National Library of Energy BETA

Sample records for max psi aromatics

  1. Max Schulze

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Today, he is a three-time unicycling world champion, with world wins in New Zealand in 2010, Italy in 2012 and Canada in 2014. June 9, 2015 Max Schulze Max Schulze "I really thrive ...

  2. Summary Max Total Units

    Energy Savers [EERE]

    Summary Max Total Units *If All Splits, No Rack Units **If Only FW, AC Splits 1000 52 28 28 2000 87 59 35 3000 61 33 15 4000 61 33 15 Totals 261 153 93 ***Costs $1,957,500.00 $1,147,500.00 $697,500.00 Notes: added several refrigerants removed bins from analysis removed R-22 from list 1000lb, no Glycol, CO2 or ammonia Seawater R-404A only * includes seawater units ** no seawater units included *** Costs = (total units) X (estimate of $7500 per unit) 1000lb, air cooled split systems, fresh water

  3. SCIDAC-PSI.WIRTH.130319.ppt

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    under combined thermalparticle fluxes * Wirth, Nordlund, Whyte, and Xu, Materials Research Society Bulletin 36 (2011) 216-222 Complex, interlinked PSI phenomena* Figure of...

  4. EA-161 PSI Energy, Inc | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Inc EA-161 PSI Energy, Inc Order authorizing PSI Energy, Inc to export electric energy to Canada. PDF icon EA-161 PSI Energy, Inc More Documents & Publications EA-162 PP&L, Inc

  5. Production of J/{Psi} in 800 GeV/c p-Si interactions

    SciTech Connect (OSTI)

    Fermilab E771 Collaboration

    1994-07-01

    The authors report on the analysis of high mass opposite sign dimuon states produced in pSi interactions at {radical}s = 38.7 GeV. These data have been collected with an open geometry fixed target spectrometer in the Fermilab Experiment E771. J/{psi} and {psi}(2S) total cross section sand J/{psi} x{sub f} and p{sub t} differential cross sections have been measured and compared with extrapolations from data at lower energies. Evidence for {Upsilon} meson production is also presented.

  6. Inclusive radiative J/{psi} decays

    SciTech Connect (OSTI)

    Besson, D.; Pedlar, T. K.; Cronin-Hennessy, D.; Gao, K. Y.; Hietala, J.; Kubota, Y.; Klein, T.; Lang, B. W.; Poling, R.; Scott, A. W.; Zweber, P.; Dobbs, S.; Metreveli, Z.; Seth, K. K.; Tomaradze, A.; Libby, J.; Powell, A.; Wilkinson, G.; Ecklund, K. M.; Love, W.

    2008-08-01

    Using data taken with the CLEO-c detector at the Cornell Electron Storage Ring, we have investigated the direct-photon momentum spectrum in the decay J/{psi}(1S){yields}{gamma}gg, via the ''tagged'' process: e{sup +}e{sup -}{yields}{psi}(2S); {psi}(2S){yields}J/{psi}{pi}{sup +}{pi}{sup -}; J/{psi}{yields}{gamma}+X. Including contributions from two-body radiative decay processes, we find the ratio of the inclusive direct-photon branching fraction to that of the dominant three-gluon branching fraction [R{sub {gamma}}=B(gg{gamma})/B(ggg)] to be R{sub {gamma}}=0.137{+-}0.001{+-}0.016{+-}0.004, where the errors shown are statistical, systematic, and the model-dependent uncertainty related to the extrapolation to zero photon energy. The shape of the scaled photon energy spectrum in J/{psi}{yields}gg{gamma} is observed to be very similar to that of {upsilon}{yields}gg{gamma}. The R{sub {gamma}} value obtained is roughly consistent with that expected by a simple quark-charge scaling [R{sub {gamma}}{approx}(q{sub c}/q{sub b}){sup 2}] of the value determined at the {upsilon}(1S), but somewhat higher than the value expected from the running of the strong coupling constant.

  7. J/psi physics at BEPC

    SciTech Connect (OSTI)

    Chanowitz, M.S.

    1984-06-01

    J/psi physics is discussed which will be of interest at T > 1988, the period of operation of the Beijing Electron Positron Collider. Emphasis is placed on the gluonic states which are best studied in radiative J/psi decay. The difficulties of these studies are discussed and the need for very high statistics is stressed. In particular it is essential to partial-wave-analyze the hadronic final states produced in J/psi ..-->.. ..gamma..X. An estimate using fixed target data suggests that 0(10/sup 8/) J/psi decays are needed to do an unambiguous partial wave analysis for hadron masses up to about 2 GeV. This requirement is an excellent match to the BEPC design parameters, which imply production of 0(10/sup 8/) J/psi's per year. With a J/psi production rate an order of magnitude greater than other electron-positron storage rings, BEPC will be a unique world facility for these studies. 58 references.

  8. Max Ambiental S A | Open Energy Information

    Open Energy Info (EERE)

    Ambiental S A Jump to: navigation, search Name: Max Ambiental S.A. Place: Sao Paulo, Brazil Zip: 01452-938 Sector: Carbon Product: Max Ambiental is a company involved in the...

  9. MaxWest Environmental Systems | Open Energy Information

    Open Energy Info (EERE)

    MaxWest Environmental Systems Jump to: navigation, search Name: MaxWest Environmental Systems Place: Houston, Texas Zip: 77057 Product: MaxWest Environmental Systems designs,...

  10. Resumming the color octet contribution to e+ e- ---> J / psi...

    Office of Scientific and Technical Information (OSTI)

    Resumming the color octet contribution to e+ e- ---> J psi + X Citation Details In-Document Search Title: Resumming the color octet contribution to e+ e- ---> J psi + X Recent ...

  11. Resumming the color octet contribution to e+ e- ---> J / psi...

    Office of Scientific and Technical Information (OSTI)

    Resumming the color octet contribution to e+ e- ---> J psi + X Citation Details In-Document Search Title: Resumming the color octet contribution to e+ e- ---> J psi + X You ...

  12. Inclusive radiative {psi}(2S) decays

    SciTech Connect (OSTI)

    Libby, J.; Martin, L.; Powell, A.; Thomas, C.; Wilkinson, G.; Mendez, H.; Ge, J. Y.; Miller, D. H.; Shipsey, I. P. J.; Xin, B.; Adams, G. S.; Hu, D.; Moziak, B.; Napolitano, J.; Ecklund, K. M.; He, Q.; Insler, J.; Muramatsu, H.; Park, C. S.; Thorndike, E. H.

    2009-10-01

    Using e{sup +}e{sup -} collision data taken with the CLEO-c detector at the Cornell Electron Storage Ring, we have investigated the direct photon spectrum in the decay {psi}(2S){yields}{gamma}gg. We determine the ratio of the inclusive direct photon decay rate to that of the dominant three-gluon decay rate {psi}(2S){yields}ggg (R{sub {gamma}}{identical_to}{gamma}({gamma}gg)/{gamma}(ggg)) to be R{sub {gamma}}(z{sub {gamma}}>0.4)=0.070{+-}0.002{+-}0.019{+-}0.011, with z{sub {gamma}} defined as the scaled photon energy relative to the beam energy. The errors shown are statistical, systematic, and that due to the uncertainty in the input branching fractions used to extract the ratio, respectively.

  13. sc0013735-psi | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    735-psi High Performance Airborne Laser Scanner for Routine Mapping of Terrain from Unmanned Aircraft Systems (UASs) Last Reviewed 11/27/2015 DE-SC0013735 Goal This project will develop a conceptual design for an unmanned aerial system-based laser scanner for aerial mapping that preserves the performance of larger systems flown on manned aircraft, but is small enough to be deployed on midsize unmanned aerial systems. This will enable more economical digital terrain mapping than manned systems.

  14. Make aromatics from LPG

    SciTech Connect (OSTI)

    Doolan, P.C. ); Pujado, P.R. )

    1989-09-01

    Liquefied petroleum gas (LPG) consists mainly of the propane and butane fraction recovered from gas fields, associated petroleum gas and refinery operations. Apart from its use in steam cracking and stream reforming, LPG has few petrochemical applications. The relative abundance of LPG and the strong demand for aromatics - benzene, toluene and xylenes (BTX) - make it economically attractive to produce aromatics via the aromatization of propane and butanes. This paper describes the Cyclar process, which is based on a catalyst formulation developed by BP and which uses UOP's CCR catalyst regeneration technology, converts propane, butanes or mixtures thereof to petrochemical-quality aromatics in a single step.

  15. Phi ({Phi}) and psi ({Psi}) angles involved in malarial peptide bonds determine sterile protective immunity

    SciTech Connect (OSTI)

    Patarroyo, Manuel E.; Moreno-Vranich, Armando; Bermudez, Adriana

    2012-12-07

    Highlights: Black-Right-Pointing-Pointer Phi ({Phi}) and psi ({Psi}) angles determine sterile protective immunity. Black-Right-Pointing-Pointer Modified peptide's tendency to assume a regular conformation related to a PPII{sub L}. Black-Right-Pointing-Pointer Structural modifications in mHABPs induce Ab and protective immunity. Black-Right-Pointing-Pointer mHABP backbone atom's interaction with HLA-DR{beta}1{sup Asterisk-Operator} is stabilised by H-bonds. -- Abstract: Modified HABP (mHABP) regions interacting with HLA-DR{beta}1{sup Asterisk-Operator} molecules have a more restricted conformation and/or sequence than other mHABPs which do not fit perfectly into their peptide binding regions (PBR) and do not induce an acceptable immune response due to the critical role of their {Phi} and {Psi} torsion angles. These angle's critical role was determined in such highly immunogenic, protection-inducing response against experimental malaria using the conformers (mHABPs) obtained by {sup 1}H-NMR and superimposed into HLA-DR{beta}1{sup Asterisk-Operator }-like Aotus monkey molecules; their phi ({Phi}) and psi ({Psi}) angles were measured and the H-bond formation between these molecules was evaluated. The aforementioned mHABP propensity to assume a regular conformation similar to a left-handed polyproline type II helix (PPII{sub L}) led to suggesting that favouring these conformations according to their amino acid sequence would lead to high antibody titre production and sterile protective immunity induction against malaria, thereby adding new principles or rules for vaccine development, malaria being one of them.

  16. SolarMax Inc | Open Energy Information

    Open Energy Info (EERE)

    Korea (Republic) Zip: 445-912 Sector: Solar Product: Manufacturer and engineer of solar heating systems and boilers. References: SolarMax Inc1 This article is a stub. You...

  17. max kwh | OpenEI Community

    Open Energy Info (EERE)

    This is likely due to users not understanding the meaning of "Max kWh"--often I see things like: "300, 700, 1000" (derived from "first 300, next 700, greater than 1000") which...

  18. Max Tech and Beyond Design Competition

    Broader source: Energy.gov [DOE]

    The Max Tech and Beyond Design Competition is an annual competition run by the Department of Energy (DOE) and the Lawrence Berkeley National Laboratory (LBNL) that challenges students to design...

  19. Bridging the PSI Knowledge Gap: A Multi-Scale Approach

    SciTech Connect (OSTI)

    Wirth, Brian D

    2015-01-08

    Plasma-surface interactions (PSI) pose an immense scientific hurdle in magnetic confinement fusion and our present understanding of PSI in confinement environments is highly inadequate; indeed, a recent Fusion Energy Sciences Advisory Committee report found that 4 out of the 5 top five fusion knowledge gaps were related to PSI. The time is appropriate to develop a concentrated and synergistic science effort that would expand, exploit and integrate the wealth of laboratory ion-beam and plasma research, as well as exciting new computational tools, towards the goal of bridging the PSI knowledge gap. This effort would broadly advance plasma and material sciences, while providing critical knowledge towards progress in fusion PSI. This project involves the development of a Science Center focused on a new approach to PSI science; an approach that both exploits access to state-of-the-art PSI experiments and modeling, as well as confinement devices. The organizing principle is to develop synergistic experimental and modeling tools that treat the truly coupled multi-scale aspect of the PSI issues in confinement devices. This is motivated by the simple observation that while typical lab experiments and models allow independent manipulation of controlling variables, the confinement PSI environment is essentially self-determined with few outside controls. This means that processes that may be treated independently in laboratory experiments, because they involve vastly different physical and time scales, will now affect one another in the confinement environment. Also, lab experiments cannot simultaneously match all exposure conditions found in confinement devices typically forcing a linear extrapolation of lab results. At the same time programmatic limitations prevent confinement experiments alone from answering many key PSI questions. The resolution to this problem is to usefully exploit access to PSI science in lab devices, while retooling our thinking from a linear and de-coupled extrapolation to a multi-scale, coupled approach. The PSI Plasma Center consisted of three equal co-centers; one located at the MIT Plasma Science and Fusion Center, one at UC San Diego Center for Energy Research and one at the UC Berkeley Department of Nuclear Engineering, which moved to the University of Tennessee, Knoxville (UTK) with Professor Brian Wirth in July 2010. The Center had three co-directors: Prof. Dennis Whyte led the MIT co-center, the UCSD co-center was led by Dr. Russell Doerner, and Prof. Brian Wirth led the UCB/UTK center. The directors have extensive experience in PSI and material research, and have been internationally recognized in the magnetic fusion, materials and plasma research fields. The co-centers feature keystone PSI experimental and modeling facilities dedicated to PSI science: the DIONISOS/CLASS facility at MIT, the PISCES facility at UCSD, and the state-of-the-art numerical modeling capabilities at UCB/UTK. A collaborative partner in the center is Sandia National Laboratory at Livermore (SNL/CA), which has extensive capabilities with low energy ion beams and surface diagnostics, as well as supporting plasma facilities, including the Tritium Plasma Experiment, all of which significantly augment the Center. Interpretive, continuum material models are available through SNL/CA, UCSD and MIT. The participating institutions of MIT, UCSD, UCB/UTK, SNL/CA and LLNL brought a formidable array of experimental tools and personnel abilities into the PSI Plasma Center. Our work has focused on modeling activities associated with plasma surface interactions that are involved in effects of He and H plasma bombardment on tungsten surfaces. This involved performing computational material modeling of the surface evolution during plasma bombardment using molecular dynamics modeling. The principal outcomes of the research efforts within the combined experimental – modeling PSI center are to provide a knowledgebase of the mechanisms of surface degradation, and the influence of the surface on plasma conditions.

  20. Evidence for the decay X(3872) -> J/\\psi\\omega

    SciTech Connect (OSTI)

    del Amo Sanchez, P.; Lees, J.P.; Poireau, V.; Prencipe, E.; Tisserand, V.; Garra Tico, J.; Grauges, E.; Martinelli, M.; Palano, A.; Pappagallo, M.; Eigen, G.; Stugu, B.; Sun, L.; Battaglia, M.; Brown, D.N.; Hooberman, B.; Kerth, L.T.; Kolomensky, Yu.G.; Lynch, G.; Osipenkov, I.L.; Tanabe, T.; /UC, Berkeley /Birmingham U. /Ruhr U., Bochum /British Columbia U. /Brunel U. /Novosibirsk, IYF /UC, Irvine /UC, Riverside /UC, Santa Barbara /UC, Santa Cruz /Caltech /Cincinnati U. /Colorado U. /Colorado State U. /Dortmund U. /Dresden, Tech. U. /Ecole Polytechnique /Edinburgh U. /INFN, Ferrara /Ferrara U. /INFN, Ferrara /INFN, Ferrara /Ferrara U. /INFN, Ferrara /Frascati /INFN, Genoa /Genoa U. /INFN, Genoa /INFN, Genoa /Genoa U. /INFN, Genoa /INFN, Genoa /Genoa U. /Indian Inst. Tech., Guwahati /Harvard U. /Heidelberg U. /Humboldt U., Berlin /Imperial Coll., London /Iowa State U. /Iowa State U. /Johns Hopkins U. /Paris U., VI-VII /LLNL, Livermore /Liverpool U. /Queen Mary, U. of London /Royal Holloway, U. of London /Royal Holloway, U. of London /Louisville U. /Mainz U., Inst. Kernphys. /Manchester U. /Maryland U. /Massachusetts U., Amherst /MIT /McGill U. /INFN, Milan /Milan U. /INFN, Milan /INFN, Milan /Milan U. /Mississippi U. /Montreal U. /INFN, Naples /Naples U. /NIKHEF, Amsterdam /NIKHEF, Amsterdam /Notre Dame U. /Ohio State U. /Oregon U. /INFN, Padua /Padua U. /INFN, Padua /INFN, Padua /Padua U. /Paris U., VI-VII /INFN, Perugia /Perugia U. /INFN, Pisa /Pisa U. /INFN, Pisa /Pisa, Scuola Normale Superiore /INFN, Pisa /Pisa U. /INFN, Pisa /Princeton U. /INFN, Rome /INFN, Rome /Rome U. /INFN, Rome /INFN, Rome /Rome U. /INFN, Rome /INFN, Rome /Rome U. /INFN, Rome /INFN, Rome /Rome U. /Rostock U. /Rutherford /DAPNIA, Saclay /SLAC /South Carolina U. /Southern Methodist U. /Stanford U., Phys. Dept. /SUNY, Albany /Tel Aviv U. /Tennessee U. /Texas U. /Texas U., Dallas /INFN, Turin /Turin U. /INFN, Trieste /Trieste U. /Valencia U. /Victoria U. /Warwick U. /Wisconsin U., Madison

    2011-08-11

    We present a study of the decays B{sup 0,+} --> J/{psi}{pi}{sup +}{pi}{sup -}{pi}{sup 0}K{sup 0,+}, using 467x10{sup 6} B{anti B} pairs recorded with the BABAR detector. We present evidence for the decay mode X(3872) --> J/{psi}{omega}, with product branching fractions B(B{sup +} --> X(3872)K{sup +}) x B(X(3872) --> J/{psi}{omega}) = [0.6 {+-} 0.2(stat) {+-} 0.1(syst)] x 10{sup -5}, and B(B{sup 0} --> X(3872)K{sup 0}) x B(X(3872) --> J/{psi}{omega}) = [0.6 {+-} 0.3(stat) {+-} 0.1(syst)] x 10{sup -5}. A detailed study of the {pi}{sup +}{pi}{sup -}{pi}{sup 0} mass distribution from X(3872) decay favors a negative-parity assignment.

  1. Rainer Held > Guest Researcher - Max-Planck Institute for Solid...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rainer Held Guest Researcher - Max-Planck Institute for Solid State Research heldrain@gmail.com Formerly a member of the Schlom Group, he joined the Max-Planck Institute for Solid...

  2. Neutron Damage and MAX Phase Ternary Compounds

    SciTech Connect (OSTI)

    Barsoum, Michael; Hoffman, Elizabeth; Sindelar, Robert; Garcua-Duaz, Brenda; Kohse, Gordon

    2014-06-17

    The Demands of Gen IV nuclear power plants for long service life under neutron radiation at high temperature are severe. Advanced materials that would withstand high temperatures (up to 1000+ C) to high doses in a neutron field would be ideal for reactor internal structures and would add to the long service life and reliability of the reactors. The objective of this work is to investigate the response of a new class of machinable, conductive, layered, ternary transition metal carbides and nitrides - the so-called MAX phases - to low and moderate neutron dose levels.

  3. Aromatic molecules as spintronic devices

    SciTech Connect (OSTI)

    Ojeda, J. H.; Orellana, P. A.; Laroze, D.

    2014-03-14

    In this paper, we study the spin-dependent electron transport through aromatic molecular chains attached to two semi-infinite leads. We model this system taking into account different geometrical configurations which are all characterized by a tight binding Hamiltonian. Based on the Green's function approach with a Landauer formalism, we find spin-dependent transport in short aromatic molecules by applying external magnetic fields. Additionally, we find that the magnetoresistance of aromatic molecules can reach different values, which are dependent on the variations in the applied magnetic field, length of the molecules, and the interactions between the contacts and the aromatic molecule.

  4. J/psi and psi(2S) production in pp collisions at sqrt(s) = 7 TeV

    SciTech Connect (OSTI)

    Chatrchyan, Serguei; et al.

    2012-02-01

    A measurement of the J/psi and psi(2S) production cross sections in pp collisions at sqrt(s)=7 TeV with the CMS experiment at the LHC is presented. The data sample corresponds to an integrated luminosity of 37 inverse picobarns. Using a fit to the invariant mass and decay length distributions, production cross sections have been measured separately for prompt and non-prompt charmonium states, as a function of the meson transverse momentum in several rapidity ranges. In addition, cross sections restricted to the acceptance of the CMS detector are given, which are not affected by the polarization of the charmonium states. The ratio of the differential production cross sections of the two states, where systematic uncertainties largely cancel, is also determined. The branching fraction of the inclusive B to psi(2S) X decay is extracted from the ratio of the non-prompt cross sections to be: BR(B to psi(2S) X) = (3.08 +/- 0.12(stat.+syst.) +/- 0.13(theor.) +/- 0.42(BR[PDG])) 10^-3

  5. AVTA: 2013 Ford C-MAX HEV Testing Results

    Broader source: Energy.gov [DOE]

    VTO's National Laboratories have tested and collected both dynamometer and fleet data for the Ford C-MAX HEV (a hybrid electric vehicle).

  6. Max Tech and Beyond: High-Intensity Discharge Lamps (Technical...

    Office of Scientific and Technical Information (OSTI)

    High-Intensity Discharge Lamps Citation Details In-Document Search Title: Max Tech and ... Visit OSTI to utilize additional information resources in energy science and technology. A ...

  7. DOE - Office of Legacy Management -- Max Zuckerman and Sons Inc...

    Office of Legacy Management (LM)

    Inc - MD 04 FUSRAP Considered Sites Site: MAX ZUCKERMAN & SONS, INC. (MD.04 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: Maryland...

  8. DOE - Office of Legacy Management -- Max Zuckerman and Sons ...

    Office of Legacy Management (LM)

    - IL 30 FUSRAP Considered Sites Site: MAX ZUCKERMAN & SONS (IL.30 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: 1925...

  9. Incorporating the min-max mesh optimization method within the...

    Office of Scientific and Technical Information (OSTI)

    Incorporating the min-max mesh optimization method within the Target-Matrix Paradigm. ... Country of Publication: United States Language: English Word Cloud More Like This Full ...

  10. Incorporating the min-max mesh optimization method within the...

    Office of Scientific and Technical Information (OSTI)

    Title: Incorporating the min-max mesh optimization method within the Target-Matrix ... Country of Publication: United States Language: English Word Cloud More Like This Full ...

  11. SolarMax Technology Inc | Open Energy Information

    Open Energy Info (EERE)

    Technology Inc Jump to: navigation, search Name: SolarMax Technology Inc Place: City of Industry, California Zip: 91745 Product: PV module maker and residential and commercial PV...

  12. Burton Richter, Storage Rings, and the J/psi Particle

    Office of Scientific and Technical Information (OSTI)

    Burton Richter, Storage Rings, and the J/psi Particle Resources with Additional Information * Honors * Interviews Burton Richter Credit: P.A. Moore, SLAC National Accelerator Laboratory "After receiving his B.S. and Ph.D. degrees from the Massachusetts Institute of Technology [MIT] in 1952 and 1956, respectively, [Burton Richter] accepted a post-doctoral position at Stanford University's High Energy Physics Laboratory. There he was seized with the idea to test the accepted theory of Quantum

  13. Inclusive J/{psi} Production in {Upsilon} Decay Via Color-Singlet Mechanism

    SciTech Connect (OSTI)

    He Zhiguo; Wang Jianxiong

    2011-05-23

    We report the recent works about the inclusive J/{psi} production in {Upsilon} decay. Our results show that until now the color-singlet (CS) contribution which includes leading order ({alpha}{sub s}{sup 5}){Upsilon}{yields}J/{psi}+cc-barg process and {alpha}{sub s}{sup 6} order {Upsilon}{yields}J/{psi}+gg(4g) process as well as {alpha}{sub s}{sup 2{alpha}2} order {Upsilon}{yields}J/{psi}+cc-bar and {Upsilon}{yields}J/{psi}+gg processes can not explain the experimental data yet. A preliminary CS prediction of R{sub cc} (B({Upsilon}{yields}J/{psi}+cc-bar+X)/B({Upsilon}{yields}J/{psi}+X)) 0.39{sub -0.20}{sup +0.21}, which is much larger than color-octet (CO) prediction, is also given as a good quantity to discriminate the CS and color-octet mechanism.

  14. University of Maryland Wins Max Tech and Beyond Competition for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ultra-Efficient Clothes Dryer | Department of Energy University of Maryland Wins Max Tech and Beyond Competition for Ultra-Efficient Clothes Dryer University of Maryland Wins Max Tech and Beyond Competition for Ultra-Efficient Clothes Dryer September 10, 2013 - 12:00pm Addthis The Energy Department announced today that the University of Maryland won the second annual Max Tech and Beyond design competition for ultra-low energy use appliances and equipment for the second year in a row. The

  15. Radiative J/psi decays and the pseudoscalar puzzle

    SciTech Connect (OSTI)

    Wermes, N.

    1985-07-01

    Recent results on radiative decays of the J/PSI, obtained by the SPEAR detectors Mark III and Crystal Ball and the DCI detector DM2 at Orsay, are presented. The status of the glueball candidates theta(1690), iota(1460), and xi(220), and the decays J/PHI ..-->.. ..gamma.. Vector Vector are reviewed. A coupled channel analysis of iota(1460) decays to K anti K..pi.., rho rho, ..omega omega.., and ..gamma..rho is presented which may help to understand the pseudoscalar sector in radiative J/PHI decays. 42 refs., 16 figs.

  16. Exclusive J/{psi} electroproduction in a dual model

    SciTech Connect (OSTI)

    Fiore, R.; Jenkovszky, L. L.; Magas, V. K.; Melis, S.; Prokudin, A.

    2009-12-01

    Exclusive J/{psi} electroproduction is studied in the framework of the analytic S-matrix theory. The differential and integrated elastic cross sections are calculated using the modified dual amplitude with Mandelstam analyticity model. The model is applied to the description of the available experimental data and proves to be valid in a wide region of the kinematical variables s, t, and Q{sup 2}. Our amplitude can be used also as a universal background parametrization for the extraction of tiny resonance signals.

  17. Subkilovolt response of Kodak T max XUV film

    SciTech Connect (OSTI)

    Dittmore, C.; Stoering, J.P. ); Gullikson, E. )

    1990-02-08

    A calibration of Kodak T max 100 XUV film at six x-ray energies ranging from 0.27 keV to 1.49 keV has been concluded. The primary purpose was to compare the sensitivity of this film to that of Kodak type 101-07 XUV film in order to appraise the feasibility of replacing the type 101-07 film with the type T max 100 film. In addition to being considerably less expensive, the T max 100 film is less disposed to abrasion from handling. A secondary objective was to provide a base for further response measurements should the T max 100 film prove to be an acceptable substitute for the type 101-07 film. 10 figs., 2 tabs.

  18. Zhejiang Max Solar Energy Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Solar Energy Co Ltd Jump to: navigation, search Name: Zhejiang Max Solar Energy Co Ltd Place: Huzhou, Zhejiang Province, China Zip: 313009 Product: A Zhejiang-based PV module...

  19. The Max Tech and Beyond Competition | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Max Tech and Beyond Competition The Max Tech and Beyond Competition Addthis 1 of 5 Team Cal Poly Solar is working to significantly reduce the cost and construction time on their solar concentrator for cooking. Image: Lawrence Berkeley National Laboratory 2 of 5 Professor Dale Dolan's students from California Polytechnic State University San Luis Obispo Electrical Engineering department testing the placement of their Hybrid Solar Photovoltaic Panel for Pool Heating. Image: Lawrence Berkeley

  20. Detection of chlorinated aromatic compounds

    DOE Patents [OSTI]

    Ekechukwu, A.A.

    1996-02-06

    A method for making a composition for measuring the concentration of chlorinated aromatic compounds in aqueous fluids, and an optical probe for use with the method are disclosed. The composition comprises a hydrophobic polymer matrix, preferably polyamide, with a fluorescent indicator uniformly dispersed therein. The indicator fluoresces in the presence of the chlorinated aromatic compounds with an intensity dependent on the concentration of these compounds in the fluid of interest, such as 8-amino-2-naphthalene sulfonate. The probe includes a hollow cylindrical housing that contains the composition in its distal end. The probe admits an aqueous fluid to the probe interior for exposure to the composition. An optical fiber transmits excitation light from a remote source to the composition while the indicator reacts with chlorinated aromatic compounds present in the fluid. The resulting fluorescence light signal is reflected to a second optical fiber that transmits the light to a spectrophotometer for analysis. 5 figs.

  1. Detection of chlorinated aromatic compounds

    DOE Patents [OSTI]

    Ekechukwu, Amy A.

    1996-01-01

    A method for making a composition for measuring the concentration of chloated aromatic compounds in aqueous fluids, and an optical probe for use with the method. The composition comprises a hydrophobic polymer matrix, preferably polyamide, with a fluorescent indicator uniformly dispersed therein. The indicator fluoresces in the presence of the chlorinated aromatic compounds with an intensity dependent on the concentration of these compounds in the fluid of interest, such as 8-amino-2-naphthalene sulfonate. The probe includes a hollow cylindrical housing that contains the composition in its distal end. The probe admits an aqueous fluid to the probe interior for exposure to the composition. An optical fiber transmits excitation light from a remote source to the composition while the indicator reacts with chlorinated aromatic compounds present in the fluid. The resulting fluorescence light signal is reflected to a second optical fiber that transmits the light to a spectrophotometer for analysis.

  2. Molecular catalytic hydrogenation of aromatic hydrocarbons and...

    Office of Scientific and Technical Information (OSTI)

    catalysts for the hydrogenation of monocyclic aromatic hydrocarbons under mild conditions. ... NAPHTHALENE; CHRYSENE; ORGANOMETALLIC COMPOUNDS; CATALYTIC EFFECTS; RHODIUM COMPOUNDS; ...

  3. The interactional foundations of MaxEnt: Open questions

    SciTech Connect (OSTI)

    Harr, Michael S.

    2014-12-05

    One of the simplest and potentially most useful techniques to be developed in the 20{sup th} century, a century noted for an ever more mathematically sophisticated formulation of the sciences, is that of maximising the entropy of a system in order to generate a descriptive, stochastic model of that system in closed form, often abbreviated to MaxEnt. The extension of MaxEnt to systems beyond the physics from which it originated is hampered by the fact that the microscopic physical interactions that are not justified or justifiable within the MaxEnt framework need to be falsifiably evaluated in each new field of application. It is not obvious that such justification exists for many systems in which the interactions are not directly based on physics. For example what is the justification for the use of MaxEnt in biology, climate modelling or economics? Is it simply a useful heuristic or is there some deeper connection with the foundations of some systems? Without further critical examination of the microscopic foundations that give rise to the success of the MaxEnt principle it is difficult to motivate the use of such techniques in other fields except through theoretically an practically unsatisfying analogical arguments. This article briefly presents the basis of MaxEnt principles as originally introduced in statistical mechanics in the Jaynes form, the Tsallis form and the Rnyi form. Several different applications are introduced including that of ecological diversity where maximising the different diversity measures is equivalent to maximising different entropic functionals.

  4. Paul Blom: Research Director, Max Planck Institute for Polymer Research |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center for Energy Efficient Materials Paul Blom: Research Director, Max Planck Institute for Polymer Research Jan 22, 2014 | 2:00 PM - 3:00 PM Paul Blom Research Director, Max Planck Institute for Polymer Research Transport and Recombination in Polymer:fullerene bulk Heterojunction Solar Cells January 22, 2014 | 2:00pm | ESB 2001 Faculty host: Thuc Quyen-Nguyen >>>Video and Slides available after the presentation* Abstract In solar cells, free charge carriers can recombine both via

  5. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, L.A. Jr.

    1989-07-18

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 fig.

  6. Nucleophilic fluorination of aromatic compounds

    DOE Patents [OSTI]

    Satyamurthy, Nagichettiar; Barrio, Jorge R

    2014-03-18

    Iodylbenzene derivatives substituted with electron donating as well as electron withdrawing groups on the aromatic ring are used as precursors in aromatic nucleophilic substitution reactions. The iodyl group (IO.sub.2) is regiospecifically substituted by nucleophilic fluoride to provide the corresponding fluoroaryl derivatives. No-carrier-added [F-18]fluoride ion derived from anhydrous [F-18](F/Kryptofix, [F-18]CsF or a quaternary ammonium fluoride (e.g., Me.sub.4NF, Et.sub.4NF, n-Bu.sub.4NF, (PhCH.sub.2).sub.4NF) exclusively substitutes the iodyl moiety in these derivatives and provides high specific activity F-18 labeled fluoroaryl analogs. Iodyl derivatives of a benzothiazole analog and 6-iodyl-L-dopa derivatives have been synthesized as precursors and have been used in the preparation of no-carrier-added [F-18]fluorobenzothiazole as well as 6-[F-18]fluoro-L-dopa.

  7. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A.; Arganbright, Robert P.; Hearn, Dennis

    1994-01-01

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

  8. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A.; Arganbright, Robert P.; Hearn, Dennis

    1993-01-01

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene to about the mid point of the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

  9. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A.

    1989-01-01

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

  10. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

    1993-09-07

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a molecular sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene to about the mid point of the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 figures.

  11. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

    1994-06-14

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a molecular sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 fig.

  12. Electroproduction and gluonic production of J/{psi} mesons under the assumption of quark-hadron duality

    SciTech Connect (OSTI)

    Berezhnoy, A. V. Likhoded, A. K.

    2008-02-15

    On the basis of the assumption of quark-hadron duality, it is shown that the color-singlet contribution to the cross sections for the processes e + g {sup {yields}} e + J/{psi} + g and gg {sup {yields}} J/{psi}g increases upon taking into account the relative motion of quarks in the J/{psi} meson.

  13. Electroproduction and gluonic production of J/{psi} mesons under the assumption of quark-hadron duality

    SciTech Connect (OSTI)

    Berezhnoy, A. V.; Likhoded, A. K.

    2008-02-15

    On the basis of the assumption of quark-hadron duality, it is shown that the color-singlet contribution to the cross sections for the processes e + g {yields} e + J/{psi} + g and gg {yields} J/{psi}g increases upon taking into account the relative motion of quarks in the J/{psi} meson.

  14. Observation of. Upsilon. (4 S ) decays into non- B B final states containing. psi. mesons

    SciTech Connect (OSTI)

    Alexander, J.; Artuso, M.; Bebek, C.; Berkelman, K.; Cassel, D.G.; Cheu, E.; Coffman, D.M.; Crawford, G.; DeWire, J.W.; Drell, P.S.; Ehrlich, R.; Galik, R.S.; Gittelman, B.; Gray, S.W.; Halling, A.M.; Hartill, D.L.; Heltsley, B.K.; Kandaswamy, J.; Katayama, N.; Kreinick, D.L.; Lewis, J.D.; Mistry, N.B.; Mueller, J.; Namjoshi, R.; Nandi, S.; Nordberg, E.; O'Grady, C.; Peterson, D.; Pisharody, M.; Riley, D.; Sapper, M.; Silverman, A.; Stone, S.; Worden, H.; Worris, M.; Sadoff, A.J.; Avery, P.; Besson, D.; Garren, L.; Yelton, J.; Bowcock, T.; Kinoshita, K.; Pipkin, F.M.; Procario, M.; Wilson, R.; Wolinski, J.; Xiao, D.; Ammar, R.; Baringer, P.; Coppage, D.; Haas, P.; Lam, H.; Jawahery, A.; Park, C.H.; Kubota, Y.; Nelson, J.K.; Perticone, D.; Poling, R.; Fulton, R.; Jensen, T.; Johnson, D.R.; Kagan, H.; Kass, R.; Morrow, F.; Whitmore, J.; Wilson, P.; Chen, W.; Dominick, J.; McIlwain, R.L.; Miller, D.H.; Ng, C.R.; Schaffner, S.F.; Shibata, E.I.; Yao, W.; Sparks, K.; Thorndike, E.H.; Wang, C

    1990-05-07

    We report on the observation of {psi} mesons from {Upsilon}(4{ital S}) decays which are too energetic to come from {ital B} mesons. These events provide the first evidence for non-{ital B{bar B}} decays of the {Upsilon}(4{ital S}). The measured rate is {ital B}({Upsilon}(4{ital s}){r arrow}{psi}{ital X})=(0.22{plus minus}0.06{plus minus}0.04)% for {psi} momentum above 2 GeV/{ital c}.

  15. Relativistic Corrections to e+e- {yields} J/{psi} + {eta}c in a Potential

    Office of Scientific and Technical Information (OSTI)

    Model (Journal Article) | SciTech Connect Relativistic Corrections to e+e- {yields} J/{psi} + {eta}c in a Potential Model Citation Details In-Document Search Title: Relativistic Corrections to e+e- {yields} J/{psi} + {eta}c in a Potential Model We compute relativistic corrections to the process e+e- {yields} J/{psi} + {eta}c and find that they resolve the discrepancy between theory and experiment. Authors: Bodwin, Geoffrey T. [1] ; Kang, Daekyoung ; Kim, Taewon ; Lee, Jungil ; Yu, Chaehyun

  16. pp{yields}J/{psi}+{Upsilon}+X as a clean probe to the quarkonium production

    Office of Scientific and Technical Information (OSTI)

    mechanism (Journal Article) | SciTech Connect pp{yields}J/{psi}+{Upsilon}+X as a clean probe to the quarkonium production mechanism Citation Details In-Document Search Title: pp{yields}J/{psi}+{Upsilon}+X as a clean probe to the quarkonium production mechanism We report that, unlike most inclusive quarkonium-production processes, the production rate for pp{yields}J/{psi}+{Upsilon}+X dominantly depends on two not well-known long-distance nonrelativistic QCD matrix elements, <O{sub 8}{sup

  17. Measurement of the relative branching ratio of B-s(0) -> J/psi f(0)(980) to B-s(0) -> J/psi phi

    SciTech Connect (OSTI)

    Abazov, V.M.; Abbott, B.; Acharya, B. S.; Adams, M.; Adams, T.; Alexeev, G. D.; Alkhazov, G.; Alton, A.; Alverson, G.; Alves, G. A.; Aoki, M.; Askew, A.; Asman, B.; Atkins, S.; Atramentov, O.; Augsten, K.; Avila, C.; BackusMayes, J.; Badaud, F.; Bagby, L.; Baldin, B.; Bandurin, D. V.; Banerjee, S.; Barberis, E.; Baringer, P.; Barreto, J.; Bartlett, J. F.; Bassler, U.; Bazterra, V.; Bean, A.; Begalli, M.; Belanger-Champagne, C.; Bellantoni, L.; Beri, S. B.; Bernardi, G.; Bernhard, R.; Bertram, I.; Besancon, M.; Beuselinck, R.; Bezzubov, V. A.; Bhat, P. C.; Bhatnagar, V.; Blazey, G.; Blessing, S.; Bloom, K.; Boehnlein, A.; Boline, D.; Boos, E. E.; Borissov, G.; Bose, T.; Brandt, A.; Brandt, O.; Brock, R.; Brooijmans, G.; Bross, A.; Brown, D.; Brown, J.; Bu, X. B.; Buehler, M.; Buescher, V.; Bunichev, V.; Burdin, S.; Burnett, T. H.; Buszello, C. P.; Calpas, B.; Camacho-Perez, E.; Carrasco-Lizarraga, M. A.; Casey, B. C. K.; Castilla-Valdez, H.; Chakrabarti, S.; Chakraborty, D.; Chan, K. M.; Chandra, A.; Chapon, E.; Chen, G.; Chevalier-Thery, S.; Cho, D. K.; Cho, S. W.; Choi, S.; Choudhary, B.; Cihangir, S.; Claes, D.; Clutter, J.; Cooke, M.; Cooper, W. E.; Corcoran, M.; Couderc, F.; Cousinou, M. -C.; Croc, A.; Cutts, D.; Das, A.; Davies, G.; De, K.; de Jong, S. J.; De La Cruz-Burelo, E.; Deliot, F.; Demina, R.; Denisov, D.; Denisov, S. P.; Desai, S.; Deterre, C.; DeVaughan, K.; Diehl, H. T.; Diesburg, M.; Ding, P. F.; Dominguez, A.; Dorland, T.; Dubey, A.; Dudko, L. V.; Duggan, D.; Duperrin, A.; Dutt, S.; Dyshkant, A.; Eads, M.; Edmunds, D.; Ellison, J.; Elvira, V. D.; Enari, Y.; Evans, H.; Evdokimov, A.; Evdokimov, V. N.; Facini, G.; Ferbel, T.; Fiedler, F.; Filthaut, F.; Fisher, W.; Fisk, H. E.; Fortner, M.; Fox, H.; Fuess, S.; Garcia-Bellido, A.; Garcia-Guerra, G. A.; Gavrilov, V.; Gay, P.; Geng, W.; Gerbaudo, D.; Gerber, C. E.; Gershtein, Y.; Ginther, G.; Golovanov, G.; Goussiou, A.; Grannis, P. D.; Greder, S.; Greenlee, H.; Greenwood, Z. D.; Gregores, E. M.; Grenier, G.; Gris, Ph.; Grivaz, J. -F.; Grohsjean, A.; Gruenendahl, S.; Gruenewald, M. W.; Guillemin, T.; Gutierrez, G.; Gutierrez, P.; Haas, A.; Hagopian, S.; Haley, J.; Han, L.; Harder, K.; Harel, A.; Hauptman, J. M.; Hays, J.; Head, T.; Hebbeker, T.; Hedin, D.; Hegab, H.; Heinson, A. P.; Heintz, U.; Hensel, C.; Heredia-De La Cruz, I.; Herner, K.; Hesketh, G.; Hildreth, M. D.; Hirosky, R.; Hoang, T.; Hobbs, J. D.; Hoeneisen, B.; Hohlfeld, M.; Hubacek, Z.; Hynek, V.; Iashvili, I.; Ilchenko, Y.; Illingworth, R.; Ito, A. S.; Jabeen, S.; Jaffre, M.; Jamin, D.; Jayasinghe, A.; Jesik, R.; Johns, K.; Johnson, M.; Jonckheere, A.; Jonsson, P.; Joshi, J.; Jung, A. W.; Juste, A.; Kaadze, K.; Kajfasz, E.; Karmanov, D.; Kasper, P. A.; Katsanos, I.; Kehoe, R.; Kermiche, S.; Khalatyan, N.; Khanov, A.; Kharchilava, A.; Kharzheev, Y. N.; Kohli, J. M.; Kozelov, A. V.; Kraus, J.; Kulikov, S.; Kumar, A.; Kupco, A.; Kurca, T.; Kuzmin, V. A.; Kvita, J.; Lammers, S.; Landsberg, G.; Lebrun, P.; Lee, H. S.; Lee, S. W.; Lee, W. M.; Lellouch, J.; Li, L.; Li, Q. Z.; Lietti, S. M.; Lim, J. K.; Lincoln, D.; Linnemann, J.; Lipaev, V. V.; Lipton, R.; Liu, Y.; Lobodenko, A.; Lokajicek, M.; de Sa, R. Lopes; Lubatti, H. J.; Luna-Garcia, R.; Lyon, A. L.; Maciel, A. K. A.; Mackin, D.; Madar, R.; Magana-Villalba, R.; Malik, S.; Malyshev, V. L.; Maravin, Y.; Martinez-Ortega, J.; McCarthy, R.; McGivern, C. L.; Meijer, M. M.; Melnitchouk, A.; Menezes, D.; Mercadante, P. G.; Merkin, M.; Meyer, A.; Meyer, J.; et al.

    2012-01-20

    We present a measurement of the relative branching fraction, R{sub f{sub 0}/{phi}}, of B{sub s}{sup 0} {yields} J/{psi}f{sub 0}(980), with f{sub 0}(980) {yields} {pi}{sup +}{pi}{sup -}, to the process B{sub s}{sup 0} {yields} J/{psi}{phi}, with {phi} {yields} K{sup +}K{sup -}. The J/{psi}f{sub 0}(980) final state corresponds to a CP-odd eigenstate of B{sub s}{sup 0} that could be of interest in future studies of CP violation. Using 8 fb{sup -1} of data recorded with the D0 detector at the Fermilab Tevatron Collider, we find R{sub f{sub 0}/{phi}} = 0.275 {+-} 0.041(stat) {+-} 0.061(syst).

  18. Molecular catalytic hydrogenation of aromatic hydrocarbons and

    Office of Scientific and Technical Information (OSTI)

    catalytic hydrogenation of aromatic hydrocarbons and hydrotreating of coal liquids. Yang, Shiyong; Stock, L.M. 01 COAL, LIGNITE, AND PEAT; 40 CHEMISTRY; COAL LIQUIDS;...

  19. Meson spectroscopy viewed from J//PSI/ decay: Gluonic states at BEPC

    SciTech Connect (OSTI)

    Chanowitz, M.S.

    1987-07-01

    The theoretical and experimental status of the search for gluonic states is reviewed. Progress clearly requires much higher statistics studies of J//psi/ decay, as will be possible at the Beijing Electron Positron Collider. 83 refs.

  20. Quantum transport through aromatic molecules

    SciTech Connect (OSTI)

    Ojeda, J. H.; Rey-Gonzlez, R. R.; Laroze, D.

    2013-12-07

    In this paper, we study the electronic transport properties through aromatic molecules connected to two semi-infinite leads. The molecules are in different geometrical configurations including arrays. Using a nearest neighbor tight-binding approach, the transport properties are analyzed into a Green's function technique within a real-space renormalization scheme. We calculate the transmission probability and the Current-Voltage characteristics as a function of a molecule-leads coupling parameter. Our results show different transport regimes for these systems, exhibiting metal-semiconductor-insulator transitions and the possibility to employ them in molecular devices.

  1. max walltime for "low" queue is increased to 24 hrs on Hopper

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    max walltime for low queue is increased to 24 hrs on Hopper max walltime for low queue is increased to 24 hrs on Hopper May 31, 2012 by Helen He (0 Comments) We have increased the...

  2. WPPI GreenMax-Scheller Residence: Near Zero Energy Monitoring Summary

    SciTech Connect (OSTI)

    2010-11-19

    This report describes results of GreenMax 2 monitoring project referred to as the GreenMax Net Zero Home, a demonstration home that can provide a wealth of information for the building community.

  3. Inclusive J/{psi} production in {Upsilon} decay via color-singlet mechanism

    SciTech Connect (OSTI)

    He Zhiguo; Wang Jianxiong

    2010-03-01

    In this work, we have calculated the tree level color-singlet contribution to the inclusive J/{psi} production in {Upsilon} decay of the {alpha}{sub s}{sup 5} order QCD process {Upsilon}{yields}J/{psi}+ccg and {alpha}{sup 2{alpha}}{sub s}{sup 2} order QED processes {Upsilon}{yields}{gamma}*{yields}J/{psi}+cc and {Upsilon}{yields}J/{psi}+gg. It is found that the contribution of the QED processes is comparable with that of the QCD process and the numerical results of the QCD process alone are about an order of magnitude smaller than the previous theoretical predictions. Our prediction in total is 4.2x10{sup -5} which is about an order of magnitude smaller than the recent CLEO measurement on the branching fraction B({Upsilon}{yields}J/{psi}+X). It indicates that the J/{psi} production mechanism in {Upsilon} decay is not well understood and further theoretical work and experimental analysis are still necessary.

  4. Dehydrocyclodimerization, converting LPG to aromatics

    SciTech Connect (OSTI)

    Johnson, J.A.; Hilder, G.K.

    1984-03-01

    British Petroleum (BP) recognized the potential need for ways of exploiting feedstocks with low opportunity cost and commenced a research program at its Sunbury Research Center to discover and develop a catalyst for the conversion of LPG to a liquid product. The successful outcome of this research program is the Cyclar /SUP SM/ process, a joint development of UOP Process Division and British Petroleum. The Cyclar process offers a single-step conversion of LPG to an aromatic product which has a highvalue, is easily transported and useful both to fuel and petrochemical applications. The LPG producer can invest in a single unit, avoiding the need to identify and develop markets for multiple C/sub 3/ and C/sub 4/ products. This catalytic process, which employs UOP Continuous Catalyst Regeneration (CCR) technology, can also be applied to refinery light ends to produce a high-quality gasoline. Aromatic and hydrogen yields from propane and butane feeds surpass those obtained from catalytic reforming of Light Arabian naphtha. This paper describes the principles of the Cyclar process and illustrates yields and economics for several interesting applications.

  5. Predicting Electrochemical Windows of Nitrogen Containing Aromatic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Molecules - Joint Center for Energy Storage Research October 20, 2014, Research Highlights Predicting Electrochemical Windows of Nitrogen Containing Aromatic Molecules Various nitrogen containing aromatic base molecules and a descriptive relationship derived to predict their reduction potentials is shown. Scientific Achievement A descriptive relationship is derived for computing reduction potentials of quinoxaline derivatives from the orbital energies of the neutral molecules without

  6. Observation of $B^0_s \\to J/\\psi K^{*0}(892)$ and $B^0_s \\to J/\\psi K^0_S$ Decays

    SciTech Connect (OSTI)

    Aaltonen, T.; /Helsinki Inst. of Phys.; Alvarez Gonzalez, B.; /Cantabria Inst. of Phys.; Amerio, S.; /INFN, Padua; Amidei, D.; /Michigan U.; Anastassov, A.; /Northwestern U.; Annovi, A.; /Frascati; Antos, J.; /Comenius U.; Apollinari, G.; /Fermilab; Appel, J.A.; /Fermilab; Apresyan, A.; /Purdue U.; Arisawa, T.; /Waseda U. /Dubna, JINR

    2011-02-01

    The authors report the first observation of two Cabibbo-suppressed decay modes of the B{sub s}{sup 0} meson. Using a sample of p{bar p} collisions at {radical}s = 1.96 TeV corresponding to 5.9 fb{sup -1} of integrated luminosity collected with the CDF II detector at the Fermilab Tevatron, they search for new B{sub s}{sup 0} decay modes in a sample of events containing J/{psi} {yields} {mu}{sup +}{mu}{sup -} decays. They reconstruct a B{sub s}{sup 0} {yields} J/{psi} K*(892){sup 0} signal with K*(892){sup 0} {yields} K{sup +}{pi}{sup -}, observing a yield of 151 {+-} 25 events with a statistical significance of 8.0{sigma}. They also reconstruct a B{sub s}{sup 0} {yields} J/{psi} K{sub S}{sup 0} signal with K{sub S}{sup 0} {yields} {pi}{sup +}{pi}{sup -}, observing a yield of 64 {+-} 14 events with a statistical significance of 7.2{sigma}. From these yields, they extract the branching ratios {Beta}(B{sub s}{sup 0} {yields} J/{psi} K*(892){sup 0}) = (8.3 {+-} 3.8) x 10{sup -5} and {Beta}(B{sub s}{sup 0} {yields} J/{psi} K{sup 0}) = (3.5 {+-} 0.8) x 10{sup -5}, where statistical, systematic, and fragmentation-fraction uncertainties are included in the combined uncertainty.

  7. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

    1993-01-05

    Aromatic compounds are alkylated in a combination reactor/distillation column comprising a vessel suitable for operating between 70 C and 500 C and from 0.5 to 20 atmospheres pressure; an inert distillation packing in the lower one-third of said vessel; solid acidic catalytic material such as zeolites or an acidic cation exchange resin supported in the middle one-third of said vessel; and inert distillation packing in the upper one-third of said vessel. A benzene inlet is located near the upper end of the vessel; an olefin inlet is juxtaposed with said solid acidic catalytic material; a bottoms outlet is positioned near the bottom of said vessel for removing said cumene and ethyl benzene; and an overhead outlet is placed at the top of said vessel for removing any unreacted benzene and olefin.

  8. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A.; Arganbright, Robert P.; Hearn, Dennis

    1993-01-01

    Aromatic compounds are alkylated in a combination reactor/distillation column comprising a vessel suitable for operating between 70.degree. C. and 500.degree. C. and from 0.5 to 20 atmospheres pressure; an inert distillation packing in the lower one-third of said vessel; solid acidic catalytic material such as zeolites or an acidic cation exchange resin supported in the middle one-third of said vessel; and inert distillation packing in the upper one-third of said vessel. A benzene inlet is located near the upper end of the vessel; an olefin inlet is juxtaposed with said solid acidic catalytic material; a bottoms outlet is positioned near the bottom of said vessel for removing said cumene and ethyl benzene; and an overhead outlet is placed at the top of said vessel for removing any unreacted benzene and olefin.

  9. Color-singlet J/{psi} production at O({alpha}{sub s}{sup 6}) in {Upsilon} decay

    SciTech Connect (OSTI)

    He Zhiguo; Wang Jianxiong

    2010-11-01

    To clarify the conflict between the theoretical predictions and experimental measurements of the inclusive J/{psi} production in {Upsilon} decay, we consider the {alpha}{sub s}{sup 6} order color-singlet (CS) contributions of processes {Upsilon}{yields}J/{psi}+gg and {Upsilon}{yields}J/{psi}+gggg. Both the branching ratio and the J/{psi} momentum spectrum are calculated, and the branching ratio (4.7x10{sup -4}) is larger than the leading-order contribution ({alpha}{sub s}{sup 5}, {Upsilon}{yields}J/{psi}+ccg). Together with the QCD and QED leading-order contributions considered in our previous work, the CS prediction of the branching ratio for the direct J/{psi} production is Br({Upsilon}{yields}J/{psi}{sub direct}+X)=0.90{sub -0.31}{sup +0.49}x10{sup -4}, which is still about 3.8 times less than the CLEO measurement. We also obtain a preliminary CS prediction of R{sub cc}=(B({Upsilon}{yields}J/{psi}+cc+X)/B({Upsilon}{yields}J/{psi}+X)) and find that the value 0.39{sub -0.20}{sup +0.21} is much larger than the color-octet prediction, and suggest to measure this quality in future experimental analysis.

  10. Polynuclear aromatic hydrocarbons for fullerene synthesis in flames

    DOE Patents [OSTI]

    Alford, J. Michael; Diener, Michael D.

    2006-12-19

    This invention provides improved methods for combustion synthesis of carbon nanomaterials, including fullerenes, employing multiple-ring aromatic hydrocarbon fuels selected for high carbon conversion to extractable fullerenes. The multiple-ring aromatic hydrocarbon fuels include those that contain polynuclear aromatic hydrocarbons. More specifically, multiple-ring aromatic hydrocarbon fuels contain a substantial amount of indene, methylnapthalenes or mixtures thereof. Coal tar and petroleum distillate fractions provide low cost hydrocarbon fuels containing polynuclear aromatic hydrocarbons, including without limitation, indene, methylnapthalenes or mixtures thereof.

  11. Aromatic and polycyclic aromatic hydrocarbon formation in a laminar premixed n-butane flame

    SciTech Connect (OSTI)

    Marinov, N.M.; Pitz, W.J.; Westbrook, C.K.; Vincitore, A.M.; Castaldi, M.J.; Senkan, S.M.; Melius, C.F.

    1998-07-01

    Experimental and detailed chemical kinetic modeling work has been performed to investigate aromatic and polycyclic aromatic hydrocarbon (PAH) formation pathways in a premixed, rich, sooting, n-butane-oxygen-argon burner stabilized flame. An atmospheric pressure, laminar flat flame operated at an equivalence ratio of 2.6 was used to acquire experimental data for model validation. Gas composition analysis was conducted by an on-line gas chromatograph/mass spectrometer technique. Measurements were made in the main reaction and post-reaction zones for a number of low molecular weight species, aliphatics, aromatics, and polycyclic aromatic hydrocarbons (PAHs) ranging from two to five-fused aromatic rings. Reaction flux and sensitivity analysis were used to help identify the important reaction sequences leading to aromatic and PAH growth and destruction in the n-butane flame. Reaction flux analysis showed the propargyl recombination reaction was the dominant pathway to benzene formation. The consumption of propargyl by H atoms was shown to limit propargyl, benzene, and naphthalene formation in flames as exhibited by the large negative sensitivity coefficients. Naphthalene and phenanthrene production was shown to be plausibly formed through reactions involving resonantly stabilized cyclopentadienyl and indenyl radicals. Many of the low molecular weight aliphatics, combustion by-products, aromatics, branched aromatics, and PAHs were fairly well simulated by the model. Additional work is required to understand the formation mechanisms of phenyl acetylene, pyrene, and fluoranthene in the n-butane flame. 73 refs.

  12. Experimental and modeling investigation of aromatic and polycyclic aromatic hydrocarbon formation in a premixed ethylene flame

    SciTech Connect (OSTI)

    Castaldi, M.J.; Marinov, N.M.; Melius, C.F.

    1996-02-01

    Experimental and detailed chemical kinetic modeling has been performed to investigate aromatic and polyaromatic hydrocarbon formation pathways in a rich, sooting, ethylene-oxygen-argon premixed flame. An atmospheric pressure, laminar flat flame operated at an equivalence ratio of 2.5 was used to acquire experimental data for model validation. Gas composition analysis was conducted by an on-line gas chromatograph/mass spectrometer (GC/MS) technique. Measurements were made in the flame and post-flame zone for a number of low molecular weight species, aliphatics, aromatics and polycyclic aromatic hydrocarbons (PAHs) ranging from two to five-aromatic fused rings. The modeling results show the key reaction sequences leading to aromatic and polycyclic aromatic hydrocarbon growth involve the combination of resonantly stabilized radicals. In particular, propargyl and 1-methylallenyl combination reactions lead to benzene and methyl substituted benzene formation, while polycyclic aromatics are formed from cyclopentadienyl radicals and fused rings that have a shared C{sub 5} side structure. Naphthalene production through the reaction step of cyclopentadienyl self-combination and phenanthrene formation from indenyl and cyclopentadienyl combination were shown to be important in the flame modeling study. The removal of phenyl by O{sub 2} leading to cyclopentadienyl formation is expected to play a pivotal role in the PAH or soot precursor growth process under fuel-rich oxidation conditions.

  13. QCD Corrections to e{sup +}e{sup -}{yields}J/{psi}+gg at B Factories

    SciTech Connect (OSTI)

    Ma Yanqing; Zhang Yujie; Chao Kuangta

    2009-04-24

    In heavy quarkonium production, the measured ratio R{sub cc}={sigma}[J/{psi}+cc+X]/{sigma}[J/{psi}+X] at B factories is much larger than existing theoretical predictions. To clarify this discrepancy, in nonrelativistic QCD we find the next-to-leading-order (NLO) QCD correction to e{sup +}e{sup -}{yields}J/{psi}+gg can enhance the cross section by about 20%. Together with the calculated NLO result for e{sup +}e{sup -}{yields}J/{psi}+cc, we show that the NLO corrections can significantly improve the fit to the ratio R{sub cc}. The effects of leading logarithm resummation near the end point on the J/{psi} momentum distribution and total cross section are also considered. Comparison of the calculated cross section for e{sup +}e{sup -}{yields}J/{psi}+gg with the observed cross section for e{sup +}e{sup -}{yields}J/{psi}+non-(cc) is expected to provide unique information on the issue of color-octet contributions.

  14. Prompt and non-prompt J/psi production in pp collisions at sqrt(s) = 7 TeV

    SciTech Connect (OSTI)

    Khachatryan, Vardan; et al.

    2011-03-01

    The production of J/psi mesons is studied in pp collisions at sqrt(s)=7 TeV with the CMS experiment at the LHC. The measurement is based on a dimuon sample corresponding to an integrated luminosity of 314 inverse nanobarns. The J/psi differential cross section is determined, as a function of the J/psi transverse momentum, in three rapidity ranges. A fit to the decay length distribution is used to separate the prompt from the non-prompt (b hadron to J/psi) component. Integrated over J/psi transverse momentum from 6.5 to 30 GeV/c and over rapidity in the range |y| < 2.4, the measured cross sections, times the dimuon decay branching fraction, are 70.9 \\pm 2.1 (stat.) \\pm 3.0 (syst.) \\pm 7.8(luminosity) nb for prompt J/psi mesons assuming unpolarized production and 26.0 \\pm 1.4 (stat.) \\pm 1.6 (syst.) \\pm 2.9 (luminosity) nb for J/psi mesons from b-hadron decays.

  15. J/{psi} production and elliptic flow in relativistic heavy-ion collisions

    SciTech Connect (OSTI)

    Song Taesoo; Xu Jun; Ko, Che Ming; Lee, Su Houng

    2011-01-15

    Using the two-component model for charmonium production, which includes contributions from both initial hard nucleon-nucleon scattering and from regeneration in the quark-gluon plasma, we study the nuclear modification factor R{sub AA} and elliptic flow v{sub 2} of J/{psi} in relativistic heavy-ion collisions. For the expansion dynamics of produced hot, dense matter, we introduce a schematic fireball model with its transverse acceleration determined from the pressure gradient inside the fireball and azimuthally anisotropic expansion parametrized to reproduce measured v{sub 2} of light hadrons. We assume that light hadrons freeze out at the temperature of 120 MeV while charmonia freeze out at 160 MeV, similar to the kinetic and chemical freeze-out temperatures in the statistical model, respectively. For the properties of charmonia in the quark-gluon plasma, we use the screening mass between their charm and anticharm quarks and their dissociation cross sections given by the perturbative quantum chromodynamical (pQCD) calculations in the leading order and up to the next-to-leading order, respectively. For the relaxation time of charm and anticharm quarks in the quark-gluon plasma, we also use the one calculated in the leading-order pQCD. Modeling the effect of higher-order corrections in pQCD by introducing multiplicative factors to the dissociation cross sections of charmonia and the elastic scattering cross sections of charm and anticharm quarks, we find that this effect is small for the R{sub AA} of J/{psi} as they suppress the number of initially produced J/{psi} but enhance the number of regenerated ones. The higher-order corrections increase, however, the v{sub 2} of J/{psi}. Our results suggest that the v{sub 2} of J/{psi} can play an important role in discriminating between J/{psi} production from initial hard collisions and from regeneration in the quark-gluon plasma.

  16. Fluorescence method for enzyme analysis which couples aromatic amines with aromatic aldehydes

    DOE Patents [OSTI]

    Smith, R.E.; Dolbeare, F.A.

    1980-10-21

    Analysis of proteinases is accomplished using conventional amino acid containing aromatic amine substrates. Aromatic amines such as 4-methoxy-2-naphthylamine (4M2NA), 2-naphthylamine, aminoisophthalic acid dimethyl ester, p-nitroaniline, 4-methoxy-1-aminofluorene and coumarin derivatives resulting from enzymatic hydrolysis of the substrate couples with aromatic aldehydes such as 5-nitrosalicylaldehyde (5-NSA), benzaldehyde and p-nitrobenzaldehyde to produce Schiff-base complexes which are water insoluble. Certain Schiff-base complexes produce a shift from blue to orange-red (visible) fluorescence. Such complexes are useful in the assay of enzymes. No Drawings

  17. Fluorescence method for enzyme analysis which couples aromatic amines with aromatic aldehydes

    DOE Patents [OSTI]

    Smith, Robert E. [557 Escondido Cir., Livermore, CA 94550; Dolbeare, Frank A. [5178 Diane La., Livermore, CA 94550

    1980-10-21

    Analysis of proteinases is accomplished using conventional amino acid containing aromatic amine substrates. Aromatic amines such as 4-methoxy-2-naphthylamine (4M2NA), 2-naphthylamine, aminoisophthalic acid dimethyl ester, p-nitroaniline, 4-methoxy-1-aminofluorene and coumarin derivatives resulting from enzymatic hydrolysis of the substrate couples with aromatic aldehydes such as 5-nitrosalicylaldehyde (5-NSA), benzaldehyde and p-nitrobenzaldehyde to produce Schiff-base complexes which are water insoluble. Certain Schiff-base complexes produce a shift from blue to orange-red (visible) fluorescence. Such complexes are useful in the assay of enzymes.

  18. Fluorescence method for enzyme analysis which couples aromatic amines with aromatic aldehydes

    DOE Patents [OSTI]

    Smith, Robert E.; Dolbeare, Frank A.

    1979-01-01

    Analysis of proteinases is accomplished using conventional amino acid containing aromatic amine substrates. Aromatic amines such as 4-methoxy-2-naphthylamine (4M2NA), 2-naphthylamine, aminoisophthalic acid dimethyl ester, p-nitroaniline, 5-methoxy-1-aminofluorene and coumarin derivatives resulting from enzymatic hydrolysis of the substrate couples with aromatic aldehydes such as 5-nitrosalicylaldehyde (5-NSA), benzaldehyde and p-nitrobenzaldehyde to produce Schiff-base complexes which are water insoluble. Certain Schiff-base complexes produce a shift from blue to orange-red (visible) fluorescence. Such complexes are useful in the assay of enzymes.

  19. Samuel C.C. Ting, the J/psi Particle (Charm), and the Alpha Magnetic

    Office of Scientific and Technical Information (OSTI)

    Spectrometer (AMS) Samuel C.C. Ting, the J/psi Particle (Charm), and the Alpha Magnetic Spectrometer (AMS) Resources with Additional Information Samuel C.C. Ting Credit: Courtesy of the Massachusetts Institute of Technology 'Samuel C.C. Ting was born ... in Ann Arbor, Michigan, ... [and] received his elementary and secondary education in China ... . He excelled in mathematics, science and history. In 1956, Ting returned to the United States to attend the University of Michigan as an

  20. Measurement of prompt psi(2S) to J/psi yield ratios in PbPb and pp collisions at sqrt(s[NN]) = 2.76 TeV

    SciTech Connect (OSTI)

    Khachatryan, V. et al.

    2014-12-01

    The ratio between the prompt psi(2S) and J/psi yields, reconstructed via their decays into muon pairs, is measured in PbPb and pp collisions at sqrt(s[NN]) = 2.76 TeV. The analysis is based on PbPb and pp data samples collected by CMS at the LHC, corresponding to integrated luminosities of 150 inverse microbarns and 5.4 inverse picobarns, respectively. The double ratio of measured yields, (N[psi(2S)]/N[J/psi])[PbPb] / (N[psi(2S)]/ N[J/psi])[pp], is computed in three PbPb collision centrality bins and two kinematic ranges: one at midrapidity, abs(y) < 1.6, covering the transverse momentum range 6.5 < pt < 30 GeV/c, and the other at forward rapidity, 1.6 < abs(y) < 2.4, extending to lower pt values, 3 < pt < 30 GeV/c. The centrality-integrated double ratio changes from 0.45 +/- 0.13 (stat) +/- 0.07 (syst) in the first range to 1.67 +/- 0.34 (stat) +/- 0.27 (syst) in the second. This difference is most pronounced in the most central collisions.

  1. max walltime for low queue is increased to 24 hrs on Hopper

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    max walltime for low queue is increased to 24 hrs on Hopper max walltime for low queue is increased to 24 hrs on Hopper May 31, 2012 by Helen He We have increased the max walltime for the low queue on Hopper from 12 to 24 hrs. Subscribe via RSS Subscribe Browse by Date February 2013 September 2012 August 2012 May 2012 April 2012 March 2012 February 2012 January 2012 November 2011 October 2011 September 2011 August 2011 July 2011 June 2011 May 2011 April 2011 March 2011 February 2011 January 2011

  2. runtime error message: "apsched: request exceeds max nodes, alloc"

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    apsched: request exceeds max nodes, alloc" runtime error message: "apsched: request exceeds max nodes, alloc" September 12, 2014 Symptom: User jobs with single or multiple apruns in a batch script may get this runtime error. "apsched: request exceeds max nodes, alloc". This problem is intermittent, started in April, then mid July, and again since late August. Status: This problem is identified as a problem when Torque/Moab batch scheduler becomes out of sync with the

  3. text in "Max kWh" fields | OpenEI Community

    Open Energy Info (EERE)

    it should as we are trying to prevent users from writing "less than X", "greater than Y", etc. and follow the intention of the "Max kWh" field. Also there should be a warning...

  4. Property:OpenEI/UtilityRate/DemandRateStructure/Tier5Max | Open...

    Open Energy Info (EERE)

    navigation, search This is a property of type Number. Retrieved from "http:en.openei.orgwindex.php?titleProperty:OpenEIUtilityRateDemandRateStructureTier5Max&oldid539754...

  5. Property:OpenEI/UtilityRate/EnergyRateStructure/Tier1Max | Open...

    Open Energy Info (EERE)

    navigation, search This is a property of type Number. Retrieved from "http:en.openei.orgwindex.php?titleProperty:OpenEIUtilityRateEnergyRateStructureTier1Max&oldid539766...

  6. Property:OpenEI/UtilityRate/DemandRateStructure/Tier4Max | Open...

    Open Energy Info (EERE)

    navigation, search This is a property of type Number. Retrieved from "http:en.openei.orgwindex.php?titleProperty:OpenEIUtilityRateDemandRateStructureTier4Max&oldid539751...

  7. Monitoring of vapor phase polycyclic aromatic hydrocarbons

    DOE Patents [OSTI]

    Vo-Dinh, Tuan; Hajaligol, Mohammad R.

    2004-06-01

    An apparatus for monitoring vapor phase polycyclic aromatic hydrocarbons in a high-temperature environment has an excitation source producing electromagnetic radiation, an optical path having an optical probe optically communicating the electromagnetic radiation received at a proximal end to a distal end, a spectrometer or polychromator, a detector, and a positioner coupled to the first optical path. The positioner can slidably move the distal end of the optical probe to maintain the distal end position with respect to an area of a material undergoing combustion. The emitted wavelength can be directed to a detector in a single optical probe 180.degree. backscattered configuration, in a dual optical probe 180.degree. backscattered configuration or in a dual optical probe 90.degree. side scattered configuration. The apparatus can be used to monitor an emitted wavelength of energy from a polycyclic aromatic hydrocarbon as it fluoresces in a high temperature environment.

  8. Max Tech Electric Heat Pump Water Heater with Lower GWP Halogenated

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Refrigerant | Department of Energy Max Tech Electric Heat Pump Water Heater with Lower GWP Halogenated Refrigerant Max Tech Electric Heat Pump Water Heater with Lower GWP Halogenated Refrigerant Information flow schematic for an integrated heat pump design model and wrapped tank model. Image credit: Oak Ridge National Laboratory. Information flow schematic for an integrated heat pump design model and wrapped tank model. Image credit: Oak Ridge National Laboratory. Information flow schematic

  9. Princeton, Max Planck Society launch new research center for plasma physics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | Princeton Plasma Physics Lab Princeton, Max Planck Society launch new research center for plasma physics By John Greenwald March 30, 2012 Tweet Widget Google Plus One Share on Facebook (From left to right) Princeton University Professor of Astrophysical Sciences James Stone, Princeton University President Shirley M. Tilghman, Princeton University Dean for Research A. J. Stewart Smith, Max Planck Society President Peter Gruss, and Consul General of the Federal Republic of Germany in New

  10. THE MASS-RICHNESS RELATION OF MaxBCG CLUSTERS FROM QUASAR LENSING

    Office of Scientific and Technical Information (OSTI)

    MAGNIFICATION USING VARIABILITY (Journal Article) | SciTech Connect THE MASS-RICHNESS RELATION OF MaxBCG CLUSTERS FROM QUASAR LENSING MAGNIFICATION USING VARIABILITY Citation Details In-Document Search Title: THE MASS-RICHNESS RELATION OF MaxBCG CLUSTERS FROM QUASAR LENSING MAGNIFICATION USING VARIABILITY Accurate measurement of galaxy cluster masses is an essential component not only in studies of cluster physics but also for probes of cosmology. However, different mass measurement

  11. Synthetic fuel aromaticity and staged combustion

    SciTech Connect (OSTI)

    Longanbach, J. R.; Chan, L. K.; Levy, A.

    1982-11-15

    Samples of middle and heavy SRC-II distillates were distilled into 50 C boiling point range fractions. These were characterized by measurements of their molecular weight, elemental analysis and basic nitrogen content and calculation of average molecular structures. The structures typically consisted of 1 to 3 aromatic rings fused to alicyclic rings with short, 1 to 3 carbon aliphatic side chains. The lower boiling fractions contained significant amounts (1 atom/molecule) of oxygen while the heavier fractions contained so few heteroatoms that they were essentially hydrocarbons. Laboratory scale oxidative-pyrolysis experiments were carried out at pyrolysis temperatures of 500 to 1100 C and oxygen concentrations from 0 to 100 percent of stoichiometry. Analysis of liquid products, collected in condensers cooled with liquid nitrogen showed that aromatization is a major reaction in the absence of oxygen. The oxygen-containing materials (phenolics) seem to be more resistant to thermal pyrolysis than unsubstituted aromatics. Nitrogen converts from basic to nonbasic forms at about 500 C. The nonbasic nitrogen is more stable and survives up to 700 C after which it is slowly removed. A recently constructed 50,000 Btu/hr staged combustor was used to study the chemistry of the nitrogen and aromatics. SRC II combustion was studied under fuel-rich, first-stage conditions at air/fuel ratios from 0.6 to 1.0 times stoichiometric. The chemistry of the fuel during combustion calls for further investigation in order to examine the mechanism by which HCN is evolved as a common intermediate for the formation of the nitrogen-containing gaseous combustion products. 25 references, 45 figures, 25 tables.

  12. Characterization and analysis of polycyclic aromatic hydrocarbons

    SciTech Connect (OSTI)

    Breuer, G.M.; Smith, J.P.

    1984-01-01

    Sampling and analytical procedures were developed for determining the concentrations of polycyclic aromatic hydrocarbons in animal-exposure chambers during studies on exposure to diesel exhaust, coal dust, or mixtures of these two pollutants. Fluoranthene, pyrene, benzo(a)anthracene, chrysene, benzo(e)pyrene, benzo(k)fluoranthene, and benzo(a)pyrene were used as representative polycyclic aromatic hydrocarbons. High-pressure liquid chromatography with fluorescence detection was used for analysis. Coal-dust only samples revealed a broad, rising background in the chromatogram with small peaks superimposed corresponding to fluoranthene, pyrene, and benzo(a)anthracene, diesel exhaust only samples showed many peaks on a flat baseline including those corresponding to fluoranthene, pyrene, benzo(a)anthracene, benzo(k)fluoranthene, and benzo(a)pyrene. In general, no polynuclear aromatics were noted in the clean air samples. The authors note that relatively minor changes in air/fuel ratio, lubricant, fuel, and load may have substantial effects on very minor components of the exhaust emission.

  13. Final Technical Report -- Bridging the PSI Knowledge Gap: A Multiscale Approach

    SciTech Connect (OSTI)

    Whyte, Dennis

    2014-12-12

    The Plasma Surface Interactions (PSI) Science Center formed by the grant undertook a multidisciplinary set of studies on the complex interface between the plasma and solid states of matter. The strategy of the center was to combine and integrate the experimental, diagnostic and modeling toolkits from multiple institutions towards specific PSI problems. In this way the Center could tackle integrated science issues which were not addressable by single institutions, as well as evolve the underlying science of the PSI in a more general way than just for fusion applications. The overall strategy proved very successful. The research result and highlights of the MIT portion of the Center are primarily described. A particular highlight is the study of tungsten nano-tendril growth in the presence of helium plasmas. The Center research provided valuable new insights to the mechanisms controlling the nano-tendrils by developing coupled modeling and in situ diagnostic methods which could be directly compared. For example, the role of helium accumulation in tungsten distortion in the surface was followed with unique in situ helium concentration diagnostics developed. These depth-profiled, time-resolved helium concentration measurements continue to challenge the numerical models of nano-tendrils. The Center team also combined its expertise on tungsten nano-tendrils to demonstrate for the first time the growth of the tendrils in a fusion environment on the Alcator C-Mod fusion experiment, thus having significant impact on the broader fusion research effort. A new form of isolated nano-tendril “columns” were identified which are now being used to understand the underlying mechanisms controlling the tendril growth. The Center also advanced PSI science on a broader front with a particular emphasis on developing a wide range of in situ PSI diagnostic tools at the DIONISOS facility at MIT. For example the strong suppression of sputtering by the certain combination of light-species plasmas and metals was experimentally studied with independent measurement methods across the Center. This surprising result challenges the universal use of the binary-collision approximation in sputtering predictions and continues to be the subject of study. In order to address this issue MIT developed a new in situ erosion measurement technique based on ion beam analysis which can be used at elevated material temperatures. This exciting new technique is now being used to study material erosion in high performance plasma thrusters for space exploration and is being adopted to fusion experimental devices. This is an indicator of the positive synergies that arise from such a Center, with the research having impact beyond the initial area of study. The Center also served successfully as an organizing force for communication to the science community. The MIT members of the Center provided many high-profile overview presentations at prestigious international conferences and national workshops. The research resulted in three student theses and 24 peer-reviewed publications. PSI research continues to be identified as a critical area for fusion energy.

  14. Di-J/psi Studies, Level 3 Tracking and the D0 Run IIb Upgrade

    SciTech Connect (OSTI)

    Vint, Philip John; /Imperial Coll., London

    2009-10-01

    The D0 detector underwent an upgrade to its silicon vertex detector and triggering systems during the transition from Run IIa to Run IIb to maximize its ability to fully exploit Run II at the Fermilab Tevatron. This thesis describes improvements made to the tracking and vertexing algorithms used by the high level trigger in both Run IIa and Run IIb, as well as a search for resonant di-J/{psi} states using both Run IIa and Run IIb data. Improvements made to the tracking and vertexing algorithms during Run IIa included the optimization of the existing tracking software to reduce overall processing time and the certification and testing of a new software release. Upgrades made to the high level trigger for Run IIb included the development of a new tracking algorithm and the inclusion of the new Layer 0 silicon detector into the existing software. The integration of Layer 0 into the high level trigger has led to an improvement in the overall impact parameter resolution for tracks of {approx}50%. The development of a new parameterization method for finding the error associated to the impact parameter of tracks returned by the high level tracking algorithm, in association with the inclusion of Layer 0, has led to improvements in vertex resolution of {approx}4.5 {micro}m. A previous search in the di-J/{psi} channel revealed a unpredicted resonance at {approx}13.7 GeV/c{sup 2}. A confirmation analysis is presented using 2.8 fb{sup -1} of data and two different approaches to cuts. No significant excess is seen in the di-J/{psi} mass spectrum.

  15. Measurement of the CP-violating phase phi sJ/psi phi using the flavor-tagged decay Bs(0) -> J/psi phi in 8 fb(-1) of p(p)over-bar collisions

    SciTech Connect (OSTI)

    Abazov, V.M.; Abazov, V. M.; Abbott, B.; Acharya, B. S.; Adams, M.; Adams, T.; Alexeev, G. D.; Alkhazov, G.; Alton, A.; Alverson, G.; Alves, G. A.; Aoki, M.; Arov, M.; Askew, A.; Asman, B.; Atkins, S.; Atramentov, O.; Augsten, K.; Avila, C.; BackusMayes, J.; Badaud, F.; Bagby, L.; Baldin, B.; Bandurin, D. V.; Banerjee, S.; Barberis, E.; Baringer, P.; Barreto, J.; Bartlett, J. F.; Bassler, U.; Bazterra, V.; Bean, A.; Begalli, M.; Begel, M.; Belanger-Champagne, C.; Bellantoni, L.; Beri, S. B.; Bernardi, G.; Bernhard, R.; Bertram, I.; Besancon, M.; Beuselinck, R.; Bezzubov, V. A.; Bhat, P. C.; Bhatnagar, V.; Blazey, G.; Blessing, S.; Bloom, K.; Boehnlein, A.; Boline, D.; Boos, E. E.; Borissov, G.; Bose, T.; Brandt, A.; Brandt, O.; Brock, R.; Brooijmans, G.; Bross, A.; Brown, D.; Brown, J.; Bu, X. B.; Buehler, M.; Buescher, V.; Bunichev, V.; Burdin, S.; Burnett, T. H.; Buszello, C. P.; Calpas, B.; Camacho-Perez, E.; Carrasco-Lizarraga, M. A.; Casey, B. C. K.; Castilla-Valdez, H.; Chakrabarti, S.; Chakraborty, D.; Chan, K. M.; Chandra, A.; Chapon, E.; Chen, G.; Chevalier-Thery, S.; Cho, D. K.; Cho, S. W.; Choi, S.; Choudhary, B.; Cihangir, S.; Claes, D.; Clutter, J.; Cooke, M.; Cooper, W. E.; Corcoran, M.; Couderc, F.; Cousinou, M. -C.; Croc, A.; Cutts, D.; Das, A.; Davies, G.; De, K.; de Jong, S. J.; De La Cruz-Burelo, E.; Deliot, F.; Demarteau, M.; Demina, R.; Denisov, D.; Denisov, S. P.; Desai, S.; Deterre, C.; DeVaughan, K.; Diehl, H. T.; Diesburg, M.; Ding, P. F.; Dominguez, A.; Dorland, T.; Dubey, A.; Dudko, L. V.; Duggan, D.; Duperrin, A.; Dutt, S.; Dyshkant, A.; Eads, M.; Edmunds, D.; Ellison, J.; Elvira, V. D.; Enari, Y.; Evans, H.; Evdokimov, A.; Evdokimov, V. N.; Facini, G.; Ferbel, T.; Fiedler, F.; Filthaut, F.; Fisher, W.; Fisk, H. E.; Fortner, M.; Fox, H.; Fuess, S.; Garcia-Bellido, A.; Garcia-Guerra, G. A.; Gavrilov, V.; Gay, P.; Geng, W.; Gerbaudo, D.; Gerber, C. E.; Gershtein, Y.; Ginther, G.; Golovanov, G.; Goussiou, A.; Grannis, P. D.; Greder, S.; Greenlee, H.; Greenwood, Z. D.; Gregores, E. M.; Grenier, G.; Gris, Ph.; Grivaz, J. -F.; Grohsjean, A.; Gruenendahl, S.; Gruenewald, M. W.; Guillemin, T.; Gutierrez, G.; Gutierrez, P.; Haas, A.; Hagopian, S.; Haley, J.; Han, L.; Harder, K.; Harel, A.; Hauptman, J. M.; Hays, J.; Head, T.; Hebbeker, T.; Hedin, D.; Hegab, H.; Heinson, A. P.; Heintz, U.; Hensel, C.; Heredia-De La Cruz, I.; Herner, K.; Hesketh, G.; Hildreth, M. D.; Hirosky, R.; Hoang, T.; Hobbs, J. D.; Hoeneisen, B.; Hohlfeld, M.; Hubacek, Z.; Huske, N.; Hynek, V.; Iashvili, I.; Ilchenko, Y.; Illingworth, R.; Ito, A. S.; Jabeen, S.; Jaffre, M.; Jamin, D.; Jayasinghe, A.; Jesik, R.; Johns, K.; Johnson, M.; Jonckheere, A.; Jonsson, P.; Joshi, J.; Jung, A. W.; Juste, A.; Kaadze, K.; Kajfasz, E.; Karmanov, D.; Kasper, P. A.; Katsanos, I.; Kehoe, R.; Kermiche, S.; Khalatyan, N.; Khanov, A.; Kharchilava, A.; Kharzheev, Y. N.; Kohli, J. M.; Kozelov, A. V.; Kraus, J.; Kulikov, S.; Kumar, A.; Kupco, A.; Kurca, T.; Kuzmin, V. A.; Kvita, J.; Lammers, S.; Landsberg, G.; Lebrun, P.; Lee, H. S.; Lee, S. W.; Lee, W. M.; Lellouch, J.; Li, L.; Li, Q. Z.; Lietti, S. M.; Lim, J. K.; Lincoln, D.; Linnemann, J.; Lipaev, V. V.; Lipton, R.; Liu, Y.; Lobodenko, A.; Lokajicek, M.; de Sa, R. Lopes; Lubatti, H. J.; Luna-Garcia, R.; Lyon, A. L.; Maciel, A. K. A.; Mackin, D.; Madar, R.; Magana-Villalba, R.; Malik, S.; Malyshev, V. L.; Maravin, Y.; Martinez-Ortega, J.; McCarthy, R.; McGivern, C. L.; Meijer, M. M.; Melnitchouk, A.; Menezes, D.; Mercadante, P. G.; Merkin, M.; Meyer, A.; Meyer, J.; et al.

    2012-02-22

    We report an updated measurement of the CP-violating phase, {phi}{sub s}{sup J/{psi}{phi}} and the decay-width difference for the two mass eigenstates, {Delta}{Gamma}{sub s}, from the flavor-tagged decay B{sub s}{sup 0} {yields} J/{psi}{phi}. The data sample corresponds to an integrated luminosity of 8.0 fb{sup -1} accumulated with the D0 detector using p{bar p} collisions at {radical}s = 1.96 TeV produced at the Fermilab Tevatron collider. The 68% Bayesian credibility intervals, including systematic uncertainties, are {Delta}{Gamma}{sub s} = 0.163{sub -0.064}{sup +0.065} ps{sup -1} and {phi}{sub s}{sup J}/{psi}{phi} = -0.55{sub -0.36}{sup +0.38}. The p-value for the Standard Model point is 29.8%.

  16. Device for aqueous detection of nitro-aromatic compounds

    DOE Patents [OSTI]

    Reagen, W.K.; Schulz, A.L.; Ingram, J.C.; Lancaster, G.D.; Grey, A.E.

    1994-04-26

    This invention relates to a compact and portable detection apparatus for nitro-aromatic based chemical compounds, such as nitrotoluenes, dinitrotoluenes, and trinitrotoluene (TNT). The apparatus is based upon the use of fiber optics using filtered light. The preferred process of the invention relies upon a reflective chemical sensor and optical and electronic components to monitor a decrease in fluorescence when the nitro-aromatic molecules in aqueous solution combine and react with a fluorescent polycyclic aromatic compound. 4 figures.

  17. Device for aqueous detection of nitro-aromatic compounds

    DOE Patents [OSTI]

    Reagen, William K. (Stillwater, MN); Schulz, Amber L. (Bremerton, WA); Ingram, Jani C. (Idaho Falls, ID); Lancaster, Gregory D. (Idaho Falls, ID); Grey, Alan E. (Idaho Falls, ID)

    1994-01-01

    This invention relates to a compact and portable detection apparatus for ro-aromatic based chemical compounds, such as nitrotoluenes, dinitrotoluenes, and trinitrotoluene (TNT). The apparatus is based upon the use of fiber optics using filtered light. The preferred process of the invention relies upon a reflective chemical sensor and optical and electronic components to monitor a decrease in fluorescence when the nitro-aromatic molecules in aqueous solution combine and react with a fluorescent polycyclic aromatic compound.

  18. Aromatics oxidation and soot formation in flames

    SciTech Connect (OSTI)

    Howard, J.B.; Pope, C.J.; Shandross, R.A.; Yadav, T.

    1993-12-01

    This project is concerned with the kinetics and mechanisms of aromatics oxidation and soot and fullerenes formation in flames. The scope includes detailed measurements of profiles of stable and radical species concentrations in low-pressure one-dimensional premixed flames. Intermediate species identifications and mole fractions, fluxes, and net reaction rates calculated from the measured profiles are used to test postulated reaction mechanisms. Particular objectives are to identify and to determine or confirm rate constants for the main benzene oxidation reactions in flames, and to characterize fullerenes and their formation mechanisms and kinetics.

  19. Color-singlet relativistic correction to inclusive J/{psi} production associated with light hadrons at B factories

    SciTech Connect (OSTI)

    Jia, Yu

    2010-08-01

    We study the first-order relativistic correction to the associated production of J/{psi} with light hadrons at B factory experiments at {radical}(s)=10.58 GeV, in the context of nonrelativistic QCD (NRQCD) factorization. We employ a strategy for NRQCD expansion that slightly deviates from the orthodox doctrine, in that the matching coefficients are not truly of a ''short-distance'' nature, but explicitly depend upon physical kinematic variables rather than partonic ones. Our matching method, with validity guaranteed by the Gremm-Kapustin relation, is particularly suited for the inclusive quarkonium production and decay processes with involved kinematics, exemplified by the process e{sup +}e{sup -}{yields}J/{psi}+gg considered in this work. Despite some intrinsic ambiguity affiliated with the order-v{sup 2} NRQCD matrix element, if we choose its value as what has been extracted from a recent Cornell-potential-model-based analysis, including the relative order-v{sup 2} effect is found to increase the lowest-order prediction for the integrated J/{psi} cross section by about 30%, and exert a modest impact on J/{psi} energy, angular and polarization distributions except near the very upper end of the J/{psi} energy. The order-v{sup 2} contribution to the energy spectrum becomes logarithmically divergent at the maximum of J/{psi} energy. A consistent analysis may require that these large end-point logarithms be resummed to all orders in {alpha}{sub s}.

  20. Band gap estimation from temperature dependent Seebeck measurementDeviations from the 2e|S|{sub max}T{sub max} relation

    SciTech Connect (OSTI)

    Gibbs, Zachary M.; Kim, Hyun-Sik; Wang, Heng; Snyder, G. Jeffrey

    2015-01-12

    In characterizing thermoelectric materials, electrical and thermal transport measurements are often used to estimate electronic band structure properties such as the effective mass and band gap. The Goldsmid-Sharp band gap, E{sub g}?=?2e|S|{sub max}T{sub max}, is a tool widely employed to estimate the band gap from temperature dependent Seebeck coefficient measurements. However, significant deviations of more than a factor of two are now known to occur. We find that this is when either the majority-to-minority weighted mobility ratio (A) becomes very different from 1.0 or as the band gap (E{sub g}) becomes significantly smaller than 10 k{sub B}T. For narrow gaps (E{sub g}???6 k{sub B}T), the Maxwell-Boltzmann statistics applied by Goldsmid-Sharp break down and Fermi-Dirac statistics are required. We generate a chart that can be used to quickly estimate the expected correction to the Goldsmid-Sharp band gap depending on A and S{sub max}; however, additional errors can occur for S?

  1. {CP} Violation in Flavor Tagged $B_s \\to J/\\psi \\phi$ Decays

    SciTech Connect (OSTI)

    Makhoul, Khaldoun; /MIT

    2009-06-01

    In this dissertation, we present the results of a time-dependent angular analysis of B{sub s} {yields} J/{psi}{phi} decays performed with the use of initial-state flavor tagging. CP violation is observed in this mode through the interference of decay without net mixing and decay with net mixing, that is, B{sub s} {yields} J/{psi}{phi} and B{sub s} {yields} {bar B}{sub s} {yields} J/{psi}{phi}. The time-dependent angular analysis is used to extract the decay widths of the heavy and light B{sub s} eigenstates and the difference between these decay widths {Delta}{Lambda}{sub s} {triple_bond} {Lambda}{sub s}{sup L}-{Lambda}{sub s}{sup H}. Initial-state flavor tagging is used to determine the matter-antimatter content of the B{sub s} mesons at production time. We combine flavor tagging with the angular analysis, which statistically determines the contributions of the CP-even and CP-odd components at decay time, to measure the CP-violating phase {beta}{sub s}. The phase {beta}{sub s} is expressed in terms of elements of the Cabibbo-Kobayashi-Maskawa matrix as {beta}{sub s} {triple_bond} arg (-V{sub ts}V*{sub tb}/V{sub cs}V*{sub cb}), and is predicted by the Standard Model to be close to zero, {beta}{sub s}{sup SM} = 0.02. In the measurement of {Delta}{Lambda}{sub s}, we use a dataset corresponding to 1.7 fb{sup -1} of luminosity, collected at the CDF experiment from proton-antiproton collisions at a center of mass energy {radical}s = 1.96 TeV. In the measurement of {beta}{sub s}, we use a dataset corresponding to 1.3 fb{sup -1} of collected luminosity. We measure {Delta}{Lambda}{sub s} = (0.071{sub -0.059}{sup +0.064} {+-} 0.007) ps{sup -1} using the time-dependent angular analysis. Combining the angular analysis with flavor-tagging, we find that assuming the Standard Model predictions of {beta}{sub s} and {Delta}{Lambda}{sub s}, the probability of a deviation as large as the level of the observed data is 33%. We obtain a suite of associated results which are discussed in detail in this dissertation alongside the main results.

  2. Mirant: Case 67a: Units 3 & 4 & 5 at Max Load for 12 hours and at Min Load

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for 12 hours | Department of Energy Case 67a: Units 3 & 4 & 5 at Max Load for 12 hours and at Min Load for 12 hours Mirant: Case 67a: Units 3 & 4 & 5 at Max Load for 12 hours and at Min Load for 12 hours Docket No. EO-05-01. Mirant: Case 67a: Units 3 & 4 & 5 at Max Load for 12 hours and at Min Load for 12 hours. Arial photograph showing plant and location of predicted SO2 violations, predicted in 2000. PDF icon Mirant: Case 67a: Units 3 & 4 & 5 at Max Load for

  3. Laboratory Investigation of Organic Aerosol Formation from Aromatic Hydrocarbons

    DOE R&D Accomplishments [OSTI]

    Molina, Luisa T.; Molina, Mario J.; Zhang, Renyi

    2006-08-23

    Our work for this DOE funded project includes: (1) measurements of the kinetics and mechanism of the gas-phase oxidation reactions of the aromatic hydrocarbons initiated by OH; (2) measurements of aerosol formation from the aromatic hydrocarbons; and (3) theoretical studies to elucidate the OH-toluene reaction mechanism using quantum-chemical and rate theories.

  4. J/psi production at high transverse momenta in p+p and Cu+Cu collisions at sqrt sNN = 200 GeV

    SciTech Connect (OSTI)

    STAR Collaboration; Abelev, B. I.

    2009-10-27

    The STAR collaboration at RHIC presents measurements of J/{psi} {yields} e{sup +}e{sup -} at mid-rapidity and high transverse momentum (p{sub T} > 5 GeV/c) in p+p and central Cu+Cu collisions at {radical}sNN = 200 GeV. The inclusive J/{psi} production cross section for Cu+Cu collisions is found to be consistent at high p{sub T} with the binary collision-scaled cross section for p+p collisions, in contrast to previous measurements at lower p{sub T}, where a suppression of J/{psi} production is observed relative to the expectation from binary scaling. Azimuthal correlations of J/{psi} with charged hadrons in p+p collisions provide an estimate of the contribution of B-meson decays to J/{psi} production of 13% {+-} 5%.

  5. Successful continuous injection of coal into gasification and PFBC system operating pressures exceeding 500 PSI - DOE funded program results

    SciTech Connect (OSTI)

    2005-07-01

    President Bush's energy program is focussed towards commercializing power production technologies that offer improvements in efficiency and reductions in emissions while utilizing the nation's most abundant energy reserve - coal. Gasification offers such benefits. To bring this technology to full commercial acceptance, the operational issue of feeding solid fuel into the pressure environment needs to be addressed. The DOE, through the National Energy Technology Laboratory, has funded research to develop the unique Stamet 'Posimetric Solids Pump' to feed coal into current gasification operating pressures. The project comprised design and testing to feed coal into 300 PSI and a second Phase for feeding into 500 PSI. The 300 PSI target was achieved in December 2003. In January 2005, the Posimetric feeder achieved continuous injection of coal into 560 PSI, exceeding the Phase 2 target. This paper presents a review and evaluation of the design, design optimizations and test results of the successful feeder. It also presents analysis of economic benefits to pump use and results from semi-commercial testing at gasifier operating test facilities, which should have commenced by the date of the Conference. 16 figs., 6 tabs.

  6. Measurement of the B+-_c Meson Lifetime Using B+-_c -> J/psi + l+- + X Decays

    SciTech Connect (OSTI)

    Hartz, Mark Patrick; /Pittsburgh U.

    2008-11-01

    This thesis describes a measurement of the average proper decay time of the B{sub c}{sup {+-}} mesons, the ground state of bottom and charm quark bound states. The lifetime measurement is carried out in the decay modes B{sub c}{sup {+-}} {yields} J/{psi} + e{sup {+-}} + X and B{sub c}{sup {+-}} {yields} J/{psi} + {mu}{sup {+-}} + X, where the J/{psi} decays as J/{psi} {yields} {mu}{sup +}{mu}{sup -} and the X are unmeasured particles such as {nu}{sub e} or {nu}{sub {mu}}. The data are collect by the CDF II detector which measures the properties of particles created in {radical}s = 1.96 TeV p{bar p} collisions delivered by the Fermilab Tevatron. This measurement uses {approx} 1 fb{sup -1} of integrated luminosity. The measured average proper decay time of B{sub c}{sup {+-}} mesons, {tau} = 0.475{sub -0.049}{sup +0.053}(stat.) {+-} 0.018(syst.) ps, is competitive with the most precise measurements in the world and confirms previous measurements and theoretical predictions.

  7. Next-to-leading-order QCD corrections to e{sup +}e{sup -}{yields}J/{psi}cc at the B factories

    SciTech Connect (OSTI)

    Gong Bin; Wang Jianxiong

    2009-09-01

    We calculate the next-to-leading-order (NLO) QCD correction to e{sup +}e{sup -}{yields}J/{psi}cc at the B factories, and present theoretical predictions on the momentum and production angular distribution for J/{psi} production, and momentum distribution for J/{psi} polarization at NLO for the first time. By applying Brodsky, Lepage, and Mackenzie scale setting for the renormalization scale, it is found that the QCD perturbative expansion is significantly improved with the unique scale choice {mu}*=1.65 GeV. Together with the {psi}{sup '} feed-down contribution, the total cross section and momentum distribution can account for the recent experimental measurement by the Belle collaboration. The total cross section and momentum distribution are also found to be consistent with the experimental measurement in the previous study on e{sup +}e{sup -}{yields}J/{psi}gg. However, the production angular distribution of J/{psi} production for either the J/{psi}cc or the J/{psi}gg channel has a quite different shape in contrast with the new experimental data, although it fits with the experimental data when the two channels are added together. This situation is difficult to explain. To clarify the puzzle of J/{psi} polarization, further experimental measurements are strongly expected to testify our predictions on the momentum distribution for J/{psi} polarization. Our total cross section agrees with that given in the previous study of Zhang and Chao by using their renormalization scheme and input parameters.

  8. Coupling of oxidative dehydrogenation and aromatization reactions of butane

    SciTech Connect (OSTI)

    Xu, Wen-Qing; Suib, S.L. )

    1994-01-01

    Coupling of oxidative dehydrogenation and aromatization of butane by using a dual function catalyst has led to a significant enhancement of the yields (from 25 to 40%) and selectivities to aromatics (from 39 to 64%). Butane is converted to aromatics by using either zinc-promoted [Ga]-ZSM-5 or zinc and gallium copromoted [Fe]-ZSM-5 zeolite as a catalyst. However, the formation of aromatics is severely limited by hydrocracking of butane to methane, ethane, and propane due to the hydrogen formed during aromatization reactions. On the other hand, the oxidative dehydrogenation of butane to butene over molybdate catalysts is found to be accompanied by a concurrent undesirable reaction, i.e., total oxidation. When two of these reactions (oxidative dehydrogenation and aromatization of butane) are coupled by using a dual function catalyst they have shown to complement each other. It is believed that the rate-limiting step for aromatization (butane to butene) is increased by adding an oxidative dehydrogenation catalyst (Ga-Zn-Mg-Mo-O). The formation of methane, ethane, and propane was suppressed due to the removal of hydrogen initially formed as water. Studies of ammonia TPD show that the acidities of [Fe]-ZSM-5 are greatly affected by the existence of metal oxides such as Ga[sub 2]O[sub 3], MgO, ZnO, and MoO[sub 3]. 40 refs., 9 figs., 1 tab.

  9. ~max0006

    National Nuclear Security Administration (NNSA)

    MANUAL Approved: 10-1 7-08 NNSA Line Oversight and Contractor Assurance System Supplemental Directive U.S. DEPARTMENT OF ENERGY National Nuclear Security Administration AVAILABLE ONLINE AT: Iink to NNSA Policicsisupplementa1 directives This page is intentionally blank. NNSA LINE OVERSIGHT AND CONTRACTOR ASSUWNCE SYSTEM SUPPLEMENTAL DIRECTIVE 1. PURPOSE. 'The Line Oversight and Contractor Assurance System (1,OCAS) is the National Nuclear Security Administration (NSSA) management system that

  10. Max Schulze

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Today, he is a three-time unicycling world champion, with world wins in New Zealand in 2010, Italy in 2012 and Canada in 2014. "My main competitive unicycling event is 'trials,'" ...

  11. Max Tech and Beyond: Fluorescent Lamps (Technical Report) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Fluorescent Lamps Citation Details In-Document Search Title: Max Tech and Beyond: Fluorescent Lamps Fluorescent lamps are the most widely used artificial light source today, responsible for approximately 70% of the lumens delivered to our living spaces globally. The technology was originally commercialized in the 1930's, and manufacturers have been steadily improving the efficacy of these lamps over the years through modifications to the phosphors, cathodes, fill-gas, operating frequency, tube

  12. Max Tech and Beyond: Fluorescent Lamps (Technical Report) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Fluorescent Lamps Citation Details In-Document Search Title: Max Tech and Beyond: Fluorescent Lamps × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit OSTI to utilize additional information resources in energy science and technology. A paper copy of this document is also available for sale to the public from the National Technical

  13. Next-to-Leading-Order QCD Corrections to e{sup +}e{sup -}{yields}J/{psi}gg at the B Factories

    SciTech Connect (OSTI)

    Gong Bin; Wang Jianxiong

    2009-04-24

    We calculate the next-to-leading-order (NLO) QCD corrections to e{sup +}e{sup -}{yields}J/{psi}gg via color singlet J/{psi}({sup 3}S{sub 1}) at the B factories. The result shows that the cross section is enhanced to 0.373 pb by a K factor (NLO/LO) of about 1.21. By considering its dependence on the charm quark mass and renormalization scale, the NLO cross section can range from 0.294 to 0.409 pb. Further including the {psi}{sup '} feed-down, {sigma}[e{sup +}e{sup -}{yields}J/{psi}X(non-cc)] is enhanced by another factor of about 1.29 and reach 0.482 pb. In addition, the momentum distributions of J/{psi} production and polarization are presented. Recent measurements from Belle agree well with our prediction for the cross section and momentum distribution. It is expected that this process can serve as a very good channel to clarify the J/{psi} polarization puzzle by performing further experimental measurements.

  14. Measurement of BR(Bu to phi K)/BR(Bu to J/psi K) at the collider detector at Fermilab

    SciTech Connect (OSTI)

    Napora, Robert A

    2004-10-01

    This thesis presents evidence for the decay mode B{sup {+-}} {yields} {phi}K{sup {+-}} in p{bar p} collisions at {radical}s = 1.96 TeV using (120 {+-} 7)pb{sup -1} of data collected by the Collider Detector at Fermilab (CDF). This signal is then used to measure the branching ratio relative to the decay mode B{sup {+-}} {yields} J/{psi}K{sup {+-}}. The measurement starts from reconstructing the two decay modes: B{sup {+-}} {yields} {phi}K{sup {+-}}, where {phi} {yields} K{sup +}K{sup -} and B{sup {+-}} {yields} J/{psi}K{sup {+-}}, where J/{psi} {yields} {mu}{sup +}{mu}{sup -}. The measurement yielded 23 {+-} 7 B{sup {+-}} {yields} {phi}K{sup {+-}} events, and 406 {+-} 26 B{sup {+-}} {yields} J/{psi}K{sup {+-}} events. The fraction of B{sup {+-}} {yields} J/{psi}K{sup {+-}} events where the J/{psi} subsequently decayed to two muons (as opposed to two electrons) was found to be f{sub {mu}{mu}} = 0.839 {+-} 0.066. The relative branching ratio of the two decays is then calculated based on the equation: BR(B{sup {+-}} {yields} {phi}K{sup {+-}})/BR(B{sup {+-}} {yields} J/{psi}K{sup {+-}}) = N{sub {phi}K}/N{sub {psi}K} {center_dot}f{sub {mu}{mu}} BR(J/{psi} {yields} {mu}{sup +}{mu}{sup -})/BR({phi} {yields} K{sup +}K{sup -}) {epsilon}{sub {mu}{mu}}K/{epsilon}KKK R({epsilon}{sub iso}). The measurement finds BR(B{sup {+-}} {yields} {phi}K{sup {+-}})/BR(B{sup {+-}} {yields} J/{psi}K{sup {+-}}) = 0.0068 {+-} 0.0021(stat.) {+-} 0.0007(syst.). The B{sup {+-}} {yields} {phi}K{sup {+-}} branching ratio is then found to be BR(B{sup {+-}} {yields} {phi}K{sup {+-}}) = [6.9 {+-} 2.1(stat.) {+-} 0.8(syst.)] x 10{sup -6}. This value is consistent with similar measurements reported by the e{sup +}e{sup -} collider experiments BaBar[1], Belle[2], and CLEO[3].

  15. Max Tech and Beyond: High-Intensity Discharge Lamps (Technical Report) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect High-Intensity Discharge Lamps Citation Details In-Document Search Title: Max Tech and Beyond: High-Intensity Discharge Lamps High-intensity discharge (HID) lamps are most often found in industrial and commercial applications, and are the light source of choice in street and area lighting, and sports stadium illumination. HID lamps are produced in three types - mercury vapor (MV), high pressure sodium (HPS) and metal halide (MH). Of these, MV and MH are considered white-light

  16. Max Tech and Beyond: Maximizing Appliance and Equipment Efficiency by Design

    SciTech Connect (OSTI)

    Desroches, Louis-Benoit; Garbesi, Karina

    2011-07-20

    It is well established that energy efficiency is most often the lowest cost approach to reducing national energy use and minimizing carbon emissions. National investments in energy efficiency to date have been highly cost-effective. The cumulative impacts (out to 2050) of residential energy efficiency standards are expected to have a benefit-to-cost ratio of 2.71:1. This project examined energy end-uses in the residential, commercial, and in some cases the industrial sectors. The scope is limited to appliances and equipment, and does not include building materials, building envelopes, and system designs. This scope is consistent with the scope of DOE's appliance standards program, although many products considered here are not currently subject to energy efficiency standards. How much energy could the United States save if the most efficient design options currently feasible were adopted universally? What design features could produce those savings? How would the savings from various technologies compare? With an eye toward identifying promising candidates and strategies for potential energy efficiency standards, the Max Tech and Beyond project aims to answer these questions. The analysis attempts to consolidate, in one document, the energy savings potential and design characteristics of best-on-market products, best-engineered products (i.e., hypothetical products produced using best-on-market components and technologies), and emerging technologies in research & development. As defined here, emerging technologies are fundamentally new and are as yet unproven in the market, although laboratory studies and/or emerging niche applications offer persuasive evidence of major energy-savings potential. The term 'max tech' is used to describe both best-engineered and emerging technologies (whichever appears to offer larger savings). Few best-on-market products currently qualify as max tech, since few apply all available best practices and components. The three primary analyses presented in this report are: Nevertheless, it is important to analyze best-on-market products, since data on truly max tech technologies are limited. (1) an analysis of the cross-cutting strategies most promising for reducing appliance and equipment energy use in the U.S.; (2) a macro-analysis of the U.S. energy-saving potential inherent in promising ultra-efficient appliance technologies; and (3) a product-level analysis of the energy-saving potential.

  17. University of Delaware | Catalysis Center for Energy Innovation | Aromatics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Thrust Green Aromatics Transition state for the Diels-Alder reaction of 2,5-dimethylfuran and ethylene in zeolite LiY Most polymers and plastics require six-carbon ring structures. Sugars (such as glucose and xylose) derived from cellulose and hemicellulose are converted into five-atom ring structures called furans, which consist of four carbons and one oxygen. In order to make the right carbon atom ring, CCEI has introduced technology for the production of aromatics from furans by

  18. Max Phase Materials And Coatings For High Temperature Heat Transfer Applications

    SciTech Connect (OSTI)

    Martinez-Rodriguez, M.; Garcia-Diaz, B.; Olson, L.; Fuentes, R.; Sindelar, R.

    2015-10-19

    Molten salts have been used as heat transfer fluids in a variety of applications within proposed Gen IV nuclear designs and in advanced power system such as Concentrating Solar Power (CSP). However, operating at elevated temperatures can cause corrosion in many materials. This work developed coating technologies for MAX phase materials on Haynes-230 and characterized the corrosion of the coatings in the presence of commercial MgCl2-KCl molten salt. Cold spraying of Ti2AlC and physical vapor deposition (PVD) of Ti2AlC or Zr2AlC were tested to determine the most effective form of coating MAX phases on structural substrates. Corrosion testing at 850°C for 100 hrs showed that 3.9 μm Ti2AlC by PVD was slightly protective while 117 μm Ti2AlC by cold spray and 3.6 μm Zr2AlC by PVD were completely protective. None of the tests showed decomposition of the coating (Ti or Zr) into the salt

  19. No-carrier-added (NCA) aryl ([sup 18]F) fluorides via the nucleophilic aromatic substitution of electron rich aromatic rings

    DOE Patents [OSTI]

    Yushin Ding; Fowler, J.S.; Wolf, A.P.

    1993-10-19

    A method for synthesizing no-carrier-added (NCA) aryl [.sup.18 F] fluoride substituted aromatic aldehyde compositions bearing an electron donating group is described. The method of the present invention includes the step of reacting aromatic nitro aldehydes having a suitably protected hydroxyl substitutent on an electron rich ring. The reaction is The U.S. Government has rights in this invention pursuant to Contract Number DE-AC02-76CH00016, between the U.S. Department of Energy and Associated Universities Inc.

  20. No-carrier-added (NCA) aryl (18E) fluorides via the nucleophilic aromatic substitution of electron rich aromatic rings

    DOE Patents [OSTI]

    Ding, Yu-Shin; Fowler, Joanna S.; Wolf, Alfred P.

    1993-01-01

    A method for synthesizing no-carrier-added (NCA) aryl [.sup.18 F] fluoride substituted aromatic aldehyde compositions bearing an electron donating group is described. The method of the present invention includes the step of reacting aromatic nitro aldehydes having a suitably protected hydroxyl substitutent on an electron rich ring. The reaction is The U.S. Government has rights in this invention pursuant to Contract Number DE-AC02-76CH00016, between the U.S. Department of Energy and Associated Universities Inc.

  1. Development of genetically engineered bacteria for production of selected aromatic compounds

    DOE Patents [OSTI]

    Ward, Thomas E.; Watkins, Carolyn S.; Bulmer, Deborah K.; Johnson, Bruce F.; Amaratunga, Mohan

    2001-01-01

    The cloning and expression of genes in the common aromatic pathway of E. coli are described. A compound for which chorismate, the final product of the common aromatic pathway, is an anabolic intermediate can be produced by cloning and expressing selected genes of the common aromatic pathway and the genes coding for enzymes necessary to convert chorismate to the selected compound. Plasmids carrying selected genes of the common aromatic pathway are also described.

  2. Relativistic correction to e{sup +}e{sup -{yields}}J/{psi}+gg at B factories and constraint on color-octet matrix elements

    SciTech Connect (OSTI)

    He Zhiguo; Fan Ying; Chao Kuangta

    2010-03-01

    We calculate the relativistic correction to J/{psi} production in the color-singlet process e{sup +}e{sup -{yields}}J/{psi}+gg at B factories. We employ the nonrelativistic QCD factorization approach, where the short-distance coefficients are calculated perturbatively and the long-distance matrix elements are extracted from the decays of J/{psi} into e{sup +}e{sup -} and light hadrons. We find that the O(v{sup 2}) relativistic correction can enhance the cross section by a factor of 20-30%, comparable to the enhancement due to the O({alpha}{sub s}) radiative correction obtained earlier. Combining the relativistic correction with the QCD radiative correction, we find that the color-singlet contribution to e{sup +}e{sup -{yields}}J/{psi}+gg can saturate the latest observed cross section {sigma}(e{sup +}e{sup -{yields}}J/{psi}+X{sub non-cc})=0.43{+-}0.09{+-}0.09 pb by Belle, thus leaving little room to the color-octet contributions. This gives a very stringent constraint on the color-octet contribution, and may imply that the values of color-octet matrix elements are much smaller than expected earlier by using the naive velocity scaling rules or extracted from fitting experimental data with the leading-order calculations.

  3. Boride-based nano-laminates with MAX-phase-like behaviour

    SciTech Connect (OSTI)

    Telle, Rainer . E-mail: telle@ghi.rwth-aachen.de; Momozawa, Ai; Music, Denis; Schneider, Jochen M.

    2006-09-15

    MAX-phases being usually composed of transition metals, group A elements and carbon/nitrogen are considered interesting materials for many applications because of their tremendous bulk modulus, 'reversible' plasticity, and machinability. This is mainly due to their unique kind of bonding comprising covalent, ionic as well as metallic bonds providing 'easy' planes of rupture and deformability due to the layered crystal structures. In transition metal boride systems, similar types of bonding are available. In particular the W{sub 2}B{sub 5}-structure type and its stacking variations allow the synthesis of strongly layered crystal structures exhibiting unique delamination phenomena. The paper presents ab initio calculations showing the similarities of bonding between the ternary carbides and the corresponding ternary or quaternary borides. Formation of boride-based nano-laminates from auxiliary liquid phases, from the melt as well as during sintering and precipitation from supersaturated solid solutions will be discussed by means of SEM and TEM studies. The role of impurities weakening the interlayer bonding will be addressed in particular. The pronounced cleavage parallel to the basal plane gives rise for crack deflection and pull-out mechanisms if the laminates are dispersed in brittle matrices such as boron carbide, silicon carbide or other transition metal borides. - Graphical abstract: Some transition metal borides crystallise in a layered structure of alternating stacks of metal and boron atoms giving rise for strongly anisotropic properties. Their preferred cleavage parallel and the deformability perpendicular to the basal plan are similar to the peculiar mechanical behaviour recently described for MAX-phases. Ab initio calculations of the crystal structure prove the weak bonds between the layers for a variety of borides which can be used to reinforce ceramic materials on a nano-scale level.

  4. Ambient aromatic hydrocarbon measurements at Welgegund, South Africa

    SciTech Connect (OSTI)

    Jaars, K.; Beukes, J. P.; van Zyl, P. G.; Venter, A. D.; Josipovic, M.; Pienaar, J. J.; Vakkari, Ville; Aaltonen, H.; Laakso, H.; Kulmala, M.; Tiitta, P.; Guenther, Alex B.; Hellen, H.; Laakso, L.; Hakola, H.

    2014-07-11

    Aromatic hydrocarbons are associated with direct adverse human health effects and can have negative impacts on ecosystems due to their toxicity, as well as indirect negative effects through the formation of tropospheric ozone and secondary organic aerosol that affect human health, crop production and regional climate. Measurements were conducted at the Welgegund measurement station (South Africa) that is considered to be a regionally representative background site. However, the site is occasionally impacted by plumes from major anthropogenic source regions in the interior of South Africa, which include the western Bushveld Igneous Complex (e.g. platinum, base metal and ferrochrome smelters), the eastern Bushveld Igneous Complex (platinum and ferrochrome smelters), the Johannesburg-Pretoria metropolitan conurbation (>10 million people), the Vaal Triangle (e.g. petrochemical and industries), the Mpumalanga Highveld (e.g. coal-fired power plants and petrochemical industry) and also a region of anti-cyclonic recirculation of air mass over the interior of South Africa. The aromatic hydrocarbon measurements were conducted with an automated sampler on Tenax-TA and Carbopack-B adsorbent tubes with heated inlet for one year. Samples were collected twice a week for two hours during daytime and two hours 1 during night-time. A thermal desorption unit, connected to a gas chromatograph and a mass 2 selective detector was used for sample preparation and analysis. Results indicated that the 3 monthly median total aromatic hydrocarbon concentrations ranged between 0.01 to 3.1 ppb. 4 Benzene levels did not exceed local air quality standards. Toluene was the most abundant 5 species, with an annual median concentration of 0.63 ppb. No statistically significant 6 differences in the concentrations measured during daytime and night-time were found and no distinct seasonal patterns were observed. Air mass back trajectory analysis proved that the lack of seasonal cycles could be attributed to patterns determining the origin of the air masses sampled. Aromatic hydrocarbon concentrations were in general significantly higher in air masses that passed over anthropocentrically impacted regions. Interspecies correlations and ratios gave some indications of the possible sources for the different aromatic hydrocarbons in the source regions defined in the paper. The highest contribution of aromatic hydrocarbon concentrations to ozone formation potential was also observed in plumes passing over anthropocentrically impacted regions.

  5. Redox shuttles having an aromatic ring fused to a 1,1,4,4-tetrasubstituted cyclohexane ring

    DOE Patents [OSTI]

    Weng, Wei; Zhang, Zhengcheng; Amine, Khalil

    2015-12-01

    An electrolyte includes an alkali metal salt; an aprotic solvent; and a redox shuttle additive including an aromatic compound having at least one aromatic ring fused with at least one non-aromatic ring, the aromatic ring having two or more oxygen or phosphorus-containing substituents.

  6. Amination of electrophilic aromatic compounds by vicarious nucleophilic substitution

    DOE Patents [OSTI]

    Mitchell, Alexander R.; Pagoria, Philip F.; Schmidt, Robert D.

    2000-01-01

    The present invention relates to a process to aminate electrophilic aromatic compounds by vicarious nucleophilic substitution of hydrogen using quaternary hydrazinium salts. The use of trialkylhydrazinium halide, e.g., trimethylhydrazinium iodide, as well as hydroxylamine, alkoxylamines, and 4-amino-1,2,4-triazole to produce aminated aromatic structures, such as 1,3-diamino-2,4,6-trinitrobenzene (DATB), 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) and 3,5-diamino-2,4,6-trinitrotoluene (DATNT), is described. DATB and TATB are useful insensitive high explosives. TATB is also used for the preparation of benzenehexamine, a starting material for the synthesis of novel materials (optical imaging devices, liquid crystals, ferromagnetic compounds).

  7. THE INFRARED SPECTROSCOPY OF NEUTRAL POLYCYCLIC AROMATIC HYDROCARBON CLUSTERS

    SciTech Connect (OSTI)

    Ricca, Alessandra; Bauschlicher, Charles W. Jr.; Allamandola, Louis J. E-mail: Charles.W.Bauschlicher@nasa.gov

    2013-10-10

    The mid-infrared spectra of neutral homogeneous polycyclic aromatic hydrocarbon (PAH) clusters have been computed using density functional theory including an empirical correction for dispersion. The C-H out-of-plane bending modes are redshifted for all the clusters considered in this work. The magnitude of the redshift and the peak broadening are dependent on PAH size, shape, and on the PAH arrangement in the cluster.

  8. Measurement of the production fraction times branching fraction $\\boldsymbol{ f(b\\to\\Lambda_{b})\\cdot \\mathcal{B}(\\Lambda_{b}\\to J/\\psi \\Lambda)}$

    SciTech Connect (OSTI)

    Abazov, Victor Mukhamedovich; /Dubna, JINR; Abbott, Braden Keim; /Oklahoma U.; Acharya, Bannanje Sripath; /Tata Inst.; Adams, Mark Raymond; /Illinois U., Chicago; Adams, Todd; /Florida State U.; Alexeev, Guennadi D.; /Dubna, JINR; Alkhazov, Georgiy D.; /St. Petersburg, INP; Alton, Andrew K.; /Michigan U. /Augustana Coll., Sioux Falls; Alverson, George O.; /Northeastern U.; Alves, Gilvan Augusto; /Rio de Janeiro, CBPF; Ancu, Lucian Stefan; /Nijmegen U. /Fermilab

    2011-05-01

    The {Lambda}{sub b}(udb) baryon is observed in the decay {Lambda}{sub b} {yields} J/{psi}{Lambda} using 6.1 fb{sup -1} of p{bar p} collisions collected with the D0 detector at {radical}s = 1.96 TeV. The production fraction multiplied by the branching fraction for this decay relative to that for the decay B{sup 0} {yields} J/{psi}K{sub s}{sup 0} is measured to be 0.345 {+-} 0.034 (stat.) {+-} 0.033 (syst.) {+-} 0.003 (PDG). Using the world average value of f(b {yields} B{sup 0}) {center_dot} {Beta}(B{sup 0} {yields} J/{psi}K{sub s}{sup 0}) = (1.74 {+-} 0.08) x 10{sup -5}, they obtain f(b {yields} {Lambda}{sub b}) {center_dot} {Beta}({Lambda}{sub b} {yields} J/{psi}{Lambda}) = (6.01 {+-} 0.60 (stat.) {+-} 0.58 (syst.) {+-} 0.28 (PDG)) x 10{sup -5}. This measurement represents an improvement in precision by about a factor of three with respect to the current world average.

  9. Method of upgrading oils containing hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline

    DOE Patents [OSTI]

    Baker, Eddie G. (Richland, WA); Elliott, Douglas C. (Richland, WA)

    1993-01-01

    The present invention is a multi-stepped method of converting an oil which is produced by various biomass and coal conversion processes and contains primarily single and multiple ring hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline. The single and multiple ring hydroxyaromatic hydrocarbon compounds in a raw oil material are first deoxygenated to produce a deoxygenated oil material containing single and multiple ring aromatic compounds. Then, water is removed from the deoxygenated oil material. The next step is distillation to remove the single ring aromatic compouns as gasoline. In the third step, the multiple ring aromatics remaining in the deoxygenated oil material are cracked in the presence of hydrogen to produce a cracked oil material containing single ring aromatic compounds. Finally, the cracked oil material is then distilled to remove the single ring aromatics as gasoline.

  10. Reduction of Aromatic Hydrocarbons by Zero-Valent Iron and Palladium Catalyst

    SciTech Connect (OSTI)

    Kim, Young-Hun; Shin, Won Sik; Ko, Seok-Oh; Kim, Myung-Chul

    2004-03-31

    Permeable reactive barrier (PRB) is an alternative technology for soil and groundwater remediation. Zero valent iron, which is the most popular PRB material, is only applicable to halogenated aliphatic organics and some heavy metals. The objective of this study was to investigate reductive dechlorination of halogenated compounds and reduction of non-halogenated aromatic hydrocarbons using zero valent metals (ZVMs) and catalysts as reactive materials for PRBs. A group of small aromatic hydrocarbons such as monochlorophenols, phenol and benzene were readily reduced with palladium catalyst and zero valent iron. Poly-aromatic hydrocarbons (PAHs) were also tested with the catalysts and zero valent metal combinations. The aromatic rings were reduced and partly reduced PAHs were found as the daughter compounds. The current study demonstrates reduction of aromatic compounds by ZVMs and modified catalysts and implicates that PRB is applicable not only for halogenated organic compounds but nonhalogenated aromatic compounds such as PAHs.

  11. Method of upgrading oils containing hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline

    DOE Patents [OSTI]

    Baker, E.G.; Elliott, D.C.

    1993-01-19

    The present invention is a multi-stepped method of converting an oil which is produced by various biomass and coal conversion processes and contains primarily single and multiple ring hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline. The single and multiple ring hydroxyaromatic hydrocarbon compounds in a raw oil material are first deoxygenated to produce a deoxygenated oil material containing single and multiple ring aromatic compounds. Then, water is removed from the deoxygenated oil material. The next step is distillation to remove the single ring aromatic compounds as gasoline. In the third step, the multiple ring aromatics remaining in the deoxygenated oil material are cracked in the presence of hydrogen to produce a cracked oil material containing single ring aromatic compounds. Finally, the cracked oil material is then distilled to remove the single ring aromatics as gasoline.

  12. Process for conversion of light olefins to LPG and aromatics

    SciTech Connect (OSTI)

    Martindale, D.C.; Andermann, R.E.; Mowry, J.R.

    1989-01-03

    A hydrocarbon conversion process is described which comprises passing a hydrocarbon feed stream comprising at least 30 mole percent olefins having 3 to 4 carbon atoms per molecule and also comprising at least 50 mole percent paraffins having 3 to 4 carbon atoms per molecule and containing less than 10 mole percent C/sub 5/-plus hydrocarbons into a catalytic reaction zone operated at low severity conditions and contacting the feed stream with a solid catalyst gallium. A reaction zone effluent stream is produced comprising C/sub 6/-C/sub 8/ aromatic hydrocarbons and C/sub 3/-C/sub 4/ paraffins, with the reaction zone effluent stream containing less than 10 mole percent olefinic hydrocarbons. The low severity conditions include a combination of pressure, feed space velocity and temperature, including a temperature below 425/sup 0/C, which results in a partial conversion of the feed hydrocarbons into aromatic hydrocarbons whereby: (i) when the effluent is separated there are produced a first product stream, which first product stream is rich in C/sub 6/-C/sub 8/ aromatic hydrocarbons and is withdrawn from the process, with the second product stream, which second product stream is rich in C/sub 3/-C/sub 4/ paraffins and is withdrawn from the process, with the second product stream having a flow rate equal to at least 30 wt. percent of the flow rate of the feed stream; and (ii) the mass flow rate of paraffinic hydrocarbons out of the reaction zone exceeds the mass flow rate of paraffinic hydrocarbons into the reaction zone.

  13. An In-Depth Look at Ground Source Heat Pumps and Other Electric Loads in Two GreenMax Homes

    SciTech Connect (OSTI)

    Puttagunta, Srikanth; Shapiro, Carl

    2012-04-01

    Building America research team Consortium for Advanced Residential Buildings (CARB) partnered with WPPI Energy to answer key research questions on in-field performance of ground-source heat pumps and lighting, appliance, and miscellaneous loads (LAMELs) through extensive field monitoring at two WPPI GreenMax demonstration homes in Wisconsin. These two test home evaluations provided valuable data on the true in-field performance of various building mechanical systems and LAMELs.

  14. LARGE ABUNDANCES OF POLYCYCLIC AROMATIC HYDROCARBONS IN TITAN'S UPPER ATMOSPHERE

    SciTech Connect (OSTI)

    Lopez-Puertas, M.; Funke, B.; Garcia-Comas, M.; Dinelli, B. M.; Adriani, A.; D'Aversa, E.; Moriconi, M. L.; Boersma, C.; Allamandola, L. J.

    2013-06-20

    In this paper, we analyze the strong unidentified emission near 3.28 {mu}m in Titan's upper daytime atmosphere recently discovered by Dinelli et al. We have studied it by using the NASA Ames PAH IR Spectroscopic Database. The polycyclic aromatic hydrocarbons (PAHs), after absorbing UV solar radiation, are able to emit strongly near 3.3 {mu}m. By using current models for the redistribution of the absorbed UV energy, we have explained the observed spectral feature and have derived the vertical distribution of PAH abundances in Titan's upper atmosphere. PAHs have been found to be present in large concentrations, about (2-3) Multiplication-Sign 10{sup 4} particles cm{sup -3}. The identified PAHs have 9-96 carbons, with a concentration-weighted average of 34 carbons. The mean mass is {approx}430 u; the mean area is about 0.53 nm{sup 2}; they are formed by 10-11 rings on average, and about one-third of them contain nitrogen atoms. Recently, benzene together with light aromatic species as well as small concentrations of heavy positive and negative ions have been detected in Titan's upper atmosphere. We suggest that the large concentrations of PAHs found here are the neutral counterpart of those positive and negative ions, which hence supports the theory that the origin of Titan main haze layer is located in the upper atmosphere.

  15. Measurement of the B_d0 lifetime using B_d0 to J/psi K0_S decays at Dzero

    SciTech Connect (OSTI)

    Balm, Paul W

    2004-12-01

    This thesis describes a measurement of the B{sub d}{sup 0} lifetime in the decay to (J/{psi}K{sub S}{sup 0}), using 114 pb{sup -1} of data collected by the D0 experiment at the Tevatron from October 15, 2002, to June 10, 2003. The measurement is motivated by the tests of the Standard Model that it makes possible. These include tests of Heavy Quark Effective Theory predicting B-meson lifetimes, and of the complex phase in the CKM-matrix as the source of CP-violation in B{sub d}{sup 0} decays to (J/{psi}K{sub S}{sup 0}).

  16. Synthesis of condensed phases containing polycyclic aromatic hydrocarbons fullerenes and nanotubes

    DOE Patents [OSTI]

    Reilly, Peter T. A.

    2004-10-19

    The invention relates to methods for producing polycyclic aromatic hydrocarbons, fullerenes, and nanotubes, comprising: a. heating at least one carbon-containing material to form a condensed phase comprising at least one polycyclic aromatic hydrocarbon; b. collecting at least some of the condensed phase; c. reacting the condensed phase to form fullerenes and/or nanotubes.

  17. Characterization of ZnO thin films grown on different p-Si substrate elaborated by solgel spin-coating method

    SciTech Connect (OSTI)

    Chebil, W.; Fouzri, A.; Fargi, A.; Azeza, B.; Zaaboub, Z.; and others

    2015-10-15

    Highlights: • High quality ZnO thin films grown on different p-Si substrates were successful obtained by sol–gel process. • PL measurement revealed that ZnO thin film grown on porous Si has the better optical quality. • I–V characteristics for all heterojunctions exhibit successful diode formation. • The diode ZnO/PSi shows a better photovoltaic effect under illumination with a maximum {sub Voc} of 0.2 V. - Abstract: In this study, ZnO thin films are deposited by sol–gel technique on p-type crystalline silicon (Si) with [100] orientation, etched silicon and porous silicon. The structural analyses showed that the obtained thin films were polycrystalline with a hexagonal wurtzite structure and preferentially oriented along the c-axis direction. Morphological study revealed the presence of rounded and facetted grains irregularly distributed on the surface of all samples. PL spectra at room temperature revealed that ZnO thin film grown on porous Si has a strong UV emission with low defects in the visible region comparing with ZnO grown on plat Si and etched Si surface. The heterojunction parameters were evaluated from the (I–V) under dark and illumination at room temperature. The ideality factor, barrier height and series resistance of heterojunction grown on different p-Si substrates are determined by using different methods. Best electrical properties are obtained for ZnO layer deposited on porous silicon.

  18. Extremely strong tubular stacking of aromatic oligoamide macrocycles

    SciTech Connect (OSTI)

    Kline, Mark A.; Wei, Xiaoxi; Horner, Ian J.; Liu, Rui; Chen, Shuang; Chen, Si; Yung, Ka Yi; Yamato, Kazuhiro; Cai, Zhonghou; Bright, Frank V.; Zeng, Xiao Cheng; Gong, Bing

    2015-01-01

    As the third-generation rigid macrocycles evolved from progenitor 1, cyclic aromatic oligoamides 3, with a backbone of reduced constraint, exhibit extremely strong stacking with an astoundingly high affinity (estimated lower limit of Kdimer > 1013 M-1 in CHCl3), which leads to dispersed tubular stacks that undergo further assembly in solution. Computational study reveals a very large binding energy (-49.77 kcal mol-1) and indicates highly cooperative local dipole interactions that account for the observed strength and directionality for the stacking of 3. In the solid-state, X-ray diffraction (XRD) confirms that the aggregation of 3 results in well-aligned tubular stacks. The persistent tubular assemblies of 3, with their non-deformable sub-nm pore, are expected to possess many interesting functions. One such function, transmembrane ion transport, is observed for 3.

  19. Extremely strong tubular stacking of aromatic oligoamide macrocycles

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kline, Mark A.; Wei, Xiaoxi; Horner, Ian J.; Liu, Rui; Chen, Shuang; Chen, Si; Yung, Ka Yi; Yamato, Kazuhiro; Cai, Zhonghou; Bright, Frank V.; et al

    2014-09-16

    As the third-generation rigid macrocycles evolved from progenitor 1, cyclic aromatic oligoamides 3, with a backbone of reduced constraint, exhibit extremely strong stacking with an astoundingly high affinity (estimated lower limit of K-dimer > 1013 M-1 in CHCl3), which leads to dispersed tubular stacks that undergo further assembly in solution. Computational study reveals a very large binding energy (-49.77 kcal mol-1) and indicates highly cooperative local dipole interactions that account for the observed strength and directionality for the stacking of 3. In the solid-state, X-ray diffraction (XRD) confirms that the aggregation of 3 results in well-aligned tubular stacks. Furthermore, themore » persistent tubular assemblies of 3, with their non-deformable sub-nm pore, are expected to possess many interesting functions. One such function, transmembrane ion transport, is observed for 3.« less

  20. Extremely strong tubular stacking of aromatic oligoamide macrocycles

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kline, Mark A.; Wei, Xiaoxi; Horner, Ian J.; Liu, Rui; Chen, Shuang; Chen, Si; Yung, Ka Yi; Yamato, Kazuhiro; Cai, Zhonghou; Bright, Frank V.; et al

    2015-01-01

    As the third-generation rigid macrocycles evolved from progenitor 1, cyclic aromatic oligoamides 3, with a backbone of reduced constraint, exhibit extremely strong stacking with an astoundingly high affinity (estimated lower limit of Kdimer > 1013 M-1 in CHCl3), which leads to dispersed tubular stacks that undergo further assembly in solution. Computational study reveals a very large binding energy (-49.77 kcal mol-1) and indicates highly cooperative local dipole interactions that account for the observed strength and directionality for the stacking of 3. In the solid-state, X-ray diffraction (XRD) confirms that the aggregation of 3 results in well-aligned tubular stacks. The persistentmore » tubular assemblies of 3, with their non-deformable sub-nm pore, are expected to possess many interesting functions. One such function, transmembrane ion transport, is observed for 3.« less

  1. Computer Simulations Reveal Multiple Functions for Aromatic Residues in Cellulase Enzymes (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-07-01

    NREL researchers use high-performance computing to demonstrate fundamental roles of aromatic residues in cellulase enzyme tunnels. National Renewable Energy Laboratory (NREL) computer simulations of a key industrial enzyme, the Trichoderma reesei Family 6 cellulase (Cel6A), predict that aromatic residues near the enzyme's active site and at the entrance and exit tunnel perform different functions in substrate binding and catalysis, depending on their location in the enzyme. These results suggest that nature employs aromatic-carbohydrate interactions with a wide variety of binding affinities for diverse functions. Outcomes also suggest that protein engineering strategies in which mutations are made around the binding sites may require tailoring specific to the enzyme family. Cellulase enzymes ubiquitously exhibit tunnels or clefts lined with aromatic residues for processing carbohydrate polymers to monomers, but the molecular-level role of these aromatic residues remains unknown. In silico mutation of the aromatic residues near the catalytic site of Cel6A has little impact on the binding affinity, but simulation suggests that these residues play a major role in the glucopyranose ring distortion necessary for cleaving glycosidic bonds to produce fermentable sugars. Removal of aromatic residues at the entrance and exit of the cellulase tunnel, however, dramatically impacts the binding affinity. This suggests that these residues play a role in acquiring cellulose chains from the cellulose crystal and stabilizing the reaction product, respectively. These results illustrate that the role of aromatic-carbohydrate interactions varies dramatically depending on the position in the enzyme tunnel. As aromatic-carbohydrate interactions are present in all carbohydrate-active enzymes, the results have implications for understanding protein structure-function relationships in carbohydrate metabolism and recognition, carbon turnover in nature, and protein engineering strategies for biofuels production.

  2. Polycyclic aromatic hydrocarbon and mid-infrared continuum emission in a z

    Office of Scientific and Technical Information (OSTI)

    > 4 submillimeter galaxy (Journal Article) | SciTech Connect Polycyclic aromatic hydrocarbon and mid-infrared continuum emission in a z > 4 submillimeter galaxy Citation Details In-Document Search Title: Polycyclic aromatic hydrocarbon and mid-infrared continuum emission in a z > 4 submillimeter galaxy We report the detection of 6.2 μm polycyclic aromatic hydrocarbon (PAH) and rest-frame 4-7 μm continuum emission in the z = 4.055 submillimeter galaxy GN20, using the Infrared

  3. THE RELATIONSHIP BETWEEN {nu}{sub max} AND AGE t FROM ZAMS TO RGB-TIP FOR LOW-MASS STARS

    SciTech Connect (OSTI)

    Tang, Y. K.; Gai, N. E-mail: ning.gai@hotmail.com

    2013-07-10

    Stellar age is an important quantity in astrophysics, which is useful for many fields both in the universe and galaxies. It cannot be determined by direct measurements, but can only be estimated or inferred. We attempt to find a useful indicator of stellar age, which is accurate from the zero-age main sequence to the tip of red giant branch for low-mass stars. Using the Yale Rotation and Evolution Code (YREC), a grid of stellar models has been constructed. Meanwhile, the frequency of maximum oscillations' power {nu}{sub max} and the large frequency separation {Delta}{nu} are calculated using the scaling relations. For the stars, the masses of which are from 0.8 M{sub Sun} to 2.8 M{sub Sun }, we can obtain the {nu}{sub max} and stellar age by combing the scaling relations with the four sets of grid models (YREC, Dotter et al., Marigo et al., and YY isochrones). We find that {nu}{sub max} is tightly correlated and decreases monotonically with the age of the star from the main sequence to the red giant evolutionary stages. Moreover, we find that the line shapes of the curves in the Age versus {nu}{sub max} diagram, which is plotted by the four sets of grid models, are consistent for red giants with masses from 1.1 M{sub Sun} to 2.8 M{sub Sun }. For red giants, the differences of correlation coefficients between Age and {nu}{sub max} for different grid models are minor and can be ignored. Interestingly, we find two peaks that correspond to the subgiants and bump of red giants in the Age versus {nu}{sub max} diagram. By general linear least-squares, we make the polynomial fitting and deduce the relationship between log(Age) and log({nu}{sub max}) in red giants' evolutionary state.

  4. Distribution of polycyclic aromatic hydrocarbons in lime spray dryer ash

    SciTech Connect (OSTI)

    Ping Sun; Panuwat Taerakul; Linda K. Weavers; Harold W. Walker

    2005-10-01

    Four lime spray dryer (LSD) ash samples were collected from a spreader stoker boiler and measured for their concentrations of 16 U.S. EPA specified polycyclic aromatic hydrocarbons (PAHs). Results showed that the total measured PAH concentration correlated with the organic carbon content of the LSD ash. Each LSD ash sample was then separated using a 140 mesh sieve into two fractions: a carbon-enriched fraction ({gt}140 mesh) and a lime-enriched fraction ({lt}140 mesh). Unburned carbon was further separated from the carbon-enriched fraction with a lithiumheteropolytungstate (LST) solution. PAH measurements on these different fractions showed that unburned carbon had the highest PAH concentrations followed by the carbon-enriched fraction, indicating that PAHs were primarily associated with the carbonaceous material in LSD ash. However, detectable levels of PAHs were also found in the lime-enriched fraction, suggesting that the fine spray of slaked lime may sorb PAH compounds from the flue gas in the LSD process. 37 refs., 5 figs., 4 tabs.

  5. Atmospheric transport and outflow of polycyclic aromatic hydrocarbons from China

    SciTech Connect (OSTI)

    Chang Lang; Shu Tao; Wenxin Liu; Yanxu Zhang; Staci Simonich

    2008-07-15

    A potential receptor influence function (PRIF) model, based on air mass forward trajectory calculations, was applied to simulate the atmospheric transport and outflow of polycyclic aromatic hydrocarbons (PAHs) emitted from China. With a 10 day atmospheric transport time, most neighboring countries and regions, as well as remote regions, were influenced by PAH emissions from China. Of the total annual PAH emission of 114 Gg, 92.7% remained within the boundary of mainland China. The geographic distribution of PRIFs within China was similar to the geographic distribution of the source regions, with high values in the North China Plain, Sichuan Basin, Shanxi, and Guizhou province. The Tarim basin and Sichuan basin had unfavorable meteorological conditions for PAH outflow. Of the PAH outflow from China (8092 tons or 7.1% of the total annual PAH emission), approximately 69.9% (5655 tons) reached no further than the offshore environment of mainland China and the South China Sea. Approximate 227, 71, 746, and 131 tons PAHs reached North Korea, South Korea, Russia-Mongolia region, and Japan, respectively, 2-4 days after the emission. Only 1.4 tons PAHs reached North America after more than 9 days. Interannual variation in the eastward PAH outflow was positively correlated to cold episodes of El Nino/Southern Oscillation. However, trans-Pacific atmospheric transport of PAHs from China was correlated to Pacific North America index (PNA) which is associated with the strength and position of westerly winds. 38 refs., 4 figs.

  6. Selective aromatization of C[sub 3]- and C[sub 4]-paraffins over modified encilite catalysts: 2. Kinetics of n-butane aromatization

    SciTech Connect (OSTI)

    Jana, A.K.; Rao, M.S. . Dept. of Chemical Engineering)

    1993-11-01

    The kinetics of the aromatization of n-butane over Zn-encilite catalyst was studied in a fixed bed reactor under steady-state conditions at atmospheric pressure and in the temperature range of 480--540 C. The experimental data were analyzed, and a dual-site mechanism was proposed. Six rate equations of the Langmuir-Hinshelwood type were tested. The unknown parameters in the rate equations were estimated by a nonlinear regression method. A kinetic equation for n-butane aromatization is proposed.

  7. Two-Step Process Converts Lignin into Simple Aromatic Compounds - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Two-Step Process Converts Lignin into Simple Aromatic Compounds Great Lakes Bioenergy Research Center Contact GLBRC About This Technology Technology Marketing Summary Lignin is a major component of non-edible biomass. It is a cheap byproduct of pulp and biofuel production and is one of the few naturally occurring sources of valuable aromatic compounds. Converting lignin's complex biopolymer structure into simple organic chemicals has attracted major interest. For example,

  8. Chemistry of Furan Conversion into Aromatics and Olefins over HZSM-5: A Model Biomass Conversion Reaction

    SciTech Connect (OSTI)

    Cheng, Yu-Ting; Huber, George W.

    2011-06-03

    The conversion of furan (a model of cellulosic biomass) over HZSM-5 was investigated in a thermogravimetric analysismass spectrometry system, in situ Fourier transform infrared analysis, and in a continuous-flow fixed-bed reactor. Furan adsorbed as oligomers at room temperature with a 1.73 of adsorbed furan/Al ratio. These oligomers were polycyclic aromatic compounds that were converted to CO, CO?, aromatics, and olefins at temperatures from 400 to 600 C. Aromatics (e.g., benzene, toluene, and naphthalene), oligomer isomers (e.g., benzofuran, 2,2-methylenebisfuran, and benzodioxane), and heavy oxygenates (C??{sub +} oligomers) were identified as intermediates formed inside HZSM-5 at different reaction temperatures. During furan conversion, graphite-type coke formed on the catalyst surface, which caused the aromatics and olefins formation to deactivate within the first 30 min of time on-stream. We have measured the effects of space velocity and temperature for furan conversion to help us understand the chemistry of biomass conversion inside zeolite catalysts. The major products for furan conversion included CO, CO?, allene, C?C? olefins, benzene, toluene, styrene, benzofuran, indene, and naphthalene. The aromatics (benzene and toluene) and olefins (ethylene and propylene) selectivity decreased with increasing space velocity. Unsaturated hydrocarbons such as allene, cyclopentadiene, and aromatics selectivity increased with increasing space velocity. The product distribution was selective to olefins and CO at high temperatures (650 C) but was selective to aromatics (benzene and toluene) at intermediate temperatures (450600 C). At low temperatures (450 C), benzofuran and coke contributed 60% of the carbon selectivity. Several different reactions were occurring for furan conversion over zeolites. Some important reactions that we have identified in this study include DielsAlder condensation (e.g., two furans form benzofuran and water), decarbonylation (e.g., furan forms CO and allene), oligomerization (allene forms olefins and aromatics plus hydrogen), and alkylation (e.g., furan plus olefins). The product distribution was far from thermodynamic equilibrium.

  9. Environmental diagnostic analysis of ground water bacteria and their involvement in utilization of aromatic compounds

    SciTech Connect (OSTI)

    Wear, J.E. Jr.

    1993-05-01

    The objective of this study was to examine the hypothesis that select functional groups of bacteria from pristine sites have an innate ability to degrade synthetic aromatics that often contaminate groundwater environments,due to exposure to naturally occurring recalcitrant aromatics in their environment. This study demonstrates that subsurface microbial communities are capable of utilizing lignin and humic acid breakdown products. Utilizers of these compounds were found to be present in most all the wells tested. Even the deepest aquifer tested had utilizers present for all six of the aromatics tested. Highest counts for the aromatics tested were observed with the naturally occurring breakdown products of either lignin or humic acid. Carboxylic acids were found to be an important sole carbon source for groundwater bacteria possibly explained by the fact that they are produced by the oxidative cleavage of aromatic ring structures. The carbohydrate sole carbon sources that demonstrated the greatest densities were ones commonly associated with humics. This study indicates that utilization of naturally occurring aromatic compounds in the subsurface is an important nutritional source for groundwater bacteria. In addition, it suggests that adaptation to naturally occurring recalcitrant substrates is the origin of degradative pathways for xenobiotic compounds with analogous structure. This work has important implications for in situ bioremediation as a method of environmental cleanup.

  10. Measurement of the ratio $\\mathcal{B}( \\mathrm{B}^0_{s} \\to \\mathrm{J}/\\psi\\, \\mathrm{f}_0(980))/\\mathcal{B}(\\mathrm{B}^0_{s} \\to \\mathrm{J}/\\psi\\, \\phi(1020))$ in pp collisions at $\\sqrt{s}$ = 7 TeV

    SciTech Connect (OSTI)

    Khachatryan, Vardan; et al.,

    2015-01-24

    The ratio $R_{\\, \\mathrm{f}_0 / \\phi}$ of the branching fractions of the $\\mathrm{B}^0_{s}$ meson to the CP-odd eigenstate $\\mathrm{J}/\\psi\\, \\mathrm{f}_0(980)$ and to $\\mathrm{J}/\\psi\\, \\phi(1020)$ is measured, where $\\mathrm{J}/\\psi \\to \\mu^+\\mu^-$, $\\mathrm{f}_0 \\to \\pi^+\\pi^-$, and $\\phi \\to \\mathrm{K}^+\\mathrm{K}^-$. The analysis is based on a data sample of pp collisions at a centre-of-mass energy of 7 TeV, collected by the CMS experiment, corresponding to an integrated luminosity of 5.3 fb$^{-1}$. The result is $R_{\\, \\mathrm{f}_0 / \\phi} = 0.140 \\pm 0.013 \\pm 0.018$, where the first uncertainty is statistical and the second is systematic. This result is consistent with theoretical predictions and previous measurements of $R_{\\, \\mathrm{f}_0 / \\phi}$. It is the most precise measurement of the ratio to date.

  11. Simulation of polycyclic aromatic hydrocarbons transport in multimedia

    SciTech Connect (OSTI)

    Chen, L.; Chu, C.J.

    1999-07-01

    Many studies have indicated that the threat from toxic air pollutants such as VOCs comes not through inhalation by humans while the pollutants are in a gaseous state but through absorption when the pollutants are in a solid state such as in an aerosol or particulate form. Pollutants such as Polycyclic Aromatic Hydrocarbons (PAHs) usually exist in a semi-volatile state. To assess the risk of the PAHs, one needs to estimate the dose of the pollutants to which a human would be exposed through various pathways. In this study, the authors modified a Spatial Multimedia Compartmental Model (SMCM) originally developed by UCLA Professor Cohen to predict the PAHs distribution among multimedia such as air, water, soil and sediment in the Taipei metropolitan area. Three PAHs were considered in this study. They are Benzo(a)pyrene, Pyrene and Chrysene. When PAHs are emitted into atmosphere, physical and chemical mechanisms may redistribute the PAHs among multimedia. Five cases of PAHs distribution in multimedia were simulated: (1) PAHs distribution in a dry condition, (2) PAHs distribution when there are different dry deposition velocities, (3) PAHs distribution under a single rainfall event, (4) PAHs distribution when there are different soil properties, (5) PAHs distribution under a random rainfall case. The simulation results are concluded: (1) In the dry case, the PAHs accumulate mostly in soil and air compartments, (2) Different dry depositing velocities will affect the PAHs distribution among compartments. (3) Different soil properties affect the PAHs concentration in the soil and sediment compartments, (4) The soil PAHs concentrations usually increase for those PAHs with a high solid/gas ratio. (5) The random rainfall only affects the PAHs concentration in the soil.

  12. Kinetics and mechanisms of reactions involving small aromatic reactive intermediates

    SciTech Connect (OSTI)

    Lin, M.C.

    1993-12-01

    Small aromatic radicals such as C{sub 6}H{sub 5}, C{sub 6}H{sub 5}O and C{sub 6}H{sub 4} are key prototype species of their homologs. C{sub 6}H{sub 5} and its oxidation product, C{sub 6}H{sub 5}O are believed to be important intermediates which play a pivotal role in hydrocarbon combustion, particularly with regard to soot formation. Despite their fundamental importance, experimental data on the reaction mechanisms and reactivities of these species are very limited. For C{sub 6}H{sub 5}, most kinetic data except its reactions with NO and NO{sub 2}, were obtained by relative rate measurements. For C{sub 6}H{sub 5}O, the authors have earlier measured its fragmentation reaction producing C{sub 5}H{sub 5} + CO in shock waves. For C{sub 6}H{sub 4}, the only rate constant measured in the gas phase is its recombination rate at room temperature. The authors have proposed to investigate systematically the kinetics and mechanisms of this important class of molecules using two parallel laser diagnostic techniques--laser resonance absorption (LRA) and resonance enhanced multiphoton ionization mass spectrometry (REMPI/MS). In the past two years, study has been focused on the development of a new multipass adsorption technique--the {open_quotes}cavity-ring-down{close_quotes} technique for kinetic applications. The preliminary results of this study appear to be quite good and the sensitivity of the technique is at least comparable to that of the laser-induced fluorescence method.

  13. Process for removing halogenated aliphatic and aromatic compounds from petroleum products

    DOE Patents [OSTI]

    Googin, John M.; Napier, John M.; Travaglini, Michael A.

    1983-01-01

    A process for removing halogenated aliphatic and aromatic compounds, e.g., polychlorinated biphenyls, from petroleum products by solvent extraction. The halogenated aliphatic and aromatic compounds are extracted from a petroleum product into a polar solvent by contacting the petroleum product with the polar solvent. The polar solvent is characterized by a high solubility for the extracted halogenated aliphatic and aromatic compounds, a low solubility for the petroleum product and considerable solvent power for polyhydroxy compound. The preferred polar solvent is dimethylformamide. A miscible compound, such as, water or a polyhydroxy compound, is added to the polar extraction solvent to increase the polarity of the polar extraction solvent. The halogenated aliphatic and aromatic compounds are extracted from the highly-polarized mixture of water or polyhydroxy compound and polar extraction solvent into a low polar or nonpolar solvent by contacting the water or polyhydroxy compound-polar solvent mixture with the low polar or nonpolar solvent. The halogenated aliphatic and aromatic compounds and the low polar or nonpolar solvent are separated by physical means, e.g., vacuum evaporation. The polar and nonpolar solvents are recovered from recycling. The process can easily be designed for continuous operation. Advantages of the process include that the polar solvent and a major portion of the nonpolar solvent can be recycled, the petroleum products are reclaimable and the cost for disposing of waste containing polychlorinated biphenyls is significantly reduced.

  14. Process for removing halogenated aliphatic and aromatic compounds from petroleum products

    DOE Patents [OSTI]

    Googin, J.M.; Napier, J.M.; Travaglini, M.A.

    1983-09-20

    A process is described for removing halogenated aliphatic and aromatic compounds, e.g., polychlorinated biphenyls, from petroleum products by solvent extraction. The halogenated aliphatic and aromatic compounds are extracted from a petroleum product into a polar solvent by contacting the petroleum product with the polar solvent. The polar solvent is characterized by a high solubility for the extracted halogenated aliphatic and aromatic compounds, a low solubility for the petroleum product and considerable solvent power for polyhydroxy compound. The preferred polar solvent is dimethylformamide. A miscible compound, such as, water or a polyhydroxy compound, is added to the polar extraction solvent to increase the polarity of the polar extraction solvent. The halogenated aliphatic and aromatic compounds are extracted from the highly-polarized mixture of water or polyhydroxy compound and polar extraction solvent into a low polar or nonpolar solvent by contacting the water or polyhydroxy compound-polar solvent mixture with the low polar or nonpolar solvent. The halogenated aliphatic and aromatic compounds and the low polar or nonpolar solvent are separated by physical means, e.g., vacuum evaporation. The polar and nonpolar solvents are recovered from recycling. The process can easily be designed for continuous operation. Advantages of the process include that the polar solvent and a major portion of the nonpolar solvent can be recycled, the petroleum products are reclaimable and the cost for disposing of waste containing polychlorinated biphenyls is significantly reduced. 1 fig.

  15. Fusing porphyrins with polycyclic aromatic hydrocarbons and heterocycles for optoelectronic applications

    DOE Patents [OSTI]

    Thompson, Mark E.; Diev, Viacheslav; Hanson, Kenneth; Forrest, Stephen R.

    2015-08-18

    A compound that can be used as a donor material in organic photovoltaic devices comprising a non-activated porphyrin fused with one or more non-activated polycyclic aromatic rings or one or more non-activated heterocyclic rings can be obtained by a thermal fusion process. The compounds can include structures of Formula I: ##STR00001## By heating the reaction mixture of non-activated porphyrins with non-activated polycyclic aromatic rings or heterocyclic rings to a fusion temperature and holding for a predetermined time, fusion of one or more polycyclic rings or heterocyclic rings to the non-activated porphyrin core in meso,.beta. fashion is achieved resulting in hybrid structures containing a distorted porphyrin ring with annulated aromatic rings. The porphyrin core can be olygoporphyrins.

  16. Borehole SASW testing to evaluate log(G{sub max}) - log({sigma}{prime}) relationships in situ

    SciTech Connect (OSTI)

    Kalinski, M.E.; Stokoe, K.H. II; Young, Y.L.; Roesset, J.M.

    1999-07-01

    A new method is being developed for the in-situ measurement of shear wave velocity, V{sub s}, in the soil surrounding a borehole. The method involves the measurement of axially propagating surface waves inside an uncased borehole using the Spectral-Analysis-of-Surface-Waves (SASW) approach. Testing if performed with instrumentation housed inside an inflatable tool. Inflation pressures applied by the tool are used to vary radial stresses in the soil surrounding the borehole. Surface wave velocities over a range of frequencies are measured at each inflation pressure. These measurements are then theoretically modeled so that the variation in V{sub s} (an hence small-strain shear module, G{sub max}) with distance behind the borehole wall is determined at each pressure. The results of field tests with the borehole SASW tool at two sites composed of unsaturated clayey soil are presented. These results are compared with independent field seismic measurements and with laboratory tests on intact specimens using the torsional resonant column to assess the validity of the new field method.

  17. Bent Diamond Crystals and Multilayer Based Optics at the new 5-Station Protein Crystallography Beamline 'Cassiopeia' at MAX-lab

    SciTech Connect (OSTI)

    Mammen, Christian B.; Als-Nielsen, Jens; Ursby, Thomas; Thunnissen, Marjolein

    2004-05-12

    A new 5-station beamline for protein crystallography is being commissioned at the Swedish synchrotron light source MAX-II at Lund University. Of the 2K/{gamma} = 14 mrad horizontal wiggler fan, the central 2 mrad are used and split in three parts. The central 1 mrad will be used for a station optimized for MAD experiments and on each side of the central fan, from 0.5 mrad to 1 mrad, there are two fixed energy stations using different energies of the same part of the beam. These, in total five stations, can be used simultaneously and independently for diffraction data collection. The two upstream monochromators for the side stations are meridionally bent asymmetric diamond(111) crystals in Laue transmission geometry. The monochromators for the downstream side stations are bent Ge(111) crystals in asymmetric Bragg reflection geometry. Curved multilayer mirrors inserted in the monochromatic beams provide focusing in the vertical plane. The first side station is under commissioning, and a preliminary test protein data set has been collected.

  18. Alternative descriptions of catalyst deactivation in aromatization of propane and butane

    SciTech Connect (OSTI)

    Koshelev, Yu.N.; Vorob`ev, B.L.; Khvorova, E.P.

    1995-08-20

    Deactivation of a zeolite-containing catalyst has been studied in aromatization of propane and butane. Various descriptions of the dependence of the alkane conversion on the coke concentration on the catalyst have been considered, and using a statistical method of estimating the model validity, the most preferable form of the deactivation function has been proposed.

  19. Influence of temperature and process duration on composition of products of butane aromatization on zeolitic catalyst

    SciTech Connect (OSTI)

    Vorob`ev, B.L.; Trishin, P.Yu.; Koshelev, Yu.N.

    1995-06-10

    A study has been made of the influence of catalyst deactivation in the course of its service. The composition of products of butane aromatization on zeolitic catalyst and on selectivity of formation of target products and by-products is reported.

  20. Aromatic-Hydroxyl Interaction of a Lignin Model Compound on SBA-15, Present at Pyrolysis Temperatures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kandziolka, III, Michael V.; Kidder, Michelle; Gill, Lance W.; Wu, Zili; Savara, Aditya Ashi

    2014-07-14

    An aromatic alpha-aryl ether compound (a benzyl phenyl ether analogue) was covalently grafted to mesoporous silica SBA-15, to create BPEa-SBA-15. The BPEa-SBA-15 was subjected to successive heating cycles up to 600 °C, with in situ monitoring by DRIFTS. It was found that the toluene moiety coordinates to SBA-15 surface silanol hydroxyl groups via an aromatic–hydroxyl interaction. This interaction is evidenced by a red-shift of the aromatic C–H stretches, as well as a red-shift and broadening of the surface hydroxyl O–H stretches, which are features characteristic of a hydrogen bond. These features remain present during heating until ~400 °C whereupon themore » ether linkage of BPEa-SBA-15 is cleaved, accompanied by loss of the toluene moiety.« less

  1. Synthetic fuel aromaticity and staged combustion. First quarterly technical progress report, September 23-December 31, 1980

    SciTech Connect (OSTI)

    Levy, Arthur; Longanbach, James R.; Chan, Lisa K.

    1981-01-28

    Synthetic liquid fuels, otherwise referred to as synfuels or coal-derived liquids, are probably best characterized from a combustion-environmental point of view as low in hydrogen, low in sulfur, high in nitrogen, and high in aromatics. As a consequence two of the more critical problems in synfuel combustion are NO/sub x/ formation and soot formation (and polycyclic organic matter). This program is directed to these two issues. At first hand the solutions to burning synfuels high in aromatics and fuel-bound nitrogen are diametrically opposed, i.e., high temperature and excess air keep soot levels down, low temperatures and vitiated air keep nitrogen oxide levels down. Staged combustion however offers a logical solution to the above. This program separates and analyzes the synfuel combustion problem via its component parts and then puts them together again phenomenologically via the stage combustion process.

  2. X{sub max}{sup μ} vs. N{sup μ} from extensive air showers as estimator for the mass of primary UHECR's. Application for the Pierre Auger Observatory

    SciTech Connect (OSTI)

    Arsene, Nicusor; Sima, Octavian

    2015-02-24

    We study the possibility of primary mass estimation for Ultra High Energy Cosmic Rays (UHECR's) using the X{sub max}{sup μ} (the height where the number of muons produced on the core of Extensive Air Showers (EAS) is maximum) and the number N{sup μ} of muons detected on ground. We use the 2D distribution - X{sub max}{sup μ} against N{sup μ} in order to find its sensitivity to the mass of the primary particle. For that, we construct a 2D Probability Function Prob(p,Fe | X{sub max}{sup μ}, N{sup μ}) which estimates the probability that a certain point from the plane (X{sub max}{sup μ}, N{sup μ}) corresponds to a shower induced by a proton, respectively an iron nucleus. To test the procedure, we analyze a set of simulated EAS induced by protons and iron nuclei at energies of 10{sup 19}eV and 20° zenith angle with CORSIKA. Using the Bayesian approach and taking into account the geometry of the infill detectors from the Pierre Auger Observatory, we observe an improvement in the accuracy of the primary mass reconstruction in comparison with the results obtained using only the X{sub max}{sup μ} distributions.

  3. Flash Vacuum Pyrolysis of Lignin Model Compounds: Reaction Pathways of Aromatic Methoxy Groups

    SciTech Connect (OSTI)

    Britt, P.F.; Buchanan, A.C., III; Martineau, D.R.

    1999-03-21

    Currently, there is interest in utilizing lignin, a major constituent of biomass, as a renewable source of chemicals and fuels. High yields of liquid products can be obtained from the flash or fast pyrolysis of biomass, but the reaction pathways that lead to product formation are not understood. To provide insight into the primary reaction pathways under process relevant conditions, we are investigating the flash vacuum pyrolysis (FVP) of lignin model compounds at 500 C. This presentation will focus on the FVP of {beta}-ether linkages containing aromatic methoxy groups and the reaction pathways of methoxy-substituted phenoxy radicals.

  4. Process for removing halogenated aliphatic and aromatic compounds from petroleum products. [Polychlorinated biphenyls; methylene chloride; perchloroethylene; trichlorofluoroethane; trichloroethylene; chlorobenzene

    DOE Patents [OSTI]

    Googin, J.M.; Napier, J.M.; Travaglini, M.A.

    1982-03-31

    A process for removing halogenated aliphatic and aromatic compounds, e.g., polychlorinated biphenyls, from petroleum products by solvent extraction. The halogenated aliphatic and aromatic compounds are extracted from a petroleum product into a polar solvent by contracting the petroleum product with the polar solvent. The polar solvent is characterized by a high solubility for the extracted halogenated aliphatic and aromatic compounds, a low solubility for the petroleum product and considerable solvent power for polyhydroxy compound. The preferred polar solvent is dimethylformamide. A miscible polyhydroxy compound, such as, water, is added to the polar extraction solvent to increase the polarity of the polar extraction solvent. The halogenated aliphatic and aromatic compounds are extracted from the highly-polarized mixture of polyhydroxy compound and polar extraction solvent into a low polar or nonpolar solvent by contacting the polyhydroxy compound-polar solvent mixture with the low polar or nonpolar solvent. The halogenated aliphatic and aromatic compounds in the low polar or nonpolar solvent by physical means, e.g., vacuum evaporation. The polar and nonpolar solvents are recovered for recycling. The process can easily be designed for continuous operation. Advantages of the process include that the polar solvent and a major portion of the nonpolar solvent can be recycled, the petroleum products are reclaimable and the cost for disposing of waste containing polychlorinated biphenyls is significantly reduced. 2 tables.

  5. Measurement of the CP-Violating Phase beta_s in B0s -> J/Psi Phi Decays with the CDF II Detector

    SciTech Connect (OSTI)

    Aaltonen, T.; et al.

    2012-04-01

    We present a measurement of the \\CP-violating parameter \\betas using approximately 6500 $\\BsJpsiPhi$ decays reconstructed with the CDF\\,II detector in a sample of $p\\bar p$ collisions at $\\sqrt{s}=1.96$ TeV corresponding to 5.2 fb$^{-1}$ integrated luminosity produced by the Tevatron Collider at Fermilab. We find the \\CP-violating phase to be within the range $\\betas \\in [0.02, 0.52] \\cup [1.08, 1.55]$ at 68% confidence level where the coverage property of the quoted interval is guaranteed using a frequentist statistical analysis. This result is in agreement with the standard model expectation at the level of about one Gaussian standard deviation. We consider the inclusion of a potential $S$-wave contribution to the $\\Bs\\to J/\\psi K^+K^-$ final state which is found to be negligible over the mass interval $1.009 < m(K^+K^-)<1.028 \\gevcc$. Assuming the standard model prediction for the \\CP-violating phase \\betas, we find the \\Bs decay width difference to be $\\deltaG = 0.075 \\pm 0.035\\,\\textrm{(stat)} \\pm 0.006\\,\\textrm{(syst)} \\ps$. We also present the most precise measurements of the \\Bs mean lifetime $\\tau(\\Bs) = 1.529 \\pm 0.025\\,\\textrm{(stat)} \\pm 0.012\\,\\textrm{(syst)}$ ps, the polarization fractions $|A_0(0)|^2 = 0.524 \\pm 0.013\\,\\textrm{(stat)} \\pm 0.015\\,\\textrm{(syst)}$ and $|A_{\\parallel}(0)|^2 = 0.231 \\pm 0.014\\,\\textrm{(stat)} \\pm 0.015\\,\\textrm{(syst)}$, as well as the strong phase $\\delta_{\\perp}= 2.95 \\pm 0.64\\,\\textrm{(stat)} \\pm 0.07\\,\\textrm{(syst)} \\textrm{rad}$. In addition, we report an alternative Bayesian analysis that gives results consistent with the frequentist approach.

  6. A study on the coagulation of polycyclic aromatic hydrocarbon clusters to determine their collision efficiency

    SciTech Connect (OSTI)

    Raj, Abhijeet; Sander, Markus; Janardhanan, Vinod; Kraft, Markus [Department of Chemical Engineering and Biotechnology, University of Cambridge, New Museums Site, Pembroke Street, Cambridge CB2 3RA (United Kingdom)

    2010-03-15

    This paper presents a theoretical study on the physical interaction between polycyclic aromatic hydrocarbons (PAHs) and their clusters of different sizes in laminar premixed flames. Two models are employed for this study: a detailed PAH growth model, referred to as the kinetic Monte Carlo - aromatic site (KMC-ARS) model [Raj et al., Combust. Flame 156 (2009) 896-913]; and a multivariate PAH population balance model, referred to as the PAH - primary particle (PAH-PP) model. Both the models are solved by kinetic Monte Carlo methods. PAH mass spectra are generated using the PAH-PP model, and compared to the experimentally observed spectra for a laminar premixed ethylene flame. The position of the maxima of PAH dimers in the spectra and their concentrations are found to depend strongly on the collision efficiency of PAH coagulation. The variation in the collision efficiency with various flame and PAH parameters is studied to determine the factors on which it may depend. A correlation for the collision efficiency is proposed by comparing the computed and the observed spectra for an ethylene flame. With this correlation, a good agreement between the computed and the observed spectra for a number of laminar premixed ethylene flames is found. (author)

  7. Enhancing muconic acid production from glucose and lignin-derived aromatic compounds via increased protocatechuate decarboxylase activity

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Johnson, Christopher W.; Salvachua, Davinia; Khanna, Payal; Smith, Holly; Peterson, Darren J.; Beckham, Gregg T.

    2016-04-22

    The conversion of biomass-derived sugars and aromatic molecules to cis,cis-muconic acid (referred to hereafter as muconic acid or muconate) has been of recent interest owing to its facile conversion to adipic acid, an important commodity chemical. Metabolic routes to produce muconate from both sugars and many lignin-derived aromatic compounds require the use of a decarboxylase to convert protocatechuate (PCA, 3,4-dihydroxybenzoate) to catechol (1,2-dihydroxybenzene), two central aromatic intermediates in this pathway. Several studies have identified the PCA decarboxylase as a metabolic bottleneck, causing an accumulation of PCA that subsequently reduces muconate production. A recent study showed that activity of the PCAmore » decarboxylase is enhanced by co-expression of two genetically associated proteins, one of which likely produces a flavin-derived cofactor utilized by the decarboxylase. Using entirely genome-integrated gene expression, we have engineered Pseudomonas putida KT2440-derived strains to produce muconate from either aromatic molecules or sugars and demonstrate in both cases that co-expression of these decarboxylase associated proteins reduces PCA accumulation and enhances muconate production relative to strains expressing the PCA decarboxylase alone. In bioreactor experiments, co-expression increased the specific productivity (mg/g cells/h) of muconate from the aromatic lignin monomer p-coumarate by 50% and resulted in a titer of >15 g/L. In strains engineered to produce muconate from glucose, co-expression more than tripled the titer, yield, productivity, and specific productivity, with the best strain producing 4.92+/-0.48 g/L muconate. Furthermore, this study demonstrates that overcoming the PCA decarboxylase bottleneck can increase muconate yields from biomass-derived sugars and aromatic molecules in industrially relevant strains and cultivation conditions.« less

  8. Determination of the Average Aromatic Cluster Size of Fossil Fuels by Solid-State NMR at High Magnetic Field

    SciTech Connect (OSTI)

    Mao, Kanmi; Kennedy, Gordon J.; Althaus, Stacey M.; Pruski, Marek

    2013-01-07

    We show that the average aromatic cluster size in complex carbonaceous materials can be accurately determined using fast magic-angle spinning (MAS) NMR at a high magnetic field. To accurately quantify the nonprotonated aromatic carbon, we edited the 13C spectra using the recently reported MAS-synchronized spinecho, which alleviated the problem of rotational recoupling of 1H-13C dipolar interactions associated with traditional dipolar dephasing experiments. The dependability of this approach was demonstrated on selected Argonne Premium coal standards, for which full sets of basic structural parameters were determined with high accuracy.

  9. Compounds having aromatic rings and side-chain amide-functionality and a method for transporting monovalent anions across biological membranes using the same

    DOE Patents [OSTI]

    Davis, Jeffery T.; Sidorov, Vladimir; Kotch, Frank W.

    2008-04-08

    A compound containing at least two aromatic rings covalently bonded together, with each aromatic ring containing at least one oxyacetamide-based side chain, the compound being capable of forming a chloride ion channel across a lipid bilayer, and transporting chloride ion across the lipid bilayer.

  10. Rendering graphene supports hydrophilic with non-covalent aromatic functionalization for transmission electron microscopy

    SciTech Connect (OSTI)

    Pantelic, Radosav S., E-mail: pantelic@imbb.forth.gr [National Cancer Institute, 50 South Drive, Building 50, Room 4306, Bethesda, Maryland 20892 (United States); Fu, Wangyang; Schoenenberger, Christian [Department of Physics, University of Basel, Klingelbergstrasse 82, Basel CH-4056 (Switzerland); Stahlberg, Henning [Center for Cellular Imaging and NanoAnalytics, Biozentrum, University of Basel, Mattenstrasse 26, WRO-1058, Basel CH-4058 (Switzerland)

    2014-03-31

    Amorphous carbon films have been routinely used to enhance the preparation of frozen-hydrated samples for transmission electron microscopy (TEM), either in retaining protein concentration, providing mechanical stability or dissipating sample charge. However, strong background signal from the amorphous carbon support obstructs that of the sample, and the insulating properties of thin amorphous carbon films preclude any efficiency in dispersing charge. Graphene addresses the limitations of amorphous carbon. Graphene is a crystalline material with virtually no phase or amplitude contrast and unparalleled, high electrical carrier mobility. However, the hydrophobic properties of graphene have prevented its routine application in Cryo-TEM. This Letter reports a method for rendering graphene TEM supports hydrophilica convenient approach maintaining graphene's structural and electrical properties based on non-covalent, aromatic functionalization.

  11. Measurement of polycyclic aromatic hydrocarbons in the air along the niagara river

    SciTech Connect (OSTI)

    Hoff, R.M.; Chan, K.W.

    1987-06-01

    Two week-long studies in 1982-1983 have measure ambient concentrations of polycyclic aromatic hydrocarbons (PAH) and phthalate esters in air in both the particulate and gas phase along the US-Canadian border and the Niagara River. Concentrations of the PAH species monitored varied from 3 pg m/sup -3/ to 40 ng m/sup -3/. PAH's with three rings or less were found in significant proportions in the gas phase while larger molecules are almost solely in the particulate phase. Particulate components of the PAH loadings appear to originate locally with Buffalo, NY, Niagara Falls, NY, and Niagara Falls, Ontario, as probably sources. Gas-phase PAH components have a more regional character indicating regional or long-range transport. Levels of benzo(a)pyrene are consistent with previous particulate measurements made along the river since 1981.

  12. Air pollution from a large steel factory: polycyclic aromatic hydrocarbon emissions from coke-oven batteries

    SciTech Connect (OSTI)

    Lorenzo Liberti; Michele Notarnicola; Roberto Primerano; Paolo Zannetti

    2006-03-15

    A systematic investigation of solid and gaseous atmospheric emissions from some coke-oven batteries of one of Europe's largest integrated steel factory (Taranto, Italy) has been carried out. These emissions, predominantly diffuse, originate from oven leakages, as well as from cyclic operations of coal loading and coke unloading. In air monitoring samples, polycyclic aromatic hydrocarbons (PAHs) were consistently detected at concentrations largely exceeding threshold limit values. By means of PAHs speciation profile and benzo-(a)pyrene (BaP) equivalent dispersion modeling from diffuse sources, the study indicated that serious health risks exist not only in working areas, but also in a densely populated residential district near the factory. 30 refs., 5 figs., 3 tabs.

  13. Aromatic carboxylate effect on dimensionality of three bis(benzimidazole)-based cobalt(II) coordination polymers: Syntheses, structures and properties

    SciTech Connect (OSTI)

    Zhang, Ju-Wen; Gong, Chun-Hua; Hou, Li-Li; Tian, Ai-Xiang; Wang, Xiu-Li

    2013-09-15

    Three new metal-organic coordination polymers [Co(4-bbc){sub 2}(bbbm)] (1), [Co(3,5-pdc)(bbbm)]·2H{sub 2}O (2) and [Co(1,4-ndc)(bbbm)] (3) (4-Hbbc=4-bromobenzoic acid, 3,5-H{sub 2}pdc=3,5-pyridinedicarboxylic acid, 1,4-H{sub 2}ndc=1,4-naphthalenedicarboxylic acid and bbbm=1,1-(1,4-butanediyl)bis-1H-benzimidazole) were hydrothermally synthesized and structurally characterized. Polymer 1 is a 1D chain formed by the bbbm ligands and Co{sup II} ions. Polymer 2 exhibits a 2D network with a (3·4·5)(3{sup 2}·4·5·6{sup 2}·7{sup 4}) topology. Polymer 3 possesses a 3D three-fold interpenetrating framework. The versatile structures of title polymers indicate that the aromatic carboxylates have an important influence on the dimensionality of 1–3. Moreover, the thermal stability, electrochemical and luminescent properties of 1–3 were investigated. - graphical abstract: Three bis(benzimidazole)-based cobalt(II) coordination polymers tuned by aromatic carboxylates were hydrothermally synthesized and structurally characterized. The aromatic carboxylates play a key role in the dimensionality of three polymers. The electrochemical and luminescent properties of three polymers were investigated. Display Omitted - Highlights: • Three bis(benzimidazole)-based cobalt(II) coordination polymers tuned by aromatic carboxylates were obtained. • The aromatic carboxylates have an important influence on the dimensionality of three polymers. • The electrochemical and luminescent properties of three polymers were investigated.

  14. Measurement of the \\textit{CP} Violating Phase $\\boldsymbol{\\sin(2\\beta_{s})}$ using $\\boldsymbol{B^{0}_{s}\\rightarrow J/\\psi\\phi}$ Decays at CDF

    SciTech Connect (OSTI)

    Pueschel, Elisa; /Carnegie Mellon U.

    2010-05-01

    A B{sub s}{sup 0} meson can oscillate into its anti-particle, the {bar B}{sub s}{sup 0} meson, before decaying. CP violation in this system is made possible by the presence of amplitudes from both mixed and unmixed B{sub s}{sup 0} meson decays. The CP violating phase {beta}s appears in the interference between the decay amplitudes. The quantity sin(2{beta}s) is expected to be small in the standard model. Thus, measuring a large value for sin(2{beta}s) would be an unequivocal sign of new physics participation in the B{sub s}{sup 0} mixing loop diagram. In this thesis, we present a latest measurement of sin(2{beta}s), using 5.2 fb{sup -1} of data collected at CDF from p{bar p} collisions at a center of mass energy of {radical}s = 1.96 TeV. A time-dependent angular analysis, with the production flavor of the B{sub s}{sup 0} meson identified with flavor tagging methods, is used to extract sin(2{beta}s) from {approx}6500 B{sub s}{sup 0} {yields} J/{psi}{phi} decays. Other parameters of interest, such as the B{sub s}{sup 0} lifetime and the decay width difference {Delta}{Lambda} between the heavy and light B{sub s}{sup 0} mass eigenstates are determined to high precision. Also, the effect of potential contributions to the final state from B{sub s}{sup 0} {yields} J/{psi}f{sub 0} and B{sub s}{sup 0} {yields} J/{psi}K{sup +}K{sup -} decays is considered for the first time. We present 68% and 95% confidence regions in the {beta}s - {Delta}{Lambda} plane. The probability that the observed central value is a fluctuation of the data from the standard model expected value of {beta}s is calculated to be 44%. The observed confidence region shows better agreement with the standard model prediction than previous measurements.

  15. Grating light reflection spectroelectrochemistry for detection of trace amounts of aromatic hydrocarbons in water

    SciTech Connect (OSTI)

    KELLY,MICHAEL J.; SWEATT,WILLIAM C.; KEMME,SHANALYN A.; KASUNIC,K.J.; BLAIR,DIANNA S.; ZAIDI,S.H.; MCNEIL,J.R.; BURGESS,L.W.; BRODSKY,A.M.; SMITH,S.A.

    2000-04-01

    Grating light reflection spectroscopy (GLRS) is an emerging technique for spectroscopic analysis and sensing. A transmission diffraction grating is placed in contact with the sample to be analyzed, and an incident light beam is directed onto the grating. At certain angles of incidence, some of the diffracted orders are transformed from traveling waves to evanescent waves. This occurs at a specific wavelength that is a function of the grating period and the complex index of refraction of the sample. The intensities of diffracted orders are also dependent on the sample's complex index of refraction. The authors describe the use of GLRS, in combination with electrochemical modulation of the grating, for the detection of trace amounts of aromatic hydrocarbons. The diffraction grating consisted of chromium lines on a fused silica substrate. The depth of the grating lines was 1 {micro}m, the grating period was 1 {micro}m, and the duty cycle was 50%. Since chromium was not suitable for electrochemical modulation of the analyte concentration, a 200 nm gold layer was deposited over the entire grating. This gold layer slightly degraded the transmission of the grating, but provided satisfactory optical transparency for the spectroelectrochemical experiments. The grating was configured as the working electrode in an electrochemical cell containing water plus trace amounts of the aromatic hydrocarbon analytes. The grating was then electrochemically modulated via cyclic voltammetry waveforms, and the normalized intensity of the zero order reflection was simultaneously measured. The authors discuss the lower limits of detection (LLD) for two analytes, 7-dimethylamino-1,2-benzophenoxazine (Meldola's Blue dye) and 2,4,6-trinitrotoluene (TNT), probed with an incident HeNe laser beam ({lambda} = 543.5 nm) at an incident angle of 52.5{degree}. The LLD for 7-dimethylamino-1,2-benzophenoxazine is approximately 50 parts per billion (ppb), while the LLD for TNT is approximately 50 parts per million (ppm). The possible factors contributing to the differences in LLD for these analytes are discussed. This is the final report for a Sandia National Laboratories Laboratory Directed Research and Development (LDRD) project conducted during fiscal years 1998 and 1999 (case number 3518.190).

  16. Gas-phase reactions of polycyclic aromatic hydrocarbon cations and their nitrogen-containing analogs with H atoms

    SciTech Connect (OSTI)

    Demarais, Nicholas J.; Yang, Zhibo; Bierbaum, Veronica M. [Department of Chemistry and Biochemistry, 215 UCB, University of Colorado, Boulder, CO 80309-0215 (United States); Snow, Theodore P., E-mail: Nicholas.Demarais@Colorado.edu, E-mail: Zhibo.Yang@ou.edu, E-mail: Veronica.Bierbaum@Colorado.edu, E-mail: Theodore.Snow@Colorado.edu [Center for Astrophysics and Space Astronomy, 389 UCB, University of Colorado, Boulder, CO 80309-0389 (United States)

    2014-03-20

    We have studied the reactions of polycyclic aromatic hydrocarbon cations and their nitrogen-containing analogs with H atoms. Reaction rate constants are measured at 300 K using a flowing afterglow-selected ion flow tube. We have implemented the laser induced acoustic desorption technique to allow the study of large, non-volatile species in the gas phase. The extension of this work from previous studies shows that the reactivity of polycyclic aromatic hydrocarbon cations with H atoms reaches a constant value for large cations. There is a small difference in reactivity when comparing molecules of different size and geometry; however, no difference in reactivity was found when nitrogen was incorporated into the ring.

  17. Variations in the structure of aromatic solvents under the influence of microadditives of the C{sub 60} fullerene

    SciTech Connect (OSTI)

    Ginzburg, B. M. Tuichiev, Sh.

    2007-02-15

    The structural ordering of aromatic solvents is investigated using wide-angle X-ray diffraction. It is shown that the degree of structural ordering of aromatic solvents at room temperature decreases in the following sequence: benzene, toluene, and n-xylene. The introduction of the C{sub 60} fullerene ({approx}0.001%) into these solvents leads to an increase in the degree of their ordering. Upon introduction of the fullerene, the degree of structural ordering increases significantly in n-xylene and only slightly in toluene and remains virtually unchanged in benzene. An analysis of the small-angle X-ray diffraction patterns of C{sub 60} fullerene solutions in benzene likewise demonstrates that the introduction of the fullerene into benzene leads to an insignificant change in the degree of structural ordering of this solvent. The specific features of the structure and behavior of benzene upon interaction with C{sub 60} fullerene additives are discussed.

  18. Applications of organo-calcium chemistry to control contaminant aromatic hydrocarbons in advanced coal gasification processes: Final technical progress report

    SciTech Connect (OSTI)

    Longwall, J.P.; Chang, C.C.S.; Lai, C.K.S.; Chen, P.; Hajaligol, M.R.; Peters, W.A.

    1988-09-01

    The broad goal of this contract was to provide quantitative understanding of the thermal reactions of aromatics contaminants with calcium oxide under conditions pertinent to their in situ or out-board reduction or elimination from advanced coal gasification process and waste streams. Specific objectives were formalized into the following four tasks: cracking of fresh coal pyrolysis tar, benzene cracking, CaO deactivation behavior, and preliminary economic implications. The approach primarily involved laboratory scale measurements of rates and extents of feed conversion, and of quality indices or compositions of the resulting products, when pure aromatic compounds or newly formed coal pyrolysis tars undergo controlled extents of thermal treatment with CaO of known preparation history. 70 refs., 54 figs., 7 tabs.

  19. Linkages and aromatic clusters in a bituminous coal: Final report, September 1, 1985--September 30, 1988

    SciTech Connect (OSTI)

    Chung, K.E.

    1988-10-01

    The distribution and arrangement of aromatic clusters, oxygen functional groups, and linkages in an Illinois No. 6 bituminous coal were determined by controlled solubilization of the coal, followed by solvent fractionation of the soluble product and detailed analyses of the product fractions. The solubilization was carried out in reactions with NaOH/ethanol/H/sub 2/O at temperatures of 260/degree/, 300/degree/ and 320/degree/C. Elemental balance and spectroscopic data revealed that the oxygen functional groups of the coal were attacked selectively in the solubilization process, resulting in an orderly definable diminution of the complex coal structure. Also aliphatic linkages present in selected solubilized product fractions were subjected to a transalkylation reaction. A molecular structural model specific to the Illinois coal was constructed, and the hydroliquefaction behavior of the coal was evaluated in terms of potential product distribution and hydrogen consumption. The structural characteristics are compared with those of a Wyoming subbituminous coal in our previous study. 9 refs., 16 figs., 11 tabs.

  20. Field application of a genetically engineered microorganism for polycyclic aromatic hydrocarbon bioremediation process monitoring and control

    SciTech Connect (OSTI)

    Sayler, G.S.; Cox, C.D.; Ripp, S.; Nivens, D.E.; Werner, C.; Ahn, Y.; Matrubutham, U.; Burlage, R.

    1998-11-01

    On October 30, 1996, the US Environmental Protection Agency (EPA) commenced the first test release of genetically engineered microorganisms (GEMs) for use in bioremediation. The specific objectives of the investigation were multifaceted and include (1) testing the hypothesis that a GEM can be successfully introduced and maintained in a bioremediation process, (2) testing the concept of using, at the field scale, reporter organisms for direct bioremediation process monitoring and control, and (3) acquiring data that can be used in risk assessment decision making and protocol development for future field release applications of GEMs. The genetically engineered strain under investigation is Pseudomonas fluorescens strain HK44 (King et al., 1990). The original P. fluorescens parent strain was isolated from polycyclic aromatic hydrocarbon (PAH) contaminated manufactured gas plant soil. Thus, this bacterium is able to biodegrade naphthalene (as well as other substituted naphthalenes and other PAHs) and is able to function as a living bioluminescent reporter for the presence of naphthalene contamination, its bioavailability, and the functional process of biodegradation. A unique component of this field investigation was the availability of an array of large subsurface soil lysimeters. This article describes the experience associated with the release of a genetically modified microorganism, the lysimeter facility and its associated instrumentation, as well as representative data collected during the first eighteen months of operation.

  1. Polycyclic aromatic hydrocarbons in surface waters of Alessandria District, South Eastern Piedmont (Italy)

    SciTech Connect (OSTI)

    Trova, C.; Cossa, G.; Gandolfo, G.

    1992-10-01

    Polynuclear aromatic hydrocarbons (PAHs) are ubiquitous environmental pollutants. Because of the high toxicity of some polycyclic compounds, such as benzopyrenes, the determination of their levels in air, water, soil and aquatic organisms was the object of several papers. Anthropogenic pyrolitic and combustion processes, related to industrial plants, domestic heating, automobile traffic, are the major sources of these compounds; from these sources they enter atmospheric environment where their concentration is reduced by scavenging during precipitation events: rain, snow and fog in urban areas usually show high contents of PAHs. Dry and wet atmospheric polluted depositions effluents transport appreciable amounts of PAHs to aquatic environment, where they are rapidly taken up and accumulated by both fish and shellfish. Alessandria District, in South-Eastern Piedmont (Italy), lies in the middle of Torino-Milano-Genova industrial area: in addition to local sources, a relatively long range transport of polluted air masses may conduct to this region atmospheric contaminants, such as polynuclear compounds, that can enter fluvial environments through meteoric precipitation. The object of this work was to evaluate PAH content in surface waters flowing across the described territory. Samplings were carried on during winter season, when the concentration of these pollutants usually reaches the highest levels. 8 refs., 4 figs., 2 tabs.

  2. Anaerobic cometabolic transformation of polycyclic and heterocyclic aromatic hydrocarbons: evidence from laboratory and field studies

    SciTech Connect (OSTI)

    Michael Safinowski; Christian Griebler; Rainer U. Meckenstock

    2006-07-01

    The sulfate-reducing enrichment culture N47 can grow on naphthalene or 2-methylnaphthalene as the sole carbon and energy source. The study reported shows that the culture can furthermore cometabolically transform a variety of polycyclic and heteroaromatic compounds with naphthalene or methylnaphthalene as the auxiliary substrate. Most of the cosubstrates were converted to the corresponding carboxylic acids, frequently to several isomers. The mass spectra of specific metabolites that were extracted from supernatants of cultures containing the cosubstrates benzothiophene, benzofuran, and 1-methylnaphthalene resembled known intermediates of the anaerobic naphthalene and 2-methylnaphthalene degradation pathways. This indicates that some of the tested compounds were first methylated and then transformed to the corresponding methylsuccinic acids by a fumarate addition to the methyl group. For some of the cosubstrates, a partial or total inhibition of growth on the auxiliary substrate was observed. This was caused by a specific combination of auxiliary substrate and cosubstrate. None of the cosubstrates tested could be utilized as the sole carbon source and electron donor by the enrichment culture N47. Field investigations at the tar-oil-contaminated aquifer (at a former gasworks in southwest Germany), where strain N47 originated, revealed the presence of metabolites similar to the ones identified in batch culture supernatants. The findings suggest that aromatic hydrocarbons and heterocyclic compounds can be converted by aquifer organisms and produce a variety of polar compounds that become mobile in groundwater. 51 refs., 4 figs., 2 tabs.

  3. PAMAM dendrimers and graphene: Materials for removing aromatic contaminants from water

    SciTech Connect (OSTI)

    DeFever, Ryan S.; Geitner, Nicholas K.; Bhattacharya, Priyanka; Ding, Feng; Ke, Pu Chun; Sarupria, Sapna

    2015-04-07

    We present results from experiments and atomistic molecular dynamics simulations on the association of naphthalene with polyamidoamine (PAMAM) dendrimers and graphene oxide (GrO). Specifically, we investigate 3rd-6th generation (G3-G6) PAMAM dendrimers and GrO with different levels of oxidation. The work is motivated by the potential applications of these materials in removing polycyclic aromatic hydrocarbon contaminants from water. Our experimental results indicate that graphene oxide outperforms dendrimers in removing naphthalene from water. Molecular dynamics simulations suggest that the prominent factors driving naphthalene association to these seemingly disparate materials are similar. Interestingly, we find that cooperative interactions between the naphthalene molecules play a significant role in enhancing their association to the dendrimers and graphene oxide. Our findings highlight that while selection of appropriate materials is important, the interactions between the contaminants themselves can also be important in governing the effectiveness of a given material. The combined use of experiments and molecular dynamics simulations allows us to comment on the possible factors resulting in better performance of graphene oxide in removing naphthalene from water.

  4. Separation, characterization and instrumental analysis of polynuclear aromatic hydrocarbon ring classes in petroleum

    SciTech Connect (OSTI)

    Chmielowiec, J.; Beshai, J.E.; George, A.E.

    1980-08-01

    To develop effective utilization technology for heavy streams from conventional fuels and unconventional resources such as heavy oils and oilsand bitumens, detailed information on the chemical composition of the feedstocks is needed. Attempts were made during the seventies to modify the API Project 60 scheme of analysis or to develop chemically more efficient, and less time-consuming, separation and characterization methods. These attempts aimed to improve characterization by separating the samples into concentrates of different structural types. Samples throughput was increased by using pressure and higher performance chromatographic systems. Other valuable contributions, such as coal-liquid characterization in terms of different chemical functionalities have also been made. The separation of aromatic ring classes and characterization or identification of their major components was our primary objective in this study. A silica-R(NH/sub 2/)/sub 2/-based HPLC system was used in our laboratory to study the analytical potential of this approach; the work was described in a previous publication. In the present study, the applicability of HPLC separation by this system and instrumental spectrometric characterization of 3- and 4-ring PAHs isolated from two Canadian oils were investigated. The oils used, Medicine River and Lloydminster, are examples of hydrocarbon-dominated materials representing light and heavy processing feedstocks, respectively.

  5. In situ toxicity evaluations of turbidity and photoinduction of polycyclic aromatic hydrocarbons

    SciTech Connect (OSTI)

    Ireland, D.S.; Burton, G.A. Jr; Hess, G.G.

    1996-04-01

    Polycyclic aromatic hydrocarbons (PAHs) are prevalent pollutants in the aquatic environment that can cause a wide range of toxic effects. Earlier studies have shown that toxicity of PAHs can be enhanced by ultraviolet (UV) radiation. In situ and laboratory exposures with Ceriodaphnia dubia were used to evaluate photoinduced toxicity of PAHs in wet-weather runoff and in turbid conditions. Exposure to UV increased the toxicity of PAH-contaminated sediment to C. dubia. Toxicity was removed when UV wavelengths did not penetrate the water column to the exposed organisms. A significant correlation was observed between in situ C. dubia survival and turbidity when organisms were exposed to sunlight. Stormwater runoff samples exhibited an increase in chronic toxicity (reproduction) to C. dubia when exposed to UV wavelengths as compared to C. dubia not exposed to UV wavelengths. Toxicity was reduced significantly in the presence of UV radiation when the organic fraction of stormwater runoff was removed. The PAHs are bound to the sediment and resuspended into the water column once the sediment is disturbed (e.g., during a storm). The in situ and laboratory results showed that photoinduced toxicity occurred frequently during low flow conditions and wet weather runoff and was reduced in turbid conditions.

  6. Use of SPMDs to determine average water concentration of polycyclic aromatic hydrocarbons in urban stormwater runoff

    SciTech Connect (OSTI)

    DeVita, W.; Crunkilton, R.

    1995-12-31

    Semipermeable polymeric membrane devices (SPMDS) were deployed for 30 day periods to monitor polycyclic aromatic hydrocarbons (PAHs) in an urban stream which receives much of its flow from urban runoff. SPMDs are capable of effectively sampling several liters of water per day for some PAHs. Unlike conventional methods, SPMDs sample only those non-polar organic contaminants which are truly dissolved and available for bioconcentration. Also, SPMDs may concentrate contaminants from episodic events such as stormwater discharge. The State of Wisconsin has established surface water quality criteria based upon human lifetime cancer risk of 23 ppt for benzo(a)pyrene and 23 ppt as the sum of nine other potentially carcinogenic PAHs. Bulk water samples analyzed by conventional methodology were routinely well above this criteria, but contained particulate bound PAHs as well as PAHs bound by dissolved organic carbon (DOC) which are not available for bioconcentration. Average water concentrations of dissolved PAHs determined using SPMDs were also above this criteria. Variables used for determining water concentration included sampling rate at the exposure temperature, length of exposure and estimation of biofouling of SPMD surface.

  7. Polycyclic aromatic hydrocarbons at selected burning grounds at Los Alamos National Laboratory

    SciTech Connect (OSTI)

    Harris, B.W.; Minor, L.K.M.; Flucas, B.J.

    1998-02-01

    A commercial immunoassay field test (IFT) was used to rapidly assess the total concentrations of polycyclic aromatic hydrocarbons (PAHs) in the soil at selected burning grounds within the explosives corridor at Los Alamos National Laboratory (LANL). Results were compared with analyses obtained from LANL Analytical Laboratory and from a commercial laboratory. Both used the Environmental Protection Agency`s (EPA`s) Methods 8270 and 8310. EPA`s Method 8270 employs gas chromatography and mass spectral analyses, whereas EPA`s Method 8310 uses an ultraviolet detector in a high-performance liquid chromatography procedure. One crude oil sample and one diesel fuel sample, analyzed by EPA Method 8270, were included for references. On an average the IFT results were lower for standard samples and lower than the analytical laboratory results for the unknown samples. Sites were selected to determine whether the PAHs came from the material burned or the fuel used to ignite the burn, or whether they are produced by a high-temperature chemical reaction during the burn. Even though the crude oil and diesel fuel samples did contain measurable quantities of PAHs, there were no significant concentrations of PAHs detected in the ashes and soil at the burning grounds. Tests were made on fresh soil and ashes collected after a large burn and on aged soil and ashes known to have been at the site more than three years. Also analyzed were twelve-year-old samples from an inactive open burn cage.

  8. Mechanisms of photoinduced C{sub {alpha}}-C{sub {beta}} bond breakage in protonated aromatic amino acids

    SciTech Connect (OSTI)

    Lucas, B.; Barat, M.; Fayeton, J. A.; Perot, M.; Jouvet, C.; Gregoire, G.; Broendsted Nielsen, S.

    2008-04-28

    Photoexcitation of protonated aromatic amino acids leads to C{sub {alpha}}-C{sub {beta}} bond breakage among other channels. There are two pathways for the C{sub {alpha}}-C{sub {beta}} bond breakage, one is a slow process (microseconds) that occurs after hydrogen loss from the electronically excited ion, whereas the other is a fast process (nanoseconds). In this paper, a comparative study of the fragmentation of four molecules shows that the presence of the carboxylic acid group is necessary for this fast fragmentation channel to occur. We suggest a mechanism based on light-induced electron transfer from the aromatic ring to the carboxylic acid, followed by a fast internal proton transfer from the ammonium group to the negatively charged carboxylic acid group. The ion formed is a biradical since the aromatic ring is ionized and the carbon of the COOH group has an unpaired electron. Breakage of the weak C{sub {alpha}}-C{sub {beta}} bond gives two even-electron fragments and is expected to quickly occur. The present experimental results together with the ab initio calculations support the interpretation previously proposed.

  9. Trends in polycyclic aromatic hydrocarbon concentrations in the Great Lakes atmosphere

    SciTech Connect (OSTI)

    Ping Sun; Pierrette Blanchard; Kenneth A. Brice; Ronald A. Hites

    2006-10-15

    Atmospheric polycyclic aromatic hydrocarbon (PAHs) concentrations were measured in both the vapor and particle phases at seven sites near the Great Lakes as a part of the Integrated Atmospheric Deposition Network. Lower molecular weight PAHs, including fluorene, phenanthrene, fluoranthrene, and pyrene, were dominant in the vapor phase, and higher molecular weight PAHs, including chrysene, benzo(a)pyrene, and coronene, were dominant in the particle phase. The highest PAH concentrations in both the vapor and particle phases were observed in Chicago followed by the semiurban site at Sturgeon Point, NY. The major sources of PAHs in and around Chicago are vehicle emissions, coal and natural gas combustion, and coke production. The spatial difference of PAH concentrations can be explained by the local population density. Long-term decreasing trends of most PAH concentrations were observed in both the vapor and particle phases at Chicago, with half-lives ranging from 3-10 years in the vapor phase and 5-15 years in the particle phase. At Eagle Harbor, Sleeping Bear Dunes, and Sturgeon Point, total PAH concentrations in the vapor phase showed significant, but slow, long-term decreasing trends. At the Sturgeon Point site, which was impacted by a nearby city, particle-phase PAH concentrations also declined. However, most particle-phase PAH concentrations did not show significant long-term decreasing trends at the remote sites. Seasonal trends were also observed for particle-phase PAH concentrations, which were higher in the winter and lower in the summer. 36 refs., 4 figs., 1 tab.

  10. Polycyclic aromatic hydrocarbons in fresh and smoked fish samples from three Nigerian cities

    SciTech Connect (OSTI)

    Akpan, V.; Lodovici, M.; Dolara, P. )

    1994-08-01

    Nigeria is a major producer of crude oil in sub-Saharan Africa. In-shore and off-shore wells are located in richly watered creeks in the southern part of the country. Although published data on environmental impact assessment of the petroleum industry in Nigeria are lacking, there is a growing concern about the possible contamination of estuarine and coastal waters and of marine species by polycyclic aromatic hydrocarbon (PAHs). PAHs are ubiquitous priority pollutants that occur naturally in crude oil, automobile exhaust emissions and smoke condensates from incomplete combustion of carbonaceous materials. PAHs with high molecular weight are less readily biodegraded by indigenous microorganisms in some regions, and given their marked hydrophobic characteristics, may persist in the aqueous environment, thus contaminating the food chain by bioaccumulating in aquatic species like fish and mussels. Major Nigerian oil wells are located in the vicinity of breeding and harvesting sites serving the fresh-water fishing industry. Large hauls of fresh fish are normally consumed cooked in soups or smoke cured in handcrafted traditional ovens using freshly cut red mangrove (Rhizophora racemosa) wood as fuel. Though smoke curing is economical and may ensure longer conservation of fish, it undoubtedly increases the burden of PAHs in finished products as a result of partial charring and from smoke condensates or mangroves that also contain PAHs in measurable quantities as reported by Asita et al. (1991). Apart from PAHs analyzed by Emerole (1980) in smoked food samples from Ibadan using simple analytical methods, those from industrial and other anthropogenic sources have rarely been analyzed in Nigeria. We tried therefore to update the data and address this discrepancy. 14 refs., 4 figs., 2 tabs.

  11. Polycyclic aromatic hydrocarbon and mid-infrared continuum emission in a z > 4 submillimeter galaxy

    SciTech Connect (OSTI)

    Riechers, Dominik A.; Pope, Alexandra; Daddi, Emanuele; Elbaz, David; Carilli, Christopher L.; Walter, Fabian; Hodge, Jacqueline; Morrison, Glenn E.; Dickinson, Mark; Dannerbauer, Helmut

    2014-05-01

    We report the detection of 6.2 μm polycyclic aromatic hydrocarbon (PAH) and rest-frame 4-7 μm continuum emission in the z = 4.055 submillimeter galaxy GN20, using the Infrared Spectrograph on board the Spitzer Space Telescope. This represents the first detection of PAH emission at z > 4. The strength of the PAH emission feature is consistent with a very high star formation rate of ∼1600 M {sub ☉} yr{sup –1}. We find that this intense starburst powers at least ∼1/3 of the faint underlying 6 μm continuum emission, with an additional, significant (and perhaps dominant) contribution due to a power-law-like hot dust source, which we interpret to likely be a faint, dust-obscured active galactic nucleus (AGN). The inferred 6 μm AGN continuum luminosity is consistent with a sensitive upper limit on the hard X-ray emission as measured by the Chandra X-Ray Observatory if the previously undetected AGN is Compton-thick. This is in agreement with the finding at optical/infrared wavelengths that the galaxy and its nucleus are heavily dust-obscured. Despite the strong power-law component enhancing the mid-infrared continuum emission, the intense starburst associated with the photon-dominated regions that give rise to the PAH emission appears to dominate the total energy output in the infrared. GN20 is one of the most luminous starburst galaxies known at any redshift, embedded in a rich protocluster of star-forming galaxies. This investigation provides an improved understanding of the energy sources that power such exceptional systems, which represent the extreme end of massive galaxy formation at early cosmic times.

  12. Characterization of polycyclic aromatic hydrocarbons in motor vehicle fuels and exhaust emissions

    SciTech Connect (OSTI)

    Marr, L.C.; Kirchstetter, T.W.; Harley, R.A.; Hammond, S.K.; Miguel, A.H.; Hering, S.V.

    1999-09-15

    Motor vehicles are a significant source of polycyclic aromatic hydrocarbon (PAH) emissions. Improved understanding of the relationship between fuel composition and PAH emissions is needed to determine whether fuel reformulation is a viable approach for reducing PAH emissions. PAH concentrations were quantified in gasoline and diesel fuel samples collected in summer 1997 in northern California. Naphthalene was the predominant PAH in both fuels, with concentrations of up to 2,600 mg L{sup {minus}1} in gasoline and 1,600 mg L{sup {minus}1} in diesel fuel. Particle-phase PAH size distributions and exhaust emission factors were measured in two bores of a roadway tunnel. Emission factors were determined separately for light-duty vehicles and for heavy-duty diesel trucks, based on measurements of PAHs, CO, and CO{sub 2}. Particle-phase emission factors, expressed per unit mass of fuel burned, ranged up to 21 {micro}g kg{sup {minus}1} for benzo[ghi]perylene for light-duty vehicles and up to {approximately} 1,000 {micro}g kg{sup {minus}1} for pyrene for heavy-duty diesel vehicles. Light-duty vehicles were found to be a significant source of heavier (four- and five-ring) PAHs, whereas heavy-duty diesel engines were the dominant source of three-ring PAHs, such as fluoranthene and pyrene. While no correlation between heavy-duty diesel truck PAH emission factors and PAH concentrations in diesel fuel was found, light-duty vehicle PAH emission factors were found to be correlated with PAH concentrations in gasoline, suggesting that gasoline reformulation may be effective in reducing PAH emissions from motor vehicles.

  13. Structurally distinct polycyclic aromatic hydrocarbons induce differential transcriptional responses in developing zebrafish

    SciTech Connect (OSTI)

    Goodale, Britton C.; Tilton, Susan C.; Corvi, Margaret M.; Wilson, Glenn R.; Janszen, Derek B.; Anderson, Kim A.; Waters, Katrina M.; Tanguay, Robert L.

    2013-11-01

    Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous in the environment as components of fossil fuels and by-products of combustion. These multi-ring chemicals differentially activate the aryl hydrocarbon receptor (AHR) in a structurally dependent manner, and induce toxicity via both AHR-dependent and -independent mechanisms. PAH exposure is known to induce developmental malformations in zebrafish embryos, and recent studies have shown cardiac toxicity induced by compounds with low AHR affinity. Unraveling the potentially diverse molecular mechanisms of PAH toxicity is essential for understanding the hazard posed by complex PAH mixtures present in the environment. We analyzed transcriptional responses to PAH exposure in zebrafish embryos exposed to benz(a)anthracene (BAA), dibenzothiophene (DBT) and pyrene (PYR) at concentrations that induced developmental malformations by 120 h post-fertilization (hpf). Whole genome microarray analysis of mRNA expression at 24 and 48 hpf identified genes that were differentially regulated over time and in response to the three PAH structures. PAH body burdens were analyzed at both time points using GCMS, and demonstrated differences in PAH uptake into the embryos. This was important for discerning dose-related differences from those that represented unique molecular mechanisms. While BAA misregulated the least number of transcripts, it caused strong induction of cyp1a and other genes known to be downstream of the AHR, which were not induced by the other two PAHs. Analysis of functional roles of misregulated genes and their predicted regulatory transcription factors also distinguished the BAA response from regulatory networks disrupted by DBT and PYR exposure. These results indicate that systems approaches can be used to classify the toxicity of PAHs based on the networks perturbed following exposure, and may provide a path for unraveling the toxicity of complex PAH mixtures. - Highlights: Defined global mRNA expression changes induced by developmental exposure to PAHs Determined PAH body burdens following developmental exposure Genes uniquely induced by benz(a)anthracene included targets of the AHR and RELA Dibenzothiophene and pyrene perturbed a distinct RELA network Transcriptional networks reveal differential mechanisms of PAH toxicity.

  14. Direct production of hydrogen and aromatics from methane or natural gas: Review of recent U.S. patents

    SciTech Connect (OSTI)

    Lucia M. Petkovic; Daniel M. Ginosar

    2012-03-01

    Since the year 2000, the United States Patent and Trademark Office (USPTO) has granted a dozen patents for inventions related to methane dehydroaromatization processes. One of them was granted to UOP LLC (Des Plaines). It relates to a catalyst composition and preparation method. Two patents were granted to Conoco Phillips Company (Houston, TX). One was aimed at securing a process and operating conditions for methane aromatization. The other was aimed at securing a process that may be integrated with separation of wellhead fluids and blending of the aromatics produced from the gas with the crude. Nine patents were granted to ExxonMobil Chemical Patents Inc. (Houston, TX). Most of these were aimed at securing a dehydroaromatization process where methane-containing feedstock moves counter currently to a particulate catalyst. The coked catalyst is heated or regenerated either in the reactor, by cyclic operation, or in annex equipment, and returned to the reactor. The reactor effluent stream may be separated in its main components and used or recycled as needed. A brief summary of those inventions is presented in this review.

  15. On-line instrumentation for the real-time monitoring of polynuclear aromatic hydrocarbons in the effluents from a fluidized bed combustor - a feasibility study

    SciTech Connect (OSTI)

    D'Silva, A.P.; Iles, M.; Rice, G.; Fassel, V.A.

    1984-04-01

    When polynuclear aromatic hydrocargons in the vapor phase are diluted preferably in a rare gas and undergo supersonic jet expansion, rotationally cooled molecules with absorption bandwidths of the order of 0.01 nm (FWHM) are obtained. Selective excitation with a tunable dye laser into such narrow absorption bands leads to the observation of highly specific luminescence spectra. Such an approach has been utilized for the on-line, real-time monitoring of polynuclear aromatic hydrocarbons in the effluents from a fluidized bed combustor.

  16. The bonding, charge distribution, spin ordering, optical, and elastic properties of four MAX phases Cr{sub 2}AX (A = Al or Ge, X = C or N): From density functional theory study

    SciTech Connect (OSTI)

    Li, Neng; Mo, Yuxiang; Ching, Wai-Yim

    2013-11-14

    In this work, we assess a full spectrum of properties (chemical bonding, charge distribution, spin ordering, optical, and elastic properties) of Cr{sub 2}AC (A = Al, Ge) and their hypothetical nitride counterparts Cr{sub 2}AN (A = Al, Ge) based on density functional theory calculations. The calculated total energy values indicate that a variety of spin ordering of these four compounds depending on interlayer-interactions between M-A and M-X within the sublattice, which is supported by bonding analysis. MAX phase materials are discovered to possess exotic magnetic properties which indicates that these materials could serve as promising candidates for novel layered magnetic materials for various electronic and spintronic applications. Further analysis of optical properties for two polarization vectors of Cr{sub 2}AX shows that the reflectivity is high in the visible-ultraviolet region up to ∼15 eV suggesting Cr{sub 2}AX as a promising candidate for use as a coating material. The elastic coefficients (C{sub ij}) and bulk mechanical properties [bulk modulus (K), shear modulus (G), Young's modulus (E), Poisson's ratio (η), and Pugh ratio (G/K)] of these four Cr{sub 2}AX compounds are also calculated and analyzed, which pave the way to predict or design new MAX phases that are less brittle or tougher by having a lower G/K value or higher η.

  17. Effect of postdeposition annealing on the electrical properties of ?-Ga{sub 2}O{sub 3} thin films grown on p-Si by plasma-enhanced atomic layer deposition

    SciTech Connect (OSTI)

    Altuntas, Halit; Donmez, Inci; Ozgit-Akgun, Cagla; Biyikli, Necmi

    2014-07-01

    Ga{sub 2}O{sub 3} dielectric thin films were deposited on (111)-oriented p-type silicon wafers by plasma-enhanced atomic layer deposition using trimethylgallium and oxygen plasma. Structural analysis of the Ga{sub 2}O{sub 3} thin films was carried out using grazing-incidence x-ray diffraction. As-deposited films were amorphous. Upon postdeposition annealing at 700, 800, and 900?C for 30?min under N{sub 2} ambient, films crystallized into ?-form monoclinic structure. Electrical properties of the ?-Ga{sub 2}O{sub 3} thin films were then investigated by fabricating and characterizing Al/?-Ga{sub 2}O{sub 3}/p-Si metaloxide-semiconductor capacitors. The effect of postdeposition annealing on the leakage current densities, leakage current conduction mechanisms, dielectric constants, flat-band voltages, reverse breakdown voltages, threshold voltages, and effective oxide charges of the capacitors were presented. The effective oxide charges (Q{sub eff}) were calculated from the capacitancevoltage (C-V) curves using the flat-band voltage shift and were found as 2.6??10{sup 12}, 1.9??10{sup 12}, and 2.5??10{sup 12} cm{sup ?2} for samples annealed at 700, 800, and 900?C, respectively. Effective dielectric constants of the films decreased with increasing annealing temperature. This situation was attributed to the formation of an interfacial SiO{sub 2} layer during annealing process. Leakage mechanisms in the regions where current increases gradually with voltage were well fitted by the Schottky emission model for films annealed at 700 and 900?C, and by the FrenkelPoole emission model for film annealed at 800?C. Leakage current density was found to improve with annealing temperature. ?-Ga{sub 2}O{sub 3} thin film annealed at 800?C exhibited the highest reverse breakdown field value.

  18. Significance of Cytochrome P450 System Responses and Levels of Bile Fluorescent Aromatic Compounds in Marine Wildlife Following Oil Spills

    SciTech Connect (OSTI)

    Lee, Richard F.; Anderson, Jack W.

    2005-07-01

    The relationships among cytochrome P450 induction in marine wildlife species, levels of fluorescent aromatic compounds (FAC) in their bile, the chemical composition of the inducing compounds, the significance of the exposure pathway, and any resulting injury, as a consequence of exposure to crude oil following a spill, are reviewed. Fish collected after oil spills often show increases in cytochrome P450 system activity, cytochrome P4501A (CYP1A) and bile fluorescent aromatic compounds (FAC), that are correlated with exposure to polycyclic aromatic hydrocarbons (PAH) in the oil. There is also some evidence for increases in bile FAC and induction of cytochrome P450 in marine birds and mammals after oil spills. However, when observed, increases in these exposure indicators are transitory and generally decrease to background levels within one year after the exposure. Laboratory studies have shown induction of cytochrome P450 systems occurs after exposure of fish to crude oil in water, sediment or food. Most of the PAH found in crude oil (dominantly 2- and 3-ring PAH) are not strong inducers of cytochrome P450. Exposure to the 4-ring chrysenes or the photooxidized products of the PAH may account for the cytochrome P450 responses in fish collected from oil-spill sites. The contribution of non-spill background PAH, particularly combustion-derived (pyrogenic) PAH, to bile FAC and cytochrome P450 system responses can be confounding and needs to be considered when evaluating oil spill effects. The ubiquity of pyrogenic PAH makes it important to fully characterize all sources of PAH, including PAH from natural resources, e.g. retene, in oil spill studies. In addition, such parameters as species, sex, age, ambient temperature and season need to be taken into account. While increases in fish bile FAC and cytochrome P450 system responses, can together, be sensitive general indicators of PAH exposure after an oil spill, there is little unequivocal evidence to suggest a linkage to higher order biological effects, e.g. toxicity, lesions, reproductive failure.

  19. Selective aromatization of C[sub 3] and C[sub 4] paraffins over modified encilite catalysts. 1. Qualitative study

    SciTech Connect (OSTI)

    Jana, A.K.; Rao, M.S. . Department of Chemical Engineering)

    1993-06-01

    The catalytic activity of Zn-encilite in the aromatization of propane and n-butane has been studied by a comparative study of the yields of benzene, toluene, and xylenes (BTX) using propane and n-butane as feeds. The results showed that n-butane had better activity and selectivity to BTX than propane. The effects of reaction temperature, contact time, inlet concentration, poisoning with ammonia on H-encilite, and different degrees of ion exchange with Zn[sup 2+] ion were studied in detail in order to obtain information on the reaction mechanism. The results indicated that the activity and the selectivity were dictated by the acidity and Zn loading on the catalyst.

  20. sc0013735-psi | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from erosion, stream sedimentation, or other surface activities that require mitigation. ... Digital terrain mapping from manned aircraft is routinely done using scanned laser range ...

  1. Aging of secondary organic aerosol from small aromatic VOCs. Changes in chemical composition, mass yield, volatility and hygroscopicity

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hildebrandt Ruiz, L.; Paciga, A. L.; Cerully, K.; Nenes, A.; Donahue, N. M.; Pandis, S. N.

    2014-12-12

    Secondary organic aerosol (SOA) is transformed after its initial formation, but this chemical aging of SOA is poorly understood. Experiments were conducted in the Carnegie Mellon environmental chamber to form and transform SOA from the photo-oxidation of toluene and other small aromatic volatile organic compounds (VOCs) in the presence of NOx. The effects of chemical aging on organic aerosol (OA) composition, mass yield, volatility and hygroscopicity were explored. Higher exposure to the hydroxyl radical resulted in different OA composition, average carbon oxidation state OSC) and mass yield. The OA oxidation state generally increased during photo-oxidation, and the final OA OSmore » C ranged from -0.29 to 0.45 in the performed experiments. The volatility of OA formed in these different experiments varied by as much as a factor of 30, demonstrating that the OA formed under different oxidizing conditions can have significantly different saturation concentration. There was no clear correlation between hygroscopicity and oxidation state for this relatively hygroscopic SOA.« less

  2. Polycyclic aromatic hydrocarbons in olive fruits as a measure of air pollution in the valley of Florence (Italy)

    SciTech Connect (OSTI)

    Ignesti, G.; Lodovici, M.; Dolara, P.; Lucia, P.; Grechi, D.

    1992-06-01

    Plants have often been used for monitoring air pollution, such as Tradescantia for detecting mutagenic chemicals, or mosses which are bio-accumulators of heavy metals. Mosses have also been used as indicators of pollution from hexachlorobenzene and polycyclic aromatic hydrocarbons. PAH are present in most crops, and are deposited on the foliar surface of plants exposed to polluted air. Plants grown in heavily polluted environments have a higher concentration of PAH than those growing in clean environments, and plants grown in cabinets with filtered air have a very low concentration of PAH. Alimentary oils have high concentrations of PAH due to crop exposure to air pollutants and a high solubility of PAH in oils. PAH are important initiators of some human cancers and their monitoring is believed to be important for public health. Most Italian towns are heavily polluted by car exhaust and industrial sources, and a high concentration of PAH has been reported in the air particulate of urban areas. On the basis of these premises we thought it of interest to determine the concentration of some PAH in the olive fruits of trees growing in the valley of Florence (Italy), to establish if this approach could be useful for monitoring air pollution by PAH. 9 refs., 3 figs.

  3. Electron correlations and two-photon states in polycyclic aromatic hydrocarbon molecules: A peculiar role of geometry

    SciTech Connect (OSTI)

    Aryanpour, Karan; Shukla, Alok; Mazumdar, Sumit; College of Optical Sciences, University of Arizona, Tucson, Arizona 85721

    2014-03-14

    We present numerical studies of one- and two-photon excited states ordering in a number of polycyclic aromatic hydrocarbon molecules: coronene, hexa-peri-hexabenzocoronene, and circumcoronene, all possessing D{sub 6h} point group symmetry versus ovalene with D{sub 2h} symmetry, within the Pariser-Parr-Pople model of interacting ?-electrons. The calculated energies of the two-photon states as well as their relative two-photon absorption cross-sections within the interacting model are qualitatively different from single-particle descriptions. More remarkably, a peculiar role of molecular geometry is found. The consequence of electron correlations is far stronger for ovalene, where the lowest spin-singlet two-photon state is a quantum superposition of pairs of lowest spin triplet states, as in the linear polyenes. The same is not true for D{sub 6h} group hydrocarbons. Our work indicates significant covalent character, in valence bond language, of the ground state, the lowest spin triplet state and a few of the lowest two-photon states in D{sub 2h} ovalene but not in those with D{sub 6h} symmetry.

  4. Dispersion modeling of polycyclic aromatic hydrocarbons from combustion of biomass and fossil fuels and production of coke in Tianjin, China

    SciTech Connect (OSTI)

    Shu Tao; Xinrong Li; Yu Yang; Raymond M. Coveney, Jr.; Xiaoxia Lu; Haitao Chen; Weiran Shen

    2006-08-01

    A USEPA procedure, ISCLT3 (Industrial Source Complex Long-Term), was applied to model the spatial distribution of polycyclic aromatic hydrocarbons (PAHs) emitted from various sources including coal, petroleum, natural gas, and biomass into the atmosphere of Tianjin, China. Benzo(a)pyrene equivalent concentrations (BaPeq) were calculated for risk assessment. Model results were provisionally validated for concentrations and profiles based on the observed data at two monitoring stations. The dominant emission sources in the area were domestic coal combustion, coke production, and biomass burning. Mainly because of the difference in the emission heights, the contributions of various sources to the average concentrations at receptors differ from proportions emitted. The shares of domestic coal increased from {approximately} 43% at the sources to 56% at the receptors, while the contributions of coking industry decreased from {approximately} 23% at the sources to 7% at the receptors. The spatial distributions of gaseous and particulate PAHs were similar, with higher concentrations occurring within urban districts because of domestic coal combustion. With relatively smaller contributions, the other minor sources had limited influences on the overall spatial distribution. The calculated average BaPeq value in air was 2.54 {+-} 2.87 ng/m{sup 3} on an annual basis. Although only 2.3% of the area in Tianjin exceeded the national standard of 10 ng/m{sup 3}, 41% of the entire population lives within this area. 37 refs., 9 figs.

  5. Distribution of polycyclic aromatic hydrocarbons in fly ash during coal and residual char combustion in a pressurized fluidized bed

    SciTech Connect (OSTI)

    Hongcang Zhou; Baosheng Jin; Rui Xiao; Zhaoping Zhong; Yaji Huang

    2009-04-15

    To investigate the distribution of polycyclic aromatic hydrocarbons (PAHs) in fly ash, the combustion of coal and residual char was performed in a pressurized spouted fluidized bed. After Soxhlet extraction and Kuderna-Danish (K-D) concentration, the contents of 16 PAHs recommended by the United States Environmental Protection Agency (U.S. EPA) in coal, residual char, and fly ash were analyzed by a high-performance liquid chromatography (HPLC) coupled with fluorescence and diode array detection. The experimental results show that the combustion efficiency is lower and the carbon content in fly ash is higher during coal pressurized combustion, compared to the residual char pressurized combustion at the pressure of 0.3 MPa. Under the same pressure, the PAH amounts in fly ash produced from residual char combustion are lower than that in fly ash produced from coal combustion. The total PAHs in fly ash produced from coal and residual char combustion are dominated by three- and four-ring PAHs. The amounts of PAHs in fly ash produced from residual char combustion increase and then decrease with the increase of pressure in a fluidized bed. 21 refs., 1 fig., 4 tabs.

  6. Synergistic effect of mixing dimethyl ether with methane, ethane, propane, and ethylene fuels on polycyclic aromatic hydrocarbon and soot formation

    SciTech Connect (OSTI)

    Yoon, S.S.; Anh, D.H.; Chung, S.H.

    2008-08-15

    Characteristics of polycyclic aromatic hydrocarbon (PAH) and soot formation in counterflow diffusion flames of methane, ethane, propane, and ethylene fuels mixed with dimethyl ether (DME) have been investigated. Planar laser-induced incandescence and fluorescence techniques were employed to measure relative soot volume fractions and PAH concentrations, respectively. Results showed that even though DME is known to be a clean fuel in terms of soot formation, DME mixture with ethylene fuel increases PAH and soot formation significantly as compared to the pure ethylene case, while the mixture of DME with methane, ethane, and propane decreases PAH and soot formation. Numerical calculations adopting a detailed kinetics showed that DME can be decomposed to produce a relatively large number of methyl radicals in the low-temperature region where PAH forms and grows; thus the mixture of DME with ethylene increases CH{sub 3} radicals significantly in the PAH formation region. Considering that the increase in the concentration of O radicals is minimal in the PAH formation region with DME mixture, the enhancement of PAH and soot formation in the mixture flames of DME and ethylene can be explained based on the role of methyl radicals in PAH and soot formation. Methyl radicals can increase the concentration of propargyls, which could enhance incipient benzene ring formation through the propargyl recombination reaction and subsequent PAH growth. Thus, the result substantiates the importance of methyl radicals in PAH and soot formation, especially in the PAH formation region of diffusion flames. (author)

  7. Source Contribution Analysis of Surface Particulate Polycyclic Aromatic Hydrocarbon Concentrations in Northeastern Asia by Source-receptor Relationships

    SciTech Connect (OSTI)

    Inomata, Yayoi; Kajino, Mizuo; Sato, Keiichi; Ohara, Toshimasa; Kurokawa, Jun-Ichi; Ueda, Hiromasa; Tang, Ning; Hayakawa, Kazuichi; Ohizumi, Tsuyoshi; Akimoto, Hajime

    2013-11-01

    We analyzed the sourceereceptor relationships for particulate polycyclic aromatic hydrocarbon (PAH) concentrations in northeastern Asia using an aerosol chemical transport model. The model successfully simulated the observed concentrations. In Beijing (China) benzo[a]pyren (BaP) concentrations are due to emissions from its own domain. In Noto, Oki and Tsushima (Japan), transboundary transport from northern China (>40N, 40-60%) and central China (30-40N, 10-40%) largely influences BaP concentrations from winter to spring, whereas the relative contribution from central China is dominant (90%) in Hedo. In the summer, the contribution from Japanese domestic sources increases (40-80%) at the 4 sites. Contributions from Japan and Russia are additional source of BaP over the northwestern Pacific Ocean in summer. The contribution rates for the concentrations from each domain are different among PAH species depending on their particulate phase oxidation rates. Reaction with O3 on particulate surfaces may be an important component of the PAH oxidation processes.

  8. Occurrence of polycyclic aromatic hydrocarbons below coal-tar-sealed parking lots and effects on stream benthic macroinvertebrate communities

    SciTech Connect (OSTI)

    Scoggins, M.; McClintock, N.L.; Gosselink, L.; Bryer, P.

    2007-12-15

    Parking-lot pavement sealants recently have been recognized as a major source of polycyclic aromatic hydrocarbons (PAHs) in urban stream sediments in Austin, Texas. Laboratory and field studies have shown that PAHs in sediments can be toxic to aquatic organisms and can degrade aquatic communities. After identifying increases in concentrations of PAHs in sediments below seal-coated parking lots, we investigated whether the increases had significant effects on stream biota in 5 Austin streams. We sampled sediment chemistry and biological communities above and below the point at which stormwater runoff from the parking lots discharged into the streams, thus providing 5 upstream reference sites and 5 downstream treatment sites. Differences between upstream and downstream concentrations of total PAH ranged from 3.9 to 32 mg/kg. Analysis of the species occurrence data from pool and riffle habitats indicated a significant decrease in community health at the downstream sites, including decreases in richness, intolerant taxa, Diptera taxa, and density. In pool sediments, Chironomidae density was negatively correlated with PAH concentrations, whereas Oligochaeta density responded positively to PAH concentrations. In general, pool taxa responded more strongly than riffle taxa to PAHs, but riffle taxa responded more broadly than pool taxa. Increases in PAH sediment-toxicity units between upstream and downstream sites explained decreases in taxon richness and density in pools between upstream and downstream sites.

  9. Probabilistic ecological risk assessment and source apportionment of polycyclic aromatic hydrocarbons in surface sediments from Yellow Sea

    SciTech Connect (OSTI)

    Liu, A.X.; Lang, Y.H.; Xue, L.D.; Liao, S.L.; Zhou, H.

    2009-11-15

    Based on the concentrations of polycyclic aromatic hydrocarbons (PAHs) in 12 surface sediment samples from Yellow Sea, the relative risk of 9 PAHs was investigated using joint risk probability distribution curves and overlapping area, which were generated based on the distributions of exposure and acute toxicity data (LC50), and the sources of PAHs were apportioned using principal component analysis. It was found that joint probability curve and overlapping area indicated the acceptable ecological risk of individual PAHs, only a small fraction of the benthic organisms was affected. Among the nine PAHs studied, the overall risk of pyrene was the highest, with that of naphthalene the lowest. For lower exposure levels at which the percentage of species affected was less than 10%, the risk associated with phenanthrene and fluorene were clearly higher than that of the other seven PAHs. It was indicated that PAHs in surface sediments mainly originated from vehicular emissions, coal combustion sources, coke oven emission and wood combustion, petroleum origin made little influence on sources of PAHs by PCA.

  10. Pulmonary metabolism of dibenz(a,j)acridine: A carcinogenic heterocyclic aromatic: Final report for period September 1, 1982-June 30, 1986

    SciTech Connect (OSTI)

    Warshawsky, D.

    1987-07-01

    The metabolism of the carcinogenic N-heterocyclic aromatic, dibenz(a,j)-acridine (DBA) was investigated in the isolated perfused lung (IPL) preparation. A significantly increased rate of metabolism was observed for DBA in benzo(a)-pyrene (BaP) and DBA-pretreated animals. This resulted in marked increases in conjugation, in particular sulfates and thioethers, and the distribution of conjugates and total metabolites in blood and lung. When Fe/sub 2/O/sub 3/ was coadministered with DBA to the IPL, the rate of metabolism was significantly decreased with respect to control experiments. This resulted in increased distributions of sulfate and thioether conjugates in blood. Spectroscopic analyses and microsomal enzyme analyses were used in the characterization of the four metabolites identified in the lung. The major nonconjugated metabolite was the 3,4 dihydrodiol of DBA and the three minor metabolites were the 4 and 3 phenol of DBA and a dihydroxy compound of DBA. The results indicate that in the lung DBA is metabolized in a manner similar to that of BaP but different from that of dibenzo-(c,g)carbazole. It is, therefore, apparent that the metabolism of N-heterocyclic aromatics are related to the aromaticity of the heteroatom-containing ring and the solubility of compound, as well as the specific enzymes responsible for activation of the compound. 115 refs., 78 figs., 24 tabs.

  11. Polarization of prompt J/{psi} in pp{yields}J/{psi}+X at {radical...

    Office of Scientific and Technical Information (OSTI)

    The transverse-momentum distribution agrees well with the PHENIX preliminary data and the color-singlet-model prediction at next-to-leading order in alphasub s, but disagrees ...

  12. MaxPower Inc | Open Energy Information

    Open Energy Info (EERE)

    Product: Pennsylvania-based firm offering research, development and production of lithium ion batteries. Coordinates: 40.281201, -75.393534 Show Map Loading map......

  13. T10K Change Max Capacity

    Energy Science and Technology Software Center (OSTI)

    2013-08-16

    This command line utility will enable/disable the Oracle StorageTek T10000 tape drive's maximum capacity feature.

  14. Effect of B20 and Low Aromatic Diesel on Transit Bus NOx Emissions Over Driving Cycles with a Range of Kinetic Intensity

    SciTech Connect (OSTI)

    Lammert, M. P.; McCormick, R. L.; Sindler, P.; Williams, A.

    2012-10-01

    Oxides of nitrogen (NOx) emissions for transit buses for up to five different fuels and three standard transit duty cycles were compared to establish whether there is a real-world biodiesel NOx increase for transit bus duty cycles and engine calibrations. Six buses representing the majority of the current national transit fleet and including hybrid and selective catalyst reduction systems were tested on a heavy-duty chassis dynamometer with certification diesel, certification B20 blend, low aromatic (California Air Resources Board) diesel, low aromatic B20 blend, and B100 fuels over the Manhattan, Orange County and UDDS test cycles. Engine emissions certification level had the dominant effect on NOx; kinetic intensity was the secondary driving factor. The biodiesel effect on NOx emissions was not statistically significant for most buses and duty cycles for blends with certification diesel, except for a 2008 model year bus. CARB fuel had many more instances of a statistically significant effect of reducing NOx. SCR systems proved effective at reducing NOx to near the detection limit on all duty cycles and fuels, including B100. While offering a fuel economy benefit, a hybrid system significantly increased NOx emissions over a same year bus with a conventional drivetrain and the same engine.

  15. Non-covalent interactions of nitrous oxide with aromatic compounds: Spectroscopic and computational evidence for the formation of 1:1 complexes

    SciTech Connect (OSTI)

    Cao, Qian; School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275 ; Gor, Gennady Y.; Krogh-Jespersen, Karsten; Khriachtchev, Leonid

    2014-04-14

    We present the first study of intermolecular interactions between nitrous oxide (N{sub 2}O) and three representative aromatic compounds (ACs): phenol, cresol, and toluene. The infrared spectroscopic experiments were performed in a Ne matrix and were supported by high-level quantum chemical calculations. Comparisons of the calculated and experimental vibrational spectra provide direct identification and characterization of the 1:1 N{sub 2}O-AC complexes. Our results show that N{sub 2}O is capable of forming non-covalently bonded complexes with ACs. Complex formation is dominated by dispersion forces, and the interaction energies are relatively low (about ?3 kcal mol{sup ?1}); however, the complexes are clearly detected by frequency shifts of the characteristic bands. These results suggest that N{sub 2}O can be bound to the amino-acid residues tyrosine or phenylalanine in the form of ? complexes.

  16. First-principles investigation on the electronic efficiency and binding energy of the contacts formed by graphene and poly-aromatic hydrocarbon anchoring groups

    SciTech Connect (OSTI)

    Li, Yang; Tu, Xingchen; Wang, Hao; Hou, Shimin; Sanvito, Stefano

    2015-04-28

    The electronic efficiency and binding energy of contacts formed between graphene electrodes and poly-aromatic hydrocarbon (PAH) anchoring groups have been investigated by the non-equilibrium Greens function formalism combined with density functional theory. Our calculations show that PAH molecules always bind in the interior and at the edge of graphene in the AB stacking manner, and that the binding energy increases following the increase of the number of carbon and hydrogen atoms constituting the PAH molecule. When we move to analyzing the electronic transport properties of molecular junctions with a six-carbon alkyne chain as the central molecule, the electronic efficiency of the graphene-PAH contacts is found to depend on the energy gap between the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO) of the corresponding PAH anchoring group, rather than its size. To be specific, the smaller is the HOMO-LUMO gap of the PAH anchoring group, the higher is the electronic efficiency of the graphene-PAH contact. Although the HOMO-LUMO gap of a PAH molecule depends on its specific configuration, PAH molecules with similar atomic structures show a decreasing trend for their HOMO-LUMO gap as the number of fused benzene rings increases. Therefore, graphene-conjugated molecule-graphene junctions with high-binding and high-conducting graphene-PAH contacts can be realized by choosing appropriate PAH anchor groups with a large area and a small HOMO-LUMO gap.

  17. Properties of polycyclic aromatic hydrocarbons in the northwest photon dominated region of NGC 7023. II. Traditional PAH analysis using k-means as a visualization tool

    SciTech Connect (OSTI)

    Boersma, C.; Bregman, J.; Allamandola, L. J.

    2014-11-10

    Polycyclic aromatic hydrocarbon (PAH) emission in the Spitzer-IRS spectral map of the northwest photon dominated region (PDR) in NGC 7023 is analyzed using the 'traditional' approach in which the PAH bands and plateaus between 5.2-19.5 μm are isolated by subtracting the underlying continuum and removing H{sub 2} emission lines. The spectra are organized into seven spectroscopic bins by using k-means clustering. Each cluster corresponds to, and reveals, a morphological zone within NGC 7023. The zones self-organize parallel to the well-defined PDR front that coincides with an increase in intensity of the H{sub 2} emission lines. PAH band profiles and integrated strengths are measured, classified, and mapped. The morphological zones revealed by the k-means clustering provides deeper insight into the conditions that drive variations in band strength ratios and evolution of the PAH population that otherwise would be lost. For example, certain band-band relations are bifurcated, revealing two limiting cases; one associated with the PDR, the other with the diffuse medium. Traditionally, PAH band strength ratios are used to gain insight into the properties of the emitting PAH population, i.e., charge, size, structure, and composition. Insights inferred from this work are compared and contrasted to those from Boersma et al. (first paper in this series), where the PAH emission in NGC 7023 is decomposed exclusively using the PAH spectra and tools made available through the NASA Ames PAH IR Spectroscopic Database.

  18. Coherence time effects on J/{psi} production and suppression...

    Office of Scientific and Technical Information (OSTI)

    measurements and a nuclear absorption cross section extracted from pA charmonium production experiments, we study Jpsi production and absorption in nucleus-nucleus collisions. ...

  19. Phoenix Silicon International Corp Psi | Open Energy Information

    Open Energy Info (EERE)

    and manufacturer of wafers to the semiconductor and solar industries; also makes lithium-ion batteries. Coordinates: 24.69389, 121.148064 Show Map Loading map......

  20. A 700 year sediment record of black carbon and polycyclic aromatic hydrocarbons near the EMEP air monitoring station in Aspvreten, Sweden

    SciTech Connect (OSTI)

    Marie Elmquist; Zdenek Zencak; Oerjan Gustafsson

    2007-10-15

    In view of poor constraints on historical combustion emissions, past environmental loadings of black carbon (BC) and polycyclic aromatic hydrocarbon (PAH) were reconstructed from dated lake sediment cores collected 70 km south of Stockholm, Sweden. Compared to several dramatic variations over the recent 150 years, the preindustrial loadings were steady within {+-}50% through the entire medieval with BC fluxes of 0.071 g m{sup -2} yr{sup -1} and PAH fluxes of 6 g m{sup -2} yr{sup -1}. In the wood-burning dominated century leading up to the industrial revolution around 1850, increasing BC fluxes were leading PAH fluxes. BC fluxes reached their millennial-scale maximum around 1920, whereas PAH fluxes increased exponentially to its record maximum around 1960, 50-fold above preindustrial values. For 1920-1950, BC fluxes consistently decreased as PAH fluxes kept increasing. Coal and coke represented >50% of the Swedish energy market in the 1930s. Combined with sharply decreasing (1,7-)/(1,7{+-}2,6-dimethylphenanthrene), indicative of diminishing wood combustion, and decreasing methylphenanthrenes/phenanthrene, indicative of higher-temperature combustion (coal instead of wood), the sediment archive suggests that the relative BC/PAH emission factors thus are lower for coal than for wood combustion. For the first time, both BC and PAH fluxes decreased after 1960. This trend break is a testament to the positive effects of decreasing reliance on petroleum fuels and a number of legislative actions aimed at curbing emissions and by 1990, the loading of BC was back at preindustrial levels, whereas that of PAH were the lowest since the 1910s. However, for the most recent period (1990-2004) the BC and PAH fluxes are no longer decreasing. 55 refs., 3 figs.

  1. CDF Grid computing and the decay X(3872) ---> J/psi pi+ pi- with J/psi ---> e+ e-

    SciTech Connect (OSTI)

    Kerzel, Ulrich; /Karlsruhe U., EKP

    2005-11-01

    The main aim of physics research is to obtain a consistent description of nature leading to a detailed understanding of the phenomena observed in experiments. The field of particle physics focuses on the discovery and understanding of the fundamental particles and the forces by which they interact with each other. Using methods from group theory, the present knowledge can be mathematically described by the so-called ''Standard Model'', which interprets the fundamental particles (quarks and leptons) as quantum-mechanical fields interacting via the electromagnetic, weak and strong force. These interactions are mediated via gauge particles such as the photon (for the electromagnetic force), W{sup {+-}} and Z{sup 0} (for the weak force) and gluons (for the strong force). Gravitation is not yet included in this description as it presently cannot be formulated in a way to be incorporated in the Standard Model. However, the gravitational force is negligibly small on microscopic levels. The validity of this mathematical approach is tested experimentally by accelerating particles such as electrons and protons, as well as their antiparticles, to high energies and observing the reactions as these particles collide using sophisticated detectors. Due to the high energy of the particles involved, these detectors need to be as big as a small house to allow for precision measurements. Comparing the predictions from theory with the analyzed reactions observed in these collisions, the Standard Model has been established as a well-founded theory. Precision measurements from the four experiments (Aleph, Delphi, Opal, L3) the Large Electron Positron collider (LEP), operated at CERN during the years 1989-2000, allow the determination of the Standard Model parameters with enormous accuracy.

  2. Rapid microwave hydrothermal synthesis of ZnGa{sub 2}O{sub 4} with high photocatalytic activity toward aromatic compounds in air and dyes in liquid water

    SciTech Connect (OSTI)

    Sun Meng; Li Danzhen; Zhang Wenjuan; Chen Zhixin; Huang Hanjie; Li Wenjuan; He Yunhui; Fu Xianzhi

    2012-06-15

    ZnGa{sub 2}O{sub 4} was synthesized from Ga(NO{sub 3}){sub 3} and ZnCl{sub 2} via a rapid and facile microwave-assisted hydrothermal method. The photocatalytic properties of the as-prepared ZnGa{sub 2}O{sub 4} were evaluated by the degradation of pollutants in air and aqueous solution under ultraviolet (UV) light illumination. The results demonstrated that ZnGa{sub 2}O{sub 4} had exhibited efficient photocatalytic activities higher than that of commercial P25 (Degussa Co.) in the degradation of benzene, toluene, and ethylbenzene, respectively. In the liquid phase degradation of dyes (methyl orange, Rhodamine B, and methylene blue), ZnGa{sub 2}O{sub 4} has also exhibited remarkable activities higher than that of P25. After 32 min of UV light irradiation, the decomposition ratio of methyl orange (10 ppm, 150 mL) over ZnGa{sub 2}O{sub 4} (0.06 g) was up to 99%. The TOC tests revealed that the mineralization ratio of MO (10 ppm, 150 mL) was 88.1% after 90 min of reaction. A possible mechanism of the photocatalysis over ZnGa{sub 2}O{sub 4} was also proposed. - Graphical abstract: In the degradation of RhB under UV light irradiation, ZnGa{sub 2}O{sub 4} had exhibited efficient photo-activity, and after only 24 min of irradiation the decomposition ratio was up to 99.8%. Highlights: Black-Right-Pointing-Pointer A rapid and facile M-H method to synthesize ZnGa{sub 2}O{sub 4} photocatalyst. Black-Right-Pointing-Pointer The photocatalyst exhibits high activity toward benzene and dyes. Black-Right-Pointing-Pointer The catalyst possesses more surface hydroxyl sites than TiO{sub 2} (P25). Black-Right-Pointing-Pointer Deep oxidation of different aromatic compounds and dyes over catalyst.

  3. Application of a fuzzy neural network model in predicting polycyclic aromatic hydrocarbon-mediated perturbations of the Cyp1b1 transcriptional regulatory network in mouse skin

    SciTech Connect (OSTI)

    Larkin, Andrew; Siddens, Lisbeth K.; Krueger, Sharon K.; Tilton, Susan C.; Waters, Katrina M.; Williams, David E.; Baird, William M.

    2013-03-01

    Polycyclic aromatic hydrocarbons (PAHs) are present in the environment as complex mixtures with components that have diverse carcinogenic potencies and mostly unknown interactive effects. Non-additive PAH interactions have been observed in regulation of cytochrome P450 (CYP) gene expression in the CYP1 family. To better understand and predict biological effects of complex mixtures, such as environmental PAHs, an 11 gene input-1 gene output fuzzy neural network (FNN) was developed for predicting PAH-mediated perturbations of dermal Cyp1b1 transcription in mice. Input values were generalized using fuzzy logic into low, medium, and high fuzzy subsets, and sorted using k-means clustering to create Mamdani logic functions for predicting Cyp1b1 mRNA expression. Model testing was performed with data from microarray analysis of skin samples from FVB/N mice treated with toluene (vehicle control), dibenzo[def,p]chrysene (DBC), benzo[a]pyrene (BaP), or 1 of 3 combinations of diesel particulate extract (DPE), coal tar extract (CTE) and cigarette smoke condensate (CSC) using leave-one-out cross-validation. Predictions were within 1 log{sub 2} fold change unit of microarray data, with the exception of the DBC treatment group, where the unexpected down-regulation of Cyp1b1 expression was predicted but did not reach statistical significance on the microarrays. Adding CTE to DPE was predicted to increase Cyp1b1 expression, whereas adding CSC to CTE and DPE was predicted to have no effect, in agreement with microarray results. The aryl hydrocarbon receptor repressor (Ahrr) was determined to be the most significant input variable for model predictions using back-propagation and normalization of FNN weights. - Highlights: ? Tested a model to predict PAH mixture-mediated changes in Cyp1b1 expression ? Quantitative predictions in agreement with microarrays for Cyp1b1 induction ? Unexpected difference in expression between DBC and other treatments predicted ? Model predictions for combining PAH mixtures in agreement with microarrays ? Predictions highly dependent on aryl hydrocarbon receptor repressor expression.

  4. Three tetranuclear copper(II) cluster-based complexes constructed from 4-amino-1,2,4-triazole and different aromatic carboxylates: Assembly, structures, electrochemical and magnetic properties

    SciTech Connect (OSTI)

    Wang, Xiu-Li; Zhao, Wei; Zhang, Ju-Wen; Lu, Qi-Lin

    2013-02-15

    Three new tetranuclear copper(II) cluster-based complexes constructed from 4-amino-1,2,4-triazole (atrz) and three types of aromatic carboxylates, [Cu{sub 4}({mu}{sub 3}-OH){sub 2}(atrz){sub 2}(DNBA){sub 6}] (1), [Cu{sub 4}({mu}{sub 3}-OH){sub 2}(atrz){sub 2}(1,3-BDC){sub 3}]{center_dot}2H{sub 2}O (2) and [Cu{sub 4}({mu}{sub 3}-OH){sub 2}(atrz){sub 2}(SIP){sub 2}]{center_dot}4H{sub 2}O (3) (HDNBA=3,5-dinitrobenzoic acid, 1,3-H{sub 2}BDC=1,3-benzenedicarboxylic acid and NaH{sub 2}SIP=sodium 5-sulfoisophthalate), have been hydrothermally synthesized and structurally characterized. Complex 1 displays a single-molecular Cu{sup II}{sub 4} cluster structure, which is further connected by the intermolecular hydrogen-bonding interactions to form a 2D supramolecular layer. In 2, there also exist tetranuclear Cu{sup II}{sub 4} clusters, which are linked by the 1,3-BDC anions to give a 3D NaCl-type framework. In 3, the Cu{sup II}{sub 4} clusters are connected by the carboxyl and sulfo groups of SIP anions to generate 3D (4,8)-connected framework with a (4{sup 10}{center_dot}6{sup 14}{center_dot}8{sup 4})(4{sup 5}{center_dot}6){sub 2} topology. The atrz ligand conduces to the construction of tetranuclear copper(II) clusters and the carboxylates with different non-carboxyl substituent show important effects on the final structures of the title complexes. The electrochemical and magnetic properties of 1-3 have been investigated. - Graphical abstract: Three tetranuclear copper(II) cluster-based complexes based on different carboxylates have been synthesized under hydrothermal conditions. The carboxylate anions play a key role in the formation of three different structures. Highlights: Black-Right-Pointing-Pointer Three new tetranuclear copper(II) cluster-based complexes have been obtained. Black-Right-Pointing-Pointer The atrz conduces to the construction of tetranuclear copper(II) clusters. Black-Right-Pointing-Pointer Carboxylates show important effect on the structures of title complexes. Black-Right-Pointing-Pointer Magnetic properties and electrochemical behaviors have been reported.

  5. Cardiac toxicity of 5-ring polycyclic aromatic hydrocarbons is differentially dependent on the aryl hydrocarbon receptor 2 isoform during zebrafish development

    SciTech Connect (OSTI)

    Incardona, John P. Linbo, Tiffany L.; Scholz, Nathaniel L.

    2011-12-15

    Petroleum-derived compounds, including polycyclic aromatic hydrocarbons (PAHs), commonly occur as complex mixtures in the environment. Recent studies using the zebrafish experimental model have shown that PAHs are toxic to the embryonic cardiovascular system, and that the severity and nature of this developmental cardiotoxicity varies by individual PAH. In the present study we characterize the toxicity of the relatively higher molecular weight 5-ring PAHs benzo[a]pyrene (BaP), benzo[e]pyrene (BeP), and benzo[k]fluoranthene (BkF). While all three compounds target the cardiovascular system, the underlying role of the ligand-activated aryl hydrocarbon receptor (AHR2) and the tissue-specific induction of the cytochrome p450 metabolic pathway (CYP1A) were distinct for each. BaP exposure (40 {mu}M) produced AHR2-dependent bradycardia, pericardial edema, and myocardial CYP1A immunofluorescence. By contrast, BkF exposure (4-40 {mu}M) caused more severe pericardial edema, looping defects, and erythrocyte regurgitation through the atrioventricular valve that were AHR2-independent (i.e., absent myocardial or endocardial CYP1A induction). Lastly, exposure to BeP (40 {mu}M) yielded a low level of CYP1A+ signal in the vascular endothelium of the head and trunk, without evident toxic effects on cardiac function or morphogenesis. Combined with earlier work on 3- and 4-ring PAHs, our findings provide a more complete picture of how individual PAHs may drive the cardiotoxicity of mixtures in which they predominate. This will improve toxic injury assessments and risk assessments for wild fish populations that spawn in habitats altered by overlapping petroleum-related human impacts such as oil spills, urban stormwater runoff, or sediments contaminated by legacy industrial activities. -- Highlights: Black-Right-Pointing-Pointer PAH compounds with 5 rings in different arrangements caused differential tissue-specific patterns of CYP1A induction in zebrafish embryos. Black-Right-Pointing-Pointer These compounds produced differential cardiac developmental toxicity that did not strictly correlate with associated CYP1A induction. Black-Right-Pointing-Pointer Cardiotoxicity of benzo(a)pyrene was partially dependent on the AHR2 isoform, while benzo(k)fluoranthene cardiotoxicity was not. Black-Right-Pointing-Pointer Individual PAH compounds have distinct toxicokinetic pathways in fish embryos, and act through different toxic mechanisms.

  6. Aromatic triamide-lanthanide complexes

    DOE Patents [OSTI]

    2013-10-08

    The present invention provides luminescent lanthanide metal chelates comprising a metal ion of the lanthanide series and a complexing agent comprising at least one phthalamidyl moiety. Also provided are probes incorporating the phthalamidyl ligands of the invention and methods utilizing the ligands of the invention and probes comprising the ligands of the invention.

  7. Aromatic-radical oxidation chemistry

    SciTech Connect (OSTI)

    Glassman, I.; Brezinsky, K.

    1993-12-01

    The research effort has focussed on discovering an explanation for the anomalously high CO{sub 2} concentrations observed early in the reaction sequence of the oxidation of cyclopentadiene. To explain this observation, a number of plausible mechanisms have been developed which now await experimental verification. One experimental technique for verifying mechanisms is to probe the reacting system by perturbing the radical concentrations. Two forms of chemical perturbation of the oxidation of cyclopentadiene were begun during this past year--the addition of NO{sub 2} and CO to the reacting mixture.

  8. Real-time measurements of particulate matter and polycyclic aromatic hydrocarbon emissions from stationary combustion sources used in oil and gas production

    SciTech Connect (OSTI)

    D. w. Hahn; K. r. Hencken; H. A. Johnsen; J. R. Ross; P. M. Walsh

    1998-12-10

    Particulate matter emissions and some components of the particles were measured in the exhaust from combustion equipment used in oil and gas production operations near Bakersfield, California. The combustion sources included a 22.5 MW (electric) turbine generator, a 342-Bhp rich-burn spark ignition engine, and a 50 million Btu/h steam generator, all fired using natural gas. The particle components and measurement techniques were as follows: (1) Calcium, magnesium, sodium, silicon, and iron were measured using laser-induced breakdown spectroscopy (LIBS), (2) particle-bound polycyclic aromatic hydrocarbons (PAH) were detected using the charge produced by photoionization, (3) particles having sizes between 0.1 and 7.5 {micro}m were counted using an instrument based on light scattering, and (4) total particulate matter was measured according to US EPA Method 5. Not all of the methods were applied to all of the sources. Measurements were also made in the ambient air near the combustion air inlets to the units, for comparison with the concentrations in the exhaust, but the inlet and outlet measurements were not done simultaneously. Calcium, sodium, and silicon were found in the exhaust from the steam generator at concentrations similar to those in the ambient air near the inlet to the burner. Sodium and silicon were observed in the engine exhaust at levels a factor of four higher than their concentrations in the air. The principal metal observed in the engine exhaust was calcium, a component of the lubricating oil, at a concentration of 11.6 {micro}g/m{sup 3}. The air entering the gas turbine is filtered, so the average concentrations of metals in the turbine exhaust under steady operating conditions were even lower than in the air. During start-up following a shut-down to wash the turbine, silicon and iron were the major species in the stack, at concentrations of 6.4 and 16.2 {micro}g/m{sup 3}, respectively. A possible source of silicon is the water injected into the turbine for NO{sub x} control. Iron-containing particles are expected to be scale from ferrous metals. A commercial photoelectric aerosol sensor was used to measure PAH adsorbed on particles in the exhaust from the steam generator and the rich-burn engine. The conversion of the instrument readings to PAH concentrations is dependent upon the specific distribution of PAH species present. Using the typical calibration factor recommended by the instrument manufacturer, the estimated average concentration of particle-bound PAH was below the instrument detection limit (3--10 ng/m{sup 3}) in the stack gas from the steam generator, and was estimated to be 0.045--0.15 {micro}g/m{sup 3} in the exhaust from the rich-burn engine. Particle mass concentrations estimated from number concentrations determined using the particle counting and sizing instrument were only small fractions of the concentrations measured using Method 5. This is thought to be due primarily to the limited range over which size was quantified (0.1 to 7.5 {micro}m) and the poor efficiency with which the sampling system transferred large particles.

  9. AVTA: 2013 Ford C-Max Energi PHEV Testing Results

    Broader source: Energy.gov [DOE]

    The Vehicle Technologies Office's Advanced Vehicle Testing Activity carries out testing on a wide range of advanced vehicles and technologies on dynamometers, closed test tracks, and on-the-road....

  10. Property:Incentive/MaxInc | Open Energy Information

    Open Energy Info (EERE)

    + 20% of the annual C&I Standard Offer Program budget AEP SWEPCO - SMART Source Solar PV Program (Texas) + Residential: 15,000
    Non-residential: 30,000 AEP Texas Central...

  11. runtime error message: "apsched: request exceeds max nodes, alloc...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    This problem is intermittent, started in April, then mid July, and again since late August. Status: This problem is identified as a problem when TorqueMoab batch scheduler becomes ...

  12. Populations Voss, R.; /Garching, Max Planck Inst., MPE; Ajello...

    Office of Scientific and Technical Information (OSTI)

    study the populations of X-ray sources in the Milky Way in the 15-55 keV band using a deep survey with the BAT instrument aboard the Swift observatory. We present the logN-logS...

  13. Max Data Report Jet Stability versus Inlet Geometry

    SciTech Connect (OSTI)

    Lomperski, S.; Bremer, N.

    2015-09-01

    This document describes experiments investigating the effect of inlet geometry on the flow field within a glass tank where two jets mix and impinge upon the lid. The setup mimics the outlet plenum of a fast reactor where core exit flows of different temperatures can mix in ways that induce thermal cycling in neighboring structures.

  14. Crivelli, Silvia; Kreylos, Oliver; Max, Nelson; Hamann, Bernd...

    Office of Scientific and Technical Information (OSTI)

    and steer a protein structure prediction process that may be running on a remote machine. ProteinShop was used to create initial configurations for a protein structure...

  15. Max Tech Electric HPWH with Lower GWP Halogenated Refrigerant | Department

    Broader source: Energy.gov (indexed) [DOE]

    Matthew Ringer - Laboratory Program Manager, National Renewable Energy Laboratory ringer.png Matthew Ringer is a Laboratory Program Manager at the National Renewable Energy Laboratory. He has worked at NREL for more than 11 years. In his current role, Matt oversees the Lab-Corps Program, SBV CAP, and the Energy Innovation Portal. Additionally, he works with EERE on various commercialization initiatives, assists companies interested in commercializing NREL IP, and improving many of NREL's

  16. Property:Incentive/WindResPercMax | Open Energy Information

    Open Energy Info (EERE)

    I Independence Light & Power - Renewable Energy Rebates (Iowa) + 25% + L Local Small Wind Rebate Programs (Colorado) + 50% + M Maquoketa Municipal Electric Utility - Renewable...

  17. Property:Incentive/PVPbiFitMaxKW | Open Energy Information

    Open Energy Info (EERE)

    P Palmetto Clean Energy (PaCE) Program (South Carolina) + 6 + Preston Municipal Electric Utility - Renewable Energy Rebates (Iowa) + 20 + Progress Energy Carolinas - SunSense...

  18. Is a 'Mad Max' apocalypse possible? | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Is Your Home as Ready for Summer as You Are? Is Your Home as Ready for Summer as You Are? June 2, 2014 - 4:09pm Addthis Learn about home energy audits in this Energy 101 video. Harris Walker Communications Specialist, Weatherization and Intergovernmental Program What does this mean for me? You can save money this summer by checking your home for air leaks and seeing if it has sufficient insulation and energy-saving lightbulbs. It took longer than expected, but the harsh winter is finally over

  19. Microsoft Word - Draft Annncmnt of Max Aggregate Payments 11...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6, 2012 Announcement of Estimated Maximum Amount of Aggregate Payments BPA will Accept for the 2012 Prepayment Program Background The Bonneville Power Administration ("BPA") issued...

  20. Cover option 1 presentation title two lines max

    Energy Savers [EERE]

    © 2015 General Electric Company - All rights reserved 2015 DOE-NEET: Environmental Cracking and Irradiation Resistant Stainless Steel by Additive Manufacturing (AM) Xiaoyuan Lou ( loux@ge.com ) Ceramics and Metallurgy Technologies GE Global Research, Niskayuna, NY 2015 DOE AMM Workshop, Arlington, VA Sep. 29, 2015 This material was prepared with the internal support from General Electric Company. Additive Manufacturing for Nuclear Overview 3 © 2015 General Electric Company - All rights

  1. Cover option 1 presentation title two lines max

    Energy Savers [EERE]

    Powder atomization Low Cobalt 5 2015 General ... Eliminating post treatment cost from HIP ... process: 1. high local temperature 2. extremely fast ...

  2. Princeton, Max Planck Society launch new research center for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Smith delivered a statement from William Brinkman, director of the DOE's Office of Science, who was unable to attend. Brinkman noted that the DOE "welcomes the creation of this new ...

  3. Independent load support in an 18 3/4-in. , 15,000-psi subsea wellhead

    SciTech Connect (OSTI)

    Cowan, W.S.

    1993-03-01

    Previous-generation subsea wellhead equipment was conceived as an extension of well-known surface wellhead equipment. Contemporary performance criteria for subsea wellhead equipment require new technology from the designer/manufacturer. This paper describes the role of a single design concept, independent load support, in addressing these criteria and illustrates the resulting configuration of a severe-service subsea wellhead system.

  4. Relativistic Corrections to e+e- {yields} J/{psi} + {eta}c in...

    Office of Scientific and Technical Information (OSTI)

    High Energy Physics Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois 60517 (United States) Department of Physics, Korea University, Seoul 136-701 ...

  5. A Study of $B \\to J/\\psi K^{(*)} 0 X$ decays (Thesis/Dissertation...

    Office of Scientific and Technical Information (OSTI)

    ThesisDissertation: A Study of B to Jpsi K(*) 0 X decays Citation Details In-Document Search Title: A Study of B to Jpsi K(*) 0 X decays You are accessing a ...

  6. Using $X(3823)\\to J/\\psi\\pi^+\\pi^-$ to Identify Coupled-Channel Effects

    SciTech Connect (OSTI)

    Wang, Bo; Xu, Hao; Liu, Xiang; Chen, Dian-Yong; Coito, Susana; Eichten, Estia

    2015-07-28

    Very recently, a new charmonium-like state X(3823) was observed by the Belle and BESIII experiments, which is a good candidate of D-wave charmonium ψ(13D2). Since the X(3872) is just below the DD¯ * threshold, the decay X(3823) → J/ψπ+π - can be a golden channel to test the significance of coupled-channel effects. In this work, this decay is considered including both the hidden-charm dipion and the usual QCDME contributions. The partial decay width, the dipion invariant mass spectrum distribution dΓ[X(3823) → J/ψπ+π - ]/dmπ +π- , and the corresponding dΓ[X(3823) → J/ψπ+π- ]/d cos θ distribution are computed. Many parameters are determined from existing experimental data, leaving the results mainly dependent on only one unknown phase between the QCDME and hidden-charm dipion amplitudes.

  7. pp{yields}J/{psi}+{Upsilon}+X as a clean probe to the quarkonium...

    Office of Scientific and Technical Information (OSTI)

    If corresponding measured rate is significantly less than the prediction, it may imply that the current values for the color-octet matrix elements are overestimated. Authors: Ko, ...

  8. Evidence for simultaneous production of $J/\\psi$ and $\\Upsilon$ mesons

    SciTech Connect (OSTI)

    Abazov, Victor Mukhamedovich

    2015-11-07

    We report evidence for the simultaneous production of J/ψ and Υ mesons in 8.1 fb-1 of data collected at √s =1.96 TeV by the D0 experiment at the Fermilab pp- Tevatron Collider. Events with these characteristics are expected to be produced predominantly by gluon-gluon interactions. In our analysis, we extract the effective cross section characterizing the initial parton spatial distribution, σeff = 2.2 ± 0.7 (stat) ± 0.9 (syst) mb.

  9. Dissociation of the J/{psi} by light mesons, and chiral symmetry...

    Office of Scientific and Technical Information (OSTI)

    Department of Physics, McGill University, 3600 University Street, Montreal, Quebec, H3A 2T8 (Canada) Publication Date: 2008-09-15 OSTI Identifier: 21192240 Resource Type: Journal ...

  10. A Study of $B \\to J/\\psi K^{(*)} 0 X$ decays (Thesis/Dissertation...

    Office of Scientific and Technical Information (OSTI)

    ThesisDissertation: A Study of B to Jpsi K(*) 0 X decays Citation Details In-Document Search Title: A Study of B to Jpsi K(*) 0 X decays Authors: Bailey, ...

  11. J/psi Production in Quark-Gluon Plasma (Journal Article) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    We solve the coupled set of transport equation for the Jpsi distribution in phase space and the hydrodynamic equation for evolution of quark-gluon plasma. At RHIC, continuous ...

  12. AVTA: 2013 Ford C-Max Energi Fleet PHEV Testing Results

    Broader source: Energy.gov [DOE]

    VTO's National Laboratories have tested and collected both dynamometer and fleet data for the Ford CMAX Energi (a plug-in hybrid electric vehicle).

  13. Claire E. Max, 2004 | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    Print Text Size: A A A FeedbackShare Page Physics: For her contributions to the theory of laser guide star adaptive optics and its application in ground-based astronomy to correct ...

  14. DOE-CX-00009_WiMAX_Upgrades_on_Gable_Mountain.pdf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

  15. Index of /datasets/files/41/pub/PUBID8_0001/MaxTech

    Open Energy Info (EERE)

    Size DIR Parent Directory - DIR Sim1 18-Apr-2012 11:06 - 429 Throttled (bot load) Error 429 Throttled (bot load) Throttled (bot load) Guru Meditation: XID: 653191376 Varnish...

  16. THE MASS-RICHNESS RELATION OF MaxBCG CLUSTERS FROM QUASAR LENSING...

    Office of Scientific and Technical Information (OSTI)

    Authors: Bauer, Anne H. 1 ; Baltay, Charles ; Ellman, Nancy ; Jerke, Jonathan ; Rabinowitz, David ; Scalzo, Richard, E-mail: bauer@ieec.uab.es 2 + Show Author Affiliations ...

  17. Max Tech Electric Heat Pump Water Heater with Lower GWP Halogenated...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Image credit: Oak Ridge National Laboratory. Information flow schematic for an integrated heat ... options, cycle configurations, and system designs to determine the best path ...

  18. Webinar: Max Tech and Beyond Design Competition for Ultra-Low-Energy-Use Appliances & Equipment

    Broader source: Energy.gov [DOE]

    The competition invited twelve University faculty-led student engineering teams to participate in a year long effort to design, build and test their original energy savings technologies and prototypes.

  19. Onshore wind max capacity 50.4% - what wind farm, what year?...

    Open Energy Info (EERE)

    willing to learn.) Submitted by Bob Wallace on 15 June, 2013 - 00:23 1 answer Points: 0 Hi Bob- Thank you for posting your question. It seems that your question developed after...

  20. ARM - Field Campaign - 2006 MAX-Mex-Megacity Aerosol eXperiment...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    characterization of the aerosols, on aerosol transformations including aging of the black carbon during outflow from the region, and on the effects of the megacity aerosol plume on...

  1. Max Tech Appliance Design: Potential for Maximizing U.S. Energy Savings through Standards

    SciTech Connect (OSTI)

    Garbesi, Karina; Desroches, Louis-Benoit; Bolduc, Christopher; Burch, Gabriel; Hosseinzadeh, Griffin; Saltiel, Seth

    2011-05-06

    This study surveyed the technical potential for efficiency improvements in 150 categories of appliances and equipment representing 33 quads of primary energy use across the US economy in 2010 and (1) documented efficient product designs, (2) identified the most promising cross-cutting strategies, and (3) ranked national energy savings potential by end use. Savings were estimated using a method modeled after US Department of Energy priority-setting reports - simplified versions of the full technical and economic analyses performed for rulemakings. This study demonstrates that large savings are possible by replacing products at the end-of-life with ultra-efficient models that use existing technology. Replacing the 50 top energy-saving end-uses (constituting 30 quads of primary energy consumption in 2010) with today's best-on-market equivalents would save {approx}200 quads of US primary energy over 30 years (25% of consumption anticipated there from). For the 29 products for maximum feasible savings potential could be estimated, the savings were twice as high. These results demonstrate that pushing ultra-efficient products to market could significantly escalate carbon emission reductions and is a viable strategy for sustaining large emissions reductions through standards. The results of this analysis were used by DOE for new coverage prioritization, to identify key opportunities for product prototyping and market development, and will leverage future standards rulemakings by identifying the full scope of maximum feasible technology options. High leverage products include advances lighting systems, HVAC, and televisions. High leverage technologies include electronic lighting, heat pumps, variable speed motors, and a host of controls-related technologies.

  2. Fermion resonances on a thick brane with a piecewise warp factor

    SciTech Connect (OSTI)

    Li Haitao; Liu Yuxiao; Zhao Zhenhua; Guo Heng

    2011-02-15

    In this paper, we mainly investigate the problems of resonances of massive Kaluza-Klein (KK) fermions on a single scalar constructed thick brane with a piecewise warp factor matching smoothly. The distance between two boundaries and the other parameters are determined by one free parameter through three junction conditions. For the generalized Yukawa coupling {eta}{Psi}{phi}{sup k{Psi}} with odd k=1,3,5,..., the mass eigenvalue m, width {Gamma}, lifetime {tau}, and maximal probability P{sub max} of fermion resonances are obtained. Our numerical calculations show that the brane without internal structure also favors the appearance of resonant states for both left- and right-handed fermions. The scalar-fermion coupling and the thickness of the brane influence the resonant behaviors of the massive KK fermions.

  3. Measurement of prompt $J/\\psi$ pair production in pp collisions at $ \\sqrt{s} $ = 7 Tev

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Khachatryan, Vardan

    2014-09-17

    Production of prompt J/? meson pairs in proton-proton collisions at ?s = 7 TeV is measured with the CMS experiment at the LHC in a data sample corresponding to an integrated luminosity of about 4.7 fb-1. The two J/? mesons are fully reconstructed via their decays into ? + ? - pairs. This observation provides for the first time access to the high-transverse-momentum region of J/? pair production where model predictions are not yet established. The total and differential cross sections are measured in a phase space defined by the individual J/? transverse momentum (p T J/? ) and rapiditymore(|y J/? |): |y J/? | T J/? > 6.5 GeV/c; 1.2 J/? | T threshold that scales linearly with |y J/? | from 6.5 to 4.5 GeV/c; and 1.43 T J/? > 4.5 GeV/c. The total cross section, assuming unpolarized prompt J/? pair production is 1.49 0.07 (stat) 0.13 (syst) nb. Different assumptions about the J/? polarization imply modifications to the cross section ranging from -31% to +27%.less

  4. Measurement of the ratio of the production cross sections times branching fractions of $$B_{c}^{\\pm} \\to J/\\psi \\pi^{\\pm}$$ and $$B^{\\pm} \\to J/\\psi K^{\\pm}$$ and $$\\mathcal{B}(B_{c}^{\\pm} \\to J/\\psi \\pi^{\\pm}\\pi^{\\pm}\\pi^{\\mp})/\\mathcal{B}(B_{c}^{\\pm} \\to J/\\psi \\pi^{\\pm})$$ in pp collisions at $$\\sqrt{s} =$$ 7 TeV

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Khachatryan, Vardan

    2015-01-13

    The ratio of the production cross sections times branching fractions (σ(B±c)B(B±c→J/ψπ±))/(σ(B±)B(B±→J/ψK±)) is studied in proton-proton collisions at a center of-mass energy of 7 TeV with the CMS detector at the LHC. The kinematic region investigated requires B c ± and B± mesons with transverse momentum p T > 15 GeV and rapidity |y|< 1.6. The data sample corresponds to an integrated luminosity of 5.1 fb-1. The ratio is determined to be [0.48±0.05(stat)± 0.03(syst)±0.05 (τBc)]%. The B c ± → J/ψπ ± π ± π ∓ decay is also observed in the same data sample. Using a model-independent method developed tomore » measure the efficiency given the presence of resonant behaviour in the three-pion system, the ratio of the branching fractions B(B±c→J/ψπ±π±π∓)/B(B±c→J/ψπ±) is measured to be 2.55±0.80(stat)±0.33(syst)+0.04-0.01(τBc), consistent with the previous LHCb result.« less

  5. Draft Genome Sequence of the Polycyclic Aromatic Hydrocarbon...

    Office of Scientific and Technical Information (OSTI)

    Authors: Chauhan, Archana 1 ; Layton, Alice 2 ; Williams, Daniel W 1 ; Smart, Abby E. 2 ; Ripp, Steven Anthony 1 ; Karpinets, Tatiana V 1 ; Brown, Steven D 1 ; ...

  6. Process for reducing aromatic compounds in ethylenediamine with calcium

    DOE Patents [OSTI]

    Benkeser, R.A.; Laugal, J.A.; Rappa, A.

    1985-08-06

    Olefins are produced by containing an organic compound having at least one benzene ring with ethylenediamine and calcium metal, the calcium metal being used in large excess or alternatively in conjunction with an inert abrasive particulate substance. Substantially all of the organic compounds are converted to corresponding cyclic olefins, largely mono-olefins.

  7. Process for reducing aromatic compounds in ethylenediamine with calcium

    DOE Patents [OSTI]

    Benkeser, Robert A.; Laugal, James A.; Rappa, Angela

    1985-01-01

    Olefins are produced by containing an organic compound having at least one benzene ring with ethylenediamine and calcium metal, the calcium metal being used in large excess or alternatively in conjunction with an inert abrasive particulate substance. Substantially all of the organic compounds are converted to corresponding cyclic olefins, largely mono-olefins.

  8. Selective Conversion of Lignin into Simple Aromatic Compounds - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Selective Catalytic Oxidation of Hydrogen Sulfide to Elemental Sulfur from Coal-Derived Fuel Gases Todd H. Gardner (todd.gardner@netl.doe.gov, 304-285-4226) David A. Berry (david.berry@netl.doe.gov, 304-285-4430) K. David Lyons (kenneth.lyons@netl.doe.gov, 304-285-4379) Stephen K. Beer (stephen.beer@netl.doe.gov, 304-285-4040) Michael J. Monahan (michael.monahan@netl.doe.gov, 304-285-4408) U. S. Department of Energy National Energy Technology Laboratory P. O. Box 880 3610 Collins Ferry Road

  9. Polycyclic aromatic hydrocarbon and mid-infrared continuum emission...

    Office of Scientific and Technical Information (OSTI)

    ... Science Center, California Institute of Technology, MC 220-6, 1200 East California Boulevard, Pasadena, CA 91125 (United States) National Radio Astronomy Observatory, PO Box O, ...

  10. Conversion of Lignocellulosic Feedstocks to Aromatic Fuels and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Continue to work on improving yields to lower effect of biomass price volatility on final fuel product. Prolonged Depression of Crude Oil Prices Strive to be the low cost producer ...

  11. Measurement of CP violation in $B_s^0\\to J/\\psi \\phi$ decays using the full CDF data set

    SciTech Connect (OSTI)

    Leo, Sabato

    2015-01-01

    We report on the final measurement of the CP-violating $B_s^0$ mixing phase $\\beta_s^{J/ψφ}$ in √s = 1.96 TeV proton-antiproton collisions collected with the Collider Detector at the Fermilab Tevatron collider. Using a sample corresponding to 9.6 fb-1 of integrated luminosity, we fit the decay-time evolution of $B_s^0$ → J/ψ (→ μ+ μ-) φ (→ K+ K) decays in which the b-quark content at production and the CP parity of the final state are identified. The interference of decays with and without mixing renders the $B_s^0$ mixing phase observable. The phase is determined to be -0.06 < $\\beta_s^{J/ψφ}$ < 0.30 at 68% confidence level. The decay-width difference between heavy and light $B_s^0$ eigenstates, and the average $B_s^0$ lifetime are also determined to be ΔΓs = 0.068 ± 0.027 ps-1 and $\\tau_s$ = 1.528 ± 0.021 ps, respectively. These results are among the world’s most precise from a single experiment, and compatible with standard model predictions.

  12. Continuous process for conversion of coal

    DOE Patents [OSTI]

    Knudson, Curtis L.; Willson, Warrack G.; Baker, Gene G.; Sondreal, Everett A.; Farnum, Sylvia A.

    1982-01-01

    An improved process for converting coal to liquid and gaseous products wherein the liquid products predominate and wherein reactor, tubing, and valve plugging due to carbonate salt formation is reduced by reacting crushed low-rank coal containing about 12 to 30% by weight of water in a solvent at a temperature in the range of about 455.degree. to 500.degree. C., under about 2000 to 5000 psi pressure of a H.sub.2 /CO mixture for a liquid residence time of about 20 to 60 minutes. The solvent is a fraction of liquid product defined on a weight basis as being made up of about 55% of which distills at less than 250.degree. C./lmm, about 20% of which is soluble in THF, and about 25% of which is carbon polymer and indigenous inorganic matter. The solvent is further defined as containing at least about 5 weight % of partially hydrogenated aromatics and/or fully hydrogenated aromatics and little or no alkylated aromatics or higher alkanes.

  13. Measurement of the ratio $\\mathcal{B}( \\mathrm{B}^0_{s} \\to \\mathrm{J}/\\psi\\, \\mathrm{f}_0(980))/\\mathcal{B}(\\mathrm{B}^0_{s} \\to \\mathrm{J}/\\psi\\, \\phi(1020))$ in pp collisions at $\\sqrt{s}$ = 7 TeV

    SciTech Connect (OSTI)

    Khachatryan, Vardan

    2015-01-27

    The ratio Rf0/? of the branching fractions of the B0 s meson to the CP-odd eigenstate J/? f0(980) and to J/? ?(1020) is measured, where J/? ? + -, f0 ? ? +? -, and ? ? K+K-. The analysis is based on a data sample of pp collisions at a centre-of-mass energy of 7 TeV, collected by the CMS experiment, corresponding to an integrated luminosity of 5.3 fb-1 . The result is Rf0/? = 0.140 0.013 0.018, where the first uncertainty is statistical and the second is systematic. This result is consistent with theoretical predictions and previous measurements of Rf0/?. It is the most precise measurement of the ratio to date.

  14. The effect of sorption on the degradation of aromatic acids and bases

    SciTech Connect (OSTI)

    Ainsworth, C.C.; Fredrickson, J.K.; Smith, S.C.

    1992-10-01

    The availability and degradation of selected ionizable organic compounds sorbed to pure mineral phases are discussed. Substrates sorbed to mineral surfaces may or may not be protected from microbial attack; the degree of protection appears to be dependent on the type and cell density of the microorganism involved. The currently available data, however, demonstrate that there is little, if any, consensus on the types of reactions or interactions that facilitate sorbed substrate utilization. Rates of degradation of organic bases and cations that sorb to clay minerals via an exchange reaction are suggested to be directly related to substrate binding intensity and conformation on the clay surface. Similarly, rates of degradation of organic acids sorbed to the surface of oxides are suggested to be related to their interaction with the surface and the type of oxide sorbent. Although the rate-limiting step in microbial utilization of sorbed acids and bases is apparently a desorption process, the rate of desorption is itself linked to the compound's binding intensities on a given sorbent. Thus, as the binding intensities of compounds increase, chemical kinetic reactions, rather than mass-transfer processes, appear to limit the rate of desorption.

  15. The effect of sorption on the degradation of aromatic acids and bases

    SciTech Connect (OSTI)

    Ainsworth, C.C.; Fredrickson, J.K.; Smith, S.C.

    1992-10-01

    The availability and degradation of selected ionizable organic compounds sorbed to pure mineral phases are discussed. Substrates sorbed to mineral surfaces may or may not be protected from microbial attack; the degree of protection appears to be dependent on the type and cell density of the microorganism involved. The currently available data, however, demonstrate that there is little, if any, consensus on the types of reactions or interactions that facilitate sorbed substrate utilization. Rates of degradation of organic bases and cations that sorb to clay minerals via an exchange reaction are suggested to be directly related to substrate binding intensity and conformation on the clay surface. Similarly, rates of degradation of organic acids sorbed to the surface of oxides are suggested to be related to their interaction with the surface and the type of oxide sorbent. Although the rate-limiting step in microbial utilization of sorbed acids and bases is apparently a desorption process, the rate of desorption is itself linked to the compound`s binding intensities on a given sorbent. Thus, as the binding intensities of compounds increase, chemical kinetic reactions, rather than mass-transfer processes, appear to limit the rate of desorption.

  16. Highly Fluorescent Group 13 Metal Complexes with Cyclic, Aromatic Hydroxamic Acid Ligands

    SciTech Connect (OSTI)

    Seitz, Michael; Moore, Evan G.; Raymond, Kenneth N.

    2008-02-11

    The neutral complexes of two ligands based on the 1-oxo-2-hydroxy-isoquinoline (1,2-HOIQO) motif with group 13 metals (Al, Ga, In) show bright blue-violet luminescence in organic solvents. The corresponding transition can be attributed to ligand-centered singlet emission, characterized by a small Stokes shifts of only a few nm combined with lifetimes in the range between 1-3 ns. The fluorescence efficiency is high, with quantum yields of up to 37% in benzene solution. The crystal structure of one of the indium(III) complexes (trigonal space group R-3, a = b = 13.0384(15) {angstrom}, c = 32.870(8) {angstrom}, ? = {beta} = 90{sup o}, {gamma} = 120{sup o}, V = 4839.3(14) {angstrom}{sup 3}, Z = 6) shows a six-coordinate geometry around the indium center which is close to trigonal-prismatic, with a twist angle between the two trigonal faces of 20.7{sup o}. Time-dependent density functional theory (TD-DFT) calculations (Al and Ga: B3LYP/6-31G(d)); In: B3LYP/LANL2DZ of the fac and mer isomers with one of the two ligands indicate that there is no clear preference for either one of the isomeric forms of the metal complexes. In addition, the metal centers do not have a significant influence on the electronic structure, and as a consequence, on the predominant intraligand optical transitions.

  17. Investigation of chlorinated aromatic compounds in the environment: Methods development and data interpretation

    SciTech Connect (OSTI)

    Ding, Wanghsien.

    1989-01-01

    Detection of low levels of chlorinated benzene compounds (CLBZ) and polychlorinated biphenyls (PCBs) in soil samples has been investigated with respect to potential sources in an industrial area of western New York state. The extract obtained by steam distillation was used directly with minimal additional cleanup steps for high resolution gas chromatography/mass spectrometry (HRGC/MS) and high resolution gas chromatography with electron capture detection (HRGC/ECD) analysis. The Nielson-Kryger steam distillation technique was used to extract CLBZ compounds and PCB congeners from soil samples. The recoveries of the CLBZ compounds in soil samples were monitored by comparison of the response for the {sup 13}C-labelled analogues in each isomeric group. The mean recoveries from field samples ranged from 63% to 76%. The recoveries of PCB congeners were measured using four air-dried subsurface soils which were spiked with Aroclors standard mixture. The mean recoveries of most PCB congeners ranged from 80% to 99%. Using HRGC/MS in the selected ion monitoring mode (SIM), a detection limit below 10 pg/g (10 pptr, parts per trillion) of the CLBZ compounds was achieved. For GC/ECD, an Apiezon L-coated glass capillary column was used to determine PCB congeners at background levels. More than 69 PCB congeners were separated on this column. The detection limit for an individual congener was about 0.01 ng/g. Application of SIMCA (SImple Modeling by Chemical Analogy) pattern recognition and multiple discriminant analysis showed that the pattern of CLBZ compounds in soil samples collected near Love Canal was similar to the patterns from the other areas in the Niagara Falls area. The highest concentrations of CLBZ compounds were detected in the area which is near and downwind from an industrial center with many potential sources of airborne emissions.

  18. Pretreatment of solid carbonaceous material with dicarboxylic aromatic acids to prevent scale formation

    DOE Patents [OSTI]

    Brunson, Roy J.

    1982-01-01

    Scale formation during the liquefaction of lower ranking coals and similar carbonaceous materials is significantly reduced and/or prevented by pretreatment with a pretreating agent selected from the group consisting of phthalic acid, phthalic anhydride, pyromellitic acid and pyromellitic anhydride. The pretreatment is believed to convert the scale-forming components to the corresponding phthalate and/or pyromellitate prior to liquefaction. The pretreatment is accomplished at a total pressure within the range from about 1 to about 2 atmospheres. Temperature during pretreatment will generally be within the range from about 5.degree. to about 80.degree. C.

  19. Redox shuttles having an aromatic ring fused to a 1,1,4,4-tetrasubstit...

    Office of Scientific and Technical Information (OSTI)

    Inventors: Weng, Wei ; Zhang, Zhengcheng ; Amine, Khalil Issue Date: 2015-12-01 OSTI Identifier: 1228404 Assignee: UCHICAGO ARGONNE, LLC CHO Patent Number(s): 9,203,112 Application ...

  20. Aromatization or dehydrocyclization of N-alkanes using soluble transition metal complexes

    DOE Patents [OSTI]

    Goldman, Alan; Ahuja, Ritu; Schinski, William

    2016-04-05

    The invention provides methods and compositions useful for synthesizing alkylaromatics from an n-alkanes.

  1. Final Report for Grant "Direct Writing via Novel Aromatic Ladder Polymer Precursors"

    SciTech Connect (OSTI)

    C. B. Gorman

    2010-10-29

    This report describes activities and findings under the above entitled grant. These pertain to the development of new synthetic routes to novel precursor polymers and oligomers that are applicable for conversion from electrical insulators to electrical conductors under the application of light (e.g. direct photolithographic writing)

  2. Introduction of ?-Complexation into Porous Aromatic Framework for Highly Selective Adsorption of Ethylene over Ethane

    SciTech Connect (OSTI)

    Li, Baiyan; Zhang, Yiming; Krishna, Rajamani; Yao, Kexin; Han, Yu; Wu, Zili; Ma, Dingxuan; Shi, Zhan; Pham, Tony; Space, Brian; Liu, Jian; Thallapally, Praveen K.; Liu, Jun; Matthew, Chrzanowski; Ma, Shengqian

    2014-06-05

    We report herein a strategy of incorporating air stable Ag(I) ions into water stable, high surface area porous organic polymer (POP) affording significant increase in ethylene uptake capacity and extremely high Qst for ethylene (over 100 kJ/mol at low ethylene load-ing) as illustrated in the context of Ag(I) ion functionalized PAF-1, PAF-1-SO3Ag. IAST calculations using single-component-isotherm data and equimolar ethylene/ethane ratio at 296 K reveal PAF-1-SO3Ag shows exceptionally high ethylene/ethane adsorption selectivi-ty (Sads: 27 to 125), far surpassing benchmark zeolite and any other MOF reported in literature. This alongside excellent water/air stability, high ethylene uptake capacity, and mild regeneration requirements make PAF-1-SO3Ag hold promise for adsorption-based eth-ylene/ethane separations, paving a way to develop Ag(I) ion function-alized POPs as a new platform for highly selective adsorption of eth-ylene over ethane.

  3. Selective aerobic alcohol oxidation method for conversion of lignin into simple aromatic compounds

    DOE Patents [OSTI]

    Stahl, Shannon S; Rahimi, Alireza

    2015-03-03

    Described is a method to oxidize lignin or lignin sub-units. The method includes oxidation of secondary benzylic alcohol in the lignin or lignin sub-unit to a corresponding ketone in the presence of unprotected primarily aliphatic alcohol in the lignin or lignin sub-unit. The optimal catalyst system consists of HNO.sub.3 in combination with another Bronsted acid, in the absence of a metal-containing catalyst, thereby yielding a selectively oxidized lignin or lignin sub-unit. The method may be carried out in the presence or absence of additional reagents including TEMPO and TEMPO derivatives.

  4. Microsoft PowerPoint - Timlin Update Slide 1-6-2012.pptx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pigment and membrane characterization in Synechocystis Timlin & Pakrasi Labs PSII PSI Mean PSII & PSI Per Cell PSII PSI As antennae size decreases:   in thylakoid membrane curvature & cytoplasmic spacing & cytoplasmic spacing   in spatial separation of PSII & PSI   in amt PSII, in amt of PSI on per cell basis  Relevance: Flexibility of antennae systems, light absorption capabilities of PSI and PSII  Urban Lab currently conducting BioSANS data on

  5. Search for CPT Violation with the FOCUS Experiment and Measurement of Lambda(b) lifetime in the decay Lambda(b) --> J / psi Lambda with the D0 Experiment

    SciTech Connect (OSTI)

    Kryemadhi, Abaz

    2004-12-01

    This dissertation describes two different projects from two different experiments. We have performed a search for CPT violation in neutral charm meson oscillations using data from the FOCUS Experiment. While flavor mixing in the charm sector is predicted to be small in the Standard Model, it is still possible to investigate CPT violation through a study of the proper time dependence of a CPT asymmetry in right-sign decay rates for D{sup 0} {yields} K{sup -} {pi}{sup +} and {bar D}{sup 0} {yields} K{sup +}{pi}{sup -}. This asymmetry is related to the CPT violating complex parameter {xi} and the mixing parameters x and y: A{sub CPT} {infinity} Re{xi}y - Im{xi}x. We determine a 95% confidence level limit of -0.0068 < Re{xi}y - Im{xi}x < 0.0234. Within the framework of the Standard Model Extension incorporating general CPT violation, we also find 95% confidence level limits for the expressions involving coefficients of Lorentz violation of (-2.8 < N(x,y,{delta}))({Delta}a{sub 0} + 0.6 {Delta}a{sub Z} < 4.8) x 10{sup -16} GeV, (-7.0 < N(x,y,{delta}){Delta}a{sub x} < 3.8) x 10{sup -16} GeV, and (-7.0 < N(x,y,{delta}){Delta}a{sub y} < 3.8) x 10{sup -16} GeV, where N(x,y,{delta}) is a normalization factor that incorporates mixing parameters x, y and the doubly Cabibbo suppressed to Cabibbo favored relative strong phase {delta}.

  6. Polycyclic aromatic hydrocarbon emission profiles and removal efficiency by electrostatic precipitator and wetfine scrubber in an iron ore sintering plant

    SciTech Connect (OSTI)

    Ettore Guerriero; Antonina Lutri; Rosanna Mabilia; Maria Concetta Tomasi Sciano; Mauro Rotatori

    2008-11-15

    A monitoring campaign of polychlorinated dibenzo-p-dioxins and dibenzofurans, polyaromatic hydrocarbons (PAHs), and polychlorinated biphenyl was carried out in an Italian iron ore sintering plant by sampling the combustion gases at the electrostatic precipitator (ESP) outlet, at the Wetfine scrubber (WS) outlet, and by collecting the ESP dust. Few data are available on these micropollutants produced in iron ore sintering plants, particularly from Italian plants. This study investigates the PAH emission profiles and the removal efficiency of ESPs and WS. PAHs were determined at the stack, ESP outlet flue gases, and in ESP dust to characterize the emission profiles and the performance of the ESP and the WS for reducing PAH emission. The 11 PAHs monitored are listed in the Italian legislative decree 152/2006. The mean total PAH sum concentration in the stack flue gases is 3.96 {mu}g/N m{sup 3}, in ESP outlet flue gases is 9.73 {mu}g/N m{sup 3}, and in ESP dust is 0.53 {mu}g/g. Regarding the emission profiles, the most abundant compound is benzo(b)fluoranthene, which has a relative low BaP toxic equivalency factors (TEF) value, followed by dibenzo(a,l)pyrene, which has a very high BaP(TEF) value. The emission profiles in ESP dust and in the flue gases after the ESP show some changes, whereas the fingerprint in ESP and stack flue gases is very similar. The removal efficiency of the ESP and of WS on the total PAH concentration is 5.2 and 59.5%, respectively. 2 figs., 5 tabs.

  7. Distribution of Polycyclic Aromatic Hydrocarbons in Soils and Terrestrial Biota After a Spill of Crude Oil in Trecate, Italy

    SciTech Connect (OSTI)

    Brandt, Charles A. ); Becker, James M. ); Porta, Augusto C.

    2001-12-01

    Following a large blowout of crude oil in northern Italy in 1994, the distribution of polyaromatic hydrocarbons (PAHs) was examined over time and space in soils, uncultivated wild vegetation, insects, mice, and frogs in the area. Within 2 y of the blowout, PAH concentrations declined to background levels over much of the area where initial concentrations were within an order of magnitude above background, but had not declined to background in areas where starting concentrations exceeded background by two orders of magnitude. Octanol-water partitioning and extent of alkylation explained much of the variance in uptake of PAHs by plants and animals. Lower Kow PAHs and higher-alkylated PAHs had higher soil-to-biota accumulation factors (BSAFs) than did high-Kow and unalkylated forms. BSAFs for higher Kow PAHs were very low for plants, but much higher for animals, with frogs accumulating more of these compounds than other species.

  8. Photo-assisted intersystem crossing: The predominant triplet formation mechanism in some isolated polycyclic aromatic molecules excited with pulsed lasers

    SciTech Connect (OSTI)

    Johnson, Philip M.; Sears, Trevor J.

    2015-07-28

    Naphthalene, anthracene, and phenanthrene are shown to have very long-lived triplet lifetimes when the isolated molecules are excited with nanosecond pulsed lasers resonant with the lowest singlet state. For naphthalene, triplet state populations are created only during the laser pulse, excluding the possibility of normal intersystem crossing at the one photon level, and all molecules have triplet lifetimes greater than hundreds of microseconds, similar to the behavior previously reported for phenylacetylene. Although containing 7–12 thousand cm⁻¹ of vibrational energy, the triplet molecules have ionization thresholds appropriate to vibrationless T₁ states. The laser power dependences (slopes of log-log power plots) of the excited singlet and triplet populations are about 0.7 for naphthalene and about 0.5 for anthracene. Kinetic modeling of the power dependences successfully reproduces the experimental results and suggests that the triplet formation mechanism involves an enhanced spin orbit coupling caused by sigma character in states at the 2-photon level. Symmetry Adapted Cluster-Configuration Interaction calculations produced excited state absorption spectra to provide guidance for estimating kinetic rates and the sigma character present in higher electronic states. It is concluded that higher excited state populations are significant when larger molecules are excited with pulsed lasers and need to be taken into account whenever discussing the molecular photodynamics.

  9. Estimating the in situ sediment-porewater distribution of PAHs and chlorinated aromatic hydrocarbons in anthropogenic impacted sediments

    SciTech Connect (OSTI)

    Hans Peter H. Arp; Gijs D. Breedveld; Gerard Cornelissen

    2009-08-15

    It has become increasingly apparent that the in situ sediment-porewater distribution behavior of organic compounds within anthropogenic impacted sediments is quite diverse, and challenging to generalize. Traditional models based on octanol-water partitioning generally overestimate native porewater concentrations, and modern approaches accounting for multiple carbon fractions, including black carbon, appear sediment specific. To assess the diversity of this sorption behavior, we collected all peer-reviewed total organic carbon (TOC)-normalized in situ sediment-porewater distribution coefficients, K{sub TOC}, for impacted sediments. This entailed several hundreds of data for PAHs, PCBs, PCDD/Fs, and chlorinated benzenes, covering a large variety of sediments, locations, and experimental methods. Compound-specific KTOC could range up to over 3 orders of magnitude. Output from various predictive models for individual carbonaceous phases found in impacted sediments, based on peer-reviewed polyparameter linear free energy relationships (PP-LFERs), Raoult's Law, and the SPARC online-calculator, were tested to see if any of the models could consistently predict literature K{sub TOC} values within a factor of 30 (i.e. about 1.5 orders of magnitude, or half the range of K{sub TOC} values). The Raoult's Law model and coal tar PP-LFER achieved the sought-after accuracy for all tested compound classes, and are recommended for general, regional-scale modeling purposes. As impacted sediment-porewater distribution models are unlikely to get more accurate than this, this review underpins that the only way to accurately obtain accurate porewater concentrations is to measure them directly, and not infer them from sediment concentrations. 86 refs., 2 figs., 3 tabs.

  10. Laser photoionization time-of-flight mass spectrometry of nitrated polycyclic aromatic hydrocarbons and nitrated heterocyclic compounds. Master's thesis

    SciTech Connect (OSTI)

    Noyes, R.A.

    1993-01-01

    Partial Contents: Laser Desorption-Laser Photoionization Time-of-Flight Mass Spectrometry; Basic Principles of TOFMS; Factors Affecting Flight Time; Source of Broadening; Laser Desorption; Theory of Multiphoton Ionization: Application to Mass Spectrometry; Quantum Theory of MPI; Time-Dependent Perturbation Theory; Time-Dependent Coefficients; Probability of a Two-Photon Process; and Attributes of R2PI.

  11. Photo-assisted intersystem crossing: The predominant triplet formation mechanism in some isolated polycyclic aromatic molecules excited with pulsed lasers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Johnson, Philip M.; Sears, Trevor J.

    2015-07-28

    Naphthalene, anthracene, and phenanthrene are shown to have very long-lived triplet lifetimes when the isolated molecules are excited with nanosecond pulsed lasers resonant with the lowest singlet state. For naphthalene, triplet state populations are created only during the laser pulse, excluding the possibility of normal intersystem crossing at the one photon level, and all molecules have triplet lifetimes greater than hundreds of microseconds, similar to the behavior previously reported for phenylacetylene. Although containing 7–12 thousand cm⁻¹ of vibrational energy, the triplet molecules have ionization thresholds appropriate to vibrationless T₁ states. The laser power dependences (slopes of log-log power plots) ofmore » the excited singlet and triplet populations are about 0.7 for naphthalene and about 0.5 for anthracene. Kinetic modeling of the power dependences successfully reproduces the experimental results and suggests that the triplet formation mechanism involves an enhanced spin orbit coupling caused by sigma character in states at the 2-photon level. Symmetry Adapted Cluster-Configuration Interaction calculations produced excited state absorption spectra to provide guidance for estimating kinetic rates and the sigma character present in higher electronic states. It is concluded that higher excited state populations are significant when larger molecules are excited with pulsed lasers and need to be taken into account whenever discussing the molecular photodynamics.« less

  12. Technical Assessment of Compressed Hydrogen Storage Tank Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    TIAX LLC) were estimated for compressed hydrogen storage tanks with design pressures of 350 bar (5000 psi) and 700 bar (10,000 psi) capable of storing 5.6 kg of usable hydrogen. ...

  13. Process Limits

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0 0 file size (blocks) unlimited unlimited pending signals 4199424 4199424 max locked memory (kbytes) 32 32 max memory size (kbytes) unlimited unlimited open files 1024 1024 pipe...

  14. SPEAR results, 1981

    SciTech Connect (OSTI)

    Scharre, D.L.

    1981-09-01

    New results from SPEAR on the inclusive photon spectrum at the psi' and on J/psi radiative transitions are presented. Evidence for an eta/sub c/' candidate is observed in the psi' inclusive photon spectrum at a mass M = 3592 +- 5 MeV. A new resonance, the theta(1640) which is observed to decay into eta eta, has been seen in radiative transitions from the J/psi. The spin-parity of the l(1440), previously observed in J/psi radiative transitions and originally identified as the E(1420), has been determined to be 0/sup -/.

  15. Ocean Carbon Cycle Models from the Carbon Dioxide Information Analysis Center (CDIAC)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    \tPacific data-model intercomparison from Patrick Wetzel (Max Planck Institute for Meteorology, Germany)

  16. Photoluminescence spectroscopy of YVO{sub 4}:Eu{sup 3+} nanoparticles with aromatic linker molecules: A precursor to biomedical functionalization

    SciTech Connect (OSTI)

    Senty, T. R.; Yalamanchi, M.; Cushing, S. K.; Seehra, M. S.; Bristow, A. D.; Zhang, Y.; Shi, X.

    2014-04-28

    Photoluminescence spectra of YVO{sub 4}:Eu{sup 3+} nanoparticles are presented, with and without the attachment of organic molecules that are proposed for linking to biomolecules. YVO{sub 4}:Eu{sup 3+} nanoparticles with 5% dopant concentration were synthesized via wet chemical synthesis. X-ray diffraction and transmission electron microscopy show the expected wakefieldite structure of tetragonal particles with an average size of 17?nm. Fourier-transform infrared spectroscopy determines that metal-carboxylate coordination is successful in replacing native metal-hydroxyl bonds with three organic linkers, namely, benzoic acid, 3-nitro 4-chloro-benzoic acid, and 3,4-dihydroxybenzoic acid, in separate treatments. UV-excitation photoluminescence spectra show that the position and intensity of the dominant {sup 5}D{sub 0} {sup 7}F{sub 2} electric-dipole transition at 619?nm are unaffected by the benzoic acid and 3-nitro 4-chloro-benzoic acid treatments. Attachment of 3,4-dihydroxybenzoic acid produces an order-of-magnitude quenching in the photoluminescence, due to the presence of high-frequency vibrational modes in the linker. Ratios of the dominant electric- and magnetic-dipole transitions confirm infrared measurements, which indicate that the bulk crystal of the nanoparticle is unchanged by all three treatments.

  17. Pulmonary metabolism of dibenz(a,j)acridine: a carcinogenic heterocyclic aromatic. Technical progress report, September 1, 1982-September 30, 1983

    SciTech Connect (OSTI)

    Warshawsky, D.

    1983-10-31

    Dibenz(a,j)acridine (D(a,j)A) is metabolized by rat liver microsomes which results in the formation of seven major metabolites. Under the present conditions of the microsomal assay, 55% of D(a,j)A is metabolized by corn oil induced microsomes in 30 minutes, whereas 80% of D(a,j)A is metabolized by 3MC induced microsomes in 60 minutes. In the presence of the 3MC induced microsomes, a metabolite in fraction 19 is produced very rapidly and disappears linearly over 60 minutes. Of the major metabolites of D(a,j)A produced by microsomal incubations metabolites in fractions 11-12, 13 and 19 are possibly the 5,6-dihydrodiol of D(a,j)A, definitely the 3,4-dihydrodiol of D(a,j)A and a phenol or epoxide respectively. BaP pretreatment of the New Zealand white rabbits doubles the rate of appearance of the metabolites of D(a,j)A in the blood in the IPL. With or without pretreatment, the major metabolites are found in fractions 13 and 19 with 70 to 80% of the activity present in the nonextractable fraction. At the end of the perfusion 50% of the D(a,j)A remains in the IPL following BaP pretreatment as compared to 72% without pretreatment. This increased rate of metabolism due to BaP pretreatment results in the appearance of more conjugated metabolites at the end of the perfusion in the mercaptan fraction.

  18. Use of aromatic salts for simultaneously removing SO.sub.2 and NO.sub.x pollutants from exhaust of a combustion system

    DOE Patents [OSTI]

    Levendis, Yiannis A.; Wise, Donald L.

    1994-10-04

    A method is disclosed for removing pollutants from the exhaust of combustion systems burning fuels containing substantial amounts of sulfur and nitrogen. An exemplary method of the invention involves the formation and reaction of a sorbent comprising calcium benzoate. The calcium benzoate is either dry-sprayed (in the form of a fine powder) or wet-sprayed in an aqueous solution in a high temperature environment such as a combustion chamber. The latter technique is feasible since calcium benzoate is a water-soluble form of calcium. When the dispersed particles of calcium benzoate are heated to a high temperature, the organic benzoate burns off and fine calcium oxide particles are formed. These particles are cenospheric (hollow) and have thin and highly porous walls, thus, affording optimum external and internal accessibility for reacting with toxic gaseous emissions such as SO.sub.2. Further, the combustion of the organic benzoate portion of the sorbent results in the conversion of NO.sub.x to N.sub.2.

  19. Numerical analysis of the effect of acetylene and benzene addition to low-pressure benzene-rich flat flames on polycyclic aromatic hydrocarbon formation

    SciTech Connect (OSTI)

    Kunioshi, Nilson; Komori, Seisaku; Fukutani, Seishiro

    2006-10-15

    A modification of the CHEMKIN II package has been proposed for modeling addition of an arbitrary species at an arbitrary temperature to an arbitrary distance from the burner along a flat flame. The modified program was applied to the problem of addition of acetylene or benzene to different positions of a 40-Torr, {phi}=2.4 benzene/O{sub 2}/40%-N{sub 2} premixed flame to reach final equivalence ratios of {phi}=2.5 and 2.681. The results obtained showed that acetylene addition to early positions of the flame led to significant increase in pyrene production rates, but pyrene concentrations were lower in the flames with acetylene addition in both the {phi}=2.5 and 2.681 cases. Addition of benzene to the flame did not alter pyrene production rates in either the {phi}=2.5 or 2.681 cases; however, for {phi}=2.5, pyrene concentrations increased with benzene addition, while for {phi}=2.681, pyrene contents decreased in comparison to the correspondent flames with no addition. Acetylene addition led to a significant increase in pyrene production rates, but the pyrene levels dropped due to increase in the flow velocity. Pyrene production rates were not sensitive to benzene addition, but pyrene contents increased with benzene addition when the flow velocity decreased. These results show that PAH concentration changes accompanying species addition to flames should be interpreted carefully, because an increase or decrease in the content of a PAH species does not necessarily reflect an effect on its formation rate or mechanism. (author)

  20. Measurement of the CP-violating weak phase $\\mathrm{ \\phi_s }$ and the decay width difference $ \\Delta \\Gamma_{ \\mathrm{s} }$ using the $ \\mathrm{B^0_s} \\to \\mathrm{J} / \\psi \\phi(1020) $ decay channel in pp collisions at $\\sqrt{s} =$ 8 TeV

    SciTech Connect (OSTI)

    Khachatryan, Vardan

    2015-07-28

    The CP-violating weak phase ?s of the B0 s meson and the decay width difference ??s of the B0 s light and heavy mass eigenstates are measured with the CMS detector at the LHC using a data sample of B0 s ?J/? ?(1020) ? + -K+K- decays. Our analysed data set corresponds to an integrated luminosity of 19.7 fb-1 collected in pp collisions at a centre-of-mass energy of 8 TeV. Additionally, a total of 49 200 reconstructed B0 s decays are used to extract the values of ?s and ??s by performing a time-dependent and flavourtagged angular analysis of the + -K+K- final state. The weak phase is measured to be ?s = -0.075 0.097 (stat) 0.031 (syst) rad, and the decay width difference is ??s = 0.095 0.013 (stat) 0.007 (syst) ps-1 .

  1. Escape behavior of a quantum particle in a loop coupled to a lead

    SciTech Connect (OSTI)

    Jacquet, Ph. A. [Department of Physics, Kwansei Gakuin University, Sanda 669-1337 (Japan)

    2011-12-15

    We consider a one-dimensional loop of circumference L crossed by a constant magnetic flux {Phi} and connected to an infinite lead with coupling parameter {epsilon}. Assuming that the initial state {psi}{sub 0} of the particle is confined inside the loop and evolves freely, we analyze the time evolution of the nonescape probability P({psi}{sub 0},L,{Phi},{epsilon},t), which is the probability that the particle will still be inside the loop at some later time t. In appropriate units, we found that P({psi}{sub 0},L,{Phi},{epsilon},t)=P{sub {infinity}}({psi}{sub 0},{Phi})+{Sigma}{sub k=1}{sup {infinity}}C{sub k}({psi}{sub 0},L,{Phi},{epsilon})/t{sup k}. The constant P{sub {infinity}}({psi}{sub 0},{Phi}) is independent of L and {epsilon}, and vanishes if {psi}{sub 0} has no bound state components or if |cos({Phi})|{ne}1. The coefficients C{sub 1}({psi}{sub 0},L,{Phi},{epsilon}) and C{sub 3}({psi}{sub 0},L,{Phi},{epsilon}) depend on the initial state {psi}{sub 0} of the particle, but only the momentum k={Phi}/L is involved. There are initial states {psi}{sub 0} for which P({psi}{sub 0},L,{Phi},{epsilon},t){approx}C{sub {delta}}({psi}{sub 0},L,{Phi},{epsilon})/t{sup {delta}}, as t{yields}{infinity}, where {delta}=1 if cos({Phi})=1 and {delta}=3 if cos({Phi}){ne}1. Thus, by submitting the loop to an external magnetic flux, one may induce a radical change in the asymptotic decay rate of P({psi}{sub 0},L,{Phi},{epsilon},t). Interestingly, if cos({Phi})=1, then C{sub 1}({psi}{sub 0},L,{Phi},{epsilon}) decreases with {epsilon} (i.e., the particle escapes faster in the long run) while in the case cos({Phi}){ne}1, the coefficient C{sub 3}({psi}{sub 0},L,{Phi},{epsilon}) increases with {epsilon} (i.e., the particle escapes slower in the long run). Assuming the particle to be initially in a bound state of the loop with {Phi}=0, we compute explicit relations and present some numerical results showing a global picture in time of P({psi}{sub 0},L,{Phi},{epsilon},t). Finally, by using the pseudospectral method, we consider the interacting case with soft-core Coulomb potentials.

  2. Materials Solutions for Hydrogen Delivery in Pipelines

    SciTech Connect (OSTI)

    Ningileri, Shridas T.; Boggess, Todd A; Stalheim, Douglas

    2013-01-02

    The main objective of the study is as follows: Identify steel compositions/microstructures suitable for construction of new pipeline infrastructure and evaluate the potential use of the existing steel pipeline infrastructure in high pressure gaseous hydrogen applications. The microstructures of four pipeline steels were characterized and tensile testing was conducted in gaseous hydrogen and helium at pressures of 5.5 MPa (800 psi), 11 MPa (1600 psi) and 20.7 MPa (3000 psi). Based on reduction of area, two of the four steels that performed the best across the pressure range were selected for evaluation of fracture and fatigue performance in gaseous hydrogen at 5.5 MPa (800 psi) and 20.7 MPa (3000 psi). The basic format for this phase of the study is as follows: Microstructural characterization of volume fraction of phases in each alloy; Tensile testing of all four alloys in He and H{sub 2} at 5.5 MPa (800 psi), 11 MPa (1600 psi), and 20.7 MPa (3000 psi). RA performance was used to choose the two best performers for further mechanical property evaluation; Fracture testing (ASTM E1820) of two best tensile test performers in H{sub 2} at 5.5 MPa (800 psi) and 20.7 MPa (3000 psi); Fatigue testing (ASTM E647) of two best tensile test performers in H2 at 5.5 MPa (800 psi) and 20.7 MPa (3000 psi) with frequency =1.0 Hz and R-ratio=0.5 and 0.1.

  3. Office of Enterprise Assessments Review of the Los Alamos National...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Feedback Improvement Tracking System PMI Preventive Maintenance Instruction psi Pounds per Square ... The completed preventive and predictive maintenance forms required by ...

  4. PSH-12-0059 - In the Matter of Personnel Security Hearing | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Security Office (LSO) conducted a Personnel Security Interview (PSI) of the individual to address concerns about the individual's falsifications and financial irresponsibility. ...

  5. Paul Scherrer Institut | Open Energy Information

    Open Energy Info (EERE)

    Paul Scherrer Institut Jump to: navigation, search Name: Paul Scherrer Institut Place: Aargau, Villigen Zip: 5232 Number of Employees: 1001-5000 Website: www.psi.ch Coordinates:...

  6. Technically Recoverable Shale Oil and Shale Gas Resources

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    ... P is pressure, in psi (pressure data is obtained from well test information published in ... T is temperature, in degrees Rankin (temperature data is obtained from well test ...

  7. Electric field dependence of junction magnetoresistance inmagnetite...

    Office of Scientific and Technical Information (OSTI)

    We have fabricated Fesub 3Osub 4p-Si heterojunction using pulsed laser deposition technique and explored its electro-magnetic transport properties. The heterojunction exhibits ...

  8. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... ; PSI, Villigen ; et al We report on a Raman scattering investigation of the ... The observed phonon peaks can be ascribed to the Raman active modes for both the ...

  9. O:\EA-161.ORD

    Energy Savers [EERE]

    PSI Energy, Inc. Order No. EA-161 I. BACKGROUND Exports of electric energy from the United States to a foreign country are regulated and require authorization under Section 202(e) of the Federal Power Act (FPA) (16 U.S.C.§824a(e)). On October 9, 1997, PSI Energy, Inc. (PSI) applied to the Office of Fossil Energy (FE) of the Department of Energy (DOE) for authorization to transmit electric energy to Canada. The application was amended by letter on October 14, 1997. PSI is a regulated public

  10. Coastal Inlet Model Facility | Open Energy Information

    Open Energy Info (EERE)

    None Available Sensors Flow, Pressure Range(psi), Turbulence, Velocity, Wave Probe Data Generation Capability Real-Time No Test Services Test Services Yes Past Pertinent...

  11. 10-ft Wave Flume Facility | Open Energy Information

    Open Energy Info (EERE)

    None Available Sensors Flow, Pressure Range(psi), Turbulence, Velocity, Wave Probe Data Generation Capability Real-Time No Test Services Test Services Yes Past Pertinent...

  12. Coastal Structures Modeling Complex | Open Energy Information

    Open Energy Info (EERE)

    None Available Sensors Flow, Pressure Range(psi), Turbulence, Velocity, Wave Probe Data Generation Capability Real-Time No Test Services Test Services None Special...

  13. Sectional Model Flume Facilities | Open Energy Information

    Open Energy Info (EERE)

    None Available Sensors Flow, Pressure Range(psi), Turbulence, Velocity, Wave Probe Data Generation Capability Real-Time No Test Services Test Services Yes Past Pertinent...

  14. Carderock Large Cavitation Tunnel | Open Energy Information

    Open Energy Info (EERE)

    None Control and Data Acquisition Cameras None Available Sensors Pressure Range(psi) Data Generation Capability Real-Time No Test Services Test Services None Special...

  15. Separations Development and Application Presentation for BETO...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    o Biochemical Platform Analysis (BPA) o Biological Sugars Utilization (BUS) o Bench Scale Integration (BSI) o Pilot Scale Integration (PSI) Quad Chart Overview Start: FY13 (as ...

  16. NETL Technologies Earn Prestigious R&D 100 Awards | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Engineering Process Simulator Interface--The VE-PSI software provides engineers with the ability to design and optimize power plants within a virtual engineering environment. ...

  17. Microsoft PowerPoint - 5_Pat Smith_NMMSS_2013_Presentation_NRC...

    National Nuclear Security Administration (NNSA)

    Reconciliation Pat Smith PSI NRC Lead NRC Reconciliation NRC Reconciliation requirements per NUREGBR-0007, Rev. 6 All RIS's must submit an MSR (Material Summary Report) ...

  18. Arylene-fluorinated-sulfonimide ionomers and membranes for fuel cells

    DOE Patents [OSTI]

    Teasley, Mark F.

    2011-11-15

    The preparation of aromatic sulfonimide polymers useful as membranes in electrochemical cells is described.

  19. Job Scheduling Policies on Cooley | Argonne Leadership Computing...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Max. running jobs per user: 10 Max. node-hours (queued and running): 1488 Priority: FIFO -- (jobs are run in order, with small, short jobs run on any otherwise-free nodes) In...

  20. Twist Solves Bilayer Graphene Mystery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    der Max-Planck-Gesellschaft, Germany). Research funding: U.S. Department of Energy (DOE), Office of Basic Energy Sciences (BES); the National Research Foundation of Korea; the Max...

  1. Advanced Technology Vehicle Lab Benchmarking - Level 1

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... C-max Hybrid Ford C-max Energi Mitsubishi I-MiEV Nissan Leaf Ford Fusion Energi Ford Focus Electric Smart Fortwo ED Dodge Ram Idle Stop Honda Accord PHEV AVTA Test Cars Level 1 ...

  2. The 60-month all-sky BAT Survey of AGN and the Anisotropy of...

    Office of Scientific and Technical Information (OSTI)

    Garching, Max Planck Inst., MPE ; Madejski, G.M. ; KIPAC, Menlo Park ; Gehrels, N. ; NASA, Goddard ; Burlon, D. ; Garching, Max Planck Inst., MPE Publication Date: 2012-04-02...

  3. Microsoft Word - ITSI award doc 06-D0008 conformed to P00001...

    Broader source: Energy.gov (indexed) [DOE]

    87 Section B - Supplies or Services and Prices ITEM NO SUPPLIESSERVICES MAX QUANTITY UNIT UNIT PRICE MAX AMOUNT 0001 1 Lump Sum 226,000,000.00 226,000,000.00 EST Firm Fixed...

  4. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Filter by Author Gunzburger, Max D (7) Webster, Clayton G (6) Zhang, Guannan (5) Gunzburger, Max D ORNL (4) Webster, Clayton G ORNL (4) Zhang, Guannan ORNL (4) Lu, Dan (2) ...

  5. Open Issues

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    September 2014 runtime error message: "apsched: request exceeds max nodes, alloc" September 1

  6. Ocean Carbon Cycle Models from the Carbon Dioxide Information Analysis Center (CDIAC)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    •\tPacific data-model intercomparison from Patrick Wetzel (Max Planck Institute for Meteorology, Germany)

  7. Microsoft Word - Final Industrial Documentation AEO2008 _6-12...

    Gasoline and Diesel Fuel Update (EIA)

    factors are multiplicative for all fuels which have values greater than zero and are additive otherwise. ( ) ( ) ( ) ( ) ( ) ( ) - - - max...

  8. CAMD Nanofabrication Links

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrastructure :: News :: Related sites National Nanotechnology Initiative Nano Technology Industries Advanced Materials Research Institute Institute of Physics Max-Planck...

  9. Production of chemical feedstock by the methanolysis of wood

    DOE Patents [OSTI]

    Steinberg, Meyer; Fallon, Peter

    1984-07-31

    A process for the production of ethylene, benzene and carbon monoxide from particulated biomass such as wood by reaction with methane at a temperature of from 700.degree. C. to 1200.degree. C., at a pressure of from 20 psi to 100 psi for a period of from 0.2 to 10 seconds.

  10. Production of chemical feedstock by the methanolysis of wood

    DOE Patents [OSTI]

    Steinberg, M.; Fallon, P.

    1983-06-01

    A process is discussed for the production of ethylene, benzene and carbon monoxide from particulated biomass such as wood by reaction with methane at a temperature of from 700/sup 0/C to 1200/sup 0/C, at a pressure of from 20 psi to 100 psi for a period of from 0.2 to 10 seconds.

  11. Hopper Featured Announcements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    August 2012 high thruput queue now available on Hopper August 30, 2012 by Helen He A new batch queue named "thruput" has been implemented on Hopper to support the increased high throughput computing needs from the user community. The queue limits for this queue are as follows: -- max wall time is 168 hrs -- max node count is 2 (max core count is 48) -- max queue-able jobs per user is 500 -- max running jobs from all users in this queue is 500 -- has same priority as of the

  12. high thruput queue now available on Hopper

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    high thruput queue now available on Hopper high thruput queue now available on Hopper August 30, 2012 by Helen He A new batch queue named "thruput" has been implemented on Hopper to support the increased high throughput computing needs from the user community. The queue limits for this queue are as follows: -- max wall time is 168 hrs -- max node count is 2 (max core count is 48) -- max queue-able jobs per user is 500 -- max running jobs from all users in this queue is 500 -- has same

  13. Pressure testing of torispherical heads

    SciTech Connect (OSTI)

    Rana, M.D.; Kalnins, A.; Updike, D.P.

    1995-12-01

    Two vessels fabricated from SA516-70 steel with 6% knuckle radius torispherical heads were tested under internal pressure to failure. The D/t ratios of Vessel 1 and Vessel 2 were 238 and 185 respectively. The calculated maximum allowable working pressures of Vessel 1 and 2 heads using the ASME Section 8, Div. 1 rules and measured dimensions were 85 and 110 psi, respectively. Vessel 1 failed at a nozzle weld in the cylindrical shell at 700 psi pressure. Neither buckling nor any other objectionable deformation of the head was observed at a theoretical double-elastic-slope collapse pressure of 241 and a calculated buckling pressure of 270 psi. Buckles were observed developing slowly after 600 psi pressure, and a total of 22 buckles were observed after the test, having the maximum amplitude of 0.15 inch. Vessel 2 failed at the edge of the longitudinal weld of the cylindrical shell at 1,080 psi pressure. Neither buckling nor any other objectionable deformation of the head was observed up to the final pressure, which exceeded the theoretical double-elastic-slope collapse and calculated buckling pressures of 274 psi and 342 psi, respectively.

  14. Behavior of a hollow core photonic crystal fiber under high radial pressure for downhole application

    SciTech Connect (OSTI)

    Sadeghi, J., E-mail: j-sadeghi@sbu.ac.ir; Chenari, Z.; Ziaee, F. [Laser and Plasma Research Institute, Shahid Beheshti University, 1983963113 Tehran (Iran, Islamic Republic of); Latifi, H., E-mail: latifi@sbu.ac.ir [Laser and Plasma Research Institute, Shahid Beheshti University, 1983963113 Tehran (Iran, Islamic Republic of); Department of Physics, Shahid Beheshti University, Evin, 1983963113 Tehran (Iran, Islamic Republic of); Santos, J. L., E-mail: josantos@fc.up.pt [INESC PortoInstituto de Engenharia de Sistemas e Computadores do Porto, Rua do Campo Alegre, 687, 4169-007 Porto (Portugal); Departamento de Fsica, da Faculdade de Cincias, da Universidade do Porto, Rua do Campo Alegre, 687, 4169-007 Porto (Portugal)

    2014-02-17

    Pressure fiber sensors play an important role in downhole high pressure measurements to withstand long term operation. The purpose of this paper is to present an application of hollow core photonic crystal fiber (HC-PCF) as a high pressure sensor head for downhole application based on dispersion variation. We used a high pressure stainless steel unit to exert pressure on the sensor. The experimental results show that different wavelengths based on sagnac loop interferometer have additive sensitivities from 5??10{sup ?5}?nm/psi at 1480?nm to 1.3??10{sup ?3}?nm/psi at 1680?nm. We developed a simulation to understand the reason for difference in sensitivity of wavelengths and also the relationship between deformation of HC-PCF and dispersion variation under pressure. For this purpose, by using the finite element method, we investigated the effect of structural variation of HC-PCF on spectral transformation of two linear polarizations under 1000?psi pressure. The simulation and experimental results show exponential decay behavior of dispersion variation from ?3.4??10{sup ?6} 1/psi to ?1.3??10{sup ?6} 1/psi and from ?5??10{sup ?6} 1/psi to ?1.8??10{sup ?6} 1/psi, respectively, which were in a good accordance with each other.

  15. Combustion performance of porous silicon-based energetic composites

    SciTech Connect (OSTI)

    Mason, Benjamin Aaron; Son, Steve F; Asay, Blaine W; Cho, Kevin Y

    2009-01-01

    The combustion performance of oxidizer filled porous silicon(PSi) was studied. PSi samples with diameters of 2.54 cm were fabricated by electrochemical etching. The % porosity of the samples ranged from 55 to 82%. The samples were cut into 3-5 mm strips and filled with the oxidizers NaClO{sub 4} x 1H{sub 2}O, Ca(ClO{sub 4}){sub 2} x 4H{sub 2}O, S and perfluoropolyether (PFPE). The filled PSi was then burned by igniting the sample with a hot NiChrome{trademark} wire. The burns were recorded using high speed photography from which bring rates were calculated. That burning rates showed a strong dependency on quality of the oxidizer loading. The % porosity did not appear to have a direct affect on the burning rates for those studied. PSi loaded with NaClO{sub 4} x 1H{sub 2}O produced burning rates that ranged from 216-349 cm/s. PSi loaded with Ca(ClO{sub 4}){sub x}x 4 H{sub 2}O had burning rates of 154-285 cm/s. An S filled PSi sample burned a rate of 16 to 290 cm/s, and perfluoropolyether loaded PSi burned at a rate of 1.4 cm/s.

  16. On rapid plasma rotation

    SciTech Connect (OSTI)

    Helander, P.

    2007-10-15

    The conditions under which rapid plasma rotation may occur in a general three-dimensional magnetic field with flux surfaces, such as that of a stellarator, are investigated. Rotation velocities comparable to the ion thermal speed are found to be attainable only in magnetic fields whose strength B depends on the arc length l along the field in approximately the same way for all field lines on each flux surface {psi}, i.e., B{approx_equal}f({psi},l). Moreover, it is shown that the rotation must be in the direction of the vector {nabla}{psi}x{nabla}B.

  17. Search for the Z(4430) at BABAR

    SciTech Connect (OSTI)

    Aubert, B.

    2009-01-12

    We report the results of a search for Z(4430){sup -} decay to J/{psi}{pi}{sup -} or {psi}(2S){pi}{sup -} in B{sup -,0} {yields} J/{psi}{pi}{sup -} K{sup 0,+} and B{sup -,0} {yields} {psi}(2S){pi}{sup -}K{sup 0,+} decays. The data were collected with the BABAR detector at the SLAC PEP-II asymmetric-energy e{sup +}e{sup -} collider operating at center of mass energy 10.58 GeV, and the sample corresponds to an integrated luminosity of 413 fb{sup -1}. Each K{pi}{sup -} mass distribution exhibits clear K*(892) and K*{sub 2}(1430) signals, and the efficiency-corrected spectrum is well-described by a superposition of the associated Breit-Wigner intensity distributions, together with an S-wave contribution obtained from the LASS I = 1/2 K{pi}{sup -} scattering amplitude measurements. Each K{pi}{sup -} angular distribution varies significantly in structure with K{pi}{sup -} mass, and is represented in terms of low-order Legendre polynomial moments. We find that each J/{psi}{pi}{sup -} or {psi}(2S){pi}{sup -} mass distribution is well-described by the reflection of the measured K{pi}{sup -} mass and angular distribution structures. We see no significant evidence for a Z(4430){sup -} signal for any of the processes investigated, neither in the total J/{psi}{pi}{sup -} or {psi}(2S){pi}{sup -} mass distribution, nor in the corresponding distributions for the regions of K{pi}{sup -} mass for which observation of the Z(4430){sup -} signal was reported. We obtain branching fraction upper limits {Beta}(B{sup -} {yields} Z{sup -}{bar K}{sup 0}, Z{sup -} {yields} J/{psi}{pi}{sup -}) < 1.5 x 10{sup -5}, {Beta}(B{sup 0} {yields} Z{sup -}K{sup +},Z{sup -} {yields} J/{psi}{pi}{sup -}) < 0.4 x 10{sup -5}, {Beta}(B{sup -} {yields} Z{sup -} {bar K}{sup 0}, Z{sup -} {yields} {psi}(2S){pi}{sup -}) > 4.7 x 10{sup -5}, and {Beta}(B{sup 0} {yields} Z{sup -} K{sup +}, Z{sup -} {yields} {psi}(2S){pi}{sup -}) < 3.1 x 10{sup -5} at 95% confidence level, where the Z(4430){sup -} mass and width have been fixed to be reported central values.

  18. Double acting stirling engine phase control

    DOE Patents [OSTI]

    Berchowitz, David M.

    1983-01-01

    A mechanical device for effecting a phase change between the expansion and compression volumes of a double-acting Stirling engine uses helical elements which produce opposite rotation of a pair of crankpins when a control rod is moved, so the phase between two pairs of pistons is changed by +.psi. and the phase between the other two pairs of pistons is changed by -.psi.. The phase can change beyond .psi.=90.degree. at which regenerative braking and then reversal of engine rotation occurs.

  19. MID-INFRARED SPECTRAL INDICATORS OF STAR FORMATION AND ACTIVE...

    Office of Scientific and Technical Information (OSTI)

    and, with poorer statistics, of the neon emission lines and molecular hydrogen ... ENERGY BALANCE; GALAXIES; LUMINOSITY; NEON; PHOTOMETRY; POLYCYCLIC AROMATIC ...

  20. Arylene fluorinated sulfonimide compositions

    DOE Patents [OSTI]

    Teasley, Mark F.

    2010-11-23

    Described herein are aromatic sulfonimide compositions that can be used to prepare polymers useful as membranes in electrochemical cells.

  1. TSO-1102- In the Matter of Personnel Security Hearing

    Broader source: Energy.gov [DOE]

    The individual is an applicant for a DOE security clearance. In March 2011, as part of a background investigation, the Local Security Office (LSO) conducted a Personnel Security Interview (PSI) of...

  2. EERE PowerPoint 97-2004 Template: Green Version

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of a 300C, 40K psi analog tool for real-time pressure and temperature monitoring EGS wells. - Outcome: Our greatest accomplishment, Perma Works has released a barefoot 275C...

  3. Compressed/Liquid Hydrogen Tanks

    Broader source: Energy.gov [DOE]

    Currently, DOE's physical hydrogen storage R&D focuses on the development of high-pressure (10,000 psi) composite tanks, cryo-compressed tanks, conformable tanks, and other advanced concepts...

  4. PSH-11-0024- In the Matter of Personnel Security Hearing

    Broader source: Energy.gov [DOE]

    The individual is an applicant for a DOE security clearance. In March 2011, as part of a background investigation, the Local Security Office (LSO) conducted a Personnel Security Interview (PSI) of...

  5. ChemCam contributions to the Lunar and Planetary Science Conference...

    Office of Scientific and Technical Information (OSTI)

    DUston, C. MNHN; Langevin, Y. Univ. Paris-Sud; Mauchien, P. CEA; McKay, C. NASA Ames; Newsom, H. UNM; Vaniman, D. PSI; Baroukh, J. CNES; Barraclough, Bruce Los...

  6. "Title","Creator/Author","Publication Date","OSTI Identifier...

    Office of Scientific and Technical Information (OSTI)

    DUston, C. MNHN; Langevin, Y. Univ. Paris-Sud; Mauchien, P. CEA; McKay, C. NASA Ames; Newsom, H. UNM; Vaniman, D. PSI; Baroukh, J. CNES; Barraclough, Bruce Los...

  7. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    N APL JHU Clark B SSI DUston C MNHN Langevin Y Univ Paris Sud Mauchien P CEA McKay C NASA Ames Newsom H UNM Vaniman D PSI Baroukh J CNES Barraclough Bruce Los Alamos National...

  8. PSH-12-0009- In the Matter of Personnel Security Hearing

    Broader source: Energy.gov [DOE]

    The individual began his DOE-related job in August 2006. Ex. D at 19, 53, 70-71. In a September 2007 personnel security interview (PSI), the individual stated that he had been charged with...

  9. CO2 Compression | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    psi to be transported via pipeline and then injected into an underground storage site. ... NETL-funded CO2 compression projects are shown in the table below. Carbon Capture Project ...

  10. Newberry EGS Demonstration: Phase 2.2 Report (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    in 2008. In the fall of 2014, 9,500m3 (2.5 million gallons) of groundwater were injected at a maximum wellhead pressure of 195 bar (2850 psi) over 4 weeks of hydraulic stimulation. ...

  11. PowerPoint Presentation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    cable & conductor into 2,000 ft coiled tubing World first high power laser hardware (optics package & fiber connector) tested to >5,000 psi Achieving target requires "world...

  12. Microsoft Word - DOE-ID-INL-15-071.docx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The project would also include the routing of a 240V circuit, 25 psi water supply, back-flow preventer, condensate drainage, and venting of the chamber relief valve. This ...

  13. PowerPoint Presentation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Inlet Pressure (psi) Min. Flow Rate (lbsMWhr) Total Min. Flow Rate (lbhr) Allison 15 200 9500 142,500 MAN Turbo 50 50 9500 475,000 Dresser Rand 134 830 9500 1,273,000 Alston 300 ...

  14. PowerPoint Presentation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... updated VERA releases, the first VERA-EDU release * ANS ... Sci. & Eng., 2013. Sun Valley, Idaho 1252016 26 51 BEAVRS ... conditions 557 F @ 2250 psi * Unit 2 Startup in ...

  15. ADR Lunchtime Program: How Do You Make Decisions?

    Broader source: Energy.gov [DOE]

    Speaker: Mary Atwater Psy.D, Licensed Clinical Psychologist, Family Mediator, Child Access Mediator Member: Maryland Program for Mediator Excellence (MPME), Academy of Professional Family Mediators (APFM), Collaborative Dispute Resolution Professionals

  16. Wave chaos in the stadium: Statistical properties of short-wave solutions of the Helmholtz equation

    SciTech Connect (OSTI)

    McDonald, S.W.; Kaufman, A.N.

    1988-04-15

    We numerically investigate statistical properties of short-wavelength normal modes and the spectrum for the Helmholtz equation in a two-dimensional stadium-shaped region. As the geometrical optics rays within this boundary (billiards) are nonintegrable, this wave problem serves as a simple model for the study of quantum chaos. The local spatial correlation function <psi/sub n/(x+(12s)psi/sub n/(x- 1) 2 s)> and the probability distribution P/sub n/(psi) of wave amplitude for normal modes psi/sub n/ are computed and compared with predictions based on semiclassical arguments applied to this nonintegrable Hamiltonian. The spectrum is analyzed in terms of the probability P(..delta..E) of neighboring energy-eigenvalue separations, which is shown to be similar to a Wigner distribution for the eigenvalues of a random matrix

  17. Property:Available Sensors | Open Energy Information

    Open Energy Info (EERE)

    25 pages using this property. (previous 25) (next 25) 1 1.5-ft Wave Flume Facility + Flow, Pressure Range(psi), Turbulence, ... 10-ft Wave Flume Facility + Flow, Pressure...

  18. This Week In Petroleum Summary Printer-Friendly Version

    Gasoline and Diesel Fuel Update (EIA)

    California pipelines require the RVP of gasoline shipped on their systems to transition from the December-January specification of 15 pounds per square inch (psi) to 13.5...

  19. Slim Holes At Alvord Hot Springs Area (Combs, Et Al., 1999) ...

    Open Energy Info (EERE)

    high. Shut-in wellhead pressure was 64 psi. After a long delay from injunctions sought by environmental groups, two additional slimholes were drilled at this location in 1993 with...

  20. PSH-12-0006- In the Matter of Personnel Security Hearing

    Office of Energy Efficiency and Renewable Energy (EERE)

    The individual is an employee of a DOE contractor and holds a suspended access authorization. A Local Security Office (LSO) summoned the individual for an interview (PSI) with a personnel security...

  1. PSH-14-0105- In the Matter of Personnel Security Hearing

    Broader source: Energy.gov [DOE]

    The Individual is employed by a DOE contractor in a position that requires her to hold a DOE security clearance.  The Local Security Office (LSO) conducted a Personnel Security Interview (PSI) with...

  2. PSH-13-0097- In the matter of Personnel Security Hearing

    Broader source: Energy.gov [DOE]

    The individual is an employee of a DOE contractor and holds a suspended access authorization. A Local Security Office (LSO) summoned the individual for a Personnel Security Interview (PSI), with a...

  3. Microsoft PowerPoint - 7_Jim Crabtree_NMMSS People, Resources...

    National Nuclear Security Administration (NNSA)

    Gary Hirsch * PSI Team LeadIAEA Reporting Lead 301-903-6870 John Ballard* DOE Lead, Training Lead 301-903-0092 Pat Smith* NRC Lead 301- 903-6860 Len Myers * Special RequestsDIMS...

  4. Microsoft PowerPoint - 4_Gary_Wednesday 5-22 Transit Matching...

    National Nuclear Security Administration (NNSA)

    Matching Case Study Gary Hirsch, PSI Scenario 1 Australia 2 Scenario 1 Australia 3 Scenario 1 Australia 4 Scenario 2 Mexico 5 Scenario 2 Mexico 6 Scenario 2 Mexico 7 Scenario 3...

  5. Poisson's ratio and porosity at Coso geothermal area, California...

    Open Energy Info (EERE)

    of the model, are estimated by a jackknife method. We use perturbations of r V p V s ratio and Psi V p .V s product to derive distributions of Poisson's ratio, sigma , and...

  6. POWER SUPPLY CONTROL AND MONITORING FOR THE SNS RING AND TRANSPORT SYSTEM

    SciTech Connect (OSTI)

    LAMBIASE,R.; OERTER,B.; PENG,S.; SMITH,J.

    2001-06-28

    There are approximately 300 magnet power supplies in the SNS accumulator ring and transport lines. Control and monitoring of the these converters will be primarily accomplished with a new Power Supply Interface and Controller (PSI/PSC) system developed for the SNS project. This PSI/PSC system provides all analog and digital commands and status readbacks in one fiber isolated module. With a maximum rate of 10KHz, the PSI/PSC must be supplemented with higher speed systems for the wide bandwidth pulsed injection supplies, and the even wider bandwidth extraction kickers. This paper describes the implementation of this PSI/PSC system, which was developed through an industry/laboratory collaboration, and the supplementary equipment used to support the wider bandwidth pulsed supplies.

  7. PSH-12-0015- In the Matter of Personnel Security Hearing

    Broader source: Energy.gov [DOE]

    The individual is an applicant for a DOE security clearance. In July 2011, as part of a background investigation, the Local Security Office (LSO) conducted a Personnel Security Interview (PSI) of...

  8. Best Management Practice #11: Commercial Kitchen Equipment |...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Observe final rinse pressure to ensure it is within manufacture recommendations, typically 20 5 psi. If the pressure is too low, the dishes may not be rinsed and sanitized ...

  9. Best Management Practice #7: Faucets and Showerheads | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Encourage cleaning or custodial crews to report problems. Test system pressure to make sure it is between 20 and 80 psi. If the pressure is too low, high-efficiency devices won't ...

  10. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    load and approaches a steady value as normal load increases. ... polar molecule while methanol is intermediate between ... as high as 650 C and pressures of 400-600 psi. ...

  11. UNCLASSIFIED Institute for Materials ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PSI: the X-ray free electron laser SwissFEL and its future experimental capabilities. Biography: Prof. Dr. Jol Mesot is, since 2008, director of the Paul Scherrer Institute...

  12. PSH-14-0101- In the Matter of Personnel Security Hearing

    Broader source: Energy.gov [DOE]

    This case involves an Individual who tested positive for alcohol during a random screening conducted at his workplace.  The LSO conducted a Personnel Security Interview (PSI) of the Individual and...

  13. Influence of Domain Wall Pinning on the Dynamic Behavior of Magnetic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    B. Van Waeyenberge (Ghent University, Belgium), K.W. Chou, H. Stoll, M. Curcic, G. Schutz (Max Planck Institute for Metals Research, Germany), T. Tyliszczak (ALS), G....

  14. Metagenomic and Metaproteomic Analyses of Symbioses between Bacteria and Gutless Marine Worms (2014 DOE JGI Genomics of Energy & Environment Meeting)

    SciTech Connect (OSTI)

    Dubilier, Nicole

    2014-03-19

    Nicole Dubilier of the Max Planck Institute speaks at the 9th Annual Genomics of Energy & Environment Meeting on March 20, 2014 in Walnut Creek, Calif.

  15. BPA-2010-00492-FResponse.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DAVID A FILER DAVID A. FILER, ATTORNEY US POSTMASTER USPS CENTRALIZED ACCOUNT PROCESSING SYSTEM RESOURCE MANAGEMENT ASSOCIATES WIND SITE MAINTENANCE SUPPORT (MAX HOLDER) RESOURCE...

  16. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Garching, Max Planck Inst., MPEMuenchen, Tech. U. Universe" Name Name ORCID Search Authors Type: All BookMonograph ConferenceEvent Journal Article Miscellaneous Patent Program...

  17. An Iridate with Fermi Arcs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (Univ. of Michigan); and B.J Kim (Argonne National Laboratory, Univ. of Michigan, and Max Planck Institute for Solid State Research). Research funding: National Science...

  18. Microsoft Word - exposure_request_form.dot

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (torr) Proximity Gap: (m) Min. Bottom Dose: (Jcm3) Max. Ratio of Top to Bottom Dose: Scan Length: (cm or inch)...

  19. --No Title--

    Broader source: Energy.gov (indexed) [DOE]

    some the revisions for both chapters includes DOE's annual reporting performance targets, MAX site quarterly reporting by the DOE Agency Coordinator, the requirement for 100%...

  20. stamnes-99.PDF

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... pressure and temperature, flow rates, film speed, condensation nuclei concentration (r > 0.02 micrometer) * max altitude: 2500 m with battery pack, 1 km on powered tether * ...

  1. Porterfield named ASTM Fellow

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the Nuclear Fuel Cycle International Committee may bestow on an individual; and the Max Hecht Award, the highest award the Water International Committee can bestow on an - 2 -...

  2. Porterfield named ASTM Fellow

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the Nuclear Fuel Cycle International Committee may bestow on an individual; and the Max Hecht Award, the highest award the Water International Committee can bestow on an...

  3. PowerPoint Presentation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... capabilities 6) Minimal to zero water consumption (energy water nexus issues ... and Key Participants; Abstract (200 words max) - Introduction - Impact of the ...

  4. Accelerated Aging Studies

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Accelerated Aging Studies LA-UR -15-27339 This document is approved for public release; further dissemination unlimited Property (max) log (aging time) Property (failure) Property ...

  5. Contact | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    Student Participation Other * Comments max. 1000 characters Captcha Display another text. Play audio version of text. Image Verification Submit Last modified: 8142013 5:25:36...

  6. Contact | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    Letters of Recommendation Other * Comments max. 1000 characters Captcha Display another text. Play audio version of text. Image Verification Submit Last modified: 8142013 5:25:36...

  7. Posters

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    San Diego La Jolla, California H. Grassl Max Planck Institute for Meteorology Hamburg, Germany A. Heymsfield National Center for Atmospheric Research Boulder, Colorado J. Spinhirne...

  8. Markus Mezger | Center for Gas SeparationsRelevant to Clean Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Presently: Project leader, Max Planck Institute for Polymer Research, Mainz, Germany Email: mezger at mpip-mainz.mpg.de Diploma in Physics, Stuttgart University,...

  9. X-ray and neutron scattering studies of the complex compounds...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by Dr. Hoyoung Jang, Max Planck Institute for Solid State Research in Stuttgart, Germany In condensed matter physics, in particular a field of complex oxide materials, most...

  10. Index of /datasets/files/41/pub/PUBID8_1234

    Open Energy Info (EERE)

    MaxTech 21-May-2012 23:38 - 429 Throttled (bot load) Error 429 Throttled (bot load) Throttled (bot load) Guru Meditation: XID: 99456974...

  11. MSExcel Document (7k)

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    usrlocalmorph3etccatdocxls2csv -cutf-8 -g -M -l --timeout60 --error-logusrlocalmorph3texisnleeiaoutlookanytotx-errors.15607 --max-depth9...

  12. Ji-Woong Lee | Center for Gas SeparationsRelevant to Clean Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Max-Planck Institut fuer Kohlenforschung, Germany BSc and MSc in Chemistry, Sungkyunkwan University, Korea EFRC research: We are currently developing a methodology for a...

  13. Three years of Swift/BAT Survey of AGN: Reconciling Theory and...

    Office of Scientific and Technical Information (OSTI)

    A. ; Garching, Max Planck Inst., MPE Muenchen, Tech. U. Universe ; Gehrels, N. ; NASA, Goddard Publication Date: 2011-02-07 OSTI Identifier: 1004918 Report Number(s):...

  14. Advanced nickel base alloys for high strength, corrosion applications

    DOE Patents [OSTI]

    Flinn, John E.

    1998-01-01

    Improved nickel-base alloys of enhanced strength and corrosion resistance, produced by atomization of an alloy melt under an inert gas atmosphere and of composition 0-20Fe, 10-30Cr, 2-12Mo, 6 max. Nb, 0.05-3 V, 0.08 max. Mn, 0.5 max. Si, less than 0.01 each of Al and Ti, less than 0.05 each of P and S, 0.01-0.08C, less than 0.2N, 0.1 max. 0, bal. Ni.

  15. Advanced nickel base alloys for high strength, corrosion applications

    DOE Patents [OSTI]

    Flinn, J.E.

    1998-11-03

    Improved nickel-base alloys of enhanced strength and corrosion resistance, produced by atomization of an alloy melt under an inert gas atmosphere and of composition 0--20Fe, 10--30Cr, 2--12Mo, 6 max. Nb, 0.05--3 V, 0.08 max. Mn, 0.5 max. Si, less than 0.01 each of Al and Ti, less than 0.05 each of P and S, 0.01--0.08C, less than 0.2N, 0.1 max. 0, bal. Ni. 3 figs.

  16. FELIX: advances in modeling forward and inverse icesheet problems...

    Office of Scientific and Technical Information (OSTI)

    icesheet problems. Authors: Perego, Mauro ; Eldred, Michael S. ; Gunazburger, Max ; Salinger, Andrew G. ; Kalashnikova, Irina ; Ju, L. ; Hoffman, M. ; Leng, W. ; Price, S ;...

  17. Healthy Efficient Homes Research & Standards

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Smart ventilation savings (Turner & Walker, 2013 ) 9 Approach: Distinctive Characteristics ... Max Sherman Iain Walker Woody Delp Rengie Chan Brennan Less Brett Singer 10 Progress and ...

  18. A drone's-eye view of a wind turbine | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by Revolutionary Onboard Turbine Reshape) - Making it Real bowman2 Is a 'Mad Max' apocalypse possible? Luis-Felipe-WillcoxM&DV Monitoring and Diagnosis of Transformers...

  19. Why Do Atoms Explode When They Split? | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by Revolutionary Onboard Turbine Reshape) - Making it Real bowman2 Is a 'Mad Max' apocalypse possible? Luis-Felipe-WillcoxM&DV Monitoring and Diagnosis of Transformers...

  20. Physics Case for the International Linear Collider (Technical...

    Office of Scientific and Technical Information (OSTI)

    ; Munich, Max Planck Inst. ; Tanabe, Tomohiko ; Tokyo U., ICEPP ; Yu, Jaehoon ; Texas U., Arlington ; Wells, James D. ; Michigan U., MCTP ; Murayama, Hitoshi ; UC, ...

  1. Combined Heat and Power (CHP): Is It Right For Your Facility...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... of peak electric demand Digester Gas: Often times considered "free gas" - consider sizing for max. electricity given available volume of digester gas (selling back to utility). ...

  2. Building America Case Study: New Town Builders' Power of Zero...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Well done" - Diane Wildrick, ReMax Masters References Yankelovich, D. and Meer, D., "Rediscovering Market Segmentation." Harvard Business Review, February 2006. hbr.org Image ...

  3. Stimulated X-Ray Emission for Spectroscopy | Stanford Synchrotron...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Room 108A Speaker: Clemens Weninger, Max Planck Institute for the Physics of Complex Systems Program Description The recent advance of x-ray free electron lasers (XFELs)...

  4. Designs for a Linac-Ring LHeC (Conference) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Accel. Sci. Tech. ; Dainton, John ; Liverpool U. ; Klein, Max ; Liverpool U. ; Eide, Anders ; Paris U., VI-VII less Publication Date: 2012-06-21 OSTI Identifier: 1043845 ...

  5. A Method to Analyze the Diffuse Gamma-Ray Emission with the Fermi...

    Office of Scientific and Technical Information (OSTI)

    Park SLAC ; Moskalenko, Igor V. ; KIPAC, Menlo Park SLAC ; Porter, Troy ; UC, Santa Cruz ; Reimer, Olaf ; KIPAC, Menlo Park SLAC ; Strong, Andrew ; Garching, Max Planck ...

  6. Stencil Computation Optimization

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... To evaluate the effectiveness of our optimization strate- ... We also show that the more aggressive software-controlled ... a combination of explicit search for global max- ima with ...

  7. One Direction: Researchers grow nanocircuitry with semiconducting...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Matthieu Fortin-Deschenes, Pierre L. Levesque, Kyle M. McElhinny, Gerald J. Brady, Richard Rojas Delgado, Susmit Singha Roy, Andrew Mannix, Max G. Lagally, Paul G....

  8. Writing Effective Initial Summary Ratings Initial Summary Rating...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Writing an Effective ISR (max 8000 characters including spaces) Before writing: * Read definitions of rating levels and critical element targets carefully * Review Strategic Plan ...

  9. "Rip" Perkins, pioneering PPPL physicist and a design leader...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    describe Rip," Hammett recalled. "He was dedicated to helping others in scientific enterprises and to working in fusion." Claire Max, a professor of astronomy and astrophysics at...

  10. Management Council - Center for Solar and Thermal Energy Conversion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organization  MANAGEMENT COUNCIL Peter Green, Dir. MSE Rachel Goldman MSE Ctirad Uher Physics Jamie Phillips EECS Max Shtein MSE Roy Clarke Physics Ted Goodson III Chemistry ...

  11. Verification of the ideal magnetohydrodynamic response at rational...

    Office of Scientific and Technical Information (OSTI)

    New Jersey 08543, USA Max-Planck-Institut fr Plasmaphysik, Greifswald 17491, Germany Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA Publication Date:...

  12. The 2-79 keV X-ray Spectrum of the Circinus Galaxy with NuSTAR...

    Office of Scientific and Technical Information (OSTI)

    Park, IGC ; Brightman, M. ; Garching, Max Planck Inst., MPE ; Christensen, F. E. ; Denmark Tech U. ; Comastri, A. ; Bologna Observ. more ; Craig, W. W. ; Space Sci. ...

  13. Burlington Electric Department - Residential Energy Efficiency...

    Broader source: Energy.gov (indexed) [DOE]

    Lighting Air conditioners Compressed air Tankless Water Heater Maximum Rebate 3200 max incentive for air compressors Program Info Sector Name Utility Administrator Burlington...

  14. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    order stochastic collocation method for Bayesian inference in groundwater reactive transport modeling Zhang Guannan ORNL Webster Clayton G ORNL Gunzburger Max D ORNL Although...

  15. An adaptive sparse-grid high-order stochastic collocation method...

    Office of Scientific and Technical Information (OSTI)

    stochastic collocation method for Bayesian inference in groundwater reactive transport modeling Zhang, Guannan ORNL; Webster, Clayton G ORNL; Gunzburger, Max D ORNL...

  16. Opacity of iron, nickel, and copper plasmas in the x-ray wavelength...

    Office of Scientific and Technical Information (OSTI)

    2 more ; Max-Planck-Institut fuer Quantenoptik, D-85748 Garching 3 ; Institute of Nuclear Fusion, Universidad Politecnica de Madrid, Spain and Laboratoire d'Optique...

  17. Alchemix Corporation | Open Energy Information

    Open Energy Info (EERE)

    Sector: Hydro Product: Alchemix Corporation is a development stage company which has as its principal asset the HydroMax technology. References: Alchemix Corporation1 This...

  18. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Heidelberg, Max Planck Inst.Tokyo U., ICRR" Name Name ORCID Search Authors Type: All BookMonograph ConferenceEvent Journal Article Miscellaneous Patent Program Document Software...

  19. NuSTAR Detection of the Blazar B2 1023+25 at Redshift 5.3 (Journal...

    Office of Scientific and Technical Information (OSTI)

    Dept. Penn State U., IGC ; Chirstensen, F.E. ; Denmark Tech. U. more ; Giommi, P. ; ASDC, Frascati Rome Observ. ; Greiner, J. ; Garching, Max Planck Inst., MPE ; Hailey, ...

  20. The Mean and Scatter of the Velocity Dispersion-Optical Richness Relation

    Office of Scientific and Technical Information (OSTI)

    for MaxBCG Galaxy Clusters (Journal Article) | SciTech Connect The Mean and Scatter of the Velocity Dispersion-Optical Richness Relation for MaxBCG Galaxy Clusters Citation Details In-Document Search Title: The Mean and Scatter of the Velocity Dispersion-Optical Richness Relation for MaxBCG Galaxy Clusters The distribution of galaxies in position and velocity around the centers of galaxy clusters encodes important information about cluster mass and structure. Using the maxBCG galaxy cluster

  1. 2012 Aspen Winter Conference New Paradigms for Low-Dimensional...

    Office of Scientific and Technical Information (OSTI)

    Two organizers who did not attend the conference were Gabriel Aeppli (University College London & London Centre for Nanotechnology) and Andrea Cavalleri (Oxford University & Max ...

  2. Deirdre Monroe

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Christina Martos Hilton Deirdre Monroe Hai Ah Nam Denise Neudecker Phil & Monica Noll Amy Ross Bryant Roybal Max Schulze Denise Thronas Michael Torrez Jos Valdez Darleen...

  3. Hai Ah Nam

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Christina Martos Hilton Deirdre Monroe Hai Ah Nam Denise Neudecker Phil & Monica Noll Amy Ross Bryant Roybal Max Schulze Denise Thronas Michael Torrez Jos Valdez Darleen...

  4. Links

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Related Sites National Nanotechnology Initiative Nano Technology Industries Advanced Materials Research Institute Institute of Physics Max-Planck Institute for Kohlenforschung The...

  5. IN-VEHICLE, HIGH-POWER ENERGY STORAGE SYSTEMS

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engineering advisor C.Y. Wang - Battery and fuel cell research * Max Ripepi - Masters Engineering Mechanics advisor Charles Bakis - Self levitating flywheel design...

  6. None

    SciTech Connect (OSTI)

    Acosta, D.; The CDF Collaboration TITLE=Measuremen

    2005-05-27

    We present measurements of the lifetimes and polarization amplitudes for B{sub s}{sup 0} {yields} J/{psi}{phi} and B{sub d}{sup 0} {yields} J/{psi} K*{sup 0} decays. Lifetimes of the heavy (H) and light (L) mass eigenstates in the B{sub s}{sup 0} system are separately measured for the first time by determining the relative contributions of amplitudes with definite CP as a function of the decay time.

  7. Sandia National Laboratories: Careers: Students & Postdocs: Internships &

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Co-ops: Technical Institute Programs: Physical Sciences Institute Physical Sciences Institute Sandia interns work side-by-side with top scientists and engineers who serve as research mentors. Sandia interns work side-by-side with top scientists and engineers who serve as research mentors. When offered Summer only Who can apply Undergraduate and graduate students Location Sandia/California About PSI Graduate and undergraduate interns in the Physical Sciences Institute (PSI) at Sandia take

  8. Production of valuable hydrocarbons by flash pyrolysis of oil shale

    DOE Patents [OSTI]

    Steinberg, M.; Fallon, P.T.

    1985-04-01

    A process for the production of gas and liquid hydrocarbons from particulated oil shale by reaction with a pyrolysis gas at a temperature of from about 700/sup 0/C to about 1100/sup 0/C, at a pressure of from about 400 psi to about 600 psi, for a period of about 0.2 second to about 20 seconds. Such a pyrolysis gas includes methane, helium, or hydrogen. 3 figs., 3 tabs.

  9. Search for the Xi(2220) and Study of the X(3872) at BaBar

    SciTech Connect (OSTI)

    Mokhtar, Arafat Gabareen; /SLAC

    2012-06-13

    The BABAR Collaboration performed a search for x (2220) production in the initial-state radiation process e{sup +}e{sup -} {yields} {gamma} J/{Psi}, J/{Psi} {yields} {gamma}K{sup +}K{sup -} or J/{Psi} {yields} {gamma}K{sub S}{sup 0}K{sub S}{sup 0}. No evidence for the {xi} (2220) resonance has been found. The 90% confidence level upper limits on the product of branching fractions are sensitive to the spin and helicity hypotheses. These upper limits are of the order 10{sup -5}, below the values reported in previous experiments. Also at BABAR, the decays B {yields} J/{Psi} {pi}{sup +}{pi}{sup -}{pi}{sup 0}K are studied to search for the decay X(3872) {yields} J/{Psi}{gamma}. This search yields a four standard deviation evidence for X(3872) {yields} J/{Psi}{omega}, with product branching fractions of {Beta}(B{sup +} {yields} X(3872)K{sup +}) x {Beta}(X(3872) {yields} J/{Psi}{omega}) = [0.6 {+-} 0.2(stat) {+-} 0.1(syst)] x 10{sup -5}, and {Beta}(B{sup 0} {yields} X(3872)K{sup 0}) x {Beta}(X(3872) {yields} J/y{Psi}) = [0.6 {+-} 0.3(stat) {+-} 0.1(syst)] x 10{sup -5}. A detailed study of the {pi}{sup +}{pi}{sup -}{pi}{sup 0} mass distribution from X(3872) decay favors a negative-parity assignment but does not rule out the positive-parity hypothesis.

  10. Effect of MgO Additive on Volumetric Expansion of Self-Degradable Cements

    SciTech Connect (OSTI)

    Sugama T.; Warren, J.; Butcher, T.

    2011-09-30

    We identified hard-burned magnesium oxide (MgO) as a suitable expansive additive for improving the plugging performance of self-degradable, temporary sodium silicate-activated slag/Class C fly ash (SSASC) blend cement sealers into rock fractures in Enhanced Geothermal Systems (EGSs). MgO extended the volumetric expansion of sealers during their exposure to a hydrothermal environment at 200 C under pressures, ranging from 300 to 1500 psi. A great expansion ratc of 19.3% was observed by adding 3.0 wt% MgO under 300 psi pressure, thus promising to plug thoroughly inner fracture. When the pressure was increased from 300 psi to 1500 psi, the expansion rate of cement markedly reduced, corresponding to the formaLion of crack-free specimens and the improvement of compressive strength. However, with 3.0 wt% MgO, the specimens still engendered the generation of numerous visual cracks, although they were prepared under a high pressure of 1500 psi. The effective content of MgO in minimizing and eliminating the generation of cracks was 2.0 wt%, which provided a moderate expansion of {ge} 0.5%. The compressive strength of 2.0 wt% MgO specimens made under a pressure of 300 psi rose {approx} 1.7-fold to 4816 psi with an increasing pressure to 1500 psi. The in-situ growth of brucite crystal formed by the hydrothermal hydration of MgO was responsive for such an expansion of the SSASC cement; meanwhile. two crystalline hydrothermal reaction products, 1.1 nm tobermorite and calcium silicate hydrated, contributed to the development of the sealer's compressive strength. Thus, the increasing pressure seems to suppress and control a growth rate of brucite crystal in response to a lower extension of expansion. Furthermore, all MgO-conlaining SSASC sealers possessed the water-catalyzed self-degradable properties.

  11. Thermal nature of charmonium transverse momentum spectra from Au-Au collisions at the highest energies available at the BNL Relativistic Heavy Ion Collider (RHIC)

    SciTech Connect (OSTI)

    Akkelin, S. V.; Sinyukov, Yu. M.; Braun-Munzinger, P.

    2010-03-15

    We analyze the transverse momentum distribution of J/psi mesons produced in Au+Au collisions at the top RHIC energy within a blast-wave model that accounts for a possible inhomogeneity of the charmonium distribution and/or flow fluctuations. The results imply that the transverse momentum spectra of J/psi, phi, and OMEGA hadrons measured at the RHIC can be described well if kinetic freeze-out takes place just after chemical freeze-out for these particles.

  12. Search for the B{sub c} meson in hadronic Z{sup 0} decays using the OPAL detector at LEP

    SciTech Connect (OSTI)

    Herndon, M.F.

    1999-01-01

    A search for decays of the B{sub c} meson was performed using data collected from 1990--1995 with the OPAL detector on or near the Z{sup 0} peak at LEP. The decay channels B{sub c}{sup +} {r_arrow} J/{psi}{pi}{sup +}, B{sub c}{sup +} {r_arrow} J/{psi}a{sub 1}{sup +} and B{sub c}{sup +} {r_arrow} J/{psi}{ell}{sup +}{nu} were investigated, where {ell} denotes an electron or a muon. Two candidates are observed in the mode B{sub c}{sup +} {r_arrow} J/{psi}{pi}{sup +}, with an estimated background of (0.63 {+-} 0.20) events. The weighted mean of the masses of the two candidates is (6.32 {+-} 0.06) GeV/c{sup 2}, which is consistent with the predicted mass of the B{sub c} meson. One candidate event is observed in the mode B{sub c}{sup +} {r_arrow} J/{psi}{ell}{sup +}{nu}, with an estimated background of (0.82 {+-} 0.19) events. No candidate events are observed in the B{sub c}{sup +} {r_arrow} J/{psi}a{sub 1}{sup +} decay mode, with an estimated background of (1.10 {+-} 0.22) events. Upper bounds at the 90% confidence level are set on the production rates for these processes.

  13. Hydraulic properties of adsorbed water films in unsaturated porous media

    SciTech Connect (OSTI)

    Tokunaga, Tetsu K.

    2009-03-01

    Adsorbed water films strongly influence residual water saturations and hydraulic conductivities in porous media at low saturations. Hydraulic properties of adsorbed water films in unsaturated porous media were investigated through combining Langmuir's film model with scaling analysis, without use of any adjustable parameters. Diffuse double layer influences are predicted to be important through the strong dependence of adsorbed water film thickness (f) on matric potential ({Psi}) and ion charge (z). Film thickness, film velocity, and unsaturated hydraulic conductivity are predicted to vary with z{sup -1}, z{sup -2}, and z{sup -3}, respectively. In monodisperse granular media, the characteristic grain size ({lambda}) controls film hydraulics through {lambda}{sup -1} scaling of (1) the perimeter length per unit cross sectional area over which films occur, (2) the critical matric potential ({Psi}{sub c}) below which films control flow, and (3) the magnitude of the unsaturated hydraulic conductivity when {Psi} < {Psi}{sub c}. While it is recognized that finer textured sediments have higher unsaturated hydraulic conductivities than coarser sands at intermediate {Psi}, the {lambda}{sup -1} scaling of hydraulic conductivity predicted here extends this understanding to very low saturations where all pores are drained. Extremely low unsaturated hydraulic conductivities are predicted under adsorbed film-controlled conditions (generally < 0.1 mm y{sup -1}). On flat surfaces, the film hydraulic diffusivity is shown to be constant (invariant with respect to {Psi}).

  14. Quantum mechanics problems in observer's mathematics

    SciTech Connect (OSTI)

    Khots, Boris; Khots, Dmitriy

    2012-11-06

    This work considers the ontology, guiding equation, Schrodinger's equation, relation to the Born Rule, the conditional wave function of a subsystem in a setting of arithmetic, algebra and topology provided by Observer's Mathematics (see www.mathrelativity.com). Observer's Mathematics creates new arithmetic, algebra, geometry, topology, analysis and logic which do not contain the concept of continuum, but locally coincide with the standard fields. Certain results and communications pertaining to solutions of these problems are provided. In particular, we prove the following theorems: Theorem I (Two-slit interference). Let {Psi}{sub 1} be a wave from slit 1, {Psi}{sub 2} - from slit 2, and {Psi} = {Psi}{sub 1}+{Psi}{sub 2}. Then the probability of {Psi} being a wave equals to 0.5. Theorem II (k-bodies solution). For W{sub n} from m-observer point of view with m>log{sub 10}((2 Multiplication-Sign 10{sup 2n}-1){sup 2k}+1), the probability of standard expression of Hamiltonian variation is less than 1 and depends on n,m,k.

  15. Instructions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 value in eV 2 sin 2 2 e,max (90% CL): upper limit in sin 2 2 e , at 90% confidence level sin 2 2 e,max (3 CL): upper limit in sin 2 2 e , at 3 confidence...

  16. Towards III-V solar cells on Si: Improvement in the crystalline quality of Ge-on-Si virtual substrates through low porosity porous silicon buffer layer and annealing

    SciTech Connect (OSTI)

    Calabrese, Gabriele; Baricordi, Stefano; Bernardoni, Paolo; Fin, Samuele; Guidi, Vincenzo; Vincenzi, Donato

    2014-09-26

    A comparison between the crystalline quality of Ge grown on bulk Si and on a low porosity porous Si (pSi) buffer layer using low energy plasma enhanced chemical vapor deposition is reported. Omega/2Theta coupled scans around the Ge and Si (004) diffraction peaks show a reduction of the Ge full-width at half maximum (FWHM) of 22.4% in presence of the pSi buffer layer, indicating it is effective in improving the epilayer crystalline quality. At the same time atomic force microscopy analysis shows an increase in root means square roughness for Ge grown on pSi from 38.5 nm to 48.0 nm, as a consequence of the larger surface roughness of pSi compared to bulk Si. The effect of 20 minutes vacuum annealing at 580C is also investigated. The annealing leads to a FWHM reduction of 23% for Ge grown on Si and of 36.5% for Ge on pSi, resulting in a FWHM of 101 arcsec in the latter case. At the same time, the RMS roughness is reduced of 8.8% and of 46.5% for Ge grown on bulk Si and on pSi, respectively. The biggest improvement in the crystalline quality of Ge grown on pSi with respect to Ge grown on bulk Si observed after annealing is a consequence of the simultaneous reorganization of the Ge epilayer and the buffer layer driven by energy minimization. A low porosity buffer layer can thus be used for the growth of low defect density Ge on Si virtual substrates for the successive integration of III-V multijunction solar cells on Si. The suggested approach is simple and fast thus allowing for high throughput-, moreover is cost effective and fully compatible with subsequent wafer processing. Finally it does not introduce new chemicals in the solar cell fabrication process and can be scaled to large area silicon wafers.

  17. Triangularity and dipole asymmetry in relativistic heavy ion collisions

    SciTech Connect (OSTI)

    Teaney, Derek; Yan Li

    2011-06-15

    We introduce a cumulant expansion to parametrize possible initial conditions in relativistic heavy ion collisions. We show that the cumulant expansion converges and that it can systematically reproduce the results of Glauber type initial conditions. At third order in the gradient expansion the cumulants characterize the triangularity psi}{sub 3,3})> and the dipole asymmetry psi}{sub 1,3})> of the initial entropy distribution. We show that for midperipheral collisions the orientation angle of the dipole asymmetry {psi}{sub 1,3} has a 20% preference out of plane. This leads to a small net v{sub 1} out of plane. In peripheral and midcentral collisions the orientation angles {psi}{sub 1,3} and {psi}{sub 3,3} are strongly correlated, but this correlation disappears towards central collisions. We study the ideal hydrodynamic response to these cumulants and determine the associated v{sub 1}/{epsilon}{sub 1} and v{sub 3}/{epsilon}{sub 3} for a massless ideal gas equation of state. The space time development of v{sub 1} and v{sub 3} is clarified with figures. These figures show that v{sub 1} and v{sub 3} develop toward the edge of the nucleus, and consequently the final spectra are more sensitive to the viscous dynamics of freezeout. The hydrodynamic calculations for v{sub 3} are provisionally compared to Alver and Roland fit of STAR inclusive two-particle correlation functions. Finally, we propose to measure the v{sub 1} associated with the dipole asymmetry and the correlations between {psi}{sub 1,3} and {psi}{sub 3,3} by measuring a two-particle correlation with respect to the participant plane Psi}{sub PP})>. The hydrodynamic prediction for this correlation function is several times larger than a correlation currently measured by the STAR collaboration Psi}{sub PP})>. This experimental measurement would provide convincing evidence for the hydrodynamic and geometric interpretation of two-particle correlations at RHIC.

  18. Process for detoxifying coal tars

    DOE Patents [OSTI]

    Longwell, John P. (Cambridge, MA); Peters, William A. (Arlington, MA)

    1983-01-01

    A process for treating liquid hydrocarbons to remove toxic, mutagenic and/or carcinogenic aromatic hydrocarbons comprises feeding the hydrocarbons into a reactor where vapors are thermally treated in contact with a catalyst consisting essentially of calcium oxide or a calcium oxide containing mineral. Thermally treating liquid hydrocarbons in contact with calcium oxide preferentially increases the cracking of aromatics thus producing a product having a reduced amount of aromatic compounds.

  19. Raw neutron scattering data for strain measurement of hydraulically loaded granite and marble samples in triaxial stress state

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Polsky, Yarom

    2014-05-23

    This entry contains raw data files from experiments performed on the Vulcan beamline at the Spallation Neutron Source at Oak Ridge National Laboratory using a pressure cell. Cylindrical granite and marble samples were subjected to confining pressures of either 0 psi or approximately 2500 psi and internal pressures of either 0 psi, 1500 psi or 2500 psi through a blind axial hole at the center of one end of the sample. The sample diameters were 1.5" and the sample lengths were 6". The blind hole was 0.25" in diameter and 3" deep. One set of experiments measured strains at points located circumferentially around the center of the sample with identical radii to determine if there was strain variability (this would not be expected for a homogeneous material based on the symmetry of loading). Another set of experiments measured load variation across the radius of the sample at a fixed axial and circumferential location. Raw neutron diffraction intensity files and experimental parameter descriptions are included.

  20. Mechanics of compression drying solid wood cubes and chip mats

    SciTech Connect (OSTI)

    Haygreen, J.G.

    1982-10-01

    Wood cubes and chip mats were compressed in a cell under ram face pressures to 13,000 psi. The amount of water removed was determined for a range of species of various specific gravities and at several green moisture contents (MCs). The time dependence of the process was also studied. The purpose of this work was to describe the mechanics of compression drying which must be considered in designing commercial equipment. Green MC of wood chip mats was reduced to 45 to 50 percent MC (31% to 33% MC, wet basis) at pressures of 13,000 psi. At low pressures of 1,000 to 2,000 psi, moisture was reduced to 60 to 75 percent MC (38% to 43% MC, wet basis). There was a significantly greater moisture reduction at these low pressures if the pressure is maintained for up to 2 minutes rather than releasing it immediately once the target pressure is obtained. Water can be removed from high density species but pressures required are higher by a factor of 2 to 3. The chip mat is reduced to about one-sixth of its original volume at 2,000 psi and one-seventh at 6,000 psi. When pressing cubes of high green MC, about 7,000 foot-pounds of work (equivalent to 9 Btu) applied to the wood will remove up to 1 pound of water. (Refs. 9).

  1. Raw neutron scattering data for strain measurement of hydraulically loaded granite and marble samples in triaxial stress state

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Polsky, Yarom

    This entry contains raw data files from experiments performed on the Vulcan beamline at the Spallation Neutron Source at Oak Ridge National Laboratory using a pressure cell. Cylindrical granite and marble samples were subjected to confining pressures of either 0 psi or approximately 2500 psi and internal pressures of either 0 psi, 1500 psi or 2500 psi through a blind axial hole at the center of one end of the sample. The sample diameters were 1.5" and the sample lengths were 6". The blind hole was 0.25" in diameter and 3" deep. One set of experiments measured strains at points located circumferentially around the center of the sample with identical radii to determine if there was strain variability (this would not be expected for a homogeneous material based on the symmetry of loading). Another set of experiments measured load variation across the radius of the sample at a fixed axial and circumferential location. Raw neutron diffraction intensity files and experimental parameter descriptions are included.

  2. PADD 5 Transportation Fuels Markets

    U.S. Energy Information Administration (EIA) Indexed Site

    ... during periods of supply disruption and market change. ... to manage distribution system inefficiencies and ... Aromatic hydrocarbons are a class of chemical substances ...

  3. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... hyperspectral (1) particle phase (1) pollution (1) polycyclic aromatic hydrocarbons (1) ... (SOA) dominate atmospheric organic aerosols that affect climate, air quality, and health. ...

  4. Molecular catalytic coal liquid conversion (Conference) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    derived from organometallic compounds that are capable of reducing monocyclic aromatic compounds under very mild conditions. Accomplishments and conclusions are discussed. ...

  5. Molecular catalytic coal liquid conversion. Quarterly report...

    Office of Scientific and Technical Information (OSTI)

    Coal liquids can be hydrogenated catalyzed by Catalyst 2 include monocyclic aromatic ... PROGRESS REPORT; ORGANOMETALLIC COMPOUNDS; EXPERIMENTAL DATA Word Cloud More Like ...

  6. Molecular catalytic coal liquid conversion. Quarterly report...

    Office of Scientific and Technical Information (OSTI)

    the hydrogenation of other unactivated aromatic hydrocarbons such as toluene, ... EXPERIMENTAL DATA; ORGANOMETALLIC COMPOUNDS; PH VALUE Word Cloud More Like This Full ...

  7. Structure of the human M2 muscarinic acetylcholine receptor bound...

    Office of Scientific and Technical Information (OSTI)

    ... Subject: 60 APPLIED LIFE SCIENCES; 59 BASIC BIOLOGICAL SCIENCES; ACETYLCHOLINE; AMINO ACIDS; AROMATICS; AUTONOMIC NERVOUS SYSTEM; BIOCHEMISTRY; BIOLOGY; CENTRAL NERVOUS SYSTEM; ...

  8. Search for: All records | SciTech Connect

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    ... Filter Results Filter by Subject acetylcholine (1) amino acids (1) applied life sciences (1) aromatics (1) autonomic nervous system (1) basic biological sciences (1) biochemistry ...

  9. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... organism in laboratory cocultures that syntrophically oxidize fatty and aromatic acids. ... Genome Sequences of Industrially Relevant Saccharomyces cerevisiae Strain M3707, Isolated ...

  10. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Archive Nevada Test Site (NTS), Mercury, NV (United States) Nevada Test Site... sciences (1) aromatics (1) autonomic nervous system (1) basic biological sciences (1) ...

  11. Electrolyte salts for nonaqueous electrolytes (Patent) | DOEPatents

    Office of Scientific and Technical Information (OSTI)

    The aromatic moiety may be reversibly oxidizedreduced at a potential slightly higher than the working potential of the positive electrode in the lithium ion battery. The metal ...

  12. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    Molecular catalytic hydrogenation of aromatic hydrocarbons and hydrotreating of coal liquids Yang Shiyong Stock L M COAL LIGNITE AND PEAT CHEMISTRY COAL LIQUIDS HYDROGENATION...

  13. Catalysis Center for Energy Innovation: University of Delaware

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. ... and hemicellulose, the production of green aromatics, the hydrodeoxygenation of ...

  14. Facile One-Pot Synthesis of Porphyrin Based Porous Polymer Networks...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by the aromatic substitution reactions of pyrrole and aldehydes. PPN-24(Fe) shows high catalytic efficiency as a biomimetic catalyst in the oxidation reaction of...

  15. ALS Evidence Confirms Combustion Theory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    hydrocarbons (PAHs) are hydrocarbons-organic compounds containing only carbon and hydrogen-that are composed of multiple aromatic rings (organic rings in which the...

  16. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Yasuo The reduction of aromatic compounds into their dihydro derivatives by dissolving metalalcohol systems (the Birch reduction) is a useful methodology in organic synthesis. ...

  17. Substituted 1,2-azaborine heterocycles

    DOE Patents [OSTI]

    Liu, Shih-Yuan; Lamm, Ashley

    2014-12-30

    Aromatic heterocycles incorporating boron and nitrogen atoms, in particular, 1,2-azaborine compounds having the formula ##STR00001## and their use as synthetic intermediates.

  18. This research was supported as part of the Catalysis Center for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    wood, agricultural wastes, and energy crops) directly into aromatics and olefins with zeolite catalysts in a fluidized bed reactor in a process called catalytic fast pyrolysis. ...

  19. DIRECTIONS AND TIPS FOR USING INTEGRITY Accessing Integrity:

    Energy Savers [EERE]

    DIRECTIONS AND TIPS FOR USING INTEGRITY Accessing Integrity: The website address for Integrity is www.integrity.gov. When you get to the website, click on the yellow box labeled "Login to Integrity." Integrity is connected to the OMB MAX Central Authentication Service. Employees who have previously used OMB MAX should use their MAX user ID and password. Do not use the CIC or PIV login option. This is not enabled for DOE Integrity filers. If you used Integrity last year, you have an OMB

  20. A Search for the singlet-P state h(c)(1**1 P(1)) of charmonium in proton-antiproton annihilations at Fermilab experiment E835p

    SciTech Connect (OSTI)

    Joffe, David Noah

    2004-12-01

    The author presents the results of a search for the spin-singlet P-wave state h{sub c}(1{sup 1}P{sub 1}) of charmonium formed through proton-antiproton annihilation at Fermilab experiment E835. The decay channels which were studied were p{bar p} {yields} J/{psi} + X {yields} e{sup +}e{sup -} + X, p{bar p} {yields} J/{psi} + {pi}{sup 0} {yields} e{sup +}e{sup -} + {gamma}{gamma}, p{bar p} {yields} J/{psi} + {pi}{sup 0}{pi}{sup 0} {yields} e{sup +}e{sup -} + 4{gamma}, and the neutral channel p{bar p} {yields} {eta}{sub c}{gamma} {yields} ({gamma}{gamma}){gamma}. The decay p{bar p} {yields} J/{psi}{gamma} {yields} e{sup +}e{sup -}{gamma}, into which {sup 1}P{sub 1} decay is forbidden by C-parity conservation, was also examined for comparison. The 90% confidence upper limits for the decay channels studied in the mass range 3525.1-3527.3 MeV for a {sup 1}P{sub 1} resonance with a presumed width of 1.0 MeV were determined to be B(p{bar p} {yields} {sup 1}P{sub 1}) x B({sup 1}P{sub 1} {yields} J/{psi} + X) {le} 1.8 x 10{sup -7}, B(p{bar p} {yields} {sup 1}P{sub 1}) x B({sup 1}P{sub 1} {yields} J/{psi} + {pi}{sup 0}) {le} 1.2 x 10{sup -7}, and B(p{bar p} {yields} {sup 1}P{sub 1}) x B({sup 1}P{sub 1} {yields} J/{psi}{gamma}) {le} 1.0 x 10{sup -7}. No evidence for a {sup 1}P{sub 1} enhancement was observed in either of the two additional reactions studied; p{bar p} {yields} J/{psi} + {pi}{sup 0}{pi}{sup 0} {yields} e{sup +}e{sup -} + 4{gamma} and p{bar p} {yields} {eta}{sub c}{gamma} {yields} ({gamma}{gamma}){gamma}.

  1. Multilayer compressive seal for sealing in high temperature devices

    DOE Patents [OSTI]

    Chou, Yeong-Shyung; Stevenson, Jeffry W.

    2007-08-21

    A mica based compressive seal has been developed exhibiting superior thermal cycle stability when compared to other compressive seals known in the art. The seal is composed of compliant glass or metal interlayers and a sealing (gasket) member layer composed of mica that is infiltrated with a glass forming material, which effectively reduces leaks within the seal. The compressive seal shows approximately a 100-fold reduction in leak rates compared with previously developed hybrid seals after from 10 to about 40 thermal cycles under a compressive stress of from 50 psi to 100 psi at temperatures in the range from 600.degree. C. to about 850.degree. C.

  2. Low-cost thin-film absorber/evaporator for an absorption chiller. Final report, May 1992-April 1993

    SciTech Connect (OSTI)

    Lowenstein, A.; Sibilia, M.

    1993-04-01

    The feasibility of making the absorber and evaporator of a small lithium-bromide absorption chiller from thin plastic films was studied. Tests were performed to measure (1) pressure limitations for a plastic thin-film heat exchanger, (2) flow pressure-drop characteristics, (3) air permeation rates across the plastic films, and (4) creep characteristics of the plastic films. Initial tests were performed on heat exchangers made of either low-density polyethylene (LDPE), high-density polyethylene (HDPE), or a LDPE/HDPE blend. While initial designs for the heat exchanger failed at internal pressures of only 5 to 6 psi, the final design could withstand pressures of 34 psi.

  3. End plate assembly having a two-phase fluid-filled bladder and method for compressing a fuel cell stack

    DOE Patents [OSTI]

    Carlstrom, Jr., Charles M.

    2001-01-01

    An end plate assembly is disclosed for use in a fuel cell assembly in which the end plate assembly includes a housing having a cavity, and a bladder receivable in the cavity and engageable with the fuel cell stack. The bladder includes a two-phase fluid having a liquid portion and a vapor portion. Desirably, the two-phase fluid has a vapor pressure between about 100 psi and about 600 psi at a temperature between about 70 degrees C. to about 110 degrees C.

  4. A relativistic quark model with infrared confinement and the tetraquark state

    SciTech Connect (OSTI)

    Dubnicka, S.; Dubnickova, A. Z.; Ivanov, M. A.; Koerner, J. G.; Saidullaeva, G. G.

    2011-05-23

    We explore the consequences of treating the X(3872) meson as a tetraquark bound state. As dynamical framework we employ a relativistic constituent quark model which includes infrared confinement in an effective way. We calculate the decay widths of the observed channels X{yields}J/{psi}+2{pi}(3{pi}) and X{yields}D-bar{sup 0}+D{sup 0}+{pi}{sup 0} via the intermediate off-shell states X{yields}J/{psi}+{rho}({omega}) and X{yields}D-bar+D*. For reasonable values of the size parameter {Lambda}{sub X} of the X(3872) we find consistency with the available experimental data.

  5. Recent progress of magnetocaloric effect and magnetic refrigerant materials of Mn compounds (invited)

    SciTech Connect (OSTI)

    Wada, H. Takahara, T.; Katagiri, K.; Ohnishi, T.; Soejima, K.; Yamashita, K.

    2015-05-07

    Magnetocaloric and related properties of Ru and Ni substituted (MnFe){sub 2}(PSi) are presented. It is found that Ru and Ni are effective doping elements to reduce the thermal hysteresis of (MnFe){sub 2}(PSi). The origin of the thermal hysteresis is discussed on the basis of a thermodynamic model. It is shown that the elastic energy is responsible for the thermal hysteresis. We also show recent developments of the production process of Mn compounds in an industrial scale.

  6. The Lifetime of a beautiful and charming meson: B_c lifetime measured using the D0 detector

    SciTech Connect (OSTI)

    Welty-Rieger, Leah Christine; /Indiana U.

    2008-09-01

    Using approximately 1.3 fb{sup -1} of data collected by the D0 detector between 2002 and 2006, the lifetime of the B{sub c}{sup {+-}} meson is studied in the B{sub c}{sup {+-}} {yields} J/{psi}{mu}{sup {+-}} + X final state. Using an unbinned likelihood simultaneous fit to J/{psi} + {mu} invariant mass and lifetime distributions, a signal of 810 {+-} 80(stat.) candidates is estimated and a lifetime measurement made of: {tau}(B{sub c}{sup {+-}}) = 0.448{sub -0.036}{sup +0.038}(stat) {+-} 0.032(sys) ps.

  7. Detonating apparatus

    DOE Patents [OSTI]

    Johnston, Lawrence H.

    1976-01-01

    1. Apparatus for detonation of high explosive in uniform timing comprising in combination, an outer case, spark gap electrodes insulatedly supported in spaced relationship within said case to form a spark gap, high explosive of the class consisting of pentaerythritol tetranitrate and trimethylene trinitramine substantially free from material sensitive to detonation by impact compressed in surrounding relation to said electrodes including said spark gap under a pressure from about 100 psi to about 500 psi, said spark gap with said compressed explosive therein requiring at least 1000 volts for sparking, and means for impressing at least 1000 volts on said spark gap.

  8. Disordered organic electronic materials based on non-benzenoid 1,6-methano[10]annulene rings

    DOE Patents [OSTI]

    Tovar, John D; Streifel, Benjamin C; Peart, Patricia A

    2014-10-07

    Conjugated polymers and small molecules including the nonplanar aromatic 1,6-methano[10]annulene ring structure along with aromatic subunits, such as diketopyrrolopyrrole, and 2,1,3-benzothiadiazole, substituted with alkyl chains in a "Tail In," "Tail Out," or "No Tail" regiochemistry are disclosed.

  9. CONTENTS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... ENVIRONMENTS February 18, 2010 Rev 1 Page 4 1 Kevlar is a registered trademark of DuPont de Nemours. 2 K-Spec is a registered trademark of SlingMax. 18.4 MARKING AND POSTING ...

  10. Manhattan Project: A Miniature Solar System, 1890s-1919

    Office of Scientific and Technical Information (OSTI)

    concepts with Max Planck's quantum theory to produce the first modern model of the atom. ... on the history of "Chemistry" and "Physics" in Roy Porter and Marilyn Ogilvie, eds., ...

  11. Scientists use plasma shaping to control turbulence in stellarators...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    at the U.S. Department of Energy's Princeton Plasma Physics Laboratory (PPPL) and the Max Planck Institute of Plasma Physics in Germany have devised a new method for minimizing...

  12. X-ray imaging, spacecraft nuclear fission and cosmic ray contraband...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and its partners are among the honorees. July 8, 2013 MiniMAX is a battery powered, digital x-ray imaging system that is completely self-contained, lightweight, compact and...

  13. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    CreatorsAuthors contains: "Webster, Clayton G" Sort by Relevance Sort by Date (newest ... Filter by Author Webster, Clayton G (8) Gunzburger, Max D (6) Webster, Clayton G ORNL ...

  14. Project of the Month | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Washington River Protection Services Company to implement a WiMAX-based communications infrastructure at Hanford to augment the existing fiber optic and Wi-Fi-based systems...

  15. Beamline 8.3.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    BEAMLINE INFORMATION Operational Yes Source characteristics Superbend magnet (5.0 tesla, single pole) Energy range 5-17 keV (1% max flux) Monochromator Double flat crystal,...

  16. Hanford Site C Tank Farm Meeting Summary

    Office of Environmental Management (EM)

    o To avoid these problems, they will use a bounding max based on data since not enough data to figure central tendency. o C-200 tanks had big difference between estimated...

  17. H2 Refuel H-Prize Overview and Q&A

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... dispensing pressure 350 bar Max dispensing time (standard fill) 10 hours 60 minutes Min. ... Home Community Home & Community 1 350 bar or higher 10 hours or less 60 minutes or ...

  18. schmid-99.PDF

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Miami, Florida P. Formenti and M. O. Andreae Max Planck Institute for Chemistry Mainz, Germany V. N. Kapustin University of Hawaii Honolulu, Hawaii T. S. Bates and P. K. Quinn...

  19. SEP Success Story: Warding Off Energy Vampires and Phantom Loads...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Max Schreck in Nosferatu, presumably climbing the stairs to plug in some unused appliances. | Photo from Wikipedia, Public Domain in the U.S. Are Energy Vampires Sucking You Dry?

  20. Energy Tomorrow | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    2011 Serena DeBeer of Cornell University and the Max Planck Institute for Bioinorganic Chemistry, led the the team that performed crucial experiments at SLAC. Dr. DeBeer is...

  1. Scientists use plasma shaping to control turbulence in stellarators...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    regions of the highest strength shown in yellow. The MPX design is named for coauthors Harry Mynick and Neil Pomphrey of PPPL and Pavlos Xanthopoulos of the Max Planck Institute...

  2. Microsoft Word - Y12GammaAppendicesAand B.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    %) Max Dose 2174 Dose(mrem) Frequency 0 200 400 600 800 0 20 40 60 80 Quarterly Y-12 Film Badge Gamma Dose for 1952 Note change in vertical scale, frequency or number of workers...

  3. Iran Thomas Auditorium, 8600

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Biology Matthias Scheffler Fritz-Haber-Institut der Max-Planck-Gesellschaft, Berlin, Germany CNMS D D I I S S C C O O V V E E R R Y Y SEMINAR SERIES Abstract: Dispersive or van...

  4. Index of /datasets/files/41/pub/PUBID8_3941

    Open Energy Info (EERE)

    Exist 22-May-2012 01:04 - DIR MaxTech 22-May-2012 01:04 - 429 Throttled (bot load) Error 429 Throttled (bot load) Throttled (bot load) Guru Meditation: XID: 1006824916 Varnish...

  5. Index of /datasets/files/41/pub/PUBID8_0332

    Open Energy Info (EERE)

    Apr-2012 11:07 - DIR MaxTech 18-Apr-2012 11:07 - 429 Throttled (bot load) Error 429 Throttled (bot load) Throttled (bot load) Guru Meditation: XID: 979859487 Varnish cache...

  6. Index of /datasets/files/41/pub/PUBID8_1506

    Open Energy Info (EERE)

    Exist 21-May-2012 23:49 - DIR MaxTech 21-May-2012 23:49 - 429 Throttled (bot load) Error 429 Throttled (bot load) Throttled (bot load) Guru Meditation: XID: 1006824909 Varnish...

  7. News | Princeton Plasma Physics Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A screen shows multiple images of the first plasma in the W7-X control room. (Photo by Sam Lazerson) PPPL physicist Novimir Pablant and Andreas Langenberg, of the Max Planck...

  8. Next-Generation Genetics in Plants: Evolutionary Trade-off, Immunity and Speciation (2010 JGI User Meeting)

    ScienceCinema (OSTI)

    Wiegel, Detlef

    2011-04-25

    Detlef Wiegel from the Max Planck Institute for Developmental Biology on "Next-generation genetics in plants: Evolutionary tradeoffs, immunity and speciation" on March 25, 2010 at the 5th Annual DOE JGI User Meeting

  9. Ford Debuts Solar Energy Concept Car

    Broader source: Energy.gov [DOE]

    The Ford Motor Company unveiled the C-MAX Solar Energi Concept, a sun-powered vehicle with the potential to deliver what a plug-in hybrid offers without depending on the electric grid for fuel.

  10. CX-012059: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Testing of Irradiated MAX Phase Materials CX(s) Applied: B3.6 Date: 03/13/2014 Location(s): South Carolina Offices(s): Savannah River Operations Office

  11. Microsoft PowerPoint - poster for ARM 2007 5

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    m as function of z n . D m decreases with z n . This indicates ice crystal has bigger max dimension with deceasing height . FIG 12 Variation of averaged area ratio as function of z...

  12. tiers | OpenEI Community

    Open Energy Info (EERE)

    This is likely due to users not understanding the meaning of "Max kWh"--often I see things like: "300, 700, 1000" (derived from "first 300, next 700, greater than 1000") which...

  13. Tritium Instrument Demonstration Station (TIDS)

    Office of Environmental Management (EM)

    - 488 nm; 200 mW max power RoMack Inc. 20' fiber optic (6 around 1) on " VCR fitting Kaiser Optical Holospec- f1.8 I VIS w 488 grating Andor DV-420-OE CCD detector Detection...

  14. BPA Visitor Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and is located at BPA headquarters in Portland, Oregon at 905 NE 11th Ave. (Public Transit @ the Lloyd Center MAX Station). Many of the publications available in the Visitor...

  15. Sputnik Engineering AG | Open Energy Information

    Open Energy Info (EERE)

    Zip: CH-2502 Sector: Solar Product: Manufacturer of SolarMax grid tie inverters for photovoltaic applications. References: Sputnik Engineering AG1 This article is a stub. You can...

  16. Posters Comparison Between General Circulation Model Simulation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    GCM used for this study is from the Max-Planck Institute and the University of Hamburg, Germany (ECHAM3); it is described in detail by Roeckner et al. (1992). The simulation for...

  17. "Group IV Nanomembranes, Nanoribbons, and Quantum Dots: Processing...

    Office of Scientific and Technical Information (OSTI)

    This theoretical project has been carried out in close interaction with the experimental project at UW-Madison under the same title led by PI Max Lagally and co-PI Mark Eriksson. ...

  18. Property:Buildings/ModelType | Open Energy Information

    Open Energy Info (EERE)

    Minimum Cost Max Tech PV Takeoff Cost Neutral 30% Energy Savings 50% Energy Savings 70% Energy Savings Other Pages using the property "BuildingsModelType" Showing 12 pages using...

  19. The NuSTAR View of Nearby Compton-thick Active Galactic Nuclei...

    Office of Scientific and Technical Information (OSTI)

    Dept. ; Brandt, W.N. ; Pennsylvania U. Penn State U., University Park, IGC ; Brightman, M. ; Garching, Max Planck Inst., MPE Denmark, Tech. U. ; Christensen, F.E. ; Craig, W.W. ...

  20. Policy Specialist | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    apply under the Merit Promotion announcement. Work Schedule Full time Work Type Permanent Series 1101 Salary Basis Per Year Grade 1313 Salary Min 87,994.00 Salary Max 114,390...