National Library of Energy BETA

Sample records for meable cap rock

  1. Failure of cap-rock seals as determined from mechanical stratigraphy, stress history, and tensile-failure analysis of exhumed analogs

    SciTech Connect (OSTI)

    Petrie, E. S.; Evans, J. P.; Bauer, S. J.

    2014-11-01

    In this study, the sedimentologic and tectonic histories of clastic cap rocks and their inherent mechanical properties control the nature of permeable fractures within them. The migration of fluid through mm- to cm-scale fracture networks can result in focused fluid flow allowing hydrocarbon production from unconventional reservoirs or compromising the seal integrity of fluid traps. To understand the nature and distribution of subsurface fluid-flow pathways through fracture networks in cap-rock seals we examine four exhumed Paleozoic and Mesozoic seal analogs in Utah. We combine these outcrop analyses with subsidence analysis, paleoloading histories, and rock-strength testing data in modified Mohr–Coulomb–Griffith analyses to evaluate the effects of differential stress and rock type on fracture mode.

  2. Failure of cap-rock seals as determined from mechanical stratigraphy, stress history, and tensile-failure analysis of exhumed analogs

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Petrie, E. S.; Evans, J. P.; Bauer, S. J.

    2014-11-01

    In this study, the sedimentologic and tectonic histories of clastic cap rocks and their inherent mechanical properties control the nature of permeable fractures within them. The migration of fluid through mm- to cm-scale fracture networks can result in focused fluid flow allowing hydrocarbon production from unconventional reservoirs or compromising the seal integrity of fluid traps. To understand the nature and distribution of subsurface fluid-flow pathways through fracture networks in cap-rock seals we examine four exhumed Paleozoic and Mesozoic seal analogs in Utah. We combine these outcrop analyses with subsidence analysis, paleoloading histories, and rock-strength testing data in modified Mohr–Coulomb–Griffith analysesmore » to evaluate the effects of differential stress and rock type on fracture mode.« less

  3. Geomechanical Simulation of CO{sub 2} Leakage and Cap Rock Remediation

    SciTech Connect (OSTI)

    Nygaard, Runar; Bai, Baojun; Eckert, Andreas

    2012-09-30

    CO{sub 2} sequestration into porous and permeable brine filled aquifers is seen as one of the most likely near-term solutions for reducing greenhouse gases. Safely storing injected CO{sub 2}, which is less dense than water, requires trapping the CO{sub 2} under an impermeable rock which would act as a seal. One of the concerns with CO{sub 2} sequestration is the generation of new fractures or reactivation of existing fractures and faults caused by CO{sub 2} injection into the sealing formation. Mitigation strategies must be developed to remediate potentially leaking faults or fractures. This project evaluated potential storage scenarios in the state of Missouri and developed coupled reservoir and geomechanic simulations to identify storage potential and leakage risks. Further, several injectable materials used to seal discontinuities were evaluated under subsurface conditions. The four sealant materials investigated were paraffin wax, silica based gel, polymer based gel, and micro-cement, which all significantly reduced the fracture permeability. However, the micro-cement was the most effective sealing agent and the only sealant able to withstand the large differential pressure caused by CO{sub 2} or brine injection and create a strong seal to prevent further fracturing.

  4. Black Rock Point Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Features: Relict Geothermal Features: Volcanic Age: Host Rock Age: Host Rock Lithology: Cap Rock Age: Cap Rock Lithology: Click "Edit With Form" above to add content Geofluid...

  5. Rocks

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rocks Rocks Rocks have been used by mankind throughout history. In geology, rock is a naturally occurring composite of one or more minerals or mineraloids. One of our most popular...

  6. C:\ANNUAL\Vol2chps.v8\ANNUAL2.VP

    Gasoline and Diesel Fuel Update (EIA)

    7 Glossary Aquifer Field: A sub-surface facility for storing natural gas consisting of water-bearing sands topped by an imper- meable cap rock. Balancing Item: Represents differences between the sum of the components of natural gas supply and the sum of the components of natural gas disposition. These differences may be due to quantities lost or to the effects of data-reporting problems. Reporting problems include differences due to the net result of conversions of flow data metered at varying

  7. Lithology and alteration mineralogy of reservoir rocks at Coso...

    Open Energy Info (EERE)

    using petrographic and analytical analyses of reservoir rock and vein material. The nature of the low-angle outflow zone and the overlying cap that prevents a surface expression...

  8. Lithology and Alteration Mineralogy of Reservoir Rocks at Coso...

    Open Energy Info (EERE)

    using petrographic and analytical analyses of reservoir rock and vein material. The nature of the low-angle outflow zone and the overlying cap that prevents a surface expression...

  9. The Hanford Site 1000-Year Cap Design Test

    SciTech Connect (OSTI)

    Gee, Glendon W. ); Ward, Anderson L. ); Wittreich, Curtis D.

    2002-12-27

    Surface barrier or capping technology is needed to isolate buried wastes. A successful cap must prevent the intrusion of plants, animals, and man into the underlying waste, minimize wind and water erosion, require minimal maintenance, and limit water intrusion to near-zero amounts. For some sites where wastes are long-lived, caps should potentially last a thousand years or more. At the U.S. Department of Energy (DOE) Hanford Site in Washington State, a surface cap with a 1000-year design life was constructed and then tested and monitored for performance under wetting conditions that are extreme for the region. The cap was built in 1994 over an existing waste site as a part of a Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) treatability test. The above-grade barrier or cap consists of a 2-m-thick silt-loam soil overlying layers (from top down) of sand, gravel, basalt rock (riprap), and a low-permeability asphalt. Two sideslope configurations, a clean-fill gravel on a 10:1 slope and a basalt riprap on a 2:1 slope were part of the overall design and testing. Design considerations included constructability; water-balance monitoring; wind and water erosion control and monitoring; surface revegetation, biointrusion control, subsidence, and sideslope stability; and durability of the asphalt layer.

  10. Property:CapRockAge | Open Energy Information

    Open Energy Info (EERE)

    Amedee Geothermal Area + Tertiary + B Beowawe Hot Springs Geothermal Area + Tertiary + Brady Hot Springs Geothermal Area + Tertiary + D Desert Peak Geothermal Area + Tertiary + G...

  11. Property:CapRockLithology | Open Energy Information

    Open Energy Info (EERE)

    + Hydrothermal alteration layer + Bouillante Geothermal Area + Illite-Smectite Clay + Brady Hot Springs Geothermal Area + Hydrothermally altered volcanics + C Cerro Prieto...

  12. CAP Program Guidance | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CAP Program Guidance CAP Program Guidance In 2002, the Department of Energy signed an interagency agreement with the Department of Defense's Computer/Electronic Accommodations Program (CAP) program to provide assistive/adaptive technology free of charge to DOE employees with disabilities. The following information regarding CAP is being provided to assist federal employees, managers and on- site disability coordinators with the CAP application process. PDF icon CAP Program Guidance Responsible

  13. Stuck fuel rod capping sleeve

    DOE Patents [OSTI]

    Gorscak, Donald A. (Bethel Park, PA); Maringo, John J. (McKeesport, PA); Nilsen, Roy J. (Upper St. Clair, PA)

    1988-01-01

    A stuck fuel rod capping sleeve to be used during derodding of spent fuel assemblies if a fuel rod becomes stuck in a partially withdrawn position and, thus, has to be severed. The capping sleeve has an inner sleeve made of a lower work hardening highly ductile material (e.g., Inconel 600) and an outer sleeve made of a moderately ductile material (e.g., 304 stainless steel). The inner sleeve may be made of an epoxy filler. The capping sleeve is placed on a fuel rod which is then severed by using a bolt cutter device. Upon cutting, the capping sleeve deforms in such a manner as to prevent the gross release of radioactive fuel material

  14. Leach Capping | Open Energy Information

    Open Energy Info (EERE)

    silica Other definitions:Wikipedia Reegle Relict Geothermal Features Typical list of modern geothermal features Hydrothermally Deposited Rock Silica Deposition Carbonate...

  15. ARM - Instrument - caps-pmex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govInstrumentscaps-pmex Documentation ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Instrument : Cavity Attenuated Phase Shift Extinction Monitor (CAPS-PMEX) Instrument Categories Aerosols, Airborne Observations The CAPS-PMEX is part of the Aerosol Observing System (AOS). See Also Contact(s) Arthur Sedlacek Brookhaven National Laboratory (631) 344-2404 sedlacek@bnl.gov Alison Tilp Brookhaven National Laboratory

  16. APowerCap Technologies | Open Energy Information

    Open Energy Info (EERE)

    Technologies Jump to: navigation, search Name: APowerCap Technologies Place: Chaiki, Ukraine Zip: 8130 Product: APCT develops breakthrough ultracapacitor-based power modules for...

  17. Cap May County Municipal Utilities Authority | Open Energy Information

    Open Energy Info (EERE)

    Cap May County Municipal Utilities Authority Jump to: navigation, search Name: Cap May County Municipal Utilities Authority Place: Cape May Court House, New Jersey Zip: 8210...

  18. Capping methane leaks a win-win

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Capping methane leaks a win-win Capping methane leaks a win-win As special correspondent Kathleen McCleery explains, that's why both environmentalists and the energy industry are trying to find ways to capture leaks from oil and gas facilities. November 13, 2015 Capping methane leaks a win-win Methane, the primary component of natural gas, is also a potent greenhouse gas, trapping energy in the atmosphere. Last year NASA released satellite images showing a hot spot in the area where New Mexico,

  19. CeCap LLP | Open Energy Information

    Open Energy Info (EERE)

    Name: CeCap LLP Place: London, United Kingdom Zip: W1S 2LQ Product: London-based investment boutique which provides investment advice to, and invests in, small to mediun size...

  20. CAP XX Pty Ltd | Open Energy Information

    Open Energy Info (EERE)

    Zip: NSW 2066 Product: Australia-based designer and manufacturer of high power density supercapacitors. References: CAP-XX Pty Ltd1 This article is a stub. You can help...

  1. Tip cap for a turbine rotor blade

    DOE Patents [OSTI]

    Kimmel, Keith D

    2014-03-25

    A turbine rotor blade with a spar and shell construction, and a tip cap that includes a row of lugs extending from a bottom side that form dovetail grooves that engage with similar shaped lugs and grooves on a tip end of the spar to secure the tip cap to the spar against radial displacement. The lug on the trailing edge end of the tip cap is aligned perpendicular to a chordwise line of the blade in the trailing edge region in order to minimize stress due to the lugs wanting to bend under high centrifugal loads. A two piece tip cap with lugs at different angles will reduce the bending stress even more.

  2. Subsea tree cap well choke system

    SciTech Connect (OSTI)

    Bednar, J.M.

    1991-04-30

    This patent describes an apparatus useful in subsea well completions requiring a subsea choke. It comprises: a wellhead connector; a tree flow passage; a tree annulus passage; a tree cap; a choke; and a production line.

  3. Perfluorocarbon vapor tagging of blasting cap detonators

    DOE Patents [OSTI]

    Dietz, Russell N. (Shoreham, NY); Senum, Gunnar I. (Patchogue, NY)

    1981-01-01

    A plug for a blasting cap is made of an elastomer in which is dissolved a perfluorocarbon. The perfluorocarbon is released as a vapor into the ambient over a long period of time to serve as a detectable taggant.

  4. Valve Cap For An Electric Storage Cell

    DOE Patents [OSTI]

    Verhoog, Roelof (Bordeaux, FR); Genton, Alain (Merignac, FR)

    2000-04-18

    The valve cap for an electric storage cell includes a central annular valve seat (23) and a membrane (5) fixed by its peripheral edge and urged against the seat by a piston (10) bearing thereagainst by means of a spring (12), the rear end of said spring (12) bearing on the endwall (8) of a chamber (20) formed in the cap and containing the piston (10) and the spring. A vent (19) puts the chamber (20) into communication with the atmosphere. A central orifice (26, 28) through the piston (10) and the membrane (5), enables gas from within the cell to escape via the top vent (19) when the valve opens.

  5. DOE - Office of Legacy Management -- Slick Rock

    Office of Legacy Management (LM)

    Slick Rock Slick Rock Sites slick_map Slick Rock Disposal Site Slick Rock Processing Site Last Updated: 12/14

  6. Capping blowouts from Iran's 8-year war

    SciTech Connect (OSTI)

    Sayers, B. )

    1991-07-01

    Control well blown up by the Iraqi military were a 2 1/2 year legacy left the National Iranian Oil Co. at the end of this long conflict. This final installment of a 2-part series describes capping of the largest wind oil well.

  7. Detached rock evaluation device

    DOE Patents [OSTI]

    Hanson, David R. (Golden, CO)

    1986-01-01

    A rock detachment evaluation device (10) having an energy transducer unit 1) for sensing vibrations imparted to a subject rock (172) for converting the sensed vibrations into electrical signals, a low band pass filter unit (12) for receiving the electrical signal and transmitting only a low frequency segment thereof, a high band pass filter unit (13) for receiving the electrical signals and for transmitting only a high frequency segment thereof, a comparison unit (14) for receiving the low frequency and high frequency signals and for determining the difference in power between the signals, and a display unit (16) for displaying indicia of the difference, which provides a quantitative measure of rock detachment.

  8. Nuclear waste vitrification efficiency: cold cap reactions

    SciTech Connect (OSTI)

    Hrma, Pavel R.; Kruger, Albert A.; Pokorny, Richard

    2012-12-15

    The cost and schedule of nuclear waste treatment and immobilization are greatly affected by the rate of glass production. Various factors influence the performance of a waste-glass melter. One of the most significant, and also one of the least understood, is the process of batch melting. Studies are being conducted to gain fundamental understanding of the batch reactions, particularly those that influence the rate of melting, and models are being developed to link batch makeup and melter operation to the melting rate. Batch melting takes place within the cold cap, i.e., a batch layer floating on the surface of molten glass. The conversion of batch to glass consists of various chemical reactions, phase transitions, and diffusion-controlled processes. These include water evaporation (slurry feed contains as high as 60% water), gas evolution, the melting of salts, the formation of borate melt, reactions of borate melt with molten salts and with amorphous oxides (Fe2O3 and Al2O3), the formation of intermediate crystalline phases, the formation of a continuous glass-forming melt, the growth and collapse of primary foam, and the dissolution of residual solids. To this list we also need to add the formation of secondary foam that originates from molten glass but accumulates on the bottom of the cold cap. This study presents relevant data obtained for a high-level-waste melter feed and introduces a one-dimensional (1D) mathematical model of the cold cap as a step toward an advanced three-dimensional (3D) version for a complete model of the waste glass melter. The 1D model describes the batch-to-glass conversion within the cold cap as it progresses in a vertical direction. With constitutive equations and key parameters based on measured data, and simplified boundary conditions on the cold-cap interfaces with the glass melt and the plenum space of the melter, the model provides sensitivity analysis of the response of the cold cap to the batch makeup and melter conditions. The model demonstrates that batch foaming has a decisive influence on the rate of melting. Understanding the dynamics of the foam layer at the bottom of the cold cap and the heat transfer through it appears crucial for a reliable prediction of the rate of melting as a function of the melter-feed makeup and melter operation parameters. Although the study is focused on a batch for waste vitrification, the authors expect that the outcome will also be relevant for commercial glass melting.

  9. NUCLEAR WASTE VITRIFICATION EFFICIENCY COLD CAP REACTIONS

    SciTech Connect (OSTI)

    KRUGER AA; HRMA PR; POKORNY R

    2011-07-29

    The cost and schedule of nuclear waste treatment and immobilization are greatly affected by the rate of glass production. Various factors influence the performance of a waste-glass melter. One of the most significant, and also one of the least understood, is the process of batch melting. Studies are being conducted to gain fundamental understanding of the batch reactions, particularly those that influence the rate of melting, and models are being developed to link batch makeup and melter operation to the melting rate. Batch melting takes place within the cold cap, i.e., a batch layer floating on the surface of molten glass. The conversion of batch to glass consists of various chemical reactions, phase transitions, and diffusion-controlled processes. These include water evaporation (slurry feed contains as high as 60% water), gas evolution, the melting of salts, the formation of borate melt, reactions of borate melt with molten salts and with amorphous oxides (Fe{sub 2}O{sub 3} and Al{sub 2}O{sub 3}), the formation of intermediate crystalline phases, the formation of a continuous glass-forming melt, the growth and collapse of primary foam, and the dissolution of residual solids. To this list we also need to add the formation of secondary foam that originates from molten glass but accumulates on the bottom of the cold cap. This study presents relevant data obtained for a high-level-waste melter feed and introduces a one-dimensional (1D) mathematical model of the cold cap as a step toward an advanced three-dimensional (3D) version for a complete model of the waste glass melter. The 1D model describes the batch-to-glass conversion within the cold cap as it progresses in a vertical direction. With constitutive equations and key parameters based on measured data, and simplified boundary conditions on the cold-cap interfaces with the glass melt and the plenum space of the melter, the model provides sensitivity analysis of the response of the cold cap to the batch makeup and melter conditions. The model demonstrates that batch foaming has a decisive influence on the rate of melting. Understanding the dynamics of the foam layer at the bottom of the cold cap and the heat transfer through it appears crucial for a reliable prediction of the rate of melting as a function of the melter-feed makeup and melter operation parameters. Although the study is focused on a batch for waste vitrification, the authors expect that the outcome will also be relevant for commercial glass melting.

  10. Low flammability cap-sensitive flexible explosive composition

    DOE Patents [OSTI]

    Wagner, Martin G. (Wilmington, DE)

    1992-01-14

    A cap-sensitive flexible explosive composition of reduced flammability is provided by incorporating a finely divided, cap-sensitive explosive in a flame resistant polymeric binder system which contains a compatible flame retardant material.

  11. Rock slope stability

    SciTech Connect (OSTI)

    Kliche, C.A.

    1999-07-01

    Whether you're involved in surface mine design, surface mine production, construction, education, or regulation, this is an important new book for your library. It describes the basic rock slope failure modes and methods of analysis--both kinematic and kinetic techniques. Chapters include geotechnical and geomechanical analysis techniques, hydrology, rock slope stabilization techniques, and geotechnical instrumentation and monitoring. Numerous examples, drawings and photos enhance the text.

  12. Long-Term Engineered Cap Performance | Department of Energy

    Office of Environmental Management (EM)

    Engineered Cap Performance Long-Term Engineered Cap Performance Summary Notes from 22 July 2008 Generic Technical Issue Discussion on Long-Term Engineered Cap Performance PDF icon Summary Notes from 22 July 2008 Generic Technical Issue Discussion on Long-Term Engineered Cap Performance More Documents & Publications Office of Civilian Radioactive Waste Management Long-Term Grout Performance Sustainable Disposal Cell Covers: Legacy Management Practices, Improvements, and Long-Term Performance

  13. ARM - Campaign Instrument - caps-pmex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govInstrumentscaps-pmex Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign Instrument : Cavity Attenuated Phase Shift Extinction Monitor (CAPS-PMEX) Instrument Categories Aerosols, Airborne Observations Primary Measurements Taken The following measurements are those considered scientifically relevant. Refer to the datastream (netcdf) file headers for the list of all available measurements, including those recorded for diagnostic or quality

  14. Hunting space rocks

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hunting space rocks Hunting space rocks Nina Lanza is studying the solar system by spending six weeks on an ice sheet in Antarctica. The 36-year-old staff scientist at the Los Alamos National Laboratory in New Mexico is on a treasure hunt of sorts. January 15, 2016 Nina Lanza Nina Lanza is part of a team driving across the Trans-Antarctica Mountains on snowmobiles in search of meteorites. (Courtesy of Nina Lanza) "One of the most interesting things from meteorites is every rocky body has a

  15. Engineering rock mass classifications

    SciTech Connect (OSTI)

    Bieniawski, Z.T.

    1989-01-01

    This book is a reference on rock mass classification, consolidating into one handy source information widely scattered through the literature. Includes new, unpublished material and case histories. Presents the fundamental concepts of classification schemes and critically appraises their practical application in industrial projects such as tunneling and mining.

  16. Category:Rock Density | Open Energy Information

    Open Energy Info (EERE)

    Rock Density Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermalpower.jpg Looking for the Rock Density page? For detailed information on Rock Density as...

  17. Microwave assisted hard rock cutting

    DOE Patents [OSTI]

    Lindroth, David P. (Apple Valley, MN); Morrell, Roger J. (Bloomington, MN); Blair, James R. (Inver Grove Heights, MN)

    1991-01-01

    An apparatus for the sequential fracturing and cutting of subsurface volume of hard rock (102) in the strata (101) of a mining environment (100) by subjecting the volume of rock to a beam (25) of microwave energy to fracture the subsurface volume of rock by differential expansion; and , then bringing the cutting edge (52) of a piece of conventional mining machinery (50) into contact with the fractured rock (102).

  18. Corrective Action Plan (CAP) 2008 | Department of Energy

    Energy Savers [EERE]

    Corrective Action Plan (CAP) 2008 Corrective Action Plan (CAP) 2008 The Root Cause Analysis Corrective Action Plan ensures that the root causes identified in the Root Cause Analysis report are addressed with meaningful and lasting solutions in order to improve contract and project management performance. PDF icon Corrective Action Plan (CAP) 2008 More Documents & Publications Layout 1 National Defense Authorization Act for Fiscal Year 2005, Information Request, ROOT CAUSE ANALYSIS AND

  19. Preform spar cap for a wind turbine rotor blade

    DOE Patents [OSTI]

    Livingston, Jamie T. (Simpsonville, SC); Driver, Howard D. (Greer, SC); van Breugel, Sjef (Enschede, NL); Jenkins, Thomas B. (Cantonment, FL); Bakhuis, Jan Willem (Nijverdal, NL); Billen, Andrew J. (Daarlerveen, NL); Riahi, Amir (Pensacola, FL)

    2011-07-12

    A spar cap for a wind turbine rotor blade. The spar cap may include multiple preform components. The multiple preform components may be planar sheets having a swept shape with a first end and a second end. The multiple preform components may be joined by mating the first end of a first preform component to the second end of a next preform component, forming the spar cap.

  20. Session: Hot Dry Rock

    SciTech Connect (OSTI)

    Tennyson, George P. Jr.; Duchane, David V.; Ponden, Raymond F.; Brown, Donald W.

    1992-01-01

    This session at the Geothermal Energy Program Review X: Geothermal Energy and the Utility Market consisted of four presentations: ''Hot Dry Rock - Summary'' by George P. Tennyson, Jr.; ''HDR Opportunities and Challenges Beyond the Long Term Flow Test'' by David V. Duchane; ''Start-Up Operations at the Fenton Hill HDR Pilot Plant'' by Raymond F. Ponden; and ''Update on the Long-Term Flow Testing Program'' by Donald W. Brown.

  1. Optimized capping layers for EUV multilayers

    DOE Patents [OSTI]

    Bajt, Sasa; Folta, James A.; Spiller, Eberhard A.

    2004-08-24

    A new capping multilayer structure for EUV-reflective Mo/Si multilayers consists of two layers: A top layer that protects the multilayer structure from the environment and a bottom layer that acts as a diffusion barrier between the top layer and the structure beneath. One embodiment combines a first layer of Ru with a second layer of B.sub.4 C. Another embodiment combines a first layer of Ru with a second layer of Mo. These embodiments have the additional advantage that the reflectivity is also enhanced. Ru has the best oxidation resistance of all materials investigated so far. B.sub.4 C is an excellent barrier against silicide formation while the silicide layer formed at the Si boundary is well controlled.

  2. Rock Density | Open Energy Information

    Open Energy Info (EERE)

    Density Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Rock Density Details Activities (2) Areas (2) Regions (0) NEPA(0) Exploration Technique...

  3. Rock Sampling | Open Energy Information

    Open Energy Info (EERE)

    resource at depth. These hand samples can be collected using a rock hammer or sledge. Data Access and Acquisition Under a detailed investigation, a systematic sampling procedure...

  4. Apparatus and method for cooling a combustor cap

    DOE Patents [OSTI]

    Zuo, Baifang; Washam, Roy Marshall; Wu, Chunyang

    2014-04-29

    A combustor includes an end cap having a perforated downstream plate and a combustion chamber downstream of the downstream plate. A plenum is in fluid communication with the downstream plate and supplies a cooling medium to the combustion chamber through the perforations in the downstream plate. A method for cooling a combustor includes flowing a cooling medium into a combustor end cap and impinging the cooling medium on a downstream plate in the combustor end cap. The method further includes flowing the cooling medium into a combustion chamber through perforations in the downstream plate.

  5. Wind blade spar cap and method of making

    DOE Patents [OSTI]

    Mohamed, Mansour H. (Raleigh, NC)

    2008-05-27

    A wind blade spar cap for strengthening a wind blade including an integral, unitary three-dimensional woven material having a first end and a second end, corresponding to a root end of the blade and a tip end of the blade, wherein the material tapers in width from the first to the second end while maintaining a constant thickness and decreasing weight therebetween, the cap being capable of being affixed to the blade for providing increased strength with controlled variation in weight from the root end to the tip end based upon the tapered width of the material thereof. The present inventions also include the method of making the wind blade spar cap and a wind blade including the wind blade spar cap.

  6. NessCap Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    NessCap Co Ltd Place: Kyonggi-Do, Korea (Republic) Zip: 449-901 Product: Engages in the research, development, production and sales of the family of capacitor products....

  7. ARM - What About Melting Polar Ice Caps and Sea Levels?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    What About Melting Polar Ice Caps and Sea Levels? Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans What About Melting Polar Ice Caps and Sea Levels? As the northern polar zone warms up, sea ice could melt (very probable) and the sea/ice interface could retreat to the north. This is likely to

  8. Capping blowouts from Iran's eight-year war

    SciTech Connect (OSTI)

    Sayers, B. )

    1991-05-01

    This paper reports on capping blowouts from Iran's eight year war. Fires in three Iranian wells (two oil, one gas), started during 1987 by Iraqi sabotage, finally were extinguished during the last several months of 1990. Burning during the final months of the countries' eight-year war, plus another subsequent peaceful two years, the fires consumed millions of barrels of oil and billions of cubic feet of gas before they were capped. Ironically, bringing the wells under control took relatively little time.

  9. Shotgun cartridge rock breaker

    DOE Patents [OSTI]

    Ruzzi, Peter L. (Eagan, NM); Morrell, Roger J. (Bloomington, MN)

    1995-01-01

    A rock breaker uses shotgun cartridges or other firearm ammunition as the explosive charge at the bottom of a drilled borehole. The breaker includes a heavy steel rod or bar, a gun with a firing chamber for the ammunition which screws onto the rod, a long firing pin running through a central passage in the rod, and a firing trigger mechanism at the external end of the bar which strikes the firing pin to fire the cartridge within the borehole. A tubular sleeve surround the main body of the rod and includes slits the end to allow it to expand. The rod has a conical taper at the internal end against which the end of the sleeve expands when the sleeve is forced along the rod toward the taper by a nut threaded onto the external end of the rod. As the sleeve end expands, it pushes against the borehole and holds the explosive gasses within, and also prevents the breaker from flying out of the borehole. The trigger mechanism includes a hammer with a slot and a hole for accepting a drawbar or drawpin which, when pulled by a long cord, allows the cartridge to be fired from a remote location.

  10. Rock of Ages | Open Energy Information

    Open Energy Info (EERE)

    of Ages Jump to: navigation, search Name Rock of Ages Facility Rock of Ages Sector Wind energy Facility Type Small Scale Wind Facility Status In Service Owner Rock of Ages Energy...

  11. Rim Rock Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    Rim Rock Wind Farm Jump to: navigation, search Name Rim Rock Wind Farm Facility Rim Rock Wind Farm Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service...

  12. Proceedings: In Situ Contaminated Sediment Capping Workshop: Cincinnati, Ohio, May 12-14, 2003

    SciTech Connect (OSTI)

    2004-03-01

    The In Situ Contaminated Sediment Capping Workshop was designed to provide the most current information and bring about consensus in understanding of a technology that offers one of the few options for remediation of contaminated sediments. These electronic proceedings document workshop sessions on various capping issues, such as site assessment; cap suitability, performance, and design; site monitoring; and research and development in capping.

  13. Supercritical Carbon Dioxide / Reservoir Rock Chemical Interactions...

    Open Energy Info (EERE)

    Supercritical Carbon Dioxide Reservoir Rock Chemical Interactions Jump to: navigation, search Geothermal Lab Call Projects for Supercritical Carbon Dioxide Reservoir Rock...

  14. Hydrothermally Deposited Rock | Open Energy Information

    Open Energy Info (EERE)

    at Paleochori, Milos, Greece. http:www.photovolcanica.comVolcanoInfoMilosMilos.html Hydrothermally deposited rock includes rocks and minerals that have precipitated from...

  15. Rock physics at Los Alamos Scientific Laboratory

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    Rock physics refers to the study of static and dynamic chemical and physical properties of rocks and to phenomenological investigations of rocks reacting to man-made forces such as stress waves and fluid injection. A bibliography of rock physics references written by LASL staff members is given. Listing is by surname of first author. (RWR)

  16. Integrated Modeling and Decision-Support System for Water Management in the Puget Sound Basin: Snow Caps to White Caps

    SciTech Connect (OSTI)

    Copping, Andrea E.; Yang, Zhaoqing; Voisin, Nathalie; Richey, Jeff; Wang, Taiping; Taira, Randal Y.; Constans, Michael; Wigmosta, Mark S.; Van Cleve, Frances B.; Tesfa, Teklu K.

    2013-12-31

    Final Report for the EPA-sponsored project Snow Caps to White Caps that provides data products and insight for water resource managers to support their predictions and management actions to address future changes in water resources (fresh and marine) in the Puget Sound basin. This report details the efforts of a team of scientists and engineers from Pacific Northwest National Laboratory (PNNL) and the University of Washington (UW) to examine the movement of water in the Snohomish Basin, within the watershed and the estuary, under present and future conditions, using a set of linked numerical models.

  17. Sampling device with a capped body and detachable handle

    DOE Patents [OSTI]

    Jezek, Gerd-Rainer (Orchard Park, NY)

    2000-01-01

    The apparatus is a sampling device having a pad for sample collection, a body which supports the pad, a detachable handle connected to the body and a cap which encloses and retains the pad and body to protect the integrity of the sample.

  18. Rock Energy Cooperative | Open Energy Information

    Open Energy Info (EERE)

    Wisconsin Phone Number: (608) 752-4550 or (866) 752-4550 Website: www.rock.coop Outage Hotline: (866) 752-4550 Outage Map: www.rock.coopcontentcurrent- References: EIA...

  19. ArchRock Corporation | Open Energy Information

    Open Energy Info (EERE)

    Arch Rock is a systems and software company that builds products and technology for wireless sensor networks. References: ArchRock Corporation1 This article is a stub. You can...

  20. RockPort Capital Partners (California) | Open Energy Information

    Open Energy Info (EERE)

    RockPort Capital Partners (California) Jump to: navigation, search Logo: RockPort Capital Partners (California) Name: RockPort Capital Partners (California) Address: 3000 Sand Hill...

  1. Mars Rover finds changing rocks, surprising scientists

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mars Rover finds changing rocks, surprising scientists Mars Rover finds changing rocks, surprising scientists As NASA's Curiosity rover treks up a three-mile-high mountain on Mars, the rocks are changing. Back on Earth, scientists analyzing the data realized this was something different: It turned out to be the first of the high-silica rocks. December 24, 2015 Mars landscape This color-adjusted composite of images taken by NASA's Curiosity rover in September shows the lower portion of Mount

  2. The cretaceous source rocks in the Zagros Foothills of Iran: An example of a large size intracratonic basin

    SciTech Connect (OSTI)

    Bordenave, M.L. ); Huc, A.Y. )

    1993-02-01

    The Zagros orogenic belt of Iran is one of the world most prolific petroleum producing area. However, most of the oil production is originated from a relatively small area, the 60,000 km[sup 2] wide Dezful Embayment which contains approximately 12% of the proven oil global reserves. The distribution of the oil and gas fields results from the area extent of six identified source rock layers, their thermal history and reservoir, cap rock and trap availability. In this paper, the emphasis is three of the layers of Cretaceous sources rocks. The Garau facies was deposited during the Neocomian to Albian interval over Lurestan, Northeast Khuzestan and extends over the extreme northeast part of Fars, the Kazhdumi source rock which deposited over the Dezful Embayment, and eventually the Senonian Gurpi Formation which has marginal source rock characteristics in limited areas of Khuzestan and Northern Fars. The deposition environment of these source rock layers corresponds to semipermanent depressions, included in an overall shallow water intracratonic basin communicating with the South Tethys Ocean. These depressions became anoxic when climatic oceanographical and geological conditions were adequate, i.e., humid climate, high stand water, influxes of fine grained clastics and the existence of sills separating the depression from the open sea. Distribution maps of these source rock layers resulting from extensive field work and well control are also given. The maturation history of source rocks is reconstructed from a set of isopachs. It was found that the main contributor to the oil reserves is the Kazhdumi source rock which is associated with excellent calcareous reservoirs.

  3. SHIF'ROCK, NEW MEXICO

    Office of Legacy Management (LM)

    SHIF'ROCK, NEW MEXICO Sampled February 2001 DATA PACKAGE CONTENTS This data package includes the following information: Item No. Description of Contents 1. Site Hydrologist S u i ~ ~ n ~ a r y 2. Dafa Package Assessment, which includes the following: a. Field procedures verification checklist b. Confirmation that chain-of-custody was maintained. c. Confirmation that holding time requirements were met. d. Evaluation of the adequacy of the QC sample results. Data Assessn~ent Summary, which

  4. Creating and maintaining a gas cap in tar sands formations

    DOE Patents [OSTI]

    Vinegar, Harold J. (Bellaire, TX); Karanikas, John Michael (Houston, TX); Dinkoruk, Deniz Sumnu (Houston, TX); Wellington, Scott Lee (Bellaire, TX)

    2010-03-16

    Methods for treating a tar sands formation are disclosed herein. Methods for treating a tar sands formation may include providing heat to at least part of a hydrocarbon layer in the formation from one or more heaters located in the formation. Pressure may be allowed to increase in an upper portion of the formation to provide a gas cap in the upper portion. At least some hydrocarbons are produced from a lower portion of the formation.

  5. EA-225 Split Rock Energy LLC | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5 Split Rock Energy LLC EA-225 Split Rock Energy LLC Order authorizing Split Rock Energy LLC to export electric energy to Canada. PDF icon EA-225 Split Rock Energy LLC

  6. Effect of. cap alpha. -ketobutyrate on the metabolism of pyruvate and palmitate in isolated rat hepatocytes

    SciTech Connect (OSTI)

    Brass, E.P.

    1986-05-01

    Alpha-ketobutyrate (..cap alpha..KB), an intermediate in the catabolism of threonine and methionine, is decarboxylated to propionyl-CoA. The authors have reported that propionate (PROP) inhibits oxidative metabolism in rate hepatocytes. Based on these observations, the present study examined the effects of ..cap alpha..KB on pyruvate and palmitate metabolism in hepatocytes isolated from fed rats. Similar to PROP, ..cap alpha..KB (10mM) inhibited palmitate oxidation and this inhibition was diminished when 10mM carnitine (CN) was added (35 +/- 6% inhibition without CN, 22 +/- 8% with CN). ..cap alpha..KB inhibited the conversion of 3-/sup 14/C-pyruvate to glucose and CO/sub 2/. Inhibition of pyruvate metabolism by ..cap alpha..KB was concentration-dependent. At equal concentrations, ..cap alpha..KB inhibited pyruvate metabolism to a greater extent than PROP. Addition of CN partially reversed the effects of PROP on pyruvate metabolism, but not those of ..cap alpha..KB despite the generation of propionylcarnitine when ..cap alpha..KB and CN were included in the incubation. These results demonstrate that accumulation of ..cap alpha..KB can impair normal hepatocyte metabolism. While some of the effects of ..cap alpha..KB can be explained on the basis of propionyl-CoA formation, ..cap alpha..KB has effects on pyruvate metabolism not explainable by this mechanism.

  7. ACTIVE CAPPING TECHNOLOGY - NEW APPROACHES FOR IN SITU REMEDIATION OF CONTAMINATED SEDIMENTS

    SciTech Connect (OSTI)

    Knox, A.; Paller, M.; Roberts, J.

    2012-02-13

    This study evaluated pilot-scale active caps composed of apatite, organoclay, biopolymers, and sand for the remediation of metal-contaminated sediments. The active caps were constructed in Steel Creek, at the Savannah River Site near Aiken, South Carolina. Monitoring was conducted for 12 months. Effectiveness of the caps was based on an evaluation of contaminant bioavailability, resistance to erosion, and impacts on benthic organisms. Active caps lowered metal bioavailability in the sediment during the one-year test period. Biopolymers reduced sediment suspension during cap construction, increased the pool of carbon, and lowered the release of metals. This field validation showed that active caps can effectively treat contaminants by changing their speciation, and that caps can be constructed to include more than one type of amendment to achieve multiple goals.

  8. Hot Dry Rock; Geothermal Energy

    SciTech Connect (OSTI)

    1990-01-01

    The commercial utilization of geothermal energy forms the basis of the largest renewable energy industry in the world. More than 5000 Mw of electrical power are currently in production from approximately 210 plants and 10 000 Mw thermal are used in direct use processes. The majority of these systems are located in the well defined geothermal generally associated with crustal plate boundaries or hot spots. The essential requirements of high subsurface temperature with huge volumes of exploitable fluids, coupled to environmental and market factors, limit the choice of suitable sites significantly. The Hot Dry Rock (HDR) concept at any depth originally offered a dream of unlimited expansion for the geothermal industry by relaxing the location constraints by drilling deep enough to reach adequate temperatures. Now, after 20 years intensive work by international teams and expenditures of more than $250 million, it is vital to review the position of HDR in relation to the established geothermal industry. The HDR resource is merely a body of rock at elevated temperatures with insufficient fluids in place to enable the heat to be extracted without the need for injection wells. All of the major field experiments in HDR have shown that the natural fracture systems form the heat transfer surfaces and that it is these fractures that must be for geothermal systems producing from naturally fractured formations provide a basis for directing the forthcoming but, equally, they require accepting significant location constraints on HDR for the time being. This paper presents a model HDR system designed for commercial operations in the UK and uses production data from hydrothermal systems in Japan and the USA to demonstrate the reservoir performance requirements for viable operations. It is shown that these characteristics are not likely to be achieved in host rocks without stimulation processes. However, the long term goal of artificial geothermal systems developed by systematic engineering procedures at depth may still be attained if high temperature sites with extensive fracturing are developed or exploited. [DJE -2005

  9. Big Bang Day : Physics Rocks

    ScienceCinema (OSTI)

    None

    2011-04-25

    Is particle physics the new rock 'n' roll? The fundamental questions about the nature of the universe that particle physics hopes to answer have attracted the attention of some very high profile and unusual fans. Alan Alda, Ben Miller, Eddie Izzard, Dara O'Briain and John Barrowman all have interests in this branch of physics. Brian Cox - CERN physicist, and former member of 90's band D:Ream, tracks down some very well known celebrity enthusiasts and takes a light-hearted look at why this subject can appeal to all of us.

  10. Enhanced thermal stability of Ag nanorods through capping

    SciTech Connect (OSTI)

    Bachenheimer, Lou; Elliott, Paul; Stagon, Stephen; Huang, Hanchen

    2014-11-24

    Ag nanorods may serve as sensors in the detection of trace amounts of chemical agents, even single molecules, through surface enhanced Raman spectroscopy (SERS). However, thermal coarsening of Ag nanorods near room temperature limits their applications. This letter proposes the use of a thin oxide capping layer to enhance the thermal stability of Ag nanorods beyond 100?°C. Using electron microscopy characterization and SERS tests, the authors show that the proposed method is effective in stabilizing both morphology and sensitivity of Ag nanorods. The results of this work extend the applicability of Ag nanorods as chemical sensors to higher temperatures.

  11. Rock Lab Analysis | Open Energy Information

    Open Energy Info (EERE)

    interaction. Can determine detailed information about rock composition and morphology. Density of different lithologic units. Rapid and unambiguous identification of unknown...

  12. Hydrothermally Altered Rock | Open Energy Information

    Open Energy Info (EERE)

    Paleochori cliffs Milos, Greece. http:www.photovolcanica.comVolcanoInfoMilosMilos.html Hydrothermal alteration refers to rocks that have been altered from their original...

  13. Winner: Hot Rocks | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Winner: Hot Rocks Winner: Hot Rocks December 31, 2008 - 2:07pm Addthis Four kilometers down below the orange earth of Australia's Cooper Basin lies some of the hottest nonvolcanic rock in the world-rock that the geothermal industry had never seriously considered using to make electricity. But next month Geodynamics, an eight-year-old company based in Milton, Queensland, will prove otherwise when it turns on its 1-megawatt pilot plant here. The company has done more to harness this unconventional

  14. Laser rods with undoped, flanged end-caps for end-pumped laser applications

    DOE Patents [OSTI]

    Meissner, Helmuth E. (Pleasanton, CA); Beach, Raymond J. (Livermore, CA); Bibeau, Camille (Danville, CA); Sutton, Steven B. (Manteca, CA); Mitchell, Scott (Tracy, CA); Bass, Isaac (Castro Valley, CA); Honea, Eric (Sunol, CA)

    1999-01-01

    A method and apparatus for achieving improved performance in a solid state laser is provided. A flanged, at least partially undoped end-cap is attached to at least one end of a laserable medium. Preferably flanged, undoped end-caps are attached to both ends of the laserable medium. Due to the low scatter requirements for the interface between the end-caps and the laser rod, a non-adhesive method of bonding is utilized such as optical contacting combined with a subsequent heat treatment of the optically contacted composite. The non-bonded end surfaces of the flanged end-caps are coated with laser cavity coatings appropriate for the lasing wavelength of the laser rod. A cooling jacket, sealably coupled to the flanged end-caps, surrounds the entire length of the laserable medium. Radiation from a pump source is focussed by a lens duct and passed through at least one flanged end-cap into the laser rod.

  15. Rock-Water Interactions In Hot Dry Rock Geothermal Systems- Field...

    Open Energy Info (EERE)

    Rock-Water Interactions In Hot Dry Rock Geothermal Systems- Field Investigations Of In Situ Geochemical Behavior Jump to: navigation, search OpenEI Reference LibraryAdd to library...

  16. DNA 3' pp 5' G de-capping activity of aprataxin: effect of cap nucleoside analogs and structural basis for guanosine recognition

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chauleau, Mathieu; Jacewicz, Agata; Shuman, Stewart

    2015-05-24

    DNA3' pp 5'G caps synthesized by the 3'-PO4/5'-OH ligase RtcB have a strong impact on enzymatic reactions at DNA 3'-OH ends. Aprataxin, an enzyme that repairs A5'pp5'DNA ends formed during abortive ligation by classic 3'-OH/5'-PO4 ligases, is also a DNA 3' de-capping enzyme, converting DNAppG to DNA3'p and GMP. By taking advantage of RtcB's ability to utilize certain GTP analogs to synthesize DNAppN caps, we show that aprataxin hydrolyzes inosine and 6-O-methylguanosine caps, but is not adept at removing a deoxyguanosine cap. We report a 1.5 Å crystal structure of aprataxin in a complex with GMP, which reveals that: (i)more » GMP binds at the same position and in the same anti nucleoside conformation as AMP; and (ii) aprataxin makes more extensive nucleobase contacts with guanine than with adenine, via a hydrogen bonding network to the guanine O6, N1, N2 base edge. Alanine mutations of catalytic residues His147 and His149 abolish DNAppG de-capping activity, suggesting that the 3' de-guanylylation and 5' de-adenylylation reactions follow the same pathway of nucleotidyl transfer through a covalent aprataxin-(His147)–NMP intermediate. Alanine mutation of Asp63, which coordinates the guanosine ribose hydroxyls, impairs DNAppG de-capping.« less

  17. POLICY FLASH 2014-12 Executive Compensation Cap | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 Executive Compensation Cap POLICY FLASH 2014-12 Executive Compensation Cap Questions concerning this policy flash should be directed to Carol Jenkins, of the Office of Acquisition and Project Management Policy at 202-287-1827 or at Carol.Jenkins@hq.doe.gov. PDF icon POLICY_FLASH_ExecutiveCompensationCap (2).pdf More Documents & Publications POLICY FLASH 2014-15 Determination of Benchmark Compensation Amount for Certain Executives and Employees POLICY FLASH 2014-15 Determination of

  18. Nuke Watch New Mexico Perspective on MDA G Cap and Cover | Department of

    Energy Savers [EERE]

    Energy Nuke Watch New Mexico Perspective on MDA G Cap and Cover Nuke Watch New Mexico Perspective on MDA G Cap and Cover Topic: Scott Kovac NWNM, Provided Information pertaining to the Proposed Cap and Cover of Material Disposal Area G and NWNMs perspective on it. PDF icon NWNM MDA G - February 12, 2014 More Documents & Publications EA-1464: Final Environmental Assessment NNMCAB Board Minutes: January 2011 Pojoaque EIS-0380: Draft Site-Wide Environmental Impact Statement

  19. Manufactured caverns in carbonate rock

    DOE Patents [OSTI]

    Bruce, David A.; Falta, Ronald W.; Castle, James W.; Murdoch, Lawrence C.

    2007-01-02

    Disclosed is a process for manufacturing underground caverns suitable in one embodiment for storage of large volumes of gaseous or liquid materials. The method is an acid dissolution process that can be utilized to form caverns in carbonate rock formations. The caverns can be used to store large quantities of materials near transportation facilities or destination markets. The caverns can be used for storage of materials including fossil fuels, such as natural gas, refined products formed from fossil fuels, or waste materials, such as hazardous waste materials. The caverns can also be utilized for applications involving human access such as recreation or research. The method can also be utilized to form calcium chloride as a by-product of the cavern formation process.

  20. Application of evolved gas analysis to cold-cap reactions of...

    Office of Scientific and Technical Information (OSTI)

    feeds for nuclear waste vitrification Citation Details In-Document Search Title: Application of evolved gas analysis to cold-cap reactions of melter feeds for nuclear waste ...

  1. FY 2014 Q3 RCA CAP Performance Metrics Report 2014-09-05.xlsx

    Office of Environmental Management (EM)

    Third Quarter Overall Root Cause Analysis (RCA)/Corrective Action Plan (CAP) Performance Metrics No. Contract/Project Management Performance Metrics FY 2014 Target FY 2014 Pre- & Post- CAP* Projected Comment 1 Capital Asset Project Success: Complete 90% of capital asset projects at original scope and within 110% of CD-2 TPC. 90% 67% Pre-CAP 75% Post-CAP Based on 3-year rolling period (FY12 to FY14). TPC is Total Project Cost. No. FY 2014 Target FY 2014 3rd Qtr Actual 2 95% 92% 3 95% 90% 4

  2. Standing Rock Sioux Tribe- 2012 Project

    Broader source: Energy.gov [DOE]

    The Standing Rock Sioux Tribe (SRST) will perform a feasibility study and associated tasks over the course of two years on sites within the exterior boundaries of the Standing Rock Sioux Reservation to support the future development ranging from 50 to 150 megawatts (MW) of wind power.

  3. ALTERNATE REDUCTANT COLD CAP EVALUATION FURNACE PHASE II TESTING

    SciTech Connect (OSTI)

    Johnson, F.; Stone, M.; Miller, D.

    2014-09-03

    Savannah River Remediation (SRR) conducted a Systems Engineering Evaluation (SEE) to determine the optimum alternate reductant flowsheet for the Defense Waste Processing Facility (DWPF). Specifically, two proposed flowsheets (nitric–formic–glycolic and nitric–formic–sugar) were evaluated based upon results from preliminary testing. Comparison of the two flowsheets among evaluation criteria indicated a preference towards the nitric–formic–glycolic flowsheet. Further research and development of this flowsheet eliminated the formic acid, and as a result, the nitric–glycolic flowsheet was recommended for further testing. Based on the development of a roadmap for the nitric–glycolic acid flowsheet, Waste Solidification Engineering (WS-E) issued a Technical Task Request (TTR) to address flammability issues that may impact the implementation of this flowsheet. Melter testing was requested in order to define the DWPF flammability envelope for the nitric-glycolic acid flowsheet. The Savannah River National Laboratory (SRNL) Cold Cap Evaluation Furnace (CEF), a 1/12th scale DWPF melter, was selected by the SRR Alternate Reductant project team as the melter platform for this testing. The overall scope was divided into the following sub-tasks as discussed in the Task Technical and Quality Assurance Plan (TTQAP): ? Phase I - A nitric–formic acid flowsheet melter test (unbubbled) to baseline the CEF cold cap and vapor space data to the benchmark melter flammability models; ? Phase II - A nitric–glycolic acid flowsheet melter test (unbubbled and bubbled) to: o Define new cold cap reactions and global kinetic parameters in support of the melter flammability model development; o Quantify off-gas surging potential of the feed; o Characterize off-gas condensate for complete organic and inorganic carbon species. After charging the CEF with cullet from Phase I CEF testing, the melter was slurry-fed with glycolic flowsheet based SB6-Frit 418 melter feed at 36% waste loading and was operated continuously for 25 days. Process data was collected throughout testing and included melter operation parameters and off-gas chemistry. In order to generate off-gas data in support of the flammability model development for the nitric-glycolic flowsheet, vapor space steady state testing in the range of ~300-750°C was conducted under the following conditions, (i) 100% (nominal and excess antifoam levels) and 125% stoichiometry feed and (ii) with and without argon bubbling. Adjustments to feed rate, heater outputs and purge air flow were necessary in order to achieve vapor space temperatures in this range. Surge testing was also completed under nominal conditions for four days with argon bubbling and one day without argon bubbling.

  4. ALTERNATE REDUCTANT COLD CAP EVALUATION FURNACE PHASE I TESTING

    SciTech Connect (OSTI)

    Johnson, F.; Miller, D.; Zamecnik, J.; Lambert, D.

    2014-04-22

    Savannah River Remediation (SRR) conducted a Systems Engineering Evaluation (SEE) to determine the optimum alternate reductant flowsheet for the Defense Waste Processing Facility (DWPF). Specifically, two proposed flowsheets (nitric–formic–glycolic and nitric–formic–sugar) were evaluated based upon results from preliminary testing. Comparison of the two flowsheets among evaluation criteria indicated a preference towards the nitric–formic–glycolic flowsheet. Further evaluation of this flowsheet eliminated the formic acid1, and as a result, the nitric–glycolic flowsheet was recommended for further testing. Based on the development of a roadmap for the nitric–glycolic acid flowsheet, Waste Solidification Engineering (WS-E) issued a Technical Task Request (TTR) to address flammability issues that may impact the implementation of this flowsheet. Melter testing was requested in order to define the DWPF flammability envelope for the nitric glycolic acid flowsheet. The Savannah River National Laboratory (SRNL) Cold Cap Evaluation Furnace (CEF), a 1/12th scale DWPF melter, was selected by the SRR Alternate Reductant project team as the melter platform for this testing. The overall scope was divided into the following sub-tasks as discussed in the Task Technical and Quality Assurance Plan (TTQAP): ? Phase I - A nitric–formic acid flowsheet melter test (unbubbled) to baseline the Cold Cap Evaluation Furnace (CEF) cold cap and vapor space data to the benchmark melter flammability models ? Phase II - A nitric–glycolic acid flowsheet melter test (unbubbled and bubbled) to: o Define new cold cap reactions and global kinetic parameters for the melter flammability models o Quantify off-gas surging potential of the feed o Characterize off-gas condensate for complete organic and inorganic carbon species Prior to startup, a number of improvements and modifications were made to the CEF, including addition of cameras, vessel support temperature measurement, and a heating element near the pour tube. After charging the CEF with cullet from a previous Sludge Batch 6 (SB6) run, the melter was slurry-fed with SB6-Frit 418 melter feed at 36% waste loading and was operated continuously for 6 days. Process data was collected throughout testing and included melter operation variables and off-gas chemistry. In order to satisfy the objective of Phase I testing, vapor space steady testing in the range of ~300°C-700°C was conducted without argon bubbling to baseline the melter data to the existing DWPF melter flammability model. Adjustments to heater outputs, air flows and feed rate were necessary in order to achieve the vapor space temperatures in this range. The results of the Phase I testing demonstrated that the CEF is capable of operating under the low vapor space temperatures A melter pressure of -5 inches of water was not sustained throughout the run, but the melter did remain slightly negative even with the maximum air flows required for the lowest temperature conditions were used. The auxiliary pour tube heater improved the pouring behavior at all test conditions, including reduced feed rates required for the low vapor space testing. Argon bubbling can be used to promote mixing and increase feed rate at multiple conditions. Improvements due to bubbling have been determined previously; however, the addition of the cameras to the CEF allows for visual observation during a range of bubbling configurations. The off-gas analysis system proved to be robust and capable of operating for long durations. The total operational hours on the melter vessel are approximately 385 hours. Dimensional measurements taken prior to Phase I testing and support block temperatures recorded during Phase I testing are available if an extension of service life beyond 1250 hours is desired in the future.

  5. The bumpy road to federal CO{sub 2} caps

    SciTech Connect (OSTI)

    Gannett, C.; Adamson, D.

    2007-07-15

    In January and February 2007 members of the US Congress introduced a number of carbon capture and trade bills that compete with each other to impose the most stringent standards possible. Soon after, the Speaker of the House, Nancy Pelosi, called for consideration of a bill by the full House by the summer. Two issues have been resolved so far: any greenhouse gas reduction program almost certainly will be mandatory, and it appears likely that regulation of the electric power sector's CO{sub 2} emissions will be via a cap and trade system. Many other issues remain. Eight of these are discussed in the article. They include: where in the energy supply chain should greenhouse gas emissions be regulated? and, How should the burden of greenhouse gas reduction be shared with the electricity industry?

  6. Category:Rock Lab Analysis | Open Energy Information

    Open Energy Info (EERE)

    Rock O Over Core Stress P Paleomagnetic Measurements Petrography Analysis R Rock Density Rock Lab Analysis X X-Ray Diffraction (XRD) X-Ray Fluorescence (XRF) Retrieved from...

  7. CO{sub 2} Cap-and-Trade: should industry speak up or sign on?

    SciTech Connect (OSTI)

    Winters, Tobey

    2008-05-15

    Should the energy community support cap-and-trade and work for a common sense method of regulation? If cap-and-trade can be expected to be a major policy blunder, would the wiser course be to support a carbon tax rather than become enablers to a failure that later may be laid at the door of the energy community? (author)

  8. Probable new type of reaction mechanism: Double. cap alpha. direct transfer process

    SciTech Connect (OSTI)

    Xu Shu-wei; Wu Guo-hua; Miao Rong-zhi; Han Fei

    1983-10-01

    It is assumed that /sup 8/Be consists of two ..cap alpha.. particles which are close to each other in configuration space. A spectroscopic density of /sup 8/Be cluster in the residue nuclei is then obtained, which is proportional to the square of the preformation probability of ..cap alpha.. particle at nuclear surface. Using the improved method of parametrization of EFR-DWBA overlap integral,/sup 1//sup en-dash//sup 2/ we calculate the double differential energy spectra and angular distributions of ..cap alpha.. particles for the reactions /sup 209/Bi (/sup 12/C, ..cap alpha..) /sup 217/Fr and extract the preformation probability of ..cap alpha.. particle at the surface of /sup 217/Fr nuclei from fitting the experimental data. The agreement within the range of calculation error between the preformation probabilities extracted from transfer reactions and ..cap alpha.. decay suggests that the reaction /sup 209/Bi(/sup 12/C, ..cap alpha..) /sup 217/Fr may be explained as a double ..cap alpha.. direct transfer process.

  9. Effect of Feeding Rate on the Cold Cap Configuration in a Laboratory-Scale Melter - 13362

    SciTech Connect (OSTI)

    Dixon, Derek R.; Schweiger, Michael J.; Hrma, Pavel; Division of Advanced Nuclear Engineering, Pohang University of Science and Technology, Pohang

    2013-07-01

    High-level-waste melter feed is converted into glass in a joule-heated melter, where it forms a floating layer of reacting feed, called the cold cap. After the glass-forming phase becomes connected, evolving gases produce bubbles that form a foam layer under the feed. The bubbles coalesce into cavities, from which most of the gases are released around the edges of the cold cap while gases also escape through small shafts in the reacting feed. The foam layer insulates the cold cap from the heat transferred from the molten glass below. The cold cap behavior was investigated in a laboratory-scale assembly with a fused silica crucible. A high-alumina waste simulant was fed into the crucible and the feed charging rate was varied from 3 to 7 mL min{sup -1}. After a fixed amount of time (35 min), feed charging was stopped and the crucible was removed from the furnace and quenched on a copper block to preserve the structure of the cold cap during cooling. During the rapid quenching, thermal cracking of the glass and cold cap allowed it to be broken up into sections for analysis. The effect of the charging rate on the height, area and volume of the cold cap was determined. The size of the bubbles collected in the foam layer under the feed increased as the cold cap expanded and the relationship between these bubbles and temperature will be determined for input into a mathematical model. (authors)

  10. Incorporating Cold Cap Behavior in a Joule-heated Waste Glass Melter Model

    SciTech Connect (OSTI)

    Varija Agarwal; Donna Post Guillen

    2013-08-01

    In this paper, an overview of Joule-heated waste glass melters used in the vitrification of high level waste (HLW) is presented, with a focus on the cold cap region. This region, in which feed-to-glass conversion reactions occur, is critical in determining the melting properties of any given glass melter. An existing 1D computer model of the cold cap, implemented in MATLAB, is described in detail. This model is a standalone model that calculates cold cap properties based on boundary conditions at the top and bottom of the cold cap. Efforts to couple this cold cap model with a 3D STAR-CCM+ model of a Joule-heated melter are then described. The coupling is being implemented in ModelCenter, a software integration tool. The ultimate goal of this model is to guide the specification of melter parameters that optimize glass quality and production rate.

  11. (p,. cap alpha. ) reactions on 1p, 2s-1d shell nuclei

    SciTech Connect (OSTI)

    Pellegrini, F.; Trivisonno, D.; Avon, S.; Bianchin, R.; Rui, R.

    1983-07-01

    The /sup 12/C(p,..cap alpha..)/sup 9/B and /sup 32/S(p,..cap alpha..)/sup 29/P reactions have been studied at incident energies of 42.77 and 41.9 MeV, respectively. The experimental (p,..cap alpha..) relative cross sections are well reproduced by distorted wave direct pickup calculations with a semimicroscopic form factor and current shell model wave functions. A comparison between (p,..cap alpha..) and (/sup 3/He,d) spectra on 1p and 2s-1d shell nuclei, leading to the same final nucleus, shows a clear evidence of a dominant pickup process over the knockout mechanism in the dynamics of the (p,..cap alpha..) reaction.

  12. Rock Sampling At Yellowstone Region (Hellman & Ramsey, 2004)...

    Open Energy Info (EERE)

    Rock Sampling At Yellowstone Region (Hellman & Ramsey, 2004) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Rock Sampling At Yellowstone Region...

  13. Rock Sampling At Jemez Mountain Area (Eichelberger & Koch, 1979...

    Open Energy Info (EERE)

    Rock Sampling At Jemez Mountain Area (Eichelberger & Koch, 1979) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Rock Sampling At Jemez Mountain...

  14. Regional Geology: GIS Database for Alternative Host Rocks and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Regional Geology: GIS Database for Alternative Host Rocks and Potential Siting Guidelines Regional Geology: GIS Database for Alternative Host Rocks and Potential Siting Guidelines ...

  15. Rock Physics of Geologic Carbon Sequestration/Storage Dvorkin...

    Office of Scientific and Technical Information (OSTI)

    Rock Physics of Geologic Carbon SequestrationStorage Dvorkin, Jack; Mavko, Gary 54 ENVIRONMENTAL SCIENCES; 58 GEOSCIENCES This report covers the results of developing the rock...

  16. Rock the Watt: An Energy Conservation Campaign at Pacific Northwest...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Rock the Watt: An Energy Conservation Campaign at Pacific Northwest National Lab Rock the Watt: An Energy Conservation Campaign at Pacific Northwest National Lab Case study ...

  17. Fundamental Research on Percussion Drilling: Improved rock mechanics

    Office of Scientific and Technical Information (OSTI)

    full-scale laboratory investigations Michael S. Bruno 58 GEOSCIENCES; 02 PETROLEUM; 03 NATURAL GAS; ROCK DRILLING; PRESSURE DEPENDENCE; ROCK MECHANICS; ROTARY DRILLING; WELL...

  18. Rock Physics of Geologic Carbon Sequestration/Storage (Technical...

    Office of Scientific and Technical Information (OSTI)

    Rock Physics of Geologic Carbon SequestrationStorage Citation Details In-Document Search Title: Rock Physics of Geologic Carbon SequestrationStorage This report covers the ...

  19. Rock Physics of Geologic Carbon Sequestration/Storage (Technical...

    Office of Scientific and Technical Information (OSTI)

    Rock Physics of Geologic Carbon SequestrationStorage Citation Details In-Document Search Title: Rock Physics of Geologic Carbon SequestrationStorage You are accessing a ...

  20. EGS rock reactions with Supercritical CO2 saturated with water...

    Office of Scientific and Technical Information (OSTI)

    Conference: EGS rock reactions with Supercritical CO2 saturated with water and water saturated with Supercritical CO2 Citation Details In-Document Search Title: EGS rock reactions ...

  1. Rock County, Wisconsin: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    in Rock County, Wisconsin CDH Energy EcoEnergy Places in Rock County, Wisconsin Avon, Wisconsin Beloit, Wisconsin Bradford, Wisconsin Brodhead, Wisconsin Center, Wisconsin...

  2. RockPort Capital Partners (Massachusetts) | Open Energy Information

    Open Energy Info (EERE)

    RockPort Capital Partners (Massachusetts) Name: RockPort Capital Partners (Massachusetts) Address: 160 Federal Street, 18th Floor Place: Boston, Massachusetts Zip: 02110 Region:...

  3. Mars Rover finds changing rocks, surprising scientists

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    It turned out to be the first of the high-silica rocks. December 24, 2015 Mars landscape This color-adjusted composite of images taken by NASA's Curiosity rover in September...

  4. First Rocks from Outside the Solar System

    SciTech Connect (OSTI)

    Westphal, Andrew

    2014-10-17

    Andrew Westphal presents his findings in examining the first rocks from outside the solar system at our '8 Big Ideas' Science at the Theater event on October 8th, 2014, in Oakland, California.

  5. Standing Rock Sioux Tribe- 2011 Project

    Broader source: Energy.gov [DOE]

    The Standing Rock Sioux Tribe's (SRST) cultural identity demands that tribal development occur in a sustainable manner and in a manner protective of the tribe's natural resources to preserve them for following generations.

  6. Rock mechanics design in mining and tunneling

    SciTech Connect (OSTI)

    Bieniawski, Z.T.

    1984-01-01

    This book introduces the design process as applied to rock mechanics aspects of underground mining and tunneling. Topics covered include a historical perspective, the design process in engineering, empirical methods of design, observational methods of design, and guided design.

  7. Standing Rock Sioux Tribe- 1995 Project

    Broader source: Energy.gov [DOE]

    The primary objective of this study is to provide the Standing Rock Sioux Nation with a strategic overview of the electric energy issues and opportunities they will be facing beginning in the year 2001.

  8. DNA 3' pp 5' G de-capping activity of aprataxin: effect of cap nucleoside analogs and structural basis for guanosine recognition

    SciTech Connect (OSTI)

    Chauleau, Mathieu; Jacewicz, Agata; Shuman, Stewart

    2015-05-24

    DNA3' pp 5'G caps synthesized by the 3'-PO4/5'-OH ligase RtcB have a strong impact on enzymatic reactions at DNA 3'-OH ends. Aprataxin, an enzyme that repairs A5'pp5'DNA ends formed during abortive ligation by classic 3'-OH/5'-PO4 ligases, is also a DNA 3' de-capping enzyme, converting DNAppG to DNA3'p and GMP. By taking advantage of RtcB's ability to utilize certain GTP analogs to synthesize DNAppN caps, we show that aprataxin hydrolyzes inosine and 6-O-methylguanosine caps, but is not adept at removing a deoxyguanosine cap. We report a 1.5 Å crystal structure of aprataxin in a complex with GMP, which reveals that: (i) GMP binds at the same position and in the same anti nucleoside conformation as AMP; and (ii) aprataxin makes more extensive nucleobase contacts with guanine than with adenine, via a hydrogen bonding network to the guanine O6, N1, N2 base edge. Alanine mutations of catalytic residues His147 and His149 abolish DNAppG de-capping activity, suggesting that the 3' de-guanylylation and 5' de-adenylylation reactions follow the same pathway of nucleotidyl transfer through a covalent aprataxin-(His147)–NMP intermediate. Alanine mutation of Asp63, which coordinates the guanosine ribose hydroxyls, impairs DNAppG de-capping.

  9. Uranium mineralization in fluorine-enriched volcanic rocks

    SciTech Connect (OSTI)

    Burt, D.M.; Sheridan, M.F.; Bikun, J.; Christiansen, E.; Correa, B.; Murphy, B.; Self, S.

    1980-09-01

    Several uranium and other lithophile element deposits are located within or adjacent to small middle to late Cenozoic, fluorine-rich rhyolitic dome complexes. Examples studied include Spor Mountain, Utah (Be-U-F), the Honeycomb Hills, Utah (Be-U), the Wah Wah Mountains, Utah (U-F), and the Black Range-Sierra Cuchillo, New Mexico (Sn-Be-W-F). The formation of these and similar deposits begins with the emplacement of a rhyolitic magma, enriched in lithophile metals and complexing fluorine, that rises to a shallow crustal level, where its roof zone may become further enriched in volatiles and the ore elements. During initial explosive volcanic activity, aprons of lithicrich tuffs are erupted around the vents. These early pyroclastic deposits commonly host the mineralization, due to their initial enrichment in the lithophile elements, their permeability, and the reactivity of their foreign lithic inclusions (particularly carbonate rocks). The pyroclastics are capped and preserved by thick topaz rhyolite domes and flows that can serve as a source of heat and of additional quantities of ore elements. Devitrification, vapor-phase crystallization, or fumarolic alteration may free the ore elements from the glassy matrix and place them in a form readily leached by percolating meteoric waters. Heat from the rhyolitic sheets drives such waters through the system, generally into and up the vents and out through the early tuffs. Secondary alteration zones (K-feldspar, sericite, silica, clays, fluorite, carbonate, and zeolites) and economic mineral concentrations may form in response to this low temperature (less than 200 C) circulation. After cooling, meteoric water continues to migrate through the system, modifying the distribution and concentration of the ore elements (especially uranium).

  10. 488-4D ASH LANDFILL CLOSURE CAP HELP MODELING

    SciTech Connect (OSTI)

    Phifer, M.

    2014-11-17

    At the request of Area Completion Projects (ACP) in support of the 488-4D Landfill closure, the Savannah River National Laboratory (SRNL) has performed Hydrologic Evaluation of Landfill Performance (HELP) modeling of the planned 488-4D Ash Landfill closure cap to ensure that the South Carolina Department of Health and Environmental Control (SCDHEC) limit of no more than 12 inches of head on top of the barrier layer (saturated hydraulic conductivity of no more than 1.0E-05 cm/s) in association with a 25-year, 24-hour storm event is not projected to be exceeded. Based upon Weber 1998 a 25-year, 24-hour storm event at the Savannah River Site (SRS) is 6.1 inches. The results of the HELP modeling indicate that the greatest peak daily head on top of the barrier layer (i.e. geosynthetic clay liner (GCL) or high density polyethylene (HDPE) geomembrane) for any of the runs made was 0.079 inches associated with a peak daily precipitation of 6.16 inches. This is well below the SCDHEC limit of 12 inches.

  11. MC4523 Sealed Cap: Component & characteristics development report

    SciTech Connect (OSTI)

    Begeal, D.R.

    1997-03-01

    The MC4523 Sealed Cap is a WW42C1 Percussion Primer that is pressed into a steel cylinder. Hermaticity of the input end is then provided by welding a thin steel closure disk on the input end of the MC4523. Thus, the user is provided with a component that is prequalified in terms of ignition sensitivity and hermeticity. The first customer is the Thermal Battery Department (1522). The MC4523 will be used on the MC2736A Thermal Battery which in turn will be used on the W78 JTA. Attachment of the MC4523 to the battery is with a laser weld. Combined test results of four production lots at a commercial supplier (PPI, TMS, WR1, and WR2) show an all-fire ignition sensitivity (.999 @ 50%) of approximately 60 millijoules of mechanical energy with a 2.2 gram firing pin. The firing pin had an impact tip with a radius of 0.020 inch. This firing pin is like that to be used in the W78 JTA application. Approximately 112 millijoules of mechanical energy will be supplied in the application, thus the design margin is more than adequate.

  12. Slick Rock Archived Soil & Groundwater Master Reports | Department of

    Office of Environmental Management (EM)

    Energy Slick Rock Archived Soil & Groundwater Master Reports Slick Rock Archived Soil & Groundwater Master Reports Slick Rock Archived Soil & Groundwater Master Reports PDF icon Slick Rock - Old North Continent PDF icon Slick Rock - Union Carbide More Documents & Publications South Valley Archived Soil & Groundwater Master Reports Weldon Spring Site Archived Soil & Groundwater Master Reports Tuba City Archived Soil & Groundwater Master Reports

  13. Attempt to extract the preformation probability of. cap alpha. cluster at the surface of heavy nuclei by means of. cap alpha. -transfer reactions leading to the continuum states

    SciTech Connect (OSTI)

    Xu Shu-wei; Wu Guo-hua; Miao Rong-zhi; Han Fei

    1983-07-01

    The method of parametrization of an EFR-DWBA overlap integral developed by T. Udagawa and T. Tamura et al./sup 1/ is improved. Using the improved method we have fitted the experimental double differential energy spectrum of the /sup 8/Be cluster coming from the reaction /sup 208/Pb(/sup 12/C, /sup 8/Be) /sup 212/Po leading to the continuum states and extracted the preformation probability of the ..cap alpha.. cluster at the surface of the /sup 212/Po nucleus. Within the range of calculation error, the result is in agreement with that extracted from fitting the experimental data of ..cap alpha.. decay.

  14. Cold cap subsidence for in situ vitrification and electrodes therefor

    DOE Patents [OSTI]

    Buelt, James L. (Richland, WA); Carter, John G. (Richland, WA); Eschbach, Eugene A. (Richland, WA); FitzPatrick, Vincent F. (Richland, WA); Koehmstedt, Paul L. (Richland, WA); Morgan, William C. (Richland, WA); Oma, Kenton H. (Richland, WA); Timmerman, Craig L. (Richland, WA)

    1992-01-01

    An electrode for use in in situ vitrification of soil comprises a molybdenum rod received within a conductive sleeve or collar formed of graphite. Electrodes of this type are placed on either side of a region containing buried waste material and an electric current is passed therebetween for vitrifying the soil between the electrodes. The graphite collar enhances the thermal conductivity of the electrode, bringing heat to the surface, and preventing the formation of a cold cap of material above the ground surface. The annulus between the molybdenum rod electrode and the graphite collar is filled with a conductive ceramic powder of a type that sinters upon the molybdenum rod, protecting the same from oxidation as the graphite material is consumed, or a metal powder which liquifies at operating temperatures. The molybdenum rod in the former case may be coated with an oxidation protectant, e.g. of molybdenum disilicide. As insulative blanket is suitably placed on the surface of the soil during processing to promote subsidence by allowing off-gassing and reducing surface heat loss. In other embodiments, connection to vitrification electrodes is provided below ground level to avoid loss of connection due to electrodes deterioration, or a sacrificial electrode may be employed when operation is started. Outboard electrodes can be utilized to square up the vitrified area. Further, the center of the molybdenum rod can be made hollow and filled with a powdered metal, such as copper, which liquifies at operating temperatures. In one embodiment, the molybdenum rod and the graphite collar are physically joined at the bottom.

  15. Evaluating Renewable Portfolio Standards and Carbon Cap Scenarios in the U.S. Electric Sector

    SciTech Connect (OSTI)

    Bird, L.; Chapman, C.; Logan, J.; Sumner, J.; Short, W.

    2010-05-01

    This report examines the impact of various renewable portfolio standards (RPS) and cap-and-trade policy options on the U.S. electricity sector, focusing mainly on renewable energy generation. The analysis uses the National Renewable Energy Laboratory's Regional Energy Deployment System (ReEDS) model that simulates the least-cost expansion of electricity generation capacity and transmission in the United States to examine the impact of an emissions cap--similar to that proposed in the Waxman-Markey bill (H.R. 2454)--as well as lower and higher cap scenarios. It also examines the effects of combining various RPS targets with the emissions caps. The generation mix, carbon emissions, and electricity price are examined for various policy combinations to simulate the effect of implementing policies simultaneously.

  16. Status of Net Metering: Assessing the Potential to Reach Program Caps

    SciTech Connect (OSTI)

    Heeter, J.; Gelman, R.; Bird, L.

    2014-09-01

    Several states are addressing the issue of net metering program caps, which limit the total amount of net metered generating capacity that can be installed in a state or utility service territory. In this analysis, we examine net metering caps to gain perspective on how long net metering will be available in various jurisdictions under current policies. We also surveyed state practices and experience to understand important policy design considerations.

  17. Cap plasticity models and compactive and dilatant pre-failure deformation

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Conference: Cap plasticity models and compactive and dilatant pre-failure deformation Citation Details In-Document Search Title: Cap plasticity models and compactive and dilatant pre-failure deformation × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit OSTI to utilize additional information

  18. How an mRNA capping enzyme reads distinct RNA polymerase II and Spt5 CTD

    Office of Scientific and Technical Information (OSTI)

    phosphorylation codes (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: How an mRNA capping enzyme reads distinct RNA polymerase II and Spt5 CTD phosphorylation codes Citation Details In-Document Search Title: How an mRNA capping enzyme reads distinct RNA polymerase II and Spt5 CTD phosphorylation codes Authors: Doamekpor, Selom K. ; Sanchez, Ana M. ; Schwer, Beate ; Shuman, Stewart ; Lima, Christopher D. [1] ; MSKCC) [2] + Show Author Affiliations

  19. Application of evolved gas analysis to cold-cap reactions of melter feeds

    Office of Scientific and Technical Information (OSTI)

    for nuclear waste vitrification (Journal Article) | SciTech Connect Application of evolved gas analysis to cold-cap reactions of melter feeds for nuclear waste vitrification Citation Details In-Document Search Title: Application of evolved gas analysis to cold-cap reactions of melter feeds for nuclear waste vitrification In the vitrification of nuclear wastes, the melter feed (a mixture of nuclear waste and glass forming and modifying additives) experiences multiple gas-evolving reactions in

  20. Application of evolved gas analysis to cold-cap reactions of melter feeds

    Office of Scientific and Technical Information (OSTI)

    for nuclear waste vitrification (Technical Report) | SciTech Connect Technical Report: Application of evolved gas analysis to cold-cap reactions of melter feeds for nuclear waste vitrification Citation Details In-Document Search Title: Application of evolved gas analysis to cold-cap reactions of melter feeds for nuclear waste vitrification In the vitrification of nuclear wastes, the melter feed (a mixture of nuclear waste and glass-forming and modifying additives) experiences multiple

  1. Status of Net Metering: Assessing the Potential to Reach Program Caps (Poster)

    SciTech Connect (OSTI)

    Heeter, J.; Bird, L.; Gelman, R.

    2014-10-01

    Several states are addressing the issue of net metering program caps, which limit the total amount of net metered generating capacity that can be installed in a state or utility service territory. In this analysis, we examine net metering caps to gain perspective on how long net metering will be available in various jurisdictions under current policies. We also surveyed state practices and experience to understand important policy design considerations.

  2. Root Cause Analysis (RCA) & Corrective Action Plan (CAP) | Department of

    Energy Savers [EERE]

    Energy Root Cause Analysis (RCA) & Corrective Action Plan (CAP) Root Cause Analysis (RCA) & Corrective Action Plan (CAP) Improving the Department of Energy's project and contract management continues to be one of the Department's management priorities. Excellence in this area helps ensure that DOE's programs and projects meet DOE's strategic objectives, provide value to the American taxpayer, and foster public confidence in DOE's ability to manage its responsibilities. As part of our

  3. Root Cause Analysis (RCA) & Corrective Action Plan (CAP) | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Root Cause Analysis (RCA) & Corrective Action Plan (CAP) Root Cause Analysis (RCA) & Corrective Action Plan (CAP) Improving the Department of Energy's project and contract management continues to be one of the Department's management priorities. Excellence in this area helps ensure that DOE's programs and projects meet DOE's strategic objectives, provide value to the American taxpayer, and foster public confidence in DOE's ability to manage its responsibilities. As part of our

  4. Laser rods with undoped, flanged end-caps for end-pumped laser applications

    DOE Patents [OSTI]

    Meissner, H.E.; Beach, R.J.; Bibeau, C.; Sutton, S.B.; Mitchell, S.; Bass, I.; Honea, E.

    1999-08-10

    A method and apparatus for achieving improved performance in a solid state laser is provided. A flanged, at least partially undoped end-cap is attached to at least one end of a laserable medium. Preferably flanged, undoped end-caps are attached to both ends of the laserable medium. Due to the low scatter requirements for the interface between the end-caps and the laser rod, a non-adhesive method of bonding is utilized such as optical contacting combined with a subsequent heat treatment of the optically contacted composite. The non-bonded end surfaces of the flanged end-caps are coated with laser cavity coatings appropriate for the lasing wavelength of the laser rod. A cooling jacket, sealably coupled to the flanged end-caps, surrounds the entire length of the laserable medium. Radiation from a pump source is focused by a lens duct and passed through at least one flanged end-cap into the laser rod. 14 figs.

  5. The Role of Organic Capping Layers of Platinum Nanoparticles in Catalytic Activity of CO Oxidation

    SciTech Connect (OSTI)

    Park, Jeong Y.; Aliaga, Cesar; Renzas, J. Russell; Lee, Hyunjoo; Somorjai, Gabor A.

    2008-12-17

    We report the catalytic activity of colloid platinum nanoparticles synthesized with different organic capping layers. On the molecular scale, the porous organic layers have open spaces that permit the reactant and product molecules to reach the metal surface. We carried out CO oxidation on several platinum nanoparticle systems capped with various organic molecules to investigate the role of the capping agent on catalytic activity. Platinum colloid nanoparticles with four types of capping layer have been used: TTAB (Tetradecyltrimethylammonium Bromide), HDA (hexadecylamine), HDT (hexadecylthiol), and PVP (poly(vinylpyrrolidone)). The reactivity of the Pt nanoparticles varied by 30%, with higher activity on TTAB coated nanoparticles and lower activity on HDT, while the activation energy remained between 27-28 kcal/mol. In separate experiments, the organic capping layers were partially removed using ultraviolet light-ozone generation techniques, which resulted in increased catalytic activity due to the removal of some of the organic layers. These results indicate that the nature of chemical bonding between organic capping layers and nanoparticle surfaces plays a role in determining the catalytic activity of platinum colloid nanoparticles for carbon monoxide oxidation.

  6. Rock melting tool with annealer section

    DOE Patents [OSTI]

    Bussod, Gilles Y. (Santa Fe, NM); Dick, Aaron J. (Oakland, CA); Cort, George E. (Montrose, CO)

    1998-01-01

    A rock melting penetrator is provided with an afterbody that rapidly cools a molten geological structure formed around the melting tip of the penetrator to the glass transition temperature for the surrounding molten glass-like material. An annealing afterbody then cools the glass slowly from the glass transition temperature through the annealing temperature range to form a solid self-supporting glass casing. This allows thermally induced strains to relax by viscous deformations as the molten glass cools and prevents fracturing of the resulting glass liner. The quality of the glass lining is improved, along with its ability to provide a rigid impermeable casing in unstable rock formations.

  7. Storage capacity in hot dry rock reservoirs

    DOE Patents [OSTI]

    Brown, D.W.

    1997-11-11

    A method is described for extracting thermal energy, in a cyclic manner, from geologic strata which may be termed hot dry rock. A reservoir comprised of hot fractured rock is established and water or other liquid is passed through the reservoir. The water is heated by the hot rock, recovered from the reservoir, cooled by extraction of heat by means of heat exchange apparatus on the surface, and then re-injected into the reservoir to be heated again. Water is added to the reservoir by means of an injection well and recovered from the reservoir by means of a production well. Water is continuously provided to the reservoir and continuously withdrawn from the reservoir at two different flow rates, a base rate and a peak rate. Increasing water flow from the base rate to the peak rate is accomplished by rapidly decreasing backpressure at the outlet of the production well in order to meet periodic needs for amounts of thermal energy greater than a baseload amount, such as to generate additional electric power to meet peak demands. The rate of flow of water provided to the hot dry rock reservoir is maintained at a value effective to prevent depletion of the liquid inventory of the reservoir. 4 figs.

  8. Hot-dry-rock geothermal resource 1980

    SciTech Connect (OSTI)

    Heiken, G.; Goff, F.; Cremer, G.

    1982-04-01

    The work performed on hot dry rock (HDR) geothermal resource evaluation, site characterization, and geophysical exploration techniques is summarized. The work was done by region (Far West, Pacific Northwest, Southwest, Rocky Mountain States, Midcontinent, and Eastern) and limited to the conterminous US.

  9. Transient Non Lin Deformation in Fractured Rock

    Energy Science and Technology Software Center (OSTI)

    1998-10-14

    MATLOC is a nonlinear, transient, two-dimensional (planer and axisymmetric), thermal stress, finite-element code designed to determine the deformation within a fractured rock mass. The mass is modeled as a nonlinear anistropic elastic material which can exhibit stress-dependent bi-linear locking behavior.

  10. Storage capacity in hot dry rock reservoirs

    DOE Patents [OSTI]

    Brown, Donald W. (Los Alamos, NM)

    1997-01-01

    A method of extracting thermal energy, in a cyclic manner, from geologic strata which may be termed hot dry rock. A reservoir comprised of hot fractured rock is established and water or other liquid is passed through the reservoir. The water is heated by the hot rock, recovered from the reservoir, cooled by extraction of heat by means of heat exchange apparatus on the surface, and then re-injected into the reservoir to be heated again. Water is added to the reservoir by means of an injection well and recovered from the reservoir by means of a production well. Water is continuously provided to the reservoir and continuously withdrawn from the reservoir at two different flow rates, a base rate and a peak rate. Increasing water flow from the base rate to the peak rate is accomplished by rapidly decreasing backpressure at the outlet of the production well in order to meet periodic needs for amounts of thermal energy greater than a baseload amount, such as to generate additional electric power to meet peak demands. The rate of flow of water provided to the hot dry rock reservoir is maintained at a value effective to prevent depletion of the liquid

  11. DOE - NNSA/NFO -- News & Views Camp Desert Rock

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Camp Desert Rock Photo - Camp Desert Rock Camp Desert Rock, also known as Desert Atom Camp, Nevada, was home to the U.S. Army's Atomic Maneuver Battalion in the 1950s. More than 2,300 soldiers were trained here in 1955. The 100 semi-permanent buildings and more than 500 tents often were filled to the 6,000 personnel capacity. Desert Rock Airport, with its 7,500 foot runway, was built on the former Camp Desert Rock. At peak operation Camp Desert Rock comprised of 100 semi-permanent buildings,

  12. Category:Little Rock, AR | Open Energy Information

    Open Energy Info (EERE)

    71 KB SVMediumOffice Little Rock AR Entergy Arkansas Inc.png SVMediumOffice Little ... 68 KB SVMidriseApartment Little Rock AR Entergy Arkansas Inc.png SVMidriseApartment Lit......

  13. Hot Dry Rock Geothermal Energy- Important Lessons From Fenton...

    Open Energy Info (EERE)

    navigation, search OpenEI Reference LibraryAdd to library Conference Paper: Hot Dry Rock Geothermal Energy- Important Lessons From Fenton Hill Abstract The concept of Hot Dry Rock...

  14. Photo of the Week: Laser Beats Rock | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Laser Beats Rock Photo of the Week: Laser Beats Rock April 8, 2013 - 5:28pm Addthis On August 5, 2012, the Curiosity rover touched down on the surface of Mars. The ChemCam ...

  15. EIS-0471: Areva Eagle Rock Enrichment Facility in Bonneville...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1: Areva Eagle Rock Enrichment Facility in Bonneville County, ID EIS-0471: Areva Eagle Rock Enrichment Facility in Bonneville County, ID May 20, 2011 delete me old download page ...

  16. Project Reports for Standing Rock Sioux Tribe- 2012 Project

    Broader source: Energy.gov [DOE]

    The Standing Rock Sioux Tribe (SRST) will perform a feasibility study and associated tasks over the course of two years on sites within the exterior boundaries of the Standing Rock Sioux...

  17. Isotopic Analysis- Rock At Coso Geothermal Area (1984) | Open...

    Open Energy Info (EERE)

    Home Exploration Activity: Isotopic Analysis- Rock At Coso Geothermal Area (1984) Exploration Activity Details Location Coso Geothermal Area Exploration Technique...

  18. Slick Rock, Colorado, Processing Sites and Disposal Sites Fact Sheet

    Office of Legacy Management (LM)

    Slick Rock, Colorado, Processing Sites and Disposal Sites This fact sheet provides information about the Uranium Mill Tailings Radiation Control Act of 1978 Title I processing sites and disposal site at Slick Rock, Colorado. These sites are managed by the U.S. Department of Energy Office of Legacy Management. Locations of the Slick Rock, Colorado, Processing and Disposal Sites Site Descriptions and History The Slick Rock processing sites consist of two former uranium- and vanadium-ore processing

  19. MODELING UNDERGROUND STRUCTURE VULNERABILITY IN JOINTED ROCK

    SciTech Connect (OSTI)

    R. SWIFT; D. STEEDMAN

    2001-02-01

    The vulnerability of underground structures and openings in deep jointed rock to ground shock attack is of chief concern to military planning and security. Damage and/or loss of stability to a structure in jointed rock, often manifested as brittle failure and accompanied with block movement, can depend significantly on jointed properties, such as spacing, orientation, strength, and block character. We apply a hybrid Discrete Element Method combined with the Smooth Particle Hydrodynamics approach to simulate the MIGHTY NORTH event, a definitive high-explosive test performed on an aluminum lined cylindrical opening in jointed Salem limestone. Representing limestone with discrete elements having elastic-equivalence and explicit brittle tensile behavior and the liner as an elastic-plastic continuum provides good agreement with the experiment and damage obtained with finite-element simulations. Extending the approach to parameter variations shows damage is substantially altered by differences in joint geometry and liner properties.

  20. NetCAP status report for the end of fiscal year 2010.

    SciTech Connect (OSTI)

    Hamlet, Benjamin Roger; Young, Christopher John

    2010-10-01

    Fiscal year 2010 (FY10) is the second full year of NetCAP development and the first full year devoted largely to new feature development rather than the reimplementation of existing capabilities found in NetSim (Sereno et al., 1990). Major tasks completed this year include: (1) Addition of hydroacoustic simulation; (2) Addition of event Identification simulation; and (3) Initial design and preparation for infrasound simulation. The Network Capability Assessment Program (NetCAP) is a software tool under development at Sandia National Laboratories used for studying the capabilities of nuclear explosion monitoring networks. This report discusses motivation and objectives for the NetCAP project, lists work performed prior to fiscal year 2010 (FY10) and describes FY10 accomplishments in detail.

  1. An inorganic capping strategy for the seeded growth of versatile bimetallic nanostructures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pei, Yuchen; Maligal-Ganesh, Raghu V.; Xiao, Chaoxian; Goh, Tian -Wei; Brashler, Kyle; Gustafson, Jeffrey A.; Huang, Wenyu

    2015-09-11

    Metal nanostructures have attracted great attention in various fields due to their tunable properties through precisely tailored sizes, compositions and structures. Using mesoporous silica (mSiO2) as the inorganic capping agent and encapsulated Pt nanoparticles as the seeds, we developed a robust seeded growth method to prepare uniform bimetallic nanoparticles encapsulated in mesoporous silica shells (PtM@mSiO2, M = Pd, Rh, Ni and Cu). Unexpectedly, we found that the inorganic silica shell is able to accommodate an eight-fold volume increase in the metallic core by reducing its thickness. The bimetallic nanoparticles encapsulated in mesoporous silica shells showed enhanced catalytic properties and thermalmore » stabilities compared with those prepared with organic capping agents. As a result, this inorganic capping strategy could find a broad application in the synthesis of versatile bimetallic nanostructures with exceptional structural control and enhanced catalytic properties.« less

  2. Scientific Visit on Crystalline Rock Repository Development

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Visit on Crystalline Rock Repository Development - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste

  3. motion-of-large-riprap-rocks

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Development of a Computational Approach to Detect Instability and Incipient Motion of Large Riprap Rocks" Presentation at the Transportation Research Board Annual Meeting Washington DC, January 14, 2014 Paper number 14-3035 Cezary Bojanowski Transportation Research and Analysis Computing Center (TRACC), Energy Systems Division Argonne National Laboratory Steven Lottes Transportation Research and Analysis Computing Center (TRACC), Energy Systems Division Argonne National Laboratory Abstract

  4. Cathedral Rock Picnic Area Rehabilitation Environmental Assessment

    National Nuclear Security Administration (NNSA)

    Department of Agriculture Forest Service Intermountain Region (R4) March 2009 Cathedral Rock Picnic Area Rehabilitation Project Environmental Assessment Spring Mountains National Recreation Area Humboldt Toiyabe National Forest Clark County, Nevada For further information, contact: Jane Schumacher, Environmental Coordinator Spring Mountains National Recreation Area 4701 North Torrey Pines Drive Las Vegas, Nevada 89130 Phone: (702) 839-5560 The U.S. Department of Agriculture (USDA) prohibits

  5. Gage for measuring displacements in rock samples

    DOE Patents [OSTI]

    Holcomb, David J. (Albuquerque, NM); McNamee, Michael J. (Albuquerque, NM)

    1986-01-01

    A gage for measuring diametral displacement within a rock sample for use in a rock mechanics laboratory and in the field, comprises a support ring housing a linear variable differential transformer, a mounting screw, and a leaf spring. The mounting screw is adjustable and defines a first point of contact with the rock sample. The leaf spring has opposite ends fixed to the inner periphery of the mounting ring. An intermediate portion of the leaf spring projecting radially inward from the ring is formed with a dimple defining a second point of contact with the sample. The first and second points of contact are diametrically opposed to each other. The LVDT is mounted in the ring with its axis parallel to the line of measurement and its core rod received in the dimple of the leaf spring. Any change in the length of the line between the first and second support points is directly communicated to the LVDT. The leaf spring is rigid to completely support lateral forces so that the LVDT is free of all load for improved precision.

  6. Gage for measuring displacements in rock samples

    DOE Patents [OSTI]

    Holcomb, D.J.; McNamee, M.J.

    1985-07-18

    A gage for measuring diametral displacement within a rock sample for use in a rock mechanics laboratory and in the field, comprises a support ring housing a linear variable differential transformer (LVDT), a mounting screw, and a leaf spring. The mounting screw is adjustable and defines a first point of contact with the rock sample. The leaf spring has opposite ends fixed to the inner periphery of the mounting ring. An intermediate portion of the leaf spring projecting radially inward from the ring is formed with a dimple defining a second point of contact with the sample. The first and second points of contact are diametrically opposed to each other. The LVDT is mounted in the ring with its axis parallel to the line of measurement and its core rod received in the dimple of the leaf spring. Any change in the length of the line between the first and second support points is directly communicated to the LVDT. The leaf spring is rigid to completely support lateral forces so that the LVDT is free of all load for improved precision.

  7. Spencer Hot Springs Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Features: Relict Geothermal Features: Volcanic Age: Host Rock Age: Host Rock Lithology: Cap Rock Age: Cap Rock Lithology: Click "Edit With Form" above to add content Geofluid...

  8. Chocolate Mountains Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Features: Relict Geothermal Features: Volcanic Age: Host Rock Age: Host Rock Lithology: Cap Rock Age: Cap Rock Lithology: Click "Edit With Form" above to add content Geofluid...

  9. Colado Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Features: Relict Geothermal Features: Volcanic Age: Host Rock Age: Host Rock Lithology: Cap Rock Age: Cap Rock Lithology: Click "Edit With Form" above to add content Geofluid...

  10. Lualualei Valley Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Features: Relict Geothermal Features: Volcanic Age: Host Rock Age: Host Rock Lithology: Cap Rock Age: Cap Rock Lithology: Click "Edit With Form" above to add content Geofluid...

  11. Little Valley Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Features: Relict Geothermal Features: Volcanic Age: Host Rock Age: Host Rock Lithology: Cap Rock Age: Cap Rock Lithology: Click "Edit With Form" above to add content Geofluid...

  12. Wedell Hot Spring Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Features: Relict Geothermal Features: Volcanic Age: Host Rock Age: Host Rock Lithology: Cap Rock Age: Cap Rock Lithology: Click "Edit With Form" above to add content Geofluid...

  13. Double Hot Springs Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Features: Relict Geothermal Features: Volcanic Age: Host Rock Age: Host Rock Lithology: Cap Rock Age: Cap Rock Lithology: Click "Edit With Form" above to add content Geofluid...

  14. Alvord Hot Springs Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Features: Relict Geothermal Features: Volcanic Age: Host Rock Age: Host Rock Lithology: Cap Rock Age: Cap Rock Lithology: Click "Edit With Form" above to add content Geofluid...

  15. Bailey Bay Hot Springs Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Features: Relict Geothermal Features: Volcanic Age: Host Rock Age: Host Rock Lithology: Cap Rock Age: Cap Rock Lithology: Click "Edit With Form" above to add content Geofluid...

  16. Dixie Hot Springs Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Features: Relict Geothermal Features: Volcanic Age: Host Rock Age: Host Rock Lithology: Cap Rock Age: Cap Rock Lithology: Click "Edit With Form" above to add content Geofluid...

  17. Honokowai Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Features: Relict Geothermal Features: Volcanic Age: Host Rock Age: Host Rock Lithology: Cap Rock Age: Cap Rock Lithology: Click "Edit With Form" above to add content Geofluid...

  18. Buffalo Valley Hot Springs Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Features: Relict Geothermal Features: Volcanic Age: Host Rock Age: Host Rock Lithology: Cap Rock Age: Cap Rock Lithology: Click "Edit With Form" above to add content Geofluid...

  19. Big Windy Hot Springs Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Features: Relict Geothermal Features: Volcanic Age: Host Rock Age: Host Rock Lithology: Cap Rock Age: Cap Rock Lithology: Click "Edit With Form" above to add content Geofluid...

  20. An oleic acid-capped CdSe quantum-dot sensitized solar cell

    SciTech Connect (OSTI)

    Chen Jing; Song, J. L.; Deng, W. Q.; Sun, X. W.; Jiang, C. Y.; Lei, W.; Huang, J. H.; Liu, R. S.

    2009-04-13

    In this letter, we report an oleic acid (OA)-capped CdSe quantum-dot sensitized solar cell (QDSSC) with an improved performance. The TiO{sub 2}/OA-CdSe photoanode in a two-electrode device exhibited a photon-to-current conversion efficiency of 17.5% at 400 nm. At AM1.5G irradiation with 100 mW/cm{sup 2} light intensity, the QDSSCs based on OA-capped CdSe showed a power conversion efficiency of about 1%. The function of OA was to increase QD loading, extend the absorption range and possibly suppress the surface recombination.

  1. Cementitious building material incorporating end-capped polyethylene glycol as a phase change material

    DOE Patents [OSTI]

    Salyer, Ival O. (Dayton, OH); Griffen, Charles W. (Mason, OH)

    1986-01-01

    A cementitious composition comprising a cementitious material and polyethylene glycol or end-capped polyethylene glycol as a phase change material, said polyethylene glycol and said end-capped polyethylene glycol having a molecular weight greater than about 400 and a heat of fusion greater than about 30 cal/g; the compositions are useful in making pre-formed building materials such as concrete blocks, brick, dry wall and the like or in making poured structures such as walls or floor pads; the glycols can be encapsulated to reduce their tendency to retard set.

  2. A cheap and effective CO{sub 2} cap-and-trade for electricity

    SciTech Connect (OSTI)

    Michel, Steven

    2009-10-15

    Now that debate has shifted from regional toward federal cap-and-trade policy, it's time to reintroduce the idea of using reduction credits rather than allowances to drive emission reductions. A credit system appears to work well to reduce CO{sub 2} emissions with minimal compliance cost - and without windfall, wealth transfer, or market power concerns. It also provides a strong incentive for renewable energy and energy efficiency, and a ready means to harmonize a federal cap-and-trade with state and federal renewable energy portfolio requirements. (author)

  3. The MuCap Experiment (Journal Article) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    The MuCap Experiment Citation Details In-Document Search Title: The MuCap Experiment Muon capture on the proton is sensitive to the weak pseudoscalar form factor, g{sub p}, one of the basic parameters characterizing the nucleon electroweak charged-current interaction. There is a precise theoretical prediction for g{sub p} based on chiral symmetry of QCD, yet the results of past experiments are controversial: they are dependent on a poorly-known, mu-molecular kinetic parameter, and there is no

  4. Design Support of an Above Cap-rock Early Detection Monitoring System using Simulated Leakage Scenarios at the FutureGen2.0 Site

    SciTech Connect (OSTI)

    Williams, Mark D.; USA, Richland Washington; Vermuel, Vince R.; USA, Richland Washington; Oostrom, Mart; USA, Richland Washington; Porse, Sean L.; USA, Richland Washington; Thorne, Paul D.; USA, Richland Washington; Szecsody, Jim E.; USA, Richland Washington; Horner, Jake A.; USA, Richland Washington; Gilmore, Tyler J.; USA, Richland Washington

    2014-12-31

    The FutureGen 2.0 Project will design and build a first-of-its-kind, near-zero emissions coal-fueled power plant with carbon capture and storage (CCS). To assess storage site performance and meet the regulatory requirements of the Class VI Underground Injection Control (UIC) Program for CO2 Geologic Sequestration, the FutureGen 2.0 project will implement a suite of monitoring technologies designed to evaluate CO2 mass balance and detect any unforeseen loss in CO2 containment. The monitoring program will include direct monitoring of the reservoir, and early-leak-detection monitoring directly above the primary confining zone. This preliminary modeling study described here focuses on hypothetical leakage scenarios into the first permeable unit above the primary confining zone (Ironton Sandstone) and is used to support assessment of early-leak detection capabilities. Future updates of the model will be used to assess potential impacts on the lowermost underground source of drinking water (Saint Peter Sandstone) for a range of theoretical leakage scenarios. This preliminary modeling evaluation considers both pressure response and geochemical signals in the overlying Ironton Sandstone. This model is independent of the FutureGen 2.0 reservoir model in that it does not simulate caprock discontinuities, faults, or failure scenarios. Instead this modeling effort is based on theoretical, volumetric-rate based leakage scenarios. The scenarios include leakage of 1% of the total injected CO2 mass, but spread out over different time periods (20, 100, and 500 years) with each case yielding a different mass flux (i.e., smaller mass fluxes for longer duration leakage cases]. A brine leakage scenario using a volumetric leakage similar to the 20 year 1% CO2 case was also considered. A framework for the comparison of the various cases was developed based on the exceedance of selected pressure and geochemical thresholds at different distances from the point of leakage and at different vertical positions within the Ironton Sandstone. These preliminary results, and results from an updated models that incorporate additional site-specific characterization data, support development/refinement of the monitoring system design.

  5. Design Support of an Above Cap-rock Early Detection Monitoring System using Simulated Leakage Scenarios at the FutureGen2.0 Site

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Williams, Mark D.; USA, Richland Washington; Vermuel, Vince R.; USA, Richland Washington; Oostrom, Mart; USA, Richland Washington; Porse, Sean L.; USA, Richland Washington; Thorne, Paul D.; USA, Richland Washington; et al

    2014-12-31

    The FutureGen 2.0 Project will design and build a first-of-its-kind, near-zero emissions coal-fueled power plant with carbon capture and storage (CCS). To assess storage site performance and meet the regulatory requirements of the Class VI Underground Injection Control (UIC) Program for CO2 Geologic Sequestration, the FutureGen 2.0 project will implement a suite of monitoring technologies designed to evaluate CO2 mass balance and detect any unforeseen loss in CO2 containment. The monitoring program will include direct monitoring of the reservoir, and early-leak-detection monitoring directly above the primary confining zone. This preliminary modeling study described here focuses on hypothetical leakage scenarios intomore » the first permeable unit above the primary confining zone (Ironton Sandstone) and is used to support assessment of early-leak detection capabilities. Future updates of the model will be used to assess potential impacts on the lowermost underground source of drinking water (Saint Peter Sandstone) for a range of theoretical leakage scenarios. This preliminary modeling evaluation considers both pressure response and geochemical signals in the overlying Ironton Sandstone. This model is independent of the FutureGen 2.0 reservoir model in that it does not simulate caprock discontinuities, faults, or failure scenarios. Instead this modeling effort is based on theoretical, volumetric-rate based leakage scenarios. The scenarios include leakage of 1% of the total injected CO2 mass, but spread out over different time periods (20, 100, and 500 years) with each case yielding a different mass flux (i.e., smaller mass fluxes for longer duration leakage cases]. A brine leakage scenario using a volumetric leakage similar to the 20 year 1% CO2 case was also considered. A framework for the comparison of the various cases was developed based on the exceedance of selected pressure and geochemical thresholds at different distances from the point of leakage and at different vertical positions within the Ironton Sandstone. These preliminary results, and results from an updated models that incorporate additional site-specific characterization data, support development/refinement of the monitoring system design.« less

  6. Explosive shaped charge penetration into tuff rock

    SciTech Connect (OSTI)

    Vigil, M.G.

    1988-10-01

    Analysis and data for the use of Explosive Shaped Charges (ESC) to generate holes in tuff rock formation is presented. The ESCs evaluated include Conical Shaped Charges (CSC) and Explosive Formed Projectiles (EFP). The CSCs vary in size from 0.158 to 9.1 inches inside cone diameter. The EFPs were 5.0 inches in diameter. Data for projectile impact angles of 30 and 90 degrees are presented. Analytically predicted depth of penetration data generally compared favorably with experimental data. Predicted depth of penetration versus ESC standoff data and hole profile dimensions in tuff are also presented. 24 refs., 45 figs., 6 tabs.

  7. Hot dry rock venture risks investigation:

    SciTech Connect (OSTI)

    Not Available

    1988-01-01

    This study assesses a promising resource in central Utah as the potential site of a future commerical hot dry rock (HDR) facility for generating electricity. The results indicate that, if the HDR reservoir productivity equals expectations based on preliminary results from research projects to date, a 50 MWe HDR power facility at Roosevelt Hot Springs could generate power at cost competitive with coal-fired plants. However, it is imperative that the assumed productivity be demonstrated before funds are committed for a commercial facility. 72 refs., 39 figs., 38 tabs.

  8. Double capping of molecular beam epitaxy grown InAs/InP quantum dots studied by cross-sectional scanning tunneling microscopy

    SciTech Connect (OSTI)

    Ulloa, J. M.; Koenraad, P. M.; Gapihan, E.; Letoublon, A.; Bertru, N.

    2007-08-13

    Cross-sectional scanning tunneling microscopy was used to study at the atomic scale the double capping process of self-assembled InAs/InP quantum dots (QDs) grown by molecular beam epitaxy on a (311)B substrate. The thickness of the first capping layer is found to play a mayor role in determining the final results of the process. For first capping layers up to 3.5 nm, the height of the QDs correspond to the thickness of the first capping layer. Nevertheless, for thicknesses higher than 3.5 nm, a reduction in the dot height compared to the thickness of the first capping layer is observed. These results are interpreted in terms of a transition from a double capping to a classical capping process when the first capping layer is thick enough to completely cover the dots.

  9. United States National Waste Terminal Storage argillaceous rock studies

    SciTech Connect (OSTI)

    Brunton, G.D.

    1981-01-01

    The past and present argillaceous rock studies for the US National Waste Terminal Storage Program consist of: (1) evaluation of the geological characteristics of several widespread argillaceous formations in the United States; (2) laboratory studies of the physical and chemical properties of selected argillaceous rock samples; and (3) two full-scale in situ surface heater experiments that simulate the emplacement of heat-generating radioactive waste in argillaceous rock.

  10. Picture of the Week: Bismuth and tin on the rocks

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    31 Bismuth and tin on the rocks Scientists at Los Alamos National Laboratory are using state-of-the-art experimental techniques to see and understand how microstructures evolve during materials processing. February 15, 2016 Bismuth and tin on the rocks Scientists at Los Alamos National Laboratory are using state-of-the-art experimental techniques to see and understand how microstructures evolve during materials processing. Bismuth and tin on the rocks Scientists at Los Alamos National Laboratory

  11. Rock Physics of Geologic Carbon Sequestration/Storage (Technical Report) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Technical Report: Rock Physics of Geologic Carbon Sequestration/Storage Citation Details In-Document Search Title: Rock Physics of Geologic Carbon Sequestration/Storage This report covers the results of developing the rock physics theory of the effects of CO{sub 2} injection and storage in a host reservoir on the rock�s elastic properties and the resulting seismic signatures (reflections) observed during sequestration and storage. Specific topics addressed are: (a) how the

  12. Regional Geology: GIS Database for Alternative Host Rocks and Potential

    Energy Savers [EERE]

    Siting Guidelines | Department of Energy Regional Geology: GIS Database for Alternative Host Rocks and Potential Siting Guidelines Regional Geology: GIS Database for Alternative Host Rocks and Potential Siting Guidelines The objective of this work is to develop a spatial database that integrates both geologic data for alternative host-rock formations and information that has been historically used for siting guidelines, both in the US and other countries. The Used Fuel Disposition Campaign

  13. DOE - Office of Legacy Management -- Rock Island Arsenal - IL 09

    Office of Legacy Management (LM)

    Rock Island Arsenal - IL 09 FUSRAP Considered Sites Site: ROCK ISLAND ARSENAL ( IL.09 ) Eliminated from consideration under FUSRAP - Referred to DOD Designated Name: Not Designated Alternate Name: None Location: Rock Island , Illinois IL.09-1 Evaluation Year: 1987 IL.09-2 Site Operations: Site located on a DOD facility and operated under AEC control. Exact nature or time period of operations not clear. No indication that radioactive materials were involved. Contract work with Albuquerque

  14. DOE - Office of Legacy Management -- WNI Split Rock Site - 043

    Office of Legacy Management (LM)

    Split Rock Site - 043 FUSRAP Considered Sites Site: WNI Split Rock Site (043) Designated Name: Alternate Name: Location: Evaluation Year: Site Operations: Site Disposition: Radioactive Materials Handled: Primary Radioactive Materials Handled: Radiological Survey(s): Site Status: The Western Nuclear, Inc. (WNI) Split Rock site is a Uranium Mill Tailings Remedial Action (UMTRA) Title II site located in Jeffrey City, Wyoming. UMTRA Title II sites are privately owned and operated sites that were

  15. Fractured rock stress-permeability relationships from in situ...

    Office of Scientific and Technical Information (OSTI)

    Fractured rock stress-permeability relationships from in situ data and effects of temperature and chemical-mechanical couplings Citation Details In-Document Search Title: Fractured...

  16. City of Rock Hill, South Carolina (Utility Company) | Open Energy...

    Open Energy Info (EERE)

    Hill, South Carolina (Utility Company) Jump to: navigation, search Name: City of Rock Hill Place: South Carolina Phone Number: 803-325-2500 Website: www.cityofrockhill.comdepartm...

  17. Rock Sampling At San Francisco Volcanic Field Area (Warpinski...

    Open Energy Info (EERE)

    Francisco Volcanic Field Area (Warpinski, Et Al., 2004) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Rock Sampling At San Francisco Volcanic...

  18. Carbonation Mechanism of Reservoir Rock by Supercritical Carbon...

    Open Energy Info (EERE)

    Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide Geothermal Lab Call Project Jump to: navigation, search Last modified on July 22, 2011. Project Title...

  19. Isotopic Analysis- Rock At Valles Caldera - Sulphur Springs Geothermal...

    Open Energy Info (EERE)

    Phillips, 2004) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis- Rock At Valles Caldera - Sulphur Springs Geothermal Area...

  20. Isotopic Analysis- Rock At Valles Caldera - Sulphur Springs Area...

    Open Energy Info (EERE)

    Details Location Valles Caldera - Sulphur Springs Area Exploration Technique Isotopic Analysis- Rock Activity Date Usefulness not indicated DOE-funding Unknown References...

  1. EGS rock reactions with Supercritical CO2 saturated with water...

    Office of Scientific and Technical Information (OSTI)

    fractures, and the lower portion of the fracture will contain connate water that will interact with the rock and the injected CO2. Dissolutionprecipitation reactions in the...

  2. Rock Island County, Illinois: Energy Resources | Open Energy...

    Open Energy Info (EERE)

    Illinois Hillsdale, Illinois Milan, Illinois Moline, Illinois Oak Grove, Illinois Port Byron, Illinois Rapids City, Illinois Reynolds, Illinois Rock Island Arsenal, Illinois...

  3. Rock Density At Alum Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Rock Density At Alum Area (DOE GTP) Exploration Activity Details Location Alum Geothermal Area...

  4. Carbon Dioxide Geological Sequestration in Fractured Porous Rocks

    Office of Scientific and Technical Information (OSTI)

    Training and Research on Probabilistic Hydro-Thermo-Mechanical Modeling of Carbon Dioxide Geological Sequestration in Fractured Porous Rocks Gutierrez, Marte 54 ENVIRONMENTAL...

  5. Isotopic Analysis- Rock At Valles Caldera - Sulphur Springs Geothermal...

    Open Energy Info (EERE)

    WoldeGabriel & Goff, 1992) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis- Rock At Valles Caldera - Sulphur Springs Geothermal...

  6. Rock Sampling At Long Valley Caldera Geothermal Area (Goff, Et...

    Open Energy Info (EERE)

    Long Valley Caldera Geothermal Area (Goff, Et Al., 1991) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Rock Sampling At Long Valley Caldera...

  7. Rock Sampling At Socorro Mountain Area (Armstrong, Et Al., 1995...

    Open Energy Info (EERE)

    SEM studies, and John Repetski (USGS, Reston, Virgina) conodont stratigraphy and color and textural alteration as guides to the carbonate rocks' thermal history. The...

  8. Fundamental Research on Percussion Drilling: Improved rock mechanics...

    Office of Scientific and Technical Information (OSTI)

    Fundamental Research on Percussion Drilling: Improved rock mechanics analysis, advanced simulation technology, and full-scale laboratory investigations Citation Details In-Document...

  9. AltaRock Energy Announces Successful Multiple-Zone Stimulation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Stimulation of Well at the Newberry Enhanced Geothermal Systems Demonstration AltaRock Energy Announces Successful Multiple-Zone Stimulation of Well at the Newberry ...

  10. Glen Rock, New Jersey: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    congressional district.12 Registered Energy Companies in Glen Rock, New Jersey BGA Engineering LLC References US Census Bureau Incorporated place and minor civil...

  11. Capping layer-tailored interface magnetic anisotropy in ultrathin Co{sub 2}FeAl films

    SciTech Connect (OSTI)

    Belmeguenai, M. Zighem, F.; Chérif, S. M.; Gabor, M. S. Petrisor, T.; Tiusan, C.

    2015-01-14

    Co{sub 2}FeAl (CFA) thin films of various thicknesses (2 nm ≤ d ≤ 50 nm) have been grown on (001) MgO single crystal substrates and then capped with Cr, V, and Ta. Their magnetic and structural properties have been studied by x-ray diffraction (XRD), vibrating sample magnetometry, and broadband microstrip ferromagnetic resonance (MS-FMR). The XRD revealed that the films are epitaxial with the cubic [001] CFA axis normal to the substrate plane and that the chemical order varies from the B2 phase to the A2 phase when decreasing the thickness. The deduced lattice parameters showed that the Cr-capped films exhibit a larger tetragonal distortion, as compared with the films capped with V or Ta. The presence of magnetic dead layers has been observed in CFA samples capped with V and Ta but not in the case of the Cr-capped ones. The effective magnetization, deduced from the fit of MS-FMR measurements, increases (decreases) linearly with the CFA inverse thickness (1/d) for the Cr-capped (Ta-capped) films while it is constant for the V-capped ones. This allows quantifying the perpendicular surface anisotropy coefficients of −0.46 erg/cm{sup 2} and 0.74 erg/cm{sup 2} for Cr and Ta-capped films, respectively. Moreover, the fourfold and the uniaxial anisotropy fields, measured in these films, showed different trends with a respect to the CFA inverse thickness. This allows inferring that a non-negligible part of the fourfold magnetocrystalline term is of interfacial origin.

  12. Elemental composition of two cumulate rocks

    SciTech Connect (OSTI)

    Naeem, A.; Almohandis, A.A.

    1983-04-01

    Two cumulate rock samples K-185, K-250 from the Kapalagulu intrusion, W. Tanzania, were analyzed using X-ray fluorescence (XRF), wet chemical and neutron activation analysis (NAA) techniques. Major element oxides were determined by XRF and wet chemical methods, while the concentration of trace elements were measured by NAA, using high resolution Ge(Li) detector, minicomputer-based data acquisition system and off-line computer. The percentage of major oxides and sixteen trace elements have been reported. It has been found that Cr, Ni, and Co are highly concentrated in K-250 while Sc, and most of the major elements are more concentrated in K-185. The variation of major and trace elements in these two samples have been discussed.

  13. Numerical evaluation of monofil and subtle-layered evapotranspiration (ET) landfill caps

    SciTech Connect (OSTI)

    Wilson, G.V.; Henley, M.; Valceschini, R.

    1998-01-01

    The US Department of Energy/Nevada Operations Office (DOE/NV) has identified the need to design a low-level waste (LLW) closure cap for the arid conditions at the Nevada Test Site (NTS). As a result of concerns for subsidence impacting the cover, DOE/NV redesigned the LLW cover from one containing a `hard` infiltration barrier that would likely fail, to a `soft` (ET) cover that is sufficiently deep to accommodate the hydrologic problems of subsidence. An ET cover is one that does not contain hydrologic barrier layers but relies on soil-water retention and sufficient thickness to store water until evapotranspiration (ET) can remove the moisture. Subtle layering within an ET cap using the native soil could be environmentally beneficial and cost effective.

  14. Mathematical Model of Cold Cap—Preliminary One-Dimensional Model Development

    SciTech Connect (OSTI)

    Pokorny, Richard; Hrma, Pavel R.

    2011-03-25

    The ultimate goal of batch-melting studies, laboratory-scale, large-scale, or mathematical modeling is to increase the rate of glass processing in an energy-efficient manner. Mathematical models are not merely an intermediate step between laboratory-scale and large-scale studies, but are also an important tool for assessing the responses of melters to vast combinations of process parameters. In the simplest melting situation considered in this study, a cold cap of uniform thickness rests on a pool of molten glass from which it receives a steady uniform heat flux. Thus, as the feed-to-glass conversion proceeds, the temperature, velocity, and extent of feed reactions are functions of the position along the vertical coordinate, and these functions do not vary with time. This model is used for the sensitivity analyses on the effects of key parameters on the cold-cap behavior.

  15. Mathematical modeling of cold cap: Effect of bubbling on melting rate

    SciTech Connect (OSTI)

    Pokorny, Richard; Kruger, Albert A.; Hrma, Pavel R.

    2014-12-31

    The rate of melting is a primary concern in the vitrification of radioactive wastes because it directly influences the life cycle of nuclear waste cleanup efforts. To increase glass melting performance, experimental and industrial all-electric waste glass melters employ various melt-rate enhancement techniques, the most prominent being the application of bubblers submerged into molten glass. This study investigates various ways in which bubbling affects melting rate in a waste glass melter. Using the recently developed cold cap model, we suggest that forced convection of molten glass, which increases the cold cap bottom temperature, is the main factor. Other effects, such as stirring the feed into molten glass or reducing the insulating effect of foaming, also play a role.

  16. Fundamentals of successful monitoring, reporting, and verification under a cap-and-trade program

    SciTech Connect (OSTI)

    John Schakenbach; Robert Vollaro; Reynaldo Forte

    2006-11-15

    The U.S. Environmental Protection Agency (EPA) developed and implemented the Acid Rain Program (ARP), and NOx Budget Trading Programs (NBTP) using several fundamental monitoring, reporting, and verification (MRV) elements: (1) compliance assurance through incentives and automatic penalties; (2) strong quality assurance (QA); (3) collaborative approach with a petition process; (4) standardized electronic reporting; (5) compliance flexibility for low-emitting sources; (6) complete emissions data record required; (7) centralized administration; (8) level playing field; (9) publicly available data; (10) performance-based approach; and (11) reducing conflicts of interest. Each of these elements is discussed in the context of the authors' experience under two U.S. cap-and-trade programs and their potential application to other cap and-trade programs. The U.S. Office of Management and Budget found that the Acid Rain Program has accounted for the largest quantified human health benefits of any federal regulatory program implemented in the last 10 yr, with annual benefits exceeding costs by {gt} 40 to 1. The authors believe that the elements described in this paper greatly contributed to this success. EPA has used the ARP fundamental elements as a model for other cap-and-trade programs, including the NBTP, which went into effect in 2003, and the recently published Clean Air Interstate Rule and Clean Air Mercury Rule. The authors believe that using these fundamental elements to develop and implement the MRV portion of their cap-and-trade programs has resulted in public confidence in the programs, highly accurate and complete emissions data, and a high compliance rate. 2 refs.

  17. Improvement of the quality of graphene-capped InAs/GaAs quantum dots

    SciTech Connect (OSTI)

    Othmen, Riadh Rezgui, Kamel; Ajlani, Hosni; Oueslati, Meherzi; Cavanna, Antonella; Madouri, Ali

    2014-06-07

    In this paper, we study the transfer of graphene onto InAs/GaAs quantum dots (QDs). The graphene is first grown on Cu foils by chemical vapor deposition and then polymer Polymethyl Methacrylate (PMMA) is deposited on the top of graphene/Cu. High quality graphene sheet has been obtained by lowering the dissolving rate of PMMA using vapor processing. Uncapped as well as capped graphene InAs/GaAs QDs have been studied using optical microscopy, scanning electron microscopy, and Raman spectroscopy. We gather from this that the average shifts ?? of QDs Raman peaks are reduced compared to those previously observed in graphene and GaAs capped QDs. The encapsulation by graphene makes the indium atomic concentration intact in the QDs by the reduction of the strain effect of graphene on QDs and the migration of In atoms towards the surface. This gives us a new hetero-structure graphene–InAs/GaAs QDs wherein the graphene plays a key role as a cap layer.

  18. SEQUESTRATION OF METALS IN ACTIVE CAP MATERIALS: A LABORATORY AND NUMERICAL EVALUATION

    SciTech Connect (OSTI)

    Dixon, K.; Knox, A.

    2012-02-13

    Active capping involves the use of capping materials that react with sediment contaminants to reduce their toxicity or bioavailability. Although several amendments have been proposed for use in active capping systems, little is known about their long-term ability to sequester metals. Recent research has shown that the active amendment apatite has potential application for metals contaminated sediments. The focus of this study was to evaluate the effectiveness of apatite in the sequestration of metal contaminants through the use of short-term laboratory column studies in conjunction with predictive, numerical modeling. A breakthrough column study was conducted using North Carolina apatite as the active amendment. Under saturated conditions, a spike solution containing elemental As, Cd, Co, Se, Pb, Zn, and a non-reactive tracer was injected into the column. A sand column was tested under similar conditions as a control. Effluent water samples were periodically collected from each column for chemical analysis. Relative to the non-reactive tracer, the breakthrough of each metal was substantially delayed by the apatite. Furthermore, breakthrough of each metal was substantially delayed by the apatite compared to the sand column. Finally, a simple 1-D, numerical model was created to qualitatively predict the long-term performance of apatite based on the findings from the column study. The results of the modeling showed that apatite could delay the breakthrough of some metals for hundreds of years under typical groundwater flow velocities.

  19. Carbonation Mechanism of Reservoir Rock by Supercritical Carbon Dioxide

    Broader source: Energy.gov [DOE]

    Project Objectives: Elucidate comprehensively the carbonation reaction mechanisms between supercritical carbon dioxide (scCO2) and reservoir rocks consisting of different mineralogical compositions in aqueous and non-aqueous environments at temperatures of up to 250ºC, and to develop chemical modeling of CO2-reservior rock interactions.

  20. Experience with in situ measurement of rock deformability

    SciTech Connect (OSTI)

    Bieniawski, Z.T.

    1981-07-01

    Although in situ tests have the advantage of involving a large volume or rock tested under the same environmental conditions as are prevailing in the rock mass, such tests are expensive and time consuming. In addition, there are a number of controversial questions pertinent to in situ tests.

  1. Determining inert content in coal dust/rock dust mixture

    DOE Patents [OSTI]

    Sapko, Michael J. (Finleyville, PA); Ward, Jr., Jack A. (Oakmont, PA)

    1989-01-01

    A method and apparatus for determining the inert content of a coal dust and rock dust mixture uses a transparent window pressed against the mixture. An infrared light beam is directed through the window such that a portion of the infrared light beam is reflected from the mixture. The concentration of the reflected light is detected and a signal indicative of the reflected light is generated. A normalized value for the generated signal is determined according to the relationship .phi.=(log i.sub.c `log i.sub.co) / (log i.sub.c100 -log i.sub.co) where i.sub.co =measured signal at 0% rock dust i.sub.c100 =measured signal at 100% rock dust i.sub.c =measured signal of the mixture. This normalized value is then correlated to a predetermined relationship of .phi. to rock dust percentage to determine the rock dust content of the mixture. The rock dust content is displayed where the percentage is between 30 and 100%, and an indication of out-of-range is displayed where the rock dust percent is less than 30%. Preferably, the rock dust percentage (RD%) is calculated from the predetermined relationship RD%=100+30 log .phi.. where the dust mixture initially includes moisture, the dust mixture is dried before measuring by use of 8 to 12 mesh molecular-sieves which are shaken with the dust mixture and subsequently screened from the dust mixture.

  2. Auger electron spectroscopy for the determination of sex and age related Ca/P ratio at different bone sites

    SciTech Connect (OSTI)

    Balatsoukas, Ioannis; Kourkoumelis, Nikolaos; Tzaphlidou, Margaret [Department of Medical Physics, Medical School, University of Ioannina, Ioannina 45110 (Greece)

    2010-10-15

    The Ca/P ratio of normal cortical and trabecular rat bone was measured by Auger electron spectroscopy (AES). Semiquantitative analysis was carried out using ratio techniques to draw conclusions on how age, sex and bone site affect the relative composition of calcium and phosphorus. Results show that Ca/P ratio is not sex dependent; quite the opposite, bone sites exhibit variations in elemental stoichiometry where femoral sections demonstrate higher Ca/P ratio than rear and front tibias. Age-related changes are more distinct for cortical bone in comparison with the trabecular bone. The latter's Ca/P ratio remains unaffected from all the parameters under study. This study confirms that AES is able to successfully quantify bone mineral main elements when certain critical points, related to the experimental conditions, are addressed effectively.

  3. Constitutive relationships for elastic deformation of clay rock: Data Analysis

    SciTech Connect (OSTI)

    Liu, H.H.; Rutqvist, J.; Birkholzer, J.T.

    2011-04-15

    Geological repositories have been considered a feasible option worldwide for storing high-level nuclear waste. Clay rock is one of the rock types under consideration for such purposes, because of its favorable features to prevent radionuclide transport from the repository. Coupled hydromechanical processes have an important impact on the performance of a clay repository, and establishing constitutive relationships for modeling such processes are essential. In this study, we propose several constitutive relationships for elastic deformation in indurated clay rocks based on three recently developed concepts. First, when applying Hooke's law in clay rocks, true strain (rock volume change divided by the current rock volume), rather than engineering strain (rock volume change divided by unstressed rock volume), should be used, except when the degree of deformation is very small. In the latter case, the two strains will be practically identical. Second, because of its inherent heterogeneity, clay rock can be divided into two parts, a hard part and a soft part, with the hard part subject to a relatively small degree of deformation compared with the soft part. Third, for swelling rock like clay, effective stress needs to be generalized to include an additional term resulting from the swelling process. To evaluate our theoretical development, we analyze uniaxial test data for core samples of Opalinus clay and laboratory measurements of single fractures within macro-cracked Callovo-Oxfordian argillite samples subject to both confinement and water reduced swelling. The results from this evaluation indicate that our constitutive relationships can adequately represent the data and explain the related observations.

  4. Testing, Modeling, and Monitoring to Enable Simpler, Cheaper, Longer-Lived Surface Caps

    SciTech Connect (OSTI)

    Piet, Steven James; Breckenridge, Robert Paul; Burns, Douglas Edward

    2003-02-01

    Society has and will continue to generate hazardous wastes whose risks must be managed. For exceptionally toxic, long-lived, and feared waste, the solution is deep burial, e.g., deep geological disposal at Yucca Mtn. For some waste, recycle or destruction/treatment is possible. The alternative for other wastes is storage at or near the ground level (in someone’s back yard); most of these storage sites include a surface barrier (cap) to prevent downward water migration. Some of the hazards will persist indefinitely. As society and regulators have demanded additional proof that caps are robust against more threats and for longer time periods, the caps have become increasingly complex and expensive. As in other industries, increased complexity will eventually increase the difficulty in estimating performance, in monitoring system/component performance, and in repairing or upgrading barriers as risks are managed. An approach leading to simpler, less expensive, longer-lived, more manageable caps is needed. Our project, which started in April 2002, aims to catalyze a Barrier Improvement Cycle (iterative learning and application) and thus enable Remediation System Performance Management (doing the right maintenance neither too early nor too late). The knowledge gained and the capabilities built will help verify the adequacy of past remedial decisions, improve barrier management, and enable improved solutions for future decisions. We believe it will be possible to develop simpler, longer-lived, less expensive caps that are easier to monitor, manage, and repair. The project is planned to: a) improve the knowledge of degradation mechanisms in times shorter than service life; b) improve modeling of barrier degradation dynamics; c) develop sensor systems to identify early degradation; and d) provide a better basis for developing and testing of new barrier systems. This project combines selected exploratory studies (benchtop and field scale), coupled effects accelerated aging testing at the intermediate meso-scale, testing of new monitoring concepts, and modeling of dynamic systems. The emphasis on meso-scale (coupled) tests, accelerated effects testing, and dynamic modeling differentiates the project from other efforts, while simultaneously building on that body of knowledge. The performance of evapotranspiration, capillary, and grout-based barriers is being examined. To date, the project can report new approaches to the problem, building new experimental and modeling capabilities, and a few preliminary results.

  5. Testing, Modeling, and Monitoring to Enable Simpler, Cheaper, Longer-lived Surface Caps

    SciTech Connect (OSTI)

    Piet, S. J.; Breckenridge, R. P.; Burns, D. E.

    2003-02-25

    Society has and will continue to generate hazardous wastes whose risks must be managed. For exceptionally toxic, long-lived, and feared waste, the solution is deep burial, e.g., deep geological disposal at Yucca Mtn. For some waste, recycle or destruction/treatment is possible. The alternative for other wastes is storage at or near the ground level (in someone's back yard); most of these storage sites include a surface barrier (cap) to prevent downward water migration. Some of the hazards will persist indefinitely. As society and regulators have demanded additional proof that caps are robust against more threats and for longer time periods, the caps have become increasingly complex and expensive. As in other industries, increased complexity will eventually increase the difficulty in estimating performance, in monitoring system/component performance, and in repairing or upgrading barriers as risks are managed. An approach leading to simpler, less expensive, longer-lived, more manageable caps is needed. Our project, which started in April 2002, aims to catalyze a Barrier Improvement Cycle (iterative learning and application) and thus enable Remediation System Performance Management (doing the right maintenance neither too early nor too late). The knowledge gained and the capabilities built will help verify the adequacy of past remedial decisions, improve barrier management, and enable improved solutions for future decisions. We believe it will be possible to develop simpler, longer-lived, less expensive caps that are easier to monitor, manage, and repair. The project is planned to: (a) improve the knowledge of degradation mechanisms in times shorter than service life; (b) improve modeling of barrier degradation dynamics; (c) develop sensor systems to identify early degradation; and (d) provide a better basis for developing and testing of new barrier systems. This project combines selected exploratory studies (benchtop and field scale), coupled effects accelerated aging testing at the intermediate meso-scale, testing of new monitoring concepts, and modeling of dynamic systems. The emphasis on meso-scale (coupled) tests, accelerated effects testing, and dynamic modeling differentiates the project from other efforts, while simultaneously building on that body of knowledge. The performance of evapotranspiration, capillary, and grout-based barriers is being examined. To date, the project can report new approaches to the problem, building new experimental and modeling capabilities, and a few preliminary results.

  6. Energy Market and Economic Impacts Proposal to Reduce Greenhouse Gas Intensity with a Cap and Trade System

    Reports and Publications (EIA)

    2007-01-01

    This report was prepared by the Energy Information Administration (EIA), in response to a September 27, 2006, request from Senators Bingaman, Landrieu, Murkowski, Specter, Salazar, and Lugar. The Senators requested that EIA assess the impacts of a proposal that would regulate emissions of greenhouse gases (GHGs) through an allowance cap-and-trade system. The program would set the cap to achieve a reduction in emissions relative to economic output, or greenhouse gas intensity.

  7. Effect of Organic Capping Layers over Monodisperse Platinum Nanoparticles upon Activity for Ethylene Hydrogenation and Carbon Monoxide Oxidation

    SciTech Connect (OSTI)

    Kuhn, John N.; Tsung, Chia-Kuang; Huang, Wenyu; Somorjai, Gabor A.

    2009-03-24

    The influence of oleylamine (OA), trimethyl tetradecyl ammonium bromide (TTAB), and polyvinlypyrrolidone (PVP) capping agents upon the catalytic properties of Pt/silica catalysts was evaluated. Pt nanoparticles that were 1.5 nm in size were synthesized by the same procedure (ethylene glycol reduction under basic conditions) with the various capping agents added afterward for stabilization. Before examining catalytic properties for ethylene hydrogenation and CO oxidation, the Pt NPs were deposited onto mesoporous silica (SBA-15) supports and characterized by transmission electron microscopy (TEM), H{sub 2} chemisorption, and elemental analysis (ICP-MS). PVP- and TTAB-capped Pt yielded mass-normalized reaction rates that decreased with increasing pretreatment temperature, and this trend was attributed to the partial coverage of the Pt surface with decomposition products from the organic capping agent. Once normalized to the Pt surface area, similar intrinsic activities were obtained regardless of the pretreatment temperature, which indicated no influence on the nature of the active sites. Consequently, a chemical probe technique using intrinsic activity for ethylene hydrogenation was demonstrated as an acceptable method for estimating the metallic surface areas of Pt. Amine (OA) capping exhibited a detrimental influence on the catalytic properties as severe deactivation and low activity were observed for ethylene hydrogenation and CO oxidation, respectively. These results were consistent with amine groups being strong poisons for Pt surfaces, and revealed the need to consider the effects of capping agents on the catalytic properties.

  8. America's Atomic Army: The Historical Archaeology of Camp Desert Rock

    SciTech Connect (OSTI)

    Susan R. Edwards

    2007-11-02

    Established in 1951, Camp Desert Rock served as the training ground for America's 'Atomic Army'. For the next six years, U.S. ground troops traveled to the Nevada desert to participate in military maneuvers during atmospheric atomic weapons testing. Nearly 60,000 soldiers received physical and psychological training in atomic warfare. Abandoned when atmospheric testing ended, Camp Desert Rock was dismantled and its buildings moved to other locations. Today, the camp appears as a sterile expanse of desert marked by rock-lined tent platforms, concrete foundations, and trash scatters. Although visually unimposing, the site is rich with the history of America's nuclear testing program.

  9. DOE - Fossil Energy: Squeezing Oil Out of Rock

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2-Squeezing Out Oil An Energy Lesson Looking Down an Oil Well Looking Down an Oil Well Squeezing Oil out of Rocks Imagine trying to force oil through a rock. Can't be done, you say? Actually, it can. In fact, oil droplets can squeeze through the tiny pores of underground rock on their own, pushed by the tremendous pressures that exist deep beneath the surface. How does this happen? Imagine a balloon, blown up to its fullest. The air in the balloon is under pressure. It wants to get out. Stick a

  10. Evaluation of Five Sedimentary Rocks Other Than Salt for Geologic Repository Siting Purposes

    SciTech Connect (OSTI)

    Croff, A.G.; Lomenick, T.F.; Lowrie, R.S.; Stow, S.H.

    2003-11-15

    The US Department of Energy (DOE), in order to increase the diversity of rock types under consideration by the geologic disposal program, initiated the Sedimary ROck Program (SERP), whose immediate objectiv eis to evaluate five types of secimdnary rock - sandstone, chalk, carbonate rocks (limestone and dolostone), anhydrock, and shale - to determine the potential for siting a geologic repository. The evaluation of these five rock types, together with the ongoing salt studies, effectively results in the consideration of all types of relatively impermeable sedimentary rock for repository purposes. The results of this evaluation are expressed in terms of a ranking of the five rock types with respect to their potential to serve as a geologic repository host rock. This comparative evaluation was conducted on a non-site-specific basis, by use of generic information together with rock evaluation criteria (RECs) derived from the DOE siting guidelines for geologic repositories (CFR 1984). An information base relevant to rock evaluation using these RECs was developed in hydrology, geochemistry, rock characteristics (rock occurrences, thermal response, rock mechanics), natural resources, and rock dissolution. Evaluation against postclosure and preclosure RECs yielded a ranking of the five subject rocks with respect to their potential as repository host rocks. Shale was determined to be the most preferred of the five rock types, with sandstone a distant second, the carbonate rocks and anhydrock a more distant third, and chalk a relatively close fourth.

  11. Process for making surfactant capped metal oxide nanocrystals, and products produced by the process

    DOE Patents [OSTI]

    Alivisatos, A. Paul; Rockenberger, Joerg

    2006-01-10

    Disclosed is a process for making surfactant capped nanocrystals of metal oxides which are dispersable in organic solvents. The process comprises decomposing a metal cupferron complex of the formula MXCupX, wherein M is a metal, and Cup is a N-substituted N-Nitroso hydroxylamine, in the presence of a coordinating surfactant, the reaction being conducted at a temperature ranging from about 150 to about 400.degree. C., for a period of time sufficient to complete the reaction. Also disclosed are compounds made by the process.

  12. InGaAs/GaAs quantum dot interdiffiusion induced by cap layer overgrowth

    SciTech Connect (OSTI)

    Jasinski, J.; Babinski, A.; Czeczott, M.; Bozek, R.

    2000-06-28

    The effect of thermal treatment during and after growth of InGaAs/GaAs quantum dot (QD) structures was studied. Transmission electron microscopy and atomic force microscopy confirmed the presence of interacting QDs, as was expected from analysis of temperature dependence of QD photoluminescence (PL) peak. The results indicate that the effect of post-growth annealing can be similar to the effect of elevated temperature of capping layer growth. Both, these thermal treatments can lead to a similar In and Ga interdiffiusion resulting in a similar blue-shift of QD PL peak.

  13. Properites of ultrathin films appropriate for optics capping layers in extreme ultraviolet lithography (EUVL)

    SciTech Connect (OSTI)

    Bajt, S; Edwards, N V; Madey, T E

    2007-06-25

    The contamination of optical surfaces by irradiation shortens optics lifetime and is one of the main concerns for optics used in conjunction with intense light sources, such as high power lasers, 3rd and 4th generation synchrotron sources or plasma sources used in extreme ultraviolet lithography (EUVL) tools. This paper focuses on properties and surface chemistry of different materials, which as thin layers, could be used as capping layers to protect and extend EUVL optics lifetime. The most promising candidates include single element materials such as ruthenium and rhodium, and oxides such as TiO{sub 2} and ZrO{sub 2}.

  14. Oxidation preventative capping layer for deep-ultra-violet and soft x-ray multilayers

    DOE Patents [OSTI]

    Prisbrey, Shon T.

    2004-07-06

    The invention uses iridium and iridium compounds as a protective capping layer on multilayers having reflectivity in the deep ultra-violet to soft x-ray regime. The iridium compounds can be formed in one of two ways: by direct deposition of the iridium compound from a prepared target or by depositing a thin layer (e.g., 5-50 angstroms) of iridium directly onto an element. The deposition energy of the incoming iridium is sufficient to activate the formation of the desired iridium compound. The compounds of most interest are iridium silicide (IrSi.sub.x) and iridium molybdenide (IrMo.sub.x).

  15. Apparent Welding Textures In Altered Pumice-Rich Rocks | Open...

    Open Energy Info (EERE)

    Apparent Welding Textures In Altered Pumice-Rich Rocks Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Apparent Welding Textures In Altered...

  16. Zeolitization Of Intracaldera Sediments And Rhyolitic Rocks In...

    Open Energy Info (EERE)

    In The 1.25 Ma Lake Of Valles Caldera, New Mexico, USA Abstract Quantitative X-ray diffraction analysis of about 80 rhyolite and associated lacustrine rocks has characterized...

  17. Zeolitization Of Intracaldera Sediments And Rhyolitic Rocks In...

    Open Energy Info (EERE)

    In The 1.25 Ma Lake Of Valles Caldera, New Mexico, Usa Abstract Quantitative X-ray diffraction analysis of about 80 rhyolite and associated lacustrine rocks has characterized...

  18. Electrical Conductivity of Soils and Rocks | Open Energy Information

    Open Energy Info (EERE)

    Reference LibraryAdd to library Report: Electrical Conductivity of Soils and Rocks Author J.D. McNeill Organization Geonics Limited Published Geonics Limited, 1980 Report Number...

  19. Rock Sampling At Coso Geothermal Area (1995) | Open Energy Information

    Open Energy Info (EERE)

    and analytical analyses of reservoir rock and vein material. References Lutz, S.J.; Moore, J.N. ; Copp, J.F. (1 June 1995) Lithology and alteration mineralogy of...

  20. Big Rock, Illinois: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Big Rock is a village in Kane County, Illinois.1 References US Census Bureau...

  1. Rock Hill Utilities- Water Heater and Heat Pump Rebate Program

    Broader source: Energy.gov [DOE]

    Through the SmartChoice program, Rock Hill Utilities offers rebates for water heater and heat pump replacements. Information on financing for heat pumps can also be found on the web site listed...

  2. Reservoir Investigations on the Hot Dry Rock Geothermal System...

    Open Energy Info (EERE)

    Investigations on the Hot Dry Rock Geothermal System, Fenton Hill, New Mexico- Tracer Test Results Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference...

  3. Figure 2. Stratigraphic Summary of Ages, Names and Rock Types...

    U.S. Energy Information Administration (EIA) Indexed Site

    2. Stratigraphic Summary of Ages, Names and Rock Types in the ANWR 1002 and Coastal Plain Area of the Alaska North Slope. Potentially Productive Reservoirs and Plays Assessed by ...

  4. Geochemical Data on Waters, Gases, Scales, and Rocks from the...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Geochemical Data on Waters, Gases, Scales, and Rocks from the Dixie Valley Region, Nevada (1996-1999)...

  5. Y-12s Moon Rocks and Jim Williams

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Moon Rocks and Jim Williams Often I am stopped and given suggestions about what would be good information to include in the history of Y-12 being published weekly in The Oak...

  6. Disposal in Crystalline Rocks: FY’15 Progress Report

    Broader source: Energy.gov [DOE]

    The objective of the Crystalline Disposal R&D Work Package is to advance our understanding of long-term disposal of used fuel in crystalline rocks and to develop necessary experimental and...

  7. Project Reports for Standing Rock Sioux Tribe- 2011 Project

    Broader source: Energy.gov [DOE]

    The Standing Rock Sioux Tribe's (SRST) cultural identity demands that tribal development occur in a sustainable manner and in a manner protective of the tribe's natural resources to preserve them for following generations.

  8. International Collaborations on Fluid Flows in Fractured Crystalline Rocks:

    Office of Scientific and Technical Information (OSTI)

    FY14 Progress Report. (Technical Report) | SciTech Connect International Collaborations on Fluid Flows in Fractured Crystalline Rocks: FY14 Progress Report. Citation Details In-Document Search Title: International Collaborations on Fluid Flows in Fractured Crystalline Rocks: FY14 Progress Report. Abstract not provided. Authors: Wang, Yifeng Publication Date: 2014-08-01 OSTI Identifier: 1155020 Report Number(s): SAND2014-16913R 536890 DOE Contract Number: DE-AC04-94AL85000 Resource Type:

  9. Experimental Program for Used Fuel Disposition in Crystalline Rocks.

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Experimental Program for Used Fuel Disposition in Crystalline Rocks. Citation Details In-Document Search Title: Experimental Program for Used Fuel Disposition in Crystalline Rocks. Abstract not provided. Authors: Wang, Yifeng Publication Date: 2014-10-01 OSTI Identifier: 1242086 Report Number(s): SAND2014-19251C 540815 DOE Contract Number: AC04-94AL85000 Resource Type: Conference Resource Relation: Conference: Proposed for presentation at the DOE Fuel Cycle

  10. Assessing the relative permeability of heterogeneous reservoir rock

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Conference: Assessing the relative permeability of heterogeneous reservoir rock Citation Details In-Document Search Title: Assessing the relative permeability of heterogeneous reservoir rock Reservoir engineers are often faced with heterogeneous core material, for which conventional methods of estimating relative permeability are susceptible to error and may lead to incorrect conclusions regarding displacement efficiency, wettability and reservoir performance.

  11. Fundamental Research on Percussion Drilling: Improved rock mechanics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    analysis, advanced simulation technology, and full-scale laboratory investigations (Technical Report) | SciTech Connect Fundamental Research on Percussion Drilling: Improved rock mechanics analysis, advanced simulation technology, and full-scale laboratory investigations Citation Details In-Document Search Title: Fundamental Research on Percussion Drilling: Improved rock mechanics analysis, advanced simulation technology, and full-scale laboratory investigations × You are accessing a

  12. Size tunable elemental copper nanoparticles: extracellular synthesis by thermoanaerobic bacteria and capping molecules

    SciTech Connect (OSTI)

    Jang, Gyoung Gug; Jacobs, Christopher B; Gresback, Ryan G; Ivanov, Ilia N; Meyer III, Harry M; Kidder, Michelle; Joshi, Pooran C; Jellison Jr, Gerald Earle; Phelps, Tommy Joe; Graham, David E; Moon, Ji Won

    2015-01-01

    Bimodal sized elemental copper (Cu) nanoparticles (NPs) were synthesized from inexpensive oxidized copper salts by an extracellular metal-reduction process using anaerobic Thermoanaerobacter sp. X513 bacteria in aqueous solution. The bacteria nucleate NPs outside of the cell, and they control the Cu2+ reduction rate to form uniform crystallites with an average diameter of 1.75 0.46 m after 3-day incubation. To control the size and enhance air stability of Cu NPs, the reaction mixtures were supplemented with nitrilotriacetic acid as a chelator, and the surfactant capping agents oleic acid, oleylamine, ascorbic acid, or L-cysteine. Time-dependent UV-visible absorption measurements and XPS studies indicated well-suspended, bimodal colloidal Cu NPs (70 150 and 5 10 nm) with extended air-stability up to 300 min and stable Cu NP films surfaces with 14% oxidation after 20 days. FTIR spectroscopy suggested that these capping agents were effectively adsorbed on the NP surface providing oxidation resistance in aqueous and dry conditions. Compared to previously reported Cu NP syntheses, this biological process substantially reduced the requirement for hazardous organic solvents and chemical reducing agents, while reducing the levels of Cu oxide impurities in the product. This process was highly reproducible and scalable from 0.01 to 1-L batches.

  13. Measurement and analysis of. cap alpha. particles emitted in reactions of /sup 12/C bombarding /sup 12/C, /sup 27/Al, and /sup nat/Ca

    SciTech Connect (OSTI)

    XIE Yuan-xiang; WU Guo-hua; ZHU Yong-tai; MIAO Rong-zhi; FONG En-pu; YIN Xu; MIAO He-bing; CAI Jing-xiang; SHEN Wen-qing; SUN Shu-ming

    1985-10-01

    The energy spectra and angular distributions of the ..cap alpha.. particles emitted in the reactions of 69.5 MeV /sup 12/C bombarding /sup 12/C, /sup 27/Al, and /sup nat/Ca have been measured and analyzed using the fast-particle exciton model. The contribution from the equilibrium and pre-equilibrium ..cap alpha.. emissions is calculated to be 89%, 81%, and 83% of the total ..cap alpha.. yields for the three reactions, respectively, where the pre-equilibrium ..cap alpha.. emissions are 11%, 14%, and 16%, respectively. A small contribution comes from other reaction mechanisms.

  14. Environmental assessment of remedial action at the slick rock Uranium Mill Tailings sites Slick Rock, Colorado

    SciTech Connect (OSTI)

    Not Available

    1994-09-01

    The Uranium Mill Tailings Radiation Control Act of 1978 (42 USC {section} 7901 et seq.), hereafter referred to as the UMTRCA, authorized the U.S. Department of Energy (DOE) to clean up two uranium mill tailings processing sites near Slick Rock, Colorado, in San Miguel County. The purpose of the cleanup is to reduce the potential health effects associated with the radioactive materials remaining on the sites and on vicinity properties (VPs) associated with the sites. Contaminated materials cover an estimated 55 acres of the Union Carbide (UC) processing site and 12 ac of the North Continent (NC) processing site. The total estimated volume of contaminated materials is approximately 61 8,300 cubic yards. In addition to the contamination in the two processing site areas, four VPs were found to contain contamination. As a result of the tailings being exposed to the environment, contamination associated with the UC and NC sites has leached into shallow ground water. Surface water has not been affected. The closest residence is approximately 0.3 air mi from either site. The proposed action is to remediate the UC and NC sites by removing all contaminated materials within the designated site boundaries or otherwise associated with the sites, and relocating them to, and stabilizing them at, a location approximately 5 road mi (8 km) northeast of the sites on land administered by the Bureau of Land Management (BLM). Remediation would be performed by the DOE`s Uranium Mill Tailings Remedial Action (UMTRA) Project. All solid contaminated materials would be buried under 5 feet (ft) of rock and soil materials. The proposed disposal site area is currently used by ranchers for cattle grazing over a 7-month period. The closest residence to the proposed disposal site is 2 air mi. An estimated 44 ac of land would be permanently transferred from the BLM to the DOE and restricted from future use.

  15. Systems and methods for measuring a parameter of a landfill including a barrier cap and wireless sensor systems and methods

    DOE Patents [OSTI]

    Kunerth, Dennis C.; Svoboda, John M.; Johnson, James T.

    2007-03-06

    A method of measuring a parameter of a landfill including a cap, without passing wires through the cap, includes burying a sensor apparatus in the landfill prior to closing the landfill with the cap; providing a reader capable of communicating with the sensor apparatus via radio frequency (RF); placing an antenna above the barrier, spaced apart from the sensor apparatus; coupling the antenna to the reader either before or after placing the antenna above the barrier; providing power to the sensor apparatus, via the antenna, by generating a field using the reader; accumulating and storing power in the sensor apparatus; sensing a parameter of the landfill using the sensor apparatus while using power; and transmitting the sensed parameter to the reader via a wireless response signal. A system for measuring a parameter of a landfill is also provided.

  16. Proceedings of the scientific visit on crystalline rock repository development.

    SciTech Connect (OSTI)

    Mariner, Paul E.; Hardin, Ernest L.; Miksova, Jitka

    2013-02-01

    A scientific visit on Crystalline Rock Repository Development was held in the Czech Republic on September 24-27, 2012. The visit was hosted by the Czech Radioactive Waste Repository Authority (RAWRA), co-hosted by Sandia National Laboratories (SNL), and supported by the International Atomic Energy Agency (IAEA). The purpose of the visit was to promote technical information exchange between participants from countries engaged in the investigation and exploration of crystalline rock for the eventual construction of nuclear waste repositories. The visit was designed especially for participants of countries that have recently commenced (or recommenced) national repository programmes in crystalline host rock formations. Discussion topics included repository programme development, site screening and selection, site characterization, disposal concepts in crystalline host rock, regulatory frameworks, and safety assessment methodology. Interest was surveyed in establishing a %E2%80%9Cclub,%E2%80%9D the mission of which would be to identify and address the various technical challenges that confront the disposal of radioactive waste in crystalline rock environments. The idea of a second scientific visit to be held one year later in another host country received popular support. The visit concluded with a trip to the countryside south of Prague where participants were treated to a tour of the laboratory and underground facilities of the Josef Regional Underground Research Centre.

  17. Alternatives Analysis Amchitka Island Mud Pit Cap Repair, Amchitka, Alaska January 2016

    SciTech Connect (OSTI)

    Darr, Paul S.

    2016-01-01

    The U.S. Department of Energy (DOE) Office of Legacy Management (LM) manages the Nevada Offsites program, which includes a series of reclaimed drilling mud impoundments on Amchitka Island, Alaska (Figure 1). Navarro Research and Engineering, Inc. is the Legacy Management Support contractor (the Contractor) for LM. The Contractor has procured Tetra Tech, Inc. to provide engineering support to the Amchitka mud pit reclamation project. The mud pit caps were damaged during a 7.9-magnitude earthquake that occurred in 2014. The goals of the current project are to investigate conditions at the mud pit impoundments, identify feasible alternatives for repair of the cover systems and the contents, and estimate relative costs of repair alternatives. This report presents descriptions of the sites and past investigations, existing conditions, summaries of various repair/mitigation alternatives, and direct, unburdened, order-of-magnitude (-15% to +50%) associated costs.

  18. Liquid-phase-deposited siloxane-based capping layers for silicon solar cells

    SciTech Connect (OSTI)

    Veith-Wolf, Boris; Wang, Jianhui; Hannu-Kuure, Milja; Chen, Ning; Hadzic, Admir; Williams, Paul; Leivo, Jarkko; Karkkainen, Ari; Schmidt, Jan

    2015-02-02

    We apply non-vacuum processing to deposit dielectric capping layers on top of ultrathin atomic-layer-deposited aluminum oxide (AlO{sub x}) films, used for the rear surface passivation of high-efficiency crystalline silicon solar cells. We examine various siloxane-based liquid-phase-deposited (LPD) materials. Our optimized AlO{sub x}/LPD stacks show an excellent thermal and chemical stability against aluminum metal paste, as demonstrated by measured surface recombination velocities below 10 cm/s on 1.3 Ωcm p-type silicon wafers after firing in a belt-line furnace with screen-printed aluminum paste on top. Implementation of the optimized LPD layers into an industrial-type screen-printing solar cell process results in energy conversion efficiencies of up to 19.8% on p-type Czochralski silicon.

  19. Distribution of ion current density on a rotating spherical cap substrate during ion-assisted deposition

    SciTech Connect (OSTI)

    Marushka, Viktor; Zabeida, Oleg Martinu, Ludvik

    2014-11-01

    The uniformity of ion density is critical for applications relying on the ion assisted deposition technique for the fabrication of the high quality thin films. The authors propose and describe here a method allowing one to calculate the ion density distribution on spherical substrate holders under stationary and rotating conditions for different positions of the ion source. The ion beam shape was approximated by a cos{sup n} function, and the ion current density was represented by a function inversely proportional to the distance from the ion source in accordance with our experimental results. As an example, a calculation of the current density distribution on the spherical cap substrate was performed for a broad beam ion source operated with an anode current of 3?A. The authors propose an approach for process optimization with respect to the ion source position and its inclination, in terms of uniformity and absolute value of the ion current density.

  20. Superhard nanophase cutter materials for rock drilling applications

    SciTech Connect (OSTI)

    Voronov, O.; Tompa, G.; Sadangi, R.; Kear, B.; Wilson, C.; Yan, P.

    2000-06-23

    The Low Pressure-High Temperature (LPHT) System has been developed for sintering of nanophase cutter and anvil materials. Microstructured and nanostructured cutters were sintered and studied for rock drilling applications. The WC/Co anvils were sintered and used for development of High Pressure-High Temperature (HPHT) Systems. Binderless diamond and superhard nanophase cutter materials were manufactured with help of HPHT Systems. The diamond materials were studied for rock machining and drilling applications. Binderless Polycrystalline Diamonds (BPCD) have high thermal stability and can be used in geothermal drilling of hard rock formations. Nanophase Polycrystalline Diamonds (NPCD) are under study in precision machining of optical lenses. Triphasic Diamond/Carbide/Metal Composites (TDCC) will be commercialized in drilling and machining applications.

  1. Generalized chemical route to develop fatty acid capped highly dispersed semiconducting metal sulphide nanocrystals

    SciTech Connect (OSTI)

    Patel, Jayesh D.; Chemical Engineering Department, University of Laval, Quebec, QC, G1K 7P4 ; Mighri, Frej; Chemical Engineering Department, University of Laval, Quebec, QC, G1K 7P4 ; Ajji, Abdellah; Chemical Engineering Department, Ecole Polytechnique, C.P. 6079, Succ. Centre-Ville Montreal, QC, H3C 3A7

    2012-08-15

    Highlights: ► Chemical route for the synthesis of OA-capped CdS, ZnS and PbS at low temperature. ► Synthesized nanocrystals via thermolysis of their metal–oleate complexes. ► Size quantized nanocrystals were highly dispersed and stable at room temperature. -- Abstract: This work deals with the synthesis of highly dispersed semiconducting nanocrystals (NCs) of cadmium sulphide (CdS), zinc sulphide (ZnS) and lead sulphide (PbS) through a simple and generalized process using oleic acid (OA) as surfactant. To synthesize these NCs, metal–oleate (M–O) complexes were obtained from the reaction at 140 °C between metal acetates and OA in hexanes media. Subsequently, M–O complexes were sulphurized using thioacetamide at the same temperature. Transmission electron microscopy (TEM) and X-ray diffraction (XRD) characterizations show that the synthesized products are of nanoscale-size with highly crystalline cubic phase. The optical absorption of OA-capped metal sulphide NCs confirms that their size quantization induced a large shift towards visible region. Photoluminescence (PL) spectrum of CdS NCs shows a broad band-edge emission with shallow and deep-trap emissions, while PL spectrum of ZnS NCs reveals a broad emission due to defects states on the surface. The thermogravimetric analysis (TGA) and Fourier transform infrared (FTIR) spectroscopy indicate that fatty acid monolayers were bound strongly on the nanocrystal surface as a carboxylate and the two oxygen atoms of the carboxylate were coordinated symmetrically to the surface of the NCs. The strong binding between the fatty acid and the NCs surface enhances the stability of NCs colloids. In general, this generalized route has a great potential in developing nanoscale metal sulphides for opto-electronic devices.

  2. Analysis of Factors Controlling Cell Cycle that Can Be Synchronized Nondestructively During Root Cap Development

    SciTech Connect (OSTI)

    Martha Hawes

    2011-02-04

    Publications and presentations during the final funding period, including progress in defining the substrate specificity, the primary goal of the project, are listed below. Both short-term and long-term responses mediated by PsUGT1 have been characterized in transgenic or mutant pea, alfalfa, and Arabidopsis with altered expression of PsUGT1. Additional progress includes evaluation of the relationship between control of the cell cycle by PsUGT1 and other glycosyltransferase and glycosidase enzymes that are co-regulated in the legume root cap during the onset of mitosis and differentiation. Transcriptional profiling and multidimensional protein identification technology ('MudPIT') have been used to establish the broader molecular context for the mechanism by which PsUGT1 controls cell cycle in response to environmental signals. A collaborative study with the Norwegian Forest Research Institute (who provided $10,000.00 in supplies and travel funds for collaborator Dr. Toril Eldhuset to travel to Arizona and Dr. H. H. Woo to travel to Norway) made it possible to establish that the inducible root cap system for studying carbohydrate synthesis and solubilization is expressed in gymnosperm as well as angiosperm species. This discovery provides an important tool to amplify the potential applications of the research in defining conserved cell cycle machinery across a very broad range of plant species and habitats. The final work, published during 2009, revealed an additional surprising parallel with mammalian immune responses: The cells whose production is controlled by PsUGT1 appear to function in a manner which is analogous to that of white blood cells, by trapping and killing in an extracellular manner. This may explain why mutation within the coding region of PsUGT1 and its homolog in humans (UGT1) is lethal to plants and animals. The work has been the subject of invited reviews. A postdoctoral fellow, eight undergraduate students, four M.S. students and three Ph.D. students have been supported.

  3. Viscuous Mech Behavior of Rock Mass Under Therm Stress

    Energy Science and Technology Software Center (OSTI)

    1998-10-14

    VISCOT is a nonlinear, transient , thermal-stress, finite-element program designed to determine the viscoelastic, viscoplastic, or elastoplastic deformation of a rock mass due to mechanical and thermal loading. A major application of VISCOT in conjunction with a SCEPTER heat transfer code, e.g. DOT-BPMD, is the thermomechanical analysis of a rock mass such as salt in which significant time-dependent, nonlinear deformations are expected to occur. Such problems include room and canister scale studies during the excavation,more » operation, and long term, post closure stages in a salt repository.« less

  4. DOE - Fossil Energy: Washing More Oil from Rocks

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3-Washing Out Oil An Energy Lesson Looking Down an Oil Well Looking Down an Oil Well Washing More Oil from Rocks A lot of oil can be left behind after "primary production." Often, it is clinging tightly to the underground rocks, and the natural reservoir pressure has dwindled to the point where it can't force the oil to the surface. Imagine spilling a can of oil on the concrete floor of a garage. Some of it can be wiped up. But the thin film of oil that's left on the floor is much more

  5. SEISMIC AND ROCK PHYSICS DIAGNOSTICS OF MULTISCALE RESERVOIR TEXTURES

    SciTech Connect (OSTI)

    Gary Mavko

    2003-10-01

    As part of our study on ''Relationships between seismic properties and rock microstructure'', we have (1) Studied relationships between velocity and permeability. (2) Used independent experimental methods to measure the elastic moduli of clay minerals as functions of pressure and saturation. (3) Applied different statistical methods for characterizing heterogeneity and textures from scanning acoustic microscope (SAM) images of shale microstructures. (4) Analyzed the directional dependence of velocity and attenuation in different reservoir rocks (5) Compared Vp measured under hydrostatic and non-hydrostatic stress conditions in sands. (6) Studied stratification as a source of intrinsic anisotropy in sediments using Vp and statistical methods for characterizing textures in sands.

  6. Environmental assessment of remedial action at the Slick Rock uranium mill tailings sites, Slick Rock, Colorado

    SciTech Connect (OSTI)

    1995-01-01

    The Uranium Mill Tailings Radiation Control Act of 1978, hereafter referred to as the UMTRCA, authorized the US Department of Energy (DOE) to clean up two uranium mill tailings processing sites near Slick Rock, Colorado, in San Miguel County. The purpose of the cleanup is to reduce the potential health effects associated with the radioactive materials remaining on the processing sites and on vicinity properties (VPs) associated with the sites. The US Environmental Protection Agency (EPA) promulgated standards for the UMTRCA that contained measures to control the contaminated materials and to protect the ground water from further degradation. The sites contain concrete foundations of mill buildings, tailings piles, and areas contaminated by windblown and waterborne radioactive tailings materials. The proposed action is to remediate the UC and NC sites by removing all contaminated materials within the designated site boundaries or otherwise associated with the sites, and relocating them to, and stabilizing them at, a location approximately 5 road mi (8 km) northeast of the processing sites on land administered by the US Bureau of Land Management (BLM). Remediation would be performed by the DOE`s Uranium Mill Tailings Remedial Action (UMTRA) Project.

  7. Rock mass response to the decline in underground coal mining

    SciTech Connect (OSTI)

    Holub, K.

    2006-01-15

    Geomechanical problems of mining in the Ostrava-Karvina Coal Basin were studied on the basis of longterm experience gained from seismological observations. They could serve as reasonable models of rock-mass response to temporary reduction and gradual decline in mining activities and mine closure.

  8. Petrology of Eocene rocks, southeastern Georgia coastal plain

    SciTech Connect (OSTI)

    Thayer, P.A.; Miller, J.A.

    1988-09-01

    Study of cores from a US Geological Survey test well in Wayne County indicates that Eocene strata represent an overall shallowing-upward, clastic-carbonate sequence. The 1397-ft (426-m) Eocene section is divided into three units: unnamed lower Eocene rocks, middle Eocene (Claibornian) Lisbon and Avon Park Formations, and upper Eocene (Jacksonian) Ocala Limestone.

  9. SEISMIC AND ROCK PHYSICS DIAGNOSTICS OF MULTISCALE RESERVOIR TEXTURES

    SciTech Connect (OSTI)

    Gary Mavko

    2004-08-01

    As part of our study on ''Relationships between seismic properties and rock microstructure'', we have continued our work on analyzing well logs and microstructural constraints on seismic signatures. We report results of three studies in this report. The first one deals with fractures and faults that provide the primary control on the underground fluid flow through low permeability massive carbonate rocks. Fault cores often represent lower transmissibility whereas the surrounding damaged rocks and main slip surfaces are high transmissibility elements. We determined the physical properties of fault rocks collected in and around the fault cores of large normal faults in central Italy. After studying the P- and S-wave velocity variation during cycles of confining pressure, we conclude that a rigid pore frame characterizes the fault gouge whereas the fractured limestone comprises pores with a larger aspect ratio. The second study was to characterize the seismic properties of brine as its temperature decreases from 25 C to -21 C. The purpose was to understand how the transmitted wave changes with the onset of freezing. The main practical reason for this experiment was to use partially frozen brine as an analogue for a mixture of methane hydrate and water present in the pore space of a gas hydrate reservoir. In the third study we analyzed variations in dynamic moduli in various carbonate reservoirs. The investigations include log and laboratory data from velocity, porosity, permeability, and attenuation measurements.

  10. SEISMIC AND ROCK PHYSICS DIAGNOSTICS OF MULTISCALE RESERVOIR TEXTURES

    SciTech Connect (OSTI)

    Gary Mavko

    2003-06-30

    As part of our study on ''Relationships between seismic properties and rock microstructure'', we have studied (1) Methods for detection of stress-induced velocity anisotropy in sands. (2) We have initiated efforts for velocity upscaling to quantify long-wavelength and short-wavelength velocity behavior and the scale-dependent dispersion caused by sediment variability in different depositional environments.

  11. Process of breaking and rendering permeable a subterranean rock mass

    DOE Patents [OSTI]

    Lekas, Mitchell A. (Concord, CA)

    1980-01-01

    The process of the present invention involves the following steps: producing, as by hydrofracing, a substantially horizontal fracture in the subterranean rock mass to be processed; emplacing an explosive charge in the mass in spaced juxtaposed position to the fracture; enlarging the fracture to create a void space thereat, an initial lifting of the overburden, and to provide a free face juxtaposed to and arranged to cooperate with the emplaced explosive charge; and exploding the charge against the free face for fragmenting the rock and to distribute the space, thus providing fractured, pervious, rubble-ized rock in an enclosed subterranean chamber. Firing of the charge provides a further lifting of the overburden, an enlargement of the chamber and a larger void space to distribute throughout the rubble-ized rock within the chamber. In some forms of the invention an explosive charge is used to produce a transitory enlargement of the fracture, and the juxtaposed emplaced charge is fired during the critical period of enlargement of the fracture.

  12. Columbia River Channel Improvement Project Rock Removal Blasting: Monitoring Plan

    SciTech Connect (OSTI)

    Carlson, Thomas J.; Johnson, Gary E.

    2010-01-29

    This document provides a monitoring plan to evaluate take as outlined in the National Marine Fisheries Service 2002 Biological Opinion for underwater blasting to remove rock from the navigation channel for the Columbia River Channel Improvement Project. The plan was prepared by the Pacific Northwest National Laboratory (PNNL) for the U.S. Army Corps of Engineers (USACE), Portland District.

  13. 2008 Rock Deformation GRC - Conference August 3-8, 2008

    SciTech Connect (OSTI)

    James G. Hirth

    2009-09-21

    The GRC on Rock Deformation highlights the latest research in brittle and ductile rock mechanics from experimental, field and theoretical perspectives. The conference promotes a multi-disciplinary forum for assessing our understanding of rock strength and related physical properties in the Earth. The theme for the 2008 conference is 'Real-time Rheology'. Using ever-improving geophysical techniques, our ability to constrain the rheological behavior during earthquakes and post-seismic creep has improved significantly. Such data are used to investigate the frictional behavior of faults, processes responsible for strain localization, the viscosity of the lower crust, and viscous coupling between the crust and mantle. Seismological data also provide information on the rheology of the lower crust and mantle through analysis of seismic attenuation and anisotropy. Geologists are improving our understanding of rheology by combining novel analyses of microstructures in naturally deformed rocks with petrologic data. This conference will bring together experts and students in these research areas with experimentalists and theoreticians studying the same processes. We will discuss and assess where agreement exists on rheological constraints derived at different length/time scales using different techniques - and where new insight is required. To encompass the elements of these topics, speakers and discussion leaders with backgrounds in geodesy, experimental rock deformation, structural geology, earthquake seismology, geodynamics, glaciology, materials science, and mineral physics will be invited to the conference. Thematic sessions will be organized on the dynamics of earthquake rupture, the rheology of the lower crust and coupling with the upper mantle, the measurement and interpretation of seismic attenuation and anisotropy, the dynamics of ice sheets and the coupling of reactive porous flow and brittle deformation for understanding geothermal and chemical properties of the shallow crust that are important for developing ideas in CO2 sequestration, geothermal and petrochemical research and the mechanics of shallow faults.

  14. Layered rocks beneath the Phanerozoic platform of the US midcontinent

    SciTech Connect (OSTI)

    Hauser, E.C. (Cornell Univ., Ithaca, NY (United States))

    1991-03-01

    A thick sequence of layered rocks lies hidden beneath the Phanerozoic cover of the central US over large regions. A thick sequence of Precambrian layered rocks in imaged on the COCORP transect across southern Illinois and Indiana. The thickness of this layered sequence varies from 1-3 times the thickness of the overlying Phanerozoic section of the Illinois basin. The layered sequence is observed for close to 200 km in an east-west direction. Similar layered reflections are seen on the COCORP data from Hardeman Co., TX, and neighboring southwest Oklahoma. Both of these known occurrences lie within the region of the middle Proterozoic Granite/Rhyolite province of the US midcontinent, an area within which scattered wells to basement commonly encounter 1.3-1.5 Ga undeformed granite and/or compositionally similar rhyolite. Therefore, these layered assemblages may comprise a thick sequence of silicic volcanic and sedimentary rocks (perhaps also injected by mafic sills) between scattered volcanic-intrusive centers, such as exposed in the St. Francois Mountains of southeast Missouri. However, in places such as Illinois and Indiana, the near absence of deep wells leaves the possibility that the upper portion of these layered rocks may locally be of late Proterozoic or earliest Paleozoic age. The reprocessing of available industry data, analyzed in conjunction with the existing COCORP data, includes extended vibroseis correlation. These industry data are invaluable in the author's effort to expand the known distribution of these layered rocks (e.g., into north-central Illinois) and to map their structures.

  15. Plastic cap evolution law derived from induced transverse isotropy in dilatational triaxial compression.

    SciTech Connect (OSTI)

    Macon, David James; Brannon, Rebecca Moss; Strack, Otto Eric

    2014-02-01

    Mechanical testing of porous materials generates physical data that contain contributions from more than one underlying physical phenomenon. All that is measurable is the (3z(Bensemble(3y (Bhardening modulus. This thesis is concerned with the phenomenon of dilatation in triaxial compression of porous media, which has been modeled very accurately in the literature for monotonic loading using models that predict dilatation under triaxial compression (TXC) by presuming that dilatation causes the cap to move outwards. These existing models, however, predict a counter-intuitive (and never validated) increase in hydrostatic compression strength. This work explores an alternative approach for modeling TXC dilatation based on allowing induced elastic anisotropy (which makes the material both less stiff and less strong in the lateral direction) with no increase in hydrostatic strength. Induced elastic anisotropy is introduced through the use of a distortion operator. This operator is a fourth-order tensor consisting of a combination of the undeformed stiffness and deformed compliance and has the same eigenprojectors as the elastic compliance. In the undeformed state, the distortion operator is equal to the fourth-order identity. Through the use of the distortion operator, an evolved stress tensor is introduced. When the evolved stress tensor is substituted into an isotropic yield function, a new anisotropic yield function results. In the case of the von Mises isotropic yield function (which contains only deviatoric components), it is shown that the distortion operator introduces a dilatational contribution without requiring an increase in hydrostatic strength. In the thesis, an introduction and literature review of the cap function is given. A transversely isotropic compliance is presented, based on a linear combination of natural bases constructed about a transverse-symmetry axis. Using a probabilistic distribution of cracks constructed for the case of transverse isotropy, a compliance expression is presented that demonstrated a decrease in lateral stiffness, but leaves axial stiffness unchanged. A demonstration of how the distortion operator could be used in the elastic/plastic analysis of a von Mises surface loaded in TXC is also presented.

  16. SU-E-T-59: Calculations of Collimator Scatter Factors (Sc) with and Without Custom-Made Build-Up Caps for CyberKnife

    SciTech Connect (OSTI)

    Wokoma, S; Yoon, J; Jung, J; Lee, S

    2014-06-01

    Purpose: To investigate the impact of custom-made build-up caps for a diode detector in robotic radiosurgery radiation fields with variable collimator (IRIS) for collimator scatter factor (Sc) calculation. Methods: An acrylic cap was custom-made to fit our SFD (IBA Dosimetry, Germany) diode detector. The cap has thickness of 5 cm, corresponding to a depth beyond electron contamination. IAEA phase space data was used for beam modeling and DOSRZnrc code was used to model the detector. The detector was positioned at 80 cm source-to-detector distance. Calculations were performed with the SFD, with and without the build-up cap, for clinical IRIS settings ranging from 7.5 to 60 mm. Results: The collimator scatter factors were calculated with and without 5 cm build-up cap. They were agreed within 3% difference except 15 mm cone. The Sc factor for 15 mm cone without buildup was 13.2% lower than that with buildup. Conclusion: Sc data is a critical component in advanced algorithms for treatment planning in order to calculate the dose accurately. After incorporating build-up cap, we discovered differences of up to 13.2 % in Sc factors in the SFD detector, when compared against in-air measurements without build-up caps.

  17. Kinetics of Cold-Cap Reactions for Vitrification of Nuclear Waste Glass Based on Simultaneous Differential Scanning Calorimetry - Thermogravimetry (DSC-TGA) and Evolved Gas Analysis (EGA)

    SciTech Connect (OSTI)

    Rodriguez, Carmen P.; Pierce, David A.; Schweiger, Michael J.; Kruger, Albert A.; Chun, Jaehun; Hrma, Pavel R.

    2013-12-03

    For vitrifying nuclear waste glass, the feed, a mixture of waste with glass-forming and modifying additives, is charged onto the cold cap that covers 90-100% of the melt surface. The cold cap consists of a layer of reacting molten glass floating on the surface of the melt in an all-electric, continuous glass melter. As the feed moves through the cold cap, it undergoes chemical reactions and phase transitions through which it is converted to molten glass that moves from the cold cap into the melt pool. The process involves a series of reactions that generate multiple gases and subsequent mass loss and foaming significantly influence the mass and heat transfers. The rate of glass melting, which is greatly influenced by mass and heat transfers, affects the vitrification process and the efficiency of the immobilization of nuclear waste. We studied the cold-cap reactions of a representative waste glass feed using both the simultaneous differential scanning calorimetry thermogravimetry (DSC-TGA) and the thermogravimetry coupled with gas chromatography-mass spectrometer (TGA-GC-MS) as complementary tools to perform evolved gas analysis (EGA). Analyses from DSC-TGA and EGA on the cold-cap reactions provide a key element for the development of an advanced cold-cap model. It also helps to formulate melter feeds for higher production rate.

  18. Search for underground openings for in situ test facilities in crystalline rock

    SciTech Connect (OSTI)

    Wollenberg, H.A.; Strisower, B.; Corrigan, D.J.; Graf, A.N.; O'Brien, M.T.; Pratt, H.; Board, M.; Hustrulid, W.

    1980-01-01

    With a few exceptions, crystalline rocks in this study were limited to plutonic rocks and medium to high-grade metamorphic rocks. Nearly 1700 underground mines, possibly occurring in crystalline rock, were initially identified. Application of criteria resulted in the identification of 60 potential sites. Within this number, 26 mines and 4 civil works were identified as having potential in that they fulfilled the criteria. Thirty other mines may have similar potential. Most of the mines identified are near the contact between a pluton and older sedimentary, volcanic and metamorphic rocks. However, some mines and the civil works are well within plutonic or metamorphic rock masses. Civil works, notably underground galleries associated with pumped storage hydroelectric facilities, are generally located in tectonically stable regions, in relatively homogeneous crystalline rock bodies. A program is recommended which would identify one or more sites where a concordance exists between geologic setting, company amenability, accessibility and facilities to conduct in situ tests in crystalline rock.

  19. Mechanical Behavior of the Near-field Host Rock Surrounding Excavation...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Mechanical Behavior of the Near-field Host Rock Surrounding Excavations Citation Details In-Document Search Title: Mechanical Behavior of the Near-field Host Rock ...

  20. Economics of a Conceptual 75 MW Hot Dry Rock Geothermal Electric...

    Open Energy Info (EERE)

    Economics of a Conceptual 75 MW Hot Dry Rock Geothermal Electric Power-Station Abstract Man-made, hot dry rock (HDR) geothermal energy reservoirs have been investigated for over...

  1. Rock-Water Interactions in the Fenton Hill, New Mexico, Hot Dry...

    Open Energy Info (EERE)

    to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Rock-Water Interactions in the Fenton Hill, New Mexico, Hot Dry Rock Geothermal Systems I. Fluid...

  2. Used Fuel Disposal in Crystalline Rocks: Status and FY14 Progress...

    Office of Scientific and Technical Information (OSTI)

    Used Fuel Disposal in Crystalline Rocks: Status and FY14 Progress. Citation Details In-Document Search Title: Used Fuel Disposal in Crystalline Rocks: Status and FY14 Progress. ...

  3. EIS-0471: Areva Eagle Rock Enrichment Facility in Bonneville County, ID |

    Office of Environmental Management (EM)

    Department of Energy 1: Areva Eagle Rock Enrichment Facility in Bonneville County, ID EIS-0471: Areva Eagle Rock Enrichment Facility in Bonneville County, ID May 20, 2011 delete me old download page duplicate

  4. Drilling Complete on Australian Hot Dry Rock Project | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Drilling Complete on Australian Hot Dry Rock Project Drilling Complete on Australian Hot Dry Rock Project January 23, 2008 - 4:37pm Addthis The first commercial attempt to create a commercial geothermal power plant using hot dry rock technology reached a crucial milestone on January 22, when a production well successfully reached its target depth. Hot dry rock technology was invented to draw energy from deep underground areas where geothermal heat is abundant, but no water exists to carry the

  5. DOE - Office of Legacy Management -- Slick Rock Mill Site - CO 08

    Office of Legacy Management (LM)

    Slick Rock Mill Site - CO 08 FUSRAP Considered Sites Site: Slick Rock Mill Site (CO.08) Designated Name: Alternate Name: Location: Evaluation Year: Site Operations: Site Disposition: Radioactive Materials Handled: Primary Radioactive Materials Handled: Radiological Survey(s): Site Status: Also see Slick Rock, Colorado, Processing Site Documents Related to Slick Rock Mill Site 2014 Annual Site Inspection and Monitoring Report for Uranium Mill Tailings Radiation Control Act Title I Disposal

  6. Panel discussion on rock mechanics issues in repository design

    SciTech Connect (OSTI)

    Bieniawski, Z.T.; Kim, K.S.; Nataraja, M.

    1996-04-01

    The panel discussion was introduced by Mr. Z.T.(Richard) Bieniawski and then continued with five additional speakers. The topics covered in the discussion included rock mechanics pertaining to the design of underground facilities for the disposal of radioactive wastes and the safety of such facilities. The speakers included: Mr. Kun-Soo Kim who is a specialist in the area of rock mechanics testing during the Basalt Waste Isolation Project; Dr. Mysore Nataraja who is the senior project manager with the NRC; Dr. Michael Voegele who is the project manager for Science Applications International Corporation (SAIC) on the Yucca Mountain Project; Dr. Edward Cording who is a member of the Nuclear Waste Technical Review Board; and Dr. Hemendra Kalia who is employed by Los Alamos National Laboratory and coordinates various activities of testing programs at the Yucca Mountain Site.

  7. Used Fuel Disposal in Crystalline Rocks. FY15 Progress Report

    SciTech Connect (OSTI)

    Wang, Yifeng

    2015-08-20

    The objective of the Crystalline Disposal R&D Work Package is to advance our understanding of long-term disposal of used fuel in crystalline rocks and to develop necessary experimental and computational capabilities to evaluate various disposal concepts in such media. Chapter headings are as follows: Fuel matrix degradation model and its integration with performance assessments, Investigation of thermal effects on the chemical behavior of clays, Investigation of uranium diffusion and retardation in bentonite, Long-term diffusion of U(VI) in bentonite: dependence on density, Sorption and desorption of plutonium by bentonite, Dissolution of plutonium intrinsic colloids in the presence of clay and as a function of temperature, Laboratory investigation of colloid-facilitated transport of cesium by bentonite colloids in a crystalline rock system, Development and demonstration of discrete fracture network model, Fracture continuum model and its comparison with discrete fracture network model.

  8. Rock Island Dam Smolt Monitoring; 1994-1995 Annual Report.

    SciTech Connect (OSTI)

    Truscott, Keith B.; Fielder, Paul C.

    1995-10-01

    Downstream migrating salmon and steelhead trout (Oncorhynchus spp.) smolts were monitored at the Rock Island Dam bypass trap from April 1 - August 31, 1954. This was the tenth consecutive year that the bypass trap was monitored. Data collected included: (1) number of fish caught by species, (2) number of adipose clipped and/or Passive Integrated Transponder (PIT) tagged fish caught by species, (3) daily average riverflow, (4) daily average powerhouse No. 1 and No. 2 flows and daily average spill. These data were transmitted to the Fish Passage Center, which manages the Smolt Monitoring Program throughout the Columbia River Basin. The Smolt Monitoring Program is used to manage the {open_quotes}water budget{close_quotes}, releasing upstream reservoir water storage allocated to supplement river flows to enhance survival of downstream migrating juvenile salmonids. The Rock Island Dam trapping facility collected 37,795 downstream migrating salmonids in 1994. Collected fish included 4 yearling and 4 sub-yearling chinook salmon (O. tshawytscha) that had been previously PIT tagged to help determine migration rates. Additionally, 1,132 sub-yearling chinook, 4,185 yearling chinook, 6,627 steelhead, (O. mykiss) and 422 sockeye (O. nerka) with clipped adipose fins were collected. The middle 80% of the 1994 spring migration (excluding sub-yearling chinooks) passed Rock Island Dam during a 34 day period, April 25 - May 28. Passage rates of chinook and steelhead smolts released from hatcheries and the downstream migration timing of all salmonids are presented. The spring migration timing of juvenile salmonids is strongly influenced by hatchery releases above Rock Island Dam.

  9. Fluid-Rock Characterization and Interactions in NMR Well Logging

    SciTech Connect (OSTI)

    Hirasaki, George J.; Mohanty, Kishore K.

    2003-02-10

    The objective of this project was to characterize the fluid properties and fluid-rock interactions that are needed for formation evaluation by NMR well logging. The advances made in the understanding of NMR fluid properties are summarized in a chapter written for an AAPG book on NMR well logging. This includes live oils, viscous oils, natural gas mixtures, and the relation between relaxation time and diffusivity.

  10. Fluid-Rock Characterization and Interactions in NMR Well Logging

    SciTech Connect (OSTI)

    Hirasaki, George J.; Mohanty, Kishore K.

    2003-02-10

    The objective of this project was to characterize the fluid properties and fluid-rock interactions which are needed for formation evaluation by NMR well logging. NMR well logging is finding wide use in formation evaluation. The formation parameters commonly estimated were porosity, permeability, and capillary bound water. Special cases include estimation of oil viscosity, residual oil saturation, location of oil/water contact, and interpretation on whether the hydrocarbon is oil or gas.

  11. Protected Polycrystalline Diamond Compact Bits For Hard Rock Drilling

    SciTech Connect (OSTI)

    Robert Lee Cardenas

    2000-10-31

    Two bits were designed. One bit was fabricated and tested at Terra-Tek's Drilling Research Laboratory. Fabrication of the second bit was not completed due to complications in fabrication and meeting scheduled test dates at the test facility. A conical bit was tested in a Carthage Marble (compressive strength 14,500 psi) and Sierra White Granite (compressive strength 28,200 psi). During the testing, Hydraulic Horsepower, Bit Weight, Rotation Rate, were varied for the Conical Bit, a Varel Tricone Bit and Varel PDC bit. The Conical Bi did cut rock at a reasonable rate in both rocks. Beneficial effects from the near and through cutter water nozzles were not evident in the marble due to test conditions and were not conclusive in the granite due to test conditions. At atmospheric drilling, the Conical Bit's penetration rate was as good as the standard PDC bit and better than the Tricone Bit. Torque requirements for the Conical Bit were higher than that required for the Standard Bits. Spudding the conical bit into the rock required some care to avoid overloading the nose cutters. The nose design should be evaluated to improve the bit's spudding characteristics.

  12. Chemical hydrofracturing of the Hot Dry Rock reservoir

    SciTech Connect (OSTI)

    Yakovlev, Leonid

    1996-01-24

    The experimental study of the water-rock interaction shows that the secondary mineral assemblage depends on the water composition. For example, granite-pure water interaction produces zeolites (relatively low-dense, Mg-poor minerals), whereas seawater yields chlorites (high-dense, Mg-rich minerals). The reactions have volumetric effects from several % to 20 % in magnitude. Volume deformations in the heterogeneous matrix cause uneven mechanical strains. Reactions with the effect of about 0,1 vol.% may cause strains of the order of 100-1000 bars being enough for destruction of rocks. Signs and magnitudes of local volume changes depend on the mineral composition of the secondary assemblage. Hence, one can provide either healing or cracking of primary fractures, as desired, by changing the composition of water in the water-felsic rock system where some elements (Mg, Fe) are in lack. The techniques of "chemical hydrofracturing" looks promising as applied to a granite HDR massif. One can regulate the permeability of fractured flow paths by changing in concord the composition and pressure of the injected water. This approach should promote efficient extraction of the petrothermal energy.

  13. Magnetic tunnel junctions for magnetic field sensor by using CoFeB sensing layer capped with MgO film

    SciTech Connect (OSTI)

    Takenaga, Takashi Tsuzaki, Yosuke; Yoshida, Chikako; Yamazaki, Yuichi; Hatada, Akiyoshi; Nakabayashi, Masaaki; Iba, Yoshihisa; Takahashi, Atsushi; Noshiro, Hideyuki; Tsunoda, Koji; Aoki, Masaki; Furukawa, Taisuke; Fukumoto, Hiroshi; Sugii, Toshihiro

    2014-05-07

    We evaluated MgO-based magnetic tunnel junctions (MTJs) for magnetic field sensors with spin-valve-type structures in the CoFeB sensing layer capped by an MgO film in order to obtain both top and bottom interfaces of MgO/CoFeB exhibiting interfacial perpendicular magnetic anisotropy (PMA). Hysteresis of the CoFeB sensing layer in these MTJs annealed at 275?°C was suppressed at a thickness of the sensing layer below 1.2?nm by interfacial PMA. We confirmed that the CoFeB sensing layers capped with MgO suppress the thickness dependences of both the magnetoresistance ratio and the magnetic behaviors of the CoFeB sensing layer more than that of the MTJ with a Ta capping layer. MgO-based MTJs with MgO capping layers can improve the controllability of the characteristics for magnetic field sensors.

  14. In situ capping for size control of monochalcogenides (ZnS, CdS, and SnS) nanocrystals produced by anaerobic metal-reducing bacteria

    SciTech Connect (OSTI)

    Jang, Gyoung Gug; Jacobs, Christopher B; Ivanov, Ilia N; Joshi, Pooran C; Meyer III, Harry M; Kidder, Michelle; Armstrong, Beth L; Datskos, Panos G; Graham, David E; Moon, Ji Won

    2015-01-01

    Metal monochalcogenide quantum dot nanocrystals of ZnS, CdS and SnS were prepared by anaerobic, metal-reducing bacteria using in situ capping by oleic acid or oleylamine. The capping agent preferentially adsorbs on the surface of the nanocrystal, suppressing the growth process in the early stages, thus leading to production of nanocrystals with a diameter of less than 5 nm.

  15. Simulation of water transport in heated rock salt

    SciTech Connect (OSTI)

    Schlich, M.; Jockwer, N.

    1986-01-01

    This paper summarizes computer simulation studies on water transport in German rock salt. Based on JOCKWERS experimental investigations on water content and water liberation, the object of these studies was to select a water transport model, that matches the water inflow which was measured in some heater experiments in the Asse Salt Mine. The main result is, that an evaporation front model, with Knudsen-type vapor transport combined with fluid transport by thermal expansion of the adsorbed water layers in the non evaporated zone, showed the best agreement with experimental evidence.

  16. SEISMIC AND ROCK PHYSICS DIAGNOSTICS OF MULTISCALE RESERVOIR TEXTURES

    SciTech Connect (OSTI)

    Gary Mavko

    2002-05-01

    As part of our study on ''Relationships between seismic properties and rock microstructure'', we have studied (1) How to quantify elastic properties of clay minerals using Atomic Force Acoustic Microscopy. We show how bulk modulus of clay can be measured using atomic force acoustic microscopy (AFAM) (2) We have successfully measured elastic properties of unconsolidated sediments in an effort to quantify attributes for detection of overpressures from seismic (3) We have initiated efforts for velocity upscaling to quantify long-wavelength and short-wavelength velocity behavior and the scale-dependent dispersion caused by sediment variability in different depositional environments.

  17. Source rock screening studies of Ordovician Maquoketa shale in western Illinois

    SciTech Connect (OSTI)

    Autrey, A.; Crockett, J.E.; Dickerson, D.R.; Oltz, D.F.; Seyler, B.J.; Warren, R.

    1987-09-01

    Rock-Eval (pyrolysis) studies of Ordovician Maquoketa Shale samples (cuttings and cores) from the shallow subsurface (500-800 ft deep) in western Illinois indicate that facies within the Maquoketa have potential as hydrocarbon source rocks. Dark, presumably organic-rich zones within the Maquoketa Shale were selected and analyzed for total organic carbon (TOC), Rock-Eval (pyrolysis), and bulk and clay mineralogy using x-ray diffraction. Preliminary results from six samples from Schuyler, McDonough, and Fulton Counties show TOC values ranging from 4.70% to as high as 12.90%. Rock-Eval parameters, measured by heating organic matter in an inert atmosphere, indicate source rock maturity and petroleum-generative potential. Screening studies, using the Rock-Eval process, describe very good source rock potential in facies of the Maquoketa Shale. Further studies at the Illinois State Geological Survey will expand on these preliminary results. This study complements a proposed exploration model in western Illinois and further suggests the possibility of source rocks on the flanks of the Illinois basin. Long-distance migration from more deeply buried effective source rocks in southern Illinois has been the traditional mechanism proposed for petroleum in basin-flank reservoirs. Localized source rocks can be an alternative to long-distance migration, and can expand the possibilities of basin-flank reservoirs, encouraging further exploration in these areas.

  18. Fluid-Rock Characterization and Interactions in NMR Well Logging

    SciTech Connect (OSTI)

    George J. Hirasaki; Kishore K. Mohanty

    2005-09-05

    The objective of this report is to characterize the fluid properties and fluid-rock interactions that are needed for formation evaluation by NMR well logging. The advances made in the understanding of NMR fluid properties are summarized in a chapter written for an AAPG book on NMR well logging. This includes live oils, viscous oils, natural gas mixtures, and the relation between relaxation time and diffusivity. Oil based drilling fluids can have an adverse effect on NMR well logging if it alters the wettability of the formation. The effect of various surfactants on wettability and surface relaxivity are evaluated for silica sand. The relation between the relaxation time and diffusivity distinguishes the response of brine, oil, and gas in a NMR well log. A new NMR pulse sequence in the presence of a field gradient and a new inversion technique enables the T{sub 2} and diffusivity distributions to be displayed as a two-dimensional map. The objectives of pore morphology and rock characterization are to identify vug connectivity by using X-ray CT scan, and to improve NMR permeability correlation. Improved estimation of permeability from NMR response is possible by using estimated tortuosity as a parameter to interpolate between two existing permeability models.

  19. Fluid-Rock Characterization and Interactions in NMR Well Logging

    SciTech Connect (OSTI)

    Hirasaki, George J.; Mohanty, Kishore, K.

    2001-07-13

    The objective of this project is to characterize the fluid properties and fluid-rock interactions that are needed for formation evaluation by NMR well logging. This is the first annual progress report submitted to the DOE. It reports on the work completed during the reporting period even if it may have started before this period. This project is a partnership between Professor George J. Hirasaki at Rice University and Professor Kishore Mohanty at University of Houston. In addition to the DOE, this project is supported by a consortium of oil companies and service companies. The fluid properties characterization has emphasized the departure of live oils from correlations based on dead oils. Also, asphaltic components can result in a difference between the T1 and T2 relaxation time distributions as well as reduce the hydrogen index. The fluid rock characterizations that are reported here are the effects of wettability and internal magnetic field gradients. A pore reconstruction method ha s been developed to recreate three-dimensional porous media from two-dimensional images that reproduce some of their key statistical properties. A Monte Carlo simulation technique has been developed to calculate the magnetization decay in fluid saturated porous media given their pore structure.

  20. Design methodology for rock excavations at the Yucca Mountain project

    SciTech Connect (OSTI)

    Alber, M.; Bieniawski, Z.T.

    1993-12-31

    The problems involved in the design of the proposed underground repository for high-level nuclear waste call for novel design approaches. Guidelines for the design are given by the Mission Plan Amendment in which licensing and regulatory aspects have to be satisfied. Moreover, systems engineering was proposed, advocating a top-down approach leading to the identification of discrete, implementable system elements. These objectives for the design process can be integrated in an engineering design methodology. While design methodologies for some engineering disciplines are available, they were of limited use for rock engineering because of the inherent uncertainties about the geologic media. Based on the axiomatic design approach of Suh, Bieniawski developed a methodology for design in rock. Design principles and design stages are clearly stated to assist in effective decision making. For overall performance goals, the domain of objectives is defined through components (DCs) - representing a design solution - satisfy the FRs, resulting in discrete, independent functional relations. Implementation is satisfied by evaluation and optimization of the design with respect to the constructibility of the design components.

  1. ChemCam rock laser for Mars Science Laboratory "Curiosity"

    ScienceCinema (OSTI)

    Wiens, Roger

    2014-08-12

    Los Alamos has a long history of space-related instruments, tied primarily to its role in defense-related treaty verification. Space-based detectors have helped determine the differences between signals from lightning bolts and potential nuclear explosions. LANL-developed gamma-ray detection instruments first revealed the existence of what we now know as gamma-ray bursts, an exciting area of astrophysical research. And the use of LANL instruments on varied space missions continues with such products as the ChemCam rock laser for NASA, shown here. The Engineering Model of the ChemCam Mars Science Laboratory rover instrument arrived at NASA's Jet Propulsion Laboratory on February 6, 2008. The Flight Model was shipped in August, 2010 for installation on the rover at JPL. ChemCam will use imaging and laser-induced breakdown spectroscopy (LIBS) to determine rock and soil compositions on Mars, up to 9 meters from the rover. The engineering model is being integrated into the rover test bed for the development and testing of the rover software. The actual flight model components were concurrently assembled at Los Alamos and in Toulouse, France. The Mars Science Laboratory is scheduled to launch in 2011. Animations courtesy of JPL/NASA.

  2. ChemCam Rock Laser for the Mars Science Laboratory

    ScienceCinema (OSTI)

    LANL

    2009-09-01

    Los Alamos has a long history of space-related instr... Los Alamos has a long history of space-related instruments, tied primarily to its role in defense-related treaty verification. Space-based detectors have helped determine the differences between signals from lightning bolts and potential nuclear explosions. LANL-developed gamma-ray detection instruments first revealed the existence of what we now know as gamma-ray bursts, an exciting area of astrophysical research. And the use of LANL instruments on varied space missions continues with such products as the ChemCam rock laser for NASA, shown here. The Engineering Model of the ChemCam Mars Science Laboratory rover instrument arrived at NASA's Jet Propulsion Laboratory on February 6, 2008. ChemCam will use imaging and laser-induced breakdown spectroscopy (LIBS) to determine rock and soil compositions on Mars, up to 9 meters from the rover. The engineering model is being integrated into the rover test bed for the development and testing of the rover software. The actual flight model components are concurrently being assembled at Los Alamos and in Toulouse, France, and will be delivered to JPL in July. The Mars Science Laboratory is scheduled to launch in 2009. Animations courtesy of JPL/NASA.

  3. Micromachined low frequency rocking accelerometer with capacitive pickoff

    DOE Patents [OSTI]

    Lee, Abraham P.; Simon, Jonathon N.; McConaghy, Charles F.

    2001-01-01

    A micro electro mechanical sensor that uses capacitive readout electronics. The sensor involves a micromachined low frequency rocking accelerometer with capacitive pickoff fabricated by deep reactive ion etching. The accelerometer includes a central silicon proof mass, is suspended by a thin polysilicon tether, and has a moving electrode (capacitor plate or interdigitated fingers) located at each end the proof mass. During movement (acceleration), the tethered mass moves relative to the surrounding packaging, for example, and this defection is measured capacitively by a plate capacitor or interdigitated finger capacitor, having the cooperating fixed electrode (capacitor plate or interdigitated fingers) positioned on the packaging, for example. The micromachined rocking accelerometer has a low frequency (<500 Hz), high sensitivity (.mu.G), with minimal power usage. The capacitors are connected to a power supply (battery) and to sensor interface electronics, which may include an analog to digital (A/D) converter, logic, RF communication link, antenna, etc. The sensor (accelerometer) may be, for example, packaged along with the interface electronics and a communication system in a 2".times.2".times.2" cube. The proof mass may be asymmetric or symmetric. Additional actuating capacitive plates may be used for feedback control which gives a greater dynamic range.

  4. Method and apparatus for determining two-phase flow in rock fracture

    DOE Patents [OSTI]

    Persoff, Peter (Oakland, CA); Pruess, Karsten (Berkeley, CA); Myer, Larry (Benicia, CA)

    1994-01-01

    An improved method and apparatus as disclosed for measuring the permeability of multiple phases through a rock fracture. The improvement in the method comprises delivering the respective phases through manifolds to uniformly deliver and collect the respective phases to and from opposite edges of the rock fracture in a distributed manner across the edge of the fracture. The improved apparatus comprises first and second manifolds comprising bores extending within porous blocks parallel to the rock fracture for distributing and collecting the wetting phase to and from surfaces of the porous blocks, which respectively face the opposite edges of the rock fracture. The improved apparatus further comprises other manifolds in the form of plenums located adjacent the respective porous blocks for uniform delivery of the non-wetting phase to parallel grooves disposed on the respective surfaces of the porous blocks facing the opposite edges of the rock fracture and generally perpendicular to the rock fracture.

  5. EGS rock reactions with Supercritical CO2 saturated with water and water

    Office of Scientific and Technical Information (OSTI)

    saturated with Supercritical CO2 (Conference) | SciTech Connect Conference: EGS rock reactions with Supercritical CO2 saturated with water and water saturated with Supercritical CO2 Citation Details In-Document Search Title: EGS rock reactions with Supercritical CO2 saturated with water and water saturated with Supercritical CO2 EGS using CO2 as a working fluid will likely involve hydro-shearing low-permeability hot rock reservoirs with a water solution. After that process, the fractures

  6. R & D Supercritiacl CO2/ Rock Chemicals Interactions | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    R & D Supercritiacl CO2/ Rock Chemicals Interactions R & D Supercritiacl CO2/ Rock Chemicals Interactions R & D Supercritiacl CO2/ Rock Chemicals Interactions presentation at the April 2013 peer review meeting held in Denver, Colorado. PDF icon university_of_minnesota_peer2013.pdf More Documents & Publications An integrated experimental and numerical study: Developing a reaction transport model that couples chemical reactions of mineral dissolution/precipitation with spatial and

  7. EA-1987: Parker-Headgate Rock and Parker-Bouse Rebuild Project, Arizona and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    California | Department of Energy 87: Parker-Headgate Rock and Parker-Bouse Rebuild Project, Arizona and California EA-1987: Parker-Headgate Rock and Parker-Bouse Rebuild Project, Arizona and California SUMMARY DOE's Western Area Power Administration is preparing an EA that will assess the potential environmental impacts of a proposal to rebuild the existing Parker Dam-Headgate Rock and Parker Dam-Bouse 161-kilovolt transmission lines along the Colorado River in western Arizona and eastern

  8. Standing Rock Sioux Tribe - Lakota/Dakota Nation: Establishment of Renewable Energy & Energy Development Office

    Energy Savers [EERE]

    8540 fwasinzi@standingrock.org Establishment of Renewable Energy & Energy Development Office Standing Rock Sioux Tribe - Lakota/Dakota Nation OVERVIEW: BACKGROUND INFORMATION ON STANDING ROCK RESERVATION SITTING BULL COLLEGE WIND TURBINE EECBG ENERGY EFFICIENCY & WIND TURBINE INSTALLATION AT SITTING BULL COLLEGE WIND ASSESSMENT STUDY ESTABLISHMENT OF RENEWABLE ENERGY & ENERGY DEVELOPMENT OFFICE (REEDO) STANDING ROCK ONE OF SEVEN RESERVATIONS OF THE GREAT SIOUX NATION LOCATED IN

  9. Rock the Watt: An Energy Conservation Campaign at Pacific Northwest National Lab

    Energy Savers [EERE]

    Rock the Watt was a direct applica- tion of the Framework for Organiza- tional Change that included building sustainability champions, integration of a sustainability checklist, and sup- port for employees to come up with their own energy saving actions. Rock the Watt: An Energy Conservation Campaign at Pacific Northwest National Lab Pacifc Northwest National Laboratory (PNNL), one of the seventeen Department of Energy laboratories, implemented the 3-month Rock the Watt campaign in FY2015 to

  10. Evaluation Of Used Fuel Disposition In Clay-Bearing Rock | Department of

    Office of Environmental Management (EM)

    Energy Of Used Fuel Disposition In Clay-Bearing Rock Evaluation Of Used Fuel Disposition In Clay-Bearing Rock Radioactive waste disposal in shale/argillite rock formations has been widely considered given its desirable isolation properties, e.g., low permeability, potential geochemically reduced conditions, anomalous groundwater pressures, and widespread geologic occurrence. This report describes various R&D activities applicable to shale/argillite media (e.g., progress made on modeling

  11. Using presence of calcite cap rock in shales to predict occurrence of reservoirs composed of leached secondary porosity in the geopressured zone. Annual report, June 1, 1980-October 31, 1980

    SciTech Connect (OSTI)

    Kaiser, W.R.; Magara, K.; Milliken, K.L.; Richmann, D.L.

    1981-01-01

    The distribution of high-resistivity shale in the Frio Formation between hydropressured and geopressured strata has been mapped along the Texas Gulf Coast. Two high-resistivity intervals more than 1000 ft thick have been mapped, one in Brazoria and Galveston Counties and the other in Kenedy County. They coincide with Frio delta systems and may be related to extraordinary quantities of CO/sub 2/ produced by deltaic sediments rich in woody and herbaceous matter. Beyond being calcareous, the nature of the high-resistivity interval is enigmatic and its relationship to deep secondary porosity problematic. Most of the contained carbonate is microscopically and isotopically skeletal in origin, revealing no evidence of diagenetic modification. Minor rhombs of iron-bearing carbonate tens of microns in size were identified. Detrital feldspar compositions are being established to test subsequent changes in feldspar composition resulting from progressive burial and albitization. Hydrolysis reactions for authigenic minerals and reactions between key pairs of minerals have been written. Thermodynamic functions for complex phyllosilicates at temperatures up to 200/sup 0/C have been calculated. From thermodynamic calculations it was predicted that ferroan calcite would be the favored authigenic carbonate in shales.

  12. Summary of Rock-Property Measurements for Hong Kong TuffSamples

    SciTech Connect (OSTI)

    Dobson, Patrick F.; Nakagawa, Seiji

    2005-09-21

    A series of rock-property measurements was performed on a suite of rhyolitic tuff samples from the area above the Aberdeen Tunnel of Hong Kong. The goal of this study was to determine the mechanical properties of these samples after weathering. This report contains petrographic descriptions, porosity, bulk and grain density, as well as ultrasonic measurements, elastic modulii calculations, and rock-strength determinations. Variations in rock properties are related to alteration and the presence of fractures in the tuff. Granitic rocks located adjacent to the altered tuffs would be better candidates for underground excavations.

  13. Rock-Water Interactions in the Fenton Hill, New Mexico, Hot Dry...

    Open Energy Info (EERE)

    Rock Geothermal Systems II. Modeling Geochemical Behavior Abstract A transient mass balance model is developed to account for the dynamic behavior of an artificially stimulated...

  14. The US Hot Dry Rock Program-20 Years of Experience in Reservoir...

    Open Energy Info (EERE)

    The US Hot Dry Rock Program-20 Years of Experience in Reservoir Testing Author Donald Brown Conference World Geothermal Congress; Florence, Italy; 19950101 Published...

  15. Rock Sampling At Mt Ranier Area (Frank, 1995) | Open Energy Informatio...

    Open Energy Info (EERE)

    Exploration Activity Details Location Mt Ranier Area Exploration Technique Rock Sampling Activity Date Usefulness not indicated DOE-funding Unknown Notes This paper relies...

  16. Rock Density At Silver Peak Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Rock Density At Silver Peak Area (DOE GTP) Exploration Activity Details Location Silver Peak Area...

  17. A Sr-Isotopic Comparison Between Thermal Waters, Rocks, And Hydrotherm...

    Open Energy Info (EERE)

    through the isotopically lighter volcanic rocks of the caldera fill. Authors Fraser Goff, Harold A. Wollenberg, D. C. Brookins and Ronald W. Kistler Published Journal Journal...

  18. Rock the Watt: An Energy Conservation Campaign at Pacific Northwest National Lab

    Broader source: Energy.gov [DOE]

    Case study describes Pacific Northwest National Laboratory's three-month Rock the Watt campaign to reduce energy use at its main campus in Richland, Washington.

  19. Rock Sampling At Blue Mountain Geothermal Area (U.S. Geological...

    Open Energy Info (EERE)

    collected included: geographic coordinates, rock type, magnetic susceptibility, and density. References US Geological Survey (2012) Geophysical Studies in the Vicinity of Blue...

  20. Rock Sampling At Seven Mile Hole Area (Larson, Et Al., 2009)...

    Open Energy Info (EERE)

    Seven Mile Hole Area (Larson, Et Al., 2009) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Rock Sampling At Seven Mile Hole Area (Larson, Et...

  1. Rock Sampling At San Juan Volcanic Field Area (Larson & Jr, 1986...

    Open Energy Info (EERE)

    Juan Volcanic Field Area (Larson & Jr, 1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Rock Sampling At San Juan Volcanic Field Area...

  2. Hydrologic test system for fracture flow studies in crystalline rock

    SciTech Connect (OSTI)

    Raber, E; Lord, D.; Burklund, P.

    1982-05-05

    A hydrologic test system has been designed to measure the intrinsic permeabilities of individual fractures in crystalline rock. This system is used to conduct constant pressure-declining flow rate and pressure pulse hydraulic tests. The system is composed of four distinct units: (1) the Packer System, (2) Injection system, (3) Collection System, and (4) Electronic Data Acquisition System. The apparatus is built in modules so it can be easily transported and re-assembled. It is also designed to operate over a wide range of pressures (0 to 300 psig) and flow rates (0.2 to 1.0 gal/min). This system has proved extremely effective and versatile in its use at the Climax Facility, Nevada Test Site.

  3. Method and apparatus for water jet drilling of rock

    DOE Patents [OSTI]

    Summers, David A.; Mazurkiewicz, Marian; Bushnell, Dwight J.; Blaine, James

    1978-01-01

    Rock drilling method and apparatus utilizing high pressure water jets for drilling holes of relatively small diameter at speeds significantly greater than that attainable with existing drilling tools. Greatly increased drilling rates are attained due to jet nozzle geometry and speed of rotation. The jet nozzle design has two orifices, one pointing axially ahead in the direction of travel and the second inclined at an angle of approximately 30.degree. from the axis. The two orifices have diameters in the ratio of approximately 1:2. Liquid jet velocities in excess of 1,000 ft/sec are used, and the nozzle is rotated at speeds up to 1,000 rpm and higher.

  4. Saturated Zone Plumes in Volcanic Rock: Implications for Yucca Mountain

    SciTech Connect (OSTI)

    S. Kelkar; R. Roback; B. Robinson; G. Srinivasan; C. Jones; P. Reimus

    2006-02-14

    This paper presents a literature survey of the occurrences of radionuclide plumes in saturated, fractured rocks. Three sites, Idaho National laboratory, Hanford, and Oak Ridge are discussed in detail. Results of a modeling study are also presented showing that the length to width ratio of a plume starting within the repository footprint at the Yucca Mountain Project site, decreases from about 20:1 for the base case to about 4:1 for a higher value of transverse dispersivity, indicating enhanced lateral spreading of the plume. Due to the definition of regulatory requirements, this lateral spreading does not directly impact breakthrough curves at the 18 km compliance boundary, however it increases the potential that a plume will encounter reducing conditions, thus significantly retarding the transport of sorbing radionuclides.

  5. Spatial statistics for predicting flow through a rock fracture

    SciTech Connect (OSTI)

    Coakley, K.J.

    1989-03-01

    Fluid flow through a single rock fracture depends on the shape of the space between the upper and lower pieces of rock which define the fracture. In this thesis, the normalized flow through a fracture, i.e. the equivalent permeability of a fracture, is predicted in terms of spatial statistics computed from the arrangement of voids, i.e. open spaces, and contact areas within the fracture. Patterns of voids and contact areas, with complexity typical of experimental data, are simulated by clipping a correlated Gaussian process defined on a N by N pixel square region. The voids have constant aperture; the distance between the upper and lower surfaces which define the fracture is either zero or a constant. Local flow is assumed to be proportional to local aperture cubed times local pressure gradient. The flow through a pattern of voids and contact areas is solved using a finite-difference method. After solving for the flow through simulated 10 by 10 by 30 pixel patterns of voids and contact areas, a model to predict equivalent permeability is developed. The first model is for patterns with 80% voids where all voids have the same aperture. The equivalent permeability of a pattern is predicted in terms of spatial statistics computed from the arrangement of voids and contact areas within the pattern. Four spatial statistics are examined. The change point statistic measures how often adjacent pixel alternate from void to contact area (or vice versa ) in the rows of the patterns which are parallel to the overall flow direction. 37 refs., 66 figs., 41 tabs.

  6. Uranium and thorium decay series disequilibria in young volcanic rocks

    SciTech Connect (OSTI)

    Williams, R.W.

    1988-01-01

    Two of the central questions in igneous geochemistry that study of radioactive disequilibria can help to answer are: what are the rates of magma genesis; and what are the timescales of magma separation and transport. In addition to the temporal information that may be extracted from disequilibria data, the {sup 230}Th/{sup 232}Th of a young rock may be used as a tracer of the Th/U ratio of its source region. Measurements were made by isotope dilution alpha-spectrometry of {sup 238}U, {sup 234}U, {sup 230}Th, and {sup 232}Th in 20 subduction related, 3 oceanic intraplate, and 10 continental intraplate volcanics. {sup 210}Pb was measured in all, {sup 226}Ra was measured in about half, and {sup 228}Th was measured in 10 of the most recent samples. Disequilibrium between {sup 228}Th and {sup 232}Th was found only in the Nacarbonatite samples from Oldoinyo Lengai volcano in Tanzania, which is attributable to {sup 228}Ra/{sup 232}Th {approximately} 27 at the time of eruption. These rocks also have {sup 226}Ra/{sup 230}Th > 60. Three Ra-enrichment models are developed which constrain carbonatite magma formation at less than 20 years before eruption. The effects of different partial melting processes on the {sup 238}U decay series are investigated. If mid-ocean ridge basalts are formed by a dynamic melting process, the {sup 230}Th/{sup 232}Th of the basalts provides a minimum estimate of the Th/U ratio of the source region. The {sup 238}U enrichment in arc volcanics is probably the results of metasomatism of the source by fluids derived from the subducting slab, and the {sup 230}Th enrichment observed for other volcanics is probably due to the partial melting process in the absence of U-bearing fluids.

  7. Internal attachment of laser beam welded stainless steel sheathed thermocouples into stainless steel upper end caps in nuclear fuel rods for the LOFT Reactor

    SciTech Connect (OSTI)

    Welty, R.K.; Reid, R.D.

    1980-01-01

    The Exxon Nuclear Company, Inc., acting as a subcontractor to EG and G Idaho Inc., Idaho National Engineering Laboratory, Idaho Falls, Idaho, conducted a laser beam welding study to attach internal stainless steel thermocouples into stainless steel upper end caps in nuclear fuel rods. The objective of this study was to determine the feasibility of laser welding a single 0.063 inch diameter stainless steel (304) sheathed thermocouple into a stainless steel (316) upper end cap for nuclear fuel rods. A laser beam was selected because of the extremely high energy input in unit volume that can be achieved allowing local fusion of a small area irrespective of the difference in material thickness to be joined. A special weld fixture was designed and fabricated to hold the end cap and the thermocouple with angular and rotational adjustment under the laser beam. A commercial pulsed laser and energy control system was used to make the welds.

  8. Nondestructive and automated testing for soil and rock properties. ASTM special technical publication 1350

    SciTech Connect (OSTI)

    Marr, W.A.; Fairhurst, C.E.

    1999-07-01

    The purpose of the symposium was to highlight recent developments in nondestructive and automated testing for soil and rock properties. Speakers present results of recent research in these areas that have practical application for the rapid and economical testing of soil and rock. Authors were encouraged to identify which testing equipment and methods have sufficient practical application to warrant standards development.

  9. Final Report. Geothermal Dual Acoustic Tool for Measurement of Rock Stress

    SciTech Connect (OSTI)

    Normann, Randy A

    2014-12-01

    This paper outlines the technology need for a rock formation stress measurement in future EGS wells. This paper reports on the results of work undertaken under a Phase I, DOE/SBIR on the feasibility to build an acoustic well logging tool for measuring rock formation stress.

  10. Final Report: Geothermal Dual Acoustic Tool for Measurement of Rock Stress

    SciTech Connect (OSTI)

    Normann, Randy A.

    2014-12-01

    This paper outlines the technology need for a rock formation stress measurement in future EGS wells. This paper reports on the results of work undertaken under a Phase I, DOE/SBIR on the feasibility to build an acoustic well logging tool for measuring rock formation stress.

  11. PROJECT-SPECIFIC TYPE A VERIFICATION FOR THE BROOKHAVEN GRAPHITE RESEARCH REACTOR ENGINEERED CAP, BROOKHAVEN NATIONAL LABORATORY UPTON, NEW YORK DCN 5098-SR-07-0

    SciTech Connect (OSTI)

    Evan Harpenau

    2011-07-15

    The Oak Ridge Institute for Science and Education (ORISE) has reviewed the project documentation and data for the Brookhaven Graphite Research Reactor (BGRR) Engineered Cap at Brookhaven National Laboratory (BNL) in Upton, New York. The Brookhaven Science Associates (BSA) have completed removal of affected soils and performed as-left surveys by BSA associated with the BGRR Engineered Cap. Sample results have been submitted, as required, to demonstrate that remediation efforts comply with the cleanup goal of {approx}15 mrem/yr above background to a resident in 50 years (BNL 2011a).

  12. Numerical simulation of fracture rocks and wave propagation by means of fractal theory

    SciTech Connect (OSTI)

    Valle G., R. del

    1994-12-31

    A numerical approach was developed for the dynamic simulation of fracture rocks and wave propagation. Based on some ideas of percolation theory and fractal growth, a network of particles and strings represent the rock model. To simulate an inhomogeneous medium, the particles and springs have random distributed elastic parameters and are implemented in the dynamic Navier equation. Some of the springs snap with criteria based on the confined stress applied, therefore creating a fractured rock consistent with the physical environment. The basic purpose of this research was to provide a method to construct a fractured rock with confined stress conditions as well as the wave propagation imposed in the model. Such models provide a better understanding of the behavior of wave propagation in fractured media. The synthetic seismic data obtained henceforth, can be used as a tool to develop methods for characterizing fractured rocks by means of geophysical inference.

  13. Evaluation of Used Fuel Disposition in Clay-Bearing Rock

    SciTech Connect (OSTI)

    Jové Colón, Carlos F.; Weck, Philippe F.; Sassani, David H.; Zheng, Liange; Rutqvist, Jonny; Steefel, Carl I.; Kim, Kunhwi; Nakagawa, Seiji; Houseworth, James; Birkholzer, Jens; Caporuscio, Florie A.; Cheshire, Michael; Rearick, Michael S.; McCarney, Mary K.; Zavarin, Mavrik; Benedicto, Ana; Kersting, Annie B.; Sutton, Mark; Jerden, James; Frey, Kurt E.; Copple, Jacqueline M.; Ebert, William

    2014-08-29

    Radioactive waste disposal in shale/argillite rock formations has been widely considered given its desirable isolation properties (low permeability), geochemically reduced conditions, anomalous groundwater pressures, and widespread geologic occurrence. Clay/shale rock formations are characterized by their high content of clay minerals such as smectites and illites where diffusive transport and chemisorption phenomena predominate. These, in addition to low permeability, are key attributes of shale to impede radionuclide mobility. Shale host-media has been comprehensively studied in international nuclear waste repository programs as part of underground research laboratories (URLs) programs in Switzerland, France, Belgium, and Japan. These investigations, in some cases a decade or more long, have produced a large but fundamental body of information spanning from site characterization data (geological, hydrogeological, geochemical, geomechanical) to controlled experiments on the engineered barrier system (EBS) (barrier clay and seals materials). Evaluation of nuclear waste disposal in shale formations in the USA was conducted in the late 70’s and mid 80’s. Most of these studies evaluated the potential for shale to host a nuclear waste repository but not at the programmatic level of URLs in international repository programs. This report covers various R&D work and capabilities relevant to disposal of heat-generating nuclear waste in shale/argillite media. Integration and cross-fertilization of these capabilities will be utilized in the development and implementation of the shale/argillite reference case planned for FY15. Disposal R&D activities under the UFDC in the past few years have produced state-of-the-art modeling capabilities for coupled Thermal-Hydrological-Mechanical-Chemical (THMC), used fuel degradation (source term), and thermodynamic modeling and database development to evaluate generic disposal concepts. The THMC models have been developed for shale repository leveraging in large part on the information garnered in URLs and laboratory data to test and demonstrate model prediction capability and to accurately represent behavior of the EBS and the natural (barrier) system (NS). In addition, experimental work to improve our understanding of clay barrier interactions and TM couplings at high temperatures are key to evaluate thermal effects as a result of relatively high heat loads from waste and the extent of sacrificial zones in the EBS. To assess the latter, experiments and modeling approaches have provided important information on the stability and fate of barrier materials under high heat loads. This information is central to the assessment of thermal limits and the implementation of the reference case when constraining EBS properties and the repository layout (e.g., waste package and drift spacing). This report is comprised of various parts, each one describing various R&D activities applicable to shale/argillite media. For example, progress made on modeling and experimental approaches to analyze physical and chemical interactions affecting clay in the EBS, NS, and used nuclear fuel (source term) in support of R&D objectives. It also describes the development of a reference case for shale/argillite media. The accomplishments of these activities are summarized as follows: Development of a reference case for shale/argillite; Investigation of Reactive Transport and Coupled THM Processes in EBS: FY14; Update on Experimental Activities on Buffer/Backfill Interactions at elevated Pressure and Temperature; and Thermodynamic Database Development: Evaluation Strategy, Modeling Tools, First-Principles Modeling of Clay, and Sorption Database Assessment;ANL Mixed Potential Model For Used Fuel Degradation: Application to Argillite and Crystalline Rock Environments.

  14. Hot dry rock geothermal energy. Draft final report

    SciTech Connect (OSTI)

    Not Available

    1994-09-01

    This second EPRI workshop on hot dry rock (HDR) geothermal energy, held in May 1994, focused on the status of worldwide HDR research and development and used that status review as the starting point for discussions of what could and should be done next: by U.S. federal government, by U.S. industry, by U.S. state governments, and by international organizations or through international agreements. The papers presented and the discussion that took place indicate that there is a community of researchers and industrial partners that could join forces, with government support, to begin a new effort on hot dry rock geothermal development. This new heat mining effort would start with site selection and confirmatory studies, done concurrently. The confirmatory studies would test past evaluations against the most current results (from the U.S. site at Fenton Hill, New Mexico, and from the two sites in Japan, the one in Russia, and the two in western Europe) and the best models of relevant physical and economic aspects. Site selection would be done in the light of the confirmatory studies and would be influenced by the need to find a site where success is probable and which is representative enough of other sites so that its success would imply good prospects for success at numerous other sites. The test of success would be circulation between a pair of wells, or more wells, in a way that confirmed, with the help of flow modeling, that a multi-well system would yield temperatures, flows and lifetimes that support economically feasible power generation. The flow modeling would have to have previously achieved its own confirmation from relevant data taken from both heat mining and conventional hydrothermal geothermal experience. There may be very relevant experience from the enhancement of ''hot wet rock'' sites, i.e., sites where hydrothermal reservoirs lack, or have come to lack, enough natural water or steam and are helped by water injected cold and produced hot. The new site would have to be selected in parallel with the confirmatory studies because it would have to be modeled as part of the studies and because its similarity to other candidate sites must be known well enough to assure that results at the selected site are relevant to many others. Also, the industry partners in the joint effort at the new site must be part of the confirmatory studies, because they must be convinced of the economic feasibility. This meeting may have brought together the core of people who can make such a joint effort take place. EPRI sponsored the organization of this meeting in order to provide utilities with an update on the prospects for power generation via heat mining. Although the emerging rules for electric utilities competing in power generation make it very unlikely that the rate-payers of any one utility (or small group of utilities) can pay the differential to support this new heat mining research and development effort, the community represented at this meeting may be able to make the case for national or international support of a new heat mining effort, based on the potential size and economics of this resource as a benefit for the nation as a whole and as a contribution to reduced emissions of fossil CO{sub 2} worldwide.

  15. Rock drilling bit and a method of producing the same

    SciTech Connect (OSTI)

    Kane, R.F.; Portugal, J.J.; Kuzniar, P.S.

    1989-09-19

    This patent describes a method for forming a drill bit of the type used for drilling rock and including a drill bit body defining a cutting face having a plurality of hard material cutting inserts mounted in openings formed in the cutting face. The method comprising the steps of: providing a drill bit body formed from a steel capable of being carburized, the body having a cutting face surface; identifying on the cutting face surface those locations wherein insert mounting openings are needed; covering each location with a material capable of preventing penetration of carbon into the bit body in the area of the location during carburizing, the area covered at each such location being at least slightly greater that the size of the insert mounting opening needed; with the insert mounting locations covered, carburizing and heat treating the bit body to case harden the cutting face to a hardness above 50 on the Rockwell C scale; and thereafter, drilling an insert receiving opening at each location and press-fitting hard material cutting inserts into each such opening.

  16. Hot-dry-rock energy: review of environmental aspects

    SciTech Connect (OSTI)

    O'Banion, K.

    1981-10-13

    The potential environmental and socioeconomic impacts of the production of energy contained in hot dry rock (HDR) is surveyed here. In general, careful siting and timing and routine control measures should be adequate to prevent significant environmental harm; sites of particular ecological or visual and recreational value, however, may require more extensive (and more expensive) precautions such as using multiwell pads to reduce land disturbance and dry or wet and dry cooling towers to reduce or eliminate the consumptive use of water. The most important uncertainty among the environmental concerns is the seismic response of HDR formations to short-duration fluid injections at pressures above fracture thresholds; continued monitoring at HDR development sites is necessary. The direct socioeconomic impacts of HDR development should be relatively minor, owing to its capital-intensive nature. Of greater potential importance are the indirect jobs resulting from such development, which could cause significant demographic (and thus fiscal and social) impacts in sparsely populated regions. However, such indirect growth is not expected to begin until a large, stable HDR industry is established in a region, and thus its impacts are expected to be permanent rather than transient.

  17. Assessment of industrial minerals and rocks in the controlled area

    SciTech Connect (OSTI)

    Castor, S.B.; Lock, D.E.

    1996-08-01

    Yucca Mountain in Nye County, Nevada, is a potential site for a permanent repository for high-level nuclear waste in Miocene ash flow tuff. The Yucca Mountain controlled area occupies approximately 98 km{sup 2} that includes the potential repository site. The Yucca Mountain controlled area is located within the southwestern Nevada volcanic field, a large area of Miocene volcanism that includes at least four major calderas or cauldrons. It is sited on a remnant of a Neogene volcanic plateau that was centered around the Timber Mountain caldera complex. The Yucca Mountain region contains many occurrences of valuable or potentially valuable industrial minerals, including deposits with past or current production of construction aggregate, borate minerals, clay, building stone, fluorspar, silicate, and zeolites. The existence of these deposits in the region and the occurrence of certain mineral materials at Yucca Mountain, indicate that the controlled area may have potential for industrial mineral and rock deposits. Consideration of the industrial mineral potential within the Yucca Mountain controlled area is mainly based on petrographic and lithologic studies of samples from drill holes in Yucca Mountain. Clay minerals, zeolites, fluorite, and barite, as minerals that are produced economically in Nevada, have been identified in samples from drill holes in Yucca Mountain.

  18. Improved microstructure of cement-based composites through the addition of rock wool particles

    SciTech Connect (OSTI)

    Lin, Wei-Ting; Cheng, An; Huang, Ran; Zou, Si-Yu

    2013-10-15

    Rock wool is an inorganic fibrous substance produced by steam blasting and cooling molten glass. As with other industrial by-products, rock wool particles can be used as cementitious materials or ultra fine fillers in cement-based composites. This study investigated the microstructure of mortar specimens produced with cement-based composites that include various forms of rock wool particles. It conducted compressive strength testing, rapid chloride penetration tests, X-ray diffraction analysis, thermo-gravimetric analysis, and scanning electronic microscopy to evaluate the macro- and micro-properties of the cement-based composites. Test results indicate that inclusion of rock wool particles in composites improved compressive strength and reduced chloride ion penetration at the age of 91 days due to the reduction of calcium hydroxide content. Microscopic analysis confirms that the use of rock wool particles contributed to the formation of a denser, more compact microstructure within the hardened paste. In addition, X-ray diffraction analysis shows few changes in formation of pozzolanic reaction products and no new hydrations are formed with incorporating rock wool particles. - Highlights: • We report the microstructural characterization of cement-based composites. • Different mixes produced with various rock wool particles have been tested. • The influence of different mixes on macro and micro properties has been discussed. • The macro properties are included compressive strength and permeability. • XRD and SEM observations confirm the pozzolanic reaction in the resulting pastes.

  19. Stratified precambrian rocks (sedimentary?) beneath the midcontinent region of the US. Final technical report

    SciTech Connect (OSTI)

    Hauser, E.C.

    1993-02-01

    A thick sequence of layered rocks occurs beneath the Phanerozoic platform strata which blanket the US midcontinent. Observed on COCORP deep reflection data in southern Illinois and Indiana and in SW Oklahoma and adjacent Texas, this sequence is locally 1--3 times as thick as the overlying Paleozoic cover, but the origin of this sequence and its ultimate lateral extent are unknown. However, the occurrences of Precambrian layered rocks on both the COCORP profiles and reprocessed industry seismic reflection data from the region lie within regions of generally low amplitude and low frequency aeromagnetic anomaly, suggesting an even greater distribution. Unmetamorphosed Precambrian sedimentary rocks have been recovered from drill holes in southwest Ohio and adjacent northern Kentucky and southwesternmost Indiana. These Precambrian sedimentary rocks lie above and may be part of an underlying package of strongly layered rocks imaged on a short and shallow seismic profile in southwest Ohio. These Precambrian sedimentary rocks were originally viewed as part of a late Precambrian (Keweenawan?) rift; however, in light of Grenville foreland structures seen on the COCORP profile to the north in west central Ohio, these Precambrian strata may (1) be part of a heretofore unrecognized Grenville foreland basin, or (2) indicate that unmetamorphosed Precambrian sedimentary material may be an important constituent of the layered rocks observed on COCORP beneath southern Illinois and Indiana.

  20. Stratified precambrian rocks (sedimentary ) beneath the midcontinent region of the US

    SciTech Connect (OSTI)

    Hauser, E.C.

    1993-02-01

    A thick sequence of layered rocks occurs beneath the Phanerozoic platform strata which blanket the US midcontinent. Observed on COCORP deep reflection data in southern Illinois and Indiana and in SW Oklahoma and adjacent Texas, this sequence is locally 1--3 times as thick as the overlying Paleozoic cover, but the origin of this sequence and its ultimate lateral extent are unknown. However, the occurrences of Precambrian layered rocks on both the COCORP profiles and reprocessed industry seismic reflection data from the region lie within regions of generally low amplitude and low frequency aeromagnetic anomaly, suggesting an even greater distribution. Unmetamorphosed Precambrian sedimentary rocks have been recovered from drill holes in southwest Ohio and adjacent northern Kentucky and southwesternmost Indiana. These Precambrian sedimentary rocks lie above and may be part of an underlying package of strongly layered rocks imaged on a short and shallow seismic profile in southwest Ohio. These Precambrian sedimentary rocks were originally viewed as part of a late Precambrian (Keweenawan ) rift; however, in light of Grenville foreland structures seen on the COCORP profile to the north in west central Ohio, these Precambrian strata may (1) be part of a heretofore unrecognized Grenville foreland basin, or (2) indicate that unmetamorphosed Precambrian sedimentary material may be an important constituent of the layered rocks observed on COCORP beneath southern Illinois and Indiana.

  1. Apparatus for the measurement of radionuclide transport rates in rock cores

    SciTech Connect (OSTI)

    Weed, H.C.; Koszykowski, R.F.; Dibley, L.L.; Murray, I.

    1981-09-01

    An apparatus and procedure for the study of radionuclide transport in intact rock cores are presented in this report. This equipment more closely simulates natural conditions of radionuclide transport than do crushed rock columns. The apparatus and the procedure from rock core preparation through data analysis are described. The retardation factors measured are the ratio of the transport rate of a non-retarded radionuclide, such as /sup 3/H, to the transport rate of a retarded radionuclide. Sample results from a study of the transport of /sup 95m/Tc and /sup 85/Sr in brine through a sandstone core are included.

  2. Strontium-85 and plutonium-239 sorption in rock samples from the Semipalatinsk Test Site, Kazakhstan

    SciTech Connect (OSTI)

    Mason, C.F.V.; Lu, N.; Marusak, N.L.; Scheber, B.; Chipera, S.; Daukeyev, D.; Khromushin, I.

    1999-03-01

    The adsorption and desorption of strontium and plutonium were studied as a function of rock type and simulated ground waters from the Semipalatinsk Test Site (STS). Seven different rock types were obtained from the Balapan Region of the STS and were subjected to x-ray diffraction analyses. Two different ground waters were simulated using data supplied by the National Nuclear Center. The results indicate the sorption of strontium is strongly dependent on the minerals present in the rock species and on the total ionic strength of the ground water whereas, in all cases, plutonium was strongly irreversibly sorbed.

  3. Environmental assessment of remedial action at the Slick Rock uranium mill tailings sites, Slick Rock, Colorado. Revision 1

    SciTech Connect (OSTI)

    Not Available

    1994-09-01

    The Uranium Mill Tailings Radiation Control Act of 1978 (42 USC {section}7901 et seq.), hereafter referred to as the UMTRCA, authorized the US Department of Energy (DOE) to clean up two uranium mill tailings processing sites near Slick Rock, Colorado, in San Miquel County. Contaminated materials cover an estimated 63 acres of the Union Carbide (UC) processing site and 15 ac of the North Continent (NC) processing site. The sites are within 1 mile of each other and are adjacent to the Dolores River. The sites contain concrete foundations of mill buildings, tailings piles, and areas contaminated by windblown and waterborne radioactive tailings materials. The total estimated volume of contaminated materials is approximately 621,300 cubic yards (yd{sup 3}). In addition to the contamination in the two processing site areas, four VPs were found to contain contamination. As a result of the tailings being exposed to the environment, contamination associated with the UC and NC sites has leached into shallow ground water. Surface water has not been affected. The closest residence is approximately 0.3 air mi from either site. The proposed action is to remediate the UC and NC sites by removing all contaminated materials within the designing site boundaries or otherwise associated with the sites, and relocating them to, and stabilizing them at, a location approximately 5 road mi northeast of the sites on land administered by the Bureau of Land Management (BLM).

  4. Hot Dry Rock Geothermal Energy In The Jemez Volcanic Field, New...

    Open Energy Info (EERE)

    navigation, search OpenEI Reference LibraryAdd to library Journal Article: Hot Dry Rock Geothermal Energy In The Jemez Volcanic Field, New Mexico Abstract Large, young calderas...

  5. Properties of CO2-Rich Pore Fluids and Their Effect on Porosity Evolution in EGS Rocks

    Broader source: Energy.gov [DOE]

    Project objective: Quantify key parameters critically needed for developing and validating numerical modeling of chemical interactions between EGS reservoir rocks and supercritical CO2and CO2-rich aqueous fluids.

  6. Synchrotron X-ray Studies of Super-critical Carbon Dioxide / Reservoir Rock Interfaces

    Broader source: Energy.gov [DOE]

    Project obectives: Utilize synchrotron X-ray measurements, to monitor all aspects of atomic to nanoscale structural changes resulting from chemical interactions of scCO2-H2O binary fluids with rocks under environments directly relevant to EGS.

  7. Used Fuel Disposal in Crystalline Rocks: Status and FY14 Progress

    Broader source: Energy.gov [DOE]

    The objective of the Crystalline Disposal R&D work is to advance our understanding of long-term disposal of used fuel in crystalline rocks and to develop necessary experimental and...

  8. Multiporosity flow in fractured low-permeability rocks: Extension to shale hydrocarbon reservoirs

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kuhlman, Kristopher L.; Malama, Bwalya; Heath, Jason E.

    2015-02-05

    We presented a multiporosity extension of classical double and triple-porosity fractured rock flow models for slightly compressible fluids. The multiporosity model is an adaptation of the multirate solute transport model of Haggerty and Gorelick (1995) to viscous flow in fractured rock reservoirs. It is a generalization of both pseudo steady state and transient interporosity flow double-porosity models. The model includes a fracture continuum and an overlapping distribution of multiple rock matrix continua, whose fracture-matrix exchange coefficients are specified through a discrete probability mass function. Semianalytical cylindrically symmetric solutions to the multiporosity mathematical model are developed using the Laplace transform tomore » illustrate its behavior. Furthermore, the multiporosity model presented here is conceptually simple, yet flexible enough to simulate common conceptualizations of double and triple-porosity flow. This combination of generality and simplicity makes the multiporosity model a good choice for flow modelling in low-permeability fractured rocks.« less

  9. Multiporosity flow in fractured low-permeability rocks: Extension to shale hydrocarbon reservoirs

    SciTech Connect (OSTI)

    Kuhlman, Kristopher L.; Malama, Bwalya; Heath, Jason E.

    2015-02-05

    We presented a multiporosity extension of classical double and triple-porosity fractured rock flow models for slightly compressible fluids. The multiporosity model is an adaptation of the multirate solute transport model of Haggerty and Gorelick (1995) to viscous flow in fractured rock reservoirs. It is a generalization of both pseudo steady state and transient interporosity flow double-porosity models. The model includes a fracture continuum and an overlapping distribution of multiple rock matrix continua, whose fracture-matrix exchange coefficients are specified through a discrete probability mass function. Semianalytical cylindrically symmetric solutions to the multiporosity mathematical model are developed using the Laplace transform to illustrate its behavior. Furthermore, the multiporosity model presented here is conceptually simple, yet flexible enough to simulate common conceptualizations of double and triple-porosity flow. This combination of generality and simplicity makes the multiporosity model a good choice for flow modelling in low-permeability fractured rocks.

  10. Proceedings of the international symposium on engineering in complex rock formations

    SciTech Connect (OSTI)

    Not Available

    1988-01-01

    This book contains over 100 papers. Some of the titles are: Rheology of rock-salt and its application for radioactive waste disposal purposes; A scale model study on the deformation around the drift in Korean inclined coal seam; Stabilization of a landslide in fractured marls and limestone; Dead Sea underground hydroelectric power station; and Rock mechanics in design of underground power house of lubuge hydropower project.

  11. Precise orientation of single crystals by a simple x-ray diffraction rocking curve method

    SciTech Connect (OSTI)

    Doucette, L.D.; Pereira da Cunha, M.; Lad, R.J.

    2005-03-01

    A simple method has been developed for accurately measuring the crystallographic orientation of a single crystal boule, employing a conventional four-circle x-ray diffraction arrangement in the rocking curve mode which relaxes the need for precise instrument and/or reference alignment. By acquiring a total of eight rocking curve measurements at specific orientations about the specimen azimuth, the absolute miscut angle between a crystal surface and the desired crystallographic plane can be resolved to within {+-}0.01 deg.

  12. Mechanical Behavior of the Near-field Host Rock Surrounding Excavations

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect Technical Report: Mechanical Behavior of the Near-field Host Rock Surrounding Excavations Citation Details In-Document Search Title: Mechanical Behavior of the Near-field Host Rock Surrounding Excavations Authors: Kelkar, Sharad M. [1] ; Stauffer, Philip H. [1] ; Robinson, Bruce Alan [1] + Show Author Affiliations Los Alamos National Laboratory Publication Date: 2015-01-09 OSTI Identifier: 1167232 Report Number(s): LA-UR-14-27717 DOE Contract Number:

  13. ACOUSTICAL IMAGING AND MECHANICAL PROPERTIES OF SOFT ROCK AND MARINE SEDIMENTS

    SciTech Connect (OSTI)

    Thurman E. Scott, Jr.; Younane Abousleiman

    2004-04-01

    The research during this project has concentrated on developing a correlation between rock deformation mechanisms and their acoustic velocity signature. This has included investigating: (1) the acoustic signature of drained and undrained unconsolidated sands, (2) the acoustic emission signature of deforming high porosity rocks (in comparison to their low porosity high strength counterparts), (3) the effects of deformation on anisotropic elastic and poroelastic moduli, and (4) the acoustic tomographic imaging of damage development in rocks. Each of these four areas involve triaxial experimental testing of weak porous rocks or unconsolidated sand and involves measuring acoustic properties. The research is directed at determining the seismic velocity signature of damaged rocks so that 3-D or 4-D seismic imaging can be utilized to image rock damage. These four areas of study are described in the report: (1) Triaxial compression experiments have been conducted on unconsolidated Oil Creek sand at high confining pressures. (2) Initial experiments on measuring the acoustic emission activity from deforming high porosity Danian chalk were accomplished and these indicate that the AE activity was of a very low amplitude. (3) A series of triaxial compression experiments were conducted to investigate the effects of induced stress on the anisotropy developed in dynamic elastic and poroelastic parameters in rocks. (4) Tomographic acoustic imaging was utilized to image the internal damage in a deforming porous limestone sample. Results indicate that the deformation damage in rocks induced during laboratory experimentation can be imaged tomographically in the laboratory. By extension the results also indicate that 4-D seismic imaging of a reservoir may become a powerful tool for imaging reservoir deformation (including imaging compaction and subsidence) and for imaging zones where drilling operation may encounter hazardous shallow water flows.

  14. Final Environmental Assessment of Ground Water Compliance at the Slick Rock, Colorado, UMTRA Project Site

    Office of Environmental Management (EM)

    458 Environmental Assessment of Ground Water Compliance at the Slick Rock, Colorado, UMTRA Project Sites Final February 2003 Prepared by U.S. Department of Energy Grand Junction Office Grand Junction, Colorado Work Performed Under DOE Contract No. DE-AC13-02GJ79491 DOE Grand Junction Office EA of Ground Water Compliance at the Slick Rock Sites February 2003 Final Page iii Contents Page Acronyms and

  15. Proceedings of the International Symposium on Dynamics of Fluids in Fractured Rocks: Concepts and Recent Advances

    SciTech Connect (OSTI)

    Faybishenko, B.

    1999-02-01

    This publication contains extended abstracts of papers presented at the International Symposium ''Dynamics of Fluids in Fractured Rocks: Concepts and Recent Advances'' held at Ernest Orlando Lawrence Berkeley National Laboratory on February 10-12, 1999. This Symposium is organized in Honor of the 80th Birthday of Paul A. Witherspoon, who initiated some of the early investigations on flow and transport in fractured rocks at the University of California, Berkeley, and at Lawrence Berkeley National Laboratory. He is a key figure in the development of basic concepts, modeling, and field measurements of fluid flow and contaminant transport in fractured rock systems. The technical problems of assessing fluid flow, radionuclide transport, site characterization, modeling, and performance assessment in fractured rocks remain the most challenging aspects of subsurface flow and transport investigations. An understanding of these important aspects of hydrogeology is needed to assess disposal of nu clear wastes, development of geothermal resources, production of oil and gas resources, and remediation of contaminated sites. These Proceedings of more than 100 papers from 12 countries discuss recent scientific and practical developments and the status of our understanding of fluid flow and radionuclide transport in fractured rocks. The main topics of the papers are: Theoretical studies of fluid flow in fractured rocks; Multi-phase flow and reactive chemical transport in fractured rocks; Fracture/matrix interactions; Hydrogeological and transport testing; Fracture flow models; Vadose zone studies; Isotopic studies of flow in fractured systems; Fractures in geothermal systems; Remediation and colloid transport in fractured systems; and Nuclear waste disposal in fractured rocks.

  16. ACOUSTICAL IMAGING AND MECHANICAL PROPERTIES OF SOFT ROCK AND MARINE SEDIMENTS

    SciTech Connect (OSTI)

    Thurman E. Scott, Jr., Ph.D.; Younane Abousleiman, Ph.D.; Musharraf Zaman, Ph.D., P.E.

    2001-01-31

    During this phase of the project the research team concentrated on acquisition of acoustic emission data from the high porosity rock samples. The initial experiments indicated that the acoustic emission activity from high porosity Danian chalk were of a very low amplitude. Even though the sample underwent yielding and significant plastic deformation the sample did not generate significant AE activity. This was somewhat surprising. These initial results call into question the validity of attempting to locate AE activity in this weak rock type. As a result the testing program was slightly altered to include measuring the acoustic emission activity from many of the rock types listed in the research program. The preliminary experimental results indicate that AE activity in the sandstones is much higher than in the carbonate rocks (i.e., the chalks and limestones). This observation may be particularly important for planning microseismic imaging of reservoir rocks in the field environment. The preliminary results suggest that microseismic imaging of reservoir rock from acoustic emission activity generated from matrix deformation (during compaction and subsidence) would be extremely difficult to accomplish.

  17. Structure of Si-capped Ge/SiC/Si (001) epitaxial nanodots: Implications for quantum dot patterning

    SciTech Connect (OSTI)

    Petz, C. W.; Floro, J. A.; Yang, D.; Levy, J.

    2012-04-02

    Artificially ordered quantum dot (QD) arrays, where confined carriers can interact via direct exchange coupling, may create unique functionalities such as cluster qubits and spintronic bandgap systems. Development of such arrays for quantum computing requires fine control over QD size and spatial arrangement on the sub-35 nm length scale. We employ electron-beam irradiation to locally decompose ambient hydrocarbons onto a bare Si (001) surface. These carbonaceous patterns are annealed in ultra-high vacuum (UHV), forming ordered arrays of nanoscale SiC precipitates that have been suggested to template subsequent epitaxial Ge growth to form ordered QD arrays. We show that 3C-SiC nanodots form, in cube-on-cube epitaxial registry with the Si substrate. The SiC nanodots are fully relaxed by misfit dislocations and exhibit small lattice rotations with respect to the substrate. Ge overgrowth at elevated deposition temperatures, followed by Si capping, results in expulsion of the Ge from SiC template sites due to the large chemical and lattice mismatch between Ge and C. Maintaining an epitaxial, low-defectivity Si matrix around the quantum dots is important for creating reproducible electronic and spintronic coupling of states localized at the QDs.

  18. Application of glucose as a green capping agent and reductant to fabricate CuI micro/nanostructures

    SciTech Connect (OSTI)

    Tavakoli, Farnosh; Salavati-Niasari, Masoud; Ghanbari, Davood; Saberyan, Kamal; Hosseinpour-Mashkani, S. Mostafa

    2014-01-01

    Graphical abstract: - Highlights: • CuI nanostructures were prepared via a simple precipitation method. • Glucose as a green capping agent and reductant was applied. • The effect of glucose concentration on the morphology of CuI was investigated. • According to XRD results, pure cubic phase CuI have been formed by using glucose. - Abstract: In this work, CuI micro/nanostructures have been successfully prepared via a simple precipitation route at room temperature. By using glucose as a clean reducing agent with different concentrations, CuI micro/nanostructures with various morphologies were obtained. Besides glucose, Na{sub 2}SO{sub 3}, KBH{sub 4} and N{sub 2}H{sub 4}·H{sub 2}O have been applied as reductant. X-ray diffraction (XRD), scanning electron microscopy (SEM), photoluminescence spectroscopy, X-ray energy dispersive spectroscopy (EDS) and Fourier transformed infrared (FT-IR) spectroscopy were used to characterize the as-produced CuI micro/nanostructures. According to the XRD results, it was found that pure cubic phase CuI have been formed by using glucose.

  19. Sonochemical and hydrothermal synthesis of PbTe nanostructures with the aid of a novel capping agent

    SciTech Connect (OSTI)

    Fard-Fini, Shahla Ahmadian; Salavati-Niasari, Masoud; Mohandes, Fatemeh

    2013-10-15

    Graphical abstract: - Highlights: • PbTe nanostructures were prepared with the aid of Schiff-base compound. • Sonochemical and hydrothermal methods were employed to fabricate PbTe nanostrucrues. • The effect of preparation parameters on the morphology of PbTe was investigated. - Abstract: In this work, a new Schiff-base compound derived from 1,8-diamino-3,6-dioxaoctane and 2-hydroxy-1-naphthaldehyde marked as (2-HyNa)-(DaDo) was synthesized, characterized, and then used as capping agent for the preparation of PbTe nanostructures. To fabricate PbTe nanostructures, two different synthesis methods; hydrothermal and sonochemical routes, were applied. To further investigate, the effect of preparation parameters like reaction time and temperature in hydrothermal synthesis and sonication time in the presence of ultrasound irradiation on the morphology and purity of the final products was tested. The products were analyzed with the aid of SEM, TEM, XRD, FT-IR, and EDS. Based on the obtained results, it was found that pure cubic phased PbTe nanostructures have been obtained by hydrothermal and sonochemical approaches. Besides, SEM images showed that cubic-like and rod-like PbTe nanostructures have been formed by hydrothermal and sonochemical methods, respectively. Sonochemical synthesis of PbTe nanostructures was favorable, because the synthesis time of sonochemical method was shorter than that of hydrothermal method.

  20. Preparation of water soluble L-arginine capped CdSe/ZnS QDs and their interaction with synthetic DNA: Picosecond-resolved FRET study

    SciTech Connect (OSTI)

    Giri, Anupam; Goswami, Nirmal; Lemmens, Peter; Pal, Samir Kumar

    2012-08-15

    Graphical abstract: Förster resonance energy transfer (FRET) studies on the interaction of water soluble arginine-capped CdSe/ZnS QDs with ethidium bromide (EB) labeled synthetic dodecamer DNA. Highlights: ? We have solubilized CdSe/ZnS QD in water replacing their TOPO ligand by L-arginine. ? We have studied arginine@QD–DNA interaction using FRET technique. ? Arginine@QDs act as energy donor and ethidium bromide-DNA acts as energy acceptor. ? We have applied a kinetic model to understand the kinetics of energy transfer. ? Circular dichroism studies revealed negligible perturbation in the DNA B-form in the arg@QD-DNA complex. -- Abstract: We have exchanged TOPO (trioctylphosphine oxide) ligand of CdSe/ZnS core/shell quantum dots (QDs) with an amino acid L-arginine (Arg) at the toluene/water interface and eventually rendered the QDs from toluene to aqueous phase. We have studied the interaction of the water soluble Arg-capped QDs (energy donor) with ethidium (EB) labeled synthetic dodecamer DNA (energy acceptor) using picoseconds resolved Förster resonance energy transfer (FRET) technique. Furthermore, we have applied a model developed by M. Tachiya to understand the kinetics of energy transfer and the distribution of acceptor (EB-DNA) molecules around the donor QDs. Circular dichroism (CD) studies revealed a negligible perturbation in the native B-form structure of the DNA upon interaction with Arg-capped QDs. The melting and the rehybridization pathways of the DNA attached to the QDs have been monitored by the CD which reveals hydrogen bonding is the associative mechanism for interaction between Arg-capped QDs and DNA.

  1. Integrating rock mechanics issues with repository design through design process principles and methodology

    SciTech Connect (OSTI)

    Bieniawski, Z.T.

    1996-04-01

    A good designer needs not only knowledge for designing (technical know-how that is used to generate alternative design solutions) but also must have knowledge about designing (appropriate principles and systematic methodology to follow). Concepts such as {open_quotes}design for manufacture{close_quotes} or {open_quotes}concurrent engineering{close_quotes} are widely used in the industry. In the field of rock engineering, only limited attention has been paid to the design process because design of structures in rock masses presents unique challenges to the designers as a result of the uncertainties inherent in characterization of geologic media. However, a stage has now been reached where we are be able to sufficiently characterize rock masses for engineering purposes and identify the rock mechanics issues involved but are still lacking engineering design principles and methodology to maximize our design performance. This paper discusses the principles and methodology of the engineering design process directed to integrating site characterization activities with design, construction and performance of an underground repository. Using the latest information from the Yucca Mountain Project on geology, rock mechanics and starter tunnel design, the current lack of integration is pointed out and it is shown how rock mechanics issues can be effectively interwoven with repository design through a systematic design process methodology leading to improved repository performance. In essence, the design process is seen as the use of design principles within an integrating design methodology, leading to innovative problem solving. In particular, a new concept of {open_quotes}Design for Constructibility and Performance{close_quotes} is introduced. This is discussed with respect to ten rock mechanics issues identified for repository design and performance.

  2. Human immunodeficiency virus contains an epitope immunoreactive with thymosin. cap alpha. /sub 1/ and the 30-amino acid synthetic p17 group-specific antigen peptide HGP-30

    SciTech Connect (OSTI)

    Naylor, P.H.; Naylor, C.W.; Badamchian, M.; Wada, S.; Goldstein, A.L.; Wang, S.S.; Sun, D.K.; Thornton, A.H.; Sarin, P.S.

    1987-05-01

    The authors have reported that an antiserum prepared against thymosin ..cap alpha../sub 1/ (which shares a region of homology with the p17 protein of the acquired immunodeficiency syndrome (AIDS)-associated human immunodeficiency virus) effectively neutralized the AIDs virus and prevented its replication in H9 cells. Using HPLC and immunoblot analysis, they have identified from a clone B, type III human T-lymphotropic virus (HTLV-IIIB) extracts a protein with a molecular weight of 17,000 that is immunoreactive with thymosin ..cap alpha../sub 1/. In contrast, no immunoreactivity was found in retroviral extracts from a number of nonhuman species including feline, bovine, simian, gibbon, and murine retroviruses. Heterologous antiserum prepared against a 30-amino acid synthetic peptide analogue (HGP-30) does not cross-react with thymosin ..cap alpha../sub 1/ but does react specifically with the p17 protein of the AIDS virus in a manner identical to that seen with an HTLV-IIIB p17-specific monoclonal antibody. The demonstration that this synthetic analogue is immunogenic and that antibodies to HGP-30 cross-react not only with synthetic peptide but also with the HTLV-IIIB p17 viral protein provides an additional, and potentially more specific, candidate for development of a synthetic peptide vaccine for AIDS. In addition, the p17 synthetic peptide (HGP-3) may prove to be useful in a diagnostic assay for the detection of AIDS virus infection in seronegative individuals.

  3. Comparison of U.S. Environmental Protection Agency’s CAP88 PC versions 3.0 and 4.0

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jannik, Tim; Farfan, Eduardo B.; Dixon, Ken; Newton, Joseph; Sailors, Christopher; Johnson, Levi; Moore, Kelsey; Stahman, Richard

    2015-08-01

    The Savannah River National Laboratory (SRNL) with the assistance of Georgia Regents University, completed a comparison of the U.S. Environmental Protection Agency's (EPA) environmental dosimetry code CAP88 PC V3.0 with the recently developed V4.0. CAP88 is a set of computer programs and databases used for estimation of dose and risk from radionuclide emissions to air. At the U.S. Department of Energy's Savannah River Site, CAP88 is used by SRNL for determining compliance with EPA's National Emission Standards for Hazardous Air Pollutants (40 CFR 61, Subpart H) regulations. Using standardized input parameters, individual runs were conducted for each radionuclide within itsmore » corresponding database. Some radioactive decay constants, human usage parameters, and dose coefficients changed between the two versions, directly causing a proportional change in the total effective 137Cs, 3H, 129I, 239Pu, and 90Sr) is provided. In general, the total effective doses will decrease for alpha/beta emitters because of reduced inhalation and ingestion rates in V4.0. However, for gamma emitters, such as 60Co and 137Cs, the total effective doses will increase because of changes EPA made in the external ground shine calculations.« less

  4. Highly chemoselective palladium-catalyzed conjugate reduction of. cap alpha. ,. beta. -unsaturated carbonyl compounds with silicon hydrides and zinc chloride cocatalyst

    SciTech Connect (OSTI)

    Keinan, E.; Greenspoon, N.

    1986-11-12

    A three-component system comprised of a soluble palladium catalyst, hydridosilane, and zinc chloride is capable of efficient conjugate reduction of ..cap alpha..,..beta..-unsaturated ketones and aldehydes. The optimal set of conditions includes diphenylsilane as the most effective hydride donor, any soluble palladium complex in either the O or II oxidation state, when it is stabilized by phosphine ligands, and ZnCl/sub 2/ as the best Lewis acid cocatalyst. The reaction is very general with respect to a broad range of unsaturated ketones and aldehydes, and it is highly selective for these Michael acceptors, as reduction of ..cap alpha..,..beta..-unsaturated carboxylic acid derivatives is very sluggish under these conditions. When dideuteriodiphenylsilane is used to reduce unsaturated ketones, deuterium is stereoselectivity introduced at the less-hindered fact of the substrate and regioselectively at the ..beta..-position. Conversely, when reductions are carried out in the presence of traces of D/sub 2/O, deuterium incorporation occurs at the ..cap alpha..-position. On the basis of deuterium-incorporation experiments and /sup 1/H NMR studies a catalytic cycle is postulated in which the first step involves reversible coordination of the palladium complex to the electron-deficient olefin and oxidative addition of silicon hydride to form a hydridopalladium olefin complex.

  5. Comparison of U.S. Environmental Protection Agency’s CAP88 PC versions 3.0 and 4.0

    SciTech Connect (OSTI)

    Jannik, Tim; Farfan, Eduardo B.; Dixon, Ken; Newton, Joseph; Sailors, Christopher; Johnson, Levi; Moore, Kelsey; Stahman, Richard

    2015-08-01

    The Savannah River National Laboratory (SRNL) with the assistance of Georgia Regents University, completed a comparison of the U.S. Environmental Protection Agency's (EPA) environmental dosimetry code CAP88 PC V3.0 with the recently developed V4.0. CAP88 is a set of computer programs and databases used for estimation of dose and risk from radionuclide emissions to air. At the U.S. Department of Energy's Savannah River Site, CAP88 is used by SRNL for determining compliance with EPA's National Emission Standards for Hazardous Air Pollutants (40 CFR 61, Subpart H) regulations. Using standardized input parameters, individual runs were conducted for each radionuclide within its corresponding database. Some radioactive decay constants, human usage parameters, and dose coefficients changed between the two versions, directly causing a proportional change in the total effective 137Cs, 3H, 129I, 239Pu, and 90Sr) is provided. In general, the total effective doses will decrease for alpha/beta emitters because of reduced inhalation and ingestion rates in V4.0. However, for gamma emitters, such as 60Co and 137Cs, the total effective doses will increase because of changes EPA made in the external ground shine calculations.

  6. Organic geochemistry and correlation of Paleozoic source rocks and Trenton crude oils, Indiana

    SciTech Connect (OSTI)

    Guthrie, J. )

    1989-08-01

    Shale samples from four cores of the New Albany and Antrim Shales (Devonian) and from six cores of the Maquoketa Group (Ordovician), representing a broad geographic area of Indiana, have been analyzed for total organic carbon, total sulfur, pyrolysis yield (Rock-Eval), bitumen content, and illite crystallinity data. These data indicate that the New Albany, Antrim, and Maquoketa shales contain a sufficient quantity and quality of organic matter to be good petroleum source rocks. Bitumen ratios, Rock-Eval yields, gas chromatography of saturated hydrocarbons, and illite crystallinity data show that the Maquoketa shales have reached a higher level of thermal maturity than the New Albany and Antrim shales. The level of thermal maturity of the Maquoketa shales suggested a maximum burial depth considerably greater than the present depth.

  7. Revegetation/rock cover for stabilization of inactive uranium mill tailings disposal sites

    SciTech Connect (OSTI)

    Beedlow, P.A.; McShane, M.C.; Cadwell, L.L.

    1982-07-01

    Pacific Northwest Laboratory is developing design and performance guidelines for surface stabilization of inactive uranium mill tailings. In this work, vegetation and rock covers are being evaluated for maintaining long-term integrity of impoundment systems. Methods are being developed to estimate erosion rates associated with rock and/or vegetation covers, and to determine the effects of surface treatments on soil moisture. Interactions between surface treatments and barriers (radon and biological) are being studied as well. The product will be a set of guidelines to aid in designing surface covers. This report presents the status of this program and a discussion of considerations pertinent to the application of surface covers to tailings. Test plots located in Grand Junction, Colorado and Waterflow, New Mexico are being used to study: (1) the interactions between vegetation and radon and biological barriers, (2) the effects of surface covers on soil moisture, and (3) the effects of rock covers on vegetation.

  8. Integrated system for investigating sub-surface features of a rock formation

    DOE Patents [OSTI]

    Vu, Cung Khac; Skelt, Christopher; Nihei, Kurt; Johnson, Paul A.; Guyer, Robert; Ten Cate, James A.; Le Bas, Pierre -Yves; Larmat, Carene S.

    2015-08-18

    A system for investigating non-linear properties of a rock formation around a borehole is provided. The system includes a first sub-system configured to perform data acquisition, control and recording of data; a second subsystem in communication with the first sub-system and configured to perform non-linearity and velocity preliminary imaging; a third subsystem in communication with the first subsystem and configured to emit controlled acoustic broadcasts and receive acoustic energy; a fourth subsystem in communication with the first subsystem and the third subsystem and configured to generate a source signal directed towards the rock formation; and a fifth subsystem in communication with the third subsystem and the fourth subsystem and configured to perform detection of signals representative of the non-linear properties of the rock formation.

  9. AltaRock Energy Announces Successful Multiple-Zone Stimulation of Well at the Newberry Enhanced Geothermal Systems Demonstration

    Broader source: Energy.gov [DOE]

    AltaRock Energy today announced that it has created multiple stimulated zones from a single wellbore at the Newberry Enhanced Geothermal System (EGS) Demonstration site.

  10. Paint Rock and southwest Paint Rock fields, Concho County, Texas: Strawn analogs of modern island carbonate facies of Ambergris Cay, Belize

    SciTech Connect (OSTI)

    Reid, A.M.; Mazzullo, S.J.

    1987-02-01

    Lower Strawn (Desmoinesian Goen Limestone) reservoirs at Paint Rock and Southwest Paint Rock fields are a complex of carbonate and associated facies interpreted as having been deposited in various environments on and around large, emergent islands on shallow carbonate shelves. The origin and geometries of the component lithofacies in these fields, and their reservoir diagenetic histories, are similar to those presently accumulating on Ambergris Cay, a linear island complex on the northern shelf of Belize. Paint Rock field originated as a narrow, elongate Chaetetes reef trend that formed the foundation on which the overlying island facies were deposited. As on Ambergris Cay, these reef limestones developed extensive porosity during postdepositional subaerial exposure due to meteoric leaching. In contrast, Southwest Paint Rock field is cored by older island deposits rather than reef limestones. With ensuing stillstand or subsequent sea level rise, beach grainstones were deposited along the windward and leeward margins of the foundation highs in these fields. Tight lagoonal micrites and coals (peat-swamp facies) comprise the inner island facies, and are locally associated with porous supratidal dolomites. These island complexes are transected locally by tidal channels that are filled with nonporous micrites. Repeated sea level fluctuations during the history of these fields resulted in a characteristic cyclic stratigraphy of stacked island facies and reservoirs. The reservoirs in the field are developed in the bedrock or older island cores, as well as in the overlying beach facies and supratidal dolomites. These fields are mappable as linear stratigraphic traps with low-relief closure, and are readily identified by subsurface geologic and facies analyses. Similar shelf island-type fields analogous to these strawn and Holocene Belizean examples are found throughout the Midland basin and Eastern shelf.

  11. MULTI-ATTRIBUTE SEISMIC/ROCK PHYSICS APPROACH TO CHARACTERIZING FRACTURED RESERVOIRS

    SciTech Connect (OSTI)

    Gary Mavko

    2000-10-01

    This project consists of three key interrelated Phases, each focusing on the central issue of imaging and quantifying fractured reservoirs, through improved integration of the principles of rock physics, geology, and seismic wave propagation. This report summarizes the results of Phase I of the project. The key to successful development of low permeability reservoirs lies in reliably characterizing fractures. Fractures play a crucial role in controlling almost all of the fluid transport in tight reservoirs. Current seismic methods to characterize fractures depend on various anisotropic wave propagation signatures that can arise from aligned fractures. We are pursuing an integrated study that relates to high-resolution seismic images of natural fractures to the rock parameters that control the storage and mobility of fluids. Our goal is to go beyond the current state-of-the art to develop and demonstrate next generation methodologies for detecting and quantitatively characterizing fracture zones using seismic measurements. Our study incorporates 3 key elements: (1) Theoretical rock physics studies of the anisotropic viscoelastic signatures of fractured rocks, including up scaling analysis and rock-fluid interactions to define the factors relating fractures in the lab and in the field. (2) Modeling of optimal seismic attributes, including offset and azimuth dependence of travel time, amplitude, impedance and spectral signatures of anisotropic fractured rocks. We will quantify the information content of combinations of seismic attributes, and the impact of multi-attribute analyses in reducing uncertainty in fracture interpretations. (3) Integration and interpretation of seismic, well log, and laboratory data, incorporating field geologic fracture characterization and the theoretical results of items 1 and 2 above. The focal point for this project is the demonstration of these methodologies in the Marathon Oil Company Yates Field in West Texas.

  12. Petroleum potential of lower and middle Paleozoic rocks in Nebraska portion of Mid-Continent

    SciTech Connect (OSTI)

    Carlson, M.P. )

    1989-08-01

    Central North America during the Paleozoic was characterized by northern (Williston) and southern (Anadarko) depositional regimes separated by a stable Transcontinental arch. Nebraska lies on the southern flank of this arch and contains the northern zero edges of the lower and middle Paleozoic rocks of the southern regime. Most of these rocks are secondary dolomites with zones of excellent intercrystalline porosity. The Reagan-LaMotte Sandstones and the overlying Arbuckle dolomites are overlapped by Middle Ordovician rocks toward the Transcontinental arch. Rocks equivalent to the Simpson consist of a basal sand (St. Peter) and overlying interbedded gray-green shales and dolomitic limestones. An uppermost shale facies is present in the Upper Ordovician (Viola-Maquoketa) eastward and southward across Nebraska. The dolomite facies extends northward into the Williston basin. The Silurian dolomites, originally more widely deposited, are overlapped by Devonian dolomites in southeastern Nebraska. Upper Devonian rocks exhibit a regional facies change from carbonate to green-gray shale to black shale southeastward across the Mid-Continent. Mississippian carbonates overlap the Devonian westward and northward across the Transcontinental arch. Pennsylvanian uplift and erosion were widespread, producing numerous stratigraphic traps. Sands related to the basal Pennsylvanian unconformity produce along the Cambridge arch. Arbuckle, Simpson, Viola, and Hunton production is present in the Forest City basin and along the Central Kansas uplift. Although source rocks are scarce and the maturation is marginal, current theories of long-distance oil migration encourage exploration in the extensive lower and middle Paleozoic reservoirs in this portion of the Mid-Continent.

  13. An asixymmetric diffusion experiment for the determination of diffusion and sorption coefficients of rock samples

    SciTech Connect (OSTI)

    Takeda, M.; Hiratsuka, T.; Ito, K.; Finsterle, S.

    2011-02-01

    Diffusion anisotropy is a critical property in predicting migration of substances in sedimentary formations with very low permeability. The diffusion anisotropy of sedimentary rocks has been evaluated mainly from laboratory diffusion experiments, in which the directional diffusivities are separately estimated by through-diffusion experiments using different rock samples, or concurrently by in-diffusion experiments in which only the tracer profile in a rock block is measured. To estimate the diffusion anisotropy from a single rock sample, this study proposes an axisymmetric diffusion test, in which tracer diffuses between a cylindrical rock sample and a surrounding solution reservoir. The tracer diffusion between the sample and reservoir can be monitored from the reservoir tracer concentrations, and the tracer profile could also be obtained after dismantling the sample. Semi-analytical solutions are derived for tracer concentrations in both the reservoir and sample, accounting for an anisotropic diffusion tensor of rank two as well as the dilution effects from sampling and replacement of reservoir solution. The transient and steady-state analyses were examined experimentally and numerically for different experimental configurations, but without the need for tracer profiling. These experimental configurations are tested for in- and out-diffusion experiments using Koetoi and Wakkanai mudstones and Shirahama sandstone, and are scrutinized by a numerical approach to identify favorable conditions for parameter estimation. The analysis reveals the difficulty in estimating diffusion anisotropy; test configurations are proposed for enhanced identifiability of diffusion anisotropy. Moreover, it is demonstrated that the axisymmetric diffusion test is efficient in obtaining the sorption parameter from both steady-state and transient data, and in determining the effective diffusion coefficient if isotropic diffusion is assumed. Moreover, measuring reservoir concentrations in an axisymmetric diffusion experiment coupled with tracer profiling may be a promising approach to estimate of diffusion anisotropy of sedimentary rocks.

  14. The Effect of Scale on the Mechanical Properties of Jointed Rock Masses

    SciTech Connect (OSTI)

    Heuze, F E

    2004-05-24

    These notes were prepared for presentation at the Defense Threat Reduction Agency's (DTRA) Hard Target Research and Analysis Center (HTRAC), at the occasion of a short course held on June 14-15, 2004. The material is intended for analysts who must evaluate the geo-mechanical characteristics of sites of interest, in order to provide appropriate input to calculations of ground shock effects on underground facilities in rock masses. These analysts are associated with the Interagency Geotechnical Assessment Team (IGAT). Because geological discontinuities introduce scale effects on the mechanical properties of rock formations, these large-scale properties cannot be estimated on the basis of tests on small cores.

  15. POSSIBLE ALTERATION OF ROCKS OBSERVED BY CHEMCAM ALONG THE TRAVERSE TO

    Office of Scientific and Technical Information (OSTI)

    GLENELG IN GALE CRATER ON MARS. (Technical Report) | SciTech Connect Technical Report: POSSIBLE ALTERATION OF ROCKS OBSERVED BY CHEMCAM ALONG THE TRAVERSE TO GLENELG IN GALE CRATER ON MARS. Citation Details In-Document Search Title: POSSIBLE ALTERATION OF ROCKS OBSERVED BY CHEMCAM ALONG THE TRAVERSE TO GLENELG IN GALE CRATER ON MARS. Authors: Berger, B. [1] ; Blaney, D. [2] ; Bridges, J. [3] ; Cousin, A. [1] ; Forni, O. [1] ; Gasnault, O. [1] ; Lasue, J. [1] ; Mangold, N. [4] ; Maurice, S.

  16. POSSIBLE ALTERATION OF ROCKS OBSERVED BY CHEMCAM ALONG THE TRAVERSE TO

    Office of Scientific and Technical Information (OSTI)

    GLENELG IN GALE CRATER ON MARS. (Technical Report) | SciTech Connect POSSIBLE ALTERATION OF ROCKS OBSERVED BY CHEMCAM ALONG THE TRAVERSE TO GLENELG IN GALE CRATER ON MARS. Citation Details In-Document Search Title: POSSIBLE ALTERATION OF ROCKS OBSERVED BY CHEMCAM ALONG THE TRAVERSE TO GLENELG IN GALE CRATER ON MARS. Authors: Berger, B. [1] ; Blaney, D. [2] ; Bridges, J. [3] ; Cousin, A. [1] ; Forni, O. [1] ; Gasnault, O. [1] ; Lasue, J. [1] ; Mangold, N. [4] ; Maurice, S. [1] ; Meslin, P. Y.

  17. POSSIBLE ALTERATION OF ROCKS OBSERVED BY CHEMCAM ALONG THE TRAVERSE TO

    Office of Scientific and Technical Information (OSTI)

    GLENELG IN GALE CRATER ON MARS. (Technical Report) | SciTech Connect Technical Report: POSSIBLE ALTERATION OF ROCKS OBSERVED BY CHEMCAM ALONG THE TRAVERSE TO GLENELG IN GALE CRATER ON MARS. Citation Details In-Document Search Title: POSSIBLE ALTERATION OF ROCKS OBSERVED BY CHEMCAM ALONG THE TRAVERSE TO GLENELG IN GALE CRATER ON MARS. × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical

  18. Comparison of the effects in the rock mass of large-scale chemical and

    Office of Scientific and Technical Information (OSTI)

    nuclear explosions. Final technical report, June 9, 1994--October 9, 1994 (Technical Report) | SciTech Connect Comparison of the effects in the rock mass of large-scale chemical and nuclear explosions. Final technical report, June 9, 1994--October 9, 1994 Citation Details In-Document Search Title: Comparison of the effects in the rock mass of large-scale chemical and nuclear explosions. Final technical report, June 9, 1994--October 9, 1994 × You are accessing a document from the Department

  19. Investigation of Coupled Processes and Impact of High Temperature Limits in Argillite Rock

    SciTech Connect (OSTI)

    Zheng, Liange; Rutqvist, Jonny; Kim, Kunhwi; Houseworth, Jim

    2015-07-01

    The focus of research within the UFD Campaign is on repository-induced interactions that may affect the key safety characteristics of an argillaceous rock. These include thermal-hydrological-mechanical-chemical (THMC) process interactions that occur as a result of repository construction and waste emplacement. Some of the key questions addressed in this report include the development of fracturing in the excavation damaged zone (EDZ) and THMC effects on the near-field argillaceous rock and buffer minerals and petrophysical characteristics, particularly the impacts of induced temperature rise caused by waste heat.

  20. Used Fuel Disposal in Crystalline Rocks: Status and FY14 Progress.

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect Used Fuel Disposal in Crystalline Rocks: Status and FY14 Progress. Citation Details In-Document Search Title: Used Fuel Disposal in Crystalline Rocks: Status and FY14 Progress. Abstract not provided. Authors: Wang, Yifeng Publication Date: 2014-09-01 OSTI Identifier: 1160341 Report Number(s): SAND2014-17992R 537706 DOE Contract Number: AC04-94AL85000 Resource Type: Technical Report Research Org: Sandia National Laboratories (SNL), Albuquerque, NM, and

  1. The effects of heat conduction on the vaporization of liquid invading superheated permeable rock

    SciTech Connect (OSTI)

    Woods, Andrew, W.; Fitzgerald, Shaun D.

    1996-01-24

    We examine the role of conductive and convective heat transfer in the vaporization of liquid as it slowly invades a superheated permeable rock. For very slow migration, virtually all of the liquid vaporizes. As the liquid supply rate increases beyond the rate of heat transfer by thermal conduction, a decreasing fraction of the liquid can vaporize. Indeed, for sufficiently high flow rates, the fraction vaporizing depends solely on the superheat of the rock, and any heat transfer from the superheated region is negligible. These results complement earlier studies of vaporization under very high injection rates, in which case the dynamic vapour pressure reduces the mass fraction vaporizing to very small values.

  2. Microsoft Word - Comments received at White Rock Scoping Mtg.doc

    National Nuclear Security Administration (NNSA)

    CMRR-NF Supplemental EIS Scoping Meeting October 19, 2010 / White Rock Town Hall, White Rock, NM Written Comments (transcribed) 061 Joni Arends The meeting format does not work. One of the purposes of the scoping meeting is for the public to hear the concerns of other community members. The people of N. NM have a strong oral tradition where people learn by listening to others. We request a "classroom" type format, such as that used during the draft document hearing process. A format

  3. Cap and trade schemes on waste management: A case study of the Landfill Allowance Trading Scheme (LATS) in England

    SciTech Connect (OSTI)

    Calaf-Forn, Maria; Roca, Jordi; Puig-Ventosa, Ignasi

    2014-05-01

    Highlights: • LATS has been effective to achieve a reduction of the amount of landfilled waste. • LATS has been one of the few environmental instruments for waste management with a cap and trade methodology. • LATS has achieved to increase recycling of the biodegradable and other waste fractions. - Abstract: The Landfill Allowance Trading Scheme (LATS) is one of the main instruments used in England to enforce the landfill diversion targets established in the Directive 1999/31/EC of the European Parliament and of the Council of 26 April 1999 on the landfill of waste (Landfill Directive). Through the LATS, biodegradable municipal waste (BMW) allowances for landfilling are allocated to each local authority, otherwise known as waste disposal authorities (WDAs). The quantity of landfill allowances received is expected to decrease continuously from 2005/06 to 2019/20 so as to meet the objectives of the Landfill Directive. To achieve their commitments, WDAs can exchange, buy, sell or transfer allowances among each other, or may re-profile their own allocation through banking and/or borrowing. Despite the goals for the first seven years – which included two target years (2005/06 and 2009/10) – being widely achieved (the average allocation of allowances per WDA was 22.9% higher than those finally used), market activity among WDAs was high and prices were not very stable. Results in terms of waste reduction and recycling levels have been satisfactory. The reduction of BMW landfilled (in percentage) was higher during the first seven years of the LATS period (2005/06–2011/12) (around 7% annually) than during the previous period (2001/02–2004/05) (4.2% annually). Since 2008, the significance of the LATS diminished because of an increase in the rate of the UK Landfill Tax. The LATS was suppressed after the 2012/13 target year, before what it was initially scheduled. The purpose of this paper is to describe the particularities of the LATS, analyse its performance as a waste management policy, make a comparison with the Landfill Tax, discuss its main features as regards efficiency, effectiveness and the application of the “polluter pays” principle and finally discuss if the effect of the increase in the Landfill Tax is what made the LATS ultimately unnecessary.

  4. EA-1987: Parker-Headgate Rock and Parker-Bouse Rebuild Project, Arizona and California

    Broader source: Energy.gov [DOE]

    DOE’s Western Area Power Administration is preparing an EA that will assess the potential environmental impacts of a proposal to rebuild the existing Parker Dam-Headgate Rock and Parker Dam-Bouse 161-kilovolt transmission lines along the Colorado River in western Arizona and eastern California.

  5. Diamond formation due to a pH drop during fluid–rock interactions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sverjensky, Dimitri A.; Huang, Fang

    2015-11-03

    Diamond formation has typically been attributed to redox reactions during precipitation from fluids or magmas. Either the oxidation of methane or the reduction of carbon dioxide has been suggested, based on simplistic models of deep fluids consisting of mixtures of dissolved neutral gas molecules without consideration of aqueous ions. The role of pH changes associated with water–silicate rock interactions during diamond formation is unknown. Here we show that diamonds could form due to a drop in pH during water–rock interactions. We use a recent theoretical model of deep fluids that includes ions, to show that fluid can react irreversibly withmore » eclogite at 900 °C and 5.0 GPa, generating diamond and secondary minerals due to a decrease in pH at almost constant oxygen fugacity. Overall, our results constitute a new quantitative theory of diamond formation as a consequence of the reaction of deep fluids with the rock types that they encounter during migration. Diamond can form in the deep Earth during water–rock interactions without changes in oxidation state.« less

  6. Stratigraphic controls on the source rock distribution, Llanos Orientales Basin, Colombia

    SciTech Connect (OSTI)

    Ramon, J.C.; Fajardo, A.; Rubiano, J.; Reyes, A. )

    1996-01-01

    All available rock and oil geochemistry analyses were tied to a high-resolution stratigraphic framework for more than 50 wells in the Central Llanos Orientates Basin. New Tertiary generation input is proposed. The best source rock intervals are at the base and top of the Gacheta Formation (Upper Cretaceous) and in the middle of the Barco-Cuervos (Paleocene) and Mirador (Eocene) formations. These organic-rich zones contain type II and III kerogen. TOC contents range from about 1% up to 15%. The four source rock intervals occur within marine shales near condensed sections, at the position maximum accommodation/sediment-supply (A/S) ratios. The development of conditions that allow accumulation and preservation of anomalously high fractions of organic matter might be explained by two mechanisms. Increased A/S ratio results in retention of more sediment in the coastal plain, thus reducing the tendency for siliciclastic sediment to dilute the organic matter accumulating on the shelf. Also, deeper water might restrict circulation, enhancing bottom anoxic conditions. In the more transitional and continental sequences, increased A/S ratio is associated with higher phreatic water level. A high ground water table enhances preservation of coaly intervals. The sea-level rise brings marine water into valleys and low-gradient coastal plains. The resulting embayments, marsh and swampy areas are organic-prone, contributing to the source rock potential of strata associated with high conditions and base-level rise-to-fall turnaround positions.

  7. Stratigraphic controls on the source rock distribution, Llanos Orientales Basin, Colombia

    SciTech Connect (OSTI)

    Ramon, J.C.; Fajardo, A.; Rubiano, J.; Reyes, A.

    1996-12-31

    All available rock and oil geochemistry analyses were tied to a high-resolution stratigraphic framework for more than 50 wells in the Central Llanos Orientates Basin. New Tertiary generation input is proposed. The best source rock intervals are at the base and top of the Gacheta Formation (Upper Cretaceous) and in the middle of the Barco-Cuervos (Paleocene) and Mirador (Eocene) formations. These organic-rich zones contain type II and III kerogen. TOC contents range from about 1% up to 15%. The four source rock intervals occur within marine shales near condensed sections, at the position maximum accommodation/sediment-supply (A/S) ratios. The development of conditions that allow accumulation and preservation of anomalously high fractions of organic matter might be explained by two mechanisms. Increased A/S ratio results in retention of more sediment in the coastal plain, thus reducing the tendency for siliciclastic sediment to dilute the organic matter accumulating on the shelf. Also, deeper water might restrict circulation, enhancing bottom anoxic conditions. In the more transitional and continental sequences, increased A/S ratio is associated with higher phreatic water level. A high ground water table enhances preservation of coaly intervals. The sea-level rise brings marine water into valleys and low-gradient coastal plains. The resulting embayments, marsh and swampy areas are organic-prone, contributing to the source rock potential of strata associated with high conditions and base-level rise-to-fall turnaround positions.

  8. Status and prospects for hot dry rock (HDR) in the United States

    SciTech Connect (OSTI)

    Brown, D.; Duchane, D.

    1992-01-01

    The vast majority of accessible geothermal energy exists in the form of heat stored in dry rock at depth. For nearly the last two decades, the Los Alamos National Laboratory has been engaged in a program to develop the technology to mine the thermal energy in this hot dry rock (HDR). The world's first heat mine was developed and operated at Fenton Hill, N.M. in the 1970's by using drilling and hydraulic fracturing techniques to create an artificial reservoir in hot rock and subsequently circulating water through this reservoir to mine the heat from the rock. Over the last ten years, a much larger, deeper, and hotter heat mine has been constructed at Fenton Hill and a permanent energy extraction plant has been built on the surface. A long-term testing program has recently begun to evaluate the potential for sustained energy extraction from the large Fenton Hill heat mine. This paper summarizes the history of HDR research and development at Los Alamos, reports the initial results of the long-term testing program at Fenton Hill, and discusses the possible future course of HDR technology.

  9. Status and prospects for hot dry rock (HDR) in the United States

    SciTech Connect (OSTI)

    Brown, D.; Duchane, D.

    1992-08-01

    The vast majority of accessible geothermal energy exists in the form of heat stored in dry rock at depth. For nearly the last two decades, the Los Alamos National Laboratory has been engaged in a program to develop the technology to mine the thermal energy in this hot dry rock (HDR). The world`s first heat mine was developed and operated at Fenton Hill, N.M. in the 1970`s by using drilling and hydraulic fracturing techniques to create an artificial reservoir in hot rock and subsequently circulating water through this reservoir to mine the heat from the rock. Over the last ten years, a much larger, deeper, and hotter heat mine has been constructed at Fenton Hill and a permanent energy extraction plant has been built on the surface. A long-term testing program has recently begun to evaluate the potential for sustained energy extraction from the large Fenton Hill heat mine. This paper summarizes the history of HDR research and development at Los Alamos, reports the initial results of the long-term testing program at Fenton Hill, and discusses the possible future course of HDR technology.

  10. A pore-scale model of two-phase flow in water-wet rock

    SciTech Connect (OSTI)

    Silin, Dmitriy; Patzek, Tad

    2009-02-01

    A finite-difference discretization of Stokes equations is used to simulate flow in the pore space of natural rocks. Numerical solutions are obtained using the method of artificial compressibility. In conjunction with Maximal Inscribed Spheres method, these computations produce relative permeability curves. The results of computations are in agreement with laboratory measurements.

  11. Sorptivity of rocks and soils of the van Genuchten-Mualem type

    SciTech Connect (OSTI)

    Zimmerman, R.W.; Bodvarsson, G.S. [Lawrence Berkeley Lab., CA (United States)

    1991-06-01

    One hydrological process that will have great relevance to the performance of the proposed underground radioactive waste repository at Yucca Mountain, Nevada, is that of the absorption of water from a water-filled fracture into the adjacent unsaturated rock formation. The rate at which water is imbibed by a rock depends on the hydrological properties of the rock and on the initial saturation (or initial capillary suction) of the formation. The hydrological properties that affect imbibition are the relative permeability function and the capillary pressure function. These functions are often collectively referred to as the `characteristic functions` of the porous medium. For one-dimensional absorption, it can be shown that, regardless of the details of the characteristic functions, the total amount of water imbibed by the formation, per unit surface area, will be proportional to the square root of the elapsed time. Hence the ability of a rock or soil to imbibe water can be quantified by a parameter known as the sorptivity S, which is defined such that the cumulative volumetric liquid influx per unit area is given by Q = S{radical}t. The paper discusses the simplification of these characteristic functions of porous medium.

  12. Parameter estimation from flowing fluid temperature logging data in unsaturated fractured rock using multiphase inverse modeling

    SciTech Connect (OSTI)

    Mukhopadhyay, S.; Tsang, Y.; Finsterle, S.

    2009-01-15

    A simple conceptual model has been recently developed for analyzing pressure and temperature data from flowing fluid temperature logging (FFTL) in unsaturated fractured rock. Using this conceptual model, we developed an analytical solution for FFTL pressure response, and a semianalytical solution for FFTL temperature response. We also proposed a method for estimating fracture permeability from FFTL temperature data. The conceptual model was based on some simplifying assumptions, particularly that a single-phase airflow model was used. In this paper, we develop a more comprehensive numerical model of multiphase flow and heat transfer associated with FFTL. Using this numerical model, we perform a number of forward simulations to determine the parameters that have the strongest influence on the pressure and temperature response from FFTL. We then use the iTOUGH2 optimization code to estimate these most sensitive parameters through inverse modeling and to quantify the uncertainties associated with these estimated parameters. We conclude that FFTL can be utilized to determine permeability, porosity, and thermal conductivity of the fracture rock. Two other parameters, which are not properties of the fractured rock, have strong influence on FFTL response. These are pressure and temperature in the borehole that were at equilibrium with the fractured rock formation at the beginning of FFTL. We illustrate how these parameters can also be estimated from FFTL data.

  13. Rock the Watt: An Energy Conservation Campaign at Pacific Northwest National Lab

    SciTech Connect (OSTI)

    2016-01-01

    Case study describes Pacific Northwest National Laboratory's (PNNL) three-month Rock the Watt campaign to reduce energy use at its main campus in Richland, Washington. The campaign objectives were to educate PNNL employees about energy conservation opportunities in their workplace and to motivate them to help PNNL save energy and costs and to reduce greenhouse gas emissions.

  14. Diamond formation due to a pH drop during fluid–rock interactions

    SciTech Connect (OSTI)

    Sverjensky, Dimitri A.; Huang, Fang

    2015-11-03

    Diamond formation has typically been attributed to redox reactions during precipitation from fluids or magmas. Either the oxidation of methane or the reduction of carbon dioxide has been suggested, based on simplistic models of deep fluids consisting of mixtures of dissolved neutral gas molecules without consideration of aqueous ions. The role of pH changes associated with water–silicate rock interactions during diamond formation is unknown. Here we show that diamonds could form due to a drop in pH during water–rock interactions. We use a recent theoretical model of deep fluids that includes ions, to show that fluid can react irreversibly with eclogite at 900 °C and 5.0 GPa, generating diamond and secondary minerals due to a decrease in pH at almost constant oxygen fugacity. Overall, our results constitute a new quantitative theory of diamond formation as a consequence of the reaction of deep fluids with the rock types that they encounter during migration. Diamond can form in the deep Earth during water–rock interactions without changes in oxidation state.

  15. Alleghanian development of the Goat Rock fault zone, southernmost Appalachians: Temporal compatibility with the master decollement

    SciTech Connect (OSTI)

    Steltenpohl, M.G. (Auburn Univ., AL (United States)); Goldberg, S.A. (Univ. of North Carolina, Chapel Hill (United States)); Hanley, T.B. (Columbus College, GA (United States)); Kunk, M.J. (Geological Survey, Reston, VA (United States))

    1992-09-01

    The Goat Rock and associated Bartletts Ferry fault zones, which mark the eastern margin of the Pine Mountain Grenville basement massif, are controversial due to the suggestion that they are rare exposed segments of the late Paleozoic southern Appalachian master decollement. The controversy in part stems from reported middle Paleozoic (Acadian) radiometric dates postulated as the time of movement along these fault zones. Ultramylonite samples from the type area at Goat Rock Dam yield a 287 [plus minus] 15 Ma Rb-Sr isochron interpreted as the time of Sr isotopic rehomgenization during mylonitization. This date is corroborated by Late Pennsylvanian-Early Permian [sup 40]Ar/[sup 39]Ar mineral ages on hornblende (297-288 Ma) and muscovite (285-278 Ma) from neomineralized and dynamically recrystallized rocks within and straddling the fault zone. These Late Pennsylvanian-Early Permian dates indicate the time of right-slip movement (Alleghenian) along the Goat Rock fault zone, which is compatible with the timing suggested by COCORP for thrusting along the southern Appalachian master decollement.

  16. Fluid-evaporation records preserved in salt assemblages in Meridiani rocks

    SciTech Connect (OSTI)

    Rao, M.N.; Nyquist, L.E.; Sutton, S.R.; Dreibus, G.; Garrison, D.H.; Herrin, J.

    2009-09-25

    We studied the inter-relationships between the major anions (SO{sub 3}, Cl, and Br) and cations (FeO, CaO and MgO) using elemental abundances determined by APXS in salt assemblages of RATted (abraded) rocks at Meridiani to characterize the behavior of fluids that infiltrated into this region on Mars. A plot of SO{sub 3} versus Cl for the abraded rocks yielded an unusual pattern, whereas the SO{sub 3}/Cl ratios versus Cl for the same rocks showed a monotonically decreasing trend represented by a hyperbola. The systematic behavior of the SO{sub 3} and Cl data in the documented rocks at Meridiani suggests that these anions behaved conservatively during fluid-rock interactions. These results further indicate that two kinds of fluids, referred to as SOL-I and SOL-II, infiltrated into Endurance/Eagle/Fram craters, where they underwent progressive evaporative concentration. SOL-I is a low pH fluid consisting of high SO{sub 3} and low Cl and high Br, (this fluid infiltrated all the way to the crater-top region), whereas SOL-II fluid of high pH with low SO{sub 3} and high Cl and low Br reached only an intermediary level known as the Whatanga contact at Endurance. Based on the FeO/MgO as well as CaO/MgO versus SO{sub 3}/Cl diagram for rocks above the Whatanga contact, the cation and anion relationships in this system suggest that the Fe{sup 2+}/SO{sub 4} and Ca{sup 2+}/SO{sub 4} ratios in SOL-I fluids at Meridiani were > 1 before the onset of evaporation based on the 'chemical divide' considerations. Below the Whatanga contact, relatively dilute SOL-II fluids seem to have infiltrated and dissolved/flushed away the easily soluble Mg-sulfate/chloride phases (along with Br) without significantly altering the SO{sub 3}/Cl ratios in the residual salt assemblages. Further, Cl/Br versus Br in rocks above the Whatanga contact show a hyperbolic trend suggesting that Cl and Br behaved conservatively similar to SO{sub 3} and Cl in the SOL-1 fluids at Meridiani. Our results are consistent with a scenario involving two episodes (SOL-I and SOL-II) of groundwater recharge at Meridiani Planum.

  17. Collective relaxation, single particle motion and short range order in. cap alpha. '-NbD/sub x/: A quasielastic neutron scattering study

    SciTech Connect (OSTI)

    Hempelmann, R.; Richter, D.; Faux, D.A.; Ross, D.K.

    1988-01-01

    Applying both incoherent and coherent quasielastic neutron scattering we have studied simultaneously single particle motion, collective relaxation and short range order of deuterium in ..cap alpha..'-NbD/sub x/. A comparison with recent Monte Carlo simulations lead to a consistent description of all results in terms of strongly repulsive deuterium-deuterium interactions. Relating the independently determined tracer and chemical diffusion coefficients with the also measured structure factor we show experimentally that for lattice gases the de Gennes narrowing Ansatz needs to be modified by correlation factors. 18 refs., 3 figs., 1 tab.

  18. ACOUSTICAL IMAGING AND MECHANICAL PROPERTIES OF SOFT ROCK AND MARINE SEDIMENTS

    SciTech Connect (OSTI)

    Thurman E. Scott, Jr., Ph.D.; Younane Abousleiman, Ph.D.; Musharraf Zaman, Ph.D., P.E.

    2002-11-18

    During the sixth quarter of this research project the research team developed a method and the experimental procedures for acquiring the data needed for ultrasonic tomography of rock core samples under triaxial stress conditions as outlined in Task 10. Traditional triaxial compression experiments, where compressional and shear wave velocities are measured, provide little or no information about the internal spatial distribution of mechanical damage within the sample. The velocities measured between platen-to-platen or sensor-to-sensor reflects an averaging of all the velocities occurring along that particular raypath across the boundaries of the rock. The research team is attempting to develop and refine a laboratory equivalent of seismic tomography for use on rock samples deformed under triaxial stress conditions. Seismic tomography, utilized for example in crosswell tomography, allows an imaging of the velocities within a discrete zone within the rock. Ultrasonic or acoustic tomography is essentially the extension of that field technology applied to rock samples deforming in the laboratory at high pressures. This report outlines the technical steps and procedures for developing this technology for use on weak, soft chalk samples. Laboratory tests indicate that the chalk samples exhibit major changes in compressional and shear wave velocities during compaction. Since chalk is the rock type responsible for the severe subsidence and compaction in the North Sea it was selected for the first efforts at tomographic imaging of soft rocks. Field evidence from the North Sea suggests that compaction, which has resulted in over 30 feet of subsidence to date, is heterogeneously distributed within the reservoir. The research team will attempt to image this very process in chalk samples. The initial tomographic studies (Scott et al., 1994a,b; 1998) were accomplished on well cemented, competent rocks such as Berea sandstone. The extension of the technology to weaker samples is more difficult but potentially much more rewarding. The chalk, since it is a weak material, also attenuates wave propagation more than other rock types. Three different types of sensors were considered (and tested) for the tomographic imaging project: 600 KHz PZT, 1 MHz PZT, and PVDF film sensors. 600 KHz PZT crystals were selected because they generated a sufficiently high amplitude pulse to propagate across the damaged chalk. A number of different configurations were considered for placement of the acoustic arrays. It was decided after preliminary testing that the most optimum arrangement of the acoustic sensors was to place three arrays of sensors, with each array containing twenty sensors, around the sample. There would be two horizontal arrays to tomographically image two circular cross-sectional planes through the rock core sample. A third array would be vertically oriented to provide a vertical cross-sectional view of the sample. A total of 260 acoustic raypaths would be shot and acquired in the horizontal acoustic array to create each horizontal tomographic image. The sensors can be used as both acoustic sources or as acoustic each of the 10 pulsers to the 10 receivers.

  19. ACOUSTICAL IMAGING AND MECHANICAL PROPERTIES OF SOFT ROCK AND MARINE SEDIMENTS

    SciTech Connect (OSTI)

    Thurman E. Scott, Jr., Ph.D.; Younane Abousleiman, Ph.D.; Musharraf Zaman, Ph.D., P.E.

    2002-11-18

    During the seven quarter of the project the research team analyzed some of the acoustic velocity data and rock deformation data. The goal is to create a series of ''deformation-velocity maps'' which can outline the types of rock deformational mechanisms which can occur at high pressures and then associate those with specific compressional or shear wave velocity signatures. During this quarter, we began to analyze both the acoustical and deformational properties of the various rock types. Some of the preliminary velocity data from the Danian chalk will be presented in this report. This rock type was selected for the initial efforts as it will be used in the tomographic imaging study outlined in Task 10. This is one of the more important rock types in the study as the Danian chalk is thought to represent an excellent analog to the Ekofisk chalk that has caused so many problems in the North Sea. Some of the preliminary acoustic velocity data obtained during this phase of the project indicates that during pore collapse and compaction of this chalk, the acoustic velocities can change by as much as 200 m/s. Theoretically, this significant velocity change should be detectable during repeated successive 3-D seismic images. In addition, research continues with an analysis of the unconsolidated sand samples at high confining pressures obtained in Task 9. The analysis of the results indicate that sands with 10% volume of fines can undergo liquefaction at lower stress conditions than sand samples which do not have fines added. This liquefaction and/or sand flow is similar to ''shallow water'' flows observed during drilling in the offshore Gulf of Mexico.

  20. Source rock geochemistry and liquid and solid petroleum occurrences of the Ouachita Mountains, Oklahoma

    SciTech Connect (OSTI)

    Curiale, J.A.

    1981-01-01

    Crude oils, solid bitumens and potential oil source rocks of the Frontal and Central Ouachita Mountains of southeastern Oklahoma were examined. The purposes of this study are to characterize the organic matter in each of these materials, and to correlate oils to potential source rocks in the Ouachita Mountains. Four Ouachita Mountain oils and seven solid bitumens (grahamite and impsonite were analyzed. The oils are paraffinic and range from 31.8 to 43.1 API gravity. Results indicate that the oils are thermally mature and generally unaltered. All four oils are commonly sourced, as suggested by n-alkane, sterane and hopane distributions, stable isotope ratios, infrared spectra and vanadium/nickel ratios. A common source for the solid bitumens is also suggested by isotope ratios and pyrolyzate characteristics. An origin due to crude oil biodegradation is suggested for these solids, based on carbon isotope ratios, elemental analyses, and sterane distributions of the solid bitumen pyrolyzates. Several stratigraphic intervals in the Ouachita Mountains possess adequate source potential for petroleum generation, based on contents of total organic carbon and extractable organic matter. Devonian rocks are oil-generative. The entire Paleozoic section examined is thermally mature enough to have generated oil, being located at about the middle of the oil window. In general, the best oil source potential is present in upper Ordovician (Polk Creek/Womble) rocks. Oil-source rock correlation techniques indicate that oils examined from the Frontal and Central Ouachita Mountains have a Siluro-Ordovician (Missouri Mountain-Polk Creek-Womble) source.

  1. Precarious Rock Methodology for Seismic Hazard: Physical Testing, Numerical Modeling and Coherence Studies

    SciTech Connect (OSTI)

    Anooshehpoor, Rasool; Purvance, Matthew D.; Brune, James N.; Preston, Leiph A.; Anderson, John G.; Smith, Kenneth D.

    2006-09-29

    This report covers the following projects: Shake table tests of precarious rock methodology, field tests of precarious rocks at Yucca Mountain and comparison of the results with PSHA predictions, study of the coherence of the wave field in the ESF, and a limited survey of precarious rocks south of the proposed repository footprint. A series of shake table experiments have been carried out at the University of Nevada, Reno Large Scale Structures Laboratory. The bulk of the experiments involved scaling acceleration time histories (uniaxial forcing) from 0.1g to the point where the objects on the shake table overturned a specified number of times. The results of these experiments have been compared with numerical overturning predictions. Numerical predictions for toppling of large objects with simple contact conditions (e.g., I-beams with sharp basal edges) agree well with shake-table results. The numerical model slightly underpredicts the overturning of small rectangular blocks. It overpredicts the overturning PGA for asymmetric granite boulders with complex basal contact conditions. In general the results confirm the approximate predictions of previous studies. Field testing of several rocks at Yucca Mountain has approximately confirmed the preliminary results from previous studies, suggesting that he PSHA predictions are too high, possibly because the uncertainty in the mean of the attenuation relations. Study of the coherence of wavefields in the ESF has provided results which will be very important in design of the canisters distribution, in particular a preliminary estimate of the wavelengths at which the wavefields become incoherent. No evidence was found for extreme focusing by lens-like inhomogeneities. A limited survey for precarious rocks confirmed that they extend south of the repository, and one of these has been field tested.

  2. Fundamental Research on Percussion Drilling: Improved rock mechanics analysis, advanced simulation technology, and full-scale laboratory investigations

    SciTech Connect (OSTI)

    Michael S. Bruno

    2005-12-31

    This report summarizes the research efforts on the DOE supported research project Percussion Drilling (DE-FC26-03NT41999), which is to significantly advance the fundamental understandings of the physical mechanisms involved in combined percussion and rotary drilling, and thereby facilitate more efficient and lower cost drilling and exploration of hard-rock reservoirs. The project has been divided into multiple tasks: literature reviews, analytical and numerical modeling, full scale laboratory testing and model validation, and final report delivery. Literature reviews document the history, pros and cons, and rock failure physics of percussion drilling in oil and gas industries. Based on the current understandings, a conceptual drilling model is proposed for modeling efforts. Both analytical and numerical approaches are deployed to investigate drilling processes such as drillbit penetration with compression, rotation and percussion, rock response with stress propagation, damage accumulation and failure, and debris transportation inside the annulus after disintegrated from rock. For rock mechanics modeling, a dynamic numerical tool has been developed to describe rock damage and failure, including rock crushing by compressive bit load, rock fracturing by both shearing and tensile forces, and rock weakening by repetitive compression-tension loading. Besides multiple failure criteria, the tool also includes a damping algorithm to dissipate oscillation energy and a fatigue/damage algorithm to update rock properties during each impact. From the model, Rate of Penetration (ROP) and rock failure history can be estimated. For cuttings transport in annulus, a 3D numerical particle flowing model has been developed with aid of analytical approaches. The tool can simulate cuttings movement at particle scale under laminar or turbulent fluid flow conditions and evaluate the efficiency of cutting removal. To calibrate the modeling efforts, a series of full-scale fluid hammer drilling tests, as well as single impact tests, have been designed and executed. Both Berea sandstone and Mancos shale samples are used. In single impact tests, three impacts are sequentially loaded at the same rock location to investigate rock response to repetitive loadings. The crater depth and width are measured as well as the displacement and force in the rod and the force in the rock. Various pressure differences across the rock-indentor interface (i.e. bore pressure minus pore pressure) are used to investigate the pressure effect on rock penetration. For hammer drilling tests, an industrial fluid hammer is used to drill under both underbalanced and overbalanced conditions. Besides calibrating the modeling tool, the data and cuttings collected from the tests indicate several other important applications. For example, different rock penetrations during single impact tests may reveal why a fluid hammer behaves differently with diverse rock types and under various pressure conditions at the hole bottom. On the other hand, the shape of the cuttings from fluid hammer tests, comparing to those from traditional rotary drilling methods, may help to identify the dominant failure mechanism that percussion drilling relies on. If so, encouraging such a failure mechanism may improve hammer performance. The project is summarized in this report. Instead of compiling the information contained in the previous quarterly or other technical reports, this report focuses on the descriptions of tasks, findings, and conclusions, as well as the efforts on promoting percussion drilling technologies to industries including site visits, presentations, and publications. As a part of the final deliveries, the 3D numerical model for rock mechanics is also attached.

  3. ACOUSTICAL IMAGING AND MECHANICAL PROPERTIES OF SOFT ROCK AND MARINE SEDIMENTS

    SciTech Connect (OSTI)

    Thurman E. Scott, Jr., Ph.D.; Musharraf Zaman, Ph.D.; Younane Abousleiman, Ph.D.

    2001-04-01

    The oil and gas industry has encountered significant problems in the production of oil and gas from weak rocks (such as chalks and limestones) and from unconsolidated sand formations. Problems include subsidence, compaction, sand production, and catastrophic shallow water sand flows during deep water drilling. Together these cost the petroleum industry hundreds of millions of dollars annually. The goals of this first quarterly report is to document the progress on the project to provide data on the acoustic imaging and mechanical properties of soft rock and marine sediments. The project is intended to determine the geophysical (acoustic velocities) rock properties of weak, poorly cemented rocks and unconsolidated sands. In some cases these weak formations can create problems for reservoir engineers. For example, it cost Phillips Petroleum 1 billion dollars to repair of offshore production facilities damaged during the unexpected subsidence and compaction of the Ekofisk Field in the North Sea (Sulak 1991). Another example is the problem of shallow water flows (SWF) occurring in sands just below the seafloor encountered during deep water drilling operations. In these cases the unconsolidated sands uncontrollably flow up around the annulus of the borehole resulting in loss of the drill casing. The $150 million dollar loss of the Ursa development project in the U.S. Gulf Coast resulted from an uncontrolled SWF (Furlow 1998a,b; 1999a,b). The first three tasks outlined in the work plan are: (1) obtain rock samples, (2) construct new acoustic platens, (3) calibrate and test the equipment. These have been completed as scheduled. Rock Mechanics Institute researchers at the University of Oklahoma have obtained eight different types of samples for the experimental program. These include: (a) Danian Chalk, (b) Cordoba Cream Limestone, (c) Indiana Limestone, (d) Ekofisk Chalk, (e) Oil Creek Sandstone, (f) unconsolidated Oil Creek sand, and (g) unconsolidated Brazos river sand. These weak rocks and sands are intended to represent analogs to the formations that present oil and gas engineers with problems during oil and gas production and drilling operations. A series of new axial acoustic sensors have been constructed (and tested) to allow measurement of compressional and shear wave velocities during high pressure triaxial tests on these weak rock and sand samples. In addition, equipment to be utilized over the next 18 months of the project have tested and calibrated. These include the load frames, triaxial pressure cells, pressure sensors, load cells, extensometers, and oscilloscopes have been calibrated and tested. The multichannel acoustic emission and acoustic pulse transmission systems have also been tested. Graduate research assistant, research faculty, and the laboratory technician have begun Tasks 4 and 5 which involve preparing the sand samples and rock samples for testing. The construction of the lateral acoustic sensors has also been started during this quarter as outlined in the project timeline. With the equipment having been tested and calibrated, and the samples now being prepared, the experiments are on schedule to be started in April, 2001.

  4. EA-1331: Remediation of Subsurface and Groundwater Contamination at the Rock Springs in situ Oil Shale Retort Site, Sweetwater County, Wyoming

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts for the proposal for the Rock Springs In-Situ Oil Shale Retort Test Site remediation that would be performed at the Rock Springs site in Sweetwater...

  5. ACOUSTICAL IMAGING AND MECHANICAL PROPERTIES OF SOFT ROCK AND MARINE SEDIMENTS

    SciTech Connect (OSTI)

    Thurman E. Scott, Jr., Ph.D.; Younane Abousleiman, Ph.D.; Musharraf Zaman, Ph.D., P.E.

    2001-07-01

    Mechanically weak formations, such as chalks, high porosity sandstones, and marine sediments, pose significant problems for oil and gas operators. Problems such as compaction, subsidence, and loss of permeability can affect reservoir production operations. For example, the unexpected subsidence of the Ekofisk chalk in the North Sea required over one billion dollars to re-engineer production facilities to account for losses created during that compaction (Sulak 1991). Another problem in weak formations is that of shallow water flows (SWF). Deep water drilling operations sometimes encounter cases where the marine sediments, at shallow depths just below the seafloor, begin to uncontrollably flow up and around the drill pipe. SWF problems created a loss of $150 million for the Ursa development project in the U.S. Gulf Coast SWF (Furlow 1998a,b; 1999a,b). The goal of this project is to provide a database on both the rock mechanical properties and the geophysical properties of weak rocks and sediments. These could be used by oil and gas companies to detect, evaluate, and alleviate potential production and drilling problems. The results will be useful in, for example, pre-drill detection of events such as SWF's by allowing a correlation of seismic data (such as hazard surveys) to rock mechanical properties. The data sets could also be useful for 4-D monitoring of the compaction and subsidence of an existing reservoir and imaging the zones of damage. During the second quarter of the project the research team has: (1) completed acoustic sensor construction, (2) conducted reconnaissance tests to map the deformational behaviors of the various rocks, (3) developed a sample assembly for the measurement of dynamic elastic and poroelastic parameters during triaxial testing, and (4) conducted a detailed review of the scientific literature and compiled a bibliography of that review. During the first quarter of the project the research team acquired several rock types for testing including: (a) Danian chalk, (b) Cordoba Cream limestone, (c) Indiana limestone, (d) Ekofisk chalk, (e) Oil Creek sandstone, (f) unconsolidated Oil Creek sand, and (g) unconsolidated Brazos river sand. During the second quarter experiments were begun on these rock types. A series of reconnaissance experiments have been carried out on all but the Ekofisk (for which there is a preliminary data set already inhouse). A series of triaxial tests have been conducted on the Danian chalk, the Cordoba Cream limestone, the Indiana limestone, and sand samples to make a preliminary determination of the deformational mechanisms present in these samples.

  6. Stable isotope evidence for limited fluid infiltration of deep crustal rocks from the Ivrea Zone, Italy

    SciTech Connect (OSTI)

    Baker, A.J.

    1988-06-01

    Isotopic and petrologic studies of the Ivrea Zone, a segment of deep-crustal high-grade rocks, suggest that metamorphism did not involve the transfer of large quantities of CO/sub 2/ from mantle to crust. High-grade Ivrea Zone calcites may retain high ..delta../sup 18/O (up to 24 per thousand SMOW), indicating little interaction with externally derived fluid. Graphite isotopic compositions (..delta../sup 13/C = -10 per thousand to -25 per thousand PDB) that do not vary with grade are attributed to mixing between carbonate carbon and biogenic noncarbonate carbon. Calcites from high-grade, carbonate-poor amphibolites have ..delta../sup 13/C of about 1 per thousand PDB and sedimentary, not infiltrative, origins. The general lack of carbon and oxygen isotopic homogenization suggests that fluid interactions may be explained in terms of fluid generated internally to the Ivrea Zone metasedimentary rocks.

  7. Effect of recirculation pump trip following anticipated transients without scram at Big Rock Point

    SciTech Connect (OSTI)

    Lyon, R.E.

    1981-08-01

    As requested by the US Atomic Energy Commission (now US Nuclear Regulatory Commission) in their Technical Report on Anticipated Transients Without Scram (ATWS) for Water-Cooled Reactors (WASH-1270), Consumers Power Company has submitted analyses which describe the response of their Big Rock Point (BRP) Plant to ATWS. The original analyses were submitted on Febuary 21, 1975, and results indicated that a recirculation pump trip (RPT) was effective in limiting the consequences of an ATWS. The response of BRP to an ATWS was reanalyzed as a part of the Big Rock Point Probabilistic Risk Assessment (PRA). Results of the analysis were submitted on February 26, 1981, with the conclusion that automatic RPT provides little safety improvement at BRP. Purpose of this report is to evaluate the submitted analyses to determine the effectiveness of Recirculation Pump Trip in ATWS recovery.

  8. Method of measuring material properties of rock in the wall of a borehole

    DOE Patents [OSTI]

    Overmier, D.K.

    1984-01-01

    To measure the modulus of elasticity of the rock in the wall of a borehole, a plug is cut in the borehole wall. The plug, its base attached to the surrounding rock, acts as a short column in response to applied forces. A loading piston is applied to the top of the plug and compression of the plug is measured as load is increased. Measurements of piston load and plug longitudinal deformation are made to determine the elastic modulus of the plug material. Poisson's ratio can be determined by simultaneous measurements of longitudinal and lateral deformation of the plug in response to loading. To determine shear modulus, the top of the plug is twisted while measurements are taken of torsional deformation.

  9. Method of measuring material properties of rock in the wall of a borehole

    DOE Patents [OSTI]

    Overmier, David K. (Albuquerque, NM)

    1985-01-01

    To measure the modulus of elasticity of the rock in the wall of a borehole, a plug is cut in the borehole wall. The plug, its base attached to the surrounding rock, acts as a short column in response to applied forces. A loading piston is applied to the top of the plug and compression of the plug is measured as load is increased. Measurement of piston load and plug longitudinal deformation are made to determine the elastic modulus of the plug material. Poisson's ratio can be determined by simultaneous measurements of longitudinal and lateral deformation of the plug in response to loading. To determine shear modulus, the top of the plug is twisted while measurements are taken of torsional deformation.

  10. Preliminary results of wildcat drilling in Absaroka volcanic rocks, Hot Springs County, Wyoming

    SciTech Connect (OSTI)

    Bailey, M.H.; Sundell, K.A.

    1986-08-01

    Recent drilling of three remote, high-elevation wildcat wells has proven that excellent Paleozoic reservoirs are present at shallow depths beneath Eocene volcaniclastic rocks. The Tensleep and Madison Formations are fluid filled above an elevation of 8000 ft, and all Paleozoic formations exhibit shows of oil and gas. These prolific reservoir rocks have produced billions of barrels of oil from the adjacent Bighorn and Wind river basins, and they pinch out with angular unconformity against the base of the volcanics, providing enormous potential for stratigraphic oil accumulations. Vibroseis and portable seismic data have confirmed and further delineate large anticlines of Paleozoic rocks, which were originally discovered by detailed surface geologic mapping. These structures can be projected along anticlinal trends from the western Owl Creek Mountains to beneath the volcanics as well. The overlying volcanics are generally soft, reworked sediments. However, large, hard boulders and blocks of andesite-dacite, which were previously mapped as intrusives, are present and are the result of catastrophic landslide/debris flow. The volcanics locally contain highly porous and permeable sandstones and abundant bentonite stringers. Oil and gas shows were observed throughout a 2400-ft thick interval of the Eocene Tepee Trail and Aycross Formations. Shows were recorded 9100 ft above sea level in the volcanic rocks. A minimum of 10 million bbl of oil (asphaltum) and an undetermined amount of gases and lighter oils have accumulated within the basal volcanic sequence, based on the evaluation of data from two drill sites. Significant amounts of hydrocarbons have migrated since the volcanics were deposited 50 Ma. Large Laramide anticlines were partially eroded and breached into the Paleozoic formations and resealed by overlying volcanics with subsequent development of a massive tar seal.

  11. Landslides and other mass movements near TA-33, northern White Rock Canyon, New Mexico. Final report

    SciTech Connect (OSTI)

    Dethier, D.P.

    1993-09-01

    Massive slump complexes and at least two rock avalanches flank the eastern rim of the Pajarito Plateau along northern White Rock Canyon, north of TA-33. Landslides failed along mechanically weak rocks in the Santa Fe Group, within the Puye Formation, or in Pliocene alluvial and lacustrine units. The landslides are mainly of early or middle Pleistocene age. The toe area of at least,one slump complex has been active in the late Pleistocene, damming White Rock Canyon near the mouth of Water Canyon. Lacustrine sediment that filled this lake, or series of lakes, to an elevation of at least 1710 m is preserved at a number of upstream sites, including a deposit near the Buckman townsite that exposes 30 m of lacustrine sediment. Charcoal collected at several sites has been submitted for {sup 14}C dating. Landslides, however, probably do not represent a significant short-term threat to the material disposal areas at TA-33. Bedrock that lies beneath the TA-33 mesa is relatively stable, the mesa shows no signs of incipient failure, and past periods of slide activity were responses to rapid downcutting of the Rio Grande and climate change, probably over periods of several decades, at least. Rockfall and headward erosion of gullies do not represent significant decadal hazards on canyon rims near TA-33. Gully migration near MDA-K is a potential threat, but the gullies were not examined in detail. A system of north-trending faults, at least one of which displays Pleistocene activity, bisects the TA-33 mesa. If these faults are capable of producing significant seismic shaking, generalizations about landslide and rockfall hazards must be reevaluated.

  12. Insensitive explosive composition and method of fracturing rock using an extrudable form of the composition

    DOE Patents [OSTI]

    Davis, Lloyd L.

    2015-07-28

    Insensitive explosive compositions were prepared by reacting di-isocyanate and/or poly-isocyanate monomers with an explosive diamine monomer. Prior to a final cure, the compositions are extrudable. The di-isocyanate monomers tend to produce tough, rubbery materials while polyfunctional monomers (i.e. having more than two isocyanate groups) tend to form rigid products. The extrudable form of the composition may be used in a variety of applications including rock fracturing.

  13. Peer Review of the Hot Dry Rock Project at Fenton Hill, New Mexico

    SciTech Connect (OSTI)

    1998-12-01

    This report briefly describes the history of the hot dry rock experiment project conducted by the U.S. Department of Energy and Los Alamos National Laboratory at Fenton Hill, New Mexico, from about 1971 through 1995. The authors identify the primary lessons learned and techniques developed during the course of the Fenton Hill project, and summarize the extent to which these technologies have been transferred to the U.S. geothermal industry.

  14. Field-Scale Effective Matrix Diffusion Coefficient for FracturedRock: Results From Literature Survey

    SciTech Connect (OSTI)

    Zhou, Quanlin; Liu, Hui Hai; Molz, Fred J.; Zhang, Yingqi; Bodvarsson, Gudmundur S.

    2005-03-28

    Matrix diffusion is an important mechanism for solutetransport in fractured rock. We recently conducted a literature survey onthe effective matrix diffusion coefficient, Dem, a key parameter fordescribing matrix diffusion processes at the field scale. Forty fieldtracer tests at 15 fractured geologic sites were surveyed and selectedfor study, based on data availability and quality. Field-scale Dem valueswere calculated, either directly using data reported in the literature orby reanalyzing the corresponding field tracer tests. Surveyed dataindicate that the effective-matrix-diffusion-coefficient factor FD(defined as the ratio of Dem to the lab-scale matrix diffusioncoefficient [Dem]of the same tracer) is generally larger than one,indicating that the effective matrix diffusion coefficient in the fieldis comparatively larger than the matrix diffusion coefficient at therock-core scale. This larger value could be attributed to the manymass-transfer processes at different scales in naturally heterogeneous,fractured rock systems. Furthermore, we observed a moderate trend towardsystematic increase in the emDFmDDF value with observation scale,indicating that the effective matrix diffusion coefficient is likely tobe statistically scale dependent. The FD value ranges from 1 to 10,000for observation scales from 5 to 2,000 m. At a given scale, the FD valuevaries by two orders of magnitude, reflecting the influence of differingdegrees of fractured rock heterogeneity at different sites. In addition,the surveyed data indicate that field-scale longitudinal dispersivitygenerally increases with observation scale, which is consistent withprevious studies. The scale-dependent field-scale matrix diffusioncoefficient (and dispersivity) may have significant implications forassessing long-term, large-scale radionuclide and contaminant transportevents in fractured rock, both for nuclear waste disposal and contaminantremediation.

  15. Figure 2. Stratigraphic Summary of Ages, Names and Rock Types in the ANWR

    Gasoline and Diesel Fuel Update (EIA)

    1002 2. Stratigraphic Summary of Ages, Names and Rock Types in the ANWR 1002 and Coastal Plain Area of the Alaska North Slope. Potentially Productive Reservoirs and Plays Assessed by the USGS are Indicated fig2.jpg (30091 bytes) Source: Edited from U.S. Geological Survey, "The Oil and Gas Resource Potential of the Arctic National Wildlife Refuge 1002 Area, Alaska," Open File Report 98-34, 1999.

  16. Summary of three dimensional pump testing of a fractured rock aquifer in the western Siberian Basin

    SciTech Connect (OSTI)

    Nichols, R.L.; Looney, B.B.; Eddy-Dilek, C.A.; Drozhko, E.G.; Glalolenko, Y.V.; Mokrov, Y.G.; Ivanov, I.A.; Glagolev, A.V.; Vasil`kova, N.A.

    1996-10-30

    A group of scientists from the Savannah River Technology Center and Russia successfully completed a 17 day field investigation of a fractured rock aquifer at the MAYAK PA nuclear production facility in Russia. The test site is located in the western Siberian Basin near the floodplain of the Mishelyak river. The fractured rock aquifer is composed of orphyrites, tuff, tuffbreccia and lava and is overlain by 0.5--12 meters of elluvial and alluvial sediments. A network of 3 uncased wells (176, 1/96, and 2/96) was used to conduct the tests. Wells 176 and 2/96 were used as observation wells and the centrally located well 1/96 was used as the pumping well. Six packers were installed and inflated in each of the observation wells at a depth of up to 85 meters. The use of 6 packers in each well resulted in isolating 7 zones for monitoring. The packers were inflated to different pressures to accommodate the increasing hydrostatic pressure. A straddle packer assembly was installed in the pumping well to allow testing of each of the individual zones isolated in the observation wells. A constant rate pumping test was run on each of the 7 zones. The results of the pumping tests are included in Appendix A. The test provided new information about the nature of the fractured rock aquifers in the vicinity of the Mishelyak river and will be key information in understanding the behavior of contaminants originating from process wastes discharged to Lake Karachi. Results from the tests will be analyzed to determine the hydraulic properties of different zones within the fractured rock aquifer and to determine the most cost effective clean-up approach for the site.

  17. Insensitive explosive composition and method of fracturing rock using an extrudable form of the composition

    DOE Patents [OSTI]

    Davis, Lloyd L

    2013-11-05

    Insensitive explosive compositions were prepared by reacting di-isocyanate and/or poly-isocyanate monomers with an explosive diamine monomer. Prior to a final cure, the compositions are extrudable. The di-isocyanate monomers tend to produce tough, rubbery materials while polyfunctional monomers (i.e. having more than two isocyanate groups) tend to form rigid products. The extrudable form of the composition may be used in a variety of applications including rock fracturing.

  18. A LANL Scientist's Dream Takes Off to Zap Rocks on Mars

    ScienceCinema (OSTI)

    Wiens, Roger

    2012-08-02

    Roger Wiens, with a team of 40 people at Los Alamos National Laboratory and the collaboration of the French space institute IRAP, created ChemCam, a laser spectrometer and telescope device aboard the Curiosity rover. ChemCam will blast rocks from as far as 7 meters, vaporize bits of their surfaces, and spectroscopically determine their chemical composition, aiding in the search for life on Mars, and making this scientist's boyhood dream a reality.

  19. A new friction factor correlation for laminar, single-phase flows through rock fractures

    SciTech Connect (OSTI)

    Nazridoust, K. (Clarkson Univ., Potsdam, NY); Ahmadi, G. (Clarkson Univ., Potsdam, NY); Smith, D.H.

    2006-09-30

    Single-phase flow through fractured media occurs in various situations, such as transport of dissolved contaminants through geological strata, sequestration of carbon dioxide in depleted gas reservoirs, and in primary oil recovery. In the present study, fluid flows through a rock fracture were simulated. The fracture geometry was obtained from the CT scans of a rock fracture produced by the Brazilian method in a sandstone sample. A post-processing code using a CAD package was developed and used to generate the three-dimensional fracture from the CT scan data. Several sections along the fracture were considered and the GambitTM code was used to generate unstructured grids for flow simulations. FLUENTTM was used to analyze the flow conditions through the fracture section for different flow rates. Because of the small aperture of the fractures, the gravitational effects could be neglected. It was confirmed that the pressure drop was dominated by the smallest aperture passages of the fracture. The accuracy of parallel plate models for estimating the pressure drops through fractures was studied. It was shown that the parallel plate flow model with the use of an appropriate effective fracture aperture and inclusion of the tortuosity factor could provide reasonable estimates for pressure drops in the fracture. On the basis of the CFD simulation data, a new expression for the friction factor for flows through fractures was developed. The new model predictions were compared with the simulation results and favorable agreement was found. It was shown that when the length of the fracture and the mean and standard deviation of the fracture are known, the pressure loss as a function of the flow rate could be estimated. These findings may prove useful for design of lab experiments, computational studied of flows through real rock fractures, or inclusions in simulators for large-scale flows in highly fractured rocks.

  20. MISCELLANEOUS PAPER S71-17 EARTHQUAKE RESISTANCE OF EARTH AND ROCK-FILL DAMS

    Office of Legacy Management (LM)

    MISCELLANEOUS PAPER S71-17 EARTHQUAKE RESISTANCE OF EARTH AND ROCK-FILL DAMS Report 2 ANALYSIS OF RESPONSE O F RIFLE.GAP D A M TO PROJECT RULISON UNDERGROUND NUCLEAR DETONATION bv J. E. Ahlberg, J. Fowler, L W. Heller ........ . . . . . . . . - . . . . . . . . . . . . . . . - . . - ...... *- , .... . . . - ->-w-J- * - : - . . June 1972 s~omsored by Office, Chief of Engineers, U. S. Army Conducted by U. S. A m y Engineer Waterways Experiment Station Soils and Pavements Laboratory Vicksburg,

  1. Subsurface cross section of lower Paleozoic rocks, Powder River basin, Wyoming and Montana

    SciTech Connect (OSTI)

    Macke, D.L.

    1988-07-01

    The Powder River basin is one of the most actively explored Rocky Mountain basins for hydrocarbons, yet the lower Paleozoic (Cambrian through Mississippian) rocks of this interval remain little studied. As a part of a program studying the evolution of sedimentary basins, approximately 3200 km of cross section, based on more than 50 combined geophysical and lithologic logs, have been constructed covering an area of about 200,000 km/sup 2/. The present-day basin is a Cenozoic structural feature located between the stable interior of the North American craton and the Cordilleran orogenic belt. At various times during the early Paleozoic, the basin area was not distinguishable from either the stable craton, the Williston basin, the Central Montana trough, or the Cordilleran miogeocline. Both deposition and preservation in the basin have been greatly influenced by the relative uplift of the Transcontinental arch. Shows of oil and dead oil in well cuttings confirm that hydrocarbons have migrated through at least parts of the basin's lower Paleozoic carbonate section. These rocks may have been conduits for long-distance migration of hydrocarbons as early as Late Cretaceous, based on (1) the probable timing of thermal maturation of hydrocarbon-source rocks within the basin area and to the west, (2) the timing of Laramide structural events, (3) the discontinuous nature of the reservoirs in the overlying, highly productive Pennsylvanian-Permian Minnelusa Formation, and (4) the under-pressuring observed in some Minnelusa oil fields. Vertical migration into the overlying reservoirs could have been through deep fractures within the basin, represented by major lineament systems. Moreover, the lower Paleozoic rocks themselves may also be hydrocarbon reservoirs.

  2. Measurements and modeling of surface waves in drilled shafts in rock

    SciTech Connect (OSTI)

    Kalinski, M.E.; Stokoe, K.H. II; Roesset, J.M.; Cheng, D.S.

    1999-07-01

    Seismic testing was conducted in the WIPP facility in November 1994 by personnel from the Geotechnical Engineering Center at the University of Texas at Austin. Surface wave measurements were made in horizontal drilled shafts in rock salt to characterize the stiffness of the rock around the shafts. The Spectral-Analysis-of-Surface-Waves (SASW) method was used to determine dispersion curves of surface wave velocity versus wavelength. Dispersion curves were measured for surface waves propagating axially and circumferentially in the shafts. Surface wave velocities determined from axial testing increased slightly with increasing wavelength due to the cylindrical geometry of the shafts. On the other hand, surface wave velocities determined from circumferential testing exhibited a completely different type of geometry-induced dispersion. In both instances, finite-element forward modeling of the experimental dispersion curves revealed the presence of a thin, slightly softer disturbed rock zone (DRZ) around the shafts. This phenomenon has been previously confirmed by crosshole and other seismic measurements and is generally associated with relaxation of the individual salt crystals after confirming stress is relieved by excavation.

  3. Final Report - Advanced Conceptual Models for Unsaturated and Two-Phase Flow in Fractured Rock

    SciTech Connect (OSTI)

    Nicholl, Michael J.

    2006-07-10

    The Department of Energy Environmental Management Program is faced with two major issues involving two-phase flow in fractured rock; specifically, transport of dissolved contaminants in the Vadose Zone, and the fate of Dense Nonaqueous Phase Liquids (DNAPLs) below the water table. Conceptual models currently used to address these problems do not correctly include the influence of the fractures, thus leading to erroneous predictions. Recent work has shown that it is crucial to understand the topology, or ''structure'' of the fluid phases (air/water or water/DNAPL) within the subsurface. It has also been shown that even under steady boundary conditions, the influence of fractures can lead to complex and dynamic phase structure that controls system behavior, with or without the presence of a porous rock matrix. Complicated phase structures within the fracture network can facilitate rapid transport, and lead to a sparsely populated and widespread distribution of concentrated contaminants; these qualities are highly difficult to describe with current conceptual models. The focus of our work is to improve predictive modeling through the development of advanced conceptual models for two-phase flow in fractured rock.

  4. WETTABILITY ALTERATION OF CARBONATE ROCK MEDIATED BY BIOSURFACTANT PRODUCED FROM HIGH-STARCH AGRICULTURAL EFFLUENTS

    SciTech Connect (OSTI)

    Mehdi Salehi; Stephen Johnson; Gregory Bala; Jenn-Tai Liang

    2006-09-01

    Surfactants can be used to alter wettability of reservoir rock, increasing spontaneous imbibition and thus improving oil yields. Commercial synthetic surfactants are often prohibitively expensive and so a crude preparation of the anionic biosurfactant, surfactin, from Bacillus subtilis grown on high-starch industrial and agricultural effluents has been proposed as an economical alternative. To assess the effectiveness of the surfactin, it is compared to commercially available surfactants. In selecting a suitable benchmark surfactant, two metrics are examined: the ability of the surfactants to alter wettability at low concentrations, and the degree to which they are absorbed onto reservoir matrix. We review the literature to survey the adsorption models that have been developed to describe surfactant adsorption in porous media. These models are evaluated using the experimental data from this study. Crushed carbonate rock samples are cleaned and aged in crude oil. The wettability change mediated by dilute solutions of commercial anionic surfactants and surfactin is assessed using a two-phase separation; and surfactant loss due to retention and adsorption the rock is determined.

  5. Thermal Expansion Behavior of Cerro Prieto Sandstones and Other Sedimentary Rocks Under Stress

    SciTech Connect (OSTI)

    Contreras, E.; Bermejo, F.

    1983-12-15

    This paper describes the experimental work and presents the results of a research program carried out to investigate the thermal expansion behavior of sedimentary rocks under high stress conditions. The aspects that were investigated include the effects of temperature, temperature cycling, and confining pressure. Furthermore, the validity of the usual assumption on thermal expansion isotropy was investigated. On the other hand, the matrix thermal expansion concept is analyzed and its physical meaning and aplications are discussed. The effect of temperature on porosity is also a subject investigated regarding experimental methods for its estimation and comparison of earlier results. The experiments carried out consisted basically of thermal strain versus temperature measurements on jacketed and unjacketed samples subjected to different confining pressures and covering the temperature range from 25 C to 280 C and the pressure range from 3.0 MPa to 34.4 MPa. A review of earlier work is included as a reference frame to discuss and compare the results of this work, as well as to emphasize the limited extent of the research on thermal expansion behavior of sedimentary rocks that had been accomplished. Results are presented by means of thermal strain versus temperature curves and tabular data of thermal expansion coefficients. Several important conclusions for laborarory and field applications are reached from each of the aspects investigated. The wide research scope of considerable amount of data reported may represent an important contribution to the knowledge of thermal expansion behavior of sedimentary rocks.

  6. Potential increases in natural radon emissions due to heating of the Yucca Mountain rock mass

    SciTech Connect (OSTI)

    Pescatore, C.; Sullivan, T.M.

    1992-02-01

    Heating of the rock mass by the spent fuel in the proposed repository at Yucca Mountain will cause extra amounts of natural radon to diffuse into the fracture system and to migrate faster to the accessible environment. Indeed, free-convection currents due to heating will act to shorten the radon travel times and will cause larger releases than would be possible under undistributed conditions. To estimate the amount of additional radon released due to heating of the Yucca Mountain rock mass, we obtain an expression for the release enhancement factor, E. This factor is defined as the ratio between the total flux of radon at the surface of the mountain before and after closure of the repository assuming the only cause of disturbance to be the heating of the rock mass. With appropriate approximations and using a heat load representative of that expected at Yucca Mountain, the present calculations indicate that the average enhancement factor over the first 10,000 years will be 4.5 as a minimum. These calculations are based on the assumption that barometric pumping does not significantly influence radon release. The latter assumption will need to be substantiated.

  7. Chemical analyses of rocks, minerals, and detritus, Yucca Mountain--Preliminary report, special report No. 11

    SciTech Connect (OSTI)

    Hill, C.A.; Livingston, D.E.

    1993-09-01

    This chemical analysis study is part of the research program of the Yucca Mountain Project intended to provide the State of Nevada with a detailed assessment of the geology and geochemistry of Yucca Mountain and adjacent regions. This report is preliminary in the sense that more chemical analyses may be needed in the future and also in the sense that these chemical analyses should be considered as a small part of a much larger geological data base. The interpretations discussed herein may be modified as that larger data base is examined and established. All of the chemical analyses performed to date are shown in Table 1. There are three parts to this table: (1) trace element analyses on rocks (limestone and tuff) and minerals (calcite/opal), (2) rare earth analyses on rocks (tuff) and minerals (calcite/opal), and (3) major element analyses + CO{sub 2} on rocks (tuff) and detritus sand. In this report, for each of the three parts of the table, the data and its possible significance will be discussed first, then some overall conclusions will be made, and finally some recommendations for future work will be offered.

  8. Commercial potential of natural gas storage in lined rock caverns (LRC)

    SciTech Connect (OSTI)

    1999-11-01

    The geologic conditions in many regions of the United States will not permit the development of economical high-deliverability gas storage in salt caverns. These regions include the entire Eastern Seaboard; several northern states, notably Minnesota and Wisconsin; many of the Rocky Mountain States; and most of the Pacific Northwest. In late 1997, the United States Department of Energy (USDOE) Federal Energy Technology Center engaged Sofregaz US to investigate the commercialization potential of natural gas storage in Lined Rock Caverns (LRC). Sofregaz US teamed with Gaz de France and Sydkraft, who had formed a consortium, called LRC, to perform the study for the USDOE. Underground storage of natural gas is generally achieved in depleted oil and gas fields, aquifers, and solution-mined salt caverns. These storage technologies require specific geologic conditions. Unlined rock caverns have been used for decades to store hydrocarbons - mostly liquids such as crude oil, butane, and propane. The maximum operating pressure in unlined rock caverns is limited, since the host rock is never entirely impervious. The LRC technology allows a significant increase in the maximum operating pressure over the unlined storage cavern concept, since the gas in storage is completely contained with an impervious liner. The LRC technology has been under development in Sweden by Sydkraft since 1987. The development process has included extensive technical studies, laboratory testing, field tests, and most recently includes a storage facility being constructed in southern Sweden (Skallen). The LRC development effort has shown that the concept is technically and economically viable. The Skallen storage facility will have a rock cover of 115 meters (375 feet), a storage volume of 40,000 cubic meters (250,000 petroleum barrels), and a maximum operating pressure of 20 MPa (2,900 psi). There is a potential for commercialization of the LRC technology in the United States. Two regions were studied in some detail - the Northeast and the Southeast. The investment cost for an LRC facility in the Northeast is approximately $182 million and $343 million for a 2.6-billion cubic foot (bcf) working gas facility and a 5.2-bcf working gas storage facility, respectively. The relatively high investment cost is a strong function of the cost of labor in the Northeast. The labor union-related rules and requirements in the Northeast result in much higher underground construction costs than might result in Sweden, for example. The LRC technology gas storage service is compared to other alternative technologies. The LRC technology gas storage service was found to be competitive with other alternative technologies for a variety of market scenarios.

  9. FIELD-SCALE EFFECTIVE MATRIX DIFFUSION COEFFICIENT FOR FRACTURED ROCK:RESULTS FROM LITERATURE SURVEY

    SciTech Connect (OSTI)

    Q. Zhou; Hui-Hai Liu; F.J. Molz; Y. Zhang; G.S. Bodvarsson

    2005-04-08

    Matrix diffusion is an important mechanism for solute transport in fractured rock. We recently conducted a literature survey on the effective matrix diffusion coefficient, D{sub m}{sup e}, a key parameter for describing matrix diffusion processes at the field scale. Forty field tracer tests at 15 fractured geologic sites were surveyed and selected for the study, based on data availability and quality. Field-scale D{sub m}{sup e} values were calculated, either directly using data reported in the literature or by reanalyzing the corresponding field tracer tests. Surveyed data indicate that the effective-matrix-diffusion-coefficient factor F{sub D} (defined as the ratio of D{sub m}{sup e} to the lab-scale matrix diffusion coefficient [D{sub m}] of the same tracer) is generally larger than one, indicating that the effective matrix diffusion coefficient in the field is comparatively larger than the matrix diffusion coefficient at the rock-core scale. This larger value can be attributed to the many mass-transfer processes at different scales in naturally heterogeneous, fractured rock systems. Furthermore, we observed a moderate trend toward systematic increase in the F{sub D} value with observation scale, indicating that the effective matrix diffusion coefficient is likely to be statistically scale dependent. The F{sub D} value ranges from 1 to 10,000 for observation scales from 5 to 2,000 m. At a given scale, the F{sub D} value varies by two orders of magnitude, reflecting the influence of differing degrees of fractured rock heterogeneity at different sites. In addition, the surveyed data indicate that field-scale longitudinal dispersivity generally increases with observation scale, which is consistent with previous studies. The scale-dependent field-scale matrix diffusion coefficient (and dispersivity) may have significant implications for assessing long-term, large-scale radionuclide and contaminant transport events in fractured rock, both for nuclear waste disposal and contaminant remediation.

  10. GEOCHEMICAL INVESTIGATIONS OF CO?-BRINE-ROCK INTERACTIONS OF THE KNOX GROUP IN THE ILLINOIS BASIN

    SciTech Connect (OSTI)

    Yoksoulian, Lois; Berger, Peter; Freiburg, Jared; Butler, Shane; Leetaru, Hannes

    2014-09-30

    Increased output of greenhouse gases, particularly carbon dioxide (CO?), into the atmosphere from anthropogenic sources is of great concern. A potential technology to reduce CO? emissions is geologic carbon sequestration. This technology is currently being evaluated in the United States and throughout the world. The geology of the Illinois Basin exhibits outstanding potential as a carbon sequestration target, as demonstrated by the ongoing Illinois Basin – Decatur Project that is using the Mt. Simon Sandstone reservoir and Eau Claire Shale seal system to store and contain 1 million tonnes of CO?. The Knox Group-Maquoketa Shale reservoir and seal system, located stratigraphically above the Mt. Simon Sandstone-Eau Claire Shale reservoir and seal system, has little economic value as a resource for fossil fuels or as a potable water source, making it ideal as a potential carbon sequestration target. In order for a reservoir-seal system to be effective, it must be able to contain the injected CO? without the potential for the release of harmful contaminants liberated by the reaction between CO?-formation fluids and reservoir and seal rocks. This study examines portions of the Knox Group (Potosi Dolomite, Gunter Sandstone, New Richmond Sandstone) and St. Peter Sandstone, and Maquoketa Shale from various locations around the Illinois Basin. A total of 14 rock and fluid samples were exposed to simulated sequestration conditions (9101–9860 kPa [1320–1430 psi] and 32°–42°C [90°– 108°F]) for varying amounts of time (6 hours to 4 months). Knox Group reservoir rocks exhibited dissolution of dolomite in the presence of CO? as indicated by petrographic examination, X-ray diffraction analysis, and fluid chemistry analysis. These reactions equilibrated rapidly, and geochemical modeling confirmed that these reactions reached equilibrium within the time frames of the experiments. Pre-reaction sample mineralogy and postreaction fluid geochemistry from this study suggests only limited potential for the release of United States Environmental Protection Agency regulated inorganic contaminants into potable water sources. Short-term core flood experiments further verify that the carbonate reactions occurring in Knox Group reservoir samples reach equilibrium rapidly. The core flood experiments also lend insight to pressure changes that may occur during CO? injection. The Maquoketa Shale experiments reveal that this rock is initially chemically reactive when in contact with CO? and brine. However, due to the conservative nature of silicate and clay reaction kinetics and the rapid equilibration of carbonate reactions that occur in the shale, these reactions would not present a significant risk to the competency of the shale as an effective seal rock.

  11. Actualistic and Geochemical Modeling of Reservoir Rock, CO2 and Formation Fluid Interaction, Citronelle Oil Field, Alabama

    SciTech Connect (OSTI)

    Weislogel, Amy

    2014-01-31

    This report includes description of the Citronelle field study area and the work carried out in the project to characterize the geology and composition of reservoir rock material and to collect an analyze the geochemical composition of produced fluid waters from the Citronelle field. Reservoir rock samples collected from well bore core were made into thin-sections and assessed for textural properties, including pore types and porosity distribution. Compositional framework grain modal data were collected via point-counting, and grain and cement mineralogy was assessed using SEM-EDS. Geochemistry of fluid samples is described and modeled using PHREEQC. Composition of rock and produced fluids were used as inputs for TOUGHREACT reactive transport modeling, which determined the rock-fluid system was in disequilibrium.

  12. Geologic Sequestration The National Energy Technology Laboratory...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the CO 2 . A properly selected site will have an impermeable trapping layer, called a "cap rock," above the porous reservoir holding the CO 2 . The integrity of the cap rock is...

  13. Raman scattering as a tool for the evaluation of strain in GaN/AlN quantum dots: The effect of capping

    SciTech Connect (OSTI)

    Cros, A.; Cantarero, A.; Garro, N.; Coraux, J.; Daudin, B.

    2007-10-15

    The strain state of GaN/AlN quantum dots grown on 6H-SiC has been investigated as a function of AlN capping thickness by three different techniques. On the one hand, resonant Raman scattering allowed the detection of the A{sub 1}(LO) quasiconfined mode. It was found that its frequency increases with AlN deposition, while its linewidth did not evolve significantly. Available experiments of multiwavelength anomalous diffraction and diffraction anomalous fine structure on the same samples provided the determination of the wurtzite lattice parameters a and c of the quantum dots. A very good agreement is found between resonant Raman scattering and x-ray measurements, especially concerning the in-plane strain state. The results demonstrate the adequacy of Raman scattering, in combination with the deformation potential and biaxial approximations, to determine quantitatively values of strain in GaN quantum dot layers.

  14. The thin section rock physics: Modeling and measurement of seismic wave velocity on the slice of carbonates

    SciTech Connect (OSTI)

    Wardaya, P. D. Noh, K. A. B. M. Yusoff, W. I. B. W.; Ridha, S.; Nurhandoko, B. E. B.

    2014-09-25

    This paper discusses a new approach for investigating the seismic wave velocity of rock, specifically carbonates, as affected by their pore structures. While the conventional routine of seismic velocity measurement highly depends on the extensive laboratory experiment, the proposed approach utilizes the digital rock physics view which lies on the numerical experiment. Thus, instead of using core sample, we use the thin section image of carbonate rock to measure the effective seismic wave velocity when travelling on it. In the numerical experiment, thin section images act as the medium on which wave propagation will be simulated. For the modeling, an advanced technique based on artificial neural network was employed for building the velocity and density profile, replacing image's RGB pixel value with the seismic velocity and density of each rock constituent. Then, ultrasonic wave was simulated to propagate in the thin section image by using finite difference time domain method, based on assumption of an acoustic-isotropic medium. Effective velocities were drawn from the recorded signal and being compared to the velocity modeling from Wyllie time average model and Kuster-Toksoz rock physics model. To perform the modeling, image analysis routines were undertaken for quantifying the pore aspect ratio that is assumed to represent the rocks pore structure. In addition, porosity and mineral fraction required for velocity modeling were also quantified by using integrated neural network and image analysis technique. It was found that the Kuster-Toksoz gives the closer prediction to the measured velocity as compared to the Wyllie time average model. We also conclude that Wyllie time average that does not incorporate the pore structure parameter deviates significantly for samples having more than 40% porosity. Utilizing this approach we found a good agreement between numerical experiment and theoretically derived rock physics model for estimating the effective seismic wave velocity of rock.

  15. Short and Long-Term Perspectives: The Impact on Low-Income Consumers of Forecasted Energy Price Increases in 2008 and A Cap & Trade Carbon Policy in 2030

    SciTech Connect (OSTI)

    Eisenberg, Joel Fred

    2008-01-01

    The Department of Energy's Energy Information Administration (EIA) recently released its short-term forecast for residential energy prices for the winter of 2007-2008. The forecast indicates increases in costs for low-income consumers in the year ahead, particularly for those using fuel oil to heat their homes. In the following analysis, the Oak Ridge National Laboratory has integrated the EIA price projections with the Residential Energy Consumption Survey (RECS) for 2001 in order to project the impact of these price increases on the nation's low-income households by primary heating fuel type, nationally and by Census Region. The report provides an update of bill estimates provided in a previous study, "The Impact Of Forecasted Energy Price Increases On Low-Income Consumers" (Eisenberg, 2005). The statistics are intended for use by policymakers in the Department of Energy's Weatherization Assistance Program and elsewhere who are trying to gauge the nature and severity of the problems that will be faced by eligible low-income households during the 2008 fiscal year. In addition to providing expenditure forecasts for the year immediately ahead, this analysis uses a similar methodology to give policy makers some insight into one of the major policy debates that will impact low-income energy expenditures well into the middle decades of this century and beyond. There is now considerable discussion of employing a cap-and-trade mechanism to first limit and then reduce U.S. emissions of carbon into the atmosphere in order to combat the long-range threat of human-induced climate change. The Energy Information Administration has provided an analysis of projected energy prices in the years 2020 and 2030 for one such cap-and-trade carbon reduction proposal that, when integrated with the RECS 2001 database, provides estimates of how low-income households will be impacted over the long term by such a carbon reduction policy.

  16. ARRA Site Characterization Projects | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    are developing comprehensive data sets of formation characteristics (porosity, permeability, reservoir architecture, cap rock integrity, etc.) while also acquiring information...

  17. Improved characterization of reservoir behavior by integration of reservoir performances data and rock type distributions

    SciTech Connect (OSTI)

    Davies, D.K.; Vessell, R.K.; Doublet, L.E.

    1997-08-01

    An integrated geological/petrophysical and reservoir engineering study was performed for a large, mature waterflood project (>250 wells, {approximately}80% water cut) at the North Robertson (Clear Fork) Unit, Gaines County, Texas. The primary goal of the study was to develop an integrated reservoir description for {open_quotes}targeted{close_quotes} (economic) 10-acre (4-hectare) infill drilling and future recovery operations in a low permeability, carbonate (dolomite) reservoir. Integration of the results from geological/petrophysical studies and reservoir performance analyses provide a rapid and effective method for developing a comprehensive reservoir description. This reservoir description can be used for reservoir flow simulation, performance prediction, infill targeting, waterflood management, and for optimizing well developments (patterns, completions, and stimulations). The following analyses were performed as part of this study: (1) Geological/petrophysical analyses: (core and well log data) - {open_quotes}Rock typing{close_quotes} based on qualitative and quantitative visualization of pore-scale features. Reservoir layering based on {open_quotes}rock typing {close_quotes} and hydraulic flow units. Development of a {open_quotes}core-log{close_quotes} model to estimate permeability using porosity and other properties derived from well logs. The core-log model is based on {open_quotes}rock types.{close_quotes} (2) Engineering analyses: (production and injection history, well tests) Material balance decline type curve analyses to estimate total reservoir volume, formation flow characteristics (flow capacity, skin factor, and fracture half-length), and indications of well/boundary interference. Estimated ultimate recovery analyses to yield movable oil (or injectable water) volumes, as well as indications of well and boundary interference.

  18. Hot Dry Rock Geothermal Energy Development Program. Annual report, fiscal year 1979

    SciTech Connect (OSTI)

    Cremer, G.M.; Duffield, R.B.; Smith, M.C.; Wilson, M.G.

    1980-08-01

    The Fenton Hill Project is still the principal center for developing methods, equipment, and instrumentation for creating and utilizing HDR geothermal reservoirs. The search for a second site for a similar experimental system in a different geological environment has been intensified, as have the identification and characterization of other HDR areas that may prove suitable for either experimental or commercial development. The Phase I fracture system was enlarged during FY79. Drilling of the injection well of the Phase II system began at Fenton Hill in April 1979. Environmental monitoring of the Fenton Hill area continued through FY79. The environmental studies indicate that the hot dry rock operations have caused no significant environmental impact. Other supporting activities included rock physics, rock mechanics, fracture mapping, and instrumentation development. Two closely related activities - evaluation of the potential HDR energy resource of the US and the selection of a site for development of a second experimental heat-extraction system generally similar to that at Fenton Hill - have resulted in the collection of geology, hydrology, and heat-flow data on some level of field activity in 30 states. The resource-evaluation activity included reconnaissance field studies and a listing and preliminary characterization of US geothermal areas in which HDR energy extraction methods may be applicable. The selection of Site 2 has taken into account such legal, institutional, and economic factors as land ownership and use, proximity to possible users, permitting and licensing requirements and procedures, environmental issues, areal extent of the geothermal area, and visibility to and apparent interest by potential industrial developers.

  19. Stress-dependent permeability of fractured rock masses: A numerical study

    SciTech Connect (OSTI)

    Min, Ki-Bok; Rutqvist, J.; Tsang, Chin-Fu; Jing, Lanru

    2004-04-30

    We investigate the stress-dependent permeability issue in fractured rock masses considering the effects of nonlinear normal deformation and shear dilation of fractures using a two-dimensional distinct element method program, UDEC, based on a realistic discrete fracture network realization. A series of ''numerical'' experiments were conducted to calculate changes in the permeability of simulated fractured rock masses under various loading conditions. Numerical experiments were conducted in two ways: (1) increasing the overall stresses with a fixed ratio of horizontal to vertical stresses components; and (2) increasing the differential stresses (i.e., the difference between the horizontal and vertical stresses) while keeping the magnitude of vertical stress constant. These numerical experiments show that the permeability of fractured rocks decreases with increased stress magnitudes when the stress ratio is not large enough to cause shear dilation of fractures, whereas permeability increases with increased stress when the stress ratio is large enough. Permeability changes at low stress levels are more sensitive than at high stress levels due to the nonlinear fracture normal stress-displacement relation. Significant stress-induced channeling is observed as the shear dilation causes the concentration of fluid flow along connected shear fractures. Anisotropy of permeability emerges with the increase of differential stresses, and this anisotropy can become more prominent with the influence of shear dilation and localized flow paths. A set of empirical equations in closed-form, accounting for both normal closure and shear dilation of the fractures, is proposed to model the stress-dependent permeability. These equations prove to be in good agreement with the results obtained from our numerical experiments.

  20. High temperature thermoelectric properties of rock-salt structure PbS

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Parker, David S.; Singh, David J.

    2013-12-18

    We present an analysis of the high temperature transport properties of rock-salt structure PbS, a sister compound to the better studied lead chalcogenides PbSe and PbTe. In this study, we find thermopower magnitudes exceeding 200 V/K in a wide doping range for temperatures of 800 K and above. Based on these calculations, and an analysis of recent experimental work we find that this material has a potential for high thermoelectric performance. Also, we find favorable mechanical properties, based on an analysis of published data.

  1. Scientists to Meet in Carlsbad, NM for Hard Rock Lab Task Force

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Scientists From Nine Countries to Converge On Carlsbad for Technical Meeting CARLSBAD, N.M., February 7, 2000 - Scientists from nine countries will converge on this southeastern New Mexico city February 7-10 to share their views during the 13 th Äspö Hard Rock Laboratory Task Force Meeting on Modelling of Groundwater Flow and Transport of Solutes. "Carlsbad is quickly becoming recognized as the international center for repository technology," said Dr. Inés Triay, manager of the U.S.

  2. Mafic and ultramafic rocks of the northwestern Brooks Range of Alaska produce nearly symmetric gravity anomalies

    SciTech Connect (OSTI)

    Morin, R.L. )

    1993-04-01

    An arc of mafic and ultramafic rocks is mapped from Asik Mountain to Siniktanneyak Mountain in the northwestern Brooks Range of Alaska. Gravity data, although not very detailed, have been collected over the region and show some very conspicuous circular or oval gravity highs over portions of the mapped mafic-ultramafic bodies. Bodies which have large associated gravity anomalies are Asik Mountain (80 mGal), Avon Hills (20 mGal), Misheguk Mountain (30 mGal), and Siniktanneyak Mountain (20 mGal). Gabbros of the Siniktanneyak Mountain complex, where the gravity coverage is best, have densities of about 3.0 g/cm[sup 3] while the densities of the surrounding sedimentary rocks are about 2.6 g/cm[sup 3]. Volcanic rocks in the area have average densities of about 2.7 g/cm[sup 3]. Three-dimensional modeling indicates that the largest anomaly, on the southwestern part of the complex, could be caused by a polygonal prism of gabbro with vertical sides, about 6 km across and about 4.5 km deep. A smaller lobe of the anomaly on the northeast of the complex could be caused by another oblong polygonal prism about 4 km long and 2 km wide trending northeast and about 1.5 km deep. Modeling this anomaly with densities lower than gabbro would require greater thicknesses to produce the same anomaly. Modeling each anomaly along this arc in 2 1/2-dimensions shows many possible solutions using different body shapes and different density contrasts. There are several other gravity anomalies in this vicinity which could represent unexposed high density rocks. One such anomaly is in the Maiyumerak Mountains northeast of Asik Mountain (30 mGal). Another anomaly is to the northwest of Asik Mountain (20 mGal). There is also an anomaly at Uchugrak (20 mGal) east of Avan Hills. Although many of the anomalies in this region are poorly controlled, an attempt has been made to interpret the data to show possible solutions.

  3. Advanced Characterization of Fractured Reservoirs in Carbonate Rocks: The Michigan Basin

    SciTech Connect (OSTI)

    Wood, James R.; Harrison, William B.

    2000-10-24

    The main objective of this project is for a university-industry consortium to develop a comprehensive model for fracture carbonate reservoirs based on the ''data cube'' concept using the Michigan Basin as a prototype. This project combined traditional historical data with 2D and 3D seismic data as well as data from modern logging tools in a novel way to produce a new methodology for characterizing fractured reservoirs in carbonate rocks. Advanced visualization software was used to fuse the data and to image it on a variety of scales, ranging from basin-scale to well-scales.

  4. THERMO-HYDRO-MECHANICAL MODELING OF WORKING FLUID INJECTION AND THERMAL ENERGY EXTRACTION IN EGS FRACTURES AND ROCK MATRIX

    SciTech Connect (OSTI)

    Robert Podgorney; Chuan Lu; Hai Huang

    2012-01-01

    Development of enhanced geothermal systems (EGS) will require creation of a reservoir of sufficient volume to enable commercial-scale heat transfer from the reservoir rocks to the working fluid. A key assumption associated with reservoir creation/stimulation is that sufficient rock volumes can be hydraulically fractured via both tensile and shear failure, and more importantly by reactivation of naturally existing fractures (by shearing), to create the reservoir. The advancement of EGS greatly depends on our understanding of the dynamics of the intimately coupled rock-fracture-fluid-heat system and our ability to reliably predict how reservoirs behave under stimulation and production. Reliable performance predictions of EGS reservoirs require accurate and robust modeling for strongly coupled thermal-hydrological-mechanical (THM) processes. Conventionally, these types of problems have been solved using operator-splitting methods, usually by coupling a subsurface flow and heat transport simulators with a solid mechanics simulator via input files. An alternative approach is to solve the system of nonlinear partial differential equations that govern multiphase fluid flow, heat transport, and rock mechanics simultaneously, using a fully coupled, fully implicit solution procedure, in which all solution variables (pressure, enthalpy, and rock displacement fields) are solved simultaneously. This paper describes numerical simulations used to investigate the poro- and thermal- elastic effects of working fluid injection and thermal energy extraction on the properties of the fractures and rock matrix of a hypothetical EGS reservoir, using a novel simulation software FALCON (Podgorney et al., 2011), a finite element based simulator solving fully coupled multiphase fluid flow, heat transport, rock deformation, and fracturing using a global implicit approach. Investigations are also conducted on how these poro- and thermal-elastic effects are related to fracture permeability evolution.

  5. Multiscale heterogeneity characterization of tidal channel, tidal delta and foreshore facies, Almond Formation outcrops, Rock Springs uplift, Wyoming

    SciTech Connect (OSTI)

    Schatzinger, R.A.; Tomutsa, L.

    1997-08-01

    In order to accurately predict fluid flow within a reservoir, variability in the rock properties at all scales relevant to the specific depositional environment needs to be taken into account. The present work describes rock variability at scales from hundreds of meters (facies level) to millimeters (laminae) based on outcrop studies of the Almond Formation. Tidal channel, tidal delta and foreshore facies were sampled on the eastern flank of the Rock Springs uplift, southeast of Rock Springs, Wyoming. The Almond Fm. was deposited as part of a mesotidal Upper Cretaceous transgressive systems tract within the greater Green River Basin. Bedding style, lithology, lateral extent of beds of bedsets, bed thickness, amount and distribution of depositional clay matrix, bioturbation and grain sorting provide controls on sandstone properties that may vary more than an order of magnitude within and between depositional facies in outcrops of the Almond Formation. These features can be mapped on the scale of an outcrop. The products of diagenesis such as the relative timing of carbonate cement, scale of cemented zones, continuity of cemented zones, selectively leached framework grains, lateral variability of compaction of sedimentary rock fragments, and the resultant pore structure play an equally important, although less predictable role in determining rock property heterogeneity. A knowledge of the spatial distribution of the products of diagenesis such as calcite cement or compaction is critical to modeling variation even within a single facies in the Almond Fin. because diagenesis can enhance or reduce primary (depositional) rock property heterogeneity. Application of outcrop heterogeneity models to the subsurface is greatly hindered by differences in diagenesis between the two settings. The measurements upon which this study is based were performed both on drilled outcrop plugs and on blocks.

  6. [Investigation of ultrasonic wave interactions with fluid-saturated porous rocks]. [Annual report

    SciTech Connect (OSTI)

    Adler, L.

    1992-07-01

    During the last two years we have continued our investigation of ultrasonic wave propagation in fluid-filled porous materials. First, we studied the feasibility of using different surface modes to characterize both synthetic and natural rocks. We introduced a novel experimental technique based on the direct generation of surface waves by edge excitation. We used two low-frequency (100--500 kHz) shear transducers in pitch-catch mode to launch and receive the ultrasonic surface wave. The contact transducers were coupled to the opposite edges of the porous specimens with normal polarization relative to the surface. The same technique was successfully used to generate Rayleigh-type surface modes on the free surface of both dry and water-saturated specimens, as well as Stoneley-type interface modes on the fluid-loaded surfaces of immersed samples. Our main achievement in this area is the realization that, due to surface tension, practically closed-pore boundary conditions can prevail on the free surface of a water-saturated rock for completely open pores. As a result, the velocity of the true surface mode might be much lower than the Rayleigh velocity of the dry skeleton.

  7. (Investigation of ultrasonic wave interactions with fluid-saturated porous rocks)

    SciTech Connect (OSTI)

    Adler, L.

    1992-01-01

    During the last two years we have continued our investigation of ultrasonic wave propagation in fluid-filled porous materials. First, we studied the feasibility of using different surface modes to characterize both synthetic and natural rocks. We introduced a novel experimental technique based on the direct generation of surface waves by edge excitation. We used two low-frequency (100--500 kHz) shear transducers in pitch-catch mode to launch and receive the ultrasonic surface wave. The contact transducers were coupled to the opposite edges of the porous specimens with normal polarization relative to the surface. The same technique was successfully used to generate Rayleigh-type surface modes on the free surface of both dry and water-saturated specimens, as well as Stoneley-type interface modes on the fluid-loaded surfaces of immersed samples. Our main achievement in this area is the realization that, due to surface tension, practically closed-pore boundary conditions can prevail on the free surface of a water-saturated rock for completely open pores. As a result, the velocity of the true surface mode might be much lower than the Rayleigh velocity of the dry skeleton.

  8. Hot dry rock geothermal energy for U.S. electric utilities. Draft final report

    SciTech Connect (OSTI)

    Not Available

    1993-06-01

    In order to bring an electric utility component into the study of hot dry rock geothermal energy called for in the Energy Policy Act of 1992 (EPAct), EPRI organized a one-day conference in Philadelphia on January 14,1993. The conference was planned as the first day of a two-day sequence, by coordinating with the U.S. Geological Survey (USGS) and the U.S. Department of Energy (DOE). These two federal agencies were charged under EPAct with the development of a report on the potential for hot dry rock geothermal energy production in the US, especially the eastern US. The USGS was given lead responsibility for a report to be done in association with DOE. The EPRI conference emphasized first the status of technology development and testing in the U.S. and abroad, i.e., in western Europe, Russia and Japan. The conference went on to address the extent of knowledge regarding the resource base in the US, especially in the eastern half of the country, and then to address some practical business aspects of organizing projects or industries that could bring these resources into use, either for thermal applications or for electric power generation.

  9. Numerical simulation of gas flow through unsaturated fractured rock at Yucca Mountain, Nevada

    SciTech Connect (OSTI)

    Cooper, C.A.

    1990-01-01

    Numerical analysis is used to identify the physical phenomena associated with barometrically driven gas (air and water vapor) flow through unsaturated fractured rock at Yucca Mountain, Nevada. Results from simple finite difference simulations indicate that for a fractured rock scenario, the maximum velocity of air out of an uncased 10 cm borehole is 0.002 m s{sub {minus}1}. An equivalent porous medium (EPM) model was incorporated into a multiphase, multicomponent simulator to test more complex conceptual models. Results indicate that for a typical June day, a diurnal pressure wave propagates about 160 m into the surrounding Tiva Canyon hydrogeologic unit. Dry air that enters the formation evaporates water around the borehole which reduces capillary pressure. Multiphase countercurrent flow develops in the vicinity of the hole; the gas phase flows into the formation while the liquid phase flows toward the borehole. The effect occurs within 0.5 m of the borehole. The amount of water vapor leaving the formation during 1 day is 900 cm{sup 3}. This is less than 0.1% of the total recharge into the formation, suggesting that the barometric effect may be insignificant in drying the unsaturated zone. However, gas phase velocities out of the borehole (3 m s{sup {minus}1}), indicating that observed flow rates from wells along the east flank of Yucca Mountain were able to be simulated with a barometric model.

  10. Rock matrix and fracture analysis of flow in western tight gas sands: Annual report, Phase 3

    SciTech Connect (OSTI)

    Dandge, V.; Graham, M.; Gonzales, B.; Coker, D.

    1987-12-01

    Tight gas sands are a vast future source of natural gas. These sands are characterized as having very low porosity and permeability. The main resource development problem is efficiently extracting the gas from the reservoir. Future production depends on a combination of gas price and technological advances. Gas production can be enhanced by fracturing. Studies have shown that many aspects of fracture design and gas production are influenced by properties of the rock matrix. Computer models for stimulation procedures require accurate knowledge of flow properties of both the rock matrix and the fractured regions. In the proposed work, these properties will be measured along with advanced core analysis procedure aimed at understanding the relationship between pore structure and properties. The objective of this project is to develop reliable core analysis techniques for measuring the petrophysical properties of tight gas sands. Recent research has indicated that the flow conditions in the reservoir can be greatly enhanced by the presence of natural fractures, which serve as a transport path for gas from the less permeable matrix. The study is mainly concerned with the dependence of flow in tight gas matrix and healed tectonic fractures on water saturation and confining pressure. This dependency is to be related to the detailed pore structure of tight sands as typified by cores recovered in the Multi-Well experiment. 22 refs., 34 figs., 9 tabs.

  11. Computational Modeling of Fluid Flow through a Fracture in Permeable Rock

    SciTech Connect (OSTI)

    Crandall, Dustin; Ahmadi, Goodarz; Smith, Duane H

    2010-01-01

    Laminar, single-phase, finite-volume solutions to the Navier–Stokes equations of fluid flow through a fracture within permeable media have been obtained. The fracture geometry was acquired from computed tomography scans of a fracture in Berea sandstone, capturing the small-scale roughness of these natural fluid conduits. First, the roughness of the two-dimensional fracture profiles was analyzed and shown to be similar to Brownian fractal structures. The permeability and tortuosity of each fracture profile was determined from simulations of fluid flow through these geometries with impermeable fracture walls. A surrounding permeable medium, assumed to obey Darcy’s Law with permeabilities from 0.2 to 2,000 millidarcies, was then included in the analysis. A series of simulations for flows in fractured permeable rocks was performed, and the results were used to develop a relationship between the flow rate and pressure loss for fractures in porous rocks. The resulting frictionfactor, which accounts for the fracture geometric properties, is similar to the cubic law; it has the potential to be of use in discrete fracture reservoir-scale simulations of fluid flow through highly fractured geologic formations with appreciable matrix permeability. The observed fluid flow from the surrounding permeable medium to the fracture was significant when the resistance within the fracture and the medium were of the same order. An increase in the volumetric flow rate within the fracture profile increased by more than 5% was observed for flows within high permeability-fractured porous media.

  12. An experimental and theoretical study to relate uncommon rock/fluid properties to oil recovery. Final report

    SciTech Connect (OSTI)

    Watson, R.

    1995-07-01

    Waterflooding is the most commonly used secondary oil recovery technique. One of the requirements for understanding waterflood performance is a good knowledge of the basic properties of the reservoir rocks. This study is aimed at correlating rock-pore characteristics to oil recovery from various reservoir rock types and incorporating these properties into empirical models for Predicting oil recovery. For that reason, this report deals with the analyses and interpretation of experimental data collected from core floods and correlated against measurements of absolute permeability, porosity. wettability index, mercury porosimetry properties and irreducible water saturation. The results of the radial-core the radial-core and linear-core flow investigations and the other associated experimental analyses are presented and incorporated into empirical models to improve the predictions of oil recovery resulting from waterflooding, for sandstone and limestone reservoirs. For the radial-core case, the standardized regression model selected, based on a subset of the variables, predicted oil recovery by waterflooding with a standard deviation of 7%. For the linear-core case, separate models are developed using common, uncommon and combination of both types of rock properties. It was observed that residual oil saturation and oil recovery are better predicted with the inclusion of both common and uncommon rock/fluid properties into the predictive models.

  13. Multi-Attribute Seismic/Rock Physics Approach to Characterizing Fractured Reservoirs

    SciTech Connect (OSTI)

    Gary Mavko

    2004-11-30

    Most current seismic methods to seismically characterize fractures in tight reservoirs depend on a few anisotropic wave propagation signatures that can arise from aligned fractures. While seismic anisotropy can be a powerful fracture diagnostic, a number of situations can lessen its usefulness or introduce interpretation ambiguities. Fortunately, laboratory and theoretical work in rock physics indicates that a much broader spectrum of fracture seismic signatures can occur, including a decrease in P- and S-wave velocities, a change in Poisson's ratio, an increase in velocity dispersion and wave attenuation, as well as well as indirect images of structural features that can control fracture occurrence. The goal of this project was to demonstrate a practical interpretation and integration strategy for detecting and characterizing natural fractures in rocks. The approach was to exploit as many sources of information as possible, and to use the principles of rock physics as the link among seismic, geologic, and log data. Since no single seismic attribute is a reliable fracture indicator in all situations, the focus was to develop a quantitative scheme for integrating the diverse sources of information. The integrated study incorporated three key elements: The first element was establishing prior constraints on fracture occurrence, based on laboratory data, previous field observations, and geologic patterns of fracturing. The geologic aspects include analysis of the stratigraphic, structural, and tectonic environments of the field sites. Field observations and geomechanical analysis indicates that fractures tend to occur in the more brittle facies, for example, in tight sands and carbonates. In contrast, strain in shale is more likely to be accommodated by ductile flow. Hence, prior knowledge of bed thickness and facies architecture, calibrated to outcrops, are powerful constraints on the interpreted fracture distribution. Another important constraint is that fracturing is likely to be more intense near faults--sometimes referred to as the damaged zone. Yet another constraint, based on world-wide observations, is that the maximum likely fracture density increases with depth in a well-defined way. Defining these prior constrains has several benefits: they lead to a priori probability distributions of fractures, that are important for objective statistical integration; they limit the number of geologic hypotheses that need to be theoretically modeled; they provide plausible models for fracture distributions below the seismic resolution. The second element was theoretical rock physics modeling of optimal seismic attributes, including offset and azimuth dependence of traveltime, amplitude, and impedance signatures of anisotropic fractured rocks. The suggested workflow is to begin with an elastic earth model, based on well logs, theoretically add fractures to the likely facies as defined by the geologic prior information, and then compute synthetic seismic traces and attributes, including variations in P and S-wave velocities, Poisson's ratio, reflectivity, travel time, attenuation, and anisotropies of these parameters. This workflow is done in a Monte-Carlo fashion, yielding ranges of expected fracture signatures, and allowing realistic assessments of uncertainty to be honored. The third element was statistical integration of the geophysical data and prior constraints to map fracture intensity and orientations, along with uncertainties. A Bayesian framework was developed that allowed systematic integration of the prior constraints, the theoretical relations between fractures and their seismic signatures, and the various observed seismic observations. The integration scheme was successfully applied on an East Texas field site. The primary benefit from the study was the optimization and refinement of practical workflows for improved geophysical characterization of natural fractures and for quantifying the uncertainty of these interpretations. By presenting a methodology for integrating various types of information, the workflow will

  14. U.S. National Committee for Rock Mechanics; and Conceptual model of fluid infiltration in fractured media. Project summary, July 28, 1997--July 27, 1998

    SciTech Connect (OSTI)

    1998-09-01

    The title describes the two tasks summarized in this report. The remainder of the report contains information on meetings held or to be held on the subjects. The US National Committee for Rock Mechanics (USNC/RM) provides for US participation in international activities in rock mechanics, principally through adherence to the International Society for Rock Mechanics (ISRM). It also keeps the US rock mechanics community informed about new programs directed toward major areas of national concern in which rock mechanics problems represent critical or limiting factors, such as energy resources, excavation, underground storage and waste disposal, and reactor siting. The committee also guides or produces advisory studies and reports on problem areas in rock mechanics. A new panel under the auspices of the US National Committee for Rock Mechanics has been appointed to conduct a study on Conceptual Models of Fluid Infiltration in Fractured Media. The study has health and environmental applications related to the underground flow of pollutants through fractured rock in and around mines and waste repositories. Support of the study has been received from the US Nuclear Regulatory Commission and the Department of Energy`s Yucca Mountain Project Office. The new study builds on the success of a recent USNC/RM report entitled Rock Fractures and Fluid Flow: Contemporary Understanding and Applications (National Academy Press, 1996, 551 pp.). A summary of the new study is provided.

  15. Fractured rock stress-permeability relationships from in situ data and effects of temperature and chemical-mechanical couplings

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rutqvist, J.

    2014-09-19

    The purpose of this paper is to (i) review field data on stress-induced permeability changes in fractured rock; (ii) describe estimation of fractured rock stress-permeability relationships through model calibration against such field data; and (iii) discuss observations of temperature and chemically mediated fracture closure and its effect on fractured rock permeability. The field data that are reviewed include in situ block experiments, excavation-induced changes in permeability around tunnels, borehole injection experiments, depth (and stress) dependent permeability, and permeability changes associated with a large-scale rock-mass heating experiment. Data show how the stress-permeability relationship of fractured rock very much depends on localmore » in situ conditions, such as fracture shear offset and fracture infilling by mineral precipitation. Field and laboratory experiments involving temperature have shown significant temperature-driven fracture closure even under constant stress. Such temperature-driven fracture closure has been described as thermal overclosure and relates to better fitting of opposing fracture surfaces at high temperatures, or is attributed to chemically mediated fracture closure related to pressure solution (and compaction) of stressed fracture surface asperities. Back-calculated stress-permeability relationships from field data may implicitly account for such effects, but the relative contribution of purely thermal-mechanical and chemically mediated changes is difficult to isolate. Therefore, it is concluded that further laboratory and in situ experiments are needed to increase the knowledge of the true mechanisms behind thermally driven fracture closure, and to further assess the importance of chemical-mechanical coupling for the long-term evolution of fractured rock permeability.« less

  16. Determination of Transport Properties From Flowing Fluid Temperature LoggingIn Unsaturated Fractured Rocks: Theory And Semi-Analytical Solution

    SciTech Connect (OSTI)

    Mukhopadhyay, Sumit; Tsang, Yvonne W.

    2008-08-01

    Flowing fluid temperature logging (FFTL) has been recently proposed as a method to locate flowing fractures. We argue that FFTL, backed up by data from high-precision distributed temperature sensors, can be a useful tool in locating flowing fractures and in estimating the transport properties of unsaturated fractured rocks. We have developed the theoretical background needed to analyze data from FFTL. In this paper, we present a simplified conceptualization of FFTL in unsaturated fractured rock, and develop a semianalytical solution for spatial and temporal variations of pressure and temperature inside a borehole in response to an applied perturbation (pumping of air from the borehole). We compare the semi-analytical solution with predictions from the TOUGH2 numerical simulator. Based on the semi-analytical solution, we propose a method to estimate the permeability of the fracture continuum surrounding the borehole. Using this proposed method, we estimated the effective fracture continuum permeability of the unsaturated rock hosting the Drift Scale Test (DST) at Yucca Mountain, Nevada. Our estimate compares well with previous independent estimates for fracture permeability of the DST host rock. The conceptual model of FFTL presented in this paper is based on the assumptions of single-phase flow, convection-only heat transfer, and negligible change in system state of the rock formation. In a sequel paper [Mukhopadhyay et al., 2008], we extend the conceptual model to evaluate some of these assumptions. We also perform inverse modeling of FFTL data to estimate, in addition to permeability, other transport parameters (such as porosity and thermal conductivity) of unsaturated fractured rocks.

  17. Fractured rock stress-permeability relationships from in situ data and effects of temperature and chemical-mechanical couplings

    SciTech Connect (OSTI)

    Rutqvist, J.

    2014-09-19

    The purpose of this paper is to (i) review field data on stress-induced permeability changes in fractured rock; (ii) describe estimation of fractured rock stress-permeability relationships through model calibration against such field data; and (iii) discuss observations of temperature and chemically mediated fracture closure and its effect on fractured rock permeability. The field data that are reviewed include in situ block experiments, excavation-induced changes in permeability around tunnels, borehole injection experiments, depth (and stress) dependent permeability, and permeability changes associated with a large-scale rock-mass heating experiment. Data show how the stress-permeability relationship of fractured rock very much depends on local in situ conditions, such as fracture shear offset and fracture infilling by mineral precipitation. Field and laboratory experiments involving temperature have shown significant temperature-driven fracture closure even under constant stress. Such temperature-driven fracture closure has been described as thermal overclosure and relates to better fitting of opposing fracture surfaces at high temperatures, or is attributed to chemically mediated fracture closure related to pressure solution (and compaction) of stressed fracture surface asperities. Back-calculated stress-permeability relationships from field data may implicitly account for such effects, but the relative contribution of purely thermal-mechanical and chemically mediated changes is difficult to isolate. Therefore, it is concluded that further laboratory and in situ experiments are needed to increase the knowledge of the true mechanisms behind thermally driven fracture closure, and to further assess the importance of chemical-mechanical coupling for the long-term evolution of fractured rock permeability.

  18. Net Metering Policy Development and Distributed Solar Generation in Minnesota: Overview of Trends in Nationwide Policy Development and Implications of Increasing the Eligible System Size Cap

    SciTech Connect (OSTI)

    Doris, E.; Busche, S.; Hockett, S.

    2009-12-01

    The goal of the Minnesota net metering policy is to give the maximum possible encouragement to distributed generation assets, especially solar electric systems (MN 2008). However, according to a published set of best practices (NNEC 2008) that prioritize the maximum development of solar markets within states, the Minnesota policy does not incorporate many of the important best practices that may help other states transform their solar energy markets and increase the amount of grid-connected distributed solar generation assets. Reasons cited include the low system size limit of 40kW (the best practices document recommends a 2 MW limit) and a lack of language protecting generators from additional utility fees. This study was conducted to compare Minnesota's policies to national best practices. It provides an overview of the current Minnesota policy in the context of these best practices and other jurisdictions' net metering policies, as well as a qualitative assessment of the impacts of raising the system size cap within the policy based on the experiences of other states.

  19. Synthesis and investigation of optical properties of TOPO-capped CuInS{sub 2} semiconductor nanocrystal in the presence of different solvent

    SciTech Connect (OSTI)

    Asgary, Saeid; Mirabbaszadeh, Kavoos; Nayebi, Payman; Emadi, Hamid

    2014-03-01

    Graphical abstract: - Highlights: • TOPO-capped CuInS{sub 2} nanoparticles were synthesized by injection method. • Pure CuInS{sub 2} nanoparticle was obtained by injection in 200 °C. • The size, shape and optical properties of products were controlled. • Nanoparticles with size smaller than 10 nm and wurtzite phase was obtained. • The absorption and PL spectra of CuInS{sub 2} nanoparticles were tunable. - Abstract: In this work, synthesis of CuInS{sub 2} semiconductor nanoparticles by thermolysis of a mixed solution of CuAc, In(Ac){sub 3} and DDT in coordinating solvent and trioctylphosphine oxide (TOPO) as ligand was developed. CuInS{sub 2} nanoparticles with size of ?10 nm and nanorods were obtained and optical properties controlled by adjusting the reaction parameters such as temperature and time. Also the shape of nanoparticles was controlled by various solvents elaborately. The as-prepared nanoparticles were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Scanning electron microscopy (SEM), UV–vis absorption, and photoluminescence (PL) spectroscopy. With the use of different solvent different morphology obtained. In the presence of oleylamine/octadecene rectangle-like nanorods obtained while with the use of oleic acid sphere-like nanoparticles achieved.

  20. Case study of the 19 October 1989 polar-cap-absorption event using the imaging riometer for ionospheric studies. Master's thesis

    SciTech Connect (OSTI)

    Davis, T.C.

    1990-01-01

    A polar cap absorption (PCA) event, beginning on 19 October 1989, is examined using the Imaging Riometer for Ionospheric Studies (IRIS) developed at the Univ. of Maryland. IRIS is a 49-beam (7 x 7) phased-array 38.2 MHz radiowave imaging system and operating at Amundsen-Scott South Pole Station, Antarctica. After applying a low-pass (>10 minute) filter, we perform a cross-correlation between the central beam and the other beams in the array. From the cross-correlation analysis, we attempt to determine whether there is any delay of effects during event onset and early main phase (plateau) within the array. For most of the period studied, no delay was detected; i.e. features of each beam's absorption time series were essentially simultaneous. However, significant delays (approx. 2 minutes) occurred at the equatorward edge during a local absorption peak occurring just prior to magnetic local noon. The peak is coincident with short-term energetic particle flux enhancements detected by GOES-7. Two possible mechanisms are proposed: a local time variation of cutoff rigidities possibly associated with the relative position of the dayside cusp, and a short-term change in energetic particle rigidity spectrum.

  1. Geochemical character and origin of oils in Ordovician reservoir rock, Illinois and Indiana, USA

    SciTech Connect (OSTI)

    Guthrie, J.M.; Pratt, L.M.

    1995-11-01

    Twenty-three oils produced from reservoirs within the Ordovician Galena Group (Trenton equivalent) and one oil from the Mississippian Ste. Genevieve Limestone in the Illinois and Indiana portions of the Illinois basin are characterized. Two end-member oil groups (1) and (2) and one intermediate group (1A) are identified using conventional carbon isotopic analysis of whole and fractionated oils, gas chromatography (GC) of saturated hydrocarbon fractions, isotope-ratio-monitoring gas chromatography/mass spectrometry (irm-GC/MS) of n-alkanes ranging from C{sub 15} to C{sub 25}, and gas chromatography/mass spectrometry (GC/MS) of the aromatic hydrocarbon fractions. Group 1 is characterized by high odd-carbon predominance in mid-chain n-alkanes (C{sub 15}-C{sub 19}), low abundance Of C{sub 20+}, n-alkanes, and an absence of pristane and phytane. Group IA is characterized by slightly lower odd-carbon predominance of mid-chain n-alkanes, greater abundance of C{sub 20+} n-alkanes compared to group 1, and no pristane and phytane. Conventional correlations of oil to source rock based on carbon isotopic-type curves and hopane (m/z 191) and sterane (m/z 217) distributions are of limited use in distinguishing Ordovician-reservoired oil groups and determining their origin. Oil to source rock correlations using the distribution and carbon isotopic composition of n-alkanes and the m/z 133 chromatograms of n-alkylarenes show that groups 1 and 1A originated from strata of the Upper Ordovician Galena Group. Group 2 either originated solely from the Upper Ordovician Maquoketa Group or from a mixture of oils generated from the Maquoketa Group and the Galena Group. The Mississippian-reservoired oil most likely originated from the Devonian New Albany Group. The use of GC, irm-GC/MS, and GC/MS illustrates the value of integrated molecular and isotopic approaches for correlating oil groups with source rocks.

  2. Coupled In-Rock and In-Drift Hydrothermal Model Stuudy For Yucca Mountain

    SciTech Connect (OSTI)

    G. Danko; J. Birkholzer; D. Bahrami

    2006-12-18

    A thermal-hydrologic-natural-ventilation model is configured for simulating temperature, humidity, and condensate distributions in the coupled domains of the in-drift airspace and the near-field rockmass in the proposed Yucca Mountain repository. The multi-physics problem is solved with MULTIFLUX in which a lumped-parameter computational fluid dynamics model is iterated with TOUGH2. The solution includes natural convection, conduction, and radiation for heat as well as moisture convection and diffusion for moisture transport with half waste package scale details in the drift, and mountain-scale heat and moisture transport in the porous and fractured rock-mass. The method provides fast convergence on a personal computer computational platform. Numerical examples and comparison with a TOUGH2 based, integrated model are presented.

  3. Fractured rock modeling in the National Waste Terminal Storage Program: a review of requirements and status

    SciTech Connect (OSTI)

    St. John, C.; Krug, A.; Key, S.; Monsees, J.

    1983-05-01

    Generalized computer codes capable of forming the basis for numerical models of fractured rock masses are being used within the NWTS program. Little additional development of these codes is considered justifiable, except in the area of representation of discrete fractures. On the other hand, model preparation requires definition of medium-specific constitutive descriptions and site characteristics and is therefore legitimately conducted by each of the media-oriented projects within the National Waste Terminal Storage program. However, it is essential that a uniform approach to the role of numerical modeling be adopted, including agreement upon the contribution of modeling to the design and licensing process and the need for, and means of, model qualification for particular purposes. This report discusses the role of numerical modeling, reviews the capabilities of several computer codes that are being used to support design or performance assessment, and proposes a framework for future numerical modeling activities within the NWTS program.

  4. Quasistatic Shock Waves: A Mechanism for Nonuniform Compaction in Porous Rock

    SciTech Connect (OSTI)

    OLSSON,WILLIAM A.

    2000-09-08

    Recent studies have observed compaction zones pass through porous rock under axisymmetric compression. An initially thin, compacted layer appears at the yield point of the stress-strain curve and then grows by thickening in the direction of maximum compression at constant stress. Strain localization theory has been applied to compaction to explain the formation of these features. This paper describes the growth of the compaction zones, that is, the propagation of their boundaries, in terms of shock wave analysis. The ratio of the applied shortening rate to the velocity of the boundary is related to the porosity change across the boundary. Certain features of the stress-strain curve are explained by the model.

  5. Influence of shape and skin of matrix-rock blocks on pressure transients in fractured reservoirs

    SciTech Connect (OSTI)

    de Swaan, A.

    1986-01-01

    A formulation of pressure transients in terms of the intrinsic, or core, properties of the two media that compose the fractured reservoir, establishes the influence of these properties, and reciprocally, their corroboration from - the pressure-time relationship observed in well tests and interference tests. The following reservoir characteristics are analyzed: the area of fractures transverse to flow; the dimensions, shape and properties of rectangular parallelepiped matrix-rock blocks; and a permeability reduction in the blocks surface. A restatement of the so-called pseudo-steady state inter-media flow gives to parameters alfa and lambda in the theory of a previous study the physical meaning they lacked, and allows a direct determination of the blocks minimum dimension.

  6. (Relative mobilities and transport mechanisms of trace elements during contact metamorphism of carbonate rocks). Progress report

    SciTech Connect (OSTI)

    1980-01-01

    The main objective of this study is to investigate the relative mobilities and transport mechanisms of major, minor, and trace elements during the contact metamorphism of carbonate rocks. The large contrasts in chemical potentials of SiO/sub 2/, Al/sub 2/O/sub 3/, and CaO across a granitic pluton-limestone contact may induce metasomatism. In addition, rare earth and transition metal elements may act as tracers, and their redistribution during metamorphism may record convective cooling processes. The results of this study may have an application toward the problem of radioactive waste disposal and the degree to which radioactive nuclides may be expected to migrate during geologically significant periods of time.

  7. Chemical migration by contact metamorphism between pegmatite and country rocks: natural analogs for radionuclide migration

    SciTech Connect (OSTI)

    Laul, J.C.; Walker, R.J.; Shearer, C.K.; Papike, J.J.; Simon, S.B.

    1984-01-01

    Comparison of trace element signatures of country rocks as a function of distance from the contact with two pegmatites, Tin Mountain and Etta, in the Black Hills of South Dakota, suggests that some elements such as K, Li, Rb, Cs, As, Sb, Zn and Pb, have migrated to distances of 4 to 40 meters during contact metamorphism. The relative degree of migration varies depending on the element. On the other hand, there is virtually no migration of rare earth elements (REE), Al, Sc, Cr, Hf, U, and Th. Biotite and muscovite are effective trace element traps for Li, Rb, and Cs. Biotite has a greater affinity for Rb, Cs and Li than muscovite. 9 references, 5 figures, 1 table.

  8. Deep crustal sediment study: Widespread precambrian layered rocks (sedimentary ?) beneath the US midcontinent

    SciTech Connect (OSTI)

    Hauser, E.C. [Cornell Univ., Ithaca, NY (United States)

    1992-05-01

    A thick sequence of layered rocks occurs beneath the Phanerozoic platform strata which blanket the U.S. midcontinent. Observed on COCORP deep reflection data in southern Illinois and Indiana and in SW Oklahoma and adjacent Texas, this sequence is locally 1-3 times as thick as the overlying Paleozoic cover, but the origin of this sequence, its ultimate lateral extent, and resource potential are unknown. The objective of this project is to seek and reprocess seismic reflection data provided by industry from the U.S. midcontinent, and together with the COCORP deep reflection data and information from the scattered basement-penetrating drill holes, to begin to constrain the distribution, origin and evolution of this enigmatic layered sequence, particularly to evaluate if sedimentary material may be an important constituent (i.e., deep gas potential).

  9. Deep crustal sediment study: Widespread Precambrian layered rocks (Sedimentary ) beneath the US midcontinent

    SciTech Connect (OSTI)

    Hauser, E.C.

    1992-01-01

    A thick sequence of layered rocks occurs beneath the Phanerozoic platform strata which blanket the US midcontinent. Observed on COCORP deep reflection data in southern Illinois and Indiana and in SW Oklahoma and adjacent Texas, this sequence is locally 1--3 times as thick as the overlying Paleozoic cover, but the origin of this sequence, its ultimate lateral extent, and resource potential are unknown. The objective of this project is to seek and reprocess seismic reflection data provided by industry from the US midcontinent and together with the COCORP deep reflection data and information from the scattered basement-penetrating drill holes, to begin to constrain the distribution, origin and evolution of this enigmatic layered sequence, particularly to evaluate if sedimentary material may be an important constituent (i.e., deep gas potential).

  10. Deep crustal sediment study: Widespread Precambrian layered rocks (Sedimentary ?) beneath the US midcontinent

    SciTech Connect (OSTI)

    Hauser, E.C.

    1992-06-01

    A thick sequence of layered rocks occurs beneath the Phanerozoic platform strata which blanket the US midcontinent. Observed on COCORP deep reflection data in southern Illinois and Indiana and in SW Oklahoma and adjacent Texas, this sequence is locally 1--3 times as thick as the overlying Paleozoic cover, but the origin of this sequence, its ultimate lateral extent, and resource potential are unknown. The objective of this project is to seek and reprocess seismic reflection data provided by industry from the US midcontinent and together with the COCORP deep reflection data and information from the scattered basement-penetrating drill holes, to begin to constrain the distribution, origin and evolution of this enigmatic layered sequence, particularly to evaluate if sedimentary material may be an important constituent (i.e., deep gas potential).

  11. Synthesis of 3-amino-4-hydroxylaminothiazolidine-2-thiones and 2,3-dimethyl-4. cap alpha. ,5-dihydro-7-thioxothiazolo(3,4-b)-1,2,4-triazines

    SciTech Connect (OSTI)

    Epshtein, S.P.; Orlova, T.I.; Rukasov, A.F.; Tashchi, V.P.; Putsykin, Yu. G.

    1987-10-01

    The reaction of dimeric nitroso chlorides of olefins with potassium dithiocarbazate was used to synthesize 3-amino-4-hydroxylaminothiazolidine-2-thiones, which undergo rearrangement to 2-mercapto-1,3,4-thiadiazines on heating and react with butane-2,3-dione to give 2,3-dimethyl-4..cap alpha..,5-dihydro-7-thioxothiazolo(3,4-b)-1,2,4-triazine 4-oxides. The latter are reduced by sodium borohydride to the corresponding 3,4,4..cap alpha..,5-tetrahydro-7-thioxo derivatives. The IR spectra of KBr pellets of the compounds were recorded with a Perkin-Elmer spectrometer. The UV spectra of solutions in ethanol were obtained with a Specord UV spectrophotometer. The PMR spectra of solutions of the compounds in d/sub 6/-DMSO were obtained with a Varian FT-80A spectrometer with tetramethylsilane (TMS) as the internal standard.

  12. Late Pleistocene landslide-dammed lakes along the Rio Grande, White Rock Canyon, New Mexico

    SciTech Connect (OSTI)

    Reneau, S.L.; Dethier, D.P.

    1996-11-01

    Massive slump complexes composed of Pliocene basaltic rocks and underlying Miocene and Pliocene sediments flank the Rio Grande along 16 km of northern White Rock Canyon, New Mexico. The toe area of at least one slump complex was active in the late Pleistocene, damming the Rio Grande at least four times during the period from 18 to 12 {sup 14}C ka and impounding lakes that extended 10-20 km upriver. Stratigraphic relationships and radiocarbon age constraints indicate that three separate lakes formed between 13.7 and 12.4 {sup 14}C ka. The age and dimensions of the ca. 12.4 ka lake are best constrained; it had an estimated maximum depth of {approx}30 m, a length of {approx}13 km, a surface area of {approx}2.7 km{sup 2}, and an initial volume of {approx}2.5 x 10{sup 7} m{sup 3}. The youngest landslide-dammed lakes formed during a period of significantly wetter regional climate, strongly suggesting that climate changes were responsible for reactivation of the slump complexes. We are not certain about the exact triggering mechanisms for these landslides, but they probably involved removal of lateral support due to erosion of the slope base by the Rio Grande during periods of exceptionally high flood discharge or rapid incision; increased pore pressures associated with higher water tables; higher seepage forces at sites of ground-water discharge; or some combination of these processes. Seismic shaking could also have contributed to triggering of some of the landslides, particularly if aided by wet antecedent conditions. 54 refs., 19 figs., 3 tabs.

  13. Hot dry rock geothermal energy development program. Annual report, fiscal year 1980

    SciTech Connect (OSTI)

    Cremer, G.M.

    1981-07-01

    Investigation and flow testing of the enlarged Phase I heat-extraction system at Fenton Hill continued throughout FY80. Temperature drawdown observed at that time indicated an effective fracture of approximately 40,000 to 60,000 m/sup 2/. In May 1980, hot dry rock (HDR) technology was used to produce electricity in an interface demonstration experiment at Fenton Hill. A 60-kVA binary-cycle electrical generator was installed in the Phase I surface system and heat from about 3 kg/s of geothermal fluid at 132/sup 0/C was used to boil Freon R-114, whose vapor drove a turboalternator. A Phase II system was designed and is now being constructed at Fenton Hill that should approach commercial requirements. Borehole EE-2, the injection well, was completed on May 12, 1980. It was drilled to a vertical depth of about 4500 m, where the rock temperature is approximately 320/sup 0/C. The production well, EE-3 had been drilled to a depth of 3044 m and drilling was continuing. Environmental monitoring of Fenton Hill site continued. Development of equipment, instruments, and materials for technical support at Fenton Hill continued during FY80. Several kinds of models were also developed to understand the behavior of the Phase I system and to develop a predictive capability for future systems. Data from extensive resource investigations were collected, analyzed, and assembled into a geothermal gradient map of the US, and studies were completed on five specific areas as possible locations for HDR Experimental Site 2.

  14. Mobilization and Transport of Organic Compounds from Reservoir Rock and Caprock in Geological Carbon Sequestration Sites

    SciTech Connect (OSTI)

    Zhong, Lirong; Cantrell, Kirk J.; Mitroshkov, Alexandre V.; Shewell, Jesse L.

    2014-05-06

    Supercritical CO2 (scCO2) is an excellent solvent for organic compounds, including benzene, toluene, ethyl-benzene, and xylene (BTEX), phenols, and polycyclic aromatic hydrocarbons (PAHs). Monitoring results from geological carbon sequestration (GCS) field tests has shown that organic compounds are mobilized following CO2 injection. Such results have raised concerns regarding the potential for groundwater contamination by toxic organic compounds mobilized during GCS. Knowledge of the mobilization mechanism of organic compounds and their transport and fate in the subsurface is essential for assessing risks associated with GCS. Extraction tests using scCO2 and methylene chloride (CH2Cl2) were conducted to study the mobilization of volatile organic compounds (VOCs, including BTEX), the PAH naphthalene, and n-alkanes (n-C20 – n-C30) by scCO2 from representative reservoir rock and caprock obtained from depleted oil reservoirs and coal from an enhanced coal-bed methane recovery site. More VOCs and naphthalene were extractable by scCO2 compared to the CH2Cl2 extractions, while scCO2 extractable alkane concentrations were much lower than concentrations extractable by CH2Cl2. In addition, dry scCO2 was found to extract more VOCs than water saturated scCO2, but water saturated scCO2 mobilized more naphthalene than dry scCO2. In sand column experiments, moisture content was found to have an important influence on the transport of the organic compounds. In dry sand columns the majority of the compounds were retained in the column except benzene and toluene. In wet sand columns the mobility of the BTEX was much higher than that of naphthalene. Based upon results determined for the reservoir rock, caprock, and coal samples studied here, the risk to aquifers from contamination by organic compounds appears to be relatively low; however, further work is necessary to fully evaluate risks from depleted oil reservoirs.

  15. Modeling of thermally driven hydrological processes in partially saturated fractured rock

    SciTech Connect (OSTI)

    Tsang, Yvonne; Birkholzer, Jens; Mukhopadhyay, Sumit

    2009-03-15

    This paper is a review of the research that led to an in-depth understanding of flow and transport processes under strong heat stimulation in fractured, porous rock. It first describes the anticipated multiple processes that come into play in a partially saturated, fractured porous volcanic tuff geological formation, when it is subject to a heat source such as that originating from the decay of radionuclides. The rationale is then given for numerical modeling being a key element in the study of multiple processes that are coupled. The paper outlines how the conceptualization and the numerical modeling of the problem evolved, progressing from the simplified to the more realistic. Examples of numerical models are presented so as to illustrate the advancement and maturation of the research over the last two decades. The most recent model applied to in situ field thermal tests is characterized by (1) incorporation of a full set of thermal-hydrological processes into a numerical simulator, (2) realistic representation of the field test geometry, in three dimensions, and (3) use of site-specific characterization data for model inputs. Model predictions were carried out prior to initiation of data collection, and the model results were compared to diverse sets of measurements. The approach of close integration between modeling and field measurements has yielded a better understanding of how coupled thermal hydrological processes produce redistribution of moisture within the rock, which affects local permeability values and subsequently the flow of liquid and gases. The fluid flow in turn will change the temperature field. We end with a note on future research opportunities, specifically those incorporating chemical, mechanical, and microbiological factors into the study of thermal and hydrological processes.

  16. Geology and geophysics of Proterozoic basement rocks in the eastern midcontinent of the United States

    SciTech Connect (OSTI)

    Lidiak, E.G. )

    1992-01-01

    Upper crustal Proterozoic rocks of the eastern midcontinent of the U.S. are part of the transcontinental Proterozoic province, a 3,000 km-long belt of anorogenic igneous rocks that extends from western Ohio to southern California. Regional magnetic and gravity anomaly maps reveal a variety of prominent anomalies and gradients that reflect major basement or intrabasement structures. Widespread are pronounced (10--20 km diameter), high-amplitude (600--700 gamma) circular to elliptical positive magnetic anomalies that are associated with magnetite-series granites and coeval rhyolites. Also present (in Indiana) are a series of ring-shaped magnetic anomalies that have a diameter of about 50 km and form circular to elliptical patterns of narrow positive anomalies bordered by negative anomalies and ringing a central minimum. Modeling of the anomalies suggests that they may be ring dike complexes associated with calderas. Two prominent circular gravity lows associated with large granitic batholiths have also been identified. The larger of these, the Wisconsin gravity minimum, has a diameter of about 250 km and an amplitude of about [minus]65 mgals and is associated with the Wolf River batholith. The second gravity low has a diameter of about 75 km and an amplitude of about [minus]25 mgals and is in east-central Kentucky. Several major rift zones are present in the eastern midcontinent. The most prominent of these is the New Madrid rift complex, a failed-arm structure that extends into the craton beneath the Mississippi embayment. Also present are linear arrays of positive magnetic and gravity anomalies that are associated with basaltic rift zones. These include the mid-Michigan rift and the Ft. Wayne rift, as well as with possible rifts associated with the mid-Tennessee and Louisville positive anomalies.

  17. GEOCHEMISTRY OF ROCK UNITS AT THE POTENTIAL REPOSITORY LEVEL, YUCCA MOUNTAIN, NEVADA

    SciTech Connect (OSTI)

    Z.E. Peterman; P.L. Cloke

    2000-12-13

    The compositional variability of the phenocryst-poor member of the 12.8-million-year Topopah Spring Tuff at the potential repository level was assessed by duplicate analysis of 20 core samples from the cross drift at Yucca Mountain, Nevada. Previous analyses of outcrop and core samples of the Topopah Spring Tuff showed that the phenocryst-poor rhyolite, which includes both lithophysal and nonlithophysal zones, is relatively uniform in composition. Analyses of rock samples from the cross drift, the first from the actual potential repository block, also indicate the chemical homogeneity of this unit excluding localized deposits of vapor-phase minerals and low-temperature calcite and opal in fractures, cavities, and faults, The possible influence of vapor-phase minerals and calcite and opal coatings on rock composition at a scale sufficiently large to incorporate these heterogeneously distributed deposits was evaluated and is considered to be relatively minor. Therefore, the composition of the phenocryst-poor member of the Topopah Spring Tuff is considered to be adequately represented by the analyses of samples from the cross drift. The mean composition as represented by the 10 most abundant oxides in weight percent or grams per hundred grams is: SiO{sub 2}, 76.29; Al{sub 2}O{sub 3}, 12.55; FeO, 0.14; Fe{sub 2}O{sub 3}, 0.97; MgO, 0.13; CaO, 0.50; Na{sub 2}O, 3.52; K{sub 2}O, 4.83; TiO{sub 2}, 0.11; and MnO, 0.07.

  18. Energy Market and Economic Impacts of the Carbon Limits and Energy for America’s Renewal (CLEAR) Act and an Electric-Power Only Cap-and-Trade Program

    Reports and Publications (EIA)

    2010-01-01

    This paper responds to a request from Senators Bingaman, Cantwell, Collins, Murkowski and Voinovich to the U.S. Energy Information Administration (EIA) to provide technical assistance to help inform deliberations on energy and climate legislation, including an evaluation of the Carbon Limits and Energy for America’s Renewal (CLEAR) Act and several possible variants of that legislation (some of which had quite extensive components), as well as a separate electric power sector only cap and trade (EPOCT) proposal.

  19. The impact of monolayer coverage, barrier thickness and growth rate on the thermal stability of photoluminescence of coupled InAs/GaAs quantum dot hetero-structure with quaternary capping of InAlGaAs

    SciTech Connect (OSTI)

    Mandal, A.; Verma, U.; Halder, N.; Chakrabarti, S.

    2012-03-15

    Highlight: Black-Right-Pointing-Pointer Coupled InAs/GaAs MQDs with (In{sub 0.21}Al{sub 0.21}Ga{sub 0.58}As + GaAs) caps are considered. Black-Right-Pointing-Pointer Monolayer coverage, barrier thickness and growth rate of the dots are the factors. Black-Right-Pointing-Pointer PL peaks for the samples are within 1.1-1.3 {mu}m; significant for IBSCs and lasers. Black-Right-Pointing-Pointer NPTP (non-resonant multi-phonon assisted tunneling process) effect on FWHM of PL. -- Abstract: The self-assembled InAs/GaAs MQDs are widely investigated for their potential application in optoelectronic devices like lasers and photovoltaics. We have explored the effect of QD growth rate and structural parameters like capping layer thickness on the morphology and optical properties of the MQD heterostructures overgrown with a combination capping of InAlGaAs and GaAs. The growth rate of the seed layers in the MQD samples is also varied to investigate its effect in the vertical stacking of the islands. The change in the morphology and the optical properties of the samples due to variation in growth and structural parameters are explained by the presence of strain in the QD structures, which arises due to lattice mismatch.

  20. National survey of crystalline rocks and recommendations of regions to be explored for high-level radioactive waste repository sites

    SciTech Connect (OSTI)

    Smedes, H.W.

    1983-04-01

    A reconnaissance of the geological literature on large regions of exposed crystalline rocks in the United States provides the basis for evaluating if any of those regions warrant further exploration toward identifying potential sites for development of a high-level radioactive waste repository. The reconnaissance does not serve as a detailed evaluation of regions or of any smaller subunits within the regions. Site performance criteria were selected and applied insofar as a national data base exists, and guidelines were adopted that relate the data to those criteria. The criteria include consideration of size, vertical movements, faulting, earthquakes, seismically induced ground motion, Quaternary volcanic rocks, mineral deposits, high-temperature convective ground-water systems, hydraulic gradients, and erosion. Brief summaries of each major region of exposed crystalline rock, and national maps of relevant data provided the means for applying the guidelines and for recommending regions for further study. It is concluded that there is a reasonable likelihood that geologically suitable repository sites exist in each of the major regions of crystalline rocks. The recommendation is made that further studies first be conducted of the Lake Superior, Northern Appalachian and Adirondack, and the Southern Appalachian Regions. It is believed that those regions could be explored more effectively and suitable sites probably could be found, characterized, verified, and licensed more readily there than in the other regions.

  1. Development of Chemical Model to Predict the Interactions between Supercritical CO2and Fluid, and Rocks in EGS Reservoirs

    Broader source: Energy.gov [DOE]

    This project will develop a chemical model, based on existing models and databases, that is capable of simulating chemical reactions between supercritical (SC) CO2 and Enhanced Geothermal System (EGS) reservoir rocks of various compositions in aqueous, non-aqueous and 2-phase environments.

  2. EIS-0471: Department of Energy Loan Guarantee to Support Proposed Eagle Rock Enrichment Facility in Bonneville County, Idaho

    Broader source: Energy.gov [DOE]

    This EIS evaluates the environmental impacts of construction, operation, and decommissioning of the proposed Eagle Rock Enrichment Facility (EREF), a gas centrifuge uranium enrichment facility to be located in a rural area in western Bonneville County, Idaho. (DOE adopted this EIS issued by NRC on 04/13/2007.)

  3. Radiocarbon as a Reactive Tracer for Tracking Permanent CO2 Storage in Basaltic Rocks

    SciTech Connect (OSTI)

    Matter, Juerg; Stute, Martin; Schlosser, Peter; Broecker, Wallace

    2015-09-30

    In view of concerns about the long-term integrity and containment of CO2 storage in geologic reservoirs, many efforts have been made to improve the monitoring, verification and accounting methods for geologically stored CO2. Our project aimed to demonstrate that carbon-14 (14C) could be used as a reactive tracer to monitor geochemical reactions and evaluate the extent of mineral trapping of CO2 in basaltic rocks. The capacity of a storage reservoir for mineral trapping of CO2 is largely a function of host rock composition. Mineral carbonation involves combining CO2 with divalent cations including Ca2+, Mg2+ and Fe2+. The most abundant geological sources for these cations are basaltic rocks. Based on initial storage capacity estimates, we know that basalts have the necessary capacity to store million to billion tons of CO2 via in situ mineral carbonation. However, little is known about CO2-fluid-rock reactions occurring in a basaltic storage reservoir during and post-CO2 injection. None of the common monitoring and verification techniques have been able to provide a surveying tool for mineral trapping. The most direct method for quantitative monitoring and accounting involves the tagging of the injected CO2 with 14C because 14C is not present in deep geologic reservoirs prior to injection. Accordingly, we conducted two CO2 injection tests at the CarbFix pilot injection site in Iceland to study the feasibility of 14C as a reactive tracer for monitoring CO2-fluid-rock reactions and CO2 mineralization. Our newly developed monitoring techniques, using 14C as a reactive tracer, have been successfully demonstrated. For the first time, permanent and safe disposal of CO2 as environmentally benign carbonate minerals in basaltic rocks could be shown. Over 95% of the injected CO2 at the CarbFix pilot injection site was mineralized to carbonate minerals in less than two years after injection. Our monitoring results confirm that CO2 mineralization in basaltic rocks is far faster than previously postulated.

  4. The overthrusted Zaza Terrane of middle Cretaceous over the North American continental carbonate rocks of upper Jurassic-Lower Cretaceous age - relationships to oil generation

    SciTech Connect (OSTI)

    Echevarria Rodriguez, G.; Castro, J.A.; Amaro, S.V.

    1996-08-01

    The Zaza Terrane is part of the Caribbean plate thrust over the southern edge of the North American basinal and platform carbonate rocks of upper Jurassic-Lower Cretaceous age. Zaza Terrane are volcanic and ophiolitic rocks of Cretaceous age. The ophiolites are mostly serpentines which behave as reservoirs and seals. All Cuban oil fields are either within Zaza Terrane or basinal carbonates underneath, or not far away to the north of the thrust contacts. It appears that the overthrusting of the Zaza Terrane caused the generation of oil in the basinal carbonate source rocks underneath, due to the increase of rock thickness which lowered the oil window to a deeper position and increased the geothermal gradient. Oil generation was after thrusting, during post-orogenic. API gravity of oil is light toward the south and heavy to very heavy to the north. Source rocks to the south are probably of terrigenous origin.

  5. Mass transfer during wall-rock alteration: An example from a quartz-graphite vein, Black Hills, South Dakota

    SciTech Connect (OSTI)

    Galbreath, K.C.; Duke, E.F.; Papike, J.J. ); Laul, J.C. )

    1988-07-01

    Mass transfer and fluid-rock interaction have been evaluated along two sample traverses in low-sillimanite grade quartz-mica schist adjacent to a synmetamorphic quartz-graphite vein in the southern Black Hills, South Dakota. In an {approximately}17 cm halo between apparently unaltered schist and the vein contact is an outer zone of cryptic alteration and three inner zones of visible alteration. The cryptic zone consists of the original prograde metamorphic mineral assemblage plus anomalously high amounts of tourmaline. The outermost visible zone contains abundant graphite. The second visible zone is defined by intensive bleaching of the schist. The innermost visible zone, immediately adjacent to the vein, is tourmaline + quartz + plagioclase + limonite + graphite. The vein is composed almost entirely of quartz, but also contains trace amounts of graphite. Mass balance calculations indicate that Al was essentially inert. The predominant chemical changes during wall-rock alteration were addition of B and C from the vein-forming fluid along with loss of K from the wall rocks, corresponding to precipitation of tourmaline and graphite, and the progressive destruction of microcline, biotite, and muscovite toward the vein. In addition, the elements V, Cr, Cu, Zn, Pb, As, Sb, W, and Au were introduced into the country rock, whereas Si, Rb, Ba, and Cs were removed. Fluid-rock interaction modeling suggests that between one and four equivalent masses of fluid interacted chemically with the most altered mineral assemblages. In addition, greater than one equivalent mass of reactive fluid penetrated to distances of at least 5 cm from the vein contact.

  6. Estimation of host rock thermal conductivities using thetemperature data from the drift-scale test at Yucca Mountain,Nevada

    SciTech Connect (OSTI)

    Mukhopadhyay, Sumitra; Tsang, Y.W.

    2003-11-25

    A large volume of temperature data has been collected from a very large, underground heater test, the Drift Scale Test (DST) at Yucca Mountain, Nevada. The DST was designed to obtain thermal, hydrological, mechanical, and chemical (THMC) data in the unsaturated fractured rock of Yucca Mountain. Sophisticated numerical models have been developed to analyze the collected THMC data. In these analyses, thermal conductivities measured from core samples have been used as input parameters to the model. However, it was not known whether these core measurements represented the true field-scale thermal conductivity of the host rock. Realizing these difficulties, elaborate, computationally intensive geostatistical simulations have also been performed to obtain field-scale thermal conductivity of the host rock from the core measurements. In this paper, we use the temperature data from the DST as the input (instead of the measured core-scale thermal conductivity values) to develop an estimate of the field-scale thermal conductivity values. Assuming a conductive thermal regime, we develop an analytical solution for the temperature rise in the host rock of the DST; and using a nonlinear fitting routine, we obtain a best-fit estimate of field-scale thermal conductivity for the DST host rock. The temperature data collected from the DST shows clear evidence of two distinct thermal regimes: a zone below boiling (wet) and a zone above boiling (dry). We obtain estimates of thermal conductivity for both the wet and dry zones. We also analyze the sensitivity of these estimates to the input heating power of the DST.

  7. Mathematical modeling of cold cap

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pohang, Republic of Korea. E-mail address: pavelhrma@postech.ac.kr (P. Hrma). Journal of Nuclear Materials 429 (2012) 245-256 Contents lists available at SciVerse...

  8. Gap solitons in rocking optical lattices and waveguides with undulating gratings

    SciTech Connect (OSTI)

    Mayteevarunyoo, Thawatchai; Malomed, Boris A.

    2009-07-15

    We report results of a systematic analysis of the stability of one-dimensional solitons in a model including the self-repulsive or attractive cubic nonlinearity and a linear potential represented by a periodically shaking lattice, which was recently implemented in experiments with Bose-Einstein condensates. In optics, the same model applies to undulated waveguiding arrays, which are also available to the experiment. In the case of the repulsive nonlinearity, stability regions are presented, in relevant parameter planes, for fundamental gap solitons and their two-peak and three-peak bound complexes, in the first and second finite band gaps. In the model with the attractive nonlinearity, stability regions are produced for fundamental solitons and their bound states populating the semi-infinite gap. In the first finite and semi-infinite gaps, unstable solitons gradually decay into radiation, while, in the second finite band gap, they are transformed into more complex states, which may represent new species of solitons. For a large amplitude of the rocking-lattice drive, the model is tantamount to that with a 'flashing' lattice potential, which is controlled by periodic sequences of instantaneous kicks. Using this correspondence, we explain generic features of the stability diagrams for the solitons. We also derive a limit case of the latter system, in the form of coupled-mode equations with a 'flashing' linear coupling.

  9. Unique aspects of drilling and completing hot-dry-rock geothermal wells

    SciTech Connect (OSTI)

    Carden, R.S.; Nicholson, R.W.; Pettitt, R.A.; Rowley, J.C.

    1983-01-01

    Drilling operations at the Fenton Hill Hot Dry Rock (HDR) Geothermal Test Site have led to numerous developments needed to solve the problems caused by a very harsh downhole environment. A pair of deep wells were drilled to approximately 15,000 ft (4.6 km); formation temperatures were in excess of 600/sup 0/F (300/sup 0/C). The wells were directionally drilled, inclined at 35/sup 0/, one above the other, in a direction orthogonal to the least principal stress field. The well site is near the flank of a young silicic composite volcano in the Jemez Mountains of northern New Mexico. The completion of this pair of wells is unique in reservoir development. The lower well was planned as a cold water injector which will be cooled by the introduced water from the static geothermal gradient to about 80/sup 0/F (25/sup 0/C). The upper well will be heated during production to over 500/sup 0/F (250/sup 0/C). The well pair is designed to perform as a closed loop heat-extraction system connected by hydraulic fractures with a vertical spacing of 1200 ft between the wells. These conditions strongly constrain the drilling technique, casing design, cement formulation, and cementing operations.

  10. Fractured rock aquifer tests in the Western Siberian Basin, Ozyorsk, Russia

    SciTech Connect (OSTI)

    Nichols, R.L.; Looney, B.B.; Eddy-Dilek, C.A.

    1997-10-01

    A series of multi-zone pumping tests was conducted in a contaminated fractured rock aquifer in the Western Siberian Basin, Ozyorsk, Russia. The tests were conducted adjacent to the Mishelyak River floodplain in fractured Paleozoic porphyrites, tufts, tuff breccia, and lava typical of the Ural mountain complex. Geophysical logs, borehole photography, core samples, and results from previous borehole contamination studies were used to identify the zones to be tested. A network of three uncased wells was tested using a system of inflatable packers, pressure transducers and data loggers. Seven zones were isolated and monitored in two of the uncased wells. A straddle packer assembly was used to isolate individual zones within the pumping well. Eight constant rate pumping tests were conducted. Results of the testing indicate that shallow groundwater migrates primarily in two intervals that are separated by an interval with low lateral conductivity. The water bearing intervals have moderate to high specific capacities (1.3 and 30 L/min/m). Several processes are responsible for fracturing present in the lower interval. The network of compound fractures produced a complex array of fracture intersections yielding a fractured media with hydraulic behavior similar to porous media. Models used for the analysis of pumping tests in porous media provide a good estimation of the hydraulic response of the lower interval to pumping. Future work will include more complex analysis of the data to determine hydraulic conductivity ellipses.

  11. Kinematic Interaction and Rocking Effects on the Seismic Response of Viaducts on Pile Foundations

    SciTech Connect (OSTI)

    Dezi, F.; Carbonari, S.; Leoni, G.

    2008-07-08

    This paper is aimed at providing a contribution for a more accurate and effective design of bridges founded on piles. A numerical model is employed herein to determine the stresses and displacements in the piles taking into account soil-foundation-structure interaction. A 3D finite element approach is developed for piles and superstructure whereas the soil is assumed to be a Winkler-type medium. The method is applied to single piers representative for a class of bridges. Varying the soil layers characteristics and the pile spacing (from 3 to 5 diameters), bending and axial stresses along piles as well as the pier base shear are computed. A comparison with respect to a fixed-base model is provided. Special issues such as the contribution of the soil profile, of the local amplification and of the rocking at the foundation level are discussed. Soil-structure interaction is found to be essential for effective design of bridges especially for squat piers and soft soil.

  12. Surface water supply for the Clearlake, California Hot Dry Rock Geothermal Project

    SciTech Connect (OSTI)

    Jager, A.R.

    1996-03-01

    It is proposed to construct a demonstration Hot Dry Rock (HDR) geothermal plant in the vicinity of the City of Clearlake. An interim evaluation has been made of the availability of surface water to supply the plant. The evaluation has required consideration of the likely water consumption of such a plant. It has also required consideration of population, land, and water uses in the drainage basins adjacent to Clear Lake, where the HDR demonstration project is likely to be located. Five sources were identified that appear to be able to supply water of suitable quality in adequate quantity for initial filling of the reservoir, and on a continuing basis, as makeup for water losses during operation. Those sources are California Cities Water Company, a municipal supplier to the City of Clearlake; Clear Lake, controlled by Yolo County Flood Control and Water Conservation District; Borax Lake, controlled by a local developer; Southeast Regional Wastewater Treatment Plant, controlled by Lake County; and wells, ponds, and streams on private land. The evaluation involved the water uses, water rights, stream flows, precipitation, evaporation, a water balance, and water quality. In spite of California`s prolonged drought, the interim conclusion is that adequate water is available at a reasonable cost to supply the proposed HDR demonstration project.

  13. Petrology of lower and middle Eocene carbonate rocks, Floridan aquifer, central Florida

    SciTech Connect (OSTI)

    Thayer, P.A.; Miller, J.A.

    1984-09-01

    Study of cores from a US Geological Survey test well near Polk City, Florida, indicates that the Avon Park-Lake City (Claibornian) and Oldsmar (Sabinian) Limestones, which comprise most of the Floridan aquifer in central Florida, can be divided into six microfacies: foraminiferal mudstone, foraminiferal wackestone-packstone, foraminiferal grainstone, nodular anhydrite, laminated dolomicrite, and replacement dolomite. Dolomite containing variable amounts of nodular anhydrite forms more than 90% of the Avon Park-Lake city interval, whereas thte Oldsmar is chiefly limestone. Several episodes of dolomite formation are recognized. Laminated dolomicrite formed syngenetically in a supratidal-sabhka environment. Crystalline dolomite with nodular anhydrite formed early by replacement of limestone through reflux of dense, magnesium-rich brines. Replacement dolomite not associated with evaporites and containing limpid crystals probably formed later by a mixed-water process in the subsurface environment. Late diagenetic processes affecting crystalline dolomites include hydration of anhydrite to gypsum, partial dissolution of gypsum, minor alteration of gypsum to calcite, and dissolution of calcian dolomite cores in stoichiometric crystals. Crystalline dolomite and grainstone are the only rock types that have high enough porosities and permeabilities to provide significant yields of water. Medium and finely crystalline dolomites show best values of porosity and permeability because they have high percentages of intercrystal and moldic pores that are well connected. Filling of pores by anhydrite or gypsum can significantly reduce porosity and permeability.

  14. Oils and source rocks from the Anadarko Basin: Final report, March 1, 1985-March 15, 1995

    SciTech Connect (OSTI)

    Philp, R. P. [School of Geology and Geophysics, Univ. of Oklahoma, Norman, OK (United States)

    1996-11-01

    The research project investigated various geochemical aspects of oils, suspected source rocks, and tar sands collected from the Anadarko Basin, Oklahoma. The information has been used, in general, to investigate possible sources for the oils in the basin, to study mechanisms of oil generation and migration, and characterization of depositional environments. The major thrust of the recent work involved characterization of potential source formations in the Basin in addition to the Woodford shale. The formations evaluated included the Morrow, Springer, Viola, Arbuckle, Oil Creek, and Sylvan shales. A good distribution of these samples was obtained from throughout the basin and were evaluated in terms of source potential and thermal maturity based on geochemical characteristics. The data were incorporated into a basin modelling program aimed at predicting the quantities of oil that could, potentially, have been generated from each formation. The study of crude oils was extended from our earlier work to cover a much wider area of the basin to determine the distribution of genetically-related oils, and whether or not they were derived from single or multiple sources, as well as attempting to correlate them with their suspected source formations. Recent studies in our laboratory also demonstrated the presence of high molecular weight components(C{sub 4}-C{sub 80}) in oils and waxes from drill pipes of various wells in the region. Results from such a study will have possible ramifications for enhanced oil recovery and reservoir engineering studies.

  15. Waste/Rock Interactions Technology Program: the status of radionuclide sorption-desorption studies performed by the WRIT program

    SciTech Connect (OSTI)

    Serne, R.J.; Relyea, J.F.

    1982-04-01

    The most credible means for radionuclides disposed as solid wastes in deep-geologic repositories to reach the biosphere is through dissolution of the solid waste and subsequent radionuclide transport by circulating ground water. Thus safety assessment activities must consider the physicochemical interactions between radionculides present in ground water with package components, rocks and sediments since these processes can significantly delay or constrain the mass transport of radionuclides in comparison to ground-water movement. This paper focuses on interactions between dissolved radiouclides in ground water and rocks and sediments away from the near-field repository. The primary mechanism discussed is adsorption-desorption, which has been studied using two approaches. Empirical studies of adsorption-desorption rely on distribution coefficient measurements while mechanism studies strive to identify, differentiate and quantify the processes that control nuclide retardation.

  16. Laboratory evaluation of mechanical properties of rock using an automated triaxial compression test with a constant mean stress criterion

    SciTech Connect (OSTI)

    Mellegard, K.D.; Pfeifle, T.W.

    1999-07-01

    A computerized, servohydraulic test system has been used in the laboratory to perform axisymmetric, triaxial compression tests on natural rock salt using a load path that maintains constant mean stress. The constant mean stress test protocol illustrates that modern test systems allow a nonstandard load path which can focus on a particular aspect of rock characterization; namely, the onset of dilation. Included are discussions of how the constant mean stress test could be used to investigate material anisotropy and determine elastic moduli. The results from the constant mean stress tests are compared to test results from a traditional test method. The paper also addresses system calibration concerns and the effects of pressure changes on the direct-contact extensometers used to measure strain.

  17. Investigations of Near-Field Thermal-Hydrologic-Mechanical-Chemical Models for Radioactive Waste Disposal in Clay/Shale Rock

    SciTech Connect (OSTI)

    Liu, H.H.; Li, L.; Zheng, L.; Houseworth, J.E.; Rutqvist, J.

    2011-06-20

    Clay/shale has been considered as potential host rock for geological disposal of high-level radioactive waste throughout the world, because of its low permeability, low diffusion coefficient, high retention capacity for radionuclides, and capability to self-seal fractures. For example, Callovo-Oxfordian argillites at the Bure site, France (Fouche et al., 2004), Toarcian argillites at the Tournemire site, France (Patriarche et al., 2004), Opalinus Clay at the Mont Terri site, Switzerland (Meier et al., 2000), and Boom clay at the Mol site, Belgium (Barnichon and Volckaert, 2003) have all been under intensive scientific investigation (at both field and laboratory scales) for understanding a variety of rock properties and their relationships to flow and transport processes associated with geological disposal of radioactive waste. Figure 1-1 presents the distribution of clay/shale formations within the USA.

  18. Geochemistry and sedimentation of organic matter in the Triassic-Liassic carbonate laminated source rocks of the Ragusa basin (Italy)

    SciTech Connect (OSTI)

    Brosse, E.; Loreau, J.P.; Frixa, A.

    1988-08-01

    The Noto and Streppenosa formations of the Ragusa basin (southeastern Sicily) are considered the main source rocks for oil in this area. They display various styles of sedimentation in a generally carbonate context. The organic matter is basically of marine planktonic origin but with some variations, especially in terms of O/C ratio and kinetic behavior. Three main styles of sedimentation occurred within these formations: (1) laminates in a dominantly carbonate rock with thin recurrent interlayers of black shales; (2) alternating layers of marls and limestones, both containing interlayers of black shales and with occasional laminations in the limestones; and (3) silty shales, more or less rich in carbonates (30-70%). The highest petroleum potentials are neither strictly associated with the algal-sedimentary laminites nor with the basinal silty facies but with the black shales interbedded in the different facies or abruptly overlying limestones. In these black shales, oxygen-poor kerogens are dominant. Limestones of the alternated layers are generally organic lean (TOC < 1%), and oxygen-rich kerogens are dominant. The transition from one type of kerogen to the other occurs in the marly layers of the sequence. A tentative integration of both sedimentological and geochemical results is proposed, at the scale of the core, to interpret the respective influence of the depositional pattern and the diagenetic conditions on the content and nature of the kerogen in the source rocks.

  19. Distribution and geochemistry of contaminated subsurface waters in fissured volcanogenic bed rocks of the Lake Karachai Area, Chelyabinsk, Southern Urals

    SciTech Connect (OSTI)

    Solodov, I.N.; Belichkin, V.I.; Zotov, A.V.; Kochkin, B.T.; Drozhko, E.G.; Glagolev, A.V.; Skokov, A.N.

    1994-06-01

    The present investigation is devoted to the study of the distribution and geochemistry of contaminated subsurface waters, beneath the site of temporary storage of liquid radioactive waste known as Lake Karachai. For this purpose a method of hydrogeochemical logging (HGCL) together with standard hydrogeochemical and geophysical methods of uncased hole logging were used. The distribution of sodium nitrate brine plumes in the subsurface was determined by the physical and physico-chemical properties of these brines and by the petrochemical composition of enclosing rocks and the structural setting of the flow paths. The latter is represented by fractures and large faults in the bedrock of volcanogenic and volcanogenic-sedimentary rocks of intermediate-to-basic composition. The volcanogenic rocks are overlain in some places by a thin cover of unconsolidated sediments, i.e., by loams and relatively impermeable silts. Contaminated waters flow-in accordance with the eluvium bottom relief towards local areas of natural (Mishelyak and Techa rivers) and artificial (Novogomenskii water intake) discharge of subsurface waters. The large Mishelyak fault, southwest of Lake Karachai and under fluvial sediments of the Mishelyak, is assumed to significantly influence the flow pattern of contaminated waters, diverting them from an intake of drinking water.

  20. Project test plan for runoff and erosion on fine-soil barrier surfaces and rock-covered side slopes

    SciTech Connect (OSTI)

    Walters, W.H.; Hoover, K.A.; Cadwell, L.L.

    1990-06-01

    Pacific Northwest Laboratory (PNL) and Westinghouse Hanford Company are working together to develop protective barriers to isolate near-surface radioactive waste. The purpose of the barriers is to protect defense wastes at the US Department of Energy's (DOE) Hanford Site from infiltration of precipitation, biointrusion, and surficial erosion for up to 10,000 years without the need for long-term monitoring, maintenance, or institutional control. The barriers will be constructed of layered earth and rock material designed to direct surface and groundwater pathways away from the buried waste. To address soil erosion as it applies to barrier design and long-term stability, a task designed to study this problem has been included in the Protective Barriers Program at PNL. The barrier soil-erosion task will investigate the ability of the soil cover and side slopes to resist the erosional and destabilizing processes from externally applied water. The study will include identification and field testing of the dominant processes contributing to erosion and barrier failure. The effects of rock mulches, vegetation cover on the top fine-grained soil surface, as well as the stability of rock armoring on the side slopes, will be evaluated. Some of the testing will include the effects of animal intrusion on barrier erosion, and these will be coordinated with other animal intrusion studies. 6 refs., 4 figs., 1 tab.

  1. End-to-End Models for Effects of System Noise on LIMS Analysis of Igneous Rocks

    SciTech Connect (OSTI)

    Clegg, Samuel M; Bender, Steven; Wiens, R. C.; Carmosino, Marco L; Speicher, Elly A; Dyar, M. D.

    2010-12-23

    The ChemCam instrument on the Mars Science Laboratory will be the first extraterrestial deployment of laser-induced breakdown spectroscopy (UBS) for remote geochemical analysis. LIBS instruments are also being proposed for future NASA missions. In quantitative LIBS applications using multivariate analysis techniques, it is essential to understand the effects of key instrument parameters and their variability on the elemental predictions. Baseline experiments were run on a laboratory instrument in conditions reproducing ChemCam performance on Mars. These experiments employed Nd:YAG laser producing 17 mJ/pulse on target and an with a 200 {micro}m FWHM spot size on the surface of a sample. The emission is collected by a telescope, imaged on a fiber optic and then interfaced to a demultiplexer capable of >40% transmission into each spectrometer. We report here on an integrated end-to-end system performance model that simulates the effects of output signal degradation that might result from the input signal chain and the impact on multivariate model predictions. There are two approaches to modifying signal to noise (SNR): degrade the signal and/or increase the noise. Ishibashi used a much smaller data set to show that the addition of noise had significant impact while degradation of spectral resolution had much less impact on accuracy and precision. Here, we specifically focus on aspects of remote LIBS instrument performance as they relate to various types of signal degradation. To assess the sensitivity of LIBS analysis to signal-to-noise ratio (SNR) and spectral resolution, the signal in each spectrum from a suite of 50 laboratory spectra of igneous rocks was variably degraded by increasing the peak widths (simulating misalignment) and decreasing the spectral amplitude (simulating decreases in SNR).

  2. Remedial action and site design for stabilization of the inactive uranium mill tailings sites at Slick Rock, Colorado. Attachment 2, Geology report

    SciTech Connect (OSTI)

    Not Available

    1993-07-01

    This report presents geologic considerations that are pertinent to the Remedial Action Plan for Slick Rock mill tailings. Topics covered include regional geology, site geology, geologic stability, and geologic suitability.

  3. Integrated Experimental and Modeling Studies of Mineral Carbonation as a Mechanism for Permanent Carbon Sequestration in Mafic/Ultramafic Rocks

    SciTech Connect (OSTI)

    Wang, Zhengrong; Qiu, Lin; Zhang, Shuang; Bolton, Edward; Bercovici, David; Ague, Jay; Karato, Shun-Ichiro; Oristaglio, Michael; Zhu, Wen-Iu; Lisabeth, Harry; Johnson, Kevin

    2014-09-30

    A program of laboratory experiments, modeling and fieldwork was carried out at Yale University, University of Maryland, and University of Hawai‘i, under a DOE Award (DE-FE0004375) to study mineral carbonation as a practical method of geologic carbon sequestration. Mineral carbonation, also called carbon mineralization, is the conversion of (fluid) carbon dioxide into (solid) carbonate minerals in rocks, by way of naturally occurring chemical reactions. Mafic and ultramafic rocks, such as volcanic basalt, are natural candidates for carbonation, because the magnesium and iron silicate minerals in these rocks react with brines of dissolved carbon dioxide to form carbonate minerals. By trapping carbon dioxide (CO2) underground as a constituent of solid rock, carbonation of natural basalt formations would be a secure method of sequestering CO2 captured at power plants in efforts to mitigate climate change. Geochemical laboratory experiments at Yale, carried out in a batch reactor at 200°C and 150 bar (15 MPa), studied carbonation of the olivine mineral forsterite (Mg2SiO4) reacting with CO2 brines in the form of sodium bicarbonate (NaHCO3) solutions. The main carbonation product in these reactions is the carbonate mineral magnesite (MgCO3). A series of 32 runs varied the reaction time, the reactive surface area of olivine grains and powders, the concentration of the reacting fluid, and the starting ratio of fluid to olivine mass. These experiments were the first to study the rate of olivine carbonation under passive conditions approaching equilibrium. The results show that, in a simple batch reaction, olivine carbonation is fastest during the first 24 hours and then slows significantly and even reverses. A natural measure of the extent of carbonation is a quantity called the carbonation fraction, which compares the amount of carbon removed from solution, during a run, to the maximum amount that could have been removed if the olivine initially present had fully dissolved and the cations released had subsequently precipitated in carbonate minerals. The carbonation fractions observed in batch experiments with olivine grains and powders varied significantly, from less than 0.01 (1%) to more than 0.5 (50%). Over time, the carbonation fractions reached an upper limit after about 24 to 72 hours of reaction, then stayed constant or decreased. The peak Final Scientific/Technical Report DE-FE0004275 | Mineral Carbonation | 4 coincided with the appearance of secondary magnesium-bearing silicate minerals, whose formation competes for magnesium ions in solution and can even promote conditions that dissolve magnesite. The highest carbonation fractions resulted from experiments with low ratios of concentrated solution to olivine, during which amorphous silica spheres or meshes formed, instead of secondary silicate minerals. The highest carbonation fractions appear to result from competing effects. Precipitation of silica layers on olivine reduces the reactive surface area and, thus, the rate of olivine dissolution (which ultimately limits the carbonation rate), but these same silica layers can also inhibit the formation of secondary silicate minerals that consume magnesite formed in earlier stages of carbonation. Simulation of these experiments with simple geochemical models using the software program EQ3/6 reproduces the general trends observed—especially the results for the carbonation fraction in short-run experiments. Although further experimentation and better models are needed, this study nevertheless provides a framework for understanding the optimal conditions for sequestering carbon dioxide by reacting CO2-bearing fluids with rocks containing olivine minerals. A series of experiments at the Rock Physics Laboratory at the University of Maryland studied the carbonation process during deformation of thermally cracked olivine-rich rock samples (dunit

  4. Standing Rock Sioux Tribe - Lakota/Dakota Nation Feasibility Study Supporting Wind Development and Establishment of Renewable Energy and Energy Development Office

    Energy Savers [EERE]

    (Washee Zee) 701-854-3437 fwasinzi@standingrock.org Standing Rock Sioux Tribe - Lakota/Dakota Nation  BACKGROUND INFORMATION ON STANDING ROCK RESERVATION  SITTING BULL COLLEGE WIND TURBINE  EECBG ENERGY EFFICIENCY & WIND TURBINE INSTALLATION AT SITTING BULL COLLEGE  WIND ASSESSMENT STUDY  ESTABLISHMENT OF RENEWABLE ENERGY & ENERGY DEVELOPMENT OFFICE (REEDO)  WIND FEASIBILITY STUDY  OCETI SAKOWIN POWER PROJECT  ONE OF SEVEN RESERVATIONS OF THE GREAT SIOUX NATION

  5. Uinta Arch Project: investigations of uranium potential in Precambrian X and older metasedimentary rocks in the Unita and Wasatch ranges, Utah and Colorado

    SciTech Connect (OSTI)

    Graff, P.J.; Sears, J.W.; Holden, G.S.

    1980-06-01

    This study is part of the United States Department of Energy's National Uranium Resource Evaluation Program to understand the geologic setting, amount, and availability of uranium resources within the boundaries of the United States. The systematic study of Precambrian quartz-pebble conglomerates and areas that may contain such conglomerates is an integral part of DOE's resource evaluation program, because deposits of world-wide importance occur in such terrains in Canada and South Africa, and because terrains similar to those producing uranium from quartz-pebble conglomerates exist elsewhere in the United States. Because of the ready availability of Tertiary sandstone and Colorado Plateau-type uranium deposits, large areas of Precambrian rocks in the US have not been fully assessed for uranium potential. Thus, the Uinta Arch Project was undertaken to assess the favorability of Precambrian metasedimentary rocks in northern Utah for deposits of uranium in Precambrian quartz-pebble conglomerates. Rocks of interest to this study are the thick, clastic sequences within the Uinta Arch that are considered to be of Early Proterozoic age. The Uinta Arch area is known to contain rocks which generally fit the lithologic characteristics that are understood to limit the occurrence of Precambrian fossil placers. However, detailed geology of these rocks and their exact fit to the model described for uraniferous conglomerates was not known. The primary goal of the Uinta Arch Project was to determine how well these Precambrian rocks resemble known deposits and to describe the favorability of placer uranium deposits.

  6. Smaller Footprint Drilling System for Deep and Hard Rock Environments; Feasibility of Ultra-High-Speed Diamond Drilling

    SciTech Connect (OSTI)

    TerraTek, A Schlumberger Company

    2008-12-31

    The two phase program addresses long-term developments in deep well and hard rock drilling. TerraTek believes that significant improvements in drilling deep hard rock will be obtained by applying ultra-high rotational speeds (greater than 10,000 rpm). The work includes a feasibility of concept research effort aimed at development that will ultimately result in the ability to reliably drill 'faster and deeper' possibly with smaller, more mobile rigs. The principle focus is on demonstration testing of diamond bits rotating at speeds in excess of 10,000 rpm to achieve high rate of penetration (ROP) rock cutting with substantially lower inputs of energy and loads. The significance of the 'ultra-high rotary speed drilling system' is the ability to drill into rock at very low weights on bit and possibly lower energy levels. The drilling and coring industry today does not practice this technology. The highest rotary speed systems in oil field and mining drilling and coring today run less than 10,000 rpm - usually well below 5,000 rpm. This document provides the progress through two phases of the program entitled 'Smaller Footprint Drilling System for Deep and Hard Rock Environments: Feasibility of Ultra-High-Speed Diamond Drilling' for the period starting 30 June 2003 and concluding 31 March 2009. The accomplishments of Phases 1 and 2 are summarized as follows: (1) TerraTek reviewed applicable literature and documentation and convened a project kick-off meeting with Industry Advisors in attendance (see Black and Judzis); (2) TerraTek designed and planned Phase I bench scale experiments (See Black and Judzis). Improvements were made to the loading mechanism and the rotational speed monitoring instrumentation. New drill bit designs were developed to provided a more consistent product with consistent performance. A test matrix for the final core bit testing program was completed; (3) TerraTek concluded small-scale cutting performance tests; (4) Analysis of Phase 1 data indicated that there is decreased specific energy as the rotational speed increases; (5) Technology transfer, as part of Phase 1, was accomplished with technical presentations to the industry (see Judzis, Boucher, McCammon, and Black); (6) TerraTek prepared a design concept for the high speed drilling test stand, which was planned around the proposed high speed mud motor concept. Alternative drives for the test stand were explored; a high speed hydraulic motor concept was finally used; (7) The high speed system was modified to accommodate larger drill bits than originally planned; (8) Prototype mud turbine motors and the high speed test stand were used to drive the drill bits at high speed; (9) Three different rock types were used during the testing: Sierra White granite, Crab Orchard sandstone, and Colton sandstone. The drill bits used included diamond impregnated bits, a polycrystalline diamond compact (PDC) bit, a thermally stable PDC (TSP) bit, and a hybrid TSP and natural diamond bit; and (10) The drill bits were run at rotary speeds up to 5500 rpm and weight on bit (WOB) to 8000 lbf. During Phase 2, the ROP as measured in depth of cut per bit revolution generally increased with increased WOB. The performance was mixed with increased rotary speed, with the depth cut with the impregnated drill bit generally increasing and the TSP and hybrid TSP drill bits generally decreasing. The ROP in ft/hr generally increased with all bits with increased WOB and rotary speed. The mechanical specific energy generally improved (decreased) with increased WOB and was mixed with increased rotary speed.

  7. Chemical migration by contact metamorphism between pegmatite/country rocks: natural analogs for radionuclides migration. [Black Hills, South Dakota

    SciTech Connect (OSTI)

    Laul, J.C.; Walker, R.J.; Shearer, C.K.; Papike, J.J.; Simon, S.B.

    1983-10-01

    Comparison of trace element signatures of country rocks as a function of distance from the contact with two pegmatites, Tin Mountain and Etta, in the Black Hills of South Dakota, suggests that some elements such as K, Li, Rb, Cs, As, Sb, Zn and Pb, have migrated to distances of 4 to 40 meters during contact metamorphism. The relative degree of migration varies depending on the element. On the other hand, there is virtually no migration of rare earth elements (REE), Al, Sc, Cr, Hf, U, and Th. Biotite and muscovite are effective trace element traps for Li, Rb and Cs. Biotite has a greater affinity for Rb, Cs and Li than muscovite.

  8. ACOUSTICAL IMAGING AND MECHANICAL PROPERTIES OF SOFT ROCK AND MARINE SEDIMENTS

    SciTech Connect (OSTI)

    Thurman E. Scott, Jr., Ph.D.; Younane Abousleiman, Ph.D.; Musharraf Zaman, Ph.D., P.E.

    2002-04-30

    Three major goals were accomplished during this phase. First, a study was completed of the effects of stress-induced changes in anisotropic elastic moduli in sandstone. Second, a new method for measuring the anisotropic poroelastic moduli from acoustic data was developed. Third, a series of triaxial experiments were conducted on unconsolidated sands to identify pressure/stress conditions where liquefaction occurs under high confining pressures. Stress-induced changes in anisotropic Young's moduli and shear moduli were observed during deformational pathway experiments. A new method was made for the acquisition of compressional and shear wave velocities along a series of 3-dimensional raypaths through a core sample as it is subjected to deformation. Three different deformational pathway experiments were conducted. During the hydrostatic deformation experiment, little or no anisotropy was observed in either the Young's moduli or shear moduli. Significant deformational anisotropies were observed in both moduli during the uniaxial strain test and the triaxial compression experiment but each had a different nature. During the triaxial experiment the axial and lateral Young's moduli and shear moduli continued to diverge as load was applied. During the uniaxial strain experiment the anisotropy was ''locked in'' early in the loading phase but then remained steady as both the confining pressure and axial stress were applied. A new method for measuring anisotropic Biot's effective stress parameters has also been developed. The method involves measuring the compressional and shear wave velocities in the aforementioned acoustic velocity experiments while varying stress paths. For a stress-induced transversely isotropic medium the acoustic velocity data are utilized to calculate the five independent elastic stiffness components. Once the elastic stiffness components are determined these can be used to calculate the anisotropic Biot's effective stress parameters, {alpha}{sub v} and {alpha}{sub h}, using the equations of Abousleiman et al. (1996). A series of experiments have been conducted, on an initially inherently isotropic Berea sandstone rock sample, to dynamically determine these anisotropic Biot's parameters during deformational pathway experiments. Data acquired during hydrostatic, triaxial, and uniaxial strain pathway experiments indicates that Biot's effective stress parameter changes significantly if the applied stresses are not hydrostatic. Variations, as large as 20% between the axial (vertical) and lateral (horizontal) Biot's effective stress parameters, were observed in some experiments. A series of triaxial compression experiments have been conducted on unconsolidated sand (Oil Creek sand) to determine the pressure/stress conditions which would be favorable for liquefaction. Liquefaction of geopressured sands is thought to be one of the major causative mechanisms of damaging shallow water flows. The experiments were developed to determine if: (1) liquefaction could be made to occur in this particular sand at high confining pressures, and (2) the state of liquefication had the same nature at high pressure conditions typical of shallow water flows as it does in low confining pressure soil mechanics tests. A series of undrained triaxial experiments were successfully used to document that the Oil Creek sand could undergo liquefaction. The nature (i.e., the shape of the deformational pathway in mean pressure/shear stress space) was very similar to those observed in soil mechanics experiments. The undrained triaxial experiments also indicated that this sand would strain soften at relatively high confining pressures--a necessary precursor to liquefaction. These experiments serve as a starting point for a series of acoustic experiments to determine the signature of compressional and shear wave properties as the sand packs approach the state of liquefaction (and shallow water flows).

  9. ADVANCED CHARACTERIZATION OF FRACTURED RESERVOIRS IN CARBONATE ROCKS: THE MICHIGAN BASIN

    SciTech Connect (OSTI)

    James R. Wood; William B. Harrison

    2002-12-01

    The purpose of the study was to collect and analyze existing data on the Michigan Basin for fracture patterns on scales ranging form thin section to basin. The data acquisition phase has been successfully concluded with the compilation of several large digital databases containing nearly all the existing information on formation tops, lithology and hydrocarbon production over the entire Michigan Basin. These databases represent the cumulative result of over 80 years of drilling and exploration. Plotting and examination of these data show that contrary to most depictions, the Michigan Basin is in fact extensively faulted and fractured, particularly in the central portion of the basin. This is in contrast to most of the existing work on the Michigan Basin, which tends to show relatively simple structure with few or minor faults. It also appears that these fractures and faults control the Paleozoic sediment deposition, the subsequent hydrocarbon traps and very likely the regional dolomitization patterns. Recent work has revealed that a detailed fracture pattern exists in the interior of the Central Michigan Basin, which is related to the mid-continent gravity high. The inference is that early Precambrian, ({approx}1 Ga) rifting events presumed by many to account for the gravity anomaly subsequently controlled Paleozoic sedimentation and later hydrocarbon accumulation. There is a systematic relationship between the faults and a number of gas and oil reservoirs: major hydrocarbon accumulations consistently occur in small anticlines on the upthrown side of the faults. The main tools used in this study to map the fault/fracture patterns are detailed, close-interval (CI = 10 feet) contouring of the formation top picks accompanied by a new way of visualizing the data using a special color spectrum to bring out the third dimension. In addition, recent improvements in visualization and contouring software were instrumental in the study. Dolomitization is common in the Michigan Basin, and it is crucial in developing reservoir quality rocks in some fields. Data on the occurrence of dolomite was extracted from driller's reports for all reported occurrences in Michigan, nearly 50 fields and over 500 wells. A digital database was developed containing the geographic location of all these wells (latitude-longitude) as well as the elevation of the first encounter of dolomite in the field/reservoir. Analysis shows that these dolomite occurrences are largely confined to the center of the basin, but with some exceptions, such as N. Adams Field. Further, some of the dolomite occurrences show a definite relationship to the fracture pattern described above, suggesting a genetic relationship that needs further work. Other accomplishments of this past reporting period include obtaining a complete land grid for the State of Michigan and further processing of the high and medium resolution DEM files. We also have measured new fluid inclusion data on dolomites from several fields that suggest that the dolomitization occurred at temperatures between 100 and 150 C. Finally, we have extracted the lithologic data for about 5000 wells and are in the process of integrating this data into the overall model for the Michigan Basin.

  10. Design and experimental testing of air slab caps which convert commercial electron diodes into dual purpose, correction-free diodes for small field dosimetry

    SciTech Connect (OSTI)

    Charles, P. H.; Cranmer-Sargison, G.; Thwaites, D. I.; Kairn, T.; Crowe, S. B.; Langton, C. M.; Trapp, J. V.; Pedrazzini, G.; Aland, T.; Kenny, J.

    2014-10-15

    Purpose: Two diodes which do not require correction factors for small field relative output measurements are designed and validated using experimental methodology. This was achieved by adding an air layer above the active volume of the diode detectors, which canceled out the increase in response of the diodes in small fields relative to standard field sizes. Methods: Due to the increased density of silicon and other components within a diode, additional electrons are created. In very small fields, a very small air gap acts as an effective filter of electrons with a high angle of incidence. The aim was to design a diode that balanced these perturbations to give a response similar to a water-only geometry. Three thicknesses of air were placed at the proximal end of a PTW 60017 electron diode (PTWe) using an adjustable “air cap”. A set of output ratios (OR{sub Det}{sup f{sub c}{sub l}{sub i}{sub n}}) for square field sizes of side length down to 5 mm was measured using each air thickness and compared to OR{sub Det}{sup f{sub c}{sub l}{sub i}{sub n}} measured using an IBA stereotactic field diode (SFD). k{sub Q{sub c{sub l{sub i{sub n,Q{sub m{sub s{sub r}{sup f{sub c}{sub l}{sub i}{sub n},f{sub m}{sub s}{sub r}}}}}}}}} was transferred from the SFD to the PTWe diode and plotted as a function of air gap thickness for each field size. This enabled the optimal air gap thickness to be obtained by observing which thickness of air was required such that k{sub Q{sub c{sub l{sub i{sub n,Q{sub m{sub s{sub r}{sup f{sub c}{sub l}{sub i}{sub n},f{sub m}{sub s}{sub r}}}}}}}}} was equal to 1.00 at all field sizes. A similar procedure was used to find the optimal air thickness required to make a modified Sun Nuclear EDGE detector (EDGEe) which is “correction-free” in small field relative dosimetry. In addition, the feasibility of experimentally transferring k{sub Q{sub c{sub l{sub i{sub n,Q{sub m{sub s{sub r}{sup f{sub c}{sub l}{sub i}{sub n},f{sub m}{sub s}{sub r}}}}}}}}} values from the SFD to unknown diodes was tested by comparing the experimentally transferred k{sub Q{sub c{sub l{sub i{sub n,Q{sub m{sub s{sub r}{sup f{sub c}{sub l}{sub i}{sub n},f{sub m}{sub s}{sub r}}}}}}}}} values for unmodified PTWe and EDGEe diodes to Monte Carlo simulated values. Results: 1.0 mm of air was required to make the PTWe diode correction-free. This modified diode (PTWe{sub air}) produced output factors equivalent to those in water at all field sizes (5–50 mm). The optimal air thickness required for the EDGEe diode was found to be 0.6 mm. The modified diode (EDGEe{sub air}) produced output factors equivalent to those in water, except at field sizes of 8 and 10 mm where it measured approximately 2% greater than the relative dose to water. The experimentally calculated k{sub Q{sub c{sub l{sub i{sub n,Q{sub m{sub s{sub r}{sup f{sub c}{sub l}{sub i}{sub n},f{sub m}{sub s}{sub r}}}}}}}}} for both the PTWe and the EDGEe diodes (without air) matched Monte Carlo simulated results, thus proving that it is feasible to transfer k{sub Q{sub c{sub l{sub i{sub n,Q{sub m{sub s{sub r}{sup f{sub c}{sub l}{sub i}{sub n},f{sub m}{sub s}{sub r}}}}}}}}} from one commercially available detector to another using experimental methods and the recommended experimental setup. Conclusions: It is possible to create a diode which does not require corrections for small field output factor measurements. This has been performed and verified experimentally. The ability of a detector to be “correction-free” depends strongly on its design and composition. A nonwater-equivalent detector can only be “correction-free” if competing perturbations of the beam cancel out at all field sizes. This should not be confused with true water equivalency of a detector.

  11. Wall rock-magma interactions in Etna, Italy, studied by U-Th disequilibrium and rare earth element systematics

    SciTech Connect (OSTI)

    Villemant, B. CNRS URA 196, Paris ); Michaud, V.; Metrich, N. )

    1993-03-01

    [sup 230]Th/[sup 238]U disequilibria have been studied in xenoliths and associated lavas of the 1892 and 1989 eruptions of Etna. Most xenoliths are out of secular equilibrium within 1 [sigma] errors and have lower [sup 230]Th/[sup 232]Th ratios than their host magmas. Siliceous and peraluminous xenoliths display large ranges of Th/U ratios for similar [sup 230]Th/[sup 232]Th values, which are interpreted in terms of Th isotopic rehomogenization. The siliceous xenoliths have also suffered thorium and uranium enrichments, which are best explained by chemical diffusion between xenolith melts and differentiated magmas. Estimates of thorium self-diffusivities and [sup 230]Th-[sup 238]U disequilibria give age constraints on these events corresponding to the last major volcanic event of Etna at 14 ka (formation of the elliptic crater caldera). These results suggest that magma storage in superficial and long-lived magma chambers favors the thorium isotopic homogenization of wall rocks by a thermal effect. Chemical diffusion of uranium and thorium and isotopic homogenization between siliceous melts of wall rocks and differentiated magmas may significantly modify the initial thorium isotopic compositions. Such contamination processes could explain the large variations of the [sup 230]Th/[sup 232]Th initial ratios of Etna magmas. 33 refs., 7 figs., 1 tab.

  12. A direct method for determining complete positive and negative capillary pressure curves for reservoir rock using the centrifuge

    SciTech Connect (OSTI)

    Spinler, E.A.; Baldwin, B.A.

    1997-08-01

    A method is being developed for direct experimental determination of capillary pressure curves from saturation distributions produced during centrifuging fluids in a rock plug. A free water level is positioned along the length of the plugs to enable simultaneous determination of both positive and negative capillary pressures. Octadecane as the oil phase is solidified by temperature reduction while centrifuging to prevent fluid redistribution upon removal from the centrifuge. The water saturation is then measured via magnetic resonance imaging. The saturation profile within the plug and the calculation of pressures for each point of the saturation profile allows for a complete capillary pressure curve to be determined from one experiment. Centrifuging under oil with a free water level into a 100 percent water saturated plug results in the development of a primary drainage capillary pressure curve. Centrifuging similarly at an initial water saturation in the plug results in the development of an imbibition capillary pressure curve. Examples of these measurements are presented for Berea sandstone and chalk rocks.

  13. Biogenicity and Syngeneity of Organic Matter in Ancient Sedimentary Rocks: Recent Advances in the Search for Evidence of Past Life

    SciTech Connect (OSTI)

    Oehler, Dorothy Z.; Cady, Sherry L.

    2014-12-01

    he past decade has seen an explosion of new technologies for assessment of biogenicity and syngeneity of carbonaceous material within sedimentary rocks. Advances have been made in techniques for analysis of in situ organic matter as well as for extracted bulk samples of soluble and insoluble (kerogen) organic fractions. The in situ techniques allow analysis of micrometer-to-sub-micrometer-scale organic residues within their host rocks and include Raman and fluorescence spectroscopy/imagery, confocal laser scanning microscopy, and forms of secondary ion/laser-based mass spectrometry, analytical transmission electron microscopy, and X-ray absorption microscopy/spectroscopy. Analyses can be made for chemical, molecular, and isotopic composition coupled with assessment of spatial relationships to surrounding minerals, veins, and fractures. The bulk analyses include improved methods for minimizing contamination and recognizing syngenetic constituents of soluble organic fractions as well as enhanced spectroscopic and pyrolytic techniques for unlocking syngenetic molecular signatures in kerogen. Together, these technologies provide vital tools for the study of some of the oldest and problematic carbonaceous residues and for advancing our understanding of the earliest stages of biological evolution on Earth and the search for evidence of life beyond Earth. We discuss each of these new technologies, emphasizing their advantages and disadvantages, applications, and likely future directions.

  14. Tomographic imaging of rock conditions ahead of mining using the shearer as a seismic source - A feasibility study

    SciTech Connect (OSTI)

    Luo, X.; King, A.; Van de Werken, M.

    2009-11-15

    Roof falls due to poor rock conditions in a coal longwall panel may threaten miner's life and cause significant interruption to mine production. There has been a requirement for technologies that are capable of imaging the rock conditions in longwall coal mining, ahead of the working face and without any interruption to production. A feasibility study was carried out to investigate the characteristics of seismic signals generated by the continuous coal cutter (shearer) and recorded by geophone arrays deployed ahead of the working face, for the purpose of seismic tomographic imaging of roof strata condition before mining. Two experiments were conducted at a coal mine using two arrays of geophones. The experiments have demonstrated that the longwall shearer generates strong and low-frequency (similar to 40 Hz) seismic energy that can be adequately detected by geophones deployed in shallow boreholes along the roadways as far as 300 m from the face. Using noise filtering and signal cross correlation techniques, the seismic arrival times associated with the shearer cutting can be reliably determined. It has proved the concept that velocity variations ahead of the face can be mapped out using tomographic techniques while mining is in progress.

  15. Characterising and modelling the excavation damaged zone (EDZ) in crystalline rock in the context of radioactive waste disposal

    SciTech Connect (OSTI)

    Hudson, J.A.; Backstrom, A.; Rutqvist, J.; Jing, L.; Backers, T.; Chijimatsu, M.; Christiansson, R.; Feng, X.-T.; Kobayashi, A.; Koyama, T.; Lee, H.-S.; Neretnieks, I.; Pan, P.Z.; Rinne, M.; Shen, B.-T.

    2008-10-01

    This paper describes current knowledge about the nature of and potential for thermo-hydro-mechanical-chemical modelling of the Excavation Damaged Zone (EDZ) around the excavations for an underground radioactive waste repository. In the first part of the paper, the disturbances associated with excavation are explained, together with reviews of Workshops that have been held on the subject. In the second part of the paper, the results of a DECOVALEX research programme on modelling the EDZ are presented. Four research teams used four different models to simulate the complete stress-strain curve for Avro granite from the Swedish Aespoe Hard Rock Laboratory. Subsequent research extended the work to computer simulation of the evolution of the repository using a 'wall block model' and a 'near-field model'. This included assessing the evolution of stress, failure and permeability and time dependent effects during repository evolution. As discussed, all the computer models are well suited to sensitivity studies for evaluating the influence of their respective supporting parameters on the complete stress-strain curve for rock and for modelling the EDZ.

  16. Digitally Available Interval-Specific Rock-Sample Data Compiled from Historical Records, Nevada Test Site and Vicinity, Nye County, Nevada

    SciTech Connect (OSTI)

    David B. Wood

    2009-10-08

    Between 1951 and 1992, underground nuclear weapons testing was conducted at 828 sites on the Nevada Test Site, Nye County, Nevada. Prior to and following these nuclear tests, holes were drilled and mined to collect rock samples. These samples are organized and stored by depth of borehole or drift at the U.S. Geological Survey Core Library and Data Center at Mercury, Nevada, on the Nevada Test Site. From these rock samples, rock properties were analyzed and interpreted and compiled into project files and in published reports that are maintained at the Core Library and at the U.S. Geological Survey office in Henderson, Nevada. These rock-sample data include lithologic descriptions, physical and mechanical properties, and fracture characteristics. Hydraulic properties also were compiled from holes completed in the water table. Rock samples are irreplaceable because pre-test, in-place conditions cannot be recreated and samples cannot be recollected from the many holes destroyed by testing. Documenting these data in a published report will ensure availability for future investigators.

  17. Evaluation of experimentally measured and model-calculated pH for rock-brine-CO2 systems under geologic CO2 sequestration conditions

    SciTech Connect (OSTI)

    Shao, Hongbo; Thompson, Christopher J.; Cantrell, Kirk J.

    2013-11-01

    pH is an essential parameter for understanding the geochemical reactions that occur in rock-brine-CO2 systems when CO2 is injected into deep geologic formations for long-term storage. Due to a lack of reliable experimental methods, most laboratory studies conducted under geological CO2 sequestration (GCS) conditions have relied on thermodynamic modeling to estimate pH. The accuracy of these model predictions is typically uncertain. In our previous work, we have developed a method for pH determination by in-situ spectrophotometry. In the present work, we expanded the applicable pH range for this method and measured the pH of several rock-brine-CO2 systems at GCS conditions for five rock samples collected from ongoing GCS demonstration projects. Experimental measurements were compared with pH values calculated using several geochemical modeling approaches. The effect of different thermodynamic databases on the accuracy of model prediction was evaluated. Results indicate that the accuracy of model calculations is rock-dependent. For rocks comprised of carbonate and sandstone, model results generally agreed well with experimentally measured pH; however, for basalt, significant differences were observed. These discrepancies may be due to the models’ failure to fully account for certain reaction occurring between the basalt minerals the CO2-saturated brine solutions.

  18. Investigation of arsenic and antimony capping layers, and half cycle reactions during atomic layer deposition of Al{sub 2}O{sub 3} on GaSb(100)

    SciTech Connect (OSTI)

    Zhernokletov, Dmitry M.; Dong, Hong; Brennan, Barry; Kim, Jiyoung; Wallace, Robert M.; Yakimov, Michael; Tokranov, Vadim; Oktyabrsky, Serge

    2013-11-15

    In-situ monochromatic x-ray photoelectron spectroscopy, low energy electron diffraction, ion scattering spectroscopy, and transmission electron microscopy are used to examine the GaSb(100) surfaces grown by molecular beam epitaxy after thermal desorption of a protective As or Sb layer and subsequent atomic layer deposition (ALD) of Al{sub 2}O{sub 3}. An antimony protective layer is found to be more favorable compared to an arsenic capping layer as it prevents As alloys from forming with the GaSb substrate. The evolution of oxide free GaSb/Al{sub 2}O{sub 3} interface is investigated by “half-cycle” ALD reactions of trimethyl aluminum and deionized water.

  19. Geochemical indicators of depositional environment and soruce-rock potential for the Upper Ordovician Maquoketa Group, Illinois basin

    SciTech Connect (OSTI)

    Guthrie, J.M.; Pratt, L.M. )

    1994-05-01

    Two depositional cycles are recognized within the Upper Ordovician Maquoketa Group of the Illinois basin in a core from the New Jersey Zinc 1 Parrish well of Fulton County, Illinois. Organic carbon (C[sub org]), total sulfur, [sup 13]C content of the organic carbon ([delta][sup 13]C[sub org]), hydrogen and oxygen indices (HI and OI) from Rock-Eval pyrolysis and yields of extractable organic matter (EOM) vary through the cycles. Dark-brown to black, laminated shales are present in the lower portion of each cycle and have high values of C[sub org] (1.0-3.0%), HI (500-1000 mg hydrocarbon [HC]/g total organic carbon[TOC]), and EOM (500-2500 ppm), and more negative [delta][sup 13]C[sub org] values ([delta][sup 13]C[sub org] = -30 to -30.5%). Gray to greenish-gray, bioturbated shales are present in the upper portion of each cycle and have low values of C[sub org] (<1.0%), HI (<500 mg HC/g TOC), and EOM (<500 ppm), and more positive [delta][sup 13]C[sub org] values (-28.5 to 29.5%) compared to the laminated shales. Although thermally immature or marginally mature in this core, the laminated shales represent potential source rock s for petroleum because they contain good to excellent quantities of oil-prone organic matter and are more deeply buried in other areas of the basin. Kerogen elemental data and Rock-Eval data suggest that the source of organic matter in the Maquoketa was uniform, with the notable exception of graptolite-rich layers. Distributions of saturated hydrocarbons for Maquoketa samples resemble those derived from amorphous organic matter. Variations in bulk geochemical data and carbon isotopic compositions within the Maquoketa Group indicate substantial reworking and degradation of organic matter associated with bioturbation and oxygenated depositional conditions. 64 refs., 10 figs., 1 tab.

  20. Strontium Isotopic Composition of Paleozoic Carbonate Rocks in the Nevada Test Site Vicinity, Clark, Lincoln, and Nye Counties, Nevada and Inyo County, California.

    SciTech Connect (OSTI)

    James B. Paces; Zell E. Peterman; Kiyoto Futa; Thomas A. Oliver; and Brian D. Marshall.

    2007-08-07

    Ground water moving through permeable Paleozoic carbonate rocks represents the most likely pathway for migration of radioactive contaminants from nuclear weapons testing at the Nevada Test Site, Nye County, Nevada. The strontium isotopic composition (87Sr/86Sr) of ground water offers a useful means of testing hydrochemical models of regional flow involving advection and reaction. However, reaction models require knowledge of 87Sr/86Sr data for carbonate rock in the Nevada Test Site vicinity, which is scarce. To fill this data gap, samples of core or cuttings were selected from 22 boreholes at depth intervals from which water samples had been obtained previously around the Nevada Test Site at Yucca Flat, Frenchman Flat, Rainier Mesa, and Mercury Valley. Dilute acid leachates of these samples were analyzed for a suite of major- and trace-element concentrations (MgO, CaO, SiO2, Al2O3, MnO, Rb, Sr, Th, and U) as well as for 87Sr/86Sr. Also presented are unpublished analyses of 114 Paleozoic carbonate samples from outcrops, road cuts, or underground sites in the Funeral Mountains, Bare Mountain, Striped Hills, Specter Range, Spring Mountains, and ranges east of the Nevada Test Site measured in the early 1990's. These data originally were collected to evaluate the potential for economic mineral deposition at the potential high-level radioactive waste repository site at Yucca Mountain and adjacent areas (Peterman and others, 1994). Samples were analyzed for a suite of trace elements (Rb, Sr, Zr, Ba, La, and Ce) in bulk-rock powders, and 87Sr/86Sr in partial digestions of carbonate rock using dilute acid or total digestions of silicate-rich rocks. Pre-Tertiary core samples from two boreholes in the central or western part of the Nevada Test Site also were analyzed. Data are presented in tables and summarized in graphs; however, no attempt is made to interpret results with respect to ground-water flow paths in this report. Present-day 87Sr/86Sr values are compared to values for Paleozoic seawater present at the time of deposition. Many of the samples have 87Sr/86Sr compositions that remain relatively unmodified from expected seawater values. However, rocks underlying the northern Nevada Test Site as well as rocks exposed at Bare Mountain commonly have elevated 87Sr/86Sr values derived from post-depositional addition of radiogenic Sr most likely from fluids circulating through rubidium-rich Paleozoic strata or Precambrian basement rocks.