Sample records for material substitution ii

  1. Wet-Weather Pollution Prevention through Materials Substitution

    E-Print Network [OSTI]

    Clark, Shirley E.

    1 Wet-Weather Pollution Prevention through Materials Substitution Shirley E. Clark, Ph.D., P the potential pollutant release from common building materials both when the materials are new and after aging often used to increase the operating range of asphalts and to prevent stripping of asphalt from binders

  2. Managing Category I and II Asbestos-Containing Materials During...

    Energy Savers [EERE]

    Managing Category I and II Asbestos-Containing Materials During Decontamination and Demolition Managing Category I and II Asbestos-Containing Materials During Decontamination and...

  3. Reactor materials study of EBR-II and BN350

    E-Print Network [OSTI]

    Yilmaz, Fatma

    2002-01-01T23:59:59.000Z

    The objective of this research is to go through the technical review of how the body of information relating to the in-reactor behavior of structural materials of Experimental Breeder Reactor-II (EBR-II) and BN350 are associated. Such an effort...

  4. Synthesis and single-crystal X-ray diffraction studies of new framework substituted type II clathrates, Cs{sub 8}Na{sub 16}Ag{sub x}Ge{sub 136-x} (x<7)

    SciTech Connect (OSTI)

    Beekman, M. [Department of Physics, University of South Florida, 4202 East Fowler Ave., PHY 114, Tampa, FL 33620 (United States); Wong-Ng, W. [Materials Science and Engineering Laboratory, National Institute of Standards and Technology, Gaithersburg, MD 20899 (United States); Kaduk, J.A. [INEOS Technologies, Naperville, IL 60566 (United States); Shapiro, A. [Materials Science and Engineering Laboratory, National Institute of Standards and Technology, Gaithersburg, MD 20899 (United States); Nolas, G.S. [Department of Physics, University of South Florida, 4202 East Fowler Ave., PHY 114, Tampa, FL 33620 (United States)], E-mail: gnolas@cas.usf.edu

    2007-03-15T23:59:59.000Z

    New inorganic type II clathrates with Ag atoms substituting for framework Ge atoms, Cs{sub 8}Na{sub 16}Ag{sub x}Ge{sub 136-x} (x=0, 5.9, and 6.7), have been synthesized by reaction of the pure elements at high temperature. Structural refinements have been performed using single crystal X-ray diffraction. The materials crystallize with the cubic type II clathrate crystal structure (space group Fd3-barm) with a=15.49262(9)A, 15.51605(6)A, and 15.51618(9) for x=0, 5.9, and 6.7, respectively, and Z=1. The structure is formed by a covalently bonded Ag-Ge framework, in which the Cs and Na atoms are found inside two types of polyhedral cages. Ag substitutes for Ge in the tetrahedrally bonded framework positions, and was found to preferentially occupy the most asymmetric 96g site. The proven ability to substitute atoms for the germanium framework should offer a route to the synthesis of new compositions of type II clathrates, materials that are of interest for potential thermoelectrics applications.

  5. Solvent substitution

    SciTech Connect (OSTI)

    Not Available

    1990-01-01T23:59:59.000Z

    The DOE Environmental Restoration and Waste Management Office of Technology Development and the Air Force Engineering and Services Center convened the First Annual International Workshop on Solvent Substitution on December 4--7, 1990. The primary objectives of this joint effort were to share information and ideas among attendees in order to enhance the development and implementation of required new technologies for the elimination of pollutants associated with industrial use of hazardous and toxic solvents; and to aid in accelerating collaborative efforts and technology transfer between government and industry for solvent substitution. There were workshop sessions focusing on Alternative Technologies, Alternative Solvents, Recovery/Recycling, Low VOC Materials and Treatment for Environmentally Safe Disposal. The 35 invited papers presented covered a wide range of solvent substitution activities including: hardware and weapons production and maintenance, paint stripping, coating applications, printed circuit boards, metal cleaning, metal finishing, manufacturing, compliance monitoring and process control monitoring. This publication includes the majority of these presentations. In addition, in order to further facilitate information exchange and technology transfer, the US Air Force and DOE solicited additional papers under a general Call for Papers.'' These papers, which underwent review and final selection by a peer review committee, are also included in this combined Proceedings/Compendium. For those involved in handling, using or managing hazardous and toxic solvents, this document should prove to be a valuable resource, providing the most up-to-date information on current technologies and practices in solvent substitution. Individual papers are abstracted separated.

  6. The Impact of Aluminum and Iron Substitution on the Structure and Electrochemistry of Li[Ni0.4Co0.2-yMyMn0.4]O2 Materials

    E-Print Network [OSTI]

    WIlcox, James D.

    2010-01-01T23:59:59.000Z

    The Impact of Aluminum and Iron Substitution on theThe incorporation of aluminum has minimal effect on theThe cycling stability of aluminum containing materials is

  7. American Material Culture: Investigating a World War II Trash Dump

    SciTech Connect (OSTI)

    Julie Braun

    2005-10-01T23:59:59.000Z

    The Idaho National Laboratory: An Historical Trash Trove Historians and archaeologists love trash, the older the better. Sometimes these researchers find their passion in unexpected places. In this presentation, the treasures found in a large historic dump that lies relatively untouched in the middle of the Idaho National Laboratory (INL) will be described. The U.S. military used the central portion of the INL as one of only six naval proving grounds during World War II. They dumped trash in dry irrigation canals during and after their wartime activities and shortly before the federal government designated this arid and desolate place as the nation’s nuclear reactor testing station in 1949. When read critically and combined with memories and photographs, the 60-year old trash provides a glimpse into 1940s’ culture and the everyday lives of ordinary people who lived and worked during this time on Idaho’s desert. Thanks to priceless stories, hours of research, and the ability to read the language of historic artifacts, the dump was turned from just another trash heap into a treasure trove of 1940s memorabilia. Such studies of American material culture serve to fire our imaginations, enrich our understanding of past practices, and humanize history. Historical archaeology provides opportunities to integrate inanimate objects with animated narrative and, the more recent the artifacts, the more human the stories they can tell.

  8. Advances in Materials Science for Environmental and Energy Technologies II

    SciTech Connect (OSTI)

    Matyas, Dr Josef [Pacific Northwest National Laboratory (PNNL); Ohji, Tatsuki [Advanced Manufacturing Research Institute, National Institute of Advanced Industrial Science and Tec; Liu, Xingbo [West Virginia University, Morgantown; Paranthaman, Mariappan Parans [ORNL; Devanathan, Ram [Pacific Northwest National Laboratory (PNNL); Fox, Kevin [Savannah River National Laboratory (SRNL); Singh, Mrityunjay [NASA-Glenn Research Center, Cleveland; Wong-ng, Winnie [National Institute of Standards and Technology (NIST), Gaithersburg, MD

    2013-01-01T23:59:59.000Z

    The Materials Science and Technology 2012 Conference and Exhibition (MS&T'12) was held October 7-11, 2012, in Pittsburgh, Pennsylvania. One of the major themes of the conference was Environmental and Energy Issues. Papers from five of the symposia held under that theme are invluded in this volume. These symposia included Materials Issues in Nuclear Waste Management for the 21st Century; Green Technologies for Materials Manufacturing and Processing IV; Energy Storage: Materials, Systems and Applications; Energy Conversion-Photovoltaic, Concentraing Solar Power and Thermoelectric; and Materials Development for Nuclear Applications and Extreme Environments.

  9. Iron(II) and Copper(I) Coordination Polymers: Electrochromic Materials with and without Chiroptical Properties

    E-Print Network [OSTI]

    Bernhard, Stefan

    Iron(II) and Copper(I) Coordination Polymers: Electrochromic Materials with and without Chiroptical of deterioration over 150 switching cycles. Additionally, in an effort to assemble an electrochromic device with chiroptical properties, the electrochromism of films generated from the enantiomerically pure CTPCT[FeII CTPCT

  10. Great Lakes Spatially Distributed Watershed Model of Water and Materials Runoff Thomas E. Croley II

    E-Print Network [OSTI]

    Great Lakes Spatially Distributed Watershed Model of Water and Materials Runoff Thomas E. Croley II.S. Environmental Protection Agency (EPA) has identified contaminated sediments, urban runoff and storm sewers there are no integrated spatially distributed physically based watershed-scale hydrological/water quality models available

  11. Selection and evaluation of materials for thermoelectric applications II

    SciTech Connect (OSTI)

    Sharp, J.W.

    1997-07-01T23:59:59.000Z

    In good thermoelectrics phonons have short mean free paths, and charge carriers have long ones. The other requirements are a multivalley band structure and a band gap greater than 0.1 eV for the 200 to 300 K temperature range. The author discusses the use of solid state physics and chemistry concepts, along with atomic and crystal structure data, to select the new materials most likely to meet these criteria.

  12. Multi-Component Copper Catalyzed Methods to Access Highly-Substituted Amine-Bearing Carbon Centers from Simple Starting Materials

    E-Print Network [OSTI]

    Pierce, Conor John

    2013-01-01T23:59:59.000Z

    123 Chapter 3: Copper/Titanium Catalysis Forms Fully-187 vi Chapter 4: Copper-Catalyzed Tandem Markovnikov237 III. Copper(II) Triflate in Dual-Catalytic Role is

  13. Cavitation in elastomeric solids: II--Onset-of-cavitation surfaces for Neo-Hookean materials

    E-Print Network [OSTI]

    Lopez-Pamies, Oscar

    Cavitation in elastomeric solids: II--Onset-of-cavitation surfaces for Neo-Hookean materials Oscar a fairly general theory of cavitation in elastomeric solids based on the sudden growth of pre-existing defects. In this article, the theory is used to determine onset-of-cavitation surfaces for Neo

  14. Cavitation in elastomeric solids: II--Onset-of-cavitation surfaces for Neo-Hookean materials

    E-Print Network [OSTI]

    Nakamura, Toshio

    Cavitation in elastomeric solids: II--Onset-of-cavitation surfaces for Neo-Hookean materials Oscar of cavitation in elastomeric solids based on the sudden growth of pre-existing defects. In this article, the theory is used to determine onset-of-cavitation surfaces for Neo-Hookean solids where the defects

  15. 0-D and 1-D inorganic-organic composite polyoxotungstates constructed from in-situ generated monocopper{sup II}-substituted Keggin polyoxoanions and copper{sup II}-organoamine complexes

    SciTech Connect (OSTI)

    Zhao Junwei; Zheng Shoutian [State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter and Graduate School of the Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China); Yang Guoyu [State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter and Graduate School of the Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China)], E-mail: guoyu.yang@hotmail.com

    2008-09-15T23:59:59.000Z

    Combination of in-situ generated monocopper{sup II}-substituted Keggin polyoxoanions with copper{sup II}-organoamine complexes under hydrothermal conditions results in seven inorganic-organic composite polyoxotungstates [Cu(en){sub 2}(H{sub 2}O)]{sub 2}{l_brace}[Cu(en){sub 2}][{alpha}-PCuW{sub 11}O{sub 39}Cl]{r_brace}.3H{sub 2}O (1), {l_brace}[Cu(en){sub 2}(H{sub 2}O)][Cu(en){sub 2}]{sub 2}[{alpha}-PCuW{sub 11}O{sub 39}Cl]{r_brace}.6H{sub 2}O (2), {l_brace}[Cu(en){sub 2}(H{sub 2}O)]{sub 2}[Cu(en){sub 2}][{alpha}-XCuW{sub 11}O{sub 39}]{r_brace}.5H{sub 2}O (3/4, X=Si{sup IV}/Ge{sup IV}), {l_brace}[Cu(deta)(H{sub 2}O){sub 2}]{sub 2}[Cu(deta)(H{sub 2}O)][{alpha}-XCuW{sub 11}O{sub 39}]{r_brace}.5H{sub 2}O (5/6, X=Ge{sup IV}/Si{sup IV}) and [Cu(dap){sub 2}]{sub 2}{l_brace}[Cu(dap){sub 2}]{sub 2}[Cu(dap){sub 2}][{alpha}-PCuW{sub 11}O{sub 39}]{sub 2}{r_brace} (7) (en=ethylenediamine, dap=1,2-diaminopropane and deta=diethylenetriamine). 1 is an isolated structure whereas 2 is a 1-D chain structure, but both contain [{alpha}-PCuW{sub 11}O{sub 39}Cl]{sup 6-} polyoxoanions. 3-6 contain the 1-D linear chains made up of [{alpha}-XCuW{sub 11}O{sub 39}]{sup 6-} polyoxoanions in the pattern of -A-A-A- (A=[{alpha}-XCuW{sub 11}O{sub 39}]{sup 6-}), while 7 demonstrates the first 1-D zigzag chain constructed from [{alpha}-PCuW{sub 11}O{sub 39}]{sub 2}{sup 10-} polyoxoanions via [Cu(en){sub 2}]{sup 2+} bridges in the pattern of -A-B-A-B- (A=[{alpha}-PCuW{sub 11}O{sub 39}]{sub 2}{sup 10-}, B=[Cu(en){sub 2}]{sup 2+}). The successful syntheses of 1-7 can provide some experimental evidences that di-/tri-/hexa-vacant polyoxoanions can be transformed into mono-vacant Keggin polyoxoanions under hydrothermal conditions. - Graphical abstract: A family of inorganic-organic composite polyoxotugstates have been harvested by combination of in-situ generated monocopper{sup II}-substituted Keggin polyoxoanions and copper{sup II}-organoamine complexes based on di-/tri-/hexa-vacant polyoxoanion precursors, CuCl{sub 2}.2H{sub 2}O and organoamines under hydrothermal conditions and structurally characterized by the elemental analysis, IR spectroscopy, TGA and single-crystal X-ray crystallography.

  16. The Impact of Aluminum and Iron Substitution on the Structure and Electrochemistry of Li[Ni0.4Co0.2-yMyMn0.4]O2 Materials

    SciTech Connect (OSTI)

    WIlcox, James D.; Rodriguez, Efrain E.; Doeff, Marca M.

    2009-07-23T23:59:59.000Z

    Li[Ni0.4Co0.2-yMyMn0.4]O2 (0<_y<_0.2) (M=Al) and Li[Ni0.4Co0.15Fe0.05Mn0.4]O2 compounds were prepared in order to investigate the effect of replacement of all or part of the cobalt on the structural and electrochemical properties. The impact of substitution on the structure has been examined by both x-ray and neutron diffraction experiments. The incorporation of aluminum has minimal effect on the anti-site defect concentration, but leads to structural changes that affect electrochemical performance. The most important effect is an opening of the lithium slab dimension upon substitution, which results in improved rate performance compared to the parent compound. In contrast, the lithium slab dimension is not affected by iron substitution and no rate enhancement effect is observed. The cycling stability of aluminum containing materials is superior to both the parent material and iron-substituted materials.

  17. Developing Substitutes | Critical Materials Institute

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to UserProduct: CrudeOfficeNERSC Helps Develop Next-Gen Batteries

  18. Role of minerals in thermal alteration of organic matter. II. A material balance

    SciTech Connect (OSTI)

    Tannenbaum, E.; Huizinga, B.J.; Kaplan, I.R.

    1986-09-01T23:59:59.000Z

    Pyrolysis experiments were performed on Green River and Monterey Formation kerogens (Types I and II, respectively) with and without calcite, illite, or montmorillonite at 300/sup 0/C for 2 to 1000 hours under dry and hydrous conditions. Pyrolysis products were identified and quantified, and a material balance of product and reactants resulted. Applying the results to maturation of organic matter in natural environments, they suggest that a given type of organic matter associated with different minerals in source rocks will yield different products. Furthermore, the different adsorption capacities of minerals exert a significant influence on the migration of polar and high molecular weight compounds generated from the breakdown of kerogen. Therefore, the overall accumulated products from carbonate source rocks are mainly heavy oils with some gas, whereas light oils and gases are the main products from source rocks that contain expandable clays with catalytic and adsorptive properties. 8 figures, 2 tables.

  19. Electrode Materials with the Na0.44MnO2 Structure: Effect ofTitanium Substitution on Physical and Electrochemical Properties

    SciTech Connect (OSTI)

    Doeff, Marca M; Saint, Juliette A.; Doeff, Marca M; Wilcox, James D.

    2008-03-10T23:59:59.000Z

    The physical and electrochemical properties of LixMnO2 and LixTi0.11Mn0.89O2 synthesized from precursors made by glycine-nitrate combustion (GNC) and solid-state synthesis methods (SS) are examined in this paper. The highest specific capacities in lithium cells are obtained for SS-LixMnO2 electrodes at low current densities, but GNC-LixTi0.11Mn0.89O2 electrodes show the best high rate performance. These results can be explained by changes in the voltage characteristics and differences in the particle morphologies induced by the Ti-substitution and synthesis method. Ti-substitution also results in a decrease in the electronic conductivity, but greatly improves the thermal properties and imparts dissolution resistance to the electrode. For these reasons, it is preferable to use LixTi0.11MnO0.89O2 in lithium battery configurations rather than LixMnO2. Suggestions for improving the electrochemical performance of the Ti-substituted variant are given based on the results described herein.

  20. Ii.

    Office of Scientific and Technical Information (OSTI)

    sponsorship of the Materials Division of ASME in conjunction with the Mechanical Metallurgy Committee of AIME. Personne l Connecte d with Contract 1. Professor ial Staff: J....

  1. Critical Materials Institute

    ScienceCinema (OSTI)

    Alex King

    2013-06-05T23:59:59.000Z

    Ames Laboratory Director Alex King talks about the goals of the Critical Materials Institute in diversifying the supply of critical materials, developing substitute materials, developing tools and techniques for recycling critical materials, and forecasting materials needs to avoid future shortages.

  2. Lower Cost Lithium Ion Batteries From Aluminum Substituted Cathode...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lower Cost Lithium Ion Batteries From Aluminum Substituted Cathode Materials Lawrence Berkeley National Laboratory Contact LBL About This Technology Technology Marketing...

  3. II

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$0.C. 20545*. . : '* FEB1f\lMUC4cb90,fioml7aa AMY yII

  4. II

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$0.C. 20545*. . : '* FEB1f\lMUC4cb90,fioml7aa AMY yII

  5. INFORMATION: Inspection Report on "Removal of Categories I and II Special Nuclear Material from Sandia National Laboratories-New Mexico"

    SciTech Connect (OSTI)

    None

    2010-01-01T23:59:59.000Z

    The Department of Energy's (DOE's) Sandia National Laboratories-New Mexico (Sandia) develops science-based technologies in support of national security in areas such as nuclear weapons, nonproliferation, military technologies, and homeland security. Sandia's primary mission is ensuring that the U.S. nuclear arsenal is safe, secure, and reliable and can fully support the Nation's deterrence policy. Part of this mission includes systems engineering of nuclear weapons; research, design, and development of non-nuclear components; manufacturing of non-nuclear weapons components; the provision of safety, security, and reliability assessments of stockpile weapons; and the conduct of high-explosives research and development and environmental testing. Sandia Corporation, a subsidiary of Lockheed Martin Corporation, operates Sandia for the National Nuclear Security Administration (NNSA). On May 7, 2004, the Secretary announced that the Department would evaluate missions at DOE sites to consolidate Special Nuclear Material (SNM) in the most secure environments possible. The Administrator of the NNSA said that this effort was a key part of an overall plan to transform the nuclear weapons complex into a smaller, safer, more secure, and more efficient national security enterprise. In February 2008, Sandia was the first site to report it had reduced its on-site inventory of nuclear material below 'Categories I and II' levels, which require the highest level of security to protect material such as plutonium and highly enriched uranium. The Office of Inspector General initiated an inspection to determine if Sandia made appropriate adjustments to its security posture in response to the removal of the Categories I and II SNM. We found that Sandia adjusted its security posture in response to the removal of Categories I and II SNM. For example, security posts were closed; unneeded protective force weapons and equipment were excessed from the site; and, Sandia's Site Safeguards and Security Plan was modified. We also found that some highly enriched uranium in a complex material configuration was not removed from Sandia. This material was designated as Category III material using a methodology for assessing the attractiveness of complex materials that was not specifically addressed in any current DOE directive. Although DOE and NNSA officials believed that this designation was appropriate, the methodology used to support this designation had not, as of the time of our review, been incorporated into the DOE directives system. Historically, the Department has considered the categorization of SNM to be an important national security and public policy issue. Consequently, we believe that expedited action should be taken to formalize this methodology in the DOE directives system and that it be disseminated throughout the Department of Energy complex.

  6. On the Symmetry of Energy Minimising Deformations in Nonlinear Elasticity II: Compressible Materials

    E-Print Network [OSTI]

    Sivaloganathan, J.

    On the Symmetry of Energy Minimising Deformations in Nonlinear Elasticity II: Compressible that has less elastic energy than the given deformation, provided that the stored-energy function, of radius R > 0, centred at the origin into another such sphere Sr = urad (SR) A that encloses the same

  7. Materials for electrochemical energy storage and conversion II -- Batteries, capacitors and fuel cells. Materials Research Society symposium proceedings, Volume 496

    SciTech Connect (OSTI)

    Ginley, D.S.; Doughty, D.H.; Scrosati, B.; Takamura, T.; Zhang, Z.J. [eds.

    1998-07-01T23:59:59.000Z

    Our energy-hungry world is increasingly relying on new methods to store and convert energy for portable electronics, as well as new, environmentally friendly modes of transportation and electrical energy generation. The availability of advanced materials is linked to the commercial success of improved power sources such as batteries, fuel cells and capacitors with higher specific energy and power, longer cycle life and rapid change/discharge rates. The papers in this symposium were heavily weighted toward lithium batteries. The proceedings volume is organized into six sections highlighting: general papers on a wide variety of rechargeable battery technologies; new approaches to modeling of Li batteries; advances in fuel-cell technology; new work on Li battery cathodes; anodes and electrolytes; and work on super-capacitors. The authors think the volume is an excellent snapshot of the current state of the art in energy storage and conversion technologies, many of which will make a significant impact on society. Separate abstracts were prepared for most papers in this volume.

  8. Vehicle Technologies Office Merit Review 2014: Multi-Material Lightweight Vehicles: Mach II Design

    Broader source: Energy.gov [DOE]

    Presentation given by VEHMA at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about multi-material lightweight vehicles:...

  9. Growth, spectral and thermal studies of an efficient NLO material: Diaquadicinnamatocadmium(II)

    SciTech Connect (OSTI)

    Roy, Sunalya M.; Sudarsanakumar, M. R.; Dhanya, V. S. [Department of Chemistry, Mahatma Gandhi College, Thiruvananthapuram 695004, Kerala (India)

    2014-01-28T23:59:59.000Z

    A nonlinear metal–organic crystal, diaquadicinnamatocadmium(II) has been grown by controlled gel diffusion technique. Sodium metasilicate was used to prepare the gel. The chemical composition of the crystal has been determined by CHN analysis. Powder X-ray diffraction studies confirm the crystalline nature of the grown crystal. Functional groups present in the compound were identified by FT-IR spectral analysis. The thermal decomposition of the compound was studied using thermogravimetry (TG). The optical transparency range and the lower cut-off wavelength were identified from the UV-Visible-NIR spectrum. The NLO activity of the grown crystal was confirmed using Kurtz and Perry powder test.

  10. Layered manganese oxide intergrowth electrodes for rechargeable lithium batteries: Part 1-substitution with Co or Ni

    E-Print Network [OSTI]

    Dolle, Mickael; Patoux, Sebastien; Doeff, Marca M.

    2004-01-01T23:59:59.000Z

    Cathode Materials for Lithium Batteries, 2003, Massachusettsfor Rechargeable Lithium Batteries: Part 1-Substitution withelectrode materials for lithium batteries because of their

  11. Economic evaluation of closure CAP barrier materials Volume I and Volume II

    SciTech Connect (OSTI)

    Serrato, M.G.; Bhutani, J.S.; Mead, S.M.

    1993-09-01T23:59:59.000Z

    This study prepared by the Site Geotechnical Services (SGS) and Environmental Restoration (ER) departments of the WSRC evaluates a generic closure cover system for a hazardous waste site, using 10 different surface areas, ranging from 0.1 acre to 80 acres, and 12 barrier materials. This study presents a revision to the previous study (Rev. 0) published in June 1993, under the same title. The objective of this study was to revise the previous study by incorporating four additional site sizes into the evaluation process and identifying the most cost-effective barrier material for a given closure cover system at the SRS.

  12. Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 MAG LAB REPORTS Volume 18 No. 1 CONDENSED MATTER SCIENCE Technique development, graphene, magnetism & magnetic materials, topological insulators, quantum fl uids & solids,...

  13. Staff summary of Issues & Recommendations Resident Fish Substitution/Blocked Area Mitigation

    E-Print Network [OSTI]

    1 Staff summary of Issues & Recommendations Resident Fish Substitution/Blocked Area Mitigation *Preliminary draft, please refer to full recommendations for complete review 10/29/2013 10:08:05 AM 2009 Fish and Wildlife Program Section Section II.C. 1. Substitution for Anadromous Fish Losses Section II. D. 8

  14. Subsolidus sintering of SYNROC: II. Materials selections, process improvements, waste form evaluations

    SciTech Connect (OSTI)

    Palmour, H. III.; Hare, T.M.; Russ, J.C.; Boss, C.B.; Solomah, A.G.; Batchelor, A.D.

    1981-07-01T23:59:59.000Z

    The principal areas of research were related to materials selections and characterization, process optimizations, crystalline phase development, sinterability, resultant microstructures and evaluations of leaching behavior. With and without simulated radwaste doping, the Modified SYNROC-B formulation was found to be sinterable to technical density (D > 0.95 in the CTS mode) at temperatures in the range 1195/sup 0/C to 1285/sup 0/C, depending upon TiO/sub 2/ and CaCO/sub 3/ materials selections, and upon powder processing methods employed prior to firing. Of the 16 TiO/sub 2/ raw materials evaluated in air-fired, undoped batches, 15 yielded technically dense compacts (D > 0.95). Three fine pigmentary grades of TiO/sub 2/ were selected for further study in doped and undoped versions fired in Ar, 4% H/sub 2/. When intensively milled with other well chosen matrix constituents and 10% spray-calcined simulated waste, each of them yielded sintered densities of greater than or equal to 4.2 g/cm/sup 3/ (D greater than or equal to 0.96) at 1260/sup 0/C, 2h in Ar, 4% H/sub 2/ atmosphere. Leachability studies have been carried out in triple distilled H/sub 2/O according to MCC-1 and MCC-2 procedures at 25/sup 0/ and 150/sup 0/C, respectively, and under ..gamma..-irradiation for dose rates of 2-5 x 10/sup 5/ rad/h at approx. 25/sup 0/C. The results obtained showed that freshly exposed interions of sintered Modified SYNROC-B ceramics were highly stable in the leaching environment, and were very retentive of simulated waste ions, including the most leachable species, Cs. Depending on leaching conditions, the highest Cs leach rates (after 3 days) were on the order of 10/sup -1/ g.m/sup -2/.day/sup -1/, but diminished sharply for longer times (up to 92 days) to the range 10/sup -2/ - 10/sup -4/ g.m/sup -2/.day/sup -1/.

  15. Spectroscopic Study of Silicate-Substituted

    E-Print Network [OSTI]

    Greenaway, Alan

    -substituted Hydroxyapatite sintered at varying temperatures. 0 50 100 150 200 250 300 0 1000 2000 3000 4000 Normalised 350 400 0 1000 2000 3000 4000 NormalisedIntensityCounts Wavenumber (cm-1) method change 3: did material with bone-like features. #12;Grand Scheme of Things 1m 1m Stress = Force/Area Pascal = Newtons

  16. FA 2: Developing Substitutes | Critical Materials Institute

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing ZirconiaPolicy andExsolution Enhanced OilExtracting theExtremeM ^ FF. WardF.1:2:

  17. Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recovery challenge fund LasDubey selectedContract Research Material

  18. A Fast, Versatile Nanoprobe for Complex Materials: The Sub-micron Resolution X-ray Spectroscopy Beamline at NSLS-II (491st Brookhaven Lecture)

    SciTech Connect (OSTI)

    Thieme, Juergen [BNL Photon Sciences Directorate

    2014-02-06T23:59:59.000Z

    Time is money and for scientists who need to collect data at research facilities like Brookhaven Lab’s National Synchrotron Light Source (NSLS), “beamtime” can be a precious commodity. While scanning a complex material with a specific technique and standard equipment today would take days to complete, researchers preparing to use brighter x-rays and the new sub-micron-resolution x-ray spectroscopy (SRX) beamline at the National Synchrotron Light Source II (NSLS-II) could scan the same sample in greater detail with just a few hours of beamtime. Talk about savings and new opportunities for researchers! Users will rely on these tools for locating trace elements in contaminated soils, developing processes for nanoparticles to deliver medical treatments, and much more. Dr. Thieme explains benefits for next-generation research with spectroscopy and more intense x-rays at NSLS-II. He discusses the instrumentation, features, and uses for the new SRX beamline, highlighting its speed, adjustability, and versatility for probing samples ranging in size from millimeters down to the nanoscale. He will talk about complementary beamlines being developed for additional capabilities at NSLS-II as well.

  19. First anniversary gift for Critical Material Institute? Inventions...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to clean energy technologies. The inventions include improved extractive processes, recycling techniques, and substitute materials-technologies designed to increase...

  20. MSE 410: Materials Foundations for Energy Applications MSE 810: Materials for Energy Applications

    E-Print Network [OSTI]

    ; materials for future wind energy needs; thermoelectric materials for solid state energy conversion II: thermoelectric materials Introduction; the design of thermoelectric materials Morelli Jan 31, Feb 2 Module II: thermoelectric materials Thermal and electrical transport properties; model systems

  1. Microsoft Word - TRILATERAL CRITICAL MATERIALS WORKSHOP Summary...

    Energy Savers [EERE]

    efficient and environmentally superior separation and extraction processes, R&D on material substitutes, more efficient use with minimization of waste, and enhanced...

  2. Emissive polymeric materials for optoelectronic devices

    DOE Patents [OSTI]

    Shiang, Joseph John (Niskayuna, NY); Chichak, Kelly Scott (Clifton Park, NY); Cella, James Anthony (Clifton Park, NY); Lewis, Larry Neil (Scotia, NY); Janora, Kevin Henry (Schenectady, NY)

    2011-07-05T23:59:59.000Z

    Polymers including at least one structural unit derived from a compound of formula I or including at least one pendant group of formula II may be used in optoelectronic devices ##STR00001## wherein R.sup.1, R.sup.3, R.sup.4 and R.sup.6 are independently hydrogen, alkyl, alkoxy, oxaalkyl, alkylaryl, aryl, arylalkyl, heteroaryl, substituted alkyl; substituted alkoxy, substituted oxaalkyl, substituted alkylaryl, substituted aryl, substituted arylalkyl, or substituted heteroaryl; R.sup.1a is hydrogen or alkyl; R.sup.2 is alkylene, substituted alkylene, oxaalkylene, CO, or CO.sub.2; R.sup.2a is alkylene; R.sup.5 is independently at each occurrence hydrogen, alkyl, alkylaryl, aryl, arylalkyl, alkoxy, carboxy, substituted alkyl; substituted alkylaryl, substituted aryl, substituted arylalkyl, or substituted alkoxy, X is halo, triflate, --B(OR.sup.1a).sub.2, or ##STR00002## located at the 2, 5- or 2, 7-positions; and L is derived from phenylpyridine, tolylpyridine, benzothienylpyridine, phenylisoquinoline, dibenzoquinozaline, fluorenylpyridine, ketopyrrole, 2-(1-naphthyl)benzoxazole)), 2-phenylbenzoxazole, 2-phenylbenzothiazole, coumarin, thienylpyridine, phenylpyridine, benzothienylpyridine, 3-methoxy-2-phenylpyridine, thienylpyridine, phenylimine, vinylpyridine, pyridylnaphthalene, pyridylpyrrole, pyridylimidazole, phenylindole, derivatives thereof or combinations thereof.

  3. System and method for producing substitute natural gas from coal

    DOE Patents [OSTI]

    Hobbs, Raymond (Avondale, AZ)

    2012-08-07T23:59:59.000Z

    The present invention provides a system and method for producing substitute natural gas and electricity, while mitigating production of any greenhouse gasses. The system includes a hydrogasification reactor, to form a gas stream including natural gas and a char stream, and an oxygen burner to combust the char material to form carbon oxides. The system also includes an algae farm to convert the carbon oxides to hydrocarbon material and oxygen.

  4. Characterization and Electrochemical Performance of SubstitutedLiNi0.4Co0.2-yAlyMn0.4O2 (0<_y<_0.2) Cathode Materials

    SciTech Connect (OSTI)

    Wilcox, James D.; Doeff, Marca M.

    2007-11-28T23:59:59.000Z

    A complete series of LiNi0.4Co0.2-yAlyMn0.4O2 (0<_y<_0.2) materials have been synthesized and investigated as cathode materials for lithium ion batteries. When cycled between 2.0 and 4.3 V vs. Li/Li+ at a current density of 0.1 mA/cm2, stable capacities of ~;;160 mAh/g for y=0 to ~;;110 mAh/g for y=0.2 are achieved. Upon increasing the current density, it is found that all materials containing aluminum show reduced polarization and improved rate performance. The optimal performance at all current densities was found for the compound with y=0.05. The effect of aluminumsubstitution on the crystal structure of the host is discussed.

  5. Woodfuel scoping study Increasing the use of woodfuel as a substitute for fossil fuels is important

    E-Print Network [OSTI]

    Woodfuel scoping study Increasing the use of woodfuel as a substitute for fossil fuels is important tonnes of material a year from currently UMW in England by 2020. New government subsidies for heat

  6. ATOMISTIC MODELING OF ELECTRODE MATERIALS

    Broader source: Energy.gov (indexed) [DOE]

    life and rate * High cost of electrode materials * Project lead: Venkat Srinivasan (LBNL) * Marca Doeff (LBNL): Al-substituted layered Li-TM-O 2 * Phil Ross (LBNL) and Gerbrand...

  7. Atomistic Modeling of Electrode Materials

    Broader source: Energy.gov (indexed) [DOE]

    and rate * High cost of electrode materials * Project lead: John Newman * Marca Doeff (LBNL) on layered Li-TM-O 2 for effects of Al substitution * Phil Ross (LBNL) on nano-LiFePO...

  8. Crystal and molecular structure of four adamantyl-substituted tetrazoles

    SciTech Connect (OSTI)

    Polyakova, I. N., E-mail: polyakova@igic.ras.ru [Russian Academy of Sciences, Kurnakov Institute of General and Inorganic Chemistry (Russian Federation); Saraev, V. V.; Gavrilov, A. S.; Golod, E. L. [St. Petersburg State Technological Institute (Technical University) (Russian Federation)

    2009-05-15T23:59:59.000Z

    Four adamantyltetrazoles-1-(1-adamantyl)tetrazole (I), 2-(1-adamantyl)tetrazole (II), 2-(3-aminoadamantyl-1)tetrazole (III), and 2-(3-aminoadamantyl-1)-5-methyltetrazole (IV)-are synthesized, and their crystal structures are studied. It is found that the tetrazole rings in the 1-substituted molecule I and 2-substituted molecules II-IV have close linear parameters but differ significantly in endocyclic angles. The degree of delocalization of double bonds in I is somewhat smaller than that in II-IV. The identical relative orientation of the tetrazole ring and adamantyl fragment in I-IV is stabilized by intramolecular C-H...N interactions (H...N, 2.57(2)-2.76(2) A). The molecular packings of crystals I-IV are determined by weak intermolecular C-H...N interactions; in III and IV, the packings are in addition affected by N-H...N interactions that involve NH{sub 2} groups. In the series of compounds I-IV, a qualitative dependence of the lengths of intermolecular H...N contacts and antiviral activity on the basicity of nitrogen atoms in the molecules is revealed.

  9. Long-term evaluation of solid oxide fuel cell candidate materials in a 3-cell generic short stack fixture, Part II: sealing glass stability, microstructure and interfacial reactions.

    SciTech Connect (OSTI)

    Chou, Y. S.; Stevenson, Jeffry W.; Choi, Jung-Pyung

    2014-03-15T23:59:59.000Z

    A generic solid oxide fuel cell stack test fixture was developed to evaluate candidate materials and processing methods under realistic conditions. Part I of the work addressed the stack fixture, seal system and cell performance of a 3-cell short stack tested at 800oC for 6000h. Commercial NiO-YSZ anode-supported thin YSZ electrolyte cells with LSM cathodes were used for assessment and were tested in constant current mode with dilute (~50% H2) fuel versus air. Part II of the work examined the sealing glass stability, microstructure development, interfacial reactions, and volatility issues. Part III of the work investigated the stability of Ce-(Mn,Co) spinel coating, AISI441 metallic interconnect, alumina coating, and cell degradation. After 6000h of testing, the refractory sealing glass YSO77 (Ba-Sr-Y-B-Si) showed desirable chemical compatibility with YSZ electrolyte in that no discernable interfacial reaction was identified, consistent with thermodynamic calculations. In addition, no glass penetration into the thin electrolyte was observed. At the aluminized AISI441 interface, the protective alumina coating appeared to be corroded by the sealing glass. Air side interactions appeared to be more severe than fuel side interactions. Metal species such as Cr, Mn, and Fe were detected in the glass, but were limited to the vicinity of the interface. No alkaline earth chromates were found at the air side. Volatility was also studied in a similar glass and weight loss in a wet reducing environment was determined. Using the steady-state volatility data, the life time (40,000h) weight loss of refractory sealing glass YSO77 was estimated to be less than 0.1 wt%.

  10. Energy-substitution in the paper industry in Brazil: A translog function approach

    SciTech Connect (OSTI)

    Verillo, J.

    1988-01-01T23:59:59.000Z

    Unlike the majority of studies, this study focuses at the micro level instead of the aggregate. The method employed involves the use of econometric techniques to estimate translog cost and production functions, and the estimation of the Allen Elasticities of Substitution (AES) from the coefficients. The data used come from firms in the paper industry of Brazil during January, 1982 to December, 1987. When using aggregated data, findings concerning energy-capital substitution are often controversial. Some authors find substitutability, while others find complementarity between energy and capital. This study found that this ambiguity also appears at the micro level. Even when the firms belong to the same industry, two inputs can be complements in one firm and substitutes in another. The basic findings are: (1) Energy demand is found to be responsive to price changes, (2) Fossil fuels and biomass are substitutes, (3) Biomass and capital are substitutes, (4) Fossil fuels and hydroelectricity are complements, (5) Hydroelectricity and capital are complements, (6) Labor and materials are substitutes, and (7) Capital and labor are substitutes. The other elasticities are ambiguous, varying from firm to firm, or not significant at the 5% level.

  11. An informatics based analysis of the impact of isotope substitution on phonon modes in graphene

    SciTech Connect (OSTI)

    Broderick, Scott; Srinivasan, Srikant; Rajan, Krishna [Department of Material Science and Engineering, Iowa State University, Ames, Iowa 50011 (United States); Ray, Upamanyu; Balasubramanian, Ganesh, E-mail: bganesh@iastate.edu [Department of Mechanical Engineering, Iowa State University, Ames, Iowa 50011 (United States)

    2014-06-16T23:59:59.000Z

    It is shown by informatics that the high frequency short ranged modes exert a significant influence in impeding thermal transport through isotope substituted graphene nanoribbons. Using eigenvalue decomposition methods, we have extracted features in the phonon density of states spectra that reveal correlations between isotope substitution and phonon modes. This study also provides a data driven computational framework for the linking of materials chemistry and transport properties in 2D systems.

  12. Polycyclic Aromatic Triptycenes: Oxygen Substitution Cyclization Strategies

    E-Print Network [OSTI]

    VanVeller, Brett

    The cyclization and planarization of polycyclic aromatic hydrocarbons with concomitant oxygen substitution was achieved through acid catalyzed transetherification and oxygen-radical reactions. The triptycene scaffold ...

  13. Olivines and Substituted Layered Materials | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L d F SSales LLC OrderEfficiencyOceanOctober0High School OilOklahoma1

  14. Olivines and Substituted Layered Materials | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L d F SSales LLC OrderEfficiencyOceanOctober0High School OilOklahoma110

  15. Olivines and Substituted Layered Materials | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L d F SSales LLC OrderEfficiencyOceanOctober0High School

  16. Oral: Division of Polymeric Materials: Science & Engineering: Nano-and Micro-Scale Porous Polymer-Based Systems. Synthesis of [Bis(pyridine)salen]ZnII

    E-Print Network [OSTI]

    Oral: Division of Polymeric Materials: Science & Engineering: Nano- and Micro-Scale Porous Polymer envisioned for these polymeric materials, enantioselectivity is one of the most challenging to incorporate.4/separation are often anticipated.5,6 Ideally, porous polymeric materials with chiral functionalities along their pores

  17. In-situ subaqueous capping of mercury-contaminated sediments in a fresh-water aquatic system, Part II-evaluation of sorption materials

    SciTech Connect (OSTI)

    Randall, Paul M., E-mail: randall.paul@epa.gov [U.S. Environmental Protection Agency, Office of Research and Development, National Risk Management Research Laboratory, 26 W. Martin Luther King Drive, Cincinnati, OH 45268 (United States); Yates, Brian J.; Lal, Vivek; Darlington, Ramona [Battelle, 505 King Avenue, Columbus, OH 43201 (United States)] [Battelle, 505 King Avenue, Columbus, OH 43201 (United States); Fimmen, Ryan [Geosyntec Consultants, 150 E. Wilson Bridge Road, Suite 232, Worthington, OH 43085 (United States)] [Geosyntec Consultants, 150 E. Wilson Bridge Road, Suite 232, Worthington, OH 43085 (United States)

    2013-08-15T23:59:59.000Z

    The function and longevity of traditional, passive, isolation caps can be augmented through the use of more chemically active capping materials which have higher sorptive capacities, ideally rendering metals non-bioavailable. In the case of Hg, active caps also mitigate the rate and extent of methylation. This research examined low cost, readily available, capping materials for their ability to sequester Hg and MeHg. Furthermore, selected capping materials were evaluated to inhibit the methylation of Hg in an incubation study as well as the capacity of a selected capping material to inhibit translocation of Hg and MeHg with respect to ebullition-facilitated contaminant transport in a column study. Results indicated that bauxite had a better capacity for mercury sorption than the other test materials. However, bauxite as well as soil capping materials did not decrease methylation to a significant extent. Materials with larger surface areas, higher organic matter and acid volatile sulfide (AVS) content displayed a larger partitioning coefficient. In the incubation experiments, the presence of a carbon source (lactate), electron acceptor (sulfate) and the appropriate strains of SRB provided the necessary conditions for Hg methylation to occur. The column study showed effectiveness in sequestering Hg and MeHg and retarding transport to the overlying water column; however, disturbances to the soil capping material resulting from gas ebullition negated its effectiveness.

  18. Products having multiple-substituted polysiloxane monolayer

    DOE Patents [OSTI]

    Wirth, Mary J. (Elkton, MD); Fatunmbi, Hafeez O. (Newark, DE)

    1998-02-10T23:59:59.000Z

    A protective monolayer is formed on e.g. silica gel and glass surfaces comprising a monolayer of silicon and oxygen atoms which is substituted with first and second hydrocarbyl substituents.

  19. Financing of Substitute Natural Gas Costs (Indiana)

    Broader source: Energy.gov [DOE]

    This statute encourages the development of local coal gasification facilities to produce substitute natural gas, calls on state energy utilities to enter into long-term contracts for the purchase...

  20. MULTIDISCIPLINARY FREE MATERIAL OPTIMIZATION 1 ...

    E-Print Network [OSTI]

    2009-10-18T23:59:59.000Z

    Nonlinear Anal. and Mech., Pitman, London, pages 136–212, 1979. [22] R. Werner. Free Material Optimization. PhD thesis, Institute of Applied Mathematics II, ...

  1. Enzymatic hydrolysis of low substituted carboxymethyl cellulose

    E-Print Network [OSTI]

    Chanona Dominquez, Guadalupe

    1984-01-01T23:59:59.000Z

    ENZYMATIC HYDROLYSIS OF LOW SUBSTITUTED CARBOXYMETHYL CELLULOSE A Thesis by GUADALUPE CHANONA DOMINGUEZ Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE... December 1984 Major Subject: Agricultural Engineering ENZYMATIC HYDROLYSIS OF LOW SUBSTITUTED CARBOXYMETHYL CELLULOSE A Thesis by GUADALUPE CHANONA DOMINGUEZ Approved as to style and content by: Cady R. Engler airman) Ed. J. Soltes (Member...

  2. Integrated systems approach to pollution prevention: A three-tier substitution strategy

    SciTech Connect (OSTI)

    Ahmed, I.; Cunniff, E.; Patch, J. [Booz-Allen & Hamilton Inc., Bethesda, MD (United States)

    1995-12-01T23:59:59.000Z

    Current pollution prevention initiatives are reactive, not proactive. Most federal and state regulations and industry participation in pollution prevention projects focus on post-production cleanup. However, an integrated systems approach to design pollution prevention strategies based on substitution of entire classes of chemicals with bio-based alternatives would significantly enhance the impact of pollution prevention efforts. Industry`s current attempts at pollution prevention efforts primarily rely on recycling, modifying processes to reduce the use of certain chemicals, or substituting a petrochemical not listed on the Toxic Release Inventory (TRI) for one currently listed. Such strategies may not constitute a long term solution to the pollution problem. A more durable and comprehensive strategy is to substitute renewable feedstock derived biochemicals for petrochemicals. The generation of pollution as driven by the consumer end-products industry occurs in three distinct levels; raw materials production (crude oil refining), commodity and intermediate chemicals production, a raw chemicals consumption. This paper suggests a three-tier substitution strategy based on the three levels of materials used in the chemical process industry with a goal of minimizing the pollution impact via substitutions. The substitution potential of each of the three tiers is determined based on the optimum impact criteria applicable to a given produce line or a process. The best existing pollution prevention initiatives should be incorporated in an integrated pollution management system. This system considers and includes long-term solutions to pollution problems faced both by the regulators and the chemical process industry. The role of existing production capacities that continue to produce toxic chemicals as a byproduct and their potential phase-out via biochemical substitution is also discussed.

  3. Atomic Substitutions in Yba2cu3o7 - Modification of the Electronic-Structure

    E-Print Network [OSTI]

    RICHERT, BA; Allen, Roland E.

    1988-01-01T23:59:59.000Z

    - viously reported, because we thought these substitutions should be possible and might prove interesting. Recently several new claattm of high T, superconductors have been reported 33 3 involving substitution of Bi, (Pb,Bi), and Tl for Y. This work...-Temperature Superconductors, edited by M. B, Brod- sky, R. C. Dynes, K. Kltazawa, and H. L. Taller (Materials Research Society, Pittsburgh, ill press). ~3K. Zhang, 8. Dabrowski?C. U. Segre, D. G. Hinks, I. K. Schuller, J. D. Jorgensen, and M. Slaski?J. Phys. C 20, L935...

  4. Soiling of building envelope surfaces and its effect on solar reflectance - Part II: Development of an accelerate aging method for roofing materials

    SciTech Connect (OSTI)

    Sleiman, Mohamad; Kirchstetter, Thomas W.; Berdahl, Paul; Gilbert, Haley; Quelen, Sarah; Marlot, Lea; Preble, Chelsea; Chen, Sharon; Montalbano, Amadine; Rosseler, Olivier; Akbari, Hashem; Levinson, Ronnen; Destaillats, Hugo

    2013-11-18T23:59:59.000Z

    Highly reflective roofs can decrease the energy required for building air conditioning, help mitigate the urban heat island effect, and slow global warming. However, these benefits are diminished by soiling and weathering processes that reduce the solar reflectance of most roofing materials. Soiling results from the deposition of atmospheric particulate matter and the growth of microorganisms, each of which absorb sunlight. Weathering of materials occurs with exposure to water, sunlight, and high temperatures. This study developed an accelerated aging method that incorporates features of soiling and weathering. The method sprays a calibrated aqueous soiling mixture of dust minerals, black carbon, humic acid, and salts onto preconditioned coupons of roofing materials, then subjects the soiled coupons to cycles of ultraviolet radiation, heat and water in a commercial weatherometer. Three soiling mixtures were optimized to reproduce the site-specific solar spectral reflectance features of roofing products exposed for 3 years in a hot and humid climate (Miami, Florida); a hot and dry climate (Phoenix, Arizona); and a polluted atmosphere in a temperate climate (Cleveland, Ohio). A fourth mixture was designed to reproduce the three-site average values of solar reflectance and thermal emittance attained after 3 years of natural exposure, which the Cool Roof Rating Council (CRRC) uses to rate roofing products sold in the US. This accelerated aging method was applied to 25 products?single ply membranes, factory and field applied coatings, tiles, modified bitumen cap sheets, and asphalt shingles?and reproduced in 3 days the CRRC's 3-year aged values of solar reflectance. This accelerated aging method can be used to speed the evaluation and rating of new cool roofing materials.

  5. Addendum to material selection guidelines for geothermal energy-utilization systems. Part I. Extension of the field experience data base. Part II. Proceedings of the geothermal engineering and materials (GEM) program conference (San Diego, CA, 6-8 October 1982)

    SciTech Connect (OSTI)

    Smith, C.S.; Ellis, P.F. II

    1983-05-01T23:59:59.000Z

    The extension of the field experience data base includes the following: key corrosive species, updated field experiences, corrosion of secondary loop components or geothermal binary power plants, and suitability of conventional water-source heat pump evaporator materials for geothermal heat pump service. Twenty-four conference papers are included. Three were abstracted previously for EDB. Separate abstracts were prepared for twenty-one. (MHR)

  6. Optical limiting materials

    DOE Patents [OSTI]

    McBranch, Duncan W. (Santa Fe, NM); Mattes, Benjamin R. (Santa Fe, NM); Koskelo, Aaron C. (Los Alamos, NM); Heeger, Alan J. (Santa Barbara, CA); Robinson, Jeanne M. (Los Alamos, NM); Smilowitz, Laura B. (Los Alamos, NM); Klimov, Victor I. (Los Alamos, NM); Cha, Myoungsik (Goleta, CA); Sariciftci, N. Serdar (Santa Barbara, CA); Hummelen, Jan C. (Groningen, NL)

    1998-01-01T23:59:59.000Z

    Optical limiting materials. Methanofullerenes, fulleroids and/or other fullerenes chemically altered for enhanced solubility, in liquid solution, and in solid blends with transparent glass (SiO.sub.2) gels or polymers, or semiconducting (conjugated) polymers, are shown to be useful as optical limiters (optical surge protectors). The nonlinear absorption is tunable such that the energy transmitted through such blends saturates at high input energy per pulse over a wide range of wavelengths from 400-1100 nm by selecting the host material for its absorption wavelength and ability to transfer the absorbed energy into the optical limiting composition dissolved therein. This phenomenon should be generalizable to other compositions than substituted fullerenes.

  7. Impedance spectroscopic characterization of gadolinium substituted cobalt ferrite ceramics

    SciTech Connect (OSTI)

    Rahman, Md. T., E-mail: mrahman5@miners.utep.edu; Ramana, C. V. [Department of Mechanical Engineering, University of Texas at El Paso, El Paso, Texas 79968 (United States)

    2014-10-28T23:59:59.000Z

    Gadolinium (Gd) substituted cobalt ferrites (CoFe{sub 2?x}Gd{sub x}O{sub 4}, referred to CFGO) with variable Gd content (x?=?0.0–0.4) have been synthesized by solid state ceramic method. The crystal structure and impedance properties of CFGO compounds have been evaluated. X-ray diffraction measurements indicate that CFGO crystallize in the inverse spinel phase. The CFGO compounds exhibit lattice expansion due to substitution of larger Gd ions into the crystal lattice. Impedance spectroscopy analysis was performed under a wide range of frequency (f?=?20?Hz–1?MHz) and temperature (T?=?303–573?K). Electrical properties of Gd incorporated Co ferrite ceramics are enhanced compared to pure CoFe{sub 2}O{sub 4} due to the lattice distortion. Impedance spectroscopic analysis illustrates the variation of bulk grain and grain-boundary contributions towards the electrical resistance and capacitance of CFGO materials with temperature. A two-layer heterogeneous model consisting of moderately conducting grain interior (ferrite-phase) regions separated by insulating grain boundaries (resistive-phase) accurately account for the observed temperature and frequency dependent electrical characteristic of CFGO ceramics.

  8. THE CORROSION OF SILICATE MATERIALS BY HYDROGEN GAS AND HYDROFLUORIC ACID SOLUTION

    E-Print Network [OSTI]

    Tso, Stephen T.

    2011-01-01T23:59:59.000Z

    THE CORROSION OF SILICATE MATERIALS BY HYDROGEN GAS ANDApparatus II. Hydrogen Gas Corrosion, HydrofluoricAcid Solution Corrosion. Material Preparation, , , ,

  9. Porous Materials Porous Materials

    E-Print Network [OSTI]

    Berlin,Technische Universität

    1 Porous Materials x Porous Materials · Physical properties * Characteristic impedance p = p 0 e -jk xa- = vej[ ] p x - j ; Zc= p ve = c ka 0k = c 1-j #12;2 Porous Materials · Specific acoustic impedance Porous Materials · Finite thickness ­ blocked p e + -jk (x-d)a p e - jk (x-d)a d x #12

  10. UTILIZATION OF LIGHTWEIGHT MATERIALS MADE FROM COAL GASIFICATION SLAGS

    SciTech Connect (OSTI)

    Vas Choudhry; Stephen Kwan; Steven R. Hadley

    2001-07-01T23:59:59.000Z

    The objective of the project entitled ''Utilization of Lightweight Materials Made from Coal Gasification Slags'' was to demonstrate the technical and economic viability of manufacturing low-unit-weight products from coal gasification slags which can be used as substitutes for conventional lightweight and ultra-lightweight aggregates. In Phase I, the technology developed by Praxis to produce lightweight aggregates from slag (termed SLA) was applied to produce a large batch (10 tons) of expanded slag using pilot direct-fired rotary kilns and a fluidized bed calciner. The expanded products were characterized using basic characterization and application-oriented tests. Phase II involved the demonstration and evaluation of the use of expanded slag aggregates to produce a number of end-use applications including lightweight roof tiles, lightweight precast products (e.g., masonry blocks), structural concrete, insulating concrete, loose fill insulation, and as a substitute for expanded perlite and vermiculite in horticultural applications. Prototypes of these end-use applications were made and tested with the assistance of commercial manufacturers. Finally, the economics of expanded slag production was determined and compared with the alternative of slag disposal. Production of value-added products from SLA has a significant potential to enhance the overall gasification process economics, especially when the avoided costs of disposal are considered.

  11. Aliovalent Substitution in Mixed Ni-Mn-Co Oxide Cathodes

    E-Print Network [OSTI]

    Kam, Kinson C.

    2012-01-01T23:59:59.000Z

    transition metal oxides, aliovalent substitution Acknowledgment This work was supported by the Assistant Secretary for Energy Efficiency and Renewable Energy,

  12. Hotspots of Biased Nucleotide Substitutions in Human Genes

    E-Print Network [OSTI]

    Sorenson, Michael

    Hotspots of Biased Nucleotide Substitutions in Human Genes Jonas Berglund1 , Katherine S. Pollard2) Hotspots of biased nucleotide substitutions in human genes. PLoS Biol 7(1): e1000026. doi:10.1371/journal selection in the human lineage. However, HARs tend to have biased patterns of nucleotide substitution

  13. Exploitative Competition in the Chemostat for Two Perfectly Substitutable Resources

    E-Print Network [OSTI]

    Wolkowicz, Gail S. K.

    Exploitative Competition in the Chemostat for Two Perfectly Substitutable Resources MARY M. BALLYK of microorganisms competing for two nonreproducing, growth-limiting resources in a chemostat, we focus on perfectly substitutable resources. Leon and Tumpson considered a model of perfectly substitutable resources in which

  14. Approximate Methods for Estimating the Pattern of Nucleotide Substitution and the Variation of Substitution Rates Among Sites

    E-Print Network [OSTI]

    Kumar, Sudhir

    Approximate Methods for Estimating the Pattern of Nucleotide Substitution and the Variation on parsimony and one on pairwise sequence comparison) for estimating the pattern of nucleotide substitution. Introduction Estimation of the pattern of nucleotide substitution, i.e., the relative probabilities

  15. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Vaughey, John; Krumpelt, Michael; Wang, Xiaoping; Carter, J. David

    2005-07-12T23:59:59.000Z

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  16. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Carter, J. David; Wang, Xiaoping; Vaughey, John; Krumpelt, Michael

    2004-11-23T23:59:59.000Z

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  17. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Vaughey, John (Elmhurst, IL); Krumpelt, Michael (Naperville, IL); Wang, Xiaoping (Downers Grove, IL); Carter, J. David (Bolingbrook, IL)

    2003-01-01T23:59:59.000Z

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  18. A micromechanical basis for partitioning the evolution of grain bridging in brittle materials

    E-Print Network [OSTI]

    Foulk III, J.W.; Cannon, R.M.; Johnson, G.C.; Klein, P.A.; Ritchie, R.O.

    2008-01-01T23:59:59.000Z

    the strength and fracture of materials. Vol. 3. Perga- monimpact damage in brittle materials. International Journal ofin polycrystalline brittle materials. part II: numerical

  19. Radon in the DRIFT-II directional dark matter TPC: emanation, detection and mitigation

    E-Print Network [OSTI]

    J. B. R. Battat; J. Brack; E. Daw; A. Dorofeev; A. C. Ezeribe; J. R. Fox; J. -L. Gauvreau; M. Gold; L. J. Harmon; J. L. Harton; J. M. Landers; E. R. Lee; D. Loomba; J. A. J. Matthews; E. H. Miller; A. Monte; A. StJ. Murphy; S. M. Paling; N. Phan; M. Pipe; M. Robinson; S. W. Sadler; A. Scarff; D. P. Snowden-Ifft; N. J. C. Spooner; S. Telfer; D. Walker; D. Warner; L. Yuriev

    2014-08-25T23:59:59.000Z

    Radon gas emanating from materials is of interest in environmental science and also a major concern in rare event non-accelerator particle physics experiments such as dark matter and double beta decay searches, where it is a major source of background. Notable for dark matter experiments is the production of radon progeny recoils (RPRs), the low energy (~100 keV) recoils of radon daughter isotopes, which can mimic the signal expected from WIMP interactions. Presented here are results of measurements of radon emanation from detector materials in the 1 metre cubed DRIFT-II directional dark matter gas time projection chamber experiment. Construction and operation of a radon emanation facility for this work is described, along with an analysis to continuously monitor DRIFT data for the presence of internal 222Rn and 218Po. Applying this analysis to historical DRIFT data, we show how systematic substitution of detector materials for alternatives, selected by this device for low radon emanation, has resulted in a factor of ~10 reduction in internal radon rates. Levels are found to be consistent with the sum from separate radon emanation measurements of the internal materials and also with direct measurement using an attached alpha spectrometer. The current DRIFT detector, DRIFT-IId, is found to have sensitivity to 222Rn of 2.5 {\\mu}Bq/l with current analysis efficiency, potentially opening up DRIFT technology as a new tool for sensitive radon assay of materials.

  20. Optical limiting materials

    DOE Patents [OSTI]

    McBranch, D.W.; Mattes, B.R.; Koskelo, A.C.; Heeger, A.J.; Robinson, J.M.; Smilowitz, L.B.; Klimov, V.I.; Cha, M.; Sariciftci, N.S.; Hummelen, J.C.

    1998-04-21T23:59:59.000Z

    Methanofullerenes, fulleroids and/or other fullerenes chemically altered for enhanced solubility, in liquid solution, and in solid blends with transparent glass (SiO{sub 2}) gels or polymers, or semiconducting (conjugated) polymers, are shown to be useful as optical limiters (optical surge protectors). The nonlinear absorption is tunable such that the energy transmitted through such blends saturates at high input energy per pulse over a wide range of wavelengths from 400--1,100 nm by selecting the host material for its absorption wavelength and ability to transfer the absorbed energy into the optical limiting composition dissolved therein. This phenomenon should be generalizable to other compositions than substituted fullerenes. 5 figs.

  1. Injectable Bone Substitute using a hydrophilic polymer Pierre Weiss, Olivier Gauthier, Jean-Michel Bouler, Gal Grimandi and Guy Daculsi

    E-Print Network [OSTI]

    Boyer, Edmond

    polymer as matrix and bioactive calcium phosphate (CaP) ceramics as fillers. This material is composed effects on this composite in a tube. The stability of the polymer and the mixture is essential between CaP ceramic granules and facilitate the role of the biological agents of bone substitution

  2. Photosystem II

    ScienceCinema (OSTI)

    James Barber

    2010-09-01T23:59:59.000Z

    James Barber, Ernst Chain Professor of Biochemistry at Imperial College, London, gives a BSA Distinguished Lecture titled, "The Structure and Function of Photosystem II: The Water-Splitting Enzyme of Photosynthesis."

  3. DEPARTMENT OF MATERIALS PART II PROJECTS

    E-Print Network [OSTI]

    Paxton, Anthony T.

    such as polymeric solar cells, or flexible displays, is limited by the performance of transparent flexible gas. This will include the `Ca test method' which is already set-up, and also the encapsulation of photovoltaic devices

  4. PARS II Training Materials | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L d F SSales LLCDieselEnergyHistory and Successes PAFCTraining

  5. Substituted 3-hydroxy-delta-lactones from epoxides

    DOE Patents [OSTI]

    Coates, Geoffrey W.; Kramer, John W.

    2013-09-10T23:59:59.000Z

    Catalysts and methods for the carbonylation of epoxides to substituted 3-hydroxy-.delta.-lactones and .beta.-lactones are disclosed.

  6. Activation of methane by transition metal-substituted aluminophosphate molecular sieves

    DOE Patents [OSTI]

    Iton, Lennox E. (Downers Grove, IL); Maroni, Victor A. (Naperville, IL)

    1991-01-01T23:59:59.000Z

    Aluminophosphate molecular sieves substituted with cobalt, manganese or iron and having the AlPO.sub.4 -34 or AlPO.sub.4 -5, or related AlPO.sub.4 structure activate methane starting at approximately 350.degree. C. Between 400.degree. and 500.degree. C. and at methane pressures .ltoreq.1 atmosphere the rate of methane conversion increases steadily with typical conversion efficiencies at 500.degree. C. approaching 50% and selectivity to the production of C.sub.2+ hydrocarbons approaching 100%. The activation mechanism is based on reduction of the transition metal(III) form of the molecular sieve to the transition metal(II) form with accompanying oxidative dehydrogenation of the methane. Reoxidation of the - transition metal(II) form to the transition metal(III) form can be done either chemically (e.g., using O.sub.2) or electrochemically.

  7. High pressure chemistry of substituted acetylenes

    SciTech Connect (OSTI)

    Chellappa, Raja [Los Alamos National Laboratory; Dattelbaum, Dana [Los Alamos National Laboratory; Sheffield, Stephen [Los Alamos National Laboratory; Robbins, David [Los Alamos National Laboratory

    2011-01-25T23:59:59.000Z

    High pressure in situ synchrotron x-ray diffraction experiments were performed on substituted polyacetylenes: tert-butyl acetylene [TBA: (CH{sub 3}){sub 3}-C{triple_bond}CH] and ethynyl trimethylsilane [ETMS: (CH{sub 3}){sub 3}-Si{triple_bond}CH] to investigate pressure-induced chemical reactions. The starting samples were the low temperature crystalline phases which persisted metastably at room temperature and polymerized beyond 11 GPa and 26 GPa for TBA and ETMS respectively. These reaction onset pressures are considerably higher than what we observed in the shockwave studies (6.1 GPa for TBA and 6.6 GPa for ETMS). Interestingly, in the case of ETMS, it was observed with fluid ETMS as starting sample, reacts to form a semi-crystalline polymer (crystalline domains corresponding to the low-T phase) at pressures less than {approx}2 GPa. Further characterization using vibrational spectroscopy is in progress.

  8. U.S. Department of Energy Critical Materials Strategy

    SciTech Connect (OSTI)

    Bauer, D.; Diamond, D.; Li, J.; Sandalow, D.; Telleen, P.; Wanner, B.

    2010-12-01T23:59:59.000Z

    This report examines the role of rare earth metals and other materials in the clean energy economy. It was prepared by the U.S. Department of Energy (DOE) based on data collected and research performed during 2010. Its main conclusions include: (a) Several clean energy technologies -- including wind turbines, electric vehicles, photovoltaic cells and fluorescent lighting -- use materials at risk of supply disruptions in the short term. Those risks will generally decrease in the medium and long term. (b) Clean energy technologies currently constitute about 20 percent of global consumption of critical materials. As clean energy technologies are deployed more widely in the decades ahead, their share of global consumption of critical materials will likely grow. (c) Of the materials analyzed, five rare earth metals (dysprosium, neodymium, terbium, europium and yttrium), as well as indium, are assessed as most critical in the short term. For this purpose, 'criticality' is a measure that combines importance to the clean energy economy and risk of supply disruption. (d) Sound policies and strategic investments can reduce the risk of supply disruptions, especially in the medium and long term. (e) Data with respect to many of the issues considered in this report are sparse. In the report, DOE describes plans to (i) develop its first integrated research agenda addressing critical materials, building on three technical workshops convened by the Department during November and December 2010; (ii) strengthen its capacity for information-gathering on this topic; and (iii) work closely with international partners, including Japan and Europe, to reduce vulnerability to supply disruptions and address critical material needs. DOE will work with other stakeholders -- including interagency colleagues, Congress and the public -- to shape policy tools that strengthen the United States' strategic capabilities. DOE also announces its plan to develop an updated critical materials strategy, based upon additional events and information, by the end of 2011.DOE's strategy with respect to critical materials rests on three pillars. First, diversified global supply chains are essential. To manage supply risk, multiple sources of materials are required. This means taking steps to facilitate extraction, processing and manufacturing here in the United States, as well as encouraging other nations to expedite alternative supplies. In all cases, extraction and processing should be done in an environmentally sound manner. Second, substitutes must be developed. Research leading to material and technology substitutes will improve flexibility and help meet the material needs of the clean energy economy. Third, recycling, reuse and more efficient use could significantly lower world demand for newly extracted materials. Research into recycling processes coupled with well-designed policies will help make recycling economically viable over time.The scope of this report is limited. It does not address the material needs of the entire economy, the entire energy sector or even all clean energy technologies. Time and resource limitations precluded a comprehensive scope. Among the topics that merit additional research are the use of rare earth metals in catalytic converters and in petroleum refining. These topics are discussed briefly in Chapter 2.

  9. SUSTAINABILITY, RESOURCE SUBSTITUTION IN ENERGY INPUTS AND LEARNING

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    it will be unsustainable. Key Words : Renewable resource, non-renewable resource, substitution, sustainability, learning non- renewable fossil fuels and renewable energy resources. As said Andr´e and Cerda (2006), the main a non-renewable resource with a renewable one. Indeed, it is relatively easy to substitute nuclear

  10. NUCLEOTIDE SUBSTITUTIONS AND THE EVOLUTION OF DUPLICATE GENES

    E-Print Network [OSTI]

    Oregon, University of

    167 NUCLEOTIDE SUBSTITUTIONS AND THE EVOLUTION OF DUPLICATE GENES JOHN S. CONERY Computational to gener- ate a corresponding alignment of the underlying nucleotide sequences and perform a codon by codon comparison of the nucleotides. Observed numbers of nucleotide substitutions can be used to make inferences

  11. LABORATORY II FORCE AND CONSERVATION OF ENERGY

    E-Print Network [OSTI]

    Minnesota, University of

    LABORATORY II FORCE AND CONSERVATION OF ENERGY Lab II - 1 After studying forces and material bodies the relationship between forces and energy conservation. Energy and forces, together, support an extremely be able to: · State the principle of conservation of energy; state the relationship between the work done

  12. Positive Selection on Nucleotide Substitutions and Indels in Accessory Gland Proteins of the Drosophila pseudoobscura Subgroup

    E-Print Network [OSTI]

    Hellberg, Michael E.

    Positive Selection on Nucleotide Substitutions and Indels in Accessory Gland Proteins due to positive selection on nucleotide substitutions. While this general pattern is well established little explored, nor have possible targets of positive selection other than nucleotide substitutions

  13. Production of Substitute Natural Gas from Coal

    SciTech Connect (OSTI)

    Andrew Lucero

    2009-01-31T23:59:59.000Z

    The goal of this research program was to develop and demonstrate a novel gasification technology to produce substitute natural gas (SNG) from coal. The technology relies on a continuous sequential processing method that differs substantially from the historic methanation or hydro-gasification processing technologies. The thermo-chemistry relies on all the same reactions, but the processing sequences are different. The proposed concept is appropriate for western sub-bituminous coals, which tend to be composed of about half fixed carbon and about half volatile matter (dry ash-free basis). In the most general terms the process requires four steps (1) separating the fixed carbon from the volatile matter (pyrolysis); (2) converting the volatile fraction into syngas (reforming); (3) reacting the syngas with heated carbon to make methane-rich fuel gas (methanation and hydro-gasification); and (4) generating process heat by combusting residual char (combustion). A key feature of this technology is that no oxygen plant is needed for char combustion.

  14. 7r ^000 S*} Materials Eteparfmen

    E-Print Network [OSTI]

    7»r ^£000 S*} Materials Eteparfmen Annual Report 1994 l***y-£ ·fflLJ*.'' £ Published bv M;)1t':ii,iN l)cn Ri\\o Viiion.il l,;tb'ii,iiof. #12;T ^ T i Y T C / T ^ Ki>. Materials Department #12;Abstract Selected activities of the Materials IX-partment at Riso National Laboratory during HW4

  15. Structure-dielectric properties relationships in copper-substituted magnesium ferrites

    SciTech Connect (OSTI)

    Druc, A.C.; Borhan, A.I. [Faculty of Chemistry, Alexandru Ioan Cuza University of Iasi, Bulevardul Carol I, nr. 11, 700506 Iasi (Romania); Nedelcu, G.G.; Leontie, L. [Faculty of Physics, Alexandru Ioan Cuza University of Iasi, Bulevardul Carol I, nr. 11, 700506 Iasi (Romania); Iordan, A.R. [Faculty of Chemistry, Alexandru Ioan Cuza University of Iasi, Bulevardul Carol I, nr. 11, 700506 Iasi (Romania); Palamaru, M.N., E-mail: palamaru@uaic.ro [Faculty of Chemistry, Alexandru Ioan Cuza University of Iasi, Bulevardul Carol I, nr. 11, 700506 Iasi (Romania)

    2013-11-15T23:59:59.000Z

    Graphical abstract: - Highlights: • Synthesis of copper substituted magnesium ferrites materials is reported. • A shift from cubic to tetragonal structure starting with x = 0.84 was observed. • The dielectric properties are influenced by Cu-substitution. - Abstract: Nanocrystalline powders of copper-substituted magnesium ferrites with general formula Mg{sub 1?x}Cu{sub x}Fe{sub 2}O{sub 4} (x = 0.00, 0.17, 0.34, 0.50, 0.67, 0.84, 1.00) were prepared for the first time by sol–gel auto-combustion method, using glycine as fuel agent. Solid phase chemical reactions and the occurrence of spinel structure were monitored by using infrared spectroscopy. X-ray diffraction analysis confirmed the spinel single-phase formation. A shift from cubic structure to tetragonal structure starting with x = 0.84 was also observed. Microstructure of the samples was analyzed by scanning electron microscopy and particle size was estimated from the micrographs. Analysis of dielectric properties revealed very low values of dielectric loss at frequencies over 10 MHz.

  16. Biofoam II

    DOE Patents [OSTI]

    Morrison, R.L.

    1994-11-01T23:59:59.000Z

    Biofoam is a rigid, microcellular organic foam made from organic materials derived from natural products and biological organisms. Starting materials include agar, agarose, gelatin, algin, alginates, gellan gum, and microcrystalline cellulose. The organic material is dissolved in a polar solvent, typically water, and the mixture is gelled. The water in the gel pores is replaced at least once with another solvent to reduce the pore size of the final biofoam. The solvent in the gel pores may be replaced several times. After the final replacement of solvent, the gel is frozen and freeze-dried to form a biofoam. Translucent biofoams are formed by selecting a final solvent that forms very small crystals. A variety of crystalline, fibrous, amorphous, or metallic additives may be incorporated into the foam structure to produce lightweight composite materials with enhanced strength and insulating properties. 1 fig.

  17. Biofoam II

    DOE Patents [OSTI]

    Morrison, Robert L. (Modesto, CA)

    1994-01-01T23:59:59.000Z

    Biofoam is a rigid, microcellular organic foam made from organic materials derived from natural products and biological organisms. Starting materials include agar, agarose, gelatin, algin, alginates, gellan gum, and microcrystalline cellulose. The organic material is dissolved in a polar solvent, typically water, and the mixture is gelled. The water in the gel pores is replaced at least once with another solvent to reduce the pore size of the final biofoam. The solvent in the gel pores may be replaced several times. After the final replacement of solvent, the gel is frozen and freeze-dried to form a biofoam. Translucent biofoams are formed by selecting a final solvent that forms very small crystals. A variety of crystalline, fibrous, amorphous, or metallic additives may be incorporated into the foam structure to produce lightweight composite materials with enhanced strength and insulating properties.

  18. Radon in the DRIFT-II directional dark matter TPC: emanation, detection and mitigation

    E-Print Network [OSTI]

    Battat, J B R; Daw, E; Dorofeev, A; Ezeribe, A C; Fox, J R; Gauvreau, J -L; Gold, M; Harmon, L J; Harton, J L; Landers, J M; Lee, E R; Loomba, D; Matthews, J A J; Miller, E H; Monte, A; Murphy, A StJ; Paling, S M; Phan, N; Pipe, M; Robinson, M; Sadler, S W; Scarff, A; Snowden-Ifft, D P; Spooner, N J C; Telfer, S; Walker, D; Warner, D; Yuriev, L

    2014-01-01T23:59:59.000Z

    Radon gas emanating from materials is of interest in environmental science and also a major concern in rare event non-accelerator particle physics experiments such as dark matter and double beta decay searches, where it is a major source of background. Notable for dark matter experiments is the production of radon progeny recoils (RPRs), the low energy (~100 keV) recoils of radon daughter isotopes, which can mimic the signal expected from WIMP interactions. Presented here are results of measurements of radon emanation from detector materials in the 1 metre cubed DRIFT-II directional dark matter gas time projection chamber experiment. Construction and operation of a radon emanation facility for this work is described, along with an analysis to continuously monitor DRIFT data for the presence of internal 222Rn and 218Po. Applying this analysis to historical DRIFT data, we show how systematic substitution of detector materials for alternatives, selected by this device for low radon emanation, has resulted in a f...

  19. Chemical and electronic characterization of cobalt in Lanthanum perovskites. Effects of Strontium substitution

    E-Print Network [OSTI]

    Hueso, Jose L.

    2009-01-01T23:59:59.000Z

    atoms. The presence of strontium cations induces two mainof these properties. Strontium-substituted lanthanum cobaltions stabilized in the Strontium-substituted perovskites,

  20. E-Print Network 3.0 - axial ligand substitution Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for Summary: applications. Alkyl substitution on the pyridine ligands did not affect the sublimation temperature for 2... -4 and 8, nor did substitution of pyridine by...

  1. Asbestos-free brake-lining materials for hydrogenerators

    SciTech Connect (OSTI)

    Lalonde, S.; Lanteigne, J. [Hydro-Quebec, Varennes, Quebec (Canada)

    1995-11-01T23:59:59.000Z

    Three different asbestos-free materials currently considered as new lining materials for hydrogenerator brakes were tested and compared to the original asbestos lining. Results show that these substitutes not only vary greatly from the original material in terms of mechanical properties and physical characteristics but also exhibit significantly different performances in braking tests. Consequently, these new materials are not entirely suitable for the intended application.

  2. Mesoporous carbon materials

    DOE Patents [OSTI]

    Dai, Sheng; Wang, Xiqing

    2013-08-20T23:59:59.000Z

    The invention is directed to a method for fabricating a mesoporous carbon material, the method comprising subjecting a precursor composition to a curing step followed by a carbonization step, the precursor composition comprising: (i) a templating component comprised of a block copolymer, (ii) a phenolic compound or material, (iii) a crosslinkable aldehyde component, and (iv) at least 0.5 M concentration of a strong acid having a pKa of or less than -2, wherein said carbonization step comprises heating the precursor composition at a carbonizing temperature for sufficient time to convert the precursor composition to a mesoporous carbon material. The invention is also directed to a mesoporous carbon material having an improved thermal stability, preferably produced according to the above method.

  3. Mesoporous carbon materials

    DOE Patents [OSTI]

    Dai, Sheng (Knoxville, TN); Wang, Xiqing (Oak Ridge, TN)

    2012-02-14T23:59:59.000Z

    The invention is directed to a method for fabricating a mesoporous carbon material, the method comprising subjecting a precursor composition to a curing step followed by a carbonization step, the precursor composition comprising: (i) a templating component comprised of a block copolymer, (ii) a phenolic compound or material, (iii) a crosslinkable aldehyde component, and (iv) at least 0.5 M concentration of a strong acid having a pKa of or less than -2, wherein said carbonization step comprises heating the precursor composition at a carbonizing temperature for sufficient time to convert the precursor composition to a mesoporous carbon material. The invention is also directed to a mesoporous carbon material having an improved thermal stability, preferably produced according to the above method.

  4. Reaction of adsorption substitution of oxygen on a cracking catalyst

    SciTech Connect (OSTI)

    Vishnetskaya, M.V.; Takhtarova, G.N.; Topchieva, K.V.

    1986-04-01T23:59:59.000Z

    In an investigation of catalysts for methanol synthesis and carbon monoxide conversion, the authors have observed, for the first time, the reaction of adsorption substitution of strongly bound oxygen on catalysts containing zeolites and compounds of lanthanum and cerium.

  5. Nickel-Catalyzed Allylic Substitution of Simple Alkenes

    E-Print Network [OSTI]

    Matsubara, Ryosuke

    This report describes a nickel-catalyzed allylic substitution process of simple alkenes whereby an important structural motif, a 1,4-diene, was prepared. The key to success is the use of an appropriate nickel–phosphine ...

  6. Computational Modeling of Degradation of Substituted Benzyltrimethyl Ammonium: Preprint

    SciTech Connect (OSTI)

    Long, H.; Pivovar, B. S.

    2014-09-01T23:59:59.000Z

    The degradation of cations on the alkaline exchange membranes is the major challenge for alkaline membrane fuel cells. In this paper, we investigated the degradation barriers by density functional theory for substituted benzyltrimethyl ammonium (BTMA+) cations, which is one of the most commonly used cations for alkaline exchange membranes. We found that substituted cations with electron-releasing substituent groups at meta-position of the benzyl ring could result in improved degradation barriers. However, after investigating more than thirty substituted BTMA+ cations with ten different substituent groups, the largest improvement of degradation barriers is only 1.6 kcal/mol. This implies that the lifetime of alkaline membrane fuel cells could increase from a few months to a few years by using substituted BTMA+ cations, an encouraging but still limited improvement for real-world applications.

  7. MULTISCALE PHENOMENA IN MATERIALS

    SciTech Connect (OSTI)

    A. BISHOP

    2000-09-01T23:59:59.000Z

    This project developed and supported a technology base in nonequilibrium phenomena underpinning fundamental issues in condensed matter and materials science, and applied this technology to selected problems. In this way the increasingly sophisticated synthesis and characterization available for classes of complex electronic and structural materials provided a testbed for nonlinear science, while nonlinear and nonequilibrium techniques helped advance our understanding of the scientific principles underlying the control of material microstructure, their evolution, fundamental to macroscopic functionalities. The project focused on overlapping areas of emerging thrusts and programs in the Los Alamos materials community for which nonlinear and nonequilibrium approaches will have decisive roles and where productive teamwork among elements of modeling, simulations, synthesis, characterization and applications could be anticipated--particularly multiscale and nonequilibrium phenomena, and complex matter in and between fields of soft, hard and biomimetic materials. Principal topics were: (i) Complex organic and inorganic electronic materials, including hard, soft and biomimetic materials, self-assembly processes and photophysics; (ii) Microstructure and evolution in multiscale and hierarchical materials, including dynamic fracture and friction, dislocation and large-scale deformation, metastability, and inhomogeneity; and (iii) Equilibrium and nonequilibrium phases and phase transformations, emphasizing competing interactions, frustration, landscapes, glassy and stochastic dynamics, and energy focusing.

  8. Depression among abused or neglected children in substitute care

    E-Print Network [OSTI]

    Woodward, Gail Cohn

    1985-01-01T23:59:59.000Z

    DEPRESSION AMONG ABUSED OR NEGLECTED CHILDREN IN SUBSTITUTE CARE A Thesis by GAIL COHN WOODWARD Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE... December 1985 Major Subject: Psychology DEPRESSION AMONG ABUSED OR NEGLECTED CHILDREN IN SUBSTITUTE CARE A Thesis by GAIL COHN WOODWARD Approved as to style and content by: illia S. Rho es (Chair of Committee) i y S. Davidson (Member) Ernest T...

  9. Quantitative NMR Analysis of Partially Substituted Biodiesel Glycerols

    SciTech Connect (OSTI)

    Nagy, M.; Alleman, T. L.; Dyer, T.; Ragauskas, A. J.

    2009-01-01T23:59:59.000Z

    Phosphitylation of hydroxyl groups in biodiesel samples with 2-chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane followed by 31P-NMR analysis provides a rapid quantitative analytical technique for the determination of substitution patterns on partially esterified glycerols. The unique 31P-NMR chemical shift data was established with a series mono and di-substituted fatty acid esters of glycerol and then utilized to characterize an industrial sample of partially processed biodiesel.

  10. Millimeter wave ferromagnetic resonance in gallium-substituted ?-iron oxide

    SciTech Connect (OSTI)

    Chao, Liu, E-mail: liu.chao@tufts.edu; Afsar, Mohammed N. [Department of Electrical and Computer Engineering, Tufts University, Medford, Massachusetts 02155 (United States); Ohkoshi, Shin-ichi [Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan)

    2014-05-07T23:59:59.000Z

    In millimeter wave frequency range, hexagonal ferrites with high uniaxial anisotropic magnetic fields are used as absorbers. These ferrites include M-type barium ferrite (BaFe{sub 12}O{sub 19}) and strontium ferrite (SrFe{sub 12}O{sub 19}), which have natural ferromagnetic resonant frequency range from 40 GHz to 60?GHz. However, the higher frequency range lacks suitable materials that support the higher frequency ferromagnetic resonance. A new series of gallium-substituted ?-iron oxides (?-Ga{sub x}Fe{sub 2?x}O{sub 3}) are synthesized which have ferromagnetic resonant frequencies appearing over the frequency range 30 GHz–150 GHz. The ?-Ga{sub x}Fe{sub 2?x}O{sub 3} is synthesized by the combination of reverse micelle and sol-gel techniques or the sol-gel method only. The particle sizes are observed to be smaller than 100 nm. In this paper, the free space magneto-optical approach has been employed to study these newly developed ?-Ga{sub x}Fe{sub 2?x}O{sub 3} particles in millimeter waves. This technique enables to obtain precise transmission spectra to determine the dielectric and magnetic properties of both isotropic and anisotropic ferrites in the millimeter wave frequency range from a single set of direct measurements. The transmittance and absorbance spectra of ?-Ga{sub x}Fe{sub 2?x}O{sub 3} are shown in this paper. Strong ferromagnetic resonances at different frequencies determined by the x parameter are found.

  11. Dissimilatory Bacterial Reduction of Al-Substituted Goethite in Subsurface Sediments

    SciTech Connect (OSTI)

    Kukkadapu, Ravi K.; Zachara, John M.; Smith, Steven C.; Fredrickson, Jim K.; Liu, Chongxuan

    2001-09-13T23:59:59.000Z

    Microbiologic reduction of the 0.2-2.0 mm size fraction of an Atlantic coastal plain sediment (Eatontown) was investigated using a dissimilatory Fe(III)-reducing bacterium (Shewanella putrefaciens, strain CN32) to evaluate mineralogic controls on the rate and extent of Fe(III) reduction and resulting distribution of biogenic Fe(II). Mössbauer spectroscopy, X-ray diffraction (XRD), and scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM/EDX) was used to show that the sedimentary Fe(III) oxide was Al-substituted goethite (11-17% Al) that existed as 1-5 mm aggregates of indistinct morphology. Bioreduction experiments were performed in two buffers [HCO3-, 1,4-piperazinediethansulfonic acid (PIPES)] both without and with 2,6-anthraquinone disulfonate (AQDS), an electron shuttle. The production of biogenic Fe(II) and the distribution of Al (aqueous and sorbed) were followed over time, as was formation of Fe(II) biominerals and physical/chemical changes to the goethite.

  12. Positive materials identification of existing equipment

    SciTech Connect (OSTI)

    Wolf, H.A. [Exxon Research and Engineering Co., Florham Park, NJ (United States)

    1996-07-01T23:59:59.000Z

    Considerable engineering effort and expertise are expended for materials selection at refining and petrochemical facilities. However, the benefits of this effort are undermined if there is an inadvertent material substitution during construction. Although procedures have always been in place to reduce the chance of such substitutions, it is known that these errors have occurred. Accordingly, over the years the industry has periodically reviewed and improved quality control in this effort. However, many older facilities that did not benefit from today`s procedures are still in operation. As a consequence, some companies have conducted positive material identification (PMI) verification of existing equipment. This process is further complicated by the fact that the most susceptible components are typically insulated and must be located. Once located, accessibility and operating temperatures are complicating issues. This paper describes prioritization issues and hardware tradeoffs for conducting a PMI verification program.

  13. Materials Scientist

    Broader source: Energy.gov [DOE]

    Alternate Title(s):Materials Research Engineer; Metallurgical/Chemical Engineer; Product Development Manager;

  14. Presentation and Structure of Substitutes Meir Bing Daniel Lehmann Paul Milgrom

    E-Print Network [OSTI]

    Lehmann, Daniel

    ; Abstract We propose two di#11;erent methods for presenting (gross-) substitutes valuations. Each providesPresentation and Structure of Substitutes Valuations Meir Bing Daniel Lehmann Paul Milgrom #3 short descriptions for a family of substitutes valuations. We also show that any substitutes valuation

  15. Glutathione-like Tripeptides as Inhibitors of Glutathionylspermidine Synthetase. Part 1: Substitution of the

    E-Print Network [OSTI]

    Schnaufer, Achim

    substituted for other acidic groups such as tetrazole, hydroxamic acid, acylsulphonamide and boronic acid

  16. UTILIZATION OF LIGHTWEIGHT MATERIALS MADE FROM COAL GASIFICATION SLAGS

    SciTech Connect (OSTI)

    Unknown

    2000-04-24T23:59:59.000Z

    The integrated-gasification combined-cycle (IGCC) process is an emerging technology that utilizes coal for power generation and production of chemical feedstocks. However, the process generates large amounts of solid waste, consisting of vitrified ash (slag) and some unconverted carbon. In previous projects, Praxis investigated the utilization of ''as-generated'' slags for a wide variety of applications in road construction, cement and concrete production, agricultural applications, and as a landfill material. From these studies, we found that it would be extremely difficult for ''as-generated'' slag to find large-scale acceptance in the marketplace even at no cost because the materials it could replace were abundantly available at very low cost. It was further determined that the unconverted carbon, or char, in the slag is detrimental to its utilization as sand or fine aggregate. It became apparent that a more promising approach would be to develop a variety of value-added products from slag that meet specific industry requirements. This approach was made feasible by the discovery that slag undergoes expansion and forms a lightweight material when subjected to controlled heating in a kiln at temperatures between 1400 and 1700 F. These results confirmed the potential for using expanded slag as a substitute for conventional lightweight aggregates (LWA). The technology to produce lightweight and ultra-lightweight aggregates (ULWA) from slag was subsequently developed by Praxis with funding from the Electric Power Research Institute (EPRI), Illinois Clean Coal Institute (ICCI), and internal resources. The major objectives of the subject project are to demonstrate the technical and economic viability of commercial production of LWA and ULWA from slag and to test the suitability of these aggregates for, various applications. The project goals are to be accomplished in two phases Phase I, comprising the production of LWA and ULWA from slag at the large pilot scale, and Phase II, which involves commercial evaluation of these aggregates in a number of applications.

  17. Factors Affecting the Battery Performance of Anthraquinone-based Organic Cathode Materials

    SciTech Connect (OSTI)

    Xu, Wu; Read, Adam L.; Koech, Phillip K.; Hu, Dehong; Wang, Chong M.; Xiao, Jie; Padmaperuma, Asanga B.; Graff, Gordon L.; Liu, Jun; Zhang, Jiguang

    2012-02-01T23:59:59.000Z

    Two organic cathode materials based on poly(anthraquinonyl sulfide) structure with different substitution positions were synthesized and their electrochemical behavior and battery performances were investigated. The substitution positions on the anthraquinone structure, binders for electrode preparation and electrolyte formulations have been found to have significant effects on the battery performances of such organic cathode materials. The substitution position with less steric stress has higher capacity, longer cycle life and better high-rate capability. Polyvinylidene fluoride binder and ether-based electrolytes are favorable for the high capacity and long cycle life of the quinonyl organic cathodes.

  18. Accurate Thermochemical Properties for Energetic Materials Applications. II. Heats of Formation of Imidazolium-, 1,2,4-Triazolium-, and Tetrazolium-Based Energetic Salts fromIsodesmic and Lattice Energy Calculations.

    SciTech Connect (OSTI)

    Gutowski, Keith E.; Rogers, Robin D.; Dixon, David A.

    2007-03-01T23:59:59.000Z

    The research described in this product was performed in part in the Environmental Molecular Sciences Laboratory, a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory. A computational approach to the prediction of the heats of formation (?Hf°’s) of solid-state energetic salts from electronic structure and volume-based thermodynamics (VBT) calculations is described. The method uses as its starting point reliable ?Hf°’s for energetic precursor molecules and ions. The ?Hf°’s of more complex energetics species such as substituted imidazole, 1,2,4-triazole, and tetrazole molecules and ions containing amino, azido, and nitro (including methyl) substituents are calculated using an isodesmic approach at the MP2/complete basis set level. On the basis of comparisons to experimental data for neutral analogues, this isodesmic approach is accurate to <3 kcal/mol for the predicted cation and anion ?Hf°’s. The ?Hf°’s of the energetic salts in the solid state are derived from lattice energy (UL) calculations using a VBT approach. Improved values for the ? and ? parameters of 19.9 (kcal nm)/mol and 37.6 kcal/mol for the UL equation were obtained on the basis of comparisons to experimental UL’s for a series of 23 salts containing ammonium, alkylammonium, and hydrazinium cations. The total volumes are adjusted to account for differences between predicted and experimental total volumes due to different shapes of the ions (flat vs spherical). The predicted ?Hf°’s of the energetic salts are estimated to have error bars of 6-7 kcal/mol, on the basis of comparisons to established experimental ?Hf°’s of a subset of the salts studied. Energetic salts with the highest positive ?Hf°’s are predicted for azido-containing cations, coupled with heterocyclic anions containing nitro substituents. The substitution of functional groups on carbon versus nitrogen atoms of the heterocyclic cations has interesting stabilization and destabilization effects, respectively.

  19. weapons material

    National Nuclear Security Administration (NNSA)

    2%2A en Office of Weapons Material Protection http:nnsa.energy.govaboutusourprogramsnonproliferationprogramofficesinternationalmaterialprotectionandcooperation-1

  20. Artificial Photosynthesis II -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    II - Artificial Photosynthesis II - Joint Center for Artificial Photosynthesis (JCAP) Simulations NathanLewis.png Schematic of a photoelectrochemical cell being designed to harness...

  1. A study of the reaction between lead (II) iodide and organic amine hydriodides

    E-Print Network [OSTI]

    Simpson, Frank Martin

    1962-01-01T23:59:59.000Z

    for the degree of NASTER OF SCIENCE AUGUST 1962 Major Sub)cot& CHENISTRY A STUDY OF THE REACTION BETWEEN LEAD(II) IODIDE AND ORGANIC AMINE HYDRIODIDES A Thesis By FRANK MARTIN SIMPSON Approved as to style and content by: Chai of Committee Head... compounds have been prepared by the reaction of lead(II) iodide with various primary, secondary, and tertiary aliphatic and substituted aromati. c amines The melting points, chemical compositions, densities, quali- tative solubilities, and absorption...

  2. Indication of Meissner Effect in Sulfur-Substituted Strontium Ruthenates

    E-Print Network [OSTI]

    Gulian, Armen

    2011-01-01T23:59:59.000Z

    Ceramic samples of Sr2RuO(4-y)Sy (y=0.03-1.2) with intended isovalent substitution of oxygen by sulfur have been synthesized and explored in the temperature range 4-300K. It is found that at a range of optimum sulfur substitution the magnetic response of ceramic samples reveals large diamagnetic signal with amplitudes approaching comparability with that of the YBCO-superconductors. Contrary to a pure ceramic Sr2RuO4, if properly optimized, the resistivity of sulfur-substituted samples has a metallic behavior except at lower temperatures where an upturn occurs. Both synthesis conditions and results of measurements are reported. The Meissner effect may point to high-temperature superconductivity.

  3. Rapid substitution of gold for aluminum metallization on integrated circuits

    SciTech Connect (OSTI)

    Krasopoulos, A.V. [Washington State Univ., Pullman, WA (United States). Dept. of Chemical Engineering; Li, J.; Josowicz, M.; Janata, J. [Pacific Northwest National Lab., Richland, WA (United States)

    1997-03-01T23:59:59.000Z

    A rapid procedure for substitution of gold for aluminum metallization on integrated solid-state circuits, such as solid-state chemical multisensor chips, has been developed. The final product consists of original aluminum overlaid with nickel and gold, both deposited by an electroless process. The final metallization is chemically inert and the resistance of the contacts remains ohmic and unchanged from the original value. The substitution can be performed either at the wafer or at the chip level. After the plasma etching, the metallization process takes only 25 min.

  4. An unusual mono-substituted Keggin anion-chain based 3D framework with 24-membered macrocycles as linker units

    SciTech Connect (OSTI)

    Pang Haijun [Key Laboratory of Green Chemical Engineering and Technology College of Heilongjiang Province, College of Chemical and Environmental Engineering, Harbin University of Science and Technology, Harbin 150040 (China); Ma Huiyuan, E-mail: mahy017@163.com [Key Laboratory of Green Chemical Engineering and Technology College of Heilongjiang Province, College of Chemical and Environmental Engineering, Harbin University of Science and Technology, Harbin 150040 (China); Yu Yan; Yang Ming; Xun Ye [Key Laboratory of Green Chemical Engineering and Technology College of Heilongjiang Province, College of Chemical and Environmental Engineering, Harbin University of Science and Technology, Harbin 150040 (China); Liu Bo, E-mail: liubo200400@vip.sina.com [Key Laboratory of Green Chemical Engineering and Technology College of Heilongjiang Province, College of Chemical and Environmental Engineering, Harbin University of Science and Technology, Harbin 150040 (China)

    2012-02-15T23:59:59.000Z

    A new compound, [Cu{sup I}(H{sub 2}O)(Hbpp){sub 2}] Subset-Of {l_brace}[Cu{sup I}(bpp)]{sub 2}[PW{sub 11}Cu{sup II}O{sub 39}]{r_brace} (1) (bpp=1,3-bis(4-pyridyl)propane), has been hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction. In compound 1, the unusual -A-B-A-B- array mono-substituted Keggin anion-chains and 24-membered (Cubpp){sub 2} cation-macrocycles are linked together to form a (2, 4) connected 3D framework with channels of ca. 9.784 Multiplication-Sign 7.771 A{sup 2} along two directions, in which the [Cu(H{sub 2}O)(Hbpp){sub 2}] coordination fragments as guest components are trapped. The photocatalytic experiments of compound 1 were performed, which show a good catalytic activity of compound 1 for photodegradation of RhB. Furthermore, the IR, TGA and electrochemical properties of compound 1 were investigated. - Graphical abstract: An unusual example of mono-substituted Keggin anion-chain based hybrid compound that possesses a 3D structure has been synthesized, which offers a feasible route for synthesis of such compounds. Highlights: Black-Right-Pointing-Pointer The first example of -A-B-A-B- array mono-substituted Keggin chain is observed. Black-Right-Pointing-Pointer An unusual three dimensional structure based mono-substituted Keggin anion-chains. Black-Right-Pointing-Pointer The photocatalysis and electrochemical properties of the title compound were studied.

  5. Scintillator material

    DOE Patents [OSTI]

    Anderson, D.F.; Kross, B.J.

    1992-07-28T23:59:59.000Z

    An improved scintillator material comprising cerium fluoride is disclosed. Cerium fluoride has been found to provide a balance of good stopping power, high light yield and short decay constant that is superior to known scintillator materials such as thallium-doped sodium iodide, barium fluoride and bismuth germanate. As a result, cerium fluoride is favorably suited for use as a scintillator material in positron emission tomography. 4 figs.

  6. Scintillator material

    DOE Patents [OSTI]

    Anderson, D.F.; Kross, B.J.

    1994-06-07T23:59:59.000Z

    An improved scintillator material comprising cerium fluoride is disclosed. Cerium fluoride has been found to provide a balance of good stopping power, high light yield and short decay constant that is superior to known scintillator materials such as thallium-doped sodium iodide, barium fluoride and bismuth germanate. As a result, cerium fluoride is favorably suited for use as a scintillator material in positron emission tomography. 4 figs.

  7. Scintillator material

    DOE Patents [OSTI]

    Anderson, David F. (Batavia, IL); Kross, Brian J. (Aurora, IL)

    1992-01-01T23:59:59.000Z

    An improved scintillator material comprising cerium fluoride is disclosed. Cerium fluoride has been found to provide a balance of good stopping power, high light yield and short decay constant that is superior to known scintillator materials such as thallium-doped sodium iodide, barium fluoride and bismuth germanate. As a result, cerium fluoride is favorably suited for use as a scintillator material in positron emission tomography.

  8. Scintillator material

    DOE Patents [OSTI]

    Anderson, David F. (Batavia, IL); Kross, Brian J. (Aurora, IL)

    1994-01-01T23:59:59.000Z

    An improved scintillator material comprising cerium fluoride is disclosed. Cerium fluoride has been found to provide a balance of good stopping power, high light yield and short decay constant that is superior to known scintillator materials such as thallium-doped sodium iodide, barium fluoride and bismuth germanate. As a result, cerium fluoride is favorably suited for use as a scintillator material in positron emission tomography.

  9. Hydrology Days 2014 Thermally Enhanced Attenuation of Substituted Benzenes

    E-Print Network [OSTI]

    as a remediation technique for substituted benzenes, anaerobic soil microcosms were constructed using soils from microcosms have produced less biogas than previous petroleum microcosm studies. This suggests at the field site. The device allows for the determination of water quality, temperature, and resistivity

  10. Adsorption, desorption, and stabilization of arsenic on aluminum substituted ferrihydrite

    E-Print Network [OSTI]

    Masue, Yoko

    2006-04-12T23:59:59.000Z

    systems were evaluated by studying their mineralogy, stability, and As adsorption and desorption behavior. The broad XRD peaks revealed that Al was substituted into the ferrihydrite structure and that this was the only major product up to about a 2:8 Al...

  11. Datasets for the Evaluation of Substitution-Tolerant Subgraph Isomorphism

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Datasets for the Evaluation of Substitution-Tolerant Subgraph Isomorphism Pierre H´eroux LITIS EA datasets allowing to evaluate the performance of subgraph iso- morphism approaches in presence of noisy data. In this paper, we present three datasets that can be used to evaluate the performance

  12. A feasibility study of a gelatin-based tissue substitute

    E-Print Network [OSTI]

    Spence, Jody Lee

    1993-01-01T23:59:59.000Z

    experiments was begun in the 1970's by Poston and colleagues at the Oak Ridge National Laboratory (ORNL). During the course of this research many types of detectors and tissue substitutes were used. Early investigations by Garry et al. (1975) used a...

  13. Vacancy mediated substitutional diffusion in binary crystalline solids

    E-Print Network [OSTI]

    Ceder, Gerbrand

    Vacancy mediated substitutional diffusion in binary crystalline solids Anton Van der Ven a,*, Hui coefficients of substi- tutional alloys from first principles. The focus is restricted to vacancy mediated and grain boundaries that can act as vacancy sources) and diffusion in a solid containing a continuous

  14. Redox chromophore compounds and electrodes of metal containing substituted bipyridines

    DOE Patents [OSTI]

    Elliott, Cecil M. (Fort Collins, CO); Redepenning, Jody G. (Fort Collins, CO)

    1986-01-01T23:59:59.000Z

    Chromophoric compounds, each having a wide range of distinct color changes in response to changes in the oxidation states thereof, are provided in the form of polymerizable monomers, and polymers thereof, of certain metal containing, and electron group substituted, 2,2'-bipyridine compounds.

  15. Critical Materials:

    Broader source: Energy.gov (indexed) [DOE]

    lighting. 14 (bottom) Criticality ratings of shortlisted raw 76 materials. 15 77 2. Technology Assessment and Potential 78 This section reviews the major trends within...

  16. Military Formations: Mexican American Civil Rights And Community Belonging During The World War II Era

    E-Print Network [OSTI]

    Bueno, Marianne

    2012-01-01T23:59:59.000Z

    Force Material Command Cold War Context, 1945-1991, vol. 2,and Job Politics during World War II. Austin: University ofin Earnings during World War II: New Evidence." Industrial

  17. Substituted copper phthalocyanine/multiwalled carbon nanotubes hybrid material for Cl{sub 2} sensing application

    SciTech Connect (OSTI)

    Sharma, Anshul Kumar, E-mail: dramanmahajan@yahoo.co.in; Saini, Rajan, E-mail: dramanmahajan@yahoo.co.in; Singh, Rajinder, E-mail: dramanmahajan@yahoo.co.in; Mahajan, Aman, E-mail: dramanmahajan@yahoo.co.in; Bedi, R. K., E-mail: dramanmahajan@yahoo.co.in [Material Science Laboratory, Department of Physics, Guru Nanak Dev University, Amritsar-143005 (India); Aswal, D. K. [Technical Physics Division, Bhabha Atomic Research Center, Mumbai-400085 (India)

    2014-04-24T23:59:59.000Z

    In this work, hybrid of soluble copper phthalocyanine (CuPcOC{sub 8}) and functionalized multi-walled carbon nanotubes (MWCNTs) has been synthesized. The formation of CuPcOC{sub 8}-MWCNTs hybrid is confirmed by atomic force microscopy, UV-Visible and FTIR spectroscopy. Subsequently, a chemi-resistive sensor is fabricated by drop casting CuPcOC{sub 8}-MWCNTs hybrid onto glass substrate. It has been demonstrated that CuPcOC{sub 8}-MWCNTs hybrid is highly selective towards Cl{sub 2} gas with minimum detection limit of 100 ppb. The response of sensor increases linearly with increase in the concentration of Cl{sub 2} gas. For 2000 ppb of Cl{sub 2}, CuPcOC{sub 8}-MWCNTs hybrid gives a response as large as 53% in 40 seconds.

  18. Substitution for petroleum products in Brasil: Urgent issues

    SciTech Connect (OSTI)

    de Araujo, J.L.; Ghirardi, A.

    1986-06-01T23:59:59.000Z

    Brazililan energy policy during the last decade has focused on the replacement of imported petroleum with domestic energy sources, combined with efforts at conservation. The substitution results, however, have been more spectacular by far. The strategy of replacement is based on two elements. first, to increase domestic petroleum exploration and production. Second, to promote non-petroleum fuels as alternatives to the industrial and transportation sectors, for the substitution of fuel oil and gasoline, respectively. A combination of the substitution strategy, the country's petroleum refining structure, and the composition of the substitution strategy, the country's petroleum refining structure, and the composition of demand, has resulted in large surpluses of both gasoline and fuel oil, while diesel has become the most used among petroleum products. The surpluses are not easily exportable because there is ample availability of fuel oil in the world market, and because the low octane number of the gasoline produced in Brasil is not compatible with the engines of cars elsewhere in the region and in the world. Furthermore, although gasoline might be upgraded, the question remains that prospects for the world market are not encouraging, and an export-based strategy does not seem justified in view of the growing surpluses. The objective of this analysis is to review the mechanisms of themajor petroleum-substitution programs currently in existence, identifying their past impact on the energy market and the possible consequences of changes in the goals and operating conditions of these programs, in the light of the new prospects for increased domestic oil production and self-sufficiency. 23 refs., 2 figs., 1 tab.

  19. Cermet materials

    DOE Patents [OSTI]

    Kong, Peter C. (Idaho Falls, ID)

    2008-12-23T23:59:59.000Z

    A self-cleaning porous cermet material, filter and system utilizing the same may be used in filtering particulate and gaseous pollutants from internal combustion engines having intermetallic and ceramic phases. The porous cermet filter may be made from a transition metal aluminide phase and an alumina phase. Filler materials may be added to increase the porosity or tailor the catalytic properties of the cermet material. Additionally, the cermet material may be reinforced with fibers or screens. The porous filter may also be electrically conductive so that a current may be passed therethrough to heat the filter during use. Further, a heating element may be incorporated into the porous cermet filter during manufacture. This heating element can be coated with a ceramic material to electrically insulate the heating element. An external heating element may also be provided to heat the cermet filter during use.

  20. Supporting Infrastructure and Acceptability Issues for Materials Used in New Generation Vehicles

    SciTech Connect (OSTI)

    Das, S.; Curlee, T.R.; Jones, D.W.; Leiby, P.E.; Rubin, J.D.; Schexnayder, S.M.; Vogt, D.P.; Wolfe, A.K.

    1999-03-01T23:59:59.000Z

    To achieve its goal of producing vehicles that use two thirds less fuel than current vehicles, the Partnership of a New Generation of Vehicles (PNGV) is designing vehicles that will use lightweight materials in place of heavier materials used in current vehicles. using new materials in automobiles will require the development of a supporting infrastructure to produce both the substitute materials and the components of the substitute materials, as well as the automotive parts constructed from the new materials. This report documents a set of analyses that attempt to identify potential barriers--economic, infrastructure, and public acceptance barriers--to the materials substitution in New Generation Vehicles. The analyses rely on hypothetical vehicle market penetration scenarios and material composition. The approach is comprehensive, examining issues ranging from materials availability to their eventual disposition and its effect on the automobile recycling industry, and from supporting industries' capacity to the public acceptability of these vehicles. The analyses focus on two likely substitute materials, aluminum and glass-reinforced polymer composites.

  1. New Vendor/Substitute W-9 Form BUSINESS Revised: 10/03/2013

    E-Print Network [OSTI]

    Royer, Dana

    New Vendor/Substitute W-9 Form BUSINESS Revised: 10/03/2013 New Vendor/Substitute W-9 Form- FOR U.S. BUSINESSES THE UNIVERSITY WILL NOT PAY VENDORS UNTIL THIS FORM IS PROVIDED Check all appropriate business

  2. Gas permeability measurements for film envelope materials

    DOE Patents [OSTI]

    Ludtka, G.M.; Kollie, T.G.; Watkin, D.C.; Walton, D.G.

    1998-05-12T23:59:59.000Z

    Method and apparatus for measuring the permeability of polymer film materials such as used in super-insulation powder-filled evacuated panels (PEPs) reduce the time required for testing from several years to weeks or months. The method involves substitution of a solid non-outgassing body having a free volume of between 0% and 25% of its total volume for the usual powder in the PEP to control the free volume of the ``body-filled panel.`` Pressure versus time data for the test piece permit extrapolation to obtain long term performance of the candidate materials. 4 figs.

  3. Gas permeability measurements for film envelope materials

    DOE Patents [OSTI]

    Ludtka, Gerard M. (Oak Ridge, TN); Kollie, Thomas G. (Oak Ridge, TN); Watkin, David C. (Clinton, TN); Walton, David G. (Knoxville, TN)

    1998-01-01T23:59:59.000Z

    Method and apparatus for measuring the permeability of polymer film materials such as used in super-insulation powder-filled evacuated panels (PEPs) reduce the time required for testing from several years to weeks or months. The method involves substitution of a solid non-outgassing body having a free volume of between 0% and 25% of its total volume for the usual powder in the PEP to control the free volume of the "body-filled panel". Pressure versus time data for the test piece permit extrapolation to obtain long term performance of the candidate materials.

  4. Copyright 0 1996 by the Genetics Society of America Patterns of Nucleotide Substitution in Mitochondrial Protein Coding

    E-Print Network [OSTI]

    Kumar, Sudhir

    Copyright 0 1996 by the Genetics Society of America Patterns of Nucleotide Substitution to study the differences in substitution rates among the four nucleotides and among different, the frequencyof nucleotideGis negativelycorrelatedwith evolution- ary ratesof genes, substitution rates vary

  5. Phase II Final Report

    SciTech Connect (OSTI)

    Schuknecht, Nate [Project Manager; White, David [Principle Investigator; Hoste, Graeme [Research Engineer

    2014-09-11T23:59:59.000Z

    The SkyTrough DSP will advance the state-of-the-art in parabolic troughs for utility applications, with a larger aperture, higher operating temperature, and lower cost. The goal of this project was to develop a parabolic trough collector that enables solar electricity generation in the 2020 marketplace for a 216MWe nameplate baseload power plant. This plant requires an LCOE of 9˘/kWhe, given a capacity factor of 75%, a fossil fuel limit of 15%, a fossil fuel cost of $6.75/MMBtu, $25.00/kWht thermal storage cost, and a domestic installation corresponding to Daggett, CA. The result of our optimization was a trough design of larger aperture and operating temperature than has been fielded in large, utility scale parabolic trough applications: 7.6m width x 150m SCA length (1,118m2 aperture), with four 90mm diameter × 4.7m receivers per mirror module and an operating temperature of 500°C. The results from physical modeling in the System Advisory Model indicate that, for a capacity factor of 75%: The LCOE will be 8.87˘/kWhe. SkyFuel examined the design of almost every parabolic trough component from a perspective of load and performance at aperture areas from 500 to 2,900m2. Aperture-dependent design was combined with fixed quotations for similar parts from the commercialized SkyTrough product, and established an installed cost of $130/m2 in 2020. This project was conducted in two phases. Phase I was a preliminary design, culminating in an optimum trough size and further improvement of an advanced polymeric reflective material. This phase was completed in October of 2011. Phase II has been the detailed engineering design and component testing, which culminated in the fabrication and testing of a single mirror module. Phase II is complete, and this document presents a summary of the comprehensive work.

  6. INVERTIBLE SUBSTITUTIONS WITH A COMMON PERIODIC HUI RAO AND ZHI-YING WEN

    E-Print Network [OSTI]

    Rao, Hui

    INVERTIBLE SUBSTITUTIONS WITH A COMMON PERIODIC POINT HUI RAO AND ZHI-YING WEN Abstract. We characterize the invertible substitutions over a two-letter alphabet which share a common periodic point (or for some n 1. A substitution is said invertible if it is an automorphism of the free group F generated

  7. Syst. Biol. 50(4):580601, 2001 Selecting the Best-Fit Model of Nucleotide Substitution

    E-Print Network [OSTI]

    Posada, David

    Syst. Biol. 50(4):580­601, 2001 Selecting the Best-Fit Model of Nucleotide Substitution DAVID.--Despite the relevant role of models of nucleotide substitution in phylogenetics, choosing among different models of nucleotide substitution. We speci cally examine the role of the topology used to estimate the likelihood

  8. Estimating a Nucleotide Substitution Rate for Maize from Polymorphism at a Major Domestication Locus

    E-Print Network [OSTI]

    Doebley, John

    Estimating a Nucleotide Substitution Rate for Maize from Polymorphism at a Major Domestication To estimate a rate for single nucleotide substitutions for maize (Zea mays ssp. mays), we have taken advantage ge- nealogy, we have derived estimates for the nucleotide substitution rate for the tb1 intergenic

  9. Quantifying the Equilibrium and Irreversibility Properties of the Nucleotide Substitution Process

    E-Print Network [OSTI]

    Spang, Rainer

    Quantifying the Equilibrium and Irreversibility Properties of the Nucleotide Substitution Process and Irreversibility Properties of the Nucleotide Substitution Process ­ p.1 #12;A Crash Course in Molecular Evolution AGTCCCTTT Quantifying the Equilibrium and Irreversibility Properties of the Nucleotide Substitution Process

  10. Complex Materials

    ScienceCinema (OSTI)

    Cooper, Valentino

    2014-05-23T23:59:59.000Z

    Valentino Cooper uses some of the world's most powerful computing to understand how materials work at subatomic levels, studying breakthroughs such as piezoelectrics, which convert mechanical stress to electrical energy.

  11. Complex Materials

    SciTech Connect (OSTI)

    Cooper, Valentino

    2014-04-17T23:59:59.000Z

    Valentino Cooper uses some of the world's most powerful computing to understand how materials work at subatomic levels, studying breakthroughs such as piezoelectrics, which convert mechanical stress to electrical energy.

  12. Material Symbols 

    E-Print Network [OSTI]

    Clark, Andy

    2006-01-01T23:59:59.000Z

    What is the relation between the material, conventional symbol structures that we encounter in the spoken and written word, and human thought? A common assumption, that structures a wide variety of otherwise competing ...

  13. Materializing Energy

    E-Print Network [OSTI]

    James Pierce; Eric Paulos

    Motivated and informed by perspectives on sustainability and design, this paper draws on a diverse body of scholarly works related to energy and materiality to articulate a perspective on energy-as-materiality and propose a design approach of materializing energy. Three critical themes are presented: the intangibility of energy, the undifferentiatedness of energy, and the availability of energy. Each theme is developed through combination of critical investigation and design exploration, including the development and deployment of several novel design artifacts: Energy Mementos and The Local Energy Lamp. A framework for interacting with energy-as-materiality is proposed involving collecting, keeping, sharing, and activating energy. A number of additional concepts are also introduced, such as energy attachment, energy engagement, energy attunement, local energy and energy meta-data. Our work contributes both a broader, more integrative design perspective on energy and materiality as well as a diversity of more specific concepts and artifacts that may be of service to designers and researchers of interactive systems concerned with sustainability and energy. Author Keywords Sustainability, energy, materiality, design, design theory

  14. Metalloenzyme chemistry: thermostability study and metal dissociation constant measurement of thermolysin, Co˛? substituted thermolysin, E. coli Zn˛?-FDP aldolase, and Co˛? substituted E. coli FDP aldolase

    E-Print Network [OSTI]

    Chen, Yie Lane

    1989-01-01T23:59:59.000Z

    . Giedroc (Member) rchael B a (Head of D rtm nt) i~ December 1989 111 ABSTRACT Metalloenzyme Chemistry: Thermostability Study and Metal Dissociation Constant Measurement of Thermolysin, Co 2+ Substituted Thermolysin, E. coli Zn -FDP aldolase, and 2...+ Co Substituted E. coli FDP Aldolase (December 1989) Yie Lane Chen, B. S. , National Taiwan University, Taipei, Taiwan, R. 0. C. Chair of Advisory Committee: Dr. Chi-Huey Wong Co substituted thermolysin was prepared from 2+ apothermolysin...

  15. Spectra of Discrete Schrödinger Operators with Primitive Invertible Substitution Potentials

    E-Print Network [OSTI]

    May Mei

    2014-07-02T23:59:59.000Z

    We study the spectral properties of discrete Schr\\"odinger operators with potentials given by primitive invertible substitution sequences (or by Sturmian sequences whose rotation angle has an eventually periodic continued fraction expansion, a strictly larger class than primitive invertible substitution sequences). It is known that operators from this family have spectra which are Cantor sets of zero Lebesgue measure. We show that the Hausdorff dimension of this set tends to $1$ as coupling constant $\\lambda$ tends to $0$. Moreover, we also show that at small coupling constant, all gaps allowed by the gap labeling theorem are open and furthermore open linearly with respect to $\\lambda$. Additionally, we show that, in the small coupling regime, the density of states measure for an operator in this family is exact dimensional. The dimension of the density of states measure is strictly smaller than the Hausdorff dimension of the spectrum and tends to $1$ as $\\lambda$ tends to $0$.

  16. Cement substitution by a combination of metakaolin and limestone

    SciTech Connect (OSTI)

    Antoni, M., E-mail: mathieu.antoni@epfl.ch [EPFL-STI-IMX-Laboratoires des Materiaux de Construction, Station12, CH-1015 Lausanne (Switzerland); Rossen, J. [EPFL-STI-IMX-Laboratoires des Materiaux de Construction, Station12, CH-1015 Lausanne (Switzerland)] [EPFL-STI-IMX-Laboratoires des Materiaux de Construction, Station12, CH-1015 Lausanne (Switzerland); Martirena, F. [CIDEM-UCLV, Universidad Las Villas, Santa Clara (Cuba)] [CIDEM-UCLV, Universidad Las Villas, Santa Clara (Cuba); Scrivener, K. [EPFL-STI-IMX-Laboratoires des Materiaux de Construction, Station12, CH-1015 Lausanne (Switzerland)] [EPFL-STI-IMX-Laboratoires des Materiaux de Construction, Station12, CH-1015 Lausanne (Switzerland)

    2012-12-15T23:59:59.000Z

    This study investigates the coupled substitution of metakaolin and limestone in Portland cement (PC). The mechanical properties were studied in mortars and the microstructural development in pastes by X-ray diffraction, thermogravimetry analysis, mercury intrusion porosimetry and isothermal calorimetry. We show that 45% of substitution by 30% of metakaolin and 15% of limestone gives better mechanical properties at 7 and 28 days than the 100% PC reference. Our results show that calcium carbonate reacts with alumina from the metakaolin, forming supplementary AFm phases and stabilizing ettringite. Using simple mass balance calculations derived from thermogravimetry results, we also present the thermodynamic simulation for the system, which agrees fairly well with the experimental observations. It is shown that gypsum addition should be carefully balanced when using calcined clays because it considerably influences the early age strength by controlling the very rapid reaction of aluminates.

  17. Rapid Microwave Preparation of Highly Efficient Ce[superscript 3+]-Substituted Garnet Phosphors for Solid State White Lighting

    SciTech Connect (OSTI)

    Birkel, Alexander; Denault, Kristin A.; George, Nathan C.; Doll, Courtney E.; Héry, Bathylle; Mikhailovsky, Alexander A.; Birkel, Christina S.; Hong, Byung-Chul; Seshadri, Ram (UCSB); (Mitsubishi)

    2012-04-30T23:59:59.000Z

    Ce{sup 3+}-substituted aluminum garnet compounds of yttrium (Y{sub 3}Al{sub 5}O{sub 12}) and lutetium (Lu{sub 3}Al{sub 5}O{sub 12}) - both important compounds in the generation of (In,Ga)N-based solid state white lighting - have been prepared using a simple microwave heating technique involving the use of a microwave susceptor to provide the initial heat source. Carbon used as the susceptor additionally creates a reducing atmosphere around the sample that helps stabilize the desired luminescent compound. High quality, phase-pure materials are prepared within a fraction of the time and using a fraction of the energy required in a conventional ceramic preparation; the microwave technique allows for a reduction of about 95% in preparation time, making it possible to obtain phase pure, Ce{sup 3+}-substituted garnet compounds in under 20 min of reaction time. It is estimated that the overall reduction in energy compared with ceramic routes as practiced in the lab is close to 99%. Conventionally prepared material is compared with material prepared using microwave heating in terms of structure, morphology, and optical properties, including quantum yield and thermal quenching of luminescence. Finally, the microwave-prepared compounds have been incorporated into light-emitting diode 'caps' to test their performance characteristics in a real device, in terms of their photon efficiency and color coordinates.

  18. Vortex pinning by inhomogeneities in type-II superconductors

    E-Print Network [OSTI]

    Chapman, Jon

    Vortex pinning by inhomogeneities in type-II superconductors S.J. Chapman #3;y G. Richardson zx of a curvilinear vortex in an inhomogeneous type-II superconducting material in the limit as the vortex core radius of the superconducting electrons acts as a pinning potential for the vortex, so that vortices will be attracted

  19. Thermoelectric materials development. Final report

    SciTech Connect (OSTI)

    Fleurial, J.P.; Caillat, T.; Borshchevsky, A.

    1998-09-01T23:59:59.000Z

    A systematic search for advanced thermoelectric materials was initiated at JPL several years ago to evaluate candidate materials which includes consideration of the following property attributes: (1) semiconducting properties; (2) large Seebeck coefficient; (3) high carrier mobility and high electrical conductivity; (4) low lattice thermal conductivity; and (5) chemical stability and low vapor pressure. Through this candidate screening process, JPL identified several families of materials as promising candidates for improved thermoelectric materials including the skutterudite family. There are several programs supporting various phases of the effort on these materials. As part of an ongoing effort to develop skutterudite materials with lower thermal conductivity values, several solid solutions and filled skutterudite materials were investigated under the effort sponsored by DOE. The efforts have primarily focused on: (1) study of existence and properties of solid solutions between the binary compounds CoSb{sub 3} and IrSb{sub 3}, and RuSb{sub 2}Te, and (2) CeFe{sub 4{minus}x}Sb{sub 12} based filled compositions. For the solid solutions, the lattice thermal conductivity reduction was expected to be reduced by the introduction of the Te and Ru atoms while in the case of CeFe{sub 4{minus}x}Ru{sub x}Sb{sub 12} based filled compositions. For the solid solutions, the lattice thermal conductivity reduction was expected to be reduced by the introduction of the Te and Ru atoms while in the case of CeFe{sub 4{minus}x}Ru{sub x}Sb{sub 12} filled compositions, the reduction would be caused by the rattling of Ce atoms located in the empty voids of the skutterudite structure and the substitution of Fe for Ru. The details of the sample preparation and characterization of their thermoelectric properties are reported in this report.

  20. Hardfacing material

    DOE Patents [OSTI]

    Branagan, Daniel J. (Iona, ID)

    2012-01-17T23:59:59.000Z

    A method of producing a hard metallic material by forming a mixture containing at least 55% iron and at least one of boron, carbon, silicon and phosphorus. The mixture is formed into an alloy and cooled to form a metallic material having a hardness of greater than about 9.2 GPa. The invention includes a method of forming a wire by combining a metal strip and a powder. The metal strip and the powder are rolled to form a wire containing at least 55% iron and from two to seven additional elements including at least one of C, Si and B. The invention also includes a method of forming a hardened surface on a substrate by processing a solid mass to form a powder, applying the powder to a surface to form a layer containing metallic glass, and converting the glass to a crystalline material having a nanocrystalline grain size.

  1. Department of Materials Science and Engineering Four Year Plan (2011-12 Catalog)

    E-Print Network [OSTI]

    Barrash, Warren

    3 MSE 482 Senior Project II 3 MSE 404L Materials Analysis Lab 1 Technical or engineering elective 3 of Materials MSE 480 Senior Project I MSE 482 Senior Project II 2 6 7 12 11 ENGR 120 IntroductionDepartment of Materials Science and Engineering Four Year Plan (2011-12 Catalog) FALL SEMESTER

  2. Neutronics analysis for HYLIFE-II

    SciTech Connect (OSTI)

    Tobin, M.T.

    1990-12-20T23:59:59.000Z

    A preliminary neutronics analysis of the HYLIFE-2 reactor concept gives a tritium breeding ratio of 1.17 and a system energy multiplication factor of 1.14. Modified SS-316 (in which Mn is substituted for Ni) is superior to Hastelloy X and Hastelloy N as a firstwall material considering He generation, dpa-limited lifetime, and shallow-burial index. Since Flibe is corrosive to Mn metals, however, a favorable first-wall material is yet to be decided on. Flibe impurities considered (e.g., inherent impurities and those arising from wall erosion or secondary-coolant leakage) do not increase the hazard to the public over that of pure Flibe. The main issues for HYLIFE-2 are the high shallow-burial index (106) and the requirement to contain some 99.7% of the {sup 18}F inventory to prevent its release to the public 18 refs., 3 figs., 9 tabs.

  3. Nd–Co substituted strontium hexaferrite powders with enhanced coercivity

    SciTech Connect (OSTI)

    Herme, C.A. [Facultad de Ingeniería, Universidad de Buenos Aires, LAFMACEL-INTECIN, Paseo Colón 850, 1063 Buenos Aires (Argentina)] [Facultad de Ingeniería, Universidad de Buenos Aires, LAFMACEL-INTECIN, Paseo Colón 850, 1063 Buenos Aires (Argentina); Bercoff, P.G., E-mail: bercoff@famaf.unc.edu.ar [Facultad de Matemática, Astronomía y Física, Universidad Nacional de Córdoba, IFEG, CONICET, Ciudad Universitaria, 5000 Córdoba (Argentina); Jacobo, S.E. [Facultad de Ingeniería, Universidad de Buenos Aires, LAFMACEL-INTECIN, Paseo Colón 850, 1063 Buenos Aires (Argentina)] [Facultad de Ingeniería, Universidad de Buenos Aires, LAFMACEL-INTECIN, Paseo Colón 850, 1063 Buenos Aires (Argentina)

    2012-11-15T23:59:59.000Z

    Graphical abstract: Display Omitted Highlights: ? Sr{sub 1?x}Nd{sub x}Fe{sub 11?x}Co{sub x}O{sub 19} was prepared by sol–gel auto-combustion method with 0 ? x ? 0.4. ? Coercivity increases 11% with 0.2 Nd–Co substitution, reaching a value of 68.9 A/m. ? The appearance of two magnetic orderings is noticed in susceptibility measurements. ? This is supported by Curie temperature and susceptibility data. -- Abstract: In this work we report the synthesis of Nd–Co substituted strontium hexaferrites of composition Sr{sub 1?x}Nd{sub x}Fe{sub 11?x}Co{sub x}O{sub 19} by the sol–gel auto-combustion method with further heat treatment. The analysis of the X-ray diffraction spectra shows the M-type hexagonal structure in samples treated at 1100 °C for 2 h. Coercivity increases 11% with 0.2 Nd–Co substitution, reaching a value of 68.9 A/m (5480 Oe) while saturation magnetization is reduced 6% to 91 A m{sup 2}/kg (91 emu/g). The behavior of magnetic susceptibility with an applied field shows two different maxima which are assigned to different magnetic orderings. This assumption is supported by the appearance of two experimental values of Curie temperatures (T{sub C}) for all the prepared samples. Magnetic susceptibility ? and T{sub C} measurements suggest an uneven distribution of the iron vacancies.

  4. Materials Science & Tech Division | Advanced Materials | ORNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Materials Science and Technology SHARE Materials Science and Technology Division The Materials Science and Technology Division is unique within the Department of Energy (DOE)...

  5. Interfuel Substitution and Energy Use in the UK Manufacturing Sector

    E-Print Network [OSTI]

    Steinbuks, Jevgenijs

    of the following reasons. First, studies based on the aggregate data fail to account for large di¤erences in technological requirements for fuel types used in speci?c industries. For ex- ample, most cement kilns today use coal and petroleum coke as primary fuels... in the manufacturing processes. Waverman (1992) pointed out that fuels used by industrial sectors for non-energy purposes, such as coking coal, petrochemical feedstocks, or lubricants, have few available substitutes, and should therefore be excluded from the data...

  6. Effects of Ti substitution on structural and magnetic properties of Zn–Mn ferrospinels

    SciTech Connect (OSTI)

    Patil, R.P., E-mail: raj_rbm_raj@yahoo.com [Department of Chemistry, Shivaji University, Kolhapur 416004 (India); Patil, N.M. [Department of Chemistry, Shivaji University, Kolhapur 416004 (India); Sasikala, R. [Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400085 (India); Hankare, P.P., E-mail: p_hankarep@rediffmail.com [Department of Chemistry, Shivaji University, Kolhapur 416004 (India); Delekar, S.D. [Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Sub-campus Osmanabad, 413501 (India)

    2013-05-15T23:59:59.000Z

    Highlights: ? Novel system ZnMn{sub 1?x}Ti{sub x}FeO{sub 4} synthesized by sol–gel route. ? Nanocrystalline materials. ? Magnetic materials. - Abstract: Nanocrystalline ZnMn{sub 1?x}Ti{sub x}FeO{sub 4} (1.0 ? x ? 0) ferrites were prepared by sol–gel route. Formation of single phase cubic spinel structure for all the compositions was confirmed from their X-ray diffraction patterns. The lattice parameter shows an increasing trend with the increase in Ti content. These ferrite samples existed as crystalline nanoparticles of about 30–40 nm size as observed from transmission electron microscopy (TEM) technique. EDAX analysis indicated that the concentration of different elements in different compositions is in close agreement with the starting concentrations. Infrared spectra showed two main absorption bands in the range 400–800 cm{sup ?1} arising due to tetrahedral (A) and octahedral (B) stretching vibrations. The magnetic studies indicated that, the ferrimagnetic behavior increases with titanium substitution.

  7. Task II: evaluation of heat-exchanger and turbine materials for use in a coal-fired fluidized-bed-combustion environment. Final report, July 1, 1976-July 31, 1980

    SciTech Connect (OSTI)

    Not Available

    1981-09-30T23:59:59.000Z

    Specific alloys were tested as in-bed and above-bed heat exchanger materials in the fireside environment of a pressurized fluidized bed coal combustor (PFBCC). Corrosion conditions on the alloys exposed to normal and very low oxygen pressures in the presence of calcium sulfate deposits were simulated. Bayonet-type specimen probes of selected alloys were exposed in the Exxon Miniplant at probe control temperatures representative of conventional steam, advanced steam, helium and liquid metal energy conversion cycles. Corrosion/erosion testing of the air cooled, welded samples consisted of a 117-hour shakedown run followed by an incremental 1000-hour exposure. Metallurgical analyses were run on removed specimens. The test matrix for in-bed and above-bed exposure was: 1050/sup 0/F (566/sup 0/C): 2.25 Cr-1Mo and 9Cr-1Mo steels (in-bed only); 1200/sup 0/F (649/sup 0/C): 304 SS and Incoloy-800; 1400/sup 0/F (760/sup 0/C): Incoloy-800 and Hastelloy-X; and 1600/sup 0/F (871/sup 0/C); Hastelloy-X and Haynes-188. Subscale sulfides formed in most of the alloys. The most severe corrosion was noted in the ferritic 2.25Cr-1Mo and 9Cr-1Mo steels at a nominal control temperature of 1050/sup 0/F (566/sup 0/C) and in Hastelloy-X at 1400/sup 0/F (760/sup 0/C) exposed in-bed. The best overall behavior of in-bed alloys was observed for Incoloy-800, which had a maximum metal loss of about .007 in (.18 mm) in 1117 hours of exposure at both 1200/sup 0/F (649/sup 0/C) and 1400/sup 0/F (760/sup 0/C) but averaged more nearly .001 in (.025 mm) to .002 in (.051 mm) and in Haynes-188 which showed maximum wall thinning of less than .003 in (.076 mm) at 1600/sup 0/F (871/sup 0/C) in the longest time exposure.

  8. ACRA-II

    Energy Science and Technology Software Center (OSTI)

    003089IBMPC00 ACRA-II: Kernel Integration Code System for Estimation of Radiation Doses Caused by a Hypothetical Reactor Accident   

  9. CSC6870 Computer Graphics II CSC6870 Computer Graphics II

    E-Print Network [OSTI]

    Hua, Jing

    CSC6870 Computer Graphics II Surfaces CSC6870 Computer Graphics II Surfaces · Plane · Quadratic. CSC6870 Computer Graphics II Plane and Intersection CSC6870 Computer Graphics II Plane Equations · General plane equation ax+by+cz+d=0 · Normal of the plane n=[a, b, c] CSC6870 Computer Graphics II

  10. Casting materials

    DOE Patents [OSTI]

    Chaudhry, Anil R. (Xenia, OH); Dzugan, Robert (Cincinnati, OH); Harrington, Richard M. (Cincinnati, OH); Neece, Faurice D. (Lyndurst, OH); Singh, Nipendra P. (Pepper Pike, OH)

    2011-06-14T23:59:59.000Z

    A foam material comprises a liquid polymer and a liquid isocyanate which is mixed to make a solution that is poured, injected or otherwise deposited into a corresponding mold. A reaction from the mixture of the liquid polymer and liquid isocyanate inside the mold forms a thermally collapsible foam structure having a shape that corresponds to the inside surface configuration of the mold and a skin that is continuous and unbroken. Once the reaction is complete, the foam pattern is removed from the mold and may be used as a pattern in any number of conventional casting processes.

  11. Reference Material

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 -the Mid-Infrared at 278, 298,NIST 800-53Reference Materials There are a variety of

  12. Materials Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment Surfaces andMapping the Nanoscale LandscapeImports 5.90 4.86(NHMFL)X-RayMaterials

  13. Photovoltaic Materials

    SciTech Connect (OSTI)

    Duty, C.; Angelini, J.; Armstrong, B.; Bennett, C.; Evans, B.; Jellison, G. E.; Joshi, P.; List, F.; Paranthaman, P.; Parish, C.; Wereszczak, A.

    2012-10-15T23:59:59.000Z

    The goal of the current project was to help make the US solar industry a world leader in the manufacture of thin film photovoltaics. The overall approach was to leverage ORNL’s unique characterization and processing technologies to gain a better understanding of the fundamental challenges for solar cell processing and apply that knowledge to targeted projects with industry members. ORNL has the capabilities in place and the expertise required to understand how basic material properties including defects, impurities, and grain boundaries affect the solar cell performance. ORNL also has unique processing capabilities to optimize the manufacturing process for fabrication of high efficiency and low cost solar cells. ORNL recently established the Center for Advanced Thin-film Systems (CATS), which contains a suite of optical and electrical characterization equipment specifically focused on solar cell research. Under this project, ORNL made these facilities available to industrial partners who were interested in pursuing collaborative research toward the improvement of their product or manufacturing process. Four specific projects were pursued with industrial partners: Global Solar Energy is a solar industry leader in full scale production manufacturing highly-efficient Copper Indium Gallium diSelenide (CIGS) thin film solar material, cells and products. ORNL worked with GSE to develop a scalable, non-vacuum, solution technique to deposit amorphous or nanocrystalline conducting barrier layers on untextured stainless steel substrates for fabricating high efficiency flexible CIGS PV. Ferro Corporation’s Electronic, Color and Glass Materials (“ECGM”) business unit is currently the world’s largest supplier of metallic contact materials in the crystalline solar cell marketplace. Ferro’s ECGM business unit has been the world's leading supplier of thick film metal pastes to the crystalline silicon PV industry for more than 30 years, and has had operational cells and modules in the field for 25 years. Under this project, Ferro leveraged world leading analytical capabilities at ORNL to characterize the paste-to-silicon interface microstructure and develop high efficiency next generation contact pastes. Ampulse Corporation is developing a revolutionary crystalline-silicon (c-Si) thin-film solar photovoltaic (PV) technology. Utilizing uniquely-textured substrates and buffer materials from the Oak Ridge National Laboratory (ORNL), and breakthroughs in Hot-Wire Chemical Vapor Deposition (HW-CVD) techniques in epitaxial silicon developed at the National Renewable Energy Laboratory (NREL), Ampulse is creating a solar technology that is tunable in silicon thickness, and hence in efficiency and economics, to meet the specific requirements of multiple solar PV applications. This project focused on the development of a high rate deposition process to deposit Si, Ge, and Si1-xGex films as an alternate to hot-wire CVD. Mossey Creek Solar is a start-up company with great expertise in the solar field. The primary interest is to create and preserve jobs in the solar sector by developing high-yield, low-cost, high-efficiency solar cells using MSC-patented and -proprietary technologies. The specific goal of this project was to produce large grain formation in thin, net-shape-thickness mc-Si wafers processed with high-purity silicon powder and ORNL's plasma arc lamp melting without introducing impurities that compromise absorption coefficient and carrier lifetime. As part of this project, ORNL also added specific pieces of equipment to enhance our ability to provide unique insight for the solar industry. These capabilities include a moisture barrier measurement system, a combined physical vapor deposition and sputtering system dedicated to cadmium-containing deposits, adeep level transient spectroscopy system useful for identifying defects, an integrating sphere photoluminescence system, and a high-speed ink jet printing system. These tools were combined with others to study the effect of defects on the performance of crystalline silicon and

  14. E-Print Network 3.0 - associations substitution models Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of substitution equality. We associate a function from Term... and the association of terms with their set ... Source: Maher, Michael - National ICT Australia (NICTA)....

  15. E-Print Network 3.0 - aromatic nucleophilic substitution Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    aromatic nucleophilic substitution Page: << < 1 2 3 4 5 > >> 1 October CUME Organic Chemistry Summary: , Thomas H. Fisher, and Debbie B. Saebo, A Low-Temperature Internal...

  16. Lignin as Both Fuel and Fusing Binder in Briquetted Anthracite Fines for Foundry Coke Substitute.

    E-Print Network [OSTI]

    Lumadue, Matthew

    2012-01-01T23:59:59.000Z

    ??Lignin that had been extracted from Kraft black liquor was investigated as a fusing binder in briquetted anthracite fines for a foundry coke substitute. Cupola… (more)

  17. Research and Devlopment Associate Center for Nanophase Materials Sciences Division

    E-Print Network [OSTI]

    Pennycook, Steve

    : i) selective conversion of biomass-derived compounds; ii) rechargeable metal-air batteries as next. · Heterogeneous catalysis and electrocatalysis on metals, metal compounds, and nano- materials. · Current focuses

  18. Abstract Presented at Synchrotron Environmental Science II (SES-II)

    E-Print Network [OSTI]

    Brookhaven National Laboratory

    Abstract Presented at Synchrotron Environmental Science II (SES-II) Argonne National Laboratory - 6 such as dioxins and furans, polychlorinated biphenyls (PCBs), and polynuclear aromatic hydrocarbons (PAHs). *Work

  19. Substitutional B in Si: Accurate lattice parameter determination

    SciTech Connect (OSTI)

    Bisognin, G.; De Salvador, D.; Napolitani, E.; Berti, M.; Carnera, A.; Mirabella, S.; Romano, L.; Grimaldi, M. G.; Priolo, F. [MATIS CNR-INFM and Dipartimento di Fisica, Universita di Padova, via Marzolo 8, 35131 Padova (Italy); MATIS CNR-INFM and Dipartimento di Fisica ed Astronomia, Universita di Catania, via S. Sofia 64, 95123 Catania (Italy)

    2007-05-01T23:59:59.000Z

    In this work the lattice deformation induced by substitutional B in Si is carefully determined by using different experimental techniques. The investigated Si{sub 1-x}B{sub x}/Si layers x=(0.0012 divide 0.005) are grown by solid phase epitaxy of B-implanted preamorphized Si and by molecular beam epitaxy. Nuclear reaction analysis both in random and in channeling geometry, secondary ion mass spectrometry and high resolution x-ray diffraction allow to quantify the total amount of B and its lattice location, the B depth profile and the B-doped Si lattice parameter, respectively. The reasons for the large spread present in the data reported so far in literature are discussed. Our results, thanks to the synergy of the earlier techniques, lead to a significantly more accurate strain determination, that is in agreement with very recent ab initio theoretical calculations.

  20. The Raman spectra of seventeen alkyl substituted cyclopentanes and cyclohexanes

    E-Print Network [OSTI]

    Faubion, Billy Don

    1965-01-01T23:59:59.000Z

    Instramentt Cary Remen Spectropbotometer, Model 81 Single Slit: 0-200 cm I; Doable Slit: 150-4000 cm I Serial No. 438, Page 2 Temparatarer 28 C Tube Outside Dhuneterr 7 mm Spectral Slit Width: fhv ? 459 cm-lr 5 0 Excitbtg Liaer 4358. 35 II Observed...

  1. ACADEMIC COURSES SUBSTITUTION COURSES Take ALL of the Following

    E-Print Network [OSTI]

    Dyer, Bill

    Catalog 2008-2010 Montana State University Secondary Teacher Education Preparation Program GID: Name: Date Mechanics 4 PHYS 317 Electricity & Magnetism I 3 PHYS 361 Laboratory Electronics II 2 Take one (1-School Experience 1 EDCI 209 Ed Psych & Adolescent Dev 3 EDCI 240 Multicultural Education 3 EDCI 320 Foundations

  2. Finding a suitable platinum substitute for fuel cells | Argonne...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to platinum. These new catalysts offer the promise of substantially reducing the fuel cell cost. The new approach developed by Liu and his team uses materials known as...

  3. Taming the Plasma-Material Interface

    E-Print Network [OSTI]

    Demo R&D: Taming the Plasma- Material Interface Rob Goldston #12;Outline · PMI-Based Mission Risks) · National High-Power Advanced Torus Experiment (NHTX) version of PMIF #12;PMI Mission Risks - I 1 facing surface. #12;PMI Mission Risks - II 5. Steady heat and particle loads result in unacceptable power

  4. Department of Materials MS Part II Course Handbook 201011

    E-Print Network [OSTI]

    Paxton, Anthony T.

    silicon imaging devices AIK / GM Helen DUGDALE MAN Understanding crack growth in nuclear reactors SL ............................................................................................................. 22 Lab Books

  5. Managing Category I and II Asbestos-Containing Materials During

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department of Energy Low-TemperatureEnergy Maine09 BalanceStorage and

  6. Input Substitution and Business Energy Consumption: Evidence from ABS Energy Survey Data

    E-Print Network [OSTI]

    1 Input Substitution and Business Energy Consumption: Evidence from ABS Energy Survey Data Kay Cao applies the system of equations approach to energy consumption modelling using the ABS 2008-09 Energy of equations, energy consumption modelling, elasticity of substitution JEL codes: C51, D24 * Please do

  7. ENDOR study of Cr3 centers substituting for lithium in lithium niobate

    E-Print Network [OSTI]

    Malovichko, Galina

    ENDOR study of Cr3ż centers substituting for lithium in lithium niobate G. Malovichko,1, * V centers in lithium niobate crystals were investigated with the help of electron nuclear double resonance and the parameters of hyperfine and quadrupole interactions were determined. It is found that Cr3 substitutes for Li

  8. Li ion migration in Li3PO4 electrolytes: Effects of O vacancies and N substitutions

    E-Print Network [OSTI]

    Holzwarth, Natalie

    Li ion migration in Li3PO4 electrolytes: Effects of O vacancies and N substitutions Y. A. Dua and N structures of isolated defects associated with extrinsic Li ion vacancies and interstitials. In particular the combination of an O vacancy and a N substitution, stabilizing a Li ion vacancy. We also studied the effects

  9. MATERIALS MANAGEMENT MATERIALS MANAGEMENT -INVENTORY CONTROL

    E-Print Network [OSTI]

    Oliver, Douglas L.

    MATERIALS MANAGEMENT MATERIALS MANAGEMENT - INVENTORY CONTROL Record of Property Transferred from ______ ___________________________________ 2. DEAN (If Applies) ______ ___________________________________ 5. UNIVERSITY DIRECTOR OF MATERIALS MANAGEMENT ______ ___________________________________ 3. HOSPITAL DIRECTOR (If Applies) ______ IF YOU NEED

  10. Nuclear Concrete Materials Database Phase I Development

    SciTech Connect (OSTI)

    Ren, Weiju [ORNL; Naus, Dan J [ORNL

    2012-05-01T23:59:59.000Z

    The FY 2011 accomplishments in Phase I development of the Nuclear Concrete Materials Database to support the Light Water Reactor Sustainability Program are summarized. The database has been developed using the ORNL materials database infrastructure established for the Gen IV Materials Handbook to achieve cost reduction and development efficiency. In this Phase I development, the database has been successfully designed and constructed to manage documents in the Portable Document Format generated from the Structural Materials Handbook that contains nuclear concrete materials data and related information. The completion of the Phase I database has established a solid foundation for Phase II development, in which a digital database will be designed and constructed to manage nuclear concrete materials data in various digitized formats to facilitate electronic and mathematical processing for analysis, modeling, and design applications.

  11. Effect of Mo substitution by W on impact property of heat affected zone in duplex stainless steels

    SciTech Connect (OSTI)

    Huh, M.J.; Kim, S.B.; Paik, K.W.; Kim, Y.G. [Korea Advanced Inst. of Science and Technology, Taejon (Korea, Republic of). Dept. of Materials Science and Engineering] [Korea Advanced Inst. of Science and Technology, Taejon (Korea, Republic of). Dept. of Materials Science and Engineering

    1997-04-01T23:59:59.000Z

    The duplex stainless steels are characterized by two phase structures composed of a mixture of austenite and ferrite phases. They offer high toughness, good weldability, satisfactory corrosion protection, excellent stress corrosion cracking resistance and high strength. Because of these characteristics, these steels have been widely used in various applications such as oil, gas, and chemical industries. Duplex stainless steels generally have suffered embrittlement when exposed at elevated temperature, i.e. above 300 C. To avoid this embrittlement, conventional duplex stainless steels are subject to solution treatment followed by water quenching in the final stage of production or fabrication, which limits the size of products. Kim et al. have recently reported that embrittlement can be greatly reduced by the partial or full replacement of Mo by W in 22Cr-base duplex stainless steels. For the processing of duplex stainless steel, fusion welding is a major fabrication method for corrosion resistant applications. Therefore the welding behavior of these materials has to be fully defined. The purpose of this study is to investigate the effect of Mo substitution by W on the impact property of simulated heat affected zones in 22Cr duplex stainless steels. Structural transformation associated with Mo substitution by W in HAZ has been also investigated on W-containing alloys and conventional 3% Mo duplex stainless steel.

  12. Gas storage materials, including hydrogen storage materials

    DOE Patents [OSTI]

    Mohtadi, Rana F; Wicks, George G; Heung, Leung K; Nakamura, Kenji

    2014-11-25T23:59:59.000Z

    A material for the storage and release of gases comprises a plurality of hollow elements, each hollow element comprising a porous wall enclosing an interior cavity, the interior cavity including structures of a solid-state storage material. In particular examples, the storage material is a hydrogen storage material, such as a solid state hydride. An improved method for forming such materials includes the solution diffusion of a storage material solution through a porous wall of a hollow element into an interior cavity.

  13. Gas storage materials, including hydrogen storage materials

    DOE Patents [OSTI]

    Mohtadi, Rana F; Wicks, George G; Heung, Leung K; Nakamura, Kenji

    2013-02-19T23:59:59.000Z

    A material for the storage and release of gases comprises a plurality of hollow elements, each hollow element comprising a porous wall enclosing an interior cavity, the interior cavity including structures of a solid-state storage material. In particular examples, the storage material is a hydrogen storage material such as a solid state hydride. An improved method for forming such materials includes the solution diffusion of a storage material solution through a porous wall of a hollow element into an interior cavity.

  14. Jan Hendrik Bruinier II Anna von Pippich Fabrizio Andreatta -Milan, Italy II Massimo Bertolini -Essen, Germany II Siegfried Bcherer -

    E-Print Network [OSTI]

    Haller-Dintelmann, Robert

    Massimo Bertolini - Essen, Germany II Siegfried Böcherer - Mannheim, Germany II Thanasis Bouganis - Durham II Jay Jorgenson - New York, USA II Winfried Kohnen - Heidelberg, Germany II Jürg Kramer - Berlin, Germany II Siddarth Sankaran - Bonn, Germany II Maryna Viazovska - Bonn, Germany II Tonghai Yang - Madison

  15. Functional Materials for Energy | Advanced Materials | ORNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Storage Fuel Cells Thermoelectrics Separations Materials Catalysis Sensor Materials Polymers and Composites Carbon Fiber Related Research Chemistry and Physics at...

  16. PARS II Training Workbook (Course 103) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PARS II Training Workbook (Course 103) PARS II Training Workbook (Course 103) PARS II More Documents & Publications PARS II TRAINING PARS II TRAINING PARS II 104 Contractor Monthly...

  17. Guidelines for identifying suspect/counterfeit material

    SciTech Connect (OSTI)

    NONE

    1995-09-01T23:59:59.000Z

    These guidelines are intended to assist users of products in identifying: substandard, misrepresented, or fraudulently marked items. The guidelines provide information about such topics as: precautions, inspection and testing, dispositioning identified items, installed inspection and reporting suspect/counterfeit materials. These guidelines apply to users who are developing procurement documents, product acceptance/verification methods, company procedures, work instructions, etc. The intent of these SM guidelines in relation to the Quality Assurance Program Description (QAPD) and implementing company Management Control Procedures is not to substitute or replace existing requirements, as defined in either the QAPD or company implementing instructions (Management Control Procedures). Instead, the guidelines are intended to provide a consolidated source of information addressing the issue of Suspect/Counterfeit materials. These guidelines provide an extensive suspect component listing and suspect indications listing. Users can quickly check their suspect items against the list of manufacturers products (i.e., type, LD. number, and nameplate information) by consulting either of these listings.

  18. Materials Project: A Materials Genome Approach

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Ceder, Gerbrand (MIT); Persson, Kristin (LBNL)

    Technological innovation - faster computers, more efficient solar cells, more compact energy storage - is often enabled by materials advances. Yet, it takes an average of 18 years to move new materials discoveries from lab to market. This is largely because materials designers operate with very little information and must painstakingly tweak new materials in the lab. Computational materials science is now powerful enough that it can predict many properties of materials before those materials are ever synthesized in the lab. By scaling materials computations over supercomputing clusters, this project has computed some properties of over 80,000 materials and screened 25,000 of these for Li-ion batteries. The computations predicted several new battery materials which were made and tested in the lab and are now being patented. By computing properties of all known materials, the Materials Project aims to remove guesswork from materials design in a variety of applications. Experimental research can be targeted to the most promising compounds from computational data sets. Researchers will be able to data-mine scientific trends in materials properties. By providing materials researchers with the information they need to design better, the Materials Project aims to accelerate innovation in materials research.[copied from http://materialsproject.org/about] You will be asked to register to be granted free, full access.

  19. MATERIALS MANAGEMENT MATERIALS MANAGEMENT -INVENTORY CONTROL

    E-Print Network [OSTI]

    Oliver, Douglas L.

    MATERIALS MANAGEMENT MATERIALS MANAGEMENT - INVENTORY CONTROL NOTICE OF DESIGNATED DEPARTMENTAL OF MATERIALS MANAGEMENT ______ FURTHER INSTRUCTIONS 1. Include a copy of any relevant documents. 2. Item MATERIALS COORDINATOR ­ IC-8 Mail, Fax or PDF the entire package to: MC 2010 Fax: 679-4240 REFERENCE # DMC

  20. Ambi-site substitution of Mn in lanthanum germanate apatites

    SciTech Connect (OSTI)

    Kendrick, E. [Chemical Sciences, University of Surrey, Guildford, Surrey GU2 7XH (United Kingdom); Knight, K.S. [ISIS Facility, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot OX11 0QX (United Kingdom); Slater, P.R., E-mail: p.r.slater@bham.ac.uk [School of Chemistry, University of Birmingham, Edgbaston, Birmingham B15 2TT (United Kingdom)

    2009-08-05T23:59:59.000Z

    A neutron diffraction study at 4 K of the Mn doped lanthanum germanate apatite-type oxide ion conductor of nominal starting composition 'La{sub 9.5}Mn{sub 0.5}(GeO{sub 4}){sub 6}O{sub 2.75}' is reported. The structure was refined in space group P6{sub 3}/m, although high thermal displacement parameters were observed for the oxide ion sites (particularly O3, and O4). Reduced thermal displacement parameters were obtained by splitting the O3 site, and allowing the O4 oxygen to move off site, which may indicate local regions of lower symmetry within the structure. In addition, the data suggested ambi-site substitution of Mn, with it being present on both the Ge site and the La site. Assuming no change in La:Mn:Ge ratio, a composition of La{sub 9.18}Mn{sub 0.28}(GeO{sub 4}){sub 5.8}(MnO{sub 4}){sub 0.2}O{sub 2} was determined. As such there are nominally no interstitial oxide ions, but rather cation vacancies on the La site. Therefore, the high conductivity for this sample is most likely related to the introduction of Frenkel-type defects at higher temperature, as previously proposed for other apatite-type systems containing vacancies on the La site.

  1. Computer Graphics II CSC6870 Computer Graphics II CSC6870 Computer Graphics II

    E-Print Network [OSTI]

    Hua, Jing

    1 Computer Graphics II CSC6870 Computer Graphics II CSC6870 Computer Graphics II Course Information://www.cs.wayne.edu/~jinghua/6870/csc6870.htm) CSC6870 Computer Graphics II Textbooks · REQUIRED TEXTBOOK: Interactive Computer Graphics: A Top-Down Approach with Shader-Based OpenGL (6th Edition) Edward Angel, Dave Shreiner ISBN-10

  2. Method for forming materials

    DOE Patents [OSTI]

    Tolle, Charles R. (Idaho Falls, ID); Clark, Denis E. (Idaho Falls, ID); Smartt, Herschel B. (Idaho Falls, ID); Miller, Karen S. (Idaho Falls, ID)

    2009-10-06T23:59:59.000Z

    A material-forming tool and a method for forming a material are described including a shank portion; a shoulder portion that releasably engages the shank portion; a pin that releasably engages the shoulder portion, wherein the pin defines a passageway; and a source of a material coupled in material flowing relation relative to the pin and wherein the material-forming tool is utilized in methodology that includes providing a first material; providing a second material, and placing the second material into contact with the first material; and locally plastically deforming the first material with the material-forming tool so as mix the first material and second material together to form a resulting material having characteristics different from the respective first and second materials.

  3. Synthesis and evaluation of optical and electrochemical properties of a new conjugated polymer containing substituted thiophene and non-conjugation linkers

    SciTech Connect (OSTI)

    R, Prashanth Kumar K, E-mail: udayaravi80@gmail.com; D, Udayakumar, E-mail: udayaravi80@gmail.com [Department of Chemistry, National Institute of Technology Karnataka, Surathkal, D.K 575 025 (India); K, Siji Narendran N; K, Chandrasekharan [Department of Physics, National Institute of Technology Calicut, Kerala, 673 601 (India)

    2014-10-15T23:59:59.000Z

    Conjugated polymers have been developed in a variety of applied fields owing to their promising optoelectronic properties. These are pursuing considerable interest as opto-electrical material because of their chemical stability and processability. This paper describes the synthesis and study of electro-optical properties of a new donoracceptor polymer composed of substituted thiophene and 4,4?-propane-2,2-diyldiphenol units as electron rich moieties and 1,3,4-oxadiazole unit as electron deficient moiety. The optical properties of the polymer are studied using UV-visible absorption spectroscopy and fluorescent emission spectroscopy. From the electrochemical data, HOMO and LUMO energy levels of the polymer are calculated.

  4. Smog Check II Evaluation Part II: Overview of Vehicle

    E-Print Network [OSTI]

    Denver, University of

    Smog Check II Evaluation Part II: Overview of Vehicle Emissions . . . . . . . . . . . . Prepared in Later Sections ____________________ 1 3. Older Vehicles Have Higher Emissions on Average _____________ 3 4. The Vehicle Fleet Is Dominated by Newer Vehicles______________ 8 5. More Recent Vehicle Models

  5. Feeding Bees Nectar Substitutes Eric C. Mussen, Extension Apiculturist, UC Davis

    E-Print Network [OSTI]

    Ferrara, Katherine W.

    Feeding Bees Nectar Substitutes Eric C. Mussen, Extension Apiculturist, UC Davis Nectar for their energy source. Nectar normally contains a low to moderate concentration of sugar, and honeybees dehydrate

  6. Short-run interfuel substitution in West European power generation : a restriced cost function approach

    E-Print Network [OSTI]

    Söderholm, Patrik

    1999-01-01T23:59:59.000Z

    This paper analyzes short-run interfuel substitution between fossil fuels in West European power generation. The problem is studied within a restricted translog cost model, which is estimated by pooling time-series data ...

  7. Policy 2003-2 Implementation of CRS 37-92-308 Regarding Substitute...

    Open Energy Info (EERE)

    03-2 Implementation of CRS 37-92-308 Regarding Substitute Water Supply Plans Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- OtherOther: Policy...

  8. Benzannulation via the Reaction of Ynamides and Vinylketenes. Application to the Synthesis of Highly Substituted Indoles

    E-Print Network [OSTI]

    Lam, Tin Yiu

    A two-stage “tandem strategy” for the synthesis of indoles with a high level of substitution on the six-membered ring is described. Benzannulation based on the reaction of cyclobutenones with ynamides proceeds via a cascade ...

  9. Methods and intermediates for the synthesis of dipyrrin-substituted porphyrinic macrocycles

    DOE Patents [OSTI]

    Yu, Lianhe; Muthukumaran, Kannan; Sreedharan, Prathapan; Lindsey, Jonathan S.

    2010-05-25T23:59:59.000Z

    The present invention provides dipyrrin substituted porphyrinic macrocycles, intermediates useful for making the same, and methods of making the same. Such compounds may be used for purposes including the making of molecular memory devices, solar cells and light harvesting arrays.

  10. Methods and intermediates for the synthesis of dipyrrin-substituted porphyrinic macrocycles

    DOE Patents [OSTI]

    Yu, Lianhe (Raleigh, NC); Muthukumaran, Kannan (Raleigh, NC); Sreedharan, Prathapan (Kerata, IN); Lindsey, Jonathan S. (Raleigh, NC)

    2011-05-24T23:59:59.000Z

    The present invention provides dipyrrin substituted porphyrinic macrocycles, intermediates useful for making the same, and methods of making the same. Such compounds may be used for purposes including the making of molecular memory devices, solar cells and light harvesting arrays.

  11. Methods and intermediates for the synthesis of dipyrrin-substituted porphyrinic macrocycles

    DOE Patents [OSTI]

    Yu, Lianhe (Raleigh, NC); Muthukumaran, Kannan (Raleigh, NC); Sreedharan, Prathapan (Kerala, IN); Lindsey, Jonathan S. (Raleigh, NC)

    2008-02-19T23:59:59.000Z

    The present invention provides dipyrrin substituted porphyrinic macrocycles, intermediates useful for making the same, and methods of making the same. Such compounds may be used for purposes including the making of molecular memory devices, solar cells and light harvesting arrays.

  12. Methods and intermediates for the synthesis of dipyrrin-substituted porphyrinic macrocycles

    DOE Patents [OSTI]

    Yu, Lianhe (Raleigh, NC); Muthukumaran, Kannan (Raleigh, NC); Sreedharan, Prathapan (Kerala, IN); Lindsey, Jonathan S. (Raleigh, NC)

    2012-03-06T23:59:59.000Z

    The present invention provides dipyrrin substituted porphyrinic macrocycles, intermediates useful for making the same, and methods of making the same. Such compounds may be used for purposes including the making of molecular memory devices, solar cells and light harvesting arrays.

  13. Ring-opening metathesis polymerization of 3-substituted cyclooctenes initiated by group 6 alkylidene complexes

    E-Print Network [OSTI]

    Kozera, Daniel James

    2012-01-01T23:59:59.000Z

    The highly cis,head-to-tail (cis,HT) selective ring-opening metathesis polymerization of 3-substituted cyclooctenes (3-RCOE; R = methyl, hexyl, phenyl) initiated by high oxidation state M and W alkylidene complexes is ...

  14. Volunteering for market-based environmental regulation : the substitution provision of the SO? emissions trading program

    E-Print Network [OSTI]

    Montero, Juan Pablo

    In this paper we explore the practical and welfare implications of a system of voluntary compliance within a market-based environmental regulation. The Substitution Provision of the SO2 emissions trading program allows the ...

  15. *can substitute CSE 131 & ESE 101 or equivalent Updated September 2014 Mechanical Engineering Sample Curriculum

    E-Print Network [OSTI]

    Subramanian, Venkat

    Dynamics and Vibration MEMS 4310 3 Vibration and Machine Elements Lab MEMS 405 2 Intro to Circuits ESE 230*can substitute CSE 131 & ESE 101 or equivalent Updated September 2014 Mechanical Engineering

  16. *can substitute CSE 131 & ESE 101 or equivalent Updated May 2014 Mechanical Engineering Sample Curriculum

    E-Print Network [OSTI]

    Subramanian, Venkat

    Modeling Simulation and Control MEMS 4301 3 Structural Dynamics and Vibration MEMS 431 4 Intro to Circuits*can substitute CSE 131 & ESE 101 or equivalent Updated May 2014 Mechanical Engineering Sample

  17. FAKULTT II MATHEMATIK UND

    E-Print Network [OSTI]

    Nabben, Reinhard

    OF A NETWORK CREATION GAME WITH EXPONENTIAL PAYOFF by NADINE BAUMANN SEBASTIAN STILLER No. 2007/19 #12;The Price of Anarchy of a Network Creation Game with Exponential Payoff Nadine Baumann Sebastian Stiller May/5-3. Technische Universität Berlin, Fakultät II, Stra�e des 17. Juni 136, 10623 Berlin, Germany. Email: stiller

  18. Atmospheric Dynamics II Instructor

    E-Print Network [OSTI]

    AT602 Atmospheric Dynamics II 2 credits Instructor: David W. J. Thompson davet: An Introduction to Dynamic Meteorology, 5th Edition, Academic Press (recommended) · Marshall, J., and Plumb, R. A., 2008: Atmosphere, Ocean, and Climate Dynamics: An Introductory Text, Academic Press. · Vallis, G. K

  19. Synthetic route to meso-tetra hydrocarbyl or substituted hydrocarbyl porphyrins and derivatives

    DOE Patents [OSTI]

    Wijesekera, T.P.; Wagner, R.W.

    1993-08-31T23:59:59.000Z

    The hydroxyl group in a pyrrolic compound having in the 2-position thereof a group having the formula R(OH)CH-R is hydrocarbyl or substituted hydrocarbyl, is replaced by a group, for example a p-nitrobenzoate group, having better leaving properties than those of hydroxyl for a subsequent self-condensation and cyclization of the pyrrolic compound to form a meso-hydrocarbyl or meso-substituted hydrocarbyl porphyrin.

  20. In situ synthesis of magnesium-substituted biphasic calcium phosphate and in vitro biodegradation

    SciTech Connect (OSTI)

    Kim, Tae-Wan; Lee, Hyeong-Shin; Kim, Dong-Hyun; Jin, Hyeong-Ho [School of Materials Science and Engineering, Pusan National University, Busan 609-735 (Korea, Republic of)] [School of Materials Science and Engineering, Pusan National University, Busan 609-735 (Korea, Republic of); Hwang, Kyu-Hong [School of Nano and Advanced Materials, Gyeongsang National University, Jinju, Kyungnam 660-701 (Korea, Republic of)] [School of Nano and Advanced Materials, Gyeongsang National University, Jinju, Kyungnam 660-701 (Korea, Republic of); Lee, Jong Kook [Department of Advanced Materials Engineering, Chosun University, Gwangju 501-759 (Korea, Republic of)] [Department of Advanced Materials Engineering, Chosun University, Gwangju 501-759 (Korea, Republic of); Park, Hong-Chae [School of Materials Science and Engineering, Pusan National University, Busan 609-735 (Korea, Republic of)] [School of Materials Science and Engineering, Pusan National University, Busan 609-735 (Korea, Republic of); Yoon, Seog-Young, E-mail: syy3@pusan.ac.kr [School of Materials Science and Engineering, Pusan National University, Busan 609-735 (Korea, Republic of)] [School of Materials Science and Engineering, Pusan National University, Busan 609-735 (Korea, Republic of)

    2012-09-15T23:59:59.000Z

    Highlights: ? Mg–BCP were successfully prepared through in situ aqueous co-precipitation method. ? The amount of ?-TCP phase was changed with the magnesium substitution level. ? The substitution of magnesium led to a decrease in the unit cell volume. ? Mg–BCP could be able to develop a new apatite phase on the surface faster than BCP. -- Abstract: In situ preparation of magnesium (Mg) substituted biphasic calcium phosphate (BCP) of hydroxyapatite (HAp)/?-tricalcium phosphate (?-TCP) were carried out through aqueous co-precipitation method. The concentrations of added magnesium were varied with the calcium in order to obtain constant (Ca + Mg)/P ratios of 1.602. X-ray diffraction (XRD) and Fourier transformed infrared (FTIR) spectroscopy were used to characterize the structure of synthesized magnesium substituted BCP powders. The results have shown that substitution of magnesium in the calcium deficient apatites revealed the formation of biphasic mixtures of different HAp/?-TCP ratios after heating at 1000 °C. The ratios of the formation of phase mixtures were dependent on the content of magnesium. After immersing in Hanks’ balanced salt solution (HBSS) for 1 week, 1 wt% magnesium substituted BCP powders were degraded and precipitation started to be formed with small granules consisting of number of flake-like crystal onto the surface of synthesized powders. On the other hand, in the case of pure BCP powders, the formation of new precipitates was detected after immersion in HBSS for 2 weeks. On the basis of these results, magnesium substituted BCP could be able to develop a new apatite phase on the surface in contact with physiological fluids faster than BCP does. In addition, the retention time to produce the new apatite phase in implantation operation for the BCP powder could be controlled by the amount of magnesium substitution.

  1. Synthetic route to meso-tetra hydrocarbyl or substituted hydrocarbyl porphyrins and derivatives

    DOE Patents [OSTI]

    Wijesekera, Tilak P. (Glen Mills, PA); Wagner, Richard W. (Murrysville, PA)

    1993-01-01T23:59:59.000Z

    The hydroxyl group in a pyrrolic compound having in the 2-position thereof a group having the formula R(OH)CH--R is hydrocarbyl or substituted hydrocarbyl, is replaced by a group, for example a p-nitrobenzoate group, having better leaving properties than those of hydroxyl for a subsequent self-condensation and cyclization of the pyrrolic compound to form a meso-hydrocarbyl or meso-substituted hydrocarbyl porphyrin.

  2. The California State University, Fullerton Emergency Management Plan establishes the framework for campus response to emergency situations. The Hazardous Material

    E-Print Network [OSTI]

    de Lijser, Peter

    1 I. Policy The California State University, Fullerton Emergency Management Plan establishes the framework for campus response to emergency situations. The Hazardous Material Contingency Plan (plan) defines specific actions and information for responding to campus hazardous materials incidents. II

  3. Transporting particulate material

    DOE Patents [OSTI]

    Aldred, Derek Leslie (North Hollywood, CA); Rader, Jeffrey A. (North Hollywood, CA); Saunders, Timothy W. (North Hollywood, CA)

    2011-08-30T23:59:59.000Z

    A material transporting system comprises a material transporting apparatus (100) including a material transporting apparatus hopper structure (200, 202), which comprises at least one rotary transporting apparatus; a stationary hub structure (900) constraining and assisting the at least one rotary transporting apparatus; an outlet duct configuration (700) configured to permit material to exit therefrom and comprising at least one diverging portion (702, 702'); an outlet abutment configuration (800) configured to direct material to the outlet duct configuration; an outlet valve assembly from the material transporting system venting the material transporting system; and a moving wall configuration in the material transporting apparatus capable of assisting the material transporting apparatus in transporting material in the material transporting system. Material can be moved from the material transporting apparatus hopper structure to the outlet duct configuration through the at least one rotary transporting apparatus, the outlet abutment configuration, and the outlet valve assembly.

  4. Methylocystis strain SB2 materials and methods

    DOE Patents [OSTI]

    Semrau, Jeremy D; Gallagher, Warren; Yoon, Sukhwan; Im, Jeongdae; DiSpririto, Alan A; Lee, Sung-Woo; Hartsel, Scott; McEllistrem, Marcus T

    2014-01-14T23:59:59.000Z

    The present disclosures provides isolated or purified compounds, each of which bind to a metal atom. Generally, the compounds are small in size (e.g., molecular weight of less than about 1 kDa) and peptidic in nature, inasmuch as the compounds comprise amino acids. In some embodiments, the compound comprises a structure of Formula I; M.sub.1-P.sub.1-M.sub.2-P.sub.2 wherein each of P.sub.1 and P.sub.2 is a peptide comprising at least two amino acids, M.sub.1 is a first metal binding moiety comprising a substituted imidazolone ring, M.sub.2 is a second metal binding moiety comprising a substituted oxazolone ring, and wherein M.sub.1 and M.sub.2 bind to a single metal atom. Also provided are related complexes, conjugates, cells which synthesize the compounds of the present disclosures, substantially homogenous cultures thereof, kits and compositions, and methods of making or using the materials of the present disclosures.

  5. Search for new manganese-cobalt oxides as positive electrode materials for lithium batteries P. Strobel, J. Tillier, A. Diaz, A. Ibarra-Palos, F. Thiry and J.B. Soupart *

    E-Print Network [OSTI]

    Boyer, Edmond

    positive electrode material for lithium batteries ; last but not least, copper or cobalt substitutionSearch for new manganese-cobalt oxides as positive electrode materials for lithium batteries P new mixed manganese-cobalt oxides for lithium battery positive electrode materials were obtained using

  6. Fluorescence of [Fe II] in H II regions

    E-Print Network [OSTI]

    M. Rodriguez

    1999-06-17T23:59:59.000Z

    A study of [Fe II] lines at various positions within the H II regions M42 and M43 is presented. The relative intensities of selected optical [Fe II] lines are shown to be correlated with the intensity of the apparent nebular continuous spectrum. Since the continuum of H II regions is known to be mostly stellar radiation scattered by dust intermixed with the emitting gas, these correlations provide direct evidence for the existence of fluorescent excitation in the formation process of the [Fe II] lines, irrespective of the prevailing physical state.

  7. CHEN 3AA0 Chemical Engineering Progress Assessment II (Concepts Inventory Exam)

    E-Print Network [OSTI]

    Ashurst, W. Robert

    CHEN 3AA0 Chemical Engineering Progress Assessment II (Concepts Inventory Exam) Instructions to as the Concept Inventory Exam (CIE). The following material discusses the nature of the CIE and the CHEN 3AA0

  8. CH E 2421 Chemical Engineering Thermodynamics I CH E 3322 Chemical Engineering Thermodynamics II

    E-Print Network [OSTI]

    Zhang, Yuanlin

    Physics PHYS 4312 Nuclear and Particle Physics Other Engineering Electives #12;CH E 2421 Chemical Engineering Thermodynamics I CH E 3322 Chemical Engineering Thermodynamics II CH E 3330 Engineering Materials Science CH E 4342 Polymer Physics

  9. Hydrogen, Fuel Cells, and Infrastructure Technologies FY 2002 Progress Report II.D Electrolytic Processes

    E-Print Network [OSTI]

    Hydrogen, Fuel Cells, and Infrastructure Technologies FY 2002 Progress Report 125 II.D Electrolytic Processes II.D.1 Photoelectrochemical Systems for Hydrogen Production Ken Varner, Scott Warren, J.A. Turner of the identified semiconductor materials as required. · Determine if existing photovoltaic (PV) device structures

  10. Nanostructured magnetic materials

    E-Print Network [OSTI]

    Chan, Keith T.

    2011-01-01T23:59:59.000Z

    Magnetism and Magnetic Materials Conference, Atlanta, GA (Nanostructured Magnetic Materials by Keith T. Chan Doctor ofinduced by a Si-based material occurs at a Si/Ni interface

  11. -STABILITY AND VORTEX MOTION IN TYPE II SUPERCONDUCTORS

    E-Print Network [OSTI]

    Spirn, Daniel

    -STABILITY AND VORTEX MOTION IN TYPE II SUPERCONDUCTORS MATTHIAS KURZKE AND DANIEL SPIRN Abstract. 1. Introduction 1.1. Physical background. The evolution of a superconducting material is usu- ally of the magnetic field and the electric field potential for a superconducting sample R2 . The parameter

  12. Multi-Component Copper Catalyzed Methods to Access Highly-Substituted Amine-Bearing Carbon Centers from Simple Starting Materials

    E-Print Network [OSTI]

    Pierce, Conor John

    2013-01-01T23:59:59.000Z

    Modern physical organic chemistry; University Science Books:Modern physical organic chemistry; University Science Books:

  13. Multi-Component Copper Catalyzed Methods to Access Highly-Substituted Amine-Bearing Carbon Centers from Simple Starting Materials

    E-Print Network [OSTI]

    Pierce, Conor John

    2013-01-01T23:59:59.000Z

    2929, 2857, 2808, 1741, 1603, cm -1 . 1 H NMR (400 MHz, CDClcolumn. IR (film) 2929, 2857, 1603, 1507, 1245, 1221, 1036,film) 2927, 2854, 1715, 1603, 1496, 1453, 1121, 907, 733,

  14. MATERIALS TRANSFER AGREEMENT

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MTAXX-XXX 1 MATERIAL TRANSFER AGREEMENT for Manufacturing Demonstration Facility and Carbon Fiber Technology Facility In order for the RECIPIENT to obtain materials, the RECIPIENT...

  15. battery materials | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    battery materials battery materials Leads No leads are available at this time. Modeling Interfacial Glass-Water Reactions: Recent Advances and Current Limitations. Abstract: The...

  16. Energy Materials & Processes | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in catalysts and energy materials needed to design new materials and systems for sustainable energy applications. By facilitating the development and rapid dissemination...

  17. Ribosomal Database Project II

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Ribosomal Database Project (RDP) provides ribosome related data and services to the scientific community, including online data analysis and aligned and annotated Bacterial small-subunit 16S rRNA sequences. As of March 2008, RDP Release 10 is available and currently (August 2009) contains 1,074,075 aligned 16S rRNA sequences. Data that can be downloaded include zipped GenBank and FASTA alignment files, a histogram (in Excel) of the number of RDP sequences spanning each base position, data in the Functional Gene Pipeline Repository, and various user submitted data. The RDP-II website also provides numerous analysis tools.[From the RDP-II home page at http://rdp.cme.msu.edu/index.jsp

  18. PARS II TRAINING | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    TRAINING PARS II TRAINING BASICS TRAINING WORKBOOK PARS II TRAINING More Documents & Publications PARS II PARS II Training Workbook (Course 103) PARSIIUserGuideV1.0Draft.pdf...

  19. Class II virus membrane fusion proteins

    SciTech Connect (OSTI)

    Kielian, Margaret [Department of Cell Biology, Albert Einstein College of Medicine, 1300 Morris Park Ave., Bronx, NY 10461 (United States)]. E-mail: kielian@aecom.yu.edu

    2006-01-05T23:59:59.000Z

    Enveloped animal viruses fuse their membrane with a host cell membrane, thus delivering the virus genetic material into the cytoplasm and initiating infection. This critical membrane fusion reaction is mediated by a virus transmembrane protein known as the fusion protein, which inserts its hydrophobic fusion peptide into the cell membrane and refolds to drive the fusion reaction. This review describes recent advances in our understanding of the structure and function of the class II fusion proteins of the alphaviruses and flaviviruses. Inhibition of the fusion protein refolding reaction confirms its importance in fusion and suggests new antiviral strategies for these medically important viruses.

  20. SRC-II process

    SciTech Connect (OSTI)

    Schmid, B.K.; Jackson, D.M.

    1980-01-01T23:59:59.000Z

    Extensive laboratory and pilot plant experimental work on the Solvent Refined Coal Process has led to the development of an improved version of the process known as SRC-II. This work has shown considerable promise and plans are being made to demonstrate the SRC-II process using commercial size equipment in a 6000 T/D plant to be located near Morgantown, West Virginia. On the basis of recent economic studies, the products (both liquid and gas) from a future large-scale commercial plant are expected to have an overall selling price of $4.00 to 5.00 per million Btu (first quarter 1980 basis). The major product of the primary process is distillate fuel oil of less than 0.3% sulfur for use largely as a non-polluting fuel for generating electrical power and steam, especially in the east where utilities and industry are presently using petroleum products. For the longer term, the major growth opportunity for SRC-II fuel oil in the generation of electric power will probably be through advanced combustion turbine units with heat recovery boilers (combined cycle units). The light liquid fractions (naphtha and middle distillate) produced by the SRC-II process can be upgraded to a high octane unleaded gasoline to supplement petroleum-derived supplies. Significant quantities of pipeline gas are also produced at a cost which should be competitive with SNG from direct coal gasification. Light hydrocarbons (ethane, propane) from the process may be effectively converted to ethylene in conventional cracking plants to offset ethylene demand from petroleum-derived naphtha and gas oil, both of which could otherwise be used for other refinery products. In addition, certain fraction of the fuel oil might also be used in medium speed diesel engines and automotive gas turbines.

  1. Cerium Substitution in Yttrium Iron Garnet: Valence State, Structure, and Energetics

    SciTech Connect (OSTI)

    Guo, Xiaofeng; Tavakoli, Amir H.; Sutton, Steve; Kukkadapu, Ravi K.; Qi, Liang; Lanzirotti, Anthony; Newville, Mathew; Asta, Mark D.; Navrotsky, Alexandra

    2014-01-28T23:59:59.000Z

    The garnet structure is a promising nuclear waste form because it can accommodate various actinide elements. Y3Fe5O12 (YIG) is a model composition for such substitutions. Since cerium (Ce) can be considered an analogue of actinide elements such as thorium (Th), plutonium (Pu), and uranium (U), studying the local structure and thermodynamic stability of Ce-substituted YIG (Ce:YIG) can provide insights into the structural and energetic aspects of large ion substitution in garnets. Single phases of yttrium iron garnet with Ce substitution up to 20 mol % (Y3-xCexFe5O12 with 0 ? x ? 0.2) were synthesized through a citrate-nitrate combustion method. The oxidation state of cerium was examined by X-ray absorption near edge structure spectroscopy (XANES); the oxidation state and site occupancy of Fe as a function of Ce loading also was monitored by 57Fe-Mössbauer spectroscopy. These measurements establish that Ce is predominantly in the trivalent state at low substitution levels, while a mixture of trivalent and tetravalent states are observed at higher concentrations. Fe was predominately trivalent and exists in multiple environments. High temperature oxide melt solution calorimetry was used to determine the enthalpy of formation of these Ce-substituted YIG garnets. The thermodynamic analysis demonstrated that, although there is an entropic driving force for the substitution of Ce for Y, the substitution reaction is enthalpically unfavorable. The experimental results are complemented by electronic structure calculations performed within the framework of density functional theory (DFT) with Hubbard-U corrections, which reproduce the observed increase in the tendency for tetravalent Ce to be present with higher loading of Ce. The DFT+U results suggest that the energetics underlying the formation of tetravalent Ce involves a competition between an unfavorable energy to oxidize Ce and reduce Fe, and a favorable contribution due to strain-energy reduction. The structural and thermodynamic findings suggest a strategy to design thermodynamically-favorable substitutions of actinides in the garnet system.

  2. Coated ceramic breeder materials

    DOE Patents [OSTI]

    Tam, Shiu-Wing (Downers Grove, IL); Johnson, Carl E. (Elk Grove, IL)

    1987-01-01T23:59:59.000Z

    A breeder material for use in a breeder blanket of a nuclear reactor is disclosed. The breeder material comprises a core material of lithium containing ceramic particles which has been coated with a neutron multiplier such as Be or BeO, which coating has a higher thermal conductivity than the core material.

  3. HAZARDOUS MATERIALS EMERGENCY RESPONSE

    E-Print Network [OSTI]

    ANNEX Q HAZARDOUS MATERIALS EMERGENCY RESPONSE #12;ANNEX Q - HAZARDOUS MATERIALS EMERGENCY RESPONSE 03/10/2014 v.2.0 Page Q-1 PROMULGATION STATEMENT Annex Q: Hazardous Materials Emergency Response, and contents within, is a guide to how the University conducts a response specific to a hazardous materials

  4. UNDERGRADUATE Materials Science & Engineering

    E-Print Network [OSTI]

    Tipple, Brett

    UNDERGRADUATE HANDBOOK Materials Science & Engineering 2013 2014 #12;STUDYING FOR A MATERIALS SCIENCE AND ENGINEERING DEGREE Materials Science and Engineering inter-twines numerous disciplines that still gives the students the opportunity to study science while earning an engineering degree. Materials

  5. Materials Science & Engineering

    E-Print Network [OSTI]

    Simons, Jack

    Materials Science & Engineering The University of Utah 2014-15 Undergraduate Handbook #12;STUDYING FOR A MATERIALS SCIENCE AND ENGINEERING DEGREE Materials Science and Engineering inter-twines numerous disciplines that still gives the students the opportunity to study science while earning an engineering degree. Materials

  6. A Materials Facilities Initiative -

    E-Print Network [OSTI]

    A Materials Facilities Initiative - FMITS & MPEX D.L. Hillis and ORNL Team Fusion & Materials for Nuclear Systems Division July 10, 2014 #12;2 Materials Facilities Initiative JET ITER FNSF Fusion Reactor Challenges for materials: fluxes and fluence, temperatures 50 x divertor ion fluxes up to 100 x neutron

  7. Computational Chemical Materials Engineering

    E-Print Network [OSTI]

    : Thermal barrier coatings, wear resistance coatings, radiation resistant materials · Materials for opticalHome Computational Chemical and Materials Engineering Tahir Cagin Chemical Engineering Department to understand behavior and properties of materials as a function of ­ Chemical constitution ­ Composition

  8. WORKING DOCUMENT -DRAFT -September 12th "Nanosciences, Nanotechnologies, Materials and new

    E-Print Network [OSTI]

    Meju, Max

    WORKING DOCUMENT - DRAFT - September 12th 2006 Theme 4 "Nanosciences, Nanotechnologies, Materials ------------------------------------------------------------------------------- Table of contents I. Context 1 II. Content of Calls 5 Nanosciences and Nanotechnologies 7 Materials 15 - September 12th 2006 I Context I.1 Policy context Theme 4 "Nanosciences, Nanotechnologies, Materials and new

  9. Ris-PhD-21(EN) Hydrogen Storage Materials with Focus

    E-Print Network [OSTI]

    Risø-PhD-21(EN) Hydrogen Storage Materials with Focus on Main Group I-II Elements Anders Andreasen Risø National Laboratory Roskilde Denmark October 2005 #12;Hydrogen storage materials with focus National Laboratory Roskilde, 2005 #12;Author: Anders Andreasen Title: Hydrogen Storage Materials

  10. Bachelor of Science, Materials Science and Engineering, 2014-2015 Name ID# Date

    E-Print Network [OSTI]

    Barrash, Warren

    404L Materials Analysis Lab 1 MSE 418 Phase Transformations and Kinetics 3 MSE 480 Senior Project I 3 FF MSE 482 Senior Project II 3 MSE 498 Materials Science Seminar 1 PHYS 212, 212L Physics IIBachelor of Science, Materials Science and Engineering, 2014-2015 Name ID# Date General Degree

  11. MATERIALS RESEARCH DEPARTMENT 2000 A n n u a l R e p o r t 2 0 0 0

    E-Print Network [OSTI]

    8 MATERIALS RESEARCH DEPARTMENT 2000 A n n u a l R e p o r t 2 0 0 0 Materials Science - Theory and characterisation This section covers the research activities within three programmes: (i) Modelling of Materials and Structures of Materials, (ii) Local Structure and Properties and (iii) Irradiation Damage, Defects and Fusion

  12. CRAD, Packaging and Transfer of Hazardous Materials and Materials...

    Office of Environmental Management (EM)

    CRAD, Packaging and Transfer of Hazardous Materials and Materials of National Security Interest Assessment Plan CRAD, Packaging and Transfer of Hazardous Materials and Materials of...

  13. Supporting Online Material Materials and Methods

    E-Print Network [OSTI]

    Wolfe, Cecily J.

    1 Supporting Online Material Materials and Methods (15) For all possible earthquake pairs. The parameters chosen for window length, filter bandpass, negative sidelobe identification, and cross-correlation threshold are appropriate for high-frequency earthquakes. In order to remove false positives or poor data

  14. SUPPORTING ONLINE MATERIAL Materials and Methods

    E-Print Network [OSTI]

    Newsome, William

    SUPPORTING ONLINE MATERIAL Materials and Methods Two adult male rhesus monkeys (Macaca mulatta with a head-holding device (S1), scleral search coil for monitoring eye position (S2) and a recording chamber monkeys remain actively engaged in experiments, so precise histological identification of recording sites

  15. Puncture detecting barrier materials

    DOE Patents [OSTI]

    Hermes, R.E.; Ramsey, D.R.; Stampfer, J.F.; Macdonald, J.M.

    1998-03-31T23:59:59.000Z

    A method and apparatus for continuous real-time monitoring of the integrity of protective barrier materials, particularly protective barriers against toxic, radioactive and biologically hazardous materials has been developed. Conductivity, resistivity or capacitance between conductive layers in the multilayer protective materials is measured by using leads connected to electrically conductive layers in the protective barrier material. The measured conductivity, resistivity or capacitance significantly changes upon a physical breach of the protective barrier material. 4 figs.

  16. Safety analysis report for the TRUPACT-II shipping package (condensed version). Volume 1, Rev. 14

    SciTech Connect (OSTI)

    NONE

    1994-10-01T23:59:59.000Z

    The condensed version of the TRUPACT-II Contact Handled Transuranic Waste Safety Analysis Report for Packaging (SARP) contains essential material required by TRUPACT-II users, plus additional contents (payload) information previously submitted to the U.S. Nuclear Regulatory Commission. All or part of the following sections, which are not required by users of the TRUPACT-II, are deleted from the condensed version: (i) structural analysis, (ii) thermal analysis, (iii) containment analysis, (iv) criticality analysis, (v) shielding analysis, and (vi) hypothetical accident test results.

  17. ARM - RHUBC II Instruments

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc Documentation RUC :ProductsSCM Forcing Data DerivedInstruments Related Links RHUBC-II Home RHUBC

  18. PART II - CONTRACT CLAUSES

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 - September 2006 The 2002OpticsPeriodical: Volume 5, Issue 32012) |GContract115I,I

  19. Evaluation of the computerized procedures Manual II (COPMA II)

    SciTech Connect (OSTI)

    Converse, S.A. [North Carolina State Univ., Raleigh, NC (United States)

    1995-11-01T23:59:59.000Z

    The purpose of this study was to evaluate the effects of a computerized procedure system, the Computerized Procedure Manual II (COPMA-II), on the performance and mental workload of licensed reactor operators. To evaluate COPMA-II, eight teams of two operators were trained to operate a scaled pressurized water reactor facility (SPWRF) with traditional paper procedures and with COPMA-II. Following training, each team operated the SPWRF under normal operating conditions with both paper procedures and COPMA-II. The teams then performed one of two accident scenarios with paper procedures, but performed the remaining accident scenario with COPMA-II. Performance measures and subjective estimates of mental workload were recorded for each performance trial. The most important finding of the study was that the operators committed only half as many errors during the accident scenarios with COPMA-II as they committed with paper procedures. However, time to initiate a procedure was fastest for paper procedures for accident scenario trials. For performance under normal operating conditions, there was no difference in time to initiate or to complete a procedure, or in the number of errors committed with paper procedures and with COPMA-II. There were no consistent differences in the mental workload ratings operators recorded for trials with paper procedures and COPMA-II.

  20. System for characterizing semiconductor materials and photovoltaic devices through calibration

    DOE Patents [OSTI]

    Sopori, B.L.; Allen, L.C.; Marshall, C.; Murphy, R.C.; Marshall, T.

    1998-05-26T23:59:59.000Z

    A method and apparatus are disclosed for measuring characteristics of a piece of material, typically semiconductor materials including photovoltaic devices. The characteristics may include dislocation defect density, grain boundaries, reflectance, external LBIC, internal LBIC, and minority carrier diffusion length. The apparatus includes a light source, an integrating sphere, and a detector communicating with a computer. The measurement or calculation of the characteristics is calibrated to provide accurate, absolute values. The calibration is performed by substituting a standard sample for the piece of material, the sample having a known quantity of one or more of the relevant characteristics. The quantity measured by the system of the relevant characteristic is compared to the known quantity and a calibration constant is created thereby. 44 figs.

  1. System for characterizing semiconductor materials and photovoltaic devices through calibration

    DOE Patents [OSTI]

    Sopori, Bhushan L. (Denver, CO); Allen, Larry C. (Arvada, CO); Marshall, Craig (Littleton, CO); Murphy, Robert C. (Golden, CO); Marshall, Todd (Littleton, CO)

    1998-01-01T23:59:59.000Z

    A method and apparatus for measuring characteristics of a piece of material, typically semiconductor materials including photovoltaic devices. The characteristics may include dislocation defect density, grain boundaries, reflectance, external LBIC, internal LBIC, and minority carrier diffusion length. The apparatus includes a light source, an integrating sphere, and a detector communicating with a computer. The measurement or calculation of the characteristics is calibrated to provide accurate, absolute values. The calibration is performed by substituting a standard sample for the piece of material, the sample having a known quantity of one or more of the relevant characteristics. The quantity measured by the system of the relevant characteristic is compared to the known quantity and a calibration constant is created thereby.

  2. Joining of dissimilar materials

    DOE Patents [OSTI]

    Tucker, Michael C; Lau, Grace Y; Jacobson, Craig P

    2012-10-16T23:59:59.000Z

    A method of joining dissimilar materials having different ductility, involves two principal steps: Decoration of the more ductile material's surface with particles of a less ductile material to produce a composite; and, sinter-bonding the composite produced to a joining member of a less ductile material. The joining method is suitable for joining dissimilar materials that are chemically inert towards each other (e.g., metal and ceramic), while resulting in a strong bond with a sharp interface between the two materials. The joining materials may differ greatly in form or particle size. The method is applicable to various types of materials including ceramic, metal, glass, glass-ceramic, polymer, cermet, semiconductor, etc., and the materials can be in various geometrical forms, such as powders, fibers, or bulk bodies (foil, wire, plate, etc.). Composites and devices with a decorated/sintered interface are also provided.

  3. PROGRAMA FISICA II. INTRODUCCI O

    E-Print Network [OSTI]

    Batiste, Oriol

    PROGRAMA F´ISICA II. INTRODUCCI ´O I ELECTRICITAT I.1 Camp electrost`atic I.2 Potencial i energia I.4 `Optica #12;BIBLIOGRAFIA B`asica 1. Tipler, P.A. F´isica. Vol. II, ed. Revert´e, 1992. 2. Purcell Blum, R. F´isica: Electricidad, Mag- netismo y Luz. Vol. II, ed. Revert´e, 1986. Complement`aria 1

  4. Cation-substituted spinel oxide and oxyfluoride cathodes for lithium ion batteries

    DOE Patents [OSTI]

    Manthiram, Arumugam; Choi, Wongchang

    2014-05-13T23:59:59.000Z

    The present invention includes compositions and methods of making cation-substituted and fluorine-substituted spinel cathode compositions by firing a LiMn.sub.2-y-zLi.sub.yM.sub.zO.sub.4 oxide with NH.sub.4HF.sub.2 at low temperatures of between about 300 and 700.degree. C. for 2 to 8 hours and a .eta. of more than 0 and less than about 0.50, mixed two-phase compositions consisting of a spinel cathode and a layered oxide cathode, and coupling them with unmodified or surface modified graphite anodes in lithium ion cells.

  5. Quantifying exchange coupling in f-ion pairs using the diamagnetic substitution method

    SciTech Connect (OSTI)

    Lukens, Wayne W.; Walter, Marc D.

    2010-04-01T23:59:59.000Z

    One of the challenges in the chemistry of actinide and lanthanide (f-ion) is quantifying exchange coupling between f-ions. While qualitative information about exchange coupling may be readily obtained using the diamagnetic substitution approach, obtaining quantitative information is much more difficult. This article describes how exchange coupling may be quantified using the susceptibility of a magnetically isolated analog, as in the diamagnetic substitution approach, along with the anisotropy of the ground state as determined by EPR spectroscopy. Several examples are used to illustrate and test this approach.

  6. Materials for breeding blankets

    SciTech Connect (OSTI)

    Mattas, R.F.; Billone, M.C.

    1995-09-01T23:59:59.000Z

    There are several candidate concepts for tritium breeding blankets that make use of a number of special materials. These materials can be classified as Primary Blanket Materials, which have the greatest influence in determining the overall design and performance, and Secondary Blanket Materials, which have key functions in the operation of the blanket but are less important in establishing the overall design and performance. The issues associated with the blanket materials are specified and several examples of materials performance are given. Critical data needs are identified.

  7. Correlation between structural, magnetic, and dielectric properties of manganese substituted cobalt ferrite

    SciTech Connect (OSTI)

    Ramana, C. V., E-mail: rvchintalapalle@utep.edu; Kolekar, Y. D.; Kamala Bharathi, K. [Department of Mechanical Engineering, University of Texas at El Paso, El Paso, Texas 79968 (United States); Sinha, B. [Functional Nanopowder Material Division, Korea Institute of Material Science, Changwon 642-831, Gyeongnam (Korea, Republic of); Ghosh, K. [Department of Physics, Astronomy and Materials Science, Missouri State University, Springfield, Missouri 65897 (United States)

    2013-11-14T23:59:59.000Z

    Manganese (Mn) substituted cobalt ferrites (CoFe{sub 2?x}Mn{sub x}O{sub 4}, referred to CFMO) were synthesized and their structural, magnetic, and dielectric properties were evaluated. X-ray diffraction measurements coupled with Rietveld refinement indicate that the CFMO materials crystallize in the inverse cubic spinel phase. Temperature (T?=?300?K and 10?K) dependent magnetization (M(H)) measurements indicate the long range ferromagnetic ordering in CoFe{sub 2?x}Mn{sub x}O{sub 4} (x?=?0.00–0.15) ferrites. The cubic anisotropy constant (K{sub 1}(T)) and saturation magnetization (M{sub s}(T)) were derived by using the “law of approach” to saturation that describes the field dependence of M(H) for magnetic fields much higher than the coercive field (H{sub c}). Saturation magnetization (M{sub s}), obtained from the model, decreases with increasing temperature. For CoFe{sub 2}O{sub 4}, M{sub s} decreases from 3.63??{sub B} per formula unit (f.u.) to 3.47??{sub B}/f.u. with increasing temperature from 10 to 300?K. CFMO (0.00–0.15) exhibit the similar trend while the magnitude of M{sub s} is dependent on Mn-concentration. M{sub s}-T functional relationship obeys the Bloch's law. The lattice parameter and magnetic moment calculated for CFMO reveals that Mn ions occupying the Fe and Co position at the octahedral site in the inverse cubic spinel phase. The structure and magnetism in CFMO are further corroborated by bond length and bond angle calculations. The dielectric constant dispersion of CFMO in the frequency range of 20?Hz–1?MHz fits to the modified Debye's function with more than one ion contributing to the relaxation. The relaxation time and spread factor derived from modeling the experimental data are ?10{sup ?4}?s and ?0.35(±0.05), respectively.

  8. Supernovae. Part II: The aftermath

    E-Print Network [OSTI]

    Trimble, V

    1983-01-01T23:59:59.000Z

    R. Viswanathan, 1980, As- Supernovae. Part II ExperimentalSmith, 1982, Astrophys. Supernovae. Chevalier, R. A. , andC. B. , 1974, Ed. , Supernovae and Supernova Rem- nants,

  9. Magnetic properties of materials for MR engineering, micro-MR and beyond

    E-Print Network [OSTI]

    Wapler, Matthias C; Dragonu, Iulius; von Elverfeld, Dominik; Zaitsev, Maxim; Wallrabe, Ulrike

    2014-01-01T23:59:59.000Z

    We present the results of a systematic measurement of the magnetic susceptibility of small material samples in a 9.4 T MRI scanner. We measured many of the most widely used materials in MR engineering and MR micro technology, including various polymers, optical and substrate glasses, resins, glues, photoresists, PCB substrates and some fluids. Based on our data, we identify particularly suitable materials with susceptibilities close to water. For polyurethane resins and elastomers, we also show the MR spectra, as they may be a good substitute for silicone elastomers and good casting resins.

  10. BOAST II for the IBM 3090 and RISC 6000

    SciTech Connect (OSTI)

    Hebert, P.; Bourgoyne, A.T. Jr.; Tyler, J.

    1993-05-01T23:59:59.000Z

    BOAST II simulates isothermal, darcy flow in three dimensions. It assumes that reservoir liquids can be described in three fluid phases (oil, gas, and water) of constant composition, with physical properties that depend on pressure, only. These reservoir fluid approximations are acceptable for a large percentage of the world's oil and gas reservoirs. Consequently, BOAST II has a wide range of applicability. BOAST II can simulate oil and/or gas recovery by fluid expansion, displacement, gravity drainage, and capillary imbibition mechanisms. Typical field production problems that BOAST II can handle include primary depletion studies, pressure maintenance by water and/or gas injection, and evaluation of secondary recovery waterflooding and displacement operations. Technically, BOAST II is a finite, implicit pressure, explicit saturation (IMPES) numerical simulator. It applies both direct and iterative solution techniques for solving systems of algebraic equations. The well model allows specification of rate or pressure constraints on well performance, and the user is free to add or to recomplete wells during the simulation. In addition, the user can define multiple rock and PVT regions and can choose from three aquifer models. BOAST II also provides flexible initialization, a bubble-point tracking scheme, automatic time-step control, and a material balance check on solution stability. The user controls output, which includes a run summary and line-printer plots of fieldwide performance.

  11. Nanocomposites as thermoelectric materials

    E-Print Network [OSTI]

    Hao, Qing

    2010-01-01T23:59:59.000Z

    Thermoelectric materials have attractive applications in electric power generation and solid-state cooling. The performance of a thermoelectric device depends on the dimensionless figure of merit (ZT) of the material, ...

  12. Factors of material consumption

    E-Print Network [OSTI]

    Silva Díaz, Pamela Cristina

    2012-01-01T23:59:59.000Z

    Historic consumption trends for materials have been studied by many researchers, and, in order to identify the main drivers of consumption, special attention has been given to material intensity, which is the consumption ...

  13. Earth-Abundant Materials

    Broader source: Energy.gov [DOE]

    DOE funds research into Earth-abundant materials for thin-film solar applications in response to the issue of materials scarcity surrounding other photovoltaic (PV) technologies. Below are a list...

  14. Nanostructured composite reinforced material

    DOE Patents [OSTI]

    Seals, Roland D. (Oak Ridge, TN); Ripley, Edward B. (Knoxville, TN); Ludtka, Gerard M. (Oak Ridge, TN)

    2012-07-31T23:59:59.000Z

    A family of materials wherein nanostructures and/or nanotubes are incorporated into a multi-component material arrangement, such as a metallic or ceramic alloy or composite/aggregate, producing a new material or metallic/ceramic alloy. The new material has significantly increased strength, up to several thousands of times normal and perhaps substantially more, as well as significantly decreased weight. The new materials may be manufactured into a component where the nanostructure or nanostructure reinforcement is incorporated into the bulk and/or matrix material, or as a coating where the nanostructure or nanostructure reinforcement is incorporated into the coating or surface of a "normal" substrate material. The nanostructures are incorporated into the material structure either randomly or aligned, within grains, or along or across grain boundaries.

  15. Institute for Materials Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Institute for Material Science Who we are and what we do 2:23 Institute for Materials Science: Alexander V. Balatsky IMS is an interdisciplinary research and educational center...

  16. Materials Science & Engineering

    E-Print Network [OSTI]

    and Forensics team in the Polymers and Coatings Group, MST-7. He graduated from the University of Toledo, aerogels, carbon fiber composites, damaged materials, and low density materials examining defects

  17. Geopolymer Sealing Materials

    Broader source: Energy.gov [DOE]

    DOE Geothermal Peer Review 2010 - Presentation. Project objectives: Develop and characterize field-applicable geopolymer temporary sealing materials in the laboratory and to transfer this developed material technology to geothermal drilling service companies as collaborators for field validation tests.

  18. Instructions and Materials

    Broader source: Energy.gov [DOE]

    The following are 2012 Program Peer Review Meeting instructions, materials and resource links for presenters and reviewers.

  19. Advanced neutron absorber materials

    DOE Patents [OSTI]

    Branagan, Daniel J. (Idaho Falls, ID); Smolik, Galen R. (Idaho Falls, ID)

    2000-01-01T23:59:59.000Z

    A neutron absorbing material and method utilizing rare earth elements such as gadolinium, europium and samarium to form metallic glasses and/or noble base nano/microcrystalline materials, the neutron absorbing material having a combination of superior neutron capture cross sections coupled with enhanced resistance to corrosion, oxidation and leaching.

  20. Magnetocaloric Materials Stinus Jeppesen

    E-Print Network [OSTI]

    Magnetocaloric Materials Stinus Jeppesen Risø-PhD-43(EN) Risø National Laboratory for Sustainable Jeppesen Title: Magnetocaloric Materials Division: Fuel Cells and Solid State Chemistry Division Risø.D. degree at The University of Copenhagen Abstract: New and improved magnetocaloric materials are one

  1. Radioactive Materials License Commitments

    E-Print Network [OSTI]

    Radioactive Materials License Commitments for The University of Texas at Austin May 2009 July 2009 in the use of radioactive materials. In July 1963, the State of Texas granted The University of Texas at Austin a broad radioactive materials license for research, development and instruction. While this means

  2. Development of biomass gasification to produce substitute fuels

    SciTech Connect (OSTI)

    Evans, R.J.; Knight, R.A.; Onischak, M.; Babu, S.P.

    1988-03-01T23:59:59.000Z

    The development of an efficient pressurized, medium-Btu steam-oxygen-blown fluidized-bed biomass gasification process was conducted. The overall program included initial stages of design-support research before the 12-ton-per-day (TPD) process research unit (PRU) was built. These stages involved the characterization of test-specific biomass species and the characteristics and limits of fluidization control. Also obtained for the design of the adiabatic PRU was information from studies with bench-scale equipment on the rapid rates of biomass devolatilization and on kinetics of the rate-controlling step of biomass char and steam gasification. The development program culminated with the sucessful operation of the PRU through 19 parametric-variation tests and extended steady-state process-proving tests. the program investigated the effect of gasifier temperature, pressure, biomass throughput rate, steam-to-biomass ratio, type of feedstock, feedstock moisture, and fludized-bed height on gasification performance. A long-duration gasification test of 3 days steady-state operation was conducted with the whole tree chips to indentify long-term effects of fluidized process conditions; to establish gasifier material and energy balances; to determine the possible breakthrough of low concentration organic species; and to evaluate the mechanical performance of the system components. Results indicate that the pressurized fludizied-bed process, can achieve carbon conversions of about 95% with cold gas thermal efficiences about 75% and with low and tar production. New information was collected on the oil and tar fraction, which relate to the process operating conditions and feedstock type. The different feedstocks studied were very similar in elemental compositions, and produced similar product gas compositions, but each has a different distribution and character of the oil and tar fractions. 11 refs., 45 figs., 18 tabs.

  3. CSC6870 Computer Graphics II Bezier Curves

    E-Print Network [OSTI]

    Hua, Jing

    CSC6870 Computer Graphics II Bezier Curves CSC6870 Computer Graphics II Bezier Curve CSC6870 Computer Graphics II Cubic Bezier Curves · Curve: · Control points · Basis functions: = = 3 0 3 )()( i ii uBpuc ip CSC6870 Computer Graphics II Bezier Curves (degree n) · Curve: · Control points · Basis functions

  4. CSC6870 Computer Graphics II Geometric Modeling

    E-Print Network [OSTI]

    Hua, Jing

    CSC6870 Computer Graphics II Geometric Modeling CSC6870 Computer Graphics II Overview 3D Shape, subdivision surfaces, implicit surfaces, particles. · Solids CSC6870 Computer Graphics II Basic Shapes CSC6870 Computer Graphics II Fundamental Shapes CSC6870 Computer Graphics II Fundamental Shapes CSC6870 Computer

  5. RadSTraM: Radiological Source Tracking and Monitoring, Phase II Final Report

    SciTech Connect (OSTI)

    Warren, Tracy A [ORNL; Walker, Randy M [ORNL; Hill, David E [ORNL; Gross, Ian G [ORNL; Smith, Cyrus M [ORNL; Abercrombie, Robert K [ORNL

    2008-12-01T23:59:59.000Z

    This report focuses on the technical information gained from the Radiological Source Tracking and Monitoring (RadSTraM) Phase II investigation and its implications. The intent of the RadSTraM project was to determine the feasibility of tracking radioactive materials in commerce, particularly International Atomic Energy Agency (IAEA) Category 3 and 4 materials. Specifically, Phase II of the project addressed tracking radiological medical isotopes in commerce. These categories of materials are susceptible to loss or theft but the problem is not being addressed by other agencies.

  6. ORIGINAL PAPER Why is the molybdenum-substituted tungsten-dependent

    E-Print Network [OSTI]

    Liao, Rongzhen

    ORIGINAL PAPER Why is the molybdenum-substituted tungsten-dependent formaldehyde ferredoxin oxidoreductase is a tungsten-dependent enzyme that catalyzes the oxidative degradation of formaldehyde to formic acid. The moly- bdenum ion can be incorporated into the active site to displace the tungsten ion

  7. Long-range interactions between substitutional nitrogen dopants in graphene: electronic properties calculations

    E-Print Network [OSTI]

    Boyer, Edmond

    Long-range interactions between substitutional nitrogen dopants in graphene: electronic properties special properties. In particular, a point-like defect in graphene may induce perturbations in the long the properties of an isolated defect. Still, this approach is often used in ab-initio electronic structure

  8. Biological therapy of strontium-substituted bioglass for soft tissue wound-healing

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Biological therapy of strontium-substituted bioglass for soft tissue wound-healing: Responses to oxidative stress in ovariectomised rats La thérapie biologique de verre bioactif substitué au strontium pour and regeneration. Bioactive glasses (BG) containing strontium have shown successful applicationsin tissue

  9. Internship Substitution Application Form Major and Special Concentration in Sustainable Development

    E-Print Network [OSTI]

    Internship Substitution Application Form Major and Special Concentration in Sustainable Development to the "Practicum" section of the Major and Special Concentration in Sustainable Development requirements in Environmental Science and Policy · INAF U3500, EI-Lamont Sustainable Development Practicum 1. Please list

  10. Graduation Checklist for Master's Non-thesis or Thesis Substitute students

    E-Print Network [OSTI]

    Texas at Arlington, University of

    are graduating (usually within 30 days of the first day of class). If you are completing a project or takingGraduation Checklist for Master's Non-thesis or Thesis Substitute students This list is for student use only and is not to be submitted to the Graduate School at any time. You can save a filled copy

  11. Nucleophilic substitutions of 1-alkenylcyclopropyl esters and 1-alkynylcyclopropyl chlorides catalyzed by palladium (0)

    SciTech Connect (OSTI)

    Stolle, A. [George-August-Universitaet, Goettingen (Germany)]|[Universite de Paris-Sud, Orsay (France); Ollivier, J.; Salauen, J. [Universite de Paris-Sud, Orsay (France)] [and others

    1992-05-20T23:59:59.000Z

    The 1-ethenylcyclopropylsulfonates 2e,f and 2-cyclopropylideneethyl esters 10b,c, readily available from cyclopropanone hemiacetal 1, undergo regioselective Pd(0) catalyzed nucleophilic substitution via the unsymmetric 1,1-dimethylene-{pi}-allyl complex 23. With stabilized anions (enolates of malonic ester, {beta}-dicarbonyl compounds, {beta}-sulfonyl ester, and Schiff bases as well as acetate anion, sulfonamide anion, etc.) the nucleophilic substitution occurs at the terminal vinylic position exclusively, providing cyclopropylideneethyl derivatives as building blocks of high synthetic potential. Competition experiments have disclosed that 1-ethenylcyclopropyl tosylate (2e) and cyclopropylideneethyl acetate (10b) are more reactive than dimethylallyl acetates 19 and 22, respectively. Use of chiral phosphines as ligands in the palladium catalyst can provide optically active methylenecyclopropane derivatives. With phenyl-, methyl-, and even n-butylzinc chloride as nucleophiles, the reaction apparently proceeds with initial transfer of the organic residue to palladium, followed by reductive elimination entailing tertiary substitution on the cyclopropane ring exclusively; the same type of product is obtained with azide and bis(trimethylsilyl)amide. But the site of hydride attack to yield reduction products depends on the hydride source. 1-Alkynylcyclopropyl chlorides 12, 13, and 14 react only with organozinc chlorides (nonstabilized nucleophiles) to provide mixtures of ethenylidenecyclopropanes 65 and alkynylcyclopropanes 66, via the {sigma}-palladium complexes 69 and 70, while chloride 15 undergoes mainly reduction. Other transition metal catalysts (Ni, Mo) also induce substitutions, but with poorer regioselectivity. 81 refs., 9 figs., 3 tabs.

  12. Variances of the Average Numbers of Nucleotide Substitutions Within and Between Populations'

    E-Print Network [OSTI]

    Nei, Masatoshi

    Variances of the Average Numbers of Nucleotide Substitutions Within and Between Populations the variances of nucleotide diversity within pop- ulations and of nucleotide divergence between populations of the extent of DNA polymorphism is nucleotide diversity (z), which is defined as the average number of either

  13. Variation in the Pattern of Nucleotide Substitution Across Sites John P. Huelsenbeck,1

    E-Print Network [OSTI]

    Nielsen, Rasmus

    Variation in the Pattern of Nucleotide Substitution Across Sites John P. Huelsenbeck,1 Rasmus, CA 94720-3140, USA Received: 4 November 1997 / Accepted: 19 May 1998 Abstract. A model of nucleotide was not accommodated, suggesting that it may be important to accommodate variation in the pattern of nucleotide sub

  14. EPR, ENDOR, and optical-absorption study of Cr3 centers substituting

    E-Print Network [OSTI]

    Malovichko, Galina

    ARTICLES EPR, ENDOR, and optical-absorption study of Cr3Âż centers substituting for niobium in Li of Sciences, Kiev, Ukraine Received 6 January 2000; revised manuscript received 3 May 2000 A triplet of EPR % of Cr. Detailed investigations of the angular dependencies of EPR and electron nuclear double

  15. Computational Study of Bond Dissociation Enthalpies for Substituted $\\beta$-O-4 Lignin Model Compounds

    SciTech Connect (OSTI)

    Younker, Jarod M [ORNL; Beste, Ariana [ORNL; Buchanan III, A C [ORNL

    2011-01-01T23:59:59.000Z

    The biopolymer lignin is a potential source of valuable chemicals. Phenethyl phenyl ether (PPE) is representative of the dominant $\\beta$-O-4 ether linkage. Density functional theory (DFT) is used to calculate the Boltzmann-weighted carbon-oxygen and carbon-carbon bond dissociation enthalpies (BDEs) of substituted PPE. These values are important in order to understand lignin decomposition. Exclusion of all conformers that have distributions of less than 5\\% at 298 K impacts the BDE by less than 1 kcal mol$^{-1}$. We find that aliphatic hydroxyl/methylhydroxyl substituents introduce only small changes to the BDEs (0-3 kcal mol$^{-1}$). Substitution on the phenyl ring at the $ortho$ position substantially lowers the C-O BDE, except in combination with the hydroxyl/methylhydroxyl substituents, where the effect of methoxy substitution is reduced by hydrogen bonding. Hydrogen bonding between the aliphatic substituents and the ether oxygen in the PPE derivatives has a significant influence on the BDE. CCSD(T)-calculated BDEs and hydrogen bond strengths of $ortho$-substituted anisoles when compared with M06-2X values confirm that the latter method is sufficient to describe the molecules studied and provide an important benchmark for lignin model compounds.

  16. National Synchrotron Light Source II

    ScienceCinema (OSTI)

    Steve Dierker

    2010-01-08T23:59:59.000Z

    The National Synchrotron Light Source II (NSLS-II) at the U.S. Department of Energy's Brookhaven National Laboratory is a proposed new state-of-the-art medium energy storage ring designed to deliver world-leading brightness and flux with top-off operation

  17. Estimation of the Number of Nucleotide Substitutions in the Control Region of Mitochondrial DNA in Humans and

    E-Print Network [OSTI]

    Nei, Masatoshi

    Estimation of the Number of Nucleotide Substitutions in the Control Region of Mitochondrial DNA of Molecular Evolutionary Genetics, The Pennsylvania State University Examining the pattern of nucleotide per site, as well as the total number of nucleotide substitutions. In this method, excess transitions

  18. When learning about the real world is better done virtually: A study of substituting computer simulations for laboratory equipment

    E-Print Network [OSTI]

    Colorado at Boulder, University of

    When learning about the real world is better done virtually: A study of substituting computer simulations for laboratory equipment N. D. Finkelstein, W. K. Adams, C. J. Keller, P. B. Kohl, K. K. Perkins; published 6 October 2005 This paper examines the effects of substituting a computer simulation for real

  19. A High-Conduction Ge Substituted Li3AsS4 Solid Electrolyte with Exceptional Low Activation Energy

    SciTech Connect (OSTI)

    Sahu, Gayatri [ORNL; Rangasamy, Ezhiylmurugan [ORNL; Li, Juchuan [ORNL; Chen, Yan [ORNL; An, Ke [ORNL; Dudney, Nancy J [ORNL; Liang, Chengdu [ORNL

    2014-01-01T23:59:59.000Z

    Lithium-ion conducting solid electrolytes show potential to enable high-energy-density secondary batteries and offer distinctive safety features as an advantage over traditional liquid electrolytes. Achieving the combination of high ionic conductivity, low activation energy, and outstanding electrochemical stability in crystalline solid electrolytes is a challenge for the synthesis of novel solid electrolytes. Herein we report an exceptionally low activation energy (Ea) and high room temperature superionic conductivity via facile aliovalent substitution of Li3AsS4 by Ge, which increased the conductivity by two orders of magnitude as compared to the parent compound. The composition Li3.334Ge0.334As0.666S4 has a high ionic conductivity of 1.12 mScm-1 at 27oC. Local Li+ hopping in this material is accompanied by distinctive low activation energy Ea of 0.17 eV being the lowest of Li+ solid conductors. Furthermore, this study demonstrates the efficacy of surface passivation of solid electrolyte to achieve compatibility with metallic lithium electrodes.

  20. Unusual magnetic hysteresis and the weakened transition behavior induced by Sn substitution in Mn{sub 3}SbN

    SciTech Connect (OSTI)

    Sun, Ying, E-mail: sunying@buaa.edu.cn [Center for Condensed Matter and Materials Physics, Department of Physics, Beihang University, Beijing 100191 (China); International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, Tsukuba, Ibaraki 305-0044 (Japan); Guo, Yanfeng; Li, Jun; Wang, Xia [Superconducting Properties Unit, National Institute for Materials Science, Tsukuba, Ibaraki 305-0044 (Japan); Tsujimoto, Yoshihiro [Materials Processing Unit, National Institute for Materials Science, Tsukuba, Ibaraki 305-0047 (Japan); Wang, Cong [Center for Condensed Matter and Materials Physics, Department of Physics, Beihang University, Beijing 100191 (China); Feng, Hai L.; Sathish, Clastin I.; Yamaura, Kazunari, E-mail: yamaura.kazunari@nims.go.jp [Superconducting Properties Unit, National Institute for Materials Science, Tsukuba, Ibaraki 305-0044 (Japan); Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Matsushita, Yoshitaka [Analysis Station, National Institute for Materials Science, Tsukuba, Ibaraki 305-0047 (Japan)

    2014-01-28T23:59:59.000Z

    Substitution of Sb with Sn was achieved in ferrimagnetic antiperovskite Mn{sub 3}SbN. The experimental results indicate that with an increase in Sn concentration, the magnetization continuously decreases and the crystal structure of Mn{sub 3}Sb{sub 1-x}Sn{sub x}N changes from tetragonal to cubic phase at around x of 0.8. In the doping series, step-like anomaly in the isothermal magnetization was found and this behavior was highlighted at x?=?0.4. The anomaly could be attributed to the magnetic frustration, resulting from competition between the multiple spin configurations in the antiperovskite lattice. Meantime, H{sub c} of 18 kOe was observed at x?=?0.3, which is probably the highest among those of manganese antiperovskite materials reported so far. With increasing Sn content, the abrupt change of resistivity and the sharp peak of heat capacity in Mn{sub 3}SbN were gradually weakened. The crystal structure refinements indicate the weakened change at the magnetic transition is close related to the change of c/a ratio variation from tetragonal to cubic with Sn content. The results derived from this study indicate that the behavior of Mn{sub 3}Sb{sub 1-x}Sn{sub x}N could potentially enhance its scientific and technical applications, such as spin torque transfer and hard magnets.

  1. Ab initio theory of planetary materials Artem R. Oganov*, I

    E-Print Network [OSTI]

    Oganov, Artem R.

    ) density (r), and pressure (P) as a function of depth. Seismic tomography gives 3D-variations of seismicAb initio theory of planetary materials Artem R. Oganov*, I , G. David PriceII and Sandro Scandolo and Neptune), referring the reader to an excellent book [1] for more details. Internal structure For the Earth

  2. Procedures for the Proper Disposition of Equipment and Materials Through

    E-Print Network [OSTI]

    Maroncelli, Mark

    Material (ACM) 1. Description a. Asbestos is a naturally occurring fibrous mineral that was used Health and Safety ~ Radiation Protection #12;Environmental Protection ~ Occupational Health and Safety ~ Radiation Protection Table of Contents I. Introduction 1 II. Items Prohibited from Sale or Transfer A

  3. PARS II KNOWN ISSUES AND SUGGESTED WORKAROUNDS

    Energy Savers [EERE]

    screen, the following workaround is suggested: Close all browser windows (PARS II and web applications). Reopen a browser and proceed with the PARS II log-in. PARS II does...

  4. Materials Science and Materials Chemistry for Large Scale Electrochemi...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Science and Materials Chemistry for Large Scale Electrochemical Energy Storage: From Transportation to Electrical Grid Materials Science and Materials Chemistry for Large Scale...

  5. Montani, Kohn, Smith and Schultz (2006), Supplemental Material Supplemental Material

    E-Print Network [OSTI]

    Smith, Matthew A.

    Montani, Kohn, Smith and Schultz (2006), Supplemental Material 1 Supplemental Material A. Entropy, Kohn, Smith and Schultz (2006), Supplemental Material 2 occupied, it is ambiguous whether

  6. SMERDON ET AL.: AUXILIARY MATERIAL Auxiliary Material

    E-Print Network [OSTI]

    Smerdon, Jason E.

    run [Ammann et al., 2007; hereinafter CCSM] and the GKSS ECHO-g ERIK2 run [González-Rouco et al., 2006; hereinafter ECHO-g]. The annual means of the modeled temperature fields are interpolated to 5° latitude;SMERDON ET AL.: AUXILIARY MATERIAL 2 ECHO-g simulations, respectively. The above conventions

  7. Webinar: Systems Performance Advancement II Funding Opportunity...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Webinar: Systems Performance Advancement II Funding Opportunity Announcement Webinar: Systems Performance Advancement II Funding Opportunity Announcement January 22, 2015 2:00PM to...

  8. Absolute nuclear material assay

    DOE Patents [OSTI]

    Prasad, Manoj K. (Pleasanton, CA); Snyderman, Neal J. (Berkeley, CA); Rowland, Mark S. (Alamo, CA)

    2012-05-15T23:59:59.000Z

    A method of absolute nuclear material assay of an unknown source comprising counting neutrons from the unknown source and providing an absolute nuclear material assay utilizing a model to optimally compare to the measured count distributions. In one embodiment, the step of providing an absolute nuclear material assay comprises utilizing a random sampling of analytically computed fission chain distributions to generate a continuous time-evolving sequence of event-counts by spreading the fission chain distribution in time.

  9. CALCULO NUMERICO II Curso 2002/2003 (2 o

    E-Print Network [OSTI]

    QuirĂłs, Fernando

    C´ALCULO NUM´ERICO II Curso 2002/2003 (2 o cuatrimestre) Programa A. M´etodos num´ericos para de m´etodos lineales multipaso. B. M´etodos num´ericos para ecuaciones en derivadas parciales. 4 tema 5 utilizaremos como material b´asico unas notas sobre An´alisis Num´erico de EDP de evoluci

  10. Composite of refractory material

    DOE Patents [OSTI]

    Holcombe, C.E.; Morrow, M.S.

    1994-07-19T23:59:59.000Z

    A composite refractory material composition comprises a boron carbide matrix and minor constituents of yttrium-boron-oxygen-carbon phases uniformly distributed throughout the boron carbide matrix.

  11. Radiation Safety Training Materials

    Broader source: Energy.gov [DOE]

    The following Handbooks and Standard provide recommended hazard specific training material for radiological workers at DOE facilities and for various activities.

  12. Materials Research Staff

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    generation and detection, this approach naturally lends itself to in situ monitoring of material property evolution. The temporal laser pulse length and the corresponding...

  13. Webinar: Materials Genome Initative

    Broader source: Energy.gov [DOE]

    Audio recording and text version of the Fuel Cell Technologies Office webinar titled "Materials Genome Initiative," originally presented on December 2, 2014.

  14. Composite of refractory material

    DOE Patents [OSTI]

    Holcombe, Cressie E. (Knoxville, TN); Morrow, Marvin S. (Kingston, TN)

    1994-01-01T23:59:59.000Z

    A composite refractory material composition comprises a boron carbide matrix and minor constituents of yttrium-boron-oxygen-carbon phases uniformly distributed throughout the boron carbide matrix.

  15. Geopolymer Sealing Materials

    Broader source: Energy.gov (indexed) [DOE]

    Geopolymer Sealing Materials PI : Dr. Tomas Butcher Presenter: Dr. Toshi Sugama Brookhaven National Laboratory May 18, 2010 This presentation does not contain any proprietary...

  16. Materials for MA 182.

    E-Print Network [OSTI]

    Materials for MA 182. INSTRUCTOR: Richard Penney. Office: MATH 822: Telephone: 494-1968: e-mail: rcp@math.purdue.edu: Office Hours: Mon, Tu, Fri,

  17. Layered Cathode Materials

    Broader source: Energy.gov (indexed) [DOE]

    Layered Cathode Materials presented by Michael Thackeray Chemical Sciences and Engineering Division, Argonne Annual Merit Review DOE Vehicle Technologies Program Washington, D.C....

  18. EMSL - battery materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    battery-materials en Modeling Interfacial Glass-Water Reactions: Recent Advances and Current Limitations. http:www.emsl.pnl.govemslwebpublicationsmodeling-interfacial-glass-wa...

  19. Thermoelectric materials having porosity

    DOE Patents [OSTI]

    Heremans, Joseph P.; Jaworski, Christopher M.; Jovovic, Vladimir; Harris, Fred

    2014-08-05T23:59:59.000Z

    A thermoelectric material and a method of making a thermoelectric material are provided. In certain embodiments, the thermoelectric material comprises at least 10 volume percent porosity. In some embodiments, the thermoelectric material has a zT greater than about 1.2 at a temperature of about 375 K. In some embodiments, the thermoelectric material comprises a topological thermoelectric material. In some embodiments, the thermoelectric material comprises a general composition of (Bi.sub.1-xSb.sub.x).sub.u(Te.sub.1-ySe.sub.y).sub.w, wherein 0.ltoreq.x.ltoreq.1, 0.ltoreq.y.ltoreq.1, 1.8.ltoreq.u.ltoreq.2.2, 2.8.ltoreq.w.ltoreq.3.2. In further embodiments, the thermoelectric material includes a compound having at least one group IV element and at least one group VI element. In certain embodiments, the method includes providing a powder comprising a thermoelectric composition, pressing the powder, and sintering the powder to form the thermoelectric material.

  20. Management of Nuclear Materials

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2009-08-17T23:59:59.000Z

    To establish requirements for the lifecycle management of DOE owned and/or managed accountable nuclear materials. Cancels DOE O 5660.1B.

  1. Radioactive Material Transportation Practices

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2002-09-23T23:59:59.000Z

    Establishes standard transportation practices for Departmental programs to use in planning and executing offsite shipments of radioactive materials including radioactive waste. Does not cancel other directives.

  2. Hazardous Material Security (Maryland)

    Broader source: Energy.gov [DOE]

    All facilities processing, storing, managing, or transporting hazardous materials must be evaluated every five years for security issues. A report must be submitted to the Department of the...

  3. Vibrational Damping of Composite Materials

    E-Print Network [OSTI]

    Biggerstaff, Janet M.

    2006-01-01T23:59:59.000Z

    Smart Structures and Materials, 3989:531- 538. Biggerstaff,2002. “Electroviscoelastic Materials As Active Dampers”,Smart Structures and Materials, 4695:345-350. Biggerstaff,

  4. Deformation Mechanisms in Nanocrystalline Materials

    E-Print Network [OSTI]

    Mohamed, Farghalli A.; Yang, Heather

    2010-01-01T23:59:59.000Z

    2010 METALLURGICAL AND MATERIALS TRANSACTIONS A 47. F.A.12. METALLURGICAL AND MATERIALS TRANSACTIONS A VOLUME 41A,of Slip: Progress in Materials Science, Pergamon Press,

  5. Advanced Materials | More Science | ORNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Materials SHARE Advanced Materials ORNL has the nation's most comprehensive materials research program and is a world leader in research that supports the development of...

  6. LCLS-II New Instruments Workshops Report

    SciTech Connect (OSTI)

    Baradaran, Samira; Bergmann, Uwe; Durr, Herrmann; Gaffney, Kelley; Goldstein, Julia; Guehr, Markus; Hastings, Jerome; Heimann, Philip; Lee, Richard; Seibert, Marvin; Stohr, Joachim; /SLAC; ,

    2012-08-08T23:59:59.000Z

    The LCLS-II New Instruments workshops chaired by Phil Heimann and Jerry Hastings were held on March 19-22, 2012 at the SLAC National Accelerator Laboratory. The goal of the workshops was to identify the most exciting science and corresponding parameters which will help define the LCLS-II instrumentation. This report gives a synopsis of the proposed investigations and an account of the workshop. Scientists from around the world have provided short descriptions of the scientific opportunities they envision at LCLS-II. The workshops focused on four broadly defined science areas: biology, materials sciences, chemistry and atomic, molecular and optical physics (AMO). Below we summarize the identified science opportunities in the four areas. The frontiers of structural biology lie in solving the structures of large macromolecular biological systems. Most large protein assemblies are inherently difficult to crystallize due to their numerous degrees of freedom. Serial femtosecond protein nanocrystallography, using the 'diffraction-before-destruction' approach to outrun radiation damage has been very successfully pioneered at LCLS and diffraction patterns were obtained from some of the smallest protein crystals ever. The combination of femtosecond x-ray pulses of high intensity and nanosized protein crystals avoids the radiation damage encountered by conventional x-ray crystallography with focused beams and opens the door for atomic structure determinations of the previously largely inaccessible class of membrane proteins that are notoriously difficult to crystallize. The obtained structures will allow the identification of key protein functions and help in understanding the origin and control of diseases. Three dimensional coherent x-ray imaging at somewhat lower resolution may be used for larger objects such as viruses. The chemistry research areas of primary focus are the predictive understanding of catalytic mechanisms, with particular emphasis on photo- and heterogeneous catalysis. Of particular interest is the efficient conversion of light to electrical or chemical energy, which requires understanding the non-adiabatic dynamics of electronic excited states. Ultrafast x-ray scattering presents an excellent opportunity to investigate structural dynamics of molecular systems with atomic resolution, and x-ray scattering and spectroscopy present an excellent opportunity to investigating the dynamics of the electronic charge distribution. Harnessing solar energy to generate fuels, either indirectly with photovoltaics and electrochemical catalysis or directly with photocatalysts, presents a critical technological challenge that will require the use of forefront scientific tools such as ultrafast x-rays. At the center of this technical challenge is the rational design of efficient and cost effective catalysts. Important materials science opportunities relate to information technology applications, in particular the transport and storage of information on increasingly smaller length- and faster time-scales. Of interest are the understanding of the intrinsic size limits associated with the storage of information bits and the speed limits of information or bit processing. Key questions revolve about how electronic charges and spins of materials can be manipulated by electric and magnetic fields. This requires the exploration of speed limits subject to the fundamental conservation laws of energy and linear and angular momentum and the different coupling of polar electric and axial magnetic fields to charge and spin. Of interest are novel composite materials, including molecular systems combining multi electric and magnetic functionality. Ultrafast x-rays offer the required probing speed, can probe either the charge or spin properties through polarization control and through scattering and spectroscopy cover the entire energy-time-momentum-distance phase space. In the field of atomic and molecular science, LCLS II promises to elucidate the fundamental interactions among electrons and between electrons and nuclei, and to explore the fron

  7. Options Study - Phase II

    SciTech Connect (OSTI)

    R. Wigeland; T. Taiwo; M. Todosow; W. Halsey; J. Gehin

    2010-09-01T23:59:59.000Z

    The Options Study has been conducted for the purpose of evaluating the potential of alternative integrated nuclear fuel cycle options to favorably address the issues associated with a continuing or expanding use of nuclear power in the United States. The study produced information that can be used to inform decisions identifying potential directions for research and development on such fuel cycle options. An integrated nuclear fuel cycle option is defined in this study as including all aspects of the entire nuclear fuel cycle, from obtaining natural resources for fuel to the ultimate disposal of used nuclear fuel (UNF) or radioactive wastes. Issues such as nuclear waste management, especially the increasing inventory of used nuclear fuel, the current uncertainty about used fuel disposal, and the risk of nuclear weapons proliferation have contributed to the reluctance to expand the use of nuclear power, even though it is recognized that nuclear power is a safe and reliable method of producing electricity. In this Options Study, current, evolutionary, and revolutionary nuclear energy options were all considered, including the use of uranium and thorium, and both once-through and recycle approaches. Available information has been collected and reviewed in order to evaluate the ability of an option to clearly address the challenges associated with the current implementation and potential expansion of commercial nuclear power in the United States. This Options Study is a comprehensive consideration and review of fuel cycle and technology options, including those for disposal, and is not constrained by any limitations that may be imposed by economics, technical maturity, past policy, or speculated future conditions. This Phase II report is intended to be used in conjunction with the Phase I report, and much information in that report is not repeated here, although some information has been updated to reflect recent developments. The focus in this Options Study was to identify any nuclear fuel cycle technology or option that may result in a significant beneficial impact to the issues as compared to the current U.S. approach of once-through use of nuclear fuel in LWRs or similar reactors followed by direct disposal of UNF. This approach was taken because incremental differences may be difficult to clearly identify and justify due to the large uncertainties that can be associated with the specific causes of the issues. Phase II of this Options Study continued the review of nuclear fuel cycle options that was initiated and documented during Phase I, concentrating on reviewing and summarizing the potential of integrated nuclear fuel cycles. However, based on the reviews of previous studies and available data, it was not always possible to clearly determine sufficiently large differences between the various fuel cycle and technology options for some of the issues or evaluation measures, for example, in cases where only incremental differences with respect to the issues might be achieved regardless of the fuel cycle option or technologies being considered, or where differences were insufficient to clearly rise above the uncertainties.

  8. Super KEKB / Belle II Project

    E-Print Network [OSTI]

    B. Golob

    2010-06-22T23:59:59.000Z

    We present the status of the KEKB collider and the Belle detector upgrade, along with several examples of physics measurements to be performed with Belle II at Super KEKB.

  9. Environmental Chemistry II (Atmospheric Chemistry)

    E-Print Network [OSTI]

    Dibble, Theodore

    Seinfeld, J. H. and Pandis, S. N. Atmospheric Chemistry and Physics: From Air Pollution to Climate ChangeSYLLABUS FOR Environmental Chemistry II (Atmospheric Chemistry) FCH 511 Fall 2013 Theodore S

  10. Materials Research Science and Engineering Center (MRSEC) 2013/2014 Rolling Call for Proposals for Support of

    E-Print Network [OSTI]

    Wisconsin at Madison, University of

    , Optical and Magnetic Properties MSE 470 Capstone Project I MSE 471 Capstone Project II Materials Emphasis Fundamentals of Analytical Science Chem 345 Intermediate Organic Chemistry Geol 203 Earth Materials Phys 205 and Electronic Circuits EMA 303 Mechanics of Materials Phys 321 Electric Circuits and Electronics Stat 424

  11. Aerogel Derived Nanostructured Thermoelectric Materials

    SciTech Connect (OSTI)

    Wendell E Rhine, PI; Dong, Wenting; Greg Caggiano, PM

    2010-10-08T23:59:59.000Z

    America’s dependence on foreign sources for fuel represents a economic and security threat for the country. These non renewable resources are depleting, and the effects of pollutants from fuels such as oil are reaching a problematic that affects the global community. Solar concentration power (SCP) production systems offer the opportunity to harness one of the United States’ most under utilized natural resources; sunlight. While commercialization of this technology is increasing, in order to become a significant source of electricity production in the United States the costs of deploying and operating SCP plants must be further reduced. Parabolic Trough SCP technologies are close to meeting energy production cost levels that would raise interest in the technology and help accelerate its adoption as a method to produce a significant portion of the Country’s electric power needs. During this program, Aspen Aerogels will develop a transparent aerogel insulation that can replace the costly vacuum insulation systems that are currently used in parabolic trough designs. During the Phase I program, Aspen Aerogels will optimize the optical and thermal properties of aerogel to meet the needs of this application. These properties will be tested, and the results will be used to model the performance of a parabolic trough HCE system which uses this novel material in place of vacuum. During the Phase II program, Aspen Aerogels will scale up this technology. Together with industry partners, Aspen Aerogels will build and test a prototype Heat Collection Element that is insulated with the novel transparent aerogel material. This new device will find use in parabolic trough SCP applications.

  12. Impacted material placement plans

    SciTech Connect (OSTI)

    Hickey, M.J.

    1997-01-29T23:59:59.000Z

    Impacted material placement plans (IMPP) are documents identifying the essential elements in placing remediation wastes into disposal facilities. Remediation wastes or impacted material(s) are those components used in the construction of the disposal facility exclusive of the liners and caps. The components might include soils, concrete, rubble, debris, and other regulatory approved materials. The IMPP provides the details necessary for interested parties to understand the management and construction practices at the disposal facility. The IMPP should identify the regulatory requirements from applicable DOE Orders, the ROD(s) (where a part of a CERCLA remedy), closure plans, or any other relevant agreements or regulations. Also, how the impacted material will be tracked should be described. Finally, detailed descriptions of what will be placed and how it will be placed should be included. The placement of impacted material into approved on-site disposal facilities (OSDF) is an integral part of gaining regulatory approval. To obtain this approval, a detailed plan (Impacted Material Placement Plan [IMPP]) was developed for the Fernald OSDF. The IMPP provides detailed information for the DOE, site generators, the stakeholders, regulatory community, and the construction subcontractor placing various types of impacted material within the disposal facility.

  13. Nanocrystalline heterojunction materials

    DOE Patents [OSTI]

    Elder, Scott H.; Su, Yali; Gao, Yufei; Heald, Steve M.

    2003-07-15T23:59:59.000Z

    Mesoporous nanocrystalline titanium dioxide heterojunction materials are disclosed. In one disclosed embodiment, materials comprising a core of titanium dioxide and a shell of a molybdenum oxide exhibit a decrease in their photoadsorption energy as the size of the titanium dioxide core decreases.

  14. Materials for Information Technology

    E-Print Network [OSTI]

    Tang, Ben Zhong

    on thin-film and nano-scale materials. The papers include content ranging from materials-related aspects for these fascinating and useful mate- rials. /jr Adv. Eng. Mater. 2009, 11, Issue 4 Colloidal Hollow Spheres Colloidal hollow spheres of conduct- ing polymers such as polypyrrole (PPy) or polyaniline (PAni) are produced

  15. Nanocrystalline Heterojunction Materials

    DOE Patents [OSTI]

    Elder, Scott H. (Portland, OR); Su, Yali (Richland, WA); Gao, Yufei (Blue Bell, PA); Heald, Steve M. (Downers Grove, IL)

    2004-02-03T23:59:59.000Z

    Mesoporous nanocrystalline titanium dioxide heterojunction materials and methods of making the same are disclosed. In one disclosed embodiment, materials comprising a core of titanium dioxide and a shell of a molybdenum oxide exhibit a decrease in their photoadsorption energy as the size of the titanium dioxide core decreases.

  16. Materials Science and Technology Mechanical and Materials Engineering

    E-Print Network [OSTI]

    Birmingham, University of

    Materials Science and Technology Metallurgy Mechanical and Materials Engineering Materials Science with Energy Engineering Materials Science with Business Management Course Prospectus School of Metallurgy for Metallurgy and Materials What difference will you make? #12;2 School of Metallurgy and Materials Contents

  17. Mössbauer spectroscopy, magnetic characteristics, and reflection loss analysis of nickel-strontium substituted cobalt ferrite nanoparticles

    SciTech Connect (OSTI)

    Ghasemi, Ali, E-mail: ali13912001@yahoo.com [Materials Engineering Department, Malek Ashtar University of Technology, Shahin Shahr (Iran, Islamic Republic of); Paesano, Andrea; Cerqueira Machado, Carla Fabiana [Departamento de Física, Centro de Cięncias Exatas, Universidade Estadual de Maringá, Maringá (Brazil); Shirsath, Sagar E. [Department of Physics, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad (India); Spin Device Technology Center, Faculty of Engineering, Shinshu University, Nagano (Japan); Liu, Xiaoxi; Morisako, Akimitsu [Spin Device Technology Center, Faculty of Engineering, Shinshu University, Nagano (Japan)

    2014-05-07T23:59:59.000Z

    In current research work, Co{sub 1-x}Ni{sub x/2}Sr{sub x/2}Fe{sub 2}O{sub 4} (x?=?0–1 in a step of 0.2) ferrite nanoparticles were synthesized by a sol-gel method. According to the evolution in the subspectral areas obtained from Mössbauer spectroscopy, it was found that the relaxing iron belongs mostly to the site B, since the Mössbauer fraction of site A does not vary appreciably. With an increase in Ni-Sr substitution contents in cobalt ferrite, the coercivity and saturation of magnetization decrease. Variation of reflection loss versus frequency in microwave X-band demonstrates that the reflection peak shifts to lower frequency by adding substituted cations and the synthesized nanoparticles can be considered for application in electromagnetic wave absorber technology.

  18. Cation-substituted spinel oxide and oxyfluoride cathodes for lithium ion batteries

    DOE Patents [OSTI]

    Manthiram, Arumugam; Choi, Wonchang

    2010-05-18T23:59:59.000Z

    The present invention includes compositions and methods of making cation-substituted and fluorine-substituted spinel cathode compositions by firing a LiMn2-y-zLiyMzO4 oxide with NH4HF2 at low temperatures of between about 300 and 700.degree. C. for 2 to 8 hours and a .eta. of more than 0 and less than about 0.50, mixed two-phase compositions consisting of a spinel cathode and a layered oxide cathode, and coupling them with unmodified or surface modified graphite anodes in lithium ion cells.

  19. Apolipoprotein A-I mutant proteins having cysteine substitutions and polynucleotides encoding same

    DOE Patents [OSTI]

    Oda, Michael N. (Benicia, CA); Forte, Trudy M. (Berkeley, CA)

    2007-05-29T23:59:59.000Z

    Functional Apolipoprotein A-I mutant proteins, having one or more cysteine substitutions and polynucleotides encoding same, can be used to modulate paraoxonase's arylesterase activity. These ApoA-I mutant proteins can be used as therapeutic agents to combat cardiovascular disease, atherosclerosis, acute phase response and other inflammatory related diseases. The invention also includes modifications and optimizations of the ApoA-I nucleotide sequence for purposes of increasing protein expression and optimization.

  20. Materials of Gasification

    SciTech Connect (OSTI)

    None

    2005-09-15T23:59:59.000Z

    The objective of this project was to accumulate and establish a database of construction materials, coatings, refractory liners, and transitional materials that are appropriate for the hardware and scale-up facilities for atmospheric biomass and coal gasification processes. Cost, fabricability, survivability, contamination, modes of corrosion, failure modes, operational temperatures, strength, and compatibility are all areas of materials science for which relevant data would be appropriate. The goal will be an established expertise of materials for the fossil energy area within WRI. This would be an effort to narrow down the overwhelming array of materials information sources to the relevant set which provides current and accurate data for materials selection for fossil fuels processing plant. A significant amount of reference material on materials has been located, examined and compiled. The report that describes these resources is well under way. The reference material is in many forms including texts, periodicals, websites, software and expert systems. The most important part of the labor is to refine the vast array of available resources to information appropriate in content, size and reliability for the tasks conducted by WRI and its clients within the energy field. A significant has been made to collate and capture the best and most up to date references. The resources of the University of Wyoming have been used extensively as a local and assessable location of information. As such, the distribution of materials within the UW library has been added as a portion of the growing document. Literature from recent journals has been combed for all pertinent references to high temperature energy based applications. Several software packages have been examined for relevance and usefulness towards applications in coal gasification and coal fired plant. Collation of the many located resources has been ongoing. Some web-based resources have been examined.

  1. Blade System Design Study. Part II, final project report (GEC).

    SciTech Connect (OSTI)

    Griffin, Dayton A. (DNV Global Energy Concepts Inc., Seattle, WA)

    2009-05-01T23:59:59.000Z

    As part of the U.S. Department of Energy's Low Wind Speed Turbine program, Global Energy Concepts LLC (GEC)1 has studied alternative composite materials for wind turbine blades in the multi-megawatt size range. This work in one of the Blade System Design Studies (BSDS) funded through Sandia National Laboratories. The BSDS program was conducted in two phases. In the Part I BSDS, GEC assessed candidate innovations in composite materials, manufacturing processes, and structural configurations. GEC also made recommendations for testing composite coupons, details, assemblies, and blade substructures to be carried out in the Part II study (BSDS-II). The BSDS-II contract period began in May 2003, and testing was initiated in June 2004. The current report summarizes the results from the BSDS-II test program. Composite materials evaluated include carbon fiber in both pre-impregnated and vacuum-assisted resin transfer molding (VARTM) forms. Initial thin-coupon static testing included a wide range of parameters, including variation in manufacturer, fiber tow size, fabric architecture, and resin type. A smaller set of these materials and process types was also evaluated in thin-coupon fatigue testing, and in ply-drop and ply-transition panels. The majority of materials used epoxy resin, with vinyl ester (VE) resin also used for selected cases. Late in the project, testing of unidirectional fiberglass was added to provide an updated baseline against which to evaluate the carbon material performance. Numerous unidirectional carbon fabrics were considered for evaluation with VARTM infusion. All but one fabric style considered suffered either from poor infusibility or waviness of fibers combined with poor compaction. The exception was a triaxial carbon-fiberglass fabric produced by SAERTEX. This fabric became the primary choice for infused articles throughout the test program. The generally positive results obtained in this program for the SAERTEX material have led to its being used in innovative prototype blades of 9-m and 30-m length, as well as other non-wind related structures.

  2. Potential for substitution of geothermal energy at domestic defense installations and White Sands Missile Range

    SciTech Connect (OSTI)

    Bakewell, C.A.; Renner, J.L.

    1982-01-01T23:59:59.000Z

    Geothermal resources that might provide substitute energy at any of 76 defense installations are identified and evaluated. The geologic characteristics and related economics of potential geothermal resources located at or near the 76 installations were estimated. The geologic assessment identified 18 installations with possible geothermal resources and 4 Atlantic Coastal Plain resource configurations that represented the alternatives available to East Coast bases. These 18 locations and 4 resource configurations, together with 2 possible resources at the White Sands Missile Range and a potential resource at Kings Bay, Georgia, were examined to determine the relative economics of substituting potential geothermal energy for part or all of the existing oil, gas, and electrical energy usage. Four of the military installations - Mountain Home, Norton, Hawthorne, and Sierra - appear to be co-located with possible geothermal resources which, if present, might provide substitute energy at or below current market prices for oil. Six additional locations - Ellsworth, Luke, Williams, Bliss, Fallon, and Twentynine Palms - could become economically attractive under certain conditions. No geothermal resource was found to be economically competitive with natural gas at current controlled prices. Generation of electric power at the locations studied is estimated to be uneconomic at present.

  3. Polymeric media comprising polybenzimidazoles N-substituted with organic-inorganic hybrid moiety

    DOE Patents [OSTI]

    Klaehn, John R. (Idaho Falls, ID) [Idaho Falls, ID; Peterson, Eric S. (Idaho Falls, ID) [Idaho Falls, ID; Wertsching, Alan K. (Idaho Falls, ID) [Idaho Falls, ID; Orme, Christopher J. (Shelley, ID) [Shelley, ID; Luther, Thomas A. (Idaho Falls, ID) [Idaho Falls, ID; Jones, Michael G. (Pocatello, ID) [Pocatello, ID

    2009-12-15T23:59:59.000Z

    A PBI compound includes imidazole nitrogens at least a portion of which are substituted with an organic-inorganic hybrid moiety may be included in a separator medium. At least 85% of the imidazole nitrogens may be substituted. The organic-inorganic hybrid moiety may be an organosilane moiety, for example, (R)Me.sub.2SiCH.sub.2-- where R is selected from among methyl, phenyl, vinyl, and allyl. The separatory medium may exhibit an H.sub.2, Ar, N.sub.2, O.sub.2, CH.sub.3, or CO.sub.2 gas permeability greater than the gas permeability of a comparable separatory medium comprising the PBI compound without substitution. The separatory medium may further include an electronically conductive medium and/or ionically conductive medium. The separatory medium may be used as a membrane (semi-permeable, permeable, and non-permeable), a barrier, an ion exhcange media, a filter, a gas chromatography coating (such as stationary phase coating in affinity chromatography), etc.

  4. WORKING DOCUMENT for ISC -DRAFT -October 11th "Nanosciences, Nanotechnologies, Materials and new

    E-Print Network [OSTI]

    Meju, Max

    WORKING DOCUMENT for ISC - DRAFT - October 11th 2006 Theme 4 "Nanosciences, Nanotechnologies ------------------------------------------------------------------------------- Table of contents I Context 1 II Content of Calls 5 Nanosciences and Nanotechnologies 7 Materials 18 New "Nanosciences, Nanotechnologies, Materials and new Production Technologies ­ NMP" is to fund research

  5. MATERIAL R&D FOR HIGH-INTENSITY PROTON BEAM PROGRESS REPORT

    E-Print Network [OSTI]

    McDonald, Kirk

    , 2005 #12;GOAL SEARCH for and evaluate under irradiation environment NEW materials or composites) Load(N) non treated Invar Temp (300 C) Temp (500 C) #12;PHASE II -TARGET MATERIAL R&D · Carbon-Carbon and property measurements) #12;Carbon-Carbon Composite Target Temp. % elongation 23 o C 0% 200 o C -0.023% 400o

  6. Materials Corrosion and Mitigation Strategies for APT, End of FY '97 Report

    E-Print Network [OSTI]

    Materials Corrosion and Mitigation Strategies for APT, End of FY '97 Report: II. Out-of-Beam Corrosion Rates and Water Analysis from the '97 A6 Irradiation R. Scott Lillard, Donald L. Pile, Darryl P. Butt Materials Corrosion & Environmental Effects Lab MST-6, Metallurgy Group Los Alamos National

  7. Packaging and Transfer or Transportation of Materials of National Security Interest

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2004-04-26T23:59:59.000Z

    To establish requirements and responsibilities for offsite shipments of naval nuclear fuel elements, Category I and Category II special nuclear material, nuclear explosives, nuclear components, special assemblies, and other materials of national security interest. Cancels DOE O 461.1. Canceled by DOE O 461.1B and DOE O 461.2.

  8. Packaging and Transfer or Transportation of Materials of National Security Interest

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2000-09-29T23:59:59.000Z

    To establish requirements and responsibilities for the Transportation Safeguards System (TSS) packaging and transportation and onsite transfer of nuclear explosives, nuclear components, Naval nuclear fuel elements, Category I and Category II special nuclear materials, special assemblies, and other materials of national security interest. Cancels: DOE 5610.12 and DOE 5610.14.

  9. Computational modeling and design of actively-cooled microvascular materials Soheil Soghrati a,b

    E-Print Network [OSTI]

    Sottos, Nancy R.

    to the optimization study, the IGFEM solver is validated through comparison with infrared measurements of the thermal of such systems to a broad field including autonomic materials [6], biotechnology [7,8], chemical reactors [9 in two specific ways: (i) by direct extraction of heat from the thermally loaded material, and (ii

  10. NSLS-II Preliminary Design Report

    SciTech Connect (OSTI)

    Dierker, S.

    2007-11-01T23:59:59.000Z

    Following the CD0 approval of the National Synchrotron Light Source II (NSLS-II) during August 2005, Brookhaven National Laboratory prepared a conceptual design for a worldclass user facility for scientific research using synchrotron radiation. DOE SC review of the preliminary baseline in December 2006 led to the subsequent CD1 approval (approval of alternative selection and cost range). This report is the documentation of the preliminary design work for the NSLS-II facility. The preliminary design of the Accelerator Systems (Part 1) was developed mostly based of the Conceptual Design Report, except for the Booster design, which was changed from in-storage-ring tunnel configuration to in external- tunnel configuration. The design of beamlines (Part 2) is based on designs developed by engineering firms in accordance with the specification provided by the Project. The conventional facility design (Part 3) is the Title 1 preliminary design by the AE firm that met the NSLS-II requirements. Last and very important, Part 4 documents the ES&H design and considerations related to this preliminary design. The NSLS-II performance goals are motivated by the recognition that major advances in many important technology problems will require scientific breakthroughs in developing new materials with advanced properties. Achieving this will require the development of new tools that will enable the characterization of the atomic and electronic structure, chemical composition, and magnetic properties of materials, at nanoscale resolution. These tools must be nondestructive, to image and characterize buried structures and interfaces, and they must operate in a wide range of temperatures and harsh environments. The NSLS-II facility will provide ultra high brightness and flux and exceptional beam stability. It will also provide advanced insertion devices, optics, detectors, and robotics, and a suite of scientific instruments designed to maximize the scientific output of the facility. Together these will enable the study of material properties and functions with a spatial resolution of {approx}1 nm, an energy resolution of {approx}0.1 meV, and the ultra high sensitivity required to perform spectroscopy on a single atom. In order to meet this need, NSLS-II has been designed to provide world-leading brightness and flux and exceptional beam stability. The brightness is defined as the number of photons emitted per second, per photon energy bandwidth, per solid angle, and per unit source size. Brightness is important because it determines how efficiently an intense flux of photons can be refocused to a small spot size and a small divergence. It scales as the ring current and the number of total periods of the undulator field (both of which contribute linearly to the total flux), as well as eing nversely proportional to the horizontal and vertical emittances (the product of beam size and divergence) of the electron beam. Raising the current in the storage ring to obtain even brighter beams is ultimately limited by beam-driven, collective instabilities in the accelerator. Thus, to maximize the brightness, the horizontal and vertical emittances must be made as small as possible. With the concept of using damping wigglers, low-field bending magnets, and a large number of lattice cells to achieve ultra small emittance, the performance of NSLS-II will be nearly at the ultimate limit of storage ring light sources, set by the intrinsic properties of the synchrotron radiation process. The facility will produce x-rays more than 10,000 times brighter than those produced at NSLS today. The facility, with various insertion devices, including three-pole-wigglers and low-field dipole radiations, has the capability of covering a broad range of radiation spectra, from hard x-ray to far infra-red. The superlative character and combination of capabilities will have broad impact on a wide range of disciplines and scientific initiatives in the coming decades, including new studies of small crystals in structural biology, a wide range of nanometer-resolution probes

  11. A Fully Biobased Epoxy Resin from Vegetable Oils: From the Synthesis of the Precursors by Thiol-ene Reaction to the Study of the Final Material

    E-Print Network [OSTI]

    Boyer, Edmond

    A Fully Biobased Epoxy Resin from Vegetable Oils: From the Synthesis of the Precursors by Thiol agent for bio-based epoxy resin. The thermal crosslinking reaction between AGSO and epoxi- dized linseed and thermal behav- iors. But, the substitution of bis-phenol A based epoxy resins by materials coming from

  12. The nature of quasistatic deformation in granular materials

    E-Print Network [OSTI]

    Jean-Noël Roux

    2009-01-15T23:59:59.000Z

    Strain in granular materials in quasistatic conditions under varying stress originate in (I) contact deformation and (II) rearrangements of the contact network. Depending on sample history and applied load, either mechanism might dominate. One may thus define rheological regimes I and II accordingly. Their properties are presented and illustrated here with discrete numerical simulation results on sphere packings. Understanding the microscopic physical origin of strain enables one to clarify such issues as the existence of macroscopic elasticity, the approach to stress-strain relations in the large system limit and the sensitivity to noise.

  13. Degrees in Metallurgy and Materials

    E-Print Network [OSTI]

    Birmingham, University of

    Degrees in Metallurgy and Materials Course outline School of Metallurgy and Materials Materials us? Dr Alessandro Mottura Undergraduate Admissions Tutor for Metallurgy and Materials What difference will you make? #12;Degrees in Metallurgy and Materials Understanding the properties of new materials

  14. Economic evaluation of closure cap barrier materials study

    SciTech Connect (OSTI)

    Serrato, M.G.; Bhutani, J.S.; Mead, S.M.

    1993-09-01T23:59:59.000Z

    Volume II of the Economic Evaluation of the Closure Cap Barrier Materials, Revision I contains detailed cost estimates for closure cap barrier materials. The cost estimates incorporate the life cycle costs for a generic hazardous waste seepage basin closure cap under the RCRA Post Closure Period of thirty years. The economic evaluation assessed six barrier material categories. Each of these categories consists of several composite cover system configurations, which were used to develop individual cost estimates. The information contained in this report is not intended to be used as a cost estimating manual. This information provides the decision makers with the ability to screen barrier materials, cover system configurations, and identify cost-effective materials for further consideration.

  15. Electrically conductive composite material

    DOE Patents [OSTI]

    Clough, R.L.; Sylwester, A.P.

    1989-05-23T23:59:59.000Z

    An electrically conductive composite material is disclosed which comprises a conductive open-celled, low density, microcellular carbon foam filled with a non-conductive polymer or resin. The composite material is prepared in a two-step process consisting of first preparing the microcellular carbon foam from a carbonizable polymer or copolymer using a phase separation process, then filling the carbon foam with the desired non-conductive polymer or resin. The electrically conductive composites of the present invention has a uniform and consistent pattern of filler distribution, and as a result is superior over prior art materials when used in battery components, electrodes, and the like. 2 figs.

  16. Electrically conductive composite material

    DOE Patents [OSTI]

    Clough, R.L.; Sylwester, A.P.

    1988-06-20T23:59:59.000Z

    An electrically conductive composite material is disclosed which comprises a conductive open-celled, low density, microcellular carbon foam filled with a non-conductive polymer or resin. The composite material is prepared in a two-step process consisting of first preparing the microcellular carbon foam from a carbonizable polymer or copolymer using a phase separation process, then filling the carbon foam with the desired non-conductive polymer or resin. The electrically conductive composites of the present invention has a uniform and consistent pattern of filler distribution, and as a result is superior over prior art materials when used in battery components, electrodes, and the like. 2 figs.

  17. Electrically conductive composite material

    DOE Patents [OSTI]

    Clough, Roger L. (Albuquerque, NM); Sylwester, Alan P. (Albuquerque, NM)

    1989-01-01T23:59:59.000Z

    An electrically conductive composite material is disclosed which comprises a conductive open-celled, low density, microcellular carbon foam filled with a non-conductive polymer or resin. The composite material is prepared in a two-step process consisting of first preparing the microcellular carbon foam from a carbonizable polymer or copolymer using a phase separation process, then filling the carbon foam with the desired non-conductive polymer or resin. The electrically conductive composites of the present invention has a uniform and consistant pattern of filler distribution, and as a result is superior over prior art materials when used in battery components, electrodes, and the like.

  18. Critical Materials Hub

    Broader source: Energy.gov [DOE]

    Critical materials, including some rare earth elements that possess unique magnetic, catalytic, and luminescent properties, are key resources needed to manufacture products for the clean energy economy. These materials are so critical to the technologies that enable wind turbines, solar panels, electric vehicles, and energy-efficient lighting that DOE's 2010 and 2011 Critical Materials Strategy reported that supply challenges for five rare earth metals—dysprosium, neodymium, terbium, europium, and yttrium—could affect clean energy technology deployment in the coming years.1, 2

  19. ATS materials/manufacturing

    SciTech Connect (OSTI)

    Karnitz, M.A.; Wright, I.G.; Ferber, M.K. [and others

    1997-11-01T23:59:59.000Z

    The Materials/Manufacturing Technology subelement is a part of the base technology portion of the Advanced Turbine Systems (ATS) Program. The work in this subelement is being performed predominantly by industry with assistance from national laboratories and universities. The projects in this subelement are aimed toward hastening the incorporation of new materials and components in gas turbines. Work is currently ongoing on thermal barrier coatings (TBCs), the scale-up of single crystal airfoil manufacturing technologies, materials characterization, and technology information exchange. This paper presents highlights of the activities during the past year. 12 refs., 24 figs., 4 tabs.

  20. Fissile material detector

    DOE Patents [OSTI]

    Ivanov, Alexander I. (Dubna, RU); Lushchikov, Vladislav I. (Dubna, RU); Shabalin, Eugeny P. (Dubna, RU); Maznyy, Nikita G. (Dubna, RU); Khvastunov, Michael M. (Dubna, RU); Rowland, Mark (Alamo, CA)

    2002-01-01T23:59:59.000Z

    A detector for fissile materials which provides for integrity monitoring of fissile materials and can be used for nondestructive assay to confirm the presence of a stable content of fissile material in items. The detector has a sample cavity large enough to enable assay of large items of arbitrary configuration, utilizes neutron sources fabricated in spatially extended shapes mounted on the endcaps of the sample cavity, incorporates a thermal neutron filter insert with reflector properties, and the electronics module includes a neutron multiplicity coincidence counter.

  1. Hydroxylation of p-substituted phenols by tyrosinase: Further insight into the mechanism of tyrosinase activity

    SciTech Connect (OSTI)

    Munoz-Munoz, Jose Luis [GENZ - Grupo de Investigacion Enzimologia, Departamento de Bioquimica y Biologia Molecular-A, Facultad de Biologia, Campus Internacional de Excelencia Campus Mare Nostrum, Universidad de Murcia, E-30100 Espinardo, Murcia (Spain)] [GENZ - Grupo de Investigacion Enzimologia, Departamento de Bioquimica y Biologia Molecular-A, Facultad de Biologia, Campus Internacional de Excelencia Campus Mare Nostrum, Universidad de Murcia, E-30100 Espinardo, Murcia (Spain); Berna, Jose [Grupo de Quimica Organica Sintetica, Departamento de Quimica Organica, Facultad de Quimica Campus Internacional de Excelencia Campus Mare Nostrum, Universidad de Murcia (Spain)] [Grupo de Quimica Organica Sintetica, Departamento de Quimica Organica, Facultad de Quimica Campus Internacional de Excelencia Campus Mare Nostrum, Universidad de Murcia (Spain); Garcia-Molina, Maria del Mar; Garcia-Molina, Francisco [GENZ - Grupo de Investigacion Enzimologia, Departamento de Bioquimica y Biologia Molecular-A, Facultad de Biologia, Campus Internacional de Excelencia Campus Mare Nostrum, Universidad de Murcia, E-30100 Espinardo, Murcia (Spain)] [GENZ - Grupo de Investigacion Enzimologia, Departamento de Bioquimica y Biologia Molecular-A, Facultad de Biologia, Campus Internacional de Excelencia Campus Mare Nostrum, Universidad de Murcia, E-30100 Espinardo, Murcia (Spain); Garcia-Ruiz, Pedro Antonio [QCPAI - Grupo de Quimica de Carbohidratos, Polimeros y Aditivos Industriales, Departamento de Quimica Organica, Facultad de Quimica Campus Internacional de Excelencia Campus Mare Nostrum, Universidad de Murcia (Spain)] [QCPAI - Grupo de Quimica de Carbohidratos, Polimeros y Aditivos Industriales, Departamento de Quimica Organica, Facultad de Quimica Campus Internacional de Excelencia Campus Mare Nostrum, Universidad de Murcia (Spain); Varon, Ramon [Departamento de Quimica-Fisica, Escuela de Ingenieros Industriales de Albacete, Universidad de Castilla la Mancha, Avda. Espana s/n. Campus Universitario, E-02071 Albacete (Spain)] [Departamento de Quimica-Fisica, Escuela de Ingenieros Industriales de Albacete, Universidad de Castilla la Mancha, Avda. Espana s/n. Campus Universitario, E-02071 Albacete (Spain); and others

    2012-07-27T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer The action the copper complexes and tyrosinase on phenols is equivalent. Black-Right-Pointing-Pointer Isotope effect showed that nucleophilic attack to copper atom may be the slower step. Black-Right-Pointing-Pointer The value of {rho} (Hammett constant) supports an electrophilic aromatic substitution. Black-Right-Pointing-Pointer Data obtained in steady state pH 7 conditions support the mechanism of Scheme 1SM. -- Abstract: A study of the monophenolase activity of tyrosinase by measuring the steady state rate with a group of p-substituted monophenols provides the following kinetic information: k{sub cat}{sup m} and the Michaelis constant, K{sub M}{sup m}. Analysis of these data taking into account chemical shifts of the carbon atom supporting the hydroxyl group ({delta}) and {sigma}{sub p}{sup +}, enables a mechanism to be proposed for the transformation of monophenols into o-diphenols, in which the first step is a nucleophilic attack on the copper atom on the form E{sub ox} (attack of the oxygen of the hydroxyl group of C-1 on the copper atom) followed by an electrophilic attack (attack of the hydroperoxide group on the ortho position with respect to the hydroxyl group of the benzene ring, electrophilic aromatic substitution with a reaction constant {rho} of -1.75). These steps show the same dependency on the electronic effect of the substituent groups in C-4. Furthermore, a study of a solvent deuterium isotope effect on the oxidation of monophenols by tyrosinase points to an appreciable isotopic effect. In a proton inventory study with a series of p-substituted phenols, the representation of k{sub cat}{sup f{sub n}}/k{sub cat}{sup f{sub 0}} against n (atom fractions of deuterium), where k{sub cat}{sup f{sub n}} is the catalytic constant for a molar fraction of deuterium (n) and k{sub cat}{sup f{sub 0}} is the corresponding kinetic parameter in a water solution, was linear for all substrates. These results indicate that only one of the proton transfer processes from the hydroxyl groups involved the catalytic cycle is responsible for the isotope effects. We suggest that this step is the proton transfer from the hydroxyl group of C-1 to the peroxide of the oxytyrosinase form (E{sub ox}). After the nucleophilic attack, the incorporation of the oxygen in the benzene ring occurs by means of an electrophilic aromatic substitution mechanism in which there is no isotopic effect.

  2. Materials at LANL

    SciTech Connect (OSTI)

    Taylor, Antoinette J [Los Alamos National Laboratory

    2010-01-01T23:59:59.000Z

    Exploring the physics, chemistry, and metallurgy of materials has been a primary focus of Los Alamos National Laboratory since its inception. In the early 1940s, very little was known or understood about plutonium, uranium, or their alloys. In addition, several new ionic, polymeric, and energetic materials with unique properties were needed in the development of nuclear weapons. As the Laboratory has evolved, and as missions in threat reduction, defense, energy, and meeting other emerging national challenges have been added, the role of materials science has expanded with the need for continued improvement in our understanding of the structure and properties of materials and in our ability to synthesize and process materials with unique characteristics. Materials science and engineering continues to be central to this Laboratory's success, and the materials capability truly spans the entire laboratory - touching upon numerous divisions and directorates and estimated to include >1/3 of the lab's technical staff. In 2006, Los Alamos and LANS LLC began to redefine our future, building upon the laboratory's established strengths and promoted by strongly interdependent science, technology and engineering capabilities. Eight Grand Challenges for Science were set forth as a technical framework for bridging across capabilities. Two of these grand challenges, Fundamental Understanding of Materials and Superconductivity and Actinide Science. were clearly materials-centric and were led out of our organizations. The complexity of these scientific thrusts was fleshed out through workshops involving cross-disciplinary teams. These teams refined the grand challenge concepts into actionable descriptions to be used as guidance for decisions like our LDRD strategic investment strategies and as the organizing basis for our external review process. In 2008, the Laboratory published 'Building the Future of Los Alamos. The Premier National Security Science Laboratory,' LA-UR-08-1541. This document introduced three strategic thrusts that crosscut the Grand Challenges and define future laboratory directions and facilities: (1) Information Science and Technology enabl ing integrative and predictive science; (2) Experimental science focused on materials for the future; and (3) Fundamental forensic science for nuclear, biological, and chemical threats. The next step for the Materials Capability was to develop a strategic plan for the second thrust, Materials for the Future. within the context of a capabilities-based Laboratory. This work has involved extending our 2006-2007 Grand Challenge workshops, integrating materials fundamental challenges into the MaRIE definition, and capitalizing on the emerging materials-centric national security missions. Strategic planning workshops with broad leadership and staff participation continued to hone our scientific directions and reinforce our strength through interdependence. By the Fall of 2008, these workshops promoted our primary strength as the delivery of Predictive Performance in applications where Extreme Environments dominate and where the discovery of Emergent Phenomena is a critical. These planning efforts were put into action through the development of our FY10 LDRD Strategic Investment Plan where the Materials Category was defined to incorporate three central thrusts: Prediction and Control of Performance, Extreme Environments and Emergent Phenomena. As with all strategic planning, much of the benefit is in the dialogue and cross-fertilization of ideas that occurs during the process. By winter of 2008/09, there was much agreement on the evolving focus for the Materials Strategy, but there was some lingering doubt over Prediction and Control of Performance as one of the three central thrusts, because it overarches all we do and is, truly, the end goal for materials science and engineering. Therefore, we elevated this thrust within the overarching vision/mission and introduce the concept of Defects and Interfaces as a central thrust that had previously been implied but not clearly articulated.

  3. Strontium Substitution for Calcium in Lithogenesis Sarah D. Blaschko, Thomas Chi, Joe Miller, Lawrence Flechner, Sirine Fakra,

    E-Print Network [OSTI]

    Strontium Substitution for Calcium in Lithogenesis Sarah D. Blaschko, Thomas Chi, Joe Miller, AK), Novato, California Purpose: Strontium has chemical similarity to calcium, which enables the replace- ment of calcium by strontium in biomineralization processes. Incorporating stron- tium into human

  4. Acta Cryst. (1994). D50, 749-756 High-Resolution Structures of Single-Metal-Substituted Concanavalin A

    E-Print Network [OSTI]

    -Metal-Substituted Concanavalin A: the Co,Ca-Protein at 1.6 ,~ and the Ni,Ca-Protein at 2.0 By C. EMMERICH,J. R. HELLIWELL,* M

  5. Explaining the increase of competitiveness in the Colombian car industry after the end of import substitution industralization [sic] policies

    E-Print Network [OSTI]

    Carrillo-Mora, Felipe, 1972-

    2003-01-01T23:59:59.000Z

    At the beginning of the decade of the nineties, Import Substitution Industrialization - ISI- policies were dismantled all over Latin America, including Colombia. This meant that tariff protection for locally produced ...

  6. Materials Science & Engineering

    E-Print Network [OSTI]

    . Aucierllo has edited 19 books, published about 450 articles, holds 14 patents, and has organized, chaired and nanocarbon thin films are providing the bases for new physics, new materials science and chemistry

  7. Microdrilling of Biocompatible Materials

    E-Print Network [OSTI]

    Mohanty, Sankalp

    2012-02-14T23:59:59.000Z

    This research studies microdrilling of biocompatible materials including commercially pure titanium, 316L stainless steel, polyether ether ketone (PEEK) and aluminum 6061-T6. A microdrilling technique that uses progressive pecking and micromist...

  8. Nuclear Material Packaging Manual

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2008-03-07T23:59:59.000Z

    The manual provides detailed packaging requirements for protecting workers from exposure to nuclear materials stored outside of an approved engineered contamination barrier. No cancellation. Certified 11-18-10.

  9. Critical Materials Workshop

    Broader source: Energy.gov [DOE]

    AMO hosted a public workshop on Tuesday, April 3, 2012 in Arlington, VA to provide background information on critical materials assessment, the current research within DOE related to critical...

  10. Management of Nuclear Materials

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1994-05-26T23:59:59.000Z

    To establish requirements and procedures for the management of nuclear materials within the Department of Energy (DOE). Cancels DOE 5660.1A. Canceled by DOE O 410.2.

  11. CRITICAL MATERIALS INSTITUTE PROJECTS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    INL Recovery of Critical Materials from Consumer Devices 3 3-2 3.2.6 McCall, Scott LLNL Additive Manufacturing of Permanent Magnets 2 2-1 2.1.2 McGuire, Michael ORNL...

  12. CRITICAL MATERIALS INSTITUTE PROJECTS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    INL National Technology Roadmap for Critical Materials 4 4-3 4.3.3 McCall, Scott LLNL Additive Manufacturing of Permanent Magnets 2 2-1 2.1.2 Payne, Steve LLNL New Efficient...

  13. MATERIALS SCIENCE HEALTHCARE POLICY

    E-Print Network [OSTI]

    Falge, Eva

    for Polymer Research are paving the way to optimizing organic substances for use in solar cells, light-emitting diodes and memory chips, and are using molecular materials to develop electronic components

  14. Electrically conductive material

    DOE Patents [OSTI]

    Singh, Jitendra P. (Bollingbrook, IL); Bosak, Andrea L. (Burnam, IL); McPheeters, Charles C. (Woodridge, IL); Dees, Dennis W. (Woodridge, IL)

    1993-01-01T23:59:59.000Z

    An electrically conductive material for use in solid oxide fuel cells, electrochemical sensors for combustion exhaust, and various other applications possesses increased fracture toughness over available materials, while affording the same electrical conductivity. One embodiment of the sintered electrically conductive material consists essentially of cubic ZrO.sub.2 as a matrix and 6-19 wt. % monoclinic ZrO.sub.2 formed from particles having an average size equal to or greater than about 0.23 microns. Another embodiment of the electrically conductive material consists essentially at cubic ZrO.sub.2 as a matrix and 10-30 wt. % partially stabilized zirconia (PSZ) formed from particles having an average size of approximately 3 microns.

  15. Electrically conductive material

    DOE Patents [OSTI]

    Singh, J.P.; Bosak, A.L.; McPheeters, C.C.; Dees, D.W.

    1993-09-07T23:59:59.000Z

    An electrically conductive material is described for use in solid oxide fuel cells, electrochemical sensors for combustion exhaust, and various other applications possesses increased fracture toughness over available materials, while affording the same electrical conductivity. One embodiment of the sintered electrically conductive material consists essentially of cubic ZrO[sub 2] as a matrix and 6-19 wt. % monoclinic ZrO[sub 2] formed from particles having an average size equal to or greater than about 0.23 microns. Another embodiment of the electrically conductive material consists essentially at cubic ZrO[sub 2] as a matrix and 10-30 wt. % partially stabilized zirconia (PSZ) formed from particles having an average size of approximately 3 microns. 8 figures.

  16. Management of Nuclear Materials

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2009-08-17T23:59:59.000Z

    To establish requirements for the lifecycle management of DOE owned and/or managed accountable nuclear materials. Cancels DOE O 410.2. Admin Chg 1 dated 4-10-2014, cancels DOE O 410.2.

  17. Nuclear material operations manual

    SciTech Connect (OSTI)

    Tyler, R.P.

    1981-02-01T23:59:59.000Z

    This manual provides a concise and comprehensive documentation of the operating procedures currently practiced at Sandia National Laboratories with regard to the management, control, and accountability of nuclear materials. The manual is divided into chapters which are devoted to the separate functions performed in nuclear material operations-management, control, accountability, and safeguards, and the final two chapters comprise a document which is also issued separately to provide a summary of the information and operating procedures relevant to custodians and users of radioactive and nuclear materials. The manual also contains samples of the forms utilized in carrying out nuclear material activities. To enhance the clarity of presentation, operating procedures are presented in the form of playscripts in which the responsible organizations and necessary actions are clearly delineated in a chronological fashion from the initiation of a transaction to its completion.

  18. Reversible hydrogen storage materials

    DOE Patents [OSTI]

    Ritter, James A. (Lexington, SC); Wang, Tao (Columbia, SC); Ebner, Armin D. (Lexington, SC); Holland, Charles E. (Cayce, SC)

    2012-04-10T23:59:59.000Z

    In accordance with the present disclosure, a process for synthesis of a complex hydride material for hydrogen storage is provided. The process includes mixing a borohydride with at least one additive agent and at least one catalyst and heating the mixture at a temperature of less than about 600.degree. C. and a pressure of H.sub.2 gas to form a complex hydride material. The complex hydride material comprises MAl.sub.xB.sub.yH.sub.z, wherein M is an alkali metal or group IIA metal, Al is the element aluminum, x is any number from 0 to 1, B is the element boron, y is a number from 0 to 13, and z is a number from 4 to 57 with the additive agent and catalyst still being present. The complex hydride material is capable of cyclic dehydrogenation and rehydrogenation and has a hydrogen capacity of at least about 4 weight percent.

  19. Nano-composite materials

    DOE Patents [OSTI]

    Lee, Se-Hee; Tracy, C. Edwin; Pitts, J. Roland

    2010-05-25T23:59:59.000Z

    Nano-composite materials are disclosed. An exemplary method of producing a nano-composite material may comprise co-sputtering a transition metal and a refractory metal in a reactive atmosphere. The method may also comprise co-depositing a transition metal and a refractory metal composite structure on a substrate. The method may further comprise thermally annealing the deposited transition metal and refractory metal composite structure in a reactive atmosphere.

  20. Piston actuated nastic materials

    E-Print Network [OSTI]

    Shah, Viral

    2009-05-15T23:59:59.000Z

    PISTON ACTUATED NASTIC MATERIALS A Thesis by VIRAL SHAH Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE December 2008... Major Subject: Mechanical Engineering PISTON ACTUATED NASTIC MATERIALS A Thesis by VIRAL SHAH Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER...

  1. Biomimetic hydrogel materials

    DOE Patents [OSTI]

    Bertozzi, Carolyn (Albany, CA); Mukkamala, Ravindranath (Houston, TX); Chen, Qing (Albany, CA); Hu, Hopin (Albuquerque, NM); Baude, Dominique (Creteil, FR)

    2000-01-01T23:59:59.000Z

    Novel biomimetic hydrogel materials and methods for their preparation. Hydrogels containing acrylamide-functionalized carbohydrate, sulfoxide, sulfide or sulfone copolymerized with a hydrophilic or hydrophobic copolymerizing material selected from the group consisting of an acrylamide, methacrylamide, acrylate, methacrylate, vinyl and a derivative thereof present in concentration from about 1 to about 99 wt %. and methods for their preparation. The method of use of the new hydrogels for fabrication of soft contact lenses and biomedical implants.

  2. Biomimetic Hydrogel Materials

    DOE Patents [OSTI]

    Bertozzi, Carolyn (Albany, CA), Mukkamala, Ravindranath (Houston, TX), Chen, Oing (Albany, CA), Hu, Hopin (Albuquerque, NM), Baude, Dominique (Creteil, FR)

    2003-04-22T23:59:59.000Z

    Novel biomimetic hydrogel materials and methods for their preparation. Hydrogels containing acrylamide-functionalized carbohydrate, sulfoxide, sulfide or sulfone copolymerized with a hydrophilic or hydrophobic copolymerizing material selected from the group consisting of an acrylamide, methacrylamide, acrylate, methacrylate, vinyl and a derivative thereof present in concentration from about 1 to about 99 wt %. and methods for their preparation. The method of use of the new hydrogels for fabrication of soft contact lenses and biomedical implants.

  3. Decommissioning of Experimental Breeder Reactor - II Complex, Post Sodium Draining

    SciTech Connect (OSTI)

    J. A. (Bart) Michelbacher; S. Paul Henslee; Collin J. Knight; Steven R. sherman

    2005-09-01T23:59:59.000Z

    The Experimental Breeder Reactor - II (EBR-II) was shutdown in September 1994 as mandated by the United States Department of Energy. This sodium-cooled reactor had been in service since 1964. The bulk sodium was drained from the primary and secondary systems and processed. Residual sodium remaining in the systems after draining was converted into sodium bicarbonate using humid carbon dioxide. This technique was tested at Argonne National Laboratory in Illinois under controlled conditions, then demonstrated on a larger scale by treating residual sodium within the EBR-II secondary cooling system, followed by the primary tank. This process, terminated in 2002, was used to place a layer of sodium bicarbonate over all exposed surfaces of sodium. Treatment of the remaining EBR-II sodium is governed by the Resource Conservation and Recovery Act (RCRA). The Idaho Department of Environmental Quality issued a RCRA Operating Permit in 2002, mandating that all hazardous materials be removed from EBR-II within a 10 year period, with the ability to extend the permit and treatment period for another 10 years. A preliminary plan has been formulated to remove the remaining sodium and NaK from the primary and secondary systems using moist carbon dioxide, steam and nitrogen, and a water flush. The moist carbon dioxide treatment was resumed in May 2004. As of August 2005, approximately 60% of the residual sodium within the EBR-II primary tank had been treated. This process will continue through the end of 2005, when it is forecast that the process will become increasingly ineffective. At that time, subsequent treatment processes will be planned and initiated. It should be noted that the processes and anticipated costs associated with these processes are preliminary. Detailed engineering has not been performed, and approval for these methods has not been obtained from the regulator or the sponsors.

  4. Nanostructured Materials for Energy Generation and Storage

    E-Print Network [OSTI]

    Khan, Javed Miller

    2012-01-01T23:59:59.000Z

    xi Material CharacterizationThermoelectric Materials . . . . . . . . Graphene-Like5 Nanostructured Materials for Electrochemical Energy

  5. Microwave impregnation of porous materials with thermal energy storage materials

    DOE Patents [OSTI]

    Benson, David K. (Golden, CO); Burrows, Richard W. (Conifer, CO)

    1993-01-01T23:59:59.000Z

    A method for impregnating a porous, non-metallic construction material with a solid phase-change material is described. The phase-change material in finely divided form is spread onto the surface of the porous material, after which the porous material is exposed to microwave energy for a time sufficient to melt the phase-change material. The melted material is spontaneously absorbed into the pores of the porous material. A sealing chemical may also be included with the phase-change material (or applied subsequent to the phase-change material) to seal the surface of the porous material. Fire retardant chemicals may also be included with the phase-change materials. The treated construction materials are better able to absorb thermal energy and exhibit increased heat storage capacity.

  6. Microwave impregnation of porous materials with thermal energy storage materials

    DOE Patents [OSTI]

    Benson, D.K.; Burrows, R.W.

    1993-04-13T23:59:59.000Z

    A method for impregnating a porous, non-metallic construction material with a solid phase-change material is described. The phase-change material in finely divided form is spread onto the surface of the porous material, after which the porous material is exposed to microwave energy for a time sufficient to melt the phase-change material. The melted material is spontaneously absorbed into the pores of the porous material. A sealing chemical may also be included with the phase-change material (or applied subsequent to the phase-change material) to seal the surface of the porous material. Fire retardant chemicals may also be included with the phase-change materials. The treated construction materials are better able to absorb thermal energy and exhibit increased heat storage capacity.

  7. BUILDING MATERIALS RECLAMATION PROGRAM

    SciTech Connect (OSTI)

    David C. Weggel; Shen-En Chen; Helene Hilger; Fabien Besnard; Tara Cavalline; Brett Tempest; Adam Alvey; Madeleine Grimmer; Rebecca Turner

    2010-08-31T23:59:59.000Z

    This report describes work conducted on the Building Materials Reclamation Program for the period of September 2008 to August 2010. The goals of the project included selecting materials from the local construction and demolition (C&D) waste stream and developing economically viable reprocessing, reuse or recycling schemes to divert them from landfill storage. Educational resources as well as conceptual designs and engineering feasibility demonstrations were provided for various aspects of the work. The project was divided into two distinct phases: Research and Engineering Feasibility and Dissemination. In the Research Phase, a literature review was initiated and data collection commenced, an advisory panel was organized, and research was conducted to evaluate high volume C&D materials for nontraditional use; five materials were selected for more detailed investigations. In the Engineering Feasibility and Dissemination Phase, a conceptual study for a regional (Mecklenburg and surrounding counties) collection and sorting facility was performed, an engineering feasibility project to demonstrate the viability of recycling or reuse schemes was created, the literature review was extended and completed, and pedagogical materials were developed. Over the two-year duration of the project, all of the tasks and subtasks outlined in the original project proposal have been completed. The Final Progress Report, which briefly describes actual project accomplishments versus the tasks/subtasks of the original project proposal, is included in Appendix A of this report. This report describes the scientific/technical aspects (hypotheses, research/testing, and findings) of six subprojects that investigated five common C&D materials. Table 1 summarizes the six subprojects, including the C&D material studied and the graduate student and the faculty advisor on each subproject.

  8. Termination of Safeguards on ULWBR Material

    SciTech Connect (OSTI)

    Ivan R. Thomas; Ernest L. Laible

    2008-07-01T23:59:59.000Z

    The Department of Energy (DOE), Office of Environmental Management, has approved the disposition of 31 metric tons of Unirradiated Light Water Breeder Reactor (ULWBR) material in canisters stored within dry wells of the Underground Fuel Storage Facility at the Idaho Nuclear Technology and Engineering Center (INTEC). This unirradiated material consists primarily of ceramic pellets of thorium oxide in stainless steel cladding, but it also contains 300 kilograms of uranium that is 98 wt% U-233. The ULWBR material was not processed at the INTEC because it was incompatible with prior chemical separation schemes. Other economical recovery options have not been identified, and expressions of interest for consolidating the material with existing projects at other DOE sites have not been received. The U-233 could be used for producing the medical isotope Actinium-225, but the proof-of-principle demonstration and follow-on pilot program have not been developed to the point of requiring production quantities of U-233. Consequently, the selected disposition of the ULWBR material was burial as Low Level Waste at the Nevada Test Site (NTS), which required terminating safeguards controls for the contained Category II quantity of Attractiveness Level D special nuclear material (SNM). The requested termination followed the twelve point evaluation criteria of the Historical Defense Program Discard Guidance and included a security analysis for evaluating the risks of theft, diversion, and radiological sabotage associated with the material. Continuity of knowledge in the book inventory was assured by documenting that the original shipper’s measurements accurately reflected the quantities of materials received and that the ULWBR materials had remained under adequate physical protection and had been subject to periodic physical inventories. The method selected for substantiating the book values as the basis for terminating safeguards was the nondestructive assay used during physical inventories. Shipping arrangements included refurbishing a licensed cask to be reused over the duration of the termination process. An accompanying batching plan and shipping schedule were developed to accommodate multiple commercial shipments of Category III quantities of SNM in the selected cask, such that all canisters would be received at NTS prior to the expiration of the nonrenewable cask license.

  9. Improvements in electrical and dielectric properties of substituted multiferroic LaMnO{sub 3} based nanostructures synthesized by co-precipitation method

    SciTech Connect (OSTI)

    Mahmood, Azhar [Chemistry Department, Baghdad-ul-Jaded Campus, The Islamia University of Bahawalpur, Bahawalpur 63100 (Pakistan)] [Chemistry Department, Baghdad-ul-Jaded Campus, The Islamia University of Bahawalpur, Bahawalpur 63100 (Pakistan); Warsi, Muhammad Farooq, E-mail: Farooq.warsi@iub.edu.pk [Chemistry Department, Baghdad-ul-Jaded Campus, The Islamia University of Bahawalpur, Bahawalpur 63100 (Pakistan); Ashiq, Muhammad Naeem [Department of Chemistry, Bahauddin Zakaryia University of Multan-60000 (Pakistan)] [Department of Chemistry, Bahauddin Zakaryia University of Multan-60000 (Pakistan); Sher, Muhammad [Chemistry Department, The University of Sargodha, Sargodha 40100 (Pakistan)] [Chemistry Department, The University of Sargodha, Sargodha 40100 (Pakistan)

    2012-12-15T23:59:59.000Z

    Graphical abstract: Display Omitted Highlights: ? Simultaneous double ion substitutions philosophy is introduced in LaMnO{sub 3}. ? La{sub 1?x}Gd{sub x}Mn{sub 1?y}Cr{sub y}O{sub 3} nanoparticles are not reported previously. ? La{sub 1?x}Gd{sub x}Mn{sub 1?y}Cr{sub y}O{sub 3} nanoparticles are synthesized by co-precipitation method. ? The 12 fold increase in resistivity of LaMnO{sub 3} nanostructures is observed. -- Abstract: A series of La{sub 1?x}Gd{sub x}Mn{sub 1?y}Cr{sub y}O{sub 3} nanoparticles (where x, y = 0, 0.25, 0.50, 0.75 and 1.0) has been synthesized by the chemical co-precipitation method, involving double ion substitution philosophy. The nanoparticles were characterized by thermo gravimetric analysis (TGA), X-ray fluorescence spectrometry (XRF), X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, vibrating sample magnetometer (VSM), DC electrical resistivity and dielectric measurements. The XRD and FTIR analysis confirmed the single orthorhombic phase and the crystallite size were found in the range of 16–34 nm. DC resistivity exhibited very interesting behavior which increased from 1.41 × 10{sup 8} to 16.35 ± 0.2 × 10{sup 8} ? cm upon complete double ions replacement of La and Mn with Gd and Cr, respectively. This very high resistivity variation upon substitution definitely would open new avenues for applications of these materials in microwave devices and other related areas. The dielectric properties of these nanoparticles were also studied at room temperature in the range of 6 kHz to 5 MHz and the maximum dielectric behavior (?? = 2.86 × 10{sup 3}, tan ? = 5.41, ?? = 15.5 × 10{sup 3}) was exhibited by La{sub 0.75}Gd{sub 0.25}Mn{sub 0.75}Cr{sub 0.25}O{sub 3} at 6 kHz. Hysteresis loops measurements showed that the synthesized nanomaterials are paramagnetic in nature at room temperature.

  10. Separation and recovery process R&D to enhance automotive materials recycling

    SciTech Connect (OSTI)

    Daniels, E.J.

    1994-05-01T23:59:59.000Z

    Since 1976, the sales-weighted curb-weight of cars and light trucks sold in the United States has decreased by almost 800 pounds. Vehicle weight reduction has, of course, provided for a significant increase in US fleet fuel economy, from 17 to 27 miles per gallon. However, achievement of the weight reduction and concomitant increase in fuel economy was brought about, in part, by the substitution of lighter-weight materials, such as thinner-gauge coated sheet-steels replacing heavy-gauge noncoated sheet-steels and new aluminum alloys replacing steel as well as the increased use of plastics replacing metals. Each of these new materials has created the need for new technology for materials recycling. This paper highlights some of the R&D being conducted at Argonne National Laboratory to develop technology that will enhance and minimize the cost of automotive materials recycling.

  11. Cyanide clusters of ReII with 3d metal ions and their magnetic properties: incorporating anisotropic ions into metal-cyanide clusters with high spin magnetic ground states

    E-Print Network [OSTI]

    Schelter, Eric John

    2005-08-29T23:59:59.000Z

    B. Synthesis of Re-triphos Compounds????????.. 33 1. II(triphos)(CH3CN)3][BF4]2 (1)??????. 33 2. [(triphos)ReII(? -Cl)3ReII(triphos)]Cl (2)................. 34 3. (triphos)ReI(? -Cl)3ReII(triphos) (3.... Experimental Section????...................................................... 74 A. Starting Materials??........................................................ 74 B. Synthesis of Molecular Cubes of Re4Mn4, Re4Fe4, Re 4Co4...

  12. Porous material neutron detector

    DOE Patents [OSTI]

    Diawara, Yacouba (Oak Ridge, TN); Kocsis, Menyhert (Venon, FR)

    2012-04-10T23:59:59.000Z

    A neutron detector employs a porous material layer including pores between nanoparticles. The composition of the nanoparticles is selected to cause emission of electrons upon detection of a neutron. The nanoparticles have a maximum dimension that is in the range from 0.1 micron to 1 millimeter, and can be sintered with pores thereamongst. A passing radiation generates electrons at one or more nanoparticles, some of which are scattered into a pore and directed toward a direction opposite to the applied electrical field. These electrons travel through the pore and collide with additional nanoparticles, which generate more electrons. The electrons are amplified in a cascade reaction that occurs along the pores behind the initial detection point. An electron amplification device may be placed behind the porous material layer to further amplify the electrons exiting the porous material layer.

  13. Apparatus for dispensing material

    DOE Patents [OSTI]

    Sutter, Peter Werner (Beach, NY); Sutter, Eli Anguelova (Beach, NY)

    2011-07-05T23:59:59.000Z

    An apparatus capable of dispensing drops of material with volumes on the order of zeptoliters is described. In some embodiments of the inventive pipette the size of the droplets so dispensed is determined by the size of a hole, or channel, through a carbon shell encapsulating a reservoir that contains material to be dispensed. The channel may be formed by irradiation with an electron beam or other high-energy beam capable of focusing to a spot size less than about 5 nanometers. In some embodiments, the dispensed droplet remains attached to the pipette by a small thread of material, an atomic scale meniscus, forming a virtually free-standing droplet. In some embodiments the droplet may wet the pipette tip and take on attributes of supported drops. Methods for fabricating and using the pipette are also described.

  14. Optimized nanoporous materials.

    SciTech Connect (OSTI)

    Braun, Paul V. (University of Illinois at Urbana-Champaign, Urbana, IL); Langham, Mary Elizabeth; Jacobs, Benjamin W.; Ong, Markus D.; Narayan, Roger J. (North Carolina State University, Raleigh, NC); Pierson, Bonnie E. (North Carolina State University, Raleigh, NC); Gittard, Shaun D. (North Carolina State University, Raleigh, NC); Robinson, David B.; Ham, Sung-Kyoung (Korea Basic Science Institute, Gangneung, South Korea); Chae, Weon-Sik (Korea Basic Science Institute, Gangneung, South Korea); Gough, Dara V. (University of Illinois at Urbana-Champaign, Urbana, IL); Wu, Chung-An Max; Ha, Cindy M.; Tran, Kim L.

    2009-09-01T23:59:59.000Z

    Nanoporous materials have maximum practical surface areas for electrical charge storage; every point in an electrode is within a few atoms of an interface at which charge can be stored. Metal-electrolyte interfaces make best use of surface area in porous materials. However, ion transport through long, narrow pores is slow. We seek to understand and optimize the tradeoff between capacity and transport. Modeling and measurements of nanoporous gold electrodes has allowed us to determine design principles, including the fact that these materials can deplete salt from the electrolyte, increasing resistance. We have developed fabrication techniques to demonstrate architectures inspired by these principles that may overcome identified obstacles. A key concept is that electrodes should be as close together as possible; this is likely to involve an interpenetrating pore structure. However, this may prove extremely challenging to fabricate at the finest scales; a hierarchically porous structure can be a worthy compromise.

  15. Packaging and Transfer of Hazardous Materials and Materials of...

    Broader source: Energy.gov (indexed) [DOE]

    PACKAGING AND TRANSFER OF HAZARDOUS MATERIALS AND MATERIALS OF NATIONAL SECURITY INTEREST Assessment Plan NNSANevada Site Office Facility Representative Division Performance...

  16. Quantitative solubility-structure relationships for some meta- and para-substituted benzoic acids

    E-Print Network [OSTI]

    Pawlowski, John Norman

    1963-01-01T23:59:59.000Z

    are due to Mr. J 0 ~ Schreck and Mr. J. S. Xdoux for their interest~ This study was supported in part by a research grant from the Robert A. Welch Foundation. The author is indebted to the Data Processing Center of Texas A 6 M College for the numerfcal... by John Norman Pawloski The solubilities of benzoic acid and of 16 m- and p- substituted ben4oic acids have been determined at 30 C in benzene and in cyc1ohexane and are reported as: (1) mole fraction of solutei (2) mole ratio of solute, and (3) grams...

  17. Nanomechanical and nanotribological properties of Nb substituted TiN thin films

    SciTech Connect (OSTI)

    Krishna, M. Ghanashyam; Vasu, K.; Padmanabhan, K. A. [School of Physics, Centre for Nanotechnology, University of Hyderabad, Hyderabad-500 046 (India); Centre for Nanotechnology, School of Engineering Sciences and Technology, University of Hyderabad, Hyderabad-500 046 (India)

    2012-06-25T23:59:59.000Z

    Nanomechanical and nanotribological properties of Ti{sub 1-x}Nb{sub x}N (0{<=}x{<=}1) thin films were investigated as a function x. The films were deposited onto polycrystalline nuclear grade 316LN stainless steel (SS) substrate by radio frequency magnetron sputtering in 100% N{sub 2} plasma. The hardness and Young's modulus increased while the friction coefficient and wear volume decreased with increasing Nb substitution. The highest hardness achieved was 31GPa for x=0.77. At the same Nb concentration, the friction coefficient was 0.15 and the elastic recovery was 60%.

  18. Deterrence of device counterfeiting, cloning, and subversion by substitution using hardware fingerprinting

    DOE Patents [OSTI]

    Hamlet, Jason R; Bauer, Todd M; Pierson, Lyndon G

    2014-09-30T23:59:59.000Z

    Deterrence of device subversion by substitution may be achieved by including a cryptographic fingerprint unit within a computing device for authenticating a hardware platform of the computing device. The cryptographic fingerprint unit includes a physically unclonable function ("PUF") circuit disposed in or on the hardware platform. The PUF circuit is used to generate a PUF value. A key generator is coupled to generate a private key and a public key based on the PUF value while a decryptor is coupled to receive an authentication challenge posed to the computing device and encrypted with the public key and coupled to output a response to the authentication challenge decrypted with the private key.

  19. MATERIAL CONTROL ACCOUNTING INMM

    SciTech Connect (OSTI)

    Hasty, T.

    2009-06-14T23:59:59.000Z

    Since 1996, the Mining and Chemical Combine (MCC - formerly known as K-26), and the United States Department of Energy (DOE) have been cooperating under the cooperative Nuclear Material Protection, Control and Accounting (MPC&A) Program between the Russian Federation and the U.S. Governments. Since MCC continues to operate a reactor for steam and electricity production for the site and city of Zheleznogorsk which results in production of the weapons grade plutonium, one of the goals of the MPC&A program is to support implementation of an expanded comprehensive nuclear material control and accounting (MC&A) program. To date MCC has completed upgrades identified in the initial gap analysis and documented in the site MC&A Plan and is implementing additional upgrades identified during an update to the gap analysis. The scope of these upgrades includes implementation of MCC organization structure relating to MC&A, establishing material balance area structure for special nuclear materials (SNM) storage and bulk processing areas, and material control functions including SNM portal monitors at target locations. Material accounting function upgrades include enhancements in the conduct of physical inventories, limit of error inventory difference procedure enhancements, implementation of basic computerized accounting system for four SNM storage areas, implementation of measurement equipment for improved accountability reporting, and both new and revised site-level MC&A procedures. This paper will discuss the implementation of MC&A upgrades at MCC based on the requirements established in the comprehensive MC&A plan developed by the Mining and Chemical Combine as part of the MPC&A Program.

  20. The Sun -II Alexei Gilchrist

    E-Print Network [OSTI]

    Wardle, Mark

    The Sun - II Alexei Gilchrist #12;Some resources · http://www.nineplanets.org/sol.html · "The Universe: Secrets of the Sun" video ­ Search on youtube (references are to clips here http in these slides Secrets of the Sun #12;Why does the sun shine? Long and fascinating history involving - geology

  1. Robotics II June 10, 2014

    E-Print Network [OSTI]

    De Luca, Alessandro

    Robotics II June 10, 2014 Exercise 1 Consider a planar 3R robot with unitary link lengths as in Fig. 1. Taking into account the robot redundancy, a velocity control scheme is active so as to track desired end-effector position trajectories while trying to locally maximize the minimum Cartesian distance

  2. Materials for geothermal production

    SciTech Connect (OSTI)

    Kukacka, L.E.

    1992-01-01T23:59:59.000Z

    Advances in the development of new materials continue to be made in the geothermal materials project. Many successes have already been accrued and the results used commercially. In FY 1991, work was focused on reducing well drilling, fluid transport and energy conversion costs. Specific activities performed included lightweight CO{sub 2}-resistant well cements, thermally conductive and scale resistant protective liner systems, chemical systems for lost circulation control, corrosion mitigation in process components at The Geysers, and elastomer-metal bonding systems. Efforts to transfer the technologies developed in these efforts to other energy-related sectors of the economy continued and considerable success was achieved.

  3. Materials Under Extremes | ORNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment Surfaces andMapping the Nanoscale LandscapeImports 5.90Materials Porous Materials

  4. Materials at the Mesoscale

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recovery challenge fund LasDubey selectedContract ResearchMaterials andMaterials

  5. Materials for the Future

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recovery challenge fund LasDubey selectedContract ResearchMaterialsMaterials for

  6. Container for radioactive materials

    DOE Patents [OSTI]

    Fields, S.R.

    1984-05-30T23:59:59.000Z

    A container is claimed for housing a plurality of canister assemblies containing radioactive material. The several canister assemblies are stacked in a longitudinally spaced relation within a carrier to form a payload concentrically mounted within the container. The payload package includes a spacer for each canister assembly, said spacer comprising a base member longitudinally spacing adjacent canister assemblies from each other and sleeve surrounding the associated canister assembly for centering the same and conducting heat from the radioactive material in a desired flow path. 7 figures.

  7. Short courses in Composite Materials

    E-Print Network [OSTI]

    Davies, John N.

    Short courses in Composite Materials Overview The ability to tailor the material properties used. Combining the adaptability of composites with clear weight savings, whilst tailoring materials properties Airbus and Glyndr University, the Advanced Composites Training and Development Centre educates current

  8. PARS II Process Document - Project Phasing | Department of Energy

    Energy Savers [EERE]

    PARS II Process Document - Project Phasing.pdf More Documents & Publications Proposed Data Elements for PARS II Web Application Slide 1 PARS II Standard Operating Procedure (SOP)...

  9. Proposed Data Elements for PARS II Web Application | Department...

    Broader source: Energy.gov (indexed) [DOE]

    Proposed Data Elements for PARS II Web Application Proposed Data Elements for PARS II Web Application Proposed Data Elements for PARS II Web Application More Documents &...

  10. PARS II - Integrated Project Team Meeting | Department of Energy

    Energy Savers [EERE]

    Meeting PARS II - Integrated Project Team Meeting More Documents & Publications PARS II 104 Contractor Monthly Upload Proposed Data Elements for PARS II Web Application Slide 1...

  11. Supercapacitors specialities - Materials review

    SciTech Connect (OSTI)

    Obreja, Vasile V. N. [National Research and Development Institute for Microtechnologies (IMT-Bucuresti), Bucharest, 126A Erou Iancu Nicolae Street, 077190 (Romania)

    2014-06-16T23:59:59.000Z

    The electrode material is a key component for supercapacitor cell performance. As it is known, performance comparison of commercial available batteries and supercapacitors reveals significantly lower energy storage capability for supercapacitor devices. The energy density of commercial supercapacitor cells is limited to 10 Wh/kg whereas that of common lead acid batteries reaches 35-40 Wh/kg. For lithium ion batteries a value higher than 100 Wh/kg is easily available. Nevertheless, supercapacitors also known as ultracapacitors or electrochemical capacitors have other advantages in comparison with batteries. As a consequence, many efforts have been made in the last years to increase the storage energy density of electrochemical capacitors. A lot of results from published work (research and review papers, patents and reports) are available at this time. The purpose of this review is a presentation of the progress to date for the use of new materials and approaches for supercapacitor electrodes, with focus on the energy storage capability for practical applications. Many reported results refer to nanostructured carbon based materials and the related composites, used for the manufacture of experimental electrodes. A specific capacitance and a specific energy are seldom revealed as the main result of the performed investigation. Thus for nanoprous (activated) carbon based electrodes a specific capacitance up to 200-220 F/g is mentioned for organic electrolyte, whereas for aqueous electrolyte, the value is limited to 400-500 F/g. Significant contribution to specific capacitance is possible from fast faradaic reactions at the electrode-electrolyte interface in addition to the electric double layer effect. The corresponding energy density is limited to 30-50 Wh/kg for organic electrolyte and to 12-17 Wh/kg for aqueous electrolyte. However such performance indicators are given only for the carbon material used in electrodes. For a supercapacitor cell, where two electrodes and also other materials for cell assembling and packaging are used, the above mentioned values have to be divided by a factor higher than four. As a consequence, the specific energy of a prototype cell, hardly could exceed 10 Wh/kg because of difficulties with the existing manufacturing technology. Graphene based materials and carbon nanotubes and different composites have been used in many experiments reported in the last years. Nevertheless in spite of the outstanding properties of these materials, significant increase of the specific capacitance or of the specific energy in comparison with activated or nanoporous carbon is not achieved. Use of redox materials as metal oxides or conducting polymers in combination with different nanostructured carbon materials (nanocomposite electrodes) has been found to contribute to further increase of the specific capacitance or of the specific energy. Nevertheless, few results are reported for practical cells with such materials. Many results are reported only for a three electrode system and significant difference is possible when the electrode is used in a practical supercapacitor cell. Further improvement in the electrode manufacture and more experiments with supercapacitor cells with the known electrochemical storage materials are required. Device prototypes and commercial products with an energy density towards 15-20 Wh/kg could be realized. These may be a milestone for further supercapacitor device research and development, to narrow the storage energy gap between batteries and supercapacitors.

  12. Revising Selected Written Patient Education Materials Through Readability and Concreteness

    E-Print Network [OSTI]

    Goolsby, Rhonda Denise

    2011-10-21T23:59:59.000Z

    education materials differ in reported level of frequency of breast self-exams (BSEs) and reported level of confidence in performing BSEs? 5 CHAPTER II REVIEW OF LITERATURE This chapter consists of a comprehensive overview of the literature... participants). One participant of the 76 had experience with finding noncancerous lumps in the breast. All other participants had no experience with breast cancer. The participants in this study were enrolled in an undergraduate education class. This sample...

  13. Microstructural Characterization of Material Properties and Damage in Asphalt Composites

    E-Print Network [OSTI]

    Mohammad Khorasani, Sara

    2013-05-03T23:59:59.000Z

    MICROSTRUCTURAL CHARACTERIZATION OF MATERIAL PROPERTIES AND DAMAGE IN ASPHALT COMPOSITES A Thesis by SARA MOHAMMAD KHORASANI Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... Engineering Copyright 2013 Sara Mohammad Khorasani ii ABSTRACT Asphalt composites are used to construct 90% of roads in the United States. These composites consist of asphalt binder, which is a product of the refinery process of oil, aggregates...

  14. New Manufacturing Method for Paper filler and Fiber Material

    SciTech Connect (OSTI)

    Doelle, Klaus

    2011-11-22T23:59:59.000Z

    The study compares commercial available filler products with a new developed â??Hybrid Fiber Filler Composite Materialâ?ť and how main structural, optical and strength properties are affected by increasing the filler content of at least 5% over commercial values. The study consists of: (i) an overview of paper filler materials used in the paper production process, (ii) discusses the manufacturing technology of lime based filler materials for paper applications, (iii) gives an overview of new emerging paper filler technologies, (iv) discusses a filler evaluation of commercial available digital printing paper products, (v) reports from a detailed handsheet study and 12â?ť pilot plant paper machine trial runs with the new Hybrid Fiber Filler Composite Material, and (vi) evaluates and compares commercial filler products and the new Hybrid Fiber Filler Composite Material with a life cycle analyses that explains manufacturing, economic and environmental benefits as they are applied to uncoated digital printing papers.

  15. Shear zone refraction and deflection in layered granular materials

    E-Print Network [OSTI]

    Tamas Borzsonyi; Tamas Unger; Balazs Szabo

    2009-12-09T23:59:59.000Z

    Refraction and deflection of shear zones in layered granular materials was studied experimentally and numerically. We show, that (i) according to a recent theoretical prediction [T. Unger, Phys. Rev. Lett. 98, 018301 (2007)] shear zones refract in layered systems in analogy with light refraction, (ii) zone refraction obeys Snell's law known from geometric optics and (iii) under natural pressure conditions (i.e. in the presence of gravity) the zone can also be deflected by the interface so that the deformation of the high friction material is avoided.

  16. Part II: Project Summaries Project Summaries

    E-Print Network [OSTI]

    Perkins, Richard A.

    Part II: Project Summaries Part II Project Summaries #12 generally cannot be achieved for reasonable computational cost. Applications that require modeling, and in nondestructive testing. The objective of this project is to advance the state of the art in electromagnetic

  17. PARS II Training Schedule | Department of Energy

    Office of Environmental Management (EM)

    will certify that user to receive a PARS II user account. PARSIITrainingSchedule03-06-2014.pdf More Documents & Publications Slide 1 Slide 1 PARS II Course Registration Form...

  18. Swift Progress on NSLS-II Booster

    ScienceCinema (OSTI)

    None

    2013-07-17T23:59:59.000Z

    Get an inside look around the booster ring at the National Synchrotron Light Source II. The booster is part of the injector complex for NSLS-II, now under construction at Brookhaven Lab.

  19. Vibrational Damping of Composite Materials

    E-Print Network [OSTI]

    Biggerstaff, Janet M.

    2006-01-01T23:59:59.000Z

    the damping material and epoxy resin. The surface of theinfiltration of the epoxy resin into the damping materialthe damping material and resin (epoxy) is occurring and is

  20. Materials and Manufacturing

    E-Print Network [OSTI]

    Environmental Assurance Anne Meinhold Unprecedented Accomplishments in the Use of Aluminum-Lithium Alloy Preston is the solution. Other times, the design must accommodate the limitations of materials properties. The design requirements, and written procedures. Nondestructive testing depends on incident or input energy that interacts

  1. Supplemental Material Supplemental methods

    E-Print Network [OSTI]

    Tsien, Roger Y.

    Material (ESI) for Integrative Biology This journal is © The Royal Society of Chemistry 2009 #12;Computing counter and % ID/g calculated as (counts/weight tissue)/ total counts injected. Mass Spectrometry. To extract ACPPs to obtain electrospray (ESI) mass spectra, a solution of 9M guanidinium chloride (Gu

  2. Materials Safety Data Sheets

    E-Print Network [OSTI]

    Schweik, Charles M.

    Materials Safety Data Sheets (MSDS) MSDS contain chemical hazard information about substances compounds and solvents. MSDS data can be accessed from the following URLs http://www.ehs.umass.edu/ http://www.chem.umass.edu/Safety the "Important Safety Sites for the University" link to reach a variety of safety related information, including

  3. NMR imaging of materials

    SciTech Connect (OSTI)

    Listerud, J.M.; Sinton, S.W.; Drobny, G.P.

    1989-01-01T23:59:59.000Z

    Interest in the area of NMR imaging has been driven by the widespread success of medical imaging. John M. Listerud of the Pendergrass Diagnostic Research Laboratories, Steven W. Sinton of Lockheed, and Gary P. Drobny of the University of Washington describe the principal image reconstruction methods, factors limiting spatial resolution, and applications of imaging to the study of materials.

  4. Sustainable Materials Course Outline

    E-Print Network [OSTI]

    New South Wales, University of

    , embodied energy; environmental footprint, waste recycling and pollution minimization, life cycle assessment Science and Engineering (Building E8) Phone: 9385 5025 j.q.zhang@unsw.edu.au Consultation hours: by appointment To be advised School of Materials Science and Engineering (Building E8) Consultation hours

  5. Action Plan Materials Science

    E-Print Network [OSTI]

    Fitze, Patrick

    sense, including all strata) has available to it a wide range of con- venient products which improve, improving companies' pros- pects and generating wealth without harming the environment. And allAction Plan 2010-2013 Materials Science Area EXECUTIVE SUMMARY #12;N.B.: If you require any further

  6. Geothermal Materials Development. Annual report FY 1991

    SciTech Connect (OSTI)

    Kukacka, L.E.

    1991-12-01T23:59:59.000Z

    Advances in the development of new materials, the commercial availabilities of which are essential for the attainment of Hydrothermal Category Level I and II Objectives, continue to be made in the Geothermal Materials Development Project. Many successes have already been accrued and the results used commercially. In FY 1991, utility company sponsored ``full cost`` recovery programs based upon materials technology developed in this project were initiated on topics such as condensing heat exchangers, high temperature composites for utility vaults used in district heating systems, and corrosion resistant coatings for use in oil-fired electric generating processes. In FY 1991 the DOE/GD-sponsored R&D project was focused on reducing well drilling, fluid transport and energy conversion costs. Specific activities being performed included lightweight CO{sub 2}- resistant well cements, chemical systems for lost circulation control, thermally conductive and scale resistant protective linear systems, corrosion mitigation in process components at The Geysers, and elastomer-metal bonding systems needed for use in high temperature well drilling and safety related applications.

  7. Geothermal Materials Development, Annual Report FY 1991

    SciTech Connect (OSTI)

    Kukacka, L.E.

    1991-12-01T23:59:59.000Z

    Advances in the development of new materials, the commercial availabilities of which are essential for the attainment of Hydrothermal Category Level I and II Objectives, continue to be made in the Geothermal Materials Development Project. Many successes have already been accrued and the results used commercially. In FY 1991, utility company sponsored full cost'' recovery programs based upon materials technology developed in this project were initiated on topics such as condensing heat exchangers, high temperature composites for utility vaults used in district heating systems, and corrosion resistant coatings for use in oil-fired electric generating processes. In FY 1991 the DOE/GD-sponsored R D project was focused on reducing well drilling, fluid transport and energy conversion costs. Specific activities being performed included lightweight CO{sub 2}- resistant well cements, chemical systems for lost circulation control, thermally conductive and scale resistant protective linear systems, corrosion mitigation in process components at The Geysers, and elastomer-metal bonding systems needed for use in high temperature well drilling and safety related applications.

  8. ASME Material Challenges for Advanced Reactor Concepts

    SciTech Connect (OSTI)

    Piyush Sabharwall; Ali Siahpush

    2013-07-01T23:59:59.000Z

    This study presents the material Challenges associated with Advanced Reactor Concept (ARC) such as the Advanced High Temperature Reactor (AHTR). ACR are the next generation concepts focusing on power production and providing thermal energy for industrial applications. The efficient transfer of energy for industrial applications depends on the ability to incorporate cost-effective heat exchangers between the nuclear heat transport system and industrial process heat transport system. The heat exchanger required for AHTR is subjected to a unique set of conditions that bring with them several design challenges not encountered in standard heat exchangers. The corrosive molten salts, especially at higher temperatures, require materials throughout the system to avoid corrosion, and adverse high-temperature effects such as creep. Given the very high steam generator pressure of the supercritical steam cycle, it is anticipated that water tube and molten salt shell steam generators heat exchanger will be used. In this paper, the ASME Section III and the American Society of Mechanical Engineers (ASME) Section VIII requirements (acceptance criteria) are discussed. Also, the ASME material acceptance criteria (ASME Section II, Part D) for high temperature environment are presented. Finally, lack of ASME acceptance criteria for thermal design and analysis are discussed.

  9. Theoretical investigations of two Si-based spintronic materials

    SciTech Connect (OSTI)

    Fong, C Y; Snow, R; Shaughnessy, M; Pask, J E; Yang, L H

    2007-08-03T23:59:59.000Z

    Two Si-based spintronic materials, a Mn-Si digital ferromagnetic heterostructure ({delta}-layer of Mn doped in Si) with defects and dilutely doped Mn{sub x}Si{sub 1-x} alloy are investigated using a density-functional based approach. We model the heterostructure and alloy with a supercell of 64 atoms and examine several configurations of the Mn atoms. We find that 25% substitutional defects without vacancies in the {delta} layer diminishes half metallicity of the DFH substantially. For the alloy, the magnetic moment M ranges from 1.0-9.0 {mu}{sub B}/unit-cell depending on impurity configuration and concentration. Mn impurities introduce a narrow band of localized states near E{sub F}. These alloys are not half metals though their moments are integer. We explain the substantially different magnetic moments.

  10. From Smart Materials to Cognitive Materials Requirements and Challenges

    E-Print Network [OSTI]

    Bremen, Universität

    From Smart Materials to Cognitive Materials ­ Requirements and Challenges Lutz Frommberger (lutz construction, production engineer- ing, or wearable computing. Smart and sensorial materials provide a variety this application than the material itself that can be considered being "smart". In this contribution, we proceed

  11. Sloan Digital Sky Survey II (SDSS-II) Supernova Data

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Sloan Digital Sky Survey (SDSS) is a series of three interlocking imaging and spectroscopic surveys, carried out over an eight-year period with a dedicated 2.5m telescope located at Apache Point Observatory in Southern New Mexico. The SDSS Supernova Survey was one of those three components of SDSS and SDSS-II, a 3-year extension of the original SDSS that operated from July 2005 to July 2008. The Supernova Survey was a time-domain survey, involving repeat imaging of the same region of sky every other night, weather permitting. The primary scientific motivation was to detect and measure light curves for several hundred supernovae through repeat scans of the SDSS Southern equatorial stripe 82 (about 2.5? wide by ~120? long). Over the course of three 3-month campaigns SDSS-II SN discovered and measured multi-band lightcurves for ~500 spectroscopically confirmed Type Ia supernovae in the redshift range z=0.05-0.4. In addition, the project harvested a few hundred light curves for SNe Ia and discovered about 80 spectroscopically confirmed core-collapse supernovae (supernova types Ib/c and II).

  12. MATERIALS AND MOLECULAR RESEARCH DIVISION ANNUAL REPORT 1979

    E-Print Network [OSTI]

    Authors, Various

    2013-01-01T23:59:59.000Z

    in Alkyne Metathesis: Flash Pyrolysis of Substituted n4-the products of vacuum flash pyrolysis of tetralin (! ) at

  13. Ti (II) Mediated Reactions in Organic Chemistry

    E-Print Network [OSTI]

    Johnson, Jeff S.

    ' #12;Generation of Ti(II) from Ti(IV) · Bercaw accessed and characterized the first Ti'X -X Generation of Ti(II) via Reductive Alkylation · Ti(IV) converted to Ti(II) via reductive/Acetylene Functionalizations · Reductive Couplings #12;Advantages of Titanium · Titanium (IV) reagents are cheap and readily

  14. I I I I II I I I II I I I II I I I II I I I II I I I II I I I II I I I II I I I II I I I IIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIII

    E-Print Network [OSTI]

    Laboratory during 1996. The department is undertaking research within Simulation and Optimisation of Energy I II I I I II I I I II I I I I I CONTENTS 4 Introduction 6 Simulation and Optimisation of Energy Related to Power Production 16 Energy and Environment in Developing Countries 16 UNEP Support Activities

  15. Final Report: Characterization of Hydrogen Adsorption in Carbon-Based Materials by NMR

    SciTech Connect (OSTI)

    Yue Wu; Alfred Kleinhammes

    2011-07-11T23:59:59.000Z

    In support of DOE/EERE's Fuel Cell Technologies Program Hydrogen Sorption Center of Excellence (HSCoE), UNC conducted Nuclear Magnetic Resonance (NMR) measurements that contributed spectroscopic information as well as quantitative analysis of adsorption processes. While NMR based Langmuir isotherms produce reliable H2 capacity measurements, the most astute contribution to the center is provided by information on dihydrogen adsorption on the scale of nanometers, including the molecular dynamics of hydrogen in micropores, and the diffusion of dihydrogen between macro and micro pores. A new method to assess the pore width using H2 as probe of the pore geometry was developed and is based on the variation of the observed chemical shift of adsorbed dihydrogen as function of H2 pressure. Adsorbents designed and synthesized by the Center were assessed for their H2 capacity, the binding energy of the adsorption site, their pore structure and their ability to release H2. Feedback to the materials groups was provided to improve the materials’ properties. To enable in situ NMR measurements as a function of H2 pressure and temperature, a unique, specialized NMR system was designed and built. Pressure can be varied between 10-4 and 107 Pa while the temperature can be controlled between 77K and room temperature. In addition to the 1H investigation of the H2 adsorption process, NMR was implemented to measure the atomic content of substituted elements, e.g. boron in boron substituted graphitic material as well as to determine the local environment and symmetry of these substituted nuclei. The primary findings by UNC are the following: • Boron substituted for carbon in graphitic material in the planar BC3 configuration enhances the binding energy for adsorbed hydrogen. • Arrested kinetics of H2 was observed below 130K in the same boron substituted carbon samples that combine enhanced binding energy with micropore structure. • Hydrogen storage material made from activated PEEK is well suited for hydrogen storage due to its controlled microporous structure and large surface area. • A new porosimetry method for evaluating the pore landscape using H2 as a probe was developed. 1H NMR can probe the nanoscale pore structure of synthesized material and can assess the pore dimension over a range covering 1.2 nm to 2.5 nm, the size that is desired for H2 adsorption. • Analysis of 1H NMR spectra in conjunction with the characterization of the bonding structure of the adsorbent by 13C NMR distinguishes between a heterogeneous and homogeneous pore structure as evidenced by the work on AX21 and activated PEEK. • Most of the sorbents studied are suited to hydrogen storage at low temperature (T < 100K). Of the materials investigated, only boron substituted graphite has the potential to work at higher temperatures if the boron content in the favorable planar BC3 configuration that actively contributes to adsorption can be increased.

  16. The Kinematic Composition of MgII Absorbers

    E-Print Network [OSTI]

    Jane C. Charlton; Christopher W. Churchill

    1997-12-17T23:59:59.000Z

    The study of galaxy evolution using quasar absorption lines requires an understanding of what components of galaxies and their surroundings are contributing to the absorption in various transitions. This paper considers the kinematic composition of the class of 0.4 < z < 1.0 MgII absorbers, particularly addressing the question of what fraction of this absorption is produced in halos and what fraction arises from galaxy disks. We design models with various fractional contributions from radial infall of halo material and from a rotating thick disk component. We generate synthetic spectra from lines of sight through model galaxies and compare the resulting ensembles of MgII profiles with the 0.4 < z < 1.0 sample observed with HIRES/Keck. We apply a battery of statistical tests and find that pure disk and pure halo models can be ruled out, but that various models with rotating disk and infall/halo contributions can produce an ensemble that is nearly consistent with the data. A discrepancy in all models that we considered requires the existence of a kinematic component intermediate between halo and thick disk. The variety of MgII profiles can be explained by the gas in disks and halos of galaxies not very much different than galaxies in the local Universe. In any one case there is considerable ambiguity in diagnosing the kinematic composition of an absorber from the low ionization high resolution spectra alone. Future data will allow galaxy morphologies, impact parameters, and orientations, FeII/MgII of clouds, and the distribution of high ionization gas to be incorporated into the kinematic analysis. Combining all these data will permit a more accurate diagnosis of the physical conditions along the line of sight through the absorbing galaxy.

  17. Part I. Ecological Sites and Soil Part II. A Framework for Soil and

    E-Print Network [OSTI]

    Part I. Ecological Sites and Soil Survey Part II. A Framework for Soil and Vegetation Dynamics Arlene Tugel, Soil Scientist Liaison to ARS, USDA-NRCS Las Cruces, NM and the Soils-ESD Advisory Group #12;What makes a site a site? Soil forming factors: climate, parent, material, biotic factors

  18. J. Phys II FYance 5 (1995) 1577-1596 OCTOBER1995, PAGE 1577 Classification

    E-Print Network [OSTI]

    Boyer, Edmond

    1995-01-01T23:59:59.000Z

    of the electrostatic interactions between ribbons in the onset of the nematic ordering of this system is stressed because they may combine the fluidity and alignment properties of liquid crystals with the (* URA 002CTO~IER1995 m #12;1578 JOURNAL DE PHYSIQUE II N°10 electronic properties of inorganic materials

  19. CURE MONITORING AND SHM OF CARBON FIBER REINFORCED PART II : MULTI-PHYSICAL CORRELATIONS

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    CURE MONITORING AND SHM OF CARBON FIBER REINFORCED POLYMER PART II : MULTI-PHYSICAL CORRELATIONS. The material (made of T700 carbon /M21 epoxy prepegs) is here used as a sensor but could be also used]. The electrical resistivity of CFRP composites depends on the type and the orientation of the fiber

  20. Resistance Spot Welding of Galvanized Steel: Part II. Mechanisms of Spot Weld Nugget Formation

    E-Print Network [OSTI]

    Eagar, Thomas W.

    ( l Resistance Spot Welding of Galvanized Steel: Part II. Mechanisms of Spot Weld Nugget Formation S. A. GEDEON and T. W. EAGAR Dynamic inspection monitoring of the weld current, voltage, resistance of material variations and weld process parameter modifications on resistance spot welding of coated

  1. Graphene: Materially Better Carbon

    SciTech Connect (OSTI)

    Fuhrer, M. S.; Lau, C. N.; MacDonald, A. H.

    2010-01-01T23:59:59.000Z

    Graphene, a single atom–thick plane of carbon atoms arranged in a honeycomb lattice, has captivated the attention of physicists, materials scientists, and engineers alike over the five years following its experimental isolation. Graphene is a fundamentally new type of electronic material whose electrons are strictly confined to a two-dimensional plane and exhibit properties akin to those of ultrarelativistic particles. Graphene's two-dimensional form suggests compatibility with conventional wafer processing technology. Extraordinary physical properties, including exceedingly high charge carrier mobility, current-carrying capacity, mechanical strength, and thermal conductivity, make it an enticing candidate for new electronic technologies both within and beyond complementary metal oxide semiconductors (CMOS). Immediate graphene applications include high-speed analog electronics and highly conductive, flexible, transparent thin films for displays and optoelectronics. Currently, much graphene research is focused on generating and tuning a bandgap and on novel device structures that exploit graphene's extraordinary electrical, optical, and mechanical properties.

  2. Geothermal materials development activities

    SciTech Connect (OSTI)

    Kukacka, L.E.

    1993-06-01T23:59:59.000Z

    This ongoing R&D program is a part of the Core Research Category of the Department of Energy/Geothermal Division initiative to accelerate the utilization of geothermal resources. High risk materials problems that if successfully solved will result in significant reductions in well drilling, fluid transport and energy conversion costs, are emphasized. The project has already developed several advanced materials systems that are being used by the geothermal industry and by Northeastern Electric, Gas and Steam Utilities. Specific topics currently being addressed include lightweight C0{sub 2}-resistant well cements, thermally conductive scale and corrosion resistant liner systems, chemical systems for lost circulation control, elastomer-metal bonding systems, and corrosion mitigation at the Geysers. Efforts to enhance the transfer of the technologies developed in these activities to other sectors of the economy are also underway.

  3. Luz II | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to:46 - 429Lacey,(MonasterLowell Point, Alaska:Luz II Jump to: navigation, search Name:

  4. Webinar: Hydrogen Compatibility of Materials

    Broader source: Energy.gov [DOE]

    Video recording of the webinar titled, Hydrogen Compatibility of Materials, originally presented on August 13, 2013.

  5. Cathode material for lithium batteries

    DOE Patents [OSTI]

    Park, Sang-Ho; Amine, Khalil

    2013-07-23T23:59:59.000Z

    A method of manufacture an article of a cathode (positive electrode) material for lithium batteries. The cathode material is a lithium molybdenum composite transition metal oxide material and is prepared by mixing in a solid state an intermediate molybdenum composite transition metal oxide and a lithium source. The mixture is thermally treated to obtain the lithium molybdenum composite transition metal oxide cathode material.

  6. Materials Department Annual Report 1992

    E-Print Network [OSTI]

    Materials Department Annual Report 1992 Published by the Materials Department Risø National and stone by Chr. Dahlgaard Larsen Materials Department Risø National Laboratory, Roskilde, Denmark Tel.: +45 46 77 46 77 Fax: +4542351173 #12;Abstract Selected activities ot the Materials Department at Riso

  7. Materials Department Annual Report 1991

    E-Print Network [OSTI]

    Materials Department Annual Report 1991 Published by the Materials Department Risø National, iron and stone by Chr. Dahlgaard Larsen Materials Department Risø National Laboratory, Roskilde, Denmark Tel.: +45 42 37 12 12 Fax: + 45 42 35 11 73 #12;Abstract Selected activities of the Materials

  8. MATERIAL HANDLING, STORAGE, AND DISPOSAL

    E-Print Network [OSTI]

    US Army Corps of Engineers

    Materials shall be stored in a manner that allows easy identification and access to labels, identification entering storage areas. All persons shall be in a safe position while materials are being loadedEM 385-1-1 XX Jun 13 14-1 SECTION 14 MATERIAL HANDLING, STORAGE, AND DISPOSAL 14.A MATERIAL

  9. George Smith, Department of Materials,

    E-Print Network [OSTI]

    Paxton, Anthony T.

    George Smith, Department of Materials, Oxford University, Parks Road, Oxford OX1 3PH UK Email: george.smith@materials.ox.ac.uk URL: www.materials.ox.ac.uk The aims of the Department of Materials experienced one of the most successful years in its 46-year history, says head of department George Smith. Top

  10. Materials in design

    E-Print Network [OSTI]

    Perata, Alfredo Ferando

    1970-01-01T23:59:59.000Z

    the strength, hardness and wear resistance has been increased. S rin Materials Since in many cases equipment requires that springs have to operate properly at conditions of excessive vibration, corrosive environment, extremes temperatures. A great care has...) It is considered a good long wearing bearing metal where good bearing conditions are present once the design has been done very good. (Accurate filling, good oil clearance; good lubrication, non-corrosive oil). It can be used with hardened shafts. B ' g B Tin...

  11. Materials Technical Team Roadmap

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department of EnergyDevelopment AccidentEnergy Objective: DevelopMaterials

  12. Materials | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department of EnergyDevelopment AccidentEnergy Objective:11 DOEMaterials Materials

  13. Lead carbonate scintillator materials

    DOE Patents [OSTI]

    Derenzo, S.E.; Moses, W.W.

    1991-05-14T23:59:59.000Z

    Improved radiation detectors containing lead carbonate or basic lead carbonate as the scintillator element are disclosed. Both of these scintillators have been found to provide a balance of good stopping power, high light yield and short decay constant that is superior to other known scintillator materials. The radiation detectors disclosed are favorably suited for use in general purpose detection and in medical uses. 3 figures.

  14. Advanced Materials Manufacturing | ORNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth (AOD)ProductssondeadjustsondeadjustAbout the BuildingInnovation Portal Advanced Material

  15. A strong magneto-optical activity in rare-earth La{sup 3+} substituted M-type strontium ferrites

    SciTech Connect (OSTI)

    Hu Feng; Liu Xiansong; Zhu Deru [Engineering Technology Research Center of Magnetic Materials, Anhui Province, School of Physics and Materials Science, Anhui University, Hefei 230039 (China); Fernandez-Garcia, Lucia; Suarez, Marta; Luis Menendez, Jose [Centro de Investigacion en Nanomateriales y Nanotecnologia (CINN), Consejo Superior de Investigaciones Cientificas (CSIC) - Universidad de Oviedo - UO - Principado de Asturias, Parque Tecnologico de Asturias, 33428 Llanera, Asturias (Spain)

    2011-06-01T23:59:59.000Z

    M-type strontium ferrites with substitution of Sr{sup 2+} by rare-earth La{sup 3+} were prepared by conventional ceramic technology. The structure, magnetic properties, and magneto-optical Kerr activity of Sr{sub 1-x}La{sub x}Fe{sub 12}O{sub 19} (x = 0, 0.05, 0.10, 0.15, 0.20) were investigated by x-ray diffraction (XRD), vibrating sample magnetometer (VSM), and magneto-optical ellipsometry, respectively. X-ray diffraction showed that the samples sintered at 1290 deg. C for 3 h were single M-type hexagonal ferrites. The magnetic properties were remarkably changed due to the valence change of Fe ions induced by the substitution of La ions. Most significantly, an important magneto-optical activity was induced in the La{sup 3+} substituted M-type strontium ferrites around 3 eV.

  16. Topaz II preliminary safety assessment

    SciTech Connect (OSTI)

    Marshall, A.C. (Sandia National Laboratories, Albuquerque, New Mexico 87185 (United States)); Standley, V. (Air Force Phillips Laboratory, Albuquerque, New Mexico 87110 (United States)); Voss, S.S. (Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)); Haskin, E. (Department of Chemical and Nuclear Engineering Department, Institute for Nuclear Power Studies, University of New Mexico, Albuquerque, New Mexico 87110 (United States))

    1993-01-10T23:59:59.000Z

    The Strategic Defense Initiative Organization (SDIO) decided to investigate the possibility of launching a Russian Topaz II space nuclear power system. A preliminary safety assessment was conducted to determine whether or not a space mission could be conducted safely and within budget constraints. As part of this assessment, a safety policy and safety functional requirements were developed to guide both the safety assessment and future Topaz II activities. A review of the Russian flight safety program was conducted and documented. Our preliminary safety assessment included a top level event tree, neutronic analysis of normal and accident configurations, an evaluation of temperature coefficients of reactivity, a reentry and disposal analysis, and analysis of postulated launch abort impact accidents, and an analysis of postulated propellant fire and explosion accidents. Based on the assessment, it appears that it will be possible to safely launch the Topaz II system in the U.S. with some possible system modifications. The principal system modifications will probably include design changes to preclude water flooded criticality and to assure intact reentry.

  17. PEP-II Operations Report

    SciTech Connect (OSTI)

    Zisman, Michael S.

    2000-11-01T23:59:59.000Z

    PEP-II is a two-ring asymmetric B factory operating at the Upsilon(4S) resonance. It was constructed by a SLAC-LBNL-LLNL collaboration. The collider comprises two rings, a High-Energy Ring (HER) storing 9 GeV electrons, and a Low-Energy Ring (LER) storing 3.1 GeV positrons. Commissioning of the HER began in mid-1997 and commissioning of the LER began in mid-1998. First evidence for collisions was obtained on July 23, 1998. The BaBar detector was installed in early 1999, and commissioning with the detector commenced in May 1999. By September 1999, PEP-II had reached a peak luminosity of 1.35 x 10{sup 33} cm{sup {minus}2} s{sup {minus}1}. In the present run, which began in October 1999, the peak luminosity has reached 3.1 x 10{sup 33} cm{sup {minus}2} s{sup {minus}1} and the integrated luminosity delivered is 25 fb{sup {minus}1}. At present, PEP-II is the world's highest luminosity collider. In this paper we describe the startup experience and summarize the operational experience during fiscal year 2000 (from October 1999 through September 2000). Plan s for luminosity upgrades are briefly described.

  18. Organic materials with acenoid and iptycene structures

    E-Print Network [OSTI]

    Chen, Zhihua, Ph. D. Massachusetts Institute of Technology

    2007-01-01T23:59:59.000Z

    Chapter 1. The synthesis of a group of alkoxy-substituted para-acenequinones and their photophysical properties in solution and liquid crystal are reported. Polarized absorption and fluorescence measurements demonstrate ...

  19. Structure and stability of Co(II)-complexes formed by wild-type and metal-ligand substitution mutants of T4 gene 32 protein

    E-Print Network [OSTI]

    Guo, Juqian

    1996-01-01T23:59:59.000Z

    Phage T4 gene 32 protein (gp32) is a zinc metalloprotein that binds cooperatively and preferentially to single-stranded nucleic acids and functions as a replication and recombination accessory protein. We have previously shown that the ZN...

  20. Electronic structure and f-orbital occupancy in Yb-substituted CeCoIn5

    SciTech Connect (OSTI)

    Booth, C. H.; Durakiewicz, T.; Capan, C.; Hurt, D.; Bianchi, A. D.; Joyce, J.J.; Fisk, Z.

    2011-05-03T23:59:59.000Z

    The local structure and 4f orbital occupancy have been investigated in Ce{sub 1?x}Yb{sub x}CoIn{sub 5} via Yb L{sub III}-edge extended x-ray absorption fine structure (EXAFS), Ce and Yb L{sub III}-edge x-ray absorption near-edge structure (XANES), and angle-resolved photoemission spectroscopy (ARPES) measurements. Yb(III) (4f{sup 13}) is the hole analog of Ce(III) (4f{sup 1}). Yb is found to be strongly intermediate-valent in Ce{sub 1?x}Yb{sub x}CoIn{sub 5} throughout the entire doping range, including pure YbCoIn{sub 5}, with an f-hole occupancy for Yb of n{sub f} ? 0.3 (i.e. Yb{sup 2.3+}), independent of Yb concentration and independent of temperature down to T = 20 K. In contrast, the f-electron orbital occupancy for Ce remains close to 1 for all Yb concentrations, suggesting that there is no mutual influence on n{sub f} between neighboring Ce and Yb sites. Likewise, ARPES measurements at 12 K have found that the electronic structure along {Gamma} ? X is not sensitive to the Yb substitution, suggesting that the Kondo hybridization of Ce f electrons with the conduction band is not affected by the presence of Yb impurities in the lattice. The emerging picture is that in Ce{sub 1?x}Yb{sub x}CoIn{sub 5} there are two networks, interlaced but independent, that couple to the conduction band: one network of Ce ions in the heavy-fermion limit, one network of Yb ions in the strongly intermediate-valent limit. The robustness of the local and electronic structure to doping suggests the absence of charge transfer between the Ce and Yb ions, and may explain the relative robustness of superconductivity for this Ce-site substitution as compared to the In-site substitution.

  1. InAs/InAsSb strain balanced superlattices for optical detectors: Material properties and energy band simulations

    E-Print Network [OSTI]

    Krishna, Sanjay

    InAs/InAsSb strain balanced superlattices for optical detectors: Material properties and energyAs/InAsSb strain balanced superlattices for optical detectors: Material properties and energy band simulations D February 2012) InAsSb/InAs type II strain balanced superlattices lattice matched to GaSb have recently been

  2. Scalable Routes to Efficient Thermoelectric Materials

    E-Print Network [OSTI]

    Feser, Joseph Patrick

    2010-01-01T23:59:59.000Z

    thermoelectric materials consisting of epitaxially-grownefficient thermoelectric materials," Nature, vol. 451, pp.superlattice thermoelectric materials and devices," Science,

  3. Advanced Battery Materials Characterization: Success stories...

    Broader source: Energy.gov (indexed) [DOE]

    Advanced Battery Materials Characterization: Success stories from the High Temperature Materials Laboratory (HTML) User Program Advanced Battery Materials Characterization: Success...

  4. Transition metalphthalocyanines as structures for materials design

    SciTech Connect (OSTI)

    Hanack, M. [Universitaet Tuebingen (Germany)

    1993-12-31T23:59:59.000Z

    Metallophthalocyanines have been used recently more and more for the preparation of materials, which exhibit interesting semiconducting and non-linear optical properties. A necessary condition for achieving, e.g. electrical properties of phthalocyanines [MacM(L)]{sub n} can be obtained by the so-called {open_quotes}shish kebab{close_quotes} approach in which transition metallomacrocycles (MacM) are linked together by bidentate bridging ligands (L). Such bridged macrocyclic metal compounds [MacM(L)]{sub n} with transition metals e.g. Fe, Ru, Os, Co, Rh in various oxidation states have been synthesized. In general, these complexes [MacM(L)]{sub n} are insoluble in organic solvents, however, soluble oligomers [R{sub 4}PcM(L)]{sub n} can be prepared using metallomacrocycles R{sub 4}PcM, R = t-bu, et, M = Fe, Ru. The influence of the bridging ligand on the conductivity of the bridged phthalocyaninato and 2,3-naphthalocyaninatotransition metal complexes is studied. As bridging ligand mostly pyrazine (pyz), 1,4-diisocyanobenzene (dib), tetrazine (tz) is used. [MacM(tz)]{sub n} exhibit intrinsic conductivities. The synthesis and characterization of [PcM(tz)], with M = Fe, Ru, Os and [2,3-NcFe(tz)]{sub n} is described. Powder conductivities in the order of 0.1 S/cm can be reached by using s-tetrazine, but also substituted tetrazine e.g. 3,6-dimethyl-s-tetrazine (me{sub 2}tz) are used as the bridging ligands in such complexes.

  5. II

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofofOxford SiteToledo SiteTonawanda North - t ' v I tfi -- ..~

  6. II

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecember 2005 (Thousand9,0, 1997Environment >7,992000 Short-TermSeptember» ;, a

  7. II*

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecember 2005 (Thousand9,0, 1997Environment >7,992000 Short-TermSeptember» ;,

  8. II

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$0.C. 20545*. . : '* FEB1f\lMUC4cb90,fioml7aa AMY y

  9. II

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$0.C. 20545*. . : '* FEB1f\lMUC4cb90,fioml7aa AMY y

  10. Structure and Electrochemistry of LiNi1/3Co1/3-yMyMn1/3O2 (M=Ti, Al, Fe) Positive Electrode Materials

    SciTech Connect (OSTI)

    Wilcox, James; Patoux, Sebastien; Doeff, Marca

    2009-01-14T23:59:59.000Z

    A series of materials based on the LiNi1/3Co1/3-yMyMn1/3O2 (M = Ti,Al,Fe) system has been synthesized and examined structurally and electrochemically. It is found that the changes in electrochemical performance depend highly on the nature of the substituting atom and its effect on the crystal structure. Substitution with small amounts of Ti4+ (y = 1/12) leads to the formation of a high-capacity and high-rate positive electrode material. Iron substituted materials suffer from an increased antisite defect concentration and exhibit lower capacities and poor rate capabilities. Single-phase materials are found for LiNi1/3Co1/3-yAlyMn1/3O2 when y<_ 1/4 and all exhibit decreased capacities when cycled to 4.3 V. However, an increase in rate performance and cycle stability upon aluminum substitution is correlated with an improved lamellar structure.

  11. Temperature dependence of the vapour tension of methyl-substituted phenol derivatives

    SciTech Connect (OSTI)

    S.G. Gagarin [Institute of Mineral Fuels (Russian Federation)

    2007-05-15T23:59:59.000Z

    Notable among the coking products of coal are phenol and its derivatives, derived for the coal tar and water layer above ht tar. Given that phenol an its derivatives are mainly extracted from coal tar fractions by rectification, information on how the vapor tension of the individual components depends on the temperature is of great importance. For phenol and various substituted alkylphenols there are tabular data. In the pre-computer era these data were sufficient for the separation of phenol mixtures. However, the development and introduction of information technology in the coal industry and in the design process demands the mathematical description of the physicochemical processes of coking products. The temperature dependence of the saturated vapor pressure for organic compounds is commonly described by the Antoine equation.

  12. Lattice constant and substitutional composition of GeSn alloys grown by molecular beam epitaxy

    SciTech Connect (OSTI)

    Bhargava, Nupur; Coppinger, Matthew; Prakash Gupta, Jay; Kolodzey, James [Department of Electrical and Computer Engineering, University of Delaware, Newark, Delaware 19716 (United States)] [Department of Electrical and Computer Engineering, University of Delaware, Newark, Delaware 19716 (United States); Wielunski, Leszek [Department of Physics and Astronomy, Rutgers University, Piscataway, New Jersey 08854 (United States)] [Department of Physics and Astronomy, Rutgers University, Piscataway, New Jersey 08854 (United States)

    2013-07-22T23:59:59.000Z

    Single crystal epitaxial Ge{sub 1?x}Sn{sub x} alloys with atomic fractions of tin up to x = 0.145 were grown by solid source molecular beam epitaxy on Ge (001) substrates. The Ge{sub 1?x}Sn{sub x} alloys formed high quality, coherent, strained layers at growth temperatures below 250 °C, as shown by high resolution X-ray diffraction. The amount of Sn that was on lattice sites, as determined by Rutherford backscattering spectrometry channeling, was found to be above 90% substitutional in all alloys. The degree of strain and the dependence of the effective unstrained bulk lattice constant of Ge{sub 1?x}Sn{sub x} alloys versus the composition of Sn have been determined.

  13. Micelle formation and surface activity of functional redox relays: viologens substituted by a long alkyl chain

    SciTech Connect (OSTI)

    Krieg, M.; Pileni, M.P.; Braun, A.M.; Gratzel, M.

    1981-09-01T23:59:59.000Z

    Viologens are receiving increasing attention from 2 major domains. First, photo- and electroreproductive processes are being developed which exploit the pronounced chromophore effect associated with the one-electron reduction of the viologens: the 2+ state is practically colorless, while the 1+ state has an intense color. However, the most prominent impact in viologen-related research arises from their use as mediators, sometimes referred to as electron relays, in the photionduced generation of hydrogen from water. Photobiologists had discovered earlier that methyl viologen in chloroplast suspensions is suited to act as a Hill reagent which can be coupled with hydrogenase to yield H/sub 2/ under illumination. More recently, in vitro systems have been developed in which synthetic dyes replace the chloroplasts as redox sensitizers. These have been shown to be remarkably effective in H/sub 2/ production. The surfactant and micellar properties of a series of potent candidates, i.e., long-chain-substituted viologens are investigated.

  14. Density Functional Investigation of Melamine-Formaldehyde Crosslinking Agents Part 1: Partially Substituted Melamine

    SciTech Connect (OSTI)

    Benson, Michael Timothy

    2003-07-01T23:59:59.000Z

    Computational modeling has been performed on the cross-linking mechanism of partially substituted melamine reacting with poly(vinyl alcohol). Ab initio calculations were performed with density functional theory employing the BLYP functional and double numerical DND basis set. The mechanism, general acid catalysis, has been modeled with respect to structures, protonation, and reaction with a polymer. Protonation of the oxygen is required initially, followed by liberation of methanol. The reaction can take one of two pathways after methanol liberation. The conjugate base of the weak acid can abstract a proton, generating a Schiff-base intermediate. The O-H on the polymer then adds to the C-N double bond, producing the polymer-melamine bond. The alternative is that the polymer adds to the charged melamine, using the specific acid catalysis mechanism. After polymer addition, the proton is abstracted, producing the product.

  15. Near fifty percent sodium substituted lanthanum manganites—A potential magnetic refrigerant for room temperature applications

    SciTech Connect (OSTI)

    Sethulakshmi, N.; Anantharaman, M. R., E-mail: mraiyer@yahoo.com [Department of Physics, Cochin University of Science and Technology, Cochin 682022, Kerala (India); Al-Omari, I. A. [Department of Physics, Sultan Qaboos University, PC 123 Muscat, Sultanate of Oman (Oman); Suresh, K. G. [Department of Physics, Indian Institute of Technology Bombay, Powai, Mumbai 400076 (India)

    2014-03-03T23:59:59.000Z

    Nearly half of lanthanum sites in lanthanum manganites were substituted with monovalent ion-sodium and the compound possessed distorted orthorhombic structure. Ferromagnetic ordering at 300?K and the magnetic isotherms at different temperature ranges were analyzed for estimating magnetic entropy variation. Magnetic entropy change of 1.5?J·kg{sup ?1}·K{sup ?1} was observed near 300?K. An appreciable magnetocaloric effect was also observed for a wide range of temperatures near 300?K for small magnetic field variation. Heat capacity was measured for temperatures lower than 300?K and the adiabatic temperature change increases with increase in temperature with a maximum of 0.62?K at 280?K.

  16. STUDIES ON TWO CLASSES OF POSITIVE ELECTRODE MATERIALS FOR LITHIUM-ION BATTERIES

    SciTech Connect (OSTI)

    Wilcox, James D.

    2008-12-18T23:59:59.000Z

    The development of advanced lithium-ion batteries is key to the success of many technologies, and in particular, hybrid electric vehicles. In addition to finding materials with higher energy and power densities, improvements in other factors such as cost, toxicity, lifetime, and safety are also required. Lithium transition metal oxide and LiFePO{sub 4}/C composite materials offer several distinct advantages in achieving many of these goals and are the focus of this report. Two series of layered lithium transition metal oxides, namely LiNi{sub 1/3}Co{sub 1/3-y}M{sub y}Mn{sub 1/3}O{sub 2} (M=Al, Co, Fe, Ti) and LiNi{sub 0.4}Co{sub 0.2-y}M{sub y}Mn{sub 0.4}O{sub 2} (M = Al, Co, Fe), have been synthesized. The effect of substitution on the crystal structure is related to shifts in transport properties and ultimately to the electrochemical performance. Partial aluminum substitution creates a high-rate positive electrode material capable of delivering twice the discharge capacity of unsubstituted materials. Iron substituted materials suffer from limited electrochemical performance and poor cycling stability due to the degradation of the layered structure. Titanium substitution creates a very high rate positive electrode material due to a decrease in the anti-site defect concentration. LiFePO{sub 4} is a very promising electrode material but suffers from poor electronic and ionic conductivity. To overcome this, two new techniques have been developed to synthesize high performance LiFePO{sub 4}/C composite materials. The use of graphitization catalysts in conjunction with pyromellitic acid leads to a highly graphitic carbon coating on the surface of LiFePO{sub 4} particles. Under the proper conditions, the room temperature electronic conductivity can be improved by nearly five orders of magnitude over untreated materials. Using Raman spectroscopy, the improvement in conductivity and rate performance of such materials has been related to the underlying structure of the carbon films. The combustion synthesis of LiFePO4 materials allows for the formation of nanoscale active material particles with high-quality carbon coatings in a quick and inexpensive fashion. The carbon coating is formed during the initial combustion process at temperatures that exceed the thermal stability limit of LiFePO{sub 4}. The olivine structure is then formed after a brief calcination at lower temperatures in a controlled environment. The carbon coating produced in this manner has an improved graphitic character and results in superior electrochemical performance. The potential co-synthesis of conductive carbon entities, such as carbon nanotubes and fibers, is also briefly discussed.

  17. PHASE II VAULT TESTING OF THE ARGONNE RFID SYSTEM

    SciTech Connect (OSTI)

    Willoner, T.; Turlington, R.; Koenig, R.

    2012-06-25T23:59:59.000Z

    The U.S. Department of Energy (DOE) (Environmental Management [EM], Office of Packaging and Transportation [EM-45]) Packaging and Certification Program (DOE PCP) has developed a Radio Frequency Identification (RFID) tracking and monitoring system, called ARG-US, for the management of nuclear materials packages during transportation and storage. The performance of the ARG-US RFID equipment and system has been fully tested in two demonstration projects in April 2008 and August 2009. With the strong support of DOE-SR and DOE PCP, a field testing program was completed in Savannah River Site's K-Area Material Storage (KAMS) Facility, an active Category I Plutonium Storage Facility, in 2010. As the next step (Phase II) of continued vault testing for the ARG-US system, the Savannah River Site K Area Material Storage facility has placed the ARG-US RFIDs into the 910B storage vault for operational testing. This latest version (Mark III) of the Argonne RFID system now has the capability to measure radiation dose and dose rate. This paper will report field testing progress of the ARG-US RFID equipment in KAMS, the operability and reliability trend results associated with the applications of the system, and discuss the potential benefits in enhancing safety, security and materials accountability. The purpose of this Phase II K Area test is to verify the accuracy of the radiation monitoring and proper functionality of the ARG-US RFID equipment and system under a realistic environment in the KAMS facility. Deploying the ARG-US RFID system leads to a reduced need for manned surveillance and increased inventory periods by providing real-time access to status and event history traceability, including environmental condition monitoring and radiation monitoring. The successful completion of the testing program will provide field data to support a future development and testing. This will increase Operation efficiency and cost effectiveness for vault operation. As the next step (Phase II) of continued vault testing for the ARG-US system, the Savannah River Site K Area Material Storage facility has placed the ARG-US RFIDs into the 910B storage vault. Deploying the ARG-US RFID system lends to a reduced need for manned surveillance and increased inventory periods by providing real-time access to status and event history traceability, including radiation and environmental monitoring. The successful completion of the testing program will provide field data to support future development and testing.

  18. Materials Research in the Information Age

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Materials Research in the Information Age Accelerating Advanced Material Development NERSC Science Gateway a 'Google of Material Properties' October 31, 2011 | Tags: Materials...

  19. RFI: DOE Materials Strategy | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    RFI: DOE Materials Strategy RFI: DOE Materials Strategy DOE Materials Strategy - request for information RFI: DOE Materials Strategy More Documents & Publications Microsoft Word -...

  20. Sandia National Laboratories: Light Creation Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TechnologiesLight Creation Materials Light Creation Materials Overview of SSL Light Creation Materials Different families of inorganic semiconductor materials can...

  1. Sandia National Laboratories: Light Creation Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    EFRCOverviewLight Creation Materials Light Creation Materials Overview of SSL Light Creation Materials Different families of inorganic semiconductor materials can contribute to...

  2. Cathode materials review

    SciTech Connect (OSTI)

    Daniel, Claus, E-mail: danielc@ornl.gov; Mohanty, Debasish, E-mail: danielc@ornl.gov; Li, Jianlin, E-mail: danielc@ornl.gov; Wood, David L., E-mail: danielc@ornl.gov [Oak Ridge National Laboratory, 1 Bethel Valley Road, MS6472 Oak Ridge, TN 37831-6472 (United States)

    2014-06-16T23:59:59.000Z

    The electrochemical potential of cathode materials defines the positive side of the terminal voltage of a battery. Traditionally, cathode materials are the energy-limiting or voltage-limiting electrode. One of the first electrochemical batteries, the voltaic pile invented by Alessandro Volta in 1800 (Phil. Trans. Roy. Soc. 90, 403-431) had a copper-zinc galvanic element with a terminal voltage of 0.76 V. Since then, the research community has increased capacity and voltage for primary (nonrechargeable) batteries and round-trip efficiency for secondary (rechargeable) batteries. Successful secondary batteries have been the lead-acid with a lead oxide cathode and a terminal voltage of 2.1 V and later the NiCd with a nickel(III) oxide-hydroxide cathode and a 1.2 V terminal voltage. The relatively low voltage of those aqueous systems and the low round-trip efficiency due to activation energies in the conversion reactions limited their use. In 1976, Wittingham (J. Electrochem. Soc., 123, 315) and Besenhard (J. Power Sources 1(3), 267) finally enabled highly reversible redox reactions by intercalation of lithium ions instead of by chemical conversion. In 1980, Goodenough and Mizushima (Mater. Res. Bull. 15, 783-789) demonstrated a high-energy and high-power LiCoO{sub 2} cathode, allowing for an increase of terminal voltage far beyond 3 V. Over the past four decades, the international research community has further developed cathode materials of many varieties. Current state-of-the-art cathodes demonstrate voltages beyond any known electrolyte stability window, bringing electrolyte research once again to the forefront of battery research.

  3. Combinatorial synthesis of novel materials

    DOE Patents [OSTI]

    Schultz, Peter G. (Oakland, CA); Xiang, Xiaodong (Alameda, CA); Goldwasser, Isy (Menlo Park, CA)

    2001-01-01T23:59:59.000Z

    Methods and apparatus for the preparation and use of a substrate having an array of diverse materials in predefined regions thereon. A substrate having an array of diverse materials thereon is generally prepared by delivering components of materials to predefined regions on a substrate, and simultaneously reacting the components to form at least two materials. Materials which can be prepared using the methods and apparatus of the present invention include, for example, covalent network solids, ionic solids and molecular solids. More particularly, materials which can be prepared using the methods and apparatus of the present invention include, for example, inorganic materials, intermetallic materials, metal alloys, ceramic materials, organic materials, organometallic materials, non-biological organic polymers, composite materials (e.g., inorganic composites, organic composites, or combinations thereof), etc. Once prepared, these materials can be screened for useful properties including, for example, electrical, thermal, mechanical, morphological, optical, magnetic, chemical, or other properties. Thus, the present invention provides methods for the parallel synthesis and analysis of novel materials having useful properties.

  4. Combinatorial synthesis of novel materials

    DOE Patents [OSTI]

    Schultz, Peter G. (Oakland, CA); Xiang, Xiaodong (Alameda, CA); Goldwasser, Isy (Alameda, CA)

    2002-02-12T23:59:59.000Z

    Methods and apparatus for the preparation and use of a substrate having an array of diverse materials in predefined regions thereon. A substrate having an array of diverse materials thereon is generally prepared by delivering components of materials to predefined regions on a substrate, and simultaneously reacting the components to form at least two materials. Materials which can be prepared using the methods and apparatus of the present invention include, for example, covalent network solids, ionic solids and molecular solids. More particularly, materials which can be prepared using the methods and apparatus of the present invention include, for example, inorganic materials, intermetallic materials, metal alloys, ceramic materials, organic materials, organometallic materials, non-biological organic polymers, composite materials (e.g., inorganic composites, organic composites, or combinations thereof), etc. Once prepared, these materials can be screened for useful properties including, for example, electrical, thermal, mechanical, morphological, optical, magnetic, chemical, or other properties. Thus, the present invention provides methods for the parallel synthesis and analysis of novel materials having useful properties.

  5. Combinatorial synthesis of novel materials

    DOE Patents [OSTI]

    Schultz, Peter G. (Oakland, CA); Xiang, Xiaodong (Alameda, CA); Goldwasser, Isy (Menlo Park, CA)

    1999-12-21T23:59:59.000Z

    Methods and apparatus for the preparation and use of a substrate having an array of diverse materials in predefined regions thereon. A substrate having an array of diverse materials thereon is generally prepared by delivering components of materials to predefined regions on a substrate, and simultaneously reacting the components to form at least two materials. Materials which can be prepared using the methods and apparatus of the present invention include, for example, covalent network solids, ionic solids and molecular solids. More particularly, materials which can be prepared using the methods and apparatus of the present invention include, for example, inorganic materials, intermetallic materials, metal alloys, ceramic materials, organic materials, organometallic materials, non-biological organic polymers, composite materials (e.g., inorganic composites, organic composites, or combinations thereof), etc. Once prepared, these materials can be screened for useful properties including, for example, electrical, thermal, mechanical, morphological, optical, magnetic, chemical, or other properties. Thus, the present invention provides methods for the parallel synthesis and analysis of novel materials having useful properties.

  6. Combinatorial sythesis of organometallic materials

    DOE Patents [OSTI]

    Schultz, Peter G. (Oakland, CA); Xiang, Xiaodong (Alameda, CA); Goldwasser, Isy (Alameda, CA)

    2002-07-16T23:59:59.000Z

    Methods and apparatus for the preparation and use of a substrate having an array of diverse materials in predefined regions thereon. A substrate having an array of diverse materials thereon is generally prepared by delivering components of materials to predefined regions on a substrate, and simultaneously reacting the components to form at least two materials. Materials which can be prepared using the methods and apparatus of the present invention include, for example, covalent network solids, ionic solids and molecular solids. More particularly, materials which can be prepared using the methods and apparatus of the present invention include, for example, inorganic materials, intermetallic materials, metal alloys, ceramic materials, organic materials, organometallic materials, non-biological organic polymers, composite materials (e.g., inorganic composites, organic composites, or combinations thereof), etc. Once prepared, these materials can be screened for useful properties including, for example, electrical, thermal, mechanical, morphological, optical, magnetic, chemical, or other properties. Thus, the present invention provides methods for the parallel synthesis and analysis of novel materials having useful properties.

  7. Synthesis of refractory materials

    DOE Patents [OSTI]

    Holt, Joseph B. (San Jose, CA)

    1984-01-01T23:59:59.000Z

    Refractory metal nitrides are synthesized during a self-propagating combustion process utilizing a solid source of nitrogren. For this purpose, a metal azide is employed, preferably NaN.sub.3. The azide is combusted with Mg or Ca, and a metal oxide is selected from Groups III-A, IV-A, III-B, IV-B, or a rare earth metal oxide. The mixture of azide, Ca or Mg and metal oxide is heated to the mixture's ignition temperature. At that temperature the mixture is ignited and undergoes self-sustaining combustion until the starter materials are exhausted, producing the metal nitride.

  8. Synthesis of refractory materials

    DOE Patents [OSTI]

    Holt, J.B.

    1983-08-16T23:59:59.000Z

    Refractory metal nitrides are synthesized during a self-propagating combustion process utilizing a solid source of nitrogen. For this purpose, a metal azide is employed, preferably NaN/sub 3/. The azide is combusted with Mg or Ca, and a metal oxide is selected from Groups III-A, IV-A, III-B, IV-B, or a rare earth metal oxide. The mixture of azide, Ca or Mg and metal oxide is heated to the mixture's ignition temperature. At that temperature the mixture is ignited and undergoes self-sustaining combustion until the starter materials are exhausted, producing the metal nitride.

  9. Construction Material And Method

    DOE Patents [OSTI]

    Wagh, Arun S. (Orland Park, IL); Antink, Allison L. (Bolingbrook, IL)

    2006-02-21T23:59:59.000Z

    A structural material of a polystyrene base and the reaction product of the polystyrene base and a solid phosphate ceramic. The ceramic is applied as a slurry which includes one or more of a metal oxide or a metal hydroxide with a source of phosphate to produce a phosphate ceramic and a poly (acrylic acid or acrylate) or combinations or salts thereof and polystyrene or MgO applied to the polystyrene base and allowed to cure so that the dried aqueous slurry chemically bonds to the polystyrene base. A method is also disclosed of applying the slurry to the polystyrene base.

  10. Careers | Critical Materials Institute

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to someone6Energy,MUSEUM DISPLAYCareers The Critical Materials Institute

  11. LANL: Materials Science Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFunInfraredJeffersonJonathanMultimaterial2RecoveryBioenergy »0 Los1Materials

  12. Work with Biological Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched FerromagnetismWaste and MaterialsWenjun1 Table 1.14 Sales of4)Delegations, andARM

  13. Work with Biological Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched FerromagnetismWaste and MaterialsWenjun1 Table 1.14 Sales of4)Delegations, andARMWork

  14. Magnetic Materials (MM)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment Surfaces and InterfacesAdministration -Lowell L.FallU . S .ofFieldMagnetic Materials

  15. Material Point Methods

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment Surfaces andMapping the Nanoscale LandscapeImports 5.90 4.86 4.77of PolarMaterial

  16. Material Safety Data Sheet

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment Surfaces andMapping the Nanoscale LandscapeImports 5.90 4.86 4.77ofMaterial Safety

  17. Materials/Condensed Matter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recovery challenge fund LasDubey selectedContractMaterials/Condensed Matter Print

  18. Materials/Condensed Matter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recovery challenge fund LasDubey selectedContractMaterials/Condensed Matter

  19. Material efficiency in construction

    E-Print Network [OSTI]

    Moynihan, Muiris

    2014-10-07T23:59:59.000Z

    , this generation must change its use of energy and materials. 1.1 The need to reduce carbon dioxide emissions The Fifth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC) states as #16;unequivocal#17; that the Earth's atmosphere and oceans... in order to save energy and carbon. University of Cambridge, Cambridge, UK. ISBN 978-0- 903428-32-3 3. Allwood, J.M., Cullen, J.M., Patel, A.C.H., Cooper, D.R.,Moynihan, M.C., Milford, R.L., Carruth, M.A. and McBrien, M. 2011. Prolonging our metal life #22...

  20. Behavior of molybdenum nitrides as materials for electrochemical capacitors: Comparison with ruthenium oxide

    SciTech Connect (OSTI)

    Liu, T.C.; Pell, W.G.; Conway, B.E. [Univ. of Ottawa, Ontario (Canada). Dept. of Chemistry; Roberson, S.L. [North Carolina State Univ., Raleigh, NC (United States). Dept. of Materials Science and Engineering

    1998-06-01T23:59:59.000Z

    Ruthenium oxide (RuO{sub 2}), formed as a thin film on a Ru or Ti metal substrate, exhibits a large specific (cm{sup {minus}2}) and almost constant, electrochemical capacitance over a 1.35 V range in aqueous H{sub 2}SO{sub 4}. This behavior has led to its investigation and use as a material for fabrication of supercapacitor devices. However, its cost has encouraged search for other materials exhibiting similar behavior. Work reported in the present paper evaluates two nitrides of Mo, Mo{sub 2}N and MoN, as substitutes for RuO{sub 2}. It is shown that very similar capacitance behavior to that of RuO{sub 2} films arises, e.g., in cyclic voltammetry and dc charging curves; in the former, almost mirror-image anodic and cathodic current-response profiles, characteristic of a capacitor, arise. However, the nitride materials have a substantially smaller voltage operating range of only some 0.7 V due to electrochemical decomposition above ca. 0.7 V vs. RHE. This limits their usefulness as a substitute for RuO{sub 2}. Of interest is that the nitride films exhibit potential-decay and potential-recovery on open circuit after respective charge and forced discharge. The decay and recovery processes are logarithmic in time, indicating the role of internal faradaic charge redistribution processes.