National Library of Energy BETA

Sample records for materials wood residues

  1. Proposed plant will turn wood residues into synfuel

    SciTech Connect (OSTI)

    Not Available

    1981-01-01

    A group of entrepreneurs plan to have a plant operating in Burney, CA. The projected facility will produce an estimated 21,000 gallons of oil per day, converting about 300 tons of raw material. Converting cellulose into synthetic fuel is superior to alcohol production. The process yields approximately 84 gallons of synthetic fuel per ton of raw material. The entire LHG (liquid hydrogen gas) patented facility is self-sufficient and releases only carbon dioxide into the atmosphere. Synfuel production is a three-phase process. First, butyl alcohol (butanol) and acetone are produced from a portion of the raw material. This is facilitated by adding to the raw material a bacteria culture. The planned facility in Burney will have thirty-five 2100 gallon fermentation tanks and will produce 1.25 million gallons of butanol. Next, organic material is blended with water and is pumped into patented LHG catalytic converters, charged with carbon monoxide gas as a catalyst and then heated to 350 degrees C at 2000 to 5000 psi. Here, the organic material is converted to No. 4 oil with bituminous tar as a residue. A patented gasifier system produces the carbon monoxide catalyst plus COH (carbon hydroxide) gas. The COH is used to power a gas turbine driving a 100 kW generator and a central hydraulic pump. The facility, which will be energy self-sufficient, will have approximately 50 kW of excess power to sell to the local utility power grid. Finally, the No. 4 oil, butanol and liquified COH gas are blended to produce any grade fuel oil or a gasoline substitute of very high octane.

  2. Effect of natural ageing on volume stability of MSW and wood waste incineration residues

    SciTech Connect (OSTI)

    Gori, Manuela; Bergfeldt, Britta; Reichelt, Jürgen; Sirini, Piero

    2013-04-15

    Highlights: ► Natural weathering on BA from MSW and wood waste incineration was evaluated. ► Type of mineral phases, pH and volume stability were considered. ► Weathering reactions effect in improved stability of the materials. - Abstract: This paper presents the results of a study on the effect of natural weathering on volume stability of bottom ash (BA) from municipal solid waste (MSW) and wood waste incineration. BA samples were taken at different steps of treatment (fresh, 4 weeks and 12 weeks aged) and then characterised for their chemical and mineralogical composition and for volume stability by means of the mineralogical test method (M HMVA-StB), which is part of the German quality control system for using aggregates in road construction (TL Gestein-StB 04). Changes of mineralogical composition with the proceeding of the weathering treatment were also monitored by leaching tests. At the end of the 12 weeks of treatment, almost all the considered samples resulted to be usable without restrictions in road construction with reference to the test parameter volume stability.

  3. Industrial recycling of glass, plastic and wood materials

    SciTech Connect (OSTI)

    Caccavo, F.N.; Posusney, J.R.

    1998-12-31

    The intent of this paper is to discuss in detail the development and implementation of a recycling program encompassing these three residual waste streams at a major plant site of a large United States company. The paper will review the history of the program`s development, the vendor selection and recycling processes, the initial efforts to include failures and successes, and the cost recovery and profit that can be realized through a well-managed recycling program. The facility that is the subject of this paper is located approximately 20 lies north west of Philadelphia, Pa and supports a site population of over 6,200 employees working in three divisions of the parent company. The primary business of this firm is the manufacture, distribution, and sale of pharmaceutical drugs. This plant is the company`s largest facility engaging its employees in predominantly research and manufacturing operations. The manufacturing operations being the largest division encompassing the widest range of activities from the receipt of raw material through packaging and shipping operations. This site and the company it represents enjoy an excellent relationship within the community stemming in part to the commitment to environmental stewardship demonstrated by this successful program. The site retains its own internal waste management and disposal operations for the wide variety of refuse materials generated and it is this department which is responsible for the creation and maintenance of the site`s extensive recycling effort. The paper will review the ongoing development of these elements of this company`s growing recycling operations and attempt to demonstrate that extensive recycling can be both a productive and cost effective alternative to conventional disposal through incineration`s or landfill.

  4. A manual for implementing residual radioactive material guidelines

    SciTech Connect (OSTI)

    Gilbert, T.L.; Yu, C.; Yuan, Y.C.; Zielen, A.J.; Jusko, M.J.; Wallo, A. III

    1989-06-01

    This manual presents information for implementing US Department of Energy (DOE) guidelines for residual radioactive material at sites identified by the Formerly Utilized Sites Remedial Action Program (FUSRAP) and the Surplus Facilities Management Program (SFMP). It describes the analysis and models used to derive site-specific guidelines for allowable residual concentrations of radionuclides in soil and the design and use of the RESRAD computer code for calculating guideline values. It also describes procedures for implementing DOE policy for reducing residual radioactivity to levels that are as low as reasonably achievable. 36 refs., 16 figs, 22 tabs.

  5. Integrating the Clearance in NPP Residual Material Management

    SciTech Connect (OSTI)

    Garcia-Bermejo, R.; Lamela, B.

    2008-01-15

    Previous Experiences in decommissioning projects are being used to optimize the residual material management in NPP, metallic scrap usually. The approach is based in the availability of a materials Clearance MARSSIM-based methodology developed and licensed in Spain. A typical project includes the integration of segregation, decontamination, clearance, quality control and quality assurance activities. The design is based in the clearance methodology features translating them into standard operational procedures. In terms of ecological taxes and final disposal costs, significant amounts of money could be saved with this type of approaches. The last clearance project managed a total amount of 405 tons scrap metal and a similar amount of other residual materials occupying a volume of 1500 m{sup 3}. After less than a year of field works 251 tons were finally recycled in a non-licensed smelting facility. The balance was disposed as LILW. In the planning phase the estimated cost savings were 4.5 Meuro. However, today a VLLW option is available in European countries so, the estimated cost savings are reduced to 1.2 Meuro. In conclusion: the application of materials clearance in NPP decommissioning lessons learnt to the NPP residual material management is an interesting management option. This practice is currently going on in Spanish NPP and, in a preliminary view, is consistent with the new MARSAME Draft. An interesting parameter is the cost of 1 m3 of recyclable scrap. The above estimates are very project specific because in the segregation process other residual materials were involved. If the effect of this other materials is removed the estimated Unit Cost were in this project around 1700 euro/m{sup 3}, this figure is clearly below the above VLLW disposal cost of 2600 euro. In a future project it appears feasible to descend to 839 euro/m{sup 3} and if it became routine values and is used in big Decommissioning projects, around 600 euro/m{sup 3} or below possibly could

  6. Mercury emissions during cofiring of sub-bituminous coal and biomass (chicken waste, wood, coffee residue, and tobacco stalk) in a laboratory-scale fluidized bed combustor

    SciTech Connect (OSTI)

    Yan Cao; Hongcang Zhou; Junjie Fan; Houyin Zhao; Tuo Zhou; Pauline Hack; Chia-Chun Chan; Jian-Chang Liou; Wei-ping Pan

    2008-12-15

    Four types of biomass (chicken waste, wood pellets, coffee residue, and tobacco stalks) were cofired at 30 wt % with a U.S. sub-bituminous coal (Powder River Basin Coal) in a laboratory-scale fluidized bed combustor. A cyclone, followed by a quartz filter, was used for fly ash removal during tests. The temperatures of the cyclone and filter were controlled at 250 and 150{sup o}C, respectively. Mercury speciation and emissions during cofiring were investigated using a semicontinuous mercury monitor, which was certified using ASTM standard Ontario Hydra Method. Test results indicated mercury emissions were strongly correlative to the gaseous chlorine concentrations, but not necessarily correlative to the chlorine contents in cofiring fuels. Mercury emissions could be reduced by 35% during firing of sub-bituminous coal using only a quartz filter. Cofiring high-chlorine fuel, such as chicken waste (Cl = 22340 wppm), could largely reduce mercury emissions by over 80%. When low-chlorine biomass, such as wood pellets (Cl = 132 wppm) and coffee residue (Cl = 134 wppm), is cofired, mercury emissions could only be reduced by about 50%. Cofiring tobacco stalks with higher chlorine content (Cl = 4237 wppm) did not significantly reduce mercury emissions. Gaseous speciated mercury in flue gas after a quartz filter indicated the occurrence of about 50% of total gaseous mercury to be the elemental mercury for cofiring chicken waste, but occurrence of above 90% of the elemental mercury for all other cases. Both the higher content of alkali metal oxides or alkali earth metal oxides in tested biomass and the occurrence of temperatures lower than 650{sup o}C in the upper part of the fluidized bed combustor seemed to be responsible for the reduction of gaseous chlorine and, consequently, limited mercury emissions reduction during cofiring. 36 refs., 3 figs. 1 tab.

  7. Method for measuring residual stresses in materials by plastically deforming the material and interference pattern comparison

    DOE Patents [OSTI]

    Pechersky, Martin J.

    1995-01-01

    A method for measuring residual stress in a material comprising the steps of establishing a speckle pattern on the surface with a first laser then heating a portion of that pattern with an infrared laser until the surface plastically deforms. Comparing the speckle patterns before and after deformation by subtracting one pattern from the other will produce a fringe pattern that serves as a visual and quantitative indication of the degree to which the plasticized surface responded to the stress dung heating and enables calculation of the stress.

  8. U.S. Department of Energy Guidelines for Residual Radioactive Material at

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Formerly Utilized Sites Remedial Action Program and Remote Surplus Facilities Management Program Sites | Department of Energy U.S. Department of Energy Guidelines for Residual Radioactive Material at Formerly Utilized Sites Remedial Action Program and Remote Surplus Facilities Management Program Sites U.S. Department of Energy Guidelines for Residual Radioactive Material at Formerly Utilized Sites Remedial Action Program and Remote Surplus Facilities Management Program Sites U.S. Department

  9. Measurement of wood/plant cell or composite material attributes with computer assisted tomography

    DOE Patents [OSTI]

    West, Darrell C.; Paulus, Michael J.; Tuskan, Gerald A.; Wimmer, Rupert

    2004-06-08

    A method for obtaining wood-cell attributes from cellulose containing samples includes the steps of radiating a cellulose containing sample with a beam of radiation. Radiation attenuation information is collected from radiation which passes through the sample. The source is rotated relative to the sample and the radiation and collecting steps repeated. A projected image of the sample is formed from the collected radiation attenuation information, the projected image including resolvable features of the cellulose containing sample. Cell wall thickness, cell diameter (length) and cell vacoule diameter can be determined. A system for obtaining physical measures from cellulose containing samples includes a radiation source, a radiation detector, and structure for rotating the source relative to said sample. The system forms an image of the sample from the radiation attenuation information, the image including resolvable features of the sample.

  10. Derivation of uranium residual radioactive material guidelines for the former Alba Craft Laboratory site, Oxford, Ohio

    SciTech Connect (OSTI)

    Nimmagadda, M.; Faillace, E.; Yu, C.

    1994-01-01

    Residual radioactive material guidelines for uranium were derived for the former Alba Craft Laboratory site in Oxford, Ohio. This site has been identified for remedial action under the Formerly Utilized Sites Remedial Action Program (FUSRAP) of the US Department of Energy (DOE). Single nuclide and total uranium guidelines were derived on the basis of the requirement that the 50-year committed effective dose equivalent to a hypothetical individual who lives or works in the immediate vicinity of the former Alba Craft Laboratory site should not exceed a dose of 30 mrem/yr following remedial action for the current use and likely future use scenarios or a dose of 100 mrem/yr for less likely future use scenarios (Yu et al. 1993). The DOE residual radioactive material guideline computer code, RESRAD, which implements the methodology described in the DOE manual for implementing residual radioactive material guidelines, was used in this evaluation.

  11. Gas Generation Test Support for Transportation and Storage of Plutonium Residue Materials - Part 1: Rocky Flats Sand, Slag, and Crucible Residues

    SciTech Connect (OSTI)

    Livingston, R.R.

    1999-08-24

    The purpose of this report is to present experimental results that can be used to establish one segment of the safety basis for transportation and storage of plutonium residue materials.

  12. Measurement of residual stresses in deposited films of SOFC component materials

    SciTech Connect (OSTI)

    Kato, T.; Momma, A.; Nagata, S.; Kasuga, Y.

    1996-12-31

    The stress induced in Solid oxide fuel cells (SOFC)s has important influence on the lifetime of SOFC. But the data on stress in SOFC and mechanical properties of SOW component materials have not been accumulated enough to manufacture SOFC. Especially, the data of La{sub 1-x}Sr{sub x}MnO{sub 3} cathode and La{sub 1-x}Sr{sub x}CrO{sub 3} interconnection have been extremely limited. We have estimated numerically the dependences of residual stress in SOFC on the material properties, the cell structure and the fabrication temperatures of the components, but these unknown factors have caused obstruction to simulate the accurate behavior of residual stress. Therefore, the residual stresses in deposited La{sub 1-x}Sr{sub x}MnO{sub 3} and La{sub 1-x}Sr{sub x}CrO{sub 3} films are researched by the observation of the bending behavior of the substrate strips. The films of SOFC component materials were prepared by the RF sputtering method, because: (1) It can fabricate dense films of poor sinterable material such as La{sub 1-x}Sr{sub x}CrO{sub 3} compared with sintering or plasma spray method. (2) For the complicated material such as perovskite materials, the difference between the composition of a film and that of a target material is generally small. (3) It can fabricate a thick ceramics film by improving of the deposition rate. For example, Al{sub 2}O{sub 3} thick films of 50{mu}m can be fabricated with the deposition rate of approximately 5{mu}m/h industrially. In this paper, the dependence of residual stress on the deposition conditions is defined and mechanical properties of these materials are estimated from the results of the experiments.

  13. Determination of residual monomers resulting from the chemical polymerization process of dental materials

    SciTech Connect (OSTI)

    Boboia, S.; Moldovan, M.; Ardelean, I.

    2013-11-13

    The residual monomer present in post-polymerized dental materials encourages premature degradation of the reconstructed tooth. That is why the residual monomer should be quantified in a simple, fast, accurate and reproducible manner. In our work we propose such an approach for accurate determination of the residual monomer in dental materials which is based on low-field nuclear magnetic resonance (NMR) relaxometry. The results of the NMR approach are compared with those of the high performance liquid chromatography (HPLC) technique. The samples under study contain the main monomers (2,2-bis[4-(2-hydroxy-3-methacryloyloxypropoxy)phenyl]propane and triethylene glycol dimethacrylate) constituting the liquid phase of most dental materials and an initiator. Two samples were analyzed with different ratios of chemical initiation systems: N,N-dimethyl-p-toluide: benzoyl peroxide (1:2 and 0.7:1.2). The results obtained by both techniques highlight that by reducing the initiator the polymerization process slows down and the amount of residual monomer reduces. This prevents the premature degradation of the dental fillings and consequently the reduction of the biomaterial resistance.

  14. Recommended Procedures for Measuring Radon Fluxes from Disposal Sites of Residual Radioactive Materials

    SciTech Connect (OSTI)

    Young,, J. A.; Thomas, V. W.; Jackson, P. 0.

    1983-03-01

    This report recornmenrls instrumentation and methods suitable for measuring radon fluxes emanating from covered disposal sites of residual radioactive materials such as uranium mill tailings. Problems of spatial and temporal variations in radon flux are discussed and the advantages and disadvantages of several instruments are examined. A year-long measurement program and a two rnonth measurement rnethodology are then presented based on the inherent difficulties of measuring average radon flux over a cover using the recommended instrumentation.

  15. A Residual Mass Ballistic Testing Method to Compare Armor Materials or Components (Residual Mass Ballistic Testing Method)

    SciTech Connect (OSTI)

    Benjamin Langhorst; Thomas M Lillo; Henry S Chu

    2014-05-01

    A statistics based ballistic test method is presented for use when comparing multiple groups of test articles of unknown relative ballistic perforation resistance. The method is intended to be more efficient than many traditional methods for research and development testing. To establish the validity of the method, it is employed in this study to compare test groups of known relative ballistic performance. Multiple groups of test articles were perforated using consistent projectiles and impact conditions. Test groups were made of rolled homogeneous armor (RHA) plates and differed in thickness. After perforation, each residual projectile was captured behind the target and its mass was measured. The residual masses measured for each test group were analyzed to provide ballistic performance rankings with associated confidence levels. When compared to traditional V50 methods, the residual mass (RM) method was found to require fewer test events and be more tolerant of variations in impact conditions.

  16. Improving material and energy recovery from the sewage sludge and biomass residues

    SciTech Connect (OSTI)

    Kliopova, Irina Makarskienė, Kristina

    2015-02-15

    Highlights: • SRF production from 10–40 mm fraction of pre-composted sludge and biomass residues. • The material and energy balance of compost and SRF production. • Characteristics of raw materials and classification of produced SRF. • Results of the efficiency of energy recovery, comparison analysis with – sawdust. - Abstract: Sewage sludge management is a big problem all over the world because of its large quantities and harmful impact on the environment. Energy conversion through fermentation, compost production from treated sludge for agriculture, especially for growing energetic plants, and treated sludge use for soil remediation are widely used alternatives of sewage sludge management. Recently, in many EU countries the popularity of these methods has decreased due to the sewage sludge content (heavy metals, organic pollutions and other hazards materials). This paper presents research results where the possibility of solid recovered fuel (SRF) production from the separate fraction (10–40 mm) of pre-composted materials – sewage sludge from municipal waste water treatment plant and biomass residues has been evaluated. The remaining fractions of pre-composted materials can be successfully used for compost or fertiliser production, as the concentration of heavy metals in the analysed composition is reduced in comparison with sewage sludge. During the experiment presented in this paper the volume of analysed biodegradable waste was reduced by 96%: about 20% of input biodegradable waste was recovered to SRF in the form of pellets with 14.25 MJ kg{sup −1} of the net calorific value, about 23% were composted, the rest – evaporated and discharged in a wastewater. The methods of material-energy balances and comparison analysis of experiment data have been chosen for the environmental impact assessment of this biodegradable waste management alternative. Results of the efficiency of energy recovery from sewage sludge by SRF production and burning

  17. Daniel Wood

    Broader source: Energy.gov [DOE]

    Daniel Wood is the Data Visualization and Cartographic Specialist in the Office of Public Affairs at the Department of Energy. He develops creative and interactive ways of viewing the Energy...

  18. Manual for implementing residual radioactive material guidelines using RESRAD, Version 5.0

    SciTech Connect (OSTI)

    Yu, C.; Zielen, A.J.; Cheng, J.J.

    1993-09-01

    This manual presents information for implementing US Department of Energy (DOE) guidelines for residual radioactive material. It describes the analysis and models used to derive site-specific guidelines for allowable residual concentrations of radionuclides in soil and the design and use of the RESRAD computer code for calculating doses, risks, and guideline values. It also describes procedures for implementing DOE policy for reducing residual radioactivity to levels that are as low as reasonably achievable. Two new pathways, radon inhalation and soil ingestion, have been added to RESRAD. Twenty-seven new radionuclides have also been added, and the cutoff half-life for associated radionuclides has been reduced to six months. Other major improvements to the RESRAD code include the ability to run sensitivity analyses, the addition of graphical output, user-specified dose factors, updated databases, an improved groundwater transport model, optional input of a groundwater concentration and a solubility constant, special models for tritium and carbon-14, calculation of cancer incidence risk, and the use of a mouse with menus.

  19. Radiological Modeling for Determination of Derived Concentration Levels of an Area with Uranium Residual Material - 13533

    SciTech Connect (OSTI)

    Perez-Sanchez, Danyl [CIEMAT, Avenida Complutense 40, 28040, Madrid (Spain)] [CIEMAT, Avenida Complutense 40, 28040, Madrid (Spain)

    2013-07-01

    As a result of a pilot project developed at the old Spanish 'Junta de Energia Nuclear' to extract uranium from ores, tailings materials were generated. Most of these residual materials were sent back to different uranium mines, but a small amount of it was mixed with conventional building materials and deposited near the old plant until the surrounding ground was flattened. The affected land is included in an area under institutional control and used as recreational area. At the time of processing, uranium isotopes were separated but other radionuclides of the uranium decay series as Th-230, Ra-226 and daughters remain in the residue. Recently, the analyses of samples taken at different ground's depths confirmed their presence. This paper presents the methodology used to calculate the derived concentration level to ensure that the reference dose level of 0.1 mSv y-1 used as radiological criteria. In this study, a radiological impact assessment was performed modeling the area as recreational scenario. The modelization study was carried out with the code RESRAD considering as exposure pathways, external irradiation, inadvertent ingestion of soil, inhalation of resuspended particles, and inhalation of radon (Rn-222). As result was concluded that, if the concentration of Ra-226 in the first 15 cm of soil is lower than, 0.34 Bq g{sup -1}, the dose would not exceed the reference dose. Applying this value as a derived concentration level and comparing with the results of measurements on the ground, some areas with a concentration of activity slightly higher than latter were found. In these zones the remediation proposal has been to cover with a layer of 15 cm of clean material. This action represents a reduction of 85% of the dose and ensures compliance with the reference dose. (authors)

  20. Table 3.6 Selected Wood and Wood-Related Products in Fuel Consumption, 2010;

    U.S. Energy Information Administration (EIA) Indexed Site

    Table 3.6 Selected Wood and Wood-Related Products in Fuel Consumption, 2010; Level: National and Regional Data; Row: Selected NAICS Codes; Column: Energy Sources; Unit: Trillion Btu. Wood Residues and Wood-Related Pulping Liquor Wood Byproducts and NAICS or Biomass Agricultural Harvested Directly from Mill Paper-Related Code(a) Subsector and Industry Black Liquor Total(b) Waste(c) from Trees(d) Processing(e) Refuse(f) Total United States 311 Food 0 44 43 * * 1 311221 Wet Corn Milling 0 1 1 0 0 0

  1. From the Woods to the Refinery

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Woods to the Refinery CORRIM Life Cycle Analyses of Woody Feedstocks Dr. Steve Kelley ... composition, sugar types, residue fuel value * TC models are sensitive to MC, much less ...

  2. Derivation of guidelines for uranium residual radioactive material in soil at the New Brunswick Site, Middlesex County, New Jersey

    SciTech Connect (OSTI)

    Dunning, D.; Kamboj, S.; Nimmagadda, M.; Yu, C.

    1996-02-01

    Residual radioactive material guidelines for uranium in soil were derived for the New Brunswick Site, located in Middlesex County, New Jersey. This site has been designated for remedial action under the Formerly Utilized Sites Remedial Action Program of the US Department of Energy (DOE). Residual radioactive material guidelines for individual radionuclides of concern and total uranium were derived on the basis of the requirement that the 50-year committed effective dose equivalent to a hypothetical individual who lives or works in the immediate vicinity of the New Brunswick Site should not exceed a dose of 30 mrem/yr following remedial action for the current-use and likely future-use scenarios or a dose of 100 mrem/yr for less likely future-use scenarios. The DOE residual radioactive material guideline computer code, RESRAD, was used in this evaluation; RESRAD implements the methodology described in the DOE manual for establishing residual radioactive material guidelines. The guidelines derived in this report are intended to apply to the remediation of these remaining residual radioactive materials at the site. The primary radionuclides of concern in these remaining materials are expected to be radium-226 and, to a lesser extent, natural uranium and thorium. The DOE has established generic cleanup guidelines for radium and thorium in soil; however, cleanup guidelines for other radionuclides must be derived on a site-specific basis.

  3. Release process for non-real property containing residual radioactive material

    SciTech Connect (OSTI)

    Ranek, N.L.; Chen, S.Y.; Kamboj, S.; Hensley, J.; Burns, D.; Fleming, R.; Warren, S.; Wallo, A.

    1997-02-01

    It is DOE`s objective to operate its facilities and to conduct its activities so that radiation exposures to members of the public are maintained within acceptable limits and exposures to residual radioactive materials are controlled. To accomplish this, DOE has adopted Order DOE 5400.51 `Radiation Protection of the Public and the Environment`, and will be promulgating IO CR Part 834 to codify and clarify the requirements of DOE 5400.5. Under both DOE 5400.5 and 10 CR Part 834, radioactively contaminated DOE property is prohibited from release unless specific actions have been completed prior to the release. This paper outlines a ten-step process that, if followed, will assist DOE Operations and contractor personnel in ensuring that the required actions established by Order DOE 5400.5 and 10 CR Part 834 have been appropriately completed prior to the release for reuse or recycle of non-real property (e.g., office furniture, computers, hand tools, machinery, vehicles and scrap metal). Following the process will assist in ensuring that radiological doses to the public from the released materials will meet applicable regulatory standards and be as low as reasonably achievable (ALARA).

  4. Table 3.6 Selected Wood and Wood-Related Products in Fuel...

    U.S. Energy Information Administration (EIA) Indexed Site

    Unit: Trillion Btu." ,,"S e l e c t e d","W o o d","a n d","W o o d -","R e l a t e d","P r o d u c t s" ,,,,,"B i o m a s s" ,,,,,,"Wood Residues" ,,,,,,"and","Wood-Related" " ...

  5. Isolation of levoglucosan from lignocellulosic pyrolysis oil derived from wood or waste newsprint

    DOE Patents [OSTI]

    Moens, L.

    1995-07-11

    A method is provided for preparing high purity levoglucosan from lignocellulosic pyrolysis oils derived from wood or waste newsprint. The method includes reducing wood or newsprint to fine particle sizes, treating the particles with a hot mineral acid for a predetermined period of time, and filtering off and drying resulting solid wood or newsprint material; pyrolyzing the dried solid wood or newsprint material at temperatures between about 350 and 375 C to produce pyrolysis oils; treating the oils to liquid-liquid extraction with methyl isobutyl ketone to remove heavy tar materials from the oils, and to provide an aqueous fraction mixture of the oils containing primarily levoglucosan; treating the aqueous fraction mixtures with a basic metal salt in an amount sufficient to elevate pH values to a range of about 12 to about 12.5 and adding an amount of the salt in excess of the amount needed to obtain the pH range to remove colored materials of impurities from the oil and form a slurry, and freeze-drying the resulting slurry to produce a dry solid residue; and extracting the levoglucosan from the residue using ethyl acetate solvent to produce a purified crystalline levoglucosan. 2 figs.

  6. Isolation of levoglucosan from lignocellulosic pyrolysis oil derived from wood or waste newsprint

    DOE Patents [OSTI]

    Moens, Luc

    1995-01-01

    A method is provided for preparing high purity levoglucosan from lignocellulosic pyrolysis oils derived from wood or waste newsprint. The method includes reducing wood or newsprint to fine particle sizes, treating the particles with a hot mineral acid for a predetermined period of time, and filtering off and drying resulting solid wood or newsprint material; pyrolyzing the dried solid wood or newsprint material at temperatures between about 350.degree. and 375.degree. C. to produce pyrolysis oils; treating the oils to liquid-liquid extraction with methyl isobutyl ketone to remove heavy tar materials from the oils, and to provide an aqueous fraction mixture of the oils containing primarily levoglucosan; treating the aqueous fraction mixtures with a basic metal salt in an amount sufficient to elevate pH values to a range of about 12 to about 12.5 and adding an amount of the salt in excess of the amount needed to obtain the pH range to remove colored materials of impurities from the oil and form a slurry, and freeze-drying the resulting slurry to produce a dry solid residue; and extracting the levoglucosan from the residue using ethyl acetate solvent to produce a purified crystalline levoglucosan.

  7. Wood and Pellet Heating

    Broader source: Energy.gov [DOE]

    Looking for an efficient, renewable way to heat your home? Wood or pellets are renewable fuel sources, and modern wood and pellet stoves are efficient heaters.

  8. Urban Mining: Quality and quantity of recyclable and recoverable material mechanically and physically extractable from residual waste

    SciTech Connect (OSTI)

    Di Maria, Francesco Micale, Caterina; Sordi, Alessio; Cirulli, Giuseppe; Marionni, Moreno

    2013-12-15

    Highlights: • Material recycling and recovery from residual waste by physical and mechanical process has been investigated. • About 6% of recyclable can be extracted by NIR and 2-3Dimension selector. • Another 2% of construction materials can be extracted by adopting modified soil washing process. • Extracted material quality is quite high even some residual heavy metal have been detected by leaching test. - Abstract: The mechanically sorted dry fraction (MSDF) and Fines (<20 mm) arising from the mechanical biological treatment of residual municipal solid waste (RMSW) contains respectively about 11% w/w each of recyclable and recoverable materials. Processing a large sample of MSDF in an existing full-scale mechanical sorting facility equipped with near infrared and 2-3 dimensional selectors led to the extraction of about 6% w/w of recyclables with respect to the RMSW weight. Maximum selection efficiency was achieved for metals, about 98% w/w, whereas it was lower for Waste Electrical and Electronic Equipment (WEEE), about 2% w/w. After a simulated lab scale soil washing treatment it was possible to extract about 2% w/w of inert exploitable substances recoverable as construction materials, with respect to the amount of RMSW. The passing curve showed that inert materials were mainly sand with a particle size ranging from 0.063 to 2 mm. Leaching tests showed quite low heavy metal concentrations with the exception of the particles retained by the 0.5 mm sieve. A minimum pollutant concentration was in the leachate from the 10 and 20 mm particle size fractions.

  9. Derivation of residual radioactive material guidelines for uranium in soil at the Middlesex Sampling Plant Site, Middlesex, New Jersey

    SciTech Connect (OSTI)

    Dunning, D.E.

    1995-02-01

    Residual radioactive material guidelines for uranium in soil were derived for the Middlesex Sampling Plant (MSP) site in Middlesex, New Jersey. This site has been designated for remedial action under the Formerly Utilized Sites Remedial Action Program (FUSRAP) of the US Department of Energy. The site became contaminated from operations conducted in support of the Manhattan Engineer District (MED) and the Atomic Energy Commission (AEC) between 1943 and 1967. Activities conducted at the site included sampling, storage, and shipment of uranium, thorium, and beryllium ores and residues. Uranium guidelines for single radioisotopes and total uranium were derived on the basis of the requirement that the 50-year committed effective dose equivalent to a hypothetical individual living or working in the immediate vicinity of the MSP site should not exceed a dose of 30 mrem/yr following remedial action for the current-use and likely future-use scenarios or a dose of 100 mrem/yr for less likely future-use scenarios. The RESRAD computer code, which implements the methodology described in the DOE manual for establishing residual radioactive material guidelines, was used in this evaluation. Four scenarios were considered for the site. These scenarios vary regarding future land use at the site, sources of water used, and sources of food consumed.

  10. Strengthening, Crack Arrest And Multiple Cracking In Brittle Materials Using Residual Stresses.

    DOE Patents [OSTI]

    Green, David J.; Sglavo, Vincenzo M.; Tandon, Rajan

    2003-02-11

    Embodiments include a method for forming a glass which displays visible cracking prior to failure when subjected to predetermined stress level that is greater than a predetermined minimum stress level and less than a failure stress level. The method includes determining a critical flaw size in the glass and introducing a residual stress profile to the glass so that a plurality of visible cracks are formed prior to failure when the glass is subjected to a stress that is greater than the minimum stress level and lower than the critical stress. One method for forming the residual stress profile includes performing a first ion exchange so that a first plurality of ions of a first element in the glass are exchanged with a second plurality of ions of a second element that have a larger volume than the first ions. A second ion exchange is also performed so that a plurality of the second ions in the glass are exchanged back to ions of the first element.

  11. Hazardous Materials Verification and Limited Characterization Report on Sodium and Caustic Residuals in Materials and Fuel Complex Facilities MFC-799/799A

    SciTech Connect (OSTI)

    Gary Mecham

    2010-08-01

    This report is a companion to the Facilities Condition and Hazard Assessment for Materials and Fuel Complex Sodium Processing Facilities MFC-799/799A and Nuclear Calibration Laboratory MFC-770C (referred to as the Facilities Condition and Hazards Assessment). This report specifically responds to the requirement of Section 9.2, Item 6, of the Facilities Condition and Hazards Assessment to provide an updated assessment and verification of the residual hazardous materials remaining in the Sodium Processing Facilities processing system. The hazardous materials of concern are sodium and sodium hydroxide (caustic). The information supplied in this report supports the end-point objectives identified in the Transition Plan for Multiple Facilities at the Materials and Fuels Complex, Advanced Test Reactor, Central Facilities Area, and Power Burst Facility, as well as the deactivation and decommissioning critical decision milestone 1, as specified in U.S. Department of Energy Guide 413.3-8, “Environmental Management Cleanup Projects.” Using a tailored approach and based on information obtained through a combination of process knowledge, emergency management hazardous assessment documentation, and visual inspection, this report provides sufficient detail regarding the quantity of hazardous materials for the purposes of facility transfer; it also provides that further characterization/verification of these materials is unnecessary.

  12. Performance oriented packaging testing of nine Mk 3 Mod 0 signal containers in PPP-B-621 wood box for packing group II solid hazardous materials. Final report

    SciTech Connect (OSTI)

    Libbert, K.J.

    1992-10-01

    A PPP-B-621 wood box containing nine Mk 3 Mod 0 Signal containers was tested for conformance to Performance Oriented Packaging criteria established by Code of Federal Regulations Title 49 CFR. The container was tested with a gross weight of 123.3 pounds (56 kilograms) and met all requirements.

  13. Lightweight combustion residues-based structural materials for use in mines. Technical report, September 1--November 30, 1994

    SciTech Connect (OSTI)

    Chugh, Y.P.; Zhang, Y.; Ghosh, A.K.; Palmer, S.R.

    1994-12-31

    The overall goal of the project is to develop a 70--80 pcf, 2,500--3,000 psi-compressive-strength cellular concrete-type product from PCC fly ash, PCC bottom ash, and/or FBC spent bed ash alone or in suitable combination thereof. The developed combustion residue-based lightweight structural material will be used to replace wooden posts and crib members in underground mines. This report outlines the work completed in the first quarter of the project. The density gradient centrifuge (DGC) has been used to separate a power plant fly ash sample into fractions of different density. Each of the fly ash fractions obtained by DGC, an aliquot of the unseparated fly ash and an aliquot of a magnetic component of the fly ash, were digested in strong acids following the procedures outlined in ASTM 3050. Preliminary experiments have also been carried out to study the effect of mix proportions and curing regimes on the strength and density on the developed material. The DGC separation test reveals that most of the fly ash sample (approx. 90%) has a density above 1.9 g/cm{sup 3}. Indeed, nearly half of the sample has a density greater than 2.4 g/cm{sup 3}. Since only a very small amount of this fly ash has a reasonably low specific gravity, it appears unlikely at this time that enough low density material would be isolated to significantly enhance lightweight concrete production using fractionated material. A series of mixes have been made using fly ash, sodium silicate, cement, sand and water. Preliminary tests show that both cement and sodium silicate can be used as the binders to develop residues-based lightweight concrete. To date, compressive strength as high as 1,290 psi have been achieved with a density of 133 pcf, with 50 g of cement, 50 g of fly ash and 300 g of sand. Most of the work during the first quarter was done to understand the characteristics of the component materials.

  14. Evaluation of residual shale oils as feedstocks for valuable carbon materials

    SciTech Connect (OSTI)

    Fei, You Qing; Derbyshire, F. [Univ. of Kentucky, Lexington, KY (United States)

    1995-12-31

    Oil shale represents one of the largest fossil fuel resources in the US and in other pans of the world. Beginning in the 1970s until recently, there was considerable research and development activity directed primarily to technologies for the production of transportation fuels from oil shale. Due to the low cost of petroleum, as with other alternate fuel strategies, oil shale processing is not economically viable at present. However, future scenarios can be envisaged in which non-petroleum resources may be expected to contribute to the demand for hydrocarbon fuels and chemicals, with the expectation that process technologies can be rendered economically attractive. There is potential to improve the economics of oil shale utilization through broadening the spectrum of products that can be derived from this resource, and producing added-value materials that are either unavailable or more difficult to produce from other sources. This concept is by no means original. The history of oil shale development shows that most attempts to commercialize oil shale technology have relied upon the marketing of by-products. Results are presented on carbonization and the potential for generating a pitch that could serve as a precursur material.

  15. Potential role of lignin in tomorrow's wood utilization technologies

    SciTech Connect (OSTI)

    Glasser, W.G.

    1981-03-01

    Low-grade timber supplies and wood processing residues are presently converted into paper products, used for fuel, or remain totally unused. Competition for this resource will continue to mount, particularly when manufacturers of chemicals and liquid fuels enter the market with new technologies now under development. The type of technology that concentrates on depolymerization of carbohydrates will generate large quantities of lignin-rich residues. The potential of these lignins to contribute to the economic feasibility of new chemical wood process technologies may involve degradative depolymerization to phenols and benzene, or polymer conversion into a wide variety of dispersants, binders, reinforcing and antioxidizing agents, etc. Where lignin's fuel value lies around 3 to 4 cents/lb. (fall of 1979), its raw material value for phenol is reported to be almost 5 cents/lb., and the value of the polymeric materials is estimated to be between 6 and 20 cents/lb. At the lower end of this range of raw material values are ligninsulfonates, which contribute nearly 98 percent to the approximately 1.5 billion lb./yr. U.S. market for lignin products. Kraft lignins are located at the opposite end of this range. Novel bioconversion-type lignins are expected to be more similar in structure and properties to kraft than to sulfite lignins. Whereas application of the dispersant properties of ligninsulfonates in tertiary oil recovery operations is expected to constitute the most significant use of lignin in terms of volume, adhesive and resin applications hold the greatest promise in terms of value. Both utilization schemes seem to require pretreatments in the form of either polymeric fractionation or chemical modification. Potential savings from the use of polymeric lignins in material systems are great.

  16. Wood pellet production

    SciTech Connect (OSTI)

    Moore, J.W.

    1983-08-01

    Southern Energy Limited's wood pellet refinery, Bristol, Florida, produces wood pellets for fuel from scrap wood from a nearby sawmill and other hog fuel delivered to the plant from nearby forest lands. The refinery will provide 50,000 tons of pellets per year to the Florida State Hospital at Chattahoochee to fire recently converted boilers in the central power plant. The pellets are densified wood, having a moisture content of about 10% and a heating value of 8000 Btu/lb. They are 0.5 inches in diameter and 2 to 3 inches in length.

  17. Solvolytic liquefaction of wood under mild conditions

    SciTech Connect (OSTI)

    Yu, S.M.

    1982-04-01

    Conversion of wood to liquid products requires cleavage of bonds which crosslink the wood structure. This study examines a low-severity wood solubilization process utilizing a solvent medium consisting of a small amount of sulfuric acid and a potentially wood-derivable alcohol. In one half hour of reaction time at 250/sup 0/C under 15 psia starting nitrogen pressure, over 95% of the wood (maf) was rendered acetone-soluble. The product is a soft, black, bitumen-like solid at room temperature but readily softens at 140/sup 0/C. Between 25 and 50% of the original wood oxygen, depending on alcohol used, was removed as water. Approximately 2 to 17% of the alcohols were retained in the product. Gel permeation chromatography showed that the product's median molecular weight is around 300. Based on experimental and literature results, a mechanism for wood solubilization is proposed. This involves protonation of the etheric oxygen atoms, leading to subsequent bond scission to form carbonium ions which are stabilized by solvent alkoxylation. At severe conditions, polymerization and condensation reactions result in acetone-insoluble materials.

  18. Wood energy system design

    SciTech Connect (OSTI)

    Not Available

    1988-01-01

    This handbook, Wood Energy System Design, was prepared with the support of the Council of Great Lakes Governors and the US Department of Energy. It contains: wood fuel properties; procurement; receiving, handling, and storage; combustion; gasification; emission control; electric power generation and cogeneration; and case studies. (JF)

  19. An economical and market analysis of Canadian wood pellets.

    SciTech Connect (OSTI)

    Peng, J.

    2010-08-01

    This study systematically examined the current and future wood pellet market, estimated the cost of Canadian torrefied pellets, and compared the torrefied pellets with the conventional pellets based on literature and industrial data. The results showed that the wood pellet industry has been gaining significant momentum due to the European bioenergy incentives and the rising oil and natural gas prices. With the new bioenergy incentives in USA, the future pellets market may shift to North America, and Canada can potentially become the largest pellet production centre, supported by the abundant wood residues and mountain pine beetle (MPB) infested trees.

  20. Cord Wood Testing in a Non-Catalytic Wood Stove

    SciTech Connect (OSTI)

    Butcher, T.; Trojanowski, R.; Wei, G.

    2014-06-30

    EPA Method 28 and the current wood stove regulations have been in-place since 1988. Recently, EPA proposed an update to the existing NSPS for wood stove regulations which includes a plan to transition from the current crib wood fuel to cord wood fuel for certification testing. Cord wood is seen as generally more representative of field conditions while the crib wood is seen as more repeatable. In any change of certification test fuel, there are questions about the impact on measured results and the correlation between tests with the two different fuels. The purpose of the work reported here is to provide data on the performance of a noncatalytic stove with cord wood. The stove selected has previously been certified with crib wood which provides a basis for comparison with cord wood. Overall, particulate emissions were found to be considerably higher with cord wood.

  1. STEO October 2012 - wood

    U.S. Energy Information Administration (EIA) Indexed Site

    More U.S. households burning wood this winter to stay warm, reversing two-decade decline Burning wood as the primary heating source in U.S. households has risen over the last 10 years, reversing the decline seen in the 1980s and 1990s. About 2.6 million households out of 115 million will rely on wood as the main way to warm their homes this winter. That's up 3 percent from last year, according to the U.S. Energy Information Administration's new winter fuels forecast. The West will have the most

  2. Generating power with waste wood

    SciTech Connect (OSTI)

    Atkins, R.S.

    1995-02-01

    Among the biomass renewables, waste wood has great potential with environmental and economic benefits highlighting its resume. The topics of this article include alternate waste wood fuel streams; combustion benefits; waste wood comparisons; waste wood ash; pilot scale tests; full-scale test data; permitting difficulties; and future needs.

  3. James F. Wood

    Broader source: Energy.gov [DOE]

    James F. Wood is currently Deputy Assistant Secretary for Clean Coal in the Office of Fossil Energy (FE). In this position, he is responsible for the management and direction of the Office's...

  4. Transportation fuels from wood

    SciTech Connect (OSTI)

    Baker, E.G.; Elliott, D.C.; Stevens, D.J.

    1980-01-01

    The various methods of producing transportation fuels from wood are evaluated in this paper. These methods include direct liquefaction schemes such as hydrolysis/fermentation, pyrolysis, and thermochemical liquefaction. Indirect liquefaction techniques involve gasification followed by liquid fuels synthesis such as methanol synthesis or the Fischer-Tropsch synthesis. The cost of transportation fuels produced by the various methods are compared. In addition, three ongoing programs at Pacific Northwest Laboratory dealing with liquid fuels from wood are described.

  5. Techno-economic analysis of wood biomass boilers for the greenhouse industry

    SciTech Connect (OSTI)

    Chau, J.; Sowlati, T.; Sokhansanj, Shahabaddine; Bi, X.T.; Preto, F.; Melin, Staffan

    2009-01-01

    The objective of this study is to perform a techno-economic analysis on a typical wood pellet and wood residue boiler for generation of heat to an average-sized greenhouse in British Columbia. The variables analyzed included greenhouse size and structure, boiler efficiency, fuel types, and source of carbon dioxide (CO2) for crop fertilization. The net present value (NPV) show that installing a wood pellet or a wood residue boiler to provide 40% of the annual heat demand is more economical than using a natural gas boiler to provide all the heat at a discount rate of 10%. For an assumed lifespan of 25 years, a wood pellet boiler system could generate NPV of C$259,311 without electrostatic precipitator (ESP) and C$74,695 with ESP, respectively. While, installing a wood residue boiler with or without an ESP could provide NPV of C$919,922 or C$1,104,538, respectively. Using a wood biomass boiler could also eliminate over 3000 tonne CO2 equivalents of greenhouse gases annually. Wood biomass combustion generates more particulate matters than natural gas combustion. However, an advanced emission control system could significantly reduce particulate matters emission from wood biomass combustion which would bring the particulate emission to a relatively similar level as for natural gas.

  6. Precision wood particle feedstocks

    DOE Patents [OSTI]

    Dooley, James H; Lanning, David N

    2013-07-30

    Wood particles having fibers aligned in a grain, wherein: the wood particles are characterized by a length dimension (L) aligned substantially parallel to the grain, a width dimension (W) normal to L and aligned cross grain, and a height dimension (H) normal to W and L; the L.times.H dimensions define two side surfaces characterized by substantially intact longitudinally arrayed fibers; the W.times.H dimensions define two cross-grain end surfaces characterized individually as aligned either normal to the grain or oblique to the grain; the L.times.W dimensions define two substantially parallel top and bottom surfaces; and, a majority of the W.times.H surfaces in the mixture of wood particles have end checking.

  7. Gas pollution control apparatus and method and wood drying system employing same

    SciTech Connect (OSTI)

    Eatherton, J.R.

    1984-02-14

    Pollution control apparatus and method are disclosed in which hot exhaust gas containing pollutants including solid particles and hydrocarbon vapors is treated by transmitting such exhaust gas through a container containing wood members, such as wood chips, which serve as a filter media for filtering out such pollutants by causing such solids to deposit and such hydrocarbon vapors to condense upon the surface of the wood members. The contaminated wood chips are discharged from the filter and further processed into chip board or other commercial wood products thereby disposing of the pollutants. Lumber may be used as the wood members of the filter in a lumber kiln by deposition of solid particles on the rough surface of such lumber. The contaminated surfaces of the lumber are removed by a planer which produces a smooth finished lumber and contaminated wood chips that may be processed into chip board or other commercial wood products. A wood drying system employing such pollution control apparatus and method includes a hot air dryer for wood or other organic material, such as a wood chip rotary dryer or a wood veneer dryer, which produces hot exhaust gases containing pollutants including hydrocarbon vapors and solid particles. This hot exhaust air is transmitted through a lumber kiln to dry lumber thereby conserving heat energy and causing solid particle pollutants to deposit on the surface of the lumber. The kiln exhaust air containing solid and hydrocarbon vapor pollutants is then transmitted up through a filter stack of wood chips.

  8. Thorium, uranium and rare earth elements content in lanthanide concentrate (LC) and water leach purification (WLP) residue of Lynas advanced materials plant (LAMP)

    SciTech Connect (OSTI)

    AL-Areqi, Wadeeah M. Majid, Amran Ab. Sarmani, Sukiman

    2014-02-12

    Lynas Advanced Materials Plant (LAMP) has been licensed to produce the rare earths elements since early 2013 in Malaysia. LAMP processes lanthanide concentrate (LC) to extract rare earth elements and subsequently produce large volumes of water leach purification (WLP) residue containing naturally occurring radioactive material (NORM). This residue has been rising up the environmental issue because it was suspected to accumulate thorium with significant activity concentration and has been classified as radioactive residue. The aim of this study is to determine Th-232, U-238 and rare earth elements in lanthanide concentrate (LC) and water leach purification (WLP) residue collected from LAMP and to evaluate the potential radiological impacts of the WLP residue on the environment. Instrumental Neutron Activation Analysis and γ-spectrometry were used for determination of Th, U and rare earth elements concentrations. The results of this study found that the concentration of Th in LC was 1289.7 ± 129 ppm (5274.9 ± 527.6Bq/kg) whereas the Th and U concentrations in WLP were determined to be 1952.9±17.6 ppm (7987.4 ± 71.9 Bq/kg) and 17.2 ± 2.4 ppm respectively. The concentrations of Th and U in LC and WLP samples determined by γ- spectrometry were 1156 ppm (4728 ± 22 Bq/kg) and 18.8 ppm and 1763.2 ppm (7211.4 Bq/kg) and 29.97 ppm respectively. This study showed that thorium concentrations were higher in WLP compare to LC. This study also indicate that WLP residue has high radioactivity of {sup 232}Th compared to Malaysian soil natural background (63 - 110 Bq/kg) and come under preview of Act 304 and regulations. In LC, the Ce and Nd concentrations determined by INAA were 13.2 ± 0.6% and 4.7 ± 0.1% respectively whereas the concentrations of La, Ce, Nd and Sm in WLP were 0.36 ± 0.04%, 1.6%, 0.22% and 0.06% respectively. This result showed that some amount of rare earth had not been extracted and remained in the WLP and may be considered to be reextracted.

  9. Process for carbonaceous material conversion and recovery of alkali metal catalyst constituents held by ion exchange sites in conversion residue

    DOE Patents [OSTI]

    Sharp, David W.

    1980-01-01

    In a coal gasification operation or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein solid particles containing alkali metal residues are produced, alkali metal constituents are recovered for the particles by contacting or washing them with an aqueous solution containing calcium or magnesium ions in an alkali metal recovery zone at a low temperature, preferably below about 249.degree. F. During the washing or leaching process, the calcium or magnesium ions displace alkali metal ions held by ion exchange sites in the particles thereby liberating the ions and producing an aqueous effluent containing alkali metal constituents. The aqueous effluent from the alkali metal recovery zone is then recycled to the conversion process where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst.

  10. Fort Yukon Wood Energy Program: Wood Boiler Deployment

    Broader source: Energy.gov (indexed) [DOE]

    1.4 M - Cord Wood 275 - 300 per cord - Kwh 0.51 (rate increase coming) - Propane 193 per 100 lbs tank - Funder reassurance - Consultant accountability - Harvest ...

  11. Feasibility for Wood Heat - Collaborative Integrated Wood Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Wood Heat * Non-Profit Consortium of Ten Tribal ... Forestry, Fire Management, Self- Governance, ... coordination's across organizations 2 boilers and one ...

  12. Final Report: Development of Renewable Microbial Polyesters for Cost Effective and Energy- Efficient Wood-Plastic Composites

    SciTech Connect (OSTI)

    Thompson, David N.; Emerick, Robert W.; England, Alfred B.; Flanders, James P.; Loge, Frank J.; Wiedeman, Katherine A.; Wolcott, Michael P.

    2010-03-31

    In this project, we proposed to produce wood fiber reinforced thermoplastic composites (WFRTCs) using microbial thermoplastic polyesters in place of petroleum-derived plastic. WFRTCs are a rapidly growing product area, averaging a 38% growth rate since 1997. Their production is dependent on substantial quantities of petroleum based thermoplastics, increasing their overall energy costs by over 230% when compared to traditional Engineered Wood Products (EWP). Utilizing bio-based thermoplastics for these materials can reduce our dependence on foreign petroleum. We have demonstrated that biopolymers (polyhydroxyalkanoates, PHA) can be successfully produced from wood pulping waste streams and that viable wood fiber reinforced thermoplastic composite products can be produced from these materials. The results show that microbial polyester (PHB in this study) can be extruded together with wastewater-derived cell mass and wood flour into deck products having performance properties comparable to existing commercial HDPE/WF composite products. This study has thus proven the underlying concept that the microbial polyesters produced from waste effluents can be used to make cost-effective and energy-efficient wood-plastic composites. The cost of purified microbial polyesters is about 5-20 times that of HDPE depending on the cost of crude oil, due to high purification (40%), carbon substrate (40%) and sterilized fermentation (20%) costs for the PHB. Hence, the ability to produce competitive and functional composites with unpurified PHA-biomass mixtures from waste carbon sources in unsterile systems—without cell debris removal—is a significant step forward in producing competitive value-added structural composites from forest products residuals using a biorefinery approach. As demonstrated in the energy and waste analysis for the project, significant energy savings and waste reductions can also be realized using this approach. We recommend that the next step for development of

  13. Wood3 Resources | Open Energy Information

    Open Energy Info (EERE)

    Wood3 Resources Jump to: navigation, search Name: Wood3 Resources Place: Houston, Texas Zip: 77056-2409 Product: Wood3 Resources is an energy project development firm run by former...

  14. Using recycled wood waste as a fuel in the northeast: A handbook for prospective urban wood waste producers, suppliers and consumers

    SciTech Connect (OSTI)

    Prast, W.G.; Donovan, C.T.

    1988-03-01

    This report provides a comprehensive analysis of existing and future markets for recycled wood wastes in the eleven-state northeast region. The purpose of the report is to estimate the availability of wood and woody materials in the solid waste stream and to determine the technical and economic viability of separating and recycling them for other uses. The topics discussed include: current and future markets for recycled wood wastes; key components of successful wood waste processing facilities; decisionmaking process used to determine technical and economic viability of a proposed processing facility; environmental regulations and the permitting process required for recycled wood waste processors and users; case studies and annotated listings of existing wood waste processors and uses; detailed assessments of market opportunities in three metropolitan areas including Boston, New York, and Philadelphia; and a proposed action plan to stimulate and facilitate future market development.

  15. Wanda Woods | Argonne Leadership Computing Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Wanda Woods Budget & Resource Administrator Wanda Woods Argonne National Laboratory 9700 South Cass Avenue Building 240 - Wkstn. 1C9 Argonne, IL 60439 630-252-1353...

  16. Fort Yukon Wood Energy Program: Wood Boiler Deployment

    Broader source: Energy.gov (indexed) [DOE]

    Oil cost per year for school 210,000 Fuel cost for electrical generation 1.4 M Cord Wood 275 - 300 per cord Kwh 0.77 (rate increase coming) Propane 203.89 per 100 ...

  17. EERE Success Story-California: Agricultural Residues Produce Renewable

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel | Department of Energy Agricultural Residues Produce Renewable Fuel EERE Success Story-California: Agricultural Residues Produce Renewable Fuel April 18, 2013 - 12:00am Addthis Logos Technologies and EERE partnered with EdeniQ of Visalia, California, to construct a pilot plant that processes 1.2 tons per day of agricultural residues, such as corn stover (leaves and stalks), as well as other California-sourced indigenous, nonfood feedstock sources (wood chips and switchgrass). The

  18. Stanford - Woods Institute for the Environment | Open Energy...

    Open Energy Info (EERE)

    Stanford - Woods Institute for the Environment Jump to: navigation, search Logo: Stanford- Woods Institute for the Environment Name: Stanford- Woods Institute for the Environment...

  19. Marcia A. Wood | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Marcia A. Wood Group Leader, Information Solutions and Technology Assurance B.S. Computer Science, University of St. Francis Telephone 630.252.4656 Fax 630.252.6866 E-mail wood@anl.gov

  20. Wood To Fuel LLC | Open Energy Information

    Open Energy Info (EERE)

    To Fuel LLC Jump to: navigation, search Name: Wood To Fuel LLC Place: Lackawana, New York Zip: 14208 Product: Wood fuelproduct supplier. Coordinates: 41.401932, -75.637848...

  1. Processes change the look of wood fuel

    SciTech Connect (OSTI)

    Zerbe, J.I.

    1980-06-01

    The various forms of wood-derived fuels are reviewed, these include briquetted and pelleted wood products. Charcoal, obtained by pyrolysis has a heating value one and a half times the equivalent weight of the dry wood from which it was made. By process modifications, more oil and gas may be produced instead of charcoal. At Albany, Oregon two barrels of oil are produced daily by hydrogenation of one ton of dry wood chips. It is stated that methanol can be synthesized from solid wood - by wood gasification - with a 38% energy efficiency while ethanol can also be made from wood. The use of wood fuels for electric power generation and cogeneration are also mentioned.

  2. Processes change the look of wood fuel

    SciTech Connect (OSTI)

    Zerbe, J.I.

    1980-06-01

    The various forms of wood-derived fuels are reviewed; these include briquetted and pelleted wood products. Charcoal, obtained by pyrolysis has a heating value one and a half times the equivalent weight of the dry wood from which it was made. By process modifications, more oil and gas may be produced instead of charcoal. At Albany, Oregon two barrels of oil are produced daily by hydrogenation of one ton of dry wood chips. It is stated that methanol can be synthesized from solid wood - by wood gasification - with a 38% energy efficiency while ethanol can also be made from wood. The use of wood fuels for electric power generation and cogeneration are also mentioned.

  3. Duffield Wood Pellets | Open Energy Information

    Open Energy Info (EERE)

    Duffield Wood Pellets Jump to: navigation, search Name: Duffield Wood Pellets Place: North Yorkshire, United Kingdom Zip: HG4 5JB Product: A Yorkshire-based, family-run producer of...

  4. SOLID PHASE MICROEXTRACTION SAMPLING OF FIRE DEBRIS RESIDUES IN THE PRESENCE OF RADIONUCLIDE SURROGATE METALS

    SciTech Connect (OSTI)

    Duff, M; Keisha Martin, K; S Crump, S

    2007-03-23

    The Federal Bureau of Investigation (FBI) Laboratory currently does not have on site facilities for handling radioactive evidentiary materials and there are no established FBI methods or procedures for decontaminating highly radioactive fire debris (FD) evidence while maintaining evidentiary value. One experimental method for the isolation of FD residue from radionuclide metals involves using solid phase microextraction (SPME) fibers to remove the residues of interest. Due to their high affinity for organics, SPME fibers should have little affinity for most (radioactive) metals. The focus of this research was to develop an examination protocol that was applicable to safe work in facilities where high radiation doses are shielded from the workers (as in radioactive shielded cells or ''hot cells''). We also examined the affinity of stable radionuclide surrogate metals (Co, Ir, Re, Ni, Ba, Cs, Nb, Zr and Nd) for sorption by the SPME fibers. This was done under exposure conditions that favor the uptake of FD residues under conditions that will provide little contact between the SPME and the FD material (such as charred carpet or wood that contains commonly-used accelerants). Our results from mass spectrometric analyses indicate that SPME fibers show promise for use in the room temperature head space uptake of organic FD residue (namely, diesel fuel oil, kerosene, gasoline and paint thinner) with subsequent analysis by gas chromatography (GC) with mass spectrometric (MS) detection. No inorganic forms of ignitable fluids were included in this study.

  5. Kenneth L. Wood | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Kenneth L. Wood Senior Engineering Specialist Telephone (630) 252-3971 E-mail klw@hep.anl

  6. URBAN WOOD/COAL CO-FIRING IN THE NIOSH BOILERPLANT

    SciTech Connect (OSTI)

    James T. Cobb, Jr.; Gene E. Geiger; William W. Elder III; Thomas Stickle; Jun Wang; Hongming Li; William P. Barry

    2002-06-13

    During the third quarter, the experimental portion of the project was carried out. Three one-day tests using wood/coal blends of 33% wood by volume (both construction wood and demolition wood) were conducted at the NIOSH Boiler Plant (NBP). Blends using hammer-milled wood were operationally successful and can form the basis of Phase II. Emissions of SO{sub 2} and NOx decreased and that of CO increased when compared with combusting coal alone. Mercury emissions were measured and the mathematical modeling of mercury speciation reactions continued, yielding many interesting results. Material and energy balances for the test periods at the NBP, as well as at the Bellefield Boiler Plant, were prepared. Steps were taken to remove severe constraints from the Pennsylvania Switchgrass Energy and Conservation Project and to organize the supplying of landfill gas to the Bruceton federal complex. Two presentations were made to meetings of the Electric Power Research Institute and the National Energy Technology Laboratory.

  7. Wood and Pellet Heating | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heat & Cool » Home Heating Systems » Wood and Pellet Heating Wood and Pellet Heating A wood stove on a stone hearth. | Photo courtesy of ©iStockphoto/King_Louie A wood stove on a stone hearth. | Photo courtesy of ©iStockphoto/King_Louie Today you can choose from a new generation of wood- and pellet-burning appliances that are cleaner burning, more efficient, and powerful enough to heat many average-sized, modern homes. Pellet fuel appliances burn small pellets that measure 3/8 to 1

  8. Evaluation of residue drum storage safety risks

    SciTech Connect (OSTI)

    Conner, W.V.

    1994-06-17

    A study was conducted to determine if any potential safety problems exist in the residue drum backlog at the Rocky Flats Plant. Plutonium residues stored in 55-gallon drums were packaged for short-term storage until the residues could be processed for plutonium recovery. These residues have now been determined by the Department of Energy to be waste materials, and the residues will remain in storage until plans for disposal of the material can be developed. The packaging configurations which were safe for short-term storage may not be safe for long-term storage. Interviews with Rocky Flats personnel involved with packaging the residues reveal that more than one packaging configuration was used for some of the residues. A tabulation of packaging configurations was developed based on the information obtained from the interviews. A number of potential safety problems were identified during this study, including hydrogen generation from some residues and residue packaging materials, contamination containment loss, metal residue packaging container corrosion, and pyrophoric plutonium compound formation. Risk factors were developed for evaluating the risk potential of the various residue categories, and the residues in storage at Rocky Flats were ranked by risk potential. Preliminary drum head space gas sampling studies have demonstrated the potential for formation of flammable hydrogen-oxygen mixtures in some residue drums.

  9. Densified fuels from wood waste

    SciTech Connect (OSTI)

    Pickering, W.H.

    1995-11-01

    Wood compressed to a specific gravity of about 1.2 constitutes an excellent clean burning fuel. {open_quotes}Prestologs{close_quotes} were marketed before 1940, but in the past ten years a much larger and growing market is densified pellet fuel has developed. The market for pellet fuel is about 90% residential, using special pellet burning stoves. Initial sales were almost entirely in the northwest, but sales in other parts of the country are now growing rapidly. Approximately 300,000 stoves are in use. Note that this industry developed from the private sector with little or no support from federal or state governments. Densified fuel is manufactured by drying and compressing sawdust feedstock. Combustion is different than that of normal wood. For example, wood pellets require ample supplies of air. They then burn with a hot flame and very low particulate emissions. Volatile organic compounds are burned almost completely and carbon monoxide can also be kept very low. Stoves burning pellets easily meet EPA standards. This paper discusses technical and economic factors associated with densified fuel and considers the future of the industry.

  10. Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Materials Materials Access to Hopper Phase II (Cray XE6) If you are a current NERSC user, you are enabled to use Hopper Phase II. Use your SSH client to connect to Hopper II:...

  11. Engineering methods for the design and employment of wood cribs

    SciTech Connect (OSTI)

    Barczak, T.M. ); Gearhart, D.F. )

    1993-01-01

    Wood cribs are used extensively by the mining industry to stabilize mine openings. While the cost per crib is relatively low, their extensive use can result in annual mine costs of over $1 million. In an effort to improve the utilization of these supports and to reduce ground control hazards, the US Bureau of Mines has developed engineering methods to assist mine operators in wood-crib design and employment. Design and employment criteria are established based on the strength, stiffness, and stability of the crib structure in relation to the load conditions imposed by the mine environment. Models have been developed based on full-scale tests in the USBM's Mine Roof Simulator that compute the capacity of wood cribs of various configurations and material constructions as a function of displacement of the crib structure due to roof-and-floor convergence. These models permit the comparison of the loading characteristics and cost of employment of different crib designs, and in conjunction with roof behavior models, provide a means to determine the optimum design and employment strategy. In eastern coal mines, wood cribs generally are constructed from hardwood timbers, while softwood timbers generally are used in western coal mines. 11 refs., 27 figs., 2 tabs.

  12. Vertical feed stick wood fuel burning furnace system

    DOE Patents [OSTI]

    Hill, Richard C.

    1984-01-01

    A new and improved stove or furnace for efficient combustion of wood fuel including a vertical feed combustion chamber for receiving and supporting wood fuel in a vertical attitude or stack, a major upper portion of the combustion chamber column comprising a water jacket for coupling to a source of water or heat transfer fluid and for convection circulation of the fluid for confining the locus of wood fuel combustion to the bottom of the vertical gravity feed combustion chamber. A flue gas propagation delay channel extending from the laterally directed draft outlet affords delayed travel time in a high temperature environment to assure substantially complete combustion of the gaseous products of wood burning with forced air as an actively induced draft draws the fuel gas and air mixture laterally through the combustion and high temperature zone. Active sources of forced air and induced draft are included, multiple use and circuit couplings for the recovered heat, and construction features in the refractory material substructure and metal component superstructure.

  13. Vertical feed stick wood fuel burning furnace system

    DOE Patents [OSTI]

    Hill, Richard C.

    1982-01-01

    A stove or furnace for efficient combustion of wood fuel includes a vertical feed combustion chamber (15) for receiving and supporting wood fuel in a vertical attitude or stack. A major upper portion of the combustion chamber column comprises a water jacket (14) for coupling to a source of water or heat transfer fluid for convection circulation of the fluid. The locus (31) of wood fuel combustion is thereby confined to the refractory base of the combustion chamber. A flue gas propagation delay channel (34) extending laterally from the base of the chamber affords delayed travel time in a high temperature refractory environment sufficient to assure substantially complete combustion of the gaseous products of wood burning with forced air prior to extraction of heat in heat exchanger (16). Induced draft draws the fuel gas and air mixture laterally through the combustion chamber and refractory high temperature zone to the heat exchanger and flue. Also included are active sources of forced air and induced draft, multiple circuit couplings for the recovered heat, and construction features in the refractory material substructure and metal component superstructure.

  14. Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Materials Materials Understanding and manipulating the most fundamental properties of materials can lead to major breakthroughs in solar power, reactor fuels, optical computing, telecommunications. News Releases Science Briefs Photos Picture of the Week Publications Social Media Videos Fact Sheets Yu Seung Kim (left) and Kwan-Soo Lee (right) New class of fuel cells offer increased flexibility, lower cost A new class of fuel cells based on a newly discovered polymer-based material could bridge

  15. Table N5.2. Selected Wood and Wood-Related Products in Fuel...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... for any table cell, multiply the cell's" "corresponding RSE column and RSE row factors. ... "Table N5.2. Selected Wood and Wood-Related Products in Fuel Consumption, 1998;" " Level: ...

  16. Grant F. Wood | Argonne Leadership Computing Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Grant F. Wood Consultant - Project Management 9700 S. Cass Avenue Building 240 Wkstn. 3D18 Argonne, IL 60439 630-252-5315 gfwood

  17. Qualifying Wood Stove Deduction | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Total cost, exclusive of taxes, interest and other finance charges Summary This incentive allows Arizona taxpayers to deduct the cost of converting an existing wood fireplace to a ...

  18. Arbuthnott Wood Pellets Ltd | Open Energy Information

    Open Energy Info (EERE)

    Scotland, United Kingdom Zip: AB30 1PA Product: Wood pellet producer. Coordinates: 56.932781, -2.42531 Show Map Loading map... "minzoom":false,"mappingservice":"googlema...

  19. Wood, Wisconsin: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Wood, Wisconsin: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 43.568752, -90.330887 Show Map Loading map... "minzoom":false,"mappingservice"...

  20. A preliminary assessment of the state of harvest and collection technology for forest residues

    SciTech Connect (OSTI)

    Webb, Erin; Perlack, Robert D; Blackwelder, D. Brad; Muth, David J.; Hess, J. Richard

    2008-08-01

    To meet the 'Twenty in Ten Initiative' goals set in the 2007 State of the Union address, forest resources will be needed as feedstocks for lignocellulosic ethanol production. It has been estimated that 368 million dry tons can be produced annually in the U.S. from logging residues and fuel treatment thinnings. Currently, very little of this woody biomass is used for energy production due to the costs and difficulty in collecting and transporting this material. However, minimizing biomass costs (including harvest, handling, transport, storage, and processing costs) delivered to the refinery is necessary to develop a sustainable cellulosic ethanol industry. Achieving this goal requires a fresh look at conventional timber harvesting operations to identify ways of efficiently integrating energy wood collection and developing cost-effective technologies to harvest small-diameter trees. In conventional whole-tree logging operations, entire trees are felled and skidded from the stump to the landing. The residues (also called slash), consisting of tops and limbs, accumulate at the landing when trees are delimbed. This slash can be ground at the landing with a mobile grinder or transported to another central location with a stationary grinder. The ground material is transported via chip vans, or possibly large roll on/off containers, to the user facility. Cut-to-length harvesting systems are gaining popularity in some locations. In these operations, specialized harvesters that can fall, delimb, and cut logs to length are used. The small diameter tops and limbs accumulate along the machine's track. It can be left in the forest to dry or removed soon after harvest while logs are extracted. Removing slash during the same operation as the wood has been shown to be more efficient. However, leaving residue in the forest to dry reduces moisture content, which improves grinder performance, reduces dry matter loss during storage, and inhibits colonization of fungi that produce

  1. Residue management at Rocky Flats

    SciTech Connect (OSTI)

    Olencz, J.

    1995-12-31

    Past plutonium production and manufacturing operations conducted at the Rocky Flats Environmental Technology Site (RFETS) produced a variety of plutonium-contaminated by-product materials. Residues are a category of these materials and were categorized as {open_quotes}materials in-process{close_quotes} to be recovered due to their inherent plutonium concentrations. In 1989 all RFETS plutonium production and manufacturing operations were curtailed. This report describes the management of plutonium bearing liquid and solid wastes.

  2. Laboratory evaluation of the hazard to wood mice, Apodemus sylvaticus, from the agricultural use of methiocarb molluscicide pellets

    SciTech Connect (OSTI)

    Tarrant, K.A.; Westlake, G.E.

    1988-01-01

    Laboratory studies have been carried out to determine the toxicity of methiocarb pellets to wild trapped wood mice in order to provide some background data prior to any further evaluation of hazard in the field. In this study, wood mice were exposed to dry and to dampened methiocarb pellets in order to reproduce field trial application conditions. Field observations of methiocarb pellets indicate that the physical character changes under dry and wet weather conditions. This may affect their relative attractiveness and potential toxicity to wood mice. The laboratory assessment of exposed wood mice included measurement of brain esterase activities, methiocarb residues in selected mouse tissue, carcasses, and histological evaluation of kidney, liver and lungs.

  3. Flash pyrolysis products from beech wood

    SciTech Connect (OSTI)

    Beaumont, O.

    1985-04-01

    Flash pyrolysis products from beech wood obtained in an original pyrolysis apparatus were analyzed. The analytical procedure is described, and the composition of pyrolytic oil presented with more than 50 compounds. Comparison of pyrolytic products of cellulose, hemicellulose, and wood indicates the origin of each product. 19 references.

  4. Rachel Woods-Robinson | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Rachel Woods-Robinson About Us Rachel Woods-Robinson - Guest Blogger, Cycle for Science Most Recent Rain or Shine: We Cycle for Science July 2 Mountains, and Teachers, and a Bear, Oh My! June 2 Sol-Cycle: Biking Across America for Science Education May 1

  5. Lake of the Woods County, Minnesota: Energy Resources | Open...

    Open Energy Info (EERE)

    in Lake of the Woods County, Minnesota Baudette, Minnesota Roosevelt, Minnesota Williams, Minnesota Retrieved from "http:en.openei.orgwindex.php?titleLakeoftheWoodsC...

  6. Compound and Elemental Analysis At Little Valley Area (Wood,...

    Open Energy Info (EERE)

    Little Valley Area (Wood, 2002) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and Elemental Analysis At Little Valley Area (Wood,...

  7. Woods Hole Research Center Wind Turbine | Open Energy Information

    Open Energy Info (EERE)

    Hole Research Center Wind Turbine Jump to: navigation, search Name Woods Hole Research Center Wind Turbine Facility Woods Hole Research Center Wind Turbine Sector Wind energy...

  8. Council of Athabascan Tribal Governments - Wood Energy Program...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    0 November 2008 Gwitchyaa Zhee Corporation CATG - AWEA For-Profit Wood Energy Business Model Fort Yukon * Forest Management Service - CATG * For-Profit Wood Utility Company -...

  9. Alaska Wood Biomass Energy Project Final Report

    SciTech Connect (OSTI)

    Jonathan Bolling

    2009-03-02

    The purpose of the Craig Wood Fired Boiler Project is to use waste wood from local sawmilling operations to provide heat to local public buildings, in an effort to reduce the cost of operating those buildings, and put to productive use a byproduct from the wood milling process that otherwise presents an expense to local mills. The scope of the project included the acquisition of a wood boiler and the delivery systems to feed wood fuel to it, the construction of a building to house the boiler and delivery systems, and connection of the boiler facility to three buildings that will benefit from heat generated by the boiler: the Craig Aquatic Center, the Craig Elementary School, and the Craig Middle School buildings.

  10. Mobility of organic carbon from incineration residues

    SciTech Connect (OSTI)

    Ecke, Holger Svensson, Malin

    2008-07-01

    Dissolved organic carbon (DOC) may affect the transport of pollutants from incineration residues when landfilled or used in geotechnical construction. The leaching of dissolved organic carbon (DOC) from municipal solid waste incineration (MSWI) bottom ash and air pollution control residue (APC) from the incineration of waste wood was investigated. Factors affecting the mobility of DOC were studied in a reduced 2{sup 6-1} experimental design. Controlled factors were treatment with ultrasonic radiation, full carbonation (addition of CO{sub 2} until the pH was stable for 2.5 h), liquid-to-solid (L/S) ratio, pH, leaching temperature and time. Full carbonation, pH and the L/S ratio were the main factors controlling the mobility of DOC in the bottom ash. Approximately 60 weight-% of the total organic carbon (TOC) in the bottom ash was available for leaching in aqueous solutions. The L/S ratio and pH mainly controlled the mobilization of DOC from the APC residue. About 93 weight-% of TOC in the APC residue was, however, not mobilized at all, which might be due to a high content of elemental carbon. Using the European standard EN 13 137 for determination of total organic carbon (TOC) in MSWI residues is inappropriate. The results might be biased due to elemental carbon. It is recommended to develop a TOC method distinguishing between organic and elemental carbon.

  11. Solidification process for sludge residue

    SciTech Connect (OSTI)

    Pearce, K.L.

    1998-09-10

    This report investigates the solidification process used at 100-N Basin to solidify the N Basin sediment and assesses the N Basin process for application to the K Basin sludge residue material. This report also includes a discussion of a solidification process for stabilizing filters. The solidified matrix must be compatible with the Environmental Remediation Disposal Facility acceptance criteria.

  12. Wood fuel in fluidized bed boilers

    SciTech Connect (OSTI)

    Virr, M.J.

    1982-01-01

    Development of fluidized bed fire-tube and water-tube boilers for the burning of wood, gas, and refuse-derived fuel will be reviewed. Experience gained in already installed plants will be outlined. Research experiments results on the use of various forms of wood and other biomass fuels, such as wood chips, pellets, peach pits, nut shells and kernels and refuse-derived fuels, will be described for small and medium sized fire-tube boilers, and for larger water-tube boilers for co-generation. (Refs. 4).

  13. Study of field assessment methods and worker risks for processing alternatives to support principles for FUSRAP waste materials. Part 1: Treatment methods and comparative risks of thorium removal from waste residues

    SciTech Connect (OSTI)

    Porter, R.D.; Hamby, D.M.; Martin, J.E.

    1997-07-01

    This study was done to examine the risks of remediation and the effectiveness of removal methods for thorium and its associated radioactive decay products from various soils and wastes associated with DOE`s Formerly Utilized Sites Remedial Action Program (FUSRAP). Its purpose was to provide information to the Environmental Management Advisory Board`s FUSRAP Committee for use in its deliberation of guiding principles for FUSRAP sites, in particular the degree to which treatment should be considered in the FUSRAP Committee`s recommendations. Treatment of FUSRAP wastes to remove thorium could be beneficial to management of lands that contain thorium if such treatment were effective and cost efficient. It must be recognized, however, that treatment methods invariably require workers to process residues and waste materials usually with bulk handling techniques. These processes expose workers to the radioactivity in the materials, therefore, workers would incur radiological risks in addition to industrial accident risks. An important question is whether the potential reduction of future radiological risks to members of the public justifies the risks that are incurred by remediation workers due to handling materials. This study examines, first, the effectiveness of treatment and then the risks that would be associated with remediation. Both types of information should be useful for decisions on whether and how to apply thorium removal methods to FUSRAP waste materials.

  14. Revk - a Tool for the Fulfilment of Requirements from National Rules for Tracking and Documentation of Radioactive Residual Material and Radioactive Waste

    SciTech Connect (OSTI)

    Hartmann, B.; Haeger, M.; Gruendler, D.

    2006-07-01

    According to the German Radiation Protection Ordinance treatment, storage, whereabouts of radioactive material etc. have to be documented. Due to legal requirements an electronic documentation system for radioactive waste has to be installed. Within the framework of the currently largest decommissioning project of nuclear facilities by Energiewerke Nord GmbH, a material flow-waste tracking and control system (ReVK) has been developed, tailored to the special needs of the decommissioning of nuclear facilities. With this system it is possible to record radioactive materials which can be released after treatment or decay storage for restricted and unrestricted utilization. Radioactive waste meant for final storage can be registered and documented as well. Based on ORACLE, ReVK is a client/server data base system with the following modules: 1. data registration, 2. transport management, 3. waste tracking, 4. storage management, 5. container management, 6. reporting, 7. activity calculation, 8. examination of technical acceptance criteria for storages and final repositories. Furthermore ReVK provides a multitude of add-ons to meet special user needs, which enlarge the spectrum of application enormously. ReVK is validated and qualified, accepted by experts and authorities and fulfils the requirements for a radioactive waste documentation system. (authors)

  15. Wood Fuel LP | Open Energy Information

    Open Energy Info (EERE)

    77034 Region: Texas Area Sector: Biomass Product: Wood by-products consulting and marketing Website: www.woodfuel.com Coordinates: 29.6221328, -95.1872605 Show Map Loading...

  16. From the Woods to the Refinery

    Broader source: Energy.gov [DOE]

    Breakout Session 2D—Building Market Confidence and Understanding II: Carbon Accounting and Woody Biofuels From the Woods to the Refinery Stephen S. Kelley, Principal and Department Head, Department of Forest Biomaterials, North Carolina State University

  17. Logs Wood Chips Straw Corn Switchgrass

    Broader source: Energy.gov (indexed) [DOE]

    Clean energy can come from the sun. The energy in wind can make electricity. Bioenergy comes from plants we can turn into fuel. Logs Wood Chips Straw Corn Switchgrass We can use ...

  18. Wood Energy Ltd | Open Energy Information

    Open Energy Info (EERE)

    Energy Ltd Jump to: navigation, search Name: Wood Energy Ltd Place: Devon, United Kingdom Zip: EX16 9EU Product: Specialises in the design, installation and service of automatic...

  19. Marin County- Wood Stove Replacement Rebate Program

    Broader source: Energy.gov [DOE]

    Homes in the San Geronimo Valley (Forest Knolls, Lagunitas, San Geronimo, and Woodacre) can receive a rebate of $1,500 for the removal and replacement of non-certified wood burning appliances with...

  20. Wood and Pellet Heating Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Wood and Pellet Heating Basics Wood and Pellet Heating Basics August 16, 2013 - 3:02pm Addthis Wood-burning and pellet fuel appliances use biomass or waste resources to heat homes or buildings. Types of Wood- and Pellet-Burning Appliances The following is a brief overview of the different types of wood and pellet fuel appliances available. High-Efficiency Fireplaces and Fireplace Inserts Designed more for show, traditional open masonry fireplaces should not be considered heating devices.

  1. Tank 12H residuals sample analysis report

    SciTech Connect (OSTI)

    Oji, L. N.; Shine, E. P.; Diprete, D. P.; Coleman, C. J.; Hay, M. S.

    2015-06-11

    The Savannah River National Laboratory (SRNL) was requested by Savannah River Remediation (SRR) to provide sample preparation and analysis of the Tank 12H final characterization samples to determine the residual tank inventory prior to grouting. Eleven Tank 12H floor and mound residual material samples and three cooling coil scrape samples were collected and delivered to SRNL between May and August of 2014.

  2. URBAN WOOD/COAL CO-FIRING IN THE BELLEFIELD BOILERPLANT

    SciTech Connect (OSTI)

    James T. Cobb Jr.; Gene E. Geiger; William W. Elder III; William P. Barry; Jun Wang; Hongming Li

    2004-04-08

    An Environmental Questionnaire for the demonstration at the Bellefield Boiler Plant (BBP) was submitted to the national Energy Technology Laboratory. An R&D variance for the air permit at the BBP was sought from the Allegheny County Health Department (ACHD). R&D variances for the solid waste permits at the J. A. Rutter Company (JARC), and Emery Tree Service (ETS) were sought from the Pennsylvania Department of Environmental Protection (PADEP). Construction wood was acquired from Thompson Properties and Seven D Corporation. Verbal authorizations were received in all cases. Memoranda of understanding were executed by the University of Pittsburgh with BBP, JARC and ETS. Construction wood was collected from Thompson Properties and from Seven D Corporation. Forty tons of pallet and construction wood were ground to produce BioGrind Wood Chips at JARC and delivered to Mon Valley Transportation Company (MVTC). Five tons of construction wood were hammer milled at ETS and half of the product delivered to MVTC. Blends of wood and coal, produced at MVTC by staff of JARC and MVTC, were shipped by rail to BBP. The experimental portion of the project was carried out at BBP in late March and early April 2001. Several preliminary tests were successfully conducted using blends of 20% and 33% wood by volume. Four one-day tests using a blend of 40% wood by volume were then carried out. Problems of feeding and slagging were experienced with the 40% blend. Light-colored fly ash was observed coming from the stack during all four tests. Emissions of SO{sub 2}, NOx and total particulates, measured by Energy Systems Associates, decreased when compared with combusting coal alone. A procedure for calculating material and energy balances on BBP's Boiler No.1 was developed, using the results of an earlier compliance test at the plant. Material and energy balances were then calculated for the four test periods. Boiler efficiency was found to decrease slightly when the fuel was shifted from coal

  3. Cellulose Nanomaterials: The Sustainable Material of Choice for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Laboratory June 26, 2012 Cellulose Nanomaterials: The Sustainable Material of Choice for the 21 st Century Sustainable Nanomaterials Workshop * Wood: a Sustainable & Renewable ...

  4. Mass transport parameters of aspen wood chip beds via stimulus-response tracer techniques

    SciTech Connect (OSTI)

    Hradil, G.; Calo, J.M.; Wunderlich, T.K. Jr. )

    1993-02-05

    A stimulus-response tracer technique has been used to characterize packed beds of untreated, as well as acid prehydrolyzed, and enzymatically hydrolyzed aspen wood chips. Glucose was used as the trace. Bulk liquid phase dispersion, interphase mass transfer, and intraparticle diffusion coefficients were determined for these materials as well as effective porosities and tortuosities. The untreated and prehydrolyzed aspen wood chips were found to have effective void fractions of ca. 0.8, while the enzymatically hydrolyzed wood chips exhibited a void fraction of 0.37. Intraparticle diffusion was approximately twice as rapid in the prehydrolyzed and enzymatically hydrolyzed wood chips as in the untreated wood chips. Also, under the current experimental conditions, intraparticle diffusional transport resistance accounted for roughly half of the total tracer pulse dispersion. It is demonstrated that stimulus-response tracer techniques can be useful and convenient probes for beds of lignocellulosic, or other porous materials, which vary in character with extent of conversion and/or treatment.

  5. Flash methanolysis of wood for the production of fuels and chemicals

    SciTech Connect (OSTI)

    Steinberg, M.; Fallon, P.T.; Sundaram, M.S.

    1983-01-01

    Biomass in the form of less than 1000 micron oven dried fir wood particles was flash pyrolyzed in the presence of methane (methanolysis) in a downflow 1 in. I.D. tubular reactor at pressures of 20 to 200 psi and temperatures between 800/sup 0/ and 1050/sup 0/C. The major products were benzene, toluene and xylene (BTX), a heavy oily liquid (greater than or equal to C/sub 9/), ethylene and carbon monoxide. As much as 12% of the available carbon in the wood was converted to BTX, 21% to ethylene and 48% to carbon monoxide at 50 psi and 1000/sup 0/C. The maximum heavier oil yield of 11% was observed at 50 psi and 800/sup 0/C. Wood particle residence times for all experiments were calculated to be less than 1 second at 20 and 50 psi and up to 2.8 sec at 200 psi. The yelds were found to be greatly influenced by the methane to wood feed ratio. Experiments were conducted to insure the results to be that produced from the wood and methane and not a catalytic effect of the reactor wall of foreign matter. Material balance, including char analyses, indicate approximately 75 to 80% of the available carbon in the feed wood reacted. Methane balances were within the margin of error of the measuring equipment showing that there is no significant net production or consumption of methane. A preliminary economic evaluation of a 2000 ton/day wood processing plant producing ethylene, benzene and methanol showed a reasonably cmpetitive plant investment of $29,000/barrel fuel oil equivalent/day assuming 15% return on investment and present market values for the products.

  6. Electric co-generation units equipped with wood gasifier and Stirling engine

    SciTech Connect (OSTI)

    Bartolini, C.M.; Caresana, F.; Pelagalli, L.

    1998-07-01

    The disposal of industrial waste such as oil sludges, waste plastic, lubricant oils, paper and wood poses serious problems due to the ever increasing amount of material to be disposed of and to the difficulty in finding new dumping sites. The interest in energy recovery technologies is accordingly on the increase. In particular, large amounts of waste wood are simply burned or thrown away causing considerable environmental damage. In this context the co-generation technique represents one of the possible solutions for efficient energy conversion. The present paper proposes the employment of a Stirling engine as prime mover in a co-generation set equipped with a wood gasifier. A Stirling engine prototype previously developed in a joint project with Mase Generators, an Italian manufacturer of fixed and portable electrogenerators, is illustrated and its design is described.

  7. Simple and Inexpensive Method of Wood Pellets Macro-porosity Measurement

    SciTech Connect (OSTI)

    C. Igathinathane; Jaya Shankar Tumuluru; S. Sokhansanj; X. Bi; C. J. Lim; S. Melin; E. Mohammad

    2010-08-01

    A novel simplified stereometric measurement method for determining the macro-porosity of wood pellets through geometrical approach was successfully developed and tested. The irregular ends of pellets of circular cross-section were sanded flat so that their geometry becomes cylinder and their volumes evaluated using mensuration formula. Such formed cylindrical pellets were loose or tap filled to selected volumes to evaluate the macro-porosity and the constant specific weight. The method was extended to evaluate actual wood pellets properties. Overall macro-porosity of actual wood pellets was determined as 41.0±2.5% and 35.5±2.7%, mean bulk density as and , and classified as “Class-3:Medium” and “Class-3&4:Medium to Low” for loose and tapped fills, respectively. Hausner ratio and Carr’s compressibility index classify wood pellets as “freely flowing.” The developed stereometric method can be used as a handy inexpensive laboratory procedure to estimate the macro-porosity of different types and makes of wood pellets and other similar packaged materials.

  8. Simple and inexpensive method of wood pellets macro-porosity measurement

    SciTech Connect (OSTI)

    Igathinathane, C.; Tumuluru, J.S.; Sokhansanj, Shahabaddine; Bi, X.T.; Lim, C. Jim; Melin, Staffan; Mohammad, E.

    2010-01-01

    A novel simplified stereometric measurement method for determining the macro-porosity of wood pellets through geometrical approach was successfully developed and tested. The irregular ends of pellets of circular cross-section were sanded flat so that their geometry becomes cylinder and their volumes evaluated using mensuration formula. Such formed cylindrical pellets were loose or tap filled to selected volumes to evaluate the macro-porosity and the constant specific weight. The method was extended to evaluate actual wood pellets properties. Overall macro-porosity of actual wood pellets was determined as 41.0 2.5% and 35.5 2.7%, mean bulk density as and, and classified as Class-3:Medium and Class-3&4:Medium to Low for loose and tapped fills, respectively. Hausner ratio and Carr s compressibility index classify wood pellets as freely flowing. The developed stereometric method can be used as a handy inexpensive laboratory procedure to estimate the macro-porosity of different types and makes of wood pellets and other similar packaged materials.

  9. URBAN WOOD/COAL CO-FIRING IN THE BELLEFIELD BOILERPLANT

    SciTech Connect (OSTI)

    James T. Cobb, Jr.; Gene E. Geiger; William W. Elder III; William P. Barry; Jun Wang; Hongming Li

    2001-08-21

    During the third quarter, important preparatory work was continued so that the experimental activities can begin early in the fourth quarter. Authorization was awaited in response to the letter that was submitted to the Allegheny County Health Department (ACHD) seeking an R&D variance for the air permit at the Bellefield Boiler Plant (BBP). Verbal authorizations were received from the Pennsylvania Department of Environmental Protection (PADEP) for R&D variances for solid waste permits at the J. A. Rutter Company (JARC), and Emery Tree Service (ETS). Construction wood was acquired from Thompson Properties and Seven D Corporation. Forty tons of pallet and construction wood were ground to produce BioGrind Wood Chips at JARC and delivered to Mon Valley Transportation Company (MVTC). Five tons of construction wood were milled at ETS and half of the product delivered to MVTC. Discussions were held with BBP and Energy Systems Associates (ESA) about the test program. Material and energy balances on Boiler No.1 and a plan for data collection were prepared. Presentations describing the University of Pittsburgh Wood/Coal Co-Firing Program were provided to the Pittsburgh Chapter of the Pennsylvania Society of Professional Engineers, and the Upgraded Coal Interest Group and the Biomass Interest Group (BIG) of the Electric Power Research Institute (EPRI). An article describing the program appeared in the Pittsburgh Post-Gazette. An application was submitted for authorization for a Pennsylvania Switchgrass Energy and Conservation Program.

  10. Residual Stresses for Structural Analysis and Fatigue Life Prediction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Life Prediction in Vehicle Components: Success stories from the High Temperature Materials Laboratory (HTML) User Program Residual Stresses for Structural Analysis and Fatigue Life ...

  11. International Trade of Wood Pellets (Brochure)

    SciTech Connect (OSTI)

    Not Available

    2013-05-01

    The production of wood pellets has increased dramatically in recent years due in large part to aggressive emissions policy in the European Union; the main markets that currently supply the European market are North America and Russia. However, current market circumstances and trade dynamics could change depending on the development of emerging markets, foreign exchange rates, and the evolution of carbon policies. This fact sheet outlines the existing and potential participants in the wood pellets market, along with historical data on production, trade, and prices.

  12. X-ray computed tomography of wood-adhesive bondlines: Attenuation and phase-contrast effects

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Paris, Jesse L.; Kamke, Frederick A.; Xiao, Xianghui

    2015-07-29

    Microscale X-ray computed tomography (XCT) is discussed as a technique for identifying 3D adhesive distribution in wood-adhesive bondlines. Visualization and material segmentation of the adhesives from the surrounding cellular structures require sufficient gray-scale contrast in the reconstructed XCT data. Commercial wood-adhesive polymers have similar chemical characteristics and density to wood cell wall polymers and therefore do not provide good XCT attenuation contrast in their native form. Here, three different adhesive types, namely phenol formaldehyde, polymeric diphenylmethane diisocyanate, and a hybrid polyvinyl acetate, are tagged with iodine such that they yield sufficient X-ray attenuation contrast. However, phase-contrast effects at material edgesmore » complicate image quality and segmentation in XCT data reconstructed with conventional filtered backprojection absorption contrast algorithms. A quantitative phase retrieval algorithm, which isolates and removes the phase-contrast effect, was demonstrated. The paper discusses and illustrates the balance between material X-ray attenuation and phase-contrast effects in all quantitative XCT analyses of wood-adhesive bondlines.« less

  13. New England Wood Pellet LLC | Open Energy Information

    Open Energy Info (EERE)

    Pellet LLC Jump to: navigation, search Name: New England Wood Pellet LLC Place: Jaffrey, New Hampshire Zip: NH 03452 Product: New England Wood Pellet LLC is a manufacturer and...

  14. Method of predicting mechanical properties of decayed wood

    DOE Patents [OSTI]

    Kelley, Stephen S.

    2003-07-15

    A method for determining the mechanical properties of decayed wood that has been exposed to wood decay microorganisms, comprising: a) illuminating a surface of decayed wood that has been exposed to wood decay microorganisms with wavelengths from visible and near infrared (VIS-NIR) spectra; b) analyzing the surface of the decayed wood using a spectrometric method, the method generating a first spectral data of wavelengths in VIS-NIR spectra region; and c) using a multivariate analysis to predict mechanical properties of decayed wood by comparing the first spectral data with a calibration model, the calibration model comprising a second spectrometric method of spectral data of wavelengths in VIS-NIR spectra obtained from a reference decay wood, the second spectral data being correlated with a known mechanical property analytical result obtained from the reference decayed wood.

  15. Genomics of wood-degrading fungi (Journal Article) | DOE PAGES

    Office of Scientific and Technical Information (OSTI)

    Genomics of wood-degrading fungi Prev Next Title: Genomics of wood-degrading fungi Authors: Ohm, Robin A. ; Riley, Robert ; Salamov, Asaf ; Min, Byoungnam ; Choi, In-Geol ; ...

  16. City of Wood River, Nebraska (Utility Company) | Open Energy...

    Open Energy Info (EERE)

    City of Wood River, Nebraska (Utility Company) Jump to: navigation, search Name: Wood River Municipal Power Place: Nebraska Phone Number: 308.583-2515; 308-583-2066 Website:...

  17. Wood County Electric Coop, Inc | Open Energy Information

    Open Energy Info (EERE)

    Wood County Electric Coop, Inc Jump to: navigation, search Name: Wood County Electric Coop, Inc Place: Texas Phone Number: 1-866-415-2951 Website: www.wcec.org Facebook: https:...

  18. Environmental-performance research priorities: Wood products. Final report

    SciTech Connect (OSTI)

    1998-01-15

    This report describes a research plan to establish environmental, energy, and economic performance measures for renewable building materials, and to identify management and technology alternatives to improve environmental performance in a cost-effective manner. The research plan is designed to: (1) collect environmental and economic data on all life-cycle stages of the materials, (2) ensure that the data follows consistent definitions and collection procedures, and (3) develop analytical procedures for life-cycle analysis to address environmental performance questions. The research will be subdivided into a number of individual project modules. The five processing stages of wood used to organize the research plan are: (1) resource management and harvesting; (2) processing; (3) design and construction of structures; (4) use, maintenance, and disposal; and (5) waste recycling. Individual research module descriptions are provided in the report, as well as assessment techniques, research standards and protocol, and research management. 13 refs., 5 figs., 3 tabs.

  19. One on One - Douglas K Woods | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    One on One - Douglas K Woods One on One - Douglas K Woods A September 2014 interview with Douglas K Woods, the President of the Association for Manufacturing Technology, on the state of US manufacturing. One on One - Douglas K Woods (97.92 KB) More Documents & Publications Printing a Car: A Team Effort in Innovation Printing a Car: A Team Effort in Innovation Advanced Microturbine System: Market Assessment, May 2003 Green Leasing Deployment Portfolio - 2014 BTO Peer Review

  20. Levelized life-cycle costs for four residue-collection systems and four gas-production systems

    SciTech Connect (OSTI)

    Thayer, G.R.; Rood, P.L.; Williamson, K.D. Jr.; Rollett, H.

    1983-01-01

    Technology characterizations and life-cycle costs were obtained for four residue-collection systems and four gas-production systems. All costs are in constant 1981 dollars. The residue-collection systems were cornstover collection, wheat-straw collection, soybean-residue collection, and wood chips from forest residue. The life-cycle costs ranged from $19/ton for cornstover collection to $56/ton for wood chips from forest residues. The gas-production systems were low-Btu gas from a farm-size gasifier, solar flash pyrolysis of biomass, methane from seaweed farms, and hydrogen production from bacteria. Life-cycle costs ranged from $3.3/10/sup 6/ Btu for solar flash pyrolysis of biomass to $9.6/10/sup 6/ Btu for hydrogen from bacteria. Sensitivity studies were also performed for each system. The sensitivity studies indicated that fertilizer replacement costs were the dominate costs for the farm-residue collection, while residue yield was most important for the wood residue. Feedstock costs were most important for the flash pyrolysis. Yields and capital costs are most important for the seaweed farm and the hydrogen from bacteria system.

  1. Commercial Demonstration of Wood Recovery, Recycling, and Value Adding Technologies

    SciTech Connect (OSTI)

    Auburn Machinery, Inc.

    2004-07-15

    This commercial demonstration project demonstrated the technical feasibility of converting low-value, underutilized and waste stream solid wood fiber material into higher valued products. With a growing need to increase product/production yield and reduce waste in most sawmills, few recovery operations and practically no data existed to support the viability of recovery operations. Prior to our efforts, most all in the forest products industry believed that recovery was difficult, extremely labor intensive, not cost effective, and that recovered products had low value and were difficult to sell. This project provided an opportunity for many within the industry to see through demonstration that converting waste stream material into higher valued products does in fact offer a solution. Our work, supported by the U.S. Department of Energy, throughout the project aimed to demonstrate a reasonable approach to reducing the millions of recoverable solid wood fiber tons that are annually treated as and converted into low value chips, mulch and fuel. Consequently sawmills continue to suffer from reduced availability of forest resources, higher raw material costs, growing waste disposal problems, increased global competition, and more pressure to operate in an Environmentally Friendly manner. It is our belief (based upon the experience of this project) that the successful mainstreaming of the recovery concept would assist in alleviating this burden as well as provide for a realistically achievable economic benefit to those who would seriously pursue the concept and tap into the rapidly growing ''GREEN'' building marketplace. Ultimately, with participation and aggressive pursuit of the recovery concept, the public would benefit in that: (1) Landfill/disposal waste volume could be reduced adding greater life to existing municipal landfill sites thereby minimizing the need to prematurely license and open added facilities. Also, there would be a cost avoidance benefit associated

  2. Fast Curing of Composite Wood Products

    SciTech Connect (OSTI)

    Dr. Arthur J. Ragauskas

    2006-04-26

    The overall objective of this program is to develop low temperature curing technologies for UF and PF resins. This will be accomplished by: • Identifying the rate limiting UF and PF curing reactions for current market resins; • Developing new catalysts to accelerate curing reactions at reduced press temperatures and times. In summary, these new curing technologies will improve the strength properties of the composite wood products and minimize the detrimental effects of wood extractives on the final product while significantly reducing energy costs for wood composites. This study is related to the accelerated curing of resins for wood composites such as medium density fiberboard (MDF), particle board (PB) and oriented strandboard (OSB). The latter is frequently manufactured with a phenol-formaldehyde resin whereas ureaformaldehyde (UF) resins are usually used in for the former two grades of composite wood products. One of the reasons that hinder wider use of these resins in the manufacturing of wood composites is the slow curing speed as well as inferior bondability of UF resin. The fast curing of UP and PF resins has been identified as an attractive process development that would allow wood to be bonded at higher moisture contents and at lower press temperatures that currently employed. Several differing additives have been developed to enhance cure rates of PF resins including the use of organic esters, lactones and organic carbonates. A model compound study by Conner, Lorenz and Hirth (2002) employed 2- and 4-hydroxymethylphenol with organic esters to examine the chemical basis for the reported enhanced reactivity. Their studies suggested that the enhance curing in the presence of esters could be due to enhanced quinone methide formation or enhanced intermolecular SN2 reactions. In either case the esters do not function as true catalysts as they are consumed in the reaction and were not found to be incorporated in the polymerized resin product. An

  3. Wood and Wood Waste - Energy Explained, Your Guide To Understanding Energy

    U.S. Energy Information Administration (EIA) Indexed Site

    - Energy Information Administration Wood and Wood Waste Energy Explained - Home What Is Energy? Forms of Energy Sources of Energy Laws of Energy Units and Calculators Energy Conversion Calculators British Thermal Units (Btu) Degree-Days U.S. Energy Facts State and U.S. Territory Data Use of Energy In Industry For Transportation In Homes In Commercial Buildings Efficiency and Conservation Energy and the Environment Greenhouse Gases Effect on the Climate Where Greenhouse Gases Come From

  4. Hygrothermal Performance of West Coast Wood Deck Roofing System

    SciTech Connect (OSTI)

    Pallin, Simon B; Kehrer, Manfred; Desjarlais, Andre Omer

    2014-02-01

    Simulations of roofing assemblies are necessary in order to understand and adequately predict actual the hygrothermal performance. At the request of GAF, simulations have been setup to verify the difference in performance between white and black roofing membrane colors in relation to critical moisture accumulation for traditional low slope wood deck roofing systems typically deployed in various western U.S. Climate Zones. The performance of these roof assemblies has been simulated in the hygrothermal calculation tool of WUFI, from which the result was evaluated based on a defined criterion for moisture safety. The criterion was defined as the maximum accepted water content for wood materials and the highest acceptable moisture accumulation rate in relation to the risk of rot. Based on the criterion, the roof assemblies were certified as being either safe, risky or assumed to fail. The roof assemblies were simulated in different western climates, with varying insulation thicknesses, two different types of wooden decking, applied with varying interior moisture load and with either a high or low solar absorptivity at the roof surface (black or white surface color). The results show that the performance of the studied roof assemblies differs with regard to all of the varying parameters, especially the climate and the indoor moisture load.

  5. Effect of species and wood to bark ratio on pelleting of southern woods

    SciTech Connect (OSTI)

    Bradfield, J.; Levi, M.P.

    1984-01-01

    Six common southern hardwoods and loblolly pine were pelleted in a laboratory pellet mill. The pellet furnishes were blended to test the effect of different wood to bark ratios on pellet durability and production rate. Included was a ratio chosen to simulate the wood to bark ratio found in whole-tree chips. This furnish produced good quality pellets for all species tested. Pelleting of the pure wood of hardwoods was not successful; furnish routinely blocked the pellet mill dies. Pure pine wood, however, did produce acceptable pellets. It was noted that, as lignin and extractive content increased above a threshold level, the precentage of fines produced in a pellet durability test increased. Thus, all pine and tupelo wood/bark mixes produces high fines. This reduces the desirability of the pellets in the marketplace. Further research is necessary to confirm this relationship. This study suggests that both tree species and wood/bark ratio affect the durability of pellets and the rate with which they can be produced in a laboratory pellet mill. 9 references.

  6. YAVAPAI APACHE NATION BIOMASS FEASIBILITY STUDY

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Materials Materials * Forest Trimmings - Wood * Agricultural Residues * Animal Manures * Human Biosolids * Municipal Solid Wastes * Carbonaceous Fossil Fuels Gasifier Process ...

  7. RESIDUAL STRESSES IN 3013 CONTAINERS

    SciTech Connect (OSTI)

    Mickalonis, J.; Dunn, K.

    2009-11-10

    The DOE Complex is packaging plutonium-bearing materials for storage and eventual disposition or disposal. The materials are handled according to the DOE-STD-3013 which outlines general requirements for stabilization, packaging and long-term storage. The storage vessels for the plutonium-bearing materials are termed 3013 containers. Stress corrosion cracking has been identified as a potential container degradation mode and this work determined that the residual stresses in the containers are sufficient to support such cracking. Sections of the 3013 outer, inner, and convenience containers, in both the as-fabricated condition and the closure welded condition, were evaluated per ASTM standard G-36. The standard requires exposure to a boiling magnesium chloride solution, which is an aggressive testing solution. Tests in a less aggressive 40% calcium chloride solution were also conducted. These tests were used to reveal the relative stress corrosion cracking susceptibility of the as fabricated 3013 containers. Significant cracking was observed in all containers in areas near welds and transitions in the container diameter. Stress corrosion cracks developed in both the lid and the body of gas tungsten arc welded and laser closure welded containers. The development of stress corrosion cracks in the as-fabricated and in the closure welded container samples demonstrates that the residual stresses in the 3013 containers are sufficient to support stress corrosion cracking if the environmental conditions inside the containers do not preclude the cracking process.

  8. Council of Athabascan Tribal Governments - Wood Energy Program in the Yukon Flats Region

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Collaborative Integrated Wood Energy Program for Fort Yukon Implementation DOE Tribal Energy Program 2 0 November 2008 Gwitchyaa Zhee Corporation CATG - AWEA For-Profit Wood Energy Business Model Fort Yukon * Forest Management Service - CATG * For-Profit Wood Utility Company - Vertically Integrated * Gwitchyaa Zhee Native Corporation - Wood Harvest Company - Village Wood Yard/Distribution Company - Wood Energy Utility - Diesel Biomass - Wood diesel hybrid power plant CHP - still dreaming for

  9. Life history and habitat associations of the broad wood cockroach, Parcoblatta lata (Blattaria: Blattellidae) and other native cockroaches in the Coastal Plain of South Carolina.

    SciTech Connect (OSTI)

    Horn, Scott; Hanula, James, L.

    2002-06-18

    Wood cockroaches are an important prey of the red-cockaded woodpecker, Picoides borealis, an endangered species inhabiting pine forests in the southern United States. These woodpeckers forage on the boles of live pine trees, but their prey consists of a high proportion of wood cockroaches, Parcoblatta spp., that are more commonly associated with dead plant material. Cockroach population density samples were conducted on live pine trees, dead snags and coarse woody debris on the ground. The studies showed that snags and logs are also important habitats of wood cockroaches in pine forests.

  10. Process to recycle shredder residue

    DOE Patents [OSTI]

    Jody, Bassam J.; Daniels, Edward J.; Bonsignore, Patrick V.

    2001-01-01

    A system and process for recycling shredder residue, in which separating any polyurethane foam materials are first separated. Then separate a fines fraction of less than about 1/4 inch leaving a plastics-rich fraction. Thereafter, the plastics rich fraction is sequentially contacted with a series of solvents beginning with one or more of hexane or an alcohol to remove automotive fluids; acetone to remove ABS; one or more of EDC, THF or a ketone having a boiling point of not greater than about 125.degree. C. to remove PVC; and one or more of xylene or toluene to remove polypropylene and polyethylene. The solvents are recovered and recycled.

  11. Immobilization of Rocky Flats graphite fines residues

    SciTech Connect (OSTI)

    Rudisill, T.S.; Marra, J.C.; Peeler, D.K.

    1999-07-01

    The Savannah River Technology Center (SRTC) is developing an immobilization process for graphite fines residues generated during nuclear materials production activities at the Rocky Flats Environmental Technology Site (Rocky Flats). The continued storage of this material has been identified as an item of concern. The residue was generated during the cleaning of graphite casting molds and potentially contains reactive plutonium metal. The average residue composition is 73 wt% graphite, 15 wt% calcium fluoride (CaF{sub 2}), and 12 wt% plutonium oxide (PuO{sub 2}). Approximately 950 kg of this material are currently stored at Rocky Flats. The strategy of the immobilization process is to microencapsulate the residue by mixing with a sodium borosilicate (NBS) glass frit and heating at nominally 700 C. The resulting waste form would be sent to the Waste Isolation Pilot Plant (WIPP) for disposal. Since the PuO{sub 2} concentration in the residue averages 12 wt%, the immobilization process was required to meet the intent of safeguards termination criteria by limiting plutonium recoverability based on a test developed by Rocky Flats. The test required a plutonium recovery of less than 4 g/kg of waste form when a sample was leached using a nitric acid/CaF{sub 2} dissolution flowsheet. Immobilization experiments were performed using simulated graphite fines with cerium oxide (CeO{sub 2}) as a surrogate for PuO{sub 2} and with actual graphite fines residues. Small-scale surrogate experiments demonstrated that a 4:1 frit to residue ratio was adequate to prevent recovery of greater than 4 g/kg of cerium from simulated waste forms. Additional experiments investigated the impact of varying concentrations of CaF{sub 2} and the temperature/heating time cycle on the cerium recovery. Optimal processing conditions developed during these experiments were subsequently demonstrated at full-scale with surrogate materials and on a smaller scale using actual graphite fines.

  12. Renewed interest in prop supports as a replacement for wood cribs

    SciTech Connect (OSTI)

    Barczak, T.M.; Gearhart, D.F.

    1995-11-01

    Wood cribs have been the dominant form of supplemental support in coal mining for many years. Recently, there has been a renewed interest in prop supports as a replacement for wood cribbing due to the increasing cost of mine timber and engineering advancements in prop design to improve their stability and yield capability. Prop supports generally consume less material, can be installed in less time with less labor, and provide less restriction to mine ventilation than wood crib supports. Several prop supports are now available or under development. These include: (1) Strata Products Propsetter{trademark} Support System, (2) Heintzmann ACS and Super Prop; (3) MBK-Hydraulik MEGA prop; (4) Advanced Mining Technology Inc. (AMTI) BTS Mortar prop; (5) Dywidag Coal Post; (6) Western Support Systems YIPPI support; and (7) ``The Can`` support by Burrell Mining Products. A comparison of the performance and cost of these support systems to wood cribs is made to provide mine operators with information needed to underground installations are discussed. Included in this assessment are full scale tests of these supports conducted in the US Bureau of Mines` Mine Roof Stimulator.

  13. Research into the pyrolysis of pure cellulose, lignin, and birch wood flour in the China Lake entrained-flow reactor

    SciTech Connect (OSTI)

    Diebold, J.

    1980-06-01

    This experimental program used the China Lake entrained-flow pyrolysis reactor to briefly investigate the pyrolysis of pure cellulose, pure lignin, and birch wood flour. The study determined that the cellulose and wood flour do pyrolyze to produce primarily gaseous products containing significant amounts of ethylene and other useful hydrocarbons. During attempts to pyrolyze powdered lignin, the material melted and bubbled to block the reactor entrance. The pure cellulose and wood flour produced C/sub 2/ + yields of 12% to 14% by weight, which were less than yields from an organic feedstock derived from processed municipal trash. The char yields were 0.1% by weight from cellulose and 1.5% from birch wood flour - one to two orders of magnitude less than were produced from the trash-derived feedstock. In scanning electron microscope photographs, most of the wood flour char had a sintered and agglomerated appearance, although some particles retained the gross cell characteristics of the wood flour. The appearance of the char particles indicated that the material had once been molten and possibly vapor before it formed spheroidal particles about 1 ..mu..m diameter which agglomerated to form larger char particles. The ability to completely melt or vaporize lignocellulosic materials under conditions of high heating rates has now been demonstrated in a continuous flow reactor and promises new techniques for fast pyrolysis. This char was unexpectedly attracted by a magnet, presumably because of iron contamination from the pyrolysis reactor tube wall. The production of water-insoluble tars was negligible compared to the tars produced from trash-derived feedstock. The production of water-soluble organic materials was fairly low and qualitatively appeared to vary inversely with temperature. This study was of a preliminary nature and additional studies are necessary to optimize ethylene production from these feedstocks.

  14. Hanford Tank Waste Residuals

    Office of Environmental Management (EM)

    Hanford Tank Waste Residuals DOE HLW Corporate Board November 6, 2008 Chris Kemp, DOE ORP Bill Hewitt, YAHSGS LLC Hanford Tanks & Tank Waste * Single-Shell Tanks (SSTs) - 27 million ...

  15. Method for improving separation of carbohydrates from wood pulping and wood or biomass hydrolysis liquors

    DOE Patents [OSTI]

    Griffith, William Louis; Compere, Alicia Lucille; Leitten, Jr., Carl Frederick

    2010-04-20

    A method for separating carbohydrates from pulping liquors includes the steps of providing a wood pulping or wood or biomass hydrolysis pulping liquor having lignin therein, and mixing the liquor with an acid or a gas which forms an acid upon contact with water to initiate precipitation of carbohydrate to begin formation of a precipitate. During precipitation, at least one long chain carboxylated carbohydrate and at least one cationic polymer, such as a polyamine or polyimine are added, wherein the precipitate aggregates into larger precipitate structures. Carbohydrate gel precipitates are then selectively removed from the larger precipitate structures. The method process yields both a carbohydrate precipitate and a high purity lignin.

  16. Massachusetts Schools Switch to Wood Pellets | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Massachusetts Schools Switch to Wood Pellets Massachusetts Schools Switch to Wood Pellets August 20, 2015 - 5:22pm Addthis Art created by a student at John Briggs Elementary School as part of their recent Green Ceremony. John Briggs Elementary is one of the Massachusetts schools switching their heating fuel source from petroleum based fuels to wood pellets. Art created by a student at John Briggs Elementary School as part of their recent Green Ceremony. John Briggs Elementary is one of the

  17. Wood-Burning Heating System Deduction | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    State Alabama Program Type Rebate Amount 100% Summary This statute allows individual taxpayers a deduction for the purchase and installation of a wood-burning heating system. The...

  18. Water Sampling At Dixie Valley Geothermal Area (Wood, 2002) ...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water Sampling At Dixie Valley Geothermal Area (Wood, 2002) Exploration Activity Details...

  19. Water Sampling At Little Valley Area (Wood, 2002) | Open Energy...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water Sampling At Little Valley Area (Wood, 2002) Exploration Activity Details Location...

  20. Water Sampling At Alvord Hot Springs Area (Wood, 2002) | Open...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water Sampling At Alvord Hot Springs Area (Wood, 2002) Exploration Activity Details Location...

  1. Water Sampling At Beowawe Hot Springs Area (Wood, 2002) | Open...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water Sampling At Beowawe Hot Springs Area (Wood, 2002) Exploration Activity Details...

  2. Water Sampling At Salton Sea Area (Wood, 2002) | Open Energy...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water Sampling At Salton Sea Area (Wood, 2002) Exploration Activity Details Location Salton...

  3. Water Sampling At Mccredie Hot Springs Area (Wood, 2002) | Open...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water Sampling At Mccredie Hot Springs Area (Wood, 2002) Exploration Activity Details...

  4. Water Sampling At Umpqua Hot Springs Area (Wood, 2002) | Open...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water Sampling At Umpqua Hot Springs Area (Wood, 2002) Exploration Activity Details Location...

  5. Water Sampling At Zim's Hot Springs Geothermal Area (Wood, 2002...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water Sampling At Zim's Hot Springs Geothermal Area (Wood, 2002) Exploration Activity...

  6. Water Sampling At Heber Area (Wood, 2002) | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water Sampling At Heber Area (Wood, 2002) Exploration Activity Details Location Heber Area...

  7. Water Sampling At Breitenbush Hot Springs Area (Wood, 2002) ...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water Sampling At Breitenbush Hot Springs Area (Wood, 2002) Exploration Activity Details...

  8. Water Sampling At Crane Hot Springs Area (Wood, 2002) | Open...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water Sampling At Crane Hot Springs Area (Wood, 2002) Exploration Activity Details Location...

  9. Water Sampling At Mickey Hot Springs Area (Wood, 2002) | Open...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water Sampling At Mickey Hot Springs Area (Wood, 2002) Exploration Activity Details Location...

  10. Title: Ames Blue Alert- Wood Cabinet Falls Apart

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ames Blue Alert- Wood Cabinet Falls Apart Lessons Learned Statement- Cumulative damage can cause a loss of structural integrity. When furnishings are repeatedly exposed to water,...

  11. International WoodFuels LLC | Open Energy Information

    Open Energy Info (EERE)

    Maine Zip: 4101 Product: Maine-based pellet producer and installer of commercial wood pellet heating systems. Coordinates: 45.511795, -122.675629 Show Map Loading map......

  12. Building America Case Study: Retrofit Measure for Embedded Wood...

    Energy Savers [EERE]

    Existing Homes Building America Case Study Retrofit Measures for Embedded Wood Members in Insulated Mass Masonry Walls Lawrence, Massachusetts PROJECT INFORMATION Project Name: The...

  13. Thermal Pretreatment of Wood for Cogasification/cofiring of Biomass...

    Office of Scientific and Technical Information (OSTI)

    ...cofiring of Biomass and Coal Citation Details In-Document Search Title: Thermal Pretreatment of Wood for Cogasificationcofiring of Biomass and Coal Utilization of biomass as a ...

  14. Method for residual stress relief and retained austenite destabilization

    DOE Patents [OSTI]

    Ludtka, Gerard M.

    2004-08-10

    A method using of a magnetic field to affect residual stress relief or phase transformations in a metallic material is disclosed. In a first aspect of the method, residual stress relief of a material is achieved at ambient temperatures by placing the material in a magnetic field. In a second aspect of the method, retained austenite stabilization is reversed in a ferrous alloy by applying a magnetic field to the alloy at ambient temperatures.

  15. The Pennsylvanian and Permian Oquirrh-Wood River basin

    SciTech Connect (OSTI)

    Geslin, J.K. . Dept. of Earth and Planetary Sciences)

    1993-04-01

    Strata of the Middle Pennsylvanian to Lower Permian Oquirrh-Wood River Basin (OWRB) lie unconformably above the Antler orogenic belt and flysch trough/starved basin in NW Utah, NE Nevada, and SC Idaho. Strata of the basin, now separated geographically by the Neogene Snake River Plain, show similar subsidence histories, identical mixed carbonate-siliciclastic sedimentary fill, and identical chert pebble conglomerate beds supplied by one or more DesMoinesian uplifts containing Lower Paleozoic strata. This conglomerate, of the lower Sun Valley Group, Snaky Canyon Formation, and parts of the Oquirrh Formation, was reworked progressively southward, to at least the Idaho-Utah border. It is present in strata as young as Virgilian. Virgilian to Leonardian rocks are ubiquitously fine-grained mixed carbonate-siliciclastic turbidites. These rocks contain cratonal, well-sorbed subarkosic and quartzose sand and silt in part derived from the Canadian Shield. This siliciclastic fraction is intimately mixed with arenaceous micritized skeletal material and peloids derived from an eastern carbonate platform represented by the Snaky Canyon Formation in east-central Idaho, an eastern facies of the Eagle Creek Member, Wood River Formation in the Boulder Mountains, and the Oquirrh Formation in the Deep Creek Mountains. Subsidence of the OWRB may have been caused by two phases (DesMoinesian and Wolfcampian to Leonardian) of crustal loading by continental margin tectonism to the west. An elevated rim separated the OWRB from coeval volcanogenic basins to the west. Earlier, Antler-age structures may have been reactivated. A new pulse of tectonism occurred in Leonardian to Guadalupian time as in most places carbonatic and phosphatic strata of the Leonardian to Guadalupian Park City and Phosphoria Formation overlie OWRB strata, with different geographic arrangement of basinal, slope, and shelf depocenters.

  16. Wood Pulp Digetster Wall Corrosion Investigation

    SciTech Connect (OSTI)

    Giles, GE

    2003-09-18

    The modeling of the flow in a wood pulp digester is but one component of the investigation of the corrosion of digesters. This report describes the development of a Near-Wall-Model (NWM) that is intended to couple with a CFD model that determines the flow, heat, and chemical species transport and reaction within the bulk flow of a digester. Lubrication theory approximations were chosen from which to develop a model that could determine the flow conditions within a thin layer near the vessel wall using information from the interior conditions provided by a CFD calculation of the complete digester. The other conditions will be determined by coupled solutions of the wood chip, heat, and chemical species transport and chemical reactions. The NWM was to couple with a digester performance code in an iterative fashion to provide more detailed information about the conditions within the NW region. Process Simulations, Ltd (PSL) is developing the digester performance code. This more detailed (and perhaps more accurate) information from the NWM was to provide an estimate of the conditions that could aggravate the corrosion at the wall. It is intended that this combined tool (NWM-PSL) could be used to understand conditions at/near the wall in order to develop methods to reduce the corrosion. However, development and testing of the NWM flow model took longer than anticipated and the other developments (energy and species transport, chemical reactions and linking with the PSL code) were not completed. The development and testing of the NWM are described in this report. In addition, the investigation of the potential effects of a clear layer (layer reduced in concentration of wood chips) near the wall is reported in Appendix D. The existence of a clear layer was found to enhance the flow near the wall.

  17. How chip size impacts steam pretreatment effectiveness for biological conversion of poplar wood into fermentable sugars

    SciTech Connect (OSTI)

    DeMartini, Jaclyn D.; Foston, Marcus; Meng, Xianzhi; Jung, Seokwon; Kumar, Rajeev; Ragauskas, Arthur J.; Wyman, Charles E.

    2015-12-09

    We report that woody biomass is highly recalcitrant to enzymatic sugar release and often requires significant size reduction and severe pretreatments to achieve economically viable sugar yields in biological production of sustainable fuels and chemicals. However, because mechanical size reduction of woody biomass can consume significant amounts of energy, it is desirable to minimize size reduction and instead pretreat larger wood chips prior to biological conversion. To date, however, most laboratory research has been performed on materials that are significantly smaller than applicable in a commercial setting. As a result, there is a limited understanding of the effects that larger biomass particle size has on the effectiveness of steam explosion pretreatment and subsequent enzymatic hydrolysis of wood chips. To address these concerns, novel downscaled analysis and high throughput pretreatment and hydrolysis (HTPH) were applied to examine whether differences exist in the composition and digestibility within a single pretreated wood chip due to heterogeneous pretreatment across its thickness. Heat transfer modeling, Simons’ stain testing, magnetic resonance imaging (MRI), and scanning electron microscopy (SEM) were applied to probe the effects of pretreatment within and between pretreated wood samples to shed light on potential causes of variation, pointing to enzyme accessibility (i.e., pore size) distribution being a key factor dictating enzyme digestibility in these samples. Application of these techniques demonstrated that the effectiveness of pretreatment of Populus tremuloides can vary substantially over the chip thickness at short pretreatment times, resulting in spatial digestibility effects and overall lower sugar yields in subsequent enzymatic hydrolysis. Finally, these results indicate that rapid decompression pretreatments (e.g., steam explosion) that specifically alter accessibility at lower temperature conditions are well suited for larger wood

  18. How chip size impacts steam pretreatment effectiveness for biological conversion of poplar wood into fermentable sugars

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    DeMartini, Jaclyn D.; Foston, Marcus; Meng, Xianzhi; Jung, Seokwon; Kumar, Rajeev; Ragauskas, Arthur J.; Wyman, Charles E.

    2015-12-09

    We report that woody biomass is highly recalcitrant to enzymatic sugar release and often requires significant size reduction and severe pretreatments to achieve economically viable sugar yields in biological production of sustainable fuels and chemicals. However, because mechanical size reduction of woody biomass can consume significant amounts of energy, it is desirable to minimize size reduction and instead pretreat larger wood chips prior to biological conversion. To date, however, most laboratory research has been performed on materials that are significantly smaller than applicable in a commercial setting. As a result, there is a limited understanding of the effects that largermore » biomass particle size has on the effectiveness of steam explosion pretreatment and subsequent enzymatic hydrolysis of wood chips. To address these concerns, novel downscaled analysis and high throughput pretreatment and hydrolysis (HTPH) were applied to examine whether differences exist in the composition and digestibility within a single pretreated wood chip due to heterogeneous pretreatment across its thickness. Heat transfer modeling, Simons’ stain testing, magnetic resonance imaging (MRI), and scanning electron microscopy (SEM) were applied to probe the effects of pretreatment within and between pretreated wood samples to shed light on potential causes of variation, pointing to enzyme accessibility (i.e., pore size) distribution being a key factor dictating enzyme digestibility in these samples. Application of these techniques demonstrated that the effectiveness of pretreatment of Populus tremuloides can vary substantially over the chip thickness at short pretreatment times, resulting in spatial digestibility effects and overall lower sugar yields in subsequent enzymatic hydrolysis. Finally, these results indicate that rapid decompression pretreatments (e.g., steam explosion) that specifically alter accessibility at lower temperature conditions are well suited for larger

  19. Upgrading residual oil

    SciTech Connect (OSTI)

    Angevine, P.J.; Stein, T.R.

    1982-04-13

    Residual oil fractions are upgraded in that Conradson Carbon Residue (CCR) is selectively removed without undue hydrogen consumption by hydroprocessing with a catalyst comprising a single metal such as molybdenum, tungsten, nickel, iron or palladium or multimetallic combination of such metals, excluding, however, active desulfurization compositions such as nickel molybdenum and nickel-tungsten. Said catalyst is characterized as having greater than about 50% of its pore volume contribution in pores having diameters in the range of between about 100 and 200 angstroms. The product of such hydroprocessing is a particularly preferable feedstock for coking to give more liquid yield and less coke make.

  20. Fuels for Schools Program Uses Leftover Wood to Warm Buildings

    Broader source: Energy.gov [DOE]

    In parts of this country, wood seems like the outsider in the biomass family. New ethanol plants that grind down millions of bushels of corn in the Midwest and breakthroughs in algae along the coasts always garner the most attention. But in states like Montana, a place with over 70 million acres of forest, wood is the biofuel of choice.

  1. Investigations of release phenomenon of volatile organic compounds and particulates from residual storage chip piles

    SciTech Connect (OSTI)

    Mohan, S.; Nagarkatti, M.

    1996-12-31

    This paper outlines the method for estimating Particulate Matter and Volatile Organic Compounds (VOCs) emissions from wood handling and storage operations at a pulp mill. Fugitive particulate matter emissions from wood handling and storage operations are due to material load/dropout operations, wind erosion from storage piles and vehicular traffic on paved roads. The particulate matter emissions are a function of a number of variables like windspeed, surface moisture content, material silt content, and number of days of precipitation. Literature review attributes VOC emissions to biological, microbiological, chemical, and physical processes occurring in wood material storage pile. The VOC emissions are from the surface of these piles and the VOC released during retrieval of chips from the pile. VOC emissions are based on the chip throughput, number of turnovers, moisture content and surface area of the pile. The emission factors with the requisite calculation methodology to be utilized for quantifying VOC emissions from chip piles has been discussed in this paper.

  2. Materials Videos

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Materials Videos Materials

  3. Wood fuel technologies and group-oriented Timber Stand Improvement Program: model for waste wood utilization and resource renewal

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    Progress is reported on the following: educating and assisting landowners in the most efficient and profitable use of wood resources; developing local timber resources as energy alternatives by representing collective interests to Consumers Power, the woodchip industry, firewood retailers, country residents, and woodlot owners; and providing public information on the economics and methods of wood heat as a supplemental energy source. (MHR)

  4. Multipass comminution process to produce precision wood particles of uniform size and shape with disrupted grain structure from wood chips

    DOE Patents [OSTI]

    Dooley, James H; Lanning, David N

    2014-05-27

    A process of comminution of wood chips (C) having a grain direction to produce a mixture of wood particles (P), wherein the wood chips are characterized by an average length dimension (L.sub.C) as measured substantially parallel to the grain, an average width dimension (W.sub.C) as measured normal to L.sub.C and aligned cross grain, and an average height dimension (H.sub.C) as measured normal to W.sub.C and L.sub.C, and wherein the comminution process comprises the step of feeding the wood chips in a direction of travel substantially randomly to the grain direction one or more times through a counter rotating pair of intermeshing arrays of cutting discs (D) arrayed axially perpendicular to the direction of wood chip travel.

  5. Implementing Strategies for Drying and Pressing Wood Without Emissions Controls

    SciTech Connect (OSTI)

    Sujit Banerjee; Terrance Conners

    2007-09-07

    Drying and pressing wood for the manufacture of lumber, particleboard, oriented strand board (OSB), veneer and medium density fiberboard (MDF) release volatile organic compounds (VOCs) into the atmosphere. These emissions require control equipment that are capital-intensive and consume significant quantities of natural gas and electricity. The objective of our work was to understand the mechanisms through which volatile organic compounds are generated and released and to develop simple control strategies. Of the several strategies developed, two have been implemented for OSB manufacture over the course of this study. First, it was found that increasing final wood moisture by about 2-4 percentage points reduced the dryer emissions of hazardous air pollutants by over 70%. As wood dries, the escaping water evaporatively cools the wood. This cooling tapers off wood when the wood is nearly dry and the wood temperature rises. Thermal breakdown of the wood tissue occurs and VOCs are released. Raising the final wood moisture by only a few percentage points minimizes the temperature rise and reduces emissions. Evaporative cooling also impacts has implications for VOC release from wood fines. Flaking wood for OSB manufacture inevitable generates fines. Fines dry out rapidly because of their high surface area and evaporative cooling is lost more rapidly than for flakes. As a result, fines emit a disproportionate quantity of VOCs. Fines can be reduced in two ways: through screening of the green furnish and through reducing their generation during flaking. The second approach is preferable because it also increased wood yield. A procedure to do this by matching the sharpness angle of the flaker knife to the ambient temperature was also developed. Other findings of practical interests are as follows: Dielectric heating of wood under low-headspace conditions removes terpenes and other extractives from softwood; The monoterpene content in trees depend upon temperature and seasonal

  6. SRC residual fuel oils

    SciTech Connect (OSTI)

    Tewari, K.C.; Foster, E.P.

    1985-10-15

    Coal solids (SRC) and distillate oils are combined to afford single-phase blends of residual oils which have utility as fuel oils substitutes. The components are combined on the basis of their respective polarities, that is, on the basis of their heteroatom content, to assure complete solubilization of SRC. The resulting composition is a fuel oil blend which retains its stability and homogeneity over the long term.

  7. SRC Residual fuel oils

    DOE Patents [OSTI]

    Tewari, Krishna C.; Foster, Edward P.

    1985-01-01

    Coal solids (SRC) and distillate oils are combined to afford single-phase blends of residual oils which have utility as fuel oils substitutes. The components are combined on the basis of their respective polarities, that is, on the basis of their heteroatom content, to assure complete solubilization of SRC. The resulting composition is a fuel oil blend which retains its stability and homogeneity over the long term.

  8. Wood-Polymer composites obtained by gamma irradiation

    SciTech Connect (OSTI)

    Gago, J.; Lopez, A.; Rodriguez, J.; Santiago, J.; Acevedo, M.

    2007-10-26

    In this work we impregnate three Peruvian woods (Calycophy spruceanum Be, Aniba amazonica Meiz and Hura crepitans L) with styrene-polyester resin and methyl methacrylate. The polymerization of the system was promoted by gamma radiation and the experimental optimal condition was obtained with styrene-polyester 1:1 and 15 kGy. The obtained composites show reduced water absorption and better mechanical properties compared to the original wood. The structure of the wood-polymer composites was studied by light microscopy. Water absorption and hardness were also obtained.

  9. Wood chips: an exploration of problems and opportunities. Final report

    SciTech Connect (OSTI)

    Not Available

    1985-01-01

    This report evaluates the current use of and potential market for wood chips as a fuel in the Northeast. This study covers the residential, commercial, and light industrial sectors and addresses cost, reliability, marketing systems, and technology improvements. A review of the available equipment for wood chip harvesting, processing, handling, drying, and transport is included. Three representative strategic business guides for different chip suppliers are presented. There is also a recommended action plan for future programs with initiatives that could facilitate the development of the wood chip market. 25 refs., 8 figs., 11 tabs.

  10. Method for lowering the VOCS emitted during drying of wood products

    DOE Patents [OSTI]

    Banerjee, Sujit (1832 Jacksons Creek Point, Marietta, GA 30068); Boerner, James Robert (154 Junedale Rd., Cincinnati, OH 45218); Su, Wei (2262 Orleans Ave., Marietta, GA 30062)

    2000-01-01

    The present invention is directed to a method for removal of VOCs from wood products prior to drying the wood products. The method of the invention includes the steps of providing a chamber having an opening for receiving wood and loading the chamber with green wood. The wood is loaded to an extent sufficient to provide a limited headspace in the chamber. The chamber is then closed and the wood is heated in the chamber for a time and at a temperature sufficient to saturate the headspace with moisture and to substantially transfer VOCs from the wood product to the moisture in the headspace.

  11. Comparison of residual stresses ...

    Office of Scientific and Technical Information (OSTI)

    C. Duty 1 Chemical and Engineering Materials Division, Oak ... and Biomedical Engineering, University of ... to be the best option for water quenched and aged Ni-based ...

  12. Laguna Woods, California: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Laguna Woods is a city in Orange County, California. It falls under California's 48th...

  13. Mission Woods, Kansas: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    article is a stub. You can help OpenEI by expanding it. Mission Woods is a city in Johnson County, Kansas. It falls under Kansas's 3rd congressional district.12 References...

  14. Huntington Woods, Michigan: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Huntington Woods is a city in Oakland County, Michigan. It falls under Michigan's 12th...

  15. Wood Dale, Illinois: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Wood Dale is a city in DuPage County, Illinois. It falls under Illinois' 6th congressional...

  16. Wood County, West Virginia: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Wood County is a county in West Virginia. Its FIPS County Code is 107. It is classified as...

  17. Wood County, Texas: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Wood County is a county in Texas. Its FIPS County Code is 499. It is classified as ASHRAE...

  18. Wood Village, Oregon: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Wood Village is a city in Multnomah County, Oregon. It falls under Oregon's 3rd...

  19. Wood-Ridge, New Jersey: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Wood-Ridge, New Jersey: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 40.8456555, -74.0879195 Show Map Loading map... "minzoom":false,"mappin...

  20. Study of emissions from small woods - fired boiler systems

    SciTech Connect (OSTI)

    1994-12-31

    This short article announces a testing project RFP to determine the air emissions produced by small wood-chip fired combustion systems and to determine associated health risks if any.

  1. Improving combustion in residential size wood chip fireboxes

    SciTech Connect (OSTI)

    Huff, E.R.

    1982-12-01

    In a small experimental wood chip firebox with separate control of grate and overfire air, combustion intensity was increased with reduction in flyash and carbon monoxide by reducing air through the grate to a small fraction of stoichiometric air.

  2. Community Based Wood Heat System for Fort Yukon

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    80,000 acres in one month Proposed Rural Wood Fuel Supply System *Capital costs for system capable of producing 7,000 TPY: 600,000 Key Obstacles to Overcome Development...

  3. Wood-Composites Industry Benefits from ALS Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    that wood-composite development is something that will bolster the U.S. economy, matches the funding from the WBC. "People in this industry are always looking for ways to...

  4. Immobilization of Rocky Flats Graphite Fines Residues

    SciTech Connect (OSTI)

    Rudisill, T. S.

    1998-11-06

    The Savannah River Technology Center (SRTC) is developing an immobilization process for graphite fines residues generated during nuclear materials production activities at the Rocky Flats Environmental Technology Site (Rocky Flats). The continued storage of this material has been identified as an item of concern. The residue was generated during the cleaning of graphite casting molds and potentially contains reactive plutonium metal. The average residue composition is 73 wt percent graphite, 15 wt percent calcium fluoride (CaF2), and 12 wt percent plutonium oxide (PuO2). Approximately 950 kilograms of this material are currently stored at Rocky Flats. The strategy of the immobilization process is to microencapsulate the residue by mixing with a sodium borosilicate (NBS) glass frit and heating at nominally 700 degrees C. The resulting waste form would be sent to the Waste Isolation Pilot Plant (WIPP) for disposal. Since the PuO2 concentration in the residue averages 12 wt percent, the immobilization process was required to meet the intent of safeguards termination criteria by limiting plutonium recoverability based on a test developed by Rocky Flats. The test required a plutonium recovery of less than 4 g/kg of waste form when a sample was leached using a nitric acid/CaF2 dissolution flowsheet. Immobilization experiments were performed using simulated graphite fines with cerium oxide (CeO2) as a surrogate for PuO2 and with actual graphite fines residues. Small-scale surrogate experiments demonstrated that a 4:1 frit to residue ratio was adequate to prevent recovery of greater than 4 g/kg of cerium from simulated waste forms. Additional experiments investigated the impact of varying concentrations of CaF2 and the temperature/heating time cycle on the cerium recovery. Optimal processing conditions developed during these experiments were subsequently demonstrated at full-scale with surrogate materials and on a smaller scale using actual graphite fines.In general, the

  5. Council of Athabascan Tribal Governments - Wood Energy Feasibility Study

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Integrated Wood Energy Program for Yukon Flats Villages DOE Tribal Energy Program 20 November 2008 Feasibility for Wood Heat Council of Athabascan Tribal Governments (CATG) * Non-Profit Consortium of Ten Tribal Governments within the Yukon Flats. * CATG Administers several Tribal Programs on behalf of the Tribes. * CATG also applies for and administers several other grants. - IHS, Regional Clinic (Fort Yukon), Health Aids in Each Village, drug and alcohol programs, and other health related

  6. How Much Wood Would a North Country School Chip

    Office of Energy Efficiency and Renewable Energy (EERE)

    North Country School in Lake Placid, New York, recently installed a high-efficiency wood chip boiler using Recovery Act funds from the New York State Energy Research and Development Authority. Using wood sourced from their sustainably managed woodlot and local forests, the school will be able to cut energy costs by $38,970 annually and reduce carbon dioxide emissions by 184 tons per year.

  7. Evaluation of processes for producing gasoline from wood. Final report

    SciTech Connect (OSTI)

    1980-05-01

    Three processes for producing gasoline from wood by pyrolysis have been investigated. Technical and economic comparisons among the processes have been made, based on a hypothetical common plant size of 2000 tons per day green wood chip feedstock. In order to consider the entire fuel production process, the energy and cost inputs for producing and delivering the feedstock were included in the analysis. In addition, perspective has been provided by comparisons of the wood-to-gasoline technologies with other similar systems, including coal-to-methanol and various biomass-to-alcohol systems. Based on several assumptions that were required because of the candidate processes' information gaps, comparisons of energy efficiency were made. Several descriptors of energy efficiency were used, but all showed that methanol production from wood, with or without subsequent processing by the Mobil route to gasoline, appears most promising. It must be emphasized, however, that the critical wood-to-methanol system remains conceptual. Another observation was that the ethanol production systems appear inferior to the wood-to-gasoline processes. Each of the processes investigated requires further research and development to answer the questions about their potential contributions confidently. The processes each have so many unknowns that it appears unwise to pursue any one while abandoning the others.

  8. Development and demonstration of a wood-fired gas turbine system

    SciTech Connect (OSTI)

    Smith, V.; Selzer, B.; Sethi, V.

    1993-08-01

    The objectives of the test program were to obtain some preliminary information regarding the nature of particulate and vapor phase alkali compounds produced and to assess any deleterious impact they might have on materials of construction. Power Generating Incorporated (PGI) is developing a wood-fired gas turbine system for specialized cogeneration applications. The system is based on a patented pressurized combustor designed and tested by PGI in conjunction with McConnell Industries. The other components of the system are fuel receiving, preparation, storage and feeding system, gas clean-up equipment, and a gas turbine generator.

  9. Moisture Distribution and Flow During Drying of Wood and Fiber

    SciTech Connect (OSTI)

    Zink-Sharp, Audrey; Hanna, Robert B.

    2001-12-28

    New understanding, theories, and techniques for moisture flow and distribution were developed in this research on wood and wood fiber. Improved understanding of the mechanisms of flake drying has been provided. Observations of flake drying and drying rate curves revealed that rate of moisture loss consisted of two falling rate periods and no constant rate drying period was observed. Convective heat transfer controls the first period, and bound water diffusion controls the second period. Influence of lower drying temperatures on bending properties of wood flakes was investigated. Drying temperature was found to have a significant influence on bending stiffness and strength. A worksheet for calculation of the energy required to dry a single strandboard flake was developed but has not been tested in an industrial setting yet. A more complete understanding of anisotropic transverse shrinkage of wood is proposed based on test results and statistical analysis. A simplified mod el of a wood cell's cross-section was drawn for calculating differential transverse shrinkage. The model utilizes cell wall thickness and microfibrillar packing density and orientation. In spite of some phenomena of cell wall structure not yet understood completely, the results might explain anisotropic transverse shrinkage to a major extent. Boundary layer theory was found useful for evaluating external moisture resistance during drying. Simulated moisture gradients were quire comparable to the actual gradients in dried wood. A mathematical procedure for determining diffusion and surface emission coefficients was also developed. Thermal conductivity models of wood derived from its anatomical structure were created and tested against experimental values. Model estimations provide insights into changes in heat transfer parameters during drying. Two new techniques for measuring moisture gradients created in wood during drying were developed. A new technique that utilizes optical properties of cobalt

  10. Staged heating by oxidation of carbonaceous material

    DOE Patents [OSTI]

    Knell, Everett W.; Green, Norman W.

    1978-01-31

    A carbonaceous material is pyrolyzed in the presence of a particulate source of heat obtained by the partial oxidation of a carbon containing solid residue of the carbonaceous material. The heat obtained from the oxidation of the carbon containing solid residue is maximized by preheating the carbon containing solid residue with a hot gas stream obtained by oxidizing the gaseous combustion products of the carbon containing solid residue.

  11. Residuals in steel products -- Impacts on properties and measures to minimize them

    SciTech Connect (OSTI)

    Emi, Toshihiko; Wijk, O.

    1996-12-31

    The effect of major residual elements on the properties of steel products is summarized. Measures to minimize these elements are discussed including the pretreatment of raw materials, innovative refining processes and environmental issues. This paper addresses (1) scrap situation, (2) upper limit of residual concentrations acceptable for processing and product quality, (3) possible means to reduce the residuals, and (4) consideration on the practicable measures to solve the residuals problem in a systematic way. 52 refs.

  12. Performance of a small underfed wood chip-fired stoker in a hot air-heated home

    SciTech Connect (OSTI)

    Schneider, M.H.

    1983-01-01

    The goal of the study was to provide space heat for a home using forest biomass presently not in demand by industry, and by using a convenient, automatic, low-emission heating system. A stoker firing wood chips was installed in a home, and chips were prepared for it from the residues of a softwood clearcut. Residues from 1 and a quarter acre provided enough fuel to heat the house for the heating season. The chip-fired heating system was convenient, maintained the house at whatever temperature was set on the room thermostat, and generated little creosote or wood smoke. It was better at converting fuel to heat than the previous combustion heating systems in the house, with steady-state combustion efficiency of approximately 75% and longer-term appliance efficiency of 69%. Electric energy required for heating hot water was reduced approximately 27% as a result of a preheating coil located in the chip-fired furnace. The major cause of heat interruptions was jamming of the stoker which occurred on the average of every 18 and a half days. Clearing such jams was simple. The system operated safely throughout the test period.

  13. Environmental and economic evaluation of energy recovery from agricultural and forestry residues

    SciTech Connect (OSTI)

    1980-09-01

    Four conversion methods and five residues are examined in this report, which describes six model systems: hydrolysis of corn residues, pyrolysis of corn residues, combustion of cotton-ginning residues, pyrolysis of wheat residues, fermentation of molasses, and combustion of pulp and papermill wastes. Estimates of material and energy flows for those systems are given per 10/sup 12/ Btu of recovered energy. Regional effects are incorporated by addressing the regionalized production of the residues. A national scope cannot be provided for every residue considered because of the biological and physical constraints of crop production. Thus, regionalization of the model systems to the primary production region for the crop from which the residue is obtained has been undertaken. The associated environmental consequences of residue utilization are then assessed for the production region. In addition, the environmental impacts of operating the model systems are examined by quantifying the residuals generated and the land, water, and material requirements per 10/sup 12/ Btu of energy generated. On the basis of estimates found in the literature, capital, operating, and maintenance cost estimates are given for the model systems. These data are also computed on the basis of 10/sup 12/ Btu of energy recovered. The cost, residual, material, land, and water data were then organized into a format acceptable for input into the SEAS data management program. The study indicates that the most serious environmental impacts arise from residue removal rather than from conversion.

  14. Characterization of ashes from co-combustion of refuse-derived fuel with coal, wood and bark in a fluidized bed

    SciTech Connect (OSTI)

    Zevenhoven, R.; Skrifvars, B.J.; Hupa, M.

    1998-12-31

    The technical and environmental feasibility of co-combustion of a recovered fuel (RF) prepared from combustible waste fractions (separated at the source), together with coal, peat, wood or wood-waste in thermal power/electricity generation has been studied in several R and D projects within Finland. The current work focuses on eventual changes in ash characteristics during co-combustion of RF with coal, wood or bark, which could lead to bed agglomeration, slagging, fouling and even corrosion in the boiler. Ashes were produced in a 15 kW bubbling fluidized bed (BFB) combustion reactor, the fly ash captured by the cyclone was further analyzed by XRF. The sintering tendency behavior of these ashes was investigated using a test procedure developed at Aabo Akademi University. Earlier, a screening program involved ashes from RF (from a waste separation scheme in Finland) co-combustion with peat, wood and bark, in which ash pellets were thermally treated in air. This showed significant sintering below 600 C as well as above 800 C for RF/wood and RF/bark, but not for RF/peat. This seemed to correlate with alkali chloride and sulfate concentrations in the ashes. The current work addresses a Danish refuse-derived fuel (RDF), co-combusted with bark, coal, bark+coal, wood, and wood+coal (eight tests). Ash pellets were thermally treated in nitrogen in order to avoid residual carbon combustion. The results obtained show no sintering tendencies below 600 C, significant changes in sintering are seen with pellets treated at 1,000 C. Ash from 100% RDF combustion does not sinter, 25% RDF co-combustion with wood and peat, respectively, gives an insignificant effect. The most severe sintering occurs during co-combustion of RDF with bark. Furthermore, it appears that the presence of a 25% coal fraction (on energy basis) seems to have a negative effect on all fuel blends. Analysis of the sintering results versus ash chemical composition shows that, in general, an increased level of

  15. Cofiring Wood and Coal to Stoker Boilers in Pittsburgh

    SciTech Connect (OSTI)

    Cobb, J.T., Jr.; Elder, W.W.

    1997-07-01

    The prime objective of the University of Pittsburgh's overall wood/coal cofiring program is the successful introduction of commercial cofiring of urban wood wastes into the stoker boilers of western Pennsylvania. Central to this objective is the demonstration test at the Pittsburgh Brewing Company. In this test the project team is working to show that two commercially-available clean wood wastes - tub-ground pallet waste and chipped clearance wood - can be included in the fuel fed daily to an industrial stoker boiler. Irrespective of its economic outcome, the technical success of the demonstration at the brewery will allow the local air quality regulation agency to permit a parametric test at the Bellefield Boiler Plant. The objective of this test is to obtain comprehensive data on all key parameters of this operational boiler while firing wood with coal. The data would then be used for thorough generic technical and economic analyses. The technical analysis would be added to the open literature for the general planning and operational guidance for boiler owners and operators. The economic analysis would gage the potential for providing this stoker fuel commercially in an urban setting and for purchasing it regularly for combustion in an urban stoker boiler.

  16. Decision-maker's guide to wood fuel for small industrial energy users. Final report. [Includes glossary

    SciTech Connect (OSTI)

    Levi, M. P.; O'Grady, M. J.

    1980-02-01

    The technology and economics of various wood energy systems available to the small industrial and commercial energy user are considered. This book is designed to help a plant manager, engineer, or others in a decision-making role to become more familiar with wood fuel systems and make informed decisions about switching to wood as a fuel. The following subjects are discussed: wood combustion, pelletized wood, fuel storage, fuel handling and preparation, combustion equipment, retrofitting fossil-fueled boilers, cogeneration, pollution abatement, and economic considerations of wood fuel use. (MHR)

  17. Management of high sulfur coal combustion residues, issues and practices: Proceedings

    SciTech Connect (OSTI)

    Chugh, Y.P.; Beasley, G.A.

    1994-10-01

    Papers presented at the following sessions are included in this proceedings: (1) overview topic; (2) characterization of coal combustion residues; (3) environmental impacts of residues management; (4) materials handling and utilization, Part I; and (5) materials handling and utilization, Part II. Selected paper have been processed separately for inclusion in the Energy Science and Technology Database.

  18. Comminution process to produce precision wood particles of uniform size and shape with disrupted grain structure from wood chips

    DOE Patents [OSTI]

    Dooley, James H.; Lanning, David N.

    2015-06-23

    A process of comminution of wood chips (C) having a grain direction to produce a mixture of wood particles (P), wherein the wood chips are characterized by an average length dimension (L.sub.C) as measured substantially parallel to the grain, an average width dimension (W.sub.C) as measured normal to L.sub.C and aligned cross grain, and an average height dimension (H.sub.C) as measured normal to W.sub.C and L.sub.C, wherein W.sub.C>L.sub.C, and wherein the comminution process comprises the step of feeding the wood chips in a direction of travel substantially randomly to the grain direction through a counter rotating pair of intermeshing arrays of cutting discs (D) arrayed axially perpendicular to the direction of wood chip travel, wherein the cutting discs have a uniform thickness (T.sub.D), and wherein at least one of L.sub.C, W.sub.C, and H.sub.C is less than T.sub.D.

  19. Comminution process to produce precision wood particles of uniform size and shape with disrupted grain structure from wood chips

    DOE Patents [OSTI]

    Dooley, James H; Lanning, David N

    2013-08-13

    A process of comminution of wood chips (C) having a grain direction to produce a mixture of wood particles (P), wherein the wood chips are characterized by an average length dimension (L.sub.C) as measured substantially parallel to the grain, an average width dimension (W.sub.C) as measured normal to L.sub.C and aligned cross grain, and an average height dimension (H.sub.C) as measured normal to W.sub.C and L.sub.C, and wherein the comminution process comprises the step of feeding the wood chips in a direction of travel substantially randomly to the grain direction through a counter rotating pair of intermeshing arrays of cutting discs (D) arrayed axially perpendicular to the direction of wood chip travel, wherein the cutting discs have a uniform thickness (T.sub.D), and wherein at least one of L.sub.C, W.sub.C, and H.sub.C is greater than T.sub.D.

  20. Production of ethanol from lignocellulosic materials using thermophilic bacteria

    SciTech Connect (OSTI)

    Lynd, L.R.

    1987-01-01

    The production of ethanol from lignocellulosic materials, e.g. wood, agricultural residues, and municipal solid wastes, is considered. The conversion of these materials to ethanol in the US could annually yield approximately 430 million tons ethanol, or about 9.8 quads, within the next 20 years. Thermophilic bacteria have advantages over yeasts for ethanol production because various species produce an active cellulase enzyme and utilize pentose sugars. However thermophiles have lower ethanol tolerance and usually lower ethanol yields. The potential of thermophilic ethanol production from hardwood chips is examined in detail. It is concluded that if high ethanol yield can be achieved this process could have economics competitive with either ethanol production from corn via yeast or synthetic production from ethylene. Low ethanol tolerance is not a major problem provided concentrations {ge} 1.5% are produced, ethanol is continuously removed from the fermentor, and IHOSR/extractive distillation is employed. Research was undertaken aimed at closing the gap between the attractive potential of thermophiles for ethanol production, and that which is possible based on present knowledge, which is not practical. Major topics were the activity of Clostridium thermocellum cellulase on pretreated mixed hardwood and Avicel in vivo, continuous culture of C. thermocellum on pretreated mixed hardwood and Avicel, and the continuous culture of Clostridium thermosaccharolyticum at high xylose concentrations in the presence and absence of ethanol removal.

  1. Community Based Wood Heat System for Fort Yukon

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Community Based Wood Heat System for Fort Yukon A Systems Integration Bill Wall, PhD Alaska Wood Energy Associates Village Survival Highest Energy Costs in Nation Project Initiation Partners 2005  Council of Athabascan Tribal Government  Alaska Village Initiatives  Original Goal: Displace as much diesel fuel as possible through development of a sustainable community based program  $0.51 per kWh electricity  $6.75 per gallon gasoline  $7.00 per gallon heating fuel  $200 per

  2. Wood energy in Georgia: a five-year progress report

    SciTech Connect (OSTI)

    Not Available

    1982-01-01

    An increasing number of industrial plants and public and residential facilities in Georgia are using wood, Georgia's greatest renewable energy source, to replace gas, oil, coal, and electricity. All wood systems described in this report are or will soon be in operation in schools, prisons, hospitals, and other state facilities, and are producing substantial financial savings. The economic values from increased markets and jobs are important in all areas of the state, with total benefits projected at $2.9 million a year for state taxpayers. 2 figures.

  3. Material Analysis for a Fire Assessment.

    SciTech Connect (OSTI)

    Brown, Alexander; Nemer, Martin

    2014-08-01

    This report consolidates technical information on several materials and material classes for a fire assessment. The materials include three polymeric materials, wood, and hydraulic oil. The polymers are polystyrene, polyurethane, and melamine- formaldehyde foams. Samples of two of the specific materials were tested for their behavior in a fire - like environment. Test data and the methods used to test the materials are presented. Much of the remaining data are taken from a literature survey. This report serves as a reference source of properties necessary to predict the behavior of these materials in a fire.

  4. 01-02-2008 - Wood Cabinet Falls Apart | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8 - Wood Cabinet Falls Apart Document Number: NA Effective Date: 012008 File (public): PDF icon 01-02-2008blue...

  5. Effect of wood chip size on update gasifier-combustor operation

    SciTech Connect (OSTI)

    Payne, F.A.; Dunlap, J.L.; Caussanel, P.

    1984-01-01

    Three wood chip sizes were tested in a 0.3 GJ/h updraft gasifier-combustor. Thermal output did not vary significantly between wood chips. Pressure and temperature profiles were measured in the gasifier bed. Channeling occurred with the small wood chips. Efficiency of the combustor was determined by a mass and energy balance and an enthalpy technique.

  6. Energy generation and cogeneration from wood

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    The papers presented at the conference are included in this volume. Discussions from the four workshops are also provided. The subjects covered in the workshops are: materials handling; combustion technologies - pile, grate, and suspension systems; gasification and pyrolysis systems; and cogeneration. Separate abstracts for each paper have been prepared for inclusion in the Energy Data Base. (DMC)

  7. Wood pellet market and trade: a global perspective

    SciTech Connect (OSTI)

    Chun Sheng Goh; Martin Junginger; Maurizio Cocchi; Didier Marchal; Daniela Thran; Christiane Hennig; Jussi Heinimo; Lars Nikolaisen; Peter-Paul Schouwenberg; Douglas Bradley; J. Richard Hess; Jacob J. Jacobson; Leslie Ovard; Michael Deutmeyer

    2001-01-01

    This perspective provides an overview of wood pellet markets in a number of countries of high significance, together with an inventory of market factors and relevant past or existing policies. In 2010, the estimated global wood pellet production and consumption were close to 14.3 Mt (million metric tonnes) and 13.5 Mt, respectively, while the global installed production capacity had reached over 28 Mt. Two types of pellets are mainly traded (i) for residential heating and (ii) for large-scale district heating or co-fi ring installations. The EU was the primary market, responsible for nearly 61% and 85% of global production and consumption, respectively in 2010. EU markets were divided according to end use: (i) residential and district heating, (ii) power plants driven market, (iii) mixed market, and (iv) export-driven countries. North America basically serves as an exporter, but also with signifi cant domestic consumption in USA. East Asia is predicted to become the second-largest consumer after the EU in the near future. The development perspective in Latin America remains unclear. Five factors that determine the market characteristics are: (i) the existence of coal-based power plants, (ii) the development of heating systems, (iii) feedstock availability, (iv) interactions with wood industry, and (v) logistics factor. Furthermore, intervention policies play a pivotal role in market development. The perspective of wood pellets industry was also analyzed from four major aspects: (i) supply potential, (ii) logistics issues, (iii) sustainability considerations, and (iv) technology development.

  8. Production of chemical feedstock by the methanolysis of wood

    DOE Patents [OSTI]

    Steinberg, Meyer; Fallon, Peter

    1984-07-31

    A process for the production of ethylene, benzene and carbon monoxide from particulated biomass such as wood by reaction with methane at a temperature of from 700.degree. C. to 1200.degree. C., at a pressure of from 20 psi to 100 psi for a period of from 0.2 to 10 seconds.

  9. Production of chemical feedstock by the methanolysis of wood

    DOE Patents [OSTI]

    Steinberg, M.; Fallon, P.

    1983-06-01

    A process is discussed for the production of ethylene, benzene and carbon monoxide from particulated biomass such as wood by reaction with methane at a temperature of from 700/sup 0/C to 1200/sup 0/C, at a pressure of from 20 psi to 100 psi for a period of from 0.2 to 10 seconds.

  10. Measure Guideline. Wood Window Repair, Rehabilitation, and Replacement

    SciTech Connect (OSTI)

    Baker, P.; Eng, P.

    2012-12-01

    This measure guideline provides information and guidance on rehabilitating, retrofitting, and replacing existing window assemblies in residential construction. The intent is to provide information regarding means and methods to improve the energy and comfort performance of existing wood window assemblies in a way that takes into consideration component durability, in-service operation, and long term performance of the strategies.

  11. Interactive Effects of Climate Change and Decomposer Communities on the Stabilization of Wood-Derived Carbon Pools: Catalyst for a New Study

    SciTech Connect (OSTI)

    Resh, Sigrid C.

    2014-11-17

    Globally, forest soils store ~two-thirds as much carbon (C) as the atmosphere. Although wood makes up the majority of forest biomass, the importance of wood contributions to soil C pools is unknown. Even with recent advances in the mechanistic understanding of soil processes, integrative studies tracing C input pathways and biological fluxes within and from soils are lacking. Therefore, our research objectives were to assess the impact of different fungal decay pathways (i.e., white-rot versus brown-rot)—in interaction with wood quality, soil temperature, wood location (i.e., soil surface and buried in mineral soil), and soil texture—on the transformation of woody material into soil CO2 efflux, dissolved organic carbon (DOC), and soil C pools. The use of 13C-depleted woody biomass harvested from the Rhinelander, WI free-air carbon dioxide enrichment (Aspen-FACE) experiment affords the unique opportunity to distinguish the wood-derived C from other soil C fluxes and pools. We established 168 treatment plots across six field sites (three sand and three loam textured soil). Treatment plots consisted of full-factorial design with the following treatments: 1. Wood chips from elevated CO2, elevated CO2 + O3, or ambient atmosphere AspenFACE treatments; 2. Inoculated with white rot (Bjerkandera adusta) or brown rot (Gloeophyllum sepiarium) pure fungal cultures, or the original suite of endemic microbial community on the logs; and 3. Buried (15cm in soil as a proxy for coarse roots) or surface applied wood chips. We also created a warming treatment using open-topped, passive warming chambers on a subset of the above treatments. Control plots with no added wood (“no chip control”) were incorporated into the research design. Soils were sampled for initial δ13C values, CN concentrations, and bulk density. A subset of plots were instrumented with lysimeters for sampling soil water and temperature data loggers for measuring soil temperatures. To determine the early

  12. Steam-explosion pretreatment of wood: effect of chip size, acid, moisture content and pressure drop

    SciTech Connect (OSTI)

    Brownell, H.H.; Yu, E.K.C.; Saddler, J.N.

    1986-06-01

    Material balances for pentosan, lignin, and hexosan, during steam-explosion pretreatment of aspenwood, showed almost quantitative recovery of cellulose in the water-insoluble fraction. Dilute acid impregnation resulted in more selective hydrolysis of pentosan relative to undesirable pyrolysis, and gave a more accessible substrate for enzymatic hydrolysis. Thermocouple probes, located inside simulated aspenwood chips heated in 240 degrees C-saturated steam, showed rapid heating of air-dry wood, whereas green or impregnated wood heated slowly. Small chips, 3.2 mm in the fiber direction, whether green or air dry gave approximately equal rates of pentosan destruction and solubilization, and similar yields of glucose and of total reducing sugars on enzmatic hydrolysis with Trichoderma harzianum. Partial pyrolysis, destroying one-third of the pentosan of aspenwood at atmospheric pressure by dry steam at 276 degrees C, gave little increase in yield of reducing sugars on enzymatic hydrolysis. Treatment with saturated steam at 240 degrees C gave essentially the same yields of butanediol and ethanol on fermentation with Klebsiella pneumoniae, whether or not 80% of the steam was bled off before explosion and even if the chips remained intact, showing that explosion was unnecessary. 17 references.

  13. California: Agricultural Residues Produce Renewable Fuel

    Broader source: Energy.gov [DOE]

    Logos Technologies and EERE are partnering with Edeniq of Visalia to build a plant that will produce cellulosic ethanol from switchgrass, wood chips, and corn leaves, stalks, and husks--all plentiful, nonfood feedstock sources in California.

  14. Alcohol production from agricultural and forestry residues

    SciTech Connect (OSTI)

    Opilla, R.; Dale, L.; Surles, T.

    1980-05-01

    A variety of carbohydrate sources can be used as raw material for the production of ethanol. Section 1 is a review of technologies available for the production of ethanol from whole corn. Particular emphasis is placed on the environmental aspects of the process, including land utilization and possible air and water pollutants. Suggestions are made for technological changes intended to improve the economics of the process as well as to reduce some of the pollution from by-product disposal. Ethanol may be derived from renewable cellulosic substances by either enzymatic or acid hydrolysis of cellulose to sugar, followed by conventional fermentation and distillation. Section 2 is a review of the use of two agricultural residues - corn stover (field stalks remaining after harvest) and straw from wheat crops - as a cellulosic feedstock. Two processes have been evaluated with regard to environmental impact - a two-stage acid process developed by G.T. Tsao of Purdue University and an enzymatic process based on the laboratory findings of C.R. Wilke of the University of California, Berkeley. Section 3 deals with the environmental residuals expected from the manufacture of methyl and ethyl alcohols from woody biomass. The methanol is produced in a gasification process, whereas ethanol is produced by hydrolysis and fermentation processes similar to those used to derive ethanol from cellulosic materials.

  15. Push for new materials, chemicals from biomass sparks active R and D

    SciTech Connect (OSTI)

    Borman, S. )

    1990-09-01

    This paper discusses how a resurgence of interest in the production of new materials, chemicals, and fuels from biomass resources such as wood, cellulose, lignin, starch, and chitin is sparking active R and D efforts in these areas. Biobased materials and chemicals currently under development include composites of conventional plastics with lignocellulosics (chemicals from wood and other plant sources); lignocellulosic nonwoven mates that can be pressed into rigid shapes to form doors, walls, and even auto body parts; phenolic chemicals produced from wood waste and bark; membranes made from chitosan (a substance derived from crustacean shells); and biodegradable plastics containing starch.

  16. URBAN WOOD/COAL CO-FIRING IN THE NIOSH BOILER PLANT

    SciTech Connect (OSTI)

    James T. Cobb Jr.

    2005-02-10

    Phase I of this project began by obtaining R&D variances for permits at the NIOSH boilerplant (NBP), Emery Tree Service (ETS) and the J. A. Rutter Company (JARC) for their portions of the project. Wood for the test burn was obtained from the JARC inventory (pallets), Thompson Properties and Seven D Corporation (construction wood), and the Arlington Heights Housing Project (demolition wood). The wood was ground at ETS and JARC, delivered to the Three Rivers Terminal and blended with coal. Three one-day tests using wood/coal blends of 33% wood by volume (both construction wood and demolition wood) were conducted at the NBP. Blends using hammermilled wood were operationally successful. Emissions of SO{sub 2} and NOx decreased and that of CO increased when compared with combusting coal alone. Mercury emissions were measured and evaluated. During the first year of Phase II the principal work focused upon searching for a replacement boilerplant and developing a commercial supply of demolition wood. The NBP withdrew from the project and a search began for another stoker boilerplant in Pennsylvania to replace it on the project. Three potential commercial demolition wood providers were contacted. Two were not be able to supply wood. At the end of the first year of Phase II, discussions were continuing with the third one, a commercial demolition wood provider from northern New Jersey. During the two-and-a-third years of the contract extension it was determined that the demolition wood from northern New Jersey was impractical for use in Pittsburgh, in another power plant in central New Jersey, and in a new wood gasifier being planned in Philadelphia. However, the project team did identify sufficient wood from other sources for the gasifier project. The Principal Investigator of this project assisted a feasibility study of wood gasification in Clarion County, Pennsylvania. As a result of the study, an independent power producer in the county has initiated a small wood

  17. State-of-the-art report summarizing techniques to determine residual oil saturation and recommendations on the requirements for residual oil saturation research and development

    SciTech Connect (OSTI)

    Chang, M.M.; Maerefat, N.L.

    1986-05-01

    An investigation was conducted on the residual oil saturation (ROS) measurement techniques developed during the last fifteen years. Knowledge of precise ROS measurements is required for EOR project planning. The advantages, limitations, and problems of each one of the techniques are presented in tabulated form. Also, some of the possible improvements in the measurement techniques for the residual oil saturation are summarized. The following residual oil saturation techniques are discussed: core analyses, well logging, backflow tracer tests, material balance and well testing, newly developed gravity log methods, and interwell residual oil saturation measurements. Several aspects left to be improved in both instrumentations and data interpretation on pressure coring, back-flow tracer tests, well logging, material balance calculations, well testing, and interwell ROS measurements are presented. A nuclear magnetism log-inject-log method is proposed in which the need for porosity measurement for determining residual oil saturation is eliminated. 91 refs., 3 tabs.

  18. Residual stresses and stress corrosion cracking in pipe fittings

    SciTech Connect (OSTI)

    Parrington, R.J.; Scott, J.J.; Torres, F.

    1994-06-01

    Residual stresses can play a key role in the SCC performance of susceptible materials in PWR primary water applications. Residual stresses are stresses stored within the metal that develop during deformation and persist in the absence of external forces or temperature gradients. Sources of residual stresses in pipe fittings include fabrication processes, installation and welding. There are a number of methods to characterize the magnitude and orientation of residual stresses. These include numerical analysis, chemical cracking tests, and measurement (e.g., X-ray diffraction, neutron diffraction, strain gage/hole drilling, strain gage/trepanning, strain gage/section and layer removal, and acoustics). This paper presents 400 C steam SCC test results demonstrating that residual stresses in as-fabricated Alloy 600 pipe fittings are sufficient to induce SCC. Residual stresses present in as-fabricated pipe fittings are characterized by chemical cracking tests (stainless steel fittings tested in boiling magnesium chloride solution) and by the sectioning and layer removal (SLR) technique.

  19. Characterization of lignin derived from water-only and dilute acid flowthrough pretreatment of poplar wood at elevated temperatures

    SciTech Connect (OSTI)

    Zhang, Libing; Yan, Lishi; Wang, Zheming; Laskar, Dhrubojyoti D.; Swita, Marie S.; Cort, John R.; Yang, Bin

    2015-12-01

    In this study, flowthrough pretreatment of biomass has high potential to valorize lignin derivatives to high-value products, which is vital to enhance the economy of biorefinery plants. Comprehensive understanding of lignin behaviors and solubilization chemistry in aqueous pretreatment such as water-only and dilute acid flowthrough pretreatment is of fundamental importance to achieve the goal of providing flexible platform for lignin utilization. In this study, the effects of flowthrough pretreatment conditions on lignin separation from poplar wood were reported as well as the characteristics of three sub-sets of lignin produced from the pretreatment, including residual lignin in pretreated solid residues (ReL), recovered insoluble lignin in pretreated liquid (RISL), and recovered soluble lignin in pretreatment liquid (RSL). Both the water-only and 0.05% (w/w) sulfuric acid pretreatments were performed at temperatures from 160 to 270°C on poplar wood in a flowthrough reactor system for 2-10 min. Results showed that water-only flowthrough pretreatment primarily removed syringyl (S units). Increased temperature and/or the addition of sulfuric acid enhanced the removal of guaiacyl (G units) compared to water-only pretreatments at lower temperatures, resulting in nearly complete removal of lignin from the biomass. Results also suggested that more RISL was recovered than ReL and RSL in both dilute acid and water-only flowthrough pretreatment at elevated temperatures. NMR spectra of the RISL revealed significant β-O-4 cleavage, α-β deoxygenation to form cinnamyl-like end groups, and slight β-5 repolymerization in both water-only and dilute acid flowthrough pretreatments. In conclusion, elevated temperature and/or dilute acid greatly enhanced lignin removal to almost 100% by improving G unit removal besides S unit removal in flowthrough system. A new lignin chemistry transformation pathway was proposed and revealed the complexity of lignin structural change during

  20. Characterization of Lignin Derived from Water-only and Dilute Acid Flowthrough Pretreatment of Poplar Wood at Elevated Temperatures

    SciTech Connect (OSTI)

    Zhang, Libing; Yan, Lishi; Wang, Zheming; Laskar, Dhrubojyoti D.; Swita, Marie S.; Cort, John R.; Yang, Bin

    2015-12-01

    Background: Flowthrough pretreatment of biomass has high potential to valorize lignin derivatives to high-value products, which is vital to enhance the economy of biorefinery plants. Comprehensive understanding of lignin behaviors and solubilization chemistry in aqueous pretreatment such as water-only and dilute acid flowthrough pretreatment is of fundamental importance to achieve the goal of providing flexible platform for lignin utilization. Results: In this study, the effects of flowthrough pretreatment conditions on lignin separation from poplar wood were reported as well as the characteristics of three sub-sets of lignin produced from the pretreatment, including residual lignin in pretreated solid residues (ReL), recovered insoluble lignin in pretreated liquid (RISL), and recovered soluble lignin in pretreatment liquid (RSL). Both the water-only and 0.05% (w/w) sulfuric acid pretreatments were performed at temperatures from 160 to 270°C on poplar wood in a flowthrough reactor system for 2-10 min. Results showed that water-only flowthrough pretreatment primarily removed syringyl (S units). Increased temperature and/or the addition of sulfuric acid enhanced the removal of guaiacyl (G units) compared to water-only pretreatments at lower temperatures, resulting in nearly complete removal of lignin from the biomass. Results also suggested that more RISL was recovered than ReL and RSL in both dilute acid and water-only flowthrough pretreatment at elevated temperatures. NMR spectra of the RISL revealed significant β-O-4 cleavage, α-β deoxygenation to form cinnamyl-like end groups, and slight β-5 repolymerization in both water-only and dilute acid flowthrough pretreatments. Conclusions: Elevated temperature and/or dilute acid greatly enhanced lignin removal to almost 100% by improving G unit removal besides S unit removal in flowthrough system. A new lignin chemistry transformation pathway was proposed and revealed the complexity of lignin structural change

  1. Kinetics of fluidized bed combustion of wood pellets

    SciTech Connect (OSTI)

    Leckner, B.; Hansson, K.M.; Tullin, C.; Borodulya, A.V.; Dikalenko, V.I.; Palchonok, G.I.

    1999-07-01

    Devolatilization and char combustion of a single wood pellet in a fluidized bed has been studied. The effect of operation parameters (bed temperature, bed particle size, oxygen concentration) and pellet characteristics has been investigated. A simplified analytical model of heat-transfer controlled pyrolysis has been developed to interpret the measured volatiles release time. The model predictions are in a good agreement with the experimental data, provided that the initial physical properties of the pellet are used. The model can be used to estimate the devolatilization times in other combustion systems. Kinetic parameters of char combustion are obtained, based on the measured burnout times and simple model considerations. The physical properties of wood pellets need further study.

  2. Incorporation of metal nanoparticles into wood substrate and methods

    DOE Patents [OSTI]

    Rector, Kirk D; Lucas, Marcel

    2015-11-04

    Metal nanoparticles were incorporated into wood. Ionic liquids were used to expand the wood cell wall structure for nanoparticle incorporation into the cell wall structure. Nanoparticles of elemental gold or silver were found to be effective surface enhanced Raman spectroscopy (SERS) imaging contrast or sensing agents. Nanoparticles of elemental iron were found to be efficient microwave absorbers and caused localized heating for disrupting the integrity of the lignocellulosic matrix. Controls suggest that the localized heating around the iron nanoparticles reduces losses of cellulose in the form of water, volatiles and CO.sub.2. The ionic liquid is needed during the incorporation process at room temperature. The use of small amounts of ionic liquid combined with the absence of an ionic liquid purification step and a lower energy and water use are expected to reduce costs in an up-scaled pretreatment process.

  3. Assessment of superheated steam drying of wood waste

    SciTech Connect (OSTI)

    Woods, B.G.; Nguyen, Y.; Bruce, S.

    1994-12-31

    A 5 MW co-generation facility using wood waste is described which will supply power to Ontario Hydro, steam to the sawmill for process heating, and hot water for district heating customers in the town. The use of superheated steam for drying the wood was investigated to determine the impact on boiler performance, the environmental impact and the economic feasibility. The main benefit with superheated steam drying is the reduction in VOC emissions. The capital cost is currently higher with superheated steam drying, but further investigation is warranted to determine if the cost reductions which could be achieved by manufacturing the major components in North America are sufficient to make the technology cost competitive.

  4. Quality of Wood Pellets Produced in British Columbia for Export

    SciTech Connect (OSTI)

    J. S. Tumuluru; S. Sokhansanj; C. J. Lim; T. Bi; A. Lau; S. Melin; T. Sowlati; E. Oveisi

    2010-11-01

    Wood pellet production and its use for heat and power production are increasing worldwide. The quality of export pellets has to consistently meet certain specifications as stipulated by the larger buyers, such as power utilities or as specified by the standards used for the non-industrial bag market. No specific data is available regarding the quality of export pellets to Europe. To develop a set of baseline data, wood pellets were sampled at an export terminal in Vancouver, British Columbia, Canada. The sampling period was 18 months in 2007-2008 when pellets were transferred from storage bins to the ocean vessels. The sampling frequency was once every 1.5 to 2 months for a total of 9 loading/shipping events. The physical properties of the wood pellets measured were moisture content in the range of 3.5% to 6.5%, bulk density from 728 to 808 kg/m3, durability from 97% to 99%, fines content from 0.03% to 0.87%, calorific value as is from 17 to almost 18 MJ/kg, and ash content from 0.26% to 0.93%.The diameter and length were in the range of 6.4 to 6.5 mm and 14.0 to 19.0 mm, respectively. All of these values met the published non-industrial European grades (CEN) and the grades specified by the Pellet Fuel Institute for the United States for the bag market. The measured values for wood pellet properties were consistent except the ash content values decreased over the test period.

  5. QUALITY OF WOOD PELLETS PRODUCED IN BRITISH COLUMBIA FOR EXPORT

    SciTech Connect (OSTI)

    Tumuluru, J.S.; Sokhansanj, Shahabaddine; Lim, C. Jim; Bi, X.T.; Lau, A.K.; Melin, Staffan; Oveisi, E.; Sowlati, T.

    2010-11-01

    Wood pellet production and its use for heat and power production are increasing worldwide. The quality of export pellets has to consistently meet certain specifications as stipulated by the larger buyers, such as power utilities or as specified by the standards used for the non-industrial bag market. No specific data is available regarding the quality of export pellets to Europe. To develop a set of baseline data, wood pellets were sampled at an export terminal in Vancouver, British Columbia, Canada. The sampling period was 18 months in 2007-2008 when pellets were transferred from storage bins to the ocean vessels. The sampling frequency was once every 1.5 to 2 months for a total of 9 loading/shipping events. The physical properties of the wood pellets measured were moisture content in the range of 3.5% to 6.5%, bulk density from 728 to 808 kg/m3, durability from 97% to 99%, fines content from 0.03% to 0.87%, calorific value as is from 17 to almost 18 MJ/kg, and ash content from 0.26% to 0.93%.The diameter and length were in the range of 6.4 to 6.5 mm and 14.0 to 19.0 mm, respectively. All of these values met the published non-industrial European grades (CEN) and the grades specified by the Pellet Fuel Institute for the United States for the bag market. The measured values for wood pellet properties were consistent except the ash content values decreased over the test period.

  6. Mechanics of compression drying solid wood cubes and chip mats

    SciTech Connect (OSTI)

    Haygreen, J.G.

    1982-10-01

    Wood cubes and chip mats were compressed in a cell under ram face pressures to 13,000 psi. The amount of water removed was determined for a range of species of various specific gravities and at several green moisture contents (MCs). The time dependence of the process was also studied. The purpose of this work was to describe the mechanics of compression drying which must be considered in designing commercial equipment. Green MC of wood chip mats was reduced to 45 to 50 percent MC (31% to 33% MC, wet basis) at pressures of 13,000 psi. At low pressures of 1,000 to 2,000 psi, moisture was reduced to 60 to 75 percent MC (38% to 43% MC, wet basis). There was a significantly greater moisture reduction at these low pressures if the pressure is maintained for up to 2 minutes rather than releasing it immediately once the target pressure is obtained. Water can be removed from high density species but pressures required are higher by a factor of 2 to 3. The chip mat is reduced to about one-sixth of its original volume at 2,000 psi and one-seventh at 6,000 psi. When pressing cubes of high green MC, about 7,000 foot-pounds of work (equivalent to 9 Btu) applied to the wood will remove up to 1 pound of water. (Refs. 9).

  7. Particulate matter emissions from combustion of wood in district heating applications

    SciTech Connect (OSTI)

    Ghafghazi, S.; Sowlati, T.; Sokhansanj, Shahabaddine; Bi, X.T.; Melin, Staffan

    2011-01-01

    The utilization of wood biomass to generate district heat and power in communities that have access to this energy source is increasing. In this paper the effect of wood fuel properties, combustion condition, and flue gas cleaning system on variation in the amount and formation of particles in the flue gas of typical district heating wood boilers are discussed based on the literature survey. Direct measurements of particulate matter (PM) emissions from wood boilers with district heating applications are reviewed and presented. Finally, recommendations are given regarding the selection of wood fuel, combustion system condition, and flue gas cleaning system in district heating systems in order to meet stringent air quality standards. It is concluded that utilization of high quality wood fuel, such as wood pellets produced from natural, uncontaminated stem wood, would generate the least PM emissions compared to other wood fuel types. Particulate matter emissions from grate burners equipped with electrostatic precipitators when using wood pellets can be well below stringent regulatory emission limit such as particulate emission limit of Metro Vancouver, Canada.

  8. SF 6110-AC Residual Inventory of Material or Equipment Furnished...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Classified Information) (See below) Acquired Quantity Total Value Weight Remarks * NOTE: Description shall include DrawingSpecification No. and whether item is Classified, ...

  9. Superfund Record of Decision amendment (EPA Region 4): Coleman-Evand Wood Preserving Co., Whitehouse, FL, September 25, 1997

    SciTech Connect (OSTI)

    1998-01-01

    This decision document represents an amendment to the selected remedial action for the Coleman-Evans Wood preserving Site (Site) in Whitehouse, Florida. This amendment is necessary because during design of the remedy that was selected in the 1990 Amended Record of Decision, dioxin was discovered at the Site as a new contaminant of concern. This document selects a new interim remedy to address an estimated 45,000 cubic yards of pentachlorophenol (PCP) and dioxin-contaminated source material (i.e., soil, sediment, and debris) and expands the scope of the groundwater remedy to permanently address PCP-, and potentially dioxin-, contaminated groundwater in the upper surficial aquifer.

  10. Superfund Record of Decision (EPA Region 6): Mid-South Wood Products, Polk County, Arkansas, November 1986. First remedial action. Final report

    SciTech Connect (OSTI)

    Not Available

    1986-11-14

    The Mid-South Wood Products site is located in Polk County, Arkansas, approximately 1/2 mile southwest of Mena, Arkansas. The 57-acre site includes the following areas: the Old Plant site, the Small Old Pond and Old Pond areas, the North and South Landfarms, the landfill, Clear Lake and an existing chromated copper arsenate (CCA) treatment plant. The Old Plant site was used to treat wood with pentachlorophenol (PCP) and creosote; the Small Old Pond was the original impoundment for waste PCP and creosote. These two areas have been covered with soil. The Old Pond area was used to store PCP and creosote sludge and has since been graded and covered with soil; materials from the Old Pond were spread over the Landfarm areas and mixed into the soil; the Landfill area contains deposits of sawdust, woodchips, and other waste-wood products; Clear Lake receives runoff from all the above areas; the CCA treatment plant contains an ongoing wood-treating operation where the surface drainage from the plant is put in sumps.

  11. Modeling of residual stresses by HY-100 weldments

    SciTech Connect (OSTI)

    Zacharia, T.; Taljat, B.; Radhakrishnan, B.

    1997-02-01

    Residual stress distribution in a HY-100 steel disk, induced by GTA spot welding, was analyzed by finite element (FE) formulations and measured by neutron diffraction (ND). Computations used temperature- dependent thermophysical and mechanical properties. FE model predictions are in good agreement with ND data in far heat affected zone (HAZ) and in base metal. Predicted residual stresses in fusion zone and near HAZ were higher than those measured by ND. This discrepancy was attributed to microstructural changes and associated material properties in the HAZ and fusion zone due to phase transformations during the weld thermal cycle.

  12. Alcohol production from agricultural and forestry residues

    SciTech Connect (OSTI)

    Dale, L; Opilla, R; Surles, T

    1980-09-01

    Technologies available for the production of ethanol from whole corn are reviewed. Particular emphasis is placed on the environmental aspects of the process, including land utilization and possible air and water pollutants. Suggestions are made for technological changes intended to improve the economics of the process as well as to reduce some of the pollution from by-product disposal. Ethanol may be derived from renewable cellulosic substances by either enzymatic or acid hydrolysis of cellulose to sugar, followed by conventional fermentation and distillation. The use of two agricultural residues - corn stover (field stalks remaining after harvest) and straw from wheat crops - is reviewed as a cellulosic feedstock. Two processes have been evaluated with regard to environmental impact - a two-stage acid process developed by G.T. Tsao of Purdue University and an enzymatic process based on the laboratory findings of C.R. Wilke of the University of California, Berkeley. The environmental residuals expected from the manufacture of methyl and ethyl alcohols from woody biomass are covered. The methanol is produced in a gasification process, whereas ethanol is produced by hydrolysis and fermentation processes similar to those used to derive ethanol from cellulosic materials.

  13. Pyrolysis of Woody Residue Feedstocks: Upgrading of Bio-Oils from Mountain-Pine-Beetle-Killed Trees and Hog Fuel

    SciTech Connect (OSTI)

    Zacher, Alan H.; Elliott, Douglas C.; Olarte, Mariefel V.; Santosa, Daniel M.; Preto, Fernando; Iisa, Kristiina

    2014-12-01

    Liquid transportation fuel blend-stocks were produced by pyrolysis and catalytic upgrading of woody residue biomass. Mountain pine beetle killed wood and hog fuel from a saw mill were pyrolyzed in a 1 kg/h fluidized bed reactor and subsequently upgraded to hydrocarbons in a continuous fixed bed hydrotreater. Upgrading was performed by catalytic hydrotreatment in a two-stage bed at 170°C and 405°C with a per bed LHSV between 0.17 and 0.19. The overall yields from biomass to upgraded fuel were similar for both feeds: 24-25% despite the differences in bio-oil (intermediate) mass yield. Pyrolysis bio-oil mass yield was 61% from MPBK wood, and subsequent upgrading of the bio-oil gave an average mass yield of 41% to liquid fuel blend stocks. Hydrogen was consumed at an average of 0.042g/g of bio-oil fed, with final oxygen content in the product fuel ranging from 0.31% to 1.58% over the course of the test. Comparatively for hog fuel, pyrolysis bio-oil mass yield was lower at 54% due to inorganics in the biomass, but subsequent upgrading of that bio-oil had an average mass yield of 45% to liquid fuel, resulting in a similar final mass yield to fuel compared to the cleaner MPBK wood. Hydrogen consumption for the hog fuel upgrading averaged 0.041 g/g of bio-oil fed, and the final oxygen content of the product fuel ranged from 0.09% to 2.4% over the run. While it was confirmed that inorganic laded biomass yields less bio-oil, this work demonstrated that the resultant bio-oil can be upgraded to hydrocarbons at a higher yield than bio-oil from clean wood. Thus the final hydrocarbon yield from clean or residue biomass pyrolysis/upgrading was similar.

  14. Method for predicting dry mechanical properties from wet wood and standing trees

    DOE Patents [OSTI]

    Meglen, Robert R.; Kelley, Stephen S.

    2003-08-12

    A method for determining the dry mechanical strength for a green wood comprising: illuminating a surface of the wood to be determined with light between 350-2,500 nm, the wood having a green moisture content; analyzing the surface using a spectrometric method, the method generating a first spectral data, and using a multivariate analysis to predict the dry mechanical strength of green wood when dry by comparing the first spectral data with a calibration model, the calibration model comprising a second spectrometric method of spectral data obtained from a reference wood having a green moisture content, the second spectral data correlated with a known mechanical strength analytical result obtained from a reference wood when dried and having a dry moisture content.

  15. Wood-fuel use in Papua New Guinea: an assessment of industrial combustion equipment

    SciTech Connect (OSTI)

    Mendis, M.S.

    1980-11-01

    This report presents the results of an engineering and economic assessment of new and retrofit industrial combustion equipment for wood-fuel use in Papua New Guinea. Existing industrial combustion equipment and practices in Papua New Guinea are appraised. Potential industrial wood-fuel systems that utilize wood, wood wastes, charcoal and pyrolytic oils and which are particularly applicable to Papua New Guinea are identified. An economic assessment of wood-fuel systems is conducted for eleven case studies which are representative of a cross-section of Papua New Guinea industry. Conclusions and recommendations are presented to aid both government and industry in Papua New Guinea in fostering the development of appropriate wood-fuel technologies and thereby help displace the consumption of imported petroleum.

  16. Residual strain mapping of Roman styli from Iulia Concordia, Italy

    SciTech Connect (OSTI)

    Salvemini, Filomena; Grazzi, Francesco; Angelini, Ivana; Davydov, Vadim; Vontobel, Peter; Vigoni, Alberto; Artioli, Gilberto; Zoppi, Marco

    2014-05-01

    Iulia Concordia is an important Roman settlement known for the production of iron objects and weapons during the Roman Empire. A huge number of well-preserved styli were found in the past century in the bed of an old channel. In order to shed light about the production processes used by Roman for stylus manufacturing, a neutron diffraction residual strain analysis was performed on the POLDI materials science diffractometer at the Paul Scherrer Institut in Switzerland. Here, we present results from our investigation conducted on 11 samples, allowing to define, in a non-invasive way, the residual strain map related to the ancient Roman working techniques. - Highlights: • We examined 11 Roman styli from the settlement of Iulia Concordia, Italy. • We performed a neutron diffraction residual strain analysis on POLDI at PSI (CH). • We identified the production processes used by Roman for stylus manufacturing. • We clarified the way and direction of working applied for different classes of styli.

  17. Vitrification of NAC process residue

    SciTech Connect (OSTI)

    Merrill, R.A.; Whittington, K.F.; Peters, R.D. [Pacific Northwest Lab., Richland, WA (United States)

    1995-12-31

    Vitrification tests have been performed with simulated waste compositions formulated to represent the residue which would be obtained from the treatment of low-level, nitrate wastes from Hanford and Oak Ridge by the nitrate to ammonia and ceramic (NAC) process. The tests were designed to demonstrate the feasibility of vitrifying NAC residue and to quantify the impact of the NAC process on the volume of vitrified waste. The residue from NAC treatment of low-level nitrate wastes consists primarily of oxides of aluminum and sodium. High alumina glasses were formulated to maximize the waste loading of the NAC product. Transparent glasses with up to 35 wt% alumina, and even higher contents in opaque glasses, were obtained at melting temperatures of 1,200 C to 1,400 C. A modified TCLP leach test showed the high alumina glasses to have good chemical durability, leaching significantly less than either the ARM-1 or the DWPF-EA high-level waste reference glasses. A significant increase in the final waste volume would be a major result of the NAC process on LLW vitrification. For Hanford wastes, NAC-treatment of nitrate wastes followed by vitrification of the residue will increase the final volume of vitrified waste by 50% to 90%; for Melton Valley waste from Oak Ridge, the increase in final glass volume will be 260% to 280%. The increase in volume is relative to direct vitrification of the waste in a 20 wt% Na{sub 2}O glass formulation. The increase in waste volume directly affects not only disposal costs, but also operating and/or capital costs. Larger plant size, longer operating time, and additional energy and additive costs are direct results of increases in waste volume. Such increases may be balanced by beneficial impacts on the vitrification process; however, those effects are outside the scope of this report.

  18. Vitrification of NAC process residue

    SciTech Connect (OSTI)

    Merrill, R.A.; Whittington, K.F.; Peters, R.D.

    1995-09-01

    Vitrification tests have been performed with simulated waste compositions formulated to represent the residue which would be obtained from the treatment of low-level, nitrate wastes from Hanford and Oak Ridge by the nitrate to ammonia and ceramic (NAC) process. The tests were designed to demonstrate the feasibility of vitrifying NAC residue and to quantify the impact of the NAC process on the volume of vitrified waste. The residue from NAC treatment of low-level nitrate wastes consists primarily of oxides of aluminum and sodium. High alumina glasses were formulated to maximize the waste loading of the NAC product. Transparent glasses with up to 35 wt% alumina, and even higher contents in opaque glasses, were obtained at melting temperatures of 1200{degrees}C to 1400{degrees}C. A modified TCLP leach test showed the high alumina glasses to have good chemical durability, leaching significantly less than either the ARM-1 or the DWPF-EA high-level waste reference glasses. A significant increase in the final waste volume would be a major result of the NAC process on LLW vitrification. For Hanford wastes, NAC-treatment of nitrate wastes followed by vitrification of the residue will increase the final volume of vitrified waste by 50% to 90%; for Melton Valley waste from Oak Ridge, the increase in final glass volume will be 260% to 280%. The increase in volume is relative to direct vitrification of the waste in a 20 wt% Na{sub 2}O glass formulation. The increase in waste volume directly affects not only disposal costs, but also operating and/or capital costs. Larger plant size, longer operating time, and additional energy and additive costs are direct results of increases in waste volume. Such increases may be balanced by beneficial impacts on the vitrification process; however, those effects are outside the scope of this report.

  19. Genomics of wood-degrading fungi (Journal Article) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Details In-Document Search This content will become publicly available on November 1, 2015 Title: Genomics of wood-degrading fungi Authors: Ohm, Robin A. ; Riley, Robert ;...

  20. Water Sampling At Hot Lake Area (Wood, 2002) | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water Sampling At Hot Lake Area (Wood, 2002) Exploration Activity Details Location Hot Lake...

  1. Water Sampling At Belknap-Foley-Bigelow Hot Springs Area (Wood...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water Sampling At Belknap-Foley-Bigelow Hot Springs Area (Wood, 2002) Exploration Activity...

  2. Particulate emissions from residential wood combustion: Final report: Norteast regional Biomass Program

    SciTech Connect (OSTI)

    Not Available

    1987-01-01

    The objective of this study was to provide a resource document for the Northeastern states when pursuing the analysis of localized problems resulting from residential wood combustion. Specific tasks performed include assigning emission rates for total suspended particulates (TSP) and benzo(a)pyrene (BaP) from wood burning stoves, estimating the impact on ambient air quality from residential wood combustion and elucidating the policy options available to Northeastern states in their effort to limit any detrimental effects resulting from residential wood combustion. Ancillary tasks included providing a comprehensive review on the relevant health effects, indoor air pollution and toxic air pollutant studies. 77 refs., 11 figs., 25 tabs.

  3. Hanford tank residual waste contaminant source terms and release models

    SciTech Connect (OSTI)

    Deutsch, William J.; Cantrell, Kirk J.; Krupka, Kenneth M.; Lindberg, Michael J.; Serne, R. Jeffrey

    2011-08-23

    Residual waste is expected to be left in 177 underground storage tanks after closure at the U.S. Department of Energys Hanford Site in Washington State (USA). In the long term, the residual wastes represent a potential source of contamination to the subsurface environment. Residual materials that cannot be completely removed during the tank closure process are being studied to identify and characterize the solid phases and estimate the release of contaminants from these solids to water that might enter the closed tanks in the future. As of the end of 2009, residual waste from five tanks has been evaluated. Residual wastes from adjacent tanks C-202 and C-203 have high U concentrations of 24 and 59 wt%, respectively, while residual wastes from nearby tanks C-103 and C-106 have low U concentrations of 0.4 and 0.03 wt%, respectively. Aluminum concentrations are high (8.2 to 29.1 wt%) in some tanks (C-103, C-106, and S-112) and relatively low (<1.5 wt%) in other tanks (C-202 and C-203). Gibbsite is a common mineral in tanks with high Al concentrations, while non-crystalline U-Na-C-O-PH phases are common in the U-rich residual wastes from tanks C-202 and C-203. Iron oxides/hydroxides have been identified in all residual waste samples studied to date. Contaminant release from the residual wastes was studied by conducting batch leach tests using distilled deionized water, a Ca(OH)2-saturated solution, or a CaCO3-saturated water. Uranium release concentrations are highly dependent on waste and leachant compositions with dissolved U concentrations one or two orders of magnitude higher in the tests with high U residual wastes, and also higher when leached with the CaCO3-saturated solution than with the Ca(OH)2-saturated solution. Technetium leachability is not as strongly dependent on the concentration of Tc in the waste, and it appears to be slightly more leachable by the Ca(OH)2-saturated solution than by the CaCO3-saturated solution. In general, Tc is much less leachable

  4. Method of the cementing of material

    SciTech Connect (OSTI)

    Konovalov, Y.G.; Shutov, G.M.; Khanenya, G.P.; Dyatko, E.K.; Buben, K.K.

    1990-10-30

    Invention relates to woodworking industry and concerns method of cementing of materials of foam plastic with duralumin, glued plywood, etc. Known methods of cementing of materials by effect of electromagnetic field of superhigh frequencies are unproductive and do not make it possible to cement parts on the plane. Target of invention - acceleration of process of cementing of planar, including of complex configuration, parts and assemblies from wood, foam plastic, duralumin, glued plywood and other materials. For this material is cemented under the effect of directed electromagnetic field of superhigh frequency in the range 01-50 GHz, the specific power of 0.5-15 W/cm3.

  5. Measuring depth profiles of residual stress with Raman spectroscopy

    SciTech Connect (OSTI)

    Enloe, W.S.; Sparks, R.G.; Paesler, M.A.

    1988-12-01

    Knowledge of the variation of residual stress is a very important factor in understanding the properties of machined surfaces. The nature of the residual stress can determine a part`s susceptibility to wear deformation, and cracking. Raman spectroscopy is known to be a very useful technique for measuring residual stress in many materials. These measurements are routinely made with a lateral resolution of 1{mu}m and an accuracy of 0.1 kbar. The variation of stress with depth; however, has not received much attention in the past. A novel technique has been developed that allows quantitative measurement of the variation of the residual stress with depth with an accuracy of 10nm in the z direction. Qualitative techniques for determining whether the stress is varying with depth are presented. It is also demonstrated that when the stress is changing over the volume sampled, errors can be introduced if the variation of the stress with depth is ignored. Computer aided data analysis is used to determine the depth dependence of the residual stress.

  6. The Honorable John T. 'Gregorio 301 N. Wood Avenue

    Office of Legacy Management (LM)

    Eiergy ; Washington, DC 20585 -, (, > - .' c ' . FEB 1 7 1995 _ .; , _-, The Honorable John T. 'Gregorio 301 N. Wood Avenue Linden, 'New Jersey 07036 d. \ Dear Mayor Gregorio: ,' ,' .' , Secretary of Energy Hazel O'Leary has announced a new approach to openness, in the'llepartment' of Energy (DDE) and its co,annunications with the .public.', In sup~port of this initiative, we are.pleased to forward.the,enclosed information reiated to the.former Linden Pilot Plant of the Chemical' Construction

  7. Environmental characterization studies of a high-throughput wood gasifier

    SciTech Connect (OSTI)

    Chang, H.; Niemann, R.C.; Wilzbach, K.E.; Paisley, M.

    1983-01-01

    Potential environmental effects associated with thermochemical biomass gasification have been studied by Argonne National Laboratory in cooperation with Battelle Columbus Laboratories (BCL). A series of samples from the process research unit of an indirectly heated, high-throughput wood gasifier operated by BCL has been analyzed for potentially toxic organic compounds and trace elements. The results indicate that, under the test-run conditions, the gasification of both pine and hardwood is accompanied by the formation of some oil, the heavier fraction of which gives a positive response in the Ames assay for mutagenicity and contains numerous phenols and polycyclic aromatic hydrocarbons, including some carcinogens. The implications of these observations are discussed.

  8. Residual stresses in weld overlay tubes: A finite element study

    SciTech Connect (OSTI)

    Taljat, B.; Zacharia, T.; Wang, X.L.; Keiser, J.R.; Feng, Z.; Jirinec, M.J.

    1997-01-03

    Residual stresses and strains in a tube with circumferential weld overlay were analyzed by the finite element (FE) method. The objective of this work was to develop and verify a FE model, to determine the magnitude and distribution of residual stresses in the weld overlay tube, and to evaluate the significance of two contributing factors to residual stress: (1) difference in material properties between tube and weld material, and (2) thermal gradients in the weld. An axisymmetric FE model was developed to simulate the circumferential two-layer welding process of alloy 625 overlay on SA210 tube. The first layer was modeled as a gas metal arc welding process with filler metal, whereas the autogenous gas tungsten arc welding process was modeled for the second layer. Neutron diffraction technique was used to experimentally determine residual elastic strains in the weld overlay tube. Comparison with the FE results shows overall good agreement. Both the experimental and FE results show high compressive stresses at the inside tube surface and high tensile stresses in the weld overlay. This suggests that weld overlay may be used to relieve tensile or produce compressive stresses at the inside tube surface, which is significant for applications where crack initiation is found at the root pass of the joining weld.

  9. Nuclear materials management overview

    SciTech Connect (OSTI)

    DiGiallonardo, D.A. )

    1988-01-01

    The true goal of Nuclear Materials MANAGEMENT (NMM) is the strategical and economical management of all nuclear materials. Nuclear Materials Management's role involves near-term and long-term planning, reporting, forecasting, and reviewing of inventories. This function is administrative in nature. it is a growing area in need of future definition, direction, and development. Improvements are required in program structure, the way residues and wastes are determined, how ''what is and what if'' questions are handled, and in overall decision-making methods.

  10. Nuclear materials management overview

    SciTech Connect (OSTI)

    DiGiallonardo, D.A.

    1988-01-01

    The true goal of Nuclear Materials Management (NMM) is the strategical and economical management of all nuclear materials. Nuclear Materials Management's role involves near-term and long-term planning, reporting, forecasting, and reviewing of inventories. This function is administrative in nature. It is a growing area in need of future definition, direction, and development. Improvements are required in program structure, the way residues and wastes are determined, how /open quotes/What is and what if/close quotes/ questions are handled, and in overall decision-making methods. 2 refs.

  11. Viscosity stabilization of SRC residual oil. Final technical report

    SciTech Connect (OSTI)

    Tewari, K.C.

    1984-05-01

    The use of SRC residual oils for No. 6 Fuel Oil substitutes has been proposed. The oils exhibit viscosity characteristics at elevated temperatures that allow this substitution with only minor modifications to the existing fuel oil infrastructure. However, loss of low-boiling materials causes an increase in the viscosity of the residual oils that is greater than expected from concentration changes. A process has been developed that minimizes the loss of volatiles and thus maintains the viscosity of these materials. The use of an additive (water, phenol, or an SRC light oil cut rich in low-boiling phenols in amounts up to 2.0 wt %) accomplishes this and hence stabilizes the pumping and atomizing characteristics for an extended period. During the course of the work, the components of the volatiles lost were identified and the viscosity change due to this loss was quantified. 3 references, 6 figures, 9 tables.

  12. weapons material | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    material

  13. THE ROLE OF DEAD WOOD IN MAINTAINING ARTHROPOD DIVERSITY ON THE FOREST FLOOR.

    SciTech Connect (OSTI)

    Hanula, James L.; Horn, Scott; Wade, Dale D.

    2006-08-01

    AbstractDead wood is a major component of forests and contributes to overall diversity, primarily by supporting insects that feed directly on or in it. Further, a variety of organisms benefit by feeding on those insects. What is not well known is how or whether dead wood influences the composition of the arthropod community that is not solely dependent on it as a food resource, or whether woody debris influences prey available to generalist predators. One group likely to be affected by dead wood is ground-dwelling arthropods. We studied the effect of adding large dead wood to unburned and frequently burned pine stands to determine if dead wood was used more when the litter and understory plant community are removed. We also studied the effect of annual removal of dead wood from large (10-ha) plots over a 5-year period on ground-dwelling arthropods. In related studies, we examined the relationships among an endangered woodpecker that forages for prey on live trees, its prey, and dead wood in the forest. The results of these and other studies show that dead wood can influence the abundance and diversity of the ground-dwelling arthropod community and of prey available to generalist predators not foraging directly on dead trees.

  14. Relationships between dead wood and arthropods in the Southeastern United States.

    SciTech Connect (OSTI)

    Ulyshen, Michael, Darragh

    2009-05-01

    The importance of dead wood to maintaining forest diversity is now widely recognized. However, the habitat associations and sensitivities of many species associated with dead wood remain unknown, making it difficult to develop conservation plans for managed forests. The purpose of this research, conducted on the upper coastal plain of South Carolina, was to better understand the relationships between dead wood and arthropods in the southeastern United States. In a comparison of forest types, more beetle species emerged from logs collected in upland pine-dominated stands than in bottomland hardwood forests. This difference was most pronounced for Quercus nigra L., a species of tree uncommon in upland forests. In a comparison of wood postures, more beetle species emerged from logs than from snags, but a number of species appear to be dependent on snags including several canopy specialists. In a study of saproxylic beetle succession, species richness peaked within the first year of death and declined steadily thereafter. However, a number of species appear to be dependent on highly decayed logs, underscoring the importance of protecting wood at all stages of decay. In a study comparing litter-dwelling arthropod abundance at different distances from dead wood, arthropods were more abundant near dead wood than away from it. In another study, grounddwelling arthropods and saproxylic beetles were little affected by large-scale manipulations of dead wood in upland pine-dominated forests, possibly due to the suitability of the forests surrounding the plots.

  15. Demonstration of wood/coal co-firing in a spreader stoker

    SciTech Connect (OSTI)

    Cobb, J.T. Jr.; Elder, W.W.; Geiger, G.E.; Campus, N.J.; Miller, W.F.; Freeman, M.C.; McCreery, L.R.

    1999-07-01

    The Forest Service of the U.S. Department of Agriculture is sponsoring a series of demonstrations of wood/coal co-firing in stoker boilers. The first demonstration was conducted in 1997 in an industrial traveling-grate stoker boiler and the second in May 1999 in a spreader stoker boiler operated by the National Institute of Occupational Safety and Health (NIOSH) at the Bruceton Research Laboratory. The principal wood used in both demonstrations was tub-ground broken pallets. In the first phase of the NIOSH demonstration, four five-ton loads of wood/coal mixtures, varying from 3% to 12% wood (by Btu content), were combusted. The second phase of this demonstration was a 50-hour test using a 10% wood/coal blend delivered in two 20-ton loads. It has been concluded from both demonstrations that (1) a 10% wood/coal blend burns acceptably in the boiler, but (2) tub-ground urban wood is unacceptably difficult to feed through the grill above the delivery pit and through the spreader stokers. A method is being sought to acquire urban waste wood, having a more chip-like nature, to use in further testing and for commercialization.

  16. All auto shredding: evaluation of automotive shredder residue generated by shredding only vehicles.

    SciTech Connect (OSTI)

    Duranceau, C. M.; Spangenberger, J. S.

    2011-09-26

    A well developed infrastructure exists for the reuse and recycling of automotive parts and materials. At the end of a vehicle's useful life many parts are removed and sold for reuse and fluids are recovered for recycling or proper disposal. What remains is shredded, along with other metal bearing scrap such as home appliances, demolition debris and process equipment, and the metals are separated out and recycled. The remainder of the vehicle materials is call shredder residue which ends up in the landfill. As energy and natural resources becomes more treasured, increased effort has been afforded to find ways to reduce energy consumption and minimize the use of our limited resources. Many of the materials found in shredder residue could be recovered and help offset the use of energy and material consumption. For example, the energy content of the plastics and rubbers currently landfilled with the shredder residue is equivalent to 16 million barrels of oil per year. However, in the United States, the recovered materials, primarily polymers, cannot be recycled due to current regulatory barriers which preclude the re-introduction into commerce of certain materials because of residual contamination with substances of concern (SOCs) such as polychlorinated biphenyls (PCBs). The source of the PCBs is not well understood. Old transformers, capacitors, white goods and ballasts from lighting fixtures are likely contributing factors. The project was designed to evaluate whether vehicles of varying age and manufacturing origin contribute to the PCB content in shredder residue. Additionally, the project was designed to determine if there are any trends in material composition of the shredder residue from varied age and manufacturing groups. This information would aid in future material recovery facility strategy and design. The test utilized a newly installed shredder plant to shred four categories of automobiles. The categories were defined by vehicle age and the manufacturing

  17. Development of palm oil-based UV-curable epoxy acrylate and urethane acrylate resins for wood coating application

    SciTech Connect (OSTI)

    Tajau, Rida; Mahmood, Mohd Hilmi; Salleh, Mek Zah; Salleh, Nik Ghazali Nik; Ibrahim, Mohammad Izzat; Yunus, Nurulhuda Mohd

    2014-02-12

    The trend of using renewable sources such as palm oil as raw material in radiation curing is growing due to the demand from the market to produce a more environmental friendly product. In this study, the radiation curable process was done using epoxy acrylate and urethane acrylate resins which are known as epoxidised palm olein acrylate (EPOLA) and palm oil based urethane acrylate (POBUA), respectively. The purpose of the study was to investigate curing properties and the application of this UV-curable palm oil resins for wood coating. Furthermore, the properties of palm oil based coatings are compared with the petrochemical-based compound such as ebecryl (EB) i.e. EB264 and EB830. From the experiment done, the resins from petrochemical-based compounds resulted higher degree of crosslinking (up to 80%) than the palm oil based compounds (up to 70%), where the different is around 10-15%. The hardness property from this two type coatings can reached until 50% at the lower percentage of the oligomer. However, the coatings from petrochemical-based have a high scratch resistance as it can withstand at least up to 3.0 Newtons (N) compared to the palm oil-based compounds which are difficult to withstand the load up to 1.0 N. Finally, the test on the rubber wood substrate showed that the coatings containing benzophenone photoinitiator give higher adhesion property and their also showed a higher glosiness property on the glass substrate compared to the coatings containing irgacure-819 photoinitiator. This study showed that the palm oil coatings can be a suitable for the replacement of petrochemicals compound for wood coating. The palm oil coatings can be more competitive in the market if the problems of using high percentage palm oil oligomer can be overcome as the palm oil price is cheap enough.

  18. Trace element partitioning in ashes from boilers firing pure wood or mixtures of solid waste with respect to fuel composition, chlorine content and temperature

    SciTech Connect (OSTI)

    Saqib, Naeem Bäckström, Mattias

    2014-12-15

    Highlights: • Different solids waste incineration is discussed in grate fired and fluidized bed boilers. • We explained waste composition, temperature and chlorine effects on metal partitioning. • Excessive chlorine content can change oxide to chloride equilibrium partitioning the trace elements in fly ash. • Volatility increases with temperature due to increase in vapor pressure of metals and compounds. • In Fluidized bed boiler, most metals find themselves in fly ash, especially for wood incineration. - Abstract: Trace element partitioning in solid waste (household waste, industrial waste, waste wood chips and waste mixtures) incineration residues was investigated. Samples of fly ash and bottom ash were collected from six incineration facilities across Sweden including two grate fired and four fluidized bed incinerators, to have a variation in the input fuel composition (from pure biofuel to mixture of waste) and different temperature boiler conditions. As trace element concentrations in the input waste at the same facilities have already been analyzed, the present study focuses on the concentration of trace elements in the waste fuel, their distribution in the incineration residues with respect to chlorine content of waste and combustion temperature. Results indicate that Zn, Cu and Pb are dominating trace elements in the waste fuel. Highly volatile elements mercury and cadmium are mainly found in fly ash in all cases; 2/3 of lead also end up in fly ash while Zn, As and Sb show a large variation in distribution with most of them residing in the fly ash. Lithophilic elements such as copper and chromium are mainly found in bottom ash from grate fired facilities while partition mostly into fly ash from fluidized bed incinerators, especially for plants fuelled by waste wood or ordinary wood chips. There is no specific correlation between input concentration of an element in the waste fuel and fraction partitioned to fly ash. Temperature and chlorine

  19. BT16 Agricultural Residues and Biomass Energy Crops Factsheet

    Broader source: Energy.gov (indexed) [DOE]

    ... forests, municipal solid wastes, urban wood waste, and algae, the report includes an evaluation of biomass supply potentially available through production on agricultural land. ...

  20. Resource recovery from coal residues

    SciTech Connect (OSTI)

    Jones, G. Jr.; Canon, R.M.

    1980-01-01

    Several processes are being developed to recover metals from coal combustion and conversion residues. Methods to obtain substantial amounts of aluminum, iron, and titanium from these wastes are presented. The primary purpose of our investigation is to find a process that is economically sound or one that at least will partially defray the costs of waste processing. A cursory look at the content of fly ash enables one to see the merits of recovery of these huge quantities of valuable resources. The major constituents of fly ash of most interest are aluminum (14.8%), iron (7.5%), and titanium (1.0%). If these major elements could be recovered from the fly ash produced in the United States (60 million tons/year), bauxite would not have to be imported, iron ore production could be increased, and titanium production could be doubled.

  1. Ecological objectives can be achieved with wood-derived bioenergy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dale, Virginia H.; Kline, Keith L.; Marland, Gregg; Miner, Reid A.

    2015-08-01

    Renewable, biomass-based energy options can reduce the climate impacts of fossil fuels. However, calculating the effects of wood-derived bioenergy on greenhouse gases (GHGs), and thus on climate, is complicated (Miner et al. 2015). To clarify concerns and options about bioenergy, in November 2014, the US Environmental Protection Agency (EPA) produced a second draft of its Framework for Assessing Biogenic CO2 Emissions fromStationary Sources (http://1.usa.gov/1dikgHq), which considers the latest scientific information and input from stakeholders. Furthermore, the EPA is expected to make decisions soon about the use of woody biomass under the Clean Power Plan, which sets targets for carbon pollutionmore » from power plants.« less

  2. Ecological objectives can be achieved with wood-derived bioenergy

    SciTech Connect (OSTI)

    Dale, Virginia H.; Kline, Keith L.; Marland, Gregg; Miner, Reid A.

    2015-08-01

    Renewable, biomass-based energy options can reduce the climate impacts of fossil fuels. However, calculating the effects of wood-derived bioenergy on greenhouse gases (GHGs), and thus on climate, is complicated (Miner et al. 2015). To clarify concerns and options about bioenergy, in November 2014, the US Environmental Protection Agency (EPA) produced a second draft of its Framework for Assessing Biogenic CO2 Emissions fromStationary Sources (http://1.usa.gov/1dikgHq), which considers the latest scientific information and input from stakeholders. Furthermore, the EPA is expected to make decisions soon about the use of woody biomass under the Clean Power Plan, which sets targets for carbon pollution from power plants.

  3. Ecological objectives can be achieved with wood-derived bioenergy

    SciTech Connect (OSTI)

    Dale, Virginia H.; Kline, Keith L.; Marland, Gregg; Miner, Reid A.

    2015-08-01

    Renewable, biomass-based energy options can reduce the climate impacts of fossil fuels. However, calculating the effects of wood-derived bioenergy on greenhouse gases (GHGs), and thus on climate, is complicated (Miner et al. 2015). To clarify concerns and options about bioenergy, in November 2014, the US Environmental Protection Agency (EPA) produced a second draft of its Framework for Assessing Biogenic CO2 Emissions fromStationary Sources (http://1.usa.gov/1dikgHq), which considers the latest scientific information and input from stakeholders. In addition, the EPA is expected to make decisions soon about the use of woody biomass under the Clean Power Plan, which sets targets for carbon pollution from power plants.

  4. Forest and wood products role in carbon sequestration

    SciTech Connect (OSTI)

    Sampson, R.N.

    1997-12-31

    An evaluation of the use of U.S. forests and forest products for carbon emission mitigation is presented. The current role of forests in carbon sequestration is described in terms of regional differences and forest management techniques. The potential for increasing carbon storage by converting marginal crop and pasture land, increasing timberland growth, reducing wildfire losses, and changing timber harvest methods is examined. Post-harvest carbon flows, environmental impacts of wood products, biomass energy crops, and increased use of energy-conserving trees are reviewed for their potential in reducing or offsetting carbon emissions. It is estimated that these techniques could offset 20 to 40 percent of the carbon emitted annually in the U.S. 39 refs., 5 tabs.

  5. Urban Wood-Based Bio-Energy Systems in Seattle

    SciTech Connect (OSTI)

    Stan Gent, Seattle Steam Company

    2010-10-25

    Seattle Steam Company provides thermal energy service (steam) to the majority of buildings and facilities in downtown Seattle, including major hospitals (Swedish and Virginia Mason) and The Northwest (Level I) Regional Trauma Center. Seattle Steam has been heating downtown businesses for 117 years, with an average length of service to its customers of 40 years. In 2008 and 2009 Seattle Steam developed a biomass-fueled renewable energy (bio-energy) system to replace one of its gas-fired boilers that will reduce greenhouse gases, pollutants and the amount of waste sent to landfills. This work in this sub-project included several distinct tasks associated with the biomass project development as follows: a. Engineering and Architecture: Engineering focused on development of system control strategies, development of manuals for start up and commissioning. b. Training: The project developer will train its current operating staff to operate equipment and facilities. c. Flue Gas Clean-Up Equipment Concept Design: The concept development of acid gas emissions control system strategies associated with the supply wood to the project. d. Fuel Supply Management Plan: Development of plans and specifications for the supply of wood. It will include potential fuel sampling analysis and development of contracts for delivery and management of fuel suppliers and handlers. e. Integrated Fuel Management System Development: Seattle Steam requires a biomass Fuel Management System to track and manage the delivery, testing, processing and invoicing of delivered fuel. This application will be web-based and accessed from a password-protected URL, restricting data access and privileges by user-level.

  6. Characterization of lignin derived from water-only and dilute acid flowthrough pretreatment of poplar wood at elevated temperatures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Libing; Yan, Lishi; Wang, Zheming; Laskar, Dhrubojyoti D.; Swita, Marie S.; Cort, John R.; Yang, Bin

    2015-12-01

    In this study, flowthrough pretreatment of biomass has high potential to valorize lignin derivatives to high-value products, which is vital to enhance the economy of biorefinery plants. Comprehensive understanding of lignin behaviors and solubilization chemistry in aqueous pretreatment such as water-only and dilute acid flowthrough pretreatment is of fundamental importance to achieve the goal of providing flexible platform for lignin utilization. In this study, the effects of flowthrough pretreatment conditions on lignin separation from poplar wood were reported as well as the characteristics of three sub-sets of lignin produced from the pretreatment, including residual lignin in pretreated solid residues (ReL),more » recovered insoluble lignin in pretreated liquid (RISL), and recovered soluble lignin in pretreatment liquid (RSL). Both the water-only and 0.05% (w/w) sulfuric acid pretreatments were performed at temperatures from 160 to 270°C on poplar wood in a flowthrough reactor system for 2-10 min. Results showed that water-only flowthrough pretreatment primarily removed syringyl (S units). Increased temperature and/or the addition of sulfuric acid enhanced the removal of guaiacyl (G units) compared to water-only pretreatments at lower temperatures, resulting in nearly complete removal of lignin from the biomass. Results also suggested that more RISL was recovered than ReL and RSL in both dilute acid and water-only flowthrough pretreatment at elevated temperatures. NMR spectra of the RISL revealed significant β-O-4 cleavage, α-β deoxygenation to form cinnamyl-like end groups, and slight β-5 repolymerization in both water-only and dilute acid flowthrough pretreatments. In conclusion, elevated temperature and/or dilute acid greatly enhanced lignin removal to almost 100% by improving G unit removal besides S unit removal in flowthrough system. A new lignin chemistry transformation pathway was proposed and revealed the complexity of lignin structural change

  7. Particulate residue separators for harvesting devices

    DOE Patents [OSTI]

    Hoskinson, Reed L.; Kenney, Kevin L.; Wright, Christopher T.; Hess, John R.

    2010-06-29

    A particulate residue separator and a method for separating a particulate residue stream may include a plenum borne by a harvesting device, and have a first, intake end and a second, exhaust end; first and second particulate residue air streams which are formed by the harvesting device and which travel, at least in part, along the plenum and in a direction of the second, exhaust end; and a baffle assembly which is located in partially occluding relation relative to the plenum, and which substantially separates the first and second particulate residue air streams.

  8. Methods of separating particulate residue streams

    DOE Patents [OSTI]

    Hoskinson, Reed L.; Kenney, Kevin L.; Wright, Christopher T.; Hess, J. Richard

    2011-04-05

    A particulate residue separator and a method for separating a particulate residue stream may include an air plenum borne by a harvesting device, and have a first, intake end and a second, exhaust end; first and second particulate residue air streams that are formed by the harvesting device and that travel, at least in part, along the air plenum and in a direction of the second, exhaust end; and a baffle assembly that is located in partially occluding relation relative to the air plenum and that substantially separates the first and second particulate residue air streams.

  9. Structural properties of laminated Douglas fir/epoxy composite material

    SciTech Connect (OSTI)

    Spera, D.A. . Lewis Research Center); Esgar, J.B. ); Gougeon, M.; Zuteck, M.D. )

    1990-05-01

    This publication contains a compilation of static and fatigue and strength data for laminated-wood material made from Douglas fir and epoxy. Results of tests conducted by several organizations are correlated to provide insight into the effects of variables such as moisture, size, lamina-to-lamina joint design, wood veneer grade, and the ratio of cyclic stress to steady stress during fatigue testing. These test data were originally obtained during development of wood rotor blades for large-scale wind turbines of the horizontal-axis (propeller) configuration. Most of the strength property data in this compilation are not found in the published literature. Test sections ranged from round cylinders 2.25 in. in diameter to rectangular slabs 6 in. by 24 in. in cross section and approximately 30 ft long. All specimens were made from Douglas fir veneers 0.10 in. thick, bonded together with the WEST epoxy system developed for fabrication and repair of wood boats. Loading was usually parallel to the grain. Size effects (reduction in strength with increase in test volume) are observed in some of the test data, and a simple mathematical model is presented that includes the probability of failure. General characteristics of the wood/epoxy laminate are discussed, including features that make it useful for a wide variety of applications. 9 refs.

  10. Superfund Record of Decision (EPA region 4): Coleman Evans Wood Preserving Co. , Jacksonville, Duval County, Florida, September 1986. Final report

    SciTech Connect (OSTI)

    Not Available

    1986-09-25

    The Coleman Evans Wood Preserving Company site is an active 11-acre wood-preserving facility located in the town of Whitehouse, Duval County, Florida. The site consists of two distinct areas: the western portion, which comprises the wood treating facility; and the eastern portion, which consists of a landfill area which has been used for the disposal of wood-chip and other wastes. Coleman Evans has produced wood products impregnated with PCP. Site investigations confirm soil and ground-water contamination, with PCP the primary contaminant of concern.

  11. Feasibility study of wood-fired cogeneration at a Wood Products Industrial Park, Belington, WV. Phase II

    SciTech Connect (OSTI)

    Vasenda, S.K.; Hassler, C.C.

    1992-06-01

    Customarily, electricity is generated in a utility power plant while thermal energy is generated in a heating/cooling plant; the electricity produced at the power plant is transmitted to the heating/cooling plant to power equipments. These two separate systems waste vast amounts of heat and result in individual efficiencies of about 35%. Cogeneration is the sequential production of power (electrical or mechanical) and thermal energy (process steam, hot/chilled water) from a single power source; the reject heat of one process issued as input into the subsequent process. Cogeneration increases the efficiency of these stand-alone systems by producing these two products sequentially at one location using a small additional amount of fuel, rendering the system efficiency greater than 70%. This report discusses cogeneration technologies as applied to wood fuel fired system.

  12. A Benchmark Study on Casting Residual Stress

    SciTech Connect (OSTI)

    Johnson, Eric M. [John Deere -- Moline Tech Center; Watkins, Thomas R [ORNL; Schmidlin, Joshua E [ORNL; Dutler, S. A. [MAGMA Foundry Technologies, Inc.

    2012-01-01

    Stringent regulatory requirements, such as Tier IV norms, have pushed the cast iron for automotive applications to its limit. The castings need to be designed with closer tolerances by incorporating hitherto unknowns, such as residual stresses arising due to thermal gradients, phase and microstructural changes during solidification phenomenon. Residual stresses were earlier neglected in the casting designs by incorporating large factors of safety. Experimental measurement of residual stress in a casting through neutron or X-ray diffraction, sectioning or hole drilling, magnetic, electric or photoelastic measurements is very difficult and time consuming exercise. A detailed multi-physics model, incorporating thermo-mechanical and phase transformation phenomenon, provides an attractive alternative to assess the residual stresses generated during casting. However, before relying on the simulation methodology, it is important to rigorously validate the prediction capability by comparing it to experimental measurements. In the present work, a benchmark study was undertaken for casting residual stress measurements through neutron diffraction, which was subsequently used to validate the accuracy of simulation prediction. The stress lattice specimen geometry was designed such that subsequent castings would generate adequate residual stresses during solidification and cooling, without any cracks. The residual stresses in the cast specimen were measured using neutron diffraction. Considering the difficulty in accessing the neutron diffraction facility, these measurements can be considered as benchmark for casting simulation validations. Simulations were performed using the identical specimen geometry and casting conditions for predictions of residual stresses. The simulation predictions were found to agree well with the experimentally measured residual stresses. The experimentally validated model can be subsequently used to predict residual stresses in different cast

  13. Characterization Report on Sand, Slag, and Crucible Residues and on Fluoride Residues

    SciTech Connect (OSTI)

    Murray, A.M.

    1999-02-10

    This paper reports on the chemical characterization of the sand, slag, and crucible (SS and C) residues and the fluoride residues that may be shipped from the Rocky Flats Environmental Technology Site (RFETS) to Savannah River Site (SRS).

  14. Assessment of Residual Stresses in 3013 Inner and Outer Containers and Teardrop Samples

    SciTech Connect (OSTI)

    Stroud, Mary Ann; Prime, Michael Bruce; Veirs, Douglas Kirk; Berg, John M.; Clausen, Bjorn; Worl, Laura Ann; DeWald, Adrian T.

    2015-12-08

    This report is an assessment performed by LANL that examines packaging for plutonium-bearing materials and the resilience of its design. This report discusses residual stresses in the 3013 outer, the SRS/Hanford and RFETS/LLNL inner containers, and teardrop samples used in studies to assess the potential for SCC in 3013 containers. Residual tensile stresses in the heat affected zones of the closure welds are of particular concern.

  15. A residual stress study in similar and dissimilar welds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Eisazadeh, Hamid; Goldak, John A.; Aidun, Daryush K.; Coules, Harry E.; Bunn, Jeffrey R; Achuthan, A.

    2016-04-01

    Residual strain distributions in similar and dissimilar welds were measured using neutron diffraction (ND) method. Then, using three strain components, three-dimensional stress states were calculated. The results were used to determine the effect of the martensitic phase transformation and material properties on residual stress (RS) distribution. It was observed that smaller longitudinal RS was induced in the low carbon steel side of dissimilar weld when compared to its similar weld. Also, it was found that the transverse RS near and within the weld zone (WZ) in dissimilar weld exhibited a distinctive trend, with tensile mode reaching the yield strength ofmore » the base metal (BM). In order to characterize the WZ in dissimilar weld, we deployed optical microscopy, hardness, and energy dispersive X-ray spectroscopy (EDAX). This study not only provides further insight into the RS state in similar and dissimilar welds; it also delivers important consequences of phase transformation in the latter case.« less

  16. Residential Bulk-Fed Wood-Pellet Central Boilers and Furnace Rebate Program

    Broader source: Energy.gov [DOE]

    The New Hampshire Public Utilities Commission (PUC) offers rebates of 30% of the installed cost of qualifying new residential bulk-fed, wood-pellet central heating boilers or furnaces. The maximum...

  17. Genomics of wood-degrading fungi Ohm, Robin A.; Riley, Robert...

    Office of Scientific and Technical Information (OSTI)

    Genomics of wood-degrading fungi Ohm, Robin A.; Riley, Robert; Salamov, Asaf; Min, Byoungnam; Choi, In-Geol; Grigoriev, Igor V. Not Available Elsevier None USDOE United States...

  18. Title 43 CFR 3620 Free Use of Petrified Wood | Open Energy Information

    Open Energy Info (EERE)

    620 Free Use of Petrified Wood Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- Federal RegulationFederal Regulation: Title 43 CFR 3620 Free Use...

  19. Preliminary investigation of steel compatibility with potential materials of construction for UF6 cylinder chocks

    SciTech Connect (OSTI)

    Pawel, S.J.; Ziehlke, K.T.; Swindeman, C.J.

    1992-12-01

    A set of compatibility experiments was performed to assess corrosion susceptibility of mild steel in long term contact with UF{sub 6} cylinder chocking materials and the atmosphere. Chock materials considered included concrete, pressure-treated wood, and creosote-treated wood. Immersion tests (panels partially submerged, 1000 h, 38 C), resistance probe measurements (600 h, ambient), and cyclic polarization tests on steel in leachate solutions generated from each chock material were performed. Results indicate that the long term corrosion susceptibility of mild steel in contact with concrete and the atmosphere is at least the equivalent of -- and under some conditions superior to -- that for steel in contact with pressure-treated or creosote-treated wood. No corrosion-related limitation for concrete chocks for long term support of mild steel UF{sub 6} cylinders was identified.

  20. SEP Success Story: How Much Wood Would a North Country School Chip

    Broader source: Energy.gov [DOE]

    The North Country School has dedicated itself to finding renewable sources of fuel to heat the approximately 85,000 square feet of classroom and office space on campus. After investigating many options, installing a wood chip boiler emerged as the most environmental and economical choice, due in large part to the availability of wood chips that are a by-product of the campus’ forest woodlot. Learn more.

  1. Microsoft Word - DOE-ID-13-053 Woods Hole EC B3-16.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 SECTION A. Project Title: Advances in the Recovery of Uranium from Seawater: Studies under Real Ocean Conditions - Woods Hole Oceanographic Institution SECTION B. Project Description Woods Hole Oceanographic Institution proposes to study the effectiveness of uranium adsorbents using different field testing designs. Objectives include: 1) To test the extraction efficiency of the uranium adsorbents under changing environmental conditions in a controlled laboratory setting and then in the field.

  2. Effect of sewage sludge content on gas quality and solid residues produced by cogasification in an updraft gasifier

    SciTech Connect (OSTI)

    Seggiani, Maurizia; Puccini, Monica; Raggio, Giovanni

    2012-10-15

    Highlights: Black-Right-Pointing-Pointer Cogasification of sewage sludge with wood pellets in updraft gasifier was analysed. Black-Right-Pointing-Pointer The effects of sewage sludge content on the gasification process were examined. Black-Right-Pointing-Pointer Sewage sludge addition up to 30 wt.% reduces moderately the process performance. Black-Right-Pointing-Pointer At high sewage sludge content slagging and clinker formation occurred. Black-Right-Pointing-Pointer Solid residues produced resulted acceptable at landfills for non-hazardous waste. - Abstract: In the present work, the gasification with air of dehydrated sewage sludge (SS) with 20 wt.% moisture mixed with conventional woody biomass was investigated using a pilot fixed-bed updraft gasifier. Attention was focused on the effect of the SS content on the gasification performance and on the environmental impact of the process. The results showed that it is possible to co-gasify SS with wood pellets (WPs) in updraft fixed-bed gasification installations. However, at high content of sewage sludge the gasification process can become instable because of the very high ash content and low ash fusion temperatures of SS. At an equivalent ratio of 0.25, compared with wood pellets gasification, the addition of sewage sludge led to a reduction of gas yield in favor of an increase of condensate production with consequent cold gas efficiency decrease. Low concentrations of dioxins/furans and PAHs were measured in the gas produced by SS gasification, well below the limiting values for the exhaust gaseous emissions. NH{sub 3}, HCl and HF contents were very low because most of these compounds were retained in the wet scrubber systems. On the other hand, high H{sub 2}S levels were measured due to high sulfur content of SS. Heavy metals supplied with the feedstocks were mostly retained in gasification solid residues. The leachability tests performed according to European regulations showed that metals leachability was

  3. Catalysts for cleaner combustion of coal, wood and briquettes sulfur dioxide reduction options for low emission sources

    SciTech Connect (OSTI)

    Smith, P.V.

    1995-12-31

    Coal fired, low emission sources are a major factor in the air quality problems facing eastern European cities. These sources include: stoker-fired boilers which feed district heating systems and also meet local industrial steam demand, hand-fired boilers which provide heat for one building or a small group of buildings, and masonary tile stoves which heat individual rooms. Global Environmental Systems is marketing through Global Environmental Systems of Polane, Inc. catalysts to improve the combustion of coal, wood or fuel oils in these combustion systems. PCCL-II Combustion Catalysts promotes more complete combustion, reduces or eliminates slag formations, soot, corrosion and some air pollution emissions and is especially effective on high sulfur-high vanadium residual oils. Glo-Klen is a semi-dry powder continuous acting catalyst that is injected directly into the furnace of boilers by operating personnel. It is a multi-purpose catalyst that is a furnace combustion catalyst that saves fuel by increasing combustion efficiency, a cleaner of heat transfer surfaces that saves additional fuel by increasing the absorption of heat, a corrosion-inhibiting catalyst that reduces costly corrosion damage and an air pollution reducing catalyst that reduces air pollution type stack emissions. The reduction of sulfur dioxides from coal or oil-fired boilers of the hand fired stoker design and larger, can be controlled by the induction of the Glo-Klen combustion catalyst and either hydrated lime or pulverized limestone.

  4. Material Misfits

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Issues submit Material Misfits How well nanocomposite materials align at their interfaces determines what properties they have, opening broad new avenues of materials-science...

  5. Recovery of Plutonium from Refractory Residues Using a Sodium Peroxide Pretreatment Process

    SciTech Connect (OSTI)

    Rudisill, T.S.

    2003-10-23

    The recycle of plutonium from refractory residues is a necessary activity for the nuclear weapon production complex. Traditionally, high-fired plutonium oxide (PuO2) was leached from the residue matrix using a nitric acid/fluoride dissolving flowsheet. The recovery operations were time consuming and often required multiple contacts with fresh dissolving solution to reduce the plutonium concentration to levels where residual solids could be discarded. Due to these drawbacks, the development of an efficient process for the recovery of plutonium from refractory materials is desirable. To address this need, a pretreatment process was developed. The development program utilized a series of small-scale experiments to optimize processing conditions for the fusion process and demonstrate the plutonium recovery efficiency using ceramic materials developed as potential long-term storage forms for PuO2 and an incinerator ash from the Rocky Flats Environmental Technology Site (Rocky Flats) as te st materials.

  6. The National Nuclear Laboratory's Approach to Processing Mixed Wastes and Residues - 13080

    SciTech Connect (OSTI)

    Greenwood, Howard; Docrat, Tahera; Allinson, Sarah J.; Coppersthwaite, Duncan P.; Sultan, Ruqayyah; May, Sarah

    2013-07-01

    The National Nuclear Laboratory (NNL) treats a wide variety of materials produced as by-products of the nuclear fuel cycle, mostly from uranium purification and fuel manufacture but also including materials from uranium enrichment and from the decommissioning of obsolete plants. In the context of this paper, treatment is defined as recovery of uranium or other activity from residues, the recycle of uranium to the fuel cycle or preparation for long term storage and the final disposal or discharge to the environment of the remainder of the material. NNL's systematic but flexible approach to residue assessment and treatment is described in this paper. The approach typically comprises up to five main phases. The benefits of a systematic approach to waste and residue assessments and processing are described in this paper with examples used to illustrate each phase of work. Benefits include early identification of processing routes or processing issues and the avoidance of investment in inappropriate and costly plant or processes. (authors)

  7. Continuous-flow wood chip reactor for biodegradation of 2,4-DCP

    SciTech Connect (OSTI)

    Yum, K.J.; Peirce, J.J.

    1998-02-01

    Chlorinated phenols are by-products of chlorine bleaching in numerous industries including pulp and paper mills and can be emitted from a variety of incineration processes. This research investigates the ability and efficiency of continuous-flow wood chip reactors seeded with a white-rot fungus to degrade 2,4-dichlorophenol (2,4-DCP) using wood chips as a carbon source. When 2,4-DCP was the only substrate (nonglucose treatment conditions), the wood chip reactor system had a high degradation efficiency and operated continuously without excessive fungal biomass buildup on the wood chips. In the presence of added glucose, a clogging problem and an effluent contamination problem of fungal cells are found during the reactor operating period. In addition, 2,4-DCP is degraded effectively both under low-nitrogen as well as high-nitrogen treatment conditions. The 2,4-DCP is degraded to a greater extent with small-size wood chips and hardwood chips as a carbon source. The results of this research demonstrate a potential application of wood chip reactor systems for the treatment of contaminated water while expanding the use of wasted forest products.

  8. Permeability of wood pellets in the presence of fines

    SciTech Connect (OSTI)

    Yazdanpanah, F.; Lau, A.K.; Sokhansanj, Shahabaddine; Lim, C. Jim; Melin, Staffan; Bi, X.T.; Afzal, M

    2010-03-01

    Broken pellets and fines are produced during mechanical handlings of wood pellets. The resistance to air flow was measured for clean pellets and for pellets mixed with 1 to 20% broken pellets (fines). A pellet diameter was 6 mm. The lengths ranged from from 6 to 12 mm. Clean pellets were defined as particles that remained on a 4 mm screen. A typical sieve analysis showed 30% of the mass of particles passed through the 4 mm screen were smaller than 1 mm. The airflow rates used in the experiment ranged from 0.004 to 0.357 ms-1. The corresponding pressure drop ranged from 1.9 Pa m-1 to 271 Pa m-1 for clean pellets and from 4.8 to 1100 Pa m 1 for pellets mixed with 10% fines. The pressure drop increased for pellets mixed with increasing fines content. Coefficients of Hukill and Ives equation were estimated for clean pellets and a multiplier was defined to calculate pressure drop for pellets mixed with fines.

  9. Co-combustion of sludge with coal or wood

    SciTech Connect (OSTI)

    Leckner, B.; Aamand, L.-E.

    2004-07-01

    There are several options for co-combustion of biomass or waste with coal. In all cases the fuel properties are decisive for the success of the arrangement: contents of volatile matter and of potential emission precursors, such as sulphur, nitrogen, chlorine, and heavy metals. The content of alkali in the mineral substance of the fuel is important because of the danger of fouling and corrosion. Research activities at Chalmers University of Technology include several aspects of the related problems areas. An example is given concerning emissions from co-combustion in circulating fluidized beds with coal or wood as base fuels, and with sewage sludge as additional fuel. Two aspects of the properties of sludge are studied: emissions of nitrogen and sulphur oxides as well as of chlorine, because the contents of the precursors to these emissions are high. The possibility of utilizing the phosphorus in sludge as a fertilizer is also discussed. The results show that emissions can be kept below existing emission limits if the fraction of sludge is sufficiently small but the concentration of trace elements in the sludge ash prevents the sludge from being used as a fertilizer. 15 refs., 9 figs., 2 tabs.

  10. End-of-life vehicle recycling : state of the art of resource recovery from shredder residue.

    SciTech Connect (OSTI)

    Jody, B. J.; Daniels, E. J.; Energy Systems

    2007-03-21

    Each year, more than 50 million vehicles reach the end of their service life throughout the world. More than 95% of these vehicles enter a comprehensive recycling infrastructure that includes auto parts recyclers/dismantlers, remanufacturers, and material recyclers (shredders). Today, about 75% of automotive materials are profitably recycled via (1) parts reuse and parts and components remanufacturing and (2) ultimately by the scrap processing (shredding) industry. The process by which the scrap processors recover metal scrap from automobiles involves shredding the obsolete automobiles, along with other obsolete metal-containing products (such as white goods, industrial scrap, and demolition debris), and recovering the metals from the shredded material. The single largest source of recycled ferrous scrap for the iron and steel industry is obsolete automobiles. The non-metallic fraction that remains after the metals are recovered from the shredded materials (about 25% of the weight of the vehicle)--commonly called shredder residue--is disposed of in landfills. Over the past 10 to 15 years, a significant amount of research and development has been undertaken to enhance the recycle rate of end-of-life vehicles (ELVs), including enhancing dismantling techniques and improving remanufacturing operations. However, most of the effort has focused on developing technology to recover materials, such as polymers, from shredder residue. To make future vehicles more energy efficient, more lighter-weight materials--primarily polymers and polymer composites--will be used in manufacturing these vehicles. These materials increase the percentage of shredder residue that must be disposed of, compared with the percentage of metals. Therefore, as the complexity of automotive materials and systems increases, new technologies will be required to sustain and maximize the ultimate recycling of these materials and systems at end-of-life. Argonne National Laboratory (Argonne), in cooperation

  11. Fate of asphaltenes during hydroprocessing of heavy petroleum residues

    SciTech Connect (OSTI)

    Stanislaus, A.; Absi-Halabi, M.; Khan, Z.

    1994-12-31

    Formation of coke like sediments or particulates is a serious problem in the hydroprocessing of heavy residues for high conversion. The sediments can cause both operability problems and rapid catalyst deactivation. The macromolecules of the heavy feedstocks such as asphaltenes are believed to contribute significantly to sediment formation and coke deposition. As part of an extensive research program on the factors which influence sludge or solids formation during residue hydroprocessing, the authors have examined the nature of changes that take place in the characteristics of the asphaltenic fraction of Kuwait vacuum residue under different operating conditions. The studies revealed that sediment formation is the result of reduction in solubilization efficiency of asphaltenes in the product medium compared with feedstock. Molecular size distribution of the product asphaltenes showed that operating at high temperatures enhanced depolymerization and fragmentation of asphaltenes to low molecular weight materials. A portion of the low molecular weight asphaltene fragments with relatively low H/C ratio resisted further cracking even at high temperatures and led to the formation of coke like sediments. Large pore catalysts were observed to reduce the problem of sediments formation. The role of catalyst pore size on asphaltenes conversion is discussed.

  12. Washing of Rocky Flats Combustible Residues (Conducted March - May 1995)

    SciTech Connect (OSTI)

    Mary E. Barr; Ann R. Schake; David A. Romero; Gordon D. Jarvinen

    1999-03-01

    The scope of this project is to determine the feasibility of washing plutonium-containing combustible residues using ultrasonic disruption as a method for dislodging particulate. Removal of plutonium particulate and, to a lesser extent, solubilized plutonium from the organic substrate should substantially reduce potential fire, explosion or radioactive release hazards due to radiolytic hydrogen generation or high flammability. Tests were conducted on polypropylene filters which were used as pre-filters in the rich-residue ion-exchange process at the Los Alamos Plutonium Facility. These filters are similar to the Ful-Flo{reg_sign} cartridges used at Rocky Flats that make up a substantial fraction of the combustible residues with the highest hazard rating. Batch experiments were run on crushed filter material in order to determine the amount of Pu removed by stirring, stirring and sonication, and stirring and sonication with the introduction of Pu-chelating water-soluble polymers or surfactants. Significantly more Pu is removed using sonication and sonication with chelators than is removed with mechanical stirring alone.

  13. Converting urban tree maintenance residue to energy

    SciTech Connect (OSTI)

    Murphey, W.K.; Massey, J.G.; Sumrall, A.

    1980-01-01

    Three methods of utilizing urban wood waste collected by a tree maintenance firm in Houston, Texas (handling 30,000 ton waste/year) are examined: (a) hauling to a remote landfill; (b) chipping and hauling to a (local) power plant and converting to electricity; and (c) chipping and selling to an outside firm for use as boiler fuel. Breakdown of costs are given for each method in monetary and energy terms. Method (b) was the cheapest, producing a net energy gain (870 million Btu/day), but the firm chose method (c), since it realized a direct monetary return.

  14. Functional Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Functional Materials Researchers in NETL's Functional Materials Development competency work to discover and develop advanced functional materials and component processing technologies to meet technology performance requirements and enable scale-up for proof-of-concept studies. Research includes separations materials and electrochemical and magnetic materials, specifically: Separations Materials Synthesis, purification, and basic characterization of organic substances, including polymers and

  15. Residual stress and plastic anisotropy in indented 2024-T351 aluminum disks

    SciTech Connect (OSTI)

    Clausen, Bjorn; Prime, Michael B; Saurabh, Kabra; Brown, Donald W; Pagliaro, Pierluigi; Backlund, Peter; Shaw, Sanjiv; Criss, Everett

    2009-01-01

    Recent studies have proven that generating a well defined residual stress state using the indented disk approach is an excellent way to validate experimental and modeling techniques for measuring and predicting residual stresses. The previous studies dealt with indented stainless steel disks, and included experimental determination of residual stresses using the Contour Method and neutron diffraction measurements. The measured residual stress states showed good agreement between the techniques, and a Finite Element Model predicted residual stress state based upon material properties determined form standard tension and compression/tension tests was also in good agreement with the measurements. In the present work, disks of 2024-T351 Aluminum were investigated. As before, the residual stress profile was measured using neutron diffraction and the Contour Method and Finite Element Modeling was employed to predict the residual stress profile. Analysis and comparison of the three techniques were complicated by the fact that the experimental data shows evidence of plastic anisotropy and strong Bauschinger effect within the indented disks.

  16. Materials Chemistry and Performance of Silicone-Based Replicating Compounds.

    SciTech Connect (OSTI)

    Brumbach, Michael T.; Mirabal, Alex James; Kalan, Michael; Trujillo, Ana B; Hale, Kevin

    2014-11-01

    Replicating compounds are used to cast reproductions of surface features on a variety of materials. Replicas allow for quantitative measurements and recordkeeping on parts that may otherwise be difficult to measure or maintain. In this study, the chemistry and replicating capability of several replicating compounds was investigated. Additionally, the residue remaining on material surfaces upon removal of replicas was quantified. Cleaning practices were tested for several different replicating compounds. For all replicating compounds investigated, a thin silicone residue was left by the replica. For some compounds, additional inorganic species could be identified in the residue. Simple solvent cleaning could remove some residue.

  17. Fuel switching from wood to LPG can benefit the environment

    SciTech Connect (OSTI)

    Nautiyal, Sunil Kaechele, Harald

    2008-11-15

    The Himalaya in India is one of the world's biodiversity hotspots. Various scientific studies have reported and proven that many factors are responsible for the tremendous decline of the Himalayan forests. Extraction of wood biomass from the forests for fuel is one of the factors, as rural households rely entirely on this for their domestic energy. Efforts continue for both conservation and development of the Himalayan forests and landscape. It has been reported that people are still looking for more viable solutions that could help them to improve their lifestyle as well as facilitate ecosystem conservation and preservation of existing biodiversity. In this direction, we have documented the potential of the introduction of liquefied petroleum gas (LPG), which is one of the solutions that have been offered to the local people as a substitute for woodfuel to help meet their domestic energy demand. The results of the current study found dramatic change in per capita woodfuel consumption in the last two decades in the villages where people are using LPG. The outcome showed that woodfuel consumption had been about 475 kg per capita per year in the region, but after introduction of LPG, this was reduced to 285 kg per capita per year in 1990-1995, and was further reduced to 46 kg per capita per year in 2000-2005. Besides improving the living conditions of the local people, this transformation has had great environmental consequences. Empirical evidence shows that this new paradigm shift is having positive external effects on the surrounding forests. Consequently, we have observed a high density of tree saplings and seedlings in adjacent forests, which serves as an assessment indicator of forest health. With the help of the current study, we propose that when thinking about a top-down approach to conservation, better solutions, which are often ignored, should be offered to local people.

  18. Quantifying And Predicting Wood Quality Of Loblolly And Slash Pine Under Intensive Forest Management Final Technical Report

    SciTech Connect (OSTI)

    Richard F. Daniels; Alexander Clark III

    2006-05-04

    The forest industry will increasingly rely on fast-growing intensively managed southern pine plantations to furnish wood and fiber. Intensive silvicultural practices, including competition control, stand density control, fertilization, and genetic improvement are yielding tremendous gains in the quantity of wood production from commercial forest land. How these technologies affect wood properties was heretofore unknown, although there is concern about the suitability of fast-grown wood for traditional forest products. A four year study was undertaken to examine the effects of these intensive practices on the properties of loblolly and slash pine wood by applying a common sampling method over 10 existing field experiments. Early weed control gets young pines off to a rapid start, often with dramatically increased growth rates. This response is all in juvenile wood however, which is low in density and strength. Similar results are found with early Nitrogen fertilization at the time of planting. These treatments increase the proportion of juvenile wood in the tree. Later, mid-rotation fertilization with Nitrogen and Phosphorus can have long term (4-8 year) growth gains. Slight reductions in wood density are short-lived (1-2 years) and occur while the tree is producing dense, stiff mature wood. Impacts of mid-rotation fertilization on wood properties for manufacturing are estimated to be minimal. Genetic differences are evident in wood density and other properties. Single family plantings showed somewhat more uniform properties than bulk improved or unimproved seedlots. Selection of genetic sources with optimal wood properties may counter some of the negative impacts of intensive weed control and fertilization. This work will allow forest managers to better predict the effects of their practices on the quality of their final product.

  19. Machine vision based particle size and size distribution determination of airborne dust particles of wood and bark pellets

    SciTech Connect (OSTI)

    Igathinathane, C; Pordesimo, L.O.

    2009-08-01

    Dust management strategies in industrial environment, especially of airborne dust, require quantification and measurement of size and size distribution of the particles. Advanced specialized instruments that measure airborne particle size and size distribution apply indirect methods that involve light scattering, acoustic spectroscopy, and laser diffraction. In this research, we propose a simple and direct method of airborne dust particle dimensional measurement and size distribution analysis using machine vision. The method involves development of a user-coded ImageJ plugin that measures particle length and width and analyzes size distribution of particles based on particle length from high-resolution scan images. Test materials were airborne dust from soft pine wood sawdust pellets and ground pine tree bark pellets. Subsamples prepared by dividing the actual dust using 230 mesh (63 m) sieve were analyzed as well. A flatbed document scanner acquired the digital images of the dust particles. Proper sampling, layout of dust particles in singulated arrangement, good contrast smooth background, high resolution images, and accurate algorithm are essential for reliable analysis. A halo effect around grey-scale images ensured correct threshold limits. The measurement algorithm used Feret s diameter for particle length and pixel-march technique for particle width. Particle size distribution was analyzed in a sieveless manner after grouping particles according to their distinct lengths, and several significant dimensions and parameters of particle size distribution were evaluated. Results of the measurement and analysis were presented in textual and graphical formats. The developed plugin was evaluated to have a dimension measurement accuracy in excess of 98.9% and a computer speed of analysis of <8 s/image. Arithmetic mean length of actual wood and bark pellets airborne dust particles were 0.1138 0.0123 and 0.1181 0.0149 mm, respectively. The airborne dust particles of

  20. Structural Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Structural Materials Structural Materials Development enables advanced technologies through the discovery, development, and demonstration of cost-effective advanced structural materials for use in extreme environments (high-temperature, high-stress, erosive, and corrosive environments, including the performance of materials in contact with molten slags and salts). Research includes materials design and discovery, materials processing and manufacturing, and service-life prediction of materials

  1. ,"U.S. Residual Fuel Oil Prices by Sales Type"

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Residual Fuel Oil Average",2,"Monthly","52016","115... AM" "Back to Contents","Data 1: Residual Fuel Oil Average" "Sourcekey","EMAEPPRPTANUS...

  2. Kaisheng Biomass Residue Power Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Kaisheng Biomass Residue Power Co Ltd Jump to: navigation, search Name: Kaisheng Biomass Residue Power Co., Ltd. Place: Nanping City, Fujian Province, China Zip: 365001 Sector:...

  3. Chemical stabilization of Hanford tank residual waste (Journal...

    Office of Scientific and Technical Information (OSTI)

    Chemical stabilization of Hanford tank residual waste Citation Details In-Document Search Title: Chemical stabilization of Hanford tank residual waste Authors: Cantrell, Kirk J. ; ...

  4. Indentation Based Techniques to Measure Residual Stresses in...

    Office of Scientific and Technical Information (OSTI)

    to Measure Residual Stresses in Engineering Ceramics. Citation Details In-Document Search Title: Indentation Based Techniques to Measure Residual Stresses in Engineering Ceramics. ...

  5. A novel approach in organic waste utilization through biochar addition in wood/polypropylene composites

    SciTech Connect (OSTI)

    Das, Oisik; Sarmah, Ajit K.; Bhattacharyya, Debes

    2015-04-15

    Highlights: • Biochar made from waste wood was added with wood polypropylene composites. • 24% biochar gave the best mechanical properties. • 6% biochar had no effect on physico-mechanical properties of composites. • Coupling agent remained unreacted in composites having higher amount of biochar. - Abstract: In an attempt to concurrently address the issues related to landfill gas emission and utilization of organic wastes, a relatively novel idea is introduced to develop biocomposites where biochar made from pyrolysis of waste wood (Pinus radiata) is added with the same wood, plastic/polymer (polypropylene) and maleated anhydride polypropylene (MAPP). Experiments were conducted by manufacturing wood and polypropylene composites (WPCs) mixed with 6 wt%, 12 wt%, 18 wt%, 24 wt%, and 30 wt% biochar. Though 6 wt% addition had similar properties to that of the control (composite without biochar), increasing biochar content to 24 wt% improved the composite’s tensile/flexural strengths and moduli. The biochar, having high surface area due to fine particles and being highly carbonised, acted as reinforcing filler in the biocomposite. Composites having 12 wt% and 18 wt% of biochar were found to be the most ductile and thermally stable, respectively. This study demonstrates that, WPCs added with biochar has good potential to mitigate wastes while simultaneously producing biocomposites having properties that might be suited for various end applications.

  6. INTERFACE RESIDUAL STRESSES IN DENTAL ZIRCONIA USING LAUE MICRO-DIFFRACTION

    SciTech Connect (OSTI)

    Bale, H. A.; Tamura, N.; Coelho, P.G.; Hanan, J. C.

    2009-01-01

    Due to their aesthetic value and high compressive strength, dentists have recently employed ceramics for restoration materials. Among the ceramic materials, zirconia provides high toughness and crack resistant characteristics. Residual stresses develop in processing due to factors including grain anisotropy and thermal coefficient mismatch. In the present study, polychromatic X-ray (Laue) micro-diffraction provided grain orientation and residual stresses on a clinically relevant zirconia model ceramic disk. A 0.5 mm x 0.024 mm region on zirconia was examined on a 500 nm scale for residual stresses using a focused poly-chromatic synchrotron X-ray beam. Large stresses ranging from - to + 1GPa were observed at some grains. On average, the method suggests a relatively small compressive stress at the surface between 47 and 75 MPa depending on direction.

  7. Propulsion Materials

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Propulsion Materials FY 2013 Progress Report ii CONTENTS INTRODUCTION ....................................................................................................................................... 1 Project 18516 - Materials for H1ybrid and Electric Drive Systems ...................................................... 4 Agreement 19201 - Non-Rare Earth Magnetic Materials ............................................................................ 4 Agreement 23278 - Low-Cost

  8. Metal recovery from porous materials

    DOE Patents [OSTI]

    Sturcken, Edward F.

    1992-01-01

    A method for recovering plutonium and other metals from materials by leaching comprising the steps of incinerating the materials to form a porous matrix as the residue of incineration, immersing the matrix into acid in a microwave-transparent pressure vessel, sealing the pressure vessel, and applying microwaves so that the temperature and the pressure in the pressure vessel increase. The acid for recovering plutonium can be a mixture of HBF.sub.4 and HNO.sub.3 and preferably the pressure is increased to at least 100 PSI and the temperature to at least 200.degree. C. The porous material can be pulverized before immersion to further increase the leach rate.

  9. Method for distributing chemicals through a fibrous material using low-headspace dielectric heating

    DOE Patents [OSTI]

    Banerjee, Sujit; Malcolm, Earl

    2002-01-01

    System and method for diffusing chemicals rapidly and evenly into and through fibrous material, such as wood. Chemicals are introduced into the fibrous material by applying the chemicals to the fibrous material. After treating the fibrous material with the chemicals, the fibrous material is maintained under low-headspace conditions. Thermal energy or dielectric heating, such as microwave or radio frequency energy, is applied to the fibrous material. As a result, the chemicals are able to distribute evenly and quickly throughout the fibrous material.

  10. Materials Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Materials Science Materials Science National security depends on science and technology. The United States relies on Los Alamos National Laboratory for the best of both. No place on Earth pursues a broader array of world-class scientific endeavors. Materials Physics and Applications» Materials Science and Technology» Institute for Materials Science» Materials Science Rob Dickerson uses a state-of-the-art transmission electron microscope at the Electron Microscopy Laboratory managed by Los

  11. Disposal of Rocky Flats residues as waste

    SciTech Connect (OSTI)

    Dustin, D.F.; Sendelweck, V.S. . Rocky Flats Plant); Rivera, M.A. )

    1993-01-01

    Work is underway at the Rocky Flats Plant to evaluate alternatives for the removal of a large inventory of plutonium-contaminated residues from the plant. One alternative under consideration is to package the residues as transuranic wastes for ultimate shipment to the Waste Isolation Pilot Plant. Current waste acceptance criteria and transportation regulations require that approximately 1000 cubic yards of residues be repackaged to produce over 20,000 cubic yards of WIPP certified waste. The major regulatory drivers leading to this increase in waste volume are the fissile gram equivalent, surface radiation dose rate, and thermal power limits. In the interest of waste minimization, analyses have been conducted to determine, for each residue type, the controlling criterion leading to the volume increase, the impact of relaxing that criterion on subsequent waste volume, and the means by which rules changes may be implemented. The results of this study have identified the most appropriate changes to be proposed in regulatory requirements in order to minimize the costs of disposing of Rocky Flats residues as transuranic wastes.

  12. Disposal of Rocky Flats residues as waste

    SciTech Connect (OSTI)

    Dustin, D.F.; Sendelweck, V.S.; Rivera, M.A.

    1993-03-01

    Work is underway at the Rocky Flats Plant to evaluate alternatives for the removal of a large inventory of plutonium-contaminated residues from the plant. One alternative under consideration is to package the residues as transuranic wastes for ultimate shipment to the Waste Isolation Pilot Plant. Current waste acceptance criteria and transportation regulations require that approximately 1000 cubic yards of residues be repackaged to produce over 20,000 cubic yards of WIPP certified waste. The major regulatory drivers leading to this increase in waste volume are the fissile gram equivalent, surface radiation dose rate, and thermal power limits. In the interest of waste minimization, analyses have been conducted to determine, for each residue type, the controlling criterion leading to the volume increase, the impact of relaxing that criterion on subsequent waste volume, and the means by which rules changes may be implemented. The results of this study have identified the most appropriate changes to be proposed in regulatory requirements in order to minimize the costs of disposing of Rocky Flats residues as transuranic wastes.

  13. Structural Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Structural Materials Development enables advanced technologies through the discovery, development, and demonstration of cost-effective advanced structural materials for use in ...

  14. Reference Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reference Materials Reference Materials Large Scale Computing and Storage Requirements for Biological and Environmental Research May 7-8, 2009 Invitation Workshop Invitation Letter...

  15. Reference Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reference Materials Reference Materials Large Scale Computing and Storage Requirements for Basic Energy Sciences February 9-10, 2010 Official DOE Invitation Workshop Invitation...

  16. Precision wood particle feedstocks with retained moisture contents of greater than 30% dry basis

    DOE Patents [OSTI]

    Dooley, James H; Lanning, David N

    2014-10-28

    Wood particles having fibers aligned in a grain, wherein: the wood particles are characterized by a length dimension (L) aligned substantially parallel to the grain, a width dimension (W) normal to L and aligned cross grain, and a height dimension (H) normal to W and L; the L.times.H dimensions define two side surfaces characterized by substantially intact longitudinally arrayed fibers; the W.times.H dimensions define two cross-grain end surfaces characterized individually as aligned either normal to the grain or oblique to the grain; the L.times.W dimensions define two substantially parallel top and bottom surfaces; and, a majority of the W.times.H surfaces in the mixture of wood particles have end checking.

  17. Renewable wood fuel: Fuel feed system for a pulverized coal boiler. Final report

    SciTech Connect (OSTI)

    1996-01-01

    This report evaluates a pilot test program conducted by New York State Gas & Electric Corporation to evaluate the feasibility of co-firing a pulverized coal plant with renewable wood fuels. The goal was to establish that such a co-firing system can reduce air emissions while maintaining good operational procedures and cost controls. The test fuel feed system employed at Greenidge Station`s Boiler 6 was shown to be effective in feeding wood products. Emission results were promising and an economic analysis indicates that it will be beneficial to pursue further refinements to the equipment and systems. The report recommends further evaluation of the generation and emission impacts using woods of varied moisture contents and at varied Btu input rates to determine if a drying system would be a cost-effective option.

  18. Assessment of potential wood supply for intermediate scale thermoconversion facilities, Tasks I, II, III

    SciTech Connect (OSTI)

    Not Available

    1985-11-01

    The Department of Energy's Biomass Thermochemical Conversion Program has been concerned with the potential of wood biomass to contribute to the Nation's energy supply. One of the factors inhibiting the selection of wood biomass for energy by non-forest industries, especially by those requiring large quantities (500 to 2000 green tons per day), is concern with adequate fuel supply in terms of both a supply system and an adequate resource base. With respect to the latter, this report looks at the gross resource base as has been historically reported and also examines factors other than traditional product removals that could reduce to some degree the amount of resource that is available. The study also examined the conversion of a New England utility from coal to wood chips.

  19. Use of selective oxidation of petroleum residue for production of low-sulfur coke

    SciTech Connect (OSTI)

    Hairudinov, I.R.; Kul`chitskaya, O.V.; Imashev, U.B.

    1995-12-10

    The chemical nature of liquid-phase oxidation of sulfurous petroleum residues by cumene hydroperoxide was studied by a tracer technique. Sulfur compounds are selectively oxidized in the presence of catalytic additives of molybdenum salts. Desulfurization of distillate products and coke during coking of preoxidized raw materials was revealed.

  20. System and method for measuring residual stress

    DOE Patents [OSTI]

    Prime, Michael B.

    2002-01-01

    The present invention is a method and system for determining the residual stress within an elastic object. In the method, an elastic object is cut along a path having a known configuration. The cut creates a portion of the object having a new free surface. The free surface then deforms to a contour which is different from the path. Next, the contour is measured to determine how much deformation has occurred across the new free surface. Points defining the contour are collected in an empirical data set. The portion of the object is then modeled in a computer simulator. The points in the empirical data set are entered into the computer simulator. The computer simulator then calculates the residual stress along the path which caused the points within the object to move to the positions measured in the empirical data set. The calculated residual stress is then presented in a useful format to an analyst.

  1. The flash pyrolysis and methanolysis of biomass (wood) for production of ethylene, benzene and methanol

    SciTech Connect (OSTI)

    Steinberg, M.; Fallon, P.T.; Sundaram, M.S.

    1990-02-01

    The process chemistry of the flash pyrolysis of biomass (wood) with the reactive gases, H{sub 2} and CH{sub 4} and with the non-reactive gases He and N{sub 2} is being determined in a 1 in. downflow tubular reactor at pressures from 20 to 1000 psi and temperatures from 600 to 1000{degrees}C. With hydrogen, flash hydropyrolysis leads to high yields of methane and CO which can be used for SNG and methanol fuel production. With methane, flash methanolysis leads to high yields of ethylene, benzene and CO which can be used for the production of valuable chemical feedstocks and methanol transportation fuel. At reactor conditions of 50 psi and 1000{degrees}C and approximately 1 sec residence time, the yields based on pine wood carbon conversion are up to 25% for ethylene, 25% for benzene, and 45% for CO, indicating that over 90% of the carbon in pine is converted to valuable products. Pine wood produces higher yields of hydrocarbon products than Douglas fir wood; the yield of ethylene is 2.3 times higher with methane than with helium or nitrogen, and for pine, the ratio is 7.5 times higher. The mechanism appears to be a free radical reaction between CH{sub 4} and the pyrolyzed wood. There appears to be no net production or consumption of methane. A preliminary process design and analysis indicates a potentially economical competitive system for the production of ethylene, benzene and methanol based on the methanolysis of wood. 10 refs., 18 figs., 1 tab.

  2. Lowell L. Wood, 1981 | U.S. DOE Office of Science (SC)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lowell L. Wood, 1981 The Ernest Orlando Lawrence Award Lawrence Award Home Nomination & Selection Guidelines Award Laureates 2010's 2000's 1990's 1980's 1970's 1960's Ceremony The Life of Ernest Orlando Lawrence Contact Information The Ernest Orlando Lawrence Award U.S. Department of Energy SC-2/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-2411 E: Email Us 1980's Lowell L. Wood, 1981 Print Text Size: A A A FeedbackShare Page National Security: For his

  3. Investigation of possible health effects of community exposure to fermenting wood chips

    SciTech Connect (OSTI)

    Birkhead, G.; Vogt, R.L.; Hudson, P.J.

    1988-03-01

    We conducted a case-control study of emergency room (ER) patients to evaluate whether asthma is caused by living near a wood-chip fueled power plant that released wood-chip fermentation products. Only eight (29 per cent) of 28 asthma patients seen in the ER during an 11-week period lived within 1.5 miles of the plant compared with 18 (34 per cent) of 54 control patients matched for severity of diagnosis and seen during the same period (Mantel-Haenszel odds ratio controlling for age = 0.96).

  4. Materials Scientist

    Broader source: Energy.gov [DOE]

    Alternate Title(s):Materials Research Engineer; Metallurgical/Chemical Engineer; Product Development Manager;

  5. material protection

    National Nuclear Security Administration (NNSA)

    %2A en Office of Weapons Material Protection http:nnsa.energy.govaboutusourprogramsnonproliferationprogramofficesinternationalmaterialprotectionandcooperation-1

  6. material protection

    National Nuclear Security Administration (NNSA)

    %2A en Office of Weapons Material Protection http:www.nnsa.energy.govaboutusourprogramsnonproliferationprogramofficesinternationalmaterialprotectionandcooperation-1

  7. Stabilization of Rocky Flats combustible residues contaminated with plutonium metal and organic solvents

    SciTech Connect (OSTI)

    Bowen, S.M.; Cisneros, M.R.; Jacobson, L.L.; Schroeder, N.C.; Ames, R.L.

    1998-09-30

    This report describes tests on a proposed flowsheet designed to stabilize combustible residues that were generated at the Rocky Flats Environmental Technology Site (RFETS) during the machining of plutonium metal. Combustible residues are essentially laboratory trash contaminated with halogenated organic solvents and plutonium metal. The proposed flowsheet, designed by RFETS, follows a glovebox procedure that includes (1) the sorting and shredding of materials, (2) a low temperature thermal desorption of solvents from the combustible materials, (3) an oxidation of plutonium metal with steam, and (4) packaging of the stabilized residues. The role of Los Alamos National Laboratory (LANL) in this study was to determine parameters for the low temperature thermal desorption and steam oxidation steps. Thermal desorption of carbon tetrachloride (CCl{sub 4}) was examined using a heated air stream on a Rocky Flats combustible residue surrogate contaminated with CCl{sub 4}. Three types of plutonium metal were oxidized with steam in a LANL glovebox to determine the effectiveness of this procedure for residue stabilization. The results from these LANL experiments are used to recommend parameters for the proposed RFETS stabilization flowsheet.

  8. Hybrid statistical testing for nuclear material accounting data and/or process monitoring data in nuclear safeguards

    SciTech Connect (OSTI)

    Burr, Tom; Hamada, Michael S.; Ticknor, Larry; Sprinkle, James

    2015-01-01

    The aim of nuclear safeguards is to ensure that special nuclear material is used for peaceful purposes. Historically, nuclear material accounting (NMA) has provided the quantitative basis for monitoring for nuclear material loss or diversion, and process monitoring (PM) data is collected by the operator to monitor the process. PM data typically support NMA in various ways, often by providing a basis to estimate some of the in-process nuclear material inventory. We develop options for combining PM residuals and NMA residuals (residual = measurement - prediction), using a hybrid of period-driven and data-driven hypothesis testing. The modified statistical tests can be used on time series of NMA residuals (the NMA residual is the familiar material balance), or on a combination of PM and NMA residuals. The PM residuals can be generated on a fixed time schedule or as events occur.

  9. Hybrid statistical testing for nuclear material accounting data and/or process monitoring data in nuclear safeguards

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Burr, Tom; Hamada, Michael S.; Ticknor, Larry; Sprinkle, James

    2015-01-01

    The aim of nuclear safeguards is to ensure that special nuclear material is used for peaceful purposes. Historically, nuclear material accounting (NMA) has provided the quantitative basis for monitoring for nuclear material loss or diversion, and process monitoring (PM) data is collected by the operator to monitor the process. PM data typically support NMA in various ways, often by providing a basis to estimate some of the in-process nuclear material inventory. We develop options for combining PM residuals and NMA residuals (residual = measurement - prediction), using a hybrid of period-driven and data-driven hypothesis testing. The modified statistical tests canmore » be used on time series of NMA residuals (the NMA residual is the familiar material balance), or on a combination of PM and NMA residuals. The PM residuals can be generated on a fixed time schedule or as events occur.« less

  10. Demonstration Results From Greenhouse Heating with Liquified Wood

    SciTech Connect (OSTI)

    Steele, Philip; Parish, Don; Cooper, Jerome

    2011-07-01

    A boiler fuel known as Lignocellulosic Boiler Fuel (LBF) was developed at the Department of Forest Products, Mississippi State University for potential application for heating agricultural buildings. LBF was field tested to heat green houses in cooperation with Natchez Trace Greenhouses (NTG) located in Kosciusko, Mississippi. MSU modified an idled natural gas boiler located at NTG to combust the LBF. Thirty gallons of bio-oil were produced at the MSU Bio-oil Research Laboratory. The bio-oil was produced from the fast-pyrolysis of southern pine (15 gal) and white oak (15 gal) feedstocks and subsequently upgraded by a proprietary process. Preliminary field testing was conducted at (NTG). The LBF was produced from each wood species was tested separately and co-fed with diesel fuel to yield three fuel formulations: (1) 100% diesel; (2) 87.5% LBF from southern pine bio-oil co-fed with 12.5% diesel and (3) 87.5% LBF from white oak co-fed with 12.5% diesel fuel formulations. Each fuel formulation was combusted in a retrofit NTG boiler. Fuel consumption and water temperature were measured periodically. Flue gas from the boiler was analyzed by gas chromatograph. The 100% diesel fuel increased water temperature at a rate of 4 °F per min. for 35 min. to achieve the target 140 °F water temperature increase. The 87.5% pine LBF fuel cofed with 12.5%) diesel attained the 140 °F water temperature increase in 62 min. at a rate of 2.3 °F per min. The 87.5% white oak LBF fuel co-fed with 12.5% diesel reached the 140 °F water temperature increase in 85 min. at a rate of 1.6 °F per min. Fuel that contained 87.5% pine LBF co-fed with 12.5% diesel yielded nitrogen and oxygen at a ratio of 5.3 and carbon dioxide and carbon monoxide at a ratio of 22.2. Fuel formulations that contained 87.5% white oak LBF co-fed with 12.5% diesel yielded nitrogen and oxygen at a ratio of 4.9 and carbon dioxide and

  11. Upgrading petroleum residues and heavy oils

    SciTech Connect (OSTI)

    Gray, M.R.

    1994-01-01

    Here is an in-depth look at current techniques for converting heavy oils and residues into more valuable distillates. It examines the chemistry of heavy hydrocarbon feeds and their properties which are important to engineering design, including phase behavior, reaction kinetics, and thermodynamic and transport characteristics.

  12. End-of-life vehicle recycling : state of the art of resource recovery from shredder residue.

    SciTech Connect (OSTI)

    Jody, B. J.; Daniels, E. J.; Duranceau, C. M.; Pomykala, J. A.; Spangenberger, J. S.

    2011-02-22

    Each year, more than 25 million vehicles reach the end of their service life throughout the world, and this number is rising rapidly because the number of vehicles on the roads is rapidly increasing. In the United States, more than 95% of the 10-15 million scrapped vehicles annually enter a comprehensive recycling infrastructure that includes auto parts recyclers/dismantlers, remanufacturers, and material recyclers (shredders). Today, over 75% of automotive materials, primarily the metals, are profitably recycled via (1) parts reuse and parts and components remanufacturing and (2) ultimately by the scrap processing (shredding) industry. The process by which the scrap processors recover metal scrap from automobiles involves shredding the obsolete automobile hulks, along with other obsolete metal-containing products (such as white goods, industrial scrap, and demolition debris), and recovering the metals from the shredded material. The single largest source of recycled ferrous scrap for the iron and steel industry is obsolete automobiles. The non-metallic fraction that remains after the metals are recovered from the shredded materials - commonly called shredder residue - constitutes about 25% of the weight of the vehicle, and it is disposed of in landfills. This practice is not environmentally friendly, wastes valuable resources, and may become uneconomical. Therefore, it is not sustainable. Over the past 15-20 years, a significant amount of research and development has been undertaken to enhance the recycle rate of end-of-life vehicles, including enhancing dismantling techniques and improving remanufacturing operations. However, most of the effort has been focused on developing technology to separate and recover non-metallic materials, such as polymers, from shredder residue. To make future vehicles more energy efficient, more lightweighting materials - primarily polymers, polymer composites, high-strength steels, and aluminum - will be used in manufacturing these

  13. Application of TDR technology to water content monitoring of capillary barriers made of pulp and paper residues

    SciTech Connect (OSTI)

    Cabral, A.R.; Burnotte, F.; Lefebvre, G.

    1999-03-01

    Acid mine drainage (AMD) can be curbed by covering tailings with capillary barriers. The purposes of these barriers is to prevent O{sub 2} from interacting with mine residues. This control can be made by keeping a high degree of moisture inside the cover material. Saturation is thus a key parameter to be monitored. The purpose of this paper is to present how the time domain reflectometry (TDR) technique can be used in order to monitor the volumetric water content for pulp and paper residues that have been used as capillary barriers. Calibration curves for deinking residues are presented and compared to literature data relating to mineral and organic soils.

  14. Evaluation of Gas, Oil and Wood Pellet Fueled Residential Heating System Emissions Characteristics

    SciTech Connect (OSTI)

    McDonald, R.

    2009-12-01

    particulate per unit of energy, expressed as milligrams per Mega-Joule (mg/MJ) versus the different sulfur contents of four different heating fuels. These were tested in a conventional cast iron boiler equipped with a flame retention head burner. The fuels included a typical ASTM No. 2 fuel oil with sulfur below 0.5 percent (1520 average ppm S), an ASTM No. 2 fuel oil with very high sulfur content (5780 ppm S), low sulfur heating oil (322 ppm S) and an ultra low sulfur diesel fuel (11 ppm S). Three additional oil-fired heating system types were also tested with normal heating fuel, low sulfur and ultralow sulfur fuel. They included an oil-fired warm air furnace of conventional design, a high efficiency condensing warm air furnace, a condensing hydronic boiler and the conventional hydronic boiler as discussed above. The linearity in the results was observed with all of the different oil-fired equipment types (as shown in the second figure on the next page). A linear regression of the data resulted in an Rsquared value of 0.99 indicating that a very good linear relationship exits. This means that as sulfur decreases the PM 2.5 emissions are reduced in a linear manner within the sulfur content range tested. At the ultra low sulfur level (15 ppm S) the amount of PM 2.5 had been reduced dramatically to an average of 0.043 mg/MJ. Three different gas-fired heating systems were tested. These included a conventional in-shot induced draft warm air furnace, an atmospheric fired hydronic boiler and a high efficiency hydronic boiler. The particulate (PM 2.5) measured ranged from 0.011 to 0.036 mg/MJ. depending on the raw material source used in their manufacture. All three stoves tested were fueled with premium (low ash) wood pellets obtained in a single batch to provide for uniformity in the test fuel. Unlike the oil and gas fired systems, the wood pellet stoves had measurable amounts of particulates sized above the 2.5-micron size that defines fine particulates (less than 2.5 microns

  15. Agenda 2020: A Technology Vision and Research Agenda for America's Forest, Wood and Paper Industry

    SciTech Connect (OSTI)

    none,

    1994-11-01

    In November 1994, the forest products industry published Agenda 2020: A Technology Vision and Research Agenda for America's Forest, Wood and Paper Industry, which articulated the industry's vision. This document set the foundation for collaborative efforts between the industry and the federal government.

  16. Review and analysis of emissions data for residential wood-fired central furnaces

    SciTech Connect (OSTI)

    McCrillis, R.C.

    1998-12-31

    The paper reviews data published over the past 10--15 years on domestic wood-fired central heaters. Emphasis is on stick-fired units, the most common type used in the US, but also presented are data on chip- and pellet-fired units, showing that they are capable of achieving lower emissions.

  17. Property:Building/SPPurchasedEngyPerAreaKwhM2WoodChips | Open...

    Open Energy Info (EERE)

    PerAreaKwhM2WoodChips" Showing 25 pages using this property. (previous 25) (next 25) S Sweden Building 05K0001 + 0.0 + Sweden Building 05K0002 + 0.0 + Sweden Building 05K0003 + 0.0...

  18. Property:Building/SPPurchasedEngyNrmlYrMwhYrWoodChips | Open...

    Open Energy Info (EERE)

    yNrmlYrMwhYrWoodChips" Showing 25 pages using this property. (previous 25) (next 25) S Sweden Building 05K0001 + 0.0 + Sweden Building 05K0002 + 0.0 + Sweden Building 05K0003 + 0.0...

  19. Property:Building/SPPurchasedEngyForPeriodMwhYrWoodChips | Open...

    Open Energy Info (EERE)

    rPeriodMwhYrWoodChips" Showing 25 pages using this property. (previous 25) (next 25) S Sweden Building 05K0001 + 0.0 + Sweden Building 05K0002 + 0.0 + Sweden Building 05K0003 + 0.0...

  20. Pennsylvanian and Permian paleogeography of south-central Idaho: The Wood River basin

    SciTech Connect (OSTI)

    Mahoney, J.B. ); Burton, B.R. ); O'Brien, J.P.; Link, P.K. )

    1991-02-01

    The Sun Valley Assemblage (Wood River, Dollarhide, and Grand Prize formations) was deposited in the Wood Rover basin in what is now south-central Idaho, north of the Snake River Plain, from the Atokan to Wolfcampian and Leonardian( ). Atokan and Des Moinesian deposition occurred in braided deltas and overlying clear water carbonate shoals. The rocks of this depositional system vary in thickness from tens to several hundreds of meters reflecting irregularities in the erosional surface on the underlying foundered Antler highland. This basal unconformity has been sheared during Mesozoic and Paleogene deformation. Significant regional subsidence of the Wood River basin began in the Des Moinesian, was most rapid in the Virgilian, and slowed in the Wolfcampian, resulting in total thickness of over 2,000 m for each of the three formations. In the central part of the basin (Wood River Formation) a sub-wave-base ramp system with southeastern paleoslope was fed by turbidite flows of mixed carbonate-siliciclastic fine-grained sediment that had been thoroughly mixed on a shelf area to the north and east. The carbonate fraction may have been derived from the Snaky Canyon Formation carbonate platform to the east. To the north, a siliciclastic fan or ramp system (Grand Prize Formation) was present. Virgilian and Wolfcampian strata represent highstand systems tracts and a lowstand tract is present in strata deposited near the Virgilian-Wolfcampian boundary.

  1. Reference Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reference Materials Reference Materials Large Scale Computing and Storage Requirements for Basic Energy Sciences February 9-10, 2010 Official DOE Invitation Workshop Invitation Letter from DOE Associate Directors Last edited: 2016-04-29 11:35:05

  2. Materials Characterization

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Materials Characterization Researchers in the Materials Characterization Research competency conduct studies of both natural and engineered materials from the micropore (nanometers) to macropore (meters) scale. Research includes, but is not limited to, thermal, chemical, mechanical, and structural (nano to macro) interactions and processes with regard to natural and engineered materials. The primary research investigation tools include SEM, XRD, micro XRD, core logging, medical CT, industrial

  3. Superfund Record of Decision (EPA Region 4): Coleman Evans Wood-Preserving site, Duval County, Jacksonville, Florida (first remedial action (amendment)). Final report, September 9, 1990

    SciTech Connect (OSTI)

    Not Available

    1990-09-26

    The 11-acre Coleman-Evans Wood Preserving site is a former wood treatment facility, which was operated from 1954 to the late 1980s, in the community of Whitehouse, Duval County, Florida. Prior to 1970, wastewater from the facility was precipated and discharged to the onsite drainage ditch. The precipitated sludge was deposited into two unlined pits until 1970, when the sludge was stored in tanks. The wastewater treatment process was also enhanced in 1970 with lime precipitation and chlorination. In 1980, onsite ground water contamination was detected and activated charcoal filters were added to the treatment process to remove organics. The primary contaminant in onsite soil and ground water has been identified as pentachlorophenol (PCP). The highest areas of PCP concentration were in the vicinity of onsite chemical tanks and the unlined pit areas. In 1985, EPA conducted an emergency response, which included excavating and disposing of pit material offsite and filling excavated areas with clean fill. The Record of Decision (ROD) amends a 1986 ROD, which documented the selection of incineration for an estimated 9,000 cubic yards of contaminated soil. Since that time, additional studies during the remedial design phase indicated that there are approximately 27,000 cubic yards of contaminated soil. Based on the excessive volume of soil and the high cost of incineration, treatability studies were conducted and an alternative source control treatment was selected. The primary contaminants of concern affecting the soil, sediment, and ground water are organics including PCP and metals.

  4. Effects of Headspace and Oxygen Level on Off-gas Emissions from Wood Pellets in Storage

    SciTech Connect (OSTI)

    Sokhansanj, Shahabaddine; Kuang, Xingya; Shankar, T.S.; Lim, C. Jim; Bi, X.T.; Melin, Staffan

    2009-10-01

    Few papers have been published in the open literature on the emissions from biomass fuels, including wood pellets, during the storage and transportation and their potential health impacts. The purpose of this study is to provide data on the concentrations, emission factors, and emission rate factors of CO2, CO, and CH4 from wood pellets stored with different headspace to container volume ratios with different initial oxygen levels, in order to develop methods to reduce the toxic off-gas emissions and accumulation in storage spaces. Metal containers (45 l, 305 mm diameter by 610 mm long) were used to study the effect of headspace and oxygen levels on the off-gas emissions from wood pellets. Concentrations of CO2, CO, and CH4 in the headspace were measured using a gas chromatograph as a function of storage time. The results showed that the ratio of the headspace ratios and initial oxygen levels in the storage space significantly affected the off-gas emissions from wood pellets stored in a sealed container. Higher peak emission factors and higher emission rates are associated with higher headspace ratios. Lower emissions of CO2 and CO were generated at room temperature under lower oxygen levels, whereas CH4 emission is insensitive to the oxygen level. Replacing oxygen with inert gases in the storage space is thus a potentially effective method to reduce the biomass degradation and toxic off-gas emissions. The proper ventilation of the storage space can also be used to maintain a high oxygen level and low concentrations of toxic off-gassing compounds in the storage space, which is especially useful during the loading and unloading operations to control the hazards associated with the storage and transportation of wood pellets.

  5. Minnesota wood energy scale-up project 1994 establishment cost data

    SciTech Connect (OSTI)

    Downing, M.; Pierce, R.; Kroll, T.

    1996-03-18

    The Minnesota Wood Energy Scale-up Project began in late 1993 with the first trees planted in the spring of 1994. The purpose of the project is to track and monitor economic costs of planting, maintaining and monitoring larger scale commercial plantings. For 15 years, smaller scale research plantings of hybrid poplar have been used to screen for promising, high-yielding poplar clones. In this project 1000 acres of hybrid poplar trees were planted on Conservation Reserve Program (CRP) land near Alexandria, Minnesota in 1994. The fourteen landowners involved re-contracted with the CRP for five-year extensions of their existing 10-year contracts. These extended contracts will expire in 2001, when the plantings are 7 years old. The end use for the trees planted in the Minnesota Wood Energy Scale-up Project is undetermined. They will belong to the owner of the land on which they are planted. There are no current contracts in place for the wood these trees are projected to supply. The structure of the wood industry in the Minnesota has changed drastically over the past 5 years. Stumpage values for fiber have risen to more than $20 per cord in some areas raising the possibility that these trees could be used for fiber rather than energy. Several legislative mandates have forced the State of Minnesota to pursue renewable energy including biomass energy. These mandates, a potential need for an additional 1700 MW of power by 2008 by Northern States Power, and agricultural policies will all affect development of energy markets for wood produced much like agricultural crops. There has been a tremendous amount of local and international interest in the project. Contractual negotiations between area landowners, the CRP, a local Resource Conservation and Development District, the Minnesota Department of Natural Resources and others are currently underway for additional planting of 1000 acres in spring 1995.

  6. Remote Automatic Material On-Line Sensor

    SciTech Connect (OSTI)

    Magnuson, Erik

    2005-12-20

    Low cost NMR sensor for measuring moisture content of forest products. The Department of Energy (DOE) Industries of the Future (IOF) program seeks development and implementation of technologies that make industry more efficient--in particular, more energy-efficient. Quantum Magnetics, Inc. (QM), a wholly-owned subsidiary of GE Security, received an award under the program to investigate roles for low-cost Nuclear Magnetic Resonance (NMR) technology in furtherance of these goals. Most NMR systems are designed for high-resolution spectroscopy applications. These systems use intense magnetic fields produced by superconducting magnets that drive price and operating cost to levels beyond industry tolerance. At low magnetic fields, achievable at low cost, one loses the ability to obtain spectroscopic information. However, measuring the time constants associated with the NMR signal, called NMR relaxometry, gives indications of chemical and physical states of interest to process control and optimization. It was the purpose of this effort to investigate the technical and economic feasibility of using such low-field, low-cost NMR to monitor parameters enabling greater process efficiencies. The primary target industry identified in the Cooperative Development Agreement was the wood industry, where the moisture content of wood is a key process parameter from the time the cut tree enters a mill until the time it is delivered as pieces of lumber. Extracting the moisture is energy consuming, and improvements in drying efficiency stand to reduce costs and emissions substantially. QM designed and developed a new, low-cost NMR instrument suitable for inspecting lumber up to 3 inches by 12 inches in cross section, and other materials of similar size. Low cost is achieved via an inexpensive, permanent magnet and low-cost NMR spectrometer electronics. Laboratory testing demonstrated that the NMR system is capable of accurate ({+-} 0.5%) measurements of the moisture content of wood for

  7. Ferns and fires: Experimental charring of ferns compared to wood and implications for paleobiology, paleoecology, coal petrology, and isotope geochemistry

    SciTech Connect (OSTI)

    McParland, L.C.; Collinson, M.E.; Scott, A.C.; Steart, D.C.; Grassineau, N.V.; Gibbons, S.J.

    2007-09-15

    We report the effects of charring on the ferns Osmunda, Pteridium, and Matteucia with coniferous wood (Sequoia) for comparison. Like charred wood, charred ferns shrink, become black and brittle with a silky sheen, and retain three-dimensional cellular structure. Ferns yield recognizable charcoal (up to 800{sup o}C) that could potentially survive in the fossil record enabling reconstruction of ancient fire-prone vegetation containing ferns. Charred fossils of herbaceous ferns would indicate surface fires. Like charred wood, cell-wall layers of charred ferns homogenize, and their reflectance values increase with rising temperature. Charcoalified fragments of thick-walled cells from conifer wood or fern tissues are indistinguishable and so cannot be used to infer the nature of source vegetation. Charred conifer wood and charred fern tissues show a relationship between mean random reflectance and temperature of formation and can be used to determine minimum ancient fire temperatures. Charred fern tissues consistently have significantly more depleted {delta}{sup 13}C values ({le} 4 parts per thousand) than charred wood. Therefore, if an analysis of {delta} {sup 13}C through time included fern charcoal among a succession of wood charcoals, any related shifts in {delta} {sup 13}C could be misinterpreted as atmospheric changes or misused as isotope stratigraphic markers. Thus, charcoals of comparable botanical origin and temperatures of formation should be used in order to avoid misinterpretations of shifts in {delta}{sup 13}C values.

  8. Residential Energy Efficiency Tax Credit | Department of Energy

    Energy Savers [EERE]

    ... basis, including agricultural crops and trees, wood and wood waste and residues (including wood pellets), plants (including aquatic plants), grasses, residues, and fibers". ...

  9. Residual Viremia in Treated HIV+ Individuals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Conway, Jessica M.; Perelson, Alan S.

    2016-01-06

    Antiretroviral therapy (ART) effectively controls HIV infection, suppressing HIV viral loads. However, some residual virus remains, below the level of detection, in HIV-infected patients on ART. Furthermore, the source of this viremia is an area of debate: does it derive primarily from activation of infected cells in the latent reservoir, or from ongoing viral replication? Our observations seem to be contradictory: there is evidence of short term evolution, implying that there must be ongoing viral replication, and viral strains should thus evolve. The phylogenetic analyses, and rare emergent drug resistance, suggest no long-term viral evolution, implying that virus derived frommore » activated latent cells must dominate. We use simple deterministic and stochastic models to gain insight into residual viremia dynamics in HIV-infected patients. Our modeling relies on two underlying assumptions for patients on suppressive ART: that latent cell activation drives viral dynamics and that the reproductive ratio of treated infection is less than 1. Nonetheless, the contribution of viral replication to residual viremia in patients on ART may be non-negligible. However, even if the portion of viremia attributable to viral replication is significant, our model predicts (1) that latent reservoir re-seeding remains negligible, and (2) some short-term viral evolution is permitted, but long-term evolution can still be limited: stochastic analysis of our model shows that de novo emergence of drug resistance is rare. Thus, our simple models reconcile the seemingly contradictory observations on residual viremia and, with relatively few parameters, recapitulates HIV viral dynamics observed in patients on suppressive therapy.« less

  10. Residual Viremia in Treated HIV+ Individuals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Conway, Jessica M.; Perelson, Alan S.

    2016-01-06

    Antiretroviral therapy (ART) effectively controls HIV infection, suppressing HIV viral loads. However, some residual virus remains, below the level of detection, in HIV-infected patients on ART. Furthermore, the source of this viremia is an area of debate: does it derive primarily from activation of infected cells in the latent reservoir, or from ongoing viral replication? Our observations seem to be contradictory: there is evidence of short term evolution, implying that there must be ongoing viral replication, and viral strains should thus evolve. The phylogenetic analyses, and rare emergent drug resistance, suggest no long-term viral evolution, implying that virus derived frommore »activated latent cells must dominate. We use simple deterministic and stochastic models to gain insight into residual viremia dynamics in HIV-infected patients. Our modeling relies on two underlying assumptions for patients on suppressive ART: that latent cell activation drives viral dynamics and that the reproductive ratio of treated infection is less than 1. Nonetheless, the contribution of viral replication to residual viremia in patients on ART may be non-negligible. However, even if the portion of viremia attributable to viral replication is significant, our model predicts (1) that latent reservoir re-seeding remains negligible, and (2) some short-term viral evolution is permitted, but long-term evolution can still be limited: stochastic analysis of our model shows that de novo emergence of drug resistance is rare. Thus, our simple models reconcile the seemingly contradictory observations on residual viremia and, with relatively few parameters, recapitulates HIV viral dynamics observed in patients on suppressive therapy.« less

  11. Materials Physics | Materials Science | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Physics A photo of laser light rays going in various directions atop a corrugated metal substrate In materials physics, NREL focuses on realizing materials that transcend the present constraints of photovoltaic (PV) and solid-state lighting technologies. Through materials growth and characterization, coupled with theoretical modeling, we seek to understand and control fundamental electronic and optical processes in semiconductors. Capabilities Optimizing New Materials An illustration showing

  12. Thin layer chromatography residue applicator sampler

    DOE Patents [OSTI]

    Nunes, Peter J.; Kelly, Fredrick R.; Haas, Jeffrey S.; Andresen, Brian D.

    2007-07-24

    A thin layer chromatograph residue applicator sampler. The residue applicator sampler provides for rapid analysis of samples containing high explosives, chemical warfare, and other analyses of interest under field conditions. This satisfied the need for a field-deployable, small, hand-held, all-in-one device for efficient sampling, sample dissolution, and sample application to an analytical technique. The residue applicator sampler includes a sampling sponge that is resistant to most chemicals and is fastened via a plastic handle in a hermetically sealed tube containing a known amount of solvent. Upon use, the wetted sponge is removed from the sealed tube and used as a swiping device across an environmental sample. The sponge is then replaced in the hermetically sealed tube where the sample remains contained and dissolved in the solvent. A small pipette tip is removably contained in the hermetically sealed tube. The sponge is removed and placed into the pipette tip where a squeezing-out of the dissolved sample from the sponge into the pipette tip results in a droplet captured in a vial for later instrumental analysis, or applied directly to a thin layer chromatography plate for immediate analysis.

  13. Conversion of forest residues to a methane-rich gas in a high-throughput gasifier

    SciTech Connect (OSTI)

    Feldmann, H.F.; Paisley, M.A.; Appelbaum, H.R.; Taylor, D.R.

    1988-05-01

    Research was conducted in a process research unit to develop an entrained bed gasifier which is supplied heat by recirculating a stream of sand between a separate combustion vessel and the gasifier. The char remaining after gasification of the wood provides the fuel for the combustor. The research program was conducted in two phases. In the first phase, a 6 in. I.D. gasifier was used to establish the feasibility of the concept for a wide variety of biomass feeds. The second phase of the program was conducted with a 10 in. I.D. gasifier, and a fully automated feeder system, to evaluate gasifier performance at very high feed rates. The experimental results were used to develop design parameters and detailed energy and material balances for a conceptual plant. A preliminary cost analysis is presented in the report based on the conceptual design. 5 refs., 24 figs., 13 tabs.

  14. Pyrolysis of carbonaceous materials with solvent quench recovery

    DOE Patents [OSTI]

    Green, Norman W.; Duraiswamy, Kandaswamy; Lumpkin, Robert E.; Knell, Everett W.; Mirza, Zia I.; Winter, Bruce L.

    1978-04-18

    In a continuous process for recovery of values contained in a solid carbonaceous material, the carbonaceous material is comminuted and then subjected to flash pyrolysis in the presence of a particulate heat source to form a pyrolysis product stream containing a carbon containing solid residue and volatilized hydrocarbons. After the carbon containing solid residue is separated from the pyrolysis product stream, values are obtained by condensing volatilized hydrocarbons. The particulate source of heat is formed by oxidizing carbon in the solid residue. Apparatus useful for practicing this process are disclosed.

  15. Use of a region of the visible and near infrared spectrum to predict mechanical properties of wet wood and standing trees

    DOE Patents [OSTI]

    Meglen, Robert R.; Kelley, Stephen S.

    2003-01-01

    In a method for determining the dry mechanical strength for a green wood, the improvement comprising: (a) illuminating a surface of the wood to be determined with a reduced range of wavelengths in the VIS-NIR spectra 400 to 1150 nm, said wood having a green moisture content; (b) analyzing the surface of the wood using a spectrometric method, the method generating a first spectral data of a reduced range of wavelengths in VIS-NIR spectra; and (c) using a multivariate analysis technique to predict the mechanical strength of green wood when dry by comparing the first spectral data with a calibration model, the calibration model comprising a second spectrometric method of spectral data of a reduced range of wavelengths in VIS-NIR spectra obtained from a reference wood having a green moisture content, the second spectral being correlated with a known mechanical strength analytical result obtained from the reference wood when dried and a having a dry moisture content.

  16. ,"Residual Fuel Oil Sales to End Users Refiner Sales Volumes...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Residual Fuel Oil Sales to End Users Refiner Sales ... "Back to Contents","Data 1: Residual Fuel Oil Sales to End Users Refiner Sales Volumes" ...

  17. ,"U.S. Residual Fuel Oil Refiner Sales Volumes"

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","U.S. Residual Fuel Oil Refiner Sales Volumes",2,"Monthly","5... "Back to Contents","Data 1: U.S. Residual Fuel Oil Refiner Sales Volumes" ...

  18. In-Situ Method for Treating Residual Sodium

    DOE Patents [OSTI]

    Sherman, Steven R.; Henslee, S. Paul

    2005-07-19

    A unique process for deactivating residual sodium in Liquid Metal Fast Breeder Reactor (LMFBR) systems which uses humidified (but not saturated) carbon dioxide at ambient temperature and pressure to convert residual sodium into solid sodium bicarbonate.

  19. In-situ method for treating residual sodium

    DOE Patents [OSTI]

    Sherman, Steven R. (Idaho Falls, ID); Henslee, S. Paul (Idaho Falls, ID)

    2005-07-19

    A unique process for deactivating residual sodium in Liquid Metal Fast Breeder Reactor (LMFBR) systems which uses humidified (but not saturated) carbon dioxide at ambient temperature and pressure to convert residual sodium into solid sodium bicarbonate.

  20. Scintillator material

    DOE Patents [OSTI]

    Anderson, D.F.; Kross, B.J.

    1992-07-28

    An improved scintillator material comprising cerium fluoride is disclosed. Cerium fluoride has been found to provide a balance of good stopping power, high light yield and short decay constant that is superior to known scintillator materials such as thallium-doped sodium iodide, barium fluoride and bismuth germanate. As a result, cerium fluoride is favorably suited for use as a scintillator material in positron emission tomography. 4 figs.

  1. Scintillator material

    DOE Patents [OSTI]

    Anderson, D.F.; Kross, B.J.

    1994-06-07

    An improved scintillator material comprising cerium fluoride is disclosed. Cerium fluoride has been found to provide a balance of good stopping power, high light yield and short decay constant that is superior to known scintillator materials such as thallium-doped sodium iodide, barium fluoride and bismuth germanate. As a result, cerium fluoride is favorably suited for use as a scintillator material in positron emission tomography. 4 figs.

  2. Scintillator material

    DOE Patents [OSTI]

    Anderson, David F.; Kross, Brian J.

    1992-01-01

    An improved scintillator material comprising cerium fluoride is disclosed. Cerium fluoride has been found to provide a balance of good stopping power, high light yield and short decay constant that is superior to known scintillator materials such as thallium-doped sodium iodide, barium fluoride and bismuth germanate. As a result, cerium fluoride is favorably suited for use as a scintillator material in positron emission tomography.

  3. Scintillator material

    DOE Patents [OSTI]

    Anderson, David F.; Kross, Brian J.

    1994-01-01

    An improved scintillator material comprising cerium fluoride is disclosed. Cerium fluoride has been found to provide a balance of good stopping power, high light yield and short decay constant that is superior to known scintillator materials such as thallium-doped sodium iodide, barium fluoride and bismuth germanate. As a result, cerium fluoride is favorably suited for use as a scintillator material in positron emission tomography.

  4. material recovery

    National Nuclear Security Administration (NNSA)

    dispose of dangerous nuclear and radiological material, and detect and control the proliferation of related WMD technology and expertise.

  5. Functional Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Testing of materials under ideal and realistic process conditions such as those found in coal-fired power plant and integrated gasification combined cycle fuel gas. Performance ...

  6. Comminution process to produce engineered wood particles of uniform size and shape with disrupted grain structure from veneer

    DOE Patents [OSTI]

    Dooley, James H; Lanning, David N

    2013-07-30

    Comminution process of wood veneer to produce wood particles, by feeding wood veneer in a direction of travel substantially normal to grain through a counter rotating pair of intermeshing arrays of cutting discs arrayed axially perpendicular to the direction of veneer travel, wherein the cutting discs have a uniform thickness (Td), to produce wood particles characterized by a length dimension (L) substantially equal to the Td and aligned substantially parallel to grain, a width dimension (W) normal to L and aligned cross grain, and a height dimension (H) substantially equal to the veneer thickness (Tv) and aligned normal to W and L, wherein the W.times.H dimensions define a pair of substantially parallel end surfaces with end checking between crosscut fibers.

  7. Wood-Producing Sunflower? Mining Genetic Diversity in Desert-Dwelling Wild Species (2010 JGI User Meeting)

    ScienceCinema (OSTI)

    Knapp, Steve

    2011-04-26

    Steve Knapp from Monsanto on "Wood-Producing Sunflower? Mining Genetic Diversity in Desert-Dwelling Wild Species" on March 25, 2010 at the 5th Annual DOE JGI User Meeting

  8. Reference Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reference Materials Reference Materials Large Scale Computing and Storage Requirements for Advanced Scientific Computing Research January 5-6, 2011 Official DOE Invitation Workshop Invitation Letter from DOE Associate Directors NERSC Documents NERSC science requirements home page NERSC science requirements workshop page NERSC science requirements case study FAQ Previous NERSC Requirements Workshops Biological and Environmental Research (BER) Basic Energy Sciences (BES) Fusion Energy Sciences

  9. Reference Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reference Materials Reference Materials Large Scale Computing and Storage Requirements for Biological and Environmental Research May 7-8, 2009 Invitation Workshop Invitation Letter from DOE Associate Directors Workshop Invitation Letter from DOE ASCR Program Manager Yukiko Sekine Last edited: 2016-04-29 11:34:54

  10. Cermet materials

    DOE Patents [OSTI]

    Kong, Peter C.

    2008-12-23

    A self-cleaning porous cermet material, filter and system utilizing the same may be used in filtering particulate and gaseous pollutants from internal combustion engines having intermetallic and ceramic phases. The porous cermet filter may be made from a transition metal aluminide phase and an alumina phase. Filler materials may be added to increase the porosity or tailor the catalytic properties of the cermet material. Additionally, the cermet material may be reinforced with fibers or screens. The porous filter may also be electrically conductive so that a current may be passed therethrough to heat the filter during use. Further, a heating element may be incorporated into the porous cermet filter during manufacture. This heating element can be coated with a ceramic material to electrically insulate the heating element. An external heating element may also be provided to heat the cermet filter during use.

  11. Composite material

    DOE Patents [OSTI]

    Hutchens, Stacy A.; Woodward, Jonathan; Evans, Barbara R.; O'Neill, Hugh M.

    2012-02-07

    A composite biocompatible hydrogel material includes a porous polymer matrix, the polymer matrix including a plurality of pores and providing a Young's modulus of at least 10 GPa. A calcium comprising salt is disposed in at least some of the pores. The porous polymer matrix can comprise cellulose, including bacterial cellulose. The composite can be used as a bone graft material. A method of tissue repair within the body of animals includes the steps of providing a composite biocompatible hydrogel material including a porous polymer matrix, the polymer matrix including a plurality of pores and providing a Young's modulus of at least 10 GPa, and inserting the hydrogel material into cartilage or bone tissue of an animal, wherein the hydrogel material supports cell colonization in vitro for autologous cell seeding.

  12. Materials Discovery | Materials Science | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Discovery Images of red and yellow particles NREL's research in materials discovery serves as a foundation for technological progress in renewable energies. Our experimental activities in inorganic solid-state materials innovation span a broad range of technological readiness levels-from basic science through applied research to device development-relying on a high-throughput combinatorial materials science approach, followed by traditional targeted experiments. In addition, our researchers work

  13. Thermal Properties of Wood-Derived Copper-Silicon Carbide Compsites Fabricated Via Electrodeposition

    SciTech Connect (OSTI)

    Pappacena, Kristen E; Johnson, M. T.; Wang, Hsin; Porter, Wallace D; Faber, K. T.

    2010-01-01

    Copper-silicon carbide composites were fabricated by electrodeposition of copper into pores of wood-derived silicon carbide, a ceramic with a microstructure that can be tailored via the use of different wood precursors. Thermal conductivity values were determined using flash diffusivity at temperatures from 0 to 900 C. Thermal conductivities of up to 202 W/m K at 0 C and 148 W/mK at 900 C were achieved. Object-oriented finite-element analysis (OOF) modeling was used to understand the heat flux distributions throughout the microstructures. OOF was also used to calculate the effective thermal conductivity, which correlated well with experimentally-determined values for axially-oriented composites. In addition, OOF was used to predict effective conductivity values and heat flux distributions for transversely-oriented composites.

  14. Treatment of plutonium process residues by molten salt oxidation

    SciTech Connect (OSTI)

    Stimmel, J.; Wishau, R.; Ramsey, K.B.; Montoya, A.; Brock, J.; Heslop, M.; Wernly, K.

    1999-04-01

    Molten Salt Oxidation (MSO) is a thermal process that can remove more than 99.999% of the organic matrix from combustible {sup 238}Pu material. Plutonium processing residues are injected into a molten salt bed with an excess of air. The salt (sodium carbonate) functions as a catalyst for the conversion of the organic material to carbon dioxide and water. Reactive species such as fluorine, chlorine, bromine, iodine, sulfur, phosphorous and arsenic in the organic waste react with the molten salt to form the corresponding neutralized salts, NaF, NaCl, NaBr, NaI, Na{sub 2}SO{sub 4}, Na{sub 3}PO{sub 4} and NaAsO{sub 2} or Na{sub 3}AsO4. Plutonium and other metals react with the molten salt and air to form metal salts or oxides. Saturated salt will be recycled and aqueous chemical separation will be used to recover the {sup 238}Pu. The Los Alamos National Laboratory system, which is currently in the conceptual design stage, will be scaled down from current systems for use inside a glovebox.

  15. Genetics of Wood Formation | U.S. DOE Office of Science (SC)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Genetics of Wood Formation Biological and Environmental Research (BER) BER Home About Research Facilities Science Highlights Searchable Archive of BER Highlights External link Benefits of BER Funding Opportunities Biological & Environmental Research Advisory Committee (BERAC) Community Resources Contact Information Biological and Environmental Research U.S. Department of Energy SC-23/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3251 F: (301) 903-5051 E:

  16. On-line measurement of lignin in wood pulp by color shift of fluorescence

    SciTech Connect (OSTI)

    Jeffers, Larry A.; Malito, Michael L.

    1996-01-01

    Lignin concentrations from wood pulp samples are measured by applying an excitation light at a selected wavelength to the samples in order to cause the lignin to emit fluorescence. A spectral distribution of the fluorescence emission is then determined. The lignin concentration is then calculated based on the spectral distribution signal. The spectral distribution is quantified by either a wavelength centroid method or a band ratio method.

  17. On-line measurement of lignin in wood pulp by color shift of fluorescence

    DOE Patents [OSTI]

    Jeffers, L.A.; Malito, M.L.

    1996-01-23

    Lignin concentrations from wood pulp samples are measured by applying an excitation light at a selected wavelength to the samples in order to cause the lignin to emit fluorescence. A spectral distribution of the fluorescence emission is then determined. The lignin concentration is then calculated based on the spectral distribution signal. The spectral distribution is quantified by either a wavelength centroid method or a band ratio method. 6 figs.

  18. Byggmeister Test Home. Analysis and Initial Results of Cold Climate Wood-Framed Home Retrofit

    SciTech Connect (OSTI)

    Gates, C.

    2013-01-01

    BSC seeks to further the energy efficiency market for New England area retrofit projects by supporting projects that are based on solid building science fundamentals that will benefit the homeowner through a combination of energy savings, improved durability, and occupant comfort. This report describes a deep retrofit project of a two-family wood-framed home in Belmont, Massachusetts, and examines the retrofit measures for the enclosure amd mechanical systems and reviews the decision-making process that took place during planning.

  19. Green Gasoline from Wood Using Carbona Gasification and Topsoe TIGAS Processes

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Green Gasoline from Wood Using Carbona Gasification and Topsoe TIGAS Processes March 24, 2015 Demonstration and Market Transformation Rick Knight Gas Technology Institute This presentation does not contain any proprietary, confidential, or otherwise restricted information Acronyms AGR Acid Gas Removal DME Dimethyl ether GTI Gas Technology Institute HGF Hot gas filter HTAS Haldor Topsoe A/S (Denmark) HTI Haldor Topsoe Inc. (Houston TX) TIGAS Topsoe Improved Gasoline Synthesis UHGF Ultra-hot gas

  20. New Methods for Investigating Wood Formation | U.S. DOE Office of Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (SC) New Methods for Investigating Wood Formation Biological and Environmental Research (BER) BER Home About Research Facilities Science Highlights Searchable Archive of BER Highlights External link Benefits of BER Funding Opportunities Biological & Environmental Research Advisory Committee (BERAC) Community Resources Contact Information Biological and Environmental Research U.S. Department of Energy SC-23/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301)

  1. Characterization of welding residual stresses with neutron diffraction

    SciTech Connect (OSTI)

    Wang, X.L.; Spooner, S.; Hubbard, C.R.; Taljat, B.; Feng, Z.

    1998-03-01

    Welding residual stresses are a key concern in the fabrication and use of structural components containing welds. Residual stresses in welds are caused by non-uniform expansion and shrinkage of differently heated zones during the thermal transient of a weld pass. In some alloys, solid state phase transformations occurring during the welding transient contribute additional residual stresses. Manufacturing problems arising from welding residual stresses include cracking and dimensional distortion. During use, tensile stresses in the welded zone limit the fatigue resistance of the component under cyclic loading. In an aggressive environment, tensile welding residual stresses also create a necessary condition for stress-corrosion cracking to take place.

  2. Chemical Characterization of Individual Particles and Residuals...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Chemical Characterization of Individual ... Collected On Board Research Aircraft in the ISDAC ... inorganic or black carbon cores coated by organic materials. ...

  3. Composites of Polystyrene/Wood Fiber, Processing Effect to Creep Resistance

    SciTech Connect (OSTI)

    Romero-Balderrama, L.; Mendoza-Duarte, M. E.; Flores-Gallardo, S. G.; Ibarra-Gomez, R. [Centro de Investigacion en Materiales Avanzados. Miguel de Cervantes 120, Complejo Industrial Chihuahua, 31109. Chihuahua, Chih. (Mexico); Gaspar-Rosas, A. [TA Instruments-Waters LLC. 109 Lukens Drive New Castle, DE 19720 (United States)

    2008-07-07

    In the present work, PS/wood fiber composites were studied in relation to their creep response as to be affected by the incorporation of a silane type coupling agent. Two elaboration variables were also considered in the experiments: wood fiber content and type of composites processing (compression, extrusion and injection molding). A series of weight ratios PS/wood fiber, with and without coupling agent, were prepared, 90/10, 80/20, 70/30 and 60/40. For the compatibilized series, 1% wt of silane coupling agent in relation to the polystyrene weight was employed. The creep tests were performed inside the lineal viscoelastic region at 80 deg. C. A general improvement of the creep resistance for the compatibilized composites was observed independently of the elaboration process. However, the injection molded samples showed by far the lowest deformation with time. This behavior suggests that the high orientation of the fibers generated by the injection molding process, in relation to the extrusion and compression molding, promotes a higher superficial area of treated fiber to be in contact with the PS matrix, which enhances the adhesion and in consequence the resistance to creep.

  4. Mathematical model of steam drying of wood chips and other hygroscopic porous media

    SciTech Connect (OSTI)

    Fyhr, C.; Rasmuson, A.

    1996-09-01

    A model is presented that is focused on the drying kinetics of single wood chips as a function of time and external conditions, such as temperature, pressure and velocity of the superheated steam. A multiphase and 2-D approach was used to model the coupled transport of water, vapor, air and heat in anisotropic hygroscopic porous media. The model was verified by drying experiments where measurements of the average moisture content, center temperature and pressure in a single wood chip could be performed simultaneously. A comparison between the calculations and the measurements showed that the drying behavior was well predicted. The drying can be divided into three stages: a heat-up period when condensation on the surface initially increases the moisture content; a period of constant drying rate when the external heat transfer controls the drying rate; and a period of decreasing drying rate when the drying is controlled by internal mass transfer. Many interesting features of the drying could be assigned to the strong anisotropicity of wood, which makes a 2-D model necessary.

  5. Influence of corn steep liquor and glucose on colonization of control and CCB (Cu/Cr/B)-treated wood by brown rot fungi

    SciTech Connect (OSTI)

    Humar, Miha; Pohleven, Franc

    2006-07-01

    There are increasing problems with regard to the disposal of treated wood waste. Due to heavy metals or arsenic in impregnated wood waste, burning and landfill disposal options are not considered to be environmentally friendly solutions for dealing with this problem. Extraction of the heavy metals and recycling of the preservatives from the wood waste is a much more promising and environmentally friendly solution. In order to study the scale up of this process, copper/chromium/boron-treated wood specimens were exposed to copper tolerant (Antrodia vaillantii and Leucogyrophana pinastri) and copper sensitive wood decay fungi (Gloeophyllum trabeum and Poria monticola). Afterwards, the ability of fungal hyphae to penetrate and overgrow the wood specimens was investigated. The fungal growths were stimulated by immersing the specimens into aqueous solution of glucose or corn steep liquor prior to exposure to the fungi. The fastest colonization of the impregnated wood was by the copper tolerant A. vaillantii. Addition of glucose onto the surface of the wood specimens increased the fungi colonization of the specimens; however, immersion of the specimens into the solution of corn steep liquor did not have the same positive influence. These results are important in elucidating copper toxicity in wood decay fungi and for using these fungi for bioremediation of treated wood wastes.

  6. Complex Materials

    ScienceCinema (OSTI)

    Cooper, Valentino

    2014-05-23

    Valentino Cooper uses some of the world's most powerful computing to understand how materials work at subatomic levels, studying breakthroughs such as piezoelectrics, which convert mechanical stress to electrical energy.

  7. material removal

    National Nuclear Security Administration (NNSA)

    %2A en Nuclear Material Removal http:nnsa.energy.govaboutusourprogramsdnnm3remove

    Page...

  8. material removal

    National Nuclear Security Administration (NNSA)

    %2A en Nuclear Material Removal http:www.nnsa.energy.govaboutusourprogramsdnnm3remove

    Pag...

  9. Propulsion materials

    SciTech Connect (OSTI)

    Wall, Edward J.; Sullivan, Rogelio A.; Gibbs, Jerry L.

    2008-01-01

    The Department of Energy’s (DOE’s) Office of Vehicle Technologies (OVT) is pleased to introduce the FY 2007 Annual Progress Report for the Propulsion Materials Research and Development Program. Together with DOE national laboratories and in partnership with private industry and universities across the United States, the program continues to engage in research and development (R&D) that provides enabling materials technology for fuel-efficient and environmentally friendly commercial and passenger vehicles.

  10. Reference Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reference Materials Reference Materials Large Scale Computing and Storage Requirements for Fusion Energy Sciences August 3-4, 2010 Official DOE Invitation Workshop Invitation Letter from DOE Associate Directors [not available] NERSC Documents NERSC science requirements home page NERSC science requirements workshop page NERSC science requirements case study FAQ Workshop Agenda Previous NERSC Requirements Workshops Biological and Environmental Research (BER) Basic Energy Sciences (BES) Fusion

  11. Reference Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reference Materials Reference Materials Large Scale Computing and Storage Requirements for High Energy Physics November 12-13, 2009 Official DOE Invitation Workshop Invitation Letter from DOE Associate Directors NERSC Documents NERSC science requirements home page NERSC science requirements workshop page NERSC science requirements case study FAQ Workshop Agenda Previous NERSC Requirements Workshops Biological and Environmental Research (BER) Basic Energy Sciences (BES) Fusion Energy Sciences

  12. Engineered Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7 Engineered Materials Materials design, fabrication, assembly, and characterization for national security needs. Contact Us Group Leader (Acting) Kimberly Obrey Email Deputy Group Leader Dominic Peterson Email Group Office (505)-667-6887 We perform polymer science and engineering, including ultra-precision target design, fabrication, assembly, characterization, and field support. We perform polymer science and engineering, including ultra-precision target design, fabrication, assembly,

  13. Meeting Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    HEP Meeting Materials Meeting Materials Here you will find various items to be used before and during the requirements review. The following documents are included: Case study worksheet to be filled in by meeting participants Sample of a completed case study from a Nuclear Physics requirements workshop held in 2011 A graph of NERSC and HEP usage as a function of time A powerpoint template you can use at the requirements review Downloads CaseStudyTemplate.docx | unknown Case Study Worksheet -

  14. Thermal upgrading of residual oil to light product and heavy residual fuel

    SciTech Connect (OSTI)

    Yan, T.Y.; Shu, P.

    1986-08-05

    The method is described of upgrading residual oil boiling in the range of 1050/sup 0/F+ comprising: thermally cracking the residual oil at a temperature of 650/sup 0/-900/sup 0/F, a pressure of 0-100 psig, and a residence time of 0.1 to 5 hours at the highest severity in the range between about 1,000-18,000 seconds, as expressed in equivalent reaction time at 800/sup 0/F, sufficient to convert at least about 50 wt% of the residual oil to light products, substantially without the formation of solid coke; recovering separate fractions of light product and emulsifiable heavy bottom product which has a fusion temperature below about 150/sup 0/C and a quinoline-insoluble content between about 10 wt% and 30 wt% and wherein the highest severity is determined by a functional relationship between the asphaltene content of the residual oil feedstock and the heavy bottom product yield and quinoline-insoluble content.

  15. Auto shredder residue recycling: Mechanical separation and pyrolysis

    SciTech Connect (OSTI)

    Santini, Alessandro; Passarini, Fabrizio; Vassura, Ivano; Serrano, David; Dufour, Javier

    2012-05-15

    Highlights: Black-Right-Pointing-Pointer In this work, we exploited mechanical separation and pyrolysis to recycle ASR. Black-Right-Pointing-Pointer Pyrolysis of the floating organic fraction is promising in reaching ELV Directive targets. Black-Right-Pointing-Pointer Zeolite catalyst improve pyrolysis oil and gas yield. - Abstract: sets a goal of 85% material recycling from end-of-life vehicles (ELVs) by the end of 2015. The current ELV recycling rate is around 80%, while the remaining waste is called automotive shredder residue (ASR), or car fluff. In Europe, this is mainly landfilled because it is extremely heterogeneous and often polluted with car fluids. Despite technical difficulties, in the coming years it will be necessary to recover materials from car fluff in order to meet the ELV Directive requirement. This study deals with ASR pretreatment and pyrolysis, and aims to determine whether the ELV material recycling target may be achieved by car fluff mechanical separation followed by pyrolysis with a bench scale reactor. Results show that flotation followed by pyrolysis of the light, organic fraction may be a suitable ASR recycling technique if the oil can be further refined and used as a chemical. Moreover, metals are liberated during thermal cracking and can be easily separated from the pyrolysis char, amounting to roughly 5% in mass. Lastly, pyrolysis can be a good starting point from a 'waste-to-chemicals' perspective, but further research should be done with a focus on oil and gas refining, in order both to make products suitable for the chemical industry and to render the whole recycling process economically feasible.

  16. Metal recovery from porous materials

    DOE Patents [OSTI]

    Sturcken, E.F.

    1992-10-13

    A method is described for recovering plutonium and other metals from materials by leaching comprising the steps of incinerating the materials to form a porous matrix as the residue of incineration, immersing the matrix into acid in a microwave-transparent pressure vessel, sealing the pressure vessel, and applying microwaves so that the temperature and the pressure in the pressure vessel increase. The acid for recovering plutonium can be a mixture of HBF[sub 4] and HNO[sub 3] and preferably the pressure is increased to at least 100 PSI and the temperature to at least 200 C. The porous material can be pulverized before immersion to further increase the leach rate.

  17. Vacuum outgassing of various materials

    SciTech Connect (OSTI)

    Erikson, E.D.; Beat, T.G.; Berger, D.D.; Frazier, B.A.

    1984-04-01

    A gas analytical system for measuring the evolved gases from materials during vacuum degassing is discussed. The outgassing data are based upon the throughput measurement and a computer-controlled quadrupole mass spectrometer allows the determination of residual gas species. A variety of materials have been tested in the ''as-received'' condition at room temperature vacuum exposure. Test results are presented for materials such as chlorinated polyvinylchloride (CPVC), low density carbon foam and Monel knitted wire mesh (both of which could be used for the attenuation of electromagnetic or radio frequency interference), polyethylene (in the form of black pipe, sheet of various thicknesses, and as an electrostatically applied coating to metal substrates), as well as Parylene-N/sup X/ conformal coatings applied to CPVC, polyethylene, and stainless steel substrates.

  18. Vacuum outgassing of various materials

    SciTech Connect (OSTI)

    Erikson, E.D.; Beat, T.G.; Berger, D.D.; Frazier, B.A.

    1983-09-28

    A gas analytical system for measuring the evolved gases from materials during vacuum degassing is discussed. The outgassing data are based upon the throughput measurement and a computer-controlled quadrupole mass spectrometer allows the determination of residual gas species. A variety of materials have been tested in the as received condition at room-temperature vacuum exposure. Test results are presented for some unusual materials such as chlorinated polyvinyl chloride (CPVC), low-density carbon foam and Monel knitted wire mesh (both of which could be used for the attenuation of electromagnetic or radio frequency interference), polyethylene (in the form of black pipe, various thicknesses of sheet, or as an electrostatically applied coating to metal substrates), as well as Parylene-N conformal coatings applied to either CPVC, polyethylene, or stainless steel substrates.

  19. Vacuum outgassing of various materials

    SciTech Connect (OSTI)

    Erikson, E.D.; Beat, T.G.; Berger, D.D.; Frazier, B.A.

    1983-12-20

    A gas analytical system for measuring the evolved gases from materials during vacuum degassing is discussed. The outgassing data are based upon the throughput measurement and a computer-controlled quadrupole mass spectrometer allows the determination of residual gas species. A variety of materials have been tested in the as received condition at room temperature vacuum exposure. Test results are presented for materials such as chlorinated polyvinychloride (CPVC), low-density carbon foam and Monel knitted wire mesh (both of which could be used for the attenuation of electromagnetic or radio frequency interference), polyethylene (in the form of black pipe, sheet of various thicknesses, and as an electrostatically applied coating to metal substrates), as well as Parylene-N conformal coatings applied to CPVC, polyethylene, and stainless steel substrates.

  20. Minimal residual method stronger than polynomial preconditioning

    SciTech Connect (OSTI)

    Faber, V.; Joubert, W.; Knill, E.

    1994-12-31

    Two popular methods for solving symmetric and nonsymmetric systems of equations are the minimal residual method, implemented by algorithms such as GMRES, and polynomial preconditioning methods. In this study results are given on the convergence rates of these methods for various classes of matrices. It is shown that for some matrices, such as normal matrices, the convergence rates for GMRES and for the optimal polynomial preconditioning are the same, and for other matrices such as the upper triangular Toeplitz matrices, it is at least assured that if one method converges then the other must converge. On the other hand, it is shown that matrices exist for which restarted GMRES always converges but any polynomial preconditioning of corresponding degree makes no progress toward the solution for some initial error. The implications of these results for these and other iterative methods are discussed.

  1. Method For Characterizing Residual Stress In Metals

    DOE Patents [OSTI]

    Jacobson, Loren A.; Michel, David J.; Wyatt, Jeffrey R.

    2002-12-03

    A method is provided for measuring the residual stress in metals. The method includes the steps of drilling one or more holes in a metal workpiece to a preselected depth and mounting one or more acoustic sensors on the metal workpiece and connecting the sensors to an electronic detecting and recording device. A liquid metal capable of penetrating into the metal workpiece placed at the bottom of the hole or holes. A recording is made over a period of time (typically within about two hours) of the magnitude and number of noise events which occur as the liquid metal penetrates into the metal workpiece. The magnitude and number of noise events are then correlated to the internal stress in the region of the workpiece at the bottom of the hole.

  2. COMPARISON OF THE POPULATIONS OF COMMON WOOD-NYMPH BUTTERFLIES IN BURNED PRAIRIE, UNBURNED PRAIRIE AND OLD FIELD GRASSES

    SciTech Connect (OSTI)

    Hahn, M.; Walton, R.

    2007-01-01

    Common wood-nymph butterfl ies are found throughout the United States and Canada. However, not much is known about how they overwinter or their preferences for particular grasses and habitats. In this study, the impact of prairie management plans on the abundance of the wood-nymph population was assessed, as well as the preference of these butterfl ies for areas with native or non-native grasses. The abundance of common wood-nymph butterfl ies was determined using Pollard walks; more common wood-nymph butterfl ies were found in the European grasses than were found in the burned and unburned prairie sites. The majority of the vegetation at each of the three sites was identifi ed and documented. Using a 1 X 3 ANOVA analysis, it was determined there were signifi cantly more butterfl ies in the European grasses than in the burned and unburned prairie sites (p < 0.0005). There was no signifi cant difference between the burned and unburned treatments of the prairie on the common wood-nymph population. A multiple variable linear regression model described the effect of temperature and wind speed on the number of observed common wood-nymph butterfl ies per hour (p = 0.026). These preliminary results need to be supplemented with future studies. Quadrat analysis of the vegetation from all three sites should be done to search for a correlation between common wood-nymph butterfl y abundance per hour and the specifi c types or quantity of vegetation at each site. The effect of vegetation height and density on the observers visual fi eld should also be assessed.

  3. Integrating the stabilization of nuclear materials

    SciTech Connect (OSTI)

    Dalton, H.F.

    1996-05-01

    In response to Recommendation 94-1 of the Defense Nuclear Facilities Safety Board, the Department of Energy committed to stabilizing specific nuclear materials within 3 and 8 years. These efforts are underway. The Department has already repackaged the plutonium at Rocky Flats and metal turnings at Savannah River that had been in contact with plastic. As this effort proceeds, we begin to look at activities beyond stabilization and prepare for the final disposition of these materials. To describe the plutonium materials being stabilize, Figure 1 illustrates the quantities of plutonium in various forms that will be stabilized. Plutonium as metal comprises 8.5 metric tons. Plutonium oxide contains 5.5 metric tons of plutonium. Plutonium residues and solutions, together, contain 7 metric tons of plutonium. Figure 2 shows the quantity of plutonium-bearing material in these four categories. In this depiction, 200 metric tons of plutonium residues and 400 metric tons of solutions containing plutonium constitute most of the material in the stabilization program. So, it is not surprising that much of the work in stabilization is directed toward the residues and solutions, even though they contain less of the plutonium.

  4. Experimental determination of the residual stresses in a Kraft recovery boiler tube

    SciTech Connect (OSTI)

    Wang, Xun-Li; Payzant, E.A.; Taljat, B.

    1997-07-01

    Neutron diffraction was used to determine the residual stresses in a spiral weld overlay tube used in Kraft recovery boilers by the pulp and paper industry. The specimen was a 2.5 inches OD carbon steel tube covered with a layer of Inconel 625 weld overlay. Residual strains in the carbon steel and weld overlay layers were determined using the ferritic (211) and austenitic (311) reflections, respectively. Residual stresses in each material were derived from the measured strains using Hooke`s law and appropriate elastic constants. Tensile stress regions were found not only in the weld metal but also in the heat affected zone in the carbon steel. The maximum tensile stress was located in the weld overlay layer and was found to be 360 MPa, or about 75% of the yield strength of the weld metal. The experimental data were compared with a finite element analysis based on an uncoupled thermal-mechanical formulation. Overall, the modeling results were in satisfactory agreement with the experimental data, although the hoop strain (stress) appears to have been overestimated by the finite element model. Additional neutron diffraction measurements on an annealed tube confirmed that these welding residual stresses were eliminated after annealing at 900{degrees}C for 20 minutes. 18 refs., 7 figs.

  5. Hardfacing material

    DOE Patents [OSTI]

    Branagan, Daniel J.

    2012-01-17

    A method of producing a hard metallic material by forming a mixture containing at least 55% iron and at least one of boron, carbon, silicon and phosphorus. The mixture is formed into an alloy and cooled to form a metallic material having a hardness of greater than about 9.2 GPa. The invention includes a method of forming a wire by combining a metal strip and a powder. The metal strip and the powder are rolled to form a wire containing at least 55% iron and from two to seven additional elements including at least one of C, Si and B. The invention also includes a method of forming a hardened surface on a substrate by processing a solid mass to form a powder, applying the powder to a surface to form a layer containing metallic glass, and converting the glass to a crystalline material having a nanocrystalline grain size.

  6. Training Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Training Materials Training Materials The following tutorials are produced by NERSC staff and are intended to provide basic instruction on NERSC systems. Sort by: Default | Name | Date (low-high) | Date (high-low) | Source | Category Introduction to Hybrid OpenMP/MPI Programming June 24, 2004 | Author(s): Helen He | Download File: hybridTalk.pdf | pdf | 1005 KB sample managed list Using OpenMP October 20, 2010 | Author(s): Helen He | Introduction to MPI January 11, 2010 | Author(s): Richard

  7. Reference Material

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reference Materials There are a variety of reference materials the NSSAB utilizes and have been made available on its website. Documents Fact Sheets - links to Department of Energy Nevada Field Office webpage Public Reading Room NTA Public Reading Facility Open Monday through Friday, 7:30 am to 4:30 pm (except holidays) 755C East Flamingo Road Las Vegas, Nevada 89119 Phone (702) 794-5106 http://www.nv.doe.gov/library/testingarchive.aspx DOE Electronic Database Also available to the public is an

  8. Fracture mechanics applied to the machining of brittle materials

    SciTech Connect (OSTI)

    Hiatt, G.D.; Strenkowski, J.S.

    1988-12-01

    Research has begun on incorporating fracture mechanics into a model of the orthogonal cutting of brittle materials. Residual stresses are calculated for the machined material by a combination of Eulerian and Lagrangian finite element models and then used in the calculation of stress intensity factors by the Green`s Function Method.

  9. Methods for purifying carbon materials

    DOE Patents [OSTI]

    Dailly, Anne; Ahn, Channing; Yazami, Rachid; Fultz, Brent T.

    2009-05-26

    Methods of purifying samples are provided that are capable of removing carbonaceous and noncarbonaceous impurities from a sample containing a carbon material having a selected structure. Purification methods are provided for removing residual metal catalyst particles enclosed in multilayer carbonaceous impurities in samples generate by catalytic synthesis methods. Purification methods are provided wherein carbonaceous impurities in a sample are at least partially exfoliated, thereby facilitating subsequent removal of carbonaceous and noncarbonaceous impurities from the sample. Methods of purifying carbon nanotube-containing samples are provided wherein an intercalant is added to the sample and subsequently reacted with an exfoliation initiator to achieve exfoliation of carbonaceous impurities.

  10. Waste minimization for selected residuals in the petroleum refining industry

    SciTech Connect (OSTI)

    1996-12-01

    This technical report on residuals in the petroleum refining industry provides an industry overview, process description, and process flow diagrams. It presents residual descriptions for each of the 29 petroleum refining residuals of concern and what source reduction option exist. It reviews the data sources - RCRA Section 2007 surveys, site visits, and journal articles. It also describes major findings and evaluates the quantity and quality of waste minization information for each source.

  11. Critical Materials:

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Critical Materials: 1 Technology Assessment 2 Contents 3 1. Introduction to the Technology/System ............................................................................................... 2 4 2. Technology Assessment and Potential ................................................................................................. 5 5 2.1 Major Trends in Selected Clean Energy Application Areas ........................................................... 5 6 2.1.1 Permanent Magnets for Wind

  12. Differential Impact of [beta] and [gamma] Residue Preorganization...

    Office of Scientific and Technical Information (OSTI)

    Differential Impact of beta and gamma Residue Preorganization on alphabetagamma-Peptide Helix Stability in Water Citation Details In-Document Search Title: Differential ...

  13. Residual orientation in micro-injection molded parts

    SciTech Connect (OSTI)

    Healy, John; Edward, Graham H.; Knott, Robert B. (Monash); (ANSTO)

    2008-06-30

    The residual orientation following micro-injection molding of small rectangular plates with linear polyethylene has been examined using small-angle neutron scattering, and small- and wide-angle X-ray scattering. The effect of changing the molding conditions has been examined, and the residual chain orientation has been compared to the residual orientation of the crystallites as a function of position in the sample. This study has found that, for micromoldings, the orientation of the crystallites decreases with increasing injection speed and increasing mold thickness. The combined data suggest that the majority of the orientation present comes from oriented crystal growth rather than residual chain orientation.

  14. Wet Gasification of Ethanol Residue: A Preliminary Assessment

    SciTech Connect (OSTI)

    Brown, Michael D.; Elliott, Douglas C.

    2008-09-22

    A preliminary technoeconomic assessment has been made of several options for the application of catalytic hydrothermal gasification (wet gasification) to ethanol processing residues.

  15. Type Ia Supernova Hubble Residuals and Host-Galaxy Properties...

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Search Results Journal Article: Type Ia Supernova Hubble Residuals and ... as distinguished from previous works that use magnitude corrections as a ...

  16. Simulation of Distortion and Residual Stress Development During...

    Office of Scientific and Technical Information (OSTI)

    Simulation of Distortion and Residual Stress Development During Heat Treatment of Steel ... Available experimental steel casting heat treatment data was determined to be of ...

  17. Improvement of the management of residual waste in areas without...

    Office of Scientific and Technical Information (OSTI)

    management scenarios for residual waste were compared by life cycle assessment (LCA). ... On the contrary the quality of the recyclables extracted can significantly modify the eco ...

  18. Water dynamics clue to key residues in protein folding

    SciTech Connect (OSTI)

    Gao, Meng [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China)] [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China); Zhu, Huaiqiu, E-mail: hqzhu@pku.edu.cn [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China)] [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China); Yao, Xin-Qiu [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China) [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China); Department of Biophysics, Kyoto University, Sakyo Kyoto 606-8502 (Japan); She, Zhen-Su, E-mail: she@pku.edu.cn [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China)] [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China)

    2010-01-29

    A computational method independent of experimental protein structure information is proposed to recognize key residues in protein folding, from the study of hydration water dynamics. Based on all-atom molecular dynamics simulation, two key residues are recognized with distinct water dynamical behavior in a folding process of the Trp-cage protein. The identified key residues are shown to play an essential role in both 3D structure and hydrophobic-induced collapse. With observations on hydration water dynamics around key residues, a dynamical pathway of folding can be interpreted.

  19. Potential solubility controls for Iodine-129 in residual tank waste

    SciTech Connect (OSTI)

    Denham, M. E.

    2015-08-03

    This report documents a scoping analysis of possible controls on the release of 129I from tank 12H residual waste.

  20. ABSTRACT: Bioenergy Harvesting Technologies to Supply Crop Residues...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Integration of Advanced Logistical Systems and Focused Bioenergy Harvesting Technologies to Supply Crop Residues and Energy Crops in a Densified Large Square Bale Format OBP WBS: ...

  1. Overcoming residual stresses and machining distortion in the...

    Office of Scientific and Technical Information (OSTI)

    in the production of aluminum alloy satellite boxes. Citation Details In-Document Search Title: Overcoming residual stresses and machining distortion in the production of ...

  2. RESIDUAL STRESSES IN ADDITIVELY MANUFACTURED INCONEL 718 ENGINE...

    Office of Scientific and Technical Information (OSTI)

    Title: RESIDUAL STRESSES IN ADDITIVELY MANUFACTURED INCONEL 718 ENGINE MOUNT Authors: Watkins, Thomas R 1 ; Cornwell, Paris A 1 ; Dehoff, Ryan R 1 ; Nangia, Vinod 2 ; ...

  3. Status Report: Characterization of Weld Residual Stresses on...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Status Report: Characterization of Weld Residual Stresses on Full Diameter SNF Interim ... and results of initial stress (and stress corrosion cracking, SCC) characterization work. ...

  4. Comparison of residual stresses in Inconel 718 simple parts made...

    Office of Scientific and Technical Information (OSTI)

    SC USDOE - Office of Science (SC) Country of Publication: United States Language: English Subject: Inconel 718; residual stess; electron beam melting; direct laser metal ...

  5. Thermal Pretreatment of Wood for Cogasification/cofiring of Biomass and Coal

    SciTech Connect (OSTI)

    Wang, Ping; Howard, Bret; Hedges, Sheila; Morreale, Bryan; Van Essendelft, Dirk; Berry, David

    2013-10-29

    Utilization of biomass as a co-feed in coal and biomass co-firing and co-gasification requires size reduction of the biomass. Reducing biomass to below 0.2 mm without pretreatment is difficult and costly because biomass is fibrous and compressible. Torrefaction is a promising thermal pretreatment process and has the advantages of increasing energy density, improving grindability, producing fuels with more homogenous compositions and hydrophobic behavior. Temperature is the most important factor for the torrefaction process. Biomass grindability is related to cell wall structure, thickness and composition. Thermal treatment such as torrefaction can cause chemical changes that significantly affect the strength of biomass. The objectives of this study are to understand the mechanism by which torrefaction improves the grindability of biomass and discuss suitable temperatures for thermal pretreatment for co-gasification/cofiring of biomass and coal. Wild cherry wood was selected as the model for this study. Samples were prepared by sawing a single tangential section from the heartwood and cutting it into eleven pieces. The samples were consecutively heated at 220, 260, 300, 350, 450 and 550oC for 0.5 hr under flowing nitrogen in a tube furnace. Untreated and treated samples were characterized for physical properties (color, dimensions and weight), microstructural changes by SEM, and cell wall composition changes and thermal behaviors by TGA and DSC. The morphology of the wood remained intact through the treatment range but the cell walls were thinner. Thermal treatments were observed to decompose the cell wall components. Hemicellulose decomposed over the range of ~200 to 300oC and resulted in weakening of the cell walls and subsequently improved grindability. Furthermore, wood samples treated above 300oC lost more than 39% in mass. Therefore, thermal pretreatment above the hemicelluloses decomposition temperature but below 300oC is probably sufficient to improve

  6. Characterization of emissions from a fluidized-bed wood chip home heating furnace. Final report Apr 82-May 83

    SciTech Connect (OSTI)

    Truesdale, R.S.

    1984-03-01

    The report gives results of measurements of emissions from a residential wood-chip combustor, operated in both a fluidized-bed and cyclone-fired mode, and their comparison with those from a conventional woodstove and industrial wood-fired boilers. In general, the combustion efficiency of the fluidized-bed and cyclone-fired wood-chip burner is higher than that of conventional woodstoves. Concomitant with this increase in efficiency is a decrease in most emissions. For the fluidized-bed tests, significant reductions of total hydrocarbons and CO were observed, compared to woodstove emissions. The cyclone test showed PAH levels far below those of conventional woodstoves, approaching levels measured in industrial wood-fired boilers. A baghouse, installed during two fluidized-bed tests, was extremely effective in reducing both particulate and PAH emissions. Method 5 samples from above the fluid bed suggest that appreciable PAH is formed in the upper region of the furnace or in the watertube heat exchangers. In general, the cyclone-fired mode was more effective in reducing emissions from residential wood combustion than the fluidized-bed mode.

  7. Assessment of alternatives for long-term management of uranium ore residues and contaminated soils located at DOE's Niagara Falls Storage Site

    SciTech Connect (OSTI)

    Merry-Libby, P.

    1984-11-05

    About 11,000 m/sup 3/ of uranium ore residues and 180,000 m/sup 3/ of wastes (mostly slightly contaminated soils) are consolidated within a diked containment area at the Niagara Falls Storage Site (NFSS) located about 30 km north of Buffalo, NY. The residues account for less than 6% of the total volume of contaminated materials but almost 99% of the radioactivty. The average /sup 226/Ra concentration in the residues is 67,000 pCi/g. Several alternatives for long-term management of the wastes and residues are being considered, including: improvement of the containment at NFSS, modification of the form of the residues, management of the residues separately from the wastes, management of the wastes and residues at another humid site (Oak Ridge, TN) or arid site (Hanford, WA), and dispersal of the wastes in the ocean. Potential radiological risks are expected to be smaller than the nonradiological risks of occupational and transportation-related injuries and deaths. Dispersal of the slightly contaminated wastes in the ocean is not expected to result in any significant impacts on the ocean environment or pose any significant radiological risk to humans. It will be necessary to take perpetual care of the near-surface burial sites because the residues and wastes will remain hazardous for thousands of years. If controls cease, the radioactive materials will eventually be dispersed in the environment. Predicted loss of the earthen covers over the buried materials ranges from several hundred to more than two million years, depending primarily on the use of the land surface. Groundwater will eventually be contaminated in all alternatives; however, the groundwater pathway is relatively insignificant with respect to radiological risks to the general population. A person intruding into the residues would incur an extremely high radiation dose.

  8. Separation of thorium (IV) from lanthanide concentrate (LC) and water leach purification (WLP) residue

    SciTech Connect (OSTI)

    AL-Areqi, Wadeeah M.; Majid, Amran Ab.; Sarmani, Sukiman

    2014-09-03

    Thorium (IV) content in industrial residue produced from rare earth elements production industry is one of the challenges to Malaysian environment. Separation of thorium from the lanthanide concentrate (LC) and Water Leach Purification (WLP) residue from rare earth elements production plant is described. Both materials have been tested by sulphuric acid and alkaline digestions. Th concentrations in LC and WLP were determined to be 1289.7 ± 129 and 1952.9±17.6 ppm respectively. The results of separation show that the recovery of Th separation from rare earth in LC after concentrated sulphuric acid dissolution and reduction of acidity to precipitate Th was found 1.76-1.20% whereas Th recovery from WLP was less than 4% after concentrated acids and alkali digestion processes. Inductively Coupled Plasma-Mass Spectroscopy (ICP-MS) was used to determine Th concentrations in aqueous phase during separation stages. This study indicated that thorium maybe exists in refractory and insoluble form which is difficult to separate by these processes and stays in WLP residue as naturally occurring radioactive material (NORM)

  9. Nuclear Car Wash sensitivity in varying thicknesses of wood and steel cargo

    SciTech Connect (OSTI)

    Church, J; Slaughter, D; Asztalos, S; Biltoft, P; Descalle, M; Hall, J; Manatt, D; Mauger, J; Norman, E; Petersen, D; Prussin, S

    2006-10-05

    The influence of incident neutron attenuation on signal strengths in the Nuclear Car Wash has been observed experimentally for both wood and steel-pipe mock cargos. Measured decay curves are presented for {beta}-delayed high-energy {gamma}-rays and thermalized neutrons following neutron-induced fission of HEU through varying irradiation lengths. Error rates are extracted for delayed-{gamma} and delayed-n signals integrated to 30 seconds, assuming Gaussian distributions for the active background. The extrapolation to a field system of 1 mA deuterium current and to a 5 kg sample size is discussed.

  10. Reference Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ID 412- 11/16/2012 - Page 1 Log No 2012-263 Reference Materials * Transporting Radioactive Waste to the Nevada National Security Site fact sheet (ww.nv.energy.gov/library/factsheets/DOENV_990.pdf) - Generators contract with commercial carriers - U.S. Department of Transportation regulations require carriers to select routes which minimize radiological risk * Drivers Route and Shipment Information Questionnaire completed by drivers to document routes taken to the NNSS upon entry into Nevada -

  11. The Effect of Weld Residual Stress on Life of Used Nuclear Fuel Dry Storage Canisters

    SciTech Connect (OSTI)

    Ronald G. Ballinger; Sara E. Ferry; Bradley P. Black; Sebastien P. Teysseyre

    2013-08-01

    With the elimination of Yucca Mountain as the long-term storage facility for spent nuclear fuel in the United States, a number of other storage options are being explored. Currently, used fuel is stored in dry-storage cask systems constructed of steel and concrete. It is likely that used fuel will continue to be stored at existing open-air storage sites for up to 100 years. This raises the possibility that the storage casks will be exposed to a salt-containing environment for the duration of their time in interim storage. Austenitic stainless steels, which are used to construct the canisters, are susceptible to stress corrosion cracking (SCC) in chloride-containing environments if a continuous aqueous film can be maintained on the surface and the material is under stress. Because steel sensitization in the canister welds is typically avoided by avoiding post-weld heat treatments, high residual stresses are present in the welds. While the environment history will play a key role in establishing the chemical conditions for cracking, weld residual stresses will have a strong influence on both crack initiation and propagation. It is often assumed for modeling purposes that weld residual stresses are tensile, high and constant through the weld. However, due to the strong dependence of crack growth rate on stress, this assumption may be overly conservative. In particular, the residual stresses become negative (compressive) at certain points in the weld. The ultimate goal of this research project is to develop a probabilistic model with quantified uncertainties for SCC failure in the dry storage casks. In this paper, the results of a study of the residual stresses, and their postulated effects on SCC behavior, in actual canister welds are presented. Progress on the development of the model is reported.

  12. Fullerene materials

    SciTech Connect (OSTI)

    Malhotra, R.; Ruoff, R.S.; Lorents, D.C.

    1995-04-01

    Fullerenes are all-carbon cage molecules. The most celebrated fullerene is the soccer-ball shaped C{sub 60}, which is composed of twenty hexagons and twelve pentagons. Because its structure is reminiscent of the geodesic domes of architect R. Buckminster Fuller, C{sub 60} is called buckminsterfullerene, and all the materials in the family are designated fullerenes. Huffman and Kraetschmer`s discovery unleashed activity around the world as scientists explored production methods, properties, and potential uses of fullerenes. Within a short period, methods for their production in electric arcs, plasmas, and flames were discovered, and several companies began selling fullerenes to the research market. What is remarkable is that in all these methods, carbon atoms assemble themselves into cage structures. The capability for self-assembly points to some inherent stability of these structures that allows their formation. The unusual structure naturally leads to unusual properties. Among them are ready solubility in solvents and a relatively high vapor pressure for a pure carbon material. The young fullerene field has already produced a surprising array of structures for the development of carbon-base materials having completely new and different properties from any that were previously possible.

  13. Long-term risk stabilization of the Rocky Flats Plant residues

    SciTech Connect (OSTI)

    Melberg, T.A.

    1994-12-31

    The liquid and solid residues continue to be a concern at Rocky Flats, primarily due to safety aspects of long-term storage and of the need for processing them into a form for ultimate disposal. Currently, Rocky Flats is processing the low-level solutions from bottles and tanks by direct cementation for storage and disposal. Plans for actinide precipitation of the high-level solutions are being finalized with an anticipated completion date of 2 to 3 yr. The solid residues present a more difficult challenge because of the numerous forms that these exist. Rocky Flats is developing several strategies to handle these materials for safe long-term storage and eventual disposal.

  14. Treatment methods and comparative risks of thorium removal from waste residues

    SciTech Connect (OSTI)

    Porter, R.D.; Hamby, D.M.; Martin, J.E.

    1997-07-01

    This study was done to examine the risks of remediation and the effectiveness of removal methods for thorium and its associated radioactive decay products from various soils and wastes associated with DOE`s Formerly Utilized Sites Remedial Action Program (FUSRAP). Removal of {sup 230}Th from uranium process residues would significantly reduce the buildup of {sup 226}Ra (half-life of 1600 years), and since {sup 230}Th concentrations at most of the important sites greatly exceed the {sup 226}Ra concentrations, such removal would reduce the accumulation of additional radiation risks associated with {sup 226}Ra and its products; and, if treatment also removed {sup 226}Ra, these risks could be mitigated even further. Removal of {sup 232}Th from thorium process residues would remove the source material for {sup 228}Ra, and since {sup 228}Ra has a half-life of 5.76 years, its control at FUSRAP sites could be done with land use controls for the 30--50 years required for {sup 228}Ra and the risks associated with its decay products to decay away. It must be recognized, however, that treatment methods invariably require workers to process residues and waste materials usually with bulk handling techniques. These processes expose workers to the radioactivity in the materials, therefore, workers would incur radiological risks in addition to industrial accident risks. An important question is whether the potential reduction of future radiological risks to members of the public justifies the risks that are incurred by remediation workers due to handling materials. This study examines, first, the effectiveness of treatment and then the risks that would be associated with remediation.

  15. Thermoacoustic method for relaxation of residual stresses in welded joints

    SciTech Connect (OSTI)

    Koshovyi, V.V.; Pakhn`o, M.I.; Tsykhan, O.I.

    1995-01-01

    We propose a thermoacoustic method for the relaxation of residual stresses in welded joints, present a block diagram of a generator of local thermoacoustic pulses designed for implementation of this method, and describe our experiment aimed at relaxation of residual tensile stresses.

  16. CONTAINER MATERIALS, FABRICATION AND ROBUSTNESS

    SciTech Connect (OSTI)

    Dunn, K.; Louthan, M.; Rawls, G.; Sindelar, R.; Zapp, P.; Mcclard, J.

    2009-11-10

    The multi-barrier 3013 container used to package plutonium-bearing materials is robust and thereby highly resistant to identified degradation modes that might cause failure. The only viable degradation mechanisms identified by a panel of technical experts were pressurization within and corrosion of the containers. Evaluations of the container materials and the fabrication processes and resulting residual stresses suggest that the multi-layered containers will mitigate the potential for degradation of the outer container and prevent the release of the container contents to the environment. Additionally, the ongoing surveillance programs and laboratory studies should detect any incipient degradation of containers in the 3013 storage inventory before an outer container is compromised.

  17. Roll-to-Roll Electrode Processing and Materials NDE for Advanced Lithium

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Secondary Batteries | Department of Energy 3 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting es165_wood_2013_p.pdf (4.5 MB) More Documents & Publications Vehicle Technologies Office Merit Review 2014: Roll-to-Roll Electrode Processing NDE for Advanced Lithium Secondary Batteries Lithium Ion Electrode Production NDE and QC Considerations Roll-to-Roll Electrode Processing and Materials NDE for Advanced Lithium Secondary

  18. Roll-to-Roll Electrode Processing and Materials NDE for Advanced Lithium

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Secondary Batteries | Department of Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting es165_wood_2012_o.pdf (3.53 MB) More Documents & Publications Roll-to-Roll Electrode Processing and Materials NDE for Advanced Lithium Secondary Batteries Vehicle Technologies Office Merit Review 2014: Roll-to-Roll Electrode Processing NDE for Advanced Lithium Secondary Batteries In-situ characterization and diagnostics of

  19. A decision analysis method for selection of waste minimization process options for TRU mixed material at Rocky Flats

    SciTech Connect (OSTI)

    Williams, R.E.; Dustin, D.F.

    1994-02-01

    When plutonium production operations were halted at the Rocky Flats Plant, there remained a volume of material that was retained in order that its plutonium content could be reclaimed. This material, known as residue, is transuranic and mixed transuranic material with a plutonium content above what was called the ``economic discard limit,`` or EDL. The EDL was defined in terms of each type of residue material, and each type of material is given an Item Description Code, or IDC. Residue IDCs have been grouped into general category descriptions which include plutonium (Pu) nitrate solutions, Pu chloride solutions, salts, ash, metal, filters, combustibles, graphite, crucibles, glass, resins, gloves, firebrick, and sludges. Similar material exists both below and above the EDL, with material with the (previous) economic potential for reclamation of plutonium classified as residue.

  20. Conversion of direct process high-boiling residue to monosilanes

    DOE Patents [OSTI]

    Brinson, Jonathan Ashley (Vale of Glamorgan, GB); Crum, Bruce Robert (Madison, IN); Jarvis, Jr., Robert Frank (Midland, MI)

    2000-01-01

    A process for the production of monosilanes from the high-boiling residue resulting from the reaction of hydrogen chloride with silicon metalloid in a process typically referred to as the "direct process." The process comprises contacting a high-boiling residue resulting from the reaction of hydrogen chloride and silicon metalloid, with hydrogen gas in the presence of a catalytic amount of aluminum trichloride effective in promoting conversion of the high-boiling residue to monosilanes. The present process results in conversion of the high-boiling residue to monosilanes. At least a portion of the aluminum trichloride catalyst required for conduct of the process may be formed in situ during conduct of the direct process and isolation of the high-boiling residue.

  1. The Influence of Process Conditions on the Chemical Composition of Pine Wood Catalytic Pyrolysis Oils

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pereira, J.; Agblevor, F. A.; Beis, S. H.

    2012-01-01

    Pine wood samples were used as model feedstock to study the properties of catalytic fast pyrolysis oils. The influence of two commercial zeolite catalysts (BASF and SudChem) and pretreatment of the pine wood with sodium hydroxide on pyrolysis products were investigated. The pyrolysis oils were first fractionated using column chromatography and characterized using GC-MS. Long chain aliphatic hydrocarbons, levoglucosan, aldehydes and ketones, guaiacols/syringols, and benzenediols were the major compounds identified in the pyrolysis oils. The catalytic pyrolysis increased the polycyclic hydrocarbons fraction. Significant decreases in phthalate derivatives using SudChem and long chain aliphatics using BASF catalyst were observed. Significant amountsmore » of aromatic heterocyclic hydrocarbons and benzene derivatives were formed, respectively, using BASF and SudChem catalysts. Guaiacyl/syringyl and benzenediols derivatives were partly suppressed by the zeolite catalysts, while the sodium hydroxide treatment enriched phenolic derivatives. Zeolite catalyst and sodium hydroxide were employed together; they showed different results for each catalyst.« less

  2. Relation between combustion heat and chemical wood composition during white and brown rot

    SciTech Connect (OSTI)

    Dobry, J.; Dziurzynski, A.; Rypacek, V.

    1986-01-01

    Samples of beech and spruce wood were incubated with the white rot fungi Pleurotus ostreatus and Lentinus tigrinus and the brown rot fungi Fomitopsis pinicola and Serpula lacrymans (S. lacrimans) for four months. Decomposition (expressed as percent weight loss) and amounts of holocellulose, lignin, humic acids (HU), hymatomelanic acids (HY) and fulvo acids (FU) were determined and expressed in weight percent. Combustion heat of holocellulose and lignin was determined in healthy wood and in specimens where decomposition was greater than 50%. During white rot decomposition, combustion heat was unchanged even at high decomposition and the relative amounts of holocellulose and lignin remained the same. Total amounts of HU, HY and FU increased during the initial stages and stabilized at 20%. The content of HU plus HY was negligible even at the highest degree of decomposition. During brown rot decomposition, combustion heat was unchanged only in the initial stages, it increased continously with increasing rot. Lignin content was unchanged in the initial stages and increased after 30% weight loss. Total amounts of HU, HY and FU increased continuously, reaching higher values than in white rot decomposition; there were differences between the two species. Biosynthesis of HU plus HY began when weight loss reached 30%; there were differences in absolute and relative amounts between species. 24 references.

  3. The influence of the drying medium on high temperature convective drying of single wood chips

    SciTech Connect (OSTI)

    Johansson, A.; Rasmuson, A.

    1997-10-01

    High temperature convective drying of single wood chips with air and superheated steam respectively is studied theoretically. The two-dimensional model presented describes the coupled transport of water, vapor, air and heat. Transport mechanisms included are the convection of gas and liquid, intergas as well as bound water diffusion. In the initial part of the drying process, moisture is transported to the surface mainly due to capillary forces in the transversal direction where evaporation occurs. As the surface becomes dry, the drying front moves towards the center of the particle and an overpressure is simultaneously built up which affects the drying process. The differences between drying in air and steam respectively can be assigned to the physical properties of the drying medium. The period of constant drying rate which does not exist (or is very short) in air drying becomes more significant with decreasing amounts of air in the drying medium and is clearly visible in pure superheated steam drying. The maximal drying rate is larger in air drying, and shorter drying times are obtained since the heat flux to the wood chip particle increases with increasing amounts of air in the drying medium. The period of falling drying rate can be divided into two parts: in the first, the drying rate is dependent upon the humidity of the drying medium whereas in the second, there is no such correlation.

  4. Wood energy and preservation of woodlands in semi-arid developing countries. The case of Dodoma region, Tanzania

    SciTech Connect (OSTI)

    Allen, J.C.

    1985-01-01

    At present little land and labour resources are expended on energy production, but the woodlands in Dodoma are disappearing, causing villagers to save time by switching from fuelwood collected on foot to charcoal shipped in by truck. Results of a linear program show that if the costs of growing the wood for charcoal are counted the switch to charcoal saves time only in areas where population is relatively dense and natural woodland remote. Woodland preservation in Dodoma will require more plantations, increased plantation productivity, improved efficiency of charcoal kilns or stoves and ultimately a switch to some other fuel than wood.

  5. Method of regulating the amount of underfire air for combustion of wood fuels in spreader-stroke boilers

    DOE Patents [OSTI]

    Tuttle, Kenneth L.

    1980-01-01

    A method of metering underfire air for increasing efficiency and reducing particulate emissions from wood-fire, spreader-stoker boilers is disclosed. A portion of the combustion air, approximately one pound of air per pound of wood, is fed through the grate into the fuel bed, while the remainder of the combustion air is distributed above the fuel in the furnace, and the fuel bed is maintained at a depth sufficient to consume all oxygen admitted under fire and to insure a continuous layer of fresh fuel thereover to entrap charred particles inside the fuel bed.

  6. Construction material

    DOE Patents [OSTI]

    Wagh, Arun S.; Antink, Allison L.

    2008-07-22

    A structural material of a polystyrene base and the reaction product of the polystyrene base and a solid phosphate ceramic is applied as a slurry which includes one or more of a metal oxide or a metal hydroxide with a source of phosphate to produce a phosphate ceramic and a poly (acrylic acid or acrylate) or combinations or salts thereof and polystyrene or MgO applied to the polystyrene base and allowed to cure so that the dried aqueous slurry chemically bonds to the polystyrene base. A method is also disclosed of applying the slurry to the polystyrene base.

  7. Alloy materials

    DOE Patents [OSTI]

    Hans Thieme, Cornelis Leo; Thompson, Elliott D.; Fritzemeier, Leslie G.; Cameron, Robert D.; Siegal, Edward J.

    2002-01-01

    An alloy that contains at least two metals and can be used as a substrate for a superconductor is disclosed. The alloy can contain an oxide former. The alloy can have a biaxial or cube texture. The substrate can be used in a multilayer superconductor, which can further include one or more buffer layers disposed between the substrate and the superconductor material. The alloys can be made a by process that involves first rolling the alloy then annealing the alloy. A relatively large volume percentage of the alloy can be formed of grains having a biaxial or cube texture.

  8. Casting materials

    DOE Patents [OSTI]

    Chaudhry, Anil R.; Dzugan, Robert; Harrington, Richard M.; Neece, Faurice D.; Singh, Nipendra P.

    2011-06-14

    A foam material comprises a liquid polymer and a liquid isocyanate which is mixed to make a solution that is poured, injected or otherwise deposited into a corresponding mold. A reaction from the mixture of the liquid polymer and liquid isocyanate inside the mold forms a thermally collapsible foam structure having a shape that corresponds to the inside surface configuration of the mold and a skin that is continuous and unbroken. Once the reaction is complete, the foam pattern is removed from the mold and may be used as a pattern in any number of conventional casting processes.

  9. Remote Compositional Analysis of Spent-Fuel Residues Using Laser-Induced Breakdown Spectroscopy

    SciTech Connect (OSTI)

    Whitehouse, A. I.; Young, J.; Evans, C. P.; Brown, A.; Simpson, A.; Franco, J.

    2003-02-26

    We report on the application of a novel technique known as Laser-Induced Breakdown Spectroscopy (LIBS) for remotely detecting and characterizing the elemental composition of highly radioactive materials including spent-fuel residues and High-Level Waste (HLW). Within the UK nuclear industry, LIBS has been demonstrated to offer a convenient alternative to sampling and laboratory analysis of a wide range of materials irrespective of the activity of the material or the ambient radiation levels. Proven applications of this technology include in-situ compositional analysis of nuclear reactor components, remote detection and characterization of vitrified HLW and remote compositional analysis of highly-active gross contamination within a spent-fuel reprocessing plant.

  10. Effects of polymethylmethacrylate-transfer residues on the growth of organic semiconductor molecules on chemical vapor deposited graphene

    SciTech Connect (OSTI)

    Kratzer, Markus Teichert, Christian; Bayer, Bernhard C.; Kidambi, Piran R.; Matkovi?, Aleksandar; Gaji?, Rado; Cabrero-Vilatela, Andrea; Weatherup, Robert S.; Hofmann, Stephan

    2015-03-09

    Scalably grown and transferred graphene is a highly promising material for organic electronic applications, but controlled interfacing of graphene thereby remains a key challenge. Here, we study the growth characteristics of the important organic semiconductor molecule para-hexaphenyl (6P) on chemical vapor deposited graphene that has been transferred with polymethylmethacrylate (PMMA) onto oxidized Si wafer supports. A particular focus is on the influence of PMMA residual contamination, which we systematically reduce by H{sub 2} annealing prior to 6P deposition. We find that 6P grows in a flat-lying needle-type morphology, surprisingly independent of the level of PMMA residue and of graphene defects. Wrinkles in the graphene typically act as preferential nucleation centers. Residual PMMA does however limit the length of the resulting 6P needles by restricting molecular diffusion/attachment. We discuss the implications for organic device fabrication, with particular regard to contamination and defect tolerance.

  11. Environmental impact of APC residues from municipal solid waste incineration: Reuse assessment based on soil and surface water protection criteria

    SciTech Connect (OSTI)

    Quina, Margarida J.; Bordado, Joao C.M.; Quinta-Ferreira, Rosa M.

    2011-09-15

    Highlights: > The Dutch Building Material Decree (BMD) was used to APC residues from MSWI. > BMD is a straightforward tool to calculate expectable loads to the environment of common pollutants. > Chloride load to the environment lead to classification of building material not allowed. > At least a pre-treatment (e.g. washing) is required in order to remove soluble salts. > The stabilization with phosphates or silicates eliminate the problem of heavy metals. - Abstract: Waste management and environmental protection are mandatory requirements of modern society. In our study, air pollution control (APC) residues from municipal solid waste incinerators (MSWI) were considered as a mixture of fly ash and fine particulate solids collected in scrubbers and fabric filters. These are hazardous wastes and require treatment before landfill. Although there are a number of treatment options, it is highly recommended to find practical applications rather than just dump them in landfill sites. In general, for using a construction material, beyond technical specifications also soil and surface water criteria may be used to ensure environmental protection. The Dutch Building Materials Decree (BMD) is a valuable tool in this respect and it was used to investigate which properties do not meet the threshold criteria so that APC residues can be further used as secondary building material. To this end, some scenarios were evaluated by considering release of inorganic species from unmoulded and moulded applications. The main conclusion is that the high amount of soluble salts makes the APC residues a building material prohibited in any of the conditions tested. In case of moulding materials, the limits of heavy metals are complied, and their use in Category 1 would be allowed. However, also in this case, the soluble salts lead to the classification of 'building material not allowed'. The treatments with phosphates or silicates are able to solve the problem of heavy metals, but

  12. Photovoltaic Materials

    SciTech Connect (OSTI)

    Duty, C.; Angelini, J.; Armstrong, B.; Bennett, C.; Evans, B.; Jellison, G. E.; Joshi, P.; List, F.; Paranthaman, P.; Parish, C.; Wereszczak, A.

    2012-10-15

    The goal of the current project was to help make the US solar industry a world leader in the manufacture of thin film photovoltaics. The overall approach was to leverage ORNL’s unique characterization and processing technologies to gain a better understanding of the fundamental challenges for solar cell processing and apply that knowledge to targeted projects with industry members. ORNL has the capabilities in place and the expertise required to understand how basic material properties including defects, impurities, and grain boundaries affect the solar cell performance. ORNL also has unique processing capabilities to optimize the manufacturing process for fabrication of high efficiency and low cost solar cells. ORNL recently established the Center for Advanced Thin-film Systems (CATS), which contains a suite of optical and electrical characterization equipment specifically focused on solar cell research. Under this project, ORNL made these facilities available to industrial partners who were interested in pursuing collaborative research toward the improvement of their product or manufacturing process. Four specific projects were pursued with industrial partners: Global Solar Energy is a solar industry leader in full scale production manufacturing highly-efficient Copper Indium Gallium diSelenide (CIGS) thin film solar material, cells and products. ORNL worked with GSE to develop a scalable, non-vacuum, solution technique to deposit amorphous or nanocrystalline conducting barrier layers on untextured stainless steel substrates for fabricating high efficiency flexible CIGS PV. Ferro Corporation’s Electronic, Color and Glass Materials (“ECGM”) business unit is currently the world’s largest supplier of metallic contact materials in the crystalline solar cell marketplace. Ferro’s ECGM business unit has been the world's leading supplier of thick film metal pastes to the crystalline silicon PV industry for more than 30 years, and has had operational cells and

  13. Residual Fuel Oil Sales to End Users Refiner Sales Volumes

    U.S. Energy Information Administration (EIA) Indexed Site

    Product: Residual Fuel Oil Residual F.O., Sulfur <= 1% Residual F.O., Sulfur > 1% No. 4 Fuel Oil Period-Unit: Monthly - Thousand Gallons per Day Annual - Thousand Gallons per Day Sales Type: Sales to End Users Sales for Resale Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product Sales Type Area Jan-16 Feb-16 Mar-16 Apr-16 May-16 Jun-16 View History U.S. 4,103.1 3,860.0 4,053.4 4,238.4 3,888.8 3,799.0

  14. Environmental assessment, finding of no significant impact, and response to comments. Sold residue treatment, repackaging, and storage

    SciTech Connect (OSTI)

    1996-04-01

    From its founding in 1952 through the cessation of production in 1989, the United States Department of Energy`s (DOE) Rocky Flats Plant (now the Rocky Flats Environmental Technology Site [the Site]) produced components for nuclear weapons. Some of those components were made of plutonium. As a result of the processes used to recover and purify plutonium and manufacture the components, a variety of materials became contaminated with plutonium. If the level of contamination were low, the material was considered waste. However, if the concentration of plutonium in the material exceeded the {open_quotes}economic discard limit,{close_quotes} the materials were classified as {open_quotes}residue{close_quotes} rather than{open_quotes}Waste{close_quotes} and were stored for later recovery of the plutonium. While large quantities of residues were processed, others, primarily those more difficult to process, accumulated at the Site in storage. Two important events regarding residues have occurred at the Site since production activities ceased. One event was the end of the Cold War in 1991, which made the return to production of nuclear weapons, with their Rocky Flats-made components, unnecessary. This event led to DOE`s decision to permanently cease production at the Site, clean up and remove radioactive and chemical contamination at the Site, and find alternative uses for the Site. This document describes methods for processing of the wastes for safe interim storage. Environmental impacts from the processing and storage are discussed.

  15. Catalytic Hydrothermal Gasification of Lignin-Rich Biorefinery Residues and Algae Final Report

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Neuenschwander, Gary G.; Hart, Todd R.; Rotness, Leslie J.; Zacher, Alan H.; Santosa, Daniel M.; Valkenburt, Corinne; Jones, Susanne B.; Tjokro Rahardjo, Sandra A.

    2009-11-03

    This report describes the results of the work performed by PNNL using feedstock materials provided by the National Renewable Energy Laboratory, KL Energy and Lignol lignocellulosic ethanol pilot plants. Test results with algae feedstocks provided by Genifuel, which provided in-kind cost share to the project, are also included. The work conducted during this project involved developing and demonstrating on the bench-scale process technology at PNNL for catalytic hydrothermal gasification of lignin-rich biorefinery residues and algae. A technoeconomic assessment evaluated the use of the technology for energy recovery in a lignocellulosic ethanol plant.

  16. Thermal input control and enhancement for laser based residual stress measurements using liquid temperature indicating coatings

    DOE Patents [OSTI]

    Pechersky, Martin J.

    1999-01-01

    An improved method for measuring residual stress in a material comprising the steps of applying a spot of temperature indicating coating to the surface to be studied, establishing a speckle pattern surrounds the spot of coating with a first laser then heating the spot of coating with a far infrared laser until the surface plastically deforms. Comparing the speckle patterns before and after deformation by subtracting one pattern from the other will produce a fringe pattern that serves as a visual and quantitative indication of the degree to which the plasticized surface responded to the stress during heating and enables calculation of the stress.

  17. Thermal input control and enhancement for laser based residual stress measurements using liquid temperature indicating coatings

    DOE Patents [OSTI]

    Pechersky, M.J.

    1999-07-06

    An improved method for measuring residual stress in a material is disclosed comprising the steps of applying a spot of temperature indicating coating to the surface to be studied, establishing a speckle pattern surrounds the spot of coating with a first laser then heating the spot of coating with a far infrared laser until the surface plastically deforms. Comparing the speckle patterns before and after deformation by subtracting one pattern from the other will produce a fringe pattern that serves as a visual and quantitative indication of the degree to which the plasticized surface responded to the stress during heating and enables calculation of the stress. 3 figs.

  18. Methanol production from Eucalyptus wood chips. Working document I. The Florida Eucalyptus energy farm: silvicultural methods and considerations

    SciTech Connect (OSTI)

    Fishkind, H.H.

    1982-04-01

    The silvicultural matrix within which the nation's first large scale wood energy plantation will develop is described in detail. The relevant literature reviewed is identified and distilled. The plantation history, site preparation, planting, species selection, maintenance and management, harvesting, and the Eucalyptus biomass production estimates are presented.

  19. Insight into trade-off between wood decay and parasitism from the genome of a fungal forest pathogen

    SciTech Connect (OSTI)

    Olson, Ake; Aerts, Andrea; Asiegbu, Fred; Belbahri, Lassaad; Bouzid, Ourdia; Broberg, Anders; Canback, Bjorn; Coutinho, Pedro M.; Cullen, Dan; Dalman, Kerstin; Deflorio, Giuliana; van Diepen, Linda T. A.; Dunand, Christophe; Duplessis, Sebastien; Durling, Mikael; Gonthier, Paolo; Grimwood, Jane; Fossdal, Carl Gunnar; Hansson, David; Henrissat, Bernard; Hietala, Ari; Himmelstrand, Kajsa; Hoffmeister, Dirk; Hogberg, Nils; James, Timothy Y.; Karlsson, Magnus; Kohler, Annegret; Lucas, Susan; Lunden, Karl; Morin, Emmanuelle; Murat, Claude; Park, Jongsun; Raffaello, Tommaso; Rouze, Pierre; Salamov, Asaf; Schmutz, Jeremy; Solheim, Halvor; Stahlberg, Jerry; Velez, Heriberto; de Vries, Ronald P.; Wiebenga, Ad; Woodward, Steve; Yakovlev, Igor; Garbelotto, Matteo; Martin, Francis; Grigoriev, Igor V.; Stenlid, Jan

    2012-01-01

    Parasitism and saprotrophic wood decay are two fungal strategies fundamental for succession and nutrient cycling in forest ecosystems. An opportunity to assess the trade-off between these strategies is provided by the forest pathogen and wood decayer Heterobasidion annosum sensu lato. We report the annotated genome sequence and transcript profiling, as well as the quantitative trait loci mapping, of one member of the species complex: H. irregulare. Quantitative trait loci critical for pathogenicity, and rich in transposable elements, orphan and secreted genes, were identified. A wide range of cellulose-degrading enzymes are expressed during wood decay. By contrast, pathogenic interaction between H. irregulare and pine engages fewer carbohydrate-active enzymes, but involves an increase in pectinolytic enzymes, transcription modules for oxidative stress and secondary metabolite production. Our results show a trade-off in terms of constrained carbohydrate decomposition and membrane transport capacity during interaction with living hosts. Our findings establish that saprotrophic wood decay and necrotrophic parasitism involve two distinct, yet overlapping, processes.

  20. Analysis of the Phlebiopsis gigantea Genome, Transcriptome and Secretome Provides Insight into Its Pioneer Colonization Strategies of Wood

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hori, Chiaki; Ishida, Takuya; Igarashi, Kiyohiko; Samejima, Masahiro; Suzuki, Hitoshi; Master, Emma; Ferreira, Patricia; Ruiz-Dueñas, Francisco J.; Held, Benjamin; Canessa, Paulo; et al

    2014-12-04

    Collectively classified as white-rot fungi, certain basidiomycetes efficiently degrade the major structural polymers of wood cell walls. A small subset of these Agaricomycetes, exemplified by Phlebiopsis gigantea, is capable of colonizing freshly exposed conifer sapwood despite its high content of extractives, which retards the establishment of other fungal species. The mechanism(s) by which P. gigantea tolerates and metabolizes resinous compounds have not been explored. Here, we report the annotated P. gigantea genome and compare profiles of its transcriptome and secretome when cultured on freshcut versus solvent-extracted loblolly pine wood. The P. gigantea genome contains a conventional repertoire of hydrolase genesmore » involved in cellulose/hemicellulose degradation, whose patterns of expression were relatively unperturbed by the absence of extractives. The expression of genes typically ascribed to lignin degradation was also largely unaffected. In contrast, genes likely involved in the transformation and detoxification of wood extractives were highly induced in its presence. Their products included an ABC transporter, lipases, cytochrome P450s, glutathione S-transferase and aldehyde dehydrogenase. Other regulated genes of unknown function and several constitutively expressed genes are also likely involved in P. gigantea’s extractives metabolism. These results contribute to our fundamental understanding of pioneer colonization of conifer wood and provide insight into the diverse chemistries employed by fungi in carbon cycling processes.« less

  1. Analysis of the Phlebiopsis gigantea Genome, Transcriptome and Secretome Provides Insight into Its Pioneer Colonization Strategies of Wood

    SciTech Connect (OSTI)

    Hori, Chiaki; Ishida, Takuya; Igarashi, Kiyohiko; Samejima, Masahiro; Suzuki, Hitoshi; Master, Emma; Ferreira, Patricia; Ruiz-Dueñas, Francisco J.; Held, Benjamin; Canessa, Paulo; Larrondo, Luis F.; Schmoll, Monika; Druzhinina, Irina S.; Kubicek, Christian P.; Gaskell, Jill A.; Kersten, Phil; St. John, Franz; Glasner, Jeremy; Sabat, Grzegorz; Splinter BonDurant, Sandra; Syed, Khajamohiddin; Yadav, Jagjit; Mgbeahuruike, Anthony C.; Kovalchuk, Andriy; Asiegbu, Fred O.; Lackner, Gerald; Hoffmeister, Dirk; Rencoret, Jorge; Gutiérrez, Ana; Sun, Hui; Lindquist, Erika; Barry, Kerrie; Riley, Robert; Grigoriev, Igor V.; Henrissat, Bernard; Berka, Randy M.; Martínez, Angel T.; Covert, Sarah F.; Blanchette, Robert A.; Cullen, Daniel; Copenhaver, Gregory P.

    2014-12-04

    Collectively classified as white-rot fungi, certain basidiomycetes efficiently degrade the major structural polymers of wood cell walls. A small subset of these Agaricomycetes, exemplified by Phlebiopsis gigantea, is capable of colonizing freshly exposed conifer sapwood despite its high content of extractives, which retards the establishment of other fungal species. The mechanism(s) by which P. gigantea tolerates and metabolizes resinous compounds have not been explored. Here, we report the annotated P. gigantea genome and compare profiles of its transcriptome and secretome when cultured on freshcut versus solvent-extracted loblolly pine wood. The P. gigantea genome contains a conventional repertoire of hydrolase genes involved in cellulose/hemicellulose degradation, whose patterns of expression were relatively unperturbed by the absence of extractives. The expression of genes typically ascribed to lignin degradation was also largely unaffected. In contrast, genes likely involved in the transformation and detoxification of wood extractives were highly induced in its presence. Their products included an ABC transporter, lipases, cytochrome P450s, glutathione S-transferase and aldehyde dehydrogenase. Other regulated genes of unknown function and several constitutively expressed genes are also likely involved in P. gigantea’s extractives metabolism. These results contribute to our fundamental understanding of pioneer colonization of conifer wood and provide insight into the diverse chemistries employed by fungi in carbon cycling processes.

  2. The effects of machine parameters on residual stress determined using micro-Raman spectroscopy

    SciTech Connect (OSTI)

    Sparks, R.G.; Enloe, W.S.; Paesler, M.A.

    1988-12-01

    The effects of machine parameters on residual stresses in single point diamond turned silicon and germanium have been investigated using micro-Raman spectroscopy. Residual stresses were sampled across ductile feed cuts in < 100 > silicon and germanium which were single point diamond turned using a variety of feed rates, rake angles and clearance angles. High spatial resolution micro-Raman spectra (1{mu}m spot) were obtained in regions of ductile cutting where no visible surface damage was present. The use of both 514-5nm and 488.0nm excitation wavelengths, by virtue of their differing characteristic penetration depths in the materials, allowed determinations of stress profiles as a function of depth into the sample. Previous discussions have demonstrated that such Raman spectra will exhibit asymmetrically broadened peaks which are characteristic of the superposition of a continuum of Raman scatterers from the various depths probed. Depth profiles of residual stress were obtained using computer deconvolution of the resulting asymmetrically broadened raman spectra.

  3. A C. elegans-based foam for rapid on-site detection of residual live virus.

    SciTech Connect (OSTI)

    Negrete, Oscar A.; Branda, Catherine; Hardesty, Jasper O. E.; Tucker, Mark David; Kaiser, Julia N.; Kozina, Carol L.; Chirica, Gabriela S.

    2012-02-01

    In the response to and recovery from a critical homeland security event involving deliberate or accidental release of biological agents, initial decontamination efforts are necessarily followed by tests for the presence of residual live virus or bacteria. Such 'clearance sampling' should be rapid and accurate, to inform decision makers as they take appropriate action to ensure the safety of the public and of operational personnel. However, the current protocol for clearance sampling is extremely time-intensive and costly, and requires significant amounts of laboratory space and capacity. Detection of residual live virus is particularly problematic and time-consuming, as it requires evaluation of replication potential within a eukaryotic host such as chicken embryos. The intention of this project was to develop a new method for clearance sampling, by leveraging Sandia's expertise in the biological and material sciences in order to create a C. elegans-based foam that could be applied directly to the entire contaminated area for quick and accurate detection of any and all residual live virus by means of a fluorescent signal. Such a novel technology for rapid, on-site detection of live virus would greatly interest the DHS, DoD, and EPA, and hold broad commercial potential, especially with regard to the transportation industry.

  4. Restoring Sustainable Forests on Appalachian Mined Lands for Wood Products, Renewable Energy, Carbon Sequestration, and Other Ecosystem Services

    SciTech Connect (OSTI)

    Burger, James A

    2005-07-20

    The overall purpose of this project is to evaluate the biological and economic feasibility of restoring high-quality forests on mined land, and to measure carbon sequestration and wood production benefits that would be achieved from forest restoration procedures. We are currently estimating the acreage of lands in Virginia, West Virginia, Kentucky, Ohio, and Pennsylvania mined under SMCRA and reclaimed to non-forested post-mining land uses that are not currently under active management, and therefore can be considered as available for carbon sequestration. To determine actual sequestration under different forest management scenarios, a field study was installed as a 3 x 3 factorial in a random complete block design with three replications at each of three locations, one each in Ohio, West Virginia, and Virginia. The treatments included three forest types (white pine, hybrid poplar, mixed hardwood) and three silvicultural regimes (competition control, competition control plus tillage, competition control plus tillage plus fertilization). Each individual treatment plot is 0.5 acres. Each block of nine plots is 4.5 acres, and the complete installation at each site is 13.5 acres. During the reporting period we determined that by grinding the soil samples to a finer particle size of less than 250 μm (sieve No. 60), the effect of mine soil coal particle size on the extent to which these particles will be oxidized during the thermal treatment of the carbon partitioning procedure will be eliminated, thus making the procedure more accurate and precise. In the second phase of the carbon sequestration project, we focused our attention on determining the sample size required for carbon accounting on grassland mined fields in order to achieve a desired accuracy and precision of the final soil organic carbon (SOC) estimate. A mine land site quality classification scheme was developed and some field-testing of the methods of implementation was completed. The classification model

  5. Reservoir characterization and performance predictions for the E.N. Woods lease

    SciTech Connect (OSTI)

    Aka-Milan, Francis A.

    2000-07-07

    The task of this work was to evaluate the past performance of the E.N. WOODS Unit and to forecast its future economic performance by taking into consideration the geology, petrophysics and production history of the reservoir. The Decline Curve Analysis feature of the Appraisal of Petroleum Properties including Taxation Systems (EDAPT) software along with the Production Management Systems (PMS) software were used to evaluate the original volume of hydrocarbon in place and estimate the reserve. The Black Oil Simulator (BOAST II) was then used to model the waterflooding operation and estimate the incremental oil production attributable to the water injection. BOAST II was also used to predict future performance of the reservoir.

  6. EERE Success Story-California: Agricultural Residues Produce...

    Broader source: Energy.gov (indexed) [DOE]

    California, to construct a pilot plant that processes 1.2 tons per day of agricultural residues, such as corn stover (leaves and stalks), as well as other California-source...

  7. Improvement of coke quality by utilization of hydrogenation residue

    SciTech Connect (OSTI)

    Meckel, J.F. ); Wairegi, T. )

    1993-01-01

    Hydrogenation residue is the product left over when petroleum residue feedstocks (or coal) are treated by, e.g. the Veba Combi Cracking (VCC) process. Many tests in semitechnical and full-sized coke ovens were carried out with hydrogenation residue (HR) as an additive in coking coal blends for the production of blast furnace coke or foundry coke. The results of the investigations reported in this paper demonstrate that HR is a very promising alternative for enlarging the coking coal basis compared to other processes or the use of other additives. The application of HR on an industrial scale did not indicate any negative impact on the handling of the hydrogenation residue or on the operation of the coke oven battery.

  8. Type Ia Supernova Hubble Residuals and Host-Galaxy Properties...

    Office of Scientific and Technical Information (OSTI)

    The K13 Hubble residual step with host mass is 0.013 ? 0.031 mag for a supernova subsample with data coverage corresponding to the K13 training; at ? 1?, the step is not ...

  9. Critical Materials Workshop

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentations during the Critical Materials Workshop held on April 3, 2012 overviewing critical materials strategies

  10. Fate of Cu, Cr, and As during combustion of impregnated wood with and without peat additive

    SciTech Connect (OSTI)

    Karin Lundholm; Dan Bostroem; Anders Nordin; Andrei Shchukarev

    2007-09-15

    The EU Directive on incineration of waste regulates the harmful emissions of particles and twelve toxic elements, including copper, chromium, and arsenic. Using a 15 kW pellets-fueled grate burner, experiments were performed to determine the fate of copper, chromium, and arsenic during combustion of chromate copper arsenate (CCA) preservative wood. The fate and speciation of copper, chromium, and arsenic were determined from analysis of the flue gas particles and the bottom ash using SEM-EDS, XRD, XPS, and ICP-AES. Chemical equilibrium model calculations were performed to interpret the experimental findings. The results revealed that about 5% copper, 15% chromium, and 60% arsenic were volatilized during combustion of pure CCA-wood, which is lower than predicted volatilization from the individual arsenic, chromium, and copper oxides. This is explained by the formation of more stable refractory complex oxide phases for which the stability trends and patterns are presented. When co-combusted with peat, an additional stabilization of these phases was obtained and thus a small but noteworthy decrease in volatilization of all three elements was observed. The major identified phases for all fuels were CuCrO{sub 2}(s), (Fe,Mg,Cu)(Cr,Fe,Al)O{sub 4}(s), Cr{sub 2}O{sub 3}(s), and Ca{sub 3}(AsO{sub 4}){sub 2}(s). Arsenic was also identified in the fine particles as KH{sub 2}AsO{sub 4}(s) and As{sub 2}O{sub 3}). A strong indication of hexavalent chromium in the form of K{sub 2}CrO{sub 4} or as a solid solution between K{sub 3}Na(CrO{sub 4}){sub 2} and K{sub 3}Na(SO{sub 4}){sub 2} was found in the fine particles. Good qualitative agreement was observed between experimental data and chemical equilibrium model calculations. 38 refs., 6 figs., 2 tabs.

  11. Extensive sampling of basidiomycete genomes demonstrates inadequacy of the white rot/ brown rot paradigm for wood decay fungi

    SciTech Connect (OSTI)

    Riley, Robert; Salamov, Asaf; Brown, Daren W.; Nagy, Laszlo G.; Floudas, Dimitris; Held, Benjamin; Levasseur, Anthony; Lombard, Vincent; Morin, Emmanuelle; Otillar, Robert; Lindquist, Erika; Sun, Hui; LaButti, Kurt; Schmutz, Jeremy; Jabbour, Dina; Luo, Hong; Baker, Scott E.; Pisabarro, Antonio; Walton, Jonathan D.; Blanchette, Robert; Henrissat, Bernard; Martin, Francis; Cullen, Dan; Hibbett, David; Grigoriev, Igor V.

    2014-03-14

    Basidiomycota (basidiomycetes) make up 32percent of the described fungi and include most wood decaying species, as well as pathogens and mutualistic symbionts. Wood-decaying basidiomycetes have typically been classified as either white rot or brown rot, based on the ability (in white rot only) to degrade lignin along with cellulose and hemicellulose. Prior genomic comparisons suggested that the two decay modes can be distinguished based on the presence or absence of ligninolytic class II peroxidases (PODs), as well as the abundance of enzymes acting directly on crystalline cellulose (reduced in brown rot). To assess the generality of the white rot/brown rot classification paradigm we compared the genomes of 33 basidiomycetes, including four newly sequenced wood decayers, and performed phylogenetically-informed Principal Components Analysis (PCA) of a broad range of gene families encoding plant biomass-degrading enzymes. The newly sequenced Botryobasidium botryosum and Jaapia argillacea genomes lack PODs, but possess diverse enzymes acting on crystalline cellulose, and they group close to the model white rot species Phanerochaete chrysosporium in the PCA. Furthermore, laboratory assays showed that both B. botryosum and J. argillacea can degrade all polymeric components of woody plant cell walls, a characteristic of white rot. We also found expansions in reducing polyketide synthase genes specific to the brown rot fungi. Our results suggest a continuum rather than a dichotomy between the white rot and brown rot modes of wood decay. A more nuanced categorization of rot types is needed, based on an improved understanding of the genomics and biochemistry of wood decay.

  12. GEOCHEMICAL TESTING AND MODEL DEVELOPMENT - RESIDUAL TANK WASTE TEST PLAN

    SciTech Connect (OSTI)

    CANTRELL KJ; CONNELLY MP

    2010-03-09

    This Test Plan describes the testing and chemical analyses release rate studies on tank residual samples collected following the retrieval of waste from the tank. This work will provide the data required to develop a contaminant release model for the tank residuals from both sludge and salt cake single-shell tanks. The data are intended for use in the long-term performance assessment and conceptual model development.

  13. Critical Materials Institute

    ScienceCinema (OSTI)

    Alex King

    2013-06-05

    Ames Laboratory Director Alex King talks about the goals of the Critical Materials Institute in diversifying the supply of critical materials, developing substitute materials, developing tools and techniques for recycling critical materials, and forecasting materials needs to avoid future shortages.

  14. Plutonium inventories for stabilization and stabilized materials

    SciTech Connect (OSTI)

    Williams, A.K.

    1996-05-01

    The objective of the breakout session was to identify characteristics of materials containing plutonium, the need to stabilize these materials for storage, and plans to accomplish the stabilization activities. All current stabilization activities are driven by the Defense Nuclear Facilities Safety Board Recommendation 94-1 (May 26, 1994) and by the recently completed Plutonium ES&H Vulnerability Assessment (DOE-EH-0415). The Implementation Plan for accomplishing stabilization of plutonium-bearing residues in response to the Recommendation and the Assessment was published by DOE on February 28, 1995. This Implementation Plan (IP) commits to stabilizing problem materials within 3 years, and stabilizing all other materials within 8 years. The IP identifies approximately 20 metric tons of plutonium requiring stabilization and/or repackaging. A further breakdown shows this material to consist of 8.5 metric tons of plutonium metal and alloys, 5.5 metric tons of plutonium as oxide, and 6 metric tons of plutonium as residues. Stabilization of the metal and oxide categories containing greater than 50 weight percent plutonium is covered by DOE Standard {open_quotes}Criteria for Safe Storage of Plutonium Metals and Oxides{close_quotes} December, 1994 (DOE-STD-3013-94). This standard establishes criteria for safe storage of stabilized plutonium metals and oxides for up to 50 years. Each of the DOE sites and contractors with large plutonium inventories has either started or is preparing to start stabilization activities to meet these criteria.

  15. Modelling of a downdraft gasifier fed by agricultural residues

    SciTech Connect (OSTI)

    Antonopoulos, I.-S.; Karagiannidis, A.; Gkouletsos, A.; Perkoulidis, G.

    2012-04-15

    Highlights: Black-Right-Pointing-Pointer Development of software for downdraft gasification simulation. Black-Right-Pointing-Pointer Prediction of the syngas concentration. Black-Right-Pointing-Pointer Prediction of the syngas heating value. Black-Right-Pointing-Pointer Investigation of the temperature effect in reduction zone in syngas concentration. - Abstract: A non-stoichiometric model for a downdraft gasifier was developed in order to simulate the overall gasification process. Mass and energy balances of the gasifier were calculated and the composition of produced syngas was predicted. The capacity of the modeled gasifier was assumed to be 0.5 MW, with an Equivalence Ratio (EQ) of 0.45. The model incorporates the chemical reactions and species involved, while it starts by selecting all species containing C, H, and O, or any other dominant elements. Olive wood, miscanthus and cardoon were tested in the formulated model for a temperature range of 800-1200 Degree-Sign C, in order to examine the syngas composition and the moisture impact on the supplied fuel. Model results were then used in order to design an olive wood gasification reactor.

  16. Gas storage materials, including hydrogen storage materials

    DOE Patents [OSTI]

    Mohtadi, Rana F; Wicks, George G; Heung, Leung K; Nakamura, Kenji

    2013-02-19

    A material for the storage and release of gases comprises a plurality of hollow elements, each hollow element comprising a porous wall enclosing an interior cavity, the interior cavity including structures of a solid-state storage material. In particular examples, the storage material is a hydrogen storage material such as a solid state hydride. An improved method for forming such materials includes the solution diffusion of a storage material solution through a porous wall of a hollow element into an interior cavity.

  17. Gas storage materials, including hydrogen storage materials

    DOE Patents [OSTI]

    Mohtadi, Rana F; Wicks, George G; Heung, Leung K; Nakamura, Kenji

    2014-11-25

    A material for the storage and release of gases comprises a plurality of hollow elements, each hollow element comprising a porous wall enclosing an interior cavity, the interior cavity including structures of a solid-state storage material. In particular examples, the storage material is a hydrogen storage material, such as a solid state hydride. An improved method for forming such materials includes the solution diffusion of a storage material solution through a porous wall of a hollow element into an interior cavity.

  18. Superfund record of decision (EPA Region 8): Smeltertown Site, Operable Unit 2, former Koppers Wood Treating site, Salida, CO, June 4, 1998

    SciTech Connect (OSTI)

    1998-10-01

    This decision document presents the selected remedial action (RA) for the former Koppers Wood Treating Operable Unit (OU2) at the Smeltertown Superfund Site (the Site). This action addresses the wood-treating contaminants from the tie treating operations at the former Koppers Wood Treating Operable Unit that were conducted by Koppers Company, Inc. (now known as Beazer East, Inc.) from 1924 through 1953. This remedy calls for the containment of soils contaminated at low levels and monitors the effect of the contaminants in the soils, dissolved polycyclic aromatic hydrocarbon (PAHs) and dense non-aqueous phase liquids (DNAPL) within the groundwater.

  19. Geopolymer resin materials, geopolymer materials, and materials produced thereby

    DOE Patents [OSTI]

    Seo, Dong-Kyun; Medpelli, Dinesh; Ladd, Danielle; Mesgar, Milad

    2016-03-29

    A product formed from a first material including a geopolymer resin material, a geopolymer resin, or a combination thereof by contacting the first material with a fluid and removing at least some of the fluid to yield a product. The first material may be formed by heating and/or aging an initial geopolymer resin material to yield the first material before contacting the first material with the fluid. In some cases, contacting the first material with the fluid breaks up or disintegrates the first material (e.g., in response to contact with the fluid and in the absence of external mechanical stress), thereby forming particles having an external dimension in a range between 1 nm and 2 cm.

  20. Illinois biomass resources: annual crops and residues; canning and food-processing wastes. Preliminary assessment

    SciTech Connect (OSTI)

    Antonopoulos, A A

    1980-06-01

    Illinois, a major agricultural and food-processing state, produces vast amounts of renewable plant material having potential for energy production. This biomass, in the form of annual crops, crop residues, and food-processing wastes, can be converted to alternative fuels (such as ethanol) and industrial chemicals (such as furfural, ethylene, and xylene). The present study provides a preliminary assessment of these Illinois biomass resources, including (a) an appraisal of the effects of their use on both agriculture and industry; (b) an analysis of biomass conversion systems; and (c) an environmental and economic evaluation of products that could be generated from biomass. It is estimated that, of the 39 x 10/sup 6/ tons of residues generated in 1978 in Illinois from seven main crops, about 85% was collectible. The thermal energy equivalent of this material is 658 x 10/sup 6/ Btu, or 0.66 quad. And by fermenting 10% of the corn grain grown in Illinois, some 323 million gallons of ethanol could have been produced in 1978. Another 3 million gallons of ethanol could have been produced in the same year from wastes generated by the state's food-processing establishments. Clearly, Illinois can strengthen its economy substantially by the development of industries that produce biomass-derived fuels and chemicals. In addition, a thorough evaluation should be made of the potential for using the state's less-exploitable land for the growing of additional biomass.

  1. Testing in support of transportation of residues in the pipe overpack container

    SciTech Connect (OSTI)

    Ammerman, D.J.; Bobbe, J.G.; Arviso, M.; Bronowski, D.R.

    1997-04-01

    The disposition of the large back-log of plutonium residues at the Rocky Flats Environmental Technology Site (Rocky Flats) will require interim storage and subsequent shipment to a waste repository. Current plants call for disposal at the Waste Isolation Pilot Plant (WIPP) and the transportation to WIPP in the TRUPACT-II. The transportation phase will require the residues to be packaged in a container that is more robust than a standard 55-gallon waste drum. Rocky Flats has designed the Pipe Overpack Container to meet this need. The tests described here were performed to qualify the Pipe Overpack Container as a waste container for shipment in the TRUPACT-II. Using a more robust container will assure the fissile materials in each container can not be mixed with the fissile material from the other containers and will provide criticality control. This will allow an increase in the payload of the TRUPACT-II from 325 fissile gram equivalents to 2,800 fissile gram equivalents.

  2. weapons material protection | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    material protection

  3. Materials Project: A Materials Genome Approach

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Ceder, Gerbrand [MIT; Persson, Kristin [LBNL

    Technological innovation - faster computers, more efficient solar cells, more compact energy storage - is often enabled by materials advances. Yet, it takes an average of 18 years to move new materials discoveries from lab to market. This is largely because materials designers operate with very little information and must painstakingly tweak new materials in the lab. Computational materials science is now powerful enough that it can predict many properties of materials before those materials are ever synthesized in the lab. By scaling materials computations over supercomputing clusters, this project has computed some properties of over 80,000 materials and screened 25,000 of these for Li-ion batteries. The computations predicted several new battery materials which were made and tested in the lab and are now being patented. By computing properties of all known materials, the Materials Project aims to remove guesswork from materials design in a variety of applications. Experimental research can be targeted to the most promising compounds from computational data sets. Researchers will be able to data-mine scientific trends in materials properties. By providing materials researchers with the information they need to design better, the Materials Project aims to accelerate innovation in materials research.[copied from http://materialsproject.org/about] You will be asked to register to be granted free, full access.

  4. A Google for Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Kristin Persson A Google for Materials February 4, 2014 Kirstin Persson, Berkeley Lab Downloads Persson-Materials-NUG2014.pdf | Adobe Acrobat PDF file A Google For Materials? -...

  5. LANSCE | Materials Test Station

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Training Office Contact Administrative nav background Materials Test Station dotline ... Materials Test Station: the Preferred Alternative When completed, the Materials Test ...

  6. Chemical digestion of low level nuclear solid waste material

    DOE Patents [OSTI]

    Cooley, Carl R.; Lerch, Ronald E.

    1976-01-01

    A chemical digestion for treatment of low level combustible nuclear solid waste material is provided and comprises reacting the solid waste material with concentrated sulfuric acid at a temperature within the range of 230.degree.-300.degree.C and simultaneously and/or thereafter contacting the reacting mixture with concentrated nitric acid or nitrogen dioxide. In a special embodiment spent ion exchange resins are converted by this chemical digestion to noncombustible gases and a low volume noncombustible residue.

  7. Radiation Effects in Nuclear Waste Materials

    SciTech Connect (OSTI)

    Weber, William J.

    2005-09-30

    The objective of this project is to develop a fundamental understanding of radiation effects in glasses and ceramics, as well as the influence of solid-state radiation effects on aqueous dissolution kinetics, which may impact the performance of nuclear waste forms and stabilized nuclear materials. This work provides the underpinning science to develop improved glass and ceramic waste forms for the immobilization and disposition of high-level tank waste, excess plutonium, plutonium residues and scrap, other actinides, and other nuclear waste streams. Furthermore, this work is developing develop predictive models for the performance of nuclear waste forms and stabilized nuclear materials. Thus, the research performed under this project has significant implications for the immobilization of High-Level Waste (HLW) and Nuclear Materials, two mission areas within the Office of Environmental Management (EM). With regard to the HLW mission, this research will lead to improved understanding of radiation-induced degradation mechanisms and their effects on dissolution kinetics, as well as development of predictive models for waste form performance. In the Nuclear Materials mission, this research will lead to improvements in the understanding of radiation effects on the chemical and structural properties of materials for the stabilization and long-term storage of plutonium, highly-enriched uranium, and other actinides. The research uses plutonium incorporation, ion-beam irradiation, and electron-beam irradiation to simulate the effects of alpha decay and beta decay on relevant glasses and ceramics. The research under this project has the potential to result in improved glass and ceramic materials for the stabilization and immobilization of high-level tank waste, plutonium residues and scraps, surplus weapons plutonium, highly-enriched uranium, other actinides, and other radioactive materials.

  8. Radiation Effects in Nuclear Waste Materials

    SciTech Connect (OSTI)

    Weber, William J.

    2005-06-01

    The objective of this project is to develop a fundamental understanding of radiation effects in glasses and ceramics, as well as the influence of solid-state radiation effects on aqueous dissolution kinetics, which may impact the performance of nuclear waste forms and stabilized nuclear materials. This work provides the underpinning science to develop improved glass and ceramic waste forms for the immobilization and disposition of high-level tank waste, excess plutonium, plutonium residues and scrap, other actinides, and other nuclear waste streams. Furthermore, this work is developing develop predictive models for the performance of nuclear waste forms and stabilized nuclear materials. Thus, the research performed under this project has significant implications for the immobilization of High-Level Waste (HLW) and Nuclear Materials, two mission areas within the Office of Environmental Management (EM). With regard to the HLW mission, this research will lead to improved understanding of radiation-induced degradation mechanisms and their effects on dissolution kinetics, as well as development of predictive models for waste form performance. In the Nuclear Materials mission, this research will lead to improvements in the understanding of radiation effects on the chemical and structural properties of materials for the stabilization and long-term storage of plutonium, highly-enriched uranium, and other actinides. The research uses plutonium incorporation, ion-beam irradiation, and electron-beam irradiation to simulate the effects of alpha decay and beta decay on relevant glasses and ceramics. The research under this project has the potential to result in improved glass and ceramic materials for the stabilization and immobilization of high-level tank waste, plutonium residues and scraps, surplus weapons plutonium, highly-enriched uranium, other actinides, and other radioactive materials.

  9. U.S. Residual Fuel Oil Refiner Sales Volumes

    U.S. Energy Information Administration (EIA) Indexed Site

    Product: Residual Fuel Oil Residual F.O., Sulfur <= 1% Residual F.O., Sulfur > 1% No. 4 Fuel Oil Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product Sales Type Area Jan-16 Feb-16 Mar-16 Apr-16 May-16 Jun-16 View History Sales to End Users 4,103.1 3,860.0 4,053.4 4,238.4 3,888.8 3,799.0 1983-2016 Sales for Resale 9,292.6 9,338.0 9,180.7 8,984.8 9,875.7 8,936.2

  10. Residual stresses and plastic deformation in GTA-welded steel

    SciTech Connect (OSTI)

    Brand, P.C. ); Keijser, T.H. de; Ouden, G. den )

    1993-03-01

    Residual stresses and plastic deformation in single pass GTA welded low-carbon steel were studied by means of x-ray diffraction in combination with optical microscopy and hardness measurements. The residual stresses and the amount of plastic deformation (microstrain) were obtained from x-ray diffraction line positions and line broading. Since the plates were polished before welding, it was possible to observe in the optical microscope two types of Lueders bands. During heating curved Lueders bands and during cooling straight Lueders bands perpendicular to the weld are formed. The curved Lueders bands extend over a larger distance from the weld than the straight Lueders bands. The amount of plastic deformation as obtained from the x-ray diffraction analysis is in agreement with these observations. An explanation is offered for the stresses measured in combination with plastic deformations observed. It is concluded that in the present experiments plastic deformation is the main cause of the residual stresses.

  11. Characterization of Residual Medium Peptides from Yersinia pestis Cultures

    SciTech Connect (OSTI)

    Clowers, Brian H.; Wunschel, David S.; Kreuzer, Helen W.; Engelmann, Heather E.; Valentine, Nancy B.; Wahl, Karen L.

    2013-04-03

    Using a range of common microbial medium formulations (TSB, BHI, LB, and G-media), two attenuated strains of Y. pestis (KIM D27 (pgm-) and KIMD1 lcr-) were cultivated in triplicate. These cellular suspensions were used to develop a method of extracting residual medium peptides from the final microbial preparation to assess their relative abundance and identity. Across the conditions examined, which included additional cellular washing and different forms of microbial inactivation, residual medium peptides were detected. Despite the range of growth medium sources used and the associated manufacturing processes used in their production, a high degree of peptide similarity was observed for a given medium recipe. These results demonstrate that residual medium peptides are retained using traditional microbial cultivation techniques and may be used to inform forensic investigations with respect to production deduction.

  12. Study on rheological characteristics of petroleum coke residual oil slurry

    SciTech Connect (OSTI)

    Shou Weiyi; Xu Xiaoming; Cao Xinyu

    1997-07-01

    We have embarked on a program to develop petroleum coke residual oil slurry (POS) as an alternative fuel for existing oil-fired boilers. The industrial application of petroleum coke residual oil slurry requires full knowledge of its flow behavior. This paper will present the results of an experimental investigation undertaken to study the Theological properties using a rotating viscometer at shear rate up to 996 s{sup -1}. The effects of temperature, concentration, particle size distribution and additives are also investigated. The experiments show that petroleum coke residual oil slurry exhibits pseudoplastic behavior, which has favorable viscosity property under a certain condition and has broad prospect to be applied on oil-fired boilers.

  13. SOLID PHASE MICROEXTRACTION SAMPLING OF HIGH EXPLOSIVE RESIDUES IN THE PRESENCE OF RADIONUCLIDES AND RADIONUCLIDE SURROGATE METALS

    SciTech Connect (OSTI)

    Duff, M; S Crump, S; Robert02 Ray, R; Donna Beals, D

    2007-04-13

    The Federal Bureau of Investigation (FBI) Laboratory currently does not have on site facilities for handling radioactive evidentiary materials and there are no established FBI methods or procedures for decontaminating high explosive (HE) evidence while maintaining evidentiary value. One experimental method for the isolation of HE residue involves using solid phase microextraction or SPME fibers to remove residue of interest. Due to their high affinity for organics, SPME fibers should have little affinity for most metals. However, no studies have measured the affinity of radionuclides for SPME fibers. The focus of this research was to examine the affinity of dissolved radionuclide ({sup 239/240}Pu, {sup 238}U, {sup 237}Np, {sup 85}Sr, {sup 133}Ba, {sup 137}Cs, {sup 60}Co and {sup 226}Ra) and stable radionuclide surrogate metals (Sr, Co, Ir, Re, Ni, Ba, Cs, Nb, Zr, Ru, and Nd) for SPME fibers at the exposure conditions that favor the uptake of HE residues. Our results from radiochemical and mass spectrometric analyses indicate these metals have little measurable affinity for these SPME fibers during conditions that are conducive to HE residue uptake with subsequent analysis by liquid or gas phase chromatography with mass spectrometric detection.

  14. Building America Case Study: Retrofit Measure for Embedded Wood Members in Insulated Mass Masonry Walls, Lawrence, Massachusetts

    SciTech Connect (OSTI)

    2015-10-01

    ?There are many existing buildings with load-bearing mass masonry walls, whose energy performance could be improved with the retrofit of insulation. However, adding insulation to the interior side of walls of such masonry buildings in cold (and wet) climates may cause performance and durability problems. Some concerns, such as condensation and freeze-thaw have known solutions. But wood members embedded in the masonry structure will be colder (and potentially wetter) after an interior insulation retrofit. Moisture content and relative humidity were monitored at joist ends in historic mass brick masonry walls retrofitted with interior insulation in a cold climate (Zone 5A); data were collected from 2012-2015. Eleven joist ends were monitored in all four orientations. One limitation of these results is that the renovation is still ongoing, with limited wintertime construction heating and no permanent occupancy to date. Measurements show that many joists ends remain at high moisture contents, especially at north- and east-facing orientations, with constant 100 percent RH conditions at the worst cases. These high moisture levels are not conducive for wood durability, but no evidence for actual structural damage has been observed. Insulated vs. non-insulated joist pockets do not show large differences. South facing joists have safe (10-15 percent) moisture contents. Given the uncertainty pointed out by research, definitive guidance on the vulnerability of embedded wood members is difficult to formulate. In high-risk situations, or when a very conservative approach is warranted, the embedded wood member condition can be eliminated entirely, supporting the joist ends outside of the masonry pocket.

  15. Cell Wall Ultrastructure of Stem Wood, Roots, and Needles of a Conifer Varies in Response to Moisture Availability

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pattathil, Sivakumar; Ingwers, Miles W.; Victoriano, Olivia L.; Kandemkavil, Sindhu; McGuire, Mary Anne; Teskey, Robert O.; Aubrey, Doug P.

    2016-06-24

    The composition, integrity, and architecture of the macromolecular matrix of cell walls, collectively referred to as cell wall ultrastructure, exhibits variation across species and organs and among cell types within organs. Indirect approaches have suggested that modifications to cell wall ultrastructure occur in response to abiotic stress; however, modifications have not been directly observed. Glycome profiling was used to study cell wall ultrastructure by examining variation in composition and extractability of non-cellulosic glycans in cell walls of stem wood, roots, and needles of loblolly pine saplings exposed to high and low soil moisture. Soil moisture influenced physiological processes and themore » overall composition and extractability of cell wall components differed as a function of soil moisture treatments. The strongest response of cell wall ultrastructure to soil moisture was increased extractability of pectic backbone epitopes in the low soil moisture treatment. The higher abundance of these pectic backbone epitopes in the oxalate extract indicate that the loosening of cell wall pectic components could be associated with the release of pectic signals as a stress response. The increased extractability of pectic backbone epitopes in response to low soil moisture availability was more pronounced in stem wood than in roots or needles. Additional responses to low soil moisture availability were observed in lignin associated carbohydrates released in chlorite extracts of stem wood, including an increased abundance of pectic arabinogalactan epitopes. Overall, these results indicate that cell walls of loblolly pine organs undergo changes in their ultrastructural composition and extractability as a response to soil moisture availability and that cell walls of the stem wood are more responsive to low soil moisture availability compared to cell walls of roots and needles. In conclusion, to our knowledge, this is the first direct evidence, delineated by

  16. Composite material dosimeters

    DOE Patents [OSTI]

    Miller, Steven D.

    1996-01-01

    The present invention is a composite material containing a mix of dosimeter material powder and a polymer powder wherein the polymer is transparent to the photon emission of the dosimeter material powder. By mixing dosimeter material powder with polymer powder, less dosimeter material is needed compared to a monolithic dosimeter material chip. Interrogation is done with excitation by visible light.

  17. Enhanced flexoelectricity through residual ferroelectricity in barium strontium titanate

    SciTech Connect (OSTI)

    Garten, Lauren M. Trolier-McKinstry, Susan

    2015-03-07

    Residual ferroelectricity is observed in barium strontium titanate ceramics over 30 °C above the global phase transition temperature, in the same temperature range in which anomalously large flexoelectric coefficients are reported. The application of a strain gradient leads to strain gradient-induced poling or flexoelectric poling. This was observed by the development of a remanent polarization in flexoelectric measurements, an induced d{sub 33} piezoelectric response even after the strain gradient was removed, and the production of an internal bias of 9 kV m{sup −1}. It is concluded that residual ferroelectric response considerably enhances the observed flexoelectric response.

  18. Evidence for residual elastic strain in deformed natural quartz

    SciTech Connect (OSTI)

    Kunz, Martin; Chen, Kai; Tamura,Nobumichi; Wenk, Hans-Rudolf

    2009-01-30

    Residual elastic strain in naturally deformed, quartz-containing rocks can be measured quantitatively in a petrographic thin section with high spatial resolution using Laue microdiffraction with white synchrotron x-rays. The measurements with a resolution of one micrometer allow the quantitative determination of the deviatoric strain tensor as a function of position within the crystal investigated. The observed equivalent strain values of 800-1200 microstrains represent a lower bound of the actual preserved residual strain in the rock, since the stress component perpendicular to the cut sample surface plane is released. The measured equivalent strain translates into an equivalent stress in the order of {approx} 50 MPa.

  19. Melting of Uranium Metal Powders with Residual Salts

    SciTech Connect (OSTI)

    Jin-Mok Hur; Dae-Seung Kang; Chung-Seok Seo

    2007-07-01

    The Advanced Spent Fuel Conditioning Process (ACP) of the Korea Atomic Energy Research Institute focuses on the conditioning of Pressurized Water Reactor spent oxide nuclear fuel. After the oxide reduction step of the ACP, the resultant metal powders containing {approx} 30 wt% residual LiCl-Li{sub 2}O should be melted for a consolidation of the fine metal powders. In this study, we investigated the melting behaviors of uranium metal powders considering the effects of a LiCl-Li{sub 2}O residual salt. (authors)

  20. Method for forming materials

    DOE Patents [OSTI]

    Tolle, Charles R.; Clark, Denis E.; Smartt, Herschel B.; Miller, Karen S.

    2009-10-06

    A material-forming tool and a method for forming a material are described including a shank portion; a shoulder portion that releasably engages the shank portion; a pin that releasably engages the shoulder portion, wherein the pin defines a passageway; and a source of a material coupled in material flowing relation relative to the pin and wherein the material-forming tool is utilized in methodology that includes providing a first material; providing a second material, and placing the second material into contact with the first material; and locally plastically deforming the first material with the material-forming tool so as mix the first material and second material together to form a resulting material having characteristics different from the respective first and second materials.