes

    E-Print Network [OSTI]

    EURODISPLAY 2002 631 P-64: A Comparative Study of Metal Oxide Coated Indium-tin Oxide Anodes and Technology Clear Water Bay, Kowloon, Hong Kong Abstract Indium-tin oxide anodes capped with certain oxides-emitting diodes (OLEDs). The oxides of tin, zinc, praseodymium, yttrium, gallium, terbium and titanium have been

  12. Plant responses to phosphorus-deficiency stress: the role of organic acids in P mobilization from iron oxide and P acquisition by sorghum 

    E-Print Network [OSTI]

    Johnson, Sarah Elizabeth

    1999-01-01T23:59:59.000Z

    at pH 4.0, 5.5, and 7.0 by citric, malic, melodic, oxalic, succinct, and tartaric acids were measured. At low initial P-adsorption levels, ligand-induced dissolution of the oxide surface as the primary mechanism of P release from oxides was supported...

  13. Carbon oxidation state as a metric for describing the chemistry of atmospheric organic aerosol

    SciTech Connect (OSTI)

    Massachusetts Institute of Technology; Kroll, Jesse H.; Donahue, Neil M.; Jimenez, Jose L.; Kessler, Sean H.; Canagaratna, Manjula R.; Wilson, Kevin R.; Altieri, Katye E.; Mazzoleni, Lynn R.; Wozniak, Andrew S.; Bluhm, Hendrik; Mysak, Erin R.; Smith, Jared D.; Kolb, Charles E.; Worsnop, Douglas R.

    2010-11-05T23:59:59.000Z

    A detailed understanding of the sources, transformations, and fates of organic species in the environment is crucial because of the central roles that organics play in human health, biogeochemical cycles, and Earth's climate. However, such an understanding is hindered by the immense chemical complexity of environmental mixtures of organics; for example, atmospheric organic aerosol consists of at least thousands of individual compounds, all of which likely evolve chemically over their atmospheric lifetimes. Here we demonstrate the utility of describing organic aerosol (and other complex organic mixtures) in terms of average carbon oxidation state (OSC), a quantity that always increases with oxidation, and is readily measured using state-of-the-art analytical techniques. Field and laboratory measurements of OSC , using several such techniques, constrain the chemical properties of the organics and demonstrate that the formation and evolution of organic aerosol involves simultaneous changes to both carbon oxidation state and carbon number (nC).

  14. Apparatus and method for oxidizing organic materials

    DOE Patents [OSTI]

    Surma, J.E.; Bryan, G.H.; Geeting, J.G.H.; Butner, R.S.

    1998-01-13T23:59:59.000Z

    The invention is a method and apparatus using high cerium concentration in the anolyte of an electrochemical cell to oxidize organic materials. The method and apparatus further use an ultrasonic mixer to enhance the oxidation rate of the organic material in the electrochemical cell. 6 figs.

  15. REVERSIBLE SOLID OXIDE CELLS Mogens Mogensen1

    E-Print Network [OSTI]

    Chorkendorff2 and Torben Jacobsen3 1 Fuel Cell and Solid State Chemistry Department Risø National Laboratory The reversibility of solid oxide fuel cells (SOFC), i.e. that they could also work in the solid oxide electrolyser at a cell voltage of 1.48 V, which is the overall thermo-neutral voltage. Assuming an electricity cost of 3

  16. Nanocomposite of graphene and metal oxide materials

    DOE Patents [OSTI]

    Liu, Jun; Aksay, Ilhan A.; Choi, Daiwon; Wang, Donghai; Yang, Zhenguo

    2013-10-15T23:59:59.000Z

    Nanocomposite materials comprising a metal oxide bonded to at least one graphene material. The nanocomposite materials exhibit a specific capacity of at least twice that of the metal oxide material without the graphene at a charge/discharge rate greater than about 10 C.

  17. Nanocomposite of graphene and metal oxide materials

    DOE Patents [OSTI]

    Liu, Jun; Aksay, Ilhan A.; Choi, Daiwon; Wang, Donghai; Yang, Zhenguo

    2012-09-04T23:59:59.000Z

    Nanocomposite materials comprising a metal oxide bonded to at least one graphene material. The nanocomposite materials exhibit a specific capacity of at least twice that of the metal oxide material without the graphene at a charge/discharge rate greater than about 10C.

  18. Sulfur oxide adsorbents and emissions control

    DOE Patents [OSTI]

    Li, Liyu (Richland, WA); King, David L. (Richland, WA)

    2006-12-26T23:59:59.000Z

    High capacity sulfur oxide absorbents utilizing manganese-based octahedral molecular sieve (Mn--OMS) materials are disclosed. An emissions reduction system for a combustion exhaust includes a scrubber 24 containing these high capacity sulfur oxide absorbents located upstream from a NOX filter 26 or particulate trap.

  19. Measurement of \

    E-Print Network [OSTI]

    Aguilar-Arevalo, A A; Bazarko, A O; Brice, S J; Brown, B C; Bugel, L; Cao, J; Coney, L; Conrad, J M; Cox, D C; Curioni, A; Djurcic, Z; Finley, D A; Fleming, B T; Ford, R; Garcia, F G; Garvey, G T; Gonzales, J; Grange, J; Green, C; Green, J A; Hart, T L; Hawker, E; Imlay, R; Johnson, R A; Karagiorgi, G; Kasper, P; Katori, T; Kobilarcik, T; Kourbanis, I; Koutsoliotas, S; Laird, E M; Linden, S K; Link, J M; Liu, Y; Louis, W C; Mahn, K B M; Marsh, W; Mauger, C; McGary, V T; McGregor, G; Metcalf, W; Meyers, P D; Mills, F; Mills, G B; Monroe, J; Moore, C D; Mousseau, J; Nelson, R H; Nienaber, P; Nowak, J A; Osmanov, B; Ouedraogo, S; Patterson, R B; Pavlovic, Z; Perevalov, D; Polly, C C; Prebys, E; Raaf, J L; Ray, H; Roe, B P; Russell, A D; Sandberg, V; Schirato, R; Schmitz, D; Shaevitz, M H; Shoemaker, F C; Smith, D; Soderberg, M; Sorel, M; Spentzouris, P; Spitz, J; Stancu, I; Stefanski, R J; Sung, M; Tanaka, H A; Tayloe, R; Tzanov, M; Van de Water, R G; Wascko, M O; White, D H; Wilking, M J; Yang, H J; Zeller, G P; Zimmerman, E D

    2009-01-01T23:59:59.000Z

    MiniBooNE reports the first absolute cross sections for neutral current single \\pi^0 production on CH_2 induced by neutrino and antineutrino interactions measured from the largest sets of NC \\pi^0 events collected to date. The principal result consists of differential cross sections measured as functions of \\pi^0 momentum and \\pi^0 angle averaged over the neutrino flux at MiniBooNE. We find total cross sections of (4.76+/-0.05_{stat}+/-0.40_{sys})*10^{-40} cm^2/nucleon at a mean energy of =808 MeV and (1.48+/-0.05_{stat}+/-0.14_{sys})*10^{-40} cm^2/nucleon at a mean energy of =664 MeV for \

  20. Growth of Ordered Ultrathin Tungsten Oxide Films on Pt(111)....

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Growth of Ordered Ultrathin Tungsten Oxide Films on Pt(111). Growth of Ordered Ultrathin Tungsten Oxide Films on Pt(111). Abstract: Ordered tungsten oxide ultra-thin films were...

  1. Revealing the Nature of Emergent Ferromagnetism at an Oxide Heterointe...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    structures 6-8. LaAlO3 (lanthanum aluminium oxide, LAO) and SrTiO3 (strontium titanium oxide, STO) materials are perovskites, a class of mineral oxides whose unique...

  2. Micropatterning of Proteins and Mammalian Cells on Indium Tin Oxide

    E-Print Network [OSTI]

    Revzin, Alexander

    Micropatterning of Proteins and Mammalian Cells on Indium Tin Oxide Sunny S. Shah, Michael C and electrochemical activation to create micropatterned cocultures on indium tin oxide (ITO) substrates applications in tissue engineering and biosensing. KEYWORDS: indium tin oxide · photolithography · switchable

  3. Oxidation of carbynes: Signatures in infrared spectra

    SciTech Connect (OSTI)

    Cinquanta, E., E-mail: eugenio.cinquanta@mdm.imm.cnr.it, E-mail: p.rudolf@rug.nl [CIMAINA, University of Milan, Via Celoria 16, 20133 Milano (Italy); Department of Materials Science, University of Milan Bicocca, Via Cozzi 53, 20125 Milano (Italy); Manini, N.; Caramella, L.; Onida, G. [European Theoretical Spectroscopy Facility (ETSF), Via Celoria 16, 20133 Milano (Italy); Physics Department, University of Milan, Via Celoria 16, 20133 Milano (Italy); Ravagnan, L.; Milani, P. [CIMAINA, University of Milan, Via Celoria 16, 20133 Milano (Italy); Physics Department, University of Milan, Via Celoria 16, 20133 Milano (Italy); Rudolf, P., E-mail: eugenio.cinquanta@mdm.imm.cnr.it, E-mail: p.rudolf@rug.nl [Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747AG Groningen (Netherlands)

    2014-06-28T23:59:59.000Z

    We report and solidly interpret the infrared spectrum of both pristine and oxidized carbynes embedded in a pure-carbon matrix. The spectra probe separately the effects of oxidation on sp- and on sp{sup 2}-hybridized carbon, and provide information on the stability of the different structures in an oxidizing atmosphere. The final products are mostly short end-oxidized carbynes anchored with a double bond to sp{sup 2} fragments, plus an oxidized sp{sup 2} amorphous matrix. Our results have important implications for the realization of carbyne-based nano-electronics devices and highlight the active participation of carbynes in astrochemical reactions where they act as carbon source for the promotion of more complex organic species.

  4. Two Dimensional Polymer That Generates Nitric Oxide.

    DOE Patents [OSTI]

    McDonald, William F. (Utica, OH); Koren, Amy B. (Lansing, MI)

    2005-10-04T23:59:59.000Z

    A polymeric composition that generates nitric oxide and a process for rendering the surface of a substrate nonthrombogenic by applying a coating of the polymeric composition to the substrate are disclosed. The composition comprises: (1) a crosslinked chemical combination of (i) a polymer having amino group-containing side chains along a backbone forming the polymer, and (ii) a crosslinking agent containing functional groups capable of reacting with the amino groups; and (2) a plurality of nitric oxide generating functional groups associated with the crosslinked chemical combination. Once exposed to a physiological environment, the coating generates nitric oxide thereby inhibiting platelet aggregation. In one embodiment, the nitric oxide generating functional groups are provided by a nitrated compound (e.g., nitrocellulose) imbedded in the polymeric composition. In another embodiment, the nitric oxide generating functional groups comprise N2O2- groups covalently bonded to amino groups on the polymer.

  5. Electro-deposition of superconductor oxide films

    DOE Patents [OSTI]

    Bhattacharya, Raghu N. (Littleton, CO)

    2001-01-01T23:59:59.000Z

    Methods for preparing high quality superconducting oxide precursors which are well suited for further oxidation and annealing to form superconducting oxide films. The method comprises forming a multilayered superconducting precursor on a substrate by providing an electrodeposition bath comprising an electrolyte medium and a substrate electrode, and providing to the bath a plurality of precursor metal salts which are capable of exhibiting superconducting properties upon subsequent treatment. The superconducting precursor is then formed by electrodepositing a first electrodeposited (ED) layer onto the substrate electrode, followed by depositing a layer of silver onto the first electrodeposited (ED) layer, and then electrodepositing a second electrodeposited (ED) layer onto the Ag layer. The multilayered superconducting precursor is suitable for oxidation at a sufficient annealing temperature in air or an oxygen-containing atmosphere to form a crystalline superconducting oxide film.

  6. ARM - Measurements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadap Documentation TDMADAP : XDCnarrowbandheat flux ARM DatagovMeasurementsVisibility ARMProject

  7. ARM - Measurements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadap Documentation TDMADAP : XDCnarrowbandheat flux ARM DatagovMeasurementsVisibility

  8. OXIDATION OF MERCURY ACROSS SCR CATALYSTS IN COAL-FIRED POWER PLANTS BURNING LOW RANK FUELS

    SciTech Connect (OSTI)

    Constance Senior

    2004-12-31T23:59:59.000Z

    The objectives of this program were to measure the oxidation of mercury in flue gas across SCR catalyst in a coal-fired power plant burning low rank fuels using a slipstream reactor containing multiple commercial catalysts in parallel and to develop a greater understanding of mercury oxidation across SCR catalysts in the form of a simple model. The Electric Power Research Institute (EPRI) and Argillon GmbH provided co-funding for this program. REI used a multicatalyst slipstream reactor to determine oxidation of mercury across five commercial SCR catalysts at a power plant that burned a blend of 87% subbituminous coal and 13% bituminous coal. The chlorine content of the blend was 100 to 240 {micro}g/g on a dry basis. Mercury measurements were carried out when the catalysts were relatively new, corresponding to about 300 hours of operation and again after 2,200 hours of operation. NO{sub x}, O{sub 2} and gaseous mercury speciation at the inlet and at the outlet of each catalyst chamber were measured. In general, the catalysts all appeared capable of achieving about 90% NO{sub x} reduction at a space velocity of 3,000 hr{sup -1} when new, which is typical of full-scale installations; after 2,200 hours exposure to flue gas, some of the catalysts appeared to lose NO{sub x} activity. For the fresh commercial catalysts, oxidation of mercury was in the range of 25% to 65% at typical full-scale space velocities. A blank monolith showed no oxidation of mercury under any conditions. All catalysts showed higher mercury oxidation without ammonia, consistent with full-scale measurements. After exposure to flue gas for 2,200 hours, some of the catalysts showed reduced levels of mercury oxidation relative to the initial levels of oxidation. A model of Hg oxidation across SCRs was formulated based on full-scale data. The model took into account the effects of temperature, space velocity, catalyst type and HCl concentration in the flue gas.

  9. Oxidized film structure and method of making epitaxial metal oxide structure

    DOE Patents [OSTI]

    Gan, Shupan [Richland, WA; Liang, Yong [Richland, WA

    2003-02-25T23:59:59.000Z

    A stable oxidized structure and an improved method of making such a structure, including an improved method of making an interfacial template for growing a crystalline metal oxide structure, are disclosed. The improved method comprises the steps of providing a substrate with a clean surface and depositing a metal on the surface at a high temperature under a vacuum to form a metal-substrate compound layer on the surface with a thickness of less than one monolayer. The compound layer is then oxidized by exposing the compound layer to essentially oxygen at a low partial pressure and low temperature. The method may further comprise the step of annealing the surface while under a vacuum to further stabilize the oxidized film structure. A crystalline metal oxide structure may be subsequently epitaxially grown by using the oxidized film structure as an interfacial template and depositing on the interfacial template at least one layer of a crystalline metal oxide.

  10. Effect Of Oxidation On Chromium Leaching And Redox Capacity Of Slag-Containing Waste Forms

    SciTech Connect (OSTI)

    Almond, P. M.; Stefanko, D. B.; Langton, C. A.

    2013-03-01T23:59:59.000Z

    The rate of oxidation is important to the long-term performance of reducing salt waste forms because the solubility of some contaminants, e.g., technetium, is a function of oxidation state. TcO{sub 4}{sup ?} in the salt solution is reduced to Tc(IV) and has been shown to react with ingredients in the waste form to precipitate low solubility sulfide and/or oxide phases [Shuh, et al., 1994, Shuh, et al., 2000, Shuh, et al., 2003]. Upon exposure to oxygen, the compounds containing Tc(IV) oxidize to the pertechnetate ion, Tc(VII)O{sub 4}{sup ?}, which is very soluble. Consequently the rate of technetium oxidation front advancement into a monolith and the technetium leaching profile as a function of depth from an exposed surface are important to waste form performance and ground water concentration predictions. An approach for measuring contaminant oxidation rate (effective contaminant specific oxidation rate) based on leaching of select contaminants of concern is described in this report. In addition, the relationship between reduction capacity and contaminant oxidation is addressed. Chromate was used as a non-radioactive surrogate for pertechnetate in simulated waste form samples. Depth discrete subsamples were cut from material exposed to Savannah River Site (SRS) ''field cured'' conditions. The subsamples were prepared and analyzed for both reduction capacity and chromium leachability. Results from field-cured samples indicate that the depth at which leachable chromium was detected advanced further into the sample exposed for 302 days compared to the sample exposed to air for 118 days (at least 50 mm compared to at least 20 mm). Data for only two exposure time intervals is currently available. Data for additional exposure times are required to develop an equation for the oxidation front progression. Reduction capacity measurements (per the Angus-Glasser method, which is a measurement of the ability of a material to chemically reduce Ce(IV) to Ce(III) in solution) performed on depth discrete samples could not be correlated with the amount of chromium leached from the depth discrete subsamples or with the oxidation front inferred from soluble chromium (i.e., effective Cr oxidation front). Exposure to oxygen (air or oxygen dissolved in water) results in the release of chromium through oxidation of Cr(III) to highly soluble chromate, Cr(VI). Residual reduction capacity in the oxidized region of the test samples indicates that the remaining reduction capacity is not effective in re-reducing Cr(VI) in the presence of oxygen. Consequently, this method for determining reduction capacity may not be a good indicator of the effective contaminant oxidation rate in a relatively porous solid (40 to 60 volume percent porosity). The chromium extracted in depth discrete samples ranged from a maximum of about 5.8 % at about 5 mm (118 day exposure) to about 4 % at about 10 mm (302 day exposure). The use of reduction capacity as an indicator of long-term performance requires further investigation. The carbonation front was also estimated to have advanced to at least 28 mm in 302 days based on visual observation of gas evolution during acid addition during the reduction capacity measurements. Depth discrete sampling of materials exposed to realistic conditions in combination with short term leaching of crushed samples has potential for advancing the understanding of factors influencing performance and will support conceptual model development.

  11. Screening method for selecting semiconductor substrates having defects below a predetermined level in an oxide layer

    DOE Patents [OSTI]

    Warren, W.L.; Vanheusden, K.J.R.; Schwank, J.R.; Fleetwood, D.M.; Shaneyfelt, M.R.; Winokur, P.S.; Devine, R.A.B.

    1998-07-28T23:59:59.000Z

    A method is disclosed for screening or qualifying semiconductor substrates for integrated circuit fabrication. The method comprises the steps of annealing at least one semiconductor substrate at a first temperature in a defect-activating ambient (e.g. hydrogen, forming gas, or ammonia) for sufficient time for activating any defects within on oxide layer of the substrate; measuring a defect-revealing electrical characteristic of at least a portion of the oxide layer for determining a quantity of activated defects therein; and selecting substrates for which the quantity of activated defects is below a predetermined level. The defect-revealing electrical characteristic may be a capacitance-versus voltage (C-V) characteristic or a current-versus-voltage (I-V) characteristic that is dependent on an electrical charge in the oxide layer generated by the activated defects. Embodiments of the present invention may be applied for screening any type of semiconductor substrate or wafer having an oxide layer formed thereon or therein. This includes silicon-on-insulator substrates formed by a separation by the implantation of oxygen (SIMOX) process or the bond and etch back silicon-on-insulator (BESOI) process, as well as silicon substrates having a thermal oxide layer or a deposited oxide layer. 5 figs.

  12. An experimental and detailed chemical kinetic modelling study of 2methyl furan oxidation

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    be burned pure in current internal combustion engines with similar performance to gasoline. Measurements Glaudeb , Henry J. Currana a Combustion Chemistry Centre, School of Chemistry, NUI Galway, Ireland the oxidation of any of the alkylated furans. The mechanism developed herein to describe 2MF combustion should

  13. Computational Prediction of One-Electron Reduction Potentials and Acid Dissociation Constants for Guanine Oxidation Intermediates

    E-Print Network [OSTI]

    Schlegel, H. Bernhard

    of Chemistry, Wayne State University, Detroit, Michigan 48202, United States *S Supporting Information ABSTRACT, and cellular death.1-9 Among the canonical nucleobases, guanine is well-known to be the most susceptible at a constant pH of 7 (E7). Redox potentials were obtained by chemical oxidation and kinetic rate measurements

  14. High-Temperature Thermoelectric Characterization of IIIV Semiconductor Thin Films by Oxide Bonding

    E-Print Network [OSTI]

    High-Temperature Thermoelectric Characterization of III­V Semiconductor Thin Films by Oxide Bonding and measurement method utilizing a SiO2­SiO2 covalent bonding technique is presented for high-temperature surface passivation, and metallization with a Ti-W-N diffusion barrier. A thermoelectric material, thin

  15. Exercise training reverses age-induced inducible nitric oxide synthase upregulation

    E-Print Network [OSTI]

    Song, Wook

    2005-02-17T23:59:59.000Z

    muscle, and 2) to identify the mechanisms by which exercise training reduces pro-oxidant signaling. Protein levels and activity of iNOS were measured in 4 groups of male Fischer-344 rats (5 mo and 24 mo, n=10/group), old-control (OC), old-trained (OT...

  16. Excited-state energy transfer pathways in photosynthetic reaction centers: 5. Oxidized and triplet

    E-Print Network [OSTI]

    Boxer, Steven G.

    - spectively, are similar to that for energy transfer to 1 P ($190 fs)À1 in wild type measured by eitherExcited-state energy transfer pathways in photosynthetic reaction centers: 5. Oxidized and triplet excited special pairs as energy acceptors Brett A. King, Tim B. McAnaney, Alex de Winter, Steven G. Boxer

  17. A Theoretical Study of Methanol Oxidation Catalyzed by Isolated...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methanol Oxidation Catalyzed by Isolated Vanadia Clusters Supported on the (101) Surface of Anatase. A Theoretical Study of Methanol Oxidation Catalyzed by Isolated Vanadia...

  18. Global kinetics for a commercial diesel oxidation catalyst with...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    kinetics for a commercial diesel oxidation catalyst with two exhaust hydrocarbons Global kinetics for a commercial diesel oxidation catalyst with two exhaust hydrocarbons...

  19. National Energy Technology Laboratory Publishes Solid Oxide Fuel...

    Broader source: Energy.gov (indexed) [DOE]

    National Energy Technology Laboratory Publishes Solid Oxide Fuel Cell Studies What does this project do? For more information on DOE's efforts to make solid oxide fuel cells an...

  20. Interactions of nickel/zirconia solid oxide fuel cell anodes...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Interactions of nickelzirconia solid oxide fuel cell anodes with coal gas containing arsenic. Interactions of nickelzirconia solid oxide fuel cell anodes with coal gas containing...

  1. Radiation Stability of Nanoclusters in Nano-structured Oxide...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    oxide dispersion strengthened (ODS) steels are considered candidates for nuclear fission and fusion applications at high temperature and dose. The complex oxide...

  2. Phosphine Oxide Based Electron Transporting and Hole Blocking...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oxide Based Electron Transporting and Hole Blocking Materials for Blue Electrophosphorescent Organic Light Emitting Phosphine Oxide Based Electron Transporting and Hole Blocking...

  3. Phosphine oxide derivatives as hosts for blue phosphors: A joint...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    oxide derivatives as hosts for blue phosphors: A joint theoretical and experimental study of their electronic Phosphine oxide derivatives as hosts for blue phosphors: A joint...

  4. In-Situ Transmission Electron Microscopy Probing of Native Oxide...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Probing of Native Oxide and Artificial Layers on Silicon Nanoparticles for Lithium Ion In-Situ Transmission Electron Microscopy Probing of Native Oxide and Artificial...

  5. Impact of the Fuel Molecular Structure on the Oxidation Process...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    on the Oxidation Process of Real Diesel fuels According to Storage Conditions and Biodiesel Content Impact of the Fuel Molecular Structure on the Oxidation Process of Real...

  6. Distance-dependent radiation chemistry: Oxidation versus hydrogenation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Distance-dependent radiation chemistry: Oxidation versus hydrogenation of CO in electron-irradiated H2OCOH2O ices. Distance-dependent radiation chemistry: Oxidation versus...

  7. Photoluminescence Properties of Alkaline-Earth Oxide Nanoparticles...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Properties of Alkaline-Earth Oxide Nanoparticles. Photoluminescence Properties of Alkaline-Earth Oxide Nanoparticles. Abstract: Previous experiments have demonstrated that...

  8. Exfoliation of Graphite Oxide in Propylene Carbonate and Thermal

    E-Print Network [OSTI]

    Exfoliation of Graphite Oxide in Propylene Carbonate and Thermal Reduction of the Resulting Chemical Society ABSTRACT Graphite oxide was exfoliated and dispersed in propylene carbonate (PC) by bath

  9. Morphology and Electronic Structure of the Oxide Shell on the...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electronic Structure of the Oxide Shell on the Surface of Iron Nanoparticles. Morphology and Electronic Structure of the Oxide Shell on the Surface of Iron Nanoparticles. Abstract:...

  10. Morphology and Oxide Shell Structure of Iron Nanoparticles Grown...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oxide Shell Structure of Iron Nanoparticles Grown by Sputter-Gas-Aggregation. Morphology and Oxide Shell Structure of Iron Nanoparticles Grown by Sputter-Gas-Aggregation. Abstract:...

  11. Oxidative Dissolution of UO2 in a Simulated Groundwater Containing...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    under oxic conditions. Field and laboratory studies have implicated iron sulfide minerals as redox buffers or oxidant scavengers that may slow oxidation of reduced U(VI) solid...

  12. Advanced Materials for Reversible Solid Oxide Fuel Cell (RSOFC...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Reversible Solid Oxide Fuel Cell (RSOFC), Dual Mode Operation with Low Degradation Advanced Materials for Reversible Solid Oxide Fuel Cell (RSOFC), Dual Mode Operation with Low...

  13. Cryogenic CO2 Formation on Oxidized Gold Clusters Synthesized...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cryogenic CO2 Formation on Oxidized Gold Clusters Synthesized via Reactive Layer Assisted Deposition. Cryogenic CO2 Formation on Oxidized Gold Clusters Synthesized via Reactive...

  14. Observation of green emission from Ce3+ doped gadolinium oxide...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    green emission from Ce3+ doped gadolinium oxide nanoparticles. Observation of green emission from Ce3+ doped gadolinium oxide nanoparticles. Abstract: Green emission at around 500...

  15. Polyelectrolyte-Induced Reduction of Exfoliated Graphite Oxide...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reduction of Exfoliated Graphite Oxide: A Facile Route to Synthesis of Soluble Graphene Nanosheets. Polyelectrolyte-Induced Reduction of Exfoliated Graphite Oxide: A Facile...

  16. Nanocomposite of graphene and metal oxide materials | OSTI, US...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanocomposite of graphene and metal oxide materials Re-direct Destination: Nanocomposite materials comprising a metal oxide bonded to at least one graphene material. The...

  17. Solid Oxide Membrane (SOM) Electrolysis of Magnesium: Scale-Up...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oxide Membrane (SOM) Electrolysis of Magnesium: Scale-Up Research and Engineering for Light-Weight Vehicles Solid Oxide Membrane (SOM) Electrolysis of Magnesium: Scale-Up Research...

  18. aluminum oxide layer: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALUMINUM OXIDE FOR THE SURFACE PASSIVATION OF HIGH-EFFICIENCY SILICON SOLAR CELLS Renewable Energy Websites Summary: ATOMIC-LAYER-DEPOSITED ALUMINUM OXIDE FOR THE...

  19. aluminum oxide layers: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALUMINUM OXIDE FOR THE SURFACE PASSIVATION OF HIGH-EFFICIENCY SILICON SOLAR CELLS Renewable Energy Websites Summary: ATOMIC-LAYER-DEPOSITED ALUMINUM OXIDE FOR THE...

  20. Burning Modes and Oxidation Rates of Soot: Relevance to Diesel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DPF Systems: Understanding the Soot Oxidation Process Application of the AT Research Capabilities: Investigation of Diesel Soot Oxidation and of the Catalysts Degradation...

  1. Diesel Particulate Oxidation Model: Combined Effects of Fixed...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oxidation Model: Combined Effects of Fixed & Volatile Carbon Diesel Particulate Oxidation Model: Combined Effects of Fixed & Volatile Carbon Poster presented at the 16th Directions...

  2. Effects of Diesel Exhaust Emissions on Soot Oxidation and DPF...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Diesel Exhaust Emissions on Soot Oxidation and DPF Regeneration Effects of Diesel Exhaust Emissions on Soot Oxidation and DPF Regeneration DPF regeneration experiments verified the...

  3. Atomic-Structural Synergy for Catalytic CO Oxidation over Palladium...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atomic-Structural Synergy for Catalytic CO Oxidation over Palladium-Nickel Nanoalloys. Atomic-Structural Synergy for Catalytic CO Oxidation over Palladium-Nickel Nanoalloys....

  4. advanced oxidation protein: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Information Sciences Websites Summary: 12OC-2001-02 New Cu-diffusion Barrier Materials Based on Ruthenium, Iridium and its Oxides Advancedruthenium oxide and iridium...

  5. Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control Catalysts Monolithic Metal Oxide based Composite Nanowire Lean NOx Emission Control Catalysts Presents...

  6. aluminum oxide membrane: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    aluminum oxide grown on the Fe at 850 C forms a homogeneous hexagonal oxide film with a thickness of approximately 10 ?. Core level 38 Development of novel...

  7. Advanced Oxidation & Stabilization of PAN-Based Carbon Precursor...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Advanced Oxidation & Stabilization of PAN-Based Carbon Precursor Fibers Vehicle Technologies Office Merit Review 2014: Advanced Oxidation &...

  8. Advanced Oxidation & Stabilization of PAN-Based Carbon Precursor...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Advanced Oxidation & Stabilization of PAN-Based Carbon Precursor Fibers Advanced Oxidation & Stabilization of PAN-Based Carbon Precursor...

  9. Synthesis of Nanodispersed Oxides of Vanadium, Titanium, Molybdenum...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanodispersed Oxides of Vanadium, Titanium, Molybdenum, and Tungsten on Mesoporous Silica using Atomic Layer Synthesis of Nanodispersed Oxides of Vanadium, Titanium, Molybdenum,...

  10. Thickness dependent self limiting 1-D tin oxide nanowire arrays...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    dependent self limiting 1-D tin oxide nanowire arrays by nanosecond pulsed laser irradiation. Thickness dependent self limiting 1-D tin oxide nanowire arrays by nanosecond pulsed...

  11. Improved Stability Of Amorphous Zinc Tin Oxide Thin Film Transistors...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stability Of Amorphous Zinc Tin Oxide Thin Film Transistors Using Molecular Passivation. Improved Stability Of Amorphous Zinc Tin Oxide Thin Film Transistors Using Molecular...

  12. Low-Temperature Carbon Monoxide Oxidation Catalysed by Regenerable...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oxidation Catalysed by Regenerable Atomically Dispersed Palladium on Alumina. Low-Temperature Carbon Monoxide Oxidation Catalysed by Regenerable Atomically Dispersed Palladium...

  13. High surface area, electrically conductive nanocarbon-supported metal oxide

    DOE Patents [OSTI]

    Worsley, Marcus A; Han, Thomas Yong-Jin; Kuntz, Joshua D; Cervanted, Octavio; Gash, Alexander E; Baumann, Theodore F; Satcher, Jr., Joe H

    2014-03-04T23:59:59.000Z

    A metal oxide-carbon composite includes a carbon aerogel with an oxide overcoat. The metal oxide-carbon composite is made by providing a carbon aerogel, immersing the carbon aerogel in a metal oxide sol under a vacuum, raising the carbon aerogel with the metal oxide sol to atmospheric pressure, curing the carbon aerogel with the metal oxide sol at room temperature, and drying the carbon aerogel with the metal oxide sol to produce the metal oxide-carbon composite. The step of providing a carbon aerogel can provide an activated carbon aerogel or provide a carbon aerogel with carbon nanotubes that make the carbon aerogel mechanically robust.

  14. Stability Of Nanoclusters In 14YWT Oxide Dispersion Strengthened...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stability Of Nanoclusters In 14YWT Oxide Dispersion Strengthened Steel Under Heavy Ion-irradiation By Atom Probe Tomography. Stability Of Nanoclusters In 14YWT Oxide Dispersion...

  15. Performance of solid oxide fuel cells operated with coal syngas...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Performance of solid oxide fuel cells operated with coal syngas provided directly from a gasification process. Performance of solid oxide fuel cells operated with coal syngas...

  16. ameliorates oxidative stress: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ambient Air Pollution is Associated with Increased Exhaled Nitric Oxide in Children with Asthma University of California eScholarship Repository Summary: oxidative stress in...

  17. EIS-0360: Depleted Uranium Oxide Conversion Product at the Portsmouth...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    60: Depleted Uranium Oxide Conversion Product at the Portsmouth, Ohio Site EIS-0360: Depleted Uranium Oxide Conversion Product at the Portsmouth, Ohio Site Summary This...

  18. SciTech Connect: Energy Transfer and Cytochrome Oxidation in...

    Office of Scientific and Technical Information (OSTI)

    Energy Transfer and Cytochrome Oxidation in Green Bacteria Citation Details In-Document Search Title: Energy Transfer and Cytochrome Oxidation in Green Bacteria In this paper we...

  19. Systems Virology Identifies a Mitochondrial Fatty Acid Oxidation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fatty Acid Oxidation Enyzme, Dodecenoyl Coenzyme A Delta Isomerase, Required for Systems Virology Identifies a Mitochondrial Fatty Acid Oxidation Enyzme, Dodecenoyl Coenzyme...

  20. anaerobic ethanol oxidation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    production from organic waste by wet oxidation pre-oxidation treatment of organic household waste enriched withwaste feedstock (from 25 to 36%) was unknown impurities, such as...

  1. The cycling and oxidation pathways of organic carbon in a shallow estuary along the Texas Gulf Coast

    SciTech Connect (OSTI)

    Warnken, Kent W.; Santschi, Peter H.; Roberts, Kimberly A.; Gill, Gary A.

    2007-08-08T23:59:59.000Z

    The cycling and oxidation pathways of organic carbon were investigated at a single shallow water estuarine site in Trinity Bay, Texas, the uppermost lobe of Galveston Bay, during November 2000. Radio-isotopes were used to estimate sediment mixing and accumulation rates, and benthic chamber and pore water measurements were used to determine sediment-water exchange fluxes of oxygen, nutrients and metals, and infer carbon oxidation rates.

  2. High-Affinity and Cooperative Binding of Oxidized Calmodulin by Methionine Sulfoxide Reductase

    SciTech Connect (OSTI)

    Xiong, Yijia; Chen, Baowei; Smallwood, Heather S.; Urbauer, Ramona J.; Markillie, Lye Meng; Galeva, Nadezhda A.; Williams, Todd D.; Squier, Thomas C.

    2006-12-12T23:59:59.000Z

    Methionines play an important role in modulating protein-protein interactions associated with intracellular signaling, and their reversible oxidation to form methionine sulfoxides [Met(O)] in calmodulin (CaM) and other signaling proteins has been suggested to couple cellular redox changes to protein function changes through the action of methionine sulfoxide reductases (Msr). Prior measurements indicate the full recovery of target protein activation upon the stereospecific reduction of oxidized CaM by MsrA, where the formation of the S-stereoisomer of Met(O) selectively inhibits the CaM-dependent activation of the Ca-ATPase. However, the physiological substrates of MsrA remain unclear, as neither the binding specificities nor affinities of protein targets have been measured. To assess the specificity of binding and its possible importance in the maintenance of CaM function, we have measured the kinetics of repair and the binding affinity between oxidized CaM and MsrA. Reduction of Met(O) in fully oxidized CaM by MsrA is sensitive to protein folding, as repair of the intact protein is incomplete, with > 6 Met(O) remaining in each CaM following MsrA reduction. In contrast, following proteolytic digestion, MsrA is able to fully reduce one-half of the oxidized methionines, indicating that Met(O) within folded proteins are not substrates for MsrA repair. Further, in comparison to free Met(O), the turnover number and Km for oxidized CaM (CaMox) are substantially smaller, indicating that the binding interaction retards Msr recycling to reduce steady-state enzyme activity. Mutation of the active site (i.e., C72S) in MsrA permitted equilibrium-binding measurements using both ensemble and single-molecule measurements obtained by fluorescence correlation spectroscopy (FCS). Multiple MsrA bind tightly to CaMox (Kd = 70 +- 10 nM) with an affinity that is three orders of magnitude greater than the Michaelis constant (KM = 71 +- 8 micromolar). These results indicate that MsrA selectively reduces surface-exposed Met(O) within unstructured sequences and suggest that only a small subset of oxidized proteins are substrates for MsrA, which may selectively modulate the function of key signaling proteins as part of an adaptive response to oxidative stress.

  3. ARM - Measurements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa- PolarizationgovCampaignsSummergovField CampaignsMidlatitudegovMeasurementsSurface

  4. Evaluation of Oxidation and Hydrogen Permeation of Al Containing Duplex Stainless Steels

    SciTech Connect (OSTI)

    Adams, Thad M.; Korinko, Paul; Duncan, Andrew

    2005-06-17T23:59:59.000Z

    As the National Hydrogen Economy continues to develop and evolve the need for structural materials that can resist hydrogen assisted degradation will become critical. To date austenitic stainless steel materials have been shown to be mildly susceptible to hydrogen attack which results in lower mechanical and fracture strengths. As a result, hydrogen permeation barrier coatings are typically applied to these steel to retard hydrogen ingress. The focal point of the reported work was to evaluate the potential for intentional alloying of commercial 300-series stainless steels to promote hydrogen permeation resistant oxide scales. Previous research on the Cr- and Fe-oxide scales inherent to 300-series stainless steels has proven to be inconsistent in effecting permeation resistance. The approach undertaken in this research was to add aluminum to the 300-series stainless steels in an attempt to promote a pure Al-oxide or and Al-rich oxide scale. Aloxide had been previously demonstrated to be an effective hydrogen permeation barrier. Results for 304L and 347H alloys doped with Al in concentration from 0.5-3.0 wt% with respect to oxidation kinetic studies, cyclic oxidation and characterization of the oxide scale chemistry are reported herein. Gaseous hydrogen permeation testing of the Al-doped alloys in both the unoxidized and oxidized (600 C, 30 mins) conditions are reported. A critical finding from this work is that at concentration as low as 0.5 wt% Al, the Al stabilizes the ferrite phase in these steels thus producing duplex austenitic-ferritic microstructures. As the Al-content increases the amount of measured ferrite increases thus resulting in hydrogen permeabilities more closely resembling ferritic steels.

  5. A Big Response to a “Small” Problem: Identifying the Oxidative Potential of Nanomaterials and the Physicochemical Characteristics That Play a Role 

    E-Print Network [OSTI]

    Berg, James Michael

    2012-02-14T23:59:59.000Z

    of nanoparticles influential in toxicological studies, surface properties of metal oxide and carbonaceous nanoparticles were measured. These properties include zeta potential, dissolution and surface-bound chemical components. Subsequently, the role...

  6. Composite catalyst for carbon monoxide and hydrocarbon oxidation

    DOE Patents [OSTI]

    Liu, Wei (Cambridge, MA); Flytzani-Stephanopoulos, Maria (Winchester, MA)

    1996-01-01T23:59:59.000Z

    A method and composition for the complete oxidation of carbon monoxide and/or hydrocarbon compounds. The method involves reacting the carbon monoxide and/or hydrocarbons with an oxidizing agent in the presence of a metal oxide composite catalyst. The catalyst is prepared by combining fluorite-type oxygen ion conductors with active transition metals. The fluorite oxide, selected from the group consisting of cerium oxide, zirconium oxide, thorium oxide, hafnium oxide, and uranium oxide, and may be doped by alkaline earth and rare earth oxides. The transition metals, selected from the group consisting of molybdnum, copper, cobalt, maganese, nickel, and silver, are used as additives. The atomic ratio of transition metal to fluorite oxide is less than one.

  7. Composite catalyst for carbon monoxide and hydrocarbon oxidation

    DOE Patents [OSTI]

    Liu, W.; Flytzani-Stephanopoulos, M.

    1996-03-19T23:59:59.000Z

    A method and composition are disclosed for the complete oxidation of carbon monoxide and/or hydrocarbon compounds. The method involves reacting the carbon monoxide and/or hydrocarbons with an oxidizing agent in the presence of a metal oxide composite catalyst. The catalyst is prepared by combining fluorite-type oxygen ion conductors with active transition metals. The fluorite oxide, selected from the group consisting of cerium oxide, zirconium oxide, thorium oxide, hafnium oxide, and uranium oxide, and may be doped by alkaline earth and rare earth oxides. The transition metals, selected from the group consisting of molybdenum, copper, cobalt, manganese, nickel, and silver, are used as additives. The atomic ratio of transition metal to fluorite oxide is less than one.

  8. Emergent Phenomena at Oxide Interfaces

    SciTech Connect (OSTI)

    Hwang, H.Y.

    2012-02-16T23:59:59.000Z

    Transition metal oxides (TMOs) are an ideal arena for the study of electronic correlations because the s-electrons of the transition metal ions are removed and transferred to oxygen ions, and hence the strongly correlated d-electrons determine their physical properties such as electrical transport, magnetism, optical response, thermal conductivity, and superconductivity. These electron correlations prohibit the double occupancy of metal sites and induce a local entanglement of charge, spin, and orbital degrees of freedom. This gives rise to a variety of phenomena, e.g., Mott insulators, various charge/spin/orbital orderings, metal-insulator transitions, multiferroics, and superconductivity. In recent years, there has been a burst of activity to manipulate these phenomena, as well as create new ones, using oxide heterostructures. Most fundamental to understanding the physical properties of TMOs is the concept of symmetry of the order parameter. As Landau recognized, the essence of phase transitions is the change of the symmetry. For example, ferromagnetic ordering breaks the rotational symmetry in spin space, i.e., the ordered phase has lower symmetry than the Hamiltonian of the system. There are three most important symmetries to be considered here. (i) Spatial inversion (I), defined as r {yields} -r. In the case of an insulator, breaking this symmetry can lead to spontaneous electric polarization, i.e. ferroelectricity, or pyroelectricity once the point group belongs to polar group symmetry. (ii) Time-reversal symmetry (T) defined as t {yields} -t. In quantum mechanics, the time-evolution of the wave-function {Psi} is given by the phase factor e{sup -iEt/{h_bar}} with E being the energy, and hence time-reversal basically corresponds to taking the complex conjugate of the wave-function. Also the spin, which is induced by the 'spinning' of the particle, is reversed by time-reversal. Broken T-symmetry is most naturally associated with magnetism, since the spin operator changes sign with T-operation. (iii) Gauge symmetry (G), which is associated with a change in the phase of the wave-function as {Psi} {yields} e{sup i{theta}}{Psi}. Gauge symmetry is connected to the law of charge conservation, and broken G-symmetry corresponds to superconductivity/superfluidity. To summarize, the interplay among these electronic degrees of freedom produces various forms of symmetry breaking patterns of I, T, and G, leading to novel emergent phenomena, which can appear only by the collective behavior of electrons and cannot be expected from individual electrons. Figure 1 shows this schematically by means of several representative phenomena. From this viewpoint, the interfaces of TMOs offer a unique and important laboratory because I is already broken by the structure itself, and the detailed form of broken I-symmetry can often be designed. Also, two-dimensionality usually enhances the effects of electron correlations by reducing their kinetic energy. These two features of oxide interfaces produce many novel effects and functions that cannot be attained in bulk form. Given that the electromagnetic responses are a major source of the physical properties of solids, and new gauge structures often appear in correlated electronic systems, we put 'emergent electromagnetism' at the center of Fig. 1.

  9. Electro Catalytic Oxidation (ECO) Operation

    SciTech Connect (OSTI)

    Morgan Jones

    2011-03-31T23:59:59.000Z

    The power industry in the United States is faced with meeting many new regulations to reduce a number of air pollutants including sulfur dioxide, nitrogen oxides, fine particulate matter, and mercury. With over 1,000 power plants in the US, this is a daunting task. In some cases, traditional pollution control technologies such as wet scrubbers and SCRs are not feasible. Powerspan's Electro-Catalytic Oxidation, or ECO{reg_sign} process combines four pollution control devices into a single integrated system that can be installed after a power plant's particulate control device. Besides achieving major reductions in emissions of sulfur dioxide (SO{sub 2}), nitrogen oxides (NOx), fine particulate matter (PM2.5) and mercury (Hg), ECO produces a highly marketable fertilizer, which can help offset the operating costs of the process system. Powerspan has been operating a 50-MW ECO commercial demonstration unit (CDU) at FirstEnergy Corp.'s R.E. Burger Plant near Shadyside, Ohio, since February 2004. In addition to the CDU, a test loop has been constructed beside the CDU to demonstrate higher NOx removal rates and test various scrubber packing types and wet ESP configurations. Furthermore, Powerspan has developed the ECO{reg_sign}{sub 2} technology, a regenerative process that uses a proprietary solvent to capture CO{sub 2} from flue gas. The CO{sub 2} capture takes place after the capture of NOx, SO{sub 2}, mercury, and fine particulate matter. Once the CO{sub 2} is captured, the proprietary solution is regenerated to release CO{sub 2} in a form that is ready for geological storage or beneficial use. Pilot scale testing of ECO{sub 2} began in early 2009 at FirstEnergy's Burger Plant. The ECO{sub 2} pilot unit is designed to process a 1-MW flue gas stream and produce 20 tons of CO{sub 2} per day, achieving a 90% CO{sub 2} capture rate. The ECO{sub 2} pilot program provided the opportunity to confirm process design and cost estimates, and prepare for large scale capture and sequestration projects. The objectives of this project were to prove at a commercial scale that ECO is capable of extended operations over a range of conditions, that it meets the reliability requirements of a typical utility, and that the fertilizer co-product can be consistently generated, providing ECO with an economic advantage over conventional technologies currently available. Further objectives of the project were to show that the ECO system provides flue gas that meets the inlet standards necessary for ECO{sub 2} to operate, and that the outlet CO{sub 2} and other constituents produced by the ECO{sub 2} pilot can meet Kinder-Morgan pipeline standards for purposes of sequestration. All project objectives are consistent with DOE's Pollution Control Innovations for Power Plants program goals.

  10. PERFORMANCE OF THE SAVANNAH RIVER SITE COULOMETER FOR NEPTUNIUM PROCESSACCOUNTABILITY AND NEPTUNIUM OXIDE PRODUCT CHARACTERIZATION

    SciTech Connect (OSTI)

    Holland, M; Patterson Nuessle, P; Sheldon Nichols, S; Joe Cordaro, J; George Reeves, G

    2008-06-04T23:59:59.000Z

    The Savannah River Site's (SRS) H-Area B-Line (HB-Line) nuclear facility is processing neptunium solutions for stabilization as an oxide. The oxide will eventually be reprocessed and fabricated into target material and the 237Np irradiated to produce {sup 238}Pu in support of National Aeronautics and Space Administration space program missions. As part of nuclear materials accountability, solution concentrations were measured using a high-precision controlled-potential coulometer developed and manufactured at the SRS for plutonium accountability measurements. The Savannah River Site Coulometer system and measurement methodology for plutonium meets performance standards in ISO 12183-2005, 'Controlled-Potential Coulometric Assay of Plutonium'. The Department of Energy (DOE) does not produce or supply a neptunium metal certified reference material, which makes qualifying a measurement method and determining accuracy and precision difficult. Testing and performance of the Savannah River Site Coulometer indicates that it can be used to measure neptunium process solutions and dissolved neptunium oxide without purification for material control and accountability purposes. Savannah River Site's Material Control and Accountability organization has accepted the method uncertainty for accountability and product characterization measurements.

  11. Synthesis and characterization of nanostructured transition metal oxides for energy storage devices

    E-Print Network [OSTI]

    Kim, Jong Woung

    2012-01-01T23:59:59.000Z

    nanostructured transition metal oxides for energy storage devicesnanostructured transition metal oxides for energy storage devices

  12. Method for producing metal oxide nanoparticles

    DOE Patents [OSTI]

    Phillips, Jonathan (Santa Fe, NM); Mendoza, Daniel (Santa Fe, NM); Chen, Chun-Ku (Albuquerque, NM)

    2008-04-15T23:59:59.000Z

    Method for producing metal oxide nanoparticles. The method includes generating an aerosol of solid metallic microparticles, generating plasma with a plasma hot zone at a temperature sufficiently high to vaporize the microparticles into metal vapor, and directing the aerosol into the hot zone of the plasma. The microparticles vaporize in the hot zone into metal vapor. The metal vapor is directed away from the hot zone and into the cooler plasma afterglow where it oxidizes, cools and condenses to form solid metal oxide nanoparticles.

  13. Oxidation of Organic Compounds in the Soil.

    E-Print Network [OSTI]

    Fraps, G. S. (George Stronach)

    1915-01-01T23:59:59.000Z

    oxidized to nitrates. The direct study of the changes in organic matter or carbon in the soil is more satisfactory than any assumption. A considerable amount of work upon the oxidation of organic matter in the soil has been clone hy Wollny... cflpo8city, so the re1ati~-e power of the soil to support oxidizing organisms ma!r he termed its oxidafion cnpaciiy. The nitrif-ing capac- it" the oxidatioa capacity 'and the capacit~ of the soil to convert am- monia into nitrates and ammonia are to a...

  14. Effects of photochemical formation of mercuric oxide

    SciTech Connect (OSTI)

    Granite, E.J.; Pennline, H.W.; Hoffman, J.S.

    1999-12-01T23:59:59.000Z

    The photochemistry of elemental mercury and oxygen was examined using quartz flow reactors. Germicidal bulbs were used as the source of 253.7-nm ultraviolet radiation. The formation of mercuric oxide, as visually detected by yellow-brown stains on the quartz walls, was confirmed by both ICP-AES and SEM-EDX analyses. In addition, a high surface area calcium silicate sorbent was used to capture the mercuric oxide in one of the experiments. The implications of mercuric oxide formation with respect to analysis of gases for mercury content, atmospheric reactions, and direct ultraviolet irradiation of flue gas for mercury sequestration are discussed.

  15. Synthesis of transparent conducting oxide coatings

    DOE Patents [OSTI]

    Elam, Jeffrey W.; Martinson, Alex B. F.; Pellin, Michael J.; Hupp, Joseph T.

    2010-05-04T23:59:59.000Z

    A method and system for preparing a light transmitting and electrically conductive oxide film. The method and system includes providing an atomic layer deposition system, providing a first precursor selected from the group of cyclopentadienyl indium, tetrakis (dimethylamino) tin and mixtures thereof, inputting to the deposition system the first precursor for reaction for a first selected time, providing a purge gas for a selected time, providing a second precursor comprised of an oxidizer, and optionally inputting a second precursor into the deposition system for reaction and alternating for a predetermined number of cycles each of the first precursor, the purge gas and the second precursor to produce the oxide film.

  16. Plasma gasification of coal in different oxidants

    SciTech Connect (OSTI)

    Matveev, I.B.; Messerle, V.E.; Ustimenko, A.B. [Applied Plasma Technology, Mclean, VA (USA)

    2008-12-15T23:59:59.000Z

    Oxidant selection is the highest priority for advanced coal gasification-process development. This paper presents comparative analysis of the Powder River Basin bituminous-coal gasification processes for entrained-flow plasma gasifier. Several oxidants, which might be employed for perspective commercial applications, have been chosen, including air, steam/carbon-dioxide blend, carbon dioxide, steam, steam/air, steam/oxygen, and oxygen. Synthesis gas composition, carbon gasification degree, specific power consumptions, and power efficiency for these processes were determined. The influence of the selected oxidant composition on the gasification-process main characteristics have been investigated.

  17. Sampling precautions for the measurement of nitrated polycyclic aromatic hydrocarbons in ambient air

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Sampling precautions for the measurement of nitrated polycyclic aromatic hydrocarbons in ambient of polycyclic aromatic hydrocarbons (PAHs) and of their oxidation products, such as nitrated and oxygenated PAHs hydrocarbons; Nitrated polycyclic aromatic hydrocarbons; Oxygenated polycyclic aromatic hydrocarbons; Sampling

  18. Silicate electrochemical measurements in seawater: Chemical and analytical aspects towards a reagentless sensor

    E-Print Network [OSTI]

    Mailhes, Corinne

    Silicate electrochemical measurements in seawater: Chemical and analytical aspects towards Sabatier, 118 route de Narbonne, 31062 Toulouse Cedex, France Keywords: Molybdenum Silicate Reagentless developed a semi-autonomous method to detect silicate in aqueous samples. Molybdenum oxidation was used

  19. Apparatus for making cathodo- and photo- luminescent measurements of thin film phosphors

    E-Print Network [OSTI]

    Babuchna, Paul Michael

    1998-01-01T23:59:59.000Z

    the understanding of the thin film phosphor, tungsten doped zinc oxide. Principally, a vacuum system is constructed and provides for both photo-and cathode-phosphor excitations. A measurement capability is then included. Finally, additions are mentioned...

  20. Preparation of silver nanoparticles/graphene nanosheets as a catalyst for electrochemical oxidation of methanol

    SciTech Connect (OSTI)

    Han, Kun; Miao, Peng; Tang, Yuguo, E-mail: tangyg@sibet.ac.cn [Suzhou Institute of Biomedical Engineering and Technology, Chinese Academy of Sciences, Suzhou 215163 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); Tong, Hui; Zhu, Xiaoli [Laboratory of Biosensing Technology, School of Life Sciences, Shanghai University, Shanghai 200444 (China); Liu, Tao; Cheng, Wenbo [Suzhou Institute of Biomedical Engineering and Technology, Chinese Academy of Sciences, Suzhou 215163 (China)

    2014-02-03T23:59:59.000Z

    In this report, silver nanoparticles (AgNPs) decorated graphene nanosheets have been prepared based on the reduction of Ag ions by hydroquinone, and their catalytic performance towards the electrochemical oxidation of methanol is investigated. The synthesis of the nano-composite is confirmed by transmission electron microscope measurements and UV-vis absorption spectra. Excellent electrocatalytic performance of the material is demonstrated by cyclic voltammograms. This material also contributes to the low peak potential of methanol oxidation compared with most of the other materials.

  1. Synthesis and characterization of some metal oxide nanocrystals by microwave irradiation

    SciTech Connect (OSTI)

    Rashad, M.; Gaber, A.; Abdelrahim, M. A.; Abdel-Baset, A. M. [Physics Department, Faculty of Science, Assiut University, 71516 Assiut (Egypt); Moharram, A. H. [Physics Dept., College of Science and Arts, King Abdulaziz Univ., Rabigh 21911 (Saudi Arabia)

    2013-12-16T23:59:59.000Z

    Copper oxide and cobalt oxide (CuO, Co3O4) nanocrystals (NCs) have been successfully prepared in a short time using microwave irradiation. The resulted powders of nanocrystals (NCs) were characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). Thermogravimetric analysis (TGA) measurements are also studied. Fourier-transform infrared (FT-IR) and UV–visible absorption spectroscopy of both kind of nanoparticels are illustrated. Optical absorption analysis indicated the direct band gap for both kinds of nanocrystals.

  2. Assessor Training Measurement Uncertainty

    E-Print Network [OSTI]

    NVLAP Assessor Training Measurement Uncertainty #12;Assessor Training 2009: Measurement Uncertainty Training 2009: Measurement Uncertainty 3 Measurement Uncertainty ·Calibration and testing labs performing Training 2009: Measurement Uncertainty 4 Measurement Uncertainty ·When the nature of the test precludes

  3. Properties and characterization of an oxide/oxide composite filter

    SciTech Connect (OSTI)

    Lane, J.E.; Painter, C.J.; Su, W.F.A.; Radford, K.C. [Westinghouse Electric Corp., Pittsburgh, PA (United States). Science and Technology Center; LeCostaouec, J.F. [Techniweave, Inc., Rochester, NH (United States)

    1996-12-31T23:59:59.000Z

    Westinghouse, with Techniweave as a major subcontractor, is conducting a three-phase program aimed at providing advanced candle filters for a 1997 pilot scale demonstration in one of the two hot gas filter system at Southern Company Service`s Wilsonville PSD Facility. This program`s objective is to develop an oxide CFCC (continuous fiber ceramic composite) candle filter that is cost competitive with prototype next generation filters through the development of a low cost sol-gel fabrication process and a 3D fiber architecture optimized for high volume filter manufacturing. Phase 1, Filter Material Development and Evaluation, results will be presented. Phase 1 activities included laboratory-scale development, characterization, and testing of a mullite matrix 3D fiber-reinforced (Nextel 550) ceramic composite filter material. Eleven 3D architectures were designed, preforms and ceramic matrix composite (CMC) filter materials were made, tested and evaluated. The CMC fabrication process was optimized for reduced cost and acceptable filter performance. Permeability, 4-pt bend and microstructural evaluation results, previously presented, were used to downselect to one 3D architecture and CMC processing method. The downselected filter material was fabricated and tested via permeability and 4-pt bend; Weibull modulus was determined. High-temperature flow-through corrosion tests and thermal aging tests in static air up to 5,000 h were conducted. SEM and XRD have been used to characterize microstructural and phase changes, if any, from high temperature exposure testing. Weaving feasibility studies for the flange and the closed end of a candle filter have been conducted in order to develop a low cost weaving method to make a single piece candle filter fiber preform. Results and conclusions for the evaluation of the downselected filter material above will be presented and discussed.

  4. The biogeochemistry of marine nitrous oxide

    E-Print Network [OSTI]

    Frame, Caitlin H

    2011-01-01T23:59:59.000Z

    Atmospheric nitrous oxide N?O concentrations have been rising steadily for the past century as a result of human activities. In particular, human perturbation of the nitrogen cycle has increased the N?O production rates ...

  5. Deoxyribose oxidation chemistry and endogenous DNA adducts

    E-Print Network [OSTI]

    Zhou, Xinfeng

    2006-01-01T23:59:59.000Z

    Endogenous and exogenous oxidants react with cellular macromolecules to generate a variety of electrophiles that react with DNA produce cytotoxic and mutagenic adducts. One source of such electrophiles is deoxyribose in ...

  6. Modeling of solid oxide fuel cells

    E-Print Network [OSTI]

    Lee, Won Yong, S.M. Massachusetts Institute of Technology

    2006-01-01T23:59:59.000Z

    A comprehensive membrane-electrode assembly (MEA) model of Solid Oxide Fuel Cell (SOFC)s is developed to investigate the effect of various design and operating conditions on the cell performance and to examine the underlying ...

  7. Photodissociation Dynamics of Halogen Oxide Species 

    E-Print Network [OSTI]

    Dooley, Kristin S.

    2010-07-14T23:59:59.000Z

    The focus of this dissertation is the study of the photodissociation dynamics of halogen oxide species (XO, X = Cl, Br, I). These radical species are known to be important in stratospheric and tropospheric ozone depletion ...

  8. Extracting metals directly from metal oxides

    DOE Patents [OSTI]

    Wai, C.M.; Smart, N.G.; Phelps, C.

    1997-02-25T23:59:59.000Z

    A method of extracting metals directly from metal oxides by exposing the oxide to a supercritical fluid solvent containing a chelating agent is described. Preferably, the metal is an actinide or a lanthanide. More preferably, the metal is uranium, thorium or plutonium. The chelating agent forms chelates that are soluble in the supercritical fluid, thereby allowing direct removal of the metal from the metal oxide. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of {beta}-diketones, halogenated {beta}-diketones, phosphinic acids, halogenated phosphinic acids, carboxylic acids, halogenated carboxylic acids, and mixtures thereof. In especially preferred embodiments, at least one of the chelating agents is fluorinated. The method provides an environmentally benign process for removing metals from metal oxides without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the metal recovered, to provide an economic, efficient process. 4 figs.

  9. Extracting metals directly from metal oxides

    DOE Patents [OSTI]

    Wai, Chien M. (Moscow, ID); Smart, Neil G. (Moscow, ID); Phelps, Cindy (Moscow, ID)

    1997-01-01T23:59:59.000Z

    A method of extracting metals directly from metal oxides by exposing the oxide to a supercritical fluid solvent containing a chelating agent is described. Preferably, the metal is an actinide or a lanthanide. More preferably, the metal is uranium, thorium or plutonium. The chelating agent forms chelates that are soluble in the supercritical fluid, thereby allowing direct removal of the metal from the metal oxide. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of .beta.-diketones, halogenated .beta.-diketones, phosphinic acids, halogenated phosphinic acids, carboxylic acids, halogenated carboxylic acids, and mixtures thereof. In especially preferred embodiments, at least one of the chelating agents is fluorinated. The method provides an environmentally benign process for removing metals from metal oxides without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the metal recovered, to provide an economic, efficient process.

  10. Catalytic wet oxidation of phenolic wastes

    E-Print Network [OSTI]

    Thomas, Brook James

    1995-01-01T23:59:59.000Z

    The effective removal of toxic chemicals from water is a problem of increasing importance. Aqueous phase oxidation of dilute organic contaminants is an attractive alternative to separation and/or incineration for the treatment of waste water...

  11. Mediating molecular recognition by methionine oxidation: Conformationa...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oxidation results in a general trend towards a random coil for residues in the C-terminal helix, as indicated by the changes in the 1H&61537;, 13C&61537;, and 13CO, with a...

  12. Nitrous Oxide Systems Maintenance in Clinical Areas

    E-Print Network [OSTI]

    Jia, Songtao

    . It specifically speaks to maintenance of nitrous oxide delivery systems, preventive maintenance for house. Arrange with Facilities for regular preventive maintenance and annual performance check of ventilation). b. Provides preventive maintenance on ventilation system as necessary. c. Coordinates annual

  13. High Temperature Oxidation Resistance and Surface Electrical...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with Filtered Arc Cr-Al-N Abstract: The requirements for low cost and high-tempurater corrosion resistance for bipolar interconnect plates in solid oxide fuel cell (SOFC) stacks...

  14. Interfacial material for solid oxide fuel cell

    DOE Patents [OSTI]

    Baozhen, Li (Essex Junction, VT); Ruka, Roswell J. (Pittsburgh, PA); Singhal, Subhash C. (Murrysville, PA)

    1999-01-01T23:59:59.000Z

    Solid oxide fuel cells having improved low-temperature operation are disclosed. In one embodiment, an interfacial layer of terbia-stabilized zirconia is located between the air electrode and electrolyte of the solid oxide fuel cell. The interfacial layer provides a barrier which controls interaction between the air electrode and electrolyte. The interfacial layer also reduces polarization loss through the reduction of the air electrode/electrolyte interfacial electrical resistance. In another embodiment, the solid oxide fuel cell comprises a scandia-stabilized zirconia electrolyte having high electrical conductivity. The scandia-stabilized zirconia electrolyte may be provided as a very thin layer in order to reduce resistance. The scandia-stabilized electrolyte is preferably used in combination with the terbia-stabilized interfacial layer. The solid oxide fuel cells are operable over wider temperature ranges and wider temperature gradients in comparison with conventional fuel cells.

  15. Removing sulphur oxides from a fluid stream

    DOE Patents [OSTI]

    Katz, Torsten; Riemann, Christian; Bartling, Karsten; Rigby, Sean Taylor; Coleman, Luke James Ivor; Lail, Marty Alan

    2014-04-08T23:59:59.000Z

    A process for removing sulphur oxides from a fluid stream, such as flue gas, comprising: providing a non-aqueous absorption liquid containing at least one hydrophobic amine, the liquid being incompletely miscible with water; treating the fluid stream in an absorption zone with the non-aqueous absorption liquid to transfer at least part of the sulphur oxides into the non-aqueous absorption liquid and to form a sulphur oxide-hydrophobic amine-complex; causing the non-aqueous absorption liquid to be in liquid-liquid contact with an aqueous liquid whereby at least part of the sulphur oxide-hydrophobic amine-complex is hydrolyzed to release the hydrophobic amine and sulphurous hydrolysis products, and at least part of the sulphurous hydrolysis products is transferred into the aqueous liquid; separating the aqueous liquid from the non-aqueous absorption liquid. The process mitigates absorbent degradation problems caused by sulphur dioxide and oxygen in flue gas.

  16. Detection of oxidation in human serum lipoproteins

    E-Print Network [OSTI]

    Myers, Christine Lee

    2006-04-12T23:59:59.000Z

    LDL oxidized LDL PB phosphate buffer PON paraoxonase PUFA polyunsaturated fatty acid SAA serum amyloid A TBA thiobarbituric acid TBARS thiobarbituric acid reactive substances TFA trifluoroacetic acid TOF time-of-flight UC...

  17. Nitrogen oxide delivery systems for biological media

    E-Print Network [OSTI]

    Skinn, Brian Thomas

    2012-01-01T23:59:59.000Z

    Elevated levels of nitric oxide (NO) in vivo are associated with a variety of cellular modifications thought to be mutagenic or carcinogenic. These processes are likely mediated by reactive nitrogen species (RNS) such as ...

  18. Oxidation of methionine residues in protein pharmaceuticals

    E-Print Network [OSTI]

    Chu, Jhih-Wei, 1973-

    2004-01-01T23:59:59.000Z

    (cont.) of free methionine. Therefore, the environments surrounding different methionine sites in G-CSF mainly provide spatial restriction to the access to the solvent but do not affect oxidation in a specific manner, ...

  19. Copper accumulation and lipid oxidation precede inflammation and myelin lesions in N,N-diethyldithiocarbamate peripheral myelinopathy

    SciTech Connect (OSTI)

    Viquez, Olga M.; Valentine, Holly L.; Amarnath, Kalyani [Department of Pathology, Vanderbilt University Medical Center, 1161 21st Ave. S., Nashville, TN 37232-2561 (United States); Milatovic, Dejan [Department of Pediatrics, Vanderbilt University Medical Center, 1161 21st Ave. S., Nashville, TN 37232-2561 (United States); Valentine, William M. [Department of Pathology, Vanderbilt University Medical Center, 1161 21st Ave. S., Nashville, TN 37232-2561 (United States); Center in Molecular Toxicology, Vanderbilt University Medical Center, 1161 21st Ave. S., Nashville, TN 37232-2561 (United States); Center for Molecular Neuroscience, Vanderbilt University Medical Center, 1161 21st Ave. S., Nashville, TN 37232-2561 (United States)], E-mail: bill.valentine@vanderbilt.edu

    2008-05-15T23:59:59.000Z

    Dithiocarbamates have a wide spectrum of applications in industry, agriculture and medicine with new applications being actively investigated. One adverse effect of dithiocarbamates is the neurotoxicity observed in humans and experimental animals. Results from previous studies have suggested that dithiocarbamates elevate copper and promote lipid oxidation within myelin membranes. In the current study, copper levels, lipid oxidation, protein oxidative damage and markers of inflammation were monitored as a function of N,N-diethyldithiocarbamate (DEDC) exposure duration in an established model for DEDC-mediated myelinopathy in the rat. Intra-abdominal administration of DEDC was performed using osmotic pumps for periods of 2, 4, and 8 weeks. Metals in brain, liver and tibial nerve were measured using ICP-MS and lipid oxidation assessed through HPLC measurement of malondialdehyde in tibial nerve, and GC/MS measurement of F{sub 2} isoprostanes in sciatic nerve. Protein oxidative injury of sciatic nerve proteins was evaluated through quantification of 4-hydroxynonenal protein adducts using immunoassay, and inflammation monitored by quantifying levels of IgGs and activated macrophages using immunoassay and immunohistochemistry methods, respectively. Changes in these parameters were then correlated to the onset of structural lesions, determined by light and electron microscopy, to delineate the temporal relationship of copper accumulation and oxidative stress in peripheral nerve to the onset of myelin lesions. The data provide evidence that DEDC mediates lipid oxidation and elevation of total copper in peripheral nerve well before myelin lesions or activated macrophages are evident. This relationship is consistent with copper-mediated oxidative stress contributing to the myelinopathy.

  20. Three-Electrode Metal Oxide Reduction Cell

    DOE Patents [OSTI]

    Dees, Dennis W. (Downers Grove, IL); Ackerman, John P. (Downers Grove, IL)

    2005-06-28T23:59:59.000Z

    A method of electrochemically reducing a metal oxide to the metal in an electrochemical cell is disclosed along with the cell. Each of the anode and cathode operate at their respective maximum reaction rates. An electrolyte and an anode at which oxygen can be evolved, and a cathode including a metal oxide to be reduced are included as is a third electrode with independent power supplies connecting the anode and the third electrode and the cathode and the third electrode.

  1. Three-electrode metal oxide reduction cell

    DOE Patents [OSTI]

    Dees, Dennis W. (Downers Groves, IL); Ackerman, John P. (Downers Grove, IL)

    2008-08-12T23:59:59.000Z

    A method of electrochemically reducing a metal oxide to the metal in an electrochemical cell is disclosed along with the cell. Each of the anode and cathode operate at their respective maximum reaction rates. An electrolyte and an anode at which oxygen can be evolved, and a cathode including a metal oxide to be reduced are included as is a third electrode with independent power supplies connecting the anode and the third electrode and the cathode and the third electrode.

  2. Advanced Oxidation Technology for Pulp Mill Effluent

    E-Print Network [OSTI]

    Hart, J. R.

    ADVANCED OXIDATION TECHNOLOGY FOR PULP MILL EFFLUENT J. ROBERT HART, MANAGER, EPRI PULP & PAPER OFFICE, ATLANTA, GA ABSTRACT The composition of effluent from various pulping processes can exhibit a wide range of physical and chemical... an oxidation and photolysis process. AOP FEASIBILITY STUDY The application of AOP for the treatment of pulp mill effluent was demonstrated in an EPRI Co-funded Project (1). This Project had the industrial support of about twenty companies and utilities...

  3. High quality transparent conducting oxide thin films

    DOE Patents [OSTI]

    Gessert, Timothy A. (Conifer, CO); Duenow, Joel N. (Golden, CO); Barnes, Teresa (Evergreen, CO); Coutts, Timothy J. (Golden, CO)

    2012-08-28T23:59:59.000Z

    A transparent conducting oxide (TCO) film comprising: a TCO layer, and dopants selected from the elements consisting of Vanadium, Molybdenum, Tantalum, Niobium, Antimony, Titanium, Zirconium, and Hafnium, wherein the elements are n-type dopants; and wherein the transparent conducting oxide is characterized by an improved electron mobility of about 42 cm.sup.2/V-sec while simultaneously maintaining a high carrier density of .about.4.4e.times.10.sup.20 cm.sup.-3.

  4. Mixed oxide nanoparticles and method of making

    DOE Patents [OSTI]

    Lauf, Robert J. (Oak Ridge, TN); Phelps, Tommy J. (Knoxville, TN); Zhang, Chuanlun (Columbia, MO); Roh, Yul (Oak Ridge, TN)

    2002-09-03T23:59:59.000Z

    Methods and apparatus for producing mixed oxide nanoparticulates are disclosed. Selected thermophilic bacteria cultured with suitable reducible metals in the presence of an electron donor may be cultured under conditions that reduce at least one metal to form a doped crystal or mixed oxide composition. The bacteria will form nanoparticles outside the cell, allowing easy recovery. Selection of metals depends on the redox potentials of the reducing agents added to the culture. Typically hydrogen or glucose are used as electron donors.

  5. Process for etching mixed metal oxides

    DOE Patents [OSTI]

    Ashby, C.I.H.; Ginley, D.S.

    1994-10-18T23:59:59.000Z

    An etching process is described using dicarboxylic and tricarboxylic acids as chelating etchants for mixed metal oxide films such as high temperature superconductors and ferroelectric materials. Undesirable differential etching rates between different metal oxides are avoided by selection of the proper acid or combination of acids. Feature sizes below one micron, excellent quality vertical edges, and film thicknesses in the 100 Angstrom range may be achieved by this method. 1 fig.

  6. Process for etching mixed metal oxides

    DOE Patents [OSTI]

    Ashby, Carol I. H. (Edgewood, NM); Ginley, David S. (Evergreen, CO)

    1994-01-01T23:59:59.000Z

    An etching process using dicarboxylic and tricarboxylic acids as chelating etchants for mixed metal oxide films such as high temperature superconductors and ferroelectric materials. Undesirable differential etching rates between different metal oxides are avoided by selection of the proper acid or combination of acids. Feature sizes below one micron, excellent quality vertical edges, and film thicknesses in the 100 Angstom range may be achieved by this method.

  7. Reduction of metal oxides through mechanochemical processing

    DOE Patents [OSTI]

    Froes, Francis H. (Moscow, ID); Eranezhuth, Baburaj G. (Moscow, ID); Senkov, Oleg N. (Moscow, ID)

    2000-01-01T23:59:59.000Z

    The low temperature reduction of a metal oxide using mechanochemical processing techniques. The reduction reactions are induced mechanically by milling the reactants. In one embodiment of the invention, titanium oxide TiO.sub.2 is milled with CaH.sub.2 to produce TiH.sub.2. Low temperature heat treating, in the range of 400.degree. C. to 700.degree. C., can be used to remove the hydrogen in the titanium hydride.

  8. Electrochemical Characterization of Vanadium Oxide Nanostructured Electrode

    E-Print Network [OSTI]

    Sadoway, Donald Robert

    microstructures called aerogels in the case of supercritical or freeze-drying and ambigels in the case of solvent for intercalated ions.7 When cycled between 4.0 and 1.5 V, vanadium oxide aerogels achieved capaci- ties of 410 mAh/g at C/40.6 Baudrin et al. have used the vanadium oxide aerogel structure to access a metastable phase

  9. PLUTONIUM METAL: OXIDATION CONSIDERATIONS AND APPROACH

    SciTech Connect (OSTI)

    Estochen, E.

    2013-03-20T23:59:59.000Z

    Plutonium is arguably the most unique of all metals when considered in the combined context of metallurgical, chemical, and nuclear behavior. Much of the research in understanding behavior and characteristics of plutonium materials has its genesis in work associated with nuclear weapons systems. However, with the advent of applications in fuel materials, the focus in plutonium science has been more towards nuclear fuel applications, as well as long term storage and disposition. The focus of discussion included herein is related to preparing plutonium materials to meet goals consistent with non-proliferation. More specifically, the emphasis is on the treatment of legacy plutonium, in primarily metallic form, and safe handling, packaging, and transport to meet non-proliferation goals of safe/secure storage. Elevated temperature oxidation of plutonium metal is the treatment of choice, due to extensive experiential data related to the method, as the oxide form of plutonium is one of only a few compounds that is relatively simple to produce, and stable over a large temperature range. Despite the simplicity of the steps required to oxidize plutonium metal, it is important to understand the behavior of plutonium to ensure that oxidation is conducted in a safe and effective manner. It is important to understand the effect of changes in environmental variables on the oxidation characteristics of plutonium. The primary purpose of this report is to present a brief summary of information related to plutonium metal attributes, behavior, methods for conversion to oxide, and the ancillary considerations related to processing and facility safety. The information provided is based on data available in the public domain and from experience in oxidation of such materials at various facilities in the United States. The report is provided as a general reference for implementation of a simple and safe plutonium metal oxidation technique.

  10. Method for making monolithic metal oxide aerogels

    DOE Patents [OSTI]

    Droege, M.W.; Coronado, P.R.; Hair, L.M.

    1995-03-07T23:59:59.000Z

    Transparent, monolithic metal oxide aerogels of varying densities are produced using a method in which a metal alkoxide solution and a catalyst solution are prepared separately and reacted. The resulting hydrolyzed-condensed colloidal solution is gelled, and the wet gel is contained within a sealed, but gas permeable, containment vessel during supercritical extraction of the solvent. The present invention is especially advantageous for making metal oxides other than silica that are prone to forming opaque, cracked aerogels. 6 figs.

  11. Method for making monolithic metal oxide aerogels

    DOE Patents [OSTI]

    Droege, Michael W. (Livermore, CA); Coronado, Paul R. (Livermore, CA); Hair, Lucy M. (Livermore, CA)

    1995-01-01T23:59:59.000Z

    Transparent, monolithic metal oxide aerogels of varying densities are produced using a method in which a metal alkoxide solution and a catalyst solution are prepared separately and reacted. The resulting hydrolyzed-condensed colloidal solution is gelled, and the wet gel is contained within a sealed, but gas permeable, containment vessel during supercritical extraction of the solvent. The present invention is especially advantageous for making metal oxides other than silica that are prone to forming opaque, cracked aerogels.

  12. Steam Oxidation of Advanced Steam Turbine Alloys

    SciTech Connect (OSTI)

    Holcomb, Gordon R.

    2008-01-01T23:59:59.000Z

    Power generation from coal using ultra supercritical steam results in improved fuel efficiency and decreased greenhouse gas emissions. Results of ongoing research into the oxidation of candidate nickel-base alloys for ultra supercritical steam turbines are presented. Exposure conditions range from moist air at atmospheric pressure (650°C to 800°C) to steam at 34.5 MPa (650°C to 760°C). Parabolic scale growth coupled with internal oxidation and reactive evaporation of chromia are the primary corrosion mechanisms.

  13. Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons

    DOE Patents [OSTI]

    Kung, H.H.; Chaar, M.A.

    1988-10-11T23:59:59.000Z

    Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons is carried out over metal vanadate catalysts under oxidizing conditions. The vanadate catalysts are represented by the formulas M[sub 3](VO[sub 4])[sub 2] and MV[sub 2]O[sub 6], M representing Mg, Zn, Ca, Pb, or Cd. The reaction is carried out in the presence of oxygen, but the formation of oxygenate by-products is suppressed.

  14. Catalytic oxidation of light alkanes in presence of a base

    DOE Patents [OSTI]

    Bhinde, Manoj V. (Boothwyn, PA); Bierl, Thomas W. (West Chester, PA)

    1998-01-01T23:59:59.000Z

    The presence of a base in the reaction mixture in a metal-ligand catalyzed partial oxidation of alkanes results in sustained catalyst activity, and in greater percent conversion as compared with oxidation in the absence of base, while maintaining satisfactory selectivity for the desired oxidation, for example the oxidation of isobutane to isobutanol.

  15. Catalytic oxidation of light alkanes in presence of a base

    DOE Patents [OSTI]

    Bhinde, M.V.; Bierl, T.W.

    1998-03-03T23:59:59.000Z

    The presence of a base in the reaction mixture in a metal-ligand catalyzed partial oxidation of alkanes results in sustained catalyst activity, and in greater percent conversion as compared with oxidation in the absence of base, while maintaining satisfactory selectivity for the desired oxidation, for example the oxidation of isobutane to isobutanol. 1 fig.

  16. Reactivity and Transformation of Antibacterial N-Oxides in the

    E-Print Network [OSTI]

    Huang, Ching-Hua

    shown in Figure 1) represent organic N-oxides that are common in many pharmaceuticals, agrochemicals

  17. High carrier concentration p-type transparent conducting oxide films

    DOE Patents [OSTI]

    Yan, Yanfa; Zhang, Shengbai

    2005-06-21T23:59:59.000Z

    A p-type transparent conducting oxide film is provided which is consisting essentially of, the transparent conducting oxide and a molecular doping source, the oxide and doping source grown under conditions sufficient to deliver the doping source intact onto the oxide.

  18. Kinetics of solid-gas reactions characterized by scanning AC nano-calorimetry with application to Zr oxidation

    SciTech Connect (OSTI)

    Xiao, Kechao; Lee, Dongwoo; Vlassak, Joost J., E-mail: vlassak@esag.harvard.edu [School of Engineering and Applied Sciences, Harvard University, 29 Oxford Street, Cambridge, Massachusetts 02138 (United States)

    2014-10-27T23:59:59.000Z

    Scanning AC nano-calorimetry is a recently developed experimental technique capable of measuring the heat capacity of thin-film samples of a material over a wide range of temperatures and heating rates. Here, we describe how this technique can be used to study solid-gas phase reactions by measuring the change in heat capacity of a sample during reaction. We apply this approach to evaluate the oxidation kinetics of thin-film samples of zirconium in air. The results confirm parabolic oxidation kinetics with an activation energy of 0.59?±?0.03 eV. The nano-calorimetry measurements were performed using a device that contains an array of micromachined nano-calorimeter sensors in an architecture designed for combinatorial studies. We demonstrate that the oxidation kinetics can be quantified using a single sample, thus enabling high-throughput mapping of the composition-dependence of the reaction rate.

  19. Oxidative particle mixtures for groundwater treatment

    DOE Patents [OSTI]

    Siegrist, Robert L. (Boulder, CO); Murdoch, Lawrence C. (Clemson, SC)

    2000-01-01T23:59:59.000Z

    The invention is a method and a composition of a mixture for degradation and immobilization of contaminants in soil and groundwater. The oxidative particle mixture and method includes providing a material having a minimal volume of free water, mixing at least one inorganic oxidative chemical in a granular form with a carrier fluid containing a fine grained inorganic hydrophilic compound and injecting the resulting mixture into the subsurface. The granular form of the inorganic oxidative chemical dissolves within the areas of injection, and the oxidative ions move by diffusion and/or advection, therefore extending the treatment zone over a wider area than the injection area. The organic contaminants in the soil and groundwater are degraded by the oxidative ions, which form solid byproducts that can sorb significant amounts of inorganic contaminants, metals, and radionuclides for in situ treatment and immobilization of contaminants. The method and composition of the oxidative particle mixture for long-term treatment and immobilization of contaminants in soil and groundwater provides for a reduction in toxicity of contaminants in a subsurface area of contamination without the need for continued injection of treatment material, or for movement of the contaminants, or without the need for continuous pumping of groundwater through the treatment zone, or removal of groundwater from the subsurface area of contamination.

  20. Solid oxide fuel cell with monolithic core

    DOE Patents [OSTI]

    McPheeters, C.C.; Mrazek, F.C.

    1988-08-02T23:59:59.000Z

    A solid oxide fuel cell in which fuel and oxidant gases undergo an electrochemical reaction to produce an electrical output includes a monolithic core comprised of a corrugated conductive sheet disposed between upper and lower generally flat sheets. The corrugated sheet includes a plurality of spaced, parallel, elongated slots which form a series of closed, linear, first upper and second lower gas flow channels with the upper and lower sheets within which a fuel gas and an oxidant gas respectively flow. Facing ends of the fuel cell are generally V-shaped and provide for fuel and oxidant gas inlet and outlet flow, respectively, and include inlet and outlet gas flow channels which are continuous with the aforementioned upper fuel gas and lower oxidant gas flow channels. The upper and lower flat sheets and the intermediate corrugated sheet are preferably comprised of ceramic materials and are securely coupled together such as by assembly in the green state and sintering together during firing at high temperatures. A potential difference across the fuel cell, or across a stacked array of similar fuel cells, is generated when an oxidant gas such as air and a fuel such as hydrogen gas is directed through the fuel cell at high temperatures, e.g., between 700 C and 1,100 C. 8 figs.

  1. Solid oxide fuel cell with monolithic core

    DOE Patents [OSTI]

    McPheeters, Charles C. (Plainfield, IL); Mrazek, Franklin C. (Hickory Hills, IL)

    1988-01-01T23:59:59.000Z

    A solid oxide fuel cell in which fuel and oxidant gases undergo an electrochemical reaction to produce an electrical output includes a monolithic core comprised of a corrugated conductive sheet disposed between upper and lower generally flat sheets. The corrugated sheet includes a plurality of spaced, parallel, elongated slots which form a series of closed, linear, first upper and second lower gas flow channels with the upper and lower sheets within which a fuel gas and an oxidant gas respectively flow. Facing ends of the fuel cell are generally V-shaped and provide for fuel and oxidant gas inlet and outlet flow, respectively, and include inlet and outlet gas flow channels which are continuous with the aforementioned upper fuel gas and lower oxidant gas flow channels. The upper and lower flat sheets and the intermediate corrugated sheet are preferably comprised of ceramic materials and are securely coupled together such as by assembly in the green state and sintering together during firing at high temperatures. A potential difference across the fuel cell, or across a stacked array of similar fuel cells, is generated when an oxidant gas such as air and a fuel such as hydrogen gas is directed through the fuel cell at high temperatures, e.g., between 700.degree. C. and 1100.degree. C.

  2. Electrochromism in copper oxide thin films

    SciTech Connect (OSTI)

    Richardson, T.J.; Slack, J.L.; Rubin, M.D.

    2000-08-15T23:59:59.000Z

    Transparent thin films of copper(I) oxide prepared on conductive SnO2:F glass substrates by anodic oxidation of sputtered copper films or by direct electrodeposition of Cu2O transformed reversibly to opaque metallic copper films when reduced in alkaline electrolyte. In addition, the same Cu2O films transform reversibly to black copper(II) oxide when cycled at more anodic potentials. Copper oxide-to-copper switching covered a large dynamic range, from 85% and 10% photopic transmittance, with a coloration efficiency of about 32 cm2/C. Gradual deterioration of the switching range occurred over 20 to 100 cycles. This is tentatively ascribed to coarsening of the film and contact degradation caused by the 65% volume change on conversion of Cu to Cu2O. Switching between the two copper oxides (which have similar volumes) was more stable and more efficient (CE = 60 cm2/C), but covered a smaller transmittance range (60% to 44% T). Due to their large electrochemical storage capacity and tolerance for alkaline electrolytes, these cathodically coloring films may be useful as counter electrodes for anodically coloring electrode films such as nickel oxide or metal hydrides.

  3. Methods of producing adsorption media including a metal oxide

    DOE Patents [OSTI]

    Mann, Nicholas R; Tranter, Troy J

    2014-03-04T23:59:59.000Z

    Methods of producing a metal oxide are disclosed. The method comprises dissolving a metal salt in a reaction solvent to form a metal salt/reaction solvent solution. The metal salt is converted to a metal oxide and a caustic solution is added to the metal oxide/reaction solvent solution to adjust the pH of the metal oxide/reaction solvent solution to less than approximately 7.0. The metal oxide is precipitated and recovered. A method of producing adsorption media including the metal oxide is also disclosed, as is a precursor of an active component including particles of a metal oxide.

  4. Simultaneous constraint and phase conversion processing of oxide superconductors

    DOE Patents [OSTI]

    Li, Qi (Marlborough, MA); Thompson, Elliott D. (Coventry, RI); Riley, Jr., Gilbert N. (Marlborough, MA); Hellstrom, Eric E. (Madison, WI); Larbalestier, David C. (Madison, WI); DeMoranville, Kenneth L. (Jefferson, MA); Parrell, Jeffrey A. (Roselle Park, NJ); Reeves, Jodi L. (Madison, WI)

    2003-04-29T23:59:59.000Z

    A method of making an oxide superconductor article includes subjecting an oxide superconductor precursor to a texturing operation to orient grains of the oxide superconductor precursor to obtain a highly textured precursor; and converting the textured oxide superconducting precursor into an oxide superconductor, while simultaneously applying a force to the precursor which at least matches the expansion force experienced by the precursor during phase conversion to the oxide superconductor. The density and the degree of texture of the oxide superconductor precursor are retained during phase conversion. The constraining force may be applied isostatically.

  5. Investigation of Self-Assembly and Micelle Polarity for a Wide Range of Ethylene Oxide-Propylene Oxide-Ethylene

    E-Print Network [OSTI]

    Loh, Watson

    Investigation of Self-Assembly and Micelle Polarity for a Wide Range of Ethylene Oxide-Propylene of 15 EO-PO-EO (EO ) ethylene oxide, PO ) propylene oxide) block copolymers by using three different) propylene oxide) block copolymers, commercially known as Polox- amers, Pluronics, or Synperonics, have been

  6. ENVR Dionysios Dionysiou Wednesday, August 22, 2012 261 -Arsenic mobilization in the critical zone: Oxidation by manganese oxide minerals

    E-Print Network [OSTI]

    Sparks, Donald L.

    : Oxidation by manganese oxide minerals Jason S. Fischel1, fischelj@udel.edu, Matthew H. Fischel1, Brandon J, biogenic and abiotic. Five Mn oxide minerals were reacted under identical conditions with equal reactivity, due to passivation. Understanding the reactivity of naturally occurring Mn oxide minerals

  7. Electrical characterization of native-oxide InAlPGaAs metal-oxide-semiconductor heterostructures using

    E-Print Network [OSTI]

    Electrical characterization of native-oxide InAlPÕGaAs metal-oxide-semiconductor heterostructures 8 December 2003; accepted 20 January 2004 InAIP native oxide/GaAs metal-oxide-semiconductor MOS of Schottky gates can lead to excessive gate leakage current and also restrict the forward gate bias to only

  8. Rank Extraction in Tin-Oxide Sensor Arrays Page 1 of 23 Rank Extraction in Tin-Oxide Sensor Arrays

    E-Print Network [OSTI]

    Roppel, Thaddeus A.

    Rank Extraction in Tin-Oxide Sensor Arrays Page 1 of 23 Rank Extraction in Tin-Oxide Sensor Arrays the amount of data to be processed. This work is a first example in feature extraction from tin-oxide sensors element array of tin-oxide sensors is presented. Results are extrapolated to other arrays of chemical

  9. Molybdenum as a contact material in zinc tin oxide thin film transistors

    SciTech Connect (OSTI)

    Hu, W.; Peterson, R. L., E-mail: blpeters@umich.edu [Department of Electrical Engineering and Computer Science, University of Michigan, Ann Arbor, Michigan 48109-2122 (United States)

    2014-05-12T23:59:59.000Z

    Amorphous oxide semiconductors are of increasing interest for a variety of thin film electronics applications. Here, the contact properties of different source/drain electrode materials to solution-processed amorphous zinc tin oxide (ZTO) thin-film transistors are studied using the transmission line method. The width-normalized contact resistance between ZTO and sputtered molybdenum is measured to be 8.7 ?-cm, which is 10, 20, and 600 times smaller than that of gold/titanium, indium tin oxide, and evaporated molybdenum electrodes, respectively. The superior contact formed using sputtered molybdenum is due to a favorable work function lineup, an insulator-free interface, bombardment of ZTO during molybdenum sputtering, and trap-assisted tunneling. The transfer length of the sputtered molybdenum/ZTO contact is 0.34??m, opening the door to future radio-frequency sub-micron molybdenum/ZTO thin film transistors.

  10. Multi-wavelength Raman scattering of nanostructured Al-doped zinc oxide

    SciTech Connect (OSTI)

    Russo, V.; Ghidelli, M.; Gondoni, P. [Dipartimento di Energia and NEMAS, Center for Nanoengineered Materials and Surfaces, Politecnico di Milano, via Ponzio 34/3, I-20133 Milano (Italy); Casari, C. S.; Li Bassi, A. [Dipartimento di Energia and NEMAS, Center for Nanoengineered Materials and Surfaces, Politecnico di Milano, via Ponzio 34/3, I-20133 Milano (Italy); Center for Nano Science and Technology PoliMI, Istituto Italiano di Tecnologia, Via Pascoli 70/3, I-20133 Milano (Italy)

    2014-02-21T23:59:59.000Z

    In this work we present a detailed Raman scattering investigation of zinc oxide and aluminum-doped zinc oxide (AZO) films characterized by a variety of nanoscale structures and morphologies and synthesized by pulsed laser deposition under different oxygen pressure conditions. The comparison of Raman spectra for pure ZnO and AZO films with similar morphology at the nano/mesoscale allows to investigate the relation between Raman features (peak or band positions, width, relative intensity) and material properties such as local structural order, stoichiometry, and doping. Moreover Raman measurements with three different excitation lines (532, 457, and 325?nm) point out a strong correlation between vibrational and electronic properties. This observation confirms the relevance of a multi-wavelength Raman investigation to obtain a complete structural characterization of advanced doped oxide materials.

  11. Structure and Electronic Configurations of the Intermediates of Water Oxidation in Blue Ruthenium Dimer Catalysis

    SciTech Connect (OSTI)

    Moonshiram, Dooshaye; Jurss, Jonah W.; Concepcion, Javier J.; Zakharova, Taisiya; Alperovich, Igor; Meyer, Thomas J.; Pushkar, Yulia (Purdue); (UNC)

    2013-04-08T23:59:59.000Z

    Catalytic O{sub 2} evolution with cis,cis-[(bpy){sub 2}(H{sub 2}O)Ru{sup III}ORu{sup III}(OH{sub 2})(bpy){sub 2}]{sup 4+} (bpy is 2,2-bipyridine), the so-called blue dimer, the first designed water oxidation catalyst, was monitored by UV-vis, EPR, and X-ray absorption spectroscopy (XAS) with ms time resolution. Two processes were identified, one of which occurs on a time scale of 100 ms to a few seconds and results in oxidation of the catalyst with the formation of an intermediate, here termed [3,4]'. A slower process occurring on the time scale of minutes results in the decay of this intermediate and O{sub 2} evolution. Spectroscopic data suggest that within the fast process there is a short-lived transient intermediate, which is a precursor of [3,4]'. When excess oxidant was used, a highly oxidized form of the blue dimer [4,5] was spectroscopically resolved within the time frame of the fast process. Its structure and electronic state were confirmed by EPR and XAS. As reported earlier, the [3,4]' intermediate likely results from reaction of [4,5] with water. While it is generated under strongly oxidizing conditions, it does not display oxidation of the Ru centers past [3,4] according to EPR and XAS. EXAFS analysis demonstrates a considerably modified ligand environment in [3,4]'. Raman measurements confirmed the presence of the O-O fragment by detecting a new vibration band in [3,4]' that undergoes a 46 cm{sup -1} shift to lower energy upon {sup 16}O/{sup 18}O exchange. Under the conditions of the experiment at pH 1, the [3,4]' intermediate is the catalytic steady state form of the blue dimer catalyst, suggesting that its oxidation is the rate-limiting step.

  12. Methane oxidation over dual redox catalysts

    SciTech Connect (OSTI)

    Klier, K.; Herman, R.G.; Sojka, Z.; DiCosimo, J.I.; DeTavernier, S.

    1992-06-01T23:59:59.000Z

    Catalytic oxidation of methane to partial oxidation products, primarily formaldehyde and C[sub 2] hydrocarbons, was found to be directed by the catalyst used. In this project, it was discovered that a moderate oxidative coupling catalyst for C[sub 2] hydrocarbons, zinc oxide, is modified by addition of small amounts of Cu and Fe dopants to yield fair yields of formaldehyde. A similar effect was observed with Cu/Sn/ZnO catalysts, and the presence of a redox Lewis acid, Fe[sup III] or Sn[sup IV], was found to be essential for the selectivity switch from C[sub 2] coupling products to formaldehyde. The principle of double doping with an oxygen activator (Cu) and the redox Lewis acid (Fe, Sn) was pursued further by synthesizing and testing the CuFe-ZSM-5 zeolite catalyst. The Cu[sup II](ion exchanged) Fe[sup III](framework)-ZSM-5 also displayed activity for formaldehyde synthesis, with space time yields exceeding 100 g/h-kg catalyst. However, the selectivity was low and earlier claims in the literature of selective oxidation of methane to methanol over CuFe-ZSM-5 were not reproduced. A new active and selective catalytic system (M=Sb,Bi,Sn)/SrO/La[sub 2]O[sub 3] has been discovered for potentially commercially attractive process for the conversion of methane to C[sub 2] hydrocarbons, (ii) a new principle has been demonstrated for selectivity switching from C[sub 2] hydrocarbon products to formaldehyde in methane oxidations over Cu,Fe-doped zinc oxide and ZSM-5, and (iii) a new approach has been initiated for using ultrafine metal dispersions for low temperature activation of methane for selective conversions. Item (iii) continues being supported by AMOCO while further developments related to items (i) and (ii) are the objective of our continued effort under the METC-AMOCO proposed joint program.

  13. Electrical conductivity in oxygen-deficient phases of transition metal oxides from first-principles calculations.

    SciTech Connect (OSTI)

    Bondi, Robert James; Desjarlais, Michael Paul; Thompson, Aidan Patrick; Brennecka, Geoffrey L.; Marinella, Matthew

    2013-09-01T23:59:59.000Z

    Density-functional theory calculations, ab-initio molecular dynamics, and the Kubo-Greenwood formula are applied to predict electrical conductivity in Ta2Ox (0x5) as a function of composition, phase, and temperature, where additional focus is given to various oxidation states of the O monovacancy (VOn; n=0,1+,2+). Our calculations of DC conductivity at 300K agree well with experimental measurements taken on Ta2Ox thin films and bulk Ta2O5 powder-sintered pellets, although simulation accuracy can be improved for the most insulating, stoichiometric compositions. Our conductivity calculations and further interrogation of the O-deficient Ta2O5 electronic structure provide further theoretical basis to substantiate VO0 as a donor dopant in Ta2O5 and other metal oxides. Furthermore, this dopant-like behavior appears specific to neutral VO cases in both Ta2O5 and TiO2 and was not observed in other oxidation states. This suggests that reduction and oxidation reactions may effectively act as donor activation and deactivation mechanisms, respectively, for VO0 in transition metal oxides.

  14. IMPACTS OF ANTIFOAM ADDITIONS AND ARGON BUBBLING ON DEFENSE WASTE PROCESSING FACILITY REDUCTION/OXIDATION

    SciTech Connect (OSTI)

    Jantzen, C.; Johnson, F.

    2012-06-05T23:59:59.000Z

    During melting of HLW glass, the REDOX of the melt pool cannot be measured. Therefore, the Fe{sup +2}/{Sigma}Fe ratio in the glass poured from the melter must be related to melter feed organic and oxidant concentrations to ensure production of a high quality glass without impacting production rate (e.g., foaming) or melter life (e.g., metal formation and accumulation). A production facility such as the Defense Waste Processing Facility (DWPF) cannot wait until the melt or waste glass has been made to assess its acceptability, since by then no further changes to the glass composition and acceptability are possible. therefore, the acceptability decision is made on the upstream process, rather than on the downstream melt or glass product. That is, it is based on 'feed foward' statistical process control (SPC) rather than statistical quality control (SQC). In SPC, the feed composition to the melter is controlled prior to vitrification. Use of the DWPF REDOX model has controlled the balanjce of feed reductants and oxidants in the Sludge Receipt and Adjustment Tank (SRAT). Once the alkali/alkaline earth salts (both reduced and oxidized) are formed during reflux in the SRAT, the REDOX can only change if (1) additional reductants or oxidants are added to the SRAT, the Slurry Mix Evaporator (SME), or the Melter Feed Tank (MFT) or (2) if the melt pool is bubble dwith an oxidizing gas or sparging gas that imposes a different REDOX target than the chemical balance set during reflux in the SRAT.

  15. Effect of Substrate Thickness on Oxide Scale Spallation for Solid Oxide Fuel Cells

    SciTech Connect (OSTI)

    Liu, Wenning N.; Sun, Xin; Stephens, Elizabeth V.; Khaleel, Mohammad A.

    2011-07-01T23:59:59.000Z

    In this paper, the effect of the ferritic substrate's thickness on the delamination/spallation of the oxide scale was investigated experimentally and numerically. At the high-temperature oxidation environment of solid oxide fuel cells (SOFCs), a combination of growth stress with thermal stresses may lead to scale delamination/buckling and eventual spallation during SOFC stack cooling, even leading to serious degradation of cell performance. The growth stress is induced by the growth of the oxide scale on the scale/substrate interface, and thermal stress is induced by a mismatch of the coefficient of thermal expansion between the oxide scale and the substrate. The numerical results show that the interfacial shear stresses, which are the driving force of scale delamination between the oxide scale and the ferritic substrate, increase with the growth of the oxide scale and also with the thickness of the ferritic substrate; i.e., the thick ferritic substrate can easily lead to scale delamination and spallation. Experimental observation confirmed the predicted results of the delamination and spallation of the oxide scale on the ferritic substrate.

  16. Method for facilitating catalyzed oxidation reactions, device for facilitating catalyzed oxidation reactions

    DOE Patents [OSTI]

    Beuhler, Robert J. (East Moriches, NY); White, Michael G. (Blue Point, NY); Hrbek, Jan (Rocky Point, NY)

    2006-08-15T23:59:59.000Z

    A catalytic process for the oxidation of organic. Oxygen is loaded into a metal foil by heating the foil while in contact with an oxygen-containing fluid. After cooling the oxygen-activated foil to room temperature, oxygen diffuses through the foil and oxidizes reactants exposed to the other side of the foil.

  17. Isotopic Tracer Studies of Reaction Pathways for Propane Oxidative Dehydrogenation on Molybdenum Oxide Catalysts

    E-Print Network [OSTI]

    Iglesia, Enrique

    Isotopic Tracer Studies of Reaction Pathways for Propane Oxidative Dehydrogenation on Molybdenum of propane over ZrO2-supported MoOx catalysts. Competitive reactions of C3H6 and CH3 13 CH2CH3 showed combustion of propene, or by direct combustion of propane. A mixture of C3H8 and C3D8 undergoes oxidative

  18. Laminated electrochromic windows based on nickel oxide, tungsten oxide, and gel electrolytes

    SciTech Connect (OSTI)

    Passerini, S.; Scrosati, B.; Hermann, V. (Univ. di Roma (Italy). Dipt. di Chimica); Holmblad, C.; Bartlett, T. (Medtronic Promeon, Minneapolis, MN (United States))

    1994-04-01T23:59:59.000Z

    The characteristic and the performance of solid-state, laminated electrochromic windows using tungsten oxide as the principal electrochromic electrode and nonstoichiometric nickel oxide as the counterelectrode separated by selected gel electrolytes, are presented and discussed. These advanced-design, electro-optical devices show a very promising behavior in terms of light modulation and cyclability.

  19. "A New Class of Creep Resistant Oxide/Oxide Ceramic Matrix Composites"

    SciTech Connect (OSTI)

    Dr. Mohit Jain, Dr. Ganesh Skandan, Prof. Roger Cannon, Rutgers University

    2007-03-30T23:59:59.000Z

    Despite recent progress in the development of SiC-SiC ceramic matrix composites (CMCs), their application in industrial gas turbines for distributed energy (DE) systems has been limited. The poor oxidation resistance of the non-oxide ceramics warrants the use of envrionmental barrier coatings (EBCs), which in turn lead to issues pertaining to life expectancy of the coatings. On the other hand, oxide/oxide CMCs are potential replacements, but their use has been limited until now due to the poor creep resistance at high temperatures, particularly above 1200 oC: the lack of a creep resistant matrix has been a major limiting factor. Using yttrium aluminum garnet (YAG) as the matrix material system, we have advanced the state-of-the-art in oxide/oxide CMCs by introducing innovations in both the structure and composition of the matrix material, thereby leading to high temperature matrix creep properties not achieved until now. An array of YAG-based powders with a unique set of particle characteristics were produced in-house and sintered to full density and compressive creep data was obtained. Aided in part by the composition and the microstructure, the creep rates were found to be two orders of magnitude smaller than the most creep resistant oxide fiber available commercially. Even after accounting for porosity and a smaller matrix grain size in a practical CMC component, the YAG-based matrix material was found to creep slower than the most creep resistant oxide fiber available commercially.

  20. Direct-Coupling O? Bond Forming Pathway in Cobalt Oxide Water Oxidation Catalysts

    E-Print Network [OSTI]

    Wang, Lee-Ping

    We report a catalytic mechanism for water oxidation in a cobalt oxide cubane model compound, in which the crucial O–O bond formation step takes place by direct coupling between two CoIV(O) metal oxo groups. Our results are ...

  1. The effect of thermo-oxidation on plasma performance and in-vessel components in DIII-D

    SciTech Connect (OSTI)

    Allen, S. L. [Lawrence Livermore National Laboratory (LLNL); Fitzpatrick, B. W. N. [University of Toronto, Institute for Aerospace Studies, Canada; Davis, J. W. [University of Toronto, Canada; Brooks, N. H. [General Atomics, San Diego; Chrobak, C P [General Atomics, San Diego; Ellis, R [Lawrence Livermore National Laboratory (LLNL); Haasz, A. A. [University of Toronto, Canada; Jackson, G. L. [General Atomics; Leonard, A. W. [General Atomics; McLean, A. G. [Oak Ridge National Laboratory (ORNL); Rudakov, D. L. [University of California, San Diego; Stangeby, P. C. [University of Toronto, Canada; Tsui, C. [University of Toronto, Canada; Umstadter, K. [University of California, San Diego; Unterberg, Ezekial A [ORNL; Wampler, W. R. [Sandia National Laboratories (SNL)

    2013-01-01T23:59:59.000Z

    In April 2010, two thermo-oxidation experiments ('O-bakes') were performed in the DIII-D tokamak. Internal surfaces of the tokamak, as well as a number of specimens inserted into the torus, were exposed to a mixture of 20% O2/80% He at a nominal pressure of 9.5 Torr (1.27 kPa) at a temperature of 350 360 C for a duration of 2 h. Three primary conclusions have been drawn from these experiments: (1) laboratory measurements on the release of deuterium from tokamak codeposits by oxidation have been duplicated in a tokamak environment, (2) no internal tokamak components or systems were adversely affected by the oxidation and (3) the recovery of plasma performance following oxidation was similar to that following regular torus openings.

  2. The Statistical Evolution of Multiple Generations of Oxidation Products in the Photochemical Aging of Chemically Reduced Organic Aerosol

    SciTech Connect (OSTI)

    Wilson, Kevin R.; Smith, Jared D.; Kessler, Sean; Kroll, Jesse H.

    2011-10-03T23:59:59.000Z

    The heterogeneous reaction of hydroxyl radicals (OH) with squalane and bis(2-ethylhexyl) sebacate (BES) particles are used as model systems to examine how distributions of reactionproducts evolve during the oxidation of chemically reduced organic aerosol. A kinetic model of multigenerational chemistry, which is compared to previously measured (squalane) and new(BES) experimental data, reveals that it is the statistical mixtures of different generations of oxidation products that control the average particle mass and elemental composition during thereaction. The model suggests that more highly oxidized reaction products, although initially formed with low probability, play a large role in the production of gas phase reaction products.In general, these results highlight the importance of considering atmospheric oxidation as a statistical process, further suggesting that the underlying distribution of molecules could playimportant roles in aerosol formation as well as in the evolution of key physicochemical properties such as volatility and hygroscopicity.

  3. Sustainable Steelmaking Using Biomass and Waste Oxides (TRP9902)

    SciTech Connect (OSTI)

    Richard J. Fruehan

    2004-09-30T23:59:59.000Z

    A new process for ironmaking was proposed to employ renewable energy in the form of wood charcoal to produce hot metal. The process was aimed at the market niche of units ranging from 400,000 to 1 million tons of hot metal a year. In the new process, a Rotary Hearth Furnace (RHF) would be combined with a smelter to produce hot metal. This combination was proposed to overcome the technical hurdles of energy generation in smelters and the low productivity of RHFs, and also allow the use of wood charcoal as energy source and reductant. In order to assess the feasibility of the new process, it was necessary to estimate the productivity of the two units involved, the RHF and the smelter. This work concentrated on the development of a productivity model for the RHF able to predict changes in productivity according to the type of carbon and iron oxides used as feed materials. This model was constructed starting with the most fundamental aspect of reduction in composites measuring intrinsic rates of oxidation of different carbons in CO{sub 2}-CO atmospheres and reduction of different oxides in the same atmospheres. After that, a model was constructed considering the interplay of intrinsic kinetics and the transfer of heat to and within pellets such as used in the RHF. Finally, a productivity model for the RHF was developed based on the model developed for a pellet and the differences in heat transfer conditions between the laboratory furnace and the actual RHF. The final model produced for the RHF predicts production rates within 30% of actual plant data reported with coal and indicates that productivity gains as high as 50% could be achieved replacing coal with wood charcoal in the green balls owing to the faster reaction rates achieved with the second carbon. This model also indicates that an increase of less than 5% in total carbon consumption should take place in operations using wood charcoal instead of coal.

  4. Synthesis and characterizations of graphene oxide and reduced graphene oxide nanosheets

    SciTech Connect (OSTI)

    Venkanna, M., E-mail: venkanna.pcu@gmail.com; Chakraborty, Amit K., E-mail: venkanna.pcu@gmail.com [Carbon Nanotechnology Laboratory, Department of Physics, National Institute of Technology Durgapur, M.G. Avenue, Durgapur - 713209 (India)

    2014-04-24T23:59:59.000Z

    Interest in graphene on its excellent mechanical, electrical, thermal and optical properties, it’s very high specific surface area, and our ability to influence these properties through chemical functionalization. Chemical reduction of graphene oxide is one of the main routes of preparation for large quantities of graphenes. Hydrazine hydrate used as reducing agent to prepare for the reduced graphene oxide (RGO). There are a number of methods for generating graphene and chemically modified graphene from natural graphite flakes, graphite derivative (such as graphite oxide) and graphite interaction compounds (i.e. expandable graphite). Here we review the use of colloidal suspensions of reduced graphene oxide (RGO) with large scalable, and is adaptable to a wide variety of applications. The graphene oxide (GO) and the reduced material (RGO) were characterized by XRD, UV-Vis spectroscopy, Thermo-gravimetric analysis (TGA), Raman spectroscopy and Field emission Scanning electron microscopy (FESEM) etc.

  5. Inhibition of Oxidation in Nuclear Graphite

    SciTech Connect (OSTI)

    Phil Winston; James W. Sterbentz; William E. Windes

    2013-10-01T23:59:59.000Z

    Graphite is a fundamental material of high temperature gas cooled nuclear reactors, providing both structure and neutron moderation. Its high thermal conductivity, chemical inertness, thermal heat capacity, and high thermal structural stability under normal and off normal conditions contribute to the inherent safety of these reactor designs. One of the primary safety issues for a high temperature graphite reactor core is the possibility of rapid oxidation of the carbon structure during an off normal design basis event where an oxidizing atmosphere (air ingress) can be introduced to the hot core. Although the current Generation IV high temperature reactor designs attempt to mitigate any damage caused by a postualed air ingress event, the use of graphite components that inhibit oxidation is a logical step to increase the safety of these reactors. Recent experimental studies of graphite containing between 5.5 and 7 wt% boron carbide (B4C) indicate that oxidation is dramatically reduced even at prolonged exposures at temperatures up to 900°C. The proposed addition of B4C to graphite components in the nuclear core would necessarily be enriched in B-11 isotope in order to minimize B-10 neutron absorption and graphite swelling. The enriched boron can be added to the graphite during billet fabrication. Experimental oxidation rate results and potential applications for borated graphite in nuclear reactor components will be discussed.

  6. MEASUREMENT OF TRITIUM DURING VOLOXIDATION OF ZIRCALOY-2 FUEL HULLS

    SciTech Connect (OSTI)

    Crowder, M.; Laurinat, J.; Stillman, J.

    2010-10-14T23:59:59.000Z

    A straightforward method to evaluate the tritium content of Zircaloy-2 cladding hulls via oxidation of the hull and capture of the volatilized tritium in liquids has been demonstrated. Hull samples were heated in air inside a thermogravimetric analyzer (TGA). The TGA was rapidly heated to 1000 C to oxidize the hulls and release absorbed tritium. To capture tritium, the TGA off-gas was bubbled through a series of liquid traps. The concentrations of tritium in bubbler solutions indicated that tritiated water vapor was captured nearly quantitatively. The average tritium content measured in the hulls was 19% of the amount of tritium produced by the fuel, according to ORIGEN2 isotope generation and depletion calculations. Published experimental data show that Zircaloy-2 oxidation follows an Arrhenius model, and that an initial, nonlinear oxidation rate is followed by a faster, linear rate after 'breakaway' of the oxide film. This study demonstrates that the linear oxidation rate of Zircaloy samples at 974 C is faster than predicted by the extrapolation of data from lower temperatures.

  7. Catalysts for the selective oxidation of hydrogen sulfide to sulfur

    DOE Patents [OSTI]

    Srinivas, Girish (Thornton, CO); Bai, Chuansheng (Baton Rouge, LA)

    2000-08-08T23:59:59.000Z

    This invention provides catalysts for the oxidation of hydrogen sulfide. In particular, the invention provides catalysts for the partial oxidation of hydrogen sulfide to elemental sulfur and water. The catalytically active component of the catalyst comprises a mixture of metal oxides containing titanium oxide and one or more metal oxides which can be selected from the group of metal oxides or mixtures of metal oxides of transition metals or lanthanide metals. Preferred metal oxides for combination with TiO.sub.2 in the catalysts of this invention include oxides of V, Cr, Mn, Fe, Co, Ni, Cu, Nb, Mo, Tc, Ru, Rh, Hf, Ta, W, Au, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu. Catalysts which comprise a homogeneous mixture of titanium oxide and niobium (Nb) oxide are also provided. A preferred method for preparing the precursor homogenous mixture of metal hydroxides is by coprecipitation of titanium hydroxide with one or more other selected metal hydroxides. Catalysts of this invention have improved activity and/or selectivity for elemental sulfur production. Further improvements of activity and/or selectivity can be obtained by introducing relatively low amounts (up to about 5 mol %)of a promoter metal oxide (preferably of metals other than titanium and that of the selected second metal oxide) into the homogeneous metal/titanium oxide catalysts of this invention.

  8. Real-Time Redox Measurements during Endoplasmic Reticulum Stress Reveal

    E-Print Network [OSTI]

    Mullins, Dyche

    Real-Time Redox Measurements during Endoplasmic Reticulum Stress Reveal Interlinked Protein Folding.10.011 SUMMARY Disruption of protein folding in the endoplasmic reticulum (ER) causes unfolded proteins to accumu is active. Because ER redox po- tential is optimized for oxidative protein folding, we reasoned

  9. Aromatics oxidation and soot formation in flames. Progress report, August 15, 1990--August 14, 1993

    SciTech Connect (OSTI)

    Howard, J.B.; Pope, C.J.; Shandross, R.A.; Yadav, T.

    1993-04-01T23:59:59.000Z

    This project is concerned with the kinetics and mechanisms of aromatics oxidation and soot and fullerenes formation in flames. The scope includes detailed measurements of profiles of stable and radical species concentrations in low-pressure one-dimensional premixed flames. Intermediate species identifications and mole fractions, fluxes, and net reaction rates calculated from the measured profiles are used to test postulated reaction mechanisms. Particular objectives are to identify, and to confirm or determine rate constants for, the main benzene oxidation reactions in flames, and to characterize soot and fullerenes and their formation mechanisms and kinetics. Stable and radical species profiles in the aromatics oxidation study are measured using molecular beam sampling with on-line mass spectrometry. The rate of soot formation measured by conventional optical techniques is found to support the hypotheses that particle inception occurs through reactive coagulation of high molecular weight PAH in competition with destruction by OHattack, and that the subsequent growth of the soot mass occurs through addition reactions of PAH and C{sub 2}H{sub 2} with the soot particles. During the first year of this reporting period, fullerenes C{sub 60} and C{sub 70} in substantial quantities were found in the flames being studied. The fullerenes were recovered, purified and spectroscopically identified. The yields of C{sub 60} and C{sub 70} were then determined over ranges of conditions in low-pressure premixed flames of benzene and oxygen.

  10. Novel Oxide-Oxide Fiber Reinforced Hot Gas Filter Development

    SciTech Connect (OSTI)

    Wagner, R.A. [Babcock and Wilcox Co., Lynchburg, VA (United States)

    1996-12-31T23:59:59.000Z

    This report describes the fabrication and testing of continuous fiber ceramic composites (CFCC) based hot gas filters. The work was divided into two primary tasks. In the first task, a preliminary set of compositions was fabricated in the form of open end tubes and characterized. The results of the first task were then used to identify the most promising compositions for sub-scale fabrication and testing. In addition to laboratory measurements of permeability and strength, exposure testing in a coal combustion environment was performed to assess the thermo-chemical stability of the CFCC materials. The results of this testing were then used to down-select the filter composition for full-scale filter fabrication and testing in the optional Phase II of the program.

  11. MERCURY OXIDIZATION IN NON-THERMAL PLASMA BARRIER DISCHARGE SYSTEM

    SciTech Connect (OSTI)

    V.K. Mathur

    2003-02-01T23:59:59.000Z

    In the past decade, the emission of toxic elements from human activities has become a matter of great public concern. Hg, As, Se and Cd typically volatilize during a combustion process and are not easily caught with conventional air pollution control techniques. In addition, there is no pollution prevention technique available now or likely be available in the foreseeable future that can prevent the emission of these trace elements. These trace elements pose additional scientific challenge as they are present at only ppb levels in large gas streams. Mercury, in particular, has attracted significant attention due to its high volatility, toxicity and potential threat to human health. In the present research work, a non-thermal plasma dielectric barrier discharge technique has been used to oxidize Hg{sup 0}(g) to HgO. The basic premise of this approach is that Hg{sup 0} in vapor form cannot be easily removed in an absorption tower whereas HgO as a particulate is amiable to water scrubbing. The work presented in this report consists of three steps: (1) setting-up of an experimental apparatus to generate mercury vapors at a constant rate and modifying the existing non-thermal plasma reactor system, (2) solving the analytical challenge for measuring mercury vapor concentration at ppb level, and (3) conducting experiments on mercury oxidation under plasma conditions to establish proof of concept.

  12. Oxide dispersion strengthening of nickel electrodeposits for microsystem applications.

    SciTech Connect (OSTI)

    Janek, Richard P. (Owens Technology Inc., Palo Alto, CA); Kotula, Paul Gabriel; Buchheit, Thomas Edward; Michael, R. P.; Goods, Steven Howard

    2003-11-01T23:59:59.000Z

    Oxide dispersion strengthened nickel (ODS-Ni) electrodeposits were fabricated to net shape in a nickel sulfamate bath using the LIGA process. A 20 g/l charge of 10 nm Al{sub 2}O{sub 3} powder was suspended in the bath during electrodeposition to produce specimens containing an approximately 0.001-0.02 volume fraction dispersion of the alumina particulate. Mechanical properties are compared to baseline specimens fabricated using an identical sulfamate bath chemistry without the Al{sub 2}O{sub 3} powder charge. Results reveal that the as-deposited ODS-Ni exhibited significantly higher yield strength and ultimate tensile strength than the baseline material. This increase in as-deposited strength is attributed to Orowan strengthening. The ODS-Ni also showed improved retention of room temperature strength after annealing over a range of temperatures up to 600 C. Microscopy revealed that this resistance to anneal softening was due to an inhibition of grain growth in the presence of the oxide dispersion. Nanoindentation measurements revealed that the properties of the dispersion strengthened deposit were uniform through its thickness, even in narrow, high aspect ratio structures. At elevated temperatures, the strength of the ODS-Ni was approximately three times greater than that of the baseline material although with a significant reduction in hot ductility.

  13. In situ oxidation of subsurface formations

    DOE Patents [OSTI]

    Beer, Gary Lee (Houston, TX); Mo, Weijian (Sugar Land, TX); Li, Busheng (Houston, TX); Shen, Chonghui (Calgary, CA)

    2011-01-11T23:59:59.000Z

    Methods and systems for treating a hydrocarbon containing formation described herein include providing heat to a first portion of the formation from a plurality of heaters in the first portion, producing produced through one or more production wells in a second portion of the formation, reducing or turning off heat provided to the first portion after a selected time, providing an oxidizing fluid through one or more of the heater wells in the first portion, providing heat to the first portion and the second portion through oxidation of at least some hydrocarbons in the first portion, and producing fluids through at least one of the production wells in the second portion. The produced fluids may include at least some oxidized hydrocarbons produced in the first portion.

  14. Lithium metal oxide electrodes for lithium batteries

    DOE Patents [OSTI]

    Thackeray, Michael M. (Naperville, IL); Kim, Jeom-Soo (Naperville, IL); Johnson, Christopher S. (Naperville, IL)

    2008-01-01T23:59:59.000Z

    An uncycled electrode for a non-aqueous lithium electrochemical cell including a lithium metal oxide having the formula Li.sub.(2+2x)/(2+x)M'.sub.2x/(2+x)M.sub.(2-2x)/(2+x)O.sub.2-.delta., in which 0.ltoreq.x<1 and .delta. is less than 0.2, and in which M is a non-lithium metal ion with an average trivalent oxidation state selected from two or more of the first row transition metals or lighter metal elements in the periodic table, and M' is one or more ions with an average tetravalent oxidation state selected from the first and second row transition metal elements and Sn. Methods of preconditioning the electrodes are disclosed as are electrochemical cells and batteries containing the electrodes.

  15. Silver manganese oxide electrodes for lithium batteries

    DOE Patents [OSTI]

    Thackeray, Michael M.; Vaughey, John T.; Dees, Dennis W.

    2006-05-09T23:59:59.000Z

    This invention relates to electrodes for non-aqueous lithium cells and batteries with silver manganese oxide positive electrodes, denoted AgxMnOy, in which x and y are such that the manganese ions in the charged or partially charged electrodes cells have an average oxidation state greater than 3.5. The silver manganese oxide electrodes optionally contain silver powder and/or silver foil to assist in current collection at the electrodes and to improve the power capability of the cells or batteries. The invention relates also to a method for preparing AgxMnOy electrodes by decomposition of a permanganate salt, such as AgMnO4, or by the decomposition of KMnO4 or LiMnO4 in the presence of a silver salt.

  16. Ceramic coating system or water oxidation environments

    DOE Patents [OSTI]

    Hong, Glenn T. (Tewksbury, MA)

    1996-01-01T23:59:59.000Z

    A process for water oxidation of combustible materials in which during at least a part of the oxidation corrosive material is present and makes contact with at least a portion of the apparatus over a contact area on the apparatus. At least a portion of the contact surface area comprises titanium dioxide coated onto a titanium metal substrate. Such ceramic composites have been found to be highly resistant to environments encountered in the process of supercritical water oxidation. Such environments typically contain greater than 50 mole percent water, together with oxygen, carbon dioxide, and a wide range of acids, bases, and salts. Pressures are typically about 27.5 to about 1000 bar while temperatures range as high as 700.degree. C. The ceramic composites are also resistant to degradation mechanisms caused by thermal stresses.

  17. Method for fluorination of uranium oxide

    DOE Patents [OSTI]

    Petit, George S. (Oak Ridge, TN)

    1987-01-01T23:59:59.000Z

    Highly pure uranium hexafluoride is made from uranium oxide and fluorine. The uranium oxide, which includes UO.sub.3, UO.sub.2, U.sub.3 O.sub.8 and mixtures thereof, is introduced together with a small amount of a fluorine-reactive substance, selected from alkali chlorides, silicon dioxide, silicic acid, ferric oxide, and bromine, into a constant volume reaction zone. Sufficient fluorine is charged into the zone at a temperature below approximately 0.degree. C. to provide an initial pressure of at least approximately 600 lbs/sq. in. at the ambient atmospheric temperature. The temperature is then allowed to rise in the reaction zone until reaction occurs.

  18. Growth of oxide exchange bias layers

    DOE Patents [OSTI]

    Chaiken, A.; Michel, R.P.

    1998-07-21T23:59:59.000Z

    An oxide (NiO, CoO, NiCoO) antiferromagnetic exchange bias layer produced by ion beam sputtering of an oxide target in pure argon (Ar) sputtering gas, with no oxygen gas introduced into the system. Antiferromagnetic oxide layers are used, for example, in magnetoresistive readback heads to shift the hysteresis loops of ferromagnetic films away from the zero field axis. For example, NiO exchange bias layers have been fabricated using ion beam sputtering of an NiO target using Ar ions, with the substrate temperature at 200 C, the ion beam voltage at 1000V and the beam current at 20 mA, with a deposition rate of about 0.2 {angstrom}/sec. The resulting NiO film was amorphous. 4 figs.

  19. Effect of Coal Gas Contaminants on Solid Oxide Fuel Cell Operation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coal Gas Contaminants on Solid Oxide Fuel Cell Operation. Effect of Coal Gas Contaminants on Solid Oxide Fuel Cell Operation. Abstract: The operation of solid oxide fuel cells...

  20. Physical properties of erbium implanted tungsten oxide films deposited by reactive dual magnetron sputtering

    E-Print Network [OSTI]

    Mohamed, Sodky H.; Anders, Andre

    2006-01-01T23:59:59.000Z

    of erbium implanted tungsten oxide films deposited byDual magnetron sputtering; tungsten oxide films; Er ionoptical waveguides [3,5]. Tungsten oxide (WO 3 ) thin films

  1. Fundamental Studies of the Durability of Materials for Interconnects in Solid Oxide Fuel Cells

    SciTech Connect (OSTI)

    Frederick S. Pettit; Gerald H. Meier

    2006-06-30T23:59:59.000Z

    Ferritic stainless steels are a leading candidate material for use as an SOFC interconnect, but have the problem of forming volatile chromia species that lead to cathode poisoning. This project has focused both on optimization of ferritic alloys for SOFC applications and evaluating the possibility of using alternative materials. The initial efforts involved studying the oxidation behavior of a variety of chromia-forming ferritic stainless steels in the temperature range 700-900 C in atmospheres relevant to solid oxide fuel cell operation. The alloys exhibited a wide variety of oxidation behavior based on composition. A method for reducing the vaporization is to add alloying elements that lead to the formation of a thermally grown oxide layer over the protective chromia. Several commercial steels form manganese chromate on the surface. This same approach, combined with observations of TiO{sub 2} overlayer formation on the chromia forming, Ni-based superalloy IN 738, has resulted in the development of a series of Fe-22 Cr-X Ti alloys (X=0-4 wt%). Oxidation testing has indicated that this approach results in significant reduction in chromia evaporation. Unfortunately, the Ti also results in accelerated chromia scale growth. Fundamental thermo-mechanical aspects of the durability of solid oxide fuel cell (SOFC) interconnect alloys have also been investigated. A key failure mechanism for interconnects is the spallation of the chromia scale that forms on the alloy, as it is exposed to fuel cell environments. Indentation testing methods to measure the critical energy release rate (Gc) associated with the spallation of chromia scale/alloy systems have been evaluated. This approach has been used to evaluate the thermomechanical stability of chromia films as a function of oxidation exposure. The oxidation of pure nickel in SOFC environments was evaluated using thermogravimetric analysis (TGA) to determine the NiO scaling kinetics and a four-point probe was used to measure the area-specific resistance (ASR) to estimate the electrical degradation of the interconnect. In addition to the baseline study of pure nickel, steps were taken to decrease the ASR through alloying and surface modifications. Finally, high conductivity composite systems, consisting of nickel and silver, were studied. These systems utilize high conductivity silver pathways through nickel while maintaining the mechanical stability that a nickel matrix provides.

  2. Superconductive articles including cerium oxide layer

    DOE Patents [OSTI]

    Wu, X.D.; Muenchausen, R.E.

    1993-11-16T23:59:59.000Z

    A ceramic superconductor comprising a metal oxide substrate, a ceramic high temperature superconductive material, and a intermediate layer of a material having a cubic crystal structure, said layer situated between the substrate and the superconductive material is provided, and a structure for supporting a ceramic superconducting material is provided, said structure comprising a metal oxide substrate, and a layer situated over the surface of the substrate to substantially inhibit interdiffusion between the substrate and a ceramic superconducting material deposited upon said structure. 7 figures.

  3. Steam reforming utilizing iron oxide catalyst

    SciTech Connect (OSTI)

    Setzer, H. T.; Bett, J. A. S.

    1985-06-11T23:59:59.000Z

    High activity steam reforming iron oxide catalysts are described. Such catalysts can be unsupported utilizing at least 90% by weight iron oxide and various modifiers (Ai/sub 2/O/sub 3/, K/sub 2/O, CaO, SiO/sub 2/) or unmodified and supported on such things as alumina, CaO impregnated alumina, and lanthanum stabilized alumina. When used in steam reformers such as autothermal and tubular steam reformers, these catalysts demonstrate much improved resistance to carbon plugging.

  4. Direct electrochemical reduction of metal-oxides

    DOE Patents [OSTI]

    Redey, Laszlo I. (Downers Grove, IL); Gourishankar, Karthick (Downers Grove, IL)

    2003-01-01T23:59:59.000Z

    A method of controlling the direct electrolytic reduction of a metal oxide or mixtures of metal oxides to the corresponding metal or metals. A non-consumable anode and a cathode and a salt electrolyte with a first reference electrode near the non-consumable anode and a second reference electrode near the cathode are used. Oxygen gas is produced and removed from the cell. The anode potential is compared to the first reference electrode to prevent anode dissolution and gas evolution other than oxygen, and the cathode potential is compared to the second reference electrode to prevent production of reductant metal from ions in the electrolyte.

  5. SOFTWARE RELATEDSOFTWARE-RELATED MEASUREMENT:MEASUREMENT

    E-Print Network [OSTI]

    SOFTWARE RELATEDSOFTWARE-RELATED MEASUREMENT:MEASUREMENT: RISKS AND OPPORTUNITIES CEM KANER, J and lazy? Most managers who I know have tried at least oney g measurement program--and abandoned them: · Measurement theory and how it applies to software development metrics (which, at their core, are typically

  6. Development of oxide dispersion strengthened ferritic steels for fusion

    SciTech Connect (OSTI)

    Mukhopadhyay, D.K. [Vista Metals, Inc., McKeesport, PA (United States); Froes, F.H. [Univ. of Idaho, ID (United States); Gelles, D.S. [Pacific Northwest National Lab., Richland, WA (United States)

    1998-03-01T23:59:59.000Z

    An oxide dispersion strengthened (ODS) ferritic steel with high temperature strength has been developed in line with low activation criteria for application in fusion power systems. The composition Fe-13.5Cr-2W-0.5Ti-0.25Y{sub 2}O{sup 3} was chosen to provide a minimum chromium content to insure fully delta-ferrite stability. High temperature strength has been demonstrated by measuring creep response of the ODS alloy in uniaxial tension at 650 and 900 C in an inert atmosphere chamber. Results of tests at 900 C demonstrate that this alloy has creep properties similar to other alloys of similar design and can be considered for use in high temperature fusion power system designs. The alloy selection process, materials production, microstructural evaluation and creep testing are described.

  7. Anomalous behaviour of magnetic coercivity in graphene oxide and reduced graphene oxide

    SciTech Connect (OSTI)

    Bagani, K.; Bhattacharya, A.; Kaur, J.; Rai Chowdhury, A.; Ghosh, B.; Banerjee, S., E-mail: sangam.banerjee@saha.ac.in [Saha Institute of Nuclear Physics, Surface Physics Division, 1/AF Bidhannagar, Kolkata 700064 (India); Sardar, M. [Material Science Division, Indira Gandhi Centre for Atomic Research, Kalpakkam 603102 (India)

    2014-01-14T23:59:59.000Z

    In this report, we present the temperature dependence of the magnetic coercivity of graphene oxide (GO) and reduced graphene oxide (RGO). We observe an anomalous decrease in coercivity of GO and RGO with decreasing temperature. The observation could be understood by invoking the inherent presence of wrinkles on graphene oxide due to presence of oxygen containing groups. Scanning electron microscopic image reveals high wrinkles in GO than RGO. We observe higher coercivity in RGO than in GO. At room temperature, we observe antiferromagnetic and ferromagnetic behaviours in GO and RGO, respectively. Whereas, at low temperatures (below T?=?60–70?K), both materials show paramagnetic behaviour.

  8. Power dissipation characteristics of zinc-oxide arresters for HVDC systems

    SciTech Connect (OSTI)

    Horiuchi, S.; Ichikawa, F. (Tokyo Electric Power Co., Inc., Tokyo (JP)); Mizukoshi, A. (Hitachi Research Lab., Hitachi Ltd. (JP)); Kurita, K.; Shirakawa, S. (Kokubu Works Hitachi Ltd., Ibaraki (JP))

    1988-10-01T23:59:59.000Z

    Zinc-oxide arresters without series gaps have been used for HVDC systems. The voltage wave shapes applied to HVDC arresters are not a simple sinusoidal shape, so that the leakage current contains high frequency components. The power dissipation characteristics of a thyristor valve arrester were measured using a 1/25 prorated arrester section with a 5kV/500kW thyristor bridge. High frequency power dissipation characteristics of zinc-oxide elements were measured and it was shown that the high frequency power dissipation of the thyristor valve arrester was larger than that of an AC system arrester. Consideration of the equivalent continuous operating voltage for the performance test of an HVDC arrester are presented.

  9. Non-destructive radiocarbon and stable isotopic analyses of archaeological materials using plasma oxidation

    E-Print Network [OSTI]

    Steelman, Karen Lynn

    2005-11-01T23:59:59.000Z

    contamination of modern carbon required to alter these measured radiocarbon dates to the archaeologically expected ages???????????? 130 18 Results of plasma oxidations and the radiocarbon age determination for the ?caribou? charcoal rock painting from... N, 13 CH, and 12 CH 2 . The use of high-energy mass spectrometry and a cesium sputter ion source in the late 1970s eliminated these interferences (Bennett et al. 1977; Nelson et al. 1977; and Muller et al. 1978). Muller (1977) proposed the use...

  10. Analysis of sequence-selective guanine oxidation by biological agents

    E-Print Network [OSTI]

    Margolin, Yelena, 1977-

    2008-01-01T23:59:59.000Z

    Oxidatively damaged DNA has been strongly associated with cancer, chronic degenerative diseases and aging. Guanine is the most frequently oxidized base in the DNA, and generation of a guanine radical cation (G'") as an ...

  11. Reversible Poisoning of the Nickel/Zirconia Solid Oxide Fuel...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Poisoning of the NickelZirconia Solid Oxide Fuel Cell Anodes by Hydrogen Chloride in Coal Gas. Reversible Poisoning of the NickelZirconia Solid Oxide Fuel Cell Anodes by Hydrogen...

  12. Process for selected gas oxide removal by radiofrequency catalysts

    DOE Patents [OSTI]

    Cha, Chang Y. (3807 Reynolds St., Laramie, WY 82070)

    1993-01-01T23:59:59.000Z

    This process to remove gas oxides from flue gas utilizes adsorption on a char bed subsequently followed by radiofrequency catalysis enhancing such removal through selected reactions. Common gas oxides include SO.sub.2 and NO.sub.x.

  13. Transformation kinetics and pathways of tetracycline antibiotics with manganese oxide

    E-Print Network [OSTI]

    Huang, Ching-Hua

    Oxidation Emerging contaminants Pharmaceuticals a b s t r a c t Tetracycline antibiotics including(IV) oxide/hydroxide colloidal particles or coatings on other minerals in soils and sediments, plays

  14. In Situ Iron Oxide Emplacement for Groundwater Arsenic Remediation 

    E-Print Network [OSTI]

    Abia, Thomas Sunday

    2012-02-14T23:59:59.000Z

    Iron oxide-bearing minerals have long been recognized as an effective reactive media for arsenic-contaminated groundwater remediation. This research aimed to develop a technique that could facilitate in situ oxidative precipitation of Fe3+ in a soil...

  15. Partial oxidation power plant with reheating and method thereof

    DOE Patents [OSTI]

    Newby, Richard A. (Pittsburgh, PA); Yang, Wen-Ching (Export, PA); Bannister, Ronald L. (Winter Springs, FL)

    1999-01-01T23:59:59.000Z

    A system and method for generating power having an air compression/partial oxidation system, a turbine, and a primary combustion system. The air compression/partial oxidation system receives a first air stream and a fuel stream and produces a first partially oxidized fuel stream and a first compressed air stream therefrom. The turbine expands the first partially oxidized fuel stream while being cooled by the first compressed air stream to produce a heated air stream. The heated air stream is injected into the expanding first partially oxidized fuel stream, thereby reheating it in the turbine. A second partially oxidized fuel stream is emitted from the turbine. The primary combustion system receives said second partially oxidized fuel stream and a second air stream, combusts said second partially oxidized fuel stream, and produces rotating shaft power and an emission stream therefrom.

  16. Partial oxidation power plant with reheating and method thereof

    DOE Patents [OSTI]

    Newby, R.A.; Yang, W.C.; Bannister, R.L.

    1999-08-10T23:59:59.000Z

    A system and method are disclosed for generating power having an air compression/partial oxidation system, a turbine, and a primary combustion system. The air compression/partial oxidation system receives a first air stream and a fuel stream and produces a first partially oxidized fuel stream and a first compressed air stream therefrom. The turbine expands the first partially oxidized fuel stream while being cooled by the first compressed air stream to produce a heated air stream. The heated air stream is injected into the expanding first partially oxidized fuel stream, thereby reheating it in the turbine. A second partially oxidized fuel stream is emitted from the turbine. The primary combustion system receives said second partially oxidized fuel stream and a second air stream, combusts said second partially oxidized fuel stream, and produces rotating shaft power and an emission stream therefrom. 2 figs.

  17. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...

    Broader source: Energy.gov (indexed) [DOE]

    rappe.pdf More Documents & Publications Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Low-Temperature HydrocarbonCO Oxidation Catalysis in...

  18. Ovarian nitric oxide synthase gene expression during peripubertal development

    E-Print Network [OSTI]

    Jones, Benjamin James

    1997-01-01T23:59:59.000Z

    Nitric oxide (NO) is generated from L-arginine by different isoforms of the enzyme nitric oxide synthase. (NOS) and is known to be involved in mediating several biological functions, some of which are associated with reproduction. Much attention...

  19. Minimal Proton Channel Enables H2 Oxidation and Production with...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Minimal Proton Channel Enables H2 Oxidation and Production with a Water-Soluble Nickel-Based Catalyst. Minimal Proton Channel Enables H2 Oxidation and Production with a...

  20. ORNL researchers make strides toward a copper oxide solar cell...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    researchers make strides toward a copper oxide solar cell (hi-res image) Amit Goyal and his team of research scientists are using copper oxide to redesign the face of solar power....

  1. Oxygen Coverage Dependence of NO Oxidation on Pt(111). | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oxygen Coverage Dependence of NO Oxidation on Pt(111). Oxygen Coverage Dependence of NO Oxidation on Pt(111). Abstract: The interaction of NO with adsorbed atomic oxygen on Pt(111)...

  2. MICROSTRUCTURE-PROPERTY RELATIONSHIPS OF A ZINC OXIDE VARISTOR MATERIAL

    E-Print Network [OSTI]

    Williama, Pamela Louise

    2011-01-01T23:59:59.000Z

    barium, cobalt. and rare earth metal oxides, which exhibitthat the barium and rare earth metals concentrate into small2 o , Ti0 2 and even rare earth metal oxides Pr 2 o and La 2

  3. Synthesis and Characterization of Hydrous Ruthenium Oxide-Carbon Supercapacitors

    E-Print Network [OSTI]

    Popov, Branko N.

    as compared to bare carbon. An electroless deposition process was used to synthesize the ruthenium oxideO2, Co3O4, and NiO2. Nickel oxide films have been synthesized both electrochemically4 and also

  4. Solid Oxide Fuel Cell and Power System Development at PNNL

    Broader source: Energy.gov (indexed) [DOE]

    Solid Oxide Fuel Cell and Power Solid Oxide Fuel Cell and Power S t D l t t PNNL S t D l t t PNNL System Development at PNNL System Development at PNNL Larry Chick Energy Materials...

  5. Porous anodic aluminum oxide scaffolds; formation mechanisms and applications

    E-Print Network [OSTI]

    Oh, Jihun

    2010-01-01T23:59:59.000Z

    Nanoporous anodic aluminium oxide (AAO) can be created with pores that self-assemble into ordered configurations. Nanostructured metal oxides have proven to be very useful as scaffolds for growth of nanowires and nanotubes ...

  6. Oxidation of Polymer-derived SiAICN Ceramics. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    decrease in oxidation rate. Citation: Wang Y, L An, Y Fan, L Zhang, SD Burton, and Z Gan.2005."Oxidation of Polymer-derived SiAICN Ceramics."Journal of the American Ceramic...

  7. Near room temperature lithographically processed metal-oxide transistors

    E-Print Network [OSTI]

    Tang, Hui, M. Eng. Massachusetts Institute of Technology

    2008-01-01T23:59:59.000Z

    A fully lithographic process at near-room-temperature was developed for the purpose of fabricating transistors based on metal-oxide channel materials. The combination of indium tin oxide (ITO) as the source/drain electrodes, ...

  8. Microbial Lithotrophic Oxidation of Structural Fe(II) in Biotite...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of weathering. Here we show that a lithotrophic Fe(II)-oxidizing, nitrate-reducing enrichment culture (Straub, 6 1996) can grow via oxidation of structural Fe(II) in biotite, a...

  9. Solid oxide fuel cell having monolithic core

    DOE Patents [OSTI]

    Ackerman, J.P.; Young, J.E.

    1983-10-12T23:59:59.000Z

    A solid oxide fuel cell is described for electrochemically combining fuel and oxidant for generating galvanic output, wherein the cell core has an array of electrolyte and interconnect walls that are substantially devoid of any composite inert materials for support. Instead, the core is monolithic, where each electrolyte wall consists of thin layers of cathode and anode materials sandwiching a thin layer of electrolyte material therebetween. The electrolyte walls are arranged and backfolded between adjacent interconnect walls operable to define a plurality of core passageways alternately arranged where the inside faces thereof have only the anode material or only the cathode material exposed. Means direct the fuel to the anode-exposed core passageways and means direct the oxidant to the anode-exposed core passageways and means direct the oxidant to the cathode-exposed core passageway; and means also direct the galvanic output to an exterior circuit. Each layer of the electrolyte and interconnect materials is of the order of 0.002 to 0.01 cm thick; and each layer of the cathode and anode materials is of the order of 0.002 to 0.05 cm thick.

  10. Nitrated metalloporphyrins as catalysts for alkane oxidation

    DOE Patents [OSTI]

    Ellis, Jr., Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA)

    1994-01-01T23:59:59.000Z

    Compositions of matter comprising nitro-substituted metal complexes of porphyrins are catalysts for the oxidation of alkanes. The metal is iron, chromium, manganese, ruthenium, copper or cobalt. The porphyrin ring has nitro groups attached thereto in meso and/or .beta.-pyrrolic positions.

  11. Potential oxidative stress due to Pb exposure

    E-Print Network [OSTI]

    Elms, Rene' Davina

    2013-02-22T23:59:59.000Z

    increases in oxidation of glutathione in K562 myelogenous leukemia cells at low Pb levels. The approach consisted of incubating K562 cells in solutions of 0, 300, and 700 ppb Pb dissolved in RPMI cell medium for a total of 96 hours. After this period...

  12. Metal-supported solid oxide fuel cells

    SciTech Connect (OSTI)

    Villarreal, I.; Jacobson, C.; Leming, A.; Matus, Y.; Visco, S.; De Jonghe, L.

    2003-01-07T23:59:59.000Z

    Low cost, colloidal deposition methods have been utilized to produce novel solid oxide fuel cell structures on metal alloy support electrodes. YSZ films were deposited on iron-chrome supports on top of a thin Ni/YSZ catalytic layer, and sintered at 1350 degrees C, in a reducing atmosphere. Dense, 20??m YSZ electrolyte films were obtained on highly porous stainless steel substrates.

  13. Molybdenum oxide electrodes for thermoelectric generators

    DOE Patents [OSTI]

    Schmatz, Duane J. (Dearborn Heights, MI)

    1989-01-01T23:59:59.000Z

    The invention is directed to a composite article suitable for use in thermoelectric generators. The article comprises a thin film comprising molybdenum oxide as an electrode deposited by physical deposition techniques onto solid electrolyte. The invention is also directed to the method of making same.

  14. Lithium metal oxide electrodes for lithium batteries

    DOE Patents [OSTI]

    Thackeray, Michael M.; Johnson, Christopher S.; Amine, Khalil; Kang, Sun-Ho

    2010-06-08T23:59:59.000Z

    An uncycled preconditioned electrode for a non-aqueous lithium electrochemical cell including a lithium metal oxide having the formula xLi.sub.2-yH.sub.yO.xM'O.sub.2.(1-x)Li.sub.1-zH.sub.zMO.sub.2 in which 0oxidation state selected from two or more of the first row transition metals or lighter metal elements in the periodic table, and M' is one or more ions with an average tetravalent oxidation state selected from the first and second row transition metal elements and Sn. The xLi.sub.2-yH.sub.y.xM'O.sub.2.(1-x)Li.sub.1-zH.sub.zMO.sub.2 material is prepared by preconditioning a precursor lithium metal oxide (i.e., xLi.sub.2M'O.sub.3.(1-x)LiMO.sub.2) with a proton-containing medium with a pH<7.0 containing an inorganic acid. Methods of preparing the electrodes are disclosed, as are electrochemical cells and batteries containing the electrodes.

  15. Nitrogen oxide abatement by distributed fuel addition

    SciTech Connect (OSTI)

    Wendt, J.O.L.; Mereb, J.B.

    1989-06-20T23:59:59.000Z

    A combustor has been designed in order to retard the formation of nitrogen oxides by injection of reburning fuel. The design and the rebuilding of the new combustor was completed. Several new features were incorporated in the new design so that it would last longer. The design and construction of the furnace are discussed in this report. (VC)

  16. Oxide strengthened molybdenum-rhenium alloy

    DOE Patents [OSTI]

    Bianco, Robert (Cleveland, OH); Buckman, Jr., R. William (Pittsburgh, PA)

    2000-01-01T23:59:59.000Z

    Provided is a method of making an ODS molybdenum-rhenium alloy which includes the steps of: (a) forming a slurry containing molybdenum oxide and a metal salt dispersed in an aqueous medium, the metal salt being selected from nitrates or acetates of lanthanum, cerium or thorium; (b) heating the slurry in the presence of hydrogen to form a molybdenum powder comprising molybdenum and an oxide of the metal salt; (c) mixing rhenium powder with the molybdenum powder to form a molybdenum-rhenium powder; (d) pressing the molybdenum-rhenium powder to form a molybdenum-rhenium compact; (e) sintering the molybdenum-rhenium compact in hydrogen or under a vacuum to form a molybdenum-rhenium ingot; and (f) compacting the molybdenum-rhenium ingot to reduce the cross-sectional area of the molybdenum-rhenium ingot and form a molybdenum-rhenium alloy containing said metal oxide. The present invention also provides an ODS molybdenum-rhenium alloy made by the method. A preferred Mo--Re-ODS alloy contains 7-14 weight % rhenium and 2-4 volume % lanthanum oxide.

  17. Nitrated metalloporphyrins as catalysts for alkane oxidation

    DOE Patents [OSTI]

    Ellis, Jr., Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA)

    1992-01-01T23:59:59.000Z

    Alkanes are oxidized by contact with oxygen-containing gas in the presence as catalyst of a metalloporphyrin in which hydrogen atoms in the porphyrin ring have been replaced with one or more nitro groups. Hydrogen atoms in the porphyrin ring may also be substituted with halogen atoms.

  18. ADVANCED OXIDATION PROCESSES FOR THE REMOVAL OF

    E-Print Network [OSTI]

    Boyer, Edmond

    ADVANCED OXIDATION PROCESSES FOR THE REMOVAL OF RESIDUAL NON-STEROIDAL ANTI- INFLAMMATORY. G. Esposito, PhD, MSc Associate Professor of Sanitary and Environmental Engineering University in Biogeochemistry University of Paris-Est Paris, France Prof. dr. ir P.N.L. Lens Professor of Biotechnology UNESCO

  19. Metal current collect protected by oxide film

    DOE Patents [OSTI]

    Jacobson, Craig P. (Lafayette, CA); Visco, Steven J. (Berkeley, CA); DeJonghe, Lutgard C. (Lafayette, CA)

    2004-05-25T23:59:59.000Z

    Provided are low-cost, mechanically strong, highly electronically conductive current collects and associated structures for solid-state electrochemical devices, techniques for forming these structures, and devices incorporating the structures. The invention provides solid state electrochemical devices having as current interconnects a ferritic steel felt or screen coated with a protective oxide film.

  20. Chemical vapor deposition of aluminum oxide

    DOE Patents [OSTI]

    Gordon, Roy (Cambridge, MA); Kramer, Keith (Cleveland, OH); Liu, Xinye (Cambridge, MA)

    2000-01-01T23:59:59.000Z

    An aluminum oxide film is deposited on a heated substrate by CVD from one or more alkylaluminum alkoxide compounds having composition R.sub.n Al.sub.2 (OR').sub.6-n, wherein R and R' are alkyl groups and n is in the range of 1 to 5.

  1. Nitrated metalloporphyrins as catalysts for alkane oxidation

    DOE Patents [OSTI]

    Ellis, P.E. Jr.; Lyons, J.E.

    1994-01-18T23:59:59.000Z

    Compositions of matter comprising nitro-substituted metal complexes of porphyrins are catalysts for the oxidation of alkanes. The metal is iron, chromium, manganese, ruthenium, copper or cobalt. The porphyrin ring has nitro groups attached thereto in meso and/or [beta]-pyrrolic positions.

  2. Filled glass composites for sealing of solid oxide fuel cells.

    SciTech Connect (OSTI)

    Tandon, Rajan; Widgeon, Scarlett Joyce; Garino, Terry J.; Brochu, Mathieu; Gauntt, Bryan D.; Corral, Erica L.; Loehman, Ronald E.

    2009-04-01T23:59:59.000Z

    Glasses filled with ceramic or metallic powders have been developed for use as seals for solid oxide fuel cells (SOFC's) as part of the U.S. Department of Energy's Solid State Energy Conversion Alliance (SECA) Program. The composites of glass (alkaline earth-alumina-borate) and powders ({approx}20 vol% of yttria-stabilized zirconia or silver) were shown to form seals with SOFC materials at or below 900 C. The type and amount of powder were adjusted to optimize thermal expansion to match the SOFC materials and viscosity. Wetting studies indicated good wetting was achieved on the micro-scale and reaction studies indicated that the degree of reaction between the filled glasses and SOFC materials, including spinel-coated 441 stainless steel, at 750 C is acceptable. A test rig was developed for measuring strengths of seals cycled between room temperature and typical SOFC operating temperatures. Our measurements showed that many of the 410 SS to 410 SS seals, made using silver-filled glass composites, were hermetic at 0.2 MPa (2 atm.) of pressure and that seals that leaked could be resealed by briefly heating them to 900 C. Seal strength measurements at elevated temperature (up to 950 C), measured using a second apparatus that we developed, indicated that seals maintained 0.02 MPa (0.2 atm.) overpressures for 30 min at 750 C with no leakage. Finally, the volatility of the borate component of sealing glasses under SOFC operational conditions was studied using weight loss measurements and found by extrapolation to be less than 5% for the projected SOFC lifetime.

  3. Efficient and Sustained Photoelectrochemical Water Oxidation by Cobalt Oxide/Silicon Photoanodes with Nanotextured Interfaces

    E-Print Network [OSTI]

    Javey, Ali

    photoelectrochem- ical water oxidation was observed with no detectable degradation after 24 h. Enhanced performance spectrum, is earth-abundant, and is widely used in photovoltaic applications.5 However, the realization

  4. On the Design of Oxide Films, Nanomaterials, and Heterostructures for Solar Water Oxidation Photoanodes

    E-Print Network [OSTI]

    Kronawitter, Coleman

    2012-01-01T23:59:59.000Z

    of high-surface-area SnO 2 aerogels, Kucheyev et al. 39previously in SnO 2 aerogels 39 and nanoribbons. 41 It isstudy of titanium oxide aerogels, and through comparisons

  5. Biological Oxidation of Fe(II) in Reduced Nontronite Coupled with Nitrate Reduction by Pseudogulbenkiania sp. Strain 2002

    SciTech Connect (OSTI)

    Zhao, Linduo; Dong, Hailiang; Kukkadapu, Ravi K.; Agrawal, A.; Liu, Deng; Zhang, Jing; Edelmann, Richard E.

    2013-10-15T23:59:59.000Z

    Nitrate contamination in soils, sediments, and water bodies is a significant issue. Although much is known about nitrate degradation in these environments, especially via microbial pathways, a complete understanding of all degradation processes, especially in clay mineral-rich soils, is still lacking. The objective of this study was to study the potential of removing nitrate contaminant using structural Fe(II) in clay mineral nontronite. Specifically, the coupled processes of microbial oxidation of Fe(II) in microbially reduced nontronite (NAu-2) and nitrate reduction by Pseudogulbenkiania species strain 2002 was investigated. Bio-oxidation experiments were conducted in bicarbonate-buffered medium under both growth and nongrowth conditions. The extents of Fe(II) oxidation and nitrate reduction were measured by wet chemical methods. X-ray diffraction (XRD), scanning and transmission electron microscopy (SEM and TEM), and 57Fe-Mössbauer spectroscopy were used to observe mineralogical changes associated with Fe(III) reduction and Fe(II) oxidation in nontronite. The bio-oxidation extent under growth and nongrowth conditions reached 93% and 57%, respectively. Over the same time period, nitrate was completely reduced under both conditions to nitrogen gas (N2), via an intermediate product nitrite. Magnetite was a mineral product of nitrate-dependent Fe(II) oxidation, as evidenced by XRD data and TEM diffraction patterns. The results of this study highlight the importance of iron-bearing clay minerals in the global nitrogen cycle with potential applications in nitrate removal in soils.

  6. BIOAVAILABILITY OF BERYLLIUM OXIDE PARTICLES: AN IN VITRO STUDY IN THE MURINE J774A.1 MACROPHAGE CELL LINE MODEL

    E-Print Network [OSTI]

    Illinois at Chicago, University of

    BIOAVAILABILITY OF BERYLLIUM OXIDE PARTICLES: AN IN VITRO STUDY IN THE MURINE J774A.1 MACROPHAGE/04/10 Forpersonaluseonly. #12;Ronald C. Scripsick & Los Alamos National Laboratory, Los Alamos, New Mexico, USA & Beryllium is assessed through measurement of beryllium aerosol mass con- centration. Compliance with the current mass

  7. Oxidized AlxGa1 xAs heterostructure planar waveguides D. C. Hall, and L. Kou

    E-Print Network [OSTI]

    for publication 20 September 1999 Waveguiding by total internal reflection is demonstrated within AlxGa1 x profile, and Fourier transform infrared transmission spectra measurements are presented to characterize 0.4 and x 0.8 AlxGa1 xAs oxide layers. Absorption loss at 1.55 m is observed due to OH groups. Near

  8. tall tower facility and instrumentation New coNstraiNts oN the Nitrous oxide budget of agricultural ecosystems

    E-Print Network [OSTI]

    Minnesota, University of

    tall tower facility and instrumentation New coNstraiNts oN the Nitrous oxide budget of agricultural approach involves multiple tunable diode laser (TDL) spectroscopy systems, a tall tower, automated chambers hectare. Measurements are also made at the tall tower trace gas observatory (TGO) located at RROC

  9. ATOMIC-LAYER-DEPOSITED ALUMINUM OXIDE FOR THE SURFACE PASSIVATION OF HIGH-EFFICIENCY SILICON SOLAR CELLS

    E-Print Network [OSTI]

    ATOMIC-LAYER-DEPOSITED ALUMINUM OXIDE FOR THE SURFACE PASSIVATION OF HIGH-EFFICIENCY SILICON SOLAR to those measured on reference cells passivated by an aluminum-annealed thermal SiO2, while those of the Al of aluminum ox- ide (Al2O3) grown by atomic layer deposition (ALD) pro- vide an excellent level of sur

  10. Mercury Absorption in Aqueous Oxidants Catalyzed by Mercury(II) Lynn L. Zhao and Gary T. Rochelle*

    E-Print Network [OSTI]

    Rochelle, Gary T.

    Mercury Absorption in Aqueous Oxidants Catalyzed by Mercury(II) Lynn L. Zhao and Gary T. Rochelle-1062 The absorption of elemental Hg vapor into aqueous solution containing Hg(II) was measured in a stirred cell at 25 °C. For mercury absorption in Hg(II) obtained by HgCl2 injection, the presence of HNO3 greatly

  11. Process Modeling of Global Soil Nitrous Oxide Emissions

    E-Print Network [OSTI]

    Saikawa, E.

    2011-09-01T23:59:59.000Z

    Nitrous oxide is an important greenhouse gas and is a major ozone-depleting substance. To understand and

  12. The oxidation of soot and carbon monoxide in hydrocarbon diffusion flames

    SciTech Connect (OSTI)

    Puri, R.; Santoro, R.J. (Pennsylvania State Univ., University Park, PA (United States). Dept. of Mechanical Engineering); Smyth, K.C. (National Inst. of Standards and Technology, Gaithersburg, MD (United States). Building and Fire Research Lab.)

    1994-05-01T23:59:59.000Z

    Quantitative hydroxyl radical concentrations and primary soot particle sizes have been determined in the soot oxidation regions of axisymmetric diffusion flames burning methane, methane/butane, and methane/1-butene in air at atmospheric pressure. The total carbon flow rate was held constant in these flames while the maximum amount of soot varied by a factor of seven along the centerline. Laser-induced fluorescence measurements of OH were placed on an absolute basis by calibration against earlier absorption results. The primary size measurements of the soot particles were made using thermophoretic sampling and transmission electron microscopy. OH concentrations are greatly reduced in the presence of soot particles. Whereas large super-equilibrium ratios are observed in the high-temperature reaction zones in the absence of soot, the OH concentrations approach equilibrium values when the soot loading is high. The diminished OH concentrations are found to arise from reactions with the soot particles and only to a minor degree from lower temperatures due to soot radiation losses. Analysis of the soot oxidation rates computed from the primary particle size profiles as a function of time along the flame centerlines shows that OH is the dominant oxidizer of soot, with O[sub 2] making only a small contribution. Higher collision efficiencies of OH reactions with soot particles are found for the flames containing larger soot concentrations at lower temperatures. A comparison of the soot and CO oxidation rates shows that although CO is inherently more reactive than soot, the soot successfully competes with CO for OH and hence suppresses CO oxidation for large soot concentrations.

  13. Systemic inflammatory changes and increased oxidative stress in rural Indian women cooking with biomass fuels

    SciTech Connect (OSTI)

    Dutta, Anindita, E-mail: anidu14@gmail.com [College of Environmental Sciences and Engineering, Peking University, Beijing (China) [College of Environmental Sciences and Engineering, Peking University, Beijing (China); Department of Experimental Hematology, Chittaranjan National Cancer Institute, 37, S.P. Mukherjee Road, Kolkata-700 026 (India); Ray, Manas Ranjan; Banerjee, Anirban [Department of Experimental Hematology, Chittaranjan National Cancer Institute, 37, S.P. Mukherjee Road, Kolkata-700 026 (India)] [Department of Experimental Hematology, Chittaranjan National Cancer Institute, 37, S.P. Mukherjee Road, Kolkata-700 026 (India)

    2012-06-15T23:59:59.000Z

    The study was undertaken to investigate whether regular cooking with biomass aggravates systemic inflammation and oxidative stress that might result in increase in the risk of developing cardiovascular disease (CVD) in rural Indian women compared to cooking with a cleaner fuel like liquefied petroleum gas (LPG). A total of 635 women (median age 36 years) who cooked with biomass and 452 age-matched control women who cooked with LPG were enrolled. Serum interleukin-6 (IL-6), C-reactive protein (CRP), tumor necrosis factor-alpha (TNF-?) and interleukin-8 (IL-8) were measured by ELISA. Generation of reactive oxygen species (ROS) by leukocytes was measured by flow cytometry, and erythrocytic superoxide dismutase (SOD) was measured by spectrophotometry. Hypertension was diagnosed following the Seventh Report of the Joint Committee. Tachycardia was determined as pulse rate > 100 beats per minute. Particulate matter of diameter less than 10 and 2.5 ?m (PM{sub 10} and PM{sub 2.5}, respectively) in cooking areas was measured using real-time aerosol monitor. Compared with control, biomass users had more particulate pollution in indoor air, their serum contained significantly elevated levels of IL-6, IL-8, TNF-? and CRP, and ROS generation was increased by 37% while SOD was depleted by 41.5%, greater prevalence of hypertension and tachycardia compared to their LPG-using neighbors. PM{sub 10} and PM{sub 2.5} levels were positively associated with markers of inflammation, oxidative stress and hypertension. Inflammatory markers correlated with raised blood pressure. Cooking with biomass exacerbates systemic inflammation, oxidative stress, hypertension and tachycardia in poor women cooking with biomass fuel and hence, predisposes them to increased risk of CVD development compared to the controls. Systemic inflammation and oxidative stress may be the mechanistic factors involved in the development of CVD. -- Highlights: ? Effect of chronic biomass smoke exposure on cardiovascular health was investigated. ? Serum markers of systemic inflammation and oxidative stress were studied. ? Biomass using women had increased systemic inflammation and oxidative stress. ? Indoor air pollution and observed changes were positively associated.

  14. Graphite Oxidation Simulation in HTR Accident Conditions

    SciTech Connect (OSTI)

    El-Genk, Mohamed

    2012-10-19T23:59:59.000Z

    Massive air and water ingress, following a pipe break or leak in steam-generator tubes, is a design-basis accident for high-temperature reactors (HTRs). Analysis of these accidents in both prismatic and pebble bed HTRs requires state-of-the-art capability for predictions of: 1) oxidation kinetics, 2) air ?helium gas mixture stratification and diffusion into the core following the depressurization, 3) transport of multi-species gas mixture, and 4) graphite corrosion. This project will develop a multi-dimensional, comprehensive oxidation kinetics model of graphite in HTRs, with diverse capabilities for handling different flow regimes. The chemical kinetics/multi-species transport model for graphite burning and oxidation will account for temperature-related changes in the properties of graphite, oxidants (O2, H2O, CO), reaction products (CO, CO2, H2, CH4) and other gases in the mixture (He and N2). The model will treat the oxidation and corrosion of graphite in geometries representative of HTR core component at temperatures of 900°C or higher. The developed chemical reaction kinetics model will be user-friendly for coupling to full core analysis codes such as MELCOR and RELAP, as well as computational fluid dynamics (CFD) codes such as CD-adapco. The research team will solve governing equations for the multi-dimensional flow and the chemical reactions and kinetics using Simulink, an extension of the MATLAB solver, and will validate and benchmark the model's predictions using reported experimental data. Researchers will develop an interface to couple the validated model to a commercially available CFD fluid flow and thermal-hydraulic model of the reactor , and will perform a simulation of a pipe break in a prismatic core HTR, with the potential for future application to a pebble-bed type HTR.

  15. Design of Inherently Safer Complex Reactive Processes: Application on the N-Oxidation of Alkylpyridines

    E-Print Network [OSTI]

    Pineda Solano, Alba Lucia

    2014-04-18T23:59:59.000Z

    Alkylpyridine N-oxides are important intermediates in the pharmaceutical industry. The N-oxides are produced via the homogeneously catalyzed N-oxidation of the respective alkylpyridines using hydrogen peroxide as the oxidizing agent...

  16. Versatile ferrofluids based on polyethylene glycol coated iron oxide nanoparticles

    E-Print Network [OSTI]

    Versatile ferrofluids based on polyethylene glycol coated iron oxide nanoparticles W. Brullot a coated iron oxide nanoparticles were obtained by a facile protocol and thoroughly characterized to chemical treatments and biocompatible [12]. An impression of an iron oxide nanoparticle coated with a PEG

  17. Selective thermal oxidation of hydrocarbons in zeolites by oxygen

    DOE Patents [OSTI]

    Frei, Heinz (Berkeley, CA); Blatter, Fritz (Basel, CH); Sun, Hai (Saint Charles, MO)

    2000-01-01T23:59:59.000Z

    A process for selective thermal oxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls is carried out in solvent free zeolites under dark thermal conditions. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.

  18. Solid Oxide Fuel Cell: Perspective of Dynamic Modeling and Control

    E-Print Network [OSTI]

    Huang, Biao

    Solid Oxide Fuel Cell: Perspective of Dynamic Modeling and Control Biao Huang Yutong Qi Monjur: This paper presents a review of state-of-the-art solid oxide fuel cells (SOFC), from perspective of dynamic. Keywords: Solid Oxide Fuel Cell, Control Relevant Model, Model Predictive Control 1. INTRODUCTION Today

  19. A New Instrument For Characterizing Solid Oxide Fuel Cell Catalysts

    E-Print Network [OSTI]

    RESEARCH HIGHLIGHTS A New Instrument For Characterizing Solid Oxide Fuel Cell Catalysts From fuels to renewable energy sources. Solid oxide fuel cells (SOFCs) have enormous potential in this area A New Instrument For Characterizing Solid Oxide Fuel Cell Catalysts Rob Usiskin In partnership

  20. COMPUTATIONAL FLUID DYNAMICS MODELING OF SOLID OXIDE FUEL CELLS

    E-Print Network [OSTI]

    COMPUTATIONAL FLUID DYNAMICS MODELING OF SOLID OXIDE FUEL CELLS Ugur Pasaogullari and Chao-dimensional model has been developed to simulate solid oxide fuel cells (SOFC). The model fully couples current density operation. INTRODUCTION Solid oxide fuel cells (SOFC) are among possible candidates